## Inorganic Chemicals Manufacturing Data Supporting the 2013 Annual Review Report **Data Compiled: November 2013 - March 2014**

**Tab Name**

Summary Rankings

Top TRI Pollutants

Top TRI Pollutant Data

Inorg - 44004SCMCH2900M

Inorg - 44004SCMCH2426M Inorg - 37134DPNTJ1PUPO

## Inorganic Chemicals Manufacturing Data Supporting the 2013 Annual Review Report **Data Compiled: November 2013 - March 2014**

**Tab Description** 2013 Final Rankings for the DMR and TRI databases. Also shows what percent DMR and TRI make up for the category being reviewed. Top pollutants in the 2011 TRI Database for the Inorganic Chemicals Manufacturing Category. Includes facility count, pounds, and TWPE for each pollutant. Highlights the pollutants that were reviewed as part of the 2013 Annual Review. No facility corrections were identified for the Inorganic Chemicals Manufacturing Category during the 2013 Annual Review. Top facilities for each top pollutant in the 2011 TRI Database for the Inorganic Chemicals Manufacturing Category reviewed as part of the 2013 Annual Review. Includes facility pounds and TWPE. Facility-specific data on dioxin and dioxin-compound discharges and notes on Millennium Inorganic Chemicals in Ashtabula, OH. Facility-specific data on manganese and manganese-compound discharges and notes on Millennium Inorganic Chemicals in Ashtabula, OH. Facility-specific data and notes on Dupont Johnsonville Plant in New Johnsonville, TN.**2013 - Final Combined Rankings Excluding Categories Recently Reviewed**

**2/14/2014 Revised to incorporate PSC code changes for facilities missed as part of the change to the DMR Loading Tool**  Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

**PSC Point Source Category**  **Total Count of**  **Facilities Direct** 

**Only Indirect** 

**Only** 414 Organic chemicals, plastics and synthetic fibers 631 194 380 430 Pulp, paper and paperboard 221 145 63 419 Petroleum refining 267 192 52 501 Drinking Water Treatment 2 0 0 440 Ore mining and dressing 33 29 3 420 Iron and steel manufacturing 222 118 50 418 Fertilizer manufacturing 41 32 4 415 Inorganic chemicals manufacturing 153 56 71 421 Nonferrous metals manufacturing 119 52 49 455 Pesticide chemicals 56 30 24 409 Sugar processing 14 12 2 433 Metal Finishing 1785 263 1256 451 Concentrated Aquatic Animal Production 0 0 0 434 Coal mining 17 17 0 432 Meat and Poultry Products 156 82 61 429 Timber products processing 102 67 21 435 Oil & Gas Extraction 0 0 0 463 Plastics molding and forming 114 24 71 503 Miscellaneous Foods and Beverages 131 19 109 445 Landfills 1 1 0 417 Soap and detergent manufacturing 70 4 62 424 Ferroalloy

manufacturing 5 5 0 436 Mineral Mining and Processing 83 49 32 458 Carbon black manufacturing 4 4 0 464 Metal molding and casting (foundries) 199 89 72 410 Textile mills 44 4 33 471 Nonferrous metals forming and metal powders 119 28 56 428 Rubber Manufacturing 157 26 85 438 Metal Products and Machinery 74 18 45 422 Phosphate manufacturing 10 9 1 406 Grain mills 23 7 10 457 Explosives manufacturing 9 5 2 469 Electrical and electronic components 70 5 62 437 Centralized Waste Treatment 2 1 1 460 Hospital 0 0 0 468 Copper forming 109 24 41 467 Aluminumforming 114 18 60 439 Pharmaceutical manufacturing 84 9 71 411 Cement manufacturing 53 43 8

407 Canned and preserved fruits and vegetables processing 26 8 18 405 Dairy

products processing 291 36 247 413 Electroplating 306 15 264 466 Porcelain Enameling 4 0 3 444 Waste combustors 2 1 0 **TRI Facility Counts**508 Printing & Publishing 57 2 54

425 Leather tanning and finishing 13 1 11 426 Glass manufacturing 53 9 35 442 Transportation Equipment Cleaning 1 1 0 443 Paving and roofing materials (tars and asphalt) 29 16 6 461 Battery

manufacturing 54 3 35 507 Independent and Stand Alone Labs 1 0 1 408 Canned and preserved seafood processing 6 6 0 427 Asbestos manufacturing 0 0 0 454 Gum and wood chemicals manufacturing 10 8 1 465 Coil coating 37 1 36 446 Paint formulating 53 10 41 505 Food Service Establishments 0 0 0 506 Industrial Laundries 0 0 0 502 Tobacco Products 17 1 15 447 Ink formulating 10 1 9 509 Photo Processing 0 0 0 459 Photographic 0 0 0**Revised to incorporate PSC code changes for facilities missed as part of the change to the DMR Loading Tool** Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

