# Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility Pearl Harbor, Oahu, Hawaii Latitude: 21 o 

# 22’15” N Longitude: 157 o 

# 53’33” W
HDOH Facility ID No. 9-102271 HDOH Release ID No. 99051, 010011, 020028

April 2009

Prepared by:

TEC Inc. 1001 Bishop St. Suite 1400 American Savings Bank Tower Honolulu, Hawaii 96813

Prepared for:

Commander Navy Region Hawaii Environmental Department, Code N45 850 Ticonderoga Street, Suite 110 Pearl Harbor, Hawaii 96860-5101

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## i 

# Table of Contents

Table of Contents

............................................................................................................................. i Executive Summary ......................................................................................................................... 1 1.0 Introduction .......................................................................................................................... 6 1.1 Project Objective ............................................................................................................. . 6 1.2 Previous Reports .............................................................................................................. 6 1.3 Background .................................................................................................................... .. 7 1.3.1 Site Description ......................................................................................................... 7 1.3.2 Facility Information .................................................................................................. 7 1.3.3 UST Information ....................................................................................................... 7 1.4 Previous Environmental Investigations ............................................................................ 7 1.5 Regulatory Updates .......................................................................................................... 9 2.0 Sample Collection and Analyses ........................................................................................ 11 2.1 Monitoring Well Purging ............................................................................................... 11 2.2 Groundwater Sample Collection .................................................................................... 11 2.3 Groundwater Sample Analyses ...................................................................................... 11 3.0 Groundwater Sample Analytical Results ........................................................................... 12 3.1 February 2009 Sample Analytical Results ..................................................................... 12 3.2 Groundwater Contaminant Trend ................................................................................... 14 3.3 Results of Oil/Water Interface Measurements ............................................................... 15 3.4 Groundwater Status ........................................................................................................ 15 4.0 Summary and Conclusions ................................................................................................. 18 5.0 References .......................................................................................................................... 22

List of Tables Table 1 Analytical Results for Quarterly Gr oundwater Sampling Release Response Report ..13 Table 2 Oil/Water Inte rface Measurements ..............................................................................15 Table 3 Action Levels fo r Compounds of Concern ..................................................................16 Table 4 Responses to Groundwater Monitoring Results ..........................................................16
List of Figures Figure 1 TPH Trends in Groundwat er, Round 14 (February 4, 2009) .......................................20 Figure 2 PAH Trends in Groundwat er, Round 14 (February 4, 2009) ......................................21
List of Appendices Appendix A – Laboratory Analytical Reports

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 1 

# Executive Summary This Quarterly Groundwater Monitoring Report pr esents the results of groundwater sampling conducted on February 4, 2009 at th e United States (US) Navy Bulk Fuel Storage Facility at Red Hill, Oahu, Hawaii (the Facility). The sampli ng and reporting was conducted by TEC Inc. (TEC) for the Fleet and Industrial Supply Center (FISC) at Pearl Harbor, Hawaii. Th is report is part of a series of quarterly groundwater monitoring repor ts provided by the US Navy to the State of Hawaii Department of Health (HDOH) in accordance with HDOH’s release response requirements. Currently, there are 18 active a nd 2 inactive, 12.5 million gallon, field-constructed underground storage tanks (USTs) located at the Facility.
Background In 2002, the US Navy installed a groundwater monitoring well (cur rently named RHMW01) into the basal aquifer, directly down-gradient from the Facility, within th e lower access tunnel. Groundwater samples from this well indicated that petroleum from the Facility had migrated to the basal aquifer (AMEC, 2002). In 2005, the US Navy began quarterly monitoring of the aquifer to protect their down-grad ient drinking water resource a ssociated with the US Navy Well 2254-01. The US Navy Well 2254-01 is located a pproximately 3,000 feet down-gradient from the Red Hill Fuel Storage Facility and provides approximately 24 % of th e potable water to the Pearl Harbor Water System (PHWS).
By September 2005, the US Navy had installe d two more groundwater monitoring wells (RHMW02 and RHMW03) within the Facility lower access tunnel, a background groundwater monitoring well (RHMW04) up-gradient from the Facility at ground surface adjacent to the US Navy Firing Range, and a groundwater monito ring well within th e US Navy Well 2254-01 infiltration gallery (RHMW2254-01).
All five wells were sampled twice as part of a comprehensive environmental investigation and risk assessment (TEC, 2006). For this investig ation, groundwater samples were analyzed for petroleum constituents and compared agains t HDOH Drinking Water E nvironmental Action Levels (EALs) (HDOH, July 2005). In additio n, a three-dimensional (3-D) groundwater model was developed to produce site-specific risk-based levels (SSRBLs) for compounds of concern. The results of this modeling effort indicated that Jet Propulsion (JP)–5 fuel presented the biggest risk to the US Navy water supply, due to its mobili ty and toxicity. Fina lly, the model indicated that a non-aqueous plume (free product) of JP-5 must migrate to within 1,100 feet of the US Navy Well 2254-01 infiltration gallery for HDOH EALs to be exceeded within the gallery. Based on this, free-product must be observed at RHMW01 for EALs to be exceeded at the US Navy Well 2254-01.
During the summer and fall of 2008, HDOH updated their EALs, which resulted in significant changes to the action levels associated with me thylnaphthalenes. The drinking water toxicity EAL for these compounds was each previously 240  g/L, assuming they were not carcinogens. Evidence that they are carcinogenic to humans has now been accepted by the US Environmental Protection Agency (USEPA), and HDOH adopted more rigorous EALs of 4.7  g/L for 1- methylnaphthalene and 24  g/L for 2-methylnaphthalene (HDOH, 2008).

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 2 The drinking water EAL for naphthalene was al so updated during this process. Previously, HDOH based their naphthalene EAL on USEPA Region 9 Preliminary Remediation Goal (USEPA PRG) of 6.2  g/L, which is associated with a non-cancer Hazard Index of 1. HDOH has updated their naphthalen e drinking water EAL to 17  g/L, in deference to the California Department of Public Health’s Drinking Water Notification Levels (HDOH, 2008).
Finally, the drinking water EAL for TPH-DRO was increased from 100  g/L to 210  g/L, although the gross contamination EAL for TPH-DRO remains 100  g/L.

Groundwater Protection Plan In 2008, the US Navy completed the Red Hill Bulk Fuel Storage Facility Final Groundwater Protection Plan (TEC, 2008), which specified SSRBLs fo r each well, and actions that would occur for the pertinent cases, based on cate gories for each groundwater monitoring well (Categories 1 through 4). The main object of the Plan is to protect groun dwater quality entering the US Navy Well 2254-01, which provides potable water to the PHWS. This is accomplished by comparing petroleum concentrations in the Facility wells (RHMW01, RHMW02, and RHMW03) to the SSRBLs and taking the corr esponding action. A secondary, but important objective of the Plan is to identify leaking US Ts by evaluating increasing concentration trends, or the sudden and lasting presence of free product in one or more groundwater monitoring wells. This quarterly report compares the water quality to these categor ies and recommended actions.

Current Results On February 4, 2009 four groundwater sample s were collected from RHMW01, RHMW02, RHMW03 and the US Navy Well 2254-01, along with the required quality control samples (duplicate, matrix spike, spike dup licate, trip blank). Samples we re analyzed for Total Petroleum Hydrocarbons (TPH) quantified as Diesel-Range Organics (DRO) and Gasoline Range Organics (GRO), Volatile Organic Compounds (VOCs), Po lynuclear Aromatic Hydrocarbons (PAHs), and lead.

TPH-DRO TPH-DRO was detected at 387 micrograms per liter (μg/L) in RHMW01, 2,840 μg/L (i.e., the average of normal and duplicate samples) in RHMW02, and at 207 μg/L in RHMW03. The HDOH Drinking Water EAL and SSRBL for TPH-DRO are 210 μg/L and 4,500 μg/L, respectively.

TPH-GRO For TPH-GRO the HDOH Drinking Water EAL is 100 μg/L. In samples collected at RHMW01, RHMW02, RHMW02D (i.e., the duplicate sa mple collected), RHMW03, and RHMW2254-01 estimated values (i.e., values below the labo ratory reporting limit, but above the method detection limit) were observed at the followi ng respective levels: 14.4 μg/L, 52.3 μg/L, 54.3 μg/L, 16.1 μg/L, and 14 μg/L. The estimated va lue of 14 μg/L of TPH-GRO detected at RHMW2254-01, which is well below the HDOH Dri nking Water EAL of 100 μg/L and just above the method detection limit of 10 μg/L was une xpected. Therefore, analytical results will be closely monitored during future quarterly groundwater sampling events at RHMW2254-01 to

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 3 assess whether the detection of trace quantitie s of TPH-GRO from the February 2009 sampling event represents an anomaly or an apparent analytical trend relative to RHMW2254-01.

Other Parameters At RHMW02, average concentrations betwee n the normal and duplicate samples were determined to be above the HDOH Drinking Wate r EALs as follows: na phthalene at 42.9 μg/L (HDOH EAL is 17 μg/L) and 1-methylnaphthalen e at 22 μg/L (HDOH Drinking Water EAL is 4.7 μg/L).
The average analytical values of the normal a nd duplicate samples for 2-methylnaphthalene at RHMW02 were 10.8 μg/L. This value slightly exceeds the HDOH Drinking Water Ceiling EAL for 2-methylnaphthalene of 10 μg/L.
It is noteworthy that 1-methylna phthalene, which was detected at trace quantities (i.e., estimated to be 0.03 μg/L) at RHMW2254-01 during the Oct ober 2008 sampling event, was not detected during the February 2009 sampling event.
Trend Analysis At RHMW01, concentrations of TPH-DRO have been greater than the HDOH Drinking Water EAL since September 2005, but less than 25 percent of the SSRBL of 4,500  g/L. In February 2009, TPH-DRO was lower in concentration than th e October 2008 sampling event. Prior to the October 2008 event, TPH-DRO concentrations had decreased for three consecutive sampling rounds.
At RHMW02, concentrations of TPH-DRO have been greater than the HDOH Drinking Water EAL since September 2005 and greater th an 50 percent of the SSRBL of 4,500  g/L over that same period. The average TPH-DRO concentration from the October 2008 sampling event increased to above the SSRBL (estimated solub ility limit). However, the February TPH-DRO concentration dropped below the SSRBL of 4,500  g/L (i.e., average of normal and duplicate samples of 2,840  g/L). Three parameters (i.e., napht halene, 1-methylnaphthalene, and 2- methylnaphthalene) also have exceeded EALs since September 2005. In October 2008, these parameters decreased in concen trations following increasing tren ds over three previous rounds (since January 2008). During the February 2009 sampling event, th e decrease continued as all three parameter concentrations were less than the respective October 200 8 values. There are no SSRBLs established for these parameters.
At RHMW03, concentrations of TPH-DRO have fluctuat ed around the HDOH EAL since September 2005 and are significantly lower th an corresponding values observed at RHMW01 and RHMW02. During the February 2009 sampli ng event, TPH-DRO at RHMW03 (i.e., 207  g/L) slightly decreased from the observed October value (i.e., 244  g/L) and was slightly less than the newly established HDOH Drinking Water EAL value of 210  g/L. Prior to the February 2009 event, TPH-DRO has been in creasing in concentration since April 2008.

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 4 Current Groundwater Status Based on the monitoring event that occurred in February 2009, no free product was observed at RHMW01, RHMW02, or RHMW03.
Although TPH-GRO was detected at US Navy Well 2254-01 during the February 2009 sampling event, it does not place the well in to the Category 1 status. Sin ce no contamination trend (i.e., two or more consecutive sampling rounds) ha s been observed at US Navy Well 2254-01, the well does not meet the Category 1 definition.
Category 1 Status Locations Based upon the February 2009 sampli ng event, RHMW03 is presently in Category 1 status, since the TPH-DRO value (i.e., 207  g/L) dipped slightly below the HDOH Drinking Water EAL (i.e., 210  g/L) and this represents a slight decrease in the concentration as compared with the October 2008 concentration. Catego ry 1 response for RHMW03 requires:

1. Quarterly reports to be sent to HDOH.
Category 2 Status Locations Results from the February 2009 sampling event indi cate that RHMW01 is presently in Category 2 status, since the TPH-DRO concentration of 387  g/L is greater than the HDOH Drinking Water EAL (210  g/L), but less than half the SSRBL of 4,500  g/L (estimated solubility limit of JP-5). Category 2 response at RHMW01 requires:

1. Quarterly reports to be sent to HDOH; and 2. Initiation of a leak determination progr am to identify if tanks are leaking.
Category 3 Status Locations Results from the February 2009 sampling event indi cate that RHMW02 is presently in Category 3 status (i.e., downgraded from Category 4 st atus observed during the October 2008 sampling event), since TPH-DRO [2,840  g/L and 2,840  g/L (duplicate)] is greater than the HDOH Drinking Water EAL (210  g/L), but is between one half a nd the established SSRBL value of 4,500  g/L (estimated solubility li mit of JP-5). In addition, the HDOH Drinking Water EAL of 4.7  g/L for 1-methylnaphthalene was exceeded [i.e., 21.2  g/L and 22.8  g/L (duplicate)].
Category 3 response at RHMW02 requires:

1. Send quarterly reports to HDOH; 2. Initiation of a leak determination progr am to identify if tanks are leaking; 3. Increase free product monitoring frequenc y to once per month (if concentrations increasing); 4. Notify HDOH verbally within 7 days and fo llow with written notification in 30 days; 5. Remove sampling pumps, measure product in pe rtinent wells with interface probe, reinstall pumps if product is not detected; and 6. Immediately evaluate tanks for leaks.

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 5 Conclusions and Recommendations There is no indication of an imminent threat to the US Navy Well 2254-01 wate r resources based on this report, since petroleum concentrations at RHMW01 remain less than half the SSRBLs. Additionally, based upon the February 2009 sampli ng event, the groundwater status at RHMW02 is Category 3 (i.e., downgraded from Cate gory 4 status observed during the October 2008 sampling event) since the concentration of TPH-DRO was greater than the HDOH Drinking Water EAL (210  g/L), but was between one half and the established SSRBL value of 4,500  g/L. The Groundwater Protection Plan requires specific responses to Category 3, which should be conducted.
Although 1-methylnaphthalene was de tected at trace quantities (i .e., estimated to be 0.03 μg/L) at RHMW2254-01 during the October 2008 sampling event, it was not detected during the February 2009 sampling event. An unexpected estimated valu e of 14 μg/L of TPH-GRO was detected at RHMW2254-01; however, this co ncentration is well below the HDOH Drinking Water EAL of 100 μg/L and just above the method detection limit of 10 μg/L.
The US Navy plans to install an additional mon itoring well in the Facility lower access tunnel and dedicated oil/water interface probes in four lower access tunnel wells in the coming year to better monitor contaminant migration in the basal drinking water aquifer.
Quarterly groundwater sampling for TPH-DRO, TPH-GRO, VOCs, PAHs, and lead will continue as previously scheduled until such time that new data indicates that a different schedule is warranted. It is recommended that future quar terly analytical results be closely monitored at RHMW2254-01 to assess whether the detection of trace quantities (i.e., 14  g/L) of TPH-GRO from the February 2009 sampling event represents an anomaly or an apparent analytical trend.

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 6 

# 1.0 Introduction This report presents the results of the 14 th 

## groundwater sampling and analysis event, conducted in February 2009 at the Red Hill Fuel Storage F acility, Oahu, Hawaii (hereafter referred to as “the Facility”). The Facility consists of 18 active and 2 inactive underground storage tanks (USTs) operated by the Fleet and Industrial Supply Center (FISC), Pearl Harbor. The groundwater sampling and analysis event is part of a groundwater monitoring program for the UST site in response to past UST releases, previous environmental investigations, and recommendations from the State of Ha waii Department of Health (HDOH). 

# 1.1 Project Objective This groundwater sampling and analysis project was performed to evaluate the presence of chemicals of potential concern in groundwater underlying the Facility. The project was conducted to ensure the Navy remains in co mpliance with HDOH UST release response requirements as described in Hawaii Administra tive Rules (HAR) 11-281 Subchapter 7, Release Response Action. The groundwater sampling and an alysis procedures generally followed the procedures described in Red Hill Bulk Fuel Storage Fa cility Groundwater Protection Plan [TEC Inc (TEC), 2008 also referred to as “the Plan”].
This groundwater sampling and analysis event was conducted by TEC under United States (US) Navy Contract Number N47408-04-D-8514, Task Order No. 54. 

