# EMISSION TEST REPORT

Performance Test
Of the 

# Lime Scrubber System
Associated with the 

# Plant 2 Kiln (EPN NK-1)

At the 

# Tiffany Brick Company LP dba Hanson Brick

Located in 

# Elgin, Texas

Prepared for 

# Hanson Brick, Inc.

October 2007 TRC Project No. 154785

# EMISSION TEST REPORT
Performance Testing

Of the 

# Lime Scrubber System
Associated with the 

# Plant 2 Kiln (EPN NK-1)

At the 

# Tiffany Brick Company LP dba Hanson Brick

Located in 

# Elgin, Texas

Prepared for 

# Hanson Brick, Inc.

October 2007 TRC Project No. 154785

# TABLE OF CONTENTS

INTRODUCTION 1 Table 1: Background Data 2 SUMMARY OF RESULTS 4 Table 2: Summary of Results Plant 2 Kiln Scrubber 5 PROCESS DESCRIPTION 6 ANALYTICAL TECHNIQUE 7 Table 3: Analytical Instrumentation 11 Figure 1: Sample System Diagram 12 Figure 2: PM System Diagram 12 QUALITY ASSURANCE ACTIVITIES 13 APPENDICES A. Field Data Sheets B. Example Calculations C. Quality Assurance Activities D. Calibration Certifications E. Data Acquisition/Gas Chromatograms/Ion Chromatograms F. Process Data

# INTRODUCTION

A performance test of the Lime Scrubber associated with the Plant 2 Kiln designated as EPN NK-1 (Plant 2 Kiln Scrubber) was conducted at the Tiffany Brick Company LP dba Hanson Brick (Hanson Brick) Elgin Facility, located at 506 Highway 290 East, Elgin, Bastrop County, Texas. The purpose of this test was to satisfy pennit requirements for Texas Commission on Environmental Quality (TCEQ) Permit #48992, Special Condition 12. TRC of Austin, Texas conducted the testing on October 21, 2007. TCEQ Pennit #48992 requires that the Plant 2 Kiln Scrubber be tested to establish the actual quantities of nitrogen oxides (NOx), carbon dioxide (CO), sulfur dioxide (S02), particulate matter (PM), and opacity being emitted from the Plant 2 Kiln Scrubber. In addition, the removal efficiency of hydrogen fluoride (HF), hydrogen chloride (HCl), and S02 was determined as required. The tests followed the procedures set forth in the Code of Federal ReQulations, Title 40, Part 60, Appendix A Methods 1, 2, 3A, 4, 5, 6C, 7E, 9, 10, 18, 25A and 26. Table 1 summarizes the background information pertinent to these tests. 

## This report has been reviewed and approved for submittal to the TCEQ by the following 

# representatives:

; 

# V

, 

# ~ 

# /

TR : ared by Hanson Brick 

# ~~C ~~ TRC: Reviewed by

# TABLE 1 BACKGROUND DATA Facility Owner/Operator: Tiffany Brick Company LP Dba Hanson Brick 506 Highway 290 East Elgin, Texas 78621 Attn: Brad George TEL (713) 466-6306 FAX (713) 466-6357 Test Contractor: TRC 9225 U. S. Highway 183 South Austin, Texas 78747 Attn: Jason Grizzle TEL (512) 243-0202 FAX (512) 243-0222 Test Participants: Hanson Brick Brad George Kevin Emberton Paul Anderson TRC Jason Grizzle ShunilJacob Jeff Militar Thor Olsen Paul Campbell Ryan McDonald Cody Jaysek Test Dates: October 21, 2007 Location: Elgin, Bastrop County, Texas Emission Points: Feed Rates from the Plant 2 Kiln Scrubber Inlet were measured from a 41.75-inch internal diameter duct. See diagrams in Appendix A. Emissions from the Plant 2 Kiln Scrubber Exhaust were measured from a 55-inch internal diameter exhaust stack. See diagrams in Appendix A.

2

## Test Methods: EPA Method 1 for traverse point location EPA Method 2 for stack volumetric flow EPA Method 3A for 02 / COz concentrations EPA Method 4 for stack gas moisture content EPA Method 5 for particulate matter emissions EPA Method 6 for S02 concentrations EPA Method 7E for NOx concentrations EPA Method 9 for opacity determinations EPA Method 10 for CO concentrations EPA Method 18 for methane and ethane concentrations EPA Method 25A for stack THC concentrations EPA Method 26 for HF and HCl concentrations

# SUMMARY OF RESULTS

On October 21, 2007, a performance test was conducted on the Lime Scrubber associated with the Plant 2 Kiln designated as EPN NK-1 (Plant 2 Kiln Scrubber), at the Tiffany Brick Company LP dba Hanson Brick (Hanson Brick) Elgin Facility, located in Elgin, Bastrop County, Texas. The purpose of the performance tests was to measure the nitrogen oxides (NOx), carbon monoxide (CO), sulfixr dioxide (SOz), particulate matter (PM), volatile organic compounds (VOC), and opacity emissions from the Plant 2 Kiln Scrubber as required by the Texas Commission on Environmental Quality (TCEQ) Permit #48992. In addition, the removal efficiencies of hydrogen fluoride (HF), hydrogen chloride (HCl) and S02 were determined as required by TCEQ Pennit #48992. The test matrix consisted of three one-hour test runs conducted on the Plant 2 Kiln Scrubber while operating at maximum conditions. During each test run, quantities of HF, HCl, and S02 were measured at the inlet and exhaust of the scrubber in conjunction with the volumetric flow rates of each. The feed and emission rates for HF, HCl, and S02 were calculated using the concentration and corresponding volumetric flow rates measured during each run. The removal efficiencies of HF, HCI, and SOZ were calculated from the feed and emission rates using the following equation.

CE (%) =(Inlet Loadine (lb/hr) - Outlet Emission Rate (lb/hr) x 100

Inlet Loading (lb/hr) In conjunction with the determination of the removal efficiencies, the emission rates of NOx, CO, PM, and VOC were detennined over three, one-hour test runs. During each run the quantities of NOx, CO, PM, and VOC were measured from the exhaust of the Plant 2 Kiln Scrubber along with the volumetric flow rates. The emission rates of NOx, CO, PM, and VOC were calculated using the concentrations and corresponding volumetric flow rate measured during each run. The visible emissions from the Plant 2 Kiln Scrubber were determined over a six-minute period during each test run to determine the compliance status with the TCEQ Permit # 48992. For the determination of VOCs being emitted from the Plant 2 Kiln Scrubber, the methane and ethane concentrations as propane were subtracted from the concentrations of total hydrocarbons (THC) during each test run. The THC concentrations are determined on a propane basis. Table 2 provides the summary for these performance tests of the Plant 2 Kiln Scrubber while being operated at the maximum conditions. All field data sheets utilized in this testing are presented in Appendix A of this report. Example calculations are located in Appendix B. Quality assurance activities are documented in Appendix C. Calibration certifications supporting the results are in Appendix D. Data acquisition and chromatograms records from TRC instrumentation can be found in Appendix E. Process data is contained in Appendix F.



# 10

# TABLE 2 Summary of Results
Hanson Brick Elgin, Texas Technicians: JSG, SJ, JM, PC, TO, RAM, CJ Project Number: 154785


### SOURCE HIln 2 Scrubber TEST RUN 1 2 3 Avera es Date 10/21/2007 10/21/2007 10/21/2007. Star[ Time 10:53 13:05 16:02 Stop Time,~~'* 11:53 1tA4:0a5t 17:02 ~ C~$Su.".L , ~ A ll ..t ~ 

### Lime Feed Rate (lb/hr) 167 167 167 167 Number of Cars (Cars/Day) 28 28 28 28 Tons of Brlck Fired (tons/hr) 10.56 10.56 10.56 10.56 Kiln Combustible Air Pressure (PSIG) 15.13 13.65 ND 14.39 Kiln Natrual Gas Pressure (PSIG) 42 42 42 42 Kiln Overpressure Fan Speed (RPM) 2,508 2,508 2,508 2,508 Itiln P*,ressure (inH2O)Y -0.15~$ -0.08 ND -0.11 

### Atmospheric Pressure (in. Hg) 29.37 29.35 29.31 29.35 Wet Bulb (°F) 70 70 71 70 Dry Bulb (°F) 84 84 87 85 Humidity ~(~](bs/.Ib of air)

. ~~qp~ 0.50283 0.0283g 0.0314 0.0293 uv~u.p.9. '~1' ~~ ~~F„~ 3'+i {~C d~ E~~' ., I" S'St ry,.. HaCtf}'~w^.'k'" ~C°' ..~ ... Volumetric Flow (DSCFH) 1,333,675 1,357,007 1,293,257 1,327,980 Volumetric Flow (WSCFH) 1,415,149 1,447,621 1,375,350 1,412,707 HF (ppmv, dry) 27.5 44.2 46.5 39.4 HCI (ppmv, dry) 9.01 17.9 35.7 20.8 SOi (ppmv, dry) 193 153 161 169 HF Qb/]v) 1.90 3.11 3.1 2.71 HCl (Ib/hr) 1.14 2.29 4.4 2.60 SOi (]b/hr) { ~ 42.8 34.4 34.7 37.3

~1 T



### e ~.`~a ~t''~ Volumetric Flow (DSCFH) 1,333,675 1,357,007 1,293,257 1,327,980 Volumetric Flow (WSCFH) 1,415,149 1,447,621 1,375,350 1,412,707 Oi (vol %, dry) 18.4 18.3 18.4 18.4 COz (vol %, dry) 1.9 1.8 1.7 1.8 NOx (ppmv, dry) 8.8 9.8 10.2 9.6 CO (ppmv, dry) 120 116 118 118 SOi (Ppmv, dry) 19.3 21.9 24.6 21.9 HF (ppmv, dry) 0.12 0.05 0.07 0.08 HCl (ppmv, dry) 0.17 0.09 0.38 0.21 VOC (ppmv, wet) 4.64 2.85 5.06 4.18 NOx (Ib/hr) 1.40 1.59 1.57 1.52 CO (Ib/]v) 11.6 11.4 11.1 11.4 SOi (Ib/Iv) 4.27 4.93 5.29 4.83 HF (]b/lv) 0.0080 0.0035 0.0050 0.0055 'HCI (lb/hr) 0.021 0.011 0.046 0.026 VOC (Ib/Iv) 0.75 0.47 0.79 0.67 Filterable PM (Ib/hr) 0.62 0.59 0.55 0.59 Filterable PM (Ib/tons of Fired Brick) 0.06 0.06 0.05 0.06 Total Suspended PM (]b/hr) 2.55 2.44 2.25 2.42 Opacity (%) 0.63 0.00 0.21 0.28 v,yu Wffp,~
, .~P~C~: ~ ;:s, 4 ;x:.n. I: SOi (%) 90.01 85.68 84.73 86.81 HF ((%) 99.58 99.89 99.84 99.77 HC1(%) _. .. 98.16 99.52 . 98.95 98.88 ND- No Data 4.33 14.73 51.97 0.40 0.81 1.51 

### 5.13 0.12 

### 5.13 5 > 

### 31 95 97 

# TRC s

# PROCESS DESCRIPTION

Tiffany Brick Company LP dba Hanson Brick owns and operates a brick manufacturing facility located at 506 Highway 290 East, Elgin, Bastrop County, Texas. Within the facility is a Lime Scrubber associated with the Plant 2 Kiln designated as EPN NK-1, which controls the hydrogen fluoride (HF), hydrogen chloride (HF) and sulfur dioxide (S02) emissions. The Elgin Plant 2 kiln was built in 1999 by Ceric hic. Bricks are set on the kiln cars in the green state and proceed from the extrusion and setting department to the holding room. The holding room holds the brick until the dryer needs a car of bricks. The bricks exit the dryer with less than %2 

## % moisture and proceed into the kiln. The cars are pushed through the kiln with a large hydraulic cylinder. A car of brick is charged into the kiln approximately every 51 minutes, 24 hours per day, seven days per week. The kiln can be described as a large counter flow heat exchanger. The first 2/3 of the kiln is the firing section. The heat is inputed into the brick by gradually increasing temperature zones until it reaches top temperature of approximately 2060 F. The heat is supplied by a number of natural gas burners installed in the roof and sides of the kiln. The hot gases from the burners in the first 2/3 of the kiln flow counter to the brick travel from the hottest zone to the exhaust section of the kiln. The air from the beginning of the cooling zone and the firing zone is drawn to the front of the kiln and out the kiln exhaust. The exhaust temperature of the gases is approximately 350 F. The last 1/3 of the tunnel kiln is the cooling section. The brick are cooled quickly as they exit the hottest firing zone until they reach 1300 F. The ambient air from the exit of the kiln is passed over the brick with the exit end fan and lowers the brick temperature and heats the air to approximately 600F. The 600F air is ducted to the dryer to dry the extrusion water from our brick. No additional gas or fuel is required to dry the brick. The exhaust gases of the Plant 2 Kiln are routed to the scrubber by the automatic valvesystem. The recirculated lime material is fed into the flue gas piping using frequencycontrolled metering screws, and the fresh lime using a frequency-controlled metering screw, at various positions, and therefore into the flue gases. The sorption process commences when the material is fed in. There is a process air connection in the flue gas piping upstream of the filter unit which is fitted with an automatic valve. This valve is used to ensure that the flue gas temperature is reduced to the maximum permissible operating temperature of the filter medium if necessary before entering the filter unit. The flue gases enriched by the absorbing agents are fed into the filter unit, where the bound pollutants are filtered out of the flue gases together with the absorption material using the filter media. The flue gases (clean gases) are fed to the fan and then, to the exhaust downstream of the filter unit.

C

# ANALYTICAL TECHNIQUE

The sampling and analysis procedures used during these tests conformed in principle with those outlined in the Code of Federal Regulations, Title 40, Part 60, Appendix A, Methods 1, 2, 3A, 4, 5, 6C, 7E, 9, 10, 18, 25A and 26. The sampling and analysis system used to determine exhaust emission concentrations is depicted in Figure 1. Stack gas entered the sample system through a heated stainless steel probe with a glass wool filter. The sample was transported via 3/8-inch heat-traced Teflon® tubing using a stainless steel/Teflon® diaphragm pump to the wet portion of the sample manifold. The sample was then delivered to a specially designed stainless steel minimum-contact condenser that dried the sample without removing the pollutants of interest before being passed back to the dry portion of the sample manifold. From the dry manifold, the sample was partitioned to the analyzers through glass rotameters that controlled the flow of the sample. Figure 1 shows that the sampling system was equipped with a separate path through which a calibration gas could be delivered to the probe and back through the entire sampling system. This allowed for convenient performance of system bias checks and calibrations as required by the testing methods. All instruments were housed in an air-conditioned trailer-mounted mobile laboratory. Gaseous calibration standards were provided in aluminum cylinders with the concentrations certified by the vendor, where applicable. All data from the continuous monitoring instruments were recorded by a computer data acquisition system. The data was recorded at one-minute intervals. Velocity determinations using EPA Methods 1 and 2 were conducted during each test run. The number and locations of the traverse points were determined according to the procedures outlined in EPA Method 1. Velocity measurements at the outlet location were made using a Type S pitot tube conforming to the geometric specifications outlined in EPA Method 2. Differential pressures were measured with an oil-inclined manometer. Gas temperatures were measured with a K-type thermocouple equipped with digital readouts. The configuration of the system is such that the outlet flow rates and the inlet flow rates are equivalent, so no inlet flow rates were determined during the testing series. The stack gas analyses for CO2 and 02 concentrations were performed by Method 3A. This analysis was performed on the exhaust outlet samples collected during the testing. A nondispersive infrared analyzer was used for CO2 concentration analyses. 02 concentration analyses were performed by a paramagnetic analyzer. Exhaust stack moisture was determined by US EPA Method 4. Stack gas was extracted and pulled through a series of iced standard impingers. The dry gas volume was measured with a dry gas meter after the impinger train and sampling pump. The amount

7

## of moisture collected was determined gravimetrically. This sampling train was combined

with the US EPA Method 5 sampling train depicted in Figure 2. US EPA Method 5 was used to determine concentrations of particulate matter, with the addition of condensable particulate recovered as required by the TCEQ regulations. Figure 2 shows that a gaseous sample was pulled through a stainless steel nozzle and heated borosilicate glass lined probe to a heated glass fiber filter. This portion of the sample train is utilized to determine filterable particulate matter. The nozzle was sized such that an isokinetic sampling rate (i.e. sampling at the same rate as the stack velocity) could be maintained within the capabilities of the sample pump. Following the filter, the sample was pulled through an impinger train to a dry gas meter and sample pump. The impingers were charged with de-ionized water. Filter and probe temperatures were maintained at the temperature range specified in the method [248 f 

## 25°F] for each PM test run on the Plant 2 Kiln Scrubber. The weight gain of the acetone rinse plus the weight gain of the filter constitute the filterable PM analysis. The back half of the filter holder, connecting glassware and impingers constitute the condensable PM assembly. The first impinger contents from each test run were saved after weighing the impingers for moisture content determination. The solutions from the first impinger were combined with the back half of the filter holder and connecting glassware and saved. Each of these solutions was measured for volume. The collection was then evaporated and weighed at TRC's Austin laboratory to determine weight gain. The weight gain of these impinger evaporations constitutes the condensable, PM analyses. All EPA Method 5 particulate matter weights were determined with an AND HR-120 analytical balance. This balance has a 120-gram capacity and 0.0001-gram sensitivity. The balance was leveled and zeroed before each series of weighing. All weighing of filters and beakers were repeated until a"constant weight" was obtained. A"constant weight" is defined in EPA Method 5 as a difference of no more than 0.5 mg or 1 percent of the total weight less tare weight, whichever is greater. This definition applies to two consecutive measurements with no less than 6 hours of desiccation time between weights. The sample recovery data sheets in Appendix A describe the weighing times and dates. The difference between weighing is recorded to establish that a constant weight had been obtained. In cases where a weight loss is apparent, the minimum detection limit of the scale as described above is recorded. All S02 concentrations contained in this report were obtained using the procedures of US EPA Method 6C (i.e. instrumental analysis). The instrument used for this analysis is based on the principle of ultraviolet absorption. Concentrations of NOx were determined using the instrumental analyzer procedure described in US EPA Method 7E. Sample gas was continuously extracted from the source and a portion of the sample was directed to a chemiluminescent analyzer for analysis of NOx. All NOx is reported as NO2 as per EPA convention.

9

## Opacity was determined using the procedures of US EPA Method 9. These tests were

conducted during daytime hours that met the sun angle specifications of the method. A certified visible emission observer conducted these test run, a certificate of the individual can be found in Appendix D. Appendix A provides the opacity observation sheets. Concentrations of CO were quantified during the tests in accordance with procedures set forth in US EPA Method 10. A continuous non-dispersive infrared (NDIR) analyzer was used for this purpose. This analyzer is equipped with a gas correlation filter, which also removes any interference from CO2 or other combustion products, eliminating the need for ascarite traps, and the associated con

- ection factors. hiterference response tests on the instruments were conducted by the instrument vendors and TRC on the analyzers. The sum of the interference responses for H2O, methane, NH3, S02, Hz, NOZ, NOx, CO, COz and 02 (as appropriate for each analyzer) are less than t2 percent of the applicable full-scale span value. The instruments used for the tests meet the performance specifications for US EPA Methods. The results of these direct interference tests are available in Appendix C of this report. Methane and ethane concentrations of the exhaust gases were determined by US EPA Method 18. The methane and ethane concentrations were detennined by a gas sample that was continuously extracted from the source and injected onto a gas chromatograph. The Hewlett Packard 5890 Series lI gas chromatograph is equipped with a dual channel; heated gas sampling valve for sample injections, 1.0 cc sample loop, split/splitless injector, capillary column, and a flame ionization detector. The capillary column used for organic compound separation was a 30 meter SGE capillary column (30BP-1-1.0). Conditions for the separation were as follows: 

# Head pressure: 3 psig Sample loop Temp: 160°C hiitial Oven Temp: 40°C Initial Time: l Omin Prior to the collection of data, TRC used calibration standards containing propane to confum compound relative retention times. Pollutant concentrations were determined using sample detector response to propane. All methane and ethane concentrations were based on the propane calibration curves. These concentrations were used to con•ect the THC concentrations for the methane and ethane portion to calculate the VOC concentrations of the exhaust stream. THC concentrations were determined according to the procedures outlined in US EPA Method 25A. A continuous sample of stack gas was directed into a heated hydrocarbon analyzer. This instrument operates on the principle of flame ionization, in which combustion of hydrocarbons results in the generation of carbon ions. This process yields a current directly proportional to the carbon content of the molecules in the gas stream. The current is converted to voltage output and recorded continuously with a computerized data acquisition system.

~

## Concentrations of HF and HCl were determined using the procedures of US EPA Method

26. A sample of stack gas was pulled through a series of chilled impingers and then through calibrated dry gas meter with a pump. A series of four impingers were used in the sample train with the first two containing 100m1 of a O.1N H2SO4 solution, the third impinger was empty, and the fmal impinger contained an indicating silica gel before being drawn through the dry gas meter. Leak checks of the sampling train were conducted prior to and following each test run. Following testing, the samples were recovered in the TRC's mobile laboratory. The contents of the first two impingers were transferred to a graduated cylinder. The iinpingers and connecting glassware were rinsed three times with Deionized water and these rinses were added to the graduated cylinder. The total volume of liquid collected was recorded and the sample were transferred to a HPDE bottle and sealed for analysis by ion chromatogram. Analysis of the halogens was performed by US EPA Method 26 (analysis by ion chromatography). Samples were analyzed using a Dionex ion chromatograph. Sample analysis was performed in the TRC mobile laboratory following collection. A five-point standard curve was generated to quantify each of the ions (fluoride and chloride). Conditions for the Dionex Model ICS-90 ion chromatograph were as follows: Eluent Flow: Eluent Pressure Loop Size: Pre-Column: Column: Eluent: Regen: 2.0 ml/min

5 psig 10 μl IonPac AG14A 37042 IonPac AS 14A 4mm 10-32 18 mM Na2CO3/ 10 mM NaHCO3 0.01 N H2SO4

10

# TABLE 3 LIST OF ANALYTICAL INSTRUMENTATION

Models antl Calibration Minimum Serial Parameter Manufacturers Span Sensitivity Number Detection Principle NOx CalifomiaAnalytical 0-50.6ppm O.lppm 6MI2004 ThertnalreductionofNO i [oNO.

400-CLD Chemiluminescent reaction ofNO with excess of ozone. Detectionbyphotomultiplierarphotodiode. Inherently linear for ranges listed

CO TEC048C 0-496 ppm 0.2 ppm 48C-73966-375 Infrared absorption, gas filter correlatfon deteclor Microprocessor based linearization.

COz Servomex1400 0-10.07% 0.02% 01415C/2650 Infraredabsorption,analoglinearizaitonsolid state detector 02 Servomex1400 0-10.05% 0.10% 01420Cl/2534 Paramagneticcell,orelectrochemicalcell all detection pdncipals are inherently Iinear uver a wide range. SOz Ametek 921 0-44.3 ppm 0.5 ppm AW-921-6232 Absorbance ofUV light at two frequencies Dual cell instrument with matched photo detectors and lamp currenl conlol. Calculation of concentration by Beer Lambert Law Hydrocarbon HewlettPackard 0-lOppm 0.5ppm Flame ionization of hydrocarbons. Capillary Species 5890aGasChroma- 0-100ppm CH4 analyticalcolunmforcompoundsepamtion.

togmph with dual 0-1000 ppm Gas sample size variable with sample loops channel FIDs 0-100 % and split mtios. THC Model 3-100 0-100 ppm 0.5 ppm 9309261-33 Flame ionization ofhydrocarbons Inherently linear over 4 orders of magnitude.
Temperature Omega HH-26K -I20 to 2000 °F 0.1 °F n/a Chromel-alumel K-Type thennocouple with digitial thertnometer. Respnse time based on thermocouple design Opera[ing range is defined by the calibration gzses used during the test (per EPA Methods 3A, 6C, 7E, 10, 20, and 25A).



# 11

# FIGURE 1: SAMPLE SYSTEM DIAGRAM

FIGURE 2: PM SYSTEM DIAGRAM

TemperaNreSensor

HealeE Zone


# ~ Mammeier Thermometer
Slack Wall



# ~ f—TemperaNre Sensor

~ Probe 8 Noule rPiWtTube



# 12

# QUALITY ASSURANCE ACTIVITIES

A number of quality assurance activities were undertaken before, during, and after this testing project to ensure the accuracy of results obtained. This section of the report and the documentation contained in Appendices C and D describe each quality assurance activity that was performed. Sampling and analyses, where appropriate, were conducted on-site to afford any interested parties the opportunity to observe all aspects of the test and to circumvent the possibility of sample loss or contamination during transport. Each instrument's response was checked and adjusted in the field prior to the collection of data via multi-point calibration (calibration error). The instrument's linearity was checked by first adjusting the zero and span responses to zero (nitrogen) and an upscale calibration gas in the range of the expected concentrations. The instrument response was then challenged with other calibration gases of known concentration and accepted as linear if the response of the other calibration gases agreed within t2 percent of range (t5 percent of calibration gas for THC only) of the predicted values. The data acquisition logs that present the results of the initial multi-point linearity test are provided in Appendix E. Before and after each test run, the sample system was checked for zero and upscale bias (Except for THC). This allowed each test run to be bracketed by calibrations and documented the precision of the collected data. The criterion for acceptable data is that the sample system bias is within t5 percent for both the zero and upscale calibration gases. Documentation of sample system bias also allowed for the use of Equation 7E-4 to assess drift. The criterion for acceptable data is that the drift assessment not exceed 3 percent for both the zero and upscale calibration gases. The Quality Assurance worksheets in Appendix C summarize all multipoint calibration checks and the zero and upscale checks performed during the tests. Equation 7E-5 was used for the correction of gas concentrations for sample system bias. When two consecutive test runs were conducted one after the other, the final bias test for the previous run was used for the initial bias test of the subsequent run. In cases where there was a sufficient delay between test runs to deem this strategy invalid, a separate initial calibration was conducted and the response from this calibration was used in Equation 7E-5. Prior to testing a NOx converter efficiency check was conducted as required by EPA Method 7E. To conduct this test, a NO2 calibration gas in nitrogen balance was used as allowed by method. The NOx response of the analyzer is monitored until the concentration reading stabilizes. The response of the analyzer is then recorded and the converter efficiency is calculated using the response of the analyzer and the actual concentration of the certified NO2 gas. The converter is acceptable if the analyzer indicates a response of 90% or greater.

13

## The instrumental sampling system was leak checked by demonstrating that a vacuum

greater than 10" Hg could be held for at least 1 minute with a decline of less than 1" Hg. A leak test was conducted after a sample system was set up and before that system was dismantled. These tests were conducted to ensure that ambient air had not diluted the sample. No leaks were found during the post-test leak checks. The absence of leaks in the sampling system was also verified by sample system bias checks. The sampling system's integrity was tested by comparing the responses of each of the analyzers used to a calibration gas introduced via two paths. The first path was into the analyzer via the zero/span calibration manifold (direct to the analyzers). The second path was to introduce a calibration gas into the sample system at the sample probe via the calibration line and switching valve. Any difference in the instrument responses by these two methods was attributed to sampling system bias. Quality Assurance worksheets in Appendix C show that the analyzer responses via both sample paths agreed within acceptable limits. All bias check results are summarized in the Quality Assurance Worksheets in Appendix C. Response time tests were conducted on site on the sample system utilized during the tests. The control gases used to calibrate the instruments were analyzed and certified by the compressed gas vendors to tl% accuracy or EPA Protocol Procedure Gl, as applicable. The gas calibration sheets as prepared by the vendor are contained in Appendix D. Appendix D also contains calibration data on the altimeter, dry gas meter, and pitot tubes. The dry gas meters used for the methods that require one were calibrated prior to testing in accordance with EPA methodology. A post test calibration check was also conducted on the meter. Calibration certification documentation of the dry gas meters can be found in Appendix C. That documentation shows that the difference between the pre and post test calibrations differed by less than 5% as required All glassware was thoroughly washed, rinsed, dried, and stored with protection to prevent contamination. Pre-weighed filters were sealed against contamination and packed safely. Reagent grade acetone (HPLC grade) and Deionized water were used for the washing of the sampling train as appropriate to the method. A blank of the acetone and the water were treated in the same manner as the samples and retained for evaporation and weighing for contaminants. A blank filter was also weighed after treating it in the same manner as the filters used during sampling. Each Method 5 sample train was leak-checked in accordance with Method 5, before and after each test run. If leaks were found prior to the test they were corrected before the test run started. No leaks were found after the test runs; therefore, no leak compensation was performed, and no test runs were voided. Isokinetic sampling rates were achieved and checked in the field at each traverse point as well as over the entire test run period. Isokinetics between 90% and 110% over the test run are required for Method 5. The isokinetic calculation spreadsheets of Appendix A show that the sample rate was within acceptable limits.

14

## The nozzles utilized for isokinetic sampling were checked prior to the sampling event per

the stipulations of EPA Method 5, §5.1. The nozzles were measured with a micrometer upon the completion of sampling, and the post-test nozzle area was used for data reduction. VOC concentrations were determined by US EPA Method 18. Provisions were made to introduce the calibration gases to the instruments under the same conditions as that of the samples. Propane standards were injected to establish a calibration standard curve prior to sample analysis. Calibration standards injections were repeated until area counts of propane from three separate injections agreed to within 5% of their average. Each test run consists of a minimum of 5 inj ections of sample gas. Upon completion of testing, the mid-range standard was injected to verify the absence of instrument dri8. This calibration check was used to ensure that the instrument response had not varied by more than 5%. If a variance of greater than 5% was observed, the calibration process was repeated and the average of the two calibration curves would be used to determine concentrations. All calibrations for the US EPA Method 18 were conducted through the entire sample system. The dry gas meters used for the HF and HCl sample trains were calibrated prior to testing in accordance with EPA Method 5. A post test calibration check was also conducted on the dry gas meters. A standard dry gas meter traceable to NIST was used for the initial annual calibration and critical orifices used for the post test checks. Calibration certification documentation of the dry gas meter can be found in Appendix C. That documentation shows that the difference between the pre and post test calibrations differed by less than 5% as required by the regulations. Each Method 26 sample train was leak-checked in accordance with Method 5, before and after each test run. If leaks were found prior to the test, they were corrected before the test run started. No leaks were found after the test runs; therefore, no leak compensation was performed, and no test runs were voided. HF and HCl concentrations were detennined by US EPA Method 26. Calibration standards injections were repeated until area counts of each ion from duplicate injections agreed to within 5% of their average. Sample runs consist of a minimum of two injections that agreed to within 5% of their average. Upon completion of testing standards were injected to verify the instrument drift. Duplicate injections were made until the areas agreed to within 5% of their average. The average of the pre and post calibration curves was used to determine the concentrations of HF and HCI. TRC collected and reported the enclosed test data in accordance with the procedures and quality assurance activities described in this test report. TRC makes no wan

- anty as to the suitability of the test methods. TRC assumes no liability relating to the interpretation and use of the test data.

15

# APPENDIX A: FIELD DATA SHEETS

### 1— 

## FIELD TEST PARTICIPANT SIGN IN SHEET

Job Name: 00,A^5VII 

# ~ r` Cle DATE(S): 

# 1 /a /Zl ( e - rJoli Number: /S

- q PERMIT# 

# 4 8 9 9a Plant Name/Location: cC Emission Source(s): 40

~ 

## 2 Svt, ~ 

## PARTICIPANTS: TRC Environmental Corporation Test Contractor
/',a..."S un T>riL 

## Owner/Operator 

## TGFQ 3egulatory Agency

Name: Affiliation: Position: Telepbone Number



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# TRC v3.0_052007

### Stack Diagram (Draw side view showing major compones, dimensions, upstream/downstream Flow disturbances)



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....... ._.. .-_.. 

### E
*Stack diameters > 24 in shall have no traverse points located wli'n 1 in of the stack wall *Stack diameters 5 24 in shall have no traverse points located w!n 0.5 in of the stack wall 50 '5 1.0 1.5 2.0 2.5 Particulate Traverses

t 40

30 24 u ~ 25• 20 20 slacktllameter>24in 

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outldzmeurs aownNwem Rcm nowa stoNZnm lo¢dnce el

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### *Port 

## Length ° Offset ~



### s E 

### s fi Traverse Number of Traverse Points Point 4 6 8 

### Number I Percent distances 

### 1 6.7 4.4 3.2 2.1 2 25.0 14.6 10.5 6.7 3 75.0 29.6 19.4 11.8 4 93.3 70.4 32.3 17.7 5 85.4 67.7 25.0 6 95.6 80.6 35.6 7 89.5 64.4 8 96.8 75.0 9= 82.3 10 - 88.2 11 = 93.3 12 = - 97.9



# Circular Stack Sampling Traverse Point Layout

(EPA Method 1) Date: 

## /D~~P~~ Plant: 1~2n9~~ ~ 

### iicLe 

### Source: Technician(s): 

# Ts

~ j 

### Port+ Stack ID (in): Port Extension (in): 

# ~ Stack ID (in): 2

~ 

### y, :75

- " 

### Stack Area (ft2): 

## 9. S Duct Diameters upstream from flow disturbance (A): ~ 

### Duct Diameters downstream from flow disturbance (B): ~ 

### Total Required Traverse Points: 17- 

### No. of Traverse Points per Diameter: 61

Stack cross section

.. .

~

~

\



### Draw traverse point layout above Unit Information



# ._ _. <- - E- -° ✓ F - 

# -

~ 

### - 

# -I- <-

+ 3ot 

## 2ti /

r 1

misemPonl



## OTRC

## Stratification Test (Method 7E ) Company: Hanson Brick Plant: Elgin Facility Location: Elgin, Texas Technicians: JSG, JM, SJ, RAM, PC, TO, CJ Source: Plant 2 Kiln Scrubber Inlet Is Stack Diameter or Equivalent Diameter greater than 7.8 ft?
S02 Point (ppmv) 1 185.55 2 194.63 3 193.23 Averages 191.14
Minimum Number of Sampling Points Required: Single Point 

# FE
— M - 0
— M - 1

Stratification determination by Method 7E, Section 8.1.2

Testing by TRC~



### SAMPLING DATA FOR : EPA METHOD 26



# Date: t 0 ( 2 t( a ftest Rurl: ej ~ 

# Plant: 14an5on _B04 04rometric Pressure (m Hg) 0-1,37 Location: L
~ 

# ',A T ~ 

# ;&M ID: Source: ;(A a Scr bbu (;ntdIDGM Correction Factor: 6. 96 ~ 

# Technicians: p{y) Probe Material/Size: d154Z45 Pre-Test Leak Check Results Rate of $3/min at a vacuum of Leakage rate must be less than 0.02 ft3/min at a vacuum of at least 15 in Hg

.. .. ... . . . 

