# C ·

0

0 Heritage - 

## wrr, Inc. OHD980613541 Revision: 22 November 

### I 0, 2009 c) The Permittee m1l 

### also conduct an annual formal review of a generator's history ofMIHW shipments to the facility. The Permittee will provide additional training to generators/customers as necessary to ensure containers of MIHW are received in accordance with. facility guidelines and specific requirements listed with.in the Part B permit application and lbe facility's permit. d ) Containers of MlHW will not be opc:ned at the facility for any reason, including sampling or splitting into smaller charge sizes . Howeve<, containers being processed to the incinerator lbrough the Direct Tanker Bays or the Direct Drum Pump Out Station can be opened for that purpose. . Consequently, the gene<ator/customer must provide sufficient documentation, as well as certification, regarding the hazardous characteristics ofthe waste. e)
f) Fingerprint samples will not be collected from MIHW when the waste arrives at the facility. However, each container of MIHW will be monitored for radioactivity to ensure levels do not exceed bac kground concemations. Untreated MIHW 

### will not be placed into any tank system (Organic Was+.e Tank Fsrrn, Pump-Out Tanks, Bulk Solid Waste Tanks, Water Collection Tanks) or into any miscellaneous unit (filter press, shredder, extruder, pusher) at the facility. Trea1ment residual (slag) from the incinaBlion of MJHW that contains waste not combusted to ash or slag, 

### eoccept for metallic, glass, and ceramic items, may be placed in the Bulk Solid Waste Tanks for reprocessing.

C-96 

### JAN 1 

### 5 2010 

# OHIO EPA NEDO

V E S 01 6 399

# c

3 .



# 0 Heritage - WTI, Inc. OHD980613541 Revision : 24 April!, 20 10 Waste profile sheets (WPS) fur M1HW will be 

# prepared,**~ewed,** and approved 

### in aCcordance with the Wast e Characteris ti cs An. d Waste Analysis Plan (!W liP), section Clb(2)(iii) of the Part B Permit Application, ami the facility's permil a) The Permittee will review each waste profile for Mfr!W and may approve the waste, approve the waste with rooditions (eonditiooal approval) , or deny the waste for 'llll1Mgemen1 at the Facility. 

### b) The prohibitions listed in C-la(l) 

### forall incoming 

### waste also apply for MIHW. c)**Cootaine~s** of MIHW are restricted to non-metal rontaincrs such as plastic or fiber (cardboard). For specific waste streams that are packaged in an appropriate ron!aincr size and/or waste concentration, metal containers may be acceptable depending on facility review and approval of the WPS . d

) Copy-ovm of waste profile sheets are o. ot allowed for MIHW 

### streams, as stated in the WAP, section C.lb(2)(vi)

C-97

### t~P**R** 

### 1 fi 2010
VES0 16400

# c

0 Heritage - WTI, Inc . OHD980613541 Revision: 22 November 10,2009 e) MlliW will be managed as miscellaneo . us special waste category 3a and therefore pre-acceptance samples are not required, as stated i n the W Al', section Clb(2){ii) . f) The WPS and the individual waste labels will incl u de specific designations to indicate the waste is 

### MIHW, "high priority'' waste, and that the waste i s to be processed only through certain feed mechanisms. g) 

### MlliW may only be received as lab packs when a specific waste profile sheet is prepared for each**waste~.** h) 

### Reserved i) The Pennittee will include with the WPS; a signed certification from the generator/customer documenting the waste is mixed infectious and hazardous. The generator/customer must provide sufficient iofonoation to properly characterize the waste and apply hazardous waste codes. If appl icable, product insert sheets or material safety data sheets 

### will also be included in the waste profile package received and evaluated during the waste approval process . j ) In the WPS, The Pennittee will include a calcula tion of the metals content present in the waste itself , if applicable, to justify the application of characteristic hazardous waste codes for metals by the generator/customer . 

### JAN 1 5 2010 C-98 

# OHIO EPA NEOO

V ES01 6401

# 0 ..

• 1. .• Heritage - WTI, Inc. OHD980613S-41 Revision: 24 April!, 2010 I) 

### lf applicable, the WPS must also include a concentration range for metals 

### sucb as 

### cadmium, chromium, and/or lead used as a pigmenting agent in bags or other containers of 

### Mm:W . This concentration range would be used to calculate the metals 

### feed rate to the incineration system. 2

) The meW conceotratioo presen t in an y bags or containm cannot be included in the ca\culati. on of metals to justify the applicati . on of characteristic hazardous waste codes to the actual waste. k) The Permittt:c may require certain MIHW to 

### be packaged for 

### transport in sufficient amounts of ice aodlor to be shipped in refrigerated vehicles to ensure the waste is maintained 

### in a non-putrcsa:nt state. Waste suspected of being putrescent upon arrival will be processed immediately regardless of any staging and/or storage lime frames. 

### If necessary, waste may be placed on ice or 

### in a refrigerated vehicle · tmtil it 

### i:ao be treated, proceased, or rejected. Specific contain= may also be rejected by the Permittee, as necessary . 4. The Permittee will schedule MIHW for receipt at the 

### facilicy only when the incinerator is operational. a} The Permittt:c will 

### consider potential scheduling conflicts, operationiu capacity, pro«&Sing and/or open.ling conditions, and equipment availability when scbeduling 

### MIHW for receipt at the 

### facility.



### C-99

VES016402

# 0

0



# c Heritage · WTI, Inc. 

### OHD980613541

. Revision: 22 November I 0, 2009 b) Shipments of MIHW to 

### the facility will be**~scheduled** if the existing inventory of waste limits the capability of the facility for trumaging the waste in accordance with facility gUidelines and the requirements listed in the Part B permit application and the permit c) The Permittee will schedule MIHW shipments (individual loads) in amounts that can reasonably be incinerated within 48 hours of 

### receipt (signing ofthe manifest ). No more 

### than fo ur truckloads of MIHW will be scheduled - for receipt at the facility on any one day. d) All efforts will he made to immediately reschedule MIHW 

### from arriving at the facility 

### if an unplanned outage occurs. I f shipments inadvertently arrive during an outage, the waste may be staged and/or stored in designated areas in accordance with Sections C and D .of the Part B permit application, and in accordance with module ! (B) of the Ohio Hazardous Waste Facility Installation and Operation Pennit.

C-100 

### JAN 1 - 5 20 1 0 

# OHIO EPA NEDO
V ES01 640 3

# 0

0



# c e) . Heritage • WTI, Inc . OHD980613541 Revision : 27

. April15 , 20 1 1 Facility personnel who unload or process Mixed Infectious and Hazardous Waste (MlHW) will be 

### train.cd in accordance with Section 

### H. Perwme! Trainio& 

## PJon. of the 

### Part 

## B Permit, and any applicable SOPs 

### prior to managing any MIHW

. waste stteams. f) 

### If shipments of MlHW arrive as unscb.eduled waste, tb.e generator/customer wiD be contacted immediatel y by facility 

## persOnnel and additional training provided. 

### If unscheduled waste arrives nn a n:gular 

## basis, Ohio EPA may take lllllion to

. reduce 

### tb.c volume of this waste from the generator/customer 

### which may be received at the facility . g) Reserved



## 'JUN 16 2011 C-10 1 

# uoz g

# r Nnr

VES016404/'\ 

# ' .**"'-- '** 



# 0 Heritage- Wri, 

### Inc. OHD98061354l Revision: 22 November 10, 2009 

### 5. MIHW will be evaluated upon arrival at the facility f or conformity with packaging, concentration, size, quantity, and/or scheduling requirements to ensure safe management and incineration. a) ,Non-conforming waste that cannot be managed safely will be placed in a secure 

### area until it 

### can be rejected back to the generator/customer or 

### sent to an alternate facility.

. 1) The waste must be sent off - site within 14 days of receipt, unless an extension is requested of, and granted by, Ohio EPA (see #9 of this section). 2) Ifnecessary , the nonconforming, waste will be over packed, pla ced on ice, and/or in a refrigerated vehicle, as necessary, while awaiting final . disposition. b) Non-conforming waste that meets other criteria for acceptabilizy and/or can be managed safely may remain on-site for incineration or be transferred to an**alt~te** facility.
c) The Pennittee will vetbally notify Ohio EPA of any major non-conformities disco:Vered as soon as p ossible. The tracking system docamentation described in #6 of Ibis document will be provided to Ohio EPA upon request.

C-102 

### J AN 1 5 

### 201 0 

# OHIO EPA NEDO VES016405

# 0

· 0 

### \
. .. 

### 6. Heritage - 

## wn , Inc. OHD98061354 1 Revision : 22 November 1 0,2009 d) The Ohio EPA may 

### require the Permittee to temporarily restrict or disallow receipt of 

### MrnW from my specific customer who demonstrates a coalinued history of non - confonning containers or containeJS which result in an injury or contingen cy plan activation. e) The Permittee will contact specific generators/customers to review the guidelines with them as necessary and/or . discontinue receiving MIHW from specific generators/cu.'<lomeJS if non-conforming or unscheduled waste is received on a regular basis from that generator. The Peonittee will develop and utilize a tracking system for MIHW which will be provided to Ohio EPA fo r review on a regular basis 

### and upon request at any time . a) The tracking system 

### will include: container receipt date, container id number, a description of 

### e.ny non-conforming waste, the date 

### any nonconforming containers were discovered, and a description of the resolution. The description of the resol ution will include the date the nonconfonnity was resolved, the 

### final disposition of the container including a date, the contact person' s name, and how the situation was resolved. b) After each 'shipment of MIHW, the Peanitt ee will perform a search on the tracking system to ensure all containers have·becn incinerated, rejected off-s i t

e, 8ndlor sent to an alternate facility , Any discrepancies will be documented on the tracking systtm and provided to Ohio EPA.

C-103 

### JAN 1 . 5 2010 

# OH IOEP A N EDO
VES016406

# c



# c

c Heritage - WTI, Inc. 

### OHD980613541 Revision: 22 November 10, 2009 7. MIHW will only be processed, staged, and/or stored: a) In specific areas that are under roofor canopy to protect contaicers from 

### weather; b) In areas restricted to authorized personnel by posting of a sufficient nUIJlbcr of precautionary signs and through required**wast~specific** training ; c) In areas tba1 meet secondary containment standards, have automatic fire detection and suppression syStems, and have easy access to appropriate spill clean-up kits; d) In areas where sump pumps are set to a manual setting during the processing of 

### MJHW, to prevent waste being automatically pumped 

### from sumps to water collection tanks 

### if any 

### spills OCCtJr

C-104 

## JAN 1 5 2010 

# OHIO EPA NEDO

VES01 640 7

# c

0

0 Heritage- WTI, 

### IDe. OHD980613541 Revision: 22 

### NovcmbC<C 10, 2009 

### 8. The 

### Permittee will manage 

### MJHW only in the specific areas designated in the 

### Part B penni! application and the facility's Pennit, with 

### certain restrictions. The Pennittee wj)] make all attempts to incinerate "high priority" waste within 48 hours of receipt (manifest is signed) at the facility. Waste 

### will be labeled as "high priority" while on-site, and prior to, and during pxooessing. On occasion, and with sufficient j u stification, Ohio EPA may allow additional time fur managing this waste. The following provide time limitations applied to the management of MIHW at the facility : a) Truck Holding and Sampling Area: I)**Tank:C~CS** may be staged for no lO<Jget than 24 hours p rior to beginniog to prooess tankers through a direct tanker bay (east bay / soUih bay). 2) With exception, in a=rdance with SOPs, tankers may be s t aged for up to 14 days in this location


## . .

C-105 

### JAN 

## 1.5 2010 

# OHIO EPA NEDO
VES016408

# C·

0



# c b) Container Processing Building (CPD): Heritage- 

## wn, Inc. OHD980613S41 Revision: 22 November I 0, 2009
I) Container Receiving Area (unloadiJ!g doclcS and receiving conveyor) A) Containers may be unloaded and may be staged on the receiving conveyor, for no longer than 24 bows total, while they are evaluated, labeled, weighed, illld entered iJ!to the automated waste tracking systan. 

### B) With exception, in accordance with 

### SOPs, containers may be staged at the unloading dock s in a truck Of trai ler, refrigerated ifnecessary, for up to 14 days. C) With exception, in accordance 

### with 

### SOPs, bucket boist hoppers filled with in

tact, individual containers of MIHW may be staged at the unloading docks in a truck or trailer, refrigerated if necessary, for up 

### to 14 days. 2) Splitti!lg Station: A) .MIHW will not be processed, staged and/or stored at this location.

C- 106 

### JAN 1 5 

### 2010 

# OHIO EPA NEDO
VES016409

# 0 Heritage- WTI, Inc. OHD980613541 

### Revision: 

### 22 November I 0, 2009 , . 3) Container Pump-Out Stations and Pump-Out Tanks, PT-1 through PT-5: A) MIHW will 

### not be placed into the pUmp-out tanks . M1HW 

### will not be processed, staged, and/or stored at this 

### location. · 4) Extruder and 

### Pump-Out Tank, PT -6: A) MIHW 

### will not be intentionally placed into 

### any miscellaneous unit such as 

### the extruder. MIHW will not be processed, 

### staged , and/or stored at this location. 5) Building

### A (Drum Warehouse 

### ofthe CPB): A) With 

### exception, in accordance with SOPs, containers 

### of M1HW 

### may be stored for up to 

### 14 days in 

### a designated area.ofthedrum warehouse .

C-107 

### JAN 15 2010 

# OHIO EP ANEDO

V ES01 6 4 10

# 0



# c 6) Queuing Lanes: Herjtage - W fl , Inc. OH09806l354 J Revision: 22 Novembeo- 10,2009

A) Containers of M1HW will be i ncinera t ed within 48 hours of receipt (signing of the manifest) at the facility. Containers of 

### MIHW may be staged in the queuing lanes of the CPB while the incinerator i s operational. Timelincs for removing containers in the event of ·

### an unplanned outage are the same as all other waste. Containers must be removed from the feed conveyor caniages within 24 hours of initiat ing shutdown procedures during an outage and may be loaded on the feed conveyor can:iages up to 48 hours prior 

### to start-up 

### after an outage. 7) North wall of CPB: A) Containers ofMIHW may .be staged along the west portion of the North Wall of the CPB for processing through certain feed mechanisms for 'no longer than 48 hours from the time the containers are received (manifest is signed) at the facility. B) Bucket hoist hoppers filled with intact, individual containers of MIHW may be staged along the west portion of the North Wall of the CPB for processing through the bucket hoist for no longer than 48 hours 

### from the time the individual cont&ners are received (manifest is signed) at the facility.



### JAN 15 2010 C-108 

# OHIO EPA NEDO

VES016411

# C·

0 c)



# 0 Heritage- WTI, 

### Inc. O

HD980613541

Revis ion: 

### 22 November 

### I0, 2009 C) With exception, in 

### accordance with SOPs, bucket hoist hoppe;rs filled with intact, individual containers of MIHW 

### may be staged on the west side of 

## . . the North Wall of the CPB for up to 1 4 days. 

### D) With exception, in accordance with SOPs, containers of 

### M1HW 

### may be staged along the west side ofthe North Wal l of the CPB for up to 14 days, as long as the incinerator is operational . If the incinerator is not o

perational, containers of MIHW will be placed into designated storage 

### areas in 

### accordance with the timelines · in Section 

### D, D - 2d(9). Incinerator Feed Building: I) Bulle Solid Waste Storage Tanks A) Untreated M1HW will not be. placed into the Bulk Solid Waste Tanks at the Facility. Treatment residual (slag) 

### from the incineration ofMII:IW that contains waste not combusted to ash or slag, except for metallic, glass, 

### and ceramic iti:ms, may be P.iaced in the Bulle Solid Waste Tanks for reprocessing .

C-109 

### JAN 15 2010 

# OHIO EPA NEDO VE$016412

# 0



# c Rentage - WTI, 

### Inc . OH0980613541 Revision: 22 November 1 0,2009 2) Canopied containment area in front of the Bulk Solid Waste Storage Tanks. A) Bucket hoist hoppers can be filled with 

### intact, individua\ ' containers of MIHW under the '?'l'lop i ed contaiwnent area in front of the Bulk Solid Waste Storage Tanks. B) A spill kit must be easily accessible when MIHW is being processed into bucket hoist hoppers. 3) Direct Organic Tanker South Bay**~)** Tankers may be staged for no longer than 24 hours prior to beginnin g to process tankers through a 

### direct tanker bay (east bay/south bay). B) With exception, in accordance with SOPs, tank.ers of MIHW may be staged for up to 14 days in direct organic tanker south bay.