# 1.2 Previous Reports The following groundwater monitoring reports we re previously submitted to the HDOH:

1. Groundwater Sampling Report, First Quarter 2005 (submitted April 2005); 2. Groundwater Sampling Report, Second Quarter 2005 (submitted August 2005); 3. Groundwater Sampling Report, Third Quarter 2005 (submitted November 2005); 4. Groundwater Sampling Report, Fourth Quarter 2005 (submitted February 2006); 5. Groundwater Monitoring Results, July 2006 (submitted September 2006);
6. Groundwater Monitoring Results, December 2006 (submitted January 2007); 7. Groundwater Monitoring Results, March 2007 (submitted May 2007); 8. Groundwater Monitoring Results, June 2007 (submitted August 2007); 9. Groundwater Monitoring Results, September 2007 (submitted October 2007); 10. Groundwater Monitoring Results, January 2008 (submitted March 2008); 11. Groundwater Monitoring Results, April 2008 (submitted May 2008); 12. Groundwater Monitoring Results, July 2008 (submitted October 2008); and 13. Groundwater Monitoring Results, October and December 2008 (submitted February 2009)

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 7 

# 1.3 Background The following sections provide a description of th e site and information on the Facility and USTs.

1.3.1 Site Description The Facility is located in Halawa Heights on Oahu, Hawaii. Land adjacen t to the north of the Facility is occupied by Halawa Correctional Faci lity and private businesses. Land to the south and west of the Facility includes the Coast Guar d Reservation. Moanalua Valley is located east of the Facility (Dawson, 2006).
The Navy Public Works Department operates a pot able water infiltratio n tunnel approximately 1,550 feet hydraulically down-gradient from th e Facility (Dawson, 2006). The US Navy Well 2254-01 is located approximately 3,000 feet down-grad ient (west) of the Facility and provides approximately 24% of the potable water to th e Pearl Harbor Water System, which serves approximately 52,200 military consumers (TEC, 2008).

1.3.2 Facility Information The Facility consists of 18 act ive and 2 inactive USTs operate d by Navy FISC Pearl Harbor. Each UST has a capacity of 12.5 million gallons. The Facility is located approximately 100 feet above the basal aquifer (Dawson, 2006).

1.3.3 UST Information The USTs were constructed in th e early 1940s. The tanks were c onstructed of steel and currently contain Jet Propulsion (JP)–5 fuel and F-76 (diesel marine fuel ). Previously, se veral tanks stored Navy Special Fuel Oil, Navy Distillate, aviati on gasoline, and motor gasoline. Each tank measures approximately 245 feet in height and 100 feet in diameter. The upper domes of the tanks lie at depths varying between approxima tely 100 feet and 200 feet below the existing ground surface (TEC, 2006). 

# 1.4 Previous Environmental Investigations 1998 to 2001: From 1998 to 2001, the Navy conducted an i nvestigation at the Facility to assess potential releases from the fuel storage USTs and piping systems. In February 2001, the Navy installed a one-inch diameter sentinel well RHMW01 (previously known as MW-V1D) to monitor for contamination of the basal aquifer underlying the Facility. The well was installed and completed at approximately 100 feet below grade within the underground access tunnel. At the time of well completion, depth to water in RHMW01 was measured at 86 feet below grade (Dawson, 2006).
In February 2001, groundwater samples collected from sentinel well RHMW01 contained total petroleum hydrocarbons (TPH) concentrati ons ranging from 883 micrograms per liter (  g/L) to 1,050  g/L and total lead ranging from 10.4  g/L to 15  g/L. The maximum total lead concentration in the samples was equal to the primary drinking water standard of 15  g/L for lead and exceeded the HDOH Tier 1 groundwater action level of 5.6  g/L (Dawson, 2006).

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 8 2005 – Groundwater Sampling: The Navy began quarterly groundwater sampling at existing monitoring wells in 2005. Da wson Group, Inc. collected groundw ater samples from RHMW01 and the Red Hill Navy Pump Station (US Navy We ll 2254-01) in February, June, September, and December 2005.
Samples collected in February and June 2005 were not filtered in the field prior to analysis for lead. Analytical results for samples collected from RHMW01 indicated concentrations of total lead were above the HDOH Tier 1 action level of 5.6  g/L. The results were not considered appropriate for risk assessment si nce the sample had not been filte red. In addition, lead was not a component of fuels from the tanks near RHMW01. Lead may have been part of the Facility construction material (TEC, 2007).
Samples were filtered in September and Decembe r 2005, and dissolved lead concentrations were below the HDOH Tier 1 action level. Concentra tions of all other cont aminants of potential concern were below HDOH Tier 1 action levels.
2005 – Site Investigation: As part of a site investigatio n, TEC installed three groundwater monitoring wells at the Facility between June and September 2005. Well RHMW02 was installed in the lower access tunnel near Tanks 5 and 6. Well RHMW03 was installed in the lower access tunnel near Tanks 13 and 14. Well RHMW04 was installed hydraulically upgradient of the USTs to provide geochemist ry for water moving through the basal aquifer beneath the Facility. Wells RHMW02 and RHMW03 were completed to depths of approximately 125 feet below the tunnel floor, and well RHMW04 was completed to a depth of approximately 300 feet below ground surface outsi de the tunnel. Groundwater samples were collected from the three newly installed well s and two existing wells (RHMW01 and US Navy Well 2254-01) in September 2005.
Naphthalene and trichloroethylene were dete cted in samples collected from RHMW02 at concentrations greater than the HDOH Tier 1 acti on levels. Lead was detected in the sample collected from RHMW01 at a con centration greater than the HDOH Tier 1 action level; however, the sample was not filtered in the field pr ior to analysis. Analytical results for filtered samples obtained by Dawson during the same period indicated concentrations of dissolved lead were below the HDOH Tier 1 action level.
2006 – Site Investigation: Dedicated sampling pumps were in stalled in five wells (RHMW01, RHMW02, RHMW03, RHMW04, a nd US Navy Well 2254-01). TEC collected groundwater samples from the wells in July 2006. The gr oundwater samples were analyzed for petroleum constituents. Naphthalene was detected in sa mples collected from RHMW02 at concentrations above the HDOH Tier 1 action level.
In September 2005, with concurrence from the HDOH, the Navy decided to use the newer HDOH Environmental Action Levels (EALs) for the Red Hill Site Investigation and Risk Assessment project. The EALs are current and pr ovide action levels for more chemicals, and are much more useful for conducting screening risk assessments. Since the HDOH (HDOH May 2005) Policy Letter stated that the two sets of action levels should not be mixed, the Tier 1

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 9 screening levels presented in HAR Section 11-281-78 would no longer be used to evaluate environmental impact at the Facility.
2006 – Groundwater Sampling: Groundwater samples were collected in December 2006. Analytical results indicated the following:

 No chemicals were detected in groundwat er from US Navy Well 2254-01 or RHMW03;

 TPH as diesel range organics (TPH-DRO) was detected in groundwater above the HDOH Drinking Water EALs in RHMW01; and

 TPH as gasoline range organics (TPH-GRO), TPH-DRO, and naphthale ne were detected in groundwater above the HDOH Dri nking Water EALs in RHMW02.
2007 – Groundwater Sampling: Groundwater samples were co llected in March, June, and September 2007. Analytical resu lts indicated the following:

 No chemicals were detected above HDOH Drinking Water EALs at US Navy Well 2254-01;

 TPH-DRO exceeded HDOH Drinking Water EALs at RHMW01 during all three sampling events;

 TPH-GRO exceeded HDOH Drinking Wate r EALs at RHMW02 in March;

 TPH-DRO and naphthalene exceeded HDOH Drinking Water EALs at RHMW02 during all three sampling events;

 1-methylnaphthalene and 2-methylnapht halene exceeded HDOH Drinking Water EAL for taste and odor at RHMW02 duri ng all three sampling events; and

 TPH-DRO exceeded HDOH Drinking Wate r EALs at RHMW03 in June.
2008 – Groundwater Sampling: Groundwater samples were collect ed in January, April, July, and October 2008. Analytical re sults indicated the following:

 No chemicals were detected above HDOH Drinking Water EALs at US Navy Well 2254-01;

 Trace detections of 1-methylnaphthalene and naphthalene prompted a resample event in December at US Navy Well 2254-01, no chemi cals were detected above the method detection limit (MDL);

 TPH-DRO exceeded HDOH Drinking Water EALs at RHMW01;

 TPH-GRO did not exceed HDOH Dr inking Water EALs at RHMW02;

 TPH-DRO, naphthalene, 1-me thylnaphthalene, and 2-met hylnaphthalene exceeded HDOH Drinking Water EALs at RHMW02; and

 TPH-DRO exceeded HDOH Drinking Water EALs at RHMW03 in October.


# 1.5 Regulatory Updates During the summer and fall of 2008, HDOH updated their EALs, which resulted in significant changes to the action levels associated with me thylnaphthalenes. The drinking water toxicity EAL for these compounds was previously 240  g/L, assuming they were not carcinogens. Evidence that they are carcinogenic to humans has now been accepted by the US Environmental Protection Agency (USEPA), and HDOH adopted more rigorous EALs of 4.7  g/L for 1-

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 10 methylnaphthalene and 24  g/L for 2-methylnaphthalene, corre sponding to a residential tap water scenario, and a 1 in a m illion cancer risk (HDOH, 2008).
The drinking water EAL for naphthalene has also been updated during this process. Previously, HDOH based their naphthalene EAL on USEPA Region 9 Preliminary Remediation Goal (USEPA PRG) of 6.2  g/L, which is associated with a non-cancer Hazard Index of 1. HDOH has updated their naphthalen e drinking water EAL to 17  g/L, in deference to the California Department of Public Health’s Drinking Wate r Notification Levels, a Hazard Index of 2.7 (HDOH, 2008).
Finally, the drinking water EAL for TPH-DRO was increased from 100  g/L to 210  g/L, although the gross contamination EAL for TPH-DRO remains 100  g/L.

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 11 

# 2.0 Sample Collection and Analyses Field activities relating to gr oundwater sample collection were conducted on February 4, 2009. Groundwater samples were collected from three monitoring wells located inside the Facility lower access tunnel and one mon itoring well located at the Red Hill Navy Pump Station. Sampling and analysis were conducted according to Red Hill Bulk Fuel Storage Facility Groundwater Protection Plan (TEC, 2009). A total of seven samples were collected; one normal environmental sample from monitoring we lls US Navy Well 2254-01, RHMW01, RHMW02 and RHMW03, one duplicate sample from RHMW02 (Sampled as RHMWA01 and reported as RHMW02D), and one matrix spike and matrix spike duplicate from US Navy Well 2254-01. 

# 2.1 Monitoring Well Purging The groundwater monitoring wells were purged a nd sampled using a dedicated pump system. Well purging was considered complete when no less than three successive water quality parameter measurements had stabilized within ap proximately 10 percent. Field parameters were measured at regular intervals during well pur ging and included pH, temperature, specific conductivity, dissolved oxyge n, and turbidity. Purge water was di sposed in the Facility oil/water separator system. 

# 2.2 Groundwater Sample Collection Each monitoring well was sampled immediatel y following purging. All wells were sampled directly from their dedicated bladder pump system. Samples were placed into sampling containers with appropriate pr eservatives [i.e., hydrochloric ac id (HCl) for volatile organic analysis, nitric acid (HNO 3 

## ) for dissolved lead]. Dissolved lead samples were filtered in the field and placed in preserved bottles. Sample cont ainers were labeled with the date, sample identification number, type of analysis, and samp ler’s name. The containers were placed on ice in sample coolers and transporte d under chain-of-custody procedur es to the certified laboratory for analysis. 

# 2.3 Groundwater Sample Analyses Groundwater samples were analyzed by SGS Environm ental Service, Inc. in Anchorage, Alaska for TPH-DRO and TPH-GRO by EPA Method 8015B, VOCs by EPA Method 8260B, polynuclear aromatic hydrocarbons (PAHs) by EP A Method 8270C SIM, and dissolved lead by EPA Method 6020.

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 12 

# 3.0 Groundwater Sample Analytical Results This section provides a summary of analytical results for groundwater samples collected from three monitoring wells located in the lower access tunnel of the F acility and one monitoring well located at the Red Hill Navy Pump Station. Duplicate sample results from monitoring wells RHMW02 are reported in this document as RHMW 02D. A summary of groundwater analytical results is included in Table 1. Complete analytical laboratory reports are provi ded in Appendix A. 

# 3.1 February 2009 Sample Analytical Results All groundwater samples were analyzed for TP H-DRO, TPH-GRO, VOCs, PAHs, and dissolved lead. The results for each groundwater monitoring well are discussed below.

RHMW01 TPH-DRO at 387 μg/L exceeded the HDOH Dri nking Water EAL of 210 μg/L. Trace concentrations of TPH-GRO, fluorine, and na phthalene were detected well below HDOH EALs (Table 1). All other constituents were not detected.

RHMW02 Eight petroleum constituents were detected at RHMW02: TPH-DRO, TPH-GRO, 1- methylnaphthalene, 2-methylnaphthalene, naphthal ene, acetone, benzene, and ethylbenzene. TPH-DRO was detected at RHMW02 in the normal and duplicate samples, at 2,840 μg/L. This result exceeded the HDOH EAL of 210 μg/L, but not the site-specific risk based level (SSRBL) of 4,500 μg/L. TPH-GRO was detected at an esti mated average concentration of 53.3 μg/L, well below the HDOH Drinking Water EAL of 100 μg/L.
Naphthalene was analyzed by USEPA Method 8270C SIM and USEPA Method 8260B. USEPA Method 8260B produced the highest naphthalene c oncentrations, which averaged 42.9 μg/L from the normal and duplicate sample (HDOH EAL is 17 μg/L). In addition, 1-methylnaphthalene and 2-methylnapthalene were detected by USEPA Method 8270C SIM in the normal and duplicate samples. The average result for 1-me thylnaphthalene was 22 μg/L, greater than the HDOH toxicity EAL of 4.7 μg/L. The average result for 2-me thylnaphthalene was 10.8 μg/L, less than the HDOH drinking water toxicity EAL of 24 μg/L, but slightly greater than the HDOH drinking water taste and odor EAL of 10  g/L. All other petroleum constituents, including trace concentrations of acetone, benzene, and ethyl benzene, were well below HDOH Drinking Water EALs at RHMW02 (Table 1).

