I - 

# •

•

• .. APPENDIX N ASSORTED FACT SHEETS (SAMPLING)

\ 

### -

/

\ "I

# ~.w4~~A~~ , 

### .. 

# '.**~aste·** 

# Program 'r

## C6-;;'~ ,- . ' ,

# \\(~;.;. -;.

# ~._,l

# .**~.**Oregon'sHazardous

# ~V,---' 

# -'----_-'----**--'---~_** I MANAGING WASTE TO PROTECT PUBLIC HEALTH AND THE ENVIRONMENT



### Your

### bu~iness'is includedin the printingand allied industry category ifit is invovled in: '.

• '" --' ' •• - \" .' • " #. '.". 

## PRINTING AND , GRAPHIC ART '



## -

## INPUStR,I~S '

......

e,**.:~** 

### , ' 

### " ,Preparation , " " ". , -' Typesetting, Gravure , :- Engraving ,

### -;Ph6toproces~in8' " 

### Letterpress c, 

### Lithographyf.,'
., Photoengraving ',' '"



### .-- 

## "

'

# •..

'

, "

. - . .



# .... ". '. \ .' 

### "Printing, , ' Heatset lithography**'~** 

### Non heatset Iithographyc- , -' Thermography ' " '.- 'Business form printing' ', .'" - Sheeted lithography , , , , '" " ,.. '-' Letterpress printing' (including flexography)

. ,-:' Gravure printing '. - , -', ,-**Sc~ee"n** 

### pres,s printing 

### , Ftnishing**operation~,** 

### ' .' , , - . Looseleafbinder manufacturers

" < 

### Trade binding operations ,

### .~**,Book.bini#ng~pe~tions"** ' ' , _' -:In-house bindingoperations , , , -' Magazine and catalog binding operations " .' . - '( ., \. 

### .. '

\,

I • , J 

### , ' Though not all printing oiailied industry operations produce hazardous waste; those thatuse "

ignitablesolvents, strong acid or, alkaline 'solutions, or paints

### aild·inks.thatcontai~ heavy metals usually 

### do, Table l lists some typical process operations.in.theprinting andallied : -,' , ": ' industries that li!'e likely toproducehazardous.wastes. ,,' ,"

l . . ...... . ....**~.** .



### -- . : 

### ::- "

,.\- 

# '. e**~.** '{

- 

## .- r >, /"". " 

# . , , .. 

### \ . I ': .. ,' 

### Note: , ,_ _ , 

### Please-see glossary for explanation ofterms.

.. 

### . 

### -: . .' .....

## Tablet' 

# 0"

" TYPICAL PROCESSI OPERATION : 'TYPICAL**·MA~·USED** TYPi¢AL MATERIALS INGREDIENI:S

ON:'LABEL GENERAL TYPES OF WASTES GENERATED PLATE PREPATIO!'l'. Counter-etch to remove phosphoric acid**p~osphoric** add acid/alkaline waste, , oxide Deep-etch coating of deep etch bath ammonium 'dichromate, acid/alkaline waste; heavy , : plates ' ammonium hydroxide metals, waste etchbath
; Etch baths rnultimetal plate and ferric chloride (copper)' : ' waste etch bath, acid/ plate coating, .aluminum/zinc alkaline-waste, heavy chloride/hydrochloric metals**~,** '



### .. acid (chromium), nitric acid (zinc, magnesium), gum arabic" ' Apply light sensitive resins, bindersi , PVNammoniunl dichto-, photographic waste coating emulsion, photosentsi- mate, polyvinyl cinnamate, ' tizers; gelatin, fish !elue/alburniri; silver photoinitiators hali e/geIatin emulsion,

. ,; gum arabic/ammonium, . , dichromate ' Developing plates developer lactic acid; zinc chloride, photographic waste**m~esium** chloride," hy oquinone ' ,:' , . Wash/clean plates, type, alcoholscsolvents" 'ethyl alcohol, benzene,. spent" solvents die, press. blanket and toulene, xylene, isopropyl I, rollers . alcohol, methyl ethyl I ketone. trichloroethylene, I perchloroethylene, carbon ,- tetrachloride; gasoline,**'naptha,'~ersoene** ' Apply lacquer resins, solvents, vinyl PVC, PYA, maleic acid; spent solvents .lacquer.Jacquer methylethyl ketone, . developers cyclohexanone, isopliorone 

# ....

, 

# ,. 

# 0"

Makinggravure cylinders acidplating bath '. Using ink (lithography,

letterpress screen .**~".**
. printing, flexography) pigments, dyes; varnish, drier, extender,' : modifier, fountain . . solutions titanium oxide, iron blues, molybdated chrome orange, phthalocyanine pigments, oils, hydrocarbon solvents, waxes; cobalt/zinc/ ' ·manllimese oleates, plasticizers, barium-based pigments " copper, chromic. acid, chrome' waste ink with solvents/ chromium/lead/barium, ink sludges with chrornium/lead/barium . spent.plating waste

