# EMISSIONS TEST REPORT BIG BEND POWER STATION FACILITY ID NUMBER 0570039 UNIT #3 MERCURY EMISSIONS SURVEY

Prepared for: Tampa Electric Company P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health, & Safety Air Services Group

# TABLE OF CONTENTS 1.0 INTRODUCTION 1 2.0 SUMMARIZED DATA 2 3.0 SOURCE DESCRIPTIONS/TEST PROCEDURES 3 4.0 FIGURES TEST LOCATION 5

APPENDIX A DATA ANALYSIS Big Bend Unit 3 05/14/2009 Big Bend Unit 3 05/27/2009 Big Bend Unit 3 05/29/2009 Big Bend Unit 3 07/31/2009 Big Bend Unit 3 09/14/2009 Big Bend Unit 3 09/15/2009

# 1.0 INTRODUCTION During 2009, Tampa Electric Company’s Environmental, Health, & Safety Air Services Group performed numerous Mercur y (Hg) sampling/analysis tests as a part of an overall Hg survey at Big Bend Station. This report summarizes the activities at Big Bend Unit #3.

1

## 2 

# 2.0 SUMMARIZED DATA EXECUTIVE SUMMARY Tampa Electric Company

Big Bend Power Station Mercury Testing Program Big Bend Power Station Unit #3 Test Date Test Duration, hrs Test Method 

## Concentration, ug/scm 05/14/2009 (a) 4 App K 0.32 05/14/2009 (b) 4 App K 0.54 05/27/2009 (a) 48 App K 0.28 05/27/2009 (b) 48 App K 0.26 05/29/2009 (a) 72 App K 0.31 05/29/2009 (b) 72 App K 0.48 07/31/2009 (a) 336 App K 0.37 07/31/2009 (b) 336 App K 0.38 09/14/2009 (a) 4 Speciated 0.48 09/15/2009 (a) 168 App K 0.44 09/15/2009 (b) 168 App K 0.49 

### App K refers to 40CFR75 Appendix K – Quality assurance and Operating Procedures for Sorbent Trap Monitoring Systems.Speciated refers to speciated traps,concentration reported is total of KCl and carbon analysis.

## 3 

# 3.0 SOURCE DESCRIPTIONS/TEST PROCEDURES Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM coordinates East 361.9 North 3075.0. The Boiler No. 3 sampling location consists of a shared circular stack 28.83 feet in diameter with four sample ports located 90 degrees apart on the stack circumference. Thes e ports are located downstream of the electrostatic precipitator, the SCR, and the FGD scrubber. The sampling ports were determined to be 3.0 diameters downstream of the transition ductwork and 8.5 diameters upstream of the stack exit. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site. Boiler No. 1 is serviced by an electrostatic precipitator for the control of flyash emissions, a flue gas desulfurization (FGD) system for control of sulfur dioxide emissions, and a selective catalytic reduction (SCR) system for the control of oxides of nitrogen emissions. Sampling was conducted using an Apex Instruments XC-6000 EPC Appendix K Sorbent Trap Monitoring Syst em. Sorbent traps were analyzed in-house using an Ohio-Lumex RA – 915+

## Zeeman Mercury Spectrometer with a RP-M324 attachment. Details of operations, calibrations, and Quality Assurance/Control activities are presented in the appendices by test date,

# 4.0 FIGURES

4

## 5 FIGURE 1 EXHAUST STACK 245 FT. BIG BEND GENERATING STATION

O TLET

U 499 FT.



# N A

B C D

PORT LOCATION PLAN BOILER NO 

### 3 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0 STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 8.5 STACK DIAMETER = 28.8333 FT. ID. 254 FT

. STACK AREA = 652.948 SQ. FT. PORT LENGTH’S = 14 IN.

168 FT

. 86 FT.

FG D

PRESSURIZED ANNULUS

# APPENDIX A DATA ANALYSIS

# BIG BEND UNIT 3 05/14/2009

## Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

ng Area Area/ng Pass/Fail



## 2000 236000 118.000 Pass 

## 1000 126000 126.000 Pass



## 500 65100 130.200 Pass 

## 100 12000 120.000 Pass



## 50 5560 111.200 Pass 

## 10 1240 124.000 Pass Mean (Area/ng): 121.567 Standard Deviation: 6.6746 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00823



