# Nov**ember 8, 2012 CA A** **Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew ater**  **PVC General Company and Facility Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility.

**Parent Company General Information**

Parent Company Name:

Address:

City: State: New Jersey Zip Code: 7039

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments owned): >1500

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City: State: Texas Zip Code: 77978

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 44 9 Peach Tree Hill Road Formosa Plastics Corp. USA

361-987-7806

Mstricklin@ftpc.fpcusa.com PVC (P-1)

201 Formosa Dr.

Point Comfort

Mark Stricklin Livingston

## November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater**  **PVC Production Process Wastewater Treatment System Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**Form C-1-c Supplemental Questions FORM C-1-c**  **PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER** Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 26,074.55liters/hour liters Process Unit ID: P-1 If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: Process Equipment ID: U-14 Wastewater Feed Rate (lb/hr): 42,500 38,187.16liters/hour (max design) Feed Temperature (°F): 185 liters (max design) Feed Inlet Pressure (psia): 5.6 Liquid Loading Rate (liters/m2): 321.76 Steam Feed Rate (lb/hr): 4200 Steam to Feed Ratio (kg steam/liter of wastewater): 1:10 Operating Temperature (°F): 195 Operating Pressure (psig): 0 Total Number of Stages: Overall Calculated Tray Efficiency: Stripping Factor: Flow configuration (countercurrent, cocurrent): countercurrent Number of Actual Trays: 40 Column Height (meters): 25

Year Equipment Installed: 1980 Equipment Currently Regulated Under (cite regulations): VCM NESHAPS 1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.**November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater PVC Production Process Wastewater Stream Information** 

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3 4**  **5 6**  **7 8**  **9 10**  **11 12**  **13**

**Min Max**  **Average** P-1 U-10 97,200 162,000 135,000 Estimated 365 PS-501A~J PVC Dryer Centrifuge WWT Combined Waste Water Treatment Yes P-1 U-11 302,400 421,200 410,400 Estimated 365 PS-501K~R PVC Dryer Centrifuge WWT Combined Waste Water Treatment Yes

**Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System 1**  **2 3**  **4 5**  **6 7**  **8 9**  **10 11**  **12 13** 

**Min Max**  **Average** P-1 PC-701D Steam Stripping Continuous U-14 115588.8 141955.2 128772 Estimated 365 WWT Combined Waste Water Treatment Yes

**Table 3. PVC Process Wastewater Destination Codes Table Code** 
Wastewater treatment system WWT Provide name of the wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall Discharge to POTW, no treatment POTWRAW Provide name of POTW Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW Zero discharge or alternative disposal method ZEROALT Describe method Recycle to process RECYC Describe where in the process the stream is recycled Other OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3 4**  **5 6**  **7**

**Min Max**  **Average PVC Process**  **Unit ID**

**Flow Rate Determination**  **Method**

None **Operating Days Per Year**  **Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Destination Description** 

**Source of Process Wastewater Stream Process Wastewater Stream Flow Rate**  **(gallons per day) PVC Process**  **Wastewater Treatment**  **System ID 1**  **Flow Rate Determination**  **Method Is this PVC process wastewater**  **stream exposed to the atmosphere at any point between the**  **originating PVC process equipment and its destination?** 

Dryer centrifuge waste water **PVC Process Wastewater Stream Flow Rate (gallons per day)**  **Associated Destination Information**  **Originating PVC Process Equipment ID**  **PVC Process Wastewater Stream Destination Code** 

(Refer to Table 3 below) **Originating PVC Process Equipment Description**  **Flow Rate Determination**  **Method Operating Days Per**  **Year PVC Process**  **Wastewater Stream ID** 

**Is this process**  **wastewater treatment**  **system batch**

**or continuous**  **operation? Type of Process**  **Wastewater Treatment System**  **PVC Process Wastewater**  **Treatment System ID**  **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream**

Dryer centrifuge waste water **2**

**PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **14**

**Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?**  **Operating Days Per Year**  **PVC Process Wastewater**  **Stream ID If your response in Column 3 is "Other" then please provide a description of the process wastewaetr**  **treatment system Associated Destination**  **Information**

(Refer to Table 3 below) **PVC Process Wastewater Stream Flow Rate**

**(gallons per day)**

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater**  **PVC Production Process Wastewater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company**Formosa Plastics Corp. USA **Facility**PVC (P-1) **PVC Process Wastewater Treatment System ID**

