RECElVEU -- &;'EL 

AIR PLANNING SEC. 

08SEP23 PW l: 26 

STATE OF ARKANSAS 

MIKE BEEHI: 

(;OVFRNOR 

July 29,2008 

Richard Greene, Regional Administrator 

United States Environmental Protection Agency- Region 6 

1445 Ross Avenue, Suite 1200 

Mail Code 6RA 

Dallas, TX 75202-2733 

Dear Mr. Greene: 

The State of Arkansas is hereby submitting a State Implementation Plan (SIR$ to? 

address requirements for regional haze visibility protection in mandatory federal Clm I 

areas. This SIP contains the necessary measures to ensure that the tate of ~rkanss is

working toward the national goal for visibility contained in 42 U. C .C. 7491-Visibility 

protection for federal Class I areas. It fulfills requirements under 40 C.F.R. Part 51, 

Requirements for Preparation, Adoption, and Submittal of Implementation Plans, Subpart 

P- Protection of Visibility. 

The Clean Air Act (CAA) and the United States Environmental Protection 

Agency (EPA) regulations require states to submit SIPs to make "reasonable progress" in 

reducing visibility impairment in federal Class I areas resulting from anthropogenic 

pollution. The CAA, 169A(a)(l), "declares as a national goal the prevention of any 

future, and the remedying of any existing, impairment of visibility in mandatory federal 

Class I areas, where impairment results from man-made air pollution." Class I areas are 

national parks, containing more than 6,000 acres, and wilderness areas, containing more 

than 5,000 acres, which Congress has recognized as significant sites. Arkansas has two 

such areas: the Upper Buffalo Wilderness Area in the Ozark National Forest and the 

Caney Creek Wilderness Area in the Ouachita National Forest. 

The Regional Haze Rule focuses on older emission sources that have not been 

regulated under other provisions of the Clean Air Act. Such older sources that could 

contribute to visibility impairment in Class I areas may be required to install Best 

Available Retrofit Technology (BART). Regional Haze SIPs must contain such emission 

limits, schedules of compliance, and other measures as may be necessary to make 

reasonable progress toward meeting the national goal, including requiring installation, 

operation, and maintenance of BART, as determined by the State on certain existing 

stationary sources. 
The EPA Regional Haze Rule strongly encourages states to work together in 

regional partnerships to reduce haze. As a member of the Central Regional Air Planning 

Association (CENRAP), Arkansas has worked closely with Kansas, Louisiana, Iowa, 

Missouri, Nebraska, Minnesota, Oklahoma, and Texas, as well as with federal agencies, 

tribal areas, and other interested parties to improve air quality in our region and the 

country. 

The State of Arkansas hereby submits to the EPA that it has met the requirements 

for regional haze visibility protection in mandatory federal Class I areas under 40 C.F.R. 

551.308. We are enclosing two hard copies and one electronic copy of the State 

Implementation Plan for your review. 

We look forward to your prompt review of this SIP submission. If you have any 

questions, please contact Mike Bates, Air Division Chief of the Arkansas Department of 

Environmental Quality, at 5301 Northshore Drive, North Little Rock, AR 7221 8-53 17, 

or by phone at (501) 682-0750. Thank you for your attention to this matter. 

Sincerely, 

ike Beebe 

cc: Mike Bates, Chief - Air Division, Arkansas Department of Environmental Quality 

Enclosure 
Arkansas Regional Haze SIP Appendices - Volume 4 of 6 

September 09, 2008 

 

Arkansas Department of Environmental Quality 

Appendices for the 

State of Arkansas 

Regional Haze Rule 

State Implementation Plan 

Appendix Volume 4 

Appendices 9.1A -9.2C
Appendix 9.1A 

Detailed Description of BART-eligible 

Emission Units 
Subject-to-Bart Unit 

American Electric Power 

SWEPCO Flint Creek Power Plant, AFIN: 04-00107 

No. 1 Power Boiler (SN-01) 

The Flint Creek Power Plant produces power using a 6324 million BTU per hour, dry 

bottom, wall fired boiler (SN-01) to produce sufficient steam to operate the turbine 

generator at the 558 megawatt gross electrical output capability of the unit. The boiler 

burns primarily low sulfur western coal, but can also combust fuel oil and tire derived 

fuels. Fuel oil firing is only allowed during startup and shutdown of the boiler, startup 

and shutdown of the pulverizer mills, for flame stabilization when the coal is frozen, fuel 

oil tank maintenance, to prevent boiler tube failure in extreme cold weather, and when the 

unit is offline for maintenance. Fly ash resulting from the coal combustion process is 

collected by two hot side electrostatic precipitators. 

SWEPCO maintains Continuous Emissions Monitoring Systems (CEMS) for NOx, SO2, 

opacity, and carbon dioxide (CO2) on the boiler. 

Stack (Emission Point) Parameters

SN-01 

Base Elevation(1), ft 1148 

Stack Height, ft 540 

Stack Diameter, ft 20.0 

Stack Velocity, ft/sec 112 

Temperature, F° 275 

UTM Northing, km 4013.449 

UTM Easting, km 363.123 

(1) Above Sea Level

9.1A-1
Subject-to-Bart Unit 

Arkansas Electric Cooperative Corporation 

Carl E. Bailey Generating Station, AFIN: 74-00024 

Boiler (SN-01) 

The Carl E. Bailey Generating Station produces power using a 1350 million BTU per 

hour Riley Stoker boiler (SN-01) to drive a 122 megawatt generator. The primary fuel is 

natural gas but the facility is also permitted to combust fuel oil. Before BART 

determination the facility was permitted to use any grade fuel oil with a sulfur content 

equal to or below 2.3 per cent. For BART compliance the facility will be limited to 

combusting fuel oil containing a maximum of one percent sulfur by weight. There is no 

emissions control equipment connected to the boiler. 

AECC maintains Continuous Emissions Monitoring Systems (CEMS) for NOx, SO2, 

opacity, and carbon monoxide (CO) on the boiler. 

Stack (Emission Point) Parameters

SN-01 

Base Elevation(1), ft 201 

Stack Height, ft 167 

Stack Diameter, ft 9.83 

Stack Velocity, ft/sec 92.0 

Temperature, F° 340 

UTM Northing, km 3903.072 

UTM Easting, km 648.831 

(1) Above Sea Level

9.1A-2
Subject-to-Bart Unit 

Arkansas Electric Cooperative Corporation 

John L. McClellan Generating Station, AFIN: 52-00055 

Boiler (SN-01) 

The John L. McClellan Generating Station produces power using a 1436 million BTU per 

hour Riley Stoker boiler (SN-01) to drive a 134 megawatt generator. The primary fuel is 

natural gas but the facility is also permitted to combust fuel oil. Before BART 

determination the facility was permitted to use any grade fuel oil with a sulfur content 

equal to or below 2.8 per cent. For BART compliance the facility will be limited to 

combusting fuel oil containing a maximum of one percent sulfur. There is no emissions 

control equipment connected to the boiler. 

AECC maintains Continuous Emissions Monitoring Systems (CEMS) for NOx, SO2, 

opacity, and carbon monoxide (CO) on the boiler. 

Stack (Emission Point) Parameters

SN-01 

Base Elevation(1), ft 110 

Stack Height, ft 160 

Stack Diameter, ft 10.83 

Stack Velocity, ft/sec 92.0 

Temperature, F° 340 

UTM Northing, km 3713.898 

UTM Easting, km 519.310 

(1) Above Sea Level

9.1A-3
Subject-to-Bart Unit 

Entergy Arkansas, Inc. 

Lake Catherine Plant, AFIN: 30-00011 

Unit 4 Boiler (SN-03) 

Unit 4 is a Combustion Engineering tilting tangential fired 5,850 million BTU per hour 

boiler powering a 552 MW generator. The primary fuel is natural gas with No.6 fuel oil 

as the secondary fuel. This boiler came on line in 1970. There is no emissions control 

equipment connected to the boiler. 

Stack (Emission Point) Parameters

SN-01 

Base Elevation(1), ft 328 

Stack Height, ft 195 

Stack Diameter, ft 17.0 

Stack Velocity, ft/sec 10.1 

Temperature, F° 254 

UTM Northing, km 3810.324 

UTM Easting, km 508.781 

(1) Above Sea Level

9.1A-4
Bart Eligible Unit 

Entergy Arkansas, Inc. 

Ritchie Plant, AFIN: 54-00017 

Unit 2 Boiler (SN-02) 

Unit 2 Boiler is a 6,000 million BTU per hour boiler powering a 544 MW generator. The 

primary fuel is natural gas with No.6 fuel oil as the secondary fuel. The boiler is 

permitted to operate combusting natural gas only or a combination of natural gas and No. 

6 fuel oil. This boiler came on line in 1968. 

There is no emissions control equipment connected to the boiler. 

Stack (Emission Point) Parameters

SN-02 

Base Elevation(1), ft 180 

Stack Height, ft 236 

Stack Diameter, ft 12.0 

Stack Velocity, ft/sec 93.9 

Temperature, F° 242 

UTM Northing, km 3816.084 

UTM Easting, km 720.501 

(1) Above Sea Level

 

9.1A-5
Subject-to-Bart Unit 

Entergy Arkansas, Inc. 

White Bluff Plant, AFIN: 35-00110 

Units No.1 and 2 (SN-01 and SN-02) 

Units Nos. 1 and 2 are identical Combustion Engineering tilting tangential 8700 million 

BTU per hour coal fired boilers with a maximum power rating of 850 MW each. The 

boilers use sub-bituminous or bituminous coal as the primary fuel and No.2 fuel oil as a 

start-up fuel. Particulate matter is controlled by an electrostatic precipitator on each 

boiler. 

Auxiliary Boiler (SN-05) 

The Auxiliary Boiler is a 183 million BTU per hour boiler burning No. 2 fuel oil as its 

only fuel type. The original purpose of the Auxiliary Boiler was to provide steam for the 

start-up of the two primary boilers, SN-01 and SN-02. Entergy Arkansas is proposing to 

use SN-01 and SN-02 as peaking units. The Auxiliary Boiler will be used to keep the 

two primary boilers hot during the down-time periods to reduce the start-up time to a 

minimum. There is no emissions control equipment connected to the Auxiliary Boiler. 

Entergy maintains Continuous Emissions Monitoring Systems (CEMS) for NOx, SO2, 

and opacity on both primary boilers. There are no CEMS on the Auxiliary Boiler. 

Stack (Emission Point) Parameters

SN-01 SN-02 SN-05 

Base Elevation(1), ft 309 309 309

Stack Height, ft 1000 1000 15

Stack Diameter, ft 25.70 25.70 3.0

Stack Velocity, ft/sec 90.0 90.0 65.0

Temperature, F° 321 321 475

UTM Northing, km 3809.437 3809.447 3809.357

UTM Easting, km 579.101 579.101 579.113

(1) Above Sea Level

9.1A-6
 Subject-to-Bart Unit 

 

Domtar Industries, AFIN: 41-00002 

No. 1 Power Boiler (SN-03) 

The No.1 Power Boiler was installed in 1968 as part of the original construction of the 

Ashdown Mill. It has a heat input rating of 580 million BTU per hour and an average 

steam generating rate of 120,000 pounds of steam per hour (lb/hr) at 850 psig. It combust 

primarily bark, but it is also permitted to burn wood chips, wood waste, recycled sanitary 

products composed of cellulose and polypropylene, pelletized paper fuel (PPF), tirederived fuel (TDF), municipal yard waste, No. 6 fuel oil, reprocessed fuel oil, used oil 

generated on site, and natural gas. Natural gas is only used to supplement other fuels 

during high steam demand periods. 

The No.1 Power Boiler is equipped with a traveling grate and a combustion air system. 

To meet applicable Boiler MACT PM emissions standard of 0.07 lb/MMBTU Domtar 

Industries installed a wet electrostatic precipitator (WESP) during the spring of 2007. 

No. 2 Power Boiler (SN-05) 

The No. 2 Power Boiler started operation in February 1976. It has a heat input rating of 

820 million BTU per hour and an average steam generating rate of approximately 

600,000 lb/hr. It combust primarily bituminous coal (over 80 percent of the heat input is 

supplied by coal), but it is also permitted to burn bark, bark and wood chips used to 

absorb oil spills, wood waste, petroleum coke, recycled sanitary products based on 

cellulose and polypropylene, PPF, TDF, municipal waste, No. 6 fuel oil, reprocessed fuel 

oil, used oil generated on site, natural gas, and non-condensable gases (NCGs). The 

NCGs are produced in the pulp and evaporator areas. It consist of nitrogen, total reduced 

sulfur (TRS) compounds, methanol, SO2, and minor quantities of other compounds such 

as methyl ethyl ketone (MEK). Under normal conditions, natural gas is not combusted. 

The No.2 Power Boiler is equipped with a traveling grate, combustion air system 

including overfire air, multiclones, and two parallel venture scrubbers. The SO2 loading 

to the boiler is significant since the boiler burns coal and NCGs. Therefore, the 

scrubbing fluid includes water and a source of alkali, such as Sodium hydroxide (NaOH) 

and/or pulp mill extraction stage filtrate. 

The No. 2 Power Boiler is equipped with Continuous Emissions Monitoring Systems 

(CEMS) for NOX, SO2, and carbon monoxide (CO). 

Stack (Emission Point) Parameters

SN-03 SN-05 

Base Elevation(1), ft 320 320

Stack Height, ft 217 235

Stack Diameter, ft 6.2 12.0

Stack Velocity, ft/sec 87.8 39.1

Temperature, F° 480 125

UTM Northing, km 3722.716 3722.640

UTM Easting, km 396.754 396.759

(1) Above Sea Level 

9.1A-7
Bart Eligible Unit 

Delta Natural Kraft and Mid-America Packaging, LLC 

Pine Bluff Plant, AFIN: 35-00017 

Recovery Boiler (SN-02) 

The Recovery Boiler is a 100 million BTU per hour boiler used to produce steam for 

various heat requiring processes throughout the plant. The primary fuel is black liquor, a 

by-product of the pulping process. Natural gas is used as a secondary fuel. 

The boiler is equipped with a scrubber to control emissions of sulfur compounds and an 

electrostatic precipitator to control particulate matter (PM) emissions. 

Delta Natural Kraft maintains a Continuous Emissions Monitoring System (CEMS) for 

Total Reduced Sulfur (TRS) on this recovery boiler. 

Stack (Emission Point) Parameters

SN-02 

Base Elevation(1), ft 218 

Stack Height, ft 165 

Stack Diameter, ft 7.0 

Stack Velocity, ft/sec 43.6 

Temperature, F° 166 

UTM Northing, km 3791.866 

UTM Easting, km 589.735 

(1) Above Sea Level

9.1A-8
Bart Eligible Unit 

Evergreen Packaging Inc. 

Pine Bluff Plant, AFIN: 35-00016 

#4 Recovery Boiler (SN-04) 

The #4 Recovery Boiler is a 1,085 million BTU per hour boiler used to produce steam for 

various heat requiring processes throughout the plant. The #4 Recovery Boiler burns 

black liquor solids, a by-product of the pulping process, as its primary fuel. The boiler 

also has the capacity to burn natural gas and No. 6, 5, 4, and 2 fuel oils with a sulfur 

content not to exceed 1%. Black liquor solids and fuel oil are not permitted to be burned 

simultaneously. The #4 Recovery Boiler was built in 1968. 

The boiler is equipped with an electrostatic precipitator to control particulate matter (PM) 

emissions. 

 Evergreen Packaging maintains a Continuous Emissions Monitoring System (CEMS) for 

Total Reduced Sulfur (TRS) on this recovery boiler. 

Stack (Emission Point) Parameters

SN-04 

Base Elevation(1), ft 207

Stack Height, ft 275

Stack Diameter, ft 8.5

Stack Velocity, ft/sec 58.5

Temperature, F° 305

UTM Northing, km 3787.135

UTM Easting, km 600.660

(1) Above Sea Level 

9.1A-9
Bart Eligible Unit 

Georgia-Pacific LLC – Crossett Paper Operations 

AFIN: 02-00013 

6A Boiler (SN-19) 

The 6A Boiler (SN-19) is a 357 million BTU per hour boiler. The boiler burns natural 

gas and specification grade oil. Specification grade oil consists of new oil, used oil, and 

pitch from the production of tall oil. The boiler was installed in 1962. 

There are no emissions controls associated with the boiler.

9A Boiler (SN-22) 

The 9A Boiler is a 720 million BTU per hour combination fuel boiler that is used to 

generate steam for general use throughout the facility. The boiler may serve as a backup 

combustion unit when the incinerator (SN-83) is offline. The boiler was installed in 1973. 

 

The combination of fuels permitted for the boiler are tire derived fuel (TDF), agriculture 

derived fuel (ADF), refuse derived fuel (RDF), non-condensable gases (NCGs), 

woodwaste, specification grade oil, natural gas, and sludge. 

The 9A Boiler is equipped with a wet venturi scrubber to control sulfur compound 

emissions. The scrubber was installed in 1980. 

Georgia-Pacific maintains a Continuous Emissions Monitoring System (CEMS) for 

carbon monoxide (CO) on Boiler 9A. 

Stack (Emission Point) Parameters

SN-19 SN-22 

Base Elevation(1), ft 148 151

Stack Height, ft 140 175

Stack Diameter, ft 13.46 12.0

Stack Velocity, ft/sec 39.7 34.3

Temperature, F° 832 155

UTM Northing, km 3667.358 3667.526

UTM Easting, km 596.129 596.143

(1) Above Sea Level

9.1A-10
Bart Eligible Unit 

Green Bay Packaging Inc. – Arkansas Kraft Division 

AFIN: 15-00001 

Recovery Boiler (SN-05A) 

The Recovery Boiler is a 730 million BTU per hour boiler used to produce steam for 

various heat requiring processes throughout the plant. The primary fuel is black liquor, a 

by-product of the pulping process. Natural gas is used as a secondary fuel. The boiler 

was installed in 1975. 

The boiler is equipped with an electrostatic precipitator (ESP) to control particulate 

matter (PM) emissions. 

Green Bay Packaging maintains Continuous Emissions Monitoring Systems (CEMS) for 

Total Reduced Sulfur (TRS) and oxygen (O2) concentration on the recovery boiler. 

Stack (Emission Point) Parameters

SN-05A 

Base Elevation(1), ft 323

Stack Height, ft 101

Stack Diameter, ft 5.9

Stack Velocity, ft/sec 84.0

Temperature, F° 362

UTM Northing, km 3883.622

UTM Easting, km 523.874

(2) Above Sea Level 

9.1A-11
Bart Eligible Unit 

Potlatch forest Products Corporation – Cypress Bend Mill 

AFIN: 21-00036 

Power Boiler (SN-04) 

The Power Boiler is a 479 million BTU per hour boiler using natural gas as the primary 

fuel and fuel oil as a secondary fuel. The steam from this unit is used to co-generate 

electricity in the turbine generator and to provide steam for various mill processes. The 

boiler was installed in 1977. 

There are no emissions controls associated with the boiler.

Potlatch maintains a CEMS to monitor and record the NOX and CO2 emissions when the 

boiler is operating with either fuel. A Continuous Opacity Monitoring System (COMS) 

and CEMS for SO2 are required when the boiler is operating on fuel oil. The CEMS 

eliminate the requirement to limit the fuel oil type and sulfur content. 

Stack (Emission Point) Parameters

SN-04 

Base Elevation(1), ft 144 

Stack Height, ft 2994 

Stack Diameter, ft 9.0 

Stack Velocity, ft/sec 48.5 

Temperature, F° 340 

UTM Northing, km 3730.970 

UTM Easting, km 663.260 

(1) Above Sea Level

9.1A-12
Bart Eligible Unit 

Lion Oil Co. 

AFIN: 70-00016 

#7 Catalyst Regenerator (SN-809) 

In the #7 Fluid Catalytic Cracking Unit (FCCU) crude oil is heated to 675°F. The hot 

crude oil is then contacted with a hot (approximately 1350°F) fluidized catalyst which 

causes the gas oil to crack into lighter petroleum products. The catalyst is separated from 

the products in the reactor and sent to the regenerator. In the regenerator, coke which has 

deposited on the catalyst is burned off and the catalyst is recycled. The hot flue gas is 

passed through a series of cyclones to remove catalyst fines and then the hot gas is used 

to produce steam in the waste heat boiler. The hot gases are cooled in the boiler to less 

than 500°F before passing through the scrubber and exiting through the #7 Catalyst 

Regenerator Stack (SN-809). 

The FCCU Catalyst Regenerator Stack was equipped in 2004 with a wet gas scrubber 

(WGS) for the control of SO2, O2, and CO emissions. 

Lion Oil maintains CEMS to monitor and record the SO2, O2 and CO emissions of the 

Catalyst Regenerator Stack. 

Stack (Emission Point) Parameters

(SN-809) 

Base Elevation(1), ft 148 

Stack Height, ft 200 

Stack Diameter, ft 5.75 

Stack Velocity, ft/sec 32.0 

Temperature, F° 500 

UTM Northing, km 3673.684 

UTM Easting, km 530.339 

(1) Above Sea Level

9.1A-13
Bart Eligible Unit 

Big River Industries 

AFIN: 18-00082 

Kiln A (SN-01) 

Big River Industries, formally General Shale Products, LLC, operates a lightweight 

aggregate facility in West Memphis, Arkansas. Locally mined clay is stockpiled during 

the summer months and moved to covered storage areas before processing. Kiln A (SN01) is a coal-fired rotary kiln that maintains a temperature of approximately 2,200°F. The 

clay is transferred to the elevated end of the kiln by a system of conveyors and it tumbles 

to the discharge end where it exits as aggregate. The kiln was installed in 1975. 

The discharge gases are processed through a wet scrubber. 

Stack (Emission Point) Parameters

(SN-01) 

Base Elevation(1), ft 197 

Stack Height, ft 100 

Stack Diameter, ft 5.0 

Stack Velocity, ft/sec 71.8 

Temperature, F° 134 

UTM Northing, km 3888.519 

UTM Easting, km 746.849 

(1) Above Sea Level

9.1A-14
Bart Eligible Unit 

Albermarle Corporation – South plant 

AFIN: 14-00028 

Tail Gas Incinerator (SR-01) 

Acid gas from the Gas Sweetening Plant is sent to a sulfur recovery plant where 93% of 

the sulfur is removed from the acid (sour) gas. This sour gas along with the exhaust from 

the diethylchlorothiophosphate (DECTP) process scrubber vent is burned in the Tail Gas 

Incinerator (SR-01). The tail gas incinerator is designed for a minimum exhaust 

temperature of 1200°F. 

Boiler #1 (BH-01) and Boiler #2 (BH-02) 

There are two boilers at the Albemarle South facility. Each boiler has the capacity to 

produce 200,000 pounds of 225 psig steam per hour. This is equivalent to a heat input of 

340 million BTU per hour. The boilers burn natural gas, which has been treated either in 

the sulfinol or the MDEA plants. They may also burn pipeline quality natural gas. They 

are not permitted to burn any other fuel. 

Emissions generated by the two boilers are permitted under a single bubble. 

Stack (Emission Point) Parameters

SR-01 BH-01 BH-02 

Base Elevation(1), ft 285 290 290

Stack Height, ft 190 21 21

Stack Diameter, ft 2.67 8.5 8.5

Stack Velocity, ft/sec 50.0 30.0 30.0

Temperature, F° 1200 450 450

UTM Northing, km 3670.700 3670.758 3670.757

UTM Easting, km 479.964 479.823 479.806

(1) Above Sea Level

9.1A-15
Bart Eligible Unit 

FutureFuel Chemical Company 

AFIN: 32-00036 

Coal Boilers, 3ea. (6M01-01) 

The three coal fired boilers are balanced draft, coal-fired steam generation boilers that 

have been fitted with atomizing nozzles to facilitate burning of liquid chemical wastes. 

Each coal fired boiler system is designed as a 70 million BTU per hour unit. The three 

coal fired boilers share a common primary fuel conveying system, a common ash 

handling system, and a common 200 foot tall stack. The boilers are independently 

controlled by a Distributed Control System (DCS). All interactions from the operator to 

the burners are made through this computer system. The three coal fired boilers were 

installed in 1975. 

The spent solvent from the 2,000 gallon liquid waste process tank is routed to either the 

coal-fired boiler auxiliary waste chemical burners or to the burner of the chemical waste 

destructor (6M03-05). Emissions from tank venting are collected and routed to the coalfired boilers (6M01-01). 

Each boiler is equipped with its own electrostatic precipitator (ESP) to control particulate 

emissions. 

Stack (Emission Point) Parameters

(6M01-01) 

Base Elevation(1), ft 270

Stack Height, ft 200

Stack Diameter, ft 9.0

Stack Velocity, ft/sec 31.0

Temperature, F° 300

UTM Northing, km 3953.681

UTM Easting, km 633.332

(1) Above Sea Level

9.1A-16
Bart Eligible Unit 

El Dorado Chemical Company 

AFIN: 70-00040 

West Nitric Acid Plant (SN-08) and East Nitric Acid Plant (SN-09) 

The East and West Regular Nitric Acid Plants produce weak nitric acid at concentrations 

ranging from 52% to 58%. These nitric acid plants employ the DuPont single (high) 

pressure process. 

 

Liquid ammonia (NH3) is received from a pipeline and placed in pressurized storage at a 

pressure of 65 psig, or in an atmospheric storage tank. Ambient air is compressed and 

preheated to approximately 125 psig and 475 o F. A mixture of approximately ten percent 

ammonia and the hot air are reacted over a platinum gauze catalyst where the ammonia is 

oxidized to nitrogen oxide(s) and water vapor. The nitrogen oxides are then absorbed 

into water in a cooled absorption process forming nitric acid (HNO3). 

Nitrogen oxide emissions from these plants are then passed through Selective Catalytic 

Reduction (SCR) Units. These SCR Units remove most of the remaining nitrogen oxides 

by reacting them with ammonia in the presence of a catalyst to form elemental nitrogen 

and water. The tail gases are then vented to the atmosphere. 

The East and West Nitric Acid Plants were built in 1962. The SCR control equipment 

was installed in 1996. 

Nitric Acid Concentrator (SN-10) 

The Nitric Acid Concentrator (SN-10) uses concentrated sulfuric acid as a dehydrating 

agent to remove water from the weak acid nitric acid. The use of a dehydrating agent is 

necessary since nitric acid forms an azeotrope with water at approximately 70% 

concentration so concentrated nitric acid cannot be produced by using normal distillation. 

Sulfuric acid at 93% concentration and nitric acid at 62% concentration are fed to a 

distilling tower. Nitric acid at 98%+ concentration distills out the top and sulfuric acid at 

70% concentration exits the bottom of the distillation tower. 

Emissions from the process are controlled by a hydrogen peroxide scrubber and a venture 

and packed tower scrubber. These two scrubbers are part of the Nitric Acid Vent 

Collection System (SN-10). 

Stack (Emission Point) Parameters

SN-08 SN-09 SN-10 

Base Elevation(1), ft 207 207 204

Stack Height, ft 75 75 78

Stack Diameter, ft 4.0 4.0 0.5

Stack Velocity, ft/sec 110 105 78.0

Temperature, F° 450 440 103

UTM Northing, km 3680.940 3680.940 3680.914

UTM Easting, km 528.761 528.777 528.838

(1) Above Sea Level

9.1A-17
Appendix 9.1B 

Method of Identifying BART-Eligible Sources in the 

State of Arkansas 
Method of Identifying BART-Eligible Sources in the State of Arkansas 

The Air Division of ADEQ began the development of BART-eligible sources by 

searching the Air Divisions data base for facilities that fit into one of the 26 BART source 

categories (Table 9.1B-1). The original list of possible-BART facilities was compiled of 

those that had the potential to emit 250 or more tons per year (tpy) of the following 

visibility impairing pollutants, sulfur dioxide (SO2), nitrogen oxides (NOX), particulate 

matter equal to or smaller than ten microns (PM10), volatile organic compounds (VOC) or 

ammonia (NH3). These facilities were listed in an Excel spreadsheet along with the name 

and source number of their possible BART-eligible units. The potential to emit 

emissions of the five above listed pollutants were also listed. (See Table 9.1B-2) 

The units listed as “in operation” before August 7, 1962 were classified as pre-BART and 

those that were not “in existence” on August 7, 1977 were classified as post-BART. The 

BART-eligible units were those not “in operation” on August 17, 1962 but were “in 

existence” on August 7, 1977. 

The term “in operation” means engaged in activity related to the primary design function 

of the source. ADEQ interprets this as the source is physically performing the task for 

which it was designed. 

The term “in existence” means that the owner or operator had obtained all necessary 

preconstruction approvals or permits. The owner or operator had either (1) begun or 

caused to begun, a continuous program of physical on-site construction of the facility, or 

(2) entered into binding agreements or contractual obligations. 

In 2004 the Environmental Protection Administration (EPA) removed ammonia from the 

list of visibility-impairing pollutants. The reasoning for the removal of ammonia was the 

complexity and variability of ammonia’s roll in the formation of PM2.5 in the atmosphere. 

Also, ammonia is the reduction agent used in Selective Catalytic Reduction (SCR) type 

NOx emissions control equipment that converts NOx to nitrogen and water. 