## Area Pass/Fail 

## Blank 161 Pass 

## 1.3 10 

## Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 46 99 

## 12-Jun-09

542 1040 1960No Description M, mg C, ng/g Area Maximum Time 1 condition 2000 1 2080 250000 17800 8:12:48 AM 2 BLANK 1 1.3 161 6 8:15:11 AM 3 Std__2000 1 1960 236000 21200 8:17:37 AM 4 Std__1000 1 1040 126000 22600 8:20:06 AM 5 Std__500 X 1 592 71100 8420 8:22:22 AM 6 Std__100 1 99 12000 1300 8:24:30 AM 7 Std__50 1 46 5560 1010 8:26:40 AM 8 Std__10 1 10 1240 119 8:28:46 AM 9 Std__500 1 542 65100 10900 8:38:13 AM 10 Trap #45246(BB#4-14 day) section 1A 1 2350 283000 16500 8:57:13 AM 11 Section 1B 1 1270 153000 9160 9:01:33 AM 12 Section 2A 1 2.8 336 18 9:05:13 AM 13 Section 2B 1 22 2750 183 9:08:54 AM 14 Section 3A 1 13 1620 54 9:17:16 AM 15 Section 3B 1 1.8 214 18 9:21:14 AM 16 Trap #452420(BB#4-14 day) section 1A 1 2350 283000 16400 9:25:52 AM 17 Section 1B 1 1090 132000 6600 9:28:19 AM 18 Section 2A 1 35 4230 223 9:32:23 AM 19 Section 2B 1 9.1 1090 51 9:34:38 AM 20 Section 3A 1 2.5 296 22 9:39:34 AM 21 Section 3B 1 -0.6 -78 3 9:49:39 AM 22 Trap#23710(BB#3-2 day) section 1 1 334 40200 4660 9:55:43 AM 23 Section 2 1 5.3 637 73 9:59:16 AM 24 Trap#23640(BB#3-2 day) section 1 1 319 38300 3010 10:05:22 AM 25 Section 2 1 0.1 8 5 10:08:43 AM 26 CCV 500 X 1 595 71500 11200 10:11:05 AM 27 CCV 500 X 1 627 75300 9300 10:15:01 AM 28 CCV 1000 1 1090 132000 15200 10:18:52 AM 29 Trap#23415(BB#3-4 day) section 1 1 31 3740 252 10:22:52 AM 30 Section 2 1 2.3 274 10 10:25:53 AM 31 Section 3 - 150ng spike 1 223 26800 1680 10:29:26 AM 32 Trap #43326(BB#3-4 day) section 1 1 47 5760 353 10:36:24 AM 33 Section 2 1 10 1260 63 10:41:50 AM 34 Trap#23661(BB#3-3 day) section 1 1 276 33200 2500 10:47:28 AM 35 Section 2 1 1.1 131 7 10:52:11 AM 36 Section 3-150ng spike 1 117 14100 992 10:54:58 AM 37 Trap #22996(BB#3-3 day) section 1 1 202 24300 1410 10:58:30 AM 38 Section 2 1 12 1490 131 11:01:23 AM 39 Trap #45220(BB#4-Ecotherm-4 day) section 1A 1 1140 138000 7720 11:06:45 AM 40 Section 1B 1 31 3800 353 11:09:51 AM 41 Section 2 1 5.6 668 74 11:13:20 AM 42 Section 3 1 0.2 21 5 11:16:08 AM 43 Trap #45250(BB#4-Ecotherm-4 day) section 1A 1 135 16300 1260 11:21:30 AM 44 1Environmental, Health, & Safety A ir Services Group

23415 43326 31 47 2.3 10 7.4% FAILED 21.3%

150 223 148.7% FAILED 0.0333 0.057 104.19 106.49

0.32 0.54 0.12 0.007 0.002 16.21 

### BB#3 - 4hr 05/14/2009 05/14/2009 05/14/2009 05/14/2009 BB#3 - 4hr BB#3 - 4hr BB#3 - 4hr lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) FAILED

Normalized Total Hg Mass (M*)

# BIG BEND UNIT 3 05/27/2009

## Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

ng Area Area/ng Pass/Fail



## 2000 236000 118.000 Pass 

## 1000 126000 126.000 Pass



## 500 65100 130.200 Pass 

## 100 12000 120.000 Pass



## 50 5560 111.200 Pass 

## 10 1240 124.000 Pass Mean (Area/ng): 121.567 Standard Deviation: 6.6746 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00823



