1750 East Club Boulevard 

 Durham, NC 27704 

 Phone: (919) 220-2570 

 Fax: (919) 220-4540 

Certificate of Analysis

Customer: 

Enthalpy Analytical, Inc. . Cylinder Number: CC157718 

2202 Ellis Road, Suite A Cylinder Size/CGA: AL150/350 

Durham, NC 27703-5518 Fill Pressure: 2000 PSIA 

 Gas Volume: 3700 liters 

Tel: (919) 850-4392 Date of Mfg: 6/18/09 

 Expiration Date: 6/18/10 

Customer Number Ship VIA Job No. Customer PO Mixture Type 

00127703NC Pick up 061809-002 CMD052809JCB Gravimetric 

Component Nominal 

Concentration 

Actual 

Concentration* 

Mixture Type 

Acetaldehyde 250 ppm 250 ppm +/- 5 ppm Gravimetric Master Gas 

Nitrogen balance balance 

NOTES: Blend Tolerance: +/-2%

 Analytical Tolerance: +/-2%

 Traceability: NIST by weight set / Internal Standards by analysis 

 Reactive Mixtures: Analyzed twice with required agreement between analyses of 2%. 

 Required wait time between analyses of >7 days. 

 Caution: Do not use below 150 PSIG.

Authorized Signature: 

 Joseph A. Ernst 

*Every effort has been made to establish the actual concentration of the components using master gas 

blending technology however, Custom Gas Solutions shall have no liability in excess of the established 

charge for this material. 






 1750 East Club Boulevard 

 Durham, NC 27704 

 Phone: (919) 220-2570 

 Fax: (919) 220-4540 

Certificate of Analysis

Customer: 

Enthalpy Analytical, Inc. . Cylinder Number 2777164Y 

2202 Ellis Road, Suite A Cylinder Size/CGA: ST300/350 

Durham, NC 27703-5518 Fill Pressure: 450 PSIA 

 Gas Volume: 1500 liters 

Tel: (919) 850-4392 Date of Mfg: 2/10/09 

 Expiration Date: 2/10/11 

Customer Number Ship VIA Job No. Customer PO Mixture Type 

00127703NC Pick up 021009-010 CMD012709DMB

JCB 

Gravimetric 

Component Nominal 

Concentration 

Actual Concentration* Mixture Type 

n-Heptane 500 ppm 500.4 ppm +/- 10 ppm Gravimetric Master Gas 

n-Hexane 1000 ppm 998 ppm +/- 20 ppm 

n-Pentane 2000 ppm 2004 ppm +/- 40 ppm 

n-Butane 1% 1.02% +/- 0.02% 

Propane 5% 5.00% +/- 0.10% 

Ethane 5% 5.02% +/- 0.10% 

Nitrogen Balance Balance 

NOTES: Blend Tolerance: +/-2%

 Analytical Tolerance: +/-2%

Authorized Signature: Stephen Vaughan (electronic) 

 Stephen Vaughan, PhD 

*Every effort has been made to establish the actual concentration of the components using master gas 

blending technology however, Custom Gas Solutions shall have no liability in excess of the established 

charge for this material. 

This Is The Last Page

Of This Report.
Civil and Environmental 

Consultants, Inc. 

4848 Park 370 Blvd, Suite F 

Hazelwood, MO 63042

KCP&L ICR Testing - La Cygne Station 

Client # 100-208-0004 

Analytical Report 

(0410-11)

EPA Method 26A

Hydrogen Chloride, Hydrogen Fluoride 

EPA CTM 33

Hydrogen Cyanide 

EPA OTM 27 

Particulate Matter 

EPA OTM 28 

Condensible Particulate Matter 

HPLC Analysis 

Sulfate 

Enthalpy Analytical, Inc. 

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 

2202 Ellis Road Durham, NC 27703 - 5518 
I certify that to the best of my knowledge all analytical data presented in this report: 

 Have been checked for completeness 

 Are accurate, error-free, and legible 

 Have been conducted in accordance with approved protocol, and that all deviations and analytical 

problems are summarized in the appropriate narrative(s) 

This analytical report was prepared in Portable Document Format (.PDF) and contains ??? pages. 
Summary of Results
Compound Sample ID / Catch Weight (ug)

Run 1 C3 Run 2 C3 Run 3 C3

Hydrogen Fluoride 3,012 J 2,805 J 4,135 J

Hydrogen Chloride 2,794 J 3,461 J 2,899 J

BT C3 H2SO4 0.01N H2SO4/NaOH M MS Run 1 C3

Hydrogen Fluoride 100 ND 0 ND 37

Hydrogen Chloride 97.9 ND 0 ND 33

Company

Analyst

Parameters

# Samples

Civil & Environ. Consult.

EO

EPA Method 26A

3 Runs, 1 Blank

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/10/2010

0410-11 res m26a 6/10/2010
Compound Sample ID / Catch Weight (ug)

CTM033-C3 A-C & C5

Run 1 Run 2 Run 3

Hydrogen Cyanide 61.0 ND 56.7 ND 56.6 ND

BT

Hydrogen Cyanide 47.2 ND

Company

Analyst

Parameters

# Samples

Civil & Environ. Consultants

ARM

EPA CTM-033, Pb Ace. & NaOH

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/29/2010

0410-11 res ctm33 6/29/2010
Compound Sample ID / Catch Weight (mg)

Run 1 Run 2 Run 3

47 mm Filter 12.5 11.2 8.0

>2.5 PM 6.9 3.1 2.9

< 2.5 PM 1.8 0.8 2.0

TOTAL 21.2 15.0 12.9

Blank Train #REF! #REF!

47 mm Filter 0.4 11.17 8.01

>2.5 PM 0.3 3.08 2.88

< 2.5 PM 0.3 0.77 2.02

TOTAL 1.1 15.02 12.91

Company

Analyst

Parameters

# Samples

Civil & Environ. Consult.

KTH

EPA OTM 27

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/9/2010
Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Run 1 Run 2 Run 3

Net Organic Catch 4.4 3.9 3.3

Corrected Inorganic 14.6 16.0 17.0

TB Corrected CPM 17.0 17.8 18.4

Train Blank

Organic Catch 2.1 If Train Blank Corrected CPM is >2.0 mg,

Inorganic Catch 1.1 then sample correction is 2.0 mg.

CPM 3.2

Company

Analyst

Parameters

# Samples

Civil & Environ. Consult.

KTH

EPA OTM 28

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/9/2010

0410-11 res OTM-028 6/10/2010
Compound Sample ID / Catch Weight (ug)

OTM 28 Inorganic Fraction

Run 1 Post Run 2 Post Run 3 Post

Sulfate 2,477 2,925 2,694 

Train Blank Post In House Blank Post MB/ DI H2O

Sulfate 25.8 6 J 0.1 ND

Company

Analyst

Parameters

# Samples

Civil & Environ. Consult.

ARM

HPLC/IC Analysis

3 Runs, 1 Blank

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

110-208

6/10/2010

0410-11 res so4 6/10/2010
Results
MDL 0.0200 (ug/mL) Lower Curve Limit 1.00 (ug/mL)

LOQ 1.00 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Acid 

Convers

Factor

Run 1 C3 015-1701.D 015-1702.D HPLC51PG128.M 3.03 3.03 0.0 0.227 0.209 4.2 0.218 1.053 Run 2 C3 018-2201.D 018-2202.D HPLC51PG128.M 3.04 3.04 0.0 0.212 0.210 0.5 0.211 1.053 Run 3 C3 019-2301.D 019-2302.D HPLC51PG128.M 3.04 3.04 0.1 0.294 0.267 4.7 0.281 1.053 

BT C3 H2SO4 Blank 020-2401.D 020-2402.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 

0.01N H2SO4/NaOH MB 007-0901.D 007-0902.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 

MS Run 1 C3 016-2001.D 016-2002.D HPLC51PG128.M 3.04 3.04 0.0 3.47 3.49 0.2 3.48 1.053 

S

Na

Sp

MSD Run 1 C3 017-2101.D 017-2102.D HPLC51PG128.M 3.04 3.04 0.0 3.43 3.46 0.5 3.44 1.053 

S

Na

Sp

HPLC51pg110 #LCS 006-0801.D 006-0802.D HPLC51PG128.M 3.04 3.04 0.0 4.27 4.31 0.5 4.29 1.053 

S

Sp

Hydrogen Fluoride as Fluoride

Company

Analyst

Parameters

# Samples

Civil & Environmental ConsultantsEOEPA Method 26A3 Runs, 1 Blank

Client #

Job #

PO #

Report Date

100-208-00040410-11100-2086/10/2010

0410-11 res m26a 
MDL 0.0200 (ug/mL) Lower Curve Limit 1.00 (ug/mL)

LOQ 1.00 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Acid 

Convers

Factor

Run 1 C3 015-1701.D 015-1702.D HPLC51PG128.M 4.07 4.07 0.1 0.207 0.208 0.0 0.207 1.028 Run 2 C3 018-2201.D 018-2202.D HPLC51PG128.M 4.08 4.09 0.1 0.268 0.267 0.1 0.267 1.028 Run 3 C3 019-2301.D 019-2302.D HPLC51PG128.M 4.09 4.09 0.0 0.201 0.201 0.0 0.201 1.028 

BT C3 H2SO4 Blank 020-2401.D 020-2402.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 

0.01N H2SO4/NaOH MB 007-0901.D 007-0902.D HPLC51PG128.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 

MS Run 1 C3 016-2001.D 016-2002.D HPLC51PG128.M 4.07 4.07 0.0 3.24 3.24 0.1 3.24 1.028 

S

Na

Sp

MSD Run 1 C3 017-2101.D 017-2102.D HPLC51PG128.M 4.08 4.08 0.0 3.22 3.23 0.1 3.22 1.028 

S

Na

Sp

HPLC51pg110 #LCS 006-0801.D 006-0802.D HPLC51PG128.M 4.07 4.07 0.0 3.96 3.97 0.1 3.96 1.028 

S

Sp

Hydrogen Chloride as Chloride

Company

Analyst

Parameters

# Samples

Civil & Environmental ConsultantsEOEPA Method 26A3 Runs, 1 Blank

Client #

Job #

PO #

Report Date

100-208-00040410-11100-2086/10/2010

0410-11 res m26a 
MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL)

LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL)

Compound

Sample

ID Lab ID Analysis

Method

Ret 

Time 

(min)

Conc

(ug/mL) DF Vol

(mL)

Catch

Weight

(ug)

Qual

CTM033-R1-C3A-C 010-1101.D 1000.M NA 0.0143 5 853 61.0 ND

CTM033-R1-C5 011-1201.D 1000.M NA 0.0143 5 156 11.2 ND

61.0 ND

CTM033-R2-C3A-C 012-1301.D 1000.M NA 0.0143 5 793 56.7 ND

CTM033-R2-C5 013-1401.D 1000.M NA 0.0143 5 248 17.7 ND

56.7 ND

CTM033-R3-C3A-C 014-1501.D 1000.M NA 0.0143 5 792 56.6 ND

CTM033-R3-C5 015-1601.D 1000.M NA 0.0143 5 233 16.7 ND

56.6 ND

CTM033-BT-C3A-C 016-1701.D 1000.M NA 0.0143 5 661 47.2 ND

CTM033-BT-C5 017-1801.D 1000.M NA 0.0143 5 155 11.1 ND

47.2 ND

0.1N NaOH - RB 007-0801.D 1000.M NA 0.0143 1 1.00 0.0143 ND

0.1N NaOH - RB 007-0802.D 1000.M NA 0.0143 1 1.00 0.0143 ND

Hplc50pg128 #LCS 008-0901.D 1000.M 7.98 1.12 1 0.525 0.588 

Hplc50pg128 #LCS 008-0902.D 1000.M 7.99 1.13 1 0.525 0.595 

0.591

Spike Amount (ug) 0.520

Spike Recovery (%) 114%

MS/CTM033-R1-C3A-C 018-1901.D 1000.M 8.00 1.13 1 0.525 0.596 

Spike Amount (ug) 0.520

Native Amount (ug) 0.00

Spike Recovery (%) 115%

Hydrogen Cyanide

Company

Analyst

Parameters

# Samples

Civil & Environ. Consultants

ARM

EPA CTM-033, Pb Ace. & NaOH

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/29/2010

0410-11 res ctm33 7/2/2010
MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL)

LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL)

Compound

Sample

ID Lab ID Analysis

Method

Ret 

Time 

(min)

Conc

(ug/mL) DF Vol

(mL)

Catch

Weight

(ug)

Qual

Hydrogen Cyanide

Company

Analyst

Parameters

# Samples

Civil & Environ. Consultants

ARM

EPA CTM-033, Pb Ace. & NaOH

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/29/2010

MSD/CTM033-R1-C3A-C 019-2201.D 1000.M 8.02 1.16 1 0.525 0.610 

Spike Amount (ug) 0.520

Native Amount (ug) 0.00

Spike Recovery (%) 117%

LD/CTM033-R1-C3A-C 020-2301.D 1000.M NA 0.0143 5 853 61.0 ND

% Difference NA

0410-11 res ctm33 7/2/2010
Other Test Method 027 (OTM-027) - Particulate Determination - Data Analysis

Analysis of Particulate Recovery

Sample ID Run 1 Run 2 Run 3 Blank Train

47 mm Filter ID 2441 Dates 2436 Dates 2437 Dates 2439 Dates

Final wt. (g) 1st 0.12478 5/29/10 0.12410 5/29/10 0.12066 5/29/10 0.11326 5/29/10

Final wt. (g) 2nd 0.12470 5/31/10 0.12403 5/31/10 0.12060 5/31/10 0.11325 5/31/10

Final Tare Weight (g) 0.11216 5/28/10 0.11287 5/28/10 0.11259 5/28/10 0.11283 5/28/10

Net filter catch (mg) 12.5 11.2 8.0 0.4

>2.5 PM Acetone Rinses

Beaker number 3960 Dates 3961 Dates 3962 Dates 3963 Dates

Final wt (g) 1st 1.90795 6/7/10 1.93430 6/7/10 1.92991 6/7/10 1.89520 6/7/10

Final wt (g) 2nd 1.90780 6/8/10 1.93406 6/8/10 1.92965 6/8/10 1.89514 6/8/10

 Beaker tare (g) 1.90092 5/28/10 1.93098 5/28/10 1.92677 5/28/10 1.89484 5/28/10

Acetone vol (mL) 36 25 21 41

>2.5 PM Catch (mg) 6.9 3.1 2.9 0.3

<2.5 PM Acetone Rinses

Beaker number 3956 Dates 3957 Dates 3958 Dates 3959 Dates

Final wt (g) 1st 1.92339 6/7/10 1.93062 6/7/10 1.94344 6/7/10 1.94628 6/7/10

Final wt (g) 2nd 1.92328 6/8/10 1.93041 6/8/10 1.94325 6/8/10 1.94610 6/8/10

 Beaker tare (g) 1.92153 5/28/10 1.92964 5/28/10 1.94123 5/28/10 1.94575 5/28/10

Acetone vol (mL) 39 37 36 35

<2.5 PM Catch (mg) 1.8 0.8 2.0 0.3

Total particulate (mg) 21.2 15.0 12.9 1.1

 In-House Blank Acetone Analysis

Blank beaker number 3914 Dates

Blank volume (mL) 200 Dates Final wt (g) 1st 1.89916 6/7/10

Beaker tare (g) 1.89890 5/27/10 Final wt (g) 2nd 1.89917 6/8/10

Max acetone residue (g) 0.0016 Acetone residue (g) 0.0003

Company

Analyst

Parameters

# Samples

Civil & Environmental Consultants

KTH

EPA OTM 27

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/9/10
Analysis of Condensible Particulate Recovery

Sample ID Number Train Blank Run 1 Run 2 Run 3

Organic

Beaker Number 3912 3909 3910 3911

Initial MeCl2/Acetone Volume, mL 134 172 178 170

Lab MeCl2 Volume, mL 165 Dates 165 Dates 165 Dates 165 

Final Weight, g 1.8959 6/7/10 1.8936 6/7/10 1.8791 6/7/10 1.8865 

Reweigh, Final, g 1.8960 6/8/10 1.8937 6/8/10 1.8792 6/8/10 1.8866 

Beaker Tare, g 1.8939 5/27/10 1.8893 5/27/10 1.8753 5/27/10 1.8832 5

Net Organic Catch, mg 2.1 4.4 3.9 3.3

Inorganic

Beaker Number 4089 Dates 4086 Dates 4087 Dates 4088 

Final Weight, g 1.8946 6/7/10 1.9528 6/7/10 1.9487 6/7/10 1.9548 

Reweigh, Final, g 1.8945 6/8/10 1.9525 6/8/10 1.9484 6/8/10 1.9544 

Beaker Tare, g 1.8935 6/1/10 1.9337 6/1/10 1.9280 6/1/10 1.9329 

H2O FV, mL 140 324 412 356

Resuspended Volume, mL 100.0 100.0 100.0 100.0

Removed Pre-aliquot, mL 0.5 0.5 0.5 0.5

Pre-aliquot CF 1.00 1.00 1.00 1.00

Removed Post-aliquot, mL 0.5 0.5 0.5 0.5

Post-aliquot CF 1.01 1.01 1.01 1.01

Net Inorganic, mg 1.1 19.0 20.6 21.7

Ammonium Correction, mg 0.0 4.4 4.6 4.7

Corrected Inorganic, mg 1.1 14.6 16.0 17.0

Condensible Particulate Matter, mg 3.2 19.0 19.8 20.4

TB Corrected CPM, mg 17.0 17.8 18.4

----------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------

Type Blank MeCl Blank Type Blank H2O Blank Type Blank 

Beaker Number 3913 Dates Beaker Number 4090 Dates Beaker Numb

Tare weight, g 1.8990 5/27/10 Tare weight, g 1.8880 6/1/10 Tare weight, 

Dry Residue Weight, g 1.9020 6/7/10 Dry Residue Weight, g 1.8887 6/7/10 Dry Residue Wei

Reweigh, Final, g 1.9021 6/8/10 Reweigh, Final, g 1.8887 6/8/10 Reweigh, Fina

MeCl2 Residue, g 0.0032 Water Residue, g 0.0007 Acetone Residu

MeCl2 Volume, mL 225 Water Volume, mL 250 Acetone Volume

Max. MeCl2 Residue, g 0.0045 Max. Water Residue, g 0.0025 Max. Acetone Res

Company

Analyst

Parameters

# Samples

Civil & Environmental ConsultantsKTHEPA OTM-0283 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-00040410-11100-2086/9/2010
MDL 0.09 (mg Ammonium)

MDL 0.26 (mg Sulfate)

Blank titrant amount (Vtb) 0.03 [Set this equal to the In-House Blank Titration Volume and then white out this note]

NH4OH normality 0.1 Lot # Sigma Aldrich 318620

Sample ID.

