P. 1 

## OAR Box 

# 1672 Prepped by Charmelle Mathews

Document

Number: 

# 'JS0JII-C-1 O Docket Number: 

# A-98-1 3

Printed 9/30/200811:01:00AM

Sheet 39of 132P. 2 A 9 8 1 3 ll-C-i o Dat e sent : From : Subject : To : Copie s to : Fri , 3 0 Ja n 199 8 11:05:3 5 -050 0 STEV E SHED D < SHEDD.STEVE@epamail.epa.gov > Organi c Liquid s Distribution MAC T -Repl y donna_h@deq.state.la.u s bhaneke@rtp.pes.com , bnorton@rtp.pes.com , glaflam@rtp.pe s JHELMS@rtp . pes . co

m Donna , W e ha d on e majo r meetin g wit h th e industr y and ar e presentl ymovin g alon g slowly . Attache d i s a WordPerfec t an d PD F fil e o f th e handou t a t th e industr y meeting . W e wil l hav e a focu s meetin g wit h th e industr y i n earl y Febr . t o discus s thei r issue s o n a draf t industr y ICR surve y w e pla n t o sen d ou t t o collec t MAC T data . Ho w an d ho w muc h d o yo u wan t t o kno w and participat e i n th e P-MACT ? ] wil l giv e yo u a cal l t o discuss ! Th e onl y othe r State/loca l contac t tha t Mar y Dougla s sen t m e wa s no t awar e h e wa s picke d and di d no t see m awar e MACT . I calle d an d lef t a messag e fo r Mar y t o hav e thi s straightene d out . Thank s fo r interest !

Stephe n Shed d U.S . EP A Offic e o f Ai r Qualit yPlannin g and Standard s Researc h Triangl e Park , N C 2771 1 voice : (919 ) 541-539 7 fax : (919 ) 541-024 6 E-mail : Shedd.Steve@EPAMAIL.EPA.GO V >> > "Hathaway , Donna " <donna_h@deq.state.la.us > 01/29/9 8 04:30pm>> > I contacte d Mar y Sulliva n Dougla s o n 1/15/9 7 t o infor mhe r tha t Louisian a i s intereste d i n participatin g i n thi s PMACT . Sh e sai d tha t sh e gav e m

y nam e t o you . I wa s wonderin g i f yo u coul d provid e m e wit h a n updat e o n thi s PMAC T development . Thanks , Donn a Hathawa y Louisian a Departmen t o f Environmenta l Qualit y ~? ^ \ 

### iCs^

Bernd Hanek e - 1 - - Fri , 3 0 Ja n 199 8 12:44:0 9P. 3

1/21/9 8 

## PRESUMPTIV

E MAC T FO R ORGANIC LIQUIDS DISTRIBUTION (NON-GASOLINE

) FACILITIES
JANUAR Y 21,199 8
FIRS T ROUNDTABL

E MEETING WIT H PROJEC T WOR

K TEA M (PRELIMINAR

Y INFORMATION )

Wast e an d Chemica l Processe s Grou p U.S . Environmenta l Protectio n Agenc y Researc h Triangl e Park , N C



### 2P. 4



## OVERVIE

W Standard s Developmen tProces s Presumptiv

e MAC T • MAC T • Projec

tSchedul e Affecte d Source s

• Definitio

n o f Sourc e Categor y • Industr

y Profil e Mode l Plants/Facilitie

s Emission s an d Control s
• HA P Emission

s • Contro

l Technique

s Curren tContro l Level s (MAC T Floors) Issues/Question s Nex tStep s
2



# 5P. 5



## STANDARD S DEVELOPMEN T

PROCES S

3 

## HP. 6



## PRESUMPTIV

E MAC T IS.. . [MAC T = maximu

m achievabl

e contro l technology

] A n estimat

e o f whatMAC T would be , base d on a revie w o f currently availabl e information Assists Stat

e an d local agencies in makin g case by-cas e MAC T determinations No ta regulatio n - offered only for guidanc e and informatio n A startin g pointfo r th e MAC T standar d developmentproces s