I, i 

### i Lacquer stencilTtlm 'solvents, \fir.ester aliphatic"acetates; cellulose- spent solvents film, viny fi m, dyes based lacquer, plasticizers Photographic stencil organic acids, gelatin acids, alkalies, peroxide- hydrogen peroxide. film Hllgmented), polyester forming compounds, 11m base . . plasticizers, surfactants - Photoemulsion resins, .binders,

_ PV A, PV AC, ammonium or photographic waste. photosensitizers, dyes' potassium bichromate, diazonium compounds Blockout (screen' filter) Pif.mtmted polymers, methylene chloride, spent solvents so vents, acetates methanol, methyl cellulose acetates .:. :"\ 

# IIII1III What, do I haveto 

# do to 

# 'manage my. 

# hazardous.waste.properly?**.~\.** . . . . - < • • , 

# 'Hazardous waste 'generators fall**intothn~e** 

# categories.' Each has differing regulatory**,re9uitements~ ':Her~**  

# arethe' basic requirements.. ' ., .. , '" r.".", 

# You are a: r " "

" ' .' -**~.**

.J' .• "'1 • 

### and you must: :

Identify 

# an hazardous wastes: , " - Send waste 

## to a regulatedhazardous: waste facility or, , "

- Recycle**you~** 'wastes or, " Send 'wastes toa landfill'with the, : operators pennission ,'. . - Never-accumulate 

# at any time more , than' 2,200 pounds of hazardous. wastes 

## .CoDtlitiooallYExempt Generator " '**~'** 

### . -if in a'calendar month you: ' -generate less than 

## z.z' pounds 

# of

c 

### acutely hazardous wastes -

- ", -generate less than -220 pounds of hazardous wastes' '

. ,:... 

### if in a calendar month you:

- generate between

### 2~0 and 2,200'

pounds

## 'Sinail'Q~antity 

## Generator

and 

# ,you must: "

- Identify all hazardous wastes -Obtain a 

### DEfIEP;\, identification

number " '. - Properly package the wastes. ; -Properly label and mark containers',' c Accumulate hazardous waste on-site .no more than 180 dayS or

### 270day~' if ': transporting more, than 

## 200 miles, , . ' - Placard waste for shipment: . Comply with the Oregon' Public " Utility Commission'stransportation ". , requirements,**~,'** , - Use a manifest

# to ship (maintain , 

# c'- copies 'for three years): , :- Use only-transporters and facilities
, ,with DEQ/EPA ID numbers

### '~Ship waste to regulated hazardous " waste facilities within 180 days, or; , .- - Recycle hazardous waste on-site' "., , within 180 days

- Prepare moditiedcontingency plans, '

emergency procedures, and person-: ' nel training. ' , ' , '

- Meet preparedness and prevention '
, requirements , ' , . ' - Keep records ,

Submit a quarterly report to DEQ ',' -Pay fees ' 

### if in a calendar month you: 

### , -generate 2.2 or.more pounds 

### of
, acutelyhazardous wastes , ' ', generate 2,200 or more pounds of**'hazardou~** 

### wastes' "', ' 

## ,:Fully Regulated 

## Generator

and youmiist: , , : Identify allhazardous wastes ' "**',~** -Obtain a DEQ/EPA identification ' 

# " '

'number . .:Properly package the wastes' , , , - Properly labeland mark.containers

- Accumulatehazardous waste on-site



### no more than**~',**

- Placard 

### waste for 

### shipment

- Comply with the Oregon.Public

Utility, Commission's transportation requirements ;' . '- Use a manifestto ship (maintain " - , ,

### c~piesfoithree years), . , lfse orily transporters and facilities ' with DEQ/EPA IDilUmbers ' • ;- Ship' waste to regulated hazardous' ,

, .waste facilities within**~,** or; . , -

### R~yclehazard;ous waste on-site within 

## 2D..dllD' , ", -.Prepare contingency plans; 

### -emer**gen~y** procedures, and 

### personnel'

training . "

- Meet preparedness and prevention

. requirements' - Keep records
, . - Submit a quarterly report to DEQ**'-P~y** fees ' , " ,,", .' 

## .' 

# . I I C



### Note: Upon registration 

# as a hazardous waste generator, you will receive a set of theregulations that-apply to each generator category. '

- 

### . - . . . 

# ()

'3 " 

## .

### 111111I111111 

## II I 

## ,II 

## WASTE DESIGNATION AND SHIPPING INFORMA

# nON- FOR,HAZARDOUS WASTES 'PRODUCED'IN,PRINTING'AND GRAPHICS SHOPS ' " " .The

## table~below provides

## info~~ti~n for

## ~l~sifying**hai~dous** waste

## pri~r to 'off-site shipment. ' The-correct designation, , for a' specific waste should be verified with the hazardous waste facility you are shipping to; the,regional offices of the "

. 'federal Department ofTransportation (DOT) or the state offices of the Public Utility Commission (PUC) prior to**~,**



### completion 

### ofthe hazardous waste manifest. ITEMS LISTED ARE,EXAMPLES ONLY! Other Department ofTransportation (DOT) descriptions and

### identifica:tio~ codes maybe applicable in some circumstances. 

## Table 2' 

## WASTE DESCRIPTIONS

'Photographic "astes', " Heavy metal Photographic, prosolutions cessing wastes conta'(ning heavy inetal's 

