ATC PROJECT No. P-10142 BORAL BRICKS

### EPAEi&f~~**f'i~!WPR8!J~/R** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# Results

APPENOIX PAGE No. 334)> ::; " , ;o 0 **~** m " __, z 0 **~** s: .. "' c Glm c, **~)>** l>fi w""' m):m

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>"" z __, "' )> , , m z 0 x **~** m z ? w w "' Company Analytical Testing Consultants Analyst EO Parameters EPA Method 26A (H2S04) #Samples

18 Runs, 2 Blanks Client# P-10124 Job# 0910-96 PO# P-10124 Report Date 1016/2010

MDL 0.0100 (ug/mL) LOQ

0.200 (ug/mL) Lower Curve Limit 0.200 (ug/mL) Upper

Curve Limit 15.0 (ug/mL)

Compound

Hydrogen Fluoride as Fluolide Sample LabiD Lab ID Analysis Ret Ret

% Qjff Cone Cone

% Diff

ID

# 1 #2 Method Time Time

Ret Itt #2

Cone

(min) (min) (ug/mL) (ug/mL)

Salisbury Run 1 In A 009-tOOt.D 009-1002.0 HPLC53PGS8.M 3.13 3.13 0.0 7.99 7.99 0.0 Avg Acid

Vol Catch
Cone

Conversion OF

(mL) Weight Qual
(uglmL)

Factor (ug)

7.99 1.053 20 266 44,722

OaiiiibUrY Run 21n A I 012-1301.0 I 012-1302.0 [ HPLC53PG98.M I 3.13 I 3.13 I

o.o I 7.99 I 7.97 I 0.1 I 7.98 I 1.053 I 20 I 292 I 49,144 I I OafiiibiiiYRun31nA--TOt3-140t.D[013=t402-:DTRI'Lc53PG98.'1vfi3.T3]}}3] (fO I 8.07- I 8.-65-[DJ r-8.06 I i.o53 I 20 I 362 I 61,452 I I

[§alisbury RuntOutA r (ij<(:jso-f:o I o14:tsoz-:ol HPLCS3PG§S;M I NA I NA-1 NA I o-:QTtj(j(j I 0.010DQTM I d.01b-02J:::t.b53:-1:1DJ 273 I 28.7 I ND I

I SalisburyRun20utA I 015-1601.0 I 015-1602.0 I HPLC53PG98.M I NA I NA IJIIA]

**o.otoooTo.01050TQJ?TO.OT~~053** I 10 I 286 I 30.1 I NO I
C§iilisiJuryRUri30utA 1 ot6:1fforD 1 **016-t9d2~b-l** HPLC53P<l98:M 1 NA **p~il-1** NA 1 o.blooo 1 o.otooorn 1 o.otoorr=t.o53 1 to 1 265 1 27.9 1 ND 1

c P4RuntlnA

m ]o2il=330Toro26:J352])1 HPI..C53i'<l9&rv\T3.1213.t2l 6.6J----s:84 r 3.86 I 0.3 I 3.85 I 1.053 I 10 1273 I 11,071 I I

I P4Run21nA I 029-3601.D I 029-3602.D I HPLC53PG98.M 13.1413.141 0.0 I 11.7 I 11.7 I 0.1 I 11.7 I 1.053 I 10 I 289 I 35,672 I I

I P4 Run 31nA I 030-3701.D I 030-3702.D I HPLC53PG98.M 13.1413.141 0.0 I 11.0 I 10.9 I 0.1 I 10.9 I 1.053 I 10 I 3561 41,007 I I

I P4 Run 1 Out A- T031-380Ul]'03t-3602.D [Ri'l.C53f>G98.M I :3:121 3.121 o.ifT 0:4921 6.487-("0.S I ().4!'l6Lt.d53- I 10 I 295 I 1,522 I I

I P4 Run 2 Out A I 032-3901.0 I 032-3902.0 I HPLC53PG98.M I 3.12 I 3.12 I 0.0 I 0.608 I 0.606 I 0.1 I 0.607 I 1.053 I 10 I 283 I 1,808 I I

I P4 Run 3 Out A I 033-4001.D I 033-4002.D I HPLC53PG98.M I 3.12 I 3.12 I 0.1 I 0.685 I 0.684 I 0.1 I 0.684 I 1.053 I 10 I 323 I 2,325 I I

0910-96 res EA#

091 0-96 Page 8 of 202 10/6/2010 "'

0 **~** "' ;o i'i "' (f),.c""0mz:!:0..Glem(/)"..;>-"'"(/)"""llZS:-<..;-m(/)(1)m"'o,,z.-<or-<w""'"co-<m.-<"',.""mz0xmz-CompanyAnalyticalTestingConsultantsAnalystEOParametersEPAMethod26A(H2S04)#Samples18Runs,2BlanksClient#P-10124Job#0910-96PO#P-10124ReportDate10/6/2010MDL0.0100(ug/mL)LOQ0.200(ug/mL)LowerCurveLimit0.200(ug/mL)UpperCurveLimit15.0(ug/mL)CompoundHydrogenFluorideasFluorideSampleLabiDLabIDAnalysisRet Ret%DiffConeCone0/nDiffTimeTime#1#2ID#1#2Method(min)(min)Ret(ug/mL) (ug/mL)ConeP5Run1InA040-4901.0040-4902.0HPLC53PG98.M3.133.130.06.19 6.24OAAvgAcidVolCatchConeConversionDFWeightQual(ug/mL)Factor(mL)(ug)6.211.0531029419206IP5Run21nAI009-1001.0I009-1002.0IHPLC53PG100.MI3.1413.14F6.ifT-8.7:fT8.68nI'0.3I'll.?o-,-1:653'120ji72!49)328-1IP5Run31nAI010-1101.0I010-1102.DIHPLC53PG100.MI3.14I3.17I1.0I11.0I11.1I0.5111.0I1.053I201246157,0641IIP5Run1OutAI043-5201.0I043-5202.0IHPLC53PG98.MI3.12I3.12I0.0I0.750I0.702I3.3Io.i28-[-T553T10-I296I2,259IIIP5Run2OutAI044-5701.0I044-5702.0IHPLC53PG98.MI3.1313.1310.0I0.622I0.839I1.0I0.830I1.053I10I23912,092IIIP5Run3OutAI045-5801.0I045-5802.0IHPLC53PG96.MI3.1213.1210.0I0.776I0.766I0.5I0.772I1.053I10I261I2,121IIIAcidBlankI052-6701.0I052-6702.0IHPLC53PG98.MT3.17INAI0.0119In1:b53I10r141T1773-TJ-1I01H20blankI054-6901.0I054-6902,0IHPLC53PG96.MINAINAINAI0.0100I0.0100I0.0I0.0100I1.053I1I147I1.55INDII0.01NH2S04/NaOHRBI008-0901.0I006-0902.0HPLC53PG96.MINAINANAo.I5100TM10l[Tll.i5nl0.01001.1J53r1n!Tili\15-:ofos---r}IDJI0.01NH2S04/Na0HRBI008-3201.0I008-3202.0HPLC53PG98.MINAINA NA0.0100I0.0100I0.0I0.01001.053I111.00I0.0105INDIIO.OtNH2S04/Na0HRBI103-5601.01103-5602.0HPLC53PG98.MINAINANA0.0100I0.0100I0.0I0.01001.053I1I1.00I0.0105INDII0.01NH2S04/NaOHRBI008-0901.0I008-0902.0HPLC53PG100.MINAINA NA0.0100I0.0100I0.0I0.01001.053I111.00I0.0105INDI0910-96res10/6/2010EA#0910-96Page9of202rOJ"0"(/)**~** () -u ;o e m <::1 z 0 :;; s: .. "' )> c Glm c-, **~)>** "'n en""'

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P-10124 Report Date 10/6/2010

MDL 0.0100 (ug/mL) LOQ 0.200 (ug/mL) Lower Curve Limo 0.200 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound

Hydrogen Fluoride as Fluoride Sample Lab ID Lab ID Analysis Ret Ret

% Diff Cone Cone

% Diff

10 #1 #2 Method Time Time

Ret # 1 #2

Cone

(min) (min) (ug/mL) (ug/mL)

MS Salisbury R 1 In A 010-1101.0 010-1102.0 HPLC53PG98.M 3.13 3.13 0.0 1 1.3 11.3 0.2

I MSD Salisbury R1 In A I 011-1201.0 011-1202.0 I HPLC53PG98.M I 3.131 3.13 I 0.0 I 10.7 I 10.1 1 0.2 I

I MS P4 R11nA I 027-3401.0 027-3402.0 I HPLC53PG98.MI 3.13 I 3.13 I 0.0 6.94 6.95 L o.o I
MSDP4R11nA L 028-3501.0 028-3502.0 HPLC53PG98.M I 3.13 3.12 0.1 6.97 6.94 I 0.2 I

HPLC53pa98 #LCS 007-0801.0 007-0802.0 HPLC53PG98.M I 3.12 3.12 0.1 5.37 5.36 I 0.1 I

I HPLC53pg98 #LCS 1 007-3101.0 007-3102.0 HPLC53PG98.M I 3.12 I 3.12 I 0.0 5.34 5.35 I 0.1

0910-96 res EA#0910-96

Page 10of202 Avg Acid

Vol

Cone Conversion DF

(mL)

(ug/mL) Factor 11.3 1.053 1 10.0 Spike

Amount (ug) Native Amount (ug) Spike Recovery (%)

10.1 I 1.053 I 1 I 10.0 Spike

Amount (ug) Native Amount (ug) Spike Recovery (%)
6.94 1 1.053 1 1 10.0 Spike

Amount (ug) Native Amount (ug) Spike Recovery (%)
6.96 1.053 I 1 I 1 0.0 Spike

Amount (ug) Native Amount (ug) Spike Recovery(%)
5.36 1.053 I 1 I 10.0 Spike Amount (ug) Spike Recovery (%)
5.35 1 1.053 I 1 I 10.0 Spike

Amount (ug) Spike Recovery (%) Catch Weight Qual (ug) 119 31.6 84.1 111% 113 31.6 84.1 91.3% 73.1 31.6 40.5 103% 73.3 31.6 40.5 104% 56.5 52.7 107% 56.3 52.7 107% 10/6/2010 I I I I I OJ 0 ?1 r OJ ;o () "' "'**~** "1l el L m **~** z 0 **~** s: .. N )> c Glm C"U **~)>** l>ij cn"''::t! mS::m -uzs: --<-;-

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EO Parameters EPA Method 26A (H2S04)

# Samples 18 Runs, 2 Blanks Client# P-10124 Job # 0910-96 PO# P-10124 Report Date 10/612010

MDL 0.0100 (ug/mL) LOQ 0.200 (ug/mL) Lower Curve Limit 0.200 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound

Hydrogen Fluoride as Fluoride Sample LabiD Lab ID Analysis Ret Ret

% Diff Cone Cone

% Diff

ID

# 1 #2 Method Time Time

Ret #1 #2

Cone

(min) (min) (ug/ml) (ug/mL)

HPLC53oo98 #LCS 102-5501.0 102.0502.0 HPLC53PG98.M 3.12 3.12 0.0 5.22 5.22 0.0

HPLC53oo1 00 #LCS 007-0801.0 I 007-DB02.D HPLC53PG100.M I 3.12 I 3.13 0.0 5.27 I 5.29 I 0.1

0910-96 res EA#

0910-96 Page 11 of 202 Avg Acid

Vol

Cone Conversion DF

(mL)

(ug/mL) Factor 5.22 1.053 1 10.0 Spike Amount (ug) Spike Recovery (%)
5.28 1.053 1 1.10.0 Spike

Amount (ug) Spike

Recovery (%) Catch Weight Qual (ug) 55.0 52.7 104% 55.6 52.7 106% 10/6/2010 I "'

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MDL 0.00695 (ug/ml) LOQ 0.200 (ug/ml) Lower Curve Limit 0.200 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound Hydrogen Chloride as Chloride Sample LabiD Lab ID Analysis Ret Ret % Oiff Cone Cone % Diff

Time nme #1 #2

ID # 1 #2 Method (min) (min) Ret (ug/mL) (ug/ml) Cone

Salisbury Run 1 In A 009-1001.0 009-1002.0 HPLC53PG98.M 4.26 4.26 0.0 0.533 0.532 0.0 Avg Acid Vol Catch

Cone Conversion DF Weight Qual

(ug/ml) Factor (mL) (ug)
0.533 1.028 20 266 2,911

I SalisburyRun21nA I 012-1301.0 I 012-13020 I HPLC53PG98.M 14.2614.261 0.0 I 0.650 I 0.644 I 0.5 I 0.647 r 1.028 I 20 I 292 I 3.890 I I

I Salisbllii-RUii31;;-;o;-jJji3-1461b I **013-1402~oTRPLC:53PG§S:MT4.26T4:26T** 0.0 I 0742 r Oi4iJTifT 0.741 I **1.~[** 2DHI 362. I 5,514 I I

I Salisbury Run 1 Out A I 014-1501.0 I 014-1502.0 I HPLC53PG98.M I 4.25 [ 4.261 0.0 I 0.120 I 0.115 I 2.2 I 0.118]--1.028 I 10 I 273 r 330 I J I

I Salisbury Run 2 DutA I 015-1601.0 I 015-1602.0 I HPLC53PG98.M I 4.25 I 4.25 I 0.0 I 0.0648 I 0.0869 I 1.2 I 0.0859 I 1.028 I 10 I 286 I 253 I J I

I Salisbury Run 3 Out A I 016-1901.0 I 016-1902.0 I HPLC53PG98.M I 4.251 4.251 0.0 I 0.0825 I 0.0764 I 3.8 I 0.079T r. 1.028 I 10 T265 I 217 I J I

I P4Run11nA I026-3301.Dio26-3302.DIHPLCS3PG98.MI4.26pi:261ool 0.218 ]-if21d I1.7T0.214\ 1.028Tf0[273l 601=:1--1

I P4Run21nA I 029-3601.0 I 029-3602.0 I HPLC53PG98.M 14.2614.261 0.0 I 1.01 I 1.01 I 0.3 I 1.01 I 1.028 I 10 I 289 I 3,000 I I

I P4 Run 31n A I 030-3701.0 I 030-3702.0 I HPLC53PG98.M I 4.261 4.261 0.0 I 0.815 I 0.823 I 0.5 I 0.819 I 1.028 I 10 I 356 I 2,995 I I

I P4 Run 1 Out A I 031-36010 I 031-3802.0 I HPLC53PG98.M I 4.26 I 4.26[ 0.0 I 0.325 [Jl.327 I 0.3 I **-0~32_6_1_1.028** I 10 I 295 1- 966 I I

I P4 Run 2 Out A I 032-3901.0 I 032-3902.0 I HPLC53PG98.M I 4.26 I 4.26 I 0.0 I 0.378 I 0.378 I 0.1 I 0.378 I 1.028 I 10 I 283 I 1,100 I I

I P4 Run 3 Out A I 033-4001 0 I 033-4002.0 I HPLC53PG98.M I 4.26 I 4.26 I 0.0 I 0.386 I 0.385 I 0.2 I 0.385 I 1.028 I 10 I 323 I 1,278 I I

0910-96 res 1 0/6/2010

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PO# P-10124 Report Date 10/6/2010

MDL 0.00695 (uglmL) LOQ 0.200 (uglmL) Lower Curve Limit 0.200 (ug/mL) Upper Curve Limit 15.0 (uglmL)

Compound Hydrogen Chloride as Chloride Semple LabiO Lab 10 Analysis Ret Ret % Oiff Cone Cone % Diff

ID #1 #2 Method Time Time Ret # 1 #2 Cone

(min) (min) (ug/mL) (ugimL)

P5 Run tin A 040-4901.0 040-4902.D HPLC53PG98.M 4.26 4.26 0.0 0.206 0.203 0.6 Avg Acid Vol Catch

Cone Conversion DF (mL) Weight Qual

(uglmL) Factor (ug) .

0.205 1.028 10 294 617
**~--P5Run2-rtiil** 1 041-5001.o 1 041-50o2.o 1 HPLcs:lf'Gee.rilll-4.27 1 4.27 1 o.o 1 o.806 TJfs12Co:4T-cfso9-r t.oz8 1 10 1 zn 1 z,z59 1 1

en""'" mlj;m "1lzS: -<-<- menen I P5 Run 31nA --1 042-51Q_1.D I 042-510i6jHPLC53PQ9(rV1T4j7[;f:rt I o.o I 1.15 I 1.14 I 0.3 I 1.14 _I __ 1.028 I 10 I 246 I 2,887 I I **~**

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I P5Run20utA I 044-5761.0 I 044-5702.D I HPLC53PG98.M [4.26T4:261 o.o I 0.115 1-o-:115--) 6.2 I 0.115 I 1.028 I 10 I 239 I 283 I J I

I P5Run30utA I 045-580-1.D I 045-5802.0 I HPLC53PG98.M P26}T26-I o.o I 0.114 I 0.118 [2]]--5:1fs-r 1.028 I 10 I 261 I 312 I J I

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I o.01N H2S041NaOH RBI oQ8:'o901.0 I 008-0902.D I HPLC53PG98.M 1-NATNA I NA I 0.00695 I o.00695 I o.o I o.oo695_1_ 1.028 I 1 I 1.00 I 0.00714 I NO I

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, **~** I 0.01N H2S041NaOH RBI 008-32010 I 008-3202.0 I HPLC53PG98.M I NA I NA I NA I 0.00695 I 0.00695 I 0.0 I 0.00695 I 1.028 I 1 I 1.00 I 0.00714 I NO I

z **~** I 0.01N H2S04/NaOH RBI 103-5601.D I 103-5602.D I HPLC53PG98.M I NA I NA I NA I 0.00695 I 0.00695 I 0.0 I 0.006951 1.028 I 1 I 1.00 I 0.007141 ND I

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EO Parameters EPA Method 26A (H2S04) #Samples 18 Runs, 2 Blanks Client# P-10124 Job# 0910-96 PO# P-10124 Report Date 101612010

MDL 0.00695 (ug/mL) LOQ 0.200 (ug/mL) Lower Curve Limit 0.200 (ug/mL) Upper

Curve Limit 15.0 (ug/mL)

Compound Hydrogen Chloride as Chloride Sample Lab 10 LabiD Analysis Ret Ret

% Diff Cone Cone

% Oiff

10

# 1 #2 Method Time Time

Ret # 1 #2

Cone

(min) (min) (ug/ml) (ug/ml)

MS Salisbury R1 In A 010-1101.0 010-1102.0 HPLC53PG98.M 4.25 4.25 0.0 3.65 3.65 0.0

I MSDSalisburyR1lnA 1011-1201.0 011-1202.0 I HPLC53PG98.M 4.26 4.26 I 0.0 I 3.45 3.45 0.1

I MS P4 R11nA I 027-3401.0 I 027-3402.0 I HPLC53PG98.M I 4.26 I 4.26 I 0.0 I 3.05 I 3.06 1 0.1 I

I MSO P4 R11nA I 028-3501.0 I 028-3502.0 I HPLC53PG98.M I 4.26 I 4.26 I 0.0 I 3.07 I 3.08 I o.o I

I HPLC53pg98#LCS I 007-0801.0 I 007-0802.0 I HPLC53PG98.M I 4.26 I 4.26 I 0.1 I 5.00 I 5.01 I 0.1 I

I HPLC53pg98 #LCS I 007-3101.0 I 007-3102.0 I HPLC53PG98.M I 4.26 I 4.26T 0.0 I 5.01 I 5.01 I o.o I

0910-96 res EA#

0910-96 Page 14 of 202 Avg Acid Vol

Cone Conversion OF

(ml) (ug/mL) Factor 3.65 1.028 1 10.0 Spike Amount (ug) Native Amount (ug) Spike

Recovery (%)
3.45 I 1.028 1 10.0 Spike

Amount (ug) Native

Amount (ug) Spike Recovery (%)
3.06 1 1.028 1 1 1 10.0 Spike

Amount (ug) Native Amount ( ug) Spike Recovery (%)

3.07 I 1.028 I 1 I 10.0 Spike Amount (ug) Native

Amount (ug) Spike Recovery(%)

5.01 1.028 I 1 10.0 Spike

Amount ( ug) Spike Recovery (%)

5.o1 r 1.028 T 1 I 10.0 Spike Amount (ug) Spike Recovery (%) Catch Weight Qual (ug) 37.5 30.8 5.47 104% 35.5 I 30.8 5.47 97.3%

. 31.4 I 30.8 2.20 94.7% - 31.6 30.8 2.20 95.4% 51.5 51.4 100% - 51.5 51.4 100% 10/6/2010 CD 0 **~** r CD ::0 (i "' en)> c **~** () "1l :0 0 **~** m '1 z 0 :!: " .. "' Gl em (1)"1l ... ,. l>fi (}),, mS::m "1lz.: -i-<- m(J)(J) **s::~!::2** ro.,o **~Olz**

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EO Parameters EPA Method 26A (H2S04) #Samples

18 Runs, 2 Blanks Client# P-10124 Job# 0910-96 PO# P-10124 Report Date 10/6/2010

MDL 0.00695 (ug/ml) LOQ 0.200 (ugiml) Lower Curve Limit 0.200 (ug/mL) Upper

Curve Limit 15.0 (ug/mL)

Compound Hydrogen Chloride as Chloride Sample Lab ID Lab ID Analysis Ret Ret

% Diff Cone Cone

% Diff

10

# 1 #2 Method Tlme Time

Ret # 1 #2

Cone

(min) (min) (ug/ml) (ug/ml)

HPLC53pq98 #LCS 102-5501.D 102-5502.0 HPLC53PG98.M 4.26 4.27 0.0 4.88 4.87 0.1

HPLC53pg100 #LCS I 007-0801.0 J 007-0802.0 I HPLC53PG100.M I 4.25 L 4.25 I 0.0 I 4.92 L 4.92 J 0.1 1

0910-96 res EA#

0910-96 Page 15 of 202 Avg Acid Vol Cone Conversion OF

(mL) (ug/ml) Factor 4.87 1.028 1 10.0 Spike

Amount (ug) Spike

Recovery (%)

4.92 I 1.028 1 1 1 10.0 Spike

Amount (ug) Spike Recovery (%) Catch Weight Qual (ug) 50.1 51 A 97.5% 50.6 51.4 98.4% 10/6/2010 I OJ 0 **~** .- "' :0 i'i " (1)"' c "'<

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or-< (ii"U "'" co **,~** -<m "U() <;;--< z --< "' Company Analytical Testing Consul Analyst EO Parameters EPA Method 26A (NaDH)

#

Samples 18 Runs, 1 Blank

MDL 0.00695 (uglmL) LDQ 0.200 (uglmL) Compound Chloride Sample LabiO Lab 10 Analysis

10

# 1 #2 Method Client# P-10124 Job# 0910-96 PD # P-10124 Report Date 101612010
Lower Curve Umit 0.200 (ug/mL) Upper

Curve Limit 15.0 (ug/mL)

Ret Ret

% Diff Cone Cone

% Diff

Time Time #1 #2
(min)

(min) Ret

(uglmL) (ug/mL) Cone Avg Cone (ug/mL)

Salisburv Run 1 In B 017-2001.0 017-2002.0 HPLC53PG98CL.M 4.23 4.23 0.0 **o.221_..._g,~** _lJ_ _o.22L Aliquot Vol Catch
OF Weight Qual Factor (mL)

(ug)

1 10 172 382

I Salisbury Run 21n 8 I Of8-2101 D I **018~2102.bl**

HPLCS3PG98CLM 1-4.23 14.231 bY]-0.0797] 0.0760 I

2.3 I

0.0779 I

1 I

10 I

260 I

202 I

J I

I Salisbury Run 31n B I

019-2201.0 I

019-2202.0 I HPLC53PG98CLM I

NA I

NA I

NA I

0.008951 0.006951 0.0 I

0.00695 I

1 I

10 I

257 I

17.8 I NO I

I Salisbury Run 1 Out

**ifi223~2601.oTo23-26o2:5JHPCC53PG98CL:wq** 4.15 I

4.15 [Jf[T7.48--!"""?:39-CO:Iq=y4 I

1 I

100 I

181 I

134,815 I I

I Salisbury Run 2 Out 8 I

021-2401.0 I

021-2402.0 I HPLC53PG98CL.M I

NA I

NA I

NA I

0.00695 I

0.00695 I

0.0 I

0.00695 I

1 I

10 I

207 I

14.4 I NO I

I Salisbury Run 3 Out B I

022-2501.0 I 022-2502f5THP[C53PG98CL.Ml424 14.241 o.lfT 2A2-- I

-2.36 -TT2 I **n2~39_]_1** TJ

0 I2[8 I

6,408 I I

I P4 Run 1ln a·To34:.,j:J51]) 1634-43o2J?THPLCSJPGS8CL.Mf423 [-NA, NA] o:m· lll.00695]92.2 I 0:088il_!_1_I::W@5T

**221"-=r-J~**

I

P4 Run 21n 8 I

035-4401.0 I

035-4402.0 I HPLC53PG98CLM I

NA I

NA I

NA I

0.006951 0.006951 0.0 I

0.006951 1 I

10 I

262 I

18.2 I NO I

I P4 Run 31n B I

036-4501.0 I

036-4502.0 I HPLC53PG98CLM I

NA I

NA I

NA I

0.00695 I

0.006951 0.0 I

0.00695 l

1 I

10 I

254 I

17.6 I NO I

"' "1J **~** I

P4 Run 1 Out B I

037-4601.0 I

037-4602.0 I HPLC53PG98CL.M I

NA I

NA I

NA I

0.00695 I

0.00695 I

0.0 I

0.00695 I

1 I

10 I

244 I

16.9 I NO I

z **~**

I

P4 Run 2 Out B I

038-4701.0 I

038-4702.0 I HPLC53PG98CL.M I

NA I

NA I

NA I

0.00695 I

0.00695 I

0.0 I

0.00695 I

1 I

10 I

269 I

18.7 I NO I

j; **~-·**

I

P4 Run 3 Out B I

039-4801.0 I

039-4802.0 I HPLC53PG98CL.M I

NA I

NA I

NA I

0.006951 0.006951 0.0 I

0.006951 1 I

10 I

217 I

15.1 I NO I

z 0 **~** "' 0910-96 res EA#

091 0-96 Page 16 of 202 101612010 "'

0 **~** .- "' :0 0 "' (J)**~** " ::0 0 **~** m '1 z ? **~** '" .. "' }> c Qm c" **~}>** »o w""' mlj;m

-uz;::

--<--<- mwU> **s:""~** Ol.,O ';Jc.nZ
-

--< "'wm **~)>CI>** or-< c;;-u Ol::O co **::o~** -<m "0 lj;--< ?:i '" }> Company Analytical Testing Consul Analyst

EO Parameters EPA Method 26A (NaOH)

# Samples 18 Runs, 1 Blank

MDL 0.00695 (u9/mL) LOQ 0.200 (ugtmL) Compound Chloride Sample Lab ID Lab ID Analysis

ID

# t #2 Method Client# P-10124 Job# 0910-96 PO# P-10124 Report Date 10/6/2010
Lower Curve Limit 0.200 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Ret Ret

% Diff Cone Cone

% Diff

Time Time #1 #2
(min)

(min) Ret

(ug/mL) (ug/mL) Cone:

P5 Runt In B

---- _046-590t ,D_ 046-5902.0 H_pLC53PG98CLf>1 NA NA - NA 0.00695 0.00695 0.0

----··- Avg

Aliquot Vol Catch
Cone

OF Weight Qual (ug/mL) Factor (mL)

(ug) 0.00695 1 10 241 16.7 NO

**~--** P5 Run 21n-B I **047-aooi~b** I 047-60b2]j] HPLC53PG98cLMT 1'1/Cr-NA" [ NAT0:00695] o.00695 1 o.o 1 o.00695 1 1 1 10 1 226 1 15.7 1 ND 1

I P5 Run 31n B I 048-6101.0 I 048-6102.0 I HPLC53PG98CL.M I NA I NA I NA I 0.00695 I 0.00695 I 0.0 I 0.006951 1 I 10 I 250 I 17.4 I NO I

**~--** P5 Ru/11-oUIB I 649:e'201:"o I o49.:a?OWJ HPLC53PG98CLMI. NA [ NA !NIITif00695 r-o.oo6¥["f6Jo.oo695) 1 I 10 1 199 1 13.8 1 No 1

I P5 Run 2 Out B I 050-6301.0 I 050-6302.0 I HPLC53PG98CL.M I NA I NA I NA I 0.006951 0.006951 0.0 I 0.006951 1 I 10 I 224 I 15.5 I NO I

I P5 Run 3 Out B I 051-6401.0 I 051-6402.0 I HPLC53PG98CL.M I NA I NA I NA I 0.00695 I 0.00695 I 0.0 I 0.00695 I 1 I 10 I 231 I 16.1 I NO I

c saseBiank- ro53-680T"o 1 o53-68o2.bJ HPLC53PG98CL.M 1 **4~2IT4J:H-o.o** 1 o.oz35-fa-:tlz31 1 oe-r o.o233 1 ,--T 10 1 w 1 34.2 1 J 1

I DIH20blank I 054-6901.0 I 054-6902.0 I HPLC53PG98.M 14.2914.291 0.0 I 0.113 I 0.0436 144.31 0.0783 I 1 I 1 I 147 I 11.5 I J I

@]! N H2S04TNaoH R\31 008-090Ui I oo8-(j96i5] HPLC53PG98.M [ NA l NA I NA 0.06695 I 0.00695 ra.o I 0.00695T- 1 I

. ,-n:QC)[o.00695 I NO I

**~** I 0.01N H2S04/NaOH RBI 008-3201.0 I 008-3202.0 I HPLC53PG98.M I NA I NA I NA 0.00695 I 0.006951 0.0 I 0.006951 1 I 1 I 1.00 I 0.00695 I NO I

z **~** I O.OtN H2S04/NaOH RBl103-5601.D 1103-5602.0 I HPLC53PG98.M I NA I NA I NA 0.00695[ 0.006951 0.0 I 0.006951 1 I 1 11.00 I 0.006951 NO I

" **~** I 0.01 N H2S04/Na0H RBI 008-0901.0 I 008-0902.0 I HPLC53PG1 OO.M I NA I NA I NA 0.00695 I 0.00695 I 0.0 I 0.00695 I 1 I 1 I 1.00 I 0.00695 I NO I

m z ? w .. .. 0910-96 res EA#

0910-96 Page 17 of 202 10/6/2010 Ol 0 ?2 r Ol ::0 0 6i}> c **~** "

;u 0 **~** m 'l z ? ::: "' .. "' Gl em (J)" -;> >c; (J)-o;u

mlj;m -oz.: -<-;- m(J)(J) **~.,..~** m"'o ;uo.z
-

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oc_-i

(J)""il

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co **,~** -<m "() r;:-< z --< "' }> " "

m z 0 x " i!i m z ? "' .. "' I I Company Analytical Testing Consul Analyst

EO Parameters EPA Method 26A (NaOH) #Samples 16 Runs, 1 Blank Client# P-10124 Job # 091 0-96 PO# P-10124 Report Date 101612010

MDL 0.00695 (uglmL) LOQ 0.200 (uglml) Compound

Chloride Lower Curve Limit 0.200 (uglmL) Upper Curve Limit 15.0 (uglml)

Sample LabiO LabiD Analysis Ret Ret

% Diff Cone Cone

% Diff

Time Time # 1 #2

10 # 1 #2 Method

(min) (min) Ret

(uglmL) (uglml) Cone

HPLC53pg98 #LCS 007-0801.D 007-0802.0 HPLC53PG98.M 4.26 4.26 0.1 5.00 5.01 0.1

HPLC53pg98 #LCS I 007-3101.0 I 007.;)102.0 I HPLC53PG98.M I 4.26 4.26 0.0 5.01 5.01 I 0.0 I Avg Cone (uglmL) 5.01 5.01 HPLC53pg98#LCS I_ 102-5501.0 I 102-5502.0 I HPLC53PG98.M I 4.26 4.27 0.0 4.86 I 4.67 I 0.1 I 4.87 I

0910-96 res EA#

0910-96 Page 18 of 202 Aliquot Vol

OF

Factor (mL)

1 1 10.0 Spike Amount (ug) Spike Recovery (%)

1 1 10.0 Spike Amount (ug) Spike Recovery (%)

1 I 1 10.0 Spike

Amount (ug) Spike

Recovery(%) Catch Weight Qual (ug) 50.1 50.0 100% 50.1 50.0 100% 48.7 50.0 97.5% 101612010 I "'

0 **~** .... "' ;u (i "' (J)ATC PROJECT No. P-10142 BORAL BRICKS



# Narrative Summary

EA# 0910-96 Paae 19 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 346BORAL BRICKS 

# Enthalpy Analytical Narrative Summary

. .

!:!}.;

**Sll.sJtg~ly•••·•·** 

## David Eckard received the samples on 9/24/10 after being relinquished by Analytical Testing Consultants fnc. The samples were received at 15.9°C and in good condition. Samples 

## Plant 5 Inlet and Outlet Runs 

# Li
.. } 

# :.>• : . 2 

## and 3 were received in glass. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.



## ;ijj~\~HX•R The samples were analyzed for hydrogen chloride (HCI), hydrogen fluoride (HF), and chloride using the analytical procedures in EPA Method 26A, Determination of Hydrogen Halide and Halogen Emissions 11-om Stationary Sources !so kinetic Method (40 CFR Part 60, Appendix A). With the exceptions noted above, all samples and standards were prepared, stored, and analyzed using high-density polyethylene containers. The Metrohm 861, High Perfom1ance Liquid Chromatograph "Mr Burns" 

## (SIN 1861004003180) was equipped with a Metrohm 861 

# ;;;F ,.•}/;').••••••.•.·.·:·.. ::···· c· i Conductivity Detector and a Metrosep A Supp 5
- ll 0/4.0mm column 

## (SIN 

## # 7908297), for these analyses. 

# ·y •

**•·(~alll:iiril'tioli** 

## • .. (. The calibration curves are included in the Calibration Curve

**C!hr()~!ll?g~!!Phic** 

## C!!I!Iditiops

ATC PROJECT No. P-10142 

## Chromatograms section ofthis report and referenced in the Analysis Method column on the Detailed Results page. For each calibration curve used, the first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantity the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantity each target compound. The acquisition method Metrohm.M is included in the Calibration Curve Chromatograms section of this report.

**EP~/5-§li!Jtfffillf~IJ~r?Sf** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 347BORAL BRICKS 

# Enthalpy Analytical Narrative Summary (continued) Fluoride was not identified above the MDL inthe analyses of the lab . reagent blanks and client 01 H20 blank. Fluoride was detected below



# ;;l"t,,;;;\.(0',/,~t;i,;:'; the LOQ in the acid blank.



## ~'~1·;~'i[.!~in!''(f;c,' Chloride was not identified above the MDL in the analyses of the lab (:, reagent blanks and client acid blank. Chloride was detected below the LOQ in the client base blank and Dl 

## H20 blank. Matrix spike and matrix spike duplicates (MS and MSD) were prepared using aliquots of the samples 

## Salihury Rl-In A and 

## P4 Rl InA. The recovery values were 111%, 91 .3%, 103%, and I 

## 05% for HF. The recovery values were 104%,97.3%, 94.7%, and 95.4% for HCJ. Laboratory Control Samples (LCS) were prepared and analyzed with the samples. TI1e recovery values ranged from 104% to 107 for HF and 97.5% to 100% for HCL. The samples were analyzed within the four-week holding time specified by the method. The results presented in this report are representative of the samples as provided to the laboratory. The H 2

## S04 

## matrix samples were analyzed for Cl- and F- but are reported as HCI and HF. The results were converted using an acid conversion factor of 1.028 for HCI and 1.053 for HF. Enthalpy Analytical, Inc. is accredited to perform EPA Method 26A for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

EA# 0910-96 

## Page 21 

## of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 348BORAL BRICKS 

# General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, Inc. data reports, unless specifically noted otherwise. • The acronym MDL 

### represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. • The acronym LOQ 

### represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyle of interest within the criteria of the method. • The acronym 

### ND following a value indicates a non-detect or analytical result below the MDL. • The Jetter 

### J following a value indicates an analytical result between the MDL and the LOQ. A J 

### flag indicates that the laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. • The Jetter E 

### following a value indicates an analytical result exceeding I00% of the highest calibration point. The associated value should be considered as an estimate. • The acronym 

### DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. • The addition of MS 

### to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis ofthe analyte(s). • The addition of MSD 

### to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. • The addition of LD 

### to the Sample lD represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ). • The addition of AD 

### to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. • The Sample lD 

### LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matdx, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory's analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. The extras (randomly chosen) are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection and/or sample transport.

ATC PROJECT No. P-10142



### EP~Mf&fl.,ll!lS/GN!ff!g'f **~fl<i'JEil:!¥2** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 349BORAL BRICKS 

# General Reporting Notes (continued)
• Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 signiticant figures. For example, a value of 10,456.45 ug catch is rounded to I0,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. • Manual Integration: The data systems used for processing will flag manually integrated peaks with an "M". There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations. The peak was 

### not integrated by the software "NI", the peak was 

### integrated incorrectly by the software "II" or the 

### wrong peak was integrated by the software "WP". These codes will accompany the analyst's manual integration stamp placed next to the com pound name.

ATC PROJECT No. P-10142



### EP~ft~8ll.ll~'§l8l'f~ **~Ml~** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 350ATC PROJECT No. P-10142 BORAL BRICKS



# Sample Custody

EPI'EM

**~~fi38R!N ~PM:i.lta112**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 351BORAL BRICKS 

# ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)·733·3193 CHAIN OF CUSTODY RECORD Project No. 

## P-10124 REQ\JESTEC PARAMETERS CLIENT: BoraJ Bricks 11El1100 !l'LEA61i CIHCI.£) 5 6 8 PLANT LOCATION:

**Augu~ta,** 11 18 

### 23 2S 26 SAMPUNQ LOCAllON: Plant 4 In 

### et VOST MULTIPLE-METALS OTHER SAMPLE 10: Run #1-HCI-Container 

### 3 Run

**#2~HC1-Contalner** 3 Run #3-HCf..Contalner 3 Container #6-HCI
Run #1-HCt-Container 4 Run #2-HC!--Container 4 Run #3·HCJ..Confainer 4 container 

### #7 -HCI


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# wt~~ RE\.INQUISHEt> BY AELO REMARKS:

NOTE: FORI.! No. A T'C 1 DATE TIME 1.0CAT10N VOI.l.JM£ IML) OR fll,;fl.l\ I CONTAINER: CONTENTS 9.15.10 

# I \,t CFA Acid lmpingera Catch 

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### & 01 Rinse 

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## •·
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### ··.·•·



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# ?:. Alkaline lmplngers CFA -200 mL Catch 

### & 01 Rinse
' 

## ' Alkaline lmpingers CFA 

### -200 ml Catch 

### & 01 Rinse 

# · ............ Alkaline Blank-Dilute to CFA -100 mL approx. volume of field 

# /. samples with 

### 01 water. 

# '.'_2 CFA 

### -100 mL Dl Water Blank OATE 

# n•• RECE!VIW8Y DATE TIME 

# cr/t 'f I {,tl.ii:>' • 

# J', 'l."'

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# ~ .:k:lll\ 10. DATE TIME RECEIVED BY OAT!! To.IE 

# I CFA: CLEAN FIELO AREA AnalyZe for HCI. HF and Cl2 per USEPA Method 26A procedures PLEASE MAAK LIQUID LEVEL ON ALL SAMPLE BOTTLES WITH GREASE PENCIL. SEAL TIGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL. 

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C:\SOrl\1 ICR\COC'IIIJ\II26A COC)P!ant 4 Inlet• HCI HF Cll

ATC PROJECT No. P-10142 

### EA# 0910-96 Page 

### 25 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 Ver 1.0 29 August 2003

APPENDIX PAGE No. 352BORAL BRICKS 

# ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)·733·3193 CHAIN OF CUSTODY RECORD Project No 

## P-10124 REQUESTeD PARAMETER$-

**CUENT~** Boral Bricka 1116TI4GD ji'L£o\Slil Cll'tC'I."£1 5 6 8 PlANT LOCATIOn: AUgusta, bA 11 18 

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# .> CFA -250 mL Acid lmpingers Catch & Dl Rinse Run #3-HCI-Gonlainer 3 

## .··.•

# \ 

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### ·.·

## ......-.



### ·---···-.· Run #1·HCI·Container 4 

# I 

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### .·-··.····

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# I FiELD REMARKS: ICFA: CLEAN FIELD AREA Analyze for HCt HF and C!2 per USEPA Method 26A procedures
NOTE: FORM flo.ATC 1 PlEASE MARK LIQUID LEVEL ON ALL SAMPLE BOTTLES WlTH GREASE PENCrL SEAL TfGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL. 

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ATC PROJECT No. P-10142 

### EA# 0910-96 Paqe 26 of 202 EPA ICR E'MISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 353BORAL BRICKS 

# ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)·733-3193 CHAIN OF CUSTODY RECORD Project No 

## P-10124
CUENT' Bo"'l Blici<S PLANT LOCATION: DATI TIME



### ~~ 

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# LY DATE TIME >BY OA; TIME 

## 'i./l'f 

# ltu:,.fl.t>\.

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# ID]'S" TIME >BY DATE TIME JvrA: CLEAN FIElD AREA Analyze for HCI. HF and Ct2 per USEPA Method 26A procedures
PlEASE MARK UQWO LEVEL ON All SAMPLE BOTTLES WITH GREASE PENCIL. SEAL TIGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL. .



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C:\BOtaiiCR\COC's\M26A COC\Plllnt

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**~** HCI HF Cl2 Ver 1.0 29 August 2003

ATC PROJECT No. P-10142



## EPA'~~gslf.§NI'ffi\!r **~MJ?d¥** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 354BORAL BRICKS 

# ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)-733-3193 CHAIN OF CUSTODY RECORD Project No. 

## P-10124 REQUESTED PAR.AMIHERS cueHT: Boral Bltelcs lolll:THOD

**/l"t.~Sf** CIR<:lfi!) 5 6 

### 8 PLANT lOCATION: **i\~Sta~_~_!.** 11 18 23 25 2$ SAMPUNQ LOCATIOU; Plant

**~Outlet** VOST MULTIPLE-METALS OTHER SAMPLe 10: DATE TU<! LOCATION Yot.Wi.E (IilLI OR Flt.TE:R II CONTAINER CONTENTS Run #1-HCI-Container 3 9.17.10 

# !,\:') CFA Acid lmpingers CatCh 

### & -250 mL 

### OJ Rinse Run **#2-HCJ~Container** 3 

# ··g. CFA Acid lmpingers Catch 

### & -250 mL 

### Of Rinse 

# ·:' Acid lmpingers Catch & Run #3--HCI-Contafner 3 CFA -250mL 01 Rinse



# ~:/ ;.·· Alkaline lmpingers Run #1-HCI-Conlalner 4 CFA -200 mL Catch 

### & Dt Rinse 

### Run #2-HCI-Container 4 

# n•: CFA Alkaline lmpingers -200 ml catch 

### & 

### Of Rinse Run #3--HCI-Ccntainer 4 

# IS
.. ) CFA Alkaline lmpingers 

### -200 mL catch 

### & 01 Rinse 

# 1> I'·-:·
. 

# 1\")!.\-' REUNOUJSHED BY DATE TIME RECEIVED BY DATE TIME



# 0lll..s-

**t/rt.'lt.~** 1/<1;,{ 

# .-E:;;... 

# ~,Q"'-AJ~ 

# •Ina cu 

# ,J,s REUNQUISHEO BY FIELD REMARKS:

NOTE: FORA! N.,. AlC 1 DATE TlME RECEIVED BY DATE TIME 

# I I CFA: CLEAN FJELD AREA Analyze for HC!, HF and Cl2 per USEPA Melhod 26A procedures PlEASE MARK liQUID lEVEl ON All SAMPLE BOTTLES WITH GREASE PENCIL. SEAL TIGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL 10 202 26A INfTlALS



## BK

**C~OI'lll** ICR\COC's\M26A GQC\Plan15

**outset~** HCi HF C!2. Ver 1.0 29 August 2003

ATC PROJECT No. P-10142 

### EA# 0910-96 Paqe 

### 28 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 355I

\ BORAL BRICKS 

# ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)·733·3193 CHAIN OF CUSTODY RECORD Project No. P-10124 REQUESTED PARAMETERS CliENT: Bora! Brfcks U£Tii00(PIL<I81! C.JIICU!) 5 

## a 8 PLANT lOCATION: Sa 1SbUty, NG 11 18 23 

### 25 26 SAMPWHOl0CA1'lOH!

**lola~** VOST MULTIPLE-METALS OTHER SA.MPI..E 10: DATe TIME LOCATION VOlOlot!' ftollJOR""-f!RJ CONTAINER CONTENTS '' :: Acid Jmpingers Catch 

### & Run #1-HCI-Conlainer 3 

### 9.21.10 CFA -250 mL Dl Rinse 

# : Acid lmpingers Catch 

### & Run #2-HCI-Conlainer 3 CFA -250 mL Dl Rinse Run #3-HCI-Container 3 

# \ CFA -250 mL Acid lmpingers Catch 

### & Dl Rinse



# ..



# . < Run #1-HCI-Contalner-1 

### .....•....•.. CFA -200 ml Alkaline lmpingers Catch 

### & Dl Rinse '·.· Alkaline lmpingers 

### Run #2-HCI-Container 4 CFA -200 mL Catch 

### & 01 Rinse 

# ·····.·. Alkaline 

### I mpingers Run #3-HCI-Contalner 4 .... CFA -200ml Catch 

### & Dl Rinse

! (,\ ·: 

# c RELINOUlSHEO BY OATe TIME AECEIVF..OBV 

### DATE TIME



### l.vj( 

# ,P, ..! 

## 1/z"-lt •• 

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**~ L~C** 

# ,iJ

**~_!{}_** 

# -d 9XJrO 

# rb '"') Ra.INO ISHED BY OATe TIME RECEIVeD 9V OATE TIME 

# I FIELD REMARKS: CFA: CLEAN FIELD AREA Analyze for HCI, HF and Cl2 per USEPA Method 26A procedures NOTE: fORM No.ATG t . PLEASE MARK UOUlD LEVEL ON A•L SAMPLE BOTTLES WITH GREASE PENCIL SEAL TIGHTI.Y AND RE·CHECK UPON DELIVERY TO lAB PERSONNEL



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## BK

C:IBoraiiCR\COC's\M2SA COC\Sallsbury lnkn- HCI HF Cl2 Ver 1.0 29 August 2003

ATC PROJECT No. P-10142 EP.i:!Mlca-MGEOONitB§!I! 

### M<:Jillml2 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 356BORAL BRICKS 

# ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)-733-3193 CHAIN OF CUSTODY RECORD Project No. 

## P-10124 REQUESTED PARAMETER& CLIENT: Boral Bricks MrnlOO (l't.O.::Je ctllct.El 5 6 8 PLANT LOCATION: Sal

**Sb~ry,** NC 11 18 23 25 

### 26 SA.MPUNQ. LOCAT.ON:

**Utl~t** YOST MULTIPLE-METALS OTHER SAMPLe: 10; DATE TIME LOCATION \IOI,.VtU (lofl.) OR A\.TER I CONTAINER CONTENT$ Run #1-HCI-Container 3 

### 9.21.10 

# i·)i···· CFA 

### -250 ml Acid lmpingers Catch 

### & Di Rinse 

# i•. 

# ? CFA 

### -250 ml Acid lmpingers Catch 

### & Run #2-HCI-Container 3 Di Rinse Run #3-HCI-Container 3 

# I> 

# "< CFA 

### -250 mL Acid lmplngers Catch 

### & Dl Rinse

. \

. 

# \/

. 

## ' 

# _{/ 

# £2 Alkaline lmpingers Run
**#1~HCI-Container** 4 CFA 

### -200 ml Catch 

### & Dl Rinse Run #2-HCl-Container 4 

# ? .. CFA Alkafine 

### Impingers 

### -200 ml Catch 

### & Dl Rinse



### ................ Alkaline lmpingers Run #3-HCI-Contalner 4 CFA 

# -zoo ml Catch 

### & 

### Dl Rinse 

# [\;}i

. 

# i······ RELINQUISHED BY DATE TIME RECENEOEI'Y DAlE TIME



# t.v;L.o '( /z.<t'k,) 

# Vo: • ..--l-£l.u,;_ AXN'll 

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# sl4N 

# tol<k RaJHOU!SHt:;OBY DATE TIME RECCIVED BY DATE TIME 

# J FE REMARKS: CFA: CLEAN FIELD AREA Analyze for HCI, HF and Cl2 par USEPA MethOd 26A procedures NOTE: PLEASE MARK LIQUID LEVEL ON At.L SAMPLE BOTTLES WITH GREASE PENCIL SEAL TIGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL



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### 8K

C:\SOf'aiiCR\COC'3\M26A COC\Sa!M:x!ry Outlet · HCI HF Cl2 Ver 1.0 29 August 2003

ATC PROJECT No. P-10142 EA# 

### 0910-96 Page 30 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 357ATC PROJECT No. P-10142 BORAL BRICKS



# Sample Chromatograms**EPA~& ~rt1111lii~~** **fEil,9fp~1:B~t~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 358

### Sample Name: Salisbury Rl In A *20 0910-96 BORAL BRICKS **~=====================================::::==============================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/l/2010 9:27:01 PM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HnC20lOQ3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by 

### IGG {modified after loading) 10 1

ADC1 A, ADC1 c·HANNECi\iu·.IHPLC2010Q4\KlRBURNS\DATAIOCT\HPLC53PG981009·1001.D) uS/em 

# j



# 180] 160
. 140 120- 100- 80 60 40 

## ~ ,.; 

### I 

## f\ ' ("') : l ('? 

### r-:. {



# :t-~~ **,-~de~,~~"--.---~** 

# ... **,.c::::::;:::::;:::;::::=;:=::;::=:::;:::::;::::'..j~-.~~~~~** ) 

## L.~~~~~2 ___________ ±_____________ --- .--'".6 __ 

## "_-_·~--~~-"~~--~--'1.9 ______

## ··----------~·?;_==_~i~ ===================================================================== External Standard Report **======~====-===================~=====================================** 

### Sorted 

### By Calib. Data Modified Signal 10/4/2010 1.0000 9:29:44 AM Multiplier Dilution Ose 

### Multiplier 

### & 1.0000 Dilution Factor 

### with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTirne Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.125 

### BV 467.71011 1.70755e-2 7.98639 Fluoride 4.257 BB 17.94451 2.96828e-2 5.32643e-l Chloride 'rotals : 

### 8.51904 **==========:.:.:=========""'~"'====:;;:======='=======================""-'=""====:====** 

### *** End of Report ***

Ins 

### trumen tAlC 

## I?Q&.llt<2"0~6. P.l1dlil42 

### 25 AM IGG 

## EPf(2;U~1£sY8N **~~~f ~~6'JE~~**  **2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX **PAGi!'~~59** 1 of 1

### Data File 0:\HPLC2010Q4\MR B0RNS\DATA\OCT\HPLC53PG98\009-1002.D Sample Name: Salisbury Rl In A *20 0910-96 BORAL BRICKS 

## ===========<==========================,=============================== Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analysis Method 

### Last changed 

### EO 

### Mr Burns Seq. Line 

### Location 10/1/2010 9:39:20 PM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM 0: \HPLC2010Q3 \MR BURNS\METHODS\HPl.C53PG98. M 10/4/2010 9:26:06 AM by IGG (modified after loading} 

### 10 2

r----A"o'-'cTA.71oC1 CHANNECii (U:\HPLC2010041MR BURNSIDATAiOcT\HPLC53PG98\009--1Dil2".o"r _______ ]

**uS/em-~**

180 

## J j 160



### ~ j 140 

## •J 120



## -~ 1oo--i 80-

**=============~,=====e==================================================·** External Standard Report 

### -=·=============================""====================================«::= Sorted By 

### Calib. Data Modified Multiplier 

### Dilution 

### Signal 10/4/2010 9:29:44 AM 1.0000 1.0000 Use Multiplier &: 

### D.ilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL 

### A RetTime 'fype Area Amt/Area 

### Amount Grp Name



### [min] [uS/cm*s] 

### [ug/ll'.L] 

## -------l------l----------l----------l----------l--1------------------ 3.125 BV 467.69397 1.70755e-2 7.98612 Fluoride 4.257 BB 17.93629 2.96844e-2 5.32427e-l Chloride Totals : 8.51854

**=============================="-~=""·=============='======================£,** 

### *** End of Report

***~***

InstrumentAllC



## ~B0d6C?IOrlOI P91:0H2 

### 33 AM 

### IGG



## EPA~~ **~mJlsfbSN ~~~;.?o~~~~z**  AUGUST A PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# I 

# I

APPENDIX PAGI?POGI'll60 1 of 1

### Sample Name: Salisbury R2 In A *20 0910-96 BORAL BRICKS **============================~=====~==================================** 

### Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 

### 10/1/2010 10:40:59 PM Inj 

### C:\llPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METBODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG {modified after loading) 

### 13 1


## -·-i\oc1A: ADCTCHANNE[A (U:IHPTC2cffod4\MR!iiJRNS\i5AfAii5c'i\HPLC53PG98\012·1301 D) uS/em



### 180 160 140- 

### 120 100 80 

# " E 0

**~** 

### u: 

# I 

# )

**===========~=========================================================** External Standard Report 

## ===================================================================== Sorted By 

### Calib- Data Nodified Multiplier 

### Dilution Signal 

### 10/4/2010 9:29:44 AM 

### 1.0000 1.0000 Use Multiplier & 

### Dilution Factor •·.dth ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area

**Arnt/ll~rea** 

### Amount Grp Name

[min] [uS/cm*s] lug/mL] 

## -------i------l----------l----------l----------l--1------------------ 3.126 

### BV 467.74438 J.70755e-2 7.98698 Fluoride 4.257 BB 22.41548 2.90028e-2 6.50llle-l Chloride Totals : 

### 8.63709 **========'"""=~"""=·============================================c=====·"''""==;.>::=-""** 

### *** End of Report 

### ***

EA# 0910-96 

### Page 34 of 202 Instrument **AtC~~giJIJ9.** 

### ill-l@ll<22 5 AN IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGJ!'!'I6~61** 

### 1 of 1

### Sample Name: Salisbury R2 In A *20 0910-96 BORAL BRICKS 

## ===================,:.::=========,========,.,============================= Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed 

### Analysis ·Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/1/2010 10:53:19 PM Inj C:\HPLC2010Q3\t1R BURNS\t1ETHODS\METROHt1.t1 4/1/2010 4:15:36 PM U:\HPLC2010Q3\t1R BURNS\t1ETHODS\HPLC53PG98.M 10/4/2010 9:26:06 

### AM by IGG
. 

### (modified after loading) 13 2

**,---~·ADC.1** A, ADC1 CHANNEL A (U:\HPLC201004\MR BURNS\DATAiOCT\HPLC53PG98\012-1302.D)

============================================================,·==''"===== 

### External Standard Report **========================·================================'"-~============** Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal 

### 10/4/2010 9:29:44 AM 1. 

### 0000 1.0000 Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

(min] [uS/cm*s] [ug/mL] 

## -------!------l----------l----------l----------1--l------------------ 3.126 BV 466.99976 1.70755e-2 7.97425 Fluoride 4.257 

### BB 22.18078 2.90316e-2 6.43944e-1 Chloride Totals : 

### 8.61819 ===========================================================""<='======== 

### *** End of Report 

### ***



## InstrumentAIC~gClJI:Je. f!>1C!l11!l'33 AM !GG 

## EPfm'l,~~~sli~N~l **~~aJm** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE'i!Nge362 

### 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG98\013-140l.D Sample Name: Salisbury R3 In A *20 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed EO Seq. Line 

### Mr Burns Location 10/1/2010 11:05:39 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4;15:36 PM U:\HPLC201DQ3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG (modified after loading) 14 1

AOC1 A, ADC1 CHANNEL A (U:\HPLC201004\MR BURNS\DATA\OCT\HPLC53PG98\013-1401.D) uS/em

180 160 140 

### 120 . 100 80 50 . 40 **~**

**~** 

## A ! i t- 

# ---l

20-



### ~ 

## I\

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### :g 0



# _j:::--=--=-~. **'C.:.~:.:.::~=-~,j-=-~1~:;;~::- =--~,.'~::-**  ... ::";c:··=--=-=· 

# =,;;:C;.==r=~:::;:=::;==;;=::;::=:;:=::...,._-r_~~-~-,-~~ L.. ______ 

### 2

___________L _________ 

### 8,__ _____ ...:8,___ _____ **_.1~0**

### _____ __,12<-_'-"m""l ====,.=========<=<.e:====,=============""=='""=========================:====== 

### External Standard Report 

### "":<-'=====================================================.,====""======== Sorted By Calib. 

### Data Modified Multiplier Dilution Signal 10/4/2010 9:29:44 AM l. 

### 0000 1. 0000 

### Use Multiplier & Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNEL A RetTirne Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

### -------l------l----------l----------l----------1--l------------------ 3.126 

### BV 472.81418 1.70757e-2 8.07365 Fluoride 4.257 BB 25.90080 2.86355e-2 7.41682e-1 Chloride Totals : 8.81534 **=========,========""·====="''="""==-==-:-~==""==""=-======='-""=""====""==========""=====** 

## *** End of Report 

## ***

Instrument 

### AfCfrjlp<j!~i:>li.tJe- RJ-!fl¥?41 

### AM IGG 

### EP~~~IQs'I.§Nflm **~~&Jiiffi2** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 

### 2010 APPENDIX
**PAGp~e363** 1 

### of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\013-1402.D Sample Name: Salisbury R3 In A *20 0910-96 BORAL BRICKS **================================~====================================** 

### Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 

### 10/1/2010 11:17:58 PM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U: \HPLC201 OQ3 \MR **BURNS\~lETHODS** 

### \HPLC53PG98 .11 10/4/2010 9:26:06 AM by 

### IGG (modified after loading) 2 

### j-------··--A5C1_A, .. A0c1 CHANNEL A (U:\HPLC2010Q4\MR **BURNS:iJ5AfA\0Cl\HPCC53PG98\013~140'2.D)** 

### -·



## ===================================================================== External Standard Report 

### =========================================================="'--=""'======== Sorted By Calib. Data Modified 

### Mul tipl.ier 

### Dilution Signal 

### 10/4/2010 9:29:44 AM 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min) [uS/cm*s] [ug/mL] 

# -------l------l----------r----------r----------r--r------------------ 3.125 BV 471.29227 l.70757e-2 8.04764 Fluoride 4.257 BB 25.83895 2.86411e-2 7.40057e-1 Chloride Totals : 

### 8. 78769 

## *** End of Report 

### ***

1. 1.11.1 L2 1 

## n g .1 4 9 Al 

### EA# 0910-96 Page 37 of 202 Instrument 

### ATC"PRO"!JEC~Nb. **P-i~l'll** M IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX


### PAG~iJ.R.e364 1 of 1Data File U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG96\014-1501.D Sample Name: Salisbury R1 Out A *10 0910-96 BORALBRICKS **=======~===========~=================================================** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line Mr Burns JJocation 10/l/2010 11:30:18 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG 

### (modified after loading) 15 

### 1
---····ADC1A."l\DC1 CHANNEL A (U:\HPLC2010Q4\MR BURNSIDAT/\\OCf\HPLcSJPG98\0{4:Tsof:iS-)-···----·--··



# I 

# l uS/em 

# i 1801 160---i

**~** 140 

## -3



# 120~ 100

**~**



# 80~ j 60...,

**~**

**==============================~======================================** 

### External Standard Report ==,,==================""================================================ 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:29:44 AM 1.0000 1.0000 

### Use Multiplier & Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNEL A 

### RetTirne Type Area Amt/Area Amount Grp Name

[min] 

### (uS/cm*s] [ug/rnlJ] 

# -------r------r----------r----------r----------J--r------------------ 3.147 Fluoride 4,254 BV 3.17554 3.7B526e-2 1.20202e-1 Chloride 

### Totals ; 1 \"larnings or Errors Warning : Calibrated cornpound(s) not found =============""====================""="''""='-"'=""=""'===:===================== 

### *** End of Report 

### ***

Instrumen tAIC 

### !'89'49'\loiJlg. P31QIIJ!;? 57 AM IGG



### EPR~~ **g~1gs\l§N!f~!lr ~~c5'JEHf**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI!>IlJge'l65 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\0l4-l502.D Sample Name: Salisbury Rl Out A *10 0910-96 BORALBRICKS **=~=~==================~~=====~=======================================** 

### Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed 

### EO 

### Seq. Line 

### Mr_Burns Location 10/l/2010 11:42:38 PM Inj C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.

**~1** 

### 4/l/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\IIPLC53PG98.M 10/4/2010 9:26:06 AM by IGG (modified after loading) 

### 15 2



### -----ADC1 

### AADC1 CHANNEL A (U \HPLC201004\MR **!ilTRNS\iSI\fA\6CN·iPLCS3PG98\014-15026)-------~-~**



# uS/em~ j

1801 ' J ' ' 160

**-~** 

### 140 

# j



# 120~ 

# ·:l

I 40-1 

## ' 20

# j _______ j 

# ~-r----~-~-- **'-~1** 

# s .._ **~** 

# : J 0 

# 1------.---r·--~-·:..,...-r **·-~-',-'--',-----',:_·'-.I··:..,..._::··.::·,..·** _:··c:..•

# ,=---=-,-----,---~-:-~~---=.d-.~~-~ **---,----r--~-~--1** ___________**_,2~-----'4~---------~.§______** _a ___ 

### ~-·- 

## 1'o. 12 **=======================================================~=============** External Standard Report **======~===~==========~=============================~====~============** Sorted By Signal 

### Calib. Data Modified 10/4/2010 9:29:44 AM Multiplier 1.0000 Dilution 

### 1.0000 Use MuJ. tiplier & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEJ, A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/em* s] [ug/mL] 

# -------r------l----------r----------r----------r--r------------------ 3.147 Fluoride 

### 4.255 BV 3.03742 3.78526e-2 l.l4974e-l Chloride Totals : 

### l.l4974e-1 1 Warnings or Errors Warning : Calibrated cornpound(s) not found **=============~""=================="''=========-==========================""** 

### *** End of Report 

## ***

IGG 

### EPiE~!Iilrt~li'a!lll!~

AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 mi



### APPENDIX **PAGij_,~~e366** 

### l 0 f lData File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\015-160l.D Sample Name: Salisbury R2 Out A *10 0910-96 BORALBRICKS **====================================~================================** 

### Acq. Operator Acq. Instrurnen t 

### Injection Date Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/l/2010 11:54:58 PM Inj C: \HPLC2010Q3\MR B.URNS\METHODS\METROHM. M 4/1/2010 4:15:36 PM O:\HPLC2010Q3\MR BURNS\METHODS\HFLC53PG98.M 10/4/2010 

### 9:26:06 AM by IGG 

### (modified after loading) 16 

### 1

**~--··----** ADC1 A, ADCn:i'lANNEL A (U:\HPLC2010Q4\MR **BURNSIDATAIOCnHPLCSJPG08\015C1fj(j'j~i))-···--·------f** '· uS/em 

# J f 

# i I 1 

### j 

# I 180-:j 

# I
. ' 160 

# ·1 :::



# ~ I i 100 .. , j 

### so 

## j 60



### ~ 

### .2 .c 

# I 40 ·· u 

## I 2o



# ~ **~**
**~** re Ol 

# m 1 

# I '



### ~ C')M 

# c:J.:S

**~**

**~** 

# / 

# J l ___J **-.,__.---J-~--.-=--,--J~----** t -- **-~-- ------~**  

# L 0 **-----,-----~-~--, -1------,----,--~-~-r-,-~---~,----1---.----.,----.--** 

**~-........-----**

, _________ 2 ________ £._ ___ 

### ------~------~-L______ 10 12



### --~ External Standard Report **=:::.·.::-..;=-=======.:.:====================-==m=====~=============================** 

### Sorted By Calib. Data Modified I"'ul tiplier Dilution 

### Signal 10/4/2010 1.0000 

### 1. 0000 9:29:44 AM 

### Use Multiplier & Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm•s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.147 Fluoride 4.250 BV 2.24146 3.78526e-2 8.4845le-2 Chloride 

### Totals : 8.48451e-2 

### 1 Warnings or Errors Warning : Calibrated compound(s) not found **===============================================~====================~** 

## *** End of Report 

### ***

Instrument AlfClR:R<Jli,EM:NJ>.II}!Q1>1i113 AM IGG 

### EP~~<jilll\f~BJ'~1>~85~ AUGUST A PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAG!'il'll'e387 1 of 1Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\015-1602.D Sample Name: Salisbury R2 Out A *10 0910-96 BORAL BRICKS **==============<====================""'=========::::=============~:=<=========** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method 

### Last changed EO Seq. Line Mr Burns Location 10/2/2010 12:07:18 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 

### AM by IGG 

### {modified after loading) 16 

### 2

**~-------ADC1** A, ADC1 CHANNEL A (U:\HPLC201 004\MFf8[iRNSIDATAIOCnHPLC53PG98\015-1602.D) 

# i uSicmlJ 

# i i 180 

### ! 160- 140 

# I

I ' ' 

# J 10 ,.________ i2

__ 

# ._ml ====================================·===============================-== External Standard Report 

## ======:=================================-============================= Sorted By 

### Calib. Data Modified 

### Multiplier Dilution 

### Signal 10/4/2010 1.0000 l. 0000 9:29:44 AM 

### Use Multiplier 

### & 

### Dilution Factor with ISTDs Signal 1: ADC1 

### A, ADC1 CHANNEL A 

### RetTime Type Area Arnt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------1------l----------l----------l----------!--l------------------ 3.147 4.250 BV 

### Totals ; 2.29672 3.78S26e-2 8.69365e-2 8.69365e-2 1 Warnings or Errors 

### Warning ; Calibrated compound ( s) not found 

### Fluoride Chloride ========,=========================================""<========·==="'-=·"··==== 

### *** End of Report 

### ***

Instrument 

### ATC:fi!\O!I~I<WN9-®-Hl121j122 AM IGG 

### EPJI'~'l!IJI9ll/I:JJ'rl%'1-~MJ~ AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX **PAGp~368** 1 of 1

### Data 

### File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\016-1901.D Sample 

### Name: Salisbury 

### R3 Out A 

### *10 0910-96 BORAL BRICKS **============================================================~========** 

### Acq. Operator Acq. Instrument Injection Date 

### Acq. Method 

### J,ast changed Analysis Method Last changed EO Seq. Line Mr Burns Location 

### 10/2/2010 1:08:57 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10(4/2010 9:26:06 AM by IGG 19 1 (modified after loading) 

# r······--······ ADC1 A. 

### ADCTCHANNELA (U:IHPLC2ioo-i-1o"'o"•'"\Miii<R·'>sii'ufi,RO;N;cS"'ID"A"T"A'"IO"'C""n=H'"'P"LC"'5"'3"'P"'G"'9

.. 81"o1"6'·1"9"'0.1.D) 

# I



# us~:: I• 160. 140 120 100 80 60 40. 20 

# "

**~**

**·~** 0 

# "' <..) 

# I 

# I
' 

# I

**~ ~**  **~~** §



# ~ 

# I L--__ **o__~...2**

# ·."'.-_·...**~.---=---~4 ~~-+-**  ::::·:;;· 

### c:T''=;.:::..:;::···.::c·



# rc:::;::::·~:=,-:_:'""::· **:;:c::::;:;=:::;::::;::;:=:'_j~"""lr** - 

# -~,.--··--.----T·..

# ·---,----·~ ... **~** ___ _c.. _____ __,6._ _____ _,8c.._______._.1_0 _________ 

### g ___!l]i<j **===================~=================================================** External Standard Report **===========~============================~===================~========** Sorted 

### By Calib. Data Hodified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1. 

### 0000 9:29:44 AM Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTiroe Type Area 

### Amt/Area Amount Grp 

### Name



### [min] [uS/cm*s] [ug/rnL] 

## -------l------l----------l----------l----------l--1------------------ 3.147 Fluoride 

### 4.250 BV 2.17866 3.78526e-2 8.24680e-2 Chloride Totals : 

### 8.24680e-2 1 Warnings or Errors 

### Warning : Calibrated compound(s) not 

### found ============================'"-"===:=======================">.'=-==::=·======= 

### *** End of Report 

### ***

Instrument AID


## P!11P<I~GllH16. F!l1C!ll:!230 AM IGG



## EP~ **~\t,Ws?BN~~~f ~~c\'JJ:<fl**  AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGIP11kje369 1 of 1

### ( 

### Sample Name: Salisbury R3 Out A *10 0910-96 Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed BORAL BRICKS 

### EO Seq. Line Mr Burns Location 10/2/2010 1:21:17 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM O:\HPLC2010Q3\MR BORNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 

# AM by 

### IGG (modified after loading) 19 2

ADC1 A. ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNSIDATAIDCTIHPLC53PG9B\016-1902.D) uS/em

180
- 160 l40
100 80 60. 40 

## :g

**~ g~** 

**~** 

## ;:: 20



### ~ **~ ~~**  

# :,

0 **·----~'------,-----J~---.-'-···** 1----------1----- ;:; I · **r--~-'··-------r----·-J** 2 ____±_ 

## s ________L ______ 1Q_________ **=========""-====~"="":=-=.--~======================-===""==="===========--======>=·""=** 

### External Standard Report ===================================================================== 

### sorted By Signal Calib. Data Modified 10/4/2010 9:29:44 AM Multiplier 1.0000 Dilution 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mLJ 

## -------l------l----------l----------l----------l--1------------------ 3.147 Fluoride 4. 

### 250 BV 2.01728 3.78526e-2 7.63593e-2 Chloride Totals : 7.63593e-2 1 Warnings or Errors Warning : Calibrated compound{s) not found 

### *** End of" Report 

### ***

Instrument l 10/4/2010 9:32:38 Al1 IGG EA#0910-96 Page43of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 12

**mi~**



### Page 1 of 1 APPENDIX PAGE No. 370Data File U: \HPLC2010Q4 \MR BURNS\DATA \OCT\HPLC53PG98\017-2001. D 

### Sample Name: Salisbury Rl In B *10 0910-96 BORAL BRICKS**=====================~===============================================** 

### Acq. Operator EO Seq. Line 20 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 1:33:04 AM Inj 1 Acq. 11ethod C:\HPLC2010Q3\11R BURNS\11ETHODS\METROHI1.M Last changed 4/1/2010 4:15:36 

### PH Analysis Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL. M Last changed 10/4/2010 9:33:01 AM by IGG

. . ADC1 A, ADC1 CHAN'NEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCi\HPLCSJPG98\ciiT2o01.Df-·---- uS!cm 

# J

1801 160**-~** 

### 1 140 _j 

### l 120 

### -·1 100 

# 1 1 

# aol ru

# ~L-~---·r··-.J---~-·. __

# J !

# -~---,~·tr· -----' _)

# .--~'?:::;-~---=,_~-J

____ 2'-. _______

### _1_______________ 6 8 --·-·····--··-_1_(J_·----··--·-- 12 ml
===============================================================o======


### Sorted 

### By Calib. Data Modified Multiplier Dilution 

### External Standard Report Signal 10/4/2010 1.0000 1. 0000 9:32:52 AM 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal l: ADCl A, ADC1 CHANNEL A 

### RetTirne Type 

### Area Amt/Area fu-nount Grp Name

(min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------1--l------------------ 4.233 VB 6.20973 3.61257e-2 2.2433le-l Chloride 

### Total_s : 2.2433le-l**================:o==========================""========oo~o:::================** 

### *** End of Report 

### ***

### InstrumentA1[q~9~9Q'I)Ij~ FIJ1:0j14 09 AM IGG

### EPiJ~~**~~)£~ ~~Mo~~tH2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAGEP~'lJ~71** 1 

### of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\017-2002.D Sample Name: Salisbury Rl In B *10 0910-96 BORAL BRICKS 

### Acq. Operator EO Seq. Line 

### 20 Acq. Instrument Mr Burns Location 

### Injection Date 1072/2010 1:50:22 AM Inj 2 

### Acq. Method C: \HPLC2010Q3\MR

**BURNS\t~ETHODS\METROHM.M** 

### Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by 

### IGG 

### ~----·-··-·ADCTJ>.-;-!ibciCHANNELA(U:IHPL-;;Cc';2-;i01,;0;,;QC;4;'iiMT.R'c-iBUCfR"'N;iS'"\:;,Dc,A""TA"'I"'O"C"'T'"IH"P"L"c"'s"'3P"G"9"8"'10"1'7·""'2"'00"-2".o")c--~~~~-, 

# I . uS/em 

# ·j 

# I \1 

# :::J
II 

# 1 j



# ~ 

# l i 140

**--~** : 

# I :::

# l I 1



# BO~

**~** 

# i



# ~L) T



# !o.,--1~-~-~---**~,-_,_!** _ _:

__

# ~---~-----.,.-_--_-_-_ ...



# ~_

.._!_-



# -'--------~.-~~----_-/_! _______ lr .



# .,~-----~-·=--**:::-_-~-** • -



# -r=~l

**-~--·····-.-·-·--·** 

### .. ·-- ... **?.·-------~~---£__-----·----·---~--** 8 10 12 mi

**====================================~=~==============================** 

### External Standard Report
**=============================================================~======~** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:32:52 AM 

### 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] 

### [uS/cm*s] [ug/mL]
**-------J-~----I--~~~~~-~-)-~--------I-~~~------I~-J~----~-~-------~--** 

### 4.233 VB 6.02410 3.64293e-2 2.19454e-l Chloride Totals : 

### 2.19454e-1

**==~o:=====::o=:==============::;==o:==::"====""""'"'~·-"""'==============================** 

### *** End of Report 

## ***

Instrument AlfclfJR'clJE{;(f:wl,



## ~~1ili4219 AM IGG



## EP~!R **O~J~~1,g:r'l&~ ~~g~tg?**  AUGUST A PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PA~372** 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\018-2101.D Sample Name: Salisbury R2 In B *10 0910-96 BORAL BRICKS**==========~=========~================================================** 

### Acq. Operator EO Seq. Line 

### 21 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 2:07:41 AM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC201 0Q3\MR BURNS\METHODS\HPLC53PG98CL. e1 

### Last changed 10/4/2010 9:33:01 lll'l by 

### IGG

### r-=~- ADC1A. ADC1 CHANNEL 

### A(U :\HPLC201

### OQ4\A1R··~B;:,U~R"'N;:_S;;\D;.A~T~A~\O"c'"T'"\H""P"'L""C53~G9~o18-21 iWi5j-- 

# l**u~~:o** I

# ~ i ! 

# I 1so.. 1 

## ! 140 

# -i i 

## I 12o

# ~ 100

# ·l i I**ao~** 

# i**20~ ~** **~ ~** **~** g c.:t

## ~ 

# i \ i 

# I I



# I I ::

# ~**~** - N

# ~ - 0

# ~ i \ -i**______,.!:'_~-.--'__,....-~----,------'-~--** { 

### _"!,_ 1-tri- --,-----------I-···<O ___

.....



### :c;::=:;=::;::=:··'·::;:·.--'·-···**-~-"'---~-----** ·r- _________} 0**:f-.-~~--.-- ....,...--~-.~~-r··**  --,.. - ·,.----..,---,...----.-· 

### -;_-,,------1

_______ 2__**~L________** 

### _.,6'-------""- . 1 

### o 12 

### _!!!!**=====~===============================================================** 

### External Standard Report ===============================·=========================:::.:============ 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4(2010 9:32:52 AM 

### 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/rnLJ 

## -------[------[----------[----------[----------l--1------------------ 4. 225 BV 

### 2.10500 3 _78526e-2 7. 

### 96796e-2 Chloride Totals : 7.96796e-2**===,==========o."o==========·================~"=========:-:o=..:==========""~·"====******~** 

### End of Report 

### ***

Ins t 

### rumentAllC

## ~ll~JqC21DI'I<il P91flH2 2 7 

### AM I GG

## EPA~~~**~Bis sro** **N f~~** **pj~b~k~~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAG~'373** 1 of 1

### Data File U;\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG98\0l8-2102.D Sample Name; Salisbury R2 In B *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 21 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 2:24:59 

### AM Inj 2 Acq. Method C; \HPLC2 01 OQ3 \MR BURNS\METHODS \METROHM, M Last changed 4/1/2010 4:15:36 PM Analysis Method U; 

### \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL .M Last changed 10/4/2010 9:33:01 AM 

### by IGG



### ~- AI5cf A, ADC1 CHANNEL"i\(ii\HFLC2010Q4\MR 

### BURNSib'~A"T"'A"IO'-C"nH""P"'LCS·J-PG98\018-2102.D) 

# I



# u~:l· **~** 160 140 _j 

## j 120 

### -! J



### 100~ 

# I ' I 

# ;:13 40 ·! r-.. Nco



## ~ g CO N _,lj 20 -=j

**~** 

# q

**~** N m ; 

## g; \1 

# I I i N ("')
. -i ...,; 10 ((:) I 0 

## '.------~~·:.···+-, 'T-- 1 

# '·=.

**~-~-,f~·'-.:<;==** 

# ----,·-==;===·..J 

## \__ i 

# I

**.c.:::...r::C::;:::=;:=:;o::=;,.=~~** ' , -- -...,.--------,------- ,. ... I



## _______......L........ 4 6 8 

### ___ 1£.______1!1!!] 10 

## ===================================================================== External Standard Report
**=================~============================~======================** 

### Sorted 

### By Calib. 

### Data tvtodified Multiplier 

### Dilution Signal 

### 10/4/2010 9:32:52 AM 1.0000 1. 

### 0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal l: ADCl A, ADCl CHANNEJ ... A 

### RetTime Type Area Amt/Area Amount 

### Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 4.225 BV 2.00891 3.78526e-2 7.60425e-2 Chloride 

### Totals : 7.60425e-2 

## =="'"·====.-:o·::::======o:.==============="====c:::"o======""======""=============:===== *** End 

### of Report 

### ***

ATC PROJECT No. P-10142

**EP'~~,.,.....,~.~. ~""""'""2**  

### Instrument 1 10/4/2010 9:33:37 AM

**I~~ ~~~~~~**  **·~VONUUtt~v** IWGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGE~<qij74** 1 

### of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\019-2201.D Sample Name: Salisbury R3 In B *10 0910-96 BORAL BRICKS

**==============================================================~======** 

### Acq. Operator EO Seq. Line 

### 22 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 2:42:16 AM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG

**~-------ADC1** A. ADC1 CHANNEL A (U:\HPLC2010Q4\MR

**BURNS\DATAiOCT\HPLC53PG"9'"8"'I0"'1"9~-2'"2"'0 1."D")-**  

# -----------.1 j uS/em] [



## ~

I ' 

# :::J ;_, ! l . 

## i : 140 

## -J ! 

## i 1 120 

# j



# ~ r 

# I 1 

# 1 I ·!; I' 100-i 1 

### 1 I I .

**80~** I I 

### j 

# I i 

# ::Ll

**~,t_.**__,_; .J. __

# ! ; __)
. -- _\;:-_____ T __

# ___,__~L.. Q -T·



### --~-...,....- **c:~::;:=:::::;,=:::;.:=~cc;:==r=--** -.-----,...---···-r··----·1 1



### --~

_____ 2 __ 1._____ 

## s ...__a____ 10 _______ 1_?

___ r!J.llj

**=================================================================:=~~** 

### External Standard Report

**======~==========================================~===================** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1. 

### 0000 9:32:52 AM Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------i----------1--l------------------ 4.156 Chloride Totals : 

### 0.00000 1 Warnings or Errors 

### warnir:g : Calibrated 

### compound(s) not found

**=============~~~-~""=========~·o::========="'"-"'============""=""=""=========·'~=====**
**================="'·=======,=:c=======,========"-~========~=======c<'=======** 

### Area Percent Report

**======,=======-====""··~======""""""'""============::.:::'00======~==0'-';;;;============:oo:".=:** 

### Sorted 

### By CaJ.ib. 

### Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 9:32:52 AM 

### 1.0000 1.0000 Use Multiplier & Dilution 

### Factor with ISTDs
InstrumentAli_q\1\)-lljQTOI'I'!i PWJ:l14 

### 45 AM IGG



## EPR~ **Q~J£;~ ~~YfPWo'3\otCf2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGEP~g<875** 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\019-2202.D Sample Name: Salisbury R3 In B *10 0910-96 BORALBRICKS

**===~===========~==============================;======================** 

### Acq. Operator EO Seq. Line 22 Acq. Instrument Mr_Burns Location Injection Date 10/2/2010 2:59:34 AM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG

**~-----·ADCi"I\:ADG1** 

### CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATAIOCT\HPLCS3PG98\01g:2zo2:5)·------

**------~** 

# I uS/em 

## ··J



# ~ 1_: ; 

### I -

**~** 

# I



# :::~ **~** II



# 140~ 1 

# 120i I 

# 100i

I 80--\ II 

# l


# l ..-


# ~L~~J~::t:~t-. **~1~;-=** =Lh -=_,Lj

**=============================""===:::.::~======~============================** 

### External Standard Report 

### ==================""'==•"'======o:======================================== Sorted By Calib. Data Modified Signal 10/4/2010 1.0000 9:32:52 At1 

### Multiplier Dilution Use t1ultiplier & 

### 1.0000 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type 

### Area A."''lt/Area Amount Grp Name



### [min) [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.156 

### Chloride Totals : 0.00000
1 

### Warnings or 

### Errors Warning : Calibrated 

### compound ( s) no·t found

**=====================-======"""-'"''-~="'~~"'";=o:o===o:o==:::c·=========o:o=====""=""========o:o** 

### Area Percent 

### Report 

### a=::-::·=============== o:o= =="" ==

**==~="""::..c=** 

### '"==""' ==== 

### ::.============================= sorted By Calib. 

### Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs
IGG

**EP!i'Mft~§Si\§NfT@S~** 

### Pll<l'.f@f2

AUGUST A PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGJF!I§e376 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG98\023-2601.D Sample Name: Salisbury Rl Out B *100 0910-96 BORALBRICKS

**=~==========================================~===============~=~======** 

### Acq. Operator EO Seq. Line 26 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 5:00:41 AM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by

**I~G~G~~**

**~---:~,:~-l** 

### ADC1 A. ADtTCHANNELA(TJ:\HPLC2010Q4\MR BURNSIDATA\OCT(HPCC53PG98\023-2601 

# D)·--···--·----·---·-· 1801 160 

### 1 140 

# i 120-.:j 

### 100 

## _j 

# "' n ·c _g 

# "' '-'

**~** 

# \ I 

### ' '•

0 -



# -.--~--~---;-~c.---, 

# ,1\._1, !



# ~ **~----~--_) ·-~~---'1cQ_·_\"_'--**  ____

# ·_~--- -.



# -~=-~--1··r·2 ______::_dm-=.; 

# i '- t ·.,---""'·-- ·--,--,----,----··c·•••--, . 2 

### .1. 6 ________ 8
-

**=====~======~===================================================~====** 

### External Standard Report

**========================================================~============** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1. 0000 9:32:52 1\M Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: I\DC1 A, 

### ADCl CHI\NNEI, A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s} [ug/mL) 

## -------l------l----------l----------l----------l--1------------------ 4.152 

### BV 282.51471 2.64899e-2 7.48380 

### Chloride Totals : 

### 7.48380 =======·'""'=======""============""'""=======================-"'""'============== 

### *** End of Report 

### ***

Instrument:ATP 

## '1\W.Jfifr.!ct!<u P91

## PW: 28 1\M IGG



### EPAEit/H\~i1;ll;~ **f~p'iiM&c? 2**  

### AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGElli.<ij<l\77 1 of 1Sample Name: Salisbury Rl Out B *100 0910-96 BORAL BRICKS Acq. Operator EO Seq. Line 

### 26 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 5:17:59 AM Inj 2 

### Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M J,ast changed 10/4/2010 9:33:01 AM by IGG

**~-** .ADC1 A, AOC1 CHANNEL A (U:\HPLC2010Q4\MR

**BURNS\DATA\QCT\HPLC53PG98\Q23:2$Q2~0)** 

# I uS/em 

## -J I l j ! ' 180 -I

. 

# I 1 I 160

**~** 

# '

**140~** 120 

## -1 100

**-~** 80j 

## -1l ·c 0 

# "' (_) 

### ! 

## so 

# ;}, : i 

# A as



# ~ _,,/ \\ ;_: 40 20 ! \ t- :; ·....,...._____



## ,--~L **'--1~-** I -------



## -~-------------· **-~=-:=::;::=:;::::::::11** 0

**-+-~- ·--.-----..·~-·r··-**  

### .. ·

**-..---~~----,-----..,.~--.,-** 

### ..

**---~----~-** 1 · '------------·£_ ____________________

### __±__________ __,6,_______ 8 . _______ _1_Q________ 12 

# mid =========""=""===========================================::o==========--=== External Standard Report 

### ===================================================================== Sorted By Calib. Data Modified Signal 

### 10/4/2010 1.0000 9:32:52 AM Multiplier Dilution Use Multiplier 

### & 1. 0000 Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------1--l------------------ 4.154 BV 278.87683 2.64928e-2 7.38822 Chloride Totals : 

### 7.38822 

### =====·=======================================,.,=====================·=:;:;= *** End of Report 

### ***

Instrument 1 10/4/2010 9:35:37 AM IGG 

### EA#0910-96 Page51of202 Page 1 of 1 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT APPENDIX PAGE No. 378 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\021-240l.D Sample

**Name~** 

### Salisbury R2 Out B *10 0910-96 BORALBRlCKS 

## ===================================================================== Acq. Operator EO Seq. Line 24 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 3:51:29 AM Inj 1 Acq. Method

**C:\HPLC2010Q3\M~** 

### BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed : 10/4/2010 9:33:01 AM by IGG 

### ,---·····----·-

**ADC1A."Ai5CTC-~lAFiNEL** 

### A

**(U:"IH.;P_;.L_:;C.;c20i.1C:O,:;Q-..4~1Mi,R~B~UC,1R"N_;S;_:I;,:D:;,A"'TA"'I"O"'C"n"H"'P"L"'C"53"'P"'G"'9"'8"10"'2 1·"'24""0"'1".D"')---**  uS/em

180 160 . 140· 120 100- 80. 60. 40 20-



## ~ **~** a; N . f"5 ..,; 

# I 

# /

**~-** 

### i

**-'-~~ ~=~**  **-~** 

# L

**------~---- L-==~-·-·_·**  _-_---.....:4c.··_____ __,_6,______ _,s____ _

**=.,.~·==~==============,====================================,==============** 

### External Standard Report

**================================================================~====** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 Use Multiplier & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area

**F~t/Area** 

### Amount 

### Grp Name

(min] 

### [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 4.156 Chloride Totals : 0.00000
1 

### Warnings or Errors Warning : Calib.rated compound(s} 

### not found

= :=

**=~** :::.= . .,.- .== ======= === = = =

**======:::o:==-::'oo~.::.== "~""===·'"-===========================** 

**====================="'-'=======""~==============================="-'=======** 

### Area Percent Report ===="="-''=>0:>================================================""'==--'===""'====== 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 

### Use Multiplier

**~** 

### Dilution Factor with ISTDs
Instrument



### AfC:fWAJj'~j5 

## :1'\9 

## '9-! !\'IJI?32 AM I GG



### EP~ft!R~I§llJ@Nf1m **~~<'/J~** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGp~e379** 1 of 21../d.l.ct l'..L..Le u; \.tH'Lt....LU.l.UI.,J':I\lvl.K
**~UKNCI\Uf\Tf\\UCT\HC'.LC!Jjt'G;l!j\U~l-L40L.0** 

### Sample Name: Salisbury R2 Out B *10 0910-96 BORAL BRICKS =======================================================""'-============= 

### Acq. Operator EO Seq. Line 24 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 4:08:47 AM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method t): \HPLC2010Q3\MR BORNS\METHODS\HPLC53PG98CL.M Last changed : 10/4/2010 9:33:01 AM by IGG ---------,.-DC1 

### 7( ADC-1 CHANNEL A (U \HPLC201004\MRBURNSi'eoi=.A""TA 00

I"'O"'c"n"H"P"L"C'"'5:iPG98\621-2402D)-- uS/em 

# l

180 

# "1 160 

# ·-j 140---1 120J 100j



### ~ 80- 60 40- 20·

0 

## ~
**~** N (f) _______. __ r·---' -----,- C!>



# ~

I 

# I

N



## ~ 

# J o; "' -.:= a:)



## . **···---~-~-----:...~=:::::..:**

## __ **·~-'-="-'-;::·:::- ::::;:=::;:::~:;:**  

### - ' I ' -- -··.---,-------,-----·r-------'<""



## __;c__ -- --- -- 4 6 . 8 ___ 1Q______________:!_? _____ mi

**=~=~==========================================~======================** 

### External Standard Report ====='""""-'==============================,=========================""=""-"== 

### Sorted By Calib. Data Modified Multiplier DiluU.on 

### Signal 10/4/2010 9:32:52 AM l. 0000 

### 1. 0000 

### Use Multiplier & 

### Dilution Factor with 

### ISTDs Signal 1: ADCl A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] (uS/cm*s] (ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.156 

### Chloride Totals : 0.00000 

### 1 

### Warnings or Errors Warning ; Calibrated compound(s) not found

**======================================================~=========~~===**
**================~.,=========="==~==============::.~""-========================** 

### Area Percent Report

**::.~====================o-.;:::::=============""'"""========'='===:=:.===========::::=======** 

### Sorted By Calib. Data Modified 

### Multiplier Dilution Signal 10/4/2010 1. 0000 1.0000 

### 9:32:52 AM Use Multiplier & 

### Dilution Factor with ISTDs 

### '-_,_ot.AL?_a,o

**~** 

### , •. _, 4 EA#0910-96 Page53of202 Instrument Al C""PRO"JECl "NO. P-iU1"4'z- AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAG!':'N"l#380 1 

### of 2

### Data File U:\HPLC2010Q4\MR BORNS\DATA\OCT\HPLC53PG98\022-2501.D Sample Name: Salisbury R3 Out B *10 0910-96 BORALBRICKS 

## ========================================.,'""=========================== Acq. Operator EO Seq. Line 25 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 4:26:05 AM Inj 1 Acq. Method C: \HPLC20l0Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed : 10/4/2010 9:33:01 AM by 

### IGG uS/em 

### lADC1 A. ADC1-CHANt:fEL A (U:\HPLC201DQ4\MR



### BURNS\DATA\OCT\HPLC53~ .. 

### G9~t2·2SOiJlf·--···-···---··---·--~ 180. ' 

## q i ; I ; 

### 160
. ' 

# i I 140. 

# l 120 100



## ===================================================================== External Standard Report 

## ====================================<================================= Sorted By Calib. Data Modified Multiplier 

### Dilution Signal 10/4/2010 1.0000 1.0000 9:32:52 Al4 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal l: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[mic.J [uS/crn*s) [ug/mL] 

## -------j------!----------l----------l----------1--l------------------ 4.236 

### BB 89.76620 2.69549e-2 2.41964 Chloride 

### Totals : 2.41964 

### *** End of Report

InstrumentAllC II'El04!l®lli1J F'l10J§2 06 AM IGG



## EPifC~ **~~1Bs?8N~g~jl**
**~~o J&Cf**  AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAG!PilJgeJ81 1 of 1,--------- 

# .. - , .... 

### ------

**,~** 

# ..... , .........

**~** 

### ,

## ............ .._ ..... __ 

# .. .._._...._, 

### ,,_,._" 

### Sample Name: Salisbury R3 Out B *10 0910-96 BORAL BRICKS

**================================~===============~================~===** 

### Acq. Operator EO Seq. Line 25 Acq, Instrument Mr Burns Location 

### Injection Date 10/2/2010 4:43:22 AM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/l/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG ADC1 A. ADC1 CHANNEL A (U:IHPLC201 004\MR BURNSIDATAIOCnHPLC53PG981022·2502.D)



### ' 

## "'

**~**
**~ ~**  tO

**~** F.!: 'V 

### o;: N (") i\ ..j.

--- **,.......-.-J--~..,.U..--'---+--** 4 6 

# 1

8! <ci


# -- .----------- 

### ..... ':::-=- 8 10

**================;'::;=======o:::=="-•======================::====,======"~"'·======c**


### Sorted By Calib. Data Modified Multiplier Dilution External Standard Report Signal 

### 10/4/2010 9:32:52 AM 1.0000 l. 

### 0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl 

### A, ADCl CHANNEL 

### A RetTime Type Area Arnt/Area Amount Grp Name

[min] 

### [uS/em's] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.238 BB 

### 87.67069 2.69712e-2 2.36459 Chloride Totals : 

### 2.36459

**==================="'o'==="-"=~~=======:=::-==========o::==========;o;;;::o=::-::=========** 

### *** End of Report ->·*->-·



### Instrument 1 10/4/2010 9:35:19 AM IGG EA#0910-96 

### Page55of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

### Page 1 

### of 1 APPENDIX PAGE No. 362

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\026-330l.D Sample Name: P4 R1 In A *10 0910-96 BORAL BRICKS

**===========~=======================================~=================** Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/2/2010 8:23:39 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U: \HPLC2010Q3\MR BURNS\METHODS\HPI,C53PG98 .M 10/4/2010 9:36:41 AM by IGG 33 1
(modified after loading)



### ~---_""A"o"c"1"A'.'A"DC""'1'C"H'i:A<'iNi,NJiE~L::.,A<-;(U:iH'PLC2010Q4\MR BURNSiOATA\OCTIHPLC53PG98\026·3301.D) ---·- ·-·---, j uS/em 

# j I l 180 _J ! -! I 1 1601 

# i i -i ! 

# i 140

**-~** 

# i 120 

# i 

# I 

# 1:: 

# J



# ~ 1

**~** I J 

### N 0 

### I 0 ;:;t; '\



## ~

**~**

**~** f 

### 1 40 o-; f 

# --2 o



# ~r=>-_-~-__g,.--~-· **.;.•-_-_·""~·-l'-~** __ ,._-:,,_.:!....:,.



# ,---~·- __ 

# .:_--=·=6



# =~;~~-~=_£_~ **----~._c.-:-_:..-~_f_··.---~--~-~-~~-~-~~---,'·o-~~---;'2** .

# J

Sorted By Calib. Data Modified 

### Multiplier Dilution External Standard Report 

### Signal 10/4/2010 9:36:41 AM 1. 

### 0000 1. 

### 0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type 

### Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] {ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.121 BB 225.06882 l.70529e-2 3.83808 Fluoride 4.261 BV 5.95215 3.6552le-2 2.17564e-l Chloride Totals : 

### 4.05564 

## *** End of Report 

### ***



### Instrument



## A'tC~Ee~M>. i£.1Mil245 

### AB IGG



## EP~~ **~!j}lg;;IIBN~1l§~ ~~c?M¥l**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0 APPENDIX PAG1i'lllqe383 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\026-3302.D Sample Name: P4 Rl In A *10 0910-96 BORAL BRICKS Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Ana_J.ysis Method 

### Last changed EO 

### Seq. Line Mr Burns Location 

### 10/2/2010 8:35:58 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by 

### IGG (modified after loading) 

### 33 2

ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\026-3302.D) uS/em

180- 160 140 120- 100 80- 

# I**~** 

# "' /\**~ ~** **~** N j '· ..j.**~**

### ···----~---· --- l_j/ __

### \....__~ 

### ---.--_j- 10 .---------'

### ~ 0 ' ' 60- 40**~** 20 <0 N I 

# I

r----------· L

___________________ __

### g____ __ _ _ _____________± __________________ _§__
___________..§_________ _._1o'-------"12.,___'"m"'i
External Standard Report 

### Sorted By Calib. Data Modified Signal 

### 10/4/2010 1. 

### 0000 9:36:48 AM Multiplier Dilution 

### Use t-1ultiplier 

### & 

### 1.0000 Dilution Factor with ISTDs 

### Signal l: 

### ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] 

### [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.121 BB 226.27061 1.70532e-2 3.85863 Fluoride 4.261 BV 5.67176 3.70602e-2 2.10197e-1 Chloride Totals : 

### 4.06882 

### *** End of Report 

### *****'Wl.'--1.~,,** 

## g -"' "·" 5 8 EA# 0910-96 Page 57 of 202**InstrumentATcfl<ill~tYN** .

### t"-ltn'4~ 

### AH IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAG~** 'l-/i!!'384 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\029-360l.D Sample Name: P4 R2 In A *10 0910-96 BORAL BRICKS

**=================================~===================================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed EO 

### Seq. Line 

### Mr Burns Location 10/2/2010 9:37:38 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM 

### by IGG 

### (modified after loading) 36 

### 1

·------.A5c1A,.AocTCHANNEL A (U:IHPLCiO-fOQ4\MR BURNSiDATA\OCT\HPLC53PG981029-3601.0)

**============================~=======~===================~============** 

### Sorted By 

### Calib. Data Modified Multiplier 

### Dilution ExLernal Standard Report 

### Signal 10/4/2010 1. 0000 1.0000 9:36:48 AM 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area

**P~t/Area** 

### Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------[----------l----------l--!------------------ 3.137 BB 685.05603 1.70822e-2 11.70224 Fluoride 4.263 BB 36.18887 2.79640e-2 1.01198 Chloride 

### Totals : 12.71423

**========='-""'==·-~==''"~~==============================================;:;:=====** 

### *** End of Report 

### ***

'-"-'·""" 111

**~'** 

### 7 EA# 0910-96 Page 58 of 202 Instrument MC.....VJt:b1JNO. j9.jtf1 

### 7 423 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

### s. SALISBURY PLANT 6 SEPTEMBER 2010 ------1 I



### APPENDIX

**PAG~'Ni\!'385** 

### 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\029-3602.D Sample Name: P4 R2 In A *10 0910-96 BORALBRICKS 

## ==============""==================,=======,===""======================= Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method 

### Last changed 

### EO Seq. Line Mr Burns Location 

### 10/2/2010 9:49:58 

### AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM 0:\HPLC2010Q3\MR BORNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AH by 

### IGG 36 2
{modified after loading) 

# r·····--···-AocTJCAbc1TH-ANNEL A



### (U:IHPLC20;i=1"0,_;Q~4Ci1MiR~BUC'RiiNrcs"'I"D **A""TA"'I"O"C'"T\"H"P"L""c"'s'"3P"'G"'9"'8"'10"2"'9-'3"'60"2'.~o)c--------,** 

# ' uS/em 

# 1 180 -] j 

### 160 140 120 100
. 

### 80 . 60- 40 20
====================================================================:::; 

### External Standard Report 

## ===================================================================== Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:36:48 AM 1.0000 1.0000 Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type 

### Area Amt/Area Amount Grp Name



### [mi.n] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.137 BB 686.89960 1.70822e-2 11.73376 Fluoride 4.261 BB 35.98354 2.79736e-2 1.00659 Chloride Totals : 

### 12.74035 =================o=:·=================,.============""'="'-================== 

### *** End of Report 

### ***



### Instrument



### A-[Cflf)J-1~\il.i 

## J'&·

**f9-~~1f?** 4 5 AM IGG



### EP,i;'MF1~§11/6Nftl!S~ **P~O>JE(W** AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG\>~Ije386** 

### 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\030-3701.D Sample Name: P4 R3 In A *10 0910-96 BORAL BRICKS 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis**Me~hod** 

### Last changed 

### EO Seq. Line 

### Mr Burns Location 

### 10/2/2010 10:02:17 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by 

### IGG (modified after loading) 

### 37 1**~-····-···-·······Ao{TI\:"I\5c1·CHANNEL**

### A(U:iRPLC20ib041MRBURNS\DATAIOCTIHPlC53PG98\o:lo-370TD-J
- -·· ·-·· 

# I**us::~** I

1

# 160~ 1 

# I 140

# ~ I I 120

# ~ 

# 1 I 

# I 100

# ~ u:: 

# I I 1

### ~ I 

## ao-i ·-· 1**~** M Q) 

### I**~** 

### i\ "g 

### I

# ::l~ N 

# n**~ ~** **~~** 1 1 20**~** I \**~ ~**  j l N I \ '<t U'l I 1 

# L_ o - ---

# ~--**,----:-~~=~.-----~~**

# __ -**~;~----** 

# __

# r __**~ -~~** 

# _ T---**-,-=--~-~--,-~~J =======~========================~================~~==~===========~~==**  

### External Standard Report**===================·""'=~.,===='-"=='""================"''==,=-="'"""================** 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:36:48 AM l. 

