425 S*ufh i\Tain SN.,Suite 201 Anu Arbor'" tuIiehigan J81lì4 'îel: 734.9Í3"2$80 Fax: 734,668.1541

Re: 

### JuIy 1,2009


### Mr. Terry Sanner 

### Southwest 

### District Office 

### Ohio EPA 

### DAPC 401 East 

### Fifth Street 

### Dayton,

# OH 43377 

### Submittal of Emissions Testing 

### Report Bellefontøine Gøs 

### Producers, 

### LLC 

### (permit #p0I0B6g0 Bellefontaine, Ohio Dear 

### Mr. Sanner: 

### Attached 

### find the

### final report 

### for emissions

### testing conducted at 

### Bellefontaine Gas 

### Producers, 

### LLC on June

### 3,2009. Thetesting 

## *ut conducted 

### to demonstrate compliance 

### with the emissions 

### limits specified in

### Air Pollution Permit-to-Install nnd Operøte, 

### Permit No, P0103690. The

### testing was conducted 

### in accordance 

### with the 

### Intentto Test

### notification sent

### to and 

### approved by the OEPA 

### prior to testing. As 

### indicated 

### inthe 

### report, emissions

### from the tested, 

### representative 

### internal cornbustion engine 

### comply 

### with both NSps (40

### cFR, 

## pirt 60,subpart

# lllf and OEPA 

### Permit 

### limits. The 

### report contains 

### all test 

### and 

### support datå

### thai are

### the basis

### for this determination. 

### If you have 

### any questions concerning the 

### report or any

### portion of thetest 

### program, please 

### contact me. 

### Sincerely, 

### DTE 

### BIOMASS ENERGY
Thomas 

### Durham Environmental Engineer 

## enc. "PM, SOz, 

### NOx, CO, and 

### NMOC Emissions Testing Report,, 

# cc: M. 

### Kotyk 

## - DTE Biomass 

### Energy (w

### /o

### enclosure) G.

### Autolitano 

## - Bellefontaine Gas producers 

### ,LLC (w

### /o

### enclosure) D.Terry

## - Bellefontaine Gas producers, 

### LLC (with enclosure)

# K

DïE Energy"



# PM, SOz, NOx, 

# CO,

# AND NMOC EMISSIONS



# TESTING REPORT Ohio Permit

# to lnstail No. 

## pOl0g690

UNIT 3


### BELLEFONTAINE 

## GAS PRODUCERS, LLC

BELLEFONTAINE, OHIO
June,2009

## DfE Energy' 

# K

CONTENTS 

### Section Page EXECUTTVE

# SUMM4RY........... ................tV 

### r.

# 0 !NTRoDUCT|ON.....

........ 1 

# 2.0 souRcE

# DEscR¡pTroN........ ........1 

# 3.0 SAMPLING AND 

### ANALYTICAL 

# PROCEDURES .........,.2 

# 3.1 STACK GAS VELOCTTY 

### AND FLOWRATES (USEPA METHODS 1-21 ......3 

## 3.1.1 Sampling

# Method..... .....................3 

## 3.1.2 Method 

### 2 Sampling

# Equipment............... ........................3 

# 3,2 OXYGEN 

### AND 

### CARBON D|OXIDE (USEPA 

### METHODS

# 3A) ......3 

## 3.2.1 Sampling

# Method..... .....................3 

## 3.2.2 Oz

### I COz 

### Sampling

# Train .............3 

## 3.2.3 Sampling 

### Train

# Calibration .........4 

# 3.3 MOISTUREDETERMINATTON(USEPAMETHOD4)...................................4 

## 3.3.1 Sampling

# Method..... .....................4 

# 3.4 PARTICULATE MATTER (USEPA METHOD

# 5).......... .................4 

## 3.4.1 Filterable Particulate 

### Sampling Method 

### (USEPA METHOD 5)......................4 

## 3.4.3 Quality 

### Control and

# Assurance............ ........5 

# 3.5 SULFUR DIOXIDE, OXIDES 

### OF NITROGEN 

### AND CARBON MONOXIDE 

### (usEPA METHODS 

### 6C,78 AND

# 10)... ....................5 

## 3.5.1 Sampling

# Method..... ....................,5 

## 3.5.2 SOz, NO*,

### and CO Sampling

# Train......... ........................6 

## 3,5.3 Sampling 

### Train

# Calibration .........6 

# 3.6 METHANE (USEPA METHOD

# r8)........... .....................6 

## 3.6.1 Sampling

# Method..... .....................6 

## 3.6.2 CH4 Sampling

# Train ....................7 

## 3.6.3 Sampling Duration &

# Frequency............... ......................7 

## 3.6.4 Sampling

# Analysis ........................7 

# 3.7 TOTAL HYDROCARBON COMPOUNDS (USEPA METHOD 25A) .............7 

## 3.7.1 Sampling

# Method..... .....................7 

## 3.7.2 THC Sampling

# Train ....................7 

## 3.7.3 Sampling 

### Train

# Calibration .........8 

## 3.7.4 Sampling Duration &

# Frequency............... ......................8 

# 3.8 QA/QC 

### AND POST 

### TEST

# PROCEDURES......... ..........8 

## 3.8.1 Quality Control and 

### Assurance (O2, CO2, SO2, NO*,

### and CO)

..... ................8 

## 3.8.2 Quality 

### Control and 

### Assurance

# (NMOC).............. .........9 

# 3.9 DATA

# REDUCTION.......... ..........9 

# 4.0 oPER.ATING

# PARAMETERS.... ....................10 ii

## DïE Energy' 

# K
5.0 RESULTS .....10 

# 6.0 cERTtFtCATtON 

# STATEMENT............ .........11


### Result Table Particulate Emissions 

### Testing Results SO2, NOx, 

### CO, NMOC Emissions 

### Testing Results 

### Fiqures 

# 1 Unit 3 Stack Drawing & 

### Exhaust Sampling point Location 

# 2 USEPA Method 5 Samplíng Train 

# 3 USEPA Method 

### 3N6CnEl10 Sampting Train 

# 4 USEPA Method 18 Sampling 

### Train 

# 5 USEPA Method 

### 254 Sampling Train 

### Appendices 

# A OEPA 

### Test Plan 

# B Equipment and

### Analyzer Calíbration Data 

# C Example Calculations 

# D Particulate Data 

# E RawAnalyzer Data 

# F Operational Data 

# G Analytical Data

i¡i

## DïE Energy"

EXECUTIVE SUMMARY



### DTE Energy Corporate Services, 

### LLC (DECS),

## a DTE Energy Company (DTE) 

### performed emissions 

### testing

## at Bellefontaine 

## Gas Producers, 

### LLC, located in 

### Bellefontaine, 

## Ohio. Thefieldwork, performed 

### on June 3, 2009 

### was conducted to satisñ7 

### requirements of

### the Ohio Permit 

### to lnstall No. P0103690 and EPA

### 40 CFR Part 

### 60 Subpart 

## JJJJ. Emissions 

### tests were performed 

### on Unit 

### 3for particulate matter (PM),sulfur dioxide (SOz), 

### oxides of nitrogen (NO"), 

### carbon monoxide (CO), 

### and non

### methane organic 

### compounds (NMOC). 

### The results of

### the emissions 

### testing are highlighted below: 

### Emissions Testing Summary Bellefontaine Gas 

### Producerc, LLC 

### Bellefontaine, OH 

### Unit 3 

### Operational Horsepower

## - 2,233 

### BHp

June 3, 2009
Unit 3 Sulfur Dioxide (lb/MMBtu) Oxides of

Nitrogen lolBHn-Hrì Carbon

Monoxide lalRHn-Hrl NMOC

(s/BHp-Hr) Particulate

(lb/MMBtu) Permit Limit 0.5 0.60 3.0 1.0 0.062 Test 1 0.01 0.52 

### 27 ND 0.004 Test 2 0.01 o52 

### 27 ND 0.002 Test 3 0.01 0.52 

### 27 ND 0.002 Average 0.01 0.52 2.7 ND 0.003

IV

## DIE Energy"



# 1.0 INTRODUCTION


### DTE Energy 

### corporate services, _LL_c

### (DEcs),

## a DTE Energy 

### company (DTE) 

### performed emissionstesting 

## at Bellefontaine 

### Gas Producer!, 

### LLC, Iocated in 

### Bellefontaine, 

### Ohio, The fieldwork, performed 

### on June

### 3, 2OOg,

### was conducted to 

### satisfy requirements 

### ofthe Ohio Permit

### to lnstall 

### No. p0103690 

### and 

### EpA40 CFR Paft 

### 60 Sub-PartJJJJ. 

### Testing 

### was performed pursuant 

### to Title

### 40, Code 

### of 

### Federal Regutations, 

### paft 60, 

### AppendixA (40 

### CFR SO0

### App.A), Methods 1-S,

### 6C, 7F_,10,1g, anã 25A. 

### The fieldwork 

### was performed on 

### one representative 

### engine in accordance

### with EpA Reference Methods 

### and DECS lntent 

### toTest 

### &Test Þlan Submittal 

### Lettei, urfrì.f, 

### was submitted 

### to Ohio Department 

### of En 

## on March 11,

## 2009. The following D 

### program: 

## Mr. Mark Grigereit, Environ 

### Environmental 

### Technician

### and Mr. Fran 

### was 

### the project 

### leader. Mr. Grigereit h 

### testing 

### for DTE Energy and private consu of source 

### testing experience testing 

### for D 

## Mr. Thomas Durham, Environmental Engíneer, 

### DTE Energy Resources, LLc

rocess coordination 

### for thetesting 

### program. Mr. Dave Terry, 

### power

,

### Shaw Environmental

### & lnfrastructure Group provided on-site 

### support 

### ofthe 

## units. Mr.Terry Sanner, Environmental Specialist 

### with the Pollution Control, 

### SW District Office 

### of

### the OEPA reviewed

### the Test Plan and observed the testing. 

# 2.0 SOURCE DESCRIPTION 

### The Bellefontaine Gas Producers, LLC power generating 

### facility, located at 

### 2g46 US 

### Route 

### 68 North, Bellefontaine, 

### Ohio 

### is

## a power generating"facility. 

### The facility 

### consists

## of three 

### (3) similar landfill gas-fired intãrnal combustion 

### engines with 

### associated electrical generators The systems are 

### caterpillar G352oc

# - 12oo 

### RPM 1600 

### kw Engine Generator sets. The sources utilize landfill gas from 

### the Cherokee Run 

### Landfilltiproduce energy 

### that 

## is sent 

## to the electrical 

## grid. All testing 

### was performed 

### while

### the enginã was operating 

### atfull load conditions (2,233 B

# lp). See Figure 

### 1 for

### a diagram 

### of the 

### tested units' stack 

### dimension and 

### sampling location.

# 3.0 SAMPLING AND 

### ANALYTICAL PROCEDURES



### DTE Energy obtained emissions measurements 

## in accordance

### with procedures 

### specified in

### the USEPA Standards of 

### Performance for New Stationary Sources. The 

### sampling and analytical 

### methods used 

### inthe testing program 

### are indicated 

### in the 

### table below. 

### Sampling Method Parameter 

### Analysis USEPA Methods 1-2 Exhaust 

### Gas Flow Rates Field data analysis and reduction 

### USEPA Method 

### 3A Oxygen 

### & CO2 lnstrumental 

### Analyzer Method 

### USEPA Method 4 Moisture 

### Content Field data analysis and reduction 

### USEPA Method 5 Particulate 

### Matter Gravimetric Analysis 

### USEPA Method 6C 

### Sulfur Dioxide Ultraviolet Fluorescence lnstrumental 

### Analyzer Method 

### USEPA Method 7E Oxides 

### of Nitrogen Chemiluminecent lnstrumental 

### Analyzer Method 

### USEPA Method 10 

### Carbon Monoxide NDIR lnstrumental 

### Analyzer Method 

### USEPA Method 18 

### Gaseous Organic Compounds (Methane) GC 

### Analytical Method 

### edlarru Bao Samn 

### USEPA Method 

### 254 Total Hydrocarbon 

### Compounds FID lnstrumental Analyzer Method

2

## DÌE Energy'



# 3.1 STACK GAS 

### VELOCITYAND FLOWRATES (USEPA METHODS T.2) 

## 3.1.1 Sampling Method 

### Stack

## gas velocitytraverses 

## were conducted

## in accordance 

## with the 

### procedures outlined 

### in USEPA Method 1, 

### "sample and Velocity Traverses 

### for Stationary Sources," and Method 

### 2, "Determination of Stack Gas Velocity and 

### Volumetric 

### Flowrate." Two (2) sampling 

### portswere utilized 

### onthe Únit's 

### exhaust duct, sampling at

### four (4) 

### points per portfor a

### total of 

### eight (8) points. Sampling 

### was conducted in conjunction 

### withthe gaseous emissiõns testing. 

### A cyclonic 

### flow check 

### was performed prior 

### totheflowrate 

### testing. Testing in 

### the stack demonstrated

### that no cyclonic 

### flow 

## is present. Data has béen 

### included in

### Appendix D demonstrating 

### the absence of cyclonic flow. 

## 3.1.2 Method 2 

### Sampling 

### Equipment 

### DTE Energy's 

### EPA Method

## 2 sampling 

### incline manometer, 

### S-type pitot 

### tube (Co thermocouple. 

### equipment consisted 

## of

## a 0-10" 

### = 0.84) 

### and

### a Type-K calibrated 

# 3.2 OXycEN AND CARBON D|OX|DE (USEPA METHOD 3A) 

## 3.2.1 Sampling Method 

### Oxygen (O2) 

### and Carbon Dioxide 

## (COt emissions 

### were evaluated using 

### USEPA Method 

### 34, "GasAnalysis 

### for

### carbon Dioxide, 

### oxygen, Excess 

## Aii and Dry Molecular 

### Weight (lnstrumental 

### Analyzer 

### Method)". The analyzers utilize 

### paramagnetic 

### sensors. Testing 

### was pedormed simultaneously with 

### the 

### particulate emissions 

### testingand consisted 

### of triplicate 60-minute sample runs. 

## 3.2.2 02l CO2Sampling Train 

### The DECS 

### EPA Method 3A sampling system consisted 

### of (1) 

### a single-point 

### sampling 

### probe (placed 

### inthe center

### ofthe stack), (2)

## a heated TeflonrM 

### sampling 

### line, (3)

## a Universal@ 

### gas conditioner 

### with particulate

### filter, (4) a 

### flexible unheated 

### reflonrM sampling line, 

### (5)

### a servomax 1400 

### ozlcoz gas analyzer, 

### (6)appropriate USEPA Protocol 1

### calibration gases, 

### and (7)

### anllO Plexer@ Data

### Acquisition System.

## Energy'

3.3 

### Refer

## to Figure 

## 3for

## a schematic 

### ofthe Oz, COz, SOz, NO", 

### and CO sampling train. 

## 3.2.3 Sampling Train 

### Galibration The Oz

### and COz 

### analyzers were calibrated according 

### to procedures outlined 

### in USEPA Method 

## 7E. Zero, span, 

### and mid range calibration gases were introduced 

### directly into

### the analyzer 

### to determine 

### the instruments linearity. 

### A zero 

### and míd 

### range 

### span gasfor each dilluent 

### was 

### then introduced through 

### the entire sampling system 

## to determine sampling 

### system bias 

### for each analyzer atthe 

### completion of each test.
MOTSTURE DETERMTNATTON (USEPA METHOD 4) 

## 3.3.1 Sampling Method Determination 

### ofthe moisture content 

### ofthe exhaust 

### gas 

### was performed using 

### the method described 

### in USEPA Method 

### 4, "Determination 

### of Moisture 

### Content in 

### Stack 

### Gases". The moisture 

### was collected in 

### glass impingers, and 

## the percentage 

## of water

### wasthen derived 

### from calculations 

### outlined in 

### USEPA Method

# 4. Moisture determinations 

### were made in conjunction with particulate sampling.
PARTTCULATE MATTER (USEPA METHOD 5) 

## 3.4.1 Filterable PaÉiculate Sampling Method (USEPA METHOD 5) 

### USEPA Method 

### 5, "Determination 

### of Particulate Emissions 

### from Stationary 

### Sources" 

## was used

# to measure

## the filterable (front-half) particulate 

### concentrations 

### (see Figure 

### 2 for 

### a schematic 

### of

### the sampling 

### train). Three 60-minute 

### test runs 

### were conducted. 

### The DECS Method 

### 5 modular isokinetic 

### stack sampling system consisted 

### of (1) 

### a staÍnless-steel 

### button-hooknozzle, (2) 

### a heated glass-lined probe, (3) a 

### heated 

## 4" glass 

### filter holder

### with

## a glass 

### fiberfilter, 

### (4)

## a set

## of four Greenburg-Smith 

### (GS) impingers

### withthefirst and second 

### each containing 

### 100 milliliters 

### (mL) 

### of HzO,

### the third 

### dry and

### a fourth impinger containing 

### approximately 

### 300 gramsof silica 

### gel desiccant, (5) 

### a length

### of sample line, 

### and (6)

### an Environmental Supply@ 

### control case equipped 

### with 

### a pump, dry 

### gas meter, 

### and calibrated orifice. 3.4



### 43.5 

## DTE 

## Energy"

After completion 

## of thefinal leak

### test

## for each

### test run, 

### the filter was 

### recovered, 

### and

## the probe, nozzle 

### andthefront half

## of thefilter holder 

### assembly 

### were brushed 

### and rinsed 

### with acetone. 

### The acetone rinses were 

### collected in 

### a pre-cleaned 

### sample

### container. DECS labeled

### the container with 

### the

### test number,

### test location, 

### test date, and marked

### the level 

### of liquid 

### onthe 

### outside 

### of

### thecontainer. lmmediately 

### after recovery,

### the sample containers 

### were placed in

### a cooler for storage. 

### The acetone rinses 

### weretransferred

## to clean pre-weighed 

### beakers. The 

### beakers 

### were weighed following room-temperature evaporation, 

### and then 

### desiccated 

### to 

### a constant 

### weight (<0.5mg 

### variability). Filters 

### were dried in a 

### desiccator 

## to 

## a constant 

### weight (<0.5mg

### variability). The data sheets 

### containing

### the initial and 

### finalweights onthefilters and beakers 

### can befound in

### Appendix G. 

### Collected 

### field blanks consisted 

### of afilter blank 

### and acetone solution blank. 

### The acetone blank 

### was collected 

### from 

## the rinse bottle used 

## in sample 

### recovery. The blankfilterand acetonewere collected and analyzed following 

### thesame procedures used

### to recover and analyze the fìerd sampres. 

### The impinger solution volume 

### was measuredto 

### determine moisture content 

### of 

### the gas 

## stream. After measuring 

### and recording

### the liquid volumes, the solution 

### was discarded Field data sheets 

### for Method 5

### sampling can be

### found in

### Appendix D. 

## 3.4.3 Quality Gontrol and 

### Assurance 

## All sampling 

### and analytical equipment 

### was calibrated according

## to the 

### guidelines referenced in EPA Method 5. Calibration 

### data can be referred 

### to in

### Appçndix B.
SULFUR DIOXIDE, OXIDES OF NITROGEN

### AND CARBON MONOXIDE 

### (usEPA METHODS 6C, 7E

### AND 10) 

## 3.5.1 Sampling Method 

### Sulfur dioxide 

### (soz) emissions 

### were evaluated using USEPA Method

### 6c, "Determination 

### of Sulfur Dioxide Emissions 

### from Stationary 

### Sources". The SO2 

### analyzer utilizes 

### an ultraviolet 

### fluorescence 

### detector. Oxides 

### of nitrogen 

## (No, emissíonswere evaluated using USEPA Method 7E, "Determination 

### of 

### oxides of Nitrogen Emissions 

### from Stationary 

### sources", The 

### No" analyzer

## DïE Energy' 

# K

utilizes 

### a Chemiluminecent 

### detector. Carbon monoxide (CO) emissions were 

### evaluated 

### using USEPA Method 

### 10, "Determination

## of Carbon Monoxide 

### Emissions 

### from Stationary 

### Sources". The 

## CO analyzer utilizes

### an NDIR detector. 

## 3.5,2 SOz, NO,, 

### and CO 

### Sampling Train 

### The EPA Methods 6C, 7E

### and 10 sampling 

### system consisted of (1)a single

### point sampling 

### probe (placed 

### inthe center 

## of the stack), 

### (2)

## a heated TeflonrM 

### sampling line, (3) 

### a Universal@ 

### gas conditionerwith particulate filter, 

## (4)

# a flexible unheated TeflonrM 

### sampling 

## line, 

## (5)

# a Bovar-Western 

### Research SO2

## gas analyzer, 

### TECO 

## 42i Chemiluminecent NO/NO" gas 

### analyzer,

### andTECO

### 48i NDIR 

### CO 

### gas analyzer, 

### (6) appropriate USEPA Protocol 1

### calibration gases, and (7) 

### an l/O Plexer@ Data Acquisition System. 

### Refer

## to Figure

## 3for

## a schematic

## ofthe 02, COz, SOz, NO*, 

### and CO sampling train. 

## 3.5.3 Sampling Train Galibration 

### The sampling 

### train 

### was calibrated according 

## to procedures outlined in 

### USEPA Method

## 7E. Zero, span, 

### and 

### mid range calibration 

### gases were introduced 

### directly into

### the analyzer 

### to determine

### the instruments linearity. 

### A zero 

### and mid range span gas 

### for each pollutant 

### was then introduced through 

### the entire sampling system 

## to determine sampling system bias 

### for each analyzer at

### the completion ofeach test. 

# 3.6 METHANE (USEPA METHOD 18) 

## 3.6.1 Sampling Method 

### Methane (CH¿) emissions 

## were evaluated 

### using USEPA Method 18, 

### "Measurement

# of Gaseous Organic Compound Emissions

# by Gas 

### Chromatography (TedlarrM 

### Bag Sampling)". 

## This method involves the collection 

### of exhaust 

### gas in a

### Tedlartt b"g, which isthen analyzed at an offsite laboratory by 

### gas chromatography (GC) Results

### from

### the methane sampling 

### were used 

### to determinethe non-methane 

### organic compound concentration from 

### the

### source. Methane emissions were subtracted 

### from total organic compound 

### emissions (asdetermined by Method 254).

## DTE 

## Energy.

3.6.2 CH4 

### Sampling Train 

## The Method 

### 18 sampling system followed

## the procedures 

### specified in 

### section 8.2.1,lntegrated Bagsampling &

### Analysis. The sampling system 

### consisted 

### of (1)

### an un-heated TeflonrM 

### sampling 

### line (kept

### tothe minimum 

### length required) located 

### after

### the heated sampling 

### line 

### and immediately before 

### the

### JUM 1094, (2) 

### asampling lung

### with 1O-literTedlarrM 

### bag, and (3) a

### vacuum pump 

### with regulator. Refer

### to Figure

### 4 for a schematic of

### the Method 18 sampling train. 

## 3.6.3 Sampling Duration & Frequency Methane samples 

### were collected simultaneously 

### with

### thetotal hydrocarbon 

### (THC) 

### testing. The vacuum pump flowrate 

### was set

### to allow 

### for

### a constant rate, integrated sample, collected for

### the duration ofeach 

### test run. 

## 3.6.4 SamplingAnalysis DECS labeled 

### the tedlar bag samples with the

### test number,test location and 

### test

### date. The samples 

### were shipped overnight 

### via Federal Express 

### on the 

### daythattheywere 

### collected. Methane analysis 

### was performed 

### on the 

### following

# day. Analysis, performed 

## by EnthalpyAnalytical Laboratory, 

### Durham, 

### NCfollowed guidelines 

## of EpA Method 

### 1g, including triplicate analysis 

### and aspike recovery 

### study. Analytical results 

### for M18 

### arelocated in 

### Appendix G. 

# 3.7 TOTAL HYDROCARBON COMPOUNDS (USEPA METHOD 25A) 

## 3.7.1 Sampling Method Total hydrocarbon compound (THC) emissionswere evaluated using USEpA Method 

### 25A, "Determination of 

### Total Hydrocarbon Emissionsfrom Stationary 

### Sources (lnstrumentalAnalyzer 

### Method)". The

### THC analyzer utilizes aflame ionization 

### detector 

### (FlD). The FID measures 

### total hydrocarbon compounds. 

## 3.7.2 THC 

### Sampling Train 

### DECS' 

### EPA Method

### 254 sampling system consisted

### of (1)

## a single-point 

### sampling 

### probe (placed 

### inthe center 

### of the stack), (2)

## a heated TeflonrM 

### sampling line, (3) 

### aJUM 1094@ 

### THC

### gas analyzer, 

### (4) appropriate certified calibration gases, 

### and (5) aThermoWestronics@ Data

### Acquisition System.

7

## DTE 

## Energy"

Refer

### to Figure 5

### for a schematic ofthe 

### THC sampling train. 

## 3.7.3 Sampling Train Galibration 

### ln accordance

### with USEPA Method 25A,

### a4-point 

### (zero,low, mid, and high) 

### calibration 

### check 

### was performed 

### onthe

### THC analyzer. The analyzer was 

### calibrated 

### with propane 

### inthe 0-1,500 

### ppm 

### range. Calibration 

### drift checks 

### were performed at

### the completion of

### each run. 

## 3.7.4 Sampling 

### Duration & Frequency 

### The THC gaseous emission testing 

### was performed simultaneously 

### with the 

### other emissions 

### sampling. Data

### was recorded

### at 4-second interuals and average 

### over 1-minute periods. 

# 3.8 QA/QC

### AND POST TEST PROCEDURES 

## 3.8.1 Quality 

### Control and 

### Assurance (O2, CO2, SO2, NOr, 

### and GO) 

## All sampling

### and analytical equipment 

### was calibrated according

## to the 

### guidelines 

### referenced 

### in Methods

### 34,

## 6c, 7E,

### and 

## 10. calibration gases 

### were EPA Protocol 

## 1 gases 

### and

## the concentrations 

### were within the 

### acceptable 

### ranges (40-60% mid range 

### and span) specified 

### in Methods 3A 

### and7E. Calibration 

### gas certification 

### sheets are located in

### Appendix B. 

### DTE performed 

### converter efficiency 

### testing 

### by directly challenging 

### the NO* analyzer 

### with 

### a nitrogen dioxide (NOz)

### calibration 

### gas of 

### 49.63 

### ppm. Results 

### from

### the converter efficiency

### test demonstrated 

### that

### the analyzer 

### met the requirements 

### of Method 75(ec t). Eq. 1
Eff.,^^

### -Co,, 

## - 49'5 =99o/o 

### ' ,r No2

## - ç, 59.63

8

### IDTE 

## Energy.

3.8.2 Quality Control 

### andAssurance (NMOC) 

### TheTHC sampling equipmentwas calibrated 

### with propane (c¡Ha) according 

### tothe guidelines referenced 

### in Methods

## 254. Calibration gases

### were EpA Protocol 1

### gases and 

### the concentrationswere within 

### the acceptable ranges 

### (25-35% low 

### range, 45-55% mid range 

### and 80-100 span). 

### An analyzer response 

### factor (RF) 

### of 3

### was appliedto

### the CHaconcentration 

### inthe exhaust 

### gas, as determined 

### by Method 18 

### sampring. The cHa 1"g methane)

### was converted 

### to CJJ+^(", propane)

### in order

### to subtract

### the CH¿

### from the 

### THC measured in 

### 1¡" ¡"¡6Go' z). 

### Eq.2


### NMoc 

## : THCrrrlosc3Hs) 

## -(cn^rfrrr^,) =

# ro,

# t#) = 

### ND

Calibration 

### gas certification sheets are located in

### Appendix B. 

# 3.9 DATA REDUCTION 

### Data collected 

### during

## the emissions 

### testing 

## was reported according to 

### emissions limits 

### specified inthe

### facility's OEPA Permit 

### to lnstall No. polOeOgO 

### and EPA Subpart

## JJJJ. Particulate 

### and SOz emissions 

### were reported as 

### pounds per million Btu 

### (lb/MMBtu). Oxides of nitrogen, CO, 

### and NMOC were reported 

### asgrams per brake horsepower hour (g/BHp-Hr). Emissions 

### calculations 

### are based on calculations located in USEPA Methods 1-5

### and 

### 19. A fuelfactor for

### the landfill 

### gas

### was determined 

### from landfill gas 

### sampling 

### at the inlet 

### to the 

### engine. Example calculations 

### are presented in 

### Appendix C and landfill 

### gas analysis is 

### presented in

### Appendix G. 

### Non-methaneorganic compound emissions are reported 

### as non-detect (ND). 

### Methane 

### is collected 

### via Method 18 (GC) 

### and reported 

### as methane. The concentration is

### then divided by 

### 3 per Method 

### 254 so

### that methane can be 

### subtracted 

### from 

### thetotal hydrocarbon concentration (reported 

### as propane) established bytesting 

### with a FlD,


# I

## DÏE

4.0 

## Energy'

OPERATING PARAMETERS
The test 

### program included 

### the collection of 

### generator load (kW), engine speed 

### (RPM), inlet manifold 

### air pressure (psi),

### fuel upper heating 

### value (BTU),fuel 

### flow (scfm) and 

### generator operating hours (kW-hour). 

### Operationaldata are located in

### Appendix F.

RESULTS


### The results of 

### the testing indicate 

### that Unit

### 3 is in compliance 

### with emissions 

### concentrations 

### stated 

### in Ohio Permit

## to lnstall 

### No. P0103690

### and EPA 40 

### CFR Part 

### 60 Subpad JJJJ. Testing

### was performed 

### while 

### the engine was operating at

### the maximum rated horsepower.



### Emissions Testing Summary Bellefontaine Gas 

### Producers, LLC 

### Bellefontaine, OH 

### Unit 3 

### Operational Horsepower

## - 2,233 

### BHp



### June 3,2009 5.0



### Unit 3 Sulfur Dioxide (lb/MMBtu) Oxides of

Nitrogen lolRHn-Hrl Carbon

Monoxide lolBHo-Hr) NMOC

(g/BHp-Hr) Particulate

(lb/MMBtu) Permit Limit 0.5 0.60 3.0 1.0 0.062 Test 1 001 052 27 ND 0.004 Test 2 001 0.52 27 ND 0.002 Test 3 001 0.52 27 ND 0.002 Average 0.01 0.52 2.7 ND 0.003

