### U. 

### .S. ENVIRONMENTAL PROTECTION AGENCY

; .1



# ii:f l_j 

# J ,1 

### ,jl' ! 

## ,, 

# PREMANUFACTURE

**-~QTICE** 

# __ FOR NEW CHEMICAL SUBSTANCES


### Enter the total number ofpages, in 

### the Premanufacture Notice Date ofreceipt 

# 2003 AUG -6 PM 

# 3:· 1'5 Company Sanitized

•You must provide all information requested in this form to the extent that it is knownto orreasonably ascertainableby you. Make reasonable estimates if you do not have actual data. . · · · ' •Before you complete this form, you should .read the "InstructionsManual forPremanufacture Notification" (the Instntctions Manual is available from the Toxic · Subst_ances Control Act (TSCA) Information Service by calling 202.-554-1404, or. faxing 2.02.-554-5603). • U a userfee has been remitted for this notice (40 CFR 700.45),indicate inthe boxes above the T5-userfee identification numberyou have generated. · Remember, youruserfee ID numbermust also appear on your **corre~ponding** fee remittance, which is sent to: EPA, HQ Accounting OperatioJ!S Brandt (PM-2.66), P.O. 360399M, Pittsburgh,PA 15251-6399;Attn.-TSCA 'UserFee. · · · · · ·· Put I- GENERAL INFORMATION You must provide the currently correct Chemical Abstracts.(CA) Name of the new chemical substance, even if you-claim.the identity as confidential....You may authorize anotherperson to submit chemical identity information foryou,but your submission will not be complete and the review will not begin until

**EP~** receives this infolDlation. A letterin support ofyour submission should reference yourTS user fee identification number. You must submit-an original and two copies ofthis notice including all.test data. Ifyou claimed any information as confidential, a single sanitized copy must also be submitted. Part IT- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE U there are several manufacture, processing, oruse-operations to be described in Part II. sections A and B of this notice, reproduce the sedio.ns as neeqed. Part ID- UST OFATTACHMENTS Attach additional sheets if there is not enough space to answera question fully. Label each continuation sheetwlth the corresponding section heading.· InPart lll'.list these attachments, U\Y test dati. orother data and any optional infolDlation included in the notice. OPTIONAL INFORMATION You·may include anyinformation that you want:EPA to consider in evaluating the new substance. On page 11 ofthis folDl, space has been provided for you to describe pollution prevention and recycling infolDlation you may have regarding the new.substance. So-called "binding" boxes are included throughout this folDl for you·to indicate yourwillingness to bebound to certain statements you make in this notice, such
.as use, production volume, protective equipment ••. This option is intended to reduce delays that routinely acmmpany the-development of consent orders or Significant NewUse Rules. Except in the case ofexemption applications (such as TMEA, LVE, LOREX) where certain information provided in such notification is binding on the submitter when the Agency approves the exemption application, checking a binding box in this **notice~ ~y**  itselfprohibit the submitter from laterdeviating from the infolUlation (except chemical identity) reported in the folDl. CON,FJDENTIALITY CLAIMS You may claim any·infolDlation in this notice as confidential. _To assert a claim on the

**fo~** marie (X) the confidential box next to the infolDlation thatyou claim as confidential. To assert a claim in an attachment, circle or bracket the information you claim as confidential. Ifyou claim lnfonnatiop ip the notice as confidential. you must also proyjde a sanitized yexsjop of the notice. <includiDJ: attachments). For additional instructions on claiming information as confidential, read the Instructions Manual.



# csa l.1ark (X) if any 

### infonnat~on in this notice is claimed as confidential. EPA FORM 771 0-25 (Rev. 5-95) TEST DAT-A AND OTIIERDATA You· are required to submit all test datainyourpossession or control and to provide a description of all otherdati.known to orxeasonably

.ascertainable byyou, ifthese dati.are related to the health and environmental effects ofthe manufacture, proCle&Smg, distribution in rommerce, use, ordisposal ofthe new chemical substance. Standard literature citations may be submitted for dati. in the open scientific ·literature. Complete

### test data Cwxitten In English!. not summaries of dafa. mustbe subuiitted ifthey do not awear in theOJ>en

**lit~.** You should clearlyidentifywhether test dati. is on the substance oron an analog. Also, thechemical composition of thetested material should be characterized. Following are examples of test dati. and other data. Data·shoUld be submitted according to the requirements of §720.50 ofthe Premanufacture Notification Rule (40 CFRPart 720). Test Dati. (Check Below any included in this notice)



### . . .. "· :•En:vironmental.<fat:e. data 

# ..,Q Yes 

# 0 Yes 

# 0 Yes • Otherdata 

# 0 Yes Risk assessments • Health effects data • ·Environmental effects dati. Structure/activity relationships • Physical/Pemical·Properties

# •[il Yes Test data not in the possession

. or control ofthe submitter •A physical and chemical properties worksheet islocated.on the last page · of this form. TYPE OF NOTICE (Check Only One) 

# .fiJ -PMN 

### (Pr~anufacture Notice)



### ~

**~** 

# 0 .INTERMEDIATE PMN (submitted in sequencewith 

### fin~duct PMN)
.. 

### c-... 

# 0 0 D D 

# 0 **c~** 

### <:::">...: -"') .;;;:o

- "-bh1 

### 0.:> -., (") 'l""r-] "(:) 

### ... ":;';;..-- L

VE (Low Volume Exemption) 0 40 CFR 723.50

**(c)(1J:.1<.~** 

### c) 

## -.r:::
. . -- f"rJ LOREX (Low Release/Low Exposure Exemption) @ 

### -kt?SO(c){i)> t::::J SNUN (Significant New Use Notice) TMEA (Test Marlceting Exeinption Application)
L

VE Modification .

# 0 LOREX

## M~llf~ IS TinS A CONSOLIDATED PMN7 

# :r:gj . Yes II of chemicals 

# <. (Prenotice Communication il required, enterll.;n page 3). Replaces previous editions of EPA Form 7719-25. 

# I

**~--~-·1···-** 

# ....

# ---,---;--r--**--~--··-~** 

### I: I I 

### Il'ubUc rcporttng burden for iliis collection ofinformation is estimated to average 110 hours per response, including time for reviewing instructions, ·, .searching existing

**d::~to:~** sources, gathering 

### and maintaining the d:ita needed, 

### and c:omplcting and reviewing the collection ofinformation. 

### Send

comments regarding ilie burden estimate or 

### 01ny other aspect of this collection of information, including suggestions for reducing this burden, to 

### Chief, **Inform::~tion** Policy Branch, 

### PM-223, U.S. Environmental Protection 

### Agency, 401 M. St., S.W., Washington, 

### D.C. 20460; and to the Office of
. Management and
**Bud~et,** Paperwork Reduction Act (2070-0012), Washington, D.C 20503. 

## CERTIFICATION 

# rcertify that to the best of my knowledge and belief: 1. The company named in 

## Part I, section A, subsection la of this notice form intends to manufacture or 

### import for a commercial purpose, other than in small quantities solely for 

### research and development, the substance identified 

### in Part I, 

### Section B. 2. All infonnation provided in 

### this notice 

### is complete and truthful 

### as ofthe date of submission. 

### 3. I am submitting with this notice all test data in my possession or control and a description 

### of all other data known 

### to or reasonably ascertainable 

### by me as required by 

### §720.50 of the Premanufacture Notiiication Rule. 

### Additional Certification Statements: .Ifyou are submitting a 

### PMN, Intermediate 

### PMN, Consolidated 

### PlvfN, or 

### SNUN, check the following user fee 

### certification statement that applies: . 

# og The Company named in 

### Part I, Section.A has.remitted the 

### fee of

### $2500 specified in.40 

### CFR 700.45 (b), 

### or 

# D The Company named in 

### Part I, section 

### A has remitted the 

### fee of 

### $1000 for 

### an Intermediate 

### PMN (defined@ 

### 40 

### CFR 700.43) in ·accordance with 

### 4D CFR 700.45(b), or 

# D The Company named in Part 

### I, Section 

### A is a small business concern under 

### 40 

### CFR 700.43 and has remitted a fee of 

### $100 in accordance with 

### 40 CFR 

### 700.45 (b). Ifyou are submitting a low

### volume exemption (LVE) 

### application in accordance with: 

### 40 CFR 

### 723.50 (c) 

### (1) or a Low release and low exposure exemption (LoREX) application 

### in accordance with 

### 40 

### CFR 

### 723.50 (c) 

### (2), checkthe following certification statements: · 

# D The manufacturer submittingthis notice intends to 

### manufacture or import the new 

### chemical substance for commercial purposes, otherthan 

### in small quanti,tilj!S solely for 

### research and development, under the terms of40 CFR 

### 723.50. . . The manufacturer is familiar with the terms of this section and will 

### comply with those terms; and The new chemical substance for which the notice is submitted 

### meets all applicable exemption conditions. 

# D D D If this application 

### is for an 

### LVE in accordance with 

### 40 

### CFR 723.50 (c)(l), the manufacturer intends to commence manufacture of the exeii1pted substance for commercial purposes within 

