P2693 - TEQ

Project ID: P-10142 

Sample Summary

Part 1 Method 23

Analyte 0_8205_

MB001

Run 1-

Dryer

Run 2-

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Run 3-

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Inlet

Run 2-

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pg pg pg pg pg pg pg pg pg pg

2,3,7,8-TCDD (2.4) (2.04) (1.86) [2.46] [5.05] [2.75] [3.1] (1.54) (1.11) (1.41)

1,2,3,7,8-PeCDD (2.56) (1.95) (2.4) (2.78) 12.5 14.1 [8.16] (1.43) [1.32] (1.31)

1,2,3,4,7,8-HxCDD (2.67) (2.12) (1.78) (2.18) (1.9) 5.61 [4.32] (1.27) (0.84) (1.2)

1,2,3,6,7,8-HxCDD (2.7) (2.13) (1.81) (2.07) (1.77) 8.04 6.06 (1.25) (0.878) (1.17)

1,2,3,7,8,9-HxCDD (3.06) (2.21) (1.95) (2.27) (2.11) 9.73 [6.71] (1.34) [1.7] 2.76

1,2,3,4,6,7,8-HpCDD (2.78) 5.53 [9.68] 9.45 24.9 29.7 27.5 7.63 7.64 [7.66]

OCDD (5.6) 34.6 49.2 [44.9] 133 151 167 82.3 63.1 44.3

2,3,7,8-TCDF (1.42) (1.36) [1.47] [1.48] 16.2 24.9 19 14.1 9.28 7.41

1,2,3,7,8-PeCDF (1.43) (1.53) (1.42) 1.46 7.34 16.6 14.6 3.85 [2.68] [3.12]

2,3,4,7,8-PeCDF (1.38) (1.41) (1.31) [1.31] [5.42] 8.94 10.5 [3.42] 2.58 4.01

1,2,3,4,7,8-HxCDF (1.69) (1.36) [1.63] (1.36) 5.97 6.64 8.87 2.76 2.04 2.99

1,2,3,6,7,8-HxCDF (1.72) (1.28) [1.65] (1.32) 6 7.66 [7.51] 2.9 1.92 2.6

2,3,4,6,7,8-HxCDF (1.65) (1.2) (0.933) (1.37) [2.69] 4.18 [5.16] [1.42] [0.934] [1.89]

1,2,3,7,8,9-HxCDF (2.34) (1.84) (1.23) (1.84) (1.27) 2.88 (1.23) (0.957) (0.892) (1.05)

1,2,3,4,6,7,8-HpCDF (1.68) (1.45) [4.39] 3.53 14.6 14.5 16 [4.76] [3.89] [5.23]

1,2,3,4,7,8,9-HpCDF (2.63) (2.14) (1.66) (2.18) (1.68) (2.4) [3.26] (1.23) (1.06) 3.06

OCDF (3.96) (3.9) (2.57) (2.54) 7.96 [4.78] 9.18 [4.54] 3.68 6.11

ITEF TEQ (ND=0; EMPC=0) 0.00 0.09 0.0492 0.203 9.98 19.9 9.97 2.32 2.76 3.66

ITEF TEQ (ND=0; EMPC=EMPC) 0.00 0.09 0.665 3.51 18.0 22.7 19.5 4.23 3.86 4.14

ITEF TEQ (ND=DL/2; EMPC=0) 3.12 2.68 2.50 3.06 11.6 20.9 11.5 4.02 3.89 4.94

ITEF TEQ (ND=DL/2; EMPC=EMPC) 3.12 2.68 2.95 4.84 18.4 22.7 19.6 5.60 4.55 5.34

ITEF TEQ (ND=DL; EMPC=EMPC) 6.25 5.27 5.24 6.16 18.7 22.7 19.7 6.98 5.24 6.54

Checkcode 843-921 701-858 716-174 222-513 868-870 609-674 798-971 925-681 363-824 117-797

Lab ID MB1_8205_DF_SDS P2693_8205_001 P2693_8205_002 P2693_8205_003 P2693_8205_004 P2693_8205_005 P2693_8205_006 P2693_8205_007 P2693_8205_008 P2693_8205_009

( ) = DL

[ ] = EMPC
0

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pg

WHO-2005-TEQ

Project ID: P-10142

P2693

ND=0; EMPC=0

ND=0; EMPC=EMPC

ND=DL/2; EMPC=0

ND=DL/2; EMPC=EMPC

ND=DL; EMPC=EMPC
 P2693 - WHO-2005-TEQ

Project ID: P-10142 

Sample Summary

Part 1 Method 23

Analyte 0_8205_

MB001

Run 1-

Dryer

Run 2-

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Run 3-

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Run 2-

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pg pg pg pg pg pg pg pg pg pg

