### 74534052789 PMNX131124382214605 Q44F6P

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Page 2 SANITIZED SUBMISSIONDouglas Rhubright Technical Director PALMER INTERNATIONAL, INC. P.O. Box 315, 2036 Lucon Road Skippack PA 19474 drhubright@palmerint.com

Douglas Rhubright Technical Director Palmer International Incorporated P.O. Box 315, 2036 Lucon Road Skippack PA 19474 drhubright@palmerint.com 610-842-7569



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730 5.8 78.9 Palmer GPC AC6079_8-30-13.docx



### Cashew Nutshell Liquid
8007-24-7 XXX 

### X XXX 

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Paraformaldehyde 30525-89-4 XXX 

### X XXX 

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Diethanol Amine
111-42-2 XXX 

### X XXX 

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Diisopropanol Amine 110-97-4 XXX 

### X XXX 

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## X 364922 CAS IES Name 1462343-28-7.pdf 

### Cashew, nutshell liquid, polymer with formaldehyde, reaction products with diethanolamine and diisopropanolamine

1462343-28-7 See Attachment 005 (Mannich Molecule_130214.pdf)

Mannich Molecule_130214.pdf Page 7 SANITIZED SUBMISSIONXXX

XXX

Cashew-Nutshell-Liquid, polymer with formaldehyde, reaction products with diethanol amine and diisopropanol amine CAS IES Name 1462343-28-7.pdf Cashew Nutshell Liquid GHS.PDF 

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X Cashew Nutshell Liquid 8007-24-7 3 Diethanol Amine 111-42-2 1 Diisopropanol AMine 110-97-4 0.1

Water 7732-18-5

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### XXX XXX 

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X The product would be used as a polyol to be reacted with polyisocyanates to create polyurethane foam. XXX 

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XXX XXX XXX 

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XXX 

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Page 10 SANITIZED SUBMISSIONSee Attachment 009 (Reactor B Basic.pdf)

Reactor B Basic.pdf Page 11 SANITIZED SUBMISSIONLoading of CNSL Safety glasses, glasses and apron liquid 2 XXX XXX 

### X Loading Diethanol Amine and Diisopropanol Amine Safety glasses, gloves and apron liquid 2 XXX XXX 

### X XXX Full face respirator, tyvek suit, gloves solid pellet 2 XXX XXX 

### X X XXX Full face respirator, gloves liquid 1 XXX XXX 

### X X Drumming Safety glasses, gloves, apron liquid 1 XXX XXX 

### X Quality Control testing Safety glasses, gloves, lab coat liquid 1 XXX XXX 

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Page 12 SANITIZED SUBMISSIONXXX XXX XXX XXX XXX XXX 

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### XXX 

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See Attachment 013 (PMN Other Sites Sanitized_131124.pdf)

PMN Other Sites Sanitized_131124.pdf Page 14 SANITIZED SUBMISSIONP10SB1(a)(4)1 Part II, Section B, 1(a)(4). Operation Site Locations

XXX

Page 15 SANITIZED SUBMISSIONA) 1 1 50 See continuation page. id: <P10ASB2(6)C1R1> 100 100

0 0 None Only in the event of a spill B) 2 2 100 See continuation page. id: <P10ASB2(6)C1R2> 100 100

0 1 Lines and hose are pumped dry and then drained of any residual liquid to collection pail which is added to next batch. C) 1 2 100 XXX XXX XXX

0 0 

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0 0 

### X E) 2 1 250 XXX XXX XXX

0 1 Lines and hose are pumped dry and then drained of any residual liquid to collection pail which is added to next batch. 

### X F) 2 6 250 XXX XXX XXX

1 0 See continuation page. id: <P10ASB2(12)C1R6> 

### X G) 1 1 65 XXX XXX XXX

0 0 No release other than in a spill event at customer 

### X

X

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## (1)

H) 2 1 250 XXX XXX XXX

0 1 Lines and hose are pumped dry and then drained of any residual liquid to collection pail which is added to next batch. 

### X I) 2 6 250 XXX XXX XXX

1 0 See continuation page. id: <P10ASB2(12)C1R9> 

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Page 17 SANITIZED SUBMISSIONP10ASB2(6)C1R1 Part II, Section B, 2.(6) Protective Equip./Eng. Controls, etc., Row 1

- Safety glasses, steel toe boots; - totes are stored in diked area; - Liquid with no appreciable vapor pressure

Page 18 SANITIZED SUBMISSIONP10ASB2(6)C1R2 Part II, Section B, 2.(6) Protective Equip./Eng. Controls, etc., Row 2

- Gloves, Safety Glasses or Googles, chemical resistant Apron; - Mix tanks are contained within a diked area, well ventilated with exhaust fans; - Liquid with no appreciable vapor pressure

Page 19 SANITIZED SUBMISSIONP10ASB2(12)C1R6 Part II, Section B, 2.(12) Media of Release & Ctrl Technology, Row 6

