I -

•

•

•

..

APPENDIX N

ASSORTED FACT SHEETS (SAMPLING)

\ -

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"
I

~.w4~~A~~ , ..

'. ~aste· Program 'r

C6-;;'~

,- . ' , \\(~;.;. -;.

~._,l.~.Oregon'sHazardous ~V,---'-'----_-'---- --'---~_ I

MANAGING WASTE TO PROTECT PUBLIC HEALTH AND THE ENVIRONMENT

Your bu~iness'isincluded in the printingand allied industry category ifit is invovled in: '. • '" --' ' •• - \" .' • " #. '.".

PRINTING AND

, GRAPHIC ART '

- INPUStR,I~S '

......

e, .:~

, '

" ,Preparation ,

" " ". , -' Typesetting,

Gravure

, :- Engraving ,

-;Ph6toproces~in8' "

Letterpress

c, Lithographyf.,'

., Photoengraving

',' '"

.--

"

'•..'

, "

. -. .

....

".

'. \ .'

"Printing,

, ' Heatset lithography

'~ Non heatset Iithographyc-

, -' Thermography '

" '.- 'Business form printing'

', .'" - Sheeted lithography , , , , '" "

,..'-' Letterpress printing' (including flexography)

. ,-:' Gravure printing '. -

, -', ,- Sc~ee"n pres,s printing

, Ftnishing operation~, ' .' ,

, - .Looseleaf binder manufacturers

" < Trade binding operations ,

.~ ,Book.bini#ng~pe~tions" ' ' ,

_' -:In-house bindingoperations ,

, , -' Magazine and catalog binding operations " .' . - '( ., \.

..'

\,

I •

, J

, ' Though not all printing oiailied industry operations produce hazardous waste; those thatuse "

ignitablesolvents, strong acid or, alkaline 'solutions, or paints aild·inks.thatcontai~heavy

metals usually do, Table l lists some typical process operations.in.theprinting andallied :-,' , ": '

industries that li!'e likely toproducehazardous.wastes. ,,'," l . . ...... . .... ~. .

-- . : ::- "

,.\-

'. e~. '{ - .- r >, /"". "

. , , .. \

. I

': .. ,'

Note: , ,_ _ ,

Please-see glossary for explanation of terms. .. . -: . .'

.....
Tablet'

0" " TYPICAL PROCESSI

OPERATION :

'TYPICAL

·MA~·USED

TYPi¢AL MATERIALS

INGREDIENI:S

ON:'LABEL

GENERAL TYPES

OF WASTES

GENERATED

PLATE PREPATIO!'l'.

Counter-etch to remove phosphoric acid p~osphoric add acid/alkaline waste, ,

oxide

Deep-etch coating of deep etch bath ammonium 'dichromate, acid/alkaline waste; heavy , : plates ' ammonium hydroxide metals, waste etchbath

;

Etch baths rnultimetal plate and ferric chloride (copper)' : ' waste etch bath, acid/

plate coating, .aluminum/zinc alkaline-waste, heavy

chloride/hydrochloric metals ~, '

.. acid (chromium), nitric acid

(zinc, magnesium), gum

arabic" '

Apply light sensitive resins, bindersi , PVNammoniunl dichto-, photographic waste coating emulsion, photosentsi- mate, polyvinyl cinnamate, ' tizers; gelatin, fish!elue/alburniri; silver

photoinitiators hali e/geIatin emulsion, . ,;

gum arabic/ammonium, . , dichromate '

Developing plates developer lactic acid; zinc chloride, photographic waste

m~esium chloride,"

hy oquinone ' ,:' , .

Wash/clean plates, type, alcoholscsolvents" 'ethyl alcohol, benzene,. spent"solvents

die, press. blanket and toulene, xylene, isopropyl

I, rollers . alcohol, methyl ethyl

I ketone. trichloroethylene, I perchloroethylene, carbon ,- tetrachloride; gasoline, 'naptha,'~ersoene '

Apply lacquer resins, solvents, vinyl PVC, PYA, maleic acid; spent solvents

.lacquer.Jacquer methylethyl ketone, . developers cyclohexanone, isopliorone

....

, ,.

0"

Makinggravure cylinders acidplating bath

'. Using ink (lithography,

letterpress screen . ~".

