### SUMMARY OF CATALYTIC REFORMING UNITS

Hydrogen Sulfide Carbonyl Sulfide Carbon Monoxide 2.40E-02 75-07-0 Acetaldehyde BDL3.43E-05 BDL 7.88E-05 1.09E-01 DLL 9.45E-07 BDL 2.10E-04 50-00-0 Formaldehyde DLL 7.25E-04 0.003 3.00E-03 DLL 3.26E-06 2.10E-04 74-90-8 Hydrogen cyanide BDL 1.83E-05 BDL 4.04E-03 BDL4.77E-04 BDL 4.00E-04 2.97E-05 BDL9.26E-04 DDL 1.75E-04 BDL 6.55E-04BDL6.54E-04 BDL 2.80E-04

Propanal BDL 3.00E-04 7.00E-04 7647-01-0 Hydrogen Chloride 4.55E-02 BDL 1.10E-02 1.03E-03 BDL 5.00E-05 6.91E-05 0.021 4.40E-03 DLL 1.05E-04BDL 1.51E-04 1.40E-04 7782-41-4 Hydrogen Fluoride 1.22E-06 BDL 1.13E-02 BDL1.52E-04 BDL 1.00E-04 BDL2.86E-07 BDL 7.98E-04 BDL 1.00E-04 BDL 2.85E-05DDL2.11E-04 2.00E-05

Chlorine DLL 3.04E-04 BDL 5.15E-03 BDL1.47E-04 BDL 5.00E-04 BDL1.55E-06 0.106 BDL 4.00E-04 DLL 4.88E-05BDL9.07E-04 1.10E-04 Propionadehyde BDL4.43E-05 BDL 1.08E-04 BDL 1.99E-07

67-64-1 Acetone DLL 1.32E-03 BDL 1.28E-01 BDL5.61E-03 BDL 1.63E-03 BDL4.31E-04 BDL 1.26E-02 BDL3.89E-02 DLL 2.12E-04 DLL 4.00E-05 2.78E-03 6.67E-03BDL 1.30E-03 BDL 3.25E-06 750-05-8 Acetonitrile BDL 5.71E-04 BDL 5.55E-02 BDL1.08E-02 BDL 1.88E-04 BDL2.62E-04 8.00E-02 BDL5.39E-03 BDL 5.97E-04 BDL 4.51E-03BDL3.00E-04 BDL 2.92E-05 107-02-8 Acrolein BDL 8.73E-04 BDL 1.07E-01 BDL4.52E-03 BDL 1.19E-03 BDL3.79E-04 BDL 1.60E-02 BDL5.15E-02 8.00E-05 BDL 1.90E-05 BDL 1.27E-03 BDL 1.07E-02BDL 1.30E-03 BDL 4.76E-06 107-13-1 Acrylonitrile BDL 4.07E-04 BDL 5.55E-02 BDL3.90E-03 BDL 1.11E-04 BDL1.91E-04 BDL 1.07E-02 BDL5.33E-03 BDL 5.41E-05 BDL 4.12E-04BDL3.20E-04 BDL 2.92E-05 71-43-2 Benzene 8.61E-03 BDL 1.20E-01 5.09E+00 1.93E-02 5.04E-04 2.11E+01 1.04E-01 3.21E-02 1.54E-03 1.37E-05 DLL 2.38E-03BDL 1.50E-03 BDL 5.05E-06

Bromomethane BDL 2.70E-05 BDL 6.00E-06 Bromoform BDL 7.90E-05 BDL 1.80E-05 Bromodichloromethane BDL 5.10E-05 BDL 1.10E-05 106-99-0 1,3-Butadiene BDL 6.11E-04 BDL 9.16E-02 BDL3.63E-03 BDL 9.34E-04 BDL2.53E-04 BDL9.65E-03 BDL2.85E-02 BDL 4.20E-05 BDL 1.00E-05 BDL 1.52E-05 DLL 1.16E-04BDL8.00E-04 BDL 4.70E-06 75-15-0 Carbon Disulfide 1.46E-03 BDL 2.08E-02 BDL5.31E-04 BDL 6.13E-04 2.10E-04 BDL 1.75E-03 0.04 DLL 1.64E-04 DLL 3.40E-05 9.48E-06 DLL 6.57E-05BDL3.70E-04 BDL 1.56E-06

Carbon Tetrachloride BDL 9.10E-05 DLL 5.20E-05 108-90-7 Chlorobenzene 1.04E-04 BDL 1.13E-02 DDL5.33E-04 BDL 2.13E-05 BDL4.10E-05 4.00E-02 BDL8.86E-04 DLL 3.70E-05 1.59E-04 BDL 1.03E-05 BDL 7.82E-05BDL5.50E-05 BDL 1.01E-05

