TI-D-130 

LETTER OF TRANSMITTAL 

Trigon Engineering Consultants, Inc. 

700 Blue Ridge Road, Suite 101 

Raleigh, North Carolina 27606 

(919) 755-5011 

To: Mr. Bruce C Jordan, Director 

Attn: Bill Neuffer 

Date: 

Project No. 

July 29, 1998 

046-97-048 

US EPA - Emission Standards Division 

NC Mutual Life Building Project Name Lee Brick & Tile 

411 W. Chapel Hill Street Sanford, North Carolina 

Durham, North Carolina 27701 

WE ARE SENDING YOU ~ Attached 0 Under separate cover via ______ the follo\Ning items 

COPIES DESCRIPTION 

I Letter - Information Request for Brick and Structural Clav Products Manufacturing 

I Stationarv Source Samoling Reoort- Stack Test Results for Kiln No. 2 

THESE ARE TRA..'\iSMITIED 

AS CHECKED BELOWo 

0 For Approval 

121 For Your Use 

121 As Requested 

0 For Review and Comment 

REMARKSo 

COPIES TO: 

Mr. J.R. Holton, Lee Brick & Tile, Inc. (letter only) 

Mr. Dale Overcash, Harding Lawson Associates 

SIGNED 

I 
ENGINEERING CONSULTANTS, INC. 

700 Blue Ridge Road, Suite 101 • Raleigh, NC 27606 • (919) 755·5011 • FAX (919) 755·1414 

July 29, 1998 

Bruce C. Jordan, Director 

Attn: Bill N euffer 

U S Environmental Protection Agency 

Emission Standards Division (MD-13) 

Office of Air Quality Planning and Standards 

NC Mutual Life Building 

411 W Chapel Hill Street 

Durham, NC 27701 

Phone: (919) 541-5435 

Reference: Information Request for Brick and Structural Clay Products Manufacturing 

Operations- Lee Brick and Tile, Sanford, NC 

Dear Mr. Neuffer 

Please find enclosed a copy of the stack test results performed for Kiln 2 at the Sanford, 

North Carolina facility. If you have any questions, please contact Kirk Rife of Trigon at (336) 

668-0093 or Mr. J.R. Holton of Lee Brick at (919) 774-4800. 

KLR\meg 

F :\C LIE:l T 3 601prvjects. 9 8\03 6 80 22 \EP A2. doc 

Attachments 

Yours Truly, 

TRIGON ENGINEERING CONSULTANTS, INC. --..... 

K;,~,~\\ Vice President, Environmental Affairs 

CC: Dale Overcash, Harding Lawson Associates 

J.R. Holton, Lee Brick and Tile 
Lee 

Brick 

& 

Tile 

CompanY 

Kiln 

2 

PC-1 

Stack 

Kiln 

2 

PC-2 

Stack 

sanford, 

North 

carolina 

Trig on 

Project# 

046-9'7-043 Apri1l99'7 

3 
Stationary Source Sampling Report 

Lee Brick & Tile Company 

Kiln 2 PC-I Stack 

Kiln 2 PC-2 Stack 

Sanford, North Carolina 

Trigon Project # 046-97-048 

April1997 
STATIONARY SOURCE SAMPLING REPORT 

FOR 

LEE BRICK & TILE COMPANY 

SANFORD, NORTH CAROLINA 

Kiln 2 PC-1 Stack 

Kiln 2 PC-2 Stack 

Performed by: 

Trigon Engineering Consultants, Inc. 

Environmental, Health & Safety Division 

6200 Harris Technology Blvd. 

Charlotte, North Carolina 28269 

704/598-1049 

Trigon Project # 046-97-048 

April 1997 
REPORT CERTIFICATION 

This report, all testing details, and final results have been performed under the supervision and 

reviewed by the persons named below. 

Date. _________ Signature. ____________________ _ 

Robert F. Callahan 

Project Manager 

Environmental, Health & Safety Division 

Trigon Engineering Consultants, Inc. 

Date. _________ Signature. ____________________ _ 

Paul R Jenkins, Jr. 

Quality Assurance Manager 

Environmental, Health & Safety Division 

Trigon Engineering Consultants, Inc. 

Date. _________ Signature, ____________________ _ 

u 

J.A "Tony" Blanton 

Manager 

Stack Testing Department 

Environmental, Health & Safety Division 

Trigon Engineering Consultants, Inc. 
TABLE OF CONTE:'{TS 

1.0 INTRODUCTION................ . ................................................................................. 1 

1.1 Purpose ......................................................................................................................... 1 

1.2 Outline of Test Program ............................................................................................... 1 

1.3 Test Participants ........................................................................................................... 2 

2.0 PROCESS DESCRIPTION................. . .................................................................. 3 

2. 1 Discussion....... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ................................................................ 3 

Figure 1 - Process Air Flow Schematic -No. 2 Kiln ..................................................... .4 

3.0 SAl'\-lPLING METHODS ........................................................................................................ 5 

3.1 Sampling Strategy .......................................................................................................... 5 

3.2 Sampling and Analytical Procedures .........•.................................................................... 5 

3.2.1 Sampling Ports, Traverse Points 

and Cyclonic Flow Determination .................................................................. 5 

3. 2.2 Stack Gas Velocity and Volumetric Flow Rate Detennination ...................... 6 

3. 2. 3 Dry Molecular Weight Determination ............................................................ 7 

3. 2. 4 Moisture Detennination ................................................................................. 8 

3 .2. 5 Total Fluoride Sampling and Analysis ............................................................ 9 

3.2.6 Hydrogen Fluoride Sampling and Analysis .................................................. 10 

3 .2. 7 Sampling Ports and Points ........................................................................... 11 

Location of Sampling Ports and Points 

Figure 2 - PC-1 Stack .................................................................................. 12 

Figure 3 - PC-2 Stack .................................................................................. 13 

3.3 Quality Assurance and Quality ControL ..................................................................... 14 

4.0 RESULTS ............................................................................................................................... 15 

4.1 Summary ofResults ..................................................................................................... 15 

4.2 Discussion ............................................................... : .................................................... 15 

4. 3 Detailed Stack Sam piing Results ................................................................................. 15 

Summary ofResults 

Table 1 - PC-1 Stack, Total Fluoride Sampling ........................................................... 16 

Table 2- PC-1 Stack, Hydrogen Fluoride Sampling .................................................... 17 

Table 3 - PC-2 Stack, Total Fluoride Sampling ........................................................... 18 

Table 4- PC-2 Stack, Hydrogen Fluoride Sampling .................................................... 19 

5.0 APPENDICES ........................................................................................................................ 20 

A Summary ofResults and Example Calculations 

B. Field Data Sheets 

C. Laboratory Data 

D. Production Documentation 

E. Calibration Data 

Ill 

1 
1.0 L'IITRODUCTION 

This section describes the purpose, a brief outline including the sampling and analytical strategy, and 

the personnel involved in the test program. 

1.1 Purpose 

The purpose of this sampling project was to determine concentrations and emission rates of total 

fluoride and hydrogen fluoride from two emission points associated with the No. 2 Kiln located at the 

Lee Brick and Tile Company facility in Sanford, North Carolina. The results of the sampling and the 

documentation provided in this report will be used by Lee. Brick for emission inventory purposes. 

1.2 Outline of Test Program 

Stationary source sampling was performed April 18, 1997 by the Environmental, Health & Safety 

Division of Trigon Engineering Consultants, Inc. on the No. 2 Kiln which is used to dry bricks. Three 

!-hour sampling runs were conducted simultaneously for total fluoride and hydrogen fluoride at the 

two exhaust stacks (PC-! and PC-2) which serve No. 2 Kiln. United States Environmental Protection 

Agency (US EPA) Methods 1 through 4 and Method 13B were used for the determination of total 

fluoride concentrations and emission rates. Method 26A was used for the determination of hydrogen 

fluoride concentrations and emission rates. All sampling and analytical procedures used were those 

established by the US EPA in standard reference test methods and appropriate state-of-the-art 

analytical procedures. The test runs were conducted during normal operating conditions. 

1 
1.3 Test Participants 

·A list of the project participants, titles, affiliation and telephone numbers can be found below. 

Participant 

Robert F. Callahan 

Paul R Jenkins, Jr. 

Chris B. Brooks 

Logan E. Butler 

Jason J. Tagliaferri 

John D. Archer 

David C. Stoll 

Bobby McCoy 

Title 

Project !vfanager 

Quality Assurance 

Manager 

Senior Environmental 

Scientist 

Environmental Scientist 

Environmental Scientist 

Environmental Scientist 

Environmental Scientist 

Manager Plant 

Engineering 

AITLliation 

Trigon Engineering 

Consultants, Inc. 

Trigon Engineering 

Consultants, Inc. 

Trigon Engineering 

Consultants, Inc. 

Trigon Engineering 

Consultants, Inc. 

Trigon Engineering 

Consultants, Inc. 

Trigon Engineering 

Consultants, Inc. 

Trigon Engineering 

Consultants, Inc. 

Lee Brick and Tile 

2 

Contact 

Telephone: (704) 598-1049 

Facsimile: (704) 598-1050 

•·· ........•....... ·. ......... ···············•·/·•••••·•·••> r 

i••• i ·································································· ·················· ........ 

·······i····················································} ............ ·.)······· ···••• }············ .<T < • · .····•· • ·• 2 c:< ···•••··· • __; 

r \hi .......... ·····•: r 

Telephone: (919) 774-4800 

Facsimile: (919) 774-7557 
2.0 PROCESS DESCRIPTION 

This section contains a brief description of the No. 2 Kiln and an air flow schematic. 

2.1 Discussion 

The No. 2 Kiln at Lee Brick and Tile Company dries standard 10-hole red brick for its brick 

manufacturing facility in Sanford, North Carolina. The pollutant sampling was conducted during 

normal production hours. The kiln produced brick at the optimum operating level and was fired with 

natural gas. 

The flue gases passed from the kiln to an induced draft (LD.) fan, 2 stacks (PC-I and PC-2) and to the 

atmosphere. The kiln emissions are exhausted uncontrolled to the atmosphere. Figure 1 details the air 

flow schematic of the No.2 Kiln. 

3 

!D 
No.2 Kiln 

Atmosphere Atmosphere 

t t 

Sampling Location~ I Stack ~ ~ Stack I ~Sampling Location 

t t 

ID. Fan 

t 

I Kiln I 

Figure 1 

Process Air Flow Schematic 

4 

II 
3.0 SA.c'\-IPLING METHODS 

This section describes the sampling strategy, sampling and analytical methods, and quality 

assurance/quality control procedures implemented during this project. 

3.1 Sampling Strategy 

The sampling and analytical procedures used during this test program were those established by the US 

EPA and NC DEHNR Sampling runs were conducted in triplicate to validate the sampling. Tests 

were conducted during normal operating conditions. There were no unusual conditions noted during 

the sampling. 

3.2 Sampling and Analytical Procedures 

The US EPA methods used in this sampling program were Method 1 for the iocation of sampling ports 

and polll.ts, and determlll.ation of cyclonic flow, Method 2 for volumetric flow rate determlll.ation, 

Method 3 for the determlll.ation of dry molecular weight of the stack gas, and Method 4 for the 

determlll.ation of moisture in the stack gas. Method l3B was used to determlll.e concentrations and 

emission rates of total fluoride. Method 26A was used for determlll.ation of hydrogen fluoride. A 

sampling and analysis synopsis is discussed briefly in the followlll.g subsection. These test methods are 

available in the Code ofFederal Regulations Volume 40, Part 60 or by request from Trigon. 

3.2.1 Sampling Ports, Traverse Points and Cyclonic Flow Determination 

The PC-1 and PC-2 stack sampling locations were prepared according to the criteria in Method 1. The 

duct diameters upstream and downstream from the sampling ports were determlll.ed prior to sampling. 

The number of traverse points were chosen with respect to sampling port location. For isokinetic 

traverses Method 1 specifies a minimum of 8 traverse points for sampling ports located >8/>2 

downstream/upstream stack diameters from flow disturbances and 24 traverse points when located 

>21>0.5. The amount of cyclonic flow was determlll.ed according to the criteria detailed in Method 1. 

5 
3.2.2 Stack Gas Velocity and Volumetric Flow Rate Determination 

Method 2 is used for determining the average gas velocity in a stack from measurements of gas density 

and the average velocity head with a Type S (Stausscheibe or reverse type) pitot tube. This method is 

applicable for quantifying gas flows which meet the criteria ofMethod I. Method 2 cannot be used for 

direct measurement of gas streams which exhibit cyclonic flow conditions as determined by Method I, 

Section 2.4. 

In principle measurements of velocity head and temperature are performed at the traverse points 

specified by Method I. A properly scaled differential pressure gauge was selected for the range of t.p 

values encountered during the traverse. A 0 - I 0 inches of water inclined manometer was used as the 

differential pressure gauge. 

During this project, the sampling location met all of the criteria detailed in Method I. Gas stream 

density was determined by Method 3. Moisture determination was performed by Method 4. The 

principal components of the gas velocity measurement system were sequentially: 

* A calibrated stainless steel Type S pitot tube and Type K thermocouple; 

* 

* 

* 

Leak-free interface tubing between pitot tube and differential pressure gauge; 

A 0 to I 0 inch inclined manometer and; 

An NISI traceable pyrometer. 

The apparatus was set-up according to manufacturer and reference method recommendations. Pretest 

and posttest leak checks were conducted using procedures outlined in Method 2, Section 3 .I. Velocity 

head and temperature measurements were performed at the traverse points specified by Method I. 

The atmospheric and static pressure of the stack was also determined for each set of velocity head 

readings. The volumetric flow rate calculations used were those specified in Method 2, Section 5. A 

more comprehensive explanation of the reference method is detailed in the Quality Assurance 

Handbook for Air Pollution Measurement Systems: Volume III (EP A/600/R-94/038c). 

6 

;3 
3.2.3 Dry Molecular Weight Detennination 

Method 3 is applicable for detennining carbon dioxide and oxygen concentrations and dry molecular 

weight of a sample from a gas stream of a fossil-fuel combustion process. This method may also be 

applicable to other processes where it has been detennined that compounds other than carbon dioxide, 

oxygen, carbon monoxide, and nitrogen are not present in concentrations sufficient to affect the results. 

In principle a gas sample was withdrawn from the emission source by multi-point, integrated sampling. 

The collected samples were then analyzed for percent carbon dioxide, percent oxygen, and percent 

carbon monoxide. The dry molecular weight detennination was performed by an Orsat analyzer. 

During this project, the gaseous components were collected using a Method 3 sampling system 

following the Analytical Procedures outlined in the reference method. The principal components of the 

sampling system were sequentially: 

• A stainless steel probe; 

• A one-way squeeze bulb, to transport the sample to the Tedlar bag; 

• A saturator tube to remove particulate matter and excess moisture and; 

• A leak-free Tedlar bag equipped with a double-end shut-off quick connect . 

The analysis was performed with an Orsat type combustion gas analyzer within 8 hours of sample 

collection. The dry molecular weight was calculated using Equation 3-1, Section 7 of Method 3. The 

analyzer was maintained and operated according to the instructions recommended by the manufacturer 

and in accordance with Method 3 criteria. The analyzer was leak-checked according to Section 6 of 

Method 3. The oxygen reagent was validated by analyzing a sample of ambient air which must meet 

the specifications of20.9% ± 0.3%. 

7 
3.2.4 Moisture Detennination 

Method 4 involves the detennination of stack gas moisture. The moisture content is used to correct 

the emission concentration or mass emission rate to a dry basis. EPA Method 4, Section 3.3 of the 

EPA's Quality Assurance Handbook, Volume ill, EPA-600/4-77-027b, was used to measure stack gas 

moisture content. Section 3.3 of the Quality Assurance Handbook, Volume ill, provides detailed 

information on the application of Method 4. 

Preliminary flue gas moisture content (for purposes of setting the isokinetic flow rate) was detennined 

using wet bulb/dry bulb thermometers and partial pressure, vapor and saturated vapor pressure 

equations. This technique is described in Method 4 and is summarized below: 

• 

• 

• 

• 

Moisten the wet bulb thermometer wick with deionized water; 

Insert both thermometers into the flue gas stream and monitor the wet bulb temperature; 

When the wet bulb temperature has stabilized, record both the wet bulb and dry bulb 

thermometer temperatures; 

Calculate the flue gas moisture content (PMV) using the equations below . 

SVP = Vapor Pressure ofWater at Saturation, inches of Mercury 

SVP = IaxY(6.69ll- (3144/(Wet Bulb+ 390.86))) 

PMV =Percent Moisture by Volume 

PMV = (SVP · (0.000367(P,)(Dry Bulb- Wet Bulb)(!+ ((Wet Bulb- 32)/1571))))/(P..,.) x 100 

P.o. = Absolute Pressure of Stack Gas 

P"" =(Barometric Pressure+ (Static Pressure/13.6)) 

The moisture content for emission rate calculations was detennined in conjunction with the Method 

13B and 26A isokinetic sampling trains. The reference method involves the withdrawal of gaseous and 

particulate pollutants from the emission source at an isokinetic rate using an isokinetic sampling system. 

The sampling and analytical procedure for reference Method 4 will be discussed in detail in Section 

3.2.5 with the isokinetic sampling procedures. 

8 
3.2.5 Total Fluoride Sampling and Analysis 

Testing for total fluoride was perfonned according to US EPA Method 13B. Emissions containing 

fluoride and particulate matter were withdrawn isokinetically from the emission source and collected in 

a multi component sampling train. The emission source gas stream was bubbled through a measured 

volume of deionized water in order to quantitatively separate and capture fluoride emissions. 

According to Section 7.1 of Method 13B an unheated glass filter was inserted between the third and 

fourth impingers to collect fluoride particulate matter from the gas stream. The principal components 

of the sampling system were sequentially: 

* 

* 

* 

* 

A stainless steel sample nozzle and borosilicate probe liner; 

A heated (248°F ±25°F) probe and filter bypass assembly; 

An irnpinger train consisting of four sequential impingers. The first two impingers containing 

100 mJ of deionized water followed by an empty impinger, and an unheated filter assembly. 

The fourth and final impinger contained 200 grams of indicating silica gel and; 

A metering system capable of maintaining an isokinetic sampling rate and accurately 

determining the sample volume according to those specifications in APTD-0581. 

The fluoride samples were recovered by measuring the liquid in the first three impingers to the nearest 

milliliter and recording the data on the moisture detennination fonn. This solution was transferred to a 

high density polyethylene storage container. The filter was then removed and added to same storage 

container. The back half of the sampling train, filter assembly, and connecting glassware was 

quantitatively rinsed with deionized water and added to the sample storage container. The resulting 

solution was diluted to 500 mJ with deionized water. All volumetric data was recorded on the sample 

recovery forms. All sample containers were sealed and the liquid level marked. Chain of custody 

documentation commenced at this time. 