C- 110 

### JAN 1 5 2010 

# OHIO EPA NEOO
V ES01641 3

# c

c 4) Direct 

### Drum Pump-Out Stations Heritage • W1l, Inc. 

### OHD98061354l Revision: 22 

### N9vember 10,**~Ob9**
A) Containers of MlHW to 

## be pumped out may be staged al; the direct drum pump-out swions on the south side of the Incinerator Feed Building, 

### for no longer than 24 hours prior to beginning to 

### process the containcts. B) Only one pallet will be slaged 

### at each station, and no additional pallets of MIHW will he staged in the Incinerator Feed Building. C) Individual containers that held MIHW shall be incinerated after t he contents are removed or the containers 

### sball be decontaminated in accordance with SOPs prior to reuse, r ecycling, or sending off-site.



### JAN 

## t.5 2010 C-111 

# OH IO EPA NEDO

VES 0 16414

# 0



# c 5) Buc kel Hoist (Skip Hoist) Heritage - WTl, Inc. bHD980613S41 Revision: 22 

### November 10, 2009
A) Bucket hoist hoppers filled with intact individual containers of MIHW may be staged for oo looga 

### than 48 ho= 

### from the tim . e the individual containers are received at the facility. The 48- bou:r period includes all hopper filliDg and staging times until the filled hopper is incinerated. See section D-2e( 4) B) Bucket hoist hoppers of MlHW can only be filled (processed) inside the CPB, or under the canopied containment area in front of the Bulle Solid W aste Storage Tanks. Hoppers 

### shall be clearly marlccd as "b.igh priority" waste and/or MIHW. C) The Permittee shall fill only the n=bcf of hoppers that can reasonably be processed through the bucket hoist while adhet"ing to S1aging and/or storage limitations. D) Bucket hoist hoppers filled with MIHW may be staged on the bucket hoist containment platfoon for up to 24 ho=.

C-112 

### JAN 1 5 2010 

# OHIO EP ANEDO ·
VES016415Heritage- WTI, 

### Inc . OHD98061354l Revisi<?n: 22 November 10,2009 E) Bucket hoist hoppers :filled with MIHW cannot be staged near the 

### bucket hoist loading platform for 

### any reason. F) With 

### exception, in 

### accordanoe with SOPs, bucket hoist hoppm filled with intact, individual containers of MIHW may be suged at 

### the unloading 

### docks in a truclc or trailer, refrigerated 

### if necessary, for up to 14 da ys . G) With exception, in accordance with SOPs, bucket hoist boppm filled with intact, individual 

### containers of MIHW may be staged on the west side of the North Wall ofthe CPB for up to 1 4 days. H) A 

### SPill kit mu.'lt be 

### ea.my =llle wbeo MIHW is beirig processed into bucket hoist hoppers . d) Organic Tanker Ullload Stations : l) Direct Organic Tanker East (Bay #I) A) :rankers p!ay be staged for no l onger than 24 hours prior to beginning to process through a direct tanker bay (east bay/south bay).



### 'JAN 1 5 7 01!> C-11 3 

# OHIO EPA NEDO

VES016416e) 2) Organic Tanker Unload Stations (Bays #2 and #3) Heritage - WI'l, Inc . 

### OHD98 061 3 S41 Revisi on : 22 November I0 , 2009
A) Tankers may be staged for no longer than 24 hours prior to b eginning to 

### process tankCJS through a direct tanke.- bay (east bay / souih ba y). 3 ) With exception, in accordance with SO'Ps, tanken of MlHW may be staged for up to 14 days in 

### bays #I, #2, andlor#3 . Organic Waste Tank.FI!Illl: 1) MlHW will not be placed 

### into the organic waste tank farm at the facility . M1HW will not be processed, staged,**an~or** stored at 

### this location. Building B (Extt:mal Truclc Wash ): A) MIHW will not be

### procesSed, staged, and/or stored at 

### this locati o n.



### JAN 1 . 5 

### 2010 C-114 

# OHIO EPANEOO

VES016417g) Building C (Lab Pack Building): Heritage- WTI, Inc . OHD980613541 Revision: 22 

### November 10, 2009
1) Conlain..s ·may be unloaded and/or staged, only when received as Jab packs with specific waste profile sheets , for no long er than 48 hours from the time the lab packs are received (manifest is signed) at the facility. 2) With exception, in accordance with SOPs, containers ofMIHW may be staged in the lab paclc building fur up to 14 days, only when 1\!Cdved as lab paclcs**~th** specific waste profile sheets for each waste stream . h) . Container Holding Building (Slag Canopy) : 1) MIHW will not be processed, staged, and/or stored at this location.



### JAN 1 5 2010 C-115 

# OHIO EPA NEDO

VES01641 8

## ·.



# C · Heritage • WTI, Inc. OHD9 80613S41 Revision: 22 November 10,2009 

### 9. If unforeseen c irCIIJllStonces occur that would cause The Permittee to req u est that MIHW remain on- site longer 

### !ban 14 days, Ohio EPA may allow additional time for processing this waste with sufficient justification. a) At minimum, The Peanittee will notify Ohio EPA pri or to the end of the 14-da y period, 

### of the need to 

### stage and/or**s~** MIHW longer thaD 14 days. 

### The notification will include I ) the reason why the waste cannot be treated within 14 days; 2) the number of containers; 3 } the volume of**was~ ;**  4) the anticipated le.Jgth of time containers will be stored; 5) the location of the waste; and 6) any other information**n:qucs~** by Ohio 

### EPA. b) MIHW can only be processed, staged, and or stored in permitted areas with the concurrence of the Ohio EPA. c) · The Permittee will also notify the Columbiana County Health Department and the City of East Liverpool Hea lth D epartment ofthe additional time nccessBI)' for this waste 

### to nmain on-site. d) The Permittee will continue to inspect and monitor the MIHW as requi red in the Part B permit application and the facility's Pcanit, until such time as tho waste is incinerated, rejected, or shipped 

### to an alternate facility. e) The Permittee will pr ovide Ohio EPA with documentation of the final disposi tion of Ibis waste on a regular basis and/or upon request.



### JAN 

### l 5 2010 C- 116 

# OHIO EPA NEDO

VES016419

# 0

10.



# 0



# c Heritage· WTI , Inc. OHD98061354 1 ;Revision: 

### 27 Aprill5 , 201 I 

### Inspections are required for MIHW while the 

### waste is being 

### managed (accepted. processed, staged, stmed, 

### aDd/or illcincraled ) at the facili ty . See 

### F-6, Attacbment F.l, a.od Attachment 1'.3 of Section F of the Part B permit 

### application for information, inspection liequen.cies , and examples ofinspection 

### fotmS Cor 

### this waste. 

### a) Each 

### contailler of MIHW that 

### is being 

### processed, staged. and/or stored 

### at lh e facility 

### m ust be 

### inspected at 

### least once per 

### day.

b) 

### I) Inspection panmeters will 

### include, at millirnum: 

### approprlalt aDd adequate 

### labels, compatibility issues, and ge:ceral containeo- 

### condition. The Permitttc will inspect lhe1reattoentr:esidual (slag) 

### when containers o f MlHW 8l"C beiog 

### incinerated to ensute 

### the 

### waste is completely combusted IIDCI is oo longer recognizable. I) Th e P ermittee will iDspect, 

### at miDimum, 

### once every two bolllll 

### for the entire time that 

### c:ontaillers ofMIHW are beiog incinerated 

### and will :make 

### a final 

### inspection of the s)Bg between one to two 

### hours after the last 

### container ofMIHW bas been inciDe:rated.

C-117 . 1 

### JIJN 1 

### 5 ZDII ·

VES016420

# 0


# •

c) Heritage· WTI, Inc. OHD980613S4l Revision: 22 November 

### I0, 2009 2) Based upon inspection or other means, if MIHW is detennined to be incom pl ete ly combusted, that waste must either be removed from the slag and placed in a collection container !hat is covered and labeled or th e entire roll-off box oftreatment residuals may be dumped in the bulk solid waste smrage tanh for rCprocessing. When the collection container is 6lled, and/or the incineration of the waste is 

### finished, the collection container will be weighed and identified with a**~tainer** munber. The container of incompletely combusted material will be re-incinerated or m

ay be sent off-site to an alternate treatment facility . This informatio n will be documented on the residual inspection follll for 

### lvDR'W. 3) If necessary, and in accordan ce with SOPs, the Permittee will take additional measures with the incineration of MIBW 

### to ensure complete combustion, such as res1ricting the 

### feed rate or decreasing the lciln rotatio n for additiona1 retention time. Inspection records associated with the management ofMIHW will be maintained by the Permittee and provided 

### to Ohio BPA on a ro uline basis and upon request



### JAN 1 - 5 2010 <:-118 

# OHIO EPA NEDO

VES016421

# 0 Heritage • WTI, Inc. OHD98061354l Revision: 22 November 10,2009 d) Additional inspections of emergency equipment, spill kits, and response equipment 

### will be conducted in accordance with the frequency schedule, the 

### requirements in Section F of 

### the Part B permit application, 

### and any procedures developed 

### by the Permittee and/or required by·Ohio EPA. 11. Addi tional pJCCalltions are required for MIHW while the waste is on·sile. See Section G of the Part B permit application for a description of emergency equipment, spill kits, and**~onse** procedun:s. a) Any**wastcwate~:,** debris, or other material resulting from a release ofMIHW shall be managed as MIHW. The spilled waste, wastewater, debris, or otb . er matmal will be collected, placed 

### in a container, and 

### incinerated or treated 

### by aoother approved treatment method. b) Spillldts for MlliW will contain the following items, 81 minimum: absorbent materials, a US EPA certified disinfectant or the ingredients for a minimum 10% househol d bleach solution. Spill 

### kits will be stationed and maintained at**des~gnated** locations throughout buildings and 

### in areas w here MIHW will be unloaded, pnx:essed, staged, and/or s tored.



### JAN 1 5 2010**~119** 

# OHIO 

# EPA NEDO

VES016422Heritage - WTI,lnc. OHD980613541 Revision: 22 November I0, 2009 c) Decontamination procedures wil l be docwnen ted in SOPs in the event it is necessary to clean equipment or tools used d uring the**proce.~i.ng** and/or spill cleanup of MIHW . Equipment mdlor tools shall 

### be either oontainerizcd for incineration, or decontaminated in accordance with applicable SOPs and regulations . d) Ifa !0% household bleacb solution is to be used for clean-up, it will be prepared within 30 minutes ofuse and applied for the necessary contact time. e) The Permittee will initiate a contingency plan activation for any release of 55 gallons or greater involving MIHW. f) A spill kit will be easily accessible when processing MIHW. 12 . Training is required for the Permittee to 

### be properly prepared for the managemc:nt and/or incinetalion ofMIHW wlnlc the waste is at the Facility. a) Training will be in aooordance with Section H of the Part B permit application. Instructions for managing MIHW will be given to esseotial personnel prior to receipt of the waste at the facility and as necessary to ensure safe mnnagemcnt of this w aste. b) Annual training will**in~lude** a review of all applicable SOPs.

C-120 

### JAN 

## 1 5 2010 

# OHIO EPA NEOO
VES016423

# · C



# c

c C-le(SJ 

# .. . Heritage Thennol Suvices, Inc. OHD980613541 Revision: 31 Sepu:mber 18, 2014 Speclflc Procedures for Acc:eplance 

### ot Compnssed Gases and Gas Mixtures (Gasa) A. 'The Permilu:e Is IN i horiud 10 IICCepl and treat, througll lhe lnci-..lion system, specl6c COJ1lprwed 

### ps lind ps mixcun:s (gases). Please refer to Table C-la(2)(i) for approved ccmpressed gas and aas mlxwrea. B. Cbanocleristic:s 

## or !he

## oases: o. The cbonlc:leristic:s or lhe compressed gJiiel cunendy 3CCepled for treaunen1 01 lhe fucitily are noo·IIDmmoble, and non-bazMdous. and ore non-<Jdoriferous. The gliSCS contain halogens such as fluoride and chloride, bl.ll tbe**Incinera~** Sysee.m has demonmated an aceeptoble removal efficiency ofacid gases from lhe flue combustlon 81'S· b. Average IllS density of eacb compresstd gDS mixture wiU be similar to that of tbe**~:as** mixtun uud ia the accic!ent analysis entitled 'Assessmen1 ofPoteatiol Off-81«: lmpi>CI of Accidental**~leases** of CornpJ=cd Oas M i xwre allhe East Uverpool Facilit y', p.epared by rr Corpotation , Monroeville. PA. and**~ted** as Project N o. &34706, Mareb 2001. c. The Pmnittee n:questlld aud!Orizallon to occept ood treat a new COICgOry of**wa.~,** • specific**~d** gas waste stream, in 2002. As port of lhe Class 38 pennit modificollon process. the Pennince contracu:d 10 hnve an occiden1 1111.alysis conducted 1o assess lhe potential offsite impiiCt should " rdease occur . Two risla were identified ossocloted wilh occeplillg, processing, and treating the compressed ps waste stream, aspbyxiJIIioo and IOxlc:ity. These risks**we~e** lldd=sed 

### liuough lhe inclusion of sevml conditions and ruulctions in lhe pennit, S\ld\ as mainlllining adequa&e ventilation Sid isolating the ofT-loading 

### process by ensurin& thAt all doo<s in E-Bay are closed. Otber Sll!ety rneasllteS include inslllllalioo ond operalioo ofMygen (0!) sellSOI(s) and visual monltorine durin& the off-loading process.

C-121

VES0 1 64 2 4

# c Heritage· WTI , 

### Inc. OHD98061354 1 Revision: 22 November 10,2009 d If the Permittee requests to add additional compressed gases to their permit, the Permittee shall evaluate the specific gas waste stream to ensure it does not pose risks 

### thai were not addressed dwing the 2002 accident analysis. Ifthe new gaseous waste stream does n ot pose any additional risks, the Permittee may add the oompressed gas to the permit following the**clas.~** l A permit modification process . Ifthe new gaseous waste stream does pose additional risk(s), the Permittee may add the compressed gas to the permit following the class 2 permit modification process. Examples of the criU:ria to be used to evaluate a new gas or gas ntixture inc lude, but are not limited to : (1) hazardous versus non-hazardous; (2) vapor pressure; (3) vapor density; (4) e:.:posure guidelines ; (S) solubility in water; (6) composition; and (7) flammability.
C-2f Additional Requiremen ts for Ignitable, R eactive or In compati b le Wast es OAC Rules 374S..54-1 3 (B)(6),**74~54-1 7**  Asdisa!Ssed in section C-1 c(2) , reactivity and compallbility tests are perfonned as 

### part o f the preacreptance analyses phase and as 

### part of fingerprint analysis. Companbility tests are conducted on bulk solids . Compatibility testing is also conducted on bulk liquids, slndges, and slurry waste prior to transfer of waste into a tank. In addition to lhese tests, facility management may decide to perrOlDI additional analysis when preparing to process 

## wasteS . Opeil!lioos at the facility , for which current and periodic sampling and 

### analyses may be important, include the following : • Storage I B lending • Treannen t (i.e. , incineration) The analytical procedures for each ofthese are described separately in. the following sections.

C-122 

### JAN 15 

### 2010 

# OHIO EPA NEDO

VES016425

# 0 C-2f( l ) Stora ge H eritage - WTI, Inc.

OHD980613541 Revisi on: 22 November I 0, 2009
The Permittee stores waste in containers and in 

### tanks. The·two systems are managed differently

. and 

### are discussed in the two 

### separate sections below.

C-2f(l ) (i ) Wast e in Containers Based on the initial hazatd determination and the analysis ofthe waste, the containerized waste will be segregated 

### with respect to ignitability and compatibility. . The US DOT 

### Hazardous Precedence List (49 CPR Part 173.2 and 177.848) shall be employed for the initial determination of compatibility. 1bis deteanination may also be made by review of the data 

### from the WPS, knowledg e of the waste source, and/or any supplemental analyses requested by the facility management. The following table l ists hazard classes with incompau'ble 

### hazard cl asses for wastes that are stored at the facility . These materials will be segregated from incompatible materials by storage in separate containment areas. T able C-2f(l ) - Incomp atible H azard Clas s T able H azard Class Incompatible . H azard Class es Flammable Liquid Oxid izer, Organic Peroxide Flammable Solid Corrosive, Oxidizer Oxidizer or Organic Peroxide Corrosive, Flammable Liquids, Flammable Solids Corrosive (acids) Oxidizer, Organic 

### Peroxide, Flammab l e Solids, Corros i v e (bases)

C- 1 23 

### JAN 15 2 0

10 

# OHIO EP A NEDO
V E S016 426

# c

0

0 Heritage - WTI, Inc. 

### OHD9 8 0613541 Revision: 22 November 

### 10, 2009 In some instances, containers of waste witb free liquids 

### are treated solely to ab sorb the free liquids and reduce the instantaneous BTU release in the incinerator. The waste will . be mixed with a proper absorbent (such as clay, cellulose or absorbent polymer) until 

### a mixture is produced that contains no free liquids. Reactive materials and other restricted wastes 'vill not be candidates for this process. Absorbents will be added with ventilation from the vapor recov ery system. After the ab sorbent has been added, these mixtures may b e fed directly to the incinerator. Section 0.1of the Part B 

### pemUt application presents · delllils regarding the container storage area. Section F-5 of the Part B permit application provides additional information regarding filcility pnctices to preveot reaction of ignitable, reactive, and incompatible wastes.. C ·Zf(l)(il) Waste in Tanks Prior to transferring any waslt into a storage tank, the compatibili ty of the waste with the material in the tank and the tank materials of construction will be determined by the facllity management, by first reviewing !he pre·acceptance evaluation and using the waste compatibility test results conducted during the iingelprint analyses. The Permittee will use differential scanning calorimetry (DSC) or an equivalent method/tes t to examine the possibility of delayed reactions, which may occur during·storage. The parameters that are used to determine compatibility are as fo ll ows: Stmti fica tion - The general miscibility of the materials will be examined. Ifstratification would appear to create a p roblem, the materials will not be combined. Heat Oenecation • Materials that, upon mixing, generate large amounts of heat or undergo exothermic reaction, 

### will not be combined.

C-124 

### · JAN 

## 1.5 2010 

# OH\0 EPA NEDO

VES016427('\



## . \..... 

## . ./



# C · Heritage • WTI, 

### Inc . OHD980613541 Revision: 22 November 10, 2009 C'.as Eyo!ution - Materials that, upon mixing, liberate flammable, explosive, or toxic vapors, fumes, or 

### mists, will not be combined. l !ndesjrab le Reactions - Materials that, upon mixing, result in th e formation of a precipitate or in the solidification or gelling ofthe mixture, will not be combined. Whea a waste .shipment is to be transferred into a tank, a representative sample will be taken from the tank into which the waste is to be pumped and the waste to be blended. Compatibitity · testing will be performed. Compatibility chardcteristics listed above will be examined. If the

mixture fails any of the compatibility tests, the waste will not be pumped into the receiving tank. If !he waste is determined to be incompatible" with the then -presen t tank contents, the procedure 

### will be repeated as necessary until a compatible tank is found. If a compabllle tank 

### ill not found, the -waste will be fed directly into the incinerator from its container or it will be re1llmed to the generator. Section D-2 of the Part B permit applieation presents details regarding the waste stored in 

### tanks. Section F-

### 5 of the Part B permit application provides ad ditional information regarding facility practices to prevent reaetion ofignitable , reactive and incompatible wastes.