4 

## 6P. 7



## STATUTOR

Y REQUIREMENT S Promulgatio n of

nationa l emissio n standard s fo r hazardou s ai r pollutant s (NESHAP

) fo r liste d source categorie s require d unde r §112(d ) o f th e Clea n Ai r Act Organi c Liquid s Distributio n (Non-Gasoline ) i s a liste d majo r source categor y unde r §112(c ) Promulgatio n o

f standards i s require d by Novembe r 200 0



## ioP. 8



# STATUTOR

Y REQUIREMENTS (2 ) "Major Source " mean

s an y stationar

y sourc e o r group o f stationar y sources located withi n a contiguou s are

a an d unde r commo

n contro l tha t emit s o r ha s th e potentia

l t o emit , considerin g controls , i n th e aggregate , 1 0 ton s pe r yea r o f any hazardou s ai r pollutant(HAP ) or 2 5 ton s pe r yea r of an y combinatio n o

f HA P "Are a Source " mean

s an y stationar

y HAP sourc e thati s no ta major source "Ne w Source " mean

s a stationar

y source , th e constructio n o r reconstructio n o f whic h i s commenced afte

r the Administrato r firs tpropose s regulation s unde

r §11 2 establishin g a

n emissio n standard applicabl e to suc h source "Existin g Source " mean

s an y stationar

y sourc e othe r than a ne

w source
6P. 9



## STATUTOR

Y REQUIREMENT S (3 ) Minimu m leve l o f

standard s ("MAC T floor")

• Fo r existing sources, the standard shal l b e a t leas ta s stringen ta

s th e average emissio n limitatio n achieve d b y th e bes tperformin g 1 2 percentof

existin g sources , or , i n th e cas e of categorie s wit

h les s tha n 3 0 sources , th e average emissio n limitatio n achieve d b y th e bes tperformin g 5 sources

• Fo r new sources, th e standar d shal l b e a

tleas t a s stringenta

s th e emission contro l achieved in practice by th e bes tcontrolle d similar source

7P.1 0



# PROJEC T SCHEDUL

E (TENTATIV E DATES ) Even tDat e Kickof f Meeting s Septembe r 24-25,199 7 Plan tVisit s Dec . 1997 - Mar . 199 8 Initial Roundtabl e Januar y 21,199 8 (Wor k Team ) Second Roundtabl e Marc h 20,199 8 (discus s draf

tP-MACT) Thir d Roundtabl e Ma y 20,199 8 (review final P-MACT , i f needed ) Issu e P-MAC T Repor

tJun e 1998 Star tStandard s Jul y 199 8 DevelopmentProces s
8P.1 1



## AFFECTED SOURCE S

9 

# toP.1 2



## HO W I S TH E SOURC E CATEGOR Y

DEFINED ? Initia l Sourc e Categor y Description : Activitie s associate d wit h th e storag e an d distributio n o f organi c liquid s othe r tha n gasoline , a tsite s tha tserv e a s distributio n point s fro m whic h organi c liquid s ma y b e obtaine d fo r furthe r us e an d processing . Fo r oi l an d ga s production , include s onl y petroleu m facilitie s tha t handl e an d distribut e hydrocarbo n liquid s afte r th e poin to f custod y transfer 

## Facilit y Type s Ma y Include :

• Pipeline facilities

• Stand-alon

e terminals

• Collocate

d terminals (e.g. , associate d wit h refinerie

s o r chemica l plants )

• Compounding/packagin

g plant s

1 0P.1 3



## Organi c Liquid s Distributio n Facilitie s Industr

y CHEMICAL S Chemica l Manufacturin g (SOCMI )
Consume r (Retail ) 