2,3,7,8-TCDD (2.4) (2.04) (1.86) [2.46] [5.05] [2.75] [3.1] (1.54) (1.11) (1.41)

1,2,3,7,8-PeCDD (2.56) (1.95) (2.4) (2.78) 12.5 14.1 [8.16] (1.43) [1.32] (1.31)

1,2,3,4,7,8-HxCDD (2.67) (2.12) (1.78) (2.18) (1.9) 5.61 [4.32] (1.27) (0.84) (1.2)

1,2,3,6,7,8-HxCDD (2.7) (2.13) (1.81) (2.07) (1.77) 8.04 6.06 (1.25) (0.878) (1.17)

1,2,3,7,8,9-HxCDD (3.06) (2.21) (1.95) (2.27) (2.11) 9.73 [6.71] (1.34) [1.7] 2.76

1,2,3,4,6,7,8-HpCDD (2.78) 5.53 [9.68] 9.45 24.9 29.7 27.5 7.63 7.64 [7.66]

OCDD (5.6) 34.6 49.2 [44.9] 133 151 167 82.3 63.1 44.3

2,3,7,8-TCDF (1.42) (1.36) [1.47] [1.48] 16.2 24.9 19 14.1 9.28 7.41

1,2,3,7,8-PeCDF (1.43) (1.53) (1.42) 1.46 7.34 16.6 14.6 3.85 [2.68] [3.12]

2,3,4,7,8-PeCDF (1.38) (1.41) (1.31) [1.31] [5.42] 8.94 10.5 [3.42] 2.58 4.01

1,2,3,4,7,8-HxCDF (1.69) (1.36) [1.63] (1.36) 5.97 6.64 8.87 2.76 2.04 2.99

1,2,3,6,7,8-HxCDF (1.72) (1.28) [1.65] (1.32) 6 7.66 [7.51] 2.9 1.92 2.6

2,3,4,6,7,8-HxCDF (1.65) (1.2) (0.933) (1.37) [2.69] 4.18 [5.16] [1.42] [0.934] [1.89]

1,2,3,7,8,9-HxCDF (2.34) (1.84) (1.23) (1.84) (1.27) 2.88 (1.23) (0.957) (0.892) (1.05)

1,2,3,4,6,7,8-HpCDF (1.68) (1.45) [4.39] 3.53 14.6 14.5 16 [4.76] [3.89] [5.23]

1,2,3,4,7,8,9-HpCDF (2.63) (2.14) (1.66) (2.18) (1.68) (2.4) [3.26] (1.23) (1.06) 3.06

OCDF (3.96) (3.9) (2.57) (2.54) 7.96 [4.78] 9.18 [4.54] 3.68 6.11

WHO-2005 TEQ (ND=0; EMPC=0) 0.00 0.0657 0.0148 0.174 16.0 24.7 7.46 2.19 2.20 2.82

WHO-2005 TEQ (ND=0; EMPC=EMPC) 0.00 0.0657 0.63 3.18 22.9 27.5 21.1 3.41 3.90 3.24

WHO-2005 TEQ (ND=DL/2; EMPC=0) 3.61 2.99 2.92 3.57 17.4 25.7 9.44 4.13 3.66 4.42

WHO-2005 TEQ (ND=DL/2; EMPC=EMPC) 3.61 2.99 3.37 5.21 23.3 27.5 21.2 5.14 4.59 4.76

WHO-2005 TEQ (ND=DL; EMPC=EMPC) 7.22 5.91 6.11 7.23 23.7 27.5 21.2 6.87 5.28 6.29

Checkcode 843-921 701-858 716-174 222-513 868-870 609-674 798-971 925-681 363-824 117-797

Lab ID MB1_8205_DF_SDS P2693_8205_001 P2693_8205_002 P2693_8205_003 P2693_8205_004 P2693_8205_005 P2693_8205_006 P2693_8205_007 P2693_8205_008 P2693_8205_009

( ) = DL

[ ] = EMPC
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Totals

Project ID: P-10142

P2693

Total PCDD/Fs (ND=0; EMPC=0)

Total PCDD/Fs (ND=0; EMPC=EMPC)

Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC)
 P2693 - Totals

Project ID: P-10142 

Sample Summary

Part 2 Method 23

Analyte 0_8205_

MB001

Run 1-

Dryer

Run 2-

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Run 3-

Dryer

Run 1-

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Run 2-

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pg pg pg pg pg pg pg pg pg pg

Totals

TCDDs 0 6.76 0 15.8 152 116 115 0 38.8 48

PeCDDs 0 5.91 3 10.4 158 208 136 6.86 19 8.17

HxCDDs 0 14.6 14.7 15.7 58.7 130 88.9 13.8 11.1 12.5

HpCDDs 0 5.53 0 9.45 52.5 71.2 60.7 7.63 18.4 0

OCDD 0 34.6 49.2 44.9 133 151 167 82.3 63.1 44.3

TCDFs 0 1.49 12.8 18.1 288 334 326 241 139 154

PeCDFs 0 0 0 5.83 60.6 108 138 40 11 31.6

HxCDFs 0 0 6.26 0 31.4 40.5 47.7 7.63 3.97 14

HpCDFs 0 0 0 3.53 16.9 14.5 19.1 2.04 0 5.3

OCDF 0 0 0 0 7.96 4.78 9.18 4.54 3.68 6.11

Total PCDD/Fs (ND=0; EMPC=0) 0.00 68.9 85.9 78.8 958 1,170 1,110 401 308 324

Total PCDD/Fs (ND=0; EMPC=EMPC) 0.00 80.6 168 196 1,120 1,320 1,200 478 398 386

Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC) 41.7 109 187 216 1,130 1,320 1,200 487 403 392

Total 2378s (ND=0; EMPC=0) 0.00 40.2 49.2 14.4 229 305 279 114 90.3 73.2

Total 2378s (ND=0.5; EMPC=0) 20.8 54.1 61.8 29.5 235 309 285 120 95 78.4

Total 2378s (ND=1; EMPC=0) 41.7 68.1 74.3 44.6 242 313 291 127 99.7 83.6

Total 2378s (ND=0; EMPC=1) 0.00 40.2 68.0 64.6 242 312 317 128 101 91.1

Total 2378s (ND=0.5; EMPC=1) 20.8 54.1 77.5 74.6 246 313 318 132 103 94.2

Total 2378s (ND=1; EMPC=1) 41.7 68.1 86.9 84.5 251 315 319 137 106 97.2

Checkcode 843-921 701-858 716-174 222-513 868-870 609-674 798-971 925-681 363-824 117-797

Lab ID MB1_8205_DF_SDS P2693_8205_001 P2693_8205_002 P2693_8205_003 P2693_8205_004 P2693_8205_005 P2693_8205_006 P2693_8205_007 P2693_8205_008 P2693_8205_009

( ) = DL

[ ] = EMPC
 P2693 - Others

Project ID: P-10142 

Sample Summary

Part 3 Method 23

Analyte 0_8205_

MB001

Run 1-

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Run 2-

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Run 3-

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pg pg pg pg pg pg pg pg pg pg

Other PCDD/Fs (ND=0, EMPC=0)

Other TCDD 0 6.76 0 15.8 152 116 115 0 38.8 48

Other PeCDD 0 5.91 3 10.4 145 193 136 6.86 19 8.17

Other HxCDD 0 14.6 14.7 15.7 58.7 107 82.8 13.8 11.1 9.73

Other HpCDD 0 0 0 0 27.6 41.5 33.2 0 10.8 0

Other TCDF 0 1.49 12.8 18.1 271 309 307 227 130 147

Other PeCDF 0 0 0 4.37 53.2 82.1 113 36.1 8.45 27.6

Other HxCDF 0 0 6.26 0 19.4 19.2 35.2 1.97 0 8.43

Other HpCDF 0 0 0 0 2.27 0 3.07 2.04 0 2.24

Other PCDD/Fs (ND=0, EMPC=EMPC)

Other TCDD 0 6.76 9.61 33.9 177 162 136 24.8 48.5 50.3

Other PeCDD 0 10.8 15.4 23.5 209 202 143 14.9 28.1 17

Other HxCDD 0 14.6 19.7 18.9 90 112 86.7 13.8 15.6 12

Other HpCDD 0 4.9 10.8 12.2 27.6 41.5 33.2 7.96 10.8 7.31

Other TCDF 0 3.41 33.8 31.7 284 361 308 236 166 156

Other PeCDF 0 0 2.22 9.43 66 101 120 41.1 22.7 37.1

Other HxCDF 0 0 9 1.81 19.4 27.9 41.5 8.36 4.72 11

Other HpCDF 0 0 0 0 4.46 2 5.4 3.37 0.845 4.35

Checkcode 843-921 701-858 716-174 222-513 868-870 609-674 798-971 925-681 363-824 117-797