## Area Pass/Fail 

## Blank 161 Pass 

## 1.3 10 

## Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 46 99 

## 12-Jun-09

542 1040 1960No Description M, mg C, ng/g Area Maximum Time 1 condition 2000 1 2080 250000 17800 8:12:48 AM 2 BLANK 1 1.3 161 6 8:15:11 AM 3 Std__2000 1 1960 236000 21200 8:17:37 AM 4 Std__1000 1 1040 126000 22600 8:20:06 AM 5 Std__500 X 1 592 71100 8420 8:22:22 AM 6 Std__100 1 99 12000 1300 8:24:30 AM 7 Std__50 1 46 5560 1010 8:26:40 AM 8 Std__10 1 10 1240 119 8:28:46 AM 9 Std__500 1 542 65100 10900 8:38:13 AM 10 Trap #45246(BB#4-14 day) section 1A 1 2350 283000 16500 8:57:13 AM 11 Section 1B 1 1270 153000 9160 9:01:33 AM 12 Section 2A 1 2.8 336 18 9:05:13 AM 13 Section 2B 1 22 2750 183 9:08:54 AM 14 Section 3A 1 13 1620 54 9:17:16 AM 15 Section 3B 1 1.8 214 18 9:21:14 AM 16 Trap #452420(BB#4-14 day) section 1A 1 2350 283000 16400 9:25:52 AM 17 Section 1B 1 1090 132000 6600 9:28:19 AM 18 Section 2A 1 35 4230 223 9:32:23 AM 19 Section 2B 1 9.1 1090 51 9:34:38 AM 20 Section 3A 1 2.5 296 22 9:39:34 AM 21 Section 3B 1 -0.6 -78 3 9:49:39 AM 22 Trap#23710(BB#3-2 day) section 1 1 334 40200 4660 9:55:43 AM 23 Section 2 1 5.3 637 73 9:59:16 AM 24 Trap#23640(BB#3-2 day) section 1 1 319 38300 3010 10:05:22 AM 25 Section 2 1 0.1 8 5 10:08:43 AM 26 CCV 500 X 1 595 71500 11200 10:11:05 AM 27 CCV 500 X 1 627 75300 9300 10:15:01 AM 28 CCV 1000 1 1090 132000 15200 10:18:52 AM 29 Trap#23415(BB#3-4 day) section 1 1 31 3740 252 10:22:52 AM 30 Section 2 1 2.3 274 10 10:25:53 AM 31 Section 3 - 150ng spike 1 223 26800 1680 10:29:26 AM 32 Trap #43326(BB#3-4 day) section 1 1 47 5760 353 10:36:24 AM 33 Section 2 1 10 1260 63 10:41:50 AM 34 Trap#23661(BB#3-3 day) section 1 1 276 33200 2500 10:47:28 AM 35 Section 2 1 1.1 131 7 10:52:11 AM 36 Section 3-150ng spike 1 117 14100 992 10:54:58 AM 37 Trap #22996(BB#3-3 day) section 1 1 202 24300 1410 10:58:30 AM 38 Section 2 1 12 1490 131 11:01:23 AM 39 Trap #45220(BB#4-Ecotherm-4 day) section 1A 1 1140 138000 7720 11:06:45 AM 40 Section 1B 1 31 3800 353 11:09:51 AM 41 Section 2 1 5.6 668 74 11:13:20 AM 42 Section 3 1 0.2 21 5 11:16:08 AM 43 Trap #45250(BB#4-Ecotherm-4 day) section 1A 1 135 16300 1260 11:21:30 AM 44 1Environmental, Health, & Safety A ir Services Group

23710 23640 334 319 5.3 0.1 1.6% PASSED 0.0%

0.3393 0.3191 1198.964 1246.006 0.28 0.26 0.71 0.044 0.001

8.20 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B

Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L

lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. 

### BB#3 - 2 day 05/(27-29)/2009 05/(27-29)/2009 05/(27-29)/2009 05/(27-29)/2009 BB#3 - 2 day BB#3 - 2 day BB#3 - 2 day

# BIG BEND UNIT 3 05/29/2009

## Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

ng Area Area/ng Pass/Fail



## 2000 236000 118.000 Pass 

## 1000 126000 126.000 Pass



## 500 65100 130.200 Pass 

## 100 12000 120.000 Pass



## 50 5560 111.200 Pass 

## 10 1240 124.000 Pass Mean (Area/ng): 121.567 Standard Deviation: 6.6746 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00823