10

## DIE Energy" 

# K

6.0 C ERTI FICATION STATEMENT 

### "l certify 

### that Ibelieve 

### the information provided in

### thisdocument istrue, accurate, and 

### complete. Results of

### testing are based onthe good 

### faith application ofsound 

### professionaljudgment, using techniques, factors, or 

### standards approved bythe Local, 

### state, or Federal Governing body, or 

### generally accepted inthetrade."



### This report 

### prepared by:
Environmental 

### Management and Resources DTE Energy Corporate 

### Services, LLC



### This report 

### reviewed by:Supervisor, Stationary 

### Source &

### Ambient Monitoring Environmental 

### Management and Resources 

### DTE Energy Corporate 

### Services, LLC

11

## DïE Energy'

RESULTS 

### TABLESResults Table 

### I Gaseous Emissions Testing Results

Unit 3 Bellefontaine Gas Producers, LLC Bellefontaine, OH Parameter Run 

### I Run 2 Run 3 Aver Sampling Date Sampling Start Time Load (BHp) Flowrate (scfm) Flowrate (dscfm) Average 02 Content (%, dry) Average O, Content (%, dry, corrected)1 Average CO Concentration (ppmv, dry) Average CO Concentration (ppmv, dry, corrected)1 Average GOConcentration (ppmv, dry, corrected)2 Average CO Emission Rate (lb/hr) Average CO Emission Rate (gram/BHp-Hr, dry) Average NO" Concentration (ppmv, dry) Average NO,. Concentration (ppmv, dry, corrected)1 Average NO" Goncentration (ppmv, dry, corrected)2 Average NO, Emission Rate (lb/hr) Average NOx Emission Rate (gram/BHp-Hr, dry) Average SO2 Concentration (ppmv, dry) Average SO2 Concentration (ppmv, dry, corrected)1 Average SO2 Concentration (ppmv, dry, corrected)z Average S02 Goncentration (lb/MMBtu) Average THC Concentration (ppmv as C3H6) Average CHa Concentration (ppmv as CH4) Average CHoConcentration (ppmv as C3Hu)3 Average NMOC Concentration (ppmv) Average NMOC Concentration (ppmv, corrected)2 06/03/09 0804-0904 2,233 5,726 5,038 8.0 8.1 584.7 601.6 277.8 13.22 2.7 69.6 71.1 32.8 2.57 0.5 4.9 4.9 2.3 0.01 545 1,730 577 ND ND I 06/03/09

0952-1052 2,233 5,762 5,045 8.0 8.1 579.0 597.5 276.0
13.15 2.7 69.7 71.4 33.0 2.58 0.5
5.4 5.6 2.6 0.01 550 1,723 574 ND ND 06/03/09

1132-1232 2,233 5,796 5,071
8.1 8.2
573.1 591.9 274.1 13.09 2.7 68.7 70.7 32.7 2.57 0.5
5.8 5.9 2.7 0.01 557 1,690 s63 ND ND 5,761

5,051 8.0 8.1 578.9 597.0 275.9 13.2 2.7 69.3 71.1 32.8 2.6 0.5
5.4 5.5 2.5 0.01
s51 1,714 571 ND ND lcorrected for analyzer drift as per USEPA Method 7E 2al15Yo02 3corrected as C3 kW:killowatts 02 :oxygen CO :carbon monoxide NO* :oxides of nitrogen ND : non-detection (less than zero) THC :total hydrocarbons CHa : methane C3H6 : propane NMOC : non-methane organic compoundsResults Table 2 Particulate Emissions Testing Results Bellefontaine Gas Producers LLC Bellefontaine, OH June 3, 2009

Start Time Stop Time

Meter Temperatureïm (oF) Meter Pressure - Pm (in. Hg) Measured SampleVolume (Vm) Sample Volume (Vm-Std) Condensate Volume (Vw-std) Gas Density (Ps(std) lbs/ft3) Total weight of sampled gas (lbs) Nozzle Size -An (sq. ft,) lsokinetic Variation - |
Average Stack Temperature -Ts (F) MolecularWeight Stack Gas- dry (Md) MolecularWeight Stack Gas-wet (Ms) Stack Gas Specific Gravity (Gs) Percent Moisture (Bws) Water VaporVolume (fraction) Pressure - Ps ("Hg) Average Stack Velocity -Vs (ft/sec) Area of Stack (ft2) Exhaust Gas Flowrate Flowrate (acfm) Flowrate (scfm) Flowrate (dscfm) Particulate

oncentration lb/1000|b (dry) lb/10001b (wet) lb/1000 lb (wet, correctedto 50% EA) Particulate Emission Rate

culate Goncentration Percent 02 Fuel Factor (F¿) lb/scf (C6) lb/MMBtu 71.92 30.12 39.12 38.36 5.39 0.07396 3.24 0.0001709 103.4

877.1 30.11 28.62 0.99 12.33 

### 0j23 29.85 173.93 1.40

14,571 5,761 5,051

lb/hr 70.50 30.12 38.48 37.84 5.16 o.o7407 3.19 0.0001709 102.3 72.44

30.12 39.23 38.43 5.47 0.07393 3.25 0.0001709 103.7 72.81

30.12 39.65 38.82 5.55 0.07388 3.28 0.0001709 104.3

876.9 30.11 28.66 0.99 12.01 o.120 29.85 172.82 1.4 877.4

30.11 28.60 0.99 12.45 o.125 29.85 174.00 1.4 877.O

30.1 0 28.59 0.99 12.52 0.125 29.85 174.96 1.4

8.1 8,714 1.664E-07 0.002

## DTE 

## Energy" 

# K

FIGURES

## IDTE 

# Energy'

Stack Diameter 16"



### Figure No. 1 DTE Tesi Traifer

Velocity Measurement Points Distance From lnner Wall 1.07 4.00 12.00 14.93



### Source Diaqram Bellefontaine Gas Producers, LLG ck Sampling Group tal Management &

## DTE Energy"

Figure No. 2 USEPA Method 5 Heated Probe M Pyrex Glass Liner & SS Nozzle

Management & Resources

# Energy"

Heated Sample Line

Calibration Line DataAcquisition System

Flow Controller

Calibration Gas



### Figure No.3 USEPA 

### Methods 3N6Cl7El1O Site: Bellefontaine Gas Producers, LLC Bellefontaine, OH Sampling Date: June 3, 2009 Stack Sampling Group Environmental Management & Western Research SO2
TECO 42i NOxAnalyzer 

# c""O Conditioner 

# I TECO48iCO Analyzer
Servomax O2|COZ Analyzer

# IDïE 

# Energy'

Figure 

### No.4 USEPA 

### Method 

## l8 JUM 1O9A

Tedlar Bag Heated Sample Line

Teflon Sample Line

Vacuum Pump

Site: Bellefontaine Gas Producers, LLC Sampling Date: llefontaine, OH June 3,2009 Stack Sampling Group Environmental Management &

# IDTE 

# Energy'

Figure 

### No.5 USEPA 

### Method 254

J.U.M. IO9A Methane/Non-Methane Total HydrocarbonAnalyzer

Flow Controller

Sampling Date:

June 3, 2009 Bellefontaine Gas Producers, LLG Stack Sampling Group Environmental Management &

## DIE Energy.

APPENDIX 

### A OEPA TEST PLAN,*l-! Siiu+Ìi: :1,{,¡É¡1. S+sct.. .ìl¡it* Íi{liii ,iiÍ:íì,.Irir+r. l'¿fil.:i:í,e..ut .¿ù l:û,{ Ii"i;: ,¡i,$ìtÐ +&),I Ë.:r:rs: ?..14_ì[)i-.t8iir].



# IITEtu*wgry
It4arch 11,2009 Mr, Terrv Sarlrre'r Ohio EPA DAPC Southlvest Dístrict ()ffi ce 401 East Fifth Streert Dayton, 

### OII 43311 ü'!Fì Ênergg kieswrces



### Rer Intent to Test

### î¡ Test pløn Subtnittal

Bcllefontøíne G,as Producers, LLC (pertnit No, p010-q6g0) Bellefontaíne, öhio Dear lvfr Sanner: On behalf of Bcllefontaine Gas Procìucers, LI-C (BGI'j), DTE Errergy Resources, Inc. is pleasecl to submit the attached Intent to Test arrdTest Plan for rerriew and-approval. In accordarrcewith Ohio Envirortmental Protection Agency - Dil'isior.r <¡fAir Pollution Control, Permit-to-Insta.ll and Operate No- P0103690, BGP operates three internal combustiorr engines at thefacility (Ir001, p002 anct P003). The attached Test Ptan prese'nts the methodology proposecl for the Compliance Demonstratio., BGI) proposesApril 15, 2009 asthe clate fclr tesiing. The CAT 3520C engirres installed at the site are iclentical rnodels ancl lvere all installed cluring the same period by the same personnel. z\s prevíously irclicated in the NSIjS Commencement of Const¡uction Notification, the 'buiit date' fc¡¡all th¡c'e engines are between Nlay 73-17,200g. With resPect to manufacturing and installatiory the engines are as identical as possiÛle, In consideration of both thetruly identicaì nature of the engines, and clfthe unusual financial Pressures facin¿¡ businesses atthis time, BGP is requesting that OEPA allow for a Compliance Demonstration based on ihe testing 

### of olrly onc'

### of the three IC engines, From 

### a technical perspective it is our belief that there is absolutely no reason, atthis time in the tife cycle of the engines, 

### to exPectthat their emission profiles are

### different. Similarly,

### in a time of nearly unprececlented fi¡ancial uncertainty BGP, like all businesses, is aggressively looking fr-lrlvavs to control exPenses' We believe thatthis one en6;inetest approacÈ, 

### pr"runtr,r"ry'iittl" ¡ìsk of undiscor,'ered non-compliance, while allowingtlGP

### to ccmtinue 

### to serve the community of Bellfontaine through the 'berreficial use' operati<r of the plant.
-A.s mentionecl, pending your approval of thethis plan, testing is scheclulecl for Apriì 1.5,2009. I can be corrtactecl at Q3Q 3t2-82j4 or af durh-amt@clteelrerqli.com if you have any questions or need aclclit.ional info¡nration. Silce'rel1., RCES

Environmental lìngineer Gary Autoìitano, lJellefontaine Cas procf ucers, Ll,CINTENT TO TEST NOTIFICAT|ON (One Emissions Unit per Sheet)

A. Facility Contact lnformation: 

### Name Bellefontaine Gas proCucers. LLC Address Contactperson Mr. Gary Autolitano Telephone

### (O) 570.383.7170

_ (Ce[) 570.446.g256 E-mait B. Test Location lnformation: 

### Name Bellefontaine Gas producers, LLC Contactperson Mr. Garv Autolitano Proposed Test Date -April 1S,2009 Proposed Start

### Tme 09;00am Testing Firm lnformation; 

### Name DTE Energy Corporate Services, LLC Address 6'100 WestWarren, Detroit, Ml 4g210 ContactPerson Mr. Mark

### Gricereit

__ Telephone(O) 313.897.1324 (Cell) 313.412.030s 

### E-mail qrigereitm@dteenergv_coq 

### Address 2946 US Route 6g North. Bellefontaine. OH 4331 1 Telephone

### (O) 570.383.7170 (Ceil)



### _ Facility Premise No. Emissions Unit pTl NoSCC Number 0546015002 P0103690 20'100802



### c' Test Plan and Emissions unit lnformation Table: List the applicable information under each respective column heading

Are anv modifications, or altematives as spelled out within the test methods, being proposed? yes

### D Uo 

### El lf ,,no,,, then no modifications or altematives, however minor, will be accepted' lfyes' list each test method and section beíng modífied, and attach adetailed modification description andjustification: 

### Sourceistestingtocomplywith(checkalllhatapply):StatePTl8StatePTo8TitleV[NSPSxMAcT[*', 

## t T:î: :::,Ï::Ï:i ',::":_:i:::1" .|. i:rousfrnul of the emissions unit siven in irs permft-ro-insrail oroermir-ro-operate? 1.600 kw electricar oursut thetest? Yes 

### EI No

### ! tfno,attachexplanation. Specifo how the operating rate will be dernonstrated during testing: Sampling Location(s); lnlet 

### I Ouflet EJ Simuttaneous 

### fl Fuel Sampling: Coal - proximate

### n Ultirnate 

### El Ot¡er

### n Power outout will be mgnitored throuohout the test Will Cyclonicflowcheck(s)beconducted? yes 

### El t¡o

### E Ifother,specifl: Emission rate to be calculated using: F_Factor EJ Uttimate Coal Analysis

### ü Otner

### fl I other, speciry: Has any maintenance or parls replacement been performed on the emissions unit orthe control eguipment within the lastyear? yes

### ü r.¡o El lfyes, briefly describe: (Note: some maintenance' such as installing newfilter bags in a baghouse, or replacing the activated carbon in an adsorber, may disqualifli the emission. 

### *i*l performance test until a sufficient amount of time has elapsed to ensure a lest whichwill be representative of normal operations.) tsm¡sston unit #/ Descriotíon Control

Eouioment Monitoring

Equipment rouuranr(sj to be lested EPA Test Method(s) Number of Samplinq Points Total Time for Sample Run Number of

Samplino Runs P001-P003 Landfill GasFíred Engines None None TSP, SO2, NOx, CO, Methane, THC tvtl-c, w¡orJr lvt/ts, lvl1u, M18, M25A appropriate number per proposed mefhods 60 min

E' Sample Train calibratlon: All affected measuring and rnonitoring equipment should be calibrated within 60 days of the schedufed

### testing. ohioEpA IUo71a. 

## Test Plan

# - Bellefontaine Gas 

## Producgrs- .LLÇ 

## CAT G3520C lG Enqing,S.tack 

## Ëxhausts lVames,

### tÍtles,

## and telephone numbers 

## for the persannel 

### directly involved with 

### study are listed 

### in the

### following table: fftrs

1b. 

### Name and 

### Title Company Telephone Gary 

### Autolitano Facility Manager Bellefontaine Gas Producers, LLC 

### 2946 US Route 

### 68 North Bellefontaine, 

### OH 43311 (570) 

### 38s-7170
Mr.

### Thomas Durham Enviro 

### nmental Engineer (DTE Energy Resources) DTE Energy Resources 425 S. Main Street Suite 201 Ann

### Arbor, Ml48104 

### (734) 302-8234

Mr. 

### Mark 

### Grigereit Air Quality 

### Specialist (DTE Environmental) DTE Energy Corporate Seruices, LLC 6100 West Warren Avenue Room H136 Detroit, 

### Ml48210 

### (313) 897-1s24

Type 

### of 

### industrial process or combustíon 

### facility: The Bellefontaine 

### Gas Producers, 

### LLCfacility 

## is located

## at 2946 

### US Route 

### 68 North, 

### Bellefontaíne,

### Ohio. The facílity is associated 

### with the Cherokee Run 

### Landfill. Bellefontaine 

### Gas Producers 

### operatesthree Caterpillar 

### G3520C reciprocating engines 

### with associated 

### generator sets,The engines are 

### fueled by landfill gas generated by

### the fandfill 

### and produce 

### electricitywhich is 

### sentto 

### the electric grid. 

### Type 

### and 

### quantity of raw and finished 

### materials used 

### in the 

### process.' The engines are landfill 

### gas-fired internal 

### combustion reciprocating 

### units, Fuel consumption 

### varies

### withfìeld pressure 

### and heat content

## of the

## gas. Perlinent 

### engine operating 

### parameterswill be measured throughout each emissions test. 

### Description of any cyclical or 

### batch operatíons 

### whichwould tendto 

### produce variable 

### emissions with time: The engÍnes operate per contract 

### with electricity providers 

### on an as needed basis 

### with load 

### varying according 

### to fuel 

### supply, Operation 

### is dependent 

### on landfill

### gasfield pressure. 

### Three (3)engines (Engines P001-P003) 

### operate at

### the

### facility. Testing witl 

### be performed on 

### one representatíve 

### engine at 90-100% speed and torque to meet Ohio PTI Requirements. 1c.

1d.7e. 

### Basic

### operatlng parameters used

### to regulate fåe

### process;

Operating parameters 

### used

## to regulate

### the engine Íncludes speed (RPM) and torque, 

### Additional Parameters monitored 

### will include

### fuelfiow, BTU content, 

### inlet 

## & exhaust 

### temperature 

## & pressure, 

### torque (bhp) and

### fuel air 

## ratio. Operating parameters

### will be documented during each test. Rated 

### capacity 

### of the 

### process and process rate 

### duríng the 

### testing: Testing 

### of the engine_will 

### be completed 

### during maximum (g0-100% speed and torque) operating 

### conditions. Testingwill consist oftriplícate 

### 60-minutetests. 

### Type 

### of

### control device associafe d

### with ffie 

### process.. N/A 

### Operating parameters 

### ofthecontrol device: N/A 

### Rated 

### capacity and 

### efficiency 

### af the

### control devÍce: NiA 

### Applicable 

### permit number and emission limits for the 

### process to be 

### fesfed; The Bellefontaine 

### Gas Producers, LLC landfifl 

### gas-fired engine emissions are regulated by 

### State

### of Ohio Permit

## to lnstall No. P0103690. The parameters 

## to be tested and their associated permit limits 

### are listed inthe following table: 

### Table A:



### Identify 

### all pollutants 

### to 

### be measured: See TableA, 

### Description 

## of the samplingtrain(s)

## to 

## be used, 

### includíng schematic diagrams

## if appropríate: 

### All emissions 

### testing

### will be performed according 

### to USEPA 

### Methodology. Sampling train diagrams are 

### depicted in

### the aftached figures (see Appendix 

### Afigures 2-s). 

### PartÍculate 

### (PM) sampling 

### will be conducted utilizing Method 

### 5. Testing

### will consist 

### of triplicate 60-minute 

### test runs. 

### Suffur Dioxide (SOz), 

### oxides

### of nitrogen (NO*), 

### and carbon monoxide (CO) testing 

### will be 

### completed according

## to Methods

## 6C, 7F*,

## and 10, respectively. Þrior

## to telting, a 1f.

2a.
2b.


### 2c.

3-

4.
5. Source 

### ïarget Emission Emission Limii Gram/Ho-hr Lb/mmBTU
2233HP Caterpíllar G3520C Particulate 0.062

Sulfur Dioxide (SOr) 

### 05 Oxidesof Nitroqen (NO") 0_60 Carbon Monoxide (CO) 3.0 

### Total Volatíle Organic Compounds 

### (voc) 1.06. stratifícatíon 

### test 

### will be performed according

### to Method

## 78. Testing 

### will be performed in



### conjunction

### with Method

# 5. Method 

### 1

# - Method 

## 4 data required 

### in the permit 

### will be collected from 

### the Method 5testing. 

### Total volatile organic sampling 

### (VOC)will be performed according 

### to lVethod

### 254. A single 

### sarnpling point 

### will 

### be selected inthe center of the stack according 

### tothe method. Testíng 

### will be performed in conjunction 

### with Method 

## 5. Method 1

# - Method 

### 4 data required inthe perm,it

### wifl 

### be collected 

### from 

### the Method

### 5testing. Testing

### will be performed utilizing 

### calibration gases of propane bafanced [n nÍtrogen. 

### Methane sampling 

### will be performed according 

### to Method 18 

### (Tedlar Bag Collection). The 

### methanesamples

### will be collected 

### in conjunction 

### withthe VOC samples 

### as 60-minute 

### integrated 

### bag 

## samples. Sampling

## will be performed 

## in triplicate 

### and sent

## to an 

### independent laboratory 

### for analysis. 

## Detailed sampllng 

### and analysis procedures, 

### includíng 

## the appllcable standard 

### methods referenced: Sampling and analysís methods 

### will include 

### the following: 

### Parameter Method 

### Analytical Method Exhaust gas 

### flowrates USEPA 

### Methods 1, 2 Field Data

### Analysisand Reduction Molecu[ar 

### weight USEPA Method 3A Paramagnetic 

### Analyzer Particulate 

### Matter USEPA Method 5 Gravimetric Analysis
SOz USEPA Method 6C NDIR

### Analyzer
NO" USEPA Method 7E Chemiluminescent 

### Analyzer
CO USEPA 

### Method 10 NDIR 

### Analyzer
Methane USEPA 

### Method 

## l8 Gas Chromatography


### VOC USEPA Method 

### 254 Flame lonízation Detector

### USEPA MEthod

# 1, ,'SAMPLE 

### AND VELOCITYTRAYERSES 

## FoR slÁiloA/ÁRy



## souRcEs", 

## and Method

# z, ,'DETERM\NAwaN 

# oF srÁcK vELoclry AND 

### FLoWRATE (TYPE-9 PITOT TTJBE)" 

### will be used 

### to measure exhaust gasflowrates in combination with 

### sther methods utilízed. 

### USEPA MCthOd 

## 3A, ''ÐETERMINATION 

## OF OXYGEN 

## AND CARBON DIOXIDE 

### coNcENTRAnOTS /N EMTSSIONS 

### FROM STATTONARy 

### SOURCES f/tVSrR TJMENTAL 

### ANALYZER PROCEDURE)",will be used to measure 

### exhaust gas moleðular weight. 

### USEPA MCthOd 

### 5, "DETERMINATION OF 

### PARTICULATE 

### MATTER EMÍSS/O/VS FROM 

### STATIONARÍ SOURCËS",

### wifl be used

### to measure 

### total solid particulate exhaust gas emission rates. 

### USEPA MCthOd 

## 6C, ''DETERMINATION 

## OF SULFUR 

### DIOXIDE E,IIISSIOA/S FROM 

### STATIONARy SOURCES (!^,SIRLIñ/IENT,4L 

### ANALZYER PROCËDURE)',, wÌil be used to measure exhaust 

### gas SO2 concentrations. 

## USEPA MEthOd 

# 7F., ''DETERMINATION 

# OF OX'DES 

# OA/ NÍTROGEN 

### O9NGENTRArO/VS 

### IN EMISSIO^IS 

### FROM STATTONARr 

### SOURCES (INSTRUMENTAL 

### ANALZYER PROCEDURE)'1 

### will be usedto measure 

### exhaust gas NO¡ òoncentrations. 

### USEPA MCthOd 

### 10, ,'DÊTERMINATION 

### OF CARBON 

### MONOXIDE 

### EM'ss,o,Vs 

### FRIM srATIoNARvsouÆcEs lrNsrRUfvlENTAL 

### ANALYZER 

### pRocEDUREl", wiil be used to rneasure exhaust 

### gas CO concentratíons. 

### USEPA MEthOd 

## 1B, .,MEASUREMENT 

## OF GASEOUS ORGANIC COMPOUND 

### EMISSIONS 

### BY GAS CHROMATOGRAPHY", 

### wilf be used

## to determine 

### the methane emission concentrations. 

## USEPA MCthOd 

## 25A, ''DETERMINATION 

# OF TOTAL GASEOUS ORGANIC 

### CONCENTRATION USTNG

# A FLAME IONIZATTON 

### ANALYZER",

## will be used to determine the 

### totalvolatile organic compound concentrations. 

# 7. The 

### number and 

### length 

### of samplÍng 

### runs which 

### utilt constitute a 

### complefe úesf.. 

### All ofthe emission 

### testing

### will be conducted 

### simultaneously. Testing 

### wili be comprised 

### of triplÍcate 60-minute 

### sampling runs. 8" 

### Ðímensioned sketches 

### showing all sampling ports 

### in downstrearn dìsturbances 

### or obstructions 

### ofgas flow: Sampling 

### will be conducted at

### the exhaust 

### stack locations (see Appendix A

### figure 1). 

### relation 

## tothe upstream 

### and depicted in

### the attached figures

### Flow (scfm)

10.

