# Patent

## Title
Luminous elements with an electroluminescent arrangement and method for producing a luminous element

## Abstract

The invention relates to a luminous element having a luminous layer which comprises electroluminescent particles and a water-dispersible or water-soluble protective colloid.

## Background
CROSS REFERENCE TO RELATED APPLICATIONS
This application is the National Stage of PCT/DE2012/001208 filed on Dec. 18, 2012, which claims priority under 35 U.S.C. §119 of German Application Nos. 10 2011 121 358.2 filed on Dec. 19, 2011, 10 2012 005 449.1 filed on Mar. 20, 2012, and 10 2012 016 759.8 filed on Aug. 27, 2012, the disclosures of which are incorporated by reference. The international application under PCT article 21(2) was not published in English.
The invention relates to a luminous element having an electroluminescent arrangement comprising a luminous layer that has inorganic electroluminescent particles. Such luminous elements are known, for example, from WO 2009/030 701 A1, “Electroluminescent arrangement on textile materials.”
From US 2008/0111108 A1, it is known, in the context of plasma cells, to use a protective colloid in the production of phosphorus particles. Because temperatures between 1000° C. and 1400° C. are used during production, it must be precluded that the protective colloid remains on the phosphors. Therefore no protective colloid in a luminous layer is disclosed. Furthermore, the plasma material is a completely different system from that of the luminous element having a luminescent arrangement according to the invention.
US 2009/0102363 A1 describes the production of very small organic luminous particles by means of micro-fragmentation of a layer that contains molecular luminous pigments, and the  application of a formulation produced with them, using a printing method. The durability of materials that are based on organic luminous particles is unsatisfactory. Furthermore, the production method comprises expensive steps such as electrolithography and vapor deposition.
Electroluminescence (also called the Destriau effect), is a phenomenon in which an inorganic substance which is capable to emit light, usually doped zinc sulfide, is excited to produce light (visible electromagnetic radiation) between the plates of a capacitor, by means of applying a high-frequency alternating voltage (50 Hz-3000 Hz).
In the case of the known luminous layers, the substances that contain solvents and the required dispersion stability make the production process more difficult.
It is therefore the task of the invention to make available an environmentally friendly luminous element that can be produced in cost-advantageous manner and, at the same time, demonstrates particularly good durability.
This task is accomplished with a luminous element of the stated type, in which the luminous layer exhibits a water-dispersible or water-soluble protective colloid.
The luminous element can comprise at least one support and at least one electroluminescent arrangement disposed on the latter, whereby the electroluminescent arrangement exhibits at least a front electrode, a luminous layer, an insulating layer, and a rear electrode. The luminous layer and insulating layer can also be applied in one step or in one layer.
In a preferred embodiment of the invention, the luminous element has the following layers on a support:

    
    
        optionally but preferably an adhesive layer that improves the adhesion of the overlying layers with the substrate,
        a transparent and electrically conductive layer as a front electrode,
        a layer that contains a luminous substance that can be excited by means of an electrical alternating voltage field as the luminous layer,
        an insulating layer with high dielectricity,
        a layer with high conductivity as the rear electrode,
        optionally but preferably conducting paths as a connector for the front electrode,
        optionally but preferably a barrier layer, and
        contacts as well as connectors for an alternating voltage source.
    
    