## Area Pass/Fail 

## Blank 161 Pass 

## 1.3 10 

## Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 46 99 

## 12-Jun-09

542 1040 1960No Description M, mg C, ng/g Area Maximum Time 1 condition 2000 1 2080 250000 17800 8:12:48 AM 2 BLANK 1 1.3 161 6 8:15:11 AM 3 Std__2000 1 1960 236000 21200 8:17:37 AM 4 Std__1000 1 1040 126000 22600 8:20:06 AM 5 Std__500 X 1 592 71100 8420 8:22:22 AM 6 Std__100 1 99 12000 1300 8:24:30 AM 7 Std__50 1 46 5560 1010 8:26:40 AM 8 Std__10 1 10 1240 119 8:28:46 AM 9 Std__500 1 542 65100 10900 8:38:13 AM 10 Trap #45246(BB#4-14 day) section 1A 1 2350 283000 16500 8:57:13 AM 11 Section 1B 1 1270 153000 9160 9:01:33 AM 12 Section 2A 1 2.8 336 18 9:05:13 AM 13 Section 2B 1 22 2750 183 9:08:54 AM 14 Section 3A 1 13 1620 54 9:17:16 AM 15 Section 3B 1 1.8 214 18 9:21:14 AM 16 Trap #452420(BB#4-14 day) section 1A 1 2350 283000 16400 9:25:52 AM 17 Section 1B 1 1090 132000 6600 9:28:19 AM 18 Section 2A 1 35 4230 223 9:32:23 AM 19 Section 2B 1 9.1 1090 51 9:34:38 AM 20 Section 3A 1 2.5 296 22 9:39:34 AM 21 Section 3B 1 -0.6 -78 3 9:49:39 AM 22 Trap#23710(BB#3-2 day) section 1 1 334 40200 4660 9:55:43 AM 23 Section 2 1 5.3 637 73 9:59:16 AM 24 Trap#23640(BB#3-2 day) section 1 1 319 38300 3010 10:05:22 AM 25 Section 2 1 0.1 8 5 10:08:43 AM 26 CCV 500 X 1 595 71500 11200 10:11:05 AM 27 CCV 500 X 1 627 75300 9300 10:15:01 AM 28 CCV 1000 1 1090 132000 15200 10:18:52 AM 29 Trap#23415(BB#3-4 day) section 1 1 31 3740 252 10:22:52 AM 30 Section 2 1 2.3 274 10 10:25:53 AM 31 Section 3 - 150ng spike 1 223 26800 1680 10:29:26 AM 32 Trap #43326(BB#3-4 day) section 1 1 47 5760 353 10:36:24 AM 33 Section 2 1 10 1260 63 10:41:50 AM 34 Trap#23661(BB#3-3 day) section 1 1 276 33200 2500 10:47:28 AM 35 Section 2 1 1.1 131 7 10:52:11 AM 36 Section 3-150ng spike 1 117 14100 992 10:54:58 AM 37 Trap #22996(BB#3-3 day) section 1 1 202 24300 1410 10:58:30 AM 38 Section 2 1 12 1490 131 11:01:23 AM 39 Trap #45220(BB#4-Ecotherm-4 day) section 1A 1 1140 138000 7720 11:06:45 AM 40 Section 1B 1 31 3800 353 11:09:51 AM 41 Section 2 1 5.6 668 74 11:13:20 AM 42 Section 3 1 0.2 21 5 11:16:08 AM 43 Trap #45250(BB#4-Ecotherm-4 day) section 1A 1 135 16300 1260 11:21:30 AM 44 1Environmental, Health, & Safety A ir Services Group

23661 22996 276 202 1.1 12 0.4% PASSED 5.9%

150 117 78.0% PASSED 0.2771 0.214 903.314 445.214 0.31 0.48 1.91 0.119 0.002 14.54 

### BB#3 - 3 day 05/29-06/01/2009 05/29-06/01/2009 05/29-06/01/2009 05/29-06/01/2009 BB#3 - 3 day BB#3 - 3 day BB#3 - 3 day lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) FAILED

Normalized Total Hg Mass (M*)

# BIG BEND UNIT 3 07/31/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

ng Area Area/ng Pass/Fail



### 2000 233000 116.500 Pass 

### 1000 112000 112.000 Pass



### 500 54700 109.400 Pass 

### 100 10500 105.000 Pass



### 50 5070 101.400 Pass 

### 10 1240 124.000 Pass Mean (Area/ng): 111.3833 Standard Deviation: 8.1251 Relative Standard Deviation: 7 Pass Inverse of Mean, A: 0.00898