Chloroform DDL 7.09E-05 1.96E-04 Chlororethane DDL 4.10E-05 DLL 7.00E-06 Cloromethane DDL 7.55E-05 3.10E-05 BDL2.00E-03 98-82-8 Cumene (Isopropylbenzene) 1.55E-04 BDL 8.31E-03 1.40E-03 BDL 2.28E-05 DLL3.53E-05 1.70E-01 1.63E-02 BDL 2.28E-05 DLL 1.73E-04BDL4.10E-05 BDL 1.18E-05

Cyclohexane DDL 7.48E-04 8.78E-04 1,3-Dichlorobenzene BDL 9.10E-05 5.20E-05 1,4-Dichlorobenzene BDL 9.10E-05 4.20E-05 1,2-Dichlorobenzene BDL 9.10E-05 DLL 2.30E-05 106-93-4 1,2-Dibromoethane BDL 2.03E-03 BDL 2.90E-01 BDL1.10E-02 BDL 3.52E-03 BDL8.78E-04 3.16E+00 BDL 1.32E-01 BDL 3.10E-05 BDL 7.00E-06 BDL 9.15E-06 BDL 8.24E-05BDL6.00E-03 BDL 1.15E-05

1,1-Dichloroethane BDL 7.00E-06 Dichlorodifluoromethane BDL 3.80E-05 BDL 8.00E-06 Dibromochloromethane BDL 6.48E-05 BDL 1.50E-05 1,2-dichlorotetrafluoroethane BDL 4.50E-05 BDL 1.00E-05 1,1-Dichloroethylene BDL 3.90E-05 DLL 1.60E-05 cis-1,2-Dichloroethylene BDL 2.90E-05 DLL 1.30E-05 trans-1,2-Dichloroethylene BDL 3.00E-05 DLL 8.00E-06 cis-1,3-Dichloropropene BDL 3.10E-05 BDL 7.00E-06 trans-1,3-dichloropropene BDL 2.90E-05 BDL 7.00E-06 1,2-Dichloropropane BDL 3.84E-04 BDL 1.50E-05 1,4-Dioxane BDL 2.74E-04 BDL 6.10E-05 100-41-4 Ethylbenzene 7.69E-03 BDL 8.52E-03 4.30E-02 DDL2.70E-04 4.04E-04 4.24E+00 0.18 2.27E-02 1.79E-03 BDL 3.19E-05 DLL 5.48E-04DDL3.90E-04 BDL 3.20E-04

Ethylene Dibromide BDL 5.00E-05 BDL 1.10E-05 Ethyl Acetate BDL 3.01E-04 BDL 6.70E-05 4 Ethyltoluene 5.83E-03 6.47E-04 Ethanol DDL 1.73E-04 DLL 1.85E-04 Heptane 6.22E-03 2.51E-03 110-54-3 Hexane BDL 8.39E-04 DLL 1.46E-01 BDL5.21E-03 BDL 9.98E-03 BDL5.99E-04 3.31E+00 DLL 5.99E-03 5.48E-03 9.38E-04 3.07E-05 BDL 1.63E-04BDL 1.10E-03 BDL 3.70E-06

Hexachlorobutadiene BDL 1.22E-03 BDL 2.72E-04 Isooctane BDL 5.27E-05 BDL 6.75E-03 BDL2.52E-05 BDL 1.94E-05 Methyl Ethyl Ketone BDL 3.36E-04 BDL 7.50E-05 108-10-1 Methyl iso-Butyl Ketone BDL 6.41E-05 BDL 8.26E-03 DDL3.23E-04 BDL 1.67E-05 BDL3.07E-05 3.80E-01 6.08E-03 BDL 4.98E-04 BDL 1.12E-04 BDL 2.28E-05 BDL 1.73E-04BDL3.10E-04 BDL 8.55E-06

Methyl Butyl Ketone BDL 7.00E-05 1634-04-4 Methyl t-Butyl Ether (MTBE) BDL 6.78E-05 BDL 8.16E-03 BDL2.47E-04 BDL 3.75E-05 BDL3.07E-05 BDL 1.08E-02 BDL5.38E-03 BDL 2.70E-05 BDL 6.00E-06 BDL 4.74E-06 BDL 3.67E-05BDL3.70E-04 BDL 8.08E-06 75-09-2 Methylene Chloride BDL 4.42E-03 BDL 6.17E-01 BDL5.21E-03 BDL 6.31E-03 BDL2.58E-03 1.95E-01 2.45E-01 DLL 2.01E-04 DLL 9.20E-05 DLL 1.26E-04 BDL 5.69E-04 BDL 1.00E-05 98-95-3 Nitrobenzene 2.33E-03 DLL 1.28E-02 3.47E-03 BDL 8.25E-05 2.10E-04 2.00E-01 6.40E-02 DLL 2.67E-04 BDL 3.20E-05 BDL 1.71E-06 BDL 1.20E-04 BDL 3.57E-05 79-46-9 2-Nitropropane DLL 2.37E-04 BDL 7.41E-02 3.67E-04 3.39E-04 1.01E-04 2.00E-01 BDL6.12E-03 BDL 1.00E-03 BDL 0.0041BDL3.10E-04 BDL 1.87E-05 109-66-0 Pentane BDL 7.78E-04 DLL 1.38E-01 BDL4.22E-03 BDL 1.14E-02 BDL3.37E-04 1.15E+00 BDL2.61E-02 BDL 7.66E-05 BDL 0.0006BDL 1.00E-03 BDL 7.23E-06