Blanks of the absorbing solution and rinsing reagent were submitted and analyzed with the samples. 

Samples were blank corrected for any background analyte concentrations. The samples and 

appropriate blanks were analyzed in-house by Trigon Engineering Consultants, Inc. Sample analysis 

was perfonned using the ion selective electrode procedure detailed in Method 13B. 

9 

;h 
3.2.6 Hydrogen Fluoride Sampling and Analysis 

Testing for hydrogen fluoride was performed according to EPA Method 26A Gaseous and particulate 

pollutants were withdrawn isokinetically from the emission source and collected in a multi component 

sampling train. In principle, particulate matter includes any material that was condensed at or above 

the filtration temperature of approximately 250 degrees Fahrenheit and was collected on a quartz filter. 

The gaseous components were then bubbled through a measured volume of 0 IN sulfuric acid and 

O.!N sodium hydroxide to determine the moisture, and hydrogen fluoride content of the emission 

source. The principal components of the sampling system were sequentially: 

* A borosilicate glass sample nozzle and probe linet;; 

* A heated (248°F ±250f) probe and filter assembly with quartz filter; 

* 

* 

An impinger train consisting of four sequential impingers. Impingers one and two containing 

100 ml each of an absorbing solution consisting of dilute sulfuric acid (O.!NH2S04). Impinger 

three contained 100 ml of dilute sodium hydroxide (O.!N NaOH) followed by an impinger 

containing 200 grams of silica gel; and 

A metering system capable of maintaining an isokinetic sampling rate and accurately 

determining the sample volume according to those specifications in APID-0581. 

Sample clean up began immediately after each test run. Hydrogen fluoride was collected in the O.!N 

sulfuric acid solution in impingers one and two. The liquid in these impingers was measured to the 

nearest milliliter. The collected sample was placed in a glass storage container along with the deionized 

water rinse of impingers one and two and connecting glassware. The container was sealed and the 

liquid level was marked. The O.!N sodium hydroxide solution in impinger three was used as a scrubber 

to protect the sampling console. The liquid in this impinger was measured to determine the moisture 

content and later discarded. The hydrogen fluoride sample container was sealed and the liquid level 

marked. The samples were then shipped to Enthalpy Analytical, Inc., Raleigh, North Carolina with 

chain of custody documentation where they were analyzed by ion chromatography. The moisture 

collected by the silica gel in the fourth impinger was determined to the nearest 0.1 gram. All collected 

condensate measurements were recorded on the moisture determination and sample analysis data 

recovery form. The particulate matter sample was also discarded. 

10 

17 
3.2. 7 Sampling Ports and Points 

The dimensions of each stack and the location of the sampling ports and points are detailed in Figures 2 

and 3. Method 1 sampling criteria was maintained. The stack cross sections were divided into the 

appropriate number of equal areas. The ports were labeled A and B. During the runs each point was 

sampled for a specified period of time, which yielded a total test time of 60 minutes per run. 

11 
No.2 Kiln PC-1 Stack 

Not to Scale 

Figure2 

Location of Sampling Ports and Points 

12 
No. 2 Kiln PC-2 Stack 

Not to Scale 

Figure 3 

Location of Sampling Ports and Points 

13 
;)_( 
3.3 Quality Assurance and Quality Control 

Trigon Engineering Consultants, Inc., has established quality assurance and quality control (QA/QC) 

guidelines for providing the highest quality sampling and analytical data from source tests. These 

QAJQC procedures were implemented to ensure the acceptability and reliability of the data generated. 

In summary, a high degree of data quality was maintained throughout this project. All leak checks and 

isokinetic QA criteria were met. Each sampling train was leak checked prior to and immediately after 

sampling. Leak rates for all of the isokinetic sampling trains were less than the maximum criterion of 

0.02 cubic feet per minute. All sampling rates were also within the 100% ±10% criterion established 

for isokinetic sampling. Quality control procedures for Methods 13B and 26A have included the 

analysis of reagent blank, spikes and laboratory control samples. The quality assurance samples are 

reported in Appendix C with the laboratory data. 

Field data and final laboratory results were entered into Trigon's Air Quality Data System by an 

environmental scientist, independently audited by the Project Manager, and reviewed by the Quality 

Assurance Manager for verification of data. After QC review by the QA Manager, the Department 

Manager verified the final report for completeness and reasonableness of data. The report was 

returned to the Project Manager for review and preparation of the final draft. The report requires the 

signature of the Project Manager, QA Manager, and the Department Manager before release to the 

client. Data and final reports are archived in a secured area for a minimum period of three years. 

Trigon's field and laboratory test equipment has been maintained and calibrated in accordance with 

quality assurance procedures established by the US EPA in the Quality Assurance Handbook for Air 

Pollution Measurement Systems: Volume III. Equipment calibrations including pre-test and post-test 

calibration data are presented in Appendix E. 

14 
4.0 RESULTS 

This section presents the mean total fluoride and hydrogen fluoride sampling results. Tabular results 

are also provided to present data from individual sampling runs collected during this project. Detailed 

sampling results and example calculations for the test program can be found in Appendix A Field data 

sheets and sample recovery documentation are presented in Appendix B. 

4.1 Summary of Results 

The table below is a synopsis of the total fluoride and hydrogen fluoride sampling conducted at the No. 

2 Kiln, PC-1 and PC-2 Stacks. 

Pollutant, lbslhr PC-1 Stack PC-2 Stack 

Total Fluoride !.09 2.85 

Hydrogen Fluoride 0.99 2.56 

4.2 Discussion 

The results from this sampling project will be used by Lee Brick & Tile Company for emission 

inventory purposes. 

4.3 Detailed Stack Sampling Results 

Tables 1, 2, 3 and 4 present the data from individual sampling runs at PC-1 and PC-2 Stacks. Included 

in these tables are gas velocity and volumetric flow rates, exhaust gas temperatures, and total fluoride 

and hydrogen fluoride catch, concentrations, and emission rates. 

15 
TABLE! 

Summary of Results, Total Fluoride Sampling 

PC-1 Stack 

Run Number 1 2 

Date 04/18/97 04/18/97 

Sample Identification 7048-01 7048-02 

Run Duration, Minutes 60 60 

Sample Time, 24-hour clock 0933-1115 1220-1324 

Percent Isokinetic 99.5 101.8 

Volume of Gas Sampled, 53.09 39 04 

dry standard cubic feet*(DSCF) 

Average Stack Temperature, °F 301.3 306.2 

Stack Gas Velocity, feet/second 22.3 20.8 

Stack Gas Flow Rate, 6440 5922 

dry standard cubic feet/minute*(DSCFM) 

Stack Gas Flow Rate, 9877 9201 

actual cubic feet/minute(ACFM) 

Total Fluoride: 

Catch, mg 66.4 60.5 

Concentration, grains/dscf* 0.0193 0.0239 

Emission Rate, lbslhr 1.06 1.21 

* 68°F, 29.92 Inches Hg 

16 

3 Avg. 

04/18/97 

7048-03 

60 

1432-1537 

101.6 101.0 

51.56 47.90 

286.5 298.0 

21.0 21.4 

6125 6162 

9274 9451 

63.8 63.6 

0.0191 0.0207 

1.00 1.09 
TABLE2 

Summary of Results, Hydrogen Fluoride Sampling 

PC-1 Stack 

Run Number 1 2 3 

Date 04/18/97 04/18/97 04/18/97 

Sample Identification 7048-08 7048-09 7048-10 

Run Duration, :Minutes 60 60 60 

Sample Time, 24-hour clock 0933-1115 1220-1324 1432-1537 

Percent Isokinetic 102.0 98.0 96.2 

Volume of Gas Sampled, 48.38 47.81 46.19 

dry standard cubic feet*(DSCF) 

Average Stack Temperature, °F 295.6 298.5 282.6 

Stack Gas Velocity, feet/second 19.8 20.1 19.2 

Stack Gas Flow Rate, 5621 5783 5691 

dry standard cubic feet/minute*(DSCFM) 

Stack Gas Flow Rate, 8731 8871 8492 

actual cubic feet/minute(ACFM) 

Hydrogen Fluoride: 

Catch, mg 68.159 68.170 52.208 

Concentration, grains/ dscf* 0.022 0.022 0.017 

Emission Rate, lbslhr 1.05 1.09 0.85 

* 68°F, 29.92 Inches Hg 

17 

Avg. 

98.7 

47.46 

292.2 

19.7 

5698 

8698 

62.846 

0.020 

0.99 
TABLE3 

Summary ofResults, Total Fluoride Sampling 

PC-2 Stack 

Run Number 1 2 

Date 04/18/97 04118/97 

Sample Identification 7048-04 7048-05 

Run Duration, Minutes 60 60 

Sample Time, 24-hour clock 0933-1114 1220-1325 

Percent Isokinetic 100.4 104.8 

Volume of Gas Sampled, 54.88 38.61 

dry standard cubic feet*(DSCF) 

Average Stack Temperature, °F 404.9 395.7 

Stack Gas Velocity, feet/second 51.7 50.8 

Stack Gas Flow Rate, 12901 12770 

dry standard cubic feet/minute*(DSCFM) 

Stack Gas Flow Rate, 22853 22433 

actual cubic feet/minute(ACFM) 

Total Fluoride: 

Catch, mg 89.6 66.7 

Concentration, grains/dscf* 0.0251 0.0266 

Emission Rate, lbs/hr 2.78 2.91 

* 68°F, 29.92 Inches Hg 

18 

3 Avg. 

04/18/97 

7048-06 

60 

1432-1537 

1039 103.0 

52.74 48.74 

416.8 405.8 

49.3 50.6 

11974 12548 

21782 22356 

94.9 83.7 

0.0277 0.0265 

2.84 2.85 
TABLE4 

Summary of Results, Hydrogen Fluoride Sampling 

PC-2 Stack 

Run Number 1 2 3 

Date 04/18/97 04/18/97 04/18/97 

Sample Identification 7048-11 7048-12 7048-13 

Run Duration, .Minutes 60 60 60 

Sample Time, 24-hour clock 0936-1116 1220-1325 1432-1537 

Percent Isokinetic 99.5 99.7 103.0 

Volume of Gas Sampled, 54.00 53.34 51.76 

dry standard cubic feet*(DSCF) 

Average Stack Temperature, °F 398.8 391.4 411.8 

Stack Gas Velocity, feet/second 50.4 49.0 47.9 

Stack Gas Flow Rate, 12642 12458 11705 

dry standard cubic feet/minute*(DSCFM) 

Stack Gas Flow Rate, 22281 21661 21155 

actual cubic feet/minute(ACFM) 

Hydrogen Fluoride: 

Catch, mg 87.497 75.711 88.263 

Concentration, grains/ dscf* 0.025 0.022 0.026 

Emission Rate, lbslhr 2.70 2.33 2.63 

* 68°F, 29.92 Inches Hg 

19 

Avg. 

100.7 

53.03 

400.7 

49.1 

12268 

21699 

83.824 

0.024 

2.56 
5.0 APPENDICES 

This section contains detailed supportive documentation that encompasses all aspects of the emission 

test program. Its contents serve as the foundation for the test report. The emission test report presents 

a summary of the information gathered during the sampling activities. The information contained in the 

appendices is necessary to facilitate the review of the emission test report and determine whether 

proper procedures were used to accomplish the test plan objectives. 

Defensible data and the subsequent pollutant concentrations and emission rates is one of the primary 

objectives of any emission test program. To this end, all r.esults, example calculations, field data sheets, 

sample recovery, laboratory results, chain of custody documentation, and equipment calibrations have 

been provided to support these objectives. 

20 
APPENDIX A 

SUMMARY OF RESULTS AND LX&'HPLE CALCULATIONS 

•'·} 

'• 

A-I 
SUM[\1ARY OF RESlJL.TS 

EPA METHOD 13B 

Determination of Total Fluoride Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-1 

Run Number 1 2 3 Avg 

Date: 04/18/97 04/18/97 04/18/97 

TT Net Time of Test, minutes 60 60 60 

PB Barometric Pressure, in. Hg 29.41 29.38 29.35 29.38 

SP Static Pressure, in. Hg -0.008 -0.008 -0.008 -0.008 

PS Stack Pressure, Absolute, in. Hg 29.402 29.372 29.342 29.372 

VM Actual Meter Volume Sampled, cu. ft. 52.89 39.44 52.40 48.24 

DH Avg. Delta H, in. H20 2.7 1.4 2.5 2.2 

TM Avg. Gas Meter Temp., Deg. F 60.7 65.7 69.8 65.4 

VSTD Volume Sampled at Stand. Cond., cu. ft. 53.09 39.04 51.56 47.90 

vw Volume of Water Collected, m1 51.1 42.4 55.1 49.5 

VMV Volume of Water Vapor at Std. Cond., SCF 2.41 2.00 2.59 2.33 

Bws Moisture Content of Gas Stream 0.043 0.049 0.048 0.047 

PMV Percent Moisture in Stack 4.3 4.9 4.8 4.7 

MFD Mole Fraction of Dry Gas 0.957 0.951 0.952 0.953 

P02 Percent Oxygen, Dry 19.0 18.5 18.8 18.8 

PC02 Percent Carbon Dioxide, Dry 1.4 1.9 1.5 1.6 

PCO Percent Carbon Monoxide, Dry 0.0 0.0 0.0 0.0 

MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 28.984 29.044 28.992 29.007 

MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.508 28.507 28.466 28.493 

CP Pi tot Tube Constant 0.84 0.84 0.84 0.84 

DPS Avg. Sqrt. Delta P, in. H20 0.33 0.30 0.31 0.31 

TS Avg. Stack Temp., Deg. F 301.3 306.2 286.5 298.0 

vs Avg. Stack Velocity, ft/sec 22.3 20.8 21.0 21.4 

AS Area Stack, ft2 7.37 7.37 7.37 7 

A-2 

30 
SillvfMARY OF RESULTS 

EPA METHOD 13B 

Determination of Total Fluoride Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-1 

QS Gas Volume Flow, Dry Std. Cond. CFM 6440 5922 6125 6162 

QA Actual Gas Volume Flow, CFM 9877 9201 9274 9451 

QSW Gas Volume Flow, Wet Std. Cond., CFM 6732 6225 6433 6463 

DN Sample Nozzle Diameter, inches 0.432 0.382 0.432 0.415 

At~ Area of Nozzle, ft2 0.00102 0.00080 0.00102 0.00094 

PERI Percent Isokinetic 99.5 101.8 101.6 101.0 

Fluoride Concentrations and Emission Rates 

FMF Catch,mg 66.4 60.5 63.8 63.6 

CAN Concentration, gr/dscf 0.0193 0.0239 0.0191 0.0207 

CAT Concentration, gr/acf 0.0126 0.0154 0.0126 0.0135 

CAW Emission Rate, lbs/hr 1.06 1.21 1.00 1.09 

•. 

A-3 

.3/ 
SUMMARY OF RESULTS 

EPA METHOD 26A 

Determination of Hydrogen Halide and Halogen Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-1 

Run Number 1 2 3 Avg 

Date: 04/18/97 04/18/97 04/18/97 

TT Net Time of Test, minutes 60 60 60 

PB Jarometric Pressure, in. Hg 29.41 29.38 29.35 29.38 

SP Static Pressure, in. Hg -0.008 -0.008 -0.008 -0.008 

PS Stack Pressure, Absolute, in. Hg 29.402 29.372 29.342 29.372 

VM Actual Meter Volume Sampled, cu. ft. 48.56 48.46 47.15 48.06 

DH Avg. Delta H, in. H20 2.4 2.3 2.2 2.3 

TM Avg. Gas Meter Temp., De g. F 64.1 68.7 71.7 68.2 

VSTD Volume Sampled at Stand. Cond., cu. ft. 48.38 47.81 46.19 47.46 

vw Volume of Water Collected, mi 68.5 49.0 39.7 52.4 

VMV Volume of Water Vapor at Std. Cond., SCF 3.22 2.31 1.87 2.47 

Bws Moisture Content of Gas Stream 0.062 0.046 0.039 0.049 

PMV Percent Moisture in Stack 6.2 4.6 3.9 4.9 

MFD Mole Fraction of Dry Gas 0.938 0.954 0.961 0.951 

P02 Percent Oxygen, Dry 19.0 18.5 18.8 18.8 

PC02 Percent Carbon Dioxide, Dry 1.4 1.9 1.5 1.6 

PCO Percent Carbon Monoxide, Dry 0.0 0.0 0.0 0.0 

MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 28.984 29.044 28.992 29.007 

MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.298 28.536 28.565 28.466 

CP Pitot Tube Constant 0.84 0.84 0.84 0.84 

DPS Avg. Sqrt. Delta P, in. H20 0.29 0.29 0.28 0.29 

TS Avg. Stack Temp., Deg. F 295.6 298.5 282.6 292.2 

vs Avg. Stack Velocity, ft/sec 19.8 20.1 19.2 19.7 

AS Area Stack, ft2 7.37 7.37 7.37 7.37 

A-4 

3~ 
SUMMARY OF RESULTS 

EPA METI-IOD 26A 

Determination of Hydrogen Halide and Halogen Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-1 

QS Gas Volume Flow, Dry Std. Cond. CFM 5621 5783 5691 5698 

QA Actual Gas Volume Flow, CFM 8731 8871 8492 8698 

QSW Gas Volume Flow, Wet Std. Cond., CFM 5995 6062 5921 5993 

DN Sample Nozzle Diameter, inches 0.436 0.436 0.436 0.436 

AN Area of Nozzle, ft2 0.00104 0.00104 0.00104 0.00104 

PERI Percent Isokinetic 102.0 98.0 96.2 98.7 

Hydrogen Fluoride Analysis 

FMF Hydrogen Fluoride Catch, mg 68.159 68.170 52.208 62.846 

CAI"\1 Hydrogen Fluoride Concentration, gr/dscf 0.022 0.022 0.017 0.020 

CAT Hydrogen Fluoride Concentration, gr/acf 0.014 0.014 0.012 0.013 

CAW Hydrogen Fluoride Emission Rate, lbs/hr 1.05 1.09 0.85 0.99 

'• 

A-5 
SUMMARY OF RESu'LTS 

EPA METHOD 13B 

Determination of Total F1uoride Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-2 