11.

12.

13.

14. 

# 9. Estimated 

### flue gas 

### conditions sucfi astemperature, 

### moisture and 

### veloclty: The estímated 

### flue gas conditions based on similar engines tested: 

### Load (kW) Temperature
1,500-1,600 900-1,000


### Projected 

### process operating eonditíons 

### during whìch thefesfs 

### will be 

### run: The engine 

### will betested during normal 

### operations. The testing 

### will

### take place will the engines is

### operating at

### the maximum load possible (>90% of rated capacity), 

### ÐescrÍption

## of any 

### process 

## or çontrol equipment data

## to 

## he collected durÍng the 

### fesfing; Data

### to be 

### collected during each day oftesting 

### will includethe following: 

### -Engine Speed 

### (RPM) -Load/ Power (kW) 

### -Gas Fuel Flow 

### (SCFM) -Fuel BTU Content -Fuel/ 

### Air Ratio 

### DescrÍptlon 

## of any manitoring data

## to

## be collected 

### duríng ffte

## fesf period (e.9.

# - contÍ n

### uous emisslo 

### n mon 

### ítori

### ng data) : N/A 

### Chain 

### of 

### Custody procedures; Standard chain 

### of custody procedures 

### will befollowed 

### for alltesting, 

## Field

## quality assurançe/quality

## control procedures 

### fe.g.

# - field blanks, sample storage 

### and

### transport methods): The sampling 

### team wíll prepare and calíbrate 

### field-sampling equipment 

### and perform quality 

### assurance/quality control (OA/OC) consistent 

### with the employed USEPA 

### methodology. To 

### ensureaccuracy of

### the 02, CO2, SO2, 

### NO¡ and CO 

### analyzers,a set of

### three (3) calibration 

### gases per analyzer 

### will be injected 

### through

### the referencesampling system 

### to demonstrate 

### the linearity 

### of

### the analyzers, The three gases

### will consist 

### of 

### a known concentration 

### of calibration gas, balanced 

### in 

### nitrogen. Calibration levels include span-100% 

### of range (high level), 

### at 40-60% 

### of span (mid), and 

### at <20o/o

### of span 

### (low). Additionally, 

### the NO¡ analyzer 

### will be calibrated 

### with a 40-60 pprn NO2 calibration 

### gasto demonstrate converter efficiency of >90%. 

### To ensureaccuracy of the VOC analyzer, a

### set of

### four (4) calibration gases 

### will be injected 

### through 

### the reference sampling system

## to demonstrate

### the linearity 

## of the analyzer, Ranges are as

### follows: 80-90%, 45-55o/o,25-350/o

### of span and 

### zero, The gases will consist15. 

## of 

## a known concentration 

## of propane 

### in nitrogen. All gases 

### wlll be documented EpA



### Protocol Number 

### 1,traceable

## to National lnstitute 

### of Standards 

### and Technology (NIST) Reference Materials. 

### Methods

### 5willfollow QA/OC standards 

### as described 

### inthe methodofogy. 

### The sampfing 

## team

## will prepare

## and catibrate fietd-sampling 

### equipment and

## -þerlorm qualit! assuranceiquality control 

### (OA/OC) consistent with thõ employed USEPA methodology. 

### Method 18

### will follow 

### QfuaC standards 

### as described 

### inthe methodology. Additionally, samples will beanafyzed 

### within 48 hours of collection 

### to assist in ensuring accuracy. 

### Laboratory 

### qualíty assurâncelquatity 

## eontrol procedures 

### utílized

# as paft

# of the fesfing.' Calibrations

### for USEPA Methods 

### 34, 6C, 7E

### and 10 

### will follow protocof stated in USEpA 

### Methods and

### will utilize appropriate calibratíon 

### gases. Method 

### b gravimetric analysis will 

### be completed 

### by DTE Energy's internal 

### laboratory. Weights wíll 

### bã collected 

### in a climate 

### controfled weight roorn,

### on

### a scalewhich is certified annually 

### and calibrated daily

### with 3 

### genified weights (2.00009, 30.00009, 

### 100.00009). Method 

### 5 samples 

### wiil be *uighuO to 

### 0.00059 constant weight 

### An lndependent laboratory, contracted 

### to perform Method 18,

### will be instructed 

### to perform all analysis and 

### QA/QC procedures according to

### the appropriate methodology. 

### Names 

### and titles 

### of personnel who 

### will be

### pertorming the 

### testing: Thetestíng will 

### be performed by DECS's Environmental Stack 

### Test ánd

### Ambient Monitoring 

### (STAM) group, with 

### theexception of Method .18analysis, 16.

Mr. Mark Grigereit, 

### Specialist

# QSTI DËCS 

### Mr. Fred Meinecke,

# Technician DECS 

### Methods 1B Project Leader LeadTechnician Enthalpy Analytical, Inc 22O2 Ellis Road 

### Durham, 

### NC 27703-5518 Phone Fax 919.850.4392

919.850.9012 

### The emission test report

### will include 

### the items 

### found on Ohio EPA General 

### Testing And Reporting 

### Requirements 

### form. lncluded 

### in

### the report 

### will be

### a site description

### with

### the reãson for testing, 

### source descriptions,

## a summary

## of results, 

### our sampling 

### and analytical procedures, 

### and test 

### results and discussion.

## APPENDIX 

## A FIGURES

# DTE Emergy.

Stack Diameter 16" Velocity Measurement Polnls Distance From 

### Points lnner WAIì 

### 1 0.70 

### 2 2.U 

### 3 4.74 

### 4 11.26 

### 5 13.66 

### 6 15.30

Figure No. 1 Source Diaqram Site: Bellfontaine Gas Produeers, LLC tack Sampling Group mentaf Management &Heated ProbeW Pyrex Glass Liner & SS Nozzte

Figure No. 2 USEPA Mêthod 5 msnagement& Resourceg

# llTE Energy'

Figure 

### No.3 USEPA Methods 3A/7El10 TECO 42i NOxAnalyzer
TECO 48i COAnalyzer
Servomax OzrcA? Analyzer

Flow Controller Heated Samle Líne

Calibratìon Line

lfontaine Gas Producers, LLC lefontaine, OH Stack Sampling Group Environmental Management &

# IDTE 

# Energy"

Probe (Center of Stack)
TeflonSampeLne 

## -'--

Vaccum Pump

Bldg Roof



### Figure No.4 USEPA 

### Method 18 Stainless 

### /
Flow

Tedlar Bag

!!!!!!=:t=!!=!!::!=!=!=:

Sampling Group ironmental Management & Bellfontaine Gas Producers, Ll-C Bellefontaine, OH Sampling Date: April, 2009

# DTË 

# Energy"

Figure 

### No.5 USEPA 

### Method 254 Flow Controller Heated Samle Line

J.U,M. 1O9A Methane/Non-Methane Total Hydrocarbon Analyzer

Sampling Date: April,2009 Site: Bellfontaine Gas Producers, LLC Bellefontaine, OH kSampling Group Environmental Management &

## Energy

APPENDIX B EQUIPMENT AND ANALYZER 

### CALIBRATION DATAEnvironmental Supply #r APEX TNSTRUMENTS EPA Method 5 522 Series Meter BoxCalibration Pre-Test Orifice Method English Meter BoxUnits, English K' Factor FiLename: s:\srAM Group\srAM Group rnfo\cal-ibrations\Meter l\ lo3-r2-og Fulr caribration-xlsl522oRpR5
!dLe:

------ Barometric Pressure: --------> Theoretical Critical Vacuum: ---> 3/12/09 29.8L (in. Hs) 14-06 (in- Hcr) Model #: Serial #: !!!!!!!!! IMPORTÀNT TMPORT.ANT !!!!:!!t! For valid test resuLts, Èhe AcEuar vacuum shoul-d be 1 to 2 in- Hq greater than the Theoretical critical vacuumstrom abowe-

Thecriticat orifice Coefficient, K', must be ent.ered in Bnglish..itr, (rt)^3*(des R)^0-5l((in-Hg)*(nin)).

__- DRY GAS METER READTNGS -CRITICÀ! ORTFTCE READINGS_ dH Time (in H2o) (nin) 0.58 l-1 .00 L.l-0 10-00 1.80 9 .00 3.30 8.00 5.30 6.00 Volume

rnataa_t (cuft) 951.200 955.159 962 -242 969.303 978.010 Vofume

Final (cu ft) 956-159 962.242 969 -303 978.010 985-089 cM7 3eMSl65-0 55 .0 65 .0 65.0 6s .0 Volume Inít.iaL Tery)s- Final Temps. TotaL lnLet OuÈl_et Inl_et OutLet (cuft) (deq F) (des F) (deg F) (deg F) 4.959 63.0 63.0 66.0 66.0 6

_083 66.0 66.0 69.0 58.0 7-06L 69.0 68

_0 73.O 69 .0 8.707 73.0 69.0 7s.o 70-0 8.079 75-0 70-0 77.0 70_o Orifice K' Orifice SeriaI# CoefficienE (number) (see above) cM48 0 -342 cM55 0.456 cM63 0

_58?

0.813 t.072 Actua1-- tunbientTemperature --

Vacuum Initial Final Average (in Hg) (degrF) (des F) (deg F) 

### 15.s 65.0 6s.0 

### 15.5 65.0 65_0 15.5 65.0 65.0 15.5 6s-0 65.0 l-5.5 55.0 6s.0 RESULTS * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * -_- DRY GAS METER --- ORIFICE -- DRY GÀS METER _- ORTFICE VOLUME VOIT'ME CORRECTED :ORRECTED Vn(std) Vm(std) (cu ft) (liters) 4.919 141.0 6.083 a72 -3 7-040 I99 _4 8.680 24s -8 8.075 228.7 VOLUME VOIJUME VOI,UME CORRECTED CORRECTED NOMINÀL Vcr(std) Vcr(std) Vcr (cuft) (liters) (cufr) 4.892 l_38.5 4.884 5.930 167-9 5 .920 6_876 194.7 6.86s 8.464 239.7 8.450 7.903 223.8 7.890 CA]JIBRATION FÀCTOR Y Value Variatíon (nunber) (nunber) 0.982 0.00s 0-975 -0.003 0.977 -0.001- 0.97s -0.002 0.979 0.001 0.9"ì8 Average Y -------> CA.LIBRÀTION FACTOR dHG Value Value Variation (in I{2O) (m H2o) (in H2o) r_.655 42.03 -0 -043 1.7s6 44.61 0-058 L-727 43.86 0 -029 1.648 41 -85 -0.0s1 1.705 43.32 0-00? 1.598 43-L3 Note: For calibration Factor Y, the ratio of the reading of Ehecalibration meter to the dry gas meter, acceptable tolerance of individuar, varues from the average is +-0-02. For orifice calibration Factor dll@, the orífice differential pressure in inches of H2othat equatesto o-25 cfm of air at 68 F and 29-92 índnes of/'3la â..êntãLììÁ È^rôr>ñ^- ^r ì-¡i,-l acc,eptab,é tolerance of indiwidual values from the average is +_g-2-

3t12t2009 

## Dare: 3-12^olAPEX INSTRUMENTS EPA Method 5 522 Series Meter BoxCaLibration Pre-Test orifíce Method English Meter Box Units, Englj.sh K, Factor Fil-ename: S:\STÄM Group\STAM Group Info\Calibrations\Meter l\t05-11-09 FuLL calíbration.xlsl522ORPR5 Model #: SeriaL #:
tttttttft IMPORTANT IMPORTANT ttttttttt EnvirorunenC.al Supply Dâte: ------ Barometric Pressure: Theoretical Critícal Vacuum: ---> 6/rr/09 29-10 

### (in. ttg) 13

### .73 (

### in. Hs) For valid test results, the Actual Vacum should be 1 to 2 in. Hg greaLer than the Theorecicaf criticaf Vacuw shown above. TheCritical Orifice Coefficient, K', musr be entered in Engtish uníts, (ft)^3*(deS R)^0-5/((in-Hg¡*(nin)).

--- DRY GAS METER REAÐINGS -CRITICÀI ORTFICE READTNGSdH Time (ín H2O) (min) 0.56 10.00 1.10 10.00 1.75 5 -00 3.30 6.00 5.20 5-00 VoIume

Initial (cu ft) 128-100 1_32 .628 I38.737 I42 .650 1,49 .L7 5 Volume

Final (cu fE) L32.62A L38 -737 r42 -650 L49 _1,75 155.936 0.456 0 .587 0-813 L.OL2 63 .0 63 .0 63-0 63 .0 63_0 volume IniEial Temps- Final Temps- Total lnlet Outl-et Inlet Outlet (cuft) (deg F) (deg F) (des F) (desr F) 4-528 65.0 63-0 66.0 63-0 6 -r.09 66.0 63.0 67.0 66

_0 3.913 67_0 66-0 69-0 66-0 6-525 69.0 66-0 70-0 64-0 6.761 70.0 64-0 71.0 62-0 Orifice K' Orifice Serial* Coefficient (nunber) (see above) cM48 0.342 cM55 cM63 cM73 cM81 Àctua1 -- Am.bj-entTemperature
-- Vacum Initial Final Àverage (in Hg) (deg F) (deg F) (degr F) 1s.5 63_0 63.0 1s.5 63.0 63.0 r-5-5 53_0 63.0 15.5 63-0 63.0 15-5 63.0 63-0

VOLIIME VOLUME CORRECTED :ORRECTED vm(std) vm(std) (cuft) (Iiters) 4-440 I25 -7 s -984 769 .5 3.828 108-4 6_406 181.4 6.675 t-89

_0 VOLUME VOLUME VOLUME CORRECTEÐ CORRECTED NOMINAL Vcr(std) Vcr(std) vcr (cuft) (liters) (cu ft) 4-349 1,23.2 4.43L 5 -800 1,64-3 5 -909 3.736 105-8 3.806 6.209 175.8 6.326 6_44I t82_4 6.s63 CA],IBRÀTION FACTOR Y Value Variation (nunber) (nunber) 0 -980 0.008 0-969 -0-003 0-976 0-004 0.969 -0 -003 0.965 -0

_00? 0.972 AverageY -------> CÄ].IBRATION FACTOR dHe Value Value Variation (in H2o) (mn H2O)(in H2o) 1.635 41.53 -0 -082 1.801 45.74 0.084 L.72I 43.72 0-005 1-696 43.0'7 -0-021 L-73A 43.96 0 -014 1-71,7 43.61 <------- Average dH@ Note: For calibràÈion FacEor Y, the raLio of the read.ing of the calibration meter Èo the dry gas meter, accepÈable tolerance of individual values from the average is +-0.02. For Orifice Calibrat.ion Faclor dHG, thg2orífíce differential pressure in inches of H20 that equaÈes Eo 0-25 cfm of air at 58 F and29-92 inchesglf ng, accepffible tolerance of individual values from the average is +-0.2. 

## srcNED: 

# Ø/t r h.u{ -.^... [o-ti-ay

6t11t2009

### 9.2.I.L Eefore beginnìng the fiefd test (a set of

three rurrs usually cons[iüutes a f 

### ield test) , operate t]re 

### metering systenl (r. e-

### / ptrnrp, 

### wolume 

### meter', and orif ice) al

### tlre 'H.., 

### pressure clifferenLial f:or I0 minutes. Recor:d 

### the vo.l-rlme 

### collected, the DGM

### temperature, and the ba.romeLriq 

### pre.ssì.-rre. CalcuÌate a DGM

### cal-íbration check value, Y", as 

### foll-ows : 10 

### .V Id 

### 0.0319 Ttì

Dbar 

## l where: 

### Y" = DGM

### cal-ibrat-ion check val-ue, di-merrsionless. 

### 10 = Rr¡.n

### time, mín. 

### 9.2.L.2 Compare 

### the Y.-

### val-rre 

### with Ehe 

### dry gas meter calj-brat j-on factor Y to determine that: 0.97Y < Y" < 1.03Y 

### ff tl:e Y. valure is not wiLhin Lhis ral:l"ge, t-he vo-Lurne 

### met,ering system sLiould be irivesl-igated before beginni.ng t-he 

### test

. Time = 

## o( Vm{c,") = u

### ç Vmlpost) = 

### ' Têmp1o,"¡ = Temp1oo.1¡ = D-lbar

## Aþ\= l, {o18 

# /= o.,9'3å 

# o 1T

## (o.r7q):

l-o3(o.q'1Ê)= c),1."18'l



## l,aùI 3 

# ,03 1g 

# Tm 

# Y,= r 0,1502

T.*,1

# 8t,,,"",^*

## Ënergy"

Nozzle

### Verification



# Date: {r" Z-fSq Verified by: ft'Y1



### Where: 1,2, 3,

### = Nozzle 

### diameter measured on a

### different diameter (in) 

### Tolerance = measure 

### within 0.001 in. ÀD

# = Maximum 

### difference in any

### two measurements (in)



### Tolerance = 

### 0.004 in. D avs

# = Average 

### of Dr, Dz, Ds. 

### Nozzle 

### ldentification # D1 

### (in) Dz

### (in) Dg

### (in) 

### ^D (in) Davg 

# 5 Tvpe 

# o"/77 O"

# lzz 0,

# /7å O. ao 

## I 62

# i77

### Dimensions

3116"

### < Dqn,e)

### <3/8" 

## Pn=Pe o*/-0.01 1.05 Dt <P(n,s) 

### <1.50 Dt



## Z< 0.32 cm

# (1/8") 

# @ No 

### S-Type 

### Pitot Tube 

### Verification Checklist Pass 

### (Yes/No)



### W <

### 0.08 cm 

### (1132") 

# @ No 

### Pitot ldentification 

# #: 01 Pitot

### Tube Correction Factor: Date Verified: 

### Verified bv:

## Ø-'z) L'Uat, -lr" I 

# st (n'z¿ 

## sq"ìh ¿

## -Yl 

# oÐ (uzz) 

## 5'qth 

## o'l 

# a3 8Eå-s'*rþh "'8.|.8-a

## h"ìB 

# zqhT"zBþl 

# o"Ç-oo 

# stif Çq uu (zzrÐ

## 5'bl,

# -Crú¿A6 S ?û t_

## S:,l,hl{'ål,t Bobþ- I

## 'obh 

# (z'er-'(t 

# 'flo"o 

# w 8=t

## ll-"ltzv¡ tQoZ'çQ 

## --*'5; 

# Çn

# - "-,\wfll* '.ON Gsn) UhLI b"c> 

### *çÐ-''f



## l;Lt-,-açLh

## -E'hBh 

# 1-çbüz'5bb 

# aL Q.Q*O C)



## õ

Fb'b"