The electroluminescent arrangement can also be applied to the support in the reverse sequence, instead of as described above.
The entire arrangement of all the layers applied to the support will also be referred to as a layer arrangement hereinafter. The layer arrangement therefore comprises the electroluminescent arrangement and thereby also the luminous layer(s).
Both the support and, in particular, also one or more of the layers of the layer package as described above can be structured in one-ply or multi-ply or multi-layer manner. In this connection, the individual plies or layers having the same function can differ in terms of their composition.
It has been found that in the case of a luminous element, one or more of the layers of the layer package situated on the support, particularly one or more luminous layers, can exhibit at least one water-dispersible or water-soluble protective colloid, and that as a result, such luminous elements can be produced in particularly simple manner.
When drying such a layer package that contains a protective colloid and water, or such a luminous layer, a strong shrinkage may occur, which can destroy the whole layer arrangement. It is therefore proposed that one or more layers of the layer package, particularly one or more luminous layers, contain one or more plasticizer(s).
In a preferred embodiment, at least one plasticizer should be contained in at least one layer of the layer package, preferably in a luminous layer, in an amount that prevents undesirable fragility, brittleness, and deformation of the luminous element on drying. The individual components should therefore be coordinated with one another in such a manner that the luminous element does not break even at a bending radius of 1 cm, preferably of 0.5 cm, and particularly preferably of 0.3 cm. This applies for tensile stress (layer side on the outside) and also for pressure stress (layer side on the inside). Bending radii are determined, within the scope of the invention, by means of a 180° loop (half) around rolls having a defined radius (corresponds to the bending radius).
In an advantageous embodiment, the layer package contains a total of 0.6 g plasticizer per m2 to 2.0 g plasticizer per m2, preferably 0.8 g plasticizer per m2 to 1.2 g plasticizer per m2.
In order to achieve great dispersion stability of the formulation used for the coating method, in each instance, during the production of the luminous element it is proposed that the resulting layer package and, in particular, those layers within that contain dispersed or suspended particles, such as the luminous layer, for example, exhibit a protective colloid, preferably in an amount of at least 10 percent by weight (wt.-%), particularly of 10 wt.-% to 40 wt.-%, based on the weight after drying. Furthermore, it is advantageous if the layer package contains maximally 0.1 wt.-% water with reference to its weight after drying. A high dispersion stability is important for all preparations that contain pigments and are used for the production of the layers of the layer arrangement of the invention, and particularly important for the layers that contain luminous pigments. The pigments are kept in suspension in the aqueous dispersion during the coating process, using the protective colloid.
It is particularly advantageous if the layer package contains residuals of maximally 0.05 wt.-% organic solvents, with the exception of ethanol, isopropanol or butanols, with reference to the dry weight, wherein ethanol, isopropanol and butanols may be present in higher amounts.
Different materials can be used as protective colloids. Protective colloids or flocculation protection agents are usually polymer systems that are supposed to prevent agglomeration, coagulation or flocculation of an emulsified, suspended or dispersed component. An essential property of protective colloids is that they bind large amounts of water during solvation. Thus, high viscosities can be achieved in aqueous solutions, depending on the concentration. In contrast to emulsifiers, protective colloids generally do not lower the surface tension between an embedded polymer particle and the surrounding water. Protective colloids do not form micelles, and are used for stabilization of dispersions.
Not only natural substances such as gelatins, starch, chitosan, casein, and dextrin, but also derivatives of natural substances, such as cellulose derivatives, for example hydroxypropyl methylcellulose (HPMC) or carboxymethyl cellulose (CMC) or modified or partially decomposed gelatins are used as protective colloids. However, polymers such as polyvinyl alcohols, polyvinyl pyrrolidones, polyacrylic acids, and polyacrylamides can also be used as protective colloids, as can wax emulsions, for example a non-ionic ethylene/vinyl acetate copolymer wax. Gelatin is particularly preferred as a protective colloid; aside from its viscosity, it also has a good insulator effect.
Particularly if protective colloids made from natural substances are used, the use of biocides is recommended in order to improve the shelf life of coating solutions. Preferably, biocides from the group of benzisothiazolones are used, for example Proxel (1,2-benzisothiazol-3(2H)-one). The biocides are preferably applied in amounts of 0.003 g/m2 to 0.03 g/m2, particularly of 0.005 g/m2 to 0.01 g/m2.
Further components, some of them optional, comprised by a luminous element according to the invention will be described in more detail below.
A support of the invention should preferably be flexible and, in particular, allow a bending radius (see above) that is desired for the luminous element, depending on its intended use. Furthermore, it is advantageous to select it from among known support materials, considering the aspect that it is well suited for the method for application of the layer package, including the electroluminescent arrangement.
Clear, transparent, and flexible films can serve as support materials, like the following polymers or mixtures thereof: polyethylene, polyester, cellulose acetate, particularly cellulose triacetate, PET (polyethylene terephthalate), polycarbonate, PLA (polylactic acid), polyamide 6, polyamide 12, PEN (polyethylene naphthalate), PTFE (Teflon®=polytetrafluoroethylene), POM (polyoxymethylene), and ETFE (ethylene tetrafluoroethylene).
The support can also be a textile. Particularly when using textiles as supports, it is advantageous when the support has a primer layer, in order to adapt the absorption capacity and/or the surface composition for the following coating steps. Thus, for example, coating of surfaces that are uneven could lead to defects in the coating. The primer layer(s) can exhibit a thermoplastic polyurethane, for example, in order to make the surface of the support smoother. This layer can preferably be diluted with water.
The substrations and surface treatments of the support, which are known for coating methods, are suitable as adherent layer. Preferably, the adherent layer contains gelatin, particularly in an amount of 1.5 g/m2 to 3.2 g/m2, and particularly preferably of 1.8 g/m2 to 2.8 g/m2.
Furthermore, the adherent layer can contain other substances which improve the coatability and the stability, for example, such as biocides and plasticizers, as described above, wetting agents, and other coating additives, for example.
The luminous element can exhibit an alcohol-soluble, transparent, conductive front electrode. This front electrode layer comprises a conductive substance and should preferably have a dry layer thickness of less than 20 μm.
Preferably, the front electrode, in addition to its high conductivity, also demonstrates a high transparency, and does not overly absorb the light emitted in the overlying luminous layer.
A particular embodiment provides that PEDOT:PSS is used as a front electrode; this is offered for sale by the company Agfa-Gevaert N.V. under the trade name Orgacon, or by the company Hereaus under the trade name Clevios, for example. In order to guarantee a defect-free wetting of a substratum with the coating solution, it is advantageous when the surface tension is adjusted using suitable anionic, cationic or non-ionic wetting agents. The front electrode can be applied over the full area, and the dry film thickness is preferably from 2 μm to 15 μm.
Alternatively, the front electrode can also be part of the substrate. Conductive yarns or threads can be used in textiles, for example. As a result, the textile itself becomes the electrode.
