## 1750 East Club Boulevard Durham, NC 27704 Phone: (919) 220-2570 Fax: (919) 220-4540 

# Certificate of Analysis Customer: Enthalpy Analytical, Inc. . Cylinder Number: CC157718 2202 Ellis Road, Suite A Cylinder Si ze/CGA: AL150/350 Durham, NC 27703-5518 Fill Pressure: 2000 PSIA Gas Volume: 3700 liters Tel: (919) 850-4392 Date of Mfg: 6/18/09 Expiration Date: 6/18/10

Customer Number Ship VIA Job No. Customer PO Mixture Type

00127703NC Pick up 061809-002 CMD052809JCB Gravimetric

Component Nominal Concentration Actual Concentration* Mixture Type
Acetaldehyde 250 ppm 250 ppm +/- 5 ppm Gravimetric Master Gas Nitrogen balance balance

NOTES: Blend Tolerance: +/-2% Analytical Tolerance: +/-2% Traceability: NIST by weight set / Internal Standards by analysis Reactive Mixtures: Analyzed twice with required agr eement between analyses of 2%. Required wait time between analyses of >7 days. Caution: Do not use below 150 PSIG.

Authorized Signature:
Joseph A. Ernst
*Every effort has been made to establish the actua l concentration of the components using master gas blending technology however, Custom Gas Solutions shall have no liability in excess of the established charge for this material.

## 1750 East Club Boulevard Durham, NC 27704 Phone: (919) 220-2570 Fax: (919) 220-4540 

# Certificate of Analysis Customer: Enthalpy Analytical, Inc. . Cylinder Number 2777164Y 2202 Ellis Road, Suite A Cylinder Si ze/CGA: ST300/350 Durham, NC 27703-5518 Fill Pressure: 450 PSIA Gas Volume: 1500 liters Tel: (919) 850-4392 Date of Mfg: 2/10/09 Expiration Date: 2/10/11

Customer Number Ship VIA Job No. Customer PO Mixture Type 00127703NC Pick up 021009-010 CMD012709DMB JCB Gravimetric

Component Nominal Concentration Actual Concentration* Mixture Type

n-Heptane 500 ppm 500.4 ppm +/- 10 ppm Gravimetric Master Gas n-Hexane 1000 ppm 998 ppm +/- 20 ppm n-Pentane 2000 ppm 2004 ppm +/- 40 ppm n-Butane 1% 1.02% +/- 0.02% Propane 5% 5.00% +/- 0.10% Ethane 5% 5.02% +/- 0.10% Nitrogen Balance Balance

NOTES: Blend Tolerance: +/-2% Analytical Tolerance: +/-2%

Authorized Signature: Stephen Vaughan (electronic)
Stephen Vaughan, PhD
*Every effort has been made to establish the actua l concentration of the components using master gas blending technology however, Custom Gas Solutions shall have no liability in excess of the established charge for this material.

# This Is The Last Page Of This Report.

# Civil and Environmental Consultants, Inc.
4848 Park 370 Blvd, Suite F Hazelwood, MO 63042 

# KCP&L ICR Testing - La Cygne Station Client # 100-208-0004 

# Analytical Report (0410-11) EPA Method 26A Hydrogen Chloride, Hydrogen Fluoride 

# EPA CTM 33 Hydrogen Cyanide 

# EPA OTM 27
Particulate Matter 

# EPA OTM 28
Condensible Particulate Matter 

# HPLC Analysis
Sulfate 

# Enthalpy Analytical, Inc.
Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 2202 Ellis Road Durham, NC 27703 - 5518

### I certify that to the best of my knowledge a ll analytical data presented in this report:

 Have been checked for completeness

 Are accurate, error-free, and legible

 Have been conducted in accordance with approved prot ocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s)
This analytical report was prepared in Portable Document Format (.PDF) and contains ??? pages.

# Summary of Results

## Compound Sample ID / Catch Weight (ug)

Run 1 C3 Run 2 C3 Run 3 C3 Hydrogen Fluoride 3,012 J 2,805 J 4,135 J Hydrogen Chloride 2,794 J 3,461 J 2,899 J

BT C3 H2SO4 0.01N H2SO4/NaOH M MS Run 1 C3 Hydrogen Fluoride 100 ND 0 ND 37 Hydrogen Chloride 97.9 ND 0 ND 33 Company

Analyst Parameters # Samples Civil & Environ. Consult. EO EPA Method 26A 3 Runs, 1 Blank Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/10/2010

0410-11 res m26a 6/10/2010

## Compound Sample ID / Catch Weight (ug)

CTM033-C3 A-C & C5 Run 1 Run 2 Run 3 Hydrogen Cyanide 61.0 ND 56.7 ND 56.6 ND

BT Hydrogen Cyanide 47.2 ND Company

Analyst Parameters # Samples Civil & Environ. Consultants ARM EPA CTM-033, Pb Ace. & NaOH 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/29/2010

0410-11 res ctm33 6/29/2010

## Compound Sample ID / Catch Weight (mg)

Run 1 Run 2 Run 3 47 mm Filter 12.5 11.2 8.0 >2.5 PM 6.9 3.1 2.9 < 2.5 PM 1.8 0.8 2.0

TOTAL 21.2 15.0 12.9

Blank Train #REF! #REF! 47 mm Filter 0.4 11.17 8.01 >2.5 PM 0.3 3.08 2.88 < 2.5 PM 0.3 0.77 2.02

TOTAL 1.1 15.02 12.91 Company

Analyst Parameters # Samples Civil & Environ. Consult. KTH EPA OTM 27 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/9/2010

## Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Run 1 Run 2 Run 3 Net Organic Catch 4.4 3.9 3.3 Corrected Inorganic 14.6 16.0 17.0 TB Corrected CPM 17.0 17.8 18.4

Train Blank Organic Catch 2.1 If Train Blank Corrected CPM is >2.0 mg, Inorganic Catch 1.1 then sample correction is 2.0 mg. CPM 3.2 Company

Analyst Parameters # Samples Civil & Environ. Consult. KTH EPA OTM 28 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/9/2010

0410-11 res OTM-028 6/10/2010

## Compound Sample ID / Catch Weight (ug)

OTM 28 Inorganic Fraction Run 1 Post Run 2 Post Run 3 Post Sulfate 2,477 2,925 2,694

Train Blank Post In House Blank Pos t MB/ DI H2O Sulfate 25.8 6 J 0.1 ND Company

Analyst Parameters # Samples Civil & Environ. Consult. ARM HPLC/IC Analysis 3 Runs, 1 Blank Client # Job # PO # Report Date 100-208-0004 0410-11 110-208 6/10/2010

0410-11 res so4 6/10/2010

# ResultsMDL 0.0200 (ug/mL) Lower Curve Limit 1.00 (ug/mL)LOQ 1.00 (ug/mL) Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidConversionFactorDFVol(mL)CatchWeight(ug)QualRun 1 C3 015-1701.D 015-1702.D HPLC51PG128.M 3.03 3.03 0.0 0.227 0.209 4.2 0.218 1.053 20 655 3,012 JRun 2 C3 018-2201.D 018-2202.D HPLC51PG128.M 3.04 3.04 0.0 0.212 0.210 0.5 0.211 1.053 20 630 2,805 JRun 3 C3 019-2301.D 019-2302.D HPLC51PG128.M 3.04 3.04 0.1 0.294 0.267 4.7 0.281 1.053 20 700 4,135 JBT C3 H2SO4 Blank 020-2401.D 020-2402.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 238 100 ND0.01N H2SO4/NaOH MB 007-0901.D 007-0902.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 1 1.00 0.0211 NDMS Run 1 C3 016-2001.D 016-2002.D HPLC51PG128.M 3.04 3.04 0.0 3.47 3.49 0.2 3.48 1.053 1 10.0 36.6Spike Amount (ug) 31.6Native Amount (ug) 2.30Spike Recovery (%) 109%MSD Run 1 C3 017-2101.D 017-2102.D HPLC51PG128.M 3.04 3.04 0.0 3.43 3.46 0.5 3.44 1.053 1 10.0 36.3Spike Amount (ug) 31.6Native Amount (ug) 2.30Spike Recovery (%) 107%HPLC51pg110 #LCS 006-0801.D 006-0802.D HPLC51PG128.M 3.04 3.04 0.0 4.27 4.31 0.5 4.29 1.053 1 1.00 4.52Spike Amount (ug) 4.21Spike Recovery (%) 107%Hydrogen Fluoride as FluorideCompanyAnalystParameters# SamplesCivil & Environmental ConsultantsEOEPA Method 26A3 Runs, 1 BlankClient #Job #PO #Report Date100-208-00040410-11100-2086/10/20100410-11 res m26a6/10/2010MDL 0.0200 (ug/mL) Lower Curve Limit 1.00 (ug/mL)LOQ 1.00 (ug/mL) Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidConversionFactorDFVol(mL)CatchWeight(ug)QualRun 1 C3 015-1701.D 015-1702.D HPLC51PG128.M 4.07 4.07 0.1 0.207 0.208 0.0 0.207 1.028 20 655 2,794 JRun 2 C3 018-2201.D 018-2202.D HPLC51PG128.M 4.08 4.09 0.1 0.268 0.267 0.1 0.267 1.028 20 630 3,461 JRun 3 C3 019-2301.D 019-2302.D HPLC51PG128.M 4.09 4.09 0.0 0.201 0.201 0.0 0.201 1.028 20 700 2,899 JBT C3 H2SO4 Blank 020-2401.D 020-2402.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 238 97.9 ND0.01N H2SO4/NaOH MB 007-0901.D 007-0902.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 1 1.00 0.0206 NDMS Run 1 C3 016-2001.D 016-2002.D HPLC51PG128.M 4.07 4.07 0.0 3.24 3.24 0.1 3.24 1.028 1 10.0 33.3Spike Amount (ug) 30.8Native Amount (ug) 2.13Spike Recovery (%) 101%MSD Run 1 C3 017-2101.D 017-2102.D HPLC51PG128.M 4.08 4.08 0.0 3.22 3.23 0.1 3.22 1.028 1 10.0 33.1Spike Amount (ug) 30.8Native Amount (ug) 2.13Spike Recovery (%) 100%HPLC51pg110 #LCS 006-0801.D 006-0802.D HPLC51PG128.M 4.07 4.07 0.0 3.96 3.97 0.1 3.96 1.028 1 1.00 4.07Spike Amount (ug) 4.11Spike Recovery (%) 99.0%Hydrogen Chloride as ChlorideCompanyAnalystParameters# SamplesCivil & Environmental ConsultantsEOEPA Method 26A3 Runs, 1 BlankClient #Job #PO #Report Date100-208-00040410-11100-2086/10/20100410-11 res m26a6/10/2010

### MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL) LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL) Compound

Sample ID Lab ID Analysis Method Ret Time (min) Conc (ug/mL) DF Vol (mL) Catch Weight

(ug) Qual

CTM033-R1-C3A-C 010-1101.D 1000.M NA 0.0143 5 853 61.0 ND

CTM033-R1-C5 011-1201.D 1000.M NA 0.0143 5 156 11.2 ND 61.0 ND

CTM033-R2-C3A-C 012-1301.D 1000.M NA 0.0143 5 793 56.7 ND

CTM033-R2-C5 013-1401.D 1000.M NA 0.0143 5 248 17.7 ND 56.7 ND

CTM033-R3-C3A-C 014-1501.D 1000.M NA 0.0143 5 792 56.6 ND

CTM033-R3-C5 015-1601.D 1000.M NA 0.0143 5 233 16.7 ND 56.6 ND

CTM033-BT-C3A-C 016-1701.D 1000.M NA 0.0143 5 661 47.2 ND

CTM033-BT-C5 017-1801.D 1000.M NA 0.0143 5 155 11.1 ND 47.2 ND

0.1N NaOH - RB 007-0801.D 1000.M NA 0.0143 1 1.00 0.0143 ND 0.1N NaOH - RB 007-0802.D 1000.M NA 0.0143 1 1.00 0.0143 ND

Hplc50pg128 #LCS 008-0901.D 1000.M 7.98 1.12 1 0.525 0.588 Hplc50pg128 #LCS 008-0902.D 1000.M 7.99 1.13 1 0.525 0.595 0.591 Spike Amount (ug) 0.520 Spike Recovery (%) 114%

MS/CTM033-R1-C3A-C 018-1901.D 1000.M 8.00 1.13 1 0.525 0.596 Spike Amount (ug) 0.520 Native Amount (ug) 0.00 Spike Recovery (%) 115% Hydrogen Cyanide Company

Analyst Parameters # Samples Civil & Environ. Consultants ARM EPA CTM-033, Pb Ace. & NaOH 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/29/2010

0410-11 res ctm33 7/2/2010

### MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL) LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL) Compound

Sample ID Lab ID Analysis Method Ret Time (min) Conc (ug/mL) DF Vol (mL) Catch Weight

(ug) Qual Hydrogen Cyanide Company

Analyst Parameters # Samples Civil & Environ. Consultants ARM EPA CTM-033, Pb Ace. & NaOH 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/29/2010

MSD/CTM033-R1-C3A-C 019-2201.D 1000.M 8.02 1.16 1 0.525 0.610 Spike Amount (ug) 0.520 Native Amount (ug) 0.00 Spike Recovery (%) 117%

LD/CTM033-R1-C3A-C 020-2301.D 1000.M NA 0.0143 5 853 61.0 ND % Difference NA

0410-11 res ctm33 7/2/2010

### Other Test Method 027 (OTM-027) - Particulate Determination - Data Analysis

Analysis of Particulate Recovery

Sample ID Run 1 Run 2 Run 3 Blank Train

47 mm Filter ID 2441 Dates 2436 Dates 2437 Dates 2439 Dates Final wt. (g) 1st 0.12478 5/29/10 0.12410 5/29/10 0.12066 5/29/10 0.11326 5/29/10 Final wt. (g) 2nd 0.12470 5/31/10 0.12403 5/31/10 0.12060 5/31/10 0.11325 5/31/10 Final Tare Weight (g) 0.11216 5/28/10 0.11287 5/28/10 0.11259 5/28/10 0.11283 5/28/10

Net filter catch (mg) 12.5 11.2 8.0 0.4

>2.5 PM Acetone Rinses Beaker number 3960 Dates 3961 Dates 3962 Dates 3963 Dates Final wt (g) 1st 1.90795 6/7/10 1.93430 6/7/10 1.92991 6/7/10 1.89520 6/7/10 Final wt (g) 2nd 1.90780 6/8/10 1.93406 6/8/10 1.92965 6/8/10 1.89514 6/8/10 Beaker tare (g) 1.90092 5/28/10 1.93098 5/28/10 1.92677 5/28/10 1.89484 5/28/10 Acetone vol (mL) 36 25 21 41 >2.5 PM Catch (mg) 6.9 3.1 2.9 0.3

<2.5 PM Acetone Rinses Beaker number 3956 Dates 3957 Dates 3958 Dates 3959 Dates Final wt (g) 1st 1.92339 6/7/10 1.93062 6/7/10 1.94344 6/7/10 1.94628 6/7/10 Final wt (g) 2nd 1.92328 6/8/10 1.93041 6/8/10 1.94325 6/8/10 1.94610 6/8/10 Beaker tare (g) 1.92153 5/28/10 1.92964 5/28/10 1.94123 5/28/10 1.94575 5/28/10 Acetone vol (mL) 39 37 36 35 <2.5 PM Catch (mg) 1.8 0.8 2.0 0.3
Total particulate (mg) 21.2 15.0 12.9 1.1



### In-House Blank Acetone Analysis Blank beaker number 3914 Dates

Blank volume (mL) 200 Dates Final wt (g) 1st 1.89916 6/7/10 Beaker tare (g) 1.89890 5/27/10 Final wt (g) 2nd 1.89917 6/8/10 Max acetone residue (g) 0.0016 Acetone residue (g) 0.0003 Company

Analyst Parameters # Samples Civil & Environmental Consultants KTH EPA OTM 27 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/9/10Analysis of Condensible Particulate RecoverySample ID Number Train Blank Run 1 Run 2 Run 3OrganicBeaker Number3912 3909 3910 3911Initial MeCl2/Acetone Volume, mL 134 172 178 170Lab MeCl2 Volume, mL 165 Dates 165 Dates 165 Dates 165 DatesFinal Weight, g 1.8959 6/7/10 1.8936 6/7/10 1.8791 6/7/10 1.8865 6/7/10Reweigh, Final, g 1.8960 6/8/10 1.8937 6/8/10 1.8792 6/8/10 1.8866 6/8/10Beaker Tare, g 1.8939 5/27/10 1.8893 5/27/10 1.8753 5/27/10 1.8832 5/27/10Net Organic Catch, mg 2.1 4.4 3.9 3.3InorganicBeaker Number4089Dates4086Dates4087Dates4088DatesFinal Weight, g 1.8946 6/7/10 1.9528 6/7/10 1.9487 6/7/10 1.9548 6/7/10Reweigh, Final, g 1.8945 6/8/10 1.9525 6/8/10 1.9484 6/8/10 1.9544 6/8/10Beaker Tare, g 1.8935 6/1/10 1.9337 6/1/10 1.9280 6/1/10 1.9329 6/1/10H2O FV, mL 140 324 412 356Resuspended Volume, mL 100.0 100.0 100.0 100.0Removed Pre-aliquot, mL 0.5 0.5 0.5 0.5Pre-aliquot CF 1.00 1.00 1.00 1.00Removed Post-aliquot, mL 0.5 0.5 0.5 0.5Post-aliquot CF 1.01 1.01 1.01 1.01Net Inorganic, mg 1.1 19.0 20.6 21.7Ammonium Correction, mg 0.0 4.4 4.6 4.7Corrected Inorganic, mg 1.1 14.6 16.0 17.0Condensible Particulate Matter, mg 3.2 19.0 19.8 20.4TB Corrected CPM, mg 17.0 17.8 18.4----------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------Type Blank MeCl Blank Type Blank H2O Blank Type Blank AcetoneBeaker Number3913Dates Beaker Number4090Dates Beaker Number3914DatesTare weight, g 1.8990 5/27/10 Tare weight, g 1.8880 6/1/10 Tare weight, g 1.8989 5/27/10Dry Residue Weight, g 1.9020 6/7/10 Dry Residue Weight, g 1.8887 6/7/10 Dry Residue Weight, g 1.8992 6/7/10Reweigh, Final, g 1.9021 6/8/10 Reweigh, Final, g 1.8887 6/8/10 Reweigh, Final, g 1.8992 6/8/10MeCl2 Residue, g 0.0032 Water Residue, g 0.0007 Acetone Residue, g 0.0003MeCl2 Volume, mL 225 Water Volume, mL 250 Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045 Max. Water Residue, g 0.0025 Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesCivil & Environmental ConsultantsKTHEPA OTM-0283 Runs, 1 Blank TrainClient #Job #PO #Report Date100-208-00040410-11100-2086/9/2010MDL 0.09 (mg Ammonium) MDL 0.26 (mg Sulfate) Blank titrant amount (Vtb) 0.03 [Set this equal to the In-House Blank Titration Volume and then white out this note] NH4OH normality 0.1 Lot # Sigma Aldrich 318620