### 0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [mln] [uS/em's] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.135 BB 641.72162 1.70812e-2 10.96138 Fluoride 4.261 BB 28.69785 2.84053e-2 8.15170e-l Chloride Totals : 

### 11.77655 

### *** End of Report 

### ***



### Instrument AJC]ft!'fll!J"fili'IJ> §·:1§1r':254 AM IGG

### EP~/S5l\IJ'im<r~IJ~J?8f AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAGji~387** 

### 1 of 1

### Sample Name: P4 R3 In A *10 0910-96 Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed 

### Analysis Metho.d 

### Last chailgect BORAL BRICKS 

### EO Seq. Line 

### Mr Burns Location 10/2/2010 10:14:37 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM 

### by IGG (modified after loading) 

### 37 2

**~---·** ADC1 A, 

### ADC1 CHANNEL A

**(U:\HPLC2010Q4\MRBURNS\DATA\0CT\HPLC53PG9-8\030~3fo~i0)~----·~----** uS/em 

# l

180- 160. 140 120

**===========~==============================================~====~=====** 

### External Standard Report

**="'"·========,.,=========~-~=,==""==,========================================** 

### Sorted By Calib. Data Hodified 

### Multiplier Dilution 

### Signal 10/4/2010 1. 

### 0000 1.0000 9:36:48 AM Use l..IJultiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTi.me Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------i----------i----------l----------1--l------------------ 3.135 BB 640.17627 1.70812e-2 10.93496 Fluoride 4.261 BB 28.99791 2.83832e-2 8.23054e-1 Chloride Totals : 11.75801 

### """"""''"'====-==:::=====""===::o·=::e:=============================;"===========o.-:.:=:o--=== *** End of Report 

## ***

lnstrument 1 10/4/2010 9:38:02 AM IGG 

### EA#0910-96 Page61 of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

### Page 1 of 1 APPENDIX PAGE No. 388

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\031-3801.D Sample Name: P4 R1 Out A *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed 

### Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 

### 10/2/2010 10:26:57 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by 

### IGG 38 1


### (modified after loading)

**~---~A~o~c~1~A-.**

### ""'A"'o"c"1"c;.H;;A:;:N.;N;;E:;L:.;A:.:;(u:IHPLc2oToa4\M"R suRNSIDAtlllocnHPCcs3PG9slo31-3ao1.DJ________ ---------- -- uSJcm l



### 180 

## j -1 

## 1 160 ·j .1 140--! 

### 120 l_1 

### 100 

## J 80 60 __ - 40- 

# I I



# __ j

**~-,---r·---~-r-··--.··---~------,--** 8 ____________!_0 ____________________11.____mi 

### =======================""===========================================-=== External Standard Report
**====:;;:==:===========~,==,============,==============""'========='"'"·=""'=======** 

### Sorted 

### By Calib. Data Modified Signal 

### 10/4/2010 1.0000 9:36:48 

### AM Multiplier Dilution Use Multiplier & 

### 1.0000 Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] 

### [uS/cm*s] [ug/rnL] 

## -------l------l----------l----------l----------l--1------------------ 3.118 BB 29.37646 1.67627e-2 4.92430e-1 Fluoride 4.259 BB 10.03031 3.23729e-2 3.24710e-1 Chloride Totals ; 

### 8.17140e-l ========""'='""'·--==,=================================================:====="" 

### *** End of Report 

### ***

IGG EP,Ii;II!IM.!Mi!lSl6Nfl1i§<f

**~i!<llUE200**



### AUGUSTA PLANTS 4 & 5, 

### SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~£18e389** 

### 1 of 1

### Sample Name: P4 Rl Out A *10 

### 0910-96 Acq. 

### Operator Acq. 

### Instrument Injection Date 

### Acq. Hethod Last changed }:\nalysis Method Last changed 

### BORAL BRICKS EO 

### Seq. Line Mr Burns Location 

### 10/2/2010 10:39:16 AH Inj C:\HPLC2010Q3\HR BURNS\HETHODS\HETROHH.H 4/1/2010 4:15:36 PH U:\HPLC2010Q3\MR BURNS\l-iETHODS\HPLC53PG98.!-i 10/4/2010 9:36:41 Al-i by 

### IGG (modified after loading} 

### 38 2 

# I S:::

# j ADC1 A. ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCf\HPLC53PijG98\031-3802.D)
160 

# l
. < I j 140 

## -i \

. 1 : 

# :::l I
l 

# i 

# ::j

**~**
**~** 

# I

N

**~**

**~** 

# L 2 : 

# .k::



# ~. 

# •-::"3 3

- 0



# -~ ,;'; T •



# -~ --T
- I - -c 

# =:--'-'- 1



# ~-,-~--~-r-----.------~

_ _______1._________________________ 4 6 ___________ B _____________ 10 12 mi 

## ============================..,==========,============================= External Standard 

### Report

**==========================~==============~===========================** 

### Sorted 

### By Calib. Data Modified 

### t-1ultiplier Dilution Signal 

### 10/4/2010 9:36:48 AM l. 

### 0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal l: 

### ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area 

### Amount Grp Name

[min] [uS/cm*s) [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.117 BB 29.06601 1.67592e-2 4.87122e-1 Fluoride 4.258 BB 10.10172 3.23298e-2 3.26587e-1 Chloride Totals : 

### 8.13709e-1 

### *** End of Report 

### ***

1 1 

## o/4/2 

### 01 

## o g 3 

## s EA# 0910-96 Page 63 of 202 Instrument ATCPROJECTNo.



### P-ioP4~ **1** 

### AH IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### APPENDIX PAGE'm8 

### 390 1 of 1

### Sample Name: P4 R2 Out A *10 0910-96 BORAL BRICKS

**============~=============~=~====================================~===** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed EO Seq. Line 

### Mr Burns Location 10/2/2010 10:51:37 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM 

### by IGG 

### {modified after loading) 39 1

,-- ----- -iili"cf :;;:·A-15cTcHANNEL A (U:\HPLC201004\MR BURNSIDAT

**AiOCTIHPLCS3PG981532~39DT6)**_____



### I 

### L 

# u~::l 160- 140 

### _j 

## ' 120.:! ; 

## ., 100

# j 80 

## ·j



## 60~

6 8 

## ======,.=========================:::==""'""=================""============== External Standard Report
**==================================~==================================** 

### Sorted By Calib. Data Modified Multiplier Dilution 

### Signal 10/4/2010 9:36:48 AM 

### 1.0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTirne Type Area Amt/Area Amount Grp Name

[min] fuS/cm*s] [ug/mL] 

# -------r------r----------l----------r----------r--r------------------ 3.119 BB 36.11133 l.682SOe-2 6.07572e-1 Fluoride 4.260 BB 12.06006 3.13464e-2 3.78039e-1 Chloride 

### Totals : 9.8561le-l

**===""====='"-'""''-~~:.;:c,__-=,======::::==========:.=:~==::::.oo'~"'======================:::o=,;:::..~=:coo** 

### *** End of Report 

### ***

'- 1"'-'d

**.~.,.**

### ..

# ,.,.o " -,.o _? 

### 6 EA# 091 0·96 Page 64 of 202 Instrument A"C 1"1<' Jtet-'1'Ntl.



### ~-1,r.fz- AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 **APPENDIXPA~391** 

### 1 of 1

### Data File U:\HPLC2010Q4\MR BORNS\DATA\OCT\HPLC53PG98\032-3902.D Sample Name: P4 R2 Out A *10 0910-96 BORALBRICKS Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed 

### EO 

### Seq. Line Mr Burns Location 10/2/2010 11:03:56 AM 

### Inj C:\HPLC2010Q3\MR 8URNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR 8URNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 

### AM by IGG (modified after loading) 

### 39 2**~--:~:: --AocOC**  

### ADCi CHANNEL A (U:\HPLC2010Q4\MR**BURNSIDATAIOCiiHPLC53~G98\o3·z:3-9b2.o)-----------~** 

### i - l 1 

### 160- 1 

# ::: l I

# ~ I 

### 1oo 

### -:1 

## I j ' oo, 

# I

# 60~**~ ~**  ! 4

# oi**~** tl ! 

# di**~** (0**~** 0 0) ! 2Ql 

## K! ';**~ ~**  1 

# I ___ 0 

# .t··;<:'c:;=. c5?.: ---:.,. ,.

# ~-~------------~-**i----~c_--:;** =-'

# c-;'Q~-:__-_=-··-1y~-;;;;-

Sorted By Calib. Data Modified 

### Multiplier Dilution External Standard Report 

### Signal 10/4/2010 9:36:48 AM 1.0000 l. 

### 0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal l: ADCl A, ADC1 CHANNEL A 

### RetTime**Ty~e** 

### Area kmt/Area Amount Grp Name

[min) [uS/cm*s) [ug/mL)**-------:------~----------l----------r----------l--l------------------**



### 3.120 88 36.00581 1.68242e-2 6.0576Be-l Fluoride 4.260 BB 12.07534 3.13399e-2 3.78440e-l Chloride Totals : 9. 84209e-l 

### *** End of Report 

### ***

Instrument

### A}Cf~,P,f~~lii'tl f9-!(\1gl?34 AM IGG

### EP~ifllA\!lffii§Nlffi!'f**Pr'i6'J~** AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAGp~e392** 

### 1 of l

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\033-4001.D Sample Name: P4 R3 Out A *10 0910-96 BORALBRICKS Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method 

### Last changed 

### EO Seq. Line Mr Burns Location 

### 10/2/2010 11:16:16 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by IGG (modified after loading) 

### 40 1

**~----** ADC1 A ADC1 CHANNEL A (U IHPLC2010Q41MR BURNSIDATAIOCT\HPLC53PG98\033·4001Ti) -----· ----- 

### 1 

# "'::j I 

# :::-1 !



# 120~ ! 100 -j 

# ! 

# 1 80 

## "i 60 

## i 

# 1 40 

## -i 

# 1 :0 m o 

# l 20l___**J_~.---.J~~,~**

**~ ~**  **~** " _ _.___• ____ ) 

## ! 0 

### +- ·

**--,-----1-~~---,----.--** - r .......,. -. -

**-.------~~-,--- ...----.---~--.,--~**  

### ------ - ______1 ____________..,1 _________ 8 ______ ---

**-~----·---·** -- __!.Q__ ___ **~-** - ___ _1?..__/!!L
External Standard Report 

## '='=-=-===================================================;:::.==""=========== Sorted By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1.0000 9:36:48 AM Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1, ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

# -------l------l----------l----------l----------l--l------------------ 3.117 BB 40.65833 1.68553e-2 6.85310e-1 Fluoride 4.259 BB 12.36708 3.12204e-2 3.86105e-1 Chloride Totals : 

### 1.07142 

### ==,==========================e========================================= 

## *** End of Report 

### ***



### InstrumentAICf'{Rp!I~Qlll-JO.i!)1QlliJ<'42 AN IGG



### EP~~l~ii/BN~\l'f **~~8J~** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI!>!II<je393 

### 1 of 

### 1

### Sample Name: P4 R3 Out A *10 0910-96 BORAL BRICKS

**===~=================================================================** 

### Acq. Operator Acq. Instrument 

### Injection Date Acq. Method Last changed Analysis Method Last changed EO 

### Seq. Line 

### Mr Burns Location 10/2/2010 11:28:36 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\HETHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by 

### IGG (modified after loading) 40 2

**~--·····** ... ADCTA. ADC1CHANNEL A(U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\o334002.D) 

# I uS/em 

### ·i



## 180~ 1 160



### ~ 

# ' 140



## ~ i 120 _j 

# i 100. 80 60 40 _- 

# "' "'

**~** 

# , 0

**~** E 

## a: () If)



# ~ .: 

## j' 200



# J.=--='.-~-='--1'==.:.-t=:...··:'

**.::~:.·**·:..·2';=:::;:::=::;=::::;====·---- . ' • ' I '
- •·•, ..... **T·-,--~--,-----~--r---1** '------'2'-- _________ _j_____________ 6 8 ___

### 1_9 __________**~1?.-** mi

**====================~=================="""·==============""'========o=======** 

### External Standard Report

**=~=======================================================~===========** 

### Sorted 

### By Cnlib. Data Modified Multiplier Dilution Signal 10/4/2010 

### 1.0000 1.0000 9:36:48 AM 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal l: 

### ADCl A,

**.~DCl** 

### CHANNEL A Ret'rirne Type Area Arnt/Area Amcunt Grp Name

[min] {uS/cm*s] {ug/rnL] 

## -------l------:----------l----------l·---------1--l------------------ 3.119 BB 40.55775 1.68547e-2 6.83590e-1 Fluoride 4.261 EB 12.31650 3.12407e-2 3.84776e-l Chloride Totals : 1.06837

**===========o=============='='·===============•:o======================~====** 

### *** End of Report 

### ***

Instrument 1 10/4/2010 9:38:52 AM 1GG EA#0910-96 Page67of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### Paqe 1 of 

### 1 APPENDIX PAGE N"o. 394

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\034-430l.D Sample Name: P4 Rl In B '10 0910-96 BORALBRICKS Acq. Operator EO Seq. Line 43 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 12:29:43 PM Inj 1 Acq. Method C:\HPLCZ010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METH0DS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM 

### by IGG**r-·-····--·~-----** ADC1 A, ADC1 CHA-NNEL".A:'(tJ:\HPLC20f0Q4\MffBuf.R'»N:«S;;,\D"A"T"-A"ID"c"n""H"'P;cLC"'s"'3"P"'G"'9'"8\"'0"'34 7 -4301.D) 

# I I uS/em 

# 1 i!; ' 180-j 

# 'f 160 

# 1 I 140

# ~ 

# I

External Standard Report 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:32:52 AM 1. 

### 0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Arnt/Area Amount Grp Name



### [min] [uS/em's] [ug/mLJ 

## -------j------l----------j----------l----------l--l------------------ 4.234 BV 4.51100 3.78526e-2 1.70753e-l Chloride Totals : 

### 1.70753e-l**================·""""==~=-================="'"==================,=~-""""'""=========** 

### *** End of Report 

### ***

ATC PROJECT No. P-10142 Instrument 1 10/4/2010 9:39:49**fu~** 

### I**EP!B(t!'l8GI1$1l!Nil'l!l!)ll~** 

### X8GUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 395 

### Page 1 of 1

### ua1:a

**t~.Le** 

### u: \I11:'LCLU.iUU.q\MK **tsU.KN::,\Uf\TA\UCT\H.r'LC~.:ll:'l:i!:lti\U.:Sll-ll.:lUL.U** 

### Sample Name: P4 Rl In B *10 0910-96 BORAL BRICKS 

### ============================<==============-===============;::=========== Acq. Operator EO Seq. Line 43 

### Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 12:47:01 PM Inj 2 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M .Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 l\1-1 by 

### IGG 

# r .. ADC1 A. ADCi CHANNEL A (U:IHPLC2010Q4\Mil"8URNSIDATA\6cYiHPLC53P.G981034-4302.D) em 

## -1 j 

## 13 

# . ' 

# "' MJ i

**~**

**~** 

### i 

## !

**60~** 

## ! i -j i 

### i 1 I ! 

# I 140 

### :j I i 1



### ~ I 1 1 120 J 1 : 

## I i , , 

# I 100i ' 

# ! 80-:j i

# I

.. _..:_ 

# \"' 10 

### ========================================='-"==============::":============ External Standard Report
**='=============================================~~==============~======** 

### Sorted By Calib. Data Modified Multiplier Si.gnal 

### 10/4/2010 9:32:52 AM 1. 

### 0000 Dilution 1.0000 Use Hultiplier & Dilution Factor with !STDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area Arnt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------i----------l----------l--1------------------ 4.156 Chloride Totals : 

### 0.00000 1 Warnings or E.rrors Warning : Calibrated compound(s) not found 

### ========================;==""'=-=,::==========-,=========================""==

**============""=:=:=================="-""'============;=:======·-"==============~·** 

### Area Percent Report
**========================================~=====================~======** 

### Sorted By Calib. Data Modified Multiplier Signal 

### 10/4/2010 9:32:52 

### AM 1.0000 Dilution 1.0000 Use Multiplier & Dilution Factor with ISTDs
EA# 0910-96 Page 69 of 202 

### Instrument 1 10/4/2010 9:39:57 AM IGG ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 T 12 

# i 'I 

## II 

# ! i 

# ii

. !

### Data File U: \HPI.,C2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\035-4401.D Sample Name: P4 R2 In B *10 0910-96 BORAL BRICKS

**================================================~====================** 

### Acq. Operator EO Seq. Line 44 Acq. Instrument lVJr Burns Location 

### Injection Date 10/2/2010 1:04:23 PM Inj 1 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\MET'ROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG uS/em 

## l AOC1 A, ADC1 

## CHANNECiiW~RPLc2010Q4\iofR""'B'"u"R"N"s\D~A"TCA\"O"c"'T'"IH"P"'L"'c"'s=apl**<39~35-4401** .D)·--··· ..

# ······-··-·1
1801



# ~ 1601 

# I

I_ I' 140--1 \ 1 

# 1 ! ! 120



# ~ 

# I 1 , 

# 1:: l_ 

# I I '



# w~ 1 

# 201

**~ ~**  **~**

**~** J \ 

### j 

# a-t=-·-'·



# N~-=.:' 

# ·

**~:-==r:_~_:_.c=;::**

# .._ !


# ~-=;---==-r~~_:::_,-__-=;=__

# r==;=d L_

____ -<.2________ 4___ .. _______ 6 ______,__ 

### a 10 .........

# _11.._...!!l!tl =========================================''"========================"="""'"" 

### External Standard Report 

## ===================================================================== Sorted By Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4//010 9:32,52 AM 1.0000 l. 

### 0000 Use Multiplier & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/rnL] 

## -------j------j----------l----------l----------l--l------------------ 4.156 Chloride Totals : 0.00000 1 Warnings or Errors lr'Jarning : Calibrated compound(s) not found

**=·======.o::=::"="""'"~"'"-:::=============='-"'======================,================="":~::: =================::.~""'"""'====================================='"'=====.;=======**  

### Area Percent Report
**============================,...==·~..;=============:..::o.·===============,.,==""====** 

### Sorted 

### By Calib. Data Modified Multiplier Signal 10/4/2010 9:32:52 

### AM 1.0000 

### Dilution 1.0000 Use Mul tipl:Ler & 

### Dilution Factor with ISTDs


### EA# 0910-96 Page 

### 70 of 

### 202 IGG EPA ICR EMISSION TEST PROJECT

AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PA~il-@397** 1 

### of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\035-4402.D Sample Name: P4 R2 In B *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 44 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 1:21:41

**P~J** 

### Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\IIFLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by 

### IGG ADC1 A. ADC1 CHANNEL A(U:IHPLC2010Q4\MR BURNSiDATA\i5ci'IHPLC53PG.S8\035'-4'4"0"2"D'-)-------,



## ===================================================================== External Standard Report 

## ===================================================================== Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 1.0000 1.0000 9:32:52 AM Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTirne Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mLJ 

## -------l------l----------l----------l----------l--1------------------ 4.156 Chloride Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound{s) 

### not found

**===-:-=~=:=o~===-================e:==~-,;:;;:===c""=========""="'===================== =============""'"========================================"'"-=~-"""'=========="""**  

### Area Percent Report ================================,.,===============================::==.=== 

### Sorted By

**Cal~b.** 

### Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs
Instrument



### AIC:f\W)!JJ'l<WN91l}l~1Jig14 AM IGG



### EPm~9s'I8N%\li- **P~8J~** AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~ill!le398** 

### 1 of 2Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\036-4501.D 

### Sample Name: P4 R3 In B *10 0910-96 BORAL BRICKS

**==========~================================~=========~===============** 

### Acq. Operator EO Seq. Line 45 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 1:38:59 PM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis t1ethod U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG ADC1 A. ADC1 CHANNEL A (U:\HPLC201004\MR BURNS\DATA\OCT\HPLC53PG98\036-4501.D) uS/em

180- 160
120· 100 80. 60- 40 N 

# "' N N 

### -'- ' 2 

# ~ I 

# I

i ! 

# I
4 6 8 10 

### External Standard Report 

## ===================================================================== Sorted By 

### Calib. Data Modified 

### Multiplier Dilution Signal 10/4/2010 1. 0000 1.0000 9:32:52 AM 

### Use Multiplier 

### & Dilution Factor with lSTDs Signal 1: ADCl A, ADCJ. CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[minJ [uS/cm"'"sJ fug/mL] 

## -------l------l----------1----------l----------l--l------------------ 4.156 

### Chloride Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound(sj not found

**===~==~=============================================~======~=========** 

### Area Percent Report

**============,.~=="~'-"====""·=============="""'"===========~.,===================** 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1. 0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs

Instrument AlfC:iAAOUJ'1jiNJ> 

### 9-j Glll22 3 !\_M IGG



## EP~~t'R **O~J&-~B~f~"r ~~8~~8f**  AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

## fl 

# 'I I' ,! 

# I' 11

**------~--L_** 12 mi

APPENDIX

**PAGE~399** 1 of 2Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\036-4502.D Sample Name: P4 R3 In B *10 0910-96 BORAL BRICKS

**==~======================================================-===========** 

### Acq. Operator EO Seq. Line 45 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 1:56:17 PM Inj 2 Acq. Method C:

**\HPLC2010Q3\!~R BURNS\METHODS\~1ETROHM.**  M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed : 10/4/2010 9:33:01 AM by IGG

---------- A6C1"A;·;..oc1ci=fiiNNEL A (U:\HPLczo1oa4\MR BURNs\oATAiocni-IPLcs3PG9aio36-4so2.1:l)-
---- -----



# uS/cm~-

180 160 140 

# -j 120

**-~** 100-1 

# I



# 80~ I 

# ::1
M 

# l

____ **;~~~~-~~~-~--i-** 6 

## ===================================================================== External Standard Report

**=========================================,.,.==:;:"~,:,:,""'======================** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 1_0000 1.0000 9:32:52 1\!1 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEl, A 

### RetTime Type Area Amt/Area Amount Grp Name

[min 

### J [us 

### I em* s] [ ug

### /mL J 

## -------l------l----------1----------[----------l--l------------------ 4.156 

### Chlor.ide Totals : 0.00000 1 

### Warnings or Errors Warning ; Calibrated compound(s) not found

**======================================""="·"""""""===================""~====**
**="'~·="'"""""'=""~==="-""=·~~=::.o::o-::=====================-,:==='-==='""""';;:,=====================** 

### Area Percent Report ==================c-.,::.o======:..--o======================================:oo=== 

### Sorted By 

### Calib. Data Modified Ivlultiplier Dilution Signal 10/4/2010 9:32:52 AM l. 0000 l. 0000 

### Use Multiplier & 

### Dilution Factor with ISTDs
Instrument AjTC1flRO!J,EM:Nl'-IJ"1q1J4i132 AM IGG



### EP~~Clrul$-§j\l,J'-fm't~85i?Bf AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGJ.i«<l'e400 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\037-460l.D Sample Name: P4 Rl Out B *10 0910-96 BORALBRICKS 

### Acq. Operator EO Seq. Line 46 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 2:13:36 PM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Ana1ysis.Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by 

### IGG

**~----··-··-·;o;;oc1A;-ii:o(:"TCHANNEL** 

### A (U.:IHPLC2CllOQ41MR

**iillRlJs\bilfl\locnHPLt:"i5":ii'G981037:46oi·~o)··----·-** ·--·1 

## i uS/cm·l 

# I 

# g I J • I 180·i Cl l 

### 160



# ~ I 

# I 140cj 

# i 1 J 

### I I 

# 1201 i I 1001 

# i
. 80-1 J 60 -l

**~** I



## 40~ I 

### 1 :'$

**~ ~** 

**~** 1 

## I 20

**-~** N 00 "<t 0 I I 

# I N ....j t,6 t- \ 

### , a

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# ..

# =-------.---=--r--.--- -

**~~-1=-=~-** ---1 

### L __________________1.___**~-----------•---~--------------§**

### _______**-~--------~-------------** 

### ____ 

### !Q_________ 12 mini 

### External Standard Report ==================--===·'-"===·==="'=======================================;,;;,; 

### Sorted 

### By Calib. Data Modified Mult.iplier Dilution Signal 10/4/2010 

### 9:32:52 AM 1.0000 1. 0000 

### Use Multiplier & Dilution Factor with ISTDs Sjgnal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Arnt/Area A..'tlount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------i----------l----------l----------l--1------------------ 4.156 Chloride Totals : 0.00000 1 

### Warnings or Errors Warning : Calibrated compound(s) not found

**============:=:==========="-'>==="--=""'""'~'·~="'=================================** ========""·"'"====================================================""====== 

### Area Per:·cent Report

**==============-==================="-"'~""=====..,======"-"=====================** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 

### Use Multiplier & Dilution Factor with ISTDs
Instrument AICfi\'P<fl'l'(itie· 

## '9-!\1\1?41 At1 

### IGG



### EP~~fls'lt§Nifi!\19' 

## ibft6'Jiil}12 AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGIP~e401** 

### 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\037-4602.D Sample Name: P4 Rl 

### Out B '10 0910-96 BORALBRICKS

**================~==~=================================================** 

### Acq. Operator EO Seq. Line 

### 46 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 2:30:53 PM Inj 2 

### Acq. Method C: \HPLC2010Q3\MR BORNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG 

# r --·-·-··

**·:i\bci·A~ADC1** CHANNEL i\(iTiRPLC201



### o·~oC.•i:,Mi;Ri-EisuifRi;-N;:is,;,,:;;D:;;A,.TA"l"'o"'c"'n"H"P"'L"c"s'3P'"G'"9'"a"'lo"3"'7-4602.l5j""'' ----· uSJcm 

### :l

**~** 

# . "' ! 180- 

# 1

**~-~** I I I. 16o 

# I 140 120 100-

External Standard Report

**=========================================================~===========** 

### Sorted By Calib. Data Modified 

### Multiplier Dilution Signal 

### 10/4/2010 9:32:52 AM LOOOO 

### 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

frnin) [uS/cm*sj [ug/mL] 

## -------l------l----------!----------1----------l--l------------------ 4.156 Chloride Totals : 

### 0.00000 1 Warnings 

### or Errors Warning : Calibrated compound(s} not found

**=========""=============::;:;:========================"'~""'"-'======-============**

**==~.,=========================:::=::-~=""==================="'--"'-'=="-===:::o::==,===:oo==** Area 

### Percent Report 

### ===================================================================== Sorted 

### By Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 9:32:52 AM 1. 

### 0000 1. 

### 0000 Use Multiplier & Dilution Factor with ISTDs



## InstrumentAICPil!M~rJlii-IO.I'}Hii1Si'49 AM IGG



## EP~~Qs'/tJNfW\!'f **~~8J~** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# i i 

# I I I I

APPENDIX

**PAG!f~e402** 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\038-470l.D Sample Name: P4 R2 Out B *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 47 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 2:48:12 PM Inj 1 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM. M 

### Last changed 4/1/2010 4:15:36 

### PM Analysis Method U:\HPLC20J.OQ3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed : 10/4/2010 9o33:01 AM by 

### IGG

**r·····:~;~:-~ADCi··;.,:·ABcrcHANNELA(U:\HPLC201iio4\MRBURNSIDAfA\ocniif'[c53~G9;63847oHi)"····--··········--~--~** 

### 1801 

# I 

# 1 I 160 

# ·l i I 1401 1 120



### ~ 

### j ' i 100



### -~ 

# i

**oo~** 

# I

**oo~** \



# ~LJ~~L .


# !)."'-~~) **.l~~~c_.** 

# .

**--·--·--·-··----------~--** 4 6 8 ___________ **,1.9~---------** 12 mi 

## ===================================================================== External Standard Report 

### =====================================================================· Sorted 

### By Calib. Data Modified l-lul 

### tiplier 

### Dilution Signal 10/4/2010 

### 1. 0000 

### 1. 0000 9:32;52 AM 

### Use !'-1ultj.plier & 

### Dilution 

### Factor with 

### ISTDs Signal 1 o ADC1 A, ADCl CHANNEL A RetTime Type 

### Area Amt/Area Amount 

### Grp Name

[min] 

### [uS/cm*s] [ug/mL] 

# -------l------l----------l----------l----------l--l------------------ 4.156 Chloride 

### Totals : 0.00000 1 

### Warnings 

### or Errors Warning : Calibrated compound ( 

### s l not found 

### "-'""""''==================================================================

**==============::::::===-:o:.'=-=:::,===~-========================-================"=====** 

### Area 

### Percent Report 

### =-·=:o"·""'================================================================= Sorted 

### By Signal Calib. Data Modified 10/4/2010 9:32:52 AN Multiplier 1.0000 Dilution 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs
Instrument



### AJ.TCl~fi§O:NJ>. **~~1~WQO** AM IGG



### EP~Ij\~,ClflJ~·~e;f,m- **~8~~** AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 

### APPENDIX

**PAGp~403** 

### 1 of 

### 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\038-4702.D Sample Name: P4 R2 Out B *10 0910-96 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 47 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 3:05:30 PM Inj 2 Acq. Method C: \!!PLC201 OQ3 \MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method

**U:\HPI~C2010Q3\MR** 

### BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG 

# f ADC1 A, ADC1 CHANNEL A (U:\HPLC2010041MR-BURNSIDATAiOCT\HPLC53PG98\038-4702.D) ----------- 1 uS/em 

# l

**~** 

# I 1801 

# i I 160

**-~** 

# ' J 140 

### -:l 120 

# -J 100



# ~ 1 i BOi I 

## ' i f


# ::o

0 

# 1i 

# eel•"--



# c:=~-~:··~,-~.**-~-.J~-------** _j



# --~:;:~~~:-:~:=;:-==;==;==;== J ' ' ' ' --r-------r-------..-·---.---·--r---,-----.,---;- - I ...,......---- L_ ____ **~2,__**_____ **_c4"------~6'-.** ____________...!!________________________ 10 ·-···

**------------~_2** _ ______m.i 

### External Standard Report 

### =========="''"'""==""=======-======================================-======== Sorted By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1.0000 9:32:52 AM Use Multiplier & 

### Dilution Factor with ISTDs Signal 1; ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount 

### Grp Name



### [min] [uS/em's] [ug/mL] 

# -------r------:----------r----------r----------r--r------------------ 4.156 Chloride Totals : 

### 0.00000 1 

### Warnings or Errors Warning : Calibrated co:mpound(s) not found 

### ===============""================================================"'""'===

**========~:===:-.:co::c==:c.:;====================================================** 

### Area Percent Report

**============================================================·======='=-~=** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:32:52 AM 1- 0000 1.0000 Use Multipli.er & 

### Dilution Factor with ISTDs
_1n/_40.010 q 

## jjJ 6 

### EA#0910-96 Page77of202 

### lnstrumen t A;-C"PRaJECTWo. P-i 142 1 

### AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~'!Sbe404 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\039-4801.D Sample Name: PI R3 Out B *10 0910-96 BORAL BRICKS
**~====================================================================** 

### Acq. Operator EO Seq. Line 48 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 3:22:48 PM Inj 

### 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by 

### IGG .ADC1 ,;;:·ADC1 CHANNEL A (U:\HPLC20 1 

### 004\MR BURNSID;:;A"'T 7 

### A"IO"c"n'"H"P'"L'C'"S"'3"'PG=sa"l.0"'3"9.-·4"B"'07 

### 1."D"l------;



## . I

**~** 

# l

**~** j i 160 

# I 

# i 

# ii
140 ) 

### j 

# li ' li 

# I! 120 100 ;I 

# ,, 80 

# II I 60 / 

# II
40
- J 

# ! 20-



# ~ **~** C»



# ~ 

# I \ i 

# l . -"'- c---"··.52_



## ~-~ .; 

## ~---~ ,_.: 

## r-::::::;:;:::;::::C:;·.~/ -- -- - 

## 'c~--~---·-····-·-·"J o- -·- 1 ------,------.-----T-· 1 -· .,.. -····'T" ,... ------r ••. .,. , -· c.,.. ---,--..........,---



### ------- 

### --~-------···----'•'-------"6'------"e_____ __,1"o'------'1"'2 _ __!!m""'i 

### External Standard Report **============================-====================-·=======~-:.==,=======-==::.==** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM l. 

### 0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------j------l----------j----------l----------l--1------------------ 4.156 

### Chloride Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound(s) not found

**======================~..:o==-====~=======""'0:'""'""'""==""=-""========-==:--==-:""'"'"====--===~o:.==-** 

### Area Percent Report 

### ====""'"'"'"o============================================================= Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 

### Use Multiplier & Dilution Factor with ISTDs



### InstrumentAICf~P~~\HitJe- '9-Hi"IJI?26 AM IGG 

### EPR~<i!IJ1g!l//3N~ **P~BJ~** AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG!'~e405** 

### 1 of 2Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\039-4802.D Sample Name: P4 R3 Out B *10 0910-96 BORAL BRICKS

**===================~===========================~=====================** 

### Acq. Operator EO Seq. Line 48 Acq. Instrument Mr_Burns Location Injection Date 10/2/2010 3:40:05 PM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 

### PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 

### AM by IGG uS/em 

# J

180 

# J ' 160 ..J



# 140~

**120~**

**100~**

80



# ~ 60 

# 1 ADC1 A. ADC1 CHANNEL A (U:IHPLC2010Q41MR BURNSIDATA\OCTIHPLC53PG98\039-4802.D) -----·-· 

# 1 I ,, il 

# II II 

# II 

# !I i il



# ::~ **~** ! 5



# ~ I \ ___

# j

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## i"-..
**--~-·--** r···--' -- 

### -~------__]------,----·-·· **~---;--....l--** 

## . **...-·---~-----** 

## __ .....-.J__ ../. .... •



### -~ **_'-.,_...,~---** ., I

**'------~2___** 

### _ ____ i_________________________ §_________________ .§_ _________________ ...

### .1.9 ________, ____ **~**

### _ _1!11_ 

### =================================-,==================================== External Standard Report
**===============================~=============:=======================** 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9;32:52 

### AM l. 0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 

### A, ADC1 CHANNEL 

### A 

### RetTirne Type Area Amt/Area Amount Grp Name

[ruin} 

### [uS/cm*s] [ug/mL] 

## -------;------l----------;----------[----------1--l------------------ 4.156 Chloride 

### Totals : 0.00000
1 

### Warnings or Errors \'Jarning : Calibrated cornpound{s) not found ===='"'='·::..-==============================================================
**=·======================='"'==~-:o·=='-""'"'=================~=:::===='""==:.=::-.::=======** 

### Area Percent Report ====;:::=====""==="'<;::':==='"'""-=====""'=============================:::==:========:::= 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 1. 0000 l. 0000 9:32:52 AM 

### Use Multiplier & 

### Dilution Factor with ISTDs



### InstrumencAICfflfW~Qjjtlg. l>tl'!!'til?37 AM IGG



### EPRit!l&'t/,gs'l§N~'f **P~O'J~** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGj;~e406** 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\040-490l.D Sample Name: P5 R1 In A *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method 

### Last changed**Ana~ysis** 

### Method Last changed 

### EO 

### Seq. Line 49 Mr Burns Location 

### 10/2/2010 3:57:55 PM Inj 1 C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:58:17 AM by 

### IGG (modified after loading) 

# r ·------------AoCfA.ADC 1-CHANNEl- A 

### (U:\H-P"LC201**o0~4;;.\M~R"'siiuf!R;';;N"S"'ID"'A"T"A'"IO"c"'T"I"H"'P.cLc"'5"3"'P"'G"'9'"al"'o"'•o'."'•9"0"1-co"')**

### ____ _**~** 

### I 1 uS/em -1 

### ' " I ! 

### 180-j ' 

## ! 1 ' I :J 

### j 

## r 1so --! · 

# I**140~** I 1203 ' j 

### . 1 

### 100**~ ~**  

## J "0

.

### ~ 80

## ~ u. 

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### ~ 

# sol**~ ~**  •ol '" '"' 

# I 2:

# ktd\\'=·l"-~-r':::_:::,:":~i.:...

# ,:c:.:::;:.:C:::;~---**·._c.-,--r'-=-r-1~~-~-~~-~---1** L
_____________ 2 __ ------------------4 6 ___________@___
______,___________ 10 

### External Standard Report 

## =============="""===::=:======================""'=============.,==========""== Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:58:17 AM 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--!------------------ 3.126 

### BB 362.59586 1.70694e-2 6.18931 Fluoride 4.262 BB 

### 5.50164 3.7393Be-2 2.05727e-l Chloride Totals : 6.39504


### *** End of Report ~** 



### Instrument:

### AfC:MOJIJ1'§~.N!I-19-J!\tJI?22 AM IGG

### EPJ\'~'MIJ,g§/@Nflm**~R6'Jiil9f** AUGUSTA PLANTS 4 & 5, 

### SALISBURY PLANT 6 SEPTEMBER 2010 12 ml



### APPENDIX**PAG['~e407** 

### 1 of 

### 1

### Data File U:\HPLC<UlUQ4\MR**BURNS\DATA\OCT\HPLCoJPG~e\U40-49U<.D** 

### Sample Name: P5 Rl In A *10 0910-96 BORAL BRICKS =================c-.:=======================================--========-""=== 

### Acq. Operator EO Seq. Line 49 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 4:10:15 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4!1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:39:38 AM by lGG



### ------------ ADC1-A-:-ADC1 Cl-IANNETA(U:\HPLC201 oo-4\MR BURNS\DATA,6Cl\HPLC53PG9Bm40:4902.D)
----- ------··-·--------



### uS/em 

# 1

180

### -~ 160 

## j 140J 

### 1 120 

# i**100~ ~** 

## 80~**~** 

# 60j**~** J

## ~**~ 40~**  M 

### u r::,":J 

# l (·· '**~.'2**

. N ;\**~ -~-**  CO**~** 20-:1 M I\ N 0<'b'**~** , . ..! N I\... 

## # It) r-.: 

### o**.:~~--~~:-~:_t;__:~~~~--,---:=-~:**

### ...,..**_:_::~r----,-__-::.**

### __**~=.-.=;:_~** -

### --=-.=-~-,----,----~-~----..-----.,----~----.,--**---~2** ------------ 4 ________ _§_____________**~-----------------·--_1Q**___________________j1
_______ rpj_


## =====================================================================
Sorted 

### By 

### calib. Data Modified Multiplier Dilution 

### External Standard Report 

### Signal 10/4/2010 9:36:48 AM 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Arnt/Area Amount Gr.p Name

[min] [uS/cm*s} [ug/rnLJ 

## -------l------l----------l----------l----------l--l------------------ 3.127 

### VB 365.51782 1.70697e-2 6.23926 Fluoride 4.262**~"~** 

### 5.41333 3.75752e-2 2.03407e-l Chloride Totals : 

### 6.44267


### *** End of Report 

### ***

IGG EA# 0910-96 Page 81 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGif\i!\!e408 l of l

### Data File U;\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\041-500l.D Sample Name: PS R2 In A *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method J ... 

### ast changed 

### EO Seq. Line 

### Mr Burns Location 

### 10/2/2010 4:22:35 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\HETHODS\HPLC53PG98.M 10/4/2010 9:58:17 AM by 

### IGG (modified after loading} 

### 50 1



# r-· --ADC1**A~Ai5C1CHANNEL A(U:IHPLC201D64iM.RiiTJR.NSIDATA\OCTIHPLC53f'698\041~55o1.D)**  

### -------, 

## !**uS/em-~** 180..:) 

# :::11 120 .,..... 

# "' 100-3 ;;; 

### j I 

## ao -1 

## I, 

# l ,,**~** 60 . ,! \ 1 

## :g 

# l 1·

### ~ 

# l I 

# I () I 

### 40. 

# I : ' ill I ·1 l(J**\~** 

## ;z (<) q r 

# 2:

# br&~k~~~~.:!~j~::~?:**--,_~·- -~·~:~~)** **~;~~----=·-·:~- ~;j=~** **m;~ =======================================================~~============**  External Standard Report**===========================================,.,~.,.========================** Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:58:25 AM 1.0000 1.0000 Use Multiplier & Dilution Factor with ISTDs 

### Sj.gnal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area**~nt/Area** Amount Grp Name



### (min] [uS/cm*s] [ug/mL] 

# -------l------!----------r----------l----------1--!------------------ 3.151 BV 937.34271 1.70860e-2 16.01546 Fluoride 4.265 VB 28.33126 2.84328e-2 8.05538e-l Chloride Totals : 

### 16.82100 

### ==================================================-'===o:·================- *** End of Report 

### ***

Instrument

### AfC:WP!JJll!~:tJ9-**f9-l~\ll?4** 5 AM IGG

### EPJi'~i¥tlr§s'/BN~**~~6'jli\9f** AUGUST A PLANTS 4 & 5. 

### SALISBURY PLANT 6 SEPTEMBER 2010 

### APPENDIX**PAGp~e409** 

### 1 of 

### 1

### Oa ta Hle U: 

### \H>' l,CLU lU\14 \MR 

### BURNS\DATA \OCT\HPLC53PG98 \041-5002. D Sample Name: P5 R2 In 

### A *10 0910-96 BORAL BRICKS 

## ================================================:==================== Acq. Operator Acq. Instrument Injection Date Acq. 

### Metl;od 

### Last changed Ana_lysis Method 

### Last changed EO Seq. Line 

### Mr Burns Location 10/2/2010 4:34:54 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM O:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:58:17 AM 

# by IGG {modified after loading) 50 2

**j:::~- --ADCfA,**  

### AOCfCHANNELA(D \HPLC201004\MR

**BURNS\DAl'A\OCf\HPLCs3P~9a\o41-s062** 

### D} 

# I 180 , 

### I 160 • I j

**~** 

## ! 

# 140-l g , u:

External Standard Report 

### =====================-=-======================""'============="'-·-========== Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal 10/4/2010 1.0000 1.0000 9:58:25 AM Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: 

### ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s} [ug/rnL} 

## -------i------l----------l----------i----------1--l------------------ 3.150 VV 935.54138 1.70860e-2 15.98466 Fluoride 

### 4.265 VB 

### 28.56014 2.84155e-2 8.11552e-1 Chloride Totals : 

### 16.79621

**===========================""""·=""=""-=======:c..-=o=:==:c"================"""-""~"==** 

### *** End of Report 

### ***

JO/ i/?010 q .SA 5 

### EA#0910-96 Page83of202 Instrument Atc"PRcfJECTNo. P-'10f42 

### 4 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAc£'tlh"410 1 of 1

### Data File O:\HPLC2010Q4\MR BORNS\DATA\OCT\HPLC53PG98\042-510l.D Sample Name: P5 R3 In A *10 0910-96 BORALBRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 51 Acq. Instrument Mr_Burns Location Injecti.on Date 10/2/2010 4:47:14

**PI~** 

### Inj 1 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:39:38 AM by IGG 

### --------ADcT.(-AOCTCHANNEL A 

### {LiiHPtJ:2o10Q4\MRBURNS\DATA\OCT\HPL-C53PG98\042-s1 

### 01.0) uS/em 

### ·1 

# '

====================================================''""-"'=="==========""== 

### External Standard Report

**============================================================~===~====** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 1.0000 1. 

### 0000 Use Multiplier & Dilution Factor with ISTDs Signal 1: ADCl Ar 

### ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount

**G~p** 

### Name

[min] [uS/cm*sj [ug/mL] 

# -------l------l----------l----------l----------l--l------------------ 3.158 MM 1155.25562 1.70880e-2 19.74100 Fluoride 4.265 MM 41.25723 2.77563e-2 1.14515 Chloride Totals : 20.88615

**=-======================================================o======:.,c:;;:.·,.-..-,~,,...:oo-.""'=-o""** 

### *** End of Report 

## ***

**InstrumentAICflj!_P~~£ol"l9 FJ:~q1,fg:**  25 AM



### IGGEPA=MR~§~NPrw'f **~1\&JEi!W** AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 201 0 **···-··-·------------~** 

# i

APPENDIX

**PAGip~e411** 1 of 1

### Data

**Fi~e** 

### U:\HPLC201UQ4\MR

**BURNS\DATA\OCT\HPLC~oPG9e\U4Z-~l02.D** 

### Sample Name: PS R3 In A *10 0910-96 BORAL BRICKS =:=.======:;===================================::o==:= 

### ===================== Acq. Operator EO Seq. Line 51 Acq. Instrument Mr Burns J_,ocation 

### Injection Date 10/2/2010 4:59:35 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Ana 1ysi s Method 0: 

### \HPLC20 1 0Q3 \MR BURNS\METHODS \HPJ"C53PG98. M Last changed 10/4/2010 9:39:38 AM by IGG ----ADC1 ;;;;·ADC1 CHANNEL A {U:\HPLC2010Q4\MR BORNS\DATA\OCT\HPLCS3Pi398\o4·2:sio2:-D)-·· uS/em 

### j

180



### ~ 160



# ~ 1 

# ::ll !\ 

## '· :[

**so~** ! 

## I

**~** 

## 6oJ 

# I i ·g 

## j !! 

# t5 a,.'b 40



### -~ \ 

### '*'ep<b J \ ID "<tO 1.0 20 

### j 

# re 1 · ..

**~** ,e;'l> 

### !;;t;::: t---

**~** N ' \
..... ,

**~** u:il.ci ,...: j I



# ---~-~-·~--~~-. **----~-~- --:~-~~--t-=-1~:~~**  **--~~-----~=~~~~~~----·~r~·-=·=~~~=--,-----·~r;---~~~~~**

**====================~=====~~~========================================** 

### External Standard Report

**===========o============================"''-==~===============""·===========** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 1.0000 1. 

### 0000 Use Multiplier & Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min) 

### [uS/em's) [ug/mL] 

## -------l------l----------l----------l----------1--l------------------ 3. 121 

### 4.265 MM 40.98282 2.77662e-2 1.13794 Fluoride Chloride Totals ; 1.13794 1 Warnings or Errors Warning : Calibrated compound ( s) not found

**==================================================================~==** 

### *** End of Report 

### ***

IGG EA# 0910-96 Page 85 of202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~~ge412 l 

### of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG100\009-1001.D Sample Name: P5 R2 In A *20 0910-96 BORALBRICKS

**====~==========================================================~~====** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/4/2010 5:39:47 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U: \ HPLC20 1 OQ3 \MR BURNS\METHODS \HPLC53PG10 0. f1 10/5/2010 9:18:49 

### AM by IGG 10 

### 1
(modified after loading)

**~-----;tiliC1A.A1fCTCHANNECA-(O:\HPLC2o10d4\MR-BURNs\DAfA\ocnHPLC53PG1-60\(Y6s-1oD1.Dr**
**------··------------~** uS/em 

### l i 180



### ~

**~** 160



### ~ 

## J 140 -4 

## 1 120-1



### ~

**~** 

# 1001

**~** 80 CJ

**~** ,1·!



### ~

**~**

**,~** 60- ('<')

**~**



# 40~ 

# f\\ 0 

## B 8 

# I 2: 1.:_::::_:;



# '-~-.==:.-"L;"rL =-:-J .



# ·-·~::;:·:__

# ~__:_:;-- .



# .Y~=::::_, -'-=--;---==;:==::;:.:!
___----- L ____ ····-··--·--·- 

## 2 _____________**:!_------------··--·---~- ·--~---·---**  __!I!i

**==================,.,=====:::====""==-=''"""''='"'"'~====""==========="-"===""'===:o-.•'"'"''==""** 

### External Standard Report

**=================================~=========================:=========** 

### Sorted 

### By Calib. Data l"iodified 

### Multiplier Dilution 

### Signal 10/5/2010 9:21:11 AH 1.0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------!------1---------- l----------l----------j--j------------------ 3.138 BV 508.88586 1.71526e-2 8.72872 Fluoride 4.252 BB 14.43764 3.07776e-2 4.44356e-1 Chloride 

### Totals : 9.17308

**==============-..---====:======O".o==~~-==-~==-~=:=="'-'==:·""~-~=====.,===c~::o":=;..-:""===::-;======:::-o=** 

### *** End of 

### Report 

### ***

Instrument AJ:Cfljlp,lfl>lit\9·



### l/r!~;p?l4 AM IGG



### EP~fu'kllJI.lt\hJ/IiNfim **~~&!E\91<** AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### APPENDIX

**PAGp~e413** 

### 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG100\009-1002.D Sample Name: P5 R2 In A *20 0910-96 BORAL BRICKS

**=========~===========================================================** Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 

### 10/4/2010 5:52:07 PM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:19 AM 

### by IGG 10 2


### (modified after loading) .-- ... -Al)cT.("/(5-cTCHANNEL A (lEHP[C201



### oo4\;:,M;;,R:;,B;cU~R!.,N"SI'"D"'A"'T A"'l"o"cn"'HPlcs3PGf60\009-1 00-i.D) ----- .


### ~--------~ uS/em 

## l

180 160- 140
100 ---i



# 80~

**~**

<0 

## i


# ___)
.• , ·- __ "_J..**--~~-~·** -,-----·-·-·-

**---,-----~--------,---..,.------** 

### -.------ 6'----------"-8.. mi 

### External Standard Report ======"===========================================c:c-===e=============="'-" 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 

### 10/5/2010 1. 

### 0000 1.0000 9:21:11 AM Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area 

### Amount Grp Name



### [min] [uS/cm*sJ [ug/mL] 

## -------;------l----------l----------l----------l--l------------------ 3.137 BV 

### 506.10544 1.71527e-2 8.68108 Fluoride 4.251 BB 

### 15.11480 3.059l7e-2 4.63306e-1 Chloride Totals : 

### 9.14439

**====================================~==============~~~================** 

### *** End of 

### Report 

### ***

EA# 0910-96 

### Page 87 of 

### 202 Instrument

**ATc~&f"ejl~Q.** 

### P'-liff42 

### 22 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~<Nile414** 1 

### of 1

### Data File U;\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG100\010-110l.D Sample Name; PS R3 In A *20 0910-96 BORAL BRICKS

**======~==========================~========~==========================** 

### Acq. Operator Acq. Instrument 

### Injection Date 

### Acq. Method Last changed Analysis Method 

### Last changed EO Seq. Line 

### Mr Burns Location 10/4/2010 6:04:27 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/l/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 

### AM by 

### IGG (modified after loading) 11 

### 1



# r -·-·····-···---- ADCTA,A6c1 CHANNEL 

### A (U\HPLC2010Q4\MR 8URNS\DATA\OCT\HPLC-53P(fi50\0TO:,-,-iffl5f- -- -- 

## ---------_.!1 uS/em

**~** 

# I 

# 1soi 1 ' 160-1 

### I

**~** I 1 

# I 140

**-~** 120 -=i 

## j 100.



## ====================""'============:======,==================="=========.:::= External Standard Report 

### ==================o:===·================================================ Sorted By 

### Calib. Data Modified Signal 

### 10/5/2010 

### 1. 0000 9:21:11 AM Multiplier Dilution Use Multiplier 

### & 1.0000 Dilution Factor 

### with ISTDs Signal l; ADCl A, ADCl CHANNEL A RetTime Type 

### Area Amt/Area Amount 

### Grp Name

[min) [uS/cm*s) [ug/mLJ 

## -------l------l----------l----------l----------l--l------------------ 3.142 BB 639.42731 1.71486e-2 10.96531 Fluoride 4.251 BB 23.24886 2.9269le-2 6.80473e-1 Chloride Totals : 

### 11.64579

**========:o::==============""-"'~=='·"==============-"''"-'=====,==================** 

### *** End of Report 

### ***

Instrument 

## Alrclffi'oJEl:JT:!r% il'm4229 AM IGG



## EP~~~Ro~~g;~~J'-i'Jlir **p~g~m** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PA~415** 1 

### of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG100\010-1102.D Sample Name: P5 R3 In 

### A *20 0910-96 BORAL BRICKS 

## ===========================::======================================== Acq. Operator Acq. Instrument Injection Date Acq. Method 

### Last changed 

### Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/4/2010 6:16:46 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M

. 10/5/2010 9:18:49 AM 

### by IGG

{modified after loading) 11 2

f------------------A6C1 A, ADC1 CHANNEL A (U:\HPLC201004\MR 

### BURNS\5AfA\6Ct\HPlC53-PG100\010-1162.5}_______ ---------------

1 

# I 

# I ' 

# ' I 

# i uS/em] 1801 160 

## cj 1 140 

## l 1201 100 -=l

### ~ 80**~**

# 60~ ' 

# i**~~- =================="'-'====·===========================.,.-.-~=::.~===============**  

### External Standard Report**~z==============·==~~======:==============================:.-,:==:::t'==========** 

### Sorted By Calib. 

### Data Modified Multiplier Dilution Signal 

### 10/5/2010 9:21:11 AM 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, 

### ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] 

### [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.]74 BB 645.62323 1.71485e-2 11.07147 Fluoride 4.287 BB 23.89014 2.92027e-2 6.97657e-l Chloride Totals : 11.76913
=:=========""' ====.,-..::"'**""="""-~''-"=:;.:,** = == 

### ==o:o==== = = 

### =--===-====**"-"C-~""** === 

### =====-=============**~~*** 

### End of Report 

### ***

I GG**EP~~~IIlSIIlN~ ~~~<9jil\l)i1** 

AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAG!'~e416** l of 

### 1

### Data 

### File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\043-5201.D Sample Name: P5 R1 Out A '10 0910-96 BORAL BRICKS

**============================================~====~=====~=============** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/2/2010 5:11:54 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:58:17 AM by 

### IGG {modified after loading) 

### 52 1

**--~A'-D'-C'-1-A:** ADCiCl·lANNELI\(U:\HPLC2010Q4\MRBURNSID''A"T"'A'-IO"C"TI'"H"-P 50 L 7 c"s"3"'PG"9"'a>c\0"-4"3co·S'"2"o'1."D')

**-----~~---·** uS/em]

180 

# j 160



### ~ 140 

# .j

**~** 120



### ~ j 100 

# "i 

# 80-l

**~** !D 

# eaj·

**~**
**~** 40- ' 0 (!) ;_jl.l')

**~** a) ,... Ol J 20



### ~ **~~**
**~ ~**  **~**

**~** 

## ! I 

# 1--A-..!

**~~,..--~~ ~**  "!' ---



# I~ ----- _, 

# -.-!:'"~-,.- ---



# --~- __ / 

# ! ____________ **~------=r=~--=~==r-~-==-=--:·----r -=-~-~~~=i·-~~~--~**  

# ...·

__

**~** 

# __ **~_~_-_-,'o--~-~-,,2-~m_,i** =======,============<==;;===·=""·==,·==============================0'='=.,===== External Standard Report """"===================================================================== Sorted By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:58:25 AM l. 

### 0000 1. 

### 0000 Use Multiplier 

### & Dilution Factor 

### with ISTDs 

### Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] 

### [uS/cm*s) [ug/mL] 

## -------!------l----------l----------l----------l--1------------------ 3-121 BV 44.45597 1.68759e-2 7.50236e-1 Fluoride 4.260 BV 3.20621 3.78526e-2 1.21364e-1 Chloride Totals : 8. 

### 71600e-l

**==============================~"'=·""'===''""""'===:.======================.~=~"==•>'=** 

### *** End of Report 

### ***

Instrument ATCRRO!J)"Illli:NO. 8.-(leOO: 

### 05 AM


### IGGEp)\'~fl!/J;g?lj1j~ft%'1-~~8)~ AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~~e417** 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\043-5202.D Sample Name: P5 Rl Out A *10 0910-96 BORAL BRICKS
**============================~========================================** Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed EO Seq. Line Mr Burns Location 

### 10/2/2010 5:24:14 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U: \HPLC2 01 OQ3 \MR BURNS\METHODS \HPI,C53PG98. M 10/4/2010 9:58:17 AM by IGG 

### 52 2

**(modi~** i 

### ed __ af

**t:_~~-~~.9}39** 

### ) _____________________



### :----ccA~D~C~17 A-.



### A,-DnC"1""CT;He;:A-c,N~N;;;EL A (U•IHPLC201 OQ4\MR BURNS\DA

### TA\OCT\HPLC53PG98\043""'-5~2"'02'.nD)~-· 

### ' 

# I uS/cml 180. 160 140 120 .. 100 80

**==============================="""'-'==>=-==,.~==============================** External Standard Report ================================================='="·'-"'"-.,================= Sorted By Calib. Data Modified Multiplier Signal 

### 10/4/2010 9:58:25 AM 1.0000 Dilution 1.0000 Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADC1 CHANNEL A Ret?irne Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] 

### [ug/mL] 

## -------i------l----------l----------l----------l--l------------------ 3.122 BV 41.62362 1.68609e-2 7.01813e-l Fluoride 4.258 BV 2.51682 3.78526e-2 9.52680e-2 Chloride Totals : 

### 7.9708le-l =""="""'=============-="''==-===--"====""""=""=====<><=,============================ 

### *** End of Report



## rnstrumentAic~eClll>J6 **F!-aJU1~g:** 14 AM 

## IGGEp.ff?ik~~1£sW3NY~§'f~~d'M:o/ AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGIPillqB418 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG98\044-5701.D Sample Name: P5 R2 Out A *10 0910-96 BORAL BRICKS 

## ===========================-=====:o=c=========""==========""======""===""'==== Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed EO Seq. Line 

### Mr Burns Location 

### 10/2/2010 7:15:12 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC20lOQ3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:58:17 AM by 

### IGG (modified after loading) 

### 57 1 

# r·· ------··7ii:5cfA:-A·oc1cHANNEL A (U:\HPLC2010Q4\MR BURNSiDATAIOCT\l'iPLCSSPG98\644-5701.D) uSIGm] 

# I

**180~** 

## ' 160



### -~ 1



### 140~ 120 

# j 100. 80· 

# " " " 60 ·co 

# " 0 

## "" 

# " 0 

## u:: 

# ,., 40-- 0

**==========""'====;-:,-·=========""=========================""'===·~"=============** External Standard Report =·""'"=""======================""==========='""-=============,================= Sorted By 

### Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 9:58:25 AM 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type 

### Area Amt/Area 

### Amount Grp Name

[min] [uS/cm*s) [ug/mL) 

## -------I------!----------J----------J----------J--I------------------ 3.125 BV 48.65992 1.68950e-2 8.22109e-l Fluoride 4.262 BV 3.04968 3.78526e-2 1.15438e-l Chloride Totals : 9.37547e-l

<::= ======="'='""'

**=<==·="'~--,o=.=** = 

### ""'====== ========== 

### ===================:: =:::= =; = === 

### ====

**=~~**

**~'*** 

### End of Report 

### ***

Instrument AlrclRlmlWI":Nl>.



## ~11 oOO: 25 AM I GG 

## EPfi"!RO~J~~-JlBJ'fl!l;'t **~~8\~8f** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE"""'419 1 

### of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\044-5702.D Sample Name: P5 R2 Out A 

### * 10 0910-96 BORAL BRICKS
**============""===============================-'='================::::==~=====** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed 

### Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 10/2/2010 7:27:32 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHOD.S\HPLC53PG98.M 10/4/2010 9:58:17 AM by 

### IGG {modified after loading) 57 

### 2

**~-------ADCTA.** 

### ADC1 CHANNEL A 

### (U:IHPLC2oi0041MR BUR-NSIDATA\OCnHPLC53PG98\044-5702.D) 

# --·--·-·------l !

**uS/em~** • 

### i 

## i 180 

## i 

# I 160 ·



# ~

Il

# l ::: 100- 80 

# I i



## ~



## 60~

**~** 40.:.! I 

## ., -f o

**~~** Nf'-. (Xi m 

# 201

**~ ~~:":!** 
**~ ~**  '<1: r-. j__ __ .J

**~-** r _______tL_.;g____--,.......l • 

### .::!:.f '!. ·! 10

**-~**

**~-** 0 --l--- T-·····---,--..,..-------,---·-.------"r- 

# I / :;=c:::;:=:;::::::;-=::::..,.._,__--._____ -,----------,-----l----·-r··------ 

### L __ _ 2 _____

### ±___
______ _ §. 8 __J_Q________________!?_____.mL_
**~=====================================================~~=============** 

### External Standard Report **=================================================~===================** 

### Sorted 

### By Cal.ib. Data Modified Multiplier Dilution Signal 10/4/2010 9:58:25 AM 1.0000 1. 

### 0000 

### Use Multiplier & 

### Dilution 

### Factor with !STDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTirne Type Area Amt/Area Amount Grp Name

[min) [uS/cm*s) [ug/mL) 

## -------!------l----------l----------l----------l--i------------------ 3.125 

### BV 49.63752 1.68990e-2 8.38823e-l Fluoride 4.262 

### BV 3.03725 3.78526e-2 l.l4967e-1 Chloride 

### Totals : 9.53790e-l

**=""============""-="·~===========~"'-======================~""-"''""'===========co=:/.~-oooo=** 

### *** End of Report 

### ***

ATC PROJECT No. P-10142 Instrument 1 10/4/2010 10:00:35 AM **EP£1\I,!Il~%S!WJ** 

## fl'§ge 00CO\E:ID2



### AB~USTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 420 

### Page 1 of 

### 1

# ( ...........

**~** .............. v. \.U-'...<.1'--.C.V.S.V\i":t \l"ll'\ **DUI'\i~.:>** \Ui'iJ.h\VO......! **\tlt'.LO.......:::l.Jt'G~ti \V':I~-:.~U1.**  D 

### Sample Name: PS R3 Out A '10 0910-96 BORAL BRICKS **============;==============================================~=========** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed EO Seq. Line Mr Burns Location 10/2/2010 7:39:51 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:58:17 AM by 

### IGG (modified after: loading) 58 1

**r----·---~--ADC1** 

### A. ADC1 CHANNEL A 

### (U:\HPCC201004\MR -BO"RNS\DAT**A\OCT\HPLC53P~98\b45-5801~0)** ____ **----~** 

## I

**~~** 

# I · 1ao 

## I 160 140 120 .j



# 100~ 1 

# sol

**~** 60-:J 

### ·g I 

# ff.
1 1,1 

# 401 1 <D

**~co** o N a> 20-=! 10 --:;;; <D :,; eo "¢" i • 

# I

'" - **V.~ r·'-..:!.1----::--f--"'.?....._-···.----'···~**  ---..- _________ j 

# I 0 

# J_I_-----·--r-'_-~.:::_,- ,.. - --_ ·'"': ____

., ___·_ - "!



# ~ **~ -.--T-~~----.......----**  

### ' **---··,-----.---...--~--.,.....--j** L-.

_____________ 2___________ 4 6 __________ _____!! ________ _,1'-'0'------------------E-_miri **======================"'"================~"=====================o::::=======** 

### External Standard Report **~=======================================~=============~==============** 

### Sor:ted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4(2010 

### 1.0000 1.0000 9:58:25 AM Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Ar:ea Amt/Area

**&~ount** 

### Grp Name

[min] [uS/cm*sJ [ug/rnLJ 

## -------l------l----------l----------l----------1--l------------------ 3.123 BV 4.260 BV Totals : 45.96114 l.68832e-2 7.75969e-1 3.00710 3.78526e-2 l.13826e-1 8.89795e-l Fluoride Chlor:ide **"'o-"'==•==~o:=~:--'==============""-=~-==============""'""'"'=========-='~'==========-====** 

## *** End of Repor:t 

### ***

Instrument 

# A;-cWJ.ktHWo

**~-go~.iJ1'** 48 AM 

### IGG EA# 0910-96 Page 94 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PA<Jfo'tlli' 421 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\045-5802.D Sample Name: PS R3 Out A *10 0910-96 BORALBRICKS 

### ===============·-====================================================== Acq. Operator Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/2/2010 7:52:11 PM Inj C: \HPLC2010Q3\MR BURNS\Mt:THODS\,JETROHM.M 4/1/2010 4:15:36 PM U: \HPLC2010Q3\MR BORNS\METHODS\HPLC53PG98. M 10/4/2010 9;58:17 AM by 

### IGG 

### (modified after loading} 58 

### 2

**=========================""-=::...-=.,:.~======================================** 

### External Standard Report 

### =========================================-,=-=========================== Sorted 

### By Calib. Data Modified Multiplier Dilution 

### Signal 10/4/2010 1.0000 1.0000 9:58:25 AM 

### Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------\----------l----------l--1------------------ 3.123 BV 45.52016 1.688lle-2 7.68430e-1 Fluoride 4.260 BV 3.13018 3.78526e-2 1.18485e-1 Chloride

**Tot~als** : 

### 8.86915e-l

**""================================""'"·=:.=,=·=~:=""====""=======================** 

### *** End of

**~eport** 

### ***

Instrument AjfClftR4J,EM:NJl.IJ'1JQW: 57 AM IGG 

### EP!i:fd/l!lJi9;-~5J'~~8~~ AUGUSTA PLANTS 4 & 5, 

### SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~** 

### 422 1 of 1Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\046-590l.D Sample Name; P5 Rl In B *10 0910-96 BORALBRICKS **==========~================~===~==~=======================~==========** 

### Acq. Operator EO Seq. Line 59 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 8:03:59 PM Inj 1 Acq. Method C:\HPLC201DQ3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Ana 1 ysi 

### s Method U: \HPLC2 0 10Q3\MR BURNS \METHODS\HPLC53PG98CL. M Last changed 10/4/2010 9:33:01 

### AM by IGG ·
. ·---ADC 1 

### A, ADC1CHANNE.CA (U:\HPCC201004\MR 

### BURNS\DAT"~A~\O~C~n~H~P~L~C~5~3~PG=98~\.0~4~6~-5~9
**0~1.~D-) ----'---~**  uS/em 

# J i

**~**

1801 

# I 1 160



# ~ 

# I 140



# ~ i



# 120~ I 

# ' 

# 1:: 

# l

**60~**

**~**



# ~1 

# I j V 0:0 1'- t-- I 1 2o 

# i

**~ ~**  **~**

**~** 0 \



# I_----~~--~~~->"~~: **~--:---'=~-=~ i~~-~J**  ,C_ 

# -=-~:~~~-~-L **1~~----·-· ---,--~;·-·--·~m:**  ===============,:;=,===,==============================""===.,·==,.=====""===""'= External Standard Report ================"""============="-'===,=====================:::::::============ Sorted By Calib. Data t1odified Multiplier Signal 10/4/2010 9:32:52 AM 1.0000 Dilution 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*sJ [,ug/rnLJ 

## -------l------j----------l----------l----------l--l------------------ 4.156 Chloride Totals ; 0.00000 1 Warnings or Errors Warning : Calibrated compound(s) not found **=======·==·===~'-'::======="'='"""=""============================================ ========================================~"===·"=""=:==·"""==================**  Area Percent Report **-""======""'·==:c~-=:==,.,===~-::=,,_,.=~===========================""======""="'""'-========** Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 

### 1. 0000 1.0000 Use Multiplier & Dilution Factor with ISTDs 

### Instrument AJ.TC11(j}(!Jf;M1ttP-



### ~(!9~2: 40 

### AM IGG 

### E~~fM\~tffml'r~8~?8i! AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGp'~** 423 1 0 f 2UdLct

**rl~e U:\tl~L~'U1UU4\MH**  

### HURNS\OATA\OCT\HPLC53PG98\046-5902.D Sample Name: P5 Rl In B '10 0910-96 BORAL BRICKS **=======~=============================================================** 

### Acq. Operator EO Seq. Line 59 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 8:21:17 PM Inj 2 

### Acq. Met hod C: \HPLC2 01 OQ3 \MR BURNS \METHODS \METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U: 

### \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by 

### IGG r-· ADC1 A, ADC1 CHAN'NELA(li,IHPLC201004\MR BURNSIDATJ\16cnHP[CS3PG981046-5902.D) 

# I

**uS/em~** 180 160

**~**

**====================================================~================** 

### External Standard Report =================::o-==========o::-·======================================= 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1. 

### 0000 1. 

# oooo Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount 

### G=p Name

[min) [uS/em's) [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.156 Chloride 

### Totals : 0.00000 1 

### Warnings or Errors Warning : Calibrated compound(s) not 

### found **=================c""=========~'::.~============o..~o;o:;:o:===========.::::::============"" """-"'-=================,.:=e~=============:o.o=""=======:=<:================·"'======~**  

### Area Percent Report **=====o:==,--"=~================,.-:.='='========"'-·================""========,======** 

### Sorted By CaJ. .ib. Data 

### Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 

### 1. 0000 

### Use Multiplier & 

### Dilution Factor with ISTDs

- EA# 0910-96 Page 97 of 202 lGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### APPENDIX
**PA~~424** 

### 1 of 2Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\047-6001.D Sample Name: P5 R2 In B *10 0910-96 BORALBRICKS

**==========:==================================================<=<=~·==·===** 

### Acq. Operator EO Seq. Line 60 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 8:38:36 PM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC2010Q3 \MR BURNS\METHODS\HPLC53PG98Cl •. M Last changed 10/4/2010 9:33:01 AM by IGG ADC1 A, ADC1 CHAffNELA **(U\HPLc2o1iii:l41MR.BURNS\DATAIOCnHPLC53i'G981647~6il6H5j-** ----. - --, uS/em 1

180 160 140- 120 100

40 20-

**~ ~**  **~**

**~**

**~** i

**~ ~**  **~**

**~**

**~** I N

**~ ~** 

**~**

**~** j 

### i 

# i \ 

## '\ ... _ 0 **JI----·-··T·----1-'--"--T~_c•~-.----- Tr_·_-_-_~_-_-T·_·.'-rCC'CC'CC'_-,=---___J**  -.--·- -----·-·-" ....-/

-1 

### ----,--.--.-,.--r----r-·--r·-------,----,---·-·r ········- . . ----,- -.---- 2 -- _1_ ___________ ,,,.,__________§_ _________________IL_______________ **l~-------·-_____:!l**

### ______ 

### ITI.t.

**==========;:,===~===================================================:=.==** 

### External Standard Report 

## ===================================================================== Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 

### 1. 0000 1.0000 9:32:52 AM 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCI A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min) [uS/crn*s) [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.156 Chloride Totals : 0.00000 1 

### t-Jarnings or Errors Warning : Calibrated compound(s) not found 

## ================================================================='""====

**===::::========================~~""=""~-,·===,;;=;;=======.,.=========:====:=========** 

### Area Percent Report
**==============:=:=="-'=~.,====c==~=============================~=============** 

### Sorted 

### By Signal Calib. Data Modified 10/4/2010 9:32:52 At1 

### Multiplier 1.0000 Dilution 1.0000 Use r-:Jultiplier & 

### Dilution Factor with ISTDs
ATC PROJECT No. P-1 0142 EPl'tl\lJl<f9>116l96Nff;!i@J 98<01120l2 Instrument 1 10/ 4 /Z010 lO:OZ:0 1 AM t-'i!f;usTAPLANTS4&5,SALISBURYPLANT6 APPENDIX PAGE No. 425 

### Page 1 of 2 SEPTEMBER 2010Data File U:\HPLC20IOQ4\MR BURNS\DATA\OCT\HPLC53PG98\047-6002.D Sample Name: PS R2 In B *10 0910-96 BORALBRICKS 

### =======""===•:;:;========================================================= Acq. Operator EO Seq. Line 

### 60 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 8:55:53 PM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG ADC1 A. ADC1 CHANNEL A (U:IHPLC2010Q41MRBURNSIDATMOCT\HPCCS3PG98\047·6002D)



### ======================================·""=====================,==.::====== External Standard Report 

## ===================================================================== Sorted By Calib. Data Moditied Multiplier Dilution Signal 10/4/2010 1.0000 1.0000 9:32:52 AM 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A 1 ADCl CHANNEl, A 

### RetTime Type Area Amt/Area Amount Grp Name

[min) [uS/cm*s) [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.156 Chloride Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound(s) not found **._,,,_~====='~""==,==»·==~~'''"====~==-=~=============<=o========================= =::oo.-.,========""~==""==~"'-"""""-""'"'-'==========""====================-=::::::o:::o==-========**  

### Area Percent Report **======================================'-"'==="'"·'~===========::.:===""·'"''·""=======** 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs
Instrument



### ATCffi0!1)'2!n"~. llOGW: 10 AM 

### IGGEPJI'~<¥J.li\~~f3rJ'ft!I/T~~8J~ AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0 APPENDIX PAGp<l'\j>e426 1 of 2

### Data File U:\HPLC201DQ4\MR BURNS\DATA\OCT\HPLC53PG98\048-6101.D Sample Name: PS R3 In B *10 0910-96 BORAL BRICKS

**================~========~===========================================** 

### Acq. Operator EO Seq. Line 61 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 9:13:11 PM Inj 1 

### Acq. Method C: \HPLC2010Q3 \MR BURNS\METHODS\METROHM. M 

### Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed

**10/~/2010** 

### 9:33:01 AM by 

### IGG

**----···-·-~--A5C1A,A6c1** CHANNEL A (U:\HPLC2010Q4\MR

**BURNS\DA"fA\bCT\HPLCtr3PG98\Ci48~10fj)f** 

### ------------- ;!



# ~

External Standard Report

**=============~===============================================·========** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 1.0000 1.0000 9:32:52 AM Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*sJ [ug/mLJ 

## -------l------l----------l----------j----------l--1------------------ 4.156 Chloride Totals : 0.00000 

### 1 Warnings 

### or Errors Warning : Calibrated compound(s) not found

**=====================================,::=================="""'''""·'=~=======** 

### Area Percent Report

**======================o·~==-::=:==:o~==============================·"-'==.--=======** 

### Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1. 

### 0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs
Instrument



## Atc~J<'~qJ J,J0.



## IL~o~: 21 AM I GG



## EPI¥itR **11~Ps~ib.ff'~gT WRo5~~~**  **2** 

### AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGE~e427** 

### 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG98\048-6102.D Sample Name: PS R3 In B '10 0910-96 BORAL BRICKS 

### Acq. Operator EO Seq. Line 61 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 9;30:29 PM Inj 2 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U;\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG



### ~--~~:::·i ADC1 A, ADCi CHANNEL 

### A(U:IHPLC2010Q4\MR 

### BURNS\bl\f/i\()CTIHPLCSJ.PG9~,!648.:5i"ii2'.D")_________

# l

! 160



### -~ 140

**·~** 120



# ~ ., 100

**~** 

### j

**M~** 

### I

. i,. ,,1 I 60 ..:1 

# ' 

# I '

**•o~** I



# ---~;:t~=;~~=-:l~~ 

# _ **~**

# :. : __-_,::t<e



# ~--~ _::_ -·

# ~-'=~~~-:r··-··=~=~-=~~~=::-:·~=--=-';,_:_~:

# J

=============:::,========-======,::::======================================== 

### External Standard Report
**"-"''"'='"'"'·===c·.o========""==""'="'~=:::~,;:===,..,=======================================** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 l. 

### 0000 1.0000 9:32:52 AM Use I'-1ultiplier & 

### Dilution F'actor with IS'I'Ds 

### Signal 1: 

### ADCl A, ADC1 CHANNEL A RetTime 

### Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------1------1----------l----------l----------1--l------------------ 4.156 Chloride Totals : 

### 0.00000 1 Warnings or Errors Warning : Calibrated cornpound(s) not found

**======""==="=''-"'"-"===~''""0::"""-'-'==,=~~="'-'"'-~~-""''~""-====::::=""=======""==""=================::=o== ==============================================~===""===~~=============** 


### Sorted 

### By Calib. Data Modified Multiplier Dilution Area Percent Report Signal 

### 10/4/2010 9:32:52 

### AM 1.0000 1. 

### 0000 Use Multiplier & Dilution Factor with ISTDs



### InstrumentAICRWl!Jg~lJW. fh'lQtl!2: 

### 32 At-1 

### IGGEM(!~@~\k~jbtfi'E~§'r1~o9bEH2 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~<Nge428** 1 

### of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\049-6201,D Sample Name: P5 R1 out 8 *10 0910-96 BORALBRICKS

**=~===================================================================** 

### Acq. Operator EO Seq. Line 62 

### Acq. Instrument Mr Burns Locat.ion Injection Date 10(2(2010 9:47:47 PM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG ADC1 A. 

### ADC1 CHANNEL A 

### (U:IHPLC2010Q4\MR BURNSIDATAIOCTIHPLC53PG981049·6201.D) uS/em l

180



# -~ 160 

## .j 

# ;::_1 1001



### 80·~ . 

# l I

**w~** 

# .



# ~~ 

# I 2:

# l-• } T--:L 

# §_



# ~-·-" **~** - ,----,



# ---~ §



# -~-;--·-,-··--~ .J .

**~----~2,_** ___ , _________

### i. ......,_..__ , ____ _§__________ , 8 

## ~ 

# i

# I I

\ '



## \ !

**~---------,---'** I ! 10 12

**============~,==,~==========:-.::c=:::'""======,======"""'=""='""·~==============="'-~====** 

### External Standard 

### Report ===================================================================== 

### Sorted 

### By Calib. Data Modified Signal 10/4/2010 1.0000 9:32:52 

### AM Multiplier Dilution 

### Use Multiplier 

### & l. 

### 0000 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL A 

### RetTime Type Area 

### Amt/Area Amount Grp Name

[min] [uS/crn*s] [ug(rn.L] 

## -------l------l----------j----------l----------l .... i--------- .. -------- 4.156 Chloride Totals : 0.00000 

### 1 Warnings 

### or Errors Warning : Calibrated compound(s) 

### not found -='==:=·=""=============================================""""==,=============

**=""'=============="'-"=~=============·=======** .. ,============================= 

### Area 

### Percent Report

**=========,=::.-o~·-"':.e:.=c"'============"-~=========""=~"'""~="''=====o::·~=~~-"'="'-===~==~'·""-===~~:-..:=c-.::** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10(4/2010 9:32:52 AM 1.0000 1. 0000 Use Multiplier & 

### Dilution 

### Factor with ISTDs mid



### Instrument AfCffiO!J)"§(!':NJ>.f!'()g'IJIJ: 42 AM



### IGGE~J{i~i!li\:;~fb,ij'fEJST **~\ot</2** AUGUST A PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGp~429** 

### 1 of 2

### Data File U:\HPLC2010Q4\MR BORNS\DATA\OCT\HPLC53PG98\049-6202.D Sample Name: P5 R1 out B *10 0910-96 BORAL BRICKS 

## =================================================================""=== Acq. Operator EO Seq. Line 62 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 10:05:05 PH Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/l/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG uS/em

**~** a 

# 1 --- ---··-

**-~7\6¢1** A. ADC1CHANNEL-A-([}\Hf''Lc'201 DQ4\MR BURNS\DATA\OCTIHP[C53PG9B\049:fi2o2:t5)
. -----· .. -·----

. 1801 

# i"' 

# ! 160



## ~ t 140 

## -ll 1 I



## 120~ 100 _:l 80

**==============================================================~=~~===** 

### External Standard Report

**=============================================~=~=====================** 

### Sorted 

### By Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 9:32:52 AM 1.0000 1.0000 Use Multipli.er & 

### Dilution Factor with ISTDs Signal 

### 1: ADCl A, ADCl CHANNEL A RetTime Type Area AmL/Area Amount Grp 

### Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 4.156 Chloride Totals : 

### 0.00000 1 Warnings or Errors VJarning : 

### Calibrated compound ( s) 

### not .found

**===;;o==============c===::;:.-c.:::======================""~=:::;:'-"'================"'-='====**
**====:==============================o=:=================:~:::===============** 

### Area Percent Report

**==================~"=c.,-;===============·""'="'-"=""'========================-~===** 

### Sorted By 

### Signal 

### Calib. Data Modified l0/4/2010 9:32:52 AM Multiplier 

### 1.0000 Dilution 

### 1.0000 Use Multiplier & Dilution Factor with ISTDs
EA# 091 0·96 Page 103 of 202 IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGEiffil! 430 1 

### of 2Data 

### File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\050-6301.D Sample Name: PS R2 Out B *10 0910-96 BORALBRICKS 

## ====:o=============================================;:====================== Acq. Operator EO Seq. Line 63 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 10:22:23 PM Inj 

### 1 Acq. Method C: \HPLC2 010Q3 \MR BURNS\METHODS \METROHM. M Last changed 4/1/2010 4:15:.36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG uS/em 

## l ADC1 A. ADC1 

### cHANNECA {U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PIG98:S0-6361 D)
-- - -- 

# -1

**180~** 

# 1 I ! 160 140



# .. I



# ~ L=-=- ..



# ~-,..=: t-'T-



# ~-!:.:c.::;=:::;:==:'..:,~::.-**e.::;=::;==;=~-=~='-}~~**::.; ..



# ~~~------ **~--~~** 120 100

....... _____ 2 __ 

### -···-······----1. 6 8 ..•...•.... 

### --hl __________**___J_;'~_mirt** 

## ===================================================================== External Standard Report

**==========~=====================~====================================** 

### Sorted 

### By Calib. Data Modified Signal 10/4/2010 1.0000 9:32:52 AM 

### Multiplier 

### Dilution Use Multiplier 

### & 1.0000 

### Dilution Factor with 

### ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp 

### Name

[min] [uS/cm*sJ [ug/rc.L] 

## -------j------j----------l----------l----------l--l------------------ 4.156 Chloride Totals : 0.00000 

### 1 Warrtings 

### or Errors 

### Warning

**~** 

### Calibrated compound(.s) 

### not found

**===""=====""""~~~=·~===============:oo:=-:=:.""=~·~c..oo"''""""='""===========================** 

### Area Percent Report 

### =============,"'=--'='==============================""====··"""""-'================= Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 1.0000 1.0000 9:32:52 AM 

### Use Multiplier 

### & Dilution Factor with ISTDs
ATC PROJECT No. P-10142

**E~fl>!>@~"f{lll)d£1all2** Instrument 1 10/4/2° 10 10:03:0G 1\M j,_'6\jiuSTAPlANTS4&5,SAUSBURYPlANT6 SEPTEMBER 2010 APPENDIX PAGE No. 431 

### Page 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\050-6302.D sample Name: P5 R2 Out B *10 0910-96 BORAL BRICKS

**=======================================================~~============** 

### Acq. Operator EO Seq. Line 63 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 10:39:41 PM Inj 

### 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\"1ETROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/4/2010 9:33:01 AM by IGG 

### ------------·---···AciC-rA-:-A5c1-CHANNEL A (U:\HPLC2010Q4\MR 

### BURNS-.i\D'CA"T"A"Io"c"n"'HPLC53PG98\6S0-6302.b)--------------- uS/cm

**-~** I

**~**

1MJ 

# I , 

# ;:: Ji

IIi 

# I 120



### ~ 

# 3 100--1 j ,1 80



### ~ 

# I 

# M1 I 40



### ~ 

# ' i , I 2
: 

# h=_



# 2~_= __:,.

__



# c::_=

__

:::; __

::. __

# = ___



# ~

__=_"_c;:L=_=;=:;:::c::;:::.....,=6;::::::::;::::'::·!



# :.·~-~e~:= ·



# ~;c ··



# 1~\';-=- · ·



# -~l~ **~d** "' "' "' 

# I "' 0 N 

# "' N ci r L ___ _



### Sorted 

### By 

### Calib. Data Modified Multiplier Dilution 

# .. "' 

# .. r··-

**~~**


### -External Standard Report 

### Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Atllount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 4.156 Chloride Totals : 0.00000
1 

### Warnings or Errors Warning : Calibrated compound(s) not found

**=========================="='=====~c:c:·.o-~=================::o:==·;.:o=============** =""'

**~** "-'"-=·""

**.0::"-~e::-** --- **="-"~=,-~=============-=~='-"'============================""=""=** 

### Area Pe:rcent Report

**====================,..-"==·""========================~===,..~=.:.==============** 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM l. 

### 0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs
Instrument ATC:MO!Jtt()'Wl. 11-ll OOO!: 15 AM I GG



## EM~,.O~~?s~?o~f~~TW~o~\&:if AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE<Npe432 1 of 

### 2

# \ Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\051-6401.D Sample Name: P5 R3 ol.lt B *10 0910-96 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 64 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 10:56:59 PM Inj 1 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC2 01 OQ3 \MR BURNS\METHODS \ HPLC5 3PG98CI,. M Last changed : 10/4/2010 9:33:01 AM by 

### IGG 

# r -- 

# ---l- AocrA:-ADCTCHANNEL A (U:\HPLC2010041MR BURNSIDATAIOCT\HPLCS3PG98\051-6401.D) 

# ! uS/em ;;5 ! 1W



# ~1- 160 

## ' 140 

# i 120 

### _:j ·I



# 100~ **-----~**

# i

l 80-1



# M~ I 11,1



## 4o~ 

## I 2oj



# ~ 

# § &1



# ~ \. 

# I

o



# .:1'==;2-:c=N=,...~=:;:'C:_-=, __::.

__

# "'~~=i;.: __ 

# = __ 

# =·-~---=-~ ... 

# ~-~~~~~56~~~~~-~-~:_.-::._~_~r-::.~==- 

# __**:::~ti==~~~~** 

# -

**~~~~-~=:j**

**=======================~=============================================** 

### External Standard Repcrt
**====================================~===~~===========================** 

### Sorted 

### By Culib. Data Modified Multiplier Dilution Signal 10/4/2010 1.0000 1.0000 Use Multi.plier & 

### Dilution Factor with ISTDs Signal l: 

### ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount 

### Grp Name

[m.in 

### I [uS/em* s] [ug/mL] 

## -------]------]----------]----------]----------l--l------------------ 4.156 Chloride Totals : 0.00000 1 Warnings or Errors VJarning : Calibrated compound ( s) 

### not found ==========:=======================.,.,===.. **,=================-·""'""'="'-'====~======== =====::..~==''"'===-===,=====~==:::================·====:=-:;:.:"'-'=====:====================**  

### Area Percent Report ========================""-""""==============================="'-'=""·'""'======= 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs
IGG EA# 0910-96 Page 106 of202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI?iifile433 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\051-6402.D Sample Name: P5 R3 out B *10 0910-96 BORALBRICKS

**=============================~=======================================** 

### Acq. Operator EO Seq. Line 64 Acq. Instrument Mr Burns Locatton Injection Date 10/2/2010 11:14:17 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \!JPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last chanaed 10/4/2010 9:33:01 AH by IGG

**--~---~** .. A£)C1 A. ADC1 CHANNEL A (U:\HPLC2010Q4\MR 8URNS\OATA\OCT\HPLC53PG98\051-6402.D) 

### uS/em 

# l

180 

# l 160 

### "1 140



# ~ 120 

# ·j 100



### ~



# 80~ 

# 60:1 40 

# 1 I I 

# I I I 0 gj 

### of

!

# \ 1 v 

### "'*" 

# 2:



# L_;_~~~~;:- _c·

# ~~-=~::::::;=~:;·=:::;:l=r==~::;:::c:;==r==::::;:::!.:_:;::.::.,.::C::::;:==::;:=::;::=;~::j 2 4 

## ' ;:; I 

# \ 0 

### I ,.: 

### . _ 

### _; '

**~** 

### ---r--- 

### - -----------"'--------"-------"'------"---------' 6 8 10

**====================================================~=~========~=====**


### Sorted 

### By Calib. Data Modified Multiplier Dilution External Standard Report Signal 10/4/2010 9:32:52 

### AM 1.0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTOs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area ./\mount Grp Name

[min] [uS/cm*s) [ug/rnL) 

## -------l------l----------1----------l----------l--l------------------ 4.156 

### Chloride Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound(s) not found

**=,;:=o:=c===========-~~o-=:c..c=~"'="'o=,.==="'-"'"'========================================** 

### Area Percent Report

**=::================================================:::"====='"-~======""======** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:32:52 AM 1. 

