EMISSIONS TEST REPORT 

BIG BEND STATION 

FACILITY ID NUMBER: 0570039 

EMISSION UNIT ID NO: -004 

PARTICULATE MATTER, SULFUR DIOXIDE, 

NITROGEN OXIDE, AND 

VISIBLE EMISSIONS EVALUATION 

April 25, 2006 

Prepared For: 

Tampa Electric Company 

Big Bend Station 

P.O. Box 111 

Tampa, Florida 33601-0111 

Prepared By: 

Tampa Electric Company 

Environmental, Health & Safety 

Environmental Services 

Air Services Group 

Environmental Services 

Air Services Group 

5010 Causeway Boulevard 

Tampa, Florida 33619- 6130 
REPORT CERTIFICATION 

I have reviewed the test performance, associated quality assurance 

activities, the resultant calculations, and the contents of this report, and certify 

that all project quality objectives have been met. This report is approved for 

submittal. 

Signature:__________________________ 

Raymond A. McDarby, Jr. 

Senior Environmental Technician 

Quality Assurance/Quality Control Specialist

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

The sampling and subsequent data entry/reduction detailed in this report

were conducted at my direction, and I hereby certify that this test report is 

authentic and accurate to the best of my knowledge. 

Signature:__________________________ 

Jorge A. Varino 

Technician 

Test Team Lead 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

I have reviewed the testing details and results submitted in this report, 

and hereby certify that this test report is authentic and accurate to the best of 

my knowledge. 

Signature:__________________________ 

David A. Smith 

Coordinator – Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 
TABLE OF CONTENTS

SECTION PAGE NO.

1.0 INTRODUCTION 1

2.0 DISCUSSION OF RESULTS 2 

3.0 SOURCE DESCRIPTION/TEST PROCEDURES 3 

4.0 TEST RESULTS 

PARTICULATE TEST SUMMARY 5

SULFUR DIOXIDE / OXIDES OF NITROGEN SUMMARY 6 

60 MINUTE OPACITY DATA SUMMARY 7 

HEAT INPUT AND FUEL CONSUMPTION SUMMARY 8 

5.0 SAMPLING LOCATION DIAGRAM 

 PARTICULATE SAMPLING TRAVERSE POINTS 10

APPENDICES

A. PARTICULATE TEST CALCULATIONS 

B. SULFUR DIOXIDE / OXIDES OF NITROGEN 

RAW DATA

C. PARTICULATE LABORATORY ANALYTICAL DATA 

D. BOILER / PRECIPITATOR OPERATIONAL DATA 

E. FUEL ANALYSIS 

F. FIELD DATA SHEETS 

G. SAMPLING EQUIPMENT CALIBRATIONS 

H. CHAIN OF CUSTODY 

I. TEST PARTICIPANTS 
1

1.0 INTRODUCTION

On April 25, 2006, Tampa Electric Company’s Environmental Services, Air 

Services Group, performed source emission tests at the Big Bend Station 

(Facility ID No.: 0570039), Boiler No. 4, (E.U. ID No.: -004). Testing was 

conducted according to procedures stipulated by the Florida Department of 

Environmental Protection (FDEP) for fossil fuel steam generators, and 

requirements in Title V Permit # 0570039-021-AV, Compliance determination 

procedures and methods, §B.26 through §B.30. 
2

2.0 DISCUSSION OF RESULTS

The average particulate matter emissions were derived by performing three 

United States Environmental Protection Agency (USEPA) reference method 5B 

test runs. The average emission rates were calculated as 0.01 lb/mmBtu, and 

33.6 lbs/hr. The FDEP permitted emission rates are 0.01 lb/mmBtu and 43.3 

lbs/hr (§ B.5.i (a) & (b)). 

During the particulate matter test the Sulfur Dioxide (SO2) emission rates were 

determined to be 0.34 lb/mmBtu and 1434 lbs/hr. The FDEP permitted emission 

rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling average (§ B.7 

(a) & (b)). 

During the particulate matter test the nitrogen dioxide (NO2) emission rates (as 

total oxides) were determined to be 0.27 lb/mmBtu and 1132 lbs/hr. The FDEP 

permitted emission rate is 0.60 lb/mmBtu and 2598 lbs/hr, based on a 30-day 

rolling average (§B.9). 

Visible emissions were determined to be 4%, maximum 6-minute average, during 

a one-hour test conducted under soot blowing conditions. The FDEP permitted 

emission rate is 20 percent opacity (6-minute average) except for one 6-minute 

period per hour of not more than 27 (twenty-seven) percent (§B.6). 

During the particulate matter test performed on April 25, 2006 Boiler No. 4 was 

operated at an average heat input rate of 4233 mmBtu/hr and an average load of 

446 megawatts. The average quantity of fuel burned was 187.3 tons per hour. 
3

3.0 SOURCE DESCRIPTION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM 

coordinates East 361.9 North 3075.0. Boiler No. 4 source sampling location 

consists of a circular stack 28.83 feet in diameter with four sample ports located 

90 degrees apart on the stack circumference. Upstream and downstream gas 

flow disturbances were determined to be 8.51 and 2.99 stack diameters from the 

test ports, respectively. Using these criteria, a total of 24 sampling points were 

chosen for particulate sampling for each stack, as stipulated in the U.S. EPA 

Method 1 test procedure. A diagram of the stack sampling location is included in 

Figure 1 along with other pertinent information on the test site. 

Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash 

emissions and a flue gas desulfurization (FGD) system for control of sulfur 

dioxide emissions. 

During the test the boiler was fired with a solid fuel matrix comprised of 90% coal 

and 10% petroleum coke. 

Particulate sampling was performed according to USEPA Method 5-B 

"Determination of Nonsulfuric Acid Particulate Matter from Stationary Sources". 

Particulate matter was collected on a high purity, glass micro fiber filter 

measuring 8.26 cm in diameter. 

Sulfur Dioxide and Nitrogen Oxide data was supplied by the installed Continuous 

Emissions Monitoring systems (CEMs), Data Acquisition and Handling System 

(DAHS) as one minute averages for the duration of the particulate matter test. 

Visible emissions compliance was assessed using the installed Continuous 

Opacity Monitor (COM) as recorded by the DAHS as one minute averages during 

the soot blowing portion of the particulate matter test. 
4

4.0 TEST RESULTS
BIG BEND STATION

PARTICULATE MATTER DATA SUMMARY

Run 1 Run 2* Run 3 Test Summary

Vm(std), scf 72.736 75.884 72.425 73.682

Bws, ratio 0.11220 0.14514 0.13971 0.132348

O2, % volume 8 8 88.00

Md, lb/lb - mole 30.40 30.40 30.40 30.400

Ms, lb/lb - mole 29.01 28.60 28.67 28.759

Qs, acf/min 1472837.0 1557155.3 1482472.8 1504155.05

Qs(std), dscf/min 1164215.8 1182496.5 1136446.8 1161053.02

I, % 98.9 101.6 100.9 100.47

C, lbs/dscf 4.82E-07 5.11E-07 4.52E-07 4.8175E-07

Em, lbs/hr 33.7 36.3 30.8 33.6

Er, lb/mmBtu 0.01 0.01 0.01 0.01

Mass emissions (Em), lbs/hr, calculated as: C x Qs(std) x 60 minutes/hour

Emission rate (Er), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O2))

*

Run 2 was a soot blowing run

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

April 25, 2006

5
BIG BEND STATION

SULFUR DIOXIDE and NITROGEN OXIDES DATA

Outlet SO2 Data

Average SO2 Concentration, ppmvw: 122.30

Average CO2 Concentration, % volume wet: 10.785

Calculated SO2 Emission Rate, lb/mmBtu: 0.34

Calculated SO2 Emission Rate, lbs/hr: 1434

Unit #4 NOx Data

Average NOx concentration, ppmvw: 158.55

Average CO2 Concentration, % volume wet: 12.742

Calculated NOx Emission Rate, lb/mmBtu: 0.27

Calculated NOx Emission Rate, lbs/hr: 1132

SO2 Emission Rate, lb(s)/mmBtu is calculated as:

SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw)

NOx Emission Rate, lb/mmBtu is calculated as:

NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw)

Emission Rates in lbs/hr are calculated as:

Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr

Average Concentration values were taken from 7:08 to 14:23 EST.

