Instructions for filling the Emission Test Template

This Information Collection Request (ICR) spreadsheet is intended to collect information about emission data from fossil fue l burning power plants and which test methods were used to do so for cases where the test methods are not currently supported by the Electronic Reporting Tool (ERT). This spreadsheet should only be used if the method is not in the ERT or if you do not h ave access to a lab which performs methods that are in the ERT. Constituents of concern are: Carbon Monoxide, Formaldehyde, Methane, Speciated Volatile Hazardous Air Pollutants (HAPs), Speciated Semi

-Volatile Organic HAPs, Sulfur Dioxide, Oxygen, Carbo n Dioxide, Hydrogen Cyanide, Nitrogen Oxides, Total Dissolved Solids (TDS), and Total Suspended Solids (TSS). You must complet e 3 separate sampling events for each of the requested constituents. This spreadsheet is intended to be used for one boiler of one facility. Data for multiple boilers should be handled by using separate copies of this spreadsheet. Fields shaded in yellow are required. All cells that are shaded in light green are populated using drop

-down lists. You do not need to populate cells sha ded in gray, as they are automatically populated from the Boiler Information worksheet. Please Do Not modify the structure of this spreadsheet by adding or subtracting rows, columns, cells. Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_EmisTestMethods.xls (example: 8100_Unit_2_EmisTestMethods.xls).

Please refer to the following steps when using these spreadsheets.

Boiler Information Worksheet

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the control device configuration.

Emission Data Worksheets

The emission data worksheets are provided for each constituent or constituent family required for this analysis. On each spreadsheet, you must enter boiler operating information during sampling, fuel input information, and emission test results. T here are generally 1 to 3 emission test results records to be entered depending on the constituent or constituent family. For exa mpl e, CO only requires 1 record with 3 sample events, while Mercury requires that you enter both Hg 0 and Hg+2, or if the Ontario

- Hydro Method was used, you would need to enter Hg0, HgP, and Hg+2 . However, both the Speciated Volatile Organic HAP and Speciated Semi

-Volatile Organic HAP worksheets allow you to use a drop

-down provided in the Constituent field to define as many records as needed to record each HAP that you have results for. General instructions follow for these worksheets:

Boiler Operation Information

1. Please determine which units of measure (acfm or dscfm) were used for Exhaust Flow Rate and which units of measure (deg C or deg F) were used for Exhaust Temperature. Fill these units of measure into the Units of Measure field. 2. Please provide the values of all requested parameters for each of the 3 sample testing periods in the Sample 1, Sample 2, an d Sample 3 fields. 3. Please provide any other supporting information or comments in the Other Supporting Information field.

Fuel Information

1. Please enter what types of fuel are being used in your boiler using the drop

-downs in the Fuel Type Selection field. You may enter up to 4 fuel types. Then, enter the input rate of each fuel in the Sample 1, Sample 2, and Sample 3 fields. If you are n ot burning one or more of the fuel types entered in one or more samples, then enter an input rate of zero. 2. Please enter the unit of measure using the drop down provided. 3. Please enter the test method used to determine the fuel input rate. 4. Please provide any other information that you feel may be important in the Other Supporting Information field.

Emission Data

1. Some constituents ask for the emission rate results of each of the 3 samples in two different units of measure, while oth ers do not. If emission rate results are requested in two different units of measure (ex. lb/MMBtu (Pounds per million BTU) and pp mvd @ 7% O 2 (parts per million by volume dry basis at 7 percent oxygen)), you are required to provide both. 2. Please provide the test method used. This may or may not match the example given in the Test Method Used field. Please ensure that the name includes the owning organization of the test method (ex. U.S. EPA Method 0010). 3. Please provide any other information that you feel may be important in the Other Supporting Information field. 4. If data sheets and QA/QC documentation tables are provided for the test method you are entering data for please also enter these data.EIA

Facility Code Facility Name Boiler ID Control Device Configuraton

298 Limestone Lim2EIA

Facility Code Facility Name Boiler ID

Parameter Sample 1 Sample 2 Sample 3 Unit of Measure Other Supporting Information Date of Testing 4/22/2010 4/22/2010 4/22/2010 Steam Output (1000 lb/hr) 6117 6110 6081 1000 lb/hr Total Heat Input (MMBtu/hr) 8735 8705 8666 MMBtu/hr Basis (W et/Dry) Dry Dry Dry N/A Exhaust Steam % Moisture 14.67 14.45 14.91 % Exhaust Flow Rate (acfm or dscfm) 1962000 1947000 1950000 dscfm Exhaust Temperature (deg C or deg F) 150 151 151 deg F

