# Patent

## Title
Semiconductor structure and method of manufacturing

## Abstract

The present application discloses a method of manufacturing a semiconductor structure. According to at least one embodiment, a first etch stop layer is formed over a conductive feature and a substrate, and the conductive feature is positioned over the substrate. A second etch stop layer is formed over the first etch stop layer. A first etch is performed to form an opening in the second etch stop layer, and the opening exposes a portion of the first etch stop layer. A second etch is performed to extend the opening downwardly by removing a portion of the exposed first etch stop layer, and the extended opening exposes a portion of the conductive feature.

## Background
BACKGROUND
The semiconductor integrated circuit (IC) industry has experienced rapid growth. In the course of IC evolution, functional density (i.e., the number of interconnected devices per chip area) has generally increased while geometry size (i.e., the smallest component or line that can be created using a fabrication process) has decreased. This scaling down process generally provides benefits by increasing production efficiency and lowering associated costs. Such scaling down has also increased the complexity of processing and manufacturing ICs and, for these advances to be realized, similar developments in IC manufacturing are needed.
For example, as semiconductor devices, such as metal-oxide-semiconductor field-effect transistors (MOSFETs), are scaled down through various technology nodes, strained source/drain features (e.g., stressor regions) using epitaxial (epi) semiconductor materials and/or layers of compressive/tensile dielectric materials formed over the MOSFETs have been implemented to enhance carrier mobility and to improve device performance. Subsequently, in order to form a contact plug connecting an interconnection layer and the gate, drain, or source terminal of a MOSFET, different materials need to be at least partially removed in order to form an opening for forming the contact plug.



DESCRIPTION OF THE DRAWINGS
One or more embodiments are illustrated by way of example, and not by limitation, in the figures of the accompanying drawings, wherein elements having the same reference numeral designations represent like elements throughout and wherein:
FIG. 1 is a cross-sectional view of a portion of a semiconductor structure in accordance with some embodiments;
FIG. 2A is a cross-sectional view of another portion of the semiconductor structure of FIG. 1 in accordance with some embodiments;
FIG. 2B is an enlarged view of region A of FIG. 2A in accordance with some embodiments;
FIG. 3 is a flow chart of a method of forming a semiconductor structure in accordance with some embodiments; and
FIGS. 4A-4F are cross-sectional views of a semiconductor structure at various manufacturing stages in accordance with some embodiments.