Sample ID. Volume Resuspended (mL) Titration Aliquot Vol (mL) Aliquot Factor (mL rec'd/aliq mL)

Train Blank 100 99.5 0.05 ND 1.01 0.26 ND 0.09 ND Run 1 100 99.5 2.60 1.01 12.41 4.40 Run 2 100 99.5 2.72 1.01 12.99 4.60 Run 3 100 99.5 2.76 1.01 13.18 4.67 In House 100 99.5 0.03 ND 1.01 0.26 ND 0.09 ND SO4 Catch (mg) NH 4 OH Titration Vol (mL) Ammonium equivalent (mg) Company

Analyst Parameters # Samples Civil & Environmental Consultants KTH EPA OTM-028 3 Runs, 1 Blank Train Client # Job # PO # Report Date 100-208-0004 0410-11 100-208 6/9/2010MDL 0.0605 (ug/mL) Lower Curve Limit 0.500 (ug/mL)LOQ 0.500 (ug/mL) Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualRun 1 Post 021-1501.D 021-1502.D HPLC49PG26.M 10.08 10.08 0.0 6.19 6.20 0.0 6.19 20 20.0 2,477Run 2 Post 024-1801.D 024-1802.D HPLC49PG26.M 10.08 10.08 0.0 7.70 6.93 5.3 7.31 20 20.0 2,925Run 3 Post 025-1901.D 025-1902.D HPLC49PG26.M 10.08 10.07 0.0 6.72 6.76 0.3 6.74 20 20.0 2,694Train Blank Post 026-2201.D 026-2202.D HPLC49PG26.M 10.07 10.06 0.0 1.32 1.26 2.2 1.29 1 20.0 25.8In House Blank Post 027-2301.D 027-2302.D HPLC49PG26.M 10.09 10.09 0.0 0.310 0.315 0.7 0.313 1 20.0 6.25 JMB/ DI H2O 007-0901.D 007-0902.D HPLC49PG26.M NA NA NA 0.0605 0.0605 0.0 0.0605 1 1.00 0.0605 NDhplc49pg22 #LCS 006-0801.D 006-0802.D HPLC49PG26.M 10.05 10.05 0.0 5.04 5.08 0.4 5.06 1 1.00 5.06Spike Amount (ug) 5.00Spike Recovery (%) 101%MS Run 1 Post 022-1601.D 022-1602.D HPLC49PG26.M 10.08 10.08 0.1 9.44 9.44 0.0 9.44 1 0.800 7.56Spike Amount (ug) 2.50Native Amount (ug) 4.95Spike Recovery (%) 104%MSD Run 1 Post 023-1701.D 023-1702.D HPLC49PG26.M 10.08 10.07 0.1 9.43 9.42 0.0 9.42 1 0.800 7.54Spike Amount (ug) 2.50Native Amount (ug) 4.95Spike Recovery (%) 103%SulfateCompanyAnalystParameters# SamplesCivil & Environmental ConsultantsARMHPLC/IC Analysis3 Runs, 1 BlankClient #Job #PO #Report Date100-208-00040410-11110-2086/10/20100410-11 res so46/10/2010

# Narrative Summary

# Enthalpy Analytical Narrative Summary

Company 

## Civil and Environmental Consultants, Inc. Client # 

## 100-208-0004

Analyst 

## EO Job # 

## 0410-11 Parameters 

## EPA Method 26A PO # 

## 100-208

# Samples 

## 3 Runs, 1 Blank Report Date 

## June 10, 2010
Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished by Civil and Environmental Consultants, Inc. The samples were received at 24.3  C in good condition. The samples were received in glass containers. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. Analysis The samples were analyzed for hydrogen chloride (HCl) and hydrogen fluoride (HF) using the analytical procedures in EPA Method 26A, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Me thod (40 CFR Part 60, Appendix A). The samples were analyzed following the procedures in Section 11.0, Analytical Procedures. All samples and standards are prepared, stored, and analyzed using high-density polyethylene containers. The Metrohm 861 Compact IC "Smithers" (S/N 1861002007189) was equipped with a Metrohm 861 Conductivity Detector and a Metrosep A Supp 5 - 110/4.0mm column (S/N # 7908289), for these analyses. Calibration The calibration curve is included in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page. The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. Chromatographic Conditions A copy of the acquisition method Metrohm.M is included in the Calibration Curve Chromatograms section of this report. QC Notes The analysis of the blank received with these samples contained no target compounds at concentrations greater than the MDL. The analysis of the laboratory reagent blank contained no target compounds at concentrations greater than the MDL.

# Enthalpy Analytical Narrative Summary (continued)
QC Notes (continued) The analysis of the LCS exhibited a recovery value of 107% for hydrogen fluoride and 99.0% for hydrogen chloride. The analyses of the duplicate matrix spikes prepared using sample Run 1 C3 exhibited recovery values within 10% of the expected values. All samples were analyzed within the four-week holding time specified in the method. Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.
The H 2 

## SO 4 

## matrix samples were analyzed for Cl - 

## and F - 

## but are reported as HCl and HF. The results were converted using an acid conversion factor of 1.028 for HCl and 1.053 for HF. Enthalpy Analytical, Inc. is accredited to perform EPA Method 26A for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company 

## Civil and Environmental Consultants, Inc. Client # 

## 100-208-0004

Analyst 

## ARM Job # 

## 0410-11 Parameters 

## EPA CTM-033 PO # 

## 100-208

# Samples 

## 3 Runs, 1 Blank Train Report Date 

## June 29, 2010
Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished by Civil and Environmental Consultants, Inc. The samples were received at 24.3  C in good condition. The pH of the sodium hydroxide fractions was 12 or greater; the pH of the lead acetate fractions was 4 or 5. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for hydrogen cyanide (HCN) using the analytical procedures in EPA Conditional Test Method 033, Sampling and Analysis for Hydrogen Cyanide Emissions from Stationary Sources. Proportional aliquots were taken from the three sodium hydroxide containers received for each run and combined for a single analysis. The DIONEX Model 500, High Performance Liquid Chromatograph ("Grandmama") was equipped with a Dionex ED40 Electrochemical Detector and a Dionex Ion Pac AS7, 4 x 250 mm column (S/N 012759), for these analyses. Calibration As required by the method, a calibration verification standard was analyzed after every 10 samples. The acceptance criterion for the calibration verification standard is ± 10% of the expected value as quantified using the calibration curve. The calibration verification standards analyzed with these samples were outside the control limit at 113% and 116%. Further analyses were not performed because the sample holding time had expired.
The calibration curve is included in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page. The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound.

# Enthalpy Analytical Narrative Summary (continued)
Chromatographic Conditions A copy of the acquisition method 1000.M is included in the Calibration Curve Chromatograms section of this report.
QC Notes The analysis of the blank received with the samples contained no hydrogen cyanide at a concentration greater that the MDL.
The analysis of the laboratory reagent blank contained no hydrogen cyanide at a concentration greater than the MDL.
The analysis of the LCS prepared with these samples exhibited a recovery value of 114%. The analyses of the duplicate matrix spikes prepared using sample R1- C3A-C exhibited recovery values of 115% and 117%. The recovery value for the MSD was slightly outside the control limit of 115%. A Laboratory Duplicate (LD) analysis was performed using sample R1- C3A-C . The results of the duplicate analysis did not differ from the results of the original analysis. Due to instrument problems which caused significant sample back log, these samples were analyzed 5 days outside the 30-day holding time specifed by the method.
Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.
Enthalpy Analytical, Inc. is accredited to perform EPA CTM-033 for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company 

## Civil and Environmental Consultants, Inc. Client # 

## 100-208-0004

Analyst 

## KTH Job # 

## 0410-11 Parameters 

## EPA OTM 27 PO # 

## 100-208

# Samples 

## 3 Runs, 1 Blank Train Report Date 

## June 10, 2010
Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished by Civil and Environmental Consultants, Inc. The samples were received at 24.3  C in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for particulate matter using EPA Other Test Method (OTM) 27, Determination of PM 10 

## and PM 2.5 

## Emissions from Stationary Sources (Constant Sampling Rate Procedures). The filters were placed in a dessicator for 24 hours. The filters were weighed at minimum 6-hour intervals until constant weights were achieved.
The volumes of the acetone rinses were measured and recorded. The acetone rinses were transferred to tare weighed aluminum weighing pans and evaporated using nitrogen in a vented chamber. The residues were placed in a dessicator for 24 hours. The residues were weighed at minimum 6-hour intervals until constant weights were achieved. Samples were weighed on a Sartorius Model ME 5-F balance (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010.
QC Notes No adjustments to the results were made for the Train Blank.
Reporting Notes Gravimetric analyses are considered accurate to ±0.5 mg. Therefore, negative catch weights between 0 and –0.5 mg are set to zero and no investigation is undertaken. Negative catch weights less than -0.5 mg are investigated. The results presented in this report are representative of the samples as provided to the laboratory.

# Enthalpy Analytical Narrative Summary

Company 

## Civil and Environmental Consultants, Inc. Client # 

## 100-208-0004

Analyst 

## KTH Job # 

## 0410-11 Parameters 

## EPA OTM 28 PO # 

## 100-208

# Samples 

## 3 Runs, 1 Blank Train Report Date 

## June 10, 2010
Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished by Civil and Environmental Consultants, Inc. The samples were received at 24.3  C in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for Particulate Matter using the analytical procedures in EPA Other Test Method (OTM) 28, Dry Impinger Method for Determining Condensable Particulate Emissions from Stationary Sources. Samples were weighed on a Sartorius Model ME 5-F balance (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010.
QC Notes The method specifies blank corrections are accomplished by subtracting the particulate mass determined in the ‘Field Train Blank’ or 2 mg (whichever is less) from the sample weight. Since the blank value is greater than 2.0 mg, 2.0 mg was used to correct the catch weights. The inorganic results for the samples were corrected for the ammonium ions used to precipitate the sulfate, per the formula in the Method (Section 12.2.1).
Reporting Notes Gravimetric analyses are considered accurate to ±0.5 mg. Therefore, negative catch weights between 0 and –0.5 mg are set to zero and no investigation is undertaken. Negative catch weights less than -0.5 mg are investigated. The results presented in this report are representative of the samples as provided to the laboratory.

# Enthalpy Analytical Narrative Summary

Company 

## Civil and Environmental Consultants, Inc. Client # 

## 100-208-0004

Analyst 

## ARM Job # 

## 0410-11 Parameters 

## HPLC Analysis PO # 

## 100-208

# Samples 

## 3 Runs, 1 Blank Report Date 

## June 10, 2010
Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished by Civil and Environmental Consultants, Inc. The samples were received at 24.3  C in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. Analysis The samples were analyzed for sulfate (SO 4 

## ) using the Agilent Model 1100, High Performance Liquid Chromatograph (HPLC) "Gonzo" equipped with a Dionex ED40 Electrochemical Detector and a Dionex Ion Pac AS14A, 4 x 250 mm column (S/N 006972). After final weights were taken, the OTM 28 inorganic fractions were resuspended in 20mL of DI water for the sulfate analysis. Calibration The calibration curve is included in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page. The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. Chromatographic Conditions A copy of the acquisition method Anions.M is included in the Calibration Curve Chromatograms section of this report. QC Notes The analysis of the blank received with these samples contained sulfate at a concentration within the calibration range. The analysis of the laboratory reagent blank contained no sulfate at a concentration greater than the LOQ. The analysis of the LCS exhibited a recovery value of 101%. The analyses of the duplicate matrix spikes prepared using sample Run 1 Post exhibited recovery values of 104% and 103%. Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.

# General Reporting Notes

The following are general reporting notes that are a pplicable to all Enthalpy Analytical, Inc. data reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.

 The acronym ND following a value indicates a non-detect or analytical result below the MDL.

 The letter J following a value indicates an analytical r esult between the MDL and the LOQ. A J flag indicates that the laboratory can positively identify th e analyte of interest as present, but the value should be considered an estimate.

 The letter E following a value indicates an analytical r esult exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analyti cal result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results.

 The addition of MS to the Sample ID represents a Matrix Sp ike. An aliquot of an actual sample is spiked with a known amount of analyte so that a per cent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s).

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.

 The addition of LD to the Sample ID represents a Laborat ory Duplicate. The analyst prepares an additional aliquot of sample for testing and the resu lts of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).

 The addition of AD to the Sample ID represents an Alte rnate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usu ally double the initial factor). This analysis helps confirm that no additional compound is present and coel uting or sharing absorbance with the analyte of interest, as they would have a different res ponse/absorbance than the analyte of interest.

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laborator y using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. The extras (randomly chosen) are labeled with the asso ciated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection and/or sample transport.

# General Reporting Notes (continued)

 Significant Figures : Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. Ther e are five significant digits displayed, but no confidence should be placed on more than two significant digits.

 Manual Integration : The data systems used for processing w ill flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations. The peak was not integrated by the software “NI” , the peak

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP” . These codes will accompany the analyst’s ma nual integration stamp placed next to the compound name.

# Sample Custody

# ----------------------------- ! 

## :nttt. • .Jy 

## Analytical, Inc 

## Chain of Custody Record Reference Document No.

2202 Ellis Road 

### Project Number 100-208 Durham, NC 27703 Phone (919) 850-4392

Fax (919) 850-9012 

### Bill To: Civil Environmental Consultants Inc. Project Name: KCP&L ICR Testing

- 

### La Cygne Samples Shipment Date: Attn: Frank stevens Sample Team Members: FMS 

### Lab DestInation: 4848 Park 370 Blvd Profit Center No.: st. Louis 

### Lab Contact: Suite F**~~~----------------------** 

### Project Manager Frank Stevens Project Contact: Hazelwood, MO 63042 Purchase Order Number -1-00--2-0-8--0-00-4-------------------­ 

### Project Phone: Report To: Civil Environmental Consultants Inc.

Required Report Date:

________________________ _ Carrier/Waybill No.: Attn: Frank Stevens (fstevens@cecinc.com)

Sample Number Sample Description/Type

M26A-R1-C3--H2S04 Imps &. rinse 

### 0.1 N H2SO4 Impingers & rim M26A-R2-C3--H2S04 Imps &. rinse 

### 0.1 N H2SO4 Impingers & rim M26A-R3-C3--H2S04 Imps &. rinse 

### 0.1 N H2SO4 Impingers & rim M26A-BT -C3--H2S04 Imps &. rinse 

### 0.1 N H2SO4 Impingers & rim

CTM033-R1-C5-- 10% Pb Acetate/l% Acetic Add 

### 10% Pb Acetate/l % Acetic Ac CTM033-R2-C5-- 10% Pb Acetate/l% Acetic Acid 

### 10% Pb Acetate/l% Acetic Ac CTM033-R3-C5-- 10% Pb Acetate/l% Acetic Acid 

### 10% Pb Acetate/l % Acetic Ac CTM033-BT -(5-- 10% Pb Acetatetl % Acetic Acid 

### 10% Pb Acetate/l% Acetic Ac

CTM033-R1-C3A-- 1st 6N NaOH Imp &. rinse 

### 6N NaOH Impinger & rinse CTM033-RI-C3B-- 2nd 6N NaOH Imp &. rinse 

### 6N NaOH Impinger & rinse CTM033-RI-C3C-- 3rd 6N NaOH Imp &. rinse 

### 6N NaOH Impinger & rinse CTM033-R2-C3A-- 1st 6N NaOH Imp &. rinse 

### 6N NaOH Impingers & rinse CTM033-R2-C3B-- 2nd 6N NaOH Imp &. rinse 

### 6N NaOH Impingers & rinse CTM033-R2-C3C-- 3rd 6N NaOH Imp &. rinse 

### 6N NaOH Impingers & rinse CTM033-R3-C3A-- 1st 6N NaOH Imp & rinse 

### 6N NaOH Impingers & rinse CTM033-R3-C3B-- 2nd 6N NaOH Imp &. rinse 

### 6N NaOH Impingers & rinse CTM033-R3-C3C-- 3rd 6N NaOH Imp &. rimS! 

### eN NaOH Impingers & rinse CTM033-BT-C3A-- 1st 6N NaOH Imp &. rinse 

### 6N NaOH Impingers & rinse CTM033-BT-C3B-- 2nd 6N NaOH Imp &. rinse 

### 6N NaOH Impingers & rinse CTM033-BT-C3C-- 3rd 6N NaOH Imp & rinse 

### 6N NaOH Impingers & rinse Date Container Collected Type 

### 20-May-l0 glass 20-May-l0 glass 20-May-l0 glass 20-May-1O glass
20-May-l0 glass 20-May-l0 glass 20-May-l0 glass 20-May-l0 glass
20-May-1O glass 20-May-1O glass 20-May-l0 glass 20-May-l0 glass 20-May-l0 glass 20-May-l0 glass 20-May-l0 glass 20-May-l0 ' glass 20-May-1O glass 20-May-l0 glass 20-May-l0 glass 20-May-l0 glass



### Special Instructions: 

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# A**~J.\** 

# ,""-­**~c;.c;.s** 

# %"0

Possible Hazard Identification:

_ Non-Hazard _Aammable _Skin Irritant _POison _X_Unknown Requested Analysis


### USEPA Test Method 26A per ICR USEPA Test Method 26A per ICR USEPA Test Method 26A per ICR USEPA Test Method 26A per ICR

USEPA CPM Test Method 033 per ICR 

### rJ 

# ="l USEPA CPM Test Method 033 per ICR 

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# """ I' USEPA CPM Test Method 033 per ICR Separately 

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TUrn Around Time Required: Normal 

### QC Level: _X_Project SpeCific _Other 

### Relinquished By:

### tJ.~ 

# II tf,1.,ec,/<. Date: 

# Y 

# h 'l-kA

.... By' Date: 

## 5(7 \.£ 

# //0 /'J 

# ;'l....-- '>< 

### Time: 

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# L 'j;z JI/dJ ' signed:



# - 

# - 'U

# ~A 

# :L Time:

## ~elinqUiShed**BY""~**

# ~**Date:S~1)**

# ~:rvo Date:

## F;/~\\J 

# bZft," J:;



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# 1.1Vd Time:**,I~'** lI.:t1nill f ",

