Control Option

H2SO4 

Emissions 

(ppm)

Filterable 

Particulate 

Emissions 

(lbs/MMBtu)

H2SO4 

Emissions 

(ppm)

Filterable 

Particulate 

Emissions 

(lbs/MMBtu)

Baseline level 17.7 0.110 17.6 0.038

Lime Injection 7.0 0.110 7.0 0.038

Wet ESP 1.8 0.015 1.8 0.015

H2SO4 

Emissions 

Filterable 

Particulate 

Emissions 

PAF BART Modeling Matrix

Unit 1 or 2 Unit 3

PAF BART Alternatives

Run Unit

Emissions 

(ppm)

Emissions 

(lbs/MMBtu)

1 1or 2 17.7 0.11

2 1or 2 7.0 0.11

3 1or 2 1.8 0.015

4 1or 2 1.8 0.03

5 3 17.6 0.038

6 3 7 0.038

7 3 1.8 0.015

Notes:

* BART exemption modeling is done for entire source, but BART determinations are made

 on a unit-by-unit basis.

* Units 1 and 2 are nearly identical, so they do not have to be modeled separately.

* Run 4 is a test cast to see if the PM removal performance of the wet ESP has a significant impact on visibility.

Nomenclature on worksheet tabs is: unit:run as designated in cells A12 through B19.
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 57% 43% 93% 7%

(g/s) 112 63.20 48.58 45.08 3.51

45.08

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 11.15 11.1531

PM425 2.50-6.00 29.4% 18.59 18.5892

PM187 1.25-2.50 20.6% 13.01 12.5307 0.4814

PM112 1.00-1.25 7.4% 4.65 4.4751 0.1719

PM081 0.625-1.00 23.0% 14.56 14.0233 0.5388 1.7539 0.625-1.00

PM056 0.50-0.625 2.0% 1.24 1.1922 0.0458 1.7539 0.50-0.625

1.00 Total 63.2 g/s

total 100.00 63.20 29.7 32.2 1.24 45.1 3.51 112

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.53

coarse

fine

PAF1-Table 1B (Unit 1 Run 1)

FILTERABLE CONDENSABLE

0.47

0900006480f84952.xls, PAF1-1 printed: 12/16/2011 1/1
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 75% 25% 84% 16%

(g/s) 84.511 63.20 21.31 17.80 3.51

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 11.15 11.1531

PM425 2.50-6.00 29.4% 18.59 18.5892

PM187 1.25-2.50 20.6% 13.01 12.5307 0.4814

PM112 1.00-1.25 7.4% 4.65 4.4751 0.1719

PM081 0.625-1.00 23.0% 14.56 14.0233 0.5388 1.7540 0.625-1.00

PM056 0.50-0.625 2.0% 1.24 1.1922 0.0458 1.7540 0.50-0.625

1.00 Total 63.2 g/s

total 100% 63.20 29.74 32.22 1.24 17.80 3.51 84.511

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.52940618

coarse

fine

PAF1-Table 2B (Unit 1 Run 2)

FILTERABLE CONDENSABLE

0.47059382

0900006480f84952.xls, PAF1-2 printed: 12/16/2011 1/1
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 53% 47% 57% 43%

(g/s) 17.029 8.94 8.09 4.58 3.51

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 1.58 1.5781

PM425 2.50-6.00 29.4% 2.63 2.6302

PM187 1.25-2.50 20.6% 1.84 1.7730 0.0681

PM112 1.00-1.25 7.4% 0.66 0.6337 0.0243

PM081 0.625-1.00 23.0% 2.06 1.9849 0.0763 1.7538 0.625-1.00

PM056 0.50-0.625 2.0% 0.18 0.1685 0.0065 1.7538 0.50-0.625

1.00 Total 8.9 g/s

total 100% 8.94 4.21 4.56 0.18 4.58 3.51 17.029

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.529464386

coarse

fine

PAF1-Table 3B (Unit 1 Run 3)

FILTERABLE CONDENSABLE

0.470535614

0900006480f84952.xls, PAF1-3 printed: 12/16/2011 1/1
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 69% 31% 57% 43%