. printing, flexography)

pigments, dyes; varnish,

drier, extender,' : modifier, fountain . .

solutions

titanium oxide, iron blues,

molybdated chrome orange,

phthalocyanine pigments,

oils, hydrocarbon solvents, waxes; cobalt/zinc/ '

·manllimese oleates,

plasticizers, barium-based

pigments "

copper, chromic. acid,

chrome'

waste ink with solvents/

chromium/lead/barium,

ink sludges with chrornium/lead/barium .

spent.plating waste

I,

i

i

Lacquer stencilTtlm 'solvents, \fir.ester aliphatic"acetates; cellulose- spent solvents

film, viny fi m, dyes based lacquer, plasticizers

Photographic stencil organic acids, gelatin acids, alkalies, peroxide- hydrogen peroxide.

film Hllgmented), polyester forming compounds, 11m base . . plasticizers, surfactants -

Photoemulsion resins, .binders, _ PV A, PV AC, ammonium or photographic waste. photosensitizers, dyes' potassium bichromate,

diazonium compounds

Blockout (screen' filter) Pif.mtmted polymers, methylene chloride, spent solvents so vents, acetates methanol, methyl cellulose acetates

.:
. :"\

IIII1III

What, do I haveto doto 'manage my.hazardous.waste.properly? .~\. . . . . - < • • ,

'Hazardous waste 'generators fall intothn~e categories.' Each has differing regulatory

,re9uitements~':Her~ arethe' basic requirements.. ' ., .. , '"

r.".",

You are a:r " "

" '

.' - ~.

.J'.•

"'1 •

and you must: :

Identify an hazardous wastes: ,

" - Send waste to a regulatedhazardous:

waste facility or, , "

- Recycle you~ 'wastes or,

"Send 'wastes toa landfill'with the,

: operators pennission ,'.

. - Never-accumulate at any time more

, than' 2,200 pounds of hazardous.

wastes

.CoDtlitiooallYExempt

Generator " ' ~'

. -if in a'calendar month you: '

-generate less than z.z' pounds of c acutely hazardous wastes -

- ",-generate less than -220 pounds of

hazardous wastes' '

. ,:...

if in a calendar month you:

-generate between 2~0 and 2,200'

pounds

'Sinail'Q~antity Generator

and ,you must: "

- Identify all hazardous wastes

-Obtain a DEfIEP;\, identification

number "

'. - Properly package the wastes. ;

-Properly label and mark containers','

c Accumulate hazardous waste on-site

.no more than 180 dayS or 270day~' if

': transporting more, than 200 miles,

, . ' - Placard waste for shipment: .

Comply with the Oregon' Public "

Utility Commission'stransportation ".

, requirements, ~,' ,

- Use a manifest to ship (maintain ,

c'- copies'for three years): ,

:- Use only-transporters and facilities

, ,with DEQ/EPA ID numbers

'~Ship waste to regulated hazardous

" waste facilities within 180 days, or; ,

.- - Recycle hazardous waste on-site'

"., , within 180 days

- Prepare moditiedcontingency plans, '

emergency procedures, and person-: '

nel training. ' , ' , '

- Meet preparedness and prevention '

, requirements , ' , . '

- Keep records ,

Submit a quarterly report to DEQ

',' -Pay fees '

if in a calendar month you:

, -generate 2.2 or.more pounds of

, acutelyhazardous wastes , '

', generate 2,200 or more pounds of

'hazardou~ wastes' "', '

,:Fully Regulated Generator

and youmiist: , ,

: Identify allhazardous wastes ' " ',~

-Obtain a DEQ/EPA identification ' " ' 'number .

.:Properly package the wastes' , ,

, - Properly labeland mark.containers

- Accumulatehazardous waste on-site

no more than ~',

- Placard waste for shipment

- Comply with the Oregon.Public

Utility, Commission's transportation

requirements ;' .

'- Use a manifestto ship (maintain " - ,

, c~piesfoithree years), .

, lfse orily transporters and facilities '

with DEQ/EPA IDilUmbers '

• ;- Ship' waste to regulated hazardous' ,

, .waste facilities within ~,or; .

, - R~yclehazard;ous waste on-site

within 2D..dllD' , ",

-.Prepare contingency plans; -emergen~y procedures, and personnel'

training . "

- Meet preparedness and prevention

. requirements'

- Keep records

, . - Submit a quarterly report to DEQ

'-P~y fees ' , "

,,", .'

.' .

I

I C

Note:

Upon registration as a hazardous waste generator, you will receive a

set of theregulations that-apply to each generator category. ' - . - . . .

()

'3 " .
111111I111111 II I

,II

WASTE DESIGNATION AND SHIPPING INFORMAnON-FOR,HAZARDOUS WASTES

'PRODUCED'IN,PRINTING'AND GRAPHICS SHOPS' " "

.The table~below provides info~~ti~n for ~l~sifying hai~dous waste pri~r to'off-site shipment. ' The-correct designation, ,

for a'specific waste should be verified with the hazardous waste facility you are shipping to; the,regional offices of the "

. 'federal Department of Transportation (DOT) or the state offices of the Public Utility Commission (PUC) prior to ~,

completion of the hazardous waste manifest. ITEMS LISTED ARE,EXAMPLES ONLY! Other Department of Transportation (DOT) descriptions and identifica:tio~ codes maybe applicable in some circumstances.

