November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City: State: New Jersey Zip Code: 7039

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments owned): >1500

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City: State: Texas Zip Code: 77978

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 44

9 Peach Tree Hill Road

Formosa Plastics Corp. USA

361-987-7806

Mstricklin@ftpc.fpcusa.com

PVC (P-1)

201 Formosa Dr.

Point Comfort

Mark Stricklin

Livingston 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

Form C-1-c Supplemental Questions

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 26,074.55 liters/hour

 liters

Process Unit ID: P-1

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

Process Equipment ID: U-14

Wastewater Feed Rate (lb/hr): 42,500 38,187.16 liters/hour (max design)

Feed Temperature (°F): 185 liters (max design)

Feed Inlet Pressure (psia): 5.6

Liquid Loading Rate (liters/m2): 321.76

Steam Feed Rate (lb/hr): 4200

Steam to Feed Ratio (kg steam/liter of wastewater): 1:10

Operating Temperature (°F): 195

Operating Pressure (psig): 0

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent): countercurrent

Number of Actual Trays: 40

Column Height (meters): 25

Year Equipment Installed: 1980

Equipment Currently Regulated Under (cite regulations): VCM NESHAPS

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary 

below.
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1 U-10 97,200 162,000 135,000 Estimated 365 PS-501A~J PVC Dryer Centrifuge WWT Combined Waste Water Treatment Yes

P-1 U-11 302,400 421,200 410,400 Estimated 365 PS-501K~R PVC Dryer Centrifuge WWT Combined Waste Water Treatment Yes

Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1 PC-701D Steam Stripping Continuous U-14 115588.8 141955.2 128772 Estimated 365 WWT Combined Waste Water Treatment Yes

Table 3. PVC Process Wastewater Destination Codes Table

Code

Wastewater treatment system WWT Provide name of the wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall

Discharge to POTW, no treatment POTWRAW Provide name of POTW

Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW

Zero discharge or alternative disposal method ZEROALT Describe method

Recycle to process RECYC Describe where in the process the stream is recycled

Other OTHER Describe

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2 3 4 5 6 7

Min Max Average

PVC Process 

Unit ID

Flow Rate 

Determination 

Method

 None

Operating Days 

Per Year

Destination Description Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

Source of Process Wastewater Stream

Process Wastewater Stream Flow Rate 

(gallons per day)

PVC Process 

Wastewater 

Treatment 

System ID

1

Flow Rate 

Determination 

Method

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process 

equipment and its destination?

Dryer centrifuge waste water

PVC Process Wastewater Stream Flow Rate 

(gallons per day) Associated Destination 

Information

Originating PVC Process 

Equipment ID

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Originating PVC Process 

Equipment Description

Flow Rate 

Determination 

Method

Operating Days Per 

Year

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or 

continuous 

operation?

Type of Process 

Wastewater 

Treatment System

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

Dryer centrifuge waste water

2

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 

below)

14

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Operating Days 

Per Year

PVC Process 

Wastewater 

Stream ID

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

Associated Destination 

Information

(Refer to Table 3 below)

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make co

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Ente

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Formosa Plastics Corp. USA

Facility PVC (P-1)

PVC Process Wastewater Treatment System ID

Refer to lab report

TC22799-1

CAS No. HAP Analysis Method Concentration 

(ppmw) Non-Detect?