Volume

Resuspended

(mL)

Titration

Aliquot

Vol (mL)

Aliquot Factor 

(mL rec'd/aliq mL)

Train Blank 100 99.5 0.05 ND 1.01 0.26 ND 0.09 ND

Run 1 100 99.5 2.60 1.01 12.41 4.40

Run 2 100 99.5 2.72 1.01 12.99 4.60

Run 3 100 99.5 2.76 1.01 13.18 4.67

In House 100 99.5 0.03 ND 1.01 0.26 ND 0.09 ND

SO4 Catch

(mg)

NH4OH

Titration

Vol (mL)

Ammonium

equivalent

(mg)

Company

Analyst

Parameters

# Samples

Civil & Environmental Consultants

KTH

EPA OTM-028

3 Runs, 1 Blank Train

Client #

Job #

PO #

Report Date

100-208-0004

0410-11

100-208

6/9/2010
MDL 0.0605 (ug/mL) Lower Curve Limit 0.500 (ug/mL)

LOQ 0.500 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Run 1 Post 021-1501.D 021-1502.D HPLC49PG26.M 10.08 10.08 0.0 6.19 6.20 0.0 6.19 Run 2 Post 024-1801.D 024-1802.D HPLC49PG26.M 10.08 10.08 0.0 7.70 6.93 5.3 7.31 Run 3 Post 025-1901.D 025-1902.D HPLC49PG26.M 10.08 10.07 0.0 6.72 6.76 0.3 6.74 

Train Blank Post 026-2201.D 026-2202.D HPLC49PG26.M 10.07 10.06 0.0 1.32 1.26 2.2 1.29 

In House Blank Post 027-2301.D 027-2302.D HPLC49PG26.M 10.09 10.09 0.0 0.310 0.315 0.7 0.313 

MB/ DI H2O 007-0901.D 007-0902.D HPLC49PG26.M NA NA NA 0.0605 0.0605 0.0 0.0605 

hplc49pg22 #LCS 006-0801.D 006-0802.D HPLC49PG26.M 10.05 10.05 0.0 5.04 5.08 0.4 5.06 

Spike 

Spike 

MS Run 1 Post 022-1601.D 022-1602.D HPLC49PG26.M 10.08 10.08 0.1 9.44 9.44 0.0 9.44 

Spike 

Native 

Spike 

MSD Run 1 Post 023-1701.D 023-1702.D HPLC49PG26.M 10.08 10.07 0.1 9.43 9.42 0.0 9.42 

Spike 

Native 

Spike 

Sulfate

Company

Analyst

Parameters

# Samples

Civil & Environmental ConsultantsARM

HPLC/IC Analysis3 Runs, 1 Blank

Client #

Job #

PO #

Report Date

100-208-00040410-11110-2086/10/2010

0410-11 res so4 
Narrative Summary
Enthalpy Analytical Narrative Summary 

Company Civil and Environmental 

Consultants, Inc.

Client # 100-208-0004

Analyst EO Job # 0410-11 

Parameters EPA Method 26A PO # 100-208 

# Samples 3 Runs, 1 Blank Report Date June 10, 2010 

Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished 

by Civil and Environmental Consultants, Inc. The samples were 

received at 24.3C in good condition. The samples were received in 

glass containers. Prior to, during, and after analysis, the samples were 

kept under lock with access only to authorized personnel by Enthalpy 

Analytical, Inc. 

Analysis The samples were analyzed for hydrogen chloride (HCl) and hydrogen 

fluoride (HF) using the analytical procedures in EPA Method 26A, 

Determination of Hydrogen Halide and Halogen Emissions from 

Stationary Sources Isokinetic Method (40 CFR Part 60, Appendix A). 

The samples were analyzed following the procedures in Section 11.0, 

Analytical Procedures. All samples and standards are prepared, stored, 

and analyzed using high-density polyethylene containers. 

The Metrohm 861 Compact IC "Smithers" (S/N 1861002007189) was 

equipped with a Metrohm 861 Conductivity Detector and a Metrosep A 

Supp 5 - 110/4.0mm column (S/N # 7908289), for these analyses. 

Calibration The calibration curve is included in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

The first page of the curve contains all method specific parameters (i.e., 

curve type, origin, weight, etc.) used to quantify the samples. The 

calibration curve section also includes a table with the Retention Time 

(RetTime), Level (Lvl), Amount (corresponding units), Area, Response 

Factor (Amt/Area) and the analyte Name. The calibration table is used 

to identify (by retention time) and quantify each target compound. 

Chromatographic 

Conditions 

A copy of the acquisition method Metrohm.M is included in the 

Calibration Curve Chromatograms section of this report. 

QC Notes The analysis of the blank received with these samples contained no 

target compounds at concentrations greater than the MDL. 

The analysis of the laboratory reagent blank contained no target 

compounds at concentrations greater than the MDL. 
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes 

(continued) 

The analysis of the LCS exhibited a recovery value of 107% for 

hydrogen fluoride and 99.0% for hydrogen chloride. 

The analyses of the duplicate matrix spikes prepared using sample Run 

1 C3 exhibited recovery values within 10% of the expected values. 

All samples were analyzed within the four-week holding time specified 

in the method. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

The H2SO4 matrix samples were analyzed for Cl- and F- but are reported 

as HCl and HF. The results were converted using an acid conversion 

factor of 1.028 for HCl and 1.053 for HF. 

Enthalpy Analytical, Inc. is accredited to perform EPA Method 26A for 

compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 
Enthalpy Analytical Narrative Summary 

Company Civil and Environmental 

Consultants, Inc.

Client # 100-208-0004

Analyst ARM Job # 0410-11 

Parameters EPA CTM-033 PO # 100-208 

# Samples 3 Runs, 1 Blank Train Report Date June 29, 2010 

Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished 

by Civil and Environmental Consultants, Inc. The samples were 

received at 24.3C in good condition. The pH of the sodium hydroxide 

fractions was 12 or greater; the pH of the lead acetate fractions was 4 or 

5. Prior to, during, and after analysis, the samples were kept under lock 

with access only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for hydrogen cyanide (HCN) using the 

analytical procedures in EPA Conditional Test Method 033, Sampling 

and Analysis for Hydrogen Cyanide Emissions from Stationary Sources. 

Proportional aliquots were taken from the three sodium hydroxide 

containers received for each run and combined for a single analysis. 

The DIONEX Model 500, High Performance Liquid Chromatograph 

("Grandmama") was equipped with a Dionex ED40 Electrochemical 

Detector and a Dionex Ion Pac AS7, 4 x 250 mm column (S/N 012759), 

for these analyses. 

Calibration As required by the method, a calibration verification standard was 

analyzed after every 10 samples. The acceptance criterion for the 

calibration verification standard is ± 10% of the expected value as 

quantified using the calibration curve. The calibration verification 

standards analyzed with these samples were outside the control limit at 

113% and 116%. Further analyses were not performed because the 

sample holding time had expired. 

The calibration curve is included in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

The first page of the curve contains all method specific parameters (i.e., 

curve type, origin, weight, etc.) used to quantify the samples. The 

calibration curve section also includes a table with the Retention Time 

(RetTime), Level (Lvl), Amount (corresponding units), Area, Response 

Factor (Amt/Area) and the analyte Name. The calibration table is used 

to identify (by retention time) and quantify each target compound. 
Enthalpy Analytical Narrative Summary 

(continued) 

Chromatographic 

Conditions 

A copy of the acquisition method 1000.M is included in the Calibration 

Curve Chromatograms section of this report. 

QC Notes The analysis of the blank received with the samples contained no 

hydrogen cyanide at a concentration greater that the MDL. 

The analysis of the laboratory reagent blank contained no hydrogen 

cyanide at a concentration greater than the MDL. 

The analysis of the LCS prepared with these samples exhibited a 

recovery value of 114%. 

The analyses of the duplicate matrix spikes prepared using sample R1-

C3A-C exhibited recovery values of 115% and 117%. The recovery 

value for the MSD was slightly outside the control limit of 115%. 

A Laboratory Duplicate (LD) analysis was performed using sample R1-

C3A-C. The results of the duplicate analysis did not differ from the 

results of the original analysis. 

Due to instrument problems which caused significant sample back log, 

these samples were analyzed 5 days outside the 30-day holding time 

specifed by the method. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

Enthalpy Analytical, Inc. is accredited to perform EPA CTM-033 for 

compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 
Enthalpy Analytical Narrative Summary 

Company Civil and Environmental 

Consultants, Inc.

Client # 100-208-0004

Analyst KTH Job # 0410-11 

Parameters EPA OTM 27 PO # 100-208 

# Samples 3 Runs, 1 Blank Train Report Date June 10, 2010 

Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished 

by Civil and Environmental Consultants, Inc. The samples were 

received at 24.3C in good condition. Prior to, during, and after 

analysis, the samples were kept under lock with access only to 

authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for particulate matter using EPA Other Test 

Method (OTM) 27, Determination of PM10 and PM2.5 Emissions from 

Stationary Sources (Constant Sampling Rate Procedures). 

The filters were placed in a dessicator for 24 hours. The filters were 

weighed at minimum 6-hour intervals until constant weights were 

achieved. 

The volumes of the acetone rinses were measured and recorded. The 

acetone rinses were transferred to tare weighed aluminum weighing 

pans and evaporated using nitrogen in a vented chamber. The residues 

were placed in a dessicator for 24 hours. The residues were weighed at 

minimum 6-hour intervals until constant weights were achieved. 

Samples were weighed on a Sartorius Model ME 5-F balance (SN 

23104965) certified by Precision Weighing, Inc. through the end of 

October 2010. 

QC Notes No adjustments to the results were made for the Train Blank. 

Reporting Notes Gravimetric analyses are considered accurate to ±0.5 mg. Therefore, 

negative catch weights between 0 and –0.5 mg are set to zero and no 

investigation is undertaken. Negative catch weights less than -0.5 mg 

are investigated. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 
Enthalpy Analytical Narrative Summary 

Company Civil and Environmental 

Consultants, Inc.

Client # 100-208-0004

Analyst KTH Job # 0410-11 

Parameters EPA OTM 28 PO # 100-208 

# Samples 3 Runs, 1 Blank Train Report Date June 10, 2010 

Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished 

by Civil and Environmental Consultants, Inc. The samples were 

received at 24.3C in good condition. Prior to, during, and after 

analysis, the samples were kept under lock with access only to 

authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for Particulate Matter using the analytical 

procedures in EPA Other Test Method (OTM) 28, Dry Impinger 

Method for Determining Condensable Particulate Emissions from 

Stationary Sources. 

Samples were weighed on a Sartorius Model ME 5-F balance (SN 

23104965) certified by Precision Weighing, Inc. through the end of 

October 2010. 

QC Notes The method specifies blank corrections are accomplished by subtracting 

the particulate mass determined in the ‘Field Train Blank’ or 2 mg 

(whichever is less) from the sample weight. Since the blank value is 

greater than 2.0 mg, 2.0 mg was used to correct the catch weights. 

The inorganic results for the samples were corrected for the ammonium 

ions used to precipitate the sulfate, per the formula in the Method 

(Section 12.2.1). 

Reporting Notes Gravimetric analyses are considered accurate to ±0.5 mg. Therefore, 

negative catch weights between 0 and –0.5 mg are set to zero and no 

investigation is undertaken. Negative catch weights less than -0.5 mg 

are investigated. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 
Enthalpy Analytical Narrative Summary 

Company Civil and Environmental 

Consultants, Inc.

Client # 100-208-0004

Analyst ARM Job # 0410-11 

Parameters HPLC Analysis PO # 100-208 

# Samples 3 Runs, 1 Blank Report Date June 10, 2010 

Custody Heather Tarjeft received the samples on 5/25/10 after being relinquished 

by Civil and Environmental Consultants, Inc. The samples were 

received at 24.3C in good condition. Prior to, during, and after 

analysis, the samples were kept under lock with access only to 

authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for sulfate (SO4) using the Agilent Model 

1100, High Performance Liquid Chromatograph (HPLC) "Gonzo" 

equipped with a Dionex ED40 Electrochemical Detector and a Dionex 

Ion Pac AS14A, 4 x 250 mm column (S/N 006972). 

After final weights were taken, the OTM 28 inorganic fractions were 

resuspended in 20mL of DI water for the sulfate analysis. 

Calibration The calibration curve is included in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

The first page of the curve contains all method specific parameters (i.e., 

curve type, origin, weight, etc.) used to quantify the samples. The 

calibration curve section also includes a table with the Retention Time 

(RetTime), Level (Lvl), Amount (corresponding units), Area, Response 

Factor (Amt/Area) and the analyte Name. The calibration table is used 

to identify (by retention time) and quantify each target compound. 

Chromatographic 

Conditions 

A copy of the acquisition method Anions.M is included in the 

Calibration Curve Chromatograms section of this report. 

QC Notes The analysis of the blank received with these samples contained sulfate 

at a concentration within the calibration range. 

The analysis of the laboratory reagent blank contained no sulfate at a 

concentration greater than the LOQ. 

The analysis of the LCS exhibited a recovery value of 101%. 

The analyses of the duplicate matrix spikes prepared using sample 

Run 1 Post exhibited recovery values of 104% and 103%. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 
General Reporting Notes 

The following are general reporting notes that are applicable to all Enthalpy Analytical, Inc. data 

reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot 

determine the presence of the analyte of interest reliably. 

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot 

quantitate the analyte of interest within the criteria of the method. 

 The acronym ND following a value indicates a non-detect or analytical result below the MDL. 

 The letter J following a value indicates an analytical result between the MDL and the LOQ. A J flag 

indicates that the laboratory can positively identify the analyte of interest as present, but the value 

should be considered an estimate. 

 The letter E following a value indicates an analytical result exceeding 100% of the highest calibration 

point. The associated value should be considered as an estimate. 

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the 

preparation and/or analysis process. The analytical result taken from a laboratory instrument is 

multiplied by the DF to determine the final undiluted sample results. 

 The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is 

spiked with a known amount of analyte so that a percent recovery value can be determined. This shows 

what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample 

matrix interferes with the analysis of the analyte(s). 

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same 

manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality 

by showing the consistency of results gained by performing the same steps multiple times. 

 The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an 

additional aliquot of sample for testing and the results of the duplicate analysis are compared to the 

initial result. The result should have a difference value of within 10% of the initial result (if the results 

of the original analysis are greater than the LOQ). 

 The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an 

additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps 

confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of 

interest, as they would have a different response/absorbance than the analyte of interest. 

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample 

matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and 

procedures used for the client samples. The LCS is used to assess the control of the laboratory’s 

analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. 

The extras (randomly chosen) are labeled with the associated project number and kept in-house at the 

appropriate temperature conditions. When the project samples are received for analysis, the LCSs are 

analyzed to confirm that the analyte could be recovered from the media, separate from the samples 

which were used on the project and which may have been affected by source matrix, sample collection 

and/or sample transport. 
General Reporting Notes 

(continued) 

 Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, 

the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a 

value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no 

confidence should be placed on more than two significant digits. 

 Manual Integration: The data systems used for processing will flag manually integrated peaks with 

an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified 

by the following two letter designations. The peak was not integrated by the software “NI”, the peak 

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software 

“WP”. These codes will accompany the analyst’s manual integration stamp placed next to the 

compound name. 
Sample Custody
-----------------------------

! 

:nttt. • .Jy Analytical, Inc Chain of Custody Record Reference Document No. 

2202 Ellis Road Project Number 100-208 

Durham, NC 27703 

Phone (919) 850-4392 

Fax (919) 850-9012 

Bill To: Civil Environmental Consultants Inc. 

Project Name: KCP&L ICR Testing - La Cygne Samples Shipment Date: Attn: Frank stevens 

Sample Team Members: FMS Lab DestInation: 4848 Park 370 Blvd 

Profit Center No.: st. Louis Lab Contact: Suite F ~~~---------------------- Project Manager Frank Stevens Project Contact: Hazelwood, MO 63042 

Purchase Order Number -1-00--2-0-8--0-00-4-------------------­ Project Phone: Report To: Civil Environmental Consultants Inc. 

Required Report Date: _________________________ Carrier/Waybill No.: Attn: Frank Stevens (fstevens@cecinc.com) 

Sample Number Sample Description/Type 

M26A-R1-C3--H2S04 Imps &. rinse 0.1 N H2SO4 Impingers & rim 

M26A-R2-C3--H2S04 Imps &. rinse 0.1 N H2SO4 Impingers & rim 

M26A-R3-C3--H2S04 Imps &. rinse 0.1 N H2SO4 Impingers & rim 

M26A-BT-C3--H2S04 Imps &. rinse 0.1 N H2SO4 Impingers & rim 

CTM033-R1-C5-- 10% Pb Acetate/l% Acetic Add 10% Pb Acetate/l % Acetic Ac 

CTM033-R2-C5-- 10% Pb Acetate/l% Acetic Acid 10% Pb Acetate/l% Acetic Ac 

CTM033-R3-C5-- 10% Pb Acetate/l% Acetic Acid 10% Pb Acetate/l % Acetic Ac 

CTM033-BT-(5-- 10% Pb Acetatetl % Acetic Acid 10% Pb Acetate/l% Acetic Ac 

CTM033-R1-C3A-- 1st 6N NaOH Imp &. rinse 6N NaOH Impinger & rinse 

CTM033-RI-C3B-- 2nd 6N NaOH Imp &. rinse 6N NaOH Impinger & rinse 

CTM033-RI-C3C-- 3rd 6N NaOH Imp &. rinse 6N NaOH Impinger & rinse 

CTM033-R2-C3A-- 1st 6N NaOH Imp &. rinse 6N NaOH Impingers & rinse 

CTM033-R2-C3B-- 2nd 6N NaOH Imp &. rinse 6N NaOH Impingers & rinse 

CTM033-R2-C3C-- 3rd 6N NaOH Imp &. rinse 6N NaOH Impingers & rinse 

CTM033-R3-C3A-- 1st 6N NaOH Imp & rinse 6N NaOH Impingers & rinse 

CTM033-R3-C3B-- 2nd 6N NaOH Imp &. rinse 6N NaOH Impingers & rinse 

CTM033-R3-C3C-- 3rd 6N NaOH Imp &. rimS! eN NaOH Impingers & rinse 

CTM033-BT-C3A-- 1st 6N NaOH Imp &. rinse 6N NaOH Impingers & rinse 

CTM033-BT-C3B-- 2nd 6N NaOH Imp &. rinse 6N NaOH Impingers & rinse 

CTM033-BT-C3C-- 3rd 6N NaOH Imp & rinse 6N NaOH Impingers & rinse 

Date Container 

Collected Type 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-1O glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-1O glass 

20-May-1O glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 ' glass 

20-May-1O glass 

20-May-l0 glass 

20-May-l0 glass 

20-May-l0 glass 

Special Instructions: t--\.ZG A ~J.\ ,""-­ ~c;.c;.s %"0 

Possible Hazard Identification: _ Non-Hazard _Aammable _Skin Irritant _POison _X_Unknown 

Requested Analysis 

USEPA Test Method 26A per ICR 

USEPA Test Method 26A per ICR 

USEPA Test Method 26A per ICR 

USEPA Test Method 26A per ICR 

USEPA CPM Test Method 033 per ICR rJ ="l 

USEPA CPM Test Method 033 per ICR 'J , ~ Lf 

USEPA CPM Test Method 033 per ICR .. "'''1 

USEPA CPM Test Method 033 per ICR • oJ ~ (' 

r 

USEPA CPM Test Method 033 per ICR Separately , " Co , ~ 

USEPA CPM Test Method 033 per ICR Separately lIP\\-': '" USEPA CPM Test Method 033 per ICR Separately .6...=

,.., 

USEPA CPM Test Method 033 per ICR Separately .., -'.". \ ~ 

USEPA CPM Test Method 033 per ICR Separately .p' ~:q,", 

USEPA CPM Test Method 033 per ICR Separately {II t;L 'I 

USEPA CPM Test Method 033 per ICR Separately b \0\ .... \"1 

USEPA CPM Test Method 033 per ICR Separately', !-Ie. ~ 

USEPA CPM Test Method 033 per ICR Separately Ii&.: ... I" 

USEPA CPM Test Method 033 per ICR Separately • ~. 9­ f" 

USEPA CPM Test Method 033 per ICR Separately I ~d """ I' 

USEPA CPM Test Method 033 per ICR Separately .1 .. Ie, -

TUrn Around Time Required: Normal QC Level: _X_Project SpeCific _Other 

Relinquished By: tJ.~ IItf,1.,ec,/<. Date: Yh 'l-kA .... By' Date: 5(7 \.£ //0 

/'J ;'l....-- '>< Time: Ilil'S'....., L 'j;z signed: JI/dJ ' - - 'U ~A :L Time: 

~elinqUiShed BY""~~ Date:S~1) 

~:rvo Date: F;/~\\J

bZft," J:; . 3\yoC--. signed: / T 11\~ Time: 1.1Vd Time: ,I~' lI.:t1nill f ", - . . 