Table 2'

WASTE DESCRIPTIONS

'Photographic "astes', " Heavy metal Photographic, prosolutions cessing wastes conta'(ning heavy inetal's

'PROCESS 'OR

WASTE ,TYPE

, Trichloro~

,ethylene

'MATERIALS

",' USED'

Trich l oroe.thvl ene ,:

eth i nyl- tri chlori de,'

,TriClene,' ~ri '

DEQ/EPA

WASTE

CODE

0003"

0'006,: -

0007,'

'or ODDS

'F001

'DOT, SHIPPING"

NAME

." ;

hez ar-dous. 'wa~te

solutionN.O.S~ , ('containing cadmIum,' ,

cliromium, .I ead,

silver,orcyanide)

, ~astetrich'loro~:

, e,thylen~

HAZARD . - .. ..

CLASS

ORM-E

ORM-A

UN/NA

NUMBER

NA9189

UN1710,

Spent, Solvents _

-Carbon Tetra-' carbon tetrachloride,

'chloride ~~~chloromethane,

"'ne'catorina, benz i no- form, ,CCl4

F001 "waste carbon

tet rach lor. i de

Ethano,l 'ethanol,ethyl at cehet: 0001 l -·'wasfe ethyl aLc oho l

,'waste ethanol

IsC?propanol 'i sop'fo'pano l ,{SOpropyl alcohol0001 waste' isoproP?lnol

Ethyl Benzene, ' e thvt benzene 'F003 waste ethyl ~enzen~

1,1,1' Tri-..

eh loroet'hane

Methylene,

Chloride ',_

1,1,1 r ri ch l cr-oe thene

aerothane, TT, cht erten, inh,ibisol ,,' trichlotoeihane, ,chloro-

~hen'NU" NCl-C04626, , methylchloroform, .

chlorothene VC; aero-

,th',ene NM', narkoul,,"

so l met h tne

,Dichloromethane, ineth-"

>ane',dichforide, methy-,

l'enebichloride;' NCICS0102~ methylerie~ichl~ride, solaesthin,

aerothene NM; narkoul,

siknethi,:\e

f001 .

" -

F002

waste 1,1,1 tri~,

chloroethane,

waste d~ch~oromeihane or methylene

chloride

ORM-A UN1593,

Notes: N.O'.S:-not otherwise specified. "

Flammable liquid (D.O.T. defmition) has a flashpomt below 100' F. ,

Combustible liquid (D.O.T. definition) has' a flashpoint between 100' and 200' F.

, Ignitable \¥aste(DEQ/EPA definition) has a flashpoint <140' F.

UN/NA: United Nations/North.Amenca.International shipping codes.

- "

4

o

"
" ..

•• , "

~ss~e'B~~·~v~~'Solve~~s o~'~e~yv ~e~~ls' 'Yaste Ink. . various constituent F001,

'.so tvents e car-bon :tet- . F002,

· rachloride, chloro- , ,F003:"

· form, 'methyLene ch t or- . FOOS,

ide,,1,1,1,-trichloro-' 000\;

. ethan'e,'benzene, tol~.· 0003,'

-uene , e·thyl. berizene , '0006,

,·tetrachlorriethyl~ne, 0007' :.

various. constituents . or 0008 , , f'rompi gme'rts:chro- .

. mium, copp~r~ lead,

. 'zinc, ~yanide; al~~-'

', "inum~ ,cadmium; ni'ckel, c'obal.t'· . ..

(waste ink · combust-i b l e.

l'i qujd, · flammable

.Li qui d

UN2867

UN1210

'.'

"

"

. s~~ori@ Acid/AQ~~lv~e'~~stes " ADlDoniUliammonium hydroxide; .'

· Hydroxide. 'aqu~'ammonia,~spirit

of hartshorn, NH 40H'.

0002' 'waste ammoni.um hydroxIde (between·12~,and

44%·ammoniaf .. '\laste' ,ammcinl.um hydrox- ..

. ide .( be l o"!J 2% ammorii a)

corrosiveNA2672

. rna t er i.a·l ~, --=.

NA2672 ".

Nitric Acid nitr.~c"acid; HN03, '_"0002~ , .aquatort I s

Hydr::ochloric

· ~cid

· hydro.ch·lori,c a'cld,' ..... :'00.02

muriatic ac.Jd, HC,l '.

,- "

. 'was'te hydrochl'or I c '

.. acid I!Ilxture·.

waste ~itrjc 'acid

(over. 40%) , . '. " .

. wasie ~Itiic'~cld

(below 40%) ,

cor'ros t ve

.'materi a l

corrosive

. mat eria l

. 'NA178~

,'UN2031

NA 1.760

Phosphoric

ACi,d.

phosphor.i c 'acid, ·0002· ...• ~~ste pho.sp~.orlc' a"ci'd" .co r r-osi ve

orthcphosphcr-ic acid, , material

H3P.o4'., ' " .' '.

