ARM Group Inc. Earth Resource Engineers
and Consultants February
28, 2011 Mr. Michael Forbeck Bureau
of Waste Management Pennsylvania Department

of Environmental Protection 400 Waterfront Drive Pittsburgh,
PA 15222-4745

Re: Form 26R- Annual Reports

- .. Derry Township, Westmoreland County Dear Mr. Forbeck: On behalf of Keystone Clearwater Solutions LLC, ARM Group has prepared the 2010 calendar year chemical analysis
of residual waste annual reports for three (3) well sites in Derry Township, Westmoreland County. Enclosed please fmd one copy of the report for each site. If you have any questions regarding this matter, please contact me at 814-272-0455. Sincerely, ARM Group Inc. \'-{ **-rr!~ ~Antolick,** 

P.E. Project Engineer cc: Keystone Clearwater Solutions

(j) 0 c: -i :I: :Eo ,..,
. (j)!""' -i.., rr1 C> 2013 Sandy Drive

• Suite 205

• State College,

PA 16803 voice: (814) 272-0455

• fax: (814) 272-0467

• e-mail: info@armgroup.net**2540-PM-~WM0347**

Rev. 1/2011 p **~!!~~~!'!!~,** COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT

OF ENVIRONMENTAL PROTECTION BUREAU
OF WASTE MANAGEMENT FORM 26R CHEMICAL ANALYSIS

OF RESIDUAL WASTE ANNUAL REPORT
BY THE GENERATOR typed or legibly printed

in the spaces provided.

If additional space

is necessary, identify

l olrte'Re:;:v:d each attached sheet as Fonn 26R, reference
the item number and identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised c. Appearance 2128/11

Mailing Address 797 or Orange, cloudy

Odor Number

of Solid or Liquid Phases
of Separation

10# Ext Describe each phase of separation

. .:..:!.W....------------

--

- --i d. e. The quality

by the attached.
The EPA approved method

to test each analyte

is listed on the attached laboratory results. Fairway Laboratories

is accredited

by the Pennsylvania Department

of Environmental Protection. The results
of the hazardous waste detennination

Is attached.

Oil and gas exploration and production waste

is exempt from regulat

i on as a hazardous waste under Subt

i tle C of the Resource Conservation
and
Act. If applicable,

a detailed

use of generator knowledge

in lieu of actual chemical **::.n::alv.~i~**

- 1 -

No N/A2540-PM-BWM0347

Rev. 1/2011 b. c. c. a. b. c. description

of manufacturing and/or pollution control processes producing the waste,
as specified

in the instructions,

is attached. schematic

of the manufacturing and/or pollution control processes producing
the waste, as specified

in the Instructions,

is attached. If portions

of the information submitted
are confidential,

the substantiation

for a confidentiality claim, as described

in the instructions,

Is attached. Address Line

1 Address Line

1 Address City State ZIP Municipality

Lawrence Facility Contact Name Title Solid waste permit Facility Name Address Line

1 Address Line

1 Address City State ZIP Municipality Facility Contact Name Title Phone Volume
of waste Volume
of waste N/A

(check one) Email Address
(check one) 0 ton (check one) - 2.

No N/A

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# 181 Form 26R 

# 0 Other(spedfY) 

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and



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# -II - 3 -FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306

(814) 946-8791-

Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Kim Nelson

••• e

·. FAIRWAY LABORATORIES ·. .- •• Project: **~** Project Number: [none] Collector:

JJ Number
of Containers:

14 Reported

: 04/01110 09:41 ANALYTICAL REPORT FOR SAMPLES I sample
ID CONCENTRATE (3/4/10) PERMEATE 9DAY Laboratory

ID OC08045-01 OC08045-02 Matrix Water Water

Date Sampled

Date Received 03/04/10 10:00 03/08/10

09

: 15 03/04110 10:00 03/08/10

09

: 15 OC08045-01 MBAS: Sample was rece

i ved beyond the EPA recommended
hold time. OC08045-01 Test Gross Alpha Gross Beta Radium 226 Radium 228 Uncert