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## En(" Ipy 

## Analytical, Inc 

## Chain of Custody Record Reference Document No.

2202 Ellis Road Durham, NC 27703 Phone (919) 850-4392

Fax (919) 850-9012


### Project Name: KCP&L ICR Testing

- La 

### Cygne Sample Team Members:**..;..FM;..;.S~** ___________ _ 

### Profit Center No.: St. louis**~~~-----------**



### Project Manager..;.F..;..ra;;.;n..;.;k..;..S;;.t;.;;e..;..ve;;.n..;.;s;;......

_______ _ Purchase Order Number 100-208-0004



### Required Report Date:**~~~~----~------** 

### standard turnaround

Sample Number

OTM27-RI-CI-PM2.5 Filter (Tared) OTM27-RI-C23- >PM2.5Ace Rinse OTM27-RI-C4-<PM2.5 Ace Rinse OTM28-RI-CI-CPM Imp Water rinse OTM28-Rl-c2-CPM Imp Ace/MeCl2 rinse OTM28-RI-C3-CPM Filter OTM27-R2-CI-PM2.5 Filter (Tared) OTM27-R2-C23- >PM2.5Ace Rinse OTM27-R2-C4-<PM2.5 Ace Rinse OTM28-R2-Cl-CPM Imp Water rinse OTM28-R2-C2-CPM Imp Ace/MeC12 rinse OTM28-R2-C3-CPM Filter OTM27-R3-CI-PM2.S Filter (Tared) OTM27-R3-C23- >PM2.5Ace Rinse OTM27-R3-C4-<PM2.5 Ace Rinse OTM28-R3-CI-CPM Imp Water rinse OTM28-R3-c2-CPM Imp Ace/Mea2 rinse OTM28-R3-C3-CPM Filter OTM27-BT-CI-PM2.5 Riter (Tared) OTM27-BT-C23- >PM2.5Ace Rinse OTM27-BT -C4-<PM2.5 Ace Rinse OTM28-BT -CI-CPM Imp Water rinse OTM28-BT -C2-CPM Imp Ace/Mea2 rinse OTM28BT-C3-CPM Filter Sample Description/Type


### filter Acetone rinsate Acetone rinsate DIUF water rinse Acetone/Methylene Chloride filter filter Acetone rinsate Acetone rinsate DIUF water rinse Acetone/Methylene Chloride filter filter Acetone rinsate Acetone rinsate DIUF water rinse Acetone/Methylene Chloride filter filter Acetone rinsate Acetone rinsate DIUF water rinse Acetone/Methylene Chloride filter 

### Project Number 100-208

Bill To: Civil Environmental Consultants Inc. Attn: Frank stevens 4848 Park 370 Blvd Suite F Hazelwood, MO 63042 Report To: Civil Environmental Consultants Inc. Attn: Frank Stevens (fstevens@cecinc.com)

Requested Analysis


### USEPA other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA other Test Method 028 per ICR, see special instructions USEPA other Test Method 028 per ICR, see special instructions USEPA other Test Method 028 per ICR, see special instructions USEPA other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA other Test Method 028 per ICR, see special instructions USEPA other Test Method 028 per ICR, see special instructions USEPA other Test Method 028 per ICR, see special instructions USEPA other Test Method 027 per ICR USEPA other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA other Test Method 028 per ICR, see special instructions USEPA Other Test Method 028 per ICR, see special instructions USEPA Other Test Method 028 per ICR, see special instructions USEPA other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA Other Test Method 027 per ICR USEPA other Test Method 028 per ICR t 

### see special instructions USEPA other Test Method 028 per JCR, see special instructions USEPA other Test Method 028 per JCR, see special instructions Samples Shipment Date: Lab Destination: Lab Contact: Project Contact:

Project Phone: Carrier/Waybill No.:

Date Collected



### 21-May-1O 21-May-10 21-May-10 21-May-1O 21-May-10 21-May-1O 21-May-1O 21-May-1O 21-May-1O 21-May-1O 21-May-l0 21-May-1O 22-May-10 22-May-l0 22-May-10 22-May-10 22-May-1O 22-May-10 21-May-10 21-May-10 21-May-1O 21-May-1O 21-May-1O 21-May-l0 Container Type 

### petri dish glass glass glass glass glass petri dish glass glass glass glass glass petri dish glass glass glass glass glass petri dish glass glass glass glass glass 

### Special Instructions: After analyzing the inorganic portion please reconstitute the residue and analyze it for Sulfate (502).
Possible Hazard Identification:

_ Non-Hazard _Flammable _Skin Irritant _Poison _X_Unknown 

### Turn Around Time Required: Nonnal QC 

### Level: _X_Project SpeCific _Other 

### Relinquished By:

### t:rI~**Iht-/Iv'~p;c..** Date:

## .~h 

# "h", Date: 

## S 

# IZ c;, / /1)

# R~: Time: 

# (II/fa signed: 

## Q. Time: 

## II/;;a..... '" "?7r 

# 'U**--~** 

# Y Date: 

# ib/ fO Date: 

# 5 f7J5I \ tJ**~elinqUiShed** "By:

## ~ I............, Time: 

# 15YJ

# I~t«r-e> Time:

# ~1~ signed: I 77V7I 

# EA 

# L? rt 

# . ft_.

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# Sample Chromatograms

### ===================================================================== Acq. Operator : EO Seq. Line : 17 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 11:57:04 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1701.D)3.033 - Fluoride3.7424.074 - Chloride6.4958.359



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.033 BV 16.19024 1.40469e-2 2.27423e-1 Fluoride 4.074 VB 8.00630 2.59004e-2 2.07366e-1 Chloride

Totals : 4.34789e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1701.D Sample Name: Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:31 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 17 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 12:07:52 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1702.D)3.032 - Fluoride3.7394.071 - Chloride6.4938.361



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.032 BV 14.89996 1.40469e-2 2.09298e-1 Fluoride 4.071 VB 8.01220 2.59004e-2 2.07520e-1 Chloride

Totals : 4.16818e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1702.D Sample Name: Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:38 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 22 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 1:45:03 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2201.D)3.035 - Fluoride3.7484.083 - Chloride6.5478.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.035 BV 15.12566 1.40469e-2 2.12469e-1 Fluoride 4.083 VB 10.32935 2.59004e-2 2.67535e-1 Chloride

Totals : 4.80003e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2201.D Sample Name: Run 2 *20 0410-11

Instrument 1 6/10/2010 12:21:16 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 22 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 1:55:51 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2202.D)3.036 - Fluoride3.7524.089 - Chloride5.8056.5668.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.036 BV 14.97443 1.40469e-2 2.10344e-1 Fluoride 4.089 VB 10.30313 2.59004e-2 2.66856e-1 Chloride

Totals : 4.77200e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2202.D Sample Name: Run 2 *20 0410-11

Instrument 1 6/10/2010 12:21:24 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 23 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 2:06:39 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2301.D)3.038 - Fluoride3.7514.090 - Chloride5.8286.5798.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.038 BV 20.90090 1.40469e-2 2.93593e-1 Fluoride 4.090 VB 7.77663 2.59004e-2 2.01418e-1 Chloride

Totals : 4.95011e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2301.D Sample Name: Run 3 *20 0410-11

Instrument 1 6/10/2010 12:21:32 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 23 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 2:17:26 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2302.D)3.036 - Fluoride3.7494.090 - Chloride5.8356.5898.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.036 BV 19.03973 1.40469e-2 2.67449e-1 Fluoride 4.090 VB 7.77752 2.59004e-2 2.01441e-1 Chloride

Totals : 4.68890e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2302.D Sample Name: Run 3 *20 0410-11

Instrument 1 6/10/2010 12:21:39 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 24 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 2:28:14 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2401.D)8.387



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 - - - Fluoride 4.109 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2401.D Sample Name: H2SO4 Blank *20 0410-11

Instrument 1 6/10/2010 12:21:48 PM ARM Page 1 of 2

### ===================================================================== Acq. Operator : EO Seq. Line : 24 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 2:39:03 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2402.D)8.387



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 - - - Fluoride 4.109 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2402.D Sample Name: H2SO4 Blank *20 0410-11

Instrument 1 6/10/2010 12:22:07 PM ARM Page 1 of 2

### ===================================================================== Acq. Operator : EO Seq. Line : 9 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 9:04:19 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0901.D)5.1278.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 - - - Fluoride 4.109 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0901.D Sample Name: 0.01N H2SO4/NaOH MB

Instrument 1 6/10/2010 12:20:11 PM ARM Page 1 of 2

### ===================================================================== Acq. Operator : EO Seq. Line : 9 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 9:15:07 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0902.D)5.1218.347



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 - - - Fluoride 4.109 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0902.D Sample Name: 0.01N H2SO4/NaOH MB

Instrument 1 6/10/2010 12:20:19 PM ARM Page 1 of 2

### ===================================================================== Acq. Operator : EO Seq. Line : 20 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 1:01:52 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2001.D)3.041 - Fluoride3.7404.071 - Chloride5.7406.4577.1488.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.041 BV 236.98174 1.46550e-2 3.47296 Fluoride 4.071 VB 134.46176 2.41210e-2 3.24335 Chloride

Totals : 6.71631

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2001.D Sample Name: MS Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:46 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 20 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 1:12:40 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2002.D)3.042 - Fluoride3.7394.071 - Chloride5.7416.4587.1348.361



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.042 BV 237.87801 1.46559e-2 3.48633 Fluoride 4.071 VB 134.18892 2.41224e-2 3.23696 Chloride

Totals : 6.72329

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2002.D Sample Name: MS Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:54 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 21 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 1:23:27 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2101.D)3.041 - Fluoride3.7434.075 - Chloride5.7526.4737.1408.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.041 BV 233.78281 1.46514e-2 3.42524 Fluoride 4.075 VB 133.38010 2.41268e-2 3.21803 Chloride

Totals : 6.64328

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2101.D Sample Name: MSD Run 1 *20 0410-11

Instrument 1 6/10/2010 12:21:01 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 21 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 1:34:15 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2102.D)3.041 - Fluoride3.7434.077 - Chloride5.7616.4877.1448.360



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.041 BV 236.21182 1.46541e-2 3.46148 Fluoride 4.077 VB 133.70741 2.41250e-2 3.22569 Chloride

Totals : 6.68717

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2102.D Sample Name: MSD Run 1 *20 0410-11

Instrument 1 6/10/2010 12:21:08 PM ARM Page 1 of 1

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: ADC1 B, ADC1 B, Metrohm Signal 2: ADC1 A, ADC1 CHANNEL A
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 3.069 2 2 9.99000e-1 69.97066 1.42774e-2 Fluoride 3 4.97500 333.44276 1.49201e-2 4 8.92000 638.93991 1.39606e-2 5 14.80000 965.00597 1.53367e-2 4.109 2 2 9.99000e-1 38.71060 2.58069e-2 Chloride 3 4.97500 208.16149 2.38997e-2 4 8.92000 374.92666 2.37913e-2 5 14.80000 630.44516 2.34755e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Instrument 1 6/10/2010 12:17:02 PM ARM Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 200 400 600 800

2 3 4 5 

### Fluoride at exp. RT: 3.069 ADC1 A, ADC1 CHANNEL A Correlation: 0.99863 Residual Std. Dev.: 34.32213 Formula: y = mx + b m: 67.04350 b: 4.14244 x: Amount y: Area Calibration Level Weights: Level 2 : 1 Level 3 : 0.200804 Level 4 : 0.111996 Level 5 : 0.0675

Amount[ug/mL] 0 10 Area

0 100 200 300 400 500 600

2 3 4 5 

### Chloride at exp. RT: 4.109 ADC1 A, ADC1 CHANNEL A Correlation: 0.99999 Residual Std. Dev.: 2.15919 Formula: y = mx + b m: 42.72553 b: -4.11202 x: Amount y: Area Calibration Level Weights: Level 2 : 1 Level 3 : 0.200804 Level 4 : 0.111996 Level 5 : 0.0675

===================================================================== Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Instrument 1 6/10/2010 12:17:02 PM ARM Page 2 of 2

### ===================================================================== Acq. Operator : EO Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 7:16:21 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0401.D)3.032 - Fluoride3.4204.077 - Chloride5.7556.5047.1198.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.032 BV 71.89967 1.40563e-2 1.01065 Fluoride 4.077 VB 38.96849 2.58750e-2 1.00831 Chloride

Totals : 2.01895

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0401.D Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:25 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 7:27:09 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0402.D)3.033 - Fluoride3.4214.077 - Chloride5.1205.7536.5017.1278.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.033 BV 70.08958 1.40469e-2 9.84541e-1 Fluoride 4.077 VB 38.81830 2.58845e-2 1.00479 Chloride

Totals : 1.98933

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0402.D Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:33 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 27 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 3:33:02 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2701.D)3.035 - Fluoride3.4304.106 - Chloride5.1895.8516.6347.1108.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.035 BV 68.36214 1.40469e-2 9.60276e-1 Fluoride 4.106 VB 38.40773 2.59004e-2 9.94777e-1 Chloride

Totals : 1.95505

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2701.D Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:40 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 27 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 3:43:50 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2702.D)3.036 - Fluoride3.4304.109 - Chloride5.1925.8586.6427.1158.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.036 BV 69.53124 1.40469e-2 9.76698e-1 Fluoride 4.109 VB 38.64785 2.58955e-2 1.00080 Chloride

Totals : 1.97750

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2702.D Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:47 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 7:37:56 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0501.D)3.044 - Fluoride3.4264.075 - Chloride5.7336.4657.1278.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.044 BV 333.96948 1.47307e-2 4.91960 Fluoride 4.075 VB 207.89630 2.38681e-2 4.96210 Chloride

Totals : 9.88170

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0501.D Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:17:55 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 7:48:45 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0502.D)3.045 - Fluoride3.4244.072 - Chloride5.7286.4597.1158.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.045 BV 334.69070 1.47311e-2 4.93036 Fluoride 4.072 VB 207.95876 2.38680e-2 4.96356 Chloride

Totals : 9.89392

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0502.D Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:18:23 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 28 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 3:54:37 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2801.D)3.049 - Fluoride3.4334.105 - Chloride5.1925.8396.6097.1038.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.049 BV 333.72778 1.47305e-2 4.91599 Fluoride 4.105 VB 208.42900 2.38670e-2 4.97457 Chloride

Totals : 9.89056

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2801.D Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:18:31 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 28 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 4:05:24 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2802.D)3.047 - Fluoride3.4364.108 - Chloride5.2025.8466.6177.1078.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.047 BV 331.38309 1.47292e-2 4.88102 Fluoride 4.108 VB 208.36191 2.38671e-2 4.97300 Chloride

Totals : 9.85402

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2802.D Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:18:39 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 7:59:33 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0601.D)2.7243.056 - Fluoride4.073 - Chloride5.7186.4427.1218.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.056 VV 622.95276 1.48165e-2 9.22998 Fluoride 4.073 VB 373.70355 2.36627e-2 8.84285 Chloride

Totals : 18.07284

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0601.D Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:18:49 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 8:10:20 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0602.D)2.7273.057 - Fluoride4.074 - Chloride5.7196.4437.1278.346



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.057 VV 624.18518 1.48167e-2 9.24837 Fluoride 4.074 VB 372.97574 2.36632e-2 8.82582 Chloride

Totals : 18.07418

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0602.D Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:18:57 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 29 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 4:16:13 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2901.D)3.059 - Fluoride4.108 - Chloride5.1645.8386.6027.1068.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.059 BV 651.93127 1.48209e-2 9.66222 Fluoride 4.108 VB 376.42206 2.36609e-2 8.90648 Chloride

Totals : 18.56870

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2901.D Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:19:10 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 29 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 4:27:00 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2902.D)3.060 - Fluoride4.107 - Chloride5.1715.8416.6067.0988.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.060 BV 656.69043 1.48216e-2 9.73320 Fluoride 4.107 VB 376.60529 2.36608e-2 8.91077 Chloride

Totals : 18.64397

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2902.D Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:19:17 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 8:21:08 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0701.D)3.069 - Fluoride4.071 - Chloride5.7096.4217.1168.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 BV 971.08032 1.48521e-2 14.42255 Fluoride 4.071 VB 629.51410 2.35581e-2 14.83015 Chloride

Totals : 29.25270

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0701.D Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:25 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 8:31:56 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0702.D)3.068 - Fluoride4.073 - Chloride5.1085.7086.4197.1238.347



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.068 BV 959.86444 1.48513e-2 14.25525 Fluoride 4.073 VB 630.14801 2.35579e-2 14.84499 Chloride

Totals : 29.10024

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0702.D Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:33 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 30 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 4:37:48 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3001.D)3.069 - Fluoride4.111 - Chloride5.1935.8416.5967.1018.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 BV 962.06219 1.48515e-2 14.28803 Fluoride 4.111 VB 630.74725 2.35578e-2 14.85901 Chloride

Totals : 29.14705

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3001.D Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:40 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 30 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 4:48:36 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3002.D)3.069 - Fluoride4.112 - Chloride5.1955.8456.6017.1038.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.069 BV 967.01691 1.48518e-2 14.36194 Fluoride 4.112 VB 631.37128 2.35576e-2 14.87362 Chloride

Totals : 29.23556

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3002.D Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:47 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 8:42:44 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0801.D)3.042 - Fluoride4.072 - Chloride5.1118.333



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.042 BV 290.32208 1.47029e-2 4.26857 Fluoride 4.072 VB 165.00069 2.39885e-2 3.95812 Chloride

Totals : 8.22668

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0801.D Sample Name: HPLC51pg110 #LCS

Instrument 1 6/10/2010 12:19:55 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 6/9/2010 8:53:31 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0802.D)3.042 - Fluoride4.070 - Chloride5.1118.334



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.042 BV 292.95966 1.47048e-2 4.30791 Fluoride 4.070 VB 165.32860 2.39873e-2 3.96579 Chloride

Totals : 8.27370

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0802.D Sample Name: HPLC51pg110 #LCS

Instrument 1 6/10/2010 12:20:03 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 18 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 12:18:40 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1801.D)3.046 - Fluoride4.070 - Chloride5.1055.7086.4327.1318.347



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.046 BV 353.35434 1.47408e-2 5.20874 Fluoride 4.070 VB 205.12195 2.38744e-2 4.89716 Chloride

Totals : 10.10590

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1801.D Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:23:17 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : EO Seq. Line : 18 Acq. Instrument : Smithers Location : - Injection Date : 6/10/2010 12:29:28 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M Last changed : 6/10/2010 12:16:41 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1802.D)3.047 - Fluoride4.071 - Chloride5.1005.7116.4357.1358.347



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 3.047 BV 354.06757 1.47412e-2 5.21937 Fluoride 4.071 VB 204.97243 2.38747e-2 4.89367 Chloride

Totals : 10.11304

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1802.D Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:23:26 PM ARM Page 1 of 1