### ~~ K: 

### gs @ 10 min intervals 

## mipling Clock 

# I DGM Time 

# I Time Reading )GM/IN 

# I DGM/OUT 

# Temp Temp 7

~ ~
~ ;

i 

# ~

Z -iXH



## SD

_ i1

~ 

## 43

I: 48 

## r.n I I -53 ,



# Post-Test Leak Check Results Rate of ('j,p0 ( ft3/min °- at a vacuum of 

# +9Z `S Leakage rate must be less than 0.002 ft3/miu at a vacuum of at least 15 in 

# Final vol' Imp ml H 2 SO 4 NaOH. 

## WEIGHTS Imp #1 Imp--#2 Imp #3 Imp #4 Imp #5 Imp #6 Contents IDA \ S:, , Begirnning Endin

## SAMPLING DATA FOR : EPA METHOD 26



# Date: Test Run: 

# (

~ 

# Z Plant: 

# } I c e o.(3r c k Barometric Pressure (in Hg) 

# Qq, 3-

~ j 

# Location: 

# 1 T X DGM3D: 

# T-3 l39 ~73q 

# Source: ~(; ~~ 

# S h, ~ t~ ~le~ 

# DGM Correction Fac 

# tor: (-g-- C •q- ®
~ 

# 9 g 7

~ 

# ! e Technicians: Probe Material/Size: 

# ahon
Pre-Test Leak Check Results Rate of 6

,) ,6?0 p ft3/min at a vacuum of 

# _,rE 20 Leakage rate must be less than 0.02 $3/min at a vacuum of at least 15 in Hg



# ~ . ~ ®~

. I

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_
- • 

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-------

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# Post-Test Leak Check Results Rate 

# ,600 ft3/min at a v 

# ~ (~ 

# iitlm of 

# 1sLeakage rate must be less than 0.002 113/min at a vacuum of at least 15 in 

# Final Vol Imp nil H 2 SO 4

-- 

# ~ NaOH 

## WEIGHTS Imp #1 Imp #2 Imp #3 Imp #4 Imp #5,

~ 

## ;

~ 

## np #6 Contents 1 n 1 fU N n't r S; Co Begmning lD0 w1 1 6 k. I

— 

## — — ~ 

## Ending

-- ~

### SAMPLING DATA FOR : EPA METHOD 26 

# ~

Date: 

# /6-7- Test Run: 

# C-3 Plant: 

# R„c_ k Barometric Pressure (in Hg) 

# 3 ~ 

# Location: 

# CI ~ ti

- ~ 

# x DGM 

# ID : 

# T

- ~ 

# 3 C3ySs73q Source: ~<~~ 

# 4 (,

~~ 

# 1,,

~ 

# \ DGM CorrectionFac 

# tor: ~~ 

## e, q 

# t

~ 

## Lo 

# Technicians: (~ M y ~ ~~ 

# Probe Material/Size: Te~ 

# '/a n 6ib1'a•<E-AR 

# Pre-Test Leak Check Results Rate of 0/min at a vacuum of /5 ;

~ 

## t-( a 

## akage rate must be less than 0.02 ft3/min a vacuum of at least 15 in Hg readings @ 10 min intervals 768°F 

## Sampling Time (min) Clock

Time (24 hr) DGM

Reading (ft3) 1 DGM/IN

Temp DGM/oUT

Temp (°F) Last Imp

Temp (°F) D 6= 03 y(, X.f 71

P6-~ ~43.~f5 

## ! l0 54.5 (o - 

# 945.133 1 160.3 5'Y5 t5 16: (8 

# `i'l1.605 I jo?_ 9U Y 20 (6= 23 8:935 

# oz f m 

# 0 '5. 6 25 b=2? , 0.750 !e2 &.g 

## 0 6= 33 452.585 loz ial. 

# M'.D

112zw SY. vo 5 S 02 iol,t 576 o 16<Y3 6.?1i2 

## Go2 fof.6 5.(2



## o Z o•6 S. 

# 55 l 

# oz fDo o ( :0 6 -5W 102- 101.5 7



# Post-Test Leak Check Results Rate of ft3/min at a vacuuni of Leakage rate must be less than 0.002 ft3/min at a vacuum of at least 15 in 

# Fina1 Vol Imp ml H 2 SO 4 ~



### ~ NaOH 

## WEIGHTS Imp #1 Imp #2 Imp #3 Imp #4 Imp #5 Imp #6 Contents 

# l Ending ~q

~ ®, /



# ~ 

# T

~ 

# T rn lek

~
Lee- ile t 1

~ 

# m M

nCe 

## pr,arpae ~

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s

~ 50 'S 1.0 1.5 2.0 2.5

Non-Particulate Traverses °"•^^ 40 a sk

30 6 I

ZO 16 slackaiamemr>z4in 1z 10 •1-arser moerror

ar:ra=k: ecaeiamecarl2za'in renaaew =k n



# O L%

2 3 4 5 6 7 8 9 10 oen ei.meea aow=:ve.m nam now ai:mre.=<e (oi:u=r. e) 

### b

oun ai.mm.rs u>mr.zm rtom now aawmznw lowi 50 'S 1.0 1.5 2.0 2.5 Particulate Traverses q p ~ 

### ao =

~ 

### • e I 30 24 or 25 - 20 20 sracktliameler>24in 16 12 10 -Laraernemeermr eorsrananeuiarera=ka slackaiamerer,z-zaib 0 9 z a 5 a 7 

### oula,m,r,B ae..,a„m,ram aa. a s,imm.- roerarr

ew, - tb.nmi 

# Circular Stack Sampling Traverse Point Layout / 

# (EPA Method 1) ZO/ Date: 

### /d 

# l O~- Plant: 

## 119,60n &;c Source:

~



# ;an. ~~iv~ 

# Erhavs Technician(s): Port+ Stack ID (in): 54 

### Port Extension (in): y,y 

### Stack ID (in): ~ 

### Stack Area (ft2): Duct Diameters upstream from flow disturbance (A): : ~ 

### L 

### Duct Diameters downstream from flow disturbance (B): 13 

### Total Required Traverse Points: 

### 7b No. of Traverse Points per Diameter: ;5Y 

### Stack Diagram (Draw side view showing major components, dimensions, upstream/downstream flow disturbances) 

### tacK cross secnon

Mv



# ~ .'.

\,

..: ~~

.. 

### Draw traverse point layout above 

### Unit Information

Traverse Number of Traverse Points on a Diamete *Calculated *Port 

## Point 

# ~ 4 6 8 12 Traverse Length Number I Percentdistances(%) Point Offset
2 25.0 14.6 10.5 6.7 3 75.0 29.6 19.4 11.8

____...,......__... 

### 4 93.3 70.4 32.3 17.7

_ _. ..... _.. _ _._. _.... 

### 5 85.4 67.7 25.0 6 95.8 80.6 35.6 7 89.5 64.4 8 96.8 75.0 9 82.3 

## 10 88.2
12 97.9 

### *Stack diameters > 24 in shall have no traverse points located wi n 1 in of the 

### stack wall 'Stack diameters <_ 24 in shall 

### have no traverse points located w/in 0.5 in of the 

### stack wall 

# TRC

## Stratification Test (Method 7E ) Company: Hanson Brick Plant: Elgin Facility Location: Elgin, Texas Technicians: JSG, JM, SJ, RAM, PC, TO, CJ Source: Plant 2 Kiln Scrubber Outlet Is Stack Diameter or Equivalent Diameter greater than 7.8 ft?
02 

### Point (%) 1 18.52 2 18.46 3 18.38

18.45 Averages Minimum Number of Sampling Points Required: Single Point
Stratification determination by Method 7E, Section 8.1.2

Testing by TRC

### SAMPLING DATA FOR : EPA METHOD 26



# Date: 

# / o/21 1 o7 Test Run: G — ~ 

# Plant: 

# 9uh54, 8 Barometric Pressure (in Hg) 

# 2 

# 1 37 7 Location: E1 ;A ( DGM ID: 95 y 9$ Q Source: I 1 r ~ 

# „ ~ P 

# „ au }le} DGM Correction Fac 

# tor: Technicians: 7~ 

# To ProbeMateriaUSize:

- 

## 4F t5H'1'65 

# -e-Test Leak Check Results ite of 0 • ob ( 

# ft3/min a vacuum of Leakage rate must be less than 0.02 $3/min at a vacuum of at least 15 in Hg



# . ~
~~ ~ ~ -~~~' • i • • .

M~=



# rNE - ~ r~

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# .'

------- ------- ------- ------- ------®
-------

- ~ 

# -----

--- 

# ~

- 

# -- Post-Test Leak Check Results Rate of 

# p,poN ft3/min at a vacuum of 

# + t ~ Leakage rate must be less than 0.002 ft3/min at a vacuum of at least 15 in 

# Final Vol Imp ml H 2 SO 4 .~ 

### NaOH

~ 

# WEIGHTS Imp #1 Imp #2 Imp #3 Ilp #4 Imp #5 Imp #6 Contents .10 FFzs d .1 N &9e em S` t ✓ f Bng 

# l oo vv,L ioo ,.nL — °— Qi —

### SAMPLING DATA FOR : EPA METHOD 26



# Date: 

# 1 0 r2i jd9 Test Run: 

# C- Z Plant: 

# Hc

~ 

# sc,, gc ~ ~,k 

# Barometric Pressure (in Hg) Location: C

_~~T?x 

# DGM ID: 

# 9549go Source: DGM Correction Fac 

# tor: ~~[, a ~ 

# Technicians: 

# NSJ EL 3
~ 

# PL, Probe Material/Size:

~ 

# Pre-Test Leak Check Results Rate of 

# ~ 

# . 001 ft3/min at a vacuum of 2 ~ Leakage rate must be less than 0.02 ft3/min at a vacuum of at least 15 in Hg readings @ 10 min intervals ;;3; a68°F 

## Sampling Time (min) Clock

Time (24 hr) DGIV4

Re40ing DGM/iN Temp (°F) DGM/oIIT

Temp (°F) Last Imp

Temp (°F) 

# 2 £s - 7 Y

. q. ( ff)14.137 8 .$ -7 6 •S 

## l0 1 7 166.36' 

## fS 4 1. 2. 7 6`1. s 4S 4 .1• 51 

# Aag3, n 

# 6`!. g;
~ 

## , 

# Oz 27 jf0,qqC fs 

# .9 s. 2 133 1 J1 

# .1

. 1 1 Ss Sy 7 3- a S. 30 1337 II'1.S39, x S. 31 - 1 1 

# 1 

# 4, . 5ti

- 7

~ 

# s5. S by • 3 ~ 

### Ll 

# o V3 4 7 fi$•6HA

r3 12 

# - 0 - 1E j so 13.5 -

7 l.

-

7 i 

# 96.3 Li•5r 6S, 5 S" 

# I H f ,5 S S - D S. 5s

Iq o

- 7 D SIX 1 3 0

Post-Test Leak Check Results Rate of 

# (), oo\ ft3/min at a vacuum of 

# a. o Leakage rate must be less than 0.002 ft3/min at a vacuum of at least 15 in 

# Final Vol Imp ml H 2 SO 4 -- — NaOH 

## WEIGHTS Imp #1 Imp #2 Imp #3 Imp #4 Imp #5 Imp #6 Contents , (V 4 D , i N .2 e 

## Begnining 100 onL Io0 AL ^ -- ✓

### SAMPLING DATA FOR : EPA METHOD 26



# Date: 

# 10121 109 TestRun: 

# C-3 Plant: 

# k4Asw, ( ~ 

# , ; c [~ 

# Barometric Pressure (in Hg) 

# a g, 3( Location: 

# [I ~; ^ ~X 

# DGMID: 

# 95

~ 

# 9g0 Source: 

# K;T 6,14 DGM Correction Factor: Technicians: 

# & GS ; To ProbeMateriaUSize: 

# -j e qor, Test Leak Check Results ite of 0,00( 

# ft3/min a vacuum of 

# 0 Leakage rate must be less than 0.02 ft3/min at a vacuum of at least 15 in Hg readings @ 10 min intervals <68°F 

## Sampling Time (min) Clock

Time (24 hr) DGM

Reading ($3) DGM/IN

Temp ( ° F) DGM/oUT

Temp ( ° F) Last Imp

Temp ( ° F) 

# O tsS 1 ` 6 . 9 6ztl 3

a 5.3ti 3

~ 

# •fs O f 

## 31 .3

- 6 8

~ 

## 5. q 

# 3.y

~ 

# IfS 4. ;L 6 0 16 '35 ° .1 5 12. 

## 2.6

. ~ 

## S.p

7 '3l.s'Sr 3. ly 1/.S -- 6s. '?O 3 3. S 2 53. 

## g/, Ff 66_. 3 s f 7 l

~ 

## ll .?

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## s 3.

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## r T2 . P, 6S. Lt0 /6 q

~ 

## L M171C 1

~~ 

## _, S, y NS 

# 16 If7 iys,fs7 S, ( 50 

## t6Sa !`f .`1 $ 9

. 

# e /3 `2

~ 

## S 16 S 7 tso.o3 k I / A

~ 

## ^.

- 7 C~ 1

- 70 

## 1'

.



# Post-Test Leak Check Results Rate of 0 , 

# 00 'k ft3/min at a vacuum of 

# 0-0 Leakage rate must be less than 0.002 ft3/min at a vacuymziTat least 15 in 

# Final Vol Imp ml H 2 SO 4 NaOH 

## WEIGHTS Imp 41 `

~ 

## jilp #3 Imp #4 Imp #5 Imp #6 Contents A Imp#2 Begin muing (d0 L

_ ~

## Preliminary Velocity/Cyclonic Flow Measurement



# PLANT: f/a' s ,, -&> 

# JeDATE: /p Zo o ~ 

# TEST RUN #: p- j 

# Start Time: so 

# End Time: J260 TECHNICIANS T7k6 PC.,
SAMPLING POINT AP CYCLONIC ANGLE (°) °F

1 0. i91 9 2 0. /V 309 

# 3 6, /y 0 3/0 4 046 3 ,3o8 

# 5 3a:i

# 6 3d& 7 D, r8 8 d.i 8 a, /9 d 30(0 9 2os' 

# 10 0. i ~

- 

## 3 30 

# 11 o./f C) 3 

# 12 0, /(. q 306 

# 14 6,16 0 30 15 o./G 3©S' 16 o.iS 1

~ 

# a 

# 17 18 19 20 21 22 23 24 AVG. AP AVG. AVG. °F



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## Plant: Hanson Brick

Location: Elgin, Texas Source: Kiln 2 Lime Scrubber Technicians: TO, CJ, PC 

## Test Run Designation Run 1 Run 2 Run 3 Date 10/21/2007 10/21/2007 10/21/2007 

## Start Time (24 hr) 11:03 13:09 16:06 

## Stop Time (24 hr) 12:13 14:23 17:18 Stack Gas Sampling Data Box No. A A A Sample Time Length (min) 64 64 64 Atmospheric Pressure (" Hg) 29.37 29.37 29.37 Avg. Stack Temperature (°F) 324 324 324 Avg. Meter Temperature (°F) 82.8 82.8 82.8 Average
~ 

## AP 0.518 0.518 0.518 Average AH 1.41 1.41 1.41 Sample Volume at STP (DSCF) 42.363 42.363 42.363 Moisture (% volume) 5.76 5.76 5.76 Dry Gas Fraction (unitless) 0.942 0.942 0.942 Molecular Weight (]b/Ib-mole) 28.40 28.401 28.401 Static Pressure (in. H20) -0.40 -0.40 -0.40 Stack Velocity (ft/min @ stack conditions) 2164 2164 2164 Stack Flow, dry (DSCFH) 1.33E+06 1.33E+06 1.33E+06 % Isokinetic 99.2 99.6 100.3 

## Calculated Particulate Emissions Average Filterable Particulate Matter Collected (g) 0.0090 0.0085 0.0080 8.47E-03 Condensable Particulate Matter Collected (g) 0.0278 0.0267 0.0245 2.63E-02 FilterableAnalysis(Ib/dscfl 4.68E-07 4.40E-07 4.14E-07 4.41E-07 Filterable Analysis (lb/hr) 0.62 0.59 0.55 0.59 

## Total Suspended Particulate Analysis (lb/dscf) 1.92E-06 1.83E-06 1.69E-06 1.81E-06 Total Suspended Particulate Analysis (gr/dsco 0.0134 0.0128 0.0118 0.013 Total Suspended Particulate Analysis (lb/hr) 2.55 2.44 2.25 2.42 Total Suspended Particulate Anal sis (tons/yr) 11.19 10.69 9.86 10.58



## OTRC

### Plant: Hanson Brick

Locatfon: Elgin, Texas Source: Kiln 2 Lime Scrubber 1'echnicians: TO, CJ, PC Test Run Desi nation Run 1 Run 2 Run 3 Date 10/21/2007 10/21/2007 10/21/2007 Start Time (24 hr) 11:03 13:09 16:06 Stop Time (24 hr) 12:13 14:23 17:18
BLANK Filter # 

### 79586 79586 79586 Avg. Tare Wt. (g) 0.3590 0.3590 0.3590 Avg. Final Wt.(g) 0.3588 0.3588 0.3588 Filter Blank Weight Gain (g) -0.0002 -0.0002 -0.0002 

## SAMPLE Fflter # 

### 79582 79583 79584 Avg. Tare Wt. (g) 0.3591 0.3597 0.3620 Avg. Final Wt. (g) 0.35925 0.3599 0.3622 Filter Weight Gain (g) 0.0002 0.0002 0.0003 Filter Weight Gain, Blank Corrected (g) 0.0004 0.0004 0.0005 

## BLANK Filterable Rfnse Beaker # 

### 139 139 139 Volume Acetone (ml) 277.3 277.3 277.3 Avg. Tare Wt. (g) 7.7222 7.7222 7.7222 Avg. Final Wt. (g) 7.7229 7.7229 7.7229 Front Half Rinse Blank Weight Gain (g) 0.0007 0.0007 0.0007 Blank Weight Concentration (mg/liter) 2.52 2.52 2.52 

## SAMPLE Filterable Rfnse Beaker # 

### 129 171 128 Volume Acetone (ml) 218.9 138.6 174.0 Avg. Tare Wt. (g) 7.9317 7.9478 7.7234 Avg. Final Wt. (g) 7.9409 7.9562 7.7313 Filterable Rinse Weight Gain (g) 0.0092 0.0084 0.0080 Filterable Rinse Wei t Gain, Blank Corrected (g) 0.0086 0.0081 0.0075
Filterable Particulate Matter Collected 0.0090 0.0085 0.0080 

## AQUEOUS BLANK Condensable Impinger Contents Beaker # 

### 142 142 142 Volume H20 (ml) 312.1 312.1 312.1 Avg. Tare Wt. (g) 7.8235 7.8235 7.8235 Avg. Final Wt. (g) 7.8242 7.8242 7.8242 Impinger Contents Blank Weight Gain (g) 0.0007 0.0007 0.0007 D.I. Water Blank Particulate Concentration (mg/liter) 2.24 2.24 2.24 

## AQUEOUS SAMPLE Condensable Impinger Beaker # 

### 114 124 133 Volume H20 (ml) 153.8 131.4 146.8 Avg. Tare Wt. (g) 7.7721 7.7142 7.7584 Avg. Final Wt. (g) 7.8003 7.7412 7.7832 Impinger Contents Weight Gain (g) 0.0282 0.0270 0.0248 Impinger Contents Weight Gain, Blank Corrected 

## O 0.0278 0.0267 0.0245
Condensable Particulate Matter Collected ) 

### 0.0278 0.0267 0.0245



## OTRC

# M-5 Beaker Weighing Data Sheet

COMPANY/JOB #: 154785 Hanson Brick

PLANT: Elgin, Texas DATE: 10/21/2007 EMISSION POINT: Lime Scrubber Page:
TARE WEIGHTS 

### Date: 9/4/2007 9/5/2007 Time: 4:00 4:00

Weight #1 ( ) Weight

#2 (g) Weight

#3 (g) Weight

#4 (g) Final

Avg. Wt. Absolute

Diff. (mg) Beaker# 139 7.7222 7.7222 7.7222 0.0000 129 7.9317 7.9317 7.9317 0.0000 171 7.9477 7.9478 7.9478 0.0001 128 7.7235 7.7232 7.7234 0.0003 0.0000 0.0000 0.0000 0.0000 142 7.8234 7.8235 7.8235 0.0001 114 7.7722 7.7720 7.7721 0.0002 124 7.7142 7.7142 7.7142 0.0000 133 7.7583 7.7584 7.7584 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
FINAL WEIGHTS Date: Time: 10/24/2007 10/25/2007

3:30 9:30 Weight #1 (g) Weight

#2 ( ) Weight

#3 (g) Weight

#4 (g) Final

Avg. Wt. Absolute

Diff. (mg) DESCRIPTION Beaker # Vol. (ml) Blank Acetone 139 277.3 7.7229 7.7229 7.7229 0.0000 Cl P/N Rinse 129 218.9 7.9410 7.9408 7.9409 0.0002 C2 P/N Rinse 171 138.6 7.9561 7.9562 7.9562 0.0001 C3 P/N Rinse 128 174.0 7.7313 7.7313 7.7313 0.0000 0.0000 0.0000 0.0000 0.0000 Blank DI H20 142 312.1 7.8242 7.8241 7.8242 0.0001 CI BackHalf 114 1 

### 153.8 7.8004 7.8001 7.8003 0.0003 C2 Back Half 124 131.4 7.7412 7.7412 7.7412 0.0000 C3 Back Half 133 146.8 7.7831 7.7832 7.7832 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

Notes:



## OTRC

# M-5 Filter Weighing Data Sheet

COMPANY: 154785 Hanson Brick PLANT: Elgin, Texas DATE: 10/21 /2007 11SSION POINT: Lime Scrubber
TARE WEIGHTS Date: 8/13/2007 8/14/2007 Time: 

# 1 4:00 I 1:00

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

----- 1 1111 1 1111

-- --- 1 1111 1 1111


### FINAL WEIGHTS Date: Time: 10/24/2007 1 0/25/2007

4:30 10:00 Weight #1 ( ) Weight

#2 (g) Weight

93 (g) Weight

#4 ( ) Final

Avg. Wt. Absolute

Diff. (mg) DESCRIPTION Filter # Blank 79586 0.3588 0.3588 0.3588 0.0000 FilterCl 79582 0.3593 0.3592 0.3593 0.0001 Filter C2 79583 0.3599 0.3599 0.3599 0.0000 Filter C3 79584 0.3622 0.3622 0.3622 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

Notes:



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## Cubix Corporation

# APPENDIX B: EXAMPLE CALCULATIONS

## Example Calculations Method 7E Concentration Correction



### Example for Run: Run 1 O 

### bserv e_d 

### Measurements: 50.40 NOx, Gas Range (CS) 8.69 NOx r, ave.reading for run (ppm) 0.40 C o; , reading for zero gas before run (ppm) -0.01 C of , reading for zero gas after run (ppm) 24.87 C Mi , reading for span gas before run (ppm) 24.55 C Mf , reading for span gas aRer run (ppm) 25.30 C., actual cal. gas concentration (ppm) -0 13 Cai c o, direct zero gas cnncentration (ppm) 24.70 C a ,,, M , direct span gas concentration (ppm)

Bias Check (SB o ) Eq 7E-2

Bias Check (SB M ) 

### Eq 7E-2

Drift Check (D) Eq 7E-4 Initial zero gas

_ (Coi - Cd', o )



### CS

= 0.40 - -0.13

50.4



### = 1.05 %

Initial span gas

- (CMI - C Eir,M)

CS

= 24.87 - 24.70

50.4

= 0.34 %

Zero gas

= ABS I SB or

- SB o; I

= ABS 10.24 - 1.05 1

= 0.81 % Final zero gas

_ (Cor - Ceic o )

CS

_ -0.01 - -0.13

50.4

= 0.24 °fo

Finalspan gas

- (CMf - CCIGM )

CS

= 24.55 - 24.70

50.4

_ -0.30 %

Span gas

= ABS I SB M( - SB Mi I

_ -ABS 10.30 - 0.34 1

= 0.63 %

NOx Correction (CNO,): Eq 7E-5

_ (NOx,r- C o ) x C ~ C M -C' o

Average zero bias (C o ) Average span bias (C M )

_ (Coi + Cof ) (CMi * CMi )

2 2

= 0.40 + -0.01 = 24.87 + 24.55

2 2

= 0.20 (ppm) = 24.71 (ppm)

( 8.69 - 0.20 ) x 25.30 ( 24.71 - 0.20 )

= 8.77 (ppm) Values may differ from Summary Tables due to rounding and truncation.

## Example Calculations Method 7E Concentration Correction



### Example for Run: Run 1 

### Observed Measurements: 496.00 CO, Gas Range (CS) 118.42 COr, ave. reading for run (ppm) . 0.05 Coi, reatling for zero gas tiefore run (ppm) -0.05 Cof, reading for zero gas after run (ppm) 251.75 Cmi, reading for span gas before run (ppm) 246.75 Cmf, reading for span gas after run (ppm) 253.00 Cma, actual cal. gas concentration (ppm)

Initial zero gas Bias Check (SB o )

_ (Coi - Cao-, o ) Eq 7E-2 CS

. = 0.05 - 0.05 496.0

= 0.00 %

Initial span gas Bias Check (SB M )

_ (CM, - Cd;,,M ) Eq 7E-2 CS

= 251.75 . - 251.75

496.0



### = 0.00 %

Zero gas Drift Check (D) = ABS I SB or - SB o; I Eq 7E-4

_ -ABS 10.02 - 0.00 ~

= 0.02 °!o 0.05 C a; ,, o , direct zero gas concentration (ppm) 251.75 Cm,, M. direct span gas concentration (ppm)

Final zero gas

_ (Cor - Cdv,a )



### CS

_ -0.05 - 0.05

496.00



### _ -0.02 %
Finalspan gas (CMf - Ctlly M ) 

### CS

= 246.75 - 251.75

496.0

_ -1.01 %

Span gas

= ABS I SB Mf - SB, I

= ABS 11.01 - 0.00 ~

= 1.01 %

CO Correction (Cco) Eq 7E-5 = (CO,r- C o ) 

### x C Mg CM

- Co
Average zero bias (C o )

_ (Coi + Cor )

2

. = 0.05 + -0.05 2

= 0.00 (ppm)

118.42 - 0.00 ) x 253.00 ( 249.25 - 0.00 )

= 120.20 (ppm) Values may differ from Summary Tables due to rounding and truncation. Average span bias (C M ) (CMI + CMf ) 2

= 251.75 + 246.75 2

= 249.25 (pprn)

### Example Calculations Method 7E Concentration Correction



### Example for Run; Run 1 

### Ob s 

### erved M easur 

### ements: 21.10 O z , Gas Range (CS)

. -0.08 Cai,, o, direct zero gas concentration (ppm) 18.42 O z r, ave. reading for run (vol. %) I. 10.12 Caic m, direct span gas concentration (ppm) -0.07 Coi, reading for zero gas tiefore run (vol %) i -0.03 C of , reading for zero gas after run (vol %) '. 9.91 CMi, reading for span gas before run (vol %) ' 10.04 C Mf , reading for span gas after run (vol %) 10.00 CMA, actual cal. gas concentration (vol %) ,

Initial zero gas Bias Check (SB o )

_ (COi - Cdo-, o ) Eq 7E-2 CS

_ -0.07 - -0.08

21.1

= 0.05 %

Initial span gas Bias Check (SB a ) (GM i - C Ciy M ) Eq 7E-2 CS

= 9.91 - 10.12

21.1

_ -1.00 %

Zero gas Drift Check (D) = ABS I SB, - SB oi I Eq 7E-4

= ABS 10.00 - 0.05 ~

= 0.19 % Final zero gas

_ (Cof - Cdv. o )

CS

_ -0.03 - -0.08

21.1

= 0.24 %

Finalspan gas (CM( - C diG M

) CS

= 10.04 - 10.12

21.1

_ -0.38 %

Span gas

= ABS I SB Mf

- SB Mi I

_ -ABS 10.38 - - 1.00 ~

= 0.62 %

0 2 Correction (Co 2 ) Eq7E-5 = (O i ,r-C o ) x C M p CM

- Go
Average zero bias (C o )

_ (Coi + Cof )

2

_ -0.07 + -0.03

2

_ -0.05 (ppm)

_ ( 18.42 - -0.05 ) x 10.00 ( 9.98 - -0.05 )

= 18.42 (vol %)

- Values may differ from Summary Tables due to rounding and truncation. Average span bias (C M ) (CiMi ~ C Mf ) 2

= 9.91 + 10.04

2

= 9.98 (ppm)

## Example Calculations Method 7E Concentration Correction



### Example for Run: Run 1 Ob 

### se 

## rv ed Measurements:

--- 10.07 CO z , Gas Range (CS) -- _ 0.10 C d ,,, o , direct zero gas concentration (ppm) 1.89 CO z r, ave. reading for run (vol. %) '

~ , 10.05 C, M , direct span gas concentration (ppm) -0.09 Coi, reatling for iero gas before run (vol %) 0.16 C c , reading for zero gas after run (vol %) I
9.95 CMi, reading for span gas before run (vol %) ' 10.10 C,, reading for span gas after run (vol %) I, 10.07 C w

„ actual cal. gas concentration (vol %)

Initial zero gas Final zero gas Bias Check (SBo)

_ (Col - Cm c O )

_ ( C of - Cdi c o ) Eq 7E-2 CS CS

-0.09 - 0.10 = 0.16 - 0.10 10.1 10.1

_ -1.89 % = 0.60 %

Initial span gas Final span gas Blas Check (SBM) - (CMi - CtlicM )

_ (CMt - cmgM ) Eq 7E-2 CS CS

= 9.95 - 10.05 = 10.10 - 10.05

10.1 10.1

_ -0.99 % = 0.50 %

Zero gas Span gas Dri$ Check (D) = ABS I SBor - SBoi I = ABS I SBMI - SBMi I Eq 7E-4

= ABS 10.60 -- 1.89 I = ABS 10.50 -- 0.99

~

= 2.48 % = 1.49 %
Op Correction (CO2): Eq 7E-5 = (O z ,r- C o ) x C Mg CM

- Co
Average zero bias (Co) Average span bias (CM)

- ( C Oi + C OI )

_ (CMi + CMf )

2 2

_ -0.09 + 0.16 = 9.95 + 10.10

2 2
` = 0.04 (ppm) = 10.03 (ppm)

_ ( 1.89 - 0.04 ) x 10.07 ( 10.03 - 0.04 )

= 1.87 (vol %)

- Values may differ from Summary Tables due to rounding and truncation.

## Example Calculations Method 7E Concentration Correction



### Example for Run: Run 1 Observed Measurements: 101.50 SO z , Gas Range (CS) 19.54 SO z r, ave. reading for run (vol. %) 1.30 C c; , reading for zero gas before run (vol %) 2:28 Ccr, reading for zeio gas aRer run (vol %) . 44.50 CM„ reading for span gas before run (vol %) 43.01 C Mr , reading for span gas aRer mn (vol %) 45.60 CM q , actual cal. gas concentration (vol %)

Initial zero gas Bias Check (SBo)

_ (Coi - Cm,.o ) Eq 7E-2 CS

= 1.30 - -0.13

101.5

= 1.41 %

Initial span gas Blas Check (SB M 

## )

_ (CMi - Cei n M ) Eq 7E-2 CS

= 44.50 - 44.48 -0.13 Ce,c o , direct zero gas cuncentration (ppm) 44.48 Caic 

## M, direct span gas concentraflon (ppm)

Finalzero gas 

## (Cor - Cdv.O ) CS

= 2.28 - -0.13

101.5

= 2.37 %

Final span gas (CM( - CEiO M ) cS

= 43.01 - 44.48

Drift Check (D) Eq 7E-4



### O z Correction (C oz ): Eq 7E-5 101.5

= 0.02 %

Zero gas

= ABS I SBor - SBOI I

= ABS 10.00 - 1.41 

### 1

= 0.97 %

_ (O z ,r- C a ) x C Mg Cm - Co

Average zero bias (C o ) ' (Coi + Cor.)

2

= 1.30 + 2.28 101.5

_ -1.45 %

Span gas

= ABS I SB Mr

- SB Mi I

_ -ABS 11.45 - 0.02 

## 1

= 1.47 %

Average span bias 

### (C M 

## ) (CMi + CMI ) 2

= 44.50 + 43.01 2

= 1.79 (ppm)

_

_ ( 19.54 - 1.79 ) x 45.60 ( 43.76 - 1.79 )

= 19.29 (vol %) Values may differ from Summary Tables tlue to rounding and truncation. 2

43.76 (ppm)

## Example Calculations NOx Emission Rates



### Example for Run: Run 1 Observed Measurements: 8.77 corrected NOx concentration (ppm) 1333458 stack exhaust flow rate (DSCFH) 

### Co nstants/Co nversi o ns/Stan da rds: 385.15 ideak gas constant @ EPA STP (68 OF and 29.92 "Hg); (scf / Ib-mol) 46.01 Molecular weight of NOX as NO2 (Ib/Ib-mol) 29.92 EPA STP (" Hg); Prer C NOx corrected NOx concentration C oz corrected Oz concentration Qd stack exhaust flow rate DNox NOx density factor



### NOx density factor

— 46.01 Ib/Ib-mol x 

### 10 385.15 scf/Ib-mol

= 11.95E-081b/scf 

### NOx mass emission rates (Ibs/hr)

— QNOx x Qd x DNOX

= 8.77 x 1.33E+06

= 1.40 Ibs/hr x 1.19E-07

Values may differ from Summary Tables due to rounding and truncation.

## Example Calculations CO Emission Rates



### Example for Run: Run 1 Observed Measurements: 120.20 corrected CO cancentration (ppm) 1.33E+06 stack exhaust flow rate (DSCFH)



### . CO densityfactor

_ — 28.01 Ib/Ib-mol x 

### 10 385.15 scf/Ib-mol

= 7.27E-081b/sd


### CO mass emission rates

= C co x Qd x Dco

= 120.20 x 1.33E+06 x 7.27E-08

= 11.661bs/hr 

### C on sta nts/Co nversi o ns/Stan d ards: 385.15 ideak gas constant @ EPA STP (68 OF and 29.92 "Hg);

(scf / Ib-mol) 28.01 Molecular weight of CO (Ib/Ib-mol) 29.92 EPASTP("Hg) C co corrected CO concentration C OZ corrected 02 concentration Qd stack exhaust flow rate D co CO density factor

Values may differ from Summary Tables due to rounding and truncation.

## Example Calculations S0 2 Emission Rates



### Example for Run: Run 1 Observed Measurements: 19.3 corrected SO z concentration (ppm) - 1.33E+06 stack exhaust flow rate (DSCFH) 

### Constants/Conversions/Standards: 385.15 ideak gas constant @ EPA STP (68 OF and 29.92 "Hg);

(scf/Ib-mol) 64.06 MolecularweightofSO z (Ib/Ib-mol) 29.92 EPASTP("Hg) 

### I Csoz corrected SO z concentration C oi corrected 02 concentration Qd stack exhaust flow rate ' D soz SO z density factor



### S0 2 density factor

= 64.06 Ib/Ib-mol x 10" s

= 1.66E-071b/scf


### S02 mass emission rates

= Csoz x Qd x Dsoz

= 19.30 x

= 4.281bs/hr 

### S02 Removal Efficiency 1.33E+06 x 1.66E-07

_ [1

_ SO, Outlet (Ibs/hrl ] x 100

SO z Inlet (Ibs/hr)

_ [1 - 4'28 ] x 100 42.8

= 90.00 i

Values may differ from Summary Tables due to rounding and truncation.

## Example Calculations HCI Emission Rates

Example 

### forRun: Run 1 Observed Measurements: 0.17 HCI concetltration (ppm) 1333458 stack exhaust flow rate (WSCFH)

HCI density factor

= 36.46 Ib/Ib-mol x 

### 10 385.15 scf/Ib-mol

= 9.47E-081b/scf
HCI mass emission rates

= C H q x Qd x DHCi

= 0.17 X 1.33E+06 x 9.47E-08

= 0.021 Ibs/hr HCI Removal Efficiency
HCI Outlet (Ibs/hr) (1 HCI Inlet (Ibs/hr) 

### 1 x 100

0.021 ) x 100 1.14

= 98.12 % 

# I Constants/Conversions/Standards: l i 385.15 ideal gas constant @ EPA STP (68 OF and 29.92 "Hg);

(scf / Ib-mol) 36.46 MolecularweightofHCl (Ib/Ib-mol) 29.92 EPA STP ( " Hg) ' C Hci HCI concentration

, C oz corrected 02 concentration I, Qd stack exhaust flow rate D Hci HCI density factor

Values may differ from Summary Tables due to rounding and truncation.

## Example Calculations HF Emission Rates

Example 

### forRun: Run 1 Otiserved Measurements: 0.12 HF concentration (ppm) 1333458 stack exhaustflow rate (WSCFH) Consta 385.15
20.01 29.92 QHF Q02 Qd DHF its/Conversions/Standards: ideal gas constant @ EPA STP (68 OF and 29.92 "Hg) (scf / Ib-mol) Molecular weight of HF (Ib/Ib-mol) EPA STP ( " Hg) HF concentration corrected 02 concentration stack exhaust flow rate HF density factor

HF density factor

= 20.01 Ib/Ib-mol x 

### 10 385.15 scf/Ib-mol

= 5.20E-081b/scf
HF inass emission rates

— QHFxQ'dxDHF

= 0.12 x

= 0.00831bs/hr HF Removal Efficiency

_ HF Outlet Ilbs/hrl

(1 HF Inlet (Ibs/hr) ) x 100

_ (1 0.0083 1.9 ) x 100

= 99.56 °fo 1.33E+06 x 5.20E-08

Values may differ from Summary Tables due to rounding and truncation.

### Example Calculations
VOC Emission Rates

Example for Run: Run 1 Observed Measurements: 4.64 VOC concentration (ppm) 1415149 stack exhaust flow rate (WSCFH) Constants/Conversions/Standards: 385.15 ideal gas constant @ EPA STP (68 OF and 29.92 "Hg);

(scf / Ib-mol) 44.10 Molecular weight of VOC as C3 (Ib/Ib-mol) 29.92 EPASTP("Hg) G1 r ,, VOC concentration Co: corrected 02 concentration Qd stack exhaust flow rate Dvoc VOC density factor

VOC density factor

— 44.10 Ib/Ib-mol x 10 385.15 scf/Ib-mol

= 1.14E-07 Ib/scf VOC mass emission rates

- = Cvoc x Qd x Dvoc

= 4.64 x 1.42E+06

= 0.75 Ibs/hr x 1.14E-07

Values may differfrom Summary Tables due to rounding and lruncation.