### i Packaging/Distributio n Facility 

# i

Facilitie s usin g chemical s a s feedstocks
Consume r (Retail ) Packaging /

Distributio n Facility 

## PETROLEU M
Domesti c Oil/Ga s Productio n Foreig n Crud e Oi l

Petrochemica l Manufacturin g 

# J" 1 Petroleu m Refinin g

Consume r (Retail ) Packaging / Distributio n Facilit y

Intermediat e Storag e and/o rTransfe rFacilit y



### 1 1 

### \2>INDUSTR Y PROFILE-BASE D O

N SI C CODE S

< ^ Majo r Grou p

4 $

4 7

4 * Industry Grou p Numbe r

4610

4780

4920 SI C

Code 8

461 2 461 3 461 9

Q 478 9

492 2 492 3 492 4 Facilit y Type "

PIPELINE S Pipelines . Excep

t Natura l <3a s Pipelines, Except

Natural Gas Crud e Petroleu m Pipeline s Refine d Petroleu m Pipeline s Pipelines , No tElsewher e Classifie d

- - Tfaas|H>rtafion Service s . - / Miscellaneous Services Incidental to Transportation Transp . Services , No tElsewher e Classifie d Gas Production and

Distribution Natura l Gas Transmissio n an d Storag e Natural Gas Transmbsio n an d Distributio n Natural Ga s Distributio n Tota l No . o f Establishments 1 1

1,085

5 9

_

• 2,455

. 4,053

. Siz e Distributio n

b y No . o f Employees 1 * <5 0 >5 0 >ib o

- 95%

100 %

- 92%

' 86% - -

3%

. 5%

* 6% 2%

1%

8%

1 2492 5 Mixed , Manuf. , o r Liq . Pe tGa s Prod./Dist . INDUSTRY PROFILE-BASE D O N SI C CODE S (CONTINUED ) Majo r Grou p Industr y

Grou p Numbe r SI C

Code 8 Facility Type " Tota l No . o f Establishments " Siz e Distributio n

b y No . o f Employees b <5 0 >5 0 >10 0 STAND-ALONE TERMINAL S 42

4 4

5 1 >

4220

4490

5160
5170 422 6

449 1

516 9
517 1 517 2 Moto r Freigh tTransportatio n an< J Warehousin g Public Warehousing and Storage Special Warehousin g and Storage , No tElsewher e

Classifie d Wa*e*Tratt$ndrtat$oi) y Services Incidental

to WaterTransportation Marin e Carg o Handlin g Wbok^al e Trade-Nondurabl e Good s Chemicals and

Allied Products Chemical s an d Allie d Products , No tElsewher e

Classifie d Petroleum and

Petroleum Products Petroleu m Bul k Station s an d Terminal s Petroleu m & Petroleu m Products Wholesalers , excep tBul k Station s an

d Terminal s 1,54 7

- - 6,742 842 14,722 10,73 3 13,410 9,24 1 3,82 4 > f

' * 93 %
95% 78 % 97% 97 % 97% 97 % 97 % 4 %
2% 8 % 2% 2% 2% 3 % 2 % 3 %
3% 14 % 1% 1 % 1% <1 % 1 % 

### 1 3INDUSTR Y PROFILE-BASE D O

N SI C CODE S (CONTINUED )

L * Majo r Grou p Industr y

Grou p Numbe r SI C

Code 8 Facilit y Type " Tota l No . o f Establishments 1 1 Siz e Distributio n

b y No . o f Employees 5 <5 0 >5 0 >10 0 COMPOUNDIN G AND PACKAGIN G FACILITIE S 19

4 7 2950

2990

4780 •

" ' * 295 1 299 2 '
478 3 Petroleu

mft&fiaing mf&$#te$f^nslide s Asphalt Paving and

Roofing Materials Asphal tPavin g Mixture s an d Block s Miscellaneous Products of Petroleum and

Coal Lubricatin g Oil s and Grease s 1 Traa&portatio

n Service s Miscellaneous Services Incidental to Transportation Packin g and Cratin g « • _ •