Refer to lab report

TC22799-1

**CAS No. HAP**  **An alysis Method**  **Concentration (ppmw)**  **Non-Detect?**

107211 Ethylene glycol SW-846-8015C 2 Non-detect 67561 Methanol SW-846-8015C 135 75070Acetaldehyde SW-846-8315A 3.9 50000 Formaldehyde SW-846-8315A 0.056 Non-detect 512852,4-dinitrophenol SW-846-8270D 0.2 Non-detect 98862Acetophenone SW-846-8270D 5.99 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.0838 123319 Hydroquinone SW-846-8270D 0.102 108952 Phenol SW-846-8270D 0.029 Non-detect 79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.0004 Non-detect 106990 1,3-butadiene SW-846-8260B 0.00054 Non-detect 540841 2,2,4-trimethylpentane SW-846-8260B 0.00049 Non-detect 71432 Benzene SW-846-8260B 0.00034 Non-detect 108907Chlorobenzene SW-846-8260B 0.00027 Non-detect 67663Chloroform SW-846-8260B 0.00035 Non-detect 126998Chloroprene SW-846-8260B 0.00042 Non-detect 98828Cumene SW-846-8260B 0.0033 75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.0175 100414 Ethylbenzene SW-846-8260B 0.00032 Non-detect 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.133 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.00034 Non-detect 74873 Methyl chloride (Chloromethane) SW-846-8260B 0.0036 75092 Methylene chloride SW-846-8260B 0.001 Non-detect 110543n-Hexane SW-846-8260B 0.0007 Non-detect 108883Toluene SW-846-8260B 0.00033 Non-detect 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.00043 Non-detect 79005 1,1,2-Trichloroethane SW-846-8260B 0.00035 Non-detect 108054Vinyl acetate SW-846-8260B 0.00074 Non-detect 593602Vinyl bromide SW-846-8260B 0.00025 Non-detect 75014Vinyl chloride EPA Method 107 0.1 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.00045 Non-detect 1330207Xylenes (isomers and mixtures) SW-846-8260B 0.00087 Non-detect **An alysis Date -->** 

**Lab Sample ID --> Lab Report ID -->** PC-701-D WW-01-07-2013 **Stream Temperature (degrees F) -->** 197 Estimated **Flow Rate Determination Method -->**

**Sample Date -->**01/07/13

**Stream Flow Rate (gallons per minute) -->**83.73 **Resin Type (suspension, dispersion, bulk, etc.) -->**Suspension1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s)**

J-estimated value J-estimated value Estimated **1**1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

Refer to lab report Refer to lab report

TC22862-2A TC22953-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 128 148 1 1.5 0.35 0.0056 Non-detect 0.1 Non-detect 0.21 Non-detect 1.92 2.99 0.3 0.151 0.053 J-estimated value 0.952 J-estimated value 0.015Non-detect 0.03 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00062 J-estimated value 0.00094 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.0017 0.0004 Non-detect 0.005 0.0021 0.00032 Non-detect 0.00032 Non-detect 0.00084 J-estimated value 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00063 Non-detect 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect PC-701D-WWDUPLICATE-01-08-2013 PC-701-D WW-01-09-2013 197 Estimated Estimated 197 01/08/13 01/09/13

84.62 85 Suspension Suspension **2 3** Refer to lab report Refer to lab report PC-701-D-01-10-2013 PC-701-D-01-11-2013 TC23037-1A TC23146-1A **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 119 117 0.79 2.3 0.0056 Non-detect 0.11 0.1 Non-detect 0.18 Non-detect 5.17 3.35 0.018 Non-detect 0.032 Non-detect 0.0931 J-estimated value 0.105 J-estimated value 0.0348 J-estimated value 0.027 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00056 J-estimated value 0.00064 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0028 0.0023 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00063 Non-detect 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0.1 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect Estimated Estimated 197 197 84.91 85.43 Suspension Suspension **5** 01/11/13 01/10/13 **4**Refer to lab report Refer to lab report PC-701-D-01-12-2013 PC-701-D-01-13-2013 TC23240-1 TC23296-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 105 145 3.2 3.9 0.11 0.089 0.2 Non-detect 0.2 Non-detect 1.91 10.5 0.195 0.144 0.33 0.458 0.03 Non-detect 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00065 J-estimated value 0.00069 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0352 0.0032 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00063 Non-detect 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0.1 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 197 Estimated Estimated 91.22 91.28 Suspension Suspension **7** 01/13/13 **6** 01/12/13Refer to lab report Refer to lab report PC-701-D-01-14-2013 PC-701D-WW-01-15-2013 TC23303-1 TC23376-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 112 144 1.2 3.8 0.044 0.13 J-estimated value 0.2 Non-detect 0.2 Non-detect 11.2 4.64 0.036 Non-detect 0.036 Non-detect 0.198 0.0299 J-estimated value 0.03 Non-detect 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.0051 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.00044 J-estimated value 0.0063 J-estimated value 0.0148 0.00072 Non-detect 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.0632 J-estimated value 0.00034 Non-detect 0.0015 0.00063 Non-detect 0.0458 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0.4 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 Estimated 197 Estimated 89.59 Suspension 92.74 Suspension **8** 01/14/13 **9** 01/15/13Refer to lab report Refer to lab report PC-701-D-01-16-2013 PC-701-D-01-17-2013 TC23449-1 TC23561-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 204 138 12 9.7 0.14 Non-detect 0.14 Non-detect 0.2 Non-detect 0.2 Non-detect 8.31 6.2 0.036 Non-detect 0.204 R R-rejected R R-rejected 0.029 Non-detect 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0446 0.00072 Non-detect 0.00032 Non-detect 0.00032 Non-detect 0.0031 0.696 0.00034 Non-detect 0.00034 Non-detect 0.0018 1.68 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.0036 0.00074 Non-detect 0.00094 J-estimated value 0.00025Non-detect 0.00025Non-detect 0 0.4 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 Estimated 197 Estimated 86.41 Suspension Suspension 91.66 01/17/13 **10 11**  01/16/13Refer to lab report Refer to lab report PC-701-D-01-18-2013 PC-701-D-01-19-2013 TC23651-1 TC23723-1A **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 165 177 12 16 0.14 Non-detect 0.14 Non-detect 0.4 Non-detect 0.2 Non-detect 10.5 8.77 0.0979 J-estimated value 0.036 Non-detect 0.0937 J-estimated value 0.174 J-estimated value 0.059 Non-detect 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00042 Non-detect 0.00042 Non-detect 0.00041 J-estimated value 0.0004 Non-detect 0.0473 0.09 0.00032 Non-detect 0.00032 Non-detect 0.318 0.068 0.00034 Non-detect 0.00034 Non-detect 0.228 0.176 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.0018 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.3 0.6 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 Estimated Estimated 197 86 91.81 **12 13** 

