# P2693 - TEQ **Project ID: P-10142** 

# Sample Summary **Part 1** 

# Method 23

**An alyte**  **0_8205_ MB001** **Run 1-**

**Dryer Run 2-** 

**Dryer Run 3-** 

**Dryer Run 1-** 

**Inlet Run 2-** 

**Inlet Run 3-** 

**Inlet Run 1-** 

**Outlet Run 2-** 

**Outlet Run 3-** 

**Outlet**
pg pg pg pg pg pg pg pg pg pg 2,3,7,8-TCDD (2.4) (2.04) (1.86) [2.46] [5.05] [2.75] [3.1] (1.54) (1.11) (1.41) 1,2,3,7,8-PeCDD (2.56) (1.95) (2.4) (2.78) 12.5 14.1 [8.16] (1.43) [1.32] (1.31) 1,2,3,4,7,8-HxCDD (2.67) (2.12) (1.78) (2.18) (1.9) 5.61 [4.32] (1.27) (0.84) (1.2) 1,2,3,6,7,8-HxCDD (2.7) (2.13) (1.81) (2.07) (1.77) 8.04 6.06 (1.25) (0.878) (1.17) 1,2,3,7,8,9-HxCDD (3.06) (2.21) (1.95) (2.27) (2.11) 9.73 [6.71] (1.34) [1.7] 2.76 1,2,3,4,6,7,8-HpCDD (2.78) 5.53 [9.68] 9.45 24.9 29.7 27.5 7.63 7.64 [7.66] OCDD (5.6) 34.6 49.2 [44.9] 133 151 167 82.3 63.1 44.3

2,3,7,8-TCDF (1.42) (1.36) [1.47] [1.48] 16.2 24.9 19 14.1 9.28 7.41 1,2,3,7,8-PeCDF (1.43) (1.53) (1.42) 1.46 7.34 16.6 14.6 3.85 [2.68] [3.12] 2,3,4,7,8-PeCDF (1.38) (1.41) (1.31) [1.31] [5.42] 8.94 10.5 [3.42] 2.58 4.01 1,2,3,4,7,8-HxCDF (1.69) (1.36) [1.63] (1.36) 5.97 6.64 8.87 2.76 2.04 2.99 1,2,3,6,7,8-HxCDF (1.72) (1.28) [1.65] (1.32) 6 7.66 [7.51] 2.9 1.92 2.6 2,3,4,6,7,8-HxCDF (1.65) (1.2) (0.933) (1.37) [2.69] 4.18 [5.16] [1.42] [0.934] [1.89] 1,2,3,7,8,9-HxCDF (2.34) (1.84) (1.23) (1.84) (1.27) 2.88 (1.23) (0.957)(0.892) (1.05) 1,2,3,4,6,7,8-HpCDF (1.68) (1.45) [4.39] 3.53 14.6 14.5 16 [4.76] [3.89] [5.23] 1,2,3,4,7,8,9-HpCDF (2.63) (2.14) (1.66) (2.18) (1.68) (2.4) [3.26] (1.23) (1.06) 3.06 OCDF (3.96) (3.9) (2.57) (2.54) 7.96 [4.78] 9.18 [4.54] 3.68 6.11
**ITEF TEQ (ND=0; EMPC=0) 0.00**  **0.09 0.0492**  **0.203 9.98**  **19.9 9.97**  **2.32 2.76**  **3.66 ITEF TEQ (ND=0; EMPC=EMPC)**  **0.00 0.09**  **0.665 3.51**  **18.0 22.7**  **19.5 4.23**  **3.86 4.14** 
**ITEF TEQ (ND=DL/2; EMPC=0) 3.12**  **2.68 2.50**  **3.06 11.6**  **20.9 11.5**  **4.02 3.89**  **4.94 ITEF TEQ (ND=DL/2; EMPC=EMPC)**  **3.12 2.68**  **2.95 4.84**  **18.4 22.7**  **19.6 5.60**  **4.55 5.34** 
**ITEF TEQ (ND=DL; EMPC=EMPC) 6.25**  **5.27 5.24**  **6.16 18.7**  **22.7 19.7**  **6.98 5.24**  **6.54**

