**SW-846 Update V CONTENTS - 1 Revision 8 October 2012**  TABLE OF CONTENTS

**--------------------- VOLUME ONE** 

**SECTION A**

**-------------------**

**_________________________________________________ PART I METHODS FOR ANALYTES AND PROPERTIES** 

**CHAPTER ONE - PROJECT QUALITY ASSURANCE AND QUALITY CONTROL** 

**1.0 Introduction 1.1 Planning**  **1.2 Implementation 1.3 Assessment**  **1.4 References and Sources for Additional Informati on on Project Quality Assurance and**  **Control 1.5 Glossary** 

**CHAPTER TWO - CHOOSING THE CORRECT PROCEDURE**

**2.0 Introduction 2.1 Guidance Regarding Flexibility Inherent to SW-8**  **46 Methods and the Precedence of SW-846 Quality Control Criteria**  **2.2 Information Necessary for Choosing the Correct Procedure**  **2.3 Choosing Procedures for Organic Analyses 2.4 Choosing Procedures for Characteristic Analyses**  **2.5 Choosing Procedures for Groundwater Analyses 2.6 Choosing Procedures for Inorganic Analyses**  **2.7 References**

**CHAPTER THREE - INORGANIC ANALYTES**

**3.0 Introduction 3.1 Definitions**  **3.2 Safety 3.3 Sampling Considerations**  **3.4 Special Considerations for Determining Inorgani c Analytes at Ultra-trace Concentration**  **Levels 3.5 Reagent Purity**  **3.6 Sample Digestion Methods** Method 3005A: **Acid Digestion of Waters for Total Recoverable or Dissolved Metals** 

**for Analysis by FLAA or ICP Spectroscopy** Method 3010A: **Acid Digestion of Aqueous Samples and Extracts for Total Metals**  **for Analysis by FLAA or ICP Spectroscopy SW-846 Update V CONTENTS - 2 Revision 8**  **October 2012** Method 3015A: **Microwave Assisted Acid Digestion of Aqueous Sampl es and** 

**Extracts** Method 3020A: **Acid Digestion of Aqueous Samples and Extracts for Total Metals**  **for Analysis by GFAA Spectroscopy** Method 3031: **Acid Digestion of Oils for Metals Analysis by Atom ic Absorption or** 

**ICP Spectrometry** Method 3040A: **Dissolution Procedure for Oils, Greases, or Waxes** Method 3050B: **Acid Digestion of Sediments, Sludges, and Soils** Method 3051A: **Microwave Assisted Acid Digestion of Sediments, Sl udges, Soils,** 

**and Oils** Method 3052: **Microwave Assisted Acid Digestion of Siliceous an d Organically** 

**Based Matrices** Method 3060A: **Alkaline Digestion for Hexavalent Chromium** Method 3200: **Mercury Species Fractionation and Quantification by Microwave** 

**Assisted Extraction, Selective Solvent Extraction a nd/or Solid**  **Phase Extraction**

**3.7 Methods for Determination of Inorganic Analytes**

Method 6010D: **Inductively Coupled Plasma-Atomic Emission Spectro metry**  Method 6020B: **Inductively Coupled Plasma-Mass Spectrometry** Method 6200: **Field Portable X-Ray Fluorescence Spectrometry for the**  **Determination of Elemental Concentrations in Soil a nd Sediment**  Method 6500: **Dissolved Inorganic Anions in Aqueous Matrices by C apillary Ion** 

**Electrophoresis** Method 6800: **Elemental and Speciated Isotope Dilution Mass Spect rometry**  Method 7000B: **Flame Atomic Absorption Spectrophotometry** Method 7010: **Graphite Furnace Atomic Absorption Spectrophotometr y**  Method 7061A: **Arsenic (Atomic Absorption, Gaseous Hydride)** Method 7062: **Antimony and Arsenic (Atomic Absorption, Borohydr ide Reduction)**  Method 7063: **Arsenic in Aqueous Samples and Extracts by Anodic Stripping** 

**Voltammetry (ASV)** Method 7195: **Chromium, Hexavalent (Coprecipitation)** Method 7196A: **Chromium, Hexavalent (Colorimetric)** Method 7197: **Chromium, Hexavalent (Chelation/Extraction)** Method 7198: **Chromium, Hexavalent (Differential Pulse Polarogr aphy)**  Method 7199: **Determination of Hexavalent Chromium in Drinking Water,** 