Run Number 1 2 3 Avg 

Date: 04/18/97 04/18/97 04/18/97 

TT Net Time of Test, minutes 60 60 60 

PB Barometric Pressure, in. Hg 29.41 29.38 29.35 29.38 

SP Static Pressure, in. Hg -0.028 -0.028 -0.028 -0.028 

PS Stack Pressure, Absolute, in. Hg 29.382 29.352 29.322 29.352 

VM Actual Meter Volume Sampled, cu. ft. 55.10 39.32 54.17 49.53 

DH Avg. Delta H, in. H20 2.9 1.5 2.8 2.4 

TM Avg. Gas Meter Temp., Deg. F 64.9 70.0 75.8 70.2 

VSTD Volume Sampled at Stand. Cond., cu. ft. 54.88 38.61 52.74 48.74 

vw Volume of Water Collected, m1 72.3 52.0 82.4 68.9 

VMV Volume of Water Vapor at Std. Cond., SCF 3.40 2.45 3.88 3.24 

Bws Moisture Content of Gas Stream 0.058 0.060 0.069 0.062 

PMV Percent Moisture in Stack 5.8 6.0 6.9 6.2 

MFD Mole Fraction of Dry Gas 0.942 0.940 0.931 0.938 

P02 Percent Oxygen, Dry 17.9 18.0 17.7 17.9 

PC02 Percent Carbon Dioxide, Dry 2.3 2.0 2.5 2.3 

PCO Percent Carbon Monoxide, Dry 0.0 0.0 0.0 0.0 

MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.084 29.040 29.108 29.077 

MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.437 28.382 28.347 28.389 

CP Pitot Tube Constant 0.84 0.84 0.84 0.84 

DPS Avg. Sqrt. Delta P, in. H20 0.71 0.70 0.67 0.69 

TS Avg. Stack Temp., Deg. F 404.9 395.7 416.8 405.8 

vs Avg. Stack Velocity, ft/sec 51.7 50.8 49.3 50.6 

AS Area Stack, ft2 7.37 7.37 7.37 7.37 

A-6 
SUMi\1A.R Y OF RESULTS 

EPA METHOD 13B 

Determination of Total Fluoride Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2PC-2 

QS Gas Volume Flow, Dry Std. Cond. CFM 12901 12770 11974 12548 

QA Actual Gas Volume Flow, CFM 22853 22433 21782 22356 

QSW Gas Volume Flow, Wet Std. Cond., CFM 13700 13579 12855 13378 

DN Sample Nozzle Diameter, inches 0.309 0.255 0.309 0.291 

AN Area of Nozzle, ft2 0.00052 0.00035 0.00052 0.00047 

PERl Percent Isokinetic 100.4 104.8 103.9 103.0 

Fluoride Concentrations and Emission Rates 

FMF Catch, mg 89.6 66.7 94.9 83.7 

CAN Concentration, gr/dscf 0.0251 0.0266 0.0277 0.0265 

CAT Concentration, gr/acf 0.0142 0.0151 0.0152 0.0149 

CAW Emission Rate, lbs/hr 2.78 2.91 2.84 2.85 

A-i 
SUMMARY OF RESliL TS 

EPA METHOD 13B 

Determination of Total Fluoride Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-2 

Example Calculations Run 1 

Stack Pressure, Absolute, in. Hg 

PS = PB + SP = 

Volume Sampled at Stand. Cond., cu. ft. 

17.647 • VM • (PB + DH /13.6) 

VSTD = ------------------------------ = 

Thf + 460 

Volume of Water Vapor at Std. Cond., SCF 

VMV = 0.04709 • VW = 

Moisture Content of Gas Stream 

VMV 

Bvvs = --------------------------------- = 

VSTD+VMV 

Percent Moisture in Stack 

lOO*VMV 

PMV == -------------------- = 

VSTD+VMV 

Mole Fraction of Dry Gas 

100-PMV 

~ == ------------------ = 

100 

Mole. WL Stack Gas, Dry Basis, lbllb mole 

MD == 0.44 • %C02 + 0.32 • %02 + 0.28 • (100- %C02- %02) = 

Mole. Wt. Stack Gas, Wet Basis, lbllb mole 

MW = MD • (1 - Bvvs) + 18.0 • Bvvs = 

Avg. Stack Velocity, ft/sec 

(TS + 460) 

VS == 85.49 • CP • DPS • SQRT ---------- == 

(PS • MW) 

A-8 

29.382 

54.88 

3.40 

0.058 

5.8 

0.942 

29.084 

28.437 

51.7 
SL~IMARY OF RESl:L.TS 

EPA METHOD 13B 

Determination of Total Fluoride Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-2 

Gas Volume Flow, Dry Std. Cond. CFM 

1058.82 * VS *AS* PS * (1- Bws) 

QS = -------= 

TS + 460 

Actual Gas Volume Flow, CFM 

QA=VS*AS*60= 

Gas Volume Flow, Wet Std. Cond., CFM 

QSW = QS • (1/(1-Bws)] = 

Area of Nozzle, ft2 

AN= ((ON /2)"'2 * 3.14159)/144 = 

Percent Isokinetic 

0.0945 * (TS + 460) • VSTD 

PERI=------------= 

TT * VS • PS * (1 - Bws) • AN 

Concentration, gr/dscf 

(At Standard Conditions) 

CAl"! = 0.0154 * FMF I VSTD = 

Emission Rate, lbs!hr 

(At Standard Conditions) 

CAW = 0.00857 • CAN • QS = 

Standard Conditions 68 Deg. F, 29.92 in. Hg 

A·9 

12901 

22853 

13700 

0.00052 

100.4 

0.0251 

278 

37 
SUMMARY OF RESULTS 

EPA N!ETI!OD 26A 

Determination of Hydrogen Halide and Halogen Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-2 

Run Number 1 2 3 Avg 

Date: 04/18/97 04/18/97 04/18/97 

TT Net Time of Test, minutes 60 60 60 

PB Barometric Pressure, in. Hg 29.41 29.38 29.35 29.38 

SP Static Pressure, in. Hg -0.028 -0.028 -0.028 -0.028 

PS StackPressure,Absolute,in. Hg 29.382 29.352 29.322 29.352 

VM Actual Meter Volume Sampled, cu. ft. 54.00 54.03 52.84 53.62 

DH Avg. Delta H, in. H20 2.9 2.8 2.6 27 

TM Avg. Gas Meter Temp., Deg. F 62.8 68.9 72.3 68.0 

VSTD Volume Sampled at Stand. Cond., cu. ft. 54.00 53.34 51.76 53.03 

vw Volume of Water Collected, ml 73.6 65.5 80.0 73.0 

VMV Volume of Water Vapor at Std. Cond., SCF 3.46 3.08 3.77 3.44 

Bws Moisture Content of Gas Stream 0.060 0.055 0.068 0.061 

PMV Percent Moisture in Stack 6.0 5.5 6.8 6.1 

MFD Mole Fraction of Dry Gas 0.940 0.945 0.932 0.939 

P02 Percent Oxygen, Dry 17.9 18.0 17.7 17.9 

PC02 Percent Carbon Dioxide, Dry 2.3 2.0 2.5 2.3 

PCO Percent Carbon Monoxide, Dry 0.0 0.0 0.0 0.0 

MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.084 29.040 29.108 29.077 

MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.416 28.437 28.355 28.402 

CP Pi tot Tube Constant 0.84 0.84 0.84 0.84 

DPS Avg. Sqrt. Delta P, in. H20 0.69 0.68 0.65 0.67 

TS Avg. Stack Temp., Deg. F 398.8 391.4 411.8 400.7 

vs Avg. Stack Velocity, ft/sec 50.4 49.0 47.9 49.1 

AS Area Stack, ft2 7.37 7.37 7.37 7.37 

A-10 
SUMMARY OF RESl..JL TS 

EPA METHOD 26A 

Determination of Hydrogen Halide and Halogen Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2PC-2 

QS Gas Volume Flow, Dry Std. Cond. CFM 12642 12458 11705 12268 

QA Actual Gas Volume Flow, CFM 22281 21661 21155 21699 

QSW Gas Volume Flow, Wet Std. Cond., CFM 13453 13178 12556 13062 

DN Sample Nozzle Diameter, inches 0.311 0.311 0.311 0.311 

AN Area of Nozzle, ft2 0.00053 0.00053 0.00053 0.00053 

PERI Percent Isokinetic 99.5 99.7 103.0 100.7 

Hydrogen Fluoride Analysis 

FMF Hydrogen Fluoride Catch, mg 87.497 75.711 88.263 83.824 

CAN Hydrogen Fluoride Concentration, gr/dscf 0.025 0.022 0.026 0.024 

CAT Hydrogen Fluoride Concentration, gr/acf 0.014 0.013 O.D15 0.014 

CAW Hydrogen Fluoride Emission Rate, lbs/hr 2.70 2.33 2.63 2.56 

A-ll 

37 
SL~llv1ARY OF RESuLTS 

EPA METHOD 26A 

Determination of Hydrogen Halide and Halogen Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-2 

Example Calculations Run 1 

Stack Pressure, Absolute, in. Hg 

PS == PB + SP == 

Volume sam~lf.g,f7 s~-*c(IJW.+clJrh 13_6) 

VSID == -------------------------------------------------- == TM+460 

Moisture Conte~as Stream 

Bvvs == ---------------------------------- == VSID+~ 

Percent Mo%W~' ~~ck 

p~ == --------------------------- == 

VSID+~ 

Mole Fraction of Dry Gas 

100-P~ 

~ == ----------------------- == 

100 

Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 

MD == 0.44 * %C02 + 0.32 * %02 + 0.28 * (100 - %C02- %02) == 

Avg. Stack Velocity, ft/sec 

(TS + 460) 

VS == 85 49 * CP * DPS * SQRT -------------------- == . (PS * MW) 

A-12 

29.382 

54.00 

3.46 

0.060 

6.0 

0.940 

29.084 

28.416 

50.4 
SUMMARY OF RESULTS 

EPA METHOD 26A 

Determination of Hydrogen Halide and Halogen Emissions 

Lee Brick & Tile Company 

Sanford, North Carolina 

Kiln 2 PC-2 

Gas Volume Flow, Dry Std. Cond. CFM 

1058.82 * VS *AS* PS * (1- Bws) 

QS = ----------------------------------------------- = TS + 460 

Actual Gas Volume Flow, CFM 

QA=VS*AS*60= 

Gas Volume Flow, Wet Std. Cond., CFM 

QSW = QS * [1/(1-Bws)] = 

Area of Nozzle, ft2 

AN= ((DN /2) A 2 * 3.14159)/144 = 

Percent !so kinetic 

0.0945 * (TS + 460) * VSTD 

PEFti = ------------------------------------------ = TT * VS * PS * (1- Bws) *AN 

Hvdrogen Fluo.ride.Con~entration, gr/dscf (At ::stanoarocondltJons J 

CAN = 0.0154 * FMF I VSTD = 

Hydrogen Fluoride Emission Ftate, lbs/hr 

(At Standard Conditions) 

CAW = 0.00857 * CAN * QS = 

Standard Conditions 68 Deg. F, 29.92 in. Hg 

A-13 

12642 

22281 

13453 

0.00053 

99.5 

0.0250 

2.70 
APPE.'iDIX B 

FIELD DATA SHEETS 

B-l 
EPA Method I 

Detennination of Sampling Ports and Points 

Oieot L?t G .. s.k c-0 :t \ P 

Sampling LDcatioo (.I., ?.. PC..-.; \ 

Sampling Location Dimensions: 

From Far Wall to Outside of Port 51.J · 7 S 

Nipple Length 0 

Depth of Duct 31.1. "15 ,. 

Width (Rectangular Duct) _ _;r_J_f. __ 

Equivalent Diameter Calculation (DE): 

Z x Leo•tb x W'odtb 2 ( / ) ( / 

City/State Sc ,, ,f; c 2 

Date G" < 'i l 

\ I . I D!Si1.1RBANCZ~ !-

1 I I 

SAMPUNC _ 

LOCArloN I 

I

' • II 

'~ ,o i- ~ 

LJ_ 

ill , DE = ----- = ------ =_,_/',..:/f..;_, _ K II ! _Q~ · 

I 

DIS'I'URBANC!: \~ 

Distance to Ports From Nearest F1ow Disturbance! 

Upstream · A Downstream · B 

., ~" '=---'• ·~?:'' .n Dimensions in Inches {.:J -r.; u ..-r-" 1 ,(..-'· 1 

Duct Diameter> ,)D ~-~ 3 . .,-j 

Stack Area. in Square Feet 7. 3 7 

Calculations By _:£!.:::._•'?:::..__ ____ _ ScMnuzlic of Sampling Location 

Poinr . Nippl• DIS&aicr From 

~ .. St.dc:.ID m Leo om Outsid .. oC Port 

I 21 3(,.1S" 6.77-+/ 00 0 I. OC> 

2. 0.1 1,\o .lS" 2.L{(o " 2 . "{ (., 

J I I & ')G 1\ 'iT D '1.3'-i 

'1 tl.l j (,. .11"" C:... )o D v. <;U 

s- 1).o I "i 0 1 t'i 

(, 3(".<., 13.08 0 13.08 

I Vi. 3r..ls 23. I 0 2.3 (p l 

6 1S".o 1t.. 7s )I. ')<,. 0 :tl.((.. 

'i B.L > "'k· 7\ ?:.c. 1. ,.- p ?,c. 2,(' 

( u 1(-e L :3<,.75 ~2....'1{ ~ )2-. ~ ( 

f3.3 .7\' )i . 2 'i 0 1i . '2-'7 

ll- 'P "i ,~.,,7)' )f. 'i A ..; ;o; ?(' 0 ";;', ,( 

@ 

I 
• 

.Cr.-... .~J.dllUU -

Determination of Stack Gas Velocity, Volumetric Flow Rate and Cyclonic Flow 

Gient C,.""€ BIZtct<= ·' {;u,£' 

Sampling Lcc>LJOn ;!,<.A 2 f'c - I 

Run D>ee <I- /e -17 

Barometric Pressu~. in. Hg _ _.:;::2.;;..1_ ....;.'1_1 ______ _ 

S<><ic Pressure. in. H,O _-...;.o:...:...· ':..:'---------

S<atic Pressure. in. Hg _-_o_._oc...;..:;S ________ _ 

Stack Pressure. in. Hg -.,-.....="2...;.'.;..· <1'-'o'-'z."------=---

Stack Dimension~ in .• di:uneter/side 1 3(. .?S 

City. StJ.te 5.-...J~oiZb Ale. 

Oper:nors G"L§ , JoA 

Tune o o 

Pitot Tube I.D. No. -.:;2.:..:•.::."'-;·..:o:,:z:..:S"--------

Date Cllibr:ned --="':..;;,t-/..:•-'J,t-/.:...1.;..7-:::--:-------

Pitot Tube Coefficient ___ c...;.. B::....;,</,---.,.-:----

Leak Cleek. in. H,O <0.1 @ 8.7 .> </. I 

Side 2. in.---------------

Field Data 

Tr:t.nrse Vdodtr Head .1p fnd'ies. Sladt Cvdonlc Flow Ofienninaelon 

P~nt u,o TempenJureT 

."lumber ~- at o- R.t'f'ft'ftlC8 Antle wtlldl Yldds a. Sun .1D· 

( o.o/8 o.oe "2 <lfc "253 0. /C., o.es l't z.e, 

z o.o'l C!.o'l '2. '18 2-!>i. 0 ,(.,. o. II I I !'I 

3' C./0 0. /7. z.'/7 r.5s0. '" 

o.o' fu /1... 

y o./o 0./2 "2.$b "255 0 .I/ ll.oS 0 5 I 

s 0.10 C .12. '2.</(. 2.54 {)./0 0.07 tO 0 

" 0./ <.) ().(/ '2-t/7 'Z. 5" I o.oo {),a~ ,5 17 

7. 0.1 I (J./0 v(1 '253 o.oS 0 .0"" /7 "2.2. 

~ I CJ./ I 0.10 "2 5 S'"" 2.5! o.a~ a .o1 z.c.. !>/ 

'I 0 .1{ ().C~ 7. 57 2. !:i5 ~ !0 ~-IZ 33 7."2. 

(Q o.<t.'T l!.cS "2.5'7 2.5! 0.// ().!] 7.1 '2.!) 

II o.og c.c'- ""Z'!i~ :2..$5" ". (0 f) .f <I :z.G. z.:; 

17.- 0-07 ~-clo ZS"< 2..5'1 t) .10 D.!'/ if! s.J 

I 

o.cfl~ z.5z.. . /9.5° 

Ann ... 

Stack Temper:lture, Dry. "F (A) l '7 "2.-

Difference (A· B) 1.-z... 

Stack Temper:nure. Wet "F (B) __ ,:_1.:.,1 ..:;o __ _ 

Preliminary Pereent Moisture-----=·(.,~---

Commen~-------------------------------------------------------------

®~J'k Dale: 'f I Z.l I '! 7 B-3 
EPA ,}[ethod 3 - Molecular Weight Determination - Data Analysis 

Client :-lame 6 I r J( Project :-lumber Ci-t(r'-(7-o-{ 8 

City;State < £..v) N(_ Sample Date Cij 1/'<ijl 

Sampling Location V:::J. .:> ., PC.- I Operator LA6 

Sample Type '"-Tedlar Bag aLMultipoint o Single Pomt Fuel Type---""'/U'"'·'-;-!v-c-"71----:;C,:--4,-----

Analyzer Type Orsat Serial # 8'1- ~ c I lir Oxygen Calibration Check Must Be 20.9 :!: 0.1% 

Analyzer Leak Checks o Pipet and Bubbler Levels Leakfree? j1q_ Buret ff. l - I '1, 1 = <0.2 mJ? 

Run # and/or Sample ID Sampling Time (04 Hour Oock) c9H 111 - - - 5> 

Gas Replicate 1 Replicate 2 Replicate 3 Average Multiplie.- Molecular Weir,ht Percent Dry lbilb moe 

Actual Net Actual Net Actual Net 

co, I,(' r.s /, L{ j, '-( I . '-( I. 'i I. '1 J Ji!" 0.44 o. ~3i 

o, zo. ( {'I 0 16 f i'i I 2o. '-\ 1'1 0 l'i. u;!>~ 0.32 G. 69 I 

co 2.JJ .§ a.o Z- 0.\ !).o -z._o . ~( a c - 6. ou 0.28 o. (; 0 c 

N, 100 ·7'1.)"' 100 1~. Sb 100 l'i. (, l"i.)'!>J' ".- o.28 . <l- 1Vi 

Total 28. '1'11 

Run# and/or Sample ID -~--------- Sampling Time (24 ·Hour Oock) /1-ZC: • 15"2.-/ 

Gas Replicate 1 Replicate 2 Replicate 3 Average Multiplier Molecular Weifoht 

Perce

1

'jL Dry lb/lb mo e 

Actual Net Actual Net Actual Net ~ .. · 

co. 

