Product Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Print Date: 02 Nov 2009

®(TM)*Trademark of The Dow Chemical Compan y ("Dow") or an affiliated company of Dow

Page 1 of 13 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the docu ment. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or

actions.



## 1. Product and Company Identification

Product Name STYROFOAM(TM) RS 2045 Polyol

COMPANY IDENTIFICATION The Dow Chemical Company

2030 Willard H. Dow Center
Midland, MI 48674

USA

Customer Information Number: 800-258-2436



### EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 989-636-4400 Local Emergency Contact: 989-636-4400



## 2. Hazards Identification

Emergency Overview

Color: Blue Physical State: Liquid.

Odor: Amine. Hazards of product:

WARNING! Harmful if swallowed. Causes eye irritation. Causes skin irritation. Causes respiratory tract irritation. May cause skin irritation. May be harmful if absorbed through skin. May be harmful if inhaled. Vapor reduces oxygen available for breathing. May cause central nervous system effects. May cause anesthetic effects. May cause central nervous system effects; may cause respiratory tract irritation. Isolate area. Keep upwind of spill. Highly toxic to fish and/or other aquatic organisms.



### OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29

CFR 1910.1200. 

# Material Safety Data Sheet

The Dow Chemical CompanyProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 2 of 13 

### Potential Health Effects Eye Contact: May cause severe eye irritation. May cause corneal injury. Vapor of amines may cause swelling of the cornea resulting in visual disturbances such as blurred or hazy vision. Bright lights may appear to be surrounded by halos. Effects may be delayed and typically disappear spontaneously.

Skin Contact: Prolonged contact may cause severe skin irritation with local redness and discomfort. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Repeated skin contact may result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potentially lethal amounts.

Inhalation: Prolonged excessive exposure may cause adverse effects. In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. May cause respiratory irritation and central nervous system depression. Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Excessive exposure may cause severe irritation to upper respiratory tract (nose and throat) and lungs. Ingestion: Oral toxicity is expected to be moderate in humans due to diethylene glycol even though tests with animals show a lower degree of toxicity. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause serious injury, even death. May cause nausea and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Effects of Repeated Exposure: Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and symptoms of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Contains component(s) which have been reported to cause effects on the following organs in animals: Liver. Heart. Respiratory tract. Central nervous system. Bladder. Contains component(s) which have been reported to cause effects on the following organs in humans: Kidney. Gastrointestinal

tract. Birth Defects/Developmental Effects: Contains component(s) which did not cause birth defects in animals; other fetal effects occurred only at doses toxi c to the mother. Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic, high doses in animals. Other animal studies have not reproduced birth defects even at much higher doses that caused severe maternal toxicity. Reproductive Effects: In animal studies on component(s), effects on reproduction were seen only at doses that produced significant toxicity to the parent animals. Diethylene glycol did not interfere with reproduction in animal studies except at very high doses.



### Component CAS # Amount

1,4-Benzenedicarboxylic Acid, Dimethyl Ester, manuf. of, by-products from, Polymers with Diethylene Glycol 70749-97-2 >= 30.0 - <= 60.0 %

Phenol, polymer with formaldehyde , propylene oxide and ethylene oxide 25134-86-5 >= 10.0 - <= 30.0 %

1,1,1,3,3 - Pentafluoropropane 460-73-1 >= 10.0 - <= 30.0 % Triethyl phosphate 78-40-0 >= 5.0 - <= 10.0 % Diethylene glycol 111-46-6 >= 5.0 - <= 10.0 % 2-(2-Hydroxyethoxy)ethyl-2-hydroxypropyl-3,4,5,6- tetrabromo phthalate 20566-35-2 >= 3.0 - <= 7.0 %

Nonylphenol diethanolamine Mannich base, propylene oxide, ethylene oxide polymer 52019-35-9 >= 1.0 - <= 5.0 %

N,N-Dimethylcyclohexylamine 98-94-2 >= 1.0 - <= 5.0 % Tris(dimethylamino)propyl amine 33329-35-0 >= 1.0 - <= 5.0 %



## 3. Composition InformationProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 3 of 13 

## 4. First-aid measures

Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Eye wash fountain should be located in immediate work area.