DETAILED DESCRIPTION
It is understood that the following disclosure provides many different embodiments, or examples, for implementing different features of the disclosure. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. In accordance with the standard practice in the industry, various features in the drawings are not drawn to scale and are used for illustration purposes only.
Moreover, the formation of a feature on, connected to, and/or coupled to another feature in the present disclosure that follows may include embodiments in which the features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the features, such that the features may not be in direct contact. In addition, spatially relative terms, for example, “lower,” “upper,” “horizontal,” “vertical,” “above,” “below,” “up,” “down,” “top,” “bottom,” etc. as well as derivatives thereof (e.g., “horizontally,” “downwardly,” “upwardly,” etc.) are used for ease of the present disclosure of one features relationship to another feature. The spatially relative terms are intended to cover different orientations of the device including the features.
FIG. 1 is a cross-sectional view of a portion of a semiconductor structure 100 in accordance with some embodiments. Semiconductor structure 100 includes a substrate 110. In some embodiments, the substrate 110 includes: an elementary semiconductor such as silicon or germanium in crystal, polycrystalline, or an amorphous structure; a compound semiconductor including silicon carbide, gallium arsenide, gallium phosphide, indium phosphide, indium arsenide, and/or indium antimonide; an alloy semiconductor including SiGe, GaAsP, AlInAs, AlGaAs, GaInAs, GaInP, and/or GaInAsP; or combinations thereof. In at least one embodiment, the substrate 110 is an alloy semiconductor substrate having a gradient SiGe feature in which the Si and Ge composition change from one ratio at one location to another ratio at another location of the gradient SiGe feature. In another embodiment, the alloy SiGe is formed over a silicon substrate. In yet another embodiment, a SiGe substrate is strained. In some further embodiments, the semiconductor substrate is a semiconductor on insulator. In some examples, the semiconductor substrate includes a doped epi layer or a buried layer. In other examples, the compound semiconductor substrate has a multilayer structure, or the substrate includes a multilayer compound semiconductor structure.
In the semiconductor structure 100, one or more insulation structures 112 are at least partially formed within the substrate 110 to define and electrically isolate regions for forming electrical components such as individual MOSFETs. For example, the region defined between the insulation structures 112 depicted in FIG. 1 is for forming a P-channel MOSFET (PMOS transistor) or an N-channel MOSFET (NMOS transistor). In some embodiments, the insulation structures 112 are local oxidation of silicon (LOCOS) structures or shallow trench isolation (STI) structures. In some embodiments, the insulation structures 112 comprise silicon oxide, silicon nitride, silicon oxynitride, fluoride-doped silicate glass (FSG), a low dielectric constant (low-K) dielectric material, other suitable materials, and/or combinations thereof.
Substrate 110 has a doped well 114 and two doped source/drain regions 116a/116b formed in the well 114. In at least one embodiment for forming a PMOS transistor, the well 114 comprises N-type dopant. In at least another embodiment for forming a NMOS transistor, the well 114 comprises P-type dopant. In some embodiments, the semiconductor structure 100 comprises at least one NMOS transistor and a PMOS transistor. The two doped source/drain regions 116a/116b are positioned to define a channel region 118 interposed between the doped source/drain regions 116a/116b. A portion of the doped source/drain regions 116a/116b is subject to a silicide process in order to form conductive features 119 on or over an upper surface 117 of the substrate 110. In some embodiments, the silicide process includes depositing a metal layer over the doped source/drain regions 116a/116b, annealing the metal layer such that the metal layer is able to react with materials in the doped source/drain regions 116a/116b to form metal silicide, and then removing the non-reacted metal layer. In some embodiments, a heavily doped region is formed in the source/drain regions 116a/116b as the conductive features 119, and the silicide process is omitted.
