Zinc Safety Data Sheet

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Format: GHS Revised: April 23, 2015

Language: English (US) Version 2

1.1 Product Identifier

Product Name: Zinc

Product Form: Solid 

Chemical Family: Metal

CAS Number: 7440-66-6

Molecular Formula: Zn

Molecular Weight: 65.39

1.2 Other Means of Identification

Synonyms: Zinc Element, Zinc Metal, UN 1436, ZN, DLA25228, RTECS ZG8600000

1.3 Recommended Uses

Recommended Use: Variety of laboratory, mechanical, and industrial applications

1.4 Manufacturer, Importer, or Responsible Party

Responsible Party: Defense Logistics Agency Strategic Materials

8725 John J. Kingman Road

Fort Belvoir, Virginia 22060

(703) 767-5525

1.5 Emergency Phone Number

Emergency Phone Number: (800) 424-9300 (CHEMTREC)

(703) 527-3887 (CHEMTREC INTERNATIONAL)

2.1 Classification of Chemical per OSHA CFR 1910.1200

Skin Irritation: Category 2

Eye Irritation: Category 2B

Respiratory Sensitization: Category 1B

2.2 Label Elements

Signal Word: DANGER

Symbol(s):

Hazard Statements: Causes skin and eye irritation. May cause allergy or asthma symptoms or 

breathing difficulties if inhaled.

Section 1: Identification

Section 2: Hazard(s) Identification

Zinc

Safety Data Sheet
Zinc Safety Data Sheet

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Format: GHS Revised: April 23, 2015

Language: English (US) Version 2

Precautionary Statements: Prevention: Wear protective gloves. Wash exposed skin thoroughly after 

handling. Avoid breathing dust. In case of inadequate ventilation, wear 

respiratory protection

Response: If on skin, wash with plenty of water. If skin irritation occurs, get 

medical advice and/or attention. Take off contaminated clothing and wash it 

before reuse. If in eyes, rinse cautiously with water for several minutes. 

Remove contact lenses, if present and easy to do. Continue rinsing. If eye 

irritation persists, get medical advice and/or attention. If inhaled and breathing 

is difficult, remove person to fresh air and keep comfortable for breathing. If 

experiencing respiratory symptoms, call a doctor.

Storage: No specific storage requirements.

Disposal: Dispose of contents and container in accordance with all federal, 

state, and local regulations.

2.3 Other Hazards

Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode.

2.4 Unknown Acute Toxicity

Does not apply to this product.

3.1 Chemical Name 

Chemical Name: Zinc

Formula: Zn

Composition: 100%

Molecular Weight: 65.39 g/mol

3.2 Common Names/Synonyms

Synonyms: See Section 1.2 for common names and synonyms.

3.3 CAS Number/Unique Identifiers

CAS Number: 7440-66-6

EIN Number (EINECS): 231-175-3

3.4 Impurities/Stabilizing Additives

No data available.

4.1 Description of First-Aid Measures

Inhalation: If adverse effects occur, remove to uncontaminated area. Give artificial 

respiration if not breathing. Get immediate medical attention.

Skin Contact: Remove contaminated clothing. Wash skin with soap and water for at least 15 

minutes. Get medical attention, if needed. Thoroughly clean and dry 

contaminated clothing and shoes before reuse.

Eye Contact: In case of contact or suspected contact, flush eyes with plenty of water for at 

least 15 minutes. Remove contacts/glasses while flushing. Get immediate 

medical attention.

Ingestion: If swallowed, get medical attention.

4.2 Most Important Symptoms/Effects, both Acute and Delayed

Inhalation (Acute): Irritation, nausea, vomiting, diarrhea, difficulty breathing, headache.

Inhalation (Chronic): Digestive disorders.

Eye Contact (Acute): Irritation (possibly severe), tearing.

Eye Contact (Chronic): Not known.

Skin Contact (Acute): Irritation (possibly severe)

Skin Contact (Chronic): No information on significant adverse effects.