### Area Pass/Fail 

### Blank 298 Pass 

### 2000 ngCheck 205000 Pass 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 45 94 

### 14-Aug-09

491 1000 2090



### 1840 2.7 11No Description M, mg C, ng/g Area Maximum Time BB#3&4-(08-14-09)

1 condition__2000ng 1 2010 224000 20700 9:36:10 AM 2 BLANK 1 2.7 298 11 9:39:36 AM 3 Std__2000 1 2090 233000 16300 9:41:42 AM 4 Std__1000 1 1000 112000 11900 9:43:41 AM 5 Std__500 1 491 54700 8090 9:45:42 AM 6 Std__100 1 94 10500 962 9:47:40 AM 7 Std__50 1 45 5070 575 9:49:44 AM 8 Std__10 1 11 1240 111 9:51:48 AM 9 Trap#45280(BB4-7 day) sec 1A 1 553 61600 6230 10:24:06 AM 10 Sec 1B 1 1090 122000 9910 10:28:16 AM 11 Sec 1C 1 58 6470 346 10:31:57 AM 12 Sec 2A 1 1.3 140 11 10:34:11 AM 13 Sec 2B 1 1.4 158 7 10:36:59 AM 14 Sec 3A 1 1.3 147 8 10:40:03 AM 15 Sec 3B 1 2.5 279 8 10:42:10 AM 16 Trap#45249(BB4-7 day) sec 1A 1 2160 241000 13800 10:54:33 AM 17 Sec 1B 1 115 12900 1250 10:56:50 AM 18 Sec 1C 1 19 2160 118 10:59:32 AM 19 Sec 2A 1 0.7 80 14 11:01:32 AM 20 Sec 2B 1 6.5 722 57 11:06:06 AM 21 Sec 3A 1 1.4 153 6 11:09:36 AM 22 Sec 3B 1 0.4 41 5 11:11:35 AM 23 CCV 1000ng 1 942 105000 8030 11:13:45 AM 24 Trap#45245(BB4-14 day) sec 1A 1 2520 281000 15900 12:16:36 PM 25 Sec 1B 1 623 69400 6260 12:19:21 PM 26 Sec 2A 1 6.3 704 51 12:23:30 PM 27 Sec 2B 1 14 1650 214 12:26:44 PM 28 Sec 3A 1 1.0 116 7 12:29:33 PM 29 Sec 3B 1 13 1520 67 12:31:46 PM 30 Trap#39335(BB4-14 day) sec1A 1 1880 210000 34500 12:39:48 PM 31 Sec 1B 1 1.9 212 24 12:42:52 PM 32 Sec 1C 1 765 85300 4620 12:46:24 PM 33 Sec 2A 1 13 1500 76 12:48:36 PM 34 Sec 2B 1 -2.2 -240 3 12:50:43 PM 35 Sec 2C 1 11 1250 65 12:53:07 PM 36 Sec 3A - spike 4500ng 1 3400 379000 32100 12:56:01 PM 37 Sec 3B 1 96 10800 855 12:59:27 PM 38 CCV-2000ng 1 1850 207000 30400 1:01:39 PM 39 Trap#45252(BB3-14 day) sec 1A 1 1240 139000 9490 1:46:18 PM 40 Sec 1B 1 50 5580 637 1:49:01 PM 41 Sec 2A 1 7.2 806 54 1:51:12 PM 42 Sec 2B 1 6.6 731 55 1:54:09 PM 43 Sec 3A 1 -0.1 -8 5 1:56:49 PM 44 Sec 3B 1 0.6 66 8 1:58:47 PM 45 Trap#45016(BB3-14 day) sec 1A 1 1280 143000 9040 2:06:56 PM 46 Sec 1B 1 94 10500 1710 2:09:39 PM 47 Sec 1C 1 35 3960 198 2:12:13 PM 48 Sec 2A 1 -0.8 -92 7 2:14:29 PM 49 Sec 2B 1 3.6 396 22 2:16:25 PM 50 Sec 3A - spiked 4500ng 1 3170 354000 28300 2:19:26 PM 51 Sec 3B 1 337 37600 3750 2:21:24 PM 52 QCS - 2000ng 1 1690 189000 19000 2:23:42 PM 53 QCS - 2000ng 1 1680 188000 25500 2:27:24 PM 54 Std__2000ng 1 1730 193000 26300 2:31:18 PM 55 Std__2000ng 1 1840 205000 28000 2:35:21 PM 56 1Environmental, Health, & Safety A ir Services Group

45252 45016 1290 1409 14.4 3.6 1.1% PASSED 0.3% 4500 3507 77.9% PASSED 1.3044 1.4126 3549.199 3758.517 0.37 0.38 5.52 0.345 0.001 10.63 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B

Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L

lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. 

