Anllunl Hours 

FIN EPN of Opctltion" 

(ltr/yr) 

Xi/II 

2-1 2 8,275 

2-2 6 8,200 

2-3 12 8,178 

Raw MiJ/,i 

1-7D F-MBI 4.007 1~7E F-MBI 3.678 

Fi"i5I1MIIL'i 

4-1 5 7.635 4-2 9 8.015 

Stamler (CI'It~;III!')

1~24 1-24 1.222 

" Per Dc:cembel" 2005 "Yell.rlo Dnte OPBRAT1NG REPORT- for the Mldlolbian Plant 

h Pel" June 30,2005, July 31.2005, Rlld AUQust 31. 2()0.5 "DAILY OPERATING RBPORT" for the Midlothian Plan 

Clinker Prodlletk)ll 

Ash Grove Texas, L.P.· Midlothian Plant 

2005 Actual Emission Rate Calculations -Input Duta 

KIIIIl, Raw Mill, Finish MlU, and Cru,"lD~ Houri of Operatlo. 

01.onCl SelUon Houn ofOpcrRHonb 

JUlle July All~USI Total 

(hr) (br) (111") (1I1·fo1.one 3el\Soll) 

713 719 680 2,111 

716 741 733 2,190 

720 742 737 2,199 

288 356 350 995 

374 348 314 ••035 

710 702 6()B 2,019 

658 683 6&9 2.031 

369 363 348 1,079 

Annual CU.I,er 

FIN EPN Produetionu 

(tpy) 

2-) 2 313,084.0 

2-2 6 308,913.8 

2-3 12 312,915.3 

I Pel' December 200S ''Year to Date OPERATIN(] REPORT" for the Midlothifm Plant 

• Per June 30. 2005, July 31, 2()()5, ;lndAtlgust 31. 2005 "DAILYOPBRATINO REPORT" for the Midlothian Plan 

Ozo.e S~"SOIl Clinker PnducU.III

' 

June July AIlJeust T~(al

{tOil) (tOil) (tu) (ton/olone ItaSon) 

27.~59.8 28.179.0 2~,125.t &1,263.9 

27,491,3 28,002.2 27,629.0 83,122.5 

28,350.0 28.800.3 27,848.6 84,998.9 

~\\f\ n6V\VS
 

~\\"'~~Y" ~~ c.~~
 

Ash Grove Texas, L.r.
 Midlothian Plant 30f30 Trinily Consullanls
 
Ash Grove Texas, L..P. - Midlothbm Plant 

2005 Actual Emission Rate Calculations - Kilns 

Kiln NOD S02, CO Emission CalcnlatiODS (CEMS Data) 

.. Monthly Emissions

January Febrwrry March April May June July August 

EPN Description Compound (tons) (tous) (tQD5) (tons) (tom) (tons) (toIlS) (tons)

2 Kiln I NQx 62.20 49.98 59.18 58.74 66.91 64.62 65.67 54.02

S02 124.92 94.11 14537 17735 232.99 197.63 187.03 180.02

CO 15.19 17.89 18.84 13.44 8.87 9.73 14.24 13.79 

6 K.i1n2 NO" 77.52 2337 67.04 62.63 63.29 60.66 67.58 66.57

SOz 247.68 88.95 249.24 230.41 211.93 199.56 140.14 15230

CO 10.54 4.15 11.62 11.97 1120 9.45 13.46 16.93 

12 Kiln 3 NO" 40.56 78.27 69.91 66.86 58.15 52.59 68.83 6.5.88

SOl 78.65 148.97 95.70 83.52 129.18 134.56 93.09 102.36

CO 4.25 16.10 21.77 20.04 17.37 15.40 17.00 2132 

Total Kiln EInlssloDS 

a MOnthly emlssioD$ obtained from Continuous Emissions Monitoring (CEMS) data reports, provided by Ash Grove on JanU8Iy 22, 200t 

b Per TCEQ 2005 Emissions Inventory Guidelines, RG-360/05 (December 2005), the ozone season is from June 1st through August 31st, inclusiv~

FIN 

2-1 

2-2 

2-3 

September 

(tom) 

October 

(tons) 

63.63 

271.72 

13.56 

55.56 

271.25 

13.00 

5&.91 

165.70 

15.48 

73.30 

205.71 

13.27 

63.98 

145.24 

2L39 

71.49 

160.87 

16.40 

November 

(tons) 

53.10 

208.05 

14.10 

70.04 

178.27 

9.77 

71.97 

195.43 

15.32 

December 

(tons) 

39.68 

112.03 

6.90 

74.22 

179.74 

14.85 

81.99 

193.31 

16.67 

NOx 

S02 

CO 

Emissions 

Annual 

(tpy) 

Ozone Seasonh 

(lblday) 

693.35 

2,202.47 

159.5S 

4,006.74 

12.,275.65 

820.87 

765.13 

2,249.63 

142.69 

4,235.00 

10,695.65 

866.09 

790.48 

1~60.88

203.03 

4,071.74 

7.,174.13 

1,167.83 

1,148.96 

6,012.98 

505.27 

12,313.48 

30)145.43 

2,854.78 

?­

7<­ ! :@
 

:$ 

UL-C
 

-~s:> ~~

>= 


 


 

(5/ 


 

\ 


 cf\ 

Ash Grove Texas, L..P. 

Midlothian Plant 7of30 Trinity Consultants 
Ash Grove Texas, L.P. - Midlothian Plant 

2006 Actual Emission Rate Calculations· Input Dnta 

Kiln) RAW MiJI~ Finish Mill. :lnd Cl'l1shing H(Ku"3 OfOpel'I1CioD 

AnnulI Hours Ozone Season HOlln or Operl\U.n· 

FIN EPN of Oporatlon· June July Anliist Totlll

(hdya9) (hr) (In) (br) (hr/o2.0DC aeason) 

Kiln 

2·) 2 8~339 714 144 7~4· 2,202

2-2 6 8,174 108 743 708 2,159

2-3 12 8,286 110 744 121 2,17S 

RaJ)lM;ll~'

)..7D F·MB) 4,410 371 3S6 441 1,168 

1·7B F-MBI 4,263 376 411 312 1,099

F1l1lsh MIII~

4-1 S 1,783 657 652 ?OS 2,013

4-~ 9 1,116 617 692 627 1,935

Stamler (ems/It,,.) 

J·24 1-24 4,229 363 392 361 J,123

I Per December 2006 ''YOSI' 10 Dale OPERATING REPORT" for the MtdlothillJl Phmt. 

II Per ]unct 30.2006. July 31, 2006, fUld AUjust 31, 2006 "DAILY OPERATING REPORT" for the Midlothian Plant. 

Clinkcl' Pl'oducUon 

FIN 

2-1 

2-2 

2..3 

ErN 

2 

{) 

12 

Annual Oinkel'
 

PI'Odudion­

(tp)') 

334,160.8 

))8,485.2 

323,847.) 

OZOIlO S"lson alubr PI'odutrion~

June ,luly August Total 

(Ion) (ton) (ton) (ton/ozone seRion) 

27,572.6 28,977,5 29,416.4 8~,966.S

26,890.6 Z8,B03,3 27,329.4 83,023.3 

26.348.4 28.534.4 27,843.4 82,726.2 

• Per December 2006 "Year to Date OPERATING REPORT' for the Midlothian Plant
 

b Per June 30, 2006. July 31, 2006, and August 31, 2006 tIDAlLY OPERATING REPORT" for the Midlod1iEUJ PLmtt.
 