Section 3: Composition / Information on Ingredients

Section 4: First-Aid Measures
Zinc Safety Data Sheet

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Language: English (US) Version 2

Ingestion (Acute): Nausea, diarrhea, stomach pain, dizziness, hyperactivity or drowsiness, 

kidney damage.

Ingestion (Chronic): Hair loss, headache, hyperactivity, lung damage, kidney damage, liver 

damage.

4.3 Indication of immediate Medical Attention/Special Treatment

Antidote: Calcium disodium edetate/dextrose, intravenous; calcium disodium 

edetate/procaine, intramuscular.

5.1 Suitable Extinguishing Media

Dolomite, dry powder for metal fires, dry sand, graphite, soda ash, sodium chloride. Burning zinc reacts chemically with 

Halon and CO2 gas extinguishers. Do not get water directly on material.

5.2 Specific Hazards

Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode. Zinc powder or dust in contact 

with water or damp air evolves hydrogen. The heat of reaction is sufficient that the hydrogen may ignite.

5.3 Special Protective Equipment and Precautions

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is 

out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned 

hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep 

unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Use extinguishing agents appropriate 

for surrounding fire. Avoid inhalation of material or combustion by-products.

6.1 Personal Precautions, Protective Equipment, and Emergency Procedures

Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or 

equal to RQ (US SARA Section 304). If release occurs in the US and is reportable under CERCLA Section 103, notify 

the National Response Center at (800)-424-8802 or (202)-426-2675. Regulatory information is described in Section 

15.0.

6.2 Methods and Materials for Containment and Cleaning Up

As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for 

liquids and at least 25 meters (75 feet) for solids. Eliminate all ignition sources. Do not get water on spilled substance. 

Keep unauthorized personnel away. Stay upwind, keep out of low areas, and ventilate the area before entry. Cover 

with dry earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with 

rain. Sweep spilled substance into containers, and then remove to safe place. Personal protection: self-contained 

breathing apparatus. Personal protective equipment is discussed in Section 8.3.

Small Spill

 Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize 

spreading or contact with rain.

 Dike for later disposal; do not apply water unless directed to do so.

Powder Spill

 Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.

 DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.

7.1 Precautions for Safe Handling

Handle in accordance with all current regulations and standards. 

Section 5: Fire Fighting Measures

Section 6: Accidental Release Measures

Section 7: Handling and Storage
Zinc Safety Data Sheet

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7.2 Conditions for Safe Storage

Store in accordance with all current regulations and standards. Finely divided zinc compounds, can be fire and 

explosion hazard if stored in damp places, or sources of spontaneous combustion. Store the metal in a cool, dry place, 

and keep residues thoroughly wet until disposal. Hydrogen is evolved, especially under acid and alkaline conditions. 

Protect from physical damage. Store in a well-ventilated area. Keep separated from incompatible substances. 

Incompatible materials are identified in Section 10.5.

8.1 Exposure Limits

As Zinc Oxide:

OSHA TWA (Respirable dust fraction) 5 mg/m3

OSHA TWA (Total dust) 15 mg/m3

OSHA TWA (Total particulate) 10 mg/m3 (Vacated by 58 FR 35338, June 30, 1993)

OSHA TWA (Fume) 5 mg/m3

OSHA STEL (Fume) 10 mg/m3(Vacated by 58 FR 35338, June 30, 1993)

ACGIH TWA (Respirable fraction) 2 mg/m3

ACGIH STEL (Respirable fraction) 10 mg/m3

NIOSH REL TWA 10 hour(s) (Fume) 5 mg/m3 (Also dust)

NIOSH REL Ceiling (Dust) 15 mg/m3

NIOSH REL STEL (Fume) 5 mg/m3

DFG MAK (Respirable fraction) 1 mg/m3(Peak limitation category – I, with excursion factor of 1 (Also fume))

8.2 Appropriate Engineering Controls

Ventilation: Provide local exhaust ventilation system. Ensure compliance with applicable 

exposure limits.

8.3 Individual Protection Measures

Eye Protection: Eye protection not required under normal conditions.

Clothing: Protective clothing is not required under normal conditions.

Gloves: Wear protective gloves.