RHMW03 Two constituents were detected at RHMW03: TPH-DRO and TP H-GRO (Table 1). TPH-DRO was detected at an estimated 207 μg/L, sligh tly below the HDOH Drinking Water toxicity EAL of 210 μg/L, but greater than the HDOH Drinking Water taste and odor EAL of 100 μg/L. TPHGRO was detected at an estimated 16.1 μg/L, well below the HDOH Drinking Water EALs of 100 μg/L. All other constituents were be low HDOH Drinking Water EALs at RHMW03.Table 1. Red Hill Analytical Results for QuarterlyGroundwater Monitoring Release Response Report (February 4, 2009)Result Q MDL RL Result Q MDL RL Result Q MDL RL Result Q MDL RL Result Q MDL RLTPH as DIESEL RANGE ORGANICS210 100387F 89.9 449284089.9 449284088.4 442207F 89.4 447 ND U 92 460TPH as GASOLINE RANGE ORGANICS100 100 14.4 F 10 100 52.3 F 10 100 54.3 F 10 100 16.1 F 10 100 14 F 10 1001-METHYLNAPHTHALENE4.7 10 ND U 0.0165 0.054921.20.161 0.53822.80.163 0.543 ND U 0.0161 0.0538 ND U 0.0161 0.05382-METHYLNAPHTHALENE24 10 ND U 0.0165 0.054910.50.161 0.53811.10.163 0.543 ND U 0.0161 0.0538 ND U 0.0161 0.0538ACENAPHTHENE370 20 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538ACENAPHTHYLENE240 2000 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538ANTHRACENE1800 22 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538BENZO(a)ANTHRACENE0 0924 7NDU0 0165 0 0549NDU0 161 0 538NDU0 0163 0 0543NDU0 0161 0 0538NDU0 0161 0 0538UG/LRHMW02UG/LRHMW02DUG/LRHMW03UG/LFebruary 4, 2009February 4, 2009February 4, 2009February 4, 2009HDOH ResidentialDrinking Water EALs1UG/LHDOH DrinkingWater CeilingEALs2UG/LChemicalFebruary 4, 20098015B (Petroleum)MethodRHMW01UG/LRHMW2254-01BENZO(a)ANTHRACENE0.0924.7NDU 0.01650.0549NDU 0.1610.538NDU 0.01630.0543NDU 0.01610.0538NDU 0.01610.0538BENZO(a)PYRENE0.20.81 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538BENZO(b)FLUORANTHENE0.0920.75 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538BENZO(g,h,i)PERYLENE15000.13 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538BENZO(k)FLUORANTHENE0.920.4 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538CHRYSENE9.21ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538DIBENZ(a,h)ANTHRACENE0.00920.52 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538FLUORANTHENE1500130 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538FLUORENE240950 0.0235 F 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538INDENO(1,2,3-c,d)PYRENE0.0920.095 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538NAPHTHALENE1721 0.173 0.0341 0.11 15.2 0.333 1.08 16.6 0.337 1.09 ND U 0.0333 0.108 ND U 0.0333 0.108PHENANTHRENE240410 ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.0538PYRENE18068ND U 0.0165 0.0549 ND U 0.161 0.538 ND U 0.0163 0.0543 ND U 0.0161 0.0538 ND U 0.0161 0.05381,1,1,2-TETRACHLOROETHANE0.5250000 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.51,1,1-TRICHLOROETHANE200970 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,1,2,2-TETRACHLOROETHANE0.067500 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.51,1,2-TRICHLOROETHANE550000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,1-DICHLOROETHANE2.450000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,2,3-TRICHLOROPROPANE (TCP)0.650000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,2,4-TRICHLOROBENZENE703000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,2-DIBROMO-3-CHLOROPROPANE (DBCP)0.0410ND U 0.62 2 ND U 0.62 2 ND U 0.62 2 ND U 0.62 2 ND U 0.62 21 2-DIBROMOETHANE (EDB)0 006550000NDU0 311NDU0 311NDU0 311NDU0 311NDU0 3118270C SIM(PAHs)1,2-DIBROMOETHANE(EDB)0.006550000NDU 0.311NDU 0.311NDU 0.311NDU 0.311NDU 0.3111,2-DICHLOROBENZENE60010ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,2-DICHLOROETHANE0.15700 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.51,2-DICHLOROPROPANE510ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,3-DICHLOROBENZENE18050000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 11,3-DICHLOROPROPANE0.450000 ND U 0.12 0.4 ND U 0.12 0.4 ND U 0.12 0.4 ND U 0.12 0.4 ND U 0.12 0.41,4-DICHLOROBENZENE755ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5ACETONE2200020000 ND U 3.1 10 8.51 F 3.1 10 8.59 F 3.1 10 ND U 3.1 10 ND U 3.1 10BENZENE5170 ND U 0.12 0.4 0.26 F 0.12 0.4 0.24 F 0.12 0.4 ND U 0.12 0.4 ND U 0.12 0.4BROMODICHLOROMETHANE0.2250000 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5BROMOFORM100510 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1BROMOMETHANE8.750000 ND U 0.94 3 ND U 0.94 3 ND U 0.94 3 ND U 0.94 3 ND U 0.94 3CARBON TETRACHLORIDE5520 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1CHLOROBENZENE10050ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5CHLOROETHANE860016ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1CHLOROFORM702400 ND U 0.3 1 ND U 0.3 1 ND U 0.3 1 ND U 0.3 1 ND U 0.3 1CHLOROMETHANE1.850000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1cis-1,2-DICHLOROETHYLENE7050000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1cis-1,3-DICHLOROPROPENE0.4350000 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5DIBROMOCHLOROMETHANE0.1650000 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5 ND U 0.15 0.5ETHYLBENZENE70030ND U 0.31 1 0.49 F 0.31 1 0.52 F 0.31 1 ND U 0.31 1 ND U 0.31 1HEXACHLOROBUTADIENE0.866NDU0.311NDU0.311NDU0.311NDU0.311NDU0.3118260B (VOCs)HEXACHLOROBUTADIENE0.866NDU 0.311NDU 0.311NDU 0.311NDU 0.311NDU 0.311M,P-XYLENE (SUM OF ISOMERS)1000020ND U 0.62 2 ND U 0.62 2 ND U 0.62 2 ND U 0.62 2 ND U 0.62 2METHYL ETHYL KETONE (2-BUTANONE)71008400 ND U 3.1 10 ND U 3.1 10 ND U 3.1 10 ND U 3.1 10 ND U 3.1 10METHYL ISOBUTYL KETONE (4-METHYL-2-PENTANONE)20001300 ND U 3.1 10 ND U 3.1 10 ND U 3.1 10 ND U 3.1 10 ND U 3.1 10METHYLENE CHLORIDE4.89100 ND U 1 5 ND U 1 5 ND U 1 5 ND U 1 5 ND U 1 5NAPHTHALENE1721ND U 0.62 242.80.62 2430.62 2 ND U 0.62 2 ND U 0.62 2STYRENE10010ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1TETRACHLOROETHYLENE(PCE)5170 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1TOLUENE100040ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1trans-1,2-DICHLOROETHENE100260 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1TRICHLOROETHYLENE (TCE)5310 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1VINYL CHLORIDE23400 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 16020LEAD1550000 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1 ND U 0.31 1PAHs - Polynuclear aromatic hydrocarbonsMDL - Method detection limitVOCs - Volatile organic compoundsRL - Reporting limitUG/L - Micrograms per LiterTPH - Total petroleum hydrocarbonsQ - Data qualifierND - Indicates that the compound was not detected above the stated method detection limitU - Indicates that the compound was analyzed for but notdetected at or above the stated limitNA - not analyzedF - Indicates that the compound was identified butthe concentration was above the MDL and below the RL-Result exceeds one or both HDOH EALs12Toxicity-based environmental action levels, Table D-1b,Screening For Environmental Concerns At Sites WithContaminated Soil and Groundwater,HDOH, 2008Taste, odor and solubilitythresholds, Table G-1,Screening For Environmental Concerns At Sites With Contaminated Soiland Groundwater, HDOH, 200820013

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 14 US Navy Well 2254-01 TPH-GRO was detected at US Navy Well 2254-01 at 14 μg/L estimated value (i.e., the value is below the laboratory reporting limit, but a bove the method detection limit). The HDOH Drinking Water EAL for TPH-GRO is 100 μg/L.


# 3.2 Groundwater Contaminant Trend Groundwater samples have been collected and analyzed by TEC since September 2005. Figure 1 shows TPH trends in groundwater at the Facility. Fi gure 2 shows PAH trends in groundwater at the Facility. In these figures, open icons (without fill) repres ent the method detection limit for chemicals that were not detected.

RHMW01 TPH-GRO has only previously be en detected in April 2008 at 13.6F μg/L, which is below the HDOH Drinking Water EAL of 100 μg/L. In February 2009, TPH-GRO was detected at 14.4 μg/L. TPH-DRO was detected above the HDOH Drinking Water EAL during all groundwater sampling events. The concentration of TPH-DR O observed during the February 2009 sampling event decreased after showing an increase in October 2008.

RHMW02 TPH-GRO was detected in all but one of the sampling rounds since September 2005, and exceeded the HDOH Drinking Water EAL of 100 μg/L three times during 2006 and 2007. The maximum concentration detected has been 148 μg/L.
The concentration of TPH-DRO was relatively stable at RHMW02 until July 2008, ranging from 2,250 to 2,995 μg/L. However, during the July and October 2008 sampling events, these average concentrations increased (i.e., average between the normal and duplicate samples). Specifically, the July 2008 average concentr ation was 4,055 μg/L and the Oct ober 2008 average concentration was 5,420 μg/L. Both of these values were well above the HDOH Drinking Water EAL of 210 μg/L, with the October 2008 average also exce eding the SSRBL of 4,500 μg/L. The average concentration of TPH-DRO observed during the February 2009 sampling event (i.e., 2,840 μg/L) decreased relative to the July and October 2008 sampling event concentrations to approximate levels not observed since the April 2008 sampli ng event. This decrease in the February 2009 sampling event downgraded RHMW02 to a Categor y 3 status from the previous Category 4 status that followed the Oct ober 2008 sampling event.

PAHs at RHMW02 remain above the HDOH Dr inking Water EALs for naphthalene and 1- methylnaphthalene. Concentrations decreased in the October 2008 and February 2009 sampling events after showing a sli ght increasing trend since th e April 2008 sampling event.

RHMW03 TPH-GRO has never been detect ed prior to February 2009. The February 2009 sampling event detected TPH-GRO at an estimated value of 16.1 μg/L, well below the HDOH Drinking Water EAL of 100 μg/L.

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 15 TPH-DRO had shown a slight in creasing trend peaking at 244 μg/L during the October 2008 sampling event. During the February 2009 samp ling event, TPH-DRO conc entrations decreased to 207 μg/L. Generally, the concentrations of TP H-DRO have remained relatively stable, near the DOH Drinking Water EAL of 210 μg/L. Concen trations of petroleu m-related compounds at RHMW03 have normally been the lowest of th e three wells located within the Facility. 

# 3.3 Results of Oil/Water Interface Measurements The presence and thickness of light-non aque ous phased liquids (LNAPL), otherwise known as free product, released from the USTs were meas ured during this sampling event using a 300 ft Heron Oil/Water Interface Meter. The static water levels were measured to a precision of ± 0.01 ft and fuel thickness was measured to a pr ecision of ± 0.01 ft with this equipment.
In January 2008, fuel was measured in mon itoring wells RHMW01 and RHMW02 at a thickness of < 0.01 ft, but has not been observed in othe r monitoring wells as of this document.
Measurements to determine the presence and thickness of fuel were conducted at RHMW01, RHMW02, and RHMW03 prior to the current samp ling round. At the end of February and the end of March subsequent rounds of oil/water interface measurements were conducted. In February, a measurement at RHMW01 was planne d but was not completed due to extensive work being performed by Tank 02, making RH MW01 inaccessible. No free product was observed in any of these wells before and after this event (see Table 2).

Table 2. Oil/Water In terface Measurements

Date RHMW01 RHMW02 RHMW03 SWL

(ft) LNAPL (ft) SWL (ft) LNAPL (ft) SWL (ft) LNAPL (ft) January 2008 17.74 < 0.01 18.78 < 0.01 NT NT July 2008 19.04 0.00 18.91 0.00 18.86 0.00 October 2008 18.61 0.00 18.56 0.00 18.82 0.00 November 2008 18.50 0.00 18.45 0.00 18.51 0.00 January 2009 19.28 0.00 19.22 0.00 102.04 0.00 February 2009 NT NT 18.66 0.00 18.75 0.00 March 2009 18.59 0.00 18.57 0.00 18.67 0.00

SWL Static water level, elevation above mean sea level LNAPL Light Non-Aqueous Phased Liquid, fuel product on groundwater ft Feet NT Not Taken


# 3.4 Groundwater Status Constituents of concern are defined as those petroleum-related chemicals that have been observed in the groundwater samples above the HDOH EALs. In accordance with the Red Hill Bulk Fuel Storage Facility Fi nal Groundwater Protection Plan (TEC, 2008), Table 3 defines the

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 16 constituents of concern in gr oundwater at the Facility and the SSRBLs and updated EALs for each (HDOH 2008). Table 3. Action Levels for Constituents of Concern

Chemical EAL (μg/L) SSRBL (μg/L) Petroleum Mixtures TPH-DRO 210 4,500 TPH-GRO 100 4,500 Semi-Volatile Compounds 1-Methylnaphthalene 4.7 NA 2-Methylnaphthalene 24 NA Naphthalene 17 NA NA – Not applicable or not determined SSRBLs are applicable at RHMW01, RHMW02, and RHMW03 EALs are applicable at US Navy Well 2254-01 

## In addition, the Plan defines four results categor ies of groundwater status for the Facility, based on concentrations of constituents of c oncern in RHMW01, RHMW 02, RHMW03 and the US Navy Well 2254-01, and requires sp ecific responses when these categories are observed during quarterly groundwater sampling. Table 4 describe s each of the four results categories and identifies response actions to be taken in accordance with the Plan. Table 4. Results Categories and Response Actions to Changes in Groundwater Status

Results Category RHMW02 or RHMW03 RHMW01 US Navy Pumping Well 2254-01
Results Category 1: Result above detection limit but below drinking water EAL and trend for all compounds stable or decreasing A A A,D,M,E,P

Results Category 2: Trend for any compound increasing or drinking water EAL exceeded A, B A, B A,B,C,D,E,F,G,K, L,O
Results Category 3: Result Between 1/10X SSRBL and SSRBL for benzene, or between 1/2X SSRBL and SSRBL for TPH A,B,G,H,I,J A,B,E,G,H,I,J A,B,C,D,E,F,G,I,J, K,L,O

Results Category 4: Result Exceeding any SSRBL or petroleum product observed A,C,D,E,F,I,J, K,M,N A,C,D,E,F,I, J,K,M,N,O A,C,D,E,F,G,I,J,K, L,O
Specific Responses: A. Send quarterly reports to HDOH B. Begin program to determine the source of leak C. Notify HDOH verbally within 1 day and fo llow with written notification in 30 days D. Notify FISC Chain of Command within 1 day E. Send Type 1 Report (see box below) to HDOH

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 17 F. Send Type 2 Report (see box below) to HDOH G. Increase monitoring frequency to once pe r month (if concentrations increasing) H. Notify HDOH verbally within 7 days and fo llow with written notification in 30 days I. Remove sampling pumps, measure product in pe rtinent wells with interface probe, re-install pumps if product is not detected. J. Immediately determine leaking tank K. Collect samples from nearby Halawa Deep Monitoring Well (2253-03) and OWDF MW01 L. Provide alternative water source at 2254-01 M. Prepare for alternative wa ter source at US Navy Well 2254-01 N. Re-measure for product every month with reports to HDOH O. Install additional monitoring well downgradient
Report Types HDOH Type 1 Report

 Re-evaluate Tier 3 Risk Asse ssment/groundwater model results

 Proposal to HDOH on a course of action HDOH Type 2 Report

 Proposal for groundwater treatment

In response to the previous Category 3 c onditions at RHMW02, oil/water interface measurements were collected in Octobe r 2008, November 2008, January 2009, February 2009, and March 2009 at Red Hill tunnel monitoring wells (Table 2). To date, there is no evidence of fuel on groundwater at any of these wells based on oil/water interface measurements.
Although TPH-GRO was detected at US Navy Well 2254-01 during the February 2009 sampling event, it does not place the well in to the Category 1 status. Sin ce no contamination trend (i.e., two or more consecutive sampling rounds) ha s been observed at US Navy Well 2254-01, the well does not meet the Category 1 definition.
Category 1 Status Locations Based upon the February 2009 sampli ng event, RHMW03 is presently in Category 1 status, since the TPH-DRO value (i.e., 207  g/L) dipped slightly below the HDOH EAL for drinking water (i.e., 210  g/L) and this represents a slight decrease in the concentration as compared with the October 2008 concentration. Ca tegory 1 response requires:
1. Quarterly reports to be sent to HDOH.
Category 2 Status Locations Results from the February 2009 sampling event indi cate that RHMW01 is presently in Category 2 status, since the TPH-DRO concentration of 387  g/L is greater than the HDOH EAL for drinking water (210  g/L), but less than ha lf the SSRBL of 4,500  g/L (estimated solubility limit of JP-5). Category 2 response at RHMW01 requires:

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 18 1. Quarterly reports to be sent to HDOH; and 2. Initiation of a leak determination program to identify if tanks are leaking.
Category 3 Status Locations Results from the February 2009 sampling event indi cate that RHMW02 is presently in Category 3 status (i.e., downgraded from Category 4 st atus observed during the October 2008 sampling event), since TPH-DRO [2,840  g/L and 2,840  g/L (duplicate)] is greater than the HDOH EAL for drinking water (210  g/L), but is between one half and the established SSRBL value of 4,500  g/L (estimated solubility limit of JP-5). In addition, the HDOH Drin king Water EAL of 4.7  g/L for 1-methylnaphthalene was exceeded [i.e., 21.2  g/L and 22.8  g/L (duplicate)].
Category 3 response at RHMW02 requires:

1. Send quarterly reports to HDOH; 2. Initiation of a leak determination progr am to identify if tanks are leaking; 3. Increase free product monitoring frequenc y to once per month (if concentrations increasing); 4. Notify HDOH verbally within 7 days and fo llow with written notification in 30 days; 5. Remove sampling pumps, measure product in pe rtinent wells with interface probe, reinstall pumps if product is not detected; and 6. Immediately evaluate tanks for leaks. 

# 4.0 Summary and Conclusions Summary At RHMW02, the concentration of TPH-DR O in groundwater exceeded the EAL of 210  g/L and was between one half and the established SSRBL value of 4,500  g/L, which indicates Category 3 groundwater status at RHMW02. Th is represents a downgrade from Category 4 status, which was prompted by the October 2008 sampling effort. Although 1- methylnaphthalene which was detected at RHMW2254-01 during the October 2008 sampling event, it was not detected dur ing the February 2009 sampling even t. An unexpected estimated value of 14 μg/L of TPH-GRO was detected at RHMW2254-01; however, th is concentration is well below the HDOH Drinking Water EAL of 100 μg /L and just above the method detection limit of 10 μg/L.

Conclusions

 Oil/water interface measurements were collected in October 2008, November 2008, January 2009, February 2009, and March 2009 from Red Hill tunnel monitoring wells and no free product was measured (Table 2).

 The concentration of TPH-DRO measured at RHMW01 in February 2009 was less than one tenth of the SSRBL. RHMW01 is dow n-gradient from RHMW02 and between RHMW02 and the US Navy Well 2254-01, an im portant drinking water source for the Pearl Harbor Water System.

 The US Navy Well 2254-01 is not imminently threatened at this time; however, conditions should be monitored closely to de termine if any USTs in the Facility are currently leaking fuel into the subsurface and whether or not the unexpected value at

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 19 RHMW2254-01 of 14  g/L of TPH-GRO from the February 2009 sampling event represents an anomaly or an apparent analytical trend.