Skin Contact: Immediately flush skin with water while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Destroy contaminated leather items such as shoes, belts, and watchbands. Safety shower should be located in immediate work area.

Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Ingestion: Do not induce vomiting. Seek medical attention immediately. If person is fully conscious give 1 cup or 8 ounces (240 ml) of water. If medical advice is delayed and if an adult has swallowed several ounces of chemical, then give 3-4 ounces (1/3-1/2 Cup) (90-120 ml) of hard liquor such as 80 proof whiskey. For children, give proportionally less liquor at a dose of 0.3 ounce (1 1/2 tsp.) (8 ml) liquor for each 10 pounds of body weight, or 2 ml per kg body weight [e.g., 1.2 ounce (2 1/3 tbsp.) for a 40 pound child or 36 ml for an 18 kg child]. Notes to Physician: Due to structural analogy and clinical data, this material may have a mechanism of intoxication similar to ethylene glycol. On that basis, treatment similar to ethylene glycol intoxication may be of benefit. In cases where several ounces (60 - 100 ml) have been ingested, consider the use of ethanol and hemodialysis in the treatment. Consult standard literature for details of treatment. If ethanol is used, a therapeutically effective blood concentration in the range of 100 - 150 mg/dl may be achieved by a rapid loading dose followed by a continuous intravenous infusion. Consult standard literature for details of treatment. 4-Methyl pyrazole (Antizol®) is an effective blocker of alcohol dehydrogenase and should be used in the treatment of ethylene glycol (EG), di- or triethylene glycol (DEG, TEG), ethylene glycol butyl ether (EGBE), or methanol intoxication if available. Fomepizole protocol (Brent, J. et al., New England Journal of Medicine, Feb. 8, 2001, 344:6, p. 424-9): loading dose 15 mg/kg intravenously, follow by bolus dose of 10 mg/kg every 12 hours; after 48 hours, increase bolus dose to 15 mg/kg every 12 hours. Continue fomepizole until serum methanol, EG, DEG, TEG or EGBE are undetectable. The signs and symptoms of poisoning include anion gap metabolic acidosis, CNS depression, renal tubular injury, and possible late stage cranial nerve involvement. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. In severe poisoning, respiratory support with mechanical ventilation and positive end expiratory pressure may be required. Maintain adequate ventilation and oxygenation of the patient. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. May cause asthma-like (reactive airways) symptoms. Bronchodilators, expectorants, antitussives and corticosteroids may be of help. This material is a cholinesterase inhibitor. Treat symptom atically. In case of severe acute poisoning, use antidote immediately after establishing an open airway and respiration. Atropine, only by injection, is the preferable antidote. Oximes, such as 2-PAM/p rotopam, may be therapeutic if used early; however, use only in conjunction with atropine. Attempt seizure control with diazepam 5-10 mg (adults) intravenous over 2-3 minutes. Repeat every 5-10 minutes as needed. Monitor for hypotension, respiratory depression, and need for intubation. Consider second agent if seizures persist after 30 mg. If seizures persist or recur administer phenobarbital 600-1200 mg (adults) intravenous diluted in 60 ml 0.9% saline given at 25-50 mg/minute. Evaluate for hypoxia, dysrhythmia, electrolyte disturbance, hypoglycemia (treat adults with dextrose 100 mg intravenous). If exposed, plasma and red blood cell cholinesterase tests may indicate significance of exposure (baseline data are useful). If burn is present, treat as any thermal burn, after decontamination. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. Exposure to amine vapors may cause minor transient edema of the corneal epithelium (glaucopsia) with blurred vision, blue haze and halos around bright objects. Effects disappear in a few hours and temporarily reduce ability to drive vehicles. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome).Product Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 4 of 13 Emergency Personnel Protection: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment.