Lab ID MB1_8205_DF_SDS P2693_8205_001 P2693_8205_002 P2693_8205_003 P2693_8205_004 P2693_8205_005 P2693_8205_006 P2693_8205_007 P2693_8205_008 P2693_8205_009

( ) = DL

[ ] = EMPC
 P2693 - TEQ overview

Project ID: P-10142 

TEQ Summary

Part 4

( ) = DL

[ ] = EMPC
Method Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F = fail)

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Mean Recoveries of Extraction Standards (N=10)

Project ID: P-10142

P2693 Mean Std. Dev.
Method Specification Limits: Tetra-Octa SS: 70-130% (F = fail)

0

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% Rec.

Mean Recoveries of Sampling Standards (N=10)

Project ID: P-10142

P2693 Mean Std. Dev.
0_8205_MB001 83.1 79.8 88.5 85.5 86.4 89.2 85.5 88.5 87.2 84.2 89.9

Run 1-Dryer 88.3 85.2 95.4 93.4 93.9 97.1 95.4 92.1 89.8 87 97.9

Run 2-Dryer 89.9 86.2 101 95 97 99.9 95.9 91.1 86.9 86.7 102

Run 3-Dryer 89.4 80.2 90 87.1 86.7 90.4 89.9 89.1 87.6 86.8 92.5

Run 1-Inlet 80 77.1 94.1 88.1 88.7 96.8 92.2 80.5 81.9 81.1 93.9

Run 2-Inlet 80.4 78.5 86.2 79.7 81.2 86.1 84.1 82.1 81.6 79.6 85.8

Run 3-Inlet 91.2 88.1 99.3 93.2 93.6 97.2 90.5 91.1 89 86.9 100

Run 1-Outlet 84.9 83.2 93.2 90 89.4 96.2 90.2 86.9 85 84.9 93

Run 2-Outlet 85.5 86.9 102 94.4 97 98.7 94 87.6 90.2 90.4 99.5

Run 3-Outlet 83.5 81.8 97.9 90.1 92.5 98.4 92.8 83.7 87.6 86.5 96.2

Average 86 83 95 90 91 95 91 87 87 85 95

SD 4 4 5 5 5 5 4 4 3 3 5

Min 80 77.1 86.2 79.7 81.2 86.1 84.1 80.5 81.6 79.6 85.8

Max 91.2 88.1 102 95 97 99.9 95.9 92.1 90.2 90.4 102

Within M23 QC TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE

13CHxCDD13CHxCDD13CHpCDD

Sample Number 13CTCDD

13CPeCDD13CHxCDD

Extraction Standard Percent Recoveries, %

13CPeCDF13CPeCDF13COCDD13CTCDF13CHxCDF
91.4 89.9 87.8 91.5 85.8 81.9 0_8205_MB001 98.2 101 98 101 95.9

98 99.9 92.8 96.2 93.5 91.7 Run 1-Dryer 104 102 99.2 101 101

100 100 98.7 100 98.7 93.6 Run 2-Dryer 100 101 101 102 100

92.5 94.4 86.1 91.8 87 86.7 Run 3-Dryer 100 102 99.2 100 98.5

94.6 92.3 90.8 92.8 91.2 89.9 Run 1-Inlet 103 101 99.1 101 104

85.5 84.6 83 84.6 82.6 79.2 Run 2-Inlet 102 97.7 98 101 100

98.4 95.4 95.1 96 93.9 90.5 Run 3-Inlet 100 97.3 102 104 101

93.2 92.8 91.5 92.7 87.6 87.1 Run 1-Outlet 107 100 102 104 105

98.8 102 97.7 96.9 99 92.5 Run 2-Outlet 101 100 96.6 100 102

96.8 98.3 90.7 94.8 93 92 Run 3-Outlet 102 101 100 101 103

95 95 91 94 91 89 Average 102 100 100 102 101

4 5 5 4 5 5 SD 3 2 2 1 3

85.5 84.6 83 84.6 82.6 79.2 Min 98.2 97.3 96.6 100 95.9

100 102 98.7 100 99 93.6 Max 107 102 102 104 105

TRUE TRUE TRUE TRUE TRUE TRUE Min within M23 QC TRUE TRUE TRUE TRUE TRUE

13CHpCDF13COCDF13CHxCDF13CHxCDF13CHxCDF13CHpCDF

Sample Number

CS/SS Percent Recoveries, %

37ClTCDD13CPeCDD13CHxCDF13CHpCDF13CPeCDF
 P2693 Page 1 of 5
 P2693 Page 2 of 5
 P2693 Page 3 of 5
 P2693 Page 4 of 5
 P2693 Page 5 of 5
 P2693 - DLs