· 

• 

• 

~ , 
En(" Ipy Analytical, Inc Chain of Custody Record Reference Document No. 

2202 Ellis Road 

Durham, NC 27703 

Phone (919) 850-4392 

Fax (919) 850-9012 

Project Name: KCP&L ICR Testing - La Cygne 

Sample Team Members: ..;..FM;..;.S~____________ 

Profit Center No.: St. louis 

Project Manager..;.F..;..ra;;.;n..;.;k..;..S;;.t;.;;e..;..ve;;.n..;.;s;;...... ~~~----------- ________ 

Purchase Order Number 100-208-0004 

Required Report Date: ~~~~----~------ standard turnaround 

Sample Number 

OTM27-RI-CI-PM2.5 Filter (Tared) 

OTM27-RI-C23- >PM2.5Ace Rinse 

OTM27-RI-C4-<PM2.5 Ace Rinse 

OTM28-RI-CI-CPM Imp Water rinse 

OTM28-Rl-c2-CPM Imp Ace/MeCl2 rinse 

OTM28-RI-C3-CPM Filter 

OTM27-R2-CI-PM2.5 Filter (Tared) 

OTM27-R2-C23- >PM2.5Ace Rinse 

OTM27-R2-C4-<PM2.5 Ace Rinse 

OTM28-R2-Cl-CPM Imp Water rinse 

OTM28-R2-C2-CPM Imp Ace/MeC12 rinse 

OTM28-R2-C3-CPM Filter 

OTM27-R3-CI-PM2.S Filter (Tared) 

OTM27-R3-C23- >PM2.5Ace Rinse 

OTM27-R3-C4-<PM2.5 Ace Rinse 

OTM28-R3-CI-CPM Imp Water rinse 

OTM28-R3-c2-CPM Imp Ace/Mea2 rinse 

OTM28-R3-C3-CPM Filter 

OTM27-BT-CI-PM2.5 Riter (Tared) 

OTM27-BT-C23- >PM2.5Ace Rinse 

OTM27-BT-C4-<PM2.5 Ace Rinse 

OTM28-BT-CI-CPM Imp Water rinse 

OTM28-BT-C2-CPM Imp Ace/Mea2 rinse 

OTM28BT-C3-CPM Filter 

Sample Description/Type 

filter 

Acetone rinsate 

Acetone rinsate 

DIUF water rinse 

Acetone/Methylene Chloride 

filter 

filter 

Acetone rinsate 

Acetone rinsate 

DIUF water rinse 

Acetone/Methylene Chloride 

filter 

filter 

Acetone rinsate 

Acetone rinsate 

DIUF water rinse 

Acetone/Methylene Chloride 

filter 

filter 

Acetone rinsate 

Acetone rinsate 

DIUF water rinse 

Acetone/Methylene Chloride 

filter 

Project Number 100-208 

Bill To: Civil Environmental Consultants Inc. 

Attn: Frank stevens 

4848 Park 370 Blvd 

Suite F 

Hazelwood, MO 63042 

Report To: Civil Environmental Consultants Inc. 

Attn: Frank Stevens (fstevens@cecinc.com) 

Requested Analysis 

USEPA other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 027 per ICR 

USEPA other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA other Test Method 028 per ICR, see special instructions 

USEPA Other Test Method 028 per ICR, see special instructions 

USEPA Other Test Method 028 per ICR, see special instructions 

USEPA other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA Other Test Method 027 per ICR 

USEPA other Test Method 028 per ICRt see special instructions 

USEPA other Test Method 028 per JCR, see special instructions 

USEPA other Test Method 028 per JCR, see special instructions 

Samples Shipment Date: 


Lab Destination: 


Lab Contact: 


Project Contact: 


Project Phone: 


Carrier/Waybill No.: 


Date Collected 

21-May-1O 

21-May-10 

21-May-10 

21-May-1O 

21-May-10 

21-May-1O 

21-May-1O 

21-May-1O 

21-May-1O 

21-May-1O 

21-May-l0 

21-May-1O 

22-May-10 

22-May-l0 

22-May-10 

22-May-10 

22-May-1O 

22-May-10 

21-May-10 

21-May-10 

21-May-1O 

21-May-1O 

21-May-1O 

21-May-l0 

Container 


Type 


petri dish 

glass 

glass 

glass 

glass 

glass 

petri dish 

glass 

glass 

glass 

glass 

glass 

petri dish 

glass 

glass 

glass 

glass 

glass 

petri dish 

glass 

glass 

glass 

glass 

glass 

Special Instructions: After analyzing the inorganic portion please reconstitute the residue and analyze it for Sulfate (502). 

Possible Hazard Identification: _ Non-Hazard _Flammable _Skin Irritant _Poison _X_Unknown 

Turn Around Time Required: Nonnal QC Level: _X_Project SpeCific _Other 

Relinquished By: t:rI~ Iht-/Iv'~p;c.. Date: .~h "h", R~: Date: S IZ c;,/ /1)

signed: Q. Time: II/;;a..... Time: (II/fa --~ '" "?7r 'U ~elinqUiShed "By: ~ Y Date: ib/fO Date: 5 f7J5I\tJ I............, 


signed: I 77V7I EA Time: 15YJ I~t«r-e> Time: ~1~

L? rt . ft_.__ 4 -a#i" " 1 

~ 
Sample 

Chromatograms
=====================================================================

Acq. Operator : EO Seq. Line : 17

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 11:57:04 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1701.D) 3.033 - Fluoride 3.742 4.074 - Chloride 6.495

 8.359

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.033 BV 16.19024 1.40469e-2 2.27423e-1 Fluoride 

 4.074 VB 8.00630 2.59004e-2 2.07366e-1 Chloride 

Totals : 4.34789e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1701.D

Sample Name: Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:31 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 17

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 12:07:52 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1702.D) 3.032 - Fluoride 3.739 4.071 - Chloride 6.493

 8.361

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.032 BV 14.89996 1.40469e-2 2.09298e-1 Fluoride 

 4.071 VB 8.01220 2.59004e-2 2.07520e-1 Chloride 

Totals : 4.16818e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\015-1702.D

Sample Name: Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:38 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 22

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 1:45:03 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2201.D) 3.035 - Fluoride 3.748 4.083 - Chloride 6.547

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.035 BV 15.12566 1.40469e-2 2.12469e-1 Fluoride 

 4.083 VB 10.32935 2.59004e-2 2.67535e-1 Chloride 

Totals : 4.80003e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2201.D

Sample Name: Run 2 *20 0410-11

Instrument 1 6/10/2010 12:21:16 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 22

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 1:55:51 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2202.D) 3.036 - Fluoride 3.752 4.089 - Chloride 5.805 6.566

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.036 BV 14.97443 1.40469e-2 2.10344e-1 Fluoride 

 4.089 VB 10.30313 2.59004e-2 2.66856e-1 Chloride 

Totals : 4.77200e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\018-2202.D

Sample Name: Run 2 *20 0410-11

Instrument 1 6/10/2010 12:21:24 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 23

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 2:06:39 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2301.D) 3.038 - Fluoride 3.751 4.090 - Chloride 5.828 6.579

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.038 BV 20.90090 1.40469e-2 2.93593e-1 Fluoride 

 4.090 VB 7.77663 2.59004e-2 2.01418e-1 Chloride 

Totals : 4.95011e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2301.D

Sample Name: Run 3 *20 0410-11

Instrument 1 6/10/2010 12:21:32 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 23

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 2:17:26 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2302.D) 3.036 - Fluoride 3.749 4.090 - Chloride 5.835 6.589

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.036 BV 19.03973 1.40469e-2 2.67449e-1 Fluoride 

 4.090 VB 7.77752 2.59004e-2 2.01441e-1 Chloride 

Totals : 4.68890e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\019-2302.D

Sample Name: Run 3 *20 0410-11

Instrument 1 6/10/2010 12:21:39 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 24

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 2:28:14 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2401.D)

 8.387

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 - - - Fluoride 

 4.109 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2401.D

Sample Name: H2SO4 Blank *20 0410-11

Instrument 1 6/10/2010 12:21:48 PM ARM Page 1 of 2
=====================================================================

Acq. Operator : EO Seq. Line : 24

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 2:39:03 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2402.D)

 8.387

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 - - - Fluoride 

 4.109 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\020-2402.D

Sample Name: H2SO4 Blank *20 0410-11

Instrument 1 6/10/2010 12:22:07 PM ARM Page 1 of 2
=====================================================================

Acq. Operator : EO Seq. Line : 9

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 9:04:19 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0901.D) 5.127

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 - - - Fluoride 

 4.109 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0901.D

Sample Name: 0.01N H2SO4/NaOH MB

Instrument 1 6/10/2010 12:20:11 PM ARM Page 1 of 2
=====================================================================

Acq. Operator : EO Seq. Line : 9

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 9:15:07 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0902.D) 5.121

 8.347

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 - - - Fluoride 

 4.109 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\007-0902.D

Sample Name: 0.01N H2SO4/NaOH MB

Instrument 1 6/10/2010 12:20:19 PM ARM Page 1 of 2
=====================================================================

Acq. Operator : EO Seq. Line : 20

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 1:01:52 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2001.D) 3.041 - Fluoride 3.740 4.071 - Chloride 5.740 6.457 7.148

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.041 BV 236.98174 1.46550e-2 3.47296 Fluoride 

 4.071 VB 134.46176 2.41210e-2 3.24335 Chloride 

Totals : 6.71631

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2001.D

Sample Name: MS Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:46 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 20

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 1:12:40 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2002.D) 3.042 - Fluoride 3.739 4.071 - Chloride 5.741 6.458 7.134

 8.361

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.042 BV 237.87801 1.46559e-2 3.48633 Fluoride 

 4.071 VB 134.18892 2.41224e-2 3.23696 Chloride 

Totals : 6.72329

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\016-2002.D

Sample Name: MS Run 1 *20 0410-11

Instrument 1 6/10/2010 12:20:54 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 21

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 1:23:27 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2101.D) 3.041 - Fluoride 3.743 4.075 - Chloride 5.752 6.473 7.140

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.041 BV 233.78281 1.46514e-2 3.42524 Fluoride 

 4.075 VB 133.38010 2.41268e-2 3.21803 Chloride 

Totals : 6.64328

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2101.D

Sample Name: MSD Run 1 *20 0410-11

Instrument 1 6/10/2010 12:21:01 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 21

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 1:34:15 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2102.D) 3.041 - Fluoride 3.743 4.077 - Chloride 5.761 6.487 7.144

 8.360

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.041 BV 236.21182 1.46541e-2 3.46148 Fluoride 

 4.077 VB 133.70741 2.41250e-2 3.22569 Chloride 

Totals : 6.68717

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\017-2102.D

Sample Name: MSD Run 1 *20 0410-11

Instrument 1 6/10/2010 12:21:08 PM ARM Page 1 of 1
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC1 B, Metrohm

Signal 2: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 3.069 2 2 9.99000e-1 69.97066 1.42774e-2 Fluoride 

 3 4.97500 333.44276 1.49201e-2 

 4 8.92000 638.93991 1.39606e-2 

 5 14.80000 965.00597 1.53367e-2 

 4.109 2 2 9.99000e-1 38.71060 2.58069e-2 Chloride 

 3 4.97500 208.16149 2.38997e-2 

 4 8.92000 374.92666 2.37913e-2 

 5 14.80000 630.44516 2.34755e-2 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Instrument 1 6/10/2010 12:17:02 PM ARM Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

200

400

600

800

2

3

4

5

Fluoride at exp. RT: 3.069

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99863

Residual Std. Dev.: 34.32213

Formula: y = mx + b

 m: 67.04350

 b: 4.14244

 x: Amount

 y: Area

Calibration Level Weights:

 Level 2 : 1

 Level 3 : 0.200804

 Level 4 : 0.111996

 Level 5 : 0.0675

Amount[ug/mL]

0 10

Area

0

100

200

300

400

500

600

2

3

4

5

Chloride at exp. RT: 4.109

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99999

Residual Std. Dev.: 2.15919

Formula: y = mx + b

 m: 42.72553

 b: -4.11202

 x: Amount

 y: Area

Calibration Level Weights:

 Level 2 : 1

 Level 3 : 0.200804

 Level 4 : 0.111996

 Level 5 : 0.0675

=====================================================================

Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Instrument 1 6/10/2010 12:17:02 PM ARM Page 2 of 2
=====================================================================

Acq. Operator : EO Seq. Line : 4

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 7:16:21 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0401.D) 3.032 - Fluoride 3.420 4.077 - Chloride 5.755 6.504 7.119

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.032 BV 71.89967 1.40563e-2 1.01065 Fluoride 

 4.077 VB 38.96849 2.58750e-2 1.00831 Chloride 

Totals : 2.01895

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0401.D

Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:25 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 4

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 7:27:09 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0402.D) 3.033 - Fluoride 3.421 4.077 - Chloride 5.120 5.753 6.501 7.127

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.033 BV 70.08958 1.40469e-2 9.84541e-1 Fluoride 

 4.077 VB 38.81830 2.58845e-2 1.00479 Chloride 

Totals : 1.98933

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-0402.D

Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:33 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 27

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 3:33:02 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2701.D) 3.035 - Fluoride 3.430 4.106 - Chloride 5.189 5.851 6.634 7.110

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.035 BV 68.36214 1.40469e-2 9.60276e-1 Fluoride 

 4.106 VB 38.40773 2.59004e-2 9.94777e-1 Chloride 

Totals : 1.95505

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2701.D

Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:40 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 27

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 3:43:50 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2702.D) 3.036 - Fluoride 3.430 4.109 - Chloride 5.192 5.858 6.642 7.115

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.036 BV 69.53124 1.40469e-2 9.76698e-1 Fluoride 

 4.109 VB 38.64785 2.58955e-2 1.00080 Chloride 

Totals : 1.97750

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\002-2702.D

Sample Name: HPLC51pg110 #2

Instrument 1 6/10/2010 12:17:47 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 5

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 7:37:56 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0501.D) 3.044 - Fluoride 3.426 4.075 - Chloride 5.733 6.465 7.127

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.044 BV 333.96948 1.47307e-2 4.91960 Fluoride 

 4.075 VB 207.89630 2.38681e-2 4.96210 Chloride 

Totals : 9.88170

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0501.D

Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:17:55 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 5

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 7:48:45 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0502.D) 3.045 - Fluoride 3.424 4.072 - Chloride 5.728 6.459 7.115

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.045 BV 334.69070 1.47311e-2 4.93036 Fluoride 

 4.072 VB 207.95876 2.38680e-2 4.96356 Chloride 

Totals : 9.89392

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-0502.D

Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:18:23 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 28

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 3:54:37 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2801.D) 3.049 - Fluoride 3.433 4.105 - Chloride 5.192 5.839 6.609 7.103

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.049 BV 333.72778 1.47305e-2 4.91599 Fluoride 

 4.105 VB 208.42900 2.38670e-2 4.97457 Chloride 

Totals : 9.89056

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2801.D

Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:18:31 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 28

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 4:05:24 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2802.D) 3.047 - Fluoride 3.436 4.108 - Chloride 5.202 5.846 6.617 7.107

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.047 BV 331.38309 1.47292e-2 4.88102 Fluoride 

 4.108 VB 208.36191 2.38671e-2 4.97300 Chloride 

Totals : 9.85402

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\003-2802.D

Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:18:39 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 6

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 7:59:33 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0601.D) 2.724 3.056 - Fluoride 4.073 - Chloride 5.718 6.442 7.121

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.056 VV 622.95276 1.48165e-2 9.22998 Fluoride 

 4.073 VB 373.70355 2.36627e-2 8.84285 Chloride 

Totals : 18.07284

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0601.D

Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:18:49 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 6

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 8:10:20 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0602.D) 2.727 3.057 - Fluoride 4.074 - Chloride 5.719 6.443 7.127

 8.346

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.057 VV 624.18518 1.48167e-2 9.24837 Fluoride 

 4.074 VB 372.97574 2.36632e-2 8.82582 Chloride 

Totals : 18.07418

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-0602.D

Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:18:57 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 29

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 4:16:13 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2901.D) 3.059 - Fluoride 4.108 - Chloride 5.164 5.838 6.602 7.106

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.059 BV 651.93127 1.48209e-2 9.66222 Fluoride 

 4.108 VB 376.42206 2.36609e-2 8.90648 Chloride 

Totals : 18.56870

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2901.D

Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:19:10 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 29

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 4:27:00 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2902.D) 3.060 - Fluoride 4.107 - Chloride 5.171 5.841 6.606 7.098

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.060 BV 656.69043 1.48216e-2 9.73320 Fluoride 

 4.107 VB 376.60529 2.36608e-2 8.91077 Chloride 

Totals : 18.64397

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\004-2902.D

Sample Name: HPLC51pg110 #4

Instrument 1 6/10/2010 12:19:17 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 7