ADEQ did not use VOC emissions from facilities for subject-BART analysis. Only 

specific VOC compounds from secondary organic aerosols affect visibility. These 

compounds are a fraction of the total VOCs reported in the emissions inventory, and 

ADEQ does not have the breakdown of VOC emissions necessary to model those that 

only impair visibility. Further, the prescribed screening model (CALPUFF) cannot 

simulate formation of particles from anthropogenic VOCs, nor their visibility impact.

9.1B-1
Table 9.1B-1: BART Categories 

BART 

Category ID BART Category BART Subcategory 

BART-01 Fossil fuel-fired steam electric plants > 250 MMBTU per hour 

BART-02 Coal Cleaning Plants (thermal dryers) Thermal Dryers 

BART-03 Kraft Pulp Mills 

BART-04 Portland Cement Plants 

BART-05 Primary Zinc Smelters 

BART-06 Iron and Steel Mill Plants 

BART-07 Primary Aluminum Ore Reduction Plants 

BART-08 Primary Copper Smelters 

BART-09 Municipal Incinerators Capable of Charging > 250 tons of Refuse Per Day 

BART-10 Hydrofluoric, Sulfuric, and Nitric Acid Plants 

BART-11 Petroleum Refineries 

BART-12 Lime Plants 

BART-13 Phosphate Rock Processing Plants 

BART-14 Coke Oven Batteries 

BART-15 Sulfur Recovery Plants 

BART-16 Carbon Black Plants Furnace Process 

BART-17 Primary Lead Smelters 

BART-18 Fuel Conversion Plants 

BART-19 Sintering Plants 

BART-20 Secondary Metal Production Facilities 

BART-21 Chemical Process Plants 

BART-22 Fossil fuel-fired boilers > 250 MMBTU per hour 

BART-23 Petroleum Storage and Transfer Facilities with a Capacity > 300,000 Barrels 

BART-24 Taconite Ore Processing Plants 

BART-25 Glass Fiber Processing Plants 

BART-26 Charcoal Production Facilities 

9.1B-2
POTENTIAL BART SOURCES LOCATED IN ARKANSAS

POLLUTANTS (TONS PER YEAR FOR CY 2001) PER UNIT

NH3 NOX PM10 SO2 VOCs D

IN 

AIRS E

STATIONARY EMISSION EMISSION UNIT CATEGORY 8

STATIONARY SOURCE NAME/LOCATION SOURCE ID 2-DIGIT SIC UNIT ID DESCRIPTION CODE POTENTIAL ACTUAL POTENTIAL ACTUAL POTENTIAL ACTUAL POTENTIAL ACTUAL POTENTIAL ACTUAL

Albermarle-South Plant / Magnolia 05-027-00028 28 SR-01 Tail Gas Incin. 15 2.6 2.6 0.3 0.3 3,184.0 900.5 0.3 0.3 yAlbermarle-South Plant / Magnolia 05-027-00028 28 BH-01 & 02 Boilers 1 & 2 21 417.0 26.2 149.0 1.4 24.5 3.2 8.4 0.5 y

American Elect. Power (SWEPCO) / Gentry 05-007-00107 49 SN-01 Boiler 1 16,379.0 5,682.3 2,340.0 125.8 28,078.0 14,531.2 92.0 69.3 y

Ark. Elect. Coop - Bailey Plant / Augusta 05-147-00024 49 SN-01 Boiler, 1350mm 1 3,069.0 324.2 572.0 202.4 7,118.0 1,560.0 41.2 9.1 yArk. Elect. Coop - Fitzhugh / Ozark 05-047-00012 49 SN-06 Turbine 1 447.0 n

Ark. Elect. Coop - McClellan Plant / Camden 05-103-00055 49 SN-01 Boiler 1 3,806.0 464.4 607.0 224.7 9,219.0 2,369.1 43.8 10.0 y

Arkansas Lime Co. / Batesville 05-063-00014 32 SN-11Q Lime Kiln 12 399.2 374.6 31.6 10.8 226.6 50.0 nAsh Grove Cement / Foreman 05-081-00001 32 SN-P1 Kiln #1 4 2,400.0 912.7 85.4 76.2 1,960.0 290.2 42.1 25.1 y

Ash Grove Cement / Foreman 05-081-00001 32 SN-P2 Kiln #2 4 2,453.0 993.0 85.4 73.9 1,686.0 270.6 42.1 24.8 y

Ash Grove Cement / Foreman 05-081-00001 32 SN-P3 Kiln #3 4 4,231.0 1,368.7 118.3 105.1 2,089.0 196.8 57.0 34.1 y

Columbian Chemical / E Dorado 05-139-00014 28 SN-23 Boiler & Dryers 16 178.0 82.0 5.3 3.0 1,672.0 513.0 23.0 3.0 n

Columbian Chemical / E Dorado 05-139-00014 28 SN-37 Thermal Oxidizer 16 608.0 377.0 17.9 6.0 5,690.0 1,151.0 78.0 7.0 n

Domtar, Inc. / Ashdown 05-081-00002 26 SN-01 #3 Power Boiler 3 1,038.1 523.7 86.5 61.3 271.6 37.3 93.3 5.0 n

Domtar, Inc. / Ashdown 05-081-00002 26 SN-02 #3 Lime Kiln 3 291.7 72.1 37.7 2.1 58.3 12.0 63.9 6.8 nDomtar, Inc. / Ashdown 05-081-00002 26 SN-03 #1 Power Boiler 3 1,085.9 275.3 1,504.1 711.0 214.0 128.5 214.6 4.5 y

Domtar, Inc. / Ashdown 05-081-00002 26 SN-05 #2 Power Boiler 3 2,514.1 1,796.3 359.2 188.9 4,305.5 2,433.5 206.5 61.1 y

Domtar, Inc. / Ashdown 05-081-00002 26 SN-06 #2 Rec. Boiler 3 1,354.3 499.8 369.7 106.0 1,252.7 37.0 204.6 43.4 n

Domtar, Inc. / Ashdown 05-081-00002 26 SN-09 #2 Lime Kiln 3 300.5 31.8 223.4 81.6 73.2 5.9 74.9 7.2 nDomtar, Inc. / Ashdown 05-081-00002 26 SN-14 #3 Rec. Boiler 3 1,182.6 580.6 409.5 77.9 1,861.5 33.1 600.1 14.7 n

Domtar, Inc. / Ashdown 05-081-00002 26 SN-22 Brownstock Vent 3 259.1 197.0 nEastman Chemical / Batesville 05-063-00036 28 6M01-01 3 Coal Boilers 21 488.2 488.2 205.3 205.3 6,213.8 6,213.8 2.3 2.3 y

El Dorado Chemical / El Dorado 05-139-00040 28 SN-07 Sulfuric Acid Plan 10 2,520.0 1,057.0 y

El Dorado Chemical / El Dorado 05-139-00040 28 SN-08 W. Nitric Acid Plan 10 840.0 507.0 y

El Dorado Chemical / El Dorado 05-139-00040 28 SN-09 E. Nitric Acid Plan 10 840.0 372.0 yEl Dorado Chemical / El Dorado 05-139-00040 28 SN-10 Nitric Acid Consen 10 314.5 8.5 yEl Dorado Chemical / El Dorado 05-139-00040 28 SN-16A #2 Boiler 10 349.5 212.0 4.0 2.0 0.4 0.3 1.1 0.7 yEntergy - Blytheville 05-093-00113 49 SN-01 Turbine 1 1 265.7 y

Entergy - Blytheville 05-093-00113 49 SN-02 Turbine 2 1 265.7 y

Entergy - Blytheville 05-093-00113 49 SN-03 Turbine 3 1 265.7 y

Entergy - Couch Plant / Stamps 05-073-00004 49 SN-01 Unit 1 1 272.8 38.0 2.7 0.7 19.3 0.4 1.1 y

Entergy - Couch Plant / Stamps 05-073-00004 49 SN-02 Unit 2 1 1,780.0 96.0 17.5 1.7 69.0 0.4 7.3 3.0 y

Entergy - Independence / Newark 05-063-00042 49 SN-01 Coal Boiler #1 1 26,674.2 7,792.0 284.7 19.0 35,438.6 11,186.0 153.3 117.0 n

Entergy - Independence / Newark 05-063-00042 49 SN-02 Coal Boiler #2 1 26,674.2 10,139.0 284.7 20.0 35,438.6 11,830.0 153.3 119.0 n

Entergy - Independence / Newark 05-063-00042 49 SN-05 Aux. Boiler 1 464.0 5.2 2.6 1.0 0.5 16.0 1.2 0.0 n

Entergy - Independence / Newark 05-063-00042 49 SN-06 Feed Conveyor 1 706.5 579.0 n

Entergy - Lake Catherine / Jones Mill 05-059-00011 49 SN-01 Unit 1Boiler 1 1,669.0 107.0 9.1 0.9 2.0 0.2 4.3 2.0 yEntergy - Lake Catherine / Jones Mill 05-059-00011 49 SN-01 Unit 2 Boiler 1 1,669.0 123.0 9.1 0.9 2.0 0.2 4.3 2.0 y

Entergy - Lake Catherine / Jones Mill 05-059-00011 49 SN-02 Unit 3 Boiler 1 2,764.0 92.0 15.4 1.7 4.4 0.3 7.1 2.0 y

Entergy - Lake Catherine / Jones Mill 05-059-00011 49 SN-03 Unit 4 Boiler 1 14,016.0 1,414.0 72.0 22.0 14.4 4.3 37.9 40.0 y

Entergy - Moses Plant / Forrest City 05-123-00010 49 SN-01 Unit 1 1 993.2 36.0 78.2 0.6 478.4 0.1 3.4 1.0 yEntergy - Moses Plant / Forrest City 05-123-00010 49 SN-02 Unit 2 1 993.2 27.0 78.2 0.5 478.4 0.1 3.4 1.0 yEntergy - Ritchie Plant / Helena 05-107-00017 49 SN-01 Unit 1 1 13,140.0 182.0 86.6 2.5 819.6 0.5 20.0 5.0 y

Entergy - Ritchie Plant / Helena 05-107-00017 49 SN-02 Unit 2 1 7,884.0 3.0 132.7 0.2 1,173.1 0.1 35.0 0.0 y

Entergy - White Bluff / Redfield 05-069-00110 49 SN-01 Unit 1 1 26,674.2 7,452.0 284.7 16.0 45,727.2 16,182.0 153.3 97.0 y

Entergy - White Bluff / Redfield 05-069-00110 49 SN-02 Unit 2 1 26,674.2 10,725.0 284.7 19.0 45,727.2 20,516.0 153.3 113.0 y

Entergy - White Bluff / Redfield 05-069-00110 49 SN-05 Aux Boiler 1 140.5 3.2 5.9 1.0 420.1 9.4 1.2 0.0 yGaylord Container / Pine Bluff 05-069-00017 26 SN-02 Recovery Boiler 3 67.9 55.9 122.0 13.9 92.7 2.5 1,638.9 489.0 y

General Shale Products / W. Memphis 05-035-00082 19 SN-01 Kiln A 19 294.8 197.3 131.4 78.6 237.4 151.5 10.6 2.3 yGeorgia-Pacific Paper / Crossett 05-003-00013 26 SN-03 10A Boiler 3 2,192.2 684.0 438.4 246.0 92.0 47.9 661.4 344.0 y

Georgia-Pacific Paper / Crossett 05-003-00013 26 SN-18 5A Boiler 3 403.0 92.8 125.6 0.3 2,413.4 0.1 14.2 0.3 y

Georgia-Pacific Paper / Crossett 05-003-00013 26 SN-19 6A Boiler 3 722.7 178.0 262.8 3.8 4,345.0 18.0 12.0 0.6 y

Georgia-Pacific Paper / Crossett 05-003-00013 26 SN-22 9A Boiler 3 1,511.1 987.0 394.2 112.0 2,601.7 1,700.0 217.7 142.0 y

Georgia-Pacific Paper / Crossett 05-003-00013 26 SN-26 8R Boiler 3 832.2 724.0 407.3 45.0 1,314.0 1,230.0 172.5 161.0 nGreat Lakes Chemical / El Dorado 05-139-00012 28 SN-301A Boiler, 150mm 21 361.4 13.4 3.5 1.8 525.6 0.1 3.5 0.7 yGreat Lakes Chemical / El Dorado 05-139-00012 28 SN-302A Boiler, 113mm 21 272.5 13.1 2.7 1.3 25.0 0.2 0.9 0.7 y

Great Lakes Chemical-West Plant / El Dorado 05-139-00101 28 SN-102&20 #2 Boiler&Flare 21 29.0 28.5 2.3 1.8 312.0 0.0 3.2 2.7 nGreen Bay Packaging / Morrilton 05-029-00001 26 SN-04 #3 Wood Boiler 3 521.0 436.4 145.0 145.5 42.0 35.2 98.7 82.7 n

Green Bay Packaging / Morrilton 05-029-00001 26 SN-05 & 06 Recovery Boiler 3 206.0 537.9 910.0 637.9 494.0 1,786.1 61.0 63.2 yGreen Bay Packaging / Morrilton 05-029-00001 26 SN-25A Paper Machine 3 339.8 261.8 y

Green Bay Packaging / Morrilton 05-029-00001 26 SN-25B Paper Machine 3 270.1 208.0 n

International Paper / Pine Bluff 05-069-00016 26 SN-01 Bark Boiler 3 894.5 191.6 526.0 57.7 219.0 6.3 447.0 24.8 nInternational Paper / Pine Bluff 05-069-00016 26 SN-02 #2 Rec. Boiler 3 458.6 180.0 202.0 122.3 876.0 531.9 153.3 6.7 nInternational Paper / Pine Bluff 05-069-00016 26 SN-03 #3 Rec. Boiler 3 545.0 187.5 240.0 141.4 876.0 516.1 153.3 1.1 n

International Paper / Pine Bluff 05-069-00016 26 SN-04 #4 Rec. Boiler 3 795.0 217.6 350.8 274.8 2,376.2 1,861.9 389.8 23.6 y

International Paper / Pine Bluff 05-069-00016 26 SN-13 #1 Power Boiler 3 1,489.0 619.5 56.9 24.7 746.0 600.7 6.4 2.8 y

International Paper / Pine Bluff 05-069-00016 26 SN-15 #2 Power Boiler 3 1,489.0 695.9 56.9 26.0 746.0 628.0 6.4 3.0 y

International Paper / Pine Bluff 05-069-00016 26 SN-21 Black Liquor Ox. T 3 873.2 486.3 n

International Paper / Pine Bluff 05-069-00016 26 SN-22,23,24Pulping Area 3 349.5 251.8 n

International Paper / Pine Bluff 05-069-00016 26 SN-41, 42 Off Mach. Coater 3 27.7 7.0 3.1 0.8 0.2 0.1 361.3 251.8 nInternational Paper / Pine Bluff 05-069-00016 26 SN-54 #2 Paper Mach. 3 278.5 223.7 nLion Oil / El Dorado 05-139-00016 29 SN-809 #7 Calalyst Regen 11 2.3 260.1 178.7 329.4 230.1 1,945.3 691.8 805.1 1.9 y

Longview Gas / Stamps 05-073-00005 13 SN-04 Sulfur Rec. Unit 15 1.7 0.5 0.2 0.1 938.6 613.0 0.1 0.1 n
POLLUTANTS (TONS PER YEAR FOR CY 2001) PER UNIT

NH3 NOX PM10 SO2 VOCs D

IN 

AIRS E

STATIONARY EMISSION EMISSION UNIT CATEGORY 8

STATIONARY SOURCE NAME/LOCATION SOURCE ID 2-DIGIT SIC UNIT ID DESCRIPTION CODE POTENTIAL ACTUAL POTENTIAL ACTUAL POTENTIAL ACTUAL POTENTIAL ACTUAL POTENTIAL ACTUALNucor Steel / Hickman 05-093-00233 33 SN-01 EAF Baghouse 6 1,061.3 233.8 162.1 9.2 416.1 190.5 183.1 32.6 n

Nucor-Yamato Steel / Blytheville 05-093-00202 33 SN-01 EAF Baghouse 6 749.0 355.0 108.2 3.9 295.7 102.0 256.2 111.0 n

Nucor-Yamato Steel / Blytheville 05-093-00202 33 SN-03 LMF Baghouse 6 153.3 16.7 40.2 13.1 394.2 295.0 21.9 15.6 nNucor-Yamato Steel / Blytheville 05-093-00202 33 SN-04 Beam Reheat 6 297.8 121.0 29.4 18.5 1.1 0.8 9.6 6.6 nPotlatch Corp. / McGehee 05-041-00036 26 SN-02 Rec. Boiler 3 651.6 446.3 208.5 129.4 164.8 17.5 38.1 6.3 nPotlatch Corp. / McGehee 05-041-00036 26 SN-04 Power Boiler 3 419.6 297.0 209.8 6.7 28.7 0.8 3.1 2.3 yPotlatch Corp. / McGehee 05-041-00036 26 SN-10 Brown Stack Was 3 658.7 50.1 y

Potlatch Corp. / McGehee 05-041-00036 26 SN-15 Digesters 3 288.6 58.7 nQuanex Corp (MacSteel) / Fort Smith 05-131-00274 33 SN-01 EAF 6 161.0 72.6 100.0 4.5 332.0 94.5 41.0 20.1 nTerra Nitrogen / Blytheville 05-093-00012 28 SN-01 #1 Packg. Boiler 21 282.1 13.6 2.6 0.1 1.5 0.2 0.9 0.1 yTerra Nitrogen / Blytheville 05-093-00012 28 SN-02 #2 Packg. Boiler 21 375.8 134.8 3.5 0.8 4.4 1.8 1.3 1.0 yTerra Nitrogen / Blytheville 05-093-00012 28 SN-03 Reformer Furnace 21 1,806.7 485.2 31.5 2.8 8.6 6.6 6.2 3.6 y

Terra Nitrogen / Blytheville 05-093-00012 28 SN-07 CO2 Vent 21 624.2 29.3 60.1 4.7 y

Terra Nitrogen / Blytheville 05-093-00012 28 SN-12A,B,CUrea Granulation 21 876.0 103.4 166.4 23.0 y

Terra Nitrogen / Blytheville 05-093-00012 28 SN-13 Urea Boiler 21 259.3 47.5 17.5 1.4 13.1 3.1 4.8 1.7 nTerra Nitrogen / Blytheville 05-093-00012 28 SN-14 Urea Production 21 1,292.1 85.9 yU. S. Vanadium / Hot Springs 05-051-00002 33 SN-12 MVO Product Ven 21 832.0 574.0 2.8 0.7 17.5 11.2 1.0 0.0 y

Williams Refining / W. Memphis 05-035-00120 51 SN-22 Barge Loading 23 480.3 26.7 y

Eastman Chemical name changed to FutureFule ChemicalGeneral Shale Products name changed to Big River IndustriesEntergy - Independence, Previously and erroneously listed as BART International Paper/Pine Bluff name changed to Evergreen PackagingTerra Nitrogen out of Business, Permit Voided 11/19/2004Entergy-Blytheville, Permit Voided 12/02/2000
Appendix 9.2A 

Modeling Protocol Used to Determine 

Subject-to-BART Sources 
STATE OF ARKANSAS 

DEPARTMENT OF ENVIRONMENTAL QUALITY 

8001 NATIONAL DRIVE 

P.O. BOX 8913 

LITTLE ROCK, ARKANSAS 72219-8913 

PHONE: (501) 682-0744 

FAX: (501) 682-0753

Draft 

BEST AVAILABLE RETROFIT 

TECHNOLOGY (BART) 

MODELING PROTOCOL 

June 7, 2006 

Prepared by: 

Mary Pettyjohn, Senior Epidemiologist 

Planning and Air Quality Analysis Branch 

Air Division 

 
ii 

Table of Contents 

 List of Figures..................................................................................................... iii 

 List of Tables ...................................................................................................... iv 

 I. Introduction...........................................................................................................1 

 II. Background...........................................................................................................2 

 III. BART-Eligible Sources ........................................................................................4 

 IV. CAIR and Arkansas ..............................................................................................8 

 V. BART Air Quality Modeling Approach ...............................................................8 

 VI. BART-Eligible Units Physical Parameters.........................................................10 

 A. Stack parameters ............................................................................................10 

 B. Emission rates ................................................................................................10 

 VII. Air Quality Model and Inputs.............................................................................11 

 A. CALPUFF No-obs and refined screening modeling......................................12 

 1. Modeling domain......................................................................................12 

 2. CALPUFF system implementation...........................................................13 

 3. Meteorological data modeling (CALMET) ..............................................13 

 4. Dispersion modeling (CALPUFF)............................................................14 

 5. Post-processing (POSTUTIL/CALPOST)................................................16 

 6. Measuring visibility impacts.....................................................................17 

VIII. Change in Visibility Due to BART Controls......................................................19 

 IX. References...........................................................................................................20 

Appendix A. Proposed Time-line.............................................................................. A-1 

Appendix B. Map of Receptors..................................................................................B-1 

Appendix C. BART-Eligible Sources’ Stack Parameters, Base Elevation 

 at Ground Level and Stack Coordinates ...............................................C-1 

Appendix D. BART-Eligible Emission Rates used for the 

 No-obs Modeling Run.......................................................................... D-1 

Appendix E.Chapter 5 of the CENRAP BART Modeling Guidelines ......................E-1 

Appendix F.CALMET Input Control Files................................................................F-1 

Appendix G.CALPUFF Input Control Files............................................................. G-1 

Appendix H.POSTUTIL Input Control Parameters...................................................F-1 

Appendix I. CALPOST Input Control Parameters .....................................................I-1 

Appendix J. Chapter 3 of the CENRAP BART Modeling Guidelines.......................J-1 

 

 
iii

List of Figures 

Figure 1 Mandatory Class I federal areas in the U.S.....................................................3 

Figure 2 Arkansas’ Class I areas ...................................................................................3 

Figure 3 Map showing the 300 km radius buffer zones around five separate 

 receptors (north, south, east, west, and center) located in the following 

 Class I areas: Upper Buffalo, Caney Creek, Hercules Glade, Mingo, and 

 Sipsey. This map was developed to determine which Class I areas will 

 Bee assessed during the BART determination modeling ...............................4 

Figure 4 Map indicating the locations of Upper Buffalo, Caney Creek, and the 

 eighteen BART-eligible facilities located in Arkansas...................................7 

Figure 5 Map indicating the locations of Upper Buffalo, Caney Creek, Hercules 

 Glade, Mingo, Sipsey, and the eighteen BART-eligible facilities 

 located in Arkansas.........................................................................................8 

Figure 6 Map of the 6 km CENRAP Central CALPUFF domain...............................12 
iv

List of Tables 

Table 1 Class I areas and their locations as well as the supervising agencies 

 ADEQ will be assessing..................................................................................4 

Table 2 Fossil fuel-fired steam electric plants > 250 MMBtu/hr and Kraft 

 pulp mills facilities with BART-eligible emissions units...............................5 

Table 3 Petroleum refineries, sintering plants and chemical processing 

 plants facilities with BART-eligible emission units .......................................6 

Table 4 CALPUFF modeling components.................................................................13 

Table 5 Species modeled in BART screening analyses.............................................15 

Table 6 EPA recommended monthly average f(RH) for the five Class I areas 

 ADEQ are assessing......................................................................................17 

Table 7 Average annual natural levels of aerosol components (μg/m3) ....................18 
1 

I. Introduction 

On 6 July 2005, the U.S. Environmental Protection Agency (EPA) published final 

amendments to its 1999 Regional Haze Rule in the Federal Register, including Appendix 

Y, the final guidance for Best Available Retrofit Technology (BART) determinations (70 

FR 39104-39172). The BART rule requires the installation of BART on emission sources 

that fit specific criteria and “may reasonably be anticipated to cause or contribute” to 

visibility impairment in any Class I area. Air quality modeling is the preferred method 

for establishing which emission sources cause or contribute to visibility impairment. 

Arkansas’ BART modeling protocol is provided herein. 

According to the Regional Haze Regulations and Guidelines for Best Available Retrofit 

Technology (BART) Determination; Final Rule (40 CFR Part 51, p 39125), each state is 

required to develop a BART Modeling Protocol that describes the required methodology 

to assess the levels of controls needed on sources subject to BART. The aforementioned 

regulation also requires states to work in partnership with all stakeholders including 

Tribes, EPA, Federal Land Managers (FLMs), Regional Planning Organizations (RPOs) 

and the various source operators. Although states are required to work in concert with 

the previously mentioned stakeholders, EPA has the ultimate authority to approve or 

disapprove a state’s State Implementation Plan (SIP). 

The main objective of this protocol is compliance with the RHR visibility improvement 

goals. To accomplish this goal, the Arkansas Department of Environmental Quality 

(ADEQ) has set forth three functions of this protocol. First, ADEQ will use the protocol 

to determine which BART-eligible units are subject-to-BART and must perform a 

BART-analysis. Second, facilities that ADEQ notifies that are subject-to-BART will use 

this protocol to conduct post-control modeling required for their BART-analysis. Third, 

the results from this protocol will be used to conduct cumulative modeling to show the 

change in visibility impact on Class I areas based on ADEQ’s BART determination and 

the BART emission limits for facilities based on their BART-analysis. The subject-toBART and final modeling will be submitted to the EPA as part of the BART section of 

the Arkansas State Implementation Plan (SIP) for Regional Haze. 

 

The AR RH SIP submittal deadline to EPA as set forth in the Regional Haze Regulations 

and Guidelines for Best Available Retrofit Technology (BART) Determination; Final 

Rule (40 CFR Part 51, p 39156) is December 17, 2007. To meet this deadline, ADEQ 

has developed a schedule for completing BART determinations and implementing the 

BART strategy in order to meet the mandatory SIP submittal deadline (Appendix A). As 

shown in Appendix A, the modeling results must be completed no later than March 1, 

2007. 

The Central States Regional Planning Association (CENRAP) contracted with Alpine 

Geophysics, LLC to develop a modeling protocol for the states within CENRAP’s region 

of which the state of Arkansas is a member. On December 22, 2005, Alpine Geophysics, 

LLC delivered the final version of the CENRAP BART Modeling Guidelines (Tesche, et 
2 

al, 2005). However, comments from EPA Regions VI and VII and the Federal Land 

Managers (FLMs) were not incorporated into the guidelines; thus, Alpine Geophysics, 

LLC rewrote the guidelines to reflect the comments from Regions VI and VII and FLMs. 

These guidelines were re-issued February 3, 2006. Hence, CENRAP’s BART Modeling 

Guidelines (Tesche, et al, 2005) have been approved by Regions VI and VII and the 

FLMs. Therefore, the Planning and Air Quality Analysis Branch, Air Division, Arkansas 

Department of Environmental Quality has chosen to adopt the CENRAP BART 

Modeling Guidelines as ADEQ’s BART Modeling Protocol. Additionally, in preparing 

this draft protocol, ADEQ also consulted the following draft BART modeling protocols: 

 

1. Best Available Retrofit Technology (BART) Modeling Protocol to Determine 

Sources Subject to BART in the State of Kansas draft version February 24, 2006 

2. Best Available Retrofit Technology (BART) Modeling Protocol to Determine 

Sources Subject to BART in the State of Minnesota draft version February 24, 

2006 

This draft protocol is most similar to the CENRAP BART Modeling Guidelines. These 

guidelines were developed to ensure “consistency between states in the development of 

BART modeling protocols and to harmonize the approaches between adjacent RPOs” 

(Tesche, et al, 2005). 

Soon after the finalization of this modeling protocol, ADEQ will notify sources subjectto-BART. For those facilities subject-to-BART, ADEQ will provide guidance for 

conducting their BART-analyses.

II. Background 

The Clean Air Act Amendments (CAAA) of 1977 established 156 Class I areas where 

visibility was determined to be an important value (Figure 1). Areas designated as Class 

I areas are those national parks exceeding 6000 acres, wilderness areas and national 

memorial parks exceeding 5000 areas, and all international parks that were in existence 

on August 7, 1977. While Rainbow Lake Wilderness Area, Wisconsin has been 

designated as a Class I area, the FLMs have indicated that visibility is not a valuable 

characteristic and therefore, is not included in BART or other RH analyses. 

The state of Arkansas has within her boundary two mandatory Class I federal areas (Class 

I area), Upper Buffalo Wilderness Area and Caney Creek Wilderness Area which are 

managed by the United States Forest Service (Figure 2). However, there are two Class I 

areas in southern Missouri that are located downwind of facilities operating in Arkansas. 

The Missouri Class I areas are Hercules-Glade Wilderness Area (US Forest Service) and 

Mingo National Wildlife Refuge (US Fish and Wildlife). While EPA has not listed the 

maximum distance from a Class I area to model, this criteria has been set by CENRAP as 

300 km. As shown in Figure 3, the eastern portion of Arkansas is within the 300 km 

radius of Sipsey Wilderness Area (US Forest Service), Alabama. Therefore, there are 
3 

five Class I areas Arkansas will be performing BART determination/exemption modeling 

(Table 1). 