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate

Sample 2 Fuel Input Rate

Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting

Information subbituminous 7352.7 7352.7 7352.7 ton/day Other lignite 6122.3 6122.3 6122.3 ton/day Other

Emission Test Results CO Emission Rate Sample 1 (lb/MMBtu) CO Emission Rate Sample 1 (ppmvd @ 7%

O2) CO Emission Rate

Sample 2 (lb/MMBtu) CO Emission Rate Sample 2 (ppmvd @ 7%

O2) CO Emission Rate

Sample 3 (lb/MMBtu) CO Emission Rate Sample 3 (ppmvd @ 7%

O2) Test Method Used

(ex. U.S. EPA Method 10A

) Other Supporting

Information 0.025 18.7 0.027 25.2 0.023 20.7 U.S. EPA Method 320EIA

Facility Code Facility Name Boiler ID

Parameter Sample 1 Sample 2 Sample 3 Unit of Measure Other Supporting Information Date of Testing 4/22/2010 4/22/2010 4/22/2010 Steam Output (1000 lb/hr) 6117 6110 6081 1000 lb/hr Total Heat Input (MMBtu/hr) 8735 8705 8666 MMBtu/hr Basis (Wet/Dry) Dry Dry Dry N/A Exhaust Steam % Moisture 14.67 14.45 14.91 % Exhaust Flow Rate (acfm or dscfm) 1962000 1947000 1950000 dscfm Exhaust Temperature (deg C or deg F) 150 151 151 deg F

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate

Sample 2 Fuel Input Rate

Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting

Information subbituminous 7352.7 7352.7 7352.7 ton/day Other lignite 6122.3 6122.3 6122.3 ton/day Other

Emission Test Results Formaldehyde Emission Rate Sample 1 (lb/MMBtu) Formaldehyde

Emission Rate Sample 1 (ppmvd @ 7% O2) Formaldehyde Emission Rate Sample 2 (lb/MMBtu) Formaldehyde

Emission Rate Sample 2 (ppmvd @ 7% O2) Formaldehyde Emission Rate Sample 3 (lb/MMBtu) Formaldehyde

Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA Method 320) Other Supporting Information 0.00006 0.044 0.00006 0.054 0.00006 0.054 U.S. EPA Method 320 [<0.00006],[<0.054] BDLEIA Facility Code Facility Name Boiler ID

Parameter Sample 1 Sample 2 Sample 3 Unit of Measure Other Supporting Information Date of Testing 4/22/2010 4/22/2010 4/22/2010 Steam Output (1000 lb/hr) 6117 6110 6081 1000 lb/hr Total Heat Input (MMBtu/hr) 8735 8705 8666 MMBtu/hr Basis (Wet/Dry) Dry Dry Dry N/A Exhaust Steam % Moisture 14.67 14.45 14.91 % Exhaust Flow Rate (acfm or dscfm) 1962000 1947000 1950000 dscfm Exhaust Temperature (deg C or deg F) 150 151 151 deg F

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3 Unit of Measure Fuel FlowMeasurement Method Other Supporting Information subbituminous 7352.7 7352.7 7352.7 ton/day Other lignite 6122.3 6122.3 6122.3 ton/day Other

Emission Test Results Methane Emission Rate Sample 1 (lb/MMBtu) Methane Emission Rate Sample 1 (ppmvd @ 7% O2) Methane Emission Rate Sample 2 (lb/MMBtu) Methane Emission Rate Sample 2 (ppmvd @ 7% O2) Methane Emission Rate Sample 3 (lb/MMBtu) Methane Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA Method 18) Other Supporting Information 0.00002 0.03 0.00001 0.01 0.00001 0.01 U.S. EPA Method 320 [<0.00001], [<0.1], DLLEIA

Facility Code Facility Name Boiler ID

Parameter Sample 1 Sample 2 Sample 3 Unit of Measure Other Supporting Information Date of Testing 4/22/2010 4/22/2010 4/22/2010 Steam Output (1000 lb/hr) 6117 6110 6081 1000 lb/hr Total Heat Input (MMBtu/hr) 8735 8705 8666 MMBtu/hr Basis (W et/Dry) Dry Dry Dry N/A Exhaust Steam % Moisture 14.67 14.45 14.91 % Exhaust Flow Rate (acfm or dscfm) 1962000 1947000 1950000 dscfm Exhaust Temperature (deg C or deg F) 150 151 151 deg F