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 8:21:08 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0701.D) 3.069 - Fluoride 4.071 - Chloride 5.709 6.421 7.116

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 BV 971.08032 1.48521e-2 14.42255 Fluoride 

 4.071 VB 629.51410 2.35581e-2 14.83015 Chloride 

Totals : 29.25270

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0701.D

Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:25 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 7

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 8:31:56 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0702.D) 3.068 - Fluoride 4.073 - Chloride 5.108 5.708 6.419 7.123

 8.347

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.068 BV 959.86444 1.48513e-2 14.25525 Fluoride 

 4.073 VB 630.14801 2.35579e-2 14.84499 Chloride 

Totals : 29.10024

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-0702.D

Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:33 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 30

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 4:37:48 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3001.D) 3.069 - Fluoride 4.111 - Chloride 5.193 5.841 6.596 7.101

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 BV 962.06219 1.48515e-2 14.28803 Fluoride 

 4.111 VB 630.74725 2.35578e-2 14.85901 Chloride 

Totals : 29.14705

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3001.D

Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:40 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 30

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 4:48:36 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3002.D) 3.069 - Fluoride 4.112 - Chloride 5.195 5.845 6.601 7.103

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.069 BV 967.01691 1.48518e-2 14.36194 Fluoride 

 4.112 VB 631.37128 2.35576e-2 14.87362 Chloride 

Totals : 29.23556

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\005-3002.D

Sample Name: HPLC51pg110 #5

Instrument 1 6/10/2010 12:19:47 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 8

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 8:42:44 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0801.D) 3.042 - Fluoride 4.072 - Chloride 5.111

 8.333

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.042 BV 290.32208 1.47029e-2 4.26857 Fluoride 

 4.072 VB 165.00069 2.39885e-2 3.95812 Chloride 

Totals : 8.22668

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0801.D

Sample Name: HPLC51pg110 #LCS

Instrument 1 6/10/2010 12:19:55 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 8

Acq. Instrument : Smithers Location : -

Injection Date : 6/9/2010 8:53:31 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0802.D) 3.042 - Fluoride 4.070 - Chloride 5.111

 8.334

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.042 BV 292.95966 1.47048e-2 4.30791 Fluoride 

 4.070 VB 165.32860 2.39873e-2 3.96579 Chloride 

Totals : 8.27370

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\006-0802.D

Sample Name: HPLC51pg110 #LCS

Instrument 1 6/10/2010 12:20:03 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 18

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 12:18:40 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1801.D) 3.046 - Fluoride 4.070 - Chloride 5.105 5.708 6.432 7.131

 8.347

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.046 BV 353.35434 1.47408e-2 5.20874 Fluoride 

 4.070 VB 205.12195 2.38744e-2 4.89716 Chloride 

Totals : 10.10590

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1801.D

Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:23:17 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : EO Seq. Line : 18

Acq. Instrument : Smithers Location : -

Injection Date : 6/10/2010 12:29:28 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG128.M

Last changed : 6/10/2010 12:16:41 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1802.D) 3.047 - Fluoride 4.071 - Chloride 5.100 5.711 6.435 7.135

 8.347

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, June 10, 2010 12:16:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 3.047 BV 354.06757 1.47412e-2 5.21937 Fluoride 

 4.071 VB 204.97243 2.38747e-2 4.89367 Chloride 

Totals : 10.11304

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\MAY\HPLC51PG126\100-1802.D

Sample Name: HPLC51pg110 #3

Instrument 1 6/10/2010 12:23:26 PM ARM Page 1 of 1
 Method Information

 Method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

 Modified: 2/23/2010 at 8:12:27 AM

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 CHANNEL A

Source: Signal

Unit: μS/cm

Units/Volt: 100.000

Peakwidth (Data Rate): 0.027 Min (10.00 Hz)

Stop Time: No Limit

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Modified on: 2/23/2010 at 8:12:27 AM

Smithers 3/16/2010 1:54:21 PM KHB/EO Page 1 of 1
Sequence Table:

 Method and Injection Info Part:

 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 1 Vial 127 DI Rinse METROHM 4 Sample 

 

 2 Vial 126 DI Rinse METROHM 4 Sample 

 3 Vial 1 HPLC51pg110 #1 METROHM 2 Sample 

 4 Vial 2 HPLC51pg110 #2 METROHM 2 Sample 

 5 Vial 3 HPLC51pg110 #3 METROHM 2 Sample 

 6 Vial 4 HPLC51pg110 #4 METROHM 2 Sample 

 7 Vial 5 HPLC51pg110 #5 METROHM 2 Sample 

 8 Vial 6 HPLC51pg110 #LCS METROHM 2 Sample 

 9 Vial 7 0.01N H2SO4/NaOH MB METROHM 2 Sample 

 10 Vial 8 Run 1 *20 0610-18 METROHM 2 Sample 

 11 Vial 9 MS Run 1 *20 0610-18 METROHM 2 Sample 

 12 Vial 10 MSD Run 1 *20 0610-18 METROHM 2 Sample 

 13 Vial 11 Run 2 *20 0610-18 METROHM 2 Sample 

 14 Vial 12 Run 3 *20 0610-18 METROHM 2 Sample 

 15 Vial 13 DI H2O Blank 0610-18 METROHM 2 Sample 

 16 Vial 14 H2SO4 Blank *20 0610-18 METROHM 2 Sample 

 17 Vial 15 Run 1 *20 0410-11 METROHM 2 Sample 

 18 Vial 100 HPLC51pg110 #3 METROHM 2 Sample 

 19 Vial 101 HPLC51pg110 #4 METROHM 2 Sample 

 20 Vial 16 MS Run 1 *20 0410-11 METROHM 2 Sample 

 21 Vial 17 MSD Run 1 *20 0410-11 METROHM 2 Sample 

 22 Vial 18 Run 2 *20 0410-11 METROHM 2 Sample 

 23 Vial 19 Run 3 *20 0410-11 METROHM 2 Sample 

 24 Vial 20 H2SO4 Blank *20 0410-11 METROHM 2 Sample 

 25 Vial 21 DI H2O blank 0610-18 METROHM 2 Sample 

 26 Vial 1 HPLC51pg110 #1 METROHM 2 Sample 

 27 Vial 2 HPLC51pg110 #2 METROHM 2 Sample 

Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG128.S

Instrument 1 6/10/2010 12:24:32 PM ARM Page 1 of 2
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 28 Vial 3 HPLC51pg110 #3 METROHM 2 Sample 

 

 29 Vial 4 HPLC51pg110 #4 METROHM 2 Sample 

 30 Vial 5 HPLC51pg110 #5 METROHM 2 Sample 

 31 Vial 110 HPLC51pg110 #LCS METROHM 2 Sample 

 32 Vial 111 0.01N H2SO4/NaOH MB METROHM 2 Sample 

 33 Vial 112 L2710*5 0510-103 METROHM 2 Sample 

 34 Vial 113 L2710*5 0510-103 METROHM 2 Sample 

 35 Vial 114 L2710*1000 0510-103 METROHM 2 Sample 

 36 Vial 115 hplc51pg126 SS*5 0510-103 METROHM 2 Sample 

 37 Vial 116 HPLC51pg110 #1 METROHM 2 Sample 

 38 Vial 117 HPLC51pg110 #2 METROHM 2 Sample 

 39 Vial 118 HPLC51pg110 #3 METROHM 2 Sample 

 40 Vial 119 HPLC51pg110 #4 METROHM 2 Sample 

 41 Vial 120 HPLC51pg110 #5 METROHM 2 Sample 

Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG128.S

Instrument 1 6/10/2010 12:24:32 PM ARM Page 2 of 2
Sample 

Chromatograms
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\010-1101.D) 1.658 2.057 2.611

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\010-1101.D

Sample Name: CTM033-R1-C3A-C *5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 11

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 5:49:47 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:27:49 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\011-1201.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\011-1201.D

Sample Name: CTM033-R1-C5*5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 12

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 6:05:04 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:28:18 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\012-1301.D) 1.653 2.060 2.615

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\012-1301.D

Sample Name: CTM033-R2-C3A-C *5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 13

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 6:20:20 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:28:46 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\013-1401.D) 1.638 1.689

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\013-1401.D

Sample Name: CTM033-R2-C5*5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 14

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 6:35:38 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:29:12 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\014-1501.D) 1.655 2.054 2.614

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\014-1501.D

Sample Name: CTM033-R3-C3A-C *5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 15

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 6:50:55 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:29:46 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\015-1601.D) 1.634 1.685 2.653

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\015-1601.D

Sample Name: CTM033-R3-C5*5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 16

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 7:06:11 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:30:08 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\016-1701.D) 1.629 1.847

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\016-1701.D

Sample Name: CTM033-BT-C3A-C *5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 17

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 7:21:27 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:30:29 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\017-1801.D) 1.604 1.739

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\017-1801.D

Sample Name: CTM033-BT-C5*5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 18

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 7:36:44 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:30:56 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\007-0801.D) 1.736 2.148

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\007-0801.D

Sample Name: 0.1N NaOH - RB

 =====================================================================

 Acq. Operator : ARM Seq. Line : 8

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 4:33:25 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:24:46 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\007-0802.D)

0.039

 1.737

 2.150

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\007-0802.D

Sample Name: 0.1N NaOH - RB

 =====================================================================

 Acq. Operator : ARM Seq. Line : 8

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 4:48:40 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:25:39 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\008-0901.D) 1.675 1.776

 7.984 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.984 BB 1699.42212 6.58766e-4 1.11952 Hydrogen Cyanide 

Totals : 1.11952

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\008-0901.D

Sample Name: Hplc50pg128 #LCS

 =====================================================================

 Acq. Operator : ARM Seq. Line : 9

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 5:03:57 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:26:17 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\008-0902.D) 1.677 1.777

 7.985 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.985 BB 1718.88452 6.58883e-4 1.13254 Hydrogen Cyanide 

Totals : 1.13254

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\008-0902.D

Sample Name: Hplc50pg128 #LCS

 =====================================================================

 Acq. Operator : ARM Seq. Line : 9

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 5:19:14 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:26:40 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\018-1901.D) 1.660 2.064 2.615

 8.000 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.000 BB 1721.80261 6.58901e-4 1.13450 Hydrogen Cyanide 

Totals : 1.13450

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\018-1901.D

Sample Name: MS/CTM033-R1-C3A-C 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 19

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 7:52:01 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:31:35 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\019-2201.D) 1.665 2.064 2.617

 8.021 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.021 BB 1763.61536 6.59144e-4 1.16248 Hydrogen Cyanide 

Totals : 1.16248

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\019-2201.D

Sample Name: MSD/CTM033-R1-C3A-C 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 22

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 9:08:24 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:33:01 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\020-2301.D) 1.665 2.065 2.617

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\020-2301.D

Sample Name: LD/CTM033-R1-C3A-C *5 0410-11

 =====================================================================

 Acq. Operator : ARM Seq. Line : 23

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 9:23:41 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:33:17 PM ARM Page 1 of 2
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.300 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.300 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 7.964 1 1 1.03500e-1 178.57640 5.79584e-4 Hydrogen Cyanide 

 2 5.07300e-1 774.35867 6.55123e-4 

 3 9.90500e-1 1564.24603 6.33212e-4 

 4 1.54100 2374.78821 6.48900e-4 

 5 2.08000 3044.28503 6.83247e-4 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

Instrument 1 6/28/2010 5:02:12 PM AMP Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 1 2

Area

0

500

1000

1500

2000

2500

3000

1

2

3

4

5

Hydrogen Cyanide at exp. RT: 7.964

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99942

Residual Std. Dev.: 67.54778

Formula: y = mx + b

 m: 1494.40013

 b: 26.40971

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.204021

 Level 3 : 0.104493

 Level 4 : 0.067164

 Level 5 : 0.04976

=====================================================================

Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

Instrument 1 6/28/2010 5:02:12 PM AMP Page 2 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\001-0201.D)

0.045

 1.405

 1.673 1.769

 8.044 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.044 BB 177.71291 5.71570e-4 1.01575e-1 Hydrogen Cyanide 

Totals : 1.01575e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\001-0201.D

Sample Name: hplc50pg118 #1

 =====================================================================

 Acq. Operator : ARM Seq. Line : 2

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 1:30:07 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:20:54 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\001-0202.D) 1.673 1.768

 8.029 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.029 BB 179.43990 5.71570e-4 1.02562e-1 Hydrogen Cyanide 

Totals : 1.02562e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\001-0202.D

Sample Name: hplc50pg118 #1

 =====================================================================

 Acq. Operator : ARM Seq. Line : 2

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 1:45:22 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:21:11 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\002-0301.D) 1.672 1.770

 8.018 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.018 BB 769.52649 6.46199e-4 4.97268e-1 Hydrogen Cyanide 

Totals : 4.97268e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\002-0301.D

Sample Name: hplc50pg118 #2

 =====================================================================

 Acq. Operator : ARM Seq. Line : 3

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 2:00:39 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:21:23 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\002-0302.D) 0.110 0.201 0.301 0.400 1.665 1.764

 7.997 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.997 BB 779.19086 6.46484e-4 5.03735e-1 Hydrogen Cyanide 

Totals : 5.03735e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\002-0302.D

Sample Name: hplc50pg118 #2

 =====================================================================

 Acq. Operator : ARM Seq. Line : 3

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 2:15:55 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:21:35 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\003-0401.D) 1.672 1.770

 8.000 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.000 BB 1555.64319 6.57805e-4 1.02331 Hydrogen Cyanide 

Totals : 1.02331

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\003-0401.D

Sample Name: hplc50pg118 #3

 =====================================================================

 Acq. Operator : ARM Seq. Line : 4

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 2:31:13 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:21:50 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\003-0402.D) 1.673 1.769

 7.998 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.998 BB 1572.84888 6.57929e-4 1.03482 Hydrogen Cyanide 

Totals : 1.03482

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\003-0402.D

Sample Name: hplc50pg118 #3

 =====================================================================

 Acq. Operator : ARM Seq. Line : 4

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 2:46:29 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:22:03 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-0501.D) 1.672 1.772

 7.988 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.988 BB 2363.89722 6.61689e-4 1.56416 Hydrogen Cyanide 

Totals : 1.56416

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-0501.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 5

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 3:01:45 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:22:25 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-0502.D) 1.672 1.772

 7.984 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.984 BB 2385.67920 6.61757e-4 1.57874 Hydrogen Cyanide 

Totals : 1.57874

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-0502.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 5

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 3:17:01 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:22:38 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\005-0601.D) 1.672 1.770

 7.982 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.982 BB 3033.08081 6.63338e-4 2.01196 Hydrogen Cyanide 

Totals : 2.01196

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\005-0601.D

Sample Name: hplc50pg118 #5

 =====================================================================

 Acq. Operator : ARM Seq. Line : 6

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 3:32:18 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:22:50 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\005-0602.D) 0.121 0.220 0.320 1.666 1.766

 7.959 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.959 BB 3055.48926 6.63381e-4 2.02695 Hydrogen Cyanide 

Totals : 2.02695

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\005-0602.D

Sample Name: hplc50pg118 #5

 =====================================================================

 Acq. Operator : ARM Seq. Line : 6

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 3:47:35 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:23:14 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-2101.D) 1.676 1.781

 8.022 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.022 BB 2610.82080 6.62396e-4 1.72940 Hydrogen Cyanide 

Totals : 1.72940

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-2101.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 21

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 8:37:51 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:32:30 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-2102.D) 1.677 1.782

 8.026 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.026 BB 2628.14233 6.62441e-4 1.74099 Hydrogen Cyanide 

Totals : 1.74099

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-2102.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 21

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 8:53:07 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:32:45 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-3301.D) 1.677 1.782

 8.081 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.081 BB 2710.03052 6.62644e-4 1.79578 Hydrogen Cyanide 

Totals : 1.79578

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-3301.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 33

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/26/2010 12:11:46 AM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:36:22 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-3302.D) 1.675 1.783

 8.078 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.078 BB 2694.15186 6.62605e-4 1.78516 Hydrogen Cyanide 

Totals : 1.78516

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-3302.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 33

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/26/2010 12:27:01 AM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:36:31 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-4601.D) 1.672 1.775 2.182

 8.127 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.127 BB 2815.30225 6.62888e-4 1.86623 Hydrogen Cyanide 

Totals : 1.86623

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-4601.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 46

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/26/2010 4:16:18 AM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:39:15 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-4602.D) 1.677 1.781

 8.135 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.135 BB 2791.87720 6.62835e-4 1.85055 Hydrogen Cyanide 

Totals : 1.85055

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-4602.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 46

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/26/2010 4:31:35 AM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:39:24 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-5001.D) 1.678 1.782

 8.161 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.161 BB 2812.00586 6.62880e-4 1.86402 Hydrogen Cyanide 

Totals : 1.86402

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-5001.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 50

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/26/2010 5:48:03 AM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:40:16 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\004-5002.D) 1.679 1.781

 8.164 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.164 BB 2824.65356 6.62908e-4 1.87249 Hydrogen Cyanide 

Totals : 1.87249

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\004-5002.D

Sample Name: hplc50pg118 #4

 =====================================================================

 Acq. Operator : ARM Seq. Line : 50

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/26/2010 6:03:20 AM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:40:25 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\006-0701.D)

0.065

 0.267

 1.667 1.767

 7.964 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.964 BB 1546.54419 6.57738e-4 1.01722 Hydrogen Cyanide Tag Value= 1.019 μg/mL 

Totals : 1.01722

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\006-0701.D

Sample Name: hplc50pg92 #SS

 =====================================================================

 Acq. Operator : ARM Seq. Line : 7

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 4:02:52 PM Inj : 1

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:23:40 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (HPLC50PG130\006-0702.D) 1.673 1.771

 7.972 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Monday, June 28, 2010 9:08:17 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.972 BB 1549.44458 6.57759e-4 1.01916 Hydrogen Cyanide Tag Value= 1.019 μg/mL 

Totals : 1.01916

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\JUN\HPLC50PG130\006-0702.D

Sample Name: hplc50pg92 #SS

 =====================================================================

 Acq. Operator : ARM Seq. Line : 7

 Acq. Instrument : Grandmama Location : -

 Injection Date : 6/25/2010 4:18:07 PM Inj : 2

 Sequence File : H:\HPLC2010Q2\GRANDMAM\SEQUENCE\HPLC50PG130.S

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/27/2010 11:58:08 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG130.M

 Last changed : 6/28/2010 9:08:27 AM by ARM

 =====================================================================

Instrument 1 6/28/2010 2:24:16 PM ARM Page 1 of 1
 Method Information

 Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Modified: 3/17/2010 at 9:48:43 AM