## 'PROCESS 'OR WASTE ,TYPE

,**Trichloro~**

,ethylene 

## 'MATERIALS ",' USED'

Trich l oroe.thv

## l ene ,: eth i nyl- tri chlori de,' ,TriClene,'**~ri** ' 

## DEQ/EPA WASTE CODE

0003" 0'006,: - 0007,' 'or ODDS 'F001 

## 'DOT, SHIPPING" 

# NAME

." ; hez ar-dous.**'wa~te solutionN.O.S~**  , ('containing cadmIum,' , cliromium, .I ead, silver,orcyanide)

,**~astetrich'loro~:** ,**e,thylen~** 

## HAZARD

. - 

## . . .. 

## CLASS
ORM-E
ORM-A 

## UN/NA NUMBER
NA9189
UN1710, Spent, Solvents

_ -Carbon Tetra-' carbon tetrachloride,

'chloride**~~~chloromethane,** "'ne'catorina, benz i no-

form, ,CCl 4 F001 "waste carbon tet rach lor. i de Ethano,l 'ethanol,ethyl 

### at cehet: 0001 l - ·'wasfe ethyl aLc oho l ,'waste ethanol IsC?propanol 'i sop'fo'pano l ,{SOpropyl alcohol 0001 waste' isoproP?lnol Ethyl Benzene, ' e thvt benzene 'F003 waste ethyl**~enzen~** 1,1,1' Tri- .. eh loroet'hane

Methylene,

Chloride ',_ 1,1,1 r ri ch l cr-oe thene aerothane, TT, cht erten, inh,ibisol ,,' trichlotoeihane, ,chloro-**~hen'NU"** NCl-C04626, , methylchloroform, .

chlorothene VC; aero- ,th',ene NM', narkoul,," so l met h tne ,Dichloromethane, ineth-" >ane',dichforide, methy-,

l'enebichloride;' NCI**CS0102~ methylerie~i** **chl~ride,** solaesthin, aerothene NM; narkoul, siknethi,:\e f001 .

" 

### - F002 waste 1,1,1**tri~,** chloroethane,

waste**d~ch~oromeih** ane or methylene chloride ORM-A UN1593,

Notes: N.O'.S: -not otherwise specified. " Flammable liquid (D.O.T. defmition) has a flashpomt below 100' F. , Combustible liquid (D.O.T. definition) has' a flashpoint between 100' and 200' F. , Ignitable \¥aste(DEQ/EPA definition) has a flashpoint <140' F.

UN/NA: United Nations/North.Amenca.International shipping codes.



## - " 4 

# o

"" 

### .. 

# •• , "

### ~ss~e'B~~·~v~~'Solve~~s**o~'~e~yv ~e~~ls'**  'Yaste Ink. . various constituent F001, '. so tvent s e car-bon :tet- . F002,

· rachloride, chloro- , ,F003:"

· form, 'methyLene ch t or- . FOOS,

ide,,1,1,1,-trichloro-' 000\;

. ethan'e,'benzene,**tol~.·** 0003,'

-uene , e·thyl. berizene , '0006,**,·tetrachlorriethyl~ne,** 0007' :. various. constituents . or 0008 , , f'rompi gme'rts :ch ro- . . mium,**copp~r~** lead,

. 'zinc,**~yanide; al~~-'**  ',**"inum~** ,cadmium; ni'ckel, c'obal.t'· . .. (waste ink · combus t-i b l e. l'i qujd,

· flammable

.Li qui d UN2867 UN1210 '.' "

"

.

### s~~ori@**Acid/AQ~~lv~e'~~stes**

" ADlDoniUliammonium hydroxide; .'

· Hydroxide.**'aqu~'ammonia,~spirit** of hartshorn, NH40H'. 0002' 'waste ammoni.um hydroxIde**(between·12~,and** 44%·ammoniaf .. '\laste' ,ammcinl.um hydrox- ..

. ide .( be l o"!J 2% ammorii a) corrosiveNA2672

. rna t er i.a·l**~,** --=. NA2672 

# "
.
Nitric Acid

## nitr.~c"acid; HN03,

## '_"0002~ , .aquatort I s Hydr::ochloric

·**~cid** · hydro.ch·lori,c a'cld,' ..... :'00.02 muriatic ac.Jd, HC,l '. ,- "

. 'was'te hydrochl'or I c '

.. acid I!Ilxture·. waste

### ~itrjc 'acid (over. 40%) , . '. " .

. wasie**~Itiic'~cld**

(below 40%) , cor'ros t ve .'materi a l corrosive . mat e

### ria l .**'NA178~** ,'UN2031 NA 1.760 Phosphoric

ACi,d. phosphor.i c 'acid, ·0002· ...•

### ~~ste**pho.sp~.orlc'** a"ci'd" .cor r-osi ve orthcphosphcr-ic acid, , material H

3P.o4'., ' " .' '. UN1805

0002'" :' was te 'sod i um

## hydr~x 

## i de ,:

## :'c.~·r r os i ve '; UN1823'" 

# ,<**ma~eri·al.,** '

, > 

# . " corrosive' . ,.UN1755 ;.-**materia~** ".corros Ive-UN1832: . mater I a l ' I'"' ,**wa'~te sUl,furic·.~dd,**  spent was'te sodium**h'Ydro~ide** .corrosi.ve;:. UN1824·· .L i qu id: or so lut i.cn mat er ie t : .;

