Mr. Michael Forbeck 

Bureau of Waste Management 

Pennsylvania Department of Environmental Protection 

400 Waterfront Drive 

Pittsburgh, PA 15222-4745 

Re: Form 26R- Annual Reports 

-

.. 

Derry Township, Westmoreland County 

Dear Mr. Forbeck: 

On behalf of Keystone Clearwater Solutions LLC, ARM Group has prepared the 2010 

calendar year chemical analysis of residual waste annual reports for three (3) well sites in 

Derry Township, Westmoreland County. Enclosed please fmd one copy of the report for 

each site. 

If you have any questions regarding this matter, please contact me at 814-272-0455. 

Sincerely, 

ARM Group Inc. \'-{ -rr!~ 

~Antolick, P.E. 

Project Engineer 

cc: Keystone Clearwater Solutions 

0 

c: 

-i 

:I: 

:Eo 

,.., . 

(j)!""' 

-i.., 

rr1 

C> 

2013 Sandy Drive • Suite 205 • State College, PA 16803 

voice: (814) 272-0455 • fax: (814) 272-0467 • e-mail: info@armgroup.net 
prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

Date Prepared/Revised 

c. Appearance 

2128/11 

Mailing Address 

797 

or Orange, cloudy Odor 

Number of Solid or Liquid Phases of Separation 

10# 

Ext 

Describe each phase of separation . .:..:!.W....--------------- --i 

d. 

e. 

The quality by the 

attached. The EPA approved method to test each analyte is listed on the attached laboratory 

results. Fairway Laboratories is accredited by the Pennsylvania Department of Environmental 

Protection. 

The results of the hazardous waste detennination Is attached. Oil and gas exploration and 

production waste is exempt from regulation as a hazardous waste under Subtitle C of the 

Resource Conservation and Act. 

If applicable, a detailed use of generator knowledge in 

lieu of actual chemical ::.n::alv.~i~ - 1 -

No 

N/A 
c. 

a. 

b. 

c. 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality Lawrence 

Facility Contact Name 

Title 

Solid waste permit 

Facility Name 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

Facility Contact Name 

Title 

Phone 

Volume of waste 

Volume of waste 

N/A 

(check one) 

Email Address 

(check one) 

0 ton (check one) 

- 2. 
(y 

q

and has nQt •119•4. . 

Fonn SubmiUefJ_; 181 Form 26R 

0 Other(spedfY) ---------~--

Date SUtiinltted: 

I certify ~e J~.nnatlc:m required fn Section a.~. Chemical Analy&l.$ was suppll«td· ~ th~ Oepartmenlf9r .,.e year -8010 andh&a not Ch~ · 

Form Stlbnittted: 181 Foim 26R 

D Other(specllfy) ---------~---

Date Subirifu.d1 

I certify the JnfmtJultlol.') required In Section B.-3, Proctess Description and ·sobematlc, was supplied to the O.parbnent 

for ·tl:le year~ 8f1d ~- .not changed. · · · 

Form Subinlttect: (83 f(JMI 268 

D~te 

Subrn~: 

:Name of Responsible Offl~f!IJ 

-Had E. Wehter 

0 other (&peclfy) 

--------------------~-------

TIUe 

Date -II 

- 3 -
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Project: ~ Project Number: [none] 

Collector: JJ 

Number of Containers: 14 

Reported: 

04/01110 09:41 

ANALYTICAL REPORT FOR SAMPLES 

I sample ID 

CONCENTRATE (3/4/10) 

PERMEATE 9DAY 

Laboratory ID 

OC08045-01 

OC08045-02 

Matrix 

Water 

Water 

Date Sampled Date Received 

03/04/10 10:00 03/08/10 09:15 

03/04110 10:00 03/08/10 09:15 

OC08045-01 MBAS: Sample was received beyond the EPA recommended hold time. 

OC08045-01 

Test 

Gross Alpha 

Gross Beta 

Radium 226 

Radium 228 

Uncert. 

+/- 438.0 

+/-165.2 

+/- 24.89 

+/- 80.82 

Fairway Laboratories, Inc. 