. +/- 438.0 +/-165.2 +/- 24

. 89 +/- 80.82 Fairway Laboratories,

Inc

. **~Submitted**

by: Michael

P. Tyler Laboratory Director

The results

m this report apply
to the sample

s analyzed

in accordance with the chain of custody document. This analytical report must be reproduced

m its entirety. Page

1 of 10FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306

(814) 946-8791-

Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Kim Nelson Client Sample ID: CONCENTRATE (3/4/10) Laboratory Sample ID: Analyte

Result Metals by EPA 200 Series Methods Silver

<2.00 Aluminum

<25.0 Arsenic

<2.00 Boron

9.69 Barium

1710 Beryllium

<0.500 Calcium

4770 Cadmium

<1.00 Cobalt

<5.00 Chromium

0.866 Copper

<5.00 Iron

121 Mercury

<0.00100 Lithium

12.3 Magnesium

8ll Manganese

8.84 Molybdenum

<5.00 Sodium

6070 Nickel

<5.00 Lead

<1.00 Fairway Laboratories

, Inc

.

••• •

•• FAIRWAY LABORATORIES ·. .- •• Project: TIOGA Project Number: [none] Collector:

JJ Reported: 04/01/10 09:41 Number
of Containers:

14 Date/Time Sampled: 03/04/10 10:00 OC08045-01 (Water) Laboratory Reporting Date/Time Limit Units Analyzed Method Analyst 2.00 mg/1 03/10/10 15:31 EPA200.7

rb 25.0 mg/1 03/10/10 15:30 EPA200.7

rb 2

. 00 mgll 03/10/10 15:31 EPA200.7

rb 5

. 00 mgll 03/10/10 15:31 EPA200.7

rb 50.0 mgll 03/10/10 15:43

. EPA200.7

rb 0.500 mg/1 03/10/10 15:31 EPA200.7

rb 50.0 mg/1 03/10/10 15:30 EPA200.7

rb 1.00 mg/1 03/10/10 15:31 EPA200.7

rb 5.00 mg/1 03/10/10 15:31 EPA200.7

rb 0.500 mg/1 03/10/10 15:31 EPA200.7

rb 5.00 mg/1 03/10/10 15:31 EPA200.7

rb 5.00 mg/1 03/10/10 15:30 EPA200.7

rb 0.00100
mgll 03/12/10

08

: 29 EPA245.l

cb 0

. 500 mg/1 03/15/10 21:59 EPA200.7

sub 50.0 mg/1 03/10/10

15

: 30 EPA200.7

rb 5.00 mg/1 03/10/10 15:31 EPA200.7

rb 5.00 mg/1 03/10/10 15:31 EPA200.7

rb 100 mg/1 03/10/10 15:31 EPA200.7

rb 5

. 00 mg/1
03/l 0/10 15:31 EPA200.7

rb 1.00 mg/1 03/10/10 15:31 EPA200.7

rb The results

in this report apply
to the samples analyzed

in accordance with the chain of custody document. Thrs analyllcalreport
must be reproduced

in its entirety

. Note SCI Page

2 of 10FAIRWAY lABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306

(814) 946-8791-

Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Kim Nelson Client Sample ID: CONCENTRATE (3/4/10) Laboratory Sample ID: Analyte

Result Metals by EPA 200 Series Methods Selenium

<5.00 Strontium

1090 Zinc

<5.00 Metals (Dissolved)

by EPA 200 Series Methods Iron, Dissolved

98.4 Volatile Organic Compounds

by EPA Method 8260B Benzene

<50.0 Toluene

<50.0 Surrogate: 4-Bromofluorobenzene

98.9% Surrogate: /,2-Dich/oroethane-d4

107% Surrogate

: Fluorobenzene

107% Conventional Chemistry Parameters

by SM!EPA Methods Acidity

-710 Total Alkalinity

1050 Biochemical Oxygen Demand

1180 Cyanide (total)

0.100 Chemical Oxygen Demand

5870 Specific Conductance (EC)

49100 Total Hardness

22000 Fairway Laboratories,

Inc

.