:, ,',

.**'~aste** chromic acid

so l ut ion .," ' 0002



### .> 1,.-:

### ~sodium'hydr~x;de~**.~** -.: caustic soda,' soda**:ly~,** scd ium hydrate,'- NaOH .
sUlfuric'acid,:O,q:of' 0'002 Vitriol, H 

# 2S0'4. .'**~~romic** acid 0002 sodium hydroxide', " caustic soda, soda lye:,**'sodium'hydrate;CN~OH**

' .. S!JUuric Acid Sodha Hydrox- :ide (sol id, .' .f l ake , bead, · dr'y,', or**gran~** 'ular.) . , ". ': : Spdi'Um Hydrox- • .Ide t t iquid ·9 r ' s o l ut i.on )

-" ,-

K086:**ha~ardou~'~ast~,_ ll~uid**  0007,: , ' or .**soli"d~'NOS** ' or. 0008**sinlTlt'~lmiin~'~sste**
.Spent PLatIng' . spent etch ,baths " .

. 'Yastes''- '\. spent**pL.a~i'ng** 

### sotut ions" and. 

### st udges', .. .: . stripping and clean- . ".**~ngbaths",·'"** 'Ink**sa~~e~it~ C~rC8V~O~** **~emcl.**
. Ink Sludge ink··sludge containing

with·Chrc.iUm . heavy 'metals' . 

# .' . or lead ' . .F006, Foot, " F008, F009, or' F019' ,**h~zardo~s** waate l,lquld. or solid, NOS'(Nat Otherwise**Spe~i.fie~)·**
-; · ORM-E .

, ORM-E: . NA9189

. NA9189 

### . 

### {



## .... j



# . ·1

i "1 

## " il 

# .' l!J!nitlllble Mlllstes ,. Ignitable .ignitable wastes, NOS ·Yastes •.· ..OS 0001 waste, f Lammabte liquid**N.b~s.** 

### - .' ' waste combustible 'l i qu i d 'N .O:,S. waste· f l emmabl.e solid , N.O.,S. , " flammable' UN1993

liquid' ' combustible UN 1-993

. liquid flammabl'e··. UN1325

sol id.

" 

### ' ",

. 

## ,.... '

" , ,

.' 

# .

·V' L ".'

.. ;. .... '.1'.',' J .'-.' .

" 

### "

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, "

, "

..**'~** .

., 

### .•

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# - 

# .**'~,** .• :< "

.'t'**~,** . ;- 

### . "



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## ..... .,

, " ·,t.' ... : 

### ,', ';,..'



### . •... ' . " , -' ! .

, " -.'. :...", "

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".-:'

,-.I' "':'" ,,:. " "

.;'


### .**~;,.** :.r" ',:.,

........ -" 

### . .'1,:'- ,".,



### .**~,'** 

# .-
" c'**-;~** .' ,',

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, 

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. ':? ..



### . - ':**~.** .: 

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### ... < •• '

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, , 

# Oregon's 'Hazardous

, . 

## EQUIPMENT REPAIR 

## INDUSTRYOVERVIEW
• .J • 

### Yourbusiness is included in the:equipment repair category

## ~f you: "



### -. Repair

### ~r maintain any equipment, appliances, mechanical, or electrical g()ods'"

- Rebuild,'refinish, restore, or paint '

- Remove oil,' grease; rust, dirt, 'or paint The products you use on equipment, tools, floor; or your hands may contain hazardousmateri-
, " als..the wastes generatedfromtheir use may be hazardous. -

### Ev~r~ day workmen use products containing hazardous materials, these include: , .-Plating solutions and

### ~iudges - Toxic

Rust removers -Corrosive

- Used rags - Ignitable

paints - Ignitable ' Cleaners and' degreasers - Ignitable These products almost always.contain chemicals or materials that arehazardous to human health and to the' environment, Table' I lists typical operations and processes that use products containing hazardous materiais and and are likelyto produce hazardous wastes. '



# , 0 

# Og Note:
, Please see glossary for explanation ofterms.

## . Table 1 

# •
TYPICAL PROCESS/ OPERATION , TYPICAL' MATERIALS USED TYPICALMATERlALS , . GENERAL TYPES, , INGREDIENTS ' OF WASTES' " .

ON LABEL GENERATED**d~greilsers-** (gunk), and petroleum distillates, cleaners, varsol, aromatic hydrocarbons, solvents, acids/alkalies m0eral' spirits , .' • Oil and grease

removalParts and equipment cleaning degreasers- (gunk), solvents, acids/alkalies;' cleaning ,fluids -" , petroleum distillates; - aromatic hydrocarbons, mineral spirits, benzene, toluene, petroleum naphtha .ignitable wastes, spent solvents, combustible solids, waste acid/alkaline solutions' . ignitable waites: spent solvents,' combustible solids, waste acid/alkaline solutions . Rust removal ' naval jelly, strong acids: phosphoric acid, hydrochlo- waste acids, waste strong alkalies ric acid, hydrofluoric acid, . alkalies' sodium hydroxide " ., Paint preparation ' , . paint thinners, enamel reducers, solvents; white spirits . .