Figure 1 Mandatory Class I federal areas in the United States of America 

Figure 2 Arkansas’s Class I areas 
4 

Figure 3 Map showing the 300 km radius buffer zones around five separate receptors 

(north, south, east, west, and center) located in the following Class I areas: Upper 

Buffalo, Caney Creek, Hercules Glade, Mingo, and Sipsey. This map was developed to 

determine which Class I areas will be assessed during the BART determination modeling 

Table 1 Class I areas and the State they are located in as well as the supervising agencies 

ADEQ will evaluate during the BART determination/exemption modeling 

Class I Area State Supervising Agency 

Upper Buffalo Wilderness Area AR U.S. Forest Service 

Caney Creek Wilderness AR U.S. Forest Service 

Hercules Glade Wilderness Area MO U.S. Forest Service 

Mingo NWS MO U.S. Fish and Wildlife

Sipsey Wilderness Area AL U.S. Forest Service 

III. BART-Eligible Sources 

The BART requirements in the RHR are intended to reduce emissions specifically from 

large emission units that, due to age, were exempted from other control requirements of 

the CAAA. For an emissions unit to be considered eligible for BART, it must fall into 

one of 26 specified categories, must have the potential to emit at least 250 tons per year 

of certain haze-forming pollutants, and must have been in existence on August 7, 1977, 

but not in operation before August 7, 1962. 

ADEQ staff determined Arkansas’ BART-eligible sources by first identifying which of 

Arkansas’ stationary sources fit the first criteria of being listed in the BART 26 specific 

categories. After identifying the sources which fit the first criteria, a database search of 
5 

these facilities was performed to determine whether or not these emitting units’ potential 

to emit were at least 250 tons per year of sulfur dioxide (SO2), nitrogen oxides (NOx), and 

particulate matter (PM). The next stage of determining BART-eligibility was to research 

the permit applications for the year the point source was placed into operation. The final 

step in the process was to contact facilities for the exact date of operation especially for 

sources that were placed into operation in the years 1977 and 1962. Tables 2 and 3 

contain the list of BART-eligible facilities (18) by BART source category and the 

number of BART-eligible emitting units (27) within each facility. Figure 4 is a map of 

Arkansas which shows the location of the 18 BART-eligible facilities located in 

Arkansas. Figure 5 depicts the five Class I areas Arkansas will be assessing and the 

BART-eligible sources in Arkansas. Appendix B contains maps showing the receptors at 

each Class I area ADEQ will be assessing. 

 

Table 2 Fossil fuel-fired steam electric plants > 250 MMBtu/hr and Kraft pulp mills 

facilities with BART-eligible emission units 

BART Source Category 

Number and Name 

Facility 

Name/Location 

Facility 

ID 

AFIN Unit 

ID 

Unit 

Description 

American Electric Power 

(SWEPCO)/Gentry 

05-007-

00107 

04-

0017 

SN-01 Boiler 

AR Electric 

Cooperative/Augusta 

05-147-

00024 

74-

00024 

SN-01 Boiler 1350mm 

AR Electric 

Cooperative/Camden 

05-103-

00055 

52-

00055 

SN-01 Boiler 

Entergy – Lake 

Catherine/Jones Mill 

05-059-

00011 

30-

00011 

SN-03 Unit 4 Boiler 

Entergy – Ritchie 

Plant/Helena 

05-107-

00017 

54-

00017 

SN-02 Unit 2 

Entergy – White Bluff/ 

Redfield 

05-069-

00110 

35-

00110 

SN-01 Unit 1 

Entergy – White 

Bluff/Redfield 

05-069-

00110 

35-

00110 

SN-02 Unit 2 

1. Fossil fuel-fired Electric 

Plants > 250 MMbtu/hour – 

Electric Generating Units 

(EGUs) 

Entergy – White 

Bluff/Redfield 

05-069-

00110 

35-

00110 

SN-05 Auxiliary Boiler 

Domtar, Inc./Ashdown 05-081-

00002 

41-

00002 

SN-03 #1 Power Boiler 

Domtar, Inc./Ashdown 05-081-

00002 

41-

00002 

SN-05 #2 Power Boiler 

Delta Natural Kraft/Pine 

Bluff 

05-069-

00017 

35-

00017 

SN-02 Recovery Boiler 

Evergreen/Pine Bluff 05-69-

00016 

35-

00016 

SN-04 #4 Recovery 

Boiler 

Georgia – Pacific 

Paper/Crossett 

05-003-

00013 

02-

00013 

SN-22 9A Boiler 

Green Bay Packing/ 

Morrilton 

05-029-

00001 

15-

00001 

SN05A Recover Boiler 

3. Kraft Pulp Mills 

Potlatch/McGehee 05-041-

00036 

21-

00036 

SN-04 Power Boiler 
6 

Table 3 Petroleum refineries, sintering plants and chemical processing plant facilities 

with BART-eligible emissions units 

BART Source 

Category Number 

and Name 

Facility 

Name/Location 

Facility 

ID 

AFIN Unit 

ID 

Unit 

Description 

11. Petroleum Refineries Lion Oil/El Dorado 05-139-

00016 

70-

00016 

SN809 #7 Catalyst 

Regenerator 

19. Sintering Plants Big River Industries 

/West Memphis 

05-035-

00082 

35-

00082 

SN-01 Kiln A 

Albermarle – South 

Plant/Magnolia 

05-027-

00028 

14-

00028 

SR-01 Tail Gas 

Incinerator 

Albermarle – South 

Plant/Magnolia 

05-027-

00028 

14-

00028 

BH-01 Boiler #1 

Albermarle – South 

Plant/Magnolia 

05-027-

00028 

14-

00028 

BH-02 Boiler #2 

FutureFuel Batesville 05-063-

00036 

32-

00036 

6M01-

01 

3 Coal Boilers 

El Dorado Chemical/El 

Dorado 

05-139-

00040 

70-

00040 

SN-08 West Nitric Acid 

Plant 

El Dorado Chemical/El 

Dorado 

05-139-

00040 

70-

00040 

SN-09 East Nitric Acid 

Plant 

21. Chemical Processing 

Plants 

El Dorado Chemical/El 

Dorado 

05-139-

00040 

70-

00040 

SN-10 Nitric Acid 

Concentrator 
7 

Figure 4 Map indicating the locations of Upper Buffalo, Caney Creek and the eighteen 

BART-eligible facilities located in Arkansas 
8 

Figure 5 Map indicating the locations of Upper Buffalo, Caney Creek, Hercules Glade, 

Mingo and the eighteen BART-eligible facilities located in Arkansas 

IV. CAIR and Arkansas 

The Clean Air Interstate Rule was finalized in May 2005 by EPA and applies to states in 

the eastern U.S. Reconsiderations were finalized March 2006. This rule address air 

pollution transport across state borders. EPA determined which states must reduce which 

pollutants based on modeling which showed how the travel of pollution affects nonattainment in other states. CAIR requires states to reduce NOx and/or SO2 emissions. Of 

the three programs in CAIR, Arkansas is required to participate in only the Ozone-Season 

NOx reductions program. Although EPA’s BART Modeling Guidance allows CAIR 

states to participate in the CAIR cap and trade program, the state of Arkansas is not 

eligible for the aforementioned trading program because Arkansas is in CAIR only for 

NOx during the ozone season. Therefore, in Arkansas CAIR is not better than BART. 

Thus BART-eligible EGUs will be modeled for BART determination/exemption by 

ADEQ. 
9 

V. BART Air Quality Modeling Approach 

According to EPA’s BART Modeling Guidance, “CALPUFF is the best regulatory 

modeling application currently available ... and is currently the only EPA-approved 

model...” (p 45); therefore, ADEQ and CENRAP have chosen to use CALPUFF in the 

BART determination process as well as in the post-control analysis. One of the air 

quality modeling approaches suggested by EPA in the BART guidance is an individual 

source attribution approach. This is the approach ADEQ proposes to take. Specifically, 

this entails modeling source-specific units and comparing modeled impacts to a particular 

deciview threshold (described below). ADEQ has decided to conduct the subject-toBART modeling, rather than have each BART-eligible facility either conduct the 

modeling or hire a contractor. This plan will eliminate the need for ADEQ to quickly 

review many air quality modeling analyses conducted using varying approaches. This 

plan will also satisfy the need to use a consistent approach among the modeling analyses. 

Once the subject-to-BART modeling is complete, all the modeling inputs will be 

available to facilities subject to BART for them or their consultants to conduct modeling 

for making BART analyses. 

ADEQ will follow EPA’s BART Modeling Guidance (p 42) in sitting a threshold limit in 

determining whether a BART-eligible source is either subject-to-BART or exempt. 

According to the aforementioned modeling guidance, an individual source will be 

considered to “cause visibility impairment” if the emissions results in a change (delta Δ) 

in deciviews (dv) that is greater than or equal to 1.0 deciview on the visibility in a Class I 

area. Additionally, if the emissions from a source results in a change in visibility that is 

greater than or equal to 0.5 dv in a Class I area the source will be considered to 

“contribute to visibility impairment” (BART Final Rule, 40 CFR 51 p 39113). Thus, 

ADEQ has set the threshold limit at 0.5 dv. 

The modeling approach discussed here is specifically designed for conducting the 

subject-to-BART screening analyses. There may be differences between modeling for 

conducting BART analyses and that for conducting a visibility analysis for a New Source 

Review permit, which may involve similar emission sources and the same air dispersion 

model used here. 

To ensure that no sources pass the screening test when they should fail, the simple 

approach, by its nature, must be the most conservative of all the conditions likely to be 

examined for the source in question. For example, many factors influence the 

contribution of a source to the Class I area other than distance. The frequency of winds 

transporting the pollutants toward the Class I area may often be important to include for a 

reliable screening analysis. Also, a more distant Class I area downwind in the 

predominant wind direction from a source may receive a higher visibility impact than a 

closer Class I area that is infrequently downwind of the source. Another example of 

conservatism in the screening process is the use of the latest beta version of the 

CALMET/CALPUFF modeling system using the no-observation (no-obs) mode (the 

prognostic meteorological model MM5). Thus, the maximum impact instead of the 98th

percentile will be used to determine if a source has an impact on visibility in a Class I. 
10 

Additionally, the BART analysis process includes several other steps in addition to the 

modeling described in this protocol (EPA, 2005). These steps, none of which are 

addressed in this document, include detailed analysis of: 

 Costs of compliance among the various retrofit control options 

 Energy and non-air quality impacts 

 Existing pollution control technologies in use at the BART-eligible unit 

particularly with respect to their affecting the choice of retrofit options 

 Remaining useful life of the units and/or facility 

 Improvements in visibility expected from the use of BART controls. 

VI. BART-Eligible Units Physical Parameters 

The physical characteristics of the BART-eligible point sources to be used for the 

screening stage one analysis will be provided by ADEQ staff. For the stage two 

screening analysis, ADEQ staff will work with the BART-eligible facilities in the 

development of actual emissions. 

A. Stack Parameters 

Stack parameters required for modeling BART-eligible units were extracted from the 

permit applications. Stack parameters include height of the stack opening from ground in 

meters, inside diameter in meters, exit velocity in meters per second, exit gas temperature 

in Kelvin, ground elevation of the stack base in meters, and location coordinates of the 

stack in Lambert Conformal Conical (LCC). The stack coordinates were taken (in 

Universal Transverse Mertcator, UTM, and then converted to LCC) by ADEQ staff and 

then verified using ArcMap. Because the BART modeling focuses on mesoscale 

transport to Class I areas, other source term parameters (needed to calculate localized 

impacts) such as building heights and widths for calculating downwash will not be used. 

Appendix C contains tables indicating the stack parameters and coordinates for each 

BART-eligible emitting unit. 

B. Emission rates 

ADEQ notified by email the BART-eligible facilities to provide the 24-hour average 

actual emission rate with normal operations from the highest emitting day of the year. 

Excluded from consideration are days where start-up, shutdown or malfunctions occurred 

unless these activities are regular, frequently occurring components of the source’s 

operation cycle. 

ADEQ does not intend to use emissions of VOCs and ammonia from facilities for 

subject-to-BART analysis. Only specific VOC compounds form secondary organic 

aerosols that affect visibility. These compounds are a fraction of the total VOCs reported 

in the emissions inventory, and ADEQ does not have the breakdown of VOC emissions 
11 

necessary to model those that only impair visibility. Further, the prescribed screening 

model (CALPUFF) cannot simulate formation of particles from anthropogenic VOCs, 

nor their visibility impacts. Ammonia from specific sources will not be evaluated in this 

process, although ammonia is included in the modeling as a background concentration—

this will be discussed later in this modeling protocol. The appropriate VOCs and 

ammonia emission data can, and will be, included in regional scale modeling used for the 

Regional Haze SIP. 

VII. Air Quality Model and Inputs 

As stated in the previous section, CALPUFF is the preferred regulatory air dispersion 

model for long distance and therefore is the model ADEQ will be using in the BART 

determination process. ADEQ recognizes that CALPUFF has limited ability to simulate 

the complex atmospheric chemistry involved in the estimation of secondary particulate 

formation. However, for purposes of the subject-to-BART analysis, ADEQ intends to use 

CALPUFF for the following reasons: 

1. The increased level of effort required for conducting particulate apportionment in 

the regional scale, full-chemistry Eulerain model (CAMx) to acquire individual 

source contributions to Class I areas, relative to the simplicity of the CALPUFF 

model 

2. The lack of a plume-in-grid feature with the particulate apportionment technique 

currently available in CAMx 

3. The desire to be consistent with other CENRAP states, which all (except Texas 

and Iowa) appear to be using CALPUFF 

4. The limited scope of what this modeling is to determine 

5. The additional modeling of BART controls that will be conducted as part of the 

Regional Haze SIP with the CAMx or CMAQ model(s). EPA’s BART guidance 

states that States should follow the EPA’s Interagency Workgroup on Air Quality 

Modeling (IWAQM) guidance, Phase 2 recommendations for long-range 

transport. The IWAQM guidance was developed to address air quality impacts as 

assessed through the Prevention of Significant Deterioration (PSD) program at 

Class I areas, where the source generally is located beyond 50 km of the Class I 

area. The IWAQM guidance does not specifically address the type of assessment 

that will occur with the BART analysis. 

EPA recommends in their BART modeling guidelines (2005) that States follow the 

Interagency Workgroup on Air Quality Modeling (IWAQM) Phase II (1998) for longrange transport. The IWAQM guidance was developed to address air quality impact – as 

assessed through the Prevention of Significant Deterioration (PSD) program – at Class I 

areas, where the source generally is located beyond 50 km of the Class I area. The 

IWAQM guidance does not specifically address the type of assessment that will occur 

with the BART modeling. 
12 

A. CALPUFF Screening Modeling: 

CALPUFF modeling will be performed on all Arkansas BART-eligible sources. ADEQ 

intends to closely follow the CENRAP BART modeling protocol for most of the settings 

and inputs. Kansas attempted puff splitting and found this method to be computationally 

prohibitive on the current domain (State of Kansas, 2006). Also, according to Tesche, et 

al (2005), 

“There is no quantitative evidence that the horizontal and vertical puff-splitting 

algorithms in CALPUFF yield improved accuracy and precision in model 

estimates of inert or linearly reactive pollutants although conceptually the 

methods have appeal in that they attempt to mimic lateral and vertical wind 

speed and direction shears.” (p 6-6) 

Therefore, ADEQ will not invoke puff splitting in the no-obs screening analysis nor in 

the refined screening analysis. However, if a potentially subject-to-BART facility wishes 

to invoke the puff splitting mode, they will be required to notify ADEQ in writing of their 

intent and provide a protocol for approval prior to performing the analysis. 

1. Modeling domain 

The CALPUFF modeling will be conducted on the CENRAP central 6 km grid. The 

extent of the proposed CALPUFF domain is shown in Figure 2. 

Figure 6 6 km CENRAP Central CALPUFF domain (Tesche, et al, 2005) 
13 

CALPUFF will be applied to each source for three annual simulations spanning the years 

2001 through 2003. The IWAQM Phase II guidance allows the use of fewer than 5 years 

of meteorological data if a meteorological model using four-dimensional data 

assimilation is used to supply data. This is the case in this modeling analysis. See the 

section on meteorology for more information. 

2. CALPUFF system implementation 

There are three main components to the CALPUFF model: 

1. Meteorological Data Modeling (CALMET); 

2. Dispersion Modeling (CALPUFF); and 

3. Post-processing (CALPOST) 

Versions of the modeling components to use in this BART analysis are shown in Table 4. 

Table 4 CALPUFF Modeling Components 

Processor Version Level 

TERREL 3.311 030709 

CTGCOMP 2.42 030709 

CTGPROC 2.42 030709 

MAKEGEO 2.22 030709 

CALMM5 2.4 050413 

CALMET 5.53a 040716 

CALPUFF 5.753 051130 

POSTUTIL 1.4 040818 

CALPOST 5.6392 051130 

The specific use of each of these components in the BART analysis is described in more 

detail below. 

For screening applications, ADEQ will use the VISTAS version which is the latest ‘beta’ 

versions of the CALMET/CALPUFF modeling system. Note that these are not the EPA 

guideline codes but rather an updated version containing recent (as of this writing) 

science improvements and bug fixes. The current guideline CALPUFF code is version 

5.7, level 030402. This substitution results from EPA phasing out the use of the legacy 

Pasquill-Gifford (P-G) dispersion parameters with the introduction of AERMOD as a 

new guideline model. CALPUFF employs the AERMOD turbulence-based dispersion 

coefficients and probability density function (pdf) dispersion methods scheme instead of 

P-G. 

The appropriate model codes may be downloaded from www.src.com or purchased with 

the latest graphical user interface (GUI) from the model developer. The sequence of 

model processors listed in Table 4 corresponds to the order in which the programs are 

typically run. 

3. Meteorological data modeling (CALMET) 

ADEQ will use the 2001-2003 CENRAP developed no-obs CALMET dataset for the 

screening analysis.* This decision was based on EPA Regions VI and VII written 

comments on the CENRAP BART Modeling Guidelines (Tesche, et al, 2005) which 

state, 
14 

“Normally, in accordance with Section 8.3.1.2 (d) of the Guideline on Air Quality 

Models, the EPA would require that observations be incorporated in conjunction 

with prognostic meteorological data. While the idea of use of prognostic data 

alone holds promise, it is our opinion that this option requires further evaluation 

to insure that this approach does not bias CALPUFF towards underestimation 

(Guideline on Air Quality Models, Section 3.2.2 (d)(iv)). While we have 

significant concern regarding the use of the CALMET fields as they have been 

developed under the procedures documented in this protocol, we would consider 

the use of the CALMET meteorological fields provided the screening 

methodology described in Section 6.1 of the protocol is strictly adhered to. In this 

case, we feel that the use of the maximum visibility impact rather than the 98th

percentile value is conservative in its application, and would overcome concerns 

of a potential bias towards underprediction [sic] of the “no-observation” mode. 

Under these circumstances, we would consider the use of the CALMET fields 

acceptable for the CALPUFF screening procedure.” (EPA, 2005)

As stated in Section V. BART Air Quality Modeling Approach, ADEQ will use the 

maximum impact instead of the 98th percentile to determine if a source has an impact on 

visibility in a Class I. 

However, subject-to-BART facilities have the option of using the CENRAP CALMET 

processed data or incorporating observational meteorological data into the 

aforementioned CALMET data. If a subject-to-BART facility opts to use the CENRAP 

CALMET processed data, then the facility will be required to use the maximum impact 

instead of the 98th percentile (8th day). If a subject-to-BART facility decides they would 

rather use the 98th percentile, then the facility will be required to incorporate 

observational data and provide a protocol as well as a performance evaluation which will 

need to be approved by ADEQ, EPA, and the FLMs. 

Appendix F contains the detailed information on all CALMET setting that was used to 

develop the post-processed no-obs data fields. 

4. Dispersion modeling (CALPUFF) 

The CALMET output is used as input to the CALPUFF model, which simulates the 

effects of the meteorological conditions on the transport and dispersion of pollutants from 

an individual source. In general, ADEQ proposes to use the recommended default options 

in the CALPUFF model. There are some deviations, which are discussed below. Table 5 

indicates the species that will be modeled and/or emitted in the no-obs and refined BART 

analyses. 
15 

Table 5 Species modeled in BART screening analyses 

Species Modeled Emitted Dry Deposited 

SO2 Yes Yes Computed-gas 

SO4

-2 Yes No Computed-particle

NOx Yes Yes Computed-gas 

HNO3 Yes No Computed-gas 

NO3

-

 Yes No Computed-particle

PM-fine* Yes Yes Computed-particle

PM10* Yes Yes Computed-particle

*Please refer to Section VI subsection B for a detailed discussion on PM-fine and PM10. 

Emissions Speciation: ADEQ does not intend to model sulfate (SO4

-2), nitrate (NO3-

), 

elemental carbon (EC), and secondary organic aerosols (SOA) during the screening 

analyses. However, ADEQ recognizes the impact EC and SOA have on visibility. For 

instance, the light extinction (βext) coefficient for EC is 10 and for SOA it is 4. Currently, 

data are quite limited on appropriate speciation of organic/inorganic and 

filterable/condensable emissions by source category. Although there are speciation 

profiles available for gas- and oil-fired combustion turbines and coal combustion 

processes, currently there are no detailed profiles for the full range of BART-eligible 

sources. Thus, in the case of a subject-to-BART source where the PM profile for SO4

2-, 

EC, and SOA are known, ADEQ recommends the aforementioned species be modeled as 

separate species in CALPUFF in the post-control modeling analysis. 

Condensable Emissions: According to Tesche, et al (p 6-5 2005), “condensable 

emissions are considered primary fine particulate.” ADEQ is aware of the inability to 

measure PM2.5 emissions. Thus, BART-eligible facilities will be most likely use AP-42 

emission factors to develop the “actual” highest average 24-hr emission rate for this 

pollutant. In the development of this emission rate, ADEQ will require these facilities to 

use the AP-42 emission factors for condensable PM2.5. For sources where AP-42 factors 

are not available, assumptions for partitioning need to be resolved with ADEQ. 

Size Classification of Primary PM Emissions: Particle size parameters are entered in the 

CALPUFF input file for dry deposition of particles. There are default values for “aerosol” 

species (i.e., SO4

-2, NO3-

, and PM2.5). The default value for each of these species is 0.48 

μm geometric mass mean diameter and 2.0 μm geometric standard deviation. The main 

sources of these particles are fuel combustion. A way to account for this, without 

including EC and SOA in the modeling, is to use particle speciation in the postprocessing step. This is discussed below in the CALPOST section. 

As stated in a previous section, all PM10 emissions will be modeled as PM2.5 for the noobs model simulations (Tesche, et al, 2005). 

Background Ozone concentrations: Ozone (O3) can be input to CALPUFF as hourly or 

monthly background values. Hourly values of ozone concentrations were obtained from 

two rural monitoring sites in Arkansas: Deer, Newton County monitoring site and Eagle 

Mountain, Montgomery County monitoring site. The hourly ozone concentrations were 

adjusted for the time differences between the post-processed prognostic meteorological 
16 

file (0 GMT) and the collection time of the ozone (LST). Also, the concentrations were 

adjusted from parts per million (ppm) to parts per billion (ppb). These hourly ozone 

values will be used in this modeling. 

Background Ammonia concentrations: Background ammonia concentration is assumed 

to be temporally and spatially invariant and will be fixed at 3 ppb across the entire 

domain for all months. It may be possible to derive NH3 concentrations from regional 

modeling outputs that CENRAP is currently developing. At this time these NH3 values 

are not available in a model ready form. 

Receptors: Receptors are locations where model results are calculated and provided in the 

CALPUFF output files. Receptor locations were derived from the National Park Service’s 

Class I area receptor database at 

http://www2.nature.nps.gov/air/maps/receptors/index.cfm. Only these discrete NPS 

receptors will be modeled in CALPUFF. The discrete receptors are necessary for 

calculating visibility impacts in the nine selected Class I areas that will be evaluated by 

ADEQ. All the discrete receptors will be placed with enough density that the highest 

visibility impacts should be evident. The NPS provides receptors in all the Class I areas 

on a 1 km basis. These receptors will be kept at the 1 km spacing for the BART 

modeling, and all receptors will be retained. NPS also provides a conversion program to 

convert the coordinates of the receptors from latitude/longitude (lat/long) to Lambert 

Conformal Conical (LCC). ADEQ used this conversion program to convert the receptors 

located in the five Class I areas it is assessing from lat/long to LCC. 

Outputs: The CALPUFF modeling results will be displayed in units of micrograms per 

cubic meter (μg/m3

). In order to determine visibility impacts, the CALPUFF outputs must 

be post-processed. 

Detailed information on all CALPUFF setting to be used in this screening analysis is 

located in Appendix G. 

5. Post-processing (POSTUTIL/CALPOST) 

Hourly concentration outputs from CALPUFF are processed through POSTUTIL and 

CALPOST to determine visibility conditions. Specifically, POSTUTIL takes the 

concentration file output from CALPUFF and recalculates the nitric acid and nitrate 

partition based on total available sulfate and ammonia. The ammonia-limiting method 

(ALM) in CALPUFF repartitions nitric acid and nitrate on a receptor-by-receptor and 

hour-by-hour basis to account for the models systematic over-prediction due to 

overlapping puffs. For both screening applications, the parameter MNIRATE=1 is set in 

POSTUTIL to implement this approximate correction in its simplest form. The 

background ammonia concentration that was obtained from CENRAP’s regional 

modeling effort will be used to maintain regional consistency in the CENRAP region. 

CALPOST uses the concentration file processed through POSTUTIL, along with relative 

humidity (RH) data, to perform visibility calculations. For the BART analysis, the only 

modeling results out of the CALPUFF modeling system of interest are the visibility 

impacts. 
17 

Please see Appendix H and I for detailed settings for POSTUTIL and CALPOST. 

Light extinction: Light extinction must be computed in order to calculate visibility. 

CALPOST has seven methods for computing light extinction. This BART screening 

analysis will use Method 6, which computes extinction from speciated particulate matter 

with monthly Class I area-specific relative humidity adjustment factors, and is implied by 

the BART guidance. Relative humidity (RH) is an important factor in determining light 

extinction (and therefore visibility) because SO4

-2 and NO3-

 aerosols, which absorb 

moisture from the air, have greater extinction efficiencies with greater RH. All BART 

analyses will apply relative humidity correction factors (f(RH)s) to SO4

-2 and NO3-

concentrations outputs from CALPUFF, which were obtained from EPA’s “Guidance for 

Estimating Natural Visibility Conditions under the Regional Haze Rule (EPA, 2003). The 

f(RH) values for the Class I areas that will be assessed are provided in Table 5. 

Table 6 EPA recommended monthly averaged f(RH) for the five Class I areas ADEQ is 

assessing (EPA, 2003) 

Class I Area Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

Caney Creek 3.4 3.1 2.9 3.0 3.6 3.6 3.4 3.4 3.6 3.5 3.4 3.5 

HerculesGlades 3.2 2.9 2.7 2.7 3.3 3.3 3.3 3.3 3.4 3.1 3.1 3.3 

Mingo 3.3 3.0 2.8 2.6 3.0 3.2 3.3 3.5 3.5 3.1 3.1 3.3 

Sipsey 3.3 3.0 2.8 2.7 3.1 3.4 3.5 3.5 3.5 3.3 3.1 3.3 

Upper Buffalo 3.3 3.0 2.7 2.8 3.4 3.4 3.4 3.4 3.6 3.3 3.2 3.3 

The PM2.5 concentrations are considered part of the dry light extinction equation and do 

not have a humidity adjustment factor. The light extinction equation is the sum of the wet 

SO4

-2 and NO3-

 and dry components PM2.5 plus Rayleigh scattering (βRay), which is 10 

inverse megameters (Mm-1). 

To account for sources modeled with a known PM speciation profile for EC, SOA, and 

SO4, an adjustment to the extinction coefficient for the PM components will be made in 

CALPOST. ADEQ intends to follow the method outlined in the FLM CALPUFF 

Reviewer’s Guide (Gebhart, 2005) which is located in Appendix K. 

6. Measuring visibility impacts 

The recommended procedure for quantifying visibility impacts can be found in Chapter 3 

of the CENRAP BART Modeling Guidelines (Tesche, et al, 2005) which is located in 

Appendix J. The key point is that the light extinction coefficient (βext) can be calculated 

from the IMPROVE equation as: 

 βext = 3 f(RH) [(NH4)2SO4] + 3 f(RH) [NH4NO3] + 4[OC] + 1[Soil] + 

 + 0.6[Coarse Mass] + 10[EC] + βRay
18 

The monthly site-specific f(RH) values were obtained for the five Class I Area ADEQ is 

assessing from Table A-3 in the EPA (2003) guidance document. Then, the haze index 

(HI), in dv, is calculated in terms of the extinction coefficient via: 

HI = 10 ln (βext/10) 

The change in visibility (measured in terms of Δ dv) is then compared against 

background conditions. The Δ dv value is calculated from the source’s contribution to 

extinction, βsource, and background extinction, βbackground, as follows:

 

Δ dv = 10 ln ({βbackground+ βsource}/ βbackground) 

If the Δ dv value is greater than or equal to 0.5 dv, the source is said to contribute to 

visibility impairment and is thus subject-to-BART controls. If not, it is BART-exempt. 