~Submitted by: 

Michael P. Tyler 

Laboratory Director 

The results m this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced m its entirety. 

Page 1 of 10 
p 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Client Sample ID: CONCENTRATE (3/4/10) 

Laboratory Sample ID: 

Analyte Result 

Metals by EPA 200 Series Methods 

Silver <2.00 

Aluminum <25.0 

Arsenic <2.00 

Boron 9.69 

Barium 1710 

Beryllium <0.500 

Calcium 4770 

Cadmium <1.00 

Cobalt <5.00 

Chromium 0.866 

Copper <5.00 

Iron 121 

Mercury <0.00100 

Lithium 12.3 

Magnesium 8ll 

Manganese 8.84 

Molybdenum <5.00 

Sodium 6070 

Nickel <5.00 

Lead <1.00 

Fairway Laboratories, Inc. 

Project: TIOGA 

Project Number: [none] 

Collector: JJ 

Reported: 

04/01/10 09:41 

Number of Containers: 14 

Date/Time Sampled: 03/04/10 10:00 

OC08045-01 (Water) 

Laboratory 

Reporting Date/Time 

Limit Units Analyzed Method Analyst 

2.00 mg/1 03/10/10 15:31 EPA200.7 rb 

25.0 mg/1 03/10/10 15:30 EPA200.7 rb 

2.00 mgll 03/10/10 15:31 EPA200.7 rb 

5.00 mgll 03/10/10 15:31 EPA200.7 rb 

50.0 mgll 03/10/10 15:43 . EPA200.7 rb 

0.500 mg/1 03/10/10 15:31 EPA200.7 rb 

50.0 mg/1 03/10/10 15:30 EPA200.7 rb 

1.00 mg/1 03/10/10 15:31 EPA200.7 rb 

5.00 mg/1 03/10/10 15:31 EPA200.7 rb 

0.500 mg/1 03/10/10 15:31 EPA200.7 rb 

5.00 mg/1 03/10/10 15:31 EPA200.7 rb 

5.00 mg/1 03/10/10 15:30 EPA200.7 rb 

0.00100 mgll 03/12/10 08:29 EPA245.l cb 

0.500 mg/1 03/15/10 21:59 EPA200.7 sub 

50.0 mg/1 03/10/10 15:30 EPA200.7 rb 

5.00 mg/1 03/10/10 15:31 EPA200.7 rb 

5.00 mg/1 03/10/10 15:31 EPA200.7 rb 

100 mg/1 03/10/10 15:31 EPA200.7 rb 

5.00 mg/1 03/l 0/10 15:31 EPA200.7 rb 

1.00 mg/1 03/10/10 15:31 EPA200.7 rb 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. Thrs analyllcalreport must be reproduced in its entirety. 

Note 

SCI 

Page 2 of 10 
M Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Client Sample ID: CONCENTRATE (3/4/10) 

Laboratory Sample ID: 

Analyte Result 

Metals by EPA 200 Series Methods 

Selenium <5.00 

Strontium 1090 

Zinc <5.00 

Metals (Dissolved) by EPA 200 Series Methods 

Iron, Dissolved 98.4 

Volatile Organic Compounds by EPA Method 8260B 

Benzene <50.0 

Toluene <50.0 

Surrogate: 4-Bromofluorobenzene 98.9% 

Surrogate: /,2-Dich/oroethane-d4 107% 

Surrogate: Fluorobenzene 107% 

Conventional Chemistry Parameters by SM!EPA Methods 

Acidity -710 

Total Alkalinity 1050 

Biochemical Oxygen Demand 1180 

Cyanide (total) 0.100 

Chemical Oxygen Demand 5870 

Specific Conductance (EC) 49100 

Total Hardness 22000 

Fairway Laboratories, Inc. 

