Table 1

ALCOA EAST OPERATIONS

Line 3

Massena, NY

Run Identification Run 1 - XAD ID: T1667-001 Run 2 - XAD ID: T1667-002 Run 3 - XAD ID: T1667-003 Average

Run Date 30Apr13 30Apr13 01May13

Start/Stop Time 1002/1418 1455/1911 0825/1230

Exhaust Gas Conditions

Temperature (deg. F) 77 91 94 87

Moisture (volume %) 0.9 0.7 0.7 0.7

Oxygen (dry volume %) 20.90 20.90 20.90 20.90

Carbon Dioxide (dry volume %) 0.00 0.00 0.00 0.00

Volumetric Flow Rate

acfm 2,539 2,662 2,610 2,604

dscfm 2,475 2,522 2,470 2,489

Total Particulate Matter

gr/dscf #DIV/0! #DIV/0! #DIV/0! #DIV/0!

 lb/hr #DIV/0! #DIV/0! #DIV/0! #DIV/0!

Parameter??

mg/dscm 0.00E+00 0.00E+00 0.00E+00 0.00E+00

lb/hr 0.00E+00 0.00E+00 0.00E+00 0.00E+00

Parameter??

mg/dscm 0.00E+00 0.00E+00 0.00E+00 0.00E+00

lb/hr 0.00E+00 0.00E+00 0.00E+00 0.00E+00

Parameter??

mg/dscm 0.00E+00 0.00E+00 0.00E+00 0.00E+00

lb/hr 0.00E+00 0.00E+00 0.00E+00 0.00E+00

Parameter??

mg/dscm 0.00E+00 0.00E+00 0.00E+00 0.00E+00

lb/hr 0.00E+00 0.00E+00 0.00E+00 0.00E+00

Parameter??

mg/dscm 0.00E+00 0.00E+00 0.00E+00 0.00E+00

lb/hr 0.00E+00 0.00E+00 0.00E+00 0.00E+00

Parameter??

mg/dscm 0.00E+00 0.00E+00 0.00E+00 0.00E+00

lb/hr 0.00E+00 0.00E+00 0.00E+00 0.00E+00

C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\4321353822904480646\09000064819454fb
Method	23-Data	Summary

ALCOA	EAST	OPERATIONS

Line	3

Massena,	NY

Run	1	-	XAD	ID:	T1667-001 Run	2	-	XAD	ID:	T1667-002 Run	3	-	XAD	ID:	T1667-003

Traverse Stack Delta Delta Tm(F) SQRT Stack Delta Delta Tm(F) SQRT Stack Delta Delta	 Tm(F) SQRT

Point Temp(F) P H in out Delta	P Temp(F) P H in out Delta	P Temp(F) P H in out Delta	P