2-Propanol BDL 2.80E-04 DLL 6.30E-05 100-42-5 Styrene BDL 7.08E-05 BDL 8.86E-03 DDL1.78E-03 BDL 1.70E-05 6.35E-05 BDL2.35E-03 BDL 7.28E-04 DLL 3.67E-04 DLL 9.00E-06 BDL 1.74E-05 BDL 1.32E-04BDL4.50E-05 1.08E-04 127-18-4 Tetrachloroethene BDL 2.02E-03 BDL 2.90E-01 DDL2.79E-02 BDL 1.71E-02 BDL8.77E-04 BDL3.66E-02 BDL 1.04E-01 DLL 3.00E-05 BDL 1.57E-04BDL5.10E-03 BDL 2.09E-05

Tetrachloroethylene DDL 2.03E-04 DLL 3.42E-04 1,1,2,2-Tetrachloroethane BDL 5.20E-05 BDL 1.20E-05 Tetrahydrofuran BDL 4.50E-05 DLL 5.30E-05 108-88-3 Toluene 6.94E-02 BDL 1.38E-01 3.69E+00 5.26E-02 5.70E-03 2.83E+01 0.23 8.57E-02 4.32E-03 1.53E-04 3.88E-03BDL4.70E-03 BDL 1.06E-05

1,2,4-Trichlorobenzene BDL 5.64E-04 DLL 1.33E-04 Trichloroethene BDL 2.28E-03 BDL 2.90E-01 BDL1.18E-02 BDL 2.99E-03 BDL9.96E-04 BDL4.12E-02 BDL 1.33E-01 BDL 1.31E-05 BDL 9.90E-05 BDL 5.21E-06 Trichloroethylene DDL 9.60E-05 DLL 1.72E-04 1,1,1-Trichloroethane BDL 6.20E-05 BDL 1.40E-05 BDL2.80E-03 1,1,2-Trichloroethane BDL 3.10E-05 BDL 7.00E-06 Trichlorofluoromethane BDL 4.30E-05 BDL 1.00E-05 Trichlorotrifluoroethane BDL 4.40E-05 BDL 1.00E-05 1,3,5-Trimethylbenzene 7.26E-03 8.94E-04 1,2,4-Trimethylbenzene 1.97E-02 2.54E-03 540-84-1 2,2,4-Trimethylpentane BDL2.23E-04 BDL 3.64E-05 3.00E-02 BDL5.54E-04 BDL 3.60E-05 BDL 8.00E-06 BDL 2.72E-04 BDL 2.06E-03BDL3.00E-05

Vinyl Acetate BDL 6.40E-05 BDL 6.00E-06 Vinyl Bromide BDL 3.30E-05 BDL 7.00E-06 Vinyl Chloride DDL 1.80E-05 DLL 4.00E-06 1330-20-7 Xylene 1.86E-03 4.23E+01 1.36E+00 1.05E-01 7.10E-03 DLL 1.42E-04 DLL 3.19E-03 4.00E-03

o-Xylene 4.52E-02 BDL 8.61E-03 8.90E-02 5.01E-04 1.06E-03 2.81E-02 1.88E-03 6.45E-04 m&p-Xylenes 1.36E-03 6.78E-02 5.20E-03 9.39E-04 p-Xylene 4.07E-02 BDL 8.36E-03 2.56E-01 1.94E-03

83-32-9 Acenaphthene 7.93E-03 4.96E-05 6.00E-07 1.33E-07 BDL 1.79E-07 209-96-8 Acenaphthylene BDL 1.33E-04 1.69E-05 BDL 3.00E-07 3.82E-08 BDL 3.03E-07 62-53-3 Aniline BDL 1.22E-04 BDL2.52E-04 BDL 3.00E-06 BDL 1.71E-06 BDL 7.48E-07 120-12-7 Anthracene DLL 2.33E-02 3.85E-04 BDL 2.00E-07 1.56E-06 BDL 1.20E-06 92-87-5 Benzidine BDL4.01E-03 BDL8.26E-03 BDL 1.21E-05 BDL 1.71E-05 BDL 1.87E-06

