### Anllunl Hours FIN EPN of Opctltion" (ltr/yr)

Xi/II 

### 2-1 2 

### 8,275 2-2 

### 6 8,200 

### 2-3 12 8,178 

### Raw MiJ/,i 1-7D F-MBI 

### 4.007**1~7E** F-MBI 

### 3.678 Fi"i5I1MIIL'i 

### 4-1 5 

### 7.635 4-2 9 

### 8.015 Stamler**(CI'It~;III!') 1~24**  

### 1-24 1.222



### " Per Dc:cembel" 2005 "Yell.rlo 

### Dnte OPBRAT1NG 

### REPORT- for the Mldlolbian 

### Plant h 

### Pel" June 30,2005, July 31.2005, Rlld AUQust 

### 31. 2()0.5 "DAILY OPERATING RBPORT" for 

### the Midlothian Plan

Clinker Prodlletk)ll 

## Ash Grove Texas, L.P.· Midlothian Plant 2005 Actual Emission Rate Calculations -Input 

## Duta

KIIIIl, Raw Mill, Finish MlU, and**Cru,"lD~** Houri of Operatlo.

01.onCl SelUon 

### Houn 

### ofOpcrRHon b 

### JUlle July**All~USI** 

### Total (hr) (br) (111") (1I1·fo1.one 3el\Soll)



### 713 719 680 2,111 

### 716 741 

### 733 2,190 720 

### 742 

### 737 2,199



### 288 356 

### 350 995 

### 374 348 

### 314 •• 035



### 710 702 6()B 

### 2,019 658 

### 683 6&9 

### 2.031

369 363 348 

### 1,079

Annual CU.I,er FIN 

### EPN Produetion u (tpy) 

### 2-) 

### 2 313,084.0 

### 2-2 6 

### 308,913.8 

### 2-3 12 312,915.3

I 

### Pel' December 200S ''Year to Date OPERA TIN(] REPORT" for the Midlothifm Plant

• Per June 30. 2005, July 

### 31, 2()()5, ;lndAtlgust 

### 31. 2005 "DAILYOPBRATINO REPORT" 

### for the Midlothian 

### Plan Ozo.e

### S~"SOIl Clinker PnducU.II I ' 

### June July 

### AIlJeust**T~(al** {tOil) (tOil) (tu) (ton/olone ItaSon)**27.~59.8** 

### 28.179.0**2~,125.t** 

### &1,263.9 

### 27,491,3 

### 28,002.2 

### 27,629.0 83,122.5 28,350.0 

### 28.800.3 27,848.6 

### 84,998.9

# ~\\f\ 

# n6V\VS

# ~\\"'~~Y"**~~ c.~~** 

Ash Grove 

### Texas, 

## L.r. Midlothian Plant 30f30 

### Trinily Consullanls

# Ash Grove Texas, L

.. P.

- Midlothbm Plant 2005 Actual Emission Rate Calculations

- Kilns

Kiln NOD S02, 

## CO Emission CalcnlatiODS 

## (CEMS Data)



# .. Monthly Emissions 

## January Febrwrry 

### March April May 

## June July August 

## EPN Description (tons) 

### (tous) (tQD5) 

### (tons) (tom) (tons) 

### (toIlS) (tons) 

### Compound

NQ x 

### 62.20 

### 49.98 59.18 58.74 66.91 

### 64.62 65.67 54.02 2 

### Kiln I 124.92 94.11 14537 17735 232.99 197.63 187.03 

### 180.02 

## S02 

## CO 15.19 17.89 18.84 13.44 

### 8.87 9.73 14.24 13.79

77.52 

### 2337 67.04 62.63 

### 63.29 60.66 

### 67.58 66.57 

### 6 K.i1n2 

## NO" 247.68 88.95 249.24 

### 230.41 211.93 

### 199.56 140.14 15230 

# SOz CO 10.54 

### 4.15 

### 11.62 11.97 

### 1120 

### 9.45 13.46 16.93



### 40.56 78.27 69.91 66.86 58.15 52.59 68.83 

### 6.5.88 

### 12 Kiln 3 

## NO" 78.65 148.97 95.70 83.52 129.18 134.56 93.09 102.36 

## SOl 

## CO 4.25 16.10 21.77 20.04 17.37 

### 15.40 17.00 2132


### Total Kiln EInlssloDS



### a MOnthly 

### emlssioD$ obtained from Continuous 

### Emissions Monitoring (CEMS) data reports, 

### provided by Ash 

### Grove on JanU8Iy 22, 

### 200t
b 

### Per TCEQ 2005 Emissions Inventory Guidelines, 

### RG-360/05 (December 

### 2005), the ozone season is from June 1st 

### through August 31st,**inclusiv~** 

### FIN

2-1



### 2-2

2-3 

### September (tom) 

### October (tons)



### 63.63 271.72 13.56 55.56 

### 271.25 13.00

5&.91 165.70 15.48 73.30 205.71 13.27

63.98 145.24 

### 2L39 71.49 160.87 16.40 

### November (tons)



### 53.10 208.05 14.10

70.04 178.27 9.77

71.97 195.43 15.32 

## December (tons)



### 39.68 112.03 6.90

74.22 179.74 14.85

81.99 193.31 16.67

NO x 

### S02 

## CO Emissions 

### Annual

(tpy) 

## Ozone Season h 

### (lblday)



### 693.35 2,202.47 

### 159.5S 4,006.74 12.,275.65 820.87

765.13 2,249.63 142.69 4,235.00 10,695.65 

### 866.09

790.48**1~60.88** 

### 203.03 4,071.74 7.,174.13 1,167.83


### 1,148.96 6,012.98 505.27 12,313.48 30)145.43 2,854.78



# ?­ 7<­ 

# ! :@ :$ 

# UL-C**-~** 

# s:>**~~**


# >= (5/

\



# cf\

Ash Grove 

## Texas, L..P. Midlothian Plant 

## 7of30 Trinity Consultants

## Ash Grove Texas, L.P.

- Midlothian Plant 2006 Actual Emission Rate Calculations· Input 

## Dnta

Kiln) 

### RAW**MiJI~** 

### Finish Mill. :lnd Cl'l1shing H(Ku"3 

### OfOpel'I1CioD

AnnulI Hours Ozone Season 

### HOlln 

# or Operl\U.n· 

### June July Anliist 

### Totlll 

### FIN EPN of Oporatlon· 

### (hdya9) (hr) (In) (br) (hr/o2.0DC 

### aeason)

Kiln 2·) 714 144**7~4·** 

### 2,202 2**8~339** 

### 2-2 6 108 

### 743 708 

### 2,159 8,174 2-3 

### 12 8,286 110 744 

### 121 2,17S**RaJ)lM;ll~'** )

.. 7D 

### F·MB) 

### 4,410 371 3S6 441 

### 1,168 F-MBI 

### 4,263 376 

### 411 312 

### 1,099 

### 1·7B F1l1lsh**MIII~** 

### 4-1 1,783 657 652 

### ?OS 2,013 

### S**4-~** 1,116 

### 617 692 

### 627 1,935 

### 9 

### Stamler (ems/It,,.) J·24 

### 1-24 363 392 361 J,123 

### 4,229

I 

### Per December 2006 ''YOSI' 10 Dale 

### OPERATING REPORT" for the 

### MtdlothillJl Phmt.

II 

### Per ]unct 30.2006. July 31, 2006, fUld AUjust 31, 2006 "DAILY 

### OPERATING REPORT" for 

### the Midlothian 

### Plant.

Clinkcl' 

### Pl'oducUon



### FIN

2-1 

### 2-2 2

.. 3 

### ErN

2 {) 

### 12 Annual Oinkel' PI'Odudion­

(tp)')