The annual average natural levels of aerosol components at each Class I area being 

evaluated by ADEQ are shown in Table 7. Natural conditions by component in Table 6 

are based on whether the Class I area is in the eastern or the western part of the United 

States. In this BART analysis, all Class I areas are located in the East. The source of this 

data is from EPA’s Guidance for Estimating Natural Visibility Conditions Under the 

Regional Haze Rule (EPA, 2003). 

Table 7 Average annual natural levels of aerosol components (μg/m3

) (EPA, 2003) 

Class I Area Region SO4 NO3 OC EC Soil Coarse Mass

Caney Creek East 0.23 0.10 1.40 0.02 0.50 3.00

Hercules-Glades East 0.23 0.10 1.40 0.02 0.50 3.00

Mingo East 0.23 0.10 1.40 0.02 0.50 3.00

Sipsey East 0.12 0.10 0.47 0.02 0.50 3.00 

Upper Buffalo East 0.23 0.10 1.40 0.02 0.50 3.00

As stated in section V, in a cooperative agreement with EPA Regions VI and VII and 

FLMs, CENRAP guidance deviates from use of the 98th percentile impact. The 

CALMET datasets as described in this protocol were processed with the no-obs options 

(i.e., surface observations were not used in the CALMET wind field interpolation). 

Aware that exercising CALMET with no-obs may lead in some applications to 

potentially less conservatism in the CALPUFF visibility results compared with the use of 

CALMET with observations, CENRAP has agreed to EPA’s recommendation that the 

maximum visibility impact, rather than the 98th percentile value, should be used for the 

no-obs screening analysis using the CENRAP-developed CALMET datasets. 

If the no-obs screening analysis results indicate a BART-eligible facility’s maximum Δ

dv on a Class I area is less that 0.5 dv, then they will be considered exempt from BART 

and will be notified by ADEQ of their status. However, if the maximum Δ dv is equal to 

or greater than 0.5 dv, the source will be considered to be subject-to-BART. ADEQ will 

notify these subject-to-BART facilities. 
19 

VIII. Change in Visibility Due to BART Controls 

Once a facility is determined to be subject-to-BART, this facility must perform an 

engineering analysis and a post-control modeling analysis using CALPUFF. This 

modeling analysis must be compared to the pre-control modeling results. Please note that 

this will be a source specific (i.e. emitting unit specific) and pollutant specific modeling 

analysis using CALPUFF. If a subject-to-BART facility opts to use the 98th percentile 

rather than the maximum impact, the subject-to-BART facility will be required to be 

incorporate observational data with the post processed CALMET prognostic 

meteorological data. Also these facilities will be required to submit their meteorological 

modeling protocol, model performance evaluation, and CALPUFF modeling protocol to 

ADEQ, EPA Region VI, and FLMs for approval. However, if the subject-to-BART 

facility opts to use the maximum impact rather than the 98th percentile, these facilities 

may use the post-processed CALMET MM5 data. 

Additionally, one control measure that a source may opt to use is to revise their Title V 

permit to provide for synthetic minor limits so that it falls under the BART emission cap. 

That permit modification must be done prior to the State going to public hearing on its 

RH SIP. The limits must be in place for as long as the RH SIP is applicable or for as long 

as the source is operational. However, the source will still need to do a post-control 

CALPUFF modeling analysis to determine the amount of emissions it needs to reduce for 

visibility improvement. (Note: ADEQ strongly recommends that all subject-to-BART 

facilities work closely with ADEQ in their engineering analyses.) Also, after all of the 

post-control results are submitted to and approved by ADEQ, these results will then be 

inputted into either CAMx or CMAQ for a cumulative model run. If the control 

measures proposed by the BART facilities still impact a Class I area, the BART facilities 

will need to implement additional control. Please note that all post-modeling results are 

due to ADEQ no later than October 23, 2006. 

 
20 

IX. References 

Gebhart, Howard (2005). Draft CALPUFF REVIEWER’S GUIDE. Air Resource 

Specialists, Inc., Fort Collins, Colorado. 

Kansas Department of Health and Environment, Bureau of Air and Radiation (March, 

2006). Best Available Retrofit Technology (BART) Modeling Protocol to Determine 

Sources Subject to BART in the State of Kansas

Minnesota Pollution Control Agency (2005). Best Available Retrofit Technology 

(BART) Modeling Protocol to Determine Sources Subject to BART in the State of 

Minnesota. 

Scire, J.S., D.G. Strimaitis, and R.J. Yamartino. (2000). A User’s Guide for the

CALPUFF Dispersion Model (Version 5). Earth Tech, Inc., Concord, Massachusetts. 

Scire, J.S., D.G. Strimaitis, and R.J. Yamartino. (2002). A User’s Guide for the

CALMET Dispersion Model (Version 5). Earth Tech, Inc., Concord, Massachusetts. 

Tesche, T.W, et al (2005) CENRAP BART Modeling Guidelines. Alpine Geophysics, 

LLC. Ft. Wright, KY 

U.S. EPA. (1998). Interagency Workgroup on Air Quality Modeling

(IWAQM) Phase2—Summary Report and Recommendations for Modeling Long Range 

Transport Impacts. EPA-454/R98-019. 

U.S. EPA (2003). Regional Haze: Estimating Natural Visibility Conditions 

Under the Regional Haze Rule. EPA-454/B-03-005. 

U.S. EPA. (2005). Regional Haze Regulations and Guidelines for Best Available 

Retrofit Technology (BART) Determinations. Federal Register Vol. 70, No. 128. 

U.S. EPA, Regions VI & VII (2005). BART Protocol Comments. 

U.S. EPA, Region VI (2006). Personal communication. 
A-1 

Appendix A. Proposed Time-line 

Figure A-1 ADEQ’s proposed time-line to meet the RH SIP deadline of December 17, 

2007 as set forth by EPA in its Regional Haze Regulations and Guidelines for Best 

Available Retrofit Technology (BART) Determination (40 CFR Part 51, p 39156) 
B-1 

Appendix B. Map of receptors 

Figure B-1 Receptors located in Caney Creek Wilderness Area, Arkansas 

Figure B-2 Receptors located in Hercules-Glade Wilderness Area, Missouri 
B-2 

Figure B-3 Receptors located in Mingo Wilderness Area, Missouri 

Figure B-4 Receptors located in Sipsey Wilderness, Alabama 
B-3 

Figure B-4 Receptors located in Upper Buffalo Wilderness Area, Arkansas 
C-1 

Appendix C. BART-Eligible Sources’ Stack Parameters, Base 

Elevation at Ground Level, and Stack Coordinates 

Table C-1 BART-eligible sources’ stack parameters 

STATIONARY SOURCE 

NAME/LOCATION 

Emission 

Unit ID 

Stack 

Height 

Meters 

Stack 

Diameter

Meters 

Exit 

Velocity 

m/sec 

Temperature

o

K 

Albermarle-South Plant / Magnolia SR-01 57.9 0.814 15.24 922 

Albermarle-South Plant / Magnolia BH-01 6.4 2.591 9.14 505 

Albermarle-South Plant / Magnolia BH-02 6.4 2.591 9.14 505 

American Elect. Power (SWEPCO) / 

Gentry SN-01 164.6 6.096 34.14 408 

AR Elect. Coop - Bailey Plant / Augusta SN-01 50.9 3.000 28.04 444 

AR Elect. Coop - McClellan Plant / 

Camden SN-01 48.8 3.301 28.04 444 

Big River Industries / W. Memphis SN-01 30.5 1.524 21.88 330 

Delta Natural Kraft / Pine Bluff SN-02 50.3 2.134 13.29 348 

Domtar, Inc. / Ashdown SN-03 66.1 1.890 26.76 522 

Domtar, Inc. / Ashdown SN-05 71.6 3.659 11.92 325 

FutureFuel / Batesville 6M01-01 61.0 2.743 9.45 422 

El Dorado Chemical / El Dorado SN-08 22.9 1.219 33.53 505 

El Dorado Chemical / El Dorado SN-09 22.9 1.219 32.00 500 

El Dorado Chemical / El Dorado SN-10 23.8 0.152 23.77 313 

Entergy - Lake Catherine / Jones Mill SN-03 59.4 5.182 3.08 396 

Entergy - Ritchie Plant / Helena SN-02 71.9 3.658 28.62 390 

Entergy - White Bluff / Redfield SN-01 304.8 7.833 27.43 434 

Entergy - White Bluff / Redfield SN-02 304.8 7.833 27.43 434 

Entergy - White Bluff / Redfield SN-05 4.6 0.914 19.81 519 

Evergreen/Pine Bluff SN-04 48.8 2.438 14.33 474 

Georgia-Pacific Paper / Crossett SN-22 53.3 3.658 10.45 341 

Great Lakes Chemical / El Dorado SN-302A 9.1 0.762 40.54 555 

Green Bay Packaging / Morrilton SN-05A 30.8 1.798 25.60 456 

Lion Oil / El Dorado SN-809 61.0 1.753 9.75 533 

Potlatch Corp. / McGehee SN-04 89.6 2.743 14.78 444 
C-2 

Table C-2 BART-Eligible Emission Units’ Base Elevation and Lambert Conformal 

Conical (LCC) Coordinates 

 

STATIONARY SOURCE 

NAME/LOCATION (BART File Name) 

Emission 

UNIT ID 

Base 

Elevation, 

meters 

(m) 

X Easting 

LCC x 

Y Northing 

LCC y 

Albermarle-South Plant / Magnolia SR-01 86.9 352.81836 -747.03381

Albermarle-South Plant / Magnolia BH-01 88.4 352.67618 -746.98114

Albermarle-South Plant / Magnolia BH-02 88.4 352.65801 -746.98190

American Elect. Power (SWEPCO) / 

Gentry SN-01 349.9 221.58128 -410.39077

Ark. Elect. Coop - Bailey Plant / Augusta SN-01 61.3 510.86643 -507.71488

Ark. Elect. Coop - McClellan Plant / 

Camden SN-01 33.5 390.21870 -702.15534

Big River Industries (General Shale)/ W. 

Memphis SN-01 60.0 609.12652 -517.70639

Delta Natural Kraft / Pine Bluff SN-02 66.4 457.00824 -621.20692

Domtar, Inc. / Ashdown SN-03 97.5 267.47491 -698.66686

Domtar, Inc. / Ashdown SN-05 97.5 267.48245 -698.74355

FutureFuel/ Batesville 6M01-01 82.3 493.14724 -458.02938

El Dorado Chemical / El Dorado SN-08 63.1 401.11728 -734.65321

El Dorado Chemical / El Dorado SN-09 63.1 401.13533 -734.65236

El Dorado Chemical / El Dorado SN-10 62.2 401.19594 -734.67412

Entergy - Lake Catherine / Jones Mill SN-03 100.0 375.45658 -606.40861

Entergy - Ritchie Plant / Helena SN-02 54.9 586.25363 -591.07129

Entergy - White Bluff / Redfield SN-01 94.2 446.73457 -625.11197

Entergy - White Bluff / Redfield SN-02 94.2 445.61252 -604.15523

Entergy - White Bluff / Redfield SN-05 94.2 445.61539 -604.25671

Evergreen/Pine Bluff SN-04 63.1 468.11868 -625.3954

Georgia-Pacific Paper / Crossett SN-22 46.0 469.03486 -745.02133

Green Bay Packaging / Morrilton SN-05A 98.5 387.29077 -532.44265

Lion Oil / El Dorado SN-809 75.6 403.01817 -741.82948

Potlatch Corp. / McGehee SN-04 43.9 533.13136 -678.59798
D-1 

Appendix D. BART-Eligible Emission Rates used for the NoObs Modeling Run 

Table D-1 BART-eligible units’ highest 24-hour actual emission rates for SO2, NOx, 

PM10* and PM2.5 in grams per second (g/sec) 

Highest 24-Hour Actual Emission 

Rates (g/sec) 

BART-Eligible Facilities/ Locations 

Emission Unit 

ID Number SO2 NOx PM10 PM2.5

Albermarle-South Plant / Magnolia SR-01 48.126 0.076 0.000 0.009 

Albermarle-South Plant / Magnolia BH-01 0.353 2.075 0.000 0.136 

Albermarle-South Plant / Magnolia BH-02 0.535 2.578 0.000 0.128 

American Elect. Power (SWEPCO) / 

Gentry SN-01 595.781 245.066 21.725 5.531 

AR Elect. Coop - Bailey Plant / Augusta SN-01 299.344 36.933 21.729 21.729 

AR Elect. Coop - McClellan Plant / 

Camden SN-01 346.189 47.124 28.764 28.764 

Big River Industries/ W. Memphis SN-01 0.000 8.589 0.000 7.076 

Delta Natural Kraft / Pine Bluff SN-02 0.239 1.701 1.058 0.529 

Domtar, Inc. / Ashdown SN-03 0.774 22.632 0.000 21.354 

Domtar, Inc. / Ashdown SN-05 70.175 52.008 0.000 7.881 

FutureFuell / Batesville 6M01-01 54.046 11.045 0.290 0.217 

El Dorado Chemical / El Dorado SN-08 0.000 20.060 0.000 0.000 

El Dorado Chemical / El Dorado SN-09 0.000 15.645 0.000 0.000 

El Dorado Chemical / El Dorado SN-10 0.000 0.415 0.000 0.000 

Entergy - Lake Catherine / Jones Mill SN-03 0.420 309.535 0.365 0.246 

Entergy - Ritchie Plant / Helena SN-02 0.105 17.640 0.997 0.997 

Entergy - White Bluff / Redfield SN-01 978.164 550.821 15.592 11.802 

Entergy - White Bluff / Redfield SN-02 985.933 596.075 16.653 12.915 

Entergy - White Bluff / Redfield SN-05 4.095 3.811 0.365 0.246 

Evergreen/Pine Bluff SN-04 21.42 28.35 1.008 0.000 

Georgia-Pacific Paper / Crossett SN-22 77.275 182.677 0.000 9.310 

Green Bay Packaging / Morrilton SN-05A 4.934 8.771 0.000 1.165 

Lion Oil / El Dorado SN-809 23.142 5.980 0.000 7.696 

Potlatch Corp. / McGehee SN-04 6.942 10.533` 2.752 2.752 
E-1 

Appendix E. Chapter 5 of the CENRAP BART Modeling 

Guidelines (Tesche, et al, 2005) 

5.0 DATA BASES FOR CALPUFF MODELING 

To support BART modeling by the states and source operators, both 

meteorological and aerometric data sets are required. Regional meteorological data sets 

generated by the CALMET model suitable for direct input to the CALPUFF modeling 

system have been developed and archived. These data sets cover calendar years 2001, 

2002, and 2003 for three sub-regional grid domains shown in Figures 5-1 through 5-4. 

The procedures used in developing the CALMET data sets generally follow the IWAQM 

recommendations (EPA, 1998), except for a few notable refinements. The processed 

CALMET files, in CALPUFF-ready input format, are available from CENRAP on hard 

disk drives to interested states and stakeholders. 

This chapter describes how these meteorological modeling sets were developed 

and evaluated. The basic CALMET model configuration used to generate the three years 

of CALPUFF-ready meteorology is described in detail so that users of this information 

have a clear understanding of the data sets and their applicability. In addition, for those 

states or source operators who elect to conduct more source-specific 

CALMET/CALPUFF modeling, the information in this chapter may be helpful in guiding 

specification of revised CALMET model inputs and generation of revised CALMET data 

sets. 

Also included in Section 5 .2 is a discussion of routinely available air quality 

monitoring data sets available to the states and source operators in support of screening 

and source-specific BART modeling exercises. 

5.1 Development of CALMET Meteorological Files 

5.1.1 MM5 Data Sets 

 Alpine Geophysics developed a consistent set of CALMET regional 

meteorological modeling data sets for use by the CENRAP States, BART eligible sources 

within the region and others. These meteorological modeling data sets were constructed 

through the joint use of the CALMET processor and results from existing annual threedimensional MM5 meteorological simulations. The specific annual prognostic model 

simulations available for CENRAP BART modeling included: 

> 2001 MM5 data set at 36/12 km resolution developed for EPA by Alpine 

Geophysics (McNally and Tesche, 2002; McNally 2003); 

> 2002 MM5 data set at 36 km resolution developed for CENRAP by 

Iowa DNR (Johnson, 2003a,b), 
E-2 

> 2003 MM5 data set at 36 km resolution developed for the Midwest RPO 

(Baker, 2005; Baker et al., 2004; Kembell-Cook et al., 2005) 

Each of these studies included a performance evaluation of the MM5 generated data sets 

against surface meteorological observations and the results of these evaluations are 

contained in the reports or presentations cited above. While there exists a set of annual 

12 km MM5 meteorology for 2002, this data set was developed by four independent 

CENRAP modeling centers and these data sets have not been concatenated into one 

master data base. More importantly, there has been no systematic, rigorous model 

performance evaluation performed on the CENRAP 2002 12 km MM5 data yet. 

Accordingly, until such time as the 2002 12 km data set has been evaluated and shown to 

be of comparable reliability as the aforementioned MM5 data sets, it’s use is 

contraindicated. 

5.1.2 CALMET Model Configuration 

 

The CALMET modeling procedures used to construct meteorological inputs to 

CALPUFF for visibility screening of BART eligible sources generally follows the 

IWAQM recommendations (EPA, 1998), except as noted below. 

CALMET Model Options. The CALMET model has a number of user-selected options, 

parameter settings, and ‘switches’ that must be defined prior to exercising the processing 

system. These options and settings are well-described in the CALMET User’s Guide 

(Scire et al., 2000a) and in the CALMET input file to the executable code. Appendix A 

of this protocol summarizes the CALMET configurations used in developing the 

processed 6 km meteorological fields over the three CENRAP BART modeling domains. 

Also included in the tables in Appendix A are the default CALMET options and 

parameter settings recommended in the IWAQM Phase 2 Report (EPA, 1998). 

 

CALMET Domain. Three slightly overlapping modeling domains were defined by 

CENRAP to support BART modeling. These domains are shown in Figures 5-1 through 

5-4 and Table 5-1. The processors used to generate the domain, land use, and elevation 

data for the CALMET/CALPUFF system include TERREL, CTGPROC, and 

MAKEGEO, as described below. 
E-3 

> TERREL is the terrain pre-processor that averages terrain features to the 

modeling grid resolution; TERREL constructs the basic properties of the 

gridded domain and defines the coordinates upon which meteorological 

data are stored. Key parameters include specification of grid type, 

location, resolution and terrain elevation. 

> CTGPROC computes the fractional land use for the modeling grid 

resolution. Land use characteristics for each grid cell are assigned using 

CTGPROC. The primary variable adjustment associated with CTGRPOC 

is selection of an appropriate land use database. Version 2.0 of the North 

American Land Cover Characteristics database is used. 

> MAKEGEO is the final pre-processor that combines the terrain and land 

use data for input to CALMET. Generating the appropriate 

MAKEGEO.INP control file requires only minimal alteration of the 

default assignments. Key modifications include specifying domain 

attributes and ensuring input files are correctly referenced. 

Terrain. CALMET requires both terrain height and land use/land cover for the 

application region. These are generated using the CALMET CTGPROC, TERREL and 

MAKEGEO processors. The terrain data were created using the TERREL (version 3.311, 

level 030709) processor and the Shuttle Radar Topography Mission (SRTM)-GTOPO 30 

second (~1 km) resolution dataset. 

Land Use. The landuse data set was created using the Composite Theme Grid CTGROC 

processor (version 2.42, level 030709) and the United States Geological Survey (USGS) 

Global Land Cover Characterization (GLCC) version 2.0 database. The GLCC database 

is available at 30 second (~1km) resolution. References for these and other modeling 

datasets can be found at www.src.com. 

Vertical Layer Structure. The vertical layer structure for the CALMET/CALPUFF 

screening applications is more refined than the general suggestions of IWAQM. The 

CENRAP vertical structure was designed to reduce the need for vertical interpolation 

while simultaneously improving vertical resolution within the planetary boundary layer 

(PBL). Table 5-2 identifies the 11 layer interfaces required to define the 10 layer vertical 

CALMET grid structure. The top interface in the CALMET simulation is 4000 meters. 

Use of Observations. Based on considerable discussions with State and Federal 

managers and agency personnel, CENRAP has elected to use the No-Obs mode in 

CALMET for constructing the 6 km meteorological fields for CALPUFF screening 

exercises. The three annual MM5 simulations (2001, 2002, and 2003) will be used as the 

sole source for meteorological data within CALMET. Blending observational data with 

the MM5 data within CALMET (i.e., use of the “OBS” option is essentially a redundant 

use of the same data. Substantial improvement in the MM5 initialization data and in the 

use of four dimensional data assimilation (FDDA) has been achieved in recent years 

using observational data. The ETA analysis data used in initial and boundary conditions 

estimates as well as within the FDDA fields derive from 3-hourly, 40 km objective 
E-4 

analysis fields computed using an extensive supply of observational data (National 

Weather Service surface and upper air data, GOES satellite precipitable water; VAD 

wind profiles from NEXRAD; ACARS aircraft temperature data; SSM/I oceanic surface 

winds; daily NESDIS snow cover and sea-ice analysis data; RAOB balloon drift; GOES 

and TOVS-1B radiance data; 2D-VAR SST from NCEP Ocean Modeling Branch; radar 

estimated rainfall; and surface rainfall). The complexity, resolution, and accuracy of the 

ETA data that is used to initialize and ‘nudge’ the MM5 forecasts is extensive indeed. 

Particularly at the 12-36 km horizontal grid scales over the flat to modestly rolling 

topography of the CENRAP domain, there is no need to introduce local meteorological 

observations in order to retrieve local terrain effects, for example. Thus, mesoscale wind 

patterns are likely to be adequately characterized by the MM5 simulations. 

Many observations, especially surface observations, reflect local conditions on a 

scale smaller than the 6 km CENRAP CALMET fields. The introduction of the local 

observations into the regional modeling domain may extend the influence of the 

observational data beyond its true representativeness and result in internally inconsistent 

flow features. In particular the time interpolation of the 12-hourly upper air sounding 

data may wash out structure in the MM5 fields that are appropriate to retain. Given that 

the CENRAP domain as a whole includes areas of moderately rolling terrain, coastal 

regions and relatively flat terrain, a single set of representative weights1

 that allows 

significant influence of the observations where appropriate, will involve a considerable 

effort and substantial testing. The internally consistent MM5 fields are considered likely 

to be appropriate for the regional simulations, and the incremental benefit of adding the 

observational data into the regional CALMET simulations is not considered worthwhile. 

However, on the smaller domains likely to be considered in source-specific 

modeling (e.g., 1-4 km in scale) with the higher CALMET grid resolution and the smaller 

domain size, more control over the region of influence of the meteorological observations 

can be achieved. It is easier for the diagnostic model to allow the local flow observations 

to have appropriate influence in the vicinity of the observation, but allow terrain-adjusted 

flow to dominate away from the observations. Given that the fine scale source-specific 

domains will be used especially in irregular and/or meteorologically complex settings, the 

relatively coarser-scale MM5 simulations are less likely to be fully adequate, and the 

introduction observational data into CALMET is more likely to achieve improvements in 

the resulting meteorological fields. 

Diagnostic Model Settings

 A number of diagnostic model settings must be selected for CALMET to properly 

process representative diagnostic meteorological data sets. These are summarized in 

Appendix A, compared to the default CALMET settings, and discussed in the following: 

 

1 Weights are assigned in CALMET to control the ‘blending’ of observations and MM5 predictions. 
E-5 

> CALMET options dealing with radius of influence parameters (R1, R2, 

RMAX1, RMAX2, RMAX3), BIAS, ICALM parameters are not used in 

No-Observations mode; 

> Gridded cloud data were inferred from the MM5 relative humidity fields 

(ICLOUD=3); 

> Given that all state variables are MM5-derived (IPROG=14; ITPROG=2), 

surface layer winds were not extrapolated to the upper layers (IEXTRP = -

1); 

 > The IWAQM recommendation for disabling the computation of kinematic 

effects in the wind field options and parameters was selected. This was 

selected in light of the very modest elevated terrain in the CENRAP 

domain, relative to the mountainous regions in the U.S. and Alps where 

the kinematic parameterizations were originally developed. Thus, the 

option for computing kinematic effects was disabled (IKINE = 0). 

 > The BIAS array was set to 0. in the CALMET control file because surface 

and upper air data were not used (NOOBS = 2); 

 > Because the MM5 wind fields supply CALMET with the initial guess 

fields to the diagnostic wind model (IWFCOD =1, IPROG = 14) and 

observational data are not reintroduced, the following variables were set to 

nominal values: 

 The minimum distance for which extrapolation of surface winds 

should occur was set to -1 (RMIN2 = -1.). 

 RMIN was left at the IWAQM recommendation of 0.1 km. 

 RMAX1 and RMAX2 were each assigned a value of 30 km. 

RMAX3 was assigned a value of 50 km. 

 R1 and R2 were each assigned the value of 1.0. 

 ISURFT and IUPT were assigned placeholder values of 4 and 2, 

respectively. 

 > The radius of influence regarding terrain features is comparable to the 

resolution of the processed terrain data: 12 km. 

 > The radius of influence for temperature interpolation is set to 36 km 

(TRADKM), a value considered appropriate given the 6 km CALMET 

domain and 36/12 km MM5 domain. 

 > The beginning/ending land use categories for temperature interpolation 

over water are assigned category 55: (JWAT1 = JWAT2 = 55). 
E-6 

 > SIGMAP was set to 50 km, while the IWAQM recommendation is 100 

km, but with no supporting documentation. Because precipitation rates 

are explicitly incorporated from the MM5 data, a lower radius of influence 

was deemed appropriate. 

> Diagnostic options: IWAQM default values were used (see Appendix A); 

> TERRAD (terrain scale) is required for runs with diagnostic terrain 

adjustments (i.e., the 2003 simulations). Values of ~10-20 km were 

tested, and an appropriate value determined.

> Land use defining water: JWAT1 = 55, JWAT2 = 55 (large bodies of 

water). This feature allows the temperature field over large bodies of 

water such as the Gulf of Mexico and the Great lakes to be properly 

characterized by buoy observations.

> Mixing height averaging parameter (MNMDAV) were determined 

sensitivity tests. The purpose of the testing is to optimize the variable to 

allow spatial variability in the mixing height field, but without excessive 

noise.

Obviously, there are some instances where more advanced and/or recently developed 

procedures for constructing the CALMET fields have been used compared with the 

IWAQM (1998) guidance. For example, one agency expressed concern about the choice 

to employ prognostic model-derived gridded cloud cover data in CALMET (ICLOUD = 

3). While this is admittedly a ‘non-guideline’ option, in our view it represents the best 

science option currently available. In particular, the EPA CAIR and CAMR rulemaking 

modeling and the CAMx/CMAQ modeling being performed by the RPOs for regional 

haze all utilize the gridded moisture fields in the MM5 model as a basis for estimating 

cloud. Presumably, if the method is suitable for such advanced visibility modeling, it is 

adequate for CALPUFF modeling. Of course, in the protocol negotiation, the States, 

source operators, and regulatory agencies have an opportunity to re-examine the 

CALMET diagnostic model settings used in creating the CENRAP gridded fields and 

modify them if warranted. 

In summary, the development of the regional CALMET meteorological fields 

from MM5 data was conducted in No-Observations (“No-Obs”) mode. CALMET’s 

boundary layer modules were used to compute mixing heights, turbulence coefficients 

and other meteorological parameters required as input to CALPUFF. 

 

 5.1.3 MM5/CALMET Processing 

Construction of the CALPUFF-ready meteorological fields entails a two-step 

process. First, the MM5 prognostic model output fields are extracted and processed for 

input to CALMET. This step entails running various extraction software routines 
E-7 

followed by the CALMM5 code. Then, CALMET is exercised for the full three year 

period over each sub-regional CENRAP domain. 

CALMM5. Previous applications of the prognostic Mesoscale Meteorological model 

version 5 (MM5) served as the source of the gridded meteorological fields for calendar 

years 2001, 2002, and 2003. The actual CALMM5 configuration entailed modification 

of a few user-specified variables. However, two setting are of primary importance: 

> All vertical layers from MM5 were extracted, providing CALMET 

configuration flexibility, and 

> Vertical velocity, relative humidity, cloud/rain fields, and ice/snow fields 

were extracted. (Graupel was extracted for 2001, the only year where the 

data were available in the MM5 datasets.) 

CALMET. CALMET (v5.53a, lev 040716) was applied consistent with CENRAP’s 

recommendation that the 6 km be generated using the ‘No-Obs’ option. The specific 

options used have been discussed above and are summarized in Appendix A. 

 

 5.1.4 Evaluation of the CALPUFF-Ready Meteorological Data Sets 

In typical applications the adequacy of the CALMET fields is seldom evaluated 

using independent measurements. Often, only cursory visual examination of wind vector 

plots or time series is considered. This evaluation is important because the CALMET 

performance analysis gives direct insight into the adequacy of the model-processed fields 

on a subregional basis. It also serves as an independent quality assurance tool. Alpine’s 

MAPS evaluation software to perform an independent evaluation of the processed 

CALMET data bases. MAPS was used in conjunction with the NCAR DS472 TDL data 

sets to evaluate the surface winds and temperatures for 2001-2003 across all three 

domains. Since only a small portion of the meteorological content of these data were 

ingested in the MM5 data assimilation routines (see Johnson, 2003a), these data sets are 

essentially an independent, quantitative means for evaluating the adequacy of the 

meteorological fields input to CALPUFF. 