A luminous layer of the invention preferably contains inorganic luminous pigments (electroluminescent particles) as the luminous substance, and is then also called a luminous pigment layer. These inorganic luminous pigments result in increased durability of the luminous element as compared with organic pigments. Such a luminous pigment layer preferably contains pigments in an aqueous dispersion during production and before drying. The luminous layer is preferably applied in the center, narrower, and at a distance of preferably 1 cm to 2 cm from the edge.
A preferred embodiment provides that the luminous layer has a dry thickness layer of less than 40 μm.
A luminous element of the invention preferably contains at least 10 wt.-%, particularly 10 wt.-% to 40 wt.-% of a protective colloid—with reference to the dry weight. This is particularly advantageous if a luminous pigment layer is involved.
Furthermore, it is advantageous if the luminous layer contains maximally 0.1 wt.-% water in relation to its dry weight.
The luminous pigments preferably have an average grain size of 0.5 μm to 50 μm, particularly of 20 μm to 40 μm. Advantageously, zinc sulfides that are doped with foreign atoms such as Cu, Mn, Ag, Au, Pb, P, As, Sb, Sn, V, Tl, Sc or mixtures of such foreign atoms are used as luminous pigments. In addition to the frequency of the applied alternating voltage, the doping determines the light color. Different color nuances or even a white color can be produced with a mixture of different pigments or by means of the application of multiple layers having different pigments, by means of additive light mixing.
In order to increase the shelf life of the luminous pigments, these are preferably encapsulated with Al2O3 or SiO2. However, they can also be embedded in lipophilic organic binders.
An insulating layer serves as electrical insulation of the luminous layer from an electrode. This layer is also referred to as a dielectric. It preferably serves, at the same time, also as a reflective layer that reflects the generated light in the luminous layer in the direction of the observer.
It is advantageous if such an insulating layer contains a protective colloid in an amount of 0.5 to 1.5 g/m2, preferably of 0.6 to 1.0 g/m2, whereby gelatin is preferred as a protective colloid.
In an advantageous embodiment, the insulating layer includes at least one electrically insulating component (non-conductor), for example a polyurethane dispersion.
Aside from the insulating property, a high level of reflection of the insulating layer for the light emitted from the luminous layer is of great importance for the light yield of the electroluminescent arrangement. Because the rear electrode that lies above absorbs light to a great degree, the proportion of luminescent radiation emitted toward the rear electrode would otherwise be lost if it were not reflected in the direction of the observer.
For this reason, the insulating layer can optionally comprise further additives such as reflective pigments such as titanium oxide, for example.
The insulating layer is applied, as compared with the luminous pigment layer, preferably as slightly as possible on each side, but maximally 33 mm, preferably between 0.2 and 10 mm wider than the light-emitting layer that lies underneath it, in order to cover the entire surface of the luminous layer. The dielectric can be applied as a layer, but short-circuits are more reliably prevented in that multiple layers, particularly 2, 3, 4, 5, 6 or more than 6 layers of a dielectric are applied.
A particular embodiment provides that the insulating layer of the electroluminescent arrangement contains reflective substances, particularly titanium dioxide in a water-soluble binder matrix such as gelatin, for example, preferably along with polymer plasticizers. The total dry layer thickness of the insulating layer preferably amounts from 10 μm to 50 μm.
A rear electrode consists of an electrically conductive material and can be either transparent like the front electrode, for example, or opaque.
The electrically conductive material is preferably contained in the rear electrode layer in an amount of 2 to 20 g/m2, particularly of 5 to 15 g/m2, and particularly preferably of 7 to 12 g/m2. Preferably, a strongly light-absorbing conductive material is used, such as carbon black, for example. Alternatively, a strongly light-absorbing material can be additionally contained in the layer.
The conductive rear electrode is preferably applied in the center and preferably covers the same area as the luminous pigment layer or overlaps the latter slightly, without touching the front electrode. In an advantageous embodiment, the rear electrode comprises at least one silver layer that contains fine silver particles which are dispersed in a conductive polymer matrix (for example polyaniline). The layer thickness of the rear electrode can amount to about 10 μm to 80 μm, for example.
The conductor paths improve the electrical supply and thereby the luminous effect, which becomes particularly noticeable as a uniform, large-area luminescence of the lamp superstructure or luminous element. This can be guaranteed by means of affixing a connector on the front electrode layer. The connector comprises such a conductor track, which is also referred to as a bus bar. For this purpose, a conductor track having a width of about 1 cm, for example, is applied to the front electrode, which should not come into contact with the rear electrode, because otherwise a short-circuit will destroy the function of the arrangement. Preferably, the same substance is used for the bus bar as for the rear electrode. In the case of a sufficiently great conductivity of the front electrode, the bus bar can also be eliminated.
Alternatively, a metal lattice, for example composed of silver, can also be used.
Preferably, a cover layer is used as a barrier layer; this layer protects the luminous element and, in particular, the luminous layer from oxygen in the air and moisture, and, if applicable, from chemicals and mechanical damage. The barrier should have an electrically insulating effect, in order to protect the user from injury caused by the electrical current. The barrier layer can be omitted at the connector parts for the front and rear electrode.
Actega Terraflex barrier varnish, for example, along with a polyethylene or polyvinylidene fluoride dispersion (PVDF) is suitable as a barrier layer. Alternatively, other commercially available barrier layers made of glass or film can also be used.
Contacting of the luminous element is made preferably with conductive materials, particularly metal sheets, which are glued onto the bus bar and/or the rear electrode with a conductive adhesive tape such as 3MTM Electrically Conductive Adhesive Transfer Tape (ECATT) 9723, for example.
Furthermore, the luminous element may also consist of the following layers or layer additives, for example:
one or more antistatic layers such as those described in Research Disclosure 38957, September 1996, p. 591 ff., TX-C, for example. The content of the entire document is hereby incorporated into the application by reference,
one or more auxiliary coating agents such as those described in Research Disclosure 38957, September 1996, p. 591 ff., IX-A, for example. The content of the entire document is hereby incorporated into the application by reference, and
one or more “non-curling” layers that can improve the planarity of the element.
In a preferred embodiment of the invention, one, multiple or all the layers have one or more hardening agents (cross-linking agents, crosslinkers) added to them, and thereby the layers are hardened after coating and drying, in order to achieve good water resistance. For this purpose, a cross-linking agent that is suitable for the given matrix, in each instance, is used. For layers containing gelatin, the compounds indicated in the Research Disclosure 38957, September 1996, p. 591 ff., II-B, for example, are suitable, particularly glyoxal, divinyl sulfone hardening agent or, for rapid hardening, an immediate hardening agent such as H-1 (see below), for example. For matrices with hydroxyl groups, such as polyvinyl alcohols, cellulose derivatives or polyethylene glycols, trifunctional isocyanates, for example, such as Desmodur N 3300, for example, are possible cross-linking agents.