### JAN 15 2010 C-125 

# OHIO EP ANEDO

V ES01 642 8

# 0



# c C..zl{l) Heri138C Tbennal Suvices, lne. OHD980613541 Revision: 3 I September 1 8 .201 4

In this proeess, liqui d, semi-solid, :tnd solid**w~** types ns w.:ll as approved compressed gases (see Table C" lll(2)(i) for approved compresse! goses) lilt destroyed by hil!h temperature thermal oltldntion. The waste**~~~teams n~sullln** **g** from thls pi'OOCS$ include**co~busllon** goses lbot are scrubbed to remove acid gases. particulates, :tnd treotmentrcsidues (sec section C-7d(4)) thai are further truted. ifnecessary, and/or londfiUed. The primary 

### purpose of pre-ueatmenl and)'Se$ for the illcioerllllon process is to e:uegorize wastes to ens ure lbot facUlty pennit and opentiooal constraints os required by 40 CFR 264.341 ( b) ond OAC Rule 374S-S7-41(8 ) m met. Wostes sclteduled f or incineration will be cvnlunted 1 0 ensure c:ompotiblllty with syStem design and operating paramecers. The minimum 

### par.uneters that 

### are used to determine optimum blend charlcleristies arc : • Heat Value - Htot value is measured to assiSI ill control of the f eed rates of waste fed intO the rolary kiln. The**~mum** be.1l value which can be burned per hour is C$1ablished in the operating penni!.

C·l26

VES016429

# 0



# c Heritage- WTI, Inc. OHD980613541 Revision: 22 November 10,2009 C-3 WASTE ANAI.VSIS RF.QJITBEMENTS Pf;RTA!NJNG TO UNp DTSPOS,\1. R P:.STRicrJONS OAC Rale 3745-2 70, 3745-54 C-3 a AppUcabWty ofTreatment Standards OAC Rules 3745-276-40 throu11b. 

### 49 The treatimDt 

### residues genaated 

### by the Permittee 

### will meet 

### the tieafment s!andanls UDder 40 CFR 268.40 aDd OAC 3 745-27().40 through OAC 3 745-270-49 prior to land disposal. C-3a(l) Wask Characterization OAC 374 5-54-13 

### Any combination ofgenerator knowledge and analytical testing may be used to cb.aracteriz.e the treatment residue for land disposal restriction requirements as discussed throughout section C.. Ib. Supporting information used to characterize waste via generator know ledge is maintained in the facility's operating record. This supporting infonnation may be obtained from itans such as the WPS, pre-acceplancc 

### 811.31yses, manife<t, land disposal restriction form, finge.pr:int analyses, and supplemental analyses. Prior to acceptance of a waste for treatment at the facility, the generator must complete a WPS as described in section C. lb(IXi). The WPS for each waste stream is assigned a unique waste profile number. Information from the WPS (e.g., EPA hazardous waste codes , applicable trcall:nenl standards, e lemental concentration ranges, etc.) is entered into the ARTS (Automated Realtime Tracking System or any successor) 

### database that 

### tracks pertinent information regarding an approved waste streatn. Therefore, 

### all waste codes associated with a waste stream are dcx:umented in the ARTS computer database and correlated with the wask profile number given to each waste stream.

C.t27 

### JAN 

### 1 5 2010 

# OHIO EPA NEDO
VES016430

# c

c Heritage • WTI, Inc. OHD980613541 Revision: 22 November .lO, 2009 As waste is received, it is logged into the database. Supporting infoonation, as noted above, (i.e., manifest data, fingttprint 

### analyses, WPS infoonation, etc.) is correlated with the waste stream. The ARTS database not only tracks pertinent waste stream information, bnt also tracks each movement of the waste at th e facility. Average retention times (i.e., the amount of time the waste may have been in the incineration process) are used to assign the waste codes that ha ve been intr oduced into the kiln and could now b e components of the ash or slag (i.e., treatment residue). These waste cod es are assigned to the treatment residue for determining land disposal restriction analysis, and notification and cerlification requirements. Incinerator ash is collected in· 

### pneumatic bullc 

### carriers , lined polypropylene 

### .fabric bags and/or dust-tight, dry-solids transport boxes. Details on the sampling methods and sampling equipm ent are presented in Attacl:unent C.6. In addition to the ash, the incinem or produces slag which is collected in roUoff boxes or dump trailers. The number o f samples taken for chemical analysis will be based on the size of the roll-off and/or end dump trailer and will follow methods described in Attachment C.6 . Initially, the 

### Permittee asswnes that all treatment residue may be land 

### restricted. Therefore, all incinerator ash and slag are evaluated via generator knowledge as described above or analytically tested for compliance with the land disposal restriction requirements. The analyses cond u cted on the treatment r esidue are based on the collective 

### EPA hazardous 

### waste codes associated 

### with the 

### waste feed that was incinerated to 

### produce the residue during the 

### residue collection interval. As stated previously, EPA hazardous waste codes fot' the waste feed are tracked on the ARTS data base. The analytical methods used are presen ted on Attachment C.S. Frequency ofresidue testing is detailed in section C-2d(4) . Analytical resuhs are compared to the appropriate treatment or technology standards to detennine if the incinerator residue complies with the cwren t land disposal restrictions. These analytical data, as well as land disposal restriction no lineation, will accompany each shipment ofthe residue 

## destiited for land disposal.

C-128 

### JAN 1 . 5 Z0 1 0 

# OHIO EPA NEDO
V E S0 1 643 1

# " \.. ./



# 0



# c Heritage - WTI, Inc. OHD980613541 Revision : 22 

### No. vember 10,2009 C-3b Problbi&ns (see 

### 1 through 

### 10 b elow) OAC 37 4 5-270..03 C-3b(l) OAC 374 5-27 0.. 30 through 39 Dilution Prohibi ted As A Substitute for 'Ireatmeat OAC 3745 - 2 70-03 Not applicable. See Section C-la(3) for further information. C-3b(2) Wastes 

### That Are Problbited 

### From Combustion OAC 3745-270-03(C) Combustion of lhe hazardous -waste codes listed in lhe Appendix to OAC Rule 3745-270..03 is prohibited unless the waste, at the point of generation, or after any bona fide treatment such as cyanide destruction prior to combustion. can be demonstrated to comply with one or more oflhe · following 

### criteria (unless olhetwise specifically prohibited 

### from combustion): I) 2) 3) 4) 5) 6) The waste contains hazardous organic constituents or cyanide at levels exceeding 

### the constituent specific 

### treatment standard in OAC Rule 3745 -270-48; The waste consists of organic debris-like materials (e .g., wood, paper, p lastic, or cloth) contaminated with an inorganic metal-bearing**~ous** waste; The waste, at lhe point ofgeneration, bas reasonable beating value such as greater 

### than or 

### equal to 5,000 

### Btu per pound; The waste is co-generated wilh wastes for 

### which combustion is a required melhod oftreatrnt!lt; The waste is subject to federal and/or state requirements necessitating reduction of organics (including b iologj.cal agents); or The waste contains greater than one per cent (> 1 %) oftotal organic carbon.

C-129 

### JAN 1 

## 5 2010 

# OHIO EPA NEDO

VES016432

# C ' :

0



# c . C-3b(3) Dllutiou Prohib ition for L ead Containing Wastes OAC Rul e 374S-270-03 (D ) Heritage- WTI, lno. OHD980613541 Revision: 22 November I0, 2009
It is a fonn of impermissible dilution, and therefore prohibited, to add iron filings or other metallic fonns of iron to lead-containing hazardous wastes 

### in on!er to achieve any land disposal restriction treatment standard for lead. C-3b(4)**Wast ~**  Specific Pr ohibitions: Wood P r es uving Wastes OAC Rule 37 4 5- 1 70-3 0 The waste specified in OAC Rules 3745-51 -30 to 35 as EPA hazardous waste codes F032, F034, and F035 are prohibited from land disposal. Specifieally, under OAC Rule 3745-270-30(bX2), waste carrying F032, F034, and F035 

### m.iJted with radioactive wastes arc prohibited :from land disposal. The facility is prohibited from accepting or incinera ting**rddioa~'tive** wastes or radioactive mixed wastes. The facility also does not land dispose of wastes on-site. Therefore, wood preserving wastes would not be arixed with these wastes prior to final disposal at a licensed off-site facility.

C-130 

### JAN 1 5 2010 

# OHI O EP ANEDO

VES0 1 6433

# 0



# 0

0 C-3b(S) Waste Specifie 

### Prohibitions: Dlosln-Coatainl.ng Wastes OAC 

### Rul e 3745-270-31 

### Heritage - WTI,Inc. OHD980613S41 Revision: 22 

### November 10, 2009

The dioxin-containing wastes specified in 

### OAC Rule 3745-51-31 with hazardous waste codes 

### F020, F021, F022, F023, F026, F027, and 

### F028 are prollloited from land disposal. However, the 

### facility does not land dispose ofwastes 

### on-site. The above mentioned dioxin-bearing 

### waste (F020, F021, F022, F023, F026, F027, and 

### F028) are regulaled 

### under Toxic Subslance Control 

### Act (TSCA) and require incineration 

### treatment technology demoostrating a destructi.on and removal efficieocy (ORE) 

### of 99 .9999% . The 

### Pet:miuee is prollll>ited 

### fiom accepting 

### these types 

### of waste. See section 

### C- la(l) and C-18(2) for more details. The**tr~ent** residues generated by the 

### Permittee from the 

### incineration of dioxin containing waste 

### will 

### meet the treatment standards 

### under 40 CFR 268.40 and OAC Rule 3745- 270-3 0 and OAC Rule 37 45-270-31 prior to 

### land disposal. 

### C-3 b(

6) Waste Specific 

### Prohibitions: Toxicity Cbaraderistic Metal Wastes OAC 

### Rul e 3745-270-34 . 

### Not applicable. This facility is 

### not a land 

### disposal facility. C- 3 b (7) Waste Specific 

### Prohibitions: Petroleum Refining W astes OAC 

### Rule 3745-270-35 Not applicable. This facility is 

### not a land disposal 

### facility .



### C-131 

### JAN 15 2010 

# OHIO EPA NEDO

V ES016434

# C ,



# c

0 C-3b(8) Heritage • 

### WTI, 

## Inc. OHD980613541 Revision: 22 

### November I 0, 2 0

09 Waste Specific · Prohibitioru: Wastes with Ignitable and Con:osive Characteristics OAC Rule 3745-276-37 

### Not applicable. 

### This facility is 

### not a land disposal facility . C-3b{9) Wast e Specific Pro hib itions: 

### Organic Toxicity Wastes,**o~ By-Product**  Wastes, and Chlorotoluene Production Wast es OAC Rule 3745-270-38 Not applicable. This facility is not a land disposal facil ity. C - 3b(l0) Waste S pecific PToblblt!ons: Spent Alum!llum Pot Liners, Reactive Wastes, and Carbamate Wastes O A C Rule 3745-276-39 

### Not applicable. 

### This facility is not a land dispo sal 

### facility.

C- 132 

## · JAN 15 20 1 0 

# OHIO EPA NEDO
VES016435

# C ·



# 0

0 C.3c( l } Heritage- WTI, Inc . OHD98061354l Revision: 22 November 

### I0, 2009 S ampliDg and Analytical Requirements for Tr e otment Residues OAC Rule 3745-270..07 Sa mpling and Analytical Procedures Appendix to OAC Rule 3. 745-270-07(B) The analytical procedures associated with treatment residue(s) are detailed 

### in section C-2a(4). 

### In general, EPA SW-846 (o r equivalent) methods are used for the sampling and analysi s of the treatment residue . When characterizing 

### any of the residuals, the Pennittee will conduct the 

### analyses as total or , if applicable, on the TCLP elltract, per the requirement s of OAC 3745-270.. 07(8). When required, the paint 

### filter test will be used to determine free liquids 

### in the waste. C-3c(2) W astes or Contaminated Soils with Treatment Standards Expressed as Concentrations of the Was te Extract OAC Rule 374S-270..07(B)(l) Tbe Permittee will provide the notifications and certifications required under ·40 CFR 268.7(b) for each shipment oftreatment residue to a land disposal facility . C-3c(3) Wastes or Contaminated Soils with Trea tment S tandards Expressed as Concentrations of the Waste OAC Rule 3745- 270..07(8 ) (2) The P ermittee will provide the notification s and certifications required under 40 CPR 268 .7(b ) 

### for each shipment of treatment residue to 

### a land d isposal 

### facility.

C-133 

### JAN 15 2010 

# OHIO EPA NEDO
VES016436

# c

c



# c C-3e(4) Freque.ncy of Analysis OAC R ule 3745-54-1 3 (A)(3) OAC R ole 3745-271H>7(JJ) Heritage - 

### wn,Inc. OHD980613541 Revision: 25 April23 , 2010

The frequency of analysis 

### aswciat<:d with treatmen t residues is 

### discussed in section C-2d(4 ). C-3 d C -3d(l) Notification a.od Certification Req u irement$ (see 1 throu gh 9 below) OAC Rules 37.c5-27G-07(A), (B)(3), (B) ( 4), a.od (B)(S) Rdeatiou of G ... enotor Notiees aod Certifications OAC Rule 3745-270-GT(A) 

### Noti . ces and certifications from the initial generator of the waste will be reviewed and 

### maintained by 1he P=ittee for three years. C-3d(2) · Notificatioa a n d Certific:atlou Requirements for Treatment Residu es Shipped to Land Disposal Facilities OAC Rule 3745-27G-07(B}(3) and (JJ}(4) A 

### copy of all 

### noli= and oa:tificalions provided by the Permittee 10 land disposal facilities will be kept in files as 

### required byOAC Rule3745-270-07 

### and 40**CFR~ 7**  fora periodoftbreeYQfS . A c:opy of notices, certifieatio!lS , demonslrations, waste analysis data, and other documentalion for wa.siCS 

### generated on-site, produced pursuant to 40 CFR 268.7 and OAC Rule 3745-2?0, 

### will be rtl8ined on-site for at least three Y=S from 1he date that the waste 

### which is the subject of such documentation was 

### trcaied or seot off - site for trealmen t, storage, or di.sposal. All I.DR notification clocuiDCIJfation for ia:o ming off -sile geoe.ated waste shipments 

### will be maintained at the facility for at least three 

### years as part of the operating record. Paper portions of the records, older 

### than three years old, may be maintained at ao off-site sorage facility. lieritagt>-WTI will 

### maintain a list of 

### these off-site locations at its facility . 

## wn will ensure tbat !be portions of the operating record 

### mainllUned at the off-site locations would be available to review at WTI's facility within frve 

### business days ofthe Ohio EPA's 

### request. C-134 

### MA Y 1 7 2 010

VES016437

# 0



# c C.3d(3) 

### Heritage- WTI, Inc. OHD980613S4l Revision: 22 N ovember I0, 2009 Notification and Certification Requirements for Wastes with Organic C o nstituents OACRule 374S-270-07(B)(4)(c) Not applicable. C-3d(4) Notlficalion and Certification Requiremea.ts for Characteristic Wast es OAC Rul es 374S-270-07(B)(4)(d) and (e) Not applicable. C-3d(5) Notification and Certification for Wastes to b e Further Managed OAC Rule 37 4S-270-07(B) (S) Treatment residues that do oot meet the land disposal restriction regulatory levels \vill be identified as requiring additional treatment prior to land disposal. A land dispos al notification form accompanies the waste when being shipped to a different treatment, storage, or disposal facility. C-3d(6) Notification and Certification Requirements for Land Disposal Fad.llties OAC Rule 374S-270-07(C) Not ap plicable. Tbe facility is not a lan d disposal Facility. · C-3d(7) Notification and Certification Reqlllrements for Facilities Treating Hazardous Debris OAC Rule 374S-270-07(D) Not applicable. The 

### facility does not claim 

### that hazardous d ebris is excluded from the definition 

### of hazardous waste.

C- 135 

### JAN 1 5 2010 

# OHIO EPA NEDO
VES016438

## 0 \ 

## .. /



# 0



# c C-3 d(8) Heritage - W1l, Inc. OHD980613541 Revision: 22 November I 0, 2009 Notification and CertiOcation Requil"ern,ents f or Facllltles Treatin g Contamiuted Soil OAC Rule 3745-2 70-07(E) Not rpplicable. C-ld( 9 )**No~tion** and Cutificstlon R.equiremellts for Recycbblc Materials Used 

### tn a 

### Mauer Coostituting D isposal OAC Rule 3745-270.07(BX6) Not Applicable. Recyclable mate:ri. als used in a 11l8llller constituting d isposal are not treated at the facility.

