# Ony xEnvironmenta l Service s Sauget , Illinois

Evaluationo

f Metals , Particulat

e Matter, Hydroge

n Chloride/ChlorineGa

s and PCDD/PCD F Emission s fo r Incinerator

s 2, 3 an d 4 Novembe

r200 2 Tes tProgra m

ENS R Corporatio n Januar y200 3 Documen t Numbe r10002-005-40 0

### m i CONTENT S

1. 0 INTRODUCTIO N 1-1 1. 1 Progra m Summar y1- 1 1. 2 Fiel d Progra m Schedul e 1- 1
2. 0 SUMMAR YO F RESULT S 2- 1 2. 1 Introductio n •2- 1 2. 2 Stac k

Emissio n Result s fo rPCDDs/PCDF s 2- 1 2. 3 Stac k

Emissio n Result s fo rTarge tMetal s 2- 1 2. 4 Stac k

Emissio n Result s fo rParticulat e matter , HCI , an d Cl 22- 2
3. 0 SAMPLIN G AN D ANALYTICA L PROCEDURE S 3- 1 3. 1 Samplin g Procedure s 3- 1 3.1. 1 Velocity , Moistur e an d Fixe d Ga s Determination s 3- 1 3.1. 2 PCDD/PCD F Samplin g 3- 1 3.1. 3 Metal s Samplin g 3- 1 3.1. 4 PM/HCI/CI 2Samplin g Procedur e 3- 1 3. 2 Analytica l Procedure s 3- 2 3.2. 1 PCDD/PCD F Analyse s 3- 2 3.2. 2 Metal s Analyse s 3- 2 3.2. 3 PM/HCI /CI 2 Analysi s 3- 2
4. 0 QUALIT YASSURANC E 4- 1 4. 1 Introductio n 4- 1 4. 2 Stac k

Samplin g QA/Q C 4- 1 4. 3 Chain-of-Custod y4- 2 4. 4 Analytica l QA/Q C 4- 2 4.4. 1 Analysi s fo rMetal s 4- 2 4.4. 2 Analysi s fo rPCDDs/PCDF s 4- 3

J:\Air_Tox\Proje d Files\Onyx\Ony x200 2 work\Novembe r2002\Report\Report j January , 200 3 Nov02.do cINTERNATIONAL CONTENT S - CONTINUE D 4.4. 3 Analysi s fo rParticulat e Matte r4- 3 4.4. 4 Analysi s fo rHCI/CI 24- 3
APPENDICE S
A - FIEL D DAT ASHEET S B - PROCES S FEE D AN D OPERATIN G CONDITION S C - FIEL D EQUIPMEN TCALIBRATIO N FORM S D - ANALYTICA L DAT AREPORT S

J:\Air_Tox\Projec t Files\Onyx\Onyx2002 work\Novembe r2002\Report\Report Nov02.do c i i January , 200 3

### EIBR . INTERNATIONAL 

### LIS TO F TABLE S

TABL E 2- 1 ONY XFIXE D HEART H INCINERATO R UNI T2 PCDD/PCD F EMISSIO N RESULT S - TE Q BASI S . . 2- 3 TABL E 2- 2 ONY XFIXE D HEART H INCINERATO R UNI T2 PCDD/PCD F EMISSIO N RESULT S - CONGENE R

CLAS S TOTAL S 2-4 TABL E 2- 3 ONY XFIXE D HEART H INCINERATO R UNI T3 PCDD/PCD F EMISSIO N RESULT S - TE Q BASI S . . 2- 5 TABL E 2- 4 ONY XFIXE D HEART H INCINERATO R UNI T3 PCDD/PCD F EMISSIO N RESULT S - CONGENE R

CLAS S TOTAL S 2- 6 TABL E 2- 5 ONY XROTAR YKIL N UNI T4 PCDD/PCD F EMISSIO N RESULT S - TE Q BASI S 2- 7 TABL E 2- 6 ROTAR YKIL N UNI T4 PCDD/PCD F EMISSIO N RESULT S - CONGENE R CLAS S TOTAL S 2- 8 TABL E 2- 7 SUMMAR YO F HW C MAC TMETAL S EMISSION S FO R UNI T2 2- 9 Tabl e 2- 8 Summar yo fIndividua l Metal s Emission s fo rUni t2 2-1 0 Tabl e 2- 9 Summar yo fHW C MAC TMetal s Emission s fo rUni t3 2-1 3 TABL E 2-1 0 SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T3 2-1 4 Tabl e 2-1 1 SUMMAR YO F HW C MAC TMETAL S EMISSION S FO R UNI T4 2-1 7 TABL E 2-1 2 SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T4.. . 2-1 8 Tabl e 2-1 3 PM/HCI/CI 2EMISSIO N RESULT S FO R UNI T2 2-2 1 Tabl e 2-1 4 PM /

HC I / Cl 2EMISSIO N RESULT S FO R UNI T3 2-2 2 Tabl e 2-1 5 PM /

HC I / Cl 2EMISSIO N RESULT S FO R UNI T4 2-2 3

J:\Aif_Tox\Frojec t Fi!es\Onyx\Onyx200 2 work\Novembe r2002\Report\Report jj j January , 200 3 Nov02.do c

### EMIR . /NTERf/ATIONAL 

### 1. 0 INTRODUCTIO N
1. 1 Progra m Summar y ENS R Internationa l wa s retaine d b yOny xEnvironmenta l Services , Sauget , Illinoi s t o conduc t stac k ga s emissio n samplin g durin g th e wee k o fNovembe r18 , 200 2 o n thre e incinerator s a t th e facility
. Uni t2 , Uni t3 an d Uni t4 wer e teste d fo rdioxin s an d furan s i n accordanc e wit h EP A Metho d 0023 , twelv e (12 ) metals 1 i n accordanc e wit h EP AMetho d 2 9 an d particulat e matte r(PM) , hydroge n chlorid e (HCI) , an d chlorin e (Cl 2 ) i n accordanc e t o EP AMetho d 26A
. Stac k flow s wer e determine d b ypito ttube/wate rmanomete ra s par to fth e actua l samplin g process . Stac k moistur e w a s determine d b ymeasurin g th e volum e gaine d i n th e samplin g trai n durin g sampling
. Oxyge n an d carbo n dioxid e wer e determine d b ycollectin g a Tediar ® ba g sampl e followe d b yORSA T analysis
. Metho d 002 3 sample s wer e labeled , package d an d shippe d followin g accepte d protocol s t o Alt a Analytica l Inc. , E l Dorad o Hills , C Afo rdioxi n an d fura n analysis
. Metho d 2 9 sample s wer e labeled , package d an d shippe d followin g accepte d protocol s t o PS C Analytica l Service s Inc. , Burlington , Ontari o (Canada)
. Th e front-hal ffraction s fro m th e Metho d 005 0 samplin g trai n (front hal frins e an d particulat e filter ) wer e labeled , package d an d shippe d followin g accepte d protocol s t o ENSR' s Ai rToxic s Laborator yi n Harvar d M Awher e the ywer e subjecte d t o gravimetri c analysis
. Back-hal ffraction s fro m thi s samplin g trai n wer e als o sen tt o PS C Analytica l Service s Inc. , Burlington , Ontari o fo rHC I an d Cl 2determination
. Th e HC I an d Cl 2analyse s wer e performe d i n accordanc e wit h EP AMetho d 905 7 (io n chromatography)
. I n additio n t o progra m samples , ENS R prepare d tw o fiel d blank s fo ranalysis , on e fo reac h incinerato rstack
. 

### 1. 2 Fiel d Progra m Schedul e T h e tes twa s complete d ove ra five-da ytim e fram e a s follows : Novembe r1 8 - Trave l t o th e sit e an d se t u p o n stac k o fUni t3 ; Novembe r1 9 - Complete d Ru n 1 an d 2 o n Uni t3 ; mov e an d set-u p equipmen to n Uni t2 ; Novembe r2 0 - Complete d Ru n 1 an d 2 o n Uni t2 , mov e an d set-u p equipmen to n Uni t4 ; Novembe r2 1 - Complete d Ru n 1 an d 2 , o n Uni t3 ; Novembe r2 2 - Complete d ru n 3 o n Uni t4 , prepare d sample s fo rshipment , departe d site
.

1 Thes e metal s included : antimony , arsenic , barium , beryllium , cadmium , chromium , lead , mercury , nickel , selenium , silve ran d thallium
.

J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002\Report\Backu p o f Report Nov02.wb k 1- 1 January , 200 3

### ENS R INTEKNATIONAL 

### 1. 0 INTRODUCTIO N

1. 1 Progra m Summar y ENS R Internationa l wa s retaine d b yOny xEnvironmenta l Services , Sauget , Illinoi s t o conduc t stac k ga s emissio n samplin g durin g th e wee k o fNovembe r18 , 200 2 o n thre e incinerator s a t th e facility
. Uni t2 , Uni t3 an d Uni t4 wer e teste d fo rdioxin s an d furan s i n accordanc e wit h EP A Metho d 0023 , twelv e (12 ) metals 1 i n accordanc e wit h EP AMetho d 2 9 an d particulat e matte r(PM) , hydroge n chlorid e (HCI) , an d chlorin e (Cl 2 ) i n accordanc e t o EP AMetho d 26A
. Stac k flow s wer e determine d b ypito ttube/wate rmanomete ra s par to fth e actua l samplin g process . Stac k moistur e w a s determine d b ymeasurin g th e volum e gaine d i n th e samplin g trai n durin g sampling
. Oxyge n an d carbo n dioxid e wer e determine d b ycollectin g a Tediar ® ba g sampl e followe d b yORSA T analysis
. Metho d 0023 Asample s wer e labeled , package d an d shippe d followin g accepte d protocol s t o Alt a Analytica l Inc. , E l Dorad o Hills , C Afo rdioxi n an d fura n analysis
. Metho d 2 9 sample s wer e labeled , package d an d shippe d followin g accepte d protocol s t o PS C Analytica l Service s Inc. , Burlington , Ontari o (Canada)
. Th e front-hal ffraction s fro m th e Metho d 26 Asamplin g trai n (front hal frins e an d particulat e filter ) wer e labeled , package d an d shippe d followin g accepte d protocol s t o ENSR' s Ai rToxic s Laborator yi n Harvar d M Awher e the ywer e subjecte d t o gravimetri c analysis
. Back-hal ffraction s fro m thi s samplin g trai n wer e als o sen tt o PS C Analytica l Service s Inc. , Burlington , Ontari o fo rHC I an d Cl 2determination
. Th e HC I an d Cl 2analyse s wer e performe d i n accordanc e wit h EP AMetho d 905 7 (io n chromatography)
. I n additio n t o progra m samples , ENS R prepare d tw o fiel d blank s fo ranalysis , on e fo reac h incinerato rstack
. 

### 1. 2 Fiel d Progra m Schedul e T h e tes twa s complete d ove ra five-da ytim e fram e a s follows : Novembe r1 8 - Trave l t o th e sit e an d se t u p o n stac k o fUni t3 ; Novembe r1 9 - Complete d Ru n 1 an d 2 o n Uni t3 ; mov e an d set-u p equipmen to n Uni t2 ; Novembe r2 0 - Complete d Ru n 1 an d 2 o n Uni t2 , mov e an d set-u p equipmen to n Uni t4 ; Novembe r2 1 - Complete d Ru n 1 an d 2 , o n Uni t4 ;

1 Thes e metal s included : antimony , arsenic , barium , beryllium , cadmium , chromium , lead , mercury , nickel , selenium , silve ran d thallium
.

J:\Air_Tox\Projec t Files\Onyx\Onyx200 2 work\Novembe r2002\Report\Report Nov02.do c 1- 1 January , 200 3INTERNATIONAL

Novembe r2 2 - Complete d ru n 3 o n Uni t4 , prepare d sample s fo rshipment , departe d site
.

J:\Air_Tca\Projec t Files\Onyx\Onyx200 2 work\Novernbe r2002\Repoit\Report Nov02.do c 1- 2 January , 200 3

### ewer . INTERNAT/ONAL 

### 2. 0 SUMMAR YO F RESULT S

2. 1 Introductio n Thi s sectio n summarize s th e tes tprogra m results
. Emission s dat a ar e summarize d i n thi s sectio n an d fee d an d proces s operatin g dat a ar e include d i n Appendi xB
. 2. 2 Stac k

Emissio n Result s fo rPCDDs/PCDF s Asummar yo fth e PCDD/PCD F emissio n result s o n a TE Q basi s fo rUni t2 , Uni t3 an d Uni t4 ar e include d i n Table s 2-1 , 2-3 , an d 2- 5 respectively
. I t shoul d b e note d tha ti t wa s necessar yt o perfor m a pos ttes tcalibratio n o n th e mete rbo xtha twa s use d fo rth e M23 Asamplin g trai n (Bo x# 80754)
. Th e resultan tcalibratio n facto ran d Delt a H wer e utilize d fo remission s calculation s i n accordanc e wit h th e specifie d metho d criteri a i n sectio n 4
. Fo rfurthe rdiscussio n regardin g th e Metho d 5 post-tes t calibratio n procedure , pleas e refe rt o sectio n 4.2
. Thes e result s indicat e that :

. Th e PCDD/PCD F emission s fo rUni t2 (averag e emission s fo rrun s 1 an d 2 wer e 0.0 7 ng/m 3@ 7 % 0 2 ) ar e belo wth e HW C MAC Temissio n standar d o f0. 4 ng/m 3@ 7 % 0 2 ;

. Th e PCDD/PCD F emission s fo rUni t3 (averag e emission s fo rrun s 1 an d 2 wer e 0.0 4 ng/m 3@ 7 % 0 2 ) ar e belo wth e HW C MAC Temissio n standar d o f0. 4 ng/m 3@ 7 % 0 2 ;

. Th e PCDD/PCD F emission s fo rUni t4 (averag e emission s fo rrun s 1 , 2 , an d 3 wer e 0.0 6 ng/m 3@ 7 % 0 2 ) ar e belo wth e HW C MAC Temissio n standar d o f0. 2 ng/m 3@ 7 % 0 2 ; 2. 3 Stac k

Emissio n Result s fo rTarge t Metal s Asummar yo fth e metal s emission s fo ral l incinerator s i s include d i n table s 2- 7 throug h 2-12
. Table s 2-8,2-1 0 an d 2-1 2 provid e a detaile d summar yofth e individua l metal s emission s fo ral l twelv e metals
. Asummar yo fmetal s emission s categorize d b yLo wVolatil e Metal s (LVM) , Semi-volatil e Metal s (SVM ) an d mercur yi s provide d i n Table s 2-7 , 2- 8 an d 2-11
. Th e targe tmetal s result s indicat e that :

. Th e LV M an d SV M metal s emission s fo rUni t2 (averag e emission s fo rrun s 1 an d 2 wer e < 34.2 1 pg/m 3@ 7 % 0 2fo rLVM s an d 8.4 4 pg/m 3@ 7 % 0 2fo rSVMs ) wer e lowe rtha n th e ne wHW C MAC Temissio n standard s o f9 7 pg/m 3an d 24 0 pg/m 3(correcte d t o 7 % 0 2 ) fo rLVM s an d SVM s respectively ; Th e mercur yemission s fo rUni t2 (averag e fo rrun s 1 an d 2 wer e 155.4 2 pg/m 3@ 7 % 0 2 ) wer e abov e th e ne wHW C MAC Temissio n standar d o f13 0 pg/m 3@ 7 % 0 2 ; Th e LV M an d SV M metal s emission s fo rUni t3 (averag e emission s fo rrun s 1 an d 2 wer e < 12.2 3 pg/m 3@ 7 % 0 2fo rLVM s an d 4.7 1 pg/m 3@ 7 % 0 2fo rSVMs ) wer e lowe rtha n th e ne wHW C MAC Temissio n standard s o f9 7 pg/m 3an d 24 0 pg/m 3(correcte d t o 7 % 0 2 ) fo rLVM s an d SVM s respectively ;

J:\Air_Tox\Prpjec t Rles\OnyxM0nyx200 2 wofX\Novembe r2002\Report\Report Nov02.do c 2- 1 January , 200 3/AITERflAr/ONAL Th e mercur yemission s fo rUni t3 (averag e fo rrun s 1 an d 2 wer e 101.3 5 ug/m 3@ 7 % 0 2 ) wer e lowe rtha n th e ne wHW C MAC Temissio n standar d o f13 0 pg/m 3@ 7 % 0 2 . Th e LV M an d SV M metal s emission s fo rUni t4 (averag e emission s fo rthre e (3 ) run s wer e < 10.2 6 ug/m 3@ 7 % 0 2fo rLVM s an d 8.8 0 pg/m 3@ 7 % 0 2fo rSVMs ) wer e lowe rtha n th e ne wHW C MAC Temissio n standard s o f9 7 pg/m 3an d 24 0 pg/m 3(correcte d t o 7 % 0 2 ) fo rLVM s an d SVM s respectively ; Th e mercur yemission s fo rUni t4 (averag e emission s fo rthre e (3 ) run s wer e 459.1 7 pg/m 3@ 7 % 0 2 ) wer e abov e th e ne wHW C MAC Temissio n standar d o f13 0 pg/m 3 @ 7 % 0 2 . 2. 4 Stac k

Emissio n Result s fo rParticulat e matter , HCI , an d Cl 2 Asummar yofth e PM/HCI/CI 2emission s fo rbot h incinerator s i s provide d i n Table s 2-1 3 throug h 2-15
. Th e dat a se tshow s emission s o fP M t o b e belo wth e MAC Tlimi to f3 4 mg/dsc m (0.01 5 gr/dscf)
. Emissio n level s fo rHC I an d Cl 2wer e als o wel l belo wth e MAC Tlimi to f7 7 ppm . Th e result s fo rUnit s 2 , 3 an d 4 wer e a s follows :

. Th e particulat e matte remission s fo rUni t2 (averag e emission s fo rrun s 1 an d 2 wer e 5. 3 mg/dsc m @ 7 % 0 2 )
.

. Th e particulat e matte remission s fo rUni t3 (averag e emission s fo rrun s 1 an d 2 wer e 3. 0 mg / dsc m @ 7 % 0 2 )
.

. Th e particulat e matte remission s fo rUni t4 (averag e emission s fo rthre e (3 ) run s wer e 4. 3 mg / dsc m @ 7 % 0 2 )
.
•Th e HCl/CI 2emission s fo rUni t2 (averag e emission s fo rrun s 1 an d 2 wer e 10.7 2 ppm , @7 % 0 2 )
.

. Th e HCI/CI 2emission s fo rUni t3 (averag e emission s fo rrun s 1 an d 2 wer e 8.3 1 ppm , @7 % 0 2 )
.

. Th e HCI/CI 2emission s fo rUni t4 (averag e emission s fo rthre e (3 ) run s wa s 11.3 5 ppm , @7 % 0 2 )
.

J:\Air_Tox\ProJect Files\Onyx\Ony x200 2 work\Novembe r2002\Report\Report No\02.do c 2- 2 January , 200 3MrERNAriONAL

TABL E 2- 1 ONY XFIXE D HEART H INCINERATO R UNI T2 PCDD/PCD F EMISSIO N RESULT S - TE Q BASI S
Ru n No . Dat e Star t Tim e Sto p Tim e Unit s 1 20-Nov-0 2 08:1 5 11:3 1 20-NOV-0 2 12:1 5 15:1 8 Sampl e Volum e dsc f 141.21 8 121.47 9 Sampl e Volum e m J 4.0 0 3.4 4 Moistur e Conten t % v/ v 38. 8 38. 1 0 2Cone
. % v/ v(dry ) 11.0 0 11.0 0 C 0 2Cone
. % v/ v(dry ) 4.7 0 4.1 0 Isokinetic s % 10 7 10 6 Stac k Flowrat e dscf m 6,12 6 5,34 1 PCDD/PCD F Parameter s TE F (a ) pg / sampl e ng/m 3

T E Q pg /

sampl e ng/m 3

T E Q 2,3,7,8-TCD D 1,2,3,7,8-PeCD D 1,2,3,4,7,8-HxCD D 1.2.3.6.7.8

- HxCDD , 1.2.3.7.8.9

- HxCD D 1,2,3,4,6,7,8-HpCD D OCD D 1.0 0 0.5 0 0.1 0 0.1 0 0.1 0 0.0 1 0.0 0 3

2 1 2 4 7 2 5 2 57 6 51 1 8.5E-0 4

2.6E-0 3 6.0E-0 4 1.8E-0 3 1.3E-0 3 1.4E-0 3 1.3E-0 4 9

4 1 4 0 11 9 8 8 83 9 80 2 2.5E-0 3

5.9E-0 3 1.2E-0 3 3.5E-0 3 2.6E-0 3 2.4E-0 3 2.3E-0 4 2,3,7,8-TCD F 1,2,3,7,8-PeCD F 2,3,4,7,8-PeCD F 1,2,3,4,7,8-HxCDF1,2,3,6,7,8-HxCD F 2.3.4.6.7.8- HxCD F 1.2.3.7.8.9

- HxCD F 1.2.3.4.6.7.8

- HpCD F 1.2.3.4.7.8.9

- HpCD F OCD F 0.1 0 0.0 5 0.5 0 0.1 0 0.1 0 0.1 0 0.1 0 0.0 1 0.0 1 0.0 0 3 8

5 4 9 3 10 1 6 7 9 6 2 5 27 3 1 9 6 5 9.5E-0 4

6.8E-0 4 1.2E-0 2 2.5E-0 3 1.7E-0 3 2.4E-0 3 6.3E-0 4 6. 8 E-0 4 4.9E-0 5 1. 6 E-0 5 7 9

10 3 19 5 17 9 12 5 19 4 5 1 42 1 3 4 9 5 2.3E-0 3

1.5E-0 3 2.8E-0 2 5.2E-0 3 3.6E-0 3 5.6E-0 3 1.5E-0 3 1.2E-0 3 9.9E-0 5 2.8E-0 5 TOTA L TOTA L TOTA L TOTA L TOTA L TOTA L TOTA L TOTA L TCD D PeCD D HxCD D HpCD D TCD F PeCD F HxCD F HpCD F 0.0 0

0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 1,56 0

2,05 0 5,04 0 1,29 0 1,20 0 97 4 76 2 33 5 0.0E+0 0

0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 O.OE+0 0 3,73 0

4,37 0 8,74 0 1,94 0 2,71 0 2,08 0 1,47 0 60 9 0.0E+0 0

0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+O 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 TOTA LTEQ s (ng/m 3 ) 0.0 3 TOTA LTEQ s (ng/m 3@ 7 % Q 1 ) 0.0 4 TOTA LTEQ s (g/s ) 8.6E-1 1 0.0 7 0.0 9 1.7E-1 0 (a ) U.S.EP A(1989 ) Toxi cEquivalenc yFacto r
= MD Lvalu e fo ra N D J:\Air_Tox\Projec t FIIes\Onyx\Ony x200 2 work\Novembe r2002\Field\Uni t 2\[M2 9 U2.xls]DAT A

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### ENSR . /NTERNAT/ONAL
TABL E 2-2 ONY XFIXE D HEART H INCINERATO R UNI T2 PCDD/PCD F EMISSIO N RESULTS CONGENE R CLAS S TOTAL S
Ru n No . 1 2 Dat e 20-Nov-0 2 20-Nov-0 2 Start Tim e 08:1 5 12:1 5 Sto p Tim e 1 I n it e 11:3 1 15:1 8 Sampl e Volum e dsc f 141.21 8 121.47 9 Sampl e Volum e m 3 3.99 9 3.4 4 Moistur e Conte i % v/ v 38. 8 38. 1 0 2Cone
. % v/ v(dry) 11. 0 11. 0 C O zCone
. % v/ v(dry) 4. 7 4. 1 Isokinetic s 

### % 10 7 10 6 Stac k Flowrat e dscf m 6,12 6 5,34 1 PCDD/PCD F pg / pg / Parameter s sampl e ng/m 3 sampl e ng/m 3 TOTA LTCD D 1,56 0 3.9E-0 1 3,73 0 1.1E+0 0 TOTA L PeCD D 2,05 0 5. 1 E-0 1 4,37 0 1.3E+0 0 TOTA LHxCD D 5,04 0 1.3E+0 0 8,74 0 2.5E+0 0 TOTA L HpCD D 1,29 0 3.2E-0 1 1,94 0 5. 6 E-0 1 OCD D 51 1 1.3E-0 1 80 2 2.3E-0 1 TOTA L TCD F 1,20 0 3.0E-0 1 2,71 0 7.9E-0 1 TOTA LPeCD F 97 4 2.4E-0 1 2,08 0 6.0E-0 1 TOTA LHxCD F 76 2 1.9E-0 1 1,47 0 4.3E-0 1 TOTA L HpCD F 33 5 8.4E-0 2 60 9 1.8E-0 1 OCD F 6 5 1.6E-0 2 9 5 2.8E-0 2

•:•:•TOTA L tetra-oct a (ng/m 3) 

### = 3. 4 7. 7 :•:•TOTA L tetra-oct a (ng/m 1 @ 7 % 0 2 ) 

### = 4. 8 10. 8 : : : TOTA L tetra-oct a (g/s) 

### = 1.0E-0 8 1.9E-0 8

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### Elftt t INTERNATIONAL
TABL E 2- 3 ONY XFIXE D HEART H INCINERATO R UNI T3 PCDD/PCD F EMISSIO N RESULT S - TE Q BASI S
Ru n No . Dat e Start Tim e Sto p Tim e Unit s 1 19-NOV-0 2 09:4 5 12:5 6 19-NOV-0 2 13:3 5 16:3 7 Sampl e Volum e dsc f 122.34 7 121.29 1 Sampl e Volum e n r 3.4 6 3.4 3 Moistur e Conten t % v/ v 37. 3 37. 1 0 2Cone
. % v/ v(dry ) 13.1 0 13.6 0 C 0 2Cone
. % v/ v(dry ) 4.3 0 3.4 0 Isokinetic s % 10 8 10 0 Stac k Flowrat e dscf m 5,15 0 5,47 2 PCDD/PCD F Parameter s TE F (a ) pg / sampl e ng/m 3

T E Q pg /

sampl e ng/m 3

TE Q 2,3,7,8 -TCD D 1,2,3,7,8 -PeCD D 1,2,3,4,7,8 -HxCD D 1.2.3.6.7.8 - HxCD D 1.2.3.7.8.9 - HxCD D 1,2,3,4,6,7,8 -HpCD D OCD D 1.0 0 0.5 0 0.1 0 0.1 0 0.1 0 0.0 1 0.0 0 : 4