## oooo l. 

### 0000 

### Use Multiplier & 

### Dilution Fact_or with ISTDs

**IGGEFW-\d!FOi111!0,91iJ~'iWOJE?;if2** 

### AUGUST A PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 201 0 **1~----** mi.



### APPENDIX

**PAGp~<J'e434** 

### l of 

# z

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\052-6701.D Sample Name: Acid Blank 

## * 10 0910-96 BORAL BRICKS

**~====================================================================** 

### Acq. Operator EO Seq. Line 67 

### Acq. Instrument Mr Burns Location Injection Date 10/3/2010 12:21:26 AM 

### Inj 1 Acq. Method C: 

### \HPLC2010Q3\MR BURNS\METIIODS\METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:39:38 AM by IGG



### ·-

**~~-"1\D-ci** A, AtliT c HANNELA(u:IHPLC2o1 oa41MR siJRN-siDAl'i\iocTIHPLc53PG9alo52-6701.DI



# "~:]_

**160~**

**140~** 120 

### j

# 1 100-1



# 80~ aoJ 1 40 

### _:j j 

# I 20 i



## ~ **~ ~**  **~ ~**  ,1 

# l C\i (") '<ttrl co Q

**-+~~~~---:-~___:_;::=-·** 1

**-=~,;_:** 

### __**:_:___,__i__~,:_-· ~,** 

### -· . 

### .:.::;_:.-:.=-::::;::.- ...-__;_---;:·-:_::··:_:'·:;:-:::_:+'

**·='"~~T, ~~~~~~,.-~_J**  L------···------l_ _______ ,___

### ~ ________

### 1_____________ 6 ·····---··?.· .......

### ~-----------lQ__ 12 

## mid

**===================================================================~=** 

### External Standard Report

**==============================~===·~======~===========================** 

### Sorted By Calib. 

### Data Modified Multiplier Dilution Signal 

### 10/4/2010 9:36:48 AM 1. 

### 0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] 

### (uS/cm*s] [ug/rnL] 

## -------!------!----------!----------l----------1--l------------------ 3.168 BB 8.45559e-l 1.62975e-2 1.37805e-2 Fluoride 4.156 Chloride Totals : l.37805e-2
1 

### Warnings or Errors Warning : 

### Calibrated

**co~pound(s)** 

### not found

**==============================================~;-~''""-"===:.o:~~====--====:o:=====** 

### *** End of Report ***



### InstrurnentAIC:f'~P4~Ql)!l!g. **fHQ1~~:** 59 AM



### IGGEp/j(~fl;~~~~ 

# 1JilbS&t?2 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGiplll<je-435 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\052-6702.D Sample Name: Acid Blank *10 0910-96 BORAL BRICKS 

### Acq. Operator EO Seq. Line 67 

### Acq. Instrument Mr Burns Location Injection Date 10/3/2010 12:33:46 AM 

### Inj 2 

### Acq. Method C:\HPLC201DQ3\MR BURNS\METHODS\METROHM.M 

### Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC20 1 OQ3\MR BURNS\METHODS \HP!,C53 PG 

### 98. M Last changed 10/4/2010 9:39:38 AM by IGG ADC1 A. ADC1 CHANNEL A (U:IHPLC2010Q4iMR.. iiUR"NSIDATA\0CT\HPLC5:lPG.iiii\o"'s"2"-6"7"'D"z.ro") ------, uS/em 

# l

180 

### -1 i 160-1 

## ' :j 140 

## "1 120 

# 1**100~** I I**~--** 

# I soc' 

# l
.. 40 T""" I() 0) .- II 20-**~ ~** **~ ~** 

0

# -11-···_·_···,;·'-_·~--**'r-~, --~,-------~r··_···_·"~-.i-**  ·

# :L:~-tl() ---.-------.-----,- T..

# ---,,-~-~~-~~---l' 2 c.4______ 6,_'

### --------·----~-------~------JQ_____ 12 

### mid**=~"'=======,=================================="""""'"-~~===============:::"""====** 

### External Standard Report Sorted 

### By Signal Calib. Data t1odified 10/4/2010 9:36:48 AM Multiplier 1.0000 

### Dilution 1.0000 Use Multiplier & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime 

### Type Area 

### Amt/JI..rea Arnount Grp Name

[min) [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.121 Fluoride 4.156 Chloride 

### Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound(s) not found 

### ========""'-'-=======================::.""""'==""'========:=:o=====::::===::::===::c-"""""'·-::===**=======================::::c~==~========================="'-''"'=:,~:::.,~-=========::::=** 

### Area Percent Report**==========================================="-~========== "-'===-~-===========**  Sorted By Calib. Data Modified 

### Mul tipl.i.er Dilut_ion 

### Signal 10/4/2010 9:36:48**~~** 

### 1.0000 l.. 

### 0000 Use 

### rvlul tiplier & Dilution 

### Factor with ISTDs 

### Instrument N"'rcl>m'<rt:Citlrib.

## I>Qo~4l2: 30 AM IGG

## E$i'**~S~Lqs~~o~'f~~T B~6'JE1;~** **2** AUGUSTA PlANTS 4 & 5, SALISBURY PlANT 6 SEPTEMBER 2010 APPENDIX**PA~** 436 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\053-6601.D Sample Name: Base Blank *10 0910-96 BORAL BRICKS

**==============================~=========~==~=========================** 

### Acq. Operator EO Seq. Line 

### 68 

### Acq. Instrument Mr Burns Location Injection Date 10/3/2010 12:45:35 AM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG96CL.M Last changed 10/4/2010 9:33:01 AM by 

### IGG

**~-·--·-·---AbcrA·,** ADC1 CHANNEL A (U:\HPLC2010Q4\MR 

### BURNS\DATA\bCT\HPLC53'PG98\053:6861X5f

**·------------~**

uS/em 

## ·j

1801

**160~** j 

# 1401 120 

# j ·I 100 -; 

# ! 

# "

**~**



# I

===================================================================== External Standard Report

**======================================="="""~=======,====::"""==============** 

### Sorted By Signal 

### Calib. Data Modified 

### 10/4/2010 9:32:52 AM Multiplier 

### 1.0000 Dilution 1.0000 Use Multiplier & 

### Dilution Factor 

### with 

### ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount 

### Grp Name

[min] 

### [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------1--l------------------ 4.2.37 BB 

### 6.20201e-1 3.78526e-2 2.34762e-2 Chloride 

### Totals : 2.34762e-2
====="" 

### ===o:= ;o: =="" ===== ===""""' = = = = == == === = = 

### ===-=- """"' ,_,= = 

### == = =="'==,·= === ==-=-=======""' 

### *** End of Report 

### ***

IGG EA# 0910-96 Page 110 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~4lbe437 1 of l

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\053-6802.D Sample Name: Base Blank *10 0910-96 BORALBRICKS 

### Acq. Operator EO Seq. Line 68 

### Acq. Instrument Mr Burns Location Injection Date 10/3/2010 1:02:52 AM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98CL.M Last changed 10/1/2010 9:33:01 AM by IGG


### ,. ···-----i\I5cTA. ADC1CHANNE'L"A (U:IHPiX:2oToa4iMR BURNS\"D;,A""T A"I"D:rc"'T"IH"P"L"C"'5'"3P'-G'-'9"B"'Io"s"'3-"B"B0'"2'.o"").-------,



# ~ ' i

External Standard Report

**============~===========~=================================~==========** 

### Sorted By 

### Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 9:32:52 AM 1. 

### 0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/ml,] 

## -------l------1··--------l----------l----------l--l-------·---------· 4.238 BB 6.09262e-l 3.78526e-2 2.30621e-2 Chloride Totals : 2.30621e-2
*** End of Report 

### ***



### InstrumentAICf!JlP4~'2ol:Je IHQ1t14: 58 AM



### IGGE~~~tf~PRb9&e92 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGJP!i'~e438** 1 

### of 1Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\054-6901.D Sample Name: DI H20 blank 0910-96 BORAL BRICKS

**===================~===============~==============~==================** 

### Acq. Operator EO Seq. Line 69 Acq. Instrument Mr Burns Location Injection Date 10/3/2010 1:20:42 AM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:39:38 AM by IGG

.. --- ADC1 A, ADC1 CHANNEL A (U:IHPLC2010Q4\MR 

### -BURN'T,S~I;<D';;-AT"'A'-I"'O"'C"TI""H"'P"L"C~53"P"G"'9"'8"'1054-6901.D)"·------------ uSicm 

# l

180 

### ··1 

## ' i 160 _j 140



# ~ 120--3 j 100-1 

# ::j

**~** ·c 0 

### :c (.) 

### 8l 

### I 20l j 

# l ....

**--~~-** j ____ _ **~** i 

# --,--
**:::..,:=:;=:::;:::==~----,** 

# ·r---,-----!

__ .c4.___ _________ 

### s_____________ a. --------'1"'o __________ **1_~-----·_rnL".** 

### =================;:..:.=================:;:::-=-==============:-================== External Standard Report
**==========================~===========-=====================""=========** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 1.0000 

### 1. 0000 

### Use Multiplier 

### & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area

**~~t/Area** 

### Amount Grp Name

[min] 

### [uS/crn*s] [ug/mLJ 

## -------l------l----------l----------l----------l--1------------------ 3.121 Fluoride 4.286 VB 2.98664 3.78526e-2 1.13052e-l Chloride 

### TotaJ.s : 1.l3052e-1 

### 1 Warnings 

### or Errors Warning : Calibrated compound{s) not found ==="'-'=======:==============·"-""==::===================='============::::.·>======= 

## *** End of 

### Report 

## ***

EA# 0910-96 Page 112 of 202 Instrument MCWdJ!o:CEf:t-Jb.



### ~-qa1J.ii!: 32 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI!<t00439 1 of 1Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\054-6902.D Sample Name: DI H20 blank 0910-96 BORAL BRICKS 

### ==============================================-======================= Acq. Operator EO Seq. Line 69 

### Acq. Instrument Mr Burns Location Injection Date 10/3/2010 1:33:02 AM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changea 10/4/2010 9:39:38 AM by IGG 

### r----·--·--------ADC-1 A. ADC1 CHANNEL A **(U:\HPLC2010Q4\MR.ff(j';;R;:-;NS"-\i'>D';;-AT"'A'-\O"crcnnc;HP""L"C'5'3PG98\0-54-_-6902-.0)-~----** 

# I 

# us::: i_l 1601 140l 1201 100 l 

## 80-1 

# 60J 1 40 

## -J 1

**~** 20



### -~ **~** 

# €i :;; a:l



### ~ r 

### J NN



### ~ **~** 

# ci ', 0-±-=-' -i- ___,_j_____

### -+- r----·--- -------, 

### +---- t t .........

### ------,-----..,.-----·-r·-
**-.,..-----r---,----.-----~-,--~---1** [__________________ ?______ 4 _______

### !;___________ ------"'8 _______ 10 ---------- ___ 

### 1~--- m1J



### Sorted By Calib. 

### Data Modified External Standard Report Signal 10/4/2010 

### 1. 0000 9:36:48 AM 

### Multiplier 

### Dilution 

### Use Multiplier & 1.0000 

### Dilution Factor with 

### !STDs Signal 1: ADC1 A, ADCl CHANNEL A 

### Ret'I'ime Type 

### Area Amt/Area Amount Grp 

### Name

(min] 

### [uS/crn*s} [ug/rnL] 

## -------l------l----------l----------l----------l--l------------------ 3.121 

### Fluoride 4.288 VB 1.15224 3.78526e-2 4.36153e-2 Chloride 

### Totals : 4.36153e-2 1 

### warnings or 

### Errors Warnj.ng : Calibrated compound(s) not found 

### =========·====================o:::o:::===========;..:============co;;,=:============= *** End of 

### Report 

### ***

EA#0910-96 Page 113of202 Instrument NTciliJRdJAAlJ4b. 

## pO,uq.f;.: 41 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAQ!;;jgo: 440 l of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\008-0901.D Sample Name: 0. 01N H2S04/NaOH RB BORAL BRICKS 

## =====:================================================================ Acq. Operator Acq. Instrument 

### Injection Date Acq. Method Last changed Analysis Method Last changed EO 

### Seq. Line Mr Burns Location 10/1/2010 9:02:21 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG 

### (modified after loading) 9 

### 1

r-----,A:ro"'c"'1'A'. "A"'o;c1 cRANNETA(u:\HPCc251 oo4iMRiiliRiJS\5P:tA\o·cnRPl.i5":iPG9Biooa.osoC6)-
- ----- uS/em**~**



### 180

### ~ 160 140- 120- 

### 100



### External Standard Report ==========""'========================================,==========="'-====""' 

### Sorted By Calib. Data Modified 

### Multiplier Dilution Signal 10/4/2010 9:26:06 AM 1.0000 l. 

### 0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area**F~ount** 

### Grp Name

[minj [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.147 Fluoride 4.156 Chloride Totals : 0.00000 

### 1 

### Warnings 

### or Errors Warning : 

### Calibrated compound{s) not found

### InstrumentAICfflfl!l~\llitl9·**f?rlil1~?28** AM IGG

### E~~rJil$-~fb~~t>"\fu9~t9**2** 

### AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGp'*J 6 

### 441 1 of 2Oa ta .t''lle U: \ti.t' LCLV 1 U\J!! \MK .!:5UKN::i \IJATA \UCT

**\til:'Lt..,.:=;.jl:'J,;,~tl** \UUtl-U

**~UL.** IJ 

### Sample Name: O.OlN H2S04/Na0H RB BORAL BRICKS 

### ===================================================================== Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analys.is Method Last changed EO Seq. Line Mr Burns Location 10/1/2010 9:14:41 PM Inj C: \HPLC2010Q3 \MR BURNS\METHODS

**\~lETROHr1.** 

### M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by 

### IGG (modified after loading) 9 

### 2



### --------AoCfA-;--ADC1 CHANNEL A **(U:\HPLC2Cdoo4iJJFfBDRNS\DATA\OCT\HPLC53PG98\008~(j962~!5}---··-----·--··j**



### uS/em-~ 

### j

**~** 

### : 

# ;::



# ~ ! q 140-1 1201 

# 1:: -j 

# 601 40] 

# 201

**~** 

# ! ···-----------...1 ___/_



## o
**-1==·-:_r~-~=-~-=.c.-.-:::_-~·:::.::-:.:::;:==;:=:;::::=;:::'.::;:":.=o::,;::.:::** 

## ..

:::::;:=
. -----r·-·-- ...,-·---·,-------,---,--------,-----·

**---·-------~1c.__________** 4 6 _________ 8 __________ 10

**==~=====:~~===============~===========================================** 

### External Standard Report 

### :=:-=::::·=======================""'==""============--"=========================== Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:26:06 AM 1. 

### 0000 1. 

### 0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area

**P~ount** 

### Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------i----------l----------l--l------------------ 3.147 Fluoride 4.156 Chloride Totals : 0.00000
1 

### Warnings or Errors Warning : Calibrated compound{s) not found 

### ====================="'·""'==============="""============""="""==============o.c;c.:.

IGG 

### EA# 091 0-96 Page 115 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### g _____ mi

APPENDIX

**PA~e442** 1 of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\008-320l.D Sample Name: O.OlN H2S04/NaOH RB BORAL BRICKS**===========================================~===~=====================** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last ehanged 

### EO Seq. Line Mr Burns Location 10/2/2010 7:58:59 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U: \HPLC2010Q3\MR BURNS\METHODS \HPl.C53PG98. M 10/4/2010 9:26:06 AM by 

### IGG (modif.ied after loading) 32 

### 1**····~·~;c~-lADCTAJii)i'TCHANNEL** A (U:IHPLC2010Q4\MR**BURNSIDATAIOCT\HPLC53PGii~668-3ioi:of·-·-------··----·-----~** 

# 'oo1 • & 

# I 160

# -~ 

# i 

# l 

# ;:: J : i ' 100-j 

## ., 80 

## J 60 

## -i " 40 

### .j

# 20~**~ ~** **~N ;::========~===;==~--~~~~~=============** 

0**---1-~--~------,~** ----··,--·---r ·r··-----· ' L_
__________ ?.____ 4 6 ______________§____



### Sorted By Calib. Data Modified 

### I-1ul tiplier External Standard Report Signal 10/4/2010 9:29:44 AM 

### 1.0000 

### Dilution 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL 

### A RetTime Type 

### Area Amt/Area Amount Grp 

### Name

[min] [uS/cm*s] [ug/mL] 

## -------l------!----------j----------!----------l--l------------------ 3.147 Fluoride 4.156 Chloride Totals : 0.00000 1 Warnings or Errors Warning : 

### Calibrat_ed compound(::>) not. found

## InstrumentAICPIJlP:)gGrD~6 F'f10'1'JZ54 AM 

### IGG

## EP~~RO~J&~~~JfR~**j,'),~9~t9 2**  AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGIP11Jge443 1 

### of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\008-3202.D Sample Name: O.OlN H2S04/NaOH RB BORALBRICKS

**===============================;==================~==================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Anal.ysis Method 

### Last changed EO 

### Seq. Line 

### Mr_Burns Location 10/2/2010 8:11:19 AM 

### Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC20l0Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG 

### (modified after loading) 32 2

**r-----------ADC1A~Ai5CT** 

### CHANNELA(U:IHPLC26Too4\MRBURNSIDATAIOCTIHPLC53PG981008-3202.D) 

# I

**~~m1 ~,** 

- 180 

# l - 160 

## --i 140

# J I



# 120~ Ill 100 

# i 80 

## -j \

**60~**



# ::~ **~ ~**  -1 N __J 

### .n o
**-~=::;=:=.;=:::;:=::;=::::** 

### r **-----.--..!.:r-----,--=~::,~.::~~.:.:~--** 

### --**-~--,-----'-cc_:__c;...**

### __ **~--~-~-----1** ···-·-----···-··__1 _________________ ___1___________________ **~----------------8** 

### _________, __________2_Q _____________ 

### _1L_Jl!L

**==""='""~=========""======oc:==:e-..:o~=~'='"-"='-"==="==============================e:=====** 

### External Standard Report ============"-'===·================================================,.==== 

### Sorted By 

### Calib. Data Hodified Multiplier Dilution Signal 10/4/2010 9:29:44 AM 

### 1. 0000 

### 1. 0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1; ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL} 

## -------l------l----------l----------l----------l--!------------------ 3.147 Fluoride 4.156 Chloride Totals : 0.00000 

### 1 Warnings or Errors Warning : Calibrated compound{s) not found

**==========================================::::================'-'""'""=~··==:o-..:===**



### InstrurnentAICf/1P<I~©ljljJg.Rj1QII6<o3 AM 

### IGG 

### Ef'ii.~f$-~Jf~lo"\?o9&e)l2 AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGp)lJ~e444** 

### 1 of 2

### Data File U: \HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\103-5601. D Sample Name: 0.01N H2S04/NaOH RB BORAL BRICKS **================================~====================================** 

### Acq. Operator EO 

### Seq. Line 56 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 6:50:32 PM Inj 

### 1 Acq. Method C:

**\HPLC2010Q3\~IR** 

### BURNS\METHODS\METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis

**~1ethod** U: 

### \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98 .M J"ast changed : 10/4/2010 9:39:38 AM 

### by IGG Ai5c1A:-!iocTd=iANNEL ii(U:\FfPLc2o1o641MlHiV"R"'N"s''"o"A"T"A'"o"c"n"H"'P'"L"c"'s"3""P<i9-Bii-oa:setTb)

-- 

### ------------~ 

# uS:::j

140-J I 120 ] 

# " 100 

### -j 

# 801 60 

### Cl



# ~~ I



# 20~ §



# ~ 

# i I

0

**-t~--- T~-**  **~~~~~-** ..... 1.' 

## :;=::::::;=:;::=;=::;::=c::=.""-·------J I 2


# -~-r~=~~-----:~----------~**-~-----** 

# ..------____ "'8_____ 

# ~_-'1"'';;''-------~-===-=-~----~-s-~_::~~d **==========================~==========================================** 

### External Standard Report 

### ====-==::==============================""======================-··==::======== Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 1.0000 1,0000 9:36:48 Al'1 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl 

### A, ADCl CHANNEL A 

### Ret'!'ime Type Area Amt/Area Amount Grp Name

[minJ [uS/cm*sJ (ug/mL] 

## -------l------l----------l----------l----------l--i------------------ 3.121 Fluoride 4. 

### 156 

### Chloride Totals : 0.00000 1 

### Warnings or Errors Warning : Calibrated compound(s) not found
**="""=====,=======~=:'Oc·:,::o"=·~""==============""=====""''"'==oc=======:.=====c===,-;;======""== =================================""===oO'oo===============.==~=============**  

### Area Percent Report 

### ====================·.::.<::c-====""=============oo:=.""''-"'=================""====""""= Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 1.0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Instrument 

# kc¥\16.@!1-Wo. M\o94i 32 AM 

### . EA# 0910-96 Page 118 of 202 IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0 APPENDIX

**PA~** 445 1 

### of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\103-5602.D Sample Name: O.OlN H2S04/NaOH RB BORAL BRICKS
**========~=======================~~===================================** 

### Acq. Operator EO Seq. Line 56 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 7:02:52 PM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\MET!!ODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method 0; 

### \HPLC2010Q3\MR BURNS\METHODS\HPI,C53PG98 .M Last changed 10/4/2010.9:39:38 AM by IGG



### - -------AOC-1 A, ADC1 CHANNEL-A(0:\HPLC201004\MR BURNS\DATA\i5CTiHPlC-53PG98\103-5602.D) uS/em l



### 180 

## j ; 160 

# 3 j 

### 140jl



## 120~ 100 

# J 80



# -~ **~** 

# 1



# ::LI



# ~................ . .!
. o



### -~ ··-··;·----·1-------.---
..



### ---- **-==::;c.=;:::::~..'-";=:=;:;:::::;::::=** ·r··----.,.......



### ·----~. **~---,.-~-~-~~-~·** ,------

__ 2 __ **-~-------j** __ _ 6 ______IL____________.... 

### JQ. 12 mi

**=====·===""=""=~'"-'"'"===============::"===================="''===========,;::=:::===** 

### External Standard Report **====~===========~====================~===============================** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 

### 1.0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 

### 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area 

### A.t-uount Grp Name

[min] [uS/cm*s) [ug/mLJ 

### -------l------l----------j----------j----------1--l------------------ 3.121 Fluoride 4.10>6 

### Chloride Totals : 0.00000 

### 1 

### Warnjngs or Errors Warning : Calibrated compound(s) not found

**=======================~~=="''·'""-"-"============="-'""===============o-.:oo:•=::--.c,===== ====================·==~""=========="'=""~"==================o.~'"'"~===========**  

### Area Percent Report **='""====================""="-'""'="-'=================""""""-''"'===""=====oo-"~==='"'=====** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 1.0000 1.0000 

### Use Mtlltiplier & Dilution Factor 

### with ISTDs Instrument 

## AlfcWo.ft'tl!% 

## ibf\o94J2: 41 AM rGG



# E~~~~~~~s~~o~mT **1**



# ~~J'JE~~ **2** 

### AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 

### 2010 APPENDIX PAGE'-.446 1 of 2

### Data File U: \HPLC2010Q4\MR BURNS\DATA\0CT\HP!,C53PG100\008-0901. D 

### Sample Name: 

### O.OlN H2S04/Na0H RB BORAL BRICKS 

## ================================,=========""=======================""== Acq. Operator 

### Acq. Inst.rument Injection Date 

### Acq. Method 

### Last changed Analysis Method 

### Last. changed EO 

### Seq. Line 

### Mi Burns Location 10/4/2010 5:15:07 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/I/2010 4:15:36 PM U: \HPLC2 01 OQ3 

### \t1R BURNS \METHODS\HPLC53PG1 00. M 10/5/2010 9:18:49 

### AM by IGG 

### (modified after .loading) 9 1

**~---** ------A5C1 "A-.A""D"c"1"C"'HP:NNE'C A (U:IHPLC201 004IMR BURNSIDATAiOCTIHP'C<;53PG 1'"o"ol"'o"'o8"·"o9"'0"1".D'-)--------------- .. uS/em 

# j

180 j 1 160 -] 140 .. 120 100 . 80 

## eoJ 

# 1 40 

# ·jl 1.() 20



## -~ **~ ~**  

# ,, f( 

# \I li 

# ,, \I 

# " i' 

# I_ 0


### -l=-·;-'-~--- **r·---=--~:::_:_·:-=::;::::.=.**

## =;:,**==;:::::::=:;::::'.·'::'"'~-** 

## -. ':.·.:;::_.. -.---·· **·--~------,--~~~:1**

__ 2,_ _____________________ -"--4

### --------------~---------- -----"8'-- _________________J!'!!j **:::::::::::c..cc""==========="-~=============================='""==============~-"'''=======** 

### External Standard Report 

### ============>====================================="===========·""'======== Sorted By Calib. Data Modified Signal 10/5/2010 1.0000 9:21:11 AM 

### Multiplier Dilution Use 

### Hultiplier 

### & 1.0000 

### Dilution Factor with ISTDs Signal l; ADCl A, ADCl CHANNEL A RetTime Type Area
**k~t/Area** 

### Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------[----------[------------l--)--------------------- 3.149 Fluoride 

### 4.153 Chloride Totals : 0.00000
1 

### Warnings or Errors Warning : Calibrated compound(s) not found **=======•"'=->=====o.o·=====================================·o-o":O;=========="-~"'-===**



### InstrumentAl:C


## !'BP61i'Qll~O- F'.J1<lll!2 57 AM IGG 

## EP~~ROJlJ/I;ilBlf!&'t **~~'b~U? 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAG!!'IHJ."147 1 of 2

### ua1:a n1e u: \li±' LCLU 1 U\.H 

### \Ml< BURNS\DATA \OCT\HPLC53PG1 00\008-0902. D Sample Name: 0.01N H2S04/Na0H RB 

### Acq. Operator Acq. Instrument 

### Injection Date Acq. Method Last changed Analysis Method Last changed BORAL BRICKS 

### EO Seq. Line Mr Burns Location 10/4/2010 

### 5:27:28 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by 

### IGG (modified after loading) 9 

### 2

ADC1 A.**ADCTCHANNEL-·A[O~iHPLC2010041MR** BURNS\b7\TAI6cnRPLC53PG100I008-o9ci'2:-oj'·----- ----··· uS/em 

# l**180~**

160 

# j

# '

# 140~ 1 1 12oj 

## 1, 

# 1 

# :1 100-j 

## \i 1 

# ll eo 

# J , 1 

### i 

# 60i ,, 

# I

# ~ -1:1-=-=:;c,=-"

# :::-~':::- -:.·

# =---=--=--=-=:::~=c;=--~-**~ ~** **cc~ ~~,=~**  "c J

# ~ ; 

## L___ _ 2 __________ 4_ ___ ----"-6 ---------·--------- __ 

## e 00 '
____________ ;] 

### External Standard Report 

## ===================================================================== Sorted 

### By Calib. Data Modified Multiplier 

### Dilution Signal 10/5/2010 1.0000 1.0000 9:21:11 AM 

### Use Multiplier & Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNEL A 

### RetTime Type Area**~~t/Area** 

### Amount Grp Name

[min] 

### [uS/cm*s) [ug/mL] 

## -------l------!----------!----------f----------t--l------------------ 3.149 

### Fluoride 4.153 Chloride 

### Totals : 0.00000 

### 1 

### Warnings or Errors**~\'arning** 

### : Calibrated compound (s) not found**===:o=~-o:==o===:.o======================'"'"''""'"========·:::.;.-"::::===========,.·========~"**



### 01"/?0lO g 

## n 0 EA#0910-96 Page 

### 121 of202 Instrument AT2PR8JECTNo. 

## P:nn4z 5 

### AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

### PA~I-/8. 4481 

### of 2

### Data File U:\HPLC2010Q4\MR BURNS\DATA\0CT\HPLC53PG9B\010-110l.D Sample 

### Name: MS Salisbury Rl 

### In A *20 0910-9EiJORALBRICKS ====================================================="'"-'""'"'==========.::o==:.·= 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method 

### Last changed EO Seq. Line 

### Mr_Burns Location 10/1/2010 9:51:40 PM Inj C:\HPLC20lOQ3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U: \HPLC2 01 

### OQ3 \MR BURNS \f1ETHODS \HPLC53PG98. M 

### 10/4/2010 

### 9:26:06 AM 

### by IGG . 11 

### 1


### (modified after loading) **----·-"""'c=-.-..=o-='i:~~:.;:;:.~~~;.;:.;~~"""~="'"===""""~~~~----,** ADC1 A, ADC1 CHANNEL A (U:IHPLC201004\MR BURNS\DATA\OCT\HPLC53PG98\01 0-1101 D) uS/em 

# l

180

**-~** 160 

# cl 140



# ~ 120

# J 1::1·,
40--. 20-

**====================~==~=======~=======~==============================** 

### External Standard Report =========='=·=="""='""=====""===========>"'=================================== 

### sor.ted By Calib. Data 

### Modified Multiplier Dilution Signal 

### 10/4/2010 9:29:44 AM 1. 

### 0000 1. 

### 0000 Use Multiplier & 

### Dilution Factor wj_th lSTDs Signal 1: ADCl A, ADCl

**CHANNEI~** A 

### RetTime 

### Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/rnL] 

## -------l------l----------l----------l----------l--l------------------ 3.132 BV 663.60602 1.70817e-2 11.33552 Fluoride 4.254 VB 136.56146 2.67214e-2 3.64911 Chloride Totals : 14.98464

**============""~="~"'==,~="""~"==============================================** 

### *** End of Report 

### ***



### InstrumentAJ:Cfi19l41'~1i~e-19-1f!l16~40 AM 

### IGG

**E~llr~~tl!l3'r1*b9~~92** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGipll«je449 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\0l0-ll02.D Sample Name: MS Salisbury Rl In A *20 0910-96 BORAL BRICKS
**===========================================~=========================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method La.s t changed EO Seq. Line M;t' Burns Location 

### 10/1/201010:04:00 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG (modified after loading) 1l 2


### j ·---···..**·----··-Aocr-A~A-OC"f** CHAN-NEl-A (U:\HPLC201 

### 004\MR BURNS\DA

### T **A\0Cf\HPLC53PG9i~\0i0~-1102.())-~~----·---** J uS/em 

# I 180- 160 140 .



### External Standard Report **==========""="=~================,==================================""=====** Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Siqna1 

### 10/4/2010 9:29:44 AM 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min} 

### [uS/cm*sJ [ug/mLJ 

## -------l------l----------j----------l----------l--l------------------ 3.131 BV 661.14001 1.70817e-2 11.29336 Fluoride 4.253 VB 136.65158 2.67211e-2 3.65148 Chloride Totals : 14.94484 

### *** End of Report 

### ***

I GG EA# 0910-96 Page 

### 123 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAGif~IJ.'l,so 1 of 1

### Data File U:\HPLC2010Q4\HR BURNS\DATA\0CT\HPLC53PG98\0ll-120l.D Sample Name: MSD Salisbury Rl In A *20 0910-9EfoRAL BRICKS

**======================================================~==============** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analysis Method 

### Last changed EO 

### Seq. Line 

### Mr Burns Location 10/1/2010 10:16:20 PM Inj C:\HPLC2010Q3\HR BURNS\METHODS\METROHM.H 4/1/2010 4:15:36 PM U:\HPLC2010Q3\HR BURNS\fffiTH0DS\HPLC53PG98.H 10/4/2010 9:26:06 AM by 

### IGG . 12 1


### (modified after loading) 

# i

-

**-:~=~** 

# i ADC1 A-, A"D"'c=1'c,CHT;AC<NT.N;E;,:L7\ (Li.\HPLC201004\MR BURNS\DATA\OCT\HPLC53PG98\0n 

### -120Tt5f-- ---- -

# --l

' 180 

# ' 

# i 1sol I 140 

## •j : 1201



# ~ 1 J 

## &: I 

# ::L:J

r )



# ~~f'~" _3



# ~-~~-+1- ...



# ~.L **L--,-------~~** ;·--- l...._____________ 2 _____ _1:_____________________ 6 8

**--~------_1_0_______** 12 mir! 

### External Standard Report
**===,.-,:=:::o===============;======="'="'=""=""'==========~o=-.o===o::r==""'============<'~====** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:29:44 AM 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area

**~~t/Area** 

### Amount Grp Name

[min) [uS/cm·-"s] [ug/mL] 

## -------l------l----------j----------!----------l--1------------------ 3.131 BV 626.82330 1.70808e-2 10.70667 Fluoride 4.255 VB 129.13361 2.67472e-2 3.45396 Chloride Totals : 14.16063

**"''o::===========:oc~-==========""-~'================:::================::o=========** 

## *** End of Report 

## ***

InstrumentAllC



## ~B(I)JI;il7llfl0l Pl1:am 

### 01 AM IGG



## EP~1l;#RQEgJI~s~8N~'lil;t **~~MJ.?P 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~~O!OI51** 1 of 1

## ( Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\011-1202.D Sample Name: MSD Salisbury R1 In A *20**0910-'~JfbRALBRICKS** 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed 

### ED Seq. Line 

### Mr Burns Location 10/1/2010 10:28:39 PM Inj C:\HPLC20l0Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG (modified after loading) 

### 12 2


# r·------- -ADC1A;7\DCTCHANNECA (U:IHPLC201 OQ41MR**BURNSil5AtAi6cnHPLC53PG98ioTi~i2oi:"5j···-·· ======-=======~~====================,,==================================**  

### External Standard Report**,..=========""'""'==========================::.:o=~:c=============""·==>'c=:===========** 

### Sorted 

### By Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 9:29:44 

### AM 1. 

### 0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area**~mt/Area** 

### Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.132 BV 

### 629.07855 1.70809e-2 10.74523 Fluoride 4.256 VB 128.93863 2.67479e-2 3.44883 Chloride Totals : 

### 14.19406**===:::===============~·================o•=============================,==·~******~** 

### End of Report 

### ***

Instrument

## Alrc~M>.**~-1iltl216** AM IGG

## EPIJ,~~rP~~?s~~o~~~~T**~~o M:If**  AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGEiNle452 l of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\027-3401.D Sample Name: MS P4 R1 In A 

### *10 0910-96 BORAL BRICKS

**===~==============~===~=============~================~===============** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysi.s Method 

### Last changed EO Seq. Line 

### Mr_Burns Location 10/2/2010 8:48:18 AM Inj C:\HPLC2010Q3\MR

**BURNS\METHODS\METRO~M.M** 

### 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by IGG {modified after loading) 

### 34 1

**~----------------:o:DC1**

### ..**A~AocTC}-IANNEL** 

### A.

**(U:YHPLC201004\MR8URNS\0ATA\OC-f\HPLC53PG~f8\027 -3401Df~**  

### -·-·-··---··· ..·-·- uS/em



### 180 160 140- 120 

# " 100- 

# :g

**~** 

### 80 

### u: 

## " 

# "' "' 0 

### 60 N :2

**~** 0 

# "'

===================================================================== External Standard Report

**=====~====================================================~==========** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:36:48 AM 1.0000 1.0000 Use Multip.lier & 

### Dilution Factor with 

### ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------!----------j----------l----------l--!------------------ 3.125 BB 406.57947 1.70724e-2 6.94127 Fluoride 4.259 

### BB 113.87910 2.68106e-2 3.05317 Chloride Totals : 9.99444

**=~=~====================================~============================** 

## *** End of Report 

### ***

Instrument



### AfC:flWlll)i'§~:t\9 **19-!~1Jii1o6** AM IGG



### E~/Ml~i!,\l;§lbifi'@S'r1AAB~e't2 AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 

## SEPTEMBER 2010 APPENDIX

**PAGp~e453** 

### 1 of 

### 1

## ( Data File**U:\HPLC2010Q4\V~** 

### BURNS\DATA\OCT\HPLC53PG98\027-3402.D Sample Name: MS P4 Rl In A *10 0910-96 Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed 

### Analysis Method Last changed BORAL BRICKS 

### EO Seq. Line Mr Burns Location 

### 10/2/2010 9:00:38 AM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM lJ:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by IGG (modified after loading) 

### 34 2

ADC1 A. Aocrc"HA"NNE'U\(i:i'\iiPLC2o100-4iMRBUR-NS\DATA\OCTIHPLC-53i'G98\627=34o2.D}____ uS/em 

# l

180**~** 

# ' 160 

# J j 140 

## :i 

## ' 120J 

# 3 100--1 J 80

### ~ 

## "

# 60~**~** 

# 40J A i II Ng 

## i 

# j'\ ...: ;;f);!

### ~o m

# 20-~1**~** i (..

# ~**~ ~**  r..: :**~------J..-~** ,., ____ ,)

__ _ \_
____, .. ,.,_..;_ .''"-,--.J**~! -~-~-**  1-""--...--**r--'·-"""'"~--** ,- 0 ...... ----,-------.----,**-----,-----~~--.---,-----,---..,...---.,.--~-.-~-~-~-,----1**

______**__g--------------~-------·····--** ..**-------·-··-~-------------** __ .'?.8______ 1'.Co,_ ____ __,1_,2_-"m'"'; ·**=-==========================~-o=::::=======================================** External Standard Report 

## ===========================,========""'""============================="""= Sorted By Calib. Data Modified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1.0000 

### 9:36:48 AM Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] 

### [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.125 BB 406.89011 1.70724e-2 6.94659 Fluoride 4.260 

### BB 114.10727 2.68095e-2 3.05916 Chloride Totals : 

### 10.00575**=·"=·~===========""·""''"""'""'=="==============================================o:o=<".::= i End of Report** *~*****~** 

### 1.ru• L2m.n

_ 9

### 7 1 EA# 

### 091 0·96 

### Page 127 

### of 202 InstrumentAtC"PRU:!Et:rNO.I'-i01<Z 4 

### AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGfWi 8 454 

### 1 of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\028-3501.D Sample Name: MSD P4 Rl In A *10 0910-96 BORAL BRICKS

**===========~=========================================================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/2/2010 9:12:58 At1 Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 

### PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by IGG 

### (modified after loading) 35 1 

# f

----------- _ ADC-fA--;-Ar5C1cHAN NEI1\(U:\-HPLCi6"1'"664\MR-8URNS\i)Al-:.A\ocT\HPLC53P,G98\028=35{Ff.b')··- ···--- ! uS/em

**~** 

### j il



## 180~ 

# i ·I ,

. 160

**~** 

# 1 

# I i

**·····--..,.-·--·-~--·.-··** 

### =====·.:::c"'"=============================================:o=================
Sorted 

### By Calib. Data Modified Multiplier Dilution External Standard Report Signal 10/4/2010 1.0000 1.0000 9:36:48 AM Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTj_me Type Area

**l~mt/Area** Amount 

### Grp Na.-ne



### [min] [uS/cm·lrs] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.126 

### BB 408.43451 1.70725e-2 6.97299 Fluoride 4.260 

### BB 114.63012 2.68071e-2 3.07290 Chloride Totals : 10.04589 ="''==="''=""==========================""========="'-================.:===""=== 

### *** End of Report 

### ***

Instrument



## AtCW<bl!Et~Ml.l<-~il1"74222 AM 'rGG



## EP'¥)~RO~~?s~itJ'f'~gT **~o~k~~z** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 12 mi

APPENDIX PAGE<me455 1 Of 1

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\028-3502.D Sample Na/(le: MSD P4 R1 In A *10 0910-96 BORALBRICKS**=================================================~===================** Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method Last changed 

### Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 

### 10/2/2010 9:25:18 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:36:41 AM by 

### IGG 35 2
{modified after loading) 

### r----------ADC17\.-ADC1CHANNEL A (UTHPLC20io64iivfR BU_R,NS"'I"'D"A"T'AI"'o"c"'n"'H"P"L'C"s'3"PG"9"'B'"I0"'2"'8'·3"5"'D2"."'D')--------. uS/em 

# l

180

### ~ 1 160 

### 140**======"-"===========»-.:=====~""'""=================================o=.=======""""'** External Standard Report 

### ==========,.,========o:o:=========,.,.======================================= Sorted By 

### Calib. Data Nodified Multiplier Dilution Signal 

### 10/4/2010 1.0000 1.0000 

### 9:36:48 AM Use Multiplier & 

### Dilution Factor with ISTDs Signal 1; ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.124 88 406.71420 1.70724e-2 6.94358 Fluoride 4.259 8B 114.74656 2.68066e-2 3.07596 Chloride Totals ; 

### 10.01954**::::=.":;;==========================::-~======o:~:==-co=:;::=::=:=:=:=-=====================-==--~** 

### *** End of Report 

### ***

### InstrumentA.fCfflOIJ~il'ill:N!>-**~J!)1/Ii!30** AM IGG

### EM~rP~i!1\§~jb~j'gTV!l\:J'3kt92 AUGUSTA PLANTS 4 & 5, 

### SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAGp~456** 

### 1 of 1Data FUe U: \HPLCLUlUQ4 \MR**EURNS\DATA\OCT\HPLC~3PG98** \007-USUl. D Sample Name: HPLC53pg98 #LCS 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last change-d Analysis Met_hod 

### Last changed BORAL BRICKS EO 

### Seq. Line 

### Mr Burns Location 10/1/2010 8:37:42 PM 

### Inj C: \HPLC2010Q3\MR**BURNS\ME.THODS\~lE'rROHM.** M 

### 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BORNS\METHODS\HPLC53PG98.M 

### 10/4/2010 9:26:06 AM by IGG 

### (modified after loading) 8 1

1 

### ----------p:o·crA:-ADCfCHANNELA {U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\007-0801.D)**u~ml** 

### g 

# I**1~j ~**  

# 1 I

. 160 

### -'1 

## i ! ' I j ) 1 ; 140 ·· 1 I 120- 

# I

Sorted 

### By Calib. Data Modified Multiplier Dilution External Standard Report Signal 

### 10/4/2010 9:26:06 AM 

### 1.0000 1. 

### 0 00 0 Use Multiplier 

### & Dilution Factor with ISTDs Signal 

### 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] I



## -------l------1----------l----------l----------l --1------------------ 3.118 BB 314.60535 1.70653e-2 5.36884 Fluoride 4.258 BB 

### 188.15720 2.65985e-2 5.00471 Chloride Totals : 10.37355


### *** 

### End of Report 

## ***

1.1lL L2n1n 

### .o**,~** 

### 5 EA#0910-96 Page 130of202 Instrument AfCWcf.JE<OTNO.I"-ioN2 4 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAG~'N"i\e457** 1 of l

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\007-0802.D Sample Name: HPLC53pg98 *LCS BORAL BRICKS 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method 

### Last changed EO Seq. Line 8 

### Mr Burns Location 10/1/2010 8:50;01 PM 

### Inj 2 C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by 

### IGG (rnodi.tied after loading)**r--~~::: I"'AD'C1~**  ADC1 

### CHAN**NET"iqU:\HPLC2610Q4\MRBURNS\5AfA\CR;n·HPLC53PG~i8\0D7~0802~6)''''-----·-···-·-------~**
160- 140 -j 

### 1 120 

# ·j 100 

## -J**~** 80

## ~ l 60 -j**~** j • ' 40 

### j c-j 

### l2 20 

# j**~** 

# [\ :;**~** 0 g5

## ~ j t'\! 

# f\ /\**~** <ci

# ~**~** / i -l------------1-:::'**-~--- _\..._.,_~J-**  .. >-.**--------'-~+-'"'"-~** -+ ......**--~~, ----J..._/~----1-.../**  I 0**-+---~** 

### -·r---·--...------..**------~--- ··-··1-------,-----.,_,.-----·--r-·--r---.----,.-------,-~----r--**  -**,----~---···;··-.----:** 2 4 __**6~--~--JI;** _________________________ . .!Q

___, _____________________**.11.._~_mir]**



### Sorted 

### By Calib. Data Modified I-:lultiplier Dilution External Standard Report Signal 10/4/2010 9:26:06 AM 1. 

### 0000 1. 

### 0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area 

### Amount Grp Name

[min] [uS/cm*s] 

### [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.115 BB 313.83789 1.70652e-2 5.35572 Fluoride 4.255 BB 

### 188.36598 2.65982e-2 5.01019 Chloride 

### Totals : 10.36591
========================================================""""""''""'""'"'='.=o".'""==="'" 

### *** End of 

### Report 

## ***

Instrument 

## Nn;J.Pltc;.JEOj-JNb

## ~'1:()~#)3 

# AM IGG

## E~A~~~~~qs~?o~~~~T**t~o"JE~~ 2**  AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI'o'Nl>l458 l of l

# ( Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\007-3101.D Sample Name: HPLC53pg98 *LCS BORAL BRICKS

**===::o====================-~~============================================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line Mr Bu.rns Location 10/2/2010 7:34:20 AM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG 

### 31 1


### (modified after loading) 

### -------ADC1 

### A'-.'A"D"'C"'1 7

### C-i:H"A"NNECA.(U:\HPLC201004\MRB0RNS\OAtA\OCT\HPTC53PG98\oo7::3101J5)·-- uS/em 

### l_,

180

**-~** 

## • 

# ' 160

**-~** ·I 140j 

## ., ., 120 ··] 

### j 100 

## ··J 80 .



## ===================================================================== External Standard Report

**============""==~o:======:o-oo:::===============================================** 

### Sorted By Calib. Data 

### Modified Multiplier Dilution Signal 10/4/2010 9:26:06 AM 1.0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------!----------l----------l----------l--l------------------ 3.116 BB 313.15643 1.70652e-2 5.34407 Fluoride 4.256 BB 188.40083 2.65981e-2 5.01111 Chloride Totals : 

### 10.35518

**======~:::::o====>==~"'"".='"'"-~==================================================** 

### *** End of Report 

### ***



## r~strument AlfCJRJlQJ.ffil:Nl>. B-mllnl 

### AM IGG



## EM~~~~?s~\br\'\"@5T\¥d?J~IJ2 AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 

### 2010 --

APPENDIX PAG!><Nj>e459 1 

### of 1UdLd

**~..l..te** u: \t1l:'1A.-LU.LUI,J<:i\l"l.K

**~UK.N:J\UATi\\UCT\Hl:'LC:Jjp(.;i;it!\UU/-jlUL.U** 

### Sample Name: HPLC53pg98 #LCS Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed .Analysis Method 

### Last changed BORAL BRICKS 

### EO 

### Seq. Line Mr Burns Location 10/2/2010 7:46:39 AM Inj C: 

### \HPLC2 01 OQ3 \MR BURNS

**\METHODS\l~ETROHM.** M 

### 4/1/2010 4:15:36 

### PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by 

### IGG (modified after loading) 31 2

**~---------.A"D'-'C'-'1.** A ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\007-3102.D)
! uS/em 

## j



## ~ 180--=l 

### o?

**~** 

### !

i 

# I 

# l :::



# ~j:.i 120- 100 80--

**=======================================================~====~====~===** 

### External Standard Report 

## ===================================================================== Sorted By 

### Calib. Data Modified t-1ultipl.ier Dilution 

### Signal 10/4/2010 9:26:06 AM 

### 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type 

### Area Amt/Area l-lmount Grp Name



### [min] [•.1S/cm*s] [ug/mL] 

## -------l------l----------l----------!----------!--l------------------ 3.117 BB 313.53778 1.70652e-2 5.35059 Fluoride 4.257 BB 

### 188.47112 2.65980e-2 5.01295 Chloride 

### Totals : 10.36354 

## ===:===='0--":0"" -"'::"-::.-

**;co,-_,._=-~.o:.--** :.._ 

### "'--"'=-=- -::=---= 

### ====== _=. 

### ====================="'" :::.=-==--======-- 

### *** End of Report 

### ***

1 10/4/2010 q 

### 29 

## o t 

### I 

### EA#0910-96 Page133of202 Instrument ATC PROJECT 

### No.



## P-\014~ **2** 

### A 4 GG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~'N/,e 460 1 of 1

## ( Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\102-5501.D Sample Name: HPLC53pg98 iLCS BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 55 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 6:25:53 PM Inj 1 Acq. Method C: \HPLC201 OQ3 \MR BURNS \METHODS \METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Joast changed : 10/4/2010 9:39:38 AM by IGG ---···---"·-- ADC1 A, ADC1 

### cHANNEL A (U:\HPLC201004\MR BURNS\DATA\OCnHPLC53PG98\102:5501.0}-.

**--~** 

# ""::J , .

140l 

# I 1 120- 

## ! 100 -

**~** u



# 80~ **~** 

# i 60· 

## <5 

# ::ot J 

# L_ ·



# --J~_ .. 

# ~1~~--J"---~.-JJ _ .... -· .. . . 

# L-d!

**..,.--- ---T~--..-----..----**  **---r--** ....,..---·-r··----, -----,---------, 2

______ ________

### L_____ ___ 6 8

__________ ____j_.9

_____ ________ **···------~** 2 mi 

## ==============================>=:==================="-"===========;;;o====== External Standard Report **======;;;o;;;o===============~,~=====;;;o===~=================~=========~======** 

### Sorted By 

### Signal Calib. Data Modified 10/4(2010 9:36:48 AM Multiplier 1.0000 

### Dilution 1.0000 Use Multiplier & 

### Dilution Factor 

### with IS1'Ds Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area 

### Amount Grp Name

[min} [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.121 BB 305.91211 1.70644e-2 5.22022 Fluoride 4.263 BB 183,26718 2.66072e-2 4.87623 Chloride Totals : 10,09645

**~c~::.-;=========::::.===========-~=~,,==,~===================·=============='==::..~:===** 

### *** End of Report 

### ***

InstrumentA)C



### \'~9~7Slo~'IJ Pi1f:W7: 13 AM


### IGcJ=Pl<MRillMitlSli'lN~ !PR4J.llf&fl2 AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGEjo~<ge461** 

### l of l

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\102-5502.D Sample Name: HPLC53pg98 #LCS BORAL BRICKS 

### ="'"·=================::=========================""'==:=====================-·== Acq. Operator EO Seq. Line 55 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 6:38:13 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:39:38 AM by 

### IGG Aoc1 A. Aoc1 cHANNEL 

### ATo:w:iPLc2of004\MR suRNS\iYATA\OCT\HPTC53PG98\1o2-s5oz_o>

# us~::J j 160**-~** -! 140 

# l ., 120-1 100 . 80

0 0

# ~ 

# I**======================================:=-:==================="'-•==·""'"~======** External Standard Report**=========~-:::;:;o==·======~"='-"'==================='=''""=="!:'~========================** 

### Sorted 

### By Calib. Data Modified 

### Multiplier Dilution 

### Signal 

### 10/4/2010 1.0000 1.0000 9:36:48 AH Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal l: ADCl A, ADCl CHANNEl" A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mLJ 

## -------j------j----------l----------l----------l--l------------------ 3.122 BB 305.85730 1.70644e-2 5.21928 Fluoride 4.265 BB 183.06128 2.66076e-2 4.87082 Chloride Totals : 

### 10.09010**========================================·~"===··=======================''"''~-** 

### *** End of Report 

### ***

Instrument AlfCJRROllttiJ:Nm R.Oero: 23 AM

## IGGEp7fl~~~~?s~fo~~~~TW~o~\ot<f2 AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGEil!!>e462 l of 

### 1

### Sample Name: HPLC53pg100 #LCS BORAL BRICKS

**~====================================================================** Acq. Operator EO Seq. Line 8 Acq. Instrument Mr Burns Location 

### Injection Date 10/4/2010 4:50:29 PM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\ME.THODS\HPLC53PG100.M Last changed 10/5/2010 9:18:49 AM by IGG (modified after loading) r·· .. ··-·--7\i5c1"ii;"i\6cTc"HiiNNEL A (V:IHPLC20 iOCi4iMRT3DRNS\6.i\i'.i\\OcnHPLC53PG 100\007-080 1.of·--··---- ··--, uSfcm 

# 3

180 

# l

**~** 

### ·:-------'
_ ....

**,-:::-.~.---** 

### --r

# I 

# !I

, ···-,-----------,------

_ __,8'--.______. 

### ..mlrl

**============o:o·=""-============""·==================~============,.::;=::========** External Standard Report

**===="""-"=~~=·-""======================="'=========================="""'o=======** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal 

### 10/5/2010 9:21:11 AM 1. 0000 ] . 0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A 1 

### ADCl CHANNEL A RetTime Type .i'\rea Amt/Area AJrl.ount Grp Name

[min]

**[uS/cm~<s)** [ug/mL) 

## -------l------l----------l----------l----------1--l------------------ 3.124 BB 307.02579 1.71654e-2 5.2.7021 Fluoride 4.249 

### BB 181.57738 2.71138e-2 4.92325 Chloride Totals : 

### 10.19346 

### *** End of Report 

### ***

EA# 091 0-96 Page 

### 136 of 

### 202 Instrument 1 10/5/2010 9:21:31 AM IGG ATC PROJECT No. P·10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~'me463 l 

### of l

### Data File U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG100\007-0802.D Sample Name: HPLC53pgl00 iLCS BORAL BRICKS 

## ===================================================================== Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed

**Analysi~** 

### Method Last changed EO Seq. Line 

### Mr Burns Location 10/4/2010 5:02:47 PM Inj C: \HPLC2010Q3\MR BURNS\METHODS \t<ETROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by IGG {modified after loading} 8 2



### ~---~~:~:-~A!5c1 **A~ADCi** CHANNEL A (U:IHPLC20iOQ4\MRBURNS\DAYAiOC·nm>t:cif:lf>(;160\6o7 :oao2:0)--
j



# 160~ 140



## ~ 120



# ~ 100-1 80 60. 40 20-

**======================================================~==============**


### Sorted 

### By Calib. Data Modified 

### Multiplier Dilution External Standard Report Signal 10/5/2010 9:21:11 AM l. 

### 0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCI CHANNEL A 

### RetTime ·rype Area Amt/Area Amount 

### Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.125 

### BB 307.89706 1.71653e-2 5.28514 Fluoride 4.249 BB 

### 181.32318 2.71142e-2 4.91644 Chloride Totals : 1.0.20157


### *** End of Report ***



### Instrument 

### Atc:f(Rd;jEt<na.



## P-l-1~114238 AM IGG



## EP):'IgRo~~?s~?orf.f~~W~o~t~~ **2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# "' 

# "' 

# 1

APPENDIX

**PAGf<Ni!~464** 1 

### of 1I



### '· BORAL BRICKS



# Calibration Curve Chromatograms

ATC PROJECT No. P-10142 

### EA# 0910-96 Paqe 138 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 465

### Method U:\HPLC2010Q3\MR

**BURNS\~£THODS\HPLC53PG98.M** BORAL BRICKS 

## ===================================================================== Calibration Table 

### ==========================,==========================================
Calib. Data Modified 

### Calculate Based on Rel. Reference Window 

### Abs. Reference Window Rel. Non-ref. Window Abs. Non-ref. Window 

### 10/4/2010 9o26:06 AM External Standard Peak Area 

### 10.000%

0.000 min 

### 10.000 

### %

0.000 min Use Multiplier 

### & Dilution Factor with ISTDs Uncalibrated Peaks not reported 

### Partial Calibration Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks Curve Type Origin Weight Linear Connected Linear (Amnt) Recalibration Settings: Average Response Average Retention Time: Calibration Report Options Average all calibrations Floating Average New 75% Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket) 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime

**I~v.1.** 

### Amount Area Amt/Area Ref Grp Name

[min] 

### Sig 

### [ug/mL] 

## -------l--!--l----------l----------l----------l---l--1--------------- 3.147 1 1 2.00000e-l 11.23373 1.78035e-2 Fluoride 2 1.00000 61.93819 1.61451e-2 3 5.00000 309.42168 1.61592e-2 4 10.00000 593.11342 1.68602e-2 5 

### 15.00000 852.09720 1.76036e-2 4.156 1 1 

### 2.00000e-l 5.55649 3.59939e-2 Chloride 2 1.00000 34.57356 2.89238e-2 3 5.00000 185.83790 2.69052e-2 4 10.00000 378.92274 2.63906e-2 5 15.00000 570.98003 2.62706e-2
**======"-"'=="·================''='====="""'-"=:=======""""~~~:-o===c.:==:"'=·====='="'=""·==oo:-"O"=~~=** 

### Peak Sum Table
**:.~:~=;;;;:::======================================================.:=~'===-======** 

### ***No Entries in table***
**==:=~=================================""=========::========:::::=====:==='"'""""':-==:0:**

Instrument 

### Alrclf100!J.Ee1HJ<>. 

### Gl-lfii/425 3 

### AM IGG



## EPE)\')@~~~9s~fo~~~~T **~~o~~t~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 

### 201 0 APPENDIX PAGEa-q,e466 

### 1 of 2

### .l"Je-cnoo U; \lit'l.A
.. .:::: U l U!,!..i \l"lK .I:WKN::J \l'l.I!:THUU::i

**\HPLC:JjP(:i~tl.** M



### ==============================~~==========~~~A~=~~~~§================= Calibration Curves 

### ====:::o==============================-,========================='"'======== Area / 

### /I



# ~ n 1 800. '5' 

## _,./ i 700

**-~** / 

# soo-j /r/ 5001 ./ 400-j 

### 3// 300l 

# /_,.7" 200

**-~** l / 100

**~1** 2__ /- 

### -j,/ Q

**-r-----,-·--·--,-·-·--~-------,----~-"f'-----,** .. - - ·T---···-,-·

0 10 Amountrug/mll_ 

### Fluoride at exp. RT: 3.147 

### ADC1 A, ADC1 CHANNEL A Correlation: Residual Std. Dev.: 0.99937 18.29678 Formula: 

### y 

### m: b: 

### mx + 

### b 58.49156



### 5.73482e-1 x: Amount y: Area Calibration Level Weights: Level 

### 1 1 Level 2 0.2 

### Level 3 

### Level 4 

### Level 

### 5 

### 0.04 0.02 0.013333 Chloride at exp. RT: 4.156 

### ADC1 A, ADC1 CHANNEL A Correlation: Residual Std. Dev.: Formula: y = 

### mx + b m: 

### 38.06134 

### b: -2.32861 x: Amount 

### y: Area 

### 0.99996 2.00920

Calibration Level Weights: Level 1 1 Level 2 0.2 

### Level 3 0.04 Level 

### 4 Level 5 

### 0.02 0.013333



## r n s truman t 

## ATclfoR'd.!EOTJNb. 1>;1;]14:!5 3



## A~; IGG



## E:;;t~~~L~s~?o~~~§T **1**



## ~~cfM~~ **2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~467** 2 of 2**-~·'""'"" ~..,,,**  .. ,. \V'-.l.- \·" .. .L.J'-"'.J..JC'J..JU \UUJ--U4U.l. • LJ 

### Sample Name: HPLC53pg98 #1 BORAL BRICKS 

### =================:::o=======================:============================ Acq. Operator EO Seq. Line 

### 2 Acq. Instrument 

### Mr Burns Location 

### Injection Date 10/1/2010 6:10:43 PM Inj 1 

### Acq. Method C: \HPLC2 0 10Q3 \MR **BURNS\METHODS\I~ETROHM.** 

### M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:21:17 AM by 

### IGG 

# f

**---Aoc1~1ii5c1** CHANNEL A cu:IHPLt2o1oo4\MRBU-Fi"NSii5AT"A"'o""'cn=H"'PccLc"s"3"P"'G""98ioOr62-6i:i5) I 

### '



## us:~:

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### c 140 120



# ~ J 100

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### ~ 1 (!) (ll 60_j

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### c_.c-

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# -_~-',_-_-_-_a'_-_·--~-- i

. .... . . . -·· _ ... ----·-T_-_--"i1l0_



# ~- ...

# ~-==~---~li:=~.-~i.J **===,..._,================""================="~==========~·===================** 

### External Standard 

### Report **=========================================================~==========~** 

### Sorted 

### By Signal Calib. Data Modified Monday, October 04, 2010 9:21:13 AM 

### Multiplier 1.0000 Dilution L 0000 Use Multiplier 

### & Dilution Factor 

### with ISTDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/Area 

### Amount Grp Name



### [min} [uS/cm*s} [ug/mL} 

## -------l------l----------l----------l----------l--1------------------ 2.984 VB 11.43427 1.62975e-2 l.86350e-1 Fluoride 4.161 EB 5.52259 3.73516e-2 2.06278e-1 Chloride Totals : 

### 3. 92628e-l

.....

**-~** .. == ---- - 

### ·-======= **====:~·=""=================c::=.=::.-.=** 

### =====:=:·=====:::o======t+o===== *** End of Report 

### '**

Instrument 1 10/4/2010 9:21:47

**A~1** 

### IGG EA#0910-96 

### Page 141 of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



## PAc!EfWo~ 468 1 0 

### f 1udLd ru.e u: \J1l:'L\...LU.lUIJ-'l\I"..K eUHN0\UA'l'A\OCT\HPLC:.3PG98\00l-0202.D sample Name: HPLC53pg98 #l BORAL BRICKS =================="'-'=============================:<==============,===== 

### Acq. Operator EO Seq. Line 2 

### Acq. Instrument Mr Burns Location Injection Date 10/1/2010 6:23:04 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M I.ast changed 4/l/2010 4:15:36 PH Analysis Method U:\HPLC2010Q3\MR BURNS\l1ETHODS\HPLC53PG98.M Last changed 10/4/2010 9:21:17 AM by IGG



### ~----- 

### -. )\Dei -A"7--6cfCHANNE:L"i\(o:\HPLC2:00i.1 

### o'-o'-4;CIM:'iR~Bi.U~R""N:;,SI"D"A""T""A"IO'-'C"T\'"H"'P"'L'c"s"3"PG"'9"'s"ID"'D"1-;-0=2o2~r5)- ··-·· . - ---- 

### 1 

# I i uS/em 

# J ,

180 

### "j 160 J 

## j 140-! 

## j 

# :::1
80 "j 60



## ~ _-g 

# g 1 § .2 

## :., u:: ..._105 ...... 'lr'l- 40

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## 2o-i

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## # m •



# L_------~·-=~~~---1·=-~=-~~=~-;:::r~--~**~--=-=-~-~=--=--· _-_-_-~_-_--,_~--J**  ____ 

# ~_- ..

# -_._,·;r"~---_-~_-·_·--~--~~-~--_-- **~~;-~~--fl)-jJ** =================================="-'·==="-'"=="======:====================== 

### External Standard Report =========:=:==============================================""="'-="-"========= 

### Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal t>'londay, October 

### 04, 2010 9:21:13 AM 1. 0000 1.0000 Use 

### Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 2. 980 Ml1 10.90178 

### 1. 62975e-2 J. 776"12e-1 F'luoride 4.156 Ml1 5.51022 3.73765e-2 2.05952e-l Chloride 

### Totals : 3.83625e-1 

## *** End of 

### Report •**

""" .o 

### o.? 6 G 

### EA#0910-96 Page 142of202 Instrument

**A'fcWcJ!Jte;~J.R,. ,-.;ol"-4~**  **0** AM I ·G EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGg<Nl>e469 1 of 1Sample Name: HPLC53pg98 *1 BORAL BRICKS 

### Acq. Operator EO Seq. Line 70 Acq. Instrument Mr Burns Location Injection Date 10/3/2010 1:45:22 AM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:21:17 AM by IGG 

# 7\ocfA: ADClCHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCT\Hi'Cc53PG98\o61-700D5)

**=============================~=========================~=~==========~** 

### External Standard Report
**=""'"'=========================================="""-~============~-=======""=** 

### Sorted By 

### Signal Calib. Data Modif.ied Monday, October 04, 2010 9:21:13 AM 

### Multiplier 1.0000 Dilution 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Arnt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 2.990 VB 11.61392 1.62975e-2 1.89278e-1 Fluoride 4.158 88 5.54815 3.73006e-2 2.06949e-l Chloride 

### Totals : 3.96227e-l 

### ===============""======o:o""="'--========-"'='"'""""'==============""=======-======== 

### *** End of Report 

### ***

101 0010 5 

### EA#0910-96 Page 

### 143of202 Instrument



### A~Cl'RdfrrrNo. **~-'1bt4'}** AM IGG EPA ICR EMISSION TEST PROJECT AUGUST A PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~'W>e470 1 of 1uaLd i'l.ie u: \.tit'LLLU_iUl,J'f\l"iK _tjU.KN0\UA.TA\UCT\HI:'LC:J
..H'ti':H:S\UUl-/UUL.O 

### Sample Name: HPLC53pg98 #1 BORAL BRICKS 

### Acq. Operator EO Seq. Line 70 Acq. Instrument Mr Burns Location Injection Date 10/3/2010 1:57:42 AM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed : 10/4/2010 9:21:17 AM 

### by IGG ADC1 A ADC1 CHANNEL A (U:\HPLC2010Q4\MR

**BURNS\DATA\OCnHPLC53PG98\00T760~------~**



# 1 uSfcm 

# l j ,



### 180 · , 1 160 

## ! 140-- 

### 120 100 80

**·····~---··-r.** -·-·····-·-··-··! 12 mi 1 =:=:;·===========""'·"'"-'=:,==""'=""'===="''====================""======,=============


### Sorted By Calib. Data Modified Multiplier Dilution External Standard Report Signal Monday, October 04, 2010 9:21:13 AM 1. 

### 0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADC1 CHANNEL .1\ 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/em's] 

### [ug/mL] 

## -------l------l----------l----------l----------1--l------------------ 2.990 MM 10.98494 1.62975e-2 1.79028e-l Fluoride 4.155 MM 5.64502 3.71113e-2 2.09494e-1 Chloride Totals : 3.88522e-l

**===='-"''"""·""'===,·~:::.::.::.;;::=:=;;=======~-=·=·"'-'=='-""==~===:===::::==============================** 

### *** End of Report 

### ***



## InstrumentAICPR£xl~<21liiJ6. f'l1il'GI229 AM IGG



## EP~I}gRO~Jfli"~tbffllll'Tj,iM&tF AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 

### 2010 APPENDIX PAGE.Nge471 

### 1 of 1

### Sample Name: HPLC53pg98 *2 BORAL BRICKS **=~===================================================================** 

### Acq. Operator EO Seq. Line 3 

### Acq. Instrument Mr Burns Location 

### Injection Date 10/1/2010 6:35:23 PM Inj l 

### Acq. Method C:\HPLC2010Q3\MR BURNS\HETHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed : 10/4/2010 9:21:17 AM by 

### IGG [" .. ··- ·-·ADCfA. :A5c1CHANNEL A (Uc1HPLC2615541MR BURNS\DATAIOCnHPLC53PG981002-03o1:b)"···----- -·----· uS/em 

### ·1

**~**

180



# ~ 

# :'! j ! 160

**··~** 

## J 

# ::1

80

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# 1 40] j 

### Ng 20·-J M J___ N --·i-/\..
__ 0-i--

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### ________ ..___________ **--~.£**

### ___________ ru 

### :g 0 E u



### ======-============================================================== External Standard Report 

### ========""·========================================,=================== Sorted 

### By Calib. Data 

### Modified Multiplier Signal Monday, October 04, 2010 9:21:13 AM 1.0000 Dilution 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTiwE Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s) (ug/mL) 

## -------l------l----------l----------l----------1--l------------------ 3 .106 VB 62.57794 l. 

### 69398e-2 1. 06006 Fluoride 4.265 BB 34.83099 2.80299e-2 9.76308e-l Chloride Totals : 2.03637

**=====""=~.>.=="-'=================""=========:;::=""""~==========:=:================·** 

### *** End of 

### Report 

### ***

Instrument 1 10/4/2010 9:22:59 AM IGG EA#0910-96 

### Page 145 of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PA~~ 472 1 of l**oarnp~e** 

### Name: HPLC53pg98 #2 BORAL BRICKS 

### ==================================================·=================== Acq. Operator 

### EO Seq. Line 3 

### Acq. Instrument Mr Burns Location 

### Injection Date 10/1/2010 6:47:44 PM Inj 2 Acq. Method C: \HPLC2010Q3\M!; BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC20lOQ3\MR BURNS\METHODS\HPLC53PG9B.M Last changed 10/4/2010 9:21:17 AM by IGG

**~-- --~ADCTA~ADC1**  CHANNEL A (U:\HPLC201004\MR BURNSIDATA\OCT\HPLC53PG98ioii2-0302

**D)~-. ·-··---~**  I US/em 

### .j 0

**~**



# 1ao~ 

# !
1 

### ] 

# ::j :
100 

## j II



### ============-===========================<--'========================e:==== External Standard Report **================~====================================================** Sorted By Calib. Data Modified Multiplier 

### Dilution Signal 

### Monday, October 04, 2010 9:21:13 AM 1.0000 1.0000 use 

### MuJ.tiplier & 

### Dilution Factor wit.h IS1'Ds Signal 1: ADCl A 1 ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/rnL] 

## -------l------l--·--·----l----------l-------·--l--l-----·------------ 3.105 BB 60.57874 1.69346e-2 1.02588 Fluoride 4.262 BB 33.81343 2.80827e-2 9.49573e-l Chloride Totals : 1. 97545

**==========""'==:~:=: ·""'=====c==·-'=';:::::::=======================o;::=============:.=~>:.::==**  

### *** Er1d of 

### Report 

### ***

lnstrurnent 1 10/4/2010 9:23:48 AM IGG EA#0910-96 Page146of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~'IJ'/,e473 1 of l

### Sample Name: HPLC53pg98 #2 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 71 

### Acq. Instrument Mr Burns Location Injection Date 10/3/2010 2:10:01 AM Inj 

### 1 Acq. 

### Method C: 

### \HPLC2010Q3\MR BURNS\METHODS\METROHM. M Last changed 4/1/2010 4:15:36 PM Ana lysis Method U: 

### \HPLC20 1003 \MR BURNS \METHODS\HPI"CS3PG98. M Last changed 10/4/2010 9:21:17 AM by IGG 

# r···· ··---·)i:tic'1 A, ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCTIHPLC53PG98\002-7101.D) 

### uS/em 

# l

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180l 

# :il 160 

# 'l 

# I 

# :::j

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# ·l 80 

## 1 

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**60-~** 

# u:

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# i ' ! l_ 

# ::1

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# ,.-'- **-~----~-....:** o -..----,---- ,---·--,--,--r--..----.,

**-.~---·r---......,...------.,---....----r·**

### .. **--,---,---..,...---y---·-~----,...----~-,-~--1**

**··--------~** 4 6 8 10 

## ===================================================================== External Standard Report

**=================='"""'"""'""'==:.==="'~""''--o·===""''"""'=====""·""'~"=="'~""==~"'""'-""==,=====-'""===:::===~** 

### Sorted 

### By Ca.lib. Data Modified Multiplier Dilution Signal Monday, 1.0000 1.0000 October 04, 2010 9:21:13 AM Use Multiplier & 

### Dilution Factor Hith ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTirne Type Area Arnt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.116 

### VB 63.31603 1.69416e-2 1.07268 Fluoride 4.267 BB 

### 35.34018 2.80046e-2 9.89686e-l Chloride Totals : 2.06236

**===========~=========================================================**

 ~**  

### End of Report 

### ***

Ins t 

### rumen tAlC



## l'lw.l~<:!1l **~6.** f!l1 t2\42 56 AM I GG



## EP~~c!RO~JPs§ibJ'fE'Jl'T **~1lo3~t~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 12 mi

APPENDIX

**PAGi£'~1'474** 1 

### of 1BORAL BRICKS 

## ===========,.=====::::===================,==============:================= Acq. Operator EO Seq. Line 71 

### Acq. Instrument Mr Burns Location Injection Date 10l3/2010 2:22:21 AM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U; \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98

**-~1** 

### Last changed 10/4/2010 9:21:17 AM by 

### IGG



### ~-------ADCTA,ADCfCHANNEL A (U:\HPLi';-ioiOQ4\MR


### BURNS\D:;cAeoT"A-c\O~c~n=H~PL~C=s3PG9ii\iiiii=71o2:b) i uS/em 

## l <?



# 180~

**~**



# I ! _, ·! 160 

# j 140 

## l 

# :::Jj.< 80 60 

# 3 

# "' '0 ·c 0 

## :c (J 40 

# l 10 t-- N 0 

# I 20J



### ~ **~** i:!il



### ~ N 10 

### f?l I 

## J N ·),__ 

## "f

**~** (0



## ~

**~** .••• /_. 0 **J,=-=;_~_-;::__-:_~-::!::_:** 

## ·· r-----', ., __ **:,..__~.:_-_··,-+~f------=-----,--.·** ...

# .:=---,--'---- -l- ' . ' ' ---r-··----,---,--,-

**-----~-** 4
_ _ __

### 2___________________ ____ 8
_ 

### _1Q_______________________**_1~,___,m,i,..~** I L_ ____ _

**========~==~=========================~=========~============~=========** 

### External Standard Report
**=========~====================================================~=~====** 

### Sorted 

### By Calib. Data Modified Multiplier Signal 

### Monday, October 04, 2010 9:21:13 AM L 

### 0000 Dilution 1.0000 

### Use

**~4ultiplier** & 

### Dilution Factor wittl ISTDs Signal 

### 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/m.L] 

## -------l------l----------l----------l----------l--l------------------ 3.115 BB 61.28004 1.69365e-2 1.03787 Fluoride 4.267 BB 34.30963 2.80566e-2 9.62610e-1 Chloride Totals : 

### 2.00048

**==========~~-"'~=======-"-'""=""'=======================~===========""~"'-========** 

### *** End of Report 

### ***

Instrument 1 10/4/2010 9:24:05 P.M IGG EA#0910-96 Page148of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGEW, 0 475 1 

### of 1

### Sample Name: HPLC53pg98 #3 BORAL BRICKS

**=======================~=============================================** 

### Acq. Operator EO Seq. Line 4 

### Acq. Instrument Mr Burns Location Injection Date 10/l/2010 6:59:03 PM Inj 1 

### Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.H Last changed 4/1/2010 4:15:36 PH Analysis Method. U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:21:17 AH by IGG 

# r---- ADC1 A, ADC1 CHANNEL A (U:\HPLC201004\MR

**8URN$\0AtA\0cnHPLC53PG98\oo3-6401~D)** 

### -------------·-·--, 

### ! uS/em 

# l

**~** 1 180-



### ~ I 

# I 160 140 120 100 80. j 

### 60 ' 

# 1 40---l 

### j <n 20--J

**~** 

# 1--·---'

**~** 0 . ' 2

**======~==~============================================~==============** 

### External Standard Report

**=========================================================::=~.,==,=======** 

### Sorted 

### By Signal Calib. Data Modified Nonday 1 

### October 04, 2010 9:21:13 AM 

### Multiplier 1.0000 Dilution 1.0000 Use 

### Multiplier & 

### Dilution Factor l-dt.h ISTDs 

### Si.gnal 

### 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/rnLJ 

## -------l------l----------l----------l----------l--!------------------ 3.112 BB 308.75937 1.70647e-2 5.26889 Fluoride 4.257 BB 185.12665 2.66039e-2 4.92508 Chloride Totals : 10.19398

**,.~==~"'""""===~-'""'~·"==~-~~==.-:c"-""'""'"'"'======""'==::::=::::===================''"~"-"""===·.-:t'"·=·========** 

### *** End of Report 

## ***

Instrument



### ArC:Rll()ii,EZ~Nl>. B-1Q1!1215 AM IGG



### EM~~~~?s~lbr\"fEJS'r1p\~bq!ofN2 AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### APPENDIX

**PAG~~476** 

### 1 of 1

### Sample Name: HPLC53pg98 #3 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 4 

### P.cq. Instrument Mr Burns Location 

### Injection Dat.e 10/1/2010 7:11:22 PM Inj 2 Acq. Method C: \HPLC20l 0Q3\MR BURNS\METHODS\METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed : 10/4/2010 9:21:17 AM by IGG Aoc1 A. AoCTcH"ANNEL ii(u\HPLc2o1oa.,MR BuRNsioATA\ocnHPtcs3PG98\oo3-o4oz:or··--
--- 

# ;g 

# i

'



# 1~----~"--1Z~j

**-·~·----------** =-====,================:;,========::::============,:=========o:o=============== External Standard Report **=============='-"======'-"===:o.~=============,-========"-'======================** 

### Sorted By Calib. Data Modified 

### Multiplier Dilution 

### Signal 

### Monday, October 04, 2010 9:21:13 AM 

### 1.0000 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal l: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min) [uS/cm*s] [ug/mL) 

## -------j------:----------l----------l----------l--l------------------ 3.113 BB 308.33966 1.70647e-2 5.26172 Fluoride 4.257 BB 185.05852 2.66040e-2 4.92329 Chloride Totals : 

### 10.18501 

### '"'======""============:o:==o=========·o•<>:<=============,.,====================:::: *** End of Report 

### ***

,nstrument 1 10/4/2010 9:24:23 AM IGG EA#0910-96 Page150of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGJE'ffi,e 477 l 0 f l

### Sample Name: HPLC53pg98 *3 BORAL BRICKS =-================================:================================""=>== 

### Acq. Operator EO Seq. Line 72 

### Acq. Instnlment Mr Burns Location Injection Date l.0/3/2010 2:34:41 AM Inj 1 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed : 10/4/2010 9:21:17 AM by IGG

**~-------~-;;;:ocrr.** AoCTc"HANNEL-A tu:IHPLc2o 1 oa4\MR BuRNs\oAT AlocTIHPCcs3?898\oo3-no1

**.o)~----~~-----** usrcm

**--~**

**~** i

**~** 180 "J '1 

### J 160 

### -1 140j

**~** 120-1 100

**so~**



## ===================================================================== External Standard Report

**==============================================~======================** 

### Sorted By Signal Calib. Data Modified Monday, October 04, 2010 9:21:13 AM 

### Multiplier 1. 0000 Dilution 1.0000 Ose Multiplier & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/em's] [ug/mL] 

## -------;------l----------l----------l----------l--l------------------ 3.124 BB 

### 309.26727 1.70648e-2 5.27758 Fluoride 4.263 BB

**186~31842** 

### 2.66017e-2 4.95640 Chloride Totals : 

### 10.23397

**==:oo========================-=---~o="'-~==:=o=="-"===============================·-=** 

### *** End of 

### Report 

### ***



## rnstrumentAtc~~enl<l. **~~~111236** AM IGG



## EP'l(;-U~~?silibtf-¥~~T **~~o~kt~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI?<Wge478 1 of 1

### Sample Name: HPLC53pg98 #3 BORAL BRICKS**===========================~=========================================** 

### Acq. Operator EO Seq. Line 72 Acq. Instrument Mr Burns Location Injection Date 10/3/2010 2:47:01 1\M Inj 2 1\cq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METRDHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC2010Q3 \MR BURNS\METHODS\HPLC53PG.98 .M J"ast changed 10/4/2010 9:21:17**~_M** 

### by IGG**~----** ADC1 A, ADC1 CHANNEL A {U:\HPLC2010Q4\MR**BURNS\DATA\6t"f\l.:(p['t53PG98\003--7202~-------~----·-··1** I ' 

### j uS/cmj 

## I**<!i!~** · ' I 1 

### 1so 1 

## 1eo 1 140 120. 100



## =====================================================================
Sorted 

### By Calib. Data 1-lodified 

### Multiplier Dilution External Standard Report Signal Monday 1 

### 1.0000 1.0000 October 04, 2010 9:21:13 AM Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTirne Type Area Amt/Area J\rnount Grp Name

[min] [uS/crn*s] (ug/mLJ 

## -------l------l----------i----------i----------l--l------------------ 3.125 BB 

### 311.32043 1.70650e-2 5.31268 Fluoride 4.266 BB 

### 186.84802 2.66008e-2 4.97031 Chloride Totals : 

### 10.28299**========================================================~============** 

### *** End of Report 

### ***

1 nt 1201n q 2 

### EA#0910-96 Page152of202 

### "nst 

### rumen t

### AtCl>RO~ECT No. P·

## i u1'l.2 4 4 

### AM I 

### GG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

### PAG~'l/ile479 l of lBORAL BRICKS
**=============================================================~=======** Acq. Operator EO Seq. Line 

### 5 Acq. Instrument Mr Burns Location 

### Injection Date 10/1/2010 7:23:42 PM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:21:17 AM by 

### IGG ,..----

**~** Aoc1-A-;-iiocTcfiliFiFiEL A <u:\HPLc2o1o6<1"fR BURNs\oArA\OCT\HPLc53PG9aloo4-oso1.D> ·---- us/em 

# ··i l8

1Mj



## ~ i 160 _:j



# 140~ 120 

## -1 1 100 . 80 

# "' 60- ,-·,

**~** 

# I



# ::J,~l~)L~'·~{'~ **;~LJ** ===========:>:·=======================================================::== External Standard Report
**===============================~~==========,====""============-===========** Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal Monday, 

### 1. 

### 0000 1.0000 October 04, 2010 9:21:13 AM Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl 

### A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

(min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.125 

### BB 592.99884 1.70799e-2 10.12839 Fluoride 4.256 

### BB 377.41034 2.64355e-2 9.97703 Chloride Totals : 

### 20.10542

**=============-==========="'·=-~=<========,============:"'===============::;.-:::.==** 

### *** End of Report



### ...• strument 1 10/4/2010 9:24:57 A11 

### IGG EA#0910-96 Page 

### 153of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

### Paae l of 1 APPENDIX PAGE N"o. 480

### Sample Name: HPLC53pg98 #4 BORAL BRICKS 

### =============:======================================================== Acq. Operator EO Seq. Line 5 

### Acq. Instrument Mr Burns Location 

### Injection Date 10/1/2010 7:36:02 PM Inj 2 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U; \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98. M Last changed 10/4/2010 9:21:17 Ar1 by 

### IGG

- ADC1 A, ADC1 CHANNEL A (U:\HPLC201004\MiHfURNS\DATA\OCTiHPLC53PG9S\004-050i:D)·-·

# ---------l uS/em 

### l N J



# ~- 180cj
- 160 

# 1 1



### 140~

**~-** 120 

### ··J



# 100-~ i ao.-.:1

**~** 

### j ,.;



# 60~ {\



# ~ 40 

# J IJ \__ 

# i\ ·1 

## i\ N 0) N 

# 2:

# l:,).:;:;:=J.- 

# L

**-~_\::-::,:;::-'J,__,-h",:~\--~-_c~},_~L---.--.**

# ----,-----.....-- -i 2 4 __ ...§________________________!___

_________ ____!Q__________ 

## g _____

## mffi ============='=============================================--""======o;o=o==:=: External Standard Report
**==,==~==="-'====·~~=========-=======================================""'=====** 

### Sorted By 

### Calib. Data Modified Multiplier Dilution Signal Monday 1 

### October 04, 2010 9:21:13 AM 1. 

### 0000 1.0000 Use Multiplier & 

### Dilution Factor 

### with ISTOs Signa1 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.123 BB 

### 591.84839 1.70799e-2 10.10872 Fluoride 4.254 BB 

### 377.41174 2.64355e-2 9.97706 Chloride Totals : 

### 20.08578 =========================================================="-'""'·""''""=""===="" 

### *** End of Report 

### ***

EA# 0910-96 PaQe 154 of 202

**InstrumentAtcrndJ~§jlji.Jg_** Jl'-18'f120 5 AM 

### IGG EPA ICR EMISSION T!OST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGJ!'l\18•481 1 of 1

### Sample Name: HPLC53pg98

**~4** BORAL BRICKS

**====~========================================~====~==================** 

### Acq. Operator EO Seq. Line 73 Acq. Instrument Mr Burns Location Injection Date 10/3/2010 2:59:21 AM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98. M J"ast changed 10/4/2010 9:21:17 AM by IGG ADC1 A. ADC1 CHANNEL A (U:iHPLC20fOQ4\MR
**BURNSIDATA\OCT\HPLC53PG981iio4~'i36cr-of·-------,**

**uS/em~**

**======================================~========~=====================** 

### External Standard Report

**""'=========.:::~~O:OO'O::::~,====::o"::=::::::::-.=-o============================================** 

### Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal Monday, 

### 1.0000 1.0000 October 04, 2010 9:21:13 AM Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/Area

**&~ount** 

### Grp Name

[min] [uS/cm*s) [ug/mL) 

## -------t------l----------l----------l----------l--1------------------ 3.135 BB 594.09766 l.70800e-2 10.14718 Fluoride 4.263 BB 380.40378 2.64342e-2 10.05567 Chlo<ide Totals : 20.20285

**============================~=======~==========~=~=================~'~** 

### *** End of Report 

### ***

Instrument Al"CJRRb!JEtiHJ0.



## ~-~ OP\221 AN I GG



## EP):'fgRo~~?s~i'ot\'f~TWRo5~~~ **2** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~<Wge482** 1 

### of 1

### Sample Name: HPLC53pg9B #4 BORAL BRICKS

**=========~========~=========~==============================~=========** Acq. Operator EO Seq. Line 

### 73 Acq. Instrument Mr Burns Location 

### Injection Date 10/3/2010 3:11:41 AM Inj 2 

### Acq. Method C : \HPLC2 0 1 OQ3 \MR BURNS \METHODS \METROHM. M Last changed 4/1/2010 1:15:36 PM Analysis Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG9B .M Last changed. 10/4/2010 9:21:17 AM 

### by IGG

**·-····----~Abc1A-.-ADC1** CHANNELA 

### (U:\HPCC2'0"T604\MR BURNS\DATA\6CnHPLCsJPG98\004-7302.Df -----··--·----

**-~** uS/em 

# l

**~** 1



### ~ 180 

## "1 160j



# ~ 

# I



# :::~

**~** 1 1 1

1 . 100 

# i

**~** 

# ! I 80



## -~ M



## ~ 

# I I eo 

# -1 1i

**~** 1 l 

## !\ ...t 

## •oJ 

## i I f1 .- i 

# I L 200



# -.1.-~-----.~**t.~J \,T-;.:.__:r::-Ti~~c,** **~-~~l, ::=::::.-'.::,c·./~->:-_···c_+_"_J~** .....-- .f· . ' ' • . **;---,.-----~----"**
_ 2_ _ • 6 

### L .._______ .. __ 1,oc_ __ 

### External Standard Report 

### ;=================================================,==========""·======= Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 

### Monday, October 04, 2010 9:21:13 AM 1.0000 1.0000 Use Multiplier & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min) [uS/cm*s) [ug/mL] 

# -------r------r----------r----------r----------r--r------------------ 3.135 BB 593.50879 1.70800e·2 10.13711 Fluoride 4.264 BB 390.46509 2.64342e-2 10.05728 Chloride Totals ; 

### 20.19439

**:..:""'=""========o.::==,._,======================:::~==::o::===,==:=-="===::;:,=;:o.=,_-===========** 

### *** End of Report

**~ 



### .,,strument 1 10/4/2010 9:25:29 At1 IGG 

### EA#0910-96 Page156of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 12Sample Name: HPLC53pg98** ~5** BORAL BRICKS 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed 

### Analysis t1ethod Last changed EO 

### Seq. Line 

### Mr Burns Location 10l1/2010 7:48:22 PM Inj C:\HPLC2010Q3\MR BORNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:**\HPLC2010Q3\~1R** BORNS\METHODS\HPLC53PG98 .M 10/4/2010 9:26:06 AM by IGG 

### (modified after loading) 6 1

ADC1 A. ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG9B\005·0601.D) 

### --- -··--·-- -··----------. uS/em 

## g

180

## ~ 160. 140 120 .

===>=====,==================c:=:==""""""===,================================ 

### External St.andard Report**"'~'""==~o::=====""==================:=:;;:========================::::======:c.:=======** Sorted 

### By Calib. Data Modified Multiplier 

### Dilution 

### Signal 10/4/2010 9:26:06 AM 1.0000 

### 1. 0000 

### Use Multiplier & 

### Dilution Facto:r:- with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/rnL} 

## -------l------l----------l----------l----------l--l------------------ 3.134 

### BB 847.65564 1.70849e-2 14.48213 Fluoride 4.255 

### BB 568.12811 2.6381le-2 14.98783 Chloride 

### Totals : 29.46995 

## *** End of Report 

## ***

-w:..LA ""'"" 

### .a**~"-** 

### 2 9 GG EA# 0910-96 Page 157 of 202 Instrument ATc+'«v.lc<:>YNn.**e--~ ~1"1~**  AM I • EPA ICR EMISSION TEST PROJECT AUGUST A PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

# I I 

# '

APPENDIX**PAG~'iiae484** 1 of 1

### Sample Name: HPLC53pg98 *5 BORAL BRICKS
**=================================~===================================** 

### Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed EO Seq. Line Mr Burns Location 

### 10/1/2010 8:00:42 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BORNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by 

### IGG 6 2
(modified after loading) 

# 1 -.- .. A"o"c"'1'A-. A"o"c"1"'ci:iHiA"NiliNEL .. 

## A(LTiRF'Cc2ofoa41MRi'isuC1REs'N"'s"''"o"'A"'TA"'"o"cnfirLcssPc9~-oo5-"06"o"'2'.o"J"---·----~ 1 uS/em



### ~

**~** 

### i 1801 q 

# i J 160 

# l 140- 120
..

**=================~===============~======================~============** 

### External Standard Report
**===================,~====================================~============** Sorted By Signal 

### Calib. Data 

### Modified 10/4/2010 9:26:06 AM 

### Multiplier 1.0000 Dilution 1.0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal l; ADCl A, ADCl CHANNEL A Ret'Time Type Area 

### Arnt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------r------l----------l----------l----------l--1------------------ 3.134 BB 850.78156 1.70850e-2 14.53557 Fluoride 4.254 BB 567.44427 2.63812e-2 14.96986 Chloride Totals : 

### 29.50543

**============~ -=-,:c--,~~============-~~~-======""'="~==============='========""===**  

### *** End of Report 

### ***

'nstrument 

### 1 10/4/2010 9:26:37 AM IGG 

### EA#0910-96 Page158of202 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# ' 12



### Paae 1 of 1 APPENDIX PAGE NO. 485**Sarr~le** 

### Name: HPLC53pg98 #5 BORAL BRICKS
**============~,========================================================** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr Burns Location 10/3/2010 3:24:00 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\HETHODS\HPLC53P(.;98.M 10/4/2010 9:26:06 AM 

### by IGG 74 

### 1
(modified after loading)

. .,A"D'-'C"1'A'."A"OC""1'c-'H"'A.,:N.,;,N;;eEL i\(lJiHPLC2016o41MKBii'U;isR:.0NocSI"D"A""'TA"'I""O"'c"'TiHi5Cc53l'G98\oos:f4-6iD"f------, 

### I 

# I ;

**~** 

### :g a 

### :c CJ 

# ~ I

**===============================~=~===================================** 

### External Standard Report
**==============================~=================================~====** Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal 10/4/2010 1. 