Project: TIOGA 

Project Number: [none] Reported: 

Collector: JJ 04/01/10 09:41 

Number of Containers: 14 

Date/Time Sampled: 03/04/10 10:00 

OC08045-01 (Water) 

Laboratory 

Reporting Date/Time 

Limit Units Analyzed Method Analyst 

5.00 mg/1 03/10/10 15:31 EPA200.7 rb 

10.0 mg/1 03/10/10 15:44 EPA200.7 rb 

5.00 mgll 03/10/10 15:31 EPA200.7 rb 

1.00 mg/1 03/15/10 14:38 EPA200.7 rb 

50.0 ug/1 03/09/10 01:00 EPA8260B wm 

50.0 ug/1 03/09/10 01:00 EPA8260B wm 

70-130 03109110 OJ.·OO EPA8260B wm 

70-130 03109110 01:00 EPA8260B wm 

70-130 03109110 01:00 EPA 8260B wm 

-10000 mg/1 03/10/10 08:11 SM2310B jf 

10.0 mg/1 03/09/10 16:53 SM2320B jf 

240 mg/1 03/08/10 13:28 SM5210B SP 

0.100 mg/1 03/15/10 08:30 SM SP 

4500-CN-C+E 

150 mg/1 03/10/10 12:40 EPA410.4 bw 

2.00 umbos/em 03/09/10 14:55 SM2510B bw 

1000 mg/1 03/11/10 17:17 SM2340C JG 

The results m this report apply to the samples analyzed m accordance with the cham of 

custody document. This analytical report must be reproduced in its entirety. 

Note 

LIO 

LIO 

H2 

Page 3 of 10 
G

oup 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Client Sample ID: CONCENTRATE (3/4/10) 

Laboratory Sample ID: 

Analyte Result 

Conventional Chemistry Parameters by SMIEPA Methods 

Methylene Blue Active Substances <1.00 

Nitrate as N <50.0 Nitrite as N <10.0 

Oil & Grease 9.02 

pH 6.72 

Phenolics <0.0500 

Total Dissolved Solids 42600 Total Suspended Solids 105 

Total Kjeldahl Nitrogen 1120 

Anions by EPA Method 300.0 

Bromide 179 

Chloride 19900 

Sulfate as S04 163 

Physical Parameters by APHA/ASTMIEPA Methods 

AmmoniaasN 21.6 

Gross Alpha- Radiological Suite 3020 

Gross Beta- Radiological Suite 1130 

Subcontracted Analyses 

Fairway Laboratories, Inc. 

Project: TIOGA 

Project Number: [none] 

Collector: JJ 

Number of Containers: 14 

Date/Time Sampled: 

OC08045-01 (Water) 

Laboratory 

Reporting Date/Time 

Limit Units Analyzed 

Reported: 

04/01/10 09:41 

03/04/10 10:00 

Method Analyst Note 

1.00 mg/1 03/11/10 08:00 SM5540C EB L6,MS 

50.0 mg/1 03/08/10 12:50 EPA300.0 BW H2 

10.0 mg/1 03/08/10 12:50 EPA300.0 BW H2 

8.35 mg/1 03/11/10 16:27 EPA 1664A JG 

pH Units 03/08/10 17:20 SM4500H+B MC H2 

0.0500 mg/1 03/11/10 17:24 EPA420.1 jf 

40.0 mg/1 03/08/10 14:00 SM2540C b1 4.00 mg/1 03/09/10 09:15 SM2540D bl 

40.0 mg/1 03/13/10 10:54 SM4500Norg MT 

c 

10.0 mg/1 03/08/10 12:50 EPA300.0 BW 

2500 . mg/1 03/08/10 13:05 EPA300.0 BW 

50.0 mg/1 03/08/10 12:50 EPA300.0 BW 

1.00 mg/1 03/13/10 13:31 ASTM MT 

06919-03 

482 pCi!L 03/18/10 00:00 EPA900.0 sub SC2 

376 pCi!L 03/18/10 00:00 EPA900.0 sub SC2 

The results in th1s report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced in its entirety. 

Page 4 of 10 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Client Sample ID: CONCENTRATE (3/4/10) 

Laboratory Sample ID: 

Analyte Result 

Subcontracted Analyses 

Ethylene glycol 16.3 

Radium 226 658 

Radium 228 222 

Thorium <0.250 

Uranium <170 

Fairway Laboratories, Inc. 