107211 Ethylene glycol SW-846-8015C 2 Non-detect

67561 Methanol SW-846-8015C 135

75070 Acetaldehyde SW-846-8315A 3.9

50000 Formaldehyde SW-846-8315A 0.056 Non-detect

51285 2,4-dinitrophenol SW-846-8270D 0.2 Non-detect

98862 Acetophenone SW-846-8270D 5.99

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.0838

123319 Hydroquinone SW-846-8270D 0.102

108952 Phenol SW-846-8270D 0.029 Non-detect

79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.0004 Non-detect

106990 1,3-butadiene SW-846-8260B 0.00054 Non-detect

540841 2,2,4-trimethylpentane SW-846-8260B 0.00049 Non-detect

71432 Benzene SW-846-8260B 0.00034 Non-detect

108907 Chlorobenzene SW-846-8260B 0.00027 Non-detect

67663 Chloroform SW-846-8260B 0.00035 Non-detect

126998 Chloroprene SW-846-8260B 0.00042 Non-detect

98828 Cumene SW-846-8260B 0.0033

75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.0175

100414 Ethylbenzene SW-846-8260B 0.00032 Non-detect

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.133

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.00034 Non-detect

74873 Methyl chloride (Chloromethane) SW-846-8260B 0.0036

75092 Methylene chloride SW-846-8260B 0.001 Non-detect

110543 n-Hexane SW-846-8260B 0.0007 Non-detect

108883 Toluene SW-846-8260B 0.00033 Non-detect

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.00043 Non-detect

79005 1,1,2-Trichloroethane SW-846-8260B 0.00035 Non-detect

108054 Vinyl acetate SW-846-8260B 0.00074 Non-detect

593602 Vinyl bromide SW-846-8260B 0.00025 Non-detect

75014 Vinyl chloride EPA Method 107 0.1

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.00045 Non-detect

1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.00087 Non-detect

Analysis Date -->

Lab Sample ID -->

Lab Report ID --> PC-701-D WW-01-07-2013

Stream Temperature (degrees F) --> 197

Flow Rate Determination Method --> Estimated

Sample Date --> 01/07/13

Stream Flow Rate (gallons per minute) --> 83.73

Resin Type (suspension, dispersion, bulk, etc.) --> Suspension
m that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

must match the IDs listed in Table 2 of the "Stream Info" worksheet.

ation, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

ection limit, in ppmw, in the "Concentration (ppmw)" column.

Note(s)

J-estimated value

J-estimated value

Estimated

1
mplete one worksheet for each single stream (make copies of this worksheet if necessary).

, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

Refer to lab report Refer to lab report

TC22862-2A TC22953-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

128 148

1 1.5

0.35 0.0056 Non-detect

0.1 Non-detect 0.21 Non-detect

1.92 2.99

0.3 0.151

0.053 J-estimated value 0.952 J-estimated value

0.015 Non-detect 0.03 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00062 J-estimated value 0.00094 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.0017 0.0004 Non-detect

0.005 0.0021

0.00032 Non-detect 0.00032 Non-detect

0.00084 J-estimated value 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00063 Non-detect 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

PC-701D-WW DUPLICATE-01-08-2013 PC-701-D WW-01-09-2013

197

Estimated Estimated

197

01/08/13 01/09/13

84.62 85

Suspension Suspension

2 3
Refer to lab report Refer to lab report

PC-701-D-01-10-2013 PC-701-D-01-11-2013

TC23037-1A TC23146-1A

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

119 117

0.79 2.3

0.0056 Non-detect 0.11

0.1 Non-detect 0.18 Non-detect

5.17 3.35

0.018 Non-detect 0.032 Non-detect

0.0931 J-estimated value 0.105 J-estimated value

0.0348 J-estimated value 0.027 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00056 J-estimated value 0.00064 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0028 0.0023

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00063 Non-detect 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0.1

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

Estimated Estimated

197 197

84.91 85.43

Suspension Suspension

5

01/10/13 01/11/13

4
Refer to lab report Refer to lab report

PC-701-D-01-12-2013 PC-701-D-01-13-2013

TC23240-1 TC23296-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

105 145

3.2 3.9

0.11 0.089

0.2 Non-detect 0.2 Non-detect

1.91 10.5

0.195 0.144

0.33 0.458

0.03 Non-detect 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00065 J-estimated value 0.00069 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0352 0.0032

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00063 Non-detect 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0.1

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197 197

Estimated Estimated

91.22 91.28

Suspension Suspension

7

01/13/13

6

01/12/13
Refer to lab report Refer to lab report

PC-701-D-01-14-2013 PC-701D-WW-01-15-2013

TC23303-1 TC23376-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

112 144

1.2 3.8

0.044 0.13 J-estimated value

0.2 Non-detect 0.2 Non-detect

11.2 4.64

0.036 Non-detect 0.036 Non-detect

0.198 0.0299 J-estimated value

0.03 Non-detect 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00035 Non-detect 0.0051 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.00044 J-estimated value 0.0063 J-estimated value