### 1

## year of the date of the expiration of the 

### 30 day review period. '
The 

### accuracy of the statements you 

### make in this notice should reflect your 

### best prediction of the 

### anticipated facts regarding the chemical

substance described herein. Any knowing and willful misinterpretation is subject to 

### criminal 

### penalty pursuant to 18 USC 1001. 

### Signatux:e and title of 

### Authorized Official (Original Signature Required) Date Signature of 

### agent- (if applicable) Date FORM EPA 7710-2.5 (Rev. 5-95) Page2 

### Confidentia.J. 

# Xla. Person Submitting Notice (in U.S.)

b. Agent (if applicable) 

## Part I- GENERAL INFORMATION Name
address (number Gty, State, 

### ZIP Code Name of authorized official Mailing address (number and street} 

### Gty, State, 

### ZIP Code Telephone c. If you are submitting this notice as part of a joint submission, mark (X) this box. **----------------~~** Joint Submitter (if applicable)

2. Technical Contact (in 

### U.S.) Name of authorized offidal Company Mailing address (number and street) 

### City, State, 

### ZIP Code. Name Company Mailing address (number and street) Gty, State, 

### ZIP Code 3. Ifyou have had a prenotice communication 

### <PO concerning this notice · and EPA assigned a PC Number to the notice, enter the number. 4. If you previously submitted an exemption application for the chemical substance covered by this notice, enter the exemption number assigned by 

### EPA. Ifyou previously submitted a PMN for this substance enter the PlviN number assigned by EPA (i.e. withdrawn or incomplete).

**--....::>-~.** If you have submitted a notice of Bona fide intent to manufacture or import for the chemical substance covered by this notice, enter the **=~=ber~~~~** 

# > Type of Notice- Mark (X) FORM EPA 7710-25 (Rev. 5-95) 

# l.D 

# D Manufacture Only Binding Option Mark(x) Page3 Position

Telephone Position

Telephone 1 I Mark(X) 

# > 

# D ifnone Mark (X) 

# » 

# D if none Mark (X) 

# > 

# D ifnone 2. **~** Import Only 

# D Both 

# D BindingOption 3. Mark(-.:} **Confl:·~** dential



# 'X )(

## Patti~- 

## GENERAL INFORMATION- Continued

. . . . . . ' 

### SectionB - CHEMICAL IDENTITY INFORMATION: You must pro'?de a

**~tly** COrrect Chemical Abstracts {CA) name oHlie substance. 

### , _ · 1!ased on the runth Collective Index {9Cl) of CAnomenclaturerules and.conventions. next to any 

### item you claim as confidential. ' . Complete eitheritem 1 (Class1 or 2 substances) .or 2 (Polymers) as appropriate. Complete all other items. ', ' , • •

**~** I ' • • • • • • ' • <i ' ' Ifanother person will submit 

### Chemical identityinformation for you (for either

# item l-or 2); mark (X) the box at the

**r~t.** · the and address of that a continuation Sheet. ·- . 

# >- 1. ·Class 1 or 2 Chemical substances (for

**definitio~** ofclass 1 and class 2 substances, see the Instructions Manual) ·



### a. aa:ss ofsubstance- Mark (X) 1 

# 0 Oass 1 . ,or 2 

# 0

**Oa~** 2 . b.



### Otemi~ name(Currently correct 

### Oi.emicalAbstract~ (CA) Name that 

### iS consistent with TSCA Inventory lisfutgs for siii!ilar substances. For Qass lsul,lstances a·<:A Index Name must beprovided. For Oass 2 substanceS either a CA IndexName.orCA PreferredName be provided,whj.chever is appropriate based on CA 90 nomenclature rules and conventions.). · · ·

c. J:'lease identifywhich method you used to develop or obtain the

**s~ed** Chemical indentityinformation reported in this notice:_ .

· (checl<:·omi). · , · · .· .· . ·. , ' · 

# ·· . · 0 Method l (CAS Inventory Expert Service - a copy: oftheidentification · QM:ethoo 2 (Other Source) reportobtainedfrcim the CAS Inventory Expert Service must be submitted as an attaChment to this notice).

. d; Molecular formula and CAS Registry Number (if a

**~umber** already existsfor the substance)
. 

### .

**~** CAS# e. For. a da,(is 1 'substance, provide a complete

**~d** correct.

**clu~micill** structure diagram.. For a clalJS 2 substance - (1) Ust the immediate

precursor. st.ibstances with thefr respective CAS RegistryNumbers. (2) DesCribe the nature of the reaction orprocess. (3) Indicate the range of;s:omposition and'the typical composition (where appropriate). (4) Provide_ a correct representative or partial Chemical: . ·structure diasram, as complete as can be knoWn, ifone

**c~** be reasonably ascertained.

**:~** l

Mark (X) this box if you attach a continuation sheet.

. . FORM EPA

**771~25-** 

## (Rev. S:.95) Page4_Q

# Part



# I~- GENERAL INFORMATION- 

# Continued. SectionB- CHEMICAL IDENTITY INFORMATIONi You must provide a currently correct Chemical Abstracts (CA)name ofthe substance basecton the ninth Collective Index (9CI) ofCknomenclature rules and.conventions;. . you claim as confidential. · . Complete eitheritem 1 (Class1 or 2 substances) ,or

**~** (Polymers) as appropriate. Complete

**~II** other items. · Ifanother



### ~5on will submit Chemical identity information for you (for either

# item 1·or 

### 2); mark 

### 00 the box· at the rigl!t. . · · · the · ·andaddress of that a continuation 

### Sheet. ·. 

## >" 1. Class 1 or 2 chemical substances (for definitions of class 1 and class 2 substances, see the Instructions Manual) ·. a. 

# aa:s8 ofsubstance- Mark 

### 00 1 

# D Oass 1 . 

### .or 2 

# D Oass 2
·. b.

**Chemi~** name

**(C~ently** .correct**c:ltenuc3J.Abstrac~(CA)** Name

**th~t** 

### iS coruiistent with TSCA Iriventorylistings for siriUlar substances. For Oass.lsubstances a·CA: Iridex Name must be provided. For Oass 2 substances either 11 CA

**Irid~** Name or CA PreferredName be provided, whj.cltever isappropriate based on CA 90nomenclature

**rul~** and conventions.). · . · .

· c. Please identify whiclt method you 

## used to develop or obtain the

**s~ed** Chemical indentityinformation reported in this notice: : (cltee:k'omi). · . , · . . ' · 

# . ' D . Method 

## r (CAS.Inventory Expert Service - a copy ofthe Identification . Q:Method 2 (Other Source) report.obtainedfrom the CAS Iriventory Expert.Service must be as an attachment to this notice). . ·d. Molecular formula and 

### cAs Registry Number (if a



### ~umber a:Iready exists for the substance) ' . . '

**,~** . CASt
e. For a cla,!Js 1 substance,provide a complete and correctcltqmical structure diagram.. For a class 

### 2 substance- (1) List the immediate



### pr~r substances With their



### r~tive CAs Registry Numbers. (2)DesCribe the nature of the reaction orprocess. (3) Iridicate the .

# -X range **o(~mposition** and the typical composition. (where appropriate). (4) Provide a correct representative or partial chemical structure diasram, as complete as can be krio'Wn, ifone

**c~** be reasonably ascertained.

Mark (X) this box if you attaclt a continuation sheet.



### .. FORM EPA 

### 7710-25. (Rev. 

### S:.95)



### Paged~

**-,~·~c··~r···--~-~··r·** I

### \ 

## Part! -GENERAL INFORMATION- Continued

**~** Section B- CHB1lC.A..L IDEN11TY INFOR..\1ATION - Continued

**-~**

::!.. Polymers (For a defutition of

**polymer,~** the Insauctions 

### Manu!.) Confi- 

# ..

**~** denti:ll

**;~..** lndicte the numbe:r-ave:-:1ge weight of the lowest molec-.llar weight composil:icn of the polymer you intend to.manufacture.