CALMET Evaluation Methodology 

Several statistical measures were calculated as part of the CALMET 

meteorological evaluation using established procedures (e.g., Tesche et al., 1990; Emery 

et al., 2001). Additional plots and graphs are used to present these statistics on both 

hourly and daily time frames over the full annual cycle. For this study, evaluation 

measures were calculated for wind, temperature, and relative humidity because these 

parameters are the principal meteorological inputs to CALPUFF. The full set of 

CALMET evaluation statistics and graphical displays generated with the AG-MAPS 

software (McNally and Tesche,1994) are contained on a DVD available from CENRAP. 
E-8 

The statistics used to evaluate the meteorological fields for 2001-2003 are 

generated in both absolute terms (e.g., wind speed error in m/s), and relative terms 

(percent error) as is commonly done for air quality assessments. Obviously, a very 

different significance is associated with a given relative error for different meteorological 

parameters. For example, a 10% error for wind speed measured at 10 m/s is an absolute 

error of 1 m/s, a minor error. Yet a 10% error for temperature at 300 K is an absolute 

error of 30 K, a ridiculously large error. On the other hand, pollutant concentration errors 

of 10% at 1 ppb or 10 ppm carry practically the same significance. 

Three key meteorological metrics include the bias, error, and index of agreement 

(IOA) for wind speed, temperature and relative humidity. These measures are defined as 

follows: 

Bias (B): Calculated as the mean difference in prediction-observation pairings with valid 

data within a given analysis region and for a given time period (hourly or daily): 

Error (E): Calculated as the mean absolute difference in prediction-observation pairings 

with valid data within a given analysis region and for a given time period (hourly or 

daily). 

Note that the bias and gross error for winds are calculated from the predicted-observed 

residuals in speed and direction (not from vector components u and v). The direction 

error for a given prediction-observation pairing is limited to range from 0 to ±180°. 

Index of Agreement (IOA): calculated following the approach of Willmont (1981). This 

metric condenses all the differences between model estimates and observations within a 

given analysis region and for a given time period (hourly and daily) into one statistical 

quantity. It is the ratio of the total RMSE to the sum of two differences – between each 

prediction and the observed mean, and each observation and the observed mean: 

Viewed from another perspective, the index of agreement is a measure of the match 

between the departure of each prediction from the observed mean and the departure of 

each observation from the observed mean. Thus, the correspondence between predicted 

∑∑( ) = =

= −

J

j

I

i

i

j

i

j OP

IJ

B

1 1

1

∑∑= =

= −

J

j

I

i

i

j

i

j OP

IJ

E

1 1

1

⎥

⎥

⎥

⎥

⎦

⎤

⎢

⎢

⎢

⎢

⎣

⎡

−+−

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∑∑= =

J

j

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RMSEIJ IOA

1 1

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1
E-9 

and observed values across the domain at a given time may be quantified in a single 

metric and displayed as a time series. The index of agreement has a theoretical range of 0 

to 1, the latter score suggesting perfect agreement. 

CALMET Evaluation Results 

Table 5-5 summarizes the statistical measures, averaged over the month, for 

temperature, wind speed, and relative humidity for all three years. The CALMET 

evaluation DVD contains a full compilation of the statistical and graphical results. 

Figures 5-7 through 5-31 present a variety of graphical displays of processed and 

observed surface temperature, relative humidity, and wind across the three CENRAP 

subdomains for the three-year period 2001-2003. Figures 5-28 through 5-31 provide 

convenient summaries of the bias and error in the relative humidity, temperature, and 

wind speed fields across the continuous 36 month period by subdomain. 

Thorough discussion of the performance findings is beyond the scope of these 

guidelines. However, a few key findings of the evaluation are worth noting here. From 

Table 5-5, the wind speed index of agreement, a general measure of correlation between 

measured and observed winds, is systematically greater than a value of 0.8 for virtually 

every month. These values are typically better than those generally achieved in urbanand regional-scale model applications for ozone SIPs. For example, the statistical 

benchmark for IOA suggested by Emery et al., (2001) is IOA > 0.6. Thus, the wind 

speed agreement for all three domains and all three years appears quite good relative to 

other MM5/RAMS model applications. From Figure 5-11, the wind speed root mean 

square error for the Central domain for 2002 is generally below 2.0 m/s, the performance 

goal for this parameter. From Figure 5-29 (as well as in Table 5-5), the temperature bias 

results for the 36 month are generally quite close to the + 0.5 deg C performance goal. As 

shown in Figure 5-30 the temperature error results are slightly poorer than the 2 deg C 

performance goal for 2001 and 2003, but are below the 2.0 deg C threshold for 2002. 

Note that the benchmarks were developed not to provide a pass/fail standard to which all 

modeling results should be held, but rather to put the results into an historical context. 

In summary, we find that: 

 Relative Humidity 

 Bias over three-year period near zero all domains 

 For some months over- and under-prediction (up to 10% or more) is 

evident – no discernable trend 

 Errors typically diminish from 2001 through 2003, and are generally < 

12% after 1st quarter of 2001. 

 Surface Temperatures 

 Monthly averaged temperatures are systematically biased low (cooler) by 

0.25 to 1.25 deg C. 

 The errors in monthly averaged temperatures typically range between 1.8 

and 2.6 deg C 
E-10 

 Average error over all months is about 2.2 deg C. 

 Surface Wind Speeds 

 IOA typically between 0.8 0-0.9 

 Seasonally variable 

 Central subdomain gives best correlation 

 Results from MM5/CALMET evaluation provide potentially useful information 

for diagnosing BART visibility modeling analyses 

 MM5/CALMET fields exhibit good statistical agreement with observations, in 

part because observations figure prominently in the construction of the 

interpolated CALMET fields. 

 MM5/CALMET fields for the three CENRAP subdomains are quite sufficient for 

use in CALPUFF modeling. 

 5.1.5 Meteorological Data Archive and Distribution 

All models, scripts and CALMET data (excepting MM5 outputs) are available 

from CENRAP on appropriate external combination Firewire/USB drives. 

5.2 Aerometric Monitoring Networks 

Data from ambient monitoring networks for both gas-phase and aerosol species 

are available for use in CENRAP BART modeling analyses. Table 5-4 summarizes 

ambient monitoring networks. Data for 2002 have been compiled for all networks 

covering the CENRAP domain with the exception of the PAMS and PM Supersites. 

These data sets may be obtained from CENRAP. Figures 5-5 and 5-6 display the 

locations of monitoring sites in and near the CENRAP States. 
E-11 

Table 5-1. CENRAP Lambert Conic Conformal Modeling Domain Specifications 

(40.97 degree projection origin; 33 and 45 degree matching parallels). 

Domain Southwest 

Coordinate (km)

Number 

of X 

grid cells

Number 

of Y 

grid cells 

Horizontal

Resolution 

CALMET 

 South -1008, -1620 306 246 6 km 

 Central -1008, -864 388 234 6 km 

 North -1008, 0 300 193 6 km 

Table 5-2. Vertical Layer Structure in CALMET Fields. (Heights are in meters.) 

LAYER 

NUMBER

LAYER 

HEIGHT

LAYER 

NUMBER

LAYER 

HEIGHT

0 0. 6 640. 

1 20. 7 1200. 

2 40. 8 2000. 

3 80. 9 3000. 

4 160. 10 4000. 

5 320. 

Table 5-3. Meteorological Model File Sizes for CENRAP BART Modeling. 

Domain Monthly Annual 3 Years Domain Grid 3 years

North 4.6 55.2 165.6 2001 12 km 1370

Central 6.6 79.2 237.6 2002 36 km 430

South 6.0 72.0 216.0 2003 36 km 430

total 17.2 206.4 619.2 total 2230

CALMET 6 km File Sizes, (Gbytes) MM5 File Sizes, (Gbytes)
E-12 

Table 5-4. Statistical Evaluation of the CALMET Meteorological Fields for 2001-

2003. 

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Mean

RH Bias (%)

 North 4.54 3.19 0.17 -14.55 -12.09 -4.35 -0.62 1.17 -2.07 -7.98 -6.62 -4.22 -3.62

 Central -2.60 -7.28 -11.38 -10.69 -8.62 -2.90 0.66 1.07 -1.44 -5.46 -6.16 -7.78 -5.21

 South -10.23 -11.53 -13.78 -4.24 -2.08 0.99 4.12 3.16 -0.12 -2.12 -3.44 -9.76 -4.09

RH Error (%)

 North 10.06 10.31 14.03 18.77 16.28 12.39 11.82 11.76 13.26 15.54 13.53 12.89 13.39

 Central 13.32 15.86 17.45 17.05 14.50 11.67 11.52 11.32 12.26 15.52 14.79 14.95 14.18

 South 16.22 18.37 18.17 13.26 12.15 11.51 12.09 12.40 11.82 14.85 14.73 16.19 14.31

Temp Bias (0

C)

 North -1.63 -1.23 -1.23 -0.24 0.08 -0.29 -0.23 -0.54 -0.55 -0.09 -0.40 -1.27 -0.64

 Central -0.99 -0.65 -0.54 -0.16 0.13 -0.23 -0.43 -0.54 -0.36 -0.34 -0.30 -0.74 -0.43

 South -0.47 -0.42 0.03 -0.31 -0.33 -0.63 -0.99 -0.85 -0.52 -0.36 -0.19 -0.21 -0.44

Temp Error (0

C)

 North 3.10 2.88 2.54 2.49 2.44 2.43 2.42 2.49 2.58 2.48 2.89 2.55 2.61

 Central 2.38 2.25 1.99 2.18 1.99 2.01 2.07 2.11 2.21 2.52 2.61 2.42 2.23

 South 2.31 2.28 1.92 2.13 2.01 2.17 2.19 2.21 2.19 2.70 2.49 2.50 2.26

Wind Speed IOA

 North 0.79 0.83 0.83 0.87 0.86 0.85 0.81 0.84 0.84 0.82 0.81 0.79 0.83

 Central 0.85 0.87 0.88 0.88 0.89 0.86 0.84 0.86 0.87 0.86 0.85 0.84 0.86

 South 0.81 0.80 0.85 0.79 0.83 0.83 0.78 0.80 0.82 0.82 0.80 0.82 0.81

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Mean

RH Bias (%)

 North 8.33 9.52 6.63 0.95 -2.42 1.25 2.43 1.60 0.57 0.47 4.47 7.73 3.46

 Central 7.43 5.13 4.60 1.65 -1.02 1.52 2.50 1.88 -0.27 -1.40 -0.01 4.35 2.20

 South 3.08 -1.19 2.53 2.32 1.26 1.98 2.51 2.62 -0.80 -2.42 -4.45 -1.03 0.53

RH Error (%)

 North 11.85 13.18 11.61 11.13 11.90 10.04 9.54 9.08 10.26 10.26 11.55 11.61 11.00

 Central 12.21 12.43 11.26 10.58 10.72 9.89 9.55 9.54 10.22 10.25 11.42 11.26 10.78

 South 11.24 11.76 10.34 8.95 9.30 9.49 9.46 9.61 9.68 9.33 11.63 10.95 10.14

Temp Bias (0

C)

 North -0.70 -0.82 -0.96 -0.52 -0.25 -0.36 -0.53 -0.49 -0.44 -0.67 -0.76 -0.69 -0.60

 Central -0.57 -0.65 -0.79 -0.62 -0.41 -0.68 -0.81 -0.74 -0.49 -0.54 -0.55 -0.52 -0.61

 South -0.23 -0.13 -0.52 -0.61 -0.61 -0.94 -0.94 -1.07 -0.65 -0.47 0.04 -0.13 -0.52

Temp Error (0

C)

 North 2.15 2.07 2.04 1.89 1.86 1.83 1.86 1.80 1.95 1.78 1.99 2.15 1.95

 Central 2.12 2.05 2.14 1.95 1.91 1.93 1.93 1.92 2.02 1.77 2.00 2.00 1.98

 South 2.18 2.05 2.17 1.83 1.89 1.91 1.88 2.00 1.92 1.68 2.06 1.93 1.96

Wind Speed IOA

 North 0.82 0.84 0.86 0.88 0.86 0.85 0.85 0.83 0.85 0.85 0.81 0.78 0.84

 Central 0.87 0.88 0.90 0.90 0.88 0.87 0.84 0.84 0.87 0.88 0.85 0.85 0.87

 South 0.86 0.86 0.85 0.85 0.84 0.82 0.79 0.80 0.83 0.83 0.83 0.82 0.83

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Mean

RH Bias (%)

 North 10.15 7.40 6.01 0.93 -3.76 -0.38 1.38 2.04 -1.66 -1.99 2.96 7.68 2.56

 Central 6.94 4.76 4.15 0.42 -2.18 0.17 2.08 2.13 -2.05 -4.13 0.00 5.47 1.48

 South 0.00 0.00 0.47 -1.10 -0.37 0.54 1.77 2.89 -3.31 -6.01 -3.66 -0.33 -0.76

RH Error (%)

 North 13.30 11.21 12.32 11.70 11.65 10.03 9.70 9.57 11.13 12.68 11.53 11.85 11.39

 Central 12.77 10.95 11.61 11.18 10.33 9.91 9.49 9.50 10.70 12.69 12.10 12.43 11.14

 South 11.18 10.00 9.85 10.17 9.20 9.54 8.90 9.91 10.21 12.12 12.15 12.39 10.47

Temp Bias (0

C)

 North -1.24 -0.99 -0.63 -0.29 -0.11 -0.10 -0.22 -0.49 -0.34 0.29 -0.85 -1.34 -0.53

 Central -0.84 -0.80 -0.64 -0.47 -0.27 -0.36 -0.60 -0.66 -0.32 0.30 -0.54 -0.89 -0.51

 South -0.17 -0.27 -0.36 -0.43 -0.46 -0.62 -0.91 -0.98 -0.28 0.53 0.00 -0.03 -0.33

Temp Error (0

C)

 North 2.31 2.15 2.14 2.02 1.81 1.77 1.91 1.98 2.25 2.57 2.30 2.67 2.16

 Central 2.14 2.03 2.15 2.13 1.80 1.81 1.96 1.99 2.16 2.54 2.31 2.45 2.12

 South 2.10 1.90 2.00 2.08 1.84 1.81 1.88 2.06 1.94 2.40 2.28 2.48 2.06

Wind Speed IOA

 North 0.79 0.81 0.83 0.86 0.87 0.85 0.86 0.87 0.84 0.82 0.80 0.82 0.83

 Central 0.85 0.88 0.87 0.89 0.90 0.87 0.87 0.86 0.87 0.87 0.86 0.86 0.87

 South 0.83 0.83 0.85 0.83 0.85 0.81 0.83 0.82 0.85 0.84 0.82 0.82 0.83

CALMET Model Evaluation Statistics for 2001. 

CALMET Model Evaluation Statistics for 2002. 

CALMET Model Evaluation Statistics for 2003. 
E-13 

Table 5-5. Overview of Ambient Data Monitoring Networks Covering the CENRAP 

Domain. 

Monitoring Network Chemical Species Measured Sampling Period Data Availability/Source 

The Interagency 

Monitoring of Protected 

Visual Environments 

(IMPROVE) 

Speciated PM25 and PM10 

(see species mappings) 

1 in 3 days; 24 hr 

average 

http://vista.cira.colostate.e

du/improve/Data/IMPRO

VE/improve_data.htm

Clean Air Status and 

Trends Network 

(CASTNET) 

Speciated PM25, Ozone (see 

species mappings) 

Approximately 1-

week average 

http://www.epa.gov/castne

t/data.html

National Atmospheric 

Deposition Program 

(NADP) 

Wet deposition (hydrogen 

(acidity as pH), sulfate, nitrate, 

ammonium, chloride, and base 

cations (such as calcium, 

magnesium, potassium and 

sodium)), Mercury 

1-week average http://nadp.sws.uiuc.edu/

Air Quality System 

(AQS) Aka Aerometric 

Information Retrieval 

System (AIRS) 

CO, NO2, O3, SO2, PM25, 

PM10, Pb 

Typically hourly 

average 

http://www.epa.gov/air/dat

a/

Speciation Trends 

Network (STN) 

Speciated PM 24-hour average http://www.epa.gov/ttn/am

tic/amticpm.html

Southeastern Aerosol 

Research and 

Characterization 

(SEARCH) 

(Southeastern US only) 

24-hr PM25 (FRM Mass, OC, 

BC, SO4, NO3, NH4, Elem.); 

24-hr PM coarse (SO4, NO3, 

NH4, elements); Hourly PM2.5 

(Mass, SO4, NO3, NH4, EC, 

TC); Hourly gases (O3, NO, 

NO2, NOy, HNO3, SO2, CO) 

Hourly or 24-hour 

average, depending 

on parameter. 

Electric Power Research 

Institute (EPRI), Southern 

Company, and other 

companies. 

http://www.atmosphericresearch.com

EPA Particulate Matter 

Supersites 

(Includes St. Louis in the 

CENRAP region) 

Speciated PM25 http://www.epa.gov/ttn/am

tic/supersites.html

Photochemical 

Assessment Monitoring 

Stations (PAMS) 

Varies for each of 4 station 

types. 

http://www.epa.gov/ttn/am

tic/pamsmain.html

National Park Service 

Gaseous Pollutant 

Monitoring Network 

Acid deposition (Dry; SO4, 

NO3, HNO3, NH4, SO2), O3, 

meteorological data 

Hourly http://www2.nature.nps.go

v/ard/gas/netdata1.htm
E-14 

Figure 5-1. CENRAP North, Central, and South 6 km Meteorological Domains. 
E-15 

Figure 5-2. CENRAP South Domain. 
E-16 

Figure 5-3. CENRAP Central Domain. 
E-17 

Figure 5-4. CENRAP North Domain. 
E-18 

Figure 5-5. Locations of IMPROVE, CASTNet, SEARCH, STN and NADP Monitoring 

Sites in and Near the CENRAP States. 
E-19 

Figure 5-6. Locations of AQS Monitoring Sites in and Near the CENRAP States.
E-20 

Figure 5-7. Spatial Mean Relative Humidity (%) over the Central Domain: July 2002.

Figure 5-8. Spatial Mean Surface Temperature (deg C) over the Central Domain: July 

2002. 
E-21 

Figure 5-9. Wind Speed Index of Agreement over the Central Domain: July 2002. 

Figure 5-10. Standard Deviation in Wind Speed (m/s) over the Central Domain: July 

2002. 
E-22 

Figure 5-11. Root Mean Square Error in Wind Speed (m/s) over the Central Domain: July 

2002. 

Figure 5-12. Scalar Mean Wind Speed (m/s) over the Central Domain: July 2002. 
E-23 

Figure 5-13. Vector Mean Wind Speed (m/s) over the Central Domain: July 2002.

Figure 5-14. Normalized Bias in Relative Humidity (%) over the Central Domain: July 

2002. 
E-24 

Figure 5-15. Normalized Error in Relative Humidity (%) over the Central Domain: July 

2002. 

Figure 5-16. Relative Humidity (%) at Kenosha, WI: July 2002. 
E-25 

Figure 5-17. Relative Humidity (%) at Topeka, KS: July 2002. 

Figure 5-18. Normalized Bias in Surface Temperature (%) over the Central Domain: July 

2002. 
E-26 

Figure 5-19. Normalized Error in Surface Temperature over the Central Domain: July 

2002.

Figure 5-20. Surface Temperature (deg C) at Kenosha, WI: July 2002. 
E-27 

Figure 5-21. Surface Temperature at Topeka, KS: July 2002. 
E-28 

Figure 5-22. MM5/CALMET Relative Humidity Bias (%) by Month for Three BART 

Modeling Years (2001, 2003, and 2003).
E-29 

Figure 5-23. MM5/CALMET Relative Humidity Error (%) by Month for Three BART 

Modeling Years (2001, 2003, and 2003). 
E-30 

Figure 5-24. MM5/CALMET Temperature Bias (deg C) by Month for Three BART 

Modeling Years (2001, 2003, and 2003). 
E-31 

Figure 5-25. MM5/CALMET Temperature Error (deg C) by Month for Three BART 

Modeling Years (2001, 2003, and 2003). 
E-32 

Figure 5-26. MM5/CALMET Wind Speed Index of Agreement by Month for Three 

BART Modeling Years (2001, 2003, and 2003). 
E-33 

Figure 5-27. MM5/CALMET Relative Humidity Bias (%) over Three Years in All 

CENRAP Domains. 
E-34 

Figure 5-28. MM5/CALMET Relative Humidity Error (%) over Three Years in All 

CENRAP Domains. 
E-35 

Figure 5-29. MM5/CALMET Surface Temperature Bias (deg C) over Three Years in All 

CENRAP Domains. 
E-36 

Figure 5-30. MM5/CALMET Surface Temperature Error (deg C) over Three Years in All 

CENRAP Domains. 
E-37 

Figure 5-31. MM5/CALMET Wind Speed Index of Agreement over Three Years in All 

CENRAP Domains. 
F-1 

Appendix F. CALMET Input Control Parameters 

Table F-1 Input Groups in the CALMET Control File.

Input 

Group Description Applicable 

0 Input and output file names Yes 

1 General run control parameters Yes 

2 Map Projection and Grid Control Parameters Yes 

3 Output Options Yes 

4 Meteorological Data Options Yes 

5 Wind field Options and Parameters Yes 

6 Mixing Height, Temperature and Precipitation Parameters Yes 

7 Surface Meteorological Station Parameters Yes 

8 Upper Air Meteorological Station Parameters Yes 

9 Precipitation Station Parameters Yes 

Table F-2 CALMET Model Input Group 0: Input and Output File Names

Parameter Default Value Comments 

Input GEO.DAT GEO.DAT 

Input SURF.DAT SURF.DAT 

Input CLOUD.DAT CLOUD.DAT 

Input PRECIP.DAT PRECIP.DAT 

Input MM4.DAT MM4.DAT 

Input WT.DAT WT.DAT 

Output CALMET.LST CALMET.LST 

Output CALMET.DAT CALMET.DAT 

Output PACOUT.DAT PACOUT.DAT 

NUSTA -- 0 Number of upper air stations 

NOWSTA -- 0 Number of over water stations 

Input UP1.DAT UP1.DAT 

Input UP2.DAT UP2.DAT 

Input UP3.DAT UP3.DAT 

Input SEA1.DAT SEA1.DAT 

Input DIAG.DAT DIAG.DAT 

Input PROG.DAT PROG.DAT 

Output TEST.PRT TEST.PRT 

Output TEST.OUT TEST.OUT 

Output TEST.KIN TEST.KIN 

Output TEST.FRD TEST.FRD 

Output TEST.SLP TEST.SLP 
F-2 

Table F-3 CALMET Model Input Group 1: General Run Control Parameters 

Parameter Default Value Comments 

IBYR - 2001 Starting year 

IBMO - 1 Starting month 

IBDY - 1 Starting day 

IBHR - 1 Starting hour 

IBTZ - 6 Base time zone 

IRLG - 8760 Length of run 

IRTYPE 1 1 Run type (must = 1 to run CALPUFF) 

LCALGRD T F Compute CALGRID data fields 

ITEST 2 2 Stop run after SETUP to do input QA 

Table F-4 CALMET Model Input Group 2: Map Projection and Grid Control Parameters 

Parameter Default Value Comments 

PMAP UTM LCC Map Projection 

RLATO -- 40N Latitude (dec. degrees) of projection origin 

RLONO -- 97W Longitude (dec. degrees) of projection origin 

XLAT1 -- 33N Matching parallel(s) of latitude for projection 

XLAT2 -- 45N Matching parallel(s) of latitude for projection 

DATUM WGS-G WGS-G 

NX -- 300 Number of X grid cells in meteorological grid 

NY -- 192 Number of Y grid cells in meteorological grid 

DGRIDKM -- 6.0 Grid spacing, km 

XORIGKM -- -1008. Ref. Coordinate of SW corner of grid cell (1,1) 

YORIGKM -- 0.0 Ref. Coordinate of SW corner of grid cell (1,1) 

NZ -- 10 No. of vertical layers 

ZFACE -- 0, 20 40, 

80, 160, 

320, 640, 

1200, 2000, 

3000, 4000 

Cell face heights in arbitrary vertical grid, m 
F-3 

Table F-5 CALMET Model Input Group 3: Output Options 

Parameter Default Value Comments 

LSAVE T T Disk output option 

IFORMO 1 1 Type of unformatted output file 

LPRINT F F Print met fields 

IPRINF 1 1 Print intervals 

IUVOUT(NZ) NZ*0 NZ*0 Specify layers of u,v wind components to 

print 

IWOUT(NZ) NZ*0 NZ*0 Specify layers of w wind component to print 

ITOUT(NZ) NZ*0 NZ*0 Specify levels of 3-D temperature field to 

print 

LDB F F Print input met data and variables 

NN1 1 1 First time step for debug data to be printed 

NN2 1 1 Last time step for debug data to be printed 

IOUTD 0 0 Control variable for writing test/debug wind 

fields 

NZPRN2 1 0 Number of levels starting at surface to print 

IPR0 0 0 Print interpolated wind components 

IPR1 0 0 Print terrain adjusted surface wind 

components 

IPR2 0 0 Print initial divergence fields 

IPR3 0 0 Print final wind speed and direction 

IPR4 0 0 Print final divergence fields 

IPR5 0 0 Print winds after kinematic effects 

IPR6 0 0 Print winds after Froude number adjustment 

IPR7 0 0 Print winds after slope flows are added 

IPR8 0 0 Print final wind field components 

Table F-6 CALMET Model Input Group 4: Meteorological Data Options 

Parameter Default Value Comments 

NOOBS 0 2 2 = No surface, over water, or upper air 

observations; use MM5 for surface, over water, and 

upper air data 

NSSTA -- 0 Number of meteorological surface stations 

NPSTA -- 0 Number of precipitation stations 

ICLOUD -- 3 Gridded cloud fields 

IFORMS 2 2 Formatted surface meteorological data file 

IFORMP 2 2 Formatted surface precipitation data file 

IFORMC 2 2 Formatted cloud data file 
F-4 

Table F-7 CALMET Model Input Group 5: Wind field Options and Parameters 

Parameter Default CENRAP Comments 

IWFCOD 1 1 Model selection variable 

IFRADJ 1 1 Compute Froude number adjustment effects? 

IKINE 0 0 Compute kinematic effects? 

IOBR 0 0 Use O’Brien (1970) vertical velocity 

adjustment? 

ISLSOPE 1 1 Compute slope flow effects? 

IEXTRP -4 -1 Extrapolate surface wind obs to upper levels? 

ICALM 0 0 Extrapolate surface winds even if calm? 

BIAS NZ*0 0, 0, 0, 0, 0, 

0, 0, 0, 0, 0 

Layer-dependent biases weighting aloft 

measurements 

RMIN2 4. -1.0 Minimum vertical extrapolation distance 

IPROG 0 14 14 = Yes, use winds from MM5.DAT file as 

initial guess field [IWFCOD = 1 

ISTEPPG 1 1 MM5 output time step 

LVARY F T Use varying radius of influence 

RMAX1 -- 30. Maximum radius of influence over land in sfc 

layer 

RMAX2 -- 30. Maximum radius of influence over land aloft 

RMAX3 -- 50. Maximum radius of influence over water 

RMIN 0.1 0.1 Minimum radius of influence used anywhere 

TERRAD -- 12. Terrain features radius of influence 

R1 -- 1. Weighting of first guess surface field 

R2 -- 1. Weighting of first guess aloft field 

RPROG -- 0. MM5 windfield weighting parameter 

DIVLIM 5.E-6 5.E-6 Minimum divergence criterion 

NITER 50 50 Number of divergence minimization iterations 

NSMMTH 2, 4, 4, 4, 

4, 4, 4 

2, 4, 4, 4, 4, 

4, 4 

Number of passes through smoothing filter in 

each layer of CALMET 

NITR2 99. 5, 5, 5, 5, 5, 

5, 5, 5, 5, 5 

Maximum number of stations used in each 

layer for the interpolation of data to a grid 

point 

CRITFN 1.0 1.0 Critical Froude number 

ALPHA 0.1 0.1 Kinematic effects parameter 

FEXTR2 NZ*0.0 NZ*0.0 Scaling factor for extrapolating sfc winds aloft 

NBAR 0 0 Number of terrain barriers 

IDIOTP1 0 0 Surface temperature computation switch 

ISURFT -- 4 Number of sfc met stations to use for temp 

calcs 

IDIOPT2 0 0 Domain-averaged lapse rate switch 

IUPT 0 2 Upper air stations to use for lapse rate 

calculation 

ZUPT 200. 200. Depth through which lapse rate is calculated 

IDIOPT3 0 0 Domain-averaged wind component switch 
F-5 

IUPWND -1 -1 Number of aloft stations to use for wind calc 

ZUPWND 1., 1000. 1., 

1000. 