## fo'or 

## -Ez'o¡ þzst"

# 87'øt 

# \e'o-\oo-ç"ç 

# rcî sgB 

# èe 

# -¡E

L9E, 

## (rr 

# i-ltr \he o ã[ f.e"B

Èro 

## æ 

# d'ò

j-'"f'Ll 

# \,o 

# ca$i 8s

# ") ìÉ S L.\ 

### o'Ð 

## -LLZt

# C\, U 

### -7bb c>o'o 

## õ 7Ub aa r) 

# "O

-s

## h'o- bg 

### 'e¡ 

### -

# I 'd

-æ

I b-

## tc' ÇroO-

### System 

### Data by Run and Sample

ReportDate 61312009 Source Identification DTE BioGas Test Persoffiel UnitName 

## Run 1 Number 

### 6

### 3 2OO9 Level H 

## Date Hour 

### Minute FF 02% Status Mins COz% Status Mins SO2 ppm Statûs Mins NOx ppm Status Mins CO ppm Status Mins 

### 613/2009 

## B 5 9780 

### 8.038 

## I I 

### 11.117 

## 1 t 

## 4.t49 1 I 

### 69.015 

## 1 1 

### 588.596 

## 1 1 

### 6/312009 

## E 6 9780 

### 8.012 

## 1 I 

### 11.140 

## 1 I 

## 4.t39 I I 

### 68.119 

## 1 r 

### 585.358 

## 1 1 

### 6/3/2009 

## I 7 9780 

### 8.021 

## 1 I 

### 11.128 

## I I 4.238 

### I 1 

### 69.433 

## I I 

### 591,.942 

## I 1 

### 613/2009 

## I 8 9780 

### 8.017 

## I I 

### 11.134 

## I 1 

## 4.289 

## 1 I 

### 68.289 

## 1 r 

### 585.035 

## 1 I 

### 6/312009 

## 8 9 9780 

### 8.014 

## I I 

### 11.13s

## I I 

# 4.4t0

# tr 1 

### 69.943 

## 1 l 591.633 

## I I 

### 613/2009 

## 8 10 9780 

### 8.044 

## I I 

## LI.I2t I I 

## 4.431 I I 

### 69.952 

## 1 I 

### 586.711 

## 1 I 

### 6/3t2009 

## 8 11 9780 

### 8.015 

## I 1 

### 11.148 

## 1 I 

## 4.506 I 1 

### 72.263 

## 1 I 

### 586.933 

## 1 I 

### 6/3/2009 

## 8 12 9780 

### 8.026 

## I 1 

### 11.135 

## I 1 

## 4.295 I 1 

### 70.198 

## 1 I 584.560 

## 1 I 

## 8 13 9780 

### 8.021 

## I I 

### 17.134 

## 1 I 

## 4.338 I I 

### 71.863 

## I I 586.'.139 

## 1 I 

### 6t3t2009 

## 8 14 9780 

### 8.043 

## I 1 

## 1.118 

## I I 

## 4.438 I I 

## 7r.t23 

## I I 

### 586.409 

## I I 

### 6/3/2009 

## 8 15 9780 

### 8.035 

## I I 

## II.t22 I 1 

## 4.530 

## I I 

### 65.127 

## 1 1 

### s82.299 

## l 1 

### 61312009

## I 16 9780 

### 8.045 

## I I 

## Il.I24 I 1 

## 4.648 I I 

### 72.882 

## 1 I 58',1.298 

## r 1 

### 613/2009 

## 8 17 9780 

### 8.026 

## I I 

### 11.136 

## I 1 

## 4.643 1 I 

### 61.100 

## I 1 

### 584.962 

## 1 I 

## 8 18 9780 

### 8,025 

## I I 

## ll.t42 I I 

## 4.815 i 1 

### 68.886 

## I I 

### 585.239 

## l I 

### 6/3/2009 

## 8 19 9780 

### 7.995 

## I I 

## t.ts''t I 1 

## 4.828 I I 

### 71.424 

## I 1 

### 587.288 

## 1 1 

### 6/3/2009 

## I 20 9780 

### 7.998 

## I l 

## II.ts4 1 I 

## 4.807 I I 

### 12.685 

## i 1 

### 588.633 

## r I

B 

## 21 9780 

### 8.036 

## I I 

## I.L25 1 1 

## 4.890 I I 

## 7t.234 

## 1 I 

### 589.781 

## 1 1 

### 6/312009 

## 8 22 9780 

### 7.99',1 

## I I 

### 11.160 

## I 1 

## 4.9s3 

# I r 

### 68.186 

## I 1 

### 583.141 

## 1 I 

### 6/3/2009 

## I 23 9780 

### 8.030 

## I 1 

## Il.t43 1 i 

## 5.030 

## I I 

### 74.056 

## I I 589.974 

## I 1 

### 6/3/2009 

## 8 24 9780 

### 8.038 

## 1 I 

## II.r32 1 I 

## 5.12A I 1 

### 65.014 

## I I 

### 583.436 

## 1 I 6/312009 

## 8 25 9780 

### 8.002 

## l I 

### 11.170 

## I r 

## 5374 I 1 

### 73.006 

## I I s86.326 

## 1 I 

## 8 26 9780 

### 7.9',t8 

## I I 

### 11.189 

## 1 I 

## 5.180 I 1 

### 69.538 

## 1 I 594.877 

## I r 

### 61312009

## I 27 9780 

### 8.001 

## r I 

## II.t73 1 I 

## 4.946 1 1 

## 7r.948 

## 1 1 

### 592.102 

## 1 l 613/2009 

## 8 28 9780 

## 7.99r 

## I I 

### 11.178 

## 1 I 

## 4.815

## tr 1 

## 6716s 

## 1 I 

### 588.653 

## 1 I 

### 6t3t2009

## 8 29 9780 

### 8.036 

## 1 I 

## I.132 1 1 

## 4.698 

## 1 r 

### 68.916 

## 1 I 

### s85.813

## I I 61312009

## 8 30 9780 

### 8.004 

## I 1 

### 11.156 

## 1 1 

## 4.6s5 

## 1 I 

### 69.882 

## 1 1 

### 583.286 

## 1 l 613t2009

## 8 31 9780 

### 8.025 

## I 1 

### 11.145 

## I 1 

## 4.6s9 

## 1 1 

### 69.309 

## 1 I 

### 581,984 

## 1 1 

### 6/3/2009 

## I 32 9780 

### 8.035 

## I 1 

## lt.r42 I 1 

## 4355 I I 

### 67.845 

## I r 

### 582.505 

## I 1 

### 61312009

## 8 33 9180 

### 8.041 

## 1 I 

## 11.t32 

## I 1 

## 4.763 1 1 

### 64.851 

## 1 1 

### 581.s11 

## 1 I 

## I 34 9780 

### 7.987 I I 

### 11.180 

## I 1 

## 4.E90 I 1 

## 7t.269 

## I I 

### s8L274 

## 1 1 

### 613/2009 

## 8 35 9780 

### 7.992 

## 1 1 

## LI.T7I 1 1 

## 5.041 

## 1 I 

### 68.963 

## 1 l 588.183 

## 1 1 

### 6/3/2009 

## 8 36 9780 

### 8.002 

## r I 

## 11.t74 

## l I 

## 5.259 1 1 

### 71.867 

## 1 I 

## .0s2 

## 1 I 

### 6/3/2009 

## 8 37 9780 

### 8.011 

## i I 

## Il.t64 I I 

## 5.419 I I 

## 1r.399 

## 1 1 

### 585.140 

## 1 I 

### 6/3/2009 

## 8 38 9780 

### '1.992 

## I 1 

## Ir.r79 I I 

## s.374 

## 1 1 

### 69.511 

## 1 I 1 1 588 Certdas System Developed byCartwright &Associates Little Rock, AR. Ph (501) 791-3655

### System 

### Data by 

### Run and Sample

Report

## Date 61312009 Source Identification DTE BioGas UnitName 

## Run 1 J

H Test Nurnber 

### 6 3 2009 Level 

## Date Hour 

### Minute FF 02% Status Mins CO2% Status Mins SO2 pom Stattrs Mins NOx ppm Status Mins COppm Status Mins 

### 61312009 

## B 39 9780 

### 8.002 

## I I 

### 11.170 

## 1 I 

## 5.107 

## 1 1 

### 73.097 

## 1 I 

### 590.142 

## 1 I 

## I 40 

### 8.003 

## I I 

### 11,159 

## 1 I 

## 4.898 I 1 

### 68.259 

## 1 I 588.475 

## I 1 

### ot'tzutJ9 E 4l g7g0 

### 8.017 

## I I 

### 11.149 

## 1 I 

## 4.766 I 1 

## 73.st4 

## I I 

### 590.819 

## I I 

### 6/3/2009 

## B 42 e780 

### 8.048 

## I I 

### 11.118 

## I I 

## 4.189 I I 

### 67.355 

## I I 

### 588.070 

## 1 1 

## I 43 9780 

### 8.017 

## I I 

### 11.139 

## 1 1 

## 4.856 1 I 

### 66.290 

## 1 I 

### 580.268 

## 1 1 

### 6t'3t2UU9 

## 8 44 9780 

### 8.043 

## I 1 

## LI,I22 1 1 

## s.083 

## 1 1 

### 69.037 

## I 1 

### 5',79.532

## 1 I 

### 613/2009 

## 8 45 9780 

### 8.016 

## I I 

### 11,145 

## 1 1 

## 5.140 I I 

### 70.782 

## 1 1 

### s'71.783 

## I I 

### 61312009 

## 8 46 9780 

### 8.009 

## I 1 

### 11.153 

## I I 

### 5.30'.'t 

## 1 I 

### 67.307 

## I I 

### 580.675 

## I I 

### bt'stzutJ9 

## 8 47 g7g0 

### 8.019 

## 1 1 

## It.L49 

## 1 I 

## s.302 

# I 1 

### 72.265 

## I I 

### 583,613 

## I 1 

### 61312009 

## 8 48 9780 

### 8.055 

## 1 I 

### 11,113 

## I I 

## 5.4s3 

## I 1 

### 66.694 

## 1 I 

## 57'Ì.54t 

## I I 

### 6t3t2009 I 49 9780 

### 8.0tr3 

## I I 

### 11.1s4 

## 1 I 

## s.462 

## I 1 

### 70.470 

## 1 I 

### 577.636 

## 1 I 61312009 

## 8 s0 9780 

### 8.02^r 

## I 1 

### 11.138 

## I 1 

## s.37L 

## 1 I 

### 70.714 

## I I 579.371 

## 1 I 

### 6/3/20Ue 

## I 5t 9780 

### 8.038 

## I 1 

### 11.134 

## I I 

## 5.2s9 

## 1 1 

### 65.219 

## 1 1 

### s'76.240 

## 1 I 

### 6/3/2009 

## I 52 9780 

### 8.013 

## I I 

### 11.156 

## 1 I 

## 5.282 1 I 

### 68.077 

## 1 I 

### s76.697 

## 1 I 

### 6/3/2009 

## 8 53 9780 

### 7.980 

## I I 

### 11.188 

## I 1 

## 5.369 I I 

### 68.261 

## 1 I 

### 583,051 

## 1 1 61312009 

## I 54 9780 

### 7.994 

## I I 

## rl.I74 l I 

## s.442 

## 1 I 

### 72.092 

## 1 I 

### 581.1s9 

## 1 l 6/3/2009 

## 8 55 9780 

### 7.985

## t I 

### 11.181 

## 1 I 

## s.309 

## I I '73.466 

## I I 

### 578.248 

## 1 1 

## 8 56 9?80 

## 7.99r 

## I I 

# n,rÌs I I 

# s.t7r I I 

### 69.010 

## 1 I 

### s84.487 

## I 1 

### 6tJtzUU9 

### U 57 9780 

### 7.992 

## 1 I 

## Lt.I76 I I 

## 5.255 I I 

## 67.14\ 

## 1 1 

### 582.529 

## 1 I 

### 61312009 

## 8 58 9780 

### 8.011 

## I I 

### 11.159 

## I 1 

## s.171 

## 1 I 

### 69.668 

## 1 I 582.23'.7 

## I I 

### 6/3/2009 

## 8 59 9780 

### 8.009 

## I r 

### 11.1s9 

## I 1 

## s.118 

## I I 

### 70.409 

## I I 

### s83.114

## 1 I 

### 613/2009 

## 9 0 9780 

### 8.004 

## I I 

### 11.1s9 

## I I 

## 5.102 I I 

### 70.056 

## 1 I 

### 583.385 

## 1 I 

### 613/2009 

## 9 I 9780 

### 8.021 

## I I 

### 11.148 

## I 1 

## s.080 

## I I 

### 68.178 

## 1 I 

### s83.246 

## 1 1 

### 61312009 

## 9 2 97BO 

## ''t.99I 

## I 1 

### LT,T72 

## 1 I 

## 5.138 1 I 

### 69.979 

## 1 I 

### s85.081

## I r 

### 61312009 

## 9 3 9780 

### 8.001 

## I 1 

## Ir.162 

## 1 I 

## s.I34 1 I 

## 67.86t 

## I I 

### s84.962 

## 1 I 

### 613t2009 

## 9 4 9780 

### 8.012 

## I I 

### 11.155 

## 1 l 

## 5.202 1 I 

### 72.730 

## 1 I 

### 582.294 

## 1 1 

## 8.0i5 60 

## 11.1s0 60 

## 4.932 60 

## 69.s90 60 

## 584.692 60

Certdas System Developed by Cartí,tight &Associqtes Little Rock, AR, Ph (50j) 79I-3655

### Post-test System 

### Calibration

Source 

### Identification DTE BioGas Test Personnel mqlfu1fu Number 6 J 2009 

### UnitName Eng_3 

### RunNumber I End Time&

## Date 6/3/2009 9: M.00 Analyzer Span Value System

Reference Value System

Calibration Resnonse System

Error f%oofsuan) System

Error Limit l% ofsoanl System

Calibration Status Zero Gas O2Yo 18.370 0.000 0.000 0.000 5.000 PASS Mid Gas 02% 18.370 10.050 9.924 0.686 5.000 PASS Zero GasCO2% 18.280 0.000 0.042 0.230 5.000 PASS MidGas COz% 18.280 10.230 9-997 1.275 5.000 PASS Zero Gas SO2 19.500 0.000 0.659 3.379 5.000 PASS Uoscale Mid Gas SO2 19.500 9.220 8.410 4.754 s.000 PASS Zero GasNOx 490.100 0.000 0.854 0.174 5.000 PASS U rscale Mid Gas NOx ppm 490.100 179.900 174.682 1.065 5.000 PASS ZeroGasCO 995.200 0.000 0.976 0.098 5.000 PASS Mid Gas CO 99s.200 484.300 470.458 1.391 5.000 PASS

Certdøs Systent Developed byCartwright &.Associates Little Roch AR. Ph (501) 791-3655

### System 

### Data by Run and Sanrple

ReportDate 61312009 Source Identification DTE BioGas Test Personnel Number 

### 6 3 2009 UnitName 

## Run 2 _3

H ineLwel 

## Date Hour 

### Minute FF O2%o Stattrs Mins COz% Status Mins SO2oom Status Mins NOx opm Státus Mins CO ppm Status Mins 

### 61312009

## 9 s2 9780 

### 8.003 

## I I 

### 11.181 

## I I 

## 5.381 I 1 

### 69.s40 

## 1 I 581.373 

## 1 1 

### 6/312009 

## 9 53 9780 

### 8.010 

## I I 

## tt.I74 I 1 

## s,254 

## tL I 

### 70.374 

## 1 1 

### 583.473 

## 1 r 

### 6t3t2t¿09 

### 9 54 g7g0 

### 8.021 

## I I 

### 11,163 

## I 1 

## s.244 

# I 1 

### 70.748 

## I I 

### 578.309 

## I I 

## 6t3t2tJï9

## 9 55 9780 

### 8.015 

## I I 

### 11.160 

## I I 

## 5,370 

## I I 

### 69.070 

## 1 I 

### 581.969 

## 1 1 

### 613/2009 

## 9 s6 9780 

### 8.028 

## I 1 

### 11,1s0

## I i 

## s.399 

## I 1 

## 7r.316 

## 1 1 

### 585.388 

## 1 I 

## btJtzuuv 

## 9 57 9780 

### 8.016 

## I 1 

## II.t57 1 1 

## s.372 

## I I 

### 68.579 

## I I 578,159 

## 1 1 

### 6/312009 

## 9 s8 9780 8.042 I 

# ll.t4r r 1 

## 5.265 1 I 

## 7t.329 

## 1 I 

### s82.296 

## 1 1 

## 9 59 9780 

### 8.005 

## I I 

## Il,t77 l I 

## 5.469 I I 

## 7I.487 

## 1 1 

### 582.494 

## 1 1 

### 61312009

## l0 0 9780 

## 8.0i4 I I 

## ll.t76 I I 

## 5.486 I 1 

### 68.871 

## 1 I 

### 584.1s9 

## 1 I 

### 6t3t20tJ9 

### l0 I g7g0 

### 8.009 

## I r 

### 11.188 

## I I 

### 5.41',1 

## I 1 

### 71..460 

## 1 I 

### 583,390 

## 1 1 

### 6/312009

## 10 2 9780 

### 8.020 

## I I 

### 11.163 

## 1 1 

## 5.399 

## I r 

### 68.035 

## 1 1 

## .s78 

## 1 I

t0 3 9780 

### 8.034 

## I t 

### 11.150 

## I 1 

## 5.382 

## I I 

### 66,156 

## I I 

## .130 

## 1 I 

### 613t2009 

## 10 4 97S0 

### 8.044 

## I 1 

### 11.133 I 

## 5.300 

## I r 

### 69.299 

## I 1 

### 573.s38 

## 1 I 

### 6t3t2009 

## l0 5 9780 

### 8.024 

## I I 

### 11.145 

## I I 

## s.181 

## I I 

### 68.527 

## I I 

### 573,42s

## I l 6t3/2009 10 6 9780 

### 8.035 

## I I 

### 11.139 

## I 1 

## 4.9s2 

# I r 

### 69.967 

## I I 574.680 

## 1 1 

### 6t3t2009 

## l0 7 9780 

### 8.019 

## I 1 

### 11.148 

## I I 

## s.065 

## I I 

### 71.320 

## 1 I 

### s74.18s 

# 1 I 

### 613/2009 

## 10 I 9780 

### 8.036 

## I 1 

## Il.r32 1 1 

## 5.121 1 1 

### 70.254 

## 1 1 

### 5B1.192 

## 1 I 

### 613/2009 

## 10 9 9780 

### 8.047 

## I 1 

### 11'127 

## I I 

## 5.116 

## I l 74.886 

## 1 1 

### 579.t8'.7 

## I I 613/2009

## t0 l0 9780 

### 8.060 

## I I 

## .r20 1 1 

## 5.088 

## 1 I 

### 66.747 

## 1 I 574.0T1 

## 1 1 

## 10 ü 9780 

### 8.037 

## 1 I 

## Il.r43 I 1 

## 5.085 

## I r 

## 70.53I 

## I I 

## s72392 

## 1 1 

### 6/312009

## 10 t2 9780 

### 8.026 

## I I 

### 11.1s3

## I 1 

## 5.t44 I r 

### 65.518 

## I 1 

## .319 1 1 

### 6/3/2009 

## 10 13 9780 

### 8.029 

## 1 I 

## Il.ts7 1 1 

## 5.199 I l 68,316 

## 1 I 

### 574.695 

## 1 r 

### 6/3/2009 

## 10 14 9780 

### 8.029 

## I l 

## ,156 I I 

## 5.323 I I 

### 68.506 

## I 1 

### s71ß38 

## 1 I 

### 613/2009 

## 10 15 9780 

### 7.998 

## I I 

## II.t'72 

## r r 

## 5.473 1 1 

### 69.304 

## l 1 

### 5',75.905

## 1 I 

### 6/312009 

## 10 16 9780 

## 7.98r 

## I I 

### 11.196 

## I i 

## 5.440 1 1 

### 75.651 

## I I 

### 584.901 

## 1 I 

### 6/3/2009 

## 10 11 9780 

### 8.023 

## I l 

## i1.160 

## 1 I 

## 5.389 I I 

### 73.340 

## 1 1 

### 586.875 

## I 1 

### 6/312009 

## 10 18 

### 8.029 

## I 1 

## ll.t4e I 1 

## s.369 

# I r 

### 68.611 

## I 1 

### 578.016 

## I 1 

## l0 19 9780 

### 8.011 

## I l 11.165 

## I I 

## 5.415 1 I 

### 67.680 

## I I 

### 576.591 

## 1 I 61312009

## l0 20 9780 

### 8.005 

## I I 

## 1.t63 l I 

## 5.489 I l 69.450 

## I I 

### 578.s44 

## 1 l 

### 6/3t2009 

## 10 21 9780 

### 8.009 

## I l 11,157 

## 1 I 

## 5.484 1 I 

### 69.537 

## I I 

### 585.282 

## I I 

### 6t3t2009 

## 10 22 9780 

### 8.032 

## 1 l 

# .r32 

# 1 1 

## s.363 

# 1 r 

### 66.964 

## I 1 

### s7s.276 

## I 1 

### 6/3/2009 

## 10 23 9780 

### 8.010 

## I I 

### 11.145 

## 1 I 

### 5.4','Ì9 

## 1 I 

### 73."741 

## 1 1 

### 57'7.047 

## I 1 

### 6/3/2009 

## 10 24 9780 

### 8.016 

## I I 

## tt.t42 I I 

## 5.483 1 l 69.926 

### I I 

### 584.524 

## 1 l 613/2009 

## 10 2s 9780 

### 8.028 

## I I 

### 11.136 

## I r 

## 5.546 I I 

### 72.227 

## I 1 

### s77.83r 

## 1 1 Certdas SystemDeveloped by Cartwright &Associates Little Rocþ, AR. Ph (S0I) 79j-365s

### System 

### Data by 

### Run and Sample

ReportDate 6/312009 Source Identífication DTE BioGas UnitName 

## Run 2 J

H Test Personnel 

### 63 2009 ine Level 

## Date llour Mintrte FF 02% Staürs Mns CO2% Status Mins SO2ppm Status Mins NOxppm Status Mins CO ppm Status Mins 

### otst¿uuv 

## ru ¿6 y7ü0 

### 8.008 

## I I 

## II.I57 I I 5.624 I I 

### 68.679 

## 1 I 

### 580.317 

## I 1 

### 6t3t2UV9 

### l0 21 g7E0 

### 8.021 

## 1 I 

### 11.154 

## I 1 

## s.734 

## I I 

### 69.15't 

## I I 

### 583.s48 

## 1 I 

### 6/3/2009 

## 10 28 9780 

### 8.010 

## 1 1 

### 11.159 

## 1 I 

## s,667 

## 1 I 

### 70.082 

## I I 

## 1.106 

## I I 

### 6/3/2009 

## 10 29 9780 

### 8.032 

## I 1 

### 11.138 

## I I 

## s.591 

## I I 

### 72.214 

## 1 l s82.220 

## 1 1 

### 6t'3t2uue 

## l0 30 9780 

### 8.023 

## I 1 

### 11..143 

## I 1 

## 5.575 1 I 

### 67.373 

## 1 1 

### 577.40s 

## 1 I 6t

### 3tzu1J9 

### l0 31 9780 

### 8.019 

## 1 l 11.156 

## I I 

## s,526 

## 1 I 

### 72.688 

## 1 I 

### 578.510 

## 1 I 

### 613/2009 

## 10 32 9780 8.007 1 

### 11.165 

## r I 

## 5.566 1 I 

### 70.229 

## 1 I 

### s80.313

## I 1 

### 6t'JI2UtJ9 

### l0 33 9790 

### 8.012 

## I I 

### 11.168 

## 1 I 

## 5.512 

## 1 I 

### 69.128 

## 1 1 

### 578.311 

## 1 I 

### 6t3t2009 

## 10 34 9780 

### 8.020 

## I I 

# tI,lse I 1 5.469 I I 

### 69.006 

## I I 

### 580.63r 

## I I 

### 6t3t200e 

## l0 3J 9780 

### 8.018 

## I 1 

### 11.159 

## I 1 

## 5.449 I I 

### 66.090 

## I 1 

### 576.752 

## 1 1 

## 10 36 9780 

### 8.018 

## I 1 

### 11.762 

## I I 5.490 I I 

### 68.987 

## 1 1 

### 577.044 

## 1 I 

### 6t3/2009 

## 10 31 9780 

### 8.042 

## 1 I 

## Il.t32 1 1 

## 5,492 1 I 

### 65.413 

## 1 1 

### 573.t71 

## I 1 

### 6t3t2009 

## l0 3E 9780 

### 8.024 

## 1 I 

# It.tsz 1 1 

## 5.500 

## I I 

### 70.425 

## 1 1 

### 574.453 

## 1 I 

### 613/2009 

## 10 39 9780 

### 8.001 

## I 1 

### 11.171 

## I 1 

## 5.550 I I 

### 69.249 

## 1 1 

### 575.432 

## 1 I t7 

## r0 40 9780 

### 7.968 

## I I 11.193 

## I 1 5.695 

### I I 

### 70.239 

## I 1 

### 581.605 

## 1 I 

### 6/3/2009 

## 10 4t 9780 

### 1.999 

## 1 1 

## ll.I73 I I 

## 5.628 1 1 

### 72.429 

## I 1 

### 584.296 

## 1 1 

### 6t3t200e 

## l0 41 9780 

### 8.038 

## 1 r 

### 11.138 

## I 1 

## s.608 

## I 1 

### 67,550 

## I 1 

### 577.686 

## I I 

### 6t3t20ue 

## l0 43 9780 

### 8.001 

## 1 1 

### 11.180 

## 1 I 5.608 1 1 

### 70.100 

## 1 I 5'.73.059

## I I 

### 6/3t2009 

## 10 44 9780 

### 8.024 

## I I 

### 11.159 

## 1 I 

## s.s92 

# I r 

### 69.094 

## 1 1 

### s7'l.594 

## 1 I 6t3t2tJv9 

## 10 45 9780 

### 8.003 

## I I 

## II.L75 1 1 

## 5.593 

## 1 I 

### 67.626 

## 1 I 579.510 

## 1 I 

## 10 46 9780 

### 8.021 

## I I 

### 11.148 

## I I 

## 5.638 

## I I 

### 70.273

## I I 

### 577.469 

## I I 

### 6/312009 

## 10 4'',1 9780 

### 8.004 

## 1 I 

## lI.t61 1 I 5.66E I 

### I 

### 69.290 

## I I 575.778 

## 1 r 

### 6/3/2009 

## l0 48 9780 

### 7.983 

## l 1 

## tt,t94 I I 

## s321 1 I 

## 7I.45s 

## I I 582.296 

## I I 

### 6/3/2009 

## 10 49 9780 

### '7.987 

## 1 I 

### 11.191 

## I I 

## s.724 

## 1 1 

### 72.546 

## 1 I 582.998 

## I I 

### 6/3/2009 

## 10 50 9780 

### 8.040 

## 1 l t1.132 

## I 1 

## 5.728 1 1 

### 67.ß95 

## 1 1 

### 579.474 

## 1 I 613/2009 

## 10 st 9780 

### 8.007 1 I 

### 11.1s5 

## 1 I 

## 5.701 1 1 

### 67.800 

## I 1 

### 576.586 

## 1 I 

## 8.018 60 

## 11.157 60 

## 5.443 60 

## 69.705 60 

## 578.976 60

Certdas System Developed by Cartwright & Associates Little Rock, AR. Ph (S0l) 79l-3655

### Post-test System

### Calibration

Source 

### Identification DTE BioGas TestPersonnel mgfu/fb ReoortNumber 

### 63 2009 

### UnitName Eng_3 

### RunNumber 2 EndTime

## &Date 6/3/2009 11:10.00 Analyzer Span Value System

Reference Value System

Calibration ResDonse System

Error (% ofspan) System



### ErorLimit loloof soan) System

Calibration Status Zero Gas O2o/o 18.370 0.000 0.006 0.033 5.000 PASS Upscale Mid Gas 02% r.8.370 10.050 9.918 0.719 s.000 PASS ZeroGasCO2% 18.280 0.000 0.079 0.432 5.000 PASS Upscale Mid Gas CO2o/o 18.280 10.230 9.948 t.543 5.000 PASS Zero Gas SO2 19.500 0.000 0.671 3.441 5.000 PASS leMid Gas SO2 19.500 9.220 8.593 3.2t5 5.000 PASS Zero Gas NOx 490.100 0.000 0.000 0.000 5.000 PASS rscale Mid Gas NOx pom 490.100 179.900 175.I70 0.96s 5.000 PASS Zero GasCO 995.200 0.000 1.220 0.123 5.000 PASS Mid Gas CO 995.200 484.300 468.s05 1.587 5.000 PASS

Certdas Syslem Developed byCartwright & Associøtes Little Rock,AR. Ph (501) 791-3655