Project: TIOGA 

Project Number: [none] 

Collector: JJ 

Number of Containers: 14 

Reported: 

04/01110 09:41 

Date/Time Sampled: 03/04/10 10:00 

OC08045-01 (Water) 

Laboratory 

Reporting Date/ Time 

Limit Units Analyzed Method Analyst 

10.0 mg/1 03/18/10 21:15 EPA8015M sub 

97.2 pCi!L 03/26/10 00:00 EPA903.0 sub 

97.9 pCi!L 03/18/10 16:00 EPA904.0 sub 

0.250 mg/1 03/16/10 00:00 EPA200.8 sub 

170 pCi!L 03/16/10 00:00 SM 7500-U sub 

A-B 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced in its entirety. 

Note 

SCI SC2 SC2 

MS,SC2 

Al,SC2 

Page 5 of 10 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Client Sample ID: PERMEATE 9 DAY 

Laboratory Sample ID: 

Analyte Result 

Metals by EPA 200 Series Methods 

Barium 370 

Calcium 1360 

Iron 5.18 

Magnesium 67.0 

Strontium 203 

Conventional Chemistry Parameters by SMIEPA Methods 

pH 7.49 

Total Dissolved Solids 30600 

Anions by EPA Method 300.0 

Chloride 17600 

Sulfate as S04 <50.0 

Fairway Laboratories, Inc. 

Project: TIOGA 

Project Number: [none] 

Collector: JJ 

Number of Containers: 14 

Date/Time Sampled: 

OC08045-02 (Water) 

Laboratory 

Reporting Date I Time 

Limit Units Analyzed 

10.0 mg/1 03/10/l 0 15:53 

10.0 mg/1 03/10/10 15:47 

1.00 mg/1 03/10/10 15:47 

10.0 mg/1 03/10/10 15:47 

2.00 mg/1 03/10/10 15:55 

pH Units 03/08/10 17:20 

10.0 mg/1 03/08/10 14:00 

2500 mg/1 03/08/10 13:35 

50.0 mg/1 03/08/10 13:20 

Reported: 

04/01110 09:41 

03/04/10 10:00 

Method Analyst 

EPA200.7 rb 

EPA200.7 rb 

EPA200.7 rb EPA200.7 rb EPA200.7 rb 

SM4500H+B MC 

SM2540C bl 

EPA300.0 BW EPA300.0 BW 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced in its entirety. 

Note 

H2 

Page 6 of 10 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Kim Nelson 

Notes 

Project: 

Project Number: 

Collector: 

Number of Containers: 

SC2 This analysis was subcontracted to BenchMark Analytical, ID# 09-00944. 

SC 1 This analysis was subcontracted to Analytical Laboratory Services, Inc, !D# 22-00293. 

TIOGA 

[none] 

JJ 

14 

MS The spike recovery was outside acceptance limits for the MS and/or MSD due to sample matrix interferences. The batch 

was accepted based on acceptable CCV recovery. 

L6 MBAS, calculated as LAS, mol wt 320 

L I 0 This sample was analyzed at a dilution due to the matrix. Reporting limits were adjusted accordingly. 

H2 This sample was received beyond the EPA recommended holding time. 

AI Due to matrix effects, not all quality control parameters met acceptance criteria SUB 

Reported: 

04/01110 09:41 

Fairway Laboratories, Inc. The results m this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytiCal report must be reproduced in its entirety. 

Page 7 of 10 
2 

••• • •• FAIRWAY LABORATORIES CIL\1!\ <)F CUSTODY/ 

REQLEST FOR ,.\l\.\LYSIS - •. • Enviro-ntal Laborruory 

••• 

2019 9th Ave. 

P.O. Box 1925 

Altoona, PA 16602 

Please print. See back of COC for instructions/terms and conditions. 