1 0 1 3 3 1 2 2 21 7 36 9 1. 1 E-0 3

1.5E-0 3 3.8E-0 4 9.0E-0 4 6.2E-0 4 6.3E-0 4 1. 1 E-0 4 2 5

2 2 5 7 3 5 45 5 70 7 2.2E-0 3

3.6E-0 3 6.5E-0 4 1.6E-0 3 1.OE-0 3 1.3E-0 3 2. 1 E-0 4 2,3,7,8 -TCD F 1,2,3,7,8 -PeCD F 2,3,4,7,8 -PeCD F 1,2,3,4,7,8 -HxCD F 1,2,3,6,7,8 -HxCD F 2.3.4.6.7.8 - HxCD F 1.2.3.7.8.9 - HxCD F 1.2.3.4.6.7.8 - HpCD F 1.2.3.4.7.8.9 - HpCD F OCD F 0.1 0 0.0 5 0.5 0 0.1 0 0.1 0 0.1 0 0.1 0 0.0 1 0.0 1 0.0 0 2 5

2 7 4 2 4 2 3 2 3 9 1 1 19 3 8 10 1 7. 1 E-0 4

3.9E-0 4 6. 1 E-0 3 1.2E-0 3 9.2E-0 4 1. 1 E-0 3 3. 1 E-0 4 5.6E-0 4 2.2E-0 5 2.9E-0 5 3 7

4 3 7 0 6 0 4 7 6 5 1 8 20 6 1 1 9 2 1. 1 E-0 3

6.2E-0 4 1.0E-0 2 1.7E-0 3 1.4E-0 3 1.9E-0 3 5. 1 E-0 4 6.0E-0 4 3.2E-0 5 2.7E-0 5 TOTA L TOTA L TOTA L TOTA L TOTA L TOTA L TOTA L TOTA L TCD D PeCD D HxCD D HpCD D TCD F PeCD F HxCD F HpCD F 0.0 0

0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 49 6

57 4 1,18 0 48 9 80 8 52 0 34 1 21 7 0.0E+0 0

O.OE+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 O.OE+0 0 0.0E+0 0 0.0E+0 0 1,31 0

1,35 0 3,02 0 1,03 0 1,12 0 84 2 53 2 24 2 0.0E+0 0

0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 TOTA LTEQ s (ng/m 3 ) 0.0 2 TOTA LTEQ s (ng/m 3@ 7 % Q 2 ) 0.0 3 TOTA LTEQ s (g/s ) 4.0E-1 1 0.0 3 0.0 5 7.4E-1 1 (a ) U.S.EP A(1989 ) Toxi cEquivalenc yFacto r | | = MD Lvalu e fo ra N D J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worirtNovembe r2002\FieW\Uni t 3\[M2 9 U3.xls]DAT A

J:\Air_Tox\Proiec t Files\Onyx\Onyx200 2 work\Novembe r2002\Report\Report 2- 5 Nov02.do c January , 200 3INTERNATIONAL
TABL E 2-4 ONY XFIXE D HEART H INCINERATO R UNI T3 PCDD/PCD F EMISSIO N RESULT S - CONGENE R CLAS S TOTAL S
Ru n No . Dat e Start Tim e Sto p Tim e 1 19-Nov-0 2 09:4 5 12:5 6 2 19-Nov-0 2 13:3 5 16:3 7 Sampl e Volum e Unit s dsc f 122.34 7 121.29 1 Sampl e Volum e m 3 3.46 5 3.4 3 Moistur e Conte i % v/ v 37. 3 37. 1 0 2Cone
. % v/ v(dry) 13. 1 13. 6 C O zCone
. % v/ v(dry) 4. 3 3. 4 Isokinetic s % 10 8 10 0 Stac k Flowrat e dscf m 5,15 0 5,47 2 PCDD/PCD F pg / pg / Parameter s sampl e ng/m 3 sampl e ng/m 3 TOTA LTCD D 49 6 1.4E-0 1 1,31 0 3. 8 E-0 1 TOTA LPeCD D 57 4 1.7E-0 1 1,35 0 3.9E-0 1 TOTA LHxCD D 1,18 0 3.4E-0 1 3,02 0 8.8E-0 1 TOTA LHpCD D 48 9 1.4E-0 1 1,03 0 3.0E-0 1 OCD D 36 9 1. 1 E-0 1 70 7 2. 1 E-0 1 TOTA LTCD F 80 8 2.3E-0 1 1,12 0 3.3E-0 1 TOTA LPeCD F 52 0 1.5E-0 1 84 2 2.5E-0 1 TOTA LHxCD F 34 1 9.8E-0 2 53 2 1.5E-0 1 TOTA LHpCD F 21 7 6.3E-0 2 24 2 7.0E-0 2 OCD F 10 1 2.9E-0 2 9 2 2.7E-0 2
TOTA L tetra-oct a (ng/m 3 ) 

### = 1. 5 3. 0 •:•: •TOTA L tetra-oct a (ng/m 3@ 7 % 0 2 ) 

### = 2. 6 5. 6 :•:•: TOTA L tetra-oct a (g/s) 

### = 3.6E-0 9 7.7E-0 9

J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worttNovembe r2002\Fie!d\Uni t 3\IM2 9 U3.xls]DAT A

J:VAiO"ox\Project Files\Onyx\Ony x200 2 work\Novembe r2002\Report\Report Nov02.do c 2- 6 January , 200 3

### ENSR . INTERNATIONAL
TABL E 2-5 ONY XROTAR YKIL N UNI T4 PCDD/PCD F EMISSIO N RESULT S - TE Q BASI S

R u n No . Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-NOV-0 2 Star t Tim e 09:45 13:52 08:1 5 Sto p Tim e 1 1 nif c 12:50 17:01 11:20 Sampl e Volum e u mi s dsc f 150.59 6 150.067 152.01 0 Sampl e Volum e m 3 4.2 6 4.2 5 4.3 0 Moistur e Conten t % v/ v 33. 1 34. 0 35. 0 0 2Cone
. % v/ v(dry ) 13.5 0 13.60 13.40 C 0 2Cone
. % v/ v(dry ) 3.90 3.80 4.5 0 Isokinetic s % 10 2 101 10 3 Stac k Flowrat e dscf m 19,05 4 19,14 1 18,98 6 PCD D / PCD F Parameter s TE F (a ) pg / sampl e ng/m 3

TE Q pg /

sa m pi e ng/m 3

TE Q pg/

sampl e ng/m 3

TE Q 2,3,7,8-TCD D 1,2,3,7,8-PeCD D 1,2,3,4,7,8-HxCD D 1.2.3.6.7.8- HxCD D 1.2.3.7.8.9- HxCD D 1,2,3,4,6,7,8-HpCD D OCD D 1.0 0 0.5 0 0.1 0 0.1 0 0.1 0 0.0 1 0.00 1 0

53 66 127 71 568 29 0 2.3E-0 3

6.3E-0 3 1.6E-0 3 3.0E-0 3 1.7E-0 3 1.3E-0 3 6.8E-0 5 8

4 6 63 125 7 0 576 28 3 1.9E-0 3

5.4E-0 3 1.5E-0 3 2.9E-0 3 1.6E-0 3 1.4E-0 3 6.7E-0 5 1 5

8 8 11 7 238 12 8 1,04 0 48 3 3.6E-0 3 1.0E-0 2 2.7E-0 3 5.5E-0 3 3.0E-0 3 2.4E-0 3 1.1 E-0 4 2,3,7,8-TCD F 1,2,3,7,8-PeCD F 2,3,4,7,8-PeCD F 1,2,3,4,7,8-HxCD F 1,2,3,6,7,8-HxCD F 2.3.4.6.7.8- HxCD F 1.2.3.7.8.9- HxCD F 1.2.3.4.6.7.8- HpCD F 1.2.3.4.7.8.9- HpCD F OCD F 0.1 0 0.05 0.5 0 0.1 0 0.1 0 0.1 0 0.1 0 0.0 1 0.0 1 0.00 2 1

2 7 5 7 3 8 3 6 77 1 3 100 9 2 8 4.8E-0 4

3.2E-0 4 6.6E-0 3 8.8E-0 4 8.5E-0 4 1.8E-0 3 3.0E-0 4 2.3E-0 4 2.2E-0 5 6.6E-0 6 1 9

3 1 56 36 36 74 1 5 10 6 1 2 32 4.5E-0 4

3.6E-0 4 6.6E-0 3 8.4E-0 4 8.4E-0 4 1.7E-0 3 3.6E-0 4 2.5E-0 4 2.9E-0 5 7.5E-0 6 3

5 4 5 9 5 6 1 6 3 12 0 20 15 8 1 9 39 8.1E-0 4

5.3E-0 4 1.1E-0 2 1.4E-0 3 1.5E-0 3 2.8E-0 3 4.7E-0 4 3.7E-0 4 4.3E-0 5 9. 1 E-0 6 TOTA L TCD D TOTA L PeCD D TOTA L HxCD D TOTA L HpCD D TOTA L TCD F TOTA L PeCD F TOTA L HxCD F TOTA L HpCD F TOTA L TEQ s (ng/

m TOTA L TEQ s (ng/

m TOTA L TEQ s (g/s

) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

3 ) ? @ 7 % 0 2 ) 2,31 0

2,77 0 3,04 0 1,220 4,40 0 1,24 0 55 2 14 3 O.OE+0

0 0.0E+0 0 0.0E+0 0 O.OE+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.0E+0 0 0.03 0.05 2.5E-1 0 2,17 0

2,65 0 3,040 1,220 4,49 0 1,250 56 5 159 0.0E+0 0

O.OE+0 0 O.OE+0 0 O.OE+0 0 O.OE+0 0 0.0E+0 0 O.OE+0 0 O.OE+0 0 0.03 0.05 2.4E-1 0 4,18 0

5,11 0 5,400 2,10 0 7,69 0 2,23 0 986 239 0.0E+0 0

O.OE+0 0 O.OE+0 0 0.0E+O O 0.0E+0 O O.OE+0 0 0.0E+0 0 0.0E+0 0 0.05 0.09 4.2E-1 0 (a ) U.S.EP A(1989) Toxi cEquivalenc yFacto r J:\Air_Tox\Projec l Files\OnyxVDny x200 2 work\Novembe r2002\Field\Uni t 4\[M2 3 U4.xls]DAT A

J:\Air_Tox\Projec t Files\Onyx\Onyx2002 work\Novembe r2002\Report\Report Nov02.do c 2- 7 January , 200 3

### ENSR . INTERNATIONAL
TABL E 2- 6 ROTAR YKIL N UNI T4 PCDD/PCD F EMISSIO N RESULT S - CONGENE R CLAS S TOTAL S

Ru n No . Dat e Star t Tim e Sto p Tim e Ru n 1 21-Nov-0 2 09:4 5 12:5 0 Ru n 2 21-Nov-0 2 13:5 2 17:0 1 Ru n 3 22-Nov-0 2 08:1 5 11:2 0 Sampl e Volum e unit s dsc f 150.59 6 150.06 7 152.01 0 Sampl e Volum e m 3 4.26 4 4.2 5 4.3 0 Moistur e Conte r % v/ v 33. 1 34. 0 35. 0 0 2Cone
. % v/ v(dry) 13. 5 13. 6 13. 4 C 0 2Cone
. % v/ v(dry) 3. 9 3. 8 4. 5 Isokinetic s 

### % 10 2 10 1 10 3 Stac k Flowrat e dscf m 19,05 4 19,14 1 18,98 6 PCDD/PCD F pg / pg / pg / Parameter s sampl e ng/m 3 sampl e ng/m 3 sampl e ng/m 3 TOTA LTCD D 2,31 0 5.4E-0 1 2,17 0 5. 1 E-0 1 4,18 0 9.7E-0 1 TOTA LPeCD D 2,77 0 6.5E-0 1 2,65 0 6.2E-0 1 5,11 0 1.2E+0 0 TOTA LHxCD D 3,04 0 7. 1 E-0 1 3,04 0 7.2E-0 1 5,40 0 1.3E+0 0 TOTA LHpCD D 1,22 0 2.9E-0 1 1,22 0 2.9E-0 1 2,10 0 4.9E-0 1 OCD D 29 0 6.8E-0 2 28 3 6.7E-0 2 48 3 1. 1 E-0 1 TOTA LTCD F 4,40 0 1.0E+0 0 4,49 0 1.1E+0 0 7,69 0 1.8E+0 0 TOTA LPeCD F 1,24 0 2.9E-0 1 1,25 0 2.9E-0 1 2,23 0 5.2E-0 1 TOTA LHxCD F 55 2 1.3E-0 1 56 5 1.3E-0 1 98 6 2.3E-0 1 TOTA LHpCD F 14 3 3.4E-0 2 15 9 3.7E-0 2 23 9 5.6E-0 2 OCD F 2 8 6.6E-0 3 3 2 7.5E-0 3 3 9 9. 1 E-0 3
TOTA L tetra-oct a (ng/m 3 ) 

### = 3. 8 3. 7 6. 6 TOTA L tetra-oct a (ng/m 3@ 7 % 0 2 ) 

### = 7. 0 7. 1 12. 2 TOTA L tetra-oct a (g/s) 

### = 3.4E-0 8 3.4E-0 8 5.9E-0 8

J:\Air_Tox\Projec i Files\Onyx\Ony x200 2 worMNovembe r2002\Fiel<AUni t 4\|M2 3 U4Jtls]DAT A

J:\Air_Tox\Project

Files\OnyxU3ny

x200 2 worMNovembe r2002\ReporftReport Nov02.do c 2- 8 January , 200 3

### ENSR . INTERNATIONAL
TABL E 2 - 7 SUMMAR YO F HW C MAC TMETAL S EMISSION S FO R UNI T2


### Lo wVolatil e Metal s Emission s micrograms/m 3@ 7% 0 2 Metal s Run l Run 2 Averag e A s 16.0 2 6.7 1 11.3 7 B e < 0.0 6 < 0.0 6 < 0.0 6 C r 34.9 5 10.6 2 22.7 8
. Tota l LV M < 51.0 3 < 17.3 9 < 34.2 1 LV M Regulator yStandar d = 9 7 micrograms/m 3@ 7 % O z 

### Semi-Volatil e Meta l Emission s micrograms/m 3@ 7% O 2 Metal s Ru n 1 Ru n 2 Averag e P b 7.0 9 8.2 1 7.6 5 C d 1.0 4 0.5 5 0.7 9 Tota l SV M 8.1 3 8.7 6 8.4 4 S V M Regulator yStandar d = 24 0 micrograms/m 3@ 7 % 0 2



### Mercur yEmission s micrograms/m 3@ 7% O 2 Ru n 1 Ru n 2 Averag e 127.3 3 183.5 1 155.4 2 MercuryRegulatoryStandar d = 13 0 micrograms/m 3@ 7 % 0 2 J:\Air_Tox\Projec t Files\0nyx\0ny x200 2 worMNovembe r2002\Fie!d\Uni t 2\JM2 9 U2j(ls]DAT A

J:\Air_Tox\Projec t Files\Onyx\Onyx200 2 worWNovembe r2002\ReportNRepor t Nov02.do c 2- 9 January , 200 3

### ENfeR . INTERNATIONAL Tabl e 2-8 Summar yo fIndividua l Metal s Emission s fo rUni t 2 Ru n No
. 1 2 Dat e 20-Nov-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 10:1 9 14:1 7 AVG S Samplin g Parameters — Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Volum e Metere d dc f 82.01 3 81.87 0 81.94 2 Sampl e Volum e dsc f 83.30 8 80.99 4 82.15 1 Moistur e % v/ v 40. 7 39. 4 40. 0 0 2a t Stac k % dr y 11.0 0 11.0 0 11.0 0 Avg
. Stac k

Temp
. ° F 34 3 36 1 35 2 Stac k Flowrat e dscf m 5,43 0 5,30 6 5,36 8 Isokinetic s % 10 5 10 4 10 4 Arseni c CAs

) - - LV M Quantit yCollecte d p g 27.0 0 11.0 0 19.0 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 16.0 2 6.7 1 11.3 7 Stac k Emissio n Rat e Ib/hr 2.33E-0 4 9.53E-0 5 1.64E-0 4 g/se c 2.93E-0 5 1.20E-0 5 2.07E-0 5 Bervlliu m (Be

) — LV M Quantit yCollecte d n g < 0.1 0 < 0.1 0 < 0.1 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 < 0.0 6 < 0.0 6 < 0.0 6 Stac k Emissio n Rat e lb/h r < 8.62E-0 7 < 8.67E-0 7 < 8.64E-0 7 g/se c < 1.09E-0 7 < 1.09E-0 7 < 1.09E-0 7 Tota l Chromiu m (Cr ) - LV M Quantit yCollecte d p g 58.8 9 17.3 9 38.1 4 Stac k Cone
. @ 7 % 0 2 pg/m 3 34.9 5 10.6 2 22.7 8 Stac k Emissio n Rat e Ib/hr 5.08E-0 4 1.5 1 E-0 4 3.29E-0 4 g/se c 6.40E-0 5 1.90E-0 5 4.15E-0 5 Cadmiu m (Cd ) — S V M Quantit yCollecte d p g 1.7 5 0.9 0 1.3 3 Stac k Cone
. @ 7 % 0 2 pg/m 3 1.0 4 0.5 5 0.7 9 Stac k Emissio n Rat e Ib/hr 1.5 1 E-0 5 7.80E-0 6 1.14E-0 5 g/se c 1.90E-0 6 9.83E-0 7 1.44E-0 6 Lea d (Pb) - S V M Quantit yCollecte d M g 11.9 5 13.4 5 12.7 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 7.0 9 8.2 1 7.6 5 Stac k Emissio n Rat e Ib/h r 1.03E-0 4 1.17E-0 4 1.10E-0 4 g/se c 1.30E-0 5 1.47E-0 5 1.38E-0 5 LV M Tota l = pg/m 3 51.0 3 17.3 9 34.2 1 SV M Tota l = pg/m 3 8.1 3 8.7 6 8.4 4
J:\Air_Tox\Projec t Files\0nyx\0ny x200 2 worMNovembe r2002\Field\Uni t 2\[M2 9 U2.xls]DAT AP g 1 o f3

J:\Alr_T6x\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002\Report\Report 2-1 0 Nov02.do c January , 200 3

### EtK R INTEflH/iriOIVAL
TABL E 2 - 8 (CONTINUED ) SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T2 Ru n No
. 1 2 Dat e 20-NOV-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 10:1 9 14:1 7 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Volum e Metere d dc f 82.01 3 81.87 0 81.94 2 Sampl e Volum e dsc f 83.30 8 80.99 4 82.15 1 Moistur e % v/ v 40. 7 39. 4 40. 0 0 2a t Stac k %dr y 11.0 0 11.0 0 11.0 0 Avg
. Stac k

Temp
. ° F 34 3 36 1 35 2 Stac k Flowrat e dscf m 5,43 0 5,30 6 5,36 8 Isokinetic s 

### % 10 5 10 4 10 4 Mercur y(He ) — V M Quantit yCollecte d u g 214. 6 300. 6 257. 6 Stac k Cone
. @ 7 % 0 2 pg/m 3 127. 3 183. 5 155. 4 Stac k Emissio n Rat e Ib/h r 1.85E-0 3 2.60E-0 3 2.23E-0 3 g/se c 2.33E-0 4 3.28E-0 4 2.8 1 E-0 4 Antimon y(Sb ) — Quantit yCollecte d u g 0.4 5 0.1 5 0. 3 Stac k Cone
. @ 7 % 0 2 pg/m 3 0.2 7 0.0 9 0. 2 Stac k Emissio n Rat e Ib/hr 3.88E-0 6 1.30E-0 6 2.59E-0 6 g/se c 4.89E-0 7 1.64E-0 7 3.26E-0 7 Bariu m (Ba ) — Quantit yCollecte d u g 31.8 9 43.3 9 37. 6 Stac k Cone
. @ 7 % 0 2 pg/m 3 18.9 3 26.4 9 22. 7 Stac k Emissio n Rat e lb/h r 2.75E-0 4 3.76E-0 4 3.25E-0 4 g/se c 3.46E-0 5 4.74E-0 5 4.10E-0 5 Silve r(Ae ) - Quantit yCollecte d p g 6.3 9 7.3 9 6. 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 3.7 9 4.5 1 4. 2 Stac k Emissio n Rat e Ib/h r 5.5 1 E-0 5 6.40E-0 5 5.96E-0 5 g/se c 6.94E-0 6 8.07E-0 6 7.5 1 E-0 6 Thalliu m (Ti ) - Quantit yCollecte d p g < 0.5 0 < 0.5 0 < 0. 5 Stac k Cone
. @ 7 % 0 2 pg/m 3 < 0.3 0 < 0.3 1 < 0. 3 Stac k Emissio n Rat e Ib/h r < 4.3 1 E-0 6 < 4.33E-0 6 < 4.32E-0 6 g/se c < 5.43E-0 7 < 5.46E-0 7 < 5.45E-0 7
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 workANovembe r2002\Field\Uni t 2\[M2 9 U 2 jcls]DAT AP g 2 of3

J:\Air_Tox\Projec i FiJes\Onyx\Onyx200 2 wo/x\Novembe r2002\Report\Repor t Nov02.dcx : 2-1 1 January , 200 3

### EMIR . mrefifi/ATioNAL
TABL E 2 - 8 (CONTINUED ) SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T2 Ru n No
. 1 2 Dat e 20-Nov-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 10:1 9 14:1 7 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Volum e Metere d dc f 82.01 3 81.87 0 81.94 2 Sampl e Volum e dsc f 83.30 8 80.99 4 82.15 1 Moistur e % v/v 40. 7 39. 4 40. 0 0 2a t Stac k %dr y 11.0 0 11.0 0 11.0 0 Avg
. Stac k

Temp
. ° F 34 3 36 1 35 2 Stac k Flowrat e dscf m 5,43 0 5,30 6 5,36 8 Isokinetic s % 10 5 10 4 10 4 Nicke l (Ni l - Quantit yCollecte d u g 35. 4 37.3 9 36. 4 Stac k Cone
. @ 7 % 0 2 pg/m 3 21. 0 22.8 2 21. 9 Stac k Emissio n Rat e Ib/h r 3.05E-0 4 3.24E-0 4 3.15E-0 4 g/se c 3.84E-0 5 4.08E-0 5 3.96E-0 5 Seleniu m (Se ) — Quantit yCollecte d p g 3.6 0 2.1 0 2. 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 2.1 4 1.2 8 1. 7 Stac k Emissio n Rat e Ib/h r 3.10E-0 5 1.82E-0 5 2.46E-0 5 g/se c 3.9 1 E-0 6 2.29E-0 6 3.10E-0 6
• J:\Air_Tox\Projec t Files\0nyx\0ny x200 2 worMNovembe r2002\Field\Uni l 2\[M2 9 U2J<1S]DAT

A P g 3 o f3

J:\Air_Tox\Projec t Files\Onyx\Onyx200 2 work\Novembe r2002\Report\Report 2-1 2 Nov02.do c January , 200 3INTERNATIONAL Tabl e 2-9 Summar yo fHW C MAC TMetal s Emission s fo rUni t 3


### Lo wVolatil e Metal s Emission s micrograms/m 3@ 7 % O ; ! Metal s Run l Run 2 Averag e A s 1.3 2 2.5 4 1.9 3 B e < 0.0 7 < 0.0 8 < 0.0 7 C r 9.4 8 10.9 8 10.2 3 Tota l LV M < 10.8 6 < 13.6 1 < 12.2 3 LV M Regulator yStandar d = 9 7 micrograms/m 3@ 7 % 0 2 

### Semi-Volatil e Meta l Emission s micrograms/m 3@ 7 % O 2 Metal s Ru n 1 Ru n 2 Averag e P b 3.0 6 3.0 8 3.0 7 C d 1.9 8 1.3 1 1.6 4 Tota l SV M 5.0 4 4.3 9 4.7 1 S V M Regulator yStandar d = 24 0 micrograms/m 3@ 7 % 0 2



### Mercur yEmission s micrograms/m 3@ 7 % O , 2 Ru n 1 Ru n 2 Averag e 85.8 6 116.8 5 101.3 5 MercuryRegulatoryStandar d = 13 0 micrograms/m 3@ 7 % 0 2 J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002\Field\Uni t 3U.M2 9 U 3 jdsJDAT A

J:\Air_Tox\Projec t files\0nyx\0nyx200 2 worWNovembe r2002\Repcrt\Report Nov02.do c 2-1 3 January , 200 3

### ENS ? INTERNATIONAL

TABL E 2-1 0 SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T3 Ru n No
. 1 2 Dat e 19-Nov-0 2 19-Nov-0 2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 11:5 2 15:4 5 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Volum e Metere d dc f 94.89 7 82.46 8 88.68 3 Sampl e Volum e dsc f 95.01 7 81.44 8 88.23 3 Moistur e % v/ v 37. 3 37. 5 37. 4 0 2a t Stac k % dr y 13.1 0 13.6 0 13.3 5 Avg
. Stac k

Temp
. ° F 32 8 35 5 34 2 Stac k Flowrat e dscf m 6,02 7 5,60 2 5,81 4 Isokinetic s % 10 6 9 9 10 3 Arseni c(As ) — LV M Quantit yCollecte d M 9 2.0 0 3.1 0 2.5 5 Stac k Cone
. @ 7 % O z pg/m 3 1.3 2 2.5 4 1.9 3 Stac k Emissio n Rat e Ib/hr 1.68E-0 5 2.82E-0 5 2.25E-0 5 g/se c 2.1 1 E-0 6 3.55E-0 6 2.83E-0 6 Berylliu m (Be ) — L V M Quantit yCollecte d u g < 0.1 0 < 0.1 0 < 0.1 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 < 0.0 7 < 0.0 8 < 0.0 7 Stac k Emissio n Rat e Ib/h r < 8.39E-0 7 < 9.10E-0 7 < 8.74E-0 7 g/se c < 1.06E-0 7 < 1.15E-0 7 < 1.10E-0 7 Tota l Chromiu m (Cr ) - L V M Quantit yCollecte d p g 14.3 9 13.3 9 13.8 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 9.4 8 10.9 8 10.2 3 Stac k Emissio n Rat e Ib/h r 1.2 1 E-0 4 1.22E-0 4 1.2 1 E-0 4 g/se c 1.52E-0 5 1.53E-0 5 1.53E-0 5 Cadmiu m (Cd ) - - S V M Quantit yCollecte d M g 3.0 0 1.6 0 2.3 0 Stac k Cone
. @ 7 % O z Mg/m 3 1.9 8 1.3 1 1.6 4 Stac k Emissio n Rat e Ib/h r 2.52E-0 5 1.46E-0 5 1.99E-0 5 g/se c 3.17E-0 6 1.83E-0 6 2.50E-0 6 Lea d (Pb ) - S V M Quantit yCollecte d p g 4.6 5 3.7 5 4.2 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 3.0 6 3.0 8 3.0 7 Stac k Emissio n Rat e Ib/h r 3.90E-0 5 3.4 1 E-0 5 3.66E-0 5 g/se c 4.92E-0 6 4.30E-0 6 4.6 1 E-0 6 LV M Tota l = Mg/m 3 10.8 6 13.6 1 12.2 3 SV M Tota l = Mg/m 3 5.0 4 4.3 9 4.7 1
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Noverribe r2Q02\Field\Unl t 3\[M2 9 U3.xls]DAT AP g 1 o f3