### 334,160.8 ))8,485.2 323,847.) OZOIlO S"lson 

### alubr

### PI'odutrion~ 

### June ,luly 

### August Total (Ion) (ton) (ton) 

### (ton/ozone seRion)


### 27,572.6 

### 28,977,5 29,416.4**8~,966.S** 

### 26,890.6 Z8,B03,3 

### 27,329.4 83,023.3 

### 26.348.4 28.534.4 

### 27,843.4 82,726.2



### • Per December 2006 "Year to 

### Date OPERATING REPORT' 

### for the Midlothian Plant

b 

### Per June 30, 2006. 

### July 31, 2006, and 

### August 31, 2006 tIDAlLY 

### OPERATING REPORT" for 

### the Midlod1iEUJ PLmtt.

# ~\n**n~YS ~ybetm** 

Ash Grove Texas. L,P, 

### Midlothian 

### Plant 30f29 

### Trinity Consultnl,ts

# Ash 

# Grove Texas, L.P.

- Midlothian Plant 2006 Actual Emission Rate Calculations

- Kilns

Kiln 

## NOv SOb CO Emission Calculations 

## (CEMS Data)



### Compound**NO~ S~**  

### CO



## NO x**S~** 

## CO

NO"**S~** 

## CO EmissioDa Monthly Emissions ll 

### January Febra:ary March April May 

### June July August 

### September October November 

### December ADnual 

### Ozmae SeasoD b 

### (toDS) 

### (tons) 

### (toDS) (trms) (tODS) 

### (tons) (toIlS) 

### (toDS) (toDS) (tons) (tons) 

### (toDS) (tpy) (lblday) FIN 

## EPN DescriptiOD



### 69.386L 60.4490 64.4573 64.2024 70.L241 72.0165 71.8020 65.9715 64.6937 5&.0380 57.4416 37.2168

# 755.7~ 4,560.6522 

## 206.8620 189.4473 183.9578 192.7933 230.2726 228.L686 246.3561 

## 213.5413 150.0201 198.8193 154.9290 103.4212 2-1 2 

## Kiln 1 2;298.5946/ 14.957.9574 11.03S9 

### 9.1573 

### 10.7232 11.1933 12.9964 11.8200 ]0.6804 11.3375 12.2003 12.9309 10.4004 4.9126 129.3882 / 735.6077



### 721.90 10./ 3,930.5467 76.9657 38.6756 66.7310 60.5552 67.0394 67.3123 59.5444 53.9485 63.6637 

## 64.3026 57.2068 45.9560 

### 2-2 

## 6 Kiln 

### 2 193.3457 102.6650 214.8876 187.7462 172.5071 131.6721 171.4602 177.6386 129.5926 163.3053 224.6011 140.9190

# 2,010.34~ 10,451.5403 15.6287 4.2951 9.6139 12.2149 14.0410 

### 15.4382 18.5628 16.1929 14.669L 

### 15.5394 9.7158 

### 11.0084 156.9201 1,091.1707

740.6744/ 

## 4,051.7109 128.1149 221.6056 149.4815 136.8023 132.8300 135.7006 166.5307 171.4562 183.6454 173.1 L59 162.0788 193.0731 47.7865 68.2169 

## 69.6191 65.1739 

### 67.1752 65.2795 63.1648 

### 57.9345 60.6852 60.1410 52.9070 62.5909 2·3 12 Kiln 

### 3

# 11954.4350.~101297_5548 189.8754'-' 1.135.9967 9.1879 10.4649 21.6800 16.3138 19.7145 18.1807 17.8374 L6.2378 14.9843 16.8908 14.5973 

### 13.7861

Total Kiln Emissions 

### N0 1 

### 2,218.3744 12,542.9098 

### SOl 6,263.3702 35,707.0525 

### CO 476.1837 2,962.7751

Calculated

Annual Emission Factor (lb/ton 

## FIN 

# EPN Description Compound clinker) 

# ,
2-1 2 

### Kiln L

# 4.52~'" NOll: 2-2 

### 6 

## Kiln 2**NO~** 

### 4.53 // 

### 2-3 

## 12 Kiln 3 N0:t

### 4.5~

.. Monthly emissions are obtained from Continuous Emissions Monitoring (CEMS) data 

### reports, per email from Francisco Pinto, 

### Ash Grove. to VmeetMasuraha, Trinity**Consul~** 

### dated April 23, 2007.
b 

### Per 

### TCEQ 2006 Emissions Inventory 

### Guidelines, RG-360AlO6 (J lUIUary 

### 2007), the ozone season is from June I st through 

### August 31st. inclusive.

# ~~ 

# '=£"7< -S­

..--**~~,.** 

# C9 ( c::: 

# -'" 'Co 

# r? \

Ash Grove Texas, L.P. Midlothian Plant 70f29 Trinity Consultants

# l~

# ~Ib**~~~:~PI!,·~** ....

# :~.t.bI&\ll 

# '.Jant. io07**·A.l·1=~o·~:~~=C.i~~iioD~.-ll)put** ;pata
.,',..



# ..



# .**~;~** 

# .. if'o

.. ·

# "c~:j**o.:o...~.H~~~*~~** 

# . FIN 

# EPN**·Ot~lioa·'.·** 

# * 4q.It'**.:r~** 0 

# '.;'**~~t**

# ~"'"**.~.** '.

# ~r/~~~.")" :**'~iJ"** o' '1. • ,h t

, I'



## .. 2

.. 1 

# 2**'8~I'** 

# 6.57

# ~1'**7~** 

# .1-.9.19' 2<2 6-:**':~~"** 

## 698 

# 407**,~**

## l~='1-": : 

## 2-3**~2**

# .'1.~~:**S~ ~32**  

# 724**1~.64'7·** 

## 2

.. 1 (With 

## SNCR. oalyt 2 

# 3':88 2t6 

## 4S6 624 

# 1,2%' IRqwMIIJI 1·10 

# '·Mal**jt~** 

## 348 96 

## 318 

## 762 

## ]

.. 7E 

# P-MBI 3,988 331 

## 288 

## 316 

# 99S Pln1.Jh 

## MiJ1$ 4-1 5 6,893 

## 457 429 1t2 

## 1,597 4-2 

## 9 

# 7.m 619 

## 547 

## 727 1.893 SflUItIn 

### (CrN$ltn) 

## 10424**1-~4** 

## 3,923,**3~S** 

# ZZ2 373 

# 94tO


# • ·Pet 

# DecofttbOr 2rx11 

# "'teir to 

# Da.QHiRA11NO**RBP6li"'ofor.w:M~I~** \ Pot 

# Juno

# 3O.:2007~·1uIy 31,2007;.a AtJ8U't 31, 

# 'JJXn. 

# -Dj\D:.Y,oPmiATnio**~POR"'"** .for,1hoMidlothl.PbI" , 

## . • the 

# SNCR 

# opcritiOO:l1 time information obtainted ttom

# FrtJi~**Pirt~** .. Ash 

# orovc; to 

# Anand

# MaSun.b~**~ity** CQD8uJtanfJ

.. Manh J6, 2008

## ~.rProcl_"



## FIN 

# EPN**Aoli~** 

## Clhd,er



# . Prud:acdoa& (tpy) 

## Total**(to~.·~e-n)** 

# OzeD. 

# s. •• CUltker. Produc:dCt

.. 1t

### J~)'**AlI"~** 

### (toD) 

## (to.) 

# 2

.. t 2-2 

## z..3 

# 2 6 

## 12**313~129.4 286.269~4** 



## . :.:'**29?~7S.~** 

## 25,409.5 25,879.1



# ..**21,9~9~8** 20

.. 101.1 

## 1S.133.5 

## l2,409.S 

## 27/134.0**25,3~.2** 

## 27,206.0 73.445.2**~12.8**

### 6~t575.3 

### Per 

## December 

# 2007 "Yeer to 

# 01. OPBltATlNG iUtP9XT'**f~·_M~.·t]_**

# ~. 

# Per llWO 

## 30, 2007.

# ~y lit 2007. aod 

## All&USt 31.2007 

# "DAILY**OPBRA~ ~R""**  

# for the 

## Midlothian PJanl



# ,Aih**~ve** 

# Texas, LP. ­



# . MDiw.tbim Platit ioi30 Trinity 

# .Consult81lts**~.** \ 

# '..



# .

# _--A-_--__._..-

...

_ 0 -_-_ ---.------ .--'.

----­ 1



## Ash 

# Grove TeDl

.. MicDotbtaa Plant 2807 

# EiaJ.sl e OdaalatloDs • 

## JaIDs

ICI1II NOp 

## CO 

## bdIdoa Calee1d

.. 

## ·(CDIS Data)

...

## ~EmI"'"

## ~Se!f}Joa" ·J--11 

## F"r, M.a:Ia AprB 

## Mar J8k 

## l1dJ Aapst 

# AmI" (tGaI) (tGa) 

# 6*).**(~.)** 

# (.> (fOal) (IDU) 

### (1M!) 

### (1b14ay) 

### SPH**~)** , .

### ~Ip)') Odokr**N~~** (tMIt> 

### (-.)**~)** 

### 39.t111 59.6G40 34..6P,!n. 

### 197-'613 lS1.s64 1 

### IJ2.B1-46 

### 19.7791 16.9285 8.6479



### 54.1092 54.4961 

### 48.1312 

### 2-C.2960 2-412.7698 2%1.sM3



### _ 

### 16364t 133936**l~l**


### n.8457 

### 55AM 61,1311 173.1113 U3.92S1 14.539;62 

## 2OS7SO lSS1I2

# ~~~;

# u:.~~~- ......... 

# : JCbl**~st** 

### 36.9483 <KIno S9.6191 

### 41.1192 26.3691 

## 3'.te7**'20~16** 

### 2.23.3.0841 

## SO:**~~** 

### 186.7-4-41

### ~. 

### 16'.1034 131.so11 131.1241. 

## 172.3161 1-42..4124**15~.2321** 

### 179.5174- 

# i19.cml**lJiJ~.8051** 

### 10.438.3152 

# co 1009131 11.5884 W163 14.2062 1

... 