C.\36 

## .,...
'JAN 1 5 20\0 

# OHIO EPA NEDO

VES016439

# 0



# c Heritage- WTI, 

### Inc. OHD9806135 4 1 Revision: 22 November 10, 2009 C-3e Additional Requirements Pertaining to St orage of R es tricted Wastes OAC Rnles 37 4 5-270-50(A) , (D ), and (F) The Permittee is a waste storage and treatment facility. Treatment of the waste is by incineration. The Permittee accepts waste from off-site as incinerator feed. This off-site waste is stored in tanks and containers. Section D of the Part B permit application provides detai ls regarding the container and tank storage 

### areas . Various wastes ml!St be stored on-site 

### so that the appropriate blend of waste may be made f o r the optimwn incinerator feed . C-3e{1) Restricted Wastes Stored in Containers OAC Rnl e 3745-270-SO( A)(Z)(a) As pr eviously noted, each shipment of waste accepted by the facility is logged into the ARTS database. This database tracks the waste 

### from the moment i t atrives at the facility throughout the 

### timo it is stored, incinerated, and shipped off site as treatment residue, or transferred to an alUo:late facili ty. For containerized waste accept ed at the facility, the ARTS database generates a labe l for the container when i t is logged into the system. At a minimum, the label has the waste COlll:eots and the date of accumulation listed. Section D of !he Part B permit app lication provides roore 

### details on· the container waste storage procedures.

C-137 

### JAN I 5 2010 

# OHIO EPA NEDO
VES016440

# c C-3e(2)**~Uitrlclcd** Wastes Stored iD Tanks OAC Rule 374 5-270-SO( A )(l)(b) Heritage - WTI, Inc. OHD9806l3541 Revision: 22 November 10,2009

AJs previously noted, each shipment of waste accepted by the facility 

### is logged into tbe ARTS database. Th.is database !nicks the waste from the moment it arrives at the facility throughout the time 

### it is stored, incinerated, and sbipped off site as treatment residue, or trnnsferred to an altemate facility . Whco waste is placed into a tank for storage, the time and date of entering the tank, the waste coUiellts, and the quantity of waste are logged into the ARTS database. Th.is infOiroation is maintai.Ded for each waste storage lank. Sedion D of the Part B peonit application provides more details on th. e waste storage tanks .

. C3e(3) S tor"ie ofUq uid PCB Wastes OAC R ule 374 5-270-SO(F) 

### Not Applicable. The Pennittee does not accept liquid waste that contains SO ppm or more of · PCBs for treatment C-Jf Additioaal Requirements for Treatm.ent S urface ln\ poandment E:rem ptioa OAC 

### Ruk 3745-270-04 Not applicable. The facility does not treat waste in surface impoundments. C-3g . Extenaioas, Exemptions, and Variances OA C Rules 3745-270-05, 06 , and 44 Not applicable. The facility has not requested any extensions, c:umptions, or varia.nccs.

Cl38 

### 'JAN 

## 1-5 2010 

# OH IO EPA NEDO

VES016441A'ITACBMENT C .l WASTE C ATEGORIES & CHACTERISTICS 

# • Heritage - Wll , Inc. 

### OHD980613541 Revision: 22 November I0, 2009



### JAN 1 . 5 2010 

# OH IO EPA NEOO

VES016442

## 0 

## :z: 

# 6 m

## ~ :z m 0 

### 0 <- l> :z:: 

# - ... "' 

# "' 0 

# 0 0

A1TACBMENTC.l WASTE CATEGORIES & CHARACTERISTICS Woote Catqory Wute Ca....,.lhzanl Basis for lhzanl Deoi&OI&doa Charatterittk.s for lBd!Ytd Dal WUie Streama witllia the Wute Catqo ryl'l A. Organic L fquldo: W aste that is Due ro tbo variability illdle 

## • GODCrlltor lnformatioo1 1 primoliq orpnlo ·ODd is 

### hisb!Y 

## waste-. fortllese wulc and/or tluid,**~low** lnorpak solido c:ategOrioo (A.B,C), ODY ODO or 

### • J>ro.Ac:copcii>CO Analylkal cxmtmt IIIII kno-IIHuodai!b lriY combln«don oftbo fi>ur Results wal<:rCO!llelll.**~** (••·· roxicity; B . Organic SlucJso• (Llquld/Solid reacti vity, J&nltabllity , ind Mbdures): Wuto that is primarily corrosivity) may be oppllc:ablc. orpnic with low-to-modontc iDarganie tolido - ond Willet CCIIIalt, ood J)UID!IIblc. C. Organic Solid: Wastethatb primarily orcanic ODd solld, wllh**low~** ioorgani<: --"""- coolaJI.**--------------** 

# -- - '---

- -- - 

# () Heritage • 

# wn. Inc.**OHD980613~41** Revision: 22 November 10, 2009


## co,_., I W

ale otmms Jnctudt<l in tbcoc

- catopioo (A.B. C), may COIIIaio lillY oae oftbo FJ>A WMie code$ LUted ill the Part A. Tbim((lre, any oao or my ooml>inatloa ottile bazanlou.o obaractuistics may be appl icable to tbo wute.

- -----

HumcnQ -...teWt.WIS nub ..**a.,..;,;~** 8cc:wle c::Kb ..._,.tO'CUl difRn rcal)ilq II • llqt eCUII ol

# ido.,.. wed**b.._..~-- blali:lmldot~**  b .._

- 11o&**~-.·- OIIM-~fidH!y** **lo iSalllh<r,>ooi.OU>.**  2 Ocnco:tor lftbmation: lne)' lndbdc My Of .. o{tbo**COl~** 'lliiiStcprofile tbeot.IIIWhdalsdt;y -'•· .b«t,. tNYot ..... SCtWd -)'ticaii'CIUia pt(Widd by thllftlle'*" « lbs PcanlttM ' • laborMOty, C.l -1
VES0 1 6443

## 0 :I: 

## 0 

## m 

# "I! z m 

# 8**~** 

### :z 

# - ., ,.., 0 ES 

# 0

W-Cateco<Y 0 . loorp Llquid.o: W1.1te !bat b prinwlly inorc>nic and bJ&hiY Jluid (e.g. aqueous), widllow suspended inorganic 10lids 1011 low orpnk CODknL. B. inoQ:.Inlc**Sill~~&<>** (Liqu:i<VSolid Mixnlla): WISielbot b primorily inorpok. with 

### -cHiich wataCClCIImsnd low orptllc coment, and pool!ltlblo. F. lnorgJmic Solids: Waste !hot is Jl<imsrily inorpnlc111d solid, with low 

### ors-ni• ·- 111d lowt.o-modoralo wlllor c:ooteot.• 

# 0

ATIACBMJ!:NT C.l WASI'E CA TE GORIES ct: CHARACJ'ERISTICS Wute Catogol')' Huard Basis for Balar4 Deolpalloa Cba r'IICieriollcs 

## ror Ia dmdaal Wute Struma wlllaln Uoe W ut e Catecort'' Due to the variability Ill 1l!o 

### • Gener>tn< I nformation '

- sln:JIIlS for tbole - end/ or categories (D,B,I'), OJ1Y one or 

### • Pre-AccoplaOOe Aoalytlcal -.y combination ofthe IDur Rtlsult! c:bmclerisllca (Lc., IOxicll)>, reaaiYily , i&uiJabilily, IDCI c:orrosM!y) may bo opplicoblc.



# - - 

# C ) Heritage - 

### Wll, Inc. OHD9806 13S4 1 Revision; 22 

### November 10, 2009

Colluual Waste m:oms included ID. tbcsc waste catq;ori01 (D.S,F), may CO!IIain any 0110 of !be BPA Waste eodos listed in lbe Part A. 

# ,...,fure, 111yaoe or any comblnllloa of!be lw:ardoos c:horocleristlc may bo appticabloto thc WUia. 1)pioally

--- olooc:outaiD SOlDO orpnk .-ial "" "'!uin: fncileraticn.**H~ 'f!r~Rsfn:Gts**  ..tc**up~ 'll'tiM~**  Bcli:usecac:h walc;llr'c:lfa cH.,JaUiliacia •**tarp~orhdba:•** to aNe4**tor~** "'"ir"'k'\ tM: iA(Oimfltioll 1:t oo&**~** lbc**~** boM't'Ct . 11**~.** tk**Pawia:te ~.**  facil(y .. Eut UrlqiOOI. ()lUg. 2**~ ~mqi:da4e**  uyor 

### .e oCik**~wtl!hpofiktbccli.** •lllri&l Mfi:lyftU**~beet, fftdlot.,.k~VeMJ** **~** ruulta**~ bytht~**  oratfitamin!e•s**·** 3 The trc•ment ru:!Ab (Lt.. ISh ad Ill&) pnetlted b,-IM**P~** is**i1~** ia thl•**wt~ te**  abelnL


### C.l-2
V ES 0 1 6444

## 0 

# :z:**~** 

## m :z

## ~ 

# - ... z:: 

# .... 0 

## m 

# 8 C5 

# 0 

# 0

ATTACHMENT C.l WASTE CATE GORIES&: CBARACTERIS1'ICS Wute Category Waste Catecory Huard Balla for Bua r d Dml&aattoa Choraderittl"" for IJillj'llidaaJ Wuto Streame witbia tbe Watte Catqorf 11 Due to the wriability in the w.CC 0 . lAb hcb: Lab pocb o! ......., fbr dlb wasto_,., my • l'octqjng Sh...- 

# -mimi-
oao or""'comblutlc. otlbe fi:IUt AMlysiJ**~** bfl'onlllOoo chcmkalt, lob - 

# . 

# d.·-- (1.6. Ollddly, 

# ---- .-M\y,fP!Ibili1y, ond '"" ...i'Y) mqbe o.l'¢icoblc. 

### • c.otainorA odn,

### The~ ... --**~** -JMd bribe pcrmillcc H.**~Gas** one! Gos MOctun.o on: llClJlollwrdooo pet**R~** 

## • Vopor-ofwasto-lo 

# ....



# .,.,.

-- oonosphcric prcoouct IISil' 

## • ()cocntor Jntonnotion' 

# • Oeo<n10r C...ilkotloo Due 10 ll>c vllllobUky In lbe WUIC Generator lnf01l118lion ' L l.oooe Pocks: CoNiioon of 

### ........**rorllll•-~·""'** 

### • CCinlnC:fci.t or ClOClSUDiCr ooo or t1f1 oomhlnalloo of tbc fOur mtlcrillo'pn>dllou.

- .. (lo.,IOXlc:iey, 

## • fll>&ul>riot 

## "*Y'i• rmlto**rracii~'Y.** q,fc.biiiQo, ond """""'Q<) - be .,,.• ble 

# () Heritage - 

# wn. Inc . OHD980613S41 

### Revision: 22 November I0, 2009

Comment 

### w

.... 11resm1 iDchdcd i.'1. tbls wute c:oo_,.may- Oil)' ooooteho SPA

......c:odeo lisraf io lbe l'ln A 'J'bcrcli:n;,. _,. one cr flll1 oombb6on of Cho ...........d .......isticsmqbe oppllcoblc II> lbe- 1)piQilyWMb::**~trams** also COClCI.iA IOI"''It- orpnk: 

# ......Wor""""- W Mto JCrelml inctuded iD this Waste COiqOfy ... ooo-llaruOOul """'<dine"'

- Olld ttdcnl**R~** 

## "''"lolion onc!"' nono ofdloi!I'A -codes ll$tcd In lho l'totAopply. Wute _,include<! In tills wute ' 

# -&OIY- ...,..., Ill)' ooo oftlool!l'A I ......, c:odeo litled!D lbe Pill A**'l'bcrdo~** _,ooe or aD}' combillld.kwl. of 1

.... ......_ ct.wa::IZ<i>1>:4 JUlY be**~It** IOtbc wute. 1)pl<a!ly ..... wuteatr.us abo CCift'IUl some orpaic**..-iolor~NUiro-** ..,....,. ......,,......nuptMac-**---~ a.c:..ecd~--..,radiaain•r.tc:IZdC!III:Itoi~WICd.b'hl:ad~......-.lbe~**  is-

- 11lo

# lo--.................,_ .. _ily lni!MtiJwtpool. OOlo. 1 

### a.- """"'""" 

### -r a.ctode ony« Ill ou,. followiac; _.JI'OIII• .,.., ollhrid olldy du .-, ooUot- ,...., ""'.rtlctl ..,...,**~dod** ilytbe -or lk p...,;o,.·, 

# """"""' · C.l·3 VES016445

# !



# e



# e AITACBMENT C.2 APPLICABLE PRE-ACCEPTANCE ANALYTICAL PARAl\1ETERS

/ 

### H eritage - WTI, Inc .

OHD980613541 Revision: 22 November 10, 2009



## JAN 15 20 1 0 

# OHIO EPA NEDO
VES016446

# c

c



# c ATTACHMENT C.Z APPLICABLE PRE-ACCEPTANCE ANALYTICAL PARAMETERS Heritage • WTI, Inc. OHD980613541 Revision: 22 November 10, 2009

Waste Category Measured Parameter A B 

### c D E F OflJU>I< o.p.le Oquk '-Pak '-Pak l •• raarUc Uquads Sludlu Solids u.q.w. Sld.,s Sollds Ash Coatea.l X 

## " X X X X Benzene Coctent X X X 

# • X X Compatibility Tes18 (Acid,Aikali,Watu) X X X X 

# " X Flashpoint 

# " X Heat Value X X X X X X Inorganic Anion CoDieat (Bromide, Chloride, X X X . X Fluoride, Iodide, Sulfur) Melals Content (Antimony. Als=ic, Barium, X X X X X X Beryllium, Cadmium, CbrocUlllll, l.ud, Mercury,**Nicke~** Seleoiwn, Silver, and Thallium) Paint Filter for Fn:c Liquids X 

# " X X PCBs (only for liquid waste less than 50% w&ler) 

# " X pH X X X X Pbys;cal Description X X X X X X llodioacti vity X X X X X X Reactivity Screen (Cyanide, Sulfide, O>ddizer) X X X X X X Water Coctent X X X X A: •wutc c Mceoric:s G aod Harc: aot M;cct 10 prc.-ec:etptab:: e

# u.atyss)
JAN 15 Z010 C.2·1 

# OHIO EPA NEOO
VES016447

# c ATI ACHME NT C .3 

### APPLICABL E FINGERPRINT A."'ALYTICAL PARAMETERS Heritage • WTI, Inc. 

### OHD9S06. 13 54 1 Revision: 22 

### November 10, 2009



## J

A

N I 5 2 0

1 0 

# OHIO EPA NEDO

VES016448

# c:

0 ATTACHMENT C.3 APPU CABLE FINGERPRINT ANALYTICAL PARAMETERS 

### Heritage - 

### Wfl, Inc. OHD98061354l 

### Revision: 22 November 10, 2009

Waste C ategory Measured Pa"mtter A 8 

### c D ! 1< Orgtnic Orpnic O rpnie t.orcaaic IM<pak lurp.Ue Uq\Uil., Sl•da« SoUds Liq.... SldttJ Solldo Compatibility Tests (i\Cid,AIIdti, Waltt,Waste Mix,. X 1 X X X X OSC or equivalent metbod/te$t) Flat<bpoint X X Heat V al

ue X X X X X X IDorganio llllioo Content (Bromide, Cbloride, X X X X Fluoride, Iodide, Sulfur) Paint Filler for Fn:e Uqulds X X pll X X X X P hysical D=ription X X X X X X Radioactivity X . X X X X X Rea<:tivity S<:reen (Cyanide, Sull.id<>, Oxid izer ) X X X X X X Waw Content X X X X



### JAN 1 5 

### 201 0 C.3 - l 

# OHI OEP A NEDO
V E S016449

# •
•
• ATTA CHMENT C.4 

### Al'PLICABLE SUPPLEMENTAL ANALYTICAL PARAMETERS Heritage- WT!, 

### Inc. OHD98061354 1 Revision: 22 November 10, 2009



### JAN 

## 1:5 2010 

# OHIO EPA NEDO
VES016450

# c

0 ATTACHMENT C .4 APPL ICABLE SUP P LEMENT AL ANAL YTICAL PARAMETERS 

### HeritAge - WTI, Inc. OHD980613S41 Revision: 22 November I0, 2009

Waste Category Meos:ared PJ.rlllleter A**~** · C ll J: F Orp.ok Oquk Orp.k IM<pak IMrpok Joortuk u., .... Sl..... 