 Category 4 activities should continue due to the October 2008 analytical results. These activities include:

 Re-evaluate risk assessment and groundw ater model (TEC, 2007) to ensure both are valid and protective of human health and the envi ronment under the existing conditions and provide a report describing th e results of this re-evaluation to the HDOH;

 Evaluate potential requirement for gr oundwater treatment and provide a report describing the results of this re-evaluation to the HDOH;

 Implement monthly oil/water interf ace measurements at RHMW01, RHMW02, and RHMW03, and provide monthly le tter reports of the results;

 Evaluate tanks associated with the middle section of the Facility (Tanks 5, 6, 7, 8, 9, 10, 11, 12, 13, and 14);

 Collect samples from nearby Halawa Deep Monitoring Well (2253-03) and OWDF MW01;

 Prepare for alternative water source at US Navy Well 2254-01, as necessary.
The US Navy plans to install an additional monitoring well (RHMW05) in the lower access tunnel of the Facility between RHMW01 and th e US Navy Well 2254-01 to better monitor the quality of the groundwater moving from the Facility to the US Navy Well 2254-01.
It is recommended that RHMW01, RHMW02, RH MW03, and RHMW05 (once installed) be evaluated monthly for the presence of fuel on groundwater, in accordance with the Plan. The US Navy plans to install dedicated oil/water inte rface probes in each of thes e wells to facilitate these measurements.
Quarterly groundwater sampling for TPH-DRO, TPH-GRO, VOCs, PAHs, and lead will continue as previously scheduled until such time that new data indicates that a different schedule is warranted. The quarterly collection and anal ysis of groundwater samp les will continue to monitor the quality of the groundwater located beneath the Facility. Groundwater monitoring reports will be submitted to the HDOH upon rece ipt and evaluation of laboratory analytical results. It is recommended that future quarter ly analytical results be closely monitored at RHMW2254-01 to assess whether the detection of trace quantities (i.e., 14  g/L) of TPH-GRO from the February 2009 sampling event represents an anomaly or an apparent analytical trend.Figure1TPHTrendsinGroundwaterRound14(February4,2009)RedHillFuelStorageFacilityThe HDOH toxicity EALs were updated in Fall, 2008.•TPH-DRO Residential Tap Water EAL is 210 ug/L; and•TPH-GRO Residential Tap Water EAL is 100 ug/L;(HDOH 2008)gyOahu,Hawaii(HDOH,2008).Figure2PAHTrendsinGroundwaterRound14(February4,2009)RedHillFuelStorageFacilityThe HDOH toxicity EALs were updated in Fall, 2008.• Naphthalene Residential Tap Water EAL is 17 ug/L;• 1-methylnaphthalene Residential Tap Water EAL is 4.7 ug/L; and• 2- methylnaphthalene Residential Tap Water EAL is 24 ug/L(HDOH 2008)gyOahu,Hawaii(HDOH,2008).

### Quarterly Groundwater Monitoring Report Red Hill Fuel Storage Facility April 2009

____________________________________________________________________________________________



## 22 

# 5.0 References AMEC. Red Hill Bulk Fuel Storage Facility Investigation Report , Prepared for NAVFAC Pacific, August 2002.
Dawson Group, Inc. Fourth Quarter 2005 Groundwater Sam pling Report, Red Hill Fuel Storage Facility, Hawaii. February 2006.
Hawaii Administrative Rules, Titl e 11, Chapter 281, Subchapter 7.

HDOH. Screening for Environmental Concerns at Sites with Contaminated Soil and Groundwater, Volume 1: Summary Tier 1 Lookup Tables. Interim Final. May 2005.

HDOH. Use of May 2005 Environmental Action Levels (“EALs”) at Leaking Underground Storage Tank Sites . Memo. July 2005.

HDOH. Evaluation of Environmental Hazards at Sites with Contaminated Soil and Groundwater . Summer 2008 (updated October 2008).
The Environmental Company, Inc. and AMEC. Red Hill Bulk Fuel Storage Facility Work Plan, Pearl Harbor, Hawaii. June 2005.
TEC, Inc. Red Hill Bulk Fuel Storage Facility, Fi nal – Addendum Planning Documents, Pearl Harbor, Hawaii. May 2006.
TEC, Inc. Red Hill Bulk Fuel Storage Facility, Final Technical Report, Pearl Harbor, Hawaii

. August 2007.
TEC, Inc. Red Hill Bulk Fuel Storage Facility, Final Groundwater Protection Plan, Pearl Harbor, Hawaii. January 2008.

# Appendix A Laboratory Analytical Reports

## SGS Work Order:

Contents:
Cover Page Case Narrative Final Report Pages Quality Control Summary Forms Chain of Custody/Sample Receipt Forms 

## Project: Client: 

# SGS North America Inc. Alaska Division Level II Laboratory Data Report

Released by:

Note: Unless otherwise noted, all quality assurance/quality control criteria is in compliance with the standards set forth by the proper regulatory authority, the SGS Quality Assurance Program Plan, and the National Environmental Accreditation Conference. 

## Red Hill BFSF The Environmental Company, Inc. (TEC) 1090476

# Case Narrative
THEENVC The Environmenta l Company, Inc. (TEC) 1090476 Red Hill BFSF Customer: Project: NPDL WO:



# SGS Environmental Services Inc.

Refer to the sample receipt form for information on sample condition. 

### 1090476005 PS RHMW02-WG14 8015C - DRO - The pattern is consistent with a weathered middle distillate. 8270D SIM - PQLs are elevated due to sample dilution. Sample analyzed at a dilution due to matrix interference with internal standards. 8270D SIM - Surrogate recovery for terphenyl-d14 doe snot meet QC criteria (biased high) due to sample dilution. 

### 1090476006 PS RHMWA01-WG14 8015C - DRO - The pattern is consistent with a weathered middle distillate. 

### 1090476002 BMS RHMW2254-WG14 MS 8260B - BMS recoveries for dichlorodifluoromethane, chloromethane, vinyl chloride and trans-1,2-dichloroethene do not meet QC goals (biased high). Refer to LCS for accuracy. 8260B - BMS/BMSD RPD for trans-1,2-dichloroethene does not meet QC goals (biased high). Refer to LCS/LCSD RPD for precision. 

### 1090476003 BMSD RHMW2254-WG14 MSD 8260B - BMSD recoveries for dichlorodifluoromethane, chloromethane and vinyl chloride do not meet QC goals (biased high). Refer to LCS for accuracy. 8260B - BMS/BMSD RPD for trans-1,2-dichloroethene does not meet QC goals (biased high). Refer to LCS/LCSD RPD for precision. 

### 883392 LCS V XX/19212 ] 8260B - LCS recoveries for dichlorodifluoromethane, chloromethane and vinyl chloride do not meet QC goals (biased high). These analytes were not dete cted above the PQL in the associated samples. 

### 883393 LCSD V XX/19212 8260B - LCSD recoveries for dichlorodifluoromethane, chloromethane and vinyl chloride do not meet QC goals (biased high). These analytes were not dete cted above the PQL in the associated samples. 

### 883395 CCV V MS/10380 ] 8260B - CCV recoveries for dichlorodifluoromethane, chloromethane, vinyl chloride and trichlorofluoromethane do not meet QC goals (biased high). These analytes were not detected above the PQL in the associated samples. 8260B - ICV recoveries for several analytes do not meet QC goals (biased high). These analytes were not detected above the PQL in the associated samples.

# Laboratory Analytical Report

Project: Client:

Workorder No.: The Environmental Company, Inc. (TEC)



### 1090476

Certification:
I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, other than the conditions noted on the sample data sheet(s) and/or the case narrative. This certification applies only to the tested parameters and the specific sample(s) received at the laboratory. 1001 Bishop Street Ste 1400 ASB Tower Honolulu, HI 96813
Attn: Jeff Hart T: (808)528-1445 F:(808)528-0768 jshart@tecinc.com

Tamara Rentz tamara.rentz@sgs.com Project Manager 

### Red Hill BFSF

If you have any questions regarding this report, or if we can be of further assistance, please contact your SGS Project Manager.

S G S N orth A m erica Inc. A laska D ivision 200 W est P otter D rive A nchorage A laska 99518 t ( 907 ) 562

. 2343 f ( 907 ) 561

. 5301 w w w . us. sgs.com M em ber of S G S G roupEnclosed are the analytical results associated with this workorder.
As required by the state of Alaska and the USEPA, a formal Quality Assurance/Quality Control Program is maintained by SGS. A copy of our Quality Assurance Plan (QAP), which outlines this program is available at your request.

The Laboratory certification numbers are AK971-05 (DW), UTS-005 (CS) and AK00971 (Micro) for ADEC and AK100001 for NELAP (RCRA methods: 1020A, 1311, 6010B, 7470A, 7471A, 9040B, 9045C, 9056, 9060, 8015B, 8021B, 8081A/8082, 8260B, 8270C).
Except as specifically noted, all statements and data in this report are in conformance to the provisions set forth by the SGS QAP, the National Environmental Laboratory Accreditation Program and, when applicable, other regulatory authorities.
If you have any questions regarding this report or if we can be of any assistance, please contact your SGS Project Manager at 907-562-2343. 

### All work is being provided under SGS general terms and conditions (http://www.sgs.com/terms_and_conditions.htm)
The following descriptors may be found on your report which will serve to further qualify the data.

MDL Method Detection Limit PQL Practical Quantitation Limit (reporting limit). CL Control Limit U Indicates the analyte was analyzed for but not detected. F Indicates value that is greater than or equal to the MDL. J The quantitation is an estimation. ND Indicates the analyte is not detected B Indicates the analyte is found in a blank associated with the sample.

* The analyte has exceeded allowable regulatory or control limits. D The analyte concentration is the result of dilution. GT Greater Than LT Less Than Q QC parameter out of acceptance range. M A matrix effect was present. E The analyte result is above the calibrated range. R Rejected DF Analytical Dilution Factor JL The analyte was positively identified, but the quantitation is a low estimation. <Surr> Surrogate QC spiked standard <Surr/IS> Surrogate / Internal Standard QC spiked standard QC Quality Control QA Quality Assurance MB Method Blank LCS (D) Laboratory Control Sample (Duplicate) MS(D) Matrix Spike (Duplicate) BMS(D) Site Specific Matrix Spike (Duplicate) RPD Relative Percent Difference ICV Initial Calibration Verification CCV Continuous Calibration Verification MSA Method of Standard Addition Notes: Soil samples are reported on a dry weight basis unless otherwise specified Print Date: 2/19/2009

Notes: All DRO/RRO analyses are integrated per SOP.

S G S N orth A m erica Inc. A laska D ivision 200 W est P otter D rive A nchorage A laska 99518 t ( 907 ) 562

. 2343 f ( 907 ) 561

. 5301 w w w . us. sgs.com M em ber of S G S G roup

## SAMPLE SUMMARY Client Name: The Environmental Company, Inc. (TEC) Project Name: Red Hill BFSF Workorder No.: 1090476 

## Analytical Methods

Method Description Analytical Method 8270 PAH SIM Semi-Vol GC/MS Liq/Liq ext. 8270D SIMS AFCEE 3.1 8260 (W) SW8260B Dissolved Metals by ICP-MS SW6020 DRO by 8015B (W) SW8015C GRO (W) SW8015C Print Date: 2/19/2009 10:58 am



## Sample ID Cross Reference
Client Sample ID Lab Sample ID 1090476001 RHMW2254-WG14
1090476002 RHMW2254-WG14 MS
1090476003 RHMW2254-WG14 MSD
1090476004 RHMW03-WG14
1090476005 RHMW02-WG14
1090476006 RHMWA01-WG14
1090476007 RHMW01-WG14
1090476008 TB01-WG14

S G S N orth A m erica Inc

. A laska D ivision 200 W est P otter D rive A nchorage A laska 99518 t ( 907 ) 562

. 2343 f ( 907 ) 561

. 5301 w w w . us. sgs.com M em ber of S G S G roup (S ociété G énérale de S urveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW2254-WG14 SGS Ref. #: 1090476001 Collection Date/Time: 02/04/09 09:20 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Dissolved Metals by ICP/MS

MDL DF

Lead ND 1.00 ug/L MMS5820 MXX21362 0.310 5

Batch Information Initial Prep Wt./Vol.: 50 mL Prep Extract Vol.: 50 mL Analytical Batch: MMS5820 Analytical Method: SW6020 Analysis Date/Time: 02/17/09 11:41 Prep Batch: MXX21362 Prep Method: SW3010A Prep Date/Time: 02/12/09 12:00 Container ID:1090476001-G Dilution Factor: 5 Analyst: SCL

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW2254-WG14 SGS Ref. #: 1090476001 Collection Date/Time: 02/04/09 09:20 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

MDL DF

Gasoline Range Organics 14.0 J 100 ug/L VFC9351 VXX19194 10.0 1 4-Bromofluorobenzene <surr> 85.2 50-150 % VFC9351 VXX19194 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC9351 Analytical Method: SW8015C Analysis Date/Time: 02/10/09 12:33 Prep Batch: VXX19194 Prep Method: SW5030B Prep Date/Time: 02/10/09 09:30 Container ID:1090476001-A Dilution Factor: 1 Analyst: HM

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW2254-WG14 SGS Ref. #: 1090476001 Collection Date/Time: 02/04/09 09:20 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Semivolatile Organic Fuels Department

MDL DF

Diesel Range Organics ND 0.460 mg/L XFC8449 XXX20585 0.0920 1 5a Androstane <surr> 79.6 50-150 % XFC8449 XXX20585 1

Batch Information Initial Prep Wt./Vol.: 870 mL Prep Extract Vol.: 1 mL Analytical Batch: XFC8449 Analytical Method: SW8015C Analysis Date/Time: 02/11/09 15:55 Prep Batch: XXX20585 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476001-H Dilution Factor: 1 Analyst: KDC

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW2254-WG14 SGS Ref. #: 1090476001 Collection Date/Time: 02/04/09 09:20 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF

Benzene ND 0.400 ug/L VMS10380 VXX19212 0.120 1 Toluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Ethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 n-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,4-Dichlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dichloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3,5-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 cis-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Isopropyltoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 cis-1,3-Dichloropropene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 n-Propylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Styrene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromomethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,3-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Acetone ND 10.0 ug/L VMS10380 VXX19212 3.10 1 1,1,2,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dibromo-3-chloropropane ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Methyl-t-butyl ether ND 5.00 ug/L VMS10380 VXX19212 1.50 1 Tetrachloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromochloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3-Dichloropropane ND 0.400 ug/L VMS10380 VXX19212 0.120 1 1,2-Dibromoethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Carbon tetrachloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 Chloroform ND 1.00 ug/L VMS10380 VXX19212 0.300 1 Bromobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromomethane ND 3.00 ug/L VMS10380 VXX19212 0.940 1 Bromochloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Vinyl chloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dichlorodifluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW2254-WG14 SGS Ref. #: 1090476001 Collection Date/Time: 02/04/09 09:20 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF Chloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 sec-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromodichloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,1-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Butanone (MEK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 Methylene chloride ND 5.00 ug/L VMS10380 VXX19212 1.00 1 Trichlorofluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 P & M -Xylene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Naphthalene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 o-Xylene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromoform ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1-Chlorohexane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 tert-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Trichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Hexachlorobutadiene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Isopropylbenzene (Cumene) ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,2-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,3-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloroethane-D4 <surr> 102 73-120 % VMS10380 VXX19212 1 Toluene-d8 <surr> 98 80-120 % VMS10380 VXX19212 1 4-Bromofluorobenzene <surr> 103 76-120 % VMS10380 VXX19212 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS10380 Analytical Method: SW8260B Analysis Date/Time: 02/16/09 17:18 Prep Batch: VXX19212 Prep Method: SW5030B Prep Date/Time: 02/16/09 11:48 Container ID:1090476001-D Dilution Factor: 1 Analyst: DSH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW2254-WG14 SGS Ref. #: 1090476001 Collection Date/Time: 02/04/09 09:20 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Polynuclear Aromatics GC/MS

MDL DF

Acenaphthylene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Acenaphthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Fluorene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Phenanthrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Anthracene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Fluoranthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Pyrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo(a)Anthracene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Chrysene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[b]Fluoranthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[k]fluoranthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[a]pyrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Indeno[1,2,3-c,d] pyrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Dibenzo[a,h]anthracene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[g,h,i]perylene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Naphthalene ND 0.108 ug/L XMS4825 XXX20586 0.0333 1 1-Methylnaphthalene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 2-Methylnaphthalene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Terphenyl-d14 <surr> 92.7 50-135 % XMS4825 XXX20586 1

Batch Information Initial Prep Wt./Vol.: 930 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS4825 Analytical Method: 8270D SIMS Analysis Date/Time: 02/10/09 22:34 Prep Batch: XXX20586 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476001-J Dilution Factor: 1 Analyst: JDH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW03-WG14 SGS Ref. #: 1090476004 Collection Date/Time: 02/04/09 11:10 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Dissolved Metals by ICP/MS

MDL DF

Lead ND 1.00 ug/L MMS5820 MXX21362 0.310 5

Batch Information Initial Prep Wt./Vol.: 50 mL Prep Extract Vol.: 50 mL Analytical Batch: MMS5820 Analytical Method: SW6020 Analysis Date/Time: 02/17/09 11:48 Prep Batch: MXX21362 Prep Method: SW3010A Prep Date/Time: 02/12/09 12:00 Container ID:1090476004-G Dilution Factor: 5 Analyst: SCL

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW03-WG14 SGS Ref. #: 1090476004 Collection Date/Time: 02/04/09 11:10 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