## 5. Fire Fighting Measures

Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function,

but will be less effective. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May spread fire. Move container from fire area if th is is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Contain fire water run-off if possible. Fire water run-off, if not cont ained, may cause environmental damage. Review the "Accidental Release Measures" and the "Ecologica l Information" sections of this (M)SDS. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothi ng with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to

the relevant sections. Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.

Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.



## 6. Accidental Release Measures

Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Absorb

with materials such as: Dirt. Sand. Sawdust. Co llect in suitable and prop erly labeled containers. Wash the spill site with water. See Section 13, Disp osal Considerations, for additional information.

Personal Precautions: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Spilled material may cause a slipping hazard. Keep upwind of spill. Ventilate area of leak or spill. Refer to Section 7, Handling, for additional precautionary measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.



## 7. Handling and Storage

Handling General Handling: Do not get in eyes. Avoid breathing vapor. Avoid contact with skin and clothing. Do not swallow. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. This material is hygroscopic in nature. Do not enter confined spaces unless adequately ventilated. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.

Other Precautions: Spills of these organic materials on hot fi brous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.Product Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 5 of 13 

### Storage Protect from atmospheric moisture. Store in a dry pl ace. Avoid prolonged exposure to heat and air. Store in the following material(s): Carbon steel. Stainless steel. Polypropylene. Polyethylene-lined

container. Teflon. Glass-lined container. Aluminum . Plasite 3066 lined container. Plasite 3070 lined

container. 316 stainless steel. See Sect ion 10 for more specific information.

Shelf life: Use within Storage temperature:

6 Months 15 - 32 °C



## 8. Exposure Controls / Personal Protection

Exposure Limits

Component List Type Value

| 1,1,1,3,3 - Pentafluoropropane AIHA WEEL TWA 1,644 mg/m3 300 ppm

|| Diethylene glycol AIHA WEEL TWA 10 mg/m3

| N,N-Dimethylcyclohexylamine Dow IHG TWA 1 ppm SKIN

A "skin" notation following the exposure guideline re fers to the potential for dermal absorption of the material including mucous membranes and the eyes either by contact with vapors or by direct skin

contact. It is intended to alert the reader that inhalation may not be the only route of exposure and that measures to minimize dermal exposures should be considered.



### Personal Protection Eye/Face Protection: Use chemical goggles. If exposure causes eye discomfort, use a full-face respirator. Eye wash fountain should be located in immediate work area.

Skin Protection: Hand protection: Use gloves chemically resistant to this material. Use gloves with insulation for thermal protection, when needed. Examples of preferred glove barrier materials include: Chlorinated polyethylene. Polyethylene. Ethy l vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber ("la tex"). Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. When respiratory protection is required, use an approvedpositive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary selfcontained air supply. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilat ed areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply. Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating.



### Engineering Controls

Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. Lethal concentrations may exist in areas with poor ventilation.Product Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 6 of 13 

## 9. Physical and Chemical Properties

Physical State Liquid.

Color Blue

Odor Amine.

Odor Threshold No test data available Flash Point - Closed Cup 100 °C (212 °F) Calculated Flammability (solid, gas) Not applicable to liquids

Flammable Limits In Air Lower : No test data available Upper : No test data available Autoignition Temperature No test data available Vapor Pressure 69 psi @ 55 °C Estimated. Boiling Point (760 mmHg) No test data available. Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 1.206 ASTM D891 Freezing Point No test data available Melting Point Not applicable to liquids Solubility in water (by weight) No test data available

pH No test data available Decomposition Temperature No test data available

Partition coefficient, noctanol/water (log Pow) No data available for this product. See Section 12 for individual component data. Evaporation Rate (Butyl Acetate = 1) No test data available

Kinematic Viscosity 375 cSt @ 25 °C ASTM D4878



## 10. Stability and Reactivity

Stability/Instability Stable under recommended storage conditions. See Storage, Section 7.