Bottom and top of layer through which the 

domain-scale winds are computed 

IDIOPT4 0 0 Observed surface wind component switch 

IDIOPT5 0 0 Observed aloft wind component switch 

LLBREZE F F Use Lake Breeze Module 

NBOX 0 0 Number of lake breeze regions 

NLB -- 0 Number of stations in the region 

METBXID(NLB) -- 0 Station ID’s in the region 

Table F-8 CALMET Model Input Group 6: Mixing Height, Temperature and 

Precipitation

Parameter Default Value Comments 

CONSTB 1.41 1.41 Neutral stability mixing height coefficient 

CONSTE 0.15 0.15 Convective stability mixing height coefficient 

CONSTN 2400. 2400. Stable stability maxing height coefficient 

CONSTW 0.16 0.16 Over water mixing height coefficient 

FCORIOL 1.E-4 1.E-4 Absolute value of Coriolis parameter 

IAVEZI 1 1 Conduct spatial averaging? Yes = 1 

MNMDAV 1 10 Maximum search radius in averaging process 

HAFANG 30. 30. Half-angle of upwind looking cone for averaging 

ILEVZI 1 1 Layers of wind use in upwind averaging 

DPTMIN 0.001 0.001 Minimum potential temperature lapse rate in the 

stable layer above the current convective mixing ht 

DZZI 200. 200. Depth of layer above current conv. mixing height 

through which lapse rate is computed 

ZIMIN 50. 50. Minimum overland mixing height 

ZIMAX 3000. 3000. Maximum overland mixing height 

ZIMINW 50. 50. Minimum over water mixing height 

ZIMAXW 3000. 3000. Maximum over water mixing height 

ITPROG 0 2 3D temperature from observations or from MM5? 

IRAD 1 1 Type of interpolation; 1 = 1/R 

TRADKM 500. 36. Temperature interpolation radius of influence 

NUMTS 5 5 Max number of stations for temp interpolation 

IAVET 1 1 Spatially average temperatures? 1 = yes 

TGDEFB -.0098 -.0098 Temp gradient below mixing height over water 

TGDEFA -.0045 -.0045 Temp gradient above mixing height over water 

JWAT1 -- 55 Beginning land use categories over water 

JWAT2 -- 55 Ending land use categories for water 

NFLAGP 2 2 Precipitation interpolation flag; 2 = 1/R-squared 

SIGMAP 100. 50. Radius of influence for precipitation interpolation 

CUTP 0.01 0.01 Minimum precipitation rate cutoff (mm/hr) 
G-1 

Appendix G. CALPUFF Input Control Parameters 

Table G-1 Input Groups in the CALPUFF Control File

Input 

Group Description Applicable 

0 Input and output file names Yes 

1 General run control parameters Yes 

2 Technical options Yes 

3 Species list Yes 

4 Grid control parameters Yes 

5 Output options Yes 

6 Sub grid scale complex terrain inputs Yes 

7 Dry deposition parameters for gases Yes 

8 Dry deposition parameters for particles Yes 

9 Miscellaneous dry deposition for parameters Yes 

10 Wet deposition parameters Yes 

11 Chemistry parameters Yes 

12 Diffusion and computational parameters Yes 

13 Point source parameters Yes 

14 Area source parameters No 

15 Line source parameters No 

16 Volume source parameters No 

17 Discrete receptor information Yes 

Table G-2 CALPUFF Model Input Group 0: Input and Output File Names 

Parameter Default Value Comments 

METDAT CALMET.DAT Not used Input file name 

PUFLST CALPUFF.LST Varies with facility CALPUFF output file name 

CONDAT CONC.DAT Varies with facility Concentration output file 

name 

DFDAT DFLX.DAT Varies with facility Dry flux output file name 

WFDAT WFLX.DAT Varies with facility Wet flux output file name 

VISDAT VISB.DAT Varies with facility Visibility output file name 

OZDAT OZONE.DAT Varies with year Ozone input file name 

LCFILES - T File names converted to lower 

case 

NMETDAT 1 12 Number of CALMET.DAT 

files for run 

CALMET.DAT - METDAT=/location of 

CALMET.DAT files 

12 entries one for each month 
G-2 

Table G-3 CALPUFF Model Input Group 1: General Run Control Parameters 

Parameter Default Value Comments 

METRUN 0 0 All model periods in met file(s) will be run 

IBYR - See note 

1 below 

Starting year 

IBMO - 1 Starting month 

IBDY - 1 Starting day 

IBHR - 1 Starting hour 

XBTZ - 0 Time zone for met files (0 = GMT) 

IRLG - See note 

2 below 

Length of run 

NSPEC 5 10 Number of MESOPUFF II chemical species 

NSE 3 See note 

3 below 

Number of chemical species to be emitted 

ITEST 2 2 Program is executed after SETUP phase 

MRESTART 0 0 Do not read or write a restart file during run 

NRESPD 0 0 File written only at last period 

METFM 1 1 CALMET binary file (CALMET.MET) 

AVET 60 60 Averaging time in minutes 

PGTIME 60 60 PG Averaging time in minutes 

Note 1: Enter the year being modeled (i.e. 2001, 2002, or 2003) 

Note 2: Enter 8760 for the years 2001 and 2002 but enter 8748 for the year 2003 

Note 3: Enter 6 for the no-obs run and 7 for the refined run 

Table G-4 CALPUFF Model Input Group 2: Technical Options 

Parameter Default Value Comments 

MGAUSS 1 1 Gaussian distribution used in near field 

MCTADJ 3 3 Partial plume path terrain adjustment 

MCTSG 0 0 Sub-grid-scale complex terrain not modeled 

MSLUG 0 0 Near-field puffs not modeled as elongated 

MTRANS 1 1 Transitional plume rise modeled 

MTIP 1 1 Stack tip downwash used 

MSHEAR 0 0 (0, 1) Vertical wind shear (not modeled, 

modeled) 

MSPLIT 0 0 Puffs are not split 

MCHEM 1 1 MESOPUFF II chemical parameterization 

scheme 

MAQCHEM 0 0 Aqueous phase transformation not modeled 

MWET 1 1 Wet removal modeled 

MDRY 1 1 Dry deposition modeled 

MDISP 3 2 AERMOD dispersion coefficients 

MTURBVW 3 3 Use both σv and σw from PROFILE.DAT to 

compute σy and σz (n/a) 

MDISP2 3 2 AERMOD dispersion coefficients 

MROUGH 0 0 PG σy and σz not adjusted for roughness 

MPARTL 1 1 No partial plume penetration of elevated 

inversion 
G-3 

MTINV 0 0 Strength of temperature inversion computed 

from default gradients 

MPDF 0 0 PDF not used for dispersion under 

convective 

conditions 

MSGTIBL 0 0 Sub-grid TIBL module not used for shoreline 

MBCON 0 0 Boundary concentration conditions not 

modeled 

MFOG 0 0 Do not configure for FOG model output 

MREG 1 1 Technical options must conform to USEPA 

Long Range Transport (LRT) guidance 

Table G-5 CALPUFF Model Input Group 3: Species List-Chemistry Options

CSPEC Modeled1 Emitted 2

Dry 

Deposition3

Output Group 

Number 

SO2 1 1 1 0 

SO4

-2 1 0 2 0 

NOx 1 1 1 0 

HNO3 1 0 1 0 

NO3

-

 1 0 2 0 

NH3 0 0 1 0 

PM10

4

 1 1 2 0 

PMF4 1 1 2 0 

EC5 1 1 2 0 

SOA5 1 1 2 0 

Note 1: 0 = No, 1 = Yes 

Note 2: 0 = No, 1 = Yes (Depends on if species is being modeled or not) 

Note 3: 0 = none, 1 = computed gas, 2 = computed particle, 3 = user specified 

Note 4: Only PMF will be modeled and emitted in the no-obs run; however, both PM10

 and PMF will be modeled and emitted in the refined analysis 

Note 5: EC and SOA will not be modeled nor will it be emitted during the no-obs and 

 the refined runs
G-4 

Table G-6 CALPUFF Model Input Group 4: Map Projection and Grid Control Parameters 

Parameter Default Value Comments 

PMAP UTM LCC Map Projection 

FEAST 0.0 0.000 False Easting 

FNORTH 0.0 0.000 False Northing 

RLATO None 40N Latitude and Longitude of projection origin 

RLONO None 97W Latitude and Longitude of projection origin 

XLAT1 None 33N Matching parallel of latitude for map 

projection 

XLAT2 None 45N Matching parallel of latitude for map 

projection 

DATUM WGS-84 WGS-G Datum region for output coordinates 

NX None 366 Number of X grid cells in meteorological 

grid 

NY None 234 Number of Y grid cells in meteorological 

grid 

NZ None 10 Number of vertical layers in meteorological 

grid 

DGRIDKM None 6 Grid spacing (km) 

ZFACE None 0, 20 40, 80, 160, 

320, 640, 1200, 

2000, 3000, 4000 

Cell face heights in meteorological grid (m) 

XORIGKM None -1008 Reference X coordinate for SW corner of 

grid cell (1,1) of meteorological grid (km) 

YORIGKM None -864 Reference Y coordinate for SW corner of 

grid cell (1,1) of meteorological grid (km) 

IBCOMP None 1 X index of lower left corner of the 

computational grid 

JBCOMP None 1 Y index of lower left corner of the 

computational grids 

IECOMP None 366 X index of the upper right corner of the 

computational grid 

JECOMP None 234 Y index of the upper right corner of the 

computational grid 

LSAMP T F Sampling grid is not used 

IBSAMP None 1 X index of lower left corner of the sampling 

grid 

JBSAMP None 1 Y index of lower left corner of the sampling 

grid 

IESAMP None 366 X index of upper right corner of the 

sampling grid 

JESAMP None 234 Y index of upper right corner of the 

sampling grid 

MESHDN 1 1 Nesting factor of the sampling grid 
G-5 

Table G-7 CALPUFF Model Input Group 5: Output Options

Parameter Default Value Comments 

ICON 1 1 Output file CONC.DAT containing concentrations is 

created 

IDRY 1 1 Output file DFLX.DAT containing dry fluxes is 

created 

IWET 1 1 Output file WFLX.DAT containing wet fluxes is 

created 

IVIS 1 1 Output file containing relative humidity data is created 

LCOMPRS T T Perform data compression in output file 

IMFLX 0 0 Do not calculate mass fluxes across specific 

boundaries 

IMBAL 0 0 Mass balances for each species not reported hourly 

ICPRT 0 1 Print concentration fields to the output list file 

IDPRT 0 0 Do not print dry flux fields to the output list file 

IWPRT 0 0 Do not print wet flux fields to the output list file 

ICFRQ 1 1 Concentration fields are printed to output list file every 

hour (hr) 

IDFRQ 1 1 Dry flux fields are printed to output list file every 1 

hour 

IWFRQ 1 1 Wet flux fields are printed to output list file every 1 

hour 

IPRTU 1 3 Units for line printer output are in g/m3 for 

concentration and g/m2

/s for deposition 

IMESG 2 2 Messages tracking the progress of run written to 

screen 

LDEBUG F F Logical value for debug output 

IPFDEB 1 1 First puff to track 

NPFDEB 1 1 Number of puffs to track 

NN1 1 1 Meteorological period to start output 

NN2 10 10 Meteorological period to end output 
G-6 

Table G-8 CALPUFF Model Input Group 6: Sub-Grid Scale Complex Terrain Input

Parameter Default Value Comments 

NHILL 0 0 Number of terrain features 

NCTREC 0 0 Number of special complex terrain receptors 

MHILL - 2 Input terrain and receptor data for CTSG hills input 

in CTDM format 

XHILL2M 1 1 Conversion factor for changing horizontal 

dimensions to meters 

ZHILL2M 1 1 Conversion factor for changing vertical dimensions 

to meters 

XCTDMKM None 0.0 E+00 X origin of CTDM system relative to CALPUFF 

coordinate system (km) 

YCTDMKM None 0.0 E+00 Y origin of CTDM system relative to CALPUFF 

coordinate system (km) 

Table G-9 CALPUFF Model Input Group 7: Dry Deposition Parameters for Gases 

Species Default Value Comments 

0.1509 0.1509 Diffusivity 

1000. 1000. Alpha star 

8.0 8.0 Reactivity 

0.0 0.0 Mesophyll resistance 

SO2

0.04 0.04 Henry’s Law coefficient 

0.1656 0.1656 Diffusivity 

1.0 1.0 Alpha star 

8.0 8.0 Reactivity 

5.0 5.0 Mesophyll resistance 

NOx

3.5 3.5 Henry’s Law coefficient 

0.1628 0.1628 Diffusivity 

1.0 1.0 Alpha star 

18.0 18.0 Reactivity 

0.0 0.0 Mesophyll resistance 

8.0E-8 8.0E-8 Henry’s Law coefficient 

HNO3

0.000359 0.000359 Henry’s Law coefficient 
G-7 

Table G-10 CALPUFF Model Input Group 8: Dry Deposition Parameters for Particles

Species Default Value Comments 

SO4

-2 0.48 0.48 Geometric mass mean diameter of SO4-2 (μm) 

NO3

-

 2.0 0.48 Geometric mass mean diameter of NO3

- (μm) 

PM10 2.0 6.0 Geometric mass mean diameter of PMC (μm) 

PMF 2.0 0.48 Geometric mass mean diameter of PMF (μm) 

EC 2.0 0.48 Geometric mass mean diameter of EC (μm) 

SOA 0.48 0.48 Geometric mass mean diameter of SOA (μm) 

(Geometric Standard Deviation for all species assumed to be 2.0 μm). 

Table G-11 CALPUFF Model Input Group 9: Miscellaneous Dry Deposition Parameters

Parameter Default Value Comments 

RCUTR 30 30 Reference cuticle resistance (s/cm) 

RGR 10 10 Reference ground resistance (s/cm) 

REACTR 8 8 Reference pollutant reactivity 

NINT 9 9 Number of particle size intervals for effective 

particle deposition velocity 

IVEG 1 1 Vegetation in non-irrigated areas is active and 

unstressed 

Table G-12 CALPUFF Model Input Group 10: Wet Deposition Parameters

Species Default Value Comments 

3.21E-05 3.21E-05 Scavenging coefficient for liquid precipitation (s-1 SO2 ) 

0.0 0.0 Scavenging coefficient for frozen precipitation (s-1) 

1.0E-04 1.0E-04 Scavenging coefficient for liquid precipitation (s-1 SO4 ) -2 

3.0E-05 3.0E-05 Scavenging coefficient for frozen precipitation (s-1) 

6.0E-05 6.0E-05 Scavenging coefficient for liquid precipitation (s-1 HNO3 ) 

0.0 0.0 Scavenging coefficient for frozen precipitation (s-1) 

1.0E-04 1.0E-04 Scavenging coefficient for liquid precipitation (s-1 NO3 ) -

3.0E-05 3.0E-05 Scavenging coefficient for frozen precipitation (s-1) 

8.0E-05 8.0E-05 Scavenging coefficient for liquid precipitation (s-1 NH3 ) 

0.0 0.0 Scavenging coefficient for frozen precipitation (s-1) 

1.0E-04 1.0E-04 Scavenging coefficient for liquid precipitation (s-1 PM10 ) 

3.0E-05 3.0E-05 Scavenging coefficient for frozen precipitation (s-1) 

1.0E-04 1.0E-04 Scavenging coefficient for liquid precipitation (s-1 PMF ) 

3.0E-05 3.0E-05 Scavenging coefficient for frozen precipitation (s-1) 

1.0E-04 1.0E-04 Scavenging coefficient for liquid precipitation (s-1 EC ) 

3.0E-05 3.0E-05 Scavenging coefficient for frozen precipitation (s-1) 

1.0E-04 1.0E-04 Scavenging coefficient for liquid precipitation (s-1 OC ) 

3.0E-05 3.0E-05 Scavenging coefficient for frozen precipitation (s-1) 

 
G-8 

Table G-13 CALPUFF Model Input Group 11: Chemistry Parameters

Parameter Default Value Comments 

MOZ 1 1 Read ozone background concentrations from 

ozone.dat file (measured values). 

BCKO3 12*80 12*40 Background ozone concentration (ppb) 

BCKNH3 12*10 12*3 Background ammonia concentration (ppb) 

RNITE1 0.2 0.2 Nighttime NO2 loss rate in percent/hour 

RNITE2 2 2 Nighttime NOX loss rate in percent/hour 

RNITE3 2 2 Nighttime HNO3 loss rate in percent/hour 

MH202 1 1 Background H2O2 concentrations (Aqueous 

phase transformations not modeled) 

BCKH202 1 1 Background monthly H2O2 concentrations 

(Aqueous phase transformations not 

modeled) 
G-9 

Table G-14 CALPUFF Model Input Group 12: Dispersion/Computational Parameters

Parameter Default Value Comments 

SYDEP 550 550 Horizontal size of a puff in meters beyond 

which the time dependant dispersion equation 

of Heffter (1965) is used 

MHFTSZ 0 0 Do not use Heffter formulas for sigma z 

JSUP 5 5 Stability class used to determine dispersion 

rates for puffs above boundary layer 

CONK1 0.01 0.01 Vertical dispersion constant for stable 

conditions 

CONK2 0.1 0.1 Vertical dispersion constant for neutral/stable 

conditions 

TBD 0.5 0.5 Use ISC transition point for determining the 

transition point between the Schulman-Scire to 

Huber-Snyder Building Downwash scheme 

IURB1 10 10 Lower range of land use categories for which 

urban dispersion is assumed 

IURB2 19 19 Upper range of land use categories for which 

urban dispersion is assumed 

ILANDUIN 20 * Land use category for modeling domain 

XLAIIN 3.0 * Leaf area index for modeling domain 

ZOIN -0.25 * Roughness length in meters for modeling 

domain 

ELEVIN 0.0 * Elevation above sea level 

XLATIN -999 - North latitude of station in degrees 

XLONIN -999 - South latitude of station in degrees 

ANEMHT 10 10 Anemometer height in meters 

ISIGMAV 1 1 Sigma-v is read for lateral turbulence data 

IMIXCTDM 0 0 Predicted mixing heights are used 

XMXLEN 1 1 Maximum length of emitted slug in 

meteorological grid units 

XSAMLEN 1 10 Maximum travel distance of slug or puff in 

meteorological grid units during one sampling 

unit 

MXNEW 99 60 Maximum number of puffs or slugs released 

from one source during one time step 

MXSAM 99 60 Maximum number of sampling steps during one 

time step for a puff or slug 

NCOUNT 2 2 Number of iterations used when computing the 

transport wind for a sampling step that includes 

transitional plume rise 

SYMIN 1 1 Minimum sigma y in meters for a new puff or 

slug 

SZMIN 1 1 Minimum sigma z in meters for a new puff or 

slug 

SVMIN .50 .50 Minimum lateral turbulence velocities (m/s) 

SWMIN 0.20, 0.12, 

0.08, 0.06, 

0.20, 0.12, 

0.08, 0.06, 

Minimum vertical turbulence velocities (m/s) 
G-10 

0.03, 0.016 0.03, 0.016 

WSCALM 0.5 0.5 Minimum non-calm wind speeds (m/s) 

XMAXZI 3000. 3000. Maximum mixing height (m) 

XMINZI 50. 20. Minimum mixing height (m) 

SL2PF 10. 10. Maximum Sy/puff length 

PLXO 0.07, 0.07, 

0.10, 0.15, 

0.35, 0.55 

0.07, 0.07, 

0.10, 0.15, 

0.35, 0.55 

Wind speed power-law exponents 

WSCAT 1.54, 3.09, 

5.14, 8.23, 

10.80 

1.54, 3.09, 

5.14, 8.23, 

10.80 

Upper bounds of 1st 5 wind speed classes 

PGGO 0.020, 0.035 0.020, 0.035 Potential temp gradients PG E & F (deg/km) 

CDIV 0.01 0.01 Divergence criterion for dw/dz (1/s) 

PPC 0.5, 0.5, 0.5, 

0.5, 0.35, 

0.35 

0.5, 0.5, 0.5, 

0.5, 0.35, 

0.35 

Plume path coefficients (only if MCTADJ=3) 

NSPLIT 3 3 Number of puffs when puffs split 

IRESPLIT - 1900 Hour(s) when puff is eligible to split 

ZISPLIT 100 100 Previous hour’s minimum mixing height, m 

ROLDMAX 0.25 0.25 Previous Max mixing height/current mixing 

height ratio, must be less than this value to 

allow puff to split 

NSPLITH 5 5 Number of puffs resulting from a split 

SYSPLITH 1.0 1.0 Minimum sigma-y of puff before it may split 

SHSPLITH 2.0 2.0 Minimum puff elongation rate from wind shear 

before puff may split 

CNSPLITH 1.0E-07 1.0E-07 Minimum species concentration before a puff 

may split 

EPSSLUG 1.0E-04 1.0E-04 Criterion for SLUG sampling 

EPSAREA 1.0E-06 1.0E-06 Criterion for area source integration 

DSRISE 1.0 1.0 Trajectory step length for numerical rise 

algorithm 

Note: Values indicated by an asterisk (*) were allowed to vary spatially across the domain 

and were obtained from CALMET 

Table G-15 CALPUFF Model Input Group 13: Point Source Parameters

Parameter Default Value Comments 

NPT1 None Varies by 

scenario 

Number of point sources with stack parameters 

IPTU 1 1 Units for point source emission rates are g/s 

NSPT1 0 0 Number of source-species combinations with 

variable emissions scaling factors 

NPT2 None 0 Number of point sources with variable emission 

parameters provided in external file 

MISC None Point source 

parameters and 

emission data 

Point source inputs include stack height (H), 

stack diameter (d), exit temperature (T), exit 

velocity (v) emissions by species, and 

coordinate of stack (LCC) 
G-11 

Table G-16 CALPUFF Model Input Group 17: Discrete Receptor Information 

Parameter Default Value Comments 

NREC None 427 Number of discrete receptors 

Please note that ADEQ will not be modeling area, line and volume sources which are 

input groups 14, 15, and 16 respectively. 
H-1 

Appendix H. POSTUTIL Input Control Parameters 

Table H-1 Input Groups in the POSTUTIL Processor Control File 

Sub 

Group Description Applicable 

0a Input and output file names Yes 

1 NMET – Number of CALMET data files (365) Yes 

2 NFILES – Number of CALPUFF data files Yes 

Table H-2 POSTUTIL Processor Input Group 1: General Run Control Parameters 

Parameter Default Value Comments 

ISYR None See note 1 

below 

Starting year 

ISMO None 1 Starting month 

ISDY None 1 Starting day 

ISHR None 0 Starting hour 

NPER None See note 2 

below 

Number of periods to process 

NSPECINP None See note 3 

below 

Number of CALPUFF species to process 

NSPECOUT None See note 3 

below 

Number of species to output 

NSPECCMP None 0 Number of species to derive 

MDUPLCT None 1 Stop run if duplicate name 

NSCALED None 0 Number of CALPUFF files to ‘scale’ 

MNITRATE None 1 Re-compute the HNO3/NO3 partition for CALPUFF 

modeled concentrations? 1 = yes for all sources 

combined 

BCKNH3 10. 3. Default NH3 concentration (ppb) for HNO3/NO3

partitioning 

Note 1: Enter the modeled year for the CALPUFF run 

Note 2: Enter 8760 for years 2001 and 2002, but enter 8748 for the year 2003 

Note 3: Enter 6 for the no-obs run and 7 for the refined run 
H-2 

Table H-3 POSTUTIL Processor Input Group 2: Species Processing Information 

Parameter Default Value Comments 

ASPECI None SO2, SO4, NOx, HNO3, NO3, 

PM10, PMF See Note 1 

Below 

Species to post-process 

ASPECO None SO2, SO4, NOx, HNO3, NO3, 

PM10, PMF See Note 4 

Below 

Species to output 

CSPECCMP None CSPECCMP = N 

SO2 = 0.0 

SO4 = 0.291667 

NO = 0.466667 

NO2 = 0.304348 

HNO3 = 0.222222 

NO3 = 0.451613 

PM10 = 0.0 

Nitrogen species to be computed by 

scaling and summing one or more of 

the processed input species using the 

scaling factors for each of the 

NSPECINP input species 

CSPECCMP None CSPECCMP = S 

SO2 = 0.50 

SO4 = 0.333333 

NO = 0.0 

NO2 = 0.0 

HNO3 = 0.0 

NO3 = 0.0 

PM10 = 0.0 

Sulfur species to be computed by 

scaling and summing one or more of 

the processed input species using the 

scaling factors for each of the 

NSPECINP input species 

MODDAT None A (Default=1.0) 

SO2 = 1.1 

SO4 = 1.5 

HNO3 = 0.8 

NO3 = 0.1 

B (Default=0.0) 

SO2 = 0.0 

SO4 = 0.0 

HNO3 = 0.0 

NO3 = 0.0 

Each species in NSCALED 

CALPUFF data files may be scaled 

before processing (e.g., to change the 

emission rate for all sources modeled 

in the run that produced a data file). 

For each scaled species the scaling 

factors are A and B where x' = Ax + 

B. 

Note 4: In the no-obs run just enter PMF, but in the refined run enter PM10 and PMF 
I-1 

Appendix I. CALPOST Input Control Parameters 

Table I-1Input Groups in the CALPOST Processor Control File

Group Description Applicable 

0 Input and output file names Yes 

1 General Run Control Parameters Yes 

2 Visibility Parameters Yes 

3 Output Options Yes 

Table I-2 CALPOST Processor Input Group 1: General Run Control Parameters 

Parameter Default Value Comments 

METRUN 0 1 1 = Run all met periods in CALPUFF data file 

ISYR None 2001, 2002, 

2003 

Starting year 

ISMO None 1 Starting month 

ISDY None 1 Starting day 

ISHR None 0 Starting hour 

NPER None See note 1 

below 

Number of periods to process 

NREP 1 1 Process every hour of data? Yes = 1 

ASPEC None VISIB Process species for visibility 

ILAYER 1 1 Layer/deposition code; 1 for CALPUFF concentrations 

A 0.0 0.0 Scaling factor, slope 

B 0.0 0.0 Scaling factor, intercept 

LBACK F F Add hourly background concentrations or fluxes 

MSOURCE 0 0 Process only total reported contribution 

LG F F Process gridded receptors 

LD F T Process discrete receptors 

LCT F F Process complex terrain receptors 

LDRING F F Report receptor ring results 

NDRECP -1 See note 2 

below 

To select the Class I area’s receptors enter *1 after the 

number of receptors otherwise enter *0 

IBGRID -1 -1 X index of LL corner of receptor grid 

JBGRID -1 -1 Y index of LL corner of receptor grid 

IEGRID -1 -1 X index of UR corner of receptor grid 

JEGRID -1 -1 X index of UR corner of receptor grid 

NGONOFF 0 0 Number of gridded receptor rows 

NGXRECP 1 0 Exclude specific gridded receptors, Yes = 0 

Note 1: Enter 8760 for the years 2001 and 2002, but enter 8748 for the year 2003. 

Note 2: CALPOST is to be run for each Class I area assessed. 

3⁄4 The following are the number of receptors for each Class I area being assessed: 

1. Caney Creek = 80 

2. Hercules-Glade = 47 

3. Mingo Wilderness = 80 

4. Sipsey = 148 

5. Upper Buffalo = 72 
I-2 

Table I-3 CALPOST Processor Input Group 2: Species Processing Information 

Parameter Default Value Comments 

RHMAX 98 95 Maximum RH (%) used in particle growth curve 

LVSO4 T T Compute light extinction for sulfate? 

LVNO3 T T Compute light extinction for nitrate? 

LVOC T T Compute light extinction for organic carbon? 

LVMPC T T Compute light extinction for coarse particles? 

LVMPF T T Compute light extinction for fine particles? 

LVEC T T Compute light extinction for elemental carbon? 

LVBK T T Include background in extinction calculation? 