Respirator: The following respirators and maximum use concentrations are drawn from 

NIOSH and/or OSHA:

50 mg/m3 1. Any particulate respirator equipped with an N95, R95, or P95 filter (including 

N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The 

following filters may also be used: N99, R99, P99, N100, R100, P100.

2. Any supplied-air respirator.

125 mg/m3 1. Any supplied-air respirator operated in a continuous-flow mode.

2. Any powered, air-purifying respirator with a high-efficiency particulate filter.

250 mg/m3 1. Any air-purifying, full-facepiece respirator equipped with an N100, R100, or 

P100 filter.

2. Any supplied-air respirator with a tight-fitting facepiece that is operated in a 

continuous-flow mode.

3. Any powered, air-purifying respirator with a tight-fitting facepiece and a 

high-efficiency particulate filter.

4. Any self-contained breathing apparatus with a full facepiece.

5. Any supplied-air respirator with a full facepiece.

500 mg/m3 1. Any supplied-air respirator operated in a pressure-demand or other 

positive-pressure mode.

Unknown Concentrations/IDLH: 1. Any self-contained breathing apparatus that has a full facepiece and is

operated in a pressure-demand or other positive-pressure mode.

Section 8: Exposure Controls / Personal Protection
Zinc Safety Data Sheet

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Language: English (US) Version 2

2. Any supplied-air respirator with a full facepiece that is operated in a 

pressure-demand or other positive-pressure mode in combination with an 

auxiliary self-contained breathing apparatus operated in pressure-demand or 

other positive-pressure mode.

Escape: 1. Any air-purifying, full facepiece respirator equipped with an N100, R100, or 

P100 filter.

2. Any appropriate escape-type, self-contained breathing apparatus.

9.1 Appearance

Physical State: Solid

Physical Description: Bluish-white lustrous metal in pig, ingot, or tub form which may develop a white 

carbonate coating on exposure to moist air.

9.2 Odor

Odorless.

9.3 Odor Threshold

Not applicable.

9.4 pH

Not applicable.

9.5 Melting/Freezing Points

Melting Point: 420oC (788oF)

Freezing Point: No data available.

9.6 Initial Boiling Point and Boiling Range

Boiling Point: 907oC (1,665oF)

9.7 Flash Point

Not determined.

9.8 Evaporation Rate

Not applicable.

9.9 Flammability

No data available.

9.10 Upper/Lower Explosive Limits

Lower Explosive Limit: 0.5 oz/ft3

9.11 Vapor Pressure

Water = 1: 1mmHg @ 487oC

9.12 Vapor Density

No data available.

9.13 Relative Density

Water = 1: 7.14

9.14 Solubility(ies)

Soluble: Acids and Alkalies

Insoluble: Water

Section 9: Physical and Chemical Properties
Zinc Safety Data Sheet

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9.15 Partition Coefficient

No data available.

9.16 Auto-Ignition Temperature

No data available.

9.17 Decomposition Temperature

No data available.

9.18 Viscosity

No data available.

10.1 Reactivity

Produces flammable gases on contact with water. May ignite on contact with water or moist air. May be ignited by 

heat, sparks, or flames. May re-ignite after fire is extinguished.

10.2 Chemical Stability

Stable under recommended storage conditions.

10.3 Possibility of Hazardous Reactions

Acids: Evolves hydrogen gas which may be ignited by the heat of the reaction.

Alkalis: Evolves hydrogen gas which may be ignited by the heat of the reaction.

Aluminum (powder): Possible ignition.

Aluminum-Magnesium Alloy + 

Rusted Steel: May spark on impact. 

Ammonium Nitrate: Violent reaction or formation of explosive mixture.

Ammonium Sulfide: May explode in a closed container.

Arsenic: Incandescent reaction when heated.

Arsenic Trioxide: Explosive reaction on heating.

Bromomethane: Forms flammable compounds.

Cadmium: Incandescent reaction.

Calcium Chloride: Evolves hydrogen gas which may be ignited by the heat of the reaction.

Carbon Disulfide: Incandescent reaction.