## Example Calculations Stack Moisture and Molecular Weight

Example for Run: Run 1 Observed Measurements:

_ 161.945 beginning DGM reading (ft3) 204.925 ending DGM reading (ft3) 2731.2 beginning impinger weight (g) 2786.1 ending impinger weight (g) 1.0286 Y, DGM factor (unitless) 542.5 Tm, ave. DGM temperature (R = F+ 460) 29.37 Pm, barometric pressure (in. Hg) 1.87 CO2 (%) 18.42 02 (%) 0.0 H2 (%) 0.0 CO (%) 

### C o nsta nts/Co nve rs i o ns/Sta n dards:
-- ----

~ I 528 Tstd, EPA standard temperature (R) i, 29.92 Pstd, EPA standard pressure (in. Hg) 0.04715 water (ft3/g) i 1.335 water (L/g) 

# I 28.3 conversion factor, (L/ft3)

Impinger Wt. Gain (IWG): = ending impinger wt. (g) - beginning impinger wt. (g)

= 2786.1 - 2731.2



### = 54.9 (g) Volume Metered (Vm): = ending DGM reading (0) - beginning DGM reading (113) = 204.925 - 161.945

= 42.98 (ft3)

Standard Volume Metered (Vstd):

_ (Vm) (Y) (Pm) (Tstd) (Pstd) (Tm)

= 42.98 x 1.0286 x 29.37 x 528 29.92 x 542.5

= 42.237 (SCF) Moisture Content (Bws): = IWG (g) x 0.04715 (ft3/g) ( (IWG (g) x 0.04715 (ft3/g) )+ ( Vstd (ft3) ) )

= 2.5885 

### (2.5885 + 42.237)

= 0.058

= 5.8 (%)
Dry Gas Fraction: = 1- Bws

= 1 - 0.058

= 0.942 Molecular Wt. (Ms): Total Molecular Moisture or Partial Compound Percent Weight Dry Fraction Mol. Wt. H20 n/a 18 0.058 1.039 02 18.4 32 0.942 5.554 CO2 1.9 44 0.942 0.775 CO 0.0 28 0.942 0.000 H2 0.0 2 0.942 0.000 N2 79.7 28 0.942 21.030 28.40 (Ib/Ib-mole)

Values may diNerfrom SummaryTables due to rounding and truncation. Ex.CaICB- Stack MOiBture/MOI.Wt. 1

## Example Calculations

Example for Run: Run 1 

### Observed Measurements: 0.84 Cps, pitot tube factor (unitless) 29.37 Pb, barometric pressure (in. Hg) 783.7 Ts(abs), ave. stack temperature (R, F+460) 28.40 Ms, stack gas molecular wt. (Ib/Ib-mole) -0.4 Pg, stack static pressure (in. H20) 16.50 A, stack area (ft2) 16 Number of traverse Points 0.942 Fd, stack dry gas fraction 

### Stack Gas Flow Rate



### Constants/Convers io ns/Sta nda rds: 528 Tstd, EPA standard temperature (R) 29.92 Pstd, EPA standard pressure (in. Hg) 85.49 Kp, (ft/s) [(Ib/Ib-mole) (in. Hg) / (R)(in.H2O)]"0.5 5129.4 Kp, (ft/min) [(Ib/Ib-mole) (in. Hg) / (R)(in.H20)]^0.5 60 conversion factor, (s/min) 60 conversion factor, (min/hr) 0.07355 conversion factor, (in Hg/in H20)

Point# dP Point# dP Point# dP ' Point# dP 1 0.24 'I 10 0.31 19 28 2 0.25 '

~~ . 11 0.3 20 29 3 0.28 ', 12 0.28 I 21 I, 30 4 0.28 ''

~ , 13 0.29 22 'I 31 5 0.3 I, 14 0.3 23 32 6 0.33 '' 15 0.25 ''

~ 24 'i l 33 7 0.31 16 0.19 I 25 34 8 0.17

~

. 17 'I 26 , 35 9 0.24 18 ''

~ , 27 ; 36

Absolute Static Pressure (Ps): = Pb x(Pg x 0.07355)

= 29.37 + ( -0.4 x 0.07355)

= 29.34 (in. Hg) Average Square Root of DiP (p1): = 8.285 16

= 0.5178 Stack Velocity (Vs): = Kp x Cp x p1 x[Ts(abs) /(Ps x Ms)]^0.5 

### (ft/min) = 5129.4 x 0.84 x 0.5178 1783.7 

### I (29.34 x 28.40 )]^0.5

= 2163.8 (ft/min)
Stack Velocity (Vs): = Vs / 60 (s/min) 

### (ft/Sec) = 2163.8 / 60

= 36.06 (ft/sec)
Stack Volumetric Flow (Qa): = Vs x A

= 2163.8 x 16.50

= 35700 (ACFM)
Stack Volumetric Flow (Qd): = Qa x 60 (Tstd/Pstd) x(Ps/Ts(abs)) x Fd

= 35700 x 60 x 528 x 29.34 x 0.942 29.92 783.7

= 1333458 DSCFH



### Values may differ from Summary 

### Tables due to rounding and truncation. 

### Ex.Calcs- Stack Gas Flowrate 1

### Example Calculations Particulate Matter weights 

### Exampfe for Run: Run 1 

### Observed Measurements: Blank Analyses: -0.0002 Bf, filter blank weight gain (g) 0.0007 Bw, back half blank weight gain (g) 0.0007 Ba, front half blank weight gain (g) 312.1 Vw, back half aqueous volume (ml) 277.3 Va, front half acetone volume (ml) Front Half Filter Analysis: 0.0002 F,weightgainofflter(g) Front Half Probe/Hozzle R7nse Analysis: 0.0092 Ra, weight gain of front half rinse (g) 218.9 Vm, front half rinse volume (ml) Back Half Impinger/Rinse Analysis: 0.02815 I, weight gain of back half rinse (g) 454 conversion factor,(g/Ib) 7000 conversion factor, (grains/Ib) 1000000 conversion factor, (ml-mg/g-L)

1000000 conversion factor, (ml-mg/g-L)

153.8 Vit, back half aqueous rinse total volume (ml)

Front Half Filter = F - Bf Blank Correction (PMf): = 0.0002 -- 0.0002

= 0.0004 (g)
PM conc in front half = Ba / Va x 1000000 (mg-ml/g-L)

acetone blank (Cba): = 0.0007 / 277.3 x 1000000 (ml-mg/g-L)

= 2.52 (mg/L)
PM conc. in front half = Ra / Vra x 1000000 (ml-mg/g-L) rinse sample (Cra): = 0.0092 / 218.9 x 1000000 (ml-mg/g-L)

= 42.0 (mg/L)
Front Half Rinse Blank = Cra - Cba Correction (Crac): = 42.0 - 2.52
= 39.5 (mg/L)
Total Front Half rinse = Crac x Vra / 1000000 (ml-mg/g-L) PM Mass (PMra): = 39.5 x 218.9 I 1000000 (ml-mg/g-L)
= 0.0086 (g)
PM conc in back half = Bw/ Vw x 1000000 aqueous blank (Cbw): = 0.0007 / 312.1 x 1000000 (ml-mg/g-L)
= 2.24 (mg/L)
PM conc. in back half = I/ Vit x 1000000 (ml-mg/g-L) sample (Ci): = 0.0282 / 153.8 x 1000000 (ml-mg/g-L)
= 183.0 (mg/L) Back Half Aqueous Rinse = Ci - Cbw Blank Correction (Cic): = 183.0 - 2.24
= 180.8 (mg/L) Total Back Half Aqueous = Cic x Vit / 1000000 (ml-mg/g-L) PM Mass (PMi): = 180.8 x 153.8 / 1000000 (ml-mg/g-L)
= 0.0278 (g)
Total PM Catch: Front Halt = Pmf + PMra + PMi Aqueous Back Half (PMtot1; = 0.0004 + 0.0086 + 0.0278

= 0.0368 (g) 

### Values may differ from Summary Tables due to rounding and truncation. ' Front Half Analyses: (filter + front half rinses)

Back Half Analysis: (impinger(s) + back half rinses)



### Ex.Calcs-Particulate Matter 1

## Example Calculations Particulate Matter Emissions / Isokinetics



### Example for Run: Run 1 

### Observed Measurements: 42.237 Vstd, gaseous volume collected (DSCF) 1333458 Qtl,stackvolumetricflowrate(DSCFH) 0.0368 PMtotal, total PM catch (g) 0.000495 An, nozzle area (R2) 0.942 Fd, tlry gas fraction (unitless) 1.400 dH, average dH of DGM (in. H20) 29.34 Ps, stack absolute pressure (in. Hg) 783.7 Ts, ave. stack temperature (R, F+460) 64 ts, sample time (min) 2163.8 Vs, stack gas velocity (ft/min) 528 Tstd, EPA standard temperature (R) 29.92 Pstd, EPA standard pressure (in. Hg) 454 wnversion factor, (g/Ib) 7000 conversion factor, (grains/Ib) 2000 conversion factor, (Ib/ton) 8780 conversion factor, (hr/year)

Filterable PM Conc. ln Stack

Total PM Conc. in Stack: (Ib/DSCI)

Total PM Conc. in Stack: 

### (grains/DSCF)

Filterable PM Emissions: (Ib/hr)

Total PM Emissions: (Ib/hr)

Filterable PM Emissions: 

### (tons/yr) = Filterable PM / 454 / Vstd

= 0.0086 / 454 / 42.237 = 4.48E-07 (IbIDSCF)
= PMtotal / 454 / Vstd

= 0.0368 / 454 / 42.237 = 1.92E-06 (IbtDSCF) = Total PM Conc. in Stack x 7000 (greins/Ib) = 1.91925E-06 x 7000

= 0.0134 (grains/DSCF)
= Filterable PM Conc. in Stack x Qd = 4.48E-07 x 1333458

= 0.60 (Ib/hr)
= Total PM Conc. in Stack x Qd = 1.92E-06 x 1333458

= 2.56 (Ib/hr) Note: Conc. in (Ib/DSCF)

Note: Conc. in (Ib/DSCF)

= Filterable PM Emissions x Tons of Brick Firetl (tons/hr) Note: Fllterable PM Emissions in (Ib/hr)

= 0.60 / 10.56

= 0.06 (Ibs/ton of Fired Brick)

Ave. Sampling Isokinetics ( % ): — (Ts x Vstd x Pstd x 100) (Tstd x Vs x ts x An x Ps x Fd)

= 783.7 x 42.237 x 29.92 x 100 528 x 2163.8 x 64 x 0.000495 x 00029 x 0.942

= 98.9 (%)



### Values may differ from Summary Tab/es due to rounding and truncation. Ex.Calcs-Particulate Matter 2

# APPENDIX C: QUALITY ASSURANCE ACTIVITIES

# Barometer/Altimeter Calibration Check

Date: 10/19/2007 Location: Austin, TX south location Technician: Neal Afflerbach Manufacturer: United Instruments Type: Aneroid Units: in Hg and ft Cubix Lab Assign.: T-8 Serial No.: GH438

standarci 6arometer 

### Lab Standard Barometer Manufacturer: Princo Type: Fortin Type Mercurial Units: in. Hg and mm Hg ID Number: NOVA 453x

Uncorrected (Observed) Lab Barometer Reading 29.39 in. Hg Temperature of Lab Barometer 70 °F Multiplier for Temperature Correction (+ or -) -0.003742 unitless Multiplier for Laftitude Correction (Austin =-30.5°N) (+ or -) -0.001327 unitless Temperature Corrected Laboratory Barometer Reading 29.28 in. Hg Temperature & La titude Corrected Laborato ry Barometer R eading 2 9.24 in. Hg Corrected Laboaratory Barometer Reading 743 mm Hg Corrected Laboaratory Barometer Reading 990 mb Corrected Laboaratory Barometer Reading 625 ft


## Field Barometer/Altimeter Field Barometer Reading (temperature compensated) 560 ft Field Barometer Reading (temperature compensated) 29.31 in. Hg 

## Calibration Test Results `Difference (in Hg) -0.07 Pass/Fail PASS

Accentance Criteria 

### Agreement within 0.1 in. Hg or 2.5 mm Hg, or 100 ft 

# 12&

u 

# h
signature



# ~~ TRC

# Barometer/Altimeter Calibration Check

Date: Location: Technician: Manufacturer: Type: Units: Cubix Lab Assign.: Serial No.: 

### 10/22/2007 Austin, TX south location RAM United Instruments Aneroid in Hg and 

## ft T-8 GH438 Lab Standard Barometer Manufacturer: 

### Princo Type: 

### Fortin Type Mercurial Units: 

### in. Hg and mm Hg ID Number: NOVA 453x



## Laooratory stanaara tsarometer Uncorrected (Observed) Lab Barometer Reading 29.65 in. Hg Temperature of Lab Barometer 70 °F Multiplier for Temperature Correction (+ or -) -0.003742 unitless Multiplier for Lattitude Correction (Austin =-30.5°N) (+ 

### or -) -0.001327 unitless Temperature Corrected Laboratory Barometer Reading 29.54 in. Hg Temperature 

### & Latitude Corrected Laboratory Barometer Reading 

## 29.50 in. Hg Corrected Laboaratory Barometer Reading 749 mm Hg Corrected Laboaratory Barometer Reading 999 mb Corrected Laboaratory Barometer Reading 390 

### ft


## Field Barometer/Altimeter =ield Barometer Reading (temperature compensated) 315 ft 

### Field Barometer Reading (temperature compensated) 29.58 in. Hg


## Calibration Test Results

Acceptance Criteria Agreement within 0.1 in. Hg or 2.5 mm Hg, or 100 ft

signature



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# Nozzle Inspection and Measurement Data Sheet

Company Nam 

# e: TW— Nozzle Numbe 

# r: FL(D p.30 ~


### Measure three diameters (in inches) as shown below. Average the diameters and calculate the Nozzle area according to the calculations below.

*Diameter 1 (in): 

# p- -

W Date: 10 *Diameter 2 (in): 03O2 *Diameter 3 (in): 

# D• 3 o Average Diameter (in): 

# ©• 3!D\5 =(Sum of Diameters 1-3) / 3
Average Radius (in): Average Diameter (in) / 2 Average Radius (ft): 

# D• ( a 5 $3 = Average Radius (in) / 12


## Nozzle Area (ft2): 

# 0, d6n 4q 52.5 =Tr x radius (ft) ^2



# at *Diameter 1 (in): 

# fl.3o ( Date: (0 

## *Diameter 2 (in): 

## D• 3 ~ 1 *Diameter 3 (in): 

# 0.302 Average Diameter (in): D,30lCj =(Sum of Diameters 1-3) / 3
Average Radius (in): 

# 0, l 5l = Average Diameter (in) / 2 Average Radius (ft): 

# 0• LaT°j ~ 

# ° ~ 

### = Average Radius (in) / 12 (ft)

Nozzle Area (ft2): 

# p, Qjpq'A 5

~ 

# )-S = Tr x radius (ft) ^2
*Maximum allowable difference between largest diameter and smallest diameter is 0.004 inches. Noale must be round, sharp-edged, free of nicks an< <r

i


### N 

### signature 

# C - TRC nozzle_insp_measure_v1.1.x1tDry Gas Meter Calibration

WORKING METER REFERENCE METER Date: 1015I2007 Prev. Calib. Dale: 7/2512007 Calibration Date: 7130/2007 Location: TRC South Auslin Loeation: TRC Austin Lab Technician: RAM Technician: KRH MeterSerial No: 1348739 Meter9edal Nu: P164240 Cubix DGM ID T-3 Cubix DGM ID American Prev. Calib Factor(Y): 0.9901 Calib. Factor Y: 0.9780 REFERENCE METER Corr Vo ~n~ Calibration Run# Time

min SlartTemp

de F StopTemp

tle F Vol(initial)

wft Vol(final)

wft Vol.Total

cufl MeterRate

w•R/min EPASTP

cuft 1 1 31 0.000 8.4930 a.306 0.2679 8.134 2 31.5 0.0000 13.3020 13.009 0.4130 12.740 3 15.5

a 77. M

77 0.0000 8.8510 8.656 0.5585 8.445 4 21.5 0.0000 14.2990 13.984 D.6504 13643 5 15 0.0000 115440 1 13.246 1 0.8831 12.827

WORKING METER ICOM. Vol @ EPA STP (cuft) Calculated

DGM Pactor (Y) Dry Gas Meter (DGM Factor)

Calibration Test Results Calibration Run# Time

(min) Start Temp

(tlegF) Stop Temp

(degF) Vol (initial)

(wft) Vol (rnaq

(wft) V.I. Total

(cuft) Meter Rate

(w•ft/min) 1 31 81.0 78 824.775 833.327 8.552 O.Z]6 8.243 0.9868 

### "AVerageY:,. .-0,9876 2 31.5 78.0 78 834.923 848.315 13.392 0.425 12.944 0.9842 :'AVe YwfinS%oFpFevlousvalue. YES -

~ PASS;

~ -. ..-Ind Y

~ value3kl<0i02fromAve: PASSe 3 15.5 78.0 79 849.167 858.038 1 8.871 1 0.572 4 1 21.5 1 79.0 1 79 859.191 871472 14.281 0.664 13.778 09903 5 1 15 79.0 79 877.347 890168 1 13.421 1 0.895 1 12.948 0.9906 cnreria: ' Y- ratio of the reading of the reference meter to the working DGM. Acceptable tolerance of intlividual values from the avera9e is+l- 0.02, wilh a value between 0.95 and 1.05.


### DGM Factor vs. Flow rate

1.0500 1.0400 1.0300 1.0200 1.0100

~ 1.0000 0.9900 0.9800 0.9700 0.9600 0.9500 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 Flow Rate (cfin)

F" , 0 7k I10/22/2007 10/5/2007 TRC South Austin RAM 1348739 T-3 0.9876 WORKING METER Date: Prev. Calib. Date: Loeation: Technician: MeterSerial No: Cubix DGM ID Prev. Calib Factor (Y) REFERENCE METER
Calibration Date: 7/3012007 Location: TRCAustinLab Technician: KRH MeterSerial No: P164240 Cubix DGM ID American Calib. Factor 0.9780 Dry Gas Meter Calibration

REFERENCE METER Cnn. vn ~~ Calibratian Run# Time

min StartTemp

tle F StopTemp

de F Vol(initiap

wR Vol(fnap

cufi Vol.TOtal

wft MeterRate

w•ft/min EPASTP

wft t 29 72.0 72 0.000 8.3280 t1.t45 0.2809 7.961 2 21.5 72.0 72 0.0000 10.5120 10.281 0.4782 10.049 3 12.5 72.0 71 0.0000 7.5350 7.369 0.5895 7.210 4 1 t 71.0 71 0.0000 7.3550 7.193 0,6539 7.044 5 17.5 71.0 71 0.0000 10.3540 10.126 0.8805 1 9 916

WORKING METER Corr. Vol g EPA STP (cuft) Calculated

DGM Factor (Y) Dry Gas Meter (DGM Factor)

Calibration Test Results Calibration Run# Time

(min) Start Temp

(degF) Stop Temp

(tlegF) Vol (initial)

(cuft) Vol (finap

(wft) Vol. Total

(cuft) Meter Rate

cu•ft/min) 1 29 66.5 72.1 972.607 980.845 8.238 0.284 8.093 0.9837 * Aveiage Y

~ ; '. ' U.9921 qve Yw(r

~ 5°lofpranousvalue I YES ' £Ave YbetweenO9Send705: ,IPASSf` 2 21.5 72.0 75 981.420 991.850 10.430 0.485 10.766 0.9885 3 12.5 75.0 76 992.371 999.847 7.476 0.598 7.260 0.9931 4 11 76.0 76 1.375 8.670 7.295 0.663 7.077 0.9953 Ihd Y9aluea+/ 0,02fromAVe.: iRASS'F 5 11.5 ]6.0 76 10266 20.488 1 10.222 1 0.989 1 9.917 1.0000 crnerla: • Y- ralio of the reading of the reference meterto the worfling OGM. Acaeptable tolerance of individual values from the avera9e is+/- 0.02, with a value between 0.95 and 1.05.


### DGM Factor vs. Flow rate

1.0500 1.0400 1.0300 1.0200 

### 1.0100 Y 1.0000 0.9900 0.9800 0.9700 0.9600 0.9500 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 Flow Rate (cfin)



# TRC

## Dry Gas Meter Calibration

WORKING METER Date: 101812007 Prev. Calib. Date: 8/30/2007 Location: TRC Austin Technician: RAM MeterSerial No: 954980 TRC Meter ID T-8 Prev. Calib Factor (Y) 0.9995 P bar (in Hg) : uncorrected: 30.17 -> 30.17 REPERENCE METER REFERENCE METER
Calibration Date: 7/3012007 Location: TRC Austin Technician: KRH MeterSerial No: P164240 Calib. Factor Y : 0.9780

frnrr vM Calibration Run # Time

min Start Temp

de F Stop Temp

de F Vol (initial)

cu ft Vol (fnal)

cu ft 

# I Vol. Total

cu ft Meter Rate

cu ft/min EPA STP

in,

~ Jjj ft 1 1 21.5 71 71 0.000 6.577 6.432 0.2992 6.352 2 29 71 71 0.000 13.069 12.781 0.4407 12.622 3 22.5 71 71 0.000 13.389 13.094 0.5820 12.932 4 27 71 71 0.000 18.904 18.488 0.6847 18.258 5 7.5 71 71 0.000 1 6.714 1 6.566 1 0.8755 1 6.485

WORKING METER Corr. Vol @ EPA STP (cu ft) I Calculatetl

DGM Factor (Y) D ry Gas Meter (DGM Factor

Calibration Test ResultS Calibretion Run # Time

(min) Start Temp

(deg F) Stop Temp

(deg F) Vol (initial)

(cu ft) Vol (final)

(cu ft) Vol. Total

(cu ft) Meter Rate

(cu•ft /min) 1 21.5 80 80 9.131 15.708 6.577 0.306 6.386 0.9947 :` Vera90 

### r 2 29 80 80 16.702 29.682 12.980 0.448 12.604 1.0015 Ave. YS9(1115%of pfevious value: , YES 3 22.5 80 80 31.744 1 45.029 1 13.285 0.590 12.900 1.0025 "AY2-Yb9twBef10,95Snd7.05' RASS

~ ". 4 27 80 80 46.650 67.390 18.740 0.694 18.197 1.0034 IOd; Y'YdIUeS'*Y- 0.92 from AVe: PASS I ,- 7.5 80 8 69.620 76.227 6.60 0.881 6.415 1 1.0108 .rnenz: ' Y- ratio of the reading uf the reference meter to lhe working DGM. Acceptable tolerance of intlivitlual values from the average is +/- 0.02, with a value between 0.95 antl 1.05.


## DGM Factor vs. Flow rate

1.0500 1.0400 1.0300 1.0200 1.0100 > 1.0000 0.9900 0.9800 0.9700 0.9600 0.9500 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 1.10 1.20 1.30 Flow Rate (cfm)

TRC Air Measurements, Austin, TX

### Dry Gas Meter Calibration

WORKING METER Date: 1012212007 Prev. Calib. Date: 10/812007 Location: TRCAustin Technician: RAM MeterSerial No: 954980 TRC Meter ID T-8 Prev. Calib Factor (Y) 1.0026 P bar (in Hg) : uncoffected: 30.17 --> 30.17 REFERENCE METER REFERENCE METER Calibration Date: 7/30/2007 Location: TRC Austin Technician: KRH MeterSerial No: P164240 Calib. Factor 0.9780

Corr. Vol @ Calibration Run # Time

min Start Temp

d F Stop Temp

de F Vol (initial)

cu ft Vol (final)

cu ft Vol. Total

cu ft Meter Rate

cu ft/min EPA STP

cu ft 1 29.5 70 70 0.000 8.773 8.521 0.2889 8.431 2 22.5 70 71 0.000 10.259 10.033 0.4459 1 918 3 1 12 77 72 0.000 7.197 7.039 0.5866 1 6.945 4

. 10.5 72 72 0.000 7.164 7.006 0.6673 6.908 5 13 1 73 1 73 1 0.000 11.655 1 11.399 1 0.8768 1 11.216

WORKING METER Corr. Vol @ EPA STP (cu ft) Calculated

DGM Facto Y) Dry Gas Meter (DGM Facto Callbration Teet ReSDlts Calibration Run # Time

(min) Start Temp

(deg F) Stop Temp

(deg F) Vol (initial)

(cu ft) Vol (final)

(cu ft) Vol. Total

(cu ft) Meter Rate (cu•ft/min) 1 29.5 76 77 157.307 165.808 8.501 0.288 8.308 1.0148 ,-. Veraye. : 2 22.5 78 82 167.833 177.698 ;vQnS%ofpfeV[oGBYalue.YES 3 10.085 Q447 9.771 1.0150

12 82 85 178.475 185543 7068 ;AvQ:Ybetweefl(1,95and1,05: PHSS 4 0589 6819 10184

10. 201.272 7.046 0.671 6.767 1.0209 P.ASS ~ 13 89 uu 205.252 216.551 11.399 I0.877 10.877 1.0311 Criteria: ' Y- ratio of the reading of the reference meter to the working DGM. Acceptable tolemnce of intlivitlual values from the average is +/_ 0.02, with a value between 0.95 antl 1.05.


## DGM Factor vs. Flow rate

1.0500 1.0400 1.0300 1.0200 1.0100 > 1.0000 0.9900 0.9800 0.9700 0.9600 0.9500 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 1.10 1.20 1.30 Flow Rate (cfm)

TRC Air Measurements, Austin, TX

### Meter Box: Orifice Full Calibration

Date: Prev. Calib. Date: Location: Technician: MeterSerial No: TRC Meter Box ID Atm. Pressure (corr. In Hg): Critical Vacuum+2 in Hg: Prev. Calib Factor (Y): 10/17/2007 8/9/2007 TRC Austin south NTA
A uncarrectetl: 29.14 --> 29.14 16 in. Hg. (required minimum) 1.0333 Reference Orifice Set Orikce # K' Factor Manufacturer: Nutech Instruments 40 0.2398 Model: LA40-73 48 0.3524 Tested By: OMD 55 0.4635 63 0.6026

Initial Tem eratures iFinal Temperature sl Orifce Serial # K' coefficient

see above dH

in. H20) min 

# I Vol (initlal) cu ft Vol (fnal)

cu ft Vol. Total

cu k Inlet

tleg F Oullet

de F Inlet

tle F Outlet

de F Vacuum

in H Initiai

tle F Final

de F 40 0.2398 0.29 17.5 124.224 129.683 5.459 80 79 81 79 23 74.0 74.0 48 0.3524 0.63 77 129.683 737.376 7.693 80 79 81 80 22 75.0 74.0 55 0.4635 1.1 13 137.376 745.069 7.693 82 80 84 81 20 74.0 76.0 63 0.6026 1.7 14 145.069 155.90fi 10.837 83 81 85 82 18.5 76.0 75.0

Meter Box Dry Gas Meter Critical Orifice Dry Gas Meter Calibration Onfice Calibration Volume Volume Volume Volume Corrected Corrected Flow Corrected Correctetl Factor (Y) Factor (dH@) Value Variation Value Variation Vm (std) Vm (std) Rate Vcr (std) Vm (std) cu ft liters CFM cu k liters # # in H20 in H20 510 147.34 0.312 1 5.29 149.87 7.017 -0.011 1.655 0.02 7.34 207.72 0.453 7.55 213.85 1.029 0.001 1.670 0.04 7.32 207.30 0.592 7.59 214.99 1.037 0.009 1.678 0.04 10.31 297.92 0.774 10.62 300.86 1.031 0.002 7.535 -0.10 

### Meter Box

Criteria: ' V- ralio of the reading of the calibration meter (cntical orifice) to the Meler Box DGM. Acceptable toterance of individual values from lhe average is +/- 0.02. " tlH- the orifice tlifferential pressure in inches of H20 that equates tu 0.75 cfm of air fiow at 68 F antl 29.92 in Hg, acceptable lolerance of intlivitlual values from the average is +/- 0.2. 

## DifPerential Pressure vs. Flow Rate

1.6

1.6

1.4



### 1.2 

# O ~

_ c 0.8 = D 

### 0.6

0.4

0.2

0 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

.. Flow Rate (cfm) -1

TRC Air Measurements Austin, TX

### Meter Box: Orifice Full Calibration

Date: 10122/2007 Prev. Calib. Date: 10/17/2007 Location: TRC Austin Lab Technician: RAM MeterSerial No: 80715.00 Cubix Meter Box ID A Atm. Pressure (corr. In 129.49 unconected: 29.65 Critical Vacuum+2 in H 16 in. Hg. (required minimum) Prev. Calib Factor (Y): 1.0286 Reference Orifice Set OriFice (#) K' Factor Manufacturer: Apex Instruments 40 0.2398 Model: LA40-73 1 48 0.3524 Tested By: SH 55 0.4635 63 0.6026 73 0.8162

Initial Temnemfiires lFinni Tcmnorafurc. Orifce Serial # K'wefficienQ

see above dH

in. H20 Time

min Vol (initial)

cu ft Vol (fna0

cu k Vol. Total

cu k Inlet

de F Outiet

tle F Inlet

de F) Outlet

de F Vacuum

in H Initial

de F Final

(de F 40 0.2398 03 24 298.200 1 305.439 1 7.239 1 70 69 75 72 23 71.0 72.0 48 0.3524 0.69 17 305.439 312.948 7.509 75 72 79 75 21.5 72.0 74.0 55 0.4635 1.1 12 312.948 319.965 7.017 79 75 80 78 20 74.0 74.0 63 0.6026 1.8 8 319.965 326.060 6.095 80 76 1 82 78 19 74.0 74.0 73 0.8162 3.9 8 326.060 1 333.834 1 7.774 1 82 78 1 85 1 74.0 1 74.0

Meter Box Calibration Test Results Pass/Fail , ".AverageY: 1.0407 t PASS ~ :AVe,YW/In5°/eufpreviousvalue - YES

,0,95 -Y=1.05

- - -PASS - •"AVera eEH 1.738 PASS . Criteria: ' Y- ratio of the reading of the calibration meter (cntical orifice) to the Meter Box DGM. Acceptabte tulerence of individual values from the averege is +/_ 0.02. "dH- the onfce differential pressure in inches of H20 that equates to 0.75 cfm of air Bow at 68 F antl 29.92 in Hg, acceptable tolerance of individual values from the average is +/- 0. 

## Differential Pressure vs. Flow Rate

4.5

4

3.5 I

3

0 " 2.5 x c x 2 0

1.5

1

0.5

0 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 Flow Rate (cfm) Meter Box Dry Gas Meter Critical Odfice Dry Gas Meter Calibration Orifce Calibration Volume Volume Volume Volume Conected Conected Flow Corrected Corrected Factor ff) Factor(dH Value VariaBon Value Variation Vm (sttl) Vm (sttl) Rate Vcr (std) Vm (std) cu k liters CFM cu k liters # # in H20 in H20 7.09 200.79 0.302 7.36 208.47 1.038 -0.002 1.748 0.01 7.31 206.99 0.442 7.65 216.70 1.047 0.006 1.708 -0.03 6.81 192.84 0.585 7.10 201.00 1.042 0.002 1.689 -0.05 5.91 167.33 0.762 6.15 174.21 1.041 0.000 1.627 -0.11 7.55 213.74 1.037 7.81 22112 1.035 -0.008 1.920 0.18

102207 Box A Full Cal.xls

## Quality Assurance Worksheet

NOx Conversion Efficiency, System Bias, Response Time, Sample System Leak Checks

Date: 10/21/2007 Client: Hanson Brick Location: Elgin, Texas Tecbnician: JSG, JM, SJ, CJ, RAM, PC, TO Source: Lime Scrubber i`O, - NO Connersio€a l:fficie¢iss


## Certified concentration, NO z standard: 45.90 Measured concentration, NO Z standard: 41.9 E'ITxoi 91.3%

Resuonse Time



## 2X SYSTEM RESPONSE TIME:
Saninle Svstem Leak Cliecl: 

## Sample System ID 

## Vacuum

(in. Hg) 

## Leak Rate

(in. Hg/min) 

## Pre test A 21.0 0.00 Post test A 21.0 0.00 Pre test B 21.0 0.00 Post test B 21.0 0.25

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# Interference Response Test

Date of Test: 

## 1/16/2007 Manufacture: 

## California Analytical Model No.: 

## 400-CLD Serial No.: 

## 6412004 Calibration Span: 

## 100.5 Technician: 

## JSG Test Gas Type Concentration Analyzer Response O z /CO z 4.99/21.0 

# % 0.02 0 2 /CO 2 21.1/5.04 

# % 0.00 H 2 0 

# i 4.50% 0.01 CO/CH 4 45.4/45.5 ppm 0.02 

## NH 3 /SF 6 10.2/10.0 ppm 

# I 0.03 

## S0 2 44.3 ppm 0.00 1-1 2 /He 2 40/60 

# % 0. 

## 01

Sum of Responses 0.09 

# % of Calibration Span 0.09 * Interferance must be less than 2.50% of calibration span



# OTRC

# Interference Response Test

Date of Test: 

## 1/16/2007 Manufacture: 

## Thermo Environmental Model No.: 

## CO 48 Serial No.: 

## 48-27403-228 Calibration Span: 

## 99.9 Technician: 

## JSG Test Gas Type Concentration Analyzer Response O z /CO z 4.99/21.0 % 

## 0.03 0 2 /CO 2 21.1/5.04 % 

## -0.01 H 2 0 4.50% 0.02 CH 4 50.5 ppm 0.02 NH 3 /SF 6 10.2/10.0 ppm 0.00 S0 2 44.3 ppm 0.00 H 2 /He 2 40/60 % 

## 0.04 NO 15.16 ppm 0.01 NO z 55.9 ppm 0.10

Sum of Responses 0.21 % 

## of Calibration Span 0.21 * Interferance must be less than 2.50% of calibration span



# AiiaLi

# Interference Response Test

Date of Test: 

## 1/16/2007 Manufacture: 

## Servomex Model No.: 

## 1400 02 1440 Serial No.: 

## 01420C1/2534 Calibration Span: 

## 21.1 Technician: JSG Test Gas Type Concentration Analyzer Response H 2 0 4.50% 0.00 CO/CH 4 45.4/45.5 ppm 0.00 NH 3 /SF 6 10.2/10.0 ppm 0.00 S0 2 44.3 ppm 0.00 H 2 /He 2 40/60 % 

## 0.00 NO 15.16 ppm 0.00 NO z 55.9 ppm 0.01

Sum of Responses 0.01 % 

## of Calibration Span 0.05 * Interferance must be less than 2.50% of calibration span

OTRC

# Interference Response Test

Date of Test: 1/16/2007 Manufacture: Servomex Model No.: 1400 CO2 1440 Serial No.: 1415C/2650 Calibration Span: 21.0 Technician: JSG Test Gas Type Concentration Analyzer Response H 2 0 4.50% 0.00 

## CO/CH 4 45.4/45.5 ppm 0.01 NH 3 /SF 6 10.2/10.0 ppm 0.01 S0 2 44.3 ppm 0.00 H 2 /He 2 40/60 % 0.00 NO 15.16 ppm 0.00 NO 2 55.9 ppm 0.00

Sum of Responses 0.02 % of Calibration S an 0.10 * Interferance must be less than 2.50% of calibration span



# ~~

# Interference Response Test

Date of Test: 

## 1/16/2007 Manufacture: 

## Western Research Ametek Model No.: 

## S02 921 Serial No.: 

## AZ-921N-9088-1 Calibration Span: 

## 44.3 Technician: JSG Test Gas Type Concentration Analyzer Response H 2 0 4.50% 0.04 CO/CH 4 45.4/45.5 ppm 0.01 NH 3 /SF 6 10.2/10.0 ppm 0.01 H 2 /He 2 40/60 % 

## 0.06 NO 15.16 ppm 0.00 NO Z 55.9 ppm 0.00 0 2 /CO 2 4.99/21.0 % 

## 0.02 0 2 /CO 2 21.1/5.04 % 

## 0.00

Sum of Responses 0.14 % 

## of Calibration S an 0.32 * Interferance must be less than 2.50% of calibration span

OTRC

# Interference Response Test

Date of Test: 1/16/2007 Manufacture: JUM Engineering Model No.: FID 3-300 Serial No.: 9303161-33 Calibration Span: 100.6 propane Technician: JSG Test Gas Type Concentration Analyzer Response H Z O 4.50% 0.04 CO 43.9 ppm 0.01 NH 3 /SF 6 10.2/10.0 ppm 0.03 NO 15.16 ppm 0.00 NO z 55.9 ppm 0.05 0 2 /CO 2 4.99/21.0 % 0.10 O Z /CO z 21.1/5.04 % 0.01



## Sum of Responses 0.24 % of Calibration S an 0.24 * Interferance must be less than 2.50% of calibration span



# ~~

### Calibration Curves 60

50■ Propane 40 > E n 

### n N C 0 30 . q

G N 

### u c 0 U 20



### — Linear(Propane) 10

01
~ 0.0 20.0 OV.V BV.V 1UU.0 1LU.0 14U.0 1bU.0 36U.0 CVU.V 

### Area Counts 

# Concentration = (Slope(m) x Area Counts 

# ~

Initial Calibration Curve Finai Calibration Curve (Combination of all Calibrations)

Com ound Slo e m R ° Com ound Slo e m R' 1 Pro ane t 0 270279 ':' 0 9998I3 l Pro ane s::0 295902

Calibrafion Datz

Initial Cal Gas Concentrations Finai Cal Gas Concentrations S 2311 ' 507 Initial Area Counts Final Area Counfs 1 Pco ane ; .21.8181

~ 931798 S e 187,I067 ;_ 18.4301 ;. . 75.7512 " " -1502929, `.i


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### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 10:17:48 Description: 5ppm C1-C6 Data file: 102107_11.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785t Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

~



### Component Retention Area Area % Methane 0.996 3.7446 3.5278 Ethane 1.058 11.0501 10.4103 Propane 1.211 22.0645 20.7871 36.8591 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 10:32:37 Description: 5ppm C1-C6 Data file: 102107_13.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

,

~



### Component Retention Area Area % Methane 0.990 4.0471 3.1512 Ethane 1.051 10.7147 8.3430 Propane 1.202 21.0014 16.3527 35.7631 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 10:39:45 Description: 5ppm C1-C6 Data file: 102107_14.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785f Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Methane 0.990 3.2546 2.4218 Ethane 1.052 10.7945 8.0321 Propane 1.203 20.8884 15.5429 34.9376 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 10:46:50 Description: 50.7ppm C3 Data file: 102107_15.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Locatlon: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area %

0.061 0.6446 0.1059 0.505 22.5787 3.7096 Methane 1.005 14.9608 2.4580 Ethane 1.044 6.3398 1.0416 Propane 1.204 188.5709 30.9815 -- C

- 1.908 0.3412 0.0561

- 2.030 1.5389 0.2528

- 2.181 187.5732 30.8176—



## - 2.934 0.2531 0.0416 ~
- 3.031 0.6800 0.1117

- 3.204 185.1759 50. +



## ~ – c3 30.4237 — 608.6570 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/2112007 10:51:21 Description: 25.1ppm C3 Data file: 102107_16.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area %

0.064 23.0271 3.5795 0.164 115.2593 17.9169 Ethane Propane 1.051 1.200 1.3993

92.8100 0.2175

14.4272 

# C - ZS, ( p
~ 

### ^ }

- 2.057 23.8366 3.7054 2.226 94.1376 14.6336

- 2.346 0.1598 0.0248 3.692 92.5919 14.3933 -
- 4.540 0.1237 0.0192

- 4.565 0.1276 0.0198

- 4.583 0.1591 0.0247

- 4.695 94.1239 14.6315- Z ~•~ ~r ~j

- 

### 5.254 0.1382 0.0215

- 5.517 0.1284 0.0200

- 5.587 0.1560 0.0243

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 U-95-4

- 7 - 

## JO53 Description: Kiln 2 Scrubber Data file: 102107_17.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785t Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % $ 

# ~ Methane 0.982 14.1878 n 

### 67.7056 Ethane 1.030 3.3347 15.9138 Propane 1.188 0.3371 1.6087 17.8596 100.0000 " '

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 16:58:24 Description: 25.1ppm C3 Data file: 102107_40.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Methane 0.957 12.7106 65.6739 Ethane 1.005 3.4196 17.6688 Propane 1.146 0.4982 2.5741 Propane 1.200 1.4127 7.2989 18.0411 100.0000 

# FQ(LA3

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 17:14:53 Description: 25.1 ppm C3 Data file: 102107_41.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Ethane Propane 1.016 1.149 0.1110

75.3333 0.0468

31.7428 2.346 0.2516 0.1060 2.417 0.3393 0.1430 f

' 

## ~ 

# s 31.8372 P 

# l y N 2 5 Pentane 2.591 75.5575 3.945 9.0955 3.8325 3.987 0.2735 0.1152 4.169 76.3627 32.1765 y ZS• 

## ~~ ~ ~~ZS

237.3245 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 17:28:05 Description: 50.7 ppm C3 Data file: 102107_42.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

~

~

~- -.