Substrate 110 also has a gate stack 120 formed over the channel region 118. The gate stack 120 includes a gate dielectric 122, a gate electrode 124, and spacers 126, and a top portion of the gate electrode 124 is subjected to a silicide process to form a conductive feature 128 on top of the gate stack 120. In some embodiments, the upper portion of the gate electrode 124 is not subjected to the silicide process, and the gate electrode 124 functions as the conductive feature 128. In some embodiments, the gate electrode 124 includes one or more layers of metallic materials comprising aluminum, copper, aluminum-copper, tungsten, P-type workfunction metal, N-type workfunction metal, or barrier materials. Therefore, in some embodiments, the gate electrode 124 comprises one or more layers of aluminum, copper, tungsten, titanium, tantulum, tantalum aluminum, tantalum aluminum nitride, titanium nitride, tantalum nitride, nickel silicide, cobalt silicide, silver, TaC, TaSiN, TaCN, TiAI, TiAIN, WN, and/or combinations thereof. In some embodiments, the gate electrode includes polysilicon.
One or more conductive plug structures 132 are formed over the conductive features 119 and contacting at least a portion of upper surfaces of the conductive features 119. In some embodiments, the conductive plug structures comprise a metallic material that is compatible with silicon (Si) or silicon germanium (SiGe) materials, such as tungsten (W), titanium (Ti), titanium nitride (TiN), or tantalum (Ta). In some embodiments, the conductive plug structures 132 comprise a conductive metallic material including aluminum (Al), aluminum-copper alloy, or copper (Cu).
A buffer layer 134 is formed over the substrate 110 and the conductive features 119/128. In at least one embodiment, the buffer layer 134 comprises silicon oxide. In some embodiments, the buffer layer 134 comprises silicon nitride, silicon oxy-nitride, silicon carbide, or combinations thereof. A first etch stop layer 136 is formed over the buffer layer 134. In some embodiments, the first etch stop layer 136 is formed in buffer layer 134, e.g., in an upper portion of the buffer layer. The buffer layer 134 and the first etch stop layer 136 are formed over another portion of the upper surface of the conductive features 119/128 that is not occupied by the conductive plug structures 132. In at least one embodiment, the first etch stop layer 136 is a doped etch stop layer comprising carbon-doped silicon oxide. In some embodiments, the first etch stop layer 136 silicon comprises oxide doped with carbon, nitride, hydrogen, indium, germanium, or a combination thereof. In some embodiments, the doped first etch stop layer is formed by implantation of appropriate atoms of the doping material in the buffer layer 134.
The semiconductor structure 100 further has a second etch stop layer 138 formed over the first etch stop layer 136. In some embodiments, the second etch stop layer 138 comprises silicon nitride or silicon oxynitride. In at least one embodiment, the second etch stop layer 138 comprises tensile silicon nitride, compressive silicon nitride, or stacked layers of tensile silicon nitride and compressive silicon nitride. In at least one embodiment for forming a PMOS transistor, a portion of the second etch stop layer 138 over the gate stack 120 and the source/drain regions 116a/116b comprises compressive silicon nitride. In yet another embodiment for forming an NMOS transistor, a portion of the second etch stop layer 138 over the gate stack 120 and the source/drain regions 116a/116b comprises tensile silicon nitride.
The semiconductor structure 100 further includes a dielectric layer 139 formed over the second etch stop layer 138 and surrounding the conductive plug structures 132. In some embodiments, the dielectric layer 139 comprises phosphorous doped silicate glass (PSG), undoped silicate glass (USG), Phosphorus-doped Tetraethoxy Silane (PTEOS), Boron-Phosphosilicate Tetraethoxy Silane (BPTEOS), spin-on-glass (SOG), other suitable materials, or combinations thereof. In some embodiments, one or more layers of conductive layers and interlayer dielectric layers are formed over the structure depicted in FIG. 1 to connect the gate stack 120 and/or the drain/source regions 116a/116b to other electrical components and/or devices on the same or a different semiconductor chip.