MDL DF

Gasoline Range Organics 16.1 J 100 ug/L VFC9351 VXX19194 10.0 1 4-Bromofluorobenzene <surr> 85.4 50-150 % VFC9351 VXX19194 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC9351 Analytical Method: SW8015C Analysis Date/Time: 02/10/09 13:28 Prep Batch: VXX19194 Prep Method: SW5030B Prep Date/Time: 02/10/09 09:30 Container ID:1090476004-A Dilution Factor: 1 Analyst: HM

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW03-WG14 SGS Ref. #: 1090476004 Collection Date/Time: 02/04/09 11:10 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Semivolatile Organic Fuels Department

MDL DF

Diesel Range Organics 0.207 J 0.447 mg/L XFC8449 XXX20585 0.0894 1 5a Androstane <surr> 88.9 50-150 % XFC8449 XXX20585 1

Batch Information Initial Prep Wt./Vol.: 895 mL Prep Extract Vol.: 1 mL Analytical Batch: XFC8449 Analytical Method: SW8015C Analysis Date/Time: 02/11/09 16:23 Prep Batch: XXX20585 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476004-H Dilution Factor: 1 Analyst: KDC

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW03-WG14 SGS Ref. #: 1090476004 Collection Date/Time: 02/04/09 11:10 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF

Benzene ND 0.400 ug/L VMS10380 VXX19212 0.120 1 Toluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Ethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 n-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,4-Dichlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dichloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3,5-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 cis-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Isopropyltoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 cis-1,3-Dichloropropene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 n-Propylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Styrene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromomethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,3-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Acetone ND 10.0 ug/L VMS10380 VXX19212 3.10 1 1,1,2,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dibromo-3-chloropropane ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Methyl-t-butyl ether ND 5.00 ug/L VMS10380 VXX19212 1.50 1 Tetrachloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromochloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3-Dichloropropane ND 0.400 ug/L VMS10380 VXX19212 0.120 1 1,2-Dibromoethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Carbon tetrachloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 Chloroform ND 1.00 ug/L VMS10380 VXX19212 0.300 1 Bromobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromomethane ND 3.00 ug/L VMS10380 VXX19212 0.940 1 Bromochloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Vinyl chloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dichlorodifluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW03-WG14 SGS Ref. #: 1090476004 Collection Date/Time: 02/04/09 11:10 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF Chloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 sec-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromodichloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,1-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Butanone (MEK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 Methylene chloride ND 5.00 ug/L VMS10380 VXX19212 1.00 1 Trichlorofluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 P & M -Xylene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Naphthalene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 o-Xylene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromoform ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1-Chlorohexane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 tert-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Trichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Hexachlorobutadiene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Isopropylbenzene (Cumene) ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,2-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,3-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloroethane-D4 <surr> 105 73-120 % VMS10380 VXX19212 1 Toluene-d8 <surr> 98.8 80-120 % VMS10380 VXX19212 1 4-Bromofluorobenzene <surr> 102 76-120 % VMS10380 VXX19212 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS10380 Analytical Method: SW8260B Analysis Date/Time: 02/16/09 17:52 Prep Batch: VXX19212 Prep Method: SW5030B Prep Date/Time: 02/16/09 11:48 Container ID:1090476004-D Dilution Factor: 1 Analyst: DSH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW03-WG14 SGS Ref. #: 1090476004 Collection Date/Time: 02/04/09 11:10 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Polynuclear Aromatics GC/MS

MDL DF

Acenaphthylene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Acenaphthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Fluorene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Phenanthrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Anthracene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Fluoranthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Pyrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo(a)Anthracene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Chrysene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[b]Fluoranthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[k]fluoranthene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[a]pyrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Indeno[1,2,3-c,d] pyrene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Dibenzo[a,h]anthracene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Benzo[g,h,i]perylene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Naphthalene ND 0.108 ug/L XMS4825 XXX20586 0.0333 1 1-Methylnaphthalene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 2-Methylnaphthalene ND 0.0538 ug/L XMS4825 XXX20586 0.0161 1 Terphenyl-d14 <surr> 85.2 50-135 % XMS4825 XXX20586 1

Batch Information Initial Prep Wt./Vol.: 930 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS4825 Analytical Method: 8270D SIMS Analysis Date/Time: 02/11/09 00:11 Prep Batch: XXX20586 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476004-J Dilution Factor: 1 Analyst: JDH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW02-WG14 SGS Ref. #: 1090476005 Collection Date/Time: 02/04/09 12:40 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Dissolved Metals by ICP/MS

MDL DF

Lead ND 1.00 ug/L MMS5820 MXX21362 0.310 5

Batch Information Initial Prep Wt./Vol.: 50 mL Prep Extract Vol.: 50 mL Analytical Batch: MMS5820 Analytical Method: SW6020 Analysis Date/Time: 02/17/09 11:50 Prep Batch: MXX21362 Prep Method: SW3010A Prep Date/Time: 02/12/09 12:00 Container ID:1090476005-G Dilution Factor: 5 Analyst: SCL

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW02-WG14 SGS Ref. #: 1090476005 Collection Date/Time: 02/04/09 12:40 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

MDL DF

Gasoline Range Organics 52.3 J 100 ug/L VFC9351 VXX19194 10.0 1 4-Bromofluorobenzene <surr> 116 50-150 % VFC9351 VXX19194 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC9351 Analytical Method: SW8015C Analysis Date/Time: 02/10/09 13:46 Prep Batch: VXX19194 Prep Method: SW5030B Prep Date/Time: 02/10/09 09:30 Container ID:1090476005-A Dilution Factor: 1 Analyst: HM

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW02-WG14 SGS Ref. #: 1090476005 Collection Date/Time: 02/04/09 12:40 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Semivolatile Organic Fuels Department

MDL DF

Diesel Range Organics 2.84 0.449 mg/L XFC8449 XXX20585 0.0899 1 5a Androstane <surr> 69.3 50-150 % XFC8449 XXX20585 1

Batch Information Initial Prep Wt./Vol.: 890 mL Prep Extract Vol.: 1 mL Analytical Batch: XFC8449 Analytical Method: SW8015C Analysis Date/Time: 02/11/09 16:32 Prep Batch: XXX20585 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476005-H Dilution Factor: 1 Analyst: KDC

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW02-WG14 SGS Ref. #: 1090476005 Collection Date/Time: 02/04/09 12:40 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF

Benzene 0.260 J 0.400 ug/L VMS10380 VXX19212 0.120 1 Toluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Ethylbenzene 0.490 J 1.00 ug/L VMS10380 VXX19212 0.310 1 n-Butylbenzene 2.37 1.00 ug/L VMS10380 VXX19212 0.310 1 1,4-Dichlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dichloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3,5-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 cis-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Isopropyltoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 cis-1,3-Dichloropropene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 n-Propylbenzene 8.60 1.00 ug/L VMS10380 VXX19212 0.310 1 Styrene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromomethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,3-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Acetone 8.51 J 10.0 ug/L VMS10380 VXX19212 3.10 1 1,1,2,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dibromo-3-chloropropane ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Methyl-t-butyl ether ND 5.00 ug/L VMS10380 VXX19212 1.50 1 Tetrachloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromochloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3-Dichloropropane ND 0.400 ug/L VMS10380 VXX19212 0.120 1 1,2-Dibromoethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Carbon tetrachloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 Chloroform ND 1.00 ug/L VMS10380 VXX19212 0.300 1 Bromobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromomethane ND 3.00 ug/L VMS10380 VXX19212 0.940 1 Bromochloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Vinyl chloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dichlorodifluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW02-WG14 SGS Ref. #: 1090476005 Collection Date/Time: 02/04/09 12:40 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF Chloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 sec-Butylbenzene 7.67 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromodichloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,1-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Butanone (MEK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 Methylene chloride ND 5.00 ug/L VMS10380 VXX19212 1.00 1 Trichlorofluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 P & M -Xylene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Naphthalene 42.8 2.00 ug/L VMS10380 VXX19212 0.620 1 o-Xylene 0.400 J 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromoform ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1-Chlorohexane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 tert-Butylbenzene 1.19 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Trichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Hexachlorobutadiene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Isopropylbenzene (Cumene) 6.48 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,2-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,3-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloroethane-D4 <surr> 104 73-120 % VMS10380 VXX19212 1 Toluene-d8 <surr> 98.4 80-120 % VMS10380 VXX19212 1 4-Bromofluorobenzene <surr> 101 76-120 % VMS10380 VXX19212 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS10380 Analytical Method: SW8260B Analysis Date/Time: 02/16/09 18:26 Prep Batch: VXX19212 Prep Method: SW5030B Prep Date/Time: 02/16/09 11:48 Container ID:1090476005-D Dilution Factor: 1 Analyst: DSH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW02-WG14 SGS Ref. #: 1090476005 Collection Date/Time: 02/04/09 12:40 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Polynuclear Aromatics GC/MS

MDL DF

Acenaphthylene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Acenaphthene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Fluorene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Phenanthrene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Anthracene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Fluoranthene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Pyrene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Benzo(a)Anthracene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Chrysene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Benzo[b]Fluoranthene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Benzo[k]fluoranthene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Benzo[a]pyrene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Indeno[1,2,3-c,d] pyrene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Dibenzo[a,h]anthracene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Benzo[g,h,i]perylene ND 0.538 ug/L XMS4828 XXX20586 0.161 10 Naphthalene 15.2 1.08 ug/L XMS4828 XXX20586 0.333 10 1-Methylnaphthalene 21.2 0.538 ug/L XMS4828 XXX20586 0.161 10 2-Methylnaphthalene 10.5 0.538 ug/L XMS4828 XXX20586 0.161 10 Terphenyl-d14 <surr> 162 50-135 % XMS4828 XXX20586 10 

### *

Batch Information Initial Prep Wt./Vol.: 930 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS4828 Analytical Method: 8270D SIMS Analysis Date/Time: 02/12/09 19:57 Prep Batch: XXX20586 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476005-I Dilution Factor: 10 Analyst: JDH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMWA01-WG14 SGS Ref. #: 1090476006 Collection Date/Time: 02/04/09 12:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Dissolved Metals by ICP/MS

MDL DF

Lead ND 1.00 ug/L MMS5820 MXX21362 0.310 5

Batch Information Initial Prep Wt./Vol.: 50 mL Prep Extract Vol.: 50 mL Analytical Batch: MMS5820 Analytical Method: SW6020 Analysis Date/Time: 02/17/09 11:52 Prep Batch: MXX21362 Prep Method: SW3010A Prep Date/Time: 02/12/09 12:00 Container ID:1090476006-G Dilution Factor: 5 Analyst: SCL

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMWA01-WG14 SGS Ref. #: 1090476006 Collection Date/Time: 02/04/09 12:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

MDL DF

Gasoline Range Organics 54.3 J 100 ug/L VFC9351 VXX19194 10.0 1 4-Bromofluorobenzene <surr> 116 50-150 % VFC9351 VXX19194 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC9351 Analytical Method: SW8015C Analysis Date/Time: 02/10/09 14:05 Prep Batch: VXX19194 Prep Method: SW5030B Prep Date/Time: 02/10/09 09:30 Container ID:1090476006-A Dilution Factor: 1 Analyst: HM

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMWA01-WG14 SGS Ref. #: 1090476006 Collection Date/Time: 02/04/09 12:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Semivolatile Organic Fuels Department

MDL DF

Diesel Range Organics 2.84 0.442 mg/L XFC8449 XXX20585 0.0884 1 5a Androstane <surr> 73 50-150 % XFC8449 XXX20585 1

Batch Information Initial Prep Wt./Vol.: 905 mL Prep Extract Vol.: 1 mL Analytical Batch: XFC8449 Analytical Method: SW8015C Analysis Date/Time: 02/11/09 16:42 Prep Batch: XXX20585 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476006-H Dilution Factor: 1 Analyst: KDC

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMWA01-WG14 SGS Ref. #: 1090476006 Collection Date/Time: 02/04/09 12:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF

Benzene 0.240 J 0.400 ug/L VMS10380 VXX19212 0.120 1 Toluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Ethylbenzene 0.520 J 1.00 ug/L VMS10380 VXX19212 0.310 1 n-Butylbenzene 2.46 1.00 ug/L VMS10380 VXX19212 0.310 1 1,4-Dichlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dichloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3,5-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 cis-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Isopropyltoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 cis-1,3-Dichloropropene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 n-Propylbenzene 9.00 1.00 ug/L VMS10380 VXX19212 0.310 1 Styrene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromomethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,3-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Acetone 8.59 J 10.0 ug/L VMS10380 VXX19212 3.10 1 1,1,2,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dibromo-3-chloropropane ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Methyl-t-butyl ether ND 5.00 ug/L VMS10380 VXX19212 1.50 1 Tetrachloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromochloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3-Dichloropropane ND 0.400 ug/L VMS10380 VXX19212 0.120 1 1,2-Dibromoethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Carbon tetrachloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 Chloroform ND 1.00 ug/L VMS10380 VXX19212 0.300 1 Bromobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromomethane ND 3.00 ug/L VMS10380 VXX19212 0.940 1 Bromochloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Vinyl chloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dichlorodifluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMWA01-WG14 SGS Ref. #: 1090476006 Collection Date/Time: 02/04/09 12:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF Chloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 sec-Butylbenzene 7.81 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromodichloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,1-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Butanone (MEK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 Methylene chloride ND 5.00 ug/L VMS10380 VXX19212 1.00 1 Trichlorofluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 P & M -Xylene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Naphthalene 43.0 2.00 ug/L VMS10380 VXX19212 0.620 1 o-Xylene 0.470 J 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromoform ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1-Chlorohexane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 tert-Butylbenzene 1.14 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Trichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Hexachlorobutadiene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Isopropylbenzene (Cumene) 6.88 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,2-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,3-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloroethane-D4 <surr> 99.7 73-120 % VMS10380 VXX19212 1 Toluene-d8 <surr> 99.8 80-120 % VMS10380 VXX19212 1 4-Bromofluorobenzene <surr> 99.5 76-120 % VMS10380 VXX19212 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS10380 Analytical Method: SW8260B Analysis Date/Time: 02/16/09 18:59 Prep Batch: VXX19212 Prep Method: SW5030B Prep Date/Time: 02/16/09 11:48 Container ID:1090476006-D Dilution Factor: 1 Analyst: DSH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMWA01-WG14 SGS Ref. #: 1090476006 Collection Date/Time: 02/04/09 12:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Polynuclear Aromatics GC/MS

MDL DF

Acenaphthylene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Acenaphthene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Fluorene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Phenanthrene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Anthracene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Fluoranthene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Pyrene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Benzo(a)Anthracene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Chrysene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Benzo[b]Fluoranthene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Benzo[k]fluoranthene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Benzo[a]pyrene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Indeno[1,2,3-c,d] pyrene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Dibenzo[a,h]anthracene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Benzo[g,h,i]perylene ND 0.0543 ug/L XMS4825 XXX20586 0.0163 1 Naphthalene 16.6 1.09 ug/L XMS4828 XXX20586 0.337 10 1-Methylnaphthalene 22.8 0.543 ug/L XMS4828 XXX20586 0.163 10 2-Methylnaphthalene 11.1 0.543 ug/L XMS4828 XXX20586 0.163 10 Terphenyl-d14 <surr> 87.2 50-135 % XMS4825 XXX20586 1

Batch Information Initial Prep Wt./Vol.: 920 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS4825 Analytical Method: 8270D SIMS Analysis Date/Time: 02/11/09 01:16 Prep Batch: XXX20586 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476006-I Dilution Factor: 1 Analyst: JDH Initial Prep Wt./Vol.: 920 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS4828 Analytical Method: 8270D SIMS Analysis Date/Time: 02/12/09 20:29 Prep Batch: XXX20586 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476006-I Dilution Factor: 10 Analyst: JDH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW01-WG14 SGS Ref. #: 1090476007 Collection Date/Time: 02/04/09 14:55 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Dissolved Metals by ICP/MS

MDL DF

Lead ND 1.00 ug/L MMS5820 MXX21362 0.310 5

Batch Information Initial Prep Wt./Vol.: 50 mL Prep Extract Vol.: 50 mL Analytical Batch: MMS5820 Analytical Method: SW6020 Analysis Date/Time: 02/17/09 11:54 Prep Batch: MXX21362 Prep Method: SW3010A Prep Date/Time: 02/12/09 12:00 Container ID:1090476007-E Dilution Factor: 5 Analyst: SCL

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW01-WG14 SGS Ref. #: 1090476007 Collection Date/Time: 02/04/09 14:55 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

MDL DF

Gasoline Range Organics 14.4 J 100 ug/L VFC9351 VXX19194 10.0 1 4-Bromofluorobenzene <surr> 85.5 50-150 % VFC9351 VXX19194 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC9351 Analytical Method: SW8015C Analysis Date/Time: 02/10/09 14:23 Prep Batch: VXX19194 Prep Method: SW5030B Prep Date/Time: 02/10/09 09:30 Container ID:1090476007-A Dilution Factor: 1 Analyst: HM