**~dicte** maximum

**wei.~ 1t**  

### per=t of low molecular weight species (not including

**re5idualll)onom~.** react:lllt:s, or :10lvent:s) below 5iXl and below 1,000 absolute molec-.l!.ar wcight of that composition. 

# • De3cribe the methods of me;;asurement or the basia far 

### your e3t:imates: GPC 

# 0 

# Othe:-0 :(Specify) !) lowest n=i:>e ave:n.;e mciec".:l:lr w.:;::t: 

# - Ul m==

**w~~t** ,. below 500 tnol«ui.ar wcgi"'!: iii) :naxi::::=

**wei;-~~** ,. below loaJ tnOitr.:l:lr wcgh:: 

# 0 Mark (X) this box if you attach a continuation 3heet.

b. You must make separate ccniid.entiality d.ai:ms for monomer or other reac:mt identity, c:cmposil:icn inio=oon, and 

### resJ.Ciual iJ:!icnnati.on. Mark (X) the MCon.fide:ntialM box next to 

### any item 

### you claim as c:oniidential. (1) - Provide the spec:ii.c chemical n=e and CAS 

### Re<gistty Number (if a number exists) of eac:h monomer or other reac::mt 

### used in the manuiac::ure 

### oi the polymer. 

# • (2) - Mark (X) this colu..-m if entry in column (1) is a:miidential. (3) - Indic::tte the typial. 

### weightpercent of each monomer or other reactant in the polymer. . (4) - Mn-k: CC the identity column ifycm w:mta mcmomer or other reac::;ntused at.two weight percent or less tc be wted as part of the polymer description on the TSCA Chemical Substance Inventcry. (5) - Mark (X) this c:cit:mn if entries in columns (3) and (4) arec:cniidential. (6) - Indic:ate the maximum weight percent of each moJ)cmer or otherreac:tmt that may be present as a residual. jn the polymer as manuiad:ured for c::ommerCal 

### purposes. (7) - Mark (X) this c:ciumn 

### if entry in column (6) is confidential. Monomer or other react:lllt and CAS 

### Registry Number 

## Conn- T 'cal Identity Con.fi- 

### Ma:d.mum Conii.- ypt dmtial. composition 

### Mark 

## CO dential residual dential. (1) (2) (3) (4) (5) (6) 

# - (7) _1'! ;:,

.% 

### r •

**-~-** %



## . ·'10 % 

# ,. ;:, '!';,

**""~** '10 '10 

# 0 Mark (X) this box if you attach a amtinuaticn sheet. c. Please identify which method. 

### you U:li!Ci to develop ar obtain 

### thespediied dlemic::!l.ideniity 

### inio=aticn reponed.in thi3 notice.. (c:heci; one).



# D Method 1 (CAS Inventory 

### Expert Servia!- a 

### ccpy of theidentification report 

# 0 Method 2 (other source) · o btai:led. 

### from CAS inventaty 

### Expert Service must be 

### submi!:ted :as an attac:..'"une:n t to thi3 notice) d. T.i'te o...-ren

### tly correct C"lemic::d :Abstrac::l (CA) name fa: 

### the poiymer thati3 consistent wil.i. TSC:A Inventa')" 

### lliltings £or similar

**pol~**
e. Provide a correc:: representative or 

### parti.;d c:hemi.Cil.

**~** 

### diagr=, as complete 

# as= be .known. ii

# one= be reasonably asc:e::-tai.ne:



# - 

# -

-
.



## - '

# 0 Mark

# 00 this box ii 

### you att:adl a



## ~~'uatian sheet. FO 0- RM EPA 

## m 25 (Rev. 5-95 PageS

## Part! 

## -GENERAL INFORMATION- Continued



# ~ Section B - CHEvrrCAL IDENTITY INFORMATION
- Continued

l. lnlparitles


# ..

**(~** - Identify -=b. lmparity th.x m.zy be reuo=bly utic:ipaed liD be pnooeat ID the chemic:a1 sab.toa:r.ce a m.mabc:u.n:d far annmcrc:W
**p~** 

## - **Pn:~vi**de the CAS
**Repl~Crr** Namber if uaW.ble.. If then. .ve .Wdentifled 1mpa:rltirs. eabor "1uUdmt!Bed.• · (b) -Estim&e the m.aximam weight

**~** of 

### ....a lmp-arity. U there .m: uidmtifl.ed lmpartlirs,.
**~a., thar~**  **w~ht ~-**  Impurity and CAS Registry Number Maximum Conii-

**~** (a) 

### percent dential (b) % 

# X: % '7. '7. % '10 % 

# 0 Mark 

### CO this box if 

### you attac:h a c:ontinuation sheet. 4. Synonyms - E."lter 

### any chemical synonyz:ns fa the new chemic:al. substanceidentified in sub!ledon 1 or 2.



# ~:l 

# . 

# 0 Marl: 

### CO this box if

### you attach a amtinuation sheet. S. T.rade icienti.-'iat:ioa
- List traCenames for the new **chemical.~** identified in subse::ticn 1 ar2. 

# 0 Mar.k 

### 00 this box if

### you attadl a amtinuati.on sheet. 

# . 6. Generic: chemial name - If you ci3im dlemic:::U identity as =Uiciential. you·mustprovide a generic chemic:::U name for 

### y= substance that reveals the 

### specific chemic:::U identity of. the new chemicl substance to the maximum extent possible. Reier to the TSC.o\ Chemical. Substance Inventory, 1985 Editian, 

### Appendix B for guidance on developing · 

# . . 

# . ge:nencnames. 

# .



# \0\od\{\~ **?o\j\S.o~y~ll'o-te** D Marl: 

### 00 .this box if 

### you attach a amtinuation sheet. 7. ByprodumDe&::ibe 

### any byprodud:! resultingfrom the 

### mmuiac::lre.
**~g,** 1l:le.. 

### a 

## disposal r:i the 

### new che:nic:::U **~** Provide the CAS Registry Number if available. · Byproduct CAS 

### Registry Number Conii- (l) (2) dcntial. 

# - . 

# -

. 

# D M:zr.k (X) this box if you attach a CDntinuatlat sheet. 

## I FORM EPA 7710-:ZS (Rev. 5-95) Pagt'6Q-

••• , ' • ' • -.>o 

### I I

## Pari I 

## -GENERAL INFORMATION- Continued Section B -CHEMICAL IDENTITY INFORMATION
- Continued l. lmpuritles ;.

(.l)- IdmUfy eadllraputity th..t m;ay be reuoD.>bly :mtic:i!"'*ed to beprew:Dt In the c:hemia.IJabd:mce a **m.m~** far a:nnmerc:iaJ. purpo.es. 

## . Provide the CAS
**R~** Numl>er If nai.Uble.. If there..., wdc:ntified lmputltla. ealier"v.D.idc:ntified.• ·

(b) -&Um.ote the m;aximum weisht ,. of 

### eaca lmpur.tty. 

## u **then:~** 'llllidc:ntifiecilmpurltia,. atim&.e thdrtoW weight'"· Impurity 

### and CAS Regi:st:ry Number

**~** Maximum Coaii- (a) pera:nt denrial (b) 'K. 

# ')( % '7. '7. '7. 'K. % 

# . Q_ Mark 00 this box if you attach a amtinuatian 

### sheet. 4. Synonym• - E."lter any chemic::al. synonyms fer the new 

### d!emic:al. substanceicienti.6.ed. 

### ±n **su~on** 1 or 2. 

# . 

# =I 0 Marx 

### 00 this box ifyou attadl. a continuation sheet. 

## s. Tr.ade 

### i.dent:ifu:at:i.ao- Ust t:racienames fer thenew 

### c:hemic:alsubatanc:e identifiedin subeedcn 1 or

### 2. 

# >< . 

# 0 Marx CO 

### this box if you attach a continuation sheet. 

# . 6. Generic dlemic!.l nameIf you claim cilemic::d identity as 

### ccruld.ential. you·muat provide a generic chemic::d name for your substance that reveals the 

### specific d!e:micll. identity oi the new chemic:al substance to the maximum extent possible. Reier tc 

### the TSC.o\ Ctemicll Substance Inventory, 1985 ECitlat, **~c!lx** Bfor guidance on developing 

## . . 

# . ge:nenc names. 

# .



# ~0(~\-\-\~ **~o\ y\~C:C.'{O-.'f'O-"t** 

# e.. ·. '


## . 

# 0 Marx (X) .this box ifyou 

### attach a amt:lnuatia:t 

### sheet. 7. ByprociucaDe:lc:ibe any byproduc%3 resulting £rem the mmuiac:::lre. **~g, u:~e.**  **or~** oi the new chemical sub8ta.nc:e. Provide the CAS Registry Number 