_ • , _ • s* 1,324 1,08 1 448 37 3

" " . ' 2455 90%

96 % 81% 83 % 92% _ • • * s 6% 3 % 12% 10 %

- 5% , '

4% 1% 7% 7 % ' 2%

1 4INDUSTR Y PROFILE-BASE D O

N SI C CODE S (CONCLUDED ) Majo r Group Industr y

Grou p Numbe r SI C

Code 8 Facility Type 8 Tota l No . of Establishments5 Siz e Distributio n

b y No . o f Employees 5 <5 0 >5 0 >10 0 COLLOCATE D DISTRIBUTIO N FACILITIE S (e.g. , wit h chemical o r petrochemica l facilities ) 9 • 9

• 9

• 9 • 9 • 9 9 • 9

•

^ "Standard

Industrial

Classification Manual, 198 7 (Offic e o f Managemen tan d Budget ) h County Business Patterns, 199 5 (Burea u ofth e Census )

1 5P.1 8



## HO W I S TH E SOURC E CATEGOR

Y DEFINED ? (2 ) 

### Whic h processe s an

d equipmen

twould b e covered ?

• Al l HA P emissio n source s atregulate d facilitie s • Possibl e sources :

- Storag e tank s

- Liqui d transfe r

- truc k

- railca r

- pipelin e

- marin e vesse l (covere d b y subpartY )

- Equipmen tleak s

- Wastewate r collectio n and treatmen t 

### Whic h liquids ? Syntheti c organi c HA P chemical s Petrochemical s Crud e oil o r othe r unrefined petroleum liquid s Refine d petroleum (non-gasoline ) Othe r pur

e liquid s o r mixture s wit

h HAP conten t


### 1 6P.1 9



### TO P 2 0 ORGANI C HA P CHEMICAL S B Y VOLUM E (1993-96) 1 Chemica l Nam e Ethylen e dichlorid e MTB E Viny l chlorid e Methano l Styren e Ethy l benzen e Formaldehyd e Ethylen e oxid e p-Xylen e Ethylen e glyco l Cumene Pheno l 1,3-Butadien e Acrylonitril e Vinyl Acetate Benzen e Caprolacta

m Anilin e Methylen e chlorid e Phthali c anhydrid e Productio n (1 0 metri c tons ) 7. 2 6. 7 6. 5 5. 1 5. 0 5. 0 3. 7 3. 1 2. 8 2. 5 2. 4 1. 7 1. 6 1.4 1. 3 0. 9 0.7 0. 5 0. 5 0. 4 1 Chemica l & Engineerin g News , 1994-97 .



### 1 7P.2 0



## INDUSTR

Y PROFIL

E (2 ) Mode l Industr y

• Stand-Alon e Organi c Liqui d Facilitie s (i n ILT A Membership ) Primar y SIC codes : 4226 , 5169,517 1

• Primar y State s b y Tota l Storag e Capacity : Stat e Texas Louisian a Ne w Jerse y California Illinoi s Capacit

y (barrels) 55,582,44 0 29,383,59 4 29,252,303 24,329,88 8 9,881,57 7 Rang e i n numbe r o f

storag e tanks : 1 t o 42 0 + Percen tof Tota l 21 % 11 % 11 % 9 % 4 %
Rang e i n tota l storag e capacit y o f individua l facilities : 2,70 0 t o 12,500,000 barrel

s Mode s o f transportatio n

- marin e vesse l (tanker ship , barge

)

- tan k truc k

- railca r

- pipeline 1 8P.2 1



## INDUSTR

Y PROFILE (3 ) Collocate d Organi c Liqui d Facilitie s (e.g. , associate d wit h refinerie s o r chemica l plants ) SI C codes ? Pipelin e Facilitie s Compounding/Packagin g Facilitie s
<Data gatherin g ha s commenced . Al l o f thes e facilitie s potentiall y hav e fou r majo r emissio n sources :

• storag e • transfe r operation s • equipmen tleak s • wastewater >

1 9P.2 2



# EMISSIONS AN

D CONTROL

S

2 0 

## iXP.2 3



## EMISSIO N FACTOR

S Emission s Calculation s

- HA P conten t

- Models/method s fo r estimatin g emission s

- Parameters : volume , loadin g method , vapo r pressure , etc. ) 

### HA P Conten t

- pur e compoun d (100 % HAP )

- se e chemical s table , pag e 1 3

- alway s store d a t100 % strength ?