### Method Information

Method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified: 2/23/2010 at 8:12:27 AM

========================================================================= ANALOG DIGITAL CONVERTER

=========================================================================  Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: μS/cm Units/Volt: 100.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified on: 2/23/2010 at 8:12:27 AM

Smithers 3/16/2010 1:54:21 PM KHB/EO Page 1 of 1

### Sequence Table:
Method and Injection Info Part:
Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========
1 Vial 127 DI Rinse METROHM 4 Sample
2 Vial 126 DI Rinse METROHM 4 Sample
3 Vial 1 HPLC51pg110 #1 METROHM 2 Sample
4 Vial 2 HPLC51pg110 #2 METROHM 2 Sample
5 Vial 3 HPLC51pg110 #3 METROHM 2 Sample
6 Vial 4 HPLC51pg110 #4 METROHM 2 Sample
7 Vial 5 HPLC51pg110 #5 METROHM 2 Sample
8 Vial 6 HPLC51pg110 #LCS METROHM 2 Sample
9 Vial 7 0.01N H2SO4/NaOH MB METROHM 2 Sample
10 Vial 8 Run 1 *20 0610-18 METROHM 2 Sample
11 Vial 9 MS Run 1 *20 0610-18 METROHM 2 Sample
12 Vial 10 MSD Run 1 *20 0610-18 METROHM 2 Sample
13 Vial 11 Run 2 *20 0610-18 METROHM 2 Sample
14 Vial 12 Run 3 *20 0610-18 METROHM 2 Sample
15 Vial 13 DI H2O Blank 0610-18 METROHM 2 Sample
16 Vial 14 H2SO4 Blank *20 0610-18 METROHM 2 Sample
17 Vial 15 Run 1 *20 0410-11 METROHM 2 Sample
18 Vial 100 HPLC51pg110 #3 METROHM 2 Sample
19 Vial 101 HPLC51pg110 #4 METROHM 2 Sample
20 Vial 16 MS Run 1 *20 0410-11 METROHM 2 Sample
21 Vial 17 MSD Run 1 *20 0410-11 METROHM 2 Sample
22 Vial 18 Run 2 *20 0410-11 METROHM 2 Sample
23 Vial 19 Run 3 *20 0410-11 METROHM 2 Sample
24 Vial 20 H2SO4 Blank *20 0410-11 METROHM 2 Sample
25 Vial 21 DI H2O blank 0610-18 METROHM 2 Sample
26 Vial 1 HPLC51pg110 #1 METROHM 2 Sample
27 Vial 2 HPLC51pg110 #2 METROHM 2 Sample Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG128.S

Instrument 1 6/10/2010 12:24:32 PM ARM Page 1 of 2

### Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========
28 Vial 3 HPLC51pg110 #3 METROHM 2 Sample
29 Vial 4 HPLC51pg110 #4 METROHM 2 Sample
30 Vial 5 HPLC51pg110 #5 METROHM 2 Sample
31 Vial 110 HPLC51pg110 #LCS METROHM 2 Sample
32 Vial 111 0.01N H2SO4/NaOH MB METROHM 2 Sample
33 Vial 112 L2710*5 0510-103 METROHM 2 Sample
34 Vial 113 L2710*5 0510-103 METROHM 2 Sample
35 Vial 114 L2710*1000 0510-103 METROHM 2 Sample
36 Vial 115 hplc51pg126 SS*5 0510-103 METROHM 2 Sample
37 Vial 116 HPLC51pg110 #1 METROHM 2 Sample
38 Vial 117 HPLC51pg110 #2 METROHM 2 Sample
39 Vial 118 HPLC51pg110 #3 METROHM 2 Sample
40 Vial 119 HPLC51pg110 #4 METROHM 2 Sample
41 Vial 120 HPLC51pg110 #5 METROHM 2 Sample Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG128.S

Instrument 1 6/10/2010 12:24:32 PM ARM Page 2 of 2

# Sample Chromatogramsmin 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\010-1101.D)1.6582.0572.611



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\010-1101.D Sample Name: CTM033-R1-C3A-C *5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 5:49:47 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:27:49 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\011-1201.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\011-1201.D Sample Name: CTM033-R1-C5*5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 12 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 6:05:04 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:28:18 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\012-1301.D)1.6532.0602.615



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\012-1301.D Sample Name: CTM033-R2-C3A-C *5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 6:20:20 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:28:46 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\013-1401.D)1.6381.689



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\013-1401.D Sample Name: CTM033-R2-C5*5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 14 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 6:35:38 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:29:12 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\014-1501.D)1.6552.0542.614



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\014-1501.D Sample Name: CTM033-R3-C3A-C *5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 6:50:55 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:29:46 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\015-1601.D)1.6341.6852.653



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\015-1601.D Sample Name: CTM033-R3-C5*5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 16 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 7:06:11 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:30:08 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\016-1701.D)1.6291.847



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\016-1701.D Sample Name: CTM033-BT-C3A-C *5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 17 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 7:21:27 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:30:29 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\017-1801.D)1.6041.739



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\017-1801.D Sample Name: CTM033-BT-C5*5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 18 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 7:36:44 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:30:56 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\007-0801.D)1.7362.148



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\007-0801.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : ARM Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 4:33:25 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:24:46 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\007-0802.D)0.0391.7372.150



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\007-0802.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : ARM Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 4:48:40 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:25:39 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\008-0901.D)1.6751.7767.984 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.984 BB 1699.42212 6.58766e-4 1.11952 Hydrogen Cyanide

Totals : 1.11952

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\008-0901.D Sample Name: Hplc50pg128 #LCS

===================================================================== Acq. Operator : ARM Seq. Line : 9 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 5:03:57 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:26:17 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\008-0902.D)1.6771.7777.985 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.985 BB 1718.88452 6.58883e-4 1.13254 Hydrogen Cyanide

Totals : 1.13254

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\008-0902.D Sample Name: Hplc50pg128 #LCS

===================================================================== Acq. Operator : ARM Seq. Line : 9 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 5:19:14 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:26:40 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\018-1901.D)1.6602.0642.6158.000 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.000 BB 1721.80261 6.58901e-4 1.13450 Hydrogen Cyanide

Totals : 1.13450

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\018-1901.D Sample Name: MS/CTM033-R1-C3A-C 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 19 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 7:52:01 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:31:35 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\019-2201.D)1.6652.0642.6178.021 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.021 BB 1763.61536 6.59144e-4 1.16248 Hydrogen Cyanide

Totals : 1.16248

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\019-2201.D Sample Name: MSD/CTM033-R1-C3A-C 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 22 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 9:08:24 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:33:01 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\020-2301.D)1.6652.0652.617



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\020-2301.D Sample Name: LD/CTM033-R1-C3A-C *5 0410-11

===================================================================== Acq. Operator : ARM Seq. Line : 23 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 9:23:41 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:33:17 PM ARM Page 1 of 2

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.300 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.300 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 7.964 1 1 1.03500e-1 178.57640 5.79584e-4 Hydrogen Cyanide 2 5.07300e-1 774.35867 6.55123e-4 3 9.90500e-1 1564.24603 6.33212e-4 4 1.54100 2374.78821 6.48900e-4 5 2.08000 3044.28503 6.83247e-4

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

Instrument 1 6/28/2010 5:02:12 PM AMP Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 1 2 Area

0 500 1000 1500 2000 2500 3000

1 2 3 4 5 

### Hydrogen Cyanide at exp. RT: 7.964 ADC1 A, ADC1 CHANNEL A Correlation: 0.99942 Residual Std. Dev.: 67.54778 Formula: y = mx + b m: 1494.40013 b: 26.40971 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.204021 Level 3 : 0.104493 Level 4 : 0.067164 Level 5 : 0.04976

===================================================================== Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

Instrument 1 6/28/2010 5:02:12 PM AMP Page 2 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\001-0201.D)0.0451.4051.6731.7698.044 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.044 BB 177.71291 5.71570e-4 1.01575e-1 Hydrogen Cyanide

Totals : 1.01575e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\001-0201.D Sample Name: hplc50pg118 #1

===================================================================== Acq. Operator : ARM Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 1:30:07 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:20:54 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\001-0202.D)1.6731.7688.029 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.029 BB 179.43990 5.71570e-4 1.02562e-1 Hydrogen Cyanide

Totals : 1.02562e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\001-0202.D Sample Name: hplc50pg118 #1

===================================================================== Acq. Operator : ARM Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 1:45:22 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:21:11 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\002-0301.D)1.6721.7708.018 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.018 BB 769.52649 6.46199e-4 4.97268e-1 Hydrogen Cyanide

Totals : 4.97268e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\002-0301.D Sample Name: hplc50pg118 #2

===================================================================== Acq. Operator : ARM Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 2:00:39 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:21:23 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\002-0302.D)0.1100.2010.3010.4001.6651.7647.997 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.997 BB 779.19086 6.46484e-4 5.03735e-1 Hydrogen Cyanide

Totals : 5.03735e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\002-0302.D Sample Name: hplc50pg118 #2

===================================================================== Acq. Operator : ARM Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 2:15:55 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:21:35 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\003-0401.D)1.6721.7708.000 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.000 BB 1555.64319 6.57805e-4 1.02331 Hydrogen Cyanide

Totals : 1.02331

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\003-0401.D Sample Name: hplc50pg118 #3

===================================================================== Acq. Operator : ARM Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 2:31:13 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:21:50 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\003-0402.D)1.6731.7697.998 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.998 BB 1572.84888 6.57929e-4 1.03482 Hydrogen Cyanide

Totals : 1.03482

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\003-0402.D Sample Name: hplc50pg118 #3

===================================================================== Acq. Operator : ARM Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 2:46:29 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:22:03 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-0501.D)1.6721.7727.988 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.988 BB 2363.89722 6.61689e-4 1.56416 Hydrogen Cyanide

Totals : 1.56416

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-0501.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 3:01:45 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:22:25 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-0502.D)1.6721.7727.984 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.984 BB 2385.67920 6.61757e-4 1.57874 Hydrogen Cyanide

Totals : 1.57874

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-0502.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 3:17:01 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:22:38 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\005-0601.D)1.6721.7707.982 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.982 BB 3033.08081 6.63338e-4 2.01196 Hydrogen Cyanide

Totals : 2.01196

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\005-0601.D Sample Name: hplc50pg118 #5

===================================================================== Acq. Operator : ARM Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 3:32:18 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:22:50 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\005-0602.D)0.1210.2200.3201.6661.7667.959 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.959 BB 3055.48926 6.63381e-4 2.02695 Hydrogen Cyanide

Totals : 2.02695

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\005-0602.D Sample Name: hplc50pg118 #5

===================================================================== Acq. Operator : ARM Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 3:47:35 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:23:14 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-2101.D)1.6761.7818.022 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.022 BB 2610.82080 6.62396e-4 1.72940 Hydrogen Cyanide

Totals : 1.72940

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-2101.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 21 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 8:37:51 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:32:30 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-2102.D)1.6771.7828.026 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.026 BB 2628.14233 6.62441e-4 1.74099 Hydrogen Cyanide

Totals : 1.74099

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-2102.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 21 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 8:53:07 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:32:45 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-3301.D)1.6771.7828.081 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.081 BB 2710.03052 6.62644e-4 1.79578 Hydrogen Cyanide

Totals : 1.79578

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-3301.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 33 Acq. Instrument : Grandmama Location : - Injection Date : 6/26/2010 12:11:46 AM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:36:22 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-3302.D)1.6751.7838.078 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.078 BB 2694.15186 6.62605e-4 1.78516 Hydrogen Cyanide

Totals : 1.78516

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-3302.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 33 Acq. Instrument : Grandmama Location : - Injection Date : 6/26/2010 12:27:01 AM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:36:31 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-4601.D)1.6721.7752.1828.127 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.127 BB 2815.30225 6.62888e-4 1.86623 Hydrogen Cyanide

Totals : 1.86623

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-4601.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 46 Acq. Instrument : Grandmama Location : - Injection Date : 6/26/2010 4:16:18 AM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:39:15 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-4602.D)1.6771.7818.135 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.135 BB 2791.87720 6.62835e-4 1.85055 Hydrogen Cyanide

Totals : 1.85055

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-4602.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 46 Acq. Instrument : Grandmama Location : - Injection Date : 6/26/2010 4:31:35 AM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:39:24 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-5001.D)1.6781.7828.161 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.161 BB 2812.00586 6.62880e-4 1.86402 Hydrogen Cyanide

Totals : 1.86402

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-5001.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 6/26/2010 5:48:03 AM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:40:16 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-5002.D)1.6791.7818.164 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.164 BB 2824.65356 6.62908e-4 1.87249 Hydrogen Cyanide

Totals : 1.87249

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-5002.D Sample Name: hplc50pg118 #4

===================================================================== Acq. Operator : ARM Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 6/26/2010 6:03:20 AM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:40:25 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\006-0701.D)0.0650.2671.6671.7677.964 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.964 BB 1546.54419 6.57738e-4 1.01722 Hydrogen Cyanide Tag Value= 1.019 μg/mL

Totals : 1.01722

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\006-0701.D Sample Name: hplc50pg92 #SS

===================================================================== Acq. Operator : ARM Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 4:02:52 PM Inj : 1 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:23:40 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\006-0702.D)1.6731.7717.972 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.972 BB 1549.44458 6.57759e-4 1.01916 Hydrogen Cyanide Tag Value= 1.019 μg/mL

Totals : 1.01916

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\006-0702.D Sample Name: hplc50pg92 #SS

===================================================================== Acq. Operator : ARM Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 6/25/2010 4:18:07 PM Inj : 2 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/27/2010 11:58:08 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M Last changed : 6/28/2010 9:08:27 AM by ARM

=====================================================================

Instrument 1 6/28/2010 2:24:16 PM ARM Page 1 of 1

### Method Information
Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified: 3/17/2010 at 9:48:43 AM
Column: Dionex Ionpac AS7 4 X 250mm Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine Flow rate: 1.0 mL/min

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: nC Units/Volt: 1000.000 Peakwidth (Data Rate): 0.133 Min (2.00 Hz) Stop Time: 14.01 Min Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1

### Sequence: C:\HPCHEM\1\SEQUENCE\hplc50pg130.txt
Line Vial Sample Name Method Inj 1 Vial 7 0.1N NaOH - RB 1000 2 2 Vial 1 hplc50pg118 #1 1000 2 3 Vial 2 hplc50pg118 #2 1000 2 4 Vial 3 hplc50pg118 #3 1000 2 5 Vial 4 hplc50pg118 #4 1000 2 6 Vial 5 hplc50pg118 #5 1000 2 7 Vial 6 hplc50pg92 #SS 1000 2 8 Vial 7 0.1N NaOH - RB 1000 2 9 Vial 8 Hplc50pg128 #LCS 1000 2 10 Vial 9 MSD/Run 1 0610-38 1000 1 11 Vial 10 CTM033-R1-C3A-C *5 0410-11 1000 1 12 Vial 11 CTM033-R1-C5*5 0410-11 1000 1 13 Vial 12 CTM033-R2-C3A-C *5 0410-11 1000 1 14 Vial 13 CTM033-R2-C5*5 0410-11 1000 1 15 Vial 14 CTM033-R3-C3A-C *5 0410-11 1000 1 16 Vial 15 CTM033-R3-C5*5 0410-11 1000 1 17 Vial 16 CTM033-BT-C3A-C *5 0410-11 1000 1 18 Vial 17 CTM033-BT-C5*5 0410-11 1000 1 19 Vial 18 MS/CTM033-R1-C3A-C 0410-11 1000 1 20 Vial 3 hplc50pg118 #3 1000 2 21 Vial 4 hplc50pg118 #4 1000 2 22 Vial 19 MSD/CTM033-R1-C3A-C 0410-11 1000 1 23 Vial 20 LD/CTM033-R1-C3A-C *5 0410-11 1000 1 24 Vial 21 ICR1-CTM33-C3-PbAc*5 0410-49 1000 1 25 Vial 22 ICR1-CTM33-C4-NaOH*5 0410-49 1000 1 26 Vial 23 ICR2-CTM33-C3-PbAc*5 0410-49 1000 1 27 Vial 24 ICR2-CTM33-C4-NaOH*5 0410-49 1000 1 28 Vial 25 ICR3-CTM33-C3-PbAc*5 0410-49 1000 1 29 Vial 26 ICR3-CTM33-C4-NaOH*5 0410-49 1000 1 30 Vial 27 ICFB-CTM33-C3-PbAc*5 0410-49 1000 1 31 Vial 28 ICFB-CTM33-C4-NaOH*5 0410-49 1000 1 32 Vial 3 hplc50pg118 #3 1000 2 33 Vial 4 hplc50pg118 #4 1000 2 34 Vial 8 Hplc50pg128 #LCS 1000 2 35 Vial 29 ICRRB-CTM33-PbAc Soln*5 0410-49 1000 1 36 Vial 30 ICRRB-CTM33-NaOH Soln*5 0410-49 1000 1 37 Vial 31 ICRFS-CTM33-Field Spike*5 0410-49 1000 1 38 Vial 32 MS/ICR1-CTM33-C3-PbAc 0410-49 1000 1 39 Vial 33 MSD/ICR1-CTM33-C3-PbAc 0410-49 1000 1 40 Vial 34 LD/ICR1-CTM33-C3-PbAc*5 0410-49 1000 1 41 Vial 35 Cope-HCl-Run 1*5 0610-71 1000 1 42 Vial 36 Cope-HCl-Run 2*5 0610-71 1000 1 43 Vial 37 Cope-HCl-Run 3*5 0610-71 1000 1 44 Vial 38 MS/Cope-HCl-Run 1 0610-71 1000 1 45 Vial 3 hplc50pg118 #3 1000 2 46 Vial 4 hplc50pg118 #4 1000 2 47 Vial 39 MSD/Cope-HCl-Run 1*5 0610-71 1000 1 48 Vial 40 LD/Cope-HCl-Run 1*5 0610-71 1000 1 49 Vial 3 hplc50pg118 #3 1000 2 50 Vial 4 hplc50pg118 #4 1000 2

# Sample Chromatograms

### ===================================================================== Acq. Operator : ARM Seq. Line : 15 Acq. Instrument : Gonzo Location : Vial 21 Injection Date : 6/8/2010 11:10:36 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\021-1501.D)10.082 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.082 BB 345.87695 1.78970e-2 6.19016 Sulfate

Totals : 6.19016

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\021-1501.D Sample Name: Run 1 Post *20 0410-11

Instrument 1 6/9/2010 9:02:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 15 Acq. Instrument : Gonzo Location : Vial 21 Injection Date : 6/8/2010 11:27:18 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\021-1502.D)10.079 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.079 VB 346.15082 1.78971e-2 6.19508 Sulfate

Totals : 6.19508

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\021-1502.D Sample Name: Run 1 Post *20 0410-11

Instrument 1 6/9/2010 9:02:43 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 18 Acq. Instrument : Gonzo Location : Vial 24 Injection Date : 6/9/2010 12:50:48 AM Inj : 1 Inj Volume : 25 μl Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GON ZO\DATA\MAY\IC HPLC49PG26ARM\024-1801.D)

A

r ea

: 42

9 .