FIG. 2A is a cross-sectional view of another portion of the semiconductor structure 100 in accordance with some embodiments. The semiconductor structure 100 includes a substrate 110 and a conductive feature 142 formed on or over an upper surface 144 of the substrate 110. In some embodiments, the conductive feature 142 is the same or similar to the conductive structures 119/128 depicted in FIG. 1. A buffer layer 134 is formed over the substrate 110 and the conductive feature 142, a first etch stop layer 136 is formed over the buffer layer 134, and a second etch stop layer 138 is formed over the first etch stop layer 136. The second etch stop layer 138 includes a first portion 138a of a first material and a second portion 138b of a second material. The first portion 138a and the second portion 138b are formed one after another and overlap one another over the conductive feature 142. In some embodiments, the first portion 138a of the second etch stop layer 138 comprises tensile silicon nitride, and the second portion 138b of the second etch stop layer 138 comprises compressive silicon nitride.
An adhesive layer 146 is formed between the first portion 138a and the second portion 138b at the overlapped portion. In some embodiments, the adhesive layer 146 bonds the first portion 138a with a hard mask layer (not shown) for patterning the first portion 138a before the formation of the second portion 138b. In some embodiments, the adhesive layer 146 comprises silicon oxide, silicon nitride, silicon oxy-nitride, silicon carbide, or combinations thereof. Additionally, a dielectric layer 139 is formed over the second etch stop layer 138.
An opening 152 is formed in order to form a conductive plug structure (similar to plug structure 132 of FIG. 1) in contact with an upper surface 148 of the conductive feature 142. In some embodiments, the opening 152 is formed by etching through the dielectric layer 139, the second etch stop layer 138, the adhesive layer 146, the first etch stop layer 136, and the buffer layer 134. In practice at times, a mask for forming the opening 152 may be misaligned, and the etch process for removing the adhesive layer 146 may inadvertently etch away a portion of other materials in the semiconductor structure 100 due to the misalignment of the mask. Therefore, in certain circumstances, the to-be-formed conductive plug structure does not properly contact the conductive structure 142 or unexpectedly causes a short circuit among the conductive structure 142 and other devices or components. By implementing the first etch stop layer 136 as being capable of withstanding the etch process for removing the adhesive layer 146, a level of tolerance with regard to manufacturing variations is broadened.
FIG. 2B is an enlarged view of region A of FIG. 2A in accordance with some embodiments. In some embodiments, the thickness D1 of the second etch stop layer 138 ranges from 200 to 800 angstroms (Å), the thickness D2 of the first etch stop layer 136 ranges from 5 to 40 Å, and the thickness D3 of the buffer layer 134 ranges from 10 to 90 Å. In some embodiments, the thickness D2 of the first etch stop layer 136 is 1⁄3 to 3⁄4 of the summation of the thickness D2 of the first etch stop layer 136 and the thickness D3 of the buffer layer 134.
FIG. 3 is a flow chart of a method 300 of forming a semiconductor structure in accordance with some embodiments. It is understood that additional processes may be provided before, during, and/or after the method 300 depicted in FIG. 3, and that some other processes may only be briefly described herein.
In operation 310, a buffer layer is formed over a conductive feature and a substrate, and the conductive feature is formed on or above the substrate. In operation 320, a first etch stop layer is formed over the buffer layer. In some embodiments, the first etch stop layer comprises silicon oxide doped with dopant such as carbon, nitride, hydrogen, indium, germanium, or a combination thereof. In at least one embodiment, the first etch stop layer comprises carbon-doped silicon oxide. In some embodiments, the first etch stop layer is formed by converting an upper portion of the buffer layer into the first etch stop layer. For example, carbon atoms are implanted onto the buffer layer by performing ion implantation or plasma assisted implantation. In some embodiments, the first etch stop layer is deposited or grown on the buffer layer by performing atomic layer deposition (ALD), chemical vapor deposition (CVD), wet oxidation, physical vapor deposition (PVD), remote plasma CVD (RPCVD), plasma enhanced CVD (PECVD), metal organic CVD (MOCVD), sputtering, plating, other suitable processes, and/or combinations thereof. In yet some other embodiments, the first etch stop layer is deposited or grown over the buffer layer or, if operation 310 is omitted, over the conductive feature and the substrate.