J:\Air_TcortProject Files\Onyx\Onyx200 2 work\Novembe r2002\Report\Report Nov02.do c 2-1 4 January , 200 3INTERNATIONAL
TABL E 2-1 0 (CONTINUED ) SUMMAR YO FINDIVIDUA L METAL S EMISSION S FO R UNI T3 Ru n No
. 1 2 Dat e 19-NOV-0 2 19-NOV-0 2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 11:5 2 15:4 5 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Volum e Metere d dc f 94.89 7 82.46 8 88.68 3 Sampl e Volum e dsc f 95.01 7 81.44 8 88.23 3 Moistur e % v/ v 37. 3 37. 5 37. 4 0 2a t Stac k %dr y 13.1 0 13.6 0 13.3 5 Avg
. Stac k

Temp
. ° F 32 8 35 5 34 2 Stac k Flowrat e dscf m 6,02 7 5,60 2 5,81 4 Isokinetic s 

### % 10 6 9 9 10 3 Mercur y(He ) — V M Quantit yCollecte d P 9 130. 4 142. 5 136. 4 Stac k Cone
. @ 7 % 0 2 pg/m 3 85, 9 116. 8 101. 4 Stac k Emissio n Rat e Ib/h r 1.09E-0 3 1.30E-0 3 1.19E-0 3 g/se c 1.38E-0 4 1.63E-0 4 1.5 1 E-0 4 Antimon y(Sb ) — Quantit yCollecte d M 9 0.1 8 6.9 1 3. 5 Stac k Cone
. @ 7 % 0 2 pg/m 3 0.1 2 5.6 7 2. 9 Stac k Emissio n Rat e Ib/hr 1.5 1 E-0 6 6.29E-0 5 3.22E-0 5 g/se c 1.90E-0 7 7.92E-0 6 4.06E-0 6 Bariu m (Ba ) — Quantit yCollecte d M 9 48.3 9 45.3 9 46. 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 31.8 7 37.2 3 34. 6 Stac k Emissio n Rat e Ib/h r 4.06E-0 4 4.13E-0 4 4.09E-0 4 g/se c 5.12E-0 5 5.20E-0 5 5.16E-0 5 Silve r(Ae ) - Quantit yCollecte d p g 148.3 9 49.3 9 98. 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 97.7 3 40.5 1 69. 1 Stac k Emissio n Rat e Ib/h r 1.25E-0 3 4.49E-0 4 8.47E-0 4 g/se c 1.57E-0 4 5.66E-0 5 1.07E-0 4 Thalliu m (Tl ) - Quantit yCollecte d p g < 0.5 0 < 0.5 0 < 0. 5 Stac k Cone
. @ 7 % 0 2 pg/m 3 < 0.3 3 < 0.4 1 < 0. 4 Stac k Emissio n Rat e Ib/h r < 4.20E-0 6 < 4.55E-0 6 < 4.37E-0 6 g/se c < 5.29E-0 7 < 5.73E-0 7 < 5.51E-0 7
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worWNovembe r2002\Field\Uni t 3\(M2 9 U3.xls]DAT AP g 2 of3

J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worMNovembe r2002\ReporRRepor t Nov02.do c 2-1 5 January , 200 3

### Etftt t IN TER fl ATIONAL
TABL E 2-1 0 (CONTINUED ) SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T3 Ru n No
. 1 2 Dat e 19-Nov-0 2 19-Nov-0 2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 11:5 2 15:4 5 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Volum e Metere d dc f 94.89 7 82.46 8 88.68 3 Sampl e Volum e dsc f 95.01 7 81.44 8 88.23 3 Moistur e %v/ v 37. 3 37. 5 37. 4 0 2a t Stac k %dr y 13.1 0 13.6 0 13.3 5 Avg
. Stac k

Temp
. ° F 32 8 35 5 34 2 Stac k Flowrat e dscf m 6,02 7 5,60 2 5,81 4 Isokinetic s % 10 6 9 9 10 3 Nicke l (Ni ) - Quantit yCollecte d u g 42.3 9 42.3 9 42. 4 Stac k Cone
. @ 7 % 0 2 pg/m 3 27. 9 34.7 7 31. 3 Stac k Emissio n Rat e Ib/h r 3.56E-0 4 3.86E-0 4 3.7 1 E-0 4 g/se c 4.48E-0 5 4.86E-0 5 4.67E-0 5 Seleniu m (Se ) — Quantit yCollecte d p g 1.1 0 1.0 0 1. 1 Stac k Cone
. @ 7 % 0 2 pg/m 3 0.7 2 0.8 2 0. 8 Stac k Emissio n Rat e Ib/h r 9.23E-0 6 9.10E-0 6 9.16E-0 6 g/se c 1.16E-0 6 1.15E-0 6 1.15E-0 6
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 workANovembe r2002\Fidd\Uni t 3\[M2 9 U3jdslDAT AP g 3 o f3

J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worirtNovembe r2002\Report\Repor t Nov02.do c 2-1 6 January , 200 3INTERNATIONAL
Tabl e 2-1 1 SUMMAR YO F HW C MAC TMETAL S EMISSION S FO R UNI T4


### Lo wVolatil e Metal s Emission s micrograms/m 3@ 7 % 0 2 Metal s Run l Run 2 Run s 3 Averag e A s 1.7 1 1.3 3 1.2 9 1.4 4 B e < 0.0 7 < 0.0 7 < 0.0 7 < 0.0 7 C r 7-7 7 8.0 0 10.4 7 8.7 5 Tota l LV M < 9.5 5 < 9.4 0 < 11.8 3 < 10.2 6 LV M Regulator yStandar d = 9 7 micrograms/m 3@ 7 % 0 2 

### Semi-Volatil e Meta l Emission s micrograms/m 3(

6 } 7 % 0 2 Metal s Ru n 1 Ru n 2 Run s 3 Averag e P b 8.5 0 10.1 4 6.2 9 8.3 1 C d 0.7 5 0.4 1 0.3 1 0.4 9 Tota l SV M 9.2 5 10.5 5 6.6 0 8.8 0 S V M Regulator yStandar d = 24 0 micrograms/m 3@ 7 % 0 2



### Mercur yEmission s micrograms/ m } 7 % 0 2 Ru n 1 Ru n 2 Ru n 3 Averag e 27.5 0 332.1 9 587.6 9 459.1 7 Mercur yRegulator yStandar d = 13 0 micrograms/m 3 @ 7 % Q 2 J:\Air_Tox\Projec l Files\Onyx\Ony x200 2 worMNovembe r2002\Field\Uni t 4\[M2 9 U4.xls]EMISSpg 2

J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worMNovembe r2002\ReporriReport Nov02.do c 2-1 7 January , 200 3

### ENS * INTERNAT/ONAL
TABL E 2-1 2 SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T4 Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-NOV-0 2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 11:4 0 15:5 9 10:2 2 AVG S Samplin g Parameters - - Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29.5 3 Volum e Metere d dc f 95.99 2 93.70 7 93.87 8 94.52 6 Sampl e Volum e dsc f 96.57 0 95.17 7 95.63 7 95.79 5 Moistur e % v/v 33. 2 34. 8 35. 4 34. 5 0 2a t Stac k % dr y 13.5 0 13.6 0 13.4 0 13.5 0 Avg
. Stac k

Temp
. " F 38 6 38 4 39 1 38 7 Stac k Flowrat e dscf m 18,90 4 18,78 1 18,61 8 18,76 8 Isokinetic s % 9 8 9 7 9 9 9 8 Arseni c tAs ) — LV M Quantit yCollecte d M9 2.5 0 1.9 0 1.9 0 2.1 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 1.7 1 1.3 3 1.2 9 1.4 4 Stac k Emissio n Rat e Ib/hr 6.47E-0 5 4.96E-0 5 4.89E-0 5 5.44E-0 5 g/se c 8.16E-0 6 6.25E-0 6 6.16E-0 6 6.86E-0 6 Berylliu m (Be

) - - LV M Quantit yCollecte d M9 < 0.1 0 < 0.1 0 < 0.1 0 < 0.1 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 < 0.0 7 < 0.0 7 < 0.0 7 < 0.0 7 Stac k Emissio n Rat e Ib/hr < 2.59E-0 6 < 2.6 1 E-0 6 < 2.58E-0 6 < 2.59E-0 6 g/se c < 3.26E-0 7 < 3.29E-0 7 < 3.24E-0 7 < 3.27E-0 7 Tota l Chromiu m fCr ) - LV M Quantit yCollecte d p g 11.3 9 11.3 9 15.3 9 12.7 2 Stac k Cone
. @ 7 % 0 2 pg/m 3 7.7 7 8.0 0 10.4 7 8.7 5 Stac k Emissio n Rat e Ib/h r 2.95E-0 4 2.97E-0 4 3.96E-0 4 3.30E-0 4 g/se c 3.72E-0 5 3.75E-0 5 4.99E-0 5 4.15E-0 5 Cadmiu m (Cd ) — S V M Quantit yCollecte d p g 1.1 0 0.5 8 0.4 5 0.7 1 Stac k Cone
. @ 7 % 0 2 pg/m 3 0.7 5 0.4 1 0.3 1 0.4 9 Stac k Emissio n Rat e lb/h r 2.85E-0 5 1.5 1 E-0 5 1.16E-0 5 1.84E-0 5 g/se c 3.59E-0 6 1.9 1 E-0 6 1.46E-0 6 2.32E-0 6 Lead(Pb ) - S V M Quantit yCollecte d p g 12.4 5 14.4 5 9.2 5 12.0 5 Stac k Cone
. @ 7 % 0 2 pg/m 3 8.5 0 10.1 4 6.2 9 8.3 1 Stac k Emissio n Rat e Ib/hr 3.22E-0 4 3.77E-0 4 2.38E-0 4 3.13E-0 4 g/se c 4.06E-0 5 4.75E-0 5 3.00E-0 5 3.94E-0 5 LV M Tota l = pg/m 3 9.5 5 9.4 0 11.8 3 10.2 6 SV M Tota l = pg/m 3 9.2 5 10.5 5 6.6 0 8.80
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002\Field\Unl t 4\[M2 9 U4.xls]Summar y(continued ) P g 1 o f3

J:\Air_Tox\Project Files\Onyx\Onyx200 2 work\Novembe r2002\Rsport\Report Nov02.do c 2-1 8 January , 200 3

### ENSR . /HTERNAriO/ML
TABL E 2-1 2 (CONTINUED ) SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T4 Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-Nov-0 2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 11:4 0 15:5 9 10:2 2 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29.5 3 Volum e Metere d dc f 95.99 2 93.70 7 93.87 8 94.52 6 Sampl e Volum e dsc f 96.57 0 95.17 7 95.63 7 95.79 5 Moistur e % v/v 33. 2 34. 8 35. 4 34. 5 O za tStac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 Avg
. Stac k

Temp
. ° F 38 6 38 4 39 1 38 7 Stac k Flowrat e dscf m 18,90 4 18,78 1 18,61 8 18,76 8 Isokinetic s 

### % 9 8 9 7 9 9 9 8 Mercur y(Hg ) — V M Quantit yCollecte d u g 40. 3 473. 2 864. 0 459. 2 Stac k Cone
. @ 7 % 0 2 pg/m 3 27. 5 332. 2 587. 7 315. 8 Stac k Emissio n Rat e Ib/h r 1.04E-0 3 1.24E-0 2 2.22E-0 2 1.19E-0 2 g/se c 1.3 1 E-0 4 1.56E-0 3 2.80E-0 3 1.50E-0 3 Antimon y(Sb ) — Quantit yCollecte d p g 0.0 8 < 0.5 3 < 0.5 2 < 0.3 8 Stac k Cone
. @ 7 % 0 2 pg/m 3 0.0 5 < 0.3 7 < 0.3 5 < 0.2 6 Stac k Emissio n Rat e Ib/h r 2.07E-0 6 < 1.38E-0 5 < 1.34E-0 5 < 9.77E-0 6 g/se c 2.6 1 E-0 7 < 1.74E-0 6 < 1.69E-0 6 < 1.23E-0 6 Bariu m (Ba ) — Quantit yCollecte d p g 38.3 9 39.3 9 40.3 9 39.3 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 26.2 1 27.6 5 27.4 7 27.1 1 Stac k Emissio n Rat e Ib/h r 9.94E-0 4 1.03E-0 3 1.04E-0 3 1.02E-0 3 g/se c 1.25E-0 4 1.30E-0 4 1.3 1 E-0 4 1.29E-0 4 Silve r(Ag ) - Quantit yCollecte d p g 62.3 9 17.3 9 0.3 9 26.7 2 Stac k Cone
. @ 7 % 0 2 pg/m 3 42.5 9 12.2 1 0.2 7 18.3 5 Stac k Emissio n Rat e Ib/h r 1.62E-0 3 4.54E-0 4 1.00E-0 5 6.93E-0 4 g/se c 2.04E-0 4 5.72E-0 5 1.27E-0 6 8.73E-0 5 Thalliu m (Tl ) - Quantit yCollecte d p g < 0.5 0 < 0.5 0 < 0.5 0 < 0.5 0 Stac k Cone
. @ 7 % O z pg/m 3 < 0.3 4 < 0.3 5 < 0.3 4 < 0.3 4 Stac k Emissio n Rat e Ib/h r < 1.29E-0 5 < 1.3 1 E-0 5 < 1.29E-0 5 < 1.30E-0 5 g/se c < 1.63E-0 6 < 1.64E-0 6 < 1.62E-0 6 < 1.63E-0 6
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002\Field\Uni t 4\(M2 9 U4.xls]EMISSpg 2 (continued ) P g 2 o f3

J:\Air_Tox\Projec t Files\Onyx\Onyx200 2 work\Novembef2002\Report\Repor t Nov02.dcx : 2-1 9 January , 200 3

### Efft R INTERNATIONAL
TABL E 2-1 2 (CONTINUED ) SUMMAR YO F INDIVIDUA L METAL S EMISSION S FO R UNI T4 Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0

2 22-Nov-0

2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 11:4 0 15:5 9 10:2 2 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29.5 3 Volum e Metere d dc f 95.99 2 93.70 7 93.87 8 94.52 6 Sampl e Volum e dsc f 96.57 0 95.17 7 95.63 7 95.79 5 Moistur e % v/ v 33. 2 34. 8 35. 4 34. 5 O za t Stac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 Avg
. Stac k

Temp
. ° F 38 6 38 4 39 1 38 7 Stac k Flowrat e dscf m 18,90 4 18,78 1 18,61 8 18,76 8 Isokinetic s 

### % 9 8 9 7 9 9 9 8 Nicke l (Ni ) - Quantit yCollecte d P 9 29. 4 31.3 9 30.3 9 30. 4 Stac k Cone
. @ 7 % 0 2 pg/m 3 20. 1 22.0 3 20.6 7 20. 9 Stac k Emissio n Rat e Ib/hr 7.6 1 E-0 4 8.19E-0 4 7.83E-0 4 7.88E-0 4 g/se c 9.59E-0 5 1.03E-0 4 9.86E-0 5 9.92E-0 5 Seleniu m (Se ) — Quantit yCollecte d p g < 1.0 0 < 1.0 0 < 1.0 0 < 1.0 0 Stac k Cone
. @ 7 % 0 2 pg/m 3 < 0.6 8 < 0.7 0 < 0.6 8 < 0.6 9 Stac k Emissio n Rat e Ib/h r < 2.59E-0 5 < 2.6 1 E-0 5 < 2.58E-0 5 < 2.59E-0 5 g/se c < 3.26E-0 6 < 3.29E-0 6 < 3.24E-0 6 < 3.27E-0 6

............ . •. ; . ; J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worttNovembe r2002\Field\Uni t 4\(M2 9 U4.xls]Surnrnar yP g 3 o f3

J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002\Reporf\Report Nov02.do c 2-2 0 January , 200 3

### ENSR . INTERNATIONAL
Tabl e 2-1 3 PM/HCI/CI 2EMISSIO N RESULT S FO R UNI T2
Ru n No
. 1 2 Dat e 20-Nov-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 10:1 9 14:1 7 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Volum e Metere d dc f 79.50 1 81.65 2 80.57 7 Volum e o fGa s Collecte d dsc f 78.38 2 79.07 4 78.72 8 Moistur e % v/ v 42. 0 37. 2 39. 6 0 2a t Stac k %dr y 11.0 0 11.0 0 11.0 0 C 0 2 a tStac k % dr y 4.7 0 4.1 0 4.4 0 Avg
. Stac k

Temp
. ° F 35 0 37 3 36 1 Stac k Flowrat e dscf m 4,94 2 5,31 1 5,12 6 Isokinetic s % 10 7 10 0 10 3 Particulat e Emissio n Result s — Fron tHal fRins e m g 2. 6 10. 8 6. 7 Particulat e Filte r m g 1. 5 2. 0 1. 8 Tota l Particulat e m g 4. 1 12. 8 8. 5 P M Loadin g @ 7 % 0 2 mg/dsc m 2. 6 8. 0 5. 3 Grai n Loadin g gr/dsc f 0.000 8 0.002 5 0.001 6 Grai n Loadin g @ 7 % 0 2 gr/dsc f 0.001 1 0.003 5 0.002 3 Grai n Loadin g @ 12 % C0 2 gr/dsc f 0.002 1 0.007 3 0.004 7 Emissio n Rat e Ib/hr 0.0 3 0.1 1 0. 1 HC I Emissio n Result s — Tota l HC I Detecte d 17,50 0 34,00 0 2575 0 Tota l HC I Concentratio n pp m 5.1 8 9.9 8 7.5 8 Cone
. @ 7 % 0 2 pp m 7.2 6 13.9 8 10.6 2 HC I Emissio n Rat e Ib/hr 0.14 6 0.30 2 0.22 4 CI , Emissio n Result s — Tota l Cl 2Detecte d p g 47 0 48 5 47 8 Tota l Cl 2Concentratio n pp m 0.0 7 0.0 7 0.0 7 Cone
. @ 7 % 0 2 pp m 0.1 0 0.1 0 0.1 0 C l 2Emissio n Rat e Ib/hr 0.00 4 0.00 4 0.00 4
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 workXNovembe r2002\Field\Uni t 2\[M2 9 U2jds]DAT A
J:\Air_Tox\Proje a Files\Onyx\Ony x200 2 work\Novembe r2002\Repx3rt\Repor t Nov02.do c 2-2 1 January , 200 3

### EPK R INTERNATIONAL
Tabl e 2-1 4 PM /

HC I / Cl 2EMISSIO N RESULT S FO R UNI T3
Ru n No
. 1 2 Dat e 19-NOV-0 2 19-NOV-0

2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 11:5 2 15:4 5 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Volum e Metere d dc f 86.75 3 79.20 0 82.97 7 Volum e o fGa s Collecte d dsc f 84.76 2 76.86 1 80.81 2 Moistur e % v/ v 38. 4 38. 5 38. 5 0 2a t Stac k %dr y 13.1 0 13.6 0 13.3 5 C O za t Stac k %dr y 4.3 0 3.4 0 3.8 5 Avg
. Stac k

Temp
. ° F 33 1 36 1 34 6 Stac k Flowrat e dscf m 5,31 4 5,21 0 5,26 2 Isokinetic s 

### % 10 7 9 9 10 3 Particulat e Emissio n Result s — Fron tHal fRins e m g 3. 0 3. 8 3. 4 Particulat e Filte r m g 0. 1 0. 5 0. 3 Tota l Particulat e m g 3. 1 4. 3 3. 7 P M Loadin g @ 7 % 0 2 mg/dsc m 2. 3 3. 7 3. 0 Grai n Loadin g gr/dsc f 0.000 6 0.000 9 0.000 7 Grai n Loadin g @ 7 % 0 2 gr/dsc f 0.001 0 0.001 6 0.001 3 Grai n Loadin g @ 12 % C0 2 gr/dsc f 0.001 6 0.003 0 0.002 3 Emissio n Rat e Ib/h r 0.0 3 0.0 4 0. 0 HC I Emissio n Result s — Tota l HC I Detecte d M 9 1,30 0 27,50 0 1440 0 Tota l HC I Concentratio n pp m 0.3 6 8.3 1 4.3 3 Cone
. @ 7 % O z pp m 0.6 3 15.7 2 8.1 7 HC I Emissio n Rat e Ib/h r 0.01 1 0.24 7 0.12 9 CI , Emissio n Result s — Tota l Cl 2Detecte d M g 50 0 51 5 50 8 Tota l Cl 2Concentratio n pp m 0.0 7 0.0 8 0.0 8 Cone
. @ 7 % 0 2 pp m 0.1 3 0.1 5 0.1 4 C l 2Emissio n Rat e Ib/h r 0.00 4 0.00 5 0.00 4
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worttNovembe r2002\Field\Uni t 3\(M2 9 U3.xls]DAT A
J:\Air_Tox\Proje d F]les\Onyx\Onyx200 2 worMNovembe r2002\Report\Report Nov02.do c 2-2 2 January , 200 3

### EPKR . INTERNATIONAL
Tabl e 2-1 5 PM /

HC I / Cl 2EMISSIO N RESULT S FO R UNI T4
Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-Nov-0 2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 11:4 0 15:5 9 10:2 2 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29.5 3 Volum e Metere d dc f 90.25 4 88.55 1 91.21 9 90.00 8 Volum e o fGa s Collecte d dsc f 88.64 7 88.06 5 91.32 9 89.34 7 Moistur e % v/v 35. 0 35. 5 36. 1 35. 5 0 2a tStac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 C 0 2a t Stac k %dr y 3.9 0 3.8 0 4.5 0 4.0 7 Avg
. Stac k

Temp
. ° F 38 9 38 5 39 2 38 9 Stac k Flowrat e dscf m 17,33 0 17,38 6 17,59 7 17,43 8 Isokinetic s 

### % 9 8 9 7 10 0 9 9 Particulat e Emissio n Result s — Fron tHal fRins e m g 4. 1 3. 9 6. 5 4. 8 Particulat e Filte r m g 1. 1 0. 9 1. 0 1. 0 Tota l Particulat e m g 5. 2 4. 8 7. 5 5. 8 P M Loadin g @ 7 % 0 2 mg/dsc m 3. 9 3. 6 5. 3 4. 3 Grai n Loadin g gr/dsc f 0.000 9 0.000 8 0.001 3 0.001 0 Grai n Loadin g @ 7 % 0 2 gr/dsc f 0.001 7 0.001 6 0.002 3 0.001 9 Grai n Loadin g @ 12 % C0 2 gr/dsc f 0.002 8 0.002 7 0.003 4 0.002 9 Emissio n Rat e Ib/h r 0.1 3 0.1 3 0.1 9 0.1 5 HC I Emissio n Result s — Tota l HC I Detecte d u g 24,00 0 20,50 0 25,00 0 23,16 7 Tota l HC I Concentratio n pp m 6.2 9 5.4 1 6.3 6 6.0 2 Cone
. @ 7 % 0 2 pp m 11.7 3 10.2 3 11.7 1 11.2 2 HC I Emissio n Rat e Ib/hr 0.62 1 0.53 5 0.63 7 0.59 8 CI , Emissio n Result s — Tota l Cl 2Detecte d u g 43 5 50 0 51 0 48 2 Tota l Cl 2Concentratio n pp m 0.0 6 0.0 7 0.0 7 0.0 7 Cone
. @ 7 % 0 2 pp m 0.1 1 0.1 3 0.1 2 0.1 2 C l 2Emissio n Rat e Ib/h r 0.01 1 0.01 3 0.01 3 0.01 2
J:\Air_Tox\Projec t Fi1es\Onyx\Ony x200 2 work\Novembe r2002\Field\Uni t 4\fM2 6 U4.xls]EMISSION S
J:\Air_Tox\Proje d Files\Onyx\Onyx200 2 work\Novembe r2002\Report\Report Nov02.do c 2-2 3 January , 200 3

### Et« t WTEKNAriOHJIL 3. 0 SAMPLIN G AN D ANALYTICA L PROCEDURE S

3. 1 Samplin g Procedure s Severa l differen tsamplin g an d monitorin g technique s wer e use d t o provid e th e require d dat a t o mee t th e goal s o fthi s tes tprogram . Tw o (2 ) run s wer e conducte d o n Uni t2 an d Uni t3 a t on e operatin g conditio n establishe d b yOnyx
. Thre e (3 ) run s wer e conducte d o n Uni t4
. Th e samplin g activitie s describe d belo wwer e conducte d durin g al l runs . Al l fiel d activitie s wer e documente d i n accordanc e wit h EP Aaccepte d procedure s an d copie s o fal l fiel d note s an d dat a sheet s ar e include d i n Appendi x Aofthi s report
.

3.1. 1 Velocity , Moistur e an d Fixe d Ga s Determination s G a s strea m velocit yan d temperatur e wer e determine d i n conjunctio n wit h eac h manua l samplin g method
. Atyp e "S " pito ttub e connecte d t o a n incline d wate rmanomete rwa s use d t o determin e velocit yhea d o fth e flu e ga s a t eac h duc ttravers e poin ta s specifie d i n EP AReferenc e Metho d 2
. Th e temperatur e profil e o fth e flu e ga s a t eac h duc ttravers e poin twa s obtaine d b ytakin g reading s wit h a thermocoupl e an d pyromete rconcurren twit h th e velocit yhea d measurements
. Moistur e conten twa s determine d a s specifie d i n EP AMetho d 4
. Velocit yan d temperatur e measuremen tprofile s wer e establishe d prio rt o testin g t o ai d i n sampl e trai n set-up
. Sample s fo rth e determinatio n o fth e fixe d ga s compositio n wer e collecte d usin g th e integrate d ba g techniqu e detaile d i n EP AReferenc e Metho d 3
.

3.1. 2 PCDD/PCD F Samplin g Samplin g fo rdioxin s an d furan s wa s complete d i n accordanc e wit h EP AMetho d 23 A(4 0 CF R 60 , Appendi xA)
. O n al l Units , eac h samplin g ru n wa s 3 hour s i n duratio n coverin g 1 2 samplin g point s a t 1 5 minute s pe rpoint
. 3.1. 3 Metal s Samplin g Th e EP AMultipl e Metal s Trai n (EP AMetho d 29 , 4 0 CF R 6 0 Appendi xA ) wa s utilize d durin g th e testin g progra m fo rth e collectio n o fth e followin g metals : antimony , arsenic , barium , beryllium , cadmium , chromium , lead , mercury , nickel , selenium , silve ran d thallium
. Eac h ru n wa s 2-h ri n duratio n coverin g 1 2 samplin g point s a t 1 0 minute s pe rpoint
.

3.1. 4 PM/HCI/CI 2Samplin g Procedur e Samplin g fo rparticulat e matte r(PM) , hydroge n chlorid e (HCI) , Chlorin e (Cl 2 ) wa s performe d i n accordanc e wit h EP AMetho d 26A
. Thi s procedur e allow s fo rth e collectio n o fHC I i n 0. 1 N H 2 S 0 4 impinge rsolution s (1 s tthre e impingers ) an d Cl 2i n th e fina l tw o impinger s containin g 0. 1 N NaOH
. Eac h ru n wa s 2-h ri n duratio n coverin g 1 2 samplin g point s a t 1 0 minute s pe rpoint
.