**Both Direct and**  **Indirect TRI LBY**  **TRI TWPE Total**  **Count of Facilities**  **Ma**

**jors Minors**  **DMR LBY DMR TWPE**  57 25991167.15 147675.2182 470 189 281 27382536251540387.114 13 17750608.67651376.5506 234 194 40 2239681616 1034369.59 23 23589915.03680608.0883 479 96 383 516230325.2751580.6938 2 12810 1643 1335 20 1315 4216219611 1384298.003 1 1826546.128 1229923.39 93 53 40 698538772.3 109758.1093 54 33509051.7282937.27287 146 83 63 1279823916 1170699.952 5 4377973.0346667.914961 39 19 20 122486680.9599100.4356 26 8732577.95326863.4381 217 70 147 1532389542 142060.7974 18 4669549.93242948.34437 57 28 29 157405728.4382840.4371 2 2115074.33373899.7328 33 20 13 29998642.94 19317.89791 0 487306.72429.8574031 26 19 7 65490570.71 373178.6753 266 4300840.87751738.65198 626 86 540 216670888.6264963.1311 0 0 0 266 20 246 105515454.3 291885.136 0 292406.0871 563.9618167 218 13 205 8405721295188756.1494 13 51722815.4739117.80918 158 34 124 464043654 119028.2383 14 39325.356732332.84936 139 4 135 1136810374 98629.5955 0 0 0 150 14 136 5024628205106089.5093 19 2926175.40369161.81513 78 5 73 724327795.526693.83158 3 3983961.5064901.790156 119 7 112 4247927288 57364.7284 0 19942.942850.60386 234 5 229 81481172.75 19311.53355 4 94322.316822368.142999 18 3 15 2781234.30847123.66268 0 135757.558990.980096 13 2 11 13220221.9227260.26418 2 2103016.3822946.423878 992 27 965 309399106431156.47101 0 559.57927865.49368 2 0 2 4375209.577 0.2009075 38 212440.04849671.857609 53 8 45 27454867.86 16283.18749 7 592379.4161 1074.029372 67 31 36 33130533.0522342.79249 35 1340579.676 17883.4982 34 11 23 6011501.3623438.610671 46 962717.5478 10197.31036 77 15 62 19197556.737322.237141 11 316649.167951.962317 491 76 415 230974159.87672.994297 0 18457.5674 193.4171027 12 8 4 23096767.64 13597.30481 6 2851270.356 10517.45364 34 7 27 55857054.62808.320562 2 18485.4034 17.39397107 11 4 7 104873877.7 11829.26076 3 2889479.153575.853324 12 5 7 80960904.97 8179.21937 0 265785.1 2353.763007 19 9 10 211936878.37864.421151 0 0 0 155 2 153 16801424.879419.724086 44 41872.93951 6178.329298 28 8 20 4005009.4242613.052703 36 175623.3605 1303.472471 27 9 18 4106427.556962.480421 4 1046704.2882347.025621 58 20 38 37208518.524519.197551 2 1148.100086651.7279191 323 6 317 99524423.295964.807959

0 5894286.824420.079944 51 7 44 856519832.8 1063.841802 8 4992508.337 3766.50093 54 3 51 36114818.66593.1695576 27 1105818.5274097.304214 0 0 0 0 0 1 300.216 27.83928 3 0 3 579081.68172733.890934 1 45.558688.22424233 9 5 4 484441.27052652.262618 **DMR Facility Counts**1 19936 388 12 2 10 1397612.326 1891.085596

1 218884.82 1898.084539 3 1 2 52662.715228.195757828 9 40981.34463246.0956356 43 1 42 10436822.26 1555.930967 0 11.7 0.012987 49 1 48 20451295.3 1697.742516 7 136.35443 1062.519238 48 3 45 11673576.8581.4361552 16 16899.04192869.8050999 2 0 2 10969.23373298.0498167 0 1.482 4.46838 33 5 28 69404043.95756.2223126 0 99330 74.1664 53 8 45 68783703.06686.4242635 0 0 0 2 0 2 7018812.068517.9002151 1 2733.1905433.58020866 12 3 9 3863729.745360.0025889 0 19825.194674.98402799 5 1 4 24097.81521 249.914905 2 70441.6375686.45111028 8 0 8 50775.600043.051504149 0 0 0 87 0 87 10346303.5345.63688716 0 0 0 5 0 5 380387.7176 12.62378436 1 88022.7562 12.5288154 1 0 1 5.17447E-07 0 0 1304.02573.612719447 3 0 3 26080.357842.222387256 0 0 0 1 0 1 21973.57197 0.06279474 0 0 0 1 0 1 21973.57197 0.06279474

3918883.447 8932381.498**Total LBY Total TWPE**  **% of Total TWPE**  **Combined %**