Conditions to Avoid: Product can oxidize at elevated temperatures. Elevated temperatures can cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas during decomposition can cause pressure in closed systems.

Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates generates heat.



### Hazardous Polymerization Will not occur by itself.



### Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.



## 11. Toxicological Information

Acute Toxicity Ingestion Single dose oral LD50 has not been determined. Based on information for component(s): Diethylene glycol. Estimated. Lethal Dose, Human, adult 2 OuncesProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 7 of 13 Skin Absorption

The dermal LD50 has not been determined. 

### Repeated Dose Toxicity Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and symptoms of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Contains component(s) which have been reported to cause effects on the following organs in anim als: Liver. Heart. Respiratory tract. Central nervous system. Bladder. Contains component(s) which have been reported to cause effects on the following organs in humans: Kidney. Gastrointestinal tract. 

### Chronic Toxicity and Carcinogenicity Diethylene glycol has been tested for carcinogenicity in animal studies and is not believed to pose a carcinogenic risk to man. 

### Developmental Toxicity Contains component(s) which did not cause birth defects in animals; other fetal effects occurred only at doses toxic to the mother. Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic, high doses in animals. Other animal studies have not reproduced birth defects even at much higher doses that caused severe maternal toxicity. 

### Reproductive Toxicity In animal studies on component(s), effects on reproduction were seen only at doses that produced significant toxicity to the parent animals. Diethylene glycol did not interfere with reproduction in animal studies except at very high doses. 

### Genetic Toxicology Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in others. Contains component(s) which were negative in some animal genetic toxicity studies and positive in others.



## 12. Ecological Information

ENVIRONMENTAL FATE Data for Component: 1,4-Benzenedicarboxylic Acid, Dimethyl Ester, manuf. of, by-products from, Polymers with Diethylene Glycol 

### Movement & Partitioning For the major component(s): Bioconcentration potential is low (BCF less than 100 or log Pow less than 3).



### Persistence and Degradability Biodegradation under aerobic static laboratory conditions is moderate (BOD20 or BOD28/ThOD between 10 and 40%). Biological oxygen demand (BOD):

BOD 5 BOD 10 BOD 20 BOD 28

17 % 29 % >= 29 % Chemical Oxygen Demand: 1.50 mg/mg

Data for Component: Phenol, polymer with formaldehyde , propylene oxide and ethylene oxide 

### Movement & Partitioning No bioconcentration is expected because of the relatively high molecular weight (MW greater than 1000).



### Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. OECD Biodegradation Tests: Biodegradation Exposure Time Method

16 % 28 d OECD 301B TestProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 8 of 13 Data for Component: 1,1,1,3,3 - Pentafluoropropane 

### Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for mobility in soil is medium (Koc between 150 and 500). Henry's Law Constant (H): 6.89E-02 atm*m3/mole; 25 °C Estimated. Partition coefficient, n-octanol/water (log Pow): 1.35 Measured Partition coefficient, soil organic carbon/water (Koc): 280 Estimated.



### Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method

2.97E-14 cm3/s 360 d Estimated. OECD Biodegradation Tests: Biodegradation Exposure Time Method

8 % 28 d OECD 301D Test Theoretical Oxygen Demand: 0.60 mg/mg Data for Component: Triethyl phosphate 

### Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from

natural bodies of water or moist soil is not ex pected to be an important fate process. Henry's Law Constant (H): 3.60E-08 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 0.80 Measured Partition coefficient, soil organic carbon/water (Koc): 48 Estimated.



### Persistence and Degradability Biodegradation under aerobic laboratory conditions is below detectable limits (BOD20 or BOD28/ThOD < 2.5%). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method

5.794E-11 cm3/s 0.18 d Estimated. Biological oxygen demand (BOD):

BOD 5 BOD 10 BOD 20 BOD 28

0 % Theoretical Oxygen Demand: 1.58 mg/mg Data for Component: Diethylene glycol 

### Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for mobility in soil is very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate

process. Henry's Law Constant (H): 7.96E-10 atm*m3/mole; 25 °C Estimated. Partition coefficient, n-octanol/water (log Pow): -1.47 Estimated. Partition coefficient, soil organic carbon/water (Koc): < 1 Estimated.