### 0000 l. 

### 0000 9:26:06 AM Use Multiplier & Dilution Factor with ISTDs Signal 

### 1: ADC1 A, ADCl CHANNEL

**~** 

### RetTirne Type A.rea Amt/Area Amount Grp Name

[min] [uS/cm*s) [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.147 

### BB 856.55316 1.70850e-2 14.63424 Fluoride 4.266 BB 

### 574.05273 2.63800e-2 15.14349 Chloride Totals : 29.77773

**:=::o;=:=.===========·=o:o.·.~-:C""-""'=============-"'."."O:=========o:::.:c.;=================~o='-"** 

### .. === 

### *** End cf Report 

### ***

IGG 

### EA# 0910-96 Page 

### 159 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGj'o'NlJB486 1 of 1

## ( Sample Name: HPLC53pg98 #5 BORAL BRICKS 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed**An~lysis** 

### Method Last changed EO Seq. Line 

### Hr Burns Location 10/3/2010 3:36:20 AM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/l/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\MET!!ODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by 

### IGG (modified after loading) 74 2



### ·--·-··---·· ADC1A-:-.A.-t5C1CHANNEL A (U:\HPLC201004\MR 

### BURNS\DATA\6CT\HPl.C53PG98\005-7402--:-D)---- -------------- 

## ---·j

External Standard Report**==============~=~==========================~=========================** 

### Sorted 

### By Calib. Data Modified Multiplier Dilution Signal 10/4/2010 9:26:06 AM 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/P..rea Amount Grp Name

[min} [uS/crn*s] [ug/mL] 

## -------l------l----------:----------l----------l--l------------------ 3.148 

### BB 853.39844 1.70850e-2 14.58031 Fluoride 4.268 BB 574.29498 2.63799e-2 15.14985 Chloride 

### Totals : 29.73016



### ••• End of Report ***

Ins t rumen tAlc

## jb~611iefl~Q.**plj(j'J~2** 54 AM I GG

## EP~~[R**O~J~~-~gNPT'i&"r ~~~~~~$** **2** 

### AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGi!'fl!i.6187 1 of 1

### Sample Name: f!PLC53pg98 #SS BORAL BRICKS

**====~=====~=~=~======================================================** 

### Acq. Operator Acq. Instrument 

### Injection Date Acq. Method Last changed Analysis Method Last chang.ed 

### EO Seq. Line 

### Mr Burns Location 10/1/2010 8:13:01 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M 10/4/2010 9:26:06 AM by IGG 

### (modified after loading) 7 

### 1 

# r--- -
.A-DC fA-: "AD-c·f-C'HAf\iNEL- X"{U:WfPCC20T6-Q4\MR 

### BORNS\bAt-A\OC'RHPLC53PG98\006-0701 

### .D)

· uS/em 

### l I 180 -=1 

### 1



# :::~ 120- 100- 80 60 

# " "' '§

**~** 

### u: N 

## 21 

# "'



# .

" :g 0 

### :c (.)



### External Standard Report ============================'=""===============================""=====,,= 

### Sorted 

### By Calib. Data Modified Multiplier Dilution 

### Signal 10/4/2010 9:26:06 AM 1. 

### 0000 1. 

### 0000 Use Multiplier & 

### Dilution Factor \oJith ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] 

### [uS/cm*sJ [ug/mLJ 

## -------l------l----------l----------l----------l--1------------------ 3.105 BB 75.83907 1.69672e-2 1.28678 Fluoride 4.255 BB 89.04053 2.69605e-2 2.40058 

### Chloride 'Totals : 3.68735
*** End of Report *•*

Instrument 

## AircWctJ.E£<HJl> ll-1ilf.!.212 AM 

### IGG



## E~~~~~~9s~~o~~~~T

**?~ °}E~~**  **2** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGE~488** 

### 1 of 

### 1Sample Name: HPLC53pg98 #SS BORAL BRICKS
**====~================================================================** Acq. Operator 

### Acq. Instrument Injection Date Acq. Method Last changed 

### Analysis t1ethod Last changed 

### EO Seq. Line 7 

### 2



### ==========================================·-=====,===-·======--=========== External Standard Report 

### ==============•-"====================================================== Sorted By Calib. Data Modified 

### Multiplier Dilution 

### Signal 10/4/2010 9:26:06

**AI~** 1.0000 1.0000 

### use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL 

### A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL} 

## -------l------l----------l----------l----------l--l------------------ 3.109 

### BB 75.80476 1.69671e-2 1.28619 Fluoride 4.259 

### BB 89.01553 2.69607e-2 2.39992 Chloride Totals : 

### 3. 68611

**====:============::o~===;.co"-'==""""================="-"=<==~·"·"'"'-'~==-c=======""========**

***~*** End of Report 

### ***

10b41 

## o g 28 

### EA#0910-96 Page 162of202 InstrumentAtC PR



## JEi:f~o. 

# P-ioH:i 20 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 Paqe 1 of 1 APPENDIX PAGE NO. 489

### Sample Name: HPLC53pg98 

### #3 BORAL BRICKS
**======================~=======================~======================** 

### Acq. Operator EO Seq. Line 17 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 12:19:37 AM Inj 1 Acq. Hethod C: \HPLC2 010Q3 \HR BURNS\HETHODS \t-!ETROHH .H 

### Last changed 4/l/2010 4:15:36 PH Analysis Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98 .M 

### Last changed 10/4/2010 9:39:38 AM by 

### IGG ADC1 A. ADC1 CHANNEL A (U:\HPLC2010041MR BURNS\OATAiOC'f\HPCC53PGSBi1DD--:fio1:0)-··-····- ·-----1 

# i uS/em 

# l ;::!



# :::j 1 ,I 

### 140 120



## ===================================================================== External Standard Report
**===•====::::-"":<"C;:::~-,..=~-::==::...--:,-:::..""O~"======"'"•================================::::::::::::::::::::=::::=::::::::** Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal 

### 10/4/2010 9:36:48 AM 1.0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNE'.L A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/crn*s] [ug/mLJ 

## -------l------l----------l----------l----------l--l------------------ 3.115 BB 

### 305.79456 1.70644e-2 5.21821 Fluoride 4.253 BB 

### 183.50085 2.66068e-2 4.88237 Chloride 

### Totals : 10.10057 

## ===================================================================== *** End of 

### Report 

### ***

"nstrument l 10/4/2010 10:05:55 AM IGG EA#0910-96 Page 163of202 

# I

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT 

### Page 1 of 1 APPENDIX PAGE No. 490 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010

### Sample Name: HPLC53pg98 i3 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 17 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 12:31:57 1\M 

### Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM**.~nalysis** 

### Method U: 

### \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98. M Last changed 10/4/2010 9:39:38 AM by IGG ··-·A.ocTA;"i\6C1

### cRA."ffNECA"(ul"H?Itzo·'=,::Coa;c4"1"M~R"BC'uf.oR"N;;S;:o\D~A"T'"'A'"Io"'c"'T"'I"H"PL"c"s'"3"'P""G~9~8\**1D"'o~-1~7'"o~z•.o~)---** uSfcm 

# l ::l "l 

# 'i i I 

# !**================================~=::::o.:o=""""'==============================** External Standard Report**========================================================="""""'"="'~=======** 

### Sorted By Calib. Data Modified 

### Multiplier Dilution Signal 

### 10/4/2010 9:36:48 AM 1.0000 

### 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADC1 CHANNEL A Ret.Time Type Area Amt/Area Amount Grp Name

[min] [uS/crn*sJ [ug/mLJ 

## -------l------l----------l----------l----------l--1------------------ 3.115 BB 305.05637 1.70643e-2 5.20559 Fluoride 

### 4.254 BB 182.77678 2.6608le-2 4.86334 Chloride Totals : 

### 10.06893 

### *** End of Report 

### ***

IGG EA#0910·96 Page 164 of202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

### PAG~~\1°491 1 

### of 1

### Sample Name: HPLC53pg98 i3 BORAL BRICKS ==========================''"==:<:·===""=====""""=========""================== 

### Acq. Operator EO Seq. Line 

### 29 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 6:45:00

**~I** 

### Inj 1 

### Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/l/2010 4:15:36 PM Analysis Method U: \HPI,C2010Q3 \MR BURNS\METHODS\HPLC53PG98 .M Last changed 10/4/2010 9:39:38 AM by IGG 

# 1 Aoc1 A. Aoc' cHANNEDqrr>H-rcc2oToo4\MifiiFRfJs,oiltAiocnfii'l."cs:lPG9s\1oo.29o1 01 

## ' uS/em 

### j 180-j 160 

# j j 140



# ~ 120 j



### ~

**100~** i

**80~** 

## 1 60 

# -l 4



### 40~ i

**~** 

# 20i

**~**

**~** N 0

**t:--~J** 

# ..._ ,r 2

**========,:=====:'='====================='"·===~.,==============================** External Standard Report ===============-==================:========================:====.o..,====== 

### Sorted By 

### Calib. Data 

### t1odified Multiplier 

### Dilution Signa 1 

### 10/4/2010 1.0000 1.0000 9:36:48

**A~1** 

### Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal l: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/crn'*s] [ug/mL] 

## -------l------!----------!----------!----------!--l------------------ 3.117 BB 305.44266 l.70644e-2 5.21219 Fluoride 4.257 BB 183.08054 2.66076e-2 4.87132 Chloride Totals : 

### 10.08352 

### *** End of Report 

### ***

InstrumentAk



# ~~6.1!f&flil.9 **plilJ~~p:** 14 AM



# IG~p;~C~ **g~~gN~~~~ !~~J~~~z**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGEfN>9'492 l 0 f l

### Sample Name: HPLC53pg98 #3 BORAL BRICKS 

### Acq. Operator EO Seq. Line 29 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 6:57:20 AM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/l/2010 4:15:36 PM Analysis Method U: 

### \HPLC2010Q3 \MR 

### BURNS\METHODS\HPLC53PG98. M 

### Last changed 10/4/2010 9:39:38 AM by 

### IGG**;-··--··-----Ai5C1--Ii~ADCTCHANNELA(UIHPLi"czi.o,:;1;;0"0""41C:Mi;'R;,B,;;U7,R"Ni.s'i\D;iA~T"A"'I"O"c"'n""H"'P""LC"s'"3"P"G'-'9"'81'"'1"00""·""29"o'"zc-,.D""J~~~~~...,** 

### i

### uS/em-~**~** 1 180-1

# 160~ " 

# " "0**-~** 0**~** 

## u: 

# " 

# "' 0 E {.)**---~-6-----··-----~-8**___________ 10 

### External Standard Report**====:========================================================~=======** 

### Sorted By 

### Calib. Data Modified Nultiplier Dilution Signal 

### 10/4/2010 9:36:48 AM 

### 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] fuS/cm*s) (ug/mJJ] 

## -------l------l----------!----------l----------!--l------------------ 3.116 BB 304.76215 1.70643e-2 5.20056 Fluoride 4.257 

### BB 182.93237 2.66078e-2 4.86743 Chloride Totals : 10.06799 ===============================================""'====;;-'"""='-"'""•'='"====::-..:=====- 

### *** End of Report 

### ***

IGG EA# 0910-96 Page 166 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

### PAG~'me 493 1 of l

### Sample Name: HPLC53pg9B #3 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 

### 41 Acq. Instrument Mr Burns Location 

### Injection Date 10/2/2010 11:40:56 AM Inj l 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHH.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed 10/4/2010 9:39:38 AM by 

### IGG 

## 1··· .._ .......... ADC 11\:-Aoc 

### f CHANNELA (U:IHP"'L"'c"2o"-1;;;o:r;a""41ii-Mi'cR;,Boiu"iiR'"N"'s"''"o"AT"'A;;;\"o"'c"'T"'IH"'P"L"c""s3"P"G"9"a"' 1"1"o.'4 7 1o"-1".o"'),.- us/cm 

### l I 11;

1ao

## ~ I

## ~ 160 140- 120 100



### Sorted By 

### Calib. Data Modified Multiplier Dilution External Standard Report Signal 

### 10/4/2010 9:36:48 AM 1.0000 1. 

### 0000 

# I , 

# I

Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADCl A, ADCl CHANNEI, A RetTime Type Area Arnt/Area Amount Grp Name

[min] 

### [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.129 

### BB 305.45007 1.70644e-2 5.21232 Fluoride 4.268 

### BB 183.04117 2.66076e-2 4.87029 Chloride Totals : 

### 10.08261 

## *** End of Report 

## ***

Instrument ArcWo'!if:e9W.. 

## f1_q 

# 0 Jl4!2' so AM IGG 

### EA# 0910-96 Page 

### 167 of 

### 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010

### ( Sample Name: HPLC53pg98 i3 80RAL BRICKS 

### Acq. Operator EO Seq. Line 

### 41 Acq. Instrument Mr_Burns Location 

### Injection Date 10/2/2010 11:53:15 AM Inj 2 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\HETHODS\HPLC53PG98.!-l Last changed 10/4/2010 9:39:38 Al-l by 

### IGG ADC1 A. ADC1 CHANNEL A (U:IHPLC2010Q41MR
**BURNSIDAfAIOCTIHPLCS3PG98\1\64i02~D)·-···-** ······-··--, uSicm 

# l

180 

# j 160 140 120 100 

# I i 

# i

==========,=============""'""""======""""-"=================================== External Standard Report 

## ===================================================================== Sorted By Calib. Data Modified Multiplier 

### Dilution Signal 

### 10/4/2010 1.0000 1.0000 9:36:48 AM 

### Use Multiplier & 

### Dilution

**:~:~actor** 

### wi·th ISTDs 

### Signal 1: ADCl A, ADC1 CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### {min] {uS/cm*s] {ug/mL] 

## -------l------l----------l----------l----------l--!------------------ 3.119 BB 

### 304.57260 1.70643e-2 5.19732 Fluoride 4.259 BB 

### 182.35q86 2.66089e-2 4.85226 Chloride Totals : 

### 10.04957 

## ===:==========================="'-'""'=,..,==-=========::=c:==""====================

***~*** End of Report 

### ***

InstrumentA-fcf>\ll6Uil-Jl/.J9.



# p.9o,C4~: 00 AM



# IGGEP~gRo~J:;;~I~:T~SeT~~~~g~ **2** AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAGf¥~ij.'l\gs** 1 

### of 1

### Sample Name: HPLC53pg98 #3 BORAL BRICKS 

### Acq. Operator EO Seq. Line 53 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 5:36:34 PM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M Last changed : 10/4/2010 9:39:38 AM by IGG ADC1 A,-

**AoC1c8Ai~fNET-A(iJ:\HPLC201 OQ4H~Ff**  BURNS\DATA\OCT\HPLC53PG98\11 0·5301.0) --------------

**--~-1**



# us:::~ ;1. ]



# 1601 ! ' 140 

### ·j 120 

# -l 100 --=1 1 .: en



### - :g J 

## g

**~** 80-J 

## u: g 1

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# 40~ M



# ~

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### ~ 

## l \ f'; 

### c; O 

## 0?

**~** I ..,

**~** j\ /1 ";!:_ c0 CD cci j ! 1 -! ______ 

### ;c:! J ' I \ ll>

**...--~,** /....,____ • ; 

### o , ·-j --- **-..:~·--;.::.~~.:,::::.c:;...=.:~-~-t:~.-r:.: ---~~-=·:,:._-:-____:;::::.c~=::::::.:_t::~** 

## . **.:--~-,-----,---.----.------,**

# ---,----! '-------··£ ___________________:1______ 6 ______________ § ________ 1_0

### ----------·-········--l?.... _____ **~** 

### ==================================================:==.,=======::-:o========
Sorted 

### By 

### Calib. Data Modified Multiplier Dilution 

### External Standard Report Signal 

### 10/4/2010 1.0000 1.0000 9:36:48 AM 

### Use Multiplier & 

### Dilution !?actor with ISTDs 

### Signal 1: ADCl 

### A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount 

### Grp Name

[min] 

### [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.121 

### BB 306.69925 1.70645e-2 5.23367 Fluoride 4.260 

### BB 183_57710 2.66066e-2 4.88437 Chloride Totals : 10.11805 

### *** End of Report 

### ***

IGG EA# 0910-96 

### Page 169 

### of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX



### PAG~"M\e 496 l of lSample Name: HPLC53pg98 #3 BORAL BRICKS 

### Acq. Operator EO Seq. Line 53 Acq. Instrument Mr Burns Location Injection Date 10/2/2010 5:48:53 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BORNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM 1\nal ys is Method U: \HPLC20 10Q3\MR BURNS\METHODS \HPLC53PG98. M Last changed 10/4/2010 9:39:38 1\M by IGG ADC1 A. ADC1 .CHANNELA"(U'IfiPTC20filQ.i\MRBURNS\DATAIOCT\HPLC53PG981 110-5302D) uS/em --1



# 1801 160 

### -i 

# i 140 

### -j 120

# ~ 100

# ~**~** 0

# ~ I 

# I

External Standard Report 

### --==·==========::::=-============:o===:::-·======================================= Sorted By 

### Calib. Data Modified 

### Multiplier Signal 10/4/2010 9:36:48 1\M 1.0000 

### Dilution 1.0000 Use Multiplier & Dilution Factor with ISTDs Signal 1: 1\DCl A, 1\DC1 CHANNEL 1\ RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] (ug/mL] 

## -------l------[----------l----------l----------[--l------------------ 3.120 BB 305.72400 1.70644e-2 5.21700 Fluoride 4.261 BB 182.98579 2.66077e-2 4.86884 Chloride 

### Totals : 10.08584 =================,=================""============::::=.:========='='====="'=""== 

### *** End of Report 

## "' ~**  

### 1.Cl64.12.m.n.:JCl.·.no 18 1\M IGG 

### EA#0910-96 Page170of202 Instrument AtC l"r<

### J~CrNo.**t"'M~Z:** EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGe'iil\1"497 l of 1

### Sample Name: HPLC53pg98 #3 BORAL BRICKS**===============================================~=================~===** 

### Acq. Operator EO Seq. Line 

### 65 Acq. Instrument Mr Burns Location 

### Injecti.on Date 10/21201011:32:07 PM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method O:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG98.M La_s_t_ .. changed 10/4/2010 9:39:38**~.M** 

### by IGG ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG98\120-6501.D) 

# us:::i**~**

160.

# 1 .I 140--!

## ~ 

# ! 120

### '~. '

# ~ \ 100--i 

## J 

# ! 80 -i 

# '

===================================================================== External Standard Report**==========o~=""==""==-~==.,,..,========"-"=================::o::====================** 

### Sorted By Calib. Data Modified 

### Multiplier Dilution 

### Signal 

### 10/4/2010 9:36:48 AM 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1; ADCl A, ADCl CHANNEL A 

### RetTLme Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--1------------------ 3.123 BB 310.41275 1.70649e-2 5.29716 Fluoride 4.263 BB 185.78922 2.66027e-2 4.94249 Chloride Totals : 

### 10.23965



## =====================================================================***~*** End of Report 

### ***

EA#0910-96 Page 171 of202 IGGEPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAG~'I-£e498** 1 of 1

### Sample Name: HPLC53pg98 #3 BORAL BRICKS 

### Acq. Operator EO Seq. Line 

### 65 

### Acq. Instrument Mr Burns Location Injection Date 10/2/2010 11:44:27 PM Inj 

### 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis**l~ethod** 

### U: \HPLC2 010Q3\MR BURNS\METHODS\HPLC53PG98. M Last changed 10/4/2010 9:39:38 AM by IGG

### ~-----~------AoCTA.-A.bc 1 

### CHANNEL A{U:\HPLC2o

### f064\Mi3R'sii'uilR"Ni.s3i,iio:i;A"T"A"Io"c~n=H"P'Lc""s3"P"'G"9"'a"'"'2"o"-6"'s"o'"2'.o"l--------·-~ I t 

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### 100-~**~** 

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### M~**~ ~** **~** G:

### ~ 

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# I 1 l ,.... ;'\ v- v- I 20

# ~ f i 

## r\ g '"":

# ~**~** I 

# i

0

# J.:=-,=~--~-__:

# __**~-~-~~::** 

# ..**_:_.:_-,~L:::.-.=-~_-··--_·_' ~~_,,_-~_--,-~---"_-.,.'-.1**  /_"_

..

# _·-_._·-~~ ..

# "---/-~~----:~--'_1__._._-·T· i
___ 

# I**~-** 

### · · ··--·-r----..,..--·-i ---------------------2 __________ 4 ______________ 

## 6__________________ 8 10 12 mi'**-----~----~~~**



### Sorted By 

### Calib. Data Modified Multiplier Dilution External Standard Report 

### Signal 10/4/2010 9:36:48 

### AM 1.0000 l. 

### 0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal l: ADC1 A, ADC1 CHANNEL A RetTime Type Area**f~t/Area** 

### Amount Grp Name

[min] [uS/cm*s] [ug/rnL] 

## -------l------)----------)----------!----------1--l------------------ 3.122 VB 310.73752 1.70649e-2 5.30271 Fluoride 

### 4.263 BB 186.29073 2.66018e-2 4.95567 Chloride Totals ; 10.25838 

### *** End of Report 

### ***

IGG EA# 

### 0910-96 Page 

### 172 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGEN\!e499 1 of 1

### ~~=~~=""=====~=~~=~~~~~================~==!lQm!l~==~============== 

### Calibration Table **============~============~===================~=======================** 

### Calib. Data Modified Calculate Based on Rel. Reference Window Abs. Reference Window Rel. Non-ref. Window Abs. Non-ref. Window 

### Use Multiplier 

### & Dilution Uncalibrated Peaks Partial Calibration Correct All Ret. Times: 

### Curve Type Origin Weight Recalibration Settings: 

### Average Response Average Retention Time: Calibration Report Options 

### 10/5/2010 9:18:49 AM 

### External Standard Peak Area 

### 10.000 

### %

0.000 

### min 10.000 

### %

0.000 

### min Factor with ISTDs 

### not reported Yes, identified peaks are recalibrated No, only for identified peaks Linear Connected l,inear ( Arnnt) 

### Average all calibrations Floating Average New 75% Printout of recalibrations within a

**se~uence:** 

### Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with 

### bracketing: Results of first cycle (ending previous bracket) 

### Signal 1: ADC1 A, ADC1 CHANNEL A 

### RetTime 

### Lvl Amount Area Amt/Area Ref GLp 

### Name

[min] Sig [ug/mL] 

## -------l--1--l----------l----------l----------l---l--1--------------- 3.149 1 1 2.00000e-1 9.95712 2.00861e-2 Fluoride

4.153 1 

### 2 

### 1.00000 61.11817 l.63617e-2 3 5.00000 308.63791 l.62002e-2 4 10.00000 589.09669 1.6975le-2 5 15.00000 849.33438 1.76609e-2 1 

### 2.00000e-1 5.66901 3.52795e-2 Chloride 

### 2 1. 

### 00000 33.68365 2. 

### 96880e-2 3 

### 5.00000 182.2.7121 2.74317e-2 

### 4 10.00000 369.59518 2.70566e-2 5 

### 15.00000 562.35474 2.66736e-2 **='-~"'---"o===,·==o:'=='""==""====='''"""''="''================~====='""-'=:;o;=;;;;::::==============** 

### Peak Sum Table ***No Entries in table*** **==============================:o---'-"'"=""=.·.oo===============,-===:oo=:=:=====-=~=====**



### , EA# 0910-96 Page 173 of 202 IGG EPA ICR EMISSION TEST PROJECT

AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGJ!'!'lS.E$00 1 of 2

### ~~~~~~~~~~~~~~~~~~~~~-~~~~~~~~~~~~~~~~~~~~-~~l~~~~~g======~~~====~--~ Calibration Curves

**'ft:ffiaT----------------------~r/l**



# 500~ / 400- // k 300 //// 4 200-- 

# _y/ / 100' / 2/ ,,;.f- 0

**-------,----~------.--·---,---.------,---·,-·i**

0 10 i

______ _i_A\[m!)!OQ!Uill]nl[yg/miJ__

_________ _______ 

## ! Fluoride at exp. RT: 3.149 

### ADCl A, ADCl CHANNEL A Correlation: Residual Std. Dev.: Formula: y = 

### mx 

### + b 

### m: 58.36617 0.99933 18.30415

**~:** 

### -5.76052e-1 

### x: Amount 

### y: Area Calibration Level 1 

### Level 2 Level 3 

### Level 4 Level 5 Level Weights: 

### 1 0.2 0.04 0.02 0.013333 Chloride at exp. RT: 4.153 

### ADC1 A, ADCl CHANNEL A Correlation: 0.99993 Residual Std. Dev.: 3.24460 

### Formula; y = 

### mx + 

### b m: 

### 37.31718 b: -2.14447 x: Am.ount 

### y: A.rea Calibration 

### Level

**Weights~** 

### Level l 1 Level 2 

### 0.2 Level 

### 3 0.04 

### Level 4 

### 0.02 Level 5 0.013333 -:==::.::=======""-<".::=•:============================================""==========



### Instrument A'rCJMt:JiJE{;i;:t.Jl,



## Fl-~oil\24 9 AM I GG



## EP~g,n~?s~?or.\'~~MJ~o~~~~z AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

## APPENDIX PAGieii{J>e501 2 of 

## 2Sample Name: HPLC53pgl00 #1 BORAL BRICKS 

### Acq. Operator EO 

### Seq. Line 

### 2 Acq. Instrument Mr Burns Location Injection Date 10/4/2010 2:22:30 PM Inj 1 Acq. Method C: \HPI.C2 010Q3\MR BURNS\METHODS \METROHM. M 

### Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M Last changed 10/5./2010 9:16:05 AM by. IGG uS/em 

# J ADC1 A. **ADC.1CHANNETA(iJWPLC2010Q4\~1RBURNS\DATAiOcnHPLCS3PG1DO\ooT:o2oT~---·** 

# --·1

180. ! 

### 160 140- 120- 100 .

80 

### 60. 40 

### 20 0


### External Standard Report ==:;::======================================·=========::===::.:========="'"·""==== 

### Sorted By Signal Calib. Data Modified Tuesday, October 05, 2010 9:15:59 AM 

### Multiplier 1.0000 Dilution 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNEL A RetTirne Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------!----------l----------l--l------------------ 2.990 MM 9.55972 1.80226e-2 l.72291e-1 Fluoride 4.157 BB 5.61364 3.70342e-2 2.07896e-1 Chloride 

### Totals : 3.80187e-l ===============================================:·===-,========""=======::::== 

## *** End of Report 

## ***

**~ 1.JlL~L2!l**  

### n .r; J.<' 

### EA# 0910-96 Page 175 of 202 Instrument AtCt'I<U;ltot: 

## r No. l'"-iiJ1"2 41 AM IGG EPA ICR EMISSION TEST PROJECT AUGUST A PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI!'fi0e502 1 of 1

### Sample Name: HPLC53pgl00 #l BORAL BRICKS 

### ================================-=====,==============================·'= Acq. Operator EO Seq. Line 2 Acq. Instrument Mr Burns Location Injection Date 10/4/2010 2:34:50 PH Inj 2 Acq. Hethod C: \HPLC2010Q3\MR BURNS\HETHODS\METROHM.M I.ast changed 4/1/2010 4:15:36 PM Analysis Method U: \HPLC2010Q3 \MR BURNS\METHODS\HPLC53PG100 .l'l Last

**~hanged** 

### : 10/5/2blO 9:16:05 AM by 

### IGG

**~-------·----p,ocTA,-Ai5cTcRii"NNEL** A (U:IHPLC201 004\MR BURNS\DAT AIOCTIHPLC53PGfOD\D0-1 -02ifi:i5j--
. -- ··- ---- ·1 

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# 60~

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# .**""[~~_::'"-~-~~-=-~·** ·,;;;_

**===========:::::============-=:.===::-~=-=============================·===~-"="=""==:=** 

### External Standard Report 

## ===================================================================... == 

### Sorted 

### By Signal Calib. Data Modified 

### Multiplier Tuesday, October 05, 2010 9:15:59 AM 1.0000 

### Dilution 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type 

### Area

**&~t/Area** 

### Amount Grp Name

[min] !uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--!------------------ 2.985 VB 10.01584 1.80226e-2 1.805lle-l Fluoride 

### 4.150 MM 

### 5.87644 3.65764e-2 2.14939e-1 Chloride Totals : 3.95450e-l

**=====================-==-e==-===~~"'c~==============================''""""-'='-""'=="'** 

### *** End of 

### Report 

### ***

Instrument



## A:tc:W~dill~~na 1'-lil-fll255 AM IGG 

## EP7,~grf~~?s~forf-i'~~N~o5~~~ **2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PAG~<Ni>e503** 1 

### of 1Sample Name: HPLC53pgl00 #1 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 14 Acq. Instrument Mr Burns Location Injection Date 10/4/2010 7:38:19 PM Inj 1 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM. M Last changed 4/1/203.0 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M Last changed 10/5/2010 9:16:05

**P~J** by IGG 

# r --· --·-ADCTA-;-Abci"·CHANNEL A (Uc\HPLC201004\MR BURNS\DATAicicTiHPLC53PG100\001·1401.D) uS/em 

# l

180 1 

### l; 160



### __:~ 140.1 

# l 120....! 

# 1 100

**-~** ·i < 80 ·:

**=======================-~===================~.,==========================** 

### External Standard Report **========~.=o~===,===================:=:::============''"============='==========** 

### Sorted By 

### Calib. Data Modified Multiplier 

### Dilution Signal Tuesday, 1. 0000 

### 1. 0000 

### October 05, 2010 9:15:59 AM 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Arnt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------j----------l----------l----------l--l------------------ 2.991 MM 10.05413 1.80226e-2 1.8120le-l Fluoride 4.154 

### BB 5.65120 3.6966le-2 2.08903e-l Chloride 

### ToT:als ; 3.90104e-l

**===~'~-,=="""='==--==-==========""·:oo-.======================-c=======,===o.:o""==========** 

### *** End of Report 

### ***

EA# 0910-96 PaQe 177 of 202 Instrument Alrclffidi.JE?;lf+Jl,.



### ~-1ef4~l O AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 **APPENDIXPA~504** 1 of 1Sample Name: HPLC53pg100 #1 BORAL BRICKS**================================:=================~==================** 

### Acq. Operator EO Seq. Line 

### 14 Acq. Instrument Mr_Burns Location Injection Date 10/4/2010 7:50:38 PM Inj 2 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis .Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100 .M Last changed 10/5/2010 9:16:05 AM by IGG ADC1 A. ADC1 CHANNEL A (U;\HPLC2010Q4\MR BURNS\DATA\0CTIHPLC53PG1001001·1402.D) uS! em 180 160 140 120**~ ===========================================================~=========**  External Standard Report 

## =====;=============================================================== Sorted By Calib. Data Modified Multiplier Dilution 

### Signal Tuesday, 1.0000 1. 0000 October 05, 2010 9:15:59 AM 

### Use Multiplier & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/ em's] [ug/rnL] 

## -------l------l----------j----------l----------1--l------------------ 2.989 VB 10.19880 1.80226e-2 1.83809e-1 Fluoride 4.153 MM 5.53477 3.71800e-2 2.05783e-l Chloride 

### Totals : 3.89592e-l**====,=========""'=·"-'======o-.===::-..o======~===========:======================== ~** ** End of Report 

### ***

Ins trumentAtC

## )?~O'li!~ili116. Pl-101'422 5 AM IGG

## EP~~!R**~Jif~1~J'i'E'!fT VR~~~~~z**  AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAGIF~0~05** 1 of 1Sample Name: HPLC53pgl00 #2 BORAL BRICKS**========================================================~============** 

### Acq. Operator EO Seq. Line 3 

### Acq. Instrument Mr Burns Location Injection Date 10/4/2010 2:47:11 PM Inj 1 Acq. Method C: \HPLC2010Q3\MR**BURNS\METHODS\~lETROHM.M** Last changed 4/1/2010 4:15:36 PM Analysis t<lethod U; \HPLC2010Q3 \MR BURNS\METHODS\HPLC53PG1 00. M Last changed 10/5/2010 9:16:05 AM 

### by IGG



### -**--~-Aoc1A.ADC1CHANNELA** (U \HPLC2010Q4\MR BURNS\OATA\OCT\HPLC53PG100\002-0301 

# Dll

uS/em

### ~ 

# I g

18o, I 

# 1
l I 

# 160] I 1 140 .: I 

# II j 

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## l i 80. 60 

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### --------1:::::-1~~**----i-~-r.=-.-....--** -.:------r-·

### "-...:.:---''-'--··',c__~-~, -"·---------'6'----**-·-----·-··----------------------~--------------.-------.l!!!.D:** 

### External Standard Report**=====""·""'=":::::::=;==~======-===================='='===================~========** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal Tuesday, October 05, 2010 9:15:59 

### AM 1. 0000 1.0000 

### Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area**&~ount** 

### Grp Name

[min] [uS/em's] [ug/mLJ 

## -------l------j----------l----------]----------l--l------------------ 3.114 VB 62.22894 l."l2918e-2 1.07605 Fluoride 4.258 BB 34.35212 2.84702e-2 9.78010e-l Chloride 

### Totals : 2.05406**=<"-'·~-"'~'·"'"·=='-""'~~====~..,==============""~"'="'-~====:=================;o==>"~"'-·===========** 

### *** End of Report 

### ***

Instrument 

## M-clfiRf<yJ&tW,_

## t9-~il¥4219 AM IGG

## EP~g~~~?s~?o~¥~~TV~o~fE~~**2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGI!iffiJe506 1 of 1UdLd J:: .l-.J.!:c! u; \flrL1...-£.U.J.UI,('i \lvlr\ DU.t'\LV;:l \Ul"\..1-l"\.\VI...-.1-

**\Dr.Lti...-:..I..Jr>.:~.J.UV** \UVo<:.-U.JVo<:, ,,u Sample Name: HPLC53pg100 *2 BORAL BRICKS 

### Acq. Operator EO Seq. Line 3 

### Acq. Instrument Mr Burns Location Injection Date 10/4/2010 2:59:30 PM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 

### Last changed : 

### 10/5/2010 9;16:05 AM by IGG 

# I .------·--·-ADC1 A. ADC1 CHANNEL A (U:IHPLC2010Q4\MRElURNSIDATAiOCTif·iP-LC53PG100\002·D302.D) .

**-·-·;::~·.** uS/em "J :::= .1 

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# J'_.~_··~_- **,-~}:·_~·~~-~":.~~~~~1~~~-:::~--_**

# _ **_-~_r_J, ~~~-~!.:::d**  External Standard Report

**============""========================================-·=~==============** 

### Sorted By Calib. Data Modified Multiplj_er Dilution Signal Tuesday, October 

### 05, 2010 

### 9:15:59 AM 1.0000 

### 1. 0000 

### Use Multiplier 

### & Dilution Factor with ISTOs Signal l: ADC1 A, ADC1 CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp 

### Name

[min} [uS/cm*s] [ug/n:L] 

## -------l------l----------l----------l----------l--1------------------ 3.115 BB 59.91656 l.72979e-2 1.03643 Fluoride 4.257 BB 32.97707 2.85399e-2 9.4ll63e-l Chloride 

### Totals : 1. 97760

**==""""============''""-"'-"''""==.:=.::====""""'""'""='==========o:========~""=""·""'~==="-"'-""========**

**~  

### End of Report 

### ** *

InstrurnentAICPRPgllClJIIJB. 

### Plt01fU28 l\11 IGG



## EP~gRO~Jfl;§ **~~N£eT ~SR~~te~**  **2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGIFNO.e507 l of 1.... 

### -

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## ... 

## '..........

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# ....... ...., 

### Sample Name: HPLC53pg100 #2 BORAL BRICKS 

## ===================================================================== Acq. Operator EO Seq. Line 

### 15 Acq. Instrument 

### Mr Burns Location 

### Injection Date 10/4/2010 8:02:58 PM Inj 1 

### Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M Last changed 10/5/2010 9:16:05 AM by lGG 

### ADCTA. ADCf"CHANNel A(U:\HPLC201004\MR BURNS\DATA\ocnHPLC53PGT60\0o2-151)f"6)
__ _



# uS~:l

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## :ri :=6 : / _,N_.. J_::c:,___ ... _l ___ L/':'-..__ __,------------,j_ 

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**..---------,---------~--------** L_ ___ , ·---- .. 

## L_________ 4 .... _ ..____.§_....... •..§ ___ ·--- .....- .• ml

**========================~=============~==============================** 

### External Standard Report

**===============================~=======================~=========~===** 

### Sorted 

### By Calib. Data 

### Modified Multiplier Dilution Signal Tuesday, October 05, 2010 9:15:59 AM 

### 1. 0000 1.0000 Use Multiplier & 

### Dilution Factor with IS'l'Ds 

### Signal 1: ADC1 A, ADC1 CHANNEL A RetTirne Type

**-~rea** Amt/Area Amount 

### Grp Name



### [min] [uS/cm*s] [ug/rnL] -------J------J----------1····--·-··I·········-J--I-·---------------- 

### 3.118 VB 62.23907 1.72918e-2 1.07622 Fluoride 4.267 BB 34.30110 2.84726e-2 9.76643e-l Chloride Totals : 

### 2.05287

**=============~='""''"'==o-o====o:..·=""=======================""'==============-:.::::o'"'""=** 

### *** End of Report 

### ***

!nstrument



## JilrcW~.ill-JNh.

**fi; 1J7,;~7**  AM IGG



## El~\~g~L~s~~o~~~~T **~~c\'Mc~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 

### SEPTEMBER 2010 

### APPENDIX

**PA~** 

### 508 1 of 

### 1lJdLd EJ.-1-t:::: u; \C"l.L.UV£..UJ.U\,.o!"t\1.U'\ UVnL'fU\LI.l>.J.r'>.\VVJ. \U.I.J..J'-'JJJ.U.I-VV\UVL. .t.JU<...,._., 

### Sample Name: HPLC53pgl00 #2 BORAL BRICKS 

### Acq. Operator EO Seq. Line 15 Acq. Instrument Mr_Burns Location Injection Date 10/4/2010 8:15:17 PM Inj 2 

### }\cq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM. M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M Last changed 10/5/2010 9:16:05 AM by IGG

**----------AoC1-;\.ADCTi5'flAi{~iEL** A (U



### \H',:,.P;i-L;iC;i;20oi;1;i;Oi;Qc;c4\;'.M;,R;-B,;iUC;iR~N,O:S\~DC.A"TA"I"'O"'C"'n"H"P"L"C **53;;Po;Goc:1"0"'0ID=o2"'· 15"0"2"'.D)** 

External Standard Report

**=====================""===================================,.~===<========** 

### Sorted By 

### Calib. Data Modified Hultiplier Dilution Signal Tuesday, October 05, 2010 9:15:59 AM l. 

### 0 000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type P..rea Amt/A:r·ea Amount Grp Name



### [min] [uS/ern's] [ug/rnL] 

## -------l------l----------l----------l----------l--1------------------ 3.119 BB 60.08810 1.72975e-2 1.03937 Fluoride 4.268 BB 33.10430 2.85332e-2 9.44572e-1 Chloride Totals : 1.98394 

### *** End of Report 

### ***

Instrument A!C



## ~II'C1l1>16 l!l-Hlfll24 6 AM I GG



## EP't'}~RO~~Ps~tbJ-fl!\;'\ **\>!!fo9tt~ 2**  AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGH'akje509 

### 1 of 1

# ( Sample Name: HPLC53pgl00 #3 BORAL BRICKS 

### Acq. Operator EO Seq. Line 4 

### Acq. Instrument Mr Burns Location 

### Injection Date 10/4/2010 3:11:49 PM Inj 1 

### Acq. Method C: \HPLC2010Q3\MR**BURNS\METHODS\METROH~l.** 

### M Last changed 4/1/2010 4:15:36 PM Ana1ysi.s Method O:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG10D.M Last changed 10/5/2010 9:16:05 AM 

### by IGG 

# r em 

# l ADC1 A, ADC1 CHANNELA(tT\HPLC2tH004iMR BURNS\DATA\6cfiHPiC53PG1iio\Oo:i:o4oij:i)---- 1 -

### ~.· 

# l**80~** 

# l ql 

## 1 

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# II 1 

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# J :;, "C !_' 

# d u:: § 

# I 'I 60- 

### ' :c \!**~** 

### (,) j

Sorted By Calib. Data Modified Multiplier Dilution E.xternal Standard Report 

### Signal Tuesday, 1. 

### 0000 1. 

### 0000 October 05, 2010 9:15:59 AM 

### Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADC1 CHANNEL A Ret'Iime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------:----------l--l------------------ 3.123 BB 

### 308.96735 1.71652e-2 5.30347 Fluoride 4.252 BB 

### 182.23886 2.71126e-2 4.94098 Chloride Totals : 

### 10.24445
*** End of Report 

### ***

## InstrumentAtC~Ei:~N~.**~11Hl!253** AM IGG

## EP~RO~~?s~rb~f~gT~**Jo3~~~z** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAGE<Nll~510** 1 

### of 1

### Sample Name: HPLC53pg100 #3 BORAL BRICKS

**=============~=================================~=====================** 

### Acq. Operator EO Seq. Line 4 Acq. Instrument Mr Burns Location Injection Date 10/4/2010 3:24:10 PM Inj 2 Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM. M Last changed 4/1/2010 4:15:36 PM P.nalysis Method U: \HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100 .M Last changed 10/5/2010 9:16:05 AM by 1GG

**~** ADC1 A, ADC1 CHANNEL A (U:\HPLC.2(ff0Q4\MR
**BURNS\bATA\OCT\H?lC·5-iPG100\0(f:f-0462.D)-----.-~** 

### ' uS/cml / 

### ;t/ 1aoJ 

# i

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. 

# 'I 160j / I -1 I I I 1 I I I



## 140~ ' 

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**~- ~----J**  =====================================,=============================== External Standard Report

**=======o:·==::-===""'==============================~'-"'======================** 

### Sorted By Calib. Data Modified Multiplier Dilution Signal Tuesday, October 05, 2010 9:15:59 

### AM 1. 0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADC1 A, ADC1 CHANNEL 

### A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------j------l----------l----------!----------j--j------------------ 3.123 BB 308.16321 1.71652e-2 5.28970 Fluoride 4.251 BB 182.15358 2.71128e-2 4.93869 Chloride 

### Totals : 10.22839

**==========================,.=============""'""'""·~'"'=""'"""-======================** 

### *** End of Report 

### ***

'-""-'- L

**~** 

### EA# 0910-96 Page 

### 184 of 

### 202 Instrument



### AtC~CliJtC~W..I'l.~~-fli~Ol AM hG EPA ICR EMISSION TEST PROJECT AUGUST A PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX

**PA~'Nl#511** 

### 1 of 1UCl'-Cl 1: ..L..l.O:::: v

**~** \nr-.wv.:.

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### Sample Name: HPLC53pg100 #3 BORAL BRICKS 

### ===================================================================::= Acq. Operator EO Seq. Line 16 

### Acq. Instrument Mr Burns Location Injection Date 10/4/2010 8:27:38 PM Inj 1 

### Acq. Method C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M Last changed 10/5/2010 9:16:05 lili 

### by IGG

**----·~--·--ADC1A.-A1S'C1CHANNEL** 

### A (U:\HPLC201 004\MR 

### BURNS\DATA\ocT\HFi[C-s3P-G10moo3-1G01.

**~------·-··-·--~.,**

uS/em 

### -j :55 

# I -i cq I 

### 180-j 

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. ' 120--1 

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### ----·- _______ ;L _____ , ___,,_, ____,_ .....:4'!.'________ ,_6___________ 

## j

**·-·-------_!!11~**

**=========================::::===============================,,===~'""·"'"""===** 

### External Standard Report

**========================================~~========================~==** 

### Sorted By 

### Calib. Data 

### Modified Multiplier Dilution Signal Tuesday, October 05, 2010 9:15:59 N1 

### 1.0000 1.0000 

### Use f"lu.lt::i.plier & 

### Dilution Factor with ISTDs Signal 1: 

### ADCl A, ADCl CHANNEL 

### A RetTime Type Area Amt/Area Amount 

### Grp Name

[min] 

### [uS/crn*s] [ug/mL] 

## -------j------l----------l----------l----------l--:------------------ 3.127 

### BB 309.30249 1.71651e-2 5.30921 Fluoride 4.264 

### BB 182.42313 2.71123e-2 4.94591 Chloride 

### Totals : 10.25513

**=============·======-===~,.-=:===·'====,===========================""'="'0"-~-~,.--=o~~==--=-** 

### *** End of 

### Report 

### ***

EA# 0910-96 Paqe 185 of 202

**InstrumentAtc~ESlJMl. Pl1~-fll20**  **9** 

### AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

### 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGli'M!e512 1 of 1

### Sample Name: HPLC53pgl00 #3 BORAL BRICKS 

### Acq. Operator EO Seq. Line 

### 16 

### Acq. Instrument Mr_Burns Location Injection Date 10/4/2010 8:39:57 PM Inj 2 

### Acq.

**~lethod** 

### C: \HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHDDS\HPLC53PG100.M Last changed 10/5/2010 9:16:05 AM by IGG ADC1 A." ADC1 **CHANNELA(iJ:IHPLC2010041MRBUR"NSIDATAiOcnHPi:c53PGforiliio3:16oTBj-·--·-----~** 

### oi



# ~~ 180 j 

### j 160-=i 

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### ·,cr_-_-_ ..u __

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# -_-_·'--~---..:•-::::::-.,.~_/ ___

\_.______ 

# ·..:•~_ ..- __



# "_-_..:f_-_·~,---r-·=-_-._·-~--'-1 .._-r---.._

___

···-··_-_- --"--'·



# ~**___.....~,_,_**__ _ 

### ' 

## ' 

# i '

_ _..! __ 

# I! II 

# II 

# II i!l 

# '

2
**--·-··1··---~----------······---·-··!5-----~-----------** .. **------------S!:-------~-----------** mi

**===~=========~=======================================================** External Standard Repoxt
**=========================================~=================~=========** Sorted By 

### Calib. Data Modified 

### Multiplier Dilution Signal Tuesday, October 05, 2010 9:15:59 AM 1.0000 

### 1.0000 Use 

### Multiplier 

### & Dilution 

### Factor with ISTDs Signal 

### 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount 

### Grp Name



### [min] [uS/cm*sj [ug/mL] 

## -------l------l----------j----------j----------l--l------------------ 3.125 

### BB 308.11859 l.71652e-2 5.28893 Fluoride 4.262 BB 

### 182.26926 2.71126e-2 4.94179 Chloride Totals : 

### 10.23072 

### *** End of Report 

### ***



## lnstrumentAtCl?~ffli!Ci:lli\Jo i>J.1d1fil216 AM 

### IGG



## EP~gRO~J&-~~~J'fJ!,"T **~~ ~~~~**  **2** AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGi!'M!e513 1 of l

### Sample Name: HPLC53pgl00 #4 BORAL BRICKS

**==========~==~=======================================================** 

### Acq. Operator EO Seq. Line 5 Acq. Instrument Mr Burns Location 

### Injection Date 10/4/2010 3:36:29 PM Inj 1 Acq. Method C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M Last changed 4/1/2010 4:15:36 PM Analysis Method U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PGlOO.M Last changed : 10/5/2010 9:16:05 A."l by 

### IGG ·



### ---- **Aoc-fA~i\i5CfcH'i.>JNECA(O'Iiii'l.c2oToa41tlRB0RNsloAT**

### AIO"c"'T"'I"H"P"Lc"'s"'3'"P"G"1"'oo"IO"'o"4"·o"s"'o"1."'o")-----, uS/em

180- 

### 160 140 

# "' 120 u "§

**~** 

### 100 

### u::

**=======o"'-==<=,-~=====================;;o===================================** External Standard Report ====·""'====::==========================================""-'=""-'=============== 

### Sorted By Calib. Data Modified Multiplier 

### Dilution 

### Signal Tuesday, October 05, 2010 9:15:59 AM 

### 1.0000 1. 

### 0000 Use Multiplier & 

### Dilution Fact.or Y. 1 

### ith ISTDs 

### Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name



### [min] [uS/cm*sJ [ug/mLJ 

## -------l------l----------l----------l----------l--1------------------ 3.135 BB 587.12793 1.7l500e-2 10.06926 Fluoride 4.251 BB 369.45987 2.69528e-2 9.95800 Chloride Totals : 

### 20.02725

**=e:======="'~'-"'=="'-'"=======================================================** 

## *** End of Report 

### ***

**'ell."-'"~'"** 

### n -" '"- 2 4 G EA# 0910-96 Page 187 of 202 

### Instrument AtCffilXlttr NO. 

### t'-1u1'12 AM IG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, 

### SALISBURY PLANT 6 SEPTEMBER 2010 

# ~ I I 

# I 

# I' 

# II \I 

# 1 i

mlf1



### APPENDIX PAG§'me514 1 of 1

### Sample Name: HPLC53pg100 *4 BORAL BRICKS 

### ===================""'''"==""'=====-========================================

I I 

# I i Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed Analysis Method Last changed

180..: 160 140
- 120-. 

# I . 100c 80 

# I 

# I : 'N 20' 

# I 0 ......



### ~ <'oi

**~-----··----?....** 

### EO 

### Seq. Line Mr Burns Location 10/4/2010 3:48:49 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPJ.C2010Q3\NR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM 

### by IGG (modified after loading) 

### 5 2

**===========-======================~-"==,====""''"'===-:======-·====,.,=====-=======**


### Sorted 

### By Calib. Data Modified Multiplier Dilution 

### External Standard Report Signal 10/5/2010 9:18:49 AM 1.0000 1. 

### 0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug(mL] 

## -------l------l----------j----------l----------l--l------------------ 3.149 BB 590.64954 1.71499e-2 10.12959 Fluoride 4.265 

### BB 369.45181 2.69529e-2 9.95778 Chloride 

### Totals ; 20.08737

**-----·--;·,.==-"'-=====-=================~~·="'"'=~-'-'-'''"'='"'"·"'"'0""'"'·==** -'''""""·=='""'======""'=""===""= 

### *** End of

**R~port** 

### ***

Instrument 

## AlrcJffi'cYJE£1ff.!6.!l.;efl4252 AM IGG



# EP~g~~~?s~fo~~~ZT **~~o~~E~~ 2**  AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# ... 

# i
I 

### l 

# I \

APPENDIX

**PAG~Wies15** 1 of 1

### Sample Name: HPLC53pg100 *4 BORAL BRICKS Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method Last changed 

### EO Seq. Line Mr Burns Location 

### 10/4/2010 8:52:17 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by 

### IGG (modified after loading) 

### 17 1

ADC1 A. ADCTCFfi\NNEL A (U:\HPLC2010Q4\MR BURNS\DATA\OCT\HPLC53PG100\004-1701.D) uS/em 

# ·j

180 

## -1 

## ' 

# :::1
120

# ·~ 100 80 60 40 20

External Standard Report**===============================================""-====·"""=='--=="·:=:=====-====~·=** Sorted 

### By Calib. Data Modified 

### Multiplier Dilution Signal 

### 10/5/2010 9:18:49 AM 1. 

### 0000 1. 

## ooco Use Multiplier & 

### Dilution Factor with ISTDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/A:rea Amount Grp Name



### [min) [uS/cm*s) [ug/mL) 

## -------l------l----------l----------l----------1--l------------------ 3.154 BB 587.89532 1.71500e-2 10.08241 Fluoride 4.280 BB 369.70758 2.69527e-2 9.96463 Chloride Tot.als : 

### 20.04704**=================""====;o==========""==========='--o=•"·'-"'="''""=:;c;"'-'~======"'========** 

### *** End of Report 

## ** "k

· · 'u<:.l.:>"' 

## '·9 -"**~.q** 

### 1 7 EA# 0910-96 Page 189 of 202 Instrumen tAtC**PKU;J~t** 

### n< . >"'ft!14:1 

### AM IGG EPA iCR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE'Ml"s16 1 of 1

### Sample Name: HPLC53pgl00 *4 BORAL BRICKS

**===================-=======""=~-=====:::.:===================================** 

### Acq. Operator Acq. Instrument Injection Date Acq. Method Last changed P.na 

### 1 ys is

**~1e** 

### thod 

### Last changed EO Seq. Line Mr_Burns Location 10/4/2010 9:04:37 PM 

### Inj C:\HPLC2010Q3\MR BURNS\M£THODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PGlOO.M 10/5/2010 9:18:49 AM by IGG 

### {modified- after loading) 

### 17 

### 2

**~~-----AOCTA,-ADCl.cHANNELA{U:IHPLC2010041M-RBURNS\DATAii5CnHPLC53PGlo6ioo4:f7o2.15)**_________ 

# ·1 I uS/em·: 

# I g 180 160- 140 <D 

### 120 '0 

## 15

**~** 

### 100 

### u:



## =====================================================================
Sorted 

### By Calib. Data Modified Multiplier 

### Dilution External Standard Report Signal 10/5/2010 9:18:49 AM 1.0000 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs Signal

**1~** 

### ADCl A, ADCl CHANNEL A 

### RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

# -------l------l----------l----------l----------t--l------------------ 3.138 BB 

### 590.71399 1.71499e-2 10.13070 Fluoride 4.265 

### BB 369.76144 2.69527e-2 9.96608 Chloride Totals : 20. 

### 096TI

**~=~================================================~====~============** +** 

### End of Report 

### ***

L Ul.LS.L2m 

### n " 1 

### o 

### 2 8 EA# 0910-96 Page 

### 190 of 

### 202 Instrument A1 C'PRUJ!ct;T 

### NO. 

### l"·lo-t'42 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# "' oi

APPENDIX

**PAG~'N!>e517** l of l

### Sample Name: HPLC53pg100 #5 BORAL BRICKS 

## ===================================================================== Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Jl..nalysis Method 

### Last changed 

### EO Seq. Line 

### Mr Burns Location 10/4/2010 4:01:09 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHN.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by 

### IGG 6 1


### (modified after loading) 

### · · AocTil. ·Aoc

### T cFii\NNEi:A: (u:\HPLc2o1

### oil•IM;~R;:;B;;;U:;:Rc,.;N'"S"I"DA'T'A"'I"ocrc"'T"'IH"'P"L"c"s3"'P"'G"1"oo""'lo"os"-a"6o.o"1'.o")------,, uS/em 

# ·3

180-j 

### 160

## ~ ,'l 140 _:J 

# ·g 120

# ~ u:: J ,. 100·-l 

### :! 

### 1 ,.; 80 

# -i (\ 

# " :g 0 

# "' '-' 

# J I'


## . /I 60 ,• ', '\ 

## j I l 

# i\ M 40**-~** ' 1 \ o\C**~** 0 <-

# ~I 

# 1! II 

# ,, 

# li 

# i! '·I 

# !i 

# !I I•**~** v I L 

### I ..-U) !'.{) I 2 :

# ~b~-;:: 

# ] ..;:-::-') \':-:;::= )

# .~-;=_. .

# .c;-:::::.3 .

# }~_,_/\__ .. , .....

# ~A'-,

# ____). I 

## 2 4 6 

# I

L
_______________________ ------------------------------------···--··------------ 8**===·==-~======="'"'===u=====""'==============================c;;.===============** 

### External Standard Report**~===========~========================~===================~===========** 

### Sorted 

### By Signal 

### Calib. Data ModHied 10/5/2010 9:18:49 AM Multiplier 1.0000 Dilutj.on 1.0000 Use Multiplier 

### & Dilution Factor with ISTDs 

### Signal 

### 1' ADCl A, ADC1 CHANNEL A RetT.ime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.144 BB 849.68134 1.11448e-2 14.56764 Fluoride 4.250 BB 562.55444 2.68995e-2 15.13241 Chloride Totals : 

### 29.'70005
*** End of Report 

## ***

1n.J.S.L?.IlHl 9 10 . __1 

### EA#0910-96 Page 191 of202 

### Instrument AlrC'PRGJECT'Nl>. 

## P-ior4'z- S AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 mi ·



### APPENDIX**PAG~'!-jl,e518** 

### 1 of 1

# ( Sample Name: HPLC53pgl00 #5 BORAL BRICKS**=================================;==~==========================~===~=** 

### Acq. Operator 

### Acq. Instrument Injection Date 

### Acq. Method Last 

### changed 

### Analysis Method 

### Last changed 

### EO Seq. 

### Line Mr Burns 

### Location 10/4/2010 4:13:29 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by IGG 6 

### 2


### (modified after loading) r---·---·--ADC1i\-:l\t5c1cHI\NNEL A

### (U:IHPLC20;1"0Q;<-4;;\;;M"'R"BC,:UfiR<.N"S"'ID'"A'"'T"A"'IO"C~T"I"H"P"LC""5'"'3"'P"'G"1"0o=\ooS:o6l5Hij-·· . ···--·-·- 

### ··1

# ~I .::qi**~] ~**  "0 ·co 0**~ ~**  

## u: "0 

### ._, ' 0 

# "' :c ;!: () ..;**======="'"-""======~,==,-~=~.eo===============""================================**



### External Standard 

### Report**====================================================~==~~============** 

### Sorted By Calib. Data t1odified Multiplier 

### Dilution Signal 10/5/2010 9;18;49 

### AM 1.0000 1.0000 

### Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp 

### Name

[min] [uS/em's] (ug/mL] 

## -------l------l----------l----------l----------l--l------------------ 3.145 BB 847.86249 1.71449e-2 14.53648 Fluoride 4.250 BB 562.09290 2.68995e-2 15.12004 Chloride Totals : 29.65652

9 

### ** End of 

### Report 

### ***

l.iV-'L"'-'"'n " '"··-" 

### 6 EA# 0910-96 Page 192 of202 Instrument JiirC"Pt<t:r.!tl.'i""NO.

### ~-1vY-iL· AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PlANTS 4 & 5. SALISBURY PlANT 6 SEPTEMBER 2010 ! 

# I :1 

# !l 

# II ll \! 

### \! 

# tl !i 

### !I 

## 1 

## ' ! 

### ·--·-4 

### --,---------1. mi

APPENDIX**PA~'\W'** 519 1 of 1

### Sample Name: HPLC53pg100 #5 BORAL BRICKS

**===============================================================~====~** 

### Acq. Operator Acq. Instrument 

### Injection Date Acq. Method Last changed Analysis Method Last changed EO 

### Seq. Line Mr 

### Burns Location 10/4/2010 9:16:57 PM Inj 

### C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM 

### by IGG 18 1
(modified after loading},--u-S-Ic-m

# 1 -.A""D"'C"1"Ac-.-.A"D"'C"1'C_;H,:;Ac;N:7N;;E;=L A



### (ii\flPic2o1oi54iMRBURNSiliATAIOCTIHPIC53PGl.OOIDOS:181ll~15f·-·····-~---~ 180- 

# 11



# ~ It 

# ·g 1l 160 140 

### 120 

## u:



## ~ 

# II
(>:) 

### ·g 

# ll 100



## ~ 

# t5 11 M !i



# 80~- r:



# ~ II

0 

## I \ .\ \i 6 -. 1 ; " ' 

### 40 ,!' : 

# n to 1 ro · 1

**~ ~~** 

**~**

**~** i ' 

### ftig «! 

## g ,II 20 -4 

## t:; 1 j \

**~** tt}q:j ,r'-_ cd 0 

# l-·--··-·J'

**~ -:-·---::.::.~.:..** 

# ..

**::._''::::=.~~/~-~':-:::** . 

# ._.:;:::~::'-_:~l--~~~----:--~.:-~:-.-._- __

- ___

# 2_=~2:-- **._.-"~--- ~---!**  '---- ____L .... _____________ 1_··-·····- -·-------- .......§ .... ·-·-··--·------'8'--------"m""l

**========,-=·========c:=:==============:-::===="-~==============================**


### Sorted 

### By Calib. Data Modified Multiplier Dilution External Standard Report Signal 

### 10/5/2010 1.0000 1.0000 9:18:49 AM Use Multiplier & 

### Dilution Factor with 

### ISTDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

## -------l------l----------l----------j----------l--1------------------ 3.148 BB 851.27545 1.71448e-2 14.59495 Fluoride 4.265 BB 

### 562.78735 2.68994e-2 15.13865 Chloride Tot-als : 29. "73360
=====o"'='"'"'·

**·''"'==""============'""=======~-'-=~"'""""======-========================** 

### *** End of Report 

## ***

l.ll.t.c

**.L~o1** n 

### .o a. 

### 54 AM EA# 

### 0910-96 Page 

### 193 of 202 Instrument AkT'ffviil=tHW.



### t-'-1oM~ IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGg%\e520 1 of 1Sample Name: HPLC53pgl00 #5 BORAL BRICKS**=========================================~===========================** 

### Acq. Operator 

### Acq. Instrument Injection Date Acq. Method 

### Last changed Analysis Method Last changed 

### EO Seq. Line 

### Mr_Burns Location 10/4/2010 9:29:17 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\ME:rROHM.M 4/1/2010 4:15:36 PM lJ:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by IGG 

### (modified after loading} 18 

### 2**~--······-·--AoCi·A;"Aot"T'CHANNEL** A (U:\HPLC201 004\MR BURNS\DATAIOCDHPLC53PG1 00\005·1802.0)
1

# us~: 

# J 

# :::1 120-1 

# 1:: 

# l

60. 40 . 20.



### =========================================================,=•:=========== External Standard Report 

### ==============================================================,,...,.,.,.,.....,=== Sorted 

### By Calib. Data Modified t.!Jul 

### tipli_er. 

### Dilution Signal 10/5/2010 9:18:49 AM 

### 1.0000 l. 

### 0000 

### Use Multiplier & Dilution Factor with ISTDs Signal 1: ADC1 A, 

### ADCl CHANNEL 

### A RetTime Type Area Amt/Area Amount Grp Name

[min] {uS/cm*s] [ug/rnL] 

## -------l------:----------l----------l----------l--!------------------ 3.146 

### BB 848.51825 1.71448e-2 14.54771 

### Fluoride 4.263 BB 561.98425 2.68996e-2 15.11713 

### Chloride Totals : 29.66484**~================~=,=========================='""""'===""=~"="-"·"""""'======""======*****~*** 

### End of Report 

### ***

L11.l 

### nmn-" 7 

### n 0 

### EA#0910-96 Page 194 of202 Instrument AtcffibjtCT NO. 

### l"'-iu1'12 2 AM IGG EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010

# ~ I ! i (

APPENDIX PAGgw,e521 1 of 1

### Sample Name: HPLC53pg100 iSS BORAL BRICKS 

### Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed 

### Analysis .Method Last changed EO Seq. Line 

### Mr Burns Location 10/4/2010 4:38:08 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHH.M 4/1/2010 4:15:36 PH U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by 

### IGG {modified after loading) 7 

### 2**~------·---Aoc1-A;-J\o·c·rcHANNEL** il(u:IHF>n;-2o1ocf41MR sDRNs\5AtAiocnHPLcs3PG1oo\oo6-o7o2.o 1 uS/em 

## l

## '

180 

# j 160 

# -i 

# 1401 120 100 80 60 .



### Sorted By 

### Calib. Data Modified Multiplier 

### Dilution 

# " :g 0**~** ;:;: 

### , 

## ,._ 

# " :g 0 

### :c () 

## :;; N



### External Standard Report Signal 

### 10/5/2010 9:21:11 AM 1.0000 1. 

### 0000 Use Multiplier & 

### Dilution Factor with ISTDs Signal 1: ADCl A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*sJ [ug/mLJ

# ~ I
; I 

# i 

# i I 

# I I --r'-j_ ml



# -------l------l----------l----------l----------l--l------------------ 3.117 BB 76.75529 1.72618e-2 1.32493 Fluoride 4.251 BB 90.33049 2.74335e-2 2.47808 Chloride Totals : 3.80301 

### *** End of Report 

### ***

-r 

### EA# 0910-96 Page 195 of 202**InstrurnentAfcPil18i~§ill.J9.** PJ-1Jl'1"1!223**AI~ .l~G**  EPA ICR EMISSION TEST PROJECT

AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAG!'<AA!e522 1 of 

### 1.

### Sample Name: HPLC53pg100 ffSS BORAL BRICKS =="'"=================,================:,===""========::;:================== Acq. Operator Acq. Instrument Injection Date 

### Acq. Method Last changed Analysis Method J_,ast changed 

### EO Seq. Line Mr Burns Location 

### 10/4/2010 4:25:48 PM Inj C:\HPLC2010Q3\MR BURNS\METHODS\METROHM.M 4/1/2010 4:15:36 PM U:\HPLC2010Q3\MR BURNS\METHODS\HPLC53PG100.M 10/5/2010 9:18:49 AM by IGG (modified after loading) 7 

### 1**··-·~-Abcf/i;** ADCTCHANNEL A (U:\HPLC201-if64\Mi'r80RNS\DATAIOCT\HPLC53PG1001006·070f0)--·---



# L

=====================================================================
Sorted 

### By Calib. Data Modified Multiplier 

### Dilution External Standard Report Signal 

### 10/5/2010 9:18:49 AM l. 

### 0000 l. 

### 0000 Use Multiplier & 

### Dilution Factor Hith ISTDs 

### Signal 1: ADC1 A, ADCl CHANNEL A RetTime Type Area Amt/Area Amount Grp Name

[min] [uS/cm*s] [ug/mL] 

# -------l------j----------!----------l----------l--[------------------ 3.119 BE 76.93913 1.72615e-2 1.32808 Fluoride 4.253 BE 90.24962 2.7434le-2 2.47591 Chloride Totals : 

### 3.80400**=~~~=================================================================** 

### *** End of Report 

### *****U\.t..c,.<~a1n** .a**~.1.** 

### OS AM IGG EA# 0910-96 Page 196 of 

### 202 Instrument**Alc...-r<v.J~bY** M>.**t--1~1"1~** EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX**PAG~%1~523** l 

### of l

### Modified on: l/13/2010 at 7:06:26 AM BORAL BRICKS



### Method Information Method: U: 

### \HPLC201 OQ1 \SM ITHERS\METHODS\METROHM.**~~** 

### Modified: 1/13/2010 at 7:06:26 AM ANALOG DIGITAL CONVERTER**=======::=o=============================================::o:=====:::="-'""'""--""""''"""-===·~==** 

### Description: 

### Source: Unit: Units/Volt: Peakwidth (Data Rate): Stop Time: Data Stora9e: Signal 1 ADCl A, Metrohm Signal 

### mAU 100.000 0.027 Min (10.00 Hz) No Limit 

### All Start Signal Source: External Device Will Start 35900 Timed Event Table: <no events>



### EA# 091 0-96 Page 197 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE 

## Ni\"511'4 1 

### of 1

## ( BORAL BRICKS 

### Sequence Table: Method and Injection Info Part: Line Location SampleName 

### Data File Method 

### AutoBalance 

### 1 Vial 127 DI Rinse METROHM 2 Vial 1 HPLC53pg98 #1 METROHM 3 Vial 2 HPLC53pg98 12 METROHM 4 Vi a.l 3 

### HPLC53pg98 #3 i1ETROHM 5 Vial 4 

### HPLC53pg98 #4 METROHM 6 Vial 5 

### HPLC53pg98 #5 METROHM 7 Vial 6 

### HPLC53pg98 #SS METROHM 8 Vial 

### 7 HPLC53pg98 #LCS**METROf~** 

### 9 

### Vial 8 

### O.OlN H2S04/Na0H RB METROHM 10 Vial 9 

### Salisbury Rl In A 

### *20 0910-96 METROHM 11 

### Vial 10 MS Salisbury R1 In A 

### *20 0910-96 METROHM 12 Vial 11 MSD Salisbury Rl In A *20 0910-96 METROHM 13 Vial 12 Salisbury R2 In A 

### *20 0910-96 METROHM 14 Vial 13 Salisbury R3 In A *20 0910-96 METROHM 15 Vial 14 Salisbury Rl Out A *10 0910-96 METROHM 

### 16 Vial 15 Salisbury R2 Out A *10 0910-96 METROHM 17 

### Vial 100 HPLC53pg98 #3 

### METROHM 18 Vial 101 HPLC53pg98 #4 METROHM 19 Vial 16 Salisbury R3 Out. A *10 0910-96 METROHM 

### 20 Vial 17 Salisbury Rl In B *10 0910-96 METROHM 21 Vial 18 Salisbury R2 In B *10 0910-96 METROHM 

### 22 Vial 19 Salisbury R3 In B 

### *10 0910-96 METROHM 23 Vial 20 Salisbury Rl B Out *10 0910-96 METROHM 24 Vial 21 Salisbury R2 Out B *10 0910-96 METROHM 

### 25 Vial 22 Salisbury R3 Out B 

### *10 0910-96 METROHM 26 Vial 23 Salisbury Rl Out B *100 0910-96 METROHM 27 

### Vial 24 

### Salisbury R2 out B *100 0910-96 METROHM Inj 

### LimsiD 4 2 

### 2 2 2 2 2 2 

### 2

2 2



### EA# 0910-96 PaQe 198 ol202 Instrument

### A'fcrn61JEs~W,. 

## M0142: 32 

### PM IGGEPA ICR EMISSION TloST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 

### 2010 SampleType InjVolume Sample Sample Sart',ple Sample Sample Sample Sample Sample Sample

2 Sample 2 Sample

2 Sample 2 

### Sample 2 

### Sample

2 

### Sample 2 

### Sample Sample Sample 2 

### Sample 2 

### Sample 2 

### Sample 2 

### Sample

2 Sample 2 

### Sample 2 

### Sample 2 

### Sample

2 

### Sample

APPENDIX PAGE rJOaSJU 

### 1 of 

### 3

## ( Sequence: U:\HPLC2010Q4\MR BURNS\SEQUENCE\HPLC53PG98.S Line Location SampleName 

### DataFile 

### Me**th~8RAL** 

### BRICKS AutoBalance Inj 

### LimsiD 28 Vial 25 Salisbury R3 Out 8 *100 0910-96 METROHM 29 Vial 100 HPLC53pg98 *3 METRO**HI~** 2 

### 30 Vial 101 HPLC53pg98 #4 METROHM 2 

### 31 Vial 7 HPLC53pg98 #LCS METROHM 2 

### 32 Vial 

### B 0.01N H2S04/Na0H RB METROHM 

### 2 33 Vial 26 P4 R1 In A 

### *10 0910-96 METROHM 2 

### 34 Vial 27 MS P4 Rl In A 

### * 10 0910-96 METROHM 35 Vial 

# n MSD P4 Rl In A 

### *10 0910-96 METROHM 36 Vial 29 P4 R2 

### In A 

### *10 0910-96 METROHM 2 

### 37 Vial 30 P4 R3 In A 

### *10 0910-96 METROHM 2 

### 38 Vial 31 P4 Rl Out 

### A *10 0910-96 METROHM 39 Vial 32 P4 R2 Out 

### A *10 0910-96 METROHM 40 Vial 33 P4 R3 Out 

### A *10 0910-96 METROHM 41 Vial 110 HPLC53pg98 #3 METROHM 

### 2 42 Vial 111 HPLC53pg98 #4 

### METROHM 2 43 Vial 34 P4 Rl In B *10 0910-96 METROHM 2 

### 44 Vial 35 P4 R2 In 

### B *10 0910-96 METROHM 2 

### 45 Vial 36 P4 R3 In B 

### *10 0910-96 METROHM 2 

### 46 Vial 37 P4 

### Rl Out B 

### *10 0910-96 METROHM 47 Vial 38 P4 R2 Out B *10 0910-96 METROHM 48 Vial 39 P4 R3 Out B *10 0910-96 METROHM 49 Via] 40 PS Rl In A *10 0910-96 METROHM 

### 2 

### 50 Vial 41 P5 

### R2 In A 

### *10 0910-96 METROHM 2 

### 51 Vial 42 P5 

### R3 In A 

### *10 0910-96 METROHM 2 52 Vj.a.l 43 PS P.l Out A *10 0910-96 t'-1ETROHM 

### 53 Vial 110 HPLC53pg98 #3 METROHM 2 

### 54 Vial 111 HPLC53pg98 #4 METROHM 2 

### 55 Vial 102 HPLC53pg98 #LCS METROHM 2 

### 56 Vial 103 O.OlN H2S04/NaOH RB METROHM 2 

### 57 Vial 44 P5 R2 Out A *10 0910-96 METROHM
Instrument

## AkP~~~gjl**j\J~** f"i.:f01l!i?: 32 PM I

## GGEP~1M~~fl;~**~J'f~T 1Jlr?o~~~~z**  AUGUST A PLANTS 4 & 

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### Sample Sample Sample Sample Sample Sample 

### Sample Sample Sample Sample Sample



### Sample Sample 

### Sample Sample 

### Sample Sample 

### Sample Sample Sample Sample


### APPENDIX PAGE 

### Nll- 2 

### of 3

## ( Sequence: U:\HPLC2010Q4\MR BURNS\SEQUENCE\HPLC53PG98.S Line Location SampleName Me ttJlcflRAL BRICKS Inj DataFile AutoBalance LimsiD ====""""'""=**====~~===~=====~==== ===~================**  

## ======== 58 

### Vial 45 P5 R3 Out A 

### *10 0910-96 METROHM 2 

### 59 Vial 46 PS Rl In B *10 0910-96 METROHM 2 60 Vial 47 

### PS R2 In B 

### *10 0910-96 METROHH 2 61 Vial 48 PS R3 In B 

### *10 0910-96 

### METROHM 2 62 Vial 49 P5 R1 

### out B 

### *10 0910-96 METROHM 

### 2 63 Vial 50 PS R2 Out B 

### *10 0910-96 METROHM 2 

### 64 Vial 51 P5 R3 

### out 8 

### *10 0910-96 METROHM 2 

### 65 V:iaJ. 120 HPLC53pg98 #3 METROHM 2 66 Vial 121 

### HPLC53pg98 #4 METROHM 2 67 Vial 52 

### Acid Blank *10 0910-96 METROHM 2 

### 68 Vial 53 Base Blank *10 0910-96 METROHM 2 69 Vial 54 Dl H20 blank 0910-96 METROHM 2 

### 70 Vial 

### 1 HPLC53pg98 

### #1 METROHM 

### 2 71 Vial 2 HPLC53pg98 #2 

### METROHM 

### 2 72 Vial 3 HPLC53pg98 

### #3 METROHM 2 73 Vial 4 

### HPLC53pg98 #4 METROHM 2 

### 74 Vial 5 HPLC53pg98 #5**I~ETROHM** 2



### Instrument

## A'tC~EGiVM\. !L'loil<l!: 32 PM

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### AUGUSTA PLANTS 4 & 

### 5. SALISBURY PLANT 6 SEPTEMBER 2010 sampleType InjVolurne 

## ""========= ========= Sample Sample Sample Sample

Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample sample Sample sample

APPENDIX PAGE Nlli>SI!'l' 3 of 

### 3

### Sequence: 

### U:\HPLC2010Q4\MR BURNS\SEQUENCE\HPLC53PG100.S BORAL BRICKS Sequence Table: Method 

### and Injection Info Part: Line Location SampleName 

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### LimsiD 

## ======== ==================== ==================::::;.=. 

### o=:===o==== 

### 1 Vial 

### 127 

### DI Rinse 

### METROHM 4 2 Vial 

### 1 HPLC53pg100 #1 

### METROHM 2 3 Vial 

### 2 HPLC53pglOO #2 METROHM 2 4 

### Vial 3 HPLC53pgl00 #3 METROHM 2 

### 5 Vial 4 

### HPLC53pgl00 #4 

### METROHM 2 6 Vial 

### 5 

### HPLC53pg100 #5 METROHM 2 7 

### Vial 6 

### HPJ"C53pg100 itSS 

### METROHM 2 

### 8 

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### METROHM 2 

### 9 Vial 8 

### O.OlN H2S04/Na0H RB METROHM 2 10 Vial 9 

### PS R2 In A 

### *20 0910-96 METROHM 

### 2 11 Vial 

### IO P5 R3 In A 

### *20 0910-96 METROHM 2 12 Vial 11 

### R1 C4 *10 1010-10 METROHM 2 

### 13 Vial 

### 12 R2 C4 

### "10 1010-10 METROHM 

### 2 14 Vial 

### 1 HPLC53pg100 #l 

### METROHM 2 15 Vj.a 1 

### 2 HPLC53pg100 #2 METROHM 

### 2 16 Vial 

### 3 HPLC53pg100 #3 METROHM 2 17 Vial 

### 4 HPLC53pglOO #4 METROHM 2 18 Vial 

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### 2

'-

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### EA#0910-96 Page201 of202 

### Instrument AtC-pffi.)jiot;f NO. 

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### 5. SALISBURY PLANT 6 SEPTEMBER 2010 SampleType InjVolume 

### =====""==== ========= Sample Sample Sample Sample 

### Sample Sample Sample Sarnple Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample



### APPENDIX PAGE J&a5![8 1 of 

### l

# ( BORAL BRICKS



# This Is The Last Page Of This Report.

ATC PROJECT No. P-10142 

### EA# 0910-96 Page 202 of 202 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 529

# ( BORAL BRICKS



# METALS LABORATORY RESULTS

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 530BORAL BRICKS



### ANALYTICAL TESTING CONSULTANTS, INC. Toll Fr<><>-(800)·733-3193 CHAIN OF CUSTODY RECORD Project No p 10124 

## -

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# ' 

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### i CFA -100 ml 0.1 HN03 FH R\n!.la 

### ; CFA -100 ml 0.1 HNO. FH

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# I CFA:CLEAN FIEl-D AArt(J Please analyze for standard metal& list {Brlck MACT !GR Emissions Testing) and HG. My quMtlcns contact B\11 Kissel (704) 241-Q315

**~** cen PLEASE MAAK LIOUlO LEVEl ON ALL SAMPLE BOTILES 1NI.TH GREASE PENCIL. SEAL TIG!-HlY AND RE-CHECK UPON OEUVERY TO LA8 PERSONNEL,

Page 55 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

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## -

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Poge 56 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

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### ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)-733-3193 CHAIN OF CUSTODY RECORD Project No p 10124 -



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## ~ **ll6'30iqf~~lt6** '-' Please analyze for standard metals list {Brtck MACT lCR Emissions Testing) and HG. Any queslions contact Bill Klssel (704) 241-0315 -<:.eJI PlEASE MARK LIQUID LEVEL ON All SAMPlE BOTILES WllH GREASE PENCJL. $EAL TIGHTLY AND RE-CHECK UP()N OE;L!VERV TO LAS PERSONNEL

Page 57 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 D 

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### ANALYTICAL TESTING CONSULTANTS, INC. Toll Frne-{800)-733·3193 CHAIN OF CUSTODY RECORD Proje<t No P-10124



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Please analyz& f-or standarcl metals list (Brick MACT !CR Emissions 1 esting) and HG. Any que:!>tions contact em Kissel (704) 241-0315- cell PlEASE MARK :.JQUIO LEVEL ON All SAMPLE 601TLE8 WITH GREASE PENCIL. SEAl. T!GBTI.Y AND RE-CH!:=CK UPON OELlVEHY TO LAS Pf.R.SONNEL

**P<:~ge** 58 of 1 03 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 Wr \.0 29 Augul-121J03

APPENDIX PAGE No. 588BORAL BRICKS 

## ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)-733-3193 CHAIN OF CUSTODY RECORD Project No. 1.-i 

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Ver 1.0 29 August 2003

EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0 APPENDIX PAGE No. 

### 589)>SampleIDElemDateTimeAbs(Co•Cone(CalRSD(Con•SpecialSoSpecialCoCone(CaliCone(Calil-<0ColibBlankAs"U10/5/20108:28:06AM0.0060;u10ppbAsAs10/5/20108:33:30AM0.0110050ppbAsAs10/5/20108:39:17AM0.0540m0-<100ppbAs As10/5/20108:45:02AM0.1080z?200ppbAsAs10/5/20108:50:26AM0.2220E"ICYAs10/5/20109:07:58AM0.112101.550.23101.3874101.7131..IC8As10/5/20109:13:26AM-0.001-1.1291.88-1.84415-0.3916"'100912.LBAs10/5/20109:18:51AM-0.002-1.7920.97-1.52533-2.05648100912.LCSAs10/5/20109:24:19AM0.10696.094.7792.8492899.33724100912.8-1As)>10/5/20109:29:44AM-0.002-1.6371.65-0.80654-2.46327c100912.SA11-1As10/5/20109:35:11AM0.02522.571.5722.3225222.82314Glmc.,100912.SA12-1As10/5/20109:46:07AM0.03329.563.9730.3898628.73101"1)>)>0100912.SA13-1As10/5/20109:51:32AM0.03127.733.9628.5062726.9516(/)"U;u100912.SA01-110/5/20109:56:56AM0.0021.733.851.7819271.687389m<;;mAs-uzs:"'-<-;-100912.SA02-1As10/5/201010:02:20AM0.0011.1757.060.6965651.638848mCJ>CJ>0100912.SA03-1As10/5/201010:07:44AM0.0000.08357.170.264686-0.11453,..;::o.0'1-iCCVAs10/5/201010:13:32AM0.10898.112.4196.4378399.78343"'"'CJ>m;u0)>(/)CC8As10/5/201010:19:00AM-0.005-4.3911.73-4.02321-4.750860"'(ii"U10/5/201010:29:44AM0.0000.061814.370.786739-0.67296(/)"'"'100912.412-1Asco100912.413-1As10/5/201010:35:28AM0.0010.5243.180.6822770.363115-<m100912.401-1As10/5/201010:40:52AM0.0032.5223.252.1096462.939948z100912.402-1As10/5/201010:46:17AM0.0043.5678.591.5837325.545232-<'"100912.403-1As10/5/201010:51:42AM0.0022.1046.541.4091282.791488100912.512-1As10/5/201010:57:08AM0.0087.2015.147.9671716.426018100912.513-1As10/5/201011:02:34AM0.0022.1293.210.7224183.515642100912.501-1As10/5/201011:07:59AM0.0010.8088.591.3037030.299473)>CCVAs10/5/201011:13:25AM0.10191.296.7795.6570386.91342"U"U-3.46774mCCBAs10/5/201011:18:51AM-0.005-4.3328.23-5.19731z0100912.502-1As10/5/201011:24:15AM0.0010.75188.361.748918-0.24894x"U100912.503-1As10/5/201011:29:39AM0.0043.2219.172.7829513.655793)>GlCCVmAs10/5/201011:35:04AM0.08880.120.4580.3767179.86679zCCBAs10/5/201011:40:28AM-0.004-3.186.96-3.33495-3.02188"'"'100912.411-1As10/5/201011:56:53AM0.0032.4010.312.5799032.2292510Page60of103)> Sample iD Elem Dote Time Abs (Co• Cone (Col RSD (Con• Special Sa Special Cc Cone (Coli Cone (Coli!

__, 100912.411-1 10/5/2010 12:02:21 PM 0.084 75.93 13.17 1 75.93197 68.85817 83.00576

0 As

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;o CCV As 10/5/2010 12:07:43 PM 0.090 81.68 2.14 80.44496 82.9218

0 L CCB As 10/5/2010 12:13:30 PM

m

0 -0.002 -1.78 22.87 -2.06439 -1.48965

__, 100912.8-2A As 10/5/2010 12:26:10 PM -0.005 -4.74 10.56 -4.38299 -5.0904

z

9 100912.5AI1-2A As 10/5/2010 12:31:36 PM 0.021 19.13 0.73 19.22348 19.02706

**~** 1 00912 .SAI2-2A As 10/5/2010 12:37:01 PM 0.023 21.04 2.41 20.68477 21.40327

'" ... 1 00912.5A13-2A As 10/5/2010 12:42:26 PM 0.018 15.89 0.69 15.96813 15.81275

**~**

100912.SA01-2A As 10/5/2010 12:47:49 PM -0.005 -4.76 11.54 -4.36776 -5.144

1 00912.SA02-2A As 10/5/2010 12:53:11 PM -0.004 -3.41 21.32 -3.92642 -2.89754
100912.SA03-2A As 10/5/2010 12:58:33 PM -0.006 -5.00 32.80 -3.8382 -6.1563

)> -4.18 -3.66811

c 100912.411-2A As 10/5/2010 1:03:58 PM -0.005 17.19 -4.68355

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c., 1 00912.412-2A As 10/5/2010 1:15:15 PM -0.003 -3.13 12.06 -3.40054 -2.86621

**~)>** ""o CCV As 10/5/201 0 1:51:41 PM 0.036 32.28 14.68 28.92916 35.62995

en""' CC8 As 10/5/2010 1:57:07 PM 0.025 22.47 54.93 13.74218 31.19618

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(J>"O 200 ppb As As 10/5/2010 2:53:06 PM 0.242 0.00

"'"' co 10/5/2010 3:03:52 PM 0.124 103.55 0.98 102.8296 104.2694

;!JL ICY As

-<m .,o ICB As 10/5/2010 3:09:18 PM 0.001 0.86 204.23 -0.37982 2.090361

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z 100912.511-1 As 10/5/2010 3:14:44PM 0.023 18.94 0.42 18.88109 18.99478

__,

"' 100912.B-2A As 10/5/2010 3:20:10 PM 0.000 -0.24 96.23 -0.41056 -0.07808
100912.SAI1-2A As 10/5/2010 3:25:38 PM 0.032 26.65 1.22 26.41596 26.87 453
100912.SAI1-2A As 10/5/2010 3:31:02 PM 0.159 132.06 0.17 1 105.4149 131.9046 132.2157

1 00912.SA12-2A As 10/5/2010 3:36:50 PM 0.042 34.97 2.90 34.25485 35.69154

)> 1 00912.SAI3-2A As 10/5/2010 3:42:18 PM 0.032 26.44 0.49 26.53181 26.34979

., ., 100912.SA01-2A 10/5/2010 3:47:43 PM 0.001 0.58 101.96 0.992452 0.160933

m As

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0 100912.SA02-2A As 10/5/2010 3:53:08 PM 0.002 1.78 90.44 0.641294 2.916893

x ., 1 00912.SA03-2A As 10/5/2010 3:58:32 PM 0.002 1.52 6.13 1.452879 1.58444

)>

Gl 1 00912.411-2A As 10/5/2010 4:03:57 PM 0.001 0.75 41.60 0.526373 0.965037

m z CCV 10/5/2010 4:09:27 PM 0. 111 91.92 0.43 91.64037 92.20489

0 As

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"1 As 10/5/2010 4:14:54 PM 0.000 0.36 46.53 0.243763 0.48284

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1 00912.402-2A

1 00912.403-2A 100912.511-2A 100912.512-2A 100912.513-2A 100912.501-2A

1 00912.502-2A

1 00912.503-2A CCV CCB Elem Date Time

As 10/5/2010 4:20:17 PM

As 10/5/2010 4:25:42 PM

As 1 0(5/2010 4:31 :08 PM

As 10/5/2010 4:36:35 PM

As 10/6/2010 8:11:29 AM

As 10/6/2010 8:16:53 AM

As 10/6/2010 8:22:40 AM

As 10/6/2010 8:28:06 AM

As 10/6/2010 8:33:29 AM

As 10/6/2010 8:44:52 AM

As 10/6/2010 8:50:17 AM

As 10/6/2010 8:55:39 AM

As 10/6/2010 9:01:05 AM

As 10/6/2010 9:06:32 AM

As 10/6/2010 9:11:59 AM

As 10/6/2010 9:17:26 AM

As 10/6/2010 9:22:54AM

As 10/6/2010 9:28:24AM

As 10/6/2010 9:33:48 AM

As 10/6/2010 9:39:15 AM

As 10/6/2010 9:44:41 AM

As 10/6/2010 9:50:28AM Abs (Co• Cone (Cal RSD (Con• Special So Special Co Cone (Cali Cone (Calil

0.002 1.72 42.36 1.206598 2.23843

0.000 0.28 206.70 -0.12921 0.689011

0.108 89.70 0.79 90.20047 89.20277

0.001 0.81 12.52 0.881699 0.738258

-0.001 0.00 0.012 0.00 0.059 0.00 0.113 0.00 0.216 0.00

0. 111 101.19 1.67 102.3822 99.99649

0.000 0.16 177.28 -0.04031 0.358288

0.000 -0.39 186.05 -0.90905 0.123884

0.001 0.66 12.54 0.717301 0.600494

0.000 -0.34 45.95 -0.44872 -0.22865

0.017 15.90 2.67 16.20371 15.60295 "' 0

0.004 3.58 20.76 4.100048 3.05053 "' )>

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0.000 -0.12 620.93 -0.63139 0.397133 "' ;o

0.000 -0.38 109.56 -0.67715 -0.08596 fi "'

-0.001 -0.49 67.84 -0.73097 -0.25703 ())

-0.001 -1.18 72.52 -1.78678 -0.57542

0.105 96.44 0.29 96.63094 96.24157

-0.001 -0.82 51.64 -1.12195 -0.52179

Page 62 of 103::; Sample ID Date Time Elem Cone (Cali lnt (Corr) Calib Unit RSD (Corr In! (Corr)11nt **(Corr)~** lnt (Corr)3

0

-u Co lib Blank 1 9/30/2010 10:46:36 AM Ag -278.801 ug/L 10.0937 -299.002 -246.658 -290.742

:0 Standard 1 9/30/2010 10:48:10AM Ag 69018.9 ug/L 1.18152 69180.6 68134.7 69741.4

0 **~** Standard 2 9/30/2010 10:49:32 AM 154833 ug/L 0.81269 155082

rn Ag 153469 155948

0 __, ICY 9/30/2010 10:51:35 AM Ag 925.345 70082.9 ug/L 0.87285 69656.8 70783.9 69808.1

z ? ICB 9/30/2010 10:54:06 AM Ag 0.11379 8.61819 ug/L 374.284 -22.2385 5.9805 42.1126

i: s: ICS 9/30/2010 10:56:55 AM Ag -3.4956 -264.747 ug/L 8.44779 -263.742 -287.597 -242.9

.. 1 00912.L8 9/30/2010 10:58:40 AM Ag -0.49744 -37.6748 ug/L 105.348 -78.2082 1.1132 -35.9294

"' 1 00912.LCS 9/30/2010 11:00:16 AM Ag 943.515 71459.1 ug/L 0.6289 71036 71410.3 71930.9

100912.8-1 9/30/2010 11:02:29 AM Ag 0.08874 6.72112 ug/L 403.804 -20.4213 33.8589 6.72577

100912.SA11-1 9/30/2010 11:11:35 AM Ag 0.84804 64.2281 ug/L 44.886 47.0746 48.0975 97.5123

l> 100912.SAI1-1 S 9/30/2010 11:12:59AM Ag 765.805 57999.8 ug/L 0.8832 58194 58386.5 57418.8

c Glrn 100912.SA12-1 9/30/2010 11:34:05 AM Ag 0.91687 69.4413 ug/L 1.32938 70.1863 69.729 68.4085

c-u **~l>** 100912.SA12-1 D 9/30/2010 11:35:42 AM Ag 0.71146 53.8842 ug/L 26.9306 37.8977 57.5298 66.2251

""i'i (/)-u;o 1 00912.SA13-1 9/30/2010 11:37:15 AM Ag 0.74132 56.1455 ug/L 38.9618 67.3605 30.9371 70.139

rnS::m -uz;: 100912.SA01-1 9/30/2010 11:38:37 AM Ag 0.12885 9.75852 ug/L 209.153 21.0001 22.0765 -13.801 "'

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**:s::.f>.~** 1 00912.SA02-1 9/30/2010 11:40:07 AM Ag -0.27778 -21.0386 ug/L 140.545 11.0389 -47.2058 -26.9489 :0 l>

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::O!JI-1 CCV 9/30/2010 11:41:48 AM Ag 937.001 70965.7 ug/L 1.04816 70825 70302.3 71769.9 "' :0

"-'C/lm CC8 9/30/2010 11:47:00 AM Ag 0.3785 28.6661 ug/L 128.173 27.8374 -7.65485 65.8159 i'i

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(I)"U 100912.SA03-1 9/30/2010 12:14:10 PM Ag -0.21052 -15.9442 ug/L 117.243 -4.56274 -37.5187 -5.75128 (/)

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co 100912.411-1 9/30/2010 12:15:44 PM Ag 0.60789 46.0399 ug/L 67.1743 45.3967 15.4395 77.2834

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9/30/2010 12:17:09 PM 0.0383 2.9006 ug/L 1122.92 -4.16132 -25.5605 38.4236

-uo 100912.412-1 Ag

,......, l> 100912.413-1 9/30/2010 12:18:44 PM Ag 0.01678 1.27099 ug/L 2216.17 26.5319 6.38359 -29.1025

z __, 100912.401-1 9/30/2010 12:20:27 PM Ag 0.81981 62.0902 ug/L 4.24723 62.2184 64.661 59.3914

"' 100912.402-1 9/30/2010 12:21:56 PM Ag -0.2402 -18.1919 ug/L 279.819 -42.6851 40.3291 -52.2196

100912.403-1 9/30/2010 12:23:30 PM Ag 0.14839 11.2386 ug/L 196.025 -6.66757 35.8398 4.54351

100912.512-1 9(30/201 0 12:25:12 PM Ag -0.25681 -19.4501 ug/L 102.757 -31.0174 3.62804 -30.961

l> 100912.513-1 9/30/2010 12:28:01 PM Ag -0.19665 -14.8935 ug/L 323.72 -0.90251 24.777 -68.555

-u 9/30/2010 12:29:53 PM

-u CCV Ag

rn 946.732 71702.7 ug/L 0.74602 72234.6 71164.8 71708.7

z CCB 9/30/2010 12:35:02 PM Ag -0.32695 -24.7 625 ug/L 47.438 -33.6577 -29.1832 -11.4467

0 x Calib Blank 1 10/5/201 0 1:11:19 PM Ag -217.981 ug/L 10.52 -243.93 -209.591 -200.421

-u l> Standard 1 10/5/2010 1:13:25PM Ag 87223.2 ug/L 0.66 86804.2 87884.9 86980.6

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z Standard 2 10/5/2010 1:14:56 PM Ag 175996 ug/L 0.33 175614 175699 176675

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<0 1:16:23 PM Ag 993.1 87240.9 ug/L 0.95 86317.2 87477.7 87927.6

"' ICS 10/5/2010 1:18:08PM Ag -3.1 -275.517 ug/L 10.66 -248.61 -2 71.07 -306.869

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1 00912.B-2A 100912.SAI1-2A 100912.SA12-2A

1 00912.SAI2-2AD 100912.SA13-2A 100912.SA01-2A CCV CC8 1 00912.SA02-2A

1 00912.SA03-2A 100912.411-2A

1 00912 .411-2AS 100912.412-2A

1 00912.413-2A 100912.401-2A

1 00912.402-2A 100912.403-2A 100912.511-2A

1 00912.512-2A CCV CCB 100912.513-2A 100912.501-2A 100912.502-2A

1 00912.503-2A CCV CC8 Co lib Blank 1 Standard 1 Date 10/5/2010 10/5/2010 10/5/2010 10/5/201 0 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/201 0 10/5/201 0 10/5/2010

1 0/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/201 0 10/5/2010 10/5/2010 10/5/201 0 10/5/2010 10/5/2010 10/5/2010 10/5/2010 9/30/2010 9/30/2010 Time 1:20:11 PM 1:22:01 PM 1:23:22 PM 1:24:50 PM 1:26:22 PM 1:28:06 PM 1:29:31 PM 1:30:55 PM 1:32:09 PM 1:33:43 PM 1:35:07 PM 1:36:28 PM 1:38:43 PM 1:43:34 PM 1:45:14PM 1:47:03 PM 1:48:30 PM

1 :50:19 PM

1 :51 :43 PM 1:53:01 PM 1:54:32 PM 1:56:39 PM 1:57:58 PM 1:59:20 PM 2:02:51 PM 2:08:19 PM 2:09:46 PM 2:11:06 PM 2:12:35 PM 2:14:07 PM 2:15:36 PM 2:18:57 PM 10:46:36 AM 10:48:10AM Elem Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ba Ba Cone (Cali lnt (Corr) Calib Uni1 RSD (Corr lnt (Corr)llnt **(Corr)~** In! (Corr)3

-0.4 -37.1978 ug/L 39.25 -51.2929 -38.1583 -22.1423

0.0 -1.98286 ug/L 314.40 4.52076 -7.90703 -2.56231

-0.7 -62.9531 ug/L 49.03 -44.8781 -98.5949 -45.3862

0.0 0.07952 ug/L 63123.00 -9.60855 54.4141 -44.567

-0.2 -17.5262 ug/L -0.5 -41.7424 ug/L -0.1 -7.02102 ug/L -0.4 -34.5806 ug/L -0.1 -9.49972 ug/L -0.1 -12.461 ug/L -0.1 -10.405 7 ug/L 1077.3 94631.4 ug/L
0.1 5.20953 ug/L -0.1 -6.98174 ug/L -0.1 -5.91871 ug/L -0.3 -25.435 ug/L 794.1 69758.6 ug/L 0.0 -1.61584 ug/L -0.6 -52.9544 ug/L -0.4 -38.7905 ug/L -0.6 -50.9975 ug/L 0.0 0.88859 ug/L -0.6 -50.1831 ug/L -0.6 -50.6836 ug/L 895.6 78671.5 ug/L 0.3 30.2433 ug/L 0.9 77.7761 ug/L 0.2 13.867 ug/L -0.5 -42.9927 ug/L -0.7 -65.4885 ug/L 971.1 85304.6 ug/L 0.3 30.061 ug/L 72.1572 ug/L 290.65 ug/L Page 64 of 103 165.66 -23.8203 14.1387 -42.8972
68.57 -23.3022 -74.7176 -27.2073 548.56 -1.45032 28.405 -48.0177
63.02 -41.0189 -52.4301 -10.2928 363.92 30.2756 -32.3253 -26.4495 186.34 -17.4876 -32.7552 12.8599
66.73 -16.8134 -3.02795 -11.3758

0.50 95173.9 94417.7 94302.6 405.00 -17.9196 10.1456 23.4026 305.54 17.636 -20.0141 -18.5672 190.76 -1 0.5638 6.95338 -14.1457
37.49 -16.0088 -25.2197 -35.0766

0.37 70039.7 69539.3 69696.8 2933.36 34.1628 -55.3734 16.3631 41.80 -28.7689 -72.2112 -57.8831 93.48 -2.71063 -38.4335 -75.2274 45.27 -62.1031 -66.4296 -24.4596 4711.01 -44.1202 8.12647 38.6595
33.86 -69.3656 -37.0126 -44.1709
69.50 -10.5043 -65.2821 -76.2643

1.00 78016.1 79540.8 78457.7 191.04 74.7326 51.0538 -35.0564 43.90 116.715 52.9788 63.6351 315.88 63.1655 -20.5784 -0.98609
65.44 -65.8249 -11.5616 -51.5915
37.45 -42.8248 -91.5285 -62.1123

1.09 84229 85895.5 85789.2
32.24 39.9861 29.5763 20.6205 5.19364 75.1576 67.9565 73.3575 7.75378 304.734 302.558 264.658 [J) 0 **~** r

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i;j)>SampleIDDateTimeElemCone(CaliIn!(Corr)CalibUnilRSD(Carrlnt(Corr)llntIn!(Corr):l-<Standard29/30/201010:49:32AM()Ba612.696ug/L3.71219586.785621.941629.363'1l;uICY9/30/201010:51:35AMBa903.797274.039ug/L9.60593264.898253.504303.7150'-ICB9/30/201010:54:06AMBa25.94527.8668ug/L75.578614.41946.364862.81618m()-<IC89/30/201010:55:40AMBa9.518892.8S621ug/L79.61124.985160.431233.24224z0ICS9/30/201010:56:55AMBa10.08293.05721ug/L141.3255.219775.86955·1.91768100912.L89/30/201010:58:40AM8a·8.92146-2.70506ug/L175.012·2.83861-7.371062.0944S..100912.LCS9/30/201011:00:16AMBa912.442.276.66ug/L10.1931249.905273.963306.112"'100912.8-19/30/201011:02:29AMBa13.56S4.11394ug/L161.573-1.225582.0087711.5586100912.SA11-19/30/201011:11:35AMSa213.4264.7109ug/L53.398826.950972.425194.7567100912.SAI1-1S9/30/201011:12:59AMSa1065.22322.984ug/L2.6592632S.717313.109327.126)>100912.SAI2-l9/30/201011:34:05AMSa339.879103.054ug/L8.42566103.82894.0105111.325cGlm100912.SAI2-1D9/30/201011:35:42AMSa326.46998.9881ug/L13.124892.3844113.95690.6245c.,100912.SAI3·19/30/201011:37:15AMBo287.987.2936ug/L36.194186.010356.3596119.511"'o(f)'1l;u100912.SA01-19/30/201011:38:37AMBa26.848.13S1ug/L114.3591.50294.1348818.7765m<;;m'1lz;::100912.SA02·19/30/201011:40:07AMBo25.77117.81401ug/L85.62470.3731S13.33489.73406OJ-<-;-0m(f)(f)CCV9/30/201011:44:42AMBa1061.32321.801ug/L9.S277S358.187306.29S300.9189/30/201011:50:49AM17.72185.37339ug/L81.60581.4334S10.09764.58906r::0_<JI-1CC8BaOJ;u"'(f)m100912.SA03-19/30/201012:14:10PMBa49.911415.1336ug/L60.22074.6106920.487720.30230S:>{/)or-<"'(ii'U100912.411·19/30/201012:15:44PMSo35.561610.7S26ug/L73.30719.318S719.31653.71235(f)OJ;Ilco100912.412-19/30/201012:17:09PMBo52.360515.8762ug/L57.465826.32349.47911.S261;ll'--<m100912.413-19/30/201012:18:44PMBo49.784515.0951ug/L59.162423.671215.76625.84783,os;'"100912.401-19/30/201012:20:27PMBa56.556717.14S5ug/L34.168615.980411.961123.5039z-<100912.402-19/30/201012:21:56PMBa50.655315.3591ug/L52.59178.S394124.395512.8425"'100912.403-19/30/201012:23:30PMBo43.247313.1129ug/L73.753920.103117.16032.07549100912.512-19/30/201012:25:12PMSa62.145918.8432ug/L39.0825m359423,588622.5S14100912.513-19/30/201012:28:01PM8a60.807818.4375ug/L59.682224.255725.31085.745S9)>CCV9/30/201012:31:21PMSa1084.36328.787ug/L3.20223317.336330.976338.049'1lCCB9/30/201012:44:37PMBo-3.99555-1.21149ug/L1237.06-1S.18464.3531710.197'1lmzCalibBlank110/5/20101:11:19PMBa76.0024ug/L18.8680.559459.942387.50530xStandard110/5/20101:13:25PMBa211.49ug/L16.86 213.323246.197174.951'1l)>Standard210/5/20101:14:56PMBa511.692ug/L4.37492.721506.014536.342GlmICY10/5/20101:16:23PM8a912.4225.344ug/L23.45184.098284.912207.021z0"'ICS"'10/5/20101:18:08PMBa17.74.36933ug/L170.382.3167312.624S-1.83354"'IC810/5/20101:20:11PM8a-21.3-5.25889ug/L109.27-9.95357 -6.972691.14958Page65of103, c **~** -u

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1 00912.501 -1 100912.502-1

1 00912.503-1 100912.8-2A 100912.SAI1-2A 100912.SAI2 -2A 100912.SA12-2AD 100912.SAI3-2A 100912.SA01-2A CCB CCV 1 00912.SA02-2A

1 00912.SA03-2A

1 00912.411-2A 100912.411-2AS

1 00912.412-2A

1 00912.413-2A

1 00912.401-2A 100912.402-2A

1 00912.403-2A

1 00912.511-2A 100912.512-2A CCV CCB 100912.513-2A 100912.501-2A

1 00912.502 -2A 100912.503-2A CCV CCB Calib Blank 1 Standard 1 Standard 2 Date 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/2010 10/5/201 0 10/5/2010 10/5/201 0 10/5/2010 10/5/2010 10/5/2010 10/5/201 0 10/5/2010 9/30/2010 9/30/2010 9/30/2010 Time 1:22:01 PM 1:23:22 PM 1:24:50 PM 1:26:22 PM 1:28:06 PM 1:29:31 PM 1:30:55 PM 1:32:09 PM 1:33:43 PM 1:35:07 PM 1:38:43 PM 1:42:00 PM 1:43:34 PM 1:45:14 PM 1:47:03 PM 1:48:30 PM 1:50:19 PM 1:51:43 PM 1:53:01 PM 1:54:32 PM 1:56:39 PM 1:57:58 PM 1:59:20 PM 2:05:54 PM 2:08:19 PM 2:09:46 PM 2:11:06 PM 2:12:35 PM 2:14:07 PM 2:16:55 PM 2:18:57 PM 10:46:36 AM 10:48:10 AM 10:49:32 AM Elem Ba Ba Sa Sa Sa Ba Sa Ba Sa Sa Ba Ba So Sa Sa Sa Ba Ba Ba Sa Sa Sa Sa Sa Ba Ba Sa 8a Sa Sa Ba p p p Cone (Cali In! (Carr) Calib Unil RSD (Carr In! (Carr) lint **(Carr)~** In! (Corr)J

54.6 13.4964 ug/l 256.35 -23.1093 17.9427 45.6559

5.5 1.3676 ug/l 443.60 6.08736 3.49078 -5.47533

7.1 1.74304 ug/l 598.41 -10.2618 8.58604 6.90492

-21.0 -5.19149 ug/l 44.72 -3.37455 -7.80695 -4.39297

-42.5 -10.4884 ug/l 63.52 -4.1039 -9.9649 -17.3965

-10.3 -2.54643 ug/l 1594.32 43.0095 -15.7 478 -34.9009

57.7 14.252 ug/l 224.84 21.1433 -20.6773 42.2901

-0.1 -0.02727 ug/L 65790.27 20.6572 -11.3489 -9.39005

29.3 7.24685 ug/l 57.19 6.12365 3.77949 11.8374

92.3 22.8018 ug/l 66.14 37.4266 23.678 7.30073

9.7 2.3869 ug/l 388.79 5.94004 9.36524 -8.14459

1014.3 250.496 ug/L 8.88 242.938 275.545 233.005

14.4 3.5578 ug/l 219.97 2.1781 -3.48672 11.982

28.3 6.99349 ug/l 26.32 9.08719 6.26166 5.63162

5.3 1.31858 ug/l 1693.97 15.6543 12.719 -24.4175

972.7 240.238 ug/l 7.30 220.857 255.026 244.831

104.5 25.813 ug/l 102.76 53.661 22.9313 0.84657

114.4 28.2442 ug/l 67.91 20.5169 14.1337 50.082

-3.2 -0.79213 ug/l 1165.06 -11.4295 3.97368 5.07944

21.5 5.31147 ug/l 67.29 5.4265 8.8268 1.68111

126.7 31.2956 ug/l 36.66 18.1274 39.1322 36.6272

66.9 16.5157 ug/l 141.81 7.98174 -1.44171 43.0071

-62.5 -15.4402 ug/l 79.85 -1.21249 -22.988 -22.12

1087.9 268.679 ug/l 10.52 236.066 285.954 284.016

15.3 3.78055 ug/l 117.28 -1.20073 7.29531 5.24708

86.0 21.242 ug/l 90.95 25.8581 37.8348 0.03312

19.8 4.89999 ug/l 30.72 3.75513 4.34003 6.60482

59.2 14.612 ug/l 22.58 11.5532 14.1753 18.1075

48.7 12.0305 ug/l 128.32 25.6493 15.1816 -4.73936

1093.2 270.001 ug/l 15.18 317.187 243.303 249.512

-11.9 -2.93683 ug/L 593.94 16.4167 -17.4443 -7.78289
108.671 ug/l 7.76157 110.801 99.3752 115.836
880.264 ug/l 1989.45 ug/l Page 66 of 103 0.70047 877.205 887.361 876.225 0.34763 1981.88 1995.45 1991 CD 0 **~** r

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"')>SampleIDDateTimeElemCone(Calilnt(Corr)CalibUnitRSD(Corrlnt(Corr)llntIn!(Corr)3-<0ICY,9/30/201010:51:35AMp4696.98912.933ug/L0.72285914.62918.525905.654:uICB9/30/201010:54:06AMp18.53083.60176ug/L89.28446.727810.303133.774350ICS9/30/201010:56:55AMpm029.06595.64943ug/L262.098.0577-10.213719.1043-<100912.LB9/30/201010:58:40AMp67.51113.1219ug/L91.664321.075119.006-0.71547z0100912.LCS9/30/201011:00:16AMp4517.53878.055ug/L1.45885880.685889.346864.135100912.8-19/30/201011:02:29AMp104.50120.3115ug/L19.447317.878118.187324.8692"'..100912.SAI1-1SX29/30/201011:26:01AMp5224.751015.51ug/L0.879591023.81016.681006.05"'100912.SAI1-1X29/30/201011:32:35AMp188.67636.6723ug/L30.793749.496528.215132.3054100912.SAI2-19/30/201011:34:05AMp356.78169.3461ug/L22.358676.569651.547579.9212100912.SAI2-1D9/30/201011:35:42AMp320.73662.3403ug/L15.413169.94265.538351.5405)>100912.SA13-19/30/201011:37:15AMp314.58961.1454ug/L16.677252.772858.161672.5018cGlm100912.SA01-19/30/201011:38:37AMp159.79931.0596ug/L18.053233.654624.624934.8992c,100912.SA02-19/30/201011:40:07AMp171.51433.3365ug/L20.139934.353339.484126.1722>c;"'"""'CCV9/30/201011:41:48AMp4962.46964.535ug/L0.32328963.452962.102968.05mS::m-uzs:CCB9/30/201011:47:00AMp97.502118.9511ug/L28.697415.144716.528825.1799"'..,_,_0moo"'100912.SA03-19/30/201012:14:10PMp147.07628.5867ug/L44.196741.720616.519527.52....::ti.Ul--!100912.411-19/30/201012:15:44PMp252.43549.0648ug/L29.054437.304764.919444.9702"':u"'oom100912.412-19/30/201012:17:09PMp165.48732.165ug/L4.5543233.053632.967230.47420O)>rf>Oc:--1"'"'""100912.413-19/30/201012:18:44PMp272.60552.9852ug/L6.1311549.398455.729853.8273"'"'"'co100912.401-19/30/201012:20:27PMp195.73138.0435ug/L35.291825.976435.647852.5063-<m100912.402-19/30/201012:21:56PMp190.49437.0257ug/L26.568129.705548.207633.1639,os;""'100912.403-19/30/201012:23:30PMp189.236.7741ug/L37.535224.492734.116751.7128z-<100912.512-19/30/201012:25:12PMp303.59659.0087ug/L18.708255.44650.190671.3897"'100912.513-19/30/201012:28:01PMp185.34436.0246ug/L25.2639 29.984246.492531.5972CCV9/30/201012:29:53PMp5045.98980.769ug/L0.79882972.16982.664987.482CCB9/30/201012:41:41PMp120.36623.3951ug/L29.787131.422918.903219.8591)>CalibBlank110/5/20101:11:19PMp26.572ug/L43.6623.63739.359116.7199,Standard110/5/20101:13:25PMp1235.38ug/L0.891241.25 1222.751242.14,mzStandard210/5/20101:14:56PMp2451.21ug/L0.112448.592454.142450.890xICY10/5/20101:16:23PMp5022.91233.19ug/L1.341247.271237.2712i5.03,e;ICS10/5/20101:18:08PMp34.28.40564ug/L45.006.3966212.76916.05121m10/5/201022.55.53145ug/L299.8623.73231.59383-8.73183zICB1:20:11PMp0100912.511-110/5/2010171.0"'1:22:01PMp<041.9873ug/L25.1833.574553.855538.5319"'100912.501-110/5/20101:23:22PMp76.718.8405ug/L51.0511.510629.732215.2786Page67af103)> Sample 10 Date Time Elem Cone (Cali lnt (Corr) Calib Unil RSO (Corr In! (Corr)llnt **(Corr)~** In! (Corr)3

--<

0 100912.502-1

" 10/5/2010 1:24:50 PM p 89.4 21.96 ug/L 54.64 11.0943 34.8362 19.9496

" 100912.503-1 10/5/2010 1:26:22 PM p 100.4 24.6461 ug/L 19.39 19.8357 24.7095 29.3932

0 L 1 00912.B-2A 10/5/2010 1:28:06 PM p

rn

0 42.3 10.374 ug/L 146.68 -0.02311 3.30605 27.8389

..; 1 00912.SAI1-2A 10/5/2010 1:29:31 PM p 184.6 45.3294 ug/L 41.09 61.5197 24.9753 49.4933

z ? 100912.SAI2-2A 10/5/2010 1:30:55 PM p 163.2 40.0622 ug/L 23.89 29.1625 47.1019 43.9222

**~** 1 00912.SA12-2AD 10/5/2010 1:32:09 PM p 156.6 38.455 ug/L 8.46 38.7481 41.5534 35.0635

':l ... 100912.SA13-2A 10/5/201 0 1:33:43 PM p 169.7 41.6655 ug/L 32.85 30.3412 56.8736 37.7818

"' 100912.SA01-2A 10/5/2010 1:35:07 PM p 146.4 35.9334 ug/L 24.77 35.3134 27.3572 45.1297

CCV 10/5/201 0 1:36:28 PM p 5352.5 1314.1 ug/L 1.31 1316.03 1330.22 1296.03

cc8 10/5/2010 1:38:43 PM p 33.7 8.2851 ug/L 85.48 14.0472 10.4299 0.37817

)> 100912.SA02-2A 10/5/2010 1:43:34 PM p 115.1 28.2651 ug/L 18.13 30.8037 31.6241 22.3676

c Glrn 100912.SA03-2A 10/5/2010 1:45:14 PM p 175.1 42.9783 ug/L 10.92 42.2211 38.7083 48.0054

c., **~)>** 1 00912 .41l-2A 10/5/2010 1:47:03 PM p 112.3 27.5812 ug/L 42.69 14.9118 38.1913 29.6406

"o **cn~:u** 100912.411-2AS 10/5/2010 1:48:30 PM p 3911.5 960.328 ug/L 1.96 981.873 947.174 951.939

rn)>rn

-uzs: 100912.412-2A 10/5/2010 1:50:19PM p 137.4 33.7404 ug/L 21.26 36.5946 39.0455 25.5811 "'

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:S:AfQ 100912.413-2A 10/5/2010 1:51:43 PM p 63.0 15.4583 ug/L 50.65 14.0403 8.43485 23.8998 "

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143.8 2.80 36.3647 ,..