0.0148 0.00072 Non-detect

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.0632 J-estimated value

0.00034 Non-detect 0.0015

0.00063 Non-detect 0.0458

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0.4

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197

Estimated

197

Estimated

89.59

Suspension

92.74

Suspension

8

01/14/13

9

01/15/13
Refer to lab report Refer to lab report

PC-701-D-01-16-2013 PC-701-D-01-17-2013

TC23449-1 TC23561-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

204 138

12 9.7

0.14 Non-detect 0.14 Non-detect

0.2 Non-detect 0.2 Non-detect

8.31 6.2

0.036 Non-detect 0.204

R R-rejected R R-rejected 

0.029 Non-detect 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0446 0.00072 Non-detect

0.00032 Non-detect 0.00032 Non-detect

0.0031 0.696

0.00034 Non-detect 0.00034 Non-detect

0.0018 1.68

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.0036

0.00074 Non-detect 0.00094 J-estimated value

0.00025 Non-detect 0.00025 Non-detect

0 0.4

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197

Estimated

197

Estimated

86.41

Suspension Suspension

91.66

01/17/13

10 11

01/16/13
Refer to lab report Refer to lab report

PC-701-D-01-18-2013 PC-701-D-01-19-2013

TC23651-1 TC23723-1A

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

165 177

12 16

0.14 Non-detect 0.14 Non-detect

0.4 Non-detect 0.2 Non-detect

10.5 8.77

0.0979 J-estimated value 0.036 Non-detect

0.0937 J-estimated value 0.174 J-estimated value

0.059 Non-detect 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00042 Non-detect 0.00042 Non-detect

0.00041 J-estimated value 0.0004 Non-detect

0.0473 0.09

0.00032 Non-detect 0.00032 Non-detect

0.318 0.068

0.00034 Non-detect 0.00034 Non-detect

0.228 0.176

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.0018 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.3 0.6

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197

Estimated Estimated

197

86 91.81

12 13

Suspension Suspension

01/18/13 01/19/13
Refer to lab report Refer to lab report

PC-701-D-01-20-2013 PC-701-D-01-21-2013

TC23730-1 TC23746-1A

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

170 165

10 1.3

0.14 Non-detect 0.036

0.2 Non-detect 0.01 Non-detect

11.2 0.0015 Non-detect

0.0969 J-estimated value 0.0018 Non-detect

0.0757 J-estimated value R R-rejected 

0.029 Non-detect 1.2

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0069 0.0064

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.0013 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.5 0.2

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197 197

Estimated Estimated

91.48 98.58

Suspension

01/20/13

Suspension

01/21/13

14 15
Refer to lab report Refer to lab report

PC-701D-WW-01-22-2013 PC-701-D-01-23-2013

TC23818-1 TC23917-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

170 133

10 13

0.28 J-estimated value 0.14 Non-detect

0.2 Non-detect 0.2 Non-detect

4.93 8.42

0.0657 J-estimated value 0.814

0.471 J-estimated value 0.0431 J-estimated value

0.029 Non-detect 0.03 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0016

0.00072 Non-detect 0.00072 Non-detect

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.0141

0.00034 Non-detect 0.00035 J-estimated value

0.007 0.0199

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.3 0.3

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197 197

Estimated Estimated

95.73

01/23/13

Suspension

93.04

Suspension

01/22/13

16 17
Refer to lab report Refer to lab report

PC-701-D-01-24-2013 PC-701-D-01-25-2013

TC23978-1 TC24065-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

148 132

6.8 0.88

0.14 Non-detect 0.0056 Non-detect

0.2 Non-detect 0.2 Non-detect

7.2 6.84

0.036 Non-detect 0.124

R 0.102 J

0.029 Non-detect 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00035 Non-detect 0.00072 J

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0163 0.0289

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.0011 0.0045

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.2 0.2

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

Estimated Estimated

92.86

197 197

01/24/13 01/25/13

Suspension Suspension

90.13

18 19
Refer to lab report Refer to lab report

PC-701-D-01-26-2013 PC-701-D-01-27-2013

TC24134-1 TC24164-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

126 151

0.48 J J-estimated value 1.2

0.45 J J-estimated value 0.0056 Non-detect

0.2 Non-detect 0.2 Non-detect

5.5 8.87

0.0389 J-estimated value 0.036 Non-detect

0.301 J-estimated value 0.209 J-estimated value

0.0377 J-estimated value 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00071 J-estimated value 0.00087 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0012

0.0052 0.525

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.0075

0.00034 Non-detect 0.00055 J-estimated value

0.00063 Non-detect 0.0299

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0.1

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

Estimated

197

91.51

197

Suspension

01/26/13

92.2

Estimated

01/27/13

Suspension

20 21
Refer to lab report Refer to lab report

PC-701-D-01-28-2013 PC-701D-WW-01-29-2013

TC24171-1A TC24224-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

142 113

0.57 1

0.094 0.19

0.2 Non-detect 0.2 Non-detect

5.3 2.99

0.0966 J-estimated value 0.239

0.657 J-estimated value 0.779 J-estimated value

0.0291 J-estimated value 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00073 J-estimated value 0.0004 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0113 0.0065

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00063 Non-detect 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0 0.2