94

910.075 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.075 MM 429.94937 1.79077e-2 7.69942 Sulfate

Totals : 7.69942

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\024-1801.D Sample Name: Run 2 Post *20 0410-11

Instrument 1 6/9/2010 9:12:54 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 18 Acq. Instrument : Gonzo Location : Vial 24 Injection Date : 6/9/2010 1:07:29 AM Inj : 2 Inj Volume : 25 μl Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GON ZO\DATA\MAY\IC HPLC49PG26ARM\024-1802.D)

A

r ea

: 38

6

. 9110.078 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.078 MM 386.91022 1.79028e-2 6.92679 Sulfate

Totals : 6.92679

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\024-1802.D Sample Name: Run 2 Post *20 0410-11

Instrument 1 6/9/2010 9:12:17 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 19 Acq. Instrument : Gonzo Location : Vial 25 Injection Date : 6/9/2010 1:24:04 AM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\025-1901.D)10.077 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.077 BB 375.11435 1.79013e-2 6.71503 Sulfate

Totals : 6.71503

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\025-1901.D Sample Name: Run 3 Post *20 0410-11

Instrument 1 6/9/2010 9:04:16 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 19 Acq. Instrument : Gonzo Location : Vial 25 Injection Date : 6/9/2010 1:40:39 AM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\025-1902.D)10.073 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.073 BB 377.35861 1.79016e-2 6.75532 Sulfate

Totals : 6.75532

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\025-1902.D Sample Name: Run 3 Post *20 0410-11

Instrument 1 6/9/2010 9:04:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 22 Acq. Instrument : Gonzo Location : Vial 26 Injection Date : 6/9/2010 3:04:01 AM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\026-2201.D)4.00010.067 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.067 VV 74.39171 1.76968e-2 1.31650 Sulfate

Totals : 1.31650

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\026-2201.D Sample Name: Train Blank Post 0410-11

Instrument 1 6/9/2010 9:05:39 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 22 Acq. Instrument : Gonzo Location : Vial 26 Injection Date : 6/9/2010 3:20:41 AM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\026-2202.D)4.00110.063 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.063 VB 71.29880 1.76858e-2 1.26097 Sulfate

Totals : 1.26097

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\026-2202.D Sample Name: Train Blank Post 0410-11

Instrument 1 6/9/2010 9:05:53 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 23 Acq. Instrument : Gonzo Location : Vial 27 Injection Date : 6/9/2010 3:37:19 AM Inj : 1 Inj Volume : 25 μl Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GON ZO\DATA\MAY\IC HPLC49PG26ARM\027-2301.D)

A

r ea

: 17 .

9 52

24.00110.087 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.087 MM 17.95224 1.72950e-2 3.10484e-1 Sulfate

Totals : 3.10484e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\027-2301.D Sample Name: In House Blank Post 0410-11

Instrument 1 6/9/2010 9:37:48 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 23 Acq. Instrument : Gonzo Location : Vial 27 Injection Date : 6/9/2010 3:53:58 AM Inj : 2 Inj Volume : 25 μl Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GON ZO\DATA\MAY\IC HPLC49PG26ARM\027-2302.D)

A

r ea

: 18

. 2 08

54.00010.085 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.085 MM 18.20848 1.72950e-2 3.14915e-1 Sulfate

Totals : 3.14915e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\027-2302.D Sample Name: In House Blank Post 0410-11

Instrument 1 6/9/2010 9:38:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 9 Acq. Instrument : Gonzo Location : Vial 7 Injection Date : 6/8/2010 7:50:44 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\007-0901.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.028 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\007-0901.D Sample Name: MB/ DI H2O

Instrument 1 6/9/2010 8:54:33 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 9 Acq. Instrument : Gonzo Location : Vial 7 Injection Date : 6/8/2010 8:07:23 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\007-0902.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.028 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\007-0902.D Sample Name: MB/ DI H2O

Instrument 1 6/9/2010 8:54:58 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 8 Acq. Instrument : Gonzo Location : Vial 6 Injection Date : 6/8/2010 7:17:19 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\006-0801.D)10.049 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.049 VB 281.71533 1.78845e-2 5.03834 Sulfate Tag Value= 5.0 μg/mL

Totals : 5.03834

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\006-0801.D Sample Name: hplc49pg22 #LCS

Instrument 1 6/9/2010 8:54:07 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 8 Acq. Instrument : Gonzo Location : Vial 6 Injection Date : 6/8/2010 7:34:01 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\006-0802.D)10.046 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.046 BB 284.10382 1.78851e-2 5.08122 Sulfate Tag Value= 5.0 μg/mL

Totals : 5.08122

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\006-0802.D Sample Name: hplc49pg22 #LCS

Instrument 1 6/9/2010 8:54:20 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 16 Acq. Instrument : Gonzo Location : Vial 22 Injection Date : 6/8/2010 11:44:05 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\022-1601.D)3.9805.6636.2577.75010.081 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.081 VB 527.16437 1.79159e-2 9.44461 Sulfate

Totals : 9.44461

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\022-1601.D Sample Name: MS Run 1 Post 0410-11

Instrument 1 6/9/2010 9:02:56 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 16 Acq. Instrument : Gonzo Location : Vial 22 Injection Date : 6/9/2010 12:00:47 AM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\022-1602.D)3.9795.6616.2567.75010.075 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.075 BB 527.06824 1.79159e-2 9.44289 Sulfate

Totals : 9.44289

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\022-1602.D Sample Name: MS Run 1 Post 0410-11

Instrument 1 6/9/2010 9:03:11 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 17 Acq. Instrument : Gonzo Location : Vial 23 Injection Date : 6/9/2010 12:17:27 AM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\023-1701.D)3.9785.6586.2507.75610.076 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.076 BB 526.20581 1.79158e-2 9.42740 Sulfate

Totals : 9.42740

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\023-1701.D Sample Name: MSD Run 1 Post 0410-11

Instrument 1 6/9/2010 9:03:24 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 17 Acq. Instrument : Gonzo Location : Vial 23 Injection Date : 6/9/2010 12:34:08 AM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\023-1702.D)3.9775.6596.2537.75410.069 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.069 VB 525.77075 1.79158e-2 9.41959 Sulfate

Totals : 9.41959

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\023-1702.D Sample Name: MSD Run 1 Post 0410-11

Instrument 1 6/9/2010 9:03:37 AM ARM Page 1 of 1

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: VWD1 A, Wavelength=210 nm Signal 2: ADC1 B, Dionex ED 40
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 10.028 2 1 4.99500e-1 28.91521 1.72746e-2 Sulfate 2 9.99000e-1 57.70783 1.73113e-2 3 4.97500 271.08472 1.83522e-2 4 8.92000 496.73793 1.79572e-2 5 14.80000 832.75290 1.77724e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Instrument 1 6/9/2010 8:48:16 AM ARM Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 100 200 300 400 500 600 700 800

1 2 3 4 5 

### Sulfate at exp. RT: 10.028 ADC1 B, Dionex ED 40 Correlation: 0.99989 Residual Std. Dev.: 5.93670 Formula: y = mx + b m: 55.70453 b: 1.05679 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.5 Level 3 : 0.100402 Level 4 : 0.055998 Level 5 : 0.03375

===================================================================== Method H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Instrument 1 6/9/2010 8:48:16 AM ARM Page 2 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 3 Acq. Instrument : Gonzo Location : Vial 1 Injection Date : 6/8/2010 4:30:20 PM Inj : 1 Inj Volume : 25 μl Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GON ZO\DATA\MAY\IC HPLC49PG26ARM\001-0301.D)

A

r ea

: 29 .

5 05

63.99310.064 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.064 MM 29.50560 1.73089e-2 5.10709e-1 Sulfate

Totals : 5.10709e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\001-0301.D Sample Name: hplc49pg22 #1

Instrument 1 6/9/2010 8:49:19 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 3 Acq. Instrument : Gonzo Location : Vial 1 Injection Date : 6/8/2010 4:47:09 PM Inj : 2 Inj Volume : 25 μl Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GON ZO\DATA\MAY\IC HPLC49PG26ARM\001-0302.D)

A

r ea

: 28

. 3 24

83.99310.036 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.036 MM 28.32482 1.72950e-2 4.89877e-1 Sulfate

Totals : 4.89877e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\001-0302.D Sample Name: hplc49pg22 #1

Instrument 1 6/9/2010 8:49:44 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 4 Acq. Instrument : Gonzo Location : Vial 2 Injection Date : 6/8/2010 5:03:50 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\002-0401.D)3.9905.6976.30810.055 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.055 VV 59.20059 1.76314e-2 1.04379 Sulfate

Totals : 1.04379

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\002-0401.D Sample Name: hplc49pg22 #2

Instrument 1 6/9/2010 8:52:07 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 4 Acq. Instrument : Gonzo Location : Vial 2 Injection Date : 6/8/2010 5:20:31 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\002-0402.D)3.9885.6876.28810.062 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.062 VV 56.21507 1.76144e-2 9.90194e-1 Sulfate

Totals : 9.90194e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\002-0402.D Sample Name: hplc49pg22 #2

Instrument 1 6/9/2010 8:52:23 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 5 Acq. Instrument : Gonzo Location : Vial 3 Injection Date : 6/8/2010 5:37:12 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\003-0501.D)3.9825.6866.2817.73810.044 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.044 BB 269.91867 1.78816e-2 4.82657 Sulfate

Totals : 4.82657

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\003-0501.D Sample Name: hplc49pg22 #3

Instrument 1 6/9/2010 8:52:40 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 5 Acq. Instrument : Gonzo Location : Vial 3 Injection Date : 6/8/2010 5:53:58 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\003-0502.D)3.9815.6826.2777.73910.053 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.053 BB 272.25076 1.78822e-2 4.86844 Sulfate

Totals : 4.86844

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\003-0502.D Sample Name: hplc49pg22 #3

Instrument 1 6/9/2010 8:52:57 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 6 Acq. Instrument : Gonzo Location : Vial 4 Injection Date : 6/8/2010 6:10:36 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-0601.D)3.9825.6816.2757.73510.037 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.037 BB 495.87808 1.79136e-2 8.88296 Sulfate

Totals : 8.88296

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-0601.D Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 8:53:12 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 6 Acq. Instrument : Gonzo Location : Vial 4 Injection Date : 6/8/2010 6:27:21 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-0602.D)3.9825.6856.2787.73610.032 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.032 VB 497.59778 1.79137e-2 8.91384 Sulfate

Totals : 8.91384

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-0602.D Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 8:53:25 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 7 Acq. Instrument : Gonzo Location : Vial 5 Injection Date : 6/8/2010 6:44:02 PM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\005-0701.D)3.9835.6826.2727.73310.024 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.024 BB 833.94806 1.79291e-2 14.95195 Sulfate

Totals : 14.95195

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\005-0701.D Sample Name: hplc49pg22 #5

Instrument 1 6/9/2010 8:53:39 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 7 Acq. Instrument : Gonzo Location : Vial 5 Injection Date : 6/8/2010 7:00:35 PM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\005-0702.D)3.9815.6766.2667.73510.029 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.029 BB 831.55774 1.79290e-2 14.90904 Sulfate

Totals : 14.90904

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\005-0702.D Sample Name: hplc49pg22 #5

Instrument 1 6/9/2010 8:53:53 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 21 Acq. Instrument : Gonzo Location : Vial 4 Injection Date : 6/9/2010 2:30:40 AM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2101.D)3.9945.7316.3397.71410.048 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.048 BB 498.29391 1.79138e-2 8.92633 Sulfate

Totals : 8.92633

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2101.D Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:05:11 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 21 Acq. Instrument : Gonzo Location : Vial 4 Injection Date : 6/9/2010 2:47:21 AM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2102.D)3.9945.7356.3457.70710.053 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.053 BB 498.68936 1.79138e-2 8.93343 Sulfate

Totals : 8.93343

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2102.D Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:05:24 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 25 Acq. Instrument : Gonzo Location : Vial 4 Injection Date : 6/9/2010 4:44:03 AM Inj : 1 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2501.D)3.9975.7546.3657.69310.037 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.037 BB 499.05215 1.79138e-2 8.93994 Sulfate

Totals : 8.93994

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2501.D Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:07:10 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 25 Acq. Instrument : Gonzo Location : Vial 4 Injection Date : 6/9/2010 5:00:44 AM Inj : 2 Inj Volume : 25 μl Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Last changed : 5/27/2010 4:50:49 PM by ARM Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M Last changed : 6/9/2010 8:48:07 AM by ARM

min 0 2 4 6 8 10 12 14 uS

350 400 450 500 550 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2502.D)3.9975.7576.3707.69210.037 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, Dionex ED 40
RetTime Type Area Amt/Area Amount Grp Name [min] [uS*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 10.037 BB 501.51471 1.79140e-2 8.98415 Sulfate

Totals : 8.98415

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2502.D Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:07:23 AM ARM Page 1 of 1

### Method Information
Method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Modified: 5/27/2010 at 4:50:49 PM

Column: Dionex IonPac AS14A, 250*4mm Mobile Phase: 8mM Na2CO3/1mM NaHCO3 Flow Rate: 1.2 mL/min Detection: Suppressed Ion Conductivity

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: Dionex ED 40 Source: Signal Unit: uS Units/Volt: 1000.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Modified on: 5/27/2010 at 4:50:49 PM

Gonzo 5/29/2010 10:43:08 AM ARM Page 1 of 3

### ===================================================================== Agilent 1100/1200 Quaternary Pump 1

=====================================================================

Control Column Flow : 1.200 ml/min Stoptime : 15.00 min Posttime : Off

Solvents Solvent A : 100.0 % (8mM Na2CO3/1mM NaHCO3) Solvent B : Off Solvent C : Off Solvent D : Off

PressureLimits Minimum Pressure : 0 bar Maximum Pressure : 400 bar

Auxiliary Maximal Flow Ramp : 100.00 ml/min^2 Primary Channel : Auto Compressibility : 83*10^-6/bar Minimal Stroke : Auto

Store Parameters Store Ratio A : Yes Store Ratio B : Yes Store Ratio C : Yes Store Ratio D : Yes Store Flow : Yes Store Pressure : Yes

===================================================================== Agilent 1100 Variable Wavelength Detector 1

=====================================================================
Signal Wavelength : 210 nm Peakwidth : > 0.1 min

Time Stoptime : As pump Posttime : Off

Analog Output Zero offset analog out.: 5 % Attenuation analog out.: 1000 mAU
Store Additionally Signal w/o Reference : No Reference : No

Autobalance Prerun balancing : Yes Postrun balancing : No
Special Parameters Margin for negative Absorbance: 100 mAU Signal Polarity : Positive Enable analysis when lamp is off: No Scan from : 190 nm method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Modified on: 5/27/2010 at 4:50:49 PM

Gonzo 5/29/2010 10:43:08 AM ARM Page 2 of 3

### Scan to : 400 nm Scan step : 2 nm

===================================================================== Agilent 1100 Autosampler 1

=====================================================================
Injection Injection Mode : Needle Wash Injector volume : 25.00 μl Wash Vial : 100 Optimization : Prefetch Sample Vial 12.00 min. after Injection
Auxiliary Drawspeed : 100 μl/min Ejectspeed : 1000 μl/min Draw position : 2.0 mm

Time Stoptime : As Pump Posttime : Off

===================================================================== Agilent 1100/1200 Column Thermostat 1

=====================================================================
Temperature settings Left temperature : 30.0°C Right temperature : Same as left Enable analysis : When Temp. is within setpoint +/- 0.8°C Store left temperature : No Store right temperature: No

Time Stoptime : As pump Posttime : Off
Column Switching Valve : Column 1 method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M Modified on: 5/27/2010 at 4:50:49 PM

Gonzo 5/29/2010 10:43:08 AM ARM Page 3 of 3

### Sequence: C:\HPCHEM\1\SEQUENCE\hplc49pg26ARM.txt
Line Vial Sample Name Method Inj 1 Vial 7 MB/ DI H2O ANIONS 1 2 Vial 1 hplc49pg22 #1 ANIONS 2 3 Vial 1 hplc49pg22 #1 ANIONS 2 4 Vial 2 hplc49pg22 #2 ANIONS 2 5 Vial 3 hplc49pg22 #3 ANIONS 2 6 Vial 4 hplc49pg22 #4 ANIONS 2 7 Vial 5 hplc49pg22 #5 ANIONS 2 8 Vial 6 hplc49pg22 #LCS ANIONS 2 9 Vial 7 MB/ DI H2O ANIONS 2 10 Vial 11 Run 1 *50 0610-27 ANIONS 2 11 Vial 12 MS Run 1 0610-27 ANIONS 2 12 Vial 13 MSD Run 1 0610-27 ANIONS 2 13 Vial 14 Run 5 *50 0610-27 ANIONS 2 14 Vial 15 Run 6 *50 0610-27 ANIONS 2 15 Vial 21 Run 1 Post *20 0410-11 ANIONS 2 16 Vial 22 MS Run 1 Post 0410-11 ANIONS 2 17 Vial 23 MSD Run 1 Post 0410-11 ANIONS 2 18 Vial 24 Run 2 Post *20 0410-11 ANIONS 2 19 Vial 25 Run 3 Post *20 0410-11 ANIONS 2 20 Vial 3 hplc49pg22 #3 ANIONS 2 21 Vial 4 hplc49pg22 #4 ANIONS 2 22 Vial 26 Train Blank Post 0410-11 ANIONS 2 23 Vial 27 In House Blank Post 0410-11 ANIONS 2 24 Vial 3 hplc49pg22 #3 ANIONS 2 25 Vial 4 hplc49pg22 #4 ANIONS 2

# This Is The Last Page Of This Report.

### 6/7/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood MO 63042

Project Name: KCP&ICR Testing La Cygne Project #: 100-208

Dear Mr. Frank Stevens
The following report includes the data for the above referenced project for sample(s) received on 5/21/2010 at Air Toxics Ltd. The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Jacquelyn Luta at 916-985-1000 if you have any questions regarding the data in this report.