- mixture s (partia l HA P content )

- petroleu m liquid s

- als o dilute d pur e HA P chemicals ?

- nee d dat a (industr y survey? ) Organic Liquid

s wit h Partia l HA P Conten t Store d Liqui d Crud e oi l Gasolin e Aviatio n gasolin e Diese l fuel TV P

(70 °F ) 3- 4 4- 8 9 • ? Annua l Volum e

(Barrels/yr ) 9 • 9 • 9 • 9 • HA P Conten ti n Vapor s

Rang e 9 • 9 • 9 • 9 • Averag e

9 • 9 • 9 • 9 • 

### 21 2JLP.2 4

Store d Liqui d Jet kerosen e Othe r petroleu m mixture s Othe r chemica l mixture s Waste wate r Others ? TV P

(7 0 °F ) 0.0 1 9 •
9 •
9 • 9 • Annua

l Volum e (Barrels/yr) 9 • 9 •
9 •
9 • 9 • HA P Conten ti n Vapor s

Rang e 9 • 9 •
9 •
9 • 9 • Averag e

9 • 9 •
9 •
9 • 9 • Model s an d Method s

- Storag e tanks

- AP-42 , Section 7. 1 (TANKS 3 software )

- Liqui d transfe r

- AP-42 , Section 5.

2 (designe d for petroleu m products )

- Equipmen

tleaks

- SOCM I factor s

- refiner y factor s

- gasoline marketin

g facilit y factor s

- Wastewater ai r emission

s

- collection an

d treatmen

tsyste m mode l (Wate r 8 ) Facilit y Parameter s (mode l industry ) 2 2 

### 2-3P.2 5



### VAPO R PRESSURE S O F SELECTE D PETROCHEMICALS/PETROLEU M LIQUID S

Tru e Vapo r Pressur e at7 0 ° F Petrochemical/Liqui d Vapo r Pressur e (psia ) Hydroge n cyanid e 11.8 5 Ammoniu m hydroxid e (28.8 % solution ) 10.7 6 Diethy l ethe r 8.7 0 Gasoline , RV P 1 3 8. 3 Methylen e chlorid e 6.7 9 Gasoline , RVP 1 0 6. 2 Gasoline , RVP 7 4. 3 Diethylamin e 3.8 7 Crud e Oil , RVP 5 3. 4 Chloroform 3.1 9 Carbo n Tetrachlorid e 1.8 0 Je tNaphth a 1.6 Benzen e 1.5 Acetonitril e 1.4 Toluen e 0.4 3 Je tKerosen e 0.01 1 # 2 Fue l Oi l 0.00 9 # 6 Fue l Oi l 0.0000 6

2 3P.2 6



## CONTRO L TECHNIQUE S Storage Tanks • Route vapors t

o control device • Floatin g roof

seal s an d fittin g control s Liqui d Transfer/Loading • Vapo r balancin g • Rout e vapors t o control device • Vapor-tigh tvessel s (trucks , railcars ) EquipmentLeak

s • Leak detectio n an

d repai r progra

m • Visual inspections Wastewate r • Cove r (eliminat

e exposur e t o atmosphere ) • Treatment

- oil-wate r separation

- biologica

l treatmen

t

- filtratio n (sand , carbon , etc. )