### BB#3 -14 day 07/31/09 - 08/12/09 07/31/09 - 08/12/09 07/31/09 - 08/12/09 07/31/09 - 08/12/09 BB#3 -14 day BB#3 -14 day BB#3 -14 day

# BIG BEND UNIT 3 09/14/2009

## Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

ng Area Area/ng Cal. ng Pass/Fail



## 2000 438000 219.000 1820 Pass 

## 1000 236000 236.000 981 Pass



## 500 117000 234.000 486 Pass 

## 100 24600 246.000 102 Pass



## 50 13000 260.000 54 Pass 

## 10 2460 246.000 10 Pass Mean (Area/ng): 240.1667 Standard Deviation: 13.8912 Relative Standard Deviation: 6 Pass Inverse of Mean, A: 0.00416 

## r2 

## 0.99928 PASS



## Area Pass/Fail 

## Blank 276 Pass 

## 2000 ngCheck 475000 Pass 

## 1970

1.1 Appendix K Mercury Analyzer Caibration

Calculated ng 15-Oct-09No Description M, mg C, ng/g Area Maximum Time BB-ST#1-2,3,4-(10-15-09)

1 condition 2000ng 1 2210 532000 37400 8:27:12 AM 2 BLANK 1 1.1 276 9 8:30:53 AM 3 Std__1000 1 1200 290000 18800 8:34:19 AM 4 Std__2000 1 1820 438000 39100 8:37:22 AM 5 Std__500 1 486 117000 8880 8:40:20 AM 6 Std__100 1 102 24600 1670 8:43:08 AM 7 Std__50 1 54 13000 917 8:46:29 AM 8 Std__10 1 10 2460 155 8:49:49 AM 9 Std__1000 1 981 236000 18200 8:59:19 AM 10 TrapB #54400-BB(stk#4)-7day-sec1 1 2000 483000 27600 9:21:18 AM 11 SEC 2 1 40 9840 422 9:26:01 AM 12 TrapA #54480-BB(stk#4)-7 day-sec1 1 1850 445000 32100 9:31:27 AM 13 SEC 2 1 37 9080 296 9:34:35 AM 14 TrapA #54482-BB(stk#3)-7 day-sec1 1 886 213000 14500 9:42:59 AM 15 SEC 2 1 15 3820 176 9:46:52 AM 16 TrapB #54479-BB(stk#3)-7 day-sec1 1 1080 261000 15200 9:54:12 AM 17 SEC 2 1 4.4 1050 37 9:57:33 AM 18 CCV-1000ng 1 985 237000 22100 10:00:50 AM 19 TrapB #001446-BB(stk#3)-spec 1 168 40600 2160 10:10:44 AM 20 TrapA #34705-BB(stk#3)-spec-sec1-kcl 1 7.3 1750 100 10:21:52 AM 21 SEC 2-kcl 1 0.2 59 11 10:25:28 AM 22 SEC 3-carbon 1 14 3400 206 10:29:07 AM 23 SEC 4-carbon 1 2.0 474 18 10:32:44 AM 24 TrapB #001430-BB(stk#4)-spec 1 0.8 190 10 10:47:31 AM 25 TrapA #34618-BB(stk#4)-spec-sec1-kcl 1 4.0 956 18 11:02:14 AM 26 SEC 1B-kcl 1 16 3960 79 11:05:29 AM 27 CCV-100ng 1 97 23500 1290 11:13:43 AM 28 SEC 2-kcl 1 0.4 99 9 11:26:43 AM 29 SEC 3-carbon 1 37 8930 619 11:31:20 AM 30 SEC 4-carbon 1 0.7 170 7 11:34:42 AM 31 CCV-100ng 1 94 22600 1140 12:38:16 PM 32 TrapB #54451-BB(cs01w)-spec-sec1-(09-14-09) 1 736 177000 10800 12:51:29 PM 33 SEC 2 1 13 3140 101 12:58:42 PM 34 TrapA #34640-BB(cs01w)-spec-sec2-kcl-(09-14-09) 1 0.6 154 8 1:07:54 PM 35 SEC 1-kcl 1 26 6310 261 1:14:42 PM 36 SEC 3-carbon 1 73 17600 1040 1:18:32 PM 37 SEC 4-carbon 1 2.1 498 27 1:23:30 PM 38 TrapA #45076-BB(cs01w)-sec1a-(09-16-09) 1 50 12200 322 1:34:22 PM 39 SEC 1b 1 32 7930 343 1:39:03 PM 40 SEC 2a 1 1.5 370 13 1:41:34 PM 41 SEC 2b 1 7.9 1910 84 1:44:56 PM 42 SEC 3a-spiked-4500ng 1 3180 765000 31900 1:48:09 PM 43 SEC 3b-spiked-4500ng 1 180 43500 1640 1:51:57 PM 44 CCV-2000ng 1 2030 488000 40000 1:55:30 PM 45 TrapB #45251-BB(cs01w)-sec1a-(09-16-09) 1 219 52700 1910 2:04:05 PM 46 SEC 1b 1 294 70800 2370 2:07:03 PM 47 SEC 2a 1 0.0 5 9 2:10:13 PM 48 SEC 2b 1 7.7 1860 107 2:15:04 PM 49 SEC 3a 1 0.9 220 9 2:18:41 PM 50 SEC 3b 1 1.4 348 16 2:21:52 PM 51 TrapA #45219-BB(cs01w)-sec2a-(10-05-09) 1 13 3230 97 2:29:40 PM 52 SEC 2b 1 0.6 142 6 2:32:34 PM 53 SEC 1A 1 17 4100 214 2:36:07 PM 54 SEC 1B 1 295 71000 3400 2:38:55 PM 55 SEC 1C 1 1860 449000 19600 2:42:40 PM 56 TrapB #39349-BB(cs01w)-sec1a-(10-05-09) 1 1640 395000 19300 2:47:38 PM 57 SEC 1b 1 91 22100 1230 2:50:30 PM 58 SEC 2a 1 0.8 199 16 2:55:04 PM 59 SEC 2b 1 0.5 117 13 2:57:38 PM 60 SEC 3a-spiked-4500ng 1 2600 626000 37400 3:00:54 PM 61 SEC 3b-spiked-4500ng 1 682 164000 6340 3:04:02 PM 62 QCS-2000ng 1 1970 475000 26900 3:07:06 PM 63 1Environmental, Health, & Safety A ir Services Group