 Column: Dionex Ionpac AS7 4 X 250mm

 Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine

 Flow rate: 1.0 mL/min

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 CHANNEL A

Source: Signal

Unit: nC

Units/Volt: 1000.000

Peakwidth (Data Rate): 0.133 Min (2.00 Hz)

Stop Time: 14.01 Min

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1
Sequence: C:\HPCHEM\1\SEQUENCE\hplc50pg130.txt

Line Vial Sample Name Method Inj

1 Vial 7 0.1N NaOH - RB 1000 2

2 Vial 1 hplc50pg118 #1 1000 2

3 Vial 2 hplc50pg118 #2 1000 2

4 Vial 3 hplc50pg118 #3 1000 2

5 Vial 4 hplc50pg118 #4 1000 2

6 Vial 5 hplc50pg118 #5 1000 2

7 Vial 6 hplc50pg92 #SS 1000 2

8 Vial 7 0.1N NaOH - RB 1000 2

9 Vial 8 Hplc50pg128 #LCS 1000 2

10 Vial 9 MSD/Run 1 0610-38 1000 1

11 Vial 10 CTM033-R1-C3A-C *5 0410-11 1000 1

12 Vial 11 CTM033-R1-C5*5 0410-11 1000 1

13 Vial 12 CTM033-R2-C3A-C *5 0410-11 1000 1

14 Vial 13 CTM033-R2-C5*5 0410-11 1000 1

15 Vial 14 CTM033-R3-C3A-C *5 0410-11 1000 1

16 Vial 15 CTM033-R3-C5*5 0410-11 1000 1

17 Vial 16 CTM033-BT-C3A-C *5 0410-11 1000 1

18 Vial 17 CTM033-BT-C5*5 0410-11 1000 1

19 Vial 18 MS/CTM033-R1-C3A-C 0410-11 1000 1

20 Vial 3 hplc50pg118 #3 1000 2

21 Vial 4 hplc50pg118 #4 1000 2

22 Vial 19 MSD/CTM033-R1-C3A-C 0410-11 1000 1

23 Vial 20 LD/CTM033-R1-C3A-C *5 0410-11 1000 1

24 Vial 21 ICR1-CTM33-C3-PbAc*5 0410-49 1000 1

25 Vial 22 ICR1-CTM33-C4-NaOH*5 0410-49 1000 1

26 Vial 23 ICR2-CTM33-C3-PbAc*5 0410-49 1000 1

27 Vial 24 ICR2-CTM33-C4-NaOH*5 0410-49 1000 1

28 Vial 25 ICR3-CTM33-C3-PbAc*5 0410-49 1000 1

29 Vial 26 ICR3-CTM33-C4-NaOH*5 0410-49 1000 1

30 Vial 27 ICFB-CTM33-C3-PbAc*5 0410-49 1000 1

31 Vial 28 ICFB-CTM33-C4-NaOH*5 0410-49 1000 1

32 Vial 3 hplc50pg118 #3 1000 2

33 Vial 4 hplc50pg118 #4 1000 2

34 Vial 8 Hplc50pg128 #LCS 1000 2

35 Vial 29 ICRRB-CTM33-PbAc Soln*5 0410-49 1000 1

36 Vial 30 ICRRB-CTM33-NaOH Soln*5 0410-49 1000 1

37 Vial 31 ICRFS-CTM33-Field Spike*5 0410-49 1000 1

38 Vial 32 MS/ICR1-CTM33-C3-PbAc 0410-49 1000 1

39 Vial 33 MSD/ICR1-CTM33-C3-PbAc 0410-49 1000 1

40 Vial 34 LD/ICR1-CTM33-C3-PbAc*5 0410-49 1000 1

41 Vial 35 Cope-HCl-Run 1*5 0610-71 1000 1

42 Vial 36 Cope-HCl-Run 2*5 0610-71 1000 1

43 Vial 37 Cope-HCl-Run 3*5 0610-71 1000 1

44 Vial 38 MS/Cope-HCl-Run 1 0610-71 1000 1

45 Vial 3 hplc50pg118 #3 1000 2

46 Vial 4 hplc50pg118 #4 1000 2

47 Vial 39 MSD/Cope-HCl-Run 1*5 0610-71 1000 1

48 Vial 40 LD/Cope-HCl-Run 1*5 0610-71 1000 1

49 Vial 3 hplc50pg118 #3 1000 2

50 Vial 4 hplc50pg118 #4 1000 2
Sample 

Chromatograms
=====================================================================

Acq. Operator : ARM Seq. Line : 15

Acq. Instrument : Gonzo Location : Vial 21

Injection Date : 6/8/2010 11:10:36 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\021-1501.D)

 10.082 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.082 BB 345.87695 1.78970e-2 6.19016 Sulfate 

Totals : 6.19016

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\021-1501.D

Sample Name: Run 1 Post *20 0410-11

Instrument 1 6/9/2010 9:02:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 15

Acq. Instrument : Gonzo Location : Vial 21

Injection Date : 6/8/2010 11:27:18 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\021-1502.D)

 10.079 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.079 VB 346.15082 1.78971e-2 6.19508 Sulfate 

Totals : 6.19508

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\021-1502.D

Sample Name: Run 1 Post *20 0410-11

Instrument 1 6/9/2010 9:02:43 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 18

Acq. Instrument : Gonzo Location : Vial 24

Injection Date : 6/9/2010 12:50:48 AM Inj : 1

 Inj Volume : 25 μl

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\024-1801.D)

 Area: 429.949 10.075 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.075 MM 429.94937 1.79077e-2 7.69942 Sulfate 

Totals : 7.69942

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\024-1801.D

Sample Name: Run 2 Post *20 0410-11

Instrument 1 6/9/2010 9:12:54 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 18

Acq. Instrument : Gonzo Location : Vial 24

Injection Date : 6/9/2010 1:07:29 AM Inj : 2

 Inj Volume : 25 μl

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\024-1802.D)

 Area: 386.91 10.078 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.078 MM 386.91022 1.79028e-2 6.92679 Sulfate 

Totals : 6.92679

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\024-1802.D

Sample Name: Run 2 Post *20 0410-11

Instrument 1 6/9/2010 9:12:17 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 19

Acq. Instrument : Gonzo Location : Vial 25

Injection Date : 6/9/2010 1:24:04 AM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\025-1901.D)

 10.077 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.077 BB 375.11435 1.79013e-2 6.71503 Sulfate 

Totals : 6.71503

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\025-1901.D

Sample Name: Run 3 Post *20 0410-11

Instrument 1 6/9/2010 9:04:16 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 19

Acq. Instrument : Gonzo Location : Vial 25

Injection Date : 6/9/2010 1:40:39 AM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\025-1902.D)

 10.073 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.073 BB 377.35861 1.79016e-2 6.75532 Sulfate 

Totals : 6.75532

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\025-1902.D

Sample Name: Run 3 Post *20 0410-11

Instrument 1 6/9/2010 9:04:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 22

Acq. Instrument : Gonzo Location : Vial 26

Injection Date : 6/9/2010 3:04:01 AM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\026-2201.D) 4.000

 10.067 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.067 VV 74.39171 1.76968e-2 1.31650 Sulfate 

Totals : 1.31650

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\026-2201.D

Sample Name: Train Blank Post 0410-11

Instrument 1 6/9/2010 9:05:39 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 22

Acq. Instrument : Gonzo Location : Vial 26

Injection Date : 6/9/2010 3:20:41 AM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\026-2202.D) 4.001

 10.063 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.063 VB 71.29880 1.76858e-2 1.26097 Sulfate 

Totals : 1.26097

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\026-2202.D

Sample Name: Train Blank Post 0410-11

Instrument 1 6/9/2010 9:05:53 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 23

Acq. Instrument : Gonzo Location : Vial 27

Injection Date : 6/9/2010 3:37:19 AM Inj : 1

 Inj Volume : 25 μl

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\027-2301.D)

 Area: 17.9522

 4.001

 10.087 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.087 MM 17.95224 1.72950e-2 3.10484e-1 Sulfate 

Totals : 3.10484e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\027-2301.D

Sample Name: In House Blank Post 0410-11

Instrument 1 6/9/2010 9:37:48 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 23

Acq. Instrument : Gonzo Location : Vial 27

Injection Date : 6/9/2010 3:53:58 AM Inj : 2

 Inj Volume : 25 μl

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\027-2302.D)

 Area: 18.2085

 4.000

 10.085 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.085 MM 18.20848 1.72950e-2 3.14915e-1 Sulfate 

Totals : 3.14915e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\027-2302.D

Sample Name: In House Blank Post 0410-11

Instrument 1 6/9/2010 9:38:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 9

Acq. Instrument : Gonzo Location : Vial 7

Injection Date : 6/8/2010 7:50:44 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\007-0901.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.028 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\007-0901.D

Sample Name: MB/ DI H2O

Instrument 1 6/9/2010 8:54:33 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 9

Acq. Instrument : Gonzo Location : Vial 7

Injection Date : 6/8/2010 8:07:23 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\007-0902.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.028 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\007-0902.D

Sample Name: MB/ DI H2O

Instrument 1 6/9/2010 8:54:58 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 8

Acq. Instrument : Gonzo Location : Vial 6

Injection Date : 6/8/2010 7:17:19 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\006-0801.D)

 10.049 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.049 VB 281.71533 1.78845e-2 5.03834 Sulfate Tag Value= 5.0 μg/mL 

Totals : 5.03834

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\006-0801.D

Sample Name: hplc49pg22 #LCS

Instrument 1 6/9/2010 8:54:07 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 8

Acq. Instrument : Gonzo Location : Vial 6

Injection Date : 6/8/2010 7:34:01 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\006-0802.D)

 10.046 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.046 BB 284.10382 1.78851e-2 5.08122 Sulfate Tag Value= 5.0 μg/mL 

Totals : 5.08122

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\006-0802.D

Sample Name: hplc49pg22 #LCS

Instrument 1 6/9/2010 8:54:20 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 16

Acq. Instrument : Gonzo Location : Vial 22

Injection Date : 6/8/2010 11:44:05 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\022-1601.D) 3.980 5.663 6.257

 7.750

 10.081 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.081 VB 527.16437 1.79159e-2 9.44461 Sulfate 

Totals : 9.44461

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\022-1601.D

Sample Name: MS Run 1 Post 0410-11

Instrument 1 6/9/2010 9:02:56 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 16

Acq. Instrument : Gonzo Location : Vial 22

Injection Date : 6/9/2010 12:00:47 AM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\022-1602.D) 3.979 5.661 6.256

 7.750

 10.075 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.075 BB 527.06824 1.79159e-2 9.44289 Sulfate 

Totals : 9.44289

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\022-1602.D

Sample Name: MS Run 1 Post 0410-11

Instrument 1 6/9/2010 9:03:11 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 17

Acq. Instrument : Gonzo Location : Vial 23

Injection Date : 6/9/2010 12:17:27 AM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\023-1701.D) 3.978 5.658 6.250

 7.756

 10.076 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.076 BB 526.20581 1.79158e-2 9.42740 Sulfate 

Totals : 9.42740

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\023-1701.D

Sample Name: MSD Run 1 Post 0410-11

Instrument 1 6/9/2010 9:03:24 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 17

Acq. Instrument : Gonzo Location : Vial 23

Injection Date : 6/9/2010 12:34:08 AM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\023-1702.D) 3.977 5.659 6.253

 7.754

 10.069 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.069 VB 525.77075 1.79158e-2 9.41959 Sulfate 

Totals : 9.41959

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\023-1702.D

Sample Name: MSD Run 1 Post 0410-11

Instrument 1 6/9/2010 9:03:37 AM ARM Page 1 of 1
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: VWD1 A, Wavelength=210 nm

Signal 2: ADC1 B, Dionex ED 40

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 10.028 2 1 4.99500e-1 28.91521 1.72746e-2 Sulfate 

 2 9.99000e-1 57.70783 1.73113e-2 

 3 4.97500 271.08472 1.83522e-2 

 4 8.92000 496.73793 1.79572e-2 

 5 14.80000 832.75290 1.77724e-2 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Instrument 1 6/9/2010 8:48:16 AM ARM Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

100

200

300

400

500

600

700

800

12

3

4

5

Sulfate at exp. RT: 10.028

ADC1 B, Dionex ED 40

Correlation: 0.99989

Residual Std. Dev.: 5.93670

Formula: y = mx + b

 m: 55.70453

 b: 1.05679

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.5

 Level 3 : 0.100402

 Level 4 : 0.055998

 Level 5 : 0.03375

=====================================================================

Method H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Instrument 1 6/9/2010 8:48:16 AM ARM Page 2 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 3

Acq. Instrument : Gonzo Location : Vial 1

Injection Date : 6/8/2010 4:30:20 PM Inj : 1

 Inj Volume : 25 μl

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\001-0301.D)

 Area: 29.5056

 3.993

 10.064 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.064 MM 29.50560 1.73089e-2 5.10709e-1 Sulfate 

Totals : 5.10709e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\001-0301.D

Sample Name: hplc49pg22 #1

Instrument 1 6/9/2010 8:49:19 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 3

Acq. Instrument : Gonzo Location : Vial 1

Injection Date : 6/8/2010 4:47:09 PM Inj : 2

 Inj Volume : 25 μl

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\001-0302.D)

 Area: 28.3248

 3.993

 10.036 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.036 MM 28.32482 1.72950e-2 4.89877e-1 Sulfate 

Totals : 4.89877e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\001-0302.D

Sample Name: hplc49pg22 #1

Instrument 1 6/9/2010 8:49:44 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 4

Acq. Instrument : Gonzo Location : Vial 2

Injection Date : 6/8/2010 5:03:50 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\002-0401.D) 3.990 5.697 6.308

 10.055 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.055 VV 59.20059 1.76314e-2 1.04379 Sulfate 

Totals : 1.04379

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\002-0401.D

Sample Name: hplc49pg22 #2

Instrument 1 6/9/2010 8:52:07 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 4

Acq. Instrument : Gonzo Location : Vial 2

Injection Date : 6/8/2010 5:20:31 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\002-0402.D) 3.988 5.687 6.288

 10.062 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.062 VV 56.21507 1.76144e-2 9.90194e-1 Sulfate 

Totals : 9.90194e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\002-0402.D

Sample Name: hplc49pg22 #2

Instrument 1 6/9/2010 8:52:23 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 5

Acq. Instrument : Gonzo Location : Vial 3

Injection Date : 6/8/2010 5:37:12 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\003-0501.D) 3.982 5.686 6.281

 7.738

 10.044 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.044 BB 269.91867 1.78816e-2 4.82657 Sulfate 

Totals : 4.82657

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\003-0501.D

Sample Name: hplc49pg22 #3

Instrument 1 6/9/2010 8:52:40 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 5

Acq. Instrument : Gonzo Location : Vial 3

Injection Date : 6/8/2010 5:53:58 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\003-0502.D) 3.981 5.682 6.277

 7.739

 10.053 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.053 BB 272.25076 1.78822e-2 4.86844 Sulfate 

Totals : 4.86844

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\003-0502.D

Sample Name: hplc49pg22 #3

Instrument 1 6/9/2010 8:52:57 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 6

Acq. Instrument : Gonzo Location : Vial 4

Injection Date : 6/8/2010 6:10:36 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-0601.D) 3.982 5.681 6.275

 7.735

 10.037 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.037 BB 495.87808 1.79136e-2 8.88296 Sulfate 

Totals : 8.88296

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-0601.D

Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 8:53:12 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 6

Acq. Instrument : Gonzo Location : Vial 4

Injection Date : 6/8/2010 6:27:21 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-0602.D) 3.982 5.685 6.278

 7.736

 10.032 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.032 VB 497.59778 1.79137e-2 8.91384 Sulfate 

Totals : 8.91384

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-0602.D

Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 8:53:25 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 7

Acq. Instrument : Gonzo Location : Vial 5

Injection Date : 6/8/2010 6:44:02 PM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\005-0701.D) 3.983 5.682 6.272

 7.733

 10.024 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.024 BB 833.94806 1.79291e-2 14.95195 Sulfate 

Totals : 14.95195

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\005-0701.D

Sample Name: hplc49pg22 #5

Instrument 1 6/9/2010 8:53:39 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 7

Acq. Instrument : Gonzo Location : Vial 5

Injection Date : 6/8/2010 7:00:35 PM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\005-0702.D) 3.981 5.676 6.266

 7.735

 10.029 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.029 BB 831.55774 1.79290e-2 14.90904 Sulfate 

Totals : 14.90904

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\005-0702.D

Sample Name: hplc49pg22 #5

Instrument 1 6/9/2010 8:53:53 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 21

Acq. Instrument : Gonzo Location : Vial 4

Injection Date : 6/9/2010 2:30:40 AM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2101.D) 3.994 5.731 6.339

 7.714

 10.048 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.048 BB 498.29391 1.79138e-2 8.92633 Sulfate 

Totals : 8.92633

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2101.D

Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:05:11 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 21

Acq. Instrument : Gonzo Location : Vial 4

Injection Date : 6/9/2010 2:47:21 AM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2102.D) 3.994 5.735 6.345

 7.707

 10.053 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.053 BB 498.68936 1.79138e-2 8.93343 Sulfate 

Totals : 8.93343

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2102.D

Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:05:24 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 25

Acq. Instrument : Gonzo Location : Vial 4

Injection Date : 6/9/2010 4:44:03 AM Inj : 1

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2501.D) 3.997 5.754 6.365

 7.693

 10.037 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.037 BB 499.05215 1.79138e-2 8.93994 Sulfate 

Totals : 8.93994

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2501.D

Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:07:10 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 25

Acq. Instrument : Gonzo Location : Vial 4

Injection Date : 6/9/2010 5:00:44 AM Inj : 2

 Inj Volume : 25 μl

Sequence File : H:\HPLC2010Q2\GONZO\SEQUENCE\HPLC49PG26ARM.S

Acq. Method : H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Last changed : 5/27/2010 4:50:49 PM by ARM

Analysis Method : H:\HPLC2010Q2\GONZO\METHODS\HPLC49PG26.M

Last changed : 6/9/2010 8:48:07 AM by ARM

0 2 4 6 8 10 12 14 min

uS

350

400

450

500

550

 ADC1 B, Dionex ED 40 (IC HPLC49PG26ARM\004-2502.D) 3.997 5.757 6.370

 7.692

 10.037 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, June 09, 2010 8:48:00 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, Dionex ED 40

RetTime Type Area Amt/Area Amount Grp Name

 [min] [uS*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 10.037 BB 501.51471 1.79140e-2 8.98415 Sulfate 

Totals : 8.98415

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GONZO\DATA\MAY\IC HPLC49PG26ARM\004-2502.D

Sample Name: hplc49pg22 #4

Instrument 1 6/9/2010 9:07:23 AM ARM Page 1 of 1
 Method Information

 Method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

 Modified: 5/27/2010 at 4:50:49 PM

 Column: Dionex IonPac AS14A, 250*4mm

 Mobile Phase: 8mM Na2CO3/1mM NaHCO3

 Flow Rate: 1.2 mL/min

 Detection: Suppressed Ion Conductivity

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: Dionex ED 40

Source: Signal

Unit: uS

Units/Volt: 1000.000

Peakwidth (Data Rate): 0.027 Min (10.00 Hz)

