A copy of the Chain of 

Custody can be found in 

LABWARELIMS 

A copy of the GPO and/or 

Protocol can be found in the 

Lotus Notes GPO Database 

Communications 

Misc - Note to File 
3M ENVIRONMENTAL LABORATORY 

Note to File 

Project or Study Number: GLPlO-01-01-39 

LIMS Number: GLP 10-01-01-39 

Affected Data: None 

All logbook pages for the individual stock standards and mixes used for the calibration curves 

and LCS used for the analysis of GLPlO-01-01-39 were printed to pdf (exact copies of originals) 

and included in a folder labeled 'Logbook pages for GLPlO-01-01-39' located in the project folder 

located at: 

P:\Projects\Lab_ESA Analytical\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

PFOA\GLP10-01-01-39 FSIA Q4 

The chromatograms for results file bl 21221 a were printed to pdf and saved in the project folder 

located at: 

P:\Projects\Lab_ESA Analytical\Lab Requests 2012 - stw\GLP 10-01-01 Decatur Phase 3 

PF0A\GLP10-01-01-39 FSIA Q4 

A pdf copy ofthe signed protocol amendment GLP10-01-01 Amendment 39 is located in the 

project folder located at: 

P:\Projects\Lab_ESA Analytical\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

PF0A\GLP10-01-01-39 FSIA Q4 

Once the data package has been reviewed by QA and the report signed, the pdf will be moved to 

the shared drive (\\usfile01\b2\Projects\Lab_Shared\Archive Requests\Electronic Reports) and a 

reference to the location of the pdf will be added to the archived request form under Elec Media 

Path. 

Recorded By: Date: 

Page 1 of 1 
Collection Bottle Prep 

Sample Prep 

Standard Prep 

(pdf in project folder) 
Note To File 

Project or Study 

Description: 

Decatur Phase 3 - FSIA groundwater 

LIMS Number: GLPlO-01-01-39 

Affected Data: None 

On November 29, 2012, seventy-five 250 mL Nalgene bottles were marked with a 200 mL level line and 

labeled. The trip blank and trip blank spikes were filled with Milli Q water (TN12-0400) and sealed after they 

were spiked. 

The field matrix spike bottles for select sampling locations were spiked with the following: 

Field Matrix Spikes 

Well No. 

Spiking 

Solution 

Approx. 

Value 

(pg/mL) 

Spike 

Amount 

(ML) 

Spike 

Cone. 

(ng/mL) 

1378 12 008-22 10.0 40 2.0 

141R 12 008-22 10.0 40 2.0 

131S 12 009-202 100 40 20 

143R 12 009-202 100 40 20 

130S 12 009-202 100 200 100 

1368 12 009-202 100 200 100 

145R 12 009-202 100 200 100 

12 008-22 10.0 40 2.0 

Trip Blank Set 12 009-202 100 40 20 

12 009-202 100 200 100 

A 1-L container of Milli Q Water (TN12-0400) will be provided to be used for the collection of equipment rinseate 

blanks. 

Used Eppendorf Research pipette 3402277 to add spiking solution to samples. 

Recorded By: Date: 

l\|2q/|Z 
Printing 12/20/2012; 2:32 PM 

GLPlO-01-01-39 Sample Prep Work Sheet; ETS-8-044.1 

date: 12/20/12 Analyst: CJG 

Sample ID Sample Description Dllutlon Sample aliquot (ml) Spiking std ID Spike Amt (uL) Reagent Water (mL) Final Vol (mL) 

LCS-121220-1 O.Sppb LCS NA NA 12009-134 50 10,0 10,05 

LCS-121220-2 O.Sppb LCS NA NA 12009-134 50 10,0 10,05 

LCS-121220-3 O.Sppb LCS NA NA 12009-134 50 10,0 10,05 

LCS-121220-4 5ppb LCS NA NA 12009-133 50 10,0 10,05 

LCS-121220-5 5ppb LCS NA NA 12009-133 50 10,0 , 10,05 

LCS-121220-6 5ppb LCS NA NA 12009-133 50 10,0 10 05 

LCS-121220-7 • 30ppb LCS NA NA 12008-22 30 10,0 10,03 

LCS-121220-8 30ppb LCS NA NA 12008-22 30 10,0 10,03 

LCS-121220-9 30ppb LCS NA NA 12008-22 30 10,0 10,03 

GLP10-01-01-39-001 DAL-GW-130R-0- 100 0.100 NA NA 9,9 10,0 

GLPIO-OI-OI-39.OO2 DAL-GW-130R-DB- 100 0.100 NA NA 9,9 10,0 

GLP10-01-01-39-003 DAL-GW-130S-0- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-004 DAL-GW-130S-DB- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-005 DAL-GW-130S-FMS- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-006 DAL-GW-130L-0- 10 1.00 NA NA 90 10,0 

GLP10-01-01-39-007 DAL-GW-130L-DB- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-008 DAL-GW-131R-0- 100 0.100 NA NA 9,9 10,0 

