### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 1 / 7 

### 1. Identification of the substance/mixture and of the company **/undertaking Product name**  **:** Benzoic acid, 4 - (1,1 - dim ethylethyl) - , hydrazide **Product code :**  10082751 **Ma nufacturer/Supplier:**  EASTMAN KODAK COMPANY and Subsidiaries **MS DS Prepared by:**  Health, Safety and Environment, Eastman Kodak Company , Rochester, NY 14652 - 6267. **For Emergency Health, Safety & Environmental Information, call:** United States: (585) 722 - 5151 **KA N Number:**  910893 **Synonyms:** Benzoic acid, 4 - (1,1 - dim ethylethyl) - ,hydrazide **Molecular Formula :**  C11H16N2O **Molecular Weight :**  192.26 g/mol **Product Use:** Film or paper manufacturing chemical 

### 2. Hazards identification **WA RNING!**  **HA RMFUL IF INHA**  **LED, ABSORBED THROUG H SKIN, OR SW** **AL LOWED**  **POSSIBLE CA NCER HA**  **ZA RD**  **- MA** 

**Y CA USE CA**  **NCER BA SED ON A**  **NIM AL** **DA TA**  **CA N CA**  **USE BLOOD DISORDERS CA**  **N CA USE LIVER A**  **ND KIDNEY DA MA** **GE CA**  **N CA USE CNS EFFECTS**  **HEA LTH HA** 

**ZA RD EVA**  **LUA TION BA** **SED ON A STRUCTURA**  **LLY SIMILA R MA** **TE RIA**  **L POWDERED M**  **AT ERI**  **AL MA**  **Y FORM EXPLOSIVE DUST -** **AIR M IXTURES**  **CA N DECOMPOSE A** 

**T ELEVA**

**TE D TEMPERA** 

**TURES THE TOXICOLOGICA** **L PROPERTIES OF THIS M AT**  **ERI AL** **H AV**  **E NOT BEEN INVESTIGA TE**  **D THE PHYSICA**  **L -**  **CHEMICA L PROPERTIES OF THIS M**  **AT ERI**  **AL H**  **AV E NOT BEEN FULLY**  **INVESTIGA**

**TE D**  **HMIS III Hazard Ratings:** Health - 2* , Flammability - 1 , Reactivity (Stability) - 1 **NFPA Hazard Ratings:**  Health - 2 , Flammability - 1 , Instability - 1 NOTE: HMIS III and NFPA 704 (2007) hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identification of the magnitude of the potential hazards. To adequately address safe handling, ALL information in this MSDS must be considered. 

### 3. Composition/information on ingredients

### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 2 / 7 **Wei ght**  **percent Components**  **- (**  **CA S**  **- No.**  **)** 100 Benzoic acid, 4 - (1,1 - dim ethylethyl) - ,hydrazide ( 43100 - 38 - 5 ) 

### 4. First aid measures **Inhalation:** If inhaled, remove to fresh air. Get medical attention. **Eyes:** In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. **Skin :**  In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention if symp toms occur. Wa sh contaminated clothing before re - use. Destroy or thoroughly clean contaminated shoes. **Ingestion :**  If swallowed, DO NOT induce vomiting. Call a physician or poison control centre immediately. Never give anything by mouth to an unconscious person. 

### 5. Fire **- fighting measures**  **Extinguishing Media :**  Water spray, Carbon dioxide (CO2), Dry chemical

. **Special Fire -**  **Fighting Procedures :**  We ar self - contained breathing apparatus and protective clothing. Fire or excessive heat may produce hazardous decomposition products. Use water spray to cool unopened containers. **Hazardous Combustion Products :**  Carbon oxides, nitrogen oxides (NOx), (see also Hazardous Decomposition Products sections.) **Unusual Fire and Explosion Hazards**  **:** Fire or high temperatures may cause decomposition. Dust may form explosive mixture in air. 

### 6. A**ccidental release measures** Shovel into suitable container for disposal. Avoid dust formation. Clean surface thoroughly to remove resid ual contamination. 

