# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions** Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information** Parent Company

Name: Address: City: Country: USA Size of Company

(approximate number of employees including all subsidiaries, branches, and related establishments owned):
**PVC Production Facility General Information** Facility Name: Facility Address: Facility City: Facility Technical Contact Name: Technical Contact Telephone Number: Technical Contact Email: Number of employees attached to the PVC production facility: 80 Avon Lake 33857 Walker Rd PolyOne Corp

856-299-8413 otis.sistrunk@polyone.com Pedricktown Rt 130 & Porcupine Rd Pedricktown Otis Sistrunk

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: OH Zip Code: 44012

Size of Company

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 7000

State: NJ Zip Code: 8067

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER** Process Unit ID: P-1 Process Equipment ID: U-17 Wastewater Feed Rate (lb/hr): 37,350 Feed Temperature (°F): 100 Feed Inlet Pressure (psia): 64.5 Liquid Loading Rate (liters/m2): SteamFeed Rate (lb/hr): Steamto Feed Ratio (kg steam/liter of wastewater): Operating Temperature (°F): 185 Operating Pressure (psig): Total Number of Stages: 2 Overall Calculated Tray Efficiency: Stripping Factor: Flow configuration (countercurrent, cocurrent): Countercurrent Number of Actual Trays: 0 Column Height (meters): 8.08 Year Equipment Installed: 1978 Equipment Currently

Regulated Under (cite regulations): 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions** Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:
If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 17744liters/hour liters If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

U20 8 U31 25

Permeate (North) Permeate (South) **2**

**PVC Process Unit ID**  **Name of PVC Process Wastewater Stream PVC Process**  **Wastewater Stream ID** 

# Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System **1 2**  **3 4**  **5 6** 

**Min** U17 SteamStripping Continuous44 30000

**Table 3. PVC Process Wastewater Destination Codes Table**
Wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW, no treatment Discharge to PrOTW, no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3**

**Min Ma** **x**

**PVC Process Wastewater Stream Flow Rate**

**1 Process Wastewater Stream Flow Rate**  **(gallons per day) Source of Process Wastewater Stream**  **Destination Description PVC Process**  **Wastewater Treatment**  **System ID PVC Process**  **Unit ID PVC Process**  **Wastewater Stream ID**  **Is this process**  **wastewater treatment**  **system batch or continuous**  **operation? Ty** **pe of Process Wastewater**  **Treatment System**

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage**

0 43000 15000Measured 12 0 43000 15000Measured 12 **Flow Rate Determination**  **Me thod**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) Operating Days Per**  **Year**

# 7 **8 9**  **10 11** 

**Ma x**  **Av erage**  90000 45200Measured 360WWT

**Code** WWT Provide name of the wastewater treatment system SW Provide name of outfall POTWRAWProvide name of POTW PrOTWRAWProvide name of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 4**  **5 6**  **7**

**Av erage**  **Flow Rate**

**Determination Me** **thod PVC Process**  **Wastewater Treatment**  **System ID PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Flow Rate**  **Determination Me** **thod**

**Operating Days Per Year**  **Process Wastewater Stream Flow Rate**

**(gallons per day) Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**  **PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below) **Operating Days Per Year** 

# 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

Fil 1N/Fil 2N UF System (North) Fil 3N/Fil 4N UF System (South) **Originating PVC Process Equipment ID**  **Originating PVC Process Equipment Description** 

# 12 **13**

Yes

Provide name of the wastewater treatment system

Describe where in the process the stream is recycled

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**As sociated Destination**  **Information** (Refer to Table 3 below) **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?** 

# 11 **12**

WWT WWT **PVC Process Wastewater Stream Destination Code**  (Refer to Table 3 below) **As sociated Destination Information** 

# Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 **14**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

# 13

Yes Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination?**

# If your response in Column 3 is "Other" then please provide a description of the process wastewaetr

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater **PVC Production Process Wastewater Sampling and Analysis Data**

**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company**PolyOne Corp **Facility**Pedricktown **PVC Process Wastewater Treatment System ID** P-1