### Persistence and Degradability Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method

2.23E-11 cm3/s 5.7 h Estimated. OECD Biodegradation Tests: Biodegradation Exposure Time Method

92 % 28 d OECD 301C Test

82 - 98 % 28 d OECD 302C Test Theoretical Oxygen Demand: 1.51 mg/mgProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 9 of 13 Data for Component: 2-(2-Hydroxyethoxy)ethyl-2-hydroxy propyl-3,4,5,6-tetrabromo phthalate 

### Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from

natural bodies of water or moist soil is not ex pected to be an important fate process. Henry's Law Constant (H): 2.74E-16 atm*m3/mole; 25 °C Estimated. Partition coefficient, n-octanol/water (log Pow): 3.83 Estimated. Partition coefficient, soil organic carbon/water (Koc): 10 Estimated. Bioconcentration Factor (BCF): 39; Estimated.



### Persistence and Degradability

No relevant information found. Theoretical Oxygen Demand: 0.74 mg/mg Data for Component: Nonylphenol diethanolamine Mannich base, propylene oxide, ethylene oxide polymer 

### Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Expected to be relatively immobile in soil (Koc > 5000). Partition coefficient, n-octanol/water (log Pow): 0.2 Measured



### Persistence and Degradability

No relevant information found.

Data for Component: N,N-Dimethylcyclohexylamine 

### Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is high (Koc between 50 and 150). Henry's Law Constant (H): 2.35E-05 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.31 Estimated. Partition coefficient, soil organic carbon/water (Koc): 70 Estimated.



### Persistence and Degradability Biodegradation under aerobic static laboratory conditions is low (BOD20 or BOD28/ThOD between 2.5 and 10%). Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method

1.0289E-10 cm3/s 0.104 d Estimated. OECD Biodegradation Tests: Biodegradation Exposure Time Method

88 % 24 d OECD 302B Test Biological oxygen demand (BOD):

BOD 5 BOD 10 BOD 20 BOD 28

4.7 % 5 % 5.3 % 8.2 % Theoretical Oxygen Demand: 3.40 mg/mg Data for Component: Tris(dimethylamino)propyl amine 

### Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant (H): 3.01E-14 atm*m3/mole Estimated. Partition coefficient, n-octanol/water (log Pow): 0.6 Estimated. Partition coefficient, soil organic carbon/water (Koc): > 5,000 Estimated.



### Persistence and Degradability Material is not readily biodegradable according to OECD/EEC guidelines. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method

3.40E-10 cm3/s 0.031 d Estimated.Product Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 10 of 13 Theoretical Oxygen Demand: 3.41 mg/mg



### ECOTOXICITY Data for Component: 1,4-Benzenedicarboxylic Acid, Dimethyl Ester, manuf. of, by-products from, Polymers with Diethylene Glycol Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

Fish Acute & Prolonged Toxicity LC50, fathead minnow (Pimephales promelas), 96 h: > 500 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, 48 h: > 500 mg/l Data for Component: Phenol, polymer with formaldehyde , propylene oxide and ethylene oxide Material is slightly toxic to fish on an acute basis (LC50 between 10 and 100 mg/L).

Fish Acute & Prolonged Toxicity LC50, zebra fish (Brachydanio rerio), static, 96 h: 57.1 mg/l Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, respiration inhibition, 30 min: > 200 mg/l Data for Component: 1,1,1,3,3 - Pentafluoropropane Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

Fish Acute & Prolonged Toxicity LC50, rainbow trout (Oncorhynchus mykiss), static renewal, 96 h: > 100 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, static, 48 h, immobilization: > 100 mg/l Data for Component: Triethyl phosphate Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L).