### if available.. · Bypnxiuct. 

### CAS Registry Number CQnfi.- (1) (2) denrial 

# .. . 

# -

- 

# 0 Mar.k: 00 thia box if you at:t:a.d\ a a:mtinuaticn sheet. 

### I FORM EPA mo.25 (Rev. .>95) Page 

### 6!::-. 

# e

_._., n ,,. --- **>•L~** .... **~** •-

**~** .. **~~** I

## Part I -GENERAL INFORMATION- Contiriued**~** Section C- PRODUCTION, IMPORT, AND USE INFORMATION: Mark 

### 00 the "Confidential" box 

### next to any item you claim as 

### confidential · 1. 

### Production volume- Estimate the 

### maximum production volume during the first 12 months of production. Also estimate the maximum production volume for any consecutive 12-month 

### period during the first three years of production. 

### Estimates should 

### be, 100% new 

### chemical substance basis. For a Low Volw:ne Exemption application, 

### if you 

### choose to 

### have your notice reviewed at a lowe production volume than 10,000 kg/yr, specify the volume and mark (X) 

### in the binding 

### box. 

### If granted, you are bound to 

### this volumE Maximum 

### first 12-month production (kg/yr) Maximum 12-month production (kg/yr) Con£i- Blaclbas 

### denti.al Optioa 

### (100% new chemical substance basis) (100% new 

### chemical substance basis) Muk(x)



# . )( 2. Use 

### Information - You must make separate confidentiality claims 

### for the description of the category of

## uR, the percent of Foo,uction volume devoted to each category, the formulation of 

### the new substance, and 

### other use information. Mark 

### 00 the 

### "Confidential" Box 

### next to any item you claim as 

### confidential _ . a. (l) - 

### Desaibe each 

### intended category of use of the 

### new chemical substance 

### by function and application. ., (2) - 

### Mark (X) this cchmm if 

### entry in mlumn (1) is 

### confidential business**~tian** 

### (CBD. · · (3) - Indicate your willingness to 

### have the 

### information provided in 

### column (1) 

### binding. "



### (4)- Estimate the.percent of total

### F,Oduction for the first three 

### years devoted to 

### each category 

### ofuse. " ; (5) - 

### Mark (X) this 

### column if 

### entry in 

### mlumn (4) is 

### confidential business information 

### (CBD. · 

## ·- (6) - 

### Estimate the percent of 

### the new substance as formulated in mixtures, suspensioDa, 

### emulsions, solutions, or**~** as 

### manufactured for commercial 

### purpoees at sites 

### under your control usociated with 

### each category 

### oi use. (7) - 

### Mark (X) this 

### column if

### entry in mlumn (6) is 

### confidentialbusiness information 

### (CBD. . (8) - Indicate 110 of 

### product volume expected 

### for the listed 

### "use" 

### sectors. Mark 

### more than 

### one box 

### if appropriate. 

### Mark 

# . (X) 

### to indicate your willingness to 

### have the 

### use 

### type provided in 

### (8) binding. . (9) - Mark (X) this cchmm if

### entry(ies) in mlumn (8) is (are) 

### amfldenti.al business 

### informaticm (CBD. Category of 

### use (1) CBl 'BmcUa1 

### Proc:iuc- 

### CBI '!I. in 

### CB1 '!1. of substance.expected

### per use

### ~ (by function and application i.e.· 

### a dispersive dye for Optioll tion"' Form- 

### (8) Muk(x)· 

### ulation finishing polyester fibers) 

### f:xte-**·~·** Indus- Com- Binciing (2) (3) 

### (4) (5) (6) 

# m limiteci**~er** trial merc:ial Option ( 

# 'X % 

# )( % 

# :X ,, 

# f:l, % % % 

### % % 

### % 

## . % %



### . % 

### % %' % 

### •If you have identified a "consumer" 

### use, please provide on a continuation sheet a detaued description of 

### the use(s) of

### this chemical substance in consumer products. 

### In addition include estimates 

### ofthe concentration 

### of the new 

### chemical substance as expected in consumer products and describe the 

### chemical reactions by**which~** 

### substance loses 

### its identity in the consumer product. 

# D Mark (X) this box if 

### you attach a continuation sheet. 

### b. Generic If

### you claim 

### any category 

### oi use deila:ipt:lan In 

### subsec:timl. 2a u 

### amfidential. enter a geMric desc:riptioo 

### oi that use category. Read the 

### IDitrUc:t:iaaa Manualfor 

### examples 

### oi generic.

### use deacriptianL • 

### desaiption

# ~~(}-.~~~~" 0 Mark (X) this box if

### you attac:h a canl:lnuatian sheet. 3. Hazard 

### IDfozmatkm- lndudein the notice a copy 

### oiteMClnllble 

### fac:aimile 

### oi any hazard warning 

### statement,. 

### label. material safety data 

### lbeet. llladi 

### or otherinformation which willbe provided to 

### any 

### pe:raoo wbo 

### Ia reuonably Ukely to be expoaed to this 

### subeamce regarding protedive Optic 

### I

# D**~pment** 01: 

### practices foe the safe handling, transport. 

### use. or 

### dispoaal. of the 

### new suhstaDoe. u.t

### in 

### put 

## m**~information.**

### you indude. Waril: 

### Mark 00 this box if 

### vou attach hazard 

### Information. · · · · · 

### FORM EPA 7710.25 

### (Rev. 5-95)

## Part. II - HUMAN EXPOSURE AND ENVIRONMENT At RELEASE



## Sectio~ A - lNDUSTRIAL SITES CONTROLLED BY THE SUBMlIIER Mark 

### 00 the


## ·eo~dential" **bo~** next to 

### any item 

### you Complete secti011 A foe each type of DWlufactare, prace..ut&- oc UM opentioa involving tbe new chemical JUbllallce at uuiu8trialsita y011 coatro lmporten.do not have ID complete tbillect:ioD for opuatiaile aabide tbe U.S.; however, 

### yoa 

### may ltUl have 

### repart:iDg requimzwsta if tbU'I! Ill further i.Ddv.atrial proceAing oru• operatiaaa after impcllt. Yoa 111111t deKribe these operatiolll. See i.Datrv.ctiODI 

### m.mul. · 

# . . . 

### .. ' ', . 

### . ' . 

## . .. •


## . ·., .: .. a. of the site at 

### wbic:h the 

## Will occur.



## ... Name' '

**.~.** . 

### . •,. ·

.... :1:·- •., ,''.\1• ' !'

**.~:** ,, •;,, : '•• •'J: I 0 ',:, '' •,,. · .. ' ,. II .. :··'' •' ,' ···:' 

### . .. 

### ... ' :· ::; 

## ... ·:i. ··. ·Site and street). 

### Clty, County, State,

**ZIP~** U. the same operatiaa

**~** oa:ur 

### at more than 

# aae lille, 

### enter the 

### number of. lites. 

### Identify the additional !lites on a ccatirluatiaa sheet, and ifay of. tbe lites have ligrlificantly diliermt · 

# > production rates oc 

### operatiODB, indude 

### Ill the inicnNti.Oil 

### requatediD thilleCti.an lor

**the.~** attach a ccadnuatitm lheet. 

### b. Type- .

MarkOO 

# 0 Pioc:e.utg 

# Ou. · 1. 

### B.tc:h ci 

### P:roces 

### clelc:riptial\ Mark 

### oo 

## miadicaellyCIIU wUliap-

# •••1'CIIIIr

**pnaca~** dncript:laa btltdiDJ. (1) Diagram

### -the major unit 

### operati011 stepa 

### Ind.

**~** CDII\IInka.

**~** 1nterbn ltaragemc:l

**traD~pC~rt** 

### a:ntalnen (spedfy--Lg. S gallaa pels, 5 gallon 

### drUm. rail 

### c:ar, tank truck, etc:.). · · . · · · · (2) 

### Provide the identity, the apprmdmate weight 

### (by 

### kg/day arkg/'blldt aa111'll:m 

### new 

### c:beiJ;Iical. subltanae

### basis), md entry pcint of. all starting materlala and .feedlltrx:kl (indudingre.dmta, aalvedl, mel 

### c:at:al:ylta, &),llld of. aD prodUdl, 

### ncydeICnmal, IDd wuteL lndude delming chemicals (note

### frequency ifnot 

### uaeci 

### cbiily ar per Du!L). · · . · · · · ('3) Identify by

**num~** the pointa of.

## re-,. inc:ludlllg 

### snailoc IDII!rmittllllt ,._.., 

### to lbe

# I!IIYirOilment oithe newchemical sublltanc:e.



# 0 Mark 00 this box if you attach a COIItinuatiCXI sheet. FORM EPA 7710.25 (Rev. 5-95) 

## ...

.. 