In operation 330, a second etch stop layer is formed over the first etch stop layer. In some embodiments, the second etch stop layer comprises silicon nitride or silicon oxynitride. In some embodiments, the second etch stop layer is formed by performing ALD, CVD, wet oxidation, PVD, RPCVD, PECVD, MOCVD, sputtering, plating, other suitable processes, and/or combinations thereof. In some embodiments, the second etch stop layer comprises a tensile etch stop layer and/or a compressive etch stop layer.
Subsequently, in operation 340 a dielectric layer is formed over the second etch stop layer. In operation 350, a portion of the dielectric layer is removed to expose a portion of the second etch stop layer, using the second etch stop layer as the etch stop layer. In some embodiments, the removal of the dielectric layer is performed by performing ALD, CVD, wet oxidation, PVD, RPCVD, PECVD, MOCVD, sputtering, plating, other suitable processes, and/or combinations thereof.
In operation 360, an etch process (such as a dry etch process, a wet etch process, or a plasma etch process) is performed to form an opening in the second etch stop layer using the first etch stop layer as the etch stop layer. In some embodiments, the first etch stop layer comprises carbon-doped silicon oxide, the second etch stop layer comprises silicon nitride, and the first etch has a selectivity characteristic of silicon nitride over carbon-doped silicon oxide equal to or greater than 8 and a selectivity characteristic of silicon nitride over silicon oxide ranging from 2 to 3. In at least one embodiment, the etching process is performed by using source gases CH2F2 and/or CHF3 together with Nitrogen, Argon, and/or Helium. In another embodiment, an etching chemical, such as C4F6 and/or C4F8, together with CF4 plasma source gases are used for performing the etching process.
In operation 370, another etch process (such as a dry etch process, a wet etch process, or a plasma etch process) is performed to downwardly extend the opening by removing a portion of the exposed first etch stop layer, and the extended opening exposing a portion of the conductive feature. The buffer layer comprises silicon oxide, and the second etch has a selectivity characteristic of silicon nitride over silicon oxide equal to or less than 2. In at least one embodiment, the etching process is performed by using source gases CH2F2 and/or CHF3 together with Nitrogen, Argon, and/or Helium. In another embodiment, an etching chemical, such as C4F6 and/or C4F8, together with CF4 plasma source gases are used for performing the etching process.
In operation 380, a conductive plug is formed in the extended opening, and the conductive plug contacts the exposed portion of the conductive feature. In some embodiments, one or more operations are performed to form one or more conductive layers and interlayer dielectric layers over the dielectric layer in order to form a complete semiconductor circuit.
FIG. 4A is a cross-sectional view of a semiconductor structure 400 after forming a buffer layer over a conductive structure (corresponding to operation 310 (FIG. 3)). Semiconductor structure 400 includes a substrate 410. In some embodiments, the substrate 410 includes: an elementary semiconductor such as silicon or germanium in crystal, polycrystalline, or an amorphous structure; a compound semiconductor including silicon carbide, gallium arsenide, gallium phosphide, indium phosphide, indium arsenide, and/or indium antimonide; an alloy semiconductor including SiGe, GaAsP, AlInAs, AlGaAs, GaInAs, GaInP, and/or GaInAsP; or combinations thereof. In at least one embodiment, the substrate 410 is an alloy semiconductor substrate having a gradient SiGe feature in which the Si and Ge composition change from one ratio at one location to another ratio at another location of the gradient SiGe feature. In another embodiment, the alloy SiGe is formed over a silicon substrate. In yet another embodiment, a SiGe substrate is strained. Furthermore, in some embodiments, the semiconductor substrate is a semiconductor on insulator. In some examples, the semiconductor substrate includes a doped epi layer or a buried layer. In other examples, the compound semiconductor substrate has a multilayer structure, or the substrate includes a multilayer compound semiconductor structure.