**of Total TWPE**  **TRI % of Total**  **DMR % of**

**Total** 2,764,244,793 1,688,062 0.13 0.13 9% 91% 2,257,432,225 1,685,746 0.13 0.26 39% 61% 539,820,240 1,432,189 0.11 0.37 48% 52% 4,216,232,421 1,385,941 0.11 0.48 0.1% 99.9% 700,365,318 1,339,681 0.10 0.59 92% 8% 1,313,332,968 1,253,637 0.10 0.68 7% 93% 126,864,654 605,768 0.05 0.73 1% 99% 1,541,122,119 468,924 0.04 0.77 70% 30% 162,075,278 425,789 0.03 0.80 10% 90% 32,113,717 393,218 0.03 0.83 95% 5% 65,977,877 373,609 0.03 0.86 0% 100% 220,971,729 316,702 0.02 0.88 16% 84% 105,515,454 291,885 0.02 0.91 0% 100% 8,406,013,701 189,320 0.01 0.92 0% 100% 515,766,469 158,146 0.01 0.93 25% 75% 1,136,849,700 130,962 0.01 0.94 25% 75% 5,024,628,205 106,090 0.01 0.95 0% 100% 727,253,971 95,856 0.01 0.96 72% 28% 4,251,911,250 62,267 0.00 0.97 8% 92% 81,501,116 62,162 0.00 0.97 69% 31% 2,875,557 49,492 0.00 0.97 5% 95% 13,355,979 36,251 0.00 0.98 25% 75% 3,096,094,081 34,103 0.00 0.98 9% 91% 4,375,769 27,866 0.00 0.98 100% 0% 27,667,308 25,955 0.00 0.98 37% 63% 33,722,912 23,417 0.00 0.99 5% 95% 7,352,081 21,322 0.00 0.99 84% 16% 20,160,274 17,520 0.00 0.99 58% 42% 231,290,809 15,625 0.00 0.99 51% 49% 23,115,225 13,791 0.00 0.99 1% 99% 58,708,325 13,326 0.00 0.99 79% 21% 104,892,363 11,847 0.00 0.99 0% 100% 83,850,384 11,755 0.00 0.99 30% 70% 212,202,663 10,218 0.00 0.99 23% 77% 16,801,425 9,420 0.00 1.00 0% 100% 4,046,882 8,791 0.00 1.00 70% 30% 4,282,051 8,266 0.00 1.00 16% 84% 38,255,223 6,866 0.00 1.00 34% 66% 99,525,571 6,617 0.00 1.00 10% 90%

862,414,120 5,484 0.00 1.00 81% 19% 41,107,327 4,360 0.00 1.00 86% 14% 1,105,819 4,097 0.00 1.00 100% 0% 579,382 2,762 0.00 1.00 1% 99% 484,487 2,740 0.00 1.00 3% 97%1,417,548 2,280 0.00 1.00 17% 83% 271,548 1,906 0.00 1.00 100% 0% 10,477,804 1,802 0.00 1.00 14% 86% 20,451,307 1,698 0.00 1.00 0% 100% 11,673,713 1,644 0.00 1.00 65% 35% 27,868 1,168 0.00 1.00 74% 26% 69,404,045 760.7 0.00 1.00 1% 99% 68,883,033 760.6 0.00 1.00 10% 90% 7,018,812 518 0.00 1.00 0% 100% 3,866,463 394 0.00 1.00 9% 91% 43,923 325 0.00 1.00 23% 77% 121,217 90 0.00 1.00 97% 3% 10,346,304 46 0.00 1.00 0% 100% 380,388 13 0.00 1.00 0% 100% 88,023 13 0.00 1.00 100% 0% 27,384 6 0.00 1.00 62% 38% 21,974 0 0.00 1.00 0% 100% 21,974 0 0.00 1.00 0% 100%

12,851,265**Top Pollutants in Inorganic Manufacturing (40 CFR Part 415) from TRI2011**

11/25/2013 Table from TRI Database: TSD 02 - Top Pollutants by PSC

Note: No facility

corrections were identified for the Inorganic Chemicals Manufacturing category as part of the 2013 Annual Review.

Pollutants Reviewed as part of the 2013 ARR

**PSC Code PSC Description**  **Fac Count**  415 Inorganic chemicals manufacturing 6

415 Inorganic chemicals manufacturing 21 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 49 415 Inorganic chemicals manufacturing 13 415 Inorganic chemicals manufacturing 30 415 Inorganic chemicals manufacturing 31 415 Inorganic chemicals manufacturing 38 415 Inorganic chemicals manufacturing 6 415 Inorganic chemicals manufacturing 37 415 Inorganic chemicals manufacturing 53 415 Inorganic chemicals manufacturing 7 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 30 415 Inorganic chemicals manufacturing 16 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 19 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 3 415 Inorganic chemicals manufacturing 6 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 6 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 18 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 8 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 3 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 6 415 Inorganic chemicals manufacturing 7 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 5 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 5415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 3 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 2 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1 415 Inorganic chemicals manufacturing 1**Top Pollutants in Inorganic Manufacturing (40 CFR Part 415) from TRI2011**

Note: No facility

corrections were identified for the Inorganic Chemicals Manufacturing category as part of the 2013 Annual Review.

