# Patent

## Title
Disinfecting and mineral deposit eliminating composition and methods

## Abstract

Source water is treated by mixing a first component selected from the group comprising neutralized phosphonic acid compounds, neutralized phosphonate compounds, neutralized derivatives of phosphorus, neutralized anti-scalent polymers, and mixtures thereof, a second component from the group comprising chlorite salt and chlorate salt is admixed to the mixture of the water and the first component, and water. The water and the first and second components are present in amounts sufficient to form a stable liquid composition in which there is substantially no conversion of the second component to chlorine dioxide.

## Background
TECHNICAL FIELD
This invention relates to a composition for disinfecting source water and surfaces contacted by the source water, and for substantially eliminating mineral deposits on surfaces. More particularly, it relates to a stable disinfecting/mineral treating composition in water that does not produce dangerous gaseous compounds when mixed with the water.
BACKGROUND OF THE INVENTION
Municipal water, surface water and well water contain varying amounts of pathogens, dissolved oxygen and minerals. The pathogens form biofilms that cause disease and corrosion. Dissolved minerals in the water form crystalline structures that restrict passageways and reduce water flow. There is a need for providing a low cost composition that will effectively eliminate microorganisms and prevent crystalline mineral deposits and that only requires a simple feed of the composition from a container into the source water via an inexpensive metering pump. It is an object of the invention to fill this need.
It is an object of the present invention to reduce or eliminate microorganisms and also prevent crystalline mineral deposits and to do so without generating substantial amounts of chlorine dioxide and/or creating risk of dangerous exothermic and explosive reactions.
Another object of the present invention is to produce an effective composition for reducing or eliminating microorganisms and crystalline mineral deposits without the need for expensive equipment and/or the monitoring and testing of the equipment to assure safe operation.
BRIEF SUMMARY OF THE INVENTION
The composition of the present invention is a disinfectant mineral treatment that causes mineral deposits to become amorphous. The composition is formed by admixing two components in the presence of water. One component is selected from the group consisting of neutralized phosphonate compounds, neutralized phosphonic acid compounds, neutralized derivatives of phosphorus, blends of neutralized phosphonate compounds, neutralized phosphonic acid compounds and neutralized phosphorus derivatives, neutralized anti-scalent polymers, and mixtures thereof. The neutralized phosphonate may be selected from the group consisting of, but not limited to; aminotri(methylene phosphonic Acid) (ATMP), 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP), ethylenediaminetetra (methylene phosphonic acid) (EDTMPA), hexamethylenediaminetetra(methylene phosphonic acid) (HMDTMPA), diethylenetriaminepenta(methylene phosphonic acid) (DETPMPA), bis(hexamethylenetriamine penta(methylene phosphonic acid)) (BHMPTMPA), 2-phosphonobutane1,2,4-tricarboxylic acid (PBTC), 2-hydroxy phosphonoacetic acid (HPA), phosphinocarboxylic acid (PCA), nitrilotris(methylene phosphonic acid) (NTMP), and diethylenetriaminepenta(methylene phosphonic acid) (DTMP). A preferred neutralized phosphonate is 2 phosphonobutane-1,2,4-tricarboxylic acid (PBTC), and mixtures thereof.
The first component is neutralized to a pH of at least about 7.0 before or after it is admixed with water. Then, a second component, selected from the group comprising chlorite salt and chlorate salt, is admixed to the mixture of the first component and water. The water and the first and second components are present in amounts sufficient to form a stable liquid composition in which there is substantially no conversion of the second component (the salt component) to chlorine dioxide.
After it is made, the composition is stored in containers until used. When used, the composition is pumped out from the container, into source water, using an inexpensive metering pump.
The composition of this invention has a pH of 7.0 or higher. The second component is preferably about a 1% to about a 25% solution of sodium chlorite in water.
A method of the invention involves the use of the composition for converting minerals in the source water to amorphous mineral deposits on surfaces contacted by the source water. The amorphous deposits are easily removed from the surfaces, such as by wiping and/or washing.
Another method of the invention comprises disinfecting source water and surfaces by use of the same two component composition.
These and other advantages and features will become apparent from the detailed description of the best mode for carrying out the invention that follows.



BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a flow diagram a water conduit flowing from a source of water, showing a component A being added to the water in the conduit and showing component B being added to the mixture of the water and the component A;
FIG. 2 is a photograph of the “blank” sample taken under a microscope at 40×-1; and
FIG. 3 is a photograph of the “treated” sample under the microscope, also at 40×-1.



DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
Referring to FIG. 1, a component A and a component B are shown to be mixed together in a mixing vessel. The mixture is then admixed to source water flowing through a conduit 10. Component A is selected from the group consisting of neutralized phosphonate compounds, neutralized phosphonic acid compounds, neutralized derivatives of phosphorus, blends of neutralized phosphonate compounds, neutralized phosphonic acid compounds and neutralized phosphorus derivatives, neutralized anti-scalent polymers, and mixtures thereof. The neutralized phosphonate may be selected from the group consisting of, but not limited to; ATMP, HEDP, EDTMPA, HMDTMPA, DETPMPA, PHMPTMPA, PBTC, HPA, PCA, NTMP, AND DTPMP. A preferred neutralized phosphonate is 2 phosphonobutane-1, 2, 4-tricarboxylic acid (PBTC). Component B is selected from the group comprising chlorite salt and chlorate salt.
One or more of the component A substances may be added to water in a container. The component A is admixed with the water. Component A can be acquired in a dry granular form or in a liquid form. It is important that the mixture of the component A and the water have a pH 7.0 or higher before it and the component B are combined. Component B is a salt and it can be acquired in a dry granular form or in a liquid form. The essential thing is that component A be neutralized so that its pH is at least 7.0 so that when component B the salt compound is added. In the presence of water, the two components A and B and the water will form a stable liquid composition in which there is substantially no conversion of the second component, viz. the chlorite salt or the chlorate salt, to chlorine dioxide.
Another way or preparing the composition is to mix component A with component B and then admix the mixture with water.
Referring to FIG. 1, a component A and a component B are shown to be mixed together in a mixing vessel. The mixture is then admixed to source water flowing through the conduit 10. Component A is selected from the group consisting of neutralized phosphonate compounds, neutralized phosphonic acid compounds, neutralized derivatives of phosphorus, blends of neutralized phosphonate compounds, neutralized phosphonic acid compounds and neutralized phosphorus derivatives, neutralized anti-scalent polymers, and mixtures thereof. The neutralized phosphonate may be selected from the group consisting of, but not limited to; aminotri(methylene phosphonic Acid) (ATMP), 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP), ethylenediaminetetra (methylene phosphonic acid) (EDTMPA), hexamethylenediaminetetra(methylene phosphonic acid) (HMDTMPA), diethylenetriaminepenta(methylene phosphonic acid) (DETPMPA), bis(hexamethylenetriamine penta(methylene phosphonic acid)) (BHMPTMPA), 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC), 2-hydroxy phosphonoacetic acid (HPA), phosphinocarboxylic acid (PCA), nitrilotris(methylene phosphonic acid) (NTMP), and diethylenetriaminepenta(methylene phosphonic acid) (DTMP). A preferred neutralized phosphonate is 2 phosphonobutane-1,2,4-tricarboxylic acid (PBTC). Component B is selected from the group comprising chlorite salt and chlorate salt.
EXAMPLE #1
Neutralized Phosphonate/Sodium Chlorite Experiment
Collect a sample of pond water or equivalent that is known to contain biological life. Reserve some of the contaminated water to use as a “blank”. Add one part neutralized phosphonate chlorite solution to yield 5 ppm NaClo2 and 5.9 ppm PBTC. Tests confirmed residuals. Allow the treated water to sit for approximately 10 minutes before proceeding. Test the blank solution and the treated solution with BTM-2 biological kit and fungi plate; note biological growth over time. On Day 3, the Blank was observed with approximately 10 distinct colonies of bacterial growth; moderate pink on about 1⁄2 of agar. There was a lot of mold growth. On Day 3 the treated growth media had no bacterial and no yeast/mold growth.
EXAMPLE #2
Neutralized Phosphonate/Sodium Chlorite Experiment
Collected two liters of tap water. Calcium chloride and sodium carbonate were added to each liter yielding solutions with approximately 250 ppm hardness. One of the liters was used as a “blank”. The other liter was treated with neutralized phosponate/sodium chlorite solution to yield 5.0 NaClO2 and 5.9 ppm PBTC. Heated the solutions for 10 hours, insuring the water volume did not evaporate below 100 mls.
Remove 1.0 ml of the treated, heated and condensed water and place it on a microscope slide. Allow the sample to dry naturally in the atmosphere. FIG. 2 is a photo of the “blank” sample under the microscope at 40×-1. FIG. 3 is a photo of the “treated” sample under the microscope at 40×-1.
Observations of Dried Blank: This made thick white film on the slide. There are white crystals with “knobs” visible to the naked eye. Under the scope, crystals are dark and rough looking with large dark knobs. The edge of the film had more “snowflake’ shaped crystals with knobs.
Observation of Dried sample treated with neutralized phosphonate/sodium chlorite product: This made a thin opaque white film, crystals were long, sparse & thin and they were not agglomerated into a dense structure as the blank was.
The conclusion: under identical circumstances, the treated solution had substantially less crystalline substance than the blank solution.
EXAMPLE #3
Neutralized Phosphonate/Sodium Chlorite Experiment
Collect four liters of tap water. Calcium chloride and sodium carbonate were added to two liters, yielding solutions with approximately 250 ppm hardness. Treat one of the plain tap water and one of the hard water liters with neutralized phosphonate/sodium chlorite solution to yield 5.0 ppm NaClo2 and 5.9 ppm PBTC. Cleanly cut (at an angle) the bottom of 16 fresh rose stems; place four stems into each beaker and observe results over 8 days.

