# A copy of

the Chain of Custody can be

found in LABWARELIMS A copy of

the GPO and/or Protocol can be found in the Lotus Notes GPO Database Communications Misc - Note to File

# 3 M ENVIRONMENTA LLABORATOR Y 

# Not e t o Fil e Projec t o r Study Number : GLPlO-01-01-3 9 LIM S Number : GL

P10-01-01-3 9 Affecte dData : Non

e Al l logboo k

page s fo rth e individua l stoc k standard s an d mixe s use d fo rth e calibratio n curve s an d LC S use d fo rth e analysi s o fGLPlO-01-01-3 9 wer e printe d t o pd f(exactcopie s o foriginals ) an d include d i n a folde rlabele d 'Logboo k page s fo rGLPlO-01-01-39 ' locate d i n th e projec tfolde r locate d at : P:\Projects\Lab_ES AAnalytical\La b Request s 201 2 - stw\GLP10-01-0 1 Decatu rPhas e 3 PFOA\GLP10-01-01-3 9 FSI AQ 4 Th e chromatogram s fo rresult s fil e b l 2122 1 a wer e printe d t o pd fan d save d i n th e projec tfolde r locate d at : P:\Projects\Lab_ES AAnalytical\La b Request s 201 2 - stw\GL P 10-01-0 1 Decatu rPhas e 3 PF0A\GLP10-01-01-3 9 FSI AQ 4 Apd fcop yofth e signe d protoco l amendmen tGLP10-01-0 1 Amendmen t3 9 i s locate d i n th e projectfolde rlocate d at : P:\Projects\Lab_ES AAnalytical\La b Request s 201 2 - stw\GLP10-01-0 1 Decatu rPhas e 3 PF0A\GLP10-01-01-3 9 FSI AQ 4 Onc e th e dat a packag e ha s bee n reviewe d byQ Aan d th e reportsigned , th e pd fwil l b e move d t o th e share d driv e (\\usfile01\b2\Projects\Lab_Shared\Archiv e Requests\Electroni cReports ) an d a referenc e t o th e locatio n o fth e pd fwil l b e adde d t o th e archive d reques tfor m unde rEle cMedi a Path .



## Recorde dBy : Date :

Pag e 1 o f 1

# Collection Bottle Prep

Sample Prep Standard Prep (pdf in project

folder)

# Not e T o Fil e Projec t o r Study Description : Decatur Phase 3 - FSI Agroundwate r LIM S Number : GLPlO-01-01-3 9 Affecte dData : None O n Novembe r29 , 2012 , seventy-fiv e 25 0 m LNalgen e bottle s were marke d wit h a 20 0 m Lleve l lin e an d labeled . Th e tri p blan k

an d tri p blan k

spike s were fille d wit h Mill i Q wate r(TN12-0400 ) an d seale d afte rthe y were spiked . Th e fiel d matri

xspik e bottle s forselect samplin g location s wer e spiked wit

h the following : Fiel d Matri xSpike s

Wel l No . Spikin g Solutio n Approx .

Valu e (pg/mL ) Spik e

Amoun t (ML ) Spik e Cone . (ng/mL ) 137 8 1 2 008-2 2 10. 0 4 0 2. 0 141 R 1 2 008-2 2 10. 0 4 0 2. 0 131 S 1 2 009-20 2 10 0 4 0 2 0 143 R 1 2 009-20 2 10 0 4 0 2 0 130 S 1 2 009-20 2 10 0 20 0 10 0 136 8 1 2 009-20 2 10 0 20 0 10 0 145 R 1 2 009-20 2 10 0 20 0 10 0 1 2 008-2 2 10. 0 4 0 2. 0 Tri p Blan k

Se t 1 2 009-20 2 10 0 4 0 2 0

1 2 009-20 2 10 0 20 0 10 0 

### A1- Lcontaine ro fMill i Q Wate r(TN12-0400 ) wil l b e provide d t o b e use d fo rth e collectio n o fequipmen trinseat e blanks . Use d Eppendor

fResearc h pipett e 340227 7 t o ad d spikin g solutio n t o samples .