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### ENSR . INTE/tNATIOf/AL 3. 2 Analytica l Procedure s 3.2. 1 PCDD/PCD F Analyse s Metho d 0023 Asample s wer e analyze d b yEP AMetho d 829 0 (hig h resolutio n Ga s Chromatograp h (GC)/Mas s Spectropotomete r(MS))
. Th e trai n fraction s recovere d fo ranalysi s o fPCDDs/PCDF s includ e th e fron thal frinses, th e particulat e filte ran d th e XA D resi n trap
. Th e analytica l result s fo reac h sampl e fractio n wer e combine d int o a singl e analytica l resul tfo reac h run . PCDD/PCD F analyse s wer e performe d b yAlt a Analytica l Laboratory , Inc
. i n E l Dorad o Hills , CA
.

3.2. 2 Metal s Analyse s Metal s analyse s fo rth e wast e fee d sample s wer e complete d usin g tw o separat e procedures
. First , sample s wer e prepare d an d analyze d fo rantimony , arsenic , barium , beryllium , cadmium , chromium , lead , nickel , selenium , silve ran d thalliu m a s specifie d i n EP AMetho d 602 0 (ICP-MS) , SW846 , 3 r d Edition
. Mercur ywa s analyze d vi a metho d 7471 Aan d Seleniu m wa s analyze d b yGraphit e Fumace/Atomi cAbsorptio n Spectrophotometer
. Metal s analyse s wer e performe d b yPS C Analytica l Inc
. o fBurlington , Ontari o (Canada)
. 3.2. 3 PM/HCI/CI 2Analysi s Sampl e analysi s fo r(PM) , (HCI) , an d (Cl 2 ) wer e conducte d i n accordanc e wit h EP AMetho d 26A , wit h gravimetri canalysi s fo rparticulat e a s pe rEP AMetho d 5 (4 0 CF R 60 , Appendi xA)
. Analysi s fo rHC I an d Cl 2followe d EP AMetho d 9057
. Analysi s wa s als o performe d b yPS C Analytica l Service s Inc
. o f Burlington , Ontari o (Canada)
.

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### ENSR . INTERNATIONAL 

### 4. 0 QUALIT YASSURANC E

4. 1 Introductio n Thi s sectio n present s th e result s o fal l QA/Q C measure s implemente d durin g th e fiel d samplin g progra m an d al l phase s o fsubsequen tanalysis
. Dat a generate d fo rth e progra m ar e judge d t o b e vali d a s overal l accurac yan d precisio n result s ar e consisten twit h genera l objectives
. Analytica l QA/Q C dat a ar e presente d t o suppor tal l sampl e result s use d fo rdeterminin g complianc e wit h performanc e criteri a o remissio n standards
. 4. 2 Stac k

Samplin g QA/Q C Th e stac k

samplin g progra m incorporate d a variet yo fmeasure s t o ensur e tha tsoun d dat a woul d b e obtained
. Al l sample s wer e collecte d a t th e stac k samplin g location s a s planne d an d i n accordanc e wit h applicabl e metho d procedures
. On e fiel d blan k fo rth e entir e samplin g even twa s submitte d fo r analysi s alon g wit h progra m samples
. Samplin g QA/Q C measur e fo rthi s progra m include d calibratio n o fal l applicabl e samplin g equipmen t use d a s describe d below
. Fiel d equipmen twer e calibrate d accordin g t o EP Aprocedure s specifie d i n EPA-60074-77-027 b (Augus t1977 ) an d 4 0 CF R 60 , Method s 1-5 , a s wel l a s manufacturer' s specifications
. 1 ) Dr vGa s Meter s an d Orific e Meter s (EP AMetho d 5 Type ) Th e dr yga s meter s fo ral l samplin g train s wer e calibrate d agains ta we t tes tmete rwhic h ha d bee n calibrate d agains ta spirometer
. Th e orific e meter s wer e calibrate d agains tth e we t tes tmete ran d checke d agains tth e dr yga s mete rt o whic h the ywer e attached
. Mete rboxe s ar e calibrate d annuall yan d the n verifie d b yus e o fth e Alternativ e Metho d 5 post-tes tcalibratio n procedure
. Thi s procedur e i s base d o n th e principle s o fth e optiona l pretes torific e mete rcoefficien tchec k outline d i n 4 0 CFR , Appendi xA , Metho d 5 , Sectio n 4.4.1
. Th e averag e Y-valu e obtaine d b ythi s metho d mus tb e withi n 5 % o fth e initia l Y-value
. Th e calculation s provide d wit h th e dat a sheet s i n Appendi xAsho wtha tthi s criterio n wa s me t fo ral l isokineti csamplin g train s use d o n th e progra m excep tBo x# 80754
. Consequently , a pos tcalibratio n wa s performe d o n Bo x# 80754
. Th e resultan tDG M calibratio n facto ran d Delt a H wa s entere d i n th e isokineti cspreadsheet
. Sinc e th e sampl e volum e wa s les s usin g th e re-calibratio n data , thi s valu e wa s utilize d fo remissio n calculation s i n accordanc e wit h th e metho d criteria
. 2 ) 2 ) Samplin g Nozzles . Eac h glas s nozzle' s interna l diamete ri s measure d t o 0.00 1 inche s alon g thre e (3 ) point s o fth e circumferenc e wit h a Dia l Caliper
. Th e thre e (3 ) measurement s ar e the n average d an d th e nozzle s ar e identifie d wit h uniqu e identificatio n numbers
. 3 ) Balance . Th e analytica l balanc e use d i n th e fiel d t o determin e initia l an d fina l silic a ge l weight s i s calibrate d agains tClas s M weight s provide d b yth e Mettle rCorporation
.

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# ENSR . INTERNATIONAL 4 ) Thermocouples . Typ e Kthermocouple s i n eac h mete rcontro l box , heate d sampl e box , impinge r umbilica l connecto ran d sampl e probe s ar e calibrate d agains tAST M mercury-in-glas s thermometer s a t thre e points : a n ic e bath , ambien ttemperatur e an d a boilin g wate rbath
. Calibratio n dat a ar e provide d i n Appendi xC
. 5 ) Pito t Tube . Eac h S-typ e stainles s stee l pito ttub e use d i s designe d t o mee tgeometri c configuration s a s define d i n EP AMetho d 2
. Calibratio n sheet s ar e provide d i n Appendi xC
. 4. 3 Chain-of-Custod y* Chain-of-custod yprocedure s wer e followe d fo ral l sample s a s follows :

•Eac h isokineti ctrai n wa s set-u p an d recovere d i n a clea n are a adjacen tt o th e incinerators
. •Sample s wer e collected , seale d an d labele d appropriately
. •Al l sample s wer e packe d i n bubbl e wra p o rothe rabsorben tmateria l an d place d i n eithe r sampl e cooler s o rappropriat e DO Tshippin g package s (dangerou s good s items)
. •Al l sample s wer e subsequentl yshippe d vi a Priorit yOvernigh tFedE xservic e t o th e designate d laboratory
. 4. 4 Analytica l QA/Q C Dat a Qualit yIndicator s (DQI's ) wer e utilize d throughou tth e progra m t o asses s th e validit yo fanalytica l data
. Thi s sectio n provide s a revie wo fthes e indicator s an d th e subsequen timpac to n th e analytica l data
. 4.4. 1 Analysi s fo rMetal s Evaluatio n o fth e validit yo fmetal s dat a resultin g fro m th e analysi s o fth e Metho d 006 0 samplin g trai n sample s wa s base d o n th e followin g tw o set s o fDQI's :

•Recoverie s o finternal , pre-spik e an d alternat e recover ystandard s adde d t o th e sample s prio r t o sampling
. Recoverie s o fthes e standard s ar e include d wit h othe rPhili p Analytica l Service s dat a i n Appendi xD
.
•Result s o fanalyse s o ffiel d an d metho d blan k sample s fo rmetals
. Thes e result s ar e include d i n Appendi xD
. O n th e basi s o fthes e Q C results , n o sampl e analyse s wer e rejecte d an d al l th e dat a wer e determine d t o b e valid
. Completenes s wa s therefor e determine d t o b e 100 % fo ral l metal s result s fro m al l samples
.

J:\Air_Tox\Projec ) Files\Onyx\Onyx200 2 worttNovembe r2002\Reporf\Report Nov02.do c 4- 2 January , 200 3EHS R mrEKMATIONAL 4.4. 2 Analysi s fo rPCDDs/PCDF s Evaluatio n o fth e validit yo fth e PCDD/PCD F dat a resultan tfro m th e analysi s o fth e Metho d 23 A samplin g trai n sample s wa s base d o n fou rset s o fDQIs
. Thes e were :

•Recoverie s o fintemal , pre-spik e surrogate s an d alternat e recover ystandard s adde d t o th e sample s prio rt o sampling ;

•Result s o fanalysi s o fLaborator yContro l Sample s (LCS ) fo rth e 1 7 PCDD/PCD F isomer s liste d i n E P AMetho d 23 ;

•Result s o fanalyse s o ffiel d an d metho d blan k sample s fo rPCDD/PCDFs
. Thes e result s ar e include d wit h th e Alt a Analytica l Dat a Repor tinclude d i n Appendi xD
. O n th e basi s o fthes e Q C results , n o sampl e analyse s wer e rejecte d an d al l th e dat a wer e determine d t o b e valid
.

4.4. 3 Analysi s fo rParticulat e Matte r Evaluatio n o fresult s o fgravimetri canalysi s o fMetho d 26 Asample s wa s base d o n routin e laborator y practice s an d processin g o fla b blan k an d fiel d blan k

samples
. Minima l particulat e contaminatio n wa s observe d i n bot h th e la b aceton e blan k an d th e fiel d aceton e blan k sample , an d thu s blan k correctio n u p t o th e maximu m allowe d b yth e metho d (0.0 1 mg/g ) wa s performed
. Th e blan k filterweigh twa s withi n acceptabl e tolerance s an d require d n o blan k correction
. Additiona l Q C measure s followe d b y th e gravimetri clab , suc h a s maintenanc e o fprope rambien tcondition s an d us e o fstandar d weights , ensure d vali d data
.

4.4. 4 Analysi s fo rHCI/CI 2 Evaluatio n o fth e validit yo fanalysi s o fMetho d 26 Atrai n sample s wa s base d o n thre e set s o f objectives
. Thes e were :

•Result s o fanalysi s o fblan k spike s an d matri xspik e samples
.

•Result s fro m th e duplicat e analysi s o fal l samples
.

•Result s o fanalysi s o ffiel d blan k samples
. A n accurac ygoa l o f+10 % i s generall yestablishe d fo rchloride s i n stac k sampl e analyse s conducte d fo rthi s typ e o fprogram . Recoverie s fo ral l blan k spike s me tthes e criteria
. Also , fiel d an d metho d blan k sample s wer e fre e o fcontaminatio n a s show n i n th e table
. N o sampl e analyse s wer e rejected , an d al l result s wer e determine d t o b e valid
. Completenes s wa s therefor e determine d t o b e 100 % fo r al l result s fro m th e Metho d 26 Atrain s fo rchlorid e analysis
.

J:\Air_Tox\Prpjec t Files\Onyx\Ony x200 2 work\Novembe r2002\Reporf\Report Nov02.do c 4- 3 January , 200 3APPENDI XA FIEL D DAT ASHEET S

# )

### Metho d 23 ASamplin g Parameter s Onyx , Fixe d Heart h Incinerato r# 2 [wl Mete rBo x8075 4 re-callibration ) Ru n No
. 1 2 Dat e 20-Nov-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 11:3 1 15:1 8 AVG S Nozzl e Diamete r inche s 0.42 6 0.42 6 0.42 6 Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Ne tSamplin g Tim e min
. 180. 0 180. 0 180. 0 Volum e Metere d dc f 139.22 0 122.86 1 131.04 1 Avg
. DG M Temp
. ° F 58. 6 71. 4 65. 0 Av g Delt a H i n H 2 0 1.8 9 1.4 1 1.6 5 Av g Delt a H in
. H g 0.139 1 0.103 6 0.121 3

- -*-DG M e^libratiortPactor-*-** ^ -«wkQQ24—- - 1.002 4 1.002 4 Ga s Sampl e Volum e dsc f 141.21 8 121.47 9 131.34 8 Tota l Wate rCollecte d m L 1899. 5 1587. 0 1743. 3 Volum e o fWate rVapo r sc f 89.56 1 74.82 7 82.19 4 Moistur e (measured ) % v/ v 38. 8 38. 1 38. 5 Moistur e ( @ saturation ) % v/ v 101. 0 101. 0 101. 0 Dr yMol e Fraction , 100-% M — 0.611 9 0.618 8 0.615 4 C O za tStac k %dr y 4.7 0 4.1 0 4.4 0 0 2a tStac k %dr y 11.0 0 11.0 0 11.0 0 C O + N 2 %dr y 84.3 0 84.9 0 84.6 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 9 29.1 0 29.1 4 We tMolecula rWeigh t Ib/lb-mol e 24.8 5 24.8 7 24.8 6 Exces s Ai ra tStac k % 97. 7 96. 4 97. 1 Stac k Diamete r inche s 39. 0 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H z O 0.2 9 0.3 3 0.3 1 Stac k Pressur e in
. H g 29.6 2 29.6 2 29.6 2 Avg
. Stac k

Temp
. ° F 344. 1 370. 8 357. 4 Avg
. Sqroo to fDelt a P — 0.412 1 0.361 3 0.386 7 S D E Averag e — 11.68 7 10.41 2 11.04 9 Pito tCoefficien t „ 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,85 6 1,65 3 1,75 5 Stac k Flowrat e we tacf m 15,39 9 13,71 4 14,55 6 Stac k Flowrat e we tscf m 10,01 1 8,63 0 9,32 0 Stac k Flowrat e dscf m 6,12 6 5,34 1 5,73 3 Isokinetic s % 10 7 10 6 10 7 Mete rBo xNo
. — 8075 4 8075 4 Delt a H @ in
. H g 1.905 0 1.905 0 — J:\Airjrox\Prqe<^Files\Onyx\Ony x200 2 vrorttNovembe r2002\Field\Un K2V.M2 9 U2jds]DAT A

### Metho d 23 ASamplin g Parameter s Onyx , Fixe d Heart h Incinerato r# 2 Ru n No
. 1 2 Dat e 20-NOV-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 11:3 1 15:1 8 AVG S Nozzl e Diamete r inche s 0.42 6 0.42 6 0.42 6 Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Ne tSamplin g Tim e min
. 180. 0 180. 0 180. 0 Volum e Metere d dc f 139.22 0 122.86 1 131.04 1 Avg
. DG M Temp
. o p 58. 6 71. 4 65. 0 Av g Delt a H i n H z O 1.8 9 1.4 1 1.6 5 Av g Delt a H in
. H g 0.139 1 0.103 6 0.121 3 D G M Calibratio n Facto r — 1.010 7 1.010 7 1.010 7 Ga s Sampl e Volum e dsc f 142.38 7 122.48 5 132.43 6 Tota l Wate rCollecte d m L 1899. 5 1587. 0 1743. 3 Volum e o fWate rVapo r sc f 89.56 1 74.82 7 82.19 4 Moistur e (measured ) % v/ v 38. 6 37. 9 38. 3 Moistur e ( @ saturation ) % v/ v 101. 0 101. 0 101. 0 Dr yMol e Fraction , 100-% M — 0.613 9 0.620 8 0.617 3 C O za t Stac k %dr y 4.7 0 4.1 0 4.4 0 0 2a t Stac k %dr y 11.0 0 11.0 0 11.0 0 C O + N 2 %dr y 84.3 0 84.9 0 84.6 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 9 29.1 0 29.1 4 We tMolecula rWeigh t Ib/lb-mol e 24.8 7 24.8 9 24.8 8 Exces s Ai ra t Stac k 

### % 97. 7 96. 4 97. 1 Stac k Diamete r inche s 39. 0 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H z O 0.2 9 0.3 3 0.3 1 Stac k Pressur e in
. H g 29.6 2 29.6 2 29.6 2 Avg
. Stac k

Temp
. ° F 344. 1 370. 8 357. 4 Avg
. Sqroo to fDelt a P — 0.412 1 0.361 3 0.386 7 S D E Averag e — 11.68 7 10.41 2 11.04 9 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,85 5 1,65 2 1,75 4 Stac k Flowrat e we tacf m 15,39 2 13,70 8 14,55 0 Stac k Flowrat e we tscf m 10,00 6 8,62 6 9,31 6 Stac k Flowrat e dscf m 6,14 3 5,35 5 5,74 9 isokinetic s 

### % 10 8 10 7 10 7 Mete rBo xNo
. — 8075 4 8075 4 — Delt a H @ in
. H g 1.923 4 1.923 4 — Fiel d Q AYq c — 0.95 3 0.94 6 0.94 9 [Deviation ] Pre- Y 

### % 5.7 % 6.4 % 6.1 % J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 worMNovembe r2002\Field\Unit2\(M2 3 U2J(1SJDAT

AOnyx , Fixe d Heart h Incinerato r# 2 P T RU N 1 AVG S - PCDDs/PCDF s RU N 2 AVG S - PCDDs/PCDF s P T D P SQR T D P DG M

I N DG M

OU T D H STAC K TEM P D P SQR T D P DG M

I N DG M

OU T D H STAC K TEM P a 1 0.1 8 0.4243 4 8 4

2 1.9

0 34

0 0.1 2 0.3464 63 63 1.3 0 359 a 2 0.1 8 0.424 3 55 4 4 2.00 34 0 0.1 4 0.374 2 64 6 3 1.5 0 363 a 3 0.1 7 0.4123 6 0 4

8 1.9

0 34

2 0.1 5 0.387 3 65 58 1.6 0 368 a 4 0.1 7 0.4123 64 5 1 1.9

0 34

4 0.1 5 0.387 3 69 60 1.6 0 37

0 a 5 0.1 6 0.4000 6 4 53 1.8 0 34

5 0.1 5 0.387 3 7

3 63 1.6 0 37

2 a 6 0.1 7 0.4123 62 53 1.9 0 34

5 0.1 2 0.346 4 7

4 65 1.3 0 37

7 a 7 0.1 7 0.4123 5 5 53 1.9 0 34

0 0.1 3 0.3606 7 2 68 1.4 0 368 a 8 0.1 7 0.4123 63 5 4 1.9

0 34

5 0.1 3 0.3606 7 6 70 1.4 0 37

2 a 9 0.1 9 0.4359 66 5 5 2.1 0 34 6 0.1 2 0.3464 86 75 1.3 0 37

4 a1 0 0.1 7 0.4123 69 57 1.9 0 34

6 0.1 2 0.3464 8 4 7

7 1.3

0 37

6 a1 1 0.1 6 0.4000 7 6 65 1.8 0 34

8 0.1 3 0.3606 8 6 7

9 1.4

0 375 a1 2 0.1 5 0.387 3 8

0 70 1.7 0 34

8 0.1 1 0.331 7 84 7 7 1.2

0 37

5 A V G 0.1 7 0.412 1 58. 6 1.8 9 34

4 0.1 3 0.361 3 71. 4 1.4 1 371SAMPLIN G TRAIN : PLANT : E P AISOKINETI C SAMPL I irf g FIEL D DAT ASHEE T j r

ORSA TDAT A

DATE : TES TLOCATIO N RU N NUMBER ; Stac k Diamete r•Inches : OPERATOR : ~T jV,,, ^ , STAR TTIME : Y 'i S 3 Ujlf f STO P TIME : <A'4S

-^H^^TS T BAROMETRI C PRESSURE :

~ STATI C PRESSUR E (+/-) : Probe/Pitot Number :

~ Pitot Coefficient :

_Filte rBo xNo. : Mete rBoxNumber : _Orific e Coefficien t (Y) : "Delt a H@ ; Nozzl e Size : XA D Thermocoupl e ID : Impinge rOutle

t ID : •0
.

# ENS R

INTERNATIONAL SAMPLIN G TRAIN : fS\ )^7 > ArPLANT : OfJ^H DATE : \)0\J

\ Q TES TLOCATION : RU N NUMBER : Stac k Diamete r- Inches

### INTERNATIONAL. PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train: A H 2- 3 Recovered by: foUrt^S RunNo.V^-rZ'l

Date:

/ / fcf RunNo.V2--fl?-~Date: jl faf) XAD Module No.: XAD Module No. : Filter No. : * Filter No.: ~~~ Impinge r No
. Initia l

Volum e (mL ) Fina l

Volum e

. (mL ) Rins e

Volum e (mL ) Impinge r

No
. Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL ) N?* C fyr*-

^ t £ 

### 1 

# #

7 1 0
2 /(TO 2 1 CT D 3 I

(SO 3 /(TO
4 O 33.5 " 4 0 or 5 5 0 0 6 6
7 7 DIFF : DIFF : Total s Total s 

# 1 1 1 Initia l

Weigh t (g ) Fina l

Weigh t (9 ) •lilt ;

DIFF : W&B : Initia l Weigh t (g ) Fina l

Weigh t (9 ) iplllifi l

DIFF : Silic a Ge l Impinge r 7 ^ 7 - 1 Silic a Ge l Impinge r NeTH 2 0 Gain , m L Ne tH 2 0 Gain , m L m m m m m

### 1 IwJ l 

### ORSA TANALYSI S (EP AMETHO D 3 ) 

# I PLANT : OMV ^ ~ 

# S**%Jr i DATE : h i I?/<>-> - ~ ., - - | LOCATION : 'Uy,, ri SW-K. /u n ^ 3 - W - | SAMPL E 

### TYP E : ^ufe-f W,n^y<*«P"fe w I OPERATOR : 

### vT> i 

### MD&fJ PRE-LEA KCHECK : POST-LEA KCHECK : JLNOTE : Vali

d Lea k Check : Liqui

d level mus

t no t fal l belo wbotto m o fcapillar ytubin g i n 4 minute

s an d meniscu s mus t no t chang e b ymor e tha n 2 m L i n 4 minutes

. DAT ACRITERI A- | CO2 : Whe n greate rtha n 4% , differenc e betwee n reading s shal l b e 0.3 % o rless
. I Whe n les s tha n 4% , differenc e betwee n reading s shal l b e 0.2 % o rless
. I O2

1 Whe n greate rtha n o requa l t o 15% , differenc e betwee n reading s shal l b e 0.2 % o rless
. 1 Whe n les s tha n 15% , differenc e betwee n reading s shal l b e 0.3 % o rless
. L I Ru n # 1 Readin g AReadin g B i Rea d in g C Avg
. Ne t Volum e | GA S Actua l | Ne tActua l i 

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C:\TEMPLATE\DATASHTS\ORSAT.VVK 4

### ORSA TANALYSI S (EP AMETHO D 3 ) PLAN T: £Wf X-S**#k DAT E : (Amy -a - t H j-mA s LOCATION : ff /p o - I SAMPL E TYP E /vgJL h t 

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t no t fal l belo wbotto m o fcapillar ytubin g in 4 minute

s an d meniscu s mus t no tchang e b ymor e tha n 2 m L i n 4 minutes

. 

### CQ 2 Qzi DAT ACRITERI A- Whe n greate rtha n 4% , differenc e betwee n reading s shal l b e 0.3 % o rless
. Whe n les s tha n 4% , differenc e betwee n reading s shal l b e 0.2 % o rless
. Whe n greate rtha n o requa l t o 15% , differenc e betwee n reading s shal l b e 0.2 % o rless
. Whe n les s tha n 15% , differenc e betwee n reading s shal l b e 0.3 % o rless
. ! Run## - Readin g A ! 