# .ss53 13.0092 8.-47JS**15~** 

# U9733 tQAS7l 805".4185 

### NH,c 

### 44224 

### 31.8939



# , XiD.2 

### NO. 

### SO.9207**1~73S8** 

### '1.7990 613&53 

### 63.2794 

### 59.1211 32.0110 S2.0Q66 

### 6S.4S22**:~l ~tll.8161**  

### 2..--«$Q.IS07**11~** 

### 180.3'14- 

### S8..1293 J08.7189 239.602 

## 233-'15& 191.6978 

### 1J9.1936**2rn~86Z1** 

### 2.13.7173 

## SO:l 13.'MOS 

### 3.313S 

### 1005'1J 11.4693 

# 12.5000 14A22S 

### 1.82S7 11.3952 13.7.(76 

### <Xl**141.~** 

### 153.1163

12 

## Kiln 3 

### 31.0842 

# sa.19Q8 63.2741**62.4~ ~.s026**  

### ... .9949 

### 2.7.3151 

### 55.9990 $«431 

## NO.**~92** 

### 1.789.321ll ll1A631 

### 196.4134 151.2975 

### l24.O611 

### 143A341 16Q.'7444 98.3SC 

### 116.8463**161~12**

### 1~**9~S4~~** 

# co U281**15.4~** 

### 16.046-C 

### 11.4040. 18.53" l

... mS1 S.-44J86 

### 14.2Sal**16.S~** 

# 733.l679

•**rr.c.lJala~ ~-**  

# ),1Mit**~. ~.,...**  

# cO "**~qfm** 

### . 

## .Miu**i1~.** fU(



### 2--1



### 2.-2



### 2-3

J'IN**~l** 

### 2-2 

### 1-3 . c.IcaIa.s 

## AimDl
JI'.-. .(DrJta



### NOll 

## J.n NO. 

## NO.. 41'

...



### _. - 

### ErN

2' 

## DDt 6**XilD~** 

### 12 KDa.3**'~~(CSMS)_d.&a ~."'1frCca**  

## lriftoilco 

## Pllco. Alb Grow. co 

### AnInd 

## MaurIha. 

## TiiDita duid Waeh4. 

## 2001.**~til** 

### .. oaia**CNH~** 

## • WoatW;air

..**··Qi~bUIt** 

## ..**D-'ai·,.-.~...,_oiow.,.~21.2L008.**



## ,**Ptr~2OOf** .........**~~~~2coI).** ..

## CI2:ODW~·wavm..,..**tIt~~31~~** •

# ··~~~~ ...

# ~~TM~ ....

# ~- ....

# ~~~_k:zAtIbt1lr4 . 11ds

....**·~witJltbohoarof~ofSNCadmiDcOZ;O"-·..-oDlldlllDUlUyil** 

### ..**~~IIIUIKXJk~w"bcaSNCRilopcati%:31-** 

### In2001.SNCRWllSoulyopcntadforKiD 

### 1. 

# Ash**Gvt>~L.** - 

# 2 0 

# 01 

# N 0'/ Sb1-

# ~Y)nlAcvt

..J •

Alb GloYO Texu, LP. 

## MkIothiaD PlIDt 70£30**TrixlityC~'**i 

# Ash Grove ·T'cxas

.. L

.. P.

- Mid loth ian 

# Pla'nt 200X Actual 

# Elll;ssinll**Rat~** 

## Cnlcu-lati(1)s

.. 

## Inpul Data

f'iln. Hn\\- Mill.**Fini~h Mill.~1I1dCru"hfng** **Ilours~'lr()pel'{llu,lI1**



## FIN



## Kiln**~-I** 

## 2-2 2-J 

## .:!

.. I (\Vith SNCR, 

### (lnlyr'**2·~** 

### (With SNCH, tmJyt 

# "-J (Wilh kNCR.**only)~** 

# LPN

6 

### 12 Annuoilloun. of ()jlera 

### I j(lIl li 

### tlll\r}**~.i\56** 

### '6,8Rl'**7.Q7~** 

### 5;221 

## 5A87**~)O1** 

## .Julie (hI")



### b8<J**70~** 

### 704 

### (

.. 10**M~~~** 

### 6(-.2 

### Ozone**S~".snn** 

### H(Jurs 

### ofOrcrulHln I. .l\lf}'**i\lIgu~(** 

### Tolar (hr) (hr) (hr··ul.<.\rH.'**~CCl~()I1)**



### 71$ 

### 744**l:l~** 

### 741 

## 7·B**~.I ~):;**  

### 714**7~4** 

### 2.f·H 

### ('RK :,\9i\ 

### 1,\)24 720 

## 734 2.1 )(, 68R 

### 714**~,(JM** 

## 1-71> 1-7E ..... \1BI F-MBI 3.ltS,'i**~l~4<}** 

### :'77 

### J5H J(J] 

### ;1(,1 1.O9() 

## J3J 3Jb I,olt) 

### F**illi~h ~'hlls** 



### Slumlcr**(Cfu~hcrl** 

## 1

.. 24 ]-24**7.~51** 

### 8.I.'iQ



### J.760 63t! 

# (i""

357**tl9~** 

### 7lt4 1.0MI 704 CJI() 

## l.tJ44

J53 

## J5Q I Jl(,&


## .' Per**l)cc~~ml~r ::W(U~** **'tYc~tr** 

### h' 

### {)mt: OP]f.RATlN(I 

## REPORT" 

## J«x lhe Mldlothiall Plant. h

### I'~r**.I11m~** 

# :W.**~()mt** 

## .I11ly 31. 2008, 'tn<l

### Augll~1 -' 

### I. '200loi 

## "nAil

. .)' OPER

... \TING 

### REPORT" l"<1r

### th~ 

## Midlothian Plant

l' 

### The SNf'I{ ('lJlCl1Jl.ional1,ime 

### intbrmalion 

## otltnlnt<.'d fhll1l Michael CnUclldcn

.. Ash Hrove. lO 

### /\mmd**Mn~urnl1n. Trtni~y**  

### Con:sultun(s. 

## P"'hrm\fy 12.**~()()Q** 

### tlnd 

### February I**~~** 

### :!OfN.

Cllnl\cr 

### Pro(hicl ion

FIN FfiN ,\nl1ml" 

### Clinker Prnduction"

"(tpy) 

## Jun" Oon) 

### {h'one

### Seu~nn Clinkl,.\'r 

## Pnxltlcllnn" ,I 

## uJy**AlIgU~il** 

### Tnlj{ (lOll) 

## (ton, (10l1·-0/,(HiI.:l\c(lSun)


## 2 6 

## 11**:~.:!2.8274 2~6~~CH\.4**  

### JOl}5 f

...**~5JlR:).n** 

### 27.10n7**:;7.~J2** 

## 5**2~.HR6.\)** 

### 28.74'1.Q 27571.0 

## 27.537.1**~7.Q09** 

### :'**:27.~4Q** l)**~(l.J()~.** ) 

### R·LJ5:'.1 X2,J5J4 

### .} Per Dt.'Ct'ml)\.\f**~O(JX** 

### "Year lO 

### I )alC 

## OPERATING REPORT" Ill!" lht: 

## Midl()(hiull Plant.

P'-'r

.

### .I11tl~ 30, 

### :!()08\ .July J I. 

### 2008:alld AugU":1 J I!

### :W[l~ -1)t\ll.Y 

### (lPFR,\TJNG REP< )RT" 

## f()l' the 

### Mid)()'hian IJJanl.**(\~h** 

### Urovc Texus

.. 

## r.,.p.**lvtidl'()lhi~tIl** 

## !)]an1. 

## 3 ofJ 

# t

## Ash Grove Texas t 

## LP. -l\tidlotbian 

## Plant 2008 Actual 

### EmiJsioD 

### Ra. CaIc:alatiol1s

- Kllns

Kiln NO., 

## co Emi.Jlioa CakulatiOltS (CKMS Data)



### I'IN 

### EPN Descripti2-1 2 KiJD 1

2-2 (; 

### K1In2

2-3 12 Kiln 3



### il'obl Da EmissiIlU

I"IN J3'N DesaiptiH.



### 2-1 2 

### Kilnl 

# .z.2 6 IGln2 2-3 12 IGIn3**MoDlbJy~o..** Jan1Ult'1 Jebnary Matda April May 

### Ju.e 

### J1I1r Aneut Septc:mber (Xfober NO'ftIDber Decembel' Compcl1lD.d (tOld) (tOld) (tal) (t8Ils) (tOBj) (10-) (tal) (ta

.. ) (tellS) (Iou) (tons) 

### ftft')
".0219**4'.~** 

### 36.6941 30.4142 29.1182 21.9]64 21.1341 29.9903 

### 29.1292 32.1934 47,S$16 1j.7632

### fN~ 239.6150 

### 169.5119 H4.8OI9**143.374~** U3.OS19 l1S.49G4 In.74.56 

### 139.1327 74.4'23 147.1116 

### 164.2769 2IUS43 

# so: U.4S60 1.5.410S 

### 13.1309 13.1006 14.2163 12.8130 11.1704 

### 12.6S09**12.6'11~** 

### 9.0734 1.1529 

### 10.7906 NIig 

### dmiD& SNC1 

### Dcrtmti1u 1 

### NliJ dariD& SNell OpcnIiQllll 

### Tota1:N':a. (SNCllDo'Wmlme 

### +**SNCR~)"** 

### CO

NO x 

### 2..5759 41.9135 44.m4 

### 34.0232 34.7371 

### 37.9218 31.4992 39.1091 

### 33.2927**41.209~** 

### 39.6677 0.0000 

## SO: 9.2299**1~** 

### 1&7.1334 i76.1469 

### 207.77S3 171.3272 

### 1:26.4267 92.4411 40.3&156 

### 93.4318**~3.7097** 0.0000 0.1263 

## 7.am 12.4697 14.0540 10.4221 13.3141 13.38" 16.2114 14.861S U.5943 lUOl5 

### 0.0000 

### cl.cug SNC&:DownIime c duriDg 

### SNCR ()pendoA. 

### Total (SN:R. Dowadme 

### + SNo. Openl:ion) 1/ 

## co

61.4612 

### 34.419& 41.2'39 3 S.23 

## so 34.1334 J9.994j 

### 3'-'OSO**35.~** 33,3527**4~.123g** S4.5&07 

### 90.9611 2073375 llO.2m 

### ZOeS.6946 145.3439**124~934** 

### 109.0122 96.6304 9O.S2S6 

### 47.7197 141.1997**99~73** 

### 189.7531**so~** 1'.9931 6.S613 11.1707 

### lll133 14.3869 16.3091 12.S3'9 14.4.164 ll.9306 

### 9.3414 5.02J3

. 