### s.... 

# ........ so.• ... Soll4J Cyanide Distillalion X 

# • X X X X Frocms (ooly for liquid wuteless 1llall SO%"""") X X Melals Content (Antimony, Amnic, Barium, X X 

# • X X X Beryllium, Cadmmm, OlromiUID, Lead, MCltW}', Nickel, Selemum, Silvtt,lllld Thallium) PCBs (ooly for liquid waste I""' than SO% water) X X Rcae<ive Sulfide Di.slillatioo X X X X X X Sellable> Solids · 

# " X X X Speci6c Gravizy X X X 

# • " Vifcosity X X •w ...**~Ga:tc!Hamootsalljecttorps'** 

# .....

# ,..

JAN 

## 1-5 2010



# .OHIO 

# EPA NEDO C .4-1 VES016451

# •
•
• AITACBMENT C.S 

### ANALYT ICAL METHODS Heritage- WI1, 

### Inc. OI:ID98061354 1 

### Revision: 22. November 10, 2009



### JAN 15 ZDIO 

# OHI O E PA NEDO
VES0164 52

### ~ 

# - '- ) . )> 

# , :z J ':"" 

# .. .,**~** 

## ,.., 'i 0 5 

# ' ) 

### r· \ ' I 

# 0

A--· - -- 

# -- - 

# --- - 

# -- --·· -·--- 

# --- PN'Imeter Analytical Method Oosc:ription Typo A!hContoot p Ash from Potroloum Produce. I Cyanide Distillation (Qilll!ltllalive)' SL Tolal ct. Amenll>le Cyanide Plashpoint P,F,S Plammllhllltv l'otalli&l S · ofWaste P,F S FiashDomt. P.F,S Peoslcy·Muttllj**~up** Metbod. for Detonninlnc lll!ltabili!Y lncnt.,ic Anloo Contont PF Anlons io Waler by loa ( Hell Value 

### PF Bomb Combwlioo Method for Solld WastB lnorp.nic Analysis l'roceclln P,S,L Jll4uctivdy Covplea Plasma·A!umic Emission (Meull) L Mercury In Uquicl Woote (Maoual CoJd.Vapor Teebrllque) L Mereury Ill SoUd or Seml101ld W- (Manuat Colci.Yapor Teclmlauel lnorp.nlc Propentlon p Acid Diaestlon ofSediments Sludges ct. Soils (Meuls) L Acid Dlgcsllo11 ofWilen for Total Recoverable or DiJJolvod Metals for AnaiYW byFLAA or ICP opy F,L Mlorowavc Auuet.d Acid Digestion ofAqueow Salllples aod Bxlracta (Mocabl P,S Miuowavc Aaslsted Acid**D!~** ofSediments Sludges, Soib ct. Oilt (Metobl L Toxiclly Cbanooterbtlc Procedure (TCLP)**~lelab)** WTI
W-1001 

# () Heritage - 

# wn. Inc. 

### OHD980613S41 Revision: 22 November 

### 10, 2009 Reforence' SW-846 ASTM

9040 9010 049112 1010 • 300 04327

5050 . Dl2964 6010 7470 7471 i ' ' 3050 . 3005 3015 30$1 Ill! 

# n....-,......,.. ...... 

# ,......,,ilodybeascollllo--. -.,.riptoo __ _,or.....,........,. __**..,.,__aflbo,_~** at*c iMdiDCOod _...,..**~equlnkcqllllit)rm~ol--.** 2**~....,...** • 

# .,._..,.i!11oe ........ _ - • ...- ...... C.S-1

VES0164 53

# ( )

PII'IUJieter Aoalytlclll l)'po ()r&anic A.nJ.Iysb Proccdum L SL P, S,L p L p L L,S L L QraMic Prq>arotlon L L p 

### s L P L 

## 0 Paint Filler P F L 

### ::I: pH 

### PF 

### 0 <- )> 

## m :z

## ~ 

# - ... P,F Phyo leal 

# .. pp ? 

# n - · 

# ,
·- ' 

# 0

.. .....

# _ 

# .. _.

### ...... 

# - ·- - 

# -- --- -·- · -. - 

# -- Mclhod Descriptkio Chlorinated Herblcldes bv OC Dctcnnlnallve c**~ed** Volatile Orpllico by GC (Freoa S<run & Volallleo ) . Ncm-Haloplated Orpulco by GCIFJD (Bcu.. o) Orpno-chlodDc Peoticides by GC Poi)'CblortoUtd Blplaooyls (PCBs) by 

### oc; s-l· ...tatilo**~** Compoooads by GCMS: CopiiJcy ColumnT Vololile Orpntc Compoomds by GCMS (Frooou A al •olatllal Solvent Bxtnoc:ted Non-volatile Compoonds by HPLC.'fS.MS or IN d<lectioG (Carllamates) Scml-volatllo Orpnlc ColllJ)OWlds by GeMS (Kepoac) I Oraonlc Exttactloo 8< Samolc l'reDanltlcn Pur11.o &; Trap**(B&~~r.ooo.** J1reoll.i) SWirlltcrv Funnel Llould - Uouid Extroetion lS.al-volatll<ol Automllled**~~~** Bxttaction {Carblmates. Seml-•"'-tlloo, Pcllllc:ld<t PCIIo WL"" Dilution (Beouno. 

# !',..,...., PCBa, Koooae l Paiat Filter Ua.tds Tert I oH Blrctrometric Mea.suremoot I SoU .t: W- pH I PhYsical . ' Saeenln• Alla!Yris in Waste C. 5-2 WTI 

# () Heritage - WIT. In c. OHD9806J3541 

### Revision: 22 November 10, 2009 Rof....,..,' SW-1!46 ASTM

8150 8000 8021 801SB 

## son 8082 1270 1260 8321 1270 3500 5030 3510 3541 3580 9095A 9040 9045 04979

VES016454

## 0 

# :::c 0 

## m**~** :JI' 

## ' ii

.:J


### · J

# ~)

Pmamacr Rldieo<:ti!(ty Set= Roodivity**Scree<~** & Compa tibility Tcsll

Sei!Jible Solids S)>Odllo Oravily Sulfide DUtilla!ioo Sulfur Conteat V"-ity Water Cooteat P - Prc · Aocq>tanee Aaaly•ls P - F lDge:rprinl Analysis S • Supplemental Analysis L • LIUid Disposal Rem'.cti011 Analys is ADalytlcal Typo PF P,F p P,F P, P p F 

### s s 

## s PF 

### s PF p F 

# 0

A I 

# ---**-- ---** **~** 

### C.S - 

### Ao alvtical Met h od 

# . Modlod D<:scripcioo Rodicamvily Callpallblllly orScrocnlD& Analysis of Waste (Add, AlluiU, aad Water Suualar Ia Wutel eomp.rtibllily wllh olhcr**waste~ (W~**  Mis oad DSC) Screening ofCyllllldea In W ute (Melhod C)**s~** ofOxldlz<rt in Waste Screeninao(Sulftda ill Wuto Water ct: Sodilnent 1n Fuel Oils by tbe Cenlrifu&e Mothod Prcccclwe) Sooel& (jruily ofUNid hldosai&J Cltemlcab Acid-Soluble 

### a: Aelcl-lllloloble Sllifida: DltdJJ.Iion Combustion MGChod for Llaulds IUid Solid Waste Low Tempenlln Vl.oc:Oiity Measured by Brooktlold**V~w** · Water In Crude 011• OCarl Fischer\ Titration Water In Palnll 

### a: paint Mm: rials bv Karl f'l.oc:her Melhod 

# . . . 

# - 

# PSI> C.S·l ::z: 

# -**~** 

## "' Q 5 WII W-1002 W-1000

W- JOOS



## - 

# ( ) Heritage - WTI. Inc. OHD9806!3S41 Revision: 22 November 10,2009 Rera-.1 SW-34jj ASTM


### ososs 896 8·83 DS049 1)4911 1)4971 01796 089 1 9030 0291!3- 87 0<1377 04017

VES016455

# .e
ATTACBMENTC .6 Heritage- WI1,1nc . 

### OHD9806 13541

· Revision: 26

June 

## 9, 2010 · BASIC PROCE DURES & . EQUIPMENT FOR WASTE SAMPLIN G



## JAN 14 2.01! 

# OHI O EPA NEDO

VES016456

# (~

. ./"'-.. 

# ,.. . · AITACBMENT C.6 

### Heritage· WTI, Inc. OBD9806 ! 354 1 Revi sion: 22 November I 0, 20()9 BAS I C PROCEDURES & EQUIPMENT FOR WASTE S AMPLING ( CBEMISTRY PRACTI CE 141 SAMJ>I JNG PRO CEDURES . n mpOSES AND GENERAl , CONSIDERATIONS 1. P URPOSES AND GENERAL C ONS IDERATIONS Sampling is pctfonned by facility employees for a variety ofpwposes.and by the waste genecator 

### at their locatio n to make au initial 

### waste detamination. Specific sampling procedures are dependent on both the nature of the material and the type of container. This section**present.~** sampling methodologies to 

### be utilized on- site by facility personnel in accordance with OAC R ule 3745-54-1 3 {C)(2). Sampling ofhazardous wastes is condu cted for several different pw:poses . In 

### all instances, it is performed to determine compliance with existing togU!¢ons promulgated by the different regulatory agencies. It is alJo conducted to ob tain data for pwposes of classifying, managing.**~** and dclemlining compatibility characteristics ofthe wastes. When a material arrives at the facil ity for treatment or storage, a determination has previously been mad e by the generator that the waste is either: • a solid waste wbich is not a hazardous waste as defined in OAC Rul e 3745·51·02; • a l isted hazardous waste as de fined in OA . C Rule3745-5 1 -31 to 33; or • a characteristic hazardous waste as defined in OAC Rule 3745-51-20 to 24.'

C .6-l 

### JAN 1'5 

### 2010 

# OHIO 

# EP A NEDO
VES016457Heritage - Wfl, Inc. OHD98061354 1 Revision: 22 November 

### I0, 2009 The generator's/custome:r's completed WPS provides the Permittee with information regarding the composition and characteristics ofthe waste . Therefore, according to USEPA docwnent SW -846, Test Methods fnr Evah!ati ng So1id Waste, vertical compositing is the appropriate meihod for collecting representative samples of a variety of materials. This method will yield a representative sample of all containers, except where noted in this manual 

### Upon ani val, the shipment of waste is sampled and analyzed to ensure it matches the ove:rall waste identity designated on the accompanying manifest and pre-acceptance paperworl<:. The sampling equipment and procedures descri bed in this document represent the facility's recommended sampling protocol for general types ofwaste and waste containers. In general, the equipment 

### utilized for specific wastes correspon ds to those referenced in 40 CFR Part 261 Appendix I. The sampling methods and the equipment utiliud are presented and desmbed in this procedure. Procedures and equipment may be updated and revised as new equipment or procedures become available. In general, sampling requires the collection ofadequate sized, representative samples of the wastes. Sampling situations vary widely and therefore no universal sampling procedure can be recommended. Rather, several procedures are outlined for sampling different waste types in various st ates and · containers.

C.6-2 

### JAN 

### 1 

### i 2010 

# OHIO EPA NEDO
VES016458

# c

0 Heritage - WTI, Inc. OHD98061354 t Revision: 22 November t 0, 2009 These 

### procedures require a plan of action to maximize safety ofpersonnel, 

### minimize sampling time and cost, reduce errors i n samplin g, 

### and protect the integrity ofthe samples 

### after sampling. The following · generalized steps 

### are essential for the Permittee's plan of action. I. 2. 

### 3. 4 . 

### 5. a) b) c) 

### 6. 7. 8 . 9. 10. 11. Obtain bac!cground information about the waste from the WPS and analysis. Select appropriate SOP for sampling. Obtain the proper sampling equjpment or tool. • Obtain the proper sam p le container · and closure. S elect an adequate sampling plan that includes the following: Cboice ofthe proper sampling point Determination ofthe number ofsamples to be taken. · Dotenninatioo ofthe volumes ofsamples to be taken.· Observe proper sampling precautions and personal protection equipment (PPE) r ecommendations. H and le samples properly. Label the samples by attacbing label to sample container. 

### Record all sample information on 

### the**!abe~** wben necessary. Observe all equipment decontamination procedures. Del iver the samples to the labora tory for analysis. 

### l.l B ackground Information About 

### the Waste Accurate background information about the waste to be sampled is critical in th e proper planning ofthe sampling activity . The information is used to determine the types ofPPE to be used and sampling precaotions to be observed, as well as tbe types ofsampling equipment, sample containers and container closures required.



### JAN 15 2010 C.6-3 

# OHIO EPA NEDO

VES016459

# c .



# c

c Heritage - WTI, 

### In c. OHD98061354l Revi . sion: 22 November 

### I 0, 2009 Generally, the info:rmation about the waste determines the kind of sampling plan to be used. All the information needed is available from pre-acceptance doctimentation, wh ich includes the manifest, the WPS, generator/customer supplied information (MSDSs, 

### analytical, etc.), and the pre-acceptance analysis, ifapplicable. The information needed by the person performing the sampling is generally a vailable on the HMIS label (Hazardous Materiallnfurmation System) . Any questions that arise, for insrance a very high rating for health, C!lD be directed t o the employee's supervisor. The supervisor will direct questions to the Safety Department. If necessary, the Safety Department 

### can verify chemical properties in references such_ as Dangerou s Properties nflndnstrial Matrria ls, Merck Index, Haw\ey!a Condensed Chemjcal Djctionery, Toxi c and Hazardous TndnstJial Cbc;mjca}s Safety Man 11al for Handling and Disposal wjth Tnxjcity and Hazanim1s 

### Data, 

### 00: o ther chemical 

### references . L2 Selection ofSarnplillg Equipment Hazardous wastes are usually complex, multiphase mixtures ofliquids, shnries, sludges, or solids. Th es e mixtures vary greatly in viscosity, corrosivity, volatility, exp losivity, and fl ammability. The solid wastes can range from fine grain powders and granules to larger bulk waste such as wood, insulation, and cans . The waste may be contained in drums , barrels , sacks , bins, vacuum 

### trucks , and other containers. No single type of sampling equipment can be used to collect representative samples of all 

## types o f wa$tes . Tabl e A 

### lists waste types and the corresponding sampling equipment available for use. Sampling procedures for multiphase wastes will be discussed later in this document.



### JAN 

### 1 5 2010 C.6-4 

# OHIO EPA NEOO

, . VES016460

# 0



# " t./ TABLE A Heritage - Wl1, lncOHD980613541 Revision: 26 

### Juue9, 2010 TYPICAL SAMPLING EQUIPMENT FOR VARIOUS WASTE CONTAINER TYPES 

### Waite Type 

### Waste Container Dnlmudtoteo SadtUlllloes 

### otiea-btcl 

### -rr.ek ClooM<cl Trud<, TIDbrTratk Sl.onp Taaka or 

# - Fnoo-llowfag llqaids ODd Collwasa orOpeD Collwasaor Coliwasaor slmrlcl Tobo Samplor NIA NIA OpeD _ 'lUbe Coll=t l!'om a SamplM Volvo Loooe aoll4s . IIDilJ ()pea T1lbc Sample!

# ==~ particles, trhigh Wcoslly OrSooop Co1iwaot. or Cotiwuaor Collwua or Sooop Slqcs Scoop Scoop Scoop Loo<o aolids • molal Scoop, Trier .

# =-~ Scoop. Trier, or Scoop, Tti«, 

### « S<oop. Tlior, or powdcn cr 

### J'1IDlll<s

# =~**s.:;;;;;~~r** 

### eonw- ColiW1a Collwasa Loooe !01ills - dry Scoop= Scoop or Scoop or Opal Scoop**or~** NA powdm ... . 

### J'IIDlll<s Tobe cr

## ~ 'i'Dbe Samplor TobeSamp Loooe solids • -or OpmTobo OpenTobo Opon Tl1bc Opcn'IUbo Open Tubo samplor**~&lid** l=loror 

# I !:"'"'**~;cror ~or**  or Auger A,.;, Loose aoicb • largo pillS**~Trier** or lArpTIW l.<qe nicr or**~Tti« or**  

# =Trlc< or 

### ScooP orStD<IO 

### scO<m Solids·Siaa 

### U.Tric or LlrSI'Tricr 

## I=Trkr.or Lei• Tti« or

### ~Trior or Scoop 

### ors;,.,.., StoOD )o Silwo lbo 

### I8IIIPihl& motbocls ba tbo appeodix are DOt

### beiDa fimully adopted by Ohio BPA, a p<rSOD wbo wishes to employ ao altemltive smiplillgme«bod, iDciDclia&previoualy**~** equiYilleatASTM melhodr, la DOCrcqoaired to-- tbo equiv1lelley ofIDs 

### methOd Ulldertbo prooedDre& sot forth in§§ 260.20 ood 260. (OAC 3745-51.20 , AppeDdix [) )o Jf tbo l8lliplilo& devi<o listed abovo iJ ootllppRl!lliale lix lbo -type. 1 more opJII<I!IIi& nmpliDa- may bo used. )o**~** _,_ ODdhomogcooou- are typioally SCIIplod llliog tbo...,. type ofnmpliDa equlpmt111. See AUaclrnO!!I C.7 

### roc more del:ailJ rcpdiDg lbo wnpliDg ofh*n>- aad**~** _.. )> For ..;rljt!maJillformatioo rcpr4iDg SIIDplfDJ cqulp!Dtm, see AU.chment C.7 . Pipe Colloot lioma Valve or

### ~:,.. n· NA

tlippcr

. tlippcr

NA Dimler

N/A

C . 6-5 

## JAtO 4 20 11 

# r OH IO EPA NEDO

VES0 1 6461

# c

0 Heritage - 

## wn, lnc. OHD980613541 Revision: 22 November I 0, 2009 Z. SELECTION OF S AMPLE CONTAINER, CONfAlNER CLOSURE, AND CLOSURE LIN1NG Z.l Sam ple C ontaioen The most important factors for facility 

### personnel to consider when choosing contaioers for**hazardo~** waste samples are compatibility, resistance to breakage, and vohnne. Containers must not me lt, rupture, or leak as a result ofcontact with the waste sample . Thus, it is important to know the characteristics ofth e waste. The containers must bitve adequate wall thickness to withstand handliog duriog sample collection and transport to the laboratory. Contaioers with wide mouths are desirable to ensure 

### the sample is not spilled when placing it in the sample container. Also, the contaioers must be large enough fnr the required volume ofsample. Plastic quart containers are generally used for collection and storage ofhazardollS waste samples at the facility. Glass containers will**be~** when specifically required by waste type. Commonly available plastic containers made ofhigh-density polyethylene or linear polyethylene (LPE) , conventional polyethylene, polypropy lene, polycarbonate, teflon FEP (fluorinated ethylene propy lene), polyvioyl chloride (PVC), or p olymethylpetitene will be used when conditious dictate their use. 