### Readin g B Rea d ing C Avg
. Ne t Volum e J! G A S Actua l Ne t Actua l : 

### Ne t 1 I Actua l Ne t Avg
. Ne t Volum e 

### CO 2 >);•>- V 

### j ° 2 * 6 ' ° I ll * i )$• * II- 0 

### n ° Run*! } Rea c in g A Readin g B Readin g C Avg
. Ne t Volum e G A S Actua l Ne t Actua l ! Ne t j Actua l Ne t Avg
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. C:\TEMPLATBDATASHTS\0RSAT.WK 4Metho d 2 9 (Metals ) Samplin g Parameter s 

### Onyx , Fixe d Heart h Incinerato r# 2 Ru n No
. 1 2 Dat e 20-Nov-0 2 20-Nov-0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 10:1 9 14:1 7 AVG S Nozzl e Diamete r inche s 0.43 1 0.43 1 0.43 1 Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Ne tSamplin g Tim e min
. 120. 0 120. 0 120. 0 Volum e Metere d dc f 82.01 3 81.87 0 81.94 2 Avg
. DG M Temp.
. ° F 60. 3 74. 1 67. 2 Av g Delt a H i n H 2 0 1.6 0 1.5 3 1.5 6 Av g Delt a H in
. H g 0.117 6 0.112 1 0.114 9 DG M Calibratio n Facto r — 1.007 7 1.007 7 1.007 7 Ga s Sampl e Volum e dsc f 83.30 8 80.99 4 82.15 1 Tota l Wate rCollecte d m L 1211. 9 1117. 0 1164. 5 Volum e o fWate rVapo r sc f 57.14 1 52.66 7 54.90 4 Moistur e (measured ) % v/v 40. 7 39. 4 40. 0 Moistur e ( @ saturation ) % v/v 101. 0 101. 0 101. 0 Dr yMol e Fraction , 100-% M 

# - 0.593 2 0.606 0 0.599 6 C 0 2a tStac k %dr y 4.7 0 4.1 0 4.4 0 0 2a tStac k %dr y 11.0 0 11.0 0 11.0 0 C O + N 2 %dr y 84.3 0 84.9 0 84.6 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 9 29.1 0 29.1 4 We tMolecula rWeigh t Ib/lb-mol e 24.6 4 24.7 2 24.6 8 Exces s Ai ra tStac k % 97. 7 96. 4 97. 1 Stac k Diamete r inche s 39. 0 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H 2 0 0.3 2 0.3 3 0.3 3 Stac k Pressur e in
. H g 29.6 2 29.6 2 29.6 2 Avg
. Stac k

Temp
. ° F 342. 6 361. 3 352. 0 Avg
. Sqroo to fDelt a P — 0.374 9 0.363 4 0.369 2 SD E Averag e — 10.62 1 10.41 4 10.51 8 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,69 4 1,65 8 1,67 6 Stac k Flowrat e we tacf m 14,05 4 13,75 6 13,90 5 Stac k Flowrat e we tscf m 9,15 4 8,75 6 8,95 5 Stac k Flowrat e dscf m 5,43 0 5,30 6 5,36 8 Isokinetic s % 10 5 10 4 10 4 Mete rBo xNo
. — 8058 2 8058 2 

# - Delt a H @ i n H 2 0 1.923 3 1.923 3 

# - Fiel d Q AYq c — 0.994 0 0.986 7 0.990 4 [Deviation ] Pre- Y % 1.36 % 2.08 % 1.72 % J:\Air_Tox\Projec t Files\0nyx\0ny x2CJ 2 wortrtNovembe r2002\FIet(MJni t 2\(M2 9 U2.xls]DAT ASAMPLIN G TRAIN : PLANT : DATE : IrT C E P AISOKINETI C SAMPLlTT O - FIEL D DAT ASHEE T

TES TLOCATIO N RU N NUMBER : Stac k Diamete r- inches : 3 7 OPERATOR : STAR TTIME : STO P TIME : CfuS ion BAROMETRI C PRESSURE :

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### W W
Ne tH 2 0 Gain , m L A'.' , Ne tH 2 0 Gain , m L

### Metho d 26 A Samplin g Parameters Onyx , Fixe d Hear l h Incinerato r# 2 Ru n No . 1 2 Dat e 20-Nov-0 2 20 -NOV -0 2 Star tTim e Unit s 08:1 5 12:1 5 Sto p Tim e 10:1 9 14:1 7 AVG S Nozzl e Diamete r inche s 0.43 4 0.43 4 0.43 4 Barometri cPressur e in
. H g 29.6 0 29.6 0 29.6 0 Ne tSamplin g Tim e min
. 120. 0 120. 0 120. 0 Volum e Metere d dc f 79.50 1 81.65 2 80.57 7 Avg
. DG M Temp
. ° F 73. 0 82. 8 77. 9 Av g Delt a H i n H 2 0 1.5 3 1.6 3 1.5 8 Av g Delt a H in
. H g 0.112 7 0.119 5 0.116 1 DG M Calibratio n Facto r 

# - 1.002 2 1.002 2 1.002 2 Ga s Sampl e Volum e dsc f 78.382 79.074 78.728 Tota l Wate rCollecte d m L 1204. 3 994. 5 1099. 4 Volum e o fWate rVapo r sc f 56.78 3 46.89 1 51.83 7 Moistur e (measured ) % v/v 42. 0 37. 2 39. 6 Moistur e ( @ saturation ) % v/v 101. 0 101. 0 101. 0 Dr yMol e Fraction , 100-% M — 0.579 9 0.627 7 0.603 8 C 0 2a t Stac k %dr y 4.7 0 4.1 0 4.4 0 0 2a t Stac k %dr y 11.0 0 11.0 0 11.0 0 C O + N 2 %dr y 84.3 0 84.9 0 84.6 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 9 29.1 0 29.1 4 We tMolecula rWeigh t Ib/lb-mol e 24.4 9 24.9 7 24.7 3 Exces s Ai ra t Stac k 

### la 97. 7 96. 4 97. 1 Stac k Diamete r inche s 39. 0 39. 0 Stac k Are a _ sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H 2 0 0.2 6 0.2 5 0.2 6 Stac k Pressur e in
. H g 29.6 2 29.6 2 29.6 2 Avg
. Stac k

Temp
. ° F 349. 8 373. 1 361. 4 Avg
. Sqroo to fDelt a P — 0.349 5 0.355 4 0.352 5 S D E Averag e — 9.94 6 10.25 7 10.10 2 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,59 1 1.62 5 1,60 8 Stac k Flowrat e we tacf m 13,20 2 13,48 4 13,34 3 Stac k Flowrat e we tscf m 8,52 2 8,46 0 8,49 1 Stac k Flowrat e dscf m 4,942 5,31 1 5,126 Isokinetic s % 10 7 10

0 10

3 Mete rBo xNo
. — 8058 1 8058 1 — Delt a H @ i n H 2 0 2.038 7 2.038 7 

# - Fiel d QAYq c — 0.987 0 0.999 8 0.993 4 [Deviation ] Pre- Y % 1.52 % 0.24 % 0.88 % J:\AirJox\Projec t Rles\0nyx\0ny > 200 2 wortrtNovembe r2002\Reld\Unt t 2\[M2 9 UZxIsJDAT A

### Onyx , Fixe d Heart h Incinerato r# 2
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a P SQR T

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. 6 6 1.6 0 35 7 a 2 0.1 2 0.346 4 6 9 5 6 1.5 0 34 7 0.1 3 0.360 6 7 1 6 7 1.7 0 36 8 a 3 0.1 2 0.346 4 7 5 5 9 1.5 0 34 8 0.1 3 0.360 6 7 9 6 9 1.7 0 37 1 a 4 0.1 3 0.360 6 7 9 6 3 1.6 0 35 0 0.1 2 0.346 4 8 3 7 1 1.5 0 37 4 a 5 0.1 3 0.360 6 8 2 6 6 1.6 0 35 2 0.1 3 0.360 6 8 7 7 4 1.7 0 37 7 a 6 0.1 0 0.316 2 8 4 6 8 1.3 0 35 1 0.1 0 0.316 2 9 0 7 7 1.3 0 37 7 a 7 0.1 0 0.316 2 7 9 7 1 1.3 0 34 8 0.1 2 0.346 4 8 8 7 8 1.5 0 37 3 a 8 0.1 3 0.360 6 8 3 7 2 1.6 0 35 4 0.1 5 0.387 3 9 4 8 1 1.9 0 37 3 a 9 0.1 3 0.360 6 8 6 7 3 1.6 0 35 4 0.1 5 0.387 3 9 8 8 2 1.9 0 37 6 a1 0 0.1 3 0.360 6 8 5 7 3 1.6 0 35 3 0.1 3 0.360 6 10 0 8 5 1.7 0 37 8 a1 1 0.1 4 0.374 2 8 7 7 4 1.8 0 35 1 0.1 2 0.346 4 10 2 8 6 1.6 0 37 7 a1 2 0.1 3 0.360 6 8 8 7 5 1.6 0 35 1 0.1 1 0.331 7 10 3 8 8 1.4 0 37 6
AV G 0.1 2 0.349 5 73. 0 1.5 3 35 0 0.1 3 0.355 4 82. 8 1.6 3 37 3 NOTE : D O NO TDELET E ROW S 6 O R 3 1 I F ADJUSTIN G FIL E FO R ACTUA L NUMBE R O F POINTS!! !SAMPLIN G TRAIN : PLANT : DATE : TES TLOCATIO N RU N NUMBER : Stac k Diamete r 

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Date:

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### Metho d 23 ASamplin g Parameter s Onyx , Fixe d Heart h Incinerato r# 3 (w / Mete rBo x8075 4 re-callibration ) Ru n No
. 1 2 Dat e 19-Nov-0 2 19-Nov-0 2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 12:5 6 16:3 7 AVG S Nozzl e Diamete r inche s 0.43 2 0.43 2 0.43 2 Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Ne tSamplin g Tim e min
. 180. 0 180. 0 180. 0 Volum e Metere d dc f 123.50 8 122.51 7 123.01 3 Avg
. DG M Temp
. o p 73. 2 73. 4 73. 3 Av g Delt a H i n H 2 0 1.4 6 1.4 0 1.4 3 Av g Delt a H in
. H g 0.107 2 0.102 9 0.105 1 D G M Calibratio n Facto r 

### - - 1.002 4 1.002 4 1.002 4 G a s Sampl e Volum e dsc f 122.34 7 121.29 1 121.81 9 Tota l Wate rCollecte d m L 1541. 3 1517. 3 1529. 3 Volum e o fWate rVapo r sc f 72.67 2 71.54 1 72.10 6 Moistur e (measured ) % v/ v 37. 3 37. 1 37. 2 Moistur e ( @ saturation ) % v/ v 100. 6 100. 6 100. 6 Dr yMol e Fraction , 100-% M — 0.627 4 0.629 0 0.628 2 C O za t Stac k %dr y 4.3 0 3.4 0 3.8 5 0 2a t Stac k %dr y 13.1 0 13.6 0 13.3 5 C O + N 2 %dr y 82.6 0 83.0 0 82.8 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.2 1 29.0 9 29.1 5 We tMolecula rWeigh t Ib/lb-mol e 25.0 3 24.9 7 25.0 0 Exces s Ai ra t Stac k 

### % 150. 5 163. 6 157. 0 Stac k Diamete r inche s 39. 0 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H z O -0.1 6 -0.2 0 -0.1 8 Stac k Pressur e in
. H g 29.7 4 29.7 4 29.7 4 Avg
. Stac k

Temp
. ° F 333. 8 344. 2 339. 0 Avg
. Sqroo to fDelt a P — 0.336 4 0.358 4 0.347 4 S D E Averag e — 9.47 6 10.16 2 9.81 9 Pito tCoefficien t „ 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,49 7 1,60 7 1,55 2 Stac k Flowrat e we tacf m 12,41 6 13,33 1 12,87 3 Stac k Flowrat e we tscf m 8,20 9 8,69 9 8,45 4 Stac k Flowrat e dscf m 5,15 0 5,47 2 5,31 1 Isokinetic s 

### % 10 8 10 0 10 4 Mete rBo xNo
. — 8075 4 8075 4 — Delt a H @ in
. H g 1.905 0 1.905 0 — J:\Air_Tox\Prqec

t Files\Onyx\Ony

x200 2 worMNovembe

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A

### Metho d 23 A Samplin g Parameter s — 

### Onyx , Fixe d Heart h Incinerato r# 3 Ru n No
. 1 2 Dat e 19-Nov-0 2 19-Nov-0 2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 12:5 6 16:3 7 AVG S Nozzl e Diamete r inche s 0.43 2 0.43 2 0.43 2 Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Ne tSamplin g Tim e min
. 180. 0 180. 0 180. 0 Volum e Metere d dc f 123.50 8 122.51 7 123.01 3 Avg
. DG M Temp
. ° F 73. 2 73. 4 73. 3 Av g Delt a H i n H 2 0 1.4 6 1.4 0 1.4 3 Av g Delt a H in
. H g 0.107 2 0.102 9 0.105 1 D G M Calibratio n Facto r — 1.010 7 1.010 7 1.010 7 G a s Sampl e Volum e dsc f 123.36 1 122.29 6 122.82 8 Tota l Wate rCollecte d m L 1541. 3 1517. 3 1529. 3 Volum e o fWate rVapo r sc f 72.67 2 71.54 1 72.10 6 Moistur e (measured ) % v/ v 37. 1 36. 9 37. 0 Moistur e ( @ saturation ) % v/v 100. 6 100. 6 100. 6 Dr yMol e Fraction , 100-% M — 0.629 3 0.630 9 0.630 1 C O za t Stac k % dr y 4.3 0 3.4 0 3.8 5 O za t Stac k %dr y 13.1 0 13.6 0 13.3 5 C O + N 2 % dr y 82.6 0 83.0 0 82.8 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.2 1 29.0 9 29.1 5 We tMolecula rWeigh t Ib/lb-mol e 25.0 6 25.0 0 25.0 3 Exces s Ai ra t Stac k % 150. 5 163. 6 157. 0 Stac k Diamete r inche s 39. 0 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H 2 0 -0.1 6 -0.2 0 -0.1 8 Stac k Pressur e in
. H g 29.7 4 29.7 4 29.7 4 Avg
. Stac k

Temp
. o p 333. 8 344. 2 339. 0 Avg
. Sqroo to fDelt a P - 0.336 4 0.358 4 0.347 4 S D E Averag e — 9.47 6 10.16 2 9.81 9 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,49 6 1,60 6 1,55 1 Stac k Flowrat e we tacf m 12,41 0 13,32 5 12,86 8 Stac k Flowrat e we tscf m 8,20 5 8,69 5 8,45 0 Stac k Flowrat e dscf m 5,16 3 5,48 6 5,32 5 Isokinetic s % 10 8 10 1 10 5 Mete rBo xNo
. — 8075 4 8075 4 - Delt a H @ in
. H g 1.923 4 1.923 4 - - Fiel d Q AYq c 0.95 4 0.94 5 0.95 0 [Deviation ] Pre- Y % 5.6 % 6.5 % 6.0 % J:\Air_Tox\Proje d Files\0nyx\0nyx200 2 worMNovember2002\Field\Uni t 3\[M2 3 U3.xls)DAT Af

i

Onyx , Fixe d Heart h Incinerato r#3
P T RU N 1 AVGS - PCDDs/PCDF s i RU N 2 AVG S - PCDDs/PCDF s P T D P SOR T D P DG M

IN DG M

OU T D H STAC K TEM P D P SQR T D P DG M

I N DG M

OU T D H STAC K TEM P a l 0.1 2 0.346 4 7

1 60 1.5 0 330 0.1 6 0.4000 6 3 6

2 1.7

0 33

4 a 2 0.1 3 0.3606 6 9 5

9 1.7

0 325 0.1 6 0.4000 7 6 68 1.7 0 338 a 3 0.1 1 0.331 7 7 6 6

2 1.4

0 330 0.1 5 0.387 3 8

0 7

0 1.7

0 330 a 4 0.1 0 0.316 2 7

8 66 1.3 0 33

2 0.1 2 , 0.346 4 8

2 7

3 1.3

0 331 a 5 0.0

9 0.3000 8 1 6

9 1.1 0 33 4 0.1 1 ( 0.331 7 8 3 7

2 1.2

0 331 a 6 0.0

7 0.264

6 8

9 7

5 0.9

0 34

0 0.1 0 s 0.316 2 8

4 7

3 1.1 0 333 a 7 0.1 4 0.374 2 8

5 7

2 1.8

0 337 0.1 2 j 0.346 4 7

6 6

9 1.3

0 333 a B 0.1 4 0.374 2 7

8 68 1.8 0 335 0.1 2 ! 0.3464 7 9 6

9 1.3

0 359 a 9 0.1 4 0.374 2 8

1 68 1.8 0 336 0.1 5 i 0.387 3 80 69 1.6 0 36 1 a1 0 0.1 2 0.346 4 8

0 6

8 1.5

0 33

6 0.1 1 : 0.331 7 7 8 68 1.2 0 36

2 al l 0.1 1 0.331 7 8 5 6

8 1.4

0 33

5 0.1 2 I 0.3464 7 5 •64 1.3 0 357 a1 2 0.1 0 0.316 2 7

9 6

9 1.3

0 33

5 0.1 3 ! 0.3606 8 0 6

9 1.4

0 361 AV G 0.1 1 0.336 4 73.2 1.4 6 33

4 0.1 3 I 0.3584 73. 4 1.4 0 34

4



### f

# ENSR ,

t/VTEHNATiONAL SAMPLIN G TRAIN : (V\ V ^ A PLANT : O/V/y " DATE : fJ'-" TES TLOCATION : RU N NUMBER : ] Stac k Diamete r- Inches :

ikJ L " 3 ^ OPERATOR : STAR TTIME : STO P TIME : ( I

VVELOCIT Y P n BAROMETRI C PRESSURE :

_STATI C PRESSUR E (+/-) : ]

_Probe/Pitot Number : .Pito t Coefficient : Filte rBo xNo. : Mete rBoxNumber : _Orific e Coefficien t (Y) : [Delt a H@ : Nozzl e Size : _XA D Thermocoupl e ID : Impinge rOutle

t ID : 

### EP AISOKINETI C SAM K IS 

### 1 FIEL D DAT ASHEE T
-O \<o o.8 4 INITIAL VAC .

MI D VAC . FINA L VAC . LEA KCHECKS :

' O In . CF M o.aOXI . Q\ u~> INIT . PITO T
' FINA L PITO

T I
. C 

### \ 1 3 4 ORSATFinal : — in . CF M " — In . CF M 0
. 0 O 3
+ . , FILTE R DAT A "NUfill ! TAR E

•• y — IMPJNG6.R . VOL' S ' INIT'."* ' 7 7 ° 3- 3 C >

SILIC AGE L * Fina l Vo l Rins

e Volume s
1 3 2 Or

\ JA TDAT A 

### c;o 2

FO R MOISTUR E CALC : NE TGAIN : ml .

m i SAMPLE'

1 POINT , rCLOC K "TIMS' " $ET6 &Va| » GA S METE R 

### met TEMPERATUR E READINGS . * F 

### 3 f t '""PlNGE R - S 

### 7 lifftf f 7 1 _CL l F VACUUM ! PUM P
4 l 4 S 4 ^
. T 4 l 

### 4 t I T
T3c T 

### 1 2 ^ 7 ? I M A 

### H i 2 X Ei Ve t 3 E 

### 4 ^ 4 

### § 1 3 3

M IT 2L. T H T 

### o Z

# ens* * n i l A SAMPLIN G TRAI N PLANT : Q

A / DATE : E P AISOKINETI C SAMPL I ORSA TDAT A

TES TLOCATIO N RU N NUMBER : Stac k Diamete r- inches : OPERATOR : STAR TTIME : STO P TIME : j SO

S CO .

### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T FO R MOISTUR E DETERMINATIO N Sample Train : A l 7~?

Recovered by: vj~ / fhOiZ/tif Run No. Date: i\\ l l RunNo\)



### 3-/2- > Date : ^ XAD Module No. : XAD Module No.: QcJick STSS

~] Filter No.: ^ M " Filter No.: " Impinge r No
. i Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL ) Impinge r

No
. •J - ; Initia l Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL )
1 

### 0 7 7 0 1 

### 0 

# ^@ * ] ^
2 f

CT D 3&o 

# r 2
3 . 3 fen?
4 C

> 4 o a-d-i
5 5
6 6
7 7 DIF F : DIFF : Total s Total s

Initia l Weigh t (g ) Fina l

-Weigh t (9 ) 

### liiiiili ^ Initia l Weigh t (g ) Fina l

Weigh t (g ) Initia l Weigh t (g ) Fina l

-Weigh t (9 ) DIFF : Initia l Weigh t (g ) Fina l

Weigh t (g ) DIF F : Silic a Ge l Impinge r Silic a Ge l Impinge r Ne tH 2 0 Gain , m L /SV/. 3 

### tSSii f Ne tH 2 0 Gain , m L 

### ^^^^ ^

### 110 1 ORSA TANALYSI S (EP AMETHO D 3)

0 M f3 PRE-LEA KCHECK : g ^

I PLANT : OMV ^ - j: L j ! DATE : U\11 /cr> . ' 1 POST-LEA KCHECK : ga , 1 LOCATIO N : Uy,, ^ Cyt^ k

/u„ . hT fPK-IL . j SAMPL E TYP E : t^o^-f^'HT - (^h?ry^4 > fe<g_NOTE : Vali d Lea k Check : Liqui

d level mus

t no t fal l OPERATOR : 

### Mfi&iJ belo wbotto m o fcapillar ytubin g i n 4 minute

s an d meniscu s mus t no t chang e b ymor e tha n 2 m L in 4 minutes

. DAT ACRITERI A- j CO2 : Whe n greate rtha n 4% , differenc e betwee n reading s shal l b e 0.3 % o rless , j i Whe n les s tha n 4% , differenc e betwee n reading s shal l b e 0.2 % o rless
. O 2 ; Whe n greate rtha n o requa l t o 15% , differenc e betwee n reading s shal l b e 0.2 % o rless
. Whe n les s tha n 15% , differenc e betwee n reading s shal l b e 0.3 % o rless
. I Ru n #1 Readin g AReadin g B ! Rea d in g C Avg
. Ne t Volum e | GA S Actua l j Ne tActua l ! Ne t ! i I ! Actua l Ne t Avg
. Ne t Volum e CO 2 

# tf. 

# lh i 

# ¥•3 

# !

O 2 * Mr

> i 

# n>- 

# (3-0
! Ru n #2 i

Readin g AIReadin g B Rea d in g C Avg
. Ne t Volum e G A S Actua l | Ne t; Actua l ij Ne t Actua l Ne t Avg
. Ne t Volum e CO 2 1 ! 3 3 3 - }
O 2 * /3.5 l

# (id- 

# on 17. 0 

# n.i Run#£ i Readin g Ai Readin g B Rea d ing C Avg
. Ne t Volum e • • G A S Actua l Ne t! Actua l Ne t Actua l Ne t Avg
. Ne t Volum e • • CO 2 I 

### fa 1 • 

# f t i l O 2 * 

# ,1.0

Ne tO 2 i s actua l O 2 minu s actua l CO 2 reading
. C:\TEMPLATBDATASHTS\ORSAT.WK 4Metho d 2 9 (Metals ) Samplin g Parameter s Onyx , 

### Fixe d Hear

t hIncinerato r# 3 Ru n No
. 1 2 Dat e 19-Nov-0 2 19-Nov-0 2 StartTim e Unit s 09:4 5 13:3 5 Sto p Tim e 11:5 2 15:4 5 AVG S Nozzl e Diamete r inche s 0.43 4 0.43 1 0.43 3 Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Ne tSamplin g Tim e min
. 120. 0 120. 0 120. 0 Volum e Metere d dc f 94.89 7 82.46 8 88.68 3 Avg
. DG M Temp
. o p 71. 1 77. 8 74. 4 Av g Delt a H i n H 2 0 2.1 1 1.5 8 1.8 4 Av g Delt a H in
. H g 0.155 0 0.115 8 0.135 4 DG M Calibratio n Facto r — 1.007 7 1.007 7 1.007 7 Ga s Sampl e Volum e dsc f 95.01 7 81.44 8 88.233 Tota l Wate rCollecte d m L 1201. 0 1036. 7 1118. 9 Volum e o fWate rVapo r sc f 56.62 7 48.88 0 52.75 4 Moistur e (measured ) % v/v 37. 3 37. 5 37. 4 Moistur e ( @ saturation ) % v/v 100. 6 100.6 100. 6 Dr yMol e Fraction , 100-% M 

# - 0.626 6 0.624 9 0.625 8 C 0 2a tStac k %dr y 4.3 0 3.4 0 3.8 5 0 2a tStac k %dr y 13.1 0 13.6 0 13.3 5 C O + N 2 %dr y 82.6 0 83.0 0 82.8 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.2 1 29.0 9 29.1 5 We tMolecula rWeigh t Ib/lb-mol e 25.0 3 24.9 3 24.9 8 Exces s Ai ra tStac k

* " % 150. 5 163.6 157. 0 Stac k Diamete r inche s 39. 0 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H 2 0 -0.1 0 -0.0 6 -0.0 8 Stac k Pressur e in
. H g 29.7 4 29.7 5 29.7 4 Avg
. Stac k

Temp
. ° F 328. 2 355. 3 341. 7 Avg
. Sqroo to fDelt a P 

## - 0.392 6 0.371 4 0.382 0 SD E Averag e 

# - 11.02 3 10.60 5 10.81 4 Pito tCoefficien t 

# - 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,74 1 1,67 8 1,71 0 Stac k Flowrat e we tacf m 14,44 4 13,92 1 14,18 3 Stac k Flowrat e we tscf m 9,61 9 8,96 4 9,29 1 Stac k Flowrat e dscf m 6,027 5,60 2 5,81 4 Isokinetic s % 10 6 9

9 10

3 Mete rBo xNo
. — 8058 2 8058 2 

## - Delt a H @ i n H 2 0 1.923 3 1.923 3 

# - Fiel d Q AYq c 

# - 0.992 9 0.996 4 0.994 7 [Deviation ] Pre- Y % 1.47 % 1.12 % 1.29 % J:\Air_Tox\Projec t R!es\0nyx\0ny x200 2 worMNovembe r2002\Reld\Uni t 3\(M2 9 U3.xls)DAT A

### Ris k Bur n Phas e 2 - Tes t Conditio n B
P T R U N 1 AVGS-METAL S R U N 2 AVG S - - METAL S P T Delt

a P SQR T

Delt a P DG M

IN DG M

OU T Delt

a H STAC K TEM P Delt

a P SQR T

Delt a P DG M

IN DG M

OU T Delt

a H STAC K TEM P 3 1 0 .1 4 0.374

2 5 6 5 5 1.8 0 31 2 0.1 2 0.346 4 7 0 7 0 1.3 0 35 0 a 2 0.1 8 0.424

3 6 5 5 7 2.4 0 31 8 0.1 4 0.374 2 7 6 7 1 1.6 0 35 3 a 3 0.1 7 0.412

3 7 1 6 0 2.3 0 32 5 0.1 6 0.400 0 7 9 7 2 1.8 0 35 7 a 4 0.1 6 0.400

0 7 5 6 3 2.2 0 32 8 0.1 4 0.374 2 8 2 7 4 1.6 0 35 9 a 5 0.1 6 0.400

0 7 7 6 5 2.2 0 32 9 0.1 3 0.360 6 8 2 7 4 1.5 0 35 7 ae 0.1 7 0.412

3 8 0 6 8 2.3 0 33 0 0.1 6 0.400 0 8 3 7 5 1.8 0 35 5 a 7 0.1 5 0.387

3 7 9 7 0 2.2 0 32 9 0.1 1 0.331 7 7 9 7 5 1.3 0 33 1 a 8 0.1 7 0.412

3 7 8 7 0 2.3 0 33 3 0.1 3 0.360 6 8 1 7 6 1.5 0 34 8 a 9 0.1 7 0.412

3 8 0 7 0 2.3 0 33 5 0.1 5 0.387 3 8 3 7 6 1.7 0 36 0 a1 0 0.1 6 0.400

0 8 2 7 2 2.2 0 33 7 0.1 4 0.374 2 8 5 7 7 •1.6 0 36 4 a1 1 0.1 3 0.360

6 84 7 3 1.8 0 33 8 0.1 5 0.387 3 8 5 7 7 1.7 0 36 5 a1 2 0.1 0 0.316

2 8 3 7 4 1.3 0 32 4 0.1 3 0.360 6 8 6 7 8 1 .5 0 36 4
AV G 0.1 6 0.392 6 71. 1 2.1 1 32 8 0.1 4 0.371 4 77. 8 1.5 8 35 5SAMPLIN G TRAIN : ' / lgTAt, S PLANT : OQY ^ DATE : TES TLOCATION : -fr? , RU N NUMBER : [ Stac k Diamete r- Inches : OPERATOR : STAR TTIME : STO P TIME : BAROMETRI C PRESSURE : [STATI C PRESSUR E (+/-) : Probe/Pitot Number : Pitot Coefficient : Filte rBo xNo. :

_Mete rBoxNumber : "orific e Coefficien t (Y) : "Delt a H@ : Nozzl e Size : XA D Thermocoupl e ID : Impinge rOutle

t ID : 

### EP AISOKINETI C SAMPLIN G - FIEL D DAT ASHEE T LEA KCHECKS : 7 a l.' r O INITIAL VAC . j "5 In . CF M Q.O\Q MI D VAC . FINA L VAC . j< -

—in . CF M

in . CF M 0.8 4 INIT

. PITO T
' FINA L PITO

T ORSATInitial : ORSATFinal : '•NUMBER. ' ''"•.TARE-'' . INI T

/CO F|NAL~ | 1ST JE 2L '.•• » 'SILICAGEL»- Fina l Vo l > ' Q Volume

s
T 5 F ORSA TDAT A CO .