### 7.0113 

## co datiDa SNCllllowJl.time f 

### N& 

## cl'IriDI SNell 0paraIic&. Total 

### NH, (SNCR. Downtime'" 

### &NCB. ()poration) I

CompGaJUl

NO. NO • NOll. 

### NOs 

### lOa CO

Caladated 

### ADuI 

# Emisu. 11'

......... (lbltoa 

### diDkr1'1 

### W 3.01**J~** bIiaioas AaBall1 

### OzoaeSeuo.· (tpy) (lblday)

456.&3" 

### 1,603.0717 1,1'&..4710 1.673.3630 146.4290 197.9185 2.914S 4.1314­ 

### 10.9767**a7_834~** 

### 13.1912 9L9702

3".2491 

### 2.41'.9513 1)41.2947 

### 1,6S4.69U 127.1345 933.0OS4**1~50** 1.1133 

### 12.0714 102.lj6j 

### 13.3264**103.26~**
54L7S7S 2,402.6511 1)"6.44'1**6.438.~16** 

### 139.6561**~O.4641** 

### 2.6700 L61U l2.9899 109.9304**1~i.fiS9.9** 111.6130


### t.384-Bm 6,495.68U 4t71'.2171 13,'T4'.7Ul 

### 413.%196 i,671.!180**4~1714** 306..1530

a MoDth1y l:EIDniou m: ob1:siDed.fi.um 

### CoDtiImous Hmis:sioDs 

## MaDitmiDi (CEMS) data tepQrtI. peranaD &am PnmcBao 

### PiDm. Ash**Gm~** to Anacel**M~** Trimly c:o-dtallU, dllllld JCl'lW)' 30, 2009. 

## or C»D.OIlia (NH,).

11 

### P

.. TCEQ 2001 PmissioDs 

### lDvemmy GuiddiDea.llG-360A/D8 (JIIIJBY 

### 2009). tba 0ll00e RISQD is 1i'om .hmc 1St**1brouP~** 

### 31st,. 

### hdusift.

• Ammrncia 

### ClIIliuioas from tbe 

### l::ilns baed CIIl aftila'b1e Uta 1br CDlcnrla 

### ccmcaa1rIdiou tmd slide flD,n ad 

### w.. obUiMd. 

### hm FrmciEco PiI11D from 

### AJiJ. 

### Grove: on F.cbtumy 10, 2009. An 

## -venae hourly ammODia 

### emiai<m me WIS ca1culmd iRlm 

# em pmmi'**soees.'~** mel &'VCrIF 

### kilD-steeJc 

### 110ws to 

### develop the 

## m1lDwiq**.minon~.** 

## i <::EMS am <:EMS 

### dal

. ­ 

### wJMsa.1Cila 

## wtaa lG1D


### was opcnied gpenad alldSNClt lIDdSNCR 

# t\sh GYO'le

- --ZOi)g

w.m wesJJlOtm opcmtion 

### opcraticm (IMlr) (1bI! 1 4.2 1.7 

### 1 4.4 1.1 4.9 

### 2.0 

# No'j. $1)2

# O\~'n~~**Q\\~**

Ash 

### Glow Teus. LP. MidlotbUm 

### Plmt 10131 

### Trinity Consult.an1s

### Asll Grove Texas. 

## L,t>. " Midlothhm 

## PIRnt

# Ed(M.r2~ 2009 AduRlll:missiou Rnte 

### Calculations I(&]ns 

# ;
( Kiln Bonn or OpeJ"otion nmJ**J~lIrticuJ"tc** 

### Mollel' DIr;C,.lbut50

.. 

# \ FIN

2 

### 6**l~** EPN

C2. C6 Cl2 CIN



### Kiln J KiJn2 

### Kiln 3 99.10 CJ'),1tl 99.10 COI1II'\lI Krric[cncy

PM/JIM 

# I'

{'Yet} 2,\76.() 1,996.4 

### (l.n 114)

.... 1 of Ollcrarloll AnnuHJ 01","e Semlon (111'111') (J

... /Ol'.one sC2lson) 

### too 100 IOU Plu1kul

.. tc 

### Matter OislJihutlun" IJM I'M..**IJM1.~** (%) ('Yo) (%)

• P.rtiC'lIlatc mnller dlstl'ibulionllcolahlCd rrom AP·42.**S~lUll** '1 ,G. TnbJc I 1.6-S, (Janullry**19')~).** )(jIn Clinker pJ'oduelion

FIN 

### ErN <.1N 

### Deler1lllkln Uiuker Prod_clion Annuli O7.ORe SCIl.IIl (tp)')**(tol"'~n)** 

### 2·t 2-2 2-3' 2 6 12 C2 C6 Cl2 Kiln I Kiln 2 Kiln 3 211l.1I611,() 226.117.7 101.077.3 10.215.6 71.SS0,9

0.0



### Kiln IJltl·ticulatc.MnHcr.**H1SO~11I1Id** 

### Speciatcd ComJlound 

### R.mlnlon Cllicuilltion. (Stllcl, Test Oata nd 

### Mass 

# n"'".rc)

1<11113 (FIN: :Z-3. ErN: 12) Kiln 1 (FIN: 1-1. EPN: 6) Kiln 1 (YIN: 2-1.**I~J)N:** ]) Ernhsioae Elllilclions Emi.!lslnn 

### Emililioru Emi$.orioft**Emf~sioflll** d F'lClor

.... · Annultf 

### Ol.one SealiOtl,J, Fltdo

....... Annllur' O¥(lDe Seftll(lJ1 ,t If;Klo(!"**AI1I1UliJ~** 07AlIlC**S~I\Ill"'''''** (Ill/lao diJJJtt!J')**(~I),)** (IMlay) (IJft(ln clinker) (tIIY) {I bid a)') (Ibfton clhlkcr)**(I(l~')** (H.fd"1) (1.16**1~.877~ 1"2.~~7J**  0.34 3R.1UJO**2~,27H) (lA~**  22.91n O.OOCH) 0,13**13.4~9** 121.42K1 0.29 ]2.4071 242.4809 0.31) 19.11KOI (I.DOOG (l.W 10.16/6 91.4281 1122 21\.4007**11Q.~7.H~** 0.29 14.6673 O.(X)(lO

'fut.-l l'l\rlicuhdc MaUel' U.R115**142JI~'1J** 38.11(,0**~1?16** 1:2,9J7;**O.CX~** Sl)ech!.1cd PllrUcu1aCc Mnlter

I Obl1oll clinker) (tJ)Y)**(Ibllln~')** (lbl!Qn clinker) (tpy) Clb/.IY} Cllll1ondlnhel1 (CPl'. (I hM l&Y)**J.32E-O~** O.IlOIJ 0,0119 !.Cl8E-(l5 0,0012 O,(lCll)l 1.2(JIi-U5 IUXI06 O.(l()()()**An1j.lon~** 2J1)ll·(J{. O.O()[Yl OJ)l1l9**7.~2R-C)(i** D,{HJ(]i) O.ooM ".93E·(16 (I.Ollell O,llfll)() ArlSCnie 1.6.HH)() O.(J(Hl2**n.r)(ll~** t.89E-06 

### n.n002. 0,0016**J.9(~-()6** O.()('IOt (J.(X){IO IlcryJllunJ 1.91fAl6 CU)()U2 O,lK1I7 2. I 7a.(N') O. OOCI 2 0.0018 3,47f.-(J(1 CI,0002, (HXIOU ('ndmil.n 1. 92E-U.5 0,(102') (l.OUA 

### 9}.Hn-o.s 0.0108 a.ORll**J.2~6-()~** CWOO6 O.lIIO() Cobnl( ChmltlJ\lnl**1.66I!-(l~** ()J)()I7**().()I~O I.Y1F.·C)~**  0.0022 0.01(;2**J.74E'()~** l),()()()lj (llll(JO 2.20E-05 O.mJ22 fUlIlJ9**3.1~6-0.s** 0.0042 ().O311**3.1()6-0~** (1.0016 O,lXI(I() Lelld**6,28E-O~** ().()()(jJ**n.n~GR :"~J~-{)4**  0.0399 0,2987 l,27E-4)4 O.OU64 