**CAS No. HAP**  **Analysis Method Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  107211Ethylene glycol SW-846-8015C 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect 67561Methanol SW-846-8015C 75.2 55 37.4 46.4 39.5 20.4 29.1 75070Acetaldehyde SW-846-8315A 4.53 8.77 7.1 6.04 6.3 6.23 8.64 50000Formaldehyde SW-846-8315A 0.0755 0.241 0.0619 0.361 0.0669 0.158 0.217 512852,4-dinitrophenol SW-846-8270D 0.17Non-detect U 17 Non-detect U 0.17Non-detect U 0.17Non-detect U 1.7 Non-detect U 1.7 Non-detect U 1.7 Non-detect 98862Acetophenone SW-846-8270D 2.69 3.52 0.966 1.39 1.57 1.24 0.683 117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.0059Non-detect U 0.59Non-detect U 0.0059Non-detect U 0.0059Non-detect U 0.059 Non-detect U 0.059 Non-detect U 0.059 Non-detect 123319Hydroquinone SW-846-8270D 0.05Non-detect U 5Non-detect U 0.05Non-detect U 0.05Non-detect U 0.5Non-detect U 0.5Non-detect U 0.5Non-detect 108952Phenol SW-846-8270D 0.013 Non-detect U 1.3 Non-detect U 0.013 Non-detect U 0.013 Non-detect U 0.13Non-detect U 0.13Non-detect U 0.13Non-detect 793451,1,2,2-tetrachloroethane SW-846-8260B 0.0011 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.0021 Non-detect U 0.0011 Non-detect U 0.0043 Non-detect U 0.0011 Non-detect 1069901,3-butadiene SW-846-8260B 0.0095Non-detect U 0.0095Non-detect U 0.095Non-detect U 0.019 Non-detect U 0.0095Non-detect U 0.038 Non-detect U 0.0095Non-detect 5408412,2,4-trimethylpentane SW-846-8260B 0.0011 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0045Non-detect U 0.0011 Non-detect 71432Benzene SW-846-8260B 0.0012 Non-detect U 0.0012 Non-detect U 0.012 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0047 Non-detect U 0.0012 Non-detect 108907Chlorobenzene SW-846-8260B 0.0011 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0046 Non-detect U 0.0011 Non-detect 67663Chloroform SW-846-8260B 0.001 Non-detect U 0.001 Non-detect U 0.01 Non-detect U 0.002 Non-detect U 0.001 Non-detect U 0.0041 Non-detect U 0.001 Non-detect 126998Chloroprene SW-846-8260B 0.001 Non-detect U 0.001 Non-detect U 0.01 Non-detect U 0.0021 Non-detect U 0.001 Non-detect U 0.0042 Non-detect U 0.001 Non-detect 98828Cumene SW-846-8260B 0.0022 Non-detect U 0.0022 Non-detect U 0.022 Non-detect U 0.0045Non-detect U 0.0022 Non-detect U 0.0089Non-detect U 0.0022 Non-detect 75003Ethyl chloride (Chloroethane) SW-846-8260B 0.4 0.252 1.39 0.208 0.148 0.361 0.159 100414Ethylbenzene SW-846-8260B 0.0011 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0046 Non-detect U 0.0011 Non-detect 107062Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.0158 0.0139 0.0499 J 0.0087 J 0.0102 0.0302 0.0086 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.00053 Non-detect U 0.00053 Non-detect U 0.0053 Non-detect U 0.0011 Non-detect U 0.00053 Non-detect U 0.0021 Non-detect U 0.00053 Non-detect 74873Methyl chloride (Chloromethane) SW-846-8260B 0.869 0.777 4.92 0.694 0.433 1.11 0.579 75092Methylene chloride SW-846-8260B 0.0035Non-detect U 0.0035Non-detect U 0.035Non-detect U 0.007 Non-detect U 0.0035Non-detect U 0.014 Non-detect U 0.0035Non-detect 110543n-Hexane SW-846-8260B 0.0023 Non-detect U 0.0023 Non-detect U 0.023 Non-detect U 0.0046 Non-detect U 0.0023 Non-detect U 0.0093 Non-detect U 0.0023 Non-detect 108883Toluene SW-846-8260B 0.0011 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0045Non-detect U 0.0011 Non-detect 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.0012 Non-detect U 0.0012 Non-detect U 0.012 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0047 Non-detect U 0.0012 Non-detect 790051,1,2-Trichloroethane SW-846-8260B 0.0014 Non-detect U 0.0014 Non-detect U 0.014 Non-detect U 0.0029Non-detect U 0.0014 Non-detect U 0.0057 Non-detect U 0.0014 Non-detect 108054Vinyl acetate SW-846-8260B 0.0056 Non-detect U 0.0056 Non-detect U 0.056 Non-detect U 0.011 Non-detect U 0.0056 Non-detect U 0.022 Non-detect U 0.0056 Non-detect 593602Vinyl bromide SW-846-8260B 0.0013 Non-detect U 0.0013 Non-detect U 0.013 Non-detect U 0.0027 Non-detect U 0.0013 Non-detect U 0.0054 Non-detect U 0.0013 Non-detect 75014Vinyl chloride EPA Method 107 3.818 4.082 9.281 4.477 0.019 5.766 2.405 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.00096 Non-detect U 0.00096 Non-detect U 0.0096 Non-detect U 0.0019Non-detect U 0.00096 Non-detect U 0.0038Non-detect U 0.00096 Non-detect 1330207Xylenes (isomers and mixtures) SW-846-8260B 0.0012 Non-detect U 0.0012 Non-detect U 0.012 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0048Non-detect U 0.0012 Non-detect JB25234 JB25235 JB25236 JB25238 JB25239 See Lab Report 22 20 21 01/08/13 01/09/13 **6** 01/10/13 01/14/13