' I . "t '" I. 'l I. 9 /. t I e, ~~~~ ~1 0.44 0. '62.1 

o, zo .4 1B. )" Zo '1 JQ,( Zo .3 ig,(' IB.S"o0fl 0.32 '>. '!20 

co zo. '1 l).o Zo -{ (),Q ?.o. 3 O.D ~o,;.;•S, 0.28. 0, 6cc 

N, 100 l'i- (p 100 l'j. (, 100 <'i .., l'i ,(r >I>¥ 0;28 l'L. Z'i/ 

Total 2"1. 038 

Run # and/or Sample ID """---------- Sampling Time (24- Hour Oock) ;</Jz -;S;/ 

Gas 

. 

Renlical<> 1 I Renlicate 2 Reolicate 3 Average· Multiplier Molecular Weight 

Percent Dry lbllb mole 

Actual Net Actual Net Actual Net . 

co, 1.~ LS ,_,... (,)"" 1.~ 1.\ 1.s-o 0.44 . ().f,~o 

0 ·• 1 -z.o . .3 tS. e. 2o.:. ,e,.e. --zo'; l8{~ /3.\Xl 0.32: ·.· c,. o10 

co Zv.J O.o "lo. :> o.o u ... o-o 

o.o0 0;28 O-ooa 

N, .. 100 ·. l'i 1 100 ~.1 100 l'i. I <'i. lo 0.28 . 22.. 31\-

Total '2. $' '1'1 2.. 

Note: Calculate the F, before evacuating any bag samples. Compare the F, to the expected fuel values. If a 

discrepancy exits, reanalyze the sample. The F, calculation is as follows: 

F = 20.9% - %02 

• %co, 

F.,. Ranges For Common Fuels 

Anthracite Coal and t.ianite L016 · l.l30 Wood 1.000. 1.120 

Bituminous Coal t.083 . 1.230 Wood Bark: 1.003 . 1.130 

Distillate Oil 1.260 · Ul3 Satural Gas 1.600 · U36 

Residual 01l 1.210. LJ10 ?rooane 1AJ-l · 1.586 

13--1 

Date: t/ I Z I I 9 7 
13i3 

EPA 1Hethod.JY". Moisture Determination -Data Analysis 

Client Name __ ,--r,_. _,_!. _______ _ Project Number i ..../ .~ 

c . -/ ~ - . - ' 

Cicy/Sute_~5_.~_J~,~·-~~"'~-~------ Sample Date '~/ I (' f = , I I 

Sampling Location k:. ,c 1 - 1 Samples Recovered By ( ; 1 I 

Clean-Up Box Number---~~---------­ Recovery Date .--/-f / fc_(;/j 

Chain of Custody: Date Received 0 '(-i< ·'>I Received By fr(.j Locked? ~ 

Equipment Documentation 

Run ~umber I - 3 

Sample ID Number 7 (' ~ f -::.-!1 )c--f-·8- (.( ?_ 7::o:..?-o3 

Sample Box ~umber {, e 6 

Probe Number 2-vtt o~··-, ..:.~'"c::; ·It/ 7 Zdu- t!l)) 

Analysis of Moisture Recovery 

Reagent Recoverv Container # '} &"'f fJ' C•i '},..,z_ ""!.. 7t:·"'t 8- c..> 

lmpin2er Absorbin2 Solution c. 1'..- .c.!-'~,..,. c ~-~~ r..' 

Description of Rea~ent (' .......... ;" /. c l-~-

Reagent Level ~arked? / / I 

2j) - 2..Ju ; -J [..l Final Volume. ml 

Initial Volume. ml z ....... .., ;:.. ,;J,_1 z~ ... "J 

Net Condensed Volume, ml >5' 1 ,;• 4'-' 

Silica Gel Recoverv Container # I '- 3 

Percent Silica Gel Soent 3,; 3.? _"7.. ,cJ 

Final Weight. g :;. ' 6. I :.,2.."' : ;,Y I 

Initial Weight. g 2.;"'c..'· (1 z r.;t,, ·0:' Z.::r.,.L (I 

Net Absorbed Water. g It I /2.4 IS. I 

Total Reagent Collected. g S/ .f "z. 'i ss., 

Sample Recovery 

Recoverv Container # 7c-tf-::1 / 7~-~s-, !... 7c...,J·<·) 

RinsingSolution t:-.H-...1) () !-',... 0 11, l 

Sample Container Sealed? / / ./ 

LiQuid Level Marked? / / / 

Reagent Blanks 

@ Audited br- _....j~\+'( __ _ Date:,',"/ ll 's I 'l I 

B·S 
L ~, /' 

Cient ' !c. /J.· '"' 

Isokinetic Field Data Sheet - EP.{ .~fechod _ _:f_:;:.ci3:__ __ _ 

;' /, Run '-iurr:C:er ________ _ 

City/State )-c 'J N, Date 6 ., / I~ 7 7 

Sampling: Locanon ICIN 2 0 r-·,.~ 

per:1 mrs --"''""'-~'-"'~'--------

~===============;============================================================== 

Am b. Temp_ 'F __ l_;_j (,_:_ __ 

2. ·; ~1 I Bar. Press .. In. Hg. -=~_::..:__ 

Static Press .. ln. H,O - C> I ( 

Meter Box ~o. ___::3.:"..;;":._:._:1_:c:_:'-:..· __ 

Sample Box ;-Ia. __ !£._ __ _ 

Probe/Pitot No. 

Probe Temp. Setting .....::2:...%:..:;:. __ 

Sample ID :"'a. I c ~ '2, - 0 1 

A 

Samole 

Poii:tt 

Cock 

1ime 

\1ece; Temp. 

Stack Temp. 

Pitot Coeff. 

% .\1oisture 

NOMOGRAPH SET-UP LEAK CHECKS 

y = I c ~ Avg ~ p {' (' 7-;-- Pre-Test c.a:-.; @ I I 

~· D Ref~ P <J · 0 l Post-Test 0 CO). @ '> <" 

-:w S Nez. Dia. Desired C' ..... , ~ ~e.Test Pitot <0.1 @ J: ~· ~ q, ,·,> 1-'i..., 

V · L - Nozzle Diame=er C' '-41o Post-Test Pitot <0.1 @- '-}. L 

....., "J,eu.,;; I:;, 

ln. Hg. 

rn. Hg. 

ln. H,O 

ln. H,O 

.J ~ozzle .'io. 3 '' ~ . 7 1 =4 Tedlar Bag :-lo. --'--'-------

C Factor I 0 c u 

Start Time (Jll 3 -7 

Orsat System Of2S41 

End Time 111\ 

Bag L~ak Check _ __;G:::'_::K,_ ____ _ 

Obser;er (_"'""fie\ V"'1, P-.:;c i--.e:" 

!mo. 

Tenip 

'F 

c .. ., 'I , z•. 'lz 0 b t r~~. ~·c 

ul. o c-, 
lsokinetic Field Data Sheer- EP.-! Jferhod -'-''--'-'"'-'---

C:ie:-u ___.:::LA::..:~_i~i--", c'-"'k'---""'~"'--__.--.L:./..-"{p:__. ------------ R: .. ~.r1 :"'umber --=2. ___ _ 

City/State ~),~;-:::;:,-£l.<:,...L__;/V:..::...::::._'-------------- Date {•~ /I 'j ( 'i 7 

Sampling Loc:1non -..t:o. . ..:_:, 1'""'----';,____!_~.::._(_ _-..:_1 ---------- Oper:ltors -~:::...;;;·<6 ___ _ 

( () Amb. Temp .. 'F ___;:;:li':..____ :VOMOGRAPH SET-UP L£.J..K CHECKS 

Bar. Press., [n. Hg. Z.C, !,g t>H@ \ .\;,~ Y = ( ·OG Avg ~ P 0 · i~ 0 Pre-Test() OC·i @ If' 

Static Press., [n. H,O ·~u . I I :vteter Temp. ~0 Ref~ P 0 . I Z.. Post-Test a.ou :> @ ~. '> 

Meter Box :-.ro. "3o 6 . t 00 Stack Temp. ~cO :-.fez .. Dia. Desired 0· 38~ Pre-Test .?irot <0.1 @ .±. ~- !; 0· 3:;.2. - •. , 

rn. Hg. 

rn. Hg. 

[n. H,O 

Sample Box No. _.w_ __ Pi tot Coeff. 0 B....( ;..f~ Diamere.;.;~ Post-Test Pi tot <0.1@ .t'~."'\ fn. H,o 

Probe/Piror No. Leo. o~ ( % Moisture ":3> Nozz!e .\i"o. ~.;:..c, • ~ Tedlar Bag No. _ __,Z~---

Probe Temp. s~mng '1. ro C Fac:or i 0 '3 ~ Orsat System 0(2S. 4-;-- Bag L:ak Check __ ~_K....:.._ __ 

Sample rD ~o. 7t " S · c "' Start Time I 'Z. 2..0 End Time I )1i Observer ( hcrle< ,_,c!:O.;c~,:,c"' 

Samcle C:cck 

PmD.t Time 

.4 I loG 

z. I 2<: 

,, :; 2 ( 

8 ,7 r 

II 12\D 

"1'11( 

II~ 

. 

Drv Gas P!tor Orifice Drv Gas 

Y[e:er R~e~J'adin;g Sc:rting ili · :viere:-

Cubic Feet ~ '. Inches. H,O Temper:1rure ~F 

ln. Ideal AC:ua! In:.~~ Ouc!e! 

Pump 

Vacuum 

In~~es 

Stac~< 

Terr::c 'F. 

Filter 

Box 

'F 

Imp. 

Temc 'F. 

fl(.,Sl'-j lo oB \1.o i.Zo G.'/ 10'-i 3.o 35b z:>o S"'3, 

I~ 

Date: l/ t~f, i 1 
' ., --'1 

lsokinetic Field Data Sheet- EP.< .Ylerhod -/~5-==!j __ , ij __,- C:ienr L ./../ J. ~, c ·- &.....-u I. 

Cry;Scate ).;.., /, . IV C. 

Sampling Lvc>ncn /(. /,. ~ (- I 

Run 'iumce:-_J::...__ ___ _ 

Date ()' l!'i/? 7 

I 

. ~ 

Amb. Temp., 'F ___,:..._. ~) -o-- NOMOGRAJ'H SET-UP LEAK CHECKS 

"l"i .. ( ' 0 c 'L 

Bar. Press .. ln. Hg. ~ ~ ~ (@ j.\3 y = I· oO Avg .l p . 0 l Pre-Test a oo'i @ 1\ ln. Hg. 

Static Press .. In. H:O -==-o. 1/ Meter Temp. B- 0 Rei..\ p 6 · Cl Post-Test V -oc "2... @ ]. 0 In. Hg. 

Meter Box :"-fo. lee - I Cl o Stacie Temp. 3oo Noz. Dia. Desired 0 · Yt/p Pre-Test Pircr <0.1 @ :t=.,f·.'b In. H:O 

Sample Box >So. Cf, Pi rot Coeff. 0 · C ·i Nozzie Diameter 0 · Y32. Post-T:st Pi rot <0. I @ ~ ~- Q In. H:O 

Probe/Pi tor ;-..to. '1.::o · ~( % \1oisrure _'-/_,__ __ Nozzle :--fo. 3cu- L.l ~ Tedlar Bag ~o. ---=3::....__ __ 

i6'2.7.. Pr' Tm St C Factor 0 t S tern o :?sA-T""" B L k C k oce e p. et tng rsa ys . ag ea. ::ec. 

Samp!e ID No. 7 6 i <! - 0 :> Starr 1ime i'-1 3 <6 2... End Time l ')) 1 Observe:- Ci-.<-.r I eS M< E~ct...,,. 

-; ....... Drv Gas Pi tot 0 Dtv Gas Pump Stack Filter Imo. 

I 

Samo!e C:ock )..o[eter Reading s.~~ll:-~H Mete; .... Vacuum T.:mo Box. T<!ril:O 

Poilu Time Cubic Feet ln~\.l:o ld~~f!tes~~~al 'F ln~~es >f' 'F 'F. 

lrJ<:' Clu-tle-t I 

1.4 I c {\ & 07 o io 12 (,,\ IZt.( (oCr, ~(, I t;,. o l'3c>l__. nc I (,~o -2 2<:" " is- u 10 2 c.-f HI r;c;- iR0 (, () 3~s lz."l_o 5'1 I ~ ):Cl Ill ~"'\ l11 if'> rz v~ 2. (,~ &c. (;.(p ( .. o JD<,. 1.3/ I 5"':z. 

~ ll,.. I Z (. g I;; I I 11 'i( 2 <t) C.1 I f,r~ 'l() I 3c'1 'Z. )o ls-0 I 

-) II 0 C) I).D > I ,j I c 11 t..S" 11 1.< G>"'i I c,l Co l11f i'Z)Z. 0;>o I 

(? IZ.\ ii.,PI n. lu h? z._t..f tD I Vl ')o 13, ::> Z3C G,r 

""'] I) 0 i , .:;---,_ I,, .oc, lz '"( '' L'-ln \O 1(,1 s-.o h,~ 131 Ccc 

e n.) 2. i G l ICJ oc1 11. "' () 1." 0 11 /:,1 C)n 1112.. 211 (,; 

-q 2.o ,l z.-; 91 o o8 l1tu :2. f(.) 11. (,l '-\~ Jl3 z;o. I & z_ ,, 2.7 .::- 2<>. 'f/ :' 0~ T1c LIC --)2 (,l '1.) ( fll"'~,~ I '2 '"' 