### alc~hols,**pe';ole~in** distillates, Oxygenated solvents, niineral spirits,; , ketones " 'spent solvents, ignitable, wastes, i/1nitable paint wastes With heavy metals ; -, enamels, lacquers" epoxys, alkyds, acrylics, primers Painting . I • • acetone, toluene, petroleum ignitable paint wastes, distillates, epoxy ester spent solvents, paint, resins, methylene chloride; . wastes with heavy metals, , xylene, VM&P naphtha, ignitable wastes '

aromatic hydrocarbons, , 'methyl isobutyl, ketones .',

, " Spraybooth, spray guns, and brush**cle~g** " 

# . Paint removal paintthinners, enamel reducers, solvents;', . white spirits

. ' ".\ solvents, paint thinners; enamel 'reducers, white spirits . , ketones, alcohols, toluene, acetone; isopropyl alcohol, petroleum distillates, ,mineral spirits ' I .acetone; toluene, petroleum· distillates, methanol; methylene chloride" isopropyl alcohol, mineral spirits; alcohols, ketones, . other oxygenated solvents,

### ignitabi~ paintwastes, heavy" metal paint wastes, spent solvents ' , ignitable paint wastes;' ' heavy metal paint wastes, spent solvents;

# "~. VIastes 

# are considered hazardous if they have any ofthe following characteristics:



### .lIgnnfiQ21IGBe -Substances that spontaneously burn or combust ata

## temper~ture less than

140· Eare'considered ignitable (flammable); They 

### canbe liquids," solids, flammable'

. gases, or oxidizers. Typical ignitable substances include solvents, paint 'and lacquer ',thinners, and stripping agents. Thesesubstances yield dangerous.wastes that pose a fire

hazard,··'·""" 

### Corrosive Corrosive substances are acidic liquids (pH less than or equal to 2), alkaline liquids (pll.greater than or equal to 12.5) or liquids that corrode steel at a rate greater than 0.25 inch per year. Wastes from these substances can dissolve most materials; specialized. , containers are necessary to resist corrosion. Extreme care must be used when handling

them because they bum the skin. . . . .


### , lRe2canve**c~Reacti~e** substances are very unstable and readily, rapidly, or violently change

when mixed with or exposed to-water, heat, pressure, orother materials, These sub-'- '

. stances, especially cyanide, or sulfide compounds, may generate toxic gasesunder mildly , acidic or alkaline conditions. Chromatic acids, perchlorates, and peroxides are common reactive substances. Wastes produced from reactive substances are hazardous since they' may explode. ' '. , ' lElP'1l'mtic - Wastes are toxic if, after, being tested through an extraction procedure (EP); " they coritain high concentrations 

### ofheavy metalsor specific pesticides. Toxic wastes can

cause illnesses such as cancer, kidney damage, birth defects.andblood disease. Examples ,of 

### EP toxic wastes are photographic processing wastes, waste inks, and paint sludge from the recycling of solvents. Some toxic wastes are acutely hazardous if they lire fatal to humans in low doses or are capable ofcontributing to serious irreversible: ' illnesses. . . 

### 2, 

# •, " 

## Hazardous' waste generators fall, into three categories:' requirements, Here are the basic requirements.

,You are a:' '



# • -ifin a calendar month you:

- generate' 

### 2.2 or more 

### pounds 'of

acutely hazardous wastes ,"

- generate 

### 2,200 or more pounds of hazardous wastes



### ,2l1l1l411 YOURmunsft:

- Identify all hazardous wastes

- Obtain a 'DEQ/EPAideIltification ' 

### number '

- Properly package the wastes' . 

### -Properly label arid mark containers' , -Accumulate hazardouswaste on-site" , , no more than , , - Placard waste for shipment



### - Complywith the oregon Public ,7Utllity Commission's transportation
, requirements - Use a manifest to ship (maintain ,copies for three years)' , - Use only transporters and facilities

with DEQ/EPA ID numbers " - Ship' waste to regulated hazardous

waste facilities withiri**~,** or; , Recycle hazardouswaste on-site ,**within'~,** '

- Prepare contingency plans, emer-. , ' gency procedures, and personnel '

training' Meet preparedness and prevention requirements
, - Keep records

- Submit a quarterly report to DEQ ' -Pay fees' ifin a, calendar' 

### month you: ' 

### "generate between 

### 220 and 2,200 pounds

. . 