**CHEMICA L_NA** **ME LBY**  **TWPE % of Total**  **TWPE** DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.008259 279154 85.4%

MANGANESE AND MANGANESE COMPOUNDS 201071.1 14074.98 4.3% POLYCHLORINATED BIPHENYLS 0.20607 7013.304 2% NITRATE COMPOUNDS 6792119 5071.449 2% MERCURY AND MERCURY COMPOUNDS 36.2521 4245.483 1% CHROMIUM AND CHROMIUM COMPOUNDS 53254.93 3727.845 1% COPPER AND COPPER COMPOUNDS 4535.092 2857.108 1% ZINC AND ZINC COMPOUNDS 55323.6 2212.944 1% ARSENIC AND ARSENIC COMPOUNDS 398.5 1609.94 0% LEAD AND LEAD COMPOUNDS 711.4445 1593.636 0% AMMONIA 960606.6 1066.273 0% VANADIUM AND VANADIUM COMPOUNDS 35275.36 1058.261 0% CADMIUM AND CADMIUM COMPOUNDS 34.2 790.362 0% BERYLLIUM AND BERYLLIUM COMPOUNDS 743 780.15 0% NICKEL AND NICKEL COMPOUNDS 4257.127 425.7127 0% COBALT AND COBALT COMPOUNDS 2173.759 239.1135 0% HEXACHLOROBENZENE 0.110781 215.7696 0% CARBON DISULFIDE 55 154 0% BARIUM AND BARIUM COMPOUNDS 66300.28 131.9878 0% ACRYLONITRILE 54.75 124.2825 0% SILVER AND SILVER COMPOUNDS 5.46 89.9262 0% SODIUM NITRITE 20941.24 67.01197 0% THALLIUM AND THALLIUM COMPOUNDS 35 35.7 0% DIBUTYL PHTHALATE 2464 24.64 0% SELENIUM AND SELENIUM COMPOUNDS 14.7 16.464 0% POLYCYCLIC AROMATIC COMPOUNDS 0.152 15.30032 0% 1,4-DIOXANE 20400 12.64479 0% CYANIDE COMPOUNDS 1533.6 8.28144 0% MOLYBDENUM TRIOXIDE 10232.23 8.185784 0% HEXACHLOROETHANE 30.82 5.5476 0% METHANOL 378444.4 5.517656 0% NAPHTHALENE 453.3 4.533 0% ANTIMONY AND ANTIMONY COMPOUNDS 426.844 4.26844 0% ACETONITRILE 14042.54 2.991602 0% 1,1,1-TRICHLOROETHANE 610 2.866812 0% CERTAIN GLYCOL ETHERS 21325.76 2.274845 0% ANILINE 328.65 2.254121 0% ETHYLENE GLYCOL 1649.288 2.210596 0% NITRIC ACID 1514.2 1.130603 0% DIETHANOLAMINE 603 1.05525 0% PENTACHLOROBENZENE 0.2 0.752 0% TOLUENE 102 0.574038 0% FORMALDEHYDE 221.88 0.517125 0% 1,2,4-TRIMETHYLBENZENE 22.8 0.456 0% HYDROGEN FLUORIDE 70783.93 0.39639 0%1,2-DICHLOROETHANE 23 0.23 0%

TRICHLOROETHYLENE 22 0.22 0% PHENOL 10.5 0.21 0% FORMIC ACID 507.12 0.187893 0% DICHLOROMETHANE 181 0.183331 0% PHOSPHINE 3 0.09 0% TERT-BUTYL ALCOHOL 1910.15 0.060434 0% BENZENE 2 0.06 0% EPICHLOROHYDRIN 5.4 0.03751 0% XYLENE (MIXED ISOMERS) 3.2 0.013839 N-BUTYL ALCOHOL 108.8 0.011134 CHLOROMETHANE 2 0.010718 CHLOROETHANE 2 0.006378 N-HEXANE 0.15 0.0045 CUMENE 0.8 0.002703 2-METHOXYETHANOL 4 0.001131 PROPYLENE 0.1 7.03E-05 2-ETHOXYETHANOL 1 8.27E-06 326863.4**40 CFR Part 415 - Inorganic Chemicals**

From TRI Database: TSD 04 - Facility Discharges

Facilities Reviewed as part of the 2013 ARR

**Dioxin and Dioxin-like Compounds**

**PSC Code TRI ID**  **Facility Name City** 

415 44004SCMCH2900M MILLENNIUM INORGANIC CHEMICALS A CRISTAL CO ASHTABULA

415 37134DPNTJ1DUPO DUPONT JOHNSONVILLE PLANT NEW JOHNSONVILLE 415 70669KRNSL3300B LOUISIANA PIGMENT CO LP WESTLAKE

415 44004SCMCH2426M MILLENNIUM INORGANIC CHEMICALS A CRISTAL CO ASHTABULA 415 19809DPNTD104HA DUPONT EDGE MOOR EDGEMOOR 415 39571DPNTD7685K DUPONT DELISLE PLANT PASS CHRISTIAN