### System 

### Data by Run and Sample

ReportDate 61312009 Source Identification Unit Name Test Personnel 

## Run 3 Number 

### 63 2009 J H Level 

## Date Hour 

### Minute FF 02% Status Mins COz% Status Mins SO2 ppm Status Mns NOxupm Status Mins CO ppm Status Mins ot

### Jt¿wy r

### r J¿ g'löu 

### 8.095 

## I 1 

### 11,121 

## 1 1 

## 5.383 

## 1 r 

### 68.373 

## 1 I 

### 579.600 

## 1 I 

### 613/2009 

## 11 33 9780 

### 8.078 

## 1 1 

### 11,097 

## I 1 

## 5.779 

## 1 I 

### 61.996 

## 1 I 

### 570.585 

## I I 

## o[ilTuve 

## ll 34 9780 

### 8.089 

## 1 1 

## 1L079 

## I 1 

## 5.963 I I 

### 69.1s9 

## 1 1 

### 572.299 

## 1 I 

### 6tJt¿uu9 

### lt 35 9780 

### 8.068 

## I 1 

### 11,098 

## I 1 

## 6.2s3 

## I I 

### 6s.529 

## 1 1 

### 568,693 

## 1 I 

### u3t2rJ09 

## 11 36 9780 

### 8.042 

## I 1 

## II,r27 I 1 

## 6.094 

## I I 

### 61.263 

## 1 I 

### 72.045 

## 1 I 

### 6t3tz00e

## lt 37 9780 

### 8.036 

## 1 I 

## IL.t44 1 I 

## 5.976 I I 

### 72.124 

## 1 1 

### 575.616 

## 1 1 

### 6t3tzuu9 

## lt 3E 9790 

### 8.055 

## 1 I 

### 11,138 

## 1 I 

## 5.781 

## 1 1 

## 67.t36 

## 1 I 

## 577.6rt 

## 1 I 613/2009 

## 11 39 9780 

### 8.048 

## 1 I 

## lLt43 I I s.589 1 I 

### 70.941 

## 1 1 

### 575.003 

## 1 I 

## 11 40 9780 

### 8.030

# tr I 

## Lr46 l 1 

## 5.611 I I 

### 68.684 

## 1 I 575.282 

## I I 61312009 

## 11 41 9780 

### 8.028 

## I I 

### 11,1s6

## I 1 

## 5.651 

## 1 1 

### 69.701 

## 1 r 

### 74.409 

## 1 1 

## 11 42 9780 

### 8.051 

## I I 

### 11,13s

## I 1 

## 5325 I r 

### 69.L94 

## 1 I 

### 576.780 

## 1 1 

### 6tJt¿uu9 

### ll 43 9780 

### 8.027 

## I I 

### 11,146 

## I I 

## s.655 

## 1 I 

### 68.798 

## 1 r 

## 76411 

## 11 44 9780 

### 8.041 

## I I 

### 11,140 

## I I 

## 5.634 I I 

### 68.908 

## 1 I 

### 575.511 

## 1 I 

### 6t3t2009 

## 11 45 9780 

### 8.044 

## I I 

### 11.14s 

## 1 1 

## 5.681 

## 1 I 

### 70.284 

## I I 

## 5x2.Ir4

## l 1 

### 61312009 

## 11 46 9780 

### 8.059 

## I I 

## tt,I43 1 I 

## 5.6st 1 1 

### 66.980 

## 1 1 

### 574.183 

## I I 6t3tztJ09 

### tl 47 g7E0 

### 8.058 

## I I 

### 11.14s 

## 1 1 

# s308 

# 1 1 

### 67.792 

## 1 1 

### 570.888 

## 1 1 

### 61312009 

## 11 48 9780 

### 8.073 

## 1 I 

## tLI2s I 1 

## 5.s16 

## 1 I 

### 65.322 

## 1 I 

### 572.460 

## 1 I 613/2009 

## 11 49 9780 

### 8.059 

## 1 I 

# tLr42 

# 1 I 

## 5.s79 

## 1 1 

### 67.050 

## 1 1 

### 566.061 

## 1 I 613/2009 

## 11 50 9780 

### 8.033 

## I I 

### 11.163 

## I 1 

## 5.788 I I 73.8',73 

## 1 1 

### 577.832 

## 1 1 

### 6t3tztJve

## tl 51 9780 

### 8.048 

## I 1 

### 11,138 

## I 1 

## 5.7e0 

## 1 I 

### 72.182 

## 1 1 

### 581.344 

## 1 I 61312009 

## 11 52 9780 

### 8.039 

## 1 I 

## ILt47 I I 

## 5.858 

## 1 I 

## 7I.034 

## 1 I 579,848 

## 1 I 

### 6t3t2009 

## 11 53 9780 

### 8.056 

## I I 

### 11.14s 

## 1 I 

## 5.734 1 1 

### 69.186 

## 1 I 

### 577.835 

## I 1 

### 6/3/2009 

## 11 54 9780 

### 8.037 

## I r 

## lLr67 1 I 

## 5.681 

## 1 I 

### 66.696 

## 1 r 

### 575.146 

## 1 I 613/2009

## ll 55 9780 8.072 I 

### 11.140 

## 1 1 

## 5.748 

## 1 r 

### 68.108 

## 1 I 

### 574.913 

## 1 I 61312009 

## 11 56 9780 

## 8.04s 

## I I 

### 11.157 

## 1 I 

## 5.803 

## 1 r 

### 68.691 

## 1 1 

### 571.627 

## 1 I 613.12009

## 11 s7 9780 

### 8.081 

## 1 I 

## IL.r32 

## I 1 

## 5.737 I I 

### 70.674 

## 1 1 

### 575.t12 

## 1 l 61312009

## tl 58 9780 

### 8.099 

## I I 

### 11,108 

## 1 1 

## 5.667 

## 1 I 

### 68.183 

## 1 I 

## 567j97 I I 

### 6/3/2009 

## 11 59 9780 8.079 I 

### 11.120 

## I 1 

## 5.77I I l 

### 70.748 

## 1 1 

### 566.803 

## 1 1 

### 613/2009 

## 12 0 97E0 

### 8.040 

## I I 

## llt62 t 1 

## 5.787 1 I 

### 66.23L 

## 1 1 

### 573.261 

## 1 I 

### 6/312009

## t2 I 97E0 

### 8.041 

## l 1 

## tLr66 l 1 

## 5.719 I I 

### 74.232 

## 1 I 57'1.2L6 

## 1 1 

### 6/312009

## t2 2 9780 

### 8.043 

## I I 

### 11.153 

## 1 1 

## s.680 

## I 1 

### 68.169 

## 1 r 

### 573.754 

## I I 

### 6/312009

## t2 3 9780 

### 8.057 

## I I 

### 11,13s 

## 1 1 

## 5.682 I I 

### 67.833 

## 1 1 

## s7l.r62 

## 1 I 

### 6/312009 

## L2 4 9780 

## 7.975 

## 1 r 

### 11.200 

## 1 1 

## 5.736 1 I 

### 69.626 

## 1 I 

### 577.425 

## 1 1 

### 6/312009

## t2 5 9780 

### 8.007 

## I 1 i

## 1.171 

## I I 

## 5.747 1 I 

## 1l.o3s 

## 1 1 

### s82.674 

## 1 1 Certdas SystemDevelaped by Cartwright & Associates Little Rock, AR. ph (S0l) 79l-3655

### System 

### Data 

### by Run and Sample

Report 

### Date 6/312009 Source ldentific¿tion DTE BioGas UnitName J H Test Fersonnel Nu¡nber 

### 6 3 2009 

## Run 3 Level 

## Date ,IÌour 

### Minute FF 02% Status Mins COz% Stafts Mins SO2ppm Status Mins NOxppm Status Mins CO pþm Status Mins 

### atstzuuy 

## tz ó g7E0 

### 8.028 

## I I 

### 11.15s 

## I 1 

## 5.7t8 1 1 

## 1t.879 

## 1 r 515

### 691 ',r 1 9780 

### 8.046 

## I I 

### 11,140 

## 1 I 

## 5.596 I I 

### 67.s06 

## 1 1 

### 576.487 

## 1 I 

### otrt4vuy L¿ ü 9'lðu 

### 8.082 

## I 1 

### 11.113 

## 1 I 

## 5.612 

## I I 

### 68.038 

## I t 511

### 017 1 1 

### otst4uvy 

## u I 9780 

### 8.057 

## 1 I 

## Il,t32 1 1 

## 5.663 

## 1 I 

### 69.805 

## 1 I 56q

### 65q 1 

### 6t5t¿utJ9

## LZ t0 

### 8.046 

## 1 I 

## ll.t44 1 I 

## 5.s90 

## I I 

### 68.624 

## 1 I 569

### 656 1 öt Jt

### luvy L'¿ I

### I g7E0 

### 8.000 

## I I 

### 11,182 

## 1 1 

## 5.670 

## I I 

### 74.316 

## I I 514ji4 1 

### ötJt¿uvy 

## Iz t2 g7ßo 

### 8.035 

## I 1 

## Il,t52 I I 

## 5.749 I I 

## 70jt2 I I 5Rû

### 11' 1 

### 6tstz0ue 

## 12 13 9780 

### 8.037 

## 1 r 

## tLr42 1 I 

## 5.809 1 I 

### 67.162 

## 1 I 

### 510141 1 

### öt3t¿uu9 

### l2 14 9780 

### 8.053 

## 1 i 11,128 

## I I 

## 5.783 1 I 

### 67.142 

## 1 I 567Rrl 1

t2 

### I 97E0 

### 8.051 

## 1 r 

## ll,t32 I I 

## s360 I 1 

### 66.922 

## 1 I 

### 56\116 1 

### 6t3t¿uue 

## Iz 16 g7g0 

### 8.043 

## 1 I 

### 11.13s 

## I I 

## 5.824 

## I 1 

### 66.759 

## 1 I 11ã11¿. 1 

### bt3tztJïg 

## 12 I7 9780 

## 8.0t0 

## 1 I 

### 11,112 

## 1 I 

## 5.716 I 1 

## 7t.6tt 1 I 5',72.824 

## I 1 

### otst¿vuy t¿ lü 

### 8.065 

## I 1 

### 11.114 

## I I 

## 5.705 

## I 1 

### 65.225 

## 1 I 564. 1 1 

### ötst¿uu9 

### I2 l9 97AO 

### 8.067 

## I I 

### 11.119 

## l I 

## 5.832 

## I I 

### 66.669 

## 1 1 

### 565.640 

## 1 1 9780 

### 8.027 

## 1 1 

### 11,155 

## I t 

## 6.013 I 1 

### 67.018 

## 1 I 466

### 9t) 1 r 

### 6t3t2009

## t2 2L 9780 

### 8.022 

## I 1 

### 11,160 

## 1 1 

# s.e3l I 1 

### 67.366 

## 1 I 

### 514891 1 

### bt3tzuue

## t2 22 g7g0 

### 8.031 

## 1 I 

### 11,156 

## I I 

## 5.859 

## I I 

### 68.351 

## 1 1 

### 57'.7.499

## 1 I 

### otJlzuue 

## L2 23 g7g0 

### 8,02e 

# 1 I 

### 11,1s9 

## 1 I 

## 5.e24 

## I 1 

### 68.901 

## 1 I 

### 575.676 

## 1 1 

## þt't¿uu9 

## l2 z4 gTEo 

### 8.045 

## 1 I 

### 11,148 

## I I 

## s.92',r 

# I I 

### 66.920 

## 1 I 

### 57I.684 

## 1 I 

### otst¿uuyt'¿ 25 9780 

### 8.019 

## 1 I 

### 11'162 

## 1 1 

## 5.969 I I 

### 6'.7.671 

## 1 I 

### 570.189 

### I 1 

### otJr¿uue 

## L2 26 g7g0 

### 8.040 

## 1 1 

### 11,143 

## I t 

## 5.636 

## 1 I 

### 69.406 

## 1 I 

### 574.sI2 

## I 1 

### 6t3t'¿uu9

## tz 27 g7g0 

### 8.059 

## 1 I 

## Il,t25 I I 

## 5.604 

## 1 1 

### 64.259 

## 1 I 

### 569.B60 

## 1 I 

### otst¿uu9 

## L2 '28 9780 

### 8.027 

## I 1 

### 11.155 

## I I 

## 6.009 

## 1 1 

### 71.328 

## 1 I 

### 572.t92 

## 1 I 

### 6t3/2009 

## t2 29 9780 

### 8.053 

## 1 1 

### 11,130 

## I 1 

## 5.99L I 1 

## 6s.21r

# 1 I 

### 574.915 

## I I 

### otstzuuv 

## L2 30 9780 

### 8.032

## tr 1 

### 11.154 

## I I 

## 5.995 1 I 

### 70.204 

## 1 I 

### 566.530 

## 1 1 

### 6t3t20u9 

### L2 31 9780 

### 8.022 

## 1 I 

### 11,164 

## 1 I 

## 5.854 1 1 

### 71.650 

## 1 I 

## s73129 

## 1 1 

## 8.047 60 

## 11.141 60 

## 5.765 60 

## 68j07 60 

## 573.t32 60

certdas systemDeveloped by cartwright &Associates LittleRock, AR. ph (501) 7gI-36s5

### Post-test System 

### Calibration

Sowce Identification DTE BioGas Test Personnel UnitName Run End Time &Date 

## 6/3/2009 12:59.00 

### 6

### 3 2009

Zero Gas O2o/o le Mid Gas O2o/o ZeroGasCO2% le Mid GasCO2o/o Zero GasSO2 Mid Gas SO2 Zero Gas NOx Mid Gas NOx ZeroGasCO MidGas CO Analyzer Span Value System

Reference Value System Calibration Status

10.015

Certdas Syslem Developed by Cartwright & Associates Little Roch AR Ph (501) 791-3655

## DIE Energy'

APPENDIX F 

### OPERATIONAL DATABellefontaine Gas Producers LLC GC 3520C IC ENGINE Bellefontaine OHIO June 3,2009 

### Run 1 Run Time: 0804-0904


### Description vatue 

## 1 vatue

## z vatue J



## Unit 0804 0833 0902 AVc Engine Speed GeneratorTotal Real Power lntake Manifold 

### Air Flow Gas Fuel Flow GeneratorTotal kW hours Gas Fuel Correction Factor 

# RPM 1

### 199.00 1201

# .00 1

# 199.00 1199.67



# kw 1624.97 

### 1521.95 

# 1614.95 1587.29 

# PSI 47

# .2Q 47.20 47.30 47.23 

# scFM 561.00 

## 570.00 

# 564.00 565.00 kW 

### hours 3370032.00 

### 3370783 3371551 3370788.67 

# % 99.00 99.00 99.00 99.00Bellefontaine Gas Producers LLC GC 3520C IC ENGINE Bellefontaine OHIO June 3,2009 Run 2 Run 

### Time: 0952-1052


### Description Unit 

### Value 

### I 1001 1036 

# 1102 AVG Engine Speed Generator Total Real power lntake Manifold 

### Air Flow Gas Fuel Flow Generator Total kW hours Gas Fuel Correction Factor RPM KW PSI SCFM kW hours o/ /o 1200.00

1577.95 47.00 563.00 Unavailable 99.00 1201.00

1617.99 47.00 568.00 Unavailable 99.00 1199.00

1599.99 47.10 568.00 3374713 99.00 1200.00

1598.64 47.03 566.33 3374713 99.00Bellefontaine Gas Producers LLC GC 3520C IC ENGINE Bellefontaine OHIO June 3, 2009 

### Run 3 Run 

### Time: 1132-1232


### Description Unit 

### value'l 1135 

### value 2

1202 

### value 3

1234 AVG Engine Speed GeneratorTotal Real Power lntake Manifold 

### Air Flow Gas Fuel Flow Generator Total kW hours Gas Fuel Correction Factor RPM KW PSI SCFM kW hours % 1203.00

1614.95 46.70 559.00 3375611.00 99.00 1201.00 1615.96 47.13 564.67 3376361.3 99.00 1199.00 1645.96 46.70 562.00 3376307 99.00 1201.00

1586.97 48.00 573.00 3377166 99.00

## DTE 

## Energy" 

# K

APPENDIX G 

### ANALYTICAL DATA

# DTE Energgr

Limit 

### of Detection: 0.5 mg 

### Analytical Method 

### (USEPA): 5 

## Analytical Laboratory Report PM

## Testing DTE 

## Energy Corp. 

## Bellefontaine Gas 

## Producers LLC 

## Bellefontaine, OH 

## Sampling Date:

## June 03, 2009

(1)correction equation = sample net wt. gain/blank net wt. gain) x (sample vol./blank vol.) 

### Source ID 

### Test 

### # Beaker Number Beaker

initialwt. (o) 

### Beaker

Final wt. 

### (q) Beaker

Volume (mL) Beaker

net

### wt. gain (q) 

### Beaker

net

### wt. gain corrected(1) (< 

### Beakers-250m1 Unit3-1 Unit3-2 Un¡t3-3 1

2 3 Btk 30

31 32 33 

### 104.3028

105.1061 

### 102.7229 103.0700 104.3059

105.1076 

### 102.7235 103.0701 50

50 50 50 0.0031



### 0.0015 0.0006 0.0001 

### 0.0030

0.0014 0.0005 0.0000
Source ID 

### Test 

### # Filter Number Filter

initial wt. (q) 

### Filter

Final wt. (q) 

### Filter

net

### wt. gain (q) 

### 4" Filters Unit3-1 Unit3-2 Unit3-3 1 2 3 Btk 73

74 75 76 

### 0.6032

0.5990 0.6002 0.5966 0.6048

0.6005 0.6017 0.5966 0.0016



### 0.001s 0.0015 0.0000 

### Total net

### wt. gain Gorrected

0.0046 0.0029 0.0020

### ÐTE Earergy"

Facility: Sounce: SanrplínE Date:

Source ID Beakers

Limit of Detection: 0.5 mg Analyst(s): Date: 

# P\ Detroit Edison Company G

### ravametric Analytical Laboratory Report 

## ÊþT6v SeA.'.

## t. ' ß*
. 44J

### t.r- 

### 1

Beaker Finalwt.-2 

## 0f. ¡o6i 

## iô6. 

## tat2 a2,72

## 95

(1)correction equation = sample netwt. gain/blank netwt. gain) x (sample vol./blank vol.)



# - b:i:.r ttFrida;', jr-rne 12, ZOO9

8:33AM

Clicnt Samplc lD: Enginc lnlct #l L¿b ID#: 0906123414

Rpt Limtt 1/,1 Amount (%t 

# øf{-r-cs LrD. L tlt(jr,, tvty 5r'¡,'¡C Js Si/ril(', /-¡i.fl

ComÞound File Name: D¡1. FåctoÊ 9060505 1.00 Date ofCollection: 6/3J09 J2;l 5:00 PM

Oxygen Nitrogen Carbon Monoxide Mêthane Carbon Dioxide Ethâne Ethene Acetylene Propane lsobutane Butane Neopehtânê ìsopentane Pentane c6+ Hydrogen Totâl BTU/Cu-F- =51û TotêlSp. Gravity - 0,95 Contá¡nèl Type: I Lite¡ Tedlar Bag 0.10 0.10 0.010 0.0001 0 0.010 0.0010 0.0010 0.0010 0.0010 0.00r0 0-0010 0-0010 0.0010 0-0010 0.010 0.010 't_3 10 Not Detecled 50 37 Not Detecled Not Detected Not Delected 0.0027 Not Detecfëd Nol, Detecled Nót Detêcled It'lot Detacled Not Detected 0.013 0.23

Pâge 6of12

Unfiled Notes Pase I

# DTE Energy 

# Corporate

Services,

# LLC 6100 W.

## Warren Detroit,

# MI 48210



# Bellefontaine


# Analytical Report (060e

# -2t)

EPA Method 18 (Bøgs)

Methane 

# Enthalpy

# Analytical, lnc. Phone: (919)850 -4392 

## I Fax: (919) 850 -9012

## / www.enthatpy.com

2202 Ellis 

### Road Durham, NC27703 - 5518I certify that to the best of my knowledge all analytical data presented in this report:



## o Have been checked for completeness 

## o Are acc¡trate, error-free, and legible 

## o Have been conducted in accordancewith approved protocol, and that all deviations and analytical problems are summarizedtnthe appropriate nanative(s)



## . This analytical report was prepared in Portable Document Format (.PDF) and contains 75 pages.

Q.A. Review Performed byl Mchael Steven Schapira



### EA#0609-21 

### Page2of75 

# 'û81 Ll''J

# Summary of ResultsCompanylDTE Energy Corp Services Analystll(AM Parametersl EPA Method 18 # Samplesl3 Bags Client #l Bellefontaine Job #10609-21 PO#lVerbal Report Datel6/9/2009

nd Sample lD

### / usted Concentration
Run 2 1,723 Methane 

### Run

## I 1,730 Run 3 1,690

EA# 

### mÐ?|nrBCry'.4ror zs 6112t2009

# ResultsCompanylDTE Energy Corp Services AnalystlKAM ,arametersl EPA Method'l

### I # Sampbsl3 Bags & '1S/R bag Client #l Bellefontaine Job #10609-21 PO #lVerbal Report Datel6/9/2009 MDL 0.500 (ppm) 

### LoQ 3.00 (ppm) Compound Methane Lower Curue Limit 3.00 (ppm) Upper Curve Limit 80,600 (ppm)
Samp e ID Lab lD

#1 Lab lD

#2 Lab lD fJ Ret Time (min) Ret

Time (min) Ret

Time (min) %Dift

Ret Conc #1 (ppm) Conc #2 (ppm) Conc #3 (ppm) o/oDill

Conc Avg Conc (ppm) DF Rec

Eff (!") Adj Conc (ppm) Qua Run 1 02580301.D 025B0302.D 02580303.D 0509-78R.M 160 160 1.60 0.1 1.752 1 744 1.736 o4 1 744 1 101 1 730 02680402.D 02780502.D

EA# 0m94j1''.,8ßg_ç"p ot

### zs 611212009v2.02 Validated by MSS 3f 6/09

Whatwas the conc ofthe bag before spik¡ng?

U' (before
What was added fo the bag?

Volume Added

Volume Added

Volume Added Tolâl Vol (mL) vaporized Total Vol (mL) added as ges Othervolume (mL) Added Volume (mL) used in anêlysis
Whaf volume was ¡n the bag alter analysís?

Or¡ginal volume in the bag (mL) Total volume added (mL) Dilulion Factor caused by add¡tion Dilulion Adjusled Base Conc (ppm) "U" Theorelical Spike Conc (ppm) 'S" Energy Spike & Recovery Unspiked Sample lDlRun 1

T = after sp¡ke concentrêt¡on %Recovery=(T-U)/Sx100 U= before spike conæntration S = theoret¡cal sp¡ke concentration

Whãtwas the conc of the bag after spik¡ng? Final Concentration (ppm)

RECOVERY

T C ¡ent Job PO Report 1

6/3/09 8:04 A[/| 614109 12:46 PM
614109 2:20 PM Delta 28142i00
Hours 32:46:00 Analyzed Spiked Spike Analyzed Della 189 6/5/09 'fl:06 PÀ, than or¡oinel hold

6/t22009 5:58 PM 

### EA#0609-21 PageT 

### of75 0609-2t-h18bag-res % Recovery

# NarratÍve SummaryComnanv DTE Enerey Corp. Services

Analvst 

### KAM Parameters EPAMethod 18 # Samnles 3 Baes 

# EnthalpyAnalytical Narrative Summary
Client # Bellefontaine Job # 0609-21 

### PO# Verbal Report Date June 9. 2009 Erin 

### ortiz of Enthalpy Analytical, Inc. received the samples on6/4/09 at ambient temperature after being relinquished by DTE Energy Corporate services, 

### LLC. The samples were received

### in good condition. 

### prior to and during ahalysis,the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. The samples were analyzed for methane using the analyticalprocedures 

## in EPA Method 18, Measurement 

## of Gaseous Organic Compound Emissions by Gas Chromatography (40 CFRPart 60,AppendixA). 

### The standards and samples 

### were analyzed 

### following the procedures specified in section 8.2.I,Integrated Bag Sampling and Analysis. 

### All samples and standards were introduced directly to the column using an automated 6-port valco gassampling valve equippedwith astainless steel loop. Methane was referenced to certified gas phase standards. TheAgilent Technologies Model 6890, Gas Chromatograph ("Gummo" 

### sli{ us00028451) was equipped with a Flame Ionization Detector and a Restek 

### Rtx-l, 30 mx 0.32mm (Sn\f666512) capillary column. The calibration curve is located in the back ofthis report and referenced in theAnalysis Method column onthe Detailed Results page. For eachcalibration curve used, thefirst pageof the curve contains all method specific parameters (i.e., curve type, origin, 

### weigh! etc.) usedto quantify the samples. The calibration curve section also includes atable 

## with the Retention 

## Time (RetTime), 

## Level (Lvl), Amount (corresponding 

### units), 

### Area, Response 

### Factor (Amt/Area) and the analyte Name.The calibrationtable 

### is used

### to identify (by retention time) and 

### quantifr each target compound. 

### The acquisition method 

### WAX.M 

## is included 

## in the Curve/eA Chromatograms sectionofthis report. Custody

Analysis



### Calibration

Chromatographic Conditions 

# H

EA# 

### 0609-21 Page g

### of75

### Enthalpy 

## Analytical 

## Narrative Summary

QC Notes 

### (continued)

As required 

### by section 8.4.2, Recovery Study

### for Bag Sampling, a recovery study is performed on a bag sample. The bag sample 

### Run 7 was spiked at2:20 PM 

### on 614109. The recovery efficiency value meets 

### the method-required 

### limit 

## of between 

### 70 and 130%. 

### The recovery efficiency value 

### is used

### to adjust the results 

### following equation 18-7 from sectionI2.8. 

## All sample preparation and analytical holding times specified 

### in the method were met. Reporting 

## Notes These analytical results are reported 

### on awet basis. The user

### of this

report should determine the %o moisture 

### in the sample and correct the reported valueto ppmvd as appropriate. Enthalpy 

### Analytical, 

### Inc. 

## is accredited 

### to perform 

### this method for compliance purposes 

## by the National Environmental Laboratory 

### Accreditation Conference

## OfELAC) through

## the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010. The results presented inthis report are representative of the samples as provided to the laboratory. 

# H

EA#

### 0609-21 Page 10

### of75

## General 

## Reporting Notes

Thefollowing are general reporting notes that are applicable to all 

### Enthaþ AnalTticaT,Inc. reports, unless specifically noted othen¡¡ise. 

## o The symbol 

### MDL represents the Minimum Detection Limit. Belowthis value the laboratory carurot confrm the presence of the analyte of interest reliably. 

## o The symbol

### LOQ represents the 

### Limit 

### of Quantification. Below this valuethe laboratory cannot quantitatethe analyte of interestwithin the criteria of the method. 

## o The symbol ND following avalue indicates a non-detect or analytical result below the MDL.



## . The symbol -Ifollowing avalue indicates an analytical result between the MDL ard the LOQ. A Jflag indicates that the laboratory can positively identifu the analyte ofinterest as presen! but the value should be considered an estimate. 

## o The symbol 

### E following avalue indicates an arnlytical resultexceedng 100% of the highest calibration point.



## . The syrnbol D,F represents a Dilution Factor. This number represents dilutions during the extraction and/or laboratory stages of sample treatment. The analytical result takenfrom a laboratory instrument is 

### muþlied by the DF to get final results. 

## o The Sample 

### ID MS represents a Matrix Spike.An aliquot of an actual sample is spiked with a known amount of analyte sothat a percent recovery value can be determined. This showswhat effect the sample matrix may have on the target analyte, i.e. whether or not anything inthe sample matrix prohibits analysis for the analyte(s). 

## ' The Sample ID MSD represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use

### of duplicate matrix spikes allows further confirmation 

### of laboratory quality 

### by showing the consistency of results gained by perfonning the same steps multiple times. Most methods performed by Enthalpy do not require analysis of an MSD. 

## o The Sample 

### ID B,S repÍesentsa Blind Spike.

### A member 

### of the Quality Assurance deparhnent has created BS samples for many of the analytes Enthalpy tests for, andonly QA and the Enthaþ Analytical ownership have access to the actual values of these samples. The laboratory analyzes them without knowledge of the actual value, and the spreadsheets get completedfor these samples solely by the

### eA goup. 

## o The Sample 

### ID LCS represents a Laboratory Control Sample.Whenever spikes are prepared for our clients more spikes are prepared than needed. The extras (randomly chosen) are kept in-house at the appropriate temperature conditions. When the spike samples come backfrom the client for analysis, the LCSs (usually two are saved) are analyzed to confirm thatthe analyte could be recovered from the media separate from the spike samples which were used on the project andwhich may have had issues caused during collection and/or transport. 

## o Significant Figures: Where the reported value is much greaterthan unity (1.00) in the units expressed (specifically values of 1,000 or greater), the number is rounded to awhole number of units, rather than to 3 significant figures. For example, avalue of 10,456.45 ug catch is rounded 

### to 10,456 ug. There are five significant digits reported, but no confidence should be placed on more than three significant digits. 

## ')
EA# 

### 0609-21 Page 1 1

### of75

# Sample

# CustodyEA# 

### 0609-21 Page 13

### of75

# Sample



# Chromatograms

### Data 

### File c: \GC2O09Q2\GUMMo\DATA\JUN09\cC10?pc106\02580301. D Sample Name:

### 0609-2I Run 1 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Date 

### Acq" Method 

### Last changed 

### Analysis Method 

### Last chanqed kam Gummo 

### 04-Jun-09, 12:46:05 

### Seq. Line 

### Location 

### rnj 3 

### Vial 25 

### I Exte

### rnal 

### fnj Volume G :\Gc20 09Q2 \GUMMO\METHoDS \WAX. M 

### 5/12/20094:42:20 PM

### by tbo G :\GC2 O O9Q2 \GUMMO\METHODS \O509-7 BR. M 

### 6/5/2009 1:07:35 PM

400 350 300 250 200 150 100



### External- Standard Report 

### Sorted By : 

### Calib. Data 

### Modified : 

### Multiplier i 

### Diluti-on : Use 

### Multiplj-er c Dilution Signal 1: FID2 B, 

### Signal 5/29

### /2009 5 :50 :

### 04 PM 1.0000 1.0000 

### Eactor

### with ISTDs 

### RetTime 

### Type Area Amt/Area Amount 

### [min] [pA*s] [ppn]

|

### ------ |

### ---------- I

### ---------- |

### ---------- | 

### 1.603 

### pv 621

### .53241 2.'19771 1751.55176 

### Totals : 1751. 551? 6 

### Grp Name

-- t------- Methane



### *** End 

### of Report ***

Gumno 

### Reprocess 6/5

### /2009 1:07: 

### 39 pM EA#

### 0609-21 Page 15

### of75 Page 

### 1of1

### Data 

### Fil-e c :\Gc2009Q2\GUMMo\DATA\JUN09\GC107PG106\02580302. D Sample Name: 0609-27 Run 1 

### Acq. 0perator Acq. Instrument fnj

### ecti-on Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 04-Jun-09, 13:02:,04 

### Seq.Line Location 

### rnj 3 

### Vial 25 2 Exte 

### rnaÌ ln

### j VoJ-ume c :\GC2 00 902\GUMMO\METHODS \WAX. M 

### 5/I2/2009 4:,42:20 PM

### by tbo G :\GC2 0 0902\GUMMO\METHoDS \0509-7 BR. M 

### 6/5/2009 

### 1:07:35 PM pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Calib. Data Modified Mul

### tip J-ie

### r Diluti on Use 

### Multipl-ier & 

### Difution Signal 1: FfD2 B, 

### RetTime Type Area 

### [min] [pA*s ] 

## r------t----------l 1.603 

### PV 624.650't0 

### Totals : Signa 

### I 5/29

### /2009 5 :50 :

### 04 PM 1.0000 1.0000 

### Factor 

### wlth ISTDs 

### Aml/Area Amount

Ippm] 