1 62 0.48 1.26 55 55 0.6928 91 0.48 1.26 65 66 0.6928 86 0.48 1.26 59 55 0.6928

1 62 0.48 1.26 55 55 0.6928 91 0.48 1.26 65 66 0.6928 87 0.48 1.26 60 55 0.6928

1 62 0.48 1.26 58 55 0.6928 91 0.48 1.26 67 66 0.6928 88 0.48 1.26 63 56 0.6928

1 62 0.48 1.26 59 55 0.6928 91 0.48 1.26 69 66 0.6928 88 0.48 1.26 65 58 0.6928

1 62 0.48 1.26 61 56 0.6928 91 0.48 1.26 70 66 0.6928 89 0.48 1.26 66 59 0.6928

1 62 0.48 1.26 62 56 0.6928 91 0.48 1.26 70 66 0.6928 89 0.48 1.26 67 60 0.6928

2 62 0.42 1.10 63 57 0.6481 91 0.50 1.32 71 66 0.7071 90 0.51 1.34 69 61 0.7141

2 62 0.42 1.10 64 57 0.6481 91 0.50 1.32 71 66 0.7071 90 0.51 1.34 69 61 0.7141

2 62 0.42 1.10 65 57 0.6481 91 0.50 1.32 71 66 0.7071 90 0.51 1.34 69 62 0.7141

2 62 0.42 1.10 66 59 0.6481 91 0.50 1.32 70 67 0.7071 91 0.51 1.34 70 63 0.7141

2 62 0.42 1.10 66 60 0.6481 91 0.50 1.32 72 67 0.7071 91 0.51 1.34 70 63 0.7141

2 62 0.42 1.10 66 60 0.6481 91 0.50 1.32 72 67 0.7071 92 0.51 1.34 71 64 0.7141

3 62 0.50 1.32 67 60 0.7071 91 0.56 1.47 71 67 0.7483 92 0.50 1.32 71 65 0.7071

3 62 0.50 1.32 68 61 0.7071 91 0.56 1.47 72 67 0.7483 91 0.50 1.32 71 65 0.7071

3 62 0.50 1.32 68 61 0.7071 91 0.56 1.47 73 67 0.7483 91 0.50 1.32 72 65 0.7071

3 62 0.50 1.32 68 62 0.7071 91 0.56 1.47 73 67 0.7483 92 0.50 1.32 73 66 0.7071

3 62 0.50 1.32 68 62 0.7071 91 0.56 1.47 73 67 0.7483 92 0.50 1.32 73 66 0.7071

3 62 0.50 1.32 68 62 0.7071 91 0.56 1.47 73 67 0.7483 92 0.50 1.32 73 67 0.7071

4 62 0.50 1.32 68 62 0.7071 91 0.48 1.26 73 68 0.6928 90 0.53 1.39 73 67 0.7280

4 62 0.50 1.32 69 63 0.7071 91 0.48 1.26 73 68 0.6928 92 0.53 1.39 73 67 0.7280

4 62 0.50 1.32 69 63 0.7071 91 0.48 1.26 74 68 0.6928 92 0.53 1.39 74 68 0.7280

4 62 0.50 1.32 69 63 0.7071 91 0.48 1.26 73 68 0.6928 92 0.53 1.39 74 68 0.7280

4 62 0.50 1.32 69 64 0.7071 91 0.48 1.26 73 68 0.6928 92 0.53 1.39 74 68 0.7280

4 62 0.50 1.32 70 64 0.7071 91 0.48 1.26 73 68 0.6928 93 0.53 1.39 74 69 0.7280

1 91 0.46 1.21 67 64 0.6782 91 0.51 1.34 69 68 0.7141 94 0.46 1.21 72 69 0.6782

1 91 0.46 1.21 70 65 0.6782 91 0.51 1.34 70 68 0.7141 95 0.46 1.21 74 70 0.6782

1 91 0.46 1.21 72 65 0.6782 91 0.51 1.34 71 68 0.7141 95 0.46 1.21 74 70 0.6782

1 91 0.46 1.21 73 66 0.6782 91 0.51 1.34 72 68 0.7141 96 0.46 1.21 74 70 0.6782

1 91 0.46 1.21 74 67 0.6782 91 0.51 1.34 73 68 0.7141 96 0.46 1.21 75 70 0.6782

1 91 0.46 1.21 75 67 0.6782 91 0.51 1.34 73 68 0.7141 96 0.46 1.21 75 70 0.6782

2 91 0.50 1.32 76 68 0.7071 91 0.56 1.47 73 68 0.7483 97 0.51 1.34 75 71 0.7141

2 91 0.50 1.32 77 68 0.7071 91 0.56 1.47 73 68 0.7483 97 0.51 1.34 75 71 0.7141

2 91 0.50 1.32 78 70 0.7071 91 0.56 1.47 73 68 0.7483 97 0.51 1.34 76 71 0.7141

2 91 0.50 1.32 78 71 0.7071 91 0.56 1.47 74 68 0.7483 98 0.51 1.34 76 71 0.7141

2 91 0.50 1.32 79 71 0.7071 91 0.56 1.47 73 68 0.7483 98 0.51 1.34 76 71 0.7141

2 91 0.50 1.32 80 72 0.7071 91 0.56 1.47 73 68 0.7483 98 0.51 1.34 76 72 0.7141

3 91 0.56 1.47 79 72 0.7483 91 0.54 1.42 72 68 0.7348 98 0.50 1.32 77 72 0.7071

3 91 0.56 1.47 79 73 0.7483 91 0.54 1.42 73 68 0.7348 98 0.50 1.32 77 72 0.7071