**Ma nganese and Manganese Compounds** 

**PSC Code TRI ID**  **Facility Name City** 

415 44004SCMCH2426M MILLENNIUM INORGANIC CHEMICALS A CRISTAL CO ASHTABULA 415 70734RCDNCHIGHW PCS NITROGEN FERTILIZER LP GEISMAR 415 70669KRNSL3300B LOUISIANA PIGMENT CO LP WESTLAKE

415 37134DPNTJ1DUPO DUPONT JOHNSONVILLE PLANT NEW JOHNSONVILLE

415 44004SCMCH2900M MILLENNIUM INORGANIC CHEMICALS A CRISTAL CO ASHTABULA

415 37134CHMTLFOOTE ERACHEM COMILOG NEW JOHNSONVILLE

415 21226SCMCH3901G MILLENNIUM INORGANIC CHEMICALS INC HAWKINS POINT PLANT BALTIMORE

415 21226CHMTL711PI ERACHEM COMILOG INC - BALTIM ORE PLANT BALTIMORE 415 08865JTBKR600NO MALLINCKRODT BAKER INC PHILLIPSBURG 415 45246THSHP4539D THE SHEPHERD COLOR CO CINCINNATI 415 39571DPNTD7685K DUPONT DELISLE PLANT PASS CHRISTIAN 415 19809DPNTD104HA DUPONT EDGE MOOR EDGEMOOR 415 62301PRNCMONEPR PRINCE MINERALS INC QUINCY 415 18071HRSHDDELAW HORSEHEAD CORP PALMERTON 415 40210NTDCT1227S SUD-CHEMIE INC 12TH STREET F ACILITY LOUISVILLE 415 15301DRKNFWESTW FERRO CORP WASHINGTON 415 44035NGLHR120PI BASF CORP ELYRIA

415 20705MNRLP7011M ROCKWOOD PIGMENTS NORTH AMERICA INC BELTSVILLE 415 38401CCDNTBOX59 OCCIDENTAL CHEMICAL CORP COLUMBIA 415 83276MNSNTHIGHW P4 PRODUCTION LLC SODA SPRINGS 415 44667FRRCR1560N FERRO CORP ORRVILLE

**PCB Discharges PSC Code**  **TRI ID Facility Name**  **City**

415 37134DPNTJ1DUPO DUPONT JOHNSONVILLE PLANT NEW JOHNSONVILLE 415 19809DPNTD104HA DUPONT EDGE MOOR EDGEMOOR**State Chem ID**  **Chemical LBY**  **TWPE**

OH N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.002453 273040.2

TN N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.002313 3102.609 LA N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.000136 1627.675

OH N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.000115 799.6382 DE N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.003146 492.9589 MS N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 9.57E-05 90.95447 279154

**State Chem ID**  **Chemical LBY**  **TWPE**

OH N450 MANGANESE AND MANGANESE COMPOUNDS 79000 5530 LA N450 MANGANESE AND MANGANESE COMPOUNDS 39934 2795.38 LA N450 MANGANESE AND MANGANESE COMPOUNDS 26270 1838.9

TN N450 MANGANESE AND MANGANESE COMPOUNDS 21685 1517.95

OH N450 MANGANESE AND MANGANESE COMPOUNDS 11300 791

TN N450 MANGANESE AND MANGANESE COMPOUNDS 5160 361.2

MD N450 MANGANESE AND MANGANESE COMPOUNDS 5103 357.21

MD N450 MANGANESE AND MANGANESE COMPOUNDS 4567.8 319.746 NJ N450 MANGANESE AND MANGANESE COMPOUNDS 3657 255.99 OH N450 MANGANESE AND MANGANESE COMPOUNDS 1594.2 111.594 MS N450 MANGANESE AND MANGANESE COMPOUNDS 976 68.32 DE N450 MANGANESE AND MANGANESE COMPOUNDS 958 67.06 IL N450 MANGANESE AND MANGANESE COMPOUNDS 520 36.4 PA N450 MANGANESE AND MANGANESE COMPOUNDS 244.8 17.136 KY N450 MANGANESE AND MANGANESE COMPOUNDS 57 3.99 PA N450 MANGANESE AND MANGANESE COMPOUNDS 23.12 1.6184 OH N450 MANGANESE AND MANGANESE COMPOUNDS 8 0.56

MD N450 MANGANESE AND MANGANESE COMPOUNDS 5 0.35 TN N450 MANGANESE AND MANGANESE COMPOUNDS 4.41 0.3087 ID N450 MANGANESE AND MANGANESE COMPOUNDS 2.2 0.154 OH N450 MANGANESE AND MANGANESE COMPOUNDS 1.6 0.112 14074.98**State Chem ID**  **Chemical LBY**  **TWPE**