Heat Input Calculated for this test was 4233 mmBtu/hr

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

April 25, 2006

6
BIG BEND STATION

VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY4 Record# DATE TIME OPACITY4

1 4/25/2006 9:50 4.09 31 4/25/2006 10:20 4.05

2 4/25/2006 9:51 3.91 32 4/25/2006 10:21 4.12

3 4/25/2006 9:52 4.16 33 4/25/2006 10:22 4.10

4 4/25/2006 9:53 4.00 34 4/25/2006 10:23 3.89

5 4/25/2006 9:54 3.90 35 4/25/2006 10:24 4.05

6 4/25/2006 9:55 4.26 36 4/25/2006 10:25 4.03

7 4/25/2006 9:56 3.82 37 4/25/2006 10:26 3.91

8 4/25/2006 9:57 4.02 38 4/25/2006 10:27 3.87

9 4/25/2006 9:58 3.97 39 4/25/2006 10:28 3.84

10 4/25/2006 9:59 3.93 40 4/25/2006 10:29 4.00

11 4/25/2006 10:00 3.89 41 4/25/2006 10:30 4.17

12 4/25/2006 10:01 3.80 42 4/25/2006 10:31 4.09

13 4/25/2006 10:02 3.81 43 4/25/2006 10:32 3.87

14 4/25/2006 10:03 3.94 44 4/25/2006 10:33 4.05

15 4/25/2006 10:04 3.99 45 4/25/2006 10:34 4.11

16 4/25/2006 10:05 3.97 46 4/25/2006 10:35 4.14

17 4/25/2006 10:06 4.03 47 4/25/2006 10:36 4.02

18 4/25/2006 10:07 3.88 48 4/25/2006 10:37 3.88

19 4/25/2006 10:08 3.96 49 4/25/2006 10:38 3.88

20 4/25/2006 10:09 4.05 50 4/25/2006 10:39 3.85

21 4/25/2006 10:10 4.08 51 4/25/2006 10:40 3.77

22 4/25/2006 10:11 4.02 52 4/25/2006 10:41 4.02

23 4/25/2006 10:12 4.27 53 4/25/2006 10:42 4.05

24 4/25/2006 10:13 4.34 54 4/25/2006 10:43 4.12

25 4/25/2006 10:14 4.08 55 4/25/2006 10:44 4.16

26 4/25/2006 10:15 4.32 56 4/25/2006 10:45 4.09

27 4/25/2006 10:16 4.10 57 4/25/2006 10:46 4.00

28 4/25/2006 10:17 4.16 58 4/25/2006 10:47 3.99

29 4/25/2006 10:18 4.07 59 4/25/2006 10:48 4.32

30 4/25/2006 10:19 4.21 60 4/25/2006 10:49 4.07

Test Average: 4 %

Minimum One Minute Average: 4 %

Maximum One Minute Average: 4 %

Maximum Six Minute Average: 4 %

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

SOOTBLOWING CONDITIONS

7
BIG BEND STATION

HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (March): 9490 KMBtu/MWh

9.4900E+06 mmBtu/MWh

MegaWatt Hour Integrator Information

Initial Integrator Reading: 724118 MWh

Final Integrator Reading: 727352 MWh

Total: 3234 MWh

Testing Start Time: 6:08

Testing End Time: 13:23

Total Test Time: 7.25 hours

Average Unit Load, MW = MWh / hours: 446 MW

Heat Input, MMBtu/h = MMBtu/MWh x MW: 4233 mmBtu/hr

Laboratory Sample ID: AA76141

Btu as received: 11303 Btu/lb

Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 187.3 Tons/hour

Unit #4

Test Time Information

Calculated Heat Input

Fuel Consumption Calculation

DRY-BOTTOM TANGENTIALLY FIRED BOILER

April 25, 2006

8
9

5.0 FIGURES
FIGURE 1

EXHAUST STACK

245 FT.

BIG BEND STATION CS003

PARTICULATE TRAVERSE POINTS

OUTLET

N

A

B C

D

PORT LOCATION

REVISED 12-31-96

BOILER NO. 4 TEST LOCATION

STACK DIAMETERS DOWNSTREAM

FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM

FROM DISTURBANCE = 8.5

STACK DIAMETER = 28.8333 FT.

STACK AREA = 652.948 SQ.

PORT LENGTH’S = 14 IN.

TRAVERSE

 POINT

 1

 2

 3

 4

 5

 6

 % OF

STACK DIAMETER

 IN. FROM

STACK WALL

 2.1%

 6.7%

11.8%

17.7%

25.0%

35.6%

 7.27 IN.

 23.18 IN.

 40.83 IN.

 61.24 IN.

 86.50 IN.

123.18 IN.

499 FT.

254 FT.

168 FT.

86 FT.

FGD

PRESSURIZED

 ANNULUS

10
APPENDIX A 

PARTICULATE TEST CALCULATIONS 
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Common Stack 3 (CS003)

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded

Run Number: 1

Date: April 25, 2006

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.251 inches

Barometric Pressure, Pb: 29.88 "Hg Nozzle Area, An: 0.000344 ft2

Stack Pressure, Ps: 29.83 "Hg Average Orifice Meter, ΔH: 1.276 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 76.250 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 97.8 o

F

Gas Analysis: 13.0 % CO2 Average Stack Temp., Ts: 131.2 o

F

8.0 % O2 Average √Δp: 0.633 "H2O

0.0 % CO Condensate Volume, Vlc: 195.0 ml

79.0 % N2 Meter Box Y: 1.006 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 9.192 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 72.736 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.112 %

FDA = 1.0 - Bws 0.888 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.40 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 29.01 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 37.59 ft/second

Qs = vs x As x 60 1472837.0 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1164215.8 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 98.9 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01590 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.003 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.003 grains/acf

C = cs / 7000 4.819E-07 lbs/dscf

EM = C x Qs(std) x 60 33.7 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.01 lbs/MMBtu
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Common Stack 3 (CS003)

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded, Sootblowing

Run Number: 1 - s

Date: April 25, 2006

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.251 inches

Barometric Pressure, Pb: 29.90 "Hg Nozzle Area, An: 0.000344 ft2

Stack Pressure, Ps: 29.85 "Hg Average Orifice Meter, ΔH: 1.394 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 79.160 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 95.6 o

F

Gas Analysis: 13.0 % CO2 Average Stack Temp., Ts: 133.0 o

F

8.0 % O2 Average √Δp: 0.664 "H2O

0.0 % CO Condensate Volume, Vlc: 273.3 ml

79.0 % N2 Meter Box Y: 1.006 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 12.883 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 75.884 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.145 %

FDA = 1.0 - Bws 0.855 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.40 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.60 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 39.75 ft/second

Qs = vs x As x 60 1557155.3 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1182496.5 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 101.6 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01760 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.004 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.003 grains/acf

C = cs / 7000 5.113E-07 lbs/dscf

EM = C x Qs(std) x 60 36.3 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.01 lbs/MMBtu
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Common Stack 3 (CS003)