Checkcode 843-921701-858716-174222-513868-870609-674798-971925-681363-824117-797 Lab ID MB1_8205_DF_SDSP2693_8205_001P2693_8205_002P2693_8205_003P2693_8205_004P2693_8205_005P2693_8205_006P2693_8205_007P2693_8205_008P2693_8205_009
( ) = DL [ ] = EMPC0 5 10 15 20 25 30

**pg** 

# WHO**- 2005** **- TEQ**  **Project ID: P -** **10142 P2693**  ND=0; EMPC=0 ND=0; EMPC=EMPC ND=DL/2; EMPC=0 ND=DL/2; EMPC=EMPC ND=DL; EMPC=EMPC

# P2693 - WHO-2005-TEQ **Project ID: P-10142** 

# Sample Summary **Part 1** 

# Method 23

**An alyte**  **0_8205_ MB001** **Run 1-**

**Dryer Run 2-** 

**Dryer Run 3-** 

**Dryer Run 1-** 

**Inlet Run 2-** 

**Inlet Run 3-** 

**Inlet Run 1-** 

**Outlet Run 2-** 

**Outlet Run 3-** 

**Outlet**
pg pg pg pg pg pg pg pg pg pg 2,3,7,8-TCDD (2.4) (2.04) (1.86) [2.46] [5.05] [2.75] [3.1] (1.54) (1.11) (1.41) 1,2,3,7,8-PeCDD (2.56) (1.95) (2.4) (2.78) 12.5 14.1 [8.16] (1.43) [1.32] (1.31) 1,2,3,4,7,8-HxCDD (2.67) (2.12) (1.78) (2.18) (1.9) 5.61 [4.32] (1.27) (0.84) (1.2) 1,2,3,6,7,8-HxCDD (2.7) (2.13) (1.81) (2.07) (1.77) 8.04 6.06 (1.25) (0.878) (1.17) 1,2,3,7,8,9-HxCDD (3.06) (2.21) (1.95) (2.27) (2.11) 9.73 [6.71] (1.34) [1.7] 2.76 1,2,3,4,6,7,8-HpCDD (2.78) 5.53 [9.68] 9.45 24.9 29.7 27.5 7.63 7.64 [7.66] OCDD (5.6) 34.6 49.2 [44.9] 133 151 167 82.3 63.1 44.3

2,3,7,8-TCDF (1.42) (1.36) [1.47] [1.48] 16.2 24.9 19 14.1 9.28 7.41 1,2,3,7,8-PeCDF (1.43) (1.53) (1.42) 1.46 7.34 16.6 14.6 3.85 [2.68] [3.12] 2,3,4,7,8-PeCDF (1.38) (1.41) (1.31) [1.31] [5.42] 8.94 10.5 [3.42] 2.58 4.01 1,2,3,4,7,8-HxCDF (1.69) (1.36) [1.63] (1.36) 5.97 6.64 8.87 2.76 2.04 2.99 1,2,3,6,7,8-HxCDF (1.72) (1.28) [1.65] (1.32) 6 7.66 [7.51] 2.9 1.92 2.6 2,3,4,6,7,8-HxCDF (1.65) (1.2) (0.933) (1.37) [2.69] 4.18 [5.16] [1.42] [0.934] [1.89] 1,2,3,7,8,9-HxCDF (2.34) (1.84) (1.23) (1.84) (1.27) 2.88 (1.23) (0.957)(0.892) (1.05) 1,2,3,4,6,7,8-HpCDF (1.68) (1.45) [4.39] 3.53 14.6 14.5 16 [4.76] [3.89] [5.23] 1,2,3,4,7,8,9-HpCDF (2.63) (2.14) (1.66) (2.18) (1.68) (2.4) [3.26] (1.23) (1.06) 3.06 OCDF (3.96) (3.9) (2.57) (2.54) 7.96 [4.78] 9.18 [4.54] 3.68 6.11