Carbon Tetrachloride + Methanol: Extremely vigorous reaction.

Chlorates: Forms shock-sensitive mixtures.

Chlorinated Rubber: Violent or explosive reaction at elevated temperatures.

Chromic Anhydride: Violent reaction and possible ignition.

Cobalt Halide (Methanolic Solution) + 

Iron Pentacarbonyl: Violent reaction. 

Ethyl Acetoacetate + 

Tribromoneopentyl Alcohol: May react explosively.

Halocarbons: Possible violent reaction with ignition.

Halogens: Possible ignition.

Hydrazine Nitrate: Ignites on warming.

Hydroxylamine: May ignite or explode when heated.

Interhalogens: Violent reaction and possible ignition.

Lead Azide: Increased sensitivity to explosive decomposition.

Manganese Dichloride: Explosive reaction when heated.

Metal Oxides: Possible ignition or incandescent reaction.

Nitric Acid: Incandescent reaction.

2-Nitroanisole + Sodium Hydroxide: Exothermic reaction.

Nitrobenzene: May form pyrophoric residue.

Nitryl Fluoride: Incandesces when warmed.

Oxidizers (Strong): Fire and explosion hazard.

Peroxyformic Acid: Violent explosion on contact.

Potassium Nitrate: Explosive reaction on heating.

Potassium Peroxide: Incandescent reaction.

Section 10: Stability and Reactivity
Zinc Safety Data Sheet

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Rhodium Halides (Methanolic Solution) + 

Iron Pentacarbonyl: Violent Reaction.

Ruthenium Halides (Methanolic Solution) + 

Iron Pentacarbonyl: Violent Reaction

Selenium: Incandescent reaction.

Seleninyl Bromide: Ignition.

Silver + Electrolytes (Batteries): May spontaneously combust.

Sodium Peroxide: Incandescent reaction.

Sulfur: Violent reaction.

Tellurium: Incandescent reaction.

Water: Produces flammable gases.

Zinc Chloride: May increase flammability.

10.4 Conditions to Avoid

None reported.

10.5 Incompatible Materials

Acids, bases, metals, oxidizing materials, reducing agents, halocarbons, metal salts, halogens, combustible materials, 

amines, metal oxides.

Safe storage of the material is discussed in Section 7.2.

10.6 Hazardous Decomposition Products

Thermal Decomposition Products: Oxides of zinc.

11.1 Likely Routes of Exposure

Routes of entry include inhalation, skin contact, eye contact, and ingestion.

11.2 Symptoms

See Section 4.2 for symptoms related to the physical, chemical, and toxicological characteristics.

11.3 Short and Long Term Effects

Inhalation (Acute): Inhalation of dust may cause irritation with difficulty in breathing and sneezing. 

Neurological and psychiatric symptomology including irritability, upper 

extremity coarse intention tremor, incoordination, and ataxia have also been 

reported. Metal fume fever, an influenza-like illness, may occur due to the 

inhalation of freshly formed metal oxide particles sized below 1.5 microns and 

usually between 0.02-0.05 microns. Symptoms may be delayed 4-12 hours 

and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in 

the mouth. Other symptoms may include upper respiratory tract irritation 

accompanied by coughing and a dryness of the mucous membranes, 

lassitude, and a generalized feeling of malaise. Fever, chills, muscular pain, 

mild to severe headache, nausea, occasional vomiting, exaggerated mental 

activity, profuse sweating, excessive urination, diarrhea, and prostration may 

also occur. Tolerance to fumes develops rapidly, but is quickly lost. All 

symptoms usually subside within 24-36 hours.

Inhalation (Chronic): Severe gastrointestinal disturbances and hypochromic anemia have been 

reported, but other chemicals may have contributed to the effects.

Skin Contact (Acute): Dust may cause mechanical irritation and mild dermatitis in intertriginous 

areas. Reaction with moisture on skin may result in serious burns.

Skin Contact (Chronic): 300 μg applied to human skin intermittently for 3 days caused mild irritation. 

Allergic reactions are rare, but have been reported.