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197

85.14

197

Estimated Estimated

84.54

Suspension Suspension

01/28/13 01/29/13

22 23
Refer to lab report Refer to lab report

PC-701-D-01-10-2013 PC-701-D-01-31-2013

TC23037-1A TC24388-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

119 169

0.79 2.6 J-estimated value

0.0056 Non-detect 0.14 Non-detect

0.1 Non-detect 0.2 Non-detect

5.17 9.89

0.018 Non-detect 0.036 Non-detect

0.0931 J-estimated value 1.56 J-estimated value

0.0348 J-estimated value 0.029 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.00056 J-estimated value 0.0011

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0028 0.0077

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00063 Non-detect 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0.2

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197 197

Estimated Estimated

84.57 80.82

Suspension

01/30/13

Suspension

01/31/13

24 25
Refer to lab report Refer to lab report

PC-701-D-02-01-2013 PC-701-D-02-02-2013

TC24486-1A TC24543-1A

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

156 118

5.1 3.9

0.14 Non-detect 0.14 Non-detect

0.22 Non-detect 0.21 Non-detect

5.79 5.14

0.038 Non-detect 0.037 Non-detect

R R-rejected R

0.031 Non-detect 0.03 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.00054 Non-detect 0.00054 Non-detect

0.00049 Non-detect 0.00049 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.0011 0.00099 J-estimated value

0.00042 Non-detect 0.00042 Non-detect

0.0004 Non-detect 0.0004 Non-detect

0.0076 0.0067

0.00032 Non-detect 0.00032 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00034 Non-detect 0.00034 Non-detect

0.00063 Non-detect 0.00063 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00043 Non-detect 0.00043 Non-detect

0.00035 Non-detect 0.00035 Non-detect

0.00074 Non-detect 0.00074 Non-detect

0.00025 Non-detect 0.00025 Non-detect

0.1 0.2

0.00045 Non-detect 0.00045 Non-detect

0.00087 Non-detect 0.00087 Non-detect

197 197

Estimated Estimated

80.49 80.27

02/02/13

Suspension

02/01/13

Suspension

26 27
Refer to lab report Refer to lab report

PC-701-D-02-03-2013 PC-701-D-02-04-2013

TC24570-1A TC24571-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

2 Non-detect 2 Non-detect

141 130

3.4 1.3

0.14 Non-detect 0.033

0.12 Non-detect 0.01 Non-detect

0.0317 J-estimated value 0.0015 Non-detect

0.0227 J-estimated value 0.0018 Non-detect

0.0598 J-estimated value R R-rejected

0.018 Non-detect 0.0015 Non-detect

0.00081 Non-detect 0.0004 Non-detect

0.0011 Non-detect 0.00054 Non-detect

0.00097 Non-detect 0.00049 Non-detect

0.00068 Non-detect 0.00034 Non-detect

0.00053 Non-detect 0.00027 Non-detect

0.001 J-estimated value 0.00044 J-estimated value

0.00084 Non-detect 0.00042 Non-detect

0.0008 Non-detect 0.0004 Non-detect

0.0051 0.0014

0.00065 Non-detect 0.00032 Non-detect

0.0007 Non-detect 0.00035 Non-detect

0.00068 Non-detect 0.00034 Non-detect

0.0019 J-estimated value 0.00063 Non-detect

0.002 Non-detect 0.001 Non-detect

0.0014 Non-detect 0.0007 Non-detect

0.00065 Non-detect 0.00033 Non-detect

0.00086 Non-detect 0.00043 Non-detect

0.00069 Non-detect 0.00035 Non-detect

0.0015 Non-detect 0.00074 Non-detect

0.0005 Non-detect 0.00025 Non-detect

0.1 0.1

0.0009 Non-detect 0.00045 Non-detect

0.0017 Non-detect 0.00087 Non-detect

197 197

Estimated Estimated

Suspension

81.97 82.92

02/03/13 02/04/13

Suspension

28 29
Refer to lab report

PC-701-D-02-05-2013

TC24663-1

Concentration 

(ppmw) Non-Detect? Note(s)

2 Non-detect

117

0.26

0.037

0.15 Non-detect

2.56

0.176

0.0786 J-estimated value

0.022 Non-detect

0.0004 Non-detect

0.00054 Non-detect

0.00049 Non-detect

0.00034 Non-detect

0.00027 Non-detect

0.00035 Non-detect

0.00042 Non-detect

0.0004 Non-detect

0.0303

0.00032 Non-detect

0.00055 J-estimated value

0.00034 Non-detect

0.0057

0.0162 J-estimated value

0.0007 Non-detect

0.00033 Non-detect

0.00043 Non-detect

0.00035 Non-detect

0.00074 Non-detect

0.00025 Non-detect

0.1

0.00045 Non-detect

0.00087 Non-detect

85.75

197

Estimated

02/05/13

Suspension

30