**WH O-2005 TEQ (ND=0; EMPC=0)**  **0.00 0.0657** **0.0148 0.174**  **16.0 24.7**  **7.46 2.19**  **2.20 2.82**  **WH O-2005 TEQ (ND=0; EMPC=EMPC)**  **0.00 0.0657**  **0.63 3.18**  **22.9 27.5**  **21.1 3.41**  **3.90 3.24** 

**WH O-2005 TEQ (ND=DL/2; EMPC=0)**  **3.61 2.99**  **2.92 3.57**  **17.4 25.7**  **9.44 4.13**  **3.66 4.42**  **WH O-2005 TEQ (ND=DL/2; EMPC=EMPC)**  **3.61 2.99**  **3.37 5.21**  **23.3 27.5**  **21.2 5.14**  **4.59 4.76** 

**WH O-2005 TEQ (ND=DL; EMPC=EMPC)**  **7.22 5.91**  **6.11 7.23**  **23.7 27.5**  **21.2 6.87**  **5.28 6.29** 

Checkcode 843-921701-858716-174222-513868-870609-674798-971925-681363-824117-797 Lab ID MB1_8205_DF_SDSP2693_8205_001P2693_8205_002P2693_8205_003P2693_8205_004P2693_8205_005P2693_8205_006P2693_8205_007P2693_8205_008P2693_8205_009
( ) = DL [ ] = EMPC0 200 400 600 800 1000 1200 1400

**pg** 

# To**tals Project ID: P** **- 10142**  **P2693** Total PCDD/Fs (ND=0; EMPC=0) Total PCDD/Fs (ND=0; EMPC=EMPC) Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC)

# P2693 - Totals **Project ID: P-10142** 

# Sample Summary **Part 2** 

# Method 23

**An alyte**  **0_8205_ MB001** **Run 1-**

**Dryer Run 2-** 

**Dryer Run 3-** 

**Dryer Run 1-** 

**Inlet Run 2-** 

**Inlet Run 3-** 

**Inlet Run 1-** 

**Outlet Run 2-** 

**Outlet Run 3-** 

**Outlet**
pg pg pg pg pg pg pg pg pg pg **Totals**

TCDDs 0 6.76 0 15.8 152 116 115 0 38.8 48 PeCDDs 0 5.91 3 10.4 158 208 136 6.86 19 8.17 HxCDDs 0 14.6 14.7 15.7 58.7 130 88.9 13.8 11.1 12.5 HpCDDs 0 5.53 0 9.45 52.5 71.2 60.7 7.63 18.4 0 OCDD 0 34.6 49.2 44.9 133 151 167 82.3 63.1 44.3

TCDFs 0 1.49 12.8 18.1 288 334 326 241 139 154 PeCDFs 0 0 0 5.83 60.6 108 138 40 11 31.6 HxCDFs 0 0 6.26 0 31.4 40.5 47.7 7.63 3.97 14 HpCDFs 0 0 0 3.53 16.9 14.5 19.1 2.04 0 5.3 OCDF 0 0 0 0 7.96 4.78 9.18 4.54 3.68 6.11

**Total PCDD/Fs (ND=0; EMPC=0) 0.00**  **68.9 85.9**  **78.8 958**  **1,170 1,110**  **401 308**  **324 Total PCDD/Fs (ND=0; EMPC=EMPC)**  **0.00 80.6**  **168 196**  **1,120 1,320**  **1,200 478**  **398 386** 
**Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC) 41.7**  **109 187**  **216 1,130**  **1,320 1,200**  **487 403**  **392**
**Total 2378s (ND=0; EMPC=0) 0.00**  **40.2 49.2**  **14.4 229**  **305 279**  **114 90.3**  **73.2 Total 2378s (ND=0.5; EMPC=0)**  **20.8 54.1**  **61.8 29.5**  **235 309**  **285 120**  **95 78.4**  **Total 2378s (ND=1; EMPC=0) 41.7**  **68.1 74.3**  **44.6 242**  **313 291**  **127 99.7**  **83.6**
**Total 2378s (ND=0; EMPC=1) 0.00**  **40.2 68.0**  **64.6 242**  **312 317**  **128 101**  **91.1 Total 2378s (ND=0.5; EMPC=1)**  **20.8 54.1**  **77.5 74.6**  **246 313**  **318 132**  **103 94.2**  **Total 2378s (ND=1; EMPC=1) 41.7**  **68.1 86.9**  **84.5 251**  **315 319**  **137 106**  **97.2**