### ~ I

~ 

### —_.... ~..~,

~

i ]



### Component Retention Area Area % Propane 1.145 149.9910 39.4677 2.352 0.1125 0.0296 2.432 2.8124 0.7400 

## 3 Pentane 2.590 149.5898 39.3621

- 4.084 0.1742 0.0458

- 4.132 0.1160 0.0305

- 4.325 71.7971 18.8922

- 5.378 2.3371 0.6150

- 7.305 0.6041 0.1590

- 7.445 1.1548 0.3039

- 7.595 0.8493 0.2235

- 7.740 0.4969 0.1308 380.0351 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 17:36:45 Description: 50.7 ppm C3 Data file: 102107_43.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Propane 1.148 151.2953 49.7213 2.382 0.1983 0.0652 Pentane 2.485 0.9808 0.3223 Pentane 2.625 151.8124 49.8912 

## (<i

~ 

## LlV

~ 

## :i:1/iGbxrPPIr]

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 17:43:01 Description: 5ppm c1-c6 Data file: 102107_44.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Ethane 1.014 9.5578 12.3612 Propane 1.155 19.0783 24.6741 Butane 1.561 20.2575 26.1992 Pentane 2.609 25.9508 33.5624 5.299 1.5709 2.0317 5.306 0.9058 1.1715

77.3212 100.0000

### Lab name: TRC

Client: Hanosn Brick Client ID: 154785 Analysis date: 10/21/2007 17:52:23 Description: 5ppm c1-c6 Data file: 102107_45.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Ethane 1.012 9.5961 9.2536 Propane 1.155 18.0910 17.4454 Butane 1.565 20.0796 19.3630 Pentane 2.620 25.4088 24.5020 5.321 30.5254 29.4360

103.7009 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 18:00:06 Description: 5ppm c1-c6 Data file: 102107_46.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785t Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

## % Ethane 1.012 4.9596 4.7997 Ethane 1.032 3.2264 3.1224 Propane 1.154 18.1210 17.5369 Butane 1.565 20.5963 19.9324 Pentane 2.625 25.8936 25.0589 5.355 30.5340 29.5497

MRIrkIII%7i Bbx4rIIII]

# Method 26A Quality Assurance Fluoride Calibration Company Name Hanson Brick Source Kiln #2 Scrubber

Facility Elgin, Texas Job No. 154785 Sampling Date 10/21/2007 Technicians JSG Calibration Curves Via US EPA Method 26 Section 5.2 Initial Curve Scale=0 • 10n IC Calihra}inn Curvn- Fhinrldn Date Time Area 1 Area 2 Precision % Mean Area Conc /m L Calc /mL 10/21/2007 08:31 1.0057 1.0524 2.27 1 6.25 6 10/21/2007 0902 2.1385 2.1254 0.31 2 12.5 12 10121/2007 09:36 4.3161 4.3194 0.04 4 25 25 10121/2007 10:08 8.7842 8.8773 0.53 9 50 51 10121/2007 11:44 17.3019 17.4534 0.44 17 100 100 unecorreiarnon: u.auaaaeis

120 100 y'5.7262x+0.1702

- R 2 = 0.9999 E 80 ca d 60 

### 0 40 U 20 0 0 2 4 6 8 10 12 14 16 18 20 Area(eounts(

Final Curve IC Calihratinn Grtva Fhmridc Date Time Area 1 Area 2 Precision °/ Mean Area 

### I Conc /mL Calc /mL I Drift % 10/22/2007 15:37 1.0963 1.0961 0.01 1 6.25 6 0.54 10/22/2007 16:08 2.1515 2.1463 0.12 2 12.5 12 0.24 10122/2007 16:41 4.3246 4.3500 0.29 4 25 25 0.11 10/22/2007 17:10 9.0120 9.0183 0.03 9 50 52 1.06 10/22/2007 17:51 17.8693 17.8926 0.07 18 100 103 2.88 Line Gorreianon: u.y8894bzbtl

120 100 E 80 

## rn 2. 60 y= 5.5616x+ 0.3972 

### 0 40 R' = 0.9999 U 20 0 0 2 4 6 8 10 12 14 16 18 20 IArea (counts



# TRC

# Method 26A Qualit 

# ~ Assurance Chloride Calibratio Company Name Hanson Brick Source Kiln #2 Scrubber

Facility Elgin, Texas Job No. 154785 Sampling Date 10/21/2007 Technicians JSG Calibration Curves Via US EPA Method 26 Section 5.2 Initial Curve a,.re=n -inn ir Date Time Area 1 Area 2 Precision % Mean Area Conc /mL Calc /mL 10/21/2007 0831 1.6369 1.6718 1.05 2 6.25 6 10/21/2007 09:02 2.7004 2.6914 0.17 3 12.5 14 10/2112007 09:36 4.1760 4.1714 0.06 4 25 24 10/21/2007 10:08 7.6027 7.4650 0.91 8 50 49 10/2112007 11:44 14.6233 14.8332 0.71 15 100 101 LlneCorrelatlon: 0.999ti5336/ y = 7.216x - 5.6807 120 R' = 0.9993 100 E 80 a

' - 60 `o 40 U 20 0 0 2 4 6 8 10 12 14 16 Area(counts)

Final Curve Ir: rAllllfA}jnn r:nNP' r:hlnflfrP Date Time Area 1 Area 2 Precision % Mean Area Conc /mL Calc /mL Drift % 10/2212007 15:37 1.8681 1.9084 1.07 2 6.25 8 1.69 10/2212007 16:08 2.5964 2.6288 0.62 3 12.5 13 0.60 10/2212007 16:41 4.0675 4.1071 0.48 4 25 24 0.62 10/2212007 17:10 7.4187 7.3551 0.43 7 50 48 1.06 10/2212007 1751 14.8919 15.0299 0.46 15 100 102 1.68 Line Correlation: 0.998754567

120 100 E 80 

### ~ y = 7.1289x - 5.3587 60 R' = 0.9975 0 40 U 20 0 0 2 4 6 8 10 12 14 16 )Area (counts

/
~ t ~ ~ ~

### lon Chromatograph Analysis

Sample 

### Name: 6.25ug/mi STD Client: Hanson8rick Control Program. 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10121/2007 8:31 Location: Elgin, Texas

53826Hanson #28 modiied by TRC-Cubix Em lo ee ECD 1 100 N S 3-414.8 S80

88

7 i l i 6 i

5 i

38

25

13
1 - Floride2 3QhlDride - 4.507

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Rel.Area

% 

### 1 3.22 Floride 2.635 1.0057 1.66 2 4.51 Chloride 2.932 1.6369 2.70 3 11.33 n.a. 62.830 3.8025 6.27 4 11.68 n.a. 131.111 54.1980 89.37 Total: 199.508 60.6431 100.00

Testing Pertormed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 6.25ug/ml STD Client Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10/21/2007 8:46 Location: Elgin, Texas

153826Hanson #29 6.25u /ml STD ECD 1 100 N S 4 -91.P 27

88

7

63

5

38

2

13
1 

### - Floride2 3Qbbride 

### - 4.500 3 

### - 7.693

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. Ret.Time



### min Peak Name Height 

### PS Area

S*min Rel.Area

% 1 3.23 Floride 2.780 1.0524 1.72 2 4.50 Chloride 2.909 1.6718 2.74 3 7.69 n.a. 0.009 0.0022 0.00 4 11.27 n.a. 64.084 3.8862 6.36 5 11.63 n.a. 131.445 54.4591 89.17 Total: 

# 1 201.226 61.0717 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample 

### Name: 12.5ug/mISTD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10/2112007 9:02 Location: Elgin, Texas

153826Hanson#30 12.5u /mISTD ECD 1 10D 

### u S 4-91. 73

88

7

63

5

3

2

1 

### - Floride2 30130de 

### - 4.470 3 

### - 7.543

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. Ret.Time

min Peak Name Height S Area

S`min 

### Rel.Area

% 1 3.21 Floride 5.709 2.1385 3.40 2 4.47 Chloride 5.599 2.7004 4.29 3 7.54 n.a. 0.166 0.2112 0.34 4 11.22 n.a. 66.680 4.0189 6.39 5 11.57 n.a. 130.844 53.8647 85.59 Total: 208.998 62.9336 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 12.5ug/mISTD Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. 

## Method: Hanson Project #: 154785 

## Recording Time: 10121/2007 9:18 Location: Elgin, Texas

153826Hanson#31 12.5u /mISTD ECD 1 1W N S

88

7

63

5 

### 4 51aL38

25

13 1 

### - Floride2•3C11fl8ride 

### - 4.417 3 

### - 7.297

min -10- 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. Ret.Time

min Peak Name Height S Area S'min Rel.Area

% 1 3.18 Floride 5.794 2.1254 0.49 2 4.42 Chloride 5.534 2.6914 0.62 3 7.30 n.a. 0.174 0.2192 0.05 4 11.13 n.a. 511.120 58.0012 13.34 5 11.44 n.a. 509.760 371.7754 85.50 Total: 1032.383 434.8126 100.00

Testing PerFormed by TRC

### lon Chromatograph Analysis

Sample Name: 25ug/mi STD 

### Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 1012112007 9:36 Location: Elgin, Texas

153826Hanson #32 25u /ml STD ECD 1 10 N S 

# A 3111 7

88

75

63

5

3

25

13 1 

## - Floride2 3 dgAride 

## - 4.430

3 

## - 7.467

1 min 0.0 2.0 4.0 6.0 8.0 10 .0 1 2. 0 15.0


### No. Ret.Time

min Peak Name Height 

### PS Area

S*min Rel.Area



## % 1 3.17 Floride 11.908 4.3161 1.00 2 4.43 Chloride 10.934 4.1760 0.97 3 7.47 n.a. 0.166 0.2013 0.05 4 11.14 n.a. 511.078 58.2823 13.51 5 11.45 n.a. 509.779 364.4433 84.48 Total: 

# 1 1043.865 431.4190 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 25ug/mi STD 

### Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10/2112007 9:52 Location: Elgin, Texas

153826Hanson #33 25u /ml STD ECD 1 10 N S 4511. .873

88

7

63

5

38

2

1 g 1- Floride2 3 CtQride 

## - 4.387



## ; 3 

## - 7.380 

## '

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. Ret.Time

min 

### Peak Name Height PS 

### Area

S'min Rel.Area



## % 1 3.15 Floride 12.055 4.3194 1.00 2 4.39 Chloride 10.894 4.1714 0.97 3 7.38 n.a. 0.176 0.2206 0.05 4 11.07 n.a. 511.255 57.7796 13.41 5 11.37 n.a. 509.787 364.3584 84.57 Totai: 1044.167 430.8492 100.00

Testing Performed by TRC

### lon Chromatograph Analysis



### Sample Name: 50ug/mISTD 

### Client: Hanson8rick 

### Control Program: Hanson Source: Multiple 

### Quantif. Method: Hanson Project #: 154785 Recording 

### Time: 1012112007 10:08 Location: Elgin, Texas

153826Hanson #34 50u /mISTD ECD 1 100 N S 

### 3 41-11 0
88

7

63

5

38
i 

### - Floride 

### - 3.037 2 2 

### - Chloride 

### - 4.333

1

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Rel.Area



### % 1 3.04 Floride 28.318 8.7842 2.07 2 4.33 Chloride 22.906 7.6027 1.79 3 11.04 n.a. 510.941 60.0603 14.17 4 11.31 n.a. 509.775 347.5216 81.97 Total: 1071.939 423.9688 100.00

Testing Pertormed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 50ug/mISTD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. 

## Method: Hanson Project #: 154785 

## Recording Time: 

### 10/21/2007 10:23 Location: Elgin, Texas

10 153826Hanson #35 50u /mISTD ECD 1 NS M1bF71 0
88 i l

75

63

5

38
1 - Floride - 3.050 2 2 - Chloride - 4.350

13

3 - 7.230 '

-1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 15.0


### No. 

### Ret.Time

min Peak Name Height PS Area



### S*min Rel.Area

% 

### 1 3.05 Floride 28.211 8.8773 2.09 2 4.35 Chloride 22.335 7.4650 1.76 3 7.23 n.a. 0.157 0.1844 0.04 4 11.04 n.a. 510.982 61.8144 14.54 5 11.31 n.a. 509.783 346.9300 81.58 Total: 1071.468 425.2711 100.00

Testing Performed by TRC

### lon Chromatograph Analysis



### Sample Name: 100ug/mi STD Client: Hanson8rick 

### Control Program: Hanson Source: Multiple 

### Quantif. Method: 

### Hanson Project #: 154785 Recording 

### Time: 10/2112007 

### 11:44 Location: Elgin, Texas

10 153826Hanson #36 100u /ml STD ECD 1 NS 34311. ED7

8

7

63 1 

### - Floride 

### - 3.013

5 2 

### - Chloride 

### - 4.290

38

2

1

-1 min 0.0 1.3 2.5 3.8 5.0 6.3 7.5 8.8 10.0 11.3 13.4


### No. Ret.Time

min Peak Name Height 

### PS Area

S*min Rel.Area



### % 1 3.01 Floride 61.327 17.3019 4.31 2 4.29 Chloride 48.432 14.6233 3.64 3 11.01 n.a. 510.225 341.9576 85.23 4 11.21 n.a. 83.321 27.3479 6.82 Total: 703.305 401.2307 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 100ug/ml STD Client: Hanson8rick Control Program: 

### Hanson Source: 

### Multiple Quantif. 

### Method: Hanson Project #: 154785 Recording Time: 

### 10121/2007 11:58 Location: Elgin, Texas

1538261-lanson #37 100u /ml STD ECD 1 10 PS 34111. M

88

7

63 1 

## - Floride 

## - 3.037

5 2 

## - Chloride 

## - 4.323

38

2

13

-1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height PS Area

S'min Re1.Area



## % 1 3.04 Floride 61.867 17.4534 4.33 2 4.32 Chloride 47.022 14.8332 3.68 3 11.09 n.a. 510.308 343.4519 85.24 4 11.28 n.a. 82.901 27.1945 6.75 Total: 702.097 402.9331 100.00

Testing PerFormed by TRC

### lon Chromatograph Analysis

Sample Name: 6.25ug/ml STD Client: Hanson8rick Control Program: Hanson 

### Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10/22/2007 15:37 Location: Elgin, Texas

100 ,153826Hanson #57 6.25u /ml STD ECD 1 NS I 4-90.6 0390
88

75

63

5

38

25

13

1 

### - Floride 

### - 29 , 407hloride 

### - 4.403 3 

### - 7.167

-1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. 

### Ret.Time

min Peak Name Height 

### PS Area

S'min Rel.Area

% 1 2.95 Floride 2.985 1.0963 1.74 2 4.40 Chloride 3.144 1.8681 2.96 3 7.17 n.a. 0.120 0.1295 0.21 4 10.63 n.a. 49.295 5.2211 8.28 5 10.99 n.a. 138.541 54.7409 86.81 Total: 

# 1 194.085 63.0559 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 6.25ug/ml STD Clienf: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10/22/2007 15:51 Location: Elgin, Texas



### 10 153826Hanson #58 6.25u /ml STD ECD 1 FS 4-50.6 ®20 88

7

63

5

38

2

13 1 - Floride - 2.94~loride - 4.373 3 - 7.117
-1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
No. Ret.Time Peak Name Height Area Rel.Area

min PS S`min % 1 2.94 Floride 2.834 1.0961 1.68 2 4.37 Chloride 3.094 1.9084 2.93 3 7.12 n.a. 0.139 0.1619 0.25 4 10.55 n.a. 51.914 5.1659 7.93 5 10.92 n.a. 141.853 56.7929 87.21 Total: 199.833 65.1253 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 12.5ug/mISTD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: Hanson 

### Project #: 154785 Recording Time: 

### 10122/2007 16:08 Location: Elgin, Texas

153826Hanson #59 12.5u /mISTD ECD 1 10 uS 4-98. ®37
88

7

63

5

38

2

13 

# ,''.. 1 

### - Floride 

### - 

# a

. 9 rghloride 

### - 4.380 '. 3 

### - 7.127

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time



### min Peak Name Height 

### PS Area

S*min Rel.Area

% 1 2.95 Floride 5.988 2.1515 0.48 2 4.38 Chloride 5.365 2.5964 0.58 3 7.13 n.a. 0.136 0.1572 0.04 4 10.61 n.a. 510.642 74.7076 16.80 5 10.94 n.a. 509.888 364.9620 82.09 Total: 1032.019 444.5746 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 12.5ug/mISTD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif Method: 

### Hanson Project #: 154785 Recording Tlme: 

### 10/2212007 16:23 Location: Elgin, Texas

10 153826Hanson i180 12.5u /mISTD ECD 1 NS 4-90.5 3330 6

7

63

5

38

2

13 1 - Floride - VVhloride - 4.367

. 3 - 7.107

. 1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
No. Ret.Time Peak Name Height Area Rel.Area

min PS S*min % 1 2.94 Floride 5.885 2.1463 3.27 2 4.37 Chloride 5.440 2.6288 4.01 3 7.11 n.a. 0.146 0.1773 0.27 4 10.57 n.a. 53.951 5.9896 9.13 5 10.93 n.a. 138.935 54.6718 83.32 Total: 

# F 204.356 65.6137 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 25ug/ml STD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: Hanson 

### Project #: 154785 Recording Time: 

### 1012212007 16:41 Location: Elgin, Texas

10 153826Hanson #61 25u /ml STD ECD 1 NS 4-98. 867

88

7

63

5

38

25

1 

## - Floride 

## - 2.943 13 2 

## - Chloride 

## - 4.377

3 

## - 7.140

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. 

### Ret.Time

min Peak Name Height 

## ps Area

S`min 

### Rel.Area



## % 1 2.94 Floride 13.564 4.3246 6.56 2 4.38 Chloride 10.344 4.0675 6.17 3 7.14 n.a. 0.139 0.1581 0.24 4 10.63 n.a. 51.821 6.2482 9.48 5 10.97 n.a. 132.930 51.1390 77.56 Total: 

# 1 208.797 65.9373 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample 

### Name: 25ug/mi STD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10/2212007 16:56 Location: Elgin, Texas

100 153826Hanson #62 25u /ml STD ECD 1 uS 4-90. A87
88

7

6

5

38

25

13 1 

## - Floride 

## - 2.957 2 

## - Chloride 

## - 4.390

3 

## - 7.160

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height IJS Area

S*min Rel.Area



## % 1 2.96 Floride 13.113 4.3500 6.36 2 4.39 Chloride 10.026 4.1071 6.01 3 7.16 n.a. 0.135 0.1539 0.23 4 10.64 n.a. 57.858 6.1919 9.06 5 10.99 n.a. 136.553 53.5475 78.34 Total: 

# 1 217.686 68.3504 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 50ug/mISTD Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 1012212007 17:10 Location: Elgin, Texas

153826Hansoni163 50u /mISTD ECD 1 I, 10 N S 45141. 917



### . 88

75

63

5

38 1 

### - Floride 

### - 2.960
2 2 

### - Chloride 

### - 4.400

1

6.963

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14. 0


### No. Ret.Time

min Peak 

### Name Height IJS Area

S'min Rel.Area

% 1 2.96 Floride 31.442 9.0120 2.10 2 4.40 Chloride 21.080 7.4187 1.73 3 6.96 n.a. 0.132 0.1534 0.04 4 10.63 n.a. 510.832 68.2457 15.92 5 10.92 n.a. 509.895 343.7748 80.21 Total1 1073.381 428.6046 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 50ug/mISTD Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10122/2007 17:36 Location: Elgin, Texas

153826Hanson #64 50u /mISTD ECD 1 10 NS ~ 4-99. 333
8

7



### 63

5

38 i - Floride - 2.947

2 2 - Chloride - 4.407



### 13

6.970



### -1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height PS Area

S`min Re1.Area

% 1 2.95 Floride 32.740 9.0183 12.50 2 4.41 Chloride 21.912 7.3551 10.19 3 6.97 n.a. 0.111 0.1215 0.17 4 10.60 n.a. 62.900 6.5671 9.10 5 10.93 n.a. 129.377 49.1084 68.05 Total: 247.040 72.1704 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample 

### Name: 100ug/ml STD Client Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10/2212007 17:51 Location: Elgin, Texas

1538261-lanson #65 100u /ml STD ECD 1 100 N S 4 51-0I 3370
8

7
1 

### - Floride 

### - 2.947 6

5 2 

### - Chloride 

### - 4.403

38

25

1 

# L

3 

### - 6.973 i



### . 

## ._—

_ 1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Rel.Area

% 1 2.95 Floride 65.546 17.8693 4.44 2 4.40 Chloride 48.403 14.8919 3.70 3 6.97 n.a. 0.109 0.1165 0.03 4 10.64 n.a. 510.609 334.5583 83.07 5 10.87 n.a. 105.364 35.3277 8.77 Total: 730.031 402.7637 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 

### 100uglml STD Client Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10122/2007 18:05 Location: Elgin, Texas

10 153826Hanson i166 100u !ml STD ECD 1 OS 4 5101


### . 0

88

7
1 

### - Floride 

### - 2.923 6

2 

### - Chloride 

### - 4.373 5

38

25

13

6.940

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height 

### PS Area

S*min Rel.Area



### % 1 2.92 Floride 66.198 17.8926 4.38 2 4.37 Chloride 51.181 15.0299 3.68 3 6.94 n.a. 0.108 0.1155 0.03 4 10.64 n.a. 510.487 339.9618 83.24 5 10.88 n.a. 104.996 35.4315 8.68 Total: 

### 732.970 408.4312 100.00

Testing Performed by TRC

# APPENDIX D: CALIBRATION CERTIFICATIONSo d' 

## L 

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## v ou y

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## E D ll p

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# ? ° c m ~ ~ 

# o E n m o -2

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA



# ,/7`C c tra ISO 9001:2000
/~ 

## Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## CERTIFICATE OF ANALYSIS EPA PROTOCOL MIXTURE 

# PROCEDURE#: G1
CUSTOMER: TRC Air Measurements SGI ORDER # : 0114982 ITEM# : 1 P.O.# : 2007141. T-8 Jason 

### CERTIFICATION DATE: 9113/2007 EXPIRATION DATE: 9/1112009
CERTIFICATION HISTORY CYLINDER # : CC-187589 CYLINDER PRES: 2000 PSIG CGA OUTLET: 660 

### PRODUCT CODE: TRC-25



## COMPONENT DATE OF 

## ASSAY MEAN



## CONCENTRATION CERTIFIED



## CONCENTRATION ANALYTICAL



## ACCURACY Carbon Monoxide 8/29/2007 9/1312007 25.29 ppm

25.39 ppm 25.3 ppm +/- 1%
Nitric Oxide

NOx 8/30/2007 9/11/2007 25.28 ppm

25.27 ppm 25.3 ppm
25.3 ppm +/- 1%

Reference Value Only Propane 9/1212007 25.4 ppm 25.4 ppm +/- 1%

I3ALANGE Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCE STANDARDS 

## COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Carbon Monoxide NTRM-81679 CC-134736 101.0 ppm Nitric Oxide NTRM-81684 CC-202693 98.8 ppm Propane GMIS-1 CC-113884 100.3 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL # DETECTOR CALIBRATION 

## DATE(S) Carbon Monoxide Horiba VIA-510 1-100021-2Y NDIR 9/5/2007 Nitric Oxide CAI-400-CLD 6L09004 Cheml 8/28/2007 Propane H. Packard 6890 US00001434 GC - FID 9/412007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: 

# &/ )a DATE: 

# 9/13/2007

CODY HAMLIN

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www.spectragases.com

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA 

# ,pEctP

~ 

# a Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## CERTIFICATE OF ANALYSIS

CUSTOMER: TRC Air Measurements SGI ORDER # : 0114982 

### ITEM# : 2 P.O.# : 2007141, T-8 Jason CERTIFICATION DATE: 9/13/2007 EXPIRATION DATE: 9/11/2009

CERTIFICATION HISTORY 

### ISO 9001:2000



## EPA PROTOCOL MIXTURE PROCEDURE#: G1
CYLINDER # : CC-250142 CYLINDER PRES: 2000 PSIG CGA OUTLET: 660 PRODUCT CODE: TRC-25



## COMPONENT DATE OF 

## ASSAY MEAN



## CONCENTRATION CERTIFIED



## CONCENTRATION ANALYTICAL



## ACCURACY Carbon Monoxide 8/29/2007 9/13/2007 50.66 ppm

50.57 ppm 50.6 ppm +/_ 1%
Nitric Oxide

NOx 8/30/2007

9/11/2007 50.26 ppm

50.31 ppm 50.3 ppm

50.4 ppm +/- 1%

Reference Value Only Propane 9/12/2007 45.2 ppm 45.2 ppm +/- 1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: None


## REFERENCESTANDARDS COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Carbon Monoxide NTRM-81679 CC-134736 101.0 ppm Nitric Oxide NTRM-81684 CC-202693 98.8 ppm 

## Propane GMIS-1 CC-113884 100.3 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL # DETECTOR CALIBRATION DATE(S) Carbon Monoxide Horiba VIA-510 1-1000212Y NDIR 9/5/2007 Nitric Oxide CAI-400-CLD 6L09004 Cheml 8/28/2007 Propane H. Packard 6890 US00001434 GC - FID 9/4/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: 

# ~ 

# A4

DATE: 

### 9/13/2007



### CODY HAMLIN

Tel: +1 908-252-9300 Fax: +1 908-252-0811 www.spectragases.com

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA 

# ;pEctra ISO 9001:2000 

## Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865


## CERTIFICATE OF ANALYSIS EPA PROTOCOL MIXTURE PROCEDURE#: G1
CUSTOMER: Cubix Corporation SGI ORDER 

### # : 0086921 ITEM# 

### : 4 P.O.#: 2006136,T8TREY
CERTIFICATION DATE: 3/29/2006 EXPIRATION DATE: 3/28/2008
CERTIFICATION HISTORY CYLINDER # : CC-126734 CYLINDER PRES: 2000 PSIG CGA OUTLET: 660

COMPONENT DATE OF ASSAY MEAN

CONCENTRATION CERTIFIED CONCENTRATION ANALYTICAL ACCURACY Carbon Monoxide 3/21/2006 3/28/2006 84.82 ppm

84.44 ppm 84.6 ppm +/-1%
Nitric Oxide

NOx 3/15/2006 3/28/2006 85.90 ppm

85.67 ppm 85.8 ppm
85.8 ppm +/_ 1%

Reference Value Only Propane 3/29/2006 85.8 ppm 85.8 ppm +/_ 1%

tlALANC:t 

### Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCESTANDARDS COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Carbon Monoxide NTRM-81679 CC-135126 101 ppm Nitric Oxide NTRM-81684 CC-202720 98.8 ppm Propane GMIS-1 CC-113884 100.3 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL 

### # DETECTOR CALIBRATION DATE(S) Carbon Monoxide Horiba VIA-510 570423011 NDIR 3/23/2006 Nitric Oxide CAI-400-CLD 6L09004 Cheml 3/22/2006 Propane H. Packard 6890 US00001434 GC 

### - FID 3/6/2006

THIS STANDARD IS 

### NIST TRACEABLE. IT 

### WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: DATE: 

### 3/2912006

CHERYL PATINO

Tel: +1908-252-9300 Fax:+1 908-252-0811

www.spectragases.com

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA 

# p ECI ~ 

# a ISO 9 

## 0 01:2000 

## Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## CERTIFICATE OF ANALYSIS EPA PROTOCOL MIXTURE 

## PROCEDURE#: G1
CUSTOMER: TRC Air Measurements SGI ORDER # : 0106245 ITEM# : 4 P.O.# : 2006666,T8GRIZZ
CERTIFICATION DATE: 4/5/2007 EXPIRATION DATE: 4/2/2009

CERTIFICATION HISTORY 

### CYLINDER # : CC-98984 CYLINDER PRES: 2000 PSIG CGA OUTLET: 660



### COMPONENT DATE OF 

### ASSAY MEAN



### CONCENTRATION CERTIFIED



### CONCENTRATION ANALYTICAL 

### ACCURACY Carbon Monoxide 3/2712007 

### 4/5/2007 252.2 ppm



### 253.1 ppm 253 ppm +/- 1%


### Nitric Oxide

NOx 3/26/2007 4/2/2007 249.6 ppm

249.6 ppm 250 ppm
250 ppm +/- 1%

Reference Value Only Propane 3/28/2007 251 ppm 251 ppm +/-1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCE STANDARDS COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Carbon Monoxide GMIS-1 CC-106962 505 ppm Nitric Oxide GMIS-1 CC-135383 251 ppm Propane GMIS-1 CC-20010 1013 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL # DETECTOR CALIBRATION DATE(S) Calbon Monoxide Horiba VIA-510 H0002L2Y NDIR 3/27/2007 Nitric Oxide CAI-400-CLD 6L09004 Cheml 3/29/2007 Propane H. Packard 6890 US00001434 GC - FID 3/13/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.