### Z.Z Contaioer Clo$11RS and Closure Linings The samp l e contaioers used by the facility bave tight, screw-type lids . Plastic con taioers are usually provided with screw caps made ofthe same material. Glass

·contaioers are usual.ly provided with gla.'lS or rigid plastic caps. The plastic caps are provided with cbemically inert liners.

C . 6 · 6 

### J AN 1 5 2010 

# OHIO EPA NEDO
VES016462

# c

0·



# c 3. S AMPLING PLAN Heritage - 

## wn, In c. OHD980613541 Revision : 22 November 10 , 2009
The sampl ing plan and container type will be well fonnulated be fore any actual sampling is attempted, when necessary. The plan will be consistent with the objectives of the sampling. It will inclllde the selected point(s ) ofsampling as well as the number, volume, and the type ofsampling equipment to be used Sampling plans are in place and utilized by the Permittee. These general requirements are discussed below. 3.1 Poin t of Samplillg A represen tative sample is cru cial to the sampling plan. The sample depends upon the proper selection ofsampling points in the waste. Hazardous wastes may be homogeoeous, mu ltiphase mixtures or heterogeneous bulk solids . The wastes may be contained and stored in containers ofdifferent sizes and shapes with varying access. No single sampling point can be specified for all types ofcontainers . Table B l ists most types ofcontainers used for hazardous wastes and the corresponding recommended sampling points. Efforts will be made to ma:ximi.ze the number of sample points.



### JA N 

### J.5 1 010 C.6-7 

# OHIO EPA NEDO
VES016463

# 0

ea.. No.

1 2 3 4 

## s 6 7 8 9 10 

### T ABLE D Heritage • 

### WT!, Inc. OliD980613541 Revision: ' 26 June 9, 2010 

### SAMPLING POINTS RE COMMENDED FOR MOST CO NTAINERS Coutaill er Type S IUilPiiq Pola t Drum (bUDg Oil CillO eod) W"llll<lnlw amplolllrou&b ibe 

### boa& opelliQ& 

### collecliD& a**\'Utica~** sample. Dnn (bung Oil side) Lay clnun aalide wiCh bomg up. W"dbdnw -.plo

### tbrouah ibe 

### bom& opailila 

### calJoctiD& a Wll1ical tampl6. 

### Rille lop clnllm, Willldmf &llllp)c 

### tluoup ibe lop ofcmPrin.... Sample 

### -...ticelJJI 

### thro1l811 bacb:b, and limilar · the CCIIIaiDcr IDd It diffeloat poiDis**~iapt•Ily** opposite 1be 

### Jl!lilll of c:atry. ooniliDon B.,a. hoppers, totes, or tlmllar ooolBio.ors Tubr lniCk, vacoum 1n><t, and similar vublcles RDU.ofl'bous, · eocl clumf!c, 

### or similar**I~** Bulk Solid Wute 

### 8unse Tanb (pils) Storqe Tlllk Roll.ofl'bax. eo:! dump ar simlllr container with

# ~·-**~(•lag)** l'Deomatlc tanker or uh tNckwith J:OileriiDr trealmeilt residue (ash) Wl:1bdraw IBIIIplo 

### tbroup fill opeoing. Sample ver1ically lhzough the 00111aiDer and at dlfferen t poiDis diapolly oppooila the poillt of

### eomy. Wllhdmw sample 

### tluoup open 

### balch; sample OSJIWlY staodcd bstcbos u possible. Wheo tanb do not permit sampling from the top,1be IIDk may bo SOIIID!ed ftoon IIIIDI>i lng porta or taps.**~le** front, canler , 111d back ofthe contain« and aoothot I'IAdcm JOCI!loo. Sampl..**will~** ooll=tcd from the fnxll, middle and back or us!Dg a 

### arid pat10n1. Divide smfacc**~a** ioto ao i.map.Ky grid; randomly sample 1ho l[id J*llll'!l; lak>e umples from ourfaoo 1D**ml~** Simple from ICI!lliDI bole"" top or from sampm.g porta 

### alolla 1be oide 06 on tbo bolll:ln oftbo lillie.. Tho lll8Dber ofsomples a flmctioo of tbo IIDDIIII1 o(
....., iD the ll1lk IDd ibeobjective of the tesling (por

### m-a """ cliscnlliol)..) Samples c:oiJoc:led from 1be top ofslag IDOU:Ids. Somples to bo "CCIIIP'>>ikd. See Tobie C fur 1be number of&llllpios 11:> bo collected. Samplca to bo . oolloctod from opeoinp in the froot and bock oftbo CCIIllllieer and lllixl>d In a contai.Derro ptodo>co a eompoai te aample.

C.6-8 

## JAH 

## 14 2011 

# OHI O EPA NEDO

VES016464

# c

I

# ~ 3.2 Number ofSIUIIJ>Iet 

### Herilaie - wri. lDc. . OHD9 8 0613S41 Revision: 26 JUIIC 9, 2010 1'be number ofsamples to!» talceo primarily clcpcuds oo the iDformation clcsiml tmd bomogaleity ofthe "111!1c. Table C lists th.e**~number** ofsample& to!» collected 

### ccmsistem with the illfom>alion sought llld lho types ofwastes to be sainp!ed. Wbon aempling, lho properties llld 1he average cootentrati01111 of the bazardoua COlllpoueots are detired. In this respect, coll ectin& a representati ve aemplc of a given 

### w aste as lodic•ted in the tabl e is adequale . TABLE C NUMBER O F**SAMPL~** TO BE COUBCTJ!.D WuteType - Coatabaer Type NIIGber .tSamplll to be Co lleded HODOIRDI Ollt Type A : LlquldJ Dnm>,tmb,tukcr 0... taDqlio coU.CfOd with Collwua or opea tubo 

## -lor vorti cally lrUtk,uadlimll.tr throughtU caotaiDor. 

# - Type C: Loooo oolicll, lllllll 

### o.-. ..... - Olio ICIIIpia colloclod- Coliwtsa, - Olbo l&mjlia-,

# at- (D

# ~=·orldP~ tmct. 01111 tlmllor opplioolllo per .-ix 11111 /ar ..,.,.;, ). I i IIDII TypeD: Loooo**~.-.** 

### Boa. cln>m, -.or 0...**._~so** of 

### ....rusampl<o colloCIId Ill ditli:rmt 

### lllll!>liDI poila**~** 

### ••U, or 

### .,..,we. dmil.oJ COIIII!ac:D**~tbo** CCIIIIIiDm'boChvet1icoJbl ...Sbarimlllally. S ee Table A for. llll%llplin& eqolpaot oud Table B, C... No. 3 for aompl!as poinlloclllioo<. 

### WaateTn-e - Colltaiaer T ype Nll.lllber ofSamples to 

### be Colleeted lleterGi!meoUI Type ll: Mulllpllue llqoid Ilnml. 

### roc.; Talbr 

### o... c "" obo.....,.. colltclocl tridla 

## eou- ar open lllbe**sa:op~«,** 'INd<...SIImllor
- olowlyll> IIIIJP!eaclll:yu. CCIIIIalam Type E: Solldl Blllk Solld WID Two Ill !l'tC 

## MpC1Ito-"" fiam cWiinot IIIIIIPiillc poiols oud cleptbo. Tlllb(pita)' The llllllli>er of """'Plea collodod buod an tbo- oflllll0ria11D lbe pia md t11o objocdvo of**die~** (per.......,..,_ discmioo). See Table B , C... No . 7, fir IIIIIPu.i;;.J';.i'loc:lliou. Type E: SolldJ - debris, Bag, DnuD, Toto. Bia Two to live acpo101e Tbo Jlllmber ofoomplos cotlecloc! baod oo powdcn, or 

### 8f01111lc• Sod<, M>d oimllu tbo li:a> oflbe ......mcrimd tbo objoctiv6 of**tho~** (pa_.,.o.t

. COIIII!oal c!is=tloQ) . See Tobie A**fir~** eqo!pnw* Uld Table B. Cue Noo. 3 "4 lilr**~** C.6-9 

## JAN 14 

## 201 1 

# OHI O EPA NED O

VES016465

### WuleTyp e- Container Type 

### Heteroteneou 'I)p&l: Solid-l..mp Roll-offbolc<s, CDC! aollc!t ODd clebril, cl=po.or•mwor C<lll>iDers 'I)pe " So-l)>cbmar Ill&>.- -.raiaoc(abgar . 9:$ ill ccmm ub) • .- .. 'ltlllba pamil Typo J: &otido • P'Dtml:latio tanker 1 lDcin ...



# lar- similar OOI!Wnottln reslduo (ub) ' -wlthtbc 

### IDCrmh Typeft Solids-!Dcioul.tor Roll-oft' [20 Cubic 

# tre•- ..mu. (slag) ' yard (CY)) or simibor 

# -- Typo F: So!Jds..IDcin«ator Elld Dump (40 CY) or

- residllo (oil&)" similorOCilllllnm



## .. 3.3 Volumeot Sampla Heritage - \VTI, Inc.

Number of Samples io be Collected OHD980613S41 IU>vision: 26 June 9, 2010

Two 10 ftw scpmtc 

## -l<s from cliflinm &amj)qpoiall. Tbt ulllllber of**~leo** collecled booed Oil tb: si: of tbc COIIbliD<:; llld tbc ol>jeci!Ye ofl!>e 11111yU (per -"- clis=tioo). See Tll>le A far .-plloc¥jpmeul10 bo usocl ood Tlbli>a Case No. 6 far locldaas. O...IIII!Ple- Soo TlhleAfor ._u,cequjpmoot 10 be -llld Tobie B, 

### c;ue No. 4 for 

### me -qpoiat 

### locaiioos. . Ouo co.,.,..lu.oft'!<><> sazples oolledocl from &IIIDJ'lio& botcbaollt Ill fb o lioal audtbcbockof!beeoortama. 0... compoa i to offuur wgples . Tho four IIIDiples pi"""" In a container and mlx..S to produce 

### me**c~alle** samplo. See Table A Cor sampllJI& oquipmcul and Table 8 Cue No. 9 far lbo t oolnt locatl.,._ ODe composlto or six 111111>los. A Jamplc will bo ooUcated tiom Jtoot lO becl< o f tbc C<llllinor (4 samples); tw1l&IIIDJ>lC1 will be collcdtd I'Oildomly. Allsbt samplea ploce4 

### m a COD1>iD« md mlxe<l to proc1u<o tho composite -plo. Soo Table B Cue No .9 !aT . ' ! poiollocatiom A sufliciem vohlme ofa sample,**~ve** ofthe waste, must be collect..t. 'Ibc sample must be adequa!C in size for a**~ ~t~d**  eomp1ete laboratory analysis. In collec1ing liquid waste SIIUlples from chums, tank 1nlcks, or similar containers, the volume collected in the Coliwasa llSIUllly determi""S the vo lmne ofthe sample. This vo

lume canraoge from about 200 to 500 m1 (1/4 qt to 112 qt). Th e Permittee requires a1 l eas t 500ml ( V2 q l ) ofa liquid sample and 1 OOOml**(l~t.)** of a solid sam ple to perform the required 

### tests. Only a small aliquot of the sampl e is . used for aoalysis .

C.6-IO 

## JAN 14 

## 20ft 

# OHI O EPA N EDO

VES0 1 64S6Heritage- WTI, Inc, OHD980613541 Revision: 22 November 10, 2009 3. 4 Sa mpling Preea utions an d P ersonal P rotective Equi pment (PP E) Proper safety precautions must always be observed when sampling hazardous wastes . In all cases, facility persoDDei collectin g a sample are aware that the waste could be a strong sensitizer, corrosi ve, Oanunable, expl osive, toxic, capable of releasing extremely poisonous gases, or any combination ofthose characteristics . The background information is 

### evaluated by facility 

### management and is communicated by the 

### Hazardous Material Information System (HI'v!IS) or a similar type system. Appropriate PPB will beworn by the person collecting the sample. When required, the facility has self-contained 

### breathing apparatus (SCBA) available, consisting of an air-tight face mask coupled to an independent system dedicated to supplying breathing air at all sampling stations. 

# 0 All PPE will be properly washed and cleaned 

### between use or properly discarded by facility personnel, as appropriate.



# c 4. S AMPLING PROCEDURES The following is a summary ofprocedures for sampling 

### waste containers presented in the Perruittee's Chemistry Practice Manual 160: Chemistry Practice 16 1 Type A - Single Phase Liquids Container Sampling Chemistry Practice 1 62 Type B- Multiple Phase Liquids Container Sampling Chemistry Practice 163 Type C - Loose Solids, Small Particles, or High Viscosity Sludge Container Sampling Chemistry Practice 164 Type D - Loose Solids, Large Solids Container Sampling ChCmistry Practice 165 Type E - N on-Homogenous Solid Debris Container**Samp in~**  Chemistry Practice 166 Typo F - Solid Slag Sampling and Compositing



### C.6 -ll 

### JAN 1 5 2010 

# OHIO EPA NEDO
V ES0 1 6467

# 0



# c Heritage - Wfl, Inc. OHD98061354 1 Revision: 22 November 10, 2009 

### These procedures are recommended for sampling different types ofhazardous wastes in various containers 

### and configmations . These procedures exist as a separate SOPs. Please refer to Attachment C . 7 . In addition, specific procedures for sampling liquid tanks are included in Attachment C.8. 5. SAMJ>LE HANDLING

After a sample is transferred into the proper sample container, the container will be tightly capped as quickly as possible 

### to prevent loss ofvolatile components and to prevent possible oxidation from air. 6

. IDENTIFICATION OF SAMPLE ,,1 Sample Labels .

Sample labels for incoming wastes are automatically printed by the compoter system and correspond 

### to tbe individual container. When sampling other materials the sampl e labels will need to be filled ' out by facility personnel to prevent misidentification of samples . The automated label includes the following information: 1) HMIS infonnation; 2) Waste Profile Number; 3) The date the material was unloaded; 4) The 

### manifest docwnent number; 5) The type and size ofcontainer; 6) A facility number 

### which designates the manifest page 

### and line item; 7) A facility ni!Uiber 

### which identifies the truck;



### JAN 1 

### 5 2010 C.6-12 

# OHIO EPA NEDO

VES016468Heritage- WT I, 

### Inc . OHD980613S41 Revision: 22 November 10,2009 8) A facility number 

### which identifies th e sample (currently called an "L-number''); · 9) and the words hazardous waste. The bar code (located on the label) identifying the sample wiU provide access to the following infonnation in the Automated Realtime T racking System (ARTS) database : I) Sample Procedure; 2) Date ofSample; 3) Time ofSampl e; 4) What the sample is to be analyzed for; and 5) Initials ofthe person who colle«ed the sample Ifthe computer tracking system fails, the MIS (Management Information Systems) 

# Q Department will be contacted to correct the problem. All other samples will be labeled with: 1) WasteNaroeorWPS 2) Tan]( or Container ID 3) Date and Tim e 4) Initials ofperson taking the sample



# c C.6-13 

### JAN 15 201 0 

# OHIO EPA NEDO
VES016469

# c

c

c Heritage - WTI, Inc . OHD980613541 Revision: 22 November I 0, 2009 

### 7. D ECONTAMINATION PROCE DURE FOR REUS ABLE SAMP L ING EQU IP MENT I. AU PPE wom for the sampling procedure must be wom for the decontamination procedure . 2 . The employee taking the sample will attempt to remove any excess material from the tool. The excess material will be placed in the following : a. The ori ginal waste container, or b . A satellite aocumulation container . 

### l t is preferable that tho excess be 

### returned to the original waste container. 3 . 

### If necessary, initiate a triple rinse sequence. 4 . Move the tool to the area designated for cleaning, . taking precaution to prevent the sampling too l from leaking waste residual. 5 . Initiate a rinse sequence wilh the sol vent a pproved by compatibility testing. Consult with a Group or Area Manager for proper disposal oftbe rinseate.



