Detroit Edison Fuel Oil Analyses - 2009

P3M 09F064310 09F064330 09F066860 09F073080 09F017010

Main Tanks MonroePP MN TNK TrentonChannelPP StClairPP BelleRiverPP MN TNK HarborBeachPP/HB PK

 & Peakers 10/24/2009 10/21/2009 11/1/2009 11/30/2009 3/3/2009

Ag 0.02 0.010 0.006 0.042 0.97

Al 4.12 < 0.01 7.84 0.167 2.23

As < 0.005 < 0.005 0.01 < 0.005 0.02

Ba 3.58 3.24 2.46 2.25 0.07

Be < 0.005 < 0.005 < 0.005 < 0.005 0.01

Br

Ca 140 141 71 66 26

Cd 0.016 0.008 0.016 0.018 0.01

Cl

Co 7.89 6.98 5.74 4.21 0.01

Cr 1.55 < 0.01 1.32 4.2 0.45

Cu 1.4 0.59 0.62 0.3 <0.001

F

Fe 4.92 8.22 3.35 0.183 <0.001

Hg 0.011 0.014 0.015 0.012 0.01

K 30 33.1 31.0 21.5

Mg 24.6 19.1 11.7 10.5 8.56

Mn 0.109 0.095 0.083 0.11 0.07

Mo < 0.005 0.008 0.006 0.007 <0.001

Na 8.13 6.72 11 3.25 0.93

Ni 0.039 0.053 0.056 0.13 0.05

Pb 0.21 0.14 0.087 0.084 0.02

Sb < 0.005 < 0.005 < 0.005 < 0.005 <0.001

Se 0.037 0.071 0.21 0.14 <0.001

Tl < 0.005 < 0.005 < 0.005 0.005 <0.001

V 3.75 3.89 3.26 1.94 0.72

Zn 2.8 4.49 3.47 1.37 0.61

FILE: EPA-HQ-OAR-2009-0234-DRAFT-2741.xlsx

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Detroit Edison Fuel Oil Analyses - 2009

P3M 09F074630 09F052640 09F052640 09F033240 09F014850 09F014650 09F074630 09F056150

Heavy Oils StClairPP HO StClairPP HO StClairPP HO StClairPP HO StClairPP HO StClairPP HO StClairPP HO StClairPP TALL OIL

12/10/2009 8/31/2009 8/31/2009 5/28/2009 3/1/2009 2/25/2009 12/10/2009 9/22/2009

Ag 0.088 0.36 0.36 0.12 2.43 4.68 0.062 0.1

Al 13.2 2.08 2.08 14.3 6.67 17.7 8.6 37.6

As 0.0553 0.03 0.03 0.061 0.04 0.07 0.054 0.05

Ba 2.12 0.64 0.64 1.35 1.1 1.19 5.41 4.01

Be < 0.005 < 0.001 <0.001 <0.001 <0.001 <0.001 < 0.005 0.006

Br <20 <20 <20

Ca 431 128 128 239 64 53 1110 3310

Cd 0.028 0.05 0.05 0.033 0.03 0.04 0.021 0.036

Cl 100 230 30

Co 0.177 0.08 0.08 0.12 0.1 0.12 9.39 0.08

Cr 6.9 0.63 0.63 0.33 0.54 0.62 6.62 2.26

Cu 4.55 2.93 2.93 6.15 2.19 3.15 3.04 1.41

F <20 <20 30

Fe 136 8.15 8.15 61.8 28 36 501 246

Hg < 0.005 0.009 0.009 0.003 0.03 0.06 0.027 0.018

K 26.2 1.98 1.98 12.6 58.7 75

Mg 32.9 12 12 29.3 29.92 14.9 27.6 49

Mn 3.42 0.37 0.37 0.9 0.58 0.65 10.19 27.7

Mo 0.59 0.67 0.67 1.29 0.78 1.04 0.51 0.14

Na 73.1 59 59 42 37 13 11.7 105

Ni 15.8 0.77 0.77 1.2 1.15 1.17 4.70 18

Pb 0.93 1.65 1.65 2.35 1.29 1.46 1.53 0.87

Sb 0.1 0.03 0.03 0.09 0.05 0.09 0.073 0.02

Se < 0.005 0.06 0.06 <0.001 <0.001 <0.001 0.16 0.06

Tl 0.006 0.001 0.001 <0.001 0.01 0.01 < 0.005 0.002

V 19.5 1.2 1.2 2.18 2.29 2.29 6.81 0.41

Zn 19.4 37 37 50.08 27 37 38.9 10

FILE: EPA-HQ-OAR-2009-0234-DRAFT-2741.xlsx

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Detroit Edison Fuel Oil Analyses - 2009

Miscellaneous 09F074500 09F074510 09F074520 09F074530

Oils MonroePP TNK 06 MonroePP TNK 09 MonroePP TNK 23 MonroePP TNK 24

11/16/2009 11/16/2009 11/16/2009 11/16/2009

Ag 0.148 0.135 0.117 0.021

Al 1.91 2.43 5.48 5.67

As < 0.005 < 0.005 < 0.005 < 0.005

Ba 0.49 0.67 0.45 0.74

Be < 0.005 < 0.005 < 0.005 < 0.005

Br

Ca 118 130 127 92.1

Cd 0.012 0.01 0.008 0.022

Cl

Co 0.012 0.0121 0.014 0.012

Cr 11.3 5.68 3.49 7.54

Cu 1.45 0.78 2.64 0.74

F

Fe < 0.01 < 0.01 < 0.01 10.3

Hg < 0.005 < 0.005 < 0.005 < 0.005

K 6.32 28.4 25.9 10.8

Mg 28.5 31.2 29.6 19.1

Mn 0.20 0.19 0.19 0.23

Mo 0.005 0.010 0.008 0.014

Na 28.1 46.2 36.2 37.6

Ni 0.14 0.13 13 0.13

Pb 0.11 0.093 0.136 0.108

Sb 0.007 0.009 < 0.005 0.015

Se < 0.005 < 0.005 < 0.005 < 0.005

Tl < 0.005 < 0.005 < 0.005 < 0.005

V 0.969 3.82 0.909 1.51

Zn 1.08 1.42 2.35 2.07

FILE: EPA-HQ-OAR-2009-0234-DRAFT-2741.xlsx

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