### ANALYST: DATE: 4/5/2007



### CHERYL PATINO

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www. spectragases. com

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA 

# pE ' 

# tra ISO 9001:20000 

## Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## CERTIFICATE OF ANALYSIS EPA PROTOCOL MIXTURE PROCEDURE#: G1
CUSTOMER: TRC Air Measurements SGI ORDER # : 0106245 ITEM# : 5 P.O.# : 2006666,T8GRI77
CERTIFICATION DATE: 4/5/2007 EXPIRATION DATE: 4/4/2009
CERTIFICATION HISTORY CYLINDER # : CC-85249 CYLINDER PRES: 2000 PSIG CGA OUTLET: 660

COMPONENT DATE OF ASSAY MEAN

CONCENTRATION CERTIFIED

CONCENTRATION ANALYTICAL ACCURACY Carbon Monoxide 3/28/2007 4/5/2007 496.1 ppm

496.3 ppm 496 ppm +/- 1%
Nitric Oxide

NOx 3/27/2007

4/4/2007 506.1 ppm

505.4 ppm 506 ppm
506 ppm +/- 1%

Reference Value Only Propane 3/2812007 450 ppm 450 ppm +/_ 1%

Lt9ALANGt Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCE STANDARDS COMPONENT SRMINTRM# CYLINDER# CONCENTRATION Carbon Monoxide GMIS-1 CC-106962 505 ppm Nitric Oxide NTRM-81687 CC-131062 992 ppm Propane GMIS-1 CC-20010 1013 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL # DETECTOR CALIBRATION DATE(S) Carbon Monoxide Horiba VIA-510 1-100021-2Y NDIR 3/27/2007 Nitric Oxide CAI-400-CLD 6L09004 Cheml 4/4/2007 Propane H. Packard 6890 US00001434 GC - FID 3/13/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: DATE: 

### 4/5/2007

CHERYL PATINO

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www.spectragases.com

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA 

# t Eetra ISO 9001:2000 

## Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865


## CERTIFICATE OF ANALYSIS EPA PROTOCOL MIXTURE PROCEDURE#: G1 

### CUSTOMER: TRC Air Measurements 

### SGI ORDER # : 0106245 ITEM# 

### : 2 

### P.O.#: 2006666,T8GRI77
CERTIFICATION DATE: 4/3/2007 EXPIRATION DATE: 4/3/2010
CERTIFICATION HISTORY 

### CYLINDER # : CC-131257 

### CYLINDER PRES: 2000 PSIG CGA OUTLET: 590

COMPONENT DATE OF ASSAY MEAN

CONCENTRATION CERTIFIED CONCENTRATION ANALYTICAL ACCURACY Carbon Dioxide 4/3/2007 10.07 

### % 10.07 

### % +/- 1% Oxygen 4/3/2007 10.00 

### % 10.00 

### % +/- 1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCE STANDARDS COMPONENT SRM/NTRM# 

# I CYLINDER# CONCENTRATION Carbon Dioxide NTRM-82745x CC-79933 20.0 

### % Oxygen NTRM-82659x CC-83906 22.8 %

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL# DETECTOR CALIBRATION DATE(S) Carbon Dioxide CIA-300 S03001 NDIR 4/3/2007 Oxygen CAI-300 S03001 PM 3/29/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: DATE: 

### 4/3/2007 TED NEEME

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www.spectragases.com

# t POE"Ctre Spectra Gases Inc. 3434 Route 22 West, Branchburg, New Jersey 08876 USA
ISO 9001:2000

Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## CERTIFICATE OF ANALYSIS

CUSTOMER: TRC Air Measurements SGI ORDER # : 0098632 

### ITEM# : 4 P.O.# : 2006465,T8GRI77
CERTIFICATION DATE: 11/3/2006 EXPIRATION DATE: 11/312009
CERTIFICATION HISTORY 

## EPA PROTOCOL MIXTURE PROCEDURE#: G1

CYLINDER # : CC-94734 CYLINDER PRES: 1900 PSIG CGA OUTLET: 590

COMPONENT DATE OF ASSAY MEAN

CONCENTRATION CERTIFIED CONCENTRATION ANALYTICAL ACCURACY Carbon Dioxide 11/3/2006 5.04 

### % 5.04 

### % +/- 1% Oxygen 11/3/2006 21.1 

### % 21.1 

### % +/_ 1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCE STANDARDS COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Carbon Dioxide GMIS-1 CC-85169 5.02 

### % Oxygen NTRM-82659x CC-83906 22.8 

### %

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL 

### # DETECTOR CALIBRATION DATE(S) Carbon Dioxide CAI-300 S03001 NDIR 11/1/2006 Oxygen CAI-300 S03001 PM 10/16/2006

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: DATE: 11/3/2006

JAMES SCHMIDT

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www.spectragases.com

### 3434 Route 22 West, Branchburg, New Jersey 08876 USA 

# t Octra ISO 9001:2000 

## Spectra Gases Inc.

Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## RECERTIFICATION OF ANALYSIS EPA PROTOCOL MIXTURE 

# PROCEDURE#: G1
CUSTOMER: Cubix Corporation SGI ORDER # : 103425 ITEM# : 1 P.O.# : 2006589, T8Jason
CERTIFICATION DATE: 2/6/2007 EXPIRATION DATE: 2/6/2009
CERTIFICATION HISTORY CYLINDER # : CC-133266 CYLINDER PRES: 1800 PSIG CGA OUTLET: 660



### COMPONENT DATE OF 

### ASSAY MEAN



### CONCENTRATION CERTIFIED



### CONCENTRATION ANALYTICAL 

### ACCURACY Nitrogen Dioxide 6/2072006 2/6/2007 46.10 ppm

45.73 ppm 45.9 ppm +/- 3%

13ALANGE Air PREVIOUS CERTIFICATION DATES: 6/2712006 by Spectra Gases
REFERENCE STANDARDS 

### COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Nitrogen Dioxide NTRM-82660 CC-200753 97.6 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL# DETECTOR CALIBRATION DATE(S) NitrogenDioxide Thermo42i-HL 621417605 Cheml 2/6/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: ~ i ' DATE: 

### 2/6/2007



## FRED PIKULA

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www.spectragases.com

# hka SPECTRR CASES INC. 3434 Route 22 West • Sranehburg, Nd 08878 USA Tel.: (908) 252-9300 •(S00) 932-0624 • Faxi (908) 252-0811 Shipped From: 80 Industrial Drive • Alpha, NJ 08865



## RECERTIFICATION OF ANALYSIS EPA PROTOCOL MIXTURE 

# PROCEDURE#: G1 CUSTOMER: Cubix Corporation CYLINDER # : CC-143342 SGI ORDER # 

### 0072957 CYLINDER PRES: 1200 PSIG ITEM# : CGA OUTLET: 660 P.O.# : 

### 2005477,T8Shane
CERTIFICATION DATE: 6/22/2005 EXPIRATION DATE: 6/2212008
CERTIFICATION HISTORY 

### COMPONENT DATE OF 

### ASSAY MEAN



### CONCENTRATION CERTIFIED



### CONCENTRATION ANALYTICAL 

### ACCURACY Sulfur Dioxide 4/23/2003 6/22/2005 45.80 ppm

45.31 ppm 45.6 ppm +/- 1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: 4/23/2003 by Spectra Gases
REFERENCE STANDARDS 

### COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Sulfur Dioxide NTRM-81694 CC-162874 96.1 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL# DETECTOR CALIBRATION DATE(S) Sulfur Dioxide Horiba VIA-510 851221093 NDIR 612/2005

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF T / HE C

~ 

### YLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: ~ 1 ' 

### DATE: 

### 6/22/2005



### FRED PIKULA

# t P2tra Spectra Gases Inc. 3434 Route 22 West, Branchburg, New Jersey 08876 USA
ISO 9001:2000

Shipped from: 80 Industrial Drive, Alpha, NJ 08865


## CERTIFICATE OF ANALYSIS

CUSTOMER: TRC Air Measurements 

### SGI ORDER # : 0108271 ITEM# : 3 P.O.# : 2007023,T1 1 TREY 

### CERTIFICATION DATE: 5/11/2007 

### EXPIRATION DATE: 5/11/2009
CERTIFICATION HISTORY 

## EPA PROTOCOL MIXTURE PROCEDURE#: G1
CYLINDER 

### # : CC-94390 

### CYLINDER PRES: 2000 PSIG 

### CGA OUTLET: 660 

### PRODUCT CODE: TRC 17

COMPONENT DATE OF ASSAY MEAN

CONCENTRATION CERTIFIED CONCENTRATION ANALYTICAL ACCURACY Sulfur Dioxide 5/3/2007 5/11/2007 101.8 ppm

101.3 ppm 101.5 ppm +/- 1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: None
REFERENCESTANDARDS COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Sulfur Dioxide GMIS-1 CC-143657 193.4 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL 

### # DETECTOR CALIBRATION DATE(S) Sulfur Dioxide Horiba VIA-510 851221093 NDIR 5/9/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.

ANALYST: 

### /' - DATE: 

### 5/11/2007 FRED PIKULA

Tel:+1 908-252-9300 Fax:+1 908-252-0811

www.spectragases.com

# SPECTRA GASES INC. 

# !3 3434 Route 22 Wesfy Branchburg, Nd 08876 USA Tel.' (908) 252-9300 •(800) 932-0624 • Fax (908) 25220811 

# ki Shipped From: 80 Intlustrial Drive • Alpha, NJ 08865



## RECERTIFICATION OF ANALYSIS EPA PROTOCOL MIXTURE PROCEDURE#: G2
CUSTOMER: Cubix Corporation CYLINDER #: CC-130956 SGI ORDER #: 0072957 CYLINDER PRES: 2000 PSIG ITEM# : 1 CGA OUTLET: 660 P.O.# : 2005477.T8Shane 

### CERTIFICATION DATE: 6/22/2005 EXPIRATION DATE: 6/22/2008
CERTIFICATION HISTORY


### COMPONENT DATE OF 

### ASSAY MEAN



### CONCENTRATION CERTIFIED



### CONCENTRATION ANALYTICAL 

### ACCURACY Sulfur Dioxide 4/2412003 6/22/2005 257.0 ppm

255.8 ppm 256 ppm +/_ 1%

tfALANGt Nitrogen PREVIOUS CERTIFICATION DATES: 412412003 by Spectra Gases 

### REFERENCESTANDARDS COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Sulfur Dioxide GMIS-1 CC-135535 202 ppm

INSTRUMENTATION COMPONENT MAKE/MODEL SERIAL # DETECTOR CALIBRATION DATE(S) Sulfur Dioxide Horiba VIA-510 851221093 NDIR 618/2005

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.



### ANALYST: ~ I ' ?' 

### DATE: 6/22/2005

FRED PIKULA

# L Ctra Spectra Gases Inc. 3434 Route 22 West, Branchburg, New Jersey 08876 USA
ISO 9001:2000



### Shipped from: 80 Industrial Drive, Alpha, NJ 08865



## RECERTIFICATION OF ANALYSIS

CUSTOMER: TRC Air Measurements SGI ORDER # : 0105188 ITEM# : 1 P.O.# : 2006625, T6 Ross
CERTIFICATION DATE: 4/3/2007 EXPIRATION DATE: 4/312010
CERTIFICATION HISTORY 

## EPA PROTOCOL MIXTURE PROCEDURE#: G1
CYLINDER # : CC-65912 CYLINDER PRES: 1700 PSIG CGA OUTLET: 660



## COMPONENT DATE OF 

## ASSAY MEAN



## CONCENTRATION CERTIFIED



## CONCENTRATION ANALYTICAL



## ACCURACY Sulfur Dioxide 1/3/2005 4/3/2007 447.0 ppm

445.1 ppm 446 ppm +/- 1%

BALANCE Nitrogen PREVIOUS CERTIFICATION DATES: 11312005 by Spectra Gases
REFERENCE STANDARDS 

## COMPONENT SRM/NTRM# CYLINDER# CONCENTRATION Sulfur Dioxide NTRM-81662 CC-143755 990 ppm

INSTRUMEN TATION COMPONENT MAKE/MODEL SERIAL # DETECTOR CALIBRATION DATE(S) Sulfur Dioxide Horiba VIA-510 851221093 NDIR 4/3/2007

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG.



## v !

' 1 J



# ~ )
ANALYST: ~ 1 

### ' , DATE: 

### 4/3/2007



### FRED PIKULA

Tel: +1 908-252-9300 Fax: +1 908-252-0811

www.spectragases.com

# APPENDIX E: DATA ACQUISITION RECORDS, GAS CHROMATOGRAMS, AND ION CHROMATOGRAMS

# Data Acquisition Records 154785 Hanson Brick
Source Run Number Date Time NOx (pmmv) CO (ppmv) 02 (%) CO2 (%) THC (ppmv) S02in (ppmv) S02out (ppmv) Kiln 2 Scrubber 10/21/2007 846:20 7.06 115.20 18.92 1.27 0.00 10.70 6.46 Kiln 2 Scrubber 10/21/2007 8:47:20 0.31 96.65 18.33 1.60 0.00 12.20 8.10 Kiln 2 Scrubber 10/21/2007 8:48:20 0.09 0.55 -0.01 -0.10 0.00 5.70 0.68 Kiln 2 Scrubber 10/21/2007 8:49:20 0.04 0.55 -0.02 -0.11 0.00 4.55 0.62 Kiln 2 Scrubber 10/21/2007 8:50:20 0.05 0.00 -0.04 0.07 0.00 0.00 0.62 Kiln 2 Scrubber 10/21/2007 8:51:20 0.02 0.00 -0.05 0.05 0.00 -0.10 0.62 Kiln 2 Scrubber 10/21/2007 8:52:20 0.00 0.05 -0.06 0.07 0.00 -0.10 -0.08 Kiln 2 Scrubber 10/2112007 8:53:20 0.01 0.05 -0.06 0.05 0.00 -0.10 -0.14 Kiln 2 Scrubber 10/21/2007 8:50:16 0.01 0.00 -0.06 0.05 0.00 -0.20 -0.14 Kilu 2 Scrubber 10/21/2007 85113 -0.14 0.00 -0.07 0.04 0.00 0.10 -0.14 Kiln 2 Scrubber CE 10/21/2007 8:52:13 -0.13 0.05 -0.08 0.05 0.00 0.10 -0.20 Kiln 2 Scrubber 10/21/2007 853:13 43.47 165.55 6.15 4.78 0.00 0.00 -0.14 Kiln2Scrubber 10/21/2007 8:54:13 49.83 480.75 9.95 10.01 0.00 346.55 84.64 Kiln 2 Serubber 10/2112007 8:55:13 50.21 485.30 9.96 10.02 0.00 363.00 100.80 Kiln 2 Scrubber 10/21/2007 8:56:13 50.26 488.30 9.96 10.05 -0.10 363.80 101.12 Kiln2Scrubber 10/21/2007 8:57:13 50.42 501.90 9.97 10.03 0.00 364.10 101.22 Kiln 2 Scrubber 10/21/2007 8:58:13 50.36 496.35 10.02 10.06 0.00 373.25 101.28 Kiln 2 Scrubber 10/21/2007 8:59:13 50.23 495.85 10.06 10.06 -0.10 444.09 101.30 Kiln 2 Scrubber 10/21/2007 8:59:47 50.18 500.90 10.06 10.07 0.00 444.27 101.36 Kiln 2 Scrubber CE 10l21l2007 9:00:47 50.29 496.35 10.06 10.05 0.00 444.39 101.30 Kiln 2 Scrubber 10/21/2007 9:01:47 17.93 500.90 10.07 10.06 0.00 444.51 101.42 Kiln 2 Scrubber 10/21/2007 9:02:47 24.41 249.80 21.20 5.09 0.00 417.62 101.42 Kiln 2 Scrubber 10/21/2007 9:03:47 24.71 250.75 21.20 5.08 0.00 417.26 101.22 Kiln 2 Scrubber

- 10/21/2007 9:04:47 24.71 249.20 21.21 5.07 4.80 254.51 101.24 Kiln 2 Scrubber 10/21/2007 9:05:47 24.70 251.25 21.23 5.07 0.00 254.57 101.24 Kiln2Scrubber 10/21/2007 9:06:47 24.82 249.20 21.22 5.08 0.00 254.21 100.86 Kiln 2 Scrubber 10/21/2007 9:07:42 24.78 250.30 21.21 5.08 0.00 254.39 44.38 Ki1n 2 Scrubber CE 10/21/2007 9:08:42 24.70 251.75 21.23 5.08 0.00 254.45 44.48 Kiln 2 Scrubber 10/21/2007 9:09:42 24.77 250.70 21.23 5.09 0.00 254.57 44.56 Kiln 2 Scrubber CE 10/21/2007 9:10:27 56.32 237.60 10.12 10.07 0.00 253.23 5.68 Kiln 2 Scrubber 10/21/2007 9:11:27 10.86 135.10 10.09 10.08 0.00 253.48 1.72 Kiln 2 Scrubber 10/21/2007 9:12:27 82.90 120.55 10.10 10.07 0.00 247.80 1.78 Kdn 2 Scrubber 10/21/2007 9:13:27 2.11 4.55 -0.03 0.10 0.00 46:65 196.48 Kiln 2 Scrubber 10/21/2007 9:14:27 0.20 0.05 -0.05 0.11 0.00 47.20 198.92 Kiln 2 Scrubber 10/21/2007 9:14:57 0.10 0.05 -0.05 0.09 8.20 47.20 198.92 Kiln 2 Scrubber 10/21/2007 9:15:57 0.15 0.05 -0.05 0.08 10.30 50.61 198.92 Kiln 2 Scrubber 10/21/2007 9:16:57 0.44 0.05 -0.07 0.10 4.60 236.16 53.36 Kiln 2 Scrubber SSB 10l21/2007 9:17:56 0.40 0.05 -0.07 0.09 -2.30 245.00 44.50 Kiln 2 Scrubber 10/21/2007 9:18:56 0.46 0.05 -0.07 0.08 4.00 246.83 42.18 KOn 2 Scrubber 10/21/2007 9:19:56 0.45 0.05 -0.08 0.12 -6.80 247.38 41.58 Kiln 2 Scrubber 10/21/2007 9:20:56 36.94 24.00 -0.08 0.12 -1.60 63.41 24.26 Kiln 2 Scrubber 10/21/2007 9:21:56 49.10 46.60 -0.09 0.10 4.80 20.91 11.02 Kiln 2 Scrubber 10/21/2007 9:22:56 27.80 30.55 -0.07 0.10 4.80 14.39 6.52 Kiln 2 Scrubber SSB 10/21/2007 9:23:42 24.87 24.00 -0.09 0.11 4.70 12.07 4.82 Kiln2Scrubber 10/21/2007 9:24:42 24.57 24.00 -0.08 0.10 -103.80 10.43 4.16 Kiln 2 Scrubber 10/21/2007 9:25:42 24.63 24.00 -0.08 0.09 0.00 10.00 3.96 Kiln 2 Scrubber 10/21/2007 9:26:42 6.63 8.10 7.42 7.76 0.00 11.04 4.02 Kiln 2 Scrubber 10/21/2007 9:27:42 1.42 1.10 9.53 9.58 0.00 11.16 3.84 Kiln 2 Scrubber 10/21/2007 9:28:03 0.88 0.55 9.71 9.72 0.00 11.59 3.72 Kiln 2 Scmbber SSB 10/2112007 9:29:03 0.42 0.05 9.91 9.95 0.00 12.07 3.42 Kiln 2 Scrubber 10/21/2007 9:30:03 120.58 118.60 3.86 3.46 -135.49 12.87 2.64 Kiln 2 Scrubber 10/21 /2007 9:31:03 121.72 231.05 0.45 0.69 133.14 13.48 2.02 Kiln 2 Scrubber 10/21/2007 9:31:57 121.72 247.25 0.02 0.22 129.64 14.33 1.72 Kiln 2 Scrubber SSB 10/21/2007 9:32:57 121.72 251.75 -0.04 0.13 127.65 15.85 1.60 Kiln 2 Scrubber 10/21/2007 9:33:57 121.73 156.05 -0.07 0.11 0.00 16.40 1.48 Kiln 2 Scrubber 10/21/2007 9:34:27 49.46 54.75 -0.07 0.12 0.00 16.65 1.42 Kiln 2 Scrubber SSB 10/21/2007 9:35:27 7.00 7.65 -0.07 0.13 0.00 17.13 1.30 Kiln 2 Scrubber 10/21/2007 9:36:27 24.83 13.70 -0.08 0.13 22.06 17.20 1.24 Kiln 2 Scrubber 10/21/2007 9:37:27 60.62 47.65 -0.06 0.13 83.55 17.38 2.02 Kiln 2 Scrubber 10/21/2007 9:37:58 71.94 67.25 -0.07 0.12 85.74 17.38 1.78 Kiln 2 Scrubber SSB 10/21/2007 9:38:58 80.37 76.75 -0.08 0.12 86.48 17.68 1.60 

### 1 

# C: TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln 2 Scmbber 10212007 9:39:52 79.74 76.75 -0.07 0.11 50.43 17.80 1.54 Kdn 2 Serubber 1021/2007 9:40:52 59.89 57.25 -0.07 0.13 50.11 17.62 1.48 Kiln 2 Scrubber 10212007 9:41:52 50.60 48.60 -0.07 0.12 21.14 18.05 1.42 Kiln 2 Scrubber 10212007 9:42:52 33.44 32.05 -0.08 0.11 21.33 18.41 1.36 Kiln 2 Scrubber 10/21/2007 9:43:52 27.68 26.60 -0.09 0.12 21.45 18.17 1.30 Kilu 2 Scrubber 10/21/2007 9:44:52 25.70 24.55 -0.08 0.11 21.31 18.23 1.24 

### Kiln 2 Scrubber 10212007 9:45:52 24.97 24.10 -0.07 0.12 86.31 18.23 0.92 Kiln 2 Scrubber THC CE 10212007 9:46:52 57.65 54.35 -0.08 0.13 85.85 18.48 1.12 Kiln 2 Scrubber 10212007 9:47:52 76.19 73.40 -0.08 0.12 86.93 18.60 1.12 Kiln 2 Scrubber 10212007 9:48:23 80.10 76.85 -0.08 0.11 87.46 18.48 1.06 Kibt 2 Scrubber 10212007 9:49:23 83.01 79.85 -0.08 0.12 86.71 18.78 1.00 Kilu 2 Scrubber 10/212007 9:50:23 84.19 81.35 -0.08 0.13 50.80 18.78 1.06 

### Kiln 2 Scrubber TT-IC CE ] 0212007 9:51:08 62.89 62.25 -0.09 0.12 48.88 18.72 0.94 Kiln 2 Scrubber 10212007 9:52:08 51.26 49.70 -0.09 0.13 48.23 18.84 0.94 Kiln 2 Scrubber 10212007 9:53:08 34.71 40.65 -0.08 0.14 20.71 18.90 0.74 Kiln 2 Scrubber 1 0212007 9:54:08 25.07 24.60 -0.08 0.14 24.36 18.96 0.62 

### Kiln 2 Scrubber THC CE 10212007 9:54:10 24.94 24.60 -0.08 0.12 24.50 19.09 0.56 Kiln 2 Scrubber 10212007 9:55:10 24.69 24.05 -0.09 0.13 23.52 18.96 0.56 

### Kiln 2 Scrubber 102112007 9:56:10 24.69 24.05 -0.09 0.12 23.74 19.02 0.50 Kiln 2 Scrubber 10212007 9:57:10 24.67 24.10 -0.08 0.14 24.61 18.96 0.50 Kiln 2 Scrubber 10/21/2007 9:58:10 24.62 24.05 -0.08 0.14 25.33 19.21 0.44 

### Kiln 2 Scmbber 10/21/2007 9:58:22 24.62 24.05 -0.09 0.14 25.27 19.15 0.50 Kiln 2 Scrubber 10212007 9:59:22 24.67 24.05 -0.09 0.13 23.75 19.51 0.44 Kiln 2 Scrubber 1 0/212007 10:00:22 24.55 24.05 -0.09 0.13 25.60 19.45 0.44 KiW 2 Scrubber 10212007 10:01:22 24.60 24.05 -0.08 0.15 26.05 19.63 0.44 Kiln 2 Scrubber 10212007 10:02:22 24.52 24.05 -0.08 0.14 25.03 19.57 0.44 Kiln 2 Scrubber 10212007 10:03:22 39.75 24.05 -0.09 0.14 5.52 19.82 0.44 Ktln 2 Scrubber 10212007 10:04:22 37.02 24.05 -0.09 0.17 5.40 19.45 0.44 Kiln 2 Scrubber 10212007 10:05:22 38.40 24.05 -0.09 0.16 4.26 19.82 0.44 Kiln 2 Scrubber 10212007 10:06:22 38.83 67.80 9.74 1.24 5.13 19.82 3.96 Ki]n 2 Scmbber 10212007 1 0:07:22 39.59 103.80 14.98 1.71 5.43 19.63 5.06 Kiln 2 Scrubber 10212007 10:08:22 40.12 115.80 16.96 1.90 5.07 20.06 5.48 Kiln 2 Scrubber 10212007 10:09:22 40.49 118.65 18.11 1.91 9.39 20.00 8.88 Kiln 2 Scrubber 10212007 10:10:22 40.71 125.10 18.22 1.96 9.16 20.00 10.16 Kiln 2 Scrubber 10212007 10:11:22 40.88 126.65 18.16 2.00 8.66 19.76 10.90 Kiln 2 Scrubber 10212007 10:12:22 40.95 123.15 18.37 1.91 8.60 20.00 11.20 Kiln 2 Scrubber 10/21/2007 10:13:22 41.12 123.00 18.38 1.91 9.18 20.00 11.08 Kiln 2 Scrubber 10/21/2007 10:14:22 41.18 126.00 18.24 1.98 9.23 20.06 10.40 Kiln 2 Scrubber 1021/2007 10:15:22 41.28 126.05 18.33 1.93 8.88 20.37 9.44 Kiln 2 Scrubber 10/21/2007 10:16:22 41.41 123.50 18.38 1.90 8.64 20.18 8.96 Kiln 2 Scmbber 10212007 10:17:22 41.41 123.50 18.35 1.94 9.44 20.30 8.76 Kilu 2 Scrubber 10212007 10:18:22 41.41 128.00 18.30 1.96 9.01 20.37 8.16 Kiin 2 Scmbber 10212007 10:19:22 41.63 123.95 18.36 1.93 8.87 20.24 8.16 Kiln2Scrubber ]0212007 10:20:22 41.49 122.45 18.39 1.89 9.36 20.67 8.40 Kiln 2 Scrubber 10212007 10:21:22 41.52 122.95 18.45 1.86 9.36 20.37 8.70 Kiln 2 Scrubber 10212007 10:22:22 41.55 122.95 18.44 1.86 9.42 153.96 8.90 Kiln 2 Scrubber 10212007 10:23:22 41.49 106.65 19.11 1.46 7181 78.35 8.16 Kiln 2 Scrubber 10212007 10:24:22 41.68 119.95 19.56 1.26 10.55 141.04 5.86 Kiln 2 Scrubber 10/21/2007 10:25:22 41.82 114.15 18.98 1.59 8.81 156.71 6.58 Kiln 2 Scrubber 10212007 10:26:22 41.79 100.60 18.49 1.84 8.60 160.18 7.74 

### Kiln 2 Scrubber NOx CCE 10212007 10:27:22 41_93 98.60 18.44 1.86 8.71 162.32 8.82 Kiln 2 Scrubber NOx CCE 10212007 10:28:22 41_84 98.15 18.45 1.87 9.04 166.46 9.32 

### Kiln 2 Scrubber NOx CCE 10/21/2007 10:29:22 41_91 103.15 18.30 1.95 9.24 188.23 10.78 Kiln 2 Scrubber 10/21/2007 10:30:22 41.91 112.65 18.31 1.94 9.33 193.72 11.20 Kiln 2 Scrubber 10/21/2007 10:31:22 41.98 120.95 18.17 2.03 9.29 197.56 10.34 Kiln 2 Scrubber 10/21/2007 10:32:22 41.83 121.00 18.14 2.05 9.26 189.82 10.22 Kiln 2 Scrubber 10212007 10:33:22 42.00 118.50 18.30 1.95 9.00 187.32 10.48 Kiln 2 Scrubber 10212007 10:34:22 39.83 119.50 18.31 1.96 9.85 191.22 10.60 Kiln 2 Scrubber 10212007 10:35:22 13.16 123.45 18.14 2.05 9.58 194.70 10.28 Kiln 2 Scrubber 10212007 10:36:22 10.75 120.40 18.30 1.95 9.45 187.32 11.26 Kiln 2 Scrubber 10212007 10:37:22 9.69 121.50 18.37 1.94 9.68 186.46 11.74 Kiln 2 Scrubber 10212007 10:38:22 9.38 120.00 18.30 1.95 10.13 189.02 12.10 

## 2 

# ~ 'TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln2Scrubber 10/21/2007 10:39:22 8.98 126.50 18.32 1.94 10.13 192.07 12.54 Kiln 2 Saubber 10/21/2007 10:40:22 8.97 123.50 18.36 1.96 9.53 188.05 13.02 Kiln 2 Scrubber 10/21/2007 10:41:22 8.97 120.95 18.37 1.92 9.67 185.91 13.46 Kiln 2 Scrubber 10/21/2007 10:42:22 8.53 121.50 18.44 1.90 10.25 187.50 13.50 Kiln2Scrubber 10/21/2007 10:43:22 8.55 126.50 18.30 1.97 10.14 194.27 13.26 Kiln 2 Scmbber 10/21/2007 10:44:22 8.77 122.05 18.31 1.95 9.92 189.15 14.12 Kiln 2 Scrubber 10/21/2007 10:45:22 8.33 120.05 18.44 1.91 9.91 187.32 14.92 Kiln2Scrubber 10/21/2007 10:46:22 7.99 124.00 18.39 1.92 10.23 194.51 14.72 Kiln 2 Scrubber 10121/2007 10:47:22 8.10 126.05 18.34 1.95 9.97 194.76 15.34 Kiln 2 Scrubber 10/21/2007 10:48:22 8.43 121.55 18.39 1.93 6.83 173.78 16.12 Kiln 2 Scmbber 10/21/2007 104922 5.29 99.65 19.36 1.37 27.02 106.77 10.96 Kiln 2 Scrubber 10/21/2007 10:50:22 4.42 119.50 19.42 1.35 9.84 168.84 8.64 Kiln 2 Scrubber 10/21/2007 10:51:22 8.31 120.00 18.45 1.91 9.35 183.29 11.38 Kiln 2 Scmbber 10/21/2007 10:52:22 9.52 115.15 18.14 2.06 9.04 185.67 11.14 Ki1n2Scrubber 10/21/2007 10:53:00 9.92 114.15 18.13 2.07 9.47 185.06 10.96 Kiln 2 Scrubber 

## c] 10/21/2007 10:54:00 9.51 114.65 18.20 2.03 9.63 182.50 11.44 KiIn2Scrubber Cl 10/21/2007 10:55:00 9.55 121.50 18.12 2.06 9.54 182.32 11.26 Kiln 2 Saubber Cl 10/21/2007 10:56:00 9.43 118.45 18.24 1.98 9.50 185.18 11.68 Kiln 2 Scrubber Cl 10/21/2007 10:57:00 9.27 118.45 18.28 1.98 9.76 188.48 12.28 Kiln2Scmbber Cl 10/21/2007 10:58:00 9.04 119.50 18.27 1.97 10.16 192.87 12.90 Kiln 2 Scrubber 

## cl 10/21/2007 10:59:00 8.84 124.00 18.25 2.00 10.22 194.82 13.14 Kiln2Scrubber Cl 10/21/2007 11:00:00 9.25 120.95 18.23 2.02 10.00 192.50 13.88 Kiln 2 Scrubber Cl 10/21/2007 11:01:00 8.95 120.00 18.41 1.91 9.76 189.27 14.72 Kiln2Scrubber 

## cl 10/21/2007 11:02:00 8.38 124.50 18.40 1.93 10.84 195.18 14.78 KiIn2Scmbber Cl 10/21/2007 11:03:00 8.67 126.00 18.30 1.99 10.34 195.18 15.32 Kiln2Scrubber Cl 10/21/2007 11:04:00 8.45 122.00 18.43 1.88 10.32 191.34 15.94 Kiln2Scrubber Cl 10/21/2007 11:05:00 8.10 122.05 18.49 1.86 10.53 190.61 17.04 Kiln2Scmbber Cl 10/21/2007 11:06:00 8.30 124.45 18.34 1.96 10.97 197.38 17.16 Kiln 2 Scrubber 

## cl 10/21/2007 11:07:00 8.44 125.55 18.38 1.93 10.15 193.72 17.58 Kiln 2 Scmbber Cl 10/21/2007 11:08:00 8.10 122.50 18.50 1.85 10.20 192.32 19.04 Kiln 2 Scrubber 

## cl 10/21/2007 11:09:00 9.57 122.05 18.43 1.91 10.64 192.44 28.88 Kiln 2 Scrubber Cl 10/21/2007 11:10:00 10.37 124.45 18.37 1.94 10.66 195.98 23.54 KiIn2Scrubber Cl 10/21/2007 11:11:00 9.56 126.55 18.41 1.92 10.46 196.04 29.42 Kiln 2 Scrubber 

## cl 10/21/2007 11:12:00 9.54 124.50 18.38 1.94 10.83 196.28 29.92 Kiln2Saubber Cl 10/21/2007 11:13:00 9.11 125.00 18.44 1.88 10.36 194.88 26.76 Kiln2Scrubber 

## cl 10/21/2007 11:14:00 8.99 121.00 18.52 1.85 7.83 185.55 26.08 Kiln 2 Scrubber Cl 10/21/2007 11:15:00 5.74 101.70 1931 1.38 39.60 111.59 17.70 Kiln 2 Scmbber Cl 10/21/2007 11:16:00 4.11 113.75 19.54 1.28 9.87 141.28 13.52 Kiln 2 Scrubber 

## cl 10/21/2007 11:17:00 7.51 110.20 18.81 1.71 9.19 157.56 19.76 Kiln 2 Scmbber Ci 10/21/2007 11:18:00 9.04 99.70 18.45 1.88 8.56 162.93 22.14 Kiln2Scmbber 

## cl 10/21/2007 11:19:00 9.24 97.20 18.44 1.87 9.09 164.63 22.98 Kiln 2 Scmbber CI 10I21/2007 11:20:00 8.92 97.20 18.50 1.85 9.81 165.43 23.30 Kiln 2 Scrubber 

## cl 10121/2007 11:21:00 9.69 101.75 18.31 1.96 9.75 187.44 25.66 Kiln2Scrubber CI 10/21/2007 11:22:00 9.42 110.20 18.30 1.93 10.39 191.10 24.44 Kiln 2 Scmbber Cl 10/212007 11:23:00 9.26 119.05 18.18 2.03 10.66 196.40 22.62 Ki1n2Scrubber 

## cl 10/21/2007 11:24:00 9.12 120.50 18.22 2.00 10.28 195.73 22.02 Kiln 2 Scmbber Cl 10/21/2007 11:25:00 9.00 122.55 18.26 1.97 10.05 196.59 20.86 Kiln2Scrubber 

## cl 10/21/2007 11:26:00 9.27 119.55 18.22 1.98 10.27 195.98 21.54 Kiln2Scrubber Cl 10/21/2007 11:27:00 8.76 117.55 18.39 1.91 10.63 192.99 21.66 K8n 2 Scmbber Cl 10/21/2007 11:28:00 8.19 123.55 18.40 1.89 10.69 196.89 20.38 Kiln 2 Scrubber Cl 10/21/2007 11:29:00 8.86 124.50 18.25 1.99 10.46 198.96 19.88 Kiln 2 Scmbber Ci 10/21/2007 11:30:00 8.47 120.50 18.42 1.88 10.00 192.87 19.94 Kiln 2 Scrubber 

## cl 10121/2007 11:31:00 7.94 120.50 18.49 1.86 10.50 192.80 19.94 Kiln 2 Scrubber 

## cl 10/21/2007 11:32:00 8.20 121.05 18.39 1.93 10.86 197.44 20.26 Kiln 2 Scmbber CI 10/21/2007 11:33:00 8.29 124.50 18.33 1.93 10.51 198.23 19.16 Kiln2Scrubber 

## cl 10/21/2007 11:34:00 7.84 122.55 18.46 1.86 10.07 194.63 19.52 Kiln 2 Saubber Cl 10/21/2007 11:35:00 8.19 120.50 18.41 1.91 10.50 195.30 19.22 Kiln2Scrubber CI 10/21/2007 11:36:00 8.08 119.50 18.45 1.88 10.43 194.21 18.54 Kiln 2 Scmbber Cl 10/21/2007 11:37:00 7.77 119.55 18.51 1.83 10.23 194.15 17.82 Kiln2Scrubber 

## cl 10/21/2007 11:38:00 8.20 120.05 18.51 1.83 10.28 193.90 18.18 Kiln 2 Scrubber Cl 10/21/2007 11:39:00 8.44 120.45 18.45 1.87 10.42 197.01 18.56 Kiln 2 Scrubber Cl 10/21/2007 11:40:00 8.15 122.00 18.54 1.81 7.64 151.40 17.82
3 

# IC)TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln 2 Scmbber Cl 10/21@007 11:41:00 4.81 102.15 19.45 1.28 17.66 107.20 11.92 Kiln 2 Scrubber Ci 10/2112007 11:42:00 5.03 122.00 19.29 1.42 9.96 183.35 15.16 Kiln2Scmbber G 10/21/2007 11:43:00 8.89 119.95 18.30 1.95 9.82 193.48 20.26 Kiln 2 Scrubber C] 10/21/2007 11:44:00 9.76 115.65 18.03 2.09 9.68 196.28 20.50 Ki1n2Scrubber Cl 10/21/2007 11:45:00 9.81 116.10 18.05 2.07 9.63 196.95 20.44 KiIn2Scrnbber Cl 10/21/2007 11:46:00 10.05 118.05 18.07 2.06 9.49 198.05 20.56 Kiln 2 Scmbber Cl 10/21/2007 11:47:00 9.81 115.65 18.27 1.96 9.39 191.40 21.34 Kiln 2 Scmbber Cl 10/21/2007 11:48:00 9.65 115.15 18.30 L96 9.75 192.87 21.52 Kiln 2 Scmbber Cl 10/21/2007 11:49:00 9.68 118.05 18.33 1.93 9.58 194.33 22.08 Kiln 2 Scrubber Ci 10/21/2007 11:50:00 9.77 120.00 18.30 1.97 9.80 195.24 22.44 Kiln2Scmbber Cl 10121/2007 11:51:00 9.65 121.55 18.30 1.94 9.12 196.83 22.20 Kiln 2 Scrubber C] 10121/2007 11:52:00 9.58 121.50 18.33 1.96 9.40 195.79 21.96 Kiln 2 Scrubber Cl 10/21/2007 11:53:00 9.58 121.00 18.38 1.90 9.25 193.23 22.08

Average 8.69 118.42 18.42 1.89 10.60 186.95 19.54 Kiln 2 Scrubber 10/21/2007 11:54:00 9.66 121.00 18.31 1.94 9.42 196.28 21.84 Kiln 2 Scmbber 10/21/2007 11:55:00 9.26 121.00 18.36 1.93 9.30 195.00 21.72 Kiln 2 Scrubber 10/21/2007 11:56:00 4.66 77.70 4.05 0.52 -0.93 70.55 157.90 Kiln 2 Scmbber 10/21/2007 11:57:00 0.63 1.95 0.12 0.20 -0.95 36.16 194.12 Kiln 2 Scrubber 10/21/2007 11:58:00 0.56 -0.05 -0.02 0.16 -0.96 25.06 49.84 Kiln 2 Scrubber 10/21/2007 11:59:00 0.74 -0.05 -0.02 0.18 -0.95 21.95 41.94 KiIn2Scrubber 10/21/2007 11:59:01 0.71 -0.05 -0.03 0.17 -0.95 21.95 41.88 Kiln 2 Scrubber 