Measured **2** 01/15/13

Measured Measured Measured Measured Measured **1**

185 25 01/07/13 **3 4** 

185 185 185
**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->** 

JB25234-1 JB25235-1 JB25236-1 JB25238-1 JB25239-1 JB25233-1 JB25233 See Lab Report 185 See Lab Report JB25237 JB25237-1 See Lab Report See Lab Report **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

185 See Lab Report 20
See Lab Report **Flow Rate Determination Method -->** 21 Measured **Sample Date -->** Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion **5** 01/11/13 Suspension/Dispersion**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect 24.9 22.8 27.5 56.6 3.49 18.2 25 17.5 22.8 30.5 46.9 26.4 16.1 19.6 14.4 8.29 8.5 7.03 6.14 7.93 7.45 6.22 6.77 2.98 7.93 7.33 6.22 7.22 4.49 5.19 0.556 0.31 0.254 0.214 0.455 0.228 0.321 0.432 0.106 0.171 0.212 0.217 0.193 0.14 0.122 U 1.7 Non-detect U 1.7 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.17Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.083 Non-detect U 0.017 Non-detect U 0.17Non-detect U 0.17Non-detect U 0.083 Non-detect U 0.017 Non-detect 0.291 0.18 J 0.0652 0.54 0.687 0.899 2.38 0.731 0.479 0.305 0 0.395 0.795 0.808 0.376 0.584 U 0.059 Non-detect U 0.059 Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.0059Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.0029Non-detect U 0.00059Non-detect U 0.0059Non-detect U 0.0059Non-detect U 0.0029Non-detect U 0.00059Non-detect U 0.5Non-detect U 0.5Non-detect U 0.005Non-detect U 0.005Non-detect U 0.005Non-detect U 0.005Non-detect U 0.05Non-detect U 0.005Non-detect U 0.005Non-detect U 0.0025Non-detect U 0.005Non-detect U 0.05Non-detect U 0.05Non-detect U 0.025Non-detect U 0.005Non-detect U 0.13Non-detect U 0.13Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0022 0.0013 Non-detect U 0.013 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0064 Non-detect U 0.0013 Non-detect U 0.013 Non-detect U 0.013 Non-detect U 0.0064 Non-detect U 0.0013 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0054 Non-detect U 0.0021 Non-detect U 0.0011 Non-detect U 0.0021 Non-detect U 0.011 Non-detect U 0.00021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0095Non-detect U 0.0095Non-detect U 0.0095Non-detect U 0.0095Non-detect U 0.0095Non-detect U 0.048 Non-detect U 0.019 Non-detect U 0.0095Non-detect U 0.019 Non-detect U 0.095Non-detect U 0.0019Non-detect U 0.019 Non-detect U 0.019 Non-detect U 0.0095Non-detect U 0.0095Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0056 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0023 Non-detect U 0.011 Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0059Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0024 Non-detect U 0.012 Non-detect U 0.00024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0057 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0023 Non-detect U 0.011 Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.0051 Non-detect U 0.002 Non-detect U 0.001 Non-detect U 0.002 Non-detect U 0.01 Non-detect U 0.0002 Non-detect U 0.002 Non-detect U 0.002 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.0052 Non-detect U 0.0021 Non-detect U 0.001 Non-detect U 0.0021 Non-detect U 0.01 Non-detect U 0.00021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U 0.001 Non-detect U 0.001 Non-detect U 0.0022 Non-detect U 0.0022 Non-detect U 0.0022 