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded

Run Number: 2

Date: April 25, 2006

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.251 inches

Barometric Pressure, Pb: 29.90 "Hg Nozzle Area, An: 0.000344 ft2

Stack Pressure, Ps: 29.86 "Hg Average Orifice Meter, ΔH: 1.298 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 77.168 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 107.4 o

F

Gas Analysis: 13.0 % CO2 Average Stack Temp., Ts: 131.4 o

F

8.0 % O2 Average √Δp: 0.634 "H2O

0.0 % CO Condensate Volume, Vlc: 249.5 ml

79.0 % N2 Meter Box Y: 1.006 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 11.761 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 72.425 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.140 %

FDA = 1.0 - Bws 0.860 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.40 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.67 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 37.84 ft/second

Qs = vs x As x 60 1482472.8 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1136446.8 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.9 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01485 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.0032 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.0024 grains/acf

C = cs / 7000 4.520E-07 lbs/dscf

EM = C x Qs(std) x 60 30.8 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.01 lbs/MMBtu
APPENDIX B 

 SULFUR DIOXIDE / OXIDES OF NITROGEN 

RAW DATA
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 7:08 162.8 12.69 101.2 10.79

4/25/2006 7:09 163.3 12.65 97.1 10.86

4/25/2006 7:10 162.3 12.7 105.3 10.89

4/25/2006 7:11 158.9 12.73 107.7 10.86

4/25/2006 7:12 162.6 12.76 105.2 10.89

4/25/2006 7:13 160.4 12.78 106.4 10.9

4/25/2006 7:14 159.7 12.79 113.5 10.83

4/25/2006 7:15 163.2 12.72 117.9 10.82

4/25/2006 7:16 163.5 12.72 120.1 10.83

4/25/2006 7:17 161.8 12.72 113.9 10.84

4/25/2006 7:18 161.7 12.72 114.6 10.81

4/25/2006 7:19 163.6 12.69 121.2 10.75

4/25/2006 7:20 162.9 12.67 123.1 10.75

4/25/2006 7:21 165.2 12.61 125.3 10.79

4/25/2006 7:22 163.8 12.63 118.9 10.82

4/25/2006 7:23 162.8 12.65 131.3 10.83

4/25/2006 7:24 163.1 12.71 109.5 10.84

4/25/2006 7:25 164.3 12.68 85.7 10.89

4/25/2006 7:26 162.6 12.69 94.1 10.87

4/25/2006 7:27 162.3 12.75 100.8 10.9

4/25/2006 7:28 161.1 12.78 108.5 10.82

4/25/2006 7:29 165.6 12.73 112.3 10.77

4/25/2006 7:30 164.6 12.65 114.3 10.85

4/25/2006 7:31 161.3 12.72 115.9 10.82

4/25/2006 7:32 163.9 12.7 113.8 10.85

4/25/2006 7:33 161 12.73 119.4 10.84

4/25/2006 7:34 161.7 12.72 117 10.85

4/25/2006 7:35 159.4 12.74 113.7 10.83

4/25/2006 7:36 161.2 12.77 124.9 10.83

4/25/2006 7:37 159.7 12.71 128.5 10.8

4/25/2006 7:38 161.7 12.67 134.2 10.82

4/25/2006 7:39 159.9 12.7 121.7 10.79

4/25/2006 7:40 163.7 12.69 131.2 10.77

4/25/2006 7:41 163.3 12.6 131.8 10.81

4/25/2006 7:42 164.2 12.66 133 10.81

4/25/2006 7:43 162.5 12.68 136.5 10.81

4/25/2006 7:44 162 12.65 147.1 10.84

4/25/2006 7:45 160.8 12.67 133.6 10.84

4/25/2006 7:46 161.8 12.66 120.8 10.89

4/25/2006 7:47 160.9 12.76 125.4 10.89

4/25/2006 7:48 161.4 12.7 138.3 10.86

4/25/2006 7:49 162.1 12.71 130.1 10.79

4/25/2006 7:50 163.3 12.63 101 10.82

Page 1 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 7:51 161.1 12.64 101.2 10.85

4/25/2006 7:52 161.2 12.7 107 10.79

4/25/2006 7:53 163.6 12.69 108.3 10.8

4/25/2006 7:54 161.4 12.65 109.8 10.86

4/25/2006 7:55 159.9 12.69 105.5 10.78

4/25/2006 7:56 162.9 12.69 108.1 10.71

4/25/2006 7:57 163.9 12.58 112.5 10.76

4/25/2006 7:58 163.4 12.65 107.3 10.75

4/25/2006 7:59 163.6 12.64 110.1 10.74

4/25/2006 8:00 161.6 12.61 106.8 10.76

4/25/2006 8:01 163.4 12.66 130.2 10.75

4/25/2006 8:02 163.6 12.66 135.5 10.79

4/25/2006 8:03 165.7 12.72 119.7 10.81

4/25/2006 8:04 165.5 12.73 132.6 10.77

4/25/2006 8:05 163.7 12.68 144 10.73

4/25/2006 8:06 166.2 12.62 138.9 10.71

4/25/2006 8:07 165.5 12.58 135.4 10.77

4/25/2006 8:08 163.8 12.63 131.5 10.8

4/25/2006 8:09 164.9 12.68 123.1 10.81

4/25/2006 8:10 163.1 12.65 108.3 10.84

4/25/2006 8:11 163.7 12.7 91.4 10.81

4/25/2006 8:12 164.9 12.66 98.4 10.86

4/25/2006 8:13 167.5 12.68 102.4 10.78

4/25/2006 8:14 167.5 12.62 106.7 10.82

4/25/2006 8:15 164.2 12.67 116.9 10.83

4/25/2006 8:16 165.5 12.68 130.5 10.91

4/25/2006 8:17 160.6 12.77 119.2 10.93

4/25/2006 8:18 161.3 12.85 113.3 10.8

4/25/2006 8:19 165.8 12.72 105 10.71

4/25/2006 8:20 165.3 12.58 117.3 10.73

4/25/2006 8:21 163.1 12.59 121.9 10.7

4/25/2006 8:22 165 12.55 122.6 10.72

4/25/2006 8:23 163.3 12.57 129.4 10.74

4/25/2006 8:24 161.9 12.63 136.8 10.83

4/25/2006 8:25 160.1 12.69 131.4 10.84

4/25/2006 8:26 160.9 12.71 119.4 10.82

4/25/2006 8:27 160.8 12.65 125.4 10.84

4/25/2006 8:28 161.3 12.66 128.3 10.81

4/25/2006 8:29 162.2 12.7 124.7 10.81

4/25/2006 8:30 163.9 12.64 130.6 10.81

4/25/2006 8:31 163.1 12.62 136.8 10.83

4/25/2006 8:32 161.7 12.68 140.5 10.84

4/25/2006 8:33 162.3 12.73 141.3 10.82

Page 2 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 8:34 161.6 12.7 150.3 10.75