34705-carbon 1446-carbon 14 168

2 0 14.3% FAILED 0.0%

0.016 0.168 49.164 51.99

0.33 3.23 0.77 0.048 0.012 104.85 

### BB-ST #3-speciated 09/14/2009 09/14/2009 09/14/2009 09/14/2009 BB-ST #3-speciated BB-ST #3-speciated BB-ST #3-speciated lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)Environmental, Health, & Safety A ir Services Group

34705-kcl7.3 0 0.2 0 2.7% PASSED #DIV/0!

0.0075 0 49.164 0.1 0.15 0.00 0.04 0.002 0.001

4.95 

### BB-ST #3-speciated 09/14/2009 09/14/2009 09/14/2009 09/14/2009 BB-ST #3-speciated BB-ST #3-speciated BB-ST #3-speciated lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) #DIV/0!

Normalized Total Hg Mass (M*)

# BIG BEND UNIT 3 09/15/2009

## Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

ng Area Area/ng Cal. ng Pass/Fail



## 2000 438000 219.000 1820 Pass 

## 1000 236000 236.000 981 Pass



## 500 117000 234.000 486 Pass 

## 100 24600 246.000 102 Pass



## 50 13000 260.000 54 Pass 

## 10 2460 246.000 10 Pass Mean (Area/ng): 240.1667 Standard Deviation: 13.8912 Relative Standard Deviation: 6 Pass Inverse of Mean, A: 0.00416 

## r2 

## 0.99928 PASS



## Area Pass/Fail 

## Blank 276 Pass 

## 2000 ngCheck 475000 Pass 

## 1970

1.1 Appendix K Mercury Analyzer Caibration

Calculated ng 15-Oct-09No Description M, mg C, ng/g Area Maximum Time BB-ST#1-2,3,4-(10-15-09)