## ·.

## Part II -- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE- Continued



# ~ Section A- INDUSTRIAL SITES CONTROLLED BY THE SUBMII I l:ili.- 

### Continued 2. Occupational Exposure- You must make separate confidentiality daims for the desa:iption of worker activity, physicll. form of the new chemical

substance, number of workers exposed. and duration of activity. Mark (X) the "Confidential" box ne:ct to any item you claim as amfidential. (T)- Describe the activities (e.g. bag dumping, tote filling, unloading drums, sampling, cleaning, etc.) in which workers may be exposed to the substance. (2)- Mark (X) this column ifentry in column (1) is confidential .business information (CBI}. (3) - Describe any protective equipment and engineering controls used to protect workers. . (4) and (6)- Indicate you willingness to have the information provided in column (3) or (5) binding. . (5)- Indicate the physical form(s) of the new chemical substance (e.g. solid: crystal, granule, powder, or dust) and% new chemical substance (ifpart of a mixture) at the time of exposure. \7) - Mark (X) this column if entry in column (5) is confiqential business information (CBI). (8)- Estimate the maximum number of workers involved in each activity for all sites combined. (9)- Mark 

### 00 this column ifentry in column (8) is confidential business information (CBl). (10) and (11)- Estimate the maximum duration of the activity for any worker in hours per day and days per year. (12)- Mark (X) this column ifentries in columns (10) and (11) are confidential business information {CBI). Worker activity CBI Protective Equipment!

**~inding** i' nys1cai form\SI !Binding CBI I of CBI Maximum duration CBI (e.g. bag dumping. .filling drums) Engineering Controls pption (e.g.solid:powder) pption Workers

**~arit** (x) and% new r.tar1c (x) Exposed Hrs/day Days/yr 

### ffi (2) (3) (4) **subs~ce** 

### IEl 

### m (8) (9) (10) (11) 

## Il12l



### ... 

# 0 Mark (X) this box if you attach a amtinuation sheet. 3. Environmental Release and Disposal- You must make separate confidentiality claims for the release number and the amount of the new chemical substance released and other release and 

### disposal information. Mark (X) the "Confidential" box next to each item you claim as confidential. (1) - Enter the number of each release pointidentified in the process description, part II, section A, subsection ld(3). . . (2) - Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch). (3) - Mark (X) this column ifentries in columns (1) and (2) are mnfidential business information (CBI). (4) - Identify the media of release ie. stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land orincineration, P01W, or other (please specify) to which the new substance will be released from that release point. (5) - a. Describe control technology, if any, ,and control efficiency that will beused to limit the release of the new substance to the environment. For releases disposed of on land, characterize the disposal method and state whether itis approved for disposal of RCRA hazardous waste. 

### On a continuation sheet , for each site describe any additional disposal methods that will be used and whether the waste is subject to secondary or tertiary on-site treatment. b. Estimate the amount released to the environment after control technology (in kg/day). (6) - Mark (X) this column if entries in columns (4) and (5) are mnfidential business information (CBI). \7) - Identify the destination(s} ofreleases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct ··dischargers or NPDES numbers of the P01W (Publicly Owned Treatment Works). Mark (X) if the PO'IW name or NPDES #is confidential business information (CBI). Release Amount ofnew substance CBI Media of Control technology and efficiency (you may wish to optionally attach efficiency data) CBI Number release : Blncllng (1) (2a) (2b) e.g. otackalr (3) (4) (Sa) MarkU<) (Sb) (6) I I I I I I I I I I I I I I I I (7) Mark (X) the 

# D POTW provide name(s) below: 

### CBI 

# 0 Navigable 

# 0 Other- Specify provide NPDES 

### # CBI destination(s) of 

# - waterway releases to water. 

# 0 Mark (X) this box if you attach a continuation sheet. FORM EPA 7710..25 (Rev. S-95) Page9 

# //

## .. PartII- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE- Continued • Section B- INDUSTRIAL SITES CONTR.OLLED BY O'l1li!RS Completeeec:tlan B

**~typical** procesalngor use operationsinvolvh!g thenew dlemica1 substance at sUes youdonot amtrol.Importendo nothaVI to complete thistii!Ctlolla Operatlcms outsidetheU.S.;however, youiDUIII:tepcld anyproce88IDg oruse activities afterimport. See**the~**

**.~** 

### ManuaL Ctmqlltle • 

### ,.,.refiCtion B

### forllldt

### type 

### of

**Jm~CtSSillg,"',.**

### opcrafim iii'IIOltlillg 

### tire ,.,.,c1rernit:tll

**~** Ifthe

### same operation :Is & atmore than one llile

### daiCilbe the typiCIIoperali<m CQII\11\011 to

### thele aill!8. 

### Identify 

### additional sitesona continuallon sheet. 

## 11. OpuatioD Dacriptial- Todaim.mfonnatlmill this section asClllllfldeolilll, c:irde 01'

### bladrdthespecifk:iniOI'matiolllhatyoudaiJn ascxm&denllal

## jos, (l)- 

### Diapmthemajorunitoperatiollllll!pB anddlemicalcxmvemions, indudiagiDterlm 

## storaue and

### tranaport Clllllainenl 

### (specify- 

### e.g. 5 

### pUoo p 

### 55p11on ciNme,. rail 

### an, bmktrw:b, ete). 01\ thediagram,

### Jdciulify byJetter andbriellydeacdbeeachwmbs: activity. (2)- Provide the identity, the appoxilltateMight(bykg/dayorkg/balda,on an



### 1~**~**dteadalllll.1blltancebasis),andeDirypoiDt ofalleedstorb (including 

### reaclaDis,

**solvent~~** and

**calal~** etc) andof

## an produds,teeye1e lltl.'eamlf.and Wlllls.Includedeaningdtemic:als (Dole&equePcyifnot useddalyor

### per batcb). (J)-lden byIIUIDber the poiDIB ofJeJeaee, indudingamal arilltennitllent le1eases, to theenvlroJIJQent oEthe newchemical 

### eubetancle. (4) Please entar lhe II oflites ( temell\ber toidentifythe localklasoltheaeBites m a cantinuatiClll sheet) : {_ 

### iohak!B 

## We do not have the information on worker ex:posure or environmental release.



# I

# 0 MaJ:k 00this boxif youattad\ a Clllllinuatlon sheet. 2. **Warlrer~IReleue** (1)- Fromthe diaplnabove,pnwidethe letter' lot'each WOI'ker aclivtly. Comp1ele 2-8 lot'

# each-- activity dellcribed. (2)- Eadmate themmtb.ofMll'lcenexpoeedfor allaitee Cllllllbined. · (4)- Estimate the typical cluratkln oE

### exposw:e per workerin (a)hoursperday and (b) dayw peryear. 

### j!d (6)- Describephyaical fonn

**of~** and 1ro newc:bemicaliiUbelance Of inDdxture), andanyprotec:tlweequipanent and engineedngClllltrols 1.11 toprotect worbn. (1)- B'slllnale thepel'Q!llt ofthenewsubstance asfonnulaled when packaged orusedasa final product. (9)- From the 

### poceaa di.agramabove. enter the nuuiber ofeadlreleaaepaint. CompJele9-13 lot'each release point idenHfied. (10)- F.sllmale the amount ofthe 

### new 8Ublltance :re1eaBed (a) dindytotheenviromnentor (b)into Clllllrol tec:lmology to theenv.homDeatt (inkg/day Ill"kg/baldt). (12)- Describe media ofrelease i.e. !lladc alr,.fusitlve air 

### (optional-see hultrudloas Manwd),swfacewater, OIHIIe arofHUelandorilldneratlcm. POlW,orother (spedfy) andcontrol tec:bnology,lfany, tbat wDl be used tolianit the :releaseofthe newaubalance totheenviromnent. (14) -ldeollfybyprocludswhich mayreeultfrom the 

### operattoa. (3), (5), (8), (11), (13) lllld (15) - Mark 00this mJumn if any oEtheproceeding eDtries areCIDRfidel\tial businellsillfclriDatiorl (CBJ). Letter tlol 