UN1805

0002'" :' waste 'sod i um hydr~x i de ,: :'c.~·r r os i ve '; UN1823'"

,< ma~eri·al., '

, >

. "

corrosive' . ,.UN1755 ;.-

materia~

".corrosIve-UN1832: .

mater I a l '

I'"' ,

wa'~te sUl,furic·.~dd,

spent

was'te sodium h'Ydro~ide .corrosi.ve;:. UN1824··

.L i qu id: or so lut i.cn mat erie t : .;

:, ,',

. '~aste chromic acid so l ut ion .," '

0002

1,.-: .>

~sodium'hydr~x;de~ .~ -.:

caustic soda,' soda :ly~,

scd ium hydrate,'- NaOH .

sUlfuric'acid,:O,q:of' 0'002

Vitriol, H2S0'4. .'

~~romic acid 0002

sodium hydroxide', "

caustic soda, soda lye:,

'sodium'hydrate;CN~OH

' .. S!JUuric Acid

Sodha Hydrox-

:ide (sol id, .'

.f l ake , bead,

· dr'y,', or gran~

'ular.) .

, ". ': : Spdi'Um Hydrox- •

.Ide t t iquid

·9 r ' s o l ut i.on )

-" ,-

K086: ha~ardou~'~ast~,_ ll~uid

0007,: , ' or . soli"d~'NOS '

or. 0008

sinlTlt'~lmiin~'~sste

.Spent PLatIng' .spent etch ,baths " .

. 'Yastes''- '\. spent pL.a~i'ng sotut ions" and. st udges', ...: .

stripping and clean- .

". ~ngbaths",·'"

'Ink sa~~e~it~ C~rC8V~O~ ~emcl.

. Ink Sludge ink··sludge containing

with·Chrc.iUm . heavy 'metals' . .' . or lead ' .

.F006,

Foot, "

F008,

F009,

or' F019'

, h~zardo~s waate l,lquld.

or solid, NOS'(Nat

Otherwise Spe~i.fie~)·

-;

· ORM-E .

, ORM-E: .

NA9189

. NA9189

. {

.... j

. ·1

i

"1

" il

.'

l!J!nitlllble Mlllstes ,. Ignitable .ignitable wastes, NOS

·Yastes•.· ..OS

0001 waste, f Lammabte liquid N.b~s. -.' ' waste combustible

'l i qu i d 'N .O:,S.

waste· f l emmabl.e solid

, N.O.,S.

, "

flammable' UN1993

liquid' '

combustible UN 1-993

. liquid

flammabl'e··. UN1325

sol id.

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III111 II

, ,

Oregon's 'Hazardous

, .

EQUIPMENT

REPAIR

INDUSTRY •.J • OVERVIEW

Your business is included in the:equipment repair category ~f you: "

-. Repair ~r maintain any equipment, appliances, mechanical, or electrical g()ods'"

- Rebuild,'refinish, restore, or paint '

- Remove oil,' grease; rust, dirt, 'or paint

The products you use on equipment, tools, floor; or your hands may contain hazardousmateri-

, " als..the wastes generatedfromtheir use may be hazardous. -

Ev~r~ day workmen use products containing hazardous materials, these include: ,

.-Plating solutions and ~iudges - Toxic

Rust removers -Corrosive

- Used rags - Ignitable

paints - Ignitable '

Cleaners and' degreasers - Ignitable

These products almost always.contain chemicals or materials that arehazardous to human

health and to the' environment, Table' I lists typical operations and processes that use products

containing hazardous materiais and and are likelyto produce hazardous wastes. '

, 0 Og Note:

,Please see glossary for explanation of terms.
. Table 1

TYPICAL PROCESS/

•

OPERATION

, TYPICAL'

MATERIALS USED

TYPICALMATERlALS , . GENERAL TYPES, ,

INGREDIENTS ' OF WASTES' " .

ON LABEL GENERATED

d~greilsers- (gunk), and petroleum distillates,

cleaners, varsol, aromatic hydrocarbons,

solvents, acids/alkalies m0eral'spirits , .'

• Oil and grease

removalParts and equipment

cleaning

degreasers- (gunk),

solvents, acids/alkalies;'

cleaning ,fluids -" ,

petroleum distillates; - aromatic hydrocarbons,

mineral spirits, benzene,

toluene, petroleum naphtha

.ignitable wastes, spent

solvents, combustible

solids, waste acid/alkaline

solutions' .

ignitable waites:spent

solvents,' combustible

solids, waste acid/alkaline

solutions .