GLP10-01-01-39-009 DAL-GW-131R-DB- 100 0.100 NA NA 9,9 10,0 

GLP10-01-01-39-010 DAL-GW-131S-0- NA NA NA NA NA NA 

GLP10-01-01-39-011 DAL-GW-131S-DB- NA NA NA NA NA NA 

GLP10-01-01-39-012 DAL-GW-131S-FMS- 10- 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-013 DAL-GW-131L-0- 10 1 00 NA NA 9,0 10,0 

GLP10-01-01-39-014 DAL-GW-131L-DB- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-015 DAL-GW-133R-0- 10 1,00 NA NA 9.0 10,0 

GLP10-01-01-39-016 DAL-GW-133R-DB- 10 1.00 NA NA 9,0 10,0 

GLPl 0-01-01-39-017 DAL-GW-133S-0- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-018 DAL-GW-133S-DB- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-019 DAL-GW-133L-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-020 DAL-GW-133L-DB- 10 1,00 NA NA 9.0 10,0 

GLPl 0-01-01-39-021 DAL-GW-134R-0- 100 0,100 NA NA 9.9 10,0 

GLP10-01-01-39-022 DAL-GW-134R-DB- 100 0,100 NA NA 9,9 10,0 

GLP 10-01-01-39-023 DAL-GW-134S-0- NA NA NA NA NA NA 

GLP10-01-01-39-024 DAL-GW-134S-DB- NA NA NA NA NA NA 

GLP10-01-01-39-025 DAL-GW-134L-0- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-026 DAL-GW-134L-DB- 100 0,100 NA NA 99 10,0 

GLP10-01-01-39-027 DAL-GW-135R-0- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-028 DAL-GW-135R-DB- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-029 DAL-GW-135S-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-030 DAL-GW-135S-DB- 10 1.00 NA NA 9,0 10,0 

GLP10-01-01-39-031 DAL-GW-135L-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-032 DAL-GW-135L-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-035 DAL-GW-135S-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-036 DAL-GW-135S-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-037 DAL-GW-136S-FMS- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-03B DAL-GW-136L-0- 10 1,00 NA NA 9,0 10,0 

GLP 10-01-01-39-039 DAL-GW-135L-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-042 DAL-GW-137S-0- NA NA NA NA NA NA 

GLP10-01-01-39-043 DAL-GW-137S-DB- NA NA NA NA NA NA 

GLP10-01-01-39-044 DAL-GW-137S-FMS- NA NA NA NA NA NA 

GLP10-01-01-39-045 DAL-GW-137L-0- NA NA NA NA NA NA 

GLP10-01-01-39-046 DAL-GW-137L-DB- NA NA NA NA NA NA 

GLP10-01-01-39-049 DAL-GW-138S-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-050 DAL-GW-138S-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-051 DAL-GW-138L-0- NA NA NA NA NA NA 

GLP10-01-01-39-052 DAL-GW-138L-DB- NA NA NA NA NA NA 

GLP10-01-01-39-053 DAL-GW-CW26C-0- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-054 DAL-GW-CW26C-DB- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-055 DAL-GW-CW26L-0- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-056 DAL-GW-CW26L-DB- 100 0,100 NA NA 9,9 10,0 

GLP10-01-01-39-057 DAL-GW-140R-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-058 DAL-GW-140R-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-059 DAL-GW-141R-0- NA NA NA NA NA NA 

GLP10-01-01-39-060 DAL-GW-141R-DB- NA NA NA NA NA NA 

GLP10-01-01-39-061 DAL-GW-141R-FMS- NA NA NA NA NA NA 

GLP10-01-01-39-062 DAL-GW-142R-0- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-063 DAL-GW-142R-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-067 DAL-GW-145R-0- 10 1,00 NA NA 9,0 10,0 

GLP 10-01-01-39-068 DAL-GW-145R-DB- 10 1,00 NA NA 9,0 10,0 

GLP10-01-01-39-069 DAL-GW-145R-FMS- 10 1,00 NA NA 9,0 10.0 

GLP10-01-01-39-070 DAL-GW-131S-RB- NA NA NA NA NA NA 

GLP10-01-01-39-071 DAL-GW-145R-RB- NA NA NA NA NA NA 

GLP10-01-01-39-072 DAL-GW-TRIP01-0- NA NA NA NA NA NA 

GLP10-01-01-39-073 DAL-GW-TRIP01-LS- NA NA NA NA NA NA 

GLP10-01-01-39-074 DAL-GW-TRIP01-MS- NA NA NA NA NA NA 

GLP10-01-01-39-075 DAL-GW-TRIP01-HS- 10 1,00 NA NA 9,0 10,0 

12/20/12 CJG; GLPlO-01-01-39 samples diluted with Milli Q Water TNI2-0421 and vortex mixed. 

I I 

12/20/12 CJG; Standard curve 12 011-30 aliquoted into 2-mL glass autovial. Ten autovials of Milli Q Water TN12-0421 were aliquoted to be used as solvent/method blanks. 

I 12/20/12 CJG: LCSs prepared using Milli Q Water TN 12-0421 for sample aliquot. 