1 condition 2000ng 1 2210 532000 37400 8:27:12 AM 2 BLANK 1 1.1 276 9 8:30:53 AM 3 Std__1000 1 1200 290000 18800 8:34:19 AM 4 Std__2000 1 1820 438000 39100 8:37:22 AM 5 Std__500 1 486 117000 8880 8:40:20 AM 6 Std__100 1 102 24600 1670 8:43:08 AM 7 Std__50 1 54 13000 917 8:46:29 AM 8 Std__10 1 10 2460 155 8:49:49 AM 9 Std__1000 1 981 236000 18200 8:59:19 AM 10 TrapB #54400-BB(stk#4)-7day-sec1 1 2000 483000 27600 9:21:18 AM 11 SEC 2 1 40 9840 422 9:26:01 AM 12 TrapA #54480-BB(stk#4)-7 day-sec1 1 1850 445000 32100 9:31:27 AM 13 SEC 2 1 37 9080 296 9:34:35 AM 14 TrapA #54482-BB(stk#3)-7 day-sec1 1 886 213000 14500 9:42:59 AM 15 SEC 2 1 15 3820 176 9:46:52 AM 16 TrapB #54479-BB(stk#3)-7 day-sec1 1 1080 261000 15200 9:54:12 AM 17 SEC 2 1 4.4 1050 37 9:57:33 AM 18 CCV-1000ng 1 985 237000 22100 10:00:50 AM 19 TrapB #001446-BB(stk#3)-spec 1 168 40600 2160 10:10:44 AM 20 TrapA #34705-BB(stk#3)-spec-sec1-kcl 1 7.3 1750 100 10:21:52 AM 21 SEC 2-kcl 1 0.2 59 11 10:25:28 AM 22 SEC 3-carbon 1 14 3400 206 10:29:07 AM 23 SEC 4-carbon 1 2.0 474 18 10:32:44 AM 24 TrapB #001430-BB(stk#4)-spec 1 0.8 190 10 10:47:31 AM 25 TrapA #34618-BB(stk#4)-spec-sec1-kcl 1 4.0 956 18 11:02:14 AM 26 SEC 1B-kcl 1 16 3960 79 11:05:29 AM 27 CCV-100ng 1 97 23500 1290 11:13:43 AM 28 SEC 2-kcl 1 0.4 99 9 11:26:43 AM 29 SEC 3-carbon 1 37 8930 619 11:31:20 AM 30 SEC 4-carbon 1 0.7 170 7 11:34:42 AM 31 CCV-100ng 1 94 22600 1140 12:38:16 PM 32 TrapB #54451-BB(cs01w)-spec-sec1-(09-14-09) 1 736 177000 10800 12:51:29 PM 33 SEC 2 1 13 3140 101 12:58:42 PM 34 TrapA #34640-BB(cs01w)-spec-sec2-kcl-(09-14-09) 1 0.6 154 8 1:07:54 PM 35 SEC 1-kcl 1 26 6310 261 1:14:42 PM 36 SEC 3-carbon 1 73 17600 1040 1:18:32 PM 37 SEC 4-carbon 1 2.1 498 27 1:23:30 PM 38 TrapA #45076-BB(cs01w)-sec1a-(09-16-09) 1 50 12200 322 1:34:22 PM 39 SEC 1b 1 32 7930 343 1:39:03 PM 40 SEC 2a 1 1.5 370 13 1:41:34 PM 41 SEC 2b 1 7.9 1910 84 1:44:56 PM 42 SEC 3a-spiked-4500ng 1 3180 765000 31900 1:48:09 PM 43 SEC 3b-spiked-4500ng 1 180 43500 1640 1:51:57 PM 44 CCV-2000ng 1 2030 488000 40000 1:55:30 PM 45 TrapB #45251-BB(cs01w)-sec1a-(09-16-09) 1 219 52700 1910 2:04:05 PM 46 SEC 1b 1 294 70800 2370 2:07:03 PM 47 SEC 2a 1 0.0 5 9 2:10:13 PM 48 SEC 2b 1 7.7 1860 107 2:15:04 PM 49 SEC 3a 1 0.9 220 9 2:18:41 PM 50 SEC 3b 1 1.4 348 16 2:21:52 PM 51 TrapA #45219-BB(cs01w)-sec2a-(10-05-09) 1 13 3230 97 2:29:40 PM 52 SEC 2b 1 0.6 142 6 2:32:34 PM 53 SEC 1A 1 17 4100 214 2:36:07 PM 54 SEC 1B 1 295 71000 3400 2:38:55 PM 55 SEC 1C 1 1860 449000 19600 2:42:40 PM 56 TrapB #39349-BB(cs01w)-sec1a-(10-05-09) 1 1640 395000 19300 2:47:38 PM 57 SEC 1b 1 91 22100 1230 2:50:30 PM 58 SEC 2a 1 0.8 199 16 2:55:04 PM 59 SEC 2b 1 0.5 117 13 2:57:38 PM 60 SEC 3a-spiked-4500ng 1 2600 626000 37400 3:00:54 PM 61 SEC 3b-spiked-4500ng 1 682 164000 6340 3:04:02 PM 62 QCS-2000ng 1 1970 475000 26900 3:07:06 PM 63 1Environmental, Health, & Safety A ir Services Group

54482 54479 886 1080

15 4.4 1.7% PASSED 0.4%

0.901 1.0844 2070.664 2210.983 0.44 0.49 4.23 0.265 0.002 13.80 

### BB #3 - 7 day 09/ (15-22) /2009 09/ (15-22) /2009 09/ (15-22) /2009 09/ (15-22) /2009 BB #3 - 7 day BB #3 - 7 day BB #3 - 7 day lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.

lbs 

## /hr. Sample MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sample MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)