th I 

/1 2)6 'll 17 C•oB L·!D ll/6 /_:"2 '(, l '-/( '1,1'-{ I "1- '"' G-i 

i7 '217 ~.77' lo o~ rz t6 r-z 10 1;, !cB 'is- 31~ 2!o 5"'i 

I r:, I 3.::> (,) I ~~ 11 icJ 00 1. /0 I'Z. iO It GB '-j)" lz..c.s- 23o c;, 

z 32 \ n. ''-~ I(• D 0 lz,, lz.,o ll G~ '1.("" l.qt '-3o c;-, 

) >f'o l),7) t! i 0 11.. L>i r 1 v( 12. (oe, ! '?C> w'J l._)j '-{ c( 

i ~ ~~ '11 lo 1 c. 1 (;) l IS 73 (o~ '>.o Z.¥>3 z.;, 2- ">0 

r 14. 0 'io ,-, b IO 12 (p\" l1.(a( •:;. 1[:'1 ~0 I zc.. z li'>o Sl 

(. 1'-1? \ fyz ..,, lu , t 2 , ,- 1 z. <>rs {\.j (,"j G. e> I Z<..3 I ZYJ S'\ 

7 ~{) ct'-f. l f ILl 1 n 2 t,? lz c,(' l'-1 (,..<; S""o z.c~ I I Z'}-\ 5"2 

s en( 0'.o1 f6 ID It,:( 12.(..," l~ fo'1 7-0 U.:,; I 2'31 53 

1 .;v c) 'i"i 14 I " II Z<t\' I z c;~ h? 04 ~-0 Z.<e 2. 130 .;-"'- ~ 

u )"- " I s-1. s---1 C I I 12 'iS'"' 1-z. <1< 14 lo G:-0 I Zr;L '2.30 ~I 

" «(.) S'J~cl ow liP~ 1-z.. <cr" lv '10 ~- 0 Zi.e I '2. J" ~ 

12- 'I I ~ :z.cl lo ,o 2. ~,. Z-its /(., II I r, o 2(<>1- 1}0 - t:;" ,;-

lt''-' S'B . ~~ 

G,'\.?J I 

TziC lo.d1C' ~sq IW-1 l·z.a :5 

~~~( Oa<r. 'I ' 21 ' 9 ? 

11-S 

-
Cient :-:axe !_8 (3.z,c~ ProJect :-lumber C</<C -'97 - c 'ic 

CrjiState S~~'<2u ,Jc_ Sample Date 'I - 1 E - '1 7 

Sampling Loco tion ---";<=z~f\'---=c_=---.:..1 _____ _ Samples Recovered By _ _t:JZ,~'F<:._::c___=-------

Recoverv Date t/ -/(3 -97 Ceon-Cp Box :-.'umber------'S"--------

Ch a in a f C us to dy: D a t e R e c e i ve d _.:c_:~t__::_!.._l ">-'-----_"lc_'_.:__ Received By P il, ..\ Locked" ~~"------

Run :--;umber 

Samole lD :-<umber 

SJmr:de Bm:: ~umber 

Probe :-lumber 

ReJ.I!ent Recoverv Container~ 

Impinge r Absorbin:z Solution 

Descriotion of Reagent 

Reagent Leve! Y!arked·? 

Final Volume. ml 

lnrtiol Volume. ml 

:-:et Condensed Volume. ml 

Rc.J.':!ent Rl!coverv Container 1# 

Imoin(J'er Absorbin(J' Solution 

Descriotion of Rea2:ent 

ReJgenr Level Marked'? 

Enol Volume. ml 

Initial Volume. ml 

\fet Condensed Volume. ml 

Silica Gel Recoverv Container # 

Percent Silica Gel Soetit 

Fin:tl \Veight.!! 

Initial \Veight. !! 

Net Absorbed Water. g 

Total Reagent Collected. g 

Rl!cover.r Container# 

Rinsing Solution 

Samole Container Sealed'! 

Liouid Level Marked'! 

Absorbina Reaaent Blank 

Absorbincr Blank Identification # 

Absorbin• Reaaent Blank 

Absorbing Blank Identification # 

Analvst lnin'als 

R~tvi~h·~tr Initials 

I 

I 

Equipment Documentation 

I 2- 3 

7c'le -cl?: 7cof'C - di 7ciE -/o I 

(D ,z_ IC I I 

]_co c c '! I zocco9 2_<-0. cc'j 

Analysis of Moisture Recovery 

7dc -"~ 7ctb -.o9 7cllc. -1c I II 

o.1J d~;c.; O.t,J ;/<Sc-i ~-'A! ;/,Sc.; I ,, 

cu:>oL I Cu:?lt2.. CLt£-p,2.. I II .....--- --- I --- I I 

Z3o I 23C zl-'1 

-z_.:>C 2.cri) I ze-c I I 

3D I 3D z-1- I 

7t'/B -c 'b I 7C'/E-o9 1o 'It! ·/o I 

c. iJ AJ,..c,./ ~ I ,J Nc.<JH I iJJ,J ,JoDJ./ I I CL~?f i2- C( t:::?4 :2- c.:...,-,. 12-

/ ./ I ./ 

v.s 2<:<;. 2Pf 

z= '2c0 z= 

Z-5' G. I "f 

I 2- 3 

52> 5D 5t> 

2-13-., Zlj.O 211.7 

2,&0.0 z..,:ro "' 2ce.o 

'3-!> I 3~ 0 /I -1 

(;8,. ~ 'f>.o 31-'7 

Sample Recovery 

7D'f8 -cf!, 7td8 -o9 ?c¥8 ·to I 

D ' ,_.;,. ;);'f2-- J>,.J,.= I).,J ... ;r,t. 

1./ ......- ./ 

/ v __......... 

Reagent Blanks 

Rinsin• Rea•ent Blank 

Rinsin• Blank Identification # 

J 

13-9 
Isokznetic Field Data Sheet - EP.4 .Vethad Zi.: . ~ 

.\.:~.~- I C:iont _-J-...;:_;.,-!<.;..:c'"-!.. _______________________ Run '<urr:co' -L;--------

CiryJState _ _.L.::c..:.J..:..;~---'L>L~-------------------­ Dato C'+/i r/ 57 

Sampling Locanon _J..:;.;'-l.!::.!-L-1:"'=-_.!_----------------- Opo,ators _ _:C':::_· _:C~<,~-----

Amb. Temp .. 'F _5_._,0~.,.____ \ .''!(;, NOMOGRAPH SET-UP LDKCHECKS 

Bar. Press .. In. Hg. J '1. 'I-\ j.H@ ·±.±; Y = ICc Avg .J. P 0. I..'C'/ S" Pre-Test C. cc3@ I ')" In. Hg. 

Stanc Press .. In. H,O - c l I Mete' Temp. {r Rei .J. p c.; c 7 lc cg- r. 

Meter Box No. 3'CC 1 it 'i Stack Temp. ::;) t ~ Nez. Dia. Desired 04-Ct 

Post-Test 0, C G <_ @ Ci In. Hg. 

Pre-Test Pitor <0.1 @ 9 .A (.(.~ rn. H~O 

Sample Box No. I 0 Pitot Coeff. C Jf\1 

Probe/Pirot :-.to. 1.u ~ r. o '1 % ~oisture _ __,_ ___ _ 

Probe Temp. S~tting -:2 5 C 

Sample lD No. 7C :t 9 - ~ 

C Factor \ , CCC 

Nozzle DiamererU· Y3j0 Posr-Tesr Piror <0.1@ 7.4!. ~ 7In. H~O 

Nozz!e ~o. 3 

ct.) • 0 q L1 Tedlar Bag :-.fa. --'-'-------

Orsat Sysremc--~f 8 ... i;,W(' Bag L~ak Check __ O;:::'.::K'------

Start Time 9 : l ? End Time 1\ '. LS Observer {__L.~..tl~s ("'J;~,~o' 

4 'Z I' "f1 5 ""'\' '\ "- (\ L} J 5hliJ- c;t l' I \ "\_ 

6ll l't B-10 

-~', l\.\~\ ~\r:~.'J.., i'i.,1 ... ,- -tu'0 ~~~~C. -.,"::. 

Stack 

Temo 

'F' 

Filter 

Bo.'l;: 

'F 

Imp. 

Temo 'F. 
C:ie:lC _ _:_.J:.i'-'''--':/9'''--'-; ''"-'-K"-------------------------

CrjiState ~S=: . .::c<'.cc'''---'-""!...r;c1_--"~"--C,._.. _________________ _ 

[sokinetic Field Data Sheet • EPA .\4ethod ), t A 

Run ~·umber_..:?=------

Date _!......!-'-"--"-'------

Sampling Location _..J.O,.:._' \c.:·f'.:___,\~..l\J-".C...L_________________ Operators -'-"'"'-L-------

=============================================================================== 

Amb. Temp .. oF _J.--':C_· __ _ 

Bar. Press., In. Hg. J. 'l ', 5 t.H @ / 9 t 

Stacie Press., In. H!O -C.\ \ 

Meter "' ,[,..' Box ~o. 7~:-c ..:.... :L 'fJ 

Sample Box :"'a. \ 'J... 

Meter Temp. 

Stack Temp. 

Picot Coeff. 

% :Ytoiscure 

NGJ!OGIUPH SEHP Q, C"i C LEAK CHECKS 

y = \ L{;. Avg ~ P C :9 c Pre-Test rJ CC' I· @ I 5 In. Hg. 

7c Ref~ P C .C I Post-Test C- cc \ @ 7 ln. Hg. 

---"--, ~ -.," ~,,_,-9,-'1'115 >,I ~-<JS Noz.Oia.Desired~ Pre-TescPicot <0.1@ lf·,y. In.H:O 

. 5 7 0 <;ij"Lf- Nozzle Diameter C.l.f] b Posc-Tesc Pitoc ~0.1@ +- , 'l [n. H;O 

3 :"'ozzle :"'a. ; >t' C '! t Tedlar Bag :"'a. _ ___:'2::::_ ____ _ 

\ ctfc J ,Q~O Orsar System oo~·-J- Bag Leak Check _.,cO..:~.!.:-'-------

Probe/Picot :"'a, 2oc.CC'l 

Probe Temp. Serting 'l.S rl 

Sample ID :-io. 7 ()!,-'{- 'l 

C Factor 

Start Time ll-'20 End Time '3 <2(f- Observer C.i.,wic) Y'lu::i,;,.bMI\ 

Clock 

Time 

0 "" i/ ,2r ,77 

B-11 

Stack 

Temp 

"F 

Fiirer 

Box OF 

Imp. 

Temo 

"F' 
;--.,. • I /' 

Isokinetic Field Data Sheet • EPA Jfetizod --'~lo:..;:.:~--

Clie~t ~ '( h ~-, 0\. 

Ciry;State c; c:;v..~/c) 1 

( 

--, 

Run :--.:umber __ "'>.:.._ _____ _ 

Date n li- - I ~- 'i J 

Sampling Location K i \V\ 2 \7( I 

=============================================================================== 

Amb. Temp., •f __ c;i..· 2._ __ 

Bar. Press., ln. Hg. J. 'l' ", 5 

Static Press., In. H,O - 0 I ) 

,\1eter Box No. )OJ 2lf5 

Sampie Box :"ro. -l..l.o'-----

1';-obe/Pitot No. '7 () iJ 0('1 

Probe Temp. Setting 2) 0 

Sample ID No. 70n-w 

Date; 

NOMOGRAPH SET-CP 

~H @ \.16 Y = l,c) Avg H ____:,C::.:·~O:.:'fi'-. :___ 

Meter Temp. 7 0 Ref~ P _.=,0~C~7 __ 

Stack Temp. :2 C'f 't[ 

Pitot Coeff. C <riJ-

% .\1oisrure 0 p Lf' 

C Factor --1-.c.l.<.!:~'--­

Start Time 

~oz. Dia. Desired 0 .''ft?f 

., J r Nozzle Diameter L.. ·.:a 

Nozzle .'io. --"J~c:;_v'.::.O..!.q.::.5_ 

Orsat System 0 r .:'<t 1--

End Time \ l' 7 7 

ll-l2 

LEAK CHECKS 

Pre-Test 0 .t...'C.I @ i ,- In. Hg. 

Post-Test 0 . . --, @ ~-~ In. Hg. 

Pre·T~st Pitot <0.1@ :.._'9~tr In. H::O 

_q_t 

Post-Test Pitot <0.1@ ~ :.1 In. H!O 

Tedlar Bag :'-lo. -~?:__ ____ _ 

Bag Look Check _::.C'.!.v_,(~----­

Observer (_[,._ ... /{er, C}l .,:;..:Cl,d/,, 

:)3 
EPA J!ethod I 

Determination of Sampling Ports and Points 

Sampling Location Dimensions: ,, From Far Wall to Outside of Port 5L.. 7 ~ 

Nipple Length 0 

Depth of Duct 3 G .1 'S 

Width (Rect.lllgular Duct) ---'-f'i:.:.A'--

Equivalent Diameter Calculation (DE): 

2 <l..-nsthxW">dth 2 ( / ) V ) 

City;St.lte __ :S::c:.:.··"':.:.';.:•:.:.·r~cl~:.:.~::._J:_~ ------

Date __ _:C::...'"::...,:...I :._'~:.:.1.::.>:.:." ________ _ 

\ I 

DISTVREANCSil' . 

SA,lJPUNC 

LOCATION{- l 

I ·---- = -----= K DE= _..!,.;1!...:.!)/-_ 

Distance to Ports From Nearest Flow Disturbance: 

Upstream· A 

IS'' ~-·/~.~ Dimensions in Inches 1..;"' Lt- ..... ~ 

Duct Diameters ,{1.0 ~ 

Stack Area, in Squan Feet 1. 31 

Calculations By _ _,!fl.,.__;_~'----

~ 

~ 

Downstream • B 

'z~ ., 

3, Zl 

Point 

So. 

2 

3 

'1 

) 

G 

l 

B 

'1 

IO 

II 

lz.. 

B-13 

SWXID "'" 

z ( 

(..,'1 

I\. '3 

il.l 

2>.o 

')').(., 

(/1. '{ 

1\.o 

02..3> 

Bs. 2. 

'1J.j 

'j/.q 

s I 2."'" 

SciwmalU: of Sampling Loetzlion 

Slade Dbtance- F'rom ~pple- Dlstmce· From 

m Cnsld• WaJI r.. ..... · Outside- o{ Port 

3(,..1'S"' 0 T7~ /.oo 0 I. o C> 

2· '{r, I 2 . y 10 

'1. 3 lj. >-( 

(,.51> G '')1) 

'! ' ( , 4. r"i 

/3.o~ !3.oB 

23.. (.., l 1.3 -~ l 

:i.l ,0,. L'-~ 

3<>. J.s :,0. -z.'i 

~2.' ?,1--'1( 

)'1 . 27 I 11. Z."i 

>. 'i~ -? )). 71' {.- !,Cl)"' 
EP.-t .Hetlzod 2 

Determination oJStack Gas Velocity, Volumetric Flow Rate and Cyclonic Flow 

Client L '' J '~ <yo.! 

Df Sampling Location,..-_,_r_,-~---'2=---------

City. State _.;.s;,_. ~-'-'----'-'-") __ "-:..;:_;' ('--------

Operators t''""' ~!?A 

Run Date 1 ""'~ r;;, ~ 7 T!Dle C 7'11~ 

Barometric Pressure, in. Hg 

Static Pressure, in. HzO - (_-,-. ,:3::.':---"------

Picot Tube I. D. No . ...:2~---'--:;~"'=~::-~------- Date Calibrated--''...,· '"''-'J"-''i_7.__ ______ _ 

St:uic Pressure, in. Hg ---:C=--. --==--------

Stack Pressure. in. Hg _ _,2.=-'i'--3"--''l'--""'----.,...-----

Stack Dimensions. in .. diameter/side 1 --"'L'---'1-'-'---

Pitot Tube Coefficient ~1._'_'1-'--t:--------

L.eak Check. in. H,O <0.1 @ _:_'? ..<.i_:..'l_'t,__ __ _ 

Side 2. in. ---"~4-----------

Field Data 

TraYene Velocity Head .l.p fnches Slade Cyclonic Flo"' Detenninatlon 

Point H,o Temper:uure T 

~umber ~- at o- Rete-rene. An ale Whidl Yl~ds a !'iull .1o 

I {I . )s-' 6. :. "' 'if D "f II u. 21 I) 7.8 , ... -z., 

'1. I}. )() 0-L/8 '11~ '1b"l 0. 1..$"' () -z. '?, IS 2o 

.5 ~ • <; L{ 0. 5"3 'fel ~II 6. 22 a .n ,_, \q 

"\ () \1 a s-'1 '-{Dfj ~I( () ·ll o. !"\ I:> l.; 

,- ln. '> 1 a s-ev "111 ~ve 0-\'\ 0 I(" II \Z.. 

(., 0 -~G 6 \1 '110 '/0 'i 0 l I <l. I I ;:; '\ 

"1 0 . )t.. o-Ld 'jt• 'Ito O.~e. 0<:>~ 0 :, 

.9 lor-~ L' . s-~ •1/lJ (.jv"f 0, cc 6 0 I 0 

"i 0 s-o 0. )"' '111 "I II D. Go 6 0 '-' 

lo ~n r: ') 2- 'i•"l 412.. (,. 0 ·. 0 {J 0 

·I b 1o c. vii '1 0 l '-11/ 0. cv b 6 (I 

'l- " '2fo 0 2.. "! "\o(., '-/10 0 f 0 (.:. lo 0 0 

I 

I 

Avern.aes (1. '-1 8S cl C"J (p ?.31o 

e~6 

Stock Temperature, Drv, •p (A) _.;:.tl.f-':/:.J'-/ ___ _ 

~ k.k. _.,_ 2 '' "l, Dit<e renee (A - B) --.J.b/.;;...-':;;,.;:?.,.;,.y~:..._..-!::>.Ci'-''"---

Stack Temperature, Wet "F (B) ~ I> 1 

Preliminary Percent Moisture __ 4"-'"'-----

Commen~--------------------------------------------

13- I 4 

e;.'l 

~..illed .,., /Fe. o ... , 1 I zz . '7 7 
EPA 1Hethod 3 • JHolecular Weight Determination - Data Analvsis 

Oient ~arne (., Pe i3,. 1 c k Project ~umber <J Lf~ , 0 7. ... _ Cft-{ C 

City/State c:1 k) N ..:_ Sample Date 13'-t I 1 t3.;77 

Sampling Location 1<: ,I A.l L PC - ? Operator _..::"-::;1'3:.:.'.:.,• (_---,.-----

Sample Type lil._Tedlar Bag ~Multipoint c Single Point Fuel Type t0 -.+. 0 ( G-s 

Analyzer Type Orsat Serial# t"- '>co-/ (li__O:<ygen Calibration Check Must Be 20.9 =: 0.1% 

Analyzer Leak Checks o Pipet and Bubbler Levels Leakiree? c Buret /6. L /v 2.- = <0.2 mJ? 

Run # and/or Sample ID Sampling Time C4 ~ - Hour Oock) c9T3 - '' ~ ' 

Gas Replicate 1 Replicate 2 Replicate 3 Average Multiplier Molecular Weir,ht 

Percent Dry lb/lb mo e 

Actual Net Actual Net Actual Net 

co, J.] 2 3 2 3 2 3 J -( '2.'{ 2. "'>31 tK- 0.~ I . 62\ 

o, 2o. )._ !1 4 2<-> . 2. /7 1 Zr;.J- 11 e D-%tt 17. 1j( 0.32 '>· Iii 

co z~.z.. {J. 0 2u. Z.. o.c 2t:. 1. o.o 0. Co/~ F-- 0.28 (]. oco 