T I 12/20/12 CJG: Used Eppendorf pipettes L13682B and L15816B 

ETS-8-044,1 sample prep 121220,xls Page 1 of 1 
Analytical Case Narrative 

Data Reduction Calculations 

(excel spreadsheet in project 

folder) 

Control Chart — Analytical 

Uncertainty 

(excel spreadsheet in project 

folder) 
3M Confidential 3M Environmental Laboratory 

Project: GLP10-01-01-39 

Sequence b121221a 

3M Environmental Laboratory 

3M Technical Lead: Susan Wolf 

Building 260-5N-17 

651-733-9851 

Report Author: Chelsie Grochow 

Analytical Team: 

Chelsie Grochow 

Analytical Cas e Narrative for Method ETS-8-44.1 

Project GLP10-01-01-39 

Decatur FSIA GW- Q4 2012 Sampling 

Direct injection analysis of samples 

Sequence: bl 21221 a 

Report Date: December 26, 2012 

Instrument run summary will be printed and included in the raw data package. 

Results table, calibration curves, and chromatograms will be printed to pdf. 

ETS 8-044 Analytical Summary Checklist Page 1 of 3 
3M Confidential 

1 Project Scope and Data Quality Objective 

3M Environmental Laboratory 

Project: GLPlO-01-01-39 

Sequence b121221a 

General Project Outline available. Yes • No 

If No, Please briefly describe 

project scope and DQO 

GLP 13 Yes • No 

2 Sample Container Preparation 

Sample container preparation documented in a Note to File included in the raw data package. 

3 Sample Analysis 

3.1 System Suitability 

Initial System Suitability area counts with RSD <5% and retention time with 

RSD <2% (ETS-8-44 section 13.1) Yes • No 

3.1.1 System Suitability Deviations 

NA 

3.2 Instrument Calibration 

Curve type Quadratic, 1/x 

r^>0.990 Linearity criteria met (ETS-8-44 section 13.2) El Yes • No 

< ± 25% residuals, except LOQ of ±30% (ETS-8-44 section 13.2) Yes • No 

Mid-level calibration points disabled • Yes No 

The highest standard was disabled for PFOA to meet method criteria. 

3.3 Continuing Calibration Verification 

±25% Difference criteria met for periodic CCVs (ETS-8-44 section 13.2) Yes • No 

3.3.1 Continuing Calibration Verification Deviations 

NA 

3.4 Method Blanks 

Method blanks uniquely identified in the run sequence. KI Yes • No 

Average area counts of target analytes in the method blank present at s 1^ x 

the area counts ofthe LOQ standard (ETS-8-44 Section 13.3) KI Yes • No 

3.4.1 Method Blank Deviations 

NA. 

ETS 8-044 Analytical Summary Checklist Page 2 of 3 
3M Confidential 

3.5 Lab Control Spikes 

3.5.1 Lab Control Spike Deviations 

NA. 

3.6 Sample Replicates 

RPD for field duplicates <20% (ETS-8-44 Section 13.4) 

3.6.1 Sample Replicates Deviations 

NA. 

3M Environmental Laboratory 

Project: GLPlO-01-01-39 

Sequence b121221a 

±20% recovery criteria met (ETS 8-44 Section 13.4) KI Yes • No 

<20% RSD precision (ETS 8-44 Section 13.4) KI Yes • No 

Yes • No 

3.7 Field Matrix Spikes 

+30% recovery criteria met. (ETS 8-44 Section 13.4) 

3.7.1 Field Matrix Spike Deviations 

NA. 

3.8 Limit of Quantitation (LOQ) 

I Yes • No 

All LOQs equal the low-level calibration standard concentration 

with area counts at least twice that of the method blank(s) (ETS 8-

44 Section 13.2) 

KI Yes • No 

Manual Integrations 

Manual integration reviewed by another analyst/team lead (ETS-12-

010.0, section 9): : Reviewed by: |(^=+v^ Date: j-z/^Z/' Z KI Yes • No 

4 Additional analytical notes 

All data will be reported. 

5 Signatures 

Analyst Date 

ETS 8-044 Analytical Summary Checklist Page 3 of 3 
Buster: API4000: J2930203 page 1/1 

DATE 12/21/12 

ANALYST: CJG 

STUDY NUMBER: GLPlO-01-01-39 Matrix: water 

Sample Prep Date: 12/20/12 

Sample Aliquot Date: 12/20/12 

Mobile Phase: (A) 2mM ammonium acetate (B) Methanol 

TN-A- or standard number (A) 12 015-50 (B) TNI2-0342 3/4 

Guard (pre-autosampler) column betasil CI8 

Size: 4.6 mm X 100 mm Type: C18 Sphere size: 5 

Part number: 70105-104630 Lot number: 11919 Serial number 10021756 Started 7/25/12 

Analytical column betasil CI8 

Size: 4.6 mm X 100 mm Type: CI8 Sphere size:__5 

Part number: 70105-104630 Lot number: 11919 Serial number 10021762 Started 10/9/12 

Batch Name: bl21221a 

Printed: Friday, December 21, 2012 12:48 PM CTG rz|20)2