Non-detect U 0.0022 Non-detect U 0.0022 Non-detect U 0.011 Non-detect U 0.0045Non-detect U 0.0022 Non-detect U 0.0045Non-detect U 0.022 Non-detect U 0.00045Non-detect U 0.0045Non-detect U 0.0045Non-detect U 0.0022 Non-detect U 0.0022 Non-detect 0.186 0.235 0.0769 0.23 0.288 0.477 0.168 0.215 0.234 0.426 0.103 0.235 0.21 0.163 0.126 U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0057 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0023 Non-detect U 0.011 Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect 0.0107 0.0129 0.0058 0.0119 0.0139 0.0268 0.0088 J 0.012 0.0136 0.0167 J 0.0151 0.0149 0.0148 0.0075 0.0129 U 0.00053 Non-detect U 0.00053 Non-detect U 0.00053 Non-detect U 0.00053 Non-detect U 0.00053 Non-detect U 0.0027 Non-detect U 0.0011 Non-detect U 0.00053 Non-detect U 0.0011 Non-detect U 0.0053 Non-detect U 0.00011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.00053 Non-detect U 0.00053 Non-detect 0.605 0.727 0.268 0.712 0.928 1.62 0.652 0.712 0.863 1.4 0.296 0.922 0.825 0.535 0.425 U 0.0035Non-detect U 0.0035Non-detect U 0.0035Non-detect U 0.0035Non-detect U 0.0035Non-detect U 0.018 Non-detect U 0.007 Non-detect U 0.0035Non-detect U 0.007 Non-detect U 0.035Non-detect U 0.0007 Non-detect U 0.007 Non-detect U 0.007 Non-detect U 0.0035Non-detect U 0.0035Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.012 Non-detect U 0.0046 Non-detect U 0.0023 Non-detect U 0.0046 Non-detect U 0.023 Non-detect U 0.00046 Non-detect U 0.0046 Non-detect U 0.0046 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0057 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0023 Non-detect U 0.011 Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0059Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0024 Non-detect U 0.012 Non-detect U 0.00024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0014 Non-detect U 0.0014 Non-detect U 0.0014 Non-detect U 0.0014 Non-detect U 0.0014 Non-detect U 0.0072 Non-detect U 0.0029Non-detect U 0.0014 Non-detect U 0.0029Non-detect U 0.014 Non-detect U 0.00029Non-detect U 0.0029Non-detect U 0.0029Non-detect U 0.0014 Non-detect U 0.0014 Non-detect U 0.0056 Non-detect U 0.0056 Non-detect U 0.0056 Non-detect U 0.0056 Non-detect U 0.0056 Non-detect U 0.028 Non-detect U 0.011 Non-detect U 0.0056 Non-detect U 0.011 Non-detect U 0.056 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.011 Non-detect U 0.0056 Non-detect U 0.0056 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0067 Non-detect U 0.0027 Non-detect U 0.0013 Non-detect U 0.0027 Non-detect U 0.013 Non-detect U 0.00027 Non-detect U 0.0027 Non-detect U 0.0027 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect 3.758 3.009 2.224 1.837 6.352 3.206 3.436 5.026 1.917 9.631 3.943 4.58 4.23 2.86 2.78 U 0.00096 Non-detect U 0.00096 Non-detect U 0.00096 Non-detect U 0.00096 Non-detect U 0.00096 Non-detect U 0.0048Non-detect U 0.0019Non-detect U 0.00096 Non-detect U 0.0019Non-detect U 0.0096 Non-detect U 0.00019Non-detect U 0.0019Non-detect U 0.0019Non-detect U 0.00096 Non-detect U 0.00096 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect U 0.006 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0024 Non-detect U 0.012 Non-detect U 0.00024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0012 Non-detect U 0.0012 Non-detect Measured 185 185 185 185 185 25 Measured Measured Measured Measured Measured Measured