••• e

•. FAIRWAY LABORATORIES ·. .- •• Project: TIOGA Project Number: [none] Reported: Collector:

JJ 04/01/10 09:41 Number
of Containers:

14 Date/Time Sampled: 03/04/10 10:00 OC08045-01 (Water) Laboratory Reporting Date/Time Limit Units Analyzed Method Analyst 5.00 mg/1 03/10/10 15:31 EPA200.7

rb 10.0 mg/1 03/10/10 15:44 EPA200.7

rb 5.00 mgll 03/10/10 15:31 EPA200.7

rb 1.00 mg/1 03/15/10 14:38 EPA200

. 7

rb 50.0 ug/1 03/09/10 01:00 EPA8260B

wm 50.0 ug/1 03/09/10 01:00 EPA8260B

wm 70-130 03109110 OJ.·OO EPA8260B

wm 70-130 03109110

01

: 00 EPA8260B

wm 70-130 03109110 01:00 EPA 8260B
wm -10000 mg/1 03/10/10 08:11 SM2310B

jf 10

. 0 mg/1 03/09/10 16:53 SM2320B

jf 240 mg/1 03/08/10 13:28 SM5210B

SP 0.100 mg/1 03/15/10 08:30

SM

SP 4500-CN-C

+ E 150 mg/1 03/10/10 12:40 EPA410.4

bw 2.00 umbos/em 03/09/10 14:55 SM2510B

bw 1000 mg/1 03/11/10 17:17 SM2340C

JG The results

m this report apply
to the

s amples analyzed

m accordance with the cham of custody document. This analytical report must be reproduced

i n its entirety.