FO R MOISTUR E CALC : NETGAIN : ml . TEMPERATUR

E READINGS

, * F ' PIJMP . I n H T 52= . -S3 - '•COMMENT-;

2
. C o /5 - ?3 " V< 0 £5 2 6 5Z

> Z -3 5-Z.3 33 D s o Lo 2.Z , 25 7 _<£<2
_ 2 3 . 7 0 •5 0 ICO IIP c9,f o t.- L LfS
_ i- J t&:t ZM S 25 7 S 3 J2£
_ / 3 fa /VSAMPLIN G TRAIN : PLANT : •<Ok>HY DATE : 

### EP AISOKINETI C SAMPL I 

# i FIELD ! DAT ASHEE T lewi s
TES TLOCATION : OO f»" 5 RU N NUMBER : Stac k Diamete r•Inches : OPERATOR : SJhrff STAR TTIME : rsfll ^ STO P TIME : 'HS* " (ftr T BAROMETRI C PRESSURE : STATI C PRESSUR E (+/-) :

_Probe/Pitot Number : Pito t Coefficient : Filte rBo xNo. :

_Mete rBoxNumber : "Orific e Coefficien t (Y) : "Delta H @ :

_Nozzl e Size : _XA D Thermocoupl e ID : Impinge rOutle

t ID : - C I INITIAL VAC . MI D VAC . ' FINA L VAC . LEA

KCHECKS : [5 In . • — In . In . CF M Q.t&S CF M — CF M £?.<r^^— ' :'jMp|N9ERi5iOL'S-.;f i INIT5S7.;FINAli S Volumes
0.8 4 INIT

. PITO T

ORSATFinal : IT- 5 -NUMBER. •TAP E

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• '•S O r"lK >

.-?-siucA..eEu i ? ; Fina l Vol , ORSA TDAT A CCV •1

FO R MOISTUR E CALC : NE TGAIN : ml .

- M ~ ' " J
. If ! 'S

fCO N f'ENT S 1IHJm . 

### MreR/v/irfONAL.

PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train: Recovered by: \f)/ *

/M 0 \ $ Run No. U3-£ tDate: H / t 1 Run

No. U 3 —&

2" Date: j | |/ 7 XAD Module

No.: XAD Module

No. Filter No. . . /pue^fo

Lf^'S'fosri Filter No.: Impinge r Initia l

Volum e (mL ) Fina l

Volum e Rins e

Volum e (mL ) Impinge r

No
. Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL )

0 

### 1
I o o 

# S6 o |CJ D 

# d m / 0

# ° " 5

s /<5rt

> O /<rd j o o 

## / c r o | o o /cn )

DIFF : DIF F Total s Total s

Initia l Weigh t (9 ) Fina l

Weigh t •(g ) DIFF : mm Initia l Weigh t (9 ) Fina l

Weigh t (9 ) DIFF : Silic a Ge l Impinge r 

### m . 3

" ' "ffl Silic a Ge l Impinge r V6/.2
. Ne tH 2 0 Gain , m L •V. u a Ne tH 2 0 Gain , m L

### Metho d 26ASamplin g Parameters Onyx , Fixe d Heart h Incinerato r# 3 Ru n No
. 1 2 Dat e 19 -NOV -0 2 19 -NOV -0 2 Star tTim e Unit s 09:4 5 13:3 5 Sto p Tim e 11:5 2 15:4 5 AVG S Nozzl e Diamete r inche s 0.43 4 0.43 4 0.43 4 Barometri cPressur e in
. H g 29.7 5 29.7 5 29.7 5 Ne tSamplin g Tim e min
. 120. 0 120. 0 120. 0 Volum e Metere d dc f 86.75 3 79.20 0 82.97 7 Avg
. DG M Temp
. ° F 81. 0 84. 2 82. 6 Av g Delt a H i n H z O 1.8 7 1.5 3 1.7 0 Av g Delt a H 0.137 3 0.T12 1 0.124 7 DG M Calibratio n Facto r — 1.002 2 1.002 2 1.002 2 Ga s Sampl e Volume 

### dsc f 84.762 76.86 1 80.81 2 Tota l Wate rCollecte d m L 1121. 8 1021. 1 1071. 5 Volum e o

fWate rVapo r sc f 52.89 3 48.14 5 50.51 9 Moistur e (measured ) %v/ v 38. 4 38. 5 38. 5 Moistur e ( @ saturation ) %v/ v 100. 6 100. 6 100.6 DryMol e Fraction , 100-% M 

### - - 0.615 8 0.614 9 0.615 3 C 0 2a t Stac k %dr y 4.3 0 3.4 0 3.8 5 0 2a t Stac k %dr y 13.1 0 13.6 0 13.3 5 C O + N 2 %dr y 82.6 0 83.0 0 82.8 0 Dr yMolecula rWeigh t Ib/lb-mol e 29.2 1 29.0 9 29.1 5 We tMolecula rWeigh t Ib/lb-mol e 24.9 0 24 .8 2 24.8 6 Exces s Ai ra t Stac k % 150. 5 163. 6 157. 0 Stac k Diamete r inche s 39. 0 39. 0 Stac k Are a sq . in
. 1194. 6 1194. 6 1194. 6 Stati cPressur e i n H 2 0 0.0 6 -0.1 0 -0.0 2 Stac k Pressur e in
. H g 29.7 5 29.7 4 29.7 5 Avg
. Stac k

Temp
. " F 330. 9 360. 7 345. 8 Avg
. Sqroo to

fDelt a P — 0.352 0 0.351 5 0.351 7 SD E Averag e — 9.89 9 10.06 8 9.98 3 Pito tCoefficien t 

## - 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,56 7 1.59 7 1,58 2 Stac k Flowrat e we tacf m 12,99 9 13,24 8 13,12 4 Stac k Flowrat e we tscf m 8,63 0 8,47 3 8,55 1 Stac k Flowrat e dscf m 5,31 4 5,21 0 5,26 2 Isokinetic s % 107 99 10 3 Mete rBo xNo
. — 8058 1 8058 1 — Delt a H @ i n H 2 0 2.038 7 2.038 7 

## - Fiel d Q AYq c — 1.002 1 0.997 6 0.999 9 [Deviation ] Pre- Y 0.01 % 0.45 % 0.23 % J:\Air_Tox\Prcjec

l Fi!es\Onyx\Ony

x200 2 worMNovembe

r20O2\Fiel(MJni

t 3\(M2 9 U3.xls]DAT A

### Onyx , Fixe d Heart h Incinerato r# 3
P T R U N 1 AVGS - -PM/H C : i /

ci 2 R U N 2 AVG S —P M / HC I / CI , P T Delt

a P SQR T

Delt a P DG M

IN DG M

ou t Delt

a H STAC K

TEM P Delt

a P SQR T

Delt a P DG M

IN DG M

OU T Delt

a H STAC K

TEM P a 1 0.1 4 0.374 2 6 5 6 3 1.9 0 31 6 0.0 9 0.300 0 7 5 7 5 1.1 0 34 2 3 2 0.1 5 0.387 3 7 4 6 6 2.1 0 32 3 0.0 9 0.300 0 7 9 7 5 1.1 0 35 3 a 3 0.1 5 0.387 3 8 1 6 9 2.1 0 32 8 0.1 3 0.360 6 8 4 7 7 1.6 0 35 7 a 4 0.1 3 0.360 6 8 6 7 2 2.0 0 33 0 0.1 3 0.360 6 8 8 7 9 1.6 0 36 2 a 5 0.1 1 0.331 7 9 0 7 6 1,7 0 33 2 0.1 3 0.360 6 9 0 8 1 1.6 0 36 3 a 6 0.0 7 0.264 6 8 8 7 7 1.1 0 31 6 0.1 4 0.374 2 9 0 8 2 1.7 0 36 1 a 7 0.1 2 0.346 4 8 3 7 2 1.8 0
. 33 1 0.1 3 0.360 6 8 5 8 3 1.6 0 36 1 a S 0.1 5 0.387 3 8 9 8 1 2.3 0 33 7 0.1 4 0.374 2 9 0 8 4 1.7 0 36 3 a 9 0.1 3 0.360 6 9 2 8 3 2.0 0 33 8 0.1 3 0.360 6 9 1 8 4 1.6 0 36 4 31 0 0.1 3 0.360 6 9 4 8 4 2.0 0 34 0 0.1 4
. 0.374 2 9 1 8 4 1.7 0 36 7 a1 1 0.1 1 0.331 7 9 4 8 5 1.7 0 34 0 0.1 3 0.360 6 9 2 8 4 1.6 0 36 8 a1 2 0.1 1 0.331 7 9 4 8 6 1.7 0 34 0 0.1 1 0.331 7 9 3 8 5 1.4 0 36 7
A V G 0.1 3 0.352 0 81. 0 1.8 7 33 1 0.1 2 0.351 5 84. 2 1.5 3 36 1 NOTE : D O NO TDELET E ROW S 6 O R 3 1 I F ADJUSTIN G FIL E FO R ACTUA L NUMBE R O F POINTS!! !

# ENS R
SAMPLIN G TRAIN : J4A(*A PLANT : Qpu DATE : JJ, E P AISOKINETI C SAMPL 1

TES TLOC A RU N NUMBE R Stac k Diamete r- inches : R u n I 0,8 4 M L OPERATOR : /£ € STAR TTIME : O^ TA « STO P TIME : ft.tl BAROMETRI C PRESSURE : 2^. 7,f |STATI C PRESSUR E (+« : Q,Q( a

_Probe/Pitot Number :

_Pitot Coefficient : Filte rBoxNo. : NB-/1 _Mete rBoxNumber : fSCS&f [orific e Coefficien t (Y) : / GOjLfi. "Delta H ( Nozzl e Size : Q.* y _XA D Thermocoupl e ID : -"^/ / INITIA L VAC . \ MI D VAC . " FINA L VAC. ' FIEL D DAT ASHEE T

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Date:

| | )| 7 ji m JV AU 3 ~ tf3 - H 11 ? X4Z > Mo-iu/ e Ab
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### 0023 A Samplin g Parameter s 

### Onyx , Rotar yKil n Incinerato r# 4 {wl Mete rBo x8075 4 re-callibration ) Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-Nov-0 2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 12:5 0 17:0 1 11:2 0 AVG S Nozzl e Diamete r inche s 0.31 5 0.31 5 0.31 5 0.31 5 Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29.5 3 Ne tSamplin g Tim e min
. 180. 0 180. 0 180. 0 180. 0 Volum e Metere d dc f 149.46 2 148.55 7 151.66 0 149.89 3 Avg
. DG M Temp
. ° F 59. 7 58. 4 67. 0 61. 7 Av g Delt a H i n H z O 2.0 8 2.1 0 2.1 8 2.1 2 Av g Delt a H in
. H g 0.152 6 0.154 4 0.160 5 0.155 8 D G M Calibratio n Facto r — 1.002 4 1.002 4 1.002 4 1.002 4 Ga s Sampl e Volum e dsc f 150.59 6 150.06 7 152.01 0 150.89 1
-. . Tota l Wate rCollecte d — - m L —1581. 8 — —1642. 1 1735. 6 1653. 2 Volum e o fWate rVapo r sc f 74.58 2 77.42 5 81.83 4 77.94 7 Moistur e (measured ) % v/ v 33. 1 34. 0 35. 0 34. 1 Moistur e ( @ saturation ) %v/ v 101. 7 101. 7 100. 8 101. 4 Dr yMol e Fraction , 100-% M — 0.668 8 0.659 7 0.650 0 0.659 5 C 0 2a t Stac k %dr y 3.9 0 3.8 0 4.5 0 4.0 7 O za t Stac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 C O + N 2 %dr y 82.6 0 82.6 0 82.1 0 82.4 3 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 6 29.1 5 29.2 6 29.1 9 We tMolecula rWeigh t Ib/lb-mol e 25.4 7 25.3 6 25.3 2 25.3 8 Exces s Ai ra t Stac k 

### % 162. 5 165. 7 161. 9 163 . 4 Stac k Diamete r inche s 48. 0 48. 0 48. 0 48. 0 Stac k Are a sq . in
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. H g 29.4 2 29.4 2 29.6 7 29.5 1 Avg
. Stac k

Temp
. ° F 381. 8 381. 8 389. 4 384. 3 Avg
. Sqroo to fDelt a P — 0.804 7 0.817 9 0.822 8 0.815 1 S D E Averag e — 23.34 8 23.73 0 23.98 1 23.68 6 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 3,67 6 3,74 4 3,77 0 3,73 0 Stac k Flowrat e we tacf m 46,18 8 47,04 5 47,38 1 46,87 1 Stac k Flowrat e we tscf m 28,49 0 29,01 7 29,20 7 28,90 4 Stac k Flowrat e dscf m 19,05 4 19,14 1 18,98 6 19,06 0 Isokinetic s 

### % 102 10 1 10 3 10 2 Mete rBo xNo
. — 8075 4 8075 4 8075 4 

# - Delt a H @ in
. H g 1.905 0 1.905 0 1.905 0 

# - J:\Air_Tox\Prqjec

t FilesVOnyxMDny

x200 2 worMNovembe

r2002\Field\Uni

t 4\(M2 3 U4(recal)jds]DAT

A

### Metho d 0023 ASamplin g Parameter s Onyx , Rotar yKil n Incinerato r# 4 Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-Nov-0 2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 12:5 0 17:0 1 11:2 0 AVG S Nozzl e Diamete r inche s 0.31 5 0.31 5 0.31 5 0.31 5 Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29 .5 3 Ne tSamplin g Tim e min
. 180. 0 180. 0 180. 0 180. 0 Volum e Metere d dc f 149.46 2 148.55 7 151.66 0 149.89 3 Avg
. DG M Temp
. ° F 59. 7 58. 4 67. 0 61. 7 Av g Delt a H i n H 2 0 2.0 8 2.1 0 2.1 8 2.1 2 Av g Delt a H in
. H g 0.152 6 0.154 4 0.160 5 0.155 8 D G M Calibratio n Facto r — 1.010 7 1.010 7 1.010 7 1.010 7 Ga s Sampl e Volum e dsc f 151.84 3 151.30 9 153.26 8 152.14 0 Tota l Wate rCollecte d m L 1581. 8 1642. 1 1735. 6 1653. 2 Volum e o fWate rVapo r sc f 74.58 2 77.42 5 81.83 4 77.94 7 Moistur e (measured ) % v/ v 32. 9 33. 8 34. 8 33. 9 Moistur e ( @ saturation ) % v/ v 101. 7 101. 7 100. 8 101. 4 Dr yMol e Fraction , 100-% M — 0.670 6 0.661 5 0.651 9 0.661 3 C O za t Stac k %dr y 3.9 0 3.8 0 4.5 0 4.0 7 0 2a t Stac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 C O + N 2 %dr y 82.6 0 82.6 0 82.1 0 82.4 3 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 6 29.1 5 29.2 6 29.1 9 We tMolecula rWeigh t Ib/lb-mol e 25.4 9 25.3 8 25.3 4 25.4 0 Exces s Ai ra t Stac k 

### % 162. 5 165. 7 161. 9 163. 4 Stac k Diamete r inche s 48. 0 48. 0 48. 0 48. 0 Stac k Are a sq . in
. 1809. 6 1809. 6 1809. 6 1809. 6 Stati cPressur e i n H z O -0.3 8 -0.3 6 -0.4 0 -0.3 8 Stac k Pressur e in
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. Stac k

Temp
. ° F 381. 8 381. 8 389. 4 384. 3 Avg
. Sqroo to fDelt a P — 0.804 7 0.817 9 0.822 8 0.815 1 S D E Averag e — 23.34 8 23.73 0 23.98 1 23.68 6 Pito tCoefficien t 0.8 4 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 3,67 4 3,74 2 3,76 9 3.72 8 Stac k Flowrat e we tacf m 46,16 9 47,02 5 47,36 1 46,85 2 Stac k Flowrat e we tscf m 28,47 9 29,00 5 29,19 4 28,89 3 Stac k Flowrat e dscf m 19,09 8 19,18 7 19,03 3 19,10 6 Isokinetic s 

### % 10 3 102 10 4 10 3 Mete rBo xNo
. 

## - - 8075 4 8075 4 8075 4 Delt a H @ in
. H g 1.923 4 1.923 4 1.923 4 — Fiel d QAYq c — 0.93 3 0.94 4 0.94 5 0.94 1 [Deviation ] Pre- Y 

### % 7.6 % 6.6 % 6.5 % 6.9 % J:\Air_Tox\Projec

t Files\Onyx\Ony

x200 2 worMNovembe

r2002\Field\Uni

I 4\(M2 3 U4.xls]DAT

ARCR ATria l Bur n

P T RU N 1AVGS - - PCDDs/ 1 PCDF s RU N 2 AVGS - PCDDs/PCDF s RU N 3 AVG S - - PCDDs/PCDF s P T D P SQR T D P DG M

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0 0.836

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6 2.3 0 38 0 0.6

6 0.812

4 6

4 5

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### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

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f7. 3 r/3 < Readin g B Actua l Ne t

3 * ! 3 ^ Ne t

Rea d Actua l

3 . ? in g C

Ne t

3 ^

Readin g C Actua l

3 * 

## 1M Ne t

3 ^ 1 3 . t
Ne tO2 i s actua l O2 minu s actua l CO 2 reading
. Avg
. Ne t Volum e



## ffAvg
. Ne t Volum e 

### 3, ?

Avg
. Ne t Volum e
3 ?

C:\TEMPLATE\DATASKTS\0RSAT.WK 4

# E_NR

R

ORSA T ANALYSI S (EP A METHO D 3 ) PLANT ; DATE :

OPERATOR : ,J 7 / H 

### Mo/titfs PRE-LEA K CHECK : POST-LEA KCHECK : LOCATIO N : 

### U^j-'Y JTW r | SAMPL E TYP E -.fH^Lfl -f-r i nhvAfdbJ

NOTE : Vali d Lea k Check : Liqui

d level mus

t no t fal l belo wbotto m o fcapillar ytubin g in 4 minute

s an d meniscu s mus t no t chang e b ymor e tha n 2 m L in 4 minutes

. DAT ACRITERI A- [ CO2 : Whe n greate rtha n 4% , differenc e betwee n reading s shal l b e 0.3 % o rless
. I Whe n les s tha n 4% , differenc e betwee n reading s shal l b e 0.2 % o rless
. I Qu

Whe n greate rtha n o requa l t o 15% , differenc e betwee n reading s shal l b e 0.2 % o rless
. Whe n les s tha n 15% , differenc e betwee n reading s shal l b e 0.3 % o rless
. R u n # 3 Readin g A Readin g B G A S Actua l

CO 2

0 2 * j|7,<

4 Ne t

4 4 Actua l Ne t

R u n # 2 G A S

CO 2
O 2 Readin g A

Actua l Ne t Readin g B Actua l Ne t

Ru n # 3 G A S

CO 2
O 2 * Readin g A

Actua l Ne t Readin g B Actua l Ne t Readin g C Actua l 

# M S
\l.<\ Ne t

4 4 i m Readin g C Actua l Ne t

Readin g C Actua l Ne t Avg
. Ne t Volum e M.- 5

Avg
. Ne t Volum e

Avg
. Ne t Volum e

Ne tO 2 i s actua l O 2 minu s actua l CO 2reading
. C:\TEMPLATBDATASHTS\0RSAT.WK 4Metho d 2 9 (Metals ) Samplin g Parameter s 

### Onyx , Rotar

yKil n Incinerato r# 4 Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-Nov-0 2 StartTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 11:4 0 15:5 9 10:2 2 AVG S Nozzl e Diamete r inche s 0.31 6 0.31 6 0.31 6 0.31 6 Barometri cPressur e in
. H g 29.4 5 29.4 5 29.7 0 29.5 3 Ne tSamplin g Tim e min
. 120. 0 120. 0 120. 0 120 . 0 Volum e Metere d dc f 95.99 2 93.70 7 93.87 8 94.52 6 Avg
. DG M Temp
. ° F 63. 3 58. 3 61. 2 60. 9 Av g Delt a H i n H 2 0 2.0 9 2.0 8 2 .1 3 2 .1 0 Av g Delt a H in
. H g 0.153 8 0.152 6 0.156 3 0.154 2 DG M Calibratio n Facto r — 1.007 7 1.007 7 1.007 7 1 .007 7 Ga s Sampl e Volum e dsc f 96.57 0 95.17

7 95.637 95.795 Tota l Wate rCollecte d m L 1019. 2 1075. 2 1111. 1 1068. 5 Volum e o fWate rVapo r sc f 48.055 " 50.69 6 52.38 8 50.38 0 Moistur e (measured ) % v/v 33. 2 34. 8 35. 4 34. 5 Moistur e ( @ saturation ) % v/v 101. 7 101. 7 100. 8 101. 4 Dr yMol e Fraction , 100-% M 

# - 0.667 7 0.652 5 0.646 1 0.655 4 C 0 2atStac k %dr y 3.9 0 3.8 0 4.5 0 4.0 7 O zatStac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 C O + N 2 %dr y 82.6 0 82.6 0 82.1 0 82.4 3 DryMolecula rWeigh t Ib/lb-mol e 29.1 6 29.1 5 29.2 6 29.1 9 We tMolecula rWeigh t Ib/lb-mol e 25.4 5 25.2 8 25.2 7 25.3 3 Exces s Ai ra tStac k % 162. 5 165. 7 161. 9 163. 4 Stac k Diamete r inche s 48. 0 48. 0 48. 0 48. 0 Stac k Are a sq . in
. 1809. 6 1809. 6 1809. 6 1809. 6 Stati cPressur e i n H 2 0 -0.3 8 -0.3 6 -0.4 0 -0.3 8 Stac k Pressur e in
. H g 29.4 2 29.4 2 29.6 7 29 .5 1 Avg
. Stac k

Temp
. ° F 385. 8 384. 3 390. 8 387 . 0 Avg
. Sqroo to fDelt a P 

# - 0.801 4 0.811 2 0.811 8 0.808 2 SD E Averag e — 23.30 8 23.573 23.68 0 23.52 0 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 3,67 0 3,72 5 3,72 6 3,70 7 Stac k Flowrat e we tacf m 46,12 0 46,80 7 46,82 7 46,58 5 Stac k Flowrat e we tscf m 28,31 1 28,78 5 28,81 7 28,63 8 Stac k Flowrat e dscf m 18,90 4 18,78 1 18,61 8 18,768 Isokinetic s % 98 97 99 98 Mete rBo xNo
. — 8058 2 8058 2 8058 2 

# - Delt a H @ i n H 2 0 1.923 3 1.923 3 1.923 3 

# - Fiel d Q AYq c — 0.976 2 0.991 5 0.998 2 0.988 6 [Deviation ] Pre- Y % 3.13 % 1.61 % 0.94 % 1.89 % J:\Air_Tox\Projec t Rles\Onyx\Ony x200 2 mrttNovembO ' 2002\Reld\Uni t 4\[M2 9 U 4 jclsJDAT A

### Ris k Bur n Phas e 2 - Tes t Conditio n B P T •RU N 1 AVG S --MET
. MS R U N 2 AVG S - METAL S R U N 3 AVG S - METAL S P T Delt

a P SQR

T Delt a P DG M

I N OG M OU T Delt a H 

# i STAC K TEM P Delt

a P SQR

T Delt a P DG M

I N DG M OU T Delt a H STAC K TEM P Delt

a P SQR

T Delt a P DG M

I N DG M OU T Delt

a H STAC K TEM P a 1 0.6

4 0.800

0 5 3 5

2 2 .1 0 38

5 0.6

4 0 .800 0 5 1 5

1 1.9

0 I 38

1 0 .6

9 0.830

7 5 2 4 8 2.1 0 387 a 2 0.6

8 0.824

6 6 5 5

5 2.2

0 38

7 0.6

1 0.781 0 5

6 5

1 1.8

0 38

3 0.6

7 0.818

5 5 8 4

9 2 .1 0 39 0 a 3 0.6

2 0.787

4 6 8 5

7 2.0

0 38

6 0.6

7 0.8

1 & 5 5 9 5

2 2.0

0 38

3 0.6

7 0.818

5 6 2 5

1 2.1 0 39 1 a 4 0.6

4 0.800

0 6 8 5

9 2 .1 0 38

6 0.6

2 0 .787 4 5 9 5

3 2.0 0 38

3 0.6

8 0.824

6 6 0 52 2.1 0 39 1 a 5 0.6

4 0.800

0 7 2 6

1 2 .1 0 38

6 0.66 0

.812 4 6 2 5

4 2 .1 0 38

5 0.6

7 0.818

5 6 6 55 2 .1 0 39 1 a 6 0.6

2 0.787

4 7 1 6

1 2 .0

0 38

6 0.6

9 0 .830 7 6 3 5

5 2 .3

0 38

5 0 .6

5 0.806

2 6 7 5

6 2 .1 0 388 a 7 0.6

2 0.787

4 6 5 6

0 2.0 0 38

6 0.6

8 0.824

6 6 3 5

6 2 .2

0 38

5 0.6

3 0.793

7 6 9 5

8 2 .1 0 38 9 a 8 0.6

8 0.824

6 6 8 6

0 2 .2

0 38 5 0.66 0

.812 4 6 4 5

5 2 .1 0 38

5 0.6 6 0.812

4 7 0 5

9 2 .2

0 39 5 a 9 0.6

7 0.818

5 7 0 6

1 2 .2

0 38 5 0.66 0.812

4 66 5

7 2.1 0 38

6 0 .66 0.812

4 7 1 6

1 2 .2

0 39 5 a1 0 0.6

0 0.774

6 7 0 6

1 2.0 0 38

6 0.66 0

.812 4 66 5

7 2 .1 0 38

5 0.6 6 0.812

4 6 9 6 1 2.2 0 38 9 a1 1 0.6

5 0.806

2 6 9 6

1 2 .1 0 38

5 0.6

9 0.830

7 66 5

8 2 .2

0 38

5 0.6

4 0.800

0 73 63 2 .1 0 38 9 a1 2 0.6

5 0.806

2 7 1 6

1 2 .1 0 38

5 0.66 0

.812 4 6 7 5

8 2 .1 0 38

6 0.6

3 0.793

7 7 4 6

4 2.1 0 39 5
AV G 0.6 4 0.801 4 63. 3 2.0 9 38 6 0.6 6 0.8111 2 58. 3 2.0 8 38 4 0.6 6 0.811 8 61. 2 2.1 3 39 1

# J E P A ISOKINETI C SAMPu l FIEL D DAT A SHEE T
\ SAMPLIN G TRAIN : PLANT : DATE : TES TLOCATION : RU N NUMBER : j Stac k Diamete r- inches : OPERATOR : STAR TTIME : STO P TIME : BAROMETRI C PRESSURE : STATI C PRESSUR E (+/-) : ~ ' I'/Z / IC7 Probe/Pitot Number : UUv TPlto t Coefficient : \ Filte rBoxNo. : H8> Mete rBoxNumber : J —Orific e Coefficien t (Y) : J ^H&ADelta H @ : ~ ICfiHg rOi& ioSt. //__TNozzl e Size : " \\fXf^ !&*€> flZZ. XA D Thermocoupl e ID : -ass INITIAL VAC . MI D VAC . FINA L VAC. ' LEA KCHECKS :



### S In .

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In . CF M £>.£ ' / ;|-, ; iMejN9gR.yoL isi : CF M - — (0 0.B 4 j__?12_ L INIT . PITO T [FINA L PITO

T" [ORSA TInitial : ORSATFinal : CFM Q GQ% /cZ> FILTE R DAT

A

ci-r NUMBE R

3 * , - E %,®^. , { '" K v-ELOcrrv , HLTER vc " D. '0. ' In.« = G^S METE R TEMPERATUR E READING

S F 3 * , - E %,®^. , { '" K v-ELOcrrv , HLTER vc " D. '0. ' In.« = ..... PR0o c FILTE R co x 

# mm, IMIMMMM i 3 * , - E %,®^. , { '" K v-ELOcrrv , HLTER vc " D. '0. ' In.« = ..... PR0o c FILTE R co x 

# mm,

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Volume s ORSATDAT A

O R MOISTUR E CALC : E TGAIN : ml .SAMPLIN G TRAI N PLANT : DATE : TES TLOCATION : RU N NUMBER :
OPERATOR : STAR TTIM E STO P TIME : E P AISOKINETI C SAMPL f 

### - FIEL D DAT ASHEE T LEA KCHECKS : 

### \ & In
. CF M 8

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1 COj " • •

rSAMPLIN G TRAIN : PLANT : DATE : 

### EP AISOKINETI C SAM .

TES TLOCATION : OhSir *? RU N NUMBER : J2 , Stac k Diamete r- Inches : h6 OPERATOR : STAR TTIME : STO P TIME : BAROMETRI C PRESSURE : STATI C PRESSUR E (+/•) : ~ Probe/Pitot Number : Plto t Coefficient : Filte rBoxNo. : Mete rBoxNumber : Orific e Coefficien t (Y) : "Delt a H @ : Nozzl e Size : XADiThermocoupl e ID : INITIAL VAC . MI D VAC . ' FINA L VAC . 