**Groundwater and Industrial Wastewater Effluents by Ion**  **Chromatography** Method 7470A: **Mercury in Liquid Waste (Manual Cold-Vapor Techniq ue)**  Method 7471B: **Mercury in Solid or Semisolid Waste (Manual Cold-V apor** 

**Technique)** Method 7472: **Mercury in Aqueous Samples and Extracts by Anodic Stripping** 

**Voltammetry (ASV)** Method 7473: **Mercury in Solids and Solutions by Thermal Decomp osition,** 

**Amalgamation, and Atomic Absorption Spectrophotomet ry**  Method 7474: **Mercury in Sediment and Tissue Samples by Atomic Fl uorescence** 

**Spectrometry** Method 7580: **White Phosphorus (P 4**  **) by Solvent Extraction and Gas**

**Chromatography** Method 7741A: **Selenium (Atomic Absorption, Gaseous Hydride) SW-846 Update V CONTENTS - 3 Revision 8**  **October 2012** Method 7742: **Selenium (Atomic Absorption, Borohydride Reduction )** 

**3.8 References for Previous Sections and the Tables and Figures** 

**NOTE : A suffix of "A" in the method number indicates re**  **vision one (the method has been revised once). A suffix of "B" in the method**  **number indicates revision two (the method has been revised twice). A suffix of "C" in**  **the method number indicates revision three (the method has been revised three t**  **imes). In order to properly document the method used for analysis, the entire m**  **ethod number including the suffix letter designation**  **(e.g., A, B, or C) must be identified by the analy st. A**  **method reference found within the text of SW-846 me thods and chapters refers to**  **the latest revision of the method, even though the method number does not include**  **the appropriate letter suffix. SW-846 Update V CONTENTS - 4 Revision 8**  **October 2012 ---------------------**  **VOLUME ONE**

**SECTION B**

**-------------------**

**CHAPTER ONE, REPRINTED - PROJECT QUALITY ASSURANCE AND QUALITY CONTROL** 

**1.0 Introduction 1.1 Planning**  **1.2 Implementation 1.3 Assessment**  **1.4 References and Sources for Additional Informati on on Project Quality Assurance and**  **Control 1.5 Glossary** 

**CHAPTER FOUR - ORGANIC ANALYTES**

**4.1 Sampling Considerations 4.2 Sample Preparation Methods** 

**4.2.1 Extractions and Preparations**

Method 3500C: **Organic Extraction and Sample Preparation** Method 3510C: **Separatory Funnel Liquid-Liquid Extraction** Method 3511 **: Organic Compounds in Water by Microextraction** Method 3520C: **Continuous Liquid-Liquid Extraction** Method 3535A: **Solid-Phase Extraction (SPE)** Method 3540C: **Soxhlet Extraction** Method 3541: **Automated Soxhlet Extraction** Method 3542B: **Extraction of Semivolatile Analytes Collected Usin g Method 0010** 

**(Modified Method 5 Sampling Train)** Method 3545A: **Pressurized Fluid Extraction (PFE)** Method 3546: **Microwave Extraction** Method 3550C: **Ultrasonic Extraction** Method 3560: **Supercritical Fluid Extraction of Total Recoverab le Petroleum** 

**Hydrocarbons** Method 3561: **Supercritical Fluid Extraction of Polynuclear Aro matic** 

**Hydrocarbons** Method 3562: **Supercritical Fluid Extraction of Polychlorinated Biphenyls (PCBs)** 

**and Organochlorine Pesticides** Method 3572: **Extraction of Wipe Samples for Chemical Agents** Method 3580A: **Waste Dilution** Method 3585: **Waste Dilution for Volatile Organics** Method 5000: **Sample Preparation for Volatile Organic Compounds** Method 5021A: **Volatile Organic Compounds in Soils and Other Soli d Matrices** 

**Using Equilibrium Headspace Analysis** Method 5030B: **Purge-and-Trap for Aqueous Samples** Method 5031: **Volatile, Nonpurgeable, Water-Soluble Compounds b y Azeotropic** 

**Distillation** Method 5032: **Volatile Organic Compounds by Vacuum Distillation SW-846 Update V CONTENTS - 5 Revision 8**  **October 2012** Method 5035: **Closed-System Purge-and-Trap and Extraction for V olatile** 