### ,.**~llIl1l411** 

### YOUR munsft: Identify all hazardous wastes

- Obtain 

### ,3 DEQ/EPA, identification

number . ' -Properly package the wastes

- Properly label and mark containers '- Accumulate hazardous waste 'on-site "no

### ~ore than 

### 180 days

### 6~ 270 days if transporting more than 200 miles
, - Placard waste for shipment,' . '. Comply with the Oregon**Publi~**

..UtilityCommission's transportation

requirements Use a manifest to ship (maintain ' copies for three years) " . Use only transporters and**facilitie~**

with DEQ/EPA ID numbers' 

### -Ship waste to regulated 

### hazardous

waste facilities within 

### 180 days; or;

- Recycle hazardous waste on-site

. within 

### 180 days . ,

- Prepare modified .contingency plans, emergency procedures, and personnel training . , , " . - Meet preparedness and prevention '

, requirements,
, -**K~p** records ,

'-,Submit a quarterly report to DEQ -Payfees, " ..' . - 

## " ,

## C((J)IJD«!Ifi~fi((J)IJDBlnny**IE~~rrUnlPa** ,**G(2IJD(2Il'~a((J)Il"** 

## ' ." , .-

if-in a calendar month you:

-generate less than 

## 2:2 pounds of. " acutely hazardous wastes 

### -generate less than 

### 220 pounds of,

hazardous wastes



### , alll1lrrll YOUR mURsft: • Identify all hazardous wastes

- Send waste to a regulated hazardous , , waste facility 

### or; ,

- Recycle**yo~r** wastes or, , , : Send wastes to a landfill with the

operators perinission

. Never accumulateat any time more . than 2,200 'pounds of hazardous ". , 'wastes



# • Note:. Upon registration

# as a hazardous waste generator, y'ouwill receive' a set 'of the

### re~ulations that apply to each generator category.



### 3.

## WA§1I'IE j]))IE§llGNA1rIION ANj])) §JHil[IPIPmG**IINlFO~MA** 

## 1fIION**lFO~ JH[AZA~]J))(Ol1U§**  

## WA§1I'IES' lP'&,Oj]))U)CIEj]))

## llNIEQWI1P'lWEN1I'~IEIPAll~ §JH[OIID§ " ' The

## tabl~ below provides information for classifying your hazar:dous waste prior t6 off-site shipment. The correct designa- " tion for a specific waste should be verified with your transporter or the regional offices ofthe federal Department of Trans- 

### .portaiiondxrl') or the state offices of the PUblic Utility, Commission (PUC) prior to completion 

# ofthe hazardous waste' ,!l1anifest: . ITEMS LISTED 

### ARE EXAMPLES 

### ONLYI ' Other Department ofTransportation 

### (DOT) descriptions 

### and identification codes may be applicable in**some,~ircumstances.** 

# •

Table 2

. 

## . ,**pet~ole~m** naphiha ' 0001
"**petroleumdistjJl~tes· ~001**  1,L'·'trichloroethane F001'

(ch lor-cethene ) . 

### :liAZARD 

## UN/NA,**C~SS** 

### 'NUMBER
corrosive varies

materialcorrosive UN1814

material- ,corrosive UN1824,

material, ' .,flammable' UN 1993

l i qui d varies varies , flammable . UN1993 ' liquid 

# • flammable UN2553

liquid flammable UN1255 liquid flammable, UN1268 , liquid

. ORM-A UN2831 

### .DOT SHIPPING 

### NAME

waste petroleum

naphtha ' w,aste petroleum.

distillate**'wa~ie** 1 1 1 triO'

.,.. 

### -" chloroethane ' depends on',**typ~** of,**ac~d** waste potas,sium

hydroxide solution waste sodium**~ydroxidesc)lution** waste flammable , l i qu i C1, N.O. S •

. varies"

. wasteflammab'ie ". l i qu i d, ,N: Q• S•

waste naphtha' 0002 

## Dooi**D09~** F002 or F004, FOO1- Dli01 0001 

### , DEQ/EPA WA,STE CODE 

### MATERIALS USED
acids:

ceus tLc vsoda carburetor ,cleaners,

. . . .**c~i~ririate~ ~olv~~ts'**  ,i gni tabl e (fl ammable) degreasers' . mineral sp i r it solvents 

### WASTE TYPE,**Oil/Gr~<nsl!, a~"61t** **lP<nintll;~~~rSl1l:'icin',white** spirits, varsol 0001 alcohols 0001. 'enamel reducers" ,0001

. "MEK" . F005 '

mjnera t'. spi**r'i~s"** -. '0001**pai~t t~inners**  varies petroleum,distillates .0001, waste 'naphtha' "flanimable' " UN2553 liquid ' 'waste flammable**flammab~e~** UN1993

Uquid,N,.O.S;.. liquid waste, flamamble flammable UN1993

l i qui d, N.O.S. ( iquid waste 'methyl ethyl flammable UNn93 " ketone _l iquid waste naphtha ' : fl aniniab l e ,UN2553 was fe ft'ammab l e l**iqui~** flammable', UN1993 'l'iquid,,'N.O.S. liquid waste petrQleum flanirnable UN1268'

d i 

### stiI Late ',' , ,.l**iq~id** "**l))ilVIl1lll:ht~** 

### acryt i 

### c .and alkyd 0001 waste flammable flamniable UN,1993 paints liquid, N;O,S. ,lJqufd enamels and 'epoxy, 0001 

# - or 

# - (-i f' U qu i d) 

### - r . paints hazardous waste., ORM-E UN9189 lacquers 0001 ' soUd, N.O.S. (if soUd) most paints with 0008 or' hazardous waste' ORM-E ' UN9189 

# •

tox i c .mer a l s 0007 .set id, N.O.S.