### CBI DuraliClll 

### CBI Protective Equip./ 

### l"in CBI Release Alnountof CBI Mectia ofRelease 

### t:BI

oE Workers of EDgineeringControJs/ Penn- NllDlber New A: Control Act- Exposed 

### Exposure Physical Form lllld " ulation Substance Tecbnology ivity newsubstance Released 

### I (1) (2) (3) (4al 

### I {4bl (5) (6) (1) (8) (9) (100 : (JOb) 

### lm (12) 

## lla> I I 

### I I



## ~ 

# ! I I I I 

# ! I I I 

# : I I I I 

### I I 

# ! I (14) Byproducts: 5) 

# 0 Mark 00this box ifyou attach a (li)Jltinuatlon sheet. FORM EPA 7710-25 (Rev.S-95) Page10

## .. 

## OPTIONAL POLLUTION PREVENTION INFORMATION To 

### claiminformationinthis sectionas c:onfidential cln:leor

### bracketthe specific information that

### you claim 

### asoonfidential. 

## In this 

## sectionyoumayprovideinformationnot

## reported elsewhere inthis form regardingyour efforts toreduce or minimize

## potential risks associated with 

## activities surrounding manufacturing,

# processing, use and disposalofthe PMN substance. Please include new informationpertinenttopollution prevention, including sourcereduction, recycling activities and saferprocesses or products available due to thenew chemical substance. Source reduction includes the reduction in

## the amountortoxicity of

## chemical wastes by

## technological modification, process andprocedure modification,productreformulation, raw materials substitution, and/ orinventorycontrol. Recycling refers to the 

## reclamation ofuseful 

## chemical components from wastes that

## would otherwise

## be treated or 

## released as air 

## emissions or water discharges, or land 

## disposal. Descriptions of

## pollutionprevention, source reduction and recycling should emphasizepotential risk

## reduction subsequent to compliance with 

## existing regulatory requirements and can be

## either quantitative orqualitative. TheEPA is 

## interested in this information to assess overall netreductions in 

## toxicity orenvironmental releases and exposures, not the 

## shifting of

## risks 

## to other environmental media ornon-environmental areas (e.g., occupational or oonsumer exposure). In

## addition, information on the 

## relative cost or performance characteriS.tics ofthe PMN substanceto potential alternatives may

## be provided. All informationprovided 

## in

## this section

## will be takeninto consideration during

## thereview ofthis 

## substance. Seethe 

## revised Instructions

## Manual 

## thatincludes a PollutionPrevention manualfor

## guidance andexamples. Describe theexpected net

### benefits, 

### such as (1) 

### an overall :reduction inrisktohuman

### health or

### theenvironment; (2) 

### a :reduction 

### in thevolumemanufactured; (3) 

### a reduction 

### in thegeneration ofwaste

### materials tluough recycling, sourcemductionorother 

### means; (4) 

### a ftduc:tion in

### potentialtoxicity 

### orhuman 

### exposwe and/or

### environmental release; (5) 

### anin.cn!ase 

### inproduct 

### per1'ormal¥:e, a decrease in

### thecost of

### production and/or

### improved operation efficiency

### ofthenew

### chemical substarulein oomparison to existing

### c:hemicalll1ibstances used in similar

### applications;or (6) the

### extent to whichthe new

### chemical substance maybea 

### substitutefor an

### exiSting substancethat

### poses a greater 

### overallriskto human health 

### ortheenvironment.



# 0 Mark (X) this box 

### ifyou 

### attach a continuation sheet.

FORMEPA7'110-2S (Rev. !HIS) 

## Posen 

# 13

**--·~~~··--"""=**...**~~-- -~** ...

**~.** I ' i

## ... 

## Partm-USTOPA1TACHMENTS Allachoaaftrm811an llheals b 8IICIIoaltaflhefama .adliStdataandadlerdata (Jndul:lblac:=daaDk:alpopedii!Baad. IIINCbn/lldl¥il;yblfmiiatk!D),8DCloplkmallafcJmldm after lids

### paae. 

# Oeldyidea:t.: alladanentlllldlheseclklla oflbebm lo 

### which JtN!ale!I.Jfappopdllle. 

### Number

## C111D181:1J1i.vtlteJ'IW!Softile

## .a-tnnena Ja CXJlumnbelow, ea1e:r 

### tbeilldalivepese IIUIDIIela

### ofeada eftal'tmuoDt Mark

### 00 lbe 

### "'nnfldenll.rboxaext

### toayattadnn•t....you dlllm 

### asCCIIIfillel:dia Read lhe lallradlall•.......,.lar 

### coahowlodabn 8DJillfuun.Unn

### m•llllal::lameDtas gjn6dentlaL 

### Yoamuatilldadewith lbe...,li:r.ed C10P.V

### oflheaolicle llllllbled.Willian

### olaay_almdulleatm whidJ.

### JOU.daimiDfarn-llcm asmafideDtlat. AUadlmeotl\8me 

### Allac:luDeot



# ~

# ~ 'JI8PDUJDIIelfJa) 

# Material Safety

## Data Sheet (MSDS) 13o; 18"' 

## GPC Chart 1 9lli:20Q. 

# X IR Chart 21r22 £1.. 

# X CAS Inventory Exp$rt Service 23a. 

# )< Continuation sheet,



# ·page4~(> ..... 

# t;,.. B 1.. 

# e 24 0.. 

# >< Physical and Chemical Properttes worksheet 2501.



## ~ASD~ '

**\~h-L.~h**



### c~?c 

# rlln V'\-

**~qb-~h** 

# )< 

# IR

**rJL.~t- d..l~n-1lb**  

# . 

# ., I 

# c

**~s** LA\I!P, 

# ·h..v'-1 "B:vVJ_(;> 

# rt 

# c e.Y'VIU )



### ~ 

## \,. 

# x C .h

# 1i



# ~ct **r~T** 

# ')-.e-e'.o:t ?(J..A,o 

# 4

**~1"-J-l~** \3 of p 

# ".1-4-. 

# \n X

**~A** ..\•u c._

# :1 (> .. 

# J

**(t~~~** I 

# \PvtnnnA1.\A 

# \A//}v-f§Jon!- '2.J)\r,

**~** 

# T



# 0 Mark

### 00 lidsbox If,YOUatlacb a cmdiDuationsheet. Iiiialhe8ltaduDeat IllUDeandnumlJer. FORM EPA T/10.25 (Rev. 5-95) 

### Papl2

=---• _,__,,- **••---~c .........-=-~**  -•o•r-c-< I_,

**~** - ..... , I 

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll Date 

### of printing: July 

### 7, 2003 Version: No.UO Date 

### of revision: Date 

### of issue: July 

### 1, 2003 

# Product name: = ----- ....... 

# 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name General description Manufacturer Modified polyisocyanate 

## Emergency telephone number
·- 

### ----- -·- 

### .... 

## (Monday - Friday, 9:00 a.m. - 6:00 p.m.) 

# 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name Modified polyisocyanate 

## Control parameters Residual HDI monomer is less than 0.4 

## wt<»lo 

# 3. HAZARDS IDENTIFICATION NFPA ratings ( scale 0-4 ) Emergency overview Major health hazards wt% 

## CAS registrY >99 ACGlli(1LV-TWA)2001 O.Olppm DFG MAK (peak) 2001 Health=2, Fire=!, Reactivity=! 

## Harmful ifinhaled, respiratory tract irritation, skin irritation, eye irritation allergic reactions. 

## Physical hazards Maypolymerize. Container may rupture or explode. May react on contact with water. 

## Potential health effect Inhalation Short term exposure: irritation, allergic reactions, wheezing, asthma, lung congestion. 

## Long term exposure: lung damage 

## Skin contact Short 

## term exposure: irritation, blisters, rash 

## Long term exposure: itching 

## Eye contact Short term exposure: irritation, tearing 

## Long term exposure: same as effects reported in short tenn exposure. 

## Ingestion

**--·~--....--.--.-=--~,---~** 

### .....------ ! 

### 1

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll 

# Product name: Short term exposure: vomiting 

## Long tenn exposure: not available 

## Carcinogen status OSHA: no NTP:no 

## IARC:no 

# 4. FIRST AID MEASURES Eye contact 

# - ....... 

### Date of printing: July

### 7, 2003 

### Version: No.UO Date ofrevision: Date ofissue: July 

### 1, 2003



## Hold eyelids apart and immediately flush eyes with plenty ofwater for at least 15 minutes. Seek immediate medical advice. 

## Skin contact Remove all contaminated clothing and shoes immediately. Wash the contaminated area·thoroughly with. watetfollowed by soap. 

## If

irritation persists or inflammation is caused, ·seek medical advice. 