**Organics in Soil and Waste Samples** Method 5041A: **Analysis for Desorption of Sorbent Cartridges from Volatile Organic** 

**Sampling Train (VOST)**

**4.2.2 Cleanup**

Method 3600C: **Cleanup** Method 3610B: **Alumina Cleanup** Method 3611B: **Alumina Column Cleanup and Separation of Petroleum Wastes**  Method 3620C: **Florisil Cleanup** Method 3630C: **Silica Gel Cleanup** Method 3640A: **Gel-Permeation Cleanup** Method 3650B: **Acid-Base Partition Cleanup** Method 3660B: **Sulfur Cleanup** Method 3665A: **Sulfuric Acid/Permanganate Cleanup**

**4.3 Determination of Organic Analytes**

**4.3.1 Gas Chromatographic Methods**

Method 8000D: **Determinative Chromatographic Separations** Method 8011: **1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by** 

**Microextraction and Gas Chromatography** Method 8015C: **Nonhalogenated Organics by Gas Chromatography** Method 8021B: **Aromatic and Halogenated Volatiles by Gas Chromato graphy** 

**Using Photoionization and/or Electrolytic Conductiv ity Detectors**  Method 8031: **Acrylonitrile by Gas Chromatography** Method 8032A: **Acrylamide by Gas Chromatography** Method 8033: **Acetonitrile by Gas Chromatography with Nitrogen- Phosphorus** 

**Detection** Method 8041A: **Phenols by Gas Chromatography** Method 8061A: **Phthalate Esters by Gas Chromatography with Electr on Capture** 

**Detection (GC/ECD)** Method 8070A: **Nitrosamines by Gas Chromatography** Method 8081B: **Organochlorine Pesticides by Gas Chromatography** Method 8082A: **Polychlorinated Biphenyls (PCBs) by Gas Chromatogr aphy**  Method 8085: **Compound-independent Elemental Quantitation of Pe sticides by** 

**Gas Chromatography with Atomic Emission Detection ( GC/AED)**  Method 8091: **Nitroaromatics and Cyclic Ketones by Gas Chromato graphy**  Method 8095: **Explosives by Gas Chromatography** Method 8100: **Polynuclear Aromatic Hydrocarbons** Method 8111: **Haloethers by Gas Chromatography** Method 8121: **Chlorinated Hydrocarbons by Gas Chromatography: C apillary** 

**Column Technique** Method 8131: **Aniline and Selected Derivatives by Gas Chromatog raphy**  Method 8141B: **Organophosphorus Compounds by Gas Chromatography** Method 8151A: **Chlorinated Herbicides by GC Using Methylation or**

**Pentafluorobenzylation Derivatization SW-846 Update V CONTENTS - 6 Revision 8**  **October 2012 4.3.2 Gas Chromatographic/Mass Spectrometric Method**  **s**

Method 8261: **Volatile Organic Compounds by Vacuum Distillation in Combination** 

**with Gas Chromatography/Mass Spectrometry (VD/GC/MS )**  Method 8270D: **Semivolatile Organic Compounds by Gas Chromatograp hy/Mass** 

**Spectrometry (GC/MS)** Method 8275A: **Semivolatile Organic Compounds (PAHs and PCBs) in**

**Soils/Sludges and Solid Wastes Using Thermal Extrac tion/Gas**  **Chromatography/Mass Spectrometry (TE/GC/MS)** Method 8276: **Toxaphene and Toxaphene Congeners by Gas**

**Chromatography/Negative Ion Chemical Ionization Mas s**  **Spectrometry (GC-NICI/MS)** Method 8280B: **Polychlorinated Dibenzo-** p **-Dioxins (PCDDs) and Polychlorinated**

**Dibenzofurans (PCDFs) by High Resolution Gas Chromatography/Low Resolution Mass Spectrometry**  **(HRGC/LRMS)** Method 8290A: **Polychlorinated Dibenzodioxins (PCDDs) and Polychl orinated** 

**Dibenzofurans (PCDFs) by High-Resolution Gas Chromatography/High-Resolution Mass Spectrometry**  **(HRGC/HRMS) Appendix A: Procedures for the Collection, Handling**  **, Analysis, and Reporting of Wipe Tests Performed within the Labora**  **tory**