In the semiconductor structure 400, one or more insulation structures 412 are at least partially formed within the substrate 410 to define and electrically isolate regions for forming electrical components such as a MOSFET 420. In some embodiments, the insulation structures 412 are local oxidation of silicon (LOCOS) structures or shallow trench isolation (STI) structures. In some embodiments, the insulation structures 412 comprise silicon oxide, silicon nitride, silicon oxynitride, fluoride-doped silicate glass (FSG), a low dielectric constant (low-K) dielectric material, other suitable materials, and/or combinations thereof.
In some embodiments, the MOSFET 420 is a PMOS transistor or an NMOS transistor. The MOSFET 420 has a well 422 formed in the substrate 410 and two doped source/drain regions 424a/424b formed in the well 422. The two doped source/drain regions 424a/424b are positioned to define a channel region 426 interposed between the doped source/drain regions 424a/424b. The MOSFET 420 also has a gate stack 428 formed over the channel region 426. One or more conductive features 430 are formed on or over an upper surface 416 of the substrate 410 to provide ohmic connection points for the drain and the source 424a/424b of the MOSFET 420. In some embodiments, a conductive feature 432 is formed at an upper portion of the gate stack 428. The MOSFET 420 is similar to the PMOS transistor or the NMOS transistor depicted in FIG. 1, and details that are the same or similar to the PMOS transistor or the NMOS transistor depicted in FIG. 1 are not repeated.
A buffer layer 442 is formed over the conductive features 430 and the substrate 410. In at least one embodiment, the buffer layer 442 comprises silicon oxide. In some embodiments, the buffer layer 442 comprises silicon oxide, silicon nitride, silicon oxy-nitride, silicon carbide, or combinations thereof. In some embodiments, the buffer layer 442 is formed by performing ALD, CVD, wet oxidation, PVD, RPCVD, PECVD, MOCVD, sputtering, plating, other suitable processes, and/or combinations thereof.
FIG. 4B is a cross-sectional view of the semiconductor structure 400 subject to a process 450 for forming a first etch stop layer 444 over a conductive feature 432 (corresponding to operation 320 (FIG. 3)). In some embodiments, the first etch stop layer 444 is a doped etch stop layer comprising silicon oxide doped with carbon, nitride, hydrogen, indium, germanium, or a combination thereof. In at least one embodiment, the first etch stop layer 444 comprises carbon-doped silicon oxide. In some embodiments, process 450 for forming the first etch stop layer 444 is an implantation process that implants carbon atoms to convert an upper portion of the buffer layer 442 into the first etch stop layer 444. In some embodiments, the implantation process comprises ion implantation or plasma assisted implantation. In yet some other embodiments, the first etch stop layer 444 is deposited or grown over the buffer layer 442 or, if operation 310 (FIG. 3) is omitted, over the conductive feature 432 and the substrate 410.
In some embodiments, the process 450 is a deposition process that deposits the first etch stop layer 444 on the buffer layer 442. In some embodiments, the deposition process comprises ALD, CVD, wet oxidation, PVD, RPCVD, PECVD, MOCVD, sputtering, plating, other suitable processes, and/or combinations thereof.
FIG. 4C is a cross-sectional view of the semiconductor structure 400 after forming a second etch stop layer 446 and a dielectric 460 layer over the first etch stop layer 444 (corresponding to operations 330 and 340 (FIG. 3)). The second etch stop layer 446 is formed over the first etch stop layer 444. In some embodiments, the second etch stop layer 446 comprises silicon nitride or silicon oxynitride. In some embodiments, the second etch stop layer 446 is formed by performing ALD, CVD, wet oxidation, PVD, RPCVD, PECVD, MOCVD, sputtering, plating, other suitable processes, and/or combinations thereof. In some embodiments, the second etch stop layer 446 comprises a tensile etch stop layer and/or a compressive etch stop layer. In at least one embodiment for forming a PMOS transistor, a portion of the second etch stop layer 446 over the MOSFET 420 comprises compressive silicon nitride. In yet another embodiment for forming an NMOS transistor, a portion of the second etch stop layer 446 over the MOSFET 420 comprises tensile silicon nitride.
Subsequently, a dielectric layer 460 is formed over the second etch stop layer 446. In some embodiments, the dielectric layer 460 comprises PSG, USG, PTEOS, BPTEOS, SOG, other suitable materials, or combinations thereof. In some embodiments, the dielectric layer 460 is formed by performing ALD, CVD, wet oxidation, PVD, RPCVD, PECVD, MOCVD, sputtering, plating, other suitable processes, and/or combinations thereof.