::0 _Ol __, 100912.401-2A 10/5/2010 1:53:01 PM p 35.3023 ug/L 34.4138 35.1286 "'

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**~** );:.{/) 100912.402-2A 10/5/2010 1:54:32 PM p 123.0 30.2063 ug/L 6.52 28.0565 31.9256 30.6367 0

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(1)'0 1 00912.403-2A 10/5/2010 1:56:39 PM p 91.0 22.3419 ug/L 30.52 25.768 14.4902 26.7675 (/)

"'" co 1 00912.511-2A 10/5/2010 1:57:58 PM p 122.8 30.1407 ug/L 9.83 33.5321 28.0571 28.8329

:OL -<rn 1 00912.512-2A 10/5/2010 1:59:20 PM p 179.0 43.9516 ug/L 20.64 53.1097 43.7768 34.9684

.,o s;:--< CCV 10/5/2010 2:02:51 PM p 4581.7 1124.87 ug/L 1.44 1115.01 1143.54 1116.06

z

..; CCB 10/5/2010 2:08:19 PM p 47.1 11 .5546 ug/L 99.44 2.02893 8.3205 24.3144

"' 100912.513-2A 10/5/2010 2:09:46 PM p 42.1 10.3475 ug/L 92.67 7.12998 21.1317 2.78071

100912.501-2A 10/5/2010 2:11:06 PM p 136.3 33.4646 ug/L 11.93 35.5019 28.8637 36.0282

100912.502-2A 10/5/2010 2:12:35 PM p 156.5 38.4298 ug/L 29.52 27.3209 37.9757 49.9929

)> 100912.503-2A 10/5/2010 2:14:07 PM p 162.4 39.8656 ug/L 17.17 46.5805 32.8999 40.1165

" 10/5/201 0

" CCV

rn 2:15:36 PM p 4836.9 1187.51 ug/L 2.47 1156.81 1215.2 1190.54

z CCB 10/5/201 0 2:18:57 PM p -7.9 -1.93136 ug/L 199.40 2.32703 -5.16966 -2.95145

0 x

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() Sample ID Date Time Elem Cone (Calillnt (Corr) Calib Unitl RSD (Corr lnt (Corr)1 lnt (Corr)2 lnt (Corr)3

" ;o Colib Blank 1 10/5/2010 10:16:34 AM Be 24979.75 ug/L 0.746267 24935.06 25184.45 24819.74

0 **~** m Standard 1 10/5/2010 10:18:05AM Be 1223052.84 ug/L 3.658159 1175160 1230223 1263776

()

-j Standard 2 10/5/2010 10:18:59 AM Be 2485883.46 ug/L 1.732014 2448535 2476139 2532976

z **~** ICY 10/5/2010 10:22:12 AM Be 1014.94 1257476.2B ug/L 0.246379 1255005 1256471 1260952

" ICB 10/5/2010 10:23:48 AM Be -0.09 -112.66 ug/L 31.79334 -152.B7 -100.964 -84.157

0

:;: ICS 10/5/2010 1 0:24:58 AM Be -0.38 -466.70 ug/L 11.43757 -501.036 -493.85 -405.199

N

1 00912.LB 10/5/2010 10:26:51 AM Be -0.41 -504.70 ug/L 18.20084 -431.213 -475.194 -607.682

100912.LCS 10/5/2010 10:28:03 AM Be 871.44 1079680.09 ug/L 2.945141 1047071 1081369 1110600

1 00912.B-1 10/5/2010 l 0:29:40 AM Be -0.62 -771.62 ug/L 20.23049 -650.271 -947.726 -716.871

)> 100912.SA11- 1 10/5/2010 10:30:53 AM Be -0.42 -521.7 4 ug/L 12.96059 -533.516 -582.69 -448.999

c 100912.SA12-1 10/5/2010 10:32:10 AM Be -0.35 -436.41 ug/L 42.89968 -650.492 -355.417 -303.327

"'m c, 1 00912.SA12-1 S 10/5/2010 10:35:59 AM Be 834.62 1034061.85 ug/L 1.944963 1012731 1036774 1052680

**~)>** l>o l 00912.SA13- 1 10/5/2010 10:37:38 AM Be -0.17 -208.79 ug/L 51.86936 -87.8084 -241.884 -296.687

(/)"\J;o 1 00912.SA13-1 D 10/5/2010 10:38:27 AM Be -0.50 -618.37 ug/L 18.61515 -603.902 -740.036 -511.182

m';m -ozs: 1 00912.SA01-1 10/5/2010 10:39:40 AM Be -0.95 -1171.81 ug/L 21.32379 -975.671 -1453.14 -1086:62

-l-j- "'

m(l)(l) 100912.SA02-1 10/5/2010 10:40:49 AM Be -0.97 -1196.82 ug/L 4.530319 -1211.45 -1136.7B -1242.22 0

**~~!!? ~** 

**:;g""~** CCV 10/5/2010 10:42:00AM Be 9B0.65 1214985.81 ug/L 2.280918 1185571 1218780 1240606 ....

**:::0~01** __, "'

N(/)m CCB 10/5/2010 10:43:24AM Be -0.96 -1195.28 ug/L 13.79672 -13B1.46 -1136.76 -1067.6 ;o

**~):>(/)** 100912.SA03-1 10/5/2010 10:44:32 AM Be -0.70 -869.55 ug/L 6.624992 -B03.657 -894.609 -910.385 0

oC:_, "

(1)"0 (/)

[D;!J 100912.411-1 10/5/2010 10:45:45 AM Be -0.85 -1053.02 ug/L 7.630754 -994.70B -1019.67 -1144.68

co

**;o~** 100912.412-1 10/5/2010 10:46:55 AM Be -0.93 -1155.79 ug/L 18.92245 -917.652 -1347.65 -1202.07

-<m

,o 100912.413-1 10/5/2010 10:4B:02 AM Be -0.89 -1106.59 ug/L 8.217627 -1001.61 -1157.04 -1161.11

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z 100912.401-1 10/5/2010 10:49:15 AM Be -1.14 -1414.46 ug/L 8.063598 -1506.76 -1449.67 -1286.95

-j 100912.402-1 10/5/2010 10:50:24 AM Be -1.08 -1341.37 ug/l 19.87531 -1094.69 -1305.23 -1624.21

'" 100912.403-1 10/5/2010 10:51:33 AM Be -1.12 -1390.78 ug/L 17.83337 -1575.77 -1108.94 -1487.61

100912.512-1 10/5/2010 10:52:48 AM Be -1.10 -1364.12 ug/L 14.02859 -1277.47 -15B3.49 -1231.41

100912.513-1 10/5/2010 10:53:58 AM Be -0.93 -1153.86 ug/L 6.3083 -1154.94 -1226.1 -1080.54

CCV 10/5/2010 10:55:52 AM Be 983.17 1218106.74 ug/L 1.762433 1194221 1224306 1235794

)> CCB 10/5/2010 10:57:26 AM Be -1.06 -1314.05 ug/L 23.43513 -1640.37 -1028.54 -1273.24

" " m 100912.501-1 10/5/2010 10:58:34 AM Be -0.88 -1 089 .84 ug/L 24.38381 -1356.38 -1088.24 -824.9

z

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1:53:28 PM 0.00043 0 1:58:54 PM 0.03442 0 2:04:21 PM 0.0859 0 2:09:49PM 0.17017 0 2:15:13 PM 0.29568 0 2:22:52 PM 0.16752 98.4 1.4 97.416 99.309

2:28:18 PM 0.00147 0.9 23.3 0.996 0.715

2:33:46 PM 0.00088 0.5 16.5 0.450 0.569

2:39:15 PM 0.16699 98.0 1.1 98.828 97.261

2:44:41 PM 0.00015 0.1 502.5 -0.222 0.395

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1 00912.LCS 100912.8-1

1 00912.SA11-1

1 00912.SAI2-1

1 00912.SA12-1 S

1 00912.SAI3-1 100912.SAI3-1D 100912.SA01-1

1 00912.SA02-1 CCV CCB 1 00912.SA03-1 100912.411-1 100912.412-1 100912.413-1 100912.401-1 100912.402-1 100912.403-1 100912.512-1 100912.513-1 CCV CCB 100912.501-1 100912.502-1 100912.503-1 CCV Date 10/1/2010 10/1/2010 10/1/2010

1 0/1/2010 10/1/2010 10/1/2010 10/1/2010 Time 10:12:10 AM 10:14:11 AM 10:15:06 AM 10:16:08 AM 10:17:32 AM 10:19:09 AM 10:20:40 AM 10/1/2010 10:21:45 AM

1 0/1/201 0 10:24:19 AM

1 0/1/201 0 10:26:04 AM 10/1/2010 10:30:38 AM 10/1/2010 10:32:37 AM 10/1/2010 10:34:51 AM 10/1/2010 10:35:38AM 10/1/2010 10:37:49AM

1 0/1/2010

1 0/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010

1 0/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010

1 0/1/2010 10:39:01 AM 10:41:09 AM 10:42:26 AM 10:43:35 AM 10:45:18 AM 10:46:45 AM 10:49:44 AM 10:51:26 AM 10:52:52 AM 10:54:07 AM 10:55:37 AM 10:57:08 AM 10:58:42 AM 11:00:09 AM 11:01:16 AM 11:02:25 AM 11:03:37 AM 11:05:04 AM Elem Cone (Calillnt (Corr) Calib RSD (Cor lnt (Corr)l lnt (Corr)21nt (Corr)3

Cr 168.829 ug/L 3.05 168.946 173.9176 163.6235

Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr 16303.31 ug/L 32442.64 ug/L 1009.60 16393.67 ug/L 0.49 7.885636 ug/L 0.86 13.9741 ug/L 1.17 19.05121 ug/L 953.66 15485.19 ug/L 20.80 337.7138 ug/L 16.91 274.6391 ug/L 23.76 385.8631 ug/L 964.69 15664.41 ug/L 24.12 391.588 ug/L 25.30 410.7741 ug/L 16.40 266.3105 ug/L 13.45 1022.82 1.60 14.19 24.19 21.61 22.69 21.56 22.26 26.97 18.87 20.32 1052.60 2.06 218.3945 ug/L 16608.19 ug/L 25.9962 ug/L 230.4006 ug/l 392.8074 ug/L 350.8375 ug/L 368.353 ug/l 350.1555 ug/L

3 61.4087 ug/L 437.9897 ug/L 306.4275 ug/L 330.0007 ug/L 17091.84 ug/l 33.437 ug/L 20.12 326.7194 ug/l 16.28 264.3521 ug/L 16.16 262.4098 ug/l 1038.25 16858.82 ug/L Page 76 of 103 1.21 16188.03 16190.99 16530.9

0.35 32414.54 32347.32 32566.06

3.10 15842.1 16845.02 16493.88 135.78 19.96992 4.104537 -0.41755
30.86 14.93038 9.263883 17.72805 102.63 36.42879 22.84503 -2.12018

0.53 15397.41 15560.66 15497.52

3.35 337.9967 348.8866 326.258

1.88 269.4557 279.7838 274.6777

3.78 374.824 402.4125 380.3528

1.47 15402.85 15750.93 15839.46

4.78 380.2094 381.3459 413.2088

2.01 411.7394 402.0948 418.4879

3.14 269.2422 272.8141 256.8752

9.78 202.0057 242.5446 210.6333

0.68 16508.49 16731.14 16584.95
82.53 10.12821 17.45545 50.40494

4.43 242.0227 222.8777 226.3014

2.04 383.8103 395.4225 399.1895

3.20 348.5556 340.9175 363.0392

3.03 365.5151 380.6636 358.8802

4.19 363.3398 352.7678 334.3589

2.63 372.3882 356.0682 355.7697

3.67 421.0543 453.0553 439.8595

6.82 324.4135 311.3551 283.514

1.82 332.2048 334.6042 323.1931

1.08 16924.49 17061.6 17289.44
36.91 27.01704 25.62701 47.66694

2.00 329.1812 319.3219 331.6551

7.71 249.7263 287.6305 255.6995

0.85 262.8045 264.4124 260.0126

1.34 16614.85 17060.21 16901.4 OJ 0 **~** r

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1 00912.SA11-1 100912.SA12-1 100912.SA12-1S 100912.SA13-1 100912.SA13-1 D 100912.SA01- 1 100912.SA02-1 COl CCB 100912 .SA03- 1 100912.411-1 100912.412-1 100912.413-1 100912.401-1 Date Time

1 0/1/2010 1 :06:52 PM 10/5/2010 12:36:02 PM 10/5/2010 12:37:15 PM 10/5/2010 12:38:10 PM 10/5/2010 12:39:45 PM 10/5/2010 12:41:06PM

1 0/5/2010 12:42:15 PM 10/5/2010 12:43:31 PM 10/5/2010 12:46:40 PM 10/5/2010 12:48:13 PM 10/1/2010 10:12:10AM 10/1/2010 10:14:11 AM 10/1/2010 10:15:06 AM 10/1/2010 10:16:08AM 10/1/201 b 10:17:32 AM 10/1/2010 10:19:09 AM 10/1/2010 10:20:40 AM 10/1/2010 10:21:45AM 10/1/2010 10:24:19 AM 10/1/2010 10:26:04 AM 10/1/2010 10:30:38 AM 10/1/2010 10:32:37 AM 10/1/2010 10:34:51 AM 10/1/2010 10:35:38 AM 10/1/2010 10:37:49 AM 10/1/2010 10:39:01 AM 10/1/2010 10:41 :09 AM 10/1/2010 10:42:26 AM 10/1/2010 10:43:35 AM 10/1/2010 10:45:18AM 10/1/2010 10:46:45 AM 10/1/2010 10:49:44 AM Elem Cr Cr Cr Cr Cr Cr Cr Cr Cr Cr Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu 10/1/2010 10:51:26AM Cu Cone (Calillnt (Carr) Calib RSD (Cor lnt (Corr)llnt (Corr)21nt (Corr)3

-0.24 -4.17557 ug/L 228.31 -5.37399 5.90008 -13.0528 216.6773 ug/L 9 _04189 218.4759 196.2482 235.3076 17964.59 ug/L 1.53719 17647.78 18154.36 18091.63 37266.75 ug/L 0.87768 37034.67 37124.75 37640.84

97 4.5 18027.0 ug/L 1.46822 17784.42 17987.22 18309.27

-1.9 -34.9 ug/L 19.7743 -35.46 -41.4608 -27.7053

-0.5 -9.3 ug/L 78.1822 -7.50853 -3.0835 -17.2785

16.4 961.8 304.1 ug/L 4.12212 317.8263 301.1012 293.2919
17793.7 ug/L 1.85689 17442.12 17841.14 18097.81

-0.6 -11.0 ug/L -2405.46 ug/L 85129.39 ug/L

1 68499 _1 ug/L 1011.28 85377.63 ug/L -0.20 -16.5093 ug/L -0.28 -23.804 ug/L -0.74 -62.6935 ug/L 975.39 82347.96 ug/L

1. 77 149.4783 ug/L 53.18 4489.779 ug/L 52.60 4440.436 ug/L 1046.50 88350.94 ug/L 48.09 4059.708 ug/L 48.98 4135.026 ug/L 2.16 182.1629 ug/L 3.34 281.6521 ug/L 1036.13 87475.61 ug/L -0.92 -77.7574 ug/L 2.87 242.408 ug/L 3.09 260.6859 ug/L 1.48 124.6719 ug/L 2.09 1 76.4825 ug/L 4.20 354.9151 ug/L Page 78 of 103 96.5139 -20.42 -13.1132 0.511536

0.43 -2401.42 -2417.27 -2397.69

1.06 84442.34 84790.35 86155.48

0.56 169593.5 167875.1 168028.6

4.36 81901.44 89304.54 84926.9 307.12 -50.3406 41.78743 -40_9749
68.98 -4.84402 -33.3759 -33.192
45.91 -30.0508 -73.5994 -84.4301

1.16 81649.94 83436.29 81957.67
39.87 86.61381 156.6606 205.1606

2. 72 4360.053 4506.227 4603.056

2.96 4288.743 4524.638 4507.926

2.26 86071.33 89171.41 89810.06

3.31 3916.907 4078.7 4183.516

0.18 4135.781 4127.154 4142.144
25.88 130.185 194.1503 222.1535

6.31 262.3354 285.3068 297.314

1.39 86946.66 88864.79 86615.37
17.59 -93.5259 -69.0696 -70.6767

0.94 241.9934 240.3713 244.8594
11.14 229.046 286.1222 266.8896
22.47 96.28556 152.2926 125.4376

4.83 168.0359 176.342 185.0695

3.20 356.6873 342.7675 365.2903 11.• "' 0 52

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:?: Sample 10 100912.402-1 100912.403-1 100912.512-1 100912.513-1 CCV CCB 100912.501-1 100912.502-1 100912.503-1 CCV CCB Calib Blank 1 Standard 1 Standard 2 ICY ICB ICS 100912.B-2A 100912.5Ail-2A

1 00912.5Al2-2A

1 00912.SAI2-2AS

1 00912.SAI3-2A

1 00912.SA13-2AD 100912.SA01-2A CCV CCB 1 00912.SA02-2A 100912.SA03-2A

1 00912.411 -2A 100912.412-2A

1 00912.413-2A

1 00912.401-2A

1 00912.402-2A Date Time 10/1/2010 10:52:52 AM

1 0/1/2010 10:54:07 AM 10/1/2010 10:55:37 AM 10/1/2010 10:57:08 AM 10/1/2010 10:58:42 AM 10/1/2010 11:00:09 AM 10/1/2010 11:01:16AM 10/1/2010 11 :02:25AM

1 0/1/2010 11 :03:37AM 10/1/2010 11:05:04 AM 10/1/2010 11:06:35 AM 10/1/2010 12:17:26 PM 10/1/2010 12:18:25 PM 10/1/2010 12:19:17 PM 10/1/2010 12:20:21 PM 10/1/2010 12:21 :44 PM

1 0/1/2010 12:22:48 PM 10/1/2010 12:24:10 PM 10/1/2010 12:25:25 PM 10/1!2010 12:26:40 PM 10/1/2010 12:28:10 PM 10/1/2010 12:34:34 PM 10/1/2010 12:35:22 PM 10/1/2010 12:37:04 PM 10/1!2010 12:38:57PM 10/1/2010 12:40:28PM 10/1/2010 12:41:34PM 10/1/2010 12:44:20 PM 10/1/2010 12:45:50 PM 10/1/2010 12:46:57 PM 10/1/2010 12:48:02 PM 10/1/2010 12:49:42 PM 10/1/2010 12:50:47 PM Elem Cone (Calillnt (Carr) Calib RSD (Cor In! (Corr)l In! (Corr)21nt (Corr)3

Cu 2.35 198.4596 ug/l 6. 71 199.3078 211.3367 184.7343

Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu 3.19 7.61 7.89 1042.76 -0.86 1.71 2.60 2.79 1028.67 -1.04 1005.52 0.49 -0.12 1.44 26.48 14.56 834.77 16.46 18.14 6.30 1039.32 0.23 8.30 11.12 6.73 7.67 5.72 10.12 4.11 269.4813 ug/L 642.1255 ug/l 665.7815 ug/L 88035.7 ug/L -72.6476 ug/L 144.1516 ug/l 219.6394 ug/L 235.8355 ug/L 86846 ug/L -87.7735 ug/L -2546.65 ug/L 89157.63 ug/L 180990. 1 ug/L 90726.04 ug/L 43.98768 ug/L -11.084 ug/L 130.2436 ug/L 2389.449 ug/L 1313.919 ug/L 75319.56 ug/L 1484.7 48 ug/l 1637.061 ug/L 568.309 ug/l 93775.33 ug/l 20.49706 ug/L

7 48.5483 ug/l 1003.419 ug/L 607.1799 ug/L 692.2285 ug/L 516.5505 ug/l 912.855 ug/l 370.9525 ug/L Page 79 of 1 03 2.68 276.1309 270.5269 261.7862

1.36 639.8957 651.7248 634.756

5.39 640.7735 649.7012 706.8699

0.87 87155.47 88495.65 88455.97
40.73 -54.3723 -106.788 -56.7826
18.88 17 4.5484 135.8652 122.0412

9.61 230.1904 233.3965 195.3313

6.90 217.1991 243.1344 247.1729

2.17 85289.7 88946.86 86301.43
26.02 -70.7168 -78.8877 -113.716

1.05 -2529.19 -2533.26 -2577.51

2.11 87351.04 89018.07 91103.79

1.71 179203.7 179210.2 184556.6

0.18 90570.96 90902.84 90704.31
40.58 23.72101 57.36908 50.87296 310.83 -50.7804 6.506393 11.02199
23.36 129.4315 100.2376 161.0617

3.57 2290.86 2437.293 2440.193

5.82 1226.046 1349.742 1365.969

1.10 75862.58 74362.17 75733.94

3.87 1419.081 1525.997 1509.165

0.77 1650.871 1626.106 1634.207

3.80 546.3028 589.4982 569.1259

0.93 94046.54 92795.83 94483.63
81.65 33.68301 1.66825 26.13992

6.07 710.5937 798.8995 736.1517

5.00 945.861 1026.605 1037.792

2.34 623.5869 599.8136 598.1393

3.06 673.9517 715.4552 687.2785

7.58 526.09 473.5009 550.0605

4.89 869.1357 9111305 958.2989
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1 00912.501-2A 100912.502-2A 100912.503-2A CCV CCB Calib Blank 1 Standard 1 Standard 2 ICY ICB ICS 100912.511-1 CCV CCB Calib Blank 1 Standard 1 Standard 2 ICV ICB ICS 100912.LB

1 00912.LCS 100912.8-1

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1 00912.SA13-1 Date Time Elem 10/1/2010 12:51:58 PM Cu

1 0/1/2010 12:53:37 PM Cu 10/1/2010 12:54:50PM Cu 10/1/2010 12:56:26 PM Cu 10/1/2010 12:57:48 PM Cu 10/1/2010 12:58:49 PM Cu 10/1/2010 1:00:41 PM Cu 10/1/2010 1 :01:47 PM Cu 10/1/2010 1 :03:20 PM Cu 10/1/2010 1 :05:04 PM Cu 10/1/2010 1 :06:52 PM Cu 10/5/2010 12:36:02 PM Cu 10/5/2010 12:37:15 PM Cu 10/5/2010 12:38:1 0 PM Cu 10/5/2010 12:39:45 PM Cu 10/5/2010 12:41:06 PM Cu 10/5/2010 12:42:15 PM Cu 10/5/2010 12:43:31 PM Cu 10/5/2010 12:46:40 PM Cu 10/5/2010 12:48:13 PM Cu 10/1/2010 10:12:10AM Mn 10/1/2010 10:14:11 AM Mn 10/1/2010 10:15:06AM Mn 10/1/2010 10:16:08 AM Mn 10/1/2010 10:17:32 AM Mn 10/1/2010 10:19:09 AM Mn 10/1/2010 10:20:40 AM Mn 10/1/2010 10:21:45 AM Mn 10/1/2010 10:24:19 AM Mn 10/1/2010 10:26:04AM Mn 10/1/2010 10:30:38AM Mn 10/1/2010 10:32:37 AM Mn 10/1/2010 10:34:51AM Mn Cone (Calillnt (Corr) Calib RSD (Cor lnt (Corr) 1 In! (Corr)2 In! (Corr)3

14.25 1285.595 ug/L 3.35 1235.98 1312.767 1308.037

7.96 717.8306 ug/L 8.64 647.0503 743.6407 762.8008

6.31 569.5036 ug/L 1042.96 94103.72 ug/L 0.18 15.83807 ug/L 8.70 512.2923 598.6911 597.5275

1.04 93638.59 95223.64 93448.93 407.24 86.99996 -38.7733 -0.7124

8.88 12.25 10.78 10.29 1065.35 0.57 970.1 -0.5 -1 .1 8.2 960.5 -0.2 801.3411 ug/L 5.13 754.8 832.4989 816.7243 1105.417 ug/L 4.09 1054.296 1121.556 1140.398 972.4859 ug/L 3.67 935.9837 974.2074 1007.267 928.3071 ug/L 10.82 817.0889 955.3209 1012.511 96124.06 ug/L 0.73 96303.53 96723.49 95345.16 51.30953 ug/L 33.51 35.04834 49.57294 69.3073
-2336.3 ug/L 1.29831 -2370.33 -2326.49 -2312.09
91537.7 ug/L 1.46043 89994.46 92340.6 92278.02 186908.0 ug/L 1.50968 186263 184464.6 189996.3
90289.3 ug/L 2.03278 88752.26 89794.21 92321.45

-47.0 ug/L 29.3681 -34.0408 -61.5285 -45.4817

-98.1 ug/L 16.8744 -80.4141 -113.229 -100.527

765.2 ug/L 5.89608 714.05 782.1952 799.3447
89397.7 ug/L 1.96062 87376 90326.94 90490.16

-21.6 ug/L 109.077 -35.4879 5 610828 -35.0005 537.3715 ug/L 4.39 538.7164 513.1184 560.2797 217775.9 ug/L 2.10 212518.3 220027.6 220781.9 443798.2 ug/L 999.61 220988.1 ug/L 0.03 7.025472 ug/L -0.70 -153.739 ug/L 0.11 23.50157 ug/L 0.17 444245 442927.7 444221.9

1.30 218107.3 221002.2 223854.8 256.74 26.09894 -9.75569 4.733172
10.22 -169.252 -154.124 -137.84
33.64 15.17134 24.43482 30.89856

1.71 205164.9 211829 210758.9

946.52 209250.9 ug/L 10.88 2406.283 ug/L 118.24 26139.4 ug/L 121.23 26801.37 ug/L 1042.67 230507.5 ug/L 123.02 27195.91 ug/L Page 80 of 103 1.73 2441.636 2416.899 2360.314

2.09 25508.97 26470.89 26438.34

2.76 25945.72 27230.11 27228.27

0.62 228991.5 231802.6 230728.5

2.40 26449.57 27473.19 27664.96 "' 0 **~** r

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**~** Sample ID 100912.SAI3-1D 100912.SA01-1

1 00912.SA02- 1 CCV CCB 100912.SA03-1 100912.411-1 100912.412-1 100912.413-1 100912.401-1 100912.402-1 100912.403-1 100912.512-1 100912.513-1 CCV CCB 100912.501-1 100912.502-1 100912.503-1 CCV CC8 Calib Blank 1 Standard 1 Standard 2 ICY ICB ICS 1 00912.B-2A 100912.SAI1-2A 100912.SA12-2A

1 00912.SA12-2AS 100912.SAI3-2A

1 00912.SAI3-2AD Date Time 10/1/2010 10:35:38 AM 10/1/2010 10:37:49 AM 10/1/2010 10:39:01 AM 10/1/2010 10:41:09 AM 10/1/2010 10:42:26 AM 10/1/2010 10:43:35AM 10/1/2010 10:45:18 AM 10/1/2010 10:46:45 AM

1 0/1 /201 0 1 0:49:44 AM 10/1/2010 10:51:26AM 10/1/2010 10:52:52 AM 10/1/2010 10:54:07 AM 10/1/2010 10:55:37 AM 10/1/2010 10:57:08 AM 10/1/2010 10:58:42 AM 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 11:00:09 AM 11:01:16AM 11:02:25 AM 11:03:37 AM 11:05:04 AM 11:06:35 AM 12:17:26 PM 12:18:25 PM 12:19:17 PM 12:20:21 PM 12:21:44 PM 12:22:48 PM 12:24:10 PM 12:25:25 PM 12:26:40 PM 12:28:10 PM 12:34:34 PM 12:35:22 PM Elem Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Mn Cone (Colillnt (Carr) Calib RSD (Cor lnt (Corr)llnt (Corr)2lnt (Corr)3

125.33 27707.68 ug/L 0.29 27647.3 27675.1 27800.66

15.76 3484.25 ug/L 0.55 3501.615 3463.591 3487.544

13.48 2980.238 ug/L 1.62 2924.573 3008.859 3007.283

1014.53 224285.6 ug/L 0.39 86.34078 ug/L 19.45 4299.558 ug/L 12.99 2871.655 ug/L 11.99 2651.599 ug/L 14.87 3287.649 ug/L 12.91 2853.113 ug/L 11.79 2606.4 ug/L 12.51 2765.494 ug/L 61.65 13629.84 ug/L 36.20 8003.992 ug/L 1041.13 230167.5 ug/L 0.49 107.7565 ug/L 19.37 4281.202 ug/L 20.46 4522.416 ug/L 22.86 5054.362 ug/L 1037.55 229376.3 ug/L 0.54 118.8628 ug/L 603.3359 ug/L 231403.2 ug/L 475898.9 ug/L 1032.75 244390.9 ug/L 0.06 14.42587 ug/L -0.81 ·192.062 ug/L 0.99 234.1274 ug/L 150.49 35611.67 ug/L 44.73 10584.47 ug/L 806.99 190967.3 ug/L 44.36 10496.75 ug/L 47.23 11176.08 ug/L Page 81 of 103 0.60 222915.3 225602.5 224339.1
15.57 77.16582 101.771 80.08556

1.42 4243.135 4291.366 4364.173

0.18 2867.608 2877.536 2869.822

2.22 2583.729 2686.138 2684.93

1.62 3237.95 3281.104 3343.892

0.47 2844.035 2868.671 2846.632

0.70 2619.527 2585.699 2613.976

1.46 2721.01 2775.467 2800.006

1.18 13444.89 13723.03 13721.6

1.36 7890.312 8014.528 8107.137

1.61 225883.4 232219.9 232399.2
33.80 125.2667 65.88158 132.1213

1.43 4230.757 4263.572 4349.277

0.85 4485.318 4519.823 4562.108

0.20 5042.729 5060.434 5059.923

0.45 230433 228362.6 229333.2

4.44 119.0753 113.4842 124.029

1.46 613.37 596.9872 599.6505

5.05 218029.5 236531.1 239648.9

1.75 466957.6 477265.2 483473.8

1.31 241612.1 243656.5 247904.3
48.86 19.7 4201 6.430799 17.10479
18.28 -202.12 -153.024 -221.043

0.78 235.2691 235.0892 232.0238

1.14 35233.99 35560.28 36040.76

2.74 10251.02 10726.86 10775.52

0.79 189258.2 191553.7 192089.9

2.51 10205.45 10567.77 10717.04

0.46 11210.88 11116.87 11200.48 **~ ~**  r

"' :0 0

A

(/),c,cilJ"0m()--izp"..NGlem"'"_,,>()en""mS::mlJZS:_,_,_men"'""'z•--iNcnmS::>(/)o!::-1"'""'"co-<m,or;:;--iz--i"',lJlJmz0xlJ,Glmz0"'NSampleID100912.SA01-2ACCVCCB100912.SA02-2A100912.SA03-2A100912.411-2A100912.412-2A100912.413-2A100912.401-2A100912.402-2A100912.403-2A100912.511-2A100912.512-2ACCVCCB100912.513-2A100912.501-2A100912.502-2A100912.503-2ACCVCCBCalibBlank1Standard1Standard2ICYIC8ICS100912.511-1CCVccsCalibBlank1Standard1Standard2Date10/1/201010/1/201010/1/201010/1/201010/1/201010/1/201010/l/201010/1/201010/1/201010/1/201010/1/201010/1/201010/1/201010/1/201010/1/201010/1/201010/l/201010/1/201010/1/201010/1/201010/1/201010/5/201010/5/201010/5/201010/5/201010/5/201010/5/201010/5/201010/5/201010/5/201010/1/201010/1/201010/1/2010Time12:37:04PM12:38:57PM12:40:28PM12:41:34PM12:44:20PM12:45:50PM12:46:57PM12:48:02PM12:49:42PM12:50:47PM12:51:58PM12:53:37PM12:54:50PM12:56:26PM12:57:48PM12:58:49PM1:00:41PM1:01:47PM1:03:20PM1:05:04PM1:06:52PM12:36:02PM12:37:15PM12:38:10PM12:39:45PM12:41:06PM12:42:15PM12:43:31PM12:46:40PM12:48:13PM10:12:10AM10:14:11AM10:15:06AMElemMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnMnNiNiNiCone(Calillnt(Corr)CalibRSD(Cortnt(Corr)llnt(Corr)21nt(Corr)310.052379.211ug/L1.462351.148 2368.5252417.9611049.43248337.2ug/L0.20247892248237.1248882.60.0920.65372ug/l8.6821.0093318.7092522.2425714.443417.294ug/l2.883305.6563455.573490.65680.1818973.42ug/L1.4018684.5119028.8819206.8731.847533.793vg/L1.397418.9067558.0677624.40532,897783.634ug/L1.727631.597 7834.1437885.16216.053798.15ug/L1.003757.2253832.7233804.50217.944244.446ug/L3.094093.4034311.4114328.5258.391985.71ug/L1.331955.2262001.3282000.57517.94178.9820.721051.140.0425.5312.08108.6811.571078.940.10976.0-0.8-1.653.6954.0-0.84244.781ug/L42354.8ug/l4903.567ug/L248741.3ug/L10.1546ug/l6042.313ug/L2859.695ug/L25718.54ug/L2736.798ug/L255321.6ug/L23.63793ug/L820.3ug/l249651.6ug/L517926.6vg/L250934.2ug/L-199.2vg/L-401.0ug/L13770.7ug/L245276.1ug/L-201.2ug/L83.11213ug/L9962.101ug/L19954.92ug/LPoge82of1030.794231.4994219.8624282.9824.7640106.542962.2643995.642.394769.8634951.7384989.0981.25245159.4250238.5250825.9338.5946.870514.87769-21.28442.625875.3916060.8536190.6943.232760.7522874.588 2943.7441.8625167.6325965.4926022.482.542657.992763.0572789.3470.96252510.8256448.8257005.259.6739.4948818.9274412.491482.05532820.6927836.8914803.18221.85034244858.2250022.1254074.70.8236514565516489.6522725.20.71784249052.4252642.5251107.76.11155-185.178-205.5-206.9561.79312-393.4-407.697-401.8942.660613384.2113814.7814112.972.29655239058.7246730.3250039.410.6199-214.031-176.553-213.08517.7489.3846793.680166.271621.269926.911 9857.60110101.790.2920021.9119928.1619914.68"'0r"'"()&))> -< 0 " ;o 0 **~** m 0 -< z 0 :!: 0 .... **~** )> c Glm C-u ':1l> l>fi (f)-u;o m't:m -uzs: -<-.<- m(f)Ul **~.,.~ mi<'O~**  :;:o_c.n -1 **~U>m ~>(/)**  or-< (ii-u '""' co **,~** -<m -uo ..:-< :'i 0> )> " "

m z 0 x **~** m z p **~** w Sample ID ICY ICB ICS 1 00912.LB 100912.LCS 100912.8-1 100912.SA11-1 100912.SA12-1 100912.SA12-1S

1 00912.SA13-1

1 00912.SA13-1 D 100912.SA01-1

1 00912.SA02-1 CCV CCB 100912.SA03-1 100912.411-1 100912.412-1 100912.413-1 100912.401-1 100912.402-1 100912.403-1 100912.512-1 100912.513-1 CCV CCB 100912.501-1 100912.502-1 100912.503-1 CCV CCB Calib Blank 1 Standard 1 Date Time 10/1/2010 10:16:08AM 10/1/2010 10:17:32AM 10/l/2010 10:19:09 AM 10/1/2010 10:20:40 AM 10/1/2010 10:21:45 AM 10/1/2010 10:24:19 AM 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/1/2010 10/l/2010 10:26:04 AM 10:30:38 AM 10:32:37 AM 10:34:51 AM 10:35:38AM 10:37:49 AM 10:39:01 AM 10:41:09 AM 10:42:26 AM 10:43:35 AM 10:45:18 AM 10:46:45 AM 10:49:44 AM 10:51:26 AM 10:52:52 AM 10:54:07 AM 10:55:37 AM 10:57:08 AM 10:58:42 AM 11:00:09 AM 11:01:16AM 11:02:25 AM 11:03:37 AM 11:05:04 AM 11:06:35 AM 12:17:26 PM 12:18:25 PM Elem Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni Ni **~** Cone (Calillnt (Corr) Calib RSD (Cor lnt (Corr)l lnt (Corr)21nt (Corr)3

1004.62 1 0020.47 ug/L 4.22 9633.219 10470.97 9957.224

-2.74 -27.3119 ug/L 104.23 0.610406 -56.2938 -26.2522

-2.90 -28.9048 ug/L 41.67 -42.4607 -24.8173 -19.4365

-2.67 -26.6271 ug/L 965.03 9625.566 ug/L 6.39 63.7 4098 ug/L 5.58 55.64485 ug/L 8.65 86.30799 ug/L 1053.60 10509.05 ug/L 9.90 98.78951 ug/L 11.35 113.2103 ug/L 6.57 65.49158 ug/L 6.67 66.48454 ug/L 1037.87 10352.12 ug/L -0.2 9 -2.88042 ug/L 8.06 80.39373 ug/L 17.43 173.8104 ug/L 10.15 101.2344 ug/L 13.66 136.2253 ug/L 11.16 111.3123 ug/L 12.64 126.0937 ug/L 16.36 163.2211 ug/L 14.49 144.5416 ug/L 10.27 102.4497 ug/L

1 046.70 1 0440.19 ug/L -2.41 -24.0084 ug/L 8.49 84.72481 ug/L 9.08 90.58308 ug/L 10.66 106.3549 ug/L 1039.52 10368.56 ug/L -0.65 -6.52264 ug/L 72.30098 ug/L 10656.64 ug/L Page 83 of 1 03 95.97 -56.1345 -12.1027 -11.644

0.50 9576.523 9672.201 9627.973
23.71 81.0845 56.75916 53.37928
13.34 64.21053 51.54077 51.18327
42.00 78.44649 125.8411 54.63637

2.23 10246.86 10582.44 10697.86
11.72 109.4865 86.50073 100.3814
15.86 133.9331 102.4407 103.2571
15.15 76.33674 56.87823 63.25978
44.54 77.60399 32.91886 88.93077

1.13 10306.39 10485.35 10264.63 140.09 -3.70283 -6.44095 1.502527

2.95 80.28117 82.82006 78.07996

2.64 169.5507 178.6668 173.2135
18.04 88.97089 122.2172 92.51526

7.65 145.068 138.8657 124.7422

5.29 104.5966 113.7243 115.6159
26.70 89.99973 131.639 156.6423

1.44 165.9093 161.5025 162.2515

4.31 151.7238 140.5388 141.3621
22.59 107.2966 122.7857 77.2668

0.79 10345.08 10483.5 10491.99
50.38 -28.7903 -10.2536 -32.9813
24.60 92.14653 100.8391 61.18876
13.55 87.45628 80.17445 104.1185
17.40 113.2798 120.399 85.38596

1.82 1 0279.72 10585.18 10240.79 597.64 -48.263 -0.24422 28.93929
37.37 103.2749 60.05149 53.57653

1.73 1 0478.32 10645.6 10846.01 '"

0 **~** r '" ;o fi 8,. Sample 10 Date Time Elem Cone (Calillnt (Corr) Calib RSD (Cor lnt (Corr)1 lnt (Corr)21nt (Corr)3

--<

0 , Standard 2 10/1/2010 12:19:17 PM Ni 21838.99 ug/L 1.11 21641.63 21765.21 22110.13

"

ICY 10/1/2010 12:20:21 PM Ni 1002.38 10892.81 ug/L 0.26 10866.9 10922.64 10888.9

0 **~** ICB 10/1/2010 12:21:44 PM Ni 0.48 5.265198 ug/L

m 98.37 2.359601 2.191081 11.24491

0 --<

ICS 10/1/2010 12:22:48 PM Ni -2.64 -28.7006 ug/L 79.10 -49.7556 -31.6972 -4.64906

z 0 100912.8-2A 10/1/2010 12:24:10 PM Ni 1.54 16.68605 ug/L

**~** 217.07 57.77417 2.909432 -10.6254

**~**

l00912.SA11-2A 10/1/2010 12:25:25 PM Ni 124.32 1351.007 ug/L 1.94 1344.796 1379.709 1328.517

'" 1 00912.SAI2-2A 10/1/201 0 12:26:40 PM Ni 24.47 265.947 ug/L 12.26 228.7127 289.3765 279.7519

" 1 00912.SAI2-2AS 10/1/2010 12:28:10 PM Ni 874.01 9497.789 ug/L 0.76 9580.339 9445.021 9468.008

1

00912.SA13-2A 10/1/2010 12:34:34 PM Ni 32.49 353.0408 ug/L 8.90 385.715 350.336 323.0715
100912.SAI3-2AD

,. 10/1/2010 12:35:22 PM Ni 36.82 400.107 ug/L 1.71 406.1725 392.7089 401.4397

c

1 00912.SAO 1-2A 1 0/l/20 10 12:37:04 PM Ni 114.49 1244.109 ug/L 0.33 1246.522 1239.388 1246.417

Glm

c, CCV 10/1/2010 12:38:57 PM Ni 1035.83 11256.32 ug/L 1.70 1 1438.02 11056.46 11274.48

**~~**

CCB 1 0/l/201 0 12:40:28 PM Ni 1.79 19.45292 ug/L 138.59 17.53324 47.32056 -6.49503

en""

m'>m 1 00912.SA02-2A 1 0/1/2010 12:41:34 PM Ni 12.86 139.7204 ug/L 7.39 129.1435 149.7791 140.2385

-oz.: --<-;- 1 00912.SA03-2A 10/1/2010 12:44:20 PM Ni 9.94 108.0349 ug/L 28.50 72.93783 120.643 130.5238 "'

men en

0

S:.:..S2

1 00912.411-2A 10/1/2010 12:45:50 PM Ni 9.36 101.7652 ug/L 17.60 82.36591 117.6777 105.2519 "

**~Qo~** ,. ,...

:::o.?J

_, 100912.412-2A 10/1/2010 12:46:57 PM Ni 15.79 171.6385 ug/L 5.65 182.8062 165.3557 166.7536 "'

"enm

"

o,.en 100912.413-2A 1 0/l/201 0 12:48:02 PM Ni 12.82 139.3656 ug/L 24.53 150.7223 166.4351 100.9393 (j

c;,-1 "'

(ii"O

100912.401-2A 10/1/2010 12:49:42 PM Ni 11.69 127.0799 ug/L 13.65 121.5341 146.5166 113.189 en

"'"

co **,~**

1 00912.402-2A 1 0/l/201 0 12:50:47 PM Ni 3.83 41.58458 ug/L 50.26 19.78833 61.45623 43.50919

-<m ,o

100912.403-2A 1 0/l/201 0 12:51 :58 PM Ni 8.24 89.55354 ug/L 16.51 84.66562 106.1636 77.83137

,...--< ,. 100912.51l-2A 10/1/2010 12:53:37 PM Ni 17.30 187.997 ug/L 12.99 164.2734 213.0727

z 186.645

--< "'

1 00912.512-2A 10/1/2010 12:54:50 PM Ni 7.02 76.29717 ug/L 14.18 77.04405 86.72481 65.12265

CCV 10/1/2010 12:56:26 PM Ni 1045.05 11356.52 ug/L 0.69 11359.57 11433.46 11276.53

CCB 10/1/2010 12:57:48 PM Ni 0.22 2.406904 ug/L 612.04 9.655177 12.10955 -14.544

1 00912.513-2A 10/1/2010 12:58:49 PM Ni 6.51 70.74254 ug/L 11.45 73.34055 77.22319 61.66389

,. 1 00912.501-2A 10/1/201 0 1:00:41 PM Ni 5.46 59.29589 ug/L 19.12 52.97378 52.53094 72.38297

, , m 100912.502-2A 10/1/2010 1:01:47 PM Ni 4.76 51.71881 ug/L 19.49 57.97878 57.08729 40.09035

z CJ

100912.503-2A 10/1/2010 1:03:20 PM Ni 7.57 82.28038 ug/L 23.54 96.97914 60.33269 89.52931

x , CCV 10/1/2010 1:05:04 PM Ni 1067.11 11596.25 ug/L 1.06 11652.63 11681.39 11454.73

,. Gl CCB 10/1/2010 1:06:52 PM Ni 0.85 9.216456 ug/L 216.95 25.97854 -12.9148 14.58562

m z Calib Blank 1

0 10/5/2010 12:36:02 PM Ni 67.2 ug/L 6.80571 69.5328 61.91013 70.09545

"' Standard 1

t 10/5/2010 12:37:15 PM Ni 10841.9 ug/L 0.78458 10749.29 10859.75 10916.57

Page 84 of 1 03,. Sample ID Date Time Elem Cone (Cali lint (Corr) Calib RSD (Cor lnt (Corr)l lnt (Corr)21nt (Corr)3

-1 0 .,

Standard 2 10/5/2010 12:38:10 PM Ni 22365.8 ug/l 1.67618 22375.74 21985.98 22735.57

:0 ICY 1 0/5/201 0 12:39:45 PM Ni 971.8 10800.8 ug/l 2.10886 10560.42 10828.62 11013.41

0 '- ICB 10/5/2010 12:41:06 PM Ni

m 1.4 15.2 ug/L 77.2807 1.682398 20.98603 22.92794

0 -1

ICS 10/5/2010 12:42:15 PM Ni -0.7 -8.1 ug/l 270.463 -31.4295 11.98529 -4.8363

z 0

100912.511-1 10/5/2010 12:43:31 PM Ni 122.5 ug/l 21.2411

**~** 11.0 98.84044 150.3608 118.2693

"'

CCV 10/5/2010 12:46:40 PM Ni 961.0 1 0681 .4 ug/l 1.99628 10436.72 10827.36 10780.21

.. CCB 10/5/2010 12:48:13 PM Ni 1.6 18.3 ug/l 88.9252 2.270081 17.82714 34.81134

"' Calib Blank 1 10/1/2010 10:12:10 AM Zn 222.259 ug/L 6.27 215.561 238.2784 212.9375

Standard 1 10/1/2010 10:14:11 AM Zn 10909.56 ug/L 1.93 10821.63 10757.3 11149.75

Standard 2 10/1/2010 10:15:06AM Zn 21748.74 ug/l 0.46 21769.85 21639.43 21836.95

,. c

ICY 10/1/2010 10:16:08 AM Zn 1019.00 11088.18 ug/l 3.06 10725.53 11397.3 11141.72

Glm c.,

ICB 10/1/2010 10:17:32 AM Zn 1.29 14.09041 ug/l 11.67 13.05439 15.98565 13.23119

**~,.** l>(i ICS 10/1/2010 10:19:09 AM Zn 4.16 45.22595 ug/L 16.31 36.88456 47.91399 50.8793

(}).,, m<;;m 100912.LB 10/1/2010 10:20:40 AM Zn 1.21 13. 161 05 ug/L 14.08 13.40253 14.88201 11.19861

'UzS: "'

_,_,_ 100912.lCS 10/1/2010 10:21:45 AM Zn 878.45 9558.7 47 ug/l 0.88 9513.269 9655.356 9507.615

m(})(})

0

s:;:AQ?

100912.8-1 1 0/1/2010 10:24:19 AM Zn 23.18 252.2405 ug/l 3.85 244.3223 263.0869 249.3122 :0

**~Qo~**

,. ....

;;u

5'1 -1 100912.SAI1-1 10/1/2010 10:26:04AM Zn 242.31 2636.703 ug/l 1.59 2589.315 2651.603 2669.191 "'

"'(})m :0

o,.(})

100912.SA12-1 10/1/2010 10:30:38 AM Zn 240.66 2618.701 ug/L 3.04 2527.197 2657.17 2671.738 (i

Or-_,

"

(})'U 1.67

11976.79 12320.41 (})

"''" 100912.SA12-1S 10/1/2010 10:32:37 AM Zn 1122.28 12212.02 ug/L 12338.87

co :0'-

1 00912.SA13-1 10/1/2010 10:34:51 AM Zn 219.29 2386.19 ug/L 2.80 2309.177 2420.322 2429.072

-<m (l

1 00912.SA13-1 D 10/1/2010 10:35:38 AM Zn 223.02 2426.728 ug/l 0.52 2420.683 2418.344 2441.156

z 100912.SA01-1 10/1/2010 10:37:49 AM Zn 29.78 324.0067 ug/L 0.38 324.2322 325.1064 322.6816

-1 '"

1 00912.SA02-1 10/1/2010 10:39:01 AM Zn 29.91 325.4985 ug/L 1.53 326.2018 320.2163 330.0773

CCV 10/1/2010 10:41:09 AM Zn 1026.60 11170.88 ug/L 1.65 10961.8 11310.2 11240.64

CCB 10/1/2010 10:42:26 AM Zn -0.60 -6.57038 ug/l 29.94 -7.51514 -4.3089 -7.88712

100912.SA03-1 10/1/2010 10:43:35 AM Zn 43.1 0 468.9953 ug/l 1.59 464.8466 464.5327 477.6067

,. 100912.411-1 10/1/2010 10:45:18 AM Zn 26.08 283.8327 ug/L 5.27 271.6744 279.2969 300.5266

., ., m 100912.412-1 10/1/2010 10:46:45 AM Zn 23.77 258.6666 ug/l 3.37 253.2597 268.7137 254.0263

z 0

100912.413-1 10/1/2010 10:49:44 AM Zn 23.32 253.8062 ug/l 1.71 255.8357 256.7525 248.8303

x ., 100912.401-1 10/1/2010 10:51:26 AM Zn 28.50 310.1117 ug/l 1.10 312.5237 306.196 311.6153

,. Gl 100912.402-1 10/1/2010 10:52:52 AM Zn 25.07 272.8099 ug/L 2.66 267.0368 270.4304 280.9625

m z 0 100912.403-1 10/1/2010 10:54:07 AM Zn 24.51 266.6679 ug/l 4.18 279.4161 258.8098 261.7777

'" **~**

100912.512-1 10/1/2010 10:55:37 AM Zn 41.29 449.299 ug/l 2.28 438.6881 459.1241 450.0848

Page 85 of 1 03---

,. Sample ID Date Time Elem Cone (Calillnt (Corr) Calib RSD (Cor lnt (Corr)1 lnt (Corr)21nt (Corr)3

-< 0

100912.513-1 10/1/2010

" 10:57:08 AM Zn 41.56 452 .1948 ug/L 0.49 453.2199 453.7016 449.6629

"' CCV 10/1/2010 10:58:42 AM Zn 1054.35 11472.82 ug/L 0.74 11374.48 11527.52 11516.47

0 **~** rn CCB 10/1/2010 11:00:09 AM Zn -1.13 -12.296 ug/L 60.72 -14.9779 -18.0504 -3.85963

0 -<

100912.501-1 10/1/2010 11:01:16AM Zn 39.50 429.8616 ug/L 2.50 421.0553 426.7026 441.8269

z 0 **~** 100912.502-1 10/1/2010 11:02:25 AM Zn 27.93 303.9576 ug/L 4.45 318.0971 291.1539 302.6216

'" 100912.503-1 10/1/2010 11:03:37 AM Zn 23.95 260.5848 ug/L 4.69 246.6914 269.6616 265.4015

.. CCV 10/1/2010 11:05:04 AM Zn 1046.83 11390.96 ug/L 1.50 11211.54 11552.55 11408.78

N CCB 10/1/2010 11:06:35 AM Zn -1.49 -16.1793 ug/L 24.24 -16.5522 -19.902 -12.0837

Calib Blank 1 10/1!2010 12:17:26 PM Zn 200.7729 ug/L 2.75 206.8627 196.1046 199.3514

,. Standard 1 10/1/2010 12:18:25 PM Zn 11961.37 ug/L 3.06 11584.32 11985.67 12314.11

c Standard 2 10/1/2010 12:19:17PM Zn 24359.99 ug/L 2.05 23926.03 24247.02 24906.92

Glrn c.,

ICY 10/1/2010 12:20:21 PM Zn 1009.94 12256.89 ug/L 0.97 12122.18 12301.95 12346.54

**~,.** "'" IC8 10/1/2010 12:21:44 PM Zn -0.13 -1.57325 ug/L 573.42 2.044121 5.077936 -11.8418

(})""' rn<;rn ICS 10/1/2010 12:22:48 PM Zn 4.87 59.10245 ug/L 15.04 50.51737 58.52741 68.26256

" z s: -<.,- 1 00912.8-2A 10/1/2010 12:24:10 PM Zn 2.72 32.97821 ug/L 10.16 30.73273 31.3706 36.83128 OJ

rn(})(})

0

**s::~~**

1 00912.SAJ1-2A 10/1/2010 12:25:25 PM Zn 84.13 1021.043 ug/L 0.42 1021.536 1025.032 1016.561 "'

**~go~**

,. r

::0.01..., 1 00912.SAJ2-2A x2 10/1/2010 12:26:40 PM Zn 15.99 194.0335 ug/L 2.63 199.6997 192.6296 189.7711 OJ

N(})rn

"'

o,_(})

100912.SA12-2AS x2 10/1/2010 12:32:26 PM Zn 930.52 11293 ug/L 0.63 11215.35 11355.5 11308.14 0

c;r--1

"'

(ii"!J

1 00912.SAJ3-2A 10/1/2010 12:34:34 PM Zn 18.22 221.1248 ug/L 7.17 204.6397 222.4919 236.243 (})

OJJl co **,~** 1 00912.SAI3-2AD 10/1/2010 12:35:22 PM Zn 19.46 236.1457 ug/L 8.27 242.5321 214.2132 251.6918

..:rn (:J

1 00912.SA01-2A 10/1/2010 12:37:04 PM Zn 13.80 167.4663 ug/L 5.00 167.0835 159.2919 176.0235

z CCV 10/1/2010 12:38:57 PM Zn 1027.36 12468.29 ug/L 0.80 12441.63 12384.04 12579.21

-< "'

CCB 10/1/2010 12:40:28 PM Zn -0.15 -1.81118 ug/L 185.19 2.038204 -3.36637 -4.10539
100912.SA02-2A 10/1!2010 12:41:34 PM Zn 22.05 267.6318 ug/l 4.48 255.0851 278.9569 268.8535
100912.SA03-2A 10/1/2010 12:44:20 PM Zn 18.27 221.7448 ug/l 7.05 235.9173 224.3526 204.9646

1 00912.411-2A 10/1/2010 12:45:50 PM Zn 23.34 283.2846 ug/l 2.47 284.3981 289.6515 275.8041

,. 1 00912.412-2A 10/1/2010 12:46:57 PM Zn 38.81 471.0484 ug/L 5.84 443.0748 498.0888 471.9815

"

"

rn 100912.413-2A 10/1/2010 12:48:02 PM Zn 29.51 358.1905 ug/L 3.96 374.5186 348.8248 351 .2279

z 0

100912.401-2A 10/1/201 0 12:49:42 PM Zn 38.99 473.1439 ug/l 4.22 453.7322 472.0394 493.6601

x " 1 00912.402-2A 10/1/2010 12:50:47 PM Zn 15.10 183.2318 ug/l 4.69 173.3014 188.3188 188.0751

,. Gl rn

100912.403-2A 10/1/2010 12:51:58PM Zn 48.34 586.7194 ug/L 2.24 573.8355 600.0827 586.2401

z ? "'

1 00912.511-2A 10/1/2010 12:53:37 PM Zn 23.59 286_3339 ug/L 2.40 278.3978 290.4695 290.1343

"' 1 00912.512-2A 10/1/2010 12:54:50 PM Zn 16.76 203.4215 ug/l 9.38 181.5919 211.7025 216.9702

Poga 86 of 1 03)> -< 0 -u "' 0 **~** m 0 -< z 0 **~** 0 .. "' )> c Glm C-u **~)>** l>(j CJJ""' m<;;m -uz;:: -<.,-

m())CJJ **s::.t>.~** ffisto 0 "'"'z
- -< "'CJJm **~l>cn** or-< o;-u "'"'

co **,~** -<m -uo s;"" **~** "' )> -u -u m z 0 x -u 1) m z 0 "1 ... Sample ID CCV CCB 1 00912.513-2A 100912.501-2A 100912.502-2A

1 00912.503-2A CCV CCB Date Time Elem 10/1/2010 12:56:26 PM Zn 10/1/2010 12:57:48 PM Zn 10/1/2010 12:58:49 PM Zn 10/1/2010 1:00:41 PM Zn 10/1/2010 1:01:47 PM Zn 10/1/2010 1:03:20 PM Zn 10/1/2010 1:05:04 PM Zn 10/1/2010 1:06:52 PM Zn -- Cone (Calil int (Corr) Calib RSD (Cor lnt (Corr)1 lnt (Corr)21nt (Corr)3

1020.06 12379.71 ug/L 1.58 12153.23 12489.41 12496.48

0.42 5.144108 ug/L 329.76 22.76797 -11.0701 3.734428

21.42 259.9716 ug/L 7.28 246.7618 251.5023 281.6508

34.99 424.61 8 ug/L 2.77 415.4229 437.8766 420.5545

42.18 511.9021 ug/L 1.4 7 504.8061 511.1256 519.7746

44.20 536.3717 ug/L 4.47 508.8126 552.4325 547.8698

I 038.23 12600.29 ug/L 0.87 12486.02 12705.54 12609.3

-0.48 -5.857 49 ug/L 39.87 -6.72519 -3.21269 -7.63458

Page 87 of 1 03 "'

0 5:: r "' "'

0 **~**)> c )> **~** -u ;u 0 **~** m '.:l z 0 **~** =: .. N Gl em rn"

-;l>l>(i rn""'

m<;;m -uz;:: -<-;- mrnUl **~~~ m20~**  :::0 **~01** -1 "rnm S.J:>cn or-< u;-u "'"' co **.,~** -<m -uo s;"" z -; "' )> -u -u m z 0 x -u )> Gl m z 0 **~** 0> Sample ID Calib Blank 1 Standard 1 Standard 2 ICY iCB ICS 100912.L8

1 00912.LCS 10912.8-1

1 00912.SAI1-1 l00912.SA12-1 l00912.SA13-1 100912.SA01-1 l00912.SA02-1

1 00912.SA03-1 100912.411-1 CCV CCB 100912.411-1 s 100912.412-1 100912.412-1 D 100912.413-1 100912.401-1 100912.402-1 100912.403-1 100912.511-1 100912.512-1 100912.513-1 CCV CCB 100912.501-1 100912.502-1 100912.503-1 Date Time Elem Cone (Calillnt (Carr) Calib I RSD (Carr In! (Carr)11nt (Corr)21nt (Carr)3

10/6/2010 9:38:49 AM Mg 27.09564 ug/l 224.97 43.9424 -40.5131 77.85762

10/6/2010 9:39:44 AM Mg 155484.6 ug/l 1.92 152521.3 155446.9 158485.5

10/6/2010 9:40:33 AM Mg 314909.7 ug/L 0.15 315323.6 315025.5 314380.1

10/6/2010 9:41:57AM Mg 10/6/2010 9:43:26 AM Mg 10/6/2010 9:44:27 AM Mg 10/6/2010 10:09:58 AM Mg 10/6/2010 10:10:55 AM Mg 10/6/2010 10:13:21 AM Mg 10/6/2010 10:14:43 AM Mg 10/6/2010 10:15:41 AM Mg 10/6/2010 10:16:36AM Mg 10/6/2010 10:18:08AM Mg 10/6/2010 10:19:02 AM Mg 10/6/2010 10:19:52 AM Mg 10/6/2010 10/6/2010 10/6/2010 10/6/2010 10/6/2010 10/6/2010 10/6/2010 10/6/201 0 10/6/2010 10:20:48 AM Mg 10:22:21 AM Mg 10:23:38AM Mg 10:27:03AM Mg 10:29:05 AM Mg 10:29:57 AM Mg 10:30:48 AM Mg

1 0:32:11 AM Mg 10:33:04 AM Mg 10/6/2010 10:33:59 AM Mg 10/6/2010 10:35:16AM Mg 10/6/2010 10:36:05 AM Mg 10/6/2010 10:36:54 AM Mg 10/6/2010 10:38:21 AM Mg 10/6/2010 10:39:43 AM Mg 10/6/2010 10:40:31 AM Mg 10/6/2010 10:41:21 AM Mg 10/6/2010 10:42:11 AM Mg 985.70 -0.09 -11.54 -1.27 870.20 128.80 367.50 458.36 507.68 114.66 115.71 11,9.53
1 S:p.03 944.71 -0.11 1029.59 157.22 156.85 141.49 188.54 185.54 154814.8 ug/L -13.942 ug/L -1811.8 ug/L

-1 98.88 ug/L 136673.6 ug/L 20229.56 ug/L 57719.44 ug/L 71990.69 ug/L 79736.58 ug/L 18008.03 ug/L 18173.36 ug/L 18773.97 ug/L 2921 7.44 ug/L 148376.1 ug/L -16.784 ug/L 161708.4 ug/L 24692.79 ug/L 24634.96 ug/L 22223.13 ug/L 29613.03 ug/L 29141.72 ug/l 191.20 30030.49 ug/L 305.19 47932.94 ug/L 303.53 47 673.44 ug/L 229.12 35985.78 ug/L 965.16 151588 ug/L -0.27 -42.8323 ug/L 216.24 33963.36 ug/L 209.93 32972.22 ug/L 243.62 38263.47 ug/L Poge 88 of 103 2.21 152973.1 152707.9 158763.3 513.53 48.42554 -92.1227 1.871057

4.75 -1903.79 -1733.29 -1798.32
12.79 -224.717 -198.047 -173.875

1.52 134689.3 136498.2 138833.2

0.90 20062.23 20203.96 20422.51

0.46 57538.95 58021.88 57597.48

0.67 72032.62 72451.18 71488.26

2.06 77844.62 80828.53 80536.58

2.23 17810.74 17743.64 18469.7

0.85 18191.32 18010.46 18318.31

0.38 18706.35 18847.9 18767.67

1.67 29202.13 28738.6 29711.58

2.62 145443.7 146893.7 152790.9 386.10 -67.4253 -39.1717 56.24502

1.86 158424.2 162395.3 164305.9

0.77 24756.12 24479.98 24842.28

1.32 24378.02 24527.24 24999.63

1.27 21998.58 22130.37 22540.45

1.21 29401.9 29411.42 30025.76

1.26 28732.42 29253.62 29439.12

1.64 29750.38 297 41.85 30599.25

1.08 47819.68 47480.77 48498.36

0.82 47229.05 47831.08 47960.19

1.77 35443.85 35828.35 36685.16

2.19 147946.2 154443.9 152374 146.23 18.49887 -106.689 -40,3067

0.71 33704.73 34001.8 34183.55

0.92 32757.57 33321.2 32837.9

2.55 37455.24 37990.39 39344.78 "'

0 ;g r "' ;u 0 " (f),. Sample 10 Date Time Elem Cone (Calillnt (Corr) Calib I RSO (Corr lnt (Corr)l lnt (Corr)21nt (Corr)3

-; (") "1l

100912.B-2A 10/6/2010 10:44:35 AM Mg 16.60 2607.382 ug/L 0.42 2598.208 2604.276 2619.66

" 100912.SAI1-2A 10/6/2010 10:45:28AM Mg 915.14 143732.2 ug/L 1.13 142776.6 145613.5 142806.6

0 '- 1 00912.SAI2-2A 10/6/2010 10:46:22 AM Mg 286.52 45000.35 ug/L

m 1.06

44551.54 4494 7.1 8 45502.33

(") -;

1 00912.SA13-2A 10/6/2010 10:47:14 AM Mg 896.73 140840.6 ug/L 2.08 137532.8 141897.8 143091.1

z 0 1

00912.SA01-2A 10/6/2010 10:48:35 AM Mg 32.26 5066.006 ug/L 2.34 4997.54 4997.633 5202.845

:!: ':l

1 00912.SA02-2A 10/6/2010 1 0:49:27 AM Mg 47.26 7422.358 ug/L 1.87 7263.246 7518.764 7485.063

... 1 00912.SA03-2A 10/6/2010 10:50:16 AM Mg 44.09 6925.299 ug/L 0.77 6964.999 6864.626 6946.271

"' CCV 10/6/2010 10:52:00 AM Mg 999.56 156991.6 ug/L 1.14 155070.4 157291.7 158612.6

CCB 10/6/2010 10:53:46 AM Mg 0.02 3.427273 ug/L 1812.00 -60.4336 7.108759 63.6067

100912.411-2Ax2 10/6/2010 11 :06:02AM Mg

,. 7 42.80 116665.3 ug/L 1.57 114697.6 11697 4.1 118324.1

c 1 00912.411-2AS X 2 10/6/2010 11:07:20 AM Mg 1683.59 264426.3 ug/L 1.41 261064 263783.7 268431.2

G)m

c"ll 100912 .412-2A 10/6/2010 11 :09:42AM Mg 1714.1 7 269229.3 ug/L 1 .51 265695.9 268328.3 273663.6

**~,.** "'o 100912.412-2AD 10/6/2010 11:10:36 AM Mg 1744.63 274013.1 ug/L 1.53 269497.9 27 4791.2 277750.1

cn"ll" ms;m

100912.413-2A 10/6/2010 11:11:27 AM Mg 882.83 138657.7 ug/L 0.68 138039.4 138196.1 139737.6

"llzS: 1.86 13358.54 13647.23 13863.25 "'

-<-;- 100912.401-2A 10/6/2010 1l:l2:54AM Mg 86.74 13623.01 ug/L

0

men"' **3:~~** "

1 00912.402-2A 10/6/2010 11:13:42 AM Mg 78.81 12377.54 ug/L 1.69 12203.63 12609.97 12319.02 ,.

**~Qo~** r

::tl }'I -1 1 00912.403-2A 10/6/2010 11:14:44 AM Mg 141.69 22254.22 ug/L 3.11 21548.66 22283.05 22930.96 "'

"

"'cnm 0

o,.cn CCV ]0/6/2010 11:16:17 AM Mg 1021.98 160513 ug/L 0.82 159170.4 160565.6 161803

;:;,-1 "'

(ii"ll en

"'" CCB 10/6/2010 11:17:45AM Mg -0.23 -36.8015 ug/L 203.78 -74.2219 -85.7203 49.5377

co "'"

100912.511-2A 10/6/2010 11 :18:37 AM Mg 2035.42 319684.3 ug/L 3.50 306818 325116.4 327118.4

-<m (1

100912.512-2A 10/6/2010 11:19:33AM Mg 789.63 124019.4 ug/L 0.43 123424.2 124442.5 124191.6

z 100912.513-2A 10/6/2010 11 :20:28 AM Mg 815.65 128107.3 ug/L 1.43 126190.1 128293.2 129838.7

-; a>

100912.501-2A 10/6/2010 11:21:48 AM Mg 71.83 11282.22 ug/L 3.51 10869.39 11317.59 11659.67
100912.502-2A

10/6/2010 11 :22:37 AM Mg 1100.37 172825.7 ug/L 1.48 170967.8 171769.4 175739.9

1 00912.503-2A 10/6/2010 11 :23:36 AM Mg 584.39 91785.13 ug/L 1.45 92473.85 90248.75 92632.79

CCV 10/6/2010 11:24:59 AM Mg 1015.75 159535 ug/L 0.23 159167.7 159549.6 159887.5

,. CCB 10/6/2010 11:26:10AM Mg -0.11 -16.6533 ug/L 358.16 43.67224 -75.5934 -18.0388

"1l "1l m z 0 x "1l ,. G) m z ? **~** <0 Page 89 of T 03**~**

)> --< 0 Sample_ID EL Sam_Date Sam_Time Mean_Sig Mean_ST RSD Cal_ Units Dilu Rec Std_U 1 Std_U 2

"

" Calib Blank Pb 9/28/2010 9:20:19 -0.004 62.6 J.lg/L

0 **~** 20

ppb Pb 9/2B/201 0 9:27:50

m 0.027 4.4 J.lg/L

0 --<

50 ppb Pb 9/28/2010 9:35:28 0.053 1 .1 /19/L

z **~**

100 ppb Pb 9/28/2010 9:43:08 0.100 3.7 /19/L

**~**

200 ppb Pb 9/28/2010 9:50:48 0.1B5 1.5 J.lg/L

0 **~**

ICY Pb 9/28/2010 10:09:17 0.099 98.7 0.7 /19/L 98.196 99.174

... N ICB

Pb 9/28/2010 10:16:38 0.003 2.1 17.4 /19/L 1.842 2.361

1 00912.LB Pb 9/2B/201 0 10:24:06 0.002 1.2 90.7 J.IQ/L 1 0.430 1.968

1 00912.LCS Pb 9/28/2010 10:31:35 0.104 104.4 3.6 J,lg/L 1 107.075 101.744

)>

100912.B-1 Pb 9/28/2010 10:39:02 0.004 2.2 14.0 J,lg/L 1 2.012 2.453

c 1 00912.SA11-1 Pb 9/28/2010 10:46:27 O.OB9 B6.6 3.7 J,lg/L 1 84.299 88.878

"'m

C-u 100912.SAI1-1 Pb 9/2B/2010 10:54:07 0.166 177.5 1.1 J.lg/L 1 90.9 176.102 178.956

**~)>** "o 100912.SAI2-1 Pb 9/28/2010 11 :01:30 O.OB2 79.5 3.3 J.IQ/L 1 77.5B3 81.339

w"" 1 00912.SA13- 1 Pb 9/28/2010 11 :08:50 0.075 71.1 4.9 J,lg/L 1 68.612 73.530

mt;;m

"UzS: 100912.SA01-1 Pb 9/28/2010 11 :16:08 0.004 2.2 90.4 J.lg/L 1 0.795 3.608

'"

--<-;- mwW

100912.SA02-1 Pb 9/2B/201 0 11:23:24 0.003 1.7 13.1 J.IQ/L 1 1.577 1.900 0

S,:A!:a **~**

**~~g** 1 00912.SA03-1 Pb 9/28/2010 11 :30:44 0.004 2.6 49.6 J.IQ/L 1 1.690 3.516 r

;::o_r.n....,

CCV Pb 9/2B/201 0 11 :3B:20 0.100 99.5 3.1 J.IQ/L 1 97.313 101.676 '"

Nwm "

0)>()) CCB

Pb 9/28/2010 11 :45:43 0.001 0.9 45.4 J-19/L 1 1.143 0.588 0

c_;,--1 ;>;

(ii-u

100912.411-1 Pb 9/2B/201 0 11 :53:04 0.003 l.B 104.8 1-19/L 3.203 0.476 ())

'"" 1

co **,~**

100912.412-1 Pb 9/2B/201 0 12:00:29 0.002 1.4 118.9 J-19/L 1 0.226 2.618

-<m "0

100912.413-1 Pb 9/28/2010 12:07:56 0.003 2.1 4.9 /lQ/L 1 2.127 1.985

t;;-< 100912.401-1

Pb 9/2B/201 0 12:15:25 0.006 4.0 58.9 J.IQ/L 1 2.307 5.596

z --<

100912.402-1 Pb 9/2B/201 0 12:22:58 0.005 3.0 67.0 1-19/L 1 1.5BB 4.446

"'

100912.403-1 Pb 9/28/2010 12:30:32 0.005 3.0 1.0 J-19/L 1 3.064 3.021

100912.512-1

Pb 9!2B/201 0 12:3B:11 0.010 6.3 18.4 J.IQ/L 1 5.480 7.119

100912.513-1

Pb 9/2B/201 0 12:45:52 0.008 5.5 1B.B J.lg/L 1 4.787 6.252

100912.501-1

Pb 9/28/2010 12:53:26 0.007 4.3 34.1 1-19/L 1 5.302 3.243

)>

CCV Pb 9/28/2010 13:01 :05 0.102 102.2 0.4 /19/L 1 102.540 101.933

"

"

m CCB Pb 9/2B/201 0 13:08:29 0.003 1.7 56.5 J-19/L 1 2.362 1.013

z 0

100912.502-1 Pb 9/2B/201 0 13:15:56 0.002 1.3 4B.7 J-19/L 1 1.765 O.B61

x "

100912.503-1 Pb 9/28/2010 13:23:26 0.005 2.9 69.8 J-19/L 1 4.257 1.444

)> G)

CCV Pb 9/28/2010 13:31 :04 0.102 101.5 0.4 1-19/L 1 101.237 101.821

m z

CCB Pb 9!28/201 0 13:38:28 0.003 2.1 19.5 jlg/L 1 1.796 2.370

**~** "'

Calib Blank Pb 9/29/2010 8:11:07 -0.001 65.9 J.IQ/L

N 0 Page 90 of 103)> _, 0 Sample_ID EL Sam_Date Sam_ Time Mean_Sig Mean_ST RSD Cai_Unlts Dilu Rec Std_U 1 Std_U 2

"

;o 20 ppb Pb 9/29/2010 8:18:39 0.020 2.1 !19/L

0 **~** m 50 ppb Pb 9/29/2010 8:26:18 0.051 3.2 !19/L

0 _,

100 ppb Pb 9/29/2010 8:33:59 0.098 1.3 !19/L

z 0

200 ppb Pb 9/29/2010 8:41:36 0.178 1.9 pg/L

"

ICY Pb 9/29/2010 8:51 :15 0.099 103.0 2.0 pg/L 101.589 104.445

0 t

ICB Pb 9/29/2010 8:58:38 0.006 5.9 118.0 !19/L 10.881 0.980

**~** 100912.B-2A Pb 9/29/2010 9:06:06 0.002 1.7 5.8 !19/L 1 1.818 1.675

100912.SAI1-2A Pb 9/29/2010 9:13:36 0.018 17.3 9.1 !19/L 1 18.376 16.164

100912.SAI1-2A Pb 9/29/2010 9:21:15 0.107 111.8 0.2 !19/L 1 94.5 111.920 111.659

)>

100912.SA12-2A Pb 9/29/2010 9:28:45 0.005 5.3 19.2 !19/L 1 4.567 5.998

c 100912.SAO 1-2A Pb 9/29/2010 9:46:41 0.004 3.5 9.6 !19/L 1 3.290 3.768

Glm

c., 100912.SA02-2A Pb 9/29/2010 9:54:01 0.001 0.7 407.4 !19/L 1 2.549 -1.236

**~)>** l>(\ 1 00912.SA03-2A Pb 9/29/2010 10:01:19 0.002 2.3 22.3 !19/L 1 1.915 2.633

rn"'" 1 00912.411 -2A Pb 9/29/2010 10:08:38 0.003 3.2 24.6 !19/L 1 3.814 2.682

m';m

-uz;;: 100912.412-2A Pb 9/29/2010 10:15:56 0.008 7.5 21.0 !19/L 1 6.421 8.657 OJ

_,_,_ mrnrn

CCV Pb 9/29/2010 10:23:32 0.092 95.4 4.0 !19/L 1 92.681 98.081 0

S:.:..Q2 ;o

**~""~** Pb )>

CC8 9/29/2010 10:30:56 0.000 -0.3 25.8 !19/L 1 -0.389 -0.269 .-

::O!Jt_,

OJ

**~rnm** 100912.413-2A Pb 9/29/2010 10:38:17 0.003 2.7 73.1 !19/L 1 1.287 4.042 ;o

o,.rn

n

Oc.-1 100912.401-2A Pb 9/29/2010 10:45:42 0.005 4.6 75.4 !19/L 1 2.133 7.009 ><

(f)"U

(f)

OJ;o 100912.402-2A Pb 9/29/2010 10:53:09 0.002 1.9 1.3 !19/L 1 1.851 1.885

co **;o~**

100912.403-2A Pb 9/29/2010 11 :00:38 0.006 5.9 23.1 !19/L 1 6.821 4.902

-<m (1

1 00912.511 -2A Pb 9/29/2010 11:08:12 0.010 9.4 27.4 !19/L 1 11.244 7.591

z

1 00912.512-2A Pb 9/29/2010 11:15:46 0.005 4.7 5.8 !19/L 1 4.498 4.884

_, 100912.513-2A Pb 9/29/2010 11:23:24 0.003 2.7 8.5 !19/L 1 2.524 2.847

"'

100912.501-2A Pb 9/29/2010 11 :31:05 0.006 6.3 38.0 !19/L 1 7.959 4.589

100912.502-2A Pb 9/29/2010 11 :38:46 0.004 3.7 43.3 !19/L 1 4.841 2.570

CCV Pb 9/29/2010 11:46:30 0.091 94.2 5.7 119/L 1 90.442 98.054

CCB Pb 9/29/2010 11:53:53 0.002 2.2 2.7 !19/L 1 2.179 2.263

)>

1 00912.503-2A Pb 9/29/2010 12:01:22 0.005 5.3 26.5 !19/L 1 6.279 4.299

"

"

m CCV Pb 9/29/2010 12:09:01 0.101 104.8 2.2 !19/L 1 106.432 103.201

z 0

CCB Pb 9/29/2010 12:16:26 0.001 0.9 278.0 !19/L 1 -0.855 2.625

x "

Calib Blank Pb 10/4/2010 8:59:08 0.003 185.5 !19/L

)>

Gl 20 ppb Pb 10/4/2010 9:06:43 0.014 0.2 !19/L

m z

50 ppb Pb 10/4/2010 9:14:22 0.046 3.4 !19/L

0 "'

100 ppb Pb 10/4/2010

**~** 9:22:01 0.076 1.2 !19/L f'Qge 91 of 103, -; 0 "0 ;o 0 **~** m 0 -; z p 'E 0 :;: "' , c Glm C-u **~,** "'o "'""' m>m -uzs: -l-;- m"'"' **s::.l>.~ ~120~**  ;o _0'1 -1 "'"'m o»"' c;,-t

--u **~;o** co **;o~** -<m **(~** z -; "' , "0 "0 m z 0 x "0 , Gl m z 0 "' "'

"' Sample_ID EL Sam_Date

200 ppb Pb 10/4/2010

ICY Pb 10/4/2010

ICB Pb 10/4/2010 100912.SA13-2A Pb 10/4/2010

CCV Pb 10/4/2010

CCB Pb 10/4/2010
Calib Blank Pb 10/6/2010

20 ppb Pb 1 0/6/2010

50 ppb Pb 10/6/2010

100 ppb Pb 10/6/2010

200 ppb Pb 10/6/2010

ICY Pb 10/6/2010

ICB Pb 10/6/2010

ICY Pb 10/6/2010

ICB Pb 10/6/2010 100912.511-1 Pb 10/6/2010

CCV Pb 10/6/2010

CCB Pb 1 0/6/201 0 "- Sam_ Time Mean_Sig Mean_ST RSD Cai_Units Dilu Rec Std_U 1 Std_U 2

9:29:39

0.152 4.5 J,Jg/L 9:44:45 0.074 93.5 3.5 J,Jg/L 1 95.822 91.222

9:52:06

-0.003 -4.3 13.6 /19/L 1 -3.687 -4.691

10:14:36

-0.003 -3.8 60.3 J.ig/L 1 -5.430 -2.184

11:14:00

0.088 112.1 4.1 J.ig/L 1 115.332 108.869

11:21:23

-0.004 -4.6 59.2 Jlg/L 1 -2.690 -6.569

8:13:33

0.000 534.1 Jlg/L 8:21:03 0.015 15.4 J.ig/L 8:28:42 0.041 2.7 Jlg/L 8:36:21 0.076 7.8 J.ig/L 8:43:58 0.156 6.4 J.ig/L 8:55:54 0.087 111.7352 3.8 J,Jg/L 1 114.728 108.743

8:59:37

-0.002 -1.90515 -1.9 J,Jg/L 1 -1.905 -1.905

9:07:37

0.084 107.3257 3.9 /19/L 1 110.281 104.371

9:14:59 -0.002 -2.32855 24.1 J.ig/L 1 -2.725 -1.932 ID

9:22:32

0.006 7.805673 0.9 J.ig/L 1 7.857 7.755 0 **~**

9:30:12 0.089 113.9833 0.4 J.ig/L 1 113.694 114.272 .- ID

9:37:36 -0.003 -3.37163 4.3 J,Jg/L 1 -3.475 -3.269 ;o 0 " "'

Page 92 of 1 03, -l () Sample ID Elem Date Time Abs (Carr) Cane (Calil RSD (Cone) Special Sa Special Ca Cone (Calib Cone (Calib

"1l :0

Calib Blank Sb 9/28/2010 8:41:11 AM -0.007 0

0

L 20

ppb Sb Sb 9/28/2010 8:47:22 AM 0.017 0

m () -l 50 ppb Sb Sb 9/28/2010 8:53:33 AM 0.036 0

z ?