**4.3.3 High Performance Liquid Chromatographic Metho ds** 

Method 8310: **Polynuclear Aromatic Hydrocarbons** Method 8315A: **Determination of Carbonyl Compounds by High Perfor mance** 

**Liquid Chromatography (HPLC) Appendix A: Recrystallization of 2,4-Dinitrophenylh**  **ydrazine (DNPH)**  Method 8316: **Acrylamide, Acrylonitrile and Acrolein by High Pe rformance Liquid** 

**Chromatography (HPLC)** Method 8318A: N **-Methylcarbamates by High Performance Liquid Chroma tography**  **(HPLC)** Method 8321B: **Solvent-Extractable Nonvolatile Compounds by High- Performance** 

**Liquid Chromatography/Thermospray/Mass Spectrometry(HPLC/TS/MS) or Ultraviolet (UV) Detect**  **ion** Method 8325: **Solvent Extractable Nonvolatile Compounds by High Performance** 

**Liquid Chromatography/Particle Beam/Mass Spectromet ry**  **(HPLC/PB/MS)** Method 8330A: **Nitroaromatics and Nitramines by High Performance Liquid** 

**Chromatography (HPLC)** Method 8331: **Tetrazene by Reverse Phase High Performance Liqui d** 

**Chromatography (HPLC)** Method 8332: **Nitroglycerine by High Performance Liquid Chromato graphy** 

**4.3.4 Infrared Methods**

Method 8410: **Gas Chromatography/Fourier Transform Infrared (GC/ FT-IR)** 

**Spectrometry for Semivolatile Organics: Capillary Column** **SW-846 Update V CONTENTS - 7 Revision 8 October 2012**  Method 8430: **Analysis of Bis(2-chloroethyl) Ether and Hydrolysi s Products by** 

**Direct Aqueous Injection GC/FT-IR** Method 8440: **Total Recoverable Petroleum Hydrocarbons by Infrar ed** 

**Spectrophotometry**

**4.3.5 Miscellaneous Spectrometric Methods**

Method 8520: **Continuous Measurement of Formaldehyde in Ambient Air** 

**4.4 Immunoassay Methods**

Method 4000: **Immunoassay** Method 4010A: **Screening for Pentachlorophenol by Immunoassay** Method 4015: **Screening for 2,4-Dichlorophenoxyacetic Acid by Im munoassay**  Method 4020: **Screening for Polychlorinated Biphenyls by Immunoa ssay**  Method 4025: **Screening for Polychlorinated Dibenzodioxins and Polychlorinated** 

**Dibenzofurans (PCDD/Fs) by Immunoassay** Method 4030: **Soil Screening for Petroleum Hydrocarbons by Immun oassay**  Method 4035: **Soil Screening for Polynuclear Aromatic Hydrocarbo ns by** 

**Immunoassay** Method 4040: **Soil Screening for Toxaphene by Immunoassay** Method 4041: **Soil Screening for Chlordane by Immunoassay** Method 4042: **Soil Screening for DDT by Immunoassay** Method 4050: **TNT Explosives in Soil by Immunoassay** Method 4051: **Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in S oil by** 

**Immunoassay** Method 4425: **Screening Extracts of Environmental Samples for Pl anar Organic** 

**Compounds (PAHs, PCBs, PCDDs/PCDFs) by a Reporter G ene on**  **a Human Cell Line** Method 4430: **Screening For Polychlorinated Dibenzo-p-Dioxins A nd Furans** 

**(PCDD/Fs) By Aryl Hydrocarbon-Receptor PCR Assay** Method 4435: **Method For Toxic Equivalents (TEQS) Determinations For** 

**Dioxin-Like Chemical Activity with the CALUX** 

### ® **Bioassay** Method 4670: **Triazine Herbicides as Atrazine in Water by Quant itative** 

**Immunoassay**

**4.5 Miscellaneous Screening Methods**

Method 3815: **Screening Solid Samples for Volatile Organics** Method 3820: **Hexadecane Extraction and Screening of Purgeable O rganics**  Method 8510: **Colorimetric Screening Procedure for RDX and HMX i n Soil**  Method 8515: **Colorimetric Screening Method for Trinitrotoluene (TNT) in Soil**  Method 8535: **Screening Procedure for Total Volatile Organic Ha lides in Water**  Method 8540: **Pentachlorophenol by UV-Induced Colorimetry** Method 9074: **Turbidimetric Screening Method for Total Recovera ble Petroleum** 