N, 100 1'1 8 100 ...., g 100 11.& {C., 'i)D 0.28 22 3'-·1'-/ 

Total 2'7 c 8 (, 

Run# and/or Sample ID _2.=----------

1!2<0 • IJZ--1 

Sampling Time (24 ·Hour Oock) o>f 3'5' ' '5'[ ~'I) 

Gas_ Replicate 1 Replicate 2 Replicate3 Average Multiplier Molecular Weif.ht 

Percent Dry lb/lb mo e 

Actual Net Actual Net Actual Net 

co, 2.1 1.1 I. "/ 1'1 2.o 2.o Z -=-o¢' t ~ 0.~ 0. 986 

o, zo.?- !&., 1'1 ~ i8.0 1o.e> re.o IS. O>!¢ z 0.32 > ((( 

co 2o. '2.. oo rc; "7 0 ,C) '2-o. c) Oo Q. 0~ ~ '(.. 0.28 C). Ooo 

N, 100 11 e, 100 So-1 100 ~c) ...,<; '"-~ if<,- 0.28 22.'3"11 

1'1 'i 7 Total 2'1tJ'{;;_ 

Run # and/or Sample ID ..:3:::._ ________ _ 

1'132- 15?? 

Sampling Time (24 · Hour Oock) I;; 2 e > ]~ d LVI) 

Gas Replicate 1 Replicate 2 Replicate3 Average Multiplier Molecular Weight 

Perceot Dry lb/lb mole 

Actual Net Actual Net Actual Net . . 

co, J..~ 2( 2s Z.) - 2 •( 2.{ l-'lii12

i1 z 0.44 {, 08) 

o, Zo./ t? (.,> ']ol /?(., ZD- 2. (l'O 1.1-Cffl'e ,7 

«- 0.32 (, ~>3 

co 'J..o f ~ .() ?.o ./ o.o 7..o. 2. 0.0 6 .oo~ 0.2~ 6. 00'-' 

N, 10(} '1<1 "1 .··. 100 '71 '7 100 l<i.B l~ ~~=~- 0.28 '2 2. ' JC,. :> 

'77. 61 Total 2 't {t-• ( 

Note: Calculate tbe F. before evacuating any bag samples. Compan: tbe F. to tbe expected fuel values. If a 

discrepancy exits, reanalyze the sample. The F. calculation is as follows: 

20.9%-%0, F = --;;;--;::;:~.o.. • %co, 

F., Ranges For Common Fuels 

Anthracilc Coal and L1tnite 1.016 . 1.130 Wood 

Bituminous Coal 1.083 . 1.230 Wood Baric. 

Distillate Oil 1.:60 · }A13 Suural Gas 

Residual OU 1..210. 1.370 Prooaae 

' 

Date: I (21 I r 7 

1.000. 1.1~ 

1.003. 1.130 

1.600 . 1.836 

U34 · 1..~86 
;313 

EPA Method -4"- Moisture Determination - Data Analysis 

Client ~arne -" <' 1$.· '/, Project Number "'"'{ •, ~ - v-. 

City/State ···~-+-.,/ .'/ L Sample Date ?~ •• 1:"/ s 7 

Sampling Location --'<.."'-'"'::--'-P.:.c.~-=----- Samples Recovered By c,·/: 

Clean-Up Box Number __ J_' ______ Recovery Date /"-t/ /P/ 7) 

Chain of Custody: Date Received OJ ;;c, /c., 7 Received By PI< j Locked? ,--

Equipment Documentation 

I - Run :-lumber /.- -> 

Samole ID Number )t<~!- c¥ 7c•-r-?- C'~ }<>-rf.'- 06 

Samole Box Number ..., i ) / 

Probe Number =ut' oaS Z.tJb~.:J6 f Z.a-,;-.;t;_(J 

Analysis of Moisture Recovery 

Reagent Recoverv Container # )t: :.;8-,• -1 7,~•8· ,;'; h·'">l- ... 

Impinger Absorbing Solution /:.HI...'-' p.tl~o P.H .... d 

Descriotion of Reagent r: It:.- j.. I c f ... ,/ c/~ 

Reagent Level Marked? / / / 

z._;,-s- - '..:.' -:..c, Final Volume. ml ~ 

Initial Volume, ml ::. ..... .::.- ::..oa ::.. ~· .:.1 

Net Condensed Volume. ml ,., i-/o c? 

Silica Gel Recoverv Container # I z_ ~ 

-" 

Percent Silica Gel Soent Sa/ .. . ·) Jo 

Final Weight. g 2//3 ~i2. 0 Z.t J "I 

Initial Weight. J1: z,h•-o Zc'o· o Zav~ 0 

Net Absorbed Water. g 1}·3 IZ 0 I) '-1 

Total Reagent Collected. g )2.J {'J.cJ ez<~ 

Sample Recovery 

Recoverv Container # )c-r2- c.:.f 7.t:t_,2.._ G')- ') • ...,. ; . ~ c 

Rinsing Solution ~ 

~. ....... c +LV p, l'i;z...d 

Sample Container Sealed? ( / / 

Liguid Level Marked? / I I 

Reagent Blanks 

D-16 

57 
13 g Isokinetic Field Data Sheet - EP.~ Jfethod _-=-.:::'-' __ 

C:ienr __ !:::U:::_2_1).!:::.~:_f •:_.:.:(-"1["-----'("--'-"'"'.>::J~/.'-'-'...lf~<-'------------ Run C<ur.1ber __ .c_/ ___ _ 

C:ty1State ____ ,.....c;;-='t:..''~:~_J_:_f'J_C. ____________ Date _ __;G,_''-f!..i/~I~:::..'"..J.'~-7 ___ _ 

Sampling Locaricn _ _c::'--'-'' \~,·--7...=--_-_.c_P..:::;C::_-.=2..=------------ Oper:Hors _ ___;:_70::_-~;_-___ _ 

=======.======================================================================== 

::l;:>i'\ 1 i _._ ( "' 

A.mb. Temp .. °F --"'trv ..J L 

Bar. Press .. In. Hg. Z'<. Y!/1 -~ Static Press .. In. H~O - .._"'1. )·J 

Meter Box ~o. ~j DJ l C,_""l 

NOMOGRAPH SET-CP 

Y= I.C;-:1 

'! cv eter T emp. _ _;_::_ L·o __ 

Stack Temp. '-! \ C ~oz. Dia. Desired C' '!... 7~ 

., ,!,f.AK CHECKS '-.!... ..... j 

Pre-Tesf'~@ IS 

Posr-Tesr'"~ J ..;...(;{ -~-4 I H n. g. 

' ! ' P~e-Tesr Piror <0.1 @ - ( ' fr.. HzO 

~H@ j !fl Avg fn. Hg. .l P _~.-_' ~__;3::_::3_ 

Sample Box :"ro. --1---..,.- Pitot Cueff. l'-r~·-l. 

r7 1/_.-: Probe/Pitot ~o. __5_?_:::Y::_) .::_:'-..:_'-' •::..__ % .'vfoisture -~~L--

Nozzle Diameter Z\. 3 ;;r; Post-Test Pi tot <O.t@ ?i C. "5' ln. H:O 

, 

C< ozze. I -.; o. 3t:: c··J•' J T e dl ar 8 ag.~o._.....=_J ' ~ ___ _ 

1S.0 · c~7 Probe Temp. Set!ing ____:-:..::.:.__ C Factor I. _,I.-' Orsat System :ro .. + r., .. l'fftJ Bag Leak Check _ _:__;J·::::,( ___ _ 

S m a p le ID . :--1 0. 7ti.i'?-· 'i St ar t rm O'· ·1-3 ·· ' e EdTi n 1me Ob ser;er - < ' - r~ 

~.;?, Gas Pi tot Orifice Drv Gas ,J'ump Stack Fiiter Irr.:J. 

Sample Clock 1 eter 

~~tJ:~g Setting .lH " Yleter ., ·~~~F Temp Box T~~D 

Point Time CubiC Feet rn: .o Inches ?ual l~'!': 'F 'F 'F 'f" 

Ideal · c;,;-,,;t ' ' .. ~~ uu s-i"i]4 o titlu i'.. s () ~.so 51 SG 3,0 1.{ 3 'l ?SO I <-~3 

2 ; : J?<;,;q Jl/3 \ 1. s.> 7 <;c ':1 s (, ?.0 '{) ti Z4'i I '/?_ 

s sc <Si ~--j :J .<ito J z..H Z.:70 )ij 5(< "3,0 'f 'J z. 2)2. 1/J.) I 

" I <; 3U~Sti I "-<-/ ~;_ - . ' Z.'5.J Gl 5"7 3.5 lfi G L4u L/1 ! ~.J ... 

'S '" c 

m. c. z... t'.-ifO ,:. jU l..P ~'\ SZ' 3.0 1.{2.'1 z.u.l./ «S I 

i. ,. I ;!?. !7 I ,11/Yu z.e'J z.so ~I s1 1.0 if3/ z :i i) ~5 

l IS c .;4Ll,JI I D.5fr! -i'.lT"J J.U;) G~ 51 ],tl i/33 2;5~ 51 

' 1"1 ("_ ,·q·z:lJl 1.::>.560 "j~. ti) ).20 &0 c.o 1-0 :;-7_5 ls~ 57 

Ci 20- ·' ~'lj () <:50 :;.JLJ 1. ,I, {;; (,() ? . .c: 3<;q ZSI( bO 

Ji) :Az.. 5 317. z~ ,1' 5 ~0 3.-?0 3.];;, ?<:: 00 3.S 35~ !.:'. l( t-.5 

:I t.').r.J 3'1(1,. (; 7 Ll ),50 ).p 3. 3~ 13 Gl }.5" ~if Z:53 <,S 

I" 71. <, l/tZ.~ I L'Yhl ~ ~ c ;_ '"' ?~ 1.-Z J, 5 JS~ Z::; I (.5 

IK I 3c 0 tJ.:h-Uitf I '~-·'1"1; -~'" ~70 '7/., (;£.. <. 'i 33q L\~ &~ 

7. u.s ".;(, g 'i D.•tbO l. 7V z.7o GG L?l ~. D 4c1 t4'> <;~ 

l l5. c ~t/0'1,1£.. I"'· -1 ~ o z:?J 1.10 ..,, uZ... 5.1:: t,ID Z)~ s~ 

" ;•J <, li II. ~u I o :s u i.au J.ao 17' GZ.. J:3 4111 z.ss (JD 

5 'i.:. ,, 411.1,- ,, fl; J.t~ 3".n 77 1..,.~11'2. 1.5 4/ln l.57 vo 

(., -4 7. ~ </II. J)~ t)~~<> 7~0 z .'{0 ?L vz. .. :r s tl I '7 ~s> c- I 

"7 

""' c 

Lf tJ-:113 I o,5uv t.<N HD lS {;3 3 5 'iF v'l (,2 

1 •{1. ~ I :fzz.-:'f. I .,_,Hl 1. oa ?,.IP ·7(; Ld JS L/11 I "'i-,z::;s- (.,3 

'I 5 c. C' I Lit J.IZ.. c. :51(0 3.tC 3.10 "7G (;-) 3. 5 42v ZSII H 

/C ~z.s 1{25.4~ r,) cflb t ?S . 2 '1\ H ul/ ~ c (111 z<, (; ()1... 

ll 5~." </1.1-?5 0 1/1C z.?S z.?) 11 v5 ' () 

Lllf z<;G ( I 

/7 ) 7.5 l.f>aP ~{,() l. ?I) ? 70 7'f (,I' J ~ I ~IV 2)"1 L1. 

f.,c1 I) '-IL'Zt( 

~-~-'l 1~¥<:. 

- ;s. 10 c) 5'-' Z.. .:. qo I bl/ q .x-:: 

~Q~) .__./ 

ftc """ { ,-z?.,17 9 

-~"'-" 

"' J , . ..,._ 

Q 

Q 

'"'" 

"'' '13 

~ 
lsokinetic Field Data Sheet - EP. 4 }fethod ! ;;; 3 

CimSta te __ ...c=:::::!."-l"-'-'L----'-'~-=--=------------- Date _ __:O:...c'l+/~lf::..:_f <''-'-· ?___ _ 

Sampling location -~i!~'-'-!-!,r~-_::::L:__-__:_P-'r_c.:?_=------------ Operators _--d.JL:!c:.!.N~----

=============~================================================================= 

Amb. Temp .. oF -5!1 j, Q NOMOGRAPH SET-CP LEAK CHECKS 

Bar.Press .. In.Hg. _ lc..f.~ _ UH::W _ L~il Y= L~-:; Av2_\P • {'.SCl..- Pre-T~st 0 . ..)~~ _ "" W ___ I) !n. Hg. 

0)''6 ') 0 _c Static Press., In. H::O - · ~[eter T~mp. Ref_\ P (). (...,Lf Post·T~st ,.,o~ @ .; In. Hg. 

Mete:- Box t'l'O. ·)·co ZtJv Stack T(!mp. 370 .'l'oz. Dia. Ol!sired _'-_! o ··o Pre-Test Picot <0.1 @ -

-~" ~o~.O In. H!O 

~ "Y ',,-c . . '>·>- Sample Box :--lo. Pi tot Coeff. l.i- ~ :-.lozzle Diameter u f..-J--' Post- T~st Pnot <0.1 @ • ~~ J In. H::O 

Probe/Picot ~o. 1. c"') · c?O i % :VIoisture J. ~ Nozzle :--;o. 3D? 0 7 'S Tedbr Bag .'l'o. __ V.:::__ __ _ 

Probe Temp. Settmg Z ':/~ C Factor _ _J__i-c.:O:...c~'-.:.0 __ Orsat Syso:e:n or:-;".1:;.. Co .... 'ti-'-!: Bag l~ak Check ----"'ci("'-----

s amp 1 e ro:-.; . 0. ~ci'6-c I . , ' s tart r 1me I L t.:o EdT n lffi< j3l.5 Ob server L~ <-r le< f'1 !"- "" - ( -~, ,,., 

Drv Gas Pi toe 

rd!~1£~~al 1 Drv Gas Pump Stack Filter I mo. Sample C:cck ~ieter 

~n~J~ · Meter 

~~m~~ Temp Box: Terilp Point Time =~~ic Feet Temoeramre Q.F "F OF "F 

!nlei Outlet 

..; I .. , ·' 

- ·~~ O.uLI D 1.30 I. 1, i) ~;; 121., z 0 4ZI Z'>u {,7_ 

z z s £;~;. '!2.. -::J,•,]C /. 30 I.", D iJy I. v 1. D I.J7.u ZSJ :57 

l <; .::0 L.'~': 1..//. ,, <;z_ CJ Ius I. <i:S 07 ~., z.o j'(J z_ zs3 :<: 1/ 

4 IS '-IJ7.! t ,, ~ <:) 1.55 I.S~ (Jj IJ:S 20 3SJ bo 53 

j 

'"· 0 

'-Hf. i8 ;), s, 0 II ' ') d /. s iJ 10 61.1 z.o JS o zsz. 5t; 

(:, .1 r ~57 " 5 1:-J lt •. H ;, s J 11 (,(.; L,C) JSO l$1,. \l , .~.c 4</z.. ;o 0. < "' t.'>c ,·, C:• /J (,{., Z-0 ?<O z.:;tf 51 

~ :" < 1 ' 1./L/ll. t-; u. ucV I JO ;, i\L' 13 &b t.o Joi Z~l/ (;0 

< l~ ;:, </4 5. q c ::1.5!) t. sr /, 5 <; '1J 05 z.o JIJ(, Z-5 C) (..( ' 

,o ; . ~ L•4 7./..S ,) 4YD ! i 1.1D I i.ilO 14 (.,I, Z.o "'>11 l.ll G {, 7.. 

II z.s ;:. <.Jll q. z ..;, J. u 1 i) 1. ,,r::; I ;,LID 1'-t C..5 z.o lt~bl l.S3 (' 1/ 

it. nS 450~ I OrlJ?O 1-J/.0 1.'10 15 (J(., Z.0 l/0 7 l..)/ ~l( 

8 I 3J.) 1./Jl j(.. tl.IJ4 D t.Jo ,, 3 !) ii I. 7 / • .s I./II -z. s 7 IG t/ 

z_ ;z.s 454.1'1:, ''-LiLlO 1. ~D /. J b 1J (,1 I. 3 <113 zsu &5 

J 1":.C ~ 35 /., '} o.tl.~D l.;i) 1-3u '73 ~1 I S t.( 14 Z53 (,') 

q 5? s L.fs7 Lu J.</30 ' t.! D {, lj c 1'1 : (, 7 /_f Lin i!S3 &3 

5 q i). cl '-/Sl. 72.. •

1.'-170 /. 4. 0 lAb 15 Gl /. 5 lj/5 zss &; 

I' ill- I WLD.Z1 c1, ~10 fiJI) /.1/0 '7!. 61 ! ;.c; 4/1, ZS ~ &Z. 

? ui.C 4Gr .. ?"1 D :>00 r.5C I. 50 11.1 1/7 z.o <1/q ZS3 1.7.. 

7 i/7. ) 1./ 1.3 :s 1 tl.5iJ() I. 5 i) ;. so 11 c. 'I z.o 1./W Z-Sl( <.3 

-i s• a </ /., <; I 'R' .:J.SIO /.SO ,, <. n 1'.? ,:.,f( t.D 1./-z-z I zs? (.,Lj 

IJ 5L ) L/U.;,gJ a. sco /_ ~iJ /.'50 1'f C71 z..o t;Z-3 zsz ~l{ 

,, c ( ~ N. /.ItS. 41c D~o f.li5 (.'I$ u (,~ Z.D ,z; z.:; 1.{ f.,i.{ 

,, ~~ .5 t.J?O, 10 o.<fq:J /.:;5 i.ll s 1'1 uq Z.O 4'tt../ I zs0 01./ 

00 •) <171. 71 

31.3L 0.4~7 lt. L/ s 10,0 1>'15. 7 

@lEe 0"" 1 (Zl : '~2 

B-lS 

~ 
lsokineric Field Data Sheet - EPA }fethod I 3' b 

C I,_, !2_ ;cJc_ 3 

lient __ _.:::~~:...;l-'1~=~------------- Run ~umber----,-,--,-----

CityiStlte ___ ~.I.J-~'-'L:·'-:2r-":::.:"r/-'-,-__:/I)_:C:__ ___________ Dlte _ ___:O:_::f._,_/.i-";'J'-+/-'-c;_c7 __ _ 

Sampling Location _ ___J'"-;''-" 1 '-'-' -'-'~-~_:~:::C:::_-,k:_t/:__ _________ Oper:J.tcrs _ __,:;O~A ___ _ 

=============================================================================== 

Amb. <cs Temp., 'F _ __:_::__ Nm!OGRAPH SET-CP LEAK CHECKS 

Bar.Press .. In.Hg, L~.3S <lliw \(\\ Y= u:o Avg:,p D,U~'7 Pre-Test o.oi w ,5 ~ ~ _ _ 10!:: ---'-'---- In. Hg. 

::\0 Ref:, P D. 50 PSst-Test .:J C''4 @ C. In. Hg. 

3cn- ~ ... <::a,t1 . -+ ~- o } v ~·oz. Dia. Desired_~- P~e-Test P:tot <0.1@ - "'· ~ In. H"O 

~ '-

Static Press., In. H::O -c.;, )0 Meter Temp. 

Meter Box :"ro. jco. z..u~ Stack T.::mp. 

Sample Box :-lo. _ __!_1__ Pi tot Coeff. 0- OL\ ~ozzle Diameter ~,) i)C\ Post-Test Pi tot <0.1@ ~-~ In. H:O 

Probe/Pitot :-lo. 2iSJ , L"':J '( % Y1oisture ~.~ ~ozzle ~o. 30? ,Q}C\ Tedlar Bag :-;o. _ __1_1 ___ _ 

Probe Temp. Setting Z5 0 

S I ID~ '70'1'1) L '

. "l1 c ,_j,. I_ 01/ C Facror _ _c;·.::..V..LI =--- Orsat System"'¥~." t:'-..1.!\ot·:u Bag L;::J.k Check _ _:::~'---

ampe 'Q, s tar t Ti tme !'131- E n d 1i ( S 3'( Ob C L._c In Y"/r E ch:r tme server ' -~ "' 

Drv Gas Pi tot Orifice Drv Gas Pump Stack Filter Imp. 

Sample Clock Meter Setting ,iH Meter Vacuum Temp Box Temo 

Point Time cu·~;~·~e~\ ln~i .o Inches ~~'?ual ~~~r ··c:j,;,,;, lnH~es 'F 'F 'F' 

Ideal 

AI ,, ; ... ;;-~~ ,, ,, ~u., ~ m ~r, '· ~ :1 '1:::> 3EJ z~o 51 

t z ~ Li 7Ll. z.~ J -;~::, z 4<': ;:.4D Lf "''i 3 Q 3'73 -c·"1 _.,..., SL 