Eye Contact (Acute): Dust may cause mechanical irritation or injury to the surface of the eye, with 

discomfort, reddening, and tearing. Direct contact may cause serious 

corneal burns.

Eye Contact (Chronic): No data available.

Section 11: Toxicological Information
Zinc Safety Data Sheet

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Ingestion (Acute): Large oral doses may cause gastrointestinal distress with stomach cramps, 

dehydration, electrolyte imbalance, abdominal pain, nausea, vomiting,

hematemesis, diarrhea, lethargy, immune system effects, fever, dizziness, 

tightness in the throat, shock collapse, renal failure, and death. Survivors may 

have residual nephritis and strictures of the esophagus and pyloric end of the 

stomach.

Ingestion (Chronic): Patients taking zinc in amounts 10 times the RDA for months and years have 

not shown any adverse reactions. Excessive absorption may cause copperdeficiency anemia. Ingestion of approximately 85.7 mg/kg/day for 2 days 

caused lethargy, lightheadedness, staggering, and difficulty in writing clearly. 

Two people who ingested 40 ppm in drinking water for several months 

experienced lack of concentration, drowsiness, mental and physical fatigue, 

pain in the arms and legs, headache, stiffness, muscle pains, loss of appetite, 

nausea, weight loss, and lassitude. 90 ppm in the diet for 5 weeks has resulted 

in a decrease in the HDL cholesterol level. Pancreatic abnormalities have also 

been observed. A diet of 0.25% in rats caused no injury; above 0.25% there 

was breakdown of the homeostatic mechanism, growth retardation, 

hypochromic anemia, and defective mineralization of the bones. Mice fed 500 

ppm for 14 months exhibited hypertrophy of the adrenal cortex and changes 

indicating hyperactivity of the pancreatic islets and pituitary gland; 30,000 ppm 

for 13 weeks caused liver and kidney damage and some deaths. Cows fed 

2% for 2 days developed severe enteritis, with 7 of 40 dying. Severe 

pulmonary emphysema and changes in the myocardium, kidneys, and liver

were observed. Pigs fed >1,000 ppm had reduced food intake and weight 

gain; at >2,000 ppm, death occurred after 2 weeks. Bone changes were 

observed in foals fed 5,400 ppm. High dietary levels of zinc have been 

associated with reduced fetal weights, altered concentrations of fetal iron and 

copper, and alopecia and reduced growth of offspring in animals.

11.4 Numerical Measures of Toxicity

Irritation Data: 300 μg/3 day(s) – intermittent skin – human mild

Toxicity Data:

TCLo (Human): 124 mg/m3/50 minute(s) inhalation 

LDLo (Duck): 388 mg/kg oral 

TDLo (Rat): 25 mg/kg intratracheal

LC50 (Multiple Sp.): 23 gm/m3/24 hour(s) (non-mammalian)

LDLo (Mouse): 5 gm/kg oral 

TDLo (Mouse): 5 gm/kg oral 

TCLo (Woman): 2.4 mg/m3/5 year(s) intermittent inhalation 

TDLo (Woman): 70 mg/kg/10 week(s) intermittent oral 

Tumorigenic Data:

TDLo (Mouse): 12,600 mg/kg oral (46 week(s) continuous)

11.5 Carcinogen Status

OSHA: Not identified as carcinogenic.

NTP: Not identified as carcinogenic.

IARC: Not identified as carcinogenic.

12.1 Ecotoxicity

Fish Toxicity: 840 μg/L 96 hour(s) LC50 (Mortality) Banded killifish (Fundulus diaphanous)

Invertebrate Toxicity: 45.8 μg/L 72 hour(s) EC50 (Shell Valve Closure) Swan mussel (Anodonta 

cygnea)

Algal Toxicity: 65 μg/L 4 hour(s) LC50 (Population Growth) Diatom (Nitzschia closterium)

Phytotoxicity: 10,000 μg/L 4 hour(s) EC50 (Growth) Duckweed (Lemna minor)

Section 12: Ecological Information
Zinc Safety Data Sheet

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12.2 Persistence and Degradability

No data available.