### SSB 10/21/2007 12:00:01 0.60 -0.05 -0.03 0.16 -0.98 20.49 43.01 Kiln 2 Scrubber 10/21/2007 12:01:01 0.39 -0.05 -0.03 0.17 0.68 93.35 42.60 Kiln 2 Scrubber 10/21/2007 12:02:01 0.03 -0.05 0.03 0.18 1.21 217.13 43.34 Kiln 2 Scrubber 10/21/2007 12:03:01 0.23 -0.05 6.86 6.27 -0.99 30.98 26.76 Kiln 2 Scmbber 10/21/2007 12:04:01 0.20 -0.50 9.53 9.35 -0.98 21.71 12.48 Kiln 2 Saubber 10/21/2007 12:05:01 0.20 -0.45 9.95 9.94 -1.00 19.51 7.56 Kiln 2 Sernbber 10/21/2007 12:06:01 0.00 -0.45 10.03 10.07 -0.99 18.11 4.58 Kiln 2 Scrubber 10/21/2007 12:07:01 0.01 -0.50 10.04 10.08 -1.01 17.56 3.30 Kiln 2 Scrubber 10/21/2007 12:08:01 -0.04 -0.50 10.05 10.09 -1.01 16.89 2.70 Kiln 2 Scmbber 10/21/2007 12:0825 0.01 -0.50 10.05 10.10 -1.03 16.77 2.58 Kiln 2 Scrubber 

### SSB 10/21/2007 12:09:25 -0.01 -0.50 10.04 10.10 -1.02 16.46 2.28 Kiln 2 Scmbber 10/21/2007 12:10:25 0.07 -0.45 10.05 10.11 -1.04 15.98 2.64 Kiln 2 Scrubber 10/21/2007 12:11:25 0.18 -0.05 0.34 0.60 -1.03 18.90 198.30 Kiln 2 Scrubber 10/21/2007 12:12:25 19.08 10.50 -0.03 0.23 31.28 159.02 57.74 Kiln2Scrubber 10/21/2007 12:13:25 24.45 23.45 -0.04 0.18 25.00 233.90 9.92 Kiln 2 Sernbber 10/21/2007 12:13:55 24.49 23.45 -0.04 0.17 24.93 238.35 6.04 Kiln 2 Scrubber 

### SSB 10/21/2007 12:14:55 24.55 23.40 -0.05 0.18 24.63 243.11 3.12 Kiln 2 Scrubber

. 10/21/2007 12:15:55 24.58 23.40 -0.06 0.18 14109 244.33 2.52 Kiln 2 Scmbber 10/21/2007 12:16:55 121.75 221.60 -0.04 0.19 143.04 261.16 2.40 Kiln 2 Scrubber 

### SSB 10/21/2007 12:17:40 121.76 246.75 -0.05 0.18 143.02 282.01 2.16 Kiln 2 Scrnbber 10/21/2007 12:18:40 121.76 249.25 -0.05 0.17 143.01 305.30 1.84 Kiln 2 Scrubber 10/21/2007 12:19:40 23.88 247.30 -0.04 0.20 26.90 303.05 2.02 Kiln 2 Scr¢bber 10/21/2007 12:20:40 85.96 197.75 12.08 1.46 7.42 294.94 20.80 Kiln 2 Scrubber 10/21/2007 12:21:40 24.65 129.60 17.12 1.84 7.46 279.02 24.82 Kiln 2 Scmbber 10/21/2007 12:22:40 13.77 122.50 18.04 1.90 7.48 268.23 23.18 Kiln 2 Scrubber 10/21/2007 12:23:40 10.96 123.05 18.19 1.93 7.18 254.21 20.44 Kiln 2 Scrubber 10/21/2007 12:24:40 10.51 121.60 18.24 1.96 7.15 231.77 18.92 Kiln 2 Scmbber 10/21/2007 12:25:40 10.11 121.55 18.33 1.90 7.14 198.23 18.06 Kiln 2 Scrubber 10/21/2007 12:26:40 9.87 121.05 18.32 1.94 7.23 158.90 16.74 Kiln 2 Scrubber 10/21/2007 12:27:40 9.65 121.00 18.29 1.96 7.08 175.98 16.06 Kiln 2 Scrubber 10/21/2007 12:28:40 9.57 121.60 18.35 1.90 7.07 180.00 15.58 Kiln 2 Saubber 10/21/2007 12:29:40 9.41 121.55 18.33 1.95 7.11 180.98 15.28 Kiln 2 Scmbber 10/21/2007 12:30:40 9.37 120.05 18.31 1.93 6.87 178.78 15.02 Kiln 2 Scmbber 10/21/2007 12:31:40 8.28 117.60 18.64 1.74 22.30 90.06 14.18 Kiln 2 Scmbber 10/21/2007 12:32:40 5.13 102.65 19.43 1.31 10.29 112.68 10.34 Kiln 2 Scrubber 10/21/2007 12:33:40 5.91 119.50 19.21 1.46 6.78 163.41 12.24 Kiln 2 Scmbber 10/21/2007 12:34:40 9.47 119.00 18.37 1.94 6.64 170.55 14.66 Kiln 2 Scmbber 10/21/2007 12:35:40 10.65 116.15 18.12 2.06 6.52 173.41 15.04 Kiln 2 Scmbber 10/21/2007 12:36:40 10.41 114.70 18.20 1.99 6.18 166.28 16.18 Kiln 2 Scrubber 10/21/2007 12:37:40 10.11 113.75 18.23 1.99 6.44 163.05 17.34 Kiln 2 Scrubber 10/21/2007 12:38:40 10.33 114.65 18.23 1.99 6.49 166.89 18.68
4 

## iC'TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln 2 Scrubber 10212007 12:39:40 10.36 120.05 18.18 2.01 6.34 167.38 1964

. Kiln 2 Scrubber 1021/2007 12:40:40 10.44 118.50 18.26 1.98 6.40 160.43 20.86 Kiln 2 Scrubber 10212007 12:41:40 10.12 118.05 18.36 1.90 6.40 156.16 21.22 Kiln 2 Scrubber 10/212007 12:42:40 9.91 118.45 18.34 1.94 6.35 157.07 21.40 Kiln 2 Scrubber 10/21/2007 12:43:40 10.35 119.00 18.26 1.96 6.73 160.73 21.22 Kiln 2 Scrubber 10/21 /2007 12:44:40 10.07 123.50 18.32 1.93 6.27 162.93 21.16 Kiln 2 Scrubber 10/21/2007 12:45:40 9.88 121.55 18.34 1.93 6.35 161.40 22.26 Kiln 2 Scrubber 1021/2007 12:46:40 10.15 118.05 18.33 1.91 6.37 160.98 22.62 Kiln 2 Scrubber 10212007 12:47:40 9.46 119.05 18.53 1.86 6.08 160.06 22.68 Kfln 2 Scrubber 10212007 12:48:40 9.46 120.00 18.46 1.86 6.57 162.74 22.26 Kiln 2 Scnrbber 10212007 12:49:40 9.87 123.50 18.33 1.94 6.07 165.37 20.98 Kiln 2 Scrubber 10212007 12:50:40 9.66 122.00 18.48 1.83 6.38 160.00 20.50 Kiln 2 Scrubber 10/21/2007 12:51:40 9.39 120.45 18.47 1.83 5.98 159.21 18.74 Kiln 2 Scrubber 10/21/2007 12:52:40 9.75 118.50 18.49 1.86 6.04 156.83 17.64 Kiln 2 Scrubber 10/21/2007 12:53:40 9.46 122.45 18.48 1.85 5.99 158.90 16.48 Kiln 2 Scrubber 10/21/2007 12:54:40 9.49 124.45 18.42 1.89 5.92 158.48 15.94 Kiln 2 Scrubber 10212007 12:55:40 9.37 119.45 18.46 1.86 5.78 155.06 15.88 Kiln 2 Scrubber 1 021/2007 12:56:40 9.23 118.50 18.55 1.80 5.57 153.23 16.00 Kiln 2 Scrubber 10212007 12:57:40 6.20 107.65 19.13 1.45 23.24 93.66 13.02 Kiln 2 Scrubber 10/212007 12:58:40 4.17 106.15 19.60 1.21 5.65 102.50 9.02 Kiln 2 Scrubber 1021/2007 12:59:40 7.17 113.15 18.97 1.60 4.34 122.38 13.94 Kiln 2 Scrubber 10212007 13:00:40 9.37 99.60 18.42 1.87 4.73 128.05 17.34 Kiln 2 Scrubber 10212007 13:01:40 10.32 95.65 18.35 1.92 4.75 130.12 17.88 Kiln 2 Scrubber 10212007 13:02:40 10.04 94.65 18.43 1.84 4.72 130.24 18.24 Kiln 2 Scmbber 10/21/2007 13:03:40 10.95 97.15 18.26 1.96 4.92 146.34 20.62 Kiln 2 Scrubber 10/21/2007 13:04:40 10.56 106.65 18.25 1.96 5.02 150.00 20.50 Kiln 2 Scrubber 10212007 13:05:02 10.51 109.70 18.27 1.94 5.00 149.76 20.32 Kiln 2 Sombber C2 10212007 13:06:02 10.62 110.65 18.22 1.97 5.17 151.34 19.76 Kiln 2 Scrubber C2 10212007 13:07:02 10.43 113.20 18.24 1.98 5.39 15184 19.70 Kiln 2 Scrubber C2 10/21/2007 13:08:02 10.43 119.00 18.21 1.99 5.30 156.40 19.70 Kiln 2 Scrubber C2 10212007 13:09:02 10.38 115.65 18.18 2.00 5.09 155.00 20.70 Kiln 2 Scmbber C2 10212007 13:10:02 10.15 113.70 18.27 1.95 5.25 153.41 20.74 Kiln 2 Scrubber C2 10212007 13:11:02 9.55 114.70 18.39 1.88 5.12 152.20 21.04 Kiln 2 Scrubber C2 10212007 13:12:02 9.75 115.70 18.25 1.97 5.45 157.50 21.72 Kiln 2 Scrubber C2 10212007 13:13:02 9.70 119.05 18.26 1.96 5.67 159.15 21.28 Kiln 2 Scrubber C2 10212007 13:14:02 9.13 115.70 18.45 1.88 5.41 156.95 21.40 Kilu 2 Scmbber C2 10212007 13:15:02 9.26 115.75 18.36 1.90 5.60 157.44 22.20 Kiln 2 Scrubber C2 10212007 13:16:02 9.33 115.75 18.38 1.90 5.60 156.10 22.44 Kilu 2 Scrubber C2 10121/2007 13:17:02 8.76 116.20 18.48 1.87 5.89 154.15 22.32 Kiln 2 Scmbber C2 10212007 13:18:02 9.36 118.55 18.38 1.92 6.07 157.20 21.40 Kiln 2 Scmbber C2 10/212007 13:19:02 9.04 119.55 18.38 1.91 5.89 158.29 21.60 Kiln 2 Scmbber C2 10212007 13:20:02 9.72 119.55 18.38 1.93 5.79 157.38 22.76 Kiln 2 Scmbber C2 10/212007 13:21:02 8.94 115.75 18.56 1.81 5.78 148.78 22.50 Kiln 2 Scrubber C2 10212007 13:22:02 9.50 116.70 18.38 1.88 5.62 154.57 21.10 K0n 2 Scrubber C2 10/21/2007 13:23:02 8.15 114.20 18.71 1.69 12.22 117.44 18.98 Kiln 2 Scrubber C2 10/212007 13:24:02 4.52 103.70 19.52 1.24 9.90 89.21 12.12 Kiln 2 Scmbber C2 10212007 13:25:02 6.22 120.50 19.15 1.49 5.81 138.54 19.10 Kiln 2 Scrubber C2 10/212007 13:26:02 9.76 114.75 18.21 2.00 5.65 151.83 21.60 Kiln 2 Scrubber C2 10212007 13:27:02 11.00 109.80 18.05 2.10 5.50 152.26 22.26 Kiln 2 Saubber C2 10/212007 13:28:02 10.77 109.30 18.15 2.03 5.32 150.61 22.68 Kiln 2 Scmbber C2 10212007 13:29:02 10.51 110.25 18.19 2.00 5.43 149.57 22.80 Kiln 2 Scrubber C2 10/212007 13:30:02 10.40 111.25 18.21 2.01 5.52 149.15 24.20 Kiln 2 Scmbber C2 10212007 13:31:02 10.62 112.80 18.21 2.01 5.67 151.04 24.76 Kiln 2 Serubber C2 10212007 13:32:02 10.25 112.70 18.27 1.99 6.38 152.13 25.12 Kiln 2 Scrubber C2 10212007 13:33:02 10.38 113.25 18.33 1.95 6.04 151.95 26.20 Kiln 2 Scmbber C2 10212007 13:34:02 10.24 113.25 18.23 2.03 6.02 153.78 27.00 Kiln 2 Scrubber C2 10/2112007 13:35:02 10.50 113.25 18.29 1.99 5.29 152.50 27.18 Kiln 2 Scrubber C2 10212007 13:36:02 9.93 114.75 18.40 1.92 5.84 150.85 27.36 Kilu 2 Scrubber C2 10212007 13:37:02 10.33 114.70 18.32 1.97 6.08 154.15 27.66 Kiln 2 Scmbber C2 10212007 13:38:02 9.93 115.20 18.40 1.93 6.32 153.78 28.58 Kiln 2 Sctubber C2 10/21/2007 13:39:02 9.69 115.70 18.45 1.89 6.16 153.48 28.34 Kiln 2 Scrubber C2 102112007 13:40:02 9.49 115.70 18.39 1.94 6.11 154.76 28.02
5 

## C;TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln 2 Scrubber C2 1021/2007 13:41:02 Kiln 2 Scrubber C2 102112007 13:42:02 Kiln 2 Scmbber C2 10/212007 13:43:02 

### Kiln 2 Scmbber C2 10/212007 13:44:02 Kiln 2 Scrubber C2 10212007 13:45:02 Kiln 2 Scrubber C2 1021/2007 13:46:02 Kiln 2 Scrubber C2 10212007 13:47:02 Kiln 2 Scrubber C2 10212007 13:48:02 Kiln 2 Scmbber C2 10/212007 13:49:02 Kiln 2 Scrubber C2 1021/2007 13:50:02 Kiln 2 Scrubber C2 10212007 13:51:02 Kiln 2 Scrubber C2 10212007 13:52:02 

### Kiln 2 Scrubber C2 10/212007 13:53:02 Kiln 2 Scmbber C2 10212007 13:54:02 Kiln 2 Scrubber C2 10212007 13:55:02 Kiln 2 Scrubber C2 10212007 13:56:02 Kiln2Scrubber C2 ]021/2007 13:57:02 Kiln 2 Scrubber C2 10/212007 13:58:02 Kiln 2 Scrubber C2 10/212007 13:59:02 Kiln 2 Scrubber C2 1021/2007 14:00:02 Kiln 2 Scrubber C2 ] 0212007 14:01:02 Kiln 2 Scrubber C2 10212007 14:02:02 Kiln 2 Scmbber C2 10212007 14:03:02 Kiln 2 Scrubber C2 10212007 14:04:02 Kiln 2 Scrubber C2 10/212007 14:05:02



### Average Kiln 2 Scrubber 10212007 14:06:02 Kiln 2 Scrubber 10/212007 14:07:02 Kiln 2 Scrubber 10212007 14:08:02 Kiln 2 Scmbber 10212007 14:09:02 Kiln 2 Scmbber 10212007 14:10:02 

### Kiln 2 Scrubber 10/21/2007 14:11:02 Kiln 2 Scrubber 10212007 14:12:02 

### Kiln 2 Scmbber SSB 10/21/2007 14:12:18 Kiln 2 Scmbber 10212007 14:13:18 Kiln 2 Scrubber ] 0212007 14:14:18 Kiln 2 Scrubber 10212007 14:15:18 Kiln 2 Scrubber 10212007 14:16:18 Kiln 2 Scrubber 10212007 14:17:18 Kiln 2 Scmbber 10212007 14:17:23 Kiln 2 Scmbber SSB 10212007 14:18:23 Kiln 2 Scrubber 10212007 14:19:23 Kiln 2 Scrubber 10212007 14:20:23 Kiln 2 Scrubber 10212007 14:21:04 

### Kiln 2 Scrubber SSB 1021/2007 14:22:04 Kiln 2 Scrubber 10212007 14:23:04 Kiln 2 Scrubber 10212007 14:24:04 Kiln 2 Scrubber 10212007 14:25:04 Kiln 2 Scrubber 10212007 14:26:04 Kiln 2 Scrubber SSB 10212007 14:26:08 Kiln 2 Scrubber 10212007 14:27:08 Kiln 2 Scmbber 10212007 14:28:08 Kiln 2 Scrubber 10212007 14:29:08 Kiln 2 Scmbber 10212007 14:30:08 Kiln 2 Scrubber ] 0212007 14:31:08 Kiln 2 Scrubber 10212007 14:32:08 Kiln 2 Scrubber 10212007 14:33:08 Kiln 2 Scrubber 10212007 14:34:08 Kiln 2 Scrubber 10212007 14:35:08 Kiln 2 Scmbber 10212007 14:36:08 Kiln 2 Scrubber 10212007 14:37:08 Kilu2Scrubber 1021/2007 14:38:08 10.11 114.70 18.38 1.94 6.49 154.21 28.20 9.33 117.55 18.49 1.86 6.28 152.87 26.28 9.98 115.70 18.45 1.90 6.21 152.44 27.30 9.53 115.70 18.47 1.88 6.87 152.50 25.90 10.09 116.70 18.41 1.91 6.69 153.60 25.00 9.22 116.70 18.50 1.88 6.61 153.23 23.24 10.13 115.75 18.40 1.91 6.82 154.15 23.30 9.99 115.75 18.47 1.86 6.78 153.35 21.96 7.77 100.10 18.99 1.55 31.42 101.83 17.40 4.57 102.65 19.56 1.20 7.29 102.38 11.14 6.97 108.15 19.04 1.57 6.48 125.18 14.60 9.66 97.15 18.45 1.87 6.30 131.95 16.66 10.83 94.05 18.37 1.93 6.26 133.17 17.46 10.34 94.00 18.43 1.86 5.72 132.38 18.26 10.94 98.55 18.18 2.04 6.73 151.65 21.40 10.80 106.60 18.22 1.99 6.89 154.09 20.26 10.51 114.60 18.12 2.07 6.31 160.24 18.12 10.43 114.60 18.15 2.04 6.10 158.90 17.58 10.25 114.20 18.26 1.98 7.02 156.83 17.70 10.27 114.15 18.31 1.95 6.71 155.98 17.04 9.70 115.25 18.33 1.96 7.04 155.61 16.74 9.72 116.25 18.37 1.92 6.90 155.18 16.48 9.75 118.65 18.26 1.99 7.30 160.24 16.42 9.87 119.65 18.25 2.00 6.71 158.90 16.54 9.46 116.80 18.37 1.90 6.55 156.95 15.82 9.62 113.07 18.41 1.90 6.66 149.08 21.45 9.91 116.25 18.38 1.91 6.41 156.71 15.76 1.29 115.30 18.33 1.91 2.36 157.07 16.36 121.77 128.15 7.25 0.78 143.10 149.76 8.72 121.78 242.75 0.25 0.19 143.06 131.59 2.28 121.78 248.40 0.02 0.14 143.04 207.74 1.12 121.78 248.45 0.00 0.17 143.03 228.23 0.62 121.78 249.50 -0.01 0.16 143.03 234.27 0.44 121.78 248.50 -0.01 0.14 143.03 236.83 0.38 121.79 247.50 -0.02 0.16 143.03 234.27 0.26 98.04 166.20 6.02 6.71 -0.37 94.15 0.38 10.07 16.05 9.63 9.83 -0.67 31.22 0.32 1.51 1.60 9.98 10.18 -0.80 23.60 0.32 0.36 0.00 10.02 10.16 -0.86 20.85 0.32 0.34 -0.45 10.02 10.18 -0.85 20.73 0.32 0.23 -0.45 10.02 10.16 -0.92 19.15 0.32 0.29 -0.45 10.03 10.13 17.29 18.23 0.26 23.76 21.50 0.31 0.49 16.98 17.38 -0.02 24.54 23.45 -0.01 0.21 24.73 16.71 -0.02 24.60 23.50 -0.03 0.15 24.25 16.04 -0.08 7.86 12.00 -0.04 0.17 -1.42 17.26 128.68 0.32 0.45 -0.04 0.17 0.40 25.12 198.92 0.38 0.00 -0.05 0.14 -0.07 37.50 60.04 0.19 0.00 -0.05 0.16 -0.04 50.06 43.96 0.21 0.00 -0.05 0.13 -0.07 50.85 43.70 037 -0.05 -0.05 0.15 -0.09 58.96 41.28 0.23 -0.05 -0.06 0.16 1.21 64.88 41.28 -0.07 0.00 -0.04 0.18 1.93 71.46 41.94 -0.23 0.00 -0.03 0.23 1.88 80.12 41.94 -0.17 0.00 -0.02 0.25 1.95 96.16 41.94 -0.18 0.00 -0.01 0.31 1.99 115.79 41.94 -0.21 0.00 0.01 0.38 1.99 121.59 41.94 -0.13 0.00 0.04 0.46 2.01 126.22 41.94 -0.30 0.00 0.07 0.56 2.03 129.15 41.94 -0.25 0.00 0.10 0.61 2.17 125.37 41.88 -0.28 0.00 0.13 0.65 2.13 118.84 41.94 -0.36 0.00 0.15 0.68 2.18 106.52 41.88



### 6 

# ~ 'TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln 2 Scrubber 10212007 14:39:08 -0.12 0.00 0.18 0.70 2.12 97.01 41.88 Kiln 2 Scrubber 10212007 14:40:08 -0.04 0.00 0.20 0.73 2.17 87.32 41.88 Kiln 2 Scrubber 10/212007 14:41:08 -0.13 0.00 0.23 0.76 2.21 81.77 41.88 Kiln 2 Scrubber 10212007 14:42:08 -0.21 0.00 0.26 0.79 2.27 75.98 41.82 Kiln 2 Scmbber 10212007 14:43:08 -0.24 0.00 0.29 0.82 2.28 71.22 41.82 Kilu 2 Scrubber 10/212007 14:44:08 -0.21 0.00 0.33 0.83 2.06 66.83 41.88 Kiln 2 Scrubber 10212007 14:45:08 -0.25 0.00 0.35 0.83 2.13 63.41 41.82 Kilu 2 Scrubber 10212007 14:46:08 -0.27 0.05 0.36 0.86 2.14 60.24 41.76 Kiln 2 Scrubber 10212007 14:47:08 -0.28 0.05 0.38 0.83 2.04 57.80 41.76 Kiln 2 Scrubber 10212007 14:48:08 -0.26 0.05 0.38 0.83 2.08 50.37 41.76 Kiln 2 Scrubber 10212007 14:49:08 -0.16 0.05 0.33 0.70 2.11 47.01 41.76 Kiln 2 Scrubber 10212007 14:50:08 -0.24 0.05 0.26 0.37 2.04 54.88 41.76 Kiln 2 Scrubber 10212007 14:51:08 -0.27 0.05 0.23 0.31 1.96 53.72 41.76 Kiln 2 Scrubber 10/21/2007 14:52:08 -0.29 0.10 0.20 0.27 2.01 43.90 41.76 

### Kiln 2 Scmbber 10/21/2007 14:53:08 -0.20 0.10 0.18 0.26 1.94 43.48 41.70 Kiln 2 Scrubber 10/21/2007 14:54:08 -0.27 0.05 0.18 0.27 2.04 39.57 41.64 Kiln 2 Scrubber 10212007 14:55:08 -0.06 0.10 0.20 0.26 2.02 35.55 41.58 Kiln 2 Scmbber 10212007 14:56:08 -0.01 0.10 0.21 0.26 2.06 32.80 41.52 Kiln 2 Scrubber 10212007 14:57:08 0.10 0.10 0.22 0.25 2.13 30.85 41.52 Kiln 2 Scmbber 10212007 14:58:08 -0.12 0.05 0.23 0.26 2.11 30.24 41.40 Kiln 2 Scrubber 10212007 14:59:08 -0.18 0.05 0.23 0.25 2.10 30.55 41.34 Kiln 2 Scmbber 10212007 15:00:08 -0.01 0.05 0.22 0.26 2.13 30.00 41.28 Kiln 2 Scrubber 1021/2007 15:01:08 0.03 0.05 0.21 0.25 2.06 29.33 41.22 Kiln 2 Scrubber 10212007 15:02:08 -0.14 0.00 0.21 0.25 2.09 28.23 41.10 Kiln 2 Scrubber 10/21/2007 15:03:08 0.00 0.00 0.20 0.26 2.04 26.95 41.04 Kiln 2 Scrubber 10/212007 15:04:08 -0.12 0.05 0.19 0.24 2.09 26.10 40.92 Kiln 2 Scrubber 10/21/2007 15:05:08 -0.11 0.00 0.19 0.25 2.10 24.82 40.72 Kiln 2 Scrubber 10/21/2007 15:06:08 0.21 0.05 0.19 0.24 2.25 24.27 40.48 Kiln 2 Scmbber 1 0212007 15:07:08 -0.32 0.05 0.23 0.22 2.18 23.60 40.12 Kiln 2 Scrubber 10212007 15:08:08 -0.13 0.05 0.36 0.22 2.25 22.80 39.76 Kiln 2 Scmbber 10212007 15:09:08 -0.03 0.00 0.75 0.21 2.32 22.20 39.40 Kiln 2 Scrubber 10/212007 15:10:08 0.07 0.05 1.62 0.22 2.37 21.71 38.96 Kiln 2 Scrubber 10212007 15:11:08 -0.11 0.05 3.10 0.21 2.35 21.52 38.54 Kiln 2 Scrubber 10212007 15:12:08 -0.01 0.05 5.15 0.20 2.46 20.91 38.12 Kiln 2 Scmbber 10212007 15:13:08 -0.03 0.05 7.53 0.19 2.45 20.67 37.70 Kiln 2 Scmbber 10212007 15:14:08 0.20 0.05 9.93 0.20 2.42 20.30 37.20 Kiln 2 Scrubber 10/21/2007 15:15:08 -0.14 0.05 12.12 0.19 2.50 20.06 36.78 Kiln 2 Scrubber 10212007 15:16:08 -0.04 0.05 13.95 0.21 2.55 19.63 36.42 Kiln 2 Scrubber 10/21/2007 15:17:08 -0.05 0.00 15.42 0.18 2.64 19.27 35.98 Kiln 2 Scmbber 10212007 15:18:08 0.04 0.05 16.54 0.21 2.63 19.09 35.50 Kiln 2 Scrubber 10/21/2007 15:19:08 0.10 0.00 17.40 0.19 2.58 18.84 35.08 Kiln 2 Scrubber 1021/2007 15:20:08 0.17 0.00 18.04 010 2.55 18.54 34.66 Kiln 2 Scrubber 10/21/2007 15:21:08 -0.14 0.00 18.51 0.19 2.49 18.05 34.28 Kiln 2 Scrubber 1021/2007 15:22:08 0.10 0.00 18.87 0.18 2.45 18.05 33.92 

### Kiln 2 Scmbber 10212007 15:23:08 -0.1 1 0.00 19.14 0.18 2.45 17.87 33.56 Kiln 2 Scrubber 1021/2007 15:24:08 0.73 0.05 19.20 0.19 2.66 17.62 33.26 Kiln2Scmbber 1021/2007 15:25:08 -0.01 0.50 0.83 0.34 2.50 50.30 36.54 

### Kiln 2 Scrubber 10/21/2007 15:26:08 0.01 0.05 0.85 0.35 2.35 44.88 36.24 Kiln 2 Scrubber 10212007 15:27:08 -0.03 0.50 0.87 0.33 2.40 40.12 36.12 Kiln 2 Scrubber ]0212007 15:28:08 -0.13 0.00 0.90 0.35 2.45 37.38 36.04 Kiln 2 Scrubber 10212007 15:29:08 -0.17 0.00 0.94 0.33 2.37 36.83 35.98 

### Kiln 2 Scmbber 10212007 15:30:08 -0.23 0.00 1.05 0.34 2.32 37.01 35.92 Kiln 2 Scrubber 10212007 15:31:08 -0.25 0.05 1.11 0.37 2.26 37.44 35.86 Kiln 2 Scrubber 10212007 15:32:08 -0.18 0.00 1.25 0.33 17.62 37.68 35.80 Kiln 2 Scrubber 10212007 15:33:08 -0.17 -0.10 1.40 0.35 15.34 37.93 35.74 Kiln 2 Scmbber 10212007 15:34:08 -0.12 -0.05 1.56 0.36 14.66 38.17 35.70 Kiln 2 Scrubber 1021/2007 15:35:08 -1.95 -0.05 1.72 0.35 14.10 38.11 35.56 Kiln 2 Scrubber 10212007 15:36:08 -0.06 -0.10 1.86 0.36 12.60 62.07 35.56 Kiln 2 Scrubber 10212007 15:37:08 1.06 0.40 0.87 0.41 10.54 152.56 29.68 Kiln 2 Scrubber 10212007 15:38:08 9.44 72.65 15.26 1.62 10.44 176.59 26.46 Kiln 2 Scrubber 10212007 15:39:08 10.31 104.65 17.50 1.84 10.40 185.73 26.40 Kiln 2 Scrubber 10/212007 15:40:08 10.47 114.20 18.02 1.90 10.40 189.39 26.40 

### 7



# ~ `TRC

# Data Acquisition Records 154785 Hanson Brick
Kiln 2 Scrubber 10/21/2007 15:41:08 10.39 117.55 18.09 1.94 10.15 188.66 26.34 Kiln 2 Scrubber 10/21/2007 15:42:08 10.62 118.55 18.17 1.89 9.93 185.37 26.46 Kilu 2 Scmbber 10/21/2007 15:43:08 10.25 119.55 18.21 1.91 10.21 182.62 26.52 Kiln 2 Scrubber 10/21/2007 15:44:08 10.45 120.10 18.17 1.94 10.06 182.38 26.34 Kiln2Scrubber 10/21/2007 15:45:08 10.56 120.05 18.20 1.90 10.11 181.34 25.72 Kiln 2 Scrubber 10/21/2007 15:46:08 10.34 118.50 18.29 1.87 10.00 179.39 24.20 Kiln 2 Scrubber 10/21/2007 15:47:08 10.29 115.20 18.34 1.83 10.11 179.88 23.30 Kiln 2 Scmbber 10/21/2007 15:48:08 10.26 119.55 18.27 1.87 10.06 180.06 24.44 Kilu 2 Scrubber 10/21/2007 15:49:08 10.05 121.00 18.29 1.87 9.86 180.49 25.90 Kiln 2 Scrubber 10/21/2007 15:50:08 9.94 121.05 18.23 1.89 9.75 181.65 26.22 Kiln 2 Scrubber 10/21/2007 15:51:08 9.82 118.55 18.27 1.89 9.35 177.44 26.88 Kiln 2 Scmbber 10/21/2007 15:52:08 9.55 115.75 18.35 1.83 9.59 175.98 27.60 Kiln 2 Scrubber 10/21/2007 15:53:08 9.72 117.60 18.30 1.85 9.45 176.28 27.12 Kiln 2 Scrubber 10/21/2007 15:54:08 9.59 118.10 18.33 1.84 9.66 175.98 25.24 Kiln 2 Scrubber 10/2112007 15:55:08 9.12 118.50 18.41 1.79 9.41 173.41 24.14 Kiln 2 Scrubber 10/21/2007 15:56:08 9.33 118.55 18.37 1.84 9.45 172.80 24.32 Kiln 2 Scrubber 10/21/2007 15:57:08 8.95 118.05 18.50 1.74 6.97 143.72 23.30 Kiln 2 Scmbber 1 0/21/2007 15:58:08 4.88 97.70 19.45 1.18 20.07 96.95 12.60 Kiln 2 Scrubber 10/21/2007 15:59:08 4.76 119.05 19.27 1.33 9.44 14154 19.10 Kiln 2 Scmbber 10/21/2007 16:00:08 9.34 117.55 18.21 1.91 8.98 161.28 23.42 Kiln 2 Scrubber 10/21/2007 16:01:08 10.54 113.20 17.92 2.08 9.07 166.52 23.18 Kdn 2 Scrubber C3 10/21/2007 16:02:00 10.83 114.70 17.99 2.03 8.55 167.07 23.00 Kiln 2 Scrubber C3 10/21/2007 16:03:00 10.61 111.75 18.14 1.96 8.41 163.29 23.84 Kiln 2 Scrubber C3 10/21/2007 16:04:00 10.39 111.70 18.19 1.93 8.77 165.18 23.90 Kiln2Scmbber C3 10/21/2007 16:05:00 10.52 118.10 18.12 1.96 8.80 170.18 23.60 Kiln 2 Scmbber C3 10/21/2007 16:06:00 10.91 118.55 18.12 1.96 8.35 169.70 23.42 Kiln 2 Scrubber C3 10/21/2007 16:07:00 10.74 116.70 18.28 1.88 8.44 165.43 25.18 Kiln 2 Scmbber C3 10/21/2007 16:08:00 10.39 116.15 18.24 1.90 9.00 168.78 24.94 Kiln 2 Scrubber C3 10/21/2007 16:09:00 10.45 120.05 18.14 1.95 9.03 170.61 23.78 Kiln 2 Scrubber C3 10/21/2007 16:10:00 10.10 120.05 18.30 1.88 8.36 166.46 24.38 Kiln 2 Scrubber C3 10/21/2007 16:11:00 9.85 116.70 18.31 1.88 8.71 164.88 23.30 Kiln 2 Scrubber C3 10/21/2007 16:12:00 10.79 116.70 18.26 1.92 9.21 166.89 22.08 Kiln 2 Scrubber C3 10/21/2007 16:13:00 10.34 120.50 18.28 1.90 8.83 167.93 21.66 Kiln 2 Scrubber C3 10/21/2007 16:14:00 10.30 118.55 18.31 1.87 8.84 164.45 22.88 Kiln 2 Scmbber C3 10/21/2007 16:15:00 10.54 117.55 18.30 1.87 9.15 165.12 23.30 Kiln 2 Scmbber C3 10/21/2007 16:16:00 9.96 121.00 18.32 1.89 9.21 166.95 22.88 Kiln 2 Scmbber C3 10/21/2007 16:17:00 10.10 120.50 18.32 1.88 8.87 165.73 23.30 Kiln 2 Scrubber C3 10/21/2007 16:18:00 10.03 117.55 18.39 1.82 9.31 163.23 23.84 Kiln 2 Scrubber C3 10/21/2007 16:19:00 10.07 118.50 18.37 1.85 9.82 165.18 24.22 Kiln 2 Scrubber C3 10/21/2007 16:20:00 9.73 121.60 18.36 1.87 9.43 167.07 23.66 Kiln 2 Scrubber C3 10/21/2007 16:21:00 9.88 120.50 18.36 1.86 9.38 164.51 24.26 Kiln 2 Scrubber C3 10/21/2007 16:22:00 9.92 117.55 18.44 1.80 9.54 161.71 24.44 Kiln 2 Scrubber C3 10121/2007 16:23:00 9.21 118.55 18.56 1.72 11.90 131.28 23.96 Kiln 2 Scrubber C3 10/21/2007 16:24:00 5.50 102.70 19.30 1.30 17.82 95.98 15.16 Kiln2Scmbber C3 10/21/2007 16:25:00 4.90 114.70 19.34 1.31 9.59 124.21 17.28 Kilu 2 Scrubber C3 10/21/2007 16:26:00 7.99 105.25 18.67 1.71 9.21 135.73 22.56 Kikt 2 Scrubber C3 10/21/2007 16:27:00 9.57 96.65 18.39 1.86 8.92 142.26 23.84 Kiln 2 Scmbber C3 10/21/2007 16:28:00 9.99 95.20 18.37 1.85 8.89 143.48 24.70 Kiln 2 Scrubber C3 10/21@007 16:29:00 10.09 95.15 18.38 1.85 8.63 154.94 25.12 Kiln 2 Scrubber C3 10/21/2007 16:30:00 10.72 99.15 18.25 1.89 8.75 158.48 27.60 Kiln 2 Scrubber C3 10/21/2007 16:31:00 10.24 108.15 18.28 1.89 8.75 161.83 25.72 Kiln 2 Scrubber C3 10/21/2007 16:32:00 10.47 112.70 18.22 1.94 8.78 162.56 24.94 Kiln 2 Scrubber C3 10/21/2007 16:33:00 11.13 112.20 18.26 1.93 8.97 161.10 24.02 Kiln 2 Scrubber C3 10121/2007 16:34:00 11.39 116.20 18.21 1.94 9.32 164.33 23.78 Kiln 2 Scrubber C3 10/21/2007 16:35:00 10.84 119.10 18.16 1.99 8.83 165.79 23.96 Kiln 2 Scrubber C3 10/21/2007 16:36:00 11.77 115.25 18.25 1.92 8.80 161.40 24.52 Kiln 2 Scmbber C3 10/21/2007 16:37:00 10.55 115.70 18.34 1.89 8.97 160.49 24.82 Kilu2Scrubber C3 10/21/2007 16:38:00 10.16 119.05 18.23 1.97 9.24 167.07 23.66 Kiln 2 Scrubber C3 10/21/2007 16:39:00 11.06 118.10 18.20 1.94 9.02 164.82 2184 Kiln 2 Scmbber C3 10/21/2007 16:40:00 10.28 116.70 18.36 1.86 9.48 162.07 23.72 Kiln 2 Scrubber C3 10/21/2007 16:41:00 10.22 116.15 18.35 1.89 9.62 162.56 24.44 Kiln 2 Scrubber C3 10/21/2007 16:42:00 10.18 115.75 18.33 1.88 9.51 160.67 24.44
8 