Rust removal ' naval jelly, strong acids: phosphoric acid, hydrochlo- waste acids, waste

strong alkalies ric acid, hydrofluoric acid, . alkalies'

sodium hydroxide " .,

Paint preparation ' , .

paint thinners, enamel

reducers, solvents;

white spirits . .

alc~hols, pe';ole~in distillates, Oxygenated

solvents, niineral spirits,; , ketones "

'spent solvents, ignitable,

wastes, i/1nitable paint

wastes With heavy metals

; -,

enamels, lacquers"

epoxys, alkyds, acrylics,

primers

Painting

. I • •

acetone, toluene, petroleum ignitable paint wastes,

distillates, epoxy ester spent solvents, paint,

resins, methylene chloride; . wastes with heavy metals, , xylene, VM&P naphtha, ignitable wastes '

aromatic hydrocarbons, ,

'methyl isobutyl, ketones

.',

, " Spraybooth, spray guns,

and brush cle~g " .

Paint removal

paintthinners, enamel

reducers, solvents;', .

white spirits . ' ".\

solvents, paint thinners;

enamel 'reducers, white

spirits .

, ketones, alcohols, toluene,

acetone; isopropyl alcohol,

petroleum distillates,

,mineralspirits '

I

.acetone; toluene, petroleum·

distillates, methanol;

methylene chloride"

isopropyl alcohol, mineral

spirits; alcohols, ketones, .

other oxygenated solvents,

ignitabi~ paintwastes,

heavy" metal paint wastes,

spent solvents ' ,

ignitable paint wastes;' '

heavy metal paint wastes,

spent solvents; "~.

VIastes are considered hazardousif they have any of the following characteristics:

.lIgnnfiQ21IGBe -Substances that spontaneously burn or combust at a temper~ture less than

140· Eare'considered ignitable (flammable); They canbe liquids,"solids, flammable'

. gases, or oxidizers. Typical ignitable substances include solvents, paint 'and lacquer

',thinners, and stripping agents. Thesesubstances yield dangerous.wastes that pose a fire

hazard,··'·"""

Corrosive Corrosive substances are acidic liquids (pH less than or equal to 2), alkaline

liquids (pll.greater than or equal to 12.5) or liquids that corrode steel at a rate greater than

0.25 inch per year. Wastes from these substances can dissolve most materials; specialized.

, containers are necessary to resist corrosion. Extreme care must be used when handling

them because they bum the skin. . . . .

, lRe2canve c~Reacti~e substances are very unstable and readily, rapidly, or violently change

when mixed with or exposed to-water, heat, pressure, orother materials, These sub-'- '

. stances, especially cyanide, or sulfide compounds, may generate toxic gasesunder mildly

, acidic or alkaline conditions. Chromatic acids, perchlorates, and peroxides are common

reactive substances. Wastes produced from reactive substances are hazardous since they'

may explode. ' '. , '

lElP'1l'mtic - Wastes are toxic if, after, being tested through an extraction procedure (EP);

" they coritain high concentrations of heavy metalsor specific pesticides. Toxic wastes can

cause illnesses such as cancer, kidney damage, birth defects.andblood disease. Examples,of EP toxic wastes are photographic processing wastes, waste inks, and paint

sludge from the recycling of solvents. Some toxic wastes are acutely hazardous if they

lire fatal to humans in low doses or are capable of contributing to serious irreversible: ' illnesses. . .

2,

•
, "

Hazardous' waste generators fall, into three categories:'

requirements, Here are the basic requirements.

,You are a:' '

•

-ifin a calendar month you:

- generate' 2.2 or more pounds'of

acutely hazardous wastes ,"

- generate 2,200 or more pounds of

hazardous wastes

,2l1l1l411 YOURmunsft:

- Identify all hazardous wastes

- Obtain a 'DEQ/EPAideIltification '

number '

- Properly package the wastes' .

-Properly label arid mark containers' ,

-Accumulate hazardouswaste on-site" ,

, no more than ,

, - Placard waste for shipment

-Complywith the oregon Public

,7Utllity Commission's transportation

, requirements

- Use a manifest to ship (maintain

,copies for three years)' ,

- Use only transporters and facilities

with DEQ/EPA ID numbers "

- Ship' waste to regulated hazardous

waste facilities withiri~,or;

, Recycle hazardouswaste on-site ,

within'~, '

- Prepare contingency plans, emer-.

, ' gency procedures, and personnel '

training'

Meet preparedness and prevention

requirements

, - Keep records

- Submit a quarterly report to DEQ '

-Pay fees'

ifin a, calendar' month you: '

"generate between 220 and 2,200

pounds

. .

,. ~llIl1l411 YOUR munsft:

Identify all hazardous wastes

- Obtain ,3 DEQ/EPA,identification

number . '

-Properly package the wastes

- Properly label and mark containers

'-Accumulate hazardous waste 'on-site

"no ~ore than 180 days 6~ 270 days if

transporting more than 200 miles

, - Placard waste for shipment,' .