12.3 Bioaccumulative Potential

Bioconcentration: 7,100 μM 2 hour(s) BCFD (Residue) Duckweed (Lemna trisulca) 3.06 uM

12.4 Mobility in Soil

No data available.

12.5 Other Adverse Effects

No data available.

Dispose in accordance with all applicable regulations. Recycle any unused portion of the material for its approved use. 

Ultimate disposal of the chemical must consider: the material’s impact on air quality, potential migration in soil or water, 

effects on animal, aquatic, and plant life, and conformance with environmental and public health regulations.

14.1 UN Number 

UN Numbers: 1435 (Zinc Ashes, Dross, Residue)

1436 (Zinc Skimmings, Dust, and Powder)

14.2 UN Proper Shipping Name

Zinc Ashes, Zinc Dross, Zinc Residue, Zinc Skimmings, Zinc Dust, and Zinc Powder

14.3 Transport Hazard Class(es)

U.S. Department Of Transportation: No classification assigned.

CA Transportation/Dangerous Goods: No classification assigned.

Land Transport ADR: No classification assigned. 

Land Transport RID: No classification assigned. 

Air Transport IATA: No classification assigned. 

Air Transport ICAO: No classification assigned.

Maritime Transport IMDG: IMO 4.3 (Zinc Powder, Dust or Ashes).

14.4 Packing Group

No classification assigned.

14.5 Environmental Hazards

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to 

effluent limitations. The secondary Maximum Contaminant Level for public water systems for zinc is 5 mg/L.

14.6 Transport in Bulk

No data available.

14.7 Special Precautions

No data available.

US Regulations

CERCLA 102A/103 (40 CFR 302.4): Zinc: 1,000 LBS (454 kg) RQ 

(Solid metal particles < 100 micrometer diameter)

Section 13: Disposal Considerations

Section 14: Transport Information

Section 15: Regulatory Information
Zinc Safety Data Sheet

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SARA Title III 

Section 302 (40 CFR 355.30): Not regulated.

Section 304 (40 CFR 355.40): Not regulated.

Sections 311/312 (40 CFR 370.21): Not regulated.

Section 313 (40 CFR 372.65): Zinc

OSHA Process Safety 

29 CFR 1910.119: Not Regulated

State Regulations:

California Proposition 65: Not Regulated

National Inventory Status:

US Inventory (TSCA): Listed on Inventory

TSCA 12(b) Export Notification: Not Listed

The information in this Safety Data Sheet meets the requirements of the United States Department of Labor OCCUPATIONAL 

SAFETY AND HEALTH ADMINISTRATION and regulations promulgated thereunder (29 CFR 1910.1200 et. seq.). This 

document is intended only as a guide to the appropriate precautionary material handling by a person trained in, or supervised 

by a person trained in, chemical handling. Exposure to this chemical may have serious adverse health effects. This chemical 

may interact with other substances. Since the potential uses are so varied, all of the potential hazards of use or interaction 

with other chemicals or materials cannot be identified on this Safety Data Sheet. The user should recognize that this chemical 

can cause injury, especially if improperly handled, precautionary measures are not followed, and personal protective 

equipment not worn. Read and understand all precautionary information prior to use. The Defense Logistics Agency (DLA) 

shall not be held liable for any damage resulting from handling or from contact with the above chemical.

References:

Chemadvisor, Inc. Material Safety Data Sheet Product Name: Zinc. March 13, 2008. (as provided by the Defense Logistics 

Agency)

American Conference of Governmental Industrial Hygienists. 2013 TLVs® and BEIs®, ACGIH® Publication #0113. 2013.

Centers for Disease Control and Prevention. NIOSH Pocket Guide to Chemical Hazards, http://www.cdc.gov/niosh/npg/.

National Institute of Health, Toxicology Data Network. http://toxnet.nlm.nih.gov/

US Department of Transportation. Emergency Response Guidebook. 2012

NOTE: No data available: no data for this topic found using references listed.

Date of Preparation: April 23, 2015

Section 16: Other Information