## o.nooo MangmlCsc 

# \S 

# i

1,12.I!-OS ().I)() I I 0.0101 5.2(lE·()S O.OOS9 CI.()4-10 J,37B·Ol O.O()()7 O,lXlOl'I Nickel**4,2(~-O~** 0,0043**O.U3~ 4,I~E..()5.**  0.0047 0.0354**1.1()6-(l~** O.1I0f)(j U.OOf)(l IhSO, Selenium C1.09 8. 8M3 79.7743 0.06 6.2:193 46,(,847 0,10 

### 4W15S f). 

## noon**?',9~%** 6.3097 4?1121 ".917S 

## n.oooo 

# J g (I blUm**~linlie** .. ) (tl)Y) (lb/dny) FOI"IQldehyde (lb/tlny) (I hit on**cUnk~** .. ) (tllY) (lbIdftY) 1,02E-02 1:0,..54 9.2261 1,!(;}!·02 1.3119 981W**2.J1~·02** LI()74 (1.00011

# -~ Benzene 3.(,JE-(lJ O.J.M!)**3.2~4** 5.1JE'(13 0.j8112 ".34IU 1.I12E·02 0.5155 

### n.oooo 

# _. 

# . 2A2E-04 O

.. 024J O.ZIH9



## - h 

## -. 4.42E-04 00223 Cl.OOOO SlyrOllc HI h)' I**Bcn~CllC** :1.63[-04 U,O:tM 0.3283 6.49£-04 UW34 0.5"92 I 33g·03 0.U672 f1J)(l()l) TohlCI\C 1.33[-03 0,1:137 1.2(00 l.nR..i13 0.2001 1.4?1R 3.39B·O) O.t713 [1.C)(IQO**.n.,)~Xylcnc 3.01~·04**  0.0:105 OZ',,, I 5.31H-04 OC)(,o1 (IA4!») 7.J6E·04 0.0372 

### (I.noon

Totlll 

### SIJCdalt:d VOC**I.'l~ 14~38** **l:12..,~** 16.6533 J.981l!> 0.0010 (it)]')**(lb/~l'IY)** (Ibf1on t1inl4u) (tp)') (UlflI t1Y) 

# s=.



# . •• tt**O~R10** 4.3918

__ h



# ­
Ki1l1 Mercury Compound Enlissic"l Calculations (using Mus n.lll.cC!: AllIH'(U1Ch) «.llY)**(lb/4a~)** (t1)Y) (Iblddy) (tn,,) (IbidA)') O.OO9H n,U1J1 0.004'1 O,C100U MCt'Cluy (tdill)f (I.()[J87 0**()~2** .tl)1) (IbId I')') (jlly) (lbldIlY) Mertlll'y (¥:lpor) OJl085 U.07()() Mcrcul'}'SllcchltiUI1**(~** • .)'

... I**(tl)~')** (!bfdtl:Y) OJlll9Ci 

### tW71G 0.000 

## o.uooo Mercurv (PM) 0.0002 Il.OCIJl) O,om72 O.OCH's ().OOOl 0,("1(10 Mcreury (PM I
.. ) O.O()()) tlOnl3 0.0002 O.OIH2 O.OOlIJ U,llll(H)

ft nlUissiOl\ f"ctof's for PM nnd**I·~SO** .. nro tbo avor!lgO hm

.. l)' omi.o;sions blod ckJrlllU the JUlle 

### :m. 2tl03. tp July J. 20113 swelt**l~~** pcrronllcd 

### by MlITCO lrnv1rolUnclllnl.

Per '['CEQ l"CqI.l()Sl, Avcrago hovd)' PM and H 1 S0 4 emlssiou f"cton are eoKYcrtcd kl -lbIIOll clinker- \Ising Ihe daily clinker- prodllCliClR 'UlIiSlios. obtoil'lccl from DDily Operating**~cporl'** ()ORI) fOllbc duy whcn SUlcI. ICSI$ were**pcr~.cd** Enlissian raelors rOl' 

### PM III 

### and PM 2 Are bn!;C(J 011 

### A 1'-'1 

### 2 p.lrli,aI

.. tc 1l

.. 1UCI· djslrillllliOl\$

to P.missiOfI**riIC~tors** ror spcc.ialcd PM and VOC**~ompollnds** 1lJ1d 1·1CIIl1\l11IC IbItot, clinker v.llnes from March 20()J M ACT SubpilJ1 L.LL compliance tests cxccpIIOrClllis$i<)1) fnctol"li (or'spocialiou ortOCalIllCl'Cll1)' cMlinions. which nrc cstinll(cd vfthlCS

• For (Joulld per hour (lb/hr) cmillSlon fn(>[or; Anl\\1il1 Emissions (ll'Y) r.;. (nmt.o!;*ioM FIIClor'llblJIQurj) • (AnnuAl 01)CJlUinS HO"fl 

### Ike/)'rl> J (ZCI()() Ib I 'on For pound I'Cllon Clinker (lMan clillkCJ') cmissi!)" Ii,ctar; AnmUlI cnmsiol'-' (t]1)')

.. (limhsion JltlClcr llblton clinker!)

... (AI'llUftl Clinker I l rodllc.lion I(py\) I (2()()O lb I too " Per TCIrQ 21111') RMlillliioll& hl\'Cl'llOI'Y (1\liclclinCfl.**RO·:16(1N~)** (lanury 2(10), [hC(V.(lIlOSCRSOn Is from JullO Ilhl'Ollg1& A\I&1Is13I, i1lClnsi,'(

• Fur pUlllld 

### per l1(lllr (Ih/hl') cmission IiIclor: OIDJIC ScnSIDallmi$slollS (lbltJ.iy) = (EmilOsloll Factor Illl1l1l'1)·**(O~IO** Slxlson Opcrl[ing Hours 

### I h rio 1

.. 01\0 SiCASOI\l) I {l)1 duy IU/ono 5011501 POI' pound**p~r** (Oil Clillkor (lblto'l4;lin!tc" emlssiou [bctOI' (}r.onc Scnson li,uill.1i()l\$ (IMlay) n (fimisslon FACIOI' lib/lOll ollcltcrl) • (0'01l<: Season Cliukcr**PI'OCh~lion** IlOll/lT/.ono sensan]) I (92**d~'** I O"/,Ol\C**lC~r** r The loral merclll)' clllission JR'e from AIIII\I'OC kilns combinc;:d is cslima\Cd til Ihc Mili1u[hi"n plnn. using n maIlS balfll\CC llPl)ronch. ll'l order to**dol~I"RtiIIC** U,c mereury cmisslolls rmm CIICoh kiln,**U~** loh&1 mercury emission rAte IS proportioned oollCd on clinker fIOd\\ctiol1 rO!' each kill

I Only Iho nlOl'(>lll'y cl'IIiuk>nm 1blare !IpCOia'cQ Il! IJM (not**tOlalll~l1ry** omjsslDllS) cQllllllowar<! dlC [mill**~iAled** PM CUlissl(H' 10**~lnl&liol\s** i)'Dlll IhcIC J)(»)JI1IHIII.!; \Yera bola\\' delcClion level. t\uri_e die Mnrch 200J MACT SubpArI 1.1.1. oolnplial!cc test!

, Spocifllcd ftlClC\ll)' V4Ipur a.d nu:rcnry IMllticul.lC p<lrWlllAjlc (Of ",at kihlll n1'C ohtained fI'O'" l'ortl:ll1d Coma.l AlIsoeiaciou (peA) rcsclH'cllllld dC'YClopn,cml dOGl.ncnt CO#lpilal/tJt'/ ulMr:rcllry Hmi.rsin/l.li })(ff(I. Flgtllc 4-17 (MerolU)' S\XlCiRlioll pcrcel11c1lJCS

.. i\wragCl far ftllliln l)'pcs), PCA R&D Serial No SN309I. Ma)' 20l)(), Per r:iQlll'C -I-I? MCfeury spcoimioo rorwelkllns ls liS follows: Mcrcmr)'**(1n1~lc** bOl.ld) 

### =- 2-4 Mercury (oxidiud)

.. 14% Mercury (c1C1l1cnlnl) => H4% POl' Section 2.3 of Iho peA dOCllJllul. pnrfi¢lc-bO\mcJ mcn:ury il> Ihe \llcreury d\i\1 hnl ct)J\dcnsc:d 0,,10 l)ilrliclll"tc maUer. tmd clel11entlll mercury (Hg') and 0;0; ldii'.ed mercury (HB1 11 •**H~2** ') cQllIprisc lhe vnpor-pl)El$O mereuI')' Il is r'r1her ossunlcd lhfll**K~%** or**ro1~1** parlicle-bound mercury C111issiOll,:rrC 

### 11M." based OIl Ibe t1i6lribmioll betwoon PM and PM",**n~vro,"dcd** in AP-42,**~Iiou** 11.6, Table 11.{)·5 (J.mo(lI)' 1<)l)5) ror,,,ct**~ililscolllrull<:d** wilb nil 

### nsp

..