Regards,

Jacquelyn Luta Project Manager Workorder #: 1005506A

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020 Hours 6:30 A.M to 5:30 PST

Page 1 of 76

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1005506A

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 05/21/2010 DATE COMPLETED: 

### 06/06/2010 P.O. #
PROJECT # 

### 100-208 KCP&ICR Testing La Cygne 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Jacquelyn Luta

NAME FRACTION # TEST 

### 01AB M0031-R1-TS1-C1/C2-Tenax Modified VOST 5041A/8260 01C M0031-R1-TS1-C4-Anasorb Modified VOST 5041A/8260 02AB M0031-R1-TS2-C1/C2-Tenax Modified VOST 5041A/8260 02C M0031-R1-TS2-C4-Anasorb Modified VOST 5041A/8260 03AB M0031-R1-TS3-C1/C2-Tenax Modified VOST 5041A/8260 03C M0031-R1-TS3-C4-Anasorb Modified VOST 5041A/8260 04AB(cancelled) M0031-R1-TS4-C1/C2-Tenax Modified VOST 5041A/8260 04C M0031-R1-TS4-C4-Anasorb Modified VOST 5041A/8260 05A M0031-R1-TS4-C3-Codensate Modified VOST 5041A/8260 06AB M0031-R2-TS1-C1/C2-Tenax Modified VOST 5041A/8260 06C M0031-R2-TS1-C4-Anasorb Modified VOST 5041A/8260 07AB M0031-R2-TS2-C1/C2-Tenax Modified VOST 5041A/8260 07C M0031-R2-TS2-C4-Anasorb Modified VOST 5041A/8260 08AB M0031-R2-TS3-C1/C2-Tenax Modified VOST 5041A/8260 08C M0031-R2-TS3-C4-Anasorb Modified VOST 5041A/8260 09AB M0031-R2-TS4-C1/C2-Tenax Modified VOST 5041A/8260 09C(cancelled) M0031-R2-TS4-C4-Anasorb Modified VOST 5041A/8260

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 2 of 76 

### Continued on next page

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1005506A

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 05/21/2010 DATE COMPLETED: 

### 06/06/2010 P.O. #
PROJECT # 

### 100-208 KCP&ICR Testing La Cygne 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Jacquelyn Luta

NAME FRACTION # TEST 

### 10A M0031-R2-TS4-C3-Condensate Modified VOST 5041A/8260 11A Lab Blank Modified VOST 5041A/8260 11B Lab Blank Modified VOST 5041A/8260 11C Lab Blank Modified VOST 5041A/8260 12A LCS Modified VOST 5041A/8260 12B LCS Modified VOST 5041A/8260 12C LCS Modified VOST 5041A/8260

CERTIFIED BY: Laboratory Director DATE:



### Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act,

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020 

### 06/07/10

Page 3 of 76 This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd. 

### Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719

## LABORATORY NARRATIVE VOST 5041A Civil & Environmental Consultants, Inc. Workorder# 1005506A Laboratory Services Since 1989



## Twenty-four VOST 0031 Tube and two VOA Vial-40 mL samples were received on May 21, 2010. The laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components into the GC/MS system for further separation. See the data sheets for the reporting limits for each compound.
Requirement ATL Modifications VOST 5041A 

### Batch Certification Blanks from the same media as samples Analysis of set of cartridges prior to onset of any project; Sampling media provided by the client is batch certified ahead of time, only if client provides blank cartridges.
Method blank Cartridges from the same media batches as the samples Media batch is certified prior to use in the field. Method Blank is used to certify instrument is contaminant free

Connection between cartridge thermal desorption apparatus & sample purge vessel PTFE 1/16" Teflon tubing Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for non-CCCs RSD +- 15 % for all non-CCCs RSD </= 30 % for some compounds: Acetone, Bromoform, Vinyl Acetate, Bromomethane, Chloromethane, 1,1,2,2-Tetracholoroethane, & 1,2,3-Trichloropropane



## Receiving Notes Sample collection date was not provided on the Chain of Custody (COC) for all samples. The sampling dates were taken from the tags.

Per client request, compounds that are not validated under Method 0031 collection protocols were reported in this work order. These compounds may not be suitable for collection by Method 0031 due to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory analytical method 5041A/8260B is validated for all target analytes.
Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the Anasorb. In addition the laboratory method has not been validated for recovery of these additional compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Due to instrument malfunction, samples M0031-R1-TS4-C1/C2-Tenax and M0031-R2-TS4-C4-Anasorb were lost during final analysis. Reporting is not possible for those samples. Analytical Notes

Page 4 of 76Laboratory Services Since 1989



## The recovery of surrogate Toluene-d8 in samples M0031-R1-TS1-C4-Anasorb, M0031-R1-TS2-C4-Anasorb, M0031-R1-TS3-C4-Anasorb, M0031-R1-TS4-C4-Anasorb, M0031-R2-TS1-C4-Anasorb, M0031-R2-TS2-C4-Anasorb and M0031-R2-TS3-C4-Anasorb was outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as qualified.

The recovery of surrogate 4-Bromofluorobenzene in samples M0031-R1-TS3-C1/C2-Tenax, M0031-R2-TS1-C1/C2-Tenax, and M0031-R2-TS2-C1/C2-Tenax was outside control limits due to high level matrix interference. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target compound non-detects in the samples that are associated with high bias in QC analyses have not been flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows: B

- Compound present in laboratory blank or tube certification greater than reporting limit (background subtraction not performed). J

- Estimated value. E

- Exceeds instrument calibration range. S

- Saturated peak. Q

- Exceeds quality control limits. U

- Compound analyzed for but not detected above the detection limit. N

- The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags

Page 5 of 76

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R1-TS1-C1/C2-Tenax
Lab ID#: 1005506A-01AB
(ng) (ng) Compound Amount Rpt. Limit

10 11 Bromomethane 10 75 Methylene Chloride 10 23 Hexane 10 50 Benzene 10 63 Toluene 10 16 Ethyl Benzene 10 72 m,p-Xylene 10 18 o-Xylene 10 16 Styrene 10 17 1,2,4-Trimethylbenzene 10 13 p-Cymene



### Client Sample ID: M0031-R1-TS1-C4-Anasorb
Lab ID#: 1005506A-01C
(ng) (ng) Compound Amount Rpt. Limit

50 330 Chloromethane 10 14 Bromomethane 10 13 Freon 11 10 54 Methylene Chloride 10 79 Freon 12



### Client Sample ID: M0031-R1-TS2-C1/C2-Tenax
Lab ID#: 1005506A-02AB
(ng) (ng) Compound Amount Rpt. Limit

50 170 Chloromethane 10 15 Bromomethane 50 62 Acetone 10 16 Hexane 10 22 Benzene 10 30 Toluene 10 23 m,p-Xylene

Page 6 of 76

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R1-TS2-C4-Anasorb
Lab ID#: 1005506A-02C
(ng) (ng) Compound Amount Rpt. Limit

50 160 Chloromethane 10 14 Bromomethane 10 22 Freon 12



### Client Sample ID: M0031-R1-TS3-C1/C2-Tenax
Lab ID#: 1005506A-03AB
(ng) (ng) Compound Amount Rpt. Limit

50 64 Chloromethane 10 27 Bromomethane 10 12 Carbon Disulfide 50 73 Acetone 10 14 Hexane 10 23 Benzene 10 34 Toluene 10 22 m,p-Xylene



### Client Sample ID: M0031-R1-TS3-C4-Anasorb
Lab ID#: 1005506A-03C
(ng) (ng) Compound Amount Rpt. Limit

50 520 Chloromethane 10 16 Bromomethane 10 28 Freon 12



### Client Sample ID: M0031-R1-TS4-C4-Anasorb
Lab ID#: 1005506A-04C
(ng) (ng) Compound Amount Rpt. Limit

50 140 Chloromethane 10 38 Freon 12



### Client Sample ID: M0031-R1-TS4-C3-Codensate
Lab ID#: 1005506A-05A
Page 7 of 76

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R1-TS4-C3-Codensate
Lab ID#: 1005506A-05A
(ng) (ng) Compound Amount Rpt. Limit

400 700 Acetone 80 940 Methylene Chloride 400 520 2-Butanone (Methyl Ethyl Ketone) 80 95 Chloroform



### Client Sample ID: M0031-R2-TS1-C1/C2-Tenax
Lab ID#: 1005506A-06AB
(ng) (ng) Compound Amount Rpt. Limit

50 110 Chloromethane 10 47 Bromomethane 10 13 Carbon Disulfide 50 64 Acetone 10 14 Methylene Chloride 10 12 Hexane 10 40 Benzene 10 25 Toluene 10 10 m,p-Xylene



### Client Sample ID: M0031-R2-TS1-C4-Anasorb
Lab ID#: 1005506A-06C
(ng) (ng) Compound Amount Rpt. Limit

10 25 Freon 12



### Client Sample ID: M0031-R2-TS2-C1/C2-Tenax
Lab ID#: 1005506A-07AB
(ng) (ng) Compound Amount Rpt. Limit

10 14 trans-1,2-Dichloroethene 10 12 Hexane 10 24 Benzene 10 17 Toluene

Page 8 of 76

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R2-TS2-C4-Anasorb
Lab ID#: 1005506A-07C
(ng) (ng) Compound Amount Rpt. Limit

50 420 Chloromethane 10 22 Freon 12



### Client Sample ID: M0031-R2-TS3-C1/C2-Tenax
Lab ID#: 1005506A-08AB
(ng) (ng) Compound Amount Rpt. Limit

10 11 Bromomethane 10 11 Carbon Disulfide 10 17 Methylene Chloride 10 12 Hexane 10 23 Benzene 10 17 Toluene



### Client Sample ID: M0031-R2-TS3-C4-Anasorb
Lab ID#: 1005506A-08C
(ng) (ng) Compound Amount Rpt. Limit

50 63 Chloromethane 10 30 Methylene Chloride 10 41 Freon 12



### Client Sample ID: M0031-R2-TS4-C1/C2-Tenax
Lab ID#: 1005506A-09AB
(ng) (ng) Compound Amount Rpt. Limit

10 11 Bromomethane 10 11 Carbon Disulfide 10 21 Methylene Chloride 10 11 Hexane 10 21 Benzene 10 20 Toluene

Page 9 of 76

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R2-TS4-C3-Condensate
Lab ID#: 1005506A-10A
(ng) (ng) Compound Amount Rpt. Limit

400 780 Acetone 80 980 Methylene Chloride 400 590 2-Butanone (Methyl Ethyl Ketone) 80 96 Chloroform

Page 10 of 76

### Client Sample ID: M0031-R1-TS1-C1/C2-Tenax Lab ID#: 1005506A-01AB MODIFIED VOST 5041A/8260B

10052630 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 09:18 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 11 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 75 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 23 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 50 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 63 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 11 of 76

### Client Sample ID: M0031-R1-TS1-C1/C2-Tenax Lab ID#: 1005506A-01AB MODIFIED VOST 5041A/8260B

10052630 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 09:18 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 16 Ethyl Benzene 10 72 m,p-Xylene 10 18 o-Xylene 10 16 Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 17 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 13 p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

96 70-130 Dibromofluoromethane

Page 12 of 76

### Client Sample ID: M0031-R1-TS1-C1/C2-Tenax Lab ID#: 1005506A-01AB MODIFIED VOST 5041A/8260B

10052630 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 09:18 PM

Limits %Recovery Surrogates Method

95 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 93 70-130 4-Bromofluorobenzene

Page 13 of 76

### Client Sample ID: M0031-R1-TS1-C4-Anasorb Lab ID#: 1005506A-01C MODIFIED VOST 5041A/8260B

10052625 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:04 PM

(ng) (ng) Compound Amount Rpt. Limit

50 330 Chloromethane 10 Not Detected Vinyl Chloride 10 14 Bromomethane 50 Not Detected Chloroethane 10 13 Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 54 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 14 of 76

### Client Sample ID: M0031-R1-TS1-C4-Anasorb Lab ID#: 1005506A-01C MODIFIED VOST 5041A/8260B

10052625 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:04 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 79 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 15 of 76

### Client Sample ID: M0031-R1-TS1-C4-Anasorb Lab ID#: 1005506A-01C MODIFIED VOST 5041A/8260B

10052625 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:04 PM

Limits %Recovery Surrogates Method

71 50-150 Dibromofluoromethane 55 50-150 1,2-Dichloroethane-d4 17 Q 50-150 Toluene-d8

Page 16 of 76

### Client Sample ID: M0031-R1-TS2-C1/C2-Tenax Lab ID#: 1005506A-02AB MODIFIED VOST 5041A/8260B

10052631 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 09:43 PM

(ng) (ng) Compound Amount Rpt. Limit

50 170 Chloromethane 10 Not Detected Vinyl Chloride 10 15 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 62 Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 16 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 22 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 30 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 17 of 76

### Client Sample ID: M0031-R1-TS2-C1/C2-Tenax Lab ID#: 1005506A-02AB MODIFIED VOST 5041A/8260B

10052631 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 09:43 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 23 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

89 70-130 Dibromofluoromethane

Page 18 of 76

### Client Sample ID: M0031-R1-TS2-C1/C2-Tenax Lab ID#: 1005506A-02AB MODIFIED VOST 5041A/8260B

10052631 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 09:43 PM

Limits %Recovery Surrogates Method

84 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 72 70-130 4-Bromofluorobenzene

Page 19 of 76

### Client Sample ID: M0031-R1-TS2-C4-Anasorb Lab ID#: 1005506A-02C MODIFIED VOST 5041A/8260B

10052626 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:31 PM

(ng) (ng) Compound Amount Rpt. Limit

50 160 Chloromethane 10 Not Detected Vinyl Chloride 10 14 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 20 of 76

### Client Sample ID: M0031-R1-TS2-C4-Anasorb Lab ID#: 1005506A-02C MODIFIED VOST 5041A/8260B

10052626 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:31 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 22 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 21 of 76

### Client Sample ID: M0031-R1-TS2-C4-Anasorb Lab ID#: 1005506A-02C MODIFIED VOST 5041A/8260B

10052626 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:31 PM

Limits %Recovery Surrogates Method

79 50-150 Dibromofluoromethane 65 50-150 1,2-Dichloroethane-d4 24 Q 50-150 Toluene-d8

Page 22 of 76

### Client Sample ID: M0031-R1-TS3-C1/C2-Tenax Lab ID#: 1005506A-03AB MODIFIED VOST 5041A/8260B

10052632 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 10:11 PM

(ng) (ng) Compound Amount Rpt. Limit

50 64 Chloromethane 10 Not Detected Vinyl Chloride 10 27 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 12 Carbon Disulfide 50 73 Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 14 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 23 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 34 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 23 of 76

### Client Sample ID: M0031-R1-TS3-C1/C2-Tenax Lab ID#: 1005506A-03AB MODIFIED VOST 5041A/8260B

10052632 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 10:11 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 22 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 24 of 76

### Client Sample ID: M0031-R1-TS3-C1/C2-Tenax Lab ID#: 1005506A-03AB MODIFIED VOST 5041A/8260B

10052632 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 10:11 PM

Limits %Recovery Surrogates Method

90 70-130 Dibromofluoromethane 82 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 62 Q 70-130 4-Bromofluorobenzene

Page 25 of 76

### Client Sample ID: M0031-R1-TS3-C4-Anasorb Lab ID#: 1005506A-03C MODIFIED VOST 5041A/8260B

10052627 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:58 PM

(ng) (ng) Compound Amount Rpt. Limit

50 520 Chloromethane 10 Not Detected Vinyl Chloride 10 16 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 26 of 76

### Client Sample ID: M0031-R1-TS3-C4-Anasorb Lab ID#: 1005506A-03C MODIFIED VOST 5041A/8260B

10052627 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:58 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 28 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 27 of 76

### Client Sample ID: M0031-R1-TS3-C4-Anasorb Lab ID#: 1005506A-03C MODIFIED VOST 5041A/8260B

10052627 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 07:58 PM

Limits %Recovery Surrogates Method

74 50-150 Dibromofluoromethane 59 50-150 1,2-Dichloroethane-d4 23 Q 50-150 Toluene-d8

Page 28 of 76

### Client Sample ID: M0031-R1-TS4-C4-Anasorb Lab ID#: 1005506A-04C MODIFIED VOST 5041A/8260B

10052706 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 01:18 AM

(ng) (ng) Compound Amount Rpt. Limit

50 140 Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 29 of 76

### Client Sample ID: M0031-R1-TS4-C4-Anasorb Lab ID#: 1005506A-04C MODIFIED VOST 5041A/8260B

10052706 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 01:18 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 38 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 30 of 76

### Client Sample ID: M0031-R1-TS4-C4-Anasorb Lab ID#: 1005506A-04C MODIFIED VOST 5041A/8260B

10052706 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 01:18 AM

Limits %Recovery Surrogates Method

67 50-150 Dibromofluoromethane 53 50-150 1,2-Dichloroethane-d4 18 Q 50-150 Toluene-d8

Page 31 of 76

### Client Sample ID: M0031-R1-TS4-C3-Codensate Lab ID#: 1005506A-05A MODIFIED VOST 5041A/8260B

10052623 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 03:44 PM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 700 Acetone 400 Not Detected 3-Chloropropene 80 940 Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 520 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 95 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 32 of 76

### Client Sample ID: M0031-R1-TS4-C3-Codensate Lab ID#: 1005506A-05A MODIFIED VOST 5041A/8260B

10052623 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 03:44 PM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

97 70-130 Dibromofluoromethane

Page 33 of 76

### Client Sample ID: M0031-R1-TS4-C3-Codensate Lab ID#: 1005506A-05A MODIFIED VOST 5041A/8260B

10052623 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 03:44 PM

Limits %Recovery Surrogates Method

104 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 101 70-130 4-Bromofluorobenzene

Page 34 of 76

### Client Sample ID: M0031-R2-TS1-C1/C2-Tenax Lab ID#: 1005506A-06AB MODIFIED VOST 5041A/8260B

10052714 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 05:36 AM

(ng) (ng) Compound Amount Rpt. Limit

50 110 Chloromethane 10 Not Detected Vinyl Chloride 10 47 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 13 Carbon Disulfide 50 64 Acetone 50 Not Detected 3-Chloropropene 10 14 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 12 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 40 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 25 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 35 of 76

### Client Sample ID: M0031-R2-TS1-C1/C2-Tenax Lab ID#: 1005506A-06AB MODIFIED VOST 5041A/8260B

10052714 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 05:36 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 10 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 36 of 76

### Client Sample ID: M0031-R2-TS1-C1/C2-Tenax Lab ID#: 1005506A-06AB MODIFIED VOST 5041A/8260B

10052714 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 05:36 AM

Limits %Recovery Surrogates Method

90 70-130 Dibromofluoromethane 82 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 28 Q 70-130 4-Bromofluorobenzene