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting Information subbituminous 7352.7 7352.7 7352.7 ton/day Other lignite 6122.3 6122.3 6122.3 ton/day Other

Emission Test Results Constituent Consitutent Emission Rate Sample 1 (%) Consitutent Emission Rate Sample 2 (%) Consitutent Emission Rate Sample 3 (%) Test Method Used

(ex. U.S. EPA

Method 3B) Other Supporting Information O 2 4.98 5.05 5.02 U.S. EPA Method 3A
CO 2 14.67 14.45 14.91 U.S. EPA Method 3AEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Sample 3 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3

Emission Test Results SO2 Emission Rate Sample 1 (lb/MMBtu) SO2 Emission Rate Sample 1 (ppmvd @ 7% O2) SO2 Emission Rate Sample 2 (lb/MMBtu)Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Unit of Measure Fuel Flow Measurement Method Other Supporting Information

SO2 Emission Rate Sample 2 (ppmvd @ 7% O2) SO2 Emission Rate Sample 3 (lb/MMBtu) SO2 Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA Method 6)Other Supporting

InformationEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Total Vapor Phase Me rcury Emission Rate Sample 1 (lb/MMBtu) Total Vapor Phase

Me rcury Emission Rate Sample 2 (lb/MMBtu) 1.89396E-05 1.81537E-05



### Data Sheets and QA

/QC Documentation

trap ID Section 1 5 A-Side 66065 127.3593432 5 B-Side 66073 254.7276019 6 A-Side 66041 245.4884536 6 B-Side 66232 124.0596474 7 A-Side 66237 122.0798299 7 B-Side 66064 225.0303395

Start 5 A-Side 40269 8:28 5 B-Side 40269 8:28 6 A-Side 40269 11:08 6 B-Side 40269 11:08 Summary of Hg Collected on Sorbent Traps via Method 30B

Run ID Appartioned Mass (ng)

Individual Sorbent Tube Emission Summary, Method 30B
Run ID Test Date Run Time7 A-Side 40269 13:22

7 B-Side 40269 13:22 Averages

Average R Vol. diff (%) 5 A-Side 0.055721212 1.547371567 5 B-Side 0.055721212 1.342560077 6 A-Side 0.055721212 0.511021092 6 B-Side 0.055721212 0.476243857 7 A-Side 0.055721212 1.358876763 7 B-Side 0.055721212 0.831538985

% Lim it 5 A-Side 0.761624531 5 B-Side 0.380798937 6 A-Side 0.593733493 6 B-Side 0.781881958 7 A-Side 0.815272285 7 B-Side 0.431052987 Summary of M30B Quality A ssurance Checks
Run ID Volum e Sam pled (dscm)

Run ID Sorbent Trap Breakthrough (B)

≤10% of Section 1 Hg

mass for Hg conc. >1
μg/dscm: or ≤20% of Section 1 for Hg conc. ≤1 μg/dscmSample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting

Information

Total Vapor Phase Me rcury Emission Rate Sample 3 (lb/MMBtu) Test Method Used (ex. U.S. EPA Method 30B) Other Supporting

Information 1.65331E-05

Total Mass (ng) Section 2 Sections 1+2 (ng) (ug)

0.97 127.3593432 0 127.3593432 0.127359343 0.97 254.7276019 120 134.7276019 0.134727602 1.45754717 246.9460008 120 126.9460008 0.126946001 0.97 124.0596474 0 124.0596474 0.124059647 0.995283019 123.0751129 0 123.0751129 0.123075113 0.97 225.0303395 120 105.0303395 0.10503034

Stop per tube per run per tube per run

10:28 1.838807643 1.838807643 0.044902406 0.044902406 10:28 1.949121378 1.949121378 0.047596191 0.047596191 13:08 1.836563977 1.836563977 0.045682677 0.045682677 13:08 1.794179108 1.794179108 0.044628396 0.044628396 Summary of Hg Collected on Sorbent Traps via Method 30B Initial Spike (ng) Total Non-spike

Individual Sorbent Tube Emission Summary, Method 30B Run Time Hg Emissions(lb/Tbtu) Hg Emissions (lb/hr)15:22 1.788479514 1.788479514 0.044670388 0.044670388 15:22 1.518143876 1.518143876 0.037918285 0.037918285 1.787549249 0.044233057