~\n n~YS
 

~ybetmAsh Grove Texas. L,P,
 

Midlothian Plant 30f29 Trinity Consultnl,ts
 
Ash Grove Texas, L.P. - Midlothian Plant 

2006 Actual Emission Rate Calculations - Kilns 

Kiln NOv SOb CO Emission Calculations (CEMS Data) 

Compound 

NO~

S~

CO 

NOx 

S~

CO 

NO" 

S~

CO	 

Monthly Emissions EmissioDa ll 

January Febra:ary March April May June July August September October November December ADnual Ozmae SeasoDb 

FIN EPN DescriptiOD (toDS) (tons) (toDS) (trms) (tODS) (tons) (toIlS) (toDS) (toDS) (tons) (tons) (toDS) (tpy) (lblday)

69.386L 60.4490 64.4573 64.2024 70.L241 72.0165 71.8020 65.9715 64.6937 5&.0380 57.4416 37.2168 755.7~ 4,560.6522 

206.8620 189.4473 183.9578 192.7933 230.2726 228.L686 246.3561 213.5413 150.0201 198.8193 154.9290 103.4212 

2-1 2 Kiln 1 

2;298.5946/ 14.957.9574 

11.03S9 9.1573 10.7232 11.1933 12.9964 11.8200 ]0.6804 11.3375 12.2003 12.9309 10.4004 4.9126 129.3882 / 735.6077 

2-2 6 Kiln 2 76.9657 38.6756 66.7310 60.5552 67.0394 67.3123 59.5444 53.9485 63.6637 64.3026 57.2068 45.9560 721.9010./ 3,930.5467

193.3457 102.6650 214.8876 187.7462 172.5071 131.6721 171.4602 177.6386 129.5926 163.3053 224.6011 140.9190 2,010.34~ 10,451.5403 

15.6287 4.2951 9.6139 12.2149 14.0410 15.4382 18.5628 16.1929 14.669L 15.5394 9.7158 11.0084 156.9201 1,091.1707 

740.6744/ 4,051.7109 

128.1149 221.6056 149.4815 136.8023 132.8300 135.7006 166.5307 171.4562 183.6454 173.1 L59 162.0788 193.0731 

2·3 12 Kiln 3 47.7865 68.2169 69.6191 65.1739 67.1752 65.2795 63.1648 57.9345 60.6852 60.1410 52.9070 62.5909

11954.4350.~101297_5548 9.1879 10.4649 21.6800 16.3138 19.7145 18.1807 17.8374 L6.2378 14.9843 16.8908 14.5973 13.7861 189.8754'-' 1.135.9967

Total Kiln Emissions	 N01 2,218.3744 12,542.9098 

SOl 6,263.3702 35,707.0525 

CO 476.1837 2,962.7751 

Calculated
 

Annual
 

Emission
 

Factor
 

(lb/ton FIN EPN Description Compound clinker) , 

2-1 2 Kiln L NOll: 4.52~'" 2-2 6 Kiln 2 NO~ 4.53 //
 

2-3 12 Kiln 3
 N0:t 4.5~

.. Monthly emissions are obtained from Continuous Emissions Monitoring (CEMS) data reports, per email from Francisco Pinto, Ash Grove. to VmeetMasuraha, Trinity Consul~ dated April 23, 2007. 

b Per TCEQ 2006 Emissions Inventory Guidelines, RG-360AlO6 (JlUIUary 2007), the ozone season is from June Ist through August 31st. inclusive. 

~~'=£"7< 

-S­

..-- ~~,. C9 ( c::: 

-'" 'Co 

r? \

Ash Grove Texas, L.P.
 

Midlothian Plant 70f29 

l~ Trinity Consultants
 
~Ib ~~~:~PI!,·~....:~.t.bI&\ll '.Jant. 

io07·A.l·1=~o·~:~~=C.i~~iioD~.-ll)put ;pata 

.,',.. .. 

. ~;~..if'o..· 

"c~:j o.:o...~.H~~~*~~ . FIN EPN ·Ot~lioa·'.· * 4q.It' .:r~ 0 

'.;' ~~t ~"'" .~. '. ~r/~~~.")" : 

'~iJ"

o' '1. • ,h t , I' 

.. 

2..1 2 '8~I' 6.57 ~1' 7~ .1-.9.19' 

2<2 6-: ':~~" 698 407 ,~ l~='1-": : 2-3 ~2 .'1.~~: S~ ~32 724 1~.64'7·

2..1(With SNCR. oalyt 2 3':88 2t6 4S6 624 1,2%' 

IRqwMIIJI 

1·10 '·Mal jt~ 348 96 318 762 

]..7E P-MBI 3,988 331 288 316 99S 

Pln1.Jh MiJ1$ 

4-1 5 6,893 457 429 1t2 1,597 

4-2 9 7.m 619 547 727 1.893 

SflUItIn (CrN$ltn) 

10424 1-~4 3,923, 3~S ZZ2 373 94tO 

• ·Pet DecofttbOr 2rx11 "'teir to Da.QHiRA11NO RBP6li"'ofor.w:M~I~

\ Pot Juno 3O.:2007~·1uIy 31,2007;.a AtJ8U't 31, 'JJXn. -Dj\D:.Y,oPmiATnio ~POR"'" .for,1hoMidlothl.PbI" , 

. • the SNCR opcritiOO:l1 time information obtainted ttom FrtJi~ Pirt~.. Ash orovc; to Anand MaSun.b~ ~ity CQD8uJtanfJ.. Manh J6, 2008 

~.rProcl_"

FIN EPN Aoli~ Clhd,er 

. Prud:acdoa& 

(tpy) 

Total 

(to~.·~e-n)

OzeD. s.•• CUltker. Produc:dCt.. 1t 

J~)' AlI"~

(toD) (to.) 

2.. t 

2-2 

z..3 

2 

6 

12 

313~129.4

286.269~4

. :.:' 29?~7S.~

25,409.5 

25,879.1 

.. 21,9~9~8

20.. 101.1 

1S.133.5 

l2,409.S 

27/134.0 

25,3~.2

27,206.0 

73.445.2 

~12.8

6~t575.3

PerDecember 2007 "Yeer to 01.OPBltATlNGiUtP9XT' f~·_M~.·t]_
 

~. PerllWO 30, 2007. ~y lit 2007. aod All&USt 31.2007 "DAILY OPBRA~ ~R"" for the Midlothian PJanl
 

,Aih~ve Texas, LP. ­


.MDiw.tbim Platit ioi30 Trinity .Consult81lts
 ~. '.. \ . 
_--A-_--__._..- ... _1 0-_-_ ---.------ .--'. ----­

Ash Grove TeDl .. MicDotbtaa Plant 

2807 EiaJ.sl e OdaalatloDs • JaIDs 

ICI1II NOp CO bdIdoa Calee1d..·(CDIS Data) ... 

~EmI"'" ·J--11 F"r, M.a:Ia AprB Mar J8k l1dJ Aapst AmI" ~Se!f}Joa"

SPH ~) (tGaI) (tGa) 6*). (~.) (.> (fOal) (IDU) (1M!) (1b14ay) , . ~Ip)')

Odokr N~~

(tMIt> (-.) ~)

39.t111 59.6G40 34..6P,!n.

197-'613 lS1.s641 IJ2.B1-46

19.7791 16.9285 8.6479 

54.1092 54.4961 48.1312

2-C.2960 2-412.7698 2%1.sM3 _ 

16364t 133936 l~l

n.8457 55AM 61,1311

173.1113 U3.92S1 14.539;62

2OS7SO lSS1I2 ~~~; u:.~~~-

.........
 : JCbl
 ~st 36.9483 <KIno S9.6191 41.1192 26.3691 3'.te7 '20~16 2.23.3.0841 

SO: 

~~

186.7-4-41 ~. 16'.1034 131.so11 131.1241. 172.3161 1-42..4124 15~.2321 179.5174- i19.cml lJiJ~.8051 10.438.3152 

co 1009131 11.5884 W163 14.2062 1....ss53 13.0092 8.-47JS 15~ U9733 tQAS7l 805".4185 

NH,c 44224 31.8939 

, XiD.2 NO. SO.9207 1~73S8 '1.7990 613&53 63.2794 59.1211 32.0110 S2.0Q66 6S.4S22 :~l ~tll.8161

SO:l 180.3'14- S8..1293 J08.7189 239.602 233-'15& 191.6978 1J9.1936 2rn~86Z1 2.13.7173 2..--«$Q.IS07 11~

<Xl 13.'MOS 3.313S 1005'1J 11.4693 12.5000 14A22S 1.82S7 11.3952 13.7.(76 141.~ 153.1163 

12 Kiln 3 NO. 31.0842 sa.19Q8 63.2741 62.4~ ~.s026 ....9949 2.7.3151 55.9990 $«431 ~92 1.789.321ll 

ll1A631 196.4134 151.2975 l24.O611 143A341 16Q.'7444 98.3SC 116.8463 161~12 1~ 9~S4~~

co U281 15.4~ 16.046-C 11.4040. 18.53" l...mS1 S.-44J86 14.2Sal 16.S~ 733.l679 

• rr.c.lJala~ ~- ),1Mit ~. ~.,...

cO " ~qfm . 

.Miu i1~.

fU( 

2--1 

2.-2 

2-3 

J'IN 

~l

2-2 

1-3 

. c.IcaIa.s 

AimDl 

JI'.-. 

.(DrJta 

NOll J.n 

NO. 

NO.. 41' 

... _. -

ErN 

2' DDt
 

6 XilD~
 

12 KDa.3 

'~~(CSMS)_d.&a ~."'1frCca lriftoilco Pllco. Alb Grow. co AnInd MaurIha. TiiDita duid Waeh4. 2001. ~til..oaia CNH~• WoatW;air.. ··Qi~bUIt ..D-'ai·,.-.~...,_oiow.,.~21.2L008.