### FIEL D DAT ASHEE T LEA KCHECKS : l(o in . CF M COO*?

CF M 13 in .

' in . 0.8 4

•INIT

. PITO T FINA L PITOT " CF M (p oo3
FILTE R DAT

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, rINIT. . . ..IFINAC

J Volume s CO s o ICO ICO o ICO ICQ FO

R MOISTUR

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WBmSSSal STAC K PPHl l C AME T E R UMP ' ! CUU M n H o £ > rCMFICE . IKRmnlM B 1 —

WBmSSSal STAC K PPHl l $|pfl$^l3w$| P I I ' OU T UMP ' ! CUU M n H o 

## ~AT~\ £ > Z.A ^ ."M O STAC K t 7 10 O.bl Zl $&>..r 3 7 ~ 

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### \ - If i 7.x £•?£>. & ZL/t . Z £ / 

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i MMHMMifAS TERM Ar/ONAi. 

### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train: fh/T ) Recovered by: xf v^ W

0 KJ Q S Run No. \JH " ^ 3

Date: ^ | >2— - Run No. Date : XAD Module No.: XAD Module No. : Filter No. : impinge r No
. Initia l

Volum e (mL ) 

### : " Fi n

Volu i (m L a l n e

-) 

## m Rins e Volum e (mL ) Impinge r

No
. Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL )
1 

## 0 1
2 j o o f l 

# / 2
3 

## fm 3
4 

## 0 4
5 5
6 /(St> 6
7 7 DIFF : DIFF : Total s Total s

Initia l Weigh t (g ) Fina l

Weigh t (g ) T i l Initia l Weigh t (g ) Fina l

Weigh t (9 ) Initia l Weigh t (g ) Fina l

Weigh t (g ) T i l Initia l Weigh t (g ) Fina l

Weigh t (9 ) DIFF : Silic a Ge l Impinge r Silic a Ge l Impinge r

. NetH 2 0 Gain , m L Ne tH 2 0 Gain , m L ^S8 S

### Metho d 26ASamplin g Parameters Onyx , Rotar

yKil n Incinerato r# 4 Ru n No
. Ru n 1 Ru n 2 Ru n 3 Dat e 21-Nov-0 2 21-Nov-0 2 22-Nov-0 2 Star tTim e Unit s 09:4 5 13:5 2 08:1 5 Sto p Tim e 11:4 0 15:5 9 10:2 2 AVG S Nozzl e Diamete r inche s 0.31 6 0.31 6 0.31 6 0 .31 6 Barometri cPressur e in
. H g 29:4 5 29.4 5 29.7 0 29.5 3 Ne tSamplin g Tim e min
. 120. 0 120. 0 120. 0 120. 0 Volum e Metere d dc f 90.25 4 88.55 1 91.21 9 90.00 8 Avg
. DG M Temp
. ° F 72. 9 66. 3 67. 3 68. 8 Av g Delt a H i n H 2 0 1.9 5 1.9 3 2.0 4 1.9 8 Av g Delt a H in
. H g 0.143 4 0.142 2 0.150 1 0 .145 2 DG M Calibratio n Facto r — 1.002 2 1.002 2 1.002 2 1 .002 2 Ga s Sampl e Volum e dsc f 88 .64 7 88.065 91.329 89 .34 7 Tota l Wate rCollecte d m L 1010. 5 1028. 1 1094. 0 1044. 2 Volum e o fWate rVapo r sc f 47.64 5 48.47 5 51.58 2 49.23 4 Moistur e (measured ) % v/ v 35. 0 35. 5 36. 1 35. 5 Moistur e ( @ saturation ) % v/v 101 . 7 101 . 7 100. 8 101. 4 Dr yMol e Fraction , 100-% M 

# - 0.650 4 0.645 0 0.639 1 0.644 8 C 0 2a t Stac k %dr y 3.9 0 3.8 0 4.5 0 4.0 7 0 2a t Stac k %dr y 13.5 0 13.6 0 13.4 0 13.5 0 C O + N 2 %dr y 82.6 0 82.6 0 82.1 0 82.4 3 Dr yMolecula rWeigh t Ib/lb-mol e 29.1 6 29.1 5 29.2 6 29.1 9 We tMolecula rWeigh t Ib/lb-mol e 25.2 6 25.1 9 25.1 9 25.2 2 Exces s Ai ra t Stac k % 162. 5 165. 7 161. 9 163. 4 Stac k Diamete r inche s 48. 0 48. 0 48. 0 Stac k Are a sq . in
. 1809. 6 1809. 6 1809. 6 1809. 6 Stati cPressur e i n H z O -0.3 8 -0.3 6 -0.4 0 -0.3 8 Stac k Pressur e in
. H g 29.4 2 29.4 2 29.6 7 29.5 1 Avg
. Stac k

Temp
. ° F 389. 2 384. 7 391. 7 388. 5 Avg
. Sqroo to fDelt a P — 0.752 9 0.758 6 0.774 9 0.762 1 SD E Averag e 

# - 21.93 8 22.04 8 22.61 3 22.20 0 Pito tCoefficien t — 0.8 4 0.8 4 0.8 4 0 .8 4 Stac k Ga s Velocit y afp m 3,46 8 3,49 0 3,56 4 3,50 7 Stac k Flowrat e we tacf m 43,57 6 43,85 2 44,78 8 44 ,07 2 Stac k Flowrat e we tscf m 26,64 4 26,95 7 27,53 6 27 ,04 5 Stac k Flowrat e dscf m 17,330 17,386 57,59 7 17,438 Isokinetic s % 9 8 97 10 0 99 Mete rBo xNo
. — 8058 1 8058 1 8058 1 

# - Delt a H @ inH 2 0 2.038 7 2.038 7 2.038 7


# - Fiel d Q AYq c — 0.982 7 0.991 4 0.983 9 0.986 0 [Deviation ] Pre- Y % 1.94 % 1.08 % 1.83 % 1.62 %
J:\Air_Tox\Projec t Files\Onyx\Ony x200 2 work\Novembe r2002VField\Uni t 4\(M2 6 U4.xls]DAT Af/VrE/WAT/O/VAC 

### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train, Recovered by: torn No. 0H-# ) Date: H XAD Module No. : \XAD Module No., Filter No. Filter No. i Impinge r No
. Initia l

Volum e (mL ) Fina l

Volum e (mL )

23Q Rins e

Volum e (mL ) Impinge r

No
. Initia l

Volum e (mL )

0 Fina l Volum e (mL ) Rins e

Volum e (mL ) 

### Sb

/OZ ? A y ©

7 o 

# to. /(fD /Ojo rOt ) ( 2 ° / o O 

## /(SV /S~L
0 

### /C/ O /(n> 

## /00 jdO 

# j CT P 

# ? 1 /(r o
DIFF : DIFF : Total s Total s

Initia l Weigh t (9 ) Fina l Weigh t •(g ) Initia l Weigh t (g ) Fina l

Weigh t (g ) DIFF : Silic a Ge l Impinge r Silic a Ge l Impinge r Ne tH z O Gain , m L Ne tH z O Gain , m L 

# M l

# v

Onyx , Rotar yKil n Incinerato r# 4 P T a 1 RU N 1 AVGS - -PM/H C l/Cl j RU N 2 AVGS — P M / HC I / C U RU N 3 AVG S - P M / HC I / C L P T a 1 Delt

a P 0.6 3 SQR

T Deli a P 0.793 7 DG M I N 5 4 DG

M OU T 5 4 Delt

a H 2.20 STAC

K TEM P 39 0 Delt

a P 0.5 7 SQR

T Delt a P 0.755 0 DG M I N 5 5 DG

M OU T 5 5 Delt

a H 1.8 0 STAC

K TEM P 38 1 Delt

a P 0.5 9 SQR

T Deli a P 0.7681 DG

M I N 5 0 DG

M OU T 4 7 Delt

a H 1.9 0 STAC

K TEM P 38 7 a 2 a 3 0.6

0 0.51 0.774

6 0.7141 7

0 7 7 5

9 6 2 2.0

0 1.7 0 39

0 39 0 0.6

0 0.61 0.774

6 0.781 0 5

9 6 5 5

3 5 5 2.0

0 2.0 0 38

4 38 3 0.5

9 0.5 7 0.7681 0.7550 5

9 6 7 4

8 5 2 1.9

0 1.8 0 38

9 39 0 a 4 0.5

9 0.7681 6

5 6

3 1.9

0 38

8 0.5

6 0.748

3 6 6 5

6 1.8

0 38

3 0.6

2 0.787

4 6 4 5

5 2.20 38

9 a S 0.6

3 0.793

7 7 2 6

6 2.1 0 38

8 0.5

9 0.7681 7

1 5

6 2.0

0 38

5 0.6

6 0.812

4 6 8 59 2.30 39 1 a 6 0.5

8 0.761 6 7

7 . 6

8 1.9

0 38

9 0.6

3 0.793

7 7 4 6

0 2.20 38

5 0.5

9 0.7681 6

9 6

2 1.9

0 391 a 7 0.51 0.7141 7 8 6

9 1.7

0 38

9 0.5

6 0.748

3 7 1 6

2 1.8

0 38

5 0.6

3 0.793

7 7 2 6

4 2.20 39

1 a a 0.5

3 0.728

0 8 7 7

2 1.9

0 39

0 0.5

5 0.741 6 7

7 6

3 1.8

0 38

6 0.61 0.781 0 7 8 6

8 2.1 0 39

4 a 9 0.5

5 0.741 6 8

9 7

3 2.0

0 38

9 0.5

8 0.761 6 7

9 6

5 2.0

0 38

6 0.5

4 0.734

8 8 0 7

0 1.9

0 39

5 a1 0 0.5

3 0.728

0 8 8 7

5 1.9

0 39

0 0.5

2 0.721 1 7

7 6

7 1.8

0 38

6 0.5

7 0.7550 8

2 7

3 2.0

0 39

4 a1 1 0.5

7 0.755

0 8 9 7

5 2.1 0 38

8 0.5

7 0.755

0 8 3 6

8 2.0

0 38

6 0.61 0.781 0 8 7 7

5 2.1 0 39

4 a12 0.5

8 0.761 6 9

1 7

6 2.0

0 38

9 0.5

7 0.755

0 8 4 6

9 2.0

0 38

6 0.6

3 0.793

7 8 9 7

7 2.20 39

5
A V G 0.5

7 0.7529 72. 9 1.9 5 38

9 0.5

8 0.758

6 66. 3 1.9 3 385 0.6

0 0.774

9 67. 3 2.0 4 39

2 NOTE : D O NOTDELET E ROW S 6 O R 3 1 IF ADJUSTIN G FIL E FO R ACTUA L NUMBE R O F POINTS!! !

### EP AISOKINETI C SAMPLI J

ri-?-H» - SAMPLIN G TRAIN : yW ||fc | | Cll-- - BAROMETRI C PRESSURE : PLANT : T P hi

VY- JA U S<

TSTATI C PRESSUR E (+/•) :

Probe/Pitot Number : Pltot Coefficient : Filte rBoxNo. : Mete rBo xNumber : Orific e Coefficien t (Y) : Delta H @ : Ollf' tOiZ

'6SZ. jygr'Nozzl e Size : " i Qfff /jtf fmpt

UHO XA D Thermocoupl e ID : Impinge rOutle

t ID : DATE : TES TLOCATIO N RU N NUMBER : g Stac k Diamete r- inches : INITIAL VAC . • [ MID VAC . " FINA L VAC. " 

### FIEL D DAT ASHEE T LEA KCHECKS :

In . CF M O.ea'o In . CF M ' ' Cr, In . CFM^} , &z. 0.8 4 4 * " Ms-' I
OPERATOR : STAR TTIME : STO P TIME : INIT . PITO T FINA L PITOT " »- 0 3S 7

_ORSATlnitlal:
_ ORSATFinal: " FILTE R DAT A AB E

\J QLLVE : i »*OHlFIGG{f> ] C< 1 of 1 In n A^'P'ROBE " ;•'>! ! 

### £ 2 - TEMPERATUR E READING S ' W INGER 1 ' " I ^ FIUTERBO

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### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T FO R MOISTUR E DETERMINATIO N Sample Train: iHoJj ^

Recovered by: \T\^% lM_ a KfA - T 

### Run No. tf^V^fDate: | { /- M Run No. >

Date:

I j | X I XAD Module No.: XAD Module No. : Filter No. : ~T ~ Filter No.: T Impinge r No
.
» Initia l

Volum e (mL ) Fina l

Volum e (mL )

. —- Ri r

Vol t (n ris e im e L ) Impinge r

No
. Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL ) 

## mmmm 1 1 7 b r

2 

## loo 2
3 

# /** / 3 

## /OV I I /O 

# / 4 O 4 

## 0 

# Y F
5 1 0 0 

## /oo 

# L 5 

## /OD 

# X

6 

## (00 / o o 6 /OO 

## foo
7 7 DIFF : DIFF : Total s Total s

Initia l Weigh t (9 )
. Fina l

Weigh t (g ) Initia l Weigh t (g ) Fina l

Weigh t (9 ) Initia l Weigh t (9 )
. Fina l

Weigh t (g ) ~.FF
. Initia l Weigh t (g ) Fina l

Weigh t (9 ) DIFF : Silic a Ge l Impinge r 

## Cfli( Silic a Ge l Impinge r Ne tH 2 0 Gain , m L Ne tH z O Gain , m LWrERA/Ar/O/VAL. 

### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train: 

### WV-itft

Recovered 

### by: ^f\f^



### pAj> fc&lS Run No. ff - /t 3 Date: 1 ! \> + Run No. Date: XAD Module No.: XAD Module No.: Filter No. : T " Filter No. : Impinge r Initia l

Volum e (mL )

- . Fina l

Volum e (mL ) Rins e

Volum e (mL ) Impinge r

No
. Initia l

Volume - (mL ) Fina l

-Volum e (mL ) 

# n Rins e

Volume — (mL )
1 - 1
2 j

CT D 2
3 /iT D 

### \ n V 3
4 

### 0 

# 3 4
5 /(S O I 

# I 5
6 

### /

(TD \ l p 6
7 7 DIFF : DIF F : Total s Total s

Initia l Weigh t (g ) Fina l

Weigh t (g ) DIFF : Initia l Weigh t (g ) Fina l

Weigh t (g ) DIFF : Silic a Ge l Impinge r 

### m \ Silic a Ge l Impinge r Ne tH 2 0 Gain , m L Ne tH 2 0 Gain , m L 

### ^^^ ^IHSR
. 

### Multi-Metals Blan kCorrectio

n
FRON THAL F BAC KHAL F Correct s FH+B H Element Sampl e Hg Fi d Bl k

Hg Defaul t

Valu e (a

) u g 5

% o f Sample Hg Corrected

Front Hal f M g Sampl e

u g Fi d Bl k

U R Defaul t

Valu e u g 5% o f;

Sampl e u g Correcte d

Bac k Hal f u g Correct s

FH+B H Antimon y(Sb

) 1.0

4 0.59 • 11.61 0.0 5 0.4

5 0.0

0 0.00 1.0 0 0.00 0.4 S Arseni c (As ) 27.00 (0.40 ) 11.61 1.3 5 27.00 0.00 0.0 0 1.0

0 

# - 0.00 27.00 Bariu m (Ba

) 43.5 0 67.00 11.61 * 2.1 8 31.89 0.00 0.0 0 1.0

0 

# - •0.00 31.89 Berylliu m (Be) (0.10 ) (0.10

) 11.61 — (0.10 ) 0.00 0.00 1.0 0 

# - ; 0.00 (0.10 ) Cadmiu m (Cd ) 1.7 5 (0.10

) 11.6 1 0.0 9 1.7

5 0.0

0 0.0

0 . 1.0

0 

# - 0.00 1.7 5 Chromiu m (Cr) 70.5 0 25.00 11.61 » 3.5 3 58.89 0.0 0 0.00 1.0 0 

# - 0.0 0 58.89 Lea d (Pb

) 12.5

0 0.5

5 * 11.61 0.6 3 11.9

5 0.0

0 0.00 1.0 0 

# - 0.00 11.9 5 Nicke l (Ni ) 47.00 62.00 11.61 * 2.35 35.39 0.00 0.00 1.0 0 

# - i 0.00 35.39 Seleniu m (Se

) 3.60 (1.00 ) 11.61 0.1 8 3.6 0 0.00 0.0 0 1.0

0 

# - 0.00 3.60 Silve r(Ag ) 18.0 0 200.00 11.61 * 0.9 0 6.39 0.0 0 0.00 1.0 0 

# - 0.00 6.39 Thalliu m (Tl ) (0.50 ) (0.50

) 11.61 — (0.50 ) 0.0

0 0.00 1.0 0 

# - 0.00 (0.50 )
I fFH B i s between 0 t

o 11.61 n g us

e blan k valu e t o correc t I fFH B > 11.61 n g then us e the greatero f11.61 n g o rthe lesse rvalu e between FH B o r5 % o fFH S .

' - valu e use

d fo rblan k

correctio n (a ) - base d on a 3.2

5 - in . filte rsiz

e I fBH B i s > 0 but <= 1 n g the n us

e the BH B valu e t

o correc t I fBH B i s >

1 n g us e the greatero feithe r1 n g ° r5% o fB H ( ) Not Detected /

Reportabl e Detectio n Limi t
MERCURY i
Mercur y Fractio n Sampl e Hg Fi d Bl k

K g Defaul t

Valu e Hg 5

% o f Sampl e Hg Corrected

Amoun t H g Hg FRON THAL F 0.2 1 0.0 5 » j 6.0

0 0.01 0.1 6 BAC KHAL F 214.45 0.0 5 * : 6.0

0 10.7

2 214.40


## mmm 

# i i mwrnmrn 

# m

i i iiiiiiiiiiiii

i i 'mm TOTA L H g 214.56 

### CLIENT : PROGRA M RU NNO . Onyx, Sauget , I L No v200 2 

### Unit2 Run1

I fF B i s >

0 bu t <= 6 n g the n us

e the F B valu e t

o correc t I fF B i s >

6 n g us e the greatero feithe r6 n g o r5 % o fF H ( ) Not Detected / Reportabl e Detectio n Limi t * Indicate

s valu e use

d fo rblan k

correctio n J:\AlO\u\Prujei 4 Ftia*0ny*\Ony) i 300 1 winlrtNovembc i 2003\Fiold\Uiii l a^METCORfi-Niirtia.i ;mm. 

### Multi-Metals Blan kCorrectio

n
FRON THAL F BAC KHAL F TOTA L
Elemen t Sampl e Hg Fi d Bl k

u g Defaul t

Valu e (a

) Hg 5

% o f! Sampl e u g 

### I Corrected

Fron t Hal f u g Sampl e

u g Fi d Bl k

Hg 

# 1 Defaul t

Valu e Hg 5

% o f Sampl e H g Correcte d

Bac k Hal f Hg COrteCtetJ

FB+B H U S Antimon y(Sb

) 0.7

4 0. 6 * 11.61 0.0 4 

### j ; 0.1 5 0.0 0 o.oo ! 

### I 1.0 0 0.00 0.1 S Arseni c (As ) 11.0 0 (0.40

) 11.61 0.5 5 ; 11.0

0 0.00 0.0 0 i 

### j i 1.0

0 

# - 0.00 11.00 Bariu m (Ba) 55.00 67.00 11.61 * 2.7 5 43.3 9 0.00 0.00

# 1 I 1.0 0 _ 0.00 43.3 9 Berylliu m (Be

) (0.10

) (0.10

) 11.61 

# - (0.10 ) 0.00 0.00 • 

### j 1.0 0 

# - 0.00 (0.10 ) Cadmiu m (Cd ) 0.90 (0.10 ) 11.61 0.0 5 

### j 0.90 0.00 0.0 0 •1.0

0 

# - 0.00 0.90 Chromiu m (Cr) 29.00 25.00 11.61 * 1.4 5 

### i 17.3

9 0.00 0.00 

# 1 1.0 0 

# - 0.00 17.39 Lea d (Pb

) 14.0

0 0.5

5 * 11.61 0.7 0 13.4

5 0.00 0.00 

### i l.o o 

# - 0.00 13.4 5 Nicke l (Ni ) 49.00 62.00 11.61 * 2.4 5 37.39 0.0 0 0.00 i 1.0 0 

# - 0.00 37.3 9 Seleniu m (Se

) 2.1 0 (1.00 ) 11.61 0.1 1 2.1 0 0.00 0.00 ! 1.0 0 — 0.00 2.1 0 Silve r(Ag ) 19.0 0 200.00 11.61 * 0.9 5 7.39 0.00 0.00 ; l.o o 

# - 0.00 7.39 Thalliu m (TI ) (0.50 ) (0.50

) 11.61 

# - (0.50 ) 0.00 0.00 ; l.o o 

# - 0.00 (0.50 )
I fFH B i s between 0 t

o 11.61 n g us

e blan k valu e t o correc t IfFHB > 11.61 n g the n us e the greatero f11.61 ngorth e lesservalu e between FH B o r5 % o fFH S . I fBH B i s > 0 but <= 1 n g the n us

e the BH B valu e t

o correc t I fBH B i s >

1 u g us e the greatero feithe r1 n g o r5 % o fB H

* - valu e used fo rblan k correctio n (a ) - base d o n a 3.2

5 •in . filte rsiz

e ( ) Not Detected / Reportabl e Detectio n Limi t

MERCURY : Defaul t 5 % o f Corrected Mercur y Sampl e Fi d Bl k Valu e Sampl e Amoun t H g Fractio n Hg Hg * Hg Hg i Hg 

### CLIENT : Onyx, Sauget , I L
FRON THAL F 0.1 0 0.0 5 * 6.0

0 0.01 0.0 5 

### PROGRA M: No v200 2 BAC KHAL F 300.6 3 0.0

5 » 6.0

0 15.0

3 300.58 

### RU NNO . Uni t2 Run2 

# I I TOTA L H g 300.63 I fF B i s >

0 but <= 6 n g the n us

e the F B valu e t

o correc t I fF B i s >

6 n g us e the greatero feithe r6 n g o r5% o fF H ( ) Not Detected / Reportabl e Detectio n Limi t * Indicate

s valu e use

d fo rblan k

correctio n JMir_T(w\Pnij« ! FllertOnyjiVJnJ X200 2 wwkWnvcmbe r2002\FtaW\Uni l HlMErCOftR-NotfH.i :ENS R 

### Multi-Metals Blan kCorrectio

n
FRONTHAL F BAC KHAL F TOTA L
Element Sampl e u g Fi d Bl k

u g Defaul t

Valu e (a ) u g 5

% o f Sampl e Hg Corrected

Front Hal f Hg Sampl e

Hg Fi d Bl k

| Hg j Defaul t

; Valu e Hg 5

% o f

### j Sampl e H g : Correcte d

Bac k Hal f : Hg COIT«««c t F H + B H H 8 Antimon y(Sb

) 0.7

7 0.5

9 * 11.6

1 0.0

4 0.1 8 0.0 0 0.0

0 [ ; 1.0

0

_

. 0.00 0.1 8 Arseni c (As ) 2.0 0 (0.40

) 11.6

1 0.1 0 2 .0 0 0.0

0 0.0

0 j 1 .0

0 

# - 0.00 2.0 0 Bariu m (Ba

) 60

.0 0 67

.0 0 11.6

1 * 3

.0 0 48.39 0.0 0 0.0

0 ; 1.0

0 

# - ; 0.0 0 48.3 9 Berylliu m (Be

) (0.10

) (0.10

) 11.6

1 — (0.10 ) 0.0

0 0.0

0 • : 1 .0

0 

# - ; 0.00 (0.10 ) Cadmiu m (Cd ) 3 .0 0 (0.10

) 11.6

1 0.1 5 3.0 0 0.0

0 0.0

0 

### i ; 1 .0

0 

# - i 0.00 3.00 Chromiu m (Cr) 26.0 0 25.0

0 11.6

1 * 1.3

0 14.3

9 0.0

0 o.oo ; ; 1 .0 0 

# - j 0.00 14.39 Lea d (Pb

) 5.20 0.5 5 » 11.6

1 0.2

6 4.65 0.0 0 0.0

0 : 1.0

0 

# - 0.00 4.6S Nicke l (Ni ) 54 .0 0 62.0

0 11.6

1 » 2.7

0 42.3 9 0.0 0 0.0

0 ; 1.0

0 _ : o.o o 42.39 Seleniu m (Se

) 1.1 0 (1.00 ) 11.6

1 0.0

6 1.1 0 0.0 0 0.0

0 

### i 1.0

0 

# - i o.o o 1.1 0 Silve r(Ag ) 160 .0 0 200

.0 0 11.6

1 * 8

.0 0 148.3

9 0.0

0 0.0

0 ; 1.0

0 

# - j •0.00 148.39 Thalliu m (Tl ) (0.50 ) (0.50

) 11.6

1 

# - (0.50 ) 0.0

0 0.0

0 ; 1.0

0 

# - : 0.00 (0.50 ) I fFH B i s between 0 t

o 11.6 1 n g us e blan k valu e t o cor r I fFH B > 11.6

1 n g then us

e the greatero f11.6

1 ugor t 5C t ie lesse rvalu e between FH B o r5 % o fFH S . I fBH B i s > 0 but <= 1 (i g the n us

e the BH B valu e to correc t I fBH B i s >

1 u g us e the greatero feithe r1 n go r5 % o fB H

* - valu e use

d fo rblan k

correctio n (a ) - base d o n a 3.2

5 - in . filte rsiz

e ( ) Not Detected / Reportabl e Detectio n Limi t
MERCURY :
Mercur y Fractio n Sampl e Hg Fi d Bl k