**Hydrocarbons in Soil** Method 9078: **Screening Test Method for Polychlorinated Biphenyl s in Soil**  Method 9079: **Screening Test Method for Polychlorinated Bipheny ls in** 

**Transformer Oil SW-846 Update V CONTENTS - 8 Revision 8**  **October 2012 NOTE**  **: A suffix of "A" in the method number indicates re vision one (the method has**  **been revised once). A suffix of "B" in the method number indicates revision two (the**  **method has been revised twice). A suffix of "C" in the method number indicates**  **revision three (the method has been revised three t imes). In order to properly**  **document the method used for analysis, the entire m ethod number including the**  **suffix letter designation (e.g., A, B, or C) must be identified by the analy**  **st. A method reference found within the text of SW-846 me**  **thods and chapters refers to the latest revision of the method, even though the**  **method number does not include the appropriate letter suffix.** **SW-846 Update V CONTENTS - 9 Revision 8 October 2012**  **--------------------- VOLUME ONE** 

**SECTION C**

**-------------------**

**CHAPTER ONE, REPRINTED - PROJECT QUALITY ASSURANCE AND QUALITY CONTROL** 

**1.0 Introduction 1.1 Planning**  **1.2 Implementation 1.3 Assessment**  **1.4 References and Sources for Additional Informati on on Project Quality Assurance and Control**  **1.5 Glossary**

**CHAPTER FIVE - MISCELLANEOUS TEST METHODS**

Method 5050: **Bomb Preparation Method for Solid Waste** Method 9000: **Determination of Water in Waste Materials by Karl Fischer Titration**  Method 9001: **Determination of Water in Waste Materials by Quant itative Calcium** 

**Hydride Reaction** Method 9010C: **Total and Amenable Cyanide: Distillation** Method 9012B: **Total and Amenable Cyanide (Automated Colorimetric , with** 

**Off-Line Distillation)** Method 9013A: **Cyanide Extraction Procedure for Solids and Oils** Method 9014: **Titrimetric and Manual Spectrophotometric Determin ative Methods** 

**for Cyanide** Method 9015: **Metal Cyanide Complexes by Anion Exchange Chromat ography** 

**and UV Detection** Method 9020B: **Total Organic Halides (TOX)** Method 9021: **Purgeable Organic Halides (POX)** Method 9022: **Total Organic Halides (TOX) by Neutron Activation Analysis**  Method 9023: **Extractable Organic Halides (EOX) in Solids** Method 9030B: **Acid-Soluble and Acid-Insoluble Sulfides: Distill ation**  Method 9031: **Extractable Sulfides** Method 9034: **Titrimetric Procedure for Acid-Soluble and Acid-I nsoluble Sulfides**  Method 9035: **Sulfate (Colorimetric, Automated, Chloranilate)** Method 9036: **Sulfate (Colorimetric, Automated, Methylthymol Bl ue, AA II)**  Method 9038: **Sulfate (Turbidimetric)** Method 9056A: **Determination of Inorganic Anions by Ion Chromatog raphy**  Method 9057: **Determination of Chloride from HCl/Cl 2**  **Emission Sampling Train**

**(Methods 0050 and 0051) by Anion Chromatography** Method 9060A: **Total Organic Carbon** Method 9065: **Phenolics (Spectrophotometric, Manual 4-AAP with Distillation)**  Method 9066: **Phenolics (Colorimetric, Automated 4-AAP with Dist illation)**  Method 9067: **Phenolics (Spectrophotometric, MBTH with Distillat ion)**  Method 9070A: n **-Hexane Extractable Material (HEM) for Aqueous Samp les**  Method 9071B: n **-Hexane Extractable Material (HEM) for Sludge, Sedi ment, and** 

**Solid Samples** Method 9075: **Test Method for Total Chlorine in New and Used Pe troleum** 

**Products by X-Ray Fluorescence Spectrometry (XRF) SW-846 Update V CONTENTS - 10 Revision 8**  **October 2012** Method 9076: **Test Method for Total Chlorine in New and Used Pe troleum** 