FIG. 4D is a cross-sectional view of the semiconductor structure 400 after removal of a portion of the dielectric layer 460 and subject to an etch process 470 for forming openings 474 in the second etch stop layer 446 (corresponding to operations 350 and 360 (FIG. 3)). First, a portion of the dielectric layer 460 is removed to expose a portion of the second etch stop layer 446, using the second etch stop layer 444 as the etch stop layer. In some embodiments, the removal of the dielectric layer 460 is performed by patterning a mask layer 472 by a photolithography process, and then etching trenches in the dielectric layer 460 (for example, by using a dry etching, wet etching, and/or plasma etching process).
Then, the etch process 470 (such as a dry etch process, a wet etch process, or a plasma etch process) is performed to form openings 474 in the second etch stop layer 444 using the first etch stop layer 442 as the etch stop layer. In some embodiments, the first etch stop layer 444 comprises carbon-doped silicon oxide, the second etch stop layer 446 comprises silicon nitride, and the first etch process 470 has a selectivity characteristic of silicon nitride over carbon-doped silicon oxide equal to or greater than 8 and a selectivity characteristic of silicon nitride over silicon oxide ranging from 2 to 3.
FIG. 4E is a cross-sectional view of the semiconductor structure 400 subject to an etch process 480 for downwardly extending the openings 474 by removing a portion of the exposed first etch stop layer 444 (corresponding to operation 370 (FIG. 3)). The extended opening 482 exposes a potion of the conductive features 430. In some embodiments, the buffer layer 442 comprises silicon oxide, and the second etch process 480 has a selectivity characteristic of silicon nitride over silicon oxide equal to or less than 2. Although the mask layer 472 is depicted in FIGS. 4D and 4E, in some embodiments, the mask layer 472 is not necessary for the etching of the first etch stop layer 444 or the second etch stop layer 446.
FIG. 4F is a cross-sectional view of the semiconductor structure 400 after forming contact plugs 490 in the extended opening 482 (corresponding to operation 380 (FIG. 3)). The conductive plug 490 contacts the exposed portion of the conductive feature 430. Subsequently, in some embodiments, one or more operations are performed to form one or more conductive layers and interlayer dielectric layers over the dielectric layer 460 in order to form a complete semiconductor circuit.
According to some embodiments, a method of manufacturing a semiconductor structure is described includes forming a first etch stop layer, which is a doped etch stop layer, over a conductive feature and a substrate and forming a second etch stop layer is formed over the first etch stop layer, where the conductive feature is positioned over the substrate.
According to some embodiments, a semiconductor structure includes a substrate, a conductive feature, a conductive plug structure, a first etch stop layer, and a second etch stop layer. The first etch stop layer is a doped etch stop layer. The conductive feature is formed on or over an upper surface of the substrate. The conductive plug structure is formed over the conductive feature and contacts a portion of an upper surface of the conductive feature. The first etch stop layer is formed over another portion of the upper surface of the conductive feature. The second etch stop layer is formed over the first etch stop layer.
According to some embodiments, a method of manufacturing a semiconductor structure includes forming a buffer layer over a conductive feature and a substrate, where the conductive feature is positioned over the substrate. An upper portion of the buffer layer is converted into a doped etch stop layer, and another etch stop layer is formed over the doped etch stop layer. A first etch is performed to form an opening in the another etch stop layer, and the opening exposes a portion of the doped etch stop layer. A second etch is performed to downwardly extend the opening by removing a portion of the exposed doped etch stop layer and a portion of the buffer layer, and the extended opening exposes a portion of the conductive feature. A conductive plug is formed in the extended opening, and the conductive plug contacts the exposed portion of the conductive feature.
The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.