### l----------l 2

### .19771 17 43. 50832

r'143.50832 

### Grp Name

--t------- Methane



### *** End 

### of RePort ***

Gummo 

### Reprocess

### 6/5/2009 1:07:48 PM EA# 

### 0609-21 Page 16

### of75 Page 

### 1of1-

### Data 

### File G:\GC2009Q2\cUMMo\DATA\,IUNO9\GCl07PG106\02580303. D Sample Name: 0609-21 Run 1 

### Acq. Operator 

### Acq. lnstrument 

### lnj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last chanqed kam Gummo 

### 04-Jun-09, 13: l-B:03 

### Seq. Line 

### Location 

### rnj 3 

### Viaf 25 3 

### External 

### Inj Volune G :\GC2 0 0902\cUMMo \METHODS \ldAX

. M 

### 5/L2/2009 

### 4:42:20 PM

### by tbo G :\GC2 O O902\GUMMO\METHODS \O 5O9-78R. M 

### 6/5/2009 

### l-:07:35 PM 107PG1

o n ¡.* pA 450 400 350 300 250 200 150 100 50



### Externaf Standard Report 

### Sorted By 

### Calib. Data Modified 

### Multiplier Dilution Use 

### MuftipJ-ier c Difution Signal 1: FID2 B, 

### Ret.TimeType Area 

### [min] [pA*s] 

### t------t---------- 1.

### 604 

### PV 622.00848 

### Totals l 

### Signal 

### 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt/Area Amount

lppml I

### ---------- |

### ---------- I 

### 2.19711 t]36.13355

1136.13355 

### Grp Name

--t------- Methane



### *** End

### of Reporl ***

Gummo 

### Reprocess 

### 6/5/2009 1:07:57 PM 

### EA#0609-21 Page 17of 75 Page 

### 1of1

### Data 

### File G:\GC2009Q2\GUMMo\DATA\JUNO9\cC107PG106\02680401. D Sample Name: 0609-2L Run 2 

### Acq. Operator 

### Acq. fnstrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 04-Jun-09, 13:34:05 Seq

### . l,ine I.ocation 

### rnj Inj Vo1ume 4



### V:-aI 26 1 

### External c :\GC2 0 0902\cUMMo\METHODS\WAX. M 

### 5/72/2009 4:42:20 PM

### by tbo G :\GC2 0 0 9Q2\GUMMO\METHODS\050 9-7 8R. M 

### 6/5/2009 1:07:35 PM pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Calib. Data 

### Modified Multiplier Di-lution Dilution Signal 

### 5/29/2009 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Area Amt,/Area Amount lpA*s 

### I [ppm] |

### ---------- |

### ---------- |

### ---------- 624.39380 2.197!1 I'142.19129 7142 .'t 91,29 Use 

### Multiplier Signal 

### 1: FID2 

### RetTime Type Imin] 

## t------ 1.604 PV 

### Total-s : & B, 

### Grp Name t--t------ Methane



### *** End 

### of Report ***

Gummo Reprocess 

### 6/5/2009 

### 1:08:09 PM EA#

### 0609-21 Page 18

### of75 Page 

### 1of1

### Data 

### Fife c: \GC200902\GUMMo\DATA\,IUN09\cC10?pc106\02680402.D Sanp1e Name:

### 0609-2I Run 2 

### Acq. Operator 

### Acq. fnstrument 

### lnj ection Date 

### Acq. Method 

### Last changed 

### Analysís Method 

### Last chanqed 

### : kam



### : Gummo 

### : 04-,Jun-09, 13:50:04 

### Seq. T,ine 

### Locatlon 

### rnj Inj Volune 4



### ViaI 26 2 Exte 

### rnal G :\GC2 0 0 9Q2\GUMMO\METHoDS\tÌAX. M 

### 5/L2/2009 4:42;20 PM

### by tbo G :\GC2 0 0 9Q2\GUMMO\METHODS\ 05 O9-78R. M 

### 6/5/2009 1:07:35 PM pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Calib. Data Modified 

### Multiplier Diluti on Use 

### MultipIi-er e Dilution Signal 1: FID2 B, 

### RetTime Type Area 

### lninl [pA*s] 

## t------l----------l 1.605 

## PV 679.62617 

### Totafs: S

### ignal 5/29/2009 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt/Area Amount

lppml t---------- 

### 2.19711 7129.48568

7129.48568 

### Grp Name

¡--t------ Methane



### *** End 

### of Report ***

Gummo 

### Reprocess 

### 6/5/2009 

### 1:08:19 pM 

### EA#0609-21 Page 19

### of75 Page 

### 1of1

### Data Eile G :\GC2009Q2\GUMMO\DATA\JUN09\GC107PGl06\02680403. D Sample Name: 

### 0609-2I Run 2 

### Acq. 0perator Acq. Instrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 04-Jun-09, 74:06:,01 

### Seq. Line Locati-on 

### lnj 4 

### Vial- 26 a J Exte

### rnaf 

### Inj Volume G :\GC2 009Q2\GUMMO\METHoDS \WAX. M 

### 5/72/2009 4:42:.20 PM

### by tbo G :\GC2 0 09Q2 \GUMMO\METHoDS \ 05 09-7 8R. M 

### 6/5/2009 1:07:35 PM I06\02680403.D) pA 450 400 350 300 250 200 150 100 50



### Externaf Standard Report 

### Sorted By 

### Calib. Data Modifíed 

### MuIti-plier Difution Use 

### Multiplier Signal 

### 1: FID2 

### RetTime Type Imin] 

## t------l 1.604 PV 

### Totals: Signal 5/29

### /2009 5 :50:

### 04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt,/Area Amount

Ippm] |

### ---------- I

### ---------- 2.19171 L'136.61668

11 36
.61668 Grp Name

t--t------ Methane ron 

### e D1lut B, Area IpA*s] 622 .7Br5B



### *** End 

### of Report ++*

Gummo Reprocess 

### 6/5/2009 

### 1:08:27 PM EA# 

### 0609-21 Page 

### 20

### of75 Page 

### 1ofL

### Data 

### Fife c: \GC2009Q2\cUMMo\DATA\JUNO9\GC107pc106\02?80501. D Sample Name: 0609-21 Run 3 

### Acq. Operator 

### Acg. Instrument 

### fnj ection Date 

### Acq. Method 

### Last chang.ed 

### Analysis Method 

### Last changed kam Gummo 

### 04-Jun-09, 74:22:70 

### Seq. Line : 5 

### Location :,

### Vial 2'7 

### Inj: 1 

### Inj Volurne: External G :\Gc2 0 09Q2 \GUMMO\METHODS \WAX

. M 

### 5/72/2009 

### 4:42:20 PM

### by tbo G :\cC20 09Q2\GUMMO\METHODS \ 0509-7 BR. M 

### 6/5/2009 1:07:35 PM pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Calib. Data Modified 

### Multipl-ier Dilution Use 

### Muftiplier Signal 

### 1: FID2 

### RetTime Type Imin] 

## t-----t 1.

### 604 PV 

### Total-s: Signal 

### 5/29/2009

### 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt/Area Amount

lppml |

### ---------- |

### ---------- 2.'191,t1 1698.58283

1698.58283 

### Grp Name

t--t------ Methane ron 

### e 

### Dilut B, Area

_

## i:i::1_

__ 608.55493



### *** End

### of Report ***



### EA#0609-21 Page21

### of75 Gummo 

### Reprocess

### 6/5/2009 1:08:37 pM Page 

### l-of1

### Data 

### FiIe Gr\GC2009Q2\GUMMO\DATA\JUNO9\cC107PG106\02780502. D Sample Name: 0609-21 Run 3 

### Acq. 0perator 

### Acq. lnstrument 

### fnjection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### Seq.Line Location 5



### ViaI 21 2 Exte 

### rnal 

### 04-Jun-09,74:,38:.1,2 Inj Tnj Volume G :\cC2 0 09Q2 \cUMMo \METHODS\WAX. M 

### 5/12/2009

### 4:42:20 PM

### by tbo G:\GC20 0902 \GUMMO\METHODS\ 0509-7 8R. M 

### 6/5/2009 

### l,:07:35 PM pA 450 400 350 300 250 200 150 100 50 t'.- @o o qo o


### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplier Dilution Use 

### Multipl-ier e Dilution Sì-gnal 1

### : EI D2 B, 

### RetTine Type Area 

### lninl [pA*s ] 

## t------t----------l 1
.604 

### PV 670 .1 6263 

### Totafs: S

### ignal 5/29/2009

### 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt,/Area Amount

lppml 

### Grp Name 

## t----------t--t----- 2.191L1 

### I104.14483 Methane

r104.'14483


### *** End

### of Report ***

Gummo Reprocess 

### 6/5/2009 

### 1:08:46 PM EA# 

### 0609-21 Page 22 

### of75 Page 

### 1of1Da

### ta File G:\cC2 0 0 9Q2\cUMMo\DATA\,lUN0 9\Gc1 0? pc1 0 6\02780503

. D Sample Name: 0609-27 Run 3 

### Acq. Operator 

### Acq. fnstrument 

### Inj ection Date .A,cq. Method 

### Last changed 

### Analysis Method 

### Last chanqed kam Gummo 

### 04-Jun-09, 14:54:18 

### Seq. l,ine Location -Ln j 5 

### ViaI 21 1 J Exte

### rnaf 

### Inj Volume G :\GC2 0 09Q2\GUMMo\METHoDS\WAX. M 5/1.2/2009 

### 4:42:20 PM

### by tbo G :\cC2 00 9Q2\cUMMo\METHoDS \0 509-7 BR. M 

### 6/5/2009 1:07:35 PM pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplie r Di

### lution Use 

### Multiplier & 

### Dilution Signa1 

### 1: FID2 B, 

### RetTime Type Area 

### [min] [pA*s ] 

### t------t---------- 1.604 PV 610.7s098 

### Totafs : 

### Siqnal 

### 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt/Area Amount

lppml |

### ---------- |

### ---------- 2 .'79171 7't 0 4.11229

7104.'t1229 

### Grp Name 

## t--t------ Methane



### *** End

### of Report ***

Gunmo Reprocess 

### 6/5/2009 1:08:55 pM EA# 

### 0609-21 Page23 of 75 Page 

### 1of1Da

### ta File G :\GC2 0 0 9Q2\GUI'4MO\DATA\JUNo9\GC1 07PG1 06\0 1? B0 2 0 1

. D Sample Name: N2 Blank 

### Acq. 

### ôperator : kam 

### Acq. fnstrument 

### : Gummo 

### Tnjectlon 

### Date : 04-Jun-09, 10:44:55 

### Inj Volume



### : G :\GC2 00902\GUMMO\METHODS \hlAx.M

pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modlfied 

### Multiplier Di.lution Signal 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Fãctor

### with ISTDs 

### Amt/Area Amount

lppml 

## t---------- Use 

### Multiplier Signal 

### 1: FID2 

### RetTime Type 

### lminl 

### l------l 1.594 

### Totals : Grp Name t--t------ Methane

1-

### Vlarnings 

### or Errors i Vüarning 

### : Calibrated compound(s) 

### not found

Gumrno Reproeess 

### 6/5/2009 

### 1:09:05 PM EA#

### 0609-21 Page 

### 24

### of75 Page 

### Iof2

### Data 

### File G :\GC2009Q2\GUMMO\DÄTA\JUN09\cC107pc106\01780202.D Sample Name 

### I N2 Bfank 

### Acq. Operator 

### Acq. Instrument 

### lnj ection Date 

### Acq. Method T,as

### t changed 

### Analysis Method LasÇ changed 

### kam Seq. 

### Line : 2



### Gummo Location : Vial 17 

### 04-Jun-09, 12:15;36 tnj : 2 

### Inj VoIume: External G:\Gc2 0 09Q2\GUMMo\METHODS \WAX. M 

### 5/I2/2009 4:42:20 PM

### by tbo G :\GC2 O O9Q2\GUMMO\METHODS \O5O 9-7 BR. M 6/5

### /2009 1 :07 :

### 35 PM pA 450 400 350 300 250 200 150 100 50



### Externaf Standard Report 

### Sorted By 

### Calib. Data 

### Modified Multipl ie 

### r Diluti on Use 

### Muftiplier & 

### Dilution Signal 1: FlD2 B, 

### RetTime Type Area 

### lminl [pA*s ] 

### t------t---------- L-594 

### Totafs : S

### ignal 5/29/2009

### 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt/Area Amount

lppml |

### ---------- |

### ---------- I

0.00000 

### Grp Name

--t------- Methane



### t hlarnings or Errors : 

### l{arning : Calibrated compound(s) 

### not found

Gummo Reproces 

### s 6/5/2009 1:09:14 pM EA# 

### 0609-21 Page25 of 75 Page 

### Iof2

### Data 

### File c :\cC2 00 9Q2\GUMM0\DATA\,IUN09 \GC107 PG10 6\0 1?802 03

. D Sample Name: N2 Blank 

### Acq. Operator 

### Acq. Instrument 

### lnj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 04-Jun-09, 12;30:01 

### Seq. Line T,ocation 

### rnj ¿ 

### ViaI 17 3External

### Inj Volune c :\cC2 0 0 9Q2\GUMMO\METHODS \I^IAX. M 5/ 1.2/2009 4 :42:,20 PM

### by tbo c :\GC2 00902 \GUMMo\METHODS \ 050 9-7 BR. M 

### 6/5/2009 1:07:35 PM



### External Standard Repor 

### Sorted By 

### Calib. Data 

### Modlfied SignaI 

### 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Area A¡nt/Area Amount lpA*s

### I [ppm]

|

### ---------- I

### ---------- Multiplier Di

### lution Use 

### MuJ-tiplier Signal 1: FfD2 RetT

### j-me Type lmin] 

## l------l 1.594 

### Totals : 10n

& 

### Dilut B, Grp Name t--t------ Methane 0.00000 

### 1Ìdarnings 

### or Errors : [nlarning 

### : Calibrated cornpound (s

### ) not found

pA 450 400 350 300 250 200 150 100 50

Gurnmo Reprocess 

### 6/5/2009 

### 1:09:23 PM EA# 

### 0609-21 Page

### 26 

### of75 Page 

### 1-of2

### Data 

### File G :\cC2 00 9Q2\GUMMO\DATA\,IUNO 9\GC1 0?pcl 07\02 58030 1
. D Sample Name: 0609-21 Run 

### 1 Sp 

### Acq. Operator 

### Acq. Instrument 

### fnj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 05-Jun-09, 20:.06:31 

### Seq. Line Location 

### rnj a

J 

### Vi-a] 25 1 

### External 

### fnj Volune G: \GC2 0 0902\cUMMo\METHODS\ldAX. M 

### 5/72/2009 

### 4:42;20 PM

### by tbo G :\cc2 0 0 9Q2\cUMMo\METHODS\0 509-? 8R. M 

### 6/5/2009 

### 1:25:03 PM 

### (modified after loadj-ng) pA 450 400 350 300 250 200 '150 100 50



### External Stairdard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplier Dilution S

### ignal 5/29

### /2009 5: 50 :

### 04 PM 1.0000 1.0000 

### Factor

### with ISTDs Use 

### Multiplier Signal 1: EID2 

### DíÌution & B, RetTime 

## _iil:1_ 1.600 

### Totafs 

### Type Area

lpA*sl 

## t------t----------l PB 1152.9189s Amt,/Area

2 .1 9176 Amount

lppml 

## t----------l 321't.97'78't 3211.91181 

### Grp Name 

## --t------- Methane



### *** End

### of RePor¡ *'t*

Gummo 

### Reprocess

### 6/5/2009 B:34:48 pM 

### EA#0609-21 Page27

### of75 Page 

### 1of1

### Data 

### File G :\GC2 0 0 9Q2\cUMMo\DATA\.lUN0 9\GC107 PG107\ 02580302

. D Sample Name: 0609-2L Run 

### 1 SP 

### Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 05-Jun-09, 20:22:,27 

### Seq.Lìne l,ocation 

### lnj Inj Volume 3



### Vial 25 2 

### External G:\GC2 0 0902 \GUMMO\METHODS \WAx. M 

### 5/72/2009 4:,42:20 PM

### by tbo G :\Gc2 00 9Q2 \GUMMO\METHoDS \0509-7 8R. M 

### 6/5/2009 'l:25:.03 PM 

### (modified after loading) pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Cafib. Data Modified 

### Multiplier Dilution S

### ignal 5/29/2009 5:50:04 PM 1.0000 1.0000 

### Factor 

### with TSTDs Use 

### Multiplier Signal 1: FID2 

### Dilution & Þ 

### RetTime

### Type Area Amt/Area Amount Grp Name 

### lminl [pA*s

### ] [ppm] 

## l------ 

## l----------l ---------- I

# -------- -r-- 

## r--------- 1.602 

### PB 7141 

### .82056 2.'79116

### 3203.14'156 Methane 

### Totals : 3203 -'1

### 41 6 

### *** End

### of Report ***

Gummo Reprocess 

### 6/5/2009 B:34:56 PM EA# 

### 0609-21 Page

### 28

### of75 Page 

### 1of1Da

### ta File c :\GC2 00 9Q2 \GUMMO\DATA\ JUNO 9\cC1 0?pcl07 \ 02 5803 03

. D Sample Name: 0609-27 Run 

### 1 Sp 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 05-Jun-09, 20:,38:.76 

### Seq.Line Locati-on 

### rnj Inj Volume 3



### ViaI 25 3 

### Bxternal G:\GC2 0 09Q2 \GUMMo\METHODS \t^lAX

. M 

### 5/12/20094:42:20 PM

### by tbo G:\GC2 O O9Q2 \GUMMO\METHODS \ O5O9-? 8R. M 

### 6/5/2009 7:25:03 PM 

### (modified after loading) pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Calib. Data 

### Modified Multipl i e

### r Dllution Use 

### Multiplier c Dilution Signal 1: FID2 B, 

### RetTime Type Area 

### lninl [pA*s ] 

## t------t----------l 1.602 

### PB 1151.56189 

### Totafs : 

### Signal 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt/Area Amount

lppml 

## t----------l 2.191,76 3214 

### .t9074

32I4.19014 

### Grp Name

Methane



### *** End 

### of Report ***

Gummo Reprocess 

### 6/5/2009 10:17:33 pM EA# 

### 0609-21 Page

### 29

### of75 Page 

### 1of1

# Curve(s)/QA PoÍnt(s)



# ChromatogramsMe

### thod c :\cC2 0 0 9Q2 \GUMMO\METHODS\ O5 09- 7BR. M 

### Calibration Table


### Ca1ib. Data 

### Modified Calcul-ate Based on 

### Rel. Reference Window 

### Äbs. Reference nüindow 

### Re1. 

### Non-ref. Vfindow 

### Abs. Non-ref. Window Use 

### Multiplier e 

### Diluti Uncafibrated Peaks : 

### Partial Calibration : 

### Correct Aff Ret. Times: 

### Curve Type 

### Origin VÍeight 

### 5/29/2009 

### 5:L2:02 PM External_ Standard PeakArea 

### 2.000 z 

### 0.000 min 

### 2.000 z 

### 0.000 min 

### on Factor with ISTDs 

### not reported Yes, ldentified peaks 

### are recalibrated No, only for identified peaks 

### : Linear : Connected 

### : Linear (Resp) 

### Recalj-bration Settj_ngs : 

### Average 

### Response : Average alJ_

### calibrations Average 

### Retention Time: Floating Averag.e New 75E' 

### Calibration Report Options : 

### Printout of recalibrations within a sequence: 

### Cafibration Table after Reca1i_bration 

### Normal 

### Report after Recalibration If the sequence 

### is done

### with bracketing: Resul_ts 

### of first cycle (ending 

### previous bracket) 

### Signal 1: FID2 B, 

### Signal 2: FID1 A/ 

### RetTime Lv1 Amount Area Amt,/Area Ref Grp Name 

### [min] Sig [ppm]

|

### -- |

### -- |

## ---------- |

## ---------- |

### -----_____ |___ t__ |______ 

### I-594 I 21 3.00000 1.09191 2.74i41 Methane 

### 22 20.00000 6.86-728 2.9\236 

### 23 45.00000 15.91A34 2.87.t55 

### 24 101.20000 

### 36.35231 2.7838-7 

### 25 1000.00000 

### 356.6"7L72 2.80370 

### 26 1,.00200e4 

### 3'tri.0s184 2.69569 2'7 

### 8.06000e4 

### 2.8'7560e4 2.BO2e2

Peak SumTable 

### Name startrime EndTime use Response 

### Multiplier rsrD



### lminl [min] Reference 

### factor peak 

### - |

### ------- I

### ------- I

### ---------- |

### -------- |__________ I___________ 

### as 

### ethane 1.655 1.890 

### None 1.45L4 1.0000 None 

### as 

### propane 1.890 2.500 

### None 9.9gO2e-1 1.0000 None 

### as 

### butane 2

### .500 3. 950 

### None i 

### .4S6Le-t 1. 0O0O None 

### as

### pentane 3.950 6.050 

### None 6-OB29e-I 1.0000 None 

### as 

### hexane 6.

### 050 7.850

### None 5.3075e-1 1. 0000 None 

### as 

### heptane 7.850 11.500 

### None 4.45g8e-1 1.0000 None


### Harpo 

### 5/29/2009 

### 5:44:37 pM EA# 

### 0609-21 Page 31ofTS 

### Page Lof 2MEthod G :\GC2 OO9Q2\GUMMO\METHODS\ 05 O9-? 8R. M

0 0

EA# 

### 0609-21 Page 32 o'f75

### Data 

### Fil-e G :\GC2 009e2 \GUMMO\DATA\APRO 9\cC1 07pcO 74\ O1 BBOT01

. D Sample Name: 9e707pq074 *1_I 

### Acq. Operator 

### Acq. fnstrument 

### Injection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed 

### : stg



### : Gummo 

### : 2L-Apr-09, 02:10:18 

### Seq. Line Location 

### rnj fnj Volume 1



### Vial 18 1 

### External 

### : G :\GC2009Q2\GUMMO\METHODS\!vAX. M 

### : 4/2/2009 10:51:55 AM

### by kam 

### : G:\GC2009Q2\GUMMO\METHODS\0509-7BR.M 

### : 5/29/2009 

### 5:21:31 PM 

### (modified 

### after loadinq) pA 90 80 70 60 50 40 30 20 10



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplier Dilution Use 

### Multiplier Signal 1: FfD2 

### RetTime Type fmin] 

## t------l 1.597 PV 

### Totals : SignaJ

### 5/29/2009 

### 5:12:02 PM 1.0000 1.0000 

### Factor 

### with fSTDs 

### Area Amt/Area Amount Grp Name 

### lpA*sl [ppm]

I

### ---------- |

### ---------- |

### -- |

### --------- 1.07959 2.81159 3.03535 Methane 3

.0353s 10n & 

### Dilut B,



### *** End 

### of RePort ***

Harpo 

### 5/29/2009 5:29:46 pM EA# 

### 0609-21 Page 33

### of75 Page 

### 1of1

### Data 

### File G :\cC2009Q2\GUMMO\DATA\APRO9\cC107PG074\01880702. D Sample Name: qclOlpq)1 

### 4 #77 

### Acq. Operator 

### Acq. Instrument fnj

### ectj-on Date 

### Acg. Method 

### Last changed 

### Analysis Method 

### Last changed Gummo



### 2!-Apx-09, 02:26:17 

### Seq. Line Location 

### rnj 'l 

### Viaf 18 2External

### Inj Volume G :\GC2 0 0 9Q2\GUMMO\METHODS\ViAx. M 

### 4/2/2009 10:51-:55 AM

### by kam c: \GC2 0 09Q2\GUMMO\METHODS\ 05 09- ? BR. M 

### 5/29/2009 5:27:31 PM 

### (modified

### after foadinq) FlD2 B, (G:\GC2009Q2\GUMMO\DATA\APR09\GC1 07PG074\01 880702.D) pA 90 80 70 60 50 40 fo 30

### --l Ë JÔ 

### l> 20

### 1 - n 

# ,oJ ffË

# i u Ë i (Ð Ì- q o



### ExLernal Standard Report 

### Sorted By 

### Cal1b. Data 

### Modified Multiplier Dil-ution Signal 5/29/2009 

### 5:]-2:02 PM 1.0000 1.0000 Use 

### MuJ-tipller ç Dil-ution Factor with ISTDs 

### Signal 1: FID2 B, 

### RetTime Type Area Amt/Area Amount Grp Name 

### lminl [pA*s] [ppm]

|

## ------ |

## ---------- I

## ---------- t---------- |

### -- |

## --------- 1.598 

### PB 7.08572 2.871-41 3.0524'l Methane 

### Totals : 3.05241


### *** End 

### of Report ***

Harpo 

### 5/29/2009 

### 5:29:52 PM EA# 

### 0609-21 Page 

### 34 o'f75 

### Page I of L

### Data 

### File G:\GC2009Q2\GUMMO\DATA\APR09\GC107PG074\01880703. D Sample Name: 

### gcI}lpqOl

### 4 #1L 

### Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed -tòL9 Gummo 21--Apr-09 

### , 02:42:04 

### Seq. T,ine 

### Location 

### rnj Inj Vol-ume 1



### Vial- 18 a J 

### External G:\GC2 0 09Q2\GUMMO\METHODS \VíAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 0 09Q2\GUMMO\METHODS\ 05 09-7 BR. M 

### 5/29/2009 5:2'7:31 PM 

### (modified after loading) pA 90 80 70 60 50 40 30 20 '10



### External- Standard Report 

### Sorted By 

### Ca1ib. Data 

### Modified Multiplier DiLution Signal 5/29/2009 5:1.2:02 PM 1.0000 1.0000 

### Factor 

### with ISTDs Use 

### Multiplier ç Dj-lution Signal 1: FlD2 Bl 

### RetTime

### Type Area Amt,/Area Amount Grp Name 

### lrnin] [pA*s] [pprn]

|

### ------ I

### ---------- |

### ---------- |

### ---------- |

### -- |

### --------- 1.598 

### PB 1.

### 11043 2

### .81702 3

### .1-2\45 Methane 

### Totals : 3.12145


### *** End 

### of Repor¡***

Harpo 

### 5/29/2009

### 5:29;59 PM EA#

### 0609-21 Page 35

### of75 Page 

### Lof L

### Data 

### Fif e G :\GC2 009Q2 \GUMMO\DATA\APR0 9\cC1 07pcO? 4\ 01980 601

. D Sample Name: gcI07pq074 #\2 

### Acg. Operator 

### Acq. Instrument 

### fnjection Date 

### Acq. Method 

### Last changed 

### Analysi-s Method 

### Last changed 

### stg Gummo 

### 21-Apr-09, 01,:,22238 

### Seq. Line Location Tnj 

### lnj Vo1ume 6



### Vi-al 19 1 

### External G: \GC2 O O9Q2\GUMMO\METHODS \WAX. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 O O9Q2\GUMMO\METHODS\ O5O9-7 8R. M 

### 5/29/2009 

### 5:27:31 PM 

### (modified after loadinq) pA 90 80 70 60 50 40 30 20 10



### External- Standard Report 

### Sorted By 

### Cafib. Data 

### Modlfied MuJ-tiplier Dilution Use 

### Multipfier c Difu Sígnal 1: FfD2 B, 

### RetTlme

### Type Area 

### [min] [pA*s ] 

### t------t---------- 1.596 PV 6.90681 

### Total-s : 

### Signal 

### 5/29/2009 5=1-2:02 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### tron
Amt,/Area 

## t----------l 2 .'7 9433 

### Amount Grp Name

Ippm] 