100ppbSb Sb 9/28/2010 8:59:48 AM 0.060 0

:!: 200 ppb Sb Sb 9/28/2010 9:05:58AM 0.110 0

**~**

ICV Sb 9/28/2010 9:34:58 AM 0.060 95.0 6.4 99.246 90.704

.. "'

IC8 Sb 9/28/2010 9:41:11 AM 0.007 7.0 22.0 5.931 8.117

100912.L8 Sb 9/28/2010 9:47:21 AM 0.006 6.8 18.0 5.963 7.706

100912.LCS Sb 9/28/2010 9:53:33 AM 0.063 101.4 13.1 92.026 110.751

100912.8-1

Sb 9/28/2010 9:59:42 AM 0.002 1.6 91.7 0.575 2.700

, Sb

c 100912.SA11-1 9!28/201 0 10:05:53 AM 0.008 9.1 42.4 11.864 6.395

"m

100912.SAI1-1 Sb 9/28/2010 10:12:05 AM 0.061 97.2 4.2 1 97.2 94.285 100.104

c., **~,** 1 00912.SA12-1 Sb 9/28/2010 10:18:17 AM 0.007 7.8 29.2 9.404 6.186

>fi (/).,,

100912.SA13-1 Sb 9/28!201 0 10:24:27 AM 0.009 9.5 12.0 10.343 8.722

m<;m

"llzS: 1 00912.SA01-1 Sb 9/28!2010 10:30:35 AM 0.006 6.4 25.2 5.248 7.530 OJ

_,_,_ mrn<n

1 00912.SA02-1 Sb 9/28/2010 10:36:45 AM 0.009 9.3 38.1 11.845 6.820 0

**s:"""~ ~** 

**~Qo~** 100912.SA03-1 Sb 9/28!2010 10:42:53 AM 0.007 7.8 7.9 7.353 8.226 ,-

AJ.OI -i "'

CCV Sb 9/28/2010 10:49:04 AM O.Q61 98.1 2.7 99.998 96.269 :0

"'rnm (i

o,.rn Or- -I CC8 Sb 9/28/2010 10:55:14AM 0.008 8.9 19.8 7.611 10.094 "'

(i;"ll

(f)

OJ:O 100912.411-1 Sb 9/28/2010 11:01:23 AM 0.009 9.2 20.5 7.905 10.583

co 100912.412-1

Sb 9/28/2010 11:07:31 AM 0.004 4.6 181.0 -1.296 10.554

:OL -<m

(1

100912.413-1 Sb 9/28/201 0 11 :13:40 AM 0.008 8.6 53.2 5.340 11.788

z

100912.401-1 Sb 9/28/2010 11:19:51 AM 0.004 4.4 28.4 5.274 3.510

-l 100912.402-1 Sb 9/28/2010 11:26:01 AM 0.004 3.8 14.3 4.182 3.413

"'

100912.403-1 Sb 9/28/2010 11:32:11 AM 0.007 7.9 13.2 8.675 7.198

100912.512-1 Sb 9/28/2010 11:38:23 AM 0.003 3.3 89.3 1.215 5.382

100912.513-1

Sb 9/28/2010 11:44:34 AM 0.004 4.7 110.7 8.388 1.020

100912.501-1

Sb 9/28/2010 11:50:44 AM 0.006 6.4 15.6 5.699 7.117

, CCV Sb 9/28/2010 11:56:55 AM 0.057 89.8 4.1 87.131 92.397

"1l "1l CC8 Sb 9/28/2010 12:03:07 PM 0.009 9.8 3.6 10.040

m 9.543

z 0

100912.502-1 Sb 9/28/2010 12:09:18 PM 0.003 2.5 77.4 3.926 1.148

x "1l

100912.503-1 Sb 9/28!2010 12:15:28 PM 0.006 5.9 3.9 5.757 6.086

, CCV

Sb 9/28/2010 12:21:39 PM 0.061 97.6 3.6 95.113 100.132

Cl m z CCB Sb 9/28/2010 12:27:51 PM

0 0.006 6.2 13.5 6.782 5.597

"'

1 00912.8-2A Sb

"' 9/28/2010 1:20:39 PM 0.004 4.0 70.5 6.057 2.026

w Page 93 of 103**~·**

)> -< 0 Sample ID Elem Date Time Abs (Corr) Cone (Cali! RSD (Cone} Special Sa Special Ca Cone (Calib Cone (Calib

"1l "

100912.SAI1-2A Sb 9/28/2010 1:26:51 PM 0.008 8.8 19.8 9.999 7.543

0 L 100912.SAI2-2A Sb 9/28/2010 0.007 7.0

m 1:40:31 PM 26.8 1 8.328 5.678

0 -<

100912.SAI2-2A Sb 9/28/2010 1:46:42 PM 0.074 124.8 2.8 1 124.8 127.262 122.256

z ?

1 00912.SAI3-2A Sb 9/28/2010 1:52:53 PM 0.007 7.0 55.1 9.739 4.277

**~**

1 00912.SA01-2A Sb 9/28/2010 1:59:05 PM 0.008 8.7 14.1 7.831 9.567

0 1

00912.SA02-2A Sb 9/28/2010 2:05:13 PM 0.008 8.3 34.9 6.272

.. 10.386

"' 100912.SA03-2A Sb 9/28/2010 2:11:21 PM 0.005 4.7 1.1 4.780 4.709

100912.411-2A

Sb 9/28/2010 2:17:30 PM 0.006 5.8 0.6 5.789 5.839

100912.412-2A

Sb 9/28/2010 2:23:39 PM 0.007 7.4 32.1 9.114 5.743

)>

100912.413-2A Sb 9/28/2010 2:29:47 PM 0.005 5.0 38.2 6.347 3.650

c

100912.401-2A Sb 9/28/2010 2:35:55 PM 0.007 7.3 30.5 5.737 8.888

Glm c"

CCV Sb 9/28/2010 2:42:06 PM 0.069 113.6 2.4 115.500 111.694

**~)>** CCB

Sb 9/28/2010 2:48:18 PM 0.005 5.3 63.5 7.608 2.893

>c; en"" 100912.402-2A Sb 9/28/2010 2:54:34 PM 0.009 9.7 9.3 9.101 10.375

m);m

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(])

-<-;-

men en 100912.511-2A Sb 9/28/2010 3:07:02 PM 0.008 8.5 45.0 5.821 11.249 0

**s:~~**

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:;:o

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9/28/2010 0.009 9.7 9.879 9.424 (])

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o,.en

100912.501-2A Sb 9/28/2010 3:25:47 PM 0.005 4.9 5.5 4.749 5.134 0

Or- -I "'

'""

6.836 en

rn::O 1 00912.502-2A Sb 9/28/2010 3:32:01 PM 0.005 5.3 39.5 3.852

co Sb

9/28/2010 0.006 6.4 42.7 4.481 8.360

;oL 100912.503-2A 3:38:14 PM

-<m (l

CCV Sb 9/28/2010 3:44:25 PM 0.063 101.1 2.0 99.653 102.459

z

CC8 Sb 9/28/2010 3:50:38 PM 0.006 6.1 37.6 7.713 4.471

-<

Calib Blank Sb 10/8/2010 9:45:35 AM 0.000 0

"'

20 ppb Sb Sb 10/8/2010 9:51:44AM 0.014 0

50 ppb Sb Sb 10/8/2010 9:57:56 AM 0.034 0

100 ppb Sb Sb 10/8/2010 10:04:09 AM 0.069 0

200 ppb Sb Sb 10/8/2010 10:10:18AM 0.133 0

)> ICY Sb 10/8/2010 10:17:15 AM 0.068 99.7 1.2 98.793 100.508

"1l "1l 62.0 -0.355

m ICB Sb 10/8/2010 10:23:26 AM 0.000 -0.6 -0.910

z 0

100912.511-1 Sb 10/8/2010 10:29:39 AM 0.001 1.0 30.3 1.207 0.781

x "1l

CCV Sb 10/8/2010 10:35:52 AM 0.067 98.6 0.1 98.682 98.513

)>

Gl CCB Sb 10/8/2010 10:42:08 AM 0.000 -0.6 6.5 -0.667 -0.609

m z ? "' "'

.. Page 94 of 103, Sample ID Elem Date Time Abs (Corr) Cone (Cali! RSD (Cone) Special Sa Special Ca Cone (Cali! Cone (Cali!

""

0 -u Calib Blank Se 9/29/2010 9:02:41 AM ..().001 0

"' 20 ppb Se Se 9/29/2010 9:08:53 AM 0.018 0

0 **~** 50

ppb Se Se 9/29/2010 9:15:04 AM 0.045

m 0

0 ""

100 ppb Se Se 9/29/2010 9:21:16AM 0.090 0

z 0 200

ppb Se Se 9/29/2010 9:27:26 AM 0.176

:!: 0

"' ICY Se 9/29/2010 9:54:29 AM 0.081 92.0 5.95 88.1485 95.89163

...

IC8 Se 9/29/2010 10:00:41 AM 0.000 -0.2 359.77 -0.77757 0.338754

N 1 00912.LB Se 9/29/2010 10:06:51 AM 0.001 0.8 73.74 0.383726 1.219958

100912.LCS

Se 9/29/2010 10:13:04 AM 0.090 101.3 0.62 100.8177 101.7123

100912.8-1 Se 9/29/2010 10:19:13 AM

, -0.001 -0.8 96.21 -1.26961 -0.24157

c 1 00912.SAil-1 Se 9/29/2010 10:25:24 AM 0.011 12.8 6.57 12.21924 13.41062

Glm

C-u 1 00912.SA!2-1 Se 9/29/2010 10:31:36 AM 0.014 15.3 1.98 15.55169 15.1-2234

**~,** "'o 100912.SA13-1 Se 9/29/2010 10:38:55 AM 0.008 9.5 9.04 10.13284 8.914633

w""'

Se 9/29/2010 0.000 0.5 71.81 0. 794339 0.259308

m<;:m 100912.SAOl-1 10:45:03 AM

-oz<: CD

-<-<- 100912.SA02-1 Se 9/29/2010 10:51:12 AM -0.001 -1.2 95.51 -0.38368 -1.97984

mwW

0

**s::.j:>.~** "'

**~!<'>~** 1 00912.SA03-1 Se 9/29/2010 10:57:21 AM 0.000 0.5 46.78 0.311877 0.620175 , r

;u 51"' -1 CCV Se 9/29/2010 11:03:34 AM 0.089 100.8 0.77 100,2635 101.3596 CD

"wm

"'

o,w CC8 Se 9/29/2010 11:09:47 AM 0.001 0.7 65.35 0.36423 0.989962 0

c;r-1 "

(ii"O

(f)

co"' 100912.411-1 Se 9/29/2010 11:18:12AM 0.012 13.1 2.43 13.35906 12.90713

co **,~**

100912.411-1 Se 9/29/2010 11:24:26 AM 0.082 92.4 1.86 1 79.22839 93.5769 91.14607

..;m

0 0.005

5.632494 4.830547

""" 100912.412-1 Se 9/29/2010 11:30:35 AM 5.2 10.84

<;: z

100912.413-1 Se 9/29/2010 11:36:45 AM 0.003 3.2 42.91 2.238499 4.188289

""

"' 100912.401-1 Se 9/29/2010 11:42:56 AM 0.000 -0.4 251.60 -1.20708 0.338398

100912.402-1 Se 9/29/2010 11:49:07 AM 0.000 0.2 676.82 -0.57055 0.87196

100912.403-1 Se 9/29/2010 11:55:18 AM 0.000 0.2 26.77 0.13863 0.203364

100912.512-1 Se 9/29/2010 12:01:32 PM 0.039 44.3 4.78 42.76824 45.75871

,

100912.513-1 Se 9/29/2010 12:07:44 PM 0.066 74.9 2.40 76.181 73.6348

"0 -u m 100912.501-1 Se 9/29/2010 12:13:56 PM 0.002 2.0 1.48 2.018815 1.976969

z 0

CCV Se 9/29/2010 12:20:09 PM 0.090 101.7 0.46 102.0416 101.3741

x "0 CCB Se 9/29/2010 12:26:21 PM -0.001 -0.9 63.34 -0.50471 -1.32345

, Gl Se

9/29/2010 12:32:32 PM 0.002 2.7 16.63 3.041577 2.401599

m 100912.502-1

z **~** 100912.503-1 Se 9/29!2010

"' 12:38:43 PM 0.005 5.1 6.68 4.880158 5.364118

N

CCV Se 9/29/2010 12:44:55 PM 0.089 100.3 0.68 100.8037 99.83964

"' Page 95 of 103**~~**

, Sample ID Elem Date Time Abs (Corr) Cone (Cali! RSD (Cone) Special Sa Special Ca Cone (Cali! Cone (Calil

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CCB

"U Se 9/29/2010 12:51:07 PM -0.001 -0.7 105.03 -0.19272 -1.30527

;o 1 00912.B-2A Se 9/29/2010 1:00:12 PM 0.000 -0.2 345.63 -0.53413 0.223949

0 **~** 1

00912.SAI3-2A Se 9/29/2010 1:24:59 PM 0.006 7.3

rn 22.81 8.499398 6.138284

0 -;

1 00912.SAI2-2A Se 9/29/2010 1:50:06 PM

z 0.013 15.0 12.33 13.66431 16.27513

0 1

00912.SA02-2A Se 9/29/2010 2:38:46 PM 0.006 6.9

:!: 17.19 6.07505 7.755775

:1

1 00912.SA03-2A Se 9/29/2010 3:12:39 PM 0.001 1.7 116.49 0.294031 3.041275

....

100912.411-2A Se 9/29/2010 3:18:49 PM 0.009 9.8 3.83 9.555777 10.08766

"' 1 00912.412-2A Se 9/29/2010 3:24:57 PM 0.015 17.2 23.82 14.30543 20.10009

100912.413-2A Se 9/29/2010 3:31 :05 PM 0.009 10.0 19.44 8.648772 11 .4056

, 1 00912.401-2A Se 9/29/2010 3:37:13 PM 0.002 2.7 26.90 3.164478 2.153027

c 1 00912.402-2A Se 9/29/2010 3:43:23 PM -0.001 -1.4 542.30 3.943918 -6.72657

"'rn

c., 1 00912.403-2A Se 9/29/2010 3:49:38 PM -0.001 -1.1 58.12 -1.56373 -0.65275

**~,** >o 1 00912.511-2A Se 9/29/2010 3:55:52 PM 0.021 24.3 15.83 21.5655 27.0031

(/j"U;o

rn\:rn CCV Se 9/29/2010 4:02:03 PM 0.075 84.7 5.11 87.75167 81.62651

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rn(f)(/j

0

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Calib Blank Se 9/30/2010 8:42:30 AM -0.003 0.00

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0}>(/) 50 ppb Se Se 9/30/2010 8:54:55 AM 0.032 0.00 0

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(/)

"'"' 100 ppb Se Se 9/30/2010 9:01:07 AM 0.070 0.00

co **,~**

200 ppb Se Se 9/30/2010 9:07:18 AM 0.132 0.00

-<m .,o ICY Se 9/30/2010 9:22:37 AM 0.067 100.3 2.41 98.58279 101.9945

);-; z ICB Se 9/30/2010 9:28:50AM -0.001 -1.5 36.90 -1.89472 -1.1105

-; "'

100912.SAI1-2A Se 9/30/2010 9:35:01 AM 0.000 -0.2 536.08 -1.04447 0.608426

1 00912.SA11-2A Se 9/30/2010 9:41:11AM 0.062 93.2 5.26 1 93.23038 89.76403 96.69673
100912.SA01-2A Se 9/30/2010 9:47:20AM 0.009 13.2 2.09 13.38956 13.00009

1 00912.512-2A Se 9/30/2010 9:53:34AM 0.007 10.7 94.05 3.582075 17.80419

, 1 00912.513-2A Se 9/30/2010 9:59:49 AM 0.006 9.7 28.77 7.719804 11.66292

"U

"U rn

100912.501-2A Se 9/30/2010 10:06:06 AM 0.005 8.1 45.10 5.525387 10.70018

z 0

1 00912.502-2A Se 9/30/2010 10:12:20AM 0.007 11 . 1 80.91 4.758931 17.48607

x "U 1 00912.503-2A Se 9/30/2010 10:18:34 AM 0.006 8.7 13.22 9.547096 7.91473

, G) m CCV Se 9/30/2010

z 10:24:47 AM 0.066 99.5 6.61 94.82669 104.1221

**~** CCB Se 9/30/2010 10:31:00 AM

"' -0.004 -5.3 10.30 -5.71039 -4.93501

"'

Calib Blank Se 10/7/2010 2:56:46 PM 0.001 0.00

"' Page 96 of 103)> -< 0 "1l ;o 0 **~** rn 0 -< z 0 **~** '= ... "' )> c Gl ern (1)"1l _,, "o (/)-u;o rnS::rn -uz;;: .,_,_ rnC/lC/l **:S:A~ ~Qo~**  ::0 **~** -1 "-'C/lrn **~::t:>cn** or-< (1)"1l OJ;Q co **,~** -<'" .,n

s;:"" z -< '" )> "1l "1l m z 0 x "1l )> Gl m z 0 '" "'

.... Sample ID Elem Date

20 ppb Se Se 10/7/2010

50 ppb Se Se 10/7/2010

100 ppb Se Se 10/7/2010

200 ppb Se Se 10/7/2010

ICV Se 10/7/2010

ICB Se 10/7/2010 100912.511-1 Se 10/7/2010

CCV Se 10/7/2010

CCB Se 10/7/2010 Time 3:02:59 PM 3:09:13 PM 3:15:28 PM 3:21:40 PM 3:30:08 PM 3:36:21 PM 3:42:37 PM 3:48:51 PM 3:55:04 PM -· Abs (Corr) Cone (Calil RSD (Cone) Special Sa Special Ca Cone (Calil Cone (Cali!

0.018 0.00 0.035 0.00 0.075 0.00 0.137 0.00 0.071 93.6 4.42 90.66327 96.51269

0.002 2.0 230.13 -1.24923 5.232298

0.016 19.3 11.15 17.79822 20.84363

0.069 91.5 4.55 94.46072 88.57311

0.000 0.4 209.58 -0.21126 1.087894

Pcge 97 of 103 "'

0 **~** ,... "' ;o 0 ;>; (/)--

,. Sample ID Elem Date Time Abs (Corr Cone (Cali! RSD (Cone) Special Sa Special Ca Cone (Cali! Cone (Calil

-; (l .,

Cal"tb Blank Tl 10/6/2010 11:02:28AM 0.000 0

;o

10 ppb Tl Tl 10/6/2010 11:07:58 AM 0.008 0

0 **~** m 20 ppb Tl Tl 10/6/2010 11:13:23 AM 0.017 0

(l -;

50 ppb Tl Tl 10/6/2010 11:18:47 AM 0.042 0

z 0 100 ppb Tl 10/6/2010

**~** Tl 11:24:11 AM 0.082 0

'"

ICV Tl 10/6/2010 11:55:24 AM 0.047 56.11 1.34 55.58219 56.64552

,. ICV Tl 10/6/2010 12:01:25 PM 0.042 50.31 1.70 49.71013 50.91869

N ICB Tl 10/6/2010 12:06:52 PM 0.000 -0.34 53.66 -0.4739 -0.21318

1 00912.LB Tl 10/6/2010 12:12:16 PM 0.000 -0.05 78.82 -0.0844 -0.02399

,.

100912.LCS Tl 10/6/2010 12:17:41 PM 0.050 59.96 0.83 60.31766 59.61011

c 100912.8-1 Tl 10/6/2010 12:23:04 PM 0.000 -0.17 10.98 -0.17943 -0.15357

Glm

c., 100912.SAI1-1 Tl 10/6/2010 12:28:29 PM 0.004 4.67 6.64 4.45124 4.889619

**~,.** >o

100912.SA12-1 Tl 10/6/2010 12:33:55 PM 0.004 4.88 4.86 5.049773 4.71449

en""

m>;;m 100912.SAI3-1 Tl 10/6/2010 12:39:18 PM 0.004 4.49 1.11 4.524508 4.453983

"Uz;< "'

-<-;- 100912.SA01-1 Tl 10/6/2010 12:44:41 PM 0.000 -0.06 396.69 0.102031 -0.21508

men"' 0

**~""""~** 1 00912.SA02-1 Tl 10/6/2010 12:50:04 PM 0.000 -0.49 87.20 -0.1872 -0.78927 "

**~Qo~** ,. r

:::0 571

__, 100912.SA03-1 Tl 10/6/2010 12:55:27 PM 0.000 -0.03 1864.91 0.338295 -0.39381 "'

Ncnm "

o,.cn CCV Tl 10/6/2010 1:00:50 PM 0.044 52.70 2.25 51.86051 53.53815 0

**~r-1** "'

c;;., 10/6/2010

1:06:16 PM -0.42 44.13 "'

"'" CCB Tl 0.000 -0.28947 -0.55207

co **,~**

100912.411-1 Tl 10/6/2010 1:11:38 PM 0.000 -0.03 27.11 -0.04089 -0.02774

..;m **(~** 100912.411-1 Tl 10/6/2010 1:17:18 PM 0.042 51.10 0.32 1 102.1935 50.9807 51.21284

z 100912.412-1 Tl 10/6/2010 1:22:40 PM 0.000 0.10 25.52 0.114479 0.079475

-; "'

100912.413-1 Tl 10/6/2010 1:28:03 PM 0.000 0.02 522.39 -0.06284 0.1 09498

100912.401-1

Tl 10/6/2010 1:33:28 PM 0.000 -0.45 26.79 -0.53987 -0.36793

100912.402-1

Tl 10/6/2010 1:38:54 PM 0.000 -0.26 107.12 -0.46284 -0.06389

100912.403-1 Tl 10/6/2010 1:44:20 PM 0.000 -0.06 278.32 0.062427 -0.19141

,. 100912.511-1 Tl 10/6/2010 1:49:45 PM 0.001 0.74 4.85 0.718394 0.769398

., "

m 100912.512-1 Tl 1 0/6/2010 1:55:10 PM 0.000 0.42 37.94 0.308182 0.534139

z 0

100912.513-1 Tl 10/6/2010 2:00:35 PM 0.001 0.73 17.80 0.637492 0.821 OS

x ., CCV Tl 10/6/201 0 2:06:21 PM 0.043 51.72 1.24 51.26847 52.17733

,. G) m CCB Tl 10/6/2010 2:11:47 PM 0.000 -0.26 111.42 -0.45947 -0.05451

z 0

100912.501-1 Tl 10/6/2010 2:17:09 PM 0.000 -0.15 123.58 -0.27851 -0.01875

"' N

100912.502-1 Tl 10/6/2010 2:22:34 PM 0.000 -0.29 77.70 -0.44423 -0.12919

"" Page 98 of 1 03--

,. Sample ID Elem Date Time Abs (Corr Cone (Cali! RSO (Cone) Special Sa Special Ca Cone (Cali! Cone (Cali!

-1 0

100912.503-1 Tl 10/6/2010 2:27:59 PM 0.000 -0.34 5.32 -0.35075 -0.32534

, :0

CCV Tl 10/6/2010 2:33:24 PM 0.044 52.54 0.05 52.51747 52.55817

0 L

CCB Tl 10/6/2010 2:38:49 PM 0.000 -0.41 39.04

m -0.52902

-0.30015

0 -1

1 00912.6-2A Tl 10/6/2010 2:45:08 PM -0.001 -0.70 26.84 -0.83128 -0.56607

z 0 100912.SAI1-2A Tl 10/6/2010 2:50:33 PM 0.000 -0.58 38.04

l -0.74125 -0.42701

:1

1 00912.SAI2-2A Tl 10/6/2010 2:55:58 PM 0.000 -0.59 25.16 -0.69491 -0.48498

... 1 00912.SAI3-2A Tl 10/6/2010 3:01:25 PM 0.000 -0.38 105.23 -0.09726 -0.66282

" 100912.SA01-2A Tl 10/6/2010 3:06:50 PM 0.000 -0.29 17.42 -0.32482 -0.25359

100912.SA02-2A Tl 10/6/2010 3:12:13 PM 0.000 -0.07 639.80 -0.41266 0.263253

1 00912.SA03-2A Tl

,. 10/6/2010 3:17:34 PM 0.000 -0.05 232.96 -0.12801 0.031299

c 1 00912.4!1-2A Tl 10/6/2010 3:22:57 PM 0.000 0.09 73.40 0.04289 0.135448

Glm

c, 100912.411-2A Tl 10/6/2010 3:28:28 PM 0.041 49.69 0.02 1 99.37454 49.67874 49.6958

'::1:» ""n 1 00912.412-2A Tl 10/6/2010 3:33:52 PM 0.000 -0.16 81.39 -0.06743 -0.25029

rn""'

CCV Tl 10/6/2010 3:39:14 PM

mS::m 0.041 49.98 1.62 50.547 65 49.40307

-uz;s: OJ

-1-i- CCB Tl 10/6/2010 3:44:40 PM -0.001 -0.64 58.24 -0.90225 -0.37587

mrn<n 0

**s:~SQ** 1 00912.413-2A Tl 10/6/2010 3:50:03 PM 0.000 -0.20 19.40 -0.1686 -0.2222 ?;

**~Qo~** .-

::0,0'1 -1 100912.401-2A Tl 10/6/2010 3:55:26 PM 0.000 -0.03 244.23 0.02225 -0.08346 OJ

"rnm :0

o,.rn 1 00912.402-2A Tl 10/6/2010 4:00:51 PM 0.000 -0.46 3.91 -0.44566 -0.47103 ()

c:::;,.--1 "'

(jj-u

100912.403-2A Tl 10/6/2010 4:06:19 PM 0.000 -0.17 30.93 -0.20709 -0.13276 (fl

OJ:O co :<JL 1 00912.511-2A Tl 10/6/2010 4:11.49 PM 0.000 -0.07 310.60 -0.21747 0.081392

-<m (4

100912.512-2A Tl 10/6/2010 4:17:16PM 0.000 -0.29 79.96 -0.44748 -0.12423

z

1 00912.513-2A Tl 10/6/2010 4:22:44 PM 0.000 0.00 13092.10 0.108362 -0.11073

-1 en

100912.501-2A Tl 10/6/2010 4:28:11 PM 0.000 -0.04 1385.23 -0.42695 0.347853

1

00912.502-2A Tl 10/6/2010 4:33:38 PM 0.000 0.01 68.23 0.006852 0.019626

CCV Tl 10/6/2010 4:39:05 PM 0.043 51.47 0.16 51.52649 51.41331

CCB Tl 10/6/2010 4:44:30 PM 0.000 -0.57 23.61 -0.47738 -0.66871

,. 1 00912.503-ZA Tl 10/6/2010 4:49:57 PM 0.000 -0.30 69.09 -0.15209 -0.44266

, , m

CCV Tl 10/6/2010 4:55:21 PM 0.042 50.95 0.22 50.87331 51.033

z 0

CCB Tl 10/6/2010 5:00:48 PM 0.000 -0.44 14.68 -0.48772 -0.39598

x , ,. Gl m z p en " "' Page 99 of 1 03"--

, Method 29 Mercury

"" Sample 10 Date Element Aliquot (mL) ConC.IJg {Reading 1) Cone. Jl9 (Reading 2)

(") "lJ

ICV 9/28/2010 Hg 4.99

;o ICB 9/28/2010 Hg -0.02

0 '-

100912.8-28 9!28/2010 Hg 5 0.01 -0.01

m (")

100912.5Ail-2B 9!28!2010 Hg 5 0.15 0.17

""

z 100912.SAI1-2BS 9!28/2010 Hg 5 5.09 5.03

0 100912.SAI2-2B 9/28!2010 Hg 5 0.75 0.80

:::: 100912.SAI3-2B 9/28!2010 Hg 5 0.54 0.52

:: 100912.SA01-2B 9/28/2010 Hg 5 0.08 0.10

,. 100912.SA0 1-28$ 9/28/2010 Hg 5 4.98 5.03

"'

CCV 9/28/2010 Hg 5.13

CCB

9!28/201 0 Hg 0.04 100912.SA02-2B

9/28/2010 Hg 5 0.11 0.12

1 00912.5A03-28 9/28/2010 Hg 5 0.07 0.08

, 100912.411-28 9/28/2010 Hg 5 0.30 0.26

c Glm

100912.411-285 9!28/2010 Hg 5 5.17 5.35

c., 100912.412-28 9!28/201 0 Hg 5 0.22 0.25

**~~**

100912.413-28 9/28!2010 Hg 5 0.17 0.19

w""' 100912.401-28 9!28!201 0 Hg 5 0.37 0.34

rn<;;m CCV 9/28/2010 Hg 4.87

"llZS: --<--<-

CC8 9/28/2010 Hg -0.03 "'

mww 0

**s:~~** 1 00912.401-285 9!28/2010 Hg 5 5.25 5.29

;o

**~Ro~** 1 00912.402·28 9/28/2010 Hg 5 0.45 0.50 , r-

:;:o_r.n-; 100912.403-28 9/28/2010 Hg 5 0.41 0.38 "'

"'wrn ;o

o,w 100912.511-28 9/28/2010 Hg 5 0.44 0.40 (j

;:;!::-;

100912.511-285 9/28!2010 Hg 5 5.57 5.60 "

(f)"ll (f)

"'"' 100912.512-28 9/28/2010 Hg 5 0.34 0.30

co ;o<-

100912.513-28 9/28/2010 Hg 5 0.13 0.19

-<rn ""

CCV 9/28/2010 Hg 5.03

,..--<

CC8 9/28/2010 Hg o.oo

, z

100912.8-3A 9/28/2010 Hg 10 0.01 -0.03

""

"' 100912.5AI1-3A 9/28/2010 Hg 10 0.06 0.04

100912.5AI2-3A 9/28/2010 Hg 10 0.04 0.03

100912.5AI3-3A 9/28/2010 Hg 10 0.01 0.03

100912.5A01-3A 9/28!2010 Hg 10 0.01 0.03

100912.SA02-3A 9/28/2010 Hg 10 -0.03 0.00

,

100912.SA03-3A 9/28!2010 Hg 10 -0.04 -0.01

"lJ

CCV 9!28/2010 Hg 4.93

"lJ CC8

9/28/2010 Hg 0.04

m z

100912.411-3A 9!28/201 0 Hg 10 0.10 0.06

0 x

100912.412-3A 9!28/2010 Hg 10 0.08 0.08

"lJ 100912.413-3A 9/28/2010 Hg 10 0.09 0.06

,

Gl 100912.401-3A 9!28/2010 Hg 10 0.03 -0.01

rn z

100912.402-3A 9/28/2010 Hg 10 -0.01 -0.01

? 1 00912.403-3A 9/28/2010 Hg 10 0.00 0.03

"'

"'

0 Page 100 of 103**~-**

)> Method 29 Mercury

-< Sample JD Dote .Element Aliquot {mL} Conc.IJg (Reading l) Cone. pg (Reading 2}

() ""0

100912.511·3A 9/28/2010 Hg 10 0.04 0.03

;o CCV 9/2812010 Hg 5.00

0 **~**

CCB 9/28/2010 Hg 0.07

m 0

1 00912.512·3A 9/28/2010 Hg 10 0.06 0.08

-< z

100912.513·3A 9/28/2010 Hg 10 0.08 0.10

0 100912.501 -3A 9/28/2010 Hg 10 0.01 0.01

**~**

1 00912.502-3A 9/28/2010 Hg 10 -0.03 0.03

**~**

100912.503-3A 9/28/2010 Hg 10 -O.Dl -0.01

.. CCV 9/28/2010 Hg 5.19

N CC8

9/28/2010 Hg 0.06 100912.501-28

9/28/2010 Hg 5 0.83 0.80

100912.502-28 9/28/2010 Hg 5 0.79 0.74

100912.503-28 9/28/2010 Hg 5 0.76 0.82

)> CCV 9/28/2010 Hg 5.05

c Glm

CC8 9/28/2010 Hg 0.03

C-a

100912.8-38 9/28/2010 Hg 20 0.01 0.00

**~)>** "o 100912 .SAil-38 9/28/2010 Hg 20 0.04 0.04

[/>""O;o 100912.SAI2-38 9/28/2010 Hg 20 0.06 0.03

m't:m 1 00912.SAI3-38 9/28/2010 Hg 20 0.04 0.01

-azs: -<-<-

l00912.SA01-3B 9/28/2010 Hg 20 0.03 0.04 "'

mV>V> 0

S:,:..<E. 1 00912 .SA02 -3 8 9/28/2010 Hg 20 0.04 0.01 **~**

mS(og

1 00912.SA03-38 9/28/2010 Hg 20 -0.01 0.06 ,-

::0 ,?1 -1 CCV 9/28/2010 Hg 4.88 "'

'-'V>m ;o

**~}>(/)** CCB 9/28/2010 Hg -0.01 0

or--< 100912.411·38

9/28/2010 Hg 20 0.01 0.00 "'

r/>""0 (JJ

"'"' 100912.412-38 9/28/2010 Hg 20 0.03 -0.01

co **:o~**

100912.413-38 9/28/2010 Hg 20 0.04 0.06

-<m ""00

100912.401-38 9/28/2010 Hg 20 0.40 0.32

,.;""

100912.402-38 9/28/2010 Hg 20 0.35 0.38

z 1 00912.403-38 9/28/2010 Hg 20 0.29 0.27

-< '"

100912.511-38 9/28/2010 Hg 20 0.38 0.44

CCV 9/28/2010 Hg 5.17

CCB

9/28/2010 Hg

" -0.03 100912.512-38

9/28/2010 Hg 20 0.50 0.50

100912.513-38 9/28/2010 Hg 20 0.47 0.49

)>

100912.501-38 9/28/2010 Hg 20 0.04 0.01

""0 100912.502-38 9/28/2010 Hg 20 ·O.Dl -0.03

""0 m

100912.503-38 9/28/2010 Hg 20 -0.03 0.00

z

0 CCV 9/28/2010 Hg 5.06

x CC8 9/28/2010 Hg 0.03

""0 100912.501-285 9128/2010 Hg 5 6.00 5.91

)>

Gl

CCV 9!28/201 0 Hg 5.19

m z

CC8 9/28/2010 Hg 0.04

0 ICY

10/1/2010 Hg 5.26

'"

'0 Page 101 of 103}> Method 29 Mercury

--< Sample 10 Date Element Aliquot (mL)

**Conc.~Jg** (Reading 1) Conc.pg (Reading 2)

0 ,

ICB 10/1/2010 Hg 0.04

;u CCV 10/1/2010 Hg 4.98

0 L

cca 10/1/2010 Hg -0.01

m 0

100912.8-1 10/1/2010 Hg 5 0.00 0.01

--< z

10091 2.SA11- 1 10/1/2010 Hg 5 0.05 0.03

0 100912.SAI2·1 10/1/2010 Hg 5 0.04 0.03

:;: 100912.SAI3-1 10/1/2010 Hg 5 0.06 0.02

'" 100912.SA01-1 10/1/2010 Hg 5 0.03 0.00

.. 100912.SA02-1 10/1/2010 Hg 5 0.01 0.02

"'

100912.SA03-1 1011/2010 Hg 5 0.00 0.04

CCV 10/1/2010 Hg 4.97

CCB 10/1/2010 Hg 0.04

100912.411-1 10/1/2010 Hg 5 0.03 0.03

}> 100912.412-1 10/1/2010 Hg 5 -0.01 -0.01

c "'m

1 00912.413-1 10/1/2010 Hg 5 0.00 0.03

c, 100912.401-1 10/1/2010 Hg 5 0.01 -0.03

**~}>** »o 100912.402-1 10/1/2010 Hg 5 0.02 0.04

(1),,

100912.403-1 10/1/2010 Hg 5 o.oo 0.04

m);m

CCV 10/1/2010 Hg

. 5.05

-uzs:

--<-;- CCB 10/1/2010 Hg -0.01

CD

m(J)(J) 0

**S:.;:..~** 100912.512-1 10/1/2010 Hg 5 O.OB 0.06 ;u

**fgS?o~** 100912.513-1 10/1/2010 Hg 5 0.01 O.D2 }> r

:::o_c.n -I 100912.501-1 10/1/2010 Hg 5 0.03 0.01 CD

"-'(l)m ;u

**~);>(/)** 100912.502-1 10/1/2010 Hg 5 o.oo -0.01 0

or-< 100912.503-1

10/1/2010 Hg 5 -0.03 0.03 "'

(jj-u

(1)

CD>l 100912.B-3C 10/1/2010 Hg 5 0.01 0.00

co >JL

100912.SAI1-3C 10/1/2010 Hg 5 0.85 0.80

-<m ,o

CCV 10/1/2010 Hg 5.34

);--<

CCB 10/1/2010 Hg -0.03

z 1 00912.SAI2-3C 10/1/2010 Hg 5 1.37 1.52

--< "'

1 00912.SA13-3C 10/1/2010 Hg 5 1.04 1.00
100912.SA01-3C 10/1/2010 Hg 5 0.00 0.04 100912.SA02-3C 10/1/2010 Hg 5 -0.02 0.00

1 00912.SA03-3C 10/1/2010 Hg 5 0.01 -0.03

100912 .41l-3C 10/1/2010 Hg 5 0.37 0.32

}> 1 00912.412-3C 10/1/2010 Hg 5 0.16 0.13

, CCV 10/1/2010 Hg 5.19

, m

CCB 10/1/2010 Hg 0.02

z

10091 2.413-3C 10/1/2010 Hg 5 0.02 0.05

0 x

100912.401-JC 10/l/2010 Hg 5 0.27 0.21

, 100912.402-3C 10/1/2010 Hg 5 0.02 0.04

}> Gl

10091 2.403-3C 10/1/2010 Hg 5 0.08 0.10

m z

100912.511 -3C 10/1/2010 Hg 5 0.14 0.16

0 1 00912.512-3C 10/1/2010 Hg 5 0.18 0.20

"'

w "' Poge 102 of 103, --; 0 "U "' 0

L m 0 --; z ? **~** s: .... "' , c Glm c.,

en,. **~0** en"" m';:m

-uz;::

--<--;- men'" **!§:"""~ ~~~**  ::u 91 -1 "'cnm **~>(/)** or-< i'ii"U OJ:O co :OL -<m .,o ';:--; z --; "' , "U "U m z 0 x **~** m z 0 "' w w Method 29 Mercury Sample 10 Date 100912.513-JC

10/1/2010

CCV

10/1/2010

CCB

10/1/2010 100912.501-JC 10/112010 100912.502-JC

10/1/2010 100912.503-3C 10/112010
CCV 10/1/2010

CCB 10/1/2010

ICY 10/512010

ICB 10/5/2010 100912.511-1

10/5/2010
CCV 10/5/2010
CCB

10/5/2010 Method 29 Mercury Calibration Data True cone., pg/L
BJ.ank 0.00 Standard 1 0.50 Standard 2 1.00 Standard 3 2.00 Standard 4 5.00 Standard 5 10.00 Element Aliquot (mL) Conc.J.Jg (Reading 1) Conc.IJg (Reading 2)

Hg 5 0.11 0.09

Hg 4.88

Hg

o.oo

Hg

5 0.22 0.20

Hg 5 0.21 0.21

Hg 5 0.26 0.22

Hg 5.13

Hg

0.04

Hg 5.03

Hg 0.01

Hg

5.00 0.04 0.04

Hg 5.20

Hg

0.03

Run 1 Run 2 Rvn 3

Abs.

Abs. Abs.
0.000 0.000 0.000 OJ 0

0.016 0.013 0.014 "'

0.034 0.026 ,

0.027

r OJ

0.060 0.052 0.054

"'

Ci

0.151 0.125 0.135

"'

en

0.300 0.248 0.265 Page 103 of 103ATC PROJECT No. P-10142 BORAL BRICKS



# ANALYTICAL 

# ANALYSIS REPORT NELAP Cert. No. 04053 

# Method 29: 

# Multi-metals

Project ID: P-10124

Prepared for: Analytical Testing Consultants, Inc. 1630 Dale Earnhardt Blvd.

Kannapolis, NC 28083

Page 1 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 531

# ( BORAL BRICKS 

# FIRST AN.A.LYTICAL


## Reviewed by:

Tara Sheehan Laboratory Manager

October 11, 2010

Reviewed and Approved by:

Jennifer B. 

## Feller Quality Assurance Manager October 11,2010
Do not reproduce this report except in whole withoutpermission oft he laboratory.

ATC PROJECT No. P-10142 

### This report meets the requirements of LAC33/NELAP.

Page 2 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 532BORAL BRICKS



# CASE NARRATIVE Project#: 100912 Client: Analytical Testing Consultants, Inc. Client Project ID: P-1 0124 Samples: Report Date: 11-0ct-10

Nineteen sets of Method 29 samples were submitted, one of which was the blank set. The target elements were antimony, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, lead, magnesium, manganese, nickel, phosphorus, selenium, silver, thallium, zinc, and mercury. The filter san1ple for Plant 

# 5 Inlet Run I 

# was received separately at a later date. The samples were received in good condition with no apparent leakage or damage, and custody seals intact. All of the remaining amounts ofthe samples and digestates will be retained by the laboratory for six months and then discarded. Preparation: The samples were prepared and analyzed according to EPA Method 29, Determination of Metals Emissions from Stationary Sources. 

# The front and back halves were analyzed separately. Analysis: Antimony, arsenic, cobalt, lead, selenium, and thallium were determined by Graphite Furnace Atomic Absorption Spectrophotometry (GFAA). Barium, beryllium, cadmium, chromium, copper, magnesium, manganese, nickel, phosphorus, silver, and zinc were determined by Inductively Coupled PlasmaOptical Emission Spectrometry (ICP-OES). Mercury was detennined by Cold Vapor Atomic Absorption Spectrophotometry (CVAA).

ATC PROJECT No. P-10142 Page 3 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 533BORAL BRICKS 

# FIRST ANALYTICAL


# Results: The Method 29 metals results are presented as total micrograms of each element present in the whole analytical fraction indicated. Antimony, beryllium, cadmium, and thallium were not detected in any ofthe samples. All other elements of interest were detected in most of the runs. Quality Control: Chromium, magnesium, manganese, nickel, phosphorus, and zinc were all detected in the blank and may be blank corrected at the user's discretion, since some sample levels are comparable to the blank levels. Cobalt, selenium, and silver all showed interferences requiring dilutions for the spikes to pass, thus, causing the detection limits to increase. All of the spike recoveries were within the normal range of75% to 125%. All ofthe samples were analyzed at least in duplicate.

ATC PROJECT No. P-10142 Page 4 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 534

### I BORAL BRICKS 

# ANALYTICALLABORATORlliS billing POBox 

### i 10372- ResMrch Triangle Park.. NC 27709 

# ,....,...,,,ipp"'g 7517 Precision Drive, Suit¢ 101
- Rnleigh, NC :r:'617 

# ANALYSIS REPORT TEL. 919**9~2** 8607 F.<\..X: 919 882 1.60:'> www.tl:r!>tnnalylicollabs. CI..'>Ol



## Project#; 1 00912 Report Dale: 08-0cl-1 0 Client: Analytical Testing Consultants, Inc. Dale Received: 24-Sep-1 0 Client Project ID: P-10124 Sample Blank Front Blank Back S. Inlet Run 1 Front S. Inlet Run 1 Back S. Inlet Run 2 Front S. Inlet Run 2 Back S. Inlet Run 3 Front S. Inlet Run 3 Back S. Outlet Run 1 Front S. Outlet Run 1 Back S. Outlet Run 2 Front S. Outlet Run 2 Back S. Outlet Run 3 Fran! S. Outlet Run 3 Back 4 Inlet Run 1 Front 4 Inlet Run 1 Back 4 Inlet Run 2 Fran! 4 Inlet Run 2 Back 4 Inlet Run 3 Front 4 Inlet Run 3 Back 4 Outlet Run 1 Front 4 Outlet Run 1 Back 4 Outlet Run 2 Front 4 Outlet Run 2 Back 4 Outlet Run 3 Front 4 Outlet Run 3 Back

ATC PROJECT No. P-1 0142 

## Total Micrograms in Sample Sb As 

## Ba Be 

## pg Jig pg Jig < 1.0 

## < 0.5 

## < 2.5 

## < 0.05 

## < 1.8 

## < 0.9 

## < 4.4 

## < 0.09 

## < 1.0 2.3 21.3 

## < 0.05 

## < 1.4 3.9 

## < 3.6 

## < 0.07 

## < 1.0 3.0 34.0 

## < 0.05 

## < 1.4 5.0 8.2 

## < 0.07 

## < 1.0 2.8 28.8 

## < 0.05 

## < 1.4 3.7 4.1 

## < 0.07 

## < 1.0 

## < 0.5 2.7 

## < 0.05 

## < 1.4 

## < 0.7 13.2 

## < 0.07 

## < 1.0 

## < 0.5 2.6 

## < 0.05 

## < 1.5 

## < 0.8 

## < 3.8 

## < 0.08 

## < 1.0 

## < 0.5 5.0 

## < 0.05 

## < 1.4 

## < 0.7 3.9 

## < 0.07 

## < 1.0 

## < 0.5 3.6 

## < 0.05 

## < 1.4 

## < 0.7 

## < 3.6 

## < 0.07 

## < 1.0 

## < 0.5 5.2 

## < 0.05 

## < 1.4 

## < 0.7 14.8 

## < 0.07 

## < 1.0 

## < 0.5 5.0 

## < 0.05 

## < 1.4 

## < 0.7 16.3 

## < 0.07 

## < 1.0 

## < 0.5 5.7 

## < 0.05 

## < 1.4 

## < 0.7 

## < 3.6 

## < 0.07 

## < 1.0 

## < 0.5 5.1 

## < 0.05 

## < 1.4 

## < 0.7 

## < 3.5 

## < 0.07 

## < 1.0 

## < 0.5 4.3 

## < 0.05 

## < 1.4 

## < 0.7 18.4 

## < 0.07

Page 5 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

## Cd Cr 

## pg 119 

## < 0.30 2.1 

## < 0.53 

## < 0.9 

## < 0.30 1. 7 

## < 0.43 3.2 

## < 0.30 2.4 

## < 0.43 1 .8 

## < 0.30 2.4 

## < 0.42 0.8 

## < 0.30 1 .6 

## < 0.43 3.1 

## < 0.30 1.3 

## < 0.46 

## < 0.8 

## < 0.30 1.4 

## < 0.41 

## < 0.7 

## < 0.30 2.4 

## < 0.43 2.1 

## < 0.30 2.2 

## < 0.43 2.7 

## < 0.30 2.3 

## < 0.43 1.4 

## < 0.30 2.2 

## < 0.43 

## < 0.7 

## < 0.30 2.2 

## < 0.42 

## < 0.7 

## < 0.30 2.7 

## < 0.43 

## < 0.7

APPENDIX PAGE No. 535

# ( BORAL BRICKS 

# FIR.':;T ANALYTICAL LABORATORIES

**~~~** - btiliog. PO Box 110372- Rese.."\rcb Trianll.iePark., NC 27709 :llippiltg: 751 "!Precision Dri\·e.. Smte 101
- Rnleigh,



### N<.~ .}161: 

# ANAlYSIS REPORT TEL. 919 9-12 8607 FA.X: 919 8821603

**ww:w.ilrstattalyi~JlJbs.com.**



## Project#: 100912 Report Date: 08-0ct-1 0 Client: Analytical Testing Consultants, Inc. Date Received: 24-Sep- 10 Client Project ID: P-10124 Sample 5 Inlet Run 1 Front 5 Inlet Run 1 Back 5 Inlet Run 2 Front 5 Inlet Run 2 Back 5 Inlet Run 3 Front 5 Inlet Run 3 Back 5 Outlet Run 1 Front 5 Outlet Run 1 Back 5 Outlet Run 2 Front 5 Outlet Run 2 Back 5 Outlet Run 3 Front 5 Outlet Run 3 Back Spike, %Rec. Front Spike, %Rec. Back Duplicate, %RPD Front Duplicate, %RPD Back

ATC PROJECT No. P-10142 

## Total Micrograms in Sample Sb As Ba Be f.l9 f.l9 f.l9 f.l9 

## < 1.0 1.9 5.5 

## < 0.05 

## < 1.4 2.3 9.5 

## < 0.07 

## < 1.0 0.7 6.2 

## < 0.05 

## < 1.4 

## < 0.7 

## < 3.5 

## < 0.07 

## < 1.0 

## < 0.5 6.1 

## < 0.05 

## < 1.4 

## < 0.7 12.3 

## < 0.07 

## < 1.0 

## < 0.5 

## < 2.5 

## < 0.05 

## < 1.4 

## < 0.7 

## < 3.5 

## < 0.07 

## < 1.0 

## < 0.5 

## < 2.5 

## < 0.05 

## < 1.4 

## < 0.7 8.4 

## < 0.07 

## < 1.0 

## < 0.5 

## < 2.5 

## < 0.05 

## < 1.4 

## < 0.7 7.0 

## < 0.07

QC 

## SUMMARY 97% 76% 85% 84% 125% 105% 97% 88%

N/A N/A 4% N/A N/A N/A N/A N/A

Page 6 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

## Cd Cr f.l9 f.l9 

## < 0.30 1.6 

## < 0.43 3.0 

## < 0.30 1.9 

## < 0.42 1.2 

## < 0.30 2.0 

## < 0.43 

## < 0.7 

## < 0.30 2.0 

## < 0.42 

## < 0.7 

## < 0.30 1 .6 

## < 0.43 

## < 0.7 

## < 0.30 1 .6 

## < 0.43 

## < 0.7 78% 94% 89% 77% N/A 5% N/A N/A

APPENDIX PAGE No. 536BORAL BRICKS 

# FIRST ANALYTICAL LABORATORIES

billin.r;: PO Box 110372 -Rese11rcb. Tnangle Park. NC 27709**""'''''~'I"·""'** !51' Premsj;:m Driv6. Smte J01
- fullei._cll. NC :-:611 

# ANAlYSIS REPORT TEL: 919 942 8607 FA .. 'X_: 919 882 1603**WW'i\'.tit-stanalyticalhh~.cbm**



### Project#: 100912 Report Date: 08-0ct-1 0 Client: Analytical Testing Consultants, Inc. Date Received: 24-Sep-1 0 Client Project ID: P-10124 

## Sample Blank Front Blank Back S. Inlet Run 1 Front S. Inlet Run 1 Back S. Inlet Run 2 Front S. Inlet Run 2 Back S. Inlet Run 3 Front S. Inlet Run 3 Back S. Outlet Run 1 Front S. Outlet Run I Back S. Outlet Run 2 Front S. Outlet Run 2 Back S. Outlet Run 3 Front S. Outlet Run 3 Back 4 Inlet Run 1 Front 4 Inlet Run 1 Back 4 Inlet Run 2 Front 4 Inlet Run 2 Back 

### 4 Inlet Run 3 Front 4 Inlet Run 3 Back 4 Outlet Run 1 Front 4 Outlet Run 1 Back 4 Outlet Run 2 Front 4 Outlet Run 2 Back 4 Outlet Run 3 Front 4 Outlet Run 3 Back

ATC PROJECT No. P-1 0142 

## Total Micrograms in Sample Co Cu Pb 

## Mg J-ig J-ig J-ig JJg 

## < 0.3 

## < 0.5 

## < 0.5 12.9 

## < 0.5 

## < 0.9 

## < 0.9 2.9 

## < 0.3 5.3 8.7 36.7 

## < 13.0 3.8 2.5 132



## < 0.3 5.3 7.9 45.8 

## < 0.4 2.1 0.8 40.8 

## < 0.3 4.8 7.1 50.8 

## < 0.4 2.3 

## < 0.7 125 

## < 0.3 

## < 0.5 

## < 0.5 11.5 

## < 0.4 0.9 

## < 0.7 4.6 

## < 0.3 

## < 0.5 

## < 0.5 11.6 

## < 0.5 

### 1.3 

## < 0.8 7.2 

## < 0.3 

## < 0.5 

## < 0.5 12.0 

## < 0.4 1.5 

## < 0.7 6.1 

## < 0.3 

## < 0.5 

## < 0.5 18.6 

## < 0.4 1.0 

## < 0.7 212 

## < 0.3 

## < 0.5 

## < 0.5 15.7 

## < 0.4 1.1 1 . 1 243 

## < 0.3 

## < 0.5 

## < 0.5 14.1 

## < 0.4 0.8 

## < 0.7 126 

## < 0.3 

## < 0.5 

## < 0.5 18.9 2.3 1.5 

## < 0.7 12.5 

## < 0.3 

## < 0.5 

## < 0.5 18.6 1.1 

## < 0.7 

## < 0.7 1 1.1 

## < 0.3 

## < 0.5 

## < 0.5 19. I 0.8 2.1 0.8 20.5
Page 7 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

## Mn Ni J-ig J-ig 

### 1.1 0.6 

## < 0.4 

## < 0.5

11.B 0.6 21.8 18.0 12.1 0.9

6.4 3.5 12.3 1.0

6.2 4.5 1.6 0.7 1.4 16.3 1.3 0.7 2.2 2.0 1 .9 O.B 11.0 1 .4

1.3 1.7 4.6 1.3 1 .2 1.0 4.7 2.2 1.5 1.4 2.3 1.8 1.3 1.1 

### 2.6 1.7 1.2 1.3 1.2 0.5 1.3 1.6 2.6 1.2

APPENOIX PAGE No. 537

# ( BORAL BRICKS 

# FIRST ANALYTICAL LABORATORIES

biJ/tng: PO Box 1 i0372. Research Triangle Park. NC 27"70'-J

. . .. tltippillg: 1517**Proc~i0n** Dtive, Sl1ite I Ol -Raleigh. NC 27617**-~f,Z~~~f.'t** 

# ANALYSIS REPORT TEL: 919 942 8607 FA.X:**~19** S82 1603 \\'"\\'\Y,i\tstanalyti..:n.)l.alll> .com



### Project#: 100912 Report Date: 08-0ct-1 0 Client: Analytical Testing Consultants, Inc. Date Received: 24-Sep-1 0 Client Project ID: P-1 0124 Sample 5 Inlet Run 1 Front 5 Inlet Run 1 Back 5 Inlet Run 2 Front 5 Inlet Run 2 Back 5 Inlet Run 3 Front 5 Inlet Run 3 Back 5 Outlet Run 1 Front 5 Outlet Run 1 Back 5 Outlet Run 2 Front 5 Outlet Run 2 Back 5 Outlet Run 3 Front 5 Outlet Run 3 Back Spike, %Rec. Front Spike, % Rec. Back Duplicate, %RPD Front Duplicate, %RPD Back

ATC PROJECT No. P-10142 

### Total Micrograms in Sample Co 

## Cu Pb Mg 

## Jig Jig Jig Jig < 0.3 0.8 0.8 30.5 

## < 0.4 

### 1.l 1.3 289 

## < 0.3 0.8 0.6 30.4 

## < 0.4 0.9 

## < 0.7 11 0 

## < 0.3 0.8 0.6 22.9 

## < 0.4 1.3 

## < 0.7 117 

## < 0.3 

## < 0.5 

## < 0.5 21.6 

## < 0.4 1.7 0.9 10.1 

## < 0.3 

## < 0.5 

## < 0.5 21.0 

## < 0.4 1.5 

## < 0.7 157 

## < 0.3 

## < 0.5 

## < 0.5 24.4 

## < 0.4 1.5 0.8 84.0



## QC SUMMARY 82% 99% 91% 84% 78% 82% 95% 94% N/A 2% N/A 0.2% N/A N/A N/A 2%

Page 8 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### Mn Ni 

## Jig Jig 5.4 

## 1.1 25.4 2.5

6.2 1.4 2.9 1.0 3.6 1.0 3.6 0.9 1.9 0.8 1.7 0.8 2.0 0.9 15.5 0.7

2.3 

### 1.l 1.7 1 . 1
92% 105% 76% 85%

2% N/A 6% 13%

APPENDIX PAGE No. 538

# ( BORAL BRICKS 

# FIRST ANALYTICAL LABORATORIES

bt!ling: PO Bl'X 1103 72**~** Research Trianlrle Pruic. NC 277CJ:J Jln}'Jiillg; 7$17 Pre(:.isionDr.h:e, Suitco 101
- 

### :R.,teigh, NC '2761 7**~~.~~~~~~** 

# ANALYSIS REPORT TEL9l9 9428607 F .

..:..:..''(: 919 882 .1603 v.''".,.·**fn"Stan~** J:ytic.;llabs. c.om



## Project#: 100912 Report Date: 08-0ct-1 0 Client: Analytical Testing Consultants, Inc. Date Received: 24-Sep- 10 Client Project ID: P-10124 Sample Blank Front Blank Back S. Inlet Run 1 Front S. Inlet Run 1 Back S. Inlet Run 2 Front S. Inlet Run 2 Back S. Inlet Run 3 Front S. Inlet Run 3 Back S. Outlet Run 1 Front S. Outlet Run 1 Back S. Outlet Run 2 Front S. Outlet Run 2 Back S. Outlet Run 3 Front S. Outlet Run 3 Back 

## 4 Inlet Run 1 Front 

## 4 Inlet Run 1 Back 4 Inlet Run 2 Front 4 Inlet Run 2 Back 4 Inlet Run 3 Front 4 Inlet Run 3 Back 4 Outlet Run 1 Front 4 Outlet Run 1 Back 4 Outlet Run 2 Front 4 Outlet Run 2 Back 

## 4 Outlet Run 3 Front 

## 4 Outlet Run 3 Back

ATC PROJECT No. P-10142 

## Total Micrograms in Sample p 

## Se Ag Tl 1-19 1-19 1-19 1-19 

## 10.5 

## < 1.0 

## < 0.5 

## < 0.5 

## < 17.6 

## < 1.8 

## < 0.9 

## < 0.9 37.7 1.3 

## < 2.5 

## < 0.5 26.7 

## < 21.7 

## < 0.7 

## < 0.7 35.7 1.5 

## < 0.5 

## < 0.5 23.2 2.1 

## < 0.7 

## < 0.7 31.5 

## < 1.0 

## < 0.5 

## < 0.5 23.6 

## < 1.4 

## < 0.7 

## < 0.7 16.0 

## < 1.0 

## < 0.5 

## < 0.5 20.9 1 .9 

## < 0.7 

## < 0.7 17.2 

## < 1.0 

## < 0.5 

## < 0.5 17.6 

## < 1.5 

## < 0.8 

## < 0.8 14.7 

## < 1.0 

## < 0.5 

## < 0.5 24.1 

## < 1.4 

## < 0.7 

## < 0.7 25.2 1.3 

## < 0.5 

## < 0.5 16.1 

## < 1.4 

## < 0.7 

## < 0.7 16.5 

## < 1.0 

## < 0.5 

## < 0.5 19.5 2.4 

## < 0.7 

## < 0.7 27.3 

## < 1.0 

## < 0.5 

## < 0.5 

## < 14.3 1.4 

## < 0.7 

## < 0.7 19.6 

## < 1.0 

## < 0.5 

## < 0.5 20.8 

## < 1.4 

## < 0.7 

## < 0.7 19.0 

## < 1.0 

## < 0.5 

## < 0.5 17.4 

## < 1.4 

## < 0.7 

## < 0.7 18.9 

## < 1.0 

## < 0.5 

## < 0.5 

## < 14.5 

## < 1.4 

## < 0.7 

## < 0.7
Page 9 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

## Zn 1-19 

## 2.3 

## < 0.9

24.2 12.2 24.1

4.6 21.9

2.5 3.0 2.0 3.0 3.4 4.3 2.5 2.6 3.3 2.4 5.5 2.3 4.2 2.8 5.6 2.5 2.1 2.5 7.0

APPENDIX PAGE No. 539

## ( BORAL BRICKS 

# ANALYTICAL LABORATORIES blllin ...

**~** PO B0.x. 110372-

**R~search** Triangle P<lrk NC 27709

7517

**Pre-cisionDrin~.** Smte 101 N Rrtleigh, NC 1i617 

# ANAlYSIS REPORT TEL: 919 942&607 F.<>;.X: 919 882 1603

**W\YW.firstanalyi.K-nllabs~~··(.'lU**



## Project#: 100912 Report Dote: 08-0ct-1 0 Client: Analytical Testing Consultants, Inc. Date Received: 24-Sep-1 0 Client Project ID: P-10124 Sample 

## 5 Inlet Run 1 Front 5 Inlet Run 1 Bock 5 Inlet Run 2 Front 5 Inlet Run 2 Back 5 Inlet Run 3 Front 5 Inlet Run 3 Back 5 Outlet Run 1 Front 5 Outlet Run 1 Back 5 Outlet Run 2 Front 5 Outlet Run 2 Back 5 Outlet Run 3 Front 5 Outlet Run 3 Bock Spike, %Rec. Front Spike, %Rec. Bock Duplicate, %RPD Front Duplicate, %RPD Back

ATC PROJECT No. P-10142 

### Total Micrograms in Sample 

## p 

# Se Ag Tl 

## Jig Jig Jig Jig 17.1 1.9 

## < 0.5 

## < 0.5 17.4 3.4 

## < 0.7 

## < 0.7 30.4 4.4 

## < 0.5 

## < 0.5 25.0 1.5 

## < 0.7 

## < 0.7 18.5 7.5 

## < 0.5 

## < 0.5 

## < 14.3 

## < 1.4 

## < 0.7 

## < 0.7 

## < 10.0 

## < 1.0 

## < 0.5 

## < 0.5 19.1 

## < 1.4 

## < 0.7 

## < 0.7 

## < 10.0 

## < 1.0 

## < 0.5 

## < 0.5 22.3 1.6 

## < 0.7 

## < 0.7 10.0 

## < 1.0 

## < 0.5 

## < 0.5 23.3 

## < 1.4 

## < 0.7 

## < 0.7 QC SUMMARY 

## 101% 79% 77% 102%

76% 93% 79% 99% N/A N/A N/A N/A N/A N/A N/A N/A

Page 10 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### Zn 

## Jig 4.9 3.3 4.1 2.3 4.2 3.1 4.0 4.9 2.8 6.0 2.4 6.3
88% 92%

2% N/A

APPENDIX PAGE No. 540

## ( BORAL BRICKS 

# FIRST ANALYTICAL LABORATORIES

b;iling 

### PO Box 1103i2

**~Research** 

### Triancle Park. NC 27709 shippmg: 7517 Precision Drive, Suite 101
- R.lleigh, NC 27617

**~"-~'1S'-k~1~"%'~** 

# MERCURY ANALYSIS REPORT TEL: 919 

### 942 8607 FAX: 919 882 1603 WW'>Y. firsbu;t<.\1)1ica1labs. com



## Project#: 100912 Report Date: 07-Oct-1 0 Client: Analytical Testing Consultants, Inc. Date Received: 24-Sep-1 0 Client Project I D: P- 10124 Total Micrograms of Mercury in Sample Sample 

## Blank Salisbury-Inlet-Run 1 Salisbury-Inlet-Run 2 Salisbury-Inlet-Run 3 Salisbury-Outlet-Run 1 Salisbury-Outlet-Run 2 Salisbury-Outlet-Run 3 Plant 4-lnlet-Run 1 Plant 4-lnlet-Run 2 Plant 4-lnlet-Run 3 Plant 4-0utlet-Run 1 Plant 4-0utlet-Run 2 Plant 4-0utlet-Run 3 Plant 5-lnlet-Run 1 Plant 5-lnlet-Run 2 Plant 5-lnlet-Run 3 Plant 5-0utlet-Run 1 Plant 5-0utlet-Run 2 Plant 5-0utlet-Run 3
BACK SPIKE Sol. Inlet BACK SPIKE Sal. Outlet BACK SPIKE-Plant 4 In BACK SPIKE-Plant 4 Out BACK SPIKE-Plant 5 In BACK SPIKE-Plant 5 Out

ATC PROJECT No. P-10142 

## Frac 1 Frac2B Frac3A Frac3B pg pg pg pg 

## < 0.4 < 0.5 < 0.1 < 0.1 < 0.4 < 1.3 < 0.3 < 0.4 < 0.4 5.2 < 0.2 < 0.4 < 0.4 3.8 < 0.3 < 0.4 < 0.4 < 1.3 < 0.2 < 0.4 <0.4 < 1.2 

## < 0.3 < 0.4 

## < 0.4 < 1.5 

## < 0.3 < 0.4 < 0.4 1.9 < 0.2 < 0.4 < 0.4 1.6 < 0.2 < 0.4 < 0.4 

## < 1.3 

## < 0.2 

## < 0.4 < 0.4 2.3 < 0.2 0.7 < 0.4 3.3 < 0.2 0.7 < 0.4 2.6 < 0.2 0.6 < 0.4 2.8 < 0.2 0.8 < 0.4 2.3 

## < 0.2 1.1 < 0.4 < 1.3 < 0.2 1.1 < 0.4 5.7 < 0.2 < 0.4 < 0.4 5.1 < 0.2 < 0.4 < 0.4 5.2 < 0.2 < 0.4 QC SUMMARY 

## %Recovery 101% %Recovery 100% %Recovery 100% %Recovery 98% %Recovery 103% %Recovery 103%

Page 11 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

## Frac3C Total j.lg pg 

## < 0.4 

## < 1.5 

## 4.2 4.2 

## 7.2 12.4 

## 5.1 8.9 

## < 1.1 

## < 3.4 

## < 1.0 

## < 3.3 

## < 1.0 < 3.6 

## 1.0 2.9 

## < 1.1 1.6 

## < 1.1 

## < 3.4 

## 1.2 4.2 

## < 1.1 4.0 

## < 1.0 3.2 

## < 1.0 3.6 

## < 1.0 3.4 

## < 0.9 1.1 

## 1.0 

## 6.1 1.0 6.1 

## 1.2 6.4

APPENDIX PAGE No. 541BORAL BRICKS


## ANTIMONY GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. MDL= 

### 10 IJg/l Proj. #: 

### 100912 Postdig'n spike cone. 

### = 

### 100 IJg/l Date: 08-0ct-1 0 Sample ID Test 

### Dig'le Dil'n Total Volume Client 

### FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total 

### IJg/l IJg/l ml ml ml 

### 119 FRONT HALVES 

### Blank 100912.8-1 1.6 1.6 100 

### < 1.0 Salisbury Inlet Run 1 1 00912.SAI1-1 9.1 9.1 100 

### < 1.0 Salisbury Inlet Run 2 100912.SAI2-1 7.8 7.8 100 < 

### 1.0 Salisbury Inlet Run 3 100912.SAI3-1 9.5 9.5 100 

### < 1.0 Salisbury Outlet Run 1 100912.SA01-1 6.4 6.4 100 

### < 1.0 Salisbury Outlet Run 2 100912.SA02-1 9.3 9.3 100 

### < 1.0 Salisbury Outlet Run 3 100912.SA03-1 7.8 7.8 100 < 

### 1.0 Plant 4 Inlet Run 1 100912.411-1 9.2 9.2 100 

### < 1.0 Pia nt 4 In let Run 2 100912.412-1 4.6 4.6 100 

### < 1.0 Plant 4 Inlet Run 3 100912.413-1 8.6 8.6 100 

### < 1.0 Plant 4 Outlet Run 1 100912.401-1 4.4 4.4 100 < 

### 1.0 Plant 4 Outlet Run 2 100912.402-1 3.8 3.8 100 

### < 1.0 Plant 4 Outlet Run 3 100912.403-1 7.9 7.9 100 

### < 1.0 Plant 5 Inlet Run 1 100912.511-1 1.0 1.0 100 < 

### 1.0 Plant 5 Inlet Run 2 100912.512-1 3.3 3.3 100 

### < 1.0 Plant 5 Inlet Run 3 100912.513-1 4.7 4.7 100 

### < 1.0 Plant 5 Outlet Run 1 100912.501-1 6.4 6.4 

### 100 

### < 1.0 Plant 5 Outlet Run 2 100912.502-1 2.5 2.5 100 

### < 1.0 Plant 5 Outlet Run 3 100912.503-1 5.9 5.9 100 

### < 1.0

ENERGY I ENVIRONMENTAL I ENGINEERING I CARBON MANAGEMENT

ATC PROJECT No. P-10142 EPA I AUGUST; www.mmal.com rX PAGE No. 542

:

### i

\ BORAL BRICKS


## ANTIMONY GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. 

### MDL; 10 J!g/L Proj. 

### #: 100912 Postdig'n spike cone. 

### = 100 J!g/L Date: 08-0ct-10 Sample ID Test Dig'te 

### Dil'n Total Volume Client 

### FAL Sol'n 

### Cone 

### FV Foetor Volume Dig'd 

### Total pg/L J1g/L ml ml ml 

### !19 BACK HALVES 

### Blank 100912.B-2A 4.0 4.0 100 116 66 

### < 1.8 Salisbury Inlet Run 1 100912.SAI1-2A 8.8 8.8 100 324 224 

### < 1.4 Salisbury Inlet Run 2 100912.SAI2-2A 7.0 7.0 100 1 336 236 

### < 1.4 Salisbury Inlet Run 3 100912.SA13-2A 7.0 7.0 100 1 356 256 

### < 1.4 Salisbury Outlet Run 1 100912.SA01-2A 8.7 8.7 100 335 235 

### < 1.4 Salisbury Outlet Run 2 100912.SA02-2A 8.3 8.3 100 288 188 

### < 1.5 Salisbury Outlet Run 3 100912.SA03-2A 4.7 4.7 100 366 266 

### < 1.4 Plant 4 Inlet Run 1 100912.411-2A 5.8 5.8 100 333 233 

### < 1.4 Plant 4 Inlet Run 2 100912.412-2A 7.4 7.4 100 339 239 

### < 1.4 Plant 4 Inlet Run 3 100912.413-2A 5.0 5.0 100 333 233 

### < 1.4 Plant 4 Outlet Run 1 100912.401-2A 7.3 7.3 100 324 224 

### < 1.4 Plant 4 Outlet Run 2 100912.402-2A 9.7 9.7 100 342 242 

### < 1.4 Plant 4 Outlet Run 3 100912 .403-2A 4.7 4.7 100 323 223 

### < 1.4 Plant 5 Inlet Run 1 100912.511-2A 8.5 8.5 100 339 239 

### < 1.4 Plant 5 Inlet Run 2 100912.512-2A 7.7 7.7 100 351 251 

### < 1.4 Plant 5 Inlet Run 3 100912.513-2A 9.7 9.7 100 333 233 

### < 1.4 Plant 5 Outlet Run 1 100912.501-2A 4.9 4.9 100 350 250 

### < 1.4 Plant 5 Outlet Run 2 100912.502 -2A 5.3 5.3 100 334 234 

### < 1.4 Plant 5 Outlet Run 3 100912.503-2A 6.4 6.4 100 329 229 

### < 1.4 FRONT SPIKE 100912.SA11-l 97.2 % REC 

### = 97.2% BACK SPIKE 100912.SAI1-2A 124.8 % REC = 

### 124.8%

Page 13 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 543

# ( BORAL BRICKS 

# ARSENIC GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Clienf: Anoly!ical Testing Consul!ants, Inc.**MDL~** 

### 5 J.lg/L Proj. 

### #: 100912 Postdig 1 n spike cone. 

### = 100 J.lg/L Dote: 06-0ct-1 0 Sample ID Test Dig'fe Dil'n To!al Volume Client 

### FAL Sol'n 

### Cone FV Factor Volume 

### Dig'd To!al J.lg/L J.lg/L ml ml ml J.l9 

### FRONT HALVES Blank 100912.B-1 -1.6 -1.6 100 

### < 0.5 Salisbury Inlet Run 1 100912.SAI1-1 22.6 22.6 100 2.3 Salisbury Inlet Run 2 100912.SAI2-1 29.6 29.6 100 3.0 Salisbury Inlet Run 3 10091 2 .SAI3- 1 27.7 27.7 100 2.8 Salisbury Outlet Run 1 100912.SA01-1 1.7 1.7 100 

### < 0.5 Salisbury Outlet Run 2 100912.SA02-1 1.2 1.2 100 

### < 0.5 Salisbury Outlet Run 3 100912.SA03-1 0.1 0.1 100 

### < 0.5 Plant 4 Inlet Run 1 100912.411-1 2.4 2.4 100 

### < 0.5 Plant 4 Inlet Run 2 100912.412-1 0.1 0.1 100 

### < 0.5 Plant 4 Inlet Run 3 100912.413-1 0.5 0.5 100 

### < 0.5 Plant 4 Outlet Run 1 100912.401-1 2.5 2.5 100 

### < 0.5 Plant 4 Outlet Run 2 100912.402-1 3.6 3.6 100 

### < 0.5 Plant 4 Outlet Run 3 100912.403-1 2.1 2.1 100 

### < 0.5 Plant 5 Inlet Run 1 100912.511-1 18.9 18.9 100 1.9 Plant 5 Inlet Run 2 100912.512-1 7.2 7.2 100 0.7 Plant 5 Inlet Run 3 100912.513-1 2.1 2.1 100 

### < 0.5 Plant 5 Outlet Run 1 100912.501-1 0.8 0.8 100 

### < 0.5 Plant 5 Outlet Run 2 100912.502-1 0.7 0.7 100 

### < 0.5 PlantS Outlet Run 3 100912.503-1 3.2 3.2 100 

### < 0.5

Page 14 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 544BORAL BRICKS


## ARSENIC GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc.**MDL~** 

### 5 flg/L Proj. 

### #: 100912 Postdig'n spike cone. 

### = 100 flg/L Dole: 06-0ct-1 0 Sample ID Test 

### Dig'le Dil'n Total Volume Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total flg/L pg/L ml ml ml 

### pg BACK HALVES Blank 100912.B-2A -0.2 -0.2 100 116 66 

### < 0.9 Salisbury Inlet Run 1 100912.SAI1-2A 26.6 26.6 100 324 224 3.9 Salisbury Inlet Run 2 100912.SAI2-2A 35.0 35.0 100 336 236 5.0 Salisbury Inlet Run 3 100912.SAI3-2A 26.4 26.4 100 356 256 3.7 Salisbury Outlet Run 1 100912.SA01-2A 0.6 0.6 100 335 235 

### < 0.7 Salisbury Outlet Run 2 

### 100912.SA02-2A 1.8 1.8 100 288 188 

### < 0.8 Salisbury Outlet Run 3 100912.SA03-2A 1.5 1.5 100 366 266 

### < 0.7 Plant 4 Inlet Run 1 100912.411-2A 0.7 0.7 100 333 233 

### < 0.7 Plant 

### 4 Inlet Run 2 100912.412-2A 1.7 1.7 100 339 239 < 

### 0.7 Plant 

### 4 Inlet Run 3 100912.413-2A 0.3 0.3 100 333 233 

### < 0.7 Plant 

### 4 Outlet Run 1 100912.401-2A -0.4 -0.4 100 324 224 

### < 0.7 Plant 4 Outlet Run 2 100912.402-2A 0.7 0.7 100 342 242 

### < 0.7 Plant 4 Outlet Run 3 100912.403-2A -0.3 -0.3 100 323 223 

### < 0.7 Plant 5 Inlet Run 1 100912 .511-2A 15.9 15.9 100 339 239 2.3 Plant 5 Inlet Run 2 100912.512-2A 3.6 3.6 100 351 251 

### < 0.7 Plant 5 Inlet Run 3 100912.513-2A -0.1 -0.1 100 333 233 < 

### 0.7 Plant 5 Outlet Run 1 100912.501-2A -0.4 -0.4 100 350 250 

### < 0.7 Plant 5 Outlet Run 2 100912.502-2A -0.5 -0.5 100 334 234 

### < 0.7 Plant 5 Outlet Run 3 100912.503-2A -1.2 -1.2 100 329 229 

### < 0.7 FRONT SPIKE 100912.411-1 75.9 % REC 

# = 75.9% BACK SPIKE 100912.SAI1-2A 132.1 % REC 

# = 105.4%

Page 15 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 545BORAL BRICKS


## BARIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. MDL= 25 jig/L Proj. #: 100912 Postdig'n spike cone. = 

### 1000 jig/l Date: 05-0ct-1 0 Sample ID Test Dig'te Dil'n 

### Total Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total Jig/L Jig/L ml ml ml jig FRONT HALVES 

### Blank 100912.8-1 13.6 13.6 100 < 

### 2.5 Salisbury Inlet Run 1 

### 100912.SAI1-1 213.4 213.4 100 21.3 Salisbury Inlet Run 2 100912.SA12-1 339.9 339.9 100 34.0 Salisbury Inlet Run 3 100912.SA13-1 287.9 287.9 100 28.8 Salisbury Outlet Run 1 

### 100912.SA01-1 26.8 26.8 100 2.7 Salisbury Outlet Run 2 1 00912.SA02-1 25.8 25.8 100 2.6 Salisbury Outlet Run 3 100912.SA03-1 49.9 49.9 100 5.0 Plant 4 

### Inlet Run 1 100912.411-1 35.6 35.6 100 3.6 Plant 4 Inlet Run 2 100912.412-1 52.4 52.4 100 5.2 Plant 4 Inlet Run 3 100912.413-1 49.8 49.8 100 5.0 Plant 4 Outlet Run 1 100912.401-1 56.6 56.6 100 5.7 Plant 4 

### Outlet Run 2 100912.402-1 50.7 50.7 100 5.1 Plant 4 Outlet Run 3 100912.403-1 43.2 43.2 100 4.3 Plant 5 Inlet Run 1 100912.511-1 54.6 54.6 100 5.5 Plant 5 Inlet Run 2 100912.512-1 62.1 62.1 100 6.2 Plant 5 Inlet Run 3 100912.513-1 60.8 60.8 100 6.1 Plant 5 Outlet Run 1 100912.501-1 5.5 5.5 100 < 

### 2.5 Plant 5 Outlet Run 2 100912.502-1 7.1 7.1 100 < 

### 2.5 Plant 5 Outlet Run 3 100912.503-1 -21.0 -21.0 100 < 

### 2.5

Page 16 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 546BORAL BRICKS


## BARIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 25 119/L Proj. #: 100912 

### Postdig'n spike cone. = 1000 119/L Date: 05-0ct-10 Sample ID Test Di9'te 

### DiPn Total 

### Volume Client FAL Sol'n Cone 

### FV Factor Volume 

### Di9'd Total 11g/L 119/L ml ml ml 

### 119 BACK HALVES Blank 1 00912.B-2A -42.5 -42.5 100 116 66 

### < 4.4 Salisbury Inlet Run 1 l00912.SAI1-2A -10.3 -10.3 100 324 224 

### < 3.6 Salisbury Inlet Run 2 100912.SAI2-2A 57.7 57.7 100 336 236 8.2 Salisbury Inlet Run 3 l00912.SAI3-2A 29.3 29.3 100 356 256 4.1 Salisbury Outlet Run 1 100912.SA01-2A 92.3 92.3 100 335 235 13.2 Salisbury Outlet Run 2 100912.SA02-2A 14.4 14.4 100 288 188 

### < 3.8 Salisbury Outlet Run 3 100912.SA03-2A 28.3 28.3 100 366 266 3.9 Plant 

### 4 Inlet Run 1 100912.41l-2A 5.3 5.3 100 333 233 

### < 3.6 Plant 

### 4 Inlet Run 2 100912.412-2A 104.5 104.5 100 339 239 14.8 Plant 4 Inlet Run 3 1 00912.413-2A 114.4 114.4 100 333 233 16.3 Plant 

### 4 Outlet Run 1 100912.401-2A -3.2 -3.2 100 324 224 

### < 3.6 Plant 4 Outlet Run 2 100912.402-2A 21.5 21.5 100 342 242 

### < 3.5 Plant 4 Outlet Run 3 100912.403-2A 126.7 126.7 100 323 223 18.4 Plant 5 Inlet Run 1 100912.51l-2A 66.9 66.9 100 339 239 9.5 Plant 5 Inlet Run 2 100912.512-2A -62.5 -62.5 100 351 251 

### < 3.5 Plant 5 Inlet Run 3 100912.513-2A 86.0 86.0 100 333 233 12.3 Plant 5 Outlet Run 1 100912.501-2A 19.8 19.8 100 350 250 

### < 3.5 Plant 5 Outlet Run 2 100912.502-2A 59.2 59.2 100 334 234 8.4 Plant 5 Outlet Run 3 100912.503-2A 48.7 48.7 100 329 229 7.0 FRONT SPIKE 100912.SA11-1S 1065.2 % REC = 85.2% BACK SPIKE l00912.411-2AS 972.7 

### % REC = 

### 97.3% FRONT DUP 100912.SAI2-1D 326.5 RPD = 4.0% 

### BACK DUP 100912.SAI2-2AD -0.1 RPD = N/A

Page 17 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 547I



### \ BORAL BRICKS



### BERYL 

## L I U M ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 0.5 J.lg/L Proj. 

### #: 100912 Postdig'n spike cone. 

## = 1000 J.lg/L Dote: 06-0ct-10 Sample ID Test 

### Dig'te Dil'n Total Volume Client FAL So/'n Cone 

### FV Factar Volume 

### Dig'd Total J.lg/L 

### flg/l ml ml ml 

### /19 

### FRONT HALVES Blank 100912.8-1 -0.62 -0.6 100 

### < 0.05 Salisbury Inlet Run 1 100912.SAI1-1 -0.42 -0.4 100 

### < 0.05 Salisbury Inlet Run 2 100912.SAI2-1 -0.35 -0.4 100 

### < 0.05 Salisbury Inlet Run 3 100912.SA13-1 -0.17 -0.2 100 

### < 0.05 Salisbury Outlet Run 1 100912.SA01-1 -0.95 -0.9 100 

### < 0.05 Salisbury Outlet Run 2 100912.SA02-1 -0.97 -1.0 100 

### < 0.05 Salisbury Outlet Run 3 100912.SA03-1 -0.70 -0.7 100 

### < 0.05 Plant4 Inlet Run 1 100912.411-1 -0.85 -0.8 100 

### < 0.05 Plant 4 Inlet Run 2 100912.412-1 -0.93 -0.9 100 

### < 0.05 Plant 4 Inlet Run 3 100912.413-1 -0.89 -0.9 100 

### < 0.05 Plant 4 Outlet Run 1 100912.401-1 -1.14 - 1. 1 100 

### < 0.05 Plant4 Outlet Run 2 100912.402-1 -1.08 -1.1 100 

### < 0.05 Plant 4 Outlet Run 3 100912.403-1 -1.12 -1.1 100 

### < 0.05 Plant 5 Inlet Run 1 100912.511-1 -0.86 -0.9 100 

### < 0.05 Plant 5 Inlet Run 2 100912.512-1 -1.10 -1.1 100 

### < 0.05 Plant 5 Inlet Run 3 100912.513-1 -0.93 -0.9 100 

### < 0.05 Plant 5 Outlet Run 1 100912.501-1 -0.88 -0.9 100 

### < 0.05 Plant 5 Outlet Run 2 100912.502-1 -1.15 -1.1 100 

### < 0.05 Plant 5 Outlet Run 3 100912 .503-1 -1.25 -1.3 100 

### < 0.05

Page 18ofl03 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PlANTS 4 & 5, SALISBURY PlANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 548BORAL BRICKS


## BERYLLIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analyfical Testing Consultants, Inc. 

### MDL= 0.5 J.lg/L Proj. #: 100912 

### Postdig'n spike cone. 

### = 1000 J.lg/L Dale: 06-0ct-1 0 Sample ID Test Dig'le Dil'n Total Volume 

### Client FAL Sol'n 

### Cone FV Factor Volume 

### Dig'd Total J.lg/L J.lg/L ml ml ml J.l9 BACK HALVES Blank 100912.B-2A -1.39 -1.4 100 116 66 

### < 0.09 Salisbury Inlet Run 1 100912.SA11-2A -1.35 -1.3 100 324 224 

### < 0.07 Salisbury Inlet Run 2 1 00912.SAI2-2A -1.40 -1.4 100 336 236 

### < 0.07 Salisbury Inlet Run 3 100912.SAI3-2A -1.80 -1.8 100 356 256 

### < 0.07 Salisbury Outlet Run 

### 1 100912.SA01-2A -1.95 -2.0 100 335 235 

### < 0.07 Salisbury Outlet Run 2 100912.SA02-2A -1.03 -1.0 100 288 188 

### < 0.08 Salisbury Outlet Run 3 

### 100912.SA03-2A -1.39 -1.4 100 366 266 

### < 0.07 Plant 4 Inlet Run 1 100912.411-2A 

### -l. 75 

### -1 .8 100 333 233 

### < 0.07 Plant 4 Inlet Run 2 100912.412-2A -0.84 -0.8 100 339 239 

### < 0.07 Plant4 Inlet Run 3 100912.413-2A -1.32 -1.3 100 333 233 

### < 0.07 Plant 

### 4 Outlet Run 

### 1 100912.401-2A -1.02 -1.0 100 324 224 

### < 0.07 Plant 4 Outlet Run 2 1 00912.402-2A -1.62 -1.6 100 342 242 

### < 0.07 Plant 4 Outlet Run 3 100912.403-2A -1.81 -1.8 100 323 223 

### < 0.07 Pia nt 5 Inlet Run 1 100912.511 -2A -1.27 -1.3 100 339 239 

### < 0.07 Plant 5 Inlet Run 2 100912.512-2A -1.78 -1.8 100 351 251 

### < 0.07 Plant 5 Inlet Run 3 100912.513-2A -0.80 -0.8 100 

### 333 233 

### < 0.07 Plant 5 Outlet Run 1 100912.501-2A -1.09 - 1 . 1 100 350 250 

### < 0.07 Plant 5 Outlet Run 2 100912.502-2A -1.61 -1.6 100 334 234 

### < 0.07 Plant 5 Outlet Run 3 100912.503-2A -1.67 -1.7 100 329 229 

### < 0.07 FRONT SPIKE 100912.SAI2-1S 834.62 % REC 

# = 83.5% BACK SPIKE 100912.411-2AS 880.80 % REC 

# = 88.1% FRONT DUP 100912.SA13-1 D -0.50 RPD = N/A BACK DUP 100912.SAI2-2AD -1.91 RPD = N/A

Page 19 of 103 ATC PROJECT No. P-1 0142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 549BORAL BRICKS


## CADMIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. MDL= 3 Jlg/L Proj. #: 

### 100912 Postdig'n spike cone. 

## = 1000 Jlg/L Date: 06-0ct- 10 Sample ID Test Dig'te Dil'n Total Volume 

### Client 

### FAL Sol'n 

### Cane 

### FY Factor Volume 

### Dig'd Total Jlg/L 1'9/L ml ml ml 

### Jig FRONT HALVES 

### Blank 100912.8-1 -38.92 -38.9 100 

### < 0.30 Salisbury Inlet Run 1 100912.SAI1- 1 -27.94 -27.9 100 < 

### 0.30 Salisbury Inlet Run 2 100912.SAI2- 1 -26.54 -26.5 100 < 

### 0.30 Salisbury Inlet Run 3 100912.SA13- 1 -44.27 -44.3 100 

### < 0.30 Salisbury Outlet Run 1 100912.SA01. 1 -36.72 -36.7 100 

### < 0.30 Salisbury Outlet Run 2 100912.SA02- 1 -37.63 -37.6 100 

### < 0.30 Salisbury Outlet Run 3 100912.SA03- 1 -36.61 -36.6 100 

### < 0.30 Plant 4 Inlet Run 1 100912.411 "1 -41.66 -41.7 100 

### < 0.30 Plant 4 In lei Run 2 100912.412-1 -44.94 -44.9 100 < 

### 0.30 Plant 4 Inlet Run 3 100912.413-1 -42.41 -42.4 100 < 

### 0.30 Plant 4 Outlet Run 1 100912.401-1 -44.19 -44.2 100 < 

### 0.30 Plant 4 Outlet Run 2 100912.402-1 -43.86 -43.9 100 < 

### 0.30 Plant 4 Outlet Run 3 100912.403-1 -44.36 -44.4 100 < 

### 0.30 Plant 5 Inlet Run 1 100912.511-1 -36.73 -36.7 100 

### < 0.30 Plant 5 Inlet Run 2 100912.512-1 -48.43 -48.4 100 < 

### 0.30 Plant 5 Inlet Run 3 100912.513-1 -41.93 -41.9 100 

### < 0.30 Planl 5 Outlet Run 1 100912.501 "1 -42.34 -42.3 100 

### < 0.30 Plant 5 Outlet Run 2 100912.502-1 -49.68 -49.7 100 

### < 0.30 Plant 5 Outlet Run 3 100912.503-1 -45.39 -45.4 100 

### < 0.30

Page 20 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 550

## ( BORAL BRICKS


## CADMIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 3 119/L Proj. 

### #: 100912 Postdig'n spike cone. = 

### 1000 119/L Dote: 06-0ct-1 0 Sample ID Test Di9'te 

### Dil'n Total Volume Client 

### FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total 

### 119/L 119/L ml ml ml 119 

### BACK HALVES Blank 100912.8-2A -5.75 -5.7 100 116 66 

### < 0.53 Salisbury Inlet Run 

### 1 100912.SAl1-2A -5.40 -5.4 100 324 224 

### < 0.43 Salisbury Inlet Run 2 100912.SAl2-2A -3.08 -3.1 100 336 236 

### < 0.43 Salisbury Inlet Run 3 100912.SAl3-2A -0.69 -0.7 100 356 256 

### < 0.42 Salisbury Outlet Run 

### 1 100912.SA01-2A -0.15 -0.1 100 335 235 

### < 0.43 Salisbury Outlet Run 2 100912.SA02-2A -0.71 -0.7 100 288 188 

### < 0.46 Salisbury Outlet Run 3 100912.SA03-2A 0.05 0.1 100 366 266 

### < 0.41 Plant 

### 4 Inlet Run 1 

### 100912.411-2A -0.48 -0.5 100 333 233 

### < 0.43 Plant 

### 4 Inlet Run 2 1 00912.412-2A 0.00 0.0 100 339 239 

### < 0.43 Plant 

### 4 Inlet Run 3 

### 100912.413-2A 1.47 1.5 100 333 233 

### < 0.43 Plant 

### 4 Outlet Run 1 100912.401-2A 1.40 1.4 100 324 224 

### < 0.43 Plant 4 Outlet Run 2 100912 .402-2A 0.36 

### 0.4 100 342 242 

### < 0.42 Plant 

### 4 Outlet Run 3 100912.403-2A 0.20 0.2 100 323 223 

### < 0.43 Plant 5 Inlet Run 1 100912.511-2A -1.10 -1.1 100 339 239 

### < 0.43 Plant 5 Inlet Run 2 100912.512-2A -0.59 -0.6 100 351 251 

### < 0.42 Plant 5 Inlet Run 3 100912.513-2A 0.61 0.6 100 333 233 

### < 0.43 Plant 5 Outlet Run 1 100912.501-2A 2.39 2.4 100 350 250 

### < 0.42 Plant 5 Outlet Run 2 100912.502-2A 0.57 0.6 100 334 234 

### < 0.43 Plant 5 Outlet Run 3 100912.503-2A 2.05 2.1 100 329 229 

### < 0.43 FRONT SPIKE 100912.SAI2-1S 776.31 % REC 

# = 77.6% BACK SPIKE 100912.411-2AS 885.57 % REC 

# = 88.6% FRONT DUP 100912.SA13-1 D -44.67 RPD 

# = N/A BACK DUP 100912.SAI2-2AD -2.55 RPD = N/A

Page 21 of 103 ATC PROJECT No.**P~** 10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 551BORAL BRICKS


## CHROMIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. MDL= 5 pg/L Proj. #: 100912 Postdig'n spike cone. = 

### 1000 pg/L Date: 05-0ct-1 0 Sample ID Test Dig'te 

### Diljn 

### Total Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total pg/l pg/L ml ml ml J.l9 

### FRONT HALVES 

### Blank 100912.8-1 20.8 20.8 100 2.1 Salisbury Inlet Run 1 100912.SAI1-1 16.9 16.9 100 1.7 Salisbury Inlet Run 2 100912.SAI2-1 23.8 23.8 100 2.4 Salisbury Inlet Run 3 100912.SAI3-1 24.1 24.1 100 2.4 Salisbury Outlet Run 1 100912.SA01-1 16.4 16.4 100 1.6 Salisbury Outlet Run 2 100912.SA02-1 13.4 13.4 100 1 1.3 Salisbury Outlet Run 3 100912.SA03-1 14.2 14.2 100 1 1.4 Plant 4 Inlet Run 1 100912.411-1 24.2 24.2 100 2.4 Plant 4 Inlet Run 2 100912.412-1 21.6 21.6 100 2.2 Plant4 Inlet Run 3 100912.413-1 22.7 22.7 100 2.3 Plant 4 Outlet Run 1 100912.401-1 21.6 21.6 100 2.2 Plant 4 Outlet Run 2 100912.402-1 22.3 

### 22.3 100 2.2 Pia nt 4 Outlet Run 3 100912.403-1 27.0 27.0 100 2.7 Plant 5 Inlet Run 1 100912.511-1 16.4 16.4 100 1.6 Plant 5 Inlet Run 2 100912.512-1 18.9 18.9 100 1.9 Plant 5 Inlet Run 3 100912.513-1 20.3 20.3 100 2.0 Plant 5 Outlet Run 1 100912.501-1 20.1 20.1 100 2.0 Plant 5 Outlet Run 2 100912.502-1 16.3 16.3 100 1.6 Plant 5 Outlet Run 3 100912.503-1 16.2 16.2 100 1.6

Page 22 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 552BORAL BRICKS 

## CHROMIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 5 Jlg/L Proj. #: 100912 Postdig 1

### n spike cone. = 

### 1000 Jlg/L Dale: 05-0ct-10 Sample ID Test Dig'te 

### Di1 1 

### n 

### Total Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total Jlg/L Jlg/L ml ml ml 

### Jlg BACK HALVES Blank 100912.B-2A 0.1 0.1 100 116 66 

### < 0.9 Salisbury Inlet Run 1 100912.SAI1-2A 22.3 22.3 100 324 224 3.2 Salisbury Inlet Run 2 100912.SA12-2A 12.5 12.5 100 336 236 1.8 Salisbury Inlet Run 3 100912.SA13-2A 5.5 5.5 100 356 256 0.8 Salisbury Outlet Run 1 100912.SA01-2A 21.9 21.9 100 335 235 3.1 Salisbury Outlet Run 2 100912.SA02-2A 3.3 3.3 100 288 188 

### < 0.8 Salisbury Outlet Run 3 100912.SA03-2A 2.1 2.1 100 366 266 

### < 0.7 Planl4 Inlet Run 1 100912.411-2A 14.9 14.9 100 333 233 2.1 Plant 4 Inlet Run 2 100912.412-2A 19.3 19.3 100 339 239 2.7 Plant 4 Inlet Run 3 100912.413-2A 9.8 9.8 100 333 233 1.4 Plant 4 Outlet Run 1 100912.401-2A 4.9 4.9 100 324 224 

### < 0.7 Plant 4 Outlet Run 2 100912.402-2A 1.6 1.6 100 342 242 

### < 0.7 Plant 4 Outlet Run 3 100912.403- 2A 4.3 4.3 100 323 223 

### < 0.7 Plant 5 Inlet Run 1 100912.5ll-2A 21 .1 21.1 100 339 239 3.0 Plant 5 Inlet Run 2 100912.512-2A 8.8 8.8 100 351 251 1.2 Plant 5 Inlet Run 3 100912.513-2A 3.9 3.9 100 333 233 