4/25/2006 8:35 164.2 12.63 150.3 10.76

4/25/2006 8:36 161.8 12.63 141.6 10.84

4/25/2006 8:37 159.5 12.72 144.5 10.86

4/25/2006 8:38 162.9 12.77 144.6 10.78

4/25/2006 8:39 164.6 12.65 119.8 10.8

4/25/2006 8:40 163.2 12.62 98.3 10.83

4/25/2006 8:41 164.1 12.62 92.6 10.79

4/25/2006 8:42 162.7 12.66 101.1 10.75

4/25/2006 8:43 163.9 12.63 114 10.8

4/25/2006 8:44 162.2 12.67 122 10.86

4/25/2006 8:45 159.9 12.75 120.6 10.8

4/25/2006 8:46 160.7 12.69 111.7 10.77

4/25/2006 8:47 162.9 12.68 112.6 10.67

4/25/2006 8:48 164.4 12.52 112.5 10.75

4/25/2006 8:49 162.7 12.58 114.6 10.81

4/25/2006 8:50 162.5 12.64 128.8 10.86

4/25/2006 8:51 160 12.64 122.4 10.85

4/25/2006 8:52 161.9 12.73 120.7 10.81

4/25/2006 8:53 161.9 12.69 130.2 10.84

4/25/2006 8:54 158.9 12.72 134.4 10.88

4/25/2006 8:55 158.6 12.77 134.2 10.82

4/25/2006 8:56 162.5 12.72 130.8 10.74

4/25/2006 8:57 163.6 12.61 137.8 10.65

4/25/2006 8:58 163.8 12.5 127.3 10.71

4/25/2006 8:59 164.6 12.52 128.5 10.73

4/25/2006 9:00 164.5 12.57 139.3 10.74

4/25/2006 9:01 162.8 12.61 138.9 10.7

4/25/2006 9:02 163.9 12.58 131.7 10.71

4/25/2006 9:03 162.1 12.6 138.1 10.69

4/25/2006 9:04 163.5 12.57 145.5 10.78

4/25/2006 9:05 162.9 12.64 143.5 10.78

4/25/2006 9:06 162.6 12.67 137.7 10.77

4/25/2006 9:07 162 12.65 138.5 10.86

4/25/2006 9:08 161.3 12.69 142.6 10.85

4/25/2006 9:09 161.3 12.68 150.4 10.9

4/25/2006 9:10 161.1 12.72 128.5 10.88

4/25/2006 9:11 161.9 12.73 118.8 10.86

4/25/2006 9:12 160.6 12.72 96.8 10.82

4/25/2006 9:13 160.8 12.68 93.7 10.88

4/25/2006 9:14 161 12.7 98 10.84

4/25/2006 9:15 163 12.69 103.1 10.85

4/25/2006 9:16 159.5 12.69 91.8 10.78

Page 3 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 9:17 163.2 12.65 98.8 10.78

4/25/2006 9:18 159.6 12.6 101.9 10.72

4/25/2006 9:19 162.1 12.57 104.3 10.69

4/25/2006 9:20 162.7 12.53 109.8 10.75

4/25/2006 9:21 162.1 12.57 117.6 10.8

4/25/2006 9:22 161.8 12.65 106.9 10.77

4/25/2006 9:23 163.5 12.58 113 10.77

4/25/2006 9:24 161.7 12.57 115.4 10.81

4/25/2006 9:25 162.9 12.65 120.2 10.8

4/25/2006 9:26 164 12.62 133.4 10.83

4/25/2006 9:27 163.2 12.67 129.3 10.78

4/25/2006 9:28 162.6 12.62 116 10.8

4/25/2006 9:29 162.6 12.63 114.4 10.8

4/25/2006 9:30 161.9 12.61 123 10.81

4/25/2006 9:31 160.6 12.65 142.7 10.86

4/25/2006 9:32 161.3 12.73 139.5 10.79

4/25/2006 9:33 164.3 12.69 126.2 10.79

4/25/2006 9:34 164.3 12.68 122.7 10.78

4/25/2006 9:35 163 12.66 124.5 10.74

4/25/2006 9:36 164.1 12.61 142.4 10.76

4/25/2006 9:37 163.8 12.65 143.2 10.77

4/25/2006 9:38 162.3 12.68 137.6 10.86

4/25/2006 9:39 160.4 12.72 136.2 10.78

4/25/2006 9:40 162.7 12.64 141.1 10.79

4/25/2006 9:41 160.5 12.63 145.1 10.8

4/25/2006 9:42 161 12.68 130.3 10.79

4/25/2006 9:43 161 12.67 131.3 10.83

4/25/2006 9:44 159.7 12.67 123.9 10.84

4/25/2006 9:45 160.2 12.7 104.7 10.82

4/25/2006 9:46 162.5 12.65 108.4 10.81

4/25/2006 9:47 161.2 12.63 116.4 10.8

4/25/2006 9:48 160.7 12.65 120.5 10.84

4/25/2006 9:49 158.8 12.7 106.5 10.85

4/25/2006 9:50 160.4 12.71 105.8 10.85

4/25/2006 9:51 159.4 12.7 117.1 10.83

4/25/2006 9:52 161.1 12.67 119.1 10.83

4/25/2006 9:53 162.2 12.68 107.6 10.85

4/25/2006 9:54 159.2 12.72 105.9 10.8

4/25/2006 9:55 160.8 12.68 108.3 10.73

4/25/2006 9:56 162.4 12.58 124.4 10.79

4/25/2006 9:57 160.7 12.57 117.4 10.82

4/25/2006 9:58 159.4 12.7 115.6 10.76

4/25/2006 9:59 160 12.64 122 10.77

Page 4 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 10:00 160 12.63 125.5 10.78

4/25/2006 10:01 160.6 12.66 138.4 10.85

4/25/2006 10:02

4/25/2006 10:03

4/25/2006 10:04

4/25/2006 10:05

4/25/2006 10:06

4/25/2006 10:07

4/25/2006 10:08

4/25/2006 10:09

4/25/2006 10:10 164.6 12.98 104.7 10.81

4/25/2006 10:11 161 12.97 109.1 10.81

4/25/2006 10:12 159.4 12.97 101.9 10.78

4/25/2006 10:13 159 12.9 105.5 10.77

4/25/2006 10:14 161.1 12.78 108.4 10.79

4/25/2006 10:15 156 12.77 112 10.89

4/25/2006 10:16 152.2 12.9 115.2 10.86

4/25/2006 10:17 156 12.85 116.8 10.84

4/25/2006 10:18 154.7 12.85 113.5 10.84

4/25/2006 10:19 156.2 12.82 112.6 10.8

4/25/2006 10:20 154.7 12.75 124.7 10.79

4/25/2006 10:21 158.7 12.71 118.3 10.73

4/25/2006 10:22 158.8 12.67 108.5 10.71

4/25/2006 10:23 160.3 12.65 116 10.77

4/25/2006 10:24 156.7 12.71 126.8 10.79

4/25/2006 10:25 156.9 12.73 127.7 10.81

4/25/2006 10:26 157.2 12.75 130.6 10.82

4/25/2006 10:27 158.9 12.73 119 10.9

4/25/2006 10:28 155.6 12.81 126.9 10.9

4/25/2006 10:29 157.2 12.85 137.2 10.95

4/25/2006 10:30 152.8 12.88 132.6 10.95

4/25/2006 10:31 153.2 12.91 115.1 10.92

4/25/2006 10:32 154.7 12.86 92.2 10.91

4/25/2006 10:33 155.7 12.8 96.8 10.88

4/25/2006 10:34 156.9 12.74 103.3 10.87

4/25/2006 10:35 154.9 12.74 100.2 10.85

4/25/2006 10:36 156.7 12.74 98.2 10.82

4/25/2006 10:37 156.4 12.76 103.4 10.86

4/25/2006 10:38 155 12.8 109.5 10.86

4/25/2006 10:39 154.9 12.82 116.5 10.89

4/25/2006 10:40 154.2 12.82 125.4 10.91

4/25/2006 10:41 153.6 12.85 109.1 10.85

4/25/2006 10:42 159.1 12.81 105.2 10.8

Data excluded due to calibrations.