JB25243-1 JB25244-1 JB25245-1 JB25247-1 JB25251 185 02/11/13

185
JB25252 JB25248-1 JB25249-1 JB25250-1 JB25251-1 JB25252-1 See Lab Report See Lab Report JB25248 JB25249 JB25250 See Lab Report See Lab Report
JB25253-1 JB25254-1 JB25255-1 JB25253 JB25254 02/14/13 02/13/13 **22 23** 

Measured See Lab Report See Lab Report See Lab Report JB25255 24 20

JB25243 JB25244 JB25239 JB25240 JB25241 JB25242 **19 9**  **10** 02/04/13 **12**

20 22 22 Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion 22 Suspension/Dispersion **13 14**  **15**

22 20 20 23 **16**

See Lab Report See Lab Report See Lab Report See Lab Report See Lab Report See Lab Report See Lab Report See Lab Report See Lab Report 185 185 185 185 01/15/13

Measured Measured 185 Measured Measured Measured Measured 01/23/13

185 185 185 **7 8** 

JB25239-1 JB25245 JB25247 JB25240-1 JB25241-1 JB25242-1 Suspension/Dispersion Suspension/Dispersion
Measured Measured 20 21 2 21 Suspension/Dispersion Suspension/Dispersion 01/16/13 Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion 01/17/13 01/20/13 01/22/13 **20** 02/08/13 02/12/13 **17 18**  02/05/13 02/06/13 02/07/13**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 10 Non-detect U 17 31.8 13.4 7.78 7.33 44 50.9 50.9 5.13 2.28 4.6 7.72 4.56 3.9 2.88 2.88 0.0386 0.102 J 0.0875 0.447 0.128 0.112 0.2 0.2 U 0.017 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.083 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 0.017 Non-detect U 2.45 1.11 1.02 3.2 1.19 0.497 1.18 1.18 U 0.00059Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.0029Non-detect U 0.00059Non-detect U 0.00059Non-detect U 0.00059Non-detect U U 0.005Non-detect U 0.005Non-detect U 0.005Non-detect U 0.005Non-detect U 0.025Non-detect U 0.005Non-detect U 0.005Non-detect U 0.005Non-detect U U 0.0013 Non-detect U 0.0013 Non-detect U 0.0013 Non-detect U 0.0027 Non-detect 0.0064 Non-detect U 0.0022 0.0032 0.0032 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0043 Non-detect U 0.00021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U U 0.0095Non-detect U 0.0095Non-detect U 0.038 Non-detect U 0.0019Non-detect U 0.019 Non-detect U 0.019 Non-detect U 0.019 Non-detect U 0.019 Non-detect U U 0.0011 Non-detect U 0.0011 Non-detect U 0.0045Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U U 0.0012 Non-detect U 0.0012 Non-detect U 0.0047 Non-detect U 0.00024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U U 0.0011 Non-detect U 0.0011 Non-detect U 0.0046 Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U U 0.001 Non-detect U 0.001 Non-detect U 0.0041 Non-detect U 0.0002 Non-detect U 0.002 Non-detect U 0.002 Non-detect U 0.002 Non-detect U 0.002 Non-detect U U 0.001 Non-detect U 0.001 Non-detect U 0.0042 Non-detect U 0.00021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U 0.0021 Non-detect U U 0.0022 Non-detect U 0.0022 Non-detect U 0.0089Non-detect U 0.0013 Non-detect