A particularly advantageous method for the production of such a luminous element of the invention includes the method step that at least one layer, i.e. one part of the layer package, and particularly one part of the luminous layer, are produced using a coating method. Preferably, the entire layer package, particularly the entire electroluminescent arrangement, and particularly preferably at least the entire luminous layer is applied to a support using a coating method, wherein the luminous layer is applied as single layer or in the form of multiple layers. All or individual ones of the layers mentioned can, however, also be applied to a support using another suitable method.
Suitable methods for the application of layers, particularly of luminous layers, onto a support are doctor blade coating, immersion coating, spray coating or roll coating, also with a reversed roll coater, or, in a preferred embodiment, a single or multilayer coating by means of a cascade or curtain coating method.
For this purpose, the individual layer components are emulsified or dispersed, if necessary, and converted to a preparation that can be used for coating solutions that contain water. This means that a water-based composition is used for at least one layer. Preferably, only demineralized sterilized water is used. The concentrations of the solutions depend on the selected application method and vary as a function of the applied wet thickness. The coating solutions are applied using an application method that corresponds to the state of the art.
In an advantageous embodiment of the invention, only so few highly volatile organic solvents are used in such a small amount for the production of the luminous element that production can take place without explosion-protected apparatuses.
This is achieved in that water-based compositions are used for the preparations used for the production of the individual layers of the luminous element, as far as possible. Preferably, water-based compositions are used for all the layers of the luminous element. A water-based composition should be understood to be a composition that contains dissolved or dispersed substances, and the volatile ingredients of which, which are removed after production of the luminous element, by means of drying, for the most part, consist of water by at least 50 wt.-%, preferably by at least 80 wt.-%, and particularly preferably by at least 95 wt.-%.
To achieve a sufficient dispersion stability for the given aqueous dispersion, it is proposed that the dispersion, after addition of the water-dispersible or water-soluble protective colloid, has a viscosity of less than 400 mPa·s (preferably 120-200 mPa·s). The viscosity of the dispersion is preferably measured using a rotation viscosimeter (for example Brookfield viscosimeter DVII), at a temperature of 40° C.
The invention therefore also covers luminous elements that are produced using water-based preparations.
Preferably, a coating equipment is used for the production of the luminous element that can be adapted to the required width.
The luminous element is preferably produced in such a manner that it can be cut using tools such as scissors or cutting rolls, without impairing its function.
In another embodiment of the invention, at least one layer, preferably more than one layer, and particularly preferably all the layers are applied using water-based inks, using a printing method, particularly an ink-jet printing method.
Such luminous elements are suitable, for example, as tent or vehicle tarps, and can also be used as an interior liner of a vehicle or for other lighting purposes.