Page 5 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 10:43 156.2 12.71 103.5 10.8

4/25/2006 10:44 159.2 12.7 112.7 10.78

4/25/2006 10:45 158.7 12.65 120.4 10.75

4/25/2006 10:46 158.2 12.68 130.7 10.81

4/25/2006 10:47 157.3 12.69 119.8 10.83

4/25/2006 10:48 156.9 12.76 114.6 10.84

4/25/2006 10:49 157.5 12.78 122.5 10.84

4/25/2006 10:50 157.6 12.75 131.3 10.83

4/25/2006 10:51 156.9 12.76 132.6 10.8

4/25/2006 10:52 156.2 12.76 120.9 10.85

4/25/2006 10:53 155.8 12.77 119.7 10.83

4/25/2006 10:54 157.5 12.79 120 10.81

4/25/2006 10:55 157.2 12.74 129.4 10.81

4/25/2006 10:56 155.9 12.75 134.5 10.85

4/25/2006 10:57 152.6 12.82 139.7 10.93

4/25/2006 10:58 150.3 12.91 127.1 10.9

4/25/2006 10:59 152.9 12.91 127 10.85

4/25/2006 11:00 153.8 12.87 123.3 10.81

4/25/2006 11:01 156.8 12.8 125.6 10.79

4/25/2006 11:02 154.6 12.77 133 10.8

4/25/2006 11:03 158.5 12.75 129.5 10.86

4/25/2006 11:04 155.5 12.82 136.4 10.88

4/25/2006 11:05 156.7 12.87 140.2 10.85

4/25/2006 11:06 158.6 12.82 132.1 10.81

4/25/2006 11:07 159 12.79 106.5 10.85

4/25/2006 11:08 156.6 12.74 95.9 10.86

4/25/2006 11:09 156.6 12.81 89.9 10.85

4/25/2006 11:10 157.7 12.76 94.3 10.82

4/25/2006 11:11 157.3 12.75 101.1 10.84

4/25/2006 11:12 157.9 12.82 107.8 10.83

4/25/2006 11:13 158.3 12.77 110.2 10.8

4/25/2006 11:14 158.2 12.77 112.7 10.78

4/25/2006 11:15 158.5 12.76 107.6 10.74

4/25/2006 11:16 159.1 12.71 107.7 10.82

4/25/2006 11:17 158.4 12.73 112.6 10.84

4/25/2006 11:18 158.6 12.78 117.1 10.83

4/25/2006 11:19 159.7 12.74 116 10.82

4/25/2006 11:20 158.2 12.77 108.3 10.83

4/25/2006 11:21 159.2 12.79 116.4 10.82

4/25/2006 11:22 161.4 12.77 128.6 10.84

4/25/2006 11:23 157.1 12.73 119.2 10.89

4/25/2006 11:24 157.2 12.84 117.8 10.86

4/25/2006 11:25 159 12.79 122.3 10.73

Page 6 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 11:26 161.5 12.66 123.1 10.72

4/25/2006 11:27 162 12.62 122.5 10.8

4/25/2006 11:28 158.4 12.73 128.6 10.85

4/25/2006 11:29 156.1 12.83 139.3 10.91

4/25/2006 11:30 153.1 12.89 127.1 10.94

4/25/2006 11:31 154 12.93 123 10.85

4/25/2006 11:32 159.2 12.8 124.1 10.78

4/25/2006 11:33 157.5 12.67 124.9 10.77

4/25/2006 11:34 159.2 12.68 127.5 10.78

4/25/2006 11:35 158.6 12.71 114.9 10.86

4/25/2006 11:36 158.2 12.78 100.5 10.91

4/25/2006 11:37 158.1 12.85 104.9 10.9

4/25/2006 11:38 156.8 12.87 98.3 10.81

4/25/2006 11:39 159.3 12.79 99 10.85

4/25/2006 11:40 157.4 12.76 102.5 10.86

4/25/2006 11:41 157.8 12.78 109.3 10.85

4/25/2006 11:42 155.4 12.8 110.8 10.78

4/25/2006 11:43 157.2 12.75 122 10.83

4/25/2006 11:44 153 12.76 115.5 10.93

4/25/2006 11:45 151.1 12.89 114.7 10.89

4/25/2006 11:46 154.4 12.88 119.2 10.95

4/25/2006 11:47 151.2 12.89 119.6 10.91

4/25/2006 11:48 154.3 12.87 114.3 10.82

4/25/2006 11:49 157.5 12.76 107.8 10.83

4/25/2006 11:50 157.7 12.71 110.3 10.86

4/25/2006 11:51 156.3 12.74 109.8 10.84

4/25/2006 11:52 157.9 12.74 123.6 10.86

4/25/2006 11:53 154.9 12.79 115.4 10.89

4/25/2006 11:54 153.7 12.83 112.6 10.9

4/25/2006 11:55 155.1 12.85 118.5 10.95

4/25/2006 11:56 152.2 12.89 132.4 10.92

4/25/2006 11:57 153.4 12.89 119.1 10.93

4/25/2006 11:58 153.3 12.87 124.2 10.88

4/25/2006 11:59 154.5 12.82 129.9 10.91

4/25/2006 12:00 154.5 12.84 136.3 10.85

4/25/2006 12:01 155.1 12.79 122.5 10.88

4/25/2006 12:02 152.4 12.83 124.8 10.92

4/25/2006 12:03 149.7 12.88 128.3 10.89

4/25/2006 12:04 153.1 12.87 127.2 10.89

4/25/2006 12:05 153.2 12.87 117 10.91

4/25/2006 12:06 153 12.85 124.7 10.88

4/25/2006 12:07 152.9 12.82 144.3 10.93

4/25/2006 12:08 148.6 12.92 130.2 10.88

Page 7 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 12:09 153.2 12.86 110 10.91

4/25/2006 12:10 154.4 12.82 102.9 10.97

4/25/2006 12:11 151.8 12.89 108.9 10.95

4/25/2006 12:12 152.4 12.92 110.6 10.87

4/25/2006 12:13 155.4 12.85 100.5 10.91

4/25/2006 12:14 152.5 12.86 99.4 10.91

4/25/2006 12:15 153.8 12.9 107.9 10.83

4/25/2006 12:16 155.8 12.8 113.4 10.87

4/25/2006 12:17 156 12.83 118.9 10.85

4/25/2006 12:18 155.4 12.83 113.4 10.9

4/25/2006 12:19 154.4 12.86 109.4 10.91

4/25/2006 12:20 154.6 12.88 117.1 10.9

4/25/2006 12:21 156.3 12.86 122.1 10.76

4/25/2006 12:22 159.5 12.66 124.7 10.83

4/25/2006 12:23 158.2 12.7 124.2 10.82

4/25/2006 12:24 159 12.72 118.4 10.85

4/25/2006 12:25 158 12.78 114.3 10.79

4/25/2006 12:26 162.5 12.73 121 10.79

4/25/2006 12:27 161 12.74 124.4 10.77

4/25/2006 12:28 161.5 12.66 136.1 10.82

4/25/2006 12:29 160.8 12.68 133.5 10.84

4/25/2006 12:30 163.6 12.72 130.1 10.92

4/25/2006 12:31 162.5 12.82 131.8 10.94

4/25/2006 12:32 160 12.96 117.4 10.85

4/25/2006 12:33 163.4 12.83 103.2 10.86

4/25/2006 12:34 163.2 12.77 91.3 10.88

4/25/2006 12:35 160.6 12.77 94.3 10.98

4/25/2006 12:36 159.9 12.86 110.8 10.98

4/25/2006 12:37 159.2 12.84 116.7 11.04

4/25/2006 12:38 158.2 12.87 122.2 10.96

4/25/2006 12:39 160.1 12.84 121.6 10.94

4/25/2006 12:40 158 12.84 114.8 10.9

4/25/2006 12:41 160.5 12.77 121.4 10.92

4/25/2006 12:42 156.5 12.77 125.4 10.87

4/25/2006 12:43 160.5 12.77 118.8 10.84

4/25/2006 12:44 159.7 12.72 117.9 10.84

4/25/2006 12:45 158.1 12.75 129 10.92

4/25/2006 12:46 157.3 12.8 134.4 10.89

4/25/2006 12:47 159.9 12.82 135.9 10.85

4/25/2006 12:48 157.6 12.77 125.2 10.89

4/25/2006 12:49 156.3 12.85 132.8 10.84

4/25/2006 12:50 157.6 12.77 136.8 10.8

4/25/2006 12:51 158 12.74 136.5 10.63

Page 8 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 12:52 160.9 12.67 137.4 10.68