Suspension Suspension 01/18/13 01/19/13Refer to lab report Refer to lab report PC-701-D-01-20-2013 PC-701-D-01-21-2013 TC23730-1 TC23746-1A **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 170 165 10 1.3 0.14 Non-detect 0.036 0.2 Non-detect 0.01 Non-detect 11.2 0.0015 Non-detect 0.0969 J-estimated value 0.0018 Non-detect 0.0757 J-estimated value R R-rejected 0.029 Non-detect 1.2 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0069 0.0064 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.0013 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.5 0.2 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 197 Estimated Estimated 98.58 91.48 Suspension 01/20/13 Suspension 01/21/13 **14 15** Refer to lab report Refer to lab report PC-701D-WW-01-22-2013 PC-701-D-01-23-2013 TC23818-1 TC23917-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 170 133 10 13 0.28 J-estimated value 0.14 Non-detect 0.2 Non-detect 0.2 Non-detect 4.93 8.42 0.0657 J-estimated value 0.814 0.471 J-estimated value 0.0431 J-estimated value 0.029 Non-detect 0.03 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0016 0.00072 Non-detect 0.00072 Non-detect 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.0141 0.00034 Non-detect 0.00035 J-estimated value 0.007 0.0199 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.3 0.3 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 197 Estimated Estimated 95.73 01/23/13 Suspension 93.04 Suspension 01/22/13 **17 16** Refer to lab report Refer to lab report PC-701-D-01-24-2013 PC-701-D-01-25-2013 TC23978-1 TC24065-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 148 132 6.8 0.88 0.14 Non-detect 0.0056 Non-detect 0.2 Non-detect 0.2 Non-detect 7.2 6.84 0.036 Non-detect 0.124 R 0.102 J 0.029 Non-detect 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.00072 J 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0163 0.0289 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.0011 0.0045 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.2 0.2 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect Estimated Estimated 92.86

197 197 01/24/13 01/25/13 Suspension Suspension 90.13 **18 19** Refer to lab report Refer to lab report PC-701-D-01-26-2013 PC-701-D-01-27-2013 TC24134-1 TC24164-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 126 151 0.48 J J-estimated value 1.2 0.45 J J-estimated value 0.0056 Non-detect 0.2 Non-detect 0.2 Non-detect 5.5 8.87 0.0389 J-estimated value 0.036 Non-detect 0.301 J-estimated value 0.209 J-estimated value 0.0377 J-estimated value 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00071 J-estimated value 0.00087 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0012 0.0052 0.525 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.0075 0.00034 Non-detect 0.00055 J-estimated value 0.00063 Non-detect 0.0299 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0.1 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect Estimated 197 91.51