Stop Time: No Limit

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Modified on: 5/27/2010 at 4:50:49 PM

Gonzo 5/29/2010 10:43:08 AM ARM Page 1 of 3
=====================================================================

 Agilent 1100/1200 Quaternary Pump 1

=====================================================================

Control

 Column Flow : 1.200 ml/min

 Stoptime : 15.00 min

 Posttime : Off

Solvents

 Solvent A : 100.0 % (8mM Na2CO3/1mM NaHCO3)

 Solvent B : Off

 Solvent C : Off

 Solvent D : Off

PressureLimits

 Minimum Pressure : 0 bar

 Maximum Pressure : 400 bar

Auxiliary

 Maximal Flow Ramp : 100.00 ml/min^2

 Primary Channel : Auto

 Compressibility : 83*10^-6/bar

 Minimal Stroke : Auto

Store Parameters

 Store Ratio A : Yes

 Store Ratio B : Yes

 Store Ratio C : Yes

 Store Ratio D : Yes

 Store Flow : Yes

 Store Pressure : Yes

=====================================================================

 Agilent 1100 Variable Wavelength Detector 1

=====================================================================

Signal

 Wavelength : 210 nm

 Peakwidth : > 0.1 min

Time

 Stoptime : As pump

 Posttime : Off

Analog Output

 Zero offset analog out.: 5 %

 Attenuation analog out.: 1000 mAU

Store Additionally

 Signal w/o Reference : No

 Reference : No

Autobalance

 Prerun balancing : Yes

 Postrun balancing : No

Special Parameters

 Margin for negative Absorbance: 100 mAU

 Signal Polarity : Positive

 Enable analysis when lamp is off: No

 Scan from : 190 nm

 method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Modified on: 5/27/2010 at 4:50:49 PM

Gonzo 5/29/2010 10:43:08 AM ARM Page 2 of 3
 Scan to : 400 nm

 Scan step : 2 nm

=====================================================================

 Agilent 1100 Autosampler 1

=====================================================================

Injection

 Injection Mode : Needle Wash

 Injector volume : 25.00 μl

 Wash Vial : 100

 Optimization : Prefetch Sample Vial

 12.00 min. after Injection

Auxiliary

 Drawspeed : 100 μl/min

 Ejectspeed : 1000 μl/min

 Draw position : 2.0 mm

Time

 Stoptime : As Pump

 Posttime : Off

=====================================================================

 Agilent 1100/1200 Column Thermostat 1

=====================================================================

Temperature settings

 Left temperature : 30.0°C

 Right temperature : Same as left

 Enable analysis : When Temp. is within setpoint +/- 0.8°C

 Store left temperature : No

 Store right temperature: No

Time

 Stoptime : As pump

 Posttime : Off

Column Switching Valve : Column 1

 method: H:\HPLC2010Q2\GONZO\METHODS\ANIONS.M

Modified on: 5/27/2010 at 4:50:49 PM

Gonzo 5/29/2010 10:43:08 AM ARM Page 3 of 3
Sequence: C:\HPCHEM\1\SEQUENCE\hplc49pg26ARM.txt

Line Vial Sample Name Method Inj

1 Vial 7 MB/ DI H2O ANIONS 1

2 Vial 1 hplc49pg22 #1 ANIONS 2

3 Vial 1 hplc49pg22 #1 ANIONS 2

4 Vial 2 hplc49pg22 #2 ANIONS 2

5 Vial 3 hplc49pg22 #3 ANIONS 2

6 Vial 4 hplc49pg22 #4 ANIONS 2

7 Vial 5 hplc49pg22 #5 ANIONS 2

8 Vial 6 hplc49pg22 #LCS ANIONS 2

9 Vial 7 MB/ DI H2O ANIONS 2

10 Vial 11 Run 1 *50 0610-27 ANIONS 2

11 Vial 12 MS Run 1 0610-27 ANIONS 2

12 Vial 13 MSD Run 1 0610-27 ANIONS 2

13 Vial 14 Run 5 *50 0610-27 ANIONS 2

14 Vial 15 Run 6 *50 0610-27 ANIONS 2

15 Vial 21 Run 1 Post *20 0410-11 ANIONS 2

16 Vial 22 MS Run 1 Post 0410-11 ANIONS 2

17 Vial 23 MSD Run 1 Post 0410-11 ANIONS 2

18 Vial 24 Run 2 Post *20 0410-11 ANIONS 2

19 Vial 25 Run 3 Post *20 0410-11 ANIONS 2

20 Vial 3 hplc49pg22 #3 ANIONS 2

21 Vial 4 hplc49pg22 #4 ANIONS 2

22 Vial 26 Train Blank Post 0410-11 ANIONS 2

23 Vial 27 In House Blank Post 0410-11 ANIONS 2

24 Vial 3 hplc49pg22 #3 ANIONS 2

25 Vial 4 hplc49pg22 #4 ANIONS 2
This Is The Last Page

Of This Report.
6/7/2010

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood MO 63042

Project Name: KCP&ICR Testing La Cygne

Project #: 100-208

Dear Mr. Frank Stevens

The following report includes the data for the above referenced project for sample(s) 

received on 5/21/2010 at Air Toxics Ltd.

The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant 

with the project requirements or laboratory criteria with the exception of the deviations 

noted in the attached case narrative.

Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is 

committed to providing accurate data of the highest quality. Please feel free to contact

the Project Manager: Jacquelyn Luta at 916-985-1000 if you have any questions 

regarding the data in this report.

Regards,

Jacquelyn Luta

Project Manager

Workorder #: 1005506A

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020

Hours 6:30 A.M to 5:30 PST

Page 1 of 76
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1005506A

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

05/21/2010

DATE COMPLETED: 06/06/2010

P.O. #

PROJECT # 100-208 KCP&ICR Testing La Cygne

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Jacquelyn Luta

FRACTION # NAME TEST

01AB M0031-R1-TS1-C1/C2-Tenax Modified VOST 5041A/8260

01C M0031-R1-TS1-C4-Anasorb Modified VOST 5041A/8260

02AB M0031-R1-TS2-C1/C2-Tenax Modified VOST 5041A/8260

02C M0031-R1-TS2-C4-Anasorb Modified VOST 5041A/8260

03AB M0031-R1-TS3-C1/C2-Tenax Modified VOST 5041A/8260

03C M0031-R1-TS3-C4-Anasorb Modified VOST 5041A/8260

04AB(cancelled) M0031-R1-TS4-C1/C2-Tenax Modified VOST 5041A/8260

04C M0031-R1-TS4-C4-Anasorb Modified VOST 5041A/8260

05A M0031-R1-TS4-C3-Codensate Modified VOST 5041A/8260

06AB M0031-R2-TS1-C1/C2-Tenax Modified VOST 5041A/8260

06C M0031-R2-TS1-C4-Anasorb Modified VOST 5041A/8260

07AB M0031-R2-TS2-C1/C2-Tenax Modified VOST 5041A/8260

07C M0031-R2-TS2-C4-Anasorb Modified VOST 5041A/8260

08AB M0031-R2-TS3-C1/C2-Tenax Modified VOST 5041A/8260

08C M0031-R2-TS3-C4-Anasorb Modified VOST 5041A/8260

09AB M0031-R2-TS4-C1/C2-Tenax Modified VOST 5041A/8260

09C(cancelled) M0031-R2-TS4-C4-Anasorb Modified VOST 5041A/8260

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 2 of 76

Continued on next page
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1005506A

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

05/21/2010

DATE COMPLETED: 06/06/2010

P.O. #

PROJECT # 100-208 KCP&ICR Testing La Cygne

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Jacquelyn Luta

FRACTION # NAME TEST

10A M0031-R2-TS4-C3-Condensate Modified VOST 5041A/8260

11A Lab Blank Modified VOST 5041A/8260

11B Lab Blank Modified VOST 5041A/8260

11C Lab Blank Modified VOST 5041A/8260

12A LCS Modified VOST 5041A/8260

12B LCS Modified VOST 5041A/8260

12C LCS Modified VOST 5041A/8260

CERTIFIED BY:

Laboratory Director

DATE:

Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, 

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

 

 

06/07/10

Page 3 of 76

This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, 

NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719
LABORATORY NARRATIVE

VOST 5041A

Civil & Environmental Consultants, Inc.

Workorder# 1005506A

Laboratory Services Since 1989

Twenty-four VOST 0031 Tube and two VOA Vial-40 mL samples were received on May 21, 2010.

The laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan

mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP

helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on

the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components

into the GC/MS system for further separation. See the data sheets for the reporting limits for each

compound.

Requirement VOST 5041A ATL Modifications

Batch Certification Blanks from the same 

media as samples

Analysis of set of cartridges prior to onset of any project; 

Sampling media provided by the client is batch certified 

ahead of time, only if client provides blank cartridges.

Method blank Cartridges from the 

same media batches as 

the samples

Media batch is certified prior to use in the field. Method 

Blank is used to certify instrument is contaminant free

Connection between cartridge 

thermal desorption apparatus & 

sample purge vessel

PTFE 1/16" Teflon 

tubing

Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for 

non-CCCs

RSD +- 15 % for all 

non-CCCs

RSD </= 30 % for some compounds: Acetone, 

Bromoform, Vinyl Acetate, Bromomethane, 

Chloromethane, 1,1,2,2-Tetracholoroethane, & 

1,2,3-Trichloropropane

Receiving Notes

Sample collection date was not provided on the Chain of Custody (COC) for all samples. The 

sampling dates were taken from the tags.

Per client request, compounds that are not validated under Method 0031 collection protocols were

reported in this work order. These compounds may not be suitable for collection by Method 0031 due

to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory

analytical method 5041A/8260B is validated for all target analytes.

Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the

Anasorb. In addition the laboratory method has not been validated for recovery of these additional

compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Due to instrument malfunction, samples M0031-R1-TS4-C1/C2-Tenax and

M0031-R2-TS4-C4-Anasorb were lost during final analysis. Reporting is not possible for those

samples.

Analytical Notes

Page 4 of 76
Laboratory Services Since 1989

The recovery of surrogate Toluene-d8 in samples M0031-R1-TS1-C4-Anasorb,

M0031-R1-TS2-C4-Anasorb, M0031-R1-TS3-C4-Anasorb, M0031-R1-TS4-C4-Anasorb,

M0031-R2-TS1-C4-Anasorb, M0031-R2-TS2-C4-Anasorb and M0031-R2-TS3-C4-Anasorb was

outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent

tube media. Data is reported as qualified.

The recovery of surrogate 4-Bromofluorobenzene in samples M0031-R1-TS3-C1/C2-Tenax,

M0031-R2-TS1-C1/C2-Tenax, and M0031-R2-TS2-C1/C2-Tenax was outside control limits due to

high level matrix interference. It is not possible to re-run to confirm matrix or dilute for matrix using

sorbent tube media. Data is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is

defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target

compound non-detects in the samples that are associated with high bias in QC analyses have not been

flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows:

B - Compound present in laboratory blank or tube certification greater than reporting limit

(background subtraction not performed).

J - Estimated value.

E - Exceeds instrument calibration range.

S - Saturated peak.

Q - Exceeds quality control limits.

U - Compound analyzed for but not detected above the detection limit.

N - The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows:

a-File was requantified

b-File was quantified by a second column and detector

r1-File was requantified for the purpose of reissue

Definition of Data Qualifying Flags

Page 5 of 76
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R1-TS1-C1/C2-Tenax

Lab ID#: 1005506A-01AB

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 11

Methylene Chloride 10 75

Hexane 10 23

Benzene 10 50

Toluene 10 63

Ethyl Benzene 10 16

m,p-Xylene 10 72

o-Xylene 10 18

Styrene 10 16

1,2,4-Trimethylbenzene 10 17

p-Cymene 10 13

Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1005506A-01C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 330

Bromomethane 10 14

Freon 11 10 13

Methylene Chloride 10 54

Freon 12 10 79

Client Sample ID: M0031-R1-TS2-C1/C2-Tenax

Lab ID#: 1005506A-02AB

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 170

Bromomethane 10 15

Acetone 50 62

Hexane 10 16

Benzene 10 22

Toluene 10 30

m,p-Xylene 10 23

Page 6 of 76
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1005506A-02C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 160

Bromomethane 10 14

Freon 12 10 22

Client Sample ID: M0031-R1-TS3-C1/C2-Tenax

Lab ID#: 1005506A-03AB

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 64

Bromomethane 10 27

Carbon Disulfide 10 12

Acetone 50 73

Hexane 10 14

Benzene 10 23

Toluene 10 34

m,p-Xylene 10 22

Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1005506A-03C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 520

Bromomethane 10 16

Freon 12 10 28

Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1005506A-04C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 140

Freon 12 10 38

Client Sample ID: M0031-R1-TS4-C3-Codensate

Lab ID#: 1005506A-05A

Page 7 of 76
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R1-TS4-C3-Codensate

Lab ID#: 1005506A-05A

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 400 700

Methylene Chloride 80 940

2-Butanone (Methyl Ethyl Ketone) 400 520

Chloroform 80 95

Client Sample ID: M0031-R2-TS1-C1/C2-Tenax

Lab ID#: 1005506A-06AB

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 110

Bromomethane 10 47

Carbon Disulfide 10 13

Acetone 50 64

Methylene Chloride 10 14

Hexane 10 12

Benzene 10 40

Toluene 10 25

m,p-Xylene 10 10

Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1005506A-06C

Compound (ng) (ng)

Rpt. Limit Amount

Freon 12 10 25

Client Sample ID: M0031-R2-TS2-C1/C2-Tenax

Lab ID#: 1005506A-07AB

Compound (ng) (ng)

Rpt. Limit Amount

trans-1,2-Dichloroethene 10 14

Hexane 10 12

Benzene 10 24

Toluene 10 17

Page 8 of 76
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1005506A-07C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 420

Freon 12 10 22

Client Sample ID: M0031-R2-TS3-C1/C2-Tenax

Lab ID#: 1005506A-08AB

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 11

Carbon Disulfide 10 11

Methylene Chloride 10 17

Hexane 10 12

Benzene 10 23

Toluene 10 17

Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1005506A-08C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 63

Methylene Chloride 10 30

Freon 12 10 41

Client Sample ID: M0031-R2-TS4-C1/C2-Tenax

Lab ID#: 1005506A-09AB

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 11

Carbon Disulfide 10 11

Methylene Chloride 10 21

Hexane 10 11

Benzene 10 21

Toluene 10 20

Page 9 of 76
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1005506A-10A

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 400 780

Methylene Chloride 80 980

2-Butanone (Methyl Ethyl Ketone) 400 590

Chloroform 80 96

Page 10 of 76
Client Sample ID: M0031-R1-TS1-C1/C2-Tenax

Lab ID#: 1005506A-01AB

MODIFIED VOST 5041A/8260B

File Name: 10052630

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 09:18 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 11

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 75

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 23

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 50

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 63

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 11 of 76
Client Sample ID: M0031-R1-TS1-C1/C2-Tenax

Lab ID#: 1005506A-01AB

MODIFIED VOST 5041A/8260B

File Name: 10052630

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 09:18 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 16

m,p-Xylene 10 72

o-Xylene 10 18

Styrene 10 16

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 17

sec-Butylbenzene 10 Not Detected

p-Cymene 10 13

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 96 70-130

Page 12 of 76
Client Sample ID: M0031-R1-TS1-C1/C2-Tenax

Lab ID#: 1005506A-01AB

MODIFIED VOST 5041A/8260B

File Name: 10052630

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 09:18 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 95 70-130

Toluene-d8 100 70-130

4-Bromofluorobenzene 93 70-130

Page 13 of 76
Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1005506A-01C

MODIFIED VOST 5041A/8260B

File Name: 10052625

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:04 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 330

Vinyl Chloride 10 Not Detected

Bromomethane 10 14

Chloroethane 50 Not Detected

Freon 11 10 13

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 54

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 14 of 76
Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1005506A-01C

MODIFIED VOST 5041A/8260B

File Name: 10052625

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:04 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 79

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 15 of 76
Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1005506A-01C

MODIFIED VOST 5041A/8260B

File Name: 10052625

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:04 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 71 50-150

1,2-Dichloroethane-d4 55 50-150

Toluene-d8 17 Q 50-150

Page 16 of 76
Client Sample ID: M0031-R1-TS2-C1/C2-Tenax

Lab ID#: 1005506A-02AB

MODIFIED VOST 5041A/8260B

File Name: 10052631

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 09:43 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 170

Vinyl Chloride 10 Not Detected

Bromomethane 10 15

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 62

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 16

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 22

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 30

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 17 of 76
Client Sample ID: M0031-R1-TS2-C1/C2-Tenax

Lab ID#: 1005506A-02AB

MODIFIED VOST 5041A/8260B

File Name: 10052631

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 09:43 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 23

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 89 70-130

Page 18 of 76
Client Sample ID: M0031-R1-TS2-C1/C2-Tenax

Lab ID#: 1005506A-02AB

MODIFIED VOST 5041A/8260B

File Name: 10052631

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 09:43 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 84 70-130

Toluene-d8 93 70-130

4-Bromofluorobenzene 72 70-130

Page 19 of 76
Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1005506A-02C

MODIFIED VOST 5041A/8260B

File Name: 10052626

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:31 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 160

Vinyl Chloride 10 Not Detected

Bromomethane 10 14

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 20 of 76
Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1005506A-02C

MODIFIED VOST 5041A/8260B

File Name: 10052626

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:31 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 22

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 21 of 76
Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1005506A-02C

MODIFIED VOST 5041A/8260B

File Name: 10052626

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:31 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 79 50-150

1,2-Dichloroethane-d4 65 50-150

Toluene-d8 24 Q 50-150

Page 22 of 76
Client Sample ID: M0031-R1-TS3-C1/C2-Tenax

Lab ID#: 1005506A-03AB

MODIFIED VOST 5041A/8260B

File Name: 10052632

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 10:11 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 64

Vinyl Chloride 10 Not Detected

Bromomethane 10 27

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 12

Acetone 50 73

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 14

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 23

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 34

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 23 of 76
Client Sample ID: M0031-R1-TS3-C1/C2-Tenax

Lab ID#: 1005506A-03AB

MODIFIED VOST 5041A/8260B

File Name: 10052632

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 10:11 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 22

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 24 of 76
Client Sample ID: M0031-R1-TS3-C1/C2-Tenax

Lab ID#: 1005506A-03AB

MODIFIED VOST 5041A/8260B

File Name: 10052632

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 10:11 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 90 70-130