Conclusion

From the information included, we can see the roses treated with neutralized phosphonate/sodium chlorite solution (5.0 NaClO2 and 5.9 ppm PBTC) demonstrated the longest shelf-life. This was particularly visible in hard water since biofilm and hardness mineral crystallization can accumulate in the stems, inhibiting the uptake of water.













TAP WATER










Tap-BLANK
Tap-Treated













Day 1:
2 yellow, 2 pink; all
2 yellow, 2 pink; all buds


Apr. 14, 2006
buds


Day 2
Saturday, no
Saturday, no observations



observations


Day 3
Sunday, no
Sunday, no observations



observations


Day 4
All buds open. 2 pinks
All buds opening &



w/brown on petals; 1
healthy. All leaves green.



pink w/dried leaves.


Day 5
Same as day 4.
Sane as day 4


Day 6
Same as day 4
Same as day 4


Day 7
Same as day 4. Both
Same as day 4



pinks mostly brown, 1



pink dying.


Day 8
2 yellow are healthy; 2
3 open & healhy; 1 pink



pink dead.
wilting with dried leaves






















HARD WATER










Hard-BLANK
Hard-Treated













Day 1;
2 pink, 2 yellow. All
2 pink, 2 yellow. All buds.


Apr. 14, 2006
buds.


Day 2
Saturday, no
Saturday, no



observations.
observations.


Day 3
Sunday, no
Sunday, no observations.



observations.


Day 4
All open & healthy. 1
All open & healthy.



yellow has minor



blemishes.


Day 5
Same as day 4
Same as day 4


Day 6
All 4 open & healthy,
Same as day 4



leaves starting to dry



out.


Day 7
1 healthy, 1 wilting
Same as day 4, leaves



yellow. 2 healthy pink.
just starting to dry a little.



All leaves dried.


Day 8
1 yellow healthy w/dry
All open & healthy, minor



leaves 3 dying w/dried
leaf drying.



leaves.









Observations:















TREATED, TAP
TREATED,



TRIAL #
WATER
HARD WATER
AVERAGE







BLANK
*
*
worst


TREATED
*****
*****
best





* = WORST


***** = BEST

## Claims

1. A water conduit treating composition comprising a pH of 7.0 or higher and consisting essentially of a first component, a second component and water, wherein the water conduit treating composition is prepared by a process comprising:
mixing the first component, the second component, and water such that the first and second components are present in amounts sufficient to form a stable liquid composition having a pH of 7.0 or higher,
wherein:
the first component is neutralized 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC),
the second component is selected from ClO2− salts and ClO3− salts, and
the water conduit treating composition does not harm plants when added to a source water.

2. The water conduit treating composition of claim 1, wherein the second component is a ClO2− salt.

3. The water conduit treating composition of claim 2, wherein the second component is NaClO2.

4. The water conduit treating composition of claim 3, wherein the second component is an aqueous solution of NaClO2 with a concentration of about 1% to about 25%.

5. A water conduit treating composition comprising a pH of 7.0 or higher and consisting essentially of a first component, a second component, and water, wherein the water conduit treating composition is prepared by a process comprising:
mixing the first component, the second component, and water such that the first and second components are present in amounts sufficient to form a stable liquid composition having a pH of 7.0 or higher,
wherein:
the first component is neutralized 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC), and
the second component is selected from ClO2− salts and ClO3− salts.

6. The water conduit treating composition of claim 5, wherein the second component is a ClO2− salt.

7. The water conduit treating composition of claim 6, wherein the second component is NaClO2.

8. The water conduit treating composition of claim 7, wherein the second component is an aqueous solution of NaClO2 with a concentration of about 1% to about 25%.