Checkcode 843-921701-858716-174222-513868-870609-674798-971925-681363-824117-797 Lab ID MB1_8205_DF_SDSP2693_8205_001P2693_8205_002P2693_8205_003P2693_8205_004P2693_8205_005P2693_8205_006P2693_8205_007P2693_8205_008P2693_8205_009

( ) = DL [ ] = EMPC

# P2693 - Others **Project ID: P-10142** 

# Sample Summary **Part 3** 

# Method 23

**An alyte**  **0_8205_ MB001** **Run 1-**

**Dryer Run 2-** 

**Dryer Run 3-** 

**Dryer Run 1-** 

**Inlet Run 2-** 

**Inlet Run 3-** 

**Inlet Run 1-** 

**Outlet Run 2-** 

**Outlet Run 3-** 

**Outlet**
pg pg pg pg pg pg pg pg pg pg **Other PCDD/Fs (ND=0, EMPC=0)**

Other TCDD 0 6.76 0 15.8 152 116 115 0 38.8 48 Other PeCDD 0 5.91 3 10.4 145 193 136 6.86 19 8.17 Other HxCDD 0 14.6 14.7 15.7 58.7 107 82.8 13.8 11.1 9.73 Other HpCDD 0 0 0 0 27.6 41.5 33.2 0 10.8 0

Other TCDF 0 1.49 12.8 18.1 271 309 307 227 130 147 Other PeCDF 0 0 0 4.37 53.2 82.1 113 36.1 8.45 27.6 Other HxCDF 0 0 6.26 0 19.4 19.2 35.2 1.97 0 8.43 Other HpCDF 0 0 0 0 2.27 0 3.07 2.04 0 2.24
**Other PCDD/Fs (ND=0, EMPC=EMPC)**

Other TCDD 0 6.76 9.61 33.9 177 162 136 24.8 48.5 50.3 Other PeCDD 0 10.8 15.4 23.5 209 202 143 14.9 28.1 17 Other HxCDD 0 14.6 19.7 18.9 90 112 86.7 13.8 15.6 12 Other HpCDD 0 4.9 10.8 12.2 27.6 41.5 33.2 7.96 10.8 7.31

Other TCDF 0 3.41 33.8 31.7 284 361 308 236 166 156 Other PeCDF 0 0 2.22 9.43 66 101 120 41.1 22.7 37.1 Other HxCDF 0 0 9 1.81 19.4 27.9 41.5 8.36 4.72 11 Other HpCDF 0 0 0 0 4.46 2 5.4 3.37 0.845 4.35

Checkcode 843-921701-858716-174222-513868-870609-674798-971925-681363-824117-797 Lab ID MB1_8205_DF_SDSP2693_8205_001P2693_8205_002P2693_8205_003P2693_8205_004P2693_8205_005P2693_8205_006P2693_8205_007P2693_8205_008P2693_8205_009

( ) = DL [ ] = EMPC

### P2693 - TEQ overview **Project ID: P-10142**



### TEQ Summary **Part 4**

( ) = DL [ ] = EMPCMethod Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F = fail) 0 10 20 30 40 50 60 70 80 90 100

**% Rec.**  

### Mean Recoveries of Extraction Standards (N=10) **Project ID: P -** **10142 P2693**  Mean Std. Dev.Method Specification Limits: Tetra-Octa SS: 70-130% (F = fail) 0 20 40 60 80 100 120

**% Rec.**  

### Mean Recoveries of Sampling Standards (N=10) **Project ID: P -** **10142 P2693**  Mean Std. Dev.0_8205_MB001 83.1 79.8 88.5 85.5 86.4 89.2 85.5 88.5 87.2 84.2 89.9