197 Suspension 01/26/13

92.2 Estimated 01/27/13 Suspension **20 21** Refer to lab report Refer to lab report PC-701-D-01-28-2013 PC-701D-WW-01-29-2013 TC24171-1A TC24224-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 142 113 0.57 1 0.094 0.19 0.2 Non-detect 0.2 Non-detect 5.3 2.99 0.0966 J-estimated value 0.239 0.657 J-estimated value 0.779 J-estimated value 0.0291 J-estimated value 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00073 J-estimated value 0.0004 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0113 0.0065 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00063 Non-detect 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0 0.2 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 85.14

197 Estimated Estimated 84.54 Suspension Suspension 01/28/13 01/29/13 **22 23** Refer to lab report Refer to lab report PC-701-D-01-10-2013 PC-701-D-01-31-2013 TC23037-1A TC24388-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 119 169 0.79 2.6 J-estimated value 0.0056 Non-detect 0.14 Non-detect 0.1 Non-detect 0.2 Non-detect 5.17 9.89 0.018 Non-detect 0.036 Non-detect 0.0931 J-estimated value 1.56 J-estimated value 0.0348 J-estimated value 0.029 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.00056 J-estimated value 0.0011 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0028 0.0077 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00063 Non-detect 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0.2 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 197 Estimated Estimated 84.57 80.82 Suspension 01/30/13 Suspension 01/31/13 **25 24** Refer to lab report Refer to lab report PC-701-D-02-01-2013 PC-701-D-02-02-2013 TC24486-1A TC24543-1A **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 156 118 5.1 3.9 0.14 Non-detect 0.14 Non-detect 0.22 Non-detect 0.21 Non-detect 5.79 5.14 0.038 Non-detect 0.037 Non-detect R R-rejected R 0.031 Non-detect 0.03 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00027 Non-detect 0.0011 0.00099 J-estimated value 0.00042 Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0004 Non-detect 0.0076 0.0067 0.00032 Non-detect 0.00032 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00034 Non-detect 0.00034 Non-detect 0.00063 Non-detect 0.00063 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00074 Non-detect 0.00025Non-detect 0.00025Non-detect 0.1 0.2 0.00045Non-detect 0.00045Non-detect 0.00087 Non-detect 0.00087 Non-detect 197 197 Estimated Estimated 80.27 80.49 02/02/13 Suspension 02/01/13 Suspension **26 27** Refer to lab report Refer to lab report PC-701-D-02-03-2013 PC-701-D-02-04-2013 TC24570-1A TC24571-1 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 2 Non-detect 141 130 3.4 1.3 0.14 Non-detect 0.033 0.12 Non-detect 0.01 Non-detect 0.0317 J-estimated value 0.0015 Non-detect 0.0227 J-estimated value 0.0018 Non-detect 0.0598 J-estimated value R R-rejected 0.018 Non-detect 0.0015 Non-detect 0.00081 Non-detect 0.0004 Non-detect 0.0011 Non-detect 0.00054 Non-detect 0.00097 Non-detect 0.00049 Non-detect 0.00068 Non-detect 0.00034 Non-detect 0.00053 Non-detect 0.00027 Non-detect 0.001 J-estimated value 0.00044 J-estimated value 0.00084 Non-detect 0.00042 Non-detect 0.0008 Non-detect 0.0004 Non-detect 0.0051 0.0014 0.00065Non-detect 0.00032 Non-detect 0.0007 Non-detect 0.00035Non-detect 0.00068 Non-detect 0.00034 Non-detect 0.0019 J-estimated value 0.00063 Non-detect 0.002 Non-detect 0.001 Non-detect 0.0014 Non-detect 0.0007 Non-detect 0.00065Non-detect 0.00033 Non-detect 0.00086 Non-detect 0.00043 Non-detect 0.00069 Non-detect 0.00035Non-detect 0.0015 Non-detect 0.00074 Non-detect 0.0005 Non-detect 0.00025Non-detect 0.1 0.1 0.0009 Non-detect 0.00045Non-detect 0.0017 Non-detect 0.00087 Non-detect 197 197 Estimated Estimated Suspension 82.92 81.97 02/03/13 02/04/13 Suspension **28 29** Refer to lab report PC-701-D-02-05-2013 TC24663-1 **Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 117 0.26 0.037 0.15Non-detect 2.56 0.176 0.0786 J-estimated value 0.022 Non-detect 0.0004 Non-detect 0.00054 Non-detect 0.00049 Non-detect 0.00034 Non-detect 0.00027 Non-detect 0.00035Non-detect 0.00042 Non-detect 0.0004 Non-detect 0.0303 0.00032 Non-detect 0.00055 J-estimated value 0.00034 Non-detect 0.0057 0.0162 J-estimated value 0.0007 Non-detect 0.00033 Non-detect 0.00043 Non-detect 0.00035Non-detect 0.00074 Non-detect 0.00025Non-detect 0.1 0.00045Non-detect 0.00087 Non-detect 85.75

197 Estimated 02/05/13 Suspension **30**