## Recorde dBy : Date : 

# l\|2q/| ZPrintin g 12/20/2012 ; 2:3 2 P M

GLPlO-01-01-3 9 Sampl e Pre p Wor k Sheet ; ETS-8-044. 1 date : 12/20/1 2 Analyst : CJ G Sampl e I D Sampl e Descriptio n Dllutlo n Sampl e aliquo t (ml ) Spikin g st d I D Spik e Am t (uL ) Reagen t Wate r(mL ) Fina l Vo l (mL ) LCS-121220- 1 O.Spp b LC S NA N A 12009-13 4 5 0 10, 0 10,0 5 LCS-121220- 2 O.Spp b LC S NA N A 12009-13 4 5 0 10, 0 10,0 5 LCS-121220- 3 O.Spp b LC S NA N A 12009-13 4 5 0 10, 0 10,0 5 LCS-121220- 4 5pp b LC S NA N A 12009-13 3 5 0 10, 0 10,0 5 LCS-121220- 5 5pp b LC S NA N A 12009-13 3 5 0 10, 0 , 10,0 5 LCS-121220- 6 5pp b LC S NA N A 12009-13 3 5 0 10, 0 1 0 0 5 LCS-121220- 7 • 30pp b LC S NA N A 12008-2 2 3 0 10, 0 10,0 3 LCS-121220- 8 30pp b LC S NA N A 12008-2 2 3 0 10, 0 10,0 3 LCS-121220- 9 30pp b LC S NA N A 12008-2 2 3 0 10, 0 10,0 3 GLP10-01-01-39-00 1 DAL-GW-130R-0 - 10 0 0.10 0 NA NA 9, 9 10, 0 GLPIO-OI-OI-39.OO 2 DAL-GW-130R-DB - 10 0 0.10 0 N A N A 9, 9 10, 0 GLP10-01-01-39-00 3 DAL-GW-130S-0 - 1 0 1.0 0 N A N

A 9, 0 10, 0 GLP10-01-01-39-00 4 DAL-GW-130S-DB - 1 0 1.0 0 N A N

A 9, 0 10, 0 GLP10-01-01-39-00 5 DAL-GW-130S-FMS - 1 0 1.0 0 N A N

A 9, 0 10, 0 GLP10-01-01-39-00 6 DAL-GW-130L-0 - 1 0 1.0 0 N A NA 9 0 10, 0 GLP10-01-01-39-00 7 DAL-GW-130L-DB - 1 0 1.0 0 N A N

A 9, 0 10, 0 GLP10-01-01-39-00 8 DAL-GW-131R-0 - 10 0 0.10 0 NA NA 9, 9 10, 0 GLP10-01-01-39-00 9 DAL-GW-131R-DB - 10 0 0.10 0 N A N A 9, 9 10, 0 GLP10-01-01-39-01 0 DAL-GW-131S-0 - NA N A N A N A N A N A GLP10-01-01-39-01 1 DAL-GW-131S-DB - NA N A N A N A NA N A GLP10-01-01-39-01 2 DAL-GW-131S-FMS - 10 - 1.0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-01 3 DAL-GW-131L-0 - 1 0 1 0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-01 4 DAL-GW-131L-DB - 1 0 1.00 NA NA 9, 0 10, 0 GLP10-01-01-39-01 5 DAL-GW-133R-0 - 1 0 1,00 NA NA 9. 0 10, 0 GLP10-01-01-39-01 6 DAL-GW-133R-DB - 1 0 1.00 NA N A 9, 0 10, 0 GLP l 0-01-01-39-01 7 DAL-GW-133S-0 - 1 0 1.0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-01 8 DAL-GW-133S-DB - 1 0 1.0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-01 9 DAL-GW-133L-0 - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-02 0 DAL-GW-133L-DB - 1 0 1,0 0 N A N A 9. 0 10, 0 GLP l 0-01-01-39-02 1 DAL-GW-134R-0 - 10 0 0,10 0 N A N A 9. 9 10, 0 GLP10-01-01-39-02 2 DAL-GW-134R-DB - 10 0 0,10 0 N A N A 9, 9 10, 0 GL P 10-01-01-39-02 3 DAL-GW-134S-0 - N A N A N A N A N A N A GLP10-01-01-39-02 4 DAL-GW-134S-DB - N A N A N A N A N