TN 1336363 POLYCHLORINATED BIPHENYLS 0.2 6806.72 DE 1336363 POLYCHLORINATED BIPHENYLS 0.00607 206.584 7013.304**% of Total**

**TWPE**

98%

1% 1%

0% 0% 0%

**% of Total TWPE** 

39.3% 20% 13%

11%

6%

3%

3%

2% 2% 1% 0% 0% 0% 0% 0% 0% 0%

0% 0% 0%**% of Total**

**TWPE**

97% 3%**415 - Inorganic Chemicals**

**Mi llennium Inorganic Chemicals A**  **Cristal Co As** **htabula, OH** 44004SCMCH2900M (NPDES ID: OH0000523)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:**

All 2011 dioxin and dioxin-like compound discharges are below EPA's Method 1613B ML. No corrections to 2011 facility data.

**TRI Data from DMR Loading Tool** Pollutants Identified for Further Review Based on High TWPE.

**Direct TRI (lbs** 

‐**eq/yr)** Dioxin and dioxin-like compounds 273,040

Manganese and manganese compounds 791

Carbon disulfide Carbonyl sulfide Hydrochloric acid (1995 and after "acid aerosols" only) Sulfuric acid (1994 and after "acid aerosols" only) Titanium tetrachloride Toluene

**Dioxin Discharges From TRI data in the DMR Loading Tool:** 

**Reporting Year Grams**  2007 0 2008 0 2009 0.034926654 2010 0.16 2011 1.09 2012 0.14

**Dioxin Distribution from tri_data_20120823.xlsx**

**Congener Number CA** **S#** 1001746016 2040321764 3039227286 Contacted facility, contact stated that the formation of dioxin compounds occurs within an extremely narrow temperature range immediately following the chlorination process. The dioxin discharges are based on quarterly sampling at the final effluent. In 2011, the non-detect data were inadvertently reported using the minimum detection limit. For other y ears, the facility

reported non-detect data as zero. This is the cause of the increase in dioxin discharges in 2011. EPA used the 2011 flow provided by the facility

contact and the facility's TRI reported 2011 congener distribution to calculate its dioxin and dioxin-like compound discharge concentrations (see below).

**Chemical Name** Top Chemicals by

Toxic-Weighted Pounds (TWPE) **(TRI, 2011)**4057653857 5019408743 6035822469 7003268879 8051207319 9057117416 10057117314 11070648269 12057117449 13072918219 14060851345 15067562394 16055673897 17039001020

**Discharge comparison to 1613 Minimum Level**

**Congener Number CA** **SNU** 11746016 240321764 339227286 457653857 519408743 635822469 73268879 851207319 957117416 1057117314 1170648269 1257117449 1372918219 1460851345 1567562394 1655673897 1739001020

Flow from facility:Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

All 2011 dioxin and dioxin-like compound discharges are below EPA's Method 1613B ML.

**Indirect TRI (lbs** 

‐**eq/yr)**

0

0

0

0

0

0

**Pounds TWPE**  0 0 0 0 0.000077 0.76 0.00035 2,396 0.0024 273,040 0.00032

**Congener Name Unit**  2,3,7,8-Tetrachlorodibenzo- p-dioxin Grams 1,2,3,7,8-Pentachlorodibenzo- p-dioxin Grams 1,2,3,4,7,8-Hexachlorodibenzo- p-dioxin Grams Contacted facility, contact stated that the formation of dioxin compounds occurs within an extremely narrow temperature range immediately following the chlorination process. The dioxin discharges are based on quarterly sampling at the final effluent. In 2011, the non-detect data were inadvertently reported using the minimum detection limit. For other years, the facility reported non-detect data as zero. This is the cause of the increase in dioxin discharges in 2011. EPA used the 2011 flow provided by the facility

contact and the facility's TRI reported 2011 congener distribution to calculate its dioxin and dioxin-like compound discharge concentrations (see below).1,2,3,6,7,8-Hexachlorodibenzo- p-dioxin Grams

1,2,3,7,8,9-Hexachlorodibenzo- p-dioxin Grams 1,2,3,4,6,7,8-Heptachlorodibenzo- p-dioxin Grams 1,2,3,4,6,7,8,9-Octachlorodibenzo- p-dioxin Grams 2,3,7,8-Tetrachlorodibenzofuran 2,3,7,8-TCDFGrams 1,2,3,7,8-Pentachlorodibenzofuran 1,2,3,7,8-PeCDF Grams 2,3,4,7,8-Pentachlorodibenzofuran 2,3,4,7,8-PeCDF Grams 1,2,3,4,7,8-Hexachlorodibenzofuran 1,2,3,4,7,8-HxCDF Grams 1,2,3,6,7,8-Hexachlorodibenzofuran 1,2,3,6,7,8-HxCDF Grams 1,2,3,7,8,9-Hexachlorodibenzofuran 1,2,3,7,8,9-HxCDF Grams 2,3,4,6,7,8-Hexachlorodibenzofuran 2,3,4,6,7,8-HxCDF Grams 1,2,3,4,6,7,8-Heptachlorodibenzofuran 1,2,3,4,6,7,8-HpCDF Grams 1,2,3,4,7,8,9-Heptachlorodibenzofuran 1,2,3,4,7,8,9-HpCDF Grams 1,2,3,4,6,7,8,9-Octachlorodibenzofuran 1,2,3,4,6,7,8,9-OCDF Grams Grams Pounds TWF