Al'h OI'O"C 'l'c:'(ns. l.P. Midiothillll 

### Plant**~oD2** Trini'}' CcmSlll14111S

# ~bl"\\~ 

# vJl E 1lQ.,

Kiln NOv 

## SOl1 

# CO Emission Calcnlations (CEMS Data)

FIN 

# EPN DescriptioD 

### Componnd**JanIl~ry** 

### (tons)

2-1 2 

### Kilnl 

# NOx**S~** 

# CO NH:; 71.4137 124.4198**~t9852** 

### 1.6730 

## February (tons)

51.5508 109.5844 8.0339 0.7842 

## March (to 115)



### 0.1957 0.1813 0.0961 0.0042 

# Ash Grove Texas, LP.

- Midlothian Plant 2009 Actual Emission lUte Calculations

- Kilns

April (tons) 

# MAy (tons) 

### Monthly Emissions**J~e** 

### July 

### (tons) (tons) Aupst (tons)

0.0000 0.0005 0.0000 

## 0.0000 33.1907 31.7892**~.6507** 

### 0.4772 55.5762 

## 85.3661 8.8647 0.4935 50.8178 

## 171.0505 10.5824**0~631.3** 

## 49.4072 129.1900 10.5805 0.7183 

## September (tons)


## 45.1982 71.1724 7.6274 0.5672 

## October (tons)



### 43.3138 

## 129.3613 6.4139 0.3406 

## November (tons)



## 173n4 64.1520 

## 28689 

## 0.0979 Emissions 

## December Annual 

## Ozone Season b



### (tons) (tpy) (lb/day)



### 0.0000 424.0413**3~86.9793** 

### 0.0000 

## 9162675 8,382.7522 

## 0.0000 67.7034 652.7717 

## 0.0000 5.7873 40.0658

0.0000 561.9725**4~041.7533** 

### 0.0000**1~153.m.3** 

## 10,413.4174 0.0000 68.9661 S58.7609 

## 0.0000 4.0538 28.9631

0.0000 279.4924 0.0000 

## 0.0000 626.3706 0.0000 

## 0.0000 38.1408 0.0000 

## 0.0000 2.3301 0.0000


## N0 1 

### 1,265.5062 7,428.7326 

# SO:z 2,696.6104 18,796.1696 

## CO 174.8103 1,211.5326**~"H3** 

### 12.1712 69.0289

2010, except for ammonia. 2-2 6 

## Kiln 2 

## INO:'C

2-3 

## 12 Kiln 3



# IT otal 

### Kiln Emissions



### FDl

2-1**2~2** 

## 2-3 

# EPN

2 

## 6 12 Description

KIln 1 Kiln 2 

## Kiln 3**SO~** 

# CO NH;

IN0:'C SOl 

## CO 

## NH

3 

### 0.0000 0.0000 0.0000 0.0000



### 88.7643 

## 148.'7380 7.1782 0.4841

edentate<! 

## Annul Emission Factor
(lblton 

### Compound clinker)



## NO:ot 4.22**KO~** 

### 4.97 

## NO" 5.53 

## 47.2372 60.4577 57.2380 64.3166 58.6683 59.5534 67.6990 425920 

## 59.4640 44.7465 76.3148 158.6943 176.9801 68.3023 94.8490 197.3927 186.7755 48.2125 106.8741 39.5770 

### 4.7556 

### 7.9994­ 6.1893 8.8445 

### 7.5594 

## 9.0036 9.1399 4.2931 5.4350 5.7462 0.5514 0.3966 

## 0.3491 0.6781 0.4058 0.3626 0.5639 0.2160 0.3905 

## 0.1397

36.1536 

## 68.2977 62.2130 24.0639 0.0000 0.0000 

### 0.0000 0.0000 

## 0.0000 0.0000 

## 633526 213.9722 

## 161.8989 38.4089 0.0000 

### 0.0000 0.0000 0.0000 0.0000 

## 0.0000 3.9753 

## 11.1S88 11.6212 4.2073 0.0000 0.0000 0.0000 0.0000 0.0000 

## 0.0000 0.4178 0.6233 

### 0.4580 

## 0.3470 0.0000 0.0000 0.0000 

### 0.0000 0.0000 

## 0#0000

# ~~**~W'!l"** 

# tW1 }tQi bQ.z.**VY\o~l~** OJ')h\kL0

<1 

### Monthly emissions are obtained from Continuous Emissions Monitoring (CEMS) 

### data**repo~** 

## per 

## email from Fnmcisco Pinto 7 

### Ash Grove, to Cutis**DeVore~ T~**  

### Consultants, dated January 13 7



## Ammonia emissions are calculated from ammonia CBvlS data, 

## stack flows. and 

## kiln uptime. and 

## were obtained from Francisco 

## Pinto from Ash Grove on 'February 16,2010.

b 

### Per TCEQ 2009 Emissions Inventory GuideIines t 

### RG-360AJ09 (January 2010), the ozone season 

## is from June 

## 1st through**A~oust** 

## 31st, inclusive.

Ash Grove 

## Texas, L.P. Midlothian Plant 7of32 Trinity Consultants

### Ash Grove 

## Texas, L.P.

- 

## Midlothian PIRnt 

## 20ro AcluA]**Emi~~jon** 

### Calcu)ntiuns

- ((ilns

Kiln lIoun 

### <If Opel'lliion And**P~I'1IC11lnlo** Matter I)istrlhution

FIN EPN CIN Dt.\.,cnptllln II(lUrll( lf OIJerlllll. Cun(r(IJ**~rnelen.:y** Anl"O\.I**Oi'.(lllIlSCIl~Ol'** PMfPM 1D (hr/yr)**(hrfo1.(~ac** nll$un) WI) ''I,rUaII1l1l\ M.t10J·**J)i~h·'l,u'inl\·** rM PM 11 J>M u ('Yo) ('Y

.. ) (%)


### 2·J 2-2 2-3 2 t'i l2 (;2 ell (;12 

### Kiln I Kiln 2 Kill13 fl.(127.8 (,,257.5 "1,7UO 1110,5 1,'l"1l.7 2,I<i2.1**<)l).~2** g),k2 9'J.B2 

### Ion 100 100 85 85 85 ft4 (.4 (lit**1't1rti~lhlle** ITl II lie..

.. dilollrillullonll**~I"l:linud** rml1J AP-tl2, Scclion J l.rt, TLlbk: II**J;~5,** (.IBnLMIry J 995).



### Kiln Clinker Productfon

FIN Rrl"t ell" nCIlt: r1 I)lliJl1 CHnker Produc.ll0. ·AIUlllld 01icM10 SU,.lIl (II'Y) (lonfsoMII.ln)

2-1 

### 2-2 2-3 2 (, 12 C2 

### cr. C12 KlIII ! Kiln 2 

### Kiln 3 221.140.8 2J-4.917.() 172,631.1 15.0102 72,944.3 n,452.l

Kill' PRr1iclllflle Matter,**H~SO** ... IU1[1 

### Spcdfltcd CDmpound Emiujon CnkulttljoAs (SlAcJ( 

### Test nAt" And**~f1ass BRliu1(~e)**  KIIIJ! (FlN: 2--1, lSPN: 6) &ml""ion. AnllwKl' O,.one Sel'lu

... ·l,r (lp,.) (lh/4Ia)')

56.3K50 31«).5190 41.9273 32JA92 I 36.0Kr14 2J\l5105
56,38.."" 3ICOS79U
(Ip)') (1111.11\.)')**O.O()I~** U.OOHli O.lXX)9 0.0061.1 0,(002 0.0015**o.ro:r~** (l.OOI?**(H)11~** n.07(ll1 O:<XJ2.2 O.l1151 ().l'l')44 tH12'n f),()1IS 0.27')1) 

### o {Xl(. I OJMI2 0.(1);\9 O.U3JI 64\f()? 1\3.1<124

f1.SS411 4<1.2364
(tpy) (lbJd.n·) 1.J(i2(. 9.1lJ'n 0.(,1:12(, ·4.0674



### _. 0.0762 0.5 1 

# "c. 0.2(1'19 1.40'\.1 O.<kI24 O.1\2W
2.3(17 15.61131 (iI'Y) ,"ttl;I)') n.(i)97 ·tI1511**(q)~')** (1"/dl'3')**n.{,()~2** 0.0(.2(1 (lilY) (1It/uIlIY) 0.0090 O.or.,(ll iH)(X)2 00012 O(W2 O.OOll Xll

.. 1 (FIN:**2~1, F.rN~**  2) tn.luloll EmbdclIlA !anlulun rllel

.... "'" hnmllll' O1.DllClSt\llslm d ,r JlIIdo 

### r"'"
CllnlJxlullCl k (lb/lo(l clinkcl')**(Ip~)** (lll/w..)') (lit/Ion cllllker)
I).4ft I·M Il, 0.2;1 2ld212 :n.52's5 PM 0.20 22.2(no 31.8%1 0.41 I'M

._ 0.15**1~.711()** 211.0)()) 0.:1'

2**T(lh.II·I\rllul.C~** Mlllller 26.l212**37.~1~-;** (Ib/tnh clinker) 

### O

.. y} (Ibid",) (l1N't(1n**clilJk~I')** Spec.l'cd p."'t:ullliu M.Uer
1\I\ti,n[)l)} U2E-OS O.OOl5 0.0022**t.OKli·O~** Arsenic HI'JE-06 O.OCK)2 0.0003 1S2H·06 I Rig·(lCI O.(XX)2 O.n003**1.1C9I~·06** Bcryllillm 1.911!·O6 O.(U)2 O.WOJ llm·Ot1 Cbmflliun) C",ltl1illln 2.921WS (J.(X>3l (lOOlfH**?.sRl~-n.s** IH,E·()S 00019 