, Ptr~2OOf.........~~~~2coI)...CI2:ODW~·wavm..,..tIt~~31~~• 

··~~~~...~~TM~....~-....~~~_k:zAtIbt1lr4 . 11ds....·~witJltbohoarof~ofSNCadmiDcOZ;O"-·..-oDlldlllDUlUyil ..~~IIIUIKXJk~w"bcaSNCRilopcati%:31-In2001.SNCRWllSoulyopcntadforKiD 1. 

Ash Gvt>~L. - 2001 

N0'/ Sb1- ~Y)nlAcvt

..J 

• 

Alb GloYO Texu, LP.
 

MkIothiaD PlIDt 70£30
 TrixlityC~'
i 

Ash Grove ·T'cxas.. L ..P. - Mid loth ian Pla'nt 

200X Actual Elll;ssinll Rat~ Cnlcu-lati(1)s .. Inpul Data 

f'iln. Hn\\- Mill. Fini~h Mill.~1I1dCru"hfngIlours~'lr()pel'{llu,lI1

FIN 

Kiln 

~-I

2-2 

2-J 

.:!.. I (\Vith SNCR, (lnlyr' 

2·~ (With SNCH, tmJyt

"-J (Wilh kNCR. only)~

LPN 

6 

12 

Annuoilloun. 

of()jlera Ij(lIlli 

tlll\r} 

~.i\56

'6,8Rl' 

7.Q7~

5;221 

5A87 

~)O1

.Julie 

(hI") 

b8<J 

70~

704 

(..10 

M~~~

6(-.2 

Ozone S~".snn H(Jurs ofOrcrulHlnI. 

.l\lf}' i\lIgu~( Tolar 

(hr) (hr) (hr··ul.<.\rH.' ~CCl~()I1)

71$ 744 l:l~

741 7·B ~.I ~):;

714 7~4 2.f·H 

('RK :,\9i\ 1,\)24 

720 734 2.1 )(, 

68R 714 ~,(JM

1-71> 

1-7E 

.....\1BI 

F-MBI 

3.ltS,'i 

~l~4<}

:'77 

J5H 

J(J] ;1(,1 1.O9() 

J3J 3Jb I,olt) 

F illi~h ~'hlls

Slumlcr (Cfu~hcrl

1..24 ]-24 

7.~51

8.I.'iQ 

J.760 

63t! 

(i"" 

357 

tl9~ 7lt4 1.0MI 

704 CJI() l.tJ44 

J53 J5Q IJl(,& 

.' Per l)cc~~ml~r ::W(U~ 'tYc~tr h' {)mt: OP]f.RATlN(I REPORT" J«x lhe Mldlothiall Plant. 

h I'~r .I11m~ :W. ~()mt .I11ly 31. 2008, 'tn<l Augll~1 -' I. '200loi "nAil..)' OPER...\TING REPORT" l"<1r th~ Midlothian Plant 

l' The SNf'I{ ('lJlCl1Jl.ional1,ime intbrmalion otltnlnt<.'d fhll1l Michael CnUclldcn.. Ash Hrove. lO /\mmd Mn~urnl1n. Trtni~y Con:sultun(s. 

P"'hrm\fy 12. ~()()Q tlnd February I~~ :!OfN. 

Cllnl\cr Pro(hicl ion 

FIN FfiN 

,\nl1ml" Clinker 

Prnduction" 

"(tpy) 

Jun" 

Oon) 

{h'one Seu~nn Clinkl,.\'r Pnxltlcllnn" 

,I uJy AlIgU~il Tnlj{ 

(lOll) (ton, (10l1·-0/,(HiI.:l\c(lSun) 

2 

6 

11 

:~.:!2.8274

2~6~~CH\.4

JOl}5 f ... 

~5JlR:).n

27.10n7 

:;7.~J2 5 

2~.HR6.\)

28.74'1.Q 

27571.0 

27.537.1 

~7.Q09 :' 

:27.~4Q l) 

~(l.J()~. ) 

R·LJ5:'.1 

X2,J5J4 

.} Per Dt.'Ct'ml)\.\f ~O(JX "Year lO I)alC OPERATING REPORT" Ill!" lht: Midl()(hiull Plant.
 

P'-'r..I11tl~ 30, :!()08\ .July J I. 2008:alld AugU":1 J I! :W[l~ -1)t\ll.Y (lPFR,\TJNG REP< )RT" f()l' the Mid)()'hian IJJanl.
 

(\~h Urovc Texus.. r.,.p.
 

lvtidl'()lhi~tIl !)]an1. 3 ofJ t
 
Ash Grove Texast LP. -l\tidlotbian Plant 

2008 Actual EmiJsioD Ra. CaIc:alatiol1s - Kllns 

Kiln NO., co Emi.Jlioa CakulatiOltS (CKMS Data) 

I'IN EPN Descripti2-1 2 KiJD 1 

2-2 (; K1In2 

2-3 12 Kiln 3 

il'obl DaEmissiIlU 

I"IN J3'N DesaiptiH. 

2-1 2 Kilnl 

.z.2 6 IGln2 

2-3 12 IGIn3 

MoDlbJy~o..

Jan1Ult'1 Jebnary Matda April May Ju.e J1I1r Aneut Septc:mber (Xfober NO'ftIDber Decembel' 

Compcl1lD.d (tOld) (tOld) (tal) (t8Ils) (tOBj) (10-) (tal) (ta..) (tellS) (Iou) (tons) ftft') 

fN~ ".0219 4'.~ 36.6941 30.4142 29.1182 21.9]64 21.1341 29.9903 29.1292 32.1934 47,S$16 1j.7632

so: 239.6150 169.5119 H4.8OI9 143.374~ U3.OS19 l1S.49G4 In.74.56 139.1327 74.4'23 147.1116 164.2769 2IUS43

U.4S60 1.5.410S 13.1309 13.1006 14.2163 12.8130 11.1704 12.6S09 12.6'11~ 9.0734 1.1529 10.7906 

NIig dmiD& SNC1Dcrtmti1u1 

NliJ dariD& SNellOpcnIiQllll 

Tota1:N':a. (SNCllDo'Wmlme + SNCR~)"

CO 

NOx 2..5759 41.9135 44.m4 34.0232 34.7371 37.9218 31.4992 39.1091 33.2927 41.209~ 39.6677 0.0000
 

SO:
 9.2299 1~ 1&7.1334 i76.1469 207.77S3 171.3272 1:26.4267 92.4411 40.3&156 93.4318 ~3.7097 0.0000 

0.1263 7.am 12.4697 14.0540 10.4221 13.3141 13.38" 16.2114 14.861S U.5943 lUOl5 0.0000 

cl.cug SNC&:DownIimec
 

duriDg SNCR ()pendoA.
 

Total (SN:R.Dowadme+SNo.Openl:ion) 1/
 

co 

61.4612 34.419& 41.2'39 3S.23 so 34.1334 J9.994j 3'-'OSO 35.~ 33,3527 4~.123g S4.5&07 90.9611

so~ 2073375 llO.2m ZOeS.6946 145.3439 124~934 109.0122 96.6304 9O.S2S6 47.7197 141.1997 99~73 189.7531

co 1'.9931 6.S613 11.1707 lll133 14.3869 16.3091 12.S3'9 14.4.164 ll.9306 9.3414 5.02J3 . 7.0113

datiDa SNCllllowJl.timef 

N& cl'IriDI SNell 0paraIic&. 

Total NH, (SNCR. Downtime'" &NCB. ()poration) I 

CompGaJUl 

NO. 

NO• 

NOll. 

NOs 

lOa 

CO 

Caladated 

ADuI 

Emisu. 

11'.........
 

(lbltoa
 

diDkr1'1
 

W 

3.01 

J~

bIiaioas 

AaBall1 OzoaeSeuo.· 

(tpy) (lblday) 

456.&3" 1,603.0717 

1,1'&..4710 1.673.3630 

146.4290 197.9185 

2.914S 4.1314­

10.9767 a7_834~

13.1912 9L9702 

3".2491 2.41'.9513 

1)41.2947 1,6S4.69U 

127.1345 933.0OS4 

1~50 1.1133 

12.0714 102.lj6j 

13.3264 103.26~

54L7S7S 2,402.6511 

1)"6.44'1 6.438.~16

139.6561 ~O.4641

2.6700 L61U 

l2.9899 109.9304 

1~i.fiS9.9 111.6130 

t.384-Bm 6,495.68U 

4t71'.2171 13,'T4'.7Ul 

413.%196 i,671.!180 

4~1714 306..1530 

a MoDth1y l:EIDniou m: ob1:siDed.fi.um CoDtiImous Hmis:sioDs MaDitmiDi (CEMS) data tepQrtI. peranaD &am PnmcBao PiDm. Ash Gm~ to Anacel M~Trimly c:o-dtallU, dllllld JCl'lW)' 30, 2009. orC»D.OIlia (NH,). 