3 91 0.56 1.47 80 73 0.7483 91 0.54 1.42 73 68 0.7348 98 0.50 1.32 77 72 0.7071

3 91 0.56 1.47 77 73 0.7483 91 0.54 1.42 73 68 0.7348 99 0.50 1.32 77 72 0.7071

3 91 0.56 1.47 76 72 0.7483 91 0.54 1.42 73 68 0.7348 99 0.50 1.32 77 73 0.7071

3 91 0.56 1.47 77 72 0.7483 91 0.54 1.42 72 68 0.7348 99 0.50 1.32 77 73 0.7071

4 91 0.48 1.26 76 72 0.6928 91 0.53 1.39 72 67 0.7280 97 0.50 1.32 78 73 0.7071

4 91 0.48 1.26 76 72 0.6928 91 0.53 1.39 72 67 0.7280 97 0.50 1.32 78 73 0.7071

4 91 0.48 1.26 76 72 0.6928 91 0.53 1.39 72 67 0.7280 98 0.50 1.32 78 73 0.7071

4 91 0.48 1.26 75 71 0.6928 91 0.53 1.39 73 67 0.7280 97 0.50 1.32 78 73 0.7071

4 91 0.48 1.26 74 71 0.6928 91 0.53 1.39 72 68 0.7280 97 0.50 1.32 79 73 0.7071

4 91 0.48 1.26 74 71 0.6928 91 0.53 1.39 72 68 0.7280 97 0.50 1.32 79 74 0.7071

Average 77 0.49 1.28 70 65 0.6977 91 0.52 1.37 72 67 0.7208 94 0.50 1.31 73 67 0.7061

Laboratory	Data Run	1 Run	2 Run	3

Filter	ID

Front	Half	Sample:

Filter	wt,	g

Acetone	rinse	volume,	ml

Acetone	wt,	g

F.H.	Total,	g 0.0000 0.0000 0.0000

Back	Half	Sample:

B.H.	Total,g

Acetone	Blank	Sample:

Acetone	blank	volume,	ml

Acetone	Blank	weight,	g 0 0 0

Acetone	weight	gain,g 0.0000 0.0000

Acetone	Blank	concentration #DIV/0! #DIV/0! #DIV/0!

0.001%		of	Acetone	Blank	Weight #DIV/0! #DIV/0! #DIV/0!

Weight	of	Sample	in	Acetone	Wash,	g #DIV/0! #DIV/0! #DIV/0!

Corrected	Acetone	Blank	Value,	g #DIV/0! #DIV/0! #DIV/0!

(F.H.	Total+B.H.	Total-Blank):

Total,	g #DIV/0! #DIV/0! #DIV/0!

C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\4321353822904480646\09000064819454fb
	Test	Data	Summary	and	Calculations

ALCOA	EAST	OPERATIONS

Line	3

Massena,	NY

Parameter Run	1	-	XAD	ID:	T1667-001 Run	2	-	XAD	ID:	T1667-002 Run	3	-	XAD	ID:	T1667-003

Run	Date 30Apr13 30Apr13 01May13

Start/Stop	Time 1002/1418 1455/1911 0825/1230

Duration	of	Run,	Minutes 240 240 240

Ave.	Nozzle	Diameter,	inches 0.223 0.223 0.223

Pitot	Calibration	Factor,	CF 0.84 0.84 0.84

Meter	Gamma 1 1 1

Meter	Delta	H,	inches	of	H2O 1.8 1.8 1.8

Stack	Diameter,	inches 14 14 14

Rectangular	Width,	inches

Rectangular	Length,	inches

Stack	Area,	sq.ft. 1.07 1.07 1.07

Barometric	Pressure,	inches	of	Hg 30.3 30.2 30.3

Static	Pressure,	inches	of	H2O -5.5 -5.5 -5.5

Dry	Gas	Meter	Sample	Volume,	(VM)ft3

Initial 103.933 252.179 404.685

Final 251.597 404.635 555.147

Difference 147.664 152.456 150.462

Ave.	Stack	Temperature,		Ts(F) 76.5 91.0 93.8

Ave.	Meter	Temperature,	Tm(F) 67.6 69.5 70.2

Ave.	Run	Delta	H,	inches	of	H2O 1.28 1.37 1.31

Ave.	Square	Root	of	Delta	P 0.6977 0.7208 0.7061

Moisture	Data

Volume	of	water	collected,	mls 0 -2 -5

Silica	Gel,	grams 27.8 25.4 26.7

Total	Collected,	mls 27.8 23.4 21.7

ORSAT	Data

%O2 20.90 20.90 20.90

%CO2

%CO

Calculations

Vw(std),	scf	= 1.309 1.101 1.021

Vm(std),	dscf	= 150.129 153.945 152.221

Bws= 0.009 0.007 0.007

Md= 28.84 28.84 28.84

Ms= 28.74 28.76 28.76

Vs,	ft/sec	= 39.6 41.5 40.7

Qs,	acfm	= 2,539 2,662 2,610

Qs(std),	dscfm	= 2,475 2,522 2,470

Isokinetic	Sampling	Rate,	% 99.6 100.2 101.2

Where:

An	=	area	of	the	nozzle

As	=	area	of	the	stack

Vw(std)	=	volume	of	water	vapor	in	gas,	standard	conditions	=	0.04707*Vlc

Vm(std)	=	vol.	of	gas	sampled,	standard	conditions	=	17.647	x	Vm	x	gamma	x	[Pb	+	(dH/13.6)]/Tm(R)

Bws	=		water	vapor	in	gas	stream,	proportion	by	volume	=	Vw(std)/(Vm(std)	+	Vw(std))

Md	=	molecular	weight	of	stack	gas,	dry	basis	=	(0.44	x%CO2)	+	(0.32	x%O2)	+	[0.28	x	(%N2	+	%CO)]

Ms	=	molecular	weight	of	stack	gas,	wet	basis	=	[Md	x	(1-Bws)]	+	(18.0	x	Bws)

Vs	=	stack	gas	velocity	=	85.49	x	Cp	x	(avg.	Sq.Rt.	dP)	x	[Sq.Rt.	(Ts(R))/(Ms	x	Ps)]

Qs	=	stack	gas	flow	rate	=	Vs	x	As	x	60

Qs(std)	=	stack	gas	flow	rate,	standard	conditions	=	Qs	x	(1-Bws)	x	(528/(Ts(R))	x	(Ps/29.92)

Isokinetic	sampling	rate	=	{(Ts(R))	x	[(0.00267	x	Vlc)	+	(Vm(std)/17.647)]	x	100}/(Time	x	vs	x	Ps	x	An	x60)

C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\4321353822904480646\09000064819454fb
Particulate	Results	Summary

ALCOA	EAST	OPERATIONS

Line	3

Massena,	NY

Test	Results: Run	1	-	XAD	ID:	T1667-001 Run	2	-	XAD	ID:	T1667-002 Run	3	-	XAD	ID:	T1667-003Average

Particulate	Emission	Concentration:

grains/dscf #DIV/0! #DIV/0! #DIV/0! #DIV/0!

grains/dscf	@	7%	O2 #DIV/0! #DIV/0! #DIV/0! #DIV/0!

grains/dscf	@	15%	O2 #DIV/0! #DIV/0! #DIV/0! #DIV/0!

lb/dscf #DIV/0! #DIV/0! #DIV/0! #DIV/0!

Particulate	Emission	Rate:

grams/minute #DIV/0! #DIV/0! #DIV/0! #DIV/0!

lb/hr #DIV/0! #DIV/0! #DIV/0! #DIV/0!

fuel	F-factor,	dscf/MMBtu 0 0 0

lb/MMBtu #DIV/0! #DIV/0! #DIV/0! #DIV/0!

Where:

Particulate	Emission	Concentration:

grains/dscf		=		(15.432	grains/gm		x		gms	of	particulate	collected)/sample	vol.,	standard	cond.	(29.92"	Hg,	68°F,	dry)

grains/dscf	@	7%O2		=		grains/dscf		x		[(20.9	-	7.0)/(20.9	-	%O2)]

grains/dscf	@15%O2		=		grains/dscf		x		[(	20.9	-	15.0	)/(	20.9	-	%O2)]

lb/dscf		=		grains/dscf/7000	grains	per	pound

Particulate	Emission	Rate:

grams/minute		=		(grams	of	particulate	collected/sample	vol.,	standard	cond.)		x		stack	gas	flow	rate,	standard	cond.		

lb/hr		=		lb/dscf		x		stack	gas	flow	rate,	standard	conditions		x		60	minutes/hr

lb/MMBtu		=		(	Fuel	F-factor,	dscf/MMBtu	)	x	(grains/dscf)	x	(1	lb/7000	grains)	x	[	20.9/(20.9	-	%O2)]

C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\4321353822904480646\09000064819454fb
Parameter???	Results	Summary

ALCOA	EAST	OPERATIONS

Line	3

Massena,	NY

Parameter: Run	1	-	XAD	ID:	T1667-001 Run	2	-	XAD	ID:	T1667-002 Run	3	-	XAD	ID:	T1667-003 Average

Mol.	Wt. mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr

Parameter?? 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 #DIV/0! 0.00E+00 #DIV/0! 0.00E+00

Parameter?? 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 #DIV/0! 0.00E+00 #DIV/0! 0.00E+00

Parameter?? 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 #DIV/0! 0.00E+00 #DIV/0! 0.00E+00

Parameter?? 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 #DIV/0! 0.00E+00 #DIV/0! 0.00E+00

Parameter?? 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 #DIV/0! 0.00E+00 #DIV/0! 0.00E+00