J 0.0045Non-detect U 0.0045Non-detect U 0.0045Non-detect U 0.0045Non-detect U 0.13 0.693 0.868 0.151 0.0635 0.0821 0.178 0.178 U 0.0011 Non-detect U 0.0011 Non-detect U 0.0046 Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0174 0.0393 0.0508 0.0606 0.005 J 0.0088 J 0.01 J 0.01 J U 0.00053 Non-detect U 0.00053 Non-detect U 0.0021 Non-detect U 0.0013 Non-detect 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.0011 Non-detect U 0.344 3.41 3.29 0.32 0.186 0.182 0.394 0.394 U 0.0035Non-detect U 0.0035Non-detect U 0.014 Non-detect U 0.0007 Non-detect U 0.007 Non-detect U 0.007 Non-detect U 0.007 Non-detect U 0.007 Non-detect U U 0.0023 Non-detect U 0.0023 Non-detect U 0.0093 Non-detect U 0.00046 Non-detect U 0.0046 Non-detect U 0.0046 Non-detect U 0.0046 Non-detect U 0.0046 Non-detect U U 0.0011 Non-detect U 0.0011 Non-detect U 0.0045Non-detect U 0.00023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U 0.0023 Non-detect U U 0.0012 Non-detect U 0.0012 Non-detect U 0.0047 Non-detect U 0.00024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U U 0.0014 Non-detect U 0.0014 Non-detect U 0.0057 Non-detect U 0.0018Non-detect 0.0029Non-detect U 0.0029Non-detect U 0.0029Non-detect U 0.0029Non-detect U U 0.0056 Non-detect U 0.0056 Non-detect U 0.022 Non-detect U 0.0011 Non-detect U 0.011 Non-detect U 0.011 Non-detect U 0.011 Non-detect U 0.011 Non-detect U U 0.0013 Non-detect U 0.0013 Non-detect U 0.0054 Non-detect U 0.00027 Non-detect U 0.0027 Non-detect U 0.0027 Non-detect U 0.0027 Non-detect U 0.0027 Non-detect U 2.73 8.56 8.41 5.27 1.74 1.15 2.09 2.09 U 0.00096 Non-detect U 0.00096 Non-detect U 0.0038Non-detect U 0.00019Non-detect U 0.0019Non-detect U 0.0019Non-detect U 0.0019Non-detect U 0.0019Non-detect U U 0.0012 Non-detect U 0.0012 Non-detect U 0.0048Non-detect U 0.00024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U 0.0024 Non-detect U **40 39**  **38 37**  **36 35**  **33** 03/19/13 Suspension/Dispersion

50 Measured 185 See Lab Report JB31445 JB31445-1 **32** 03/18/13 Suspension/Dispersion

21 Measured 185 See Lab Report
JB31145-1 JB29350-1 **31** 03/12/13 Suspension/Dispersion

21 Measured 185 See Lab Report JB31069 JB31069-1 **27** 03/04/13 Suspension/Dispersion

22 Measured 185 **29 30**  03/06/13 03/08/13
21 20
185 185 See Lab Report Measured See Lab Report Suspension/Dispersion Suspension/Dispersion

JB29490 25 20
185 185 Measured See Lab Report JB29350 JB29490-1 JB25262-1 JB29487-1 See Lab Report See Lab Report JB25262 JB29487 Measured Measured

JB29488-1 JB29488 **28** 02/28/13 03/05/13

JB25255-1 20 02/14/13 **24**

185 Measured **25**

See Lab Report JB25255 Suspension/Dispersion Suspension/Dispersion Suspension/Dispersion**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **55 54**  **53 52**  **51 50**  **49 48**  **47 46**  **45 44**  **43 42**  **41 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **60 59**  **58 57**  **56**