11 P..TCEQ 2001 PmissioDs lDvemmy GuiddiDea.llG-360A/D8 (JIIIJBY 2009). tba 0ll00e RISQD is1i'om .hmc 1St 1brouP~ 31st,. hdusift. 

• Ammrncia ClIIliuioas from tbe l::ilns baed CIIl aftila'b1e Uta 1br CDlcnrla ccmcaa1rIdiou tmd slide flD,n adw.. obUiMd.hm FrmciEco PiI11D from AJiJ. Grove: on F.cbtumy 10, 2009. 

An -venae hourly ammODia emiai<m me WIS ca1culmd iRlm empmmi' soees.'~mel &'VCrIF kilD-steeJc 110ws to develop the m1lDwiq .minon~. i <::EMS am <:EMS dal . ­

wJMsa.1Cila wtaa lG1D
 

was
 

opcnied gpenad
 

alldSNClt lIDdSNCR
 

w.m wesJJlOtm t\sh GYO'le - --ZOi)g

opcmtion opcraticm
 

(IMlr) (1bI!
 

1 4.2 1.7 

1 4.4 1.1 

4.9 2.0 No'j. $1)2 O\~'n~~

Q\\~ Ash Glow Teus. LP.
 

MidlotbUm Plmt 10131 Trinity Consult.an1s
 
Ed(M.r2~ Asll Grove Texas. L,t>. " Midlothhm PIRnt

2009 AduRlll:missiou Rnte Calculations I(&]ns 

; 

( Kiln Bonn or OpeJ"otion nmJ J~lIrticuJ"tc Mollel' DIr;C,.lbut50.. 

\ 

FIN 

2 

6 

l~

EPN 

C2. 

C6 

Cl2 

CIN 

Kiln J 

KiJn2 

Kiln 3 

99.10 

CJ'),1tl 

99.10 

COI1II'\lI Krric[cncy 

PM/JIM I' {'Yet} 

2,\76.() 

1,996.4 

(l.n 

114)....1 of Ollcrarloll 

AnnuHJ 01","e Semlon 

(111'111') (J.../Ol'.one sC2lson) 

too 

100 

IOU 

Plu1kul..tc Matter OislJihutlun" 

IJM I'M.. IJM1.~

(%) ('Yo) (%) 

• P.rtiC'lIlatc mnller dlstl'ibulionllcolahlCd rrom AP·42. S~lUll '1 ,G. TnbJc I 1.6-S, (Janullry 19')~).

)(jIn Clinker pJ'oduelion 

FIN ErN <.1N Deler1lllkln 

Uiuker Prod_clion Annuli O7.ORe SCIl.IIl 

(tp)') (tol"'~n)

2·t 

2-2 

2-3' 

2 

6 

12 

C2 

C6 

Cl2 

Kiln I 

Kiln 2 

Kiln 3 

211l.1I611,() 

226.117.7 

101.077.3 

10.215.6 

71.SS0,9 

0.0 

Kiln IJltl·ticulatc.MnHcr. H1SO~11I1Id Speciatcd ComJlound R.mlnlon Cllicuilltion. (Stllcl, Test Oata nd Mass n"'".rc) 

Kiln 1 (YIN: 2-1. I~J)N: ]) Kiln 1 (FIN: 1-1. EPN: 6) 1<11113 (FIN: :Z-3. ErN: 12)

Emi$.orioft Emf~sioflll Emi.!lslnn Emililioru Ernhsioae Elllilclions d Fltdo....... Annllur' O¥(lDe Seftll(lJ1 ,t
 F'lClor....· Annultf Ol.one SealiOtl,J, If;Klo(!" AI1I1UliJ~ 07AlIlC S~I\Ill"'''''

(IJft(ln clinker) (tIIY) {I bida)') (Ill/lao diJJJtt!J') (~I),) (IMlay) (Ibfton clhlkcr) (I(l~') (H.fd"1) 

(1.16 1~.877~ 1"2.~~7J 0.34 3R.1UJO 2~,27H) (lA~ 22.91n O.OOCH) 

0,13 13.4~9 121.42K1 0.29 ]2.4071 242.4809 0.31) 19.11KOI (I.DOOG 

(l.W 10.16/6 91.4281 1122 21\.4007 11Q.~7.H~ 0.29 14.6673 O.(X)(lO 

'fut.-l l'l\rlicuhdc MaUel' U.R115 142JI~'1J 38.11(,0 ~1?16 1:2,9J7; O.CX~

Sl)ech!.1cd PllrUcu1aCc Mnlter I Obl1oll clinker) (tJ)Y) (Ibllln~') (lbl!Qn clinker) (tpy) Clb/.IY} Cllll1ondlnhel1 (CPl'. (IhMl&Y) 

An1j.lon~ J.32E-O~ O.IlOIJ 0,0119 !.Cl8E-(l5 0,0012 O,(lCll)l 1.2(JIi-U5 IUXI06 O.(l()()()

ArlSCnie 2J1)ll·(J{. O.O()[Yl OJ)l1l9 7.~2R-C)(i D,{HJ(]i) O.ooM ".93E·(16 (I.Ollell O,llfll)()

IlcryJllunJ 1.6.HH)() O.(J(Hl2 n.r)(ll~ t.89E-06 n.n002. 0,0016 J.9(~-()6 O.()('IOt (J.(X){IO

('ndmil.n 1.91fAl6 CU)()U2 O,lK1I7 2. I 7a.(N') O. OOCI 2 0.0018 3,47f.-(J(1 CI,0002, (HXIOU

1.92E-U.5 0,(102') (l.OUA 9}.Hn-o.s 0.0108 a.ORll J.2~6-()~ CWOO6 O.lIIO()
 

Cobnl(
 

ChmltlJ\lnl 

1.66I!-(l~ ()J)()I7 ().()I~O I.Y1F.·C)~ 0.0022 0.01(;2 J.74E'()~ l),()()()lj (llll(JO 

Lelld 2.20E-05 O.mJ22 fUlIlJ9 3.1~6-0.s 0.0042 ().O311 3.1()6-0~ (1.0016 O,lXI(I()

MangmlCsc 6,28E-O~ ().()()(jJ n.n~GR :"~J~-{)4 0.0399 0,2987 l,27E-4)4 O.OU64 o.nooo \S i Nickel 1,12.I!-OS ().I)()I I 0.0101 5.2(lE·()S O.OOS9 CI.()4-10 J,37B·Ol O.O()()7 O,lXlOl'I

4,2(~-O~ 0,0043 O.U3~ 4,I~E..()5. 0.0047 0.0354 1.1()6-(l~ O.1I0f)(j U.OOf)(l 
 IhSO,
 

Selenium 

C1.09 8. 8M3 79.7743 0.06 6.2:193 46,(,847 0,10 4W15S f). noon 

?',9~% 6.3097 4?1121 ".917S n.oooo 

J g 

(I blUm ~linlie ..) (tl)Y) (lb/dny)
 

FOI"IQldehyde
 

(lb/tlny) (I hit on cUnk~ ..) (tllY) (lbIdftY) 

Benzene 3.(,JE-(lJ 

1,02E-02 

O.J.M!) 