Client Name: AI-M {lrt~p Int. Rec:eivlae Info y N Please Circle Program Analyses Requested 

Address: ;).()u 5"'".!.y br•"« ~"'~~ »~ Custody seals ACfll 

~' 'r' , 

Seals Intact? CERCLA 

S-t..~ (a''fgc PA lb~O.~ Received on ice? RCRA 

' s . Contact: ~·- ~llfl!f\ COC/Labels aan:e? NPDES 

Zl'1-~)') • o 'i~ ~ ~ ~ ) SDWA Phone#: Correct containers? CWA ~ &;;, 

Fax#: ~~ ... ~ l"'}- QY\.f Correct pn:servation? 

J~, J ~ ~ ~jectName: \0)~" E.•>'t..._OoYt SH VOA head space? Matrix 

.! <\.::: •01 .... 

Quote/PO#: Sample Temp: .i 

f! 

TAT: Normal 0 Rush]( iJJ t t c. 

Reportable to PADEP? E 

e = .Si h 

Rush TAT subject ! to pre-approval and sun:harge. Yes 0 t,.) 

Date Required: .A~r, I PWSID# ~ 1:1 ~ 1 ~ ""' ~ 'f 1! ~ a \JjJ ~ ~ (L 

FLI use only Sample Description/Location Sample Date !sample Time = ~ 'S 

c;!l ~ ,.., t ..,.....,. 

OCbftNS Cont:(tlfr.J-t I.J1"1Jrt>' ll C,Jit> I DOD . I& ;.,; ~ Ill I~ / 

1>1 r,r~...u 1 6.: . JJ~IIO 1000 ~~ fr; l'e= ')( ~!!!~ .;: . ~ -~ 

.. . .. IJ~·::~ 11: ... .. 

.. .· ' ~ ~ . } _ w. lf.. ""f • ~ __ l . ... ' -·. · ~ "· I ~~: .. ~ 

, .. ' ' J 

!i ·;·.,. '· ' ~ J· •J li ·: 11 ~~ ~ ' .. t .. ~ . ·, • •A . , I . . .. "' ~ & • , ~ 

~· . . .. ~~.1.'. ·"' f-i,·,l t ~t· ., . ... . t~· 

- ~c "" ..... 1 

·~ f: · .. . 1-1~, 

\ Y7~ 

By relinquishing my sample Signature Date nme Remarks 

to Fairway Laboratories, Samoled bv: J ~ IJJ.fn" t)1.aGL) 

Inc., I hereby agree to the Received by: ... tenns and conditions printed Relinquished by: N.\... I'J,~<f 1'/F\" u "'"")_ Received by: /. r"" • on the reverse.* Relinquished by: / f u IJ'J "'"' ~ 

Received by: ~ 1..7 Jf'-" -, ,, ..) :J•c_ 

White Original - FLI File Canary - Customer Mailing/Report Pink - Customer Receipt Copy 

1 

Phone: (814)946-4306 

Fax: (814)946-8791 

Page___i of _I 

Bottle Type/Comments 

0 

rl 

4-1 

0 

co 

Q) 

01 

cu 

0.. 
the Eaglehouse 5H well pad. The sampling of flow back water at the site consisted of collecting 

grab samples of the material and placing the samples into laboratory provided glassware. A total 

of fourteen (14) representative samples were collected. Samples were collected by personnel 

wearing a clean pair of nitrile gloves for each sampling area to minimize sample cross 

contamination. 

The samples of the flow back water were submitted to Fairway Laboratories of Altoona, 

Pennsylvania for analysis of the appropriate Form 26R constituents. A complete list of analyses 

is attached. The analytical results for the samples are representative the quality of the fluids 

generated during well drilling activities at the McCullough property. 
Flow Back 

Tanks 

Clearwater Treated Water 

Nanofiltration Tanks 

Concentrate 

Concentrate 

Tank 

r 

To Offsite Treatment Facility 

Process Description: A mobile filtration unit was utilized to filter flow back water from 

fracturing of natural gas wells. Filtered water was reused and "concentrate" from the filtering 

process was hauled off-site to a permitted brine water treatment facility.