'.Comply with the Oregon Publi~

..UtilityCommission's transportation

requirements

Use a manifest to ship (maintain '

copies for three years) "

. Use only transporters and facilitie~

with DEQ/EPA ID numbers'

-Ship waste to regulated hazardous

waste facilities within 180 days; or;

- Recycle hazardous waste on-site

. within 180 days . ,

- Prepare modified .contingency plans,

emergency procedures, and personnel training . , , "

. - Meet preparedness and prevention '

,requirements,

, - K~p records ,

'-,Submit a quarterly report to DEQ

-Payfees,

" ..' . -

" , C((J)IJD«!Ifi~fi((J)IJDBlnny IE~~rrUnlPa , G(2IJD(2Il'~a((J)Il" ' ." , .-

if-in a calendar month you:

-generate less than 2:2 pounds of.

" acutely hazardous wastes

-generate less than 220 pounds of,

hazardous wastes

, alll1lrrll YOUR mURsft:

• Identify all hazardous wastes

- Send waste to a regulated hazardous

, , waste facility or; ,

- Recycle yo~r wastes or, ,

, : Send wastes to a landfill with the

operators perinission

. Never accumulateat any time more

. than 2,200 'pounds of hazardous ".

, 'wastes

•

Note:.

Upon registration as a hazardous waste generator, y'ouwill receive' a

set 'of the re~ulations that apply to each generator category.

3.
WA§1I'IE j]))IE§llGNA1rIION ANj])) §JHil[IPIPmG IINlFO~MA 1fIION lFO~ JH[AZA~]J))(Ol1U§ WA§1I'IES'

lP'&,Oj]))U)CIEj])) llNIEQWI1P'lWEN1I'~IEIPAll~ §JH[OIID§ " '

The tabl~ below provides information for classifying your hazar:dous waste prior t6 off-site shipment. The correct designa-

" tion for a specific waste should be verified with your transporter or the regional offices of the federal Department of Trans-

.portaiiondxrl') or the state offices ofthe PUblic Utility, Commission (PUC) prior to completion ofthe hazardous waste'

,!l1anifest: .ITEMS LISTED ARE EXAMPLES ONLYI' Other Department of Transportation (DOT) descriptions and identification codes may be applicable in some,~ircumstances.

•

Table 2

. . ,

pet~ole~m naphiha ' 0001

"

petroleumdistjJl~tes· ~001

1,L'·'trichloroethane F001'

(ch lor-ce thene ) .

:liAZARD UN/NA, C~SS 'NUMBER

corrosive varies

materialcorrosive UN1814

material-

,corrosive UN1824,

material, '

.,flammable' UN 1993

l i qui d

varies varies , flammable . UN1993 '

liquid • flammable UN2553

liquid

flammable UN1255

liquid

flammable, UN1268

, liquid . ORM-A UN2831

.DOT SHIPPING

NAME

waste petroleum

naphtha '

w,aste petroleum.

distillate

'wa~ie 1 1 1 triO' .,.. -"

chloroethane '

depends on', typ~ of,

ac~d

waste potas,sium

hydroxide solution

waste sodium

~ydroxidesc)lution

waste flammable

, l i qu i C1, N.O. S •

. varies" . wasteflammab'ie

". l i qu i d, ,N: Q• S•

waste naphtha'

0002

Dooi

D09~

F002 or

F004,

FOO1-

Dli01

0001

, DEQ/EPA

WA,STE

CODE

MATERIALS

USED

acids:

ceus tLc vsoda

carburetor ,cleaners, . . . .

c~i~ririate~ ~olv~~ts'

,i gni tabl e (fl ammable)

degreasers' .

mineral spi r it solvents

WASTE TYPE,

Oil/Gr~<nsl!,

a~"61t

lP<nintll;~~~rSl1l:'icin',whitespirits, varsol 0001

alcohols 0001.

'enamel reducers" ,0001

. "MEK" . F005 '

mjnera t'. spi r'i~s" -. '0001

pai~t t~inners varies

petroleum,distillates .0001,

waste 'naphtha' "flanimable' " UN2553

liquid '

'waste flammable flammab~e~ UN1993

Uquid,N,.O.S;.. liquid

waste, flamamble flammable UN1993

l i qui d, N.O.S. ( iquid

waste 'methyl ethyl flammable UNn93

" ketone _l iquid

waste naphtha ' : fl aniniab l e ,UN2553

wasfe ft'ammab l e

l iqui~

flammable', UN1993

'l'iquid,,'N.O.S. liquid

waste petrQleum flanirnable UN1268'

d i stiI Late ',' , ,.l iq~id "

l))ilVIl1lll:ht~ acryt i c .and alkyd 0001 waste flammable flamniable UN,1993

paints liquid, N;O,S. ,lJqufd

enamels and 'epoxy, 0001 - or - (-i f' U qu i d) -

r . paints hazardous waste., ORM-E UN9189

lacquers 0001 ' soUd, N.O.S. (if soUd)

most paints with 0008 or' hazardous waste' ORM-E ' UN9189

• tox i c .mer a l s 0007 .set id, N.O.S.

4
II1II1111111

i

.0

Spray Booth/

Spray Gun/

Brush Cleaninli,

Paint ReIIOval/.