Page 37 of 76

### Client Sample ID: M0031-R2-TS1-C4-Anasorb Lab ID#: 1005506A-06C MODIFIED VOST 5041A/8260B

10052707 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 01:46 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 38 of 76

### Client Sample ID: M0031-R2-TS1-C4-Anasorb Lab ID#: 1005506A-06C MODIFIED VOST 5041A/8260B

10052707 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 01:46 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 25 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 39 of 76

### Client Sample ID: M0031-R2-TS1-C4-Anasorb Lab ID#: 1005506A-06C MODIFIED VOST 5041A/8260B

10052707 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 01:46 AM

Limits %Recovery Surrogates Method

84 50-150 Dibromofluoromethane 70 50-150 1,2-Dichloroethane-d4 28 Q 50-150 Toluene-d8

Page 40 of 76

### Client Sample ID: M0031-R2-TS2-C1/C2-Tenax Lab ID#: 1005506A-07AB MODIFIED VOST 5041A/8260B

10052715 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 06:22 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 14 trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 12 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 24 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 17 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 41 of 76

### Client Sample ID: M0031-R2-TS2-C1/C2-Tenax Lab ID#: 1005506A-07AB MODIFIED VOST 5041A/8260B

10052715 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 06:22 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 42 of 76

### Client Sample ID: M0031-R2-TS2-C1/C2-Tenax Lab ID#: 1005506A-07AB MODIFIED VOST 5041A/8260B

10052715 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 06:22 AM

Limits %Recovery Surrogates Method

95 70-130 Dibromofluoromethane 85 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 55 Q 70-130 4-Bromofluorobenzene

Page 43 of 76

### Client Sample ID: M0031-R2-TS2-C4-Anasorb Lab ID#: 1005506A-07C MODIFIED VOST 5041A/8260B

10052708 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 02:38 AM

(ng) (ng) Compound Amount Rpt. Limit

50 420 Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 44 of 76

### Client Sample ID: M0031-R2-TS2-C4-Anasorb Lab ID#: 1005506A-07C MODIFIED VOST 5041A/8260B

10052708 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 02:38 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 22 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 45 of 76

### Client Sample ID: M0031-R2-TS2-C4-Anasorb Lab ID#: 1005506A-07C MODIFIED VOST 5041A/8260B

10052708 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 02:38 AM

Limits %Recovery Surrogates Method

76 50-150 Dibromofluoromethane 62 50-150 1,2-Dichloroethane-d4 25 Q 50-150 Toluene-d8

Page 46 of 76

### Client Sample ID: M0031-R2-TS3-C1/C2-Tenax Lab ID#: 1005506A-08AB MODIFIED VOST 5041A/8260B

10060106 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 10:53 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 11 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 11 Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 17 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 12 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 23 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 17 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 47 of 76

### Client Sample ID: M0031-R2-TS3-C1/C2-Tenax Lab ID#: 1005506A-08AB MODIFIED VOST 5041A/8260B

10060106 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 10:53 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

84 70-130 Dibromofluoromethane

Page 48 of 76

### Client Sample ID: M0031-R2-TS3-C1/C2-Tenax Lab ID#: 1005506A-08AB MODIFIED VOST 5041A/8260B

10060106 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 10:53 AM

Limits %Recovery Surrogates Method

78 70-130 1,2-Dichloroethane-d4 88 70-130 Toluene-d8 75 70-130 4-Bromofluorobenzene

Page 49 of 76

### Client Sample ID: M0031-R2-TS3-C4-Anasorb Lab ID#: 1005506A-08C MODIFIED VOST 5041A/8260B

10052709 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 03:02 AM

(ng) (ng) Compound Amount Rpt. Limit

50 63 Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 30 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 50 of 76

### Client Sample ID: M0031-R2-TS3-C4-Anasorb Lab ID#: 1005506A-08C MODIFIED VOST 5041A/8260B

10052709 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 03:02 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 41 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 51 of 76

### Client Sample ID: M0031-R2-TS3-C4-Anasorb Lab ID#: 1005506A-08C MODIFIED VOST 5041A/8260B

10052709 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/27/10 03:02 AM

Limits %Recovery Surrogates Method

79 50-150 Dibromofluoromethane 64 50-150 1,2-Dichloroethane-d4 24 Q 50-150 Toluene-d8

Page 52 of 76

### Client Sample ID: M0031-R2-TS4-C1/C2-Tenax Lab ID#: 1005506A-09AB MODIFIED VOST 5041A/8260B

10060107 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 11:23 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 11 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 11 Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 21 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 11 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 21 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 20 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 53 of 76

### Client Sample ID: M0031-R2-TS4-C1/C2-Tenax Lab ID#: 1005506A-09AB MODIFIED VOST 5041A/8260B

10060107 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 11:23 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

94 70-130 Dibromofluoromethane

Page 54 of 76

### Client Sample ID: M0031-R2-TS4-C1/C2-Tenax Lab ID#: 1005506A-09AB MODIFIED VOST 5041A/8260B

10060107 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 11:23 AM

Limits %Recovery Surrogates Method

90 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 74 70-130 4-Bromofluorobenzene

Page 55 of 76

### Client Sample ID: M0031-R2-TS4-C3-Condensate Lab ID#: 1005506A-10A MODIFIED VOST 5041A/8260B

10052624 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 04:10 PM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 780 Acetone 400 Not Detected 3-Chloropropene 80 980 Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 590 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 96 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 56 of 76

### Client Sample ID: M0031-R2-TS4-C3-Condensate Lab ID#: 1005506A-10A MODIFIED VOST 5041A/8260B

10052624 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 04:10 PM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

104 70-130 Dibromofluoromethane

Page 57 of 76

### Client Sample ID: M0031-R2-TS4-C3-Condensate Lab ID#: 1005506A-10A MODIFIED VOST 5041A/8260B

10052624 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 5/26/10 04:10 PM

Limits %Recovery Surrogates Method

112 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 110 70-130 4-Bromofluorobenzene

Page 58 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11A MODIFIED VOST 5041A/8260B

10052622 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/26/10 03:07 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 59 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11A MODIFIED VOST 5041A/8260B

10052622 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/26/10 03:07 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

108 70-130 Dibromofluoromethane

Page 60 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11A MODIFIED VOST 5041A/8260B

10052622 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/26/10 03:07 PM

Limits %Recovery Surrogates Method

119 70-130 1,2-Dichloroethane-d4 117 70-130 Toluene-d8 116 70-130 4-Bromofluorobenzene

Page 61 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11B MODIFIED VOST 5041A/8260B

10052705 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/27/10 12:33 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 62 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11B MODIFIED VOST 5041A/8260B

10052705 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/27/10 12:33 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

98 70-130 Dibromofluoromethane

Page 63 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11B MODIFIED VOST 5041A/8260B

10052705 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/27/10 12:33 AM

Limits %Recovery Surrogates Method

104 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 106 70-130 4-Bromofluorobenzene

Page 64 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11C MODIFIED VOST 5041A/8260B

10060104 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:37 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 65 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11C MODIFIED VOST 5041A/8260B

10060104 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:37 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

100 70-130 Dibromofluoromethane

Page 66 of 76

### Client Sample ID: Lab Blank Lab ID#: 1005506A-11C MODIFIED VOST 5041A/8260B

10060104 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:37 AM

Limits %Recovery Surrogates Method

102 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 92 70-130 4-Bromofluorobenzene

Page 67 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12A MODIFIED VOST 5041A/8260B

10052621 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/26/10 02:33 PM

%Recovery Compound
119 Chloromethane 110 Vinyl Chloride 120 Bromomethane 105 Chloroethane 108 Freon 11 129 2-Chloropropane 102 1,1-Dichloroethene 126 Freon 113 135 Q Carbon Disulfide 180 Q Acetone 123 3-Chloropropene 150 Q Methylene Chloride 113 trans-1,2-Dichloroethene 121 Acrylonitrile 125 Hexane 105 1,1-Dichloroethane Not Spiked Vinyl Acetate 93 2,2-Dichloropropane 102 cis-1,2-Dichloroethene 164 Q 2-Butanone (Methyl Ethyl Ketone) 108 Bromochloromethane 106 Chloroform 102 1,1,1-Trichloroethane 102 Carbon Tetrachloride 106 1,1-Dichloropropene 106 Benzene 111 1,2-Dichloroethane 106 Trichloroethene 104 1,2-Dichloropropane 107 Dibromomethane 91 Bromodichloromethane 96 cis-1,3-Dichloropropene 99 trans-1,3-Dichloropropene 110 4-Methyl-2-pentanone 106 Toluene 109 1,1,2-Trichloroethane 107 Tetrachloroethene 109 1,3-Dichloropropane 138 2-Hexanone

Page 68 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12A MODIFIED VOST 5041A/8260B

10052621 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/26/10 02:33 PM

%Recovery Compound
89 Dibromochloromethane 109 Chlorobenzene 106 1,2-Dibromoethane (EDB) 105 Ethyl Benzene 108 m,p-Xylene 98 o-Xylene 96 Styrene 73 Bromoform 105 1,1,2,2-Tetrachloroethane 101 1,3-Dichlorobenzene 97 1,4-Dichlorobenzene 97 1,2-Dichlorobenzene 115 Cumene 88 cis-1,4-Dichloro-2-butene 99 Bromobenzene 110 1,2,3-Trichloropropane 98 trans-1,4-Dichloro-2-butene 97 Propylbenzene 96 2-Chlorotoluene 99 4-Chlorotoluene 97 1,3,5-Trimethylbenzene 96 tert-Butylbenzene 94 1,2,4-Trimethylbenzene 97 sec-Butylbenzene 95 p-Cymene 66 Q 1,2-Dibromo-3-chloropropane 95 1,2,4-Trichlorobenzene 94 Naphthalene 93 Hexachlorobutadiene 92 1,2,3-Trichlorobenzene 99 1,1,1,2-Tetrachloroethane 91 Butylbenzene 127 Iodomethane 82 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 69 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12A MODIFIED VOST 5041A/8260B

10052621 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/26/10 02:33 PM

Limits %Recovery Surrogates Method

106 70-130 Dibromofluoromethane 109 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 106 70-130 4-Bromofluorobenzene

Page 70 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12B MODIFIED VOST 5041A/8260B

10052704 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/27/10 12:09 AM

%Recovery Compound
139 Chloromethane 125 Vinyl Chloride 129 Bromomethane 122 Chloroethane 114 Freon 11 134 Q 2-Chloropropane 108 1,1-Dichloroethene 130 Freon 113 146 Q Carbon Disulfide 110 Acetone 128 3-Chloropropene 108 Methylene Chloride 118 trans-1,2-Dichloroethene 114 Acrylonitrile 135 Q Hexane 111 1,1-Dichloroethane Not Spiked Vinyl Acetate 97 2,2-Dichloropropane 106 cis-1,2-Dichloroethene 115 2-Butanone (Methyl Ethyl Ketone) 110 Bromochloromethane 110 Chloroform 106 1,1,1-Trichloroethane 102 Carbon Tetrachloride 110 1,1-Dichloropropene 110 Benzene 113 1,2-Dichloroethane 109 Trichloroethene 108 1,2-Dichloropropane 108 Dibromomethane 91 Bromodichloromethane 98 cis-1,3-Dichloropropene 102 trans-1,3-Dichloropropene 92 4-Methyl-2-pentanone 110 Toluene 109 1,1,2-Trichloroethane 110 Tetrachloroethene 111 1,3-Dichloropropane 97 2-Hexanone

Page 71 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12B MODIFIED VOST 5041A/8260B

10052704 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/27/10 12:09 AM

%Recovery Compound
86 Dibromochloromethane 112 Chlorobenzene 104 1,2-Dibromoethane (EDB) 106 Ethyl Benzene 112 m,p-Xylene 101 o-Xylene 97 Styrene 67 Q Bromoform 103 1,1,2,2-Tetrachloroethane 105 1,3-Dichlorobenzene 101 1,4-Dichlorobenzene 99 1,2-Dichlorobenzene 120 Cumene 84 cis-1,4-Dichloro-2-butene 102 Bromobenzene 108 1,2,3-Trichloropropane 95 trans-1,4-Dichloro-2-butene 104 Propylbenzene 102 2-Chlorotoluene 104 4-Chlorotoluene 103 1,3,5-Trimethylbenzene 104 tert-Butylbenzene 100 1,2,4-Trimethylbenzene 105 sec-Butylbenzene 105 p-Cymene 56 Q 1,2-Dibromo-3-chloropropane 97 1,2,4-Trichlorobenzene 88 Naphthalene 107 Hexachlorobutadiene 95 1,2,3-Trichlorobenzene 99 1,1,1,2-Tetrachloroethane 101 Butylbenzene 133 Q Iodomethane 100 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 72 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12B MODIFIED VOST 5041A/8260B

10052704 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/27/10 12:09 AM

Limits %Recovery Surrogates Method

108 70-130 Dibromofluoromethane 110 70-130 1,2-Dichloroethane-d4 111 70-130 Toluene-d8 111 70-130 4-Bromofluorobenzene

Page 73 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12C MODIFIED VOST 5041A/8260B

10060103 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:13 AM

%Recovery Compound
116 Chloromethane 101 Vinyl Chloride 100 Bromomethane 98 Chloroethane 105 Freon 11 109 2-Chloropropane 100 1,1-Dichloroethene 116 Freon 113 124 Carbon Disulfide 109 Acetone 118 3-Chloropropene 104 Methylene Chloride 109 trans-1,2-Dichloroethene 96 Acrylonitrile 114 Hexane 99 1,1-Dichloroethane Not Spiked Vinyl Acetate 99 2,2-Dichloropropane 94 cis-1,2-Dichloroethene 119 2-Butanone (Methyl Ethyl Ketone) 95 Bromochloromethane 98 Chloroform 99 1,1,1-Trichloroethane 98 Carbon Tetrachloride 104 1,1-Dichloropropene 100 Benzene 97 1,2-Dichloroethane 100 Trichloroethene 100 1,2-Dichloropropane 97 Dibromomethane 95 Bromodichloromethane 99 cis-1,3-Dichloropropene 102 trans-1,3-Dichloropropene 97 4-Methyl-2-pentanone 97 Toluene 96 1,1,2-Trichloroethane 100 Tetrachloroethene 94 1,3-Dichloropropane 129 2-Hexanone

Page 74 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12C MODIFIED VOST 5041A/8260B

10060103 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:13 AM

%Recovery Compound
95 Dibromochloromethane 97 Chlorobenzene 96 1,2-Dibromoethane (EDB) 100 Ethyl Benzene 99 m,p-Xylene 99 o-Xylene 101 Styrene 94 Bromoform 91 1,1,2,2-Tetrachloroethane 101 1,3-Dichlorobenzene 100 1,4-Dichlorobenzene 101 1,2-Dichlorobenzene 117 Cumene 86 cis-1,4-Dichloro-2-butene 96 Bromobenzene 95 1,2,3-Trichloropropane 88 trans-1,4-Dichloro-2-butene 100 Propylbenzene 98 2-Chlorotoluene 101 4-Chlorotoluene 101 1,3,5-Trimethylbenzene 102 tert-Butylbenzene 102 1,2,4-Trimethylbenzene 103 sec-Butylbenzene 103 p-Cymene 93 1,2-Dibromo-3-chloropropane 106 1,2,4-Trichlorobenzene 98 Naphthalene 121 Hexachlorobutadiene 107 1,2,3-Trichlorobenzene 100 1,1,1,2-Tetrachloroethane 101 Butylbenzene 115 Iodomethane 103 Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

103 70-130 Dibromofluoromethane

Page 75 of 76

### Client Sample ID: LCS Lab ID#: 1005506A-12C MODIFIED VOST 5041A/8260B

10060103 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:13 AM

Limits %Recovery Surrogates Method

104 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 96 70-130 4-Bromofluorobenzene

Page 76 of 76

### 6/7/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood MO 63042

Project Name: KCP&ICR Testing La Cygne Project #: 100-208

Dear Mr. Frank Stevens
The following report includes the data for the above referenced project for sample(s) received on 5/21/2010 at Air Toxics Ltd. The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Jacquelyn Luta at 916-985-1000 if you have any questions regarding the data in this report.

Regards,

Jacquelyn Luta Project Manager Workorder #: 1005506B

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020 Hours 6:30 A.M to 5:30 PST

Page 1 of 49

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1005506B

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 05/21/2010 DATE COMPLETED: 

### 06/06/2010 P.O. #
PROJECT # 

### 100-208 KCP&ICR Testing La Cygne 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Jacquelyn Luta

NAME FRACTION # TEST 

### 11AB M0031-R3-TS1-C1/C2-Tenax Modified VOST 5041A/8260 11C(cancelled) M0031-R3-TS1-C4-Anasorb Modified VOST 5041A/8260 12AB M0031-R3-TS2-C1/C2-Tenax Modified VOST 5041A/8260 12C M0031-R3-TS2-C4-Anasorb Modified VOST 5041A/8260 13AB M0031-R3-TS3-C1/C2-Tenax Modified VOST 5041A/8260 13C M0031-R3-TS3-C4-Anasorb Modified VOST 5041A/8260 14AB M0031-R3-TS4-C1/C2-Tenax Modified VOST 5041A/8260 14C M0031-R3-TS4-C4-Anasorb Modified VOST 5041A/8260 15A M0031-R3-TS4-C3-Codensate Modified VOST 5041A/8260 16AB M0031-BT-TS1-C1/C2-Tenax Modified VOST 5041A/8260 16C M0031-BT-TS1-C4-Anasorb Modified VOST 5041A/8260 17AB M0031-Trip Blank-TS1-C1/C2-Tenax Modified VOST 5041A/8260 17C M0031-Trip Blank-TS1-C4-Anasorb Modified VOST 5041A/8260 18A Lab Blank Modified VOST 5041A/8260 19A LCS Modified VOST 5041A/8260

CERTIFIED BY: Laboratory Director DATE:



### Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act,

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020 

### 06/07/10

Page 2 of 49 This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd. 

### Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719

## LABORATORY NARRATIVE VOST 5041A Civil & Environmental Consultants, Inc. Workorder# 1005506B Laboratory Services Since 1989



## Eighteen VOST 0031 Tube and one VOA Vial-40 mL samples were received on May 21, 2010. The laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components into the GC/MS system for further separation. See the data sheets for the reporting limits for each compound.
Requirement ATL Modifications VOST 5041A 

### Batch Certification Blanks from the same media as samples Analysis of set of cartridges prior to onset of any project; Sampling media provided by the client is batch certified ahead of time, only if client provides blank cartridges.
Method blank Cartridges from the same media batches as the samples Media batch is certified prior to use in the field. Method Blank is used to certify instrument is contaminant free

Connection between cartridge thermal desorption apparatus & sample purge vessel PTFE 1/16" Teflon tubing Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for non-CCCs RSD +- 15 % for all non-CCCs RSD </= 30 % for some compounds: Acetone, Bromoform, Vinyl Acetate, Bromomethane, Chloromethane, 1,1,2,2-Tetracholoroethane, & 1,2,3-Trichloropropane



## Receiving Notes Sample collection date was not provided on the Chain of Custody (COC) for all samples. The sampling dates were taken from the tags.