Lines and hose are pumped dry and then drained of any residual liquid to collection pail which is allowed to solidify. Any overspray or mold overflow solidifies within minutes and is trimmed off parts -then disposed off as nonhaz waste

Page 20 SANITIZED SUBMISSIONP10ASB2(12)C1R9 Part II, Section B, 2.(12) Media of Release & Ctrl Technology, Row 9

Lines and hose are pumped dry and then drained of any residual liquid to collection pail which is allowed to solidify. Any belt overflow solidifies within minutes and is trimmed off parts -then disposed off as nonhaz waste

Page 21 SANITIZED SUBMISSIONRaw Material Source - Traditional Mannich-polyols used in polyurethane foams are based on the reaction of ethanolamine, formaldehyde,

nonylphenol and ethyleneoxide such as CAS 940912-28-7. These materials use nonylphenol which is derived from petroleum feedstock. Nonylphenol is undesirable due to evidence that it is an endocrine disrupter. The proposed product 1462343-28-7 is derived from cashew nutshell liquid, CNSL, as the base phenolic. CNSL is a naturally occuring phenolic lipd isolated from the shell of the cashew nut. CNSL is a by product of the cashew nut harvest and does not take away from the food harvest as soy or sugar based product do. Substitution of nonylphenol polyols with CNSL based polyols will reduce the carbon footprint of polyurethane foams by replacing up to 75% by weight petroleum feedstock with a green renewable byproduct. Manufacturing - {XXX} Customer Use: The 1462343-28-7 CNSL derived polyol will be used in polyurethane and polyisocyanurate foams. The resulting foam will be used at an industrial manufacturing site for foam board production by mixing with flame retardants, blowing agents, surfactants and polyisocyanates. The foams will also be used by trained prefessional contractors for on-site spray foam applications. The use of foam board and spray foam insulation reduces energy use for heating and cooling of residential and commercial businesses as well as industrial process equipment such as tanks and pipes. Increased foam insulation qulaity reduces energy use and reduces CO2 emmisions.

Page 22 SANITIZED SUBMISSION001 MSDS of Cashew Nutshell Liquid ingredient Cashew Nutshell Liquid GHS.PDF Pt.I, Sec.B, 3. 0 002 Partition Coef for AC6079 Kow Report AC6079.pdf Worksheet: Octanol / water partition coefficient 0 003 CAS IES name CAS IES Name 1462343-28- 7.pdf Pt.I, Sec.B, 2c. | Pt.I, Sec.B, 6. 0 004 CNSL Composition CNSL Composition_131015.docx 30 005 CNSL Polyol Structure Diagram Mannich Molecule_130214.pdf Pt.I, Sec.B, 2e. 1 006 Process Description PROCESS DESCRIPTION OF CNSL MANNICH POLYOL 1 007 FTIR of AC6079 AC6079 FTIR.pdf Worksheet: Spectra 1 008 GPC of AC6079 Palmer GPC AC6079_8-30- 13.docx Pt.I, Sec.B, 2a. 3 009 Reactor Diagram Reactor B Basic.pdf Pt.2, Sec.A, 1d. 1 010 msds AC6079 AC6079 MSDS.doc 0 011 Analog Dermal Irritation Study AC6060 Acute Dermal Irritation.pdf 0 012 Analog Oral Tox Results AC6060 Oral Tox.pdf 0 013 Sanitized Exposure at other Sites PMN Other Sites Sanitized_131124.pdf Pt.2, Sec.B, 1a. 6

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## X Measured 1.1017 Measured
500 Estimate 25 acetone



## X 007 FTIR Measured 

## X 002 Measured

XXX XXX 

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## ATTACHMENT HEADER SHEET Attachment Number 001 Attachment Name MSDS of Cashew Nutshell Liquid ingredient 

## Associated PMN Section Number

Pt.I, Sec.B, 3. Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 002 Attachment Name Partition Coef for AC6079 

## Associated PMN Section Number Worksheet: Octanol / water partition coefficient

Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 003 Attachment Name CAS IES name 

## Associated PMN Section Number Pt.I, Sec.B, 2c. | Pt.I, Sec.B, 6. Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 004 Attachment Name CNSL Composition 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 005 Attachment Name CNSL Polyol Structure Diagram 

## Associated PMN Section Number

Pt.I, Sec.B, 2e. Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 006 Attachment Name Process Description 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 007 Attachment Name FTIR of AC6079 

## Associated PMN Section Number

Worksheet: Spectra Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 008 Attachment Name GPC of AC6079 

## Associated PMN Section Number

Pt.I, Sec.B, 2a. Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 009 Attachment Name Reactor Diagram 

## Associated PMN Section Number

Pt.2, Sec.A, 1d. Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 010 Attachment Name msds AC6079 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 011 Attachment Name Analog Dermal Irritation Study 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 012 Attachment Name Analog Oral Tox Results 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number PMNX131124382214605

## ATTACHMENT HEADER SHEET Attachment Number 013 Attachment Name Sanitized Exposure at other Sites 

## Associated PMN Section Number

Pt.2, Sec.B, 1a. Does not contain CBI 

## Report Number PMNX131124382214605