Stripping,

"Rust Removal

acetone

alcohols

enamel reducers

"MEK"

methylene chl~ride'

mineral spirits

pain,t thinners

'petroleum disti l Lat es

VM&P naphtha

toluene (Toluol)

'pa j'nt thinners

white spirits

,xyl~ne (xylol)

paint thinner

aci·ds

naval 'jeUy

\ '

F003

0001

0001

F005

"F002

0001.

,0001

0001

F005

0001

F003

0002

0002

'waste acetone

waste 'flammable'

l i qu i d, N.O.S.. I

waste flammable'

liquid; N.O.S.

waste methyl e~hyl

ketone

waste dichloromethane

waste naphtha

waste' flammable

liquid, N.0. S. '

,waste petroleum

,di.still~te. ' ~ast~ pa~nt related

material'

waste toluene

waste naphtha

waste xylene

depends'on type of

acid

waste phosphoric acid

flammable

liquid .

flammable

,liquid

'fl anuilab l e

,liquid

flammable

liquid

ORM-A

flammable

liquid

f l ammebte

l i qui d

f·lammable

liquid

flammable

, liquid

flammable

liquid

ft'ammable

liquid

flammable

liquid

. corrosive

material

corrosive

material

·UN1090

UN1993

UN1993 ,

UN1193 ,

UN1593 '

UN2553

'UN1993

UN1268'

NA;263

.UN1294

UN2553

UN1307

var.ies

waste cyanide mixture,

dr:y

Poison B • UN15'88

.0

-Metal Finishing, strrpping/clea,ning'

including . solutions (cyanide)

E~ectrop~ating plating bath solu~ions

,and Electroless (cyanide).

ph.ting, Etching, plating bath sludges

~tc. (cyanide)

platin~ p~etreatment

sl~dges(cyanide)

F009

F007

F008

F006

waste cyanide

N.O.S·,

waste "cyanide

N,.O.S.

waste cyanide

d,ry

solution,

mixture,

Poison B .

Poison B

Poison B

UN1935

UN1935

UN1588

hydroch'toric solutions 0002

spent acid solutions:

chromicsolutiori~ 0002

nitric' stripping,

solutions '

phosphoric solutions

s~ljuric ~olutions

0002 .

0002

0002

. , waste chromic acid:

,solution

wa's t.ehydroch lor i d acid

waste nitri~'a~id > 40%

waste nitric acid < 40%

waste phosphoric acid

waste sulfuri~ acid,

spent

corrosive

material

corrosive

material

oX'idizer

. corrosive

material

corrosive

material

corrosive

'material

UN1755 '

NA1789

UN2031

,NA1760

UN1805

UN;832

I

I

I.

o

Notes:', N,O,S. - not otherwise specified.

Flammable liquid ro.o.r. definition) has a flashpoint below 100' F.

.Combustible liquid (D.O.T. definition) has a flashpoint between 100' and 200' F.

Ignitable waste(DEQIEPA definition) has aflashpoint <140' F.

UN/NA: United Nations/North America, international shipping codes.

5
'. / ,-@'oregonDEQ'.

". i Hazardous Waste Program

...• 811 SW 6th· . ., .

[Q) ® ~. Portland, Oregon 97204 .

(503) 229-5913 .'

Toll Free 1-800-452-40 II

6

'-

••••

•

•

. 9-88

=

,1

·1

I
."

\

\ \!c":':~'/;' ../" '~-7 ,

·Oregoll'sHazardous· .'@'waste .Program

MANAGING WASTE TO PROTECT PUBLIC' HEALTH AND THE ENVIRONMENT

,-; :

'" "ACUTELY

,~AZARDOUS'

'WASTE'

'GLOSSARY," "J

. , Some wastes are consid~red acutely hazardous." These are wastes'thatEPA: has deter-

- minedto be.dangerous irrsmall-amountsi-therefore, theyare regulated the same as

,', 'large ~ounts of other hazardous wastes; Acutely hazardous wastes, for example,-,

may be generated using certain 'pesticides. 'They.also include dioxin-containing' ' . , wastes. ;.

.- i

.' TOXIC

If your bU'sines~ generates more than 2.2 pounds of acutely hazardous wastes·in:an.y', '

single calendar month, 'you would be categorized ;IS'a' fully regulated'generator. 'if _'

'your businessgenerates 2.2'pounds or less of acutely hazardous waste.in any.single

"calendar month, you would be categorized as aconditionally 'exempt small quantity'

'generator·> 'Those substances that ate 'classified as acutely hazardous are explicitly: .

listed inseveralfederal and state handbooks; Call DEQ if you,'art: unsure about any ~'

wastes you generate. ' , ',", . . ' ,

A ~ubstanceis toxic ifiris poisonous orharmfui to plant or anima(life.~ A toxic ',"

substance can alter _~ organism's .environment through chemical or physicalaction. "

DEQ/EP~' ,ADEQ/EPA Identification Numberisaunique, 12-character number .assigned

HAZARpOUS. .' to the physical location where'ahazardous waste is generated, to 'transporters of haz- ,

" WASTE ,"ardouswaste:and to owners/operatorswho treat.istore.iordisposeof.hazardous waste:'

IDENTIFICATION, . The-identification numbers help DEQ compile and maintain adatabase .on hazardous'

:NU~BER .waste'activities,' ' . - ,,', . ,

.'