**Congener Name Congener**  **Number** Tetrachlorodibenzo-p-dioxin, 2,3,7,8- 1 Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- 2 Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- 3 Hexachlorodibenzo-p-dioxin, 1,2,3,6,7,8- 4 Hexachlorodibenzo-p-dioxin, 1,2,3,7,8,9- 5 Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- 6 Octachlorodibenzo-p-dioxin 7 Tetrachlorodibenzofuran, 2,3,7,8- 8 Pentachlorodibenzofuran, 1,2,3,7,8- 9 Pentachlorodibenzofuran, 2,3,4,7,8- 10 Hexachlorodibenzofuran, 1,2,3,4,7,8- 11 Hexachlorodibenzofuran, 1,2,3,6,7,8- 12 Hexachlorodibenzofuran, 1,2,3,7,8,9- 13 Hexachlorodibenzofuran, 2,3,4,6,7,8- 14 Heptachlorodibenzofuran, 1,2,3,4,6,7,8- 15 Heptachlorodibenzofuran, 1,2,3,4,7,8,9- 16 Octachlorodibenzofuran 17

867.5MGY 812.7MGYIndicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

**Direct TRI Indirect TRI**  **(lbs/yr) (lbs/yr)**  Manganese and manganese compounds 11,300 0

Dioxin and dioxin-like compounds 0.0024 0

Carbon disulfide 0 Carbonyl sulfide 0 Hydrochloric acid (1995 and after "acid aerosols" only) 0

Sulfuric acid (1994 and after "acid aerosols" only) 0

Titanium tetrachloride 0 Toluene 0

**TWF**

9,870

6,845,714 113,766,667Data from facility contact (Schmude, 2014)

**Loads Facility Confirmed**  **Distribution** 0.01617 0.016 0.07804 0.078 0.07892 0.078 Contacted facility, contact stated that the formation of dioxin compounds occurs within an extremely narrow temperature range immediately following the chlorination process. The dioxin discharges are based on quarterly sampling at the final effluent. In 2011, the non-detect data were inadvertently reported using the minimum detection limit. For other years, the facility reported non-detect data as zero. This is the cause of the increase in dioxin discharges in 2011. EPA used the 2011 flow provided by the facility

contact and the facility's TRI reported 2011 congener distribution to calculate its dioxin and dioxin-like compound discharge concentrations (see below).

**Chemical Name** Top Chemicals by

Pounds **(TRI, 2011)**0.07907 0.079 0.08016 0.08 0.0804 0.0804 0.02145 0.021 0.01561 0.015 0.07804 0.078 0.07889 0.078 0.0794 0.079 0.08012 0.08 0.07895 0.078 0.07978 0.079 0.08583 0.085 0.07973 0.079 0.02228 0.022 1.11284 1.1054 0.0024534 111,290,938.49(TWPE divided by lbs - 273,040/0.0024534)

**Current TWF % discharged**  **lbs discharged grams**  **discharged** 703584000 1.453039071 3.56487E-05 0.01617 692928000 7.012688257 0.000172049 0.07804 23498240 7.091765213 0.000173989 0.07892 9556480 7.10524424 0.000174319 0.07907 10595840 7.203191834 0.000176722 0.08016 411136 7.224758276 0.000177251 0.0804 6585.6 1.927500809 4.72891E-05 0.02145 43819553.68 1.402717372 3.44141E-05 0.01561 7632640 7.012688257 0.000172049 0.07804 557312000 7.089069408 0.000173922 0.07889 5760000 7.134898099 0.000175047 0.0794 14109440 7.199597426 0.000176634 0.08012 47308800 7.094461019 0.000174055 0.07895 51204160 7.169044966 0.000175885 0.07978 85760 7.71269904 0.000189223 0.08583 3033984 7.164551957 0.000175774 0.07973 2020.96 2.002084756 4.91189E-05 0.02228 Total 100 Total lbs released 0.0024534

for 2011 for 2012**pg pg/L**  **1613 ML (pg/L)**  16170000000 4.9 10 78040000000 23.8 50 78920000000 24.0 50 79070000000 24.1 50 80160000000 24.4 50 80400000000 24.5 50 21450000000 6.5 100 15610000000 4.8 10 78040000000 23.8 50 78890000000 24.0 50 79400000000 24.2 50 80120000000 24.4 50 78950000000 24.0 50 79780000000 24.3 50 85830000000 26.1 50 79730000000 24.3 50 22280000000 6.8 100**415 - Inorganic Chemicals**

**Millennium Inorganic Chemicals A Cristal Co**  **As htabula, OH**  44004SCMCH2426M (NPDES ID: OH0000493)

**Recommendation:** Facility confirmed manganese discharges (79,000 lbs).

The facility

is one of the few remaining US facilities that manufacture titanium dioxide - discharges do not represent discharges across the category as a whole. Facility contact provided 2012 discharge quantities for comparison.