**Products by Oxidative Combustion and Microcoulometr y**  Method 9077: **Test Methods for Total Chlorine in New and Used P etroleum** 

**Products (Field Test Kit Methods) Method A: Fixed End Point Test Kit Method**  **Method B: Reverse Titration Quantitative End Poin t Test Kit Method**  **Method C: Direct Titration Quantitative End Point Test Kit Method**  Method 9131: **Total Coliform: Multiple Tube Fermentation Techn ique**  Method 9132: **Total Coliform: Membrane-Filter Technique** Method 9210A: **Potentiometric Determination of Nitrate in Aqueous Samples with** 

**an Ion-Selective Electrode** Method 9211: **Potentiometric Determination of Bromide in Aqueous Samples with** 

**Ion-Selective Electrode** Method 9212: **Potentiometric Determination of Chloride in Aqueou s Samples with** 

**Ion-Selective Electrode** Method 9213: **Potentiometric Determination of Cyanide in Aqueou s Samples and** 

**Distillates with Ion-Selective Electrode** Method 9214: **Potentiometric Determination of Fluoride in Aqueo us Samples with** 

**Ion-Selective Electrode** Method 9215: **Potentiometric Determination of Sulfide in Aqueou s Samples and** 

**Distillates with Ion-Selective Electrode** Method 9216: **Potentiometric Determination of Nitrite in Aqueous Samples with** 

**Ion-Selective Electrode** Method 9250: **Chloride (Colorimetric, Automated Ferricyanide AAI )**  Method 9251: **Chloride (Colorimetric, Automated Ferricyanide AAII )**  Method 9253: **Chloride (Titrimetric, Silver Nitrate)** Method 9320: **Radium-228**

**CHAPTER SIX - PROPERTIES**

Method 1030: **Ignitability of Solids** Method 1040: **Test Method for Oxidizing Solids** Method 1050: **Test Methods to Determine Substances Likely to Sp ontaneously** 

**Combust** Method 1120: **Dermal Corrosion** Method 1312: **Synthetic Precipitation Leaching Procedure (SPLP)** Method 1320: **Multiple Extraction Procedure** Method 1330A: **Extraction Procedure for Oily Wastes** Method 9041A: **pH Paper Method** Method 9045D: **Soil and Waste pH** Method 9050A: **Specific Conductance** Method 9080: **Cation-Exchange Capacity of Soils (Ammonium Acetat e)**  Method 9081: **Cation-Exchange Capacity of Soils (Sodium Acetate )**  Method 9090A: **Compatibility Test for Wastes and Membrane Liners** Method 9095B: **Paint Filter Liquids Test** Method 9096: **Liquid Release Test (LRT) Procedure**

**Appendix A: Liquid Release Test Pre-Test** Method 9100: **Saturated Hydraulic Conductivity, Saturated Leach ate** 

**Conductivity, and Intrinsic Permeability** Method 9310: **Gross Alpha and Gross Beta SW-846 Update V CONTENTS - 11 Revision 8**  **October 2012** Method 9315: **Alpha-Emitting Radium Isotopes SW-846 Update V CONTENTS - 12 Revision 8**  **October 2012 __________________________**  **PART II CHARACTERISTICS**

**CHAPTER SEVEN - CHARACTERISTICS INTRODUCTION AND RE GULATORY DEFINITIONS** 

**7.1 Ignitability 7.2 Corrosivity**  **7.3 Reactivity (See Narrative Standard in 40 CFR 26 1.23 and 24)**  **7.4 Toxicity Characteristic Leaching Procedure**

**CHAPTER EIGHT - METHODS FOR DETERMINING CHARACTERIS TICS** 

**8.1 Ignitability**

Method 1010A: **Test Methods for Flash Point by Pensky-Martens Clo sed Cup** 

**Tester** Method 1020B: **Standard Test Methods for Flash Point by Setaflash (Small Scale)** 

**Closed-cup Apparatus**

**8.2 Corrosivity**

Method 9040C: **pH Electrometric Measurement** Method 1110A: **Corrosivity Toward Steel**