## C,TRC

# Data Acquisition Records 154785 

# Hanson Brick
Kiln 2 Scmbber C3 10/21/2007 16:43:00 Kiln 2 Scmbber C3 10/21/2007 16:44:00 Kiln 2 Scrubber C3 10/21/2007 16:45:00 Kiln 2 Scrubber C3 10/21/2007 16:46:00 KBn 2 Scrubber C3 10/21/2007 16:47:00 Kiln 2 Scrubber C3 10/21/2007 16:48:00 Kiln 2 Scrubber C3 10/21/2007 16:49:00 Kiln 2 Scrubber C3 10/21/2007 16:50:00 Kiln 2 Scrubber C3 10/21/1007 16:51:00 Kiln 2 Scrubber C3 10/21/2007 16:52:00 Kiln 2 Scmbber C3 10/21/2007 16:53:00 Kiln 2 Scrubber C3 10/21/2007 16:54:00 Kiln 2 Scrubber C3 10/21/2007 16:55:00 Kiln 2 Scrubber C3 10/21 /2007 16:56:00 Kiln 2 Scrubber C3 10/21/2007 16:57:00 Kiln 2 Scrubber C3 10/21/2007 16:58:00 Kiln 2 Scrubber C3 10/21/2007 16:59:00 Kiln 2 Scrubber C3 10/21/2007 17:00:00 Kiln 2 Serubber C3 10/21/2007 17:01:00 Kiln 2 Scrubber C3 10/21/2007 17:02:00

Average Kiln 2 Scrubber 10/21/2007 17:03:00 Kiln 2 Scrubber 10/21/2007 17:04:00 Kiln 2 Scrubber 10/21/2007 17:05:00 Kiln 2 Scrubber 10/21/2007 17:06:00 Kiln 2 Scrubber SSB 10/21/2007 17:06:31 Kiln2Scrubber 10/21/2007 17:07:31 Kiln 2 Scmbber 10/21/2007 17:08:31 Kiln 2 Scrubber 10/21/2007 17:09:24 Kiln 2 Scrubber SSB 10/21/2007 17:10:24 Kiln 2 Scrubber 10/21/2007 17:11:24 Kiln 2 Scrubber 10/21/2007 17:12:24 Kiln 2 Scrubber SSB 10/21/2007 17:12:28 Kiln 2 Scrubber 10/21/2007 17:13:28 Kiln 2 Scrubber 10/2112007 17:14:28 Kiln 2 Scrubber 10/21/2007 17:15:28 Kiln 2 Scrubber 10/21/2007 17:16:28 Kiln 2 Scrubber 10/21/2007 17:16:44 Kiln 2 Scrubber SSB 10/21/2007 17:17:44 Kiln 2 Scrubber 10/21/2007 17:18:44 Kiln 2 Scrubber 10/21/2007 17:19:44 Kilu 2 Scrubber 10/21/2007 17:20:44 Kiln 2 Scrubber 10/21/2007 17:21:44 Kiln2Scrubber 10/21/2007 17:22:44 Kiln 2 Scrubber 10/21/2007 17:23:44 Kiln 2 Scrubber 10/21/2007 17:24:44 Kiln 2 Scrubber 10/21l2007 17:25:44 9.72 117.60 18.42 1.83 9.34 160.55 24.08 9.81 120.10 18.35 1.88 9.57 164.94 23.30 10.06 121.60 18.33 1.90 9.32 163.78 23.36 9.44 119.10 18.54 1.78 9.13 159.51 23.90 9.30 119.10 18.57 1.77 9.26 157.68 24.52 9.57 119.60 18.59 1.73 9.22 155.43 25.00 7.71 112.20 19.00 1.49 35.23 110.49 22.14 4.58 103.75 19.59 1.18 10.39 102.20 15.04 6.34 119.55 19.14 1.46 8.47 140.91 23.96 10.09 114.70 18.41 1.84 8.21 150.85 25.48 11.58 113.70 18.26 1.94 7.92 152.99 25.00 11.09 114.70 18.29 1.90 7.94 152.93 24.44 11.51 116.15 18.33 1.91 8.13 153.84 24.08 11.80 116.15 18.26 1.92 8.34 153.78 24.20 11.89 117.55 18.37 1.87 8.33 15156 24.26 10.81 119.05 18.40 1.86 8.58 154.21 23.72 11.08 118.05 18.36 1.89 8.85 154.63 24.02 10.58 123.00 18.36 1.90 8.82 158.11 24.02 10.47 122.50 18.36 1.89 8.75 156.28 25.18 11.15 119.55 18.34 1.91 8.49 155.30 25.60 10.02 115.33 18.40 1.84 9.56 156.43 23.66 6.71 120.05 18.43 1.84 3.48 153.41 26.10 121.79 165.05 5.31 0.55 -0.82 179.51 9.14 121.80 243.25 0.35 0.23 -0.96 224.51 2.52 121.80 247.90 0.04 0.18 -1.01 237.20 1.06 121.80 247.85 0.02 0.17 -1.04 242.74 0.68 121.80 248.85 0.00 0.18 -0.18 238.60 0.32 60.33 98.15 -0.01 0.18 -0.18 124.21 20.98 3.78 2.90 -0.02 0.17 -0.21 43.96 32.58 0.78 -0.10 -0.03 0.18 -0.21 28.05 43.16 18.25 16.45 -0.03 0.20 -0.21 22.80 12.66 24.43 23.40 -0.03 0.18 25.22 20.67 2.82 24.78 23.40 -0.03 0.19 24.64 20.37 2.56 24.61 23.45 -0.04 0.17 24.15 18.84 1.00 12.40 15.50 5.52 6.10 0.73 17.68 0.94 1.75 1.50 9.38 9.38 0.72 16.83 0.88 0.10 -0.05 9.92 9.93 0.72 16.04 0.76 0.11 -0.50 9.96 9.97 0.71 15.91 0.68 0.04 -0.45 10.01 10.04 0.71 15.37 0.50 0.07 -0.50 10.01 10.03 0.72 14.63 0.38 0.01 -0.40 10.03 10.06 0.71 14.39 0.32 -0.03 -0.50 10.03 10.04 0.74 15.85 0.20 0.09 -0.50 9.99 9.96 2.20 19.21 0.38 -0.28 -0.50 10.00 9.89 2.09 20.91 0.44 -0.13 -0.50 9.99 9.92 2.17 21.40 0.38 -0.19 -0.50 10.00 9.90 2.11 22.50 0.44 -0.25 -0.50 10.01 9.85 2.03 23.23 0.46



### 9 

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### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 11:16:09 Description: Kiln 2 Scrubber Data file: 102107_18.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Methane 0.983 14.5534 67.3666 Ethane 1.031 3.4276 15.8659 Propane 1.185 0.4842 2.2413 18.4651 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 11:34:45 Description: Kiln 2 Scrubber Data file: 102107_20.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785f Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Methane 0.984 13.2982 64.3967 Ethane 1.032 3.4019 16.4738 Propane 1.185 0.5480 2.6537 17.2481 100.0000

### Lab name: TRC

Client: Hanson Brick ClientlD: 154785 Analysis date: 10/21/2007 11:49:07 CI- 

## ~ ~ Description: Kiln 2 Scrubber Data file: 102107_24.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

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Component Retention Area Area % Methane 0.975 11.0813 55.8525 Ethane 1.025 3.9014 19.6640 Propane 1.174 0.5718 2.8823 15.5546 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 11:54:52 Description: Kiln 2 Scrubber Data file: 102107_25.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785t Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

## %
Methane 0.974 10.4674 47.5192 Ethane 1.023 3.7628 17.0821 Propane 1.175 0.6272 2.8473
14.8574 100.0000 

## ` \

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10121/2007 13:05:26 Description: Kiln 2 Scrubber Data file: 102107_26.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Methane 0.970 8.1921 47.3857 / -A Methane 1.001 0.4076 2.3577 Ethane 1.018 3.0056 17.3851 Propane 1.171 0.5132 2.9682 

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### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 13:25:44 Description: Kiln 2 Scrubber Data file: 102107_28.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Methane 0.965 12.6903 69.1766 Ethane 1.013 3.0400 16.5717 Propane 1.159 0.6043 3.2941 16.3347 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10121/2007 13:47:57 Description: Kiln 2 Scrubber Data file: 102107_30.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Methane 0.964 8.7411 68.2726 Ethane 1.013 2.2174 17.3191 Propane 1.160 0.5222 4.0783 Propane 1.223 1.1092 8.6636
12.5899 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 13:59:35 Description: Kiln 2 Scrubber Data file: 102107_31.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

:`

Component Retention Area Area 

### % Methane 0.960 13.0506 62.9219 Methane 1.008 3.1638 15.2539 Propane 1.158 0.6168 2.9736 Propane 1.217 1.3539 6.5277 18.1850 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 14:06:31 Description: Kiln 2 Scrubber Data file: 102107_32.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Methane 0.963 10.3433 62.7841 Ethane 1.012 2.3570 14.3068 Propane 1.162 0.6515 3.9545 Propane 1.225 1.2414 7.5351 

# JF

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 16:10:32 Description: Kiln 2 Scrubber Data file: 102107_34.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area % Methane 0.958 12.6175 70.8261 Ethane 1.005 3.1244 17.5384 tey' Propane 1.145 0.4723 2.6515 Propane 1.199 1.0860 6.0958 1.377 0.5145 2.8882

17.8148 100.0000 

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### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/2112007 16:17:50 Description: Kiln 2 Scrubber Data file: 102107_35.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

;'

Component Retention Area Area % Methane 0.957 13.0801 73.3341 Methane 1.006 3.0219 16.9427 Propane 1.145 0.5492 3.0788 Propane 1.202 1.1851 6.6444 17.8363 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10/21/2007 16:26:06 Description: Kiln 2 Scrubber Data file: 102107_36.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\154785f Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

;'

Component Retention Area Area 

### % Methane 0.957 12.0719 69.0776 Methane 1.005 2.9749 17.0230 Propane 1.146 0.4503 2.5767 Propane 1.200 1.1891 6.8044 16.6862 100.0000

### Lab name: TRC

Client: Hanson Brick Client ID: 154785 Analysis date: 10121/2007 16:44:18 Description: Kiln 2 Scrubber Data file: 102107_38.CHR (C:\Documents and Settings\Data Logger\My Documents\PeakSimpleData\1547851 Comments: Location: Elgin, Texas

Source: Lime Kiln Scrubber Technicians: JSG

Component Retention Area Area 

### % Methane 0.955 13.3000 68.6607 Ethane 1.005 3.1692 16.3612 Propane 1.145 0.5718 2.9522 Propane 1.198 1.4388 7.4278 18.4799 100.0000

# Method 26A Data

Fluoride Data Company Name Hanson Bnck Source Kiln #2 Scrubber

Facillty Elgin, Tems Job No. 154785 Sampling Date 10/2112007 Technicians JSG Calibra0on Curves Va US EPA Method 26 Sec[ion 5.2 Inidal Curve Scale=0 - 100 IC Calibration Curve: Fluoritle Date Time I Area 1 Anz 2 Precision % Mean Area Calc /mL 10121/2007 08:31 1.0057 1.0524 2.27 1 6 10/21/2007 0902 2.1385 2.1254 0.31 2 

# T
12 10/21/2007 09:36 4.3161 4.3194 0.04 4 25 10/21/2007 10:08 8.7842 8.8773 0.53 9 51 10/21/2007 11:44 17.3019 17.4534 0.44 17 100 Line Correlation: 0.99993913

120 100 y=5.726E+00x+1.702EE 80 

## a 3 60 

## o 40 U 20 0 0 2 4 6 8 1 ➢ 12 14 16 t8 20 Area (comka)

ExoerimnMalOafae Flnnrida Date Time RUN Area1 1 Area2 1 Pmcision % MeanArea I Conc Imh 10/21/2007 12:13 Blank 0.0082 0.0076 3.75 0.0079 0.05 N/A 10/21/2007 12:46 C-i lnlet 8.3601 8.2488 0.67 83045 4763 1 10/21/2007 15:29 C-2lnlet 10.8779 10.7806 0.45 10.8293 62.12 1 10/22/2007 15:04 C-3lnlet 8.3396 8.4931 0.91 8.4164 48.27 I Diluti 

# 7

0.18

2 10/21/2007 13:15 C-1 Outlet 0.0545 0.0502 4.10 0.0524 0.26 1 10/21/2007 15:59 C-20u8et 0.0265 0.0278 2.39 0.0272 0.11 1 10/21/2007 17:48 C-30u0et 0.0386 0.0402 2.03 0.0394 0.18 1



# C' TRC

# Method 26A Data

Chloride Data Company Name Hanson Brick Source Kiln #2 Scrubber

Facility Elgin, Texas Job No. 154785 Sampling Date 10/21/2007 Technicians JSG
Calibration Curves Via US EPA Method 26 Seetion 5.2 Initial Curve Scale=0 - 100 IC Calibration Curve: Chloritle Date Time Area 1 Area 2 Precision (%I Mean Area I Conc /mL Calc /mL 10121/2007 0831 1.6369 1.6718 1.05 2 6.25 6 10 1 21/2007 0902 2.7004 2.6914 0.17 3 12.5 14 10/21/2007 09:36 4.176 4.1714 0.06 4 25 24 10/2112007 10:08 7.6027 7.465 0.91 8 50 49 10/21/2007 11:44 14.6233 14.8332 0.71 15 100 101 Line Correlation: 0.999653387

120 100 y= 7.216E+00x - 5.681 E+ E 80 = 60 o` 40

~ 20 0 0 2 4 6 8 10 12 14 16 Area (counts)

Exnerimental Data: Chloritle Date Time RUN Area 1 1 Area 2 Precision % Mean Area Conc /ml Dilution Conc /ml 10121/2007 12:13 Blank 0.0410 0.0451 4.75 0.0431 0.29 N/A 0.29 10/21/2007 12:46 C-1lnlet 4.3533 4.2994 0.62 4.3264 28.42 1 28.42 10/21/2007 15:29 C-2lnlet 7.0171 6.8640 1.10 6.9406 45.77 1 45.77 10/22/2007 15:04 C-3lnlet 9.9334 10.4694 2.63 10.2014 67.40 2 134.81 10/21/2007 13:15 C-1 Outlet 0.1367 0.1489 4.27 0.1428 0.66 1 0.66 10121/2007 15:59 C-20utlet 0.0935 0.0973 1.99 0.0954 0.35 1 0.35 10/21/2007 17:48 C-30utlet 0.2941 0.2927 0.24 0.2934 1.66 1 1.66



# TRC

### lon Chromatograph Analysis

Sample Name: Blank Client: Hanson8rick 

### Control Program: Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording 

### Time: 10/2112007 12:13 Location: Elgin, Texas

100 153826Hanson #38 modified by TRC-Cubix Em lo ee ECD 1 NS 3-40.9 1297
88

7

63

5

38

25

13

1 

## - Floride 

## - 2 1 aloride 

## - 4.587

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min 

### Peak Name Height PS 

### Area

S'min Rel.Area



## % 1 3.17 Floride 0.045 0.0082 0.01 2 4.59 Chloride 0.181 0.0410 0.07 3 10.94 n.a. 65.186 3.8633 6.51 4 11.30 n.a. 135.297 55.4690 93.41 Total: 

### 200.708 59.3816 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: Blank Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10121/2007 12:28 Location: Elgin, Texas

153826Hanson #39 modified by TRC-Cubix Em lo ee ECD 1 100 

### u S 4-90.8 0163

8

75

63

5

38

25

13

1- Floride 

### - loride 

### - 4.507 3- 9,44

min -1 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0



### No. Ret.Time

min 

### Peak Name Height PS Area

S*min Rel.Area

% 1 3.15 Floride 0.035 0.0076 0.01 2 4.51 Chloride 0.189 0.0451 0.07 3 9.44 n.a. 0.000 0.0002 0.00 4 10.80 n.a. 65.436 4.0984 6.81 5 11.16 n.a. 135.579 56.0613 93.11 Total: 201.239 60.2127 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: C-1 Inlet Client Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 1012112007 12:46 Location: Elgin, Texas

153826Hanson #40 C-1 Inlet ECD 1 100 

### u S 6-710. 010

88

7

6

5

38

2 1 

## - Floride 

## - 3.027

13 2 

## - Chloride 

## - 4.243
5 10.173 3-5.457 4-7.097

_1 min ' 0.0 2.0 4.0 610 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height IJS 

### Area

S*min Rel.Area



## % 1 3.03 Floride 23.923 8.3601 12.85 2 4.24 Chloride 10.720 4.3533 6.69 3 5.46 n.a. 0.584 0.6674 1.03 4 7.10 n.a. 0.023 0.0063 0.01 5 10.17 n.a. 1.089 0.2549 0.39 6 10.79 n.a. 60.445 4.3087 6.62 7 11.11 n.a. 122.333 47.1091 72.41 Total: 

# F 219.118 65.0598 100.00

Testing Performed by TRC

### lon Chromatograph Analysis



### Sample Name: 

### C-1 Inlet 

### Client: Hanson8rick 

### Control Program: Hanson Source: Multiple 

### Quantif. Method: Hanson Project #: 154785 Recordfng 

### Time: 1012112007 13:00 Location: Elgin, Texas

153826Hanson #41 C-1 Inlet ECD 1 100 N S 6 -710. 070
88

7

63

5

3

25 1 

### - Floride 

### - 2.990

13 2 

### - Chloride 

### - 4.210
5 10.133 3-5.407 4-7.043

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time



### min Peak Name Height PS Area

S*min Rel.Area



### % 1 2.99 Floride 24.464 8.2488 13.05 2 4.21 Chloride 10.529 4.2994 6.80 3 5.41 n.a. 0.543 0.6252 0.99 4 7.04 n.a. 0.022 0.0061 0.01 5 10.13 n.a. 1.042 0.2459 0.39 6 10.76 n.a. 57.467 4.2381 6.71 7 11.07 n.a. 119.568 45.5378 72.05 Total: 

# 1 213.636 63.2014 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: C-1 Outlet CIlent: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 1012112007 13:15 Location: Elgin, Texas

53826Hanson #42 modifed by TRC-Cubix Em lo ee ECD 1 100 N S 461018 0
8

7

63

5

38

25

13

1- Floride -J

. 0,Qh1onde 

### - 4.503

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min 

### Peak Name Height 

### PS Area

S'min Rel.Area



### % 1 3.05 Floride 0.138 0.0545 0.01 2 4.50 Chloride 0.300 0.1367 0.03 3 9.08 n.a. 0.000 0.0000 0.00 4 10.80 n.a. 510.245 76.2795 18.59 5 11.04 n.a. 509.664 333.8208 81.36 Total: 

# F 1020.346 410.2915 100.00

Testing Performed by TRC

### Ion Chromatograph Analysis

Sample Name: 

### C-1 Outlet Client: Hanson8rick Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10121/2007 13:32 Location: Elgin, Texas

153826Hanson #43 modified by TRC-Cubix Em lo ee ECD 1 6N 

### Ns

4 10 1$.` , i3$7 

### 50

40

30 , 1



### 20

10

1 - Flodd - 2.0Q

~ loride - 4.460

min 10 0.0 2.0 4.0 6.0 8.0 1 0.0 12.0 14.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Rel.Area

% 1 3.04 Floride 0.118 0.0502 0.01 2 4.46 Chloride 0.342 0.1489 0.04 3 10.85 n.a. 510.003 375.7880 91.50 4 11.09 n.a. 99.866 34.7141 8.45 Total: 610.328 410.7012 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: DiH2O Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10121t2007 13:53 Location: Elgin, Texas

153826Hanson #44 modifed by TRC-Cubix Em lo ee ECD 1 0.6 

### NS 1 - 11.380 

### 0.5

0.4

0.3

0.2

0.1

0.0



### -0.1

-0.2

-0.3

min 

### -0.4 0.0 2.0 4.0 6.0 8.0 

### 1 0.0 12.0 

### 14. 0 ~~.


### No. Ret.Time Peak Name Height

min IJS Area S*min Rel.Area

% 1 11.38 n.a. 0.551 0.2869 100.00 Total: 0.551 0.2869 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: DIH2O 

### Client' Hanson8rick Control Program: Hanson 

### Source: Multiple Quantif. Method: Hanson 

### Project #: 154785 Recording Time: 1012112007 14:08 

### Location: Elgin, Texas

153826Hanson ri45 modified by TRC-Cubix Em lo eel ECD 1 0.300 NS

0.20 1 

### - 11.370

0.10

0.00 —"

-0.10

-0.20

-0.30

min -0.40 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time Peak Name Height

min PS Area S'min Re1.Area



### % 1 11.37 n.a. 0.185 0.0975 100.00 Total: 

### 0.185 0.0975 100.00

Testing 

## Performed by TRC

### lon Chromatograph Analysis



## Sample Name: C-2 Inlet 

## Client: HansonBrick Control Program: Hanson Source: Multiple 

## Quantif. Method: Hanson Project #: 154785 

## Recording Time: 10/21/2007 15:29 Location: Elgin, Texas

153826Hanson i146 modified by TRC-Cubix Em lo ee ECD 1 

### ~ 100 N S 4-10.7 0 '


### 88

7

63

5

38 1 - Floride - 2.913 2 2 - Chloride - 4.337 1

3 - 5.330

1 min 

### 0.0 2.0 4.0 6.0 8.0 

### 10.0 12.0 1 4.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Re1.Area

% 1 2.91 Floride 30.714 10.8779 2.40 2 4.34 Chloride 16.418 7.0171 1.55 3 5.33 n.a. 0.796 0.7559 0.17 4 10.76 n.a. 509.594 434.5007 95.88 Total: 557.522 453.1516 100.00

Testing Performed by TRC

### lon Chromatograph Analysis



### Sample Name: C-2 Inlet 

### Client Hanson8rick Control Program: Hanson Source: Multiple 

### Quantif. Method: Hanson Project #: 154785 

### Recording Time: 1012112007 

### 15:44 Location: Elgin, Texas

153826Hanson#47 C-2lnlet ECD 1 10 N S 6 

### - 10 950

88

7

6

5

38 1 

### - Floride 

### - 2.937
2 2 

### - Chlodde -4.327 1

3 

### - 5. 9f- .137 6.850

1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Rel.Area

% 1 2.94 Floride 31.328 10.7806 2.35 2 4.33 Chloride 17.019 6.8640 1.50 3 5.30 n.a. 0.607 0.5151 0.11 4 6.14 n.a. 0.022 0.0047 0.00 5 6.85 n.a. 0.019 0.0050 0.00 6 10.95 n.a. 509.507 440.2927 96.04 Total: 558.503 458.4622 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: 

### C-2 Outlet Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording 

### Time: 10/21/2007 15:59 Location: Elgin, Texas

100 53826Hanson #48 modified by TRC-Cubix Em lo ee ECD 1 NS 5 - 10 927 88

7

63

5

38

25 il 13
1- Florid -:0bloride - 4.3 7 3- 6.817 4 9. ------- ___.___ 1 min 0.0 2.0 410 6.0 8.0 10.0 12.0 14.0
No. Ret.Time Peak Name Height Area Rel.Area

min PS S'min % 1 3.00 Floride 0.074 0.0265 0.01 2 4.34 Chloride 0.314 0.0935 0.02 3 6.82 n.a. 0.229 0.0510 0.01 4 9.24 n.a. 0.000 0.0005 0.00 5 10.93 n.a. 509.474 422.0610 99.96 Total: 510.091 422.2325 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: C-2 Outlet Client: Hanson8rick 

### Control Program: 

### Hanson Source: Multiple Quantif. Method: 

### Hanson Project #: 154785 Recording Time: 

### 10121t2007 16:13 Location: Elgin, Texas

53826Hanson #49 modified by TRC-Cubix Em lo ee ECD 1 100 N S 3 - 10 887
88

75

63 I i

5 i i

38

25

13

1 - Florid - bloride - 4.333

_ 1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time Peak 

### Name Height Area Rel.Area

min 

### PS S'min % 

### 1 2.98 Floride 0.064 0.0278 0.01 2 4.33 Chloride 0.324 0.0973 0.02 3 10.89 n.a. 509.459 419.5222 99.97 Total: 509.847 419.6473 100.00

Testing PerPormed by TRC

### lon Chromatograph Analysis

Sample Name: C-3 Outlet Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10/21/2007 17:48 Location: Elgin, Texas

153826Hanson #52 rmodified by TRC-Cubix Em lo ee ECD 1 10 PS 3 - 10 837


### 88

7

63

5

38

25

13

1- Flor de - B

~ Ehloride - 4.280

1 min 

### 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time Peak Name

min Height PS Area

S`min Re1.Area

% 1 2.86 Floride 0.108 0.0386 0.01 2 4.28 Chloride 0.646 0.2941 0.07 3 10.84 n.a. 484.550 427.3754 99.92 Total: 485.304 427.7082 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: C-3 Outlet Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10/21/2007 18:03 Location: Elgin, Texas

53826Hanson #53 modifed by TRC-Cubix Em lo ee ECD 1 100 N S 4 - 10. 27


### 88

75

63

5

38

25

13

1- Flo id~ ~pfslrtide - 4.31,7 3- 6. 873
._.__._. —~. . _ .......—.........—
1 min 

### 0. 0 

### 2.0 4.0 6.0 8.0 10.0 12.0 14.0


### No. Ret.Time

min Peak Name Height PS Area

S*min Rel.Area

% 1 3.26 Floride 0.037 0.0165 0.00 2 4.32 Chloride 0.617 0.2927 0.07 3 6.87 n.a. 0.202 0.0451 0.01 4 10.83 n.a. 486.395 425.7016 99.92 Total: 487.252 426.0558 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: C-3 Inlet 2:1 Client: HansonBrick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 1012212007 

### 15:04 Location: Elgin, Texas



### 100 1538261-lanson #55 C-3 Inlet 2:1 ECD 1 NS 6 -71U 000 8

7

6

5

38 2 - Chloride - 4.450 '. 1 - Floride - .960 2

13
3 - 5.4 04 - 307.023 ' i --. 1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0

No. Ret.Time Peak Name Height Area Rel.Area

min PS 

### S`min % 1 2.96 Floride 28.056 8.3396 1.87 2 4.45 Chloride 31.846 9.9334 2.23 3 5.48 n.a. 0.445 0.3807 0.09 4 6.51 n.a. 0.026 0.0069 0.00 5 7.02 n.a. 0.134 0.1278 0.03 6 10.72 n.a. 510.495 83.5606 18.74 7 11.00 n.a. 509.976 343.4542 77.04 Tota1: 1080.979 445.8033 100.00

Testing Performed by TRC

### lon Chromatograph Analysis

Sample Name: C-3 

### Inlet 2:1 

### Client: Hanson8rick Control Program: Hanson Source: Multiple Quantif. Method: Hanson Project #: 154785 Recording Time: 10122/2007 15:19 Location: Elgin, Texas

100 153826Hanson #56 C-3 Inlet 2:1 ECD 1 us 5 -610. 087 88 i
7 i

63

5

38 2 - Chloride - 4.423 1 - Floride - .947 2

13
3-6. 9b-7.270
-1 min 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
No. Ret.Time Peak Name Height 

### Area Rel.Area

min 

### PS S'min 

### % 1 2.95 Floride 27.863 8.4931 1.87 2 4.42 Chloride 32.056 10.4694 2.31 3 6.39 n.a. 0.222 0.2361 0.05 4 7.27 n.a. 0.017 0.0046 0.00 5 10.68 n.a. 510.501 79.9926 17.65 6 10.99 n.a. 509.786 353.9736 78.11 Total: 1080.444 453.1694 100.00

Testing PerFormed by TRC

# APPENDIX F: PROCESS DATA

# Process Data

DateTime Kiln Comb Air Kiln_Gas_ Kiln_OverPre Kiln_Press Kiln_Push_Car Kiln_Pusher Kiln_Pushing Brick



### Press Top

~ 

### Press ssure_Fan_Sp s_per_Day Pushes_Today Production eed_Out (tons/lu') 10/21/20077:00 11.74 42 2600 -0.17 28 19 0 10.56 

### 10/21/2007 7:01 12.05 42 2600 -0.17 28 19 0 10.56 10/21/2007 7:02 12.02 42 2600 -0.18 28 19 0 10.56 10/21/2007 7:03 11.99 42 2600 -0.16 28 19 0 10.56 10/21/2007 7:04 11.93 42 2600 -0.17 28 19 0 10.56 10/21/2007 7:05 11.82 42 2600 -0.13 28 19 0 10.56 

### 10/21/2007 7:06 11.88 42 2600 -0.15 28 19 0 10.56 10/21/20077:07 11.87 42 2600 -0.19 28 19 0 10.56 10/21/20077:08 11.79 42 2600 -0.15 28 19 0 10.56 10/21/2007 7:09 11.61 42 2600 -0.18 28 19 0 10.56 10/21/2007 7:10 30.83 42 1200 -0.06 28 19 1 10.56 10/21/20077:11 29.36 42 1200 -0.07 28 20 0 10.56 

### 10/21/2007 7:12 11.21 42 2600 -0.14 28 20 0 10.56 10/21/2007 7:13 11.85 42 2600 -0.17 28 20 0 10.56 10/21/2007 7:14 11.67 42 2600 -0.18 28 20 0 10.56 10/21/2007 7:15 11.8 42 2600 -0.16 28 20 0 10.56 10/21/2007 7:16 11.73 42 2600 -0.17 28 20 0 10.56 

### 10/21/2007 7:17 11.72 42 2600 -0.17 28 20 0 10.56 10/21/2007 7:18 13.65 42 2600 -0.2 28 20 0 10.56 10/21/20077:19 13.31 42 2600 -0.13 28 20 0 10.56 10/21/20077:20 12.54 42 2600 -0.17 28 20 0 10.56 10/21/20077:21 12.29 42 2600 -0.18 28 20 0 10.56 

### 10/21/2007 7:22 12.09 42 2600 -0.16 28 20 0 10.56 10/21/20077:23 12.12 42 2600 -0.16 28 20 0 10.56 10/21/20077:24 12.08 42 2600 -0.16 28 20 0 10.56 10/21/2007 7:25 12.11 42 2600 -0.17 28 20 0 10.56 10/21/2007 7:26 12.22 42 2600 -0.15 28 20 0 10.56 10/21/2007 7:27 12.16 42 2600 -0.19 28 20 0 10.56 

### 10/21/2007 7:28 12.35 42 2600 -0.18 28 20 0 10.56 10/21/2007 7:29 12.44 42 2600 -0.16 28 20 0 10.56 10/21/2007 7:30 12.45 42 2600 -0.17 28 20 0 10.56 10/21/20077:31 12.41 42 2600 -0.16 28 20 0 10.56 

### 10/21/2007 7:32 12.58 42 2600 -0.18 28 20 0 10.56 10/21/2007 7:33 12.38 42 2600 -0.17 28 20 0 10.56 10/21/2007 7:34 12.67 42 2600 -0.16 28 20 0 10.56 10/21/2007 7:35 14.43 42 2600 -0.17 28 ' 20 0 10.56 10/21/2007 7:36 30.68 42 1200 -0.09 28 20 1 10.56 

### 10/21/2007 7:37 13.39 42 2600 -0.13 28 21 0 10.56 10/21/20077:38 11.42 42 2600 -0.09 28 21 0 10.56 10/21/2007 7:39 12.23 42 2600 -0.1 28 21 0 10.56 10/21/2007 7:40 12.11 42 2600 -0.03 28 21 0 10.56 10/21/2007 7:41 13.42 42 2600 -0.06 28 21 0 10.56 

### 10/21/2007 7:42 13.3 42 2600 -0.19 28 21 0 10.56 10/21/20077:43 13.11 42 2600 -0.16 28 21 0 10.56 10/21/2007 7:44 1142 42 2600 -0.18 28 21 0 10.56 

### 10/21/2007 7:45 13.42 42 2600 -0.16 28 21 0 10.56 10/21/2007 7:46 13.14 42 2600 -0.15 28 21 0 10.56 10/21/20077:47 13.39 42 2600 -0.15 28 21 0 10.56 

### 10/21/2007 7:48 14.83 42 2600 -0.15 28 21 0 10.56 10/21/2007 7:49 13.39 42 2600 -0.14 28 21 0 10.56 10/21/2007 7:50 13.67 42 2600 -0.12 28 21 0 10.56 10/2112007 7:51 13.86 42 2600 -0.14 28 21 0 10.56 10/21/2007 7:52 13.37 42 2600 -0.11 28 21 0 10.56 10/21/2007 7:53 13.8 42 2600 -0.18 28 21 0 10.56 10/21/2007 7:54 13.75 42 2600 -0.12 28 21 0 10.56 10/21/2007 7:55 13.66 42 2600 -0.15 28 21 0 10.56 10/21/2007 7:56 13.41 42 2600 -0.17 28 21 0 10.56 

### 10/21/2007 7:57 14.8 42 2600 -0.13 28 21 0 10.56

1

# Process Data

10/21/2007 7:58 13.85 42 2600 -0.16 28 21 0 10.56 30/21/2007 7:59 13.55 42 2600 -0.14 28 21 0 10.56 10/21/2007 8:00 13.96 42 2600 -0.11 28 21 0 10.56 10/21/2007 8:01 14.1 42 2600 -0.13 28 21 0 10.56 10/21/2007 8:02 30.45 42 1200 -0.06 28 21 1 10.56 10/21/20078:03 11.34 42 2600 -0.17 28 22 0 10.56 10/21/2007 8:04 11.86 42 2600 -0.15 28 22 0 10.56 10/21/2007 8:05 12.31 42 2600 -0.05 28 22 0 10.56 10/21/2007 8:06 14.01 42 2600 -0.13 28 22 0 10.56 10/21/2007 8:07 13.73 42 2600 -0.15 28 22 0 10.56 30/21/20078:08 14.22 42 2600 -0.13 28 22 0 10.56 10/21/2007 8:09 14.27 42 2600 -0.12 28 22 0 10.56 10/21/2007 8:10 14.53 42 2600 -0.12 28 22 0 10.56 10/21/2007 8:11 14.81 42 2600 -0.12 28 22 0 10.56 10/21/2007 8:12 14.37 42 2600 -0.15 28 22 0 10.56 10/21/2007 8:13 14.74 42 2600 -0.14 28 22 0 10.56 10/21/2007 8:14 14.43 42 2600 -0.13 28 22 0 10.56 10/21/2007 8:15 13.57 42 2600 -0.11 28 22 0 10.56 10/21/20078:16 14.39 42 2600 -0.15 28 22 0 10.56 10/21/2007 8:17 14.84 42 2600 -0.13 28 22 0 10.56 10/21/20078:18 13.42 42 2600 -0.12 28 22 0 10.56 10/21/2007 8:19 14.47 42 2600 -0.09 28 22 0 10.56 10/21/2007 8:20 14.04 42 2600 -0.13 28 22 0 10.56 10/21/2007 8:21 14.14 42 2600 -0.13 28 22 0 10.56 10/21/2007 8:22 14.08 42 2600 -0.1 28 22 0 10.56 10/21/2007 8:23 14.19 42 2600 -0.12 28 22 0 10.56 10/21/2007 8:24 14.04 42 2600 -0.08 28 22 0 10.56 10/21/2007 8:25 13.84 42 2600 -0.13 28 22 0 10.56 10/21/2007 8:26 13.73 42 2600 -0.09 28 22 0 10.56 10/21/2007 8:27 29.38 42 1200 0.04 28 22 0 10.56 10/21/2007 8:28 29.72 42 1200 -0.06 28 23 0 10.56 10/21/2007 8:29 11.89 42 2600 0.03 28 23 0 10.56 10/21/2007 8:30 12.77 42 2600 -0.03 28 23 0 10.56 10/21/2007 8:31 11.94 42 2600 0 28 23 0 10.56 10/21/2007 8:32 13.42 42 2600 -0.01 28 23 0 10.56 10/21/2007 8:33 12.04 42 2600 -0.13 28 23 0 10.56 10/21/2007 8:34 15.73 42 2600 -0.15 28 23 0 10.56 10/21/2007 8:35 13.96 42 2600 -0.11 28 23 0 10.56 10/21/2007 8:36 13.09 42 2600 -0.06 28 23 0 10.56 10/21/2007 8:37 15.67 42 2600 -0.13 28 23 0 10.56 10/21/2007 8:38 14.05 42 2600 -0.12 28 23 0 10.56 10/21/2007 8:39 14.44 42 2600 -0.03 28 23 0 10.56 10121/2007 8:40 14.77 42 2600 -0.05 28 23 0 10.56 10/21/2007 8:41 13.57 42 2600 -0.08 28 23 0 10.56 10/21/2007 8:42 15.38 42 2600 -0.06 28 23 0 10.56 10/21/2007 8:43 14.32 42 2600 -0.13 28 23 0 30.56 10/21/2007 8:44 13.56 42 2600 -0.11 28 23 0 10.56 10/21/2007 8:45 15.01 42 2600 -0.09 28 23 0 10.56 10/21/2007 8:46 15.52 42 2600 -0.16 28 23 0 10.56 10/21/20078:47 15.38 42 2600 -0.13 28 23 0 10.56 10/21/2007 8:48 14.79 42 2600 -0.05 28 23 0 10.56 10/21/20078:49 15.47 42 2600 -0.07 28 23 0 10.56 10/21/2007 8:50 14.56 42 2600 -0.08 28 23 0 10.56 10/21/2007 8:51 15.14 42 2600 -0.14 28 23 0 10.56 10/21/2007 8:52 15.86 42 2600 -0.14 28 23 0 10.56 10/21/2007 8:53 30.32 42 1200 0.08 28 23 1 10.56 10/21/20078:54 29.58 42 1200 -0.01 28 24 0 10.56 10121/2007 8:55 11.67 42 2600 -0.07 28 24 0 10.56 10/21/2007 8:56 12.41 42 2600 -0.08 28 24 0 10.56 10/21/2007 8:57 12.66 42 2600 -0.07 28 24 0 10.56 10/21/2007 8:58 12.53 42 2600 -0.04 28 24 0 10.56