### C.6- 14 

### JAN 1 5 2 0

10 

# OHIO EPA NEDO
V ES01 6 470

# c

0

0 Heritage · Wll, Inc. OHD98061354l Revision: 22 November l 0, 2009 

### 8. DECONTAMINATION PROCEDURE FOR DISPOSABLE SAMPLING DEVICES AND EQUIPMENT 1 . All PPE worn for the sampling 

### procedure must bo worn for the 

### decontaminat ion procedure. 2. The employee taking the sample will attempt to remove any excess material from the tooL The excess material 

### will be p laced in 

### the following: 

### a The original waste container, or b. A 

### satellite accumulation container. It is preferable that the excess be retumed to the original waste container. 3. 

### Pack the disposable sampling tool into a satellite accmnulation container. The material will be packed with compatible material. 4 . When the satellite accwnulation container is full, it will be pl aced into inventory.

C.6-15 

### JAN 15 2 0

10 

# OHIO EPA NEDO
VES016471

### i 

## ! 

# •
j et I ATTACHMENT C.7 Heritage- WTI, 

### Inc. OHD980613541 Revision: 22 November 10, 2009
PROCEDURES FOR SAMPLING WASTE CONTAINERS



### JAN 1 5 201n 

# OHIO EPA NEDO
VES016472( -.... 

### \.

. .

..-'



# c

(\ A 1TACBME NTC. 7 PROCEDURES FOR S AMPLING W ASTE C ONT AINER S CHEMISTRY PRACTICE 1 6 1 TYPE A - SINGLE PHASE LIQUIDS C O NTAINER S AMPLIN G GENERAL Heritage- WTI, Inc. OHD9 806 1 3S41 Revision: 22 November 1 0, 2009



## nus procedur e is applicable for sampling single phase liquids in any type ofcontainer. PPB requirements are defined and required as in dicated by the HMIS label. If the container does notbave 

### a legib l e HMIS label, then contact 

### a group or 

### area manager prior to starting this procedure. If required, r efer to procedures for using a Coliwasa or oiher sampling equipmeot and obtaining representative samples provided in Chemistry Practice Manual CPM-140, Waste Sampling - Basic Procedures and Equipment 

## A-**~1** Z PROCEDURE 1. Ensure the following materials are available for sampling. Sample container, high-density polyethylene pint jar with a lid HMlS label for material to be sampled Coliwasa (42" for 

### drums, 60" for tankers) or other sampling equipment Sevecal wipes BUcket S atellite accumulation container 2. Clear all UllDOCOSSary personnel from sampling 

### area. 3. Place a vapor collection hood over con tainer opening . 4 . Connec t the grounding wires to the container.

C.7-1 

### JA N 1 5 ZOIO 

# OHIO EPA NEDO

VES016473

# c

c 5. Open container . Heritage - WTI , Inc. OHD9806 !354l Revision: 22 November 10, 2009 6. Use Coliwasa or other sampling tool that is being used to obtain a representative sample, or samples; 

### tnnsfer sample to 

### sample container. 7 . When sample has been collected, place used Cotiwasa or other sampling e q

uipment that is being used into 

### a satellite accumulation container. 8. Wipe any material fro m sample**con~er** lid threads. Screw lid on sample container. Wipe any material :from sample container exterior. Place used wipes in satellite accumulation container. 

### 9. 10. 11. 12. 13. 14. [fany material 

### was spilled, then clean up spilled material. Place used wipes in satellite accumulation container. Close the container that was sampled. Disconnect tho grounding wires. Place HMIS label on sample container . Perform appropriate comput er functions. Place sample container in a five-gallon bucket to be 

### traDsported to the laboratory. CHEMISTRY PRACTICE 162 TYPE B- MULTIPL E PHASE LIQUID S CONTAINER S AMPLING GENERAl, This procedure 

### is applicable for sampling multiphase liquids. PPE requirements are defined and required as indicated by the HMIS label fftbe container does not have a legible HMIS label, then oontaet a group or area llllll188"< prior to starting this procednrc. lf required, refer to procedures for using a Coliwasa or other s=pl.i.ng equipment that is being used and obtaining representative samples provided in Chemistry Practice Manual CPM- 140, Waste Sampling- BMic Procedures and Equipment. ,/ _ 

### 1 /' 1 - - ftO 

# w to IJ,O.(_, 

# a. L0{1 

## K/6 

# a.. ()(j 

# tit**A/h.~** 

# c; JAN 1.5 

### 2010 C.7-2 

# OHIOEPA NEOn

VES016474

# c Heritage· 

### W11, ln. c. OHD98061354 1 Revision: 22 November I 0, 2009 

### PROC E D

URE I . Ensure the following materials are available for sampl ing.



### 2. 3. 4. 

# s. 6. 7 . 8. Sample containen,**o~** for each expected layer, high-density polyelhylene pint j ars with lids HMlS labels for material to be sampled Coliwasa ( 42 " fur drums,**60 ~**  for tankers) or other sampling equipment Several wipes Bueket Satelli te aocumulation contaiper Clear all Wlllecessary personnel from sernpling area. 

### Place a vapor collection hood over container opening. Connect lhe grounding wires to the container. Open container: Insert the Coliwasa or other sampling equipment as directed by the procedures for u.'ling a Coliwasa. Repeat step 6 for each phase. When samples have been collected, place the used Coliwasa or other sampling equipment in satellite accumnlation container. W'tpe any material from sample container lid threads. Screw lids on sample con!Ainers. Wipe any material from sample container exteriors. Place used wipes in satellite accumulation 

### COillaintr. 

### 9 . If any lllllterial 

### was spilled, then 

### clean up spilled material. 

### Place used wipes in a satellite accumulation container or back into the container being sampled. I 0. Close matcri . al container. 11. Disconnect the grounding wires. 12. Place HMlS label on sample container. 13 . Record any waste composition information when appropriate . 14. Perform appropriate computer functions. IS . Place sample containers 

### in a five--gallon bucket for transportation to the laboratory.

C .7-3 

### JAN 1 6 201 0 

# OHIO EPA NEDO
VES016475

# c

c Heritage- WTI, Inc. OHD980613541 Revision: 22 November I 0, 2009 6. Use sampling auger to extract samples from 3 to 4 locations. Place samples in the sample container. 7 . When sample bas been collected, then decontaminate auger. Place wipes and other disposable auger sampling i tems into the drum being sampled or a satellite accumulation container. 8. W i pe any material from s ample container lid threads. Screw lid on sample container. Wipe any material from sample container e x terior . Place used wipes in the satellite accumulation container. 

### 9 . Ifany material was spilled., then clean up spilled material. Place used wipes into the container being sampled or satellite accumulation container. I 0. Close material container. 11. Dis connect the grounding wires. 12. Place HMJS label on sample container. 13. Perform appropriate computer functions. 14. Record any waste composition information when appropriate. 15. Place sample container 

### in a five-gallon bucket for transportation.



### JAN 1 5 

### 2 0

10 C .?-5 

# OHIO EPA NEDO

VES016476

# 0 CHEMISTRY PRACTICE 164 Heritage- WTI, Inc. OHD98061354l Revision: 22 November 10, 2009
TYPED - 

### LOOSE SOLIDS, LARGE PARTICLES CONTAINER SAMPLING GENERAL This procedure is applicable for sampling loose solids composed oflarge (exceeding 

### 118") particles. PPE requirements are defined and required as indicated 

### by the HMIS label . 

### If the container does not have a legible HMlS label, then

### .,;,n~ group or area manager prior to starting this procedure. / If required, refer to procedures for using an scoop, or mor e appropriate sampling deVice, and . obtaining representative samples, and decontaminating items, provided in Chemistry Practice Manual CPM-140, Waste Sampling- Basic Procedures and Equipment. PROCEDURE 1. Ensure the fullowing materials are available for sampling. Sample container, high-density polyethylene pintjar with a lid HMIS label for material to be sampled Scoop, large trier, or similar tool Several wipes • Bucket Satellite accwnulation container 2. Clear all unnecessary personnel from sampling area. 3. Ifa container (non-bulk) is being sampled, then place a vapor collection hood over container opening. 

### 4. Connect groundiJlg wires to 

### the container. 5. Open container

C.7-6 

### JAN 15 

### 2010 

# OHIO EP A NEDO


# ..**~** V E S0 1 6477( ' 

# '· '



# C ·



# c Heritage · WTI, Inc . OHD980613541 Revision: 22 November 10,2009 6. Use scoop and/or shovel as required to obtain samples from at least 3 different locations (lbree locations when sampling a drum, multip le samples for larger containers. Refer to Ta ble C in Attachment C.6). Place each sample into the sample container. 7. When sampl e has been collected, then decontaminate the equipment Place wipes and other disposable equipment sampling 

### it=s into the dnnn being samplecl 8 . Wipe any material from sample container lid threads. Screw lid on sample container. W i pe any material 

### from sample container ex1erior. Place used wipes in the satellite accumulation container. 

### 9. 10 . 11. 1 2 13 . 14. 15. Ifany materi.al was spilled, then clean up spilled malcrial. Place used wipes into the container being sampled . Close material container. Disconnect the grounding wires. Place HMIS label on sample container. Perform appropriate computer functioM. 

### Record 

### any waste composition 

### informa . tion when appropriate. · Place sample container in a fi.v&-galloo bucket for transportation.

C.7-7 

## JAN 1 6 201n 

# OHI OEP A NEL'O

VE5016 4 78

# 0



# c CJIEMISTRY PRAcriCE 16S Heritage - WTI, I nc . OHD980613541 

### Revision: 22 November 10,2009



### TYPE E- NON- HOMOGENEOUS SOLID DEBRIS CONTAINER SAMPLING G:tNERAL 1bis proced ure is 

### applicable for 

### sampling DOn-hc;>mogeneous debris . PPE reqaitrmeo.ts are defined and required as 

### ind. icated by ihe HMJS label. Ifthe container 

### does not ba ve a 

### legible HMJS 

### label, then 

### contact a group 

### or area manager prior to 

### SUrtiog this procedure. 

### If**req~ed,** 

### refer to procedures for obtaining samples and decontaminating items, 

### provided in Chemistry Pxaetice Manual CPM-140, Waste Sampling· Ba.,ic Procedures and Equipment

### PROCEDURE I. Ensure 

### the following materials are available for sampling_ Sample 

### contAiner, high-deosity polyethylene j ar (suitable siu) 

### with a lid 

### HMIS label for material to be 

### S3111pled Scoop SevCBI 

### wipes Buclcet Satellite BCCUillUiation cootainer 

### 2. Clear aU unnecessacy perso nnel from sarupling area. 3. If feasible, then p lace 

### a vapor collection hood over container opening. 4 . Connect grounding 

### wires to the 

### container. 5. Open 

### container. NOTE: 

### Since the waste may be 

### composed of various types of debris (e.g_, paper, gloves, wood). Tbe 

### sample may not be 

### representative of all 

### material io 

### the container. NormaUy, a scoop and/or shovel is sufficient for 

### obta.iniog a sam ple.



### JAN 1 

### 5 2010 

# OHIO EPA NEDO
VES016479

# c Heritage- WTl, fnc. OHD9806 13541 Revision: 22 November I0, 2009 6. Use 

### scoop and/or shovel as required to obtain samples from at least 3 differen t locations (three locations when sampling a drum, multiple samples for larger containers. Refer to Table C in Attachment C.6). Place each sample into the sample container. 7 . When sample has been collected, then decontaminate equipment Place wipes and other disposable equipment samp ling items into the drum being sampled or satellite accumulation container. 8 . Wipe any material from sample container lid threads. Screw lid on sample container. Wipe any material from sample container exterior. Place used wi pes 

## in the satcllite accumulation container. 9. Ifany material was spilled, then clean up spilled material. Place used wipes into the container being sampled or satellite accumulation container. I0. Close ma terial container. II . Disconnect the grounding wires. 12. Place HMIS label on sample container. · I 3 . Perform appropriate computer functions.

14. Record any waste composition information wben 

### appropriate. 15. Place sample container in a five-gallon bucket for transportation.

C .7-9 

## JAN U 2010 

# OHIO EPA NEDO
VES016480

# c

0



# c Heritage - WTI, Inc . OHD980613541 Revision: 22 November 10, 2009
CHEMISTRY PRACTICE 166 TYPE F- SOLID SLAG SAMPLING AND COMPOSITING

. GENERAL

This procedure is applicable for sampling incinerator slag. lncinecator slag drops into the quench tank, where the slag solidifies. The quench tank conveyor txansports slag to a roll offbox: . PPE requirements are safety glasses, nitrile or viton gloves, and a hard hat when obtaining sample. 

### If requited, r efer to procedures for obtaining representative samples, provided in Chemis try Practice Manual CPM-140, Waste Sampling- Basic Procedures and Equipment. PROC EDURE I. Ensure the following materials are available for sampling. Sample container, high-density polyethylenejar (suitable size) wi1h a lid HMIS label for material to be sampled Scoop Severa l wipes Two buckets 2. · Use a scoop to obtain a sample ofslag. For 20 cubic yard roll-offoontainers take 4 samples, I 

### from the front, middle, and rear ofthe box . A forth sample must 

### be pulled randomly from the box. All 4 samples should be placed in a bucket and mixed to produce I composite sample. For end-dumps and 40 cubic yard roll-offoontainers take 6 fixed samples (approximately every 3 feet) and 2 random samples to placed into a bucket and mixed to produce 1 composite sample. 3. Place a oomposite of the samples into a single sample oontainer. Extra sample must be txansferred 

### from the bucket back into the roll-off or end dum p.

C.7-10 

### JAN 15 2010 

# OHIO EPA NEDO
VES016481

# c

0 Heritage - 

### Wfl, Inc. OHD 9806 13 541 Revision : 22 November I0, 2009 4 . When samp l e has been collected, tben decontaminare equipmenL Place wipes and other disposabl e equipment szmpling items into lhe drum being smnp led or satellite accumulation container. 5 . Wipe any •u.alerlal from sample container li d threads. Sc r ew lid on sample container. 

### 6. 

### 7. 8. 9. 10 . Wtpe any material from sample container exterior. Place used w ipes in the sa tellite accumulation container. If

any material was spilled, then clean up spilled materi al . Place used wipes into the containe:- beiog sampled or satellite a.ccumull>.lion containtt. Place HMIS label on sample container. Perform appropriare computer functions. Record any waste composition information, when app ropriate. Place sample container in a five-g;illon bucket for transportation.

C .7-ll 

### JAN 15 ZOIO 

# OHIO EP A NEDO
VES016482

# c

c . ATTACHMENT C.8 Herilage - WTI,lnc. OHD980613S41 Revision: 22 

### November I 0, 2009 SAMPLING PROCEDURES FOR LIQUID TANKS AND PROCESS LINES



### JAN 15 2010 

# OHIO EPA NEDO
VES016483ATTACBMENT C .8 Heritage- WI1 , Inc. OHD980613541

. Revision: 22 November I 0, 2009 S AMP L ING PROCEDURES F OR LI Q UID T ANKS AND PROCESS LINES . CHEMISTR Y P RACTI C E lll S AMP LIN G PROCEDURES FOR VARIOUS LIQUID T Al'o'KS AND PROCESS LINES P URP OSE Tlus procedure provides instructions for sampling tanks and process lines in order to obtain samples for analyses as desired by the laboratory. GENERAL Samples arc obtained and analyted for various &cility pwposes. For the storm water tanks, proCedure WT-200, Q jschar:ging B Water Tanks, will be reviewed prior to the initiation of the req11ired sampling. Specific instructions for obtaining samples for discharge analyses are included in t he procedure. 

# Q When using ladders, then f ollow Safety Standard 

### SIS, Ladders.



# C · P R

OCEDURE I. Ensure tlle following materials are available for sampling. Routine Safety Equipment Hardhat Safety glasses Sampling Material Samplebottle, at least I 00 mL, plastic or glass as indicated by laborotory 2 . Go to the appropriate taok or process line to obtain the sample. 2.1 Purge at least I gallon of material through sam p le line into a sump. Sources that are stagnan t will need to flow at least I minute to allow for good sample . 2.2 Obtain samp le in sample bott l e . Label bottle with the following. WasteName orWPS Tank or Process Line lD Number Date and Tune Initials of the person doing tho sampling 3. Talce sau>ple to lab and recoJd date, time, and taok sampled into the l aboratory log book. C.B-1 

### J A

N 1 5 

### 2010 

# OHIO EPA NEDO VES016484

### (' \,. .

CHEMISTRY P RACT I CE U2 TANK FARM ORGANIC TANK SAMPLING PlJRPOSE Heritage - WI1, Inc. OHD980613541 Revision: 22 

### November I 0, 2009

This procedure provides instructions for sampling tanks in the Organic Tank Farm . GENERAL**Routine~amples** for compatibility are obtained in accordance with 

### procedure OTF-11 0, Tllllk to Tank Transfer. This Chemistry Practice 122 is used to obtain a tank sample when needed for any reason, as determined appropriate by Group Manager or Laboratocy per.;oooel. Contact a group or area manager prior to starting this procodure fur proper PPE requirements. Wb . cn using ladders, then foll o w Safety Standard S 15, Ladders . 

# C Usc 

### lifting device (bucke t) to raise and lower samples. P'ROCEDURE 1. Obtain the following sampling equipment: • One quart wide mouth sample container for each 

### tank sampled Absorbent mat and wipes Water resistant blaclc marlter 2. Using the 

### marker, print on the sample bottles the following data. Tank:# Date Initials ofthe person taking the sample 3. Obtain and wear appropriate PPE. 4. Verify location and operation ofsafety shower. 