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW01-WG14 SGS Ref. #: 1090476007 Collection Date/Time: 02/04/09 14:55 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Semivolatile Organic Fuels Department

MDL DF

Diesel Range Organics 0.387 J 0.449 mg/L XFC8449 XXX20585 0.0899 1 5a Androstane <surr> 77.9 50-150 % XFC8449 XXX20585 1

Batch Information Initial Prep Wt./Vol.: 890 mL Prep Extract Vol.: 1 mL Analytical Batch: XFC8449 Analytical Method: SW8015C Analysis Date/Time: 02/11/09 16:51 Prep Batch: XXX20585 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476007-F Dilution Factor: 1 Analyst: KDC

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW01-WG14 SGS Ref. #: 1090476007 Collection Date/Time: 02/04/09 14:55 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF

Benzene ND 0.400 ug/L VMS10380 VXX19212 0.120 1 Toluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Ethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 n-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,4-Dichlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dichloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3,5-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 cis-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Isopropyltoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 cis-1,3-Dichloropropene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 n-Propylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Styrene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromomethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,3-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Acetone ND 10.0 ug/L VMS10380 VXX19212 3.10 1 1,1,2,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dibromo-3-chloropropane ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Methyl-t-butyl ether ND 5.00 ug/L VMS10380 VXX19212 1.50 1 Tetrachloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromochloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3-Dichloropropane ND 0.400 ug/L VMS10380 VXX19212 0.120 1 1,2-Dibromoethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Carbon tetrachloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 Chloroform ND 1.00 ug/L VMS10380 VXX19212 0.300 1 Bromobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromomethane ND 3.00 ug/L VMS10380 VXX19212 0.940 1 Bromochloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Vinyl chloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dichlorodifluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW01-WG14 SGS Ref. #: 1090476007 Collection Date/Time: 02/04/09 14:55 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF Chloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 sec-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromodichloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,1-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Butanone (MEK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 Methylene chloride ND 5.00 ug/L VMS10380 VXX19212 1.00 1 Trichlorofluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 P & M -Xylene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Naphthalene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 o-Xylene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromoform ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1-Chlorohexane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 tert-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Trichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Hexachlorobutadiene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Isopropylbenzene (Cumene) ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,2-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,3-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloroethane-D4 <surr> 102 73-120 % VMS10380 VXX19212 1 Toluene-d8 <surr> 99.1 80-120 % VMS10380 VXX19212 1 4-Bromofluorobenzene <surr> 100 76-120 % VMS10380 VXX19212 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS10380 Analytical Method: SW8260B Analysis Date/Time: 02/16/09 19:33 Prep Batch: VXX19212 Prep Method: SW5030B Prep Date/Time: 02/16/09 11:48 Container ID:1090476007-C Dilution Factor: 1 Analyst: DSH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### RHMW01-WG14 SGS Ref. #: 1090476007 Collection Date/Time: 02/04/09 14:55 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Polynuclear Aromatics GC/MS

MDL DF

Acenaphthylene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Acenaphthene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Fluorene 0.0235 J 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Phenanthrene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Anthracene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Fluoranthene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Pyrene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Benzo(a)Anthracene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Chrysene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Benzo[b]Fluoranthene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Benzo[k]fluoranthene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Benzo[a]pyrene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Indeno[1,2,3-c,d] pyrene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Dibenzo[a,h]anthracene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Benzo[g,h,i]perylene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Naphthalene 0.173 0.110 ug/L XMS4825 XXX20586 0.0341 1 1-Methylnaphthalene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 2-Methylnaphthalene ND 0.0549 ug/L XMS4825 XXX20586 0.0165 1 Terphenyl-d14 <surr> 86.2 50-135 % XMS4825 XXX20586 1

Batch Information Initial Prep Wt./Vol.: 910 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS4825 Analytical Method: 8270D SIMS Analysis Date/Time: 02/11/09 01:48 Prep Batch: XXX20586 Prep Method: SW3520C Prep Date/Time: 02/10/09 10:50 Container ID:1090476007-H Dilution Factor: 1 Analyst: JDH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### TB01-WG14 SGS Ref. #: 1090476008 Collection Date/Time: 02/04/09 08:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF

Benzene ND 0.400 ug/L VMS10380 VXX19212 0.120 1 Toluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Ethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 n-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,4-Dichlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dichloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3,5-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chlorobenzene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 cis-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 4-Isopropyltoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 cis-1,3-Dichloropropene ND 0.500 ug/L VMS10380 VXX19212 0.150 1 n-Propylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Styrene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromomethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,3-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Acetone ND 10.0 ug/L VMS10380 VXX19212 3.10 1 1,1,2,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,2-Dibromo-3-chloropropane ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Methyl-t-butyl ether ND 5.00 ug/L VMS10380 VXX19212 1.50 1 Tetrachloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dibromochloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,3-Dichloropropane ND 0.400 ug/L VMS10380 VXX19212 0.120 1 1,2-Dibromoethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Carbon tetrachloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1,2-Tetrachloroethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 Chloroform ND 1.00 ug/L VMS10380 VXX19212 0.300 1 Bromobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Chloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromomethane ND 3.00 ug/L VMS10380 VXX19212 0.940 1 Bromochloromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Vinyl chloride ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Dichlorodifluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)

### The Environmental Company, Inc. (TEC) Print Date: 2/19/2009 10:58 am

Client Sample ID: 

### TB01-WG14 SGS Ref. #: 1090476008 Collection Date/Time: 02/04/09 08:05 Receipt Date/Time: 02/06/09 11:00 Project ID: Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch PQL/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

MDL DF Chloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 sec-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromodichloromethane ND 0.500 ug/L VMS10380 VXX19212 0.150 1 1,1-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Butanone (MEK) ND 10.0 ug/L VMS10380 VXX19212 3.10 1 Methylene chloride ND 5.00 ug/L VMS10380 VXX19212 1.00 1 Trichlorofluoromethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 P & M -Xylene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 Naphthalene ND 2.00 ug/L VMS10380 VXX19212 0.620 1 o-Xylene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Bromoform ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1-Chlorohexane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,4-Trimethylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 tert-Butylbenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,1-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2-Chlorotoluene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Trichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 trans-1,2-Dichloroethene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 2,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Hexachlorobutadiene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 Isopropylbenzene (Cumene) ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloropropane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1-Dichloropropene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,1,2-Trichloroethane ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,3-Dichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2,3-Trichlorobenzene ND 1.00 ug/L VMS10380 VXX19212 0.310 1 1,2-Dichloroethane-D4 <surr> 101 73-120 % VMS10380 VXX19212 1 Toluene-d8 <surr> 102 80-120 % VMS10380 VXX19212 1 4-Bromofluorobenzene <surr> 98.9 76-120 % VMS10380 VXX19212 1

Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS10380 Analytical Method: SW8260B Analysis Date/Time: 02/16/09 16:45 Prep Batch: VXX19212 Prep Method: SW5030B Prep Date/Time: 02/16/09 11:48 Container ID:1090476008-A Dilution Factor: 1 Analyst: DSH

SGS North America Inc. Alaska Division 200 West Potter Drive Anchorage Alaska 99518 t ( 907 ) 562

. 2343 f

( 907 ) 561

. 5301 www. us. sgs.com Member of SGS Group (Société Générale de Surveillance)Matrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 882405 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) XXX20585 SW3520C 02/10/2009
QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Semivolatile Organic Fuels Department


### Diesel Range Organics ND 0.400 mg/L 02/11/09 

### 0.0800
Surrogates


### 5a Androstane <surr> 77.3 60-120 % 02/11/09

Instrument Method Batch XFC8449

SW8015C HP 6890 Series II FID SV D RMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 882440 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) XXX20586 SW3520C 02/10/2009
QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Polynuclear Aromatics GC/MS


### Acenaphthylene ND 0.0500 ug/L 02/10/09 

### 0.0150 Acenaphthene ND 0.0500 ug/L 02/10/09 

### 0.0150 Fluorene ND 0.0500 ug/L 02/10/09 

### 0.0150 Phenanthrene ND 0.0500 ug/L 02/10/09 

### 0.0150 Anthracene ND 0.0500 ug/L 02/10/09 

### 0.0150 Fluoranthene ND 0.0500 ug/L 02/10/09 

### 0.0150 Pyrene ND 0.0500 ug/L 02/10/09 

### 0.0150 Benzo(a)Anthracene ND 0.0500 ug/L 02/10/09 

### 0.0150 Chrysene ND 0.0500 ug/L 02/10/09 

### 0.0150 Benzo[b]Fluoranthene ND 0.0500 ug/L 02/10/09 

### 0.0150 Benzo[k]fluoranthene ND 0.0500 ug/L 02/10/09 

### 0.0150 Benzo[a]pyrene ND 0.0500 ug/L 02/10/09 

### 0.0150 Indeno[1,2,3-c,d] pyrene ND 0.0500 ug/L 02/10/09 

### 0.0150 Dibenzo[a,h]anthracene ND 0.0500 ug/L 02/10/09 

### 0.0150 Benzo[g,h,i]perylene ND 0.0500 ug/L 02/10/09 

### 0.0150 Naphthalene ND 0.100 ug/L 02/10/09 

### 0.0310 1-Methylnaphthalene ND 0.0500 ug/L 02/10/09 

### 0.0150 2-Methylnaphthalene ND 0.0500 ug/L 02/10/09 

### 0.0150
Surrogates 

### Terphenyl-d14 <surr> 90.6 50-135 % 02/10/09

Instrument Method Batch XMS4825

8270D SIMS HP 6890/5973 MS SVOAMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 882496 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19194 SW5030B 02/10/2009
QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Volatile Fuels Department


### Gasoline Range Organics ND 100 ug/L 02/10/09 

### 10.0
Surrogates


### 4-Bromofluorobenzene <surr> 85.6 50-150 % 02/10/09

Instrument Method Batch VFC9351

SW8015C HP 5890 Series II PID+HECD VBAMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 882936 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) MXX21362 SW3010A 02/12/2009
QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Metals by ICP/MS



### Lead ND 1.00 ug/L 02/17/09 

### 0.310

Instrument Method Batch MMS5820

SW6020 Perkin Elmer Sciex ICP-MS P3Matrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 883391 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009
QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007, 1090476008

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Volatile Gas Chromatography/Mass SpectroscopyMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 883391 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Volatile Gas Chromatography/Mass Spectroscopy



### Benzene ND 0.400 ug/L 02/16/09 

### 0.120 Toluene ND 1.00 ug/L 02/16/09 

### 0.310 Ethylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 n-Butylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 1,4-Dichlorobenzene ND 0.500 ug/L 02/16/09 

### 0.150 1,2-Dichloroethane ND 0.500 ug/L 02/16/09 

### 0.150 1,3,5-Trimethylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 4-Chlorotoluene ND 1.00 ug/L 02/16/09 

### 0.310 Chlorobenzene ND 0.500 ug/L 02/16/09 

### 0.150 4-Methyl-2-pentanone (MIBK) ND 10.0 ug/L 02/16/09 

### 3.10 cis-1,2-Dichloroethene ND 1.00 ug/L 02/16/09 

### 0.310 4-Isopropyltoluene ND 1.00 ug/L 02/16/09 

### 0.310 cis-1,3-Dichloropropene ND 0.500 ug/L 02/16/09 

### 0.150 n-Propylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 Styrene ND 1.00 ug/L 02/16/09 

### 0.310 Dibromomethane ND 1.00 ug/L 02/16/09 

### 0.310 trans-1,3-Dichloropropene ND 1.00 ug/L 02/16/09 

### 0.310 1,2,4-Trichlorobenzene ND 1.00 ug/L 02/16/09 

### 0.310 Acetone ND 10.0 ug/L 02/16/09 

### 3.10 1,1,2,2-Tetrachloroethane ND 0.500 ug/L 02/16/09 

### 0.150 1,2-Dibromo-3-chloropropane ND 2.00 ug/L 02/16/09 

### 0.620 Methyl-t-butyl ether ND 5.00 ug/L 02/16/09 

### 1.50 Tetrachloroethene ND 1.00 ug/L 02/16/09 

### 0.310 Dibromochloromethane ND 0.500 ug/L 02/16/09 

### 0.150 1,3-Dichloropropane ND 0.400 ug/L 02/16/09 

### 0.120 1,2-Dibromoethane ND 1.00 ug/L 02/16/09 

### 0.310 Carbon tetrachloride ND 1.00 ug/L 02/16/09 

### 0.310 1,1,1,2-Tetrachloroethane ND 0.500 ug/L 02/16/09 

### 0.150 Chloroform ND 1.00 ug/L 02/16/09 

### 0.300 Bromobenzene ND 1.00 ug/L 02/16/09 

### 0.310 Chloromethane ND 1.00 ug/L 02/16/09 

### 0.310 1,2,3-Trichloropropane ND 1.00 ug/L 02/16/09 

### 0.310 Bromomethane ND 3.00 ug/L 02/16/09 

### 0.940 Bromochloromethane ND 1.00 ug/L 02/16/09 

### 0.310 Vinyl chloride ND 1.00 ug/L 02/16/09 

### 0.310 Dichlorodifluoromethane ND 1.00 ug/L 02/16/09 

### 0.310 Chloroethane ND 1.00 ug/L 02/16/09 

### 0.310 sec-Butylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 Bromodichloromethane ND 0.500 ug/L 02/16/09 

### 0.150Matrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Prep 

### 883391 Method Blank The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter Results Reporting/Control Limit Units Analysis Date MDL



### Volatile Gas Chromatography/Mass Spectroscopy


### 1,1-Dichloroethene ND 1.00 ug/L 02/16/09 

### 0.310 2-Butanone (MEK) ND 10.0 ug/L 02/16/09 

### 3.10 Methylene chloride ND 5.00 ug/L 02/16/09 

### 1.00 Trichlorofluoromethane ND 1.00 ug/L 02/16/09 

### 0.310 P & M -Xylene ND 2.00 ug/L 02/16/09 

### 0.620 Naphthalene ND 2.00 ug/L 02/16/09 

### 0.620 o-Xylene ND 1.00 ug/L 02/16/09 

### 0.310 Bromoform ND 1.00 ug/L 02/16/09 

### 0.310 1-Chlorohexane ND 1.00 ug/L 02/16/09 

### 0.310 1,2,4-Trimethylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 tert-Butylbenzene ND 1.00 ug/L 02/16/09 

### 0.310 1,1,1-Trichloroethane ND 1.00 ug/L 02/16/09 

### 0.310 1,1-Dichloroethane ND 1.00 ug/L 02/16/09 

### 0.310 2-Chlorotoluene ND 1.00 ug/L 02/16/09 

### 0.310 Trichloroethene ND 1.00 ug/L 02/16/09 

### 0.310 trans-1,2-Dichloroethene ND 1.00 ug/L 02/16/09 

### 0.310 1,2-Dichlorobenzene ND 1.00 ug/L 02/16/09 

### 0.310 2,2-Dichloropropane ND 1.00 ug/L 02/16/09 

### 0.310 Hexachlorobutadiene ND 1.00 ug/L 02/16/09 

### 0.310 Isopropylbenzene (Cumene) ND 1.00 ug/L 02/16/09 

### 0.310 1,2-Dichloropropane ND 1.00 ug/L 02/16/09 

### 0.310 1,1-Dichloropropene ND 1.00 ug/L 02/16/09 

### 0.310 1,1,2-Trichloroethane ND 1.00 ug/L 02/16/09 

### 0.310 1,3-Dichlorobenzene ND 1.00 ug/L 02/16/09 

### 0.310 1,2,3-Trichlorobenzene ND 1.00 ug/L 02/16/09 

### 0.310
Surrogates 

### 1,2-Dichloroethane-D4 <surr> 101 73-120 % 02/16/09 

### Toluene-d8 <surr> 101 80-120 % 02/16/09 

### 4-Bromofluorobenzene <surr> 103 76-120 % 02/16/09

Instrument Method Batch VMS10380

SW8260B HP 5890 Series II MS1 VJAMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 882441 Lab Control Sample

The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) XXX20586 SW3520C 02/10/2009

QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Polynuclear Aromatics GC/MS 