**8.3 Toxicity**

Method 1310B: **Extraction Procedure (EP) Toxicity Test Method and Structural** 

**Integrity Test** Method 1311: **Toxicity Characteristic Leaching Procedure (TCLP)**

**NOTE : A suffix of "A" in the method number indicates re**  **vision one (the method has been revised once). A suffix of "B" in the method**  **number indicates revision two (the method has been revised twice). A suffix of "C" in**  **the method number indicates revision three (the method has been revised three t**  **imes). In order to properly document the method used for analysis, the entire m**  **ethod number including the suffix letter designation**  **(e.g., A, B, or C) must be identified by the analy st. A**  **method reference found within the text of SW-846 me thods and chapters refers to**  **the latest revision of the method, even though the method number does not include**  **the appropriate letter suffix. SW-846 Update V CONTENTS - 13 Revision 8**  **October 2012 ------------------------**  **VOLUME TWO**

**------------------------**

**CHAPTER ONE, REPRINTED - PROJECT QUALITY ASSURANCE AND QUALITY CONTROL** 

**1.0 Introduction 1.1 Planning**  **1.2 Implementation 1.3 Assessment**  **1.4 References and Sources for Additional Informati on on Project Quality Assurance and Control**  **1.5 Glossary**

**___________________ PART III SAMPLING** 

**CHAPTER NINE - SAMPLING PLAN**

**CHAPTER TEN - SAMPLING METHODS**

Method 0010: **Modified Method 5 Sampling Train**

**Appendix A: Preparation of XAD-2 Sorbent Resin Appendix B:**  **Total Chromatographable Organic Material Analysis** Method 0011: **Sampling for Selected Aldehyde and Ketone Emissio ns from** 

**Stationary Sources** Method 0020: **Source Assessment Sampling System (SASS)** Method 0023A: **Sampling Method for Polychlorinated Dibenzo-p-Diox ins and** 

**Polychlorinated Dibenzofuran Emissions from Station ary Sources**  Method 0030: **Volatile Organic Sampling Train** Method 0031: **Sampling Method for Volatile Organic Compounds (SM VOC)**  Method 0040: **Sampling of Principal Organic Hazardous Constituen ts from** 

**Combustion Sources Using Tedlar® Bags** Method 0050: **Isokinetic HCl/Cl 2**  **Emission Sampling Train** Method 0051: **Midget Impinger HCl/Cl 2**  **Emission Sampling Train** Method 0060: **Determination of Metals in Stack Emissions** Method 0061: **Determination of Hexavalent Chromium Emissions fr om Stationary** 

**Sources** Method 0100: **Sampling for Formaldehyde and Other Carbonyl Comp ounds in** 

**Indoor Air** Method 25D: **Determination of the Volatile Organic Concentrati on of Waste** 

**Samples** Method 25E: **Determination of Vapor Phase Organic Concentratio n in Waste** 

**Samples** Method 207: **A Method for Measuring Isocyanates in Stationary Source** 

**Emissions SW-846 Update V CONTENTS - 14 Revision 8**  **October 2012 ______________________**  **PART IV MONITORING**

**CHAPTER ELEVEN - GROUND WATER MONITORING**

**Referral to the EPA Office of Solid Waste guidance document entitled "RCRA Ground-water Monitoring:**  **Draft Technical Guidance," published in 1992.**

**CHAPTER TWELVE - LAND TREATMENT MONITORING**

**12.1 Background 12.2 Treatment Zone**  **12.3 Regulatory Definition 12.4 Monitoring and Sampling Strategy**  **12.5 Analysis 12.6 References and Bibliography** 

**CHAPTER THIRTEEN - INCINERATION**

**13.1 Introduction 13.2 Regulatory Definition**  **13.3 Waste Characterization Strategy 13.4 Stack-Gas Effluent Characterization Strategy**  **13.5 Additional Effluent Characterization Strategy 13.6 Selection of Specific Sampling and Analysis Me**  **thods 13.7 References** 

**NOTE : A suffix of "A" in the method number indicates re**  **vision one (the method has been revised once). A suffix of "B" in the method**  **number indicates revision two (the method has been revised twice). A suffix of "C" in**  **the method number indicates revision three (the method has been revised three t**  **imes). In order to properly document the method used for analysis, the entire m**  **ethod number including the suffix letter designation**  **(e.g., A, B, or C) must be identified by the analy st. A**  **method reference found within the text of SW-846 me thods and chapters refers to**  **the latest revision of the method, even though the method number does not include**  **the appropriate letter suffix.**