### N!ITE: A buclcet with an attached rope is located at the bottom of the sampling platform . 

### 5. Place sampling materials into the bucket

C.B-2 

### JAN 

## 1 5 2010 

# OHI O EP A NEDO
VES 01648 5

# c

e

e 6. Climb ladder to designated tank sam pling pl atform. 

### 7. Raise bucket 

### to sample platform. 8. Extract sample from sample port on the side oftank. 9. Clean up any spills . I 0. Return sample bucket to floor . I I. Take sample or samples to Laboratory. Heritage • 

## wn , Inc. OHD980613541 Revision: 22 November 10, 2009

12. Place all contaminated PPE and wipes into a satellite accumulation container.

C.8-3 

### JAN 15 

### 2010 

# OHIO EPA NEDO
VES016486

# •
•
• ATTACHMENT 

### C.9 Herilllge- WTl, Inc. OHD980613541 Revision: 22 

### November 10, 2009 SAMPLING EQUll'MENT AND METHODOLOGIES



### J A N 1 

### 5 ZIJ\0 

# OHIO EPA NEDO
VES016487

# ('

A TTACHMENT C.9 Heritage - Wfl, Inc. OHD98061354 1 Revision : 22 November 10;2009 S AMPLING E Q UIPMENT AND METHODOLOGIES GENERAL R UL ES FOR SAMPLIN G I) Most sampling equipment will be 

### used once and discarded in proper satellite , accwnula tion containers. 2) Wear proper personal protective equipment (PPE) for all sampling activities . 3 ) Seal and labe l all sam pling containers . 4) All sampling tools 

### that are to be reused i. e . trim, scoops, auger, sbovet, waste pile samplers, weighted bottles and dippers are 

### to be plaud in a container to avoid \llllleCeSSary 'spilling' ofwaste. The Permittee may cho ose to decontaminate reusable tool 

### if warranted. S AMPLING EQUIPMENT Sampling ofhazardouswastes at the facility requires the use of several 

### different types oftools. This section lists and describes suitable tools, their availability, as well as directions for their proper use . 1. COLIWASA D esc riptio n The Coliwasa is one of two types of sampling equipment used extensively at the facility . It has been chosen from a number of other liquid sampling tools based upon laboratory and field applications . It is a practical, 

### easy to use, effective sampling device. It will permit th e representative sampling ofmultiphase wastes of a wide range of viscosity, oorrosivity, volatil ity, and solids content Its simple design allows the rapid collection of samples, thus minimizing th e exposure ofthe sampler 

### to potential hazards from the wastes. Typically, a single-use, disposable Coliwasa will be utilized. Coliwasa 

### that are contaminated will be incinerated . A typical Coliwasa is shown in Figure I . The main parts of the Coliwasa consist ofa sampling tube, a closure-locking mechanism, and the closure system .

C.9-l 

### JAN I 5 2010 

# OHIO EPA NEDO
VES016488Uses Heritag e- 

### W'TI , Inc. OH0980613S41 Revision: 22 November 10, 2009 Th e plastic Coliwasa will be used to sample most bulk liquid wastes except for those wastes 

### that contain high 

### COllCUllra tioos ofketones, nitrobenzene, dimethylfoJlllamide, mesityl oxide, and tettrabydrofuran . Proeedu e for Use I. Choose !be plastic tube for the liquid 

### waste to be sampled and assemble the Coliwasa as shown in**fi~** I. 2. Make 

### suxe that the Coliwasa is clean. 3. Check to make sure the Coliwasa is functioning properly. Adjust th e lockiog mechanism ifnecessary to make sure the neoprene rubber stopper provides a tight closure. 4. Wear recommended PPB and observe required sampling precautions. S. Put the Coliwasa in the open position by plscing the stopper rod han d

le in the T-position and pushing the rod down until the handle sits against the ,-.... Co!iwasa's locking block. '- 6. Slowly lower the Coliwasa into the liquid waste. (Lower the Coliwasa at a rate that permits the lev els of the liqruds inside and outside the Coliwasa tube to be about the same, lftbe level of the liquid in the sampler 

### tube is lower 

### than that outside the tube, the sampling rate is too fast and will result in a nomepreseD!ative sample). · . 7. When tbeColiwasa stopper hits tbe bottom ofthewaste oon. tainer , push the sampler tube downward Bg$inst the stopper to close the Coliwasa. Loclc the Coliwasa in lhe closed position by turning the T handle until it is upright and one end rests tightly on the lockmg block. 8. Slowly withdraw the Coli

### was a from tbc waste container with one hand while wiping the tube with a disposable cloth or 

### rsg with the other hand. 9. Carefully discharge the sample into 

### a suitable sample container by slowly opening the Coliwasa . This is done by slowly pulling the lower end ofthe 

### T handle away from tho locking block while the lower end ofthe. Coliwasa is positioned in the sample con. tainer. 

### I0. Cap the sample container; attach label and seal . 11. Place Coliwasa (If not being re-used), paper towels, and any waste rags into the 

### satellite accumulation coatainer. 12. Deliver the sample to the laboratory fur analysis.
C.9-2 

## JAN 1 

## 5 ZOIO 

# OHIO EPA NEDO
VES01648 9

# c

c Fisrure 1 C OLIW ASA SAMPLER- not t o sca l e**~** :rr . 

## " " 

### " 

## " 

# .. .. " " Sampling : . : Po$Uion : : 

### " 

# .. Stopper 

# -H ! Rod " 

# .. 

# .. " 

### " 

## " 

# .. THandle 

## A 

# Looklng- j !l\ 

# l Block I . 

### • • 

### •• ' •

(: :\Tape red 

# Ldtr1 Stoppe r 

# .. 2. O PEN T UBE SAMPLER Oosed Position**~** Tl'llpped Sample
Description . Heritage • WTI, Inc. OHD980613541 Revision: 22 November 10,2009

The open tube sampler is another versatile liquid sampler- that lhe**~cility** will use in a wideT811ge of applications. Its ' relatively low cost and ease of operation make it an attractive sampling tool. It is a hoUow plastic 

## tul!e, usuaUy 4 

### feet long, with an internal diameter of 0.25 to 0.50 inches, depeDding on the viscosity of the sample . These tools have a constricted orifice at 

### the top ofthe tub e in order to facilitate plugging the opening to maintain a vacuum in the tube .



### C.9-3 

### JAN 1 5 70 "' 

# OHIO EPA NE DC
VES016490

## 0 . '-.._./ Uses Heritage • WTI, 

### Inc. OHD98061354l Revision: 22 November 10,2009
The Open Tube Sampler will be 

### used to sample liquid and slu dge drummed wastes. Procedures for Use l. Choose an open tube sampler ofthe 

### proper length for the waste to be sampled, i.e. small container, 

### dnun, and large container or tank truck. 2. Make sure the open tube samp l er is clean. 3 . Wear recommended PPE and observe sampling precautions. 4 . Slowly lo wer the tube into the liquid waste. (Lower the tube at a rate that pennits the levels of 

### the l iquid inside and outside the tube to be about the same. 

### If the level oftbe liquid in the tube is lower tluui that outside the tube, the sampling rate is too fast and will result in a nonrepresentative sample) . S. When the tube is insert ed to the desired depth, stopper the tube with a rubber stopper, thumb, or by creasing a piece· of flexible tubing attached to the open end ofthe open tube sampler. This is done to establish a vacuum in the tube, t hereby enabling 

### withdrawal of the sample from the container. 

### 6 . 

### 7. 8. 9. 1 0. Slowly withdraw the tube from the waste container with one hand wbile wiping the tube with a disposabl e cloth or rag with the other hand. Carefully discharge the sample into a suitable sample container by slowl y opening the tube. Cap the sample container ; attach l abel and seal. Place sampling tube (ifnot being re·used), paper towels or waste 

### rags into a s atellite accumulation container. Deliver the sample to the la boratory for analysis.

C.9-4 

### JAN 1 5 

### 2010 

# OHIO EPA NEDO
VES016491Heritage - 

### Wfi, Inc . OHD98061354 1 Revision: 22 November 10, 2009 3. S AMP LING TRI E R D escription A typical sampling trier, as shown in Figure 2, is along tube with a slot that extends almost its entire length. The tip and edges of the tube slot are sh81Jlened to allow the trier to cut a core of the material to be sampled when rotated after insertion into the ma terial. Sampling triers are usually made ofstainless steel with wooden handles . They are about 6 1 to 100 em (24 to 40 in.) long and 1.27 to 2 .54 em (112 to 1 in.) in diameter. They can be purchased readily from laboratory supply houses. 

### Uses The sampling trier is used for sampling powdered or granular wastes or materials in bags, fiber drums, sacks, or similar containers. In addition, the sampling trier can be used to obtain samples ofmoist I sticky waste and soft or loosened waste soil up to a depth of61 (-', em (24 in.) as outlined below. \.._/ Procedure for Use I . Insert the trier into the waste material at a 0 to 45 degree angle from horizontal . This orientation minimizes the spillage of sample. Extraction of samples might 

### require tilting of the container. 2 . Rotate the trier once or twice to cut a core ofmaterial. 3. Slow ly withdraw the tri er, making sure that the slot is facing 

### upward . 4 . Ttansfer the sample into a sui table sample container with the aid ofa spatula and/or blUsh. 5. Repeat the sampling at different points, two or more times, and combine the sainples in the same sample container. 6. Cap 

### the samp l e container; attach the labe l and seal . 7 . Wipe the trier clean, and store it in a plastic bag for subsequent cleaning. 8. Deli ver the sample to the laboratory for analysis.

C.9-5 

### JAN l5 2010 

# OHIO EPA NEDO

V ES01 649 2

# c

0



# c Pi e2 SA. '\fPLING TRIER - n ot to scale

4. TROWEL OR SCOOP (HAND S HO VEL) D escription Heritage - WTI, I nc. OHD98061354 1 Revision: 22 November 10, 2009

· A garden-variety trowel looks like a small shovel (Figure 3). The blade is usually about 7 by 13 an (3 by 5 in.) with a sharp tip. A laboratory scoop is similar to the trpwel, 

### but t h

e blade is usually more curved and has a closed upper end to permit the containment of material. Scoops come in different 

### sizeS and makes . Stainless steel or polypropy1ene scoops w ith 7 by 15-cm (2-3/4 by 6-in) blades are preferred. A trowel can be bought from hardware stores; the scoop can be bought from laboratory supply houses. 

### Uses An ordinary zinc-plated garden trowe l can be used in some cases for sampling dry granular or powdered materials in**b~** or other shallow containers . The laboratory scoop, however, is a superior choice. 

### It is usually made ofmaterials less subject to corrosion or chemical reactions, thus lessening the probability of sample contamination. The trowel or scoop can also be used in collecting top surface soil samples .

C9-6 

### JAN 1 5 

### 2010 

# OHIO EPA NEDO
VES016493

# 0 5 .



# c Procedure for Use Heritage- WTI, Inc. OHD980613541 Revision: 22 November 1 0,2009 I . At regular intervals, take small , equal portions o f sample from the surface or near the surface of the malerial to be sampled. 2. Combine the samples in a suitable sample container. 3. Cap the container; attaclllhc label and seal. 4. Wipe the tool clean and store it in • plastic bag for subsequent cleaning. 

### 5. Deliver the sample to the lllbonrtory for analysi s. Fi 3 TROWEL O R SCO OP, WITH CALffiRATIO NS- n ot to scal.e

WAS TE PILE S AMPLER D escription A**~aste** pile sampler (Figure 4) is essentially a large sampling trier. It is commercially available, but it can be easily fabricated from sheet mclal plastic pipe. A polyvinyl chloride p lumbing pipe 1.52 m (5 ft) long and 3.2 em ( 1-1/4 in.) in diameter with a 0.32 an (1/8 in.) wall thiclcness is !be typical size. The pipe is shaved lengthwise (about 6<V40 split) until !be last 10 em (4 in.). The narrower piece is sawn off and forms a slot 

### in the pipe. The edges ofthe s lot and the tip ofthe pipe are sharpened to permit th e sampler to cut into the waste material bein g sampled. The unsplit length ofthe pipe serves as the handle. The plastic pipe can be purchased from hardware stor e.q.



### JAN 

### 1 5 2010 C.9 - 1 

# OH IO

# EPA NEDO

VES0 1 6494

# 0

0 Uses Heritage - WTI, Inc. OHD980613541 Revision: 22 November I 0, 2009 The waste pile sampler is used for sampling wastes in huge heaps with cross-sectional diameters greater than I m (39.4 in.). It can also be uSed for sampling granular or powdered wastes or materials in huge bins, or pits where a sampling trier is not long enough. This sampler should only be used to collect samples when the diame ter ofthe 

### solid particles is less than halfthe diameter of the tube . Because the facility typically would not have large heaps , bins, or pits of waste to sample, it is used infrequently. Procedure for U se 1. 

### Insert the sampler into the waste material being sampled at 0 to 45 degrees from horizontal . 2 . Rotate the sampler two or three times in order to cut a core ofth e material. 3. Slowly withdraw the sampler, making sure that the slot is facing upward. 4. Transfer the sample into a suitable container with the aid ofa spatula and/or brush. 

### 5. Repeat the sampling at different sampling points two or more times · and combine !he samples in the same sample container in step 4. 6. Cap the 

### cOntainer, attach label and 

### seal. 7. Wipe the sampler clean and store it in a plastic bag 

### for subsequent cleamng. 8 . Deliver the sample to the laboratory for analysis . Figure4 W AS TE PIL E SAMPLER - n ot t o sca l e 

# (

C.9-8 

### JAN 1 5 2010 

# OHIO EPA NEOO

V E S 0164 9 5

# 0

6.



# 0

0 Heritage - WTI, Inc. OHD9806135 4 1 Revision: 

## 22 November 10, 2009 

### DIPPER SAMPLER Description The dipper sampler (Figure 5) consists ofa glass or plastic**beak<:~:** clamped to the end of a 2 or 3 piece telescoping aluminum or fiberglass pole, which serves as the handle. Uses Dipper samplers are used to sample liquids and free-flowing slunies . Diw= are not available commercially and 

### must be fabricated to confonn to desired specifications . 

### This type ofsampling equipment is rare l y used at the facility. P rocedlll'CS for 

### Use 1. Clean beaker, clamp, handle. 2. Assemble dipper by bolting adjustable clamp 

### to fue pole . Place beaker in clamp and fasten shut. 3 . Tum dipper so the mouth of the beaker face s down and insert into waste material. Tum beaker right side 

### up when dipper is at desired depth. Allow**beak<:~:** t o fill completely as shown by cessation of air bubbles . 4. Raise dipper and transfer t o sample container. 5 . Cap the container; attach 

### label and seal. 6. Wipe the sampler clean ·and store it in a plastic bag for subsequent cleaning. 7. Deliver the sample to the laboratory . for analysis. 

### Preeauttons I. 

### 2 . 3 . Do not use a nonfluorocaibon plastic beaker to sample wastes containing organic materials . . Do not use a glass beaker to sample wastes ofhigh pH or wastes that contain bydrolluoric acid. Paint aluminum pole and clamp with a 2-part epoxy or other chemicalresistant paint 

### when sampling either alkaline or acidic wastes.



### 'JAN l5 2010 C .9-9 

# OHIO EPA NEDO

VES016496

# c

0



# c FigureS DIP PER SAMPLE R - not to seale Heritage- 

### wrr, Inc. 

### OHD9806135 4 1 Revision : 22 November I0, 2009

# ~~~~=========T~e~le~sco~p~ln~g~P**~l e~~~** **~~ ~~**  Beaker 7. AUGER Descr:lption An auger consists ofslwpened spiral blades attaclled to a hard metal ceotral shaft (Figure 6). 

### U

ses

The auger will be used to sample hard packed solid wastes and soil. Augers are available at hardware and laboratory supply stores . Procedure for Use I. Clean sunpla:. 2. Bore a hole through the middle of**anal~** pie pan large enough to allow lhe blade ofthe auger to pass through. The pan will be used to catch . the sample brought to the surface by the auger. 3. Place pan against the sampling 

### point. Auger through the hole in the pan unJiJ the desired sampling depth is reached. Back offthe auger and transfer the sample ofthe waste that is in the pan to the sample conlalner. Transfer the rest of the loosened sample from tbe pan and the auger with 

### a. sam ple trier into tlie sampling container. 4. Cap the container; attach label and seal. S. Wipe the sampler clean 

### and store it in a plastic bag for subsequent cleaning. 6. Deliver the sample to the laboratory for analysis.

C.9-10 

### JAN 1 

### 5 2010 

# OH IOEPA NEDO VE$ 0 1 6497

# c:

AUGER SAMP L ER· not to scale



# 0

C.9-ll Heritage • WTI, Inc. 

### OHD9806!3541 Revision: 22 

### November 10, 2009



### JAN 1 5 

### 2010 

# OHIO EPA NEDO
VES016498

# 0


# •

0 ATTACHEMENT C. l O COMPATIBU..ITY OPERATING GUIDELINES Heritage • 

### wrr, Inc. OHD980613541 Revision : 22 

### November 10, 2009



### JAN 15 

### 2010 

# OHIO EPA NEDO
VES016499