) <.D 4'71. '~"7.. v.t.f 3b z._GS z.r.,s 11 ~'l 3.0 ]q'( Z..<; 3 ,.; 

" ? <. 4'>:(.tJC: ,;.~ALiO Z.?D z 70 13 u1 3.D L/03 ZSI 5( 

s .o ;:. i/YrJ,/;1 ,,,u~,) 7 r,i) z.oD 7) ~.t! J,u L(OS Z.H t.o 

I; '~-~ ~~LA1 fl 1//,('. z.85 us 1r ur ].5 l{D! Z)<; &?-

7 .~ c i../?), /'7 o.sJ-;; 3,10 -'· './0 7'f ~~~ 3.5 4!0 LSI( 1J3 

! -?-< 411. 57 ;), ;; .::; Jjt) J.ID 11 I' 'I 3.5 41/ l)'J i:Jl/ 

c; z-: 0 1/,r'l '! t. J,•,qs 3.05 I J,oS iL 1D 3.5 4t3 z.s<.:. (,/! 

/v 72 '<; -I../ (ft. 15 I ,14qt ;.os 3.~5 J3 10 .J.S l(f] Z.SLi tv~ 

II ,.;, c U<tl/11 ,, ::15 2. 'l 0 ~ !ii '70 3_11 41'2- -z::;r ld 

,-z. z" < '' J L/'17 oG 0.4YD z. 9.5 7.. '(5 '?[, 71 J,c l/ It- Z.Sl< it, ~ 

Iii' I 10-0 l.(qq .47 (J~<,QO L4S z. L/ ~ '1<1 71 ],0 '111 z.s~ 01 

7 '"5 c)c;. ss v. <h.'D Z.0/5 zAS <;'/ 71 ]. {) y lq Z.:03 1.1 

-~ 35 !) 5!l< 1,1 ,l .. 4t/o 7 ?u ·{.77) :;.-7 7 I 3.0 l.f '1_ z.. zso &2. 

4 ;~ .5 :;o).'if o.4su l.!O LfD :n 11 3'.D 4ZLI 7S3 lo"l-

.. ••. 0 ~~.1 <'.I.~ ~"i')' C' :: 7 () I~ 7c- f'1 72- ~ 'IZ'7 z.::- 3 6-:_ ->· "' 

G ;IZ-5 ~-;-,,. "' I ·7. "'' ~· Z.?o z.fi" p--; )2.. r_ o '-<2) z~-, c::; 

• i/<;, 0 s-·1.. 7o !-; -rt.- 2 5>. ? ~'i I ("_:,- )L 3.v ,_,:;, I c.,-:... ,_ 

- ... 

;J u?.' ~15.0'1 J.'/57:> lt.rO z.to 61 13 J,v tr3/ z.) II (..j 

•i s<>.CI 517.3 I I cltK0 t.SD z .80 17 73 3. D <(32 7 ~ <( 01{ 

,.:; 51,) 5/'I.IJ< ,J,t/~<) z . .ra z.w :<i 73 3.u Lf34 z.s z_ (,5 

II SJ .o lsz.u~q n.l/10 7.b0 l.~O ~ 74 3,1) <f3L.l z..~q icL 

It ---· I :s . 'Z'L vq lo oiJo l,J'5 ? . :s 5 ..r1 7'1 3.0 l/3 5" Z.Sic G] 

toC .J _:'ZI,..l!( 

54.17 o. Y'l1 IL:J(;, 1~.'b ~ "'· '0 

6~/k_ Do<" t/ I Z "2., 'f7 ( "Qi't' D-19 '---
EPA J[erhod 26A - Jfoisrure Derermination and Sampi>! Recovery • Data .-Inm}szs 

Client ~-a.GJ.e Lc:C 3.2,c.k:. 

Cirj;St~te .SA-N;::;,.zv, ;/c_ 

Projec: Number c-/?, -7? -c/S, 

Sample Date '-/ -IE -'i '1 

Somp lil::g Loco tio n _r:~::.Z.=r..:c_=-·-<-.:::_ _____ _ Samples Recovered By _ _!:K=r·_c...:_ _____ _ 

Recove~; Date 'f- 1/3 - 7/ C!ean-Cp Box Number __ ..;5=--------

C~J.i..n of Custody: Date Received c~- !c. ; q 7 Received By _ __:_f..:r<::cJ'--- Locked''--'=---

Equipment Documentation 

R;,m :.;umber I I 2- ..5 I 

Sa::no!e ID ~umber 7DY8 ·/) I 7e<f8 . I z_ 7d& ·13 

Sar.mle Box Numbec If I 13 /1 I 

Probe Number I -z.co C:J'-1 

:;be; 4 t:; c ~ I ~cc . c ·?<4 

20C C3<f 

Analysis of :'vfoisture Recovery 

Real!ent Recover/ Container # 1c'IB -1 1 I 7d& -I 'Z- I 7o~IS ·13 I I 

Imoinzer Absorbin£ Solution C.I.J H~)O-{ I (), I,_} 1-h~c'-i I C.' .J Hz 5o'-/ I 

Des.:riotion of Reage:-n C.LE"'".4 ;z._ I C'-...G"»..2. CLL?>R.. I I 

Rea\Zent Level \1arked? ,/ I ~ ...- I I 

F'nol Volume. rnl I 2 5Z- I 2-+'=> :z.c,c I I 

Initial Volume. ml 2.0C:: I 7,C.C I ;:/00 I I 

'.'et Condensed Volume. ml 1>2- I '15 Go I I 

R.:J':!ent Recover; Container# 7ctf: -II I 7df: -I'-. I 7o'le -13 I 

lmoinozer Absorbina Solution OI..J tJ~•o-1 0.1...! ,Je..e.,j O.,,J ~-.lo.c.-1 I 

Oescriorion of Reazent cc~'")l. ;2. I <::..£..~2- C'-t~IL I 

Reo£ent Level :Vlarked'' I 

Ftnal Volume. ml 2c'l I zcC- :z.o7 

Initial Volume. ml zeo '2-= 7,cc I 

:--:et Condensed Volume. ml ~ (, '7 

5i!ica Gel Recoverv Container# I "2. 3 

Per·:ent Silica Gel Soent 5D c.,s-- so 

Fiu.1i \V d~ht. 2 2 f 2. . G::. Zl~-5 213.0 

InitiJt \Veight. g :Z.oO I :z.oO z~o 

Net Absorbed Water. g 12 (., /~- 5 1,3 D 

Total ReJ::zent Collected. 2: 'l3Ja c.,.; 5" So.C 

Sample Recovery 

Reccn:erv Container# 7c~8- II 'lo<!e -• ~ '7oHl -13 

Rinsing Solution l), .J .. n.-i.. \),t,..)A--')l;.""J!.. l> ( ~ k ·:-rp_ 

Samole Cont~iner Sealed'? / ,/ ,/ 

Liouid Level Marked'' / / ,/ 

Reagent Blanks 

Absorbincr Reaaent Bbnk c i ,_} HLS<'<-i Rinsin• Reaoent Blao.k p,J .. ~ 

Absorbin• Blank Identification # 7dB-I..j RinsinO' Blank Identification # 7o<! e -1<-/ 

Absorbin• Rea~ent Blank - Rinsin• Rea.ent Blao.k ~ 

Absorbing Blao.k ldentilication # - Rinsing Blao.k ldentilication # - Aoalvst lnin'a!s t<_r={_ ·-···· ··.·····.··········.. ....... i · ... ·······-···· . 

Rcvil!~~·t!r !nizials J,( . .·.··· ·······--·····-·.··-·· ..... · ... --... -.... · ..... - ..... 

13-20 

b/ 
Isokinetic Field Data Sheet - EPA Jfethod ·.;__ v ~ 

Sarr.pling Location ___l(/-"'' !~(_tc.>"___;,~_!_r"_:.(~--~)._::..____________ Operarors -~J l:...:.f ____ _ 

=============================================================================== 

Amb. Terr.p .. 'F -~~c..:·'---

Bar. Press., In. Hg. 1- ~ . '-/ i 

Staric Press., In. H:O - !) ~ ~ 

~lerer Box ~o. ·)flo ").J <../ 

Sample Box 'lo. _..!...(~/ __ 

Probe/Piror ~o. ..l..c -:.~ C3 --1 

c,H@ I ,, G 

Mere; Te:np. 

Srack Temp. 

Piror Coeff. 

% ~1oist:Jre 

NOMOGRAPH SET·CP LEAK CHECKS 

Y= 

f.(" 

YIC' 

0. ')-,( 

'-I.S' 

Pre-T:::sr ('1/..., i @ '~- fn. Hg. 

Posr-Tesr ~~ 0::.5" @ ,. · '' In. Hg. 

~oz. Dia. Desired L' .l71 Pre-Test Pi tor <0.1@ b -~ 5- f In. H::O 

:-.iozzle Diamerer 0 .)I{ Post-Tesr Piror <0.1@ ZW( '{J In. H,O 

~ozz!e ~o. 3C::.1 CS";l Tedlar Bag ~o. _ _..J.._ ___ _ 

Probe Temp. Setting ~ _) C C Fac:or O.']'ll 

Sample ID ~O- J c., 'I'.> - J/ Start Time r~.·; ..,., f. E.1d Time 1 I : Obser.:er c_, rs f"1..: :: '\' ;_., 

Drv Gas Pi rot Orifice Dr~ Gas 

vl~{,m Stack Filter I mo. Sample Clock \-{eter 

~n~J~ Setting ;lH Mer~: .... Temp Box TerTio 

Point Time Cubic Feer Incfl:es H.O j;;j'~[ "i5.{tl;; 'F 'F 'F. 

Ideal AC:ua! 

~I L, e c..,'< ). 5 C. q;, .}, 7) ) 7i 5.-s <~ '-i <-:- '133 ).'-/7 Gl 

") \ o-1; -1; t'· '-J {, J 7\ ':) . 71' n )- ~ <..1 'ir <-;13 ).4 J '-1)-. 

3 ,- ,, 0'1) b" c 'I 7 .) _7'• ) . 7 'i <,'.:, )- s- '-1.1;' q I .2 J- <./ 5 'i 'I 

L ~.1 c-i<l, yc rJ,,ft. 1. ?S' ) 75 )C, ~- 7 q,y 4 '1 ~- ~.; I u '3 

~- I, •. L r::-'i7. C1 I C . :J 1: ). )) ) . 7 'J n .; 1 (/. 'r '-i ')...(, ). ,-c <I ;t 

G ) ( ('~ 'i 1. 3 L:.<-i5' ;.. 7o ). 70 Lr ~-y 'f-, y 4 ,.,._ )- '-1 7 4'1 

I I ,· . (.' I 40 o.';c 3.cc j.c,'(' 6) ~--s- r.c' 17'-', J w'y '/'-. 

.'r ; 7 .,- IC 1. ( <; c s·1 ), 10 '5 I C 6 { )- ':1 'f. I '3)<./ .~~;<! "iC, 

"I 1.. -~ !C(·C'.S t.J ~·)" ) .J 'i ~ J.S- ~,- .,-'] (<;-. -n 3 ,-, d,<J 'i s-; 

},] }J. ) /,J ',f' J(' 0.•;) ·~.j_c -; 1 c' u. ,- <:r '-.-' \ '?)I ;;l<J)- ~3 

II ~ 7 ;'(-- /!(' . 7(_ {) )f 3, ~c '), 3(} C,:-r S""' )-. \ -;).J ,').. 4'i )G 

I ) [!!)7) ~~ • .s I r1 ' :l ~o.t , J ')' U'_, (, ,, (o{) (.(I \75' ).) "i 'I 

,j I '~ ?l'--<:J 1,..,. )<;-- C·~'i 4 ~, .),.'r)- 6 ~ f..., I " . c I_J(j') )')3 J) 

]. ~-'- /17- t' ] 0 u~ :ZIT\ ) .:,-.; ;;, (.j-. ~----:;; (J (l iJ ).)] );;2 

.3 ~ ,-0 I.,, <,I O.<IS ) L•C .) he.' ( (. t. I >.c) (.j(l/ ;;.>c.' 51 

4 > 1· ( I ,}::l,. 1 \ () ~-, ~.c~ ),(_)') {,7 bl \- I '-{I c '). ., ' )j 

( 'lc o '-, 'i. <./ <.) (I 5' I ?,, 0 ') 3 c< ?:c.: r I '-i. I 413 :;z " ) .;-? 

( '-/). .s I::Z0 7cl 0-~-3 3, ro ':10 G'l (_ I 1. · I l..i1u ).)I '>'1 

7 4\- (' l~'i.l) J u't ) . g-<: J .,.,- 71 (:; :}. ) i' '-<I <I ;;/ll 7 5'( 

'i> '.1 7 ~- I ;,1 , t.J J 0 '<I J, J. 'ic .).<;[! 7c' (, I !./--:;;: /Jil ))"() iC 

'I ,-c c 1\J,)(_ 0 .<;) :J. )C .) 1 (') '7) (; ~ -:r. <' 41" ). ,::, >9 

I<' "1 5' i ~) 7 (, (j '~ (, ). ') 5 :J.. .){ I'? G~ s· . r- I.J '<' ;}'-' 7 s->-

II ,-~- 0 1?1f Ol <-' <.1 I ) .4_ ~ J <I) 71 ' 3 w.y ';I) ::1 >"l )5' 

11 ,-) s 1'-/0· II..{ o '-II 1. <1) )_ <./)- 7~ r;_q <.j."i" "" ~)') n61' ,:1 I ·~ J. . J ~ 

-z.BS ~,- '1. rJ o.<~'lo ~ ! 28 -''i"S,v 

~' 1Z -~ ;.1:'~"11·~ {? }0 ,;. f,Z2.,97 ::f S t, ... r ~,..~---.. '1 :.,I q i' QA.,,£;:c Date: U-i ..... . .) 

[)CB:2~~ I 

'--
lsokinetic Field Data Sheet - EPA .vlethod _;1. ( -1 

Clienr I .:.- ~ 6 ,--,".::_ f.- Ron :-;umber __ .,_:1. ----

Ct;I/Stare .(. , :f..:,./) i"v' f Dare l~ -( - t·:· - I 7 

Sampling Loc:uion _.D.;_I..!l._.J,__!:_..!.._:....L ___________ Ope;arors ~'CL· t lc___ ___ _ 

=============================================================================== 

Amb. Temp .. 'F _...J>C...:..:• 0:::..___ 

Bar. P:-ess., In. Hg. 05 ~ rr 

Staric Press., In. H::O - C ~ ~ 

);!erer Box :--<o. 3ct ).1 { 

Sample Box :'-io. I 3 

NOMOGRAPH SET-CP 

.lH~ I 'iC 

);I e rer Temp. _ _:,.'.!..:_.,:._____ 

Srock Temp. _3,_5.L5L---

Pitot Coeff. ---''"-~ _,_'r...:..'-' __ 

Avp P Q,<.!<;( 

Ref .l P (J ).. 'l '1 

Noz. Dia. Desired (? ) 7 (, 

Nozzle Diameter 0 J !I 

LEA.K CHECKS 

Pre-T:::sr r:. oo (../@ I;, [n. Hg. 

Post-T:::st ?) . OQI...l @ b [n. H?. 

P:-e-Test Pirot <0.1@ 7.).. {"I In. H::O 

Post· Test Pitot <0.1@ r;.fi' t..( >ln. H;O 

Probe/Piror ~o. ),oo c:o-3 </ % \<loi,ruce 4 · "i ;-..[ozz!e ;-..[o. Jc.: C ~ Y T.::dlar Bag :--ro. _ _JL;:_o ----

Probe Temp. Setting J...;,-c C Factor f ~ 3 5 Orsat Sysrem c-.J~'-f .ti·J:obl .... Bag Leak Check _.!::O:..r.:K~---

S ampe I ID 'I I '</'i- I J Sro r Ti e ');;! C7 . o. c r lffi E dTi 13;1) Ob Ctour,, V"1 r- eLc n 1me se:·ver ' -~ ~" 

Drv Gas Pitot 

~~:;1& Drv Gas Pump Stack Filter Imp. 

Sample Clock Meter Reading Meter Vacaum Temp Box Temp 

Point Time CubiC Feet "'p Id~~i ~cmal ~~~i -;5;:,1;; In~~" 'F 'f 'f 

ln. HD 

A I CJ () "'iZi).. '-1 7 a." r. 1 Yc J,t0 t;;<J t-.4 4 (. 4t5' JS'i ')'-I 

,). " ,~ fi•U 1f.. 1:'."' ') ~-) ,- ;) i) (<J (, Lf '-{,_(. 37'-/ ). ) _) ,--cJ 

3 ro {4{;. ~-y o s-o 3.cc 3.0C (. ) (o'-{ '-{. y ~ n-- J )' J '-\"t 

1.{ ,( I 4 .'\ , ;.c c__') ' 5-1 5, I .; ", 12 ( l (.4 L/' y 3f./'r ).</'-( ~-7 I 

r h' n h-1 '~-) 0 . ) ::2 '.),; ., . ). () {.';r 6'-1 ,, '4 ~" 7 ;., )<I <,. :~. I 

i j). 5 l'l"' 'i?- Q.S'3 -?.ri ~ ~,- G 'l & .-; '.() "3'-17 ;.. ·-a ~ r-

) I~-. 0 il-t..~_3 o . .,-o ( ,(;(' '?_cJ 7::1 6) <.(,y N7 ) )-, ~ .Jv •}. s I)' 'f, 7 3 u, fc. ;; ''-! 1- • i.<-1) -._;;_ (u )-,"?_; 3 3) ), )'-1 {.. I 

"' J.- n //,I.e!', L• ,q 7 -~ i-; .:l,ri /) (o ~~ --q,~ ) 7'f .. ')} 

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1C _).') \ I L ~. ')) J.~lb ) '~J .7 to 1':. t:s 4. s- ) 'i I J r<-! I. 3 

i I ,;l ( 6 ,T~ 73 c r.J '-( J.. h' ;;. . 70 7 I ')' '-,'I 5 3 'i c; )_ '-) "' ' '3 

l:l ,;7.f /p-:c; 7 75-;:1 q d.~ :uo 7<;" -~. 'l~ y3 4cO :1 ~-7 ''-/ 

A I <.t> (') I "/. I :t' lJ, '-1 I J., rc J. -;-c) 7J- &C. ~, <./ y :l. 'J-G s· 'I I 

.2 lo.( I))._~() (j "{ ;). -;..,)) ~-'i\- 7J.. {, 1 LJ I 410 J. .,- ~ ::,-r-

? :!, .; - i) i/4.'-{C, o--o )..)\' ). ~-; 7l ' 7 "'' '-Ill )._ •; 7 S< ~ 

4 n.( ;?,(,7 O'i.] ). .{.(; ).(Ji 71 (, G. u ·' t./rCJ c:g \ 5') 

\ (J 0 0 'n. ~3 0.'-13 ). -~ ;)._(. (} ?:; c~ t_; . I 410 ~-) I )'3-' 

i r.J) { lt.-'1 117- t? ·" ~ :). f (' ).{(~ 7f' (.~- ( <-II 41-::l r \'S n 

} 'II. ·' IY~ Ll. a, 4 ~ 2. C.t) :;. 60 7r. G0 4. I ~,,__, ;;.. ,-!/ (, I 

" u' ,- (<,-\. Uf () 41./ ) 71' ). )() It:, 6'] "-1 . ; '----( ( (., :;L-'7-J 1 I 

~ .;·Lry C ty'),I,L,- J .'-i~- ). . 7 ) ;;. . 7) 71 C.) r., ~ '-1 I (, )>'" ' '). 

tC '- ') . . ,- !V'i.'i{") u,w.; ]-., 7 ~ ).. 7 r -, 7 (, 1 '--/.<(" '-j,y H'C (, ')_ 

(I ~'7 "- •"i.f. tC, 10.4~ ;),5{ ;;...;;? 7 7 C,l ..., j '-/If ). )' ? ' '-I 

I ~ [.),t; /C.,~ .!4 JJ-yl .?. . 'i i) .J S'll ]'i( ?~ <--1. I '-{ I y J_S'T t:, L/ 

,: ,, c.' tC:.f..)6 

(Lirn I r, 4)'f -~ ./CJ £!?~ Y7f.4 

~fFc o ... , r ,zz, 11 .i.Jo _. 4'-; i 

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lsokinetic Field Data Sheer • EPA .Verhod }. C .-'1 

Cient L _ _. · r:;' -, ~ k 

City;State . C· ~ f, ') I'J' ( 

Run :-.Ju:-:-.be~ --'-------

__ Date ·:.; .... ;Y··; I 

Sampling Luc::mon )C- I,...., .) ;1. Oper:Hors .J J r 

=============================================================================== 

Amb. Temp .. 'F ~ ') NOMOGIIAPH SET-CP LEAK CHECKS 

Bar. Press., In. Hg. .:<_ C'l · 3 <) .lH @ I 'lC y = I~~~~·· Avg ~ ? (l <..../) "/ Pre·T~sr 0 rce; ~ ru,, --'-·"'-,~- I H n. g. 

Static Press .. In. H:O -Ct ..; C..; 

Meter Box :-<o. 3 00 2; '-1 

Meter Terr:p. 'y.D Ref 1 P C 2") G Post-Test '-1 Cc '·{ @ 6 0 In. Hg. 