Fish Acute & Prolonged Toxicity LC50, Japanese medaka (Oryzias latipes), static, 48 h: > 500 mg/l Data for Component: Diethylene glycol Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

Fish Acute & Prolonged Toxicity LC50, rainbow trout (Oncorhynchus mykiss), 96 h: > 1,000 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, 48 h, immobilization: 48,900 mg/l Aquatic Plant Toxicity EC50, green alga Pseudokirchneriella subcapitata (formerly known as Selenastrum capricornutum), biomass growth inhibition, 7 d: > 100 mg/l Toxicity to Micro-organisms IC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: > 1,000 mg/l Data for Component: 2-(2-Hydroxyethoxy)ethyl-2-hydroxypropyl-3,4,5,6-tetrabromo phthalate Material is slightly toxic to fish on an acute basis (LC50 between 10 and 100 mg/L).

Fish Acute & Prolonged Toxicity LC50, bluegill (Lepomis macrochirus), 96 h: 12 mg/l Data for Component: Nonylphenol diethanolamine Mannich base, propylene oxide, ethylene oxide polymer Based on information for a similar material: Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1 and 10 mg/L in the most sensitive species tested).

Data for Component: N,N-Dimethylcyclohexylamine Material is very highly toxic to aquatic organisms on an acute basis (LC50/EC50 <0.1 mg/L in the most sensitive species).

Fish Acute & Prolonged ToxicityProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 11 of 13 LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 28.1 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, static, 48 h: 75 mg/l Aquatic Plant Toxicity EC50, alga Scenedesmus sp., biomass growth inhibition, 96 h: 0.0885 mg/l Data for Component: Tris(dimethylamino)propyl amine Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L).

Fish Acute & Prolonged Toxicity LC50, Japanese medaka (Oryzias latipes), 48 h: 430 mg/l



## 13. Disposal Considerations

DO NOT DUMP INTO ANY SEWERS, ON THE GROU ND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of th e waste generator. AS YOUR SUPPLIER, WE HAVE

NO CONTROL OVER THE MANAGEMENT PRAC TICES OR MANUFACTURING PROCESSES OF

PARTIES HANDLING OR USING THIS MATERI AL. THE INFORMATION PRESENTED HERE

PERTAINS ONLY TO THE PRODUCT AS SH IPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section 10 Regulatory Information, MSDS Section 15



## 14. Transport Information

DOT Non-Bulk

NOT REGULATED



### DOT Bulk

NOT REGULATED



### IMDG

NOT REGULATED



### ICAO/IATA

NOT REGULATED

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.



## 15. Regulatory Information

OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29

CFR 1910.1200. 

### Superfund Amendments and R eauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard YesProduct Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 12 of 13 Fire Hazard No

Reactive Hazard No

Sudden Release of Pressure Hazard No

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 To the best of our knowledge, this product does not contain chemicals at levels which require reporting

under this statute.

Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous Substances List and/or Pennsylvania Environmental Hazardous Substance List: The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and ar e present at levels which require reporting.

Component CAS # Amount

Diethylene glycol 111-46-6 >= 1.0 - <= 5.0 %

Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous

Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting

under this statute.

California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute.

US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed.



## 16. Other Information

Recommended Uses and Restrictions Polyurethane foam.



### Revision

Identification Number: 1040725 / 0000 / Issue Date 10/30/2009 / Version: 1.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this

document.



### Legend

N/A Not available

W/W Weight/Weight

OEL Occupational Exposure Limit

STEL Short Term Exposure Limit

TWA Time Weighted Average

ACGIH American Conference of Governmental Industrial Hygienists, Inc.

DOW IHG Dow Industrial Hygiene Guideline

WEEL Workplace Environmental Exposure Level

HAZ_DES Hazard Designation

Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded.Product Name: STYROFOAM(TM) RS 2045 Polyol Issue Date: 10/30/2009

Page 13 of 13 The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associ ated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's re sponsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.