### 4

### II1II1111111

i 

# .0 Spray Booth/ Spray Gun/ Brush Cleaninli, Paint ReIIOval/. Stripping,

"Rust Removal acetone alcohols enamel reducers 

### "MEK" methylene**chl~ride'** 

### mineral spirits pain,t thinners 'petroleum disti l 

### Lat es VM&P naphtha toluene (Toluol)

'paj'nt thinners white spirits**,xyl~ne** 

### (xylol)

paint thinner aci·ds naval 'jeUy

\ ' 

### F003 0001 0001 F005
" F002 0001. ,0001

0001 F005 0001 F003
0002 0002 'waste acetone waste 'flammable'

l i 

### qu i 

### d, N.O.S .. I 

### waste flammable'

liquid; N.O.S. 

### waste methyl**e~hyl**



### ketone waste dichloromethane waste naphtha waste' flammable

liquid, N.0. S. ' 

### ,waste petroleum**,di.still~te.** 

### '**~ast~ pa~nt**  

### related

material' waste toluene waste naphtha waste xylene depends'on type of

acid waste phosphoric acid flammable liquid . flammable ,liquid 'fl anuilab l e ,liquid flammable

liquid ORM-A flammable

liquid f l ammebte



### l i qui d f·lammable

liquid flammable , liquid flammable

liquid ft'ammable

liquid flammable

liquid

. corrosive

material corrosive

material ·UN1090 UN1993 UN1993 , UN1193 , UN1593 ' UN2553 'UN1993 UN1268' NA;263 .UN1294 UN2553 UN1307 var.ies

waste cyanide mixture,

dr:y Poison B • UN15'88 

# .0 -Metal Finishing, strrpping/clea,ning' including . solutions (cyanide)**E~ectrop~ating** 

### plating bath**solu~ions** 

### ,and Electroless (cyanide). ph.ting, Etching, plating bath sludges**~tc.** 

### (cyanide)**platin~ p~etreatment** **sl~dges(cyanide)** 

### F009 F007 F008 F006 waste cyanide N.O.S·, 

### waste "cyanide

N,.O.S. 

### waste cyanide

d,ry solution, mixture, Poison B . 

### Poison B 

### Poison 

### B UN1935 UN1935 UN1588

hydroch'toric solutions 0002 spent acid solutions:**chromicsolutiori~** 

### 0002

nitric' stripping,

solutions ' phosphoric solutions**s~ljuric ~olutions**  

### 0002 

# . 0002 0002 . , waste chromic acid: ,solution wa's t.ehydroch lor i d acid waste**nitri~'a~id** > 

### 40% waste nitric acid < 

### 40% waste phosphoric acid waste**sulfuri~** 

### acid,

spent corrosive material corrosive material oX'idizer

. corrosive

material corrosive

material corrosive 'material UN1755 ' NA1789

UN2031 ,NA1760 UN1805

UN;832


# I I I. 

# o Notes:', N,O,S. - not otherwise specified. Flammable liquid 

### ro.o.r. definition) has a flashpoint below 100' F. .Combustible liquid (D.O.T. definition) has a flashpoint between 100' and 200' F. Ignitable waste(DEQIEPA definition) has aflashpoint <140' F. UN/NA: United Nations/North America, international shipping codes.


## 5

### '. / ,-@'oregonDEQ'. ". i 

### Hazardous Waste Program ...• 811 SW 6th· . ., . 

# [Q) 

# ®**~.** Portland, Oregon 97204 . (503) 229-5913 .' Toll Free 1-800-452-40 II 

### 6 

## '- 

# ••••



# •

•

. 9-88 

# = ,1

·1 I

# ." \ / .."**'~-7** \

# \!c":':~'/;' , 

# ·Oregoll'sHazardous· . '@'waste .Program
MANAGING WASTE TO PROTECT PUBLIC' HEALTH AND THE ENVIRONMENT

,-; :



### '" "ACUTELY**,~AZARDOUS** 

### ' 'WASTE' 

# 'GLOSSARY, " "J



### . , Some wastes are

## consid~red acutely hazardous." These are wastes 'that 

## EPA: has deter-

- minedto be.dangerous irr small-amountsi-therefore, theyare regulated the same as ,', 'large

### ~ounts ofother hazardous wastes; Acutely hazardous wastes, for example,-, may be generated using certain 'pesticides. 'They.also include dioxin-containing' ' 

# . , 

### wastes. ;. .- i 

# .' TOXIC 

### If your

## bU'sines~ generates more than 2.2 pounds of acutely hazardous wastes ·in:an.y', ' single calendar month, 'you would be categorized ;IS'

# a' fully regulated'generator. 'if_' 'your businessgenerates 2.2'pounds or less of acutely hazardous waste.in any.single "calendar month, you would be categorized as 

# aconditionally 'exempt small quantity' 'generator·> 'Those substances that ate 'classified as acutely hazardous are explicitly: . listed 