1:0,..54 9.2261 

3.2~4 5.1JE'(13 

1,!(;}!·02 

0.j8112 

1.3119 981W 2.J1~·02 LI()74 (1.00011 -~ ".34IU 1.I12E·02 0.5155 n.oooo

2A2E-04 O..024J O.ZIH9 _.	 . - h -. 4.42E-04 00223 Cl.OOOO
 

SlyrOllc
 

HI h)' I Bcn~CllC

:1.63[-04 U,O:tM 0.3283 6.49£-04 UW34 0.5"92 I 33g·03 0.U672 f1J)(l()l)
 

TohlCI\C
 1.33[-03 0,1:137 1.2(00 l.nR..i13 0.2001 1.4?1R 3.39B·O) O.t713 [1.C)(IQO 

.n.,)~Xylcnc 3.01~·04 0.0:105 OZ',,, I 5.31H-04 OC)(,o1 (IA4!») 7.J6E·04 0.0372 (I.noon 

Totlll SIJCdalt:d VOC I.'l~ 14~38 l:12..,~ 16.6533 J.981l!> 0.0010 

(it)]') (lb/~l'IY) (Ibf1on t1inl4u) (tp)') (UlflI t1Y) s=. O~R10 4.3918 ••tt __h .­ Ki1l1 Mercury Compound Enlissic"l Calculations (using Mus n.lll.cC!: AllIH'(U1Ch)
 

«.llY) (lb/4a~)
 (t1)Y) (Iblddy) (tn,,) (IbidA)') 

MCt'Cluy (tdill)f (I.()[J87 0 ()~2 O.OO9H n,U1J1 0.004'1 O,C100U

.tl)1) (IbId I')') (jlly) (lbldIlY)
 

Mertlll'y (¥:lpor) OJl085 U.07()()
 

Mcrcul'}'SllcchltiUI1 (~ •.)'... I (tl)~') (!bfdtl:Y) 

OJlll9Ci tW71G 0.000 o.uooo
 Mercurv (PM) 0.0002 Il.OCIJl)
 O,om72 O.OCH's ().OOOl 0,("1(10
 

Mcreury (PM I..) O.O()()) tlOnl3
 0.0002 O.OIH2 O.OOlIJ U,llll(H) 

ft nlUissiOl\ f"ctof's for PM nnd I·~SO.. nro tbo avor!lgO hm..l)' omi.o;sions blod ckJrlllU the JUlle :m. 2tl03. tp July J. 20113 swelt l~~ pcrronllcd by MlITCO lrnv1rolUnclllnl.
 

Per '['CEQ l"CqI.l()Sl, Avcrago hovd)' PM and H1S04emlssiou f"cton are eoKYcrtcd kl -lbIIOll clinker- \Ising Ihe daily clinker- prodllCliClR 'UlIiSlios.
 

obtoil'lccl from DDily Operating ~cporl' ()ORI) fOllbc duy whcn SUlcI. ICSI$ were pcr~.cd
 

Enlissian raelors rOl' PM III and PM2 Are bn!;C(J 011 A1'-'12 p.lrli,aI..tc 1l..1UCI· djslrillllliOl\$
 

to	 P.missiOfI riIC~tors ror spcc.ialcd PM and VOC ~ompollnds 1lJ1d 1·1CIIl1\l11IC IbItot, clinker v.llnes from March 20()J MACT SubpilJ1 L.LL compliance tests
 

cxccpIIOrClllis$i<)1) fnctol"li (or'spocialiou ortOCalIllCl'Cll1)' cMlinions. which nrc cstinll(cd vfthlCS
 

• For (Joulld per hour (lb/hr) cmillSlon fn(>[or; Anl\\1il1 Emissions (ll'Y) r.;. (nmt.o!;*ioM FIIClor'llblJIQurj) • (AnnuAl 01)CJlUinS HO"fl Ike/)'rl> J(ZCI()() Ib I 'on 

For pound I'Cllon Clinker (lMan clillkCJ') cmissi!)" Ii,ctar; AnmUlI cnmsiol'-' (t]1)') .. (limhsion JltlClcr llblton clinker!) ... (AI'llUftl Clinker I

l rodllc.lion I(py\) I (2()()O lb I too
 

" Per TCIrQ 21111') RMlillliioll& hl\'Cl'llOI'Y (1\liclclinCfl. RO·:16(1N~) (lanury 2(10), [hC(V.(lIlOSCRSOn Is from JullO Ilhl'Ollg1& A\I&1Is13I, i1lClnsi,'(
 

• Fur pUlllld per l1(lllr (Ih/hl') cmission IiIclor: OIDJIC ScnSIDallmi$slollS (lbltJ.iy) = (EmilOsloll Factor Illl1l1l'1)· (O~IO Slxlson Opcrl[ing Hours Ihrio1..01\0 SiCASOI\l) I {l)1 duy IU/ono 5011501
 

POI' pound p~r (Oil Clillkor (lblto'l4;lin!tc" emlssiou [bctOI'
 

(}r.onc Scnson li,uill.1i()l\$ (IMlay) n (fimisslon FACIOI' lib/lOll ollcltcrl) • (0'01l<: Season Cliukcr PI'OCh~lion IlOll/lT/.ono sensan]) I (92 d~' I O"/,Ol\C lC~r
 

r The loral merclll)' clllission JR'e from AIIII\I'OC kilns combinc;:d is cslima\Cd til Ihc Mili1u[hi"n plnn. using n maIlS balfll\CC llPl)ronch.
 

ll'l order to dol~I"RtiIIC U,c mereury cmisslolls rmm CIICoh kiln, U~ loh&1 mercury emission rAte IS proportioned oollCd on clinker fIOd\\ctiol1 rO!' each kill
 

I Only Iho nlOl'(>lll'y cl'IIiuk>nm 1blare !IpCOia'cQ Il! IJM (not tOlalll~l1ry omjsslDllS) cQllllllowar<! dlC [mill ~iAled PM CUlissl(H'
 

10 ~lnl&liol\s i)'Dlll IhcIC J)(»)JI1IHIII.!; \Yera bola\\' delcClion level. t\uri_e die Mnrch 200J MACT SubpArI 1.1.1. oolnplial!cc test! 

, Spocifllcd ftlClC\ll)' V4Ipur a.d nu:rcnry IMllticul.lC p<lrWlllAjlc (Of ",at kihlll n1'C ohtained fI'O'" l'ortl:ll1d Coma.l AlIsoeiaciou (peA) rcsclH'cllllld dC'YClopn,cml dOGl.ncnt
 

CO#lpilal/tJt'/ ulMr:rcllry Hmi.rsin/l.li })(ff(I. Flgtllc 4-17 (MerolU)' S\XlCiRlioll pcrcel11c1lJCS .. i\wragCl far ftllliln l)'pcs), PCA R&D Serial No SN309I. Ma)' 20l)(),
 

Per r:iQlll'C -I-I? MCfeury spcoimioo rorwelkllns ls liS follows:
 

Mcrcmr)' (1n1~lc bOl.ld) =- 2-4
 

Mercury (oxidiud) .. 14%
 

Mercury (c1C1l1cnlnl) => H4%
 

POl' Section 2.3 of Iho peA dOCllJllul. pnrfi¢lc-bO\mcJ mcn:ury il> Ihe \llcreury d\i\1 hnl ct)J\dcnsc:d 0,,10 l)ilrliclll"tc maUer. tmd
 

clel11entlll mercury (Hg') and 0;0; ldii'.ed mercury (HB1 11 • H~2 ') cQllIprisc lhe vnpor-pl)El$O mereuI')'
 

Il is r'r1her ossunlcd lhfll K~% or ro1~1 parlicle-bound mercury C111issiOll,:rrC 11M."
 based OIl Ibe t1i6lribmioll betwoon PM and PM", n~vro,"dcd in AP-42, ~Iiou 11.6, Table 11.{)·5 (J.mo(lI)' 1<)l)5) ror,,,ct ~ililscolllrull<:d wilb nil nsp..
 

Al'h OI'O"C 'l'c:'(ns. l.P.
 

Midiothillll Plant ~oD2 Trini'}' CcmSlll14111S
 
~bl"\\~ vJl E 1lQ., 

Kiln NOv SOl1 CO Emission Calcnlations (CEMS Data) 

FIN EPN DescriptioD Componnd 

JanIl~ry

(tons) 

2-1 2 Kilnl NOx 

S~

CO 

NH:; 

71.4137 

124.4198 

~t9852

1.6730 

February 

(tons) 

51.5508 

109.5844 

8.0339 

0.7842 

March 

(to115) 

0.1957 

0.1813 

0.0961 

0.0042 

Ash Grove Texas, LP. - Midlothian Plant 

2009 Actual Emission lUte Calculations - Kilns 

April 

(tons) 

MAy 

(tons) 

Monthly EmissionsJ~e July 

(tons) (tons) 

Aupst 

(tons) 

0.0000 

0.0005 

0.0000 

0.0000 

33.1907 

31.7892 

~.6507

0.4772 

55.5762 

85.3661 

8.8647 

0.4935 

50.8178 

171.0505 

10.5824 

0~631.3

49.4072 

129.1900 

10.5805 

0.7183 

September 

(tons) 

45.1982 

71.1724 

7.6274 

0.5672 

October 

(tons) 

43.3138 

129.3613 

6.4139 

0.3406 

November 

(tons) 

173n4 

64.1520 

28689 

0.0979 

Emissions 

December Annual Ozone Seasonb 

(tons) (tpy) (lb/day) 

0.0000 424.0413 3~86.9793

0.0000 9162675 8,382.7522 

0.0000 67.7034 652.7717 

0.0000 5.7873 40.0658 

0.0000 561.9725 4~041.7533

0.0000 1~153.m.3 10,413.4174 

0.0000 68.9661 S58.7609 

0.0000 4.0538 28.9631 

0.0000 279.4924 0.0000 

0.0000 626.3706 0.0000 

0.0000 38.1408 0.0000 

0.0000 2.3301 0.0000 

N01 1,265.5062 7,428.7326 

SO:z 2,696.6104 18,796.1696 

CO 174.8103 1,211.5326 

~"H3 12.1712 69.0289 

2010, except for ammonia. 