## t--l------ 19.30011 Methane 19.30011 

### *** End 

### of Report ***

Harpo 

### 5/29/2009 5:30:06 pM EA# 

### 0609-21 Page 36

### of75 Page 

### 1of1

### Data 

### Fife c: \GC2009Q2\GUMMO\DATA\APR09\cC107pc074\01980602

. D Sample Name: gcL07pg074 #1,2 

### Acq. Operator 

### Acq- fnstrument 

### Injection Date 

### Acq- Method 

### Last changed 

### Analysis Method 

### Last changed 

### stg Gummo 

### 21--Apr-09, 01:38:34 

### Seq. Line Locati-on 

### rnj Inj Volume 6

Vi-al- 19 2 

### External G :\GC2 O O9Q2\GUMMO\METHODS\VüAX. M 

### 4/2/2009 10:51:55 AM

### by kam G :\cC2 0 09Q2\GUMMO\METHODS\ 050 9-7 BR. M 

### 5/29/2009

### 5:2'l:31 PM 

### (modified

### after loading)



### External Standard Report 

### Sorted By 

### Ca1ib. Data 

### Modified 

### Multiplier Dilution Use 

### Multiplier Signal 1: ElD2 

### RetTime Type 

### lminl 

## l------ 1.596 PV 

### Totafs : 

### Signal 5/29/2009 5:1-2:02 PM 1.0000 1.0000 

### Factor

### with ISTDs


### Amt/Area Amount

Ippm] 6 .8817 6 2 .19434 

### Grp Name



## r----------t--l 19.24676 Methane
1-9 .246't 6 ton & 

### Dilut B, Area lpA* sl



### *** End 

### of Report ***

Harpo 5/29/2009 

### 5:30:13 PM 

### EA#0609-21 Page 37 of 75 Page 

### lofl

### Data 

### FiIe G :\Gc2 0 09Q2\GUMMO\DATA\APR0 9\cC107PGO7 4\01 980 603

. D Sample Name: qc1-01p9074 #12 

### Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method 

### Last changed 

### .Analysis Method 

### f,ast changed . ùL9



### : Gummo 

### : 21-Apr-09, 01,:54221 

### Seq. Line Location 

### rnj 6 

### Viaf 19 JExternal

### Inj Volume G:\GC2 0 0 9Q2 \GUMMO\METHODS \vüAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 0 0 9Q2 \GUMIVO\METHODS\ 0s 09-7 BR. M 

### 5/29/2009 5:2'l:31 PM 

### (modified after loadinq) pA 90 80 70 60 50 40 30 20 t0



### Externaf Standard Report 

### Sorted By : 

### Ca1ib. Data 

### Modifi-ed : 

### Multiplier : 

### Difution : Use 

### Multiplier c Di-lution Signal 1: FID2 B, 

### RetTime Type Area 

### Signal 5/29/2009 

### 5:72:02 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt,/Area Amount Grp

IPPm] Name 

### lminl IpA*s] 

### 1.597 PV 

### Totals : 

### 6.80720 2.19438 1-9.021-92 Methane L9 -02192 

### *** End 

### of Report ***

Harpo 5/29/2009 5:30:20 PM EA# 

### 0609-21 Page 38

### of75 Page 

### 1of1

### Data 

### Fife G:\GC2009Q2\GUMMO\DATA\APR09\GC107pcO74\02080501. D Sample Name: 9c107pq074 #13 

### Acq. Operator 

### Acq. fnstrument 

### lnjection Date 

### Acq. Method T,ast changed 

### Analysis Method 

### Last changed 

### stg Gummo 

### 21--Apr-09, 00:34:40 

### Seq. T,ine 

### Location 

### rnj Inj Volume 5



### VíaI 20 1-ExternalG:\GC2 0 0 9Q2\cUMMo\METHODS \WAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 O O9Q2\GUMMO\METHODS \ O5 O9-7 8R. M 

### 5/29/2009 5:2'1:31 PM 

### (modified after loadinq)



### External Standard Report 

### Sorted By 

### Cai-ib. Data 

### Modified Multiplier Dil-ution Signal 

### 5/29/2009

### 5:72:02 PM 1.0000 1.0000 

### Factor

### with ISTDs Use 

### Multiplier Siqnal 

### 1: FID2 

### Dil-ution & Þ 

### RetTime 

### Type Area 

### lminl [pA* s] t------t---------- 

### 1.598 

### PV 75.94104 

### Totafs : Amt,/Area



## l----------l 2.79252 Amount

lppml 44.5]-513 44.51,513 

### Grp Name 

## t--t------ Methane



### x** End

### of Report ***

Harpo 

### 5/29/2009 5:30:30 PM EA#

### 0609-21 Page 39

### of75 Page 

### 1of1

### Data 

### Fife G:\GC2009Q2\GUMMO\DATA\APR09\GC107PG074\ 02080502 .D Sample Name: qc107p9074 #13 

### Acg. Operator 

### Acq. ïnstrument 

### Inj ection Date 

### Acq- Method 

### Last changed 

### Analysis Method 

### Last changed . ù L9



### : Gummo 

### : 21-Apr-09, 00: 50:36 

### Seq. Line Locati-on Tnj 

### Tnj Vol-ume 5



### Vial 20 2 

### Externaf G:\cC2 0 0 9Q2\GUMMO\METHODS\wAx

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 00 9Q2\GUMMO\METHODS\ 05 09-7 BR. M 

### 5/29/2009 5:27:31 PM 

### (modified after loadinq)



### External Standard Reporl 

### Sorted By 

### Cafib. Data 

### Modified MuJ-tiplier Dilution Use 

### Multiplier Signal 1: FID2 

### RetTj-me Type Imin] 

## t------l 1.596 PV 

### Totals : 

### SignaI 5/29/2009 5:1,2:02 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt/Area Amount

lPpml 

### l----------l 2.'792s7 44.83'tB6

44.83186 

### Grp Name


### -- |

## ------- Methane 10n 

### e 

### Dilut
D Area lpA* sl 

### ----------l 76 .05646



### *** End 

### of Report ***

Harpo 5/29/2009 

### 5:30:36 PM EA# 

### 0609-21 Page40

### of75 Paqe 

### lofLDAtA 

### FilE G:\GC2OO9Q2\GUMMO\DATA\APRO9\GC1O7PGO74\02OBO503. D Sample Name: gcl07pq074 #13 

### Acq. Operator 

### Acq" Instrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysls Method 

### Last changed 

### : Gummo



### :2l-Apr-09,01:06:35 Seq. Line 

### Location 

### rnj fnj Volume 5



### Vial- 20 3 

### External G:\GC2 O O9Q2\GUMMO\METHODS \WAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\cC2 0 09Q2\GUMMO\METHODS \ 05 09-7 BR. M 

### 5/29/2009 5:2'7:31 PM 

### (modifled after loadinq)


# 'ol ffì n e



### Externaf Standard Report 

### Sorted By : 

### Cafib. Data 

### Modified : 

### Multiplier : 

### Difution : Use 

### Multiplier c Dilution Signal- 

### 1: FID2 B, 

### RetTime Type Area 

### [min] [pA*s ] 

## t------t----------l 1 -596 

### PV 15. 91650 

### Totals : 

### Slgnal 5/29/2009 

### 5:L2:02 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt/Area Amount

Ippn] 

## t----------l 2

### .19252 44 " 44'724

44 .441 24 

### Grp Name

--t------- Methane



### *** End 

### of Report ***

Harpo 

### 5/29/2009 5:30:42 pM EA# 

### 0609-21 Page 41 

### of75 Page 

### 1of1

### Data 

### File c: \GC2009Q2\GUMMO\DATA\APR09\cC107PGO74\021B0901. D Sample Name: qc1,07pq07 

### 4 #1,4 

### Acq. Operator 

### Acq. fnstrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed 

### stg Gummo 21"-Apr-09 

### , 09:1-'l :43 

### Seq. Line Location 

### rnj 9 

### VíaI 21- 1 

### External 

### Inj Volume G:\GC2 0 09Q2\GUMMO\METHODS \WAx

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 009Q2 \GUMMO\METHODS\05 09-7 8R. M 

### 5/29/2009 

### 5:34:41 PM



### ExternaÌ Standard Report 

### Sorted By 

### Calib. Data Modifi-ed 

### Multlplier Dilution Use 

### Multiplier & 

### Sj-gnal 

### 1: EfD2 B, 

### RetTime

### Type Area 

### [min] [pA*s ] ¡------t---------- 1
.593 

### PV 36 .2'7 6'7'1 

### Totafs : 

### Signal 5/29/2009 

### 5:L2:02 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt,/Area Amount

Ippm] |

### ---------- |

### ---------- 2

### .191_15 1_01" .27 554

10r.21554 Grp Name

t--t------ Methane aon 

### Difut

*** End 

### of Report ***

Harpo 

### 5/29/2009 

### 5z4l:50 PM 

### EA#0609-21 Page42of75 Page 

### 1of1

### Data 

### File G:\GC2009Q2\GUMMO\DATA\APR09\cC107pGO?4\02180902. D Sample Name: 9c707pq074 #74 

### Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last chanoed 

### stg Gummo 

### 2I-Apr-09,09:33:49 Seq. Line Location 

### rnj 9 

### YiaI 27 2 

### External Inj Volume G:\GC2 O O9Q2\GUMMO\METHODS \WAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 O O9Q2\GUMMO\METHODS\ O5 O9- ?BR. M 

### 5/29/2009 5:34:41- PM



### External Standard Report 

### Sorted By 

### Cafib. Data 

### Modified MultipJ-1er 

### Dilution Use 

### Multiplíer & 

### Difution Signal 1: FID2 B, 

### RetTj-me

### Type Area Amt,/Area Amount Grp Name 

### lminl [pA*s

### ] [ppm]

|

## ------ 

## t---------- |

## ---------- |

## ---------- |

### -- |

## --------- 1.593 

### PV 6-28415 2.191,'75 

### 1-0I.29i82 Methane 

### Totafs 

### : 101 .29'lB2 

### *** End 

### of Report *** Slgnal 5/29/2009 

### 5:12:02 PM 1.0000 1.0000 

### Factor 

### with ISTDs



### Harpo 5/29

### /2009 5: 4'7

### :57 PM EA#

### 0609-2'1 Page

### 43 of 75 Page 

### Lofl

### Data 

### Fil-e G :\cC2 0 0 9Q2\GUM'4O\DATA\APR0 9\ GCI01 PG074\ 02 180 903

. D Sample Name:

### gcl07pg074 #I4 

### Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed 

### stg Gummo 21--Apr-09 

### , 09 :,49 z31 

### Seq. Line Location 

### rnj 9 

### Vial 21 3 

### External Inj Volume G:\GC2 0 09Q2\GUMMO\METHODS \WAX

. M 

### 4/2/2009 10:51:55 AM 

### by kam G :\GC2 00 9Q2\GUMMO\METHODS\0509-7 BR. M 

### 5/29/2009 

### 5:34:41 PM pA '140 120
100 80 60 40 20



### External Standard Report 

### Sorted By 

### Cafib. Data 

### Modified Multiplier Dilution Use

### Multiplier Signal 

### 1: EID2 

### RetTime Type Imin] 

### l------l 1.593 PV 

### Total-s : 

### Signal 5/29/2009 5:]-2:.02 PM 1.0000 1.0000 

### Factor 

### with fSTDs 

### Amt,/Area Amount

lppml |

### ---------- |

### ---------- 2.'791_74 101.88583

101.88583 

### Grp Name

t--l------ Methane l_on &

### Dilut
D Area [pA* s ] 36.49542



### *** End

### of Report ***

Harpo 5/29/2009 5:48:03 PM EA# 

### 0609-21 

### Page44of75 Page 

### lof1Data F11e G :\GC2 0 0 9Q2\GUMMO\DATA\APR0 9\GC1 07PGO 76\0 1 9BO 1O 1

. D Sample Name: 9c107pq076 #15 

### Acq. Operator 

### Acg, ïnstrument 

### fnjection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed Sample 

### Info ^l

- ò L9 Gummo 

### 23-Apr-09, 7L:0L¡12 

### Seq. Line Location 

### rnj 1 

### Vial 19 1 

### Externaf 

### Inj VoJ-ume G:\GC2 O O9Q2\GUMMO\METHODS \WAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 0 09Q2\GUMMO\METHODS \05 09-7 8R. M 

### 5/29/2009 5:32:00 PM 

### (modifíed after l-oading) Methane Only

pA 1400
1200

1000 800 600 400 200



### External Standard Report 

### Sorted By 

### Calib. Data 

### Modified MultipJ-ier Dilution Use 

### Multiplier c 

### Signal 

### 1: FID2 B, 

### RetTime 

### Type Area 

### [min] [pA* s ] t------l---------- 

### 1.592 

### PB 363.40607 

### Totals : 

### Signal 

### 5/29/2009 5:L2:,02 PM 1. 0000 1.0000 

### Factor 

### with ISTDs
Amt,/Area Amount

Ippm] 2.'79120 1014.338s3

1014.33853 

### Grp Name 

## l--t------ Methane 

### Dilut 10n



### *** End

### of Report ***

Harpo 5/29/2009 

### 5:32;05 pM 

### EA#0609-21 Page

### 45of 75 Page 

### 1of1

### Data 

### F1Ie G :\GC2 00 9Q2\GU¡04O\DATA\APR0 9\GC107 PGO7 6\01980102

. D Sample Name: 9c107pq076 #15 

### Acq. Operator 

### Acq. fnstrument 

### lnj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed Sample 

### Info stq Gummo 

### 23-Apr-09, 11: 17 :06 

### Seq. Line 

### Location 

### rnj 1 

### Vial 19 2 

### External Inj Volume G :\GC2 O O9Q2\GUMMO\METHODS \WAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 O O9Q2\GUMMO\METHODS\0509-7 8R. M 

### 5/29/2009 

### 5:32:00 PM 

### (modified after loading) Methane Only

pA 1400 1200

1000
800 600 400 200



### Externaf Standard Report 

### Sorted By 

### Calib. Data 

### Modified Multiplier Dilution Use 

### Multiplier e Dil-ut 

### Signal 1-:,TID2 B, 

### RetTime Type Area 

### Amt/Area Amount Grp Name Ippm] 

### Inin] lpA* sl

1_-

### 593 PB 

### Totals : 357

.

### 05508 2 -1

### 9120 996 -

### 61.206 Methane 996 .6L206 ron 

### Signal 5/29/2009 5:1,2:02 PM 1.0000 l-.0000 

### Factor

### with ISTDs



### *** End

### of Report ***

Harpo 

### 5/29/2009 5:32211 PM EA# 

### 0609-21 Page 46

### of75 Page 

### lofl-

### Data 

### Fil-e c :\cC2 0 09Q2 \GUMMO\DATA\APRO9 \cC107PGO7 6\ 01980 103

. D Sample Name: gc107pqO76 #15 

### Acg. Operator 

### Acq. ïnstrument 

### fnj ection Date 

### Acq. Method 

### Last changed 

### AnaÌysis Method 

### Last changed Sample 

### fnfo stg Seq. Lj_ne 

### : 1



### Gummo Location : Viaf 19 

### 23-Apr-09, 1L:24:.29 nj: 3 

### lnj Volume 

### : Externaf G:\GC2 O O9Q2\GUMMO\METHODS \ÍfAX

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\cC2 0 09Q2 \GUMMO\METHODS\ 05 09- 7BR. M 

### 5/29/2009 5:,32:00 PM 

### (modified after loading) Methane OnJ-y

pA 1400 1200

1000 800 600 400 200 c,

c ñ E d)
t $ o¡ q? N C\¡ o



### External Standard Report 

### Sorted By 

### Caflb. Data 

### Modified Multiplier Dilution SignaI 

### 5/29/2009 5;1,2:02 PM 1.0000 1. 0000 Use 

### Multiplier ç Difution Factor with ISTDs 

### Signal 1: FID2 Bl 

### RetTime Type Area Amt/Area Amount Grp Name 

### [min] [pA*s] [ppm]

|

### ------ |

### ---------- I

### ---------- |

### ---------- |

### -- I

### --------- 1.594 

### PB 349.55222 2-79120 

### 9'75.61052 Methane 

### Totafs 

### : 975-61052 

### *** End

### of Report ***

Harpo 5/29/2009 5:32:.20 PM 

### EA#0609-21 Page47 

### of75 Page 1 of 1

### Data 

### File G:\GC2009Q2\GUMMO\DATA\APR09\cC10?PGO76\02180401. D SampJ-e Name: qc107pq076 #16 

### Acq. Operator 

### Acq. ïnstrument 

### Injection Date 

### Acq. Method 

### T,ast changed 

### Analysis Method 

### Last changed Sample 

### lnfo Gummo

23-Apr-09 

### , 11 :51 : 18 

### Seq. Line Location 

### rnj 4 

### Vial 21 1 

### External lnj Volume G :\GC2 0 09Q2\GUMMO\METHODS \WAX. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 00 9Q2\GUMMO\METHODS \05 09-7 8R. M 

### 5/29/2009 

### 5:32:00 PM 

### (modified after loading) Methane Only

pA 1400 1200
I 000 800 600 400 200



### Externaf Standard Report 

### Sorted By 

### Ca1ib. Data 

### Modified Multiplier Dilution Use 

### Multiplier c Difution Signal 1: EID2 Bl 

### RetTime Type Area 

### [nin] [pA*s ] 

## t------t----------l 1.594 

### PB 3713.00903 

### Totafs : 

### Signal 5/29/2009 

### 5:L2:02 PM 1.0000 t-.0000 

### Factor 

### wíth fSTDs 

### Amt,/Area Amount

IPPm] 

## t----------l 2.1911-4 1.03635e4

1. 03635e4 Grp Name

--t------- Methane



### *** End

### of Report ***

Harpo 5/29/2009 5:32:,34 PM EA# 

### 0609-21 Page 48

### of75 Page 

### 1of1

### Data 

### Fife G:\cC2009e2\GUMMO\DATA\APRO9\GC1O7pco7 6\021B04O2.D Sampì-e Name: gc107pg076 #16 

## *:: ?f::"o' ' rts seq. 

### Line 

## : 4 

### Acq. Instrument 

### : Gummo 

### Location: Vial 21 

### lnjection Date : 23-Apr-09, 

### I1_:5g:42 -""-';;i : "': r¡rJ

. Z G:\GC2oo9e2\GUMM.\METH.DS\wAX. 

### rnj volume 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 O O9Q2 \GUMMO\METHODS\ O5 O9-7 BR. M 

### 5/29/2009 5:32:O0 PM 

### (modified

### after loading) Methane Only 

### External Ä,cq. Method 

### Last changed 

### Analysis Method 

### Last changed Sample 

### Info

External Standard Repor 

### Sorted By 

### Ca1ib. Data 

### Modified Multiplier Dilution & 

### Dilution B, Signaì_



### 5/29/2009 5:12:02 pM 1.0000 1.0000 

### Factor

### with ISTDs 

### Area Amt,/Area Amount Grp Name 

### [pA*s] Ippml

|

### ---------- I---_______ |__ |_________ 

### 3701.8'1280 2.i9IL4 1.03325e4 Merhane 1. 03325e4 Use

### Multiplier Signal 

### 1: FID2 

### RetTime Type [min] 

## t------l 1.594 PB 

### Totals : 

### *** End 

### of Report ***



### larpo 5/29/2009 S:32-.42 pM 

### EA#0609-21 Page49 ofTS Page 

### 1of1

### )ata File G:\GC2009Q2\GUMMO\DATA\APR09\GC107PGO76\02180403' D 

### iample Name: gc107PgO76 +16 

### Acq. Operator 

### Acq. fnstrument 

### Injectíon Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed Sample Tnfo 

### : stg



### : Gummo 

### : 23-APr-09, t2:O'1t0'l 

### Seq. Line Location Tnj 

### Tni Volume 4

YLa:. 21 3 

### External G:\GC2 O0 9Q2\GUMMO\METHoDS \WAX ' M 

### 4/2/2009 10:51:55 AM 

### bY kam G :\GC200 9Q2\GUMMO\METHODS\0509-7 BR' M 

### 5/29/2009 

### 5:32:00 PM 

### (modifÍed after loading) Methane OnlY



### Externaf Standard Repor 

### Sorted BY 

### Ca1lb. Data Modi-fied 

### MultiPlier Dilution Signal 

### s/29/2009 5"L2z02 PM 1. 0000 1. 0000 

### Factor 

### with ISTDs Use 

### MultiPlier Signal 1: EID2 

### RetTime TYPe Imin] 

### l------l 1.593 PB 

### Totals : 

### Difution & B, Area [pA* s] 

### ----------l 3136.21368 

### Amt/Area Amount IPPm] 

## t---------- 2.'19114 1-.04285e4

L -04285e4 

### Grp Name 

## t--l------ Methane



### *** End 

### of Report *** pA 1400 1200

't000
800 600 400



### Ilarpo 5/29/2009 5"32:48 PM EA# 0609-2',l Page 50 of 75 Page 

### 1of1

### Data Fife G:\GC2009Q2\GUMMO\DATA\APR09\GC107PG074\02181401-. D Sample Name: 9c101p9014 #77 

### Acq. Operator 

### Acq. fnstrument 

### fnjection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed 

### : Gummo



### :, 2I-Apr-09 

### , 22 232:00 

### Seq. Llne Location Tnj 

### Inj Volume 74



### Vial 21 1 

### Externaf G :\GC2 0 09Q2 \GUMMO\METHODS \WAX. M 

### 4/2/2009 10:51:55 AM

### by kam c :\GC2 00 9Q2 \GUMMO\METHODS\ 05 09-7 8R. M 

### 5/29/2009 

### 5:31:26 PM 

### (modified after loadinq) pA 14000

12000
I0000 8000 6000 4000 2000



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplier Diluti-on Use 

### Muftiplier & 

### Dil-ution 

### Signal 

### 1: FID2 B, 

### RetTime 

### Type Area Amt,/Area Amount Grp Name 

### [min] [pA*s

### ] [ppm] 

## t------t---------t----------t-l--l----- 1.581 

### PB 2.87722e4 2.19a1-4

### 8.030?3e4 Methane 

### Totals : 8.03073e4


### *** End 

### of Report *** Signal 5/29/2009 5:12:.02 PM 1.0000 1.0000 

### Factor 

### with ISTDs



### Harpo 

### 5/29/2009 5:31.t29 PNI EA# 

### 0609-21 Page 51

### of75 Page 

### 1of1DAIA 

### FilE G:\GC2OO9Q2\GUMMO\DATA\APRO9\GC1O?PGO74\0218]-402. D Samp1e Name: qc107pg0?4 #17 

### Acq. Operator 

### Acq. fnstrument 

### Tnjection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last chanqed 

### stg Gummo 27-Apr-09 

### , 22: 48:,04 

### Seq. Lj-ne LocaLion 

### rnj Inj Volume 

### I4



### Yial- 2L 2 

### External G :\cC2 0 09Q2 \GUMMO\METHODS \WAx

. M 

### 4/2/2009 10:51:55 AM

### by kam G :\GC2 O O9Q2\GUMMO\METHODS\ O5 O9-7 8R. M 

### 5/29/2009 5:31:26 PM 

### (modified 

### after loading) pA 14000

12000

10000 8000 6000 4000
2000



### Externaf Standard Report 

### Sorted By 

### Cal-ib. Data 

### Modified Multiplier Difution Use 

### Multiplier Signal 

### 1: FlD2 

### RetTime

### Type Area Amt,/Area .Amount 

### Grp Name 

### lminl [pA*s] [ppm]

I

## ------

## t------- --

## t----------

## t----------t--l
--------- 1.582 

### PB 2.88351e4 2.19114 

### 8.0482'te4 Methane 

### Totafs: 8.0482'le


### *** End

### of Report *** 

### : Signal 

### : 5/29/2009 

### 5:!2:02 PM 

### : 1.0000 

### : l-.0000 

### ion Factor

### with TSTDs &

### Dilut
D



### Harpo 5/29/2009 

### 5:31:36 PM 

### EA#0609-21 Page

### 52of 75 Page 

### 1of1

### Data 

### File G :\cC2 0 0 9Q2 \GUMMO\DATA\APRO 9\cC107PG07 4\02 181 403

. D Sample Name:

### qclOlpq)l4 #I7 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Date 

### Acq. Method 

### Last changed. 

### Analysis Method 

### Last changed 

### stg Gummo 21--Apr-09

### , 23 :,04:08 

### Seq. T,ine 

### Location 

### rnj 74 

### via:. 2t 3 

### External fnj Volume G:\GC2 0 09Q2 \GUMMO\METHODS \WAx

. M 

### 4/2/2009 10:51:55 AM 

### by kam G :\GC2 0 09Q2 \GUMMO\METHODS\0s 09-7 8R. M 

### 5/29/2009 

### 5:31:26 PM 

### (modified after loadinq)



### External Standard Report pA 14000 12000
I0000 8000 6000 4000 2000



### Sorted By 

### Calib. Data Modified 

### Multlplier Di-lution Signal 5/29/2009 5:12202 PNj 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt/Area Amount

lppml |

### ---------- |

### ---------- | 

### 2-'l9LI4 8.00023e4


### - 8.00023e4 10n Use 

### Multiplier Signal 1: FID2 

### RetTime Type 

### lmin] 

### l------l 1.584 PB 

### Totals : 

### e 

### Difut

D Area lpA* sl 2.86630e4 

### Grp Name --t------- Methane



### *** End

### of Report ***

Harpo 5/29/2009 5:31:42 PM EA# 

### 0609-21 Page 53

### of75 Page 

### 1of1

### Data 

### File c :\GC2 00 902\GUMMo\DATA\ JUNO 9\cC10 7 PG1 06\02 180 1 0 1

. D Sample Name: qc107pg74 #13 

### Acq. Operator 

### Acq. lnstrument Injection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 04-Jun-09, 09:5'1 :46 

### Seq. Line Locatíon 

### rnj Inj Volume 1



### Vial 21 1 

### External G :\GC2 0 0902\GUMMo\METHODS \WAX

. M 

### 5/12/20094:42:20 PM

### by tbo G :\GC2 00 9Q2\GUMM0\METHODS \0509-7 BR. M 

### 6/5/2009 10:57:49 AM A\JUNO9\GC 1OTPG 1 pA 45 40 ÒE
30 25 20 15 10 5



### External Standard Report 

### Sorted By 

### Ca1ib. Data 

### Modified Multiplier Di

### lution Use 

### Multipfier c Dilution Signal 1: FID2 B, 

### RetTime Type Area 

### [mín] [pA*s ] 

## t------t----------l 1.598 

## PV 14.98742 

### Totafs: Signa 1 

### 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt/Area Amount

Ippm] 