**TRI Data from DMR Loading Tool** Pollutants Identified for Further Review Based on High TWPE.

**Top Chemical Direct TRI TWPE**  **(lbs-eq/yr) Indirect** 

**TRI TWPE (lbs**  **eq/yr)** Manganese and manganese compounds 5,530.00 0

**Chemical Name Direct TRI (lbs**  **eq/year) Indirect** 

**TRI (lbs eq/year)**  Manganese and manganese compounds 5,530 0 Dioxin and dioxin-like compounds 800 0

**Dioxin Discharges From TRI data in the DMR Loading Tool:** 

**Reporting Year Grams**  **Pounds TWPE**  **TWF** 2007 16329344.74 36,000 2,520 0.07 2008 24947610.02 55,000 3,850 0.07 2009 10432636.92 23,000 1,610 0.07 2010 17236530.56 38,000 2,660 0.07 2011 35,833,839.85 79,000 5,530 0.07 2012 24250437.72 53,463 3,742 0.07 The facility

calculated manganese discharges based off of direct sampling at the NPDES compliance point (final effluent). The samples are taken once per week and they are 24 hour composite samples. The facility

contact stated that the increase in the manganese and manganese compound discharge in 2011 was due to a slight increase in flow. The increase in flow resulted from many factors such as process rate, process conditions, and volume of stormwater.The facility is one of the few remaining US facilities that manufacture titanium dioxide - discharges do not represent discharges across the category as a whole.

From facility

contact - Schmude, 2014 The facility

calculated manganese discharges based off of direct sampling at the NPDES compliance point (final effluent). The samples are taken once per week and they are 24 hour composite

The facility

contact stated that the increase in the manganese and manganese compound discharge in 2011 was due to a slight increase in flow. The increase in flow resulted from many factors such**415 - Inorganic Chemicals**

**Dupont Johnsonville Plant New Johnsonville, TN**  37134DPNTJ1DUPO (NPDES ID: TN0001465)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

**RECOMMENDA TION:** 

Discharges have doubled from 2010 to 2011.

**TRI Data from DMR Loading Tool**

**Direct TRI Indirect TRI**  **(lbs**

‐**eq/yr) (lbs** 

‐**eq/yr)** Polychlorinated biphenyls 6,807 0 Manganese and manganese compounds Dioxin and dioxin-like compounds 3,103 0 Barium and barium compounds Manganese and manganese compounds 1,518 0 Cobalt and cobalt compounds Arsenic and arsenic compounds 1,277 0 Zinc and zinc compounds Lead and lead compounds 354 0 Arsenic and arsenic compounds Cobalt and cobalt compounds 57.86 0 Chromium and chromium compounds Zinc and zinc compounds 21.04 0 Lead and lead compounds Chromium and chromium compounds 16.94 0 Polychlorinated biphenyls Barium and barium compounds 10.2 0 Pentachlorobenzene Pentachlorobenzene 0.37 0 Dioxin and dioxin-like compounds

**PCB Discharges From TRI data in the DMR Loading Tool:** 

**Reporting Year Grams**  **Pounds TWPE**  **TWF** 2007 45.35929094 0.1 3,403 34,030.000 2008 45.35929094 0.1 3,403 34,030.000 2009 0 0 0 2010 45.36 0.1 3,403 34,030.000 2011 90.72 0.2 6,807 34,035.000 Facility was contacted as part of the screening-level outlier reviews and the contact confirmed the PCB discharges. Contact stated that the PCB discharges are a result of small amounts of fine solids in the wastewater discharge resulting from the chlorination process.

**Chemical Name Chemical Name**  Top Chemicals by

Toxic-Weighted Pounds (TWPE) Top Chemicals by Pounds **(TRI, 2011) (TRI, 2011)**  Pollutants Identified for Further Review Based on High TWPE.Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

**Direct TRI Indirect TRI**  **(lbs/yr) (lbs/yr)**  21,685 0 5,158 0 526 0 526 0 316 0 242 0 158 0 0.2 0 0.1 0 0.0023 0 Facility was contacted as part of the screening-level outlier reviews and the contact confirmed the PCB discharges. Contact stated that the PCB discharges are a result of small amounts of fine solids in the wastewater discharge