2-2 6 Kiln 2 INO:'C 

2-3 12 Kiln 3 

ITotal Kiln Emissions 

FDl 

2-1 

2~2

2-3 

EPN 

2 

6 

12 

Description 

KIln 1 

Kiln 2 

Kiln 3 

SO~

CO
 

NH;
 

IN0:'C 

SOl 

CO 

NH3 

0.0000 

0.0000 

0.0000 

0.0000 

88.7643 

148.'7380 

7.1782 

0.4841 

edentate<! Annul 

Emission Factor 

(lblton Compound clinker) 

NO:ot 4.22 

KO~ 4.97 

NO" 5.53 

47.2372 60.4577 57.2380 64.3166 58.6683 59.5534 67.6990 425920 59.4640 44.7465 

76.3148 158.6943 176.9801 68.3023 94.8490 197.3927 186.7755 48.2125 106.8741 39.5770 

4.7556 7.9994­ 6.1893 8.8445 7.5594 9.0036 9.1399 4.2931 5.4350 5.7462 

0.5514 0.3966 0.3491 0.6781 0.4058 0.3626 0.5639 0.2160 0.3905 0.1397 

36.1536 68.2977 62.2130 24.0639 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

633526 213.9722 161.8989 38.4089 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

3.9753 11.1S88 11.6212 4.2073 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

0.4178 0.6233 0.4580 0.3470 0.0000 0.0000 0.0000 0.0000 0.0000 0#0000 

~~ ~W'!l" tW1 

}tQi bQ.z. VY\o~l~

OJ')h\kL0 

<1 Monthly emissions are obtained from Continuous Emissions Monitoring (CEMS) data repo~ per email from Fnmcisco Pinto7 Ash Grove, to Cutis DeVore~ T~ Consultants, dated January 137 

Ammonia emissions are calculated from ammonia CBvlS data, stack flows. and kiln uptime. and were obtained from Francisco Pinto from Ash Grove on'February 16,2010. 

b Per TCEQ 2009 Emissions Inventory GuideIinest RG-360AJ09 (January 2010), the ozone season is from June 1stthrough A~oust 31st, inclusive. 

Ash Grove Texas, L.P.
 

Midlothian Plant 7of32 Trinity Consultants
 
Ash Grove Texas, L.P. - Midlothian PIRnt 

20ro AcluA] Emi~~jon Calcu)ntiuns - ((ilns 

Kiln lIoun <If Opel'lliion And P~I'1IC11lnlo Matter I)istrlhution 

FIN EPN CIN Dt.\.,cnptllln 

II(lUrll(lf OIJerlllll. Cun(r(IJ ~rnelen.:y

Anl"O\.I Oi'.(lllIlSCIl~Ol' PMfPM1D 

(hr/yr) (hrfo1.(~ac nll$un) WI) 

''I,rUaII1l1l\ M.t10J· J)i~h·'l,u'inl\·

rM PM 11 J>M u 

('Yo) ('Y.. ) (%) 

2·J 

2-2 

2-3 

2 

t'i 

l2 

(;2 

ell 

(;12 

Kiln I 

Kiln 2 

Kill13 

fl.(127.8 

(,,257.5 

"1,7UO 

1110,5 

1,'l"1l.7 

2,I<i2.1 

<)l).~2

g),k2 

9'J.B2 

Ion 

100 

100 

85 

85 

85 

ft4 

(.4 

(lit 

1't1rti~lhlleITl II lie.... dilollrillullonll ~I"l:linud rml1J AP-tl2, Scclion Jl.rt, TLlbk: II J;~5, (.IBnLMIry J995). 

Kiln Clinker Productfon 

FIN Rrl"t ell" nCIlt: r1 I)lliJl1 

CHnker Produc.ll0. 

·AIUlllld 01icM10 SU,.lIl 

(II'Y) (lonfsoMII.ln) 

2-1 

2-2 

2-3 

2 

(, 

12 

C2 

cr. 

C12 

KlIII ! 

Kiln 2 

Kiln 3 

221.140.8 

2J-4.917.() 

172,631.1 

15.0102 

72,944.3 

n,452.l 

Kill' PRr1iclllflle Matter, H~SO... IU1[1 Spcdfltcd CDmpound Emiujon CnkulttljoAs (SlAcJ( Test nAt" And ~f1ass BRliu1(~e)

KIIIJ! (FlN: 2--1, lSPN: 6) 

&ml""ion. 

AnllwKl' O,.one Sel'lu...·l,r 

(lp,.) (lh/4Ia)') 

56.3K50 31«).5190 

41.9273 32JA92 I 

36.0Kr14 2J\l5105 

56,38.."" 3ICOS79U 

(Ip)') (1111.11\.)') 

O.O()I~ U.OOHli 

O.lXX)9 0.0061.1 

0,(002 0.0015 

o.ro:r~ (l.OOI? 

(H)11~ n.07(ll1 

O:<XJ2.2 O.l1151 

().l'l')44 tH12'n 

f),()1IS 0.27')1) 

o{Xl(. I OJMI2 

0.(1);\9 O.U3JI 

64\f()? 1\3.1<124 

f1.SS411 4<1.2364 

(tpy) (lbJd.n·) 

1.J(i2(. 9.1lJ'n 

0.(,1:12(, ·4.0674 

_. 

0.0762 0.5 1"c. 0.2(1'19 1.40'\.1 

O.<kI24 O.1\2W 

2.3(17 15.61131 

(iI'Y) ,"ttl;I)') 

n.(i)97 ·tI1511 

	 (q)~') (1"/dl'3') 

n.{,()~2 0.0(.2(1 

(lilY) (1It/uIlIY) 

0.0090 O.or.,(ll 

iH)(X)2 00012 

O(W2 O.OOll 

Xll.. 1 (FIN: 2~1, F.rN~ 2) 

tn.luloll EmbdclIlA !anlulun 

rllel...."'" hnmllll' O1.DllClSt\llslmd

,r JlIIdor"'" 

CllnlJxlullCl k (lb/lo(l clinkcl') (Ip~) (lll/w..)') (lit/Ion cllllker) 

I).4ft
 

I·M Il,
 

PM 0.2;1 2ld212 :n.52's5

0.20 22.2(no 31.8%1 0.41 

I'M ._ 2 0.15 1~.711() 211.0)()) 0.:1'

T(lh.II·I\rllul.C~ Mlllller	 26.l212 37.~1~-;

Spec.l'cd p."'t:ullliu M.Uer (Ib/tnh clinker) O..y} (Ibid",) (l1N't(1n clilJk~I')

1\I\ti,n[)l)} U2E-OS O.OOl5 0.0022 t.OKli·O~

Arsenic HI'JE-06 O.OCK)2 0.0003 1S2H·06 

Bcryllillm IRig·(lCI O.(XX)2 O.n003 1.1C9I~·06

1.911!·O6 O.(U)2 O.WOJ llm·Ot1
 

Cbmflliun)
 

C",ltl1illln 

2.921WS (J.(X>3l (lOOlfH ?.sRl~-n.s

Cobalt IH,E·()S 00019 o.oem L91H·OS
 

LcsKI
 2.2()1~-()S (U1"l25 (l.Il!!.'\" PSE·OS
 

Mangllncsc
 (~2~E·05 oem I 0.01(12 l..SJE·04
 

Nickel
 1.121W5 (lmJl O.ll')l~ 5.20lW5
 

Sclcl\il.ll
 o(.2(,I~·()5 O.f.04M UJI070 -I.IRH·OS
 

H2"~O ...
 O()t) ICIOIM 141~<)5 (L()(1

ToilJI Slled"le.tlll.rCh~lIll\le M"th~l.R 10.0396 1".42.10 

(Ib/lclll clinker) (Cpy) (Ill/lillY) (lh/1D1\clllll(rr) 