2 4P.2 7



## CURREN T CONTROL LEVEL S Informatio n o n presen tlevel s o f contro l i s bein g obtaine d from :

• Federa l Rule s Refiner y NESHA P (subpar tCC ) Gasolin e Distribution NESHA P (subpar tR ) Oil/Natura

l Ga s Production/Transmission (subpart s HH , HHH

) Marin e Vesse

l Loadin g NESHA P (subpar tY ) Hazardou s Organic NESHA P (HON ) (subpart s F , G, H , I ) Miscellaneou s Organi

c NESHA P (MON ) Storag e Vesse

l NESHA P (subpar tWW ) Oil-Wate r Separator

s (subpar tW ) Benzene Storag

e an d Transfer

• NSPS rules (Storag

e Tanks-subpar tKb , etc. )

2 5P.2 8



# CURRENT CONTRO L LEVEL S

(2 ) Industr y Dat a

• Plantvisit

s

• Surve

y responses

- scree n al l facilities ?

- detaile d survey : • t o a limite d numbe r o f

facilities ? • facilit y types ? • type s o f liquid s surveyed ? • facilitie s covere d b y othe r MAC T rules ? • facilit y siz e ( < 50 % o f

10/2 5 tp y HA P criteria) ?

- surve y packagin g an d pipelin e facilitie s separately ?



### • Other information

2 6



# 1*P.2 9



# CURREN T CONTRO L LEVEL S

(3 ) State/Loca

l Rules (Examples )

• Storag e Vessel s - Californi a an d Illinoi s rule s amon g th e mos tstringen t

tanks > 19,80

0 gallons , > 1.

5 psia , o x tanks > 39,630 gallons , > 0. 5 psia : • floating roo

f or vapo r contro

l a t95 % b y weight an y capacity , > 1 1 psia : • pressur e tan k an d vapo r contro

l a t95 % by weigh t tank cleaning : • liqui d balancin

g t o < 0. 5 psia , o

r vapor control a

t 90 %

• Transfe r Operation s -Texas , Alaska , an d Californi a rule s amon g th e mos tstringen t • > 0. 5 psia : vapo r contro l a t90 % (Texas) • > 1. 5 psia : emissio

n limit= 0.08 lb/1,000 gallons (lOmg/liter

) (Alaska , California

)

• Wastewate r Operation s - Connecticut , Virginia , an d Hawai i rule s amon g th e mos tstringen t • > 20 0 gallon

s (VOC>1. 5 psia)/day : vapo r control a t95 % (Connecticut

, Virginia ) • > 20 0 gallon

s (VOC>0. 5 psia)/day : floating roo f tank (Hawaii

) 

### 27 2 ?P.3 0



## ISSUES/QUESTION S Whatfacilities/processe s shoul d b e included ? Whatar e th e emissio n source s atcompoundin g an d packagin g operations ? Impac to f th e othe r Federa

l ai r rule s

• D o the y adequately cover collocated distributio n emission sources ? • Whic h emission sources in presentl y regulated source categorie s shoul d b e considered ? 

## Impac to n o r fro m othe r media standard s Water (Benzene Wast

e NSPS? ) • Solid wast

e Others ?

2 8

0>° \P.3 1



### ISSUES/QUESTION S

(2 ) Are a Source s

• Som e ar e smal l businesse s (ho w many? )

• Mus tcove r are a source s i f the y presen t " a threa to f

advers e effect

s to huma n health o r th e environment " (§112(c)(3) )

• Nee d t o develo p simpl e mechanism s t o distinguis h the m from majo r source s (throughput , equipmen t size , etc. ) 

### Need additiona

l information t

o defin e industr y an d complet e industr y profile Completio n o f

dat a collectio n fo r MAC T floor determinatio n Othe r question s

2 9



# 3oP.3 2



## NEX T STEP S Finaliz e an

d mai l outindustr

y surve y (ICR) Additional sit

e visits Develo p draf

tP-MAC T Second Roundtabl e Meetin g (t o receive comment

s on an d discus s draf

tP-MACT ) Wor k wit h Tea m to gathe r additiona

l informatio n

3 0 1 \