### inseveral federal and state 

### handbooks; Call 

### DEQ if you,'art: unsure about any

## ~' wastes you generate. ' , ',", . . ' , A

## ~ubstanceis toxic ifiris poisonous orharmfui to plant or

## anima(life.~ A toxic '," substance can alter**_~** 

### organism's .environment through chemical or physicalaction. "

## DEQ/EP~' ,ADEQ/EPA Identification Numberisaunique, 

### 12-character number .assigned HAZARpOUS. .' 

### to the physical location where'

# a hazardous waste is generated, to 'transporters ofhaz- , " WASTE 

### ,"ardouswaste:and to owners/operatorswho treat.istore.iordisposeof.hazardous waste:' IDENTIFICATION, . 

### The-identification numbers help DEQ compile and maintain 

# adatabase .on hazardous'**:NU~BER** 

### . 

### waste'activities,' ' . - ,,', . , 

# .' GENERATOR

MANIFEST 

### To obtain 'a DEQ,tEPA Identification Number, you shouldcomplete the form "Notification 

# of Hazardous Waste Activity". 

## .To request theform.contactyourstate hazardous,waste management agency (DEQ), Along withthe appropriate notification . ' 'form: you will receive instructions for-completing the.form and information onwhere you**cang~t_aoditioriarassistance'.** 

### , , ' ',' .',"': ' -' , ,,' " :' ' . ' A generatods.the personor'

## b~siness who actually produces the hazardous waste or > , 

### 'whose act firstcauses a hazardouswaste to become .subject to regulation; Under state and federal regulations, generators must determine if theirwaste ishazardolls and if 'so, must manage their waste according to regulation' from the point of generation -through 

### final destination, or "cradle to grave", Once awaste is.determined to be '

.hazardous, .generators must notify the DEQ and obtain 

# an DEQ/EPA Identification, .: Number 

# tor each site where hazardous waste is generated. ' " , ,A 'hazardous.wastemanifest is inulticopy shipping: docunient you fill out 

### that accompanies your hazardous waste shipments off-site.

_ , . ( , The manifest.forrnis designed so that shipments· of hazardous waste 

## can betracked. from their point of generation to their final.destination. 'The hazardous waste generator,' the hauler and the designated hazardous waste 

## facility must each sign this docu- '

,. . .. " , :

### NOT(FY 

### menrandkeepacopy.

## 'the'designate~ facility'operatoralso must send a copy back to' the generator to ensure that the shipment arrived. You must keep 

## a: copy of the manifest, which must be signed by the hauler and designated facility, on file for three' 'years. DEQ requires submission of a quarterly report consistingofsummaries of 'wastes manifested, and wastes managed on site.

_-I • ..' 

### RCRA law, along with DEQ regulations, requires you to notify your state DEQ of hazardous waste, activity if in asingle calendar month you produce more, than: ' ·,220 pounds per month of hazardous waste ' '

.. 2.2 pounds per month of acutely hazardous waste • 220 pounds ofspill material' , You can satisfy this requirement by completing and signing the notification form and obtaining ';1 

### DEQ/EPA**Ideritifi~ation** 

### Number. 

# C,'

, TSD 

### (Treatment, ' Storage 

### and Disposal) FACILITIES' 

### TSD facilities are the last step inthe hazardous waste management system. All**T~D's** 

### must registerwith DEQ, obtain a permit 'when necessary, and above all, they-must have a DEQ/EPA Identification Number.

### th~ definition of a TSD encompasses three. different functions: , .

'. Treatment - Any' method, techniql.!.e, or process, including neutralization, 'designed to change the.physical, chemical, or biological character orcomposition of 'any, hazardous waste. ,Treatment can, neutralize the waste, can make itless

hazardous, can recover the raw materials, or can make it safer and easier to transport,**sto~e** 

### or dispose 

# of.

_ Storage - The holding ofhazardous waste for a temporary period, at the end of. ' which.the hazardous waste is treated, disposed or stored elsewhere. '

.

## ~. Disposal - The discharge, deposit, injection, dumping, spilling, leaking.ior

"placing ofany solid waste or hazardous waste into or on any land orwater so that' ',' any part of itmay enter the environment or be emitted intothe air or discharged

.intoany waters.dncluding

### g~ound waters .. " DEQ' , 

### The Oregon Departmentof Environmental Quality. State agency that imple- . " ments regulations dealing with air,and water quality', .hazardous .wastear1d solid waste reduction, recycling and ,disposal. ',EPA 

### The United States Environmental Protection Agency. Thefedetal government ' • agency that oversees environmental regulation nationwide. RCI;fA 

### The Resource Conservation and Recovery Act: Federal legislation passed. in 1976 that initiated regulation of hazardous wastes. This .law is reauthorized every four years and may be amended or changed to broadenthe regulation ofhazardous wastes; , I r-. 

### I I I**~.--** 

### MATERIAL SAFETY 

### DATA SHEET 

## . . .. . 

### Manufacturers are required bylaw to provide material safety data sheets on '- all products they manufacture and sell. These data sheets provide information on the physical, chemical and toxic properties ofthe product. Often they provide information which is useful in evaluating a waste to determine ifit 'is hazardous. ,,'



# . 0' Oregon DEQ ' . 

# gfJ

' . Hazardous waste. Program , ,'811 SW 6th ' 

# . e 

# g Portland, Oregon 97204 . , . (503) 229-5913 

## h •• Toll Free Ic800-452-40l1