EXAMPLES
Example 1
Production of the Casting Solution for a Luminous Layer
An exemplary formula for the production of a solution for coating a luminous layer consists of the following substances:
4.16 g/m2 photo gelatin,
19.02 g/m2 distilled water, and
11.83 g/m2 luminous pigment GTP GG44.
The photo gelatin is stirred in distilled water at 20° C. The mixture must swell for 1 hour.
The gelatin/water mixture is slowly digested at 45° C., until the gelatin has melted completely.
The luminous pigment is added 20 minutes (min.) before coating the aqueous gelatin solution, and the dispersion is digested for 15 min. This is followed by ultrasound degasification for 5 min.
The dispersion is applied to the substrated support, using a wet thickness of 25 μm, by means of doctor blade coating, roll coating or cascade coating. The drying time is approx. 30 min. at 40° C.
This luminous layer is only a part of a luminous element, which usually consists of an adhesive layer, a front electrode layer, a luminous layer, a dielectric, and a rear electrode layer.
Example 2
Luminous Element
A particularly preferred water-based luminous element is produced in that the layers described below, one after the other (layer package 1) are applied to a polyester base (manufacturer: Agfa Gevaert N.V., thickness: 125 μm, trade name Astera 125, substrated on one side).
The components used (see the following table) are commercially available.