Benzyl Chloride BDL 1.97E-04 BDL 4.40E-05 56-55-3 Benzo(a)Anthracene 1.04E-02 5.27E-06 BDL 2.00E-07 4.13E-08 BDL 1.56E-08 205-99-2 Benzo(b)Fluoranthene 3.87E-02 1.20E-05 BDL 2.00E-07 1.13E-07 BDL 2.43E-08 207-08-9 Benzo(k)Fluoranthene 2.97E-03 BDL3.62E-06 BDL 3.00E-07 BDL 6.15E-08 BDL 5.61E-09 191-24-2 Benzo(ghi)Perylene 5.16E-03 3.75E-06 BDL 2.00E-07 3.93E-08 BDL 2.47E-08 **TX3A1190 - Delek Refining Tyler, TX (Coke Burn Vent)** 

**DL lb/hr** 

**VOLATILE ORGANIC HAP**

**SVOC CAS #**  **Compound DL**  **WA 5A1420 Tesoro Anacortes,** 
**WA (Oxychlorination Cycle)** 

**DL LA3C0590 ExxonMobil Baton**  **Rouge, LA (Purge Vent)**

**lb/hr TX3B1260 - Shell Oil Deer**  **Park, TX (Coke Burn Vent)**

**DL IL2A0430 ConocoPhillips WRB**  **Refining LP Roxana, IL (Coke**

**Burn Vent)**

**DL LA3C0610 Marathon Petroleum**  **Garyville, LA**

**(Coke Burn Vent)**

**DL lb/hr**  **TX3B1131 - CITGO Corpus Christi, TX (Coke Burn Vent)** 

**lb/hr Detection**  **Limit (DL) KS2C0480 Frontier El Dorado, KS**  **(Coke Burn Vent)**

**lb/hr KS2C0480 Frontier El Dorado, KS**  **(Purge Cycle Vent) WA**  **5A1420 Tesoro Anacortes,**
**WA (Coke Burn Vent)** 

**lb/hr TX3B1220 Motiva Port** 
**Ar thur, TX (Coke Burn**  **Vent)**

**DL lb/hr**  **lb/hr lb/hr**  **lb/hr lb/hr**  **DL lb/hr**  **DL DL** **lb/hr PA1A1020 Sunoco Marcus**  **Hook, PA**

**(Coke Burn Vent)**

**DL DL**  **LA3C0590 ExxonMobil Baton Rouge, LA (Coke Burn Vent)** 

### SUMMARY OF CATALYTIC REFORMING UNITS

**TX3A1190 - Delek Refining Tyler, TX (Coke Burn Vent)** 

**DL lb/hr**  **CAS # Compound**  **DL WA**  **5A1420 Tesoro Anacortes,**
**WA (Oxychlorination Cycle)** 

**DL LA3C0590 ExxonMobil Baton**  **Rouge, LA (Purge Vent)**

**lb/hr TX3B1260 - Shell Oil Deer**  **Park, TX (Coke Burn Vent)**

**DL IL2A0430 ConocoPhillips WRB**  **Refining LP Roxana, IL (Coke**

**Burn Vent)**

**DL LA3C0610 Marathon Petroleum**  **Garyville, LA**

**(Coke Burn Vent)**

**DL lb/hr**  **TX3B1131 - CITGO Corpus Christi, TX (Coke Burn Vent)** 

**lb/hr Detection**  **Limit (DL) KS2C0480 Frontier El Dorado, KS**  **(Coke Burn Vent)**

**lb/hr KS2C0480 Frontier El Dorado, KS**  **(Purge Cycle Vent) WA**  **5A1420 Tesoro Anacortes,**
**WA (Coke Burn Vent)** 