## o.oem Cobalt L91H·OS LcsKI**2.2()1~-()S** (U1"l25 (l.Il!!.'\" PSE·OS Mangllncsc**(~2~E·05** 

### oem I 0.01(12 l..SJE·04 Nickel 1.121W5 (lmJl**O.ll')l~** 5.20lW5 Sclcl\il.ll**o(.2(,I~·()5** O.f.04M UJI070 -I.IRH·OS**H2"~O** ... (L()(1 O()t) ICIOIM**141~<)5**
ToilJI**Slled"le.tlll.rCh~lIll\le M"th~l.R**  10.0396 1".42.10
(Ib/lclll clinker) (Cpy) (Ill/lillY) (lh/1D1\clllll(rr) "'lIll1Jnlochydu S •• ed'lll!l' 

### voe U)2E-02 I. 1 5Xtt 16M2 I 16E-02 Iklli'U1': JCl3B·OJ <1.412J 0.5921 S IJI'.-O:\ ElhVfllcll:rollC**2tl21~-Ot1** O-f1215 OO:lt)S**J(.:11~-()4** 0.0412**O.(~lJ2 ~Incne** **6.491~·04** ToilICnLl IJ3F·(j) Ol5W lJ.2J70 I 17IW,\ 1Il.1,-Xylcl\c**5l)1~·()ol ~.(lJE·()4**  (J.nJ44 O.(}494

Tohtl**SP~L;iltcd** VOC 1.8148 2.61J('**~n** VOC Cl)fll()oIIlHI fib/COil dlnkllr) (1Ilv) (lblt'''Y) (1hlton elllllccr) IIy dw f.l. cl1 C'hloTiIJc ]J.21':-{)2 I.HJ98 2.M31**S.Il)I~·m** 

### Kiln Mercury Com I)Olmd HmissloJl Calc.lntiolls (using 

### M nss lJltJnacc Appl'oac:h) '(lpy) (lJlIdlty) Mcrc1lry (lUIIlI)' O.OOR9 lUll 27 MOI'tur S )«falloll (uf,)r

... i (lilY) (lb/dllY) Mcrcmy**(Vll(l(~l** D,OOS? 0.0114 MCI"ClIl)' (f'M) (l.()()O2 OJlOO:l MCl'Cln'y(l)M Il, l GlXXJ2 110002 KiIDI J (fIN: 2-3,**~PN:** 12) Krnb!lclI. EmJ!5ltll1l Jl"dnr",h AJU\llltl t o-'Aloe SDlIJlDn'

.... (1Jlilon clinker) (1Ily) (lMJ •. ,,)

0.41**J~U1l94** J-45.167t1 (1.:\5 ;lOJ)fW1 293 J 92.1 0.2(, 22M92 220.')07)
3f\.3tI'.J**:W~1674** (Ot/lon**d'hlu~r)** (tpy) (Md.y)**I.U,}~·05** (looll OJ)jOo

4.9JH·06 0.0004 OJJQ42 1.9(,J.!.·..()(' 0.0002 

## n.nO]' J.-47H-06 O.lIOOJ "(10029 I 251l·0j 0.11011 MHOS I.HIi·()S 0.0015 O.1l14(,**lli)l~.05** n.Om7 OOUiI 1.27E-M o.O}W O.I()IW 1.J7E·OS 0.0012 OnllS tinE-OS ()J)()09 

## o.nmn 0.10 HAR0'7 lC2.7\53

8.5012 81.9149
(lM"l tlil.kcr)**(lll~)** (JblclAY)

231E·[)2 1.9919 19.41172 1.02E·n2 U."X!«ltl 85871 4.42E-(14 OO:l1i2 0.:1721 1

.. \:lli-tl;l 0.1148 I.lllJ7 3

.. "-)1:.-0:\ 0.292(, VlS39 7.:\("!-O1 O.()(';I;,) O.fll%

J.JS34 32.9!J96 (lb/tl)tldinlull') (til)') (IMln!l

.­ J>



### . ..h**(tr~')** (Ih/dlly) 0,00(\7 ()()(jSM (111")**(1b/d"~l** O.OOM 0.0(-45 0.0001 0001:\ O.(lOOI ().OOll

• Emi:l.'1lt'ln fileII I I1lI(\("**II~SO~** ("II kiln:c) arc lhe II.,.cl1lga hlMlrly**omi.~~i(lll:lll<::ltcd** during the .lnly '.].2(0). i\talOk**lC8l~** ]lcrfonnoo by MBH.:O Im"it'nnltl(Jnl:U. Tho cmi:\oUon flllO(UT rUT PM ror Kill' I il'llmllUll OR Ill" J'nmt·bIlU' I·M umis:till •. (Ciled dlllill!'-.hu**.~cmhcr** JO, 2(IIO.lIlrKlk IUl'l151"K:!"(lmlcJ by AiT SAUIIpi intt J\.<;,'\OIl)llllo-:' umnhillul WillilblJ bn!Jk-hllll" I'M

...**'lnj!l~icll111** (cllical

.. \cd**II~** k>l.l PM**CUli~it1tllC** minlr< l'runt·hol1f**cl1li!t$lon~)** IUilccl d\qlftK the July I. 20tH. 3IJd: k.'l'Il1i rcrfum,cd hy METeO l;.l1Y;"lnlJlcl1\ul Thc{,'U;k.'t.lO'1 f"ctm r'lf PM rllr Kiln 21K lhc**llver;I~'C** !If,lurly \lmi:t!CKlflIC l(lSloll dl.·lnl1 Uw Ault\l:( 2S.**201()~llCk** tu.o;( pcrf'('f1l1ocJ hy METe() Hrlllirlllimunlill ThccmlH!licm r.ctflt lhr PM rot' Kiln J ifol bal'iCll mllhe**rl'lIll·hall·I~M** ClnislI![)'u**l~lal (hllill~**  Ihe**1"~brual)1** ) 1,201 I,lllllet ie"" pcr{onllro**b~'** Air**~llI'lCllblg** AStitlclulCll cmllhilllXl \¥llh the hCll:Ii.-half PM 1X111l'.io.}IIS (cllkallliOlI :l!c lulallJM cDlhailXlJl nlill\l.'C li·olll·b.lr**CIl11.k~lo11ll)** leoctul dlllinB the July .1. 2lJ()J. sttlGt**IL~~ 1)~'rnn\1cd** **h~** MHTCO Ellvirll!lIllL-,ITtll 1 1 01' TChQ**r~(jl1c~l. 8WI'H~**  hl,.rty ))M 1"ld I hS04 cmb!Uoll r"cl.ors II'C cO)l\'crllllllo ·IWton elh)j.:cr"**lIMil~** lhe daily elinl:"r rrl.ldu(l4j(}n**~llltill\i~.** {thlninod ('roJD Daily**(}pcrlllin~ Rcroo~**  (DOR

.. ,) rOT lllO (lay wIlen 9l:ack**l(,'j,1~** weI'\} IlUrfnnucu.**Hrni~ion** litClI(1r,; (or PM"mul**PM,~** llro hll!lOd (In**I\P-~2 pllr1Jouf.t6m"lIul'di~**  .. tfihllh(mll.

to**1~n1i~~ioll** fllCtOI'!\ 1<11" lol[lCCillled l'M mId V(X: ClOOlpl.lllWds lind IIClllTC lbe llYlon clinker**valuc~** from March 2ll(l1**MAt~·["** .'iltl>p;lrl 1,1,1. cllf\lpli;mcc**lc.'!l~.** c:-:<.:cpt Ifl!'**~ni~<'l1** rllck.-s f(lr**~"lOCillh(1II1** (II' lulal**fBOI"CUJ~ r:ll1is~i{lnlt.**  which arc csLiJlutcd YIIlUClt

• J'(1"11(111Iltl pl.'f boor (Ibllll) clllislci(lll**(M~lur: AnnUl~**  1**~nil<.'Si()ns** (lpy.) = (I**~1Ilir«i()n** FllCltll·llh/],()url). (/1I1ll1ll1l Opcr.IOng**110l~** IlIr!)'