"'lIll1Jnlochydu 

S••ed'lll!l' voe U)2E-02 I. 15Xtt 16M2 I 16E-02
 

Iklli'U1':
 JCl3B·OJ <1.412J 0.5921 S IJI'.-O:\
 

ElhVfllcll:rollC
 2tl21~-Ot1 O-f1215 OO:lt)S 

~Incne J(.:11~-()4 0.0412 O.(~lJ2 6.491~·04

ToilICnLl IJ3F·(j) Ol5W lJ.2J70 I 17IW,\
 

1Il.1,-Xylcl\c
 ~.(lJE·()4 (J.nJ44 O.(}494 5l)1~·()ol

Tohtl SP~L;iltcd VOC	 1.8148 2.61J(' 

~n VOC Cl)fll()oIIlHI fib/COil dlnkllr) (1Ilv) (lblt'''Y) (1hlton elllllccr) 

IIy dwf.l. cl1 C'hloTiIJc ]J.21':-{)2 I.HJ98 2.M31 S.Il)I~·m

Kiln Mercury Com I)Olmd HmissloJl Calc.lntiolls (using Mnss lJltJnacc Appl'oac:h) 

'(lpy) (lJlIdlty)
 

Mcrc1lry (lUIIlI)' O.OOR9 lUll 27
 

MOI'tur S )«falloll (uf,)r... i
 (lilY) (lb/dllY) 

Mcrcmy (Vll(l(~l D,OOS? 0.0114
 

MCI"ClIl)' (f'M)
 (l.()()O2 OJlOO:l
 

MCl'Cln'y(l)M Il,l
 GlXXJ2 110002 

KiIDI J (fIN: 2-3, ~PN: 12) 

Krnb!lclI. EmJ!5ltll1l 

Jl"dnr",h AJU\llltlt o-'Aloe SDlIJlDn'.... 

(1Jlilon clinker) (1Ily) (lMJ•.,,) 

0.41 J~U1l94 J-45.167t1 

(1.:\5 ;lOJ)fW1 293 J 92.1 

0.2(, 22M92 220.')07) 

3f\.3tI'.J :W~1674

(Ot/lon d'hlu~r) (tpy) (Md.y) 

I.U,}~·05 (looll OJ)jOo 

4.9JH·06 0.0004 OJJQ42 

1.9(,J.!.·..()(' 0.0002 n.nO]' J.-47H-06 O.lIOOJ "(10029 

I 251l·0j 0.11011 MHOS 

I.HIi·()S 0.0015 O.1l14(, 

lli)l~.05 n.Om7 OOUiI 

1.27E-M o.O}W O.I()IW 

1.J7E·OS 0.0012 OnllS 

tinE-OS ()J)()09 o.nmn 0.10 HAR0'7 lC2.7\53 

8.5012 81.9149 

(lM"l tlil.kcr) (lll~) (JblclAY) 

231E·[)2 1.9919 19.41172 

1.02E·n2 U."X!«ltl 85871 

4.42E-(14 OO:l1i2 0.:1721 

1..\:lli-tl;l 0.1148 I.lllJ7 

3.."-)1:.-0:\ 0.292(, VlS39 

7.:\("!-O1 O.()(';I;,) O.fll% 

J.JS34 32.9!J96 

(lb/tl)tldinlull') (til)') (IMln!l 

.­ J> ...h 

(tr~') (Ih/dlly) 

0,00(\7 ()()(jSM 

(111") (1b/d"~l

O.OOM 0.0(-45 

0.0001 0001:\ 

O.(lOOI ().OOll 

•	 Emi:l.'1lt'ln fileII II1lI(\(" II~SO~ ("II kiln:c) arc lhe II.,.cl1lga hlMlrly omi.~~i(lll:lll<::ltcd during the .lnly '.].2(0). i\talOk lC8l~ ]lcrfonnoo by MBH.:O Im"it'nnltl(Jnl:U.
 

Tho cmi:\oUon flllO(UT rUT PM ror Kill' I il'llmllUll OR Ill" J'nmt·bIlU' I·M umis:till•. (Ciled dlllill!'-.hu .~cmhcrJO, 2(IIO.lIlrKlk IUl'l151"K:!"(lmlcJ by AiT SAUIIpi intt J\.<;,'\OIl)llllo-:' umnhillul WillilblJ bn!Jk-hllll"
 

I'M ...'lnj!l~icll111 (cllical..\cd II~ k>l.l PM CUli~it1tllC minlr< l'runt·hol1f cl1li!t$lon~) IUilccl d\qlftK the July I. 20tH. 3IJd: k.'l'Il1i rcrfum,cd hy METeO l;.l1Y;"lnlJlcl1\ul
 

Thc{,'U;k.'t.lO'1 f"ctm r'lf PM rllr Kiln 21K lhc llver;I~'C !If,lurly \lmi:t!CKlflIC l(lSloll dl.·lnl1 Uw Ault\l:( 2S. 201()~llCk tu.o;( pcrf'('f1l1ocJ hy METe() Hrlllirlllimunlill
 

ThccmlH!licm r.ctflt lhr PM rot' Kiln J ifol bal'iCll mllhe rl'lIll·hall·I~M ClnislI![)'u l~lal (hllill~ Ihe 1"~brual)1 ) 1,201 I,lllllet ie"" pcr{onllro b~' Air ~llI'lCllblg AStitlclulCll cmllhilllXl \¥llh the hCll:Ii.-half
 

PM 1X111l'.io.}IIS (cllkallliOlI :l!c lulallJM cDlhailXlJl nlill\l.'C li·olll·b.lr CIl11.k~lo11ll) leoctul dlllinB the July .1. 2lJ()J. sttlGt IL~~ 1)~'rnn\1cd h~ MHTCO Ellvirll!lIllL-,ITtll
 

1

1

01' TChQ r~(jl1c~l. 8WI'H~ hl,.rty ))M 1"ld I hS04 cmb!Uoll r"cl.ors II'C cO)l\'crllllllo ·IWton elh)j.:cr" lIMil~ lhe daily elinl:"r rrl.ldu(l4j(}n ~llltill\i~.
 

{thlninod ('roJD Daily (}pcrlllin~ Rcroo~ (DOR..,) rOT lllO (lay wIlen 9l:ack l(,'j,1~ weI'\} IlUrfnnucu.
 

Hrni~ion litClI(1r,; (or PM"mul PM,~ llro hll!lOd (In I\P-~2 pllr1Jouf.t6m"lIul'di~..tfihllh(mll. 

to	 1~n1i~~ioll fllCtOI'!\ 1<11" lol[lCCillled l'M mId V(X: ClOOlpl.lllWds lind IIClllTC lbe llYlon clinker valuc~ from March 2ll(l1 MAt~·[" .'iltl>p;lrl 1,1,1. cllf\lpli;mcc lc.'!l~.
 

c:-:<.:cpt Ifl!' ~ni~<'l1 rllck.-s f(lr ~"lOCillh(1II1 (II' lulal fBOI"CUJ~ r:ll1is~i{lnlt. which arc csLiJlutcd YIIlUClt
 

•	 J'(1"11(111Iltl pl.'f boor (Ibllll) clllislci(lll (M~lur: AnnUl~ 1~nil<.'Si()ns (lpy.) = (I ~1Ilir«i()n FllCltll·llh/],()url). (/1I1ll1ll1l Opcr.IOng 110l~ IlIr!)' ..!) I ChIlO Ih I fl'll:
 

F(\I'!lI.\UnJ pea" lUll Clink<.'I' (lh/tun clin~c.·) Clllillf(\llll (:K:lur: AllIIU:.) Emis!\inO:1 (Ipy) - (1':m~(1II1 Fadm lIn/trill ditlkcl'l) .. (AtI1l11",1 (JinklJr Prclllllelil>11 lillY J) J (2(XXllh 'Inll
 

d Per TCrlQ 2010 Hlnil':!tinllH ItlVCIlluC)' HllidclinL'2l, IHI-J(tlJA!lO(Jmlllllf)' 2011), lhculI'l1c MC:t~1t1 h( rr()lll.l\lIl~ 11I}]'(lU~1I A_B"Hl :11. illclllsivc 

4 h'r P'lI11d PCI hour (Ih/hr) Cf11i~!>ioll (lieu: (}J:onc SClIIun Emi!C!iioll~ (Ill/da}') =0imis!lioll l/ootOl' Iltvhl'D " (On\JIc SI,)II~(lft OfUolill{\ IlOll,... Ihrlt'....)llC xenoJl I) I (92 <.I1l~' f tr/,unc !l1.:lI:W,lll:
 

]inr \ullld por lun Clinker (1l>/tun ulilM;l.:r) cll1)slIin'lliK:lur
 

O/lll1U :-loR!iOn limi~tlllS (lh/c1ay)'" (E1.i~~jnn Fllettlr liMon clintcrl)· (OZllilC l-ie<lSUII Clinker Pro!lllcilon Ikll1fa/.l'll<: ~'~lnn I ('n.dl)' IO/(lll':lIcn:oon
 

, 'JllC 1(11111 mcmmy cmilt~n{ll'.lc{mIn :dllhrec tilnli Ctltl1hiLlCd j~ CHl.jlO"lC>llullhu Midluilliml plmll using ,,11l:1"~ halallce. :11)fll'llClch.
 