**lb/hr TX3B1220 Motiva Port** 
**Ar thur, TX (Coke Burn**  **Vent)**

**DL lb/hr**  **lb/hr lb/hr**  **lb/hr lb/hr**  **DL lb/hr**  **DL DL** **lb/hr PA1A1020 Sunoco Marcus**  **Hook, PA**

**(Coke Burn Vent)**

**DL DL**  **LA3C0590 ExxonMobil Baton Rouge, LA (Coke Burn Vent)** 

50-32-8 Benzo(a)Pyrene 4.52E-03 BDL3.62E-06 BDL 3.00E-07 2.45E-08 BDL 5.61E-09 192-97-2 Benzo(e)Pyrene 1.13E-02 4.81E-06 9.14E-08 BDL 2.81E-08 92-52-4 Biphenyl 1.52E-01 2.03E-03 DLL 1.60E-06 DLL 9.03E-07 3.34E-06 1319-77-3 Cresols BDL2.23E-04 4.60E-04 BDL 1.71E-06 218-01-9 Chrysene* 8.98E-03 4.69E-06 BDL 2.00E-07 8.44E-08 8.41E-08 53-70-3 Dibenzo(a,h)Anthracene* BDL 7.49E-05 BDL 7.25E-06 BDL 2.00E-07 DLL 2.09E-08 BDL 1.24E-08 132-64-9 Dibenzofuran BDL 1.21E-04 BDL2.49E-04 BDL 3.00E-06 BDL 1.71E-06 BDL 7.48E-07 192-65-4 Dibenzo(a,e)pyrene BDL 1.71E-06 BDL 2.81E-08 119-90-4 3,3'-Dimethoxybenzidine BDL8.79E-04 BDL 1.81E-03 BDL 1.71E-05 60-11-7 Dimethylaminobenzene BDL8.79E-04 BDL 1.81E-03 BDL 1.71E-06 57-97-6 7,12-Dimethybenz(a)anthracene BDL0.00E+00 BDL 7.25E-06 BDL 1.71E-06 BDL 2.81E-08 119-93-7 3,3'-Dimethylbenzidine BDL0.00E+00 BDL3.91E-03 BDL 6.00E-04 122-09-8 a,a-Dimethylphenethylamine BDL0.00E+00 BDL 1.81E-03 BDL 4.28E-06 105-67-9 2,4-Dimethylphenol BDL0.00E+00 BDL2.64E-04 BDL 1.20E-06 BDL 1.71E-06 BDL 1.87E-07 206-44-0 Fluoranthene 1.17E-01 8.84E-05 BDL 2.00E-07 4.50E-07 1.90E-06 86-73-7 Fluorene 2.07E-01 2.29E-03 2.00E-06 6.96E-06 4.47E-06 193-39-5 Indeno(1,2,3-cd)Pyrene 5.28E-03 BDL3.62E-06 BDL 3.00E-07 3.17E-08 BDL 1.78E-08 78-59-1 Isophorone BDL0.00E+00 BDL2.71E-04 BDL 2.40E-06 BDL 1.71E-06 BDL 3.74E-07 56-49-5 3-Methylcholanthrene BDL0.00E+00 BDL 1.81E-05 BDL 1.71E-06 BDL 2.81E-08 91-57-6 2-Methylnaphthalene 6.67E-01 2.18E-03 6.98E-05 1.87E-04 1.81E-05 91-20-3 Naphthalene 9.57E-01 2.79E-03 1.59E-04 7.47E-06 4.03E-05 198-55-0 Perylene BDL0.00E+00 BDL3.62E-06 DLL 3.33E-09 2.81E-08 85-01-8 Phenanthrene 2.08E-01 4.74E-03 2.30E-06 2.52E-06 7.70E-06 108-95-2 Phenol BDL0.00E+00 BDL2.36E-04 BDL 9.00E-07 BDL 1.71E-06 BDL 1.50E-07 106-50-3 1,4-Phenylenediamine BDL0.00E+00 BDL 1.81E-03 BDL 1.71E-05

Propene DDL 4.11E-04 BDL 3.73E-04 129-00-0 Pyrene 4.80E-02 3.83E-05 BDL 3.00E-07 1.60E-07 2.86E-07 95-53-4 o-Toluidine BDL0.00E+00 BDL3.62E-04 BDL 1.71E-06

7400-36-0 Antimony DDL 1.54E-05 BDL 3.88E-07 2.09E-08 DLL 6.95E-05 BDL 3.10E-07 DLL 7.59E-06BDL2.84E-07 BDL 2.53E-07 7440-38-2 Arsenic 1.10E-04 BDL 3.07E-07 5.69E-08 2.16E-04 DLL 3.70E-07 DLL 1.42E-04BDL2.84E-07 BDL 2.53E-07

Barium BDL 5.54E-06 7440-41-7 Beryllium BDL 1.26E-05 BDL 4.36E-07 3.60E-08 BDL 1.64E-06 BDL 8.00E-08 DLL 2.08E-07BDL 7.10E-08 BDL 5.05E-08 7440-43-9 Cadmium 4.28E-05 2.06E-07 2.87E-08 DLL 1.13E-05 DLL 8.00E-08 DLL 4.88E-07BDL 7.10E-08 BDL 1.98E-07 7440-47-3 Chromium 1.77E-04 7.18E-07 7.65E-07 3.52E-05 2.90E-06 1.21E-06 7.84E-07 BDL 2.04E-07

Copper BDL 4.80E-06 7439-92-1 Lead 1.79E-04 1.40E-06 4.21E-07 3.74E-04 DLL 1.74E-06 DLL 2.53E-06 4.83E-07 BDL 4.40E-07 7439-96-5 Manganese 3.79E-03 3.81E-05 2.10E-06 2.43E-04 1.90E-05 9.09E-06 1.11E-05 BDL 1.45E-06 7440-02-0 Nickel 2.25E-04 1.50E-06 1.73E-06 3.64E-05 1.96E-06 3.05E-06 1.33E-06 BDL 7.38E-07 7782-22-4 Selenium DDL 9.29E-05 BDL 1.45E-06 1.51E-07 1.15E-04 BDL 7.90E-07 DLL 1.10E-06BDL 7.10E-07 BDL 5.05E-07