### Acenaphthylene LCS 0.259 52 ( 50-105 ) 0.5 ug/L 02/10/2009

Acenaphthene LCS 0.253 51 ( 45-110 ) 0.5 ug/L 02/10/2009

Fluorene LCS 0.271 54 ( 50-110 ) 0.5 ug/L 02/10/2009

Phenanthrene LCS 0.288 58 ( 50-115 ) 0.5 ug/L 02/10/2009

Anthracene LCS 0.282 56 ( 55-110 ) 0.5 ug/L 02/10/2009

Fluoranthene LCS 0.374 75 ( 55-125 ) 0.5 ug/L 02/10/2009

Pyrene LCS 0.364 73 ( 50-130 ) 0.5 ug/L 02/10/2009

Benzo(a)Anthracene LCS 0.363 73 ( 55-120 ) 0.5 ug/L 02/10/2009

Chrysene LCS 0.360 72 ( 55-120 ) 0.5 ug/L 02/10/2009

Benzo[b]Fluoranthene LCS 0.382 76 ( 46-130 ) 0.5 ug/L 02/10/2009

Benzo[k]fluoranthene LCS 0.357 71 ( 60-125 ) 0.5 ug/L 02/10/2009

Benzo[a]pyrene LCS 0.364 73 ( 55-120 ) 0.5 ug/L 02/10/2009

Indeno[1,2,3-c,d] pyrene LCS 0.361 72 ( 45-125 ) 0.5 ug/L 02/10/2009

Dibenzo[a,h]anthracene LCS 0.361 72 ( 41-140 ) 0.5 ug/L 02/10/2009

Benzo[g,h,i]perylene LCS 0.361 72 ( 46-125 ) 0.5 ug/L 02/10/2009

Naphthalene LCS 0.252 50 ( 42-100 ) 0.5 ug/L 02/10/2009

1-Methylnaphthalene LCS 0.243 49 ( 46-115 ) 0.5 ug/L 02/10/2009

2-Methylnaphthalene LCS 0.233 47 ( 45-105 ) 0.5 ug/L 02/10/2009

Surrogates 

### Terphenyl-d14 <surr> LCS 84 ( 50-135 ) 02/10/2009Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 882441 Lab Control Sample

The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) XXX20586 SW3520C 02/10/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Polynuclear Aromatics GC/MS

Batch Method Instrument 

### XMS4825

8270D SIMS HP 6890/5973 MS SVOAMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 882497 Lab Control Sample 882498 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19194 SW5030B 02/10/2009

QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits



### Volatile Fuels Department 

### Gasoline Range Organics LCS 192 96 ( 79-108 ) 200 ug/L 02/10/2009 LCSD 191 95 1 (< 20 ) 200 ug/L 02/10/2009

Surrogates 

### 4-Bromofluorobenzene <surr> LCS 91 ( 50-150 ) 02/10/2009 LCSD 90 1 02/10/2009

Batch Method Instrument 

### VFC9351

SW8015C HP 5890 Series II PID+HECD VBAMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 882788 Lab Control Sample 882789 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) XXX20585 SW3520C 02/10/2009

QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits



### Semivolatile Organic Fuels Department 

### Diesel Range Organics LCS 4.47 90 ( 75-125 ) 5 mg/L 02/11/2009 LCSD 4.27 85 5 (< 20 ) 5 mg/L 02/11/2009

Surrogates 

### 5a Androstane <surr> LCS 88 ( 60-120 ) 02/11/2009 LCSD 84 4 02/11/2009

Batch Method Instrument 

### XFC8449

SW8015C HP 6890 Series II FID SV D RMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 882937 Lab Control Sample

The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) MXX21362 SW3010A 02/12/2009

QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Metals by ICP/MS



### Lead LCS 986 99 ( 80-120 ) 1000 ug/L 02/17/2009

Batch Method Instrument 

### MMS5820

SW6020 Perkin Elmer Sciex ICP-MS P3Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

QC results affect the following production samples: 

### 1090476001, 1090476004, 1090476005, 1090476006, 1090476007, 1090476008

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass SpectroscopyMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### Benzene LCS 31.1 104 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 29.2 97 7 (< 20 ) 30 ug/L 02/16/2009

Toluene LCS 30.7 102 ( 77-120 ) 30 ug/L 02/16/2009 LCSD 30.6 102 0 (< 20 ) 30 ug/L 02/16/2009

Ethylbenzene LCS 32.9 110 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 32.1 107 2 (< 20 ) 30 ug/L 02/16/2009

n-Butylbenzene LCS 33.0 110 ( 80-124 ) 30 ug/L 02/16/2009 LCSD 31.9 106 3 (< 20 ) 30 ug/L 02/16/2009

1,4-Dichlorobenzene LCS 30.9 103 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 30.9 103 0 (< 20 ) 30 ug/L 02/16/2009

1,2-Dichloroethane LCS 31.5 105 ( 80-129 ) 30 ug/L 02/16/2009 LCSD 29.8 99 6 (< 20 ) 30 ug/L 02/16/2009

1,3,5-Trimethylbenzene LCS 32.6 109 ( 80-128 ) 30 ug/L 02/16/2009 LCSD 31.9 106 2 (< 20 ) 30 ug/L 02/16/2009

4-Chlorotoluene LCS 31.2 104 ( 79-128 ) 30 ug/L 02/16/2009 LCSD 31.2 104 0 (< 20 ) 30 ug/L 02/16/2009

Chlorobenzene LCS 32.5 108 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.8 106 2 (< 20 ) 30 ug/L 02/16/2009

4-Methyl-2-pentanone (MIBK) LCS 91.4 102 ( 69-134 ) 90 ug/L 02/16/2009 LCSD 86.8 97 5 (< 20 ) 90 ug/L 02/16/2009

cis-1,2-Dichloroethene LCS 32.5 108 ( 80-125 ) 30 ug/L 02/16/2009 LCSD 31.5 105 3 (< 20 ) 30 ug/L 02/16/2009

4-Isopropyltoluene LCS 32.5 108 ( 80-125 ) 30 ug/L 02/16/2009 LCSD 32.0 107 2 (< 20 ) 30 ug/L 02/16/2009

cis-1,3-Dichloropropene LCS 32.2 107 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 30.8 103 4 (< 20 ) 30 ug/L 02/16/2009

n-Propylbenzene LCS 32.0 107 ( 80-129 ) 30 ug/L 02/16/2009 LCSD 31.8 106 1 (< 20 ) 30 ug/L 02/16/2009Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### Styrene LCS 33.3 111 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 32.7 109 2 (< 20 ) 30 ug/L 02/16/2009

Dibromomethane LCS 32.8 109 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.2 104 5 (< 20 ) 30 ug/L 02/16/2009

trans-1,3-Dichloropropene LCS 29.1 97 ( 80-124 ) 30 ug/L 02/16/2009 LCSD 29.2 97 0 (< 20 ) 30 ug/L 02/16/2009

1,2,4-Trichlorobenzene LCS 32.1 107 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.6 105 2 (< 20 ) 30 ug/L 02/16/2009

Acetone LCS 100 111 ( 50-135 ) 90 ug/L 02/16/2009 LCSD 89.3 99 12 (< 20 ) 90 ug/L 02/16/2009

1,1,2,2-Tetrachloroethane LCS 30.7 102 ( 76-123 ) 30 ug/L 02/16/2009 LCSD 30.3 101 1 (< 20 ) 30 ug/L 02/16/2009

1,2-Dibromo-3-chloropropane LCS 30.5 102 ( 73-130 ) 30 ug/L 02/16/2009 LCSD 29.7 99 2 (< 20 ) 30 ug/L 02/16/2009

Methyl-t-butyl ether LCS 38.7 86 ( 80-120 ) 45 ug/L 02/16/2009 LCSD 39.3 87 1 (< 20 ) 45 ug/L 02/16/2009

Tetrachloroethene LCS 32.9 110 ( 79-122 ) 30 ug/L 02/16/2009 LCSD 31.6 105 4 (< 20 ) 30 ug/L 02/16/2009

Dibromochloromethane LCS 29.9 100 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 29.5 98 1 (< 20 ) 30 ug/L 02/16/2009

1,3-Dichloropropane LCS 32.1 107 ( 80-121 ) 30 ug/L 02/16/2009 LCSD 31.8 106 1 (< 20 ) 30 ug/L 02/16/2009

1,2-Dibromoethane LCS 32.2 107 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.6 105 2 (< 20 ) 30 ug/L 02/16/2009

Carbon tetrachloride LCS 35.2 117 ( 80-126 ) 30 ug/L 02/16/2009 LCSD 33.2 111 6 (< 20 ) 30 ug/L 02/16/2009

1,1,1,2-Tetrachloroethane LCS 29.7 99 ( 80-120 ) 30 ug/L 02/16/2009Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### LCSD 30.1 100 2 (< 20 ) 30 ug/L 02/16/2009

Chloroform LCS 31.5 105 ( 80-124 ) 30 ug/L 02/16/2009 LCSD 29.8 99 5 (< 20 ) 30 ug/L 02/16/2009

Bromobenzene LCS 29.9 100 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 30.6 102 2 (< 20 ) 30 ug/L 02/16/2009

Chloromethane LCS 48.5 162 ( 67-125 ) * 30 ug/L 02/16/2009 LCSD 56.4 188 * 15 (< 20 ) 30 ug/L 02/16/2009

1,2,3-Trichloropropane LCS 32.2 107 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.3 104 3 (< 20 ) 30 ug/L 02/16/2009

Bromomethane LCS 25.3 84 ( 30-140 ) 30 ug/L 02/16/2009 LCSD 30.5 102 19 (< 20 ) 30 ug/L 02/16/2009

Bromochloromethane LCS 34.1 114 ( 77-129 ) 30 ug/L 02/16/2009 LCSD 32.4 108 5 (< 20 ) 30 ug/L 02/16/2009

Vinyl chloride LCS 44.4 148 ( 72-145 ) * 30 ug/L 02/16/2009 LCSD 44.4 148 * 0 (< 20 ) 30 ug/L 02/16/2009

Dichlorodifluoromethane LCS 56.6 189 ( 62-153 ) * 30 ug/L 02/16/2009 LCSD 55.0 183 * 3 (< 20 ) 30 ug/L 02/16/2009

Chloroethane LCS 30.3 101 ( 67-133 ) 30 ug/L 02/16/2009 LCSD 27.6 92 9 (< 20 ) 30 ug/L 02/16/2009

sec-Butylbenzene LCS 31.6 105 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.4 105 1 (< 20 ) 30 ug/L 02/16/2009

Bromodichloromethane LCS 34.1 114 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 32.0 107 7 (< 20 ) 30 ug/L 02/16/2009

1,1-Dichloroethene LCS 35.1 117 ( 76-130 ) 30 ug/L 02/16/2009 LCSD 32.0 107 9 (< 20 ) 30 ug/L 02/16/2009

2-Butanone (MEK) LCS 103 115 ( 66-136 ) 90 ug/L 02/16/2009 LCSD 93.7 104 10 (< 20 ) 90 ug/L 02/16/2009Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy 

### Methylene chloride LCS 32.9 110 ( 63-131 ) 30 ug/L 02/16/2009 LCSD 31.4 105 5 (< 20 ) 30 ug/L 02/16/2009

Trichlorofluoromethane LCS 37.7 126 ( 68-145 ) 30 ug/L 02/16/2009 LCSD 33.9 113 11 (< 20 ) 30 ug/L 02/16/2009

P & M -Xylene LCS 68.1 113 ( 80-120 ) 60 ug/L 02/16/2009 LCSD 66.4 111 2 (< 20 ) 60 ug/L 02/16/2009

Naphthalene LCS 31.0 103 ( 75-120 ) 30 ug/L 02/16/2009 LCSD 30.9 103 0 (< 20 ) 30 ug/L 02/16/2009

o-Xylene LCS 33.4 111 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 32.7 109 2 (< 20 ) 30 ug/L 02/16/2009

Bromoform LCS 31.9 106 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 30.9 103 3 (< 20 ) 30 ug/L 02/16/2009

1-Chlorohexane LCS 49.9 111 ( 70-125 ) 45 ug/L 02/16/2009 LCSD 47.8 106 4 (< 20 ) 45 ug/L 02/16/2009

1,2,4-Trimethylbenzene LCS 31.6 105 ( 80-125 ) 30 ug/L 02/16/2009 LCSD 31.3 104 1 (< 20 ) 30 ug/L 02/16/2009

tert-Butylbenzene LCS 31.4 105 ( 80-122 ) 30 ug/L 02/16/2009 LCSD 30.9 103 1 (< 20 ) 30 ug/L 02/16/2009

1,1,1-Trichloroethane LCS 32.7 109 ( 80-122 ) 30 ug/L 02/16/2009 LCSD 31.0 103 5 (< 20 ) 30 ug/L 02/16/2009

1,1-Dichloroethane LCS 32.6 109 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 30.7 102 6 (< 20 ) 30 ug/L 02/16/2009

2-Chlorotoluene LCS 30.7 102 ( 80-125 ) 30 ug/L 02/16/2009 LCSD 31.0 103 1 (< 20 ) 30 ug/L 02/16/2009

Trichloroethene LCS 30.8 103 ( 80-125 ) 30 ug/L 02/16/2009 LCSD 28.8 96 7 (< 20 ) 30 ug/L 02/16/2009

trans-1,2-Dichloroethene LCS 31.8 106 ( 79-132 ) 30 ug/L 02/16/2009 LCSD 31.1 104 2 (< 20 ) 30 ug/L 02/16/2009Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### 1,2-Dichlorobenzene LCS 30.6 102 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 30.5 102 0 (< 20 ) 30 ug/L 02/16/2009

2,2-Dichloropropane LCS 33.4 111 ( 80-132 ) 30 ug/L 02/16/2009 LCSD 31.9 106 5 (< 20 ) 30 ug/L 02/16/2009

Hexachlorobutadiene LCS 28.4 95 ( 77-125 ) 30 ug/L 02/16/2009 LCSD 28.6 95 1 (< 20 ) 30 ug/L 02/16/2009

Isopropylbenzene (Cumene) LCS 33.4 111 ( 80-121 ) 30 ug/L 02/16/2009 LCSD 32.3 108 3 (< 20 ) 30 ug/L 02/16/2009

1,2-Dichloropropane LCS 33.0 110 ( 80-121 ) 30 ug/L 02/16/2009 LCSD 31.4 105 5 (< 20 ) 30 ug/L 02/16/2009

1,1-Dichloropropene LCS 33.0 110 ( 80-122 ) 30 ug/L 02/16/2009 LCSD 31.5 105 5 (< 20 ) 30 ug/L 02/16/2009

1,1,2-Trichloroethane LCS 32.1 107 ( 77-120 ) 30 ug/L 02/16/2009 LCSD 31.7 106 1 (< 20 ) 30 ug/L 02/16/2009

1,3-Dichlorobenzene LCS 31.4 105 ( 80-120 ) 30 ug/L 02/16/2009 LCSD 31.1 104 1 (< 20 ) 30 ug/L 02/16/2009

1,2,3-Trichlorobenzene LCS 30.9 103 ( 77-120 ) 30 ug/L 02/16/2009 LCSD 30.2 101 2 (< 20 ) 30 ug/L 02/16/2009

Surrogates 

### 1,2-Dichloroethane-D4 <surr> LCS 98 ( 73-120 ) 02/16/2009 LCSD 95 3 02/16/2009

Toluene-d8 <surr> LCS 99 ( 80-120 ) 02/16/2009 LCSD 101 1 02/16/2009

4-Bromofluorobenzene <surr> LCS 95 ( 76-120 ) 02/16/2009 LCSD 99 4 02/16/2009Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 02/19/2009 10:58
Batch Method Date Prep 

### 883392 Lab Control Sample 883393 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) Red Hill BFSF Water (Surface, Eff., Ground) VXX19212 SW5030B 02/16/2009

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy

Batch Method Instrument 

### VMS10380

SW8260B HP 5890 Series II MS1 VJAMatrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) MXX21362 3010 H20 Digest for Metals ICP-MS 02/12/2009

QC results affect the following production samples:

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Dissolved Metals by ICP/MS


### Lead BMS ND 877 88 ( 80-120 ) 1000 ug/L 02/17/2009 BMSD 922 92 5 (< 15 ) 1000 ug/L 02/17/2009

Batch Method Instrument 

### MMS5820

SW6020 Perkin Elmer Sciex ICP-MS P3

Volatile Fuels Department 

### Gasoline Range Organics BMS 14.0 J 423 91 ( 79-108 ) 450 ug/L 02/10/2009 BMSD 411 88 3 (< 20 ) 450 ug/L 02/10/2009 Surrogates 

### 4-Bromofluorobenzene <surr> BMS 45.2 90 ( 50-150 ) 02/10/2009 BMSD 46.0 92 2 02/10/2009

Batch Method Instrument 

### VFC9351

SW8015C HP 5890 Series II PID+HECD VBA

Semivolatile Organic Fuels Department 

### Diesel Range Organics BMS ND 4.9 88 ( 75-125 ) 5.56 mg/L 02/11/2009 BMSD 5.23 95 6 (< 30 ) 5.49 mg/L 02/11/2009 Surrogates 

### 5a Androstane <surr> BMS .0984 89 ( 50-150 ) 02/11/2009 BMSD 0.0985 90 0 02/11/2009

Batch Method Instrument 

### XFC8449

SW8015C HP 6890 Series II FID SV D R

Volatile Gas Chromatography/Mass SpectroscopyMatrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) VXX19212 Volatiles Extraction AFCEE 3.1 8260 (W) 02/16/2009

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Volatile Gas Chromatography/Mass Spectroscopy