### l----------l 2.19267 41.83't28

47.83'128 

### Grp Name

--t------- Methane



### *** End 

### of Report ***

Gummo 

### Reprocess

### 6/5/2009 1:04:39 PM 

### EA#0609-21 Page

### 54of75 Page 

### Lofl

### Data 

### File c :\GC2 009Q2\GUMMO\DATA\JUN09\Gc107PGIO6\02180102. D Sample Name: gc107pq?4 #13 

### Acq. Operator 

### Acq, fnstrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysi-s Method 

### Last chanqed kam Gummo 

### 04-Jun-09, 10:13:40 

### Seq.Line Location 

### rnj 1 

### Vial- 21 2External

### lnj Volume c: \GC2 0 0902\cUMMo\METHODS \WAX

. M 

### 5/72/2009 

### 4:42:20 PM

### by tbo c :\GC2 0 09Q2\GUMMO\METHODS\ 0509-78R. M 

### 6/5/2009 10:57:49 AM pA 45 40 35 30 25 20 15 10
5



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplier Diluti on Use 

### Muftiplier c DiÌution Signal 1: FID2 B, 

### RetTime Type .Area 

### lminl [pA*s ]

l------l---------- 

### 1.599 

### PV 74.99452 

### Totals: Signal 

### 5/29/2009 

### 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Ant/Area Amount

lPPml | ---------- I ---------- 

### 2.19267 41.87386

41.87386 Grp Name

t--t------ Methane



### *** End 

### of Report ***

Gummo 

### Reprocess 

### 6/5/2009 1:04:49 PM EA# 

### 0609-21 Page 55

### of75 Page 

### 1of1

### Data File G:\GC2009Q2\GUMMO\DATA\JUN09\GCl-07PG106\02180103. D SampIe Name: gc107pg74 #1-3 

### Acq. 0perator 

### Acq. ïnstrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last chanqed kan Gumrno 

### 04-Jun-09, 10:29:33 

### Seq. line Locatíon 

### rnj lnj Volume 1



### VíaI 21 3 

### Externaf G:\GC2 0 0902\cUMMo\METHODS\i^lAX. M 

### 5/L2/2009 4:,42:20 PM

### by tbo G :\GC2 0 0 9Q2\GUMMO\METHoDS \05 09-7 BR. M 

### 6/5/2009 10:57:49 AM



### External Standard Report 

### Sorted By 

### Ca1ib. Data 

### Modified 

### Multiplie r Difution Use 

### Multipfier & 

### Dilut Signal 1: FID2 B, 

### Signal 

### 5/29/2009 5:50:04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 10n 

### RetTime 

### Type Area Amt/Area Amount Grp Name 

### [min] [pA*s

### ] [ppm]

|

## ------ |

## ---------- |

## ---------- t---------- |

### -- |

## --------- l-.599 

### PV 14.93088 2.'19262 4I.69621 Methane 

### Totals : 4I.69627


### *** End 

### of Report ***

Gummo Reprocess 

### 6/5/2009 

### 1:04:59 PM EA# 

### 0609-21 Page 56

### of75 Page 

### lofl-

### Data FiIe G:\GC2009Q2\GUMMO\DATA\JUNO9\cC107PG106\02180701. D Sample Name: gc107pg74 #13 

### Acq. Operator 

### Acq. Instrument Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kan Gummo 

### 04-Jun-09, 17:02:38 

### Seq. Line 

### Location 

### rnj 't 

### Vial 21 1 Exte

### rnal 

### Inj Volume c :\GC2 0 0 9Q2 \GUMMO\METHODS \!fAX. M 

### 5/12/2009 

### 4:42:20 PM

### by tbo G :\GC20 0902 \GUMMO\METHoDS \050 9-7 8R. M 

### 6/5/2009 10:57:49 AM pA 45 40 35 30 25 20 15 10 5



### External Standard Report 

### Sorted By 

### Calib. Data Modified 

### MulLipli e

### r Di

### l-uti on Use 

### Multiplier c Dílutíon Signal 1: FID2 B, 

### RetTíme Type Area 

### [nin] [pA*s ] 

### t------t---------- 1.599 PV 15.?0?94 

### Totafs: Sì-gnal 

### 5/29/2009 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt,/Area Amount

lppnl |

### ---------- |

### ---------- 2.'19254 43.8651-0

43.86510 

### Grp Name

t--t------ Methane



### *** End 

### of Report ++*

Gurnmo 

### Reprocess 

### 6/5/2009 1:05:11 PM EA# 

### 0609-21 Page57

### of75 Paqe 

### 1of1

### Data Fil-e G:\GC2009Q2\GUMMO\DATA\JUNO9\GC107PG106\02180702. D Sample Namer gc107pg74 #13 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Dat.e 

### Acq. Method 

### Last changed 

### Analysis Method 

### l,ast changed kam Gummo 

### 04-'Jun-09, I'1 

### :I8:25 Seq. Line Location 

### lnj Inj Volume 1



### Vial 2l2 

### External c :\GC2 0 09Q2 \GUMMO\METHODS\llAX. M 

### 5/L2/2009 4:42:20 PM

### by tbo G :\GC2 00 9Q2 \cUMMo\METHoDS \0 509-7 BR. M 

### 6/5/2009 10:57:49 AM



### External Standard Report 

### Sorted By 

### Calib. Data 

### Modified Multlpl ier Diluti on Use 

### Multiplier Si-gnal 

### 1: FID2 

### RetTine Type Imin] 

## t------ 1. 600 PV 

### Totals: Signal 5/29/2009 

### 5:50:04 PM 1. 0000 1.0000 

### Factor

### wìth ISTDs 

### Amt./Area Amount

lppnl t---------- 

### 2.'79254 43.88166

43.88166 

### Grp Name

t--t------ Methane ron 

### & 

### Dilut

D Area 

### lpA*sl 

## t----------l 15.71387



### *** End 

### of Report ***

Gummo Reprocess 

### 6/5/2009 

### l-:05:19 PM EA#

### 0609-21 Page 58

### of75 Page 

### 1of1

### Data File c: \GC2009Q2\GUMMO\DATA\JUN09\GC107PGIO6\02180703. D Sample Name: gc107pg74 #13 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last chanqed karn Gumno 

### 04-Jun-09, 17:34:15 

### Seq. Line Location 

### rnj Inj Volume '7



### Vial- 27 3 

### Externaf G :\GC2 0 0 9Q2 \cUMMo\METHODS \WAX. M 5/ 12

### /2009 4:,42: 2

### 0 PM

### by tbo G :\GC2 0 0902\GUMMO\METHODS \ 0509-? BR. M 

### 6/5/2009 L0:57:49 AM D)

@ 6 ñ pA 45 40 35 30 25 20 15 10 5



### External- Standard Report 

### Sorted By 

### Calib. Data Modified Mul

### tip 1i- e

### r Dílution Use 

### Muftiplier e Dilution Signal 1: FID2 B, 

### Ret.TímeType Area 

### [min] [pA*s] 

## i------t---------- 1.600 

## PV 15.69332 

### Totafs: SÍgnal 

### 5/29/2009 

### 5:50:04 PM 1. 0000 1.0000 

### Factor 

### with ISTDs 

### Amt/Area Amount

Ippm] |

### ---------- |

### ---------- 2.79254 43.82429

43.82429 Grp Name

t--t------ Methane



### *** End 

### of Report ***

Gummo 

### Reprocess 

### 6/5/2009 1:05:,29 PM EA# 

### 0609-21 Page 59

### of75 Page 

### 1of1

### Data 

### FiIe G:\GC200902\GUMMO\DATA\,IUN09\cC107PG107\02180101. D Sample Name: 9c107p9107 #13 

### Acq. Operator 

### Acq. lnstrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed 

### kam Seq. 

### Line : L



### Gummo Location 

### : ViaI 21 

### 05-Jun-09,76:,05:,23 tnj: 1 

### Inj Volume 

### : External G:\cC2 0 0902 \GUMMC\METHoDS \l^jAX

. M 

### 5/72/2009 

### 4:42:20 PM

### by tbo G :\GC2 0 0902 \GUMMo\METHODS \ 050 9-7 BR. M 

### 6/5/2009 1:25:03 PM 

### (modified after loading)

, lG:\GC2009O2\GUM

dJ c G c c) = -s aoI, @Jì @F 180101.D)

o o ñ pA 450 400 350 300 250 200 150 100 50 o q @ @@ SN Oô 

## ññ @ n o + ON oh @c! @ a? $ t-. @
10 

### External Standard Report 

### Sorted By : Signal 

### Calib. Data 

### Modified : 5/29/2009 

### 5:50:04 pM 

### Multiplier : 1. 0000 

### Dilutlon : 1.0000 Use 

### Mufti-p1ier & 

### Dilution Factor with ISTDs 

### Signal 1: FID2 Bf 

### RetTime Type Area Amt,/Area Amount Grp Name 

### [min] [pA*s

### ] tppml

|

### ------ |

### ---------- |

### ---------- |

### ---------- |

### -- |

### --------- 1.599 

### PV 15.73393 2.19254 43.93764 Methane 

### Totafs | 43 .931 64 

### *** End

### of RePo¡¡ 

### ***

Gummo Reprocess 6/8

### /2009 9:08:57 AM EA# 

### 0609-21 Page 60 of 75 

### Page 1 of 1

### Data 

### FiIe c: \cC2 009Q2\GUMMO\DATA\.IUN09\GC107Pc107\02180102

. D Sample Name: 9c107p9107 #13 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Date 

### Acg. Method 

### Last changed 

### Analysis Method 

### Last changed 

### : kam



### : Gummo 

### : 05-Jun-09, 76:,2I:,23 

### Seq.Line T,ocation 

### rnj 1 

### VLaI 27 2 Exte

### rnal 

### Inj Volume G :\GC2 0 0 9Q2 \GUMMO\METHODS \l/iAX. M 

### 5/12/2009

### 4:42:20 PM

### by tbo G :\cC200 9Q2 \GUMMO\METHoDS \ 0509-7 BR. M 

### 6/5/2009 

### 'l:25:03 PM 

### (modified after loadinq) 102

o s ñ pA 450 400 350 300 250 200 '150 100 50



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### MuIti-plier Dilution Use 

### Muftiplier & 

### Dilution Signal L: EID2 Bl 

### RetTime Type Area 

### lminl [pA*s ] 

## r------t----------l 1.597 

### PV 15.87698 

### Totals : Si

### gnal 

### 5/29/2009 5:50:04 PM 1.0000 1.0000 

### Factor

### with ISTDs 

### Amt,/Area Amount Grp Name

Ippm] 

## t----------l--t----- 2.19253 44.33692 Methane

44.33692


### *** End 

### of Report ***

Gummo 

### Reprocess 

### 6/8/2009 9:09:06 AM EA# 

### 0609-21 Page 61

### of75 Page 

### lofL

### Data Fife G:\GC2009Q2\GUMMO\DATA\,IUN09\GC107pc107\02180103. D Sample Name: 9c107p9107 #13 

### Acq. Operator 

### Acq. lnstrument 

### lnj ection Date 

### Acq. Method 

### Last changed AnaJ-ysis Method 

### Last changed kam Gummo 

### 05-Jun-09, 16:37:08 

### Seq.Line T,ocation 

### rnj 1 

### Vial- 21 3 

### External 

### lnj Volume G :\Gc2 0 0 9Q2 \GUMMo\METHoDS \WAX. M 

### 5/72/2009

### 4:42:20 PM

### by tbo G:\GC2 O O9Q2\GUMMO\METHODS \05 O9-7 BR. M 

### 6/5/2009 

### ?:25:03 PM 

### (modified after loadinq) pA 450 400 350 300 250 200 '150 '100 50



### External Standard Report 

### Sorted By 

### CalÍb. Data 

### Modified 

### Multiplier Dilution Signal 

### 5/29/2009

### 5:50:04 PM 1.0000 1.0000 

### Factor 

### with TSTDs Use 

### MuÌtiplier Signal 

### 1: FID2 

### Dilution &
D 

### RetTime 

### Type Area 

### lmj-nl [pA*s] 

## t------t----------l 1.59? 

### PV 15.73795 

### Totafs: Amt/Area

2 .1 9254 Amount

lppml 

## t---------- 43.94888 43.94888 

### Grp Name 

## l--t------ Methane



### *** End 

### of Report ***

Gummo Reprocess 6/B

### /2009 9: 09: 

### 19 AM 

### EA#0609-21 

### Page62of75 Paqe 

### 1of1

### Data Fif 

### e c :\GC2 00 9Q2\GUMMO\DATA\,IUN0 9\cC1 07 PG107 \ 021804 0 1
. D Sample Name: qc701pgl

### 4 +13 

### Acq. Operator 

### Acq. lnstrument Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed 

### kam Seq. 

### Line ; 4



### Gummo Location : Vial 21 

### 05-Jun-09, 20:54:00 Inj : 1 

### Inj Volume 

### : External G :\GC2 O O9Q2\GUMMO\METHODS \WAX. M 

### 5/72/2009 

### 4:42:20 PM

### by tbo G :\GC2 0 0902\cUMMo\METHoDS \ 0 509-7 8R. M 

### 6/5/2009 7:25:03 PM 

### (modifi-ed

### after loadíng)

TA\JU

t- q? s pA 450 400 350 300 250 200 150 100 50 0) C õ E (¡) _o ø-: |æ N N (ì 6 n \t ñ O@ eO Oo ñôi e Ì.- oì s 

### s @ q @ @

G



### External Standard Report 

### Sorted By : Signal 

### Ca1ib. Data 

### Modified : 5/29/2009 

### 5:50:04 PM 

### Multiplier : 1.0000 

### Di-lution : 1.0000 Use 

### Mul-tj-p1ier c Dilution Factor with TSTDs 

### Signal 1: FID2 B, 

### RetTime Type Area A¡nt,/Area Amount Grp Name 

### [min] [pA*s] [ppn]

|

## ------ |

## ----------l ---------- |

## ---------- |

### -- I

## --------- 1.599 

## PV 15.59427 2.19255 43.54166 Methane 

### Total-s: 43 .54"t 66 

### *** End

### of Report +**

Gummo 

### Reprocess 6/B/2009 

### 9:07:40 AM EA#

### 0609-21 Page 63

### of75 Page 1 of LDa

### ta Fil-e G :\GC2 0 0 9Q2\GUMMO\DATA\JUNO 9\GC1 07 pG1 O7\02 180 402

. D Sample Name: gc107pg74 +13 

### Acq. Operator 

### Acq. Instrument 

### Injection Date 

### Acq. Method 

### Last changed 

### Analysís Method 

### Last changed kam Gurnmo 

### 05-Jun-09, 2L:.09:46 

### Seq. Line 

### Location 

### rnj Inj Vo1ume 4



### Vial 21 2 

### External G :\GC2 0 0 9Q2\cUMMo\METHODS\WAX. M 

### 5/12/2009 4:42:20 PM

### by tbo G :\GC2 O O902\GUMMO\METHODS \O5O 9-7 BR. M 

### 6/5/2009 7:25:03 PM 

### (nodified after loading) pA 450 400 350 300 250 200 150 100 50



### External Standard Report 

### Sorted By 

### Ca1ib. Data Modified 

### Multiplier Di

### luti on Use 

### Multiplier & 

### Dilution Signal 1: FID2 B, 

### RetTime Type Area 

### lminl [pA*s ] 

### t------t---------- 1.599 PV 15.56863 

### Totals i 

### Signal 5/29

### /2009 5: 50:

### 04 PM 1.0000 1.0000 

### Factor 

### with ISTDs 

### Amt,/Area Amount

lppml |

### ---------- |

### ---------- 2 .7

### 9256 43

. 4't 626

43

. 41626 

### Grp Name 

## t--t------ Methane



### *** End 

### of Report ***

Gummo 

### Reprocess 6/B/2009 

### 9:07:58 AM EA#

### 0609-21 Page

### 64 of 75 Page 

### 1of1

### Data 

### File G:\GC200902\GUMMO\DATA\JUN09\GC107PG107\02180403.D Sample Name: gc107pg?4 +13 

### Acq. Operator 

### Acq. Instrument 

### Inj ection Date 

### Acq. Method 

### Last changed 

### Analysis Method 

### Last changed kam Gummo 

### 05-Jun-09, 21:25:35 

### Seq. Line 

### Location 

### rnj 4 

### Vial 21 3 ExternaL 

### Inj Volume c :\cC2 0 0902 \GUMMO\METHODS \WAX. M 

### 5/72/2009 4:,42:,20 PM

### by tbo G :\GC200 9Q2\GUMMO\METHODS \05 09-7 BR. M 

### 6/5/2009 

### 7:25:03 PM 

### (modified 

### after loading)

, (G: TA\JUN09\GC1 07PG 107\021 80403.D)

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### External Standard Report 

### Sorted By : Signal 

### Ca1lb. Data 

### Modified : 5/29/2009 5:50:04 PM 

### MuJ-tiplier 1 1.0000 

### Dil-ution : 1.0000 Use 

### Multiplier e Dilution Factor with ISTDs 

### Signal 1: îlDz B, 

### RetTime Type Area Amt/Area Amount Grp Name 

### [min] [pA*s] [ppm]

|

## ------ I

## ---------- r

## ---------- |

## ---------- |

### -- |

## --------- 1.

### 600 

### PV 15.51795 2.'19256 43.33480 Methane 

### Totals: 43.33480


### *** End

### of Report ***

Gummo 

### Reprocess 6/B

### /2009 9: 08 :

### 08 AM EA# 

### 0609-21 Page 65

### of75 Page 1 of 1

### method: G:\GC2 0 09Q1\GUMMO\METHODS \I/VAX

. M 

### Modifled on: \/37/2009 at 1:24:1-0 PM

6890 GC METHOD
OVEN 

### Initial temp: 40 rC (On) Maximum 

### temp: 250 'C 

### Initial time: 4.00 

### min Equilibration time: 0.20 min Ramps: 

### # Rate Final temp Final t.im 

### 1 15.00 10 0.07 

### 2 30.00 200 1.00 

### 3 0.0(off) Post temp: 50 'C 

### Post time; 0.00 min Run

### time: 11.40 rnin FRONT INLET 

### (SPlIT/SPLTTLESS) BACK INLET (SPLIT/SPLITLBSS) 

### Mode: Split Mode: Split Initial temp: 160'C (On) Ini_tial temp: 160 'C (On) 

### Pressure: 1.83 psí (On) Pressure: 5.27 psi (On) 

### Split ratio: 1

### ;1 Split ratio: 0. 5: 1 

### Split ffow: 5.3 mllmin Split flow: 1.0 ml/min 

### Total ffow: 16. B 

### ml/nin Total flow

### z 9

### .4 ml/min Gas

### saver: Off Gas 

### saver: Off Gas 

### type: Hydrogen Gas 

### type: Hydrogen COLUMN

### 1 COLUMN 2 

### Capillary Column Capillary Cofumn 

### Model 

### Number: Ä,1fteck 

### EC-Wax Model 

### Number: Restek RTX-1 30m*0.53mm 1.2un Max

### temperature: 260 rC Max

### temperature: 340 'C 

### Nominal 

### length: 30

.

### 0 n Nominal 

### length: 30

.

### 0 m 

### Nominal 

### diameter: 530

.

### 00 

### um Nominal diameter 

### : 320.

### 00 un 

### Nominal 

### film thickness: 1.20 um Nominal 

### film thickness: 4.00 um 

### Mode: constant fl-ow Mode: constant flow f

### nitial f

### low: 5.3 ml,/min Tnitial f

### low: 2
.

### 1 nl,/min 

### Nominal 

### init pressure: 1.83 psi Nominal 

### init pressure: 5.28 psi Average

### velocÍty: 40 

### cmlsec Average 

### vefocity:, 40 cm/sec 

### Inlet: Front Infet Tnlet: Back 

### Infet Outlet: Front Detector Outfet: Back 

### Detector 

### Outlet pressure: ambient Outlet pressure: ambient FRONT DETECTOR 

### (F]D) BACK DETECTOR (FID) 

### Temperature: 250tC (On) Temperature: 250 rC (On) Hydrogen 

### flow: 40.0 mllmín (On) Hydrogen 

### flow: 40.0 mllmin (On) 

### Air flow: 450.0 

### ml/min (On) Air flow: 450.0 

### mtlmin (On) 

### Mode: Constant makeup

### flow Mode: Constant makeup

### flow Makeup

### flow: 45.0 ml/min (On) Makeup

### ffow: 45.0 nllmin (On) Makeup Gas

### Type: 

### Nitrogen Makeup Gas

### Type: Nitrogen Flame: On Flame: On 

### El-ectrometer: 0n Electrometer: On 

### Lit offset : 2

### .0 Lit offset : 2.0 STGNAL 

### 1 SIGNAL 2 

### Data rate: 20 

### Hz Data 

### rate: 20 Hz 

### Type: front detector Type: backdetector Save 

### Data: On Save 

### Data: On 

### Zero: 0.0 (Off) Zero: 0.0 (Off) 

### Range: 0 Range: 0 

### Fast Peaks: Off Fast. 

### Peaks: Off

Gummo4/1,/2009 

### 11:04:10 AM kam EA# 

### 0609-21 Page 66

### of75 Page I of 2

### EA#0609-21 Page 67

### of75Sequence 

### : G:\GC2009Q2\GUMMO\SEQUENCE\GC1OTpGO?4. S

Sequence 

### Table (Front Tnjector): Method 

### and 

### fnjection fnfo Part: Line Location SampleName



### DataFile LimsÏD Method 

### lnj SampleType InjVolume


### 1 Vial 16 

### 2 vía]- 76 

### 3 Vial- 16 

### 4 Viaf 16 

### 5 Vial 4 

### 6 Viaf 3 

### '7 YíaI 2 

### I Vial- 1 

### 9 Vial 6 

### 10 Viaf 1 

### l-1 Vial- 3 

### 72 Vial- 4 

### 13 Vial 1 

### 14 Vial 5 

### 15 Vial- 1 

### 1-6 Vlal- 6 

### I7 Vial 1 gc10 7p907 4

gctl1pg07 4 gc101pg07 4 gc707pgO1 4 qc1,01p907 4 9c1,07p907 4 gct01pg07 4 Bfank gc707pg07 4 Bfank qc1,07p907 4 9cL01pq01 4 Blank qc1,07p907 4 Bfank gc107pg07 4 Blank WAX VfAX WAX
VüAX
VüAX WAX
VüAX PAUSE WAX PAUSE WAX
VüAX PAUSE WAX PAUSE !üAX PAUSE

Method #1 +2 #3 +4 +13 #72 #11

#1-4 4 3 3
J 3 3 3 1 3 1 3 3 1 3 1 3 1 SampIe

Sample Sample Sample Sample Sample Sample Sample SampIe Sample SampIe Sample Sample SampIe Sample Sample Sample #15 +16

#r1

#18

Sequence 

### Table (Back 

### Tnjector): Method 

### and 

### Injectj-on fnfo Part: l,ine Location SampleName



### DataFile LimslD 

### rnj SampleType InjVolume

1 2 3
4 5 

### Vial 32 

### Vial- 32 

### víal- 32 

### \IiaI 32 

### Vial 20 gc707pg07 4

qc1,07p907 4 gc707pg07 4 gcI07pg07 4 gcl07pq07 4 #1

+2 #3 #4 #13 VIAX

VfAX vÍAx
WAX WAX 4 3 3 3 3 SampIe

Sample Sample Sample Sample 

### Harpo 

### 6/I/2009 1,0:42: 14 AM EA# 

### 0609-21 Page68 of 75 Page 

### 1-of2Li-ne 

### l,ocation SampLeName 

### DataFile LimsfD 

### rnj

EA#0609-21 Page69of75SEqUCNCE

### : G: \GC2OO9Q2\GUMMO\SEQUENCE\GC1O7PGO76. S

Sequence 

### Table (Front Tnjector): Method 

### and 

### Injection fnfo part: Line Location SampleName



### DataFile LimsfD Method 

### lnj SampJ-eType fnjVolume


### 1 Vial 3 

### 2 YiaI 4 

### 3 Vial 4 

### 4 Viaf 5 

### 5 ViaI 13 

### 6 Vial 14 

### 7 Vial 15 

### B ViaI 13 

### 9 via:. L2 

### 10 vial 11 

### 11 Vial 10 

### 1-2 Vial 9 

### 13 Vial 8 

### 14 Vial 7 

### 1-5 Vial- 16 

### 16 Vial 16 

### 1-'l Vlal 5 

### 18 1'Iiú. 2 

### 19 Vial 1 

### 20 Vial 1 9c107pq076 +15

gc107pg07 

### 6 +1,6 gc107pg07 

### 6 #16 9c107pq076 #16

gcL01pg064 

### #1 & +5 qcl07pq064 

### #1

### c #5 gic107pg064 

### #l-

### c #5 Blank Blank VüAX I/üÄx vüAx WAX WAX
VüAX WAX VfAX VÍAX
WAX VfAX WAX V{AX WAX Ï\ÏAX
WAX WAX WAX WAX PAUSE 3 3
J

a J 3

a J 3 3 3

a J 3

a J 3 3 3 2 3 3 4 1 Sample

SampJ-e Sample Sample Sample Sample SampJ-e Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample SampIe Sampl-e Sequence 

### Table (Back 

### lnjector): Method 

### and 

### Injection fnfo part: Line Location SampleName



### DataFile LimsID Method 

### rnj SampleType InjVolume

3 3 l_ 2 

### Vial 19 qc|)1pgOl6 

### Viaf 20 qc1,01p9076 VÍAX
VüAX #15 #16 Sample Sample 

### Harpo 6/1/2009 

### I0:42:21 AM EA# 

### 0609-21 Page 70

### of75 Page 

### 7of2Sequence 

### : G: \GC2 OO9Q2\GUMMO\SEOUENCE\GC1O7PG1O5. S

Sequence 

### Table (Front fnjector): Method 

### and 

### Injection fnfo part: Line location SampleName



### DataFile LimsID Method 

### rnj SampleType InjVolume 

### 1 Vial 2 ViaI 3 Vlaf 4 Vial

### 5 Vial 6 Vial 7 Vial I Vial 9 Vial 10 Vial 11 Vial 72 VialN2 Blank

paus e

paus e qc10?pq106 gc10?p9106 9c107p9106 paus e i,{AX WAX
t^TAX WAX ü]AX PAUSE I^IAX PAUSE i¡]AX WAX I^ïAX PAUSE

Method E J
1 9 10 11
1
5
1 76 76 76
1 +1 +2 +3 3
3
3 3 3
1 3
1 3 3 3
1 Sample

Sample Sample

Sampl e SampIe SampIe Sample Sample SampIe

Sanpl e SampÌe

SampJ- e Sequence 

### Tabl-e (Back 

### Tnjector): Method 

### and 

### Injection lnfo part: Line Location SampleName



### DataFile LimsID 

### rnj SanpleType InjVolurne 

### 1 Viaf 21 

### 2 ViaI 7'l 

### 3 Vial 25 

### 4 ViaI 26 

### 5 vial- 2'7 

### 6 Vial 17 

### 7 Vj-aI 2L 

### B Vial 17 

### 9 Vial 32 

### 10 Vial 32 gc107pg74 #13

N2 Blank 0609-2L Run 1 0609-27 Run 2 

### 0609-2I Run 3 paus e gc701pg7

### 4 #1.3 paus e gc10?p9106 *1 gc107pgL06 #2 I,[AX I,VAX t/üAx I,{AX Î^iAX PAÜSE I,{AX PAUSE tVAX L{AX 

### EA#0609-21 Page72 3 3 3 3 3 1 3
1 3 3 of 75 Sample

Sample Sample Sanple Sanple Sample Sample Sample Sample SampIe

Gummo 

### 6/5/2009 

### I:06:02 PM kam Page 

### Lof2

### Line 

### location SampleName



### trA#0609-21 Page 73 

### ofTS