(g/s) 25.972 17.89 8.09 4.58 3.51

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 3.16 3.1570

PM425 2.50-6.00 29.4% 5.26 5.2610

PM187 1.25-2.50 20.6% 3.68 3.5467 0.1363

PM112 1.00-1.25 7.4% 1.31 1.2663 0.0487

PM081 0.625-1.00 23.0% 4.12 3.9685 0.1525 1.7538 0.625-1.00

PM056 0.50-0.625 2.0% 0.35 0.3370 0.0129 1.7538 0.50-0.625

1.00 Total 17.9 g/s

total 100% 17.89 8.42 9.12 0.35 4.58 3.51 25.972

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.529378879

coarse

fine

PAF1-Table 4B (Unit 1 Run 4)

FILTERABLE CONDENSABLE

0.470621121

0900006480f84952.xls, PAF1-4 printed: 12/16/2011 1/1
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 32% 68% 93% 7%

(g/s) 117 37.30 79.48 73.70 5.77

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 6.58 6.5827

PM425 2.50-6.00 29.4% 10.97 10.9705

PM187 1.25-2.50 20.6% 7.68 7.3955 0.2841

PM112 1.00-1.25 7.4% 2.74 2.6414 0.1015

PM081 0.625-1.00 23.0% 8.59 8.2766 0.3180 2.8870 0.625-1.00

PM056 0.50-0.625 2.0% 0.73 0.7039 0.0270 2.8870 0.50-0.625

1.00 Total 37.3 g/s

total 100.00 37.30 17.55 19.02 0.731 73.70 5.77 117

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.53

coarse

fine

PAF3-Table 1B (Unit 3 Run 5)

FILTERABLE CONDENSABLE

0.47

0900006480f84952.xls, PAF3-5 printed: 12/16/2011 1/1
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 52% 48% 84% 16%

(g/s) 72.385 37.30 35.08 29.31 5.77

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 6.58 6.5827

PM425 2.50-6.00 29.4% 10.97 10.9705

PM187 1.25-2.50 20.6% 7.68 7.3955 0.2841

PM112 1.00-1.25 7.4% 2.74 2.6414 0.1015

PM081 0.625-1.00 23.0% 8.59 8.2766 0.3180 2.8871 0.625-1.00

PM056 0.50-0.625 2.0% 0.73 0.7039 0.0270 2.8871 0.50-0.625

1.00 Total 37.3 g/s

total 100% 37.30 17.55 19.02 0.73 29.31 5.77 72.385

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.529421226

coarse

fine

PAF3-Table 2B (Unit 3 Run 6)

FILTERABLE CONDENSABLE

0.470578774

0900006480f84952.xls, PAF3-6 printed: 12/16/2011 1/1
blue = input

condensable split

total filterable condensable H2SO4

condensable - 

H2SO4

(lb/mmBTU)

% 53% 47% 57% 43%

(g/s) 28.035 14.72 13.31 7.54 5.77

fine filterable

96.30% 3.70%

Geometric 

Mass Mean 

Diameter filterable

coarse 

filterable 

inorganic

inorganic 

(96.3% of 

fine filterable)

elemental 

carbon (3.7% 

of fine 

filterable) H2SO4

organic 

condensable

Geometric 

Mass Mean 

Diameter 

(μm) % (g/s) (g/s) (g/s) (g/s) (g/s) (g/s) (μm)

PM800 6.00 - 10.00 17.6% 2.60 2.5980

PM425 2.50-6.00 29.4% 4.33 4.3311

PM187 1.25-2.50 20.6% 3.03 2.9189 0.1121

PM112 1.00-1.25 7.4% 1.08 1.0429 0.0401

PM081 0.625-1.00 23.0% 3.39 3.2675 0.1255 2.8872 0.625-1.00

PM056 0.50-0.625 2.0% 0.29 0.2773 0.0107 2.8872 0.50-0.625

1.00 Total 14.7 g/s

total 100% 14.72 6.93 7.51 0.29 7.54 5.77 28.035

PMC SOIL EC H2SO4 SOA

Ext. coefficient 0.6 1 10 3*f(RH) 4

0.52940777

coarse

fine

PAF3-Table 3B (Unit 3 Run 7)

FILTERABLE CONDENSABLE

0.47059223

0900006480f84952.xls, PAF3-7 printed: 12/16/2011 1/1