### Benzene BMS ND 31 103 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 29.4 98 5 (< 20 ) 30.0 ug/L 02/16/2009 Toluene BMS ND 31.7 106 ( 77-120 ) 30.0 ug/L 02/16/2009 BMSD 29.6 99 7 (< 20 ) 30.0 ug/L 02/16/2009 Ethylbenzene BMS ND 33.9 113 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.8 106 6 (< 20 ) 30.0 ug/L 02/16/2009 n-Butylbenzene BMS ND 33.8 113 ( 80-124 ) 30.0 ug/L 02/16/2009 BMSD 31.8 106 6 (< 20 ) 30.0 ug/L 02/16/2009 1,4-Dichlorobenzene BMS ND 32.2 107 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.8 103 5 (< 20 ) 30.0 ug/L 02/16/2009 1,2-Dichloroethane BMS ND 30.9 103 ( 80-129 ) 30.0 ug/L 02/16/2009 BMSD 29.5 98 5 (< 20 ) 30.0 ug/L 02/16/2009 1,3,5-Trimethylbenzene BMS ND 33.7 112 ( 80-128 ) 30.0 ug/L 02/16/2009 BMSD 31.6 105 6 (< 20 ) 30.0 ug/L 02/16/2009 4-Chlorotoluene BMS ND 32.6 109 ( 79-128 ) 30.0 ug/L 02/16/2009 BMSD 31.0 103 5 (< 20 ) 30.0 ug/L 02/16/2009 Chlorobenzene BMS ND 32.7 109 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.1 104 5 (< 20 ) 30.0 ug/L 02/16/2009 4-Methyl-2-pentanone (MIBK) BMS ND 97.8 109 ( 69-134 ) 90.0 ug/L 02/16/2009 BMSD 90.2 100 8 (< 20 ) 90.0 ug/L 02/16/2009 cis-1,2-Dichloroethene BMS ND 33.5 112 ( 80-125 ) 30.0 ug/L 02/16/2009 BMSD 31.6 105 6 (< 20 ) 30.0 ug/L 02/16/2009 4-Isopropyltoluene BMS ND 33.7 112 ( 80-125 ) 30.0 ug/L 02/16/2009 BMSD 32.3 108 4 (< 20 ) 30.0 ug/L 02/16/2009 cis-1,3-Dichloropropene BMS ND 32.1 107 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.4 101 6 (< 20 ) 30.0 ug/L 02/16/2009 n-Propylbenzene BMS ND 33.3 111 ( 80-129 ) 30.0 ug/L 02/16/2009 BMSD 31.6 105 5 (< 20 ) 30.0 ug/L 02/16/2009 Styrene BMS ND 33.3 111 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.5 105 6 (< 20 ) 30.0 ug/L 02/16/2009 Dibromomethane BMS ND 32.1 107 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.0 103 3 (< 20 ) 30.0 ug/L 02/16/2009 trans-1,3-Dichloropropene BMS ND 30.3 101 ( 80-124 ) 30.0 ug/L 02/16/2009 BMSD 27.6 92 9 (< 20 ) 30.0 ug/L 02/16/2009 1,2,4-Trichlorobenzene BMS ND 32.2 107 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.4 105 3 (< 20 ) 30.0 ug/L 02/16/2009 Acetone BMS ND 95.7 106 ( 50-135 ) 90.0 ug/L 02/16/2009 BMSD 92.0 102 4 (< 20 ) 90.0 ug/L 02/16/2009 1,1,2,2-Tetrachloroethane BMS ND 32.3 108 ( 76-123 ) 30.0 ug/L 02/16/2009 BMSD 31.4 105 3 (< 20 ) 30.0 ug/L 02/16/2009Matrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) VXX19212 Volatiles Extraction AFCEE 3.1 8260 (W) 02/16/2009

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Volatile Gas Chromatography/Mass Spectroscopy 

### 1,2-Dibromo-3-chloropropane BMS ND 31.4 105 ( 73-130 ) 30.0 ug/L 02/16/2009 BMSD 30.5 102 3 (< 20 ) 30.0 ug/L 02/16/2009 Methyl-t-butyl ether BMS ND 50 111 ( 80-120 ) 45.0 ug/L 02/16/2009 BMSD 43.6 97 14 (< 20 ) 45.0 ug/L 02/16/2009 Tetrachloroethene BMS ND 34.3 114 ( 79-122 ) 30.0 ug/L 02/16/2009 BMSD 31.6 105 8 (< 20 ) 30.0 ug/L 02/16/2009 Dibromochloromethane BMS ND 29.5 98 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 27.1 90 8 (< 20 ) 30.0 ug/L 02/16/2009 1,3-Dichloropropane BMS ND 32.8 109 ( 80-121 ) 30.0 ug/L 02/16/2009 BMSD 30.9 103 6 (< 20 ) 30.0 ug/L 02/16/2009 1,2-Dibromoethane BMS ND 32.5 108 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.5 102 6 (< 20 ) 30.0 ug/L 02/16/2009 Carbon tetrachloride BMS ND 35.2 117 ( 80-126 ) 30.0 ug/L 02/16/2009 BMSD 32.7 109 7 (< 20 ) 30.0 ug/L 02/16/2009 1,1,1,2-Tetrachloroethane BMS ND 30.6 102 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 28.7 96 6 (< 20 ) 30.0 ug/L 02/16/2009 Chloroform BMS ND 31.1 104 ( 80-124 ) 30.0 ug/L 02/16/2009 BMSD 29.4 98 6 (< 20 ) 30.0 ug/L 02/16/2009 Bromobenzene BMS ND 31.7 106 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.0 100 5 (< 20 ) 30.0 ug/L 02/16/2009 Chloromethane BMS ND 54.3 181 * ( 67-125 ) 30.0 ug/L 02/16/2009 BMSD 50.5 168 * 7 (< 20 ) 30.0 ug/L 02/16/2009 1,2,3-Trichloropropane BMS ND 33.1 110 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.1 104 6 (< 20 ) 30.0 ug/L 02/16/2009 Bromomethane BMS ND 37.6 125 ( 30-140 ) 30.0 ug/L 02/16/2009 BMSD 39.7 132 5 (< 20 ) 30.0 ug/L 02/16/2009 Bromochloromethane BMS ND 34.1 114 ( 77-129 ) 30.0 ug/L 02/16/2009 BMSD 32.1 107 6 (< 20 ) 30.0 ug/L 02/16/2009 Vinyl chloride BMS ND 47.5 158 * ( 72-145 ) 30.0 ug/L 02/16/2009 BMSD 45.0 150 * 5 (< 20 ) 30.0 ug/L 02/16/2009 Dichlorodifluoromethane BMS ND 56.3 188 * ( 62-153 ) 30.0 ug/L 02/16/2009 BMSD 52.8 176 * 7 (< 20 ) 30.0 ug/L 02/16/2009 Chloroethane BMS ND 30.1 100 ( 67-133 ) 30.0 ug/L 02/16/2009 BMSD 27.4 91 9 (< 20 ) 30.0 ug/L 02/16/2009 sec-Butylbenzene BMS ND 32.6 109 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.1 104 5 (< 20 ) 30.0 ug/L 02/16/2009 Bromodichloromethane BMS ND 33.8 113 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 32.0 107 6 (< 20 ) 30.0 ug/L 02/16/2009 1,1-Dichloroethene BMS ND 33.1 110 ( 76-130 ) 30.0 ug/L 02/16/2009 BMSD 31.7 106 4 (< 20 ) 30.0 ug/L 02/16/2009Matrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) VXX19212 Volatiles Extraction AFCEE 3.1 8260 (W) 02/16/2009

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Volatile Gas Chromatography/Mass Spectroscopy 

### 2-Butanone (MEK) BMS ND 104 115 ( 66-136 ) 90.0 ug/L 02/16/2009 BMSD 97.8 109 6 (< 20 ) 90.0 ug/L 02/16/2009 Methylene chloride BMS ND 32.7 109 ( 63-131 ) 30.0 ug/L 02/16/2009 BMSD 31.2 104 5 (< 20 ) 30.0 ug/L 02/16/2009 Trichlorofluoromethane BMS ND 35.6 119 ( 68-145 ) 30.0 ug/L 02/16/2009 BMSD 32.4 108 9 (< 20 ) 30.0 ug/L 02/16/2009 P & M -Xylene BMS ND 68.3 114 ( 80-120 ) 60.0 ug/L 02/16/2009 BMSD 64.6 108 6 (< 20 ) 60.0 ug/L 02/16/2009 Naphthalene BMS ND 33.1 110 ( 75-120 ) 30.0 ug/L 02/16/2009 BMSD 31.1 104 6 (< 20 ) 30.0 ug/L 02/16/2009 o-Xylene BMS ND 33.8 113 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 31.1 104 8 (< 20 ) 30.0 ug/L 02/16/2009 Bromoform BMS ND 30.2 101 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 28.6 95 6 (< 20 ) 30.0 ug/L 02/16/2009 1-Chlorohexane BMS ND 50.7 113 ( 70-125 ) 45.0 ug/L 02/16/2009 BMSD 48.2 107 5 (< 20 ) 45.0 ug/L 02/16/2009 1,2,4-Trimethylbenzene BMS ND 33.1 110 ( 80-125 ) 30.0 ug/L 02/16/2009 BMSD 31.1 104 6 (< 20 ) 30.0 ug/L 02/16/2009 tert-Butylbenzene BMS ND 33 110 ( 80-122 ) 30.0 ug/L 02/16/2009 BMSD 31.2 104 5 (< 20 ) 30.0 ug/L 02/16/2009 1,1,1-Trichloroethane BMS ND 33 110 ( 80-122 ) 30.0 ug/L 02/16/2009 BMSD 31.5 105 5 (< 20 ) 30.0 ug/L 02/16/2009 1,1-Dichloroethane BMS ND 33.3 111 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.5 102 9 (< 20 ) 30.0 ug/L 02/16/2009 2-Chlorotoluene BMS ND 32.5 108 ( 80-125 ) 30.0 ug/L 02/16/2009 BMSD 30.6 102 6 (< 20 ) 30.0 ug/L 02/16/2009 Trichloroethene BMS ND 31.1 104 ( 80-125 ) 30.0 ug/L 02/16/2009 BMSD 29.5 98 5 (< 20 ) 30.0 ug/L 02/16/2009 trans-1,2-Dichloroethene BMS ND 48.4 161 * ( 79-132 ) 30.0 ug/L 02/16/2009 BMSD 32.2 107 40 (< 20 ) 30.0 ug/L 02/16/2009 * 1,2-Dichlorobenzene BMS ND 31.2 104 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.4 101 2 (< 20 ) 30.0 ug/L 02/16/2009 2,2-Dichloropropane BMS ND 35.3 118 ( 80-132 ) 30.0 ug/L 02/16/2009 BMSD 33.0 110 7 (< 20 ) 30.0 ug/L 02/16/2009 Hexachlorobutadiene BMS ND 29.4 98 ( 77-125 ) 30.0 ug/L 02/16/2009 BMSD 29.0 97 1 (< 20 ) 30.0 ug/L 02/16/2009 Isopropylbenzene (Cumene) BMS ND 33.3 111 ( 80-121 ) 30.0 ug/L 02/16/2009 BMSD 31.5 105 6 (< 20 ) 30.0 ug/L 02/16/2009 1,2-Dichloropropane BMS ND 33.4 111 ( 80-121 ) 30.0 ug/L 02/16/2009 BMSD 31.8 106 5 (< 20 ) 30.0 ug/L 02/16/2009Matrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) VXX19212 Volatiles Extraction AFCEE 3.1 8260 (W) 02/16/2009

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Volatile Gas Chromatography/Mass Spectroscopy 

### 1,1-Dichloropropene BMS ND 34.1 114 ( 80-122 ) 30.0 ug/L 02/16/2009 BMSD 31.6 105 8 (< 20 ) 30.0 ug/L 02/16/2009 1,1,2-Trichloroethane BMS ND 33.3 111 ( 77-120 ) 30.0 ug/L 02/16/2009 BMSD 31.3 104 6 (< 20 ) 30.0 ug/L 02/16/2009 1,3-Dichlorobenzene BMS ND 32.6 109 ( 80-120 ) 30.0 ug/L 02/16/2009 BMSD 30.7 102 6 (< 20 ) 30.0 ug/L 02/16/2009 1,2,3-Trichlorobenzene BMS ND 31.8 106 ( 77-120 ) 30.0 ug/L 02/16/2009 BMSD 30.5 102 4 (< 20 ) 30.0 ug/L 02/16/2009 Surrogates 

### 1,2-Dichloroethane-D4 <surr> BMS 28.9 96 ( 73-120 ) 02/16/2009 BMSD 29.1 97 1 02/16/2009 Toluene-d8 <surr> BMS 29.9 100 ( 80-120 ) 02/16/2009 BMSD 29.4 98 2 02/16/2009 4-Bromofluorobenzene <surr> BMS 29.9 100 ( 76-120 ) 02/16/2009 BMSD 29.9 100 0 02/16/2009

Batch Method Instrument 

### VMS10380

SW8260B HP 5890 Series II MS1 VJA

Polynuclear Aromatics GC/MSMatrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) XXX20586 3520 Liquid/Liquid Ext for 8270 SIM 02/10/2009

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Polynuclear Aromatics GC/MS 

### Acenaphthylene BMS ND .345 60 ( 50-105 ) 0.575 ug/L 02/10/2009 BMSD 0.313 58 10 (< 30 ) 0.538 ug/L 02/10/2009 Acenaphthene BMS ND .332 58 ( 45-110 ) 0.575 ug/L 02/10/2009 BMSD 0.311 58 7 (< 30 ) 0.538 ug/L 02/10/2009 Fluorene BMS ND .351 61 ( 50-110 ) 0.575 ug/L 02/10/2009 BMSD 0.326 61 7 (< 30 ) 0.538 ug/L 02/10/2009 Phenanthrene BMS ND .348 61 ( 50-115 ) 0.575 ug/L 02/10/2009 BMSD 0.332 62 5 (< 30 ) 0.538 ug/L 02/10/2009 Anthracene BMS ND .352 61 ( 55-110 ) 0.575 ug/L 02/10/2009 BMSD 0.329 61 7 (< 30 ) 0.538 ug/L 02/10/2009 Fluoranthene BMS ND .42 73 ( 55-125 ) 0.575 ug/L 02/10/2009 BMSD 0.395 73 6 (< 30 ) 0.538 ug/L 02/10/2009 Pyrene BMS ND .41 71 ( 50-130 ) 0.575 ug/L 02/10/2009 BMSD 0.380 71 8 (< 30 ) 0.538 ug/L 02/10/2009 Benzo(a)Anthracene BMS ND .413 72 ( 55-120 ) 0.575 ug/L 02/10/2009 BMSD 0.383 71 8 (< 30 ) 0.538 ug/L 02/10/2009 Chrysene BMS ND .409 71 ( 55-120 ) 0.575 ug/L 02/10/2009 BMSD 0.375 70 9 (< 30 ) 0.538 ug/L 02/10/2009 Benzo[b]Fluoranthene BMS ND .411 72 ( 46-130 ) 0.575 ug/L 02/10/2009 BMSD 0.389 72 6 (< 30 ) 0.538 ug/L 02/10/2009 Benzo[k]fluoranthene BMS ND .426 74 ( 60-125 ) 0.575 ug/L 02/10/2009 BMSD 0.386 72 10 (< 30 ) 0.538 ug/L 02/10/2009 Benzo[a]pyrene BMS ND .432 75 ( 55-120 ) 0.575 ug/L 02/10/2009 BMSD 0.391 73 10 (< 30 ) 0.538 ug/L 02/10/2009 Indeno[1,2,3-c,d] pyrene BMS ND .435 76 ( 45-125 ) 0.575 ug/L 02/10/2009 BMSD 0.387 72 12 (< 30 ) 0.538 ug/L 02/10/2009 Dibenzo[a,h]anthracene BMS ND .445 77 ( 41-140 ) 0.575 ug/L 02/10/2009 BMSD 0.395 73 12 (< 30 ) 0.538 ug/L 02/10/2009 Benzo[g,h,i]perylene BMS ND .422 73 ( 46-125 ) 0.575 ug/L 02/10/2009 BMSD 0.390 73 8 (< 30 ) 0.538 ug/L 02/10/2009 Naphthalene BMS ND .334 58 ( 42-100 ) 0.575 ug/L 02/10/2009 BMSD 0.307 57 9 (< 30 ) 0.538 ug/L 02/10/2009 1-Methylnaphthalene BMS ND .332 58 ( 46-115 ) 0.575 ug/L 02/10/2009 BMSD 0.301 56 10 (< 30 ) 0.538 ug/L 02/10/2009 2-Methylnaphthalene BMS ND .32 56 ( 45-105 ) 0.575 ug/L 02/10/2009 BMSD 0.289 54 10 (< 30 ) 0.538 ug/L 02/10/2009 Surrogates 

### Terphenyl-d14 <surr> BMS .456 79 ( 50-135 ) 02/10/2009 BMSD 0.425 79 7 02/10/2009Matrix SGS Ref.# Printed Date/Time 

### 02/19/2009 10:58 Batch Method Date Original Prep 

### 1090476002 Billable Matrix Spike 1090476003 Billable Matrix Spike Dup.

1090476001 Water (Surface, Eff., Ground) XXX20586 3520 Liquid/Liquid Ext for 8270 SIM 02/10/2009

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers



### Polynuclear Aromatics GC/MS

Batch Method Instrument 

### XMS4825

8270D SIMS HP 6890/5973 MS SVOA