Lim it Abs. diff. % Lim it

C rec R (%) by Run R (%) by

program Lim it

≥ 10 % RD mass for Hg conc. >1 μg/dscm: or ≤20% RD or ≤0.2 μg/dscm abs.diff. for Hg conc. ≤1μg/dscm 0.042384868 1.167388253 Summary of M30B Quality A ssurance Checks Paired Trap Agreement (RD)

Measured Spike Recovery ( R )

2.260079815 106.3542754
97.73669418 Average Recovery

, between 85 and 115% 2.217488173 102.4414203

1.833173586 84.41438679 0.270335638 8.175579937 ≤20% of field recovery

test 0.110313735 2.912243971per tube per run

393.3450788 393.3450788 416.9426338 416.9426338 400.1802463 400.1802463 390.944746 390.944746 Hg Emissions (lb/yr)*391.3125989 391.3125989

332.1641767 332.1641767

387.4815801EIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Me rcury Species Me rcury Emission Rate Sample 1 (lb/MMBtu) Hg 0 Hg +2 Hg PSample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting

Information

Me rcury Emission Rate Sample 2 (lb/MMBtu) Me rcury Emission Rate Sample 3 (lb/MMBtu) Test Method Used

(ex. ASTM Method D6784) Other Supporting InformationEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Compound (use drop down to define for as many

rows as needed) Volatile Organic HAP Emission Rate Sample

1 (lb/MMBtu) Volatile Organic HAP

Emission Rate Sample

1 (ppmvd @ 7% O2) Speciated Volatile Organic HAP Emission DataSample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting

Information

Volatile Organic HAP Emission Rate Sample 2 (lb/MMBtu) Volatile Organic

HAP Emission Rate Sample 2 (ppmvd @ 7% O2) Volatile Organic HAP Emission Rate Sample 3 (lb/MMBtu) Volatile Organic

HAP Emission Rate Sample 3 (ppmvd @ 7% O2)Test Method Used Other Supporting InformationEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Compound (use drop down to define for as many rows as needed) Semi-Volatile Organic HAP Emission Rate Sample 1 (lb/MMBtu) Semi-Volatile Organic HAP Emission Rate Sample 1 (ppmvd @ 7% O2) Am inoazobenzene Speciated Semi Volatile Organic HAP Emission DataSample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method

Semi-Volatile Organic HAP Emission Rate Sample 2 (lb/MMBtu) Semi-Volatile Organic HAP Emission Rate Sample 2 (ppmvd @ 7% O2) Semi-Volatile Organic HAP Emission Rate Sample 3 (lb/MMBtu)Other Supporting Information

Semi-Volatile Organic HAP Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method UsedOther Supporting InformationEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Sample 3 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3

Emission Test Results Hydrogen Cyanide Emission Rate Sample 1 (lb/MMBtu) Hydrogen Cyanide

Emission Rate Sample 2 (lb/MMBtu) Hydrogen Cyanide

Emission Rate Sample 3 (lb/MMBtu)Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Unit of Measure Fuel Flow Measurement Method

Test Method Used (ex. U.S. EPA

Conditional Test Method 033) Other Supporting InformationOther Supporting InformationEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Constituent Nitrogen Oxides Emission Rate Sample 1 (lb/MMBtu) NO NO 2Sample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method

Nitrogen Oxides Emission Rate

Sample 1 (ppmvd @ 7% O2) Nitrogen Oxides Emission Rate Sample 2 (lb/MMBtu) Nitrogen Oxides Emission Rate Sample 2 (ppmvd @ 7% O2)Other Supporting Information

Nitrogen Oxides Emission Rate

Sample 3 (lb/MMBtu) Nitrogen Oxides Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA

Method 7)Other Supporting

InformationEIA

Facility Code Facility Name Boiler ID 298 Lim estone Lim 2

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Constituent Constituent Emission Rate Sample 1 (mg solids/liter) Total Dissolved Solids (TDS) Total Suspended Solids (TSS)Sample 3 Unit of Measure

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure

Constituent Emission Rate

Sample 2 (mg solids/liter) Constituent Emission Rate Sample 3 (mg solids/liter)Other Supporting Information

Fuel Flow Measurement Method

Test Method Used (ex. Standard Test Method for Filterable and Nonfilterable Matter in Water ASTM D5907)Other Supporting

Information

Other Supporting Information