Active substance




(active substance
Manufacturer/Source


Product
class)
of supply







Imagel AP
Gelatin (protective
Gelita



colloid)


Proxel U5
1,2-benzisothiazol-
Arch Chemicals, Inc.



3(2H)-one (biocide)


Polymer dispersion,
Polyethylene
Agfa Labs


copolymer of
acrylate


polyethylene and
(plasticizer)


polyacrylate


Metaupon OMT
Sodium-2-
Leuna-Tenside GmbH



[methyloleoyl-



amino]ethane-1-



sulfonate (wetting



agent)


TERGITOL ®
Nonyl phenol
Union Carbide



polyethylene glycol



ether (wetting



agent)


Clevios SV4
PEDOT:PSS
Heraeus



(conductive



substance)


Luminous pigment
Zinc sulfide
GT&P


GG44
(luminous substance)


CMC carboxymethyl
Carboxymethyl
Alfa Aesar


cellulose
cellulose



(protective colloid)


Dynasylan F8815
Fluoroalkyl silane
Evonik



(adhesion-imparting



agent)


Tubicoat MEA
Polyurethane
CHT R. Breitlich



dispersion (non-
GmbH



conductive



substance)


Titanium dioxide
TiO2 (reflective
Kronos Titan GmbH


dispersion
substance)


Carbon black
Carbon (conductive
Evonik Carbon Black



substance)
GmbH


Aquatix 8421
Ethylene vinyl
BYK-Chemie GmbH



acetate copolymer



wax (protective



colloid)









The layers are applied in one pass with a cascade coater (multilayer coating). The concentrations required for good coating rheology, the amounts of water per coating solution, and the viscosity of the latter are determined and taken into consideration in accordance with known methods.
The applications of the layer components listed below are given in g/m2. The values in the curly brackets indicate a practical amount range, and the values in the square brackets refer to amount ranges for a particularly preferred exemplary embodiment with high luminance and good durability. Thus, 1.5 g/m2 to 3.2 g/m2 gelatin are preferably used in the adhesive layer, particularly preferably 1.8 g/m2 to 2.8 g/m2.
The amounts stated, in each instance, are not restricted to the exemplary embodiment, but rather apply in general for corresponding layers of the invention or the additives contained in them. Thus, for example, the information explained for the adhesive layer, for the amount of gelatin preferably contained in it, also applies, within the context of the invention, as a preferred amount range for gelatin in any desired adhesive layer, independent of the other ingredients and independent of the structure of the luminous element, in each instance. Furthermore, the information applies not just for the concrete preferred additive (active substance) in the layer, but rather also for other suitable representatives of the active substance class, in each instance. The amount information for gelatin in the adhesive layer, for example, therefore applies also to other suitable protective colloids. This applies analogously for all the active substances listed in the above table and for the active substance class indicated in parentheses, in each instance.
The value in front of the brackets represents the amount of active substance used in the concrete exemplary embodiment.










Layer Package 1







Layer 1 (adhesive layer)










Gelatin
2.38{1.5[1.8-2.8]3.2}



1,2-benzisothiazol-3(2H)-one
0.007{0.003[0.005-0.008]0.015}



Polyethylene acrylate
0.24{0.15[0.18-0.28]0.32}



Sodium-2-[methyloleoyl
0.095{0.095[0.72-0.11]0.13}



amino]ethane-1-sulfonate



Nonyl phenol polyethylene
0.060{0.05[0.05-0.2]0.3}



glycol ether







Layer 2 (front electrode)










Clevios SV4
20.5{18.0[19.0-28.0]36.0}



Nonyl phenol polyethylene
0.14 {0.10[0.12-0.18]0.20}



glycol ether







Layer 3 (luminous layer)










Gelatin
1.80{1.0[1.2-3.2]3.4}



Luminous pigment GG44
18.0{10.0[16.0-24.0]28.0}



Carboxymethyl cellulose
0.18{0.10[0.12-0.32]0.34}



Polyethylene acrylate
0.480{0.27[0.32-0.85]0.90}



Sodium-2-[methyloleoyl
0.192{0.11[0.13-0.33]0.35}



amino]ethane-1-sulfonate



Dynasylan F8815
0.240{0.01[0.02-0.25]0.26}







Layer 4 (dielectric)