Run 1-Dryer 88.3 85.2 95.4 93.4 93.9 97.1 95.4 92.1 89.8 87 97.9 Run 2-Dryer 89.9 86.2 101 95 97 99.9 95.9 91.1 86.9 86.7 102 Run 3-Dryer 89.4 80.2 90 87.1 86.7 90.4 89.9 89.1 87.6 86.8 92.5 Run 1-Inlet 80 77.1 94.1 88.1 88.7 96.8 92.2 80.5 81.9 81.1 93.9 Run 2-Inlet 80.4 78.5 86.2 79.7 81.2 86.1 84.1 82.1 81.6 79.6 85.8 Run 3-Inlet 91.2 88.1 99.3 93.2 93.6 97.2 90.5 91.1 89 86.9 100 Run 1-Outlet 84.9 83.2 93.2 90 89.4 96.2 90.2 86.9 85 84.9 93 Run 2-Outlet 85.5 86.9 102 94.4 97 98.7 94 87.6 90.2 90.4 99.5 Run 3-Outlet 83.5 81.8 97.9 90.1 92.5 98.4 92.8 83.7 87.6 86.5 96.2

Average 86 83 95 90 91 95 91 87 87 85 95 SD 4 4 5 5 5 5 4 4 3 3 5 Min 80 77.1 86.2 79.7 81.2 86.1 84.1 80.5 81.6 79.6 85.8 Max 91.2 88.1 102 95 97 99.9 95.9 92.1 90.2 90.4 102 Within M23 QC TRUETRUETRUETRUETRUETRUETRUETRUETRUETRUETRUE 13CHxCDD 13CHxCDD 13CHpCDD Sample Number 13CTCDD 13CPeCDD 13CHxCDD Extraction Standard Percent Recoveries, % 13CPeCDF 13CPeCDF 13COCDD 13CTCDF 13CHxCDF91.4 89.9 87.8 91.5 85.8 81.9 0_8205_MB001 98.2 101 98 101 95.9

98 99.9 92.8 96.2 93.5 91.7 Run 1-Dryer 104 102 99.2 101 101 100 100 98.7 100 98.7 93.6 Run 2-Dryer 100 101 101 102 100 92.5 94.4 86.1 91.8 87 86.7 Run 3-Dryer 100 102 99.2 100 98.5 94.6 92.3 90.8 92.8 91.2 89.9 Run 1-Inlet 103 101 99.1 101 104 85.5 84.6 83 84.6 82.6 79.2 Run 2-Inlet 102 97.7 98 101 100 98.4 95.4 95.1 96 93.9 90.5 Run 3-Inlet 100 97.3 102 104 101 93.2 92.8 91.5 92.7 87.6 87.1 Run 1-Outlet 107 100 102 104 105 98.8 102 97.7 96.9 99 92.5 Run 2-Outlet 101 100 96.6 100 102 96.8 98.3 90.7 94.8 93 92 Run 3-Outlet 102 101 100 101 103

95 95 91 94 91 89 Average 102 100 100 102 101 4 5 5 4 5 5 SD 3 2 2 1 3 85.5 84.6 83 84.6 82.6 79.2 Min 98.2 97.3 96.6 100 95.9 100 102 98.7 100 99 93.6 Max 107 102 102 104 105 TRUETRUETRUETRUETRUETRUE Min within M23 QC TRUETRUETRUETRUETRUE 13CHpCDF 13COCDF 13CHxCDF 13CHxCDF 13CHxCDF 13CHpCDF Sample Number CS/SS Percent Recoveries, % 37ClTCDD 13CPeCDD 13CHxCDF 13CHpCDF 13CPeCDFP2693 Page 1 of 5P2693 Page 2 of 5P2693 Page 3 of 5P2693 Page 4 of 5P2693 Page 5 of 5