Note LIO LIO H2 Page

3 of 10FAIRWAYLABORATORIES2019NinthAvenuePOBox1925Altoona,Pennsylvania16603(814)946-4306(814)946-8791-FaxARMGroup2013SandyDrive,Suite205StateCollegePA,16803ProjectManager:KimNelsonClientSampleID:CONCENTRATE(3/4/10)LaboratorySampleID:AnalyteResultConventionalChemistryParametersbySMIEPAMethodsMethyleneBlueActiveSubstances<1.00NitrateasN<50.0NitriteasN<10.0Oil&Grease9.02pH6.72Phenolics<0.0500TotalDissolvedSolids42600TotalSuspendedSolids105TotalKjeldahlNitrogen1120AnionsbyEPAMethod300.0Bromide179Chloride19900SulfateasS04163PhysicalParametersbyAPHA/ASTMIEPAMethodsAmmoniaasN21.6GrossAlpha-RadiologicalSuite3020GrossBeta-RadiologicalSuite1130SubcontractedAnalysesFairwayLaboratories,Inc.•••e•.FAIRWAYLABORATORIES·..-••Project:TIOGAProjectNumber: [none]Collector:JJNumberofContainers:14Date/TimeSampled:OC08045-01(Water)LaboratoryReportingDate/TimeLimitUnitsAnalyzedReported:04/01/1009:4103/04/1010:00MethodAnalystNote1.00mg/103/11/1008:00SM5540CEBL6,MS50.0mg/103/08/1012:50EPA300.0BWH210.0mg/103/08/1012:50EPA300.0BWH28.35mg/103/11/1016:27EPA1664AJGpHUnits03/08/1017:20SM4500H+BMCH20.0500mg/103/11/1017:24EPA420.1jf40.0mg/103/08/1014:00SM2540Cb14.00mg/103/09/1009:15SM2540Dbl40.0mg/103/13/1010:54SM4500NorgMTc10.0mg/103/08/1012:50EPA300.0BW2500.mg/103/08/1013:05EPA300.0BW50.0mg/103/08/1012:50EPA300.0BW1.00mg/103/13/1013:31ASTMMT06919-03482pCi!L03/18/1000:00EPA900.0subSC2376pCi!L03/18/1000:00EPA900.0subSC2Theresultsinth1sreportapplytothesamplesanalyzedinaccordancewiththechainofcustodydocument.Thisanalyticalreportmustbereproducedinitsentirety.Page4of10FAIRWAYLABORATORIES2019NinthAvenuePOBox1925Altoona,Pennsylvania16603(814)946-4306(814)946-8791-FaxARMGroup2013SandyDrive,Suite205StateCollegePA,16803ProjectManager:KimNelsonClientSampleID:CONCENTRATE(3/4/10)LaboratorySampleID:AnalyteResultSubcontractedAnalysesEthyleneglycol16.3Radium226658Radium228222Thorium<0.250Uranium<170FairwayLaboratories,Inc.•••e·.FAIRWAYLABORATORIES·..-••Project:TIOGAProjectNumber:[none]Collector:JJNumberofContainers:14Reported:04/0111009:41Date/TimeSampled:03/04/1010:00OC08045-01(Water)LaboratoryReportingDate/TimeLimitUnitsAnalyzedMethodAnalyst10.0mg/103/18/1021:15EPA8015Msub97.2pCi!L03/26/1000:00EPA903.0sub97.9pCi!L03/18/1016:00EPA904.0sub0.250mg/103/16/1000:00EPA200.8sub170pCi!L03/16/1000:00SM7500-UsubA-BTheresultsinthisreportapplytothesamplesanalyzedinaccordancewiththechainofcustodydocument.Thisanalyticalreportmustbereproducedinitsentirety.NoteSCISC2SC2MS,SC2Al,SC2Page5of10FAIRWAYLABORATORIES2019NinthAvenuePOBox1925Altoona,Pennsylvania16603(814)946-4306(814)946-8791-FaxARMGroup2013SandyDrive,Suite205StateCollegePA,16803ProjectManager:KimNelsonClientSampleID:PERMEATE9DAYLaboratorySampleID:AnalyteResultMetalsbyEPA200SeriesMethodsBarium370Calcium1360Iron5.18Magnesium67.0Strontium203ConventionalChemistryParametersbySMIEPAMethodspH7.49TotalDissolvedSolids30600AnionsbyEPAMethod300.0Chloride17600SulfateasS04<50.0FairwayLaboratories,Inc.•••e·.FAIRWAYLABORATORIES·..-••Project:TIOGAProjectNumber:[none]Collector:JJNumberofContainers:14Date/TimeSampled:OC08045-02(Water)LaboratoryReportingDateITimeLimitUnitsAnalyzed10.0mg/103/10/l015:5310.0mg/103/10/1015:471.00mg/103/10/1015:4710.0mg/103/10/1015:472.00mg/103/10/1015:55pHUnits03/08/1017:2010.0mg/103/08/1014:002500mg/103/08/1013:3550.0mg/103/08/1013:20Reported:04/0111009:4103/04/1010:00MethodAnalystEPA200.7rbEPA200.7rbEPA200.7rbEPA200.7rbEPA200.7rbSM4500H+BMCSM2540CblEPA300.0BWEPA300.0BWTheresultsinthisreportapplytothesamplesanalyzedinaccordancewiththechainofcustodydocument.Thisanalyticalreportmustbereproducedinitsentirety.NoteH2Page6of10•••e·.FAIRWAYLABORATORIES2019NinthAvenueFAIRWAYLABORATORIESPOBox1925Altoona,Pennsylvania16603(814)946-4306(814)946-8791-FaxARMGroup2013SandyDrive,Suite205StateCollegePA,16803ProjectManager:KimNelsonNotesProject:ProjectNumber:Collector:NumberofContainers:SC2ThisanalysiswassubcontractedtoBenchMarkAnalytical,ID#09-00944.SC1ThisanalysiswassubcontractedtoAnalyticalLaboratoryServices,Inc,!D#22-00293.·..-••TIOGA[none]JJ14MSThespikerecoverywasoutsideacceptancelimitsfortheMSand/orMSDduetosamplematrixinterferences.ThebatchwasacceptedbasedonacceptableCCVrecovery.L6MBAS,calculatedasLAS,molwt320LI0Thissamplewasanalyzedatadilutionduetothematrix.Reportinglimitswereadjustedaccordingly.H2Thissamplewasreceivedbeyond theEPArecommendedholdingtime.AIDuetomatrixeffects,notallqualitycontrolparametersmetacceptancecriteriaSUBReported:04/0111009:41FairwayLaboratories,Inc.Theresultsmthisreportapplytothesamplesanalyzedinaccordancewiththechainofcustodydocument.ThisanalytiCalreportmustbereproducedinitsentirety.Page7of102