Silver BDL 1.25E-07 Thallium BDL 7.78E-07 7440-48-4 Cobalt 2.66E-05 BDL 3.68E-07 4.27E-08 BDL3.78E-05 BDL 1.70E-07 BDL 4.46E-07DDL8.96E-08 BDL 1.00E-07 7439-97-6 Oxidized/Organic Mercury DLL 2.88E-08 1.33E-05 BDL3.43E-07 1.88E-08 BDL1.44E-08 1.94E-04 DLL 3.88E-08 BDL 1.30E-06

Total Mercury DDL3.54E-08 1.61E-05 DLL 1.78E-07 1.30E-06 BDL 2.30E-06 7439-97-6 Elemental Mercury BDL 2.21E-07 BDL 7.93E-06 DLL 1.00E-06 DDL 1.45E-08 BDL3.27E-08 1.17E-02 DLL 1.36E-07 BDL 1.00E-06

Phorphorus BDL 2.93E-05 18540-29-9 Hexavalent Chromium

Zinc 1.04E-05

7664-41-7 Ammonia BDL 0.000074 630-08-0 Carbon Monoxide 2.75E+00 0.029 0.15 7782-50-5 Chlorine DLL 3.04E-04 BDL 5.15E-03 BDL 5.00E-04 BDL1.55E-06 0.106 BDL 4.00E-04 DLL 4.88E-05BDL9.07E-04 1.10E-04 67-56-1 Methanol DLL 3.01E-04 DDL 2.09E-02 BDL8.50E-04 BDL 2.30E-05 1.07E-04 DLL 2.85E-02 DLL 1.05E-03 DLL 2.00E-03 BDL 4.33E-04 BDL 1.90E-04 74-82-8 Methane 1.16E+01 DLL 8.94E-03 DDL 2.00E-03 DLL 7.25E-05 7.00E-04

Nonmethane Hydrocarbons 6.00E-03 74-84-0 Ethane 1.12E+01 BDL4.02E-03 BDL 3.00E-03 DLL 2.07E-05 1.30E-03 75-69-4 Trichlorofluoromethane BDL 4.30E-05 74-83-9 Bromomethane 10102-43-9 Nitric Oxide 7.05E-04 2.23E+01 1.00E-04 9.66E-04 BDL2.17E-03 1.60E-04 1.30E-03 4.40E-03

Sulfur Dioxide BDL 7.21E-05 DDL 9.27E-02 BDL 5.00E-04 BDL1.17E-05 4.38 2.20E-02 DLL 7.15E-04 6.00E-03 2.80E-03 Total Hydrocarbons BDL 3.26E-03

Condensible Particulate 4.60E-01 1.00E-03 0.151 1.58E-03 9.00E-03 2.00E-04 Filterable Particulate 3.40E-01 3.00E-03 4.02E-04 0.022 1.00E-03 DLL 1.00E-04 Filterable PM2.5 Total PM2.5 Total PM 8.00E-01 4.00E-03 DLL6.71E-04 5.71E-03 3.60E-03 4.00E-02 6.00E-04

NONE 1336-36-3 Total PCBs BDL 2.54E-13 BDL 9.29E-12 7.55E-11 2.35E-10

PCBs TEQ 1.82E-12

39635-31-9 2,3,3',4,4',5,5'-HpCB (PCB189) 1.43E-14 DDL 3.78E-13 BDL1.86667E-11 BDL 2.64E-14 1.59E-13 BDL 1.73E-12BDL 7.29E-12 38380-08-4 2,3,3',4,4',5'-HxCB (PCB156) 2.64E-14 BDL 7.21E-13 8.30667E-11 included with PCB157 1.96E-12 DLL 3.62E-12 6.86E-11 69782-90-7 2,3,3',4,4',5'-HxCB (PCB157) 2.64E-14 BDL 7.21E-13 8.30667E-11 DLL 2.30E-13 1.96E-12 DLL 1.41E-12 6.86E-11 32598-14-4 2,3,3',4,4'-PeCB (PCB105) 1.56E-14 1.50E-12 2.09E-10 5.95E-13 5.96E-12 2.74E-11 1.36E-10 52663-72-6 2,3',4,4',5,5'-HxCB (PCB167) DLL 5.67E-15 BDL 4.44E-13 BDL2.3E-11 DLL 1.78E-13 1.43E-12 DLL 1.91E-12DDL2.90E-11 74472-37-0 2,3,4,4',5-PeCB (PCB114) 5.54E-15 BDL 3.18E-13 BDL1.93333E-11 BDL 8.43E-14 2.69E-12 DLL 2.52E-12DDL 1.13E-11 31508-00-6 2,3',4,4',5-PeCB (PCB118) 2.35E-14 3.18E-12 5.74667E-10 1.84E-12 9.14E-12 6.22E-11 4.15E-10 65510-44-3 2',3,4,4',5-PeCB (PCB123) DLL 5.46E-15 BDL 3.43E-13 BDL2.23333E-11 BDL 6.01E-14 8.28E-12 DLL 2.04E-12DDL5.10E-12 32774-16-6 3,3',4,4',5,5'-HxCB (PCB169) 2.82E-14 BDL 4.51E-13 BDL2.03333E-11 BDL 1.13E-14 2.57E-13 BDL 1.11E-12BDL 1.25E-12 57465-28-8 3,3',4,4',5-PeCB (PCB126) 4.68E-14 BDL 3.56E-13 BDL2.16667E-11 DLL 1.11E-13 6.12E-12 3.68E-12BDL 1.82E-12 32598-13-3 3,3',4,4'-TCB (PCB77) 2.90E-14 BDL 4.37E-13 DLL 5.83667E-11 BDL 6.86E-13 2.08E-11 1.57E-11 4.38E-11 70362-50-4 3,4,4',5-TCB (PCB81) 2.67E-14 BDL 4.37E-13 BDL2.36667E-11 BDL 1.44E-13 1.67E-11 DLL 3.32E-12BDL4.15E-12