Parameter?? 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 0.00E+00 #DIV/0! 0.00 #DIV/0! 0.00E+00 #DIV/0! 0.00E+00

Where:

Pollutant	Emission	Concentration:

mg=	total	sample	collected,	milligrams

mg/dscm	=	milligrams	of	pollutant	per	dry	standard	cubic	meter	sampled	=		(mg/dscf	)	x	(35.314	cubic	feet/cubic	meter)	

ppm	=	parts	per	million	=((mg/dscm	x	24.04	liters/mol)/mol.wt))

Pollutant	Emission	Rate:

lb/hr	=	pounds	of	pollutant	emitted	per	hour	=	mg/1000/[(453.59	g/lb)/(dscf)]	x	dscfm	x	60	min/hr

C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\4321353822904480646\09000064819454fb
Example	Calculations	

ALCOA	EAST	OPERATIONS

Line	3

Massena,	NY

Note:	Values	are	shown	for	example	purposes	only.

Vm,a	= Dry	gas	volume	at	actual	conditions	(acf)	

Initial	gas	meter	volume:

Final	gas	meter	volume:

Difference:

Vm,std	= Volume	of	dry	gas	at	standard	conditions	(dscf)	

= 17.647x	Vm,	a	x	Gamma*[Pbar+(DeltaH/13.6)]/Tm(R)

= 17.647 x 0.000 x 1.000 x	( 30.30 +	[	( 1.800 /13.6)]/ 528

= 150.129

Vl,c	= Volume	of	water	collected	in	impingers	and	silica	gel	(ml)	

impinger	catch	(mls): 0

silica	gel	(g) 27.8

total: 27.8

Vw,std	= Volume	of	water	vapor	in	gas	at	standard	conditions	(cu.ft.)	

= (0.04707)	x	(Vl,c)

= 0.04707 x 27.8

= 1.309

Bwo	= Proportion	by	volume	of	water	vapor	in	gas	stream

= Vw,std/(Vw,std+Vm,std)

= 1.31 /	( 1.31 + #### )

= 0.009

Ps	= Stack	gas	static	pressure	(in.	Hg)	

= St/13.6

= -5.50 /	13.6

= -0.404

Pa	= Absolute	stack	gas	pressure	(in.	Hg)	

= Ps+Pbar

= -0.404 + 30.30

= 29.90

MFD	= Dry	mole	fraction	of	stack	gas

= 1-Bwo

= 1	-	

= 0.991

Md	= Dry	molecular	weight	of	stack	gas	(lb/lb-mol)	

= (0.32	x	%O2)	+	(0.44	x	%CO2)	+	(0.28	x	%N2)

= (0.32	 x	 20.90 )+ (0.44 x 0.00 )		+ (0.28	x	 79.10 )

= 28.84

Mw	= Wet	molecular	weight	of	stack	gas	(lb/lb-mol)	

= (Md)	x	(MFD)	+	(0.18)	x	(Bwo*100)

= 28.84 x 0.991 	+			0.18 x 0.86

= 28.74

Vs,avg	= Average	stack	gas	velocity	(fps)	

= Kp	x	(Cp)	x	(sqrt,deltaP)	x	sqrt((Ts	+	460°R)/Mw*Pa))

= 85.48 x 0.84 x 0.70 x		sqrt	( 0.62 )

= 39.6

A	 Cross	sectional	areas	of	stack	(sq.	ft)	

= pi/4*d^2

= 1.17 ^2

= 1.07

Qa	 Volumetric	flow	rate	at	actual	conditions	(acfm)	

= (60)sec/min(A)(Vs,	avg)

= 60 x 1.0690 x 39.59

= 2,539

Qstd	 Volumetric	flow	rate	at	standard	conditions	(scfm)	

= Qa	x	(528/Ts,avg	+	460)	x	Pa/29.92

= 2,539 x	( 528 / 537 )	x 0.999

= 2,497

Qstd,dry	 Volumetric	flow	rate	at	dry	standard	conditions	per	minute(dscfm)	

= Qstd	x	(1-Bwo)

= 2,497 x 0.9914

= 2,475

gr/dscf PM	concentration

= (15.43	x	Gm)	/	Vm,std

= (15.43	 x #### )	/ ####

= #DIV/0!

lb/hr PM	Mass	Emission	Rate

= (gr/dscf	x	dscfm	x	60	min/hour)/7000	grains	per	pound

=	( #DIV/0! x 2,475 x 60 )	/ 7000

= #DIV/0!

3.14159/4	x	

0.009

103.933

251.597

147.664

C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\4321353822904480646\09000064819454fb