### < 0.7 Plant 5 Outlet Run 1 100912.501-2A 3.2 3.2 100 350 250 

### < 0.7 Plant 5 Outlet Run 2 100912.502-2A 2.7 2.7 100 334 234 

### < 0.7 Plant 5 Outlet Run 3 100912.503-2A 3.0 3.0 100 329 229 < 

### 0.7 FRONT SPIKE 100912.SA12-1 964.7 

### % REC

**~** 

### 94.1% BACK SPIKE 1 00912.SA12-2A 781.2 % REC

**~** 

### 76.9% FRONT DUP 100912.SAI3- 1 25.3 RPD = 4.8% BACK DUP 100912.SAI3-2A 4.8 RPD = N/A

Page 23 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 553BORAL BRICKS


## COBALT GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: 

### Analytical Testing Consultants, Inc. MDL= 3 /lg/L Proj. 

### #: 100912 

### Postdig'n spike cone. = 

### 100 /19/L Date: 07-Oct-1 0 Sample ID Test Dig'te Dil'n Total Volume 

### Client FAL Sol'n Cone 

## FV Factor Volume 

### Dig'd Total 119/L pg/L ml ml ml 

### 119 

### FRONT HALVES Blank 100912.8-1 0.7 0.7 100 

### < 0.3 Salisbury Inlet Run 1 100912.SAI1-1 -0.7 -0.7 100 

### < 0.3 Salisbury Inlet Run 2 1 00912.SAI2- 1 0.0 0.0 100 

### < 0.3 Salisbury Inlet Run 3 100912.SA13-1 0.4 0.4 100 

### < 0.3 Salisbury Outlet Run 1 100912.SA01-1 -0.4 -0.4 100 

### < 0.3 Salisbury Outlet Run 2 100912.SA02-1 -1.2 -1.2 100 1 

### < 0.3 Salisbury Outlet Run 3 100912.SA03-1 -1.0 -1.0 100 1 

### < 0.3 Plant 4 Inlet Run 1 100912.411-1 -0.2 -0.2 100 

### < 0.3 Plant 4 Inlet Run 2 100912.412-1 0.1 0.1 100 

### < 0.3 Plant 4 Inlet Run 3 100912.413-1 -0.4 -0.4 100 

### < 0.3 Plant 4 Outlet Run 1 100912.401-1 -0.8 -0.8 100 

### < 0.3 Plant 4 Outlet Run 2 100912.402-1 -0.3 -0.3 100 

### < 0.3 Plant 4 Outlet Run 3 100912.403-1 -1.0 -1.0 100 

### < 0.3 Plant 5 Inlet Run 1 100912.511-1 0.5 0.5 100 

### < 0.3 Plant 5 Inlet Run 2 100912.512-1 -1.5 -1.5 100 

### < 0.3 Plant 5 Inlet Run 3 100912.513-1 -1.5 -1.5 100 

### < 0.3 Plant 5 Outlet Run 1 100912.501-1 -2.2 -2.2 100 

### < 0.3 Plant 5 Outlet Run 2 100912.502-1 -0.1 -0.1 100 1 

### < 0.3 Plant 5 Outlet Run 3 100912.503-1 0.1 0.1 100 1 

### < 0.3

Page 24 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 554BORAL BRICKS


## COBALT GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 3 Jig/L Proj. 

### #: 100912 Postdig'n spike cone. = 

### 100 JIQ/l Dale: 07-0ct-10 Sample ID Test Dig'fe 

### Dil'n Tolal Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Toto! Jig/L Jig/l ml ml ml 

### Jig 

### BACK HALVES Blank 100912.B-2A -0.6 -0.6 100 1 116 66 

### < 0.5 Salisbury Inlet Run 1 100912.SA11-2A -1.3 -39.6 100 30 324 224 

### < 13.0 Salisbury Inlet Run 2 100912.SAI2-2A 1.2 1.2 100 336 236 

### < 0.4 Salisbury Inlet Run 3 100912.SAI3-2A 0.0 0.0 100 356 256 

### < 0.4 Salisbury Outlet Run 1 100912.SA01-2A 1.1 1.1 100 335 235 

### < 0.4 Salisbury Outlet Run 2 100912.SA02-2A 0.6 0.6 100 288 188 

### < 0.5 Salisbury Outlet Run 3 100912.SA03-2A -0.2 -0.2 100 366 266 

### < 0.4 Plant 4 Inlet Run 1 100912.411-2A 0.3 0.3 100 333 233 

### < 0.4 Plant 4 Inlet Run 2 100912.412-2A 0.2 0.2 100 339 239 

### < 0.4 Plant 4 Inlet Run 3 100912.413-2A 0.0 0.0 100 1 333 233 

### < 0.4 Pion! 4 Outlet Run 1 100912.401-2A 15.8 15.8 100 1 324 224 2.3 Plant 4 Outlet Run 2 100912.402-2A 7.5 7.5 100 342 242 1.1 Plant 4 Outlet Run 3 100912.403-2A 5.4 5.4 100 323 223 0.8 Plant 5 Inlet Run 1 

### 100912.511-2A -1.2 -1.2 100 339 239 

### < 0.4 Plant 5 Inlet Run 2 100912.512-2A -3.0 -3.0 100 351 251 

### < 0.4 Plant 5 inlet Run 3 100912.513-2A -1.4 -1.4 100 333 233 

### < 0.4 Plant 5 Outlet Run 1 100912.501-2A 0.4 0.4 100 350 250 

### < 0.4 Plant 5 Outlet Run 2 100912.502-2A 0.5 0.5 100 334 234 

### < 0.4 Pion! 5 Outlet Run 3 100912.503-2A -1.4 -1.4 100 329 229 

### < 0.4 FRONT SPIKE 100912.SAI1-1 82.1 % REC 

### = 82.1% BACK SPIKE 100912.SAI1-2A 78.3 % REC 

### = 78.3%

Page 25 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 555BORAL BRICKS


### COPPER ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. 

### MDL= 5 pg/l Proj. #: 100912 Postdig'n spike cone. = 

### 1000 pg/l Date: 05-0ct-1 0 Sample ID Test Dig'le Dil'n 

### Total Volume Client 

### FAL Sol'n Cone 

### FV Foetor Volume 

### Dig'd Total pg/l pg/l ml ml ml /19 

### FRONT HALVES 

### Blank 100912.8-1 1.8 1.8 100 

### < 0.5 Salisbury Inlet Run 1 100912.SAI1-1 53.2 53.2 100 5.3 Salisbury Inlet Run 2 100912.SAI2-1 52.6 52.6 100 5.3 Salisbury Inlet Run 3 100912.SA13-1 48.1 48.1 100 4.8 Salisbury Outlet Run 1 100912.SA01-1 2.2 2.2 100 1 

### < 0.5 Salisbury Outlet Run 2 100912.SA02-1 3.3 3.3 100 1 

### < 0.5 Salisbury Outlet Run 3 100912.SA03-1 2.9 2.9 100 

### < 0.5 Plant 4 Inlet Run 1 100912.411-1 3.1 3.1 100 

### < 0.5 Plant 4 Inlet Run 2 100912.412-1 1.5 1.5 100 

### < 0.5 Plant 4 Inlet Run 3 100912.413-1 2.1 2.1 100 

### < 0.5 Plant 4 Outlet Run 1 100912.401-1 4.2 4.2 100 

### < 0.5 Plant 4 Outlet Run 2 100912 .402-1 2.4 2.4 100 

### < 0.5 Plant 4 Outlet Run 3 100912.403-1 3.2 3.2 100 

### < 0.5 Plant 5 Inlet Run 1 100912.511-1 8.2 8.2 100 0.8 Plant 5 Inlet Run 2 100912.512-1 7.6 7.6 100 0.8 Plant 5 Inlet Run 3 100912.513-1 7.9 7.9 100 0.8 Plant 5 Outlet Run 1 100912.501-1 1.7 1.7 100 

### < 0.5 Plant 5 Outlet Run 2 100912.502-1 2.6 2.6 100 

### < 0.5 Plant 5 Outlet Run 3 100912.503-1 2.8 2.8 100 

### < 0.5

Poge 26 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 556BORAL BRICKS


## COPPER ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 5 pg/l Proj. 

### #: 100912 Posfdig'n spike cone. 

### = 1000 pg/L Dale: 05-0cl-1 0 Sample ID Test Dig'te 

### Dil'n Total Volume 

### Client FAL Sol'n Cone 

## FV Fodor Volume 

### Dig'd Total Jlg/l Jlg/l ml ml ml 

### Jlg BACK HALVES Blank 100912.B-2A 1.4 1.4 100 116 66 

### < 0.9 Salisbury Inlet Run 1 100912.SAI1-2A 26.5 26.5 100 324 224 3.8 Salisbury Inlet Run 2 100912.SAI2-2A 14.6 14.6 100 336 236 2.1 Salisbury Inlet Run 3 100912.SA13-2A 16.5 16.5 100 356 256 2.3 Salisbury Outlet Run 1 100912.SA01-2A 6.3 6.3 100 335 235 0.9 Salisbury Outlet Run 2 100912.SA02-2A 8.3 8.3 100 288 188 1.3 Salisbury Outlet Run 3 1 00912.SA03-2A 11.1 11.1 100 366 266 1.5 Plant 4 Inlet Run 1 100912.411-2A 6.7 6.7 100 333 233 1.0 Plant4 Inlet Run 2 100912.412-2A 7.7 7.7 100 339 239 1.1 Plant 4 Inlet Run 3 100912.413-2A 5.7 5.7 100 333 233 0.8 Plant 4 Outlet Run 1 100912.401-2A 10.1 10.1 100 324 224 1.5 Plant 4 Outlet Run 2 100912.402 -2A 4.1 4.1 100 342 242 

### < 0.7 Plant 4 Outlet Run 3 100912.403-2A 14.2 14.2 100 323 223 2.1 Plant 5 Inlet Run 1 100912.511-2A 8.0 8.0 100 339 239 1.1 Plant 5 Inlet Run 2 100912.512-2A 6.3 6.3 100 351 251 0.9 Plant 5 Inlet Run 3 100912.513-2A 8.9 8.9 100 333 233 1.3 Plant 5 Outlet Run 1 100912.501-2A 12.3 12.3 100 350 250 1.7 Plant 5 Outlet Run 2 100912.502-2A 10.8 10.8 100 334 

### 234 1.5 Plant 5 Outlet Run 3 100912.503-2A 10.3 10.3 100 329 229 1.5 FRONT SPIKE 100912.SAI2-1 1046.5 %REC = 

### 99.4% BACK SPIKE 100912.SAI2-2A 834.8 % REC 

### = 82.0% FRONT DUP 100912.SA13-1D 49.0 RPD 

### = 1.8% BACK DUP 100912.SAI3-2AD 18.1 RPD = N/A

Page 27 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 557BORAL BRICKS


### LEAD GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc.**MDL~** 

### 5 J.lg/l Proj. #: 100912**Postdig~n** spike cone. 

### = 

### 100 J.lg/l Date: 

### 06-0ct-1 0 Sample ID Test 

### Dig'te Dil'n 

### Total Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total J.lg/L J.lg/L ml ml ml 

### 119 FRONT HALVES 

### Blank 100912.8-1 2.2 2.2 100 

### < 0.5 Salisbury Inlet Run 1 100912.SA11- 1 86.6 86.6 100 8.7 Salisbury Inlet Run 2 100912.SAI2-1 79.5 79.5 100 

### 7.9 Salisbury Inlet Run 3 100912.SAI3-1 71.1 71.1 100 7.1 Salisbury Outlet Run 1 

### l00912.SA01-1 2.2 2.2 100 

### < 0.5 Salisbury Outlet Run 2 100912.SA02-1 1.7 1.7 100 

### < 0.5 Salisbury Outlet Run 3 100912.SA03-1 2.6 2.6 100 

### < 0.5 Plant 4 Inlet Run 1 100912.411-1 1.8 1.8 100 

### < 0.5 Plant 4 Inlet Run 2 100912.412-1 1.4 1.4 100 

### < 0.5 Plant 4 Inlet Run 3 100912.413-1 2.1 2.1 100 

### < 0.5 Plant 4 Outlet Run 1 100912.401-1 4.0 4.0 100 

### < 0.5 Plant 4 Outlet Run 2 100912.402-1 3.0 3.0 100 

### < 0.5 Plant 4 Outlet Run 3 100912.403-1 3.0 3.0 100 

### < 0.5 Plant 5 Inlet Run 1 

### 100912.511-1 7.8 7.8 100 0.8 Plant 5 Inlet Run 2 100912.512-1 6.3 6.3 100 0.6 Plant 5 Inlet Run 3 100912.513-1 5.5 5.5 100 0.6 Plant 5 Outlet Run 1 100912.501-1 4.3 4.3 100 < 

### 0.5 Plant 5 Outlet Run 2 100912.502-1 1.3 1.3 100 < 

### 0.5 Plant 5 Outlet Run 3 100912.503-1 

### 2.9 2.9 100 

### < 0.5

Page 28 of 103 ATC PROJECT No.**P~10142** EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 558BORAL BRICKS


## LEAD GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 5 pg/L Proj. 

### #: 100912 Postdig'n spike cone. 

### == 100 pg/L Date: 06-0ct-10 Sample ID Test Dig'te Dil'n Total Volume 

### Client FAL Sol'n Cone 

## FV Factor Volume 

### Dig'd Total f!g/L pg/L ml ml ml fl9 

### BACK HALVES Blank 100912.B-2A 1.7 1.7 100 116 66 

### < 0.9 Salisbury Inlet Run 1 100912.SA11-2A 17.3 17.3 100 324 224 2.5 Salisbury Inlet Run 2 100912.SAI2-2A 5.3 5.3 100 336 236 0.8 Salisbury Inlet Run 3 100912.SAI3-2A -3.8 -3.8 100 356 256 

### < 0.7 Salisbury Outlet Run 1 100912.SA01-2A 3.5 3.5 100 335 235 

### < 0.7 Salisbury Outlet Run 2 100912.SA02-2A 0.7 0.7 100 28B 188 

### < 0.8 Salisbury Outlet Run 3 100912.SA03-2A 2.3 2.3 100 366 266 

### < 0.7 Plant 4 Inlet Run 1 100912.411-2A 3.2 3.2 100 333 233 

### < 0.7 Plant 4 Inlet Run 2 100912.412-2A 7.5 7.5 100 339 239 1.1 Plant 4 Inlet Run 3 100912.413-2A 2.7 2.7 100 333 233 

### < 0.7 Plant 4 Outlet Run 1 100912.401-2A 4.6 4.6 100 324 224 

### < 0.7 Plant 4 Outlet Run 2 100912.402-2A 1.9 1.9 100 342 242 

### < 0.7 Plant 

### 4 Outlet Run 3 100912.403-2A 5.9 5.9 100 323 223 0.8 Plant 5 Inlet Run 1 100912.511-2A 9.4 9.4 100 339 239 1.3 Plant 5 Inlet Run 2 100912.512-2A 4.7 4.7 100 351 251 

### < 0.7 Plant 5 Inlet Run 3 100912.513-2A 2.7 2.7 100 333 233 

### < 0.7 Plant 5 Outlet Run 1 1 00912.501-2A 6.3 6.3 100 350 250 0.9 Plant 5 Outlet Run 2 100912.502-2A 3.7 3.7 100 334 234 

### < 0.7 Plant 5 Outlet Run 3 100912.503-2A 5.3 5.3 100 329 229 0.8 FRONT SPIKE 100912.SA11-1 177.5 % REC; 90.9% BACK SPIKE 100912.SAI1-2A 111.8 % REC; 94.5%

Page 29 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 559BORAL BRICKS


## MAGNESIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 5 pg/L Proj. #: 100912 Postdig'n spike cone. 

### = 1000 pg/L Date: 06-0ct- 10 Sample ID Test 

### Dig'te 

### Dil'n Total Volume 

### Client FAL Sol'n Cane 

### FV Factor Volume Dig'd Total pg/L pg/L ml ml ml pg 

### FRONT HALVES Blank 100912.8-1 128.8 128.8 100 12.9 Salisbury Inlet Run 1 100912.SA11- 1 367.5 367.5 100 36.7 Salisbury Inlet Run 2 100912.SAI2-1 458.4 458.4 100 45.8 Salisbury Inlet Run 3 100912.SA13-1 507.7 507.7 100 50.8 Salisbury Outlet Run 1 100912.SA01-1 114.7 114.7 100 11.5 Salisbury Outlet Run 2 100912.SA02-1 115.7 115.7 100 11.6 Salisbury Outlet Run 3 100912.SA03-1 119.5 119.5 100 12.0 Plant 4 Inlet Run 1 100912.411-1 186.0 186.0 100 18.6 Plant 4 Inlet Run 2 100912.412-1 157.2 157.2 100 15.7 Plant 4 Inlet Run 3 100912.413-1 141.5 141.5 100 1 14.1 Plant 4 Outlet Run 1 100912.401-1 188.5 188.5 100 1 18.9 Plant 4 Outlet Run 2 100912.402-1 185.5 185.5 100 18.6 Plant 4 Outlet Run 3 100912.403-1 191.2 191.2 100 19.1 Plant 5 Inlet Run 1 100912.511-1 305.2 305.2 100 30.5 Plant 5 Inlet Run 2 100912.512-1 303.5 303.5 100 30.4 Plant 5 Inlet Run 3 100912.513-1 229.1 229.1 100 22.9 Plant 5 Outlet Run 1 100912.501-1 216.2 216.2 100 21.6 Plant 5 Outlet Run 2 100912.502-1 209.9 209.9 100 21.0 Plant 5 Outlet Run 3 100912.503-1 243.6 243.6 100 24.4

Page 30 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 560BORAL BRICKS


## MAGNESIUM ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 5 )lg/l Proj. #: 100912 

### Postdig'n spike cone. 

## = 1000 )lg/l Dote: 06-0ct-1 0 Sample ID Test Dig'te Dil'n 

### Total Volume Client FAL Sol'n Cone 

### FV Foetor Volume 

### Dig'd Total )lg/l )lg/l ml ml ml 

### Jlg 

### BACK HALVES Blank 100912.B-2A 16.6 16.6 100 116 66 2.9 Salisbury Inlet Run 1 1 00912.SAI1-2A 915.1 915.1 100 324 224 132.4 Salisbury Inlet Run 2 100912.SAI2-2A 286.5 286.5 100 336 236 40.8 Salisbury Inlet Run 3 100912.SAI3-2A 896.7 896.7 100 356 256 124.7 Salisbury Outlet Run 1 100912.SA01-2A 32.3 32.3 100 335 235 4.6 Salisbury Outlet Run 2 100912.SA02-2A 47.3 47.3 100 288 188 7.2 Salisbury Outlet Run 3 100912.SA03-2A 44.1 44.1 100 366 266 6.1 Plant 4 Inlet Run 1 100912.411-2A 742.8 1485.6 100 2 333 233 212.3 Plant 4 Inlet Run 2 100912.412-2A 1714.2 1714.2 100 339 239 243.1 Plant 4 Inlet Run 3 100912.413-2A 882.8 882.8 100 333 233 126.2 Plant 4 Outlet Run 1 100912.401-2A 86.7 86.7 100 324 224 12.5 Plant 4 Outlet Run 2 100912.402-2A 78.8 78.8 100 342 242 11.1 Plant 4 Outlet Run 3 100912.403-2A 141.7 141.7 100 323 223 20.5 Plant 5 Inlet Run 1 100912.511-2A 2035.4 2035.4 100 339 239 288.7 Plant 5 Inlet Run 2 100912.512-2A 789.6 789.6 100 351 251 110.4 Plant 5 Inlet Run 3 100912.513-2A 815.7 815.7 100 333 233 116.6 Plant 5 Outlet Run 1 100912.501-2A 71.8 71.8 100 350 250 10.1 Plant 5 Outlet Run 2 100912.502-2A 1100.4 1100.4 100 334 234 157.1 Plant 5 Outlet Run 3 100912.503-2A 584.4 584.4 100 329 229 84.0 FRONT SPIKE 100912.411-1S 1029.6 % REC 

### = 84.4% BACK SPIKE 100912.411-2AS 1683.6 % REC 

### = 94.1% FRONT DUP 100912.412-1 D 156.8 RPD = 0.2% BACK DUP 100912.412-2AD 1744.6 RPD = 1.8%

Page 3l of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 561BORAL BRICKS


## MANGANESE ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 2 pg/L Proj. 

### #: 100912 

### Posfdig'n spike cone. 

## = 1000 pg/L 

### Date: 05-0ct-10 Sample ID Test Dig'te Dil 1 n 

### Total Volume 

### Client FAL 

### Sol'n Cone 

### FV Factor Volume 

### Dig'd Total pg/L pg/L ml ml ml 

## pg FRONT HALVES Blank 100912.8-1 10.9 10.9 100 1 1.1 Salisbury Inlet Run 1 100912.SAI1-1 118.2 118.2 100 11.8 Salisbury Inlet Run 2 l00912.SAI2-1 121.2 121.2 100 12.1 Salisbury Inlet Run 3 100912.SA13-1 123.0 123.0 100 12.3 Salisbury Outlet Run 1 100912.SA01-1 15.8 15.8 100 1.6 Salisbury Oullet Run 2 100912.SA02-1 13.5 13.5 100 1.3 Salisbury Outlet Run 3 100912.SA03-1 19.4 19.4 100 1.9 Plan! 4 Inlet Run 1 100912.411-1 13.0 13.0 100 1 1.3 Plan! 4 Inlet Run 2 100912.412-1 12.0 12.0 100 1 1.2 Plant 4 Inlet Run 3 100912.413-1 14.9 14.9 100 1.5 Plant 4 Outlet Run 1 100912.401-1 12.9 12.9 100 

### 1.3 Plant 4 Outlet Run 2 100912.402-1 11.8 

### 11.8 100 1.2 Plant 4 Outlet Run 3 100912.403-1 12.5 12.5 100 1.3 Plant 5 Inlet Run 1 100912.511-1 53.6 53.6 100 5.4 Plan! 5 Inlet Run 2 100912.512-1 61.7 61.7 100 1 6.2 Plant 5 Inlet Run 3 100912.513-1 36.2 36.2 100 1 3.6 Plant 5 Outlet Run 1 100912.501-1 19.4 19.4 100 1.9 Plant 5 Outlet Run 2 100912.502-1 20.5 20.5 100 2.0 Plan! 5 Oullet Run 3 100912.503-1 22.9 22.9 100 2.3

Page 32 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 562BORAL BRICKS


## MANGANESE ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 2 IJg/L Pro;.#: 100912 

### Postdig'n spike cone. 

## = 1000 IJg/L Date: 05-0ct-10 Sample ID Test Dig'te 

### Dil'n Total Volume Client FAL Sol'n Cone 

### FV Foetor Volume 

### Dig'd Toto! IJg/L IJg/L ml ml ml 

### 119 BACK HALVES Blank 100912.B-2A 1.0 1.0 100 116 66 

### < 0.4 Salisbury Inlet Run 1 100912.SAI1-2A 150.5 150.5 100 324 224 21.8 Salisbury Inlet Run 2 100912.SA12-2A 44.7 44.7 100 336 236 6.4 Salisbury Inlet Run 3 100912.SA13-2A 44.4 44.4 100 356 256 6.2 Salisbury Outlet Run 

### 1 100912.SA01-2A 10.1 I 0.1 100 335 235 1.4 Salisbury Outlet Run 2 100912.SA02-2A 14.4 14.4 100 288 188 2.2 Salisbury Outlet Run 3 100912.SA03-2A 80.2 80.2 100 366 266 11.0 Plant 4 Inlet Run 1 100912.411-2A 31.8 31.8 100 333 233 4.6 Plant 4 Inlet Run 2 100912.412-2A 32.9 32.9 100 339 239 4.7 Plant 4 Inlet Run 3 100912.413-2A 16.1 16.1 100 333 233 2.3 Plant 4 Oullet Run 

### 1 100912.401-2A 17.9 17.9 100 324 224 2.6 Plant 4 Oullet Run 2 100912.402-2A 8.4 8.4 100 342 242 1.2 Plant 4 Outlet Run 3 100912.403-2A 17.9 17.9 100 323 223 2.6 Plant 5 Inlet Run 

### 1 100912.511-2A 179.0 179.0 100 339 239 25.4 Plant 5 Inlet Run 2 100912.512-2A 20.7 20.7 100 351 251 2.9 Plant 5 Inlet Run 3 I 00912.513-2A 25.5 25.5 100 333 233 3.6 Plant 5 Outlet Run 1 100912.501-2A 12.1 12.1 100 350 250 1.7 Plant 5 Outlet Run 2 100912.502-2A 108.7 108.7 100 334 234 15.5 Plant 5 Outlet Run 3 100912.503-2A 11.6 11.6 100 329 229 1.7 FRONT SPIKE 100912.SAI2-1 1042.7 % REC 

### = 92.1% BACK SPIKE 100912.SAI2-2A 807.0 % REC 

### = 76.2% FRONT DUP I 00912.SA13-1 D 125.3 RPD = 

### 1.9% BACK DUP 1 00912.SAI3-2AD 47.2 RPD = 

### 6.3%

Page 33 af l 03 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 563BORAL BRICKS


## NICKEL ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: 

### Analytical Testing Consultants, Inc. MDL= 3 119/l Proj. #: 100912 Postdig*n spike cone. 

## = 1000 119/l Dote: 05-0ct-1 0 Sample ID Test 

### Dig'te Dil'n 

### Total Volume 

### Client FAL Sol'n Cone FV 

### Foetor Volume 

### Dig'd Total 119/L 119/L ml ml ml 119 

### FRONT HALVES Blank 100912.8-1 6.4 6.4 100 0.6 Salisbury Inlet Run 1 100912.SA11-1 5.6 5.6 100 0.6 Salisbury Inlet Run 2 100912.SAI2-1 8.7 8.7 100 0.9 Salisbury Inlet Run 3 100912.SAI3-1 9.9 9.9 100 1.0 Salisbury Outlet Run 1 100912.SA01-1 6.6 6.6 100 0.7 Salisbury Outlet Run 2 1 00912.SA02-1 6.7 6.7 100 0.7 Salisbury Outlet Run 3 100912.SA03-1 8.1 8.1 100 0.8 Plant 

### 4 Inlet Run 1 100912.411-1 17.4 17.4 100 1.7 Plant 

### 4 Inlet Run 2 100912.412-1 10.1 10.1 100 1.0 Plant 

### 4 Inlet Run 3 100912.413-1 13.7 13.7 100 1.4 Plant 

### 4 Outlet Run 1 100912.401-1 11.2 11.2 100 1.1 Plant 

### 4 Outlet Run 2 100912.402-1 12.6 12.6 100 1.3 Plant4 Outlet Run 3 100912.403-1 16.4 16.4 100 1.6 Plant 5 Inlet Run 1 100912.511-1 11.0 11.0 100 1 . 1 Plant 5 Inlet Run 2 100912.512-1 14.5 14.5 100 1.4 Plant 5 Inlet Run 3 100912.513-1 10.3 10.3 100 1.0 Plant 5 Outlet Run 1 100912.501-1 8.5 8.5 100 0.8 Plant 5 Outlet Run 2 100912.502-1 9.1 9.1 100 0.9 Plant 5 Outlet Run 3 100912.503-1 10.7 10.7 100 1 . 1

Page 34 of l 03 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 564BORAL BRICKS


## NICKEL ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 3 pg/l Proj. #: 100912 Postdig'n spike cone. = 

### 1000 pg/l Date: 05-0ct-1 0 Sample ID Test Dig'te 

### Dil'n Total Volume 

### Client FAl Sol'n Cone 

## FV Factor Volume 

### Dig'd Total pg/l pg/l ml ml ml !19 

### BACK HALVES Blank 100912.B-2A 1.5 1.5 100 116 66 < 

### 0.5 Salisbury Inlet Run 1 100912.SA11-2A 124.3 124.3 100 324 224 18.0 Salisbury Inlet Run 2 100912.SAI2-2A 24.5 24.5 100 336 236 3.5 Salisbury Inlet Run 3 100912.SAI3-2A 32.5 32.5 100 356 256 4.5 Salisbury Outlet Run 1 1 00912.SA01-2A 114.5 114.5 100 335 235 16.3 Salisbury Outlet Run 2 100912.SA02-2A 12.9 12.9 100 288 188 2.0 Salisbury Outlet Run 3 100912.SA03-2A 9.9 9.9 100 366 266 1.4 Plant 

### 4 Inlet Run 1 100912.411-2A 9.4 9.4 100 333 233 1.3 Plant 

### 4 Inlet Run 2 100912.412-2A 15.8 15.8 100 339 239 2.2 Plant 4 Inlet Run 3 100912.413-2A 12.8 12.8 100 333 233 1.8 Plant 

### 4 Outlet Run 1 100912.401-2A 11.7 11.7 100 324 224 1.7 Plant 

### 4 Outlet Run 2 100912.402-2A 3.8 3.8 100 342 242 0.5 Plant 4 Outlet Run 3 100912.403-2A 8.2 8.2 1

# oo 323 223 1.2 Plant 5 Inlet Run 1 100912.511-2A 17.3 17.3 100 339 239 2.5 Plant 5 Inlet Run 2 100912.512-2A 7.0 7.0 100 351 251 1.0 Plant 5 Inlet Run 3 100912.513-2A 6.5 6.5 100 333 233 0.9 Plant 5 Outlet Run 1 100912.501-2A 5.5 5.5 100 350 250 0.8 Plant 5 Outlet Run 2 100912.502-2A 4.8 4.8 100 334 234 0.7 Plant 5 Outlet Run 3 100912.503-2A 7.6 7.6 100 329 229 1.1 FRONT SPIKE 100912.SAI2·1 1053.6 % REC 

# = 104.5% BACK SPIKE 100912.SAI2-2A 874.0 % 

### REC 

# = 85.0% FRONT DUP 100912.SAI3-1 D 11 .4 RPD = N/A BACK DUP 1 00912.SAI3-2AD 36.8 RPD 

## = 12.5%

Page 35 of 103 ATC PROJECT No. P·10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 565BORAL BRICKS


## PHOSPHORUS ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. 

### MDL= 100 

### fJg/l Proj. #: 

### 100912 Postdig'n spike cone. = 

### 5000 

### Jlg/l Dale: 05-0ct-1 0 Sample ID Tesl Dig'te Dil'n Total Volume 

### Client FAL Sol'n 

### Cone 

### FV Factor Volume 

### Dig'd Total 

### Jlg/L Jlg/L ml ml ml 

### 119 FRONT HALVES 

### Blank 100912.8-1 104.5 104.5 100 10.5 Salisbury Inlet Run 1 100912.SAI1-1 188.7 377.4 100 2 37.7 Salisbury Inlet Run 2 100912.SAI2-1 356.8 356.8 100 35.7 Salisbury Inlet Run 3 1 

### 00912 .SA13- 1 

### 314.6 314.6 100 31.5 Salisbury Outlet Run 1 100912.SA01-1 159.8 159.8 100 16.0 Salisbury Outlet Run 2 100912.SA02-1 171.5 171.5 100 17.2 Salisbury Outlet Run 3 1 

### 00912.SA03-1 147.1 147.1 100 14.7 Plant 4 Inlet Run 1 

### 100912.411-1 252.4 252.4 100 25.2 Plant 4 

### Inlet Run 2 100912.412-1 165.5 165.5 100 16.5 Plant4 Inlet Run 3 100912.413-1 272.6 272.6 100 27.3 Plant 4 

### Outlet Run 1 100912.401-1 195.7 195.7 100 19.6 Plant 4 

### Outlet Run 2 100912.402-1 190.5 190.5 100 19.0 Plant 4 Outlet Run 3 100912.403-1 189.2 189.2 100 18.9 PlantS Inlet Run 1 

### 100912.511-1 171.0 171.0 100 17.1 Plant 5 Inlet Run 2 100912.512-1 303.6 303.6 100 30.4 Plant 5 Inlet Run 3 100912.513-1 185.3 185.3 100 18.5 Plant 5 Outlet Run 1 

### 100912.501-1 76.7 76.7 100 

### < 10.0 Plant 5 Outlet Run 2 100912.502-1 89.4 89.4 100 

### < 10.0 Plant 5 Outlet Run 3 100912.503-1 100.4 100.4 100 10.0

Paga 36 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 566BORAL BRICKS


## PHOSPHORUS ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 100 119/L Proj. 

### #: 100912 Postdig 1 n spike cone. 

## = 5000 119/L Date: 05-0c!-1 0 Sample ID Test Dig 1 

### fe 

### OWn Total Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total 119/L 119/l ml ml ml 

### 119 

### BACK HALVES Blank 100912.B-2A 42.3 42.3 100 116 66 

### < 17.6 Salisbury Inlet Run 1 

### 100912.SA11-2A 184.6 184.6 100 324 224 26.7 Salisbury Inlet Run 2 100912.SAI2-2A 163.2 163.2 100 336 236 23.2 Salisbury Inlet Run 3 100912.SAI3-2A 169.7 169.7 100 356 256 23.6 Salisbury Outlet Run 1 100912.SA01-2A 146.4 146.4 100 335 235 20.9 Salisbury Outlet Run 2 100912.SA02-2A 115.1 115.1 100 288 188 17.6 Salisbury Outlet Run 3 100912.SA03-2A 175.1 175.1 100 366 266 24.1 Plant 4 Inlet Run 1 100912.411-2A 112.3 112.3 100 333 233 16.1 Plant 4 Inlet Run 2 1 

### 00912.412 -2A 137.4 137.4 100 339 239 19.5 Plant 4 Inlet Run 3 100912.413-2A 63.0 63.0 100 333 233 

### < 14.3 Plant 4 Outlet Run 1 100912.401-2A 143.8 143.8 100 324 224 20.8 Plant 4 Outlet Run 2 100912.402-2A 123.0 123.0 100 342 242 17.4 Plant 4 Outlet Run 3 100912.403-2A 91.0 91.0 100 323 223 

### < 14.5 Plant 5 Inlet Run 1 100912.511-2A 122.8 122.8 100 339 239 17.4 Plant 5 Inlet Run 2 100912.512-2A 179.0 179.0 100 351 251 25.0 Plant 5 Inlet Run 3 100912.513-2A 42.1 42.1 100 333 233 

### < 14.3 Plant 5 Outlet Run 1 100912.501-2A 136.3 136.3 100 350 250 19.1 Plant 5 Outlet Run 2 100912.502-2A 156.5 156.5 100 334 234 22.3 Plant 5 Outlet Run 3 100912 .503-2A 162.4 162.4 100 329 229 23.3 FRONT SPIKE 100912.SAI1-1S 5224.7 % REC 

## = 100.7% BACK SPIKE 1

### 00912.411-2AS 3911.5 % REC 

## = 76.0% FRONTDUP 1 00912.SAI2-1 D 320.7 RPD 

## = N/A BACK DUP 100912.SAI2-2AD 156.6 RPD 

## = N/A

Page 37 of l 03 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 567BORAL BRICKS


## SELENIUM GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc.

**MDL~** 

### 10 J.lg/l Proj. #: 100912 Postdig'n spike cone. 

### = 

### 100 J.Ig/l Date: 08-0ct-10 Sample 10 Test Dig'te Dil'n 

### Total Volume 

### Client FAL sorn Cone FV Factor Volume 

### Dig'd Total J.lg/l J.lg/l ml ml ml 

### /.19 FRONT HALVES 

### Blank 100912.8-1 -0.8 

## -O.B 100 

### < 1.0 Salisbury Inlet Run 1 100912.SAI1-1 12.8 12.8 100 1.3 Salisbury Inlet Run 2 100912.SA12-1 15.3 15.3 100 1.5 Salisbury Inlet Run 3 100912.SAI3-1 9.5 9.5 100 

### < 1.0 Salisbury Outlet Run 1 100912.SA01-1 0.5 0.5 100 

### < 1.0 Salisbury Outlet Run 2 1 00912.SA02-1 -1.2 -1.2 100 

### < 1.0 Salisbury Outlet Run 3 l00912.SA03-1 0.5 0.5 100 

### < 1.0 Plant 4 Inlet Run 1 100912.411-1 13.1 13.1 100 1.3 Plant 4 Inlet Run 2 100912.412-1 5.2 5.2 100 

### < 1.0 Plant 4 Inlet Run 3 100912.413-1 3.2 3.2 100 

### < 1.0 Plant 4 Outlet Run 1 100912.401-1 -0.4 -0.4 100 < 

### 1.0 Plant 4 Outlet Run 2 100912.402-1 0.2 0.2 100 

### < 1.0 Plant 4 Outlet Run 3 100912.403-1 0.2 0.2 100 

### < 1.0 Plant 5 Inlet Run 1 100912.511-1 19.3 19.3 100 1.9 Plant 5 Inlet Run 2 100912.512-1 44.3 44.3 100 4.4 Plant 5 Inlet Run 3 100912.513-1 74.9 74.9 100 7.5 Plant 5 Outlet Run 1 100912.501-1 2.0 2.0 100 

### < 1.0 Plant 5 Outlet Run 2 100912.502-1 2.7 2.7 100 

### < 1.0 Plant 5 Outlet Run 3 100912.503-1 5.1 5.1 100 

### < 1.0

Page 38 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 568BORAL BRICKS


## SELENIUM GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 10 J.lg/L Proj. 

### #: 100912 

### Postdig'n spike cone. = 

### 100 J.lg/L Dale: 08-0ct-1 0 Sample ID Test Dig'te 

### Dil 1 

### n 

### Total 

### Volume Client FAL Sol'n 

### Cone FV Factor Volume 

### Dig'd Total J.lg/L J.lg/L ml ml ml J.l9 

### BACK HALVES Blank 100912.B-2A -0.2 -0.2 100 1 116 66 

## < 1.8 Salisbury Inlet Run 1 100912 .SA11-2A -0.2 -3.3 100 15 324 224 

## < 21.7 Salisbury Inlet Run 2 100912.SAI2-2A 15.0 15.0 100 336 236 2.1 Salisbury Inlet Run 3 100912.SA13-2A 7.3 7.3 100 356 256 

### < 1.4 Salisbury Outlet Run 1 100912.SA01-2A 13.2 13.2 100 335 235 1.9 Salisbury Outlet Run 2 l00912.SA02-2A 6.9 6.9 100 288 188 

## < 1.5 Salisbury Outlet Run 3 100912.SA03-2A 1.7 1.7 100 366 266 

## < 1.4 Plant 4 Inlet Run 1 100912.411-2A 9.8 9.8 100 333 233 

## < 1.4 Plant 4 Inlet Run 2 100912.412-2A 17.2 17.2 100 339 239 2.4 Plant 4 Inlet Run 3 100912. 413-2A 10.0 10.0 100 333 233 1.4 Plant 4 Outlet Run 1 100912.401-2A 2.7 2.7 100 324 224 

## < 1.4 Plant 4 Outlet Run 2 100912.402-2A -1 .4 -1.4 100 342 242 

### < 1.4 Plant 4 Outlet Run 3 100912.403-2A -1.1 -1.1 100 323 223 

## < 1.4 Plant 5 Inlet Run 1 100912.511-2A 24.3 24.3 100 339 239 3.4 Plant 5 Inlet Run 2 100912.512-2A 10.7 10.7 100 351 251 1.5 Plant 5 Inlet Run 3 100912.513-2A 9.7 9.7 100 333 233 

### < 1.4 Plant 5 Outlet Run 1 100912.501-2A B.l 8.1 100 350 250 

## < 1.4 Plant 5 Outlet Run 2 1 00912.502-2A 11.1 11.1 100 334 234 1.6 Plant 5 Outlet Run 3 100912.503-2A 8.7 8.7 100 329 229 

## < 1.4 FRONT SPIKE 100912.411-1 92.4 % REC 

### = 79.2% BACK SPIKE 100912 .SAI1-2A 93.2 % REC = 

### 93.2%

Page 39 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 569BORAL BRICKS


## SILVER ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET 

### Client: Analytical Testing Consultants, Inc. MDL= 5 pg/L Proj. #: 100912 Postdig'n spike cone. = 1000 pg/L Dale: 05-0cl-1 0 Sample ID Test Dig'te Dil'n Total Volume 

### Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total jJg/l pg/l ml ml ml jJg FRONT HALVES 

### Blank 100912.8-1 0.1 0.1 100 < 

### 0.5 Salisbury Inlet Run 1 100912.SAI1-1 0.8 4.2 100 5 < 

### 2.5 Salisbury Inlet Run 2 100912.SAI2-1 0.9 0.9 100 < 

### 0.5 Salisbury Inlet Run 3 100912.SA13-1 0.7 0.7 100 < 

### 0.5 Salisbury Outlet Run 1 100912.SA01-1 0.1 0.1 100 < 

### 0.5 Salisbury Outlet Run 2 100912.SA02-1 -0.3 .o.3 100 < 

### 0.5 Salisbury Outlet Run 3 100912.SA03-1 -0.2 -0.2 100 < 

### 0.5 Plant 4 Inlet Run 1 100912.411-1 0.6 0.6 100 < 

### 0.5 Plant 4 Inlet Run 2 100912.412-1 0.0 0.0 100 < 

### 0.5 Plant 4 Inlet Run 3 100912.413-1 0.0 0.0 100 < 

### 0.5 Plant 4 Outlet Run 1 100912.401-1 0.8 0.8 100 < 

### 0.5 Plant 4 Outlet Run 2 100912.402-1 -0.2 -0.2 100 < 

### 0.5 Plant 4 Outlet Run 3 100912.403-1 0.1 0.1 100 < 

### 0.5 Plant 5 Inlet Run 1 100912.511-1 0.0 0.0 100 < 

### 0.5 Plant 5 Inlet Run 2 100912.512-1 -0.3 -0.3 100 < 

### 0.5 Plant 5 Inlet Run 3 100912.513-1 -0.2 -0.2 100 < 

### 0.5 Plant 5 Outlet Run 1 100912.501-1 -0.7 -0.7 100 < 

### 0.5 Plant 5 Outlet Run 2 100912.502-1 0.0 0.0 100 < 

### 0.5 Plant 5 Outlet Run 3 100912.503-1 -0.2 -0.2 100 < 

### 0.5

Page 40 of 103 ATC PROJECT No. P·10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 570

### I BORAL BRICKS


### SILVER ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 5 llg/L Proj. 

### #: 100912 Postdig'n spike cone. 

### == 1000 119/L Date: 05-0ct-1 0 Sample ID Test Dig'te Dil'n Total Volume 

### Clienl FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total 

### Jlg/l Jlg/L ml ml ml 

### Jig BACK HALVES Blank 100912.B-2A -0.5 -0.5 100 116 66 

### < 0.9 Salisbury Inlet Run 1 100912.SAI1-2A -0.1 -0.1 100 324 224 

### < 0.7 Salisbury Inlet Run 2 l00912.SAI2-2A -0.4 -0.4 100 336 236 

### < 0.7 Salisbury Inlet Run 3 100912.SA13-2A -0.1 -0.1 100 356 256 

### < 0.7 Salisbury Outlet Run 

### 1 1 00912.SAO 

### 1-2A -0.1 -0.1 100 335 235 

### < 0.7 Salisbury Outlet Run 2 l00912.SA02-2A -0.1 -0.1 100 288 188 

### < 0.8 Salisbury Outlet Run 3 100912.SA03-2A -0.1 -0.1 100 366 266 

### < 0.7 Plant 

### 4 Inlet Run 

### 1 100912.41l-2A -0.3 -0.3 100 333 233 

### < 0.7 Plant 

### 4 Inlet Run 2 100912 .412-2A 0.0 0.0 100 339 239 

### < 0.7 Plant 

### 4 Inlet Run 3 100912.413-2A -0.6 -0.6 100 333 233 

### < 0.7 Plant 4 Ouflet Run 

### 1 100912.401-2A -0.4 -0.4 100 324 224 

### < 0.7 Plant 

### 4 Outlet Run 2 100912.402-2A -0.6 -0.6 100 342 242 

### < 0.7 Plant 4 Outlet Run 3 100912.403-2A 0.0 0.0 100 323 223 

### < 0.7 Plant 5 Inlet Run 1 100912.51l-2A -0.6 -0.6 100 339 239 

### < 0.7 Plant 5 Inlet Run 2 100912.512-2A -0.6 -0.6 100 351 251 

### < 0.7 Plant 5 Inlet Run 3 100912.513-2A 0.9 0.9 100 333 233 

### < 0.7 Plant 5 Outlet Run 

### 1 100912.50l-2A 0.2 0.2 100 350 250 

### < 0.7 Plant 5 Outlet Run 2 100912.502 -2A -0.5 -0.5 100 334 234 

### < 0.7 Plant 5 Outlet Run 3 

### 100912.503-2A -0.7 -0.7 100 329 229 

### < 0.7 FRONT SPIKE 100912.SAI1-1S 765.8 % REC = 76.6% BACK SPIKE 100912.411-2AS 794.1 % REC = 79.4% FRONT DUP 100912.SA12-10 0.7 RPD = N/A BACK DUP 100912.SAI2-2AD -0.1 RPD = N/A

Page 41 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 571

# ( BORAL BRICKS


## THALLIUM GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 5 

### Jlg(l Praj. #: 100912 Postdig'n spike cone. 

### = 50 

### Jlg(l Date: 

### 07-0ct-10 Sample ID Test Dig'te Dil'n 

### Total Volume 

### Client FAL Sol'n Cone 

### FV Foetor Volume 

### Dig'd Total 

### Jlg(l Jlg(L ml ml ml 

### Jlg 

### FRONT HALVES Blank 100912.8-1 -0.2 -0.2 100 

### < 0.5 Salisbury Inlet Run 1 100912.SAI1-1 4.7 4.7 100 

### < 0.5 Salisbury Inlet Run 2 100912.SAI2-1 4.9 4.9 100 

### < 0.5 Salisbury Inlet Run 3 100912.SAI3-1 4.5 4.5 100 

### < 0.5 Salisbury Outlet Run 1 100912.SA01-1 -0.1 -0.1 100 

### < 0.5 Salisbury Outlet Run 2 100912.SA02-1 -0.5 -0.5 100 

### < 0.5 Salisbury Outlet Run 3 100912.SA03-1 0.0 0.0 100 

### < 0.5 Plant 4 Inlet Run 1 100912.411-1 0.0 0.0 100 

### < 0.5 Plant 4 Inlet Run 2 100912.412-1 0.1 0.1 100 

### < 0.5 Plant 4 Inlet Run 3 100912.413-1 0.0 0.0 100 

### < 0.5 Plant 4 Outlet Run 1 100912.401-1 -0.5 -0.5 100 

### < 0.5 Plant 4 Outlet Run 2 100912.402-1 -0.3 -0.3 100 

### < 0.5 Plant 4 Outlet Run 3 100912.403-1 -0.1 -0.1 100 

### < 0.5 Plant 5 Inlet Run 1 100912.511-1 0.7 0.7 100 

### < 0.5 Plant 5 Inlet Run 2 100912.512-1 0.4 0.4 100 

### < 0.5 Plant 5 Inlet Run 3 100912.513-1 0.7 0.7 100 

### < 0.5 Plant 5 Outlet Run 1 100912.501-1 -0.1 -0.1 100 

### < 0.5 Plant 5 Outlet Run 2 100912.502-1 -0.3 -0.3 100 

### < 0.5 Plant 5 Outlet Run 3 100912.503-1 -0.3 -0.3 100 

### < 0.5

Page 42 of 1OJ ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 572

### ( BORAL BRICKS


## THALLIUM GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 5 fJg/L Proj. 

### #: 100912 

### Postdig 1

### n spike cone. 

## = 50 fJ9/L Date: 

### 07-Oct-1 0 Sample ID Test Dig'te 

### Dil 1 n 

### Total Volume 

### Client FAL Sol'n Cone FV Factor Volume 

### Dig'd Total !Jg/L fJg/L ml ml ml 

### 1'9 BACK HALVES Blank 100912.B-2A -0.7 -0.7 100 116 66 

### < 0.9 Salisbury Inlet Run 1 

### 1 00912.SA11-2A -0.6 -0.6 100 324 224 

### < 0.7 Salisbury Inlet Run 2 100912.SAI2-2A -0.6 -0.6 100 336 236 

### < 0.7 Salisbury Inlet Run 3 100912.SA13-2A -0.4 -0.4 100 356 256 

### < 0.7 Salisbury Outlet Run 1 100912 SA01-2A -0.3 -0.3 100 335 235 

### < 0.7 Salisbury Outlet Run 2 100912.SA02-2A -0.1 -0.1 100 288 188 

### < 0.8 Salisbury Outlet Run 3 100912.SA03-2A 0.0 0.0 100 366 266 

### < 0.7 Plant4 Inlet Run 1 100912.411-2A 0.1 0.1 100 333 233 

### < 0.7 Plant 4 Inlet Run 2 100912.412-2A -0.2 -0.2 100 339 239 

### < 0.7 Plan! 4 Inlet Run 3 100912.413-2A -0.2 -0.2 100 333 233 

### < 0.7 Plant4 Outlet Run 1 100912.401-2A 0.0 0.0 100 324 224 

### < 0.7 Plant 4 Outlet Run 2 100912.402-2A -0.5 -0.5 100 342 242 

### < 0.7 Plant 4 Outlet Run 3 100912.403-2A -0.2 -0.2 100 323 223 

### < 0.7 Plant 5 Inlet Run 1 100912.511-2A -0.1 -0.1 100 339 239 

### < 0.7 Plant 5 Inlet Run 2 100912.512-2A -0.3 -0.3 100 351 251 

### < 0.7 Plan! 5 Inlet Run 3 

### 1 00912.513-2A 0.0 0.0 100 333 233 

### < 0.7 Plan! 5 Outlet Run 1 100912.501-2A 0.0 0.0 100 350 250 

### < 0.7 Plant 5 Outlet Run 2 100912.502-2A 0.0 0.0 100 334 234 

### < 0.7 Plan! 5 Outlet Run 

### 3 100912.503-2A -0.3 -0.3 100 329 229 

### < 0.7 FRONT SPIKE 100912.411-1 51.1 % REC

**~** 

### 102.2% BACK SPIKE 10091 2 .411-2A 49.7 % REC

**~** 

### 99.4%

Page 43 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 573BORAL BRICKS


### ZINC ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants 1 

### Inc.

**MDL~** 

### 5 pg/L Proj. #: 

### 100912 Postdig•n spike cone. = 

### 1000 pg/L Date: 05-0ct-10 Sample ID Test Dig'te 

### Dil'n Total Volume 

### Client FAL Sol'n 

### Cone FV 

### Factor Volume 

### Dig'd Total pg/L pg/L ml ml mf 

## pg FRONT HALVES Blank 100912.8-1 23.2 23.2 100 2.3 Salisbury Inlet Run 1 100912.SAI1-1 242.3 242.3 100 24.2 Salisbury Inlet Run 2 100912.SAI2·1 240.7 240.7 100 24.1 Salisbury Inlet Run 3 100912.SAI3-1 219.3 219.3 100 21.9 Salisbury Outlet Run 1 100912.SA01-1 29.8 29.8 100 3.0 Salisbury Outlet Run 2 100912.SA02-1 29.9 29.9 100 3.0 Salisbury Outlet Run 3 1 00912.SA03-1 43.1 43.1 100 4.3 Plant 

### 4 Inlet Run 1 100912.411-1 26.1 26.1 100 2.6 Plant 4 Inlet Run 2 100912.412-1 23.8 23.8 100 2.4 Plant 4 Inlet Run 3 100912.413-1 23.3 23.3 100 2.3 Plant 4 Outlet Run 1 100912.401-1 28.5 28.5 100 2.8 Plant 

### 4 Outlet Run 2 100912.402-1 25.1 25.1 100 2.5 Plant 

### 4 Outlet Run 3 100912.403-1 24.5 24.5 100 2.5 Plant 5 Inlet Run 1 100912.511-1 49.0 49.0 100 4.9 Plant 5 Inlet Run 2 100912.512-1 41.3 41.3 100 4.1 Plant 5 Inlet Run 3 100912.513-1 41.6 41.6 100 4.2 Plant 5 Outlet Run 1 100912.501-1 39.5 39.5 100 4.0 Plant 5 Outlet Run 2 100912.502-1 27.9 27.9 100 2.8 Plant 5 Outlet Run 3 100912.503-1 23.9 23.9 100 2.4

Page 44 of l 03 ATC PROJECT No. P-1 0142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 574BORAL BRICKS


## ZINC ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc.

**MDL~** 

### 5 pg/L Proj. #: 100912 Postdig' n spike cone. = 

### 1000 pg/L Dale: 05-0cl-1 0 Sample ID Test 

### Dig 1fe 

### Dil'n Total Volume 

### Client FAL 

## SoPn Cane 

### FV Factor Volume 

### Dig'd Total pg/L pg/L ml ml ml 

### /19 

### BACK HALVES Blank 100912.B-2A 2.7 2.7 100 116 66 

### < 0.9 Salisbury Inlet Run 1 100912.SAI1-2A 84.1 84.1 100 324 224 12.2 Salisbury Inlet Run 2 100912.SAI2-2A 16.0 32.0 100 2 336 236 4.6 Salisbury Inlet Run 3 100912.SAI3-2A 18.2 18.2 100 356 256 2.5 Salisbury Outlet Run 1 100912.SA01-2A 13.8 13.8 100 335 235 2.0 Salisbury Outlet Run 2 100912.SA02-2A 22.1 22.1 100 288 188 3.4 Salisbury Outlet Run 3 100912.SA03-2A 18.3 18.3 100 366 266 2.5 Plant 

### 4 Inlet Run 1 100912.411-2A 23.3 23.3 100 333 233 3.3 Plant 

### 4 Inlet Run 2 100912 .412-2A 38.8 38.8 100 339 239 5.5 Plant4 Inlet Run 3 100912.413-2A 29.5 29.5 100 333 233 4.2 Plant 

### 4 Outlet Run 1 100912.401-2A 39.0 39.0 100 324 224 5.6 Plant 

### 4 Outlet Run 2 100912.402-2A 15.1 15.1 100 342 242 2.1 Plant 4 Outlet Run 3 100912.403-2A 48.3 48.3 100 323 223 7.0 Plant 5 Inlet Run 1 100912.511-2A 23.6 23.6 100 339 239 3.3 Plant 5 Inlet Run 2 100912.512-2A 16.8 16.8 100 351 251 2.3 Plant 5 Inlet Run 3 100912.513-2A 21.4 21.4 100 333 233 3.1 Plant 5 Outlet Run 1 100912.501-2A 35.0 35.0 100 350 250 4.9 Plant 5 Outlet Run 2 100912.502-2A 42.2 42.2 100 334 234 6.0 Plant 5 Outlet Run 3 100912.503-2A 44.2 44.2 100 329 229 6.3 FRONT SPIKE 100912.SAI2-1 1122.3 

### % REC = 

### 88.2% BACK SPIKE 100912.SA12-2A 930.5 % REC 

### = 91.5% FRONT DUP 100912 .SAI3- 1D 223.0 RPD 

# = 1.7% BACK DUP 100912.SAI3-2AD 19.5 RPD 

# = N/A

Poge 45 of 103 ATC PROJECT No. P-1 0142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 

## s. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 575

### ( BORAL BRICKS


## MERCURY CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 0.20 jlg/L Proj. #: 100912 Postdig 1

### n spike cone. === 

### 5.00 119/L Date: 07-0ct-1 0 Sample ID Test Dig 1te 

### Dil'n 

### Total Volume Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total jlg/L jlg/L ml ml ml 119 

### FRONT HALVES 

### Blank 100912.8-1 -0.01 -0.01 100 100 5 

### < 0.40 Salisbury-Inlet-Run 1 100912.SAI1-1 0.04 0.04 100 100 5 

### < 0.40 Salisbury-Inlet-Run 2 100912.SA12-1 0.04 0.04 100 100 5 

### < 0.40 Salisbury-Inlet-Run 3 100912.SA13-1 0.04 0.04 100 100 5 

### < 0.40 Salisbury-Outlet-Run 1 100912.SA01·1 0.02 0.02 100 100 5 

### < 0.40 Salisbury-Outlet-Run 2 100912.SA02-1 0.02 0.02 100 100 5 

### < 0.40 Salisbury-Outlet-Run 3 100912.SA03-1 0.02 0.02 100 100 5 

### < 0.40 Plant 4-lnlet-Run 1 100912.411-1 0.03 0.03 100 100 5 

### < 0.40 Plant 4-lnlet-Run 2 100912.412-1 -0.01 -0.01 100 1 100 5 

### < 0.40 Plant 4-lnlet-Run 3 100912.413-1 0.02 0.02 100 1 100 5 

### < 0.40 Plant 4-0utlet-Run 1 100912.401-1 -0.01 -0.01 100 100 5 

### < 0.40 Plant 4-0utlet-Run 2 100912.402-1 0.03 0.03 100 100 5 

### < 0.40 Plant 4-0utlet-Run 3 100912.403-1 0.02 0.02 100 100 5 

### < 0.40 Plant 5-lnlet-Run 1 100912.511-1 0.04 0.04 100 100 5 

### < 0.40 Plant 5-lnlet-Run 2 100912.512-1 0.07 0.07 100 100 

### 5 < 0.40 Plant 5-lnlet-Run 3 100912.513-1 0.02 0.02 100 100 5 

### < 0.40 Plant 5-0utlet-Run 1 100912.501-1 0.02 0.02 100 100 5 < 

### 0.40 Plant 5-0utlet-Run 2 100912.502-1 -0.01 -0.01 100 100 5 

### < 0.40 Plant 5-0utlet-Run 3 100912.503-1 0.00 0.00 100 100 5 

### < 0.40

Page 46 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 576BORAL BRICKS


## MERCURY CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 0.20 Jig/L Proj. 

### #: 100912 Postdig'n spike cone. 

## = 5.00 Jig/L Date: 07-Oct-1 0 Sample ID Test 

### Dig'fe 

### Dil'n Total Volume Client FAL 

### Sol'n Cone 

### FV Fador Volume 

### Dig'd Total Jlg/l Jlg/L ml ml ml 

### Jig FRACTIONS 26 Blank 100912.B-2B 0.00 0.00 100 1 116 5 

## < 0.46 Salisbury-Inlet-Run 1 100912.SAI1-2B 0.16 0.16 100 1 324 5 

## < 1.30 Salisbury-Inlet-Run 2 100912.SAJ2-2B 0.78 0.78 100 336 5 5.21 Salisbury-Inlet-Run 3 100912.SA13-2B 0.53 0.53 100 356 

### 5 3.77 Salisbury-Outlet-Run 1 100912.SAO 1-28 0.09 0.09 100 335 5 

## < 1.34 Salisbury-Outlet-Run 2 1 00912.SA02 -2B 0.12 0.12 100 288 5 

## < 1.15 Salisbury-Outlet-Run 3 100912.SA03-2B 0.08 0.08 100 366 5 

## < 1.46 Plant 4-lnlet-Run 1 100912.411-2B 0.28 0.28 100 333 5 1.86 Plant 4-lnlet-Run 2 100912.412-2B 0.24 0.24 100 339 5 1.59 Plant 4-lnlet-Run 3 100912.413-28 0.18 0.18 100 333 5 

## < 1.33 Plant 4-0utlet-Run 1 100912.401-28 0.36 0.36 100 324 

### 5 2.30 Plant 4-0utlet-Run 2 100912.402-2B 0.48 0.48 100 342 

### 5 3.25 Plant 4-0utlet-Run 3 100912.403-28 0.40 0.40 100 323 5 2.55 Plant 5-lnlet-Run 1 100912.511-28 0.42 0.42 100 339 5 2.85 Plant 5-lnlet-Run 2 100912.512-28 0.32 0.32 100 351 5 2.25 Plant 5-lnlet-Run 3 100912.513-2B 0.16 0.16 100 333 5 

## < 1.33 Plant 5-0utlet-Run 1 100912.501-28 O.B2 0.82 100 350 

### 5 5.71 Plant 5-0utlet-Run 2 1 00912.502-2B 0.77 0.77 100 334 5 5.11 Plant 5-0utlet-Run 3 100912.503-28 0.79 0.79 100 329 5 5.20 BACK SPIKE Sal. Inlet 100912.SAI1-2BS 5.06 % REC = 101.2% BACK SPIKE Sal. Outlet

**100912.SA01-2B~** 

### 5.01 %REC=100.1% BACK SPIKE-Plant 4 In 100912.411-2BS 5.26 % REC = 99.6% BACK SPIKE-Plant 4 Out 100912.401-28S 5.27 % REC = 98.3% BACK SPIKE-Plant 5 In 100912.5tl-2BS 5.59 % REC = 103.3% BACK SPIKE-Plant 5 Out 100912.501-2BS 5.96 % REC = 102.8%

Page 47 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 577BORAL BRICKS


## MERCURY CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. 

### MDL= 0.20 Jlg/l Proj. 

### #: 100912 Date: 07-0ct-1 0 Sample ID Client 

### FRACTIONS 3A Blank Salisbury-Inlet-Run 1 Salisbury-Inlet-Run 2 Salisbury-Inlet-Run 3 Salisbury-Outlet-Run 1 Salisbury-Outlet-Run 2 Salisbury-Outlet-Run 3 Plant 4-lnlet-Run 1 Plant 4-lnlet-Run 2 Plant 4-lnlet-Run 3 Plant 4-0utlet-Run 1 Plant 4-0utlet-Run 2 Plant 4-0utlet-Run 3 Plant 5-lnlet-Run 1 Plant 5-lnlet-Run 2 Plant 5-lnlet-Run 3 Plant 5-0utlet-Run 1 Plant 5-0utlet-Run 2 Plant 5-0utlet-Run 3

ATC PROJECT No. P-10142 

### Postdig'n spike cone. = 

### 5.00 Jlg/l
Test Dig'te 

### Dil'n Total Volume FAL 

### Sol'n Cone 

### FV Factor Volume 

### Jlg/L Jlg/l ml 1 00912.8-3A -0.01 -0.01 100 100912.SAI1-3A 0.05 0.05 100 100912.SA12-3A 0.04 0.04 100 100912.SA13-3A 0.02 0.02 100 l00912.SA01-3A 0.02 0.02 100 100912.SA02-3A -0.02 -0.02 100 100912.SA03-3A -0.03 -0.03 100 100912.411-3A 0.08 0.08 100 100912.412-3A 0.08 0.08 100 1 00912.413-3A 0.08 0.08 100 100912.401-3A 0.01 0.01 100 100912.402-3A -0.01 -0.01 100 1 00912.403-3A 0.02 0.02 100 1 00912.511-3A 0.04 0.04 100 100912.512-3A 0.07 0.07 100 100912.513-3A 0.09 0.09 100 100912.501-JA 0.01 0.01 100 1 00912.502-3A 0.00 0.00 100 1 00912.503-3A -0.01 -0.01 100

Page 48 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0 

### ml 33 124 111 153 119 123 146 118 113 112 110 11 5 114 107 121 115 121 108 110 Dig'd Total ml /19 

### 10 

## < 0.07 10 

## < 0.25 10 

## < 0.22 10 

## < 0.31 10 

## < 0.24 10 

## < 0.25 10 

## < 0.29 10 

## < 0.24 10 

## < 0.23 10 

## < 0.22 10 

## < 0.22 10 

## < 0.23 10 

## < 0.23 10 

### < 0.21 10 

## < 0.24 10 

## < 0.23 10 

## < 0.24 10 

## < 0.22 10 

## < 0.22

APPENDIX PAGE No. 578BORAL BRICKS


## MERCURY CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 0.20 J.lg/l Proj. 

### #: 100912 Postdig 1

### n spike cone. :::::: 

### 5.00 J.lg/l Dale: 07-0ct- 10 Sample ID Test Dig'le Dil'n Total Volume Client FAL Sol'n Cone 

### FV Factor Volume 

### Dig'd Total J.lg/L J.lg/L ml ml ml J.l9 

### FRACTIONS 3B Blank 100912.B-3B 0.01 0.01 100 87 20 

### < 0.09 Salisbury-Inlet-Run 1 100912.SAI1-3B 0.04 0.04 100 386 20 

### < 0.39 Salisbury-Inlet-Run 2 100912.SAI2-38 0.05 0.05 100 388 20 < 

### 0.39 Salisbury-Inlet-Run 3 100912.SA13-38 0.03 0.03 100 387 20 

### < 0.39 Salisbury-Outlet-Run 1 100912.SA01-3B 0.04 0.04 100 408 20 

### < 0.41 Salisbury-Outlet-Run 2 100912.SA02-3B 0.03 0.03 100 389 20 < 

### 0.39 Salisbury-Outlet-Run 3 100912.SA03-38 0.03 0.03 100 405 20 < 

### 0.41 Plant 4-lnlet-Run 1 100912.411-38 0.01 0.01 100 395 20 < 

### 0.40 Plant 4-lnlet-Run 2 100912.412-38 O.Ql 

### 0.01 100 390 20 < 

### 0.39 Plant 4-lnlet-Run 3 100912.413-38 0.05 0.05 100 400 20 

### < 0.40 Plant 4-0utlet-Run 1 100912.401 -3B 0.36 0.36 100 405 20 0.73 Plant 4-0utlet-Run 2 100912.402-38 0.37 0.37 100 388 20 0.71 Plant 4-0utlet-Run 3 100912.403-38 0.28 0.28 100 399 20 0.56 Plant 5-lnlet-Run 1 100912.511-38 0.41 0.41 100 406 20 0.83 Plant 5-lnlet-Run 2 100912.512-38 0.50 0.50 100 421 20 1.05 Plant 5-lnlei-Run 3 100912.513-38 0.48 0.48 100 438 20 1.05 Plant 5-0utlei-Run 1 100912.501-38 0.03 0.03 100 389 20 < 

### 0.39 Plant 5-0utlet-Run 2 100912.502-38 -0.02 -0.02 100 400 20 < 

### 0.40 Plant 5-0utlet-Run 3 100912.503-38 -0.02 -0.02 100 373 20 < 

### 0.37

Page 49 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 579

# ( BORAL BRICKS


## MERCURY CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET Client: Analytical Testing Consultants, Inc. MDL= 0.20 pg/L Proj. 

### #: 100912 

### Postdig'n spike cone. == 5.00 pg/L Date: 

### 07-0ct-10 Sample ID Test Dig'te Dil'n Total Volume Client FAL Sol'n 

### Cone FV Factor Volume 

### Dig'd Total pg/L pg/L ml ml ml 

### Jlg FRACTIONS 3C Blank 100912.B-3C 0.01 0.01 100 107 5 

### < 0.43 Salisbury-Inlet-Run 1 100912.SAI1-3C 0.83 0.83 100 255 5 4.21 Salisbury-Inlet-Run 2 100912.SAI2-3C 1.45 1.45 100 249 5 7.20 Salisbury-Inlet-Run 3 100912.SAJ3-3C 1.02 1.02 100 250 5 5.10 Salisbury-Outlet-Run 1 100912.SA01-3C 0.02 0.02 100 272 5 

### < 1.09 Salisbury-Outlet-Run 2 100912.SA02-3C -0.01 -0.01 100 250 5 

### < 1.00 Salisbury-Outlet-Run 3 100912 .SA03-3C -0.01 -0.01 100 246 5 

### < 0.98 Planl4-lnlet-Run 1 100912.411-3C 0.35 0.35 100 150 5 1.04 Plant 4-lnlet-Run 2 100912.412-3C 0.15 0.15 100 263 5 

### < 1.05 Plant 4-lnlet-Run 3 100912.413-3C 0.04 0.04 100 264 5 

### < 1.06 Plant 4-0utlet-Run 1 100912.401-3C 0.24 0.24 100 258 5 1.24 Plant 4-0utlet-Run 2 100912.402-3C 0.03 0.03 100 273 5 

### < 1.09 Plant 4-0utlet-Run 3 100912.403-3C 0.09 0.09 100 259 5 

### < 1.04 Plant 5-lnlet-Run 1 100912.511-3C 0.15 0.15 100 25B 5 

### < 1.03 Plant 5-lnlet-Run 2 100912 .512-3C 0.19 0.19 100 253 5 

### < 1.01 Plant 5-lnlet-Run 3 100912.513-3C 0.10 0.10 100 232 5 

### < 0.93 Plant 5-0utlet-Run 1 100912.501-3C 0.21 0.21 100 246 5 1.03 Plant 5-0utlet-Run 2 100912.502-3C 0.21 0.21 100 248 5 1.04 Plant 5-0utlet-Run 3 100912.503-3C 0.24 0.24 100 243 5 1.17

Page 50 of 103 ATC PROJECT No. P·10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 580BORAL BRICKS


## MERCURY QUALITY CONTROL DATA Client: Analytical Testing Consultants, Inc. 

### Proj. #: 

### 100912 Dote: 07-0ct-1 0 Calibration Data Run 1 Run 2 True cone.**/1~/l** 

### Abs. Abs. 

### Blank 0.00 0.000 0.000 Standard 1 0.50 0.016 0.013 Standard 2 1.00 0.034 0.026 Standard 3 2.00 0.060 0.052 Standard 4 5.00 0.151 0.125 Standard 5 10.00 0.300 0.248 Calibration Verifications Run 1 Run 2

ATC PROJECT No. P-10142 

### ICV 

# = 5 4.99 4.99 ICB 

# = 0 -0.02 -0.02 CCV1 = 5 5.13 5.13 CCB1 = 0 0.04 0.04 CCV2 = 5 4.87 4.87 CCB2 = 0 -0.03 -0.03 CCV3 = 5 5.03 5.03 CCB3 = 0 0.00 0.00 CCV4 = 5 4.93 4.93 CCB4 = 0 0.04 0.04 CCV5 = 5 5.00 5.00 CCB5 = 0 0.01 0.01 CCV6 = 5 5.19 5.19 CCB6 = 0 0.06 0.06 CCV?= 5 5.05 5.05 CCB7 = 0 0.03 0.03

Page 51 ofl03 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### Run 3 

### Abs. 

### 0.000 0.014 0.027 0.054 0.135 0.265 Run 3



### 5.03 0.01 5.20 0.03

APPENDIX PAGE No. 581BORAL BRICKS


## MERCURY QUALITY CONTROL DATA Client: Analytical Testing Consultants, Inc. 

### Proj. 

### #: 100912 Date: 07-Oct-1 0 

### Calibration Verifications Run 1 Run 

### 2

ATC PROJECT No. P-1 0142 

### CCV8 = 5 4.88 CCB8 = 0 -0.01 CCV9 = 5 5.17 CCB9 = 0 -0.03 CCV10=5 5.06 CCB10 

### = 0 0.03 CCVll = 5 5.19 CCB11 

### = 0 0.04

Page 52 of 103 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 

### Run 3

APPENDIX PAGE No. 582BORAL BRICKS



### ANALYTICAL TESTING CONSULTANTS, INC. Toll

**Free~B00)-733-3193** CHAIN OF CUSTODY RECORD Projoot No p 10124 

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**241~0~15.** cell PLE-'SE MARK UOUlO LEvEL ON AlllSAMPLE BOTTLES WITH GREASE PENCIL. SEAL nGHTLY ft,N(l RE-CHECK UPON OEUVEAY TO l..AB PERSONNEL 

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# dl'fr/z.l/}16 J./:oaPM ATC PROJECT No. P-1 0142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PlANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 583BORAL BRICKS



### ANALYTICAL TESTING CONSULTANTS, INC. Toll Free-(800)·733·3193 CHAIN OF CUSTODY RECORD Proj•ct No 

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**AOTTL~S** WITH GREASE' PENCll. SEAL TlGHTI.v AND RE-CHt:CK UPON. OEUVERY TO LAB PERSONNEl.

Poge 54 of 103 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 **~** 

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APPENDIX PAGE No. 584

# i BORAL BRICKS



# ATC EQUIPMENT CALIBRATIONS

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 634BORAL BRICKS 

## GLASS NOZZLE CALIBRATION DATA FORM Re<i: Box 1 PR!MARY DATE: CALIBRATED BY: SERIES: 

### 12/3012009 Black: Box 2 Mallory P. Beam lnllials 1 1\() 

# \? 

# B 20, 30, 40, 50, 60, 70, 80, 90, 100, 110, 120,130 Glass Sehes, Quartz Nozzles

ATC Fonn i49 R Primary Nozzle Calibration Record version 1.0 January 2006 F:\Work.V\11 FormsRFiefd Data Sheets, Calc Formulae ... '\149-Prlmary Nozzle Calibration Record.xls ATC (BOO) 733·3193 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 635PRIMARY DATE CALIBRATED BY: SERIES: BORAL BRICKS 

## GLASS NOZZLE CALIBRATION DATA FORM Red: Box 1 12/30/2009 Black: Box 2 Mallory P. Beam Initials 

# ro p 

# l; 20, 30, 40, 50, 60, 70, 80, 90, 100, 110, 120,130 Glass Series, QuartZ Nozzles

ATC Fonn 149 ·Primary Nozzle Calibration Record version 1.0 January 2006 F:\Work\AII

**Forms~Field** Data Sheets, Calc Formulae ... \149-Prtmary Nozzle Calibration Recor:d.xls ATC (800) 733-.3193 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 636BORAL BRICKS 

## GLASS NOZZLE CALIBRATION DATA FORM Red: Box 1 PRIMARY DATE: 12/3012009 

### Black: Box 2 CALIBRATED BY: Mallory P. 

### Beam Initials 

## yvy(J 

## (3 SERIES: 20, 30, 40, 50, 60, 70, 80, 90, 100, 110, 120,130 

### Glass Series, Quartz Nozzles NOTE· Nozzles are a ranged from smallest to gteatest average diametet 

## 27 MISSING MISSING MISSING #VALUE! 

## 28 MISSING MISSING MISSING #VALUE! 

## 29 MISSING MISSING MISSING #VALUE! 

## 30 MISSING MISSING MISSING #VALUE! 

## 31 MISSING MISSING MISSING #VALUE! 

## 33 BROKEN BROKEN BROKEN #VALUE! 

## 58 MISSING MISSING MISSING #VALUE! 

## 84 MISSING MISSING MISSING #VALUE I 

## 85 MISSING MISSING MISSING #VALUE! 

## 86 MISSING MISSING MISSING #VALUE! 

## 94 MISSING MISSING MISSING #VALUE! 

## 95 MISSING MISSING MISSING #VALUE! 

## 98 MISSING MISSING MISSING #VALUE! 

## 101 MISSING MISSING MISSING #VALUE! 

## 120 MISSING MISSING MISSING #VALUE! 

## 121 MISSING MISSING MISSING #VALUE! 

## 122 MISSING MISSING MISSING #VALUE! 

## 124 BROKEN BROKEN BROKEN #VALUE! 

## 125 MISSING MISSING MISSING #VALUE! 

## 130 MISSING MISSING MISSING #VALUE!



## 0.000 where.

**·~** 

### Three different nozzle diameters; Each diameter must be within 0.001 

### inches



### ...... = Maximum difference between 

### any two diam'?ters must be less than or equal to 0.004 inches "'*"'::::Average of three diameters 

## 0.193 0.167 0.198 0.211 0.212 0.219 0.281 0.346 0.347 0.343 0.373 0.379 0.387 0.409 0.495 0.497 0.499 0.503 0.502 1.023

0.000

ATC Form 149. Primary Nozzle Calibration Record version 1.0 January 2006 F:\Wor1<\Ait Forms-Field Data Sheets, Calc Formulae
.. , \149-Prlmary Nozzle Calibration Record.xis ATC (800) 733-3193 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 637BORAL BRICKS 

# NOZZLE CALIBRATION DATA FORM Red: Box 1 DATE: 

### 2/24/2009 Black: Box 2 --=::...:.:.;::.:..:..::___ CALIBRATED BY:

ATC Form 149- Primary Nozzle Calibration Record version 1.0 January 2006 F:\Work\AII Forms-Field Data Sheets, Calc Formulae ... \149-Primary Nozzle Calibration Record.xls ATC (800)

**733~3193** ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PlANTS 4 & 5, SALISBURY PlANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 638

# ( BORAL BRICKS 

# NOZZLE CALIBRATION DATA FORM Red: Box 1 DATE 

### 2/2412009 Black: Box 2 CALIBRATED BY: 

### Mallory Beam Initials: 

# 'J/t7Yi1 ___ _ All

where: 

### ·=Three different nozzle diameters; Each diameter must be within 0.001 inches **=Maximum difference between any two diameters must be less than or equal to 0.005 inches ***;:; Average of three diameters

ATC Form 149- Primary Nozzle Calibration Record version 1.0 January 2006 F:\Work\AII Forms-Field Data Sheets, Calc Formulae ... \149-Primary Nozzle Calibration Record.xls ATC (BOO) 733-3193 ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 639BORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet**Degre~** lndicEted !eve! positit.m for detennining !l1 and 

### B 2•**Degr~e** indicating ieve.l position for**~'lclerminiug** cf0.

., .l.

### h.:o::C~Tc)!~,--- 

# •**D~grc~:s** iadicating level position tOr dcten11ining y then C{llculate 

### z. 

# --**-----~--** 

### Level mtd Perpendicular? 

# .Y Obstruction? 

# ;V Damaged? 

# /1/

----- 

### a, (-Ill' 

## :S a1.:S+10')



# -- 

# 2"

a 2 

### (-111' 

## :S a 2

### .:S+llf') -, 

# "' ,;-



# ---- ·--·-- 

## p, (-5'' 

# :s fl, 

# :s +5") 

# /,j [J, (-5' 

# .:s p, 

# .:s +50) 

# ;o

- 

# r 0 

# e ()



# -- Z=A tan7 (< 

### 0.125'') 0 W=A tan 

# e (_:50.03115'? 

## 0



## - ··--·-- f-- 

### D,(J/16" :SD, 

## :5: 318'') 

# eJ 

# '57S



# -- f--· 

### A 

# I-I)· 

# il"f 

# s

------------- A12D,(l.OS ::;P ,.ID, ::;J.50) /. 

# f<i3**·--------~-** 

# ----=-- ![temperature sensor isjlus!t. wit!t 

# Y**~~tube** Of!_enin!JJ 

### is Z >'!. "?

## ~n---- ![temperature seusor is set back from. 

# Jt./ oitot tt1be ooettitlf!, 

### is W> 2"? i**IsX::,:~''forDn=~"** 

# )!__ Is impact side o[pitot tuba ew.m 

### witlc 

# f-- or**abo~'C** 

### noule eutrv nlane? Is 

### Y;:: J"for 3116'' <Dt 

### < 318"? '---·**-·-'-----~** 

## QAIQC Check / Completeness i..,...../ 

### Legibility f.../'Accuracy _ ____.. Specificatjons Reasonableness ---· 

## Certification I certify that 

### the Type S pilot tube/probe ID # _ 

# 50 meets or exceeds ali specifications_, criteria and/or applicable design features and is hereby assigned a pilot ttl

### be calibration factor CP 

### of 0.84 1• • . . .· •



# . :;tJ'&_wvtzu**jJ~2S-01 !!.,.f(/1~._,** **iZ-'&-~-:.<:<**

# 1 Ce11ified by
-

### ~**-~-** redand 

### (Signature/Date) Team Leader 

### (Signature/Date)

1 

### This certification also applies to the specifications of EPA Method 2, section 10.1.4.1. l regaiding inter-component spacing ofpitot tube-sampling probe assemblies. Refer to the figures on the reverse side of this page for spcciflcs. ATC Form 37·PI·imary S-typc Pito\ Tube Calibrations-version 3.0 September 2007

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 ATC@ (800) 733-3193

APPENDIX PAGE No. 6401: **~** () -u 13 **~** m () --; z ? **~ ~**  ... " Gl em en" --;» "'o en""' m<;;m **-uz~** ""-<-

men"' **~~5** "'"'z
. --; "cnm

:i:t-CI.l or-< u;-u "'"' co **;u~** -<m -u" s;"" !:1 "' , -u -u m z 0 x -u , Gl m z ? **~ ~**  Thermocouple Primary Calibration Data Form

Calibration Date U- 2 .,;--oq Thermocouple Number 50

Ambient

Temp., °F rp <f

o Technician **-J~<'Gi-N'"r"""":{l'l}+R.--.a;'<-. -~-~-**  Barometric Pressure, Inches Hg 2q. 1 S Reference Thermometer (List ID #) 1 r7, ;::a, Fo/

Reference Source 2 Reference Thermocouple Temperatur:l

Point (Specify) Temperature Potentiometer Difference, %:

Number

OF

Temperature, °F (calculate in Kelvin)'

1 Ambient Air Jd/;· **&:3~"'** 0 -I'll

2 Ice Bath

3 Thelco Oven

1 Reference thermometer

.. mercury in glass

2 Type of calibration system used cf

D/Jt **~oe:,::** 4 z. (:

D. 'IOO **3CJft>~F** o,

**·a~..r.l** {3, **~on ~Iff..** 

'=[(Ref Temp, C+273) ·Test Temp., C + 273)/Ref Temp, C + 273]*100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QA/QC Check Completeness **/~egibility** /Accuracy

**/specifications~easonableness** /
Checked by:

**flcZt4.<.~** 1/·c-s -d! Galibra.tion Technician (Signature/Date)

ATC Form 209vPrimary Them1ocouple Calibration Record
version 2.1 May 2009 [;J ,1{,.;.&!._ fb

11.-[l /

oi

Test Team Leader (Signature/Date) F:\Work\AII **Fonns~** .. \2090-Prlmary thermocouple Calibrations.xls ATC (800) 733-3193 "'

0 **~** .- "' ;u 0 "' enBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

Degree: indicating levd posttion for dcterntin iug llt and a 1 .

Degree i11dicating level p.osition for detcrmining of G.**:r>~** 

## r::-:**:-:~~:ct,::-')'-.-.--** Degrees indicating le"vcl position for determining y then calculate. 

### z 

# -- 

# ------------,-------- v Level aJJd Perpeudicular? / 

### ---------------i-<------1 

## 1-0_b_s_tr_u_ct_io_n __

? ________________

# +-- 

# Af
__ Damaged?


# -------------- N
__ a 1 

### (-10':; al:;+IO'j 

## 6**~--------------------~---~--** 

### a, (-10':5;a,:S+10') A iJ___
__ 

## fl!J. 

# :L
_________________ ----t---'t.L)_-1



# e 1 

# o Z=A tan 

## r (< 

### 0.125") 

# 0 W=A tan 

# e (:S 0.03125") 

# I D**~- ------------~~----1**  

### D,(3/16";:;D, :;318'? 

# 0.) 

# 75**~-----------------------~~----1** 

## (}. 9'f() AI2D, (1.05 :5; P,11), 

## :S 1.50) 

# 1- 153 If

temperature sensor is jlus/t with 

# y oitot tube openiJzg, is Z**~---4--L----~** 

### lftemperattll'e 

### sem;or is set back from 

# I nftot tube oveuinf!, is W> 2"? __ 

# _Jjj ____

.**IsX~.J.4"forDn=~" ~** 



### - Tshnpact side of 

### pilot tube even 

# wi±th
- 

# ys

or above flOZ?;.le entl')!_.£1ane?
__, ..:- 

### Is

## ~3**'[or3116''<Dt<3/8·''?** 

# ;! __ QA!QC Check / Completeness ._-;',.... Legibility .,.....,.......7\ccmacy _..-- Speclficauons Reasonableness 

## Cert!ficatioTt I certify that the Type S pitot h1belprobe ID 

### #

### ------~5.LJ} 

# __________ meets or exceeds all specifications, criteria a11d/or applicable design features and is hereby assigned a pitot tube calibration fJ.ctor Cp 

### of 

## os4' •. · 

# /'j .' D
_ , .

# ~ . · ·. 

# /1 / ';.1 Certifted 

### by: 

# ce-e..1 f)i..U.t{g!./)._, 

# /f---- 

# s-() 1**~~-'</(** 

# V<'__k,e_._,__--. i 2 

# -8-oq Persbfmel {Sign&rureiD::ue) ·

## Tea~**Lc~der** {Signature/Date)

1 

### This cettification also applies to tht specifications of EPA Method 2. section 

### 1 0.1.4.1.1 regarding inter-component spacing of pi 

### tot tube-sampling probe assemblies. Refer to the figure.s on the reverse side of this page for specifics. ATC Form 37-f>rim::ll)' S-typc Pi tot Tube Ca1ibratie>l1S-ver\lion 3.0 September**2~07**

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 ATC@ (800) 733-3193

APPENDIX PAGE No. 642>c>--<0lJ;u0m0--<z0:!:"..."'Glem>r;(/)lJ;um'>m"zS:--<-;-m(/)(1)m"'oN(nrl1or-<(jjlJCD:Uco-<m-,<::1'>"'>lJlJmzClxlJmz"'...wThermocouplePrimaryCalibrationDataFormCalibrationDateII·zs·-0qAmbientTemp.,'F6'/<Y_:r:...r.,_____Techniciand.,......'-!'X::."'-•ReferenceSource2Point(Specify)Number1AmbientAir2IceBath3ThelcoOven1Referencethermometer-mercuryinglass'TypeofcalibrationsystemusedThermocoupleNumber51BarometricPressure,inchesHg;zqi5"ReferenceThermometer(Lis!ID#)11"7,F5,r-qReferenceThermocoupleTemperatureTemperaturePotentiometerDifference,%OFTemperature,'F(calculateinKelvin)'•0(,l/'fc(p4Fo.ooo1/D"FL/foF1),/.0021!:'/(;.3DO"r-6·l.b'('=[(RefTemp,C+273)·TestTemp.,C +273)/RefTemp,C +273]'100<1.5%Kelvin=(5/9)•(F-32)+273.15QA/QCCheckCompletenessjLegibility__6ccuracy/Reasonableness/Checkedby:i.J(Vcle.Nti-2';·<'"1CalibrationTechnician(Signature/Date)ATCForm209-PrimaryThem1ocoupleCalibrationRecordversion2.1May2009t,.)-n-/-tf<ttTestTeamLeader(Signature/Date)F:\Work.\AilForms-...\2090-PrlmarythermocoupleCalibraticns.x:lsATC(800)733-3193CD052rCD;u0:><(/)BORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

Degree indicuting !r.vd position for detcrminiilg Ctt and

**~·**

Degree indicated

**l~vel** position for determining 

### p 1 3Jld 

### thDegree i11dicating lc:vel position for detcm)inlng of0.

Degrees indic:l.ling level position for determining y t11en calcufate 

## z - 

## - Le••el mul Perpendicular?

-

**-~-** 

### Obstruction.? ·----· Dam(lged?



### ····- l1J 

### (-10' 

## :5 a1:5;+J(f') a1 (-1(1' 

## :5 a,:;-;+10')



# --- PI (-5' 

## :5 

## fJI :5 +5")

**---~--~---** 

# p, (-5' 

## :5 

# p, :5 +5")

- 

# -- )' 

# e Z=A fan 7 (< 

### 0.125'') I 

### W=A tan@ 

## (:5 0.03!25'7



# - i D,(3/l6" :;'; D, 

## :5 3/8'') 

# r-------- A



# -- AI2D, (1.05 :5;P_,!D, :5;1.50) If



### temperature sensor is flush 'H!itlt 

### pito-t tube openiltJ:, is Z 

# >-x 1 

### 7



### ----- lftempel'ature sensor 

### is set backfrom pitoc tube 

### opeuina- is W> 2"? Is X?:, ¥/'fot· Dn 

### =¥.?u 

### Is impact side of pitot tube even with or above !lOUie 

### entrv plane? 

# lis I?_J"for3fl6"<Dt<318"? -

### .. **-~** 

# y 

# r-- Al_ ____ 

# N

I " f--- 

# 7



# ~-- 

# ;o 'i> 

# 1--L--- 0 ()



# -- 

# 0

-- 

# 0 

# D-375

**0-1~!** 

# f.261I 

# y

-- 

# N 

# y )/

--- 

# /

- 

### QAIQC Check Completeness 

### legibility Accuracy Specifications Reasonableness 

### Cei·tification I certify that the TypeS pitot tube/probe ID # 

## -----~5-WJ~AWc----~ meets or exceeds all specifications, criteria and/or 

### applicable design 

### fealt.rres and is hC'.reby assjgned a pitot 

### tube calibration fiactor Cp 

### of 

# o.s4'. /:1 :l
. 

# I 

# /1 /I
.

.fi 

### db 

# "L.• 

# d

**/)t~.· ~**  I- 2



# ~- D9 K,·<w

# I (/L!..r.a



# cr.~

# ... _. iz 

# -B -if! Ccri.! 

### :e y:



### ~ **~-~·** r P.er.-;' nne!
**(Sigm,tU!'eJOat~)** Team Leader (Signature/Date)

1 

### This 

### certification also applies to the specifications of EPA

**M~thq.~** 

### 2, section 

### l 0.1.4.1.1 regarding inter-component spacing ofpitot tube-sampling piobe as$emblics. Refer to the figlli:es on the reverse side of th:is 

### page for specifics. ATC Form 37-Prlmary S-tYPe Pitol Tube C'alibr-Jtlom-verslon 3.0 September 2007 ATC@ (800) 73]-3193

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PlANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 644, c '=<

0 "0 ;u 0 **~** m 0 --< z ? ]; s: .. "' Gl em "'"

-;» "'o "'""' mt;m

"Ozl:

-<-;- m"'"' **~..,.~** m"'o ;.:l5JI **~** "'"'m

:;:>en

or-< (ii"O '""'

cO **,~** -<m "00 r;-< z --< "' , "0 "0 m z " x "0 **~** m z ? "' .. "'rThermocouple Primary Calibration Data Form

Calibration Date 1/· 2'5- o"'' Ambient Temp., !)F r..

**c.f'~**

" **Ke~** (}f t=t.tD E7-.J Reference Source 2 Point (Specify) Number 1 Ambient Air

2 Ice Bath

3 Thelco Oven
------ - -----------------· ---

1 Reference thermometer-mercury in glass
'Type of calibration system used Thermocouple Number 51A Barometric Pressure, inches Hg zCf.

1 <:;

- -- **--~** F7 F8 F"? Reference Thermocouple Temperature' Temperature Potentiometer Difference1 %

OF

Temperature, °F (calculate in Kelvin)'

(,I/(.: (,_'CP (),pCb

'-/0 **1~** tfJO.,

r- - o. <.o<>
**----~~Of.?_~'** _____ zqq" o. 132-

3 :[(Ref Temp, C+273)- Test Temp., C + 273)/RefTemp, C + 273]"100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QA/QCCheck Completeness ../ Legibility /Accuracy /specifications /Reasonableness /".

Checked by: **~1~.....,** ;t·;?';,--o-:; **C~libration** Technician (Signature/Date)

ATC Form 209·Prirnary Thermacouple Calibration Record
Vf'...rslon 2.1 May 2009 1_,_), L.& ruxL **(l:hJI)~**
Test Team Leader (Signature/Date) F:\Work.\A(J Fonnsv.,,\2090..Prtmary tharmocouple ca!lbratlons.xls 1\TC (800) 733-3193 '"

0 ?! r '" ;u 0 "' (ll

## ( BORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

-- 

# --- 

# K' 

# 'y Level a11d Perpe111licrdar? 

# r-----

ObstructiOTt? 

# N 

# r~CP:n

**[r:---~j'i'l** 

# ' - ---, I I 

# " ' 

# ,, (-< LJ Degret!

**in<!ic~ting** level pmit1on for dele1mining: 0.1 and a1.

Degree indicated \evei position for det..:nnining

**~~** ood

**.**

Degree indic:uins level position for delennining 

### ore.

:. _2 ;('



# ~- **~·~~==~d;-,~--** Degrees indicating levd

**po.~ition** tbr determining -y then calculate 

## z. QA/QC Check , Damaged? a, (-10' S

**al~+IO")**



### - a, (-10'

**:;;;a,~+JO')** 

## fl; (-5'

**~** 

## p,

**~** 

### +5')

- 

# --- -·------ 

## p, (-5" 

# s p,

**~** 

### +5') 

# r---

)' 

# e Z=A ta11 

### y (< 

### 0.125'? W=A 

## t'm 

# e (:5:

**0.03125'~**

**D,(3116"~D,** 

### :5;318'? A AI2D, (1.05 :5;P,,ID,

**~** 

### 1.50) 

## if

temperature seJisor is}lush 

### with _pilot tube

**ope~tin_e,** 

### is Z 

### >¥.- "? 

### lftemperauu·e sens-or 

### is set back from 

### pitot tube 

### ope»imt, Is fV

### > 2"?

**JsX?:.~"fcrDit** 

### ='ll" 

### Is 

### impact side of 

### pi

tot tube even wlth or aboveyozz/e eJttry

### plmte? 

### Is

**}~3''Jor** 

### 3116" <Dt < 3!8"? 

# N 

# L_ ___ 

# r

-- 

# ic



# ." l 

# 0 

# D 0


# -- 0



# 0-~75~ 

# (]. /25

**1-23,~** 

# c-y N

--- 

# y 

# y y Completeness ""'_,..... Legibility 

### .!- ,_.-·Accmacy _..- SpectficatiOl.lS -:--- Reasonableness _____. 

## Certificatioll I certify that the Type S pitot tube/probe lD # 

# 52 meets or exceeds all

nel {Sign3ture/Date) Team Leader (Sigmnure-/Date)

1 

### T1lis 

### certification also 

### applies to the 

### specifications of EPA Method 2, section 1 0.1.4.1.1 regarding inter*component spacing of pitot tube-sampling probe assemblies. Refer to the figures on 

### the reverse side of this page for specifics. ATC Fotm 37-Primary S-type PitOI Tt1be Calibrations-version 3.0

**Sept~tJiber** 2007

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PlANTS 4 & 5. SALISBURY PtA NT 6 SEPTEMBER 2010 ATC@ (800)733·3193

APPENDIX PAGE No. 646 

### I)> )> _, 0 "0 " 0 **~** m 0 _, z 0 :!: :l .. " a em cn"O

_,, "'o cn"O"

m<;;m

"Oz;;:

_,_,_ men

(I) **~~~** :u ,?1 -I "cnm **~)>en** or-_, cn"O "'" co **,~** -:m "00 <;;_, z _, "' )> "0 "0 m z 0 x **~** m z p **~** .... **~** Thermocouple Primary Calibration Data Form

. Calibration Date i i

· Z5- b 9 Ambient Temp., 'F 6 'f

<> **~** Kc:.-r Cu-><.l::£t.-'>

· Reference Source 2 Point (Specify) Number 1 Ambient Air

2 Ice Bath

3 Thelco Oven

-- **~-----------**

1 Reference thermometer-mercury in glass

2 Type of calibration system used Thermocouple Number 52 Barometric Pressure, inches Hg z"t

.I **~**

.. - - ' ---- ' 1"''1, FB

1 ;<::q Referen<>e Thermocouple Temperature· Temperature Potentiometer Difference, %

OF Temperature, °F (calculate in Kelvin)'

6'/!= ·10

k, F o.o.oo

'10"e 1.(0

iJ f'

0 ,0(\0
3oz.> **30Z~** O.coo

'=[(Ref Temp, C+273) ·Test Temp., C + 273)/Ref Temp, C + 273!*100<1.5%

Kelvin= (519) * (F-32) + 273.15 QA/QC Check Completeness .,/Legibility / Accuracy_..-§pecifications __ ,...ifeasonableness /
Checked by: l{,j U/dt.P>

Jf-1";-0CJ Calibration Technician (Signature/Date)

ATC Form 209-Primary Thermocouple Calibration Record
version 2_1 May 2009 **~** ·**~-B~l""' 1~n1** 

-·----------·----------- Test Team Leader (Signature/Daie) F:\Work\A!I **Forms~** ... \2090-Primary thermocouple Calibrations.x!s ATC (800) 733-3193 OJ 0 **~** r OJ " 0 6iBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

-- 

# _j :;·- Level and Pl!lpendicular? Obstruction? ------··· 

### Dam11ged? 

# !J a, Hrf :'Oal:'O+lrf) {a

**L-~-** Degree indicating le.,-c! positiml for dctermining o: 1 and Q1. 

## a, (-10' :::a,:'O+lrf) 

# !"

- 

## --- _ ___j

Degree indicated level position for determi;1ing 

### p, and 0.,.

Degree irodicating level position for dete1mining of<:>.