4/25/2006 12:53 157.7 12.79 129 10.64

4/25/2006 12:54 158.2 12.82 137.5 10.64

4/25/2006 12:55 155 12.81 144.4 10.66

4/25/2006 12:56 157.6 12.8 142.9 10.69

4/25/2006 12:57 156.1 12.81 113.5 10.63

4/25/2006 12:58 158.3 12.76 105.3 10.6

4/25/2006 12:59 157 12.69 111.3 10.6

4/25/2006 13:00 155.2 12.75 107.1 10.57

4/25/2006 13:01 152.6 12.78 102.8 10.59

4/25/2006 13:02 153.3 12.54 109.7 10.6

4/25/2006 13:03 153.8 12.73 121.2 10.63

4/25/2006 13:04 155.2 12.85 127.1 10.62

4/25/2006 13:05 153.5 12.83 128.6 10.73

4/25/2006 13:06 151.6 12.89 125.9 10.76

4/25/2006 13:07 151.2 12.97 126.8 10.73

4/25/2006 13:08 155 12.94 129.1 10.6

4/25/2006 13:09 157.7 12.78 121.3 10.62

4/25/2006 13:10 155.7 12.8 116.9 10.59

4/25/2006 13:11 156.3 12.79 125.5 10.6

4/25/2006 13:12 155.7 12.77 134.8 10.66

4/25/2006 13:13 153.7 12.85 131.6 10.71

4/25/2006 13:14 154.1 12.92 129.3 10.7

4/25/2006 13:15 154.2 12.91 143.4 10.69

4/25/2006 13:16 154.4 12.9 149.5 10.69

4/25/2006 13:17 153.3 12.92 149.5 10.69

4/25/2006 13:18 155.4 12.93 140.6 10.62

4/25/2006 13:19 160.6 12.87 141.7 10.59

4/25/2006 13:20 158 12.79 145.9 10.67

4/25/2006 13:21 156.9 12.83 138.3 10.65

4/25/2006 13:22 155.6 12.81 137.9 10.66

4/25/2006 13:23 156.6 12.84 119 10.63

4/25/2006 13:24 158.5 12.77 105.1 10.69

4/25/2006 13:25 157.9 12.84 104.2 10.68

4/25/2006 13:26 157.9 12.8 112.6 10.68

4/25/2006 13:27 157.3 12.82 115.9 10.61

4/25/2006 13:28 159.5 12.78 122.3 10.6

4/25/2006 13:29 158.6 12.73 119.8 10.66

4/25/2006 13:30 158.2 12.77 122.1 10.61

4/25/2006 13:31 158.2 12.73 131.8 10.68

4/25/2006 13:32 158.2 12.81 130.4 10.64

4/25/2006 13:33 158.8 12.78 126.2 10.64

4/25/2006 13:34 156.4 12.78 129.3 10.65

Page 9 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 13:35 154.5 12.78 128.8 10.73

4/25/2006 13:36 151.5 12.84 124.2 10.72

4/25/2006 13:37 151.1 12.9 130.2 10.69

4/25/2006 13:38 150.2 12.83 139.9 10.69

4/25/2006 13:39 151.5 12.84 126.5 10.64

4/25/2006 13:40 154.8 12.81 125.8 10.61

4/25/2006 13:41 156.8 12.79 131.7 10.57

4/25/2006 13:42 157.2 12.75 139.3 10.56

4/25/2006 13:43 156.5 12.71 142.3 10.58

4/25/2006 13:44 153.8 12.75 138.3 10.59

4/25/2006 13:45 150.9 12.72 136 10.63

4/25/2006 13:46 151.1 12.76 142.3 10.58

4/25/2006 13:47 153.9 12.68 153.6 10.63

4/25/2006 13:48 153.4 12.71 149.4 10.63

4/25/2006 13:49 152.7 12.76 146.6 10.6

4/25/2006 13:50 153 12.73 145.5 10.65

4/25/2006 13:51 152.9 12.77 148.3 10.63

4/25/2006 13:52 153.1 12.78 146.5 10.64

4/25/2006 13:53 149.4 12.76 144.7 10.61

4/25/2006 13:54 151.9 12.76 131.7 10.65

4/25/2006 13:55 151.5 12.76 127.7 10.67

4/25/2006 13:56 152.5 12.78 118.5 10.57

4/25/2006 13:57 157.9 12.69 112.5 10.49

4/25/2006 13:58 157 12.64 114.8 10.53

4/25/2006 13:59 155.6 12.65 123.6 10.55

4/25/2006 14:00 156.3 12.71 134.4 10.6

4/25/2006 14:01 154.7 12.77 133.4 10.63

4/25/2006 14:02 153.6 12.8 125.2 10.62

4/25/2006 14:03 153.9 12.82 129.4 10.62

4/25/2006 14:04 153.6 12.78 135 10.62

4/25/2006 14:05 153.4 12.72 144.1 10.64

4/25/2006 14:06 149.1 12.8 134.1 10.63

4/25/2006 14:07 153.8 12.76 137.6 10.63

4/25/2006 14:08 151.6 12.76 141.9 10.59

4/25/2006 14:09 153.4 12.76 147.9 10.67

4/25/2006 14:10 148.2 12.81 135.6 10.64

4/25/2006 14:11 150.4 12.85 139.2 10.62

4/25/2006 14:12 148.4 12.81 148.3 10.62

4/25/2006 14:13 149.1 12.8 154.8 10.63

4/25/2006 14:14 148.6 12.83 149.3 10.69

4/25/2006 14:15 147.3 12.85 139.4 10.7

4/25/2006 14:16 147.9 12.88 142.6 10.64

4/25/2006 14:17 152.8 12.79 144.4 10.6

Page 10 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

4/25/2006 14:18 151.2 12.74 142.4 10.57

4/25/2006 14:19 154.5 12.72 137.9 10.49

4/25/2006 14:20 155.3 12.65 137.8 10.49

4/25/2006 14:21 155.3 12.64 134.1 10.53

4/25/2006 14:22 150.1 12.7 146 10.59

4/25/2006 14:23 151.4 12.81 143.1 10.58

Page 11 of 11
 

APPENDIX C 

PARTICULATE LABORATORY ANALYTICAL DATA 
Customer Air Services Plant Big Bend Unit 4

Method 5-B Stack Test Completion Date 4/25/2006Analyst SS Sample Number AA82367

ACETONE BEAKER 1st weighing Date 5/1/2006 Time 10:30 % RH 41.0%

2nd weighing Date 5/2/2006 Time 8:45 % RH 42.0%

3rd weighing Date Time % RH

4th weighing Date Time % RH

***Blank*** Run 1 Run 2 Run 3 Run 1S Run 2S Run 3

Acetone Container ID AIR 12 AIR AZ AIR 104 AIR B2

Acetone Rinse Vol.(Va), mls 150.0000 150 150 150 Enter Container ID Enter Conta

1st Gross Wt., grams 111.4940 106.7933 105.6336 108.4117

2nd Gross Wt., grams 111.4937 106.7930 105.6334 108.4114

3rd Gross Wt., grams

4th Gross Wt., grams

Avg. Gross Wt., grams 111.49385 106.79315 105.63350 108.41155 Enter Gross Wts. Enter Gross Wts. Enter Gros

Tare Wt., grams 111.49310 106.78925 105.62735 108.40945

Acetone Blank Wt., mg 0.75 0.75 0.75 0.75 Enter Tare Wt.