## Claims

1. A method of manufacturing a semiconductor structure, the semiconductor structure comprising a conductive feature positioned on or over a substrate, the method comprising:
forming a buffer layer over the conductive feature and the substrate;
converting an upper portion of the buffer layer into a first etch stop layer and leaving a lower portion of the buffer layer as a remaining buffer layer;
forming a second etch stop layer over the first etch stop layer; and
performing a first etch to form an opening in the second etch stop layer, the opening exposing a portion of the first etch stop layer.

2. The method of claim 1, wherein the conversion of the upper portion of the buffer layer comprises performing carbon implantation on the buffer layer.

3. The method of claim 1, further comprising:
performing a second etch to downwardly extend the opening by removing a portion of the exposed first etch stop layer, the extended opening exposing a portion of the conductive feature.

4. The method of claim 3, further comprising:
forming a dielectric layer over the second etch stop layer; and
performing a third etch, prior to performing the first etch, to remove a portion of the dielectric layer and expose a portion of the second etch stop layer.

5. The method of claim 4, further comprising:
forming a conductive plug in the extended opening, the conductive plug contacting the exposed portion of the conductive feature.

6. The method of claim 1, wherein the formation of the second etch stop layer comprises:
forming a tensile etch stop layer over a portion of the first etch stop layer;
forming an adhesive layer over at least an end portion of the tensile etch stop layer; and
forming a compressive etch stop layer over another portion of the first etch stop layer and the adhesive layer,
the second etch stop layer comprising the tensile etch stop layer and the compressive etch stop layer.

7. The method of claim 1, wherein the first etch stop layer comprises carbon-doped silicon oxide, the second etch stop layer comprises silicon nitride, and the first etch has a selectivity characteristic of silicon nitride over carbon-doped silicon oxide equal to or greater than 8.

8. The method of claim 1, wherein the first etch stop layer comprises carbon-doped silicon oxide, the buffer layer comprises silicon oxide, and the second etch has a selectivity characteristic of silicon nitride over silicon oxide equal to or less than 2.

9. A method of manufacturing a semiconductor structure, comprising:
forming a buffer layer over a conductive feature and a substrate, the conductive feature being positioned on or over the substrate;
converting an upper portion of the buffer layer into a doped etch stop layer by implanting dopant into the upper portion of the buffer layer;
forming another etch stop layer over the doped etch stop layer;
performing a first etch to form an opening in the another etch stop layer, the opening exposing a portion of the doped etch stop layer;
performing a second etch to downwardly extend the opening by removing a portion of the exposed doped etch stop layer and a portion of the buffer layer, the extended opening exposing a portion of the conductive feature; and
forming a conductive plug in the extended opening, the conductive plug contacting the exposed portion of the conductive feature.

10. The method of claim 9, wherein the dopant comprises carbon, nitride, hydrogen, indium, germanium, or a combination thereof.

11. The method of claim 9, further comprising:
forming a dielectric layer over the another etch stop layer; and
performing a third etch, prior to performing the first etch, to remove a portion of the dielectric layer and expose a portion of the another etch stop layer.

12. The method of claim 9, wherein the formation of the another etch stop layer comprises:
forming a tensile etch stop layer over a portion of the doped etch stop layer;
forming an adhesive layer over at least an end portion of the tensile etch stop layer; and
forming a compressive etch stop layer over another portion of the doped etch stop layer and the adhesive layer,
the another etch stop layer comprising the tensile etch stop layer and the compressive etch stop layer.

13. The method of claim 9, wherein the doped etch stop layer comprises carbon-doped silicon oxide, the another etch stop layer comprises silicon nitride, and the first etch has a selectivity characteristic of silicon nitride over carbon-doped silicon oxide equal to or greater than 8.

14. The method of claim 9, wherein the doped etch stop layer comprises carbon-doped silicon oxide, the buffer layer comprises silicon oxide, and the second etch has a selectivity characteristic of silicon nitride over silicon oxide equal to or less than 2.

15. A method of manufacturing a semiconductor structure, comprising:
forming a buffer layer over a conductive feature and a substrate, the conductive feature being positioned on or over the substrate;
converting the buffer layer into a first etch stop layer and a remaining buffer layer under the first etch stop layer, the converting comprising implanting dopant into an upper portion of the buffer layer; and
performing a first etch to form an opening in the first etch stop layer and the remaining buffer layer to expose a portion of the conductive feature.

16. The method of claim 15, further comprising:
forming a second etch stop layer over the first etch stop layer; and
performing a second etch, prior to performing the first etch, to expose a portion of the first etch stop layer.

17. The method of claim 16, wherein the first etch stop layer comprises carbon-doped silicon oxide, the second etch stop layer comprises silicon nitride, and the second etch has a selectivity characteristic of silicon nitride over carbon-doped silicon oxide equal to or greater than 8.

18. The method of claim 15, further comprising:
forming a dielectric layer over the second etch stop layer; and
performing a third etch, prior to performing the second etch, to expose a portion of the second etch stop layer.

19. The method of claim 15, wherein the first etch stop layer comprises carbon-doped silicon oxide, the remaining buffer layer comprises silicon oxide, and the first etch has a selectivity characteristic of silicon nitride over silicon oxide equal to or less than 2.