A N A GLP10-01-01-39-02 5 DAL-GW-134L-0 - 10 0 0,10 0 N A N A 9, 9 10, 0 GLP10-01-01-39-02 6 DAL-GW-134L-DB - 10 0 0,10 0 N A N A 9 9 10, 0 GLP10-01-01-39-02 7 DAL-GW-135R-0 - 10 0 0,10 0 N A N A 9, 9 10, 0 GLP10-01-01-39-02 8 DAL-GW-135R-DB - 10 0 0,10 0 N A N A 9, 9 10, 0 GLP10-01-01-39-02 9 DAL-GW-135S-0 - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-03 0 DAL-GW-135S-DB - 1 0 1.0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-03 1 DAL-GW-135L-0 - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-03 2 DAL-GW-135L-DB - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-03 5 DAL-GW-135S-0 - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-03 6 DAL-GW-135S-DB - 1 0 1,0 0 N A NA 9, 0 10, 0 GLP10-01-01-39-03 7 DAL-GW-136S-FMS - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-03 B DAL-GW-136L-0 - 1 0 1,0 0 N A NA 9, 0 10, 0 GL P 10-01-01-39-03 9 DAL-GW-135L-DB - 1 0 1,0 0 N A NA 9, 0 10, 0 GLP10-01-01-39-04 2 DAL-GW-137S-0 - NA N A NA NA NA N A GLP10-01-01-39-04 3 DAL-GW-137S-DB - NA N A N A NA NA N A GLP10-01-01-39-04 4 DAL-GW-137S-FMS - NA N A NA NA NA N A GLP10-01-01-39-04 5 DAL-GW-137L-0 - NA N A N A NA NA N A GLP10-01-01-39-04 6 DAL-GW-137L-DB - NA N A NA N A NA N A GLP10-01-01-39-04 9 DAL-GW-138S-0 - 1 0 1,0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-05 0 DAL-GW-138S-DB - 1 0 1,0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-05 1 DAL-GW-138L-0 - NA N A N A N A NA N A GLP10-01-01-39-05 2 DAL-GW-138L-DB - N A N A N A N A NA N A GLP10-01-01-39-05 3 DAL-GW-CW26C-0 - 10 0 0,10 0 N A N

A 9, 9 10, 0 GLP10-01-01-39-05 4 DAL-GW-CW26C-DB - 10 0 0,10 0 N A NA 9, 9 10, 0 GLP10-01-01-39-05 5 DAL-GW-CW26L-0 - 10 0 0,10 0 N A N