2

# Process Data

10/21/20078:59 15.35 42 2600 -0.1 28 24 0 10.56 10/21/2007 9:00 13.79 42 2600 -0.04 28 24 0 10.56 10/21/2007 9:01 14.63 42 2600 -0.09 28 24 0 10.56 10/21/2007 9:02 15.46 42 2600 -0.04 28 24 0 10.56 10/21/2007 9:03 13.71 42 2600 -0.01 28 24 0 10.56 10/21/2007 9:04 15.3 42 2600 -0.1 28 24 0 10.56 10/21/20079:05 15.38 42 2600 -0.05 28 24 0 10.56 10/21/2007 9:06 13.87 42 2600 -0.03 28 24 0 10.56 10/21/2007 9:07 15.51 42 2600 0.03 28 24 0 10.56 10/21/2007 9:08 15.56 42 2600 0.01 28 24 0 10.56 10/21/20079:09 13.86 42 2600 -0.04 28 24 0 10.56 10/21/2007 9:10 15.64 42 2600 0.03 28 24 0 10.56 10/21/2007 9:11 15.62 42 2600 0.08 28 24 0 10.56 10/21/20079:12 14.26 42 2600 0 28 24 0 10.56 10/21/20079:13 15.67 42 2600 -0.03 28 24 0 10.56 10/21/20079:14 15.64 42 2600 -0.04 28 24 0 10.56 10/21/2007 9:15 14.37 42 2600 0 28 24 0 10.56 10/21/20079:16 15.68 42 2600 -0.03 28 24 0 10.56 10/21/20079:17 15.7 42 2600 0 28 24 0 10.56 10/21/20079:18 15.66 42 2600 -0.03 28 24 0 10.56 10/21/20079:19 30.1 42 1200 0.1 28 24 1 10.56 10/21/20079:20 11.47 42 2600 0.06 28 25 0 10.56 10/21/20079:21 11.77 42 2600 0.11 28 25 0 10.56 10/21/2007 9:22 12.83 42 2600 0.07 28 25 0 10.56 10/21/2007 9:23 - 12.83 42 2600 0.08 28 25 0 10.56 10/21/2007 9:24 12.7 42 2600 0.05 28 25 0 10.56 10/21/2007 9:25 15.06 42 2600 -0.02 28 25 0 10.56 10/21/2007 9:26 14.27 42 2600 -0.03 28 25 0 10.56 10/21/2007 9:27 14.13 42 2600 -0.03 28 25 0 10.56 10/21/2007 9:28 15.79 42 2600 -0.06 28 25 0 10.56 10/21/2007 9:29 15.77 42 2600 -0.02 28 25 0 10.56 10/21/2007 9:30 14.12 42 2600 0 28 25 0 10.56 10/21/20079:31 15.72 42 2600 -0.02 28 25 0 10.56 10/21/20079:32 15.75 42 2600 0.08 28 25 0 10.56 10/21/2007 9:33 14.1 42 2600 0 28 25 0 10.56 10/21/2007 9:34 15.77 42 2600 -0.03 28 25 0 10.56 10/21/2007 9:35 15.68 42 2600 -0.12 28 25 0 10.56 10/21/2007 9:36 14.07 42 2600 -0.09 28 25 0 10.56 10/21/2007 9:37 15.74 42 2600 -0.1 28 25 0 10.56 10/21/20079:38 15.72 42 2600 -0.01 28 25 0 10.56 10/21/2007 9:39 13.99 42 2600 -0.09 28 25 0 10.56 10/21/20079:40 15.66 42 2600 -0.11 28 25 0 10.56 10/21/2007 9:41 15.69 42 2600 -0.09 28 25 0 10.56 10/21/20079:42 15.77 42 2600 -0.09 28 25 0 10.56 10/21/20079:43 14.11 42 2600 -0.09 28 25 0 10.56 10121/20079:44 15.67 42 2600 -0.14 28 25 0 10.56 10/21/20079:45 29.94 42 1200 -0.04 28 26 0 10.56 10/21/2007 9:46 11.65 42 2600 -0.16 28 26 0 10.56 10/21/20079:47 11.8 42 2600 -0.14 28 26 0 10.56 10/21/20079:48 12.85 42 2600 -0.14 28 26 0 10.56 10/21/20079:49 14.12 42 2600 -0.13 28 26 0 10.56 10/21/2007 9:50 12.75 42 2600 -0.14 28 26 0 10.56 10/21/2007 9:51 13.18 42 2600 -0.14 28 26 0 10.56 10/21/20079:52 14.05 42 2600 -0.08 28 26 0 10.56 10/21/2007 9:53 14.55 42 2600 -0.15 28 26 0 10.56 10/21/2007 9:54 15.9 42 2600 -0.17 28 26 0 10.56 10/21/2007 9:55 12.96 42 2600 -0.16 28 26 0 10.56 10/21/2007 9:56 15.81 42 2600 -0.19 28 26 0 10.56 30/21/20079:57 15.78 42 2600 -0.12 28 26 0 10.56 10/21/2007 9:58 14.18 42 2600 -0.14 28 26 0 10.56 10/21/2007 9:59 15.78 42 2600 -0.2 28 26 0 10.56

3

# Process Data

10/21/2007 10:00 15.79 42 2600 -0.16 28 26 0 10.56 10/21/200710:01 14.06 42 2600 -0.18 28 26 0 10.56 10/21/200710:02 15.71 42 2600 -0.16 28 26 0 10.56 10/21/200710:03 15.7 42 2600 -0.17 28 26 0 10.56 10/21/200710:04 13.98 42 2600 -0.13 28 26 0 10.56 10/21/200710:05 15.75 42 2600 -0.16 28 26 0 10.56 10/21/200710:06 15.63 42 2600 -0.16 28 26 0 10.56 10/21/2007 10:07 14.27 42 2600 -0.16 28 26 0 10.56 10/21/200710:08 15.71 42 2600 -0.19 28 26 0 10.56 10/21/200710:09 15.57 42 2600 -0.19 28 26 0 10.56 10/21/200710:10 29.95 42 1200 -0.06 28 26 1 10.56 10/21/200710:11 29.91 42 1200 -0.1 28 27 0 10.56 10/21/200710:12 11.64 42 2600 -0.12 28 27 0 10.56 10/21/2007 10:13 11.84 42 2600 -0.09 28 27 0 10.56 10/21/200710:14 12.73 42 2600 -0.08 28 27 0 10.56 10121/200710:15 12.7 42 2600 -0.06 28 27 0 10.56 10/21/200710:16 11.64 42 2600 -0.22 28 27 0 10.56 10/21/200710:17 14.31 42 2600 -0.21 28 27 0 10.56 10/21/200710:18 14.01 42 2600 -0.17 28 27 0 10.56 10/21/200710:19 14.74 42 2600 -0.05 28 27 0 10.56 10/21/200710:20 14.43 42 2600 -0.18 28 27 0 10.56 10/21/2007 10:21 12.88 42 2600 -0.2 28 27 0 10.56 10/21/2007 10:22 15.49 42 2600 -0.15 28 27 0 10.56 10/2112007 10:23 15.63 42 2600 -0.15 28 27 0 10.56 10/21/2007 10:24 12.99 42 2600 -0.19 28 27 0 10.56 10/21/200710:25 15.54 42 2600 -0.17 28 27 0 10.56 10/21/2007 10:26 15.6 42 2600 -0.2 28 27 0 10.56 10/21/2007 10:27 13.92 42 2600 -0.18 28 27 0 10.56 10/21/200710:28 15.49 42 2600 -0.16 28 27 0 10.56 10/21/2007 10:29 15.58 42 2600 -0.14 28 27 0 10.56 10/21/200710:30 13.97 42 2600 -0.11 28 27 0 10.56 10/21/2007 10:31 15.6 42 2600 -0.17 28 27 0 10.56 10/21/200710:32 15.72 42 2600 -0.21 28 27 0 10.56 10/21/200710:33 15.57 42 2600 -0.16 28 27 0 10.56 10/21/200710:34 13.97 42 2600 -0.15 28 27 0 10.56 10/21/2007 10:35 15.61 42 2600 -0.13 28 27 0 10.56 10/21/200710:36 29.76 42 1200 -0.07 28 27 1 10.56 10/21/200710:37 17.62 42 2600 -0.23 28 28 0 10.56 10/21/200710:38 11.82 42 2600 -0.22 28 28 0 10.56 10/21/2007 10:39 11.77 42 2600 -0.19 28 28 0 10.56 10/21/200710:40 12.73 42 2600 -0.13 28 28 0 10.56 10/21/200710:41 11.79 42 2600 -0.17 28 28 0 10.56 10/21/200710:42 13 42 2600 -0.18 28 28 0 10.56 10/21/200710:43 11.55 42 2600 -0.21 28 28 0 10.56 10/21/2007 10:44 14.04 42 2600 -0.16 28 28 0 10.56 10/21/200710:45 12.93 42 2600 -0.09 28 28 0 10.56 10/21/2007 10:46 13.84 42 2600 -0.18 28 28 0 10.56 10/21/2007 10:47 14.1 42 2600 -0.19 28 28 0 10.56 10/21/2007 10:48 15.49 42 2600 -0.19 28 28 0 10.56 10/21/200710:49 12.95 42 2600 -0.18 28 28 0 10.56 10/21/2007 10:50 15.42 42 2600 -0.16 28 28 0 10.56 10/21/200710:51 15.71 42 2600 -0.19 28 28 0 10.56 10/21/2007 10:52 13.37 42 2600 -0.14 28 28 0 10.56 10/21/200710:53 15.64 42 2600 -0.13 28 28 0 10.56 10/21/200710:54 15.66 42 2600 -0.13 28 28 0 10.56 10/21/200710:55 14.21 42 2600 -0.18 28 28 0 10.56 10/21/200710:56 14.06 42 2600 -0.19 28 28 0 10.56 10/21/2007 10:57 15.73 42 2600 -0.16 28 28 0 10.56 10/21/200710:58 15.55 42 2600 -0.16 28 28 0 10.56 10/21/2007 10:59 13.99 42 2600 -0.18 28 28 0 10.56 10/21/2007 11:00 15.72 42 2600 -0.21 28 28 0 10.56

4

# Process Data

10/21/200711:01 15.71 42 2600 -0.12 28 28 0 10.56 10/21/2007 11:02 29.86 42 1200 -0.06 28 28 1 10.56 10/21/200711:03 11.71 42 2600 0 28 29 0 10.56 10/21/200711:04 11.94 42 2600 -0.1 28 29 0 10.56 10/21/200711:05 11.91 42 2600 -0.09 28 29 0 10.56 10/21/200711:06 13.74 42 2600 -0.11 28 29 0 10.56 10/21/2007 11:07 11.85 42 2600 -0.09 28 29 0 10.56 10/21/2007 11:08 14.31 42 2600 -0.14 28 29 0 10.56 10/21/200711:09 12.48 42 2600 -0.17 28 29 0 10.56 10/21/200711:10 12.88 42 2600 -0.16 28 29 0 10.56 10/21/200711:11 14.25 42 2600 -0.17 28 29 0 10.56 10/21/2007 11:12 14.71 42 2600 -0.12 28 29 0 10.56 10/21/200711:13 12.97 42 2600 -0.24 28 29 0 10.56 10/21/200711:14 14.16 42 2600 -0.19 28 29 0 10.56 10/21/2007 11:15 15.78 42 2600 -0.18 28 29 0 10.56 10/21/2007 11:16 12.77 42 2600 -0.14 28 29 0 10.56 10/21/2007 11:17 14.89 42 2600 -0.2 28 29 0 10.56 10/21/200711:18 15.45 42 2600 -0.15 28 29 0 10.56 10/21/200711:19 14.06 42 2600 -0.21 28 29 0 10.56 10/21/200711:20 14.26 42 2600 -0.21 28 29 0 10.56 10/21/200711:21 15.77 42 2600 -0.16 28 29 0 10.56 10/21/200711:22 14.03 42 2600 -0.17 28 29 0 10.56 10/21/2007 11:23 14.51 42 2600 -0.16 28 29 0 10.56 10/21/200711:24 15.81 42 2600 -0.14 28 29 0 10.56 10/21/200711:25 13.99 42 2600 -0.19 28 29 0 10.56 10/21/2007 11:26 15.7 42 2600 -0.17 28 29 0 10.56 10/21/200711:27 29.21 42 1200 -0.07 28 29 0 10.56 10/21/200711:28 29.84 42 1200 -0.04 28 30 0 10.56 10/21/200711:29 11.79 42 2600 -0.11 28 30 0 10.56 10/21/200711:30 11.7 42 2600 -0.17 28 30 0 10.56 10/21/200711:31 12.24 42 2600 -0.12 28 30 0 10.56 10/21/2007 11:32 12.71 42 2600 -0.17 28 30 0 10.56 10/21/200711:33 11.8 42 2600 -0.18 28 30 0 10.56 10/21/200711:34 11.66 42 2600 -0.16 28 30 0 10.56 10/21/20071135 12.4 42 2600 -0.13 28 30 0 10.56 10/21/200711:36 14.02 42 2600 -0.12 28 30 0 10.56 10/21/200711:37 14.44 42 2600 -0.19 28 30 0 10.56 10/21/200711:38 13.21 42 2600 -0.16 28 30 0 10.56 10/21/200711:39 14.22 42 2600 -0.1 28 30 0 10.56 10/21/2007 11:40 15.92 42 2600 -0.13 28 30 0 10.56 10/21/200711:41 13.06 42 2600 -0.17 28 30 0 10.56 10/21/200711:42 14.34 42 2600 -0.19 28 30 0 10.56 10/21/200711:43 15.82 42 2600 -0.2 28 30 0 10.56 10/21/200711:44 14.23 42 2600 -0.15 28 30 0 10.56 10/21/200711:45 14.6 42 2600 -0.13 28 30 0 10.56 10/21/200711:46 15.85 42 2600 -0.19 28 30 0 10.56 10/21/200711:47 14.07 42 2600 -0.17 28 30 0 10.56 10/21/200711:48 14.45 42 2600 -0.18 28 30 0 10.56 10/21/2007 11:49 15.93 42 2600 -0.13 28 30 0 10.56 10/21/2007 11:50 14.26 42 2600 -0.17 28 30 0 10.56 10/21/2007 11:51 15.64 42 2600 -0.19 28 30 0 10.56 10/21/2007 11:52 15.74 42 2600 -0.14 28 30 0 10.56 10/21/200711:53 29.78 42 1200 0.02 28 30 1 10.56 10/21/200711:54 29.8 42 1200 -0.1 28 31 0 10.56 10/21/200711:55 11.87 42 2600 -0.09 28 31 0 10.56 10/21/200711:56 11.95 42 2600 -0.15 28 31 0 10.56 10/21/200711:57 11.82 42 2600 -0.1 28 31 0 10.56 10/21/200711:58 11.6 42 2600 -0.07 28 31 0 10.56 10/21/200711:59 11.63 42 2600 -0.24 28 31 0 10.56 10/21/200712:00 11.64 42 2600 -0.21 28 31 0 10.56 10/21/200712:01 11.75 42 2600 -0.17 28 31 0 10.56

5

# Process Data

10/21/2007 12:02 13.99 42 2600 -0.17 28 31 0 10.56 10/21/200712:03 13.19 42 2600 -0.2 28 31 0 10.56 10/21/200712:04 13.21 42 2600 -0.18 28 31 0 10.56 10/21/200712:05 14.23 42 2600 -0.19 28 31 0 10.56 10/21/200712:06 15.82 42 2600 -0.18 28 31 0 10.56 10/211200712:07 12.86 42 2600 -0.17 28 31 0 10.56 10/21/2007 12:08 14.45 42 2600 -0.18 28 31 0 10.56 10/21/200712:09 15.77 42 2600 -0.21 28 31 0 10.56 10/21/200712:10 13.15 42 2600 -0.16 28 31 0 10.56 101211200712:11 14.65 42 2600 -0.18 28 31 0 10.56 10/21/2007 12:12 15.79 42 2600 -0.15 28 31 0 10.56 10/21/200712:13 14.08 42 2600 -0.19 28 31 0 10.56 10/21/2007 12:14 14.16 42 2600 -0.15 28 31 0 10.56 10/21/2007 12:15 13.06 42 2600 -0.14 28 31 0 10.56 10/21/200712:16 15.69 42 2600 -0.2 28 31 0 10.56 10/21/200712:17 12.61 42 2600 -0.12 28 31 0 10.56 10/21/2007 12:18 15.74 42 2600 -0.18 28 31 0 10.56 10/21/200712:19 29.69 42 1200 -0.03 28 31 1 10.56 10/21/200712:20 10.46 42 2600 -0.19 28 32 0 10.56 10/21/200712:21 11.76 42 2600 -0.14 28 32 0 10.56 10/21/200712:22 11.65 42 2600 -0.18 28 32 0 10.56 10/21/200712:23 12.74 42 2600 -0.19 28 32 0 10.56 10/21/200712:24 12.68 42 2600 -0.18 28 32 0 10.56 10/21/2007 12:25 11.49 42 2600 -0.21 28 32 0 10.56 10/21/200712:26 11.64 42 2600 -0.19 28 32 0 10.56 10/21/200712:27 12.57 42 2600 -0.17 28 32 0 10.56 10/21/2007 12:28 12.56 42 2600 -0.15 28 32 0 10.56 10/21/2007 12:29 12.87 42 2600 -0.16 28 32 0 10.56 10/21/200712:30 13.33 42 2600 -0.19 28 32 0 10.56 10/21/200712:31 15.79 42 2600 -0.2 28 32 0 10.56 10/21/200712:32 11.11 42 2600 -0.17 28 32 0 10.56 10/21/200712:33 14.25 42 2600 -0.18 28 32 0 10.56 10121/200712:34 13.34 42 2600 -0.19 28 32 0 10.56 10/21/200712:35 14.08 42 2600 -0.15 28 32 0 10.56 10/21/200712:36 13.26 42 2600 -0.15 28 32 0 10.56 10/21/200712:37 15.57 42 2600 -0.13 28 32 0 10.56 10/21/2007 12:38 12.91 42 2600 -0.17 28 32 0 10.56 10/21/200712:39 14.01 42 2600 -0.01 28 32 0 10.56 10/21/200712:40 11.53 42 2600 -0.2 28 32 0 10.56 10/21/200712:41 15.73 42 2600 -0.19 28 32 0 10.56 10/21/200712:42 11.59 42 2600 -0.17 28 32 0 10.56 10121/200712:43 15.31 42 2600 -0.21 28 32 0 10.56 10/21/200712:44 14.28 42 2600 -0.16 28 32 0 10.56 10/21/200712:45 29.72 42 1200 -0.05 28 32 1 10.56 10/21/200712:46 11.78 42 2600 -0.12 28 33 0 10.56 10/21/200712:47 11.79 42 2600 -0.09 28 33 0 10.56 10/21/200712:48 11.68 42 2600 -0.03 28 33 0 10.56 10/21/2007 12:49 12.74 42 2600 -0.09 28 33 0 10.56 10/21/200712:50 11.7 42 2600 -0.23 28 33 0 10.56 10/21/200712:51 11.73 42 2600 -0.19 28 33 0 10.56 10/21/200712:52 12.66 42 2600 -0.13 28 33 0 10.56 10/21/200712:53 12.53 42 2600 -0.17 28 33 0 10.56 10/21/200712:54 11.49 42 2600 -0.23 28 33 0 10.56 10/21/200712:55 12.45 42 2600 -0.17 28 33 0 10.56 10/21/200712:56 12.56 42 2600 -0.14 28 33 0 10.56 10/21/200712:57 13.34 42 2600 -0.2 28 33 0 10.56 10/21/200712:58 12.95 42 2600 -0.18 28 33 0 10.56 10/21/200712:59 13.59 42 2600 -0.19 28 33 0 10.56 10/21/200713:00 14.09 42 2600 -0.15 28 33 0 10.56 10/21/200713:01 13.26 42 2600 -0.19 28 33 0 10.56 10/21/200713:02 13.91 42 2600 -0.18 28 33 0 10.56 

# a]

# Process Data

10/21/2007 13:03 13.9 42 2600 -0.13 28 33 0 10.56 10/21/2007 13:04 13.74 42 2600 -0.19 28 33 0 10.56 10/21/200713:05 13.35 42 2600 -0.17 28 33 0 10.56 10/21/200713:06 14.21 42 2600 -0.17 28 33 0 10.56 10/21/200713:07 13.63 42 2600 -0.13 28 33 0 10.56 10/21/200713:08 13.34 42 2600 -0.15 28 33 0 10.56 10/21/2007 13:09 13.17 42 2600 -0.14 28 33 0 10.56 10/21/200713:10 28.59 42 1200 -0.06 28 33 1 10.56 10/21/200713:11 29.54 42 1200 -0.02 28 34 0 10.56 10/21/200713:12 11.76 42 2600 •-0.13 28 34 0 10.56 10/21/200713:13 11.82 42 2600 -0.1 28 34 0 10.56 10/21/2007 13:14 12.02 42 2600 -0.12 28 34 0 10.56 10/21/200713:15 11.75 42 2600 -0.14 28 34 0 10.56 10/21/200713:16 11.62 42 2600 -0.15 28 34 0 10.56 10/21/2007 13:17 11.75 42 2600 -0.13 28 34 0 10.56 10/21/200713:18 11.38 42 2600 -0.11 28 34 0 10.56 10/21/200713:19 11.62 42 2600 -0.03 28 34 0 10.56 10/21/200713:20 11.4 42 2600 -0.11 28 34 0 10.56 10/21/200713:21 11 42 2600 -0.09 28 34 0 10.56 10/21/2007 13:22 12.47 42 2600 -0.09 28 34 0 10.56 10/21/2007 13:23 11.86 42 2600 -0.03 28 34 0 10.56 10/21/2007 13:24 14.07 42 2600 -0.1 28 34 0 10.56 10/21/200713:25 10.68 42 2600 -0.14 28 34 0 10.56 10/21/200713:26 14.03 42 2600 0.02 28 34 0 10.56 10/21/2007 13:27 11.85 42 2600 -0.14 28 34 0 10.56 10/21/2007 13:28 15.28 42 2600 -0.1 28 34 0 10.56 10/21/2007 13:29 13.27 42 2600 -0.09 28 34 0 10.56 10/21/2007 13:30 13.5 42 2600 -0.12 28 34 0 10.56 10121/200713:31 11.74 42 2600 -0.15 28 34 0 10.56 10/21/200713:32 15.48 42 2600 -0.1 28 34 0 10.56 10/21/200713:33 11.92 42 2600 -0.13 28 34 0 10.56 10/21/200713:34 13.47 42 2600 -0.08 28 34 0 10.56 10/21/200713:35 12.91 42 2600 -0.09 28 34 0 10.56 10/21/200713:36 29.49 42 1200 -0.01 28 34 1 10.56 10/21/2007 13:37 20.72 42 2600 -0.12 28 35 0 10.56 10/21/2007 13:38 11.87 42 2600 -0.03 28 35 0 10.56 10/21/200713:39 11.78 42 2600 -0.03 28 35 0 10.56 10/21/200713:40 11.6 42 2600 -0.01 28 35 0 10.56 10/21/2007 13:41 11.85 42 2600 -0.03 28 35 0 10.56 10/21/200713:42 11.48 42 2600 -0.08 28 35 0 10.56 10/21/200713:43 12.27 42 2600 -0.07 28 35 0 10.56 10/21/200713:44 11.3 42 2600 -0.08 28 35 0 10.56 10/21/200713:45 11.61 42 2600 -0.07 28 35 0 10.56 10/21/200713:46 11.32 42 2600 -0.06 28 35 0 10.56 10/21/200713:47 11.04 42 2600 -0.07 28 35 0 10.56 10/21/2007 13:48 12.06 42 2600 -0.05 28 35 0 10.56 10/21/200713:49 13.27 42 2600 -0.09 28 35 0 10.56 10/21/200713:50 11.01 42 2600 -0.05 28 35 0 10.56 10/21/200713:51 13.29 42 2600 -0.05 28 35 0 10.56 10/21/200713:52 12.96 42 2600 -0.06 28 35 0 10.56 10/21/200713:53 12.92 42 2600 -0.07 28 35 0 10.56 10/21/200713:54 12.26 42 2600 -0.06 28 35 0 10.56 10/21/200713:55 14.59 42 2600 -0.05 28 35 0 10.56 10/21/200713:56 11.49 42 2600 -0.1 28 35 0 10.56 10/21/200713:57 12.88 42 2600 -0.02 28 35 0 10.56 10/21/200713:58 11.93 42 2600 -0.07 28 35 0 10.56 10/21/200713:59 12.73 42 2600 -0.07 28 35 0 10.56 10/21/200714:00 11.23 42 2600 -0.04 28 35 0 10.56 10/21/2007 14:01 14.89 42 2600 -0.04 28 35 0 10.56 10/21/200714:02 29.58 42 1200 0.09 28 35 1 10.56 10/21/200714:03 11.47 42 2600 -0.12 28 36 0 10.56

7

# Process Data

10/21/200714:04 11.71 42 2600 -0.05 28 36 0 10.56 10/21/2007 14:05 11.87 42 2600 -0.04 28 36 0 10.56 10/21/2007 14:06 11.68 42 2600 -0.04 28 36 0 10.56 10/21/2007 14:07 11.13 42 2600 0 28 36 0 10.56 10/21/2007 14:08 11.39 42 2600 -0.1 28 36 0 10.56 10/21/2007 14:09 11.15 42 2600 -0.01 28 36 0 10.56 10/21/2007 14:10 12.04 42 2600 -0.03 28 36 0 10.56 10/21/2007 14:11 11.15 42 2600 -0.03 28 36 0 10.56 10/21/200714:12 11.27 42 2600 -0.05 28 36 0 10.56 10/21/200714:13 11.98 42 2600 0.05 28 36 0 10.56 10/21/200714:14 11.05 42 2600 -0.08 28 36 0 10.56 10/21/200714:15 11.2 42 2600 -0.07 28 36 0 10.56 10/21/2007 14:16 10.95 42 2600 -0.07 28 36 0 10.56 10/21/200714:17 12.55 42 2600 -0.03 28 36 0 10.56 10/21/200714:18 11.13 42 2600 0.01 28 36 0 10.56 10/21/2007 14:19 12.51 42 2600 -0.04 28 36 0 10.56 10/2112007 14:20 12.38 42 2600 -0.02 28 36 0 10.56 10/21/200714:21 12.41 42 2600 -0.03 28 36 0 10.56 10/21/200714:22 11.07 42 2600 -0.04 28 36 0 10.56 10/21/2007 14:23 13.05 42 2600 -0.06 28 36 0 10.56 10/21/200714:24 11.06 42 2600 -0.07 28 36 0 10.56 10/21/200714:25 12.38 42 2600 0.01 28 36 0 10.56 10/21/200714:26 11.16 42 2600 -0.04 28 36 0 10.56 10/21/200714:27 25.92 42 1200 0.06 28 36 0 10.56 10/21/2007 14:28 29.4 42 1200 0 28 37 0 10.56 10/21/200714:29 11.76 42 2600 0.11 28 37 0 10.56 10/21/200714:30 11.72 42 2600 0.05 28 37 0 10.56 10/21/200714:31 11.66 42 2600 0.06 28 37 0 10.56 10/211200714:32 11.7 42 2600 0.01 28 37 0 10.56 10/21/200714:33 11.44 42 2600 -0.16 28 37 0 10.56 10/21/200714:34 11.66 42 2600 -0.08 28 37 0 10.56 10/21/200714:35 11.59 42 2600 -0.05 28 37 0 10.56 10/21/200714:36 11.63 42 2600 -0.07 28 37 0 10.56 10/21/200714:37 11.68 42 2600 -0.03 28 37 0 10.56 10/21/200714:38 11.19 42 2600 -0.04 28 37 0 10.56 10/21/2007 14:39 11.15 42 2600 -0.03 28 37 0 10.56 10/21/200714:40 11.49 42 2600 -0.07 28 37 0 10.56 10/21/200714:41 10.87 42 2600 -0.04 28 37 0 10.56 10/21/200714:42 10.84 42 2600 -0.1 28 37 0 10.56 10/21/200714:43 10.92 42 2600 -0.07 28 37 0 10.56 10/21/2007 14:44 11.12 42 2600 -0.04 28 37 0 10.56 10/21/200714:45 10.92 42 2600 0 28 37 0 10.56 10/21/200714:46 11.49 42 2600 0.03 28 37 0 10.56 10/21/200714:47 10.9 42 2600 -0.1 28 37 0 10.56 10/21/2007 14:48 12.03 42 2600 -0.06 28 37 0 10.56 10/21/200714:49 10.84 42 2600 -0.04 28 37 0 10.56 10/21/200714:50 11.94 42 2600 -0.08 28 37 0 10.56 10/21/2007 14:51 10.92 42 2600 -0.03 28 37 0 10.56 10/21/200714:52 11.93 42 2600 -0.09 28 37 0 10.56 10/21/200714:53 29.58 42 1200 0.04 28 37 1 10.56 10/21/200714:54 29.68 42 1200 0.06 28 38 0 10.56 10/211200714:55 11.62 42 2600 -0.02 28 38 0 10.56 10/21/200714:56 11.64 42 2600 -0.05 28 38 0 10.56 10/21/200714:57 11.11 42 2600 -0.07 28 38 0 10.56 10/21/200714:58 11.55 42 2600 -0.05 28 38 0 10.56 10/21/200714:59 11.56 42 2600 -0.07 28 38 0 10.56 10/21/200715:00 11.19 42 2600 -0.04 28 38 0 10.56 10/21/200715:01 10.93 42 2600 -0.06 28 38 0 10.56 10/21/200715:02 10.85 42 2600 -0.07 28 38 0 10.56 10/21/200715:03 11 42 2600 -0.03 28 38 0 10.56 10/21/2007 15:04 11.04 42 2600 -0.04 28 38 0 10.56

8

# Process Data

10/21/200715:05 12.92 42 2600 0 28 38 0 10.56 10/21/200715:06 10.72 42 2600 -0.06 28 38 0 10.56 10/21/200715:07 11.66 42 2600 -0.05 28 38 0 10.56 10/21/200715:08 11.93 42 2600 -0.06 28 38 0 10.56 10/21/200715:09 11.47 42 2600 -0.05 28 38 0 10.56 10/21/200715:10 10.67 42 2600 -0.01 28 38 0 10.56 10/21/200715:11 11.91 42 2600 -0.04 28 38 0 10.56 10/21/200715:12 10.81 42 2600 -0.06 28 38 0 10.56 10/21/2007 15:13 12.83 42 2600 -0.12 28 38 0 10.56 10/21/200715:14 10.67 42 2600 -0.06 28 38 0 10.56 10/21/200715:15 11.98 42 2600 0.02 28 38 0 10.56 10/21/2007 15:16 11.4 42 2600 -0.03 28 38 0 10.56 10/21/200715:17 12.33 42 2600 -0.07 28 38 0 10.56 10/21/2007 15:18 12.2 42 2600 -0.03 28 38 0 10.56 10/21/200715:19 29.52 42 1200 0.03 28 38 1 10.56 10/21/200715:20 11.74 42 2600 0.03 28 39 0 10.56 10/21/200715:21 11.67 42 2600 0.08 28 39 0 10.56 10/21/200715:22 11.65 42 2600 -0.01 28 39 0 10.56 10/21/200715:23 11.64 42 2600 0 28 39 0 10.56 10/21/200715:24 11.57 42 2600 0.03 28 39 0 10.56 10/21/200715:25 11.42 42 2600 -0.08 28 39 0 10.56 10/21/200715:26 11.21 42 2600 -0.08 28 39 0 10.56 10/21/200715:27 11.45 42 2600 -0.07 28 39 0 10.56 10/211200715:28 10.86 42 2600 -0.06 28 39 0 10.56 10/21/200715:29 11 42 2600 -0.03 28 39 0 10.56 10/21/200715:30 11.22 42 2600 -0.02 28 39 0 10.56 10/21/200715:31 10.59 42 2600 -0.06 28 39 0 10.56 10/21/200715:32 10.5 42 2600 -0.06 28 39 0 10.56 10/21/2007 15:33 10.72 42 2600 0 28 39 0 10.56 10/21/2007 15:34 10.44 42 2600 -0.05 28 39 0 10.56 10/21/200715:35 11.71 42 2600 -0.06 28 39 0 10.56 30/21/200715:36 10.5 42 2600 -0.05 28 39 0 10.56 10/21/200715:37 10.51 42 2600 -0.06 28 39 0 10.56 10/21/200715:38 11.93 42 2600 -0.01 28 39 0 10.56 10/21/200715:39 10.7 42 2600 -0.01 28 39 0 10.56 10/211200715:40 10.6 42 2600 -0.04 28 39 0 10.56 10/21/2007 15:41 12.49 42 2600 -0.08 28 39 0 10.56 10/21/2007 15:42 10.45 42 2600 -0.04 28 39 0 10.56 10/211200715:43 11.22 42 2600 -0.06 28 39 0 10.56 10/21/200715:44 11.13 42 2600 -0.05 28 39 0 10.56 10/21/2007 15:45 29.7 42 1200 0.08 28 39 1 10.56 10/21/200715:46 11.07 42 2600 -0.09 28 40 0 10.56 10/21/200715:47 11.38 42 2600 -0.01 28 40 0 10.56 10/21/200715:48 10.6 42 2600 -0.08 28 40 0 10.56 10/21/200715:49 10.81 42 2600 -0.05 28 40 0 10.56 10/21/200715:50 10.76 42 2600 -0.07 28 40 0 10.56 10/21/200715:51 10.45 42 2600 -0.08 28 40 0 10.56 10/21/2007 15:52 11.57 42 2600 -0.05 28 40 0 10.56 10/21/200715:53 11.22 42 2600 -0.03 28 40 0 10.56 10/21/200715:54 11.24 42 2600 -0.08 28 40 0 10.56 10/21/200715:55 10.43 42 2600 -0.06 28 40 0 10.56 10/21/200715:56 10.63 42 2600 -0.08 28 40 0 10.56 10/21/200715:57 11.28 42 2600 -0.03 28 40 0 10.56 10/21/200715:58 11.6 42 2600 -0.07 28 40 0 10.56 10/21/200715:59 10.43 42 2600 -0.01 28 40 0 10.56 10/21/200716:00 10.45 42 2600 -0.1 28 40 0 10.56

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