SPECPMC PMC PMC Coarse particulate species 

SPECPMF PMF PMF Fine particulate species 

EEPMC 0.6 0.6 Extinction efficiency for coarse particulates 

EEPMF 1.0 1.0 Extinction efficiency for fine particulates 

EEPMCBK 0.6 0.6 Extinction efficiency for coarse part. background 

EESO4 3.0 3.0 Extinction efficiency for ammonium sulfate 

EENO3 3.0 3.0 Extinction efficiency for ammonium nitrate 

EEOC 4.0 4.0 Extinction efficiency for organic carbon 

EESOIL 1.0 1.0 Extinction efficiency for soil 

EEEC 10.0 10.0 Extinction efficiency for elemental carbon 

MVISBK 2 6 Method 6 for background light extinction: 

Compute extinction from speciated PM measurements. FLAG 

RH adjustment factor applied to observed & modeled sulfate 

and nitrate 

BEXTBTBK -- 12 Background extinction for MVISBK=1 (1/Mm) 

RHFRAC -- 10 Percentage of particles affected by RH 

RHFAC 12*value Depends 

on Class I 

Area 

Extinction coefficients for modeled and background 

hygroscopic species computed using EPA (2003) monthly RH 

adjustment factors 

BKSEC 0.02 0.02 Eastern background elemental carbon βext 

BKSO4 0.23 0.23 Eastern background sulfate βext

BKNO3 0.10 0.10 Eastern background nitrate βext

BKPMC 3.00 3.00 Eastern background PMC βext

BKSOC 1.40 1.40 Easter background organic carbon βext

BKSSOIL 0.50 0.50 Eastern background soil βext

BKSEC 0.02 0.02 Eastern background elem. βext

BEXTRAY 10.0 10.0 Extinction due to Rayleigh scattering (1/Mm) 
I-3 

Table I-4 CALPOST Processor Input Group 3: Output Options 

Parameter Default Value Comments 

LDOC F F Print documentation image 

IPRTU 1 3 Print output units (μg/m3) for concentrations and (μg/m2/sec) 

for deposition 

L1HR T F Report 1 hr averaging times 

L3HR T F Report 3 hr averaging times 

L24HR T T Report 24 hr averaging times 

LRUNL T F Report run-length (annual) averaging times 

LT50 T F Top 50 table 

LTOPN F F Top ‘N’ table 

NTOP 4 4 Number of ‘Top-N’ values at each receptor 

ITOP 1,2,3,4 1,2,3,4 Ranks of ‘Top-N’ values at each receptor 

LEXCD F F Threshold exceedances counts 

THRESH1 -1.0 -1.0 Averaging time threshold for 1 hr averages 

THRESH3 -1.0 -1.0 Averaging time threshold for 3 hr averages 

THRESH24 -1.0 -1.0 Averaging time threshold for 24 hr averages 

THRESHN -1.0 -1.0 Averaging time threshold for NAVG-hr averages 

NDAY 0 0 Accumulation period, days 

NCOUNT 1 1 Number of exceedances allowed 

LECHO F F Echo option 

LTIME F F Time series option 

LPLT F F Plot file option 

LGRD F F Use grid format instead of DATA format 

LDEBUG F F Output information for debugging? 
J-1 

Appendix J. Chapter 3 of the CENRAP BART Modeling 

Guidelines (Tesche, et al, 2005) 

3.0 CALPUFF FORMULATION AND IMPLEMENTATION 

The RHR relates visibility attenuation to extinction coefficient (bext) which is a 

measure of light scattering and absorption due to atmospheric constituents. Values for 

bext are estimated using an empirically derived equation which relates the extinction 

coefficient to relative humidity and the following components of particulate matter mass: 

(a) sulfates (SO4); (b) nitrates (NO3); (c) organic carbon (OC); (d) elemental carbon (EC); 

(f) particulate matter (IP) (“crustal material”); and (g) coarse mass (CM) (i.e., PM10 – 

PM2.5). The BART guidance requires the use of modeled concentrations of these 

components, together with a “humidity correction factor”, to estimate values for bext on 

all days within a three year period. These estimates, when compared with naturally 

occurring background extinction, are used to determine whether a source is causing or 

contributing to visibility impairment and also to measure the effectiveness of emissions 

controls on the source aimed at mitigating such effects. EPA notes that secondary 

particulate matter constitutes an important fraction of PM2.5 and that the modeling 

requirements for secondary and primary particulate matter differ in their need to consider 

atmospheric chemistry and in the degree of spatial resolution needed for the modeling 

(EPA, 2001, pg 22). 

This chapter introduces the formulation of the CALPUFF modeling system. We 

summarize the model capabilities as described in the user’s manuals (Scire et al., 

2000a,b) and discuss the capabilities and limitations of the model. Equipped with this 

information, states and source operators can identify those situations for which screening 

and/or source-specific applications of CALPUFF are appropriate. 

In most cases, we expect that application of the CALPUFF system will be 

sufficient to meet the BART Rule requirements. For that subset of conditions requiring 

advanced methods, Chapter 5 provides details on full-science alternative models and 

available data bases for BART modeling. Such conditions might include a situation 

where the default modeling shows that a source just barely causes or contributes to 

visibility degradation or in negotiations over the final BART determination that weighs 

technical and economic feasibility against expected air quality benefits. In both 

situations, a more accurate estimate of a source’s impacts may be very important to 

source operators. 

3.1 Original Model Development 

 

The CALPUFF modeling system was originally developed as a component of a 

three-part modeling system sponsored by the California Air Resources Board (ARB) in 

the mid-1980s. The ARB sought to develop a new puff-based model, a new grid-based 

model and an improved meteorological processor that would support application of the 

two. CALGRID was the urban-scale photochemical grid model resulting from the 
J-2 

project (Yamartino et al., 1992) comparable in science and capabilities to the Urban 

Airshed Model (UAM-IV) (Scheffe and Morris, 1993). The model formulation was 

aimed at overcoming the deficiencies in EPA’s steady-state Gaussian plume models that 

were routinely used in California for inert and linearly reactive materials (principally 

SO2) from elevated point sources. Thus, the CALGRID model was designed to treat the 

complexities of urban-scale photochemical processes while CALPUFF was formulated to 

treat the non-steady state transport, diffusion, linear reaction, and deposition of primary 

pollutants from point sources. CALPUFF was not designed to address photochemical 

oxidants or and secondary aerosol formation production processes in a scientifically 

rigorous manner. 

 

In recent years, CALPUFF and its meteorological pre-processor (CALMET) have 

been used in a range of regulatory modeling studies to address point source issues that 

include complexities posed by complex terrain, large source-receptor distances, 

parameterized chemical transformation and deposition, and issues related to Class I 

visibility impacts. These applications are more complex than the California ARB’s nonsteady-state, linear chemistry formulation of the mid-1980s. 

The CALPUFF modeling system has been adopted by the EPA as a guideline 

model for source-receptor distances greater than 50 km, and for use on a case-by-case 

basis in complex flow situations for shorter distances. It was recommended for Class I 

impact assessments by the FLM Workgroup (FLAG, 2000) and the Interagency 

Workgroup on Air Quality Modeling (IWAQM) (EPA, 1998). As directed in the BART 

guidance, CALPUFF is the primary modeling system for screening and source-specific 

BART applications in the CENRAP region. Thus, examination of the model’s 

formulation provides the context for assessing the extent to which it suitable for 

simulating the various physical processes and gas-phase, aerosol, and aqueous-phase 

chemical processes that influences visibility. 

3.2 CALPUFF Model Formulation 

The CALPUFF user’s guide (Scire et al., 2000a) depicts the modeling system as 

shown in Figure 3-1. CALMET is a diagnostic/interpolation model that provides 

meteorological inputs to CALPUFF. These fields include hourly-averaged threedimensional wind and temperature fields and two-dimensional fields of mixing heights 

and other meteorological parameters. CALMET uses routine surface and aloft 

meteorological observations and/or three-dimensional output from prognostic numerical 

models such as MM5 (Grell et al., 1995) or RUC (Benjamin et al., 2004) to construct the 

meteorological inputs. Other inputs to the air quality program include emissions 

information, receptor locations, ancillary geophysical information, and estimated 

concentrations of ambient pollutants that are entrained by the modeled puffs as each is 

carried downwind. Tables 3-1 and 3-2 summarize the key features of the 

CALMET/CALPUFF models as described in the user’s guides. 

Two post-processor routines are included to facilitate cumulative source impacts 

(POSTUTIL) and estimates of light extinction and visibility attenuation at Class I 
J-3 

receptors of interest (CALPOST). In particular, CALPOST contains several options for 

computing change in extinction and deciviews for visibility assessments while the 

POSTUTIL postprocessor includes options for summing contributions of individual 

sources or groups of sources to assess cumulative impacts. POSTUTIL also contains an 

empirical nitric acid-nitrate chemical equilibrium module to estimate the cumulative 

effects of ammonia consumption by background sources once the simulation is 

completed. 

 3.2.1 Model Concept and Governing Equations 

The starting point for the CALPUFF development was the choice of the 

fundamental reference system of which there are two: Eulerian and Lagrangian. 

Consistent with the original ARB design criteria, the Lagrangian (moving puff) reference 

system was chosen for CALPUFF. In the Eulerian approach, the behavior of pollutants is 

described relative to a fixed coordinate system. The Lagrangian reference frame, in 

contrast, relates the behavior of pollutants relative to a coordinate system that moves with 

the average wind. These two approaches yield different mathematical relationships for 

pollutant concentrations that are equally valid. The choice of which approach to adopt 

depends upon the specific design goals of the modeling system. 

 The advantages and drawbacks of each approach are thoroughly discussed in the 

literature (Tesche, 1983; Seinfeld and Pandis, 1998; Jacobson, 1999; Russell and Dennis, 

2000). One of the criticisms of early Eulerian grid models was their ‘over-dilution’ of 

point source emissions into the fixed grid cells; but for the past twenty years, this 

limitation has been overcome through with the development of sub-grid-scale, plume-ingrid algorithms (Seigneur, et al., 1981; Godowitch, 2004; Karamchandani et al., 2005; 

Emery and Yarwood, 2005) and the use of multi-scale nested grids (Russell and Dennis, 

2000). While the Lagrangian approach is conceptually simple, flexible, and 

computationally inexpensive, the governing equations are not directly applicable to 

situations involving non-linear chemical reactions (Seinfeld and Pandis, (1998) and it is 

awkward to handle a large number of sources realistically. 

 3.2.2 Transport and Dispersion 

Adopting the Lagrangian concept, CALPUFF simulates the transport, dispersion, 

linear chemical transformation, and deposition of individual puffs carried downwind by 

the three-dimensional fields generated by CALMET. The model’s implementation 

follows puffs from the near source region (a few tens of meters) to hundreds of 

kilometers downwind. Its puff-based formulation, in conjunction with three-dimensional 

hourly meteorological data, allow CALPUFF to simulate the effects of time- and spacevarying meteorological conditions on pollutants emitted from a variety of source types. 

The major features and options of the CALPUFF model are summarized below: 

Building Downwash: The Huber-Snyder and Schulman-Scire downwash models are both 

incorporated into CALPUFF. An option is provided to use either model for all stacks, or 

make the choice on a stack-by-stack and wind sector-by-wind sector basis. Both 
J-4 

algorithms have been implemented in such a way as to allow the use of wind direction 

specific building dimensions. The PRIME building downwash model (Schulman et al., 

2000) is also included in CALPUFF as an option. 

Dispersion Coefficients: Turbulent dispersion in CALPUFF is treated with the K-theory 

(flux-gradient) closure scheme, defined for a Lagrangian frame of reference. Several 

options are provided in CALPUFF for the computation of dispersion coefficients, 

including the use of turbulence measurements (σv and σw), the use of similarity theory to 

estimate σv and σw from modeled surface heat and momentum fluxes, or the use of 

Pasquill-Gifford (PG) or McElroy-Pooler (MP) dispersion coefficients, or dispersion 

equations based on the CTDM. Options are provided to apply an averaging time 

correction or surface roughness length adjustments to the PG coefficients. Recently, the 

EPA AERMOD dispersion parameters have been included in CALPUFF and are used 

regularly. 

Puff Sampling Functions: Puff sampling routines are included in CALPUFF to address 

computational difficulties encountered when applying a puff model to near-field releases. 

For near-field applications during rapidly-varying meteorological conditions, an 

elongated puff (slug) sampling function may be used. An integrated puff approach may 

be used during less demanding conditions. Both techniques reproduce continuous plume 

results under the appropriate steady state conditions. 

Wind Shear Effects: A key underpinning of the Lagrangian concept is that the modeled 

puffs retain their identity over the time- and spatial-scale associated with the effects the 

model is attempting to predict (i.e., visibility impairment at 200 km or beyond) While 

discrete puffs emitted from a source retain their physical integrity for a period of time, at 

some point the action of horizontal and vertical variations in wind speed and direction 

(i.e. ‘wind shear’) shred the puff into multiple elements. These new puff parcels, 

composed of remnants of the old puff, continue to be diffused and dispersed by the wind. 

The point where significant puff shredding occurs is difficult to define since it depends 

substantially upon the complexity of the meteorological conditions and the underlying 

terrain. But when shredding occurs, the Lagrangian concept in CALPUFF breaks down. 

By ignoring puff shredding (i.e., by keeping puffs intact), the model will systematically 

over-predict pollutant concentrations. 

To deal with this conceptual limitation, CALPUFF contains an optional puff 

splitting algorithm to simulate vertical wind shear effects across individual puffs. 

Differential rates of dispersion and transport among the “new” puffs generated from the 

original, well-mixed puff act to increase the effective rate of horizontal spread of the 

material as would be expected in the real atmosphere. Puffs may also be split in the 

horizontal when the puff size becomes large relative to the grid size to account for wind 

shear across the puffs. Detailed guidance on when and how the puff-splitting algorithm 

should be used and actual verification studies demonstrating that the technique operates 

as intended are not discussed in the model documentation or presented in the science 

literature.
J-5 

Complex Terrain: Effects of complex terrain on puff transport are derived from the 

CALMET winds. In addition, puff-terrain interactions at gridded and discrete receptor 

locations are simulated using one of two algorithms that modify the puff-height (either 

that of ISCST3 or a general “plume path coefficient” adjustment), or an algorithm that 

simulates enhanced vertical dispersion derived from the weakly-stratified flow and 

dispersion module of the Complex Terrain Dispersion Model (CTDMPLUS) (Perry et al., 

1989). The puff-height adjustment algorithms rely on the receptor elevation (relative to 

the elevation at the source) and the height of the puff above the surface. The enhanced 

dispersion adjustment relies on the slope of the gridded terrain in the direction of 

transport during the time step. 

Subgrid Scale Complex Terrain (CTSG): An optional module, CTSG treats terrain 

features that are not resolved by the gridded terrain field, and is based on the 

CTDMPLUS (Perry et al., 1989). Plume impingement on subgrid-scale hills is evaluated 

at the CTSG subgroup of receptors using a dividing streamline height (Hd) to determine 

which pollutant material is deflected around the sides of a hill (below Hd) and which 

material is advected over the hill (above Hd). The local flow (near the feature) used to 

define Hd is taken from the gridded CALMET fields. As in CTDMPLUS, each feature is 

modeled in isolation with its own set of receptors. 

Overwater and Coastal Interaction Effects: The CALMET processor contains overwater 

and overland boundary layer parameterizations allowing certain of the effects of water 

bodies on plume transport, dispersion, and deposition to be estimated. In a sense, 

CALPUFF operates as a hybrid model, by utilizing gridded fields of meteorology and 

dispersion conditions as well as grid-based descriptions of underlying land use. This 

includes the abrupt changes that occur at the coastline of a major body of water. 

Dry Deposition: A resistance model is used for the computation of dry deposition rates 

of gases and particulate matter as a function of geophysical parameters, meteorological 

conditions, and pollutant species. For particles, source-specific mass distributions may 

be provided for use in the resistance model. Of particular interest for BART analyses is 

the ability to separately model the deposition of fine particulate matter (< 2.5 μm 

diameter) from coarse particulate matter (2.5-10 μm diameter). 

Wet Deposition: An empirical scavenging coefficient approach is used to compute the 

depletion and wet deposition fluxes due to precipitation scavenging. The scavenging 

coefficients are specified as a function of the pollutant and precipitation type (i.e., frozen 

vs. liquid precipitation). 

 

 3.2.3 Primary Particulates 

CALPUFF is designed to simulate PM10 or PM2.5 or other user defined size 

distributions of particles. The smaller the particles, the more they disperse like an inert 

gas. In most cases, the dispersion of inert PM2.5 particles will differ only slightly from 

that of an inert gas. A key primary PM2.5 emission from coal-fired electric generating 

units (EGUs) of relevance to visibility calculations is particulate sulfate. Although 
J-6 

primary sulfate emissions account for only a small fraction of the total sulfur emissions 

from such sources, it is appropriate to include their effect if reasonable estimates of 

primary sulfate emissions from the source are available. Treating primary sulfate 

emissions is likely to be most important at short distances from the stack before 

significant SO2 to secondary sulfate conversion has taken place. 

 3.2.4 Gas-Phase Chemistry 

Chemical reactions in the gas-phase play an important role in secondary aerosol 

formation by generating radical concentrations (e.g., the hydroxyl radical). These radical 

species oxidize SO2 and NOx, providing the precursors to aqueous–phase chemistry (i.e., 

chemistry in liquid water droplets) that convert SO2 to sulfate (e.g., H2O2 and O3), and 

form condensable gases from some volatile organic compounds (VOCs) that can then 

condense into particulate secondary organic aerosols (SOA). The levels of NOx, VOC, 

and O3 concentrations along with the reactivity of the VOCs, sunlight, temperature, and 

water vapor are all key variables that influence the radical cycle and consequent sulfate 

and nitrate formation rates. 

CALPUFF neglects realistic gas-phase processes entirely. The chemistry in 

CALPUFF parameterizes chemical transformation effects using five species (SO2, SO4

=

, 

NOx, HNO3, and NO3

-

) via a set of user-specified, diurnally-varying transformation rates. 

The model estimates secondary fine particulate matter (sulfate and nitrate) from 

emissions of gas-phase SO2 and NOx. Rather than simulating important non-linear gas 

phase oxidant chemistry, the model employs a user-supplied hourly ozone concentration 

as a surrogate for the hydroxyl radical and other oxidizing radical species. Ambient 

ammonia concentrations are also a user input along with temperature and relative 

humidity. 

Although simplifications of photochemistry have been attempted in the past, 

correct representation of the gas-phase photochemistry and the radical cycles are 

critically important in order to properly characterize sulfate and nitrate formation in the 

real atmosphere. Seigneur et al., (2000) demonstrated this fact in their evaluation of fullscience representations of photochemistry against simplified representations (but more 

advanced than CALPUFF). They concluded that simplified linearized transformation 

schemes are inadequate for describing sulfate and nitrate formation processes: 

“These results indicate that the accurate prediction of source-receptor 

relationships for PM2.5 requires a comprehensive treatment of PM2.5 formation 

from gaseous precursors for the secondary components of PM2.5 and a spatially 

resolved treatment of transport processes for primary PM2.5. Simplified 

treatments of either atmospheric chemistry or transport are appropriate only when 

the secondary or primary components of PM2.5, respectively, are not significant. 

Therefore, the development of source-receptor relationships for PM2.5 should be 

based on air quality models that provide comprehensive descriptions of 

atmospheric chemistry and transport.” 
J-7 

Morris et al., (1998) also compared the sulfate and nitrate particulate estimates from a 

comprehensive full-science regional model with those from a model incorporating a 

simplified empirical chemical mechanism developed in a manner similar to the 

mechanism in CALPUFF. Evaluating the full-science and empirical chemistry models 

against observed concentrations, Morris and co-workers concluded: 

“Given the importance of the radical cycle for determining secondary PM 

formation rates, it appears that empirical gas-phase algorithms are inadequate for 

determining secondary PM formation.” 

The uncertainty and potential biases introduced into the CALPUFF visibility estimates 

due to neglect of gas phase oxidant chemistry remain unknown. 

3.2.5 Aerosol Chemistry 

 

Formation of secondary fine particulate matter (e. g., nitrates, sulfates, organic 

aerosols) in point source plumes is strongly dependent on the rate of mixing with ambient 

(background) air and the chemical composition of this background. The rates of 

oxidation of sulfur dioxide (SO2) and nitrogen dioxide (NO2) to sulfate and nitric acid can 

be very different within a power plant or industrial plume compared to that in the 

background air (Gillani and Godowitch, 1999; Karamchandani et al., 2000). Similarly, 

the formation of secondary organic aerosols from emitted VOCs and those from other 

anthropogenic and biogenic sources, adds yet another pathway in the formation of 

visibility-impairing aerosols. The presence of atmospheric ammonia introduces further 

nonlinearities into the gas phase and aerosol reactions. Accordingly, for a model to 

realistically simulate the production of secondary particulate sulfate, nitrate, and organic 

aerosols from a potential BART source, the mixing processes and chemical reactions 

within and outside of the plume must be treated realistically. If the chemical interactions 

between these two fundamentally different and interactive chemical environments are 

overly-simplified or neglected altogether, the ability of the model to correctly calculate 

plume concentrations, deposition, or visibility impacts is lost. 

Sulfate and Nitrate Formation. Two SO2 and NOx chemical transformation schemes are 

available in CALPUFF: the MESOPUFF-II algorithm (Scire et al., 1983; Atkinson et al., 

1982) and the RIVAD algorithm (Latimer et al., 1986). These algorithms calculate 

sulfate and nitrate formation rates based on the puff concentrations, background 

environmental parameters provided by CALMET, and background ozone and ammonia 

concentrations provided as input by the user. SOA particulates are not treated by either 

mechanism. The parameters used are as follows (note that each method does not use all 

of these parameters). 

Puff Average Concentrations (from CALPUFF)

• NOx concentration 

• SO2 concentration 

Environmental Parameters (from CALMET)
J-8 

• Temperature 

• Surface Relative Humidity (RH) 

• Atmospheric Stability 

• Solar Radiation 

Background Concentrations (User Input)

• Ozone (O3) 

• Ammonia (NH3) 

The MESOPUFF-II chemical transformation scheme is EPA’s recommended approach 

for Class I area impact assessment (IWAQM, 1998). It entails pathways for five active 

pollutants (SO2, SO4, NOx, HNO3, and NO3) as follows: 

k1

SO2 Æ SO4

k2

NOx Æ HNO3 (+RNO3) 

k3

NOx Æ HNO3

NH3

HNO3 (g) ÅÆ NO3 (PM) 

where, 

SO2 is the puff average sulfur dioxide concentration; 

NOx is the puff average oxides of nitrogen concentrations; 

SO4 is sulfate concentrations formed from the SO2; 

HNO3 is the nitric acid formed from the NOx; 

NO3 is the particulate nitrate that is in equilibrium with the nitric acid; and 

NH3 is the background ammonia concentration. 

Daytime Rates

k1 = 36 x R0.55 x [O3]

0.71 x S-1.29 + k1(aq) 

k1(aq) = 3 x 10-8 x RH4 (added to k1 above during the day) 

k2 = 1206 x [O3]

1.5 x S-1.41 x [NOx]-0.33

k3 = 1261 x [O3]

1.45 x S-1.34 x [NOx]-0.12 

Nighttime Rates

k1 = 0.20 (%/hr) 

k2 = 0.00 (%/hr) 

k3 = 2.00 (%/hr) 

with, 
J-9 

k1 is the SO2 to SO4 gas-phase transformation rate (%/hr)

k1(aq) is the SO2 to SO4 aqueous-phase transformation rate (%/hr) 

k2 is the NOx to HNO3+RNO3 transformation rate (%/hr) 

k3 is the NOx to HNO3 (only) transformation rate (%/hr) 

S is the stability index ranging from 2 to 6 

(PGT class A&B=2, C=3, D=4, E=5, F=6) 

R is the total solar radiation intensity (kw/m2

) 

RH is the relative humidity (%) 

[O3] is the user provided background ozone concentrations (ppm) 

[NOx] is the plume average NOx concentration (ppm) 

NH3 is the user provided background ammonia concentrations 

Daytime chemical transformations are based on statistically analyzed hourly 

transformation rates (Scire et al., 1983) obtained from box model simulations using the 

Atkinson et al., (1982) photochemical mechanism. In this scheme, gas-phase oxidation of 

SO2 and NOx depends on the hydroxyl (OH) radical concentrations for which 

background ozone, solar intensity (R), and stability index are used as surrogates. At 

night, OH concentrations are much lower and default SO2 and NOx oxidation rates of 0.2 

%/hr and 2.0 %/hr are assumed. The k1(aq) sulfate formation rate is added to the k1 rate 

during the day as a surrogate for aqueous-phase sulfate formation which begins to assume 

importance above approximately 50% RH (~0.2 %/hr sulfate formation rate) and peaks at 

100% RH (3%/hr sulfate formation rate). 

The sulfate and nitrate formation rate equations used in the MESOPUFF II 

scheme were originally generated by developing regression equations for a few key 

variables on the results of 144 box model simulations that used the 1982 photochemical 

mechanism of Atkinson et al. These box model simulations varied ambient temperature, 

ozone concentration, sunlight intensity, VOC concentrations, atmospheric stability, and 

plume NOx concentrations as shown in Table 3-1. The actual environmental conditions 

used to generate the sulfate and nitrate transformation equations were extremely limited. 

For example, the transformation rates did not cover temperatures below 10 deg C (50 deg 

F) or cleaner rural atmospheric conditions with VOC concentrations less than 50 ppbC. 

The CALPUFF MESOPUFF-II chemistry clearly neglects several environmental 

parameters and chemical processes that are important in simulating sulfate and nitrate 

formation in NOX/SO2 emissions source plumes. In many cases these deficiencies lead to 

an overestimation bias of the source’s sulfate and nitrate impacts. Factors that lead such 

a bias include: 

Lack of Temperature Effects: Photochemistry is known to be highly temperature 

sensitive, as evidenced by the fact that elevated ozone concentrations tend to 

occur on hot summer days. Lower temperatures produce lower OH and other 

radical concentrations and consequently lower sulfate and nitrate formation rates. 

The CALPUFF sulfate and nitrate formation rates, however, do not adequately 

incorporate temperature effects. The MESOPUFF-II chemical transformation 

algorithm was developed under conditions with a minimum temperature of only 
J-10 

10° C (50° F). Thus, under conditions colder than 10° C, CALPUFF will 

overpredict sulfate and nitrate formation rates and impacts. CALPUFF typically 

estimates maximum sulfate and visibility impacts during the late fall/early spring 

and winter months; these are the same months when the CALPUFF 

overestimation bias from not considering temperature effects will be greatest. In 

addition, under colder temperatures, NOx will be converted to peroxyacetyl 

nitrate (PAN) so that the NOx is no longer available to be converted to nitrate. 

Since the CALPUFF chemistry ignores the PAN sink for NOx, it will 

systematically overpredict nitrate impacts. 

Effects of NOx Emissions on Sulfate Chemistry: Downwind of a point source 

with significant NOx/SO2 emissions, high NOx and SO2 concentrations co-exist. 

Under high NOx concentrations, radical concentrations are greatly reduced, 

resulting in very low ozone, sulfate, and nitrate formation rates. This is due to the 

NOx inhibition effect on photochemistry whereby: (1) the titration of NO with 

ozone eliminates ozone and its source as a radical generator; and (2) the high NO2

concentrations eliminate the OH radical via the NO2 + OH reaction thereby 

effectively shutting down photochemistry. Thus, in a NOx/SO2 point source 

plume near the source, there will be very low OH radical and ozone 

concentrations and consequently very low sulfate and nitrate formation. Since the 

simple MESOPUFF-II transformation equations cannot account for the NOx 

effect on the sulfate formation, CALPUFF will tend to over-predict sulfate 

formation rate in a NOx/SO2 point source plume near the source, which in turn 

leads to overstating the sulfate formation rate. Because NOx/SO2 point sources 

are typically buoyant, they are frequently be emitted aloft in a stable layer where 

the high NOx concentrations and inhibited sulfate and nitrate formation rates 

could persist 100 km or more downwind. 

Aqueous-Phase Sulfate Formation Algorithm. CALPUFF’s MESOPUFF-II chemistry 

treats aqueous-phase sulfate formation solely as a function of relative humidity (RH), 

which actually has no direct affect on aqueous-phase sulfate formation chemistry. The 

CALPUFF MESOPUFF-II aqueous-phase sulfate formation rate ranges from values of 

approximately 0.2 %/hr at 50% RH to 3.0 %/hr at 100% RH. Relative humidity (RH) is a 

measure of the content of water vapor in the atmosphere. However, in reality aqueousphase sulfate formation will depend on the amount of atmospheric liquid water content 

(LWC) in cloud or fog droplets, the pH of the water droplets, and the level of H2O2, 

ozone, and SO2 concentrations. Accordingly, in the atmosphere, aqueous-phase sulfate 

formation chemistry is not affected by RH. Thus, the CALPUFF aqueous-phase 

chemistry parameterization is incorrect. Although under conditions of clouds and fog 

there will be high RH, the occurrence of high RH with very little or no clouds or fog can 

be quite frequent. 

In a liquid water droplet, the reaction of SO2 with H2O2 to form sulfate is 

essentially instantaneous and is usually limited by the amount of H2O2 present (i.e., 

oxidant limited) for a NOx/SO2 point source. Once the H2O2 is reacted away within the 

water droplet, sulfate formation via this pathway slows to the rate of H2O2 formation, 
J-11 

which would be extremely slow to nonexistent in a large point source plume due to the 

scavenging of radicals by the high NOx concentrations. This introduces an inaccurate 

representation of sulfate formation in CALPUFF that creates uncertainties and bias in 

modeled visibility impacts. Whether this uncertainty results in an under- or overestimate 

of sulfate formation is difficult to determine since the approach is scientifically invalid. 

Under conditions of high RH and little clouds or little plume interaction with clouds, it 

will clearly overstate sulfate formation. However, under conditions of cloudy conditions 

with available photochemical oxidants (i.e., H2O2 and O3) and a dilute NOx/Sox point 

source plume, it may understate sulfate formation. Near large NOx/SO2 point source 

where the elevated NOx concentrations scavenge and limit photochemical oxidants, the 

MESOPUFF-II algorithm will likely overstates sulfate formation. 

Thus, the CALPUFF aerosol chemistry fails to account for many environmental 

parameters that are necessary to simulate sulfate and nitrate formation rates, including 

VOCs and their reactivity, temperature, liquid water content, and NOx concentrations. In 

their evaluations against full-science PM models and observations, Seigneur et al., (2000) 

and Morris et al., (1998) both independently found that the empirical chemistry modules, 

such as employed by CALPUFF, are inadequate for estimating sulfate and nitrate 

formation. These findings are supported by EPA’s PM2.5 and Regional Haze SIP 

modeling guidance (EPA, 2001) that recommends against using Lagrangian models such 

as CALPUFF for simulating secondary PM. 