1746-01-6 2,3,7,8-TCDD BDL 2.49E-12 BDL 4.34E-10 BDL1.15E-11 BDL 2.66E-12 8.73E-11 BDL 1.12E-12 BDL9.05E-13 BDL 1.12E-12 1.09E-09 40321-76-4 1,2,3,7,8-PeCDD 4.87E-12 BDL 2.18E-10 2.72E-11 BDL 6.21E-12 5.18E-11 DLL 2.94E-11 BDL7.57E-13 BDL 1.19E-12 2.88E-09 39227-28-6 1,2,3,4,7,8-HxCDD 2.14E-12 BDL 1.77E-10 1.86667E-11 BDL 8.23E-12 DLL3.67E-12 7.61E-11 DLL8.43E-13 BDL9.88E-13 2.82E-09 57653-85-7 1,2,3,6,7,8-HxCDD 8.01E-12 BDL 1.73E-10 3.56667E-11 DLL 1.54E-11 6.73E-12 1.26E-10 DLL 1.09E-12 BDL 1.01E-12 3.55E-09 19408-74-3 1,2,3,7,8,9-HxCDD 9.45E-12 BDL 1.77E-10 3.62667E-11 DLL 2.05E-11 1.02E-11 1.56E-10 DLL 1.26E-12 BDL9.12E-13 7.08E-09 35822-46-9 **1,2,3,4,6,7,8-HpCDD** 3.36E-11 BDL 2.97E-10 1.50667E-10 8.98E-11 1.63E-11 6.79E-10 DLL4.86E-12 DLL 1.61E-12 8.99E-09 3268-87-9 OCDD 2.90E-11 5.92E-10 1.077E-10 DLL 1.07E-10 1.59E-11 7.40E-10 1.41E-11 6.92E-12 6.44E-09 51207-31-9 2,3,7,8-TCDF 1.03E-11 BDL 2.83E-10 3.32E-11 BDL 1.75E-10 1.18E-09 DLL 2.19E-10 DLL 1.61E-12 DLL 1.40E-12 1.08E-07 57117-41-6 1,2,3,7,8-PeCDF 9.77E-12 BDL 1.74E-10 7.20333E-11 2.32E-11 3.35E-10 5.17E-10 DLL 1.36E-12 BDL 1.18E-12 1.59E-08 57117-31-4 **2,3,4,7,8-PeCDF** 1.36E-11 BDL 1.74E-10 7.38333E-11 3.54E-11 2.81E-10 1.31E-09 DLL2.14E-12 1.77E-12 2.29E-08 70648-26-9 1,2,3,4,7,8-HxCDF 2.15E-11 BDL 1.12E-10 1.91667E-10 7.45E-11 6.85E-11 5.49E-09 5.77E-12 BDL 1.11E-12 4.67E-08