H g Defaul t

Valu e Hg 5

% o f Sampl e Hg Corrected

Amoun t H g Hg 

### CLIENT : Onyx , Sauget , I L FRON THAL F 0.0 7 0.0

5 * 6

.0 0 0.0

0 0.0

2 PROGRA M : No v200 2 BAC KHAL F 130.39 0.0 5 * 6

.0 0 6.5

2 130.3

4 R U NNO . 

### Uni t3 Run1 

# I TOTA L H g 130.36 I fF B i s >

0 but <= 6 n gthen us

e the F B valu e t

o correc t I fF B i s >

6 n gus e th e greatero feithe r6 n go r5 % o fFrt ( ) Not Detected / Reportabl e Detectio n Limi t * Indicate

s valu e use

d fo rblan k

correctio n J.-WrJTtuVProjre l FikrtOnyxVDnyn 200 2 wmkVNownibo

f2O02\Fwtd\Unit 3\IMETCORR-Nort2. L

### Multi-Metals Blan kCorrectio

n
FRON THAL F BAC KHAL F TOTA L Defaul t 5

% o f Correcte d Defaul t 5% o f Correcte d Correcte d Sampl e Fi d Bl k Valu e (a ) Sampl e Front Hal f Sampl e Fi d Bl k Valu e Sampl e Bac k Hal f P H +B H Element u g Hg Hg Hg Hg Hg Hg Hg H g Hg iiiiiiiiiiiiiiigiiiiiiiii i Antimon y(Sb

) 7.50 0. 6 * 11.61 0.38 j 6.91 0.00 0.00 1 : 1.0 0

_ _ 0.00 6.9 1 Arseni c (As ) 3.1 0 (0.40 ) 11.61 0.1 6 3.1 0 0.00 0.00 ; l.o o 

# - 0.00 3.1 0 Bariu m (Ba) 57.00 67.00 11.61 « 2.85 ! 45.39 0.00 0.00 ! 1.0 0 

# - 0.00 45.3 9 Berylliu m (Be) (0.10 ) (0.10

) 11.61

—| (0.10 ) 0.00 0.0 0 i 1 1.0

0 

# - 0.00 (0.10 ) Cadmiu m (Cd ) 1.6 0 (0.10

) 11.61 0.0 8 i 1.6

0 0.0

0 0.00 = ! 1.0 0 

# - 0.00 1.6 0 Chromiu m (Cr) 25.00 25.00 11.61 * 1.2 5 1 13.3

9 0.0

0 0.00 : i 1.0 0 - - 0.00 13.39 Lea d (Pb

) 4.30 0.5 5 * 11.61 0.2 2 3.7

5 0.0

0 0.00 i 1.0 0 

# - 0.00 3.7 5 Nicke l (Ni ) 54.00 62.00 11.61 * 2.7 0 42.39 0.00 0.00 ; i 1.0 0 

# - 0.00 42.3 9 Seleniu m (Se

) 1.0

0 (1.00

) 11.61 0.0 5 1.0

0 0.0

0 0.00 i i 1.0 0 

# - 0.00 1.0 0 Silve r(Ag ) 61.00 200.00 11.61 * 3.0 5 ! 49.3 9 0.00 0.00 ! ! 1.0 0 

# - 0.00 49.3 9 Thalliu m (Tl ) (0.50 ) (0.50

) 11.61 

# - (0.50 ) 0.00 0.00 i ! 1.0 0 

# - 0.00 (0.50 )
I fFH B i s between 0 t

o 11.61 n

gus e blan k valu e t o correc t I fFH B > 11.61 u g the n us e the greatero f11.61 n g o rthe lesservalu e between FH B o r5 % o fFH S .
* - valu e use

d fo rblan k

correctio n

MERCURY : (a ) - base d o n a 3.25 - in . filtersiz e I fBH B i s > 0 but <= 1 n g the n us

e the BH B valu e t

o correc t I fBH B i s >1 n g us

e th e greaterpfeithe r1 n g o r5 % o fB H ( ) Not Detected /

Reportabl e Detectio n Limi t

Mercur y Fractio n Sampl e H g Fi d Bl k

Hg Defaul t

Valu e H g 5

% o f Sampl e Hg Corrected

Amoun t H g i H g FRON THAL F 0.0 7 0.0

5 * 6.0

0 0.00 0.0 2 BAC KHAL F 142.4 9 0.0

5 * 6.0

0 7.1 2 142.4 4

iiiiiiiiiiii i TOTA L H g 142.4 5 CLIENT :



### PROGRA M: RU NNO . Onyx, Sauget , I L No v200 2 Unit3 Run2

I fF B i s >

0 bu t <= 6 n gthe n us

e the F B valu e t

o correc t I fF B i s >

6 u g us e the greatero feithe r6 n go r5 % o fF H ( ) Not Detected / Reportabl e Detectio n Limi t * Indicate

s valu e use

d fo rblan k

correctio n JMir..Ttw\Projcct Fita\Onyi«)iiy * 200 2 wmttNovcmb n 2O02*kld\Un! l SAtMETCORR.N.Mfln.i :

# mat , Multi-Metals Blan kCorrectio

n
FRON THAL F BAC KHAL F

Element Sampl e Hg Fi d Bl k

Hg Defaul t

Valu e (a

) Hg 5

% o f Sampl e Hg Corrected

Front Hal f Hg Sampl e

Hg Fi d Bl k

Hg Defaul t

Valu e Hg 5%

o f Sampl e H g Corrected

! Bac k

Hal f 

### i H g Correcte d F H + B H fig Antimon y(Sb

) 0.6

7 0.59 * 11.61 0.0 3 0.0

8 0.00 0.0 0 1.0

0 0.00 0.0 8 Arseni c (As ) 2.50 (0.40 ) 11.61 0.1 3 2.50 0.0 0 0.00 1.0 0 — 0.00 2.S0 Bariu m (Ba

) 50.00 67.00 11.61 * 2.50 38.39 0.0 0 0.00 1.0 0 — 0.00 38.39 Berylliu m (Be

) (0.10

) (0.10

) 11.61 — (0.10 ) 0.0

0 0.00 1.0 0 

# - 0.00 (0.10 ) Cadmiu m (Cd ) 1.1 0 (0.10 ) 11.61 0.0 6 1.1 0 0.00 0.0 0 1.0

0 — 0.00 1.1 0 Chromiu m (Cr

) 23.00 25.00 11.61 * 1.1 5 11.3 9 0.0

0 0.0

0 1.0

0 — 0.00 11.39 Lea d (Pb

) 13.0

0 0.5

5 * 11.61 0.6 5 12.4

5 0.0

0 0.0

0 1.0

0 .. . 

### i 0.00 12.4 5 Nicke l (Ni ) 41.00 62.00 11.61 * 2.0 5 29.3 9 0.0 0 0.00 1.0 0 — 0.00 29.39 Seleniu m (Se

) (1.00

) (1.00

) 11.61 — (1.00 ) 0.0

0 0.00 1.0 0 — 0.00 (1.00 ) Silve r(Ag ) 74.00 200.00 11.61 * 3.7 0 62.39 0.0 0 0.00 1.0 0 

# - i o.oo 62.39 Thalliu m (Tl ) (0.50 ) (0.50

) 11.61 

# - (0.50 ) 0.00 0.0 0 1.0

0 

# - 0.00 (0.50 ) I fFH B i s betwee n 0 t

o 11.61 n g us

e blan k valu e t o correc t I fBH B is> 0 but<= l n g the n us e the BH B valu e t

o correc t I fFH B > 11.6 1 n g the n us e the greatero f11.61 n g o rthe lesservalu e between FH B o r5 % o fFH S . I fBH B i s > 1 n g us e the greatero feithe r1 n g o r5% o fB H

* - valu e use

d fo rblan k

correctio n (a ) - base d o n a 3.2

5 - in . filte rsiz

e ( ) Not Detected / Reportabl e Detectio n Limi t
MERCURY ;
Mercur y Fractio n Sampl e Hg Fi d Bl k

Hg Defaul t

Valu e Hg 5

% o f Sampl e Hg Corrected

Amoun t H g Hg 

### CLIEN T : Onyx, Sauget , I L
FRON THAL F 1.4 0 0.0

5 * 6.0

0 0.0

7 1.3

5 PROGRAM : 

### No v200 2 BAC KHAL F 38.98 0.0 5 » 6.0

0 1.9

5 38.9

3 R U NNO . 

### Uni t4 Run1


## mmm TOTA L H g 40.28 I fF B i s >

0 but <= 6 n g the n us

e the F B valu e t

o correc t I fF B i s >

6 n g us e the greatero feithe r6 n g o r5 % o fF H ( ) Not Detected / Reportabl e Detectio n Limi t * Indicate

s valu e use

d fo rblan k

correctio n JMir_TPii\Projw t PiWOnyxtffciy * 200 2 wittNowmbe r 2O02\FieU\Uni t

3^ETCORR-NoV02,l
.

# I

Multi-Metals Blan kCorrectio

n
FRON THAL F BAC KHAL F TOTA L Defaul t 5%

o f; Corrected . Defaul t 5% o f Correcte d Correcte d Sampl e Fi d Bl k Valu e (a ) Sampl e Front Hal f Sampl e Fi d Bl k Valu e Sampl e Bac k Hal f FB+B H Element u g M S u g u g j u g ' u g u g ; \ u g H

g u g . . . M* . Antimon y(Sb

) 0.5

3 0. 6 11.61 0.0 3 i (0.53) 0.0 0 0.00 \ i l.o o 0.00 (0.53) Arseni c (As ) 1.9 0 (0.40

) 11.61 0.1 0 1.9 0 0.0

0 0.00 ; l.o o ~ 0.00 1.9 0 Bariu m (Ba

) 51.00 67.00 11.61 * 2.55 ; 39.39 0.0 0 0.00 • : 1.0 0 0.00 39.3 9 Berylliu m (Be) (0.10 ) (0.10

) 11.61 

# - j (0.10 ) 0.00 0.00 j 1.0 0 

# - 0.00 (0.10 ) Cadmiu m (Cd ) 0.58 (0.10 ) 11.61 0.0 3 0.58 0.00 0.00 ! 1.0 0 — 0.00 0.58 Chromiu m (Cr

) 23.00 25.00 11.61 * 1.1 5 ! 11.3 9 0.00 0.00 I 1.0 0 

# - 0.00 11.39 Lea d (Pb ) 15.0

0 0.5

5 * 11.61 0.7 5 14.4

5 0.00 0.00 i l.o o 

# - 0.00 14.4 5 Nicke l (Ni ) 43.00 62.00 11.61 * 2.1 5 31.39 0.00 0.0 0 i l.o o 0.00 31.3 9 Seleniu m (Se

) (1.00

) (1.00

) 11.61 

# - (1.00 ) 0.00 0.00 ; 1.0 0 

# - 0.00 (1.00 ) Silve r(Ag ) 29.00 200.00 11.61 * 1.4 5 17.3

9 0.0

0 0.00 i 1.0 0 

# - 0.00 17.39 Thalliu m (Tl ) (0.50 ) (0.50

) 11.61 — i (0.50 ) 0.0

0 0.00 . • 1.0 0 

# - 0.00 (0.50 )
I fFH B i s between 0 t

o 11.61 n

gus eblan k valu e t o correc t I fFH B > 11.61 n

gthen us

e the greatero f11.61 n go rthe lesse rvalu e between FH B o r5 % o fFH S . I fBH B i s > 6 but <= 1 n gthe n us

e the BH B valu e t

o correc t I fBH B i s >

} n gus e the greatero feithe r1 n go r5 % o fB H

*- valu e use

d fo rblan k

correctio n (a ) - base d o n a 3.2

5 - in . filtersiz

e () Not Detected / Reportabl e Detectio n Limi t

MERCURY : Mercury Fractio n Sampl e u g Fi d Bl k

jj j u g Ii i Defaul t

Valu e Hg 5

% o fj Sampl e Hg ! Corrected

Amoun t H g Hg FRON THAL F 1.1 0 0.0 5 * |i | 6.0

0 0.0

6 1.0

5 BAC KHAL F 472.23 0.0 5 * || | 6.0

0 23.6 1 472.1 8 

# mmmrnmmmmmmmmmmmmimm TOTA L H g 473.23 CLIENT : PROG : 

# T i RUN'NO . 

### Onyx, Sauget , I L No v200 2 

### Unit4 Run2

I fF B i s >

0 but <= 6 n gthe n us ethe F B valu e t

o correc t I fF B i s >

6 n gus ethe greatero feithe r6 n go r5 % o fF H () Not Detected / Reportabl e Detectio n Limi t *Indicate

s valu e use

d fo rblan k

correctio n J:\AiT_Tu\Pmje a Fikrtftiyilttny x100 2 workWovsmbc r2002\FieW\Uni l WMETCORK-NmTO.l .

# !

Multi-Metal

s Blan kCorrectio

n
FRON THAL F BAC KHAL F TOTA L Corrected . F H + B H
U S Elemen t J ! Sample

H g Fi d Bl k

jj j H g 

### li ; Default

Valu e (a

) ug 5

% o f Sampl e H S Correcte

d Fron t Hal f U g Sample

H S Fi d Bl k

H S ; Default

I Valu e H g 5

% o f Sample H g 

### i Correcte d Back Hal f H g TOTA L

Corrected . F H + B H
U S AntimonyKb ) 0 .5 2 0

. 6 

## U 11

.6 1 0

.0 3 (0

.52 ) 0.0

0 30.0

0 

### i 1 .0

0 0.0 0 (0

.52 ) Arseni c (tk) 1.9 0 (0

.40 ) tj j 11 .6 1 0

.1 0 1

.9 0 0.0

0 0.0

0 

### i 1.0

0 

# - 0.0 0 1.9

0 Bariu m (A ) 52 .0 0 67

.0 0 Ii i 11

.6 1 • 2

.6 0 40.3

9 0.0

0 0.0

0 

### i 1 .0

0 

# - 0.0 0 40.3

9 Berylliu m fee) (0 .10 ) (0

.10 ) i ; 11

.6 1 

# - (0 .10 ) 0.0

0 0.0

0 

### i 1.0

0 

# - 0.0 0 (0

.10 ) Cadmiu m (Ed ) 0 .4 5 (0.10

) 11.6

1 0

.0 2 0

.4 5 0.0

0 0.0

0 

### i 1.0

0 

# - 0.0 0 0

.4 5 ChromiumlCr

) 27.0

0 25

.0 0 11.6

1 » 1

.3 5 15.3

9 0.0

0 0.0

0 

### i l.o o 

# - 0.0 0 15.3

9 Lea d (P * 9.8

0 0

.5 5 * !:! ; 11

.6 1 0

.4 9 9.2

5 0.0

0 0.0

0 

### i 1.0

0 

# - 0.0 0 9.2

5 Nicke l (I§ ) 42 .0 0 62

.0 0 ti i 11

.6 1 * 2

.1 0 30.3

9 0.0

0 0.0

0 

### i 1.0

0 

### i 0.0 0 30.3

9 Seleniu m fie) (1 .00 ) (1 .00

) i i 11

.6 1 — (1.00 ) 0.0

0 0.0

0 

### i 1.0

0 — 0.0 0 (1 .00

) Silve r(Al ) 12 .0 0 200.0

0 ti i 11

.6 1 * 0

.6 0 0

.3 9 0.0

0 0.0

0 

### i 1.0

0 

# - 0.0 0 0

.3 9 Thalliu m Sti ) (0 .50 ) (0

.50 ) i i 11

.6 1 

# - (0 .50 ) 0.0

0 0.0

0 | 1.0

0 

# - 0.0 0 (0

.50 ) J K I fFH B i s betwej n 0 t

o 11.6 1 n g us e blan k value t o correc t t fFH B > 11.6

1 | gthe n us e th e greate ro f11.6 1 n g orth

e lesservalue betwee

n FH B or5

% ofFH S . I fBH B is > 0 bu t <= 1 n g *e n us

e th e BH B value t

o correc t I fBH B is >

1 n g us e th e greate ro feither1 n g or5

% ofB H

•value use

d fofblan k

correction (a ) - base d on a 3.2

5 - in . filtersiz

e ( ) No t Detecte d / Reportable Detectio n Limi t

IfFBis> 0 but< | MERCURY : Mercur y1 Fraction | Sample Hg Fi d Bl k

H g Default

Valu e Hg 5

% of Sampl e H g Correcte

d Amoun t H g Hg 

### CLIEN T : Onyx , Sauget , IL FRON THAL ] 42.0 0 0.0

5 * 6.0

0 2.1 0 41.9 5 

### PROGRAM : No v200 2 BAC KHALrj 822.1 0 0.0 5 * 6.0

0 41.1 1 822.0 5 

### RU

NNO . Uni

t4 Ru n3

TOTA L H g 864.0 0 6 n g the n us e th e F B value t

o correc t ( ) No t Detecte d / Reportable Detection Limi t JftAir_To<yST>j^Fil^i^^y»3miwfk\NDTOifcr31ffl3^»WUnil<\)METCOBR.Nin'n2.U 4 Rl,3^.ililRon 3

I <

### Ony xEnvironmenta l Service s - Novembe r200 2 Particulat e Filte ran d Aceton e Rins e Result s ACETON E FRON T HAL F RINSE RESULT S Sampl e ID #
La b Aceton e Blan k Sampl e

Volum e (mL ) 5 0 Tar e

Weigh t (9 ) 104.041 9 Gros s

Sampl e Weigh t (g ) 104.041 6 Ne t

Sampl e Weigh t (g ) -0.000 3 Blank-Correcte d

Ne tSampl e Weigh t Sampl e ID #
La b Aceton e Blan k Sampl e

Volum e (mL ) 5 0 Tar e

Weigh t (9 ) 104.041 9 Gros s

Sampl e Weigh t (g ) 104.041 6 Ne t

Sampl e Weigh t (g ) -0.000 3 (g ) (mg ) M50-FHR-R B U2-M26A-FHR-R 1 18 0 5 9 102.189 8 102.354 9 102.188 3

102.357 5 -0.001 5

0.002 6 0.002 6 2. 6 U2-M26A-FHR-R 2 5 3 105.335 8 105.346 6 0.010 8 0.010 8 10. 8 U3-M26A-FHR-R 1 6 2 103.721 3 103.724 3 0.003 0 0.003 0 3. 0 U3-M26A-FHR-R 2 7 3 116.434 3 116.438 1 0.003 8 0.003 8 3. 8 0.000 0 0.000 0 0. 0 0.000 0 0.000 0 0. 0

g/m L 

### mg/ g g/mL P M cone , i n aceton e (L B # 1 ) = 0.00 0 0.00E+0 0 P M cone , i n aceton e (FB # 1 ) = 0.00 0 0.00E+0 0 Max
. Aceton e Blan k

Correctio n = 0.01 0 7.9 1 E-0 6 

### PARTICULAT E FILTE RRESULTS
Ru n # Tar e

Weigh t (g ) Gros s

Sampl e Weigh t (g ) Ne tSampl e Weigh t NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. Ru n # Tar e

Weigh t (g ) Gros s

Sampl e Weigh t (g ) (g ) (mg ) NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. La b Filte rBlan k 0.390 1 0.390 2 0.000 1 0. 1 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. M26A-PF-F B 0.392 9 0.393 1 0.000 2 0. 2 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U2-M26A-FHR-R 1 0.380 2 0.381 7 0.001 5 1. 5 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U2-M26A-FHR-R 2 0.402 4 0.404 4 0.002 0 2. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U3-M26A-FHR-R 1 0.387 8 0.387 9 0.000 1 0. 1 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U3-M26A-FHR-R 2 0.380 7 0.381 2 0.000 5 0. 5 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. 0.000 0 0. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. 0.000 0 0. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n ±5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
.

j:\air_tox\projec

t files\onyx\ony

x200 2 work\novembe r2002\field\[m5corr 6 - u2&3.xls] a

### Ony x

### Environmenta l Service s - Novembe r200 2 

### Particulat e Filte ran d Aceton e Rins e Result s
Sampl e ID #

t a hA f»rtn o Dlant f Sampl e

Volum e (mL ) *i 0 Tar e

Weigh t (g ) 10 4 041 9 Gros s

Sampl e Weigh t (g ) 10 4 041 6 Ne t

Sampl e Weigh t (g )

- 0 000 3 Blank-Correcte d

Ne tSampl e Weigh t Sampl e ID #

t a hA f»rtn o Dlant f Sampl e

Volum e (mL ) *i 0 Tar e

Weigh t (g ) 10 4 041 9 Gros s

Sampl e Weigh t (g ) 10 4 041 6 Ne t

Sampl e Weigh t (g )

- 0 000 3 (g ) (mg )
L d UnOClUU c DldllK
. M50-FHR-R B 18 0 102.189 8 1 \J—f*\J*T 1 \J 102.188 3 -0.001 5 U4-M26A-FHR-R 1 8 4 103.412 0 103.416 1 0.004 1 0.004 1 4. 1 U4-M26A-FHR-R 2 7 8 103.281 5 103.285 4 0.003 9 0.003 9 3. 9 U4-M26A-FHR-R 3 7 3 103.177 2 103.183 7 0.006 5 0.006 5 6. 5 0.000 0 0.000 0 0. 0 0.000 0 0.000 0 0. 0 0.000 0 0.0000**"* " 0.0"""~'~
— " utMis>ii yu i Muetunt : - u./au o g/m L 

### mg/ g g/m L P M cone , i n aceton e (L B # 1 ) = 0.00 0 O.OOE+0 0 P M cone , i n aceton e (F B # 1 ) = 0.00 0 0.O0E+O 0 Max
. Aceton e Blan k

Correctio n = 0.01 0 7.9 1 E-0 6 

### PARTICULAT E FILTE RRESULTS
Ru n # Tar e

Weigh t (g ) Gros s

Sampl e Weigh t (g ) Ne tSampl e Weigh t NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. Ru n # Tar e

Weigh t (g ) Gros s

Sampl e Weigh t (g ) (9)
. (mg ) NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. La b Filte rBlan k 0.390 1 0.390 2 0.000 1 0. 1 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. M26A-PF-F B 0.392 9 0.393 1 0.000 2 0. 2 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U4-M26A-FHR-R 1 0.406 5 0.407 6 0.001 1 1. 1 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U4-M26A-FHR-R 2 0.402 9 0.403 8 0.000 9 0. 9 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. U4-M26A-FHR-R 3 0.383 9 0.384 9 0.001 0 1. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. 0.000 0 0. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. 0.000 0 0. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
. 0.000 0 0. 0 NOTE : N o blan k

filte rcorrectio n i s necessar yi fblan k filte ri s withi n + 5 m g o finitia l tar e weigh t o r2 % o fsampl e weight , whicheve ri s greater
.

j:\air_tox\projec

t files\onyx\ony

x200 2 work\november2002\field\[m5corr 6 - u4.xls]a' )

) iINTERNATtONAL

APPENDI XB PROCES S FEE D AN D OPERATIN G CONDITION S

### UNI T2/ 3 TES TCONDITION S Wee k o fNovembe r18 , 200 2 

## Chlorin e - Ibs/h r 20 0 - 25 0 Dru m Solid s - Ibs/h r Hig h Bt u liquid s - Ibs/h r Lo wBt u liquid s - Ibs/h r Lea d i n dru m solid s - Ibs/h r Chromiu m i n lo wBt u liquid s - Ibs/h r Mercuryi n dru m solid s - Ibs/h r SD AOutle tTemperatur e - 0

## F Uni t2 Ru n 1 Uni t2 Ru n 2 Uni t3 Ru n 1 Uni t3 Ru n 2 Lowe rChambe rTemperatur e - 0

## F Uppe rChambe rTemperatur e - 0

## F 75 0 (25lbs/charqe ) 70 0 100 0 3 0 1 5 n o mercury 39 0 42 5 39 0 42 5 175 0 190 0 Tw o Conditions , On e Run s pe rConditio n pe rIncinerato r

### UNI T4 TES TCONDITION S Wee k o fNovembe r18 , 200 2 

## Chlorin e - Ibs/h r Dru m Solid s - Ibs/h r Bul k Solid s - Ibs/h r Hig h Bt u Liquid s i n SC C - Ibs/h r Hig h BT U Liquid s i n Kil n - Ibs/h r Lo wBt u liquid s - Ibs/h r Lea d i n dru m solid s - Ibs/h r Chromiu m i n lo wBt u liquid s - Ibs/h r Mercuryi n Dru m Solid s - Ibs/h r Powdere d Activate d Carbo n Ru n 1 - Ibs/h r Ru n 2 - Ibs/h r Ru n 3 - Ibs/h r SD AInle tTemperatur e - 0

## F SD AOutle tTemperatur e - ° F Kil n Temperatur e - 0

## F S C C Temperatur e - ° F 25 0 (al l i n liquids ) 150 0 (2 5 lbs/charge ) 500 0 80 0 40 0 75 0 3 0 15 0. 1 (Run s 2 an d 3 only ) 6 ( n o mercuryspiking ) 15 1 0 75 0 42 5 185 0 195 0APPENDI XC FIEL D EQUIPMEN TCALIBRATIO N FORM SAPPENDI XD ANALYTICA L DAT AREPORT S

# ALT A

Decembe r11,200 2 

## Alt aProjec tI.D. : 2314

1 Mr . CraigDoolittl

e ENS RConsultin

gan dEngineerin

g 2 Technolog

yPar kDrive Westford, M A 0188

6 Dea rMr . Doolittle, Enclose d ar eth eresult s forth eeigh tXA D sample

s receive d a tAltaAnalytica

l Laborator

yo n Novembe r25, 2002

. Thes esample s wer eextracte

d an danalyze

d usin gEP A Metho

d 2 3 for tetra-through-oct

achlorinate

d dioxin s an d furans. A standar

d turnaroun

d tim ewa s provide d forthi s work . Th efollowingrepor

tconsist s of aSampl eInventor

y(Sectio nI) , Analytica

l Result s (Sectio nII ) an d th eAppendix, whic

h contain

s th echain-of-custody, alisto f dat aqualifier

s an d abbreviations

, Alta' s curren tcertifications, an

d copie s of th era wdat a(if requested). AltaAnalytica

l Laborator

yi s cornmitte

d t o servin gyo ueffectively. If

yo urequir eadditiona

l information

, pleas econtac tm ea t916-933-164

0 o rb yemai l a tmmaier@altalab.com

. Than kyo ufo r choosin gAltaa s par to f you ranalytica

l suppor tteam . Sincerely,

Marth aM . Maier Directo rof HRM S Service

s

Alta Analytical

laboraion- certifies that the report

herein meets all

the requirements setforth hy NELAC for those applicable test

methods.This report

should not be reproduced

except in full without the written approval

of ALTA.

Projec t 2314 1 

## AltaAnalytica l LaboratoryInc . 110 4 Windfiel d Way E lDorad o Hills , C A 9576 2 FA X(916 ) 673-010 6 Pag e 1 o f62 0