 From the foregoing, it is clear that the CALPUFF chemical transformation 

algorithms neglect important chemical processes necessary to accurately estimate the 

sulfate and nitrate impacts due to SO2 and NOX emissions. Given that EPA recommends 

the model for BART determinations, a key question is “What is the influence of the 

simplified chemistry on modeled estimates of visibility impacts from BART sources? In 

some cases, the inadequacies in the CALPUFF chemistry algorithms may simply 

introduce broader uncertainties into the calculation of estimated sulfate and nitrate 

impacts. In many cases, however, the simplifications made in the CALPUFF description 

of chemical processes result in a systematic bias in the estimated concentrations and 

visibility impacts due to SO2 and NOX emissions sources. For large point sources that 

emit SO2 and NOx emissions, such as EGUs, petrochemical process heaters, cement plant 

kilns, etc., many of the limitations in the CALPUFF MESOPUFF-II SO2 and NOx 

transformation algorithms would result in an overestimation bias. While models that are 

systematically biased high (i.e., over-predict impacts) may be appealing to regulatory 

decision-makers because they are ‘conservative’, the overprediction tendency may well 

lead to unwarranted and excessive control of emissions from some sources. Thus, the 

tradeoff between simplicity and conservativism on the one hand and technical credibility 

and unbiased answers on the other is a key element in the negotiation of modeling 

protocols developed by the states or source operators. 

 3.2.6 Surface Removal 

An especially important contributor to particulate concentrations is the rate of 

deposition to the surface. PM2.5 particles, which have a mass median diameter around 0.5 
J-12 

μm, have an average net deposition velocity of about 1 cm/min (or about 14 m/day) and 

thus the deposition of fine particles is not usually significant except for ground-level 

emissions. On the other hand, coarse particles (those PM10 particles larger than PM2.5) 

have an average deposition velocity of more than 1 m/min (or 1440 m/day), which is 

significant, even for emissions from elevated stacks. 

CALPUFF includes parametric representations of particle and gas deposition in 

terms of atmospheric, deposition layer, and vegetation layer “resistances” and, for 

particles, the gravitational settling speed. Gravitational settling, which is of particular 

importance for the coarse fraction of PM10, is accounted for in the calculation of the 

deposition velocity. Effects of inertial impaction (important for the upper part of the PM10

distribution) and Brownian motion (important for small, sub-micron particles) and wet 

scavenging are also addressed. The BART guidance recommends that fine particulate 

matter (less than 2.5 μm diameter), which has higher light extinction efficiency than 

coarse particulate matter (2.5-10 μm diameters), should be treated separately in the 

model. CALPUFF allows for user-specified size categories to be treated as separate 

species, which includes calculating size-specific dry deposition velocities for each size 

category. 

3.3 CALMET Meteorological Preprocessor 

The CALMET meteorological model consists of a diagnostic wind field module 

and micrometeorological modules for over-water and overland boundary layers. When 

modeling a large geographical area such as the CENRAP domain, the user has the option 

to use a Lambert Conformal Projection coordinate system to account for Earth’s 

curvature. The major features and options of the meteorological model are summarized in 

Table 3-1. The techniques used in the CALMET model are briefly described below. 

3.3.1 Boundary Layer Modules 

The CALMET processor contains two boundary layer modules for application to 

overland and overwater grid cells. 

Overland Boundary Layer Module: Over land surfaces, the energy balance method of 

Holtslag and van Ulden (1983) is used to compute hourly gridded fields of the sensible 

heat flux, surface friction velocity, Monin-Obukhov length, and convective velocity 

scale. Mixing heights are determined from the computed hourly surface heat fluxes and 

observed temperature soundings using a modified Carson (1973) method based on Maul 

(1980). The module also determines gridded fields of PGT stability class and hourly 

precipitation rates. 

Overwater Boundary Layer Module: The aerodynamic and thermal properties of water 

surfaces suggest that a different method is needed for estimating boundary layer 

parameters in the marine environment. A profile technique, using air-sea temperature 

differences, is used in CALMET to compute the micro-meteorological parameters in the 

marine boundary layer. An upwind-looking spatial averaging scheme is optionally 
J-13 

applied to the mixing heights and three-dimensional temperature fields in order to 

account for important advective effects. 

3.3.2 CALMET Diagnostic Wind Field Module 

The CALMET wind model was constructed from two other meteorological 

models used in California in the late 1970s. One was the California Institute of 

Technology (CIT) mass consistent interpolation model described by Goodin et al., 

(1980). The other was the Complex Terrain Wind Model (CTWM) developed at Systems 

Applications, Inc. (Tesche and Yocke, 1978; Yocke and Liu, 1978). The CTWM terrain 

adjustments used to modify the flow fields were assembled in the 1970s as part of 

research into fire spread and avalanche forecasting in mountainous regions of California. 

Various heuristic algorithms were developed to approximate down slope drainage flows, 

terrain blocking and channeling (Geiger, 1965), thermal heat islands (Stern and Malkus, 

1953), surface friction retardation, capping by an elevated inversion and so on. These 

algorithms were based on empirical studies in wind tunnels, numerical modeling 

experiments, and field studies in the Alps, some dating back to the 1930s (Defant, 1933). 

Later work by Tesche et al., (1986), Kessler et al., (1987) and Douglas and Kessler 

(1988) integrated the CIT and CTWM modeling system into a single meteorological 

model that included algorithms to blend observational data with prognostic 

meteorological model output. The combined model was used extensively for urban-scale 

ozone studies throughout the U.S. prior to the switch to MM5 as the preferred 

meteorological model for SIP studies in the mid-1990s. 

The CALMET model development incorporated the main features of the CTWM 

and CIT wind model and significantly updated the physical parameterizations and 

improved model input/output (I/O) schemes (Scire et al., 2000a). Today, CALMET uses 

the CTWM two-step approach to the computation of the wind fields. In the first step, an 

‘initial-guess’ wind field is constructed and then adjusted to approximate the kinematic 

effects of terrain, slope flows, and terrain blocking. Currently, the gridded MM5 field is 

used as the initial guess prior to terrain-perturbation. The second step consists of an 

objective analysis procedure to blend the MM5 field with observational data to produce a 

final wind field. This introduction of observational data in the second step of the 

CALMET wind field development is optional. It is also possible to run the model in “no 

observations” (No-Obs) mode, which involves the use only of MM5 gridded data for the 

initial guess field followed by fine-scale terrain adjustments on the scale of the CALMET 

domain. 

Normally, the CALMET computational domain is specified to be at smaller grid 

spacing than the MM5 dataset used to initialize the initial guess field. For example, 

36/12 km MM5 data sets available for 2000-2003 over the CENRAP domain have been 

used to develop the 6 km CALMET grids shown in Figures 5-1 through 5-4. 

The current thermal, kinematic, and dynamic effects parameterized in CALMET, 

used in the first step of the windfield development, are as follows: 
J-14 

Kinematic Effects of Terrain: The CTWM algorithms for kinematic effects (Liu and 

Yocke, 1980) is used to evaluate the influence of the terrain on the wind field. The initial 

guess field winds are used to compute a terrain-forced vertical velocity, subject to an 

exponential, stability-dependent decay function. The effects of terrain on the horizontal 

wind components are evaluated by applying a divergence-minimization scheme to the 

initial guess wind field. The divergence minimization scheme is applied iteratively until 

the three-dimensional divergence is less than a threshold value. 

Slope Flows: The original slope flow algorithm (Defant, 1933) has been upgraded (Scire 

and Robe, 1997) based on the shooting flow algorithm of Mahrt (1982). This scheme 

includes both advective-gravity and equilibrium flow regimes. At night, the slope flow 

model parameterizes the flow down the sides of the valley walls into the floor of the 

valley, and during the day, upslope flows are parameterized. The magnitude of the slope 

flow depends on the local surface sensible heat flux and local terrain gradients. The slope 

flow wind components are added to the wind field adjusted for kinematic effects. 

Blocking Effects: The thermodynamic blocking effects of terrain on the wind flow are 

parameterized in terms of the local Froude number (Allwine and Whiteman, 1985). If the 

Froude number at a particular grid point is less than a critical value and the wind has an 

uphill component, the wind direction is adjusted to be tangent to the terrain. 

3.4 Estimation of Regional Haze Contributions 

The default procedure for quantifying visibility impacts is described in 

several documents (IWAQM, 1998; FLAG, 2000). Implementation of these 

procedures in CALPUFF is described in the user’s documentation (Scire et al., 

2000b). Generally, ‘visibility’ may be quantified either by visual range (the 

greatest distance that a large object can be seen) or by the light extinction 

coefficient, which is a measure of the light attenuation per unit distance due to 

scattering and absorption by gases and particles. Visibility is impaired when light 

is scattered in and out of the line of sight and by light absorbed along the line of 

sight. The light extinction coefficient (bext) considers light extinction by scattering 

(bscat) and absorption (babs): 

 

b

ext

 = b

scat

 + b

abs

 

The scattering components of extinction (bscat) are represented by light scattering 

due to air molecules (i.e., Rayleigh scattering, brayleigh) and light scattering due to 

particles, bsp. The absorption components of extinction (babs) include light 

absorption due to gases (bag) and particles (bap). Furthermore, particle 

scattering, bsp, can be expressed by its components: 

 

b

sp

 = b

SO4

 + b

NO3

 + b

OC

 + b

SOIL

+ b

Coarse

 

where the chemical species and soot scattering coefficients are given as: 
J-15 

 

b

SO4 = 3 [(NH4

)

2

SO

4

] f(RH) 

b

NO3 = 3 [NH4

NO

3

]f(RH) 

b

OC = 4 [OC] 

b

SOIL= [Soil] 

b

Coarse= 0.6 [Coarse Mass] 

 

b

ap = 10 [EC] 

 

The numeric coefficient at the beginning of each equation is the dry scattering or 

absorption efficiency in meters-squared per gram. The f(RH) term is a monthlyaverage relative humidity adjustment factor. The terms in the brackets are the 

estimated concentrations fro CALPUFF (or other model) in micrograms per cubic 

meter (μg/m3

). 

 

Finally, the total atmospheric extinction is estimated as: 

 

b

ext

 = b

SO4

 + b

NO3

 + b

OC

 + b

SOIL

+ b

Coarse

+ b

ap

+ b

rayleigh 

or, substituting in the above terms, 

 bext = 3 f(RH) [(NH4)2SO4] + 3 f(RH) [NH4NO3] + 4[OC] + 

1[Soil] + (3-1) 

 + 0.6[Coarse Mass] + 10[EC] + bRay

This is the so-called IMPROVE extinction equation currently recommended by 

EPA (2003). Note that the sulfate (SO4) and nitrate (NO3) components are 

hygroscopic because their extinction coefficients depend upon relative humidity. 

The concentrations, in square brackets, are in μg/m3

 and bext is in units of Mm-1. 

The Rayleigh scattering term (bRay) has a default value of 10 Mm-1, as 

recommended in EPA guidance for tracking reasonable progress (EPA, 2003a). 

The effect of relative humidity variability on the extinction coefficients for SO4 and 

NO3 can be estimated in several ways, but following the EPA BART guidelines, 

the Class I area-specific monthly f(RH) values shown in Table 6-1 should be 

used. 

 

Modeled ground level concentrations of each of the above visibility 

impairing pollutants are used with the IMPROVE equation to deduce the 

extinction coefficient. The change in visibility (measured in terms of ‘deciviews’) 

is compared against background conditions. The delta-deciview, Δdv, value is 
J-16 

calculated from the source’s contribution to extinction, bsource, and background 

extinction, bbackground, as follows:

 

Δdv = 10 ln((bbackground

+ bsource)/ bbackground) 

 

The impact of a source is determined by comparing the Δdv, or haze index (HI), for 

estimated natural background conditions with the impact of the source and without the 

impact of the source. If the Δdv value is greater than the 0.5 dv threshold the source is 

said to contribute to visibility impairment and is thus subject to BART controls. 

CALPOST uses a previous IMPROVE f(RH) curve (FLAG, 2000) which differs 

slightly from the f(RH) now used by IMPROVE and EPA (2003), mainly at high relative 

humidity. Also, CALPOST sets the maximum RH at 98% by default (although the user 

can change it), while the EPA’s guidance now caps it at 95% (easily modified in the 

CALPUFF input file). 

For regional haze light extinction calculations, use of a plume-simulating model 

such as CALPUFF is appropriate only when the plume is sufficiently diffuse that it is not 

visually discernible as a plume per se, but nevertheless its presence could alter the 

visibility through the background haze. The IWAQM Phase 2 report states that such 

conditions occur starting 30 to 50 km from a source. This is consistent with the BART 

guidance recommendation for using CALPUFF for source-receptor distances greater than 

50 km. But, CALPUFF is also recommended by EPA as an option that can be considered 

for shorter transport distances when the plume may in fact be discernible from the 

background haze. 

Apart from the chemistry issues discussed previously, there do not appear to be 

any major reasons why CALPUFF cannot be used for even shorter transport distances 

than 30 km, as long as the scale of the plume is larger than the scale of the output grid so 

that the maximum concentrations and the width of the plume are adequately represented 

and so that the sub-grid details of plume structure can be ignored when estimating effects 

on light extinction. The standard 1-km output grid that has been established for Class I 

area analyses should serve down to source-receptor distances somewhat under 30 km; 

how much closer than 30 km will depend on the topography and meteorology of the area 

and should be evaluated on a case-by-case basis with individual CENRAP State 

modelers. (For reference, the width of a Gaussian plume, 2σy, is roughly 1 km after 10 

km of travel distance, assuming Pasquill-Gifford dispersion rates under neutral 

conditions.) 

3.4.1 CALPOST Methods 

Calculation of the impact of the simulated plume particulate matter component 

concentrations on light extinction is carried out in the CALPOST postprocessor. For 

BART applications, this processor is of considerable importance. 
J-17 

CALPOST is used to process the CALPUFF outputs, producing tabulations that 

summarize the results of the simulations, identifying for example, the highest and secondhighest hourly-average concentrations at each receptor. When performing visibilityrelated modeling, CALPOST uses concentrations from CALPUFF to compute light 

extinction and related measures of visibility (deciviews), reporting these for a 24-hour 

averaging time. The CALPOST processor contains several options for evaluating visibility 

impacts, including the method described in the BART guidance, which uses monthly 

average relative humidity values. CALPOST contains implementations of the IWAQMrecommended and FLAG-recommended visibility techniques and additional options to 

evaluate the impact of natural weather events (fog, rain and snow) on background visibility 

and visibility impacts from modeled sources. CALPOST uses Equation 3-1 to calculate 

the extinction increment due to the source of interest and provides various methods for 

estimating the background extinction against which the increment is compared in terms 

of percent or deciviews. 

For background extinction, the CALPOST processor contains seven techniques 

for computing the change in light extinction due to a source or group of sources (i.e., 

Methods 1 through 7). These are usually reported as 24-hour average values, consistent 

with EPA and FLM guidance. In addition, there are two techniques for computing the 

24-hour average change in extinction (i.e., as the ratio of 24-hour average extinctions, or 

as the average of 24-hour ratios). Method 2 is the current default, recommended by both 

IWAQM (EPA, 1998) and FLAG (2000) for source-specific. Method 6 is recommended 

by EPA’s BART guidance (70 FR 39162). 

In Method 2, user-specified, speciated monthly concentration values are used to 

describe the background. When applied to natural conditions, for which EPA’s default 

natural conditions concentrations are annual averages, the same component 

concentrations would have to be used throughout the year (unless potential refinements to 

those default values resulted in concentrations that vary during the year). Hourly 

background extinction is then calculated using these concentrations and hourly, sitespecific f(RH) from a 1993 IWAQM curve or, optionally, the EPA regional haze f(RH) 

curve.

2

 Again the RH is capped at either 98% (default) or a user-selected value (most 

commonly at 95%). 

Method 6 is similar to Method 2, except monthly f(RH) values (e.g., EPA’s 

monthly climatologically representative values) are used in place of hourly values for 

calculating both the extinction impact of the source emissions and the background 

conditions extinction. Hourly source impacts, with the effect on extinction due to sulfates 

and nitrates calculated using the monthly-average relative humidity in f(RH), are 

compared against the monthly default natural background concentrations. Thus the 

monthly-averaged relative humidity is applied to the hygroscopic components (i.e., 

sulfate and nitrate) of both the source impact and the background extinction with Method 

6. 

 

2

 Note that the hourly-varying natural background extinction here is not consistent with that prescribed by 

the EPA’s natural conditions guidance (EPA, 2003b), for which a “climatologically-representative” f(RH) 

that only varies monthly is to be used. Method 6 uses these monthly average humidity values. 
J-18 

3.4.2 POSTUTIL 

The POSTUTIL processor allows the cumulative impacts of multiple sources 

from different simulations to be summed, including computing the difference between 

two sets of predicted impacts (useful for evaluating the benefits of BART controls). It 

also contains a chemistry module to evaluate the equilibrium relationship between nitric 

acid and nitrate aerosols. This capability allows the potential non-linear effects of 

ammonia scavenging by background sulfate and nitrate sources to be approximated in the 

formation of nitrate from an individual source. The processor can compute the impacts 

of individual sources or groups of sources on sulfur and nitrogen deposition into aquatic, 

forest and coastal ecosystems, thereby allowing changes in deposition fluxes resulting 

from changes in emissions to be quantified. 

The POSTUTIL processor attempts to overcome the bias introduced when 

CALPUFF assumes that the full background ammonia concentration is entrained into 

each discrete puff. For a single puff, this may be satisfactory, but the model 

overestimates the production of ammonium nitrate when multiple puffs co-exist and 

overlap. The POSTUTIL processor re-partitions the ammonia and nitric acid 

concentrations to conform to the ammonia-limiting processes influencing nitrate 

formation. Though based on recognized science, this approximate post-processing 

method is fundamentally dependent on reliable estimates of ambient NH3 at the Class I 

receptor of interest. 

3.4.3 Refined Extinction and Background Visibility Estimates 

EPA, the IMPROVE Steering Committee, and the RPOs are evaluating whether 

refinements are warranted to the methods recommended for calculating extinction and the 

default estimate of natural background visibility. Whether EPA will approve of any 

changes to the IMPROVE equation is uncertain at this time. Also, the responsibility for 

incorporating any changes to the algorithms in CALPUFF (e.g., new f(RH) curves) is 

unclear. If changes to these methods are recommended by EPA, CENRAP is encouraged 

to adopt them. However, details of the process for incorporation of any refinements to 

the IMPROVE equations in the CALPUFF system should be addressed in the State’s or 

source operators modeling protocol. 

3.5 Model Availability 

The EPA-approved version of the CALPUFF modeling system is available from 

Earth Tech, Inc., (http://www.src.com/calpuff/calpuff1.htm). The main models 

(CALMET, CALPUFF, and CALPOST), their GUIs, and many of the processors are 

available to download. One may also register to receive notices of model updates. The 

most recent update to the system (25 May 2005) is a new version of CALMM5 (MM5 

V3) that has been added to the Download BETA-Test page. This version of CALMM5 

processes MM5 Version 3 output data directly. 
J-19 

Earth Tech offers CALPUFF training courses that include a description of the 

technical formulation of the models, overviews of each of the processor programs, and 

hands-on application of the models to several case study data sets. Attendees of the 

course receive a training notebook, a workbook of case study problems, exercises, and 

data sets, updates on recent and future model enhancements, and the latest (proprietary) 

versions of the models and Graphical User Interfaces (GUIs). Other third-party training 

courses and materials are also available. 

3.6 CALPUFF Evaluation Studies 

Tesche (2002, 2003) reviewed results of various CALPUFF evaluation studies 

and reached the following conclusions: 

> There is a paucity of model evaluation information for CALPUFF at 

scales of 50 to 200 km and beyond; 

> Based on the limited information available, CALPUFF may be able to 

give unbiased estimates of short-term (i.e., 3-10 hr) concentrations of nonreactive contaminants to within a factor of two (e.g. 200%) out to 

distances of about 200 km from a source. This level or uncertainty in a 

200 km radius around a source is increased if one examines CALPUFF’s 

predictions in a particular modeling cell (e.g., one containing a population 

center) at a specific hour as opposed to considering the question of bias 

generally over the entire 200 km region irrespective of location and time 

of occurrence; 

> For time periods of a day or less, CALPUFF is unable to produce reliable 

predictions of non-reactive concentrations at a specific location and time; 

> What limited experimental data do exist suggest that the accuracy and 

reliability of the model’s predictions degrade as the distance scale 

increases; 

> While the IWAQM recommendations on the range of applicability of the 

CALPUFF model (50 to 200 km) rests on very sparse model evaluation 

information, EPA’s suggestion that the model can be used for scales 

beyond 200 km, even with case-by-case approval, is not based on model 

evaluation data; and 

> For chemically reactive pollutants such as SO2, NOx, sulfate, nitrate, nitric 

acid, and other secondary reaction products, the testing of CALPUFF 

model over extended spatial scales (50 km and beyond) has not been 

attempted in a rigorous manner. 

Scire et al., (2001) report an evaluation of CALPUFF sulfate, nitrate, light 

extinction, and sulfur and nitrogen deposition at a Class I areas over a range of source-
J-20 

receptor distances. In this study, in which a large number of sources were modeled 

simultaneously, sulfate and nitrate predictions at the CASTNet monitoring site in 

Pinedale, Wyoming were evaluated against observations, and light extinction predictions 

were evaluated using transmissometer measurements. Wet sulfur and nitrogen 

predictions were compared to observations at several acid deposition monitoring sites. 

This study is especially relevant because it evaluates the performance of the model to 

predict variables of direct interest in Class I visibility analyses, such as sulfate and nitrate 

concentrations and light extinction coefficients 

More recently, Chang et al., (2003) reported an intercomparison of CALPUFF 

with two other transport and dispersion models with high resolution field data. CALPUFF 

predictions for inert SF6 were compared using two recent mesoscale field datasets: the 

Dipole Pride 26 (DP26) and the Overland Along-wind Dispersion (OLAD). Both field 

experiments involved instantaneous releases of sulfur hexafluoride tracer gas in a 

mesoscale region with desert basins and mountains. Tracer concentrations were observed 

along lines of samplers at distances up to 20 km. CALPUFF predictions were evaluated 

using the maximum 3-h dosage (concentration integrated over time) along a sampling 

line. At the DP26 sampler array, CALPUFF had mean biases within 35% and random 

scatters of about a factor of 3–4. About 50%–60% of the CALPUFF predictions were 

within a factor of 2 of the observations. At the OLAD site, the model underpredicted by 

a factor of 2–3, on average, with random scatters of a factor of 3–7. Only about 25%–

30% of the CALPUFF predictions of inert SF6 were within a factor of 2 of observations. 

The tracer studies with which CALPUFF transport and diffusion capabilities were 

evaluated in the IWAQM Phase 2 report were generally over distances greater than 50 

km. More recently, model performance has been performed at shorter distances including 

a power plant in Illinois in simple terrain at source-receptor distances in arcs ranging 

from 0.5 km to 50 km from the stack (Strimaitis et al., 1998). Another CALPUFF 

evaluation study over short-distances is reported by Morrison et al. (2003). These 

studies address model performance over source-receptor distances from a few hundred 

meters to 50 km. 
J-21 

Figure 3-1. CALPUFF Modeling System Components. (Scire et al., 2000a) 
J-22 

Table 3-1. Major Features of the CALMET Meteorological Model. (Scire et al., 

2000b)

 • Boundary Layer Modules of CALMET 

 - Overland Boundary Layer - Energy Balance Method 

 - Overwater Boundary Layer - Profile Method 

 - Produces Gridded Fields of: 

 -- Surface Friction Velocity 

 -- Convective Velocity Scale 

 -- Monin-Obukhov Length 

 -- Mixing Height 

 -- PGT Stability Class 

 -- Air Temperature (3-D) 

 -- Precipitation Rate 

 • Diagnostic Wind Field Module of CALMET

 - Slope Flows 

 - Kinematic Terrain Effects 

 - Terrain Blocking Effects 

 - Divergence Minimization 

 - Produces Gridded Fields of U, V, W Wind Components 

 - Inputs Include Domain-Scale Winds, Observations, and 

 (optionally) Coarse-Grid Prognostic Model Winds 

 - Lambert Conformal Projection Capability 
J-23 

Table 3-2. Major Features of the CALPUFF Dispersion Model (Scire et al., 2000a) 

 • Source types

 - Point sources (constant or variable emissions) 

 - Line sources (constant or variable emissions) 

 - Volume sources (constant or variable emissions) 

 - Area sources (constant or variable emissions) 

 • Non-steady-state emissions and meteorological conditions

 - Gridded 3-D fields of meteorological variables (winds, temperature) 

- Spatially-variable fields of mixing height, friction velocity, convective 

velocity scale, 

 Monin-Obukhov length, precipitation rate 

 - Vertically and horizontally-varying turbulence and dispersion rates 

 - Time-dependent source and emissions data for point, area, and volume 

sources 

 - Temporal or wind-dependent scaling factors for emission rates, for all 

source types 

 • Interface to the Emissions Production Model (EPM)

 - Time-varying heat flux and emissions from controlled burns and 

wildfires 

 • Efficient sampling functions

 - Integrated puff formulation 

 - Elongated puff (slug) formulation 

 • Dispersion coefficient (σy, σz) options

 - Direct measurements of σv and σw

 - Estimated values of σv and σw based on similarity theory 

 - Pasquill-Gifford (PG) dispersion coefficients (rural areas) 

 - McElroy-Pooler (MP) dispersion coefficients (urban areas) 

 - CTDM dispersion coefficients (neutral/stable) 

 • Vertical wind shear

 - Puff splitting 

 - Differential advection and dispersion 

 • Plume rise

 - Buoyant and momentum rise 

 - Stack tip effects 

 - Building downwash effects 

 - Partial penetration 

 - Vertical wind shear 

 • Building downwash
J-24 

 - Huber-Snyder method 

 - Schulman-Scire method 

 - PRIME method 

 

Table 3-2. Major Features of the CALPUFF Dispersion Model (Concluded). 

 • Complex terrain

 - Steering effects in CALMET wind field 

 - Optional puff height adjustment: ISC3 or "plume path coefficient" 

 - Optional enhanced vertical dispersion (neutral/weakly stable flow in 

CTDMPLUS) 

 • Subgrid scale complex terrain (CTSG option)

 - Dividing streamline, Hd, as in CTDMPLUS: 

 - Above Hd, material flows over the hill and experiences altered 

diffusion rates 

 - Below Hd, material deflects around the hill, splits, and wraps 

around the hill 

 • Dry Deposition 

 - Gases and particulate matter 

 - Three options: 

- Full treatment of space and time variations of deposition with a 

resistance model 

 - User-specified diurnal cycles for each pollutant 

 - No dry deposition 

 • Overwater and coastal interaction effects

 - Overwater boundary layer parameters 

 - Abrupt change in meteorological conditions, plume dispersion at 

coastal boundary 

 - Plume fumigation 

 • Chemical transformation options

- Pseudo-first-order chemical mechanism for SO2, SO=

4, NOx, HNO3, and 

NO3 

(MESOPUFF II method) 

 - Pseudo-first-order chemical mechanism for SO2, SO=

4, NO, NO2 HNO3, 

and NO3 (RIVAD/ARM3 method) 

 - User-specified diurnal cycles of transformation rates 

 - No chemical conversion 
J-25 

 • Wet Removal

 - Scavenging coefficient approach 

 - Removal rate a function of precipitation intensity and precipitation type 
J-26 

Table 3-3. Parameter Variations in Box Model Simulations Used to Develop the 

CALPUFF Sulfate and Nitrate Formation Algorithms. (Morris et al., 

2003).

Surrogate 

Parameter 

Number of 

Variations 

Model Input Parameters And Variations 

Season 3 Temperatures of 30, 20 and 10 °C were used for the, 

respectively, summer, fall and winter seasons. 

Diurnally varying clear skies solar radiation was 

assumed for each season corresponding to a latitude 

of 40°. 

Background Air 

Reactivity 

4 For the summer season the following four levels of 

background ozone and VOCs were used: 

Ozone 

(ppb) 

VOC 

(ppbC) 

20 50 

50 250 

80 500 

200 2,000 

For fall and winter the ozone concentrations were 

assumed to be 75% and 50% of the summer levels. 

Dispersion 2 Two different rates of plume dispersion were used: 

(1) a stable case with a wind speed of 1.5 m/s and; (2) 

a slightly unstable case with a wind speed of 5.0 m/s. 

Release Time 2 Photochemical box model simulations were 

performed with release times of sunrise and noon. 

Plume NOx 

Concentration 

3 Initial plume NOx concentrations of 7, 350 and 1400 

ppb were used. 
Appendix 9.2B 

BART Exemption CALPUFF Modeling Input and 

Output Files 
Appendix 9.2C 

Subject-to-BART CALPUFF Post Control Modeling 

Input and Output Files