A 9, 9 10, 0 GLP10-01-01-39-05 6 DAL-GW-CW26L-DB - 10 0 0,10 0 N A NA 9, 9 10, 0 GLP10-01-01-39-05 7 DAL-GW-140R-0 - 1 0 1,0 0 NA NA 9, 0 10, 0 GLP10-01-01-39-05 8 DAL-GW-140R-DB - 1 0 1,0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-05 9 DAL-GW-141R-0 - NA N A NA N A NA N A GLP10-01-01-39-06 0 DAL-GW-141R-DB - NA N A NA N A NA N A GLP10-01-01-39-06 1 DAL-GW-141R-FMS - N A N A N A N A N A N A GLP10-01-01-39-06 2 DAL-GW-142R-0 - 1 0 1,0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-06 3 DAL-GW-142R-DB - 1 0 1,0 0 N A N A 9, 0 10, 0 GLP10-01-01-39-06 7 DAL-GW-145R-0 - 1 0 1,0 0 N A N A 9, 0 10, 0 GL P 10-01-01-39-06 8 DAL-GW-145R-DB - 1 0 1,0 0 NA N A 9, 0 10, 0 GLP10-01-01-39-06 9 DAL-GW-145R-FMS - 1 0 1,0 0 NA NA 9, 0 10. 0 GLP10-01-01-39-07 0 DAL-GW-131S-RB - NA N A N A N A NA N A GLP10-01-01-39-07 1 DAL-GW-145R-RB - NA N A N A NA N A N A GLP10-01-01-39-07 2 DAL-GW-TRIP01-0 - NA N A N A NA NA N A GLP10-01-01-39-07 3 DAL-GW-TRIP01-LS - NA N A N A NA N A N A GLP10-01-01-39-07 4 DAL-GW-TRIP01-MS - NA N A N A NA N A N A GLP10-01-01-39-07 5 DAL-GW-TRIP01-HS - 1 0 1,00 N A NA 9, 0 10, 0 12/20/1 2 CJG ; GLPlO-01-01-3 9 sample s dilute d wit h Mill i Q Wate rTNI2-042 1 an d vorte xmixed . I I 12/20/1 2 CJG ; Standar d curv e 1 2 011-3 0 aliquote d int o 2-m Lglas s autovial . Te n autovial s ofMill i Q Wate rTN12-042 1 wer e aliquote d t o b e use d a s solvent/metho d blanks . 

### I 12/20/1 2 CJG: LCS s prepare d usin g Mill i Q Wate rT N 12-042 1 fo rsampl e aliquot . 

### T I 12/20/1 2 CJG: Use d Eppendorfpipette s L13682 B an d L15816 B

ETS-8-044, 1 sampl e pre p 121220,xl s Pag e 1 of1

# Analytical

Case Narrative Data Reduction Calculations (excel spreadsheet

in project folder) Control Chart — Analytical Uncertainty (excel spreadsheet

in project folder)

### 3 M Confidentia l 3 M Environmenta l Laboratory Project : GLP10-01-01-3 9 Sequenc e b121221 a 3 M Environmenta l Laborator y 3 M Technica l Lead : Susa n Wol f Buildin g 260-5N-1 7 651-733-985 1 Report Author: Chelsie Grochow Analytical

Team: Chelsi e Grochow 

# Analytica l Cas e Narrativ e fo rMetho d ETS-8-44. 1

Projec t GLP10-01-01-3 9 Decatur FSIAGW-

Q4 2012 Sampling Direc tinjectio n analysi s o

fsamples Sequence : b l 2122 1 a ReportDate : Decembe r26 , 201 2 Instrumen tru n summar

ywil l b e printe d an d include d i n th e ra wdata package . Result s table , calibratio n curves , an d chromatogram s wil l b e printe d to pdf .

ET S 8-04 4 Analytica l SummaryChecklis tPag e 1 o f33 M Confidentia l



## 1 Projec t Scop e an d Dat a Qualit yObjectiv e 3 M Environmenta l Laborator y Project : GLPlO-01-01-3 9 Sequenc e b121221 a

Genera l ProjectOutlin e available . Ye s •N o I fNo , Pleas e briefl ydescrib e projectscop e an d DQ O GL P 1 3 Ye s •N o 

## 2 Sampl e Containe rPreparatio n Sampl e containe rpreparatio n documente d i n a Not e t o Fil e include d i n th e rawdat a package . 

## 3 Sampl e Analysi s 3. 1 Syste m Suitabilit y

Initia l Syste m Suitabilit yare a count s wit h RS D <5 % an d retentio n tim e wit h RS D <2 % (ETS-8-4 4 sectio n 13.1 ) Ye s •N o 

## 3.1. 1 Syste m Suitabilit yDeviation s

N A 

## 3. 2 Instrumen t Calibratio n Curv e typ e Quadratic , 1/ x r^>0.99 0 Linearit ycriteri a me t(ETS-8-4 4 sectio n 13.2 ) E l Ye s •N o < ±25 % residuals , excep tLO Q o f±30 % (ETS-8-4 4 sectio n 13.2 ) Ye s •N o Mid-leve l calibratio n point s disable d •Ye s N o Th e highes tstandar d wa s disable d fo rPFO At o mee tmetho d criteria . 