Project ID: P-10142 

Sample Summary

Part 5 (DLs) Method 23

Analyte 0_8205_

MB001

Run 1-

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Run 2-

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Run 1-

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pg pg pg pg pg pg pg pg pg pg

2,3,7,8-TCDD 2.4 2.04 1.86 2.18 1.63 1.99 1.53 1.54 1.11 1.41

1,2,3,7,8-PeCDD 2.56 1.95 2.4 2.78 2.11 2.68 1.71 1.43 1.35 1.31

1,2,3,4,7,8-HxCDD 2.67 2.12 1.78 2.18 1.9 1.94 1.86 1.27 0.84 1.2

1,2,3,6,7,8-HxCDD 2.7 2.13 1.81 2.07 1.77 2.06 1.86 1.25 0.878 1.17

1,2,3,7,8,9-HxCDD 3.06 2.21 1.95 2.27 2.11 2.2 2.13 1.34 0.923 1.28

1,2,3,4,6,7,8-HpCDD 2.78 2.41 2.03 2.65 1.98 2.48 2.35 1.53 1.35 1.42

OCDD 5.6 4.96 3.36 5.35 3.61 4.25 4.01 2.78 1.87 2.39

2,3,7,8-TCDF 1.42 1.36 1.08 1.24 1.13 1.53 1.19 1.21 0.93 0.831

1,2,3,7,8-PeCDF 1.43 1.53 1.42 1.54 1.61 1.91 1.29 1.2 0.855 1.03

2,3,4,7,8-PeCDF 1.38 1.41 1.31 1.5 1.42 1.88 1.25 1.13 0.765 0.971

1,2,3,4,7,8-HxCDF 1.69 1.36 0.89 1.36 0.946 1.37 0.829 0.748 0.683 0.751

1,2,3,6,7,8-HxCDF 1.72 1.28 0.948 1.32 0.896 1.34 0.859 0.72 0.682 0.787

2,3,4,6,7,8-HxCDF 1.65 1.2 0.933 1.37 0.9 1.42 0.867 0.767 0.677 0.787

1,2,3,7,8,9-HxCDF 2.34 1.84 1.23 1.84 1.27 1.7 1.23 0.957 0.892 1.05

1,2,3,4,6,7,8-HpCDF 1.68 1.45 1.23 1.44 1.09 1.62 1.21 0.823 0.77 1.02

1,2,3,4,7,8,9-HpCDF 2.63 2.14 1.66 2.18 1.68 2.4 1.79 1.23 1.06 1.6

OCDF 3.96 3.9 2.57 2.54 2.74 3.43 3.08 1.74 1.51 1.45

Total TCDD 2.4 2.04 1.86 2.18 1.63 1.99 1.53 1.54 1.11 1.41

Total PeCDD 2.56 1.95 2.4 2.78 2.11 2.68 1.71 1.43 1.35 1.31

Total HxCDD 2.8 2.15 1.84 2.16 1.92 2.06 1.94 1.28 0.878 1.21

Total HpCDD 2.78 2.41 2.03 2.65 1.98 2.48 2.35 1.53 1.35 1.42

Total TCDF 1.42 1.36 1.08 1.24 1.13 1.53 1.19 1.21 0.93 0.831

Total PeCDF 1.41 1.47 1.37 1.52 1.51 1.89 1.27 1.16 0.809 0.998

Total HxCDF 1.83 1.4 0.992 1.45 0.991 1.45 0.933 0.791 0.727 0.832

Total HpCDF 2.08 1.75 1.42 1.76 1.35 1.96 1.46 0.998 0.899 1.28

Checkcode 843-921 701-858 716-174 222-513 868-870 609-674 798-971 925-681 363-824 117-797

Lab ID MB1_8205_DF_SDS P2693_8205_001 P2693_8205_002 P2693_8205_003 P2693_8205_004 P2693_8205_005 P2693_8205_006 P2693_8205_007 P2693_8205_008 P2693_8205_009