## Inhalation Remove the patient immediately to an area with fresh air. Seek medical attention. 

## Ingestion Ifswallowed, seek medical advice immediately. Wash out mouth with water. Do not induce vomiting. 

## Try to get the patient to vomit ifhe is positive. 

# 5. FIRE FIGHTING :MEASURES Flash point Autoignition point Range ofexplosion Flammability Combustibility Oxidizibility 

## 421F (216"C), detennined by open cup flash test.
Selfreactivity Dust explosion 

## General hazard Not available Not available None Yes None None None During a fire, aerosols or gases may be generated through decomposition. 

## Fire fighting instructions Positive pressure self-contained breathing apparatus and full protective clothing and gloves 2 

# /6

... **-.~-~··< --.-.----~"',.___**  **~-** 

## .......... ' '

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll


# Product name: should be provided. Date ofprinting: July 

### 7, 2003 

### Version: No.UO Date ofrevision: Date ofissue: July 

### 1, 2003


### Splash water onto drums and facilities which are not on 

### fire to avoid 

## fire spreading and heat evolved. After the 

## fire is extinguished, neutralize the spilled material with decontaminant. Restrict entry ofunauthorized personnel. Extinguishing media: dry chemical powder, carbon dioxide, water and foam. 

# 6.. ACCIDENTAL RELEASE l\1EASURES General Protective goggles, rubber gloves, and gas mask should be worn. Restrict entry ofunauthorized personnel. Stay in 

## windward position at the time ofdisposal. The hazard area should be well-ventilated. Safely stop discharge. Small spill Neutralize the leakage/spillage with decontaminant, or by admixing it with sand, clay or sawdust. Dispose ofin a closed chemical waste container. Large spill Admix with sand, clay or sawdust to prevent the spillage/leakage from further spreading out. Dispose ofin a chemical waste container. This container should not be closed. Neutralize the residues with decontaminant. Wash the spillage area clean with water. 

# 7. HANDLING AND STORAGE Handling The operator should be trained in handling this product. Appropriate safety measures and protective equipment should be used for this operation. Provide adequate ventilation and the operator should use protective equipment. When the 

## drum is pressurized, unscrew the bung slowly to release the pressure before taking it off. This product should not be filled in an unwashed or wet container. The use offrre is strictly prohibited in the work area. Those who show allergenic and sensitizing effects should not be in charge. Storage Keep container properly sealed and store indoors in a weli ventilated area. 

# 17 3

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll 

# Product name: ........................................ -= 

### Date ofprinting: July 

### 7, 2003 Version: No.UO Date ofrevision: Date ofissue: July 

### 1, 2003


## Once opened, the container should be closed and sealed with nitrogen gas. Ifstored outdoors, the container should be covered with waterproofcanvas sheet to 

## avoid being exposed in the rain. The use 

## offire 

## is strictly prohibited in

## the work area. 

# 8. EXPOSURE CONTROLS 

# I PERSONAL PROTECTION Engineering controls 

## Local exhaust ventilation should be 

## provided for indoors use. Readily accessible eye and hand wash stations should be 

## provided. Personal protection 

## Chemical goggles, rubber gloves and suitable respiratory equipment. Exposure limit: 

## Refer to Section 2 

# 9. PHYSICAL AND CHEMICAL·PROPERTIES Physical form Color Odor Boiling point Vapor pressure Evaporation rate Freezing point Specific gravity Initial boiling point Viscosity Solubility (water) Solubility (other) Liquid Pale yellow No odor None None None

**-4F(~20t)** 

## 1.079 

## at 73F(23°C) 

## Not available 100 mPa·s at 77F(25"C) 

## Insoluble Soluble in 

## toluene, ethyl acetate or acetone Note: The above data are typical physical properties and should not be taken as a specification. 

# lO.STABILITY AND REACTIVITY Chemical stability (Condition to avoid) High 

## temperature and moisture. Incompatibility 

## This product reacts with materials with active hydrogen groups such as amines and alcohols. 4

# MATERIAL SAFETY DATA SHEET llllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllltlllllllllllllllllllllllllllllllllllllll

--- ---- --- ___..! 

# Product name: Hazardous decomposition product Reaction with 

## water produces heat and carbon dioxide gas. Hazardous polymerization Date of printing: July 

### 7, 2003 Version: No.UO Date ofrevision: Date ofissue: July 

### I, 2003



## will occur. It

## gets polymerized by alkaline materials or

## tertiary amines. 

# 11.TOXICOLOGICAL INFORMATION Corrosive properties Irritant properties Allergeric & 

## sensitizing effects Acute toxicity Sub-acute toxicity Chronic toxicity Not available Not available Not available Not available Not available Repeated exposure may cause an allergic sensitization ofthe respiratory tract. Carcinogenic effects Not available Mutagenic effects Not available Effects on the reproductive system Not available Teratogenic effects Not available Others This material is not listed by IARC, OSHA, or NTP. 

# 12.ECOLOGICALINFORMATION Biodegradability Bioaccumulation Fish toxicity Other information on ecotoxicity 

# 13.DISPOSAL CONSIDERATIONS Disposal methods Not available Not available Not available Not available This product should be incinerated in an appropriate facility. This product should be treated by authorized agents professionally trained in disposing industrial waste. This product should be disposed ofafter forming solid foam through reaction with polyol. Mix 

## this product with decontaminant to form urea compound through chemical reaction, and remove the toxicity by dripping the mix and being left to stand for 24 hours. 5

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll Date ofprinting: July 

### 7, 2003 Version: No.UO Date of revision: 

### Date ofissue: July 

### 1, 2003 

# Product name:
__ _.:1: ,.._ .... **.._~ ~.**  II

## Handling empty container after use Empty 

## drum should be left to stand with water and left unsealed for 24 hoW'S. Water should subsequently be removed afterward. Used container should be punctured and scrapped. 

# 14.TRANSPORT INFORMATION Proper shipping name: Modified polyisocyanate Hazardous class: Not applicable Identification no.: Not applicable 

## IMDG class : Not applicable Follow all the regulations in your country. Be sure that the container is tightly sealed, that no leakage is found and that all the necessary indications 

## are specified. Filling, loading and extracting operations should be performed under the supervision ofan authorized operator. · ·· · Nitrogen gas or 

## dry 

## air should be charged into the container for transportation 

## after fllling or extracting. 

# 15.REGULATORY INFORMATION U.S. regulations Not confirmed U.S. inventory Not confirmed TSCA 12(b) export notification Not confirmed. Regulatory information with regard to this substance in your country should be examined by your own responsibility. 

# 16.0THER INFORMATION Reason for issue: Prepared by : Update to new format Technical department All the chemical materials maypresent unknown hazards and should be used in caution. The information herein is given in good faith, but no warranty, express or implied is made. Consult Nippon Polyurethane Industry Co., Ltd. for further information.

**-·~~_.~** 

# - ..

**~~ -··~,..,....,.**  i 

### 6-= ., ..,.....__. !

### -·I

# .2CJA



# ~-~-,,--,.-~··""!--:-~-··--~-· . ,. . ,,,_, " . 1

## PHYSICAL AND CHEMICAL PROPERTIES WO:a:KSHEET To8ll8lstEPA'sreviewof

### ph~ chemic:alpaperHesdata. 

### 1'1-complele thefollowingWodalheetbdatayouprovide 

### ud.JadudeItill theDOtlae. the**property~** lite

### papalthe

### notiae em whld\ the plaperly

### appears. the

### Value of**the~** theualtsin whidl.thepropeatyia --.. ;;::::::l.),aDdwhether al'llot**the~c:1aimeclas** 

# ....,a..,..tiaJ ph;plallataofthe Delli: llllbetaaaeshould be These11l41881Jn1Cl propert1e1J belor

**the~** noow. puze) c:l1emil:aliAiblltmc:e. PIOpertlee that

### aremeasured

### fclr mlxturel Gl"

### fcmau1ld:kms 

### ahou1d'be 110DOted (1. 

### PMN llll1lalanceiD 

### _).You arenotrequlledto

### aubmit 

### this worbheet;however,

### BPAibulglyrecoaunencls ht 

### you do 110, aslt

## wm eiiJlplifyJ'e\liew and e&I8Ul'e that amftdeallaliDformalion

# is= eleCted. You should

### submit Ibis wurbbeel:

### as a supplementto 

### your subJniasion of

### test dala. 

### 1blsworbheet isnot

### a 111 tu1e 

### aubmisalon oftest 

### clala. 

### Property 

# .!:. Value -.....4

# = MarkOOif or 

### provided 

# ......

**~** (a) (b) (c) tilarlO 

### ~4 Physicaletateofaeatsubabmae

- (s)...L. (I)- (K) 