Tubicoat MEA
27.4{20.0[25.0-35.0]75.0}



Titanium dioxide
9.14{0.50[0.60-10.0]30.0}



Gelatin
0.640{0.60[0.60-0.80]1.5}







Layer 5 (rear electrode)










Proxel U5
0.040{0.01[0.02-0.08]0.16}



Gelatin
8.58{4.0[5.0-9.0]9.2}



Carbon black
7.42{7.0[7.2-10.0]14.0}



Nonyl phenol polyethylene
0.044{0.04[0.042-0.08]0.10}



glycol ether



Aquatix 8421
22.2{15.0[17.0-23.0]25.0}










In comparison with luminous elements that are produced according to the state of the art, the luminous element described above yields a high luminance and a long useful lifetime. It allows small bending radii of approx. 3 mm (both tension and pressure) by means of the great flexibility of the layers. No organic solvents are used during production, the use of heavy metals is not necessary, and the production costs are low. There are no expenditures for explosion protection. Production scrap that occurs does not need to be disposed of as hazardous waste.
The FIGURE shows an exemplary embodiment with an advantageous layer structure.
An adhesive layer 2 is applied to a support 1. A transparent and electrically conductive layer lies on top of this as a front electrode 3. In the central region, a luminous layer 4 lies on the front electrode 3, above which layer there is an insulating layer 5 that reaches all the way to the front electrode 3 in the edge region. The rear electrode 6 lies above the luminous layer 4; this electrode also lies in the central region. Conductor tracks 7 disposed at the edges, outside of the central region, serve as connectors for the front electrode 3. A barrier layer 8 is applied over the entire width and above the rear electrode. Contacts 9 on the conductor track 7 and 9′ on the rear electrode 6 serve as a connection to an alternating voltage source 10.

## Claims

1. Luminous element having an electroluminescent arrangement comprising a luminous layer that has inorganic electroluminescent particles, wherein the luminous layer exhibits a water-soluble protective colloid, and wherein the water-soluble protective colloid exhibits gelatin.

2. Luminous element according to claim 1, wherein the luminous layer exhibits at least one plasticizer.

3. Luminous element according to claim 1, wherein the electroluminescent particles exhibit doped zinc sulfide.

4. Luminous element according to claim 1, wherein it does not break at a bending radius of 0.5 cm.

5. Luminous element according to claim 1, wherein the luminous layer has at least 10 wt.-% protective colloid, with reference to its dry weight.

6. Luminous element according to claim 1, wherein the luminous element contains residuals of maximally 0.005 wt.-% organic solvent, with the exception of ethanol, isopropanol or butanols, with reference to the dry weight, wherein ethanol, isopropanol and butanols may be present in higher amounts.

7. Luminous element according to claim 1, wherein the luminous layer is disposed on a support.

8. Luminous element according to claim 1, wherein the luminous layer has a thickness of less than 40 μm.

9. Luminous element according to claim 1, wherein it exhibits an alcohol-soluble, transparent, conductive front electrode layer.

10. Luminous element according to claim 9, wherein the front electrode layer has a thickness of less than 20 μm.

11. Method for the production of a luminous element having an electroluminescent arrangement comprising a luminous layer that has inorganic electroluminescent particles, wherein the luminous layer exhibits a water-soluble protective colloid, wherein the water-soluble protective colloid is selected from the group consisting of natural substances, derivatives of natural substances, polyvinyl pyrrolidones, polyacrylic acids, and wax emulsions, and wherein all of the layers are produced using a coating method, with the use of water-based compositions.

12. Method according to claim 11, wherein the composition is a dispersion that exhibits a water-dispersible or water-soluble protective colloid and has a viscosity of less than 400 mPa·s.

13. Method according to claim 11, wherein the water-based composition contains volatile ingredients removed after production of the luminous element via drying for the most part, and wherein the volatile ingredients are composed of at least 50 wt. % of water.

14. Luminous element having an electroluminescent arrangement comprising a luminous layer that has inorganic electroluminescent particles, wherein the luminous layer exhibits a water-soluble protective colloid, wherein the water-soluble protective colloid is selected from the group consisting of natural substances, derivatives of natural substances, polyvinyl pyrrolidones, polyacrylic acids, and wax emulsions, and wherein the luminous layer contains maximally 0.1 wt.-% water, with reference to its dry weight.