.. !) I ChIlO Ih I fl'll:

F(\I'!lI.\UnJ pea" lUll Clink<.'I' (lh/tun**clin~c.·)** Clllillf(\llll (:K:lur: AllIIU:.) Emis!\inO:1 (Ipy)

-**(1':m~(1II1** Fadm lIn/trill ditlkcl'l)

.. (AtI1l11",1 (JinklJr Prclllllelil>11 lillY J) J (2(XXllh 'Inll d Per TCrlQ 2010 Hlnil':!tinllH ItlVCIlluC)' HllidclinL'2l, IHI-J(tlJA!lO(Jmlllllf)' 2011), lhculI'l1c**MC:t~1t1** h(**rr()lll.l\lIl~ 11I}]'(lU~1I**  A_B"Hl :11. illclllsivc

4 h'r P'lI11d PCI hour (Ih/hr)**Cf11i~!>ioll** (lieu: (}J:onc SClIIun**Emi!C!iioll~** (Ill/da}') 

## = 0 imis!lioll l/ootOl' Iltvhl'D " (On\JIc**SI,)II~(lft** OfUolill{\ I lOll,... Ihrlt'

.... )llC xenoJl I) I (92**<.I1l~'** f tr/,unc !l1.:lI:W,lll:

]inr \ullld por lun Clinker (1l>/tun ulilM;l.:r) cll1)slIin'lliK:lur O/lll1U :-loR!iOn**limi~tlllS** (lh/c1ay)'"**(E1.i~~jnn** Fllettlr liMon clintcrl)· (OZllilC l-ie<lSUII Clinker Pro!lllcilon Ikll1fa/.l'll<:**~'~lnn** I ('n.dl)' IO/(lll':lIcn:oon

, 'JllC 1(11111 mcmmy**cmilt~n{ll'.lc** {mIn :dllhrec tilnli Ctltl1hiLlCd**j~** CHl.jlO"lC>llullhu Midluilliml plmll using**,,11l:1"~** halallce. :11)fll'llClch. 111**{lnk.'·I()dcl"l'mill~** the m':fel.'Y cOlisAiom.; rrom**ca~h I;,jhl.lh~**  1(11:11**)l~I'CUI)'** clllisKinll Talc /lcl'l't'l'l)rlionoo hMCd lIll elinl:cqll\tdllclion rnrcllcb Idlll II Only Ihcll1l2"CllIy**clIJi~sinns** lhllllln:**~1"kX)inttJlllt<:** I'M (oullolal mcrcu1)'**cmi!l~j()(l~)** llllol1lltll\':mllllc t01:11 !iPCCilllcd PM Cmilo'liion

It**hmi~~i()ll:lrlUm thc~.:** **Jl()l1lllool.~** WCl'C hf.:!C1\l1'**delccti~1Il k.'VcI~**  dorin?-lllc Morcb 2001 MACT SahpOll'lI.l.L l,;(IlnlllllllM:-C**lo~l~** • Spcci:\tcd lllL're\lry I'UJlllT mul mercury j1C1I1j(llJlil(C**11I;,.'f~mlaltc** f(\1 wet**Idh~** om: olllni.od film' Ptlfllootl CCl11C1l1**A~'!COa\lltlllll** (I'eA) rCiWSrrch <lilt! llcvcklpmcnl dOClmK:nt. Cr'

....**~';/rll;cJl' ofU~rr.I/')I**  f(",/.tJiOllV J.)cr/u. FiIU.'C 4-1/ (MCHlIll"r'**~"lOCjll(i()Jl rell;~Jlul!-c.~** **-{Il'c"ngc~** I<l!' 1111**killlly~),** peA H&n Hr.rilll No SN:1091. May 200') Pl:J'lo'igul'l:: 11·17. Mcn:UIY**:epcCi;lli~'fl** l'<.-wet**ldln~ i!l4l~**  l'tl]l<w.':c: MCRlnry (pllrtiQlo b,,.mli) = 2% M en

..

't 11)' (mddi/cd) a J4'!o11 Ml.t"QII)' (clcmcnlaJ)=**~4%** I'cr St.-ctillil 2.'\ oj' lhc peA IiOCUlllC'l'lI. Plll1iclc-hllUlld IUCruilry is Ihe**mCRl"~** Ihlll**hil~ C(lmlcl\~l**  tVlICl rHr1ic.ul:l(c rmliler. :md**cl"ll1~nlalll'~1}UIJ' (Ihi~**  lll)ll**n~)di/.ul** JnC,,",'f)' (f**t~~ ~1.11(t~·)CIJlI11l\i**  ... lhe**Vllll{lr'ptl;l~C** l1lCl\;ury. It i:-: l'm1hcl**Il~!'\lmcd** lhnl k5% of lnllli "articlc-b",uml n\CfCllry l:l\lIMsillll!f lire I'M)lb**h~L~'d** tlJllbl.: di:-&trilYulionllOlwC\:11 PM anel PM 1f1

.. IU'cWLllccl ill /'11'-42, Scr.;tiol\ ll.(1, T'lhlc II ,(i·5**(J;lnwIT~** 1995-) rll( \\-et l:ibt.!' lJ('uh't1/lcxl Wilh IIlI I**~~P.**



### Ash GrOOte TC'Ilfta. 

### L.P. Midlothian Plfl\l :'i 

# or 32 'friuity CORSlillanlS

# Ash 

# Grove Texas, L.P.

- Midlothian 

# Plant 2010 Actual Emission Rate Calculations

- Kilns

Kiln NO u 

## S0:2T 

## CO Emission Calculations (CEMS Data)

FIN 

# EPN Description

2-1 

## 2 Kiln 1

2-2 

## 6 

## Kiln 2

2-3 

### 12 

## Kiln 3

Total Kiln Emissions



## FIN 

## EPN Description

2-1 

### 2 Kiln I 

## 2-2 6 

## Ki1n2 2-3 12 

## Ki1n3 

## Componnd

NO x 

## 80 1 

## CO**NO~**

### S~ 

## CO NH 3



## NO x 

### S02 

## CONHsJanuary (tons) 

## February (tons) 

## March (tons) April (tons) May 

### (tons) 

## Monthly Emissious ll 

## J"Ql1e July (tons) 

### (tons) August (tons) 

## September (tons) 

## October (tons) 

## November (tons) 

## December (tons)

33.5323 

## 152.3534 7.7135 0.4016 

## 44.1461 169.4614 10.7627 0.4032 

## 48.1654 162.3678 13.9956 0.4458 

### 43.4702 

## 139.4419 12.8902 0.5720 

## 26.7770 135.8482 16.0617 0.9294 

## 11.8456 12.4844 5.7893 0.3486 

## 0.0000 0.0000 0.0000 0.0000 

## 7.4070 

## 29.5971 1.8684 0.1343 

## 48.6827 153.4941 13.1474 0.8255 

## 55.6257 186.5213 11.5784 

## 0.7440 61.7826 

## 172.9408 12.6943 0.5979 

## 12.4596 33.1387 1.4946 0.1197

41.4193 

### 141.4500 

## 3.8157 0.2265 

## 5:5.2806 214.9901 

## 8.1412 0.2050 

## 58.8246 217.8229 10.8744 0.2708 

## 30.7389 108.7478 

### 5.0453 0.5081 

## :53.7287 168,6355 11.1593 

### 1.5246 

## 58.6087 169.9477 10.9414 0.8476 

## 47.9426 158.6270 7.8354 

### 0.2905 

## 68.5754 208.3345 12.0485 0.4084 

## 3.4544 11.9739 0.9485 0.0390 

## 44.3540 140.4001 7.9300 0.3827 

## 67.4211 168.8753 10.5754 0.3101 

## 11.1839 36.9144 1.2734 0.0428

0.0000 

### 0.0000 0.0000 0,0000 0.0000 

## 0.0000 0.0000 

### 0.0000 O.OQOO 

## 0.0000 0.0000 

### 0.0114 

## 37.5299 100.5190 5.4950 

### 0.6141 46.0169 

## 125.2225 9.2289 

## 1.1085 54.3938 

## 125.4465 8.1196 

### 0.8821 

## 61.2836 57.4766 

### 10.9200 

## 1.4880 55.2865 114.8472 

### 11.9464 0.7556 50.2107 

### 228.3764 

### IS.8191 0.8699 23.0715 

## 136.7936 9.6604 

## 0.4437 25.7667 

## 71.6868 4.9465 0.5189 0.0075 0-.0570 

### 0.0817 0.0000

NOr 

## SO! 

# CO NH 3



### C2kulated A.rtnaal**Em~sion** 

### Factor
(lb/ton Compound clinker)
NO

x 

## 3A7 

## NO x 

### 4.61 

## NO x 

### 4.10 Emissiom Annual (tpy) Ozone Season 1> 

### (lb/day)



## 394.4941 1,407.6490 107.99:58 5.5219 

## 418.5348 2.219.1620 166.4696 10.4960



## 541.5319 

## 1,746.7191 90.5883 5.0559 

## 3.807.1011 11,671.9380 670.1152 33.6186



### 353.5669 960.4256 76,2174 6.6921 

## 3,716_6054**6~473.2674** 

### 673.6065 

## 67.9485

1.289.3929 4,114.7937 274.8015 

## 11.2699 7,942.2413 20"'-64.3674**1~lO_1913**



## 112

.. 0631

01. 

## Monthly emissions !L""e 

## obtained from 

## Continuous Emissions Monitoring (C&1S) 

## data report, 

## per email**fromMichaelCri:ttende:n.AshGrov~toJaimeBretzmann.Trinity Consultants~**  

## dated February**2~ 2011~**  

## except for ammonia.

Ammonia emissions are calculated. 

### from 

## ammonia 

## CEM.$ stack**tlo\VS~** 

### and 

### kiln 

## up time and were provided via 

## email from Francisco Pinto, Ash Grove, to 

### Jaime Bretzmmm, Trinity Consultants, dated 

### March 15,2011.



## o Per TCEQ 2010 Emissions 

## Invemory Guidelines, RG.360AlIO (January 2011), 

## the ozone season is 

## _from June 1st through

## A~ 31 inclusive.

# ~h**~w-t~** 

# - 2010

# N~'/.**S~~ o.'I\~ij.J.**  Ash Grove Texas, L.P.

# ~~ Midlothian Plant 

## 1 of 32 frinity 

## Consultants