Per client request, compounds that are not validated under Method 0031 collection protocols were reported in this work order. These compounds may not be suitable for collection by Method 0031 due to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory analytical method 5041A/8260B is validated for all target analytes.
Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the Anasorb. In addition the laboratory method has not been validated for recovery of these additional compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Due to instrument malfunction, sample M0031-R3-TS1-C4-Anasorb was lost during final analysis. Reporting is not possible for this sample.

The recovery of surrogate 1,2-Dichloroethane-d4 in sample M0031-R3-TS2-C4-Anasorb was outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube Analytical Notes

Page 3 of 49Laboratory Services Since 1989



## media. Data is reported as qualified.

The recovery of surrogate Toluene-d8 in samples M0031-R3-TS2-C4-Anasorb, M0031-R3-TS3-C4-Anasorb, and M0031-BT-TS1-C4-Anasorb was outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as qualified.

The recovery of surrogate 4-Bromofluorobenzene in sample M0031-R3-TS1-C1/C2-Tenax was outside control limits due to high level matrix interference. It is not possible to re-run to confirm matrix

or dilute for matrix using sorbent tube media. Data is reported as qualified.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows: B

- Compound present in laboratory blank or tube certification greater than reporting limit (background subtraction not performed). J

- Estimated value. E

- Exceeds instrument calibration range. S

- Saturated peak. Q

- Exceeds quality control limits. U

- Compound analyzed for but not detected above the detection limit. N

- The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags

Page 4 of 49

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R3-TS1-C1/C2-Tenax
Lab ID#: 1005506B-11AB
(ng) (ng) Compound Amount Rpt. Limit

10 32 Bromomethane 10 14 Methylene Chloride 10 13 Hexane 10 32 Benzene 10 17 Toluene



### Client Sample ID: M0031-R3-TS2-C1/C2-Tenax
Lab ID#: 1005506B-12AB
(ng) (ng) Compound Amount Rpt. Limit

10 12 Carbon Disulfide 10 46 Methylene Chloride 10 12 Hexane 10 29 Benzene 10 15 Toluene



### Client Sample ID: M0031-R3-TS2-C4-Anasorb
Lab ID#: 1005506B-12C
(ng) (ng) Compound Amount Rpt. Limit

50 6100 E Chloromethane 10 170 Bromomethane 10 26 Freon 12



### Client Sample ID: M0031-R3-TS3-C1/C2-Tenax
Lab ID#: 1005506B-13AB
(ng) (ng) Compound Amount Rpt. Limit

10 27 Bromomethane 10 12 Carbon Disulfide 50 51 Acetone 10 12 Methylene Chloride 10 14 Hexane 10 29 Benzene 10 18 Toluene
Page 5 of 49

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R3-TS3-C1/C2-Tenax
Lab ID#: 1005506B-13AB 10 12 1,3-Dichlorobenzene 10 12 1,4-Dichlorobenzene 10 14 1,2-Dichlorobenzene



### Client Sample ID: M0031-R3-TS3-C4-Anasorb
Lab ID#: 1005506B-13C
(ng) (ng) Compound Amount Rpt. Limit

50 620 Chloromethane 10 15 Bromomethane 10 11 1,4-Dichlorobenzene 10 12 1,2-Dichlorobenzene 10 24 Freon 12



### Client Sample ID: M0031-R3-TS4-C1/C2-Tenax
Lab ID#: 1005506B-14AB
(ng) (ng) Compound Amount Rpt. Limit

10 20 Bromomethane 10 34 Methylene Chloride 10 11 Hexane 10 29 Benzene 10 16 Toluene



### Client Sample ID: M0031-R3-TS4-C4-Anasorb
Lab ID#: 1005506B-14C
(ng) (ng) Compound Amount Rpt. Limit

10 25 Freon 12



### Client Sample ID: M0031-R3-TS4-C3-Codensate
Lab ID#: 1005506B-15A
(ng) (ng) Compound Amount Rpt. Limit

80 870 Methylene Chloride 80 87 Chloroform
Page 6 of 49

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-BT-TS1-C1/C2-Tenax
Lab ID#: 1005506B-16AB No Detections Were Found.



### Client Sample ID: M0031-BT-TS1-C4-Anasorb
Lab ID#: 1005506B-16C
(ng) (ng) Compound Amount Rpt. Limit

10 10 Bromomethane



### Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax
Lab ID#: 1005506B-17AB No Detections Were Found.



### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb
Lab ID#: 1005506B-17C
(ng) (ng) Compound Amount Rpt. Limit

10 11 Bromomethane 10 10 1,4-Dichlorobenzene 10 10 1,2-Dichlorobenzene

Page 7 of 49

### Client Sample ID: M0031-R3-TS1-C1/C2-Tenax Lab ID#: 1005506B-11AB MODIFIED VOST 5041A/8260B

10060108 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 11:46 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 32 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 14 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 13 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 32 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 17 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 8 of 49

### Client Sample ID: M0031-R3-TS1-C1/C2-Tenax Lab ID#: 1005506B-11AB MODIFIED VOST 5041A/8260B

10060108 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 11:46 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 9 of 49

### Client Sample ID: M0031-R3-TS1-C1/C2-Tenax Lab ID#: 1005506B-11AB MODIFIED VOST 5041A/8260B

10060108 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 11:46 AM

Limits %Recovery Surrogates Method

80 70-130 Dibromofluoromethane 81 70-130 1,2-Dichloroethane-d4 80 70-130 Toluene-d8 67 Q 70-130 4-Bromofluorobenzene

Page 10 of 49

### Client Sample ID: M0031-R3-TS2-C1/C2-Tenax Lab ID#: 1005506B-12AB MODIFIED VOST 5041A/8260B

10060109 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 12:22 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 12 Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 46 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 12 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 29 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 15 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 11 of 49

### Client Sample ID: M0031-R3-TS2-C1/C2-Tenax Lab ID#: 1005506B-12AB MODIFIED VOST 5041A/8260B

10060109 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 12:22 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

106 70-130 Dibromofluoromethane

Page 12 of 49

### Client Sample ID: M0031-R3-TS2-C1/C2-Tenax Lab ID#: 1005506B-12AB MODIFIED VOST 5041A/8260B

10060109 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 12:22 PM

Limits %Recovery Surrogates Method

104 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 106 70-130 4-Bromofluorobenzene

Page 13 of 49

### Client Sample ID: M0031-R3-TS2-C4-Anasorb Lab ID#: 1005506B-12C MODIFIED VOST 5041A/8260B

10060110 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 12:46 PM

(ng) (ng) Compound Amount Rpt. Limit

50 6100 E Chloromethane 10 Not Detected Vinyl Chloride 10 170 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 14 of 49

### Client Sample ID: M0031-R3-TS2-C4-Anasorb Lab ID#: 1005506B-12C MODIFIED VOST 5041A/8260B

10060110 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 12:46 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 26 Freon 12
E = Exceeds instrument calibration range. Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 15 of 49

### Client Sample ID: M0031-R3-TS2-C4-Anasorb Lab ID#: 1005506B-12C MODIFIED VOST 5041A/8260B

10060110 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 12:46 PM

Limits %Recovery Surrogates Method

62 50-150 Dibromofluoromethane 44 Q 50-150 1,2-Dichloroethane-d4 8.8 Q 50-150 Toluene-d8

Page 16 of 49

### Client Sample ID: M0031-R3-TS3-C1/C2-Tenax Lab ID#: 1005506B-13AB MODIFIED VOST 5041A/8260B

10060115 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 03:59 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 27 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 12 Carbon Disulfide 50 51 Acetone 50 Not Detected 3-Chloropropene 10 12 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 14 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 29 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 18 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 17 of 49

### Client Sample ID: M0031-R3-TS3-C1/C2-Tenax Lab ID#: 1005506B-13AB MODIFIED VOST 5041A/8260B

10060115 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 03:59 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 12 1,3-Dichlorobenzene 10 12 1,4-Dichlorobenzene 10 14 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

91 70-130 Dibromofluoromethane

Page 18 of 49

### Client Sample ID: M0031-R3-TS3-C1/C2-Tenax Lab ID#: 1005506B-13AB MODIFIED VOST 5041A/8260B

10060115 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 03:59 PM

Limits %Recovery Surrogates Method

98 70-130 1,2-Dichloroethane-d4 86 70-130 Toluene-d8 91 70-130 4-Bromofluorobenzene

Page 19 of 49

### Client Sample ID: M0031-R3-TS3-C4-Anasorb Lab ID#: 1005506B-13C MODIFIED VOST 5041A/8260B

10060111 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 01:14 PM

(ng) (ng) Compound Amount Rpt. Limit

50 620 Chloromethane 10 Not Detected Vinyl Chloride 10 15 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 20 of 49

### Client Sample ID: M0031-R3-TS3-C4-Anasorb Lab ID#: 1005506B-13C MODIFIED VOST 5041A/8260B

10060111 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 01:14 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 11 1,4-Dichlorobenzene 10 12 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 24 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 21 of 49

### Client Sample ID: M0031-R3-TS3-C4-Anasorb Lab ID#: 1005506B-13C MODIFIED VOST 5041A/8260B

10060111 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 01:14 PM

Limits %Recovery Surrogates Method

97 50-150 Dibromofluoromethane 86 50-150 1,2-Dichloroethane-d4 25 Q 50-150 Toluene-d8

Page 22 of 49

### Client Sample ID: M0031-R3-TS4-C1/C2-Tenax Lab ID#: 1005506B-14AB MODIFIED VOST 5041A/8260B

10060116 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 04:24 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 20 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 34 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 11 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 29 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 16 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 23 of 49

### Client Sample ID: M0031-R3-TS4-C1/C2-Tenax Lab ID#: 1005506B-14AB MODIFIED VOST 5041A/8260B

10060116 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 04:24 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

105 70-130 Dibromofluoromethane

Page 24 of 49

### Client Sample ID: M0031-R3-TS4-C1/C2-Tenax Lab ID#: 1005506B-14AB MODIFIED VOST 5041A/8260B

10060116 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 04:24 PM

Limits %Recovery Surrogates Method

113 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 102 70-130 4-Bromofluorobenzene

Page 25 of 49

### Client Sample ID: M0031-R3-TS4-C4-Anasorb Lab ID#: 1005506B-14C MODIFIED VOST 5041A/8260B

10060112 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 01:58 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 26 of 49

### Client Sample ID: M0031-R3-TS4-C4-Anasorb Lab ID#: 1005506B-14C MODIFIED VOST 5041A/8260B

10060112 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 01:58 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 25 Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

125 50-150 Dibromofluoromethane

Page 27 of 49

### Client Sample ID: M0031-R3-TS4-C4-Anasorb Lab ID#: 1005506B-14C MODIFIED VOST 5041A/8260B

10060112 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 01:58 PM

Limits %Recovery Surrogates Method

130 50-150 1,2-Dichloroethane-d4 81 50-150 Toluene-d8

Page 28 of 49

### Client Sample ID: M0031-R3-TS4-C3-Codensate Lab ID#: 1005506B-15A MODIFIED VOST 5041A/8260B

10060105 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 10:25 AM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 Not Detected Acetone 400 Not Detected 3-Chloropropene 80 870 Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 Not Detected 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 87 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 29 of 49

### Client Sample ID: M0031-R3-TS4-C3-Codensate Lab ID#: 1005506B-15A MODIFIED VOST 5041A/8260B

10060105 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 10:25 AM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

101 70-130 Dibromofluoromethane

Page 30 of 49

### Client Sample ID: M0031-R3-TS4-C3-Codensate Lab ID#: 1005506B-15A MODIFIED VOST 5041A/8260B

10060105 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 10:25 AM

Limits %Recovery Surrogates Method

94 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 96 70-130 4-Bromofluorobenzene

Page 31 of 49

### Client Sample ID: M0031-BT-TS1-C1/C2-Tenax Lab ID#: 1005506B-16AB MODIFIED VOST 5041A/8260B

10060117 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 04:58 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 32 of 49

### Client Sample ID: M0031-BT-TS1-C1/C2-Tenax Lab ID#: 1005506B-16AB MODIFIED VOST 5041A/8260B

10060117 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 04:58 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

102 70-130 Dibromofluoromethane

Page 33 of 49

### Client Sample ID: M0031-BT-TS1-C1/C2-Tenax Lab ID#: 1005506B-16AB MODIFIED VOST 5041A/8260B

10060117 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 04:58 PM

Limits %Recovery Surrogates Method

113 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 90 70-130 4-Bromofluorobenzene

Page 34 of 49

### Client Sample ID: M0031-BT-TS1-C4-Anasorb Lab ID#: 1005506B-16C MODIFIED VOST 5041A/8260B

10060113 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 02:59 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 10 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 35 of 49

### Client Sample ID: M0031-BT-TS1-C4-Anasorb Lab ID#: 1005506B-16C MODIFIED VOST 5041A/8260B

10060113 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 02:59 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 36 of 49

### Client Sample ID: M0031-BT-TS1-C4-Anasorb Lab ID#: 1005506B-16C MODIFIED VOST 5041A/8260B

10060113 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 02:59 PM

Limits %Recovery Surrogates Method

51 50-150 Dibromofluoromethane 78 50-150 1,2-Dichloroethane-d4 18 Q 50-150 Toluene-d8

Page 37 of 49

### Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax Lab ID#: 1005506B-17AB MODIFIED VOST 5041A/8260B

10060118 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 05:26 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 38 of 49

### Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax Lab ID#: 1005506B-17AB MODIFIED VOST 5041A/8260B

10060118 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 05:26 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

106 70-130 Dibromofluoromethane

Page 39 of 49

### Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax Lab ID#: 1005506B-17AB MODIFIED VOST 5041A/8260B

10060118 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 05:26 PM

Limits %Recovery Surrogates Method

117 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 92 70-130 4-Bromofluorobenzene

Page 40 of 49

### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb Lab ID#: 1005506B-17C MODIFIED VOST 5041A/8260B

10060114 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 03:26 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 11 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 41 of 49

### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb Lab ID#: 1005506B-17C MODIFIED VOST 5041A/8260B

10060114 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 03:26 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 10 1,4-Dichlorobenzene 10 10 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

79 50-150 Dibromofluoromethane

Page 42 of 49

### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb Lab ID#: 1005506B-17C MODIFIED VOST 5041A/8260B

10060114 File Name: Dil. Factor: 1.00 Date of Collection: 5/19/10 Date of Analysis: 6/1/10 03:26 PM

Limits %Recovery Surrogates Method

101 50-150 1,2-Dichloroethane-d4 67 50-150 Toluene-d8

Page 43 of 49

### Client Sample ID: Lab Blank Lab ID#: 1005506B-18A MODIFIED VOST 5041A/8260B

10060104 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:37 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 44 of 49

### Client Sample ID: Lab Blank Lab ID#: 1005506B-18A MODIFIED VOST 5041A/8260B

10060104 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:37 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

100 70-130 Dibromofluoromethane

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### Client Sample ID: Lab Blank Lab ID#: 1005506B-18A MODIFIED VOST 5041A/8260B

10060104 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:37 AM

Limits %Recovery Surrogates Method

102 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 92 70-130 4-Bromofluorobenzene

Page 46 of 49

### Client Sample ID: LCS Lab ID#: 1005506B-19A MODIFIED VOST 5041A/8260B

10060103 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:13 AM

%Recovery Compound
116 Chloromethane 101 Vinyl Chloride 100 Bromomethane 98 Chloroethane 105 Freon 11 109 2-Chloropropane 100 1,1-Dichloroethene 116 Freon 113 124 Carbon Disulfide 109 Acetone 118 3-Chloropropene 104 Methylene Chloride 109 trans-1,2-Dichloroethene 96 Acrylonitrile 114 Hexane 99 1,1-Dichloroethane Not Spiked Vinyl Acetate 99 2,2-Dichloropropane 94 cis-1,2-Dichloroethene 119 2-Butanone (Methyl Ethyl Ketone) 95 Bromochloromethane 98 Chloroform 99 1,1,1-Trichloroethane 98 Carbon Tetrachloride 104 1,1-Dichloropropene 100 Benzene 97 1,2-Dichloroethane 100 Trichloroethene 100 1,2-Dichloropropane 97 Dibromomethane 95 Bromodichloromethane 99 cis-1,3-Dichloropropene 102 trans-1,3-Dichloropropene 97 4-Methyl-2-pentanone 97 Toluene 96 1,1,2-Trichloroethane 100 Tetrachloroethene 94 1,3-Dichloropropane 129 2-Hexanone

Page 47 of 49

### Client Sample ID: LCS Lab ID#: 1005506B-19A MODIFIED VOST 5041A/8260B

10060103 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:13 AM

%Recovery Compound
95 Dibromochloromethane 97 Chlorobenzene 96 1,2-Dibromoethane (EDB) 100 Ethyl Benzene 99 m,p-Xylene 99 o-Xylene 101 Styrene 94 Bromoform 91 1,1,2,2-Tetrachloroethane 101 1,3-Dichlorobenzene 100 1,4-Dichlorobenzene 101 1,2-Dichlorobenzene 117 Cumene 86 cis-1,4-Dichloro-2-butene 96 Bromobenzene 95 1,2,3-Trichloropropane 88 trans-1,4-Dichloro-2-butene 100 Propylbenzene 98 2-Chlorotoluene 101 4-Chlorotoluene 101 1,3,5-Trimethylbenzene 102 tert-Butylbenzene 102 1,2,4-Trimethylbenzene 103 sec-Butylbenzene 103 p-Cymene 93 1,2-Dibromo-3-chloropropane 106 1,2,4-Trichlorobenzene 98 Naphthalene 121 Hexachlorobutadiene 107 1,2,3-Trichlorobenzene 100 1,1,1,2-Tetrachloroethane 101 Butylbenzene 115 Iodomethane 103 Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

103 70-130 Dibromofluoromethane

Page 48 of 49

### Client Sample ID: LCS Lab ID#: 1005506B-19A MODIFIED VOST 5041A/8260B

10060103 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 6/1/10 09:13 AM

Limits %Recovery Surrogates Method

104 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 96 70-130 4-Bromofluorobenzene

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# APPENDIX F

ANALYTICAL DATA - FUELS

# APPENDIX G
CALIBRATIONS SHEETS, CERTIFICATIONS

# APPENDIX H

PROCESS DATA