1,2-Dichloroethane-d4 82 70-130

Toluene-d8 97 70-130

4-Bromofluorobenzene 62 Q 70-130

Page 25 of 76
Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1005506A-03C

MODIFIED VOST 5041A/8260B

File Name: 10052627

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:58 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 520

Vinyl Chloride 10 Not Detected

Bromomethane 10 16

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 26 of 76
Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1005506A-03C

MODIFIED VOST 5041A/8260B

File Name: 10052627

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:58 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 28

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 27 of 76
Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1005506A-03C

MODIFIED VOST 5041A/8260B

File Name: 10052627

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 07:58 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 74 50-150

1,2-Dichloroethane-d4 59 50-150

Toluene-d8 23 Q 50-150

Page 28 of 76
Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1005506A-04C

MODIFIED VOST 5041A/8260B

File Name: 10052706

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 01:18 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 140

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 29 of 76
Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1005506A-04C

MODIFIED VOST 5041A/8260B

File Name: 10052706

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 01:18 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 38

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 30 of 76
Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1005506A-04C

MODIFIED VOST 5041A/8260B

File Name: 10052706

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 01:18 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 67 50-150

1,2-Dichloroethane-d4 53 50-150

Toluene-d8 18 Q 50-150

Page 31 of 76
Client Sample ID: M0031-R1-TS4-C3-Codensate

Lab ID#: 1005506A-05A

MODIFIED VOST 5041A/8260B

File Name: 10052623

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 03:44 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 700

3-Chloropropene 400 Not Detected

Methylene Chloride 80 940

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 520

Bromochloromethane 80 Not Detected

Chloroform 80 95

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 32 of 76
Client Sample ID: M0031-R1-TS4-C3-Codensate

Lab ID#: 1005506A-05A

MODIFIED VOST 5041A/8260B

File Name: 10052623

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 03:44 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Dibromofluoromethane 97 70-130

Page 33 of 76
Client Sample ID: M0031-R1-TS4-C3-Codensate

Lab ID#: 1005506A-05A

MODIFIED VOST 5041A/8260B

File Name: 10052623

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 03:44 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 104 70-130

Toluene-d8 103 70-130

4-Bromofluorobenzene 101 70-130

Page 34 of 76
Client Sample ID: M0031-R2-TS1-C1/C2-Tenax

Lab ID#: 1005506A-06AB

MODIFIED VOST 5041A/8260B

File Name: 10052714

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 05:36 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 110

Vinyl Chloride 10 Not Detected

Bromomethane 10 47

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 13

Acetone 50 64

3-Chloropropene 50 Not Detected

Methylene Chloride 10 14

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 12

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 40

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 25

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 35 of 76
Client Sample ID: M0031-R2-TS1-C1/C2-Tenax

Lab ID#: 1005506A-06AB

MODIFIED VOST 5041A/8260B

File Name: 10052714

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 05:36 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 10

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 36 of 76
Client Sample ID: M0031-R2-TS1-C1/C2-Tenax

Lab ID#: 1005506A-06AB

MODIFIED VOST 5041A/8260B

File Name: 10052714

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 05:36 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 90 70-130

1,2-Dichloroethane-d4 82 70-130

Toluene-d8 94 70-130

4-Bromofluorobenzene 28 Q 70-130

Page 37 of 76
Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1005506A-06C

MODIFIED VOST 5041A/8260B

File Name: 10052707

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 01:46 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 38 of 76
Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1005506A-06C

MODIFIED VOST 5041A/8260B

File Name: 10052707

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 01:46 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 25

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 39 of 76
Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1005506A-06C

MODIFIED VOST 5041A/8260B

File Name: 10052707

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 01:46 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 84 50-150

1,2-Dichloroethane-d4 70 50-150

Toluene-d8 28 Q 50-150

Page 40 of 76
Client Sample ID: M0031-R2-TS2-C1/C2-Tenax

Lab ID#: 1005506A-07AB

MODIFIED VOST 5041A/8260B

File Name: 10052715

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 06:22 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 14

Acrylonitrile 50 Not Detected

Hexane 10 12

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 24

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 17

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 41 of 76
Client Sample ID: M0031-R2-TS2-C1/C2-Tenax

Lab ID#: 1005506A-07AB

MODIFIED VOST 5041A/8260B

File Name: 10052715

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 06:22 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 42 of 76
Client Sample ID: M0031-R2-TS2-C1/C2-Tenax

Lab ID#: 1005506A-07AB

MODIFIED VOST 5041A/8260B

File Name: 10052715

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 06:22 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 95 70-130

1,2-Dichloroethane-d4 85 70-130

Toluene-d8 101 70-130

4-Bromofluorobenzene 55 Q 70-130

Page 43 of 76
Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1005506A-07C

MODIFIED VOST 5041A/8260B

File Name: 10052708

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 02:38 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 420

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 44 of 76
Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1005506A-07C

MODIFIED VOST 5041A/8260B

File Name: 10052708

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 02:38 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 22

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 45 of 76
Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1005506A-07C

MODIFIED VOST 5041A/8260B

File Name: 10052708

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 02:38 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 76 50-150

1,2-Dichloroethane-d4 62 50-150

Toluene-d8 25 Q 50-150

Page 46 of 76
Client Sample ID: M0031-R2-TS3-C1/C2-Tenax

Lab ID#: 1005506A-08AB

MODIFIED VOST 5041A/8260B

File Name: 10060106

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 10:53 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 11

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 11

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 17

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 12

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 23

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 17

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 47 of 76
Client Sample ID: M0031-R2-TS3-C1/C2-Tenax

Lab ID#: 1005506A-08AB

MODIFIED VOST 5041A/8260B

File Name: 10060106

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 10:53 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 84 70-130

Page 48 of 76
Client Sample ID: M0031-R2-TS3-C1/C2-Tenax

Lab ID#: 1005506A-08AB

MODIFIED VOST 5041A/8260B

File Name: 10060106

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 10:53 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 78 70-130

Toluene-d8 88 70-130

4-Bromofluorobenzene 75 70-130

Page 49 of 76
Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1005506A-08C

MODIFIED VOST 5041A/8260B

File Name: 10052709

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 03:02 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 63

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 30

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 50 of 76
Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1005506A-08C

MODIFIED VOST 5041A/8260B

File Name: 10052709

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 03:02 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 41

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 51 of 76
Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1005506A-08C

MODIFIED VOST 5041A/8260B

File Name: 10052709

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/27/10 03:02 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 79 50-150

1,2-Dichloroethane-d4 64 50-150

Toluene-d8 24 Q 50-150

Page 52 of 76
Client Sample ID: M0031-R2-TS4-C1/C2-Tenax

Lab ID#: 1005506A-09AB

MODIFIED VOST 5041A/8260B

File Name: 10060107

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 11:23 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 11

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 11

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 21

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 11

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 21

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 20

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 53 of 76
Client Sample ID: M0031-R2-TS4-C1/C2-Tenax

Lab ID#: 1005506A-09AB

MODIFIED VOST 5041A/8260B

File Name: 10060107

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 11:23 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 94 70-130

Page 54 of 76
Client Sample ID: M0031-R2-TS4-C1/C2-Tenax

Lab ID#: 1005506A-09AB

MODIFIED VOST 5041A/8260B

File Name: 10060107

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 11:23 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 90 70-130

Toluene-d8 97 70-130

4-Bromofluorobenzene 74 70-130

Page 55 of 76
Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1005506A-10A

MODIFIED VOST 5041A/8260B

File Name: 10052624

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 04:10 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 780

3-Chloropropene 400 Not Detected

Methylene Chloride 80 980

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 590

Bromochloromethane 80 Not Detected

Chloroform 80 96

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 56 of 76
Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1005506A-10A

MODIFIED VOST 5041A/8260B

File Name: 10052624

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 04:10 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Dibromofluoromethane 104 70-130

Page 57 of 76
Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1005506A-10A

MODIFIED VOST 5041A/8260B

File Name: 10052624

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 5/26/10 04:10 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 112 70-130

Toluene-d8 110 70-130

4-Bromofluorobenzene 110 70-130

Page 58 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11A

MODIFIED VOST 5041A/8260B

File Name: 10052622

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/26/10 03:07 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 59 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11A

MODIFIED VOST 5041A/8260B

File Name: 10052622

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/26/10 03:07 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 108 70-130

Page 60 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11A

MODIFIED VOST 5041A/8260B

File Name: 10052622

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/26/10 03:07 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 119 70-130

Toluene-d8 117 70-130

4-Bromofluorobenzene 116 70-130

Page 61 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11B

MODIFIED VOST 5041A/8260B

File Name: 10052705

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/27/10 12:33 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 62 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11B

MODIFIED VOST 5041A/8260B

File Name: 10052705

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/27/10 12:33 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 98 70-130

Page 63 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11B

MODIFIED VOST 5041A/8260B

File Name: 10052705

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/27/10 12:33 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 104 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 106 70-130

Page 64 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11C

MODIFIED VOST 5041A/8260B

File Name: 10060104

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:37 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 65 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11C

MODIFIED VOST 5041A/8260B

File Name: 10060104

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:37 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 100 70-130

Page 66 of 76
Client Sample ID: Lab Blank

Lab ID#: 1005506A-11C

MODIFIED VOST 5041A/8260B

File Name: 10060104

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:37 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 102 70-130

Toluene-d8 101 70-130

4-Bromofluorobenzene 92 70-130

Page 67 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12A

MODIFIED VOST 5041A/8260B

File Name: 10052621

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/26/10 02:33 PM

Compound %Recovery

Chloromethane 119

Vinyl Chloride 110

Bromomethane 120

Chloroethane 105

Freon 11 108

2-Chloropropane 129

1,1-Dichloroethene 102

Freon 113 126

Carbon Disulfide 135 Q

Acetone 180 Q

3-Chloropropene 123

Methylene Chloride 150 Q

trans-1,2-Dichloroethene 113

Acrylonitrile 121

Hexane 125

1,1-Dichloroethane 105

Vinyl Acetate Not Spiked

2,2-Dichloropropane 93

cis-1,2-Dichloroethene 102

2-Butanone (Methyl Ethyl Ketone) 164 Q

Bromochloromethane 108

Chloroform 106

1,1,1-Trichloroethane 102

Carbon Tetrachloride 102

1,1-Dichloropropene 106

Benzene 106

1,2-Dichloroethane 111

Trichloroethene 106

1,2-Dichloropropane 104

Dibromomethane 107

Bromodichloromethane 91

cis-1,3-Dichloropropene 96

trans-1,3-Dichloropropene 99

4-Methyl-2-pentanone 110

Toluene 106

1,1,2-Trichloroethane 109

Tetrachloroethene 107

1,3-Dichloropropane 109

2-Hexanone 138

Page 68 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12A

MODIFIED VOST 5041A/8260B

File Name: 10052621

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/26/10 02:33 PM

Compound %Recovery

Dibromochloromethane 89

Chlorobenzene 109

1,2-Dibromoethane (EDB) 106

Ethyl Benzene 105

m,p-Xylene 108

o-Xylene 98

Styrene 96

Bromoform 73

1,1,2,2-Tetrachloroethane 105

1,3-Dichlorobenzene 101

1,4-Dichlorobenzene 97

1,2-Dichlorobenzene 97

Cumene 115

cis-1,4-Dichloro-2-butene 88

Bromobenzene 99

1,2,3-Trichloropropane 110

trans-1,4-Dichloro-2-butene 98

Propylbenzene 97

2-Chlorotoluene 96

4-Chlorotoluene 99

1,3,5-Trimethylbenzene 97

tert-Butylbenzene 96

1,2,4-Trimethylbenzene 94

sec-Butylbenzene 97

p-Cymene 95

1,2-Dibromo-3-chloropropane 66 Q

1,2,4-Trichlorobenzene 95

Naphthalene 94

Hexachlorobutadiene 93

1,2,3-Trichlorobenzene 92

1,1,1,2-Tetrachloroethane 99

Butylbenzene 91

Iodomethane 127

Freon 12 82

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 69 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12A

MODIFIED VOST 5041A/8260B

File Name: 10052621

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/26/10 02:33 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 106 70-130

1,2-Dichloroethane-d4 109 70-130

Toluene-d8 107 70-130

4-Bromofluorobenzene 106 70-130

Page 70 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12B

MODIFIED VOST 5041A/8260B

File Name: 10052704

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/27/10 12:09 AM

Compound %Recovery

Chloromethane 139

Vinyl Chloride 125

Bromomethane 129

Chloroethane 122

Freon 11 114

2-Chloropropane 134 Q

1,1-Dichloroethene 108

Freon 113 130

Carbon Disulfide 146 Q

Acetone 110

3-Chloropropene 128

Methylene Chloride 108

trans-1,2-Dichloroethene 118

Acrylonitrile 114

Hexane 135 Q

1,1-Dichloroethane 111

Vinyl Acetate Not Spiked

2,2-Dichloropropane 97

cis-1,2-Dichloroethene 106

2-Butanone (Methyl Ethyl Ketone) 115

Bromochloromethane 110

Chloroform 110

1,1,1-Trichloroethane 106

Carbon Tetrachloride 102

1,1-Dichloropropene 110

Benzene 110

1,2-Dichloroethane 113

Trichloroethene 109

1,2-Dichloropropane 108

Dibromomethane 108

Bromodichloromethane 91

cis-1,3-Dichloropropene 98

trans-1,3-Dichloropropene 102

4-Methyl-2-pentanone 92

Toluene 110

1,1,2-Trichloroethane 109

Tetrachloroethene 110

1,3-Dichloropropane 111

2-Hexanone 97

Page 71 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12B

MODIFIED VOST 5041A/8260B

File Name: 10052704

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/27/10 12:09 AM

Compound %Recovery

Dibromochloromethane 86

Chlorobenzene 112

1,2-Dibromoethane (EDB) 104

Ethyl Benzene 106

m,p-Xylene 112

o-Xylene 101

Styrene 97

Bromoform 67 Q

1,1,2,2-Tetrachloroethane 103

1,3-Dichlorobenzene 105

1,4-Dichlorobenzene 101

1,2-Dichlorobenzene 99

Cumene 120

cis-1,4-Dichloro-2-butene 84

Bromobenzene 102

1,2,3-Trichloropropane 108

trans-1,4-Dichloro-2-butene 95

Propylbenzene 104

2-Chlorotoluene 102

4-Chlorotoluene 104

1,3,5-Trimethylbenzene 103

tert-Butylbenzene 104

1,2,4-Trimethylbenzene 100

sec-Butylbenzene 105

p-Cymene 105

1,2-Dibromo-3-chloropropane 56 Q

1,2,4-Trichlorobenzene 97

Naphthalene 88

Hexachlorobutadiene 107

1,2,3-Trichlorobenzene 95

1,1,1,2-Tetrachloroethane 99

Butylbenzene 101

Iodomethane 133 Q

Freon 12 100

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 72 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12B

MODIFIED VOST 5041A/8260B

File Name: 10052704

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/27/10 12:09 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 108 70-130

1,2-Dichloroethane-d4 110 70-130

Toluene-d8 111 70-130

4-Bromofluorobenzene 111 70-130

Page 73 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12C

MODIFIED VOST 5041A/8260B

File Name: 10060103

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:13 AM

Compound %Recovery

Chloromethane 116

Vinyl Chloride 101

Bromomethane 100

Chloroethane 98

Freon 11 105

2-Chloropropane 109

1,1-Dichloroethene 100

Freon 113 116

Carbon Disulfide 124

Acetone 109

3-Chloropropene 118

Methylene Chloride 104

trans-1,2-Dichloroethene 109

Acrylonitrile 96

Hexane 114

1,1-Dichloroethane 99

Vinyl Acetate Not Spiked

2,2-Dichloropropane 99

cis-1,2-Dichloroethene 94

2-Butanone (Methyl Ethyl Ketone) 119

Bromochloromethane 95

Chloroform 98

1,1,1-Trichloroethane 99

Carbon Tetrachloride 98

1,1-Dichloropropene 104

Benzene 100

1,2-Dichloroethane 97

Trichloroethene 100

1,2-Dichloropropane 100

Dibromomethane 97

Bromodichloromethane 95

cis-1,3-Dichloropropene 99

trans-1,3-Dichloropropene 102

4-Methyl-2-pentanone 97

Toluene 97

1,1,2-Trichloroethane 96

Tetrachloroethene 100

1,3-Dichloropropane 94

2-Hexanone 129

Page 74 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12C

MODIFIED VOST 5041A/8260B

File Name: 10060103

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:13 AM

Compound %Recovery

Dibromochloromethane 95

Chlorobenzene 97

1,2-Dibromoethane (EDB) 96

Ethyl Benzene 100

m,p-Xylene 99

o-Xylene 99

Styrene 101

Bromoform 94

1,1,2,2-Tetrachloroethane 91

1,3-Dichlorobenzene 101

1,4-Dichlorobenzene 100

1,2-Dichlorobenzene 101

Cumene 117

cis-1,4-Dichloro-2-butene 86

Bromobenzene 96

1,2,3-Trichloropropane 95

trans-1,4-Dichloro-2-butene 88

Propylbenzene 100

2-Chlorotoluene 98

4-Chlorotoluene 101

1,3,5-Trimethylbenzene 101

tert-Butylbenzene 102

1,2,4-Trimethylbenzene 102

sec-Butylbenzene 103

p-Cymene 103

1,2-Dibromo-3-chloropropane 93

1,2,4-Trichlorobenzene 106

Naphthalene 98

Hexachlorobutadiene 121

1,2,3-Trichlorobenzene 107

1,1,1,2-Tetrachloroethane 100

Butylbenzene 101

Iodomethane 115

Freon 12 103

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 103 70-130

Page 75 of 76
Client Sample ID: LCS

Lab ID#: 1005506A-12C

MODIFIED VOST 5041A/8260B

File Name: 10060103

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:13 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 104 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 96 70-130

Page 76 of 76


6/7/2010

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood MO 63042

Project Name: KCP&ICR Testing La Cygne

Project #: 100-208

Dear Mr. Frank Stevens

The following report includes the data for the above referenced project for sample(s) 

received on 5/21/2010 at Air Toxics Ltd.

The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant 

with the project requirements or laboratory criteria with the exception of the deviations 

noted in the attached case narrative.

Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is 

committed to providing accurate data of the highest quality. Please feel free to contact

the Project Manager: Jacquelyn Luta at 916-985-1000 if you have any questions 

regarding the data in this report.