111 {lnk.'·I()dcl"l'mill~ the m':fel.'Y cOlisAiom.; rrom ca~h I;,jhl.lh~ 1(11:11 )l~I'CUI)' clllisKinll Talc /lcl'l't'l'l)rlionoo hMCd lIll elinl:cqll\tdllclion rnrcllcb Idlll
 

II Only Ihcll1l2"CllIy clIJi~sinns lhllllln: ~1"kX)inttJlllt<: I'M (oullolal mcrcu1)' cmi!l~j()(l~) llllol1lltll\':mllllc t01:11 !iPCCilllcd PM Cmilo'liion 

It hmi~~i()ll:lrlUmthc~.: Jl()l1lllool.~ WCl'C hf.:!C1\l1' delccti~1Il k.'VcI~ dorin?-lllc Morcb 2001 MACT SahpOll'lI.l.L l,;(IlnlllllllM:-C lo~l~

• Spcci:\tcd lllL're\lry I'UJlllT mul mercury j1C1I1j(llJlil(C 11I;,.'f~mlaltc f(\1 wet Idh~ om: olllni.od film' Ptlfllootl CCl11C1l1 A~'!COa\lltlllll (I'eA) rCiWSrrch <lilt! llcvcklpmcnl dOClmK:nt. 

Cr'....~';/rll;cJl' ofU~rr.I/')I f(",/.tJiOllV J.)cr/u. FiIU.'C 4-1/ (MCHlIll"r' ~"lOCjll(i()Jl rell;~Jlul!-c.~ -{Il'c"ngc~ I<l!' 1111 killlly~), peA H&n Hr.rilll No SN:1091. May 200')
 

Pl:J'lo'igul'l:: 11·17. Mcn:UIY :epcCi;lli~'fl l'<.-wet ldln~ i!l4l~ l'tl]l<w.':c:
 

MCRlnry (pllrtiQlo b,,.mli) = 2%
 

Men..'t11)' (mddi/cd) a J4'!o11
 

Ml.t"QII)' (clcmcnlaJ)= ~4%
 

I'cr St.-ctillil 2.'\ oj' lhc peA IiOCUlllC'l'lI. Plll1iclc-hllUlld IUCruilry is Ihe mCRl"~ Ihlll hil~ C(lmlcl\~l tVlICl rHr1ic.ul:l(c rmliler. :md
 

cl"ll1~nlalll'~1}UIJ' (Ihi~ lll)ll n~)di/.ul JnC,,",'f)' (f t~~ ~1.11(t~·)CIJlI11l\i... lhe Vllll{lr'ptl;l~Cl1lCl\;ury.
 

It i:-: l'm1hcl Il~!'\lmcd lhnl k5% of lnllli "articlc-b",uml n\CfCllry l:l\lIMsillll!f lire I'M)lb
 

h~L~'d tlJllbl.: di:-&trilYulionllOlwC\:11 PM anel PM1f1 .. IU'cWLllccl ill /'11'-42, Scr.;tiol\ ll.(1, T'lhlc II ,(i·5 (J;lnwIT~ 1995-) rll( \\-et l:ibt.!' lJ('uh't1/lcxl Wilh IIlI I~~P.

Ash GrOOte TC'Ilfta. L.P.
 

Midlothian Plfl\l :'i or 32 'friuity CORSlillanlS
 
Ash Grove Texas, L.P. - Midlothian Plant 

2010 Actual Emission Rate Calculations - Kilns 

Kiln NOu S0:2T CO Emission Calculations (CEMS Data) 

FIN EPN Description 

2-1 2 Kiln 1 

2-2 6 Kiln 2 

2-3 12 Kiln 3 

Total Kiln Emissions 

FIN EPN Description 

2-1 2 Kiln I 

2-2 6 Ki1n2 

2-3 12 Ki1n3 

Componnd 

NOx 

801 

CO 

NO~

S~

CO 

NH3 

NOx 

S02 

CO 

NHsJanuary 

(tons) 

February 

(tons) 

March 

(tons) 

April 

(tons) 

May 

(tons) 

Monthly Emissiousll 

J"Ql1e July 

(tons) (tons) 

August 

(tons) 

September 

(tons) 

October 

(tons) 

November 

(tons) 

December 

(tons) 

33.5323 

152.3534 

7.7135 

0.4016 

44.1461 

169.4614 

10.7627 

0.4032 

48.1654 

162.3678 

13.9956 

0.4458 

43.4702 

139.4419 

12.8902 

0.5720 

26.7770 

135.8482 

16.0617 

0.9294 

11.8456 

12.4844 

5.7893 

0.3486 

0.0000 

0.0000 

0.0000 

0.0000 

7.4070 

29.5971 

1.8684 

0.1343 

48.6827 

153.4941 

13.1474 

0.8255 

55.6257 

186.5213 

11.5784 

0.7440 

61.7826 

172.9408 

12.6943 

0.5979 

12.4596 

33.1387 

1.4946 

0.1197 

41.4193 

141.4500 

3.8157 

0.2265 

5:5.2806 

214.9901 

8.1412 

0.2050 

58.8246 

217.8229 

10.8744 

0.2708 

30.7389 

108.7478 

5.0453 

0.5081 

:53.7287 

168,6355 

11.1593 

1.5246 

58.6087 

169.9477 

10.9414 

0.8476 

47.9426 

158.6270 

7.8354 

0.2905 

68.5754 

208.3345 

12.0485 

0.4084 

3.4544 

11.9739 

0.9485 

0.0390 

44.3540 

140.4001 

7.9300 

0.3827 

67.4211 

168.8753 

10.5754 

0.3101 

11.1839 

36.9144 

1.2734 

0.0428 

0.0000 

0.0000 

0.0000 

0,0000 

0.0000 

0.0000 

0.0000 

0.0000 

O.OQOO 

0.0000 

0.0000 

0.0114 

37.5299 

100.5190 

5.4950 

0.6141 

46.0169 

125.2225 

9.2289 

1.1085 

54.3938 

125.4465 

8.1196 

0.8821 

61.2836 

57.4766 

10.9200 

1.4880 

55.2865 

114.8472 

11.9464 

0.7556 

50.2107 

228.3764 

IS.8191 

0.8699 

23.0715 

136.7936 

9.6604 

0.4437 

25.7667 

71.6868 

4.9465 

0.5189 

0.0075 

0-.0570 

0.0817 

0.0000 

NOr 

SO! 

CO 

NH3 

C2kulated A.rtnaal
 

Em~sion Factor
 

(lb/ton Compound clinker) 

NOx 3A7 

NOx 4.61 

NOx 4.10 

Emissiom 

Annual 

(tpy) 

Ozone Season1> 

(lb/day) 

394.4941 

1,407.6490 

107.99:58 

5.5219 

418.5348 

2.219.1620 

166.4696 

10.4960 

541.5319 

1,746.7191 

90.5883 

5.0559 

3.807.1011 

11,671.9380 

670.1152 

33.6186 

353.5669 

960.4256 

76,2174 

6.6921 

3,716_6054 

6~473.2674

673.6065 

67.9485 

1.289.3929 

4,114.7937 

274.8015 

11.2699 

7,942.2413 

20"'-64.3674 

1~lO_1913

112..0631 

01. Monthly emissions !L""e obtained from Continuous Emissions Monitoring (C&1S) data report, per email fromMichaelCri:ttende:n.AshGrov~toJaimeBretzmann.Trinity Consultants~ dated February 2~ 2011~ except for ammonia. 

Ammonia emissions are calculated. from ammonia CEM.$ stack tlo\VS~ and kiln up time and were provided via email from Francisco Pinto, Ash Grove, to Jaime Bretzmmm, Trinity Consultants, dated March 15,2011. 

o Per TCEQ 2010 Emissions Invemory Guidelines, RG.360AlIO (January 2011), the ozone season is _from June 1st through A~31 inclusive. 

~h ~w-t~ - 2010 

N~'/. S~~ o.'I\~ij.J. Midlothian 

Ash Grove Texas, 

Plant 

L.P. 

1 of 32 ~~ frinity Consultants