Acetone Particulate Wt., mg 3.15 5.40 1.35

Acetone Residue, mg/g 0.0063

Acetone Blank Criteria OK to subtract acetone blank

 FILTER 1st weighing Date 5/1/2006 Time 10:43 % RH 41.0%

Date 5/2/2006 Time 8:45 % RH 42.0%

3rd weighing Date Time % RH

4th weighing Date Time % RH

Filter/Thimble ID 203029 203023 203022 203024

1st Gross Wt., grams 0.2634 0.2821 0.2779 0.2839

2nd Gross Wt., grams 0.2633 0.2820 0.2776 0.2839

3rd Gross Wt., grams

4th Gross Wt., grams

Avg. Gross Wt., grams 0.26335 0.28205 0.27775 0.28390 Enter Gross Wts. Enter Gross Wts. Enter Gros

Tare Wt., grams 0.26330 0.26930 0.26555 0.27040

Filter Particulate Wt., mg 12.75 12.20 13.50

Difference, milligrams 0.05

Total Sample Particulate Wt., mg 15.90 17.60 14.85

Start Here
APPENDIX D 

BOILER / PRECIPITATOR OPERATION DATA 







APPENDIX E 

FUEL ANALYSIS 
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Report For:

Laboratory ID: AA82367

Date and Time Collected:

Sampled By:

Sample Information

Description: ASG

Location Code:

Report Date: 5/10/2006

Big Bend 4 Compliance

TE_BB_4_COMP_COAL

Project Account Code:

Sample Collection Method: Date of Sample Receipt: 4/26/2006

Laboratory Results

4/25/2006 1:25:00 PM

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

Ash, as Received % 0.01 ASTM D-3174 PJ 8.21 5/3/2006 3:49:00 PM

Ash, Dry Basis % 0.01 ASTM D-3174 PJ 9.27 5/3/2006 3:49:00 PM

BTU, as Received BTU/Lb 100 ASTM D-5865 PJ 11677 5/3/2006 3:49:00 PM

BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 PJ 13180 5/3/2006 3:49:00 PM

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 PJ 14527 5/3/2006 3:49:00 PM

Carbon, as Received % 0.5 ASTM D-5373 PJ 66.55 5/3/2006 3:49:00 PM

Carbon, Dry Basis % 0.5 ASTM D-5373 PJ 75.11 5/3/2006 3:49:00 PM

Chlorine as Cl, as Received % 0.01 ASTM4208/300 SS 0.13 5/10/2006 10:27:00 AM

Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 SS 0.15 5/10/2006 10:27:00 AM

Hydrogen, as Received % 0.14 ASTM D-5373 PJ 4.23 5/3/2006 3:49:00 PM

Hydrogen, Dry Basis % 0.14 ASTM D-5373 PJ 4.77 5/3/2006 3:49:00 PM

Nitrogen, as Determd., by CHN % 0.1 ASTM D-5373 MM 1.41 5/3/2006 8:00:00 AM

Nitrogen, as Received % 0.10 ASTM D-5373 PJ 1.34 5/3/2006 3:49:00 PM

Nitrogen, Dry Basis % 0.10 ASTM D-5373 PJ 1.51 5/3/2006 3:49:00 PM

NOx emission rate, lb/mmBtu lb/mmBtu EPA RM-7E RAM 0.27 5/4/2006 10:39:00 AM

NOx emission rate, lbs/hr lbs/hr EPA RM-7E RAM 1132 5/4/2006 10:39:00 AM

Oxygen, as Received % ASTM D-5373 PJ 5.16 5/3/2006 3:49:00 PM

Oxygen, Dry Basis % Calculated PJ 5.83 5/3/2006 3:49:00 PM

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 3.15 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 5.40 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 1.35 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 12.75 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 12.20 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 13.50 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Total Sample, Run 1 mg 0.0001 15.90 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Total Sample, Run 2 mg 0.0001 17.60 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

Particulate Wt., Total Sample, Run 3 mg 0.0001 14.85 5/4/2006 10:35:00 AM EPA Method 5B/17 RAM

PM, lb/mmBtu lb/mmBtu EPA RM-5/17 RAM 0.01 5/4/2006 10:39:00 AM

Pounds SO2 / Million BTU Lbs. 

SO2/MMBTU

4.85 5/3/2006 3:11:00 PM Calculated PJ

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C RAM 1434 5/4/2006 10:39:00 AM

Report Number: -051006- 12 AA82367 Page 1 of 2

Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicated otherwise in the body of the report.
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

SO2 emission rate, lbs/mmBtu lbs/mmBtu EPA - RM6C RAM 0.34 5/4/2006 10:39:00 AM

Sulfur, as Received % 0.02 ASTM D-4239 PJ 2.98 5/3/2006 3:49:00 PM

Sulfur, Dry Basis % 0.08 ASTM D-4239 PJ 3.36 5/3/2006 3:49:00 PM

Total Moisture % 0.1 ASTM D-3173 PJ 11.4 5/3/2006 3:49:00 PM

Comments

Data Qualifier Codes Explanation:

Robert Dorey,

Manager, Laboratory Services

Subcontracted Laboratories:

All results calculated on a wet to wet basis, unless otherwise indicated.

Report Number: -051006- 12 AA82367 Page 2 of 2

Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicated otherwise in the body of the report.
APPENDIX F 

FIELD DATA SHEETS 




APPENDIX G 

SAMPLING EQUIPMENT CALIBRATIONS 
Environmental Services

Air Services Group

SUMMARY OF EQUIPMENT CALIBRATIONS

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 06) USEPA RM 5

INITIAL 04/18/2006 (ORIFICE) 1.011

POST TEST 05/01/2006 1.008

NOZZLE (SN48)

INITIAL 04/19/2006 CALIPER 0.251

POST TEST 05/04/2006 MEASUREMENTS 0.250

PYROMETER (PY 10) 04/24/2006 ASTM THERMOMETER + 2o

 F

PITOT TUBE (PT 05) 02/22/2006 USEPA RM 2 Cp = 0.84

BAROMETER (BR 07) 04/03/2006 NWS COMPARISON + 0.01" Hg
Environmental Services

Air Services Group

Red Team

Manufacturer: Thermo Anderson Calibration Date:

Model Number:MST-C1 Barometric Pressure: 29.89 "Hg

Instrument Code Number: ^MB06 Theoretical Critical Vacuum: 14.10 "Hg

LabWorks Sample Number: Calibrated By:

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

0.64 15 714.264 721.099 6.835 77 81 77 80

1.15 15 703.291 712.358 9.067 75 80 77 81

1.95 15 737.668 749.422 11.754 78 86 80 87

3.65 15 751.367 767.417 16.050 80 87 81 92

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

48 0.3483 20.0 75 75 75.0

55 0.4660 19.0 75 75 75.0

63 0.5971 17.0 75 75 75.0

73 0.8177 15.5 75 75 75.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.700 6.751 6.851 1.008 -0.003 1.740 -0.025

8.907 9.033 9.165 1.014 0.004 1.748 -0.016

11.473 11.574 11.744 1.009 -0.002 1.790 0.026

15.667 15.850 16.083 1.012 0.001 1.780 0.015

Averages: 1.011 1.764

Review/Approval: 25-Apr-06

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

Quarterly Calibration

4/18/2006

CRD

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

The Critical Orifice Coefficient, K', should be in English units.