### M Vapor-&::: Oem llure "C 

## NK Tatt Dellalty/J:etallve deaudty 

### g/cm3 Solubility "C

OTemperatare

Solvent 

### ft!L illwats OTi "C 

## Insoluble "C Mellin "C llallblg/aubllmalloJI. 

# • &orrpreasme Spectra 

## GPC, IR Dissociation cxmslant 

## NK Partideaizedistribullon Octanol/walerpartitionCIOeffid-• 

## NK Henry's Law CD.181ant 

## NK VontaJizallon from water 

## NK VoB.talizatiall &om soil 

## NK pH • CDJ\Celltraticm 

## NK Flam!nabi1ity 

## NO M ExplodabiJitr 

## No E Adsorplillll/coeOideut 

## NK Other- Spedfy 

## Viscosity 

## at 77F 100mP.s M 

# ..J..S-o...

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll 

# Product name: Date ofprinting: July 

### 7,.2003 

### Version: No.UO 

### Dale of 

### revision: Date ofissue: July 

### 1, 2003 

# 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name General description Manufacturer Modified polyisocyanate 

## Emergency telephone number (Monday -Friday, 9:00 a.m. - 6:00 p.m.) 

# 2. 

# COMPOSITION/INFORMATION ON INGREDIENTS Chemical name Modified polyisocyanate 

## Control parameters Residual HDI monomer is less than 

## 0.4 

## m&/o 

# 3. HAZARDS 

# IDENTIFICATION **~** 

## CAS 

## registry >99 1 

## ACGllf('ILV-TWA)2001 O.Olppm DFG MA.K (peak) 

## 2001 

## NFPA ratings ( scale 0-4 ) Emergency overview Health=2 Fire=l Reactivity=l 

## Major health hazards Harmful 

## ifinhaled, respiratory tract irritation, 

## skin irritation, eye irritation allergic reactions. 

## Physical hazards May polymerize. Container may rupture or explode. May 

## react on contact 

## with water. 

## Potential health effect Inhalation Short term exposure: irritation, allergic reactions, wheezing, asthma, lung congestion. 

## Long term exposure: lung damage 

## Skin contact Shortterm exposure: irritation, blisters, rash 

## Long term exposure: itching 

## Eye contact Shortterm exposure: irritation, tearing 

## Long term exposure: same as effects reported in short term exposure. 

## Ingestion 1 

# b

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll

- -- =--.eea.-· Short term exposure: vomiting 

## Long term exposure: not available 

## Carcinogen status OSHA: no NTP:no 

## IARC:no 

# 4. FIRST AID MEASURES Eye 

## contact Dale 

### ofprinting: July 7, 2003 

### Version: No.UO Dale 

### of revision: Date 

### ofissue: July 1, 2003



# ---

Hold eyelids apart and immediately flush eyes with plenty ofwater for at least 

## 15 minutes. Seekimmediate medical advice. 

## Skin contact Remove all contaminated clothing and shoes immediately. Wash the contaminated area thoroughly with water followed by soap. Ifirritation persists or inflammation is caused, seek medical advice. 

## Inhalation Remove the patient immediately to an area with fresh air. Seek medical attention. 

## Ingestion Ifswallowed, seek medical advice immediately. Wash out mouth with water. 

## Do not induce vomiting. 

## T:ry to get the patient to vomit if

## he is positive. 

# S. FIRE FIGHTINGMEASURES Flash 

## point Autoignition point Range ofexplosion Flammability Combustibility Oxidizibility 

## 414F (212t), determined by open cup flash test.
Selfreactivity Dust explosion 

## General hazard Not available Not available None Yes None None None During a fire, aerosols or gases may be generated through decomposition. 

## Fire fighting instructions Positive pressure self -contained breathing apparatus and full protective clothing and gloves 2

_ r- =---Or **,......._-••~•r"'~-** ,..,,.--- **-~·~•L'** I

# MATERIAL SAFETY DATA SHEET lllllllllllllllllllflllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll
-·--r----. 

# Product name:

should be provided. Dale 

### ofprinting: July 

### 7, 2003 Version: No.UO 

### Date of 

### revision: Dale 

### of issue: July 1, 2003 

## Splash water onto drums 

## and facilities which are not on fire 

## to avoid fire spreading and heat evolved. After the fire 

## is extinguished, neutralize the spilled material with decontaminant. Restrict entry ofunauthorized personnel. I 

## Extinguishing media: dry 

## chemical powder, carbon dioxide, water and foam. 

# 6. ACCIDENTAL RELEASE MEASURES General Protective goggles, rubber gloves, and gas 

## mask should be worn. Restrict entry ofunauthorized personnel. Stay 

## in windward position at the time ofdisposal. The hazard area 

## should be **well~ventilated.** 

## Safely stop discharge. Small spill 

## Neutralize the leakage/spillage with decontaminant, or by admixing it

## with sand, clay or sawdust. Dispose ofin a closed chemical waste container. LargespDI 

## Admix with sand, clay or sawdust to prevent the spillage/leakage from further spreading out. Dispose ofin a chemical waste 

## container. This container should not be closed. Neutralize the residues with decontaminant. 

## Wash the spillage 

# area clean with water. 

# 7. HANDLING AND STORAGE Handling The operator should be trained 

## in handling this product. Appropriate safety measures and protective equipment should be used for this operation. Provide adequate ventilation and the operator should use protective equipment. When 

## the drum 

## is pressurized, unscrew the bung slowly to release the pressure before taking it off. This product should not be filled in an unwashed or wet container. The use offire is strictly proln"bited in the work area. Those who show allergenic and sensitizing effects shorild not be in charge. Storage Keep container properly sealed and store indoors in a well ventilated area. Once opened, the container should be closed and sealed with nitrogen gas. 3

# llb 

# 3Z,

**·-·-··-~ ~---**  **--~~·-**

# lb>b



# 3~ '

**-·~~ ~~~**  o.c-

**~ --~·**  •. ' -• •

**"'-~'"'** 

## T

**-~- ~·-T~•-:r·-~** **----~-**

## PHYSICAL AND CHEMICAL PROPERTIES WOJU<SHEEI' Toulilll:BPA'arevlewofphr=anddlemiallproperlles&Wa. pleasecxmpJete**the~worbheetf«** dataJOUprovlde aDd badude ItIa theDOikle. dealifylbepoperty**~the** 

### pageoflbenotlCle 011 whidl 

### popertyappars.

### the

### Value of**the~** lbeualtalnwhicll**thep-opertyism~** (as .-ry),IIJicl whether arnot **the~l•c:1abDedas** Cllllfl e ph)'lllallltal8oftheneatllllbiltallceshoUldbeprcwlded.'l'helle-.ured

### poperta lielorthenat(lOOW. pule)cllemk:aliiUIMialcle. Properties tbatiiJemeiiUNCllor

### mixtures 

### or fonauJalfous 

### abouhi be 

### soDOted(!.

### PMNIIUbellmeein 

### _).You are :not

### requited to

## submit Ibis 'Mlll:bheel;

### however, 

### EPAsfmllslyrecommmdsthatyoudoso,asIt willtlimplifywviewandeiiiiiDe that CDDftdenHaJ 

### .lafannlllioais

### properly

### pmlec:led. You shouldsubmit this 

### worbheetasa su.ppJementto

### yourIIUbmisskm. oftest data. 

### 'l1dlworbheetis

### nota 1111bltlt.ulefor suhmillslo.n 

### oflest

### data. 

### Prapert:y 

### Page Value 

# ........ 

# = MarkOOif ar provided number Eollallle



## ~ {a) (b) (c:) 

# u:c INarlO Phyaiallstateofllaltsubstance

- (B)-X... Q)- (A:) 

### M Vaporpnsure OTemPIRlUre 

## ere NK TGn" 

### Density 

### /relative c1enally 

### g/cm3 Solubilit,y "C

0 Temperabae

Scivent ElL Solubililyin Wider • "C 

## Insoluble "C ture "C BollbldaubBmatlan 

# • &orrpreasme 5Jlectra 

## GPC, 

## IR Dlslloc:iatiOD amsbmt 

## NK •. Particle si7.A! disb:ibulion 

### Octancll/wala' partlliOD CXJeffident 

## NK Henrv's LawCIDDlllant 

## NK VoJilalizallon &um walel' 

## NK Volitalizatim &um 80ft 

## NK pH • CXJJ\CIII'Illratfon 

## NK FJammability 

## No M Explodability 

## No E Adsorplioa/coeftident 

## NK Other- Spedfy Ui e!r-r.co: i 

### t-v

**~i-.** 

### 77'F 

## 125mP.s M