GENERATOR

MANIFEST

To obtain 'a DEQ,tEPA Identification Number, you shouldcomplete the form

"Notification of Hazardous Waste Activity". .To request theform.contactyourstate

hazardous,waste management agency (DEQ), Along withthe appropriate notification . '

'form: you will receive instructions for-completing the.form and information onwhere

you cang~t_aoditioriarassistance'. , , ' ',' .',"': ' -' , ,,' " :' ' . '

A generatods.the personor' b~siness who actually produces the hazardous waste or > ,

'whose act firstcauses a hazardouswaste to become.subject to regulation; Under state

and federal regulations, generators must determine if theirwaste ishazardolls and if

'so, must manage their waste according to regulation' from the point of generation

-through final destination, or "cradle to grave", Once awaste is.determined to be '

.hazardous, .generators must notify the DEQ and obtain an DEQ/EPA Identification,

.: Number tor each site where hazardous waste is generated. ' " ,

,A 'hazardous.wastemanifest is inulticopy shipping:docunient you fill out that

accompanies your hazardous waste shipments off-site. _ , . (,

The manifest.forrnis designed so that shipments· of hazardous waste can betracked.

from their point of generation to their final.destination. 'The hazardous waste generator,' the hauler

,.

and the designated hazardous waste facility must each sign this docu- ' . .. "

, :
NOT(FY

menrandkeepacopy. 'the'designate~facility'operatoralso must send a copy back to'

the generator to ensure that the shipment arrived. You must keep a: copy of the

manifest, which must be signed by the hauler and designated facility, on file for three'

'years. DEQ requires submission of a quarterly report consistingofsummaries of

'wastes manifested, and wastes managed on site.

_-I • ..'

RCRA law, along with DEQ regulations, requires you to notify your state DEQ of

hazardous waste, activity if in asingle calendar month you produce more, than: '

·,220 pounds per month of hazardous waste ' '

.. 2.2 pounds per month of acutely hazardous waste

• 220 pounds ofspill material' ,

You can satisfy this requirement by completing and signing the notification form and

obtaining ';1 DEQ/EPA Ideritifi~ation Number.

C,'

, TSD

(Treatment, '

Storage and

Disposal)

FACILITIES'

TSD facilities are the last step inthe hazardous waste management system. All T~D's

must registerwith DEQ, obtain a permit 'when necessary, and above all, they-must

have a DEQ/EPA Identification Number. th~ definition of a TSD encompasses three.

different functions: , .

'. Treatment - Any' method, techniql.!.e, or process, including neutralization, 'designed to change the.physical, chemical, or biological character orcomposition of

'any, hazardous waste. ,Treatment can, neutralize the waste, can make itless

hazardous, can recover the raw materials, or can make it safer and easier to

transport, sto~e or dispose of. _

Storage - The holding of hazardous waste for a temporary period, at the end of. '

which.the hazardous waste is treated, disposed or stored elsewhere. '

. ~. Disposal - The discharge, deposit, injection, dumping, spilling, leaking.ior

"placing ofany solid waste or hazardous waste into or on any land orwater so that'

',' any part of itmay enter the environment or be emitted intothe air or discharged

.intoany waters.dncluding g~ound waters.. "

DEQ' , The Oregon Departmentof Environmental Quality. State agency that imple-

. " ments regulations dealing with air,and water quality', .hazardous .wastear1d

solid waste reduction, recycling and ,disposal.

',EPA The United States Environmental Protection Agency. Thefedetal government '

• agency that oversees environmental regulation nationwide.

RCI;fA The Resource Conservation and Recovery Act: Federal legislation passed. in

1976 that initiated regulation ofhazardous wastes. This .law is reauthorized

every four years and may be amended or changed to broadenthe regulation

of hazardous wastes; ,

I

r-.

I

I

I

~.--

MATERIAL SAFETY

DATA SHEET

. . .. .

Manufacturers are required bylaw to provide material safety data sheets on

'- all products they manufacture and sell. These data sheets provide information on the physical, chemical and toxic properties of the product. Often they

provide information which is useful in evaluating a waste to determine ifit

'is hazardous. ,,'

. 0' Oregon DEQ ' .

gfJ

' . Hazardous waste. Program , ,'811 SW 6th '

. e g Portland, Oregon 97204.

, . (503) 229-5913

h •• Toll Free Ic800-452-40l1