**DIOXIN AND FURANS METALS** 

**TOTAL PCBs**

### SUMMARY OF CATALYTIC REFORMING UNITS

**TX3A1190 - Delek Refining Tyler, TX (Coke Burn Vent)** 

**DL lb/hr**  **CAS # Compound**  **DL WA**  **5A1420 Tesoro Anacortes,**
**WA (Oxychlorination Cycle)** 

**DL LA3C0590 ExxonMobil Baton**  **Rouge, LA (Purge Vent)**

**lb/hr TX3B1260 - Shell Oil Deer**  **Park, TX (Coke Burn Vent)**

**DL IL2A0430 ConocoPhillips WRB**  **Refining LP Roxana, IL (Coke**

**Burn Vent)**

**DL LA3C0610 Marathon Petroleum**  **Garyville, LA**

**(Coke Burn Vent)**

**DL lb/hr**  **TX3B1131 - CITGO Corpus Christi, TX (Coke Burn Vent)** 

**lb/hr Detection**  **Limit (DL) KS2C0480 Frontier El Dorado, KS**  **(Coke Burn Vent)**

**lb/hr KS2C0480 Frontier El Dorado, KS**  **(Purge Cycle Vent) WA**  **5A1420 Tesoro Anacortes,**
**WA (Coke Burn Vent)** 

**lb/hr TX3B1220 Motiva Port** 
**Ar thur, TX (Coke Burn**  **Vent)**

**DL lb/hr**  **lb/hr lb/hr**  **lb/hr lb/hr**  **DL lb/hr**  **DL DL** **lb/hr PA1A1020 Sunoco Marcus**  **Hook, PA**

**(Coke Burn Vent)**

**DL DL**  **LA3C0590 ExxonMobil Baton Rouge, LA (Coke Burn Vent)** 

57117-44-9 **1,2,3,6,7,8-HxCDF** 9.97E-12 BDL 9.95E-11 9.24E-11 3.60E-11 4.49E-11 2.51E-09 4.31E-12 BDL8.21E-13 1.67E-08 72918-21-9 1,2,3,7,8,9-HxCDF DLL 3.02E-12 BDL 1.21E-10 DLL 1.24E-11 BDL 6.57E-12 DDL2.90E-12 2.39E-10 1.33E-12 BDL9.59E-13 1.80E-09 60851-34-5 2,3,4,6,7,8-HxCDF 5.29E-12 BDL 1.04E-10 3.56333E-11 3.65E-11 1.55E-11 2.53E-09 3.60E-12 BDL9.18E-13 1.32E-08 67562-39-4 1,2,3,4,6,7,8-HpCDF 2.48E-11 DDL 1.95E-10 2.29667E-10 BDL 1.49E-10 4.61E-11 7.06E-09 1.27E-11 BDL 1.27E-12 4.23E-08 55673-89-7 1,2,3,4,7,8,9-HpCDF 3.22E-12 BDL 2.01E-10 8.23E-11 DLL 4.34E-11 8.94E-12 2.39E-09 5.81E-12 BDL9.39E-13 9.99E-09 39001-02-0 OCDF 8.31E-12 BDL 2.32E-10 2.02333E-10 BDL 9.62E-11 2.04E-11 3.45E-09 1.62E-11 BDL 1.41E-12 1.90E-08

Other TCDD 9.70333E-11 Other PeCDD 1.26467E-10 Other HxCDD 1.99333E-10 Other HpCDD 9.75E-11 Other TCDF 8.98667E-10 Other PeCDF 6.46E-10 Other HxCDF 4.23333E-10 Other HpCDF 1.47333E-10 Total TCDD 9.01E-11 BDL 4.34E-10 1.08867E-10 7.06E-10 9.34E-09 BDL6.51E-11 1.06E-11 BDL 9.05E-13 Total PeCDD 1.18E-10 BDL 2.18E-10 1.53667E-10 1.69E-10 8.69E-10 DLL 4.595E-10 3.13E-10 BDL 7.57E-13 Total HxCDD 1.23E-10 BDL 1.77E-10 2.90333E-10 3.79E-10 8.08E-11 DLL 6.13E-10 1.16E-09 DLL 3.35E-10 Total HpCDD 6.29E-11 BDL 2.97E-10 2.48E-10 1.80E-10 3.02E-11 DLL 1.04E-09 1.37E-09 DLL 4.86E-12 Total TCDF 6.93E-10 BDL 2.83E-10 9.29333E-10 1.97E-09 6.94E-08 3.65E-09 5.92E-10 DLL 1.61E-12 Total PeCDF 5.85E-10 BDL 1.74E-10 7.93E-10 4.75E-10 6.65E-09 DLL 3.71E-10 6.58E-09 DLL 2.11E-10 Total HxCDF 1.31E-10 BDL 1.07E-10 7.56E-10 3.85E-10 3.79E-10 BDL 1.90E-10 2.00E-08 2.22E-09 Total HpCDF 3.40E-11 BDL 2.09E-10 4.59667E-10 8.32E-11 7.35E-11 BDL4.65E-10 1.48E-08 2.19E-09

Total Dioxins 4.23E-10 BDL 1.72E-09 Total Furans 1.45E-09 BDL 1.00E-09 Total Dioxins and Furans 1.873E-09 4.55E-09 8.68E-08 4.88E-08 1.78E-10 1746-01-6 Dioxin toxic equivalents (TEQ) 1.67E-09 1.12E-12

**Calculated TEQ**