,,

**~l** 

# "

**h.:-::;:~::::·::.·_** 

### t 

# -::>,--- 

# -. Degrees indicating level position for determining y the11 calcuta.re 

## z {1, (-5"::: 

## p, :'0 +5')
····-· 

## p, (-5' 

## :'0 

# /IJ ::: +5') 

## "I 

# e Z=A tan y 

### (.< 

### 0.125") W=A tan 

# e (S

**0.03125'~** 

### D, (3116" 

## S D, 

## :5: 318") A AI2.D, (1.05 :'OP ,/D, 

### S 1.50) Iftempernture sensor isflusil witlz 

# I pitot tube

**"''e'!~g.** 

### is Z

**>~"?** 

### _ 

## If

temperature sensor is set !Jack from 

# ! pitot tube open

**in~,** 

### is

**~V** 

### > 

### 2"? __ 

### b· X:::_-% 1 '

### for Dn 

### =YJ" ....,-,------ 1 

### Is impact side ofpitot tube even li'itlt 

# ! or above 

### noz.zle entq.J!J.ane'? 

# D 

# I

-- 

# 0 0

·-·-·---·- 

# 0

**-~** 

# 0 

# 0 

# 0-'376 

# (} 150 I. ..-, ,.,...,. 

# r ..,... -"'-1 

# / 

# __ (I} 

# y 

# 7

-- 

# 7 QA/QCCheck 

# G" Y;o:



# -~"for 3116"<Dt <318"? 

## ---" Completeness ,._._..-" 

### Legibiljty L----Accmacy
- Spccific.at10ns

**~** 

### ReMonablene-ss '---· 

## Certificatiou l certify 

### that the TypeS pitot tllbe/probe ID #



## ---··--~5c.3.LLA::>.-.

# __ _ meets or exceeds all 

### spe:cificarions-, criteria andior appllcable design 

### features and is hcrtby assigned a pitot tube calibration factor Cp of 

### o.84I 

# _q 

# 1. k' . ·;



# .~ **"-c:~-** 

# '/ /. /] 

# (S/

**~:./)"/~.** 

## w

.. .

# ·,u r/L-.-f.q.£(/1__. 

# l

**-~** ..L



## ~· ,r 7 

## /-t, . .L.-t · 

# c./{:4

**~** 

# ,,lc J 1



## ~~ Certified by: · -- 

# -;r:-:, - - "..L:..!..fJ/; , Personftl {Signature/Date) Te-am Leader (Signature/Date)

1 

### This 

### certification also applies to 

### the specifications of 

### EPA Method 2, section 10.1.4.1.1 regarding inter-component spacing of pitot rube-sampling probe assembhes. Refer to the figures on the reverse side of this page for specifics. ATC Fom1 37-Primary S-type Pitot Tube Calibrations-version 3_0 Sep!ember 2007

ATC.PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 ATC @ (800) 133-3193

APPENDIX PAGE No. 648 

# /. z<s?)> c ':4 0 -u **~ ~**  m <::1 z 0 l: :l .. N Gl em "'"

-;l> )>0 "'""' ml:m **::sz~** m-1Ci5

;::"'"'

co""-

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- -< Ncnm **~)>Cf.l** or-< o;-u co:U co **,~** -<m -,0 <;;""" z -< "' )> -u -u m z 0 x :;: Gl m fi "' .. "' **~-** Thermocouple Primary Calibration Data Form

Calibration Date if· 2S:-oq Ambient Temp., °F (,<.{" Technician **~i("'e;;cN..:,...-C."::':"~-t-c:-t-r:JG-'""-A--·-:-'>--** Reference Source Point (Specify) Number 1 Ambient Air

2 Ice Bath

3 Thelco Oven

1 Reference

**thermometer~mercury** in glass

2 Type of calibration system used Thermocouple Number 53A Barometric Pressure, inches Hg

_ _.£9

.... **~·** .._!.;;<>;.....

____ _ Reference

Thermometer {List ID #) 1 1"7. F8, r:r-t Reference Thermocouple Temperature Temperature Potentiometer Difference, %

OF

Temperature, °F {calculate in Kelvin)'

&'I; (,A';;

o.ooo

**'-}D~** 4of:

o.ooo

" 3C.O'f- 2"11t= o.:w>

'=[(Ref Temp, C+273)- Test Temp., C + 273)/Ref Temp, C + 273]'100<1-5%

Kelvin= (519) * (F-32) + 273.15 QAJQC Check Completeness /

**Legibility~Accuracy** /specifications

**~easonableness** /
Checked by: Jiu.i **{Jjc/;,~; tt~Zt;-**  oCj **~aUbration** Technician (Signature/Date)

ATC Form 209-Primary Thermocouple Ca!ibfation Record
version 2.1 May 2009 GJ **~LL, tJ~~**  tt./tt,loi
Test Team Leader (Signature/Date) F:\Work\Ail **Forms~** ... \2090·Primary thermocouple Calibrations.xls ATC (800) 733-3193 "5·· co 0 **~** r co ;u 0 " "'BORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet Level and Perpendicular?



# ~ Obstruction? Damaged? 

# ,tJ Degree indicating level position for determining 11 1 and a 1 •

Degree indicated level positian for detemlinh1g 

### fh and 

### !h..

Degree indicating level positiou for 

### detennin;ng of 

## e.

Degrees indicatillg lc.vel po.<:>ition for determiningy then calculate 

## z. 

## a, (-II!':::; al:::;+IIf') a, (-11!' 

## :5: a2 

### :::;+IIf') 

# p, (-5":::: 

# p, :::: -J-5D) 

# p, (-5" 

## :5: 

# p, :5: +5D)



# ---------

'I


# ----------



# e Z=A

**tar~** 

### 7 (.< 0.125'') W=A tun 

## 19 (::; 0.03125') D, (3116" :::;D, _::: 318'J 

### A AI2D, (1.05 

## :5: P,,D, 

## :5: 1.50) If



### temperature se11sor is flush wltb pilot tube opening, is Z>W'? If



### temperature sensor is set back from pitot tube opming, is W> 2"? Is X2: 

### X"for Du =M" 

### Is impact side ofpitol tube evefl with 

### or above nozzle ei111V vltme? Is l?:;3"fol'3/16" 

### < Dt <318"? 

## ,c

**~-** 

### / 

# I c 

# 0 0 0 \) 

# 0 0 f------



## (). )?D 

# (). i''f7 

# t-

**,.~,L**



# y 

# N N/A 

# /'J/A 

# NIA OA/QC Clteck Completeness 

# _L- Legibility c./- 

### Accuracy



### ~SpecificatiOns .-------- Reasonableness



### ~ Certification ,- __ 

# 7 11 I certify that the Type S pitot tube/probe ID # 

# -> J7 meets or exceeds all specifications, criteria and/or applicable design featnres and is hereby assigned a pitot tube calibration factor 

### Cp of 

## o.s 4 '- 

# rf • n ,



# ~ - A,, 

## I 1 

## 1 

# i 1 VI 

## f! •



# ~- 

# L C 'fi 

### db . _ .. 

## J!/8,__,7(- 15t



## ~<c>f1lz 

## [ 

## f· j 

### 5 -



## ~- 

# 7 lA.. L



## l{..v~ 

## ( 

# y r"t oru 1e y•. _.;- ?"/
.

**Pcr~6nnel** (Signature/Date) Te.am Leader (SignaturefDate)
1 

### This certification also applies to the specifications ofEPA Method 2. section 10.1.4.1.1 regarding inter-component spacing ?c_fpitot tube--sampling .Ptobe assemblies. Refer to the figures on the reverse side of this page for specifics. ATC Fonn']7-P;imary S-type Pitot TubeCalibra1ions•version 3.0 Septernber2007

ATCPMJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PlANTS 4 & 5. SALISBURY PlANT 6 SEPTEMBER 2010 ATC@ (800) 733-3193

APPENDIX PAGE No. 650> c **~** (l -o :0 0 **~** m <::) z **~** :!: :1 ... " Gl em cn" ..;> >(i cn":O m):m -ozs: -<-;-

mcncn **~~B** :0"'z

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(ii-o

CD:O

cO **:o~** -<m -o(l >-< !:! 0> > -o -o m z D x -o > Gl m z 0 0> **~** Thermocouple Primary Calibration Data Form

Calibration Date 12 • :Z 1- () 'f Ambient Temp., 'F 51' Technician (.B. Reference Source' Point (Specify) Number 1 Ambient Air

2 Ice Bath

l Thelco Oven ----- --------- -

1 Reference thermometer-mercury in glass
'Type of calibration system used Thermocouple Number 57 A

---::-'::::--:-:-:::---

Barometric Pressure, inches Hg ,;2 [ '-19 _ Reference

Thermometer (List ID #)' F·7 Reference Thermocouple Temperature Temperature Potontiomater Difference, %

'F Temperature, 'F (calculate in Kelvin)'

51. 50' 0. tpd,"/o

'32"" '"5 "3

0 - 0,3?il
2ft!. 2t??"' o.ql"'/.

**~--·** -· ···-------

3 =[(Ref Temp, C+273)- Test Temp., C + 273)/Ref Temp, C.,. 273]'100<1.5%

Kelvin= (5/9) • (F-32).,. 273.15 QA/QC Check Completeness **~egibility** /Accuracy /specifications,_..../'Reasonableness ,/

Checked by:

r- ;;2-.J/·() r Calibration 1' hnician (Signature/Date)

ATC Form

**209~Primary** Thermocouple Calibration Record
version 2 1 May 2009 **~J. '-(.,__,~**  1 '1.-1 **'~-l** lor
Test Team

**Teaaer-~~~** {Signature/Date) F:\W<Jrk\A!I Forms-

... \2090-Primary thermocouple Calibrations.xls ATC (800) 733··3193 CD 0 **~** r CD :0 (i &iBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet Lepe[ 

### a11d 

### Pmpendicnlar?



# ~~ - --------- 

### Obstruction? 

# /Vi 

# I Damaged?

, a 1 

### (-111'

**~** 

### aJ:!;+lll') 

# . 

# Ia, (-111'



# ~ a 2

### :!;+111') ---·--------- 

# -ft-=1 Degree i.ndic.atitlg level position for determining o: 1 Hnd o 2 

# /"

----- 

### {J I 

### (-5' 

## :S fJ1

**~** 

### +5') 14 

## t

. 

### ----·--- 

## p, (-5'

**~** 

## p,

**~** 

### +5') 

# '" __/__:__

# ___ y 

# 0



# -- **-~-·** 

# e D Degree indicated level position for determining 

## n1

**and~~** 

### Z=A tan 1 (< 

### 0.125'? 

## D ·--···---- W=A

**tall@(~** 

### 0.03125'7 

## ()

**D,(3116"~D,** 

### ;SJ/8") 

# o. -:;75 Degree indicnting level position for determining of0. 

### A 

# -ro -'1ii?i AI2D, (1.05 

### < P /Dr < 

### 1.50) c-;-;;----- - - 

# ;. 2jJ"t

!/temperature sensor i..r.;jlush with 

# _____y pitot tube

**ope~tiug,** 

### is Z 

### >% "? Degrees indicating level pn!::itiOll for determining y th.:o:n calculate 2 

## If temperature se1tsor 

### is set back from _p_itot tube Qpenlne, is W 

### > 2"?

**IsX~-%"for.l)Jl =~"**  

### [ Is itnpact side ofpitol tobe even with 

# /1/ 

# y

·-- 

# y I or abQt'e nozzle entlyplaue? ___ 

### --c

# y QA!QCCheck 

# i ls 

## 1'?:. 3" for 3/16" < Dt < 3/8"? '

. 

### Completeness

**::.---~** 

### · Legibility 

### Ac:cmacy- SpeCificatiOns Reasonableness 

# ---- Certification I ce1tify that the TypeS pitot tube/probe ID 

### # 

# 59 meets or exc:eeds all specifications> criteria and/or applic.ablc de-sign features and is hereby assigned a pitot tube calibration factor

**~** 

### of 1

-

- . . . 

### 0.84. 

# ,..-f -. . ,; " /j
. . . Cel1ifiedby: 

# (;0e.,_.-ffjt-1£t.. /1-21:,-0<j 

# /yv/

**i~~~:tRr->** 12-.:l-c:u-; Per_}6nncl (Signature/Date) Team Leader {Signature/Dote:) 

### 1 This certification a.lso applies to the specifications ofEPA Method 2, section 10.1 A.l.l regarding 

### inteT-component spacing of pitot tube-sampling probe assemblies. Refer to the figures on the reverse side of this page for specifics. ATC Form 37-PJimary S·type PitcH Tube 

### Cafibra\ioruH•ersion 3.0 September 2007 ATC@ (800) 733·3193
ATC PROJECT No. P-1 0142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 652)> c **~** " e5 L rn 0 -< z 0 **~** 0 ... "' G) ern en"

"""'

>o en"'" rnS::rn -ozs: -<-<- rnenen **~~5** "'"'z

. -<

"'en'" **~>en** or-< (ii-o

"'"'

co ;lJL -<'" "0 s;"" **~** "' )> " "

rn z 0 x " )> G) rn z 0 "' "'

'"' **~** Thermocouple Primary Calibration Data Form

Calibration Date II

- Z "? -oq Thermocouple Number 59

Ambient

Temp., °F c;, '-{

Barometric Pressure, inches Hg ;?'(. 1 5" - Kl!5vr'/J.c::<Df3't-S ······· ·-- ···········--- ·-·-··- .. , F 7, r-g. F'l

Reference

Source Reference Thermocouple Temperature

Point (Specify) Temperature Potentiometer Difference, %

Number

°F Temperature, °F (calculate in Kelvin)"

1 Ambient Air G cf'F (;, .5""

- 0. 10 I

2 Ice Bath'-IO'P**L/Z~-::**

-o. ··fo•>

., .0

3 Thelco Oven 3 I t...;r- ::n::: •""

- o. zr:,. o

i.___ --- -- -------- **-----------~..::...:...** ----------- **------~···** ----------- L___ __ **---~-~---~---** -

1 Reference thermoineter

.. mercury in glass
"Type of calibration system used

3 =[(Ref Temp, C+273) ·Test Temp., C + 273)/Ref Temp, C + 273]'100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QA/QC Check Completeness /Legibility ./Accuracy Apecifications v'Reasonableness /"

• /"). I Checked

by: !(t.t-;( (;.;jd,._,

it- ?c:co") Cqlibration Technician (Signature/Date)

ATC Forrn

**209~Primary** Thermocouple Calibration Rer,ard
version 2.1 May 2009 lA **Lt.;~_** J?srb

i£c\ **+~1**

Test Team Leaaer (Signature/Date) F:\Work\AJI Forms-

... \2090-Primacy thermocouple CalibraiJons.x.ls ATC (800) 733-3193 "'

0 **~** r "' , (i " en

# ( BORAL BRICKS 

# Analytical 

# Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

Degree indicating level position for deteJmining 0::1 and U2·

Degree indicuted level position for detetmining (h and fh.

Degree indicating level pru.ition for dttcmlining 

### ore.

**IY~** 

### ( ..

**~- .:::':::=--.::-:~.;:;**  

### - -


# .. 

# .

**Degree~** indil::a1ing level position for detennining y then calculate 7.. 

### Level and Perpmdicular? Obstruction? Damaged?

-- ar 

### (-1{/' ::C::a1::C::+f(/') ··------------ 

# a, (-1{/' 

## :S a,::::+J0') 

# p, (-S' 

## :5 Pr :": 

### +5') 

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## :5 

# p, 5 +5') 

# 'Y 

# e

-

**z~A** 

### tan 7 

### (< 

### 0.125") 

# -·

**W~** 

### A 

### tan I?J 

### ('5; 0.03125 ") D.(3iJ6"'5;D, '5;318") 

## -· A 

### AI2D, (1.05 :!;P,ID, :":1.50) If 

### temperature seusor is flush with pitot tube openiltfl! 

### is Z >X"? IftemperatuJ"c sensor is set backfrnm pitot tube opening, is 1¥> J»? 1 **IsX~-%-"forDn :::~"**  

### !Is Impact side ofpitot tnbe even with 

# l or above uoule etttrp 

### plane?

Is **~3"for3116"<Dt<3/8"?** ·-- 

# ·v / 

# N 

# tJ 1---·---

**~~** 

### I f-·---- 

# /' 

# z·

**2~** I 

# 6 

# 0
----- 0 0 

# o. 37.! 

# o. '115 /. Z{<f

-·- 

# y N



# --- 

# y

-- 

# y 

# t QAIQC C/reck Completeness / Legibility ...->"'}\ccuracy



### ~ Spec1fications 

# -· Reasonableness__ _ 

### Certificatiou J certify that the TypeS pitot tube/probe lD 

### # 

# ------'-'8'"'2._ _____ _ **meet~** 

### or exceeds all specifications, criteria and/or appiicab1e 

### design features and is 

### hereby assigned a 

### pitot tube yalibJ:ati\)11 

### fador Cp of 0.84 1 • • 

# /! ,..; . .

**~** 

# /] . . • . ·c . ·fi 

### db·. 

# c?fie . 

# i

**fx<~** 

# 11 

# -25 -b 

# '1

**~---~** ufaA.J__j_Z-8 

# -c '? .e1t1 1e 

### y. _ .. . ,

· · -

**~** Pcfsonne! (SJgnaturt:/Datc) Tct:nl L¢acier (Signature/Date)



# ---·---------- 1 

### This certification also applies to the ;;pecifications ofEPA Method 2, section 10.1.4. 1.1 

### regarding int6--component

**sp:~cillg** 

### ofpitot 

### tube--sampling probe assemblies.

**R~fer** 

### to the figures on the reverse side ofthis page for specifics. ATC Form 37-Primary S-type Pi tot Tube **Ca.Jibrations-vcrsio~** 

### 3.0 Sei)tember 2007 ATC@ (800)

**733~3193**
ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 654i: "'<

0 "ll "' 0 **~** m <::1 z 0 :!: "" ... N G) em <A" ..;> :t>(i (f>"ll:U mr;;m

"llzS:

-<-;-

m(f>U> **~.f>o.~** m"o **:u~z**

. -< Nrnm **~}:>(/)** or-< (ji"ll "'"'

co **:u~** -<[!l "-< r;; **~** 0> :t> "ll "ll m z 0 x **~** m z ? "' **~ ~**  Thermocouple Primary Calibration Data Form

Calibration Date i1

A /tf" c r Ambient Temp., °F 5{" Thermocouple Number

. 1?.;2 **-......,;:.,-~---** Barometric Pressure, inches Hg a 1

.. 5 I

**~** .... **~'.':"'** T.B-

_- _ _---·------- - **··-····-··---~-** \------

.. , F7

Reference Source' Reference Thermocouple Temperature

Point (Specify) Temperature Potentiometer Difference, %

Number

OF Temperature, 'F (calculate in Kelvin)'

1 Ambient Air 56jj

5 5 1 ' o. ;;,o "1

c

2 Ice Bath 1-fl)' ?I" 0. 3':J.I}Ia

3 The_l_c_() Ove_flJ____-:2<1 0 "-·· 2fi'"o

0.

**3~s>''fl;>**

. - --------- __ ._ .. --- ---- _.____ ___________ **~--** . - ----

1 Reference thermometer-mercury in glass

2 Type of calibration system used '=[(Ref Temp, C+273) ·Test Temp., C + 273)/Ref Temp, C + 273]'100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QA/QC Check Completeness /

**Legibillty~Accuracy** ./

**Specifications~Reasonableness** /

,._.,:! "") Checked by:

**(1-~"'f** iJ£,_:iJ&n. 12-t4·c<f Calibration Te$hnician (Signature/Date)

ATC Form 209-Primary Thermocouple Calibrauon Record
version 2. 1 May 2009 f, J. **~:0\.LO~ JYl'fJ~**  TestTeam

Leader (Signature/Date) F:\WorK\Ail Forms-

.. \2090-Primary thermocouple CaUbrations.x!s ATC (800) 733-3193 "'

0 **~** r "' "'

(i 1:iBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type 

# S Pitot Tube Inspection Sheet

Degree indicating hwel position fur delemtining 1:1 1 and a: 1 .

D!!gree indicated level positiOli for determining

**~~** and 

## P 2 .

Degree indicating level position for &termining of0.

**Dtgr~** indicating Je1·cl position for detennilling y tl1en calcldaie 

### z. 

## QAIQCC!teck Comp 1e-teness .....,/ 

### Level and Papendicular? Obstruction? 

## 1------·-·· Dantaged?



# - a, 

### (-!If' :5; al:;:;+l(/') 

## f-·

([2 

### (-1{/':;:; at::;+J(/') 

## p, (-5' :5; 

## p, :5; 

### +.5') 

# P1 (-5" :5; 

## p, :5; +5') 

## y @ Z=A 

### tan 7 (< 

### 0.125'') 

### W=A tan 

# e (:;:; 0.03125") D,(JIJ6":5D, :::;318'') A 

### A/2D, (1. 05:::; PAID, 

## 5 1.50) 

## If

temperature sensor isflush 

### wit"- pilot tube opening, 

### t's Z >% 

### "? 

### lftemperaJure sensor is set back from _pitoJtuhe open ina, is W> 2"? 

### Is X::-%" for Dll =M" 

### Js impact side ofpitot tube e1-•en wftlt or above liOl,t.le entqp_[ane? Is Y?;, 3'•jor

**3/16~'** < 

### Dt <318"?



## - 

# ------- 

# 7 N f/ 

# ;o i" C.J 

# 6 D 0 0 I 

## {)



# 0· 

# 37¥ 0.11 

# f. 330



# y jl/ 

# r--_L..__ 

# y "'-' 

# / ------·

1 

### This certification also applies to the specifications of EPA Method 2, section 1 0.1.4.1.1 regarding inter-component spacing ofpitot

**tube~sampling** 

### probe assemblies. Refer to the figures on the reverse side of this page for specifics. ATC

**Form37~Primary** S·type Pilot T11be Calibrations-version 3.0 September 2007

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 ATC@ (800) 733-3193

APPENDIX PAGE No. 656J> c "<

0 -u ;o 0 L m 0 --< z **~** i: :1 ... " "m C-u CijJ> J>() "'""' **m~m** -uz.:: --<-;-

m<n"' **~.0:0.~** "'"'0 **~Oiz** • --< "cnm **~,_en** or-< (jj-u

"'"'

co ;tJL -<m -uo **~--<** z --< "' J> -u -u m z 0 x **~** m z **~** "' "'

... **~** Thermocouple Primary Calibration Data Form

Calibration Date 11 **~/4·~0'1** Ambient Temp., °F SY;;.

-- -- •. - ·-rg

J •• , Reference

Source Point (Specify) Number 1 Ambient Air

2 Ice Bath

3 Thelco Oven

1 Reference thermometer-mercury in glass
'Type of calibration system used Thermocouple Number ?{ 1-f **----io~----** Barometric Pressure, inches Hg 2 <:J, S 1

- --.- • **-''.'""'~·-** ••• -· ••• - •• ·-·-· **\-,~-** ·- •· I .F1 Reference Thermocouple Temperature! Temperature Potentiometer **Difference~** %!

OF Temperature, °F (calculate in Kelvin)'!

5'1° **s~-t** ,. 0&/,.

40p ·""")Q <;

)1 0.

**:J...~•Je,**
**2~d"'**

271?"

0. ?Ji.:e "l.,

**'~[(Ref** Temp, C+273)- Test Temp., C + 273)/RefTemp, C + 273]"100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QA/QC Check Completeness **,/Legibility__L_Accuracy~pecifications__::::Reasonableness** /
Checked by:

**d'l.~,;r** !5liMq.n /1-lt..;-tr'l

- - - - - } - - (Signature/Date)

ATC Form 209-.Prim.ary ThermocoupJe Calfbratton Record
version 2.1 May 2009 (A)_ **tL~~ f~**  **l~/t'-1/o"l**
Test

Team L..eaoer (Signature/Date) F:\Work\Aif Forms-

... \2:00Q..Primary tl1ermoco!Jple CallbraUons.x!s ATC (800) 733-3193 Ol 0 **~** .- "' ;o 0 i:iBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet



# -- Level and Perpeltdicular? 

# y

--

Obstructimt? 

# N Damaged? 

# N a, (-10"::; 

### al:':;+lf!') IC I 

### 1--- Degree indicating !evt:l pmition for determining o 1 and a 1• 

### a 1 

### (-If!' :5;az:5;+lf!') 

# I c f-----



# h (-5" :':; 

## p, :':;

**+)~)** 

# ?" p, (-5" 

## 5 

## pl 5 +5") 

# !"

--
Degree indkated

**le~·eJ** position for

**determining~~** llild

**~l**

Degree indi"nring level po:c;ltion for detem1iJ1ing 

### ore.

,, _,1. ::- 

### r;:::-::-: 

# :::,:..:=..d,
- - • Degrees uHiit;ating le-.·el position fur determining y thl!n ca\clllate Z. 

## 'l 

# e

**-----~----------·-·** ·-··------ 

### Z=A 

## tan y (< 

### 0.125 

# '? W=A 

### tan @(:5;0.03125i") 

### D, (3116" :5;D, 

## 5 318'?

·-------------····-------- 

### A 

### A/2D, (!.05 

## 5 p_,!D, :5; 1.50) 

## If

temperature sensor is flush with pr'tof tube oe.ening, 

### i!l' Z 

### >Yt'"? 

### lftempetature sensor is 

### set backf,.om oitot tube

**ope11i11~,** 

### is W 

### > 1"? ls X2: %''for Dtt =V:r·'' 

### ls impact side of pitot tube even with o1· 

### above nozzle entry

**J!..~mre?** .l.r:; 

## Y?:. 3" for 1116" <Dt < 

### 318''? 

# 0 {) 

## 1---------- 1) 

# 0 

# 0.375 o. 'I '-{-2 

# {2S6- 

# y /'/ 

# y 

# y f QAIQC Check / Completeness

**~** 

### Legibility



### ~__......,.,.Accuracy ·- Specifications ___.., Reasonableness ---··· 

### Certification 1 certify that the Type S pitot tubefprobe ID # 

# 85 meets or exceeds all ·specifications, criteria and/or applicable design features and is hereby assigned a 

### pilOt tube calibration factor Cr of



# ~·r.db .. 

# "--:v. qf;. 

# 1/-15 ··C>/ 

# J?A



# (~/j-"-"~ Jz-ff



# ~r.:Jfi' . enLte y. t. Te«m Leader

**(Sign~:~ture/Date)**

t 

### This certification also apphes to the :>pecifications of EPA Method 2, section 10, 1.4. 1.1 regarding inter-component spacing of pi tot tube-sampling probe 

### assm11blies. Refer to 

### the figures on the reverse side of this page for specifics. ATC Fom1 :l7-PrimaJ)' S-typc Pitot Tube Calibralions-ven;io.n 3.0 September 2007 ATC@ (800) 133-3!93 

### .

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 658 

# 1"'< 0 , ;IJ 0 L m ':1 z 0 E "l ... "' )> c Clm c, **~)>** "o "'""' mS::m "1lzS: -<-.<- m"'"' **~~~** ::tl 5" --i "'"'m **~);>Cf.l** or-< 1ii"1l "'"' co **;IJ~ -<~**  "-< s; z -< "' )> , , m z 0 x , )> Cl m z 0 "' "'

<0 i Thermocouple Primary Calibration Data Form

Calibration Date /2 '1'/

- (,!J Ambient Temp., "F '?•i" Technician T.l3 Reference Source 2 Point (Specify) Number 1 Ambient Air

2 Ice Bath

3 Thelco Oven

1 Reference thermometer-mercury in glass
'Type of calibration system used Thermocouple Number ?5 Barometric Pressure, inches

**Hg---~:-:,,::::9;-."'l.J,.,.;/----** Reference Thermometer (List ID #) 1 ;:·7 Reference Thermocouple Temperature Temperature Potentiometer Difference,%

"F Temperature, "F (calculate in Kelvin)'

**SLJ~>** '-.("'

.)

, ·- ('). lol 0 /o

i-11)0 37" () ?:>d"k

. 0

2. '10.

**4)7~0** - - ..

- Q, S__'2l_D I"-

-

----- ...:; " I ----

3 .

=[(Ref Temp, C.,.273)- Test Temp., C

.,. 273)/Ref Temp, C + 273]'100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QA/QC Check Completeness **o/iegibilityLAccuracy~pecifications** ._/'Reasonableness /

;•-' 7 Checked

by: i-..;.,.1 /5

•. **~** !1-14-0J Calibration T4nician (Signature/Date)

ATC Form 209-Prirnary Thermocouple Calibration Record
version 2. '1 May 2009 /;, ). **~L** R/191._,.___ r:-f (Y

r (} 1

Test Team Leacfer (Signature/Date) F:\WorkWI Forms-

... \2090-Prlmary 1hennocouple Calibralions.xls ATC (800) 733-3193 "'

0 **~** r "' ;IJ 0 "' (/)BORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

**D~!gree** indiclltirtg level position for determining 

### o. 1 ood a,..

Dcg,tee indicated level position for determinir.gfJJ and }h.

Degree indicating level position for determining of B.

Degrees indicating levd position for determining 1 then calculate 

## z. 

## QAIQC Check Level andPerpendicular? 

# ----- Obstmctio11?

**~·**



## Damaged? 

## a, (-iff ::: 

## a]:::+1 (/') 

## a, (-10' 

## ;:;u.,;:;+lff) 

# p, (-5'5 

## PI::: +5') 

## p, (-5'::: 

# p,::: +5') 

# 7 @



# -- Z=A ta117 {.< 

### 0.125")

**W~A** 

### tell!@(::; 0.031Z5") 

## D, (3116" 5 

## D, ::; 318'? A 

### A/2D, (1.05 

### :!;P#D 1 

### ::,1.50) lftempmtture seusor is flush with



## . oitot l!the oveninJ!. is 

## z >'),"?



### I[temperature sensor is set back from 

### Ditot 

### tube open!!J:& f.s 

### W> 2"? Is X?:, "A"for 

### Du **~"** 

### Is impactside of pilot tube even with or above noa;le entrv plane? 

# u Y?:. :!"for 3/lli" <Dt < 

### 318"? 

# y N N

I , 

# ----- 

# r
/ 0 

# 14 0 

# o__ {) 

## 13 (!. 

# )75



# 1}.1/'l. 

# l.?d

y N tJ/A 

# N/4



# All4 Completeness
**~-** 

## - **Legibility~-** 

### Accuracy ...-· Specifications 

# -- Reasonableness 

# -- Catificatiolt v

# 3 I certifY 

### that the Type S pitot tube/probe ID # **~--_:d::_:----~---~** 

### meets 

### or exceeds 

### all specificatioru, crite-ria and/or apPlicable design features and is hereby assigned a pitot tube caHbration factor 

### Cp of
0. 84l 

# "1" 

# v /::' :/, /_.? . 

## .o : · ...: 

## r \("- L J · ... 

## l / { C "fi • · 

## ,11

**~** l 

## OU/ { 

# f- 2 ::> 

## ·-t• 1 1 

## :.uA , /,_v'("'-'-i/1 

## I'L tl ;1



## --~~ 

# . Team Leader (Signalure/Oate)

- 1



### ._'_This certification also applies to the spedtications l)fEPA Method 2, section 

### t0.\ 

### .4. \.1 regarding **inter~component**

**:~;-~pacing** 

### of pitot tube-sampling 

### probe assemblies. Refer to the figures on the reverse side ofthis page for specifics.



## ·:·\~\KTc Form 37-Primary S-typc PitotTube Calibrations-version 3.0 Septemher 2007 ATC@ {800} 733-3193

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 660)>c"0;ot'mz'"....NGlem"'"_.,J>(j"'""'m"'"'m"'o"''"z....N"'mS:J>Cilor-<(ii-o"'"'co..;m-o"...z..."')>"0"0mz0xmz0"'"1(ThermocouplePrimaryCalibrationDataFormCalibrationDatet:Z-ZI-<>'1AmbientTemp.,°F5;z.oTechnicianTG.ReferenceSource'Point(Specify)Number1AmbientAir2leeBath3ThelcoOven·1Referencethermometer-mercuryinglass2TypeofcalibrationsystemusedThermocoupleNumber?IBarometricPressure,inchesHgJ"/.'79'ReferenceThermometer(ListID#)1;::::"-7ReferenceThermocoupleTemperaturePotentiometerDifference,%1OFTemperature,oF(calculateinKelvin)'!sJ·5o¥D.VJ,#Io32•33'-0.53°/o/J'{>o1774vwf.c%·-·-------------•--------------------------·'=[(RefTemp,C+273)-TestTemp.,C,.273)/RefTemp,C+273].100<1.5%Kelvin=(519)•(F-32)+273.15QAJQCCheckCompleteness/Legibility/.Accuracy/Checkedby:',/J-:2/-tli/M.....jOUv.t.-(l.0-JJ'1CalibrationhnicianestearnLeader(Signature/Date)(Signature/Date)ATCForm209-PrimaryThermocoupleCalibrationRecordversion2.1May2009..tF;\Work.\AUForms-,..\2090-PrimarythermocoupleCalibrations_x:lsATC(BOO)733-3193"'0r"';o""'<JjBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

Degree indicating- kvel position fur detemllning £4 and n1 .

.-. ·._· -. .
Dc:gtee indicated level positio11 for determining**~~** and 

### fh.

Degree indicating level position for determining of 

### e. 

# 77EJ Level and Perpendicular? Obstruction?



## ·--- Danza
.. !fed? 

### a, (-10":: al::;+l 0") a2 (-10".::; a,.::;+JO") 

# p, (-5'.::: 

# fJ,::: +5') 

# P1 (-5'::: 

# p,::: +5') 

# y 

# e Z=A tan 7 (< 

### 0.125") W= A tan fJ (:5; 

### 0. 03125'') D, (3116" ::;D, ::;318") A AI2D 1 

### (1.05 

## .S P,,ID, 

## :5: 1.50) 

## If

temperature sensor is

### flusII 

### wit/r. pilot tube**openin~,** 

### b;.**Z>~"?** 

### If

temperature sensor is set 

### hack from pitot tube openina, is W 

### > 2"?**1-tX~** 

### %;"for Dn =%,, I

Degrees indicating Je\'el position for cleterntining y tlltO calcl1late 

## z. Is impact side ofpitot tube even with-- or above nozzle entry plf!pe? 

# y N N 

# ;o I" 

# c.> 

# 0 0 0 0 {) 

# (). 37¥ 

# 0.1'15 

# f. 

# 330



# y f\1 

# _L __ 

# / QA/QC Check Is 

## Y?. 3"for 3/16" < 

### Dt < 

### 318"? / 

# J
--. 

# ---------- ---· ----·- Completeness / Legibility 

### SpecificatiOns**~-~ Reasonableness~**  

## Certification '"?u 

### l certify that the 

### Type S pitot rube/probe 

### lD # 

### ¥o meets or exceeds 

### all specifications, criteria and/or applicable design features and is hereby assigned a pi tot 

### tube calibration factor CP of 0.84 1

. /"-

# ~- {:' 

# /, ·it -kn.

# !f-2~"-o**.** ' 

# I _"· 1

# :c.../_ -cr.:? Certified by:

## ~ · - ' :l '

## ~ - 

### ·-fC:L.i'r1 

## /2--- 

## 6 ' 7 el (Sig.nature!Droe) Team Leader (Signahlre/Date)

1 

### This certification also applies to the specifications of EPA Method 2, section 1 0.1.4.1.1 regarding inter-component 

### spacing ofpitot**tube~sampling** 

### probe assemblies. Refer to the figures on the reverse side ofthls page for specifics. ATC Form 37·Primary S-type Pltot Tube Calibrations-versiorJ 3.0 September 2007

ATC PROJECT No. P-10142 EPA JCR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & s. SALISBURY PLANT 6 SEPTEMBER 2010 ATC@ (800) 733-3!93

APPENDIX PAGE No. 656 ·BORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet

,, Degree indicating level position for detem1ining a1 a.'ld a2-

Degree indicated level position for detenninlng

**~~** and Pl.>

Degree indicating level position for detcrulining of 

### e. 

# ;;.--z

**~-- +~--**  .• 

# . Dtgrees i11dlcating level position fQr detcnnining y then celculate 

### z. 

## QA/QC Clteck ---- 

## Level and Perpendicular? Obstruction? Damaged? a, (-10':::: a1:::+10') a, (-lrl':::: a2

## :0+lrl') 

# PI (-5':::: 

# p,:::: +5") 

# p, (-5' :5 

# Pz :5 +5") 

## '! 

# e

**z~A** 

### tan 

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**0.115'~**

**w~** 

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### e 

## (:5

**0.03115'~** 

## D, 

## (3116" :5D, :::: 

## 318'? A 

## AI2D, (LOS:::: 

## P,.ID,:::: 1.50) Iftempernture sensor is jluslt 

## wltlt pilot ftlbe opem'u,f(, Is Z 

### >%"? 

### Ifumperature sensor is 

### set hack from pilot tube opening, is W> 2"? h X;! 

### Y-t"for Dn 

### ='h" 

### Is 

## Impact slue ofplto/ /t{be eve1r 

## will! or above 11oule e11tn nlane? Is f?:.3"for3!16"<Dt<318"? 

# y IV 

# IV



# '0 ' 

# ,c I


### _......., t. .i.

'I.> 

## I A (/ 

## i./ 

# 0 

# "'' v



# .

**~--x** 

## 0.5 /....,

_

### ...... 

## ....,. 

# .. 0.

**~** I{.

s 

### i{C /-. 

# . )



# / ;J '/ / 

## y /



# - I 

# l Completeness v/ / _.-- 

### Legibility .,./ Accuracy 

### vr Specifications ..

**~** 

### Reasonableness ..,..,..- 

## Certification """' I certify thatthe Type S pitot tube/probe l.D 

### # 

## 6 

## i meets or exceeds all specifications. criteria andlor appllcable design featw·es and is hereby assigned a pitot tube calibration factor Cp 

### of 

### 0.84 1 

### /';f r. 

### 0

**/f··JL~.-,•j<'7J** C <'fi db , 

### .;.·LJ.:..""-'"'"~t-e<·if,_. _:.:V:..'.:.[7V.fi"P.:.V_.:1:_Z.:.,·_·__ 

## o __ **~_·_,;_** Chi 1e 

### y.-



### Pers~nel (Signature/Date) Team Leader (Signature/Date) 

### 'This certification 

### also applies 

### to the specifications 

### ofEPA Method 2, 

### section10.L4.L I regmding inter-component spacing ofpitot tube-sampling probe assemblies. Refer to the figures on the reverse side ofthis page for specifics. ATC Fonn .37·Primary S-type Pilot Tube

**Calibrations~version** 3.0 September 2007 ATC@ (800} 733-3193

ATC PROJECT No. P- 10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0 APPENDIX PAGE No. 662> "'< () " "' 0 **~** m

<::1

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**~** § em (fl'TJ __,, >c;

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c;;..; " ..; "' !(; 'TJ

m

" 0 x **~** m

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?

"' !:!: Thermocouple Primary Calibration Data Form

Calibration Date I 1 **~ 14~**  () '1 Ambient Temp., "F S'-1 c Technician ''1":- B.

' .,r Reference Source Point (Specify) Number 1 Ambient Air

2 lee Bath

3 Thelco Oven

---- -----------------------------

1 Reference thermometer-mercury in glass
'Type of calibration system used Thermocouple Number )? l-f **-~i----**

Barometric Pressure, inches Hg 2 q, <; 1 Reference Thermometer (List ID #) 1 F "' Reference Thermocouple Temperature Temperature Potentiometer Difference, %

"F Temperature, oF (calculate in Kelvin)'

5'1¢ Stt '' oct,.

40P **·~Q~ o.~·;.,,** 

)l -

-;; 9<) 6 "27f't} 0 :;l• fl(

..-' ·' ------ ------- -· --- . - -------- **-------~** "----"- - __ _,_:::.2_\g ___ ,;, - - --- -

3 =[(Ref Temp, C+273)- Test Temp., C + 273)1Ref Temp, C + 273]"100<1 .5%

Kelvin= (519) • (F-32) + 273.1$ QA/QC Check Completeness **v'Legibility_LAccuracy~pecifications___::::Reasonabteness** /

/'-;/ - /7

Checked by: **d\t~,;r** 6t.:'M1• canoratlon TeFJinlcian (Signature/Date)

A IC Form 209-Pr!mary Thermocouple CaliOratlon Record
version 2.1 May 2009 l'l-JI..J-IJ'I \A} 4JJ- **f~** 1?-/1'1/oa;
Test Team Leader (Signature/Date) F':\Work\AI! Forms- ... t2090.Primary thermoGoup\e Catibralions.xts

ATC {800) 733-3193 "' 0 **~** r **~** Ci

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e:

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0

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0 **~** :1 .... N Gl em "'"" _.,

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,

,

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'"' Thermocouple Primary Calibration Data Form

Calibration Date ;2 - 2;- Oy Ambient Temp., °F 59•
.n T.i3. Reference Source 2 Point (Specify) Number i Ambient Air

2 Ice Bath

3 Thelco Oven

1 Reference thermometer-mercury in glass

2 Type of calibration system used Thermocouple Number [/9 **---=~~--** Barometric Pressure, inches Hg 2 '1. S I

. ·-·-· ----- . -·------------· \------ .. , F]

Reference Thermocouple Temperature Temperature Potentiometer Difference, %

OF Temperature, °F (calculate in Kelvin)'

5'1" Sir ...\l3.1J"L.

2 'Jo 31° -0 jg_to"/o

; 8o· li'20 - Q,_J.jlj <Jo

'=[(Ref Temp, C+273) ·Test Temp., C + 273)/RefTemp, C + 273]'100<1.5%

Kelvin" (519) • (F-32) + 273.15 QAJQC Check Compieteness_i Legibility · VAccuracy_LSpecifications /Reasonableness /
Checked by: fk,,a-Cv::;;;en, 12-21·tJ7 Calibration · · · (Signature/Date)

ATC Form 209-Primary Thermocouple Calibration Record
version 2.1 May 2009 lJ **t~P. ='2/wo~** 

Test Team Leader (Signature/Date) F:\Work.\All Fonns- ... **1.2090~Pfimary** thermocouple Callbrallons.xls ATC (BOO) 733-3193 !D 0 **~** r-

"' :0 0

" UJBORAL BRICKS 

# Analytical Testing Consultants, Inc. Primary Type S Pitot Tube Inspection Sheet**,-~-r**

# ~~**U--~** 

# U ' " ' I**L_~** Degree indic-.1ting levd position for determining 1,1 1 and u. 2•

Degree indicated level pmition for dctcm"rinin.g P1 and 

### fu.

Degree indicating level pusilion for determining of 

### e. 

## 0

-li· 

# 1

.------- <- 

# ,_____ ( 

# ·'------------ "-!

# jL~~el ami 

### Perpmdicular? Obstntction?

--**-----------------·---~--** 

### Damaged? a1 

### (-Iff :5;ai:S+lff) a, (-Iff 

## :5 a,:':;

### +I If') 

# r--

/JI (-$" 

## :5: 

## /JJ :5 +$") 

## p, (-5' 

## :5 

## p, :5: +5') 

# .. y 

# e Z=A tnn y 

### (< 0.125 ")


## _____ ._



### W=A tune 

## (:5 0.03125") D, 

### (3116" 

## :5 D, 

## :5 3/8 ,,



# --------- A

------ 

### A/2D, 

### (1.05 :5;P 

### ,.ID, 

## :5: 1.50) 

## If

temperature sensor is flush with l!...itot tube oneni.nv. is Z >'4"? 

### If

temperature sensor i's 

### set back.from 

# y N 

# il r ;c I 0 6 

# 0 C) 

# 0 

# 6 

# o. 37')

--- ,1, 

# J"('f 

# j. t=/'2. 

# y 

# N -

·--



### _p_j_tot tube**opell!iJ:,~** 

### W 

### > 1"?**------~ J~-**  

### X?:. Y.t"fiJr 

### Dn =!6" 

# .L ! Degree:; indicating le"l'el position for detcm1ming "!then cakulaLe Z. 

### Is impact side of pitot tube eveJJ with 

### or above 

### Itt! We 

### entt:f.J!!p.ne? 

# _)"
_ 

# __] QA/QCCheck Is 

## Y?:. 3" for 3116" < 

### Dt <3/8"? 

# y Completet1ess V**~-** 

### -- Legibl"Jity "-./ Acc.macy ;._/ Specifications

### ~ Reasonable-ness t_.../ 

## Certification 1 certlfy that the TypeS pitot tube/probe ID # 

# 89a meets or exceeds all specifications, criteria and/or applicable design features_and is 

### hereby assigned a pitot tube calibrailon factor Cp 

### of 0.84 1

. · .. ..¢ . . ·.. ...-, 

# d/'e.,i ,bc•AU.",n- I{-- 2 £; 

# -o 

# '1 

# !{.j**(~~~** 12 

## ··if 

# -o9 Certified by: ---L. 

## "--L-"""-"-'-!-""':::.;71";;p;.-""''-'-L1...-'"-·-'---='---'-
_

- .

## Pet·s~el (Signature/Dale) Team Lcaqcr (Signature/Date)

1 

### Tills certification also applies to the specifications of EPA Method 2, section 10. L4.L 1 regarding U,.ter-component spacing ofpltot tube-san1pling probe assemblies. Refer to 

### the figures on the reverse slde of this page for specifics. ATC**F~.<rm** 37hPrimat)' Shtypt:: Pi tot Tube Cu!ibrations-veuion 3.0 September 2007

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 ATC@ (SOO) 733-3193

APPENDIX PAGE No. 664 

## I !)> c **~** -u **~ ~**  m

'1 z

0 **~** '=

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em

"'" -;» l>o "'""' m);m -uzs: -<-;- mUlUl **~,f:o~** m"'o "'"'z

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z

-<

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'0

'0

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0

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?

"' "' "' Thermocouple Primary Calibration Data Form

Calibration Date / Z - f 7 **~** 6 /' Ambient Temp., °F 6do Technician -r: S

·-

Reference Source' Point (Specify) Number 1 Ambient Air

2 Ice Bath

3 Thelco Oven

1 Reference **thermometer~mercury** in glass

2 Type of calibration system used Thermocouple Number ?1 <'1. Barometric Pressure, inches Hg 2 '/ .. 51 Reference Thermometer (List ID #) 1 t=.,..

' ' Reference Thermocouple Temperature Temperature Potentiometer Difference, %

'F Temperature, 'F (calculate In Kelvin)'

**cg~**

. .J 60c - (:) l.c!_D **~**

'10 {) **36~ 0**  0 t,L)•Io

2'ftJ Q 2ST' o. S3•1 ..

'=[(Ref Temp, C+273)- Test Temp., C + 273)/Ref Temp, C + 273].100<1.5%

Kelvin= (5/9) • (F-32) + 273.15 QAJQC Check Completeness / **Legibility~Accuracy~Specifications~Reasonableness_::::..**

,r-.7 -?':1 Checked by: **?~.-;/** t:Jt-v/.ft?.t !.2 ·/tf -t/1 Calibration Technician (Signature/Date)

ATC form 209-Primary Thermocouple Calibration Record
version 2.1 May 2009 't· kJ **~ P~**  iz./l'f/o'l
Test Team Leader (Signature/Date) F:\Work\Ail Forms· ... \2090·i>rimary thermocouple Calibrattons.xrs ATC (800) 733-3193 "' 0 51 ...

"' ::0 0

"' UlBORAL BRICKS 

## Primary Module Calibration Calculation bate:r.n== Pbar. Calibrations by Mallory Beam Wet Test Mete( Sertal No.: 175$2 Module ID:L-"=-'-l Prewtest Calibration Factor 0.963 Orifice



### t.H~~~es 0.5( 1.0( 1.5( 2.00 3.00 4.00 Orifice A.H (inches 

### Vw,rt' Jnitlal 

### 109.41 113.8: 126.3: 133.2' 151.11 161.1!
I minutes Ending 

### 113.50 119.56 133.04



# i~

**~.4** dH@ 1 Vd, ft3 tnitlaJ Ending



# ;~~ 32911 39.097 46.070 52.957 53.154 61.277 71.585 81.618 81.995 93.653

1.781 0.975l Specifications. (QA

**Handbook~Vollll** CD5·1, 9130/94) 

### Tw,

**~f** Initial 

### 55 

### 55 55 55 55 551

1) No value of .8.H@i shall vary from the average AH@ by more than 0.20. 2) No value of Yl shatt vary from Yavg by more than 0.02. 

# ( li.H) 0.031961! 

## I;+- 

# r J'

**dH@~** ' 

## 13.6 (t.+459.69)e



# ~J + 459.69) L 

# V,.P. .

QNQC

**Ch~X:k** Ending 

### 55 55 55 55 55 55 Td,

**~F** !nUl a! Ending 

### 57.0 57.0 57.0 

## 5JUl 59.0 59.0 59.0 60.0 61.0 61.0 61.0 61.0 

## •

/ Completeness __ 

### ,_1_ Clleck.ed by: **,~,.,-··** 

# (

;:

**v:::;::_r;~/**



# 1/_d;o Reasonableness ___ _ Team Leader (Signature/Date} •

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 666BORAL BRICKS 

## Primary Module Calibration Calculation
Date· Pbar: Calibr alions by: Mallory Beam Wei Test Meter Serial No.: 175$2 Module 10: '-'-"''-=----' Pre-test Calibration Factor'---_o,.oc97"7'-----' Orifice**~H** (inches H20) 

### 0.50 1.00 1.50 2.00 3.00 4.00 Ormes .O.H (inches 

### vw,te Initial Ending



### 56.39 61.87 62.43 70.24 70.47 79.71 79.91 90.93 91.37 104.98 105.16 120.86
minutes dH@.



### 2.084 

### vd,te Initial Ending 

### 275.837 281.567 282.149 290.294 290.537 300.188 300.391 311.915 312.371 326.604 326.792 343.233 y,



### 0.969J Specifications {QA HandbookNollll CDS..1, 9/30194) Tw, °F initial 

### 58 58 58 58 58 58

1} No value of .61-!@i shall vary from the average 6H@ by m<Jre than 0.20. 2) No 

# value**o~~~:h~::(ro;. Y:v~:m)olrethan**  0.0:.

# ~]' Y dH@ =

# --~----13.6 

# (t,, + 

## 4)9.69

# )e ; 

# (t" +459.69J. V,,Pb

QA/QC Check**Check~** by.
A.TC Fotm 34c.·P<Imary MocMe C•libr.alioo1 Recore!**~e.·~WO\** 4.0 Hove1nbt!r 2001} Ending 

### 58 58 58 58 58 58

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# I Td, 11 F Initial Ending 

### 66.0 66.0 66.0 66.0 66.0 67.0 67.0 68.0 68.0 69.0 69.0 70.0

APPENDIX PAGE No. 667BORAL BRICKS


## PRIMARY MODULE CALIBRATION CALCULATION

Module 1.0. ;-f 

### r-::.:_ '-/ Barometric Pressure, P 

## 2. c.? , 

# 1J 

### ::J Pre·test Calibration Factor,



## v~l I .DJ 0 Personn

### e Oat Wet Test Meter Selia! 

### e 

## i<C.F..-r (.;, C'-QG<.<, 

### '2.- iO- .2 .;>; ...) i 

### 75-l 

## z

v. 

## v, T. Final, 'F



# ~ Initial, 'F 

## r, Orifice Setting Initial, ft 3 FIMI, ft iai.ft,l Flnal, ft.l Initial, °F Final,

**~F** 

### 0.50

**Z7.6~** 

### I 

### JlVi'l

**(1~'3.** 

### :J& I <;{.··· 

## 36 ,'

**~..,L.** 

# .

**~** 

# (.· r,.o (.,tJ 

# &I 

# &3 1.00 

### 3'f. 2< 1 

## 1 ]'t.tJ30 

## 13>-3. 0/0 

## !Ski'-573 

## fPh v 

# &o 

# r:. 3 

# ks 1.50 

## <f(}.IJ:;- 

## 'fl. G<lo 

## -&!3. t&-11o {i

**75~**

## ..)-.zz._ 

# t;o ;;_, 0 {.:) 

# r.,·:t- -:- 2.00 

### i-ffo•·"11"1

**s~r.** 

## 'if3o 87<;,/3Z,;- 

### b'i3 

## 3. 

# ·'I'R (,.D 

# 40 (.,'f 

## b'f 3.00 

## -'"- 8'1'1 t,'( 

### csO 

## sil3. 6ZS !3'-73.2..4:;: 

## &o {p() 

# (:;y 7:? 4.00 

### G'i. 'ibO 

### Jr{. 131J 

## t'/'13. t.-30 

## lt.fol/.37:>

**&~** (,0 

# 72 

# 7'-f Speclflcatlons {QA Handbook-Volllt CDS-1 9130/94) 1) No value of ilH@! shall vary from the average llH@ by more thom 0.20



# ~ **~:~·** TIME



# ~ Y; 2) No value of Y 1 shall vary from the average Y by mor£J than 0.02. ng min.



## ' 

# I 

# I 

# (

**~H)** 0.03191lli P,+--- 2 

## dH@ _ 13.6 [ 

# (t, +459.69)0] 

# Va + 459.69) VwP,

.. 

# Y; 

# VwPJtd +459.69)

- 

# - vd(pb+



# ~)tw +459.69) legend Vw =Volume of WetTest Meter. 

# fe Vd = Volume of 

## Dry Gas Meter, 

## rf Tw =Temperature of Wet Test Meter, °F Td::: Temperature of Dry Gas Meter, °F 6.H@i = Pressure differentia! across the orifce meter, lr'l. !i.O Yi = Drj Gas Meter Calibration Coefficient, dirnenstonless

### 0.50 

## /() I, 770 

### 1.00 

## /0 /. 67i} 1.50 

## !0 

## i.tlas 2.00 jO 

### ;z.. Cll (, 3.00 (() 

### 7-t:<J§ 4.00 

## /0 ;z.o6o 

# I I qt;l

Ccmpleteness lsgibilily 

### /- 

# . Accuracy Spe.cificafions •/ .1,/..j'j - 

### .·\tt•·( (

**~~t.{IJU.i<·l** 

## 2 -I 0 .:_' i_cc'·-'-- 

# [ ' . ' ' 

### ("' [) 

### .A ) •



# ~- 

# t't.N•<-·- Signaturw: Technician (Signat\Jre/Date) Project Manager {S!gnatu:e/DEte) f, 0()'2- !)
. 

## '?CJ::l t!.q<J<;" (1. 

## 9'9</ o.'ro/Z 0 

### .ql?l"f 

# II o. 

# qq,-1

/ 

## v Reasonableness

ATC Fonn 34·f'rimary r.md!?.e CaHOr3tl<ul Record version 3.1 May 20(;5 **F:\Wgr'~\An** !"QfOIS·Flekl D<1lll

**~-Calc** FD!!llUi:se..**J34·Pri~** Mcdule

**C~~b..">16on** Rueord Slaii",qpH ATC (000) 73J-:3t93

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 669BORAL BRICKS 

## PRIMARY MODULE CALIBRATION CALCULATION

Orifice Setting 

## v. 

# v, Initial, ft! F(n.al, tt' Initial, tt' Fi11al, ft 3 0.50



# ~n~ **~~~-'\;:}o** 

# w9nst 76/.ciJ3 1.00



# ~~.a11\ 

# wn. OiO 

# J::J. 

# rf7S 7ut{.lJI7 1.50



# ~\lf.J\o **~Jf.ll3~** 

# []vz. H"'ilb 

# 'rl;t;H)!o 2.00 

# at..'7tc 'fJ>J. 

# no l7ts-_q'\5 i7Jt.llll'l 3.00



## ~3'5.<.1.o 

# S'ID~tl 7iJI/.4t"i' 

# !735. '/i).<;' 4.00 

# rb%- 730 1\)].

**73~** 

# 735:757 

# il/7. [.ilo Specifications (QA Handboak-Vollll C05-1 9130/94) i] No va\tle of AH@i shall vary from !he average

**li.H~** by more then 0.20 2) No value of Y; shail var-; from !he average Y by more than o.a2. 

## dH@ 

## 0 0319AH[P, 

# +



# ~:) [

# 0. :45969)e

# i &d +459.69J VwP• 

# Y. I 

## - 

# vw~(td 

# +459.69)

- 

# V,{Pb+

**~-}tw** +459.69) 13.6 Legend Vw =Volume of Wet Test Meter, 

# fe Vd =Volume of 

### Dry Gas Meter, 

## ff Tw::: Temperature of Wet Test Meter, °F Td::::: Temperature of 

### Dry Gas Meter, °F 

## Personne~l 

# Rtii{iiJ\ii. Date J 

# J

**JJ~IJJ.** 

# ¢1.'0 lO Wet Test Meter Serial 

# oil /75'/o 

# :J
r. r, lniJJa.l, Dp Final,

**~F'** lniti'lll, "F

**Fin:~!,~** 

# 7ff 

# 97 ;o;;L 

# tn·z. ' LJ 

# 'l 

# 'i9 JO) 

## JDll 

# 9"'1 I 

# '1 l 

# o'-1 1

**o')~** 

### tfln 

## I'DO 

## 105' !D7 100 

## loo \0( \09 

## )()i) 

## tllO [O'i 

## \\0
Orifice



# c:J~ Y, Sctdng



### . 0.50 

# 10 

# If o?,/o 

# 0. 

# <ii21 1.00 

### )f) 

# '\. ,[\<\ 

# D.q&D 1.50 

## il! 

# \.lS) 

# In CJT7 2.00 

## tn 

# tl11 Ifl c1 

# I r/1 3.00 

# fO 

# 1- 

# 7'70 o.%5 4.00 

# !0 J /. 

# fDJ.

**{),q~')'** 

# I!l!Jiw 

# I o,q-p II 

# Pf\-55 .6.H@i 

### = Pressure differential across the orlfce meter, in.I}O Y1=' Dry Gas Meter Calibration Coefficient, dimensionless
Q,.'\/QCChy· Cnmpletene!ls

ATC Form

**34-Prim;;~;y** Module CalitraliOn Record

**version~-** t May 20o."lS

ATC PROJECT No. P-1 0142 Reasonableness



# 7/t/1~ Project Manager {Signature/Dale} F.IWorkWI Ftom•-Fleld Data St-eels, Calc

**f~rmulae** ...

**13~·Prinulry** W"'dule: Cal!tn;ion R

**~COfd** Slarit tW<f A'fC (SOO) 7.l3-3193

EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 670BORAL BRICKS 

## Primary Module Calibration Calculation
Date: Calibrations by: Kirkman Pbar. Wet Test Meter Serial No.: 17562 

### MOdule 10:'---"="'--' Pre-test Calibration **FactorL__,"o"'.9""99~8'--..J** Orifice Vw.te Vd, 

# re Tw,°F Td, °F



### AH~~n~~GS Initial Ending Jnltlal Ending Initial Ending Initial Ending 

### 0.5( 808.61 8129? 701.772 9t 

### 99 102.( 103.( 1.( 813.22 819.01 702.075 7( 1.01 

### 1 

### 104.0 1 119. 826.4: 7'



# ~

**~** 2.( 

### 126. 834.9: 715. 

### \5 7: 1 

### 3.( 135 

### 7.

**~4.** 

### 15 7: ;.425 1 )7 109. 

### 4.0 1145.7. 

### 857.3< 

### 7 

### !5. 27 

### 7 >7.84( 10( 100 

### 1o\l:c 110.( Orifice 

### minutes dH@; Vt



### 1.766 0.9721 Speclflcatloru;. (QA Handbook-Val ill CDS-1, 9/36194) 1) No value of fiH@i shall vary from the average AH@ by more than 0.20. 2) No value of Yl shall vary from Yavg by more than 0.02. 

## 0.0319Llli(P,+ 

# l'lH) '



# ~- **VJ~(t"** +459.69) dH@= 

## l3.6 (tw+459.69}e ; - 

# Ml Vd+459.69) [ V.P, 

# J . Va(Pb+-)(tw+459.69)

QAIQG Check

. .1\.TC Fcr.n

**34e-Pr~tngry** MOdule Ca!ibrallon Record \8!<IC>O l_ij Novernller 2009

ATC PROJECT No. P-10142 

### 1 

# 13.6

EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 ATC(800j73H193

APPENDIX PAGE No. 671BORAL BRICKS


## PRIMARY MODULE CALIBRATION CALCULATION

Module I.D 

## /J"T,.-: b Personne - rff



### {i~r::c.o...~ Barometric Pressure, P 

### Z 8 ""1 3 

# sPre-test Calibration Factor,



### Y~l 

# [) /fl(, Date 

# I 2



## -~tO· :;zotd 

### Wet Test Meter Serial •· 1



### bd,,f,,d,E.~==dl
Orifice Setting 

### v. v, lnHial, 

# te Final, fil lnltlal, ftl Flnal,te 0.50 £!;0.(,2.0 

## !N.S'i'l 3q'),JI,<; 

### 35.::1. 

### 7(,'! 1.00 

## 6>/.'fB<I 

# qo. </L2 

### 35•('-.30 

## 35'77?4 1.50 

# o/0. 760 

### '17.4-60 36tl12'r 3-·',/;,8$1} 2.00 

### q7510 !tJ'I. 

## 870 367110 

### 37'/.7'{8 3.00

**/o.5~** 

## z.;;o 

# l!t'l 1'/o 

## 375:/'ls- 36</.,?t.C 4.CO 

## 1/'1'. 'fBo J;t-/.Bo5 

### 3cN·b7o 

## _?<J>;3''5



### . SpecJtiC:atlons (QA Handbool<.Vol 1!1 CD5·1 9"/30194) 1) No va;lue of AH@i shall vary from the average ll.H@ by more than 020 2) No value of '1 1 shall vary fium the average Y by mote than 0.02 

# ( Mi) 0.0319Mi P,+-- ' dH@=---L 

## n.6 [(t,.+459.69)e] 

# f!a



# +459.~ V,.P, 

# yi - 

# VwPb 

# (t d 

# + 459.69)

- 

# vd(pb+



# ~)iw +459.69) Legend Vw::: Volume of Wet Test Meter, 

### tf Vd :::; Volume of 

### Dry Gas Meter, 

### ff Tw::: Temperature of Wet Test Meter, °F Td 

### = Temperature of Dry Gas Meter, I)F Initial, 3 F 

# Go 

# r:o {:;(}



### {;0 

## 60 &0
Orifice Settlng 0.50 1.00 1.50 2.00 

### 3.00 4.00

ll.H@i = Pressure differential across the orifce meter, ln. 110 Y 1 ::: Dry Gas Meter Calibration Coefficient, dimensionless 

# / Completeness Accuracy 

## r. T, r!nal, QF lnitiai,"F

**Final,~**



# c,o &o .f, 

## z_ 

# iS&' r;, 

# z (_. 3 (,()

**~3** 

# 6'( 6:,0 

## 6•1

**~b** 

### {;.0 &{, 

# :;; (o.O 

## (, '7 

# t.!J

TIME ll.H@I 

### Y, min. 

### /0 

## J.t:Js<: o.qe;; 

## It' /.Cf3? 

# o.c;gz fO 

## -;z. 

# c:?8 o.1M3 

## !0 

# J. ·lOb tO. 

## qb8 [0 

## :J...N'> o.qJ'I iO 

## :J..N/ 0·17<;



## lz.o.?s-~ 

# Cl.'775l


# II II

specifications Reasonableness Legibility



# ~'LI-='G"":"'~·,{L":. **~"'"---',:"'-~~"-=l"""''l'-"!..:::c.i'---** 

# {,.). kV\-

**f1.,,J.-~** 

# zp.,/; 0 sign;;!!ures: Technlc!an (Signamre!Dete) ATC Fctm 34-Primary

**Modur,:~** Calibration

**Re~:ocd**

**~'{!tsiU'l** 5.1 May 2C<l6 Project Man01ger (Signature!Oa:e)

**F:\WOI~V'.tl f~s-i"i~rd**  O.;ta.Shee!S. Cali: Formulae..
..

**'.!l4--Pr~nal)' ~100\JJe**  **Calillro.G~n** RllCOid Blanl<_qp\Y ATC (000) 733·3193

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5. SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 672BORAL BRICKS


## PRIMARY MODULE CALIBRATION CALCULATION

Personn

### e

## ll~Nr 

# L ;.J. C<.O_f2._ Module 1.0 

# A·r -:: b Barometric Pressure, P 

# j Z 8 - 

### -1 3 

## s-' Prevtest Calibration Factor,

### Y~l 

# [) /f9'b Oat Wet Test Meter Serial 

### e 

### 2 -JO -· ::ZO! ,_)



# I Oriflc-e Setting 

## v. v, Initial, ft3 Final, ftl lnitial,te Finai, tt' lnitlaf, DF 0.50 

## BIJ, &20 

## fNS'i1 

## 3'/'i.tb<' .3:>.3, 7/A 

### t;,o 1.00 

# M-98'1 C[IJ. 

## 'IL?. 35•/.?.30 

## 3<;'?.77<1 

# &o 1.50 

## 'fa 760 

### 11. J.-60 

### 360.125-**3t.~r...85""8** 

## 6(} 2.00 

## q7510 1/J'I 8}0 

### 367110 

## :J7i.J'1E (:,0 3.00 

# tos:z60 I !!<I 

## /"Jo 37.'>-1'15 39•/.:;:bt 

## 60 4,00 

### II'{ 

## '(/3o !.P/.Bo'S 

# l.::?ii'/ 

# "n _<:tW3os (;,D 

# '" 00 - 0 

### . ' Specifications {QA H db k v 1111 cos 1 9/30/94) 1) No value or t.H@! shall \lary from the averaga lt.H@ by more lhan 0.20 Orifice 2) No \lalue ofY1a-hall vary from the average Y by more than 0.02. I Setting 

# ( Mf) 0.50 

## 0.0319Mf P, 

## +- _ ' dH@!.= 

## 13.6 [(t,.+4)9.69)e] 1.00

# ~· 

# Va +459.69) 

## V,.P, 1,50 

# VwPb(td 

# + 459.69) 2.00 

# yi 3.00


## - 

# - 

# v{Pb+

# ~~)tw + 459.69) 4.00

. 

### Legend Vvv =Volume of Wet Test Meter, 

### ft 3 Vd 

### = Volume of Dry Gas Meter, 

### ff Tw 

### = Temperature of Wet Test Meter, °F Td 

### = Temperature of Dry Gas Mete1·, °F llH@i:: Pressure differential across the orifce meter, in. }10 Y 1 ;; Dry Gas Meter Cal!bratlon Coefficient, dimensionless

OAJQC Chep-1(: 

### ./ 

## / ·' Completeness lagibl!ity

# x~~Ji**C:t4~"** 7/lt:'//{.) 

# / Accuracy 

# l I 

## ;.,_/, 

# I t.. 7**s--~,** 

# z.. 

# I
r. r, Final, "F Initial, '"F**F~naf,** °F



# c;.o (,,o f
.. , '(.:.. 

### hi? L1 ;:__ 

# 63 r;,o**~3** 

# 61 6;,0 (,'{**&.~~** 

# r;.o r;_.(, 

## {,j (.,0 

## 0'7 

# It: 

# e

TIME 

### AH@i 

# c:J min.. 

### /{) 

## l85<; 

## o-'hor /0 /."131 t)-9§Z 

# ;o 2- c.?t} 

### t1-'1M3 !0 

# J.. 

# rot;. I!J, 

## qt·8 {0 

# :;;..N<: o."!J'I 

## lo J.. 

## i'll o.qJS: 

# lz.o.<:d O-'t7il 

# II

Specifications Reasonableness Signa\ures: Technlc!an (Signature/Date} Project Manager {SlgnaturetDate} AlC Form 34-Primary Morlula**Calibfali~;~o'l** Rw.:cn:l**~<etslro** 3.1**M~y** zc-os**f:l~"\lorkl/1~ Fu•=·Ft~ld**  Oal.;l**Shee~. C~lc** **ForrroU~e....\3.1;-Prlmij<y** Moduli! Calibr.lti0t1 RSI;;Ofd Blank.QPIV ATC (600) 13-3-3-193

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 673BORAL BRICKS



# Report on Calibration of Field Barometers The following barometers were calibrated: By: Keith Poole Date: August 

# 27, 2010 Barometer ID 

# ATC#l

.. 

# ATC#2 Pre-Calibration Reading 

# :J-9- 3f5 ·';A

**~-** 

# '3 3 Adjustment Needed 

# --·u.o'j)

- o. a'-f{



# ----- I 

# ATC#3 {"\;), iW'(;\ub 

### k


# ------------ 

# -j 

# ATC#4 

# dv Of.5Y -O-J.)(; I 

# I ! I 

## Barometer adjusted to reading obtained from National Weather Service website. Reading 

## j adjusted for elevation of 835 ft.

**L------------------~ational** 

## Weathe1· Service Barometer reading, actual = 

# I 30.12



# 1--- **_E!~vation** 

## Ad'ustment (ATC Office=835 ft., 

## NWS elevation=836 ft). 

## Adjusted Station Pressure for correction ofA TC Barometers -0.835 29.285

ATC Form 53-Barometer Calibrations

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 vefsion l.l February 2007 Analytical Testing Consultants, Inc. (800) 733-3193

APPENDIX PAGE No. 674**~** -u "' e m 0 -; z ? **~** :: .... "' )> c Glm C-u **~)>** l>(j rn""' mS::m -uzs: -<-;- mrn<f> ;g:.f>-22 ro..,o **~c.nz**

. -; "'rnm **~;p.cn** or--< (jj'U "'"'

co **"'~** -<m .,o s;"" **~** "' )> -u -u m z 0 x ;! Gl m z 0 "' **~** "' Dare 717/2009 817/2009 9118/2009 10/12/2009 11112/2009 12/23/2009 1/512010 2/212010 41812010 6/28/2010 8127/2010

I ! Date 717/2009 8nl20o9 9/18/2009 10/1212009 11/1212009 12123/2009 11512010 212/2010 4/812010 6128/2010 8/27/2010 Calibration of ATC Field Barometers 1 Barometer #1 Barometer #2

Station

Barometer

Adjustment

Pressure, in. Reading. in. Technician Hg Hg

Needed Station Barometer

AdJustment

Date Pressure, in. Reading, in. Hg Hg

Needed

29.005 29.000 0.005 Childers, K 7nl2009 29.005 29.150 0.145

29,356

29.480 0.125 Childers, K 8n12009 29.355 29.300 0.055

29.305

29.320 O.G15 Childers. K 9/18/2009 29.305 29.380 0.075

29.385

29.340 O.G45 Burgess, T 10/1212009 29.385 29.440 0.055

29.035

29.100 0.065 Burgess, T 29.035

29.455

29.430 0.025 Burgess, 'T 1212312009 29.455 29.490 0.035

29.175

29.200 0.025 Burgass, T 115/2010 29.175 29.190 0.015

29.275

29.200 0.075 Burgess, T 212/2010 29.275 29.180 0.095

29.035

29.020 0.015 Burgess, T 4/8/2010 29.035 29.200 0.165

29.035

29.000 0.035 Burgess, T 6/2812010 29.035 29.020 0.{)15

29.285

29.380 0.095 812712010 0.045

----- ------------ ---- **-~---- --·-~**  **_P~I~IS:** ----------··· -- **~--~9.285** ---. 29.330 --
UOIVUit:C.O:H fro) Barometer #4

Station

Barometer

Adjustment

Pressure, in. Reading, in. Technician Station Barometer

Adjustment

Dare Pressure, in. Reading, in.

Hg

Hg 29.005 29.150 29.355 29.500 Z9.305 29.400 29.385 29.500 29.035 29.060 29.455 29.510 29.175 29.290 29.275 29.300 29.036 29.150 29.035 29.050 29.285 n1a Needed 0.145 0.14S 0.095 0.115 0.025 0.055 0.115 O.Q25 0.115 0.015 Childers. K Childers, K Childers, K Burgess, T Burgess, T Burgess. T Burgess, T Burgess. T **Burgess~** T 4/8/2010 Burgess, T 6/28/2010 8127/2010 Shop Eleva1ion = Charlotte-Douglas

Airport Elevation=

' Data provided by NOAA National Weather Service for Charlotte-Douglas Airport. Hg 29.035 29.035 29.285 835 836 Hg Needed 29.210 0.175 28.070 0-965 29.540 0.255 Technician Childers, K Childers, K Childers, K Burgess, T Burgess, T Burgess, T Burgess, T Burgess, T Burgess, T PC1ole, K. Technician :• Burgess, T Burgess, T. **~g~~,_K.** "'

0 **~** r- "' "'

0 "' <f)BORAL BRICKS 

# Precision Weighing 1949 Evans Road 

## Cary, North Carolina 27513 Phone: (919) 678-0077 

### * Fax: (919) 678-0075 Email: pweighing@aol.com 

# BALANCE CERTIFICATE OF CALIBRATION Calibration Date: Balance ID 

### #: Dept: 

# W#fit! lfjtl Calibration due date: 

# .4vr/( Type/Model: 

# Preafa J.t8ff

. I
. '



# '--«;fr Weight set ID#



### .,Pt,{tz, P/7-l/ 

# ·----== Room Number: NIST Test Number



### 1~'7!7111./tJ:..·l:.'/ifJ


# - h 

### ItA-"· f)!) 

# ' ''/ 

# ' g!i 

# In

. I
. Cal Date 

## &ifJf'Ul'l SOP: 2000 Rev L 

# JTolerance +/· : 0.1% Cal Due 

## IA'"ll)

-........

B"ef'ore 

### CalibJcatlon Readings: 

# d After Calibration Readings: In Tolerance: In Tolerance: Out of Tolerance: 

# 0 0 Out of Tolerance: N/A: N/A: 

### Co!:'jments: This certifies that the balance listed above has been serviced and calibrated to manufacturer specifications and/or Precision Weighing Standard Operating Procedures with weights traceable to the National Institute of Standards and Technology (NIST).

Oate of Service

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 Customer Signature (Review)
Dale of Review

APPENDIX PAGE No. 676BORAL BRICKS

Contractor: 

### Precision Weighing Inc 1949 Evans Rd Ca_!)', NC 27513-2041 Purchase Order II: 10JCI 

### Client: 

### Precision Weighing Inc Address: 1949 Evans Rd 

### City & State: Cary, NC 27513 Date Received: 25 NOV 2009 Date Calibrated: 01 DEC 2009 

### Temperature Ranga: 20.91 

### to 21.40 

## ·c Pressure Range: 720.8 l<l 722.6 mmHg Relative Humidity Range: 50% AirOensfty: 1.1312 to 1.1358

**mg/cm~** Traceable Report#: 1575793 NIST Certificate#: 8221272801-06 8221274081-08 Tested 

### By: 12 Procedure: Modified Substitution {WI05-0023l Contractor Req Rl3cal! Data: 12131/2010 Primary Standard Calibration Date: 111031{)6 Due: 11/03110 Description of Weights: 1mg·100g Polished Kil. Class

**"1~,** S/N F824 Allkl1.1gh \hen! are two NISi

**numbe~.** rJJ'le 01 both m.11y apply

**~onventlonal** Mass Corr. Unc. Nnminal

V.:!ue 

### Ia. 

### 1 mg 

### 2 mg 2 

### mg 5 

### mg 

### 10 mg 

### 20 mg 

### 20 mg 

### 50 mg 

### 100 mg 

### 200 mg 

### 200 mg 

### 500 mg 

### 1 g 

### 2 g 

## 2 g 

### 5 g 

### 10 g 

### 20 g 

### 20 g 

### 50 g 

### 100 g

Prep;:; red By:

**;htte'i&C~~~~~** 

## !RiiCE I!I.AKIE v ..
**-~ICt-::r-.:c, ~y~rEMS**  t:orMJnnem Be;·or.d

**Mt'ttillJ~fil!'Jtt~** As Found (mg) 

### 0.00229 0.00194 0.00354 0.00392

0.0001 0.0037 0.0052 0.0005 0.0081 -0.0009 -0.0011 0.0016 0.0035 0.0150 0.0111 -0.0166 0.0129 -0.002 0.011 -0.056 

### -0.006

230

**Wes~** Co!o'll;::n .S!reo?l • Rice Lr.ke,

**'~N[** 5•!668 •lJSi; TEL: f

**16-20-J.-Dl.~** 1 " FAX: -;:·15-23<l-6S'IJ7 

### As Left K•2 Tol. (mg) (mg) (mg) 

### 0.00229 0.00078 0.010 0.0(}194 0.00066 0.010 0.00354 0.00066 0.010 0.00392 0.00097 0.010

0.0001 0.0013 0.010 0.0037 0.0012 0.010 0.0052 0.0012 0.010 0.0005 0.0014 0.010 0.0081 0.0015 0.010 -0.0009 0.0014 0.010 -0.0011 0.0014 0.010 0.0016 0.0017 0.010 0.0035 0.0026 0.034 0.0150 0.0027 0.034 0.0111 0.0027 0.034 -0.0166 0.0053 0.034

. 0.0129 0.0099 0.050

-0.002 0.010 0.074 0.011 0.010 0.074 -0.056 0.021 0.12 ·0.006 0.034 0.25



### Page 1 of 1 Page r ' 

# I r, Y, 

# "J_:- r ! [/ 

### 1-


# . ' (

Standafd Set Used 

### Assumed 

### Balance Cafibrated/due Density

Used MM·DO-YYIMM-DD·YY (glcm') 

### 5010 K5940 11-20-09/02·19·1 0 7.95 5010 K5940 11-20-09/02-19-10 7.95 5010 K5940 11-20-09/02·19-10 7.95 5010 K594Q 11-20-09/02-19-10 7.95 5010 K5940 11-20-09102-19-10 7.95 5010 K5940 11-20-09/02-19-10 7.95 5010 K5940 11-20-09102-19-10 7.95 5010 K5940 11-20-09/02-19-10 7.95 5010 K594Q 11-20-09/02-19-10 7.95 5010 K5940 11-20-09/02-19-10 7.95 5010 K5940 11-20-09/02-19-10 7.95 5010 K5940 11-20-09/02-19-10 7.95 5010 K594Q 11·20-09/02-19-1 0 7.95 5010 K594Q 11-20-09/02-19-10 7.95 5010 K594Q 11-20-09/02-19-10 7.95 5010 K5940 11-20-09/02-19-10 7.95 6760 K5940 11-20-09/02-19-10 "1.95 

### 6760 K5940 11-20-09/02-19-10 7.95 6760 K5940 11-20-09/02-19-10 7.95 1i83Q K5940 11-20-09102-19-10 7.95 1183Q 

### K594Q 11-20-09/02-19-10 7.95

9(lted 01 DEC 2009 ' \ (\ 

# \! to.._... 

# V. ·

**~** lj ......%



## y,..~ Dan Demers. M:irologist Ti1:s rt;po:l ;!, •·-ot kl

**01~** •• s:l.i to

**cia~~~ pr>J:~,:;:;:**  er ... i,11't>f:\fl'l<tnt by

**Ri~** Lah!!

**'i'li'·g~·~::•~** .S/>t;;:r;-.;, C• <Jntage!',Gy t') t!i::, U.S. G0-,;s;nmer.t. ATC



### PRoJ~Cf'N~!.'F~':i'il1~4f' **1**



### bofrtK~rx;J~te~d- **~~~~;,~,~~ EiJISJts**  **1bN''fE'~iPPRbJ~~~f**
**Lc~~;** ··N;;irt·M><



### s:,-•i\£:'n~-k~~~1~'6T~bPA~:~ No. 677 AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 201 0Contractor:
Purchase Order#; 

### Client;

**Address~** Ci!y & Stata: Date Received: Date Calibrated: 

### Temperatura Range: Pressure Range: 

### Relative Humidity Range-: Air Density: 

### Traceable Report#: NIST 

### Certificate 

### I: Testad 

### By: Procedure: 

### Contractor Req li:eca/1 Date: Prlmary Standard Calibration Date: 

### Description of Weights: A.lthO(.lgh t,"lere are Lwo N!ST numbers, one or OO!h rna-J appry. 

### Precision Weighing Inc 1949 Evans Rd Cary, NC 27513-2041 10301 

### Precision Weighing Inc 1949 Evans Rd Cary, NC 27513 25 NOV2009 01 DEC 2009 20.95"' 2145 

## ·c ?20. 7to 721.2 mmHg 50 % 1.1309!Q

**1.1~27** rngtcm 3 1575793A 822/272801-06 822!274081-06 12 Modmed Subs•Jtuiion (WJ05-0023) 12!31/2010 11/03106 Due: 11/03110 100g-5kg Satln Finis/1. Kit, Class "1", SIN F822 Conventional

**M~ss** Corr. 

### Unc. Standard Set Used Assumed Nominal

Value I d.



### 100 g 200 

## 9 200 

## 9 500 

## g 1 kg 

### 2 kg 

### 2 kg 5 kg

**P~ep::-.::ed** 8y:



# -- RifCE LAKEr

**W~_IGHINC S\~STF.M$** 

C(l(Ml.i;nM?Jl>

**lb.i~:lli Mca.~nrcmem·**  As Found (mg) 

### .0.057 0.228 -0.161 0.303

0.17 -0.53

1.87 2.3

TE::...:

**?15-2J·J·9~** r1 • Fr-\X· 715-234-69(17 As Left K=2 

### Tot. Balance CalibratedJdue 

### Density (mg) (mg) (mg) Usad 

### MM·DD·YYIMM·DD·YY (g/cm') 

### -0.057 

# "' 0.034 0.25 11830 K594Q 11·20-09/02-19-10 0.228 

# "' 0.064 0.50 619Q K5940 11-20-09/02·19-1 0 ·0.161 

# * 0.064 0.50 619Q K594Q 11·20.09/02-19-1 0 0.303 

## a 0.091 1.2 6190 K594Q 11·20-09/02-19-1 0



### 0.17 

## a 0.15 2.5 6190 K5940 11·20-09/02-19-1 0 ·0.53 

# * 0.71 5.0 9750 K5940 11·20-09/02-19-1 0 1.87 

# " 0.71 5.0 975Q K594Q 11·20-09/02·1 9-10

2.3 

# * 1.0 12 9750 K594Q 11-20-09/02·19-1 0



### Page 1 of 1 Page i;iated 01 DEC 2009 

# * Although this lest weight has beenlesled lor the

tolerance of the

**Cia~s** fo' which it was s:;t.mitted. H does r.ot rnee1 .:::!! lhe reauirements for\hat class. 

# ; ' C\

**··r..J<::'-·""-~** 

# 4-.,•

**!?~--~** Dan 

### Oe:r.&rs MltrolOg!st 

### 7.84 7.84 7.84 7.84 7.84 

### 7.84 7.84 7.84

lh!s

**r:;;i>~~11s no~**  !o b<Ol

**;.rs~i** J'j

**,%;r~t** oroG.Jct

**cmlcr~rn,or:t** r_,,. Rir;e l,<:t<-.e W-?.igl1ir;g

**s:.-st~M>=** or !lf1/ <>ge:1(;t otl!;e U.S.

**C'io'<':'rr~l\l.<ftL** .ii;:s

**dt~...::urner,t** sr.al!

**~:Ot** t;a rc:prcducc-cl. e<Gtl}! lll f.]!, wftXut :t;-o;

**•:.tl!t~n** ap,)<·.Jva:' of Fl:.;:f< L;,k:: 'Ni:•Qhi;>J

**S~'St.e:-;•s' M,;;tr·~'~C9J."**  **Lab~retor~;.** ATC PROJECT No. P·1

**014~)&** e.bcvn

**.,~~;certa:..~ty ~X**  **f'Ct~Etm~~ltf~ff~t~rpworrt't'f~ped:t**

**~** i·;a."V.1fing a:ld vs&APPENDIX PAGE No.

**If~;:,** 

### a:c.e AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010BORAL BRICKS 

# Precision Weighing 1949 .Evans Road 

### Cary, North Carolina 27513 PJ10nc: (919) 678-0077 *fax: (919) 678-0075

**Email~** 

### pweighing@aol.com 

# Weight Set Verification Certificate cneflt_-_, Analytical TestiOg Consultants **-r;,.;,_rita~_t:t**

## .. , Keith Poole **:';-:i~e;paftm.en:ft** 

## ,:-.; Lab

**Dfi):S_cliP.tli>n~** Class 1 weights 

### 'Wi>.i9htlO#: See below

!Verification Date: 19-Apr-10 !verification Due Date: Apr-11 CaUimHIOD

**SO~** Metr-ology 2190 StamJard s) Used Class I wei ht set Precisa balance model 303A Comme11ts: ID F822, F824

43108 Ex imlion Date Dee-10 A r-11 Readings of welght(s) taken on balance(s) listed after balance(s) calibrated with NIST traceable weight sel{s) noted.

**T~ellnicianm~te:** 19-Api·-IO,

ATC PROJECT No. P-10142 Cusrumer.:

EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 679BORAL BRICKS 

# ISO 17025 lf.OiliOllll

**Certlfj~~~l,3.01** 

# Thermo fisher SCIENTIFIC 

# Thermometer Calibration Report In serving sdet'lte This Is to certify that the Instrument described below has been examined and tested by dlrect measurement of generated temperatures in our· calibration laboratory using high precision temperature calibraflon equipment. The calibration methods used are based on the technical Information contained in NIST Technical note 1265, "Guldellnes for Realizing the International Temperature Scale of 1990 (ITS·90)" and NIST Special Publlcallon 250-23,

**~uquld** In Glass Thermometer Calibration Services". This calibration meets the requirements of the ISO 9001 series of quality standards. 

### Instrument Description Serial Number: 1548 

### Product: 1 005-BFC-BF 

### Results of Physical Examination Inscription: 10058-BF 

### Scale Range: -1 TO 

### 101 Immersion: TOTAL 

### Scale Divisions: 

### 0.2 Units: 

# oc
This InstrUment has been examfned under a polariscope for strains In the glass. If any, were fudged 

### to be minimal and of no detriment to the functionality of the Instrument. The capilfar; of this thennometer has been examined under magnification and no foreign material, moisture, or other evldence of contamination were discovered. No discernible capillary irregularities were noted. 

### Upon completion of physical examination, it has bean determined the instrument is In good working order and is therefore suitable for calibration.



### Calibration Results Unless othetwfse noted 1 these results are considered "as found" and "as left", 

### Results In Target Test Actual Test Reading 

### Of This Emergent Column 

### System Engineering Units: 

# oc Temperature Temperature Instrument Correction Temperature Uncertainty 

### 0.00 0.000 0.000 0.000 

### NA 0.0277 20.00 19.998 20.000 ·0.002 NA 0.0267 40.00 40.002 40.000 0.002 NA 0.0267 60.00 59.991 60.040 ·0.049 NA 0.0267 80.00 80.007 80.100 ·0.093 NA 0.0267 100.00 100.001 100.200 -0.199 NA 0.0357 "'"'IMPORTANT NOTE: If no sign Is given on the correction, the true temperature Is higher then the indicated temperature. If the sign given Is negative, the true temperatura Is lower than the Indicated temperature. The estimated system uncertainties as stated above (k = 2) were determined In accordance with the guldeUnes given In NIST Publica1ion IR 5341, take ln1o account the type or thennometer tested, the precision with which Its reading can be resolVed, and the degree of confidence one can have In its Indications under similar conditions of usage. For further discussion of accuracies attainable with such thermometers, see NIST Special Publication 250-23 and NIST Publication IR 5341. The caUbralion performed and documented by this report of test is a full scale calibration and no !Imitations of use are Imposed on this inslrument. The Instrument mentioned In this report was tested In accordance with Barnstead International procedure number CPM105 which is based upon standard test method ASTM E-77 and N.I.S.T. Special Publication SP250-23 

### Traceability Information The measurement standards used in thts calibration are given below: 

### Test 

### Point: 0.00 Model 

### No. Serial

**Numbe~** 

### Description 2563 A36152 Thermister Meter 

### 5640 N/A Test Point: 

### 20.00 Mode! No. 1590 5699 7007

Page 1of2 ATC PROJECT No. P-10142 

### 1047 N/A Serial Number A27184 1476 A33016

2555 Kerpar Blvd

**Oubt~que.** lA 52001 Thermister 

### Ice Bath Description PRT Thermometer PRT Calibration Bath

(563)556-1241

**{563}58~0516** fax EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

### Recall Date 11/4/2009 11/4/2009 Recall Date 3/20/2009 11/4/2009 

# RECEIVED FEB 1 

# 0 2009



# ~-n<f BY: Calibration Traceability No.: 1282719442 w.vw.t!\ermofisher.tllm Rlrm No,: CC-300 Revls!on: 10{05 APPENDIX PAGE No. 680

### Test Point:

Test Point: 40.00 60.00 80.00
100.00 

### Model No.
5680 7007 

### Model No. 1590 5628 6054 BORAL BRICKS 

### Serial Number 

### 1475 A33017 

### Serial Number A27184 1477 A33014 

### Description Recall Date 

## PRT 11/4/2009 Calibration Bath 

### Descriotion Recall Date PRT Thermometer 

### 3120/2009 

## PRT 11/4/2009 Calibration Bath The results Indicated in this report relate only to the item{s) calibrated. If addltlonallnfonnatlon regarding this calibration Is required, please contact this laboratory. Results of this calibration are traceable to NIST.



# .
**~u~** Appoved By. Jeff Welly Quanty Operations Manager 

### Calibration Date: 01126/2009 Calibration Due: Not Defined 

### Batch No.: M714760
This certificate may not be reproduCfJd except In 

## run without the written approval ofBarnstead International.

Page 2 of 2 ATC PROJECT No. P-10142 End Of Report

EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 

# RECEIVED BY:



# FEBG~ **tf**

# __
Calibration Traceability No.: 1282719442 Form No.: CC-300

Revision: 10/0S APPENDIX PAGE No. 681

### 84/08/2618 11:05 7049829705 ST D GAS METER BORAL BRICKS 

## ST A.l'IDARD GAS METER SALES AM> REPAIR INC 537 WEST MAIN ST POBOX273 

## ALBEMARLE NC 28001 704-982-%01 FAX 704-982-9705 

## stlmdardgllll@windsmam.net PAGE !'Jl



## To: Analytical Tming 03-10.10 Keith 

## Poole 704-932.0570 

## Te§ting and Calibration: American Wet Teat Meter AL19#17562 Conditions: 69F, 

## l.S"WC, Barometric P..-ure 31).1" 

## Meter w1111 

## preclflely leveled, t:hecked for lealu and proper operation. A foreign objttct wu removed 

## from the

**wat~** 

## reservoir. Calibration was efl'eeted at the termination 

## off"ln cycles and 

## the minbcus gauge adjusted aecordl.!lgiy. Calibrated on RW Prover lfflt, 

## Certlfiod Tape 1#26727,


# /1/.,.~dfJ~

ATC PROJECT No. P-10142 

# ~p Miller-SGM

EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 682E: "<

() "U ;u 0 L m () --l z p :!: ':1 .. N Gl em **~~** >-o (/)"U;u m<;;m -uzs: --<--<- m(/)(1) **s:.,f:r.~ ~""0**  "'"'z

• --l '->(l)m **~)>(/)** or---< (j)"U "'"' co ;!JL -<m -u" ,---< ,. !!i "' ,. "U "U m z 0 x **~** m z p "' **~ Ql~~**  STATE OF LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY

Is hereby granting a Louisiana Environmental I.aboratot-y Accreditation to Analytical .. :r **e$tip~'¥?** ?S qltan ts Inc. **19~p-jaie Ear~il~riit**  **igiy~** .. **~nnapolis,**

NC 28083<{21:9 Agency Interest No. 94216 "'a **t:nvir ~**  .

.**~.,~-----.:;~ ~rLELA~~**  **~~~ ~**  o<lli.

,..,('('"'

-- q'< ' **-~**

According to the Louisiana Administrative Code, Title

**~~{Part~!lifup~,t** 3,

**LA~G)~ y{ilR~~)i;ACCREDIT**  A TION, the State of Louisiana formally

recognizes

that this laboratory is technically competent!<o

**perf41'ffi'"fh<)[i:invli·o~~al** ijllalys"i,s listed on )he scope of accreditation detailed in the

attachment. .,, ;•,.. i/ '' "

The laboratory agrees to perfomt all analyses listed on this scope of accreditation

**accordi1~,;,tb** .the Part I, Subpart 3 requirements and

acknowledges

that continued accreditation is )lependent on successful ongoing compliance with 'the applicable requirements of Pat1 L Please

contact

the Department of Enviromnental Quality, Louisiana Environmental Laboratory Acctcdjul.j)bnProgram (LELAP) to verify the laboratory's

scope

of accreditation and accreditation status. Accreditation by the State of Louisiana is not an

**end~bnent** or a guarantee pf validity 0 gfthe data generated by the laboratory. To be accredited

initially and maintain accreditation, the laboratory agrees

**lf:P?r!Jcip;tt<:in.,two.~J?gl~cbli'hd,** single-concentration PT studies, where available, per

year

for each field of testing for which it seeks

**accreditationor'nfuint.'li~Si:\i4~~~di!1itlori** asreqnired in LAC 33:L47l J. **Cl::!:::Z::il~en~:Ler** Notifications and Accreditations Section Pennit Support Sen·ices Division Certificate Number: 04044 Expiration Date: June 30, 2011 Issued On: July 1, 2010BORAL BRICKS



# This is the last page of this report.

ATC PROJECT No. P-10142 EPA ICR EMISSION TEST PROJECT AUGUSTA PLANTS 4 & 5, SALISBURY PLANT 6 SEPTEMBER 2010 APPENDIX PAGE No. 684