## 3. 3 Continuin g Calibratio n Verificatio n ±25 % Differenc e criteria me tfo rperiodi cCCV s (ETS-8-4 4 sectio n 13.2 ) Ye s •N o 

## 3.3. 1 Continuin g Calibratio n Verificatio n Deviation s N A 

## 3. 4 Metho d Blank s

Metho d blank s uniquel yidentifie d i n th e ru n sequence . K I Ye s •N o Averag e are a count s o ftarge tanalyte s i n th e metho d blan k presen tats 1 ^

x th e are a count s ofth e LO Q standar d (ETS-8-4 4 Sectio n 13.3 ) K I Ye s •N o 

## 3.4. 1 Metho d Blan k

Deviation s NA .

ET S 8-04 4 Analytica l Summar yChecklis t Pag e 2 o f33 M Confidentia l



## 3. 5 La b Contro l Spike s

3.5. 1 La b Contro l Spik e Deviation s NA. 

## 3. 6 Sampl e Replicate s

RP D fo rfiel d duplicate s <20 % (ETS-8-4 4 Sectio n 13.4 ) 

## 3.6. 1 Sampl e Replicate s Deviation s NA . 3 M Environmenta l Laboratory Project : GLPlO-01-01-3 9 Sequenc e b121221 a ±20 % recoverycriteri a me t(ET S 8-4 4 Sectio n 13.4 ) K I Ye s •N o <20 % RS D precisio n (ET S 8-4 4 Sectio n 13.4 ) K I Ye s •N o

Ye s • N

o



## 3. 7 Fiel d Matri xSpike s +30 % recoverycriteri a met . (ET S 8-4 4 Sectio n 13.4 ) 

## 3.7. 1 Fiel d Matri xSpik e Deviation s NA . 

## 3. 8 Limi t ofQuantitatio n (LOQ ) I Yes •N o

Al l LOQ s equa l th e low-leve l calibratio n standar d concentratio n wit h are a count s at leas ttwic e tha to fth e metho d blank(s ) (ET S 8 - 4 4 Sectio n 13.2 ) K I Ye s •N o 

## Manua l Integration s Manua l integratio n reviewe d b yanothe ranalyst/tea m lea d (ETS-12 - 010.0 , sectio n 9) : : Reviewe d by : |(^=+v ^ Date : j-z/^Z/' Z K I Ye s •N o 

## 4 Additiona l analytica l note s Al l dat a wil l b e reported . 

## 5 Signature s

Analys t Dat e

ET S 8-04 4 Analytica l Summar yChecklis t Pag e 3 o f3

## Buster : API4000 : J293020 3 pag e1/ 1 DATE12/21/1 2 ANALYST : CJ

G STUDYNUMBER : GLPlO-01-01-3 9 Matrix : wate r Sampl e Pre p Date : 12/20/1 2 Sampl e Aliquo t Date : 12/20/1 2 Mobil ePhase : (A ) 2m M ammoniu

macetat e (B ) Methanol TN-A

- o r standar dnumbe r (A ) 1 2 015-5 0 (B ) TNI2-034 2 3/ 4 Guard(pre-autosampler) colum nbetasi l CI 8 Size : 4. 6 m

mX10 0 m mType : C1 8 Spher e size : 5 Par t number: 70105-10463 0 Lo t number: 1191 9 Seria

l numbe r 1002175 6 Starte

d7/25/1 2 Analytical colum

nbetasi l CI 8 Size : 4. 6 m

mX10 0 m mType : CI 8 Spher e size:__5 Par t number: 70105-10463 0 Lo t number: 1191 9 Seria

l numbe r 1002176 2 Starte d10/9/1 2 BatchName : bl21221 a Printed : Friday , Decembe

r 21 , 201 2 12:4

8 P M 

# CT Grz|20) 2