# P2693 - DLs **Project ID: P-10142** 

# Sample Summary **Part 5 (DLs)** 

# Method 23

**An alyte**  **0_8205_ MB001** **Run 1-**

**Dryer Run 2-** 

**Dryer Run 3-** 

**Dryer Run 1-** 

**Inlet Run 2-** 

**Inlet Run 3-** 

**Inlet Run 1-** 

**Outlet Run 2-** 

**Outlet Run 3-** 

**Outlet**
pg pg pg pg pg pg pg pg pg pg 2,3,7,8-TCDD 2.4 2.04 1.86 2.18 1.63 1.99 1.53 1.54 1.11 1.41 1,2,3,7,8-PeCDD 2.56 1.95 2.4 2.78 2.11 2.68 1.71 1.43 1.35 1.31 1,2,3,4,7,8-HxCDD 2.67 2.12 1.78 2.18 1.9 1.94 1.86 1.27 0.84 1.2 1,2,3,6,7,8-HxCDD 2.7 2.13 1.81 2.07 1.77 2.06 1.86 1.25 0.878 1.17 1,2,3,7,8,9-HxCDD 3.06 2.21 1.95 2.27 2.11 2.2 2.13 1.34 0.923 1.28 1,2,3,4,6,7,8-HpCDD 2.78 2.41 2.03 2.65 1.98 2.48 2.35 1.53 1.35 1.42 OCDD 5.6 4.96 3.36 5.35 3.61 4.25 4.01 2.78 1.87 2.39
2,3,7,8-TCDF 1.42 1.36 1.08 1.24 1.13 1.53 1.19 1.21 0.93 0.831 1,2,3,7,8-PeCDF 1.43 1.53 1.42 1.54 1.61 1.91 1.29 1.2 0.855 1.03 2,3,4,7,8-PeCDF 1.38 1.41 1.31 1.5 1.42 1.88 1.25 1.13 0.765 0.971 1,2,3,4,7,8-HxCDF 1.69 1.36 0.89 1.36 0.946 1.37 0.829 0.748 0.683 0.751 1,2,3,6,7,8-HxCDF 1.72 1.28 0.948 1.32 0.896 1.34 0.859 0.72 0.682 0.787 2,3,4,6,7,8-HxCDF 1.65 1.2 0.933 1.37 0.9 1.42 0.867 0.767 0.677 0.787 1,2,3,7,8,9-HxCDF 2.34 1.84 1.23 1.84 1.27 1.7 1.23 0.957 0.892 1.05 1,2,3,4,6,7,8-HpCDF 1.68 1.45 1.23 1.44 1.09 1.62 1.21 0.823 0.77 1.02 1,2,3,4,7,8,9-HpCDF 2.63 2.14 1.66 2.18 1.68 2.4 1.79 1.23 1.06 1.6 OCDF 3.96 3.9 2.57 2.54 2.74 3.43 3.08 1.74 1.51 1.45

Total TCDD 2.4 2.04 1.86 2.18 1.63 1.99 1.53 1.54 1.11 1.41 Total PeCDD 2.56 1.95 2.4 2.78 2.11 2.68 1.71 1.43 1.35 1.31 Total HxCDD 2.8 2.15 1.84 2.16 1.92 2.06 1.94 1.28 0.878 1.21 Total HpCDD 2.78 2.41 2.03 2.65 1.98 2.48 2.35 1.53 1.35 1.42

Total TCDF 1.42 1.36 1.08 1.24 1.13 1.53 1.19 1.21 0.93 0.831 Total PeCDF 1.41 1.47 1.37 1.52 1.51 1.89 1.27 1.16 0.809 0.998 Total HxCDF 1.83 1.4 0.992 1.45 0.991 1.45 0.933 0.791 0.727 0.832 Total HpCDF 2.08 1.75 1.42 1.76 1.35 1.96 1.46 0.998 0.899 1.28
Checkcode 843-921701-858716-174222-513868-870609-674798-971925-681363-824117-797 Lab ID MB1_8205_DF_SDSP2693_8205_001P2693_8205_002P2693_8205_003P2693_8205_004P2693_8205_005P2693_8205_006P2693_8205_007P2693_8205_008P2693_8205_009