Regards,

Jacquelyn Luta

Project Manager

Workorder #: 1005506B

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020

Hours 6:30 A.M to 5:30 PST

Page 1 of 49
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1005506B

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

05/21/2010

DATE COMPLETED: 06/06/2010

P.O. #

PROJECT # 100-208 KCP&ICR Testing La Cygne

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Jacquelyn Luta

FRACTION # NAME TEST

11AB M0031-R3-TS1-C1/C2-Tenax Modified VOST 5041A/8260

11C(cancelled) M0031-R3-TS1-C4-Anasorb Modified VOST 5041A/8260

12AB M0031-R3-TS2-C1/C2-Tenax Modified VOST 5041A/8260

12C M0031-R3-TS2-C4-Anasorb Modified VOST 5041A/8260

13AB M0031-R3-TS3-C1/C2-Tenax Modified VOST 5041A/8260

13C M0031-R3-TS3-C4-Anasorb Modified VOST 5041A/8260

14AB M0031-R3-TS4-C1/C2-Tenax Modified VOST 5041A/8260

14C M0031-R3-TS4-C4-Anasorb Modified VOST 5041A/8260

15A M0031-R3-TS4-C3-Codensate Modified VOST 5041A/8260

16AB M0031-BT-TS1-C1/C2-Tenax Modified VOST 5041A/8260

16C M0031-BT-TS1-C4-Anasorb Modified VOST 5041A/8260

17AB M0031-Trip Blank-TS1-C1/C2-Tenax Modified VOST 5041A/8260

17C M0031-Trip Blank-TS1-C4-Anasorb Modified VOST 5041A/8260

18A Lab Blank Modified VOST 5041A/8260

19A LCS Modified VOST 5041A/8260

CERTIFIED BY:

Laboratory Director

DATE:

Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, 

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

 

 

06/07/10

Page 2 of 49

This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, 

NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719
LABORATORY NARRATIVE

VOST 5041A

Civil & Environmental Consultants, Inc.

Workorder# 1005506B

Laboratory Services Since 1989

Eighteen VOST 0031 Tube and one VOA Vial-40 mL samples were received on May 21, 2010. The

laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan

mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP

helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on

the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components

into the GC/MS system for further separation. See the data sheets for the reporting limits for each

compound.

Requirement VOST 5041A ATL Modifications

Batch Certification Blanks from the same 

media as samples

Analysis of set of cartridges prior to onset of any project; 

Sampling media provided by the client is batch certified 

ahead of time, only if client provides blank cartridges.

Method blank Cartridges from the 

same media batches as 

the samples

Media batch is certified prior to use in the field. Method 

Blank is used to certify instrument is contaminant free

Connection between cartridge 

thermal desorption apparatus & 

sample purge vessel

PTFE 1/16" Teflon 

tubing

Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for 

non-CCCs

RSD +- 15 % for all 

non-CCCs

RSD </= 30 % for some compounds: Acetone, 

Bromoform, Vinyl Acetate, Bromomethane, 

Chloromethane, 1,1,2,2-Tetracholoroethane, & 

1,2,3-Trichloropropane

Receiving Notes

Sample collection date was not provided on the Chain of Custody (COC) for all samples. The 

sampling dates were taken from the tags.

Per client request, compounds that are not validated under Method 0031 collection protocols were

reported in this work order. These compounds may not be suitable for collection by Method 0031 due

to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory

analytical method 5041A/8260B is validated for all target analytes.

Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the

Anasorb. In addition the laboratory method has not been validated for recovery of these additional

compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Due to instrument malfunction, sample M0031-R3-TS1-C4-Anasorb was lost during final analysis.

Reporting is not possible for this sample.

The recovery of surrogate 1,2-Dichloroethane-d4 in sample M0031-R3-TS2-C4-Anasorb was outside

control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube

Analytical Notes

Page 3 of 49
Laboratory Services Since 1989

media. Data is reported as qualified.

The recovery of surrogate Toluene-d8 in samples M0031-R3-TS2-C4-Anasorb,

M0031-R3-TS3-C4-Anasorb, and M0031-BT-TS1-C4-Anasorb was outside control limits. It is not

possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as

qualified.

The recovery of surrogate 4-Bromofluorobenzene in sample M0031-R3-TS1-C1/C2-Tenax was

outside control limits due to high level matrix interference. It is not possible to re-run to confirm matrix

or dilute for matrix using sorbent tube media. Data is reported as qualified.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows:

B - Compound present in laboratory blank or tube certification greater than reporting limit

(background subtraction not performed).

J - Estimated value.

E - Exceeds instrument calibration range.

S - Saturated peak.

Q - Exceeds quality control limits.

U - Compound analyzed for but not detected above the detection limit.

N - The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows:

a-File was requantified

b-File was quantified by a second column and detector

r1-File was requantified for the purpose of reissue

Definition of Data Qualifying Flags

Page 4 of 49
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R3-TS1-C1/C2-Tenax

Lab ID#: 1005506B-11AB

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 32

Methylene Chloride 10 14

Hexane 10 13

Benzene 10 32

Toluene 10 17

Client Sample ID: M0031-R3-TS2-C1/C2-Tenax

Lab ID#: 1005506B-12AB

Compound (ng) (ng)

Rpt. Limit Amount

Carbon Disulfide 10 12

Methylene Chloride 10 46

Hexane 10 12

Benzene 10 29

Toluene 10 15

Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1005506B-12C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 6100 E

Bromomethane 10 170

Freon 12 10 26

Client Sample ID: M0031-R3-TS3-C1/C2-Tenax

Lab ID#: 1005506B-13AB

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 27

Carbon Disulfide 10 12

Acetone 50 51

Methylene Chloride 10 12

Hexane 10 14

Benzene 10 29

Toluene 10 18

Page 5 of 49
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R3-TS3-C1/C2-Tenax

Lab ID#: 1005506B-13AB

1,3-Dichlorobenzene 10 12

1,4-Dichlorobenzene 10 12

1,2-Dichlorobenzene 10 14

Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1005506B-13C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 620

Bromomethane 10 15

1,4-Dichlorobenzene 10 11

1,2-Dichlorobenzene 10 12

Freon 12 10 24

Client Sample ID: M0031-R3-TS4-C1/C2-Tenax

Lab ID#: 1005506B-14AB

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 20

Methylene Chloride 10 34

Hexane 10 11

Benzene 10 29

Toluene 10 16

Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1005506B-14C

Compound (ng) (ng)

Rpt. Limit Amount

Freon 12 10 25

Client Sample ID: M0031-R3-TS4-C3-Codensate

Lab ID#: 1005506B-15A

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 80 870

Chloroform 80 87

Page 6 of 49
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-BT-TS1-C1/C2-Tenax

Lab ID#: 1005506B-16AB

No Detections Were Found.

Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1005506B-16C

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 10

Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax

Lab ID#: 1005506B-17AB

No Detections Were Found.

Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1005506B-17C

Compound (ng) (ng)

Rpt. Limit Amount

Bromomethane 10 11

1,4-Dichlorobenzene 10 10

1,2-Dichlorobenzene 10 10

Page 7 of 49
Client Sample ID: M0031-R3-TS1-C1/C2-Tenax

Lab ID#: 1005506B-11AB

MODIFIED VOST 5041A/8260B

File Name: 10060108

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 11:46 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 32

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 14

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 13

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 32

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 17

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 8 of 49
Client Sample ID: M0031-R3-TS1-C1/C2-Tenax

Lab ID#: 1005506B-11AB

MODIFIED VOST 5041A/8260B

File Name: 10060108

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 11:46 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 9 of 49
Client Sample ID: M0031-R3-TS1-C1/C2-Tenax

Lab ID#: 1005506B-11AB

MODIFIED VOST 5041A/8260B

File Name: 10060108

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 11:46 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 80 70-130

1,2-Dichloroethane-d4 81 70-130

Toluene-d8 80 70-130

4-Bromofluorobenzene 67 Q 70-130

Page 10 of 49
Client Sample ID: M0031-R3-TS2-C1/C2-Tenax

Lab ID#: 1005506B-12AB

MODIFIED VOST 5041A/8260B

File Name: 10060109

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 12:22 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 12

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 46

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 12

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 29

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 15

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 11 of 49
Client Sample ID: M0031-R3-TS2-C1/C2-Tenax

Lab ID#: 1005506B-12AB

MODIFIED VOST 5041A/8260B

File Name: 10060109

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 12:22 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 106 70-130

Page 12 of 49
Client Sample ID: M0031-R3-TS2-C1/C2-Tenax

Lab ID#: 1005506B-12AB

MODIFIED VOST 5041A/8260B

File Name: 10060109

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 12:22 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 104 70-130

Toluene-d8 107 70-130

4-Bromofluorobenzene 106 70-130

Page 13 of 49
Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1005506B-12C

MODIFIED VOST 5041A/8260B

File Name: 10060110

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 12:46 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 6100 E

Vinyl Chloride 10 Not Detected

Bromomethane 10 170

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 14 of 49
Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1005506B-12C

MODIFIED VOST 5041A/8260B

File Name: 10060110

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 12:46 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 26

E = Exceeds instrument calibration range.

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 15 of 49
Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1005506B-12C

MODIFIED VOST 5041A/8260B

File Name: 10060110

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 12:46 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 62 50-150

1,2-Dichloroethane-d4 44 Q 50-150

Toluene-d8 8.8 Q 50-150

Page 16 of 49
Client Sample ID: M0031-R3-TS3-C1/C2-Tenax

Lab ID#: 1005506B-13AB

MODIFIED VOST 5041A/8260B

File Name: 10060115

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 03:59 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 27

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 12

Acetone 50 51

3-Chloropropene 50 Not Detected

Methylene Chloride 10 12

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 14

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 29

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 18

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 17 of 49
Client Sample ID: M0031-R3-TS3-C1/C2-Tenax

Lab ID#: 1005506B-13AB

MODIFIED VOST 5041A/8260B

File Name: 10060115

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 03:59 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 12

1,4-Dichlorobenzene 10 12

1,2-Dichlorobenzene 10 14

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 91 70-130

Page 18 of 49
Client Sample ID: M0031-R3-TS3-C1/C2-Tenax

Lab ID#: 1005506B-13AB

MODIFIED VOST 5041A/8260B

File Name: 10060115

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 03:59 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 98 70-130

Toluene-d8 86 70-130

4-Bromofluorobenzene 91 70-130

Page 19 of 49
Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1005506B-13C

MODIFIED VOST 5041A/8260B

File Name: 10060111

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 01:14 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 620

Vinyl Chloride 10 Not Detected

Bromomethane 10 15

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 20 of 49
Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1005506B-13C

MODIFIED VOST 5041A/8260B

File Name: 10060111

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 01:14 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 11

1,2-Dichlorobenzene 10 12

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 24

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 21 of 49
Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1005506B-13C

MODIFIED VOST 5041A/8260B

File Name: 10060111

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 01:14 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 97 50-150

1,2-Dichloroethane-d4 86 50-150

Toluene-d8 25 Q 50-150

Page 22 of 49
Client Sample ID: M0031-R3-TS4-C1/C2-Tenax

Lab ID#: 1005506B-14AB

MODIFIED VOST 5041A/8260B

File Name: 10060116

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 04:24 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 20

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 34

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 11

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 29

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 16

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 23 of 49
Client Sample ID: M0031-R3-TS4-C1/C2-Tenax

Lab ID#: 1005506B-14AB

MODIFIED VOST 5041A/8260B

File Name: 10060116

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 04:24 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 105 70-130

Page 24 of 49
Client Sample ID: M0031-R3-TS4-C1/C2-Tenax

Lab ID#: 1005506B-14AB

MODIFIED VOST 5041A/8260B

File Name: 10060116

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 04:24 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 113 70-130

Toluene-d8 102 70-130

4-Bromofluorobenzene 102 70-130

Page 25 of 49
Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1005506B-14C

MODIFIED VOST 5041A/8260B

File Name: 10060112

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 01:58 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 26 of 49
Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1005506B-14C

MODIFIED VOST 5041A/8260B

File Name: 10060112

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 01:58 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 25

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 125 50-150

Page 27 of 49
Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1005506B-14C

MODIFIED VOST 5041A/8260B

File Name: 10060112

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 01:58 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 130 50-150

Toluene-d8 81 50-150

Page 28 of 49
Client Sample ID: M0031-R3-TS4-C3-Codensate

Lab ID#: 1005506B-15A

MODIFIED VOST 5041A/8260B

File Name: 10060105

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 10:25 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 Not Detected

3-Chloropropene 400 Not Detected

Methylene Chloride 80 870

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 Not Detected

Bromochloromethane 80 Not Detected

Chloroform 80 87

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 29 of 49
Client Sample ID: M0031-R3-TS4-C3-Codensate

Lab ID#: 1005506B-15A

MODIFIED VOST 5041A/8260B

File Name: 10060105

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 10:25 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Dibromofluoromethane 101 70-130

Page 30 of 49
Client Sample ID: M0031-R3-TS4-C3-Codensate

Lab ID#: 1005506B-15A

MODIFIED VOST 5041A/8260B

File Name: 10060105

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 10:25 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 94 70-130

Toluene-d8 106 70-130

4-Bromofluorobenzene 96 70-130

Page 31 of 49
Client Sample ID: M0031-BT-TS1-C1/C2-Tenax

Lab ID#: 1005506B-16AB

MODIFIED VOST 5041A/8260B

File Name: 10060117

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 04:58 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 32 of 49
Client Sample ID: M0031-BT-TS1-C1/C2-Tenax

Lab ID#: 1005506B-16AB

MODIFIED VOST 5041A/8260B

File Name: 10060117

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 04:58 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 102 70-130

Page 33 of 49
Client Sample ID: M0031-BT-TS1-C1/C2-Tenax

Lab ID#: 1005506B-16AB

MODIFIED VOST 5041A/8260B

File Name: 10060117

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 04:58 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 113 70-130

Toluene-d8 97 70-130

4-Bromofluorobenzene 90 70-130

Page 34 of 49
Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1005506B-16C

MODIFIED VOST 5041A/8260B

File Name: 10060113

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 02:59 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 10

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 35 of 49
Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1005506B-16C

MODIFIED VOST 5041A/8260B

File Name: 10060113

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 02:59 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 36 of 49
Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1005506B-16C

MODIFIED VOST 5041A/8260B

File Name: 10060113

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 02:59 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 51 50-150

1,2-Dichloroethane-d4 78 50-150

Toluene-d8 18 Q 50-150

Page 37 of 49
Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax

Lab ID#: 1005506B-17AB

MODIFIED VOST 5041A/8260B

File Name: 10060118

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 05:26 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 38 of 49
Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax

Lab ID#: 1005506B-17AB

MODIFIED VOST 5041A/8260B

File Name: 10060118

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 05:26 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 106 70-130

Page 39 of 49
Client Sample ID: M0031-Trip Blank-TS1-C1/C2-Tenax

Lab ID#: 1005506B-17AB

MODIFIED VOST 5041A/8260B

File Name: 10060118

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 05:26 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 117 70-130

Toluene-d8 98 70-130

4-Bromofluorobenzene 92 70-130

Page 40 of 49
Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1005506B-17C

MODIFIED VOST 5041A/8260B

File Name: 10060114

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 03:26 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 11

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 41 of 49
Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1005506B-17C

MODIFIED VOST 5041A/8260B

File Name: 10060114

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 03:26 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 10

1,2-Dichlorobenzene 10 10

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 79 50-150

Page 42 of 49
Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1005506B-17C

MODIFIED VOST 5041A/8260B

File Name: 10060114

Dil. Factor: 1.00

Date of Collection: 5/19/10 

Date of Analysis: 6/1/10 03:26 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 101 50-150

Toluene-d8 67 50-150

Page 43 of 49
Client Sample ID: Lab Blank

Lab ID#: 1005506B-18A

MODIFIED VOST 5041A/8260B

File Name: 10060104

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:37 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 44 of 49
Client Sample ID: Lab Blank

Lab ID#: 1005506B-18A

MODIFIED VOST 5041A/8260B

File Name: 10060104

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:37 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 100 70-130

Page 45 of 49
Client Sample ID: Lab Blank

Lab ID#: 1005506B-18A

MODIFIED VOST 5041A/8260B

File Name: 10060104

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:37 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 102 70-130

Toluene-d8 101 70-130

4-Bromofluorobenzene 92 70-130

Page 46 of 49
Client Sample ID: LCS

Lab ID#: 1005506B-19A

MODIFIED VOST 5041A/8260B

File Name: 10060103

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:13 AM

Compound %Recovery

Chloromethane 116

Vinyl Chloride 101

Bromomethane 100

Chloroethane 98

Freon 11 105

2-Chloropropane 109

1,1-Dichloroethene 100

Freon 113 116

Carbon Disulfide 124

Acetone 109

3-Chloropropene 118

Methylene Chloride 104

trans-1,2-Dichloroethene 109

Acrylonitrile 96

Hexane 114

1,1-Dichloroethane 99

Vinyl Acetate Not Spiked

2,2-Dichloropropane 99

cis-1,2-Dichloroethene 94

2-Butanone (Methyl Ethyl Ketone) 119

Bromochloromethane 95

Chloroform 98

1,1,1-Trichloroethane 99

Carbon Tetrachloride 98

1,1-Dichloropropene 104

Benzene 100

1,2-Dichloroethane 97

Trichloroethene 100

1,2-Dichloropropane 100

Dibromomethane 97

Bromodichloromethane 95

cis-1,3-Dichloropropene 99

trans-1,3-Dichloropropene 102

4-Methyl-2-pentanone 97

Toluene 97

1,1,2-Trichloroethane 96

Tetrachloroethene 100

1,3-Dichloropropane 94

2-Hexanone 129

Page 47 of 49
Client Sample ID: LCS

Lab ID#: 1005506B-19A

MODIFIED VOST 5041A/8260B

File Name: 10060103

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:13 AM

Compound %Recovery

Dibromochloromethane 95

Chlorobenzene 97

1,2-Dibromoethane (EDB) 96

Ethyl Benzene 100

m,p-Xylene 99

o-Xylene 99

Styrene 101

Bromoform 94

1,1,2,2-Tetrachloroethane 91

1,3-Dichlorobenzene 101

1,4-Dichlorobenzene 100

1,2-Dichlorobenzene 101

Cumene 117

cis-1,4-Dichloro-2-butene 86

Bromobenzene 96

1,2,3-Trichloropropane 95

trans-1,4-Dichloro-2-butene 88

Propylbenzene 100

2-Chlorotoluene 98

4-Chlorotoluene 101

1,3,5-Trimethylbenzene 101

tert-Butylbenzene 102

1,2,4-Trimethylbenzene 102

sec-Butylbenzene 103

p-Cymene 103

1,2-Dibromo-3-chloropropane 93

1,2,4-Trichlorobenzene 106

Naphthalene 98

Hexachlorobutadiene 121

1,2,3-Trichlorobenzene 107

1,1,1,2-Tetrachloroethane 100

Butylbenzene 101

Iodomethane 115

Freon 12 103

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 103 70-130

Page 48 of 49
Client Sample ID: LCS

Lab ID#: 1005506B-19A

MODIFIED VOST 5041A/8260B

File Name: 10060103

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 6/1/10 09:13 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 104 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 96 70-130

Page 49 of 49


APPENDIX F 

ANALYTICAL DATA - FUELS 

 


















APPENDIX G 

CALIBRATIONS SHEETS, CERTIFICATIONS 

 









































APPENDIX H 

PROCESS DATA