••• • •• FAIRWAY LABORATORIES CIL\1!\ <)F CUSTODY / REQLEST FOR ,. \l\ . \LYSIS

- •. • Enviro-ntal Laborruory •••

2019 9th Ave. P.O. Box 1925 Altoona, PA 16602 Please print. See back of COC for instructions/terms and conditions. Client Name: AI-M **{lrt~p** Int. Rec:eivlae Info y N Please Circle Program Analyses Requested Address: ;).()u 5"'".!.y br•"« **~"'~~ »~**  Custody seals ACfll **~'** 'r' ,

Seals Intact? CERCLA **S-t..~** (a''fgc PA **lb~O.~** Received on ice? RCRA ' s . Contact: **~·- ~llfl!f\**  COC/Labels aan:e? NPDES **~ ~**  **~** )

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**'i~** SDWA Phone#: Correct containers? CWA **~** &;;, **~~** ...

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**.A~r,** I PWSID# 'f 1! **~** a **\JjJ ~**  **~** (L FLI use only Sample Description/Location Sample Date !sample Time = **~** 'S c;!l **~** ,.., t ..,.....,. OCbftNS Cont:(tlfr.J-t I.J1"1Jrt>' ll C,Jit> I DOD . I&

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**~** IJJ.fn" t)1.aGL) Inc., I hereby agree to the Received by: ... tenns and conditions printed Relinquished by: N.\...

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Phone: (814)946-4306 Fax: (814)946-8791 Page___i of _I Bottle Type/Comments

0 rl 4-1 0 co Q) 01 cu 0..Form 26R: Chemical Analysis

of Residual Waste Annual Report by the Generator Flow Back Water Sampling Methods Narrative Flow back water samples were collected
on March

4, 2010 from the concentrate tank staged

at the Eaglehouse

5H well pad. The sampling

of flow back water
at the site consisted

of collecting grab samples
of the material and placing the samples into laboratory provided glassware.

A total of fourteen (14) representative samples were collected. Samples were collected
by personnel wearing

a clean pair of nitrile gloves for each sampling area to minimize sample cross contamination. The samples
of the flow back water were submitted

to Fairway Laboratories

of Altoona, Pennsylvania

for analysis
of the appropriate Form 26R constituents.

A complete
list of analyses is attached. The analytical results for the samples are representative

the quality of the fluids generated during well drilling activities

at the McCullough property.Water Treatment Schematic and Process Description

· for Marcellus Shale Flowback Fluid Wells
J Flow Back Tanks Clearwater Treated Water Nanofiltration

Tanks Concentrate Concentrate Tank

r To Offsite Treatment Facility Process Description:

A mobile filtration unit was utilized

to filter flow back water from fracturing

of natural gas wells. Filtered water was reused and "concentrate" from the filtering process was hauled off-site

to a permitted brine water treatment facility.