### 7. Handling and storage **Personal precautions :**  Do not breathe dust. Avoid contact with eyes, skin, and clothing. Keep container closed. Use only with adequate ventilation. Wa sh thoroughly after handling. **Prevention of Fire and Explosion :**  Keep away from heat and sources of ignition. Exercise caution if heating, especially in a closed container. Dust may form explosive mixture in air. Minimize dust generation and accumulation. Use only with adequate ventila tion. Refer to NFPA 654, "Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids." Keep from contact with oxidizing materials. **Storage :**  Keep container tightly closed. Ke ep away from incompatible substances (see Incompatibility section.)

### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 3/ 7 

### 8. Exposure controls/personal protection **Occupational exposure controls :**  Not established **Ventilation :**  Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels to an acceptable level. **Respiratory protection :**  If engineering controls do not maintain airborne concentrations to an acceptable level, an appro ved respirator must be worn. Respirator type: NIOSH - approved with an APF (assigned protection factor) of 10 (example: N95 Particulate Filter). If respirators are used, a program should be instituted to assure compliance with applicable federal, state, com mo nwealth, provincial, or local laws and regulations. **Eye protection :**  We ar safety glasses with side shields (or goggles). **Hand protection :**  We ar impervious gloves and protective clothing appropriate for the risk of exposure. 

### 9. **Physical and chemical properties Physical form**  **:** solid **Colour :**  no data available **Odour :**  no data available **Specific gravity :**  no data available **Vapour pressure :**  no data available **Vapour density :**  no data available **Volatile fraction by weight :**  no data available **Me lting point/range**  **:** 120 - 127 °C ( 248.0 - 260.6 °F ) **Water solubility :**  no data available **pH :**  no data available **Flash point :**  not applicable 

### 10. Stability

**and reactivity Stability**  **:** Not fully evaluated. Materials containing similar structural groups can decompose if heated. **Incompatibility :**  Strong oxidizing agents

. **Hazardous decomposition products :**  None under normal conditions of use. **Hazardous Polymerization :**  Hazardous poly me risation does not oc cur.

### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 4 / 7 

### 11. Toxicological information **Effects of Exposure General advice**  **:** Can cause CNS effects. Can cause kidney damage. Can cause liver damage. Can cause blood disorders. Possible cancer hazard. May cause cancer based on animal data. **Inhalation :**  Harmful if inhaled. **Eyes :**  No specific hazard known. May cause transient irritation. **Skin :**  Harmful if absorbed through skin. **Ingestion :**  Harmful if swallowed. 

### 12. Ecological information This section has not been completed. 

### 13. Disposal considerations Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local laws. Since emptied containers retain product residue, follow label warnings even after container is em ptied. **14. Transport information** For transportation information, go to: www.kodak.com/go/ship. 

### 15. Regulatory

**information Notification status**  **Regulatory List Notification status**  TSCA Not all listed DSL Not all listed NDSL None listed EINECS All listed ELINCS None listed NLP None listed AICS Not all listed IECS All listed ENCS All listed ECI Not all listed

### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 5/ 7 NZIoC Not all listed PICCS Not all listed "Not all listed" indicates one or more component is either not on the public Inventory or is subject to exemption requirements. If additional information is needed contact Kodak. **WHMIS (Canada):** D2A, D2B **WHMIS Symbol(s):**

**Other regulations** Am erican Conference of Governmental Industrial Hygienists (ACGIH): No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. International Agenc y for Research on Cancer (IARC): No component of this product present at levels greater than o r equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. U.S. National Toxicology Program (NTP): No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcin ogen by NTP. U.S. Occupational Safety and Health Administration (OSHA): No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. California Prop. 65 This product does no t contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. U.S. - CERCLA/SARA (40 CFR § 302.4 Designation of hazardous substances) : No components of this product are subject to the SARA Section 3 02 (40 CFR 302.4) reporting requirements. U.S. - CERCLA/SARA - Section 302 (40 CFR § 355 Appendices A and B - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities) : No components of this product are subject to the SARA Section 302 (40 CFR 355) reporting requirements.

### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 6/ 7 U.S. - CERCLA/SARA - Section 313 (40 CFR § 372.65 Toxic Chemical Release Reporting) : No components of this product are subject to the SARA Section 313 (40 CFR 372.65) reporting requirements. U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances : No components found on the California Director's List of Hazardous Substances. U.S. - California - 8 CCR Section 5200 - 5220 - Speci fically Regulated Carcinogens : No components found on the California Specifically Regulated Carcinogens List. U.S. - California - 8 CCR Section 5203 Carcinogens : No components found on the California Section 5203 Carcinogens List. U.S. - California - 8 CCR Section 5209 Carcinogens : No components found on the California Section 5209 Carcinogens List. U.S. - Massachusetts - General Law Chapter 111F (MGL c 111F) - Hazardous Substances Disclosure by Em ployers (a.k.a. Right to Know Law) : No components reg ulated under the Massachusetts Hazardous Substances Disclosure by Em ployers Law. U.S. - Minnesota Employee Right- to - Know (5206.0400, Subpart 5. List of Hazardous Substances) : No components found on the Minnesota Employee Right - to Know List of Hazardous Substances. U.S. - New Jersey - Wo rk er and Community Right to Know Act (N.J.S.A. 34:5A- 1) : No components regulated under the New Jersey W ork er and Community Right- to - Know Act. U.S. - Pennsylvania - Part XIII. Wo rk er and Community Right- to - Know Act (Chapters 301 - 323) : Benzoic acid, 4 - (1,1 - dim ethylethyl) - ,hydrazide U.S. - Rhode Island - Title 28 Labor and Labor Relations (Chapters 28 - 21 Hazardous Substance Right- to - Know Act) : No components regulated under the Rhode Island Hazardous Substance Right- to - Know Act. 

### 16. Other information The data below reflects current legislative requirements whereas the product in your possession may carry a different version of the label depending on the date of manufacture. **US/Canadian Label Statements: Benzoic acid, 4**  **- (1,1**  **- dimethylethyl)**  **- , hydrazide**  **WA RNING!**  **HA RMFUL IF INHA** **LED, A BSORBED THROUGH SKIN, OR SWA**  **LLOWED .**  **POSSIBLE CA**  **NCER HA**

**ZA RD**  **- MA** 

**Y CA USE CA**  **NCER BA SED ON A**  **NIM AL** **DA TA**  **. CA**  **N CA USE BLOOD**  **DISORDERS .**  **CA N CA**  **USE LIVER A ND KIDNEY DAM**  **AG E**  **. CA**  **N C AU**  **SE CNS EFFECTS .**  **HEA LTH**  **HA ZA**  **RD EVA LUA** **TION BASED ON A STRUCTURALLY SIMILA** **R M AT**  **ERIA L**  **. POWDERED**  **MA TERIA**  **L M AY** **FORM EXPLOSIVE DUS T**  **- AIR M**  **IXTURES .**  **CA N DECOMPOSE A**  **T ELEVA**

**TED TE**  **MP ERA** 

**TU RES**  **. THE TOXICOLOGICA**  **L PROPERTIES OF THIS M AT**  **ERI AL** **HA VE NOT BEEN** 

### Material Safety **Data Sheet** Revision Date: 05/04/2011 000000017207/Version: 1.1 Print Date : 05/06/2011 Page : 7/ 7 **INVESTIGA**

**TE D**  **. THE PHYSICA**  **L -**  **CHEMICA L PROPERTIES OF THIS M**  **AT ERIA**  **L HA VE NOT BEEN**  **FULLY INVESTIGA**

**TED .**  Minimize dust generation and accumulation

. Do not breathe dust. Avoid contact with eyes, skin, and clothing. Keep container closed. Use only with adequate ventilation. Wa sh thoroughly after handling. FOR R&D USE ONLY - NOT ON TSCA INVENTORY **FIRST A ID:**  If inhaled, remove to fresh air. In case of c ontact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wa sh contaminated clothing before re - use. Destroy or thoroughly clean contaminated shoes. If swallowe d, only induce vomiting as directed by me dical personnel. Never give anything by mouth to an unconscious person. Call a physician or poison control centre immediately. Keep out of reach of children. Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read and understood. Since emptied containers retain product residue, follow label warnings even after container is emptied. **IN C AS**  **E OF FIRE:** Wa ter spray , Carbon dioxide (CO2), Dry chemical

. **IN C AS**  **E OF SPILL:** Shovel into suitable container for disposal. Avoid dust formation. Clean surface thoroughly to remove residual contamination. **WHMIS (Canada):** D2A, D2B **WHMIS Symbol(s):**

Th e information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. The information relating to the working solution is for guidance purposes only, and is based on correct mixing and use of the product according to instructions. R- 3 , S - 3 , F - 1 , C - 2T CARC