IMPORTANT

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

Critical Orifice Readings

Ambient Temperatures

CALCULATED DATA

Critical Orifice
Environmental Services

Air Services Group

Manufacturer: Calibration Date:

Model Number: Barometric Pressure: 30.1 "Hg

Instrument Code Number: MB06 Theoretical Critical Vacuum: 14.20 "Hg

LabWorks Sample Number: Calibrated By:

Associated Test: Team: RED

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

1.2 10 67.812 73.900 6.088 79 75 80 77

1.2 10 73.900 79.980 6.080 80 77 81 77

1.2 10 79.980 86.060 6.080 81 77 81 78

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

55 0.4660 19.0 75 75 75.0

55 0.4660 19.0 75 75 75.0

55 0.4660 19.0 75 75 75.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.029 6.064 6.110 1.006 -0.002 1.813 0.003

6.010 6.064 6.110 1.009 0.001 1.810 -0.001

6.004 6.064 6.110 1.010 0.002 1.808 -0.002

Averages: 1.008 1.810

Prior Y: 1.011

% Difference: 0.27%

Review/Approval: Date:

Big Bend Unit 4 Compliance

IMPORTANT

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

The Critical Orifice Coefficient, K', should be in English units.

Ambient Temperatures

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

Critical Orifice Readings

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

JAV

5/1/2006

POST - TEST CALIBRATION CHECK

2-May-06

CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

Critical Orifice
Environmental Services

Air Services Group

QUARTERLY NOZZLE CALIBRATIONS

Shared Resource

STEEL NOZZLE SET

Calibration Date: 4/19/2006 Responsible Party: CRD

Nozzle Nozzle Diameter, Dn (cm) Maximum Average

I.D. D1 D2 D3 Difference, " Dn, inches

^SN01 0.285 0.290 0.290 0.002 0.114

^SN04 0.320 0.325 0.320 0.002 0.127

^SN05 0.380 0.383 0.383 0.001 0.150

^SN06 0.503 0.505 0.505 0.001 0.199

^SN09 0.698 0.700 0.700 0.001 0.275

^SN10 0.760 0.755 0.758 0.002 0.298

^SN12 0.986 0.985 0.988 0.001 0.388

^SN15 0.422 0.420 0.424 0.002 0.166

^SN16 0.504 0.502 0.504 0.001 0.198

^SN19 0.714 0.710 0.710 0.002 0.280

^SN22 0.933 0.935 0.938 0.002 0.368

^SN30 0.798 0.793 0.795 0.002 0.313

^SN36 0.482 0.480 0.480 0.001 0.189

^SN37 0.530 0.534 0.538 0.003 0.210

^SN38 0.640 0.630 0.640 0.004 0.251

^SN46 0.482 0.482 0.485 0.001 0.190

^SN47 0.520 0.518 0.518 0.001 0.204

^SN48 0.640 0.635 0.640 0.002 0.251

^SN50 0.792 0.790 0.790 0.001 0.311

^SN58 0.620 0.620 0.620 0.000 0.244

^SN68 0.630 0.630 0.635 0.002 0.249

^SN69 0.950 0.950 0.950 0.000 0.374

^SN70 1.560 1.560 1.560 0.000 0.614

^SN71 1.560 1.560 1.560 0.000 0.614

^SN72 0.955 0.955 0.955 0.000 0.376

^SN73 1.280 1.280 1.285 0.002 0.505

^SN74 1.245 1.245 1.245 0.000 0.490

Data Notations: All micometer readings are converted from cm to inches by multiplying by

0.393700787. Maximum Difference must be < 0.004".

QA/QC Review by: 25-Apr-06
Environmental Services

Air Services Group

POST TEST NOZZLE CALIBRATION 

Shared Resource

Calibration Date: 5/4/2005

Calibration Personnel: Charles Dufeny

Test Designation: Big Bend 4

Nozzle Nozzle Diameter, Dn (cm) Maximum Average

Identifier D1 D2 D3 Difference, " Dn, inches

SN48 0.635 0.635 0.635 0.000 0.250

Data Notations: All micometer readings are converted from cm to inches by multiplying by

0.393700787. Maximum Difference must be < 0.004".

Quarterly (pre-test) value for nozzle ID SN48 was 0.251

Difference (Pre-test/Post-test) is: 0.001

QA/QC Review by: 4-May-06
Environmental Services

Air Services Group

Pyrometer Calibration

Red Team

Pyrometer Under Test

Pyrometer Number: ^PY10

Labworks Sample # N/A

Calibration Date: 4/24/2006

Calibrator Information

Calibrator Type/Manufacturer: Hart Scientific

Calibrator Serial Number: AOA024

Date of Last Calibration: 10/6/2005

Calibration Personnel (Typed and Signature): Jorge A Varino

Calibration Data

Calibration Reference Pyrometer

Point Temperature Indication Difference

1 400 402 -2

2 212 211 1

3 32 34 -2

Reference temperatures must encompass the expected range of measurement. These three points

should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit.

Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration

Point Difference

1 Pass

2 Pass

3 Pass

Reviewer: Date: 2-May-06
Environmental Services

Air Services Group

_ _

s

PITOT TUBE CALIBRATION

DATA SHEET

Pitot Tube ID # PT05

Calibration Date 2/22/2006 Operating Quarter/Year: 1/06 Red Team

Openings Damaged? ___ Y __ N Repaired? ___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 1.1 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 1.3 degrees Pass α < 10 degrees

β 1 0.1 degrees Pass (α1 measured across top impact openings)

β 2 0.2 degrees Pass (α2 measured across bottom impact openings)

β1 < 5 degrees (alongside top impact openings)

Gamma, Theta, Α, Ζ, and W Determination β2 < 5 degrees (alongside bottom impact openings)

ψ 0.6 degrees Ζ < 0.32 cm (Αsinψ)

Α 2.28 cm W < 0.08 cm (Asinο)

Ζ 0.024 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.8 degrees ψ angle between tips

W 0.032 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, 

Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement

details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems:

Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by: Charles Dufeny

Quality Assurance Review / Approval: 24-Feb-06
Environmental Services

Air Services Group

BAROMETER CALIBRATION

Blue Team

Instrument Number: ^BR07

Calibration Date: 4/3/2006

Calibration Personnel: JAV

Labworks #:

Barometer Reading Reference Reading Difference

Time Inches Mercury Inches Mercury "Hg

8:25 30.13 30.10 0.03

9:30 30.14 30.12 0.02

10:30 30.14 30.11 0.03

Average Difference: 0.03

Note: Barometric readings must agree within ± 0.1 "Hg.

Current Reference is National Weather Service, TIA.

Current Conditions at Tampa International Airport

Comments (Note any adjustments):

QA/QC Review by: Date: 3-Apr-06
APPENDIX H 

CHAIN OF CUSTODY 


 

APPENDIX I

TEST PARTICIPANTS 
TEST PARTICIPANTS

AIR SERVICES GROUP 

ENVIRONMENTAL SERVICES

Charles Dufeny Environmental Technician 

Juan Ramirez Environmental Technician 

Jorge Varino Technician 

BIG BEND STATION

Karen Zwolak Senior Environmental Consultant