Stack Temp. 3 4 I 

Sample Box ~o. _----!..:1 '~- Pi tot Coeff. 0 'S i.l 

Probe;Pirot :--.;o. -9. CJ{J ~ 3 v % :Vloisture U · C."' 

Probe Temp. Setting )TO C Factor i 0.5 { 

S amp I e !D'I . 0. ),~,,. . < . !J Star·T • 1me ILJ3;( ,.. 

Drv Gas P1tot 

Sample Clock .\ieter 

Pomt Time Cubic Feer Rn~;Jng rn: ro Id~~l 

! 4 i 0 0 lqc, ?-{ C -io ~.'{<)' 

) ") ,_;' 17>-. '>j c.n .. 2 J(. 

~ {-. I' ~eel 'i ~ "' 3 7 ) lC 

'-I 7 )' ).0 ~. 00 c] . ., 7 } )C 

r f(;. {) ).a ') o) 0 3i J..<~c 

l /) s ).() 1 il- G.-if ), )~· 

} I(. 0 IJ.c'i.<:s- 0.'-{f l. ro ~ 11r .JJ),L!Cr <!;' '-( <.{ J,, h-' 

~ ').<). 0 ;<I) c, G .:.'{, ) ,5'{ 

I(' ,-;.;;.. ( ).!k- ,()I ;[J. '-{ 7 1<',) 

1 I ?. ).Q )..!'). lf,- (),<-!U d..?,' 

,.) ,'). 7. <: ')....)..0 6) () '<J 1../ ) ')t: 

y;; I '(]C) j).:J~7 I c « Lj J. .7c 

) ~ J. )- J. ').<) a ;; C',<Q ). (. 0 

3 1, ,-. 0 1J. 7·3~ c. 4 ~ J. . ) . ) 

4 -,)) .;:{J-'1. 44 l' ·4 3 J. .& 0 

; LJO· 0 J,?.,t.~i1 -' w' J, ~( 

[. i.l).) J.\'10}. C>.'i-1 J >-c 

? u' r; .l J,[ .. ) a, C L > ) (, () 

q {J 7' ~ 1 ~~.n O.u 3 ") 6 0 

q I {y. c ;:;. "c;, 7 :l. 0 ·''. 1 7C 

,(l ') . .,- ~'I) c, G ()' J 3 )..(,C 

II n·. c ,1.45 I 7 o. 'I) ).. (; c 

I] C? ,- ?.1/' d () 0y1 1 .)( 

?0 0 u"/7'0 

.:;-.] "' '-/ 'I'J.cj,J.'f 

(~~Jfc o .. ., I{ .z,.t. ! r7 

-

Noz. Dia. Desired .Q...l]_i P:-e-Test Pi tot <0.1 ·:Q:· j" ~ '.'-!In. H:O 

.Sozzle Diameter C 3• ! Post· Test Piror <0.1 @ l ~ 4 7 In. H:O 

:"J'ozz!e '-."o. ?tltl 0<fY Ted!ar Bag ~o. __ L_ __ _ 

Orsat SystemL.L::..·,/•.$ ... ~1-Bag Leak Check _cr-_r:K)__ __ _ 

EdTi n ;me !"f"T,? J Ob server C.~ ., i<s V""/ ·"I~ ' . - '(.-...;..r 

['lli Drv Gas Pump Stack Filter Imp. Meter 

~~ffi~~ Temp Box Temp 

,-~i';al Temoerature <)F 'F 'F 'F 

Inlet Ourlet 

;;. . -I') ' I f. I 4,/ I")M~' ;] j'<l b' 

2 :lu £ r t.: '7 '-/() S''i c ). "I J r;, :J 

' 3c (,'1 r~ 7 <-1. c )']) ),4~ (,I 

J 3C t'i C7 t..j '6 I'i" ). •I) (.I 

;;. </ 0 7C> ~ 7 4, I '-tC<O ). ')0 6-;l 

). . ')c) 7). (. 7 '-II 'iC3 ).L/7 G.t. 

3 )0 n (, 'l Lf, I <1 us- ")..'-17 ~ ;;} 

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) )CJ 7~ 7>:1' l.!.t; /.fo4 )5) bO 

) )() ((, ., () 'i ''l- 41 s- ,)U 60 

:::.~c 7 -: 7 ~' L(' 3 i-tt..S d-~ I y')'" 

).f\ )<( 70 i.{ ~ '""' ~<Is 5) 

.){,() 7¥" I I 4.~ 1.{1~ ;l.~~ <5 

')., &-{ . ?'f 70 u s· Ll ). ';). ). s·" <;</ 

;;< '5-C 7~ 7o <.I. ) 'i )i.J '}.. f J s-'!_ 

;. to 7'1 ?o '-' . I 4 :u; :f,'ly ~- '{ 

J ~0 7<i 7 () v . I 4).7 ;;.. )I.J S'"<; 

J, )o 7rJ )G 4 ~- ...... J "1 J.q y ,,. 

) &i!J ii'C '7l •1.3 4l"t ;;.. :t'S' s-r 

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J. . 1-i y) 7 I ~' j q )'Y. ::z $'( \ r 

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H6 ~ 1 <;ti,C',/ 

!..s, ~ IO/ '3 

£1.23 
APPE:"o/DLXC 

.. LABORATORY DATA - ' .· 

., 

:-1 
ENGINEERING CONSULTANTS, INC. 

6200 Harris Technology Blvd. • Charlotte, NC 28269 • {704) 598·1049 • FAX {704) 598·1050 

April 22. l 997 

REPORT OF LABORATORY Al~AL YSIS 

Mr. Rad Holton 

Lee Brick & Tile Company 

Post Office Box I 027 

Sanford, North Carolina 27330 

Trigon Project !1/o.: 046-97-048 

Trigon Project Name: Compliance Stack Test April1997 

Trigon Sample Number. 

Date Collected: 

Description: 

ln~u:gaoi~: aoilb:~i~ 

Date Analyzed 

EPA Method of Analysis 

!.!nils 

Fluoride as FVolume of Solution 

Fluoride as FTrigon Sample Number. 

Date Collected: 

Description: 

Io2rgaoi~: Aoilb:sis 

Date Analyzed 

EPA Method of Analysis 

Fluoride as FVolume of Solution 

Fluoride as Fmg/1 

I 

mg 

!.!nils 

mg:l 

l 

mg 

7048-0! 

04/l 8/97 

RWll 

K2PC-l 

04/22197 

340.2 

102.2 

0.650 

66.4 

7048-04 

04/!8197 

RWl l 

K2PC-2 

04/22197 

340.2 

!37.8 

0.650 

89.6 

Comments: All of the above data has been blank corrected. 

C-2 

7048-02 

04/!8/97 

RW12 

K2PC-l 

04/22/97 

340.2 

93.! 

0.650 

60.5 

7048-05 

04/18/97 

Run2 

K2PC-2 

04/22197 

340.2 

102.6 

0.650 

66.7 

7048-03 

041! 8/97 

Rwt3 

K2PC-! 

04/22/97 

340.2 

98.1 

0.650 

63.8 

7048-06 

04/18197 

RW13 

K2PC-2 

04122197 

3402 

!46.0 

0.650 

94.9 

7048-07 

041!8/97 

Field 

Blank 

04/22197 

340.2 

<!.0 

0.650 

<0.65 
Mr. Rad Holton 

Page 2 

Apnl22. 1997 

Trigon Project "'o.: 

Trigon Project Name: 

046-97-1148 

Compliance Stack Test April 1997 

The data contained in this report were obtained using U.S. EPA approved methodologies. These data have been 

reviewed and are approved for release. 

Paul R. Jenkins, Jr. 

Laboratory Director 

QUALITY ASSL'RANCE DATA 

Analyses were performed using Orion Model 720A Ion Selective Meter. Serial Number 001390 and Fluoride 

potentiometric electrode Model 96-119 BN, Serial Number XZl 01736. Reagents used in performing these analyses 

were logged in the Trigon Laboratory Analysis book as follows: 

Fluoride Standard Number 3173-16 Lot Number F:2 11 1,000 ppm as FFluoride TISAB Number 7-34021 Lot Number 02276LL 

Fluoride Electrode Filling Solution Number 90000 I Lot Number YZ1 

The slope for the fluoride electrode was -57.9 millivolts. The acceptable slope for the fluoride electrode must be in the 

range of -54 to -60 millivolts. The following matrix interference checks. calibration performance checks and precision 

checks were performed: 

Trigon Sample Number: 7048-112 7048-113 QCl-710 

Date Collected: 04/18197 04/18/97 07/15/96 

Description: Run2 Run 3 Laboratory 

K2PC-I K2PC-1 Control 

Duplicate Spike Code 64669 

ID!l[gliDi!: ~Dllb:5ia 

Date Analyzed 04f22197 04f22J97 04f22J97 

EPA Method of Analysis 340.2 340.2 340.2 

J.!n.il.:i 

Fluoride as F- mg/1 91.8 87.9 9.89 

Volume of Solution I 0.650 0.650 0.100 

Fluoride as F · True mg 59.7 8.91 9.73 mg/1 

Percent Recovery o/o 1.4% RPD 98.7% 10!.6% 

Sample No. 7048-113 spiked with 4.0 mg/100 ml of Fluoride as FRPD = Relative Percent Difference 

C-3 

bl 
~ ~ () j. 

Trigon Engineering Consultants, Inc. 

Company: L, ... /y, .• k 

Address 5"f•·•{ ;1r L 

/ 

. 

--

Sample Description 

r<. '"I I .. tjB •• k '""· f,H,r •• 5, /, fo-. 

' R," Z .+,,,1/8 • .1< ' ...... fH .. &....~ s.t.f,. 

f/.,"3 f •.. _l /&..~ ,.,_ i-/1,. !,..~ ,_;.," 

(('"') f, .• f/R.-" .. ~ f.li, ·. t •• l; ,,,,f,., f._~"'- f, __ jjb,.( r"'"- lr. tL b ..... k, s,t.:f·· 

f._·<> f,. }ft.·! r•"•· j.' f •' b •• ; s.o •. 

f!,/ •. , k · 0. Hz,. .f. Hu bf,, J, 

ff .J/,5.b"1l•ished lly: 

Relinquished Hy: 

Received fur Laboratory Ily: 

Chain of Custody Samplet·'s 

-

. 

Signature 

-

·-----

---

... ~ 

Contact: P.,l J.o/(,.' Number of Samp

Project No. <>'rt-<1 7' d'l' s Containers: fn·

Purchase Order No. l fl. Pjjt .... 

-· 

Sample lD Date Time Sample Disposition 

7d'18- r> I ""/,s;;; a'H3, /), 11-zv/ !:,rnl kz.P

111-5" 

}to'>'E - o .,_ p'Yc ,glj, /llD • I? I~ p.Ao/~,,nz loP

7o'18- o3 P'>'j '9f.,} mz-tnl 0.-lt. o !F~<n~ 1\Z.

N~8 - o'f ~r;&l,) o?5) · /111 /).· 11z.o I r., Tfj' K7..

7d'rS - o>- o"/,._1'/. 

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7o't8- ~>6 o'll,t;, l l'/11-m1 f) II,_;,/;:; w .. :L J:.,2

)d'tg- 0) "~.V,; - 0. ·I/' t> /!it TW-

Datc{fime 

MA~)ldny: 

'L-21- 111 / )"» _f'CN./ I 

-I-' 

Date{fime v Rec~ived Hy: 

I 

. . 

-

. - 

Date{fime Comments: 

I 

I 
Trigon Engineering Consultants, Inc. 

Lee Brick 

(046-97-048) 

Analytical Report 

(0497-24) 

EPA Method 26 

Hydrogen Fluoride 

Enthalpy Analytical, Inc. 

32 I I Bramer Drive 

Raleigh, NC 27604 

919/850-4392 

C-5 
Summary of Results 

~• 

--~ ENTHALPY analyt1cal, 1nc C6 
Comp4Dy: TneorvLee Bnck Cliem ff: 0464 97-048 i 

' Analyst: BGH Enthalpy#' 0497-24 

ParaJl)l:ten : Hvdroacn Fluoride. PO#' Verbal 

lfS~es: 7 Reoort Date: 05112/97 

Compound I Sample 1D & Catch We1ght tug) 

7048..08 7048..09 7048-10 7048-11 7048-13 

Hydrogen Fluoride 68,159 68,170 52,208 87.497 75,711 88,263 

r.7 '1•\ge: 1 

ENTHALPY analytical. rnc. 

:?/ 
Results 

.,.-~ ~ C-8 

........: ~ ENTHALPY ana1yt1ca1. inc 
..... • S; ~ ~ ~ - ~.3 ~ ;: 

'-..~~ ~ -; :i ,; 

~ ~ ~ ~ ~ 

~-, J~ ~ 

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C-9 

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Narrative Summary 

,..-~ 

:::~ 1 C-10 

......: ...__ ENTHALPY analytical, inc 
Enthalpy Analytical Narrative Summary 

Companv: Trigon En!!ineerinll Enthalpy#; 0497-24 

Client#: 046-97-048 Anal_yst: BGH 

PO# Verbal 

Custody 

Analysis 

Labeling 

Reproducibility 

Quality of Data 

Reporting Notes 

Parameters HF 

Samples were received on .!./23/97 by Steve Eckard after being relinquished by 

Paul Jenkins of Trigon. Samples were cold upon arrival and kept cold during 

storage. Prior to and during analysis thev were kept under lock with access only 

to authorized personnel of Enthalpy Analytical, lnc. 

The samples were analyzed for hydrogen fluoride according to the procedures 

outlined m the EPA Method 26. Quanntauon was performed a Hew leu Packard 

series 1100 High Performance Liquid Chromatograph. Detection occurred by 

indirect UV at 280nm. Separation was accomplished by a Hamilton PRP-XlOO 

150 mm x 4.6 mm anion exchange column using 2 mM potassium hydrogen 

phthalate pH6.1 as the eluent at 1.2 mL per minute. 

Standards were prepared in 0.1 N H2S04. 

A four point calibration curve was run before and after the samples. Data from 

all calibration runs were used for the calibration curve. The linearity coefficient 

of the curve was 0.9999 

OK 

OK- The lower (first) standard calculated values were between 66% and 147% 

of the tag value although the peaks were well above the noise level. The 

samples did not have similar variability in the reproducibility. All samples were 

significantly greater than the lower standard. 

OK 

MDL --Minimum Detection Limit. 

LOQ --Limit of Quantitation. 

C-11 

ENTHALPY analyt1cal. 1nc. 
Sample Custody 

,-~ 

:::~ 1 . . C-12 

.........: ~ ENTHALPY analyt1cal. 1nc. 
'(j 

0 

"' 

( 

'-

,._.,,_,_.,.,. 

Trigon Engineering Consultants, Inc. 

Company: L.. b •.. lt. r '• 

Address >:.. ·t. -r "' 1. 

( ) 

Chain of Cu11ti>dy · Sampler's Signature 

Contact: f., 1 J:, lo. ... 

Project No. o¥/·1.,- t:J ..,, Purchase Order No. 

Number of 

Containers: 

7 -IJ.. p ,, 

/'·/ ' tj.//'"

Samp

rYJ. 

H

Sample ID I Date I Time I Sample Disposition 

............. 

' I 1 ""'/).· r. q 1>.., ll /.. ...... , 

Q. · l. '·, t' .·1, I , /,._ Jc 

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&' .... /.. f-/ < C. ],1 7\' -"''J , 1 - o./L //).·/ .-:. (c;,_

//' By: 

/),-(j I .. /.1/ . 

fl L 

Received for Laboratory By: 

Date(fime 

II I r;,{J 

_ 

Date(fime 

___ 

I 

__ _ 

___ 

I 

__ _ 

/ I' 

\<·- 

.2 l /It ...,,.k./1 

n .F- .. 

A (,'; By: 

' Comments: 
Sample 

Chromatograms 

,..-~ 

:::~ 1 C-14 

.......: "~ ENTHALPY analytical, inc 
=~: es:::...:;r.. ::·a::e 

Sa1:1.p:..e Name 

Ace. Ooe::-a~or 

S ~1.:::.....,",:...:::. ';:;'.:lo e~ ..... --... '--- . --- _o,.cq. Method 

.4l: .. a2.ys :..s Me-:hod 

Las:: changed 

08 -Nay- 97, 20::6:4: Seq. Line 

'7048-08 ~,, Via: 

!3GH In~ 

F:\H?CE~M'\2'.SEQU~~CE\0497-24A.S 

A.NIONS.M 

F:\H?CHEM\2\ME~HODS\0497-24A.M 

5 I 9 I 9 7 9 : 3 7 : 2 9 .Z\.!"1 by BG2 

Ar ... a:..ys:..s c~ a:--.. :..or:s Ion by V-;a:.e::::-s ~:;c:. :::·: - PRP-x2-0C 150x4 .l :::o:u:nr: 

WJD1 A. Wave!engtn-280 nm (0497-24A\054-C50~ .Q) 

mAU ~ 

175-

150-

125- ~ 

N 

100- .,. 

.,. 

N 

75-

50-

25-

/ 

0 

0 2 4 6 8 

Ex::e~~al S::anda~d Report 

=====~=============================================================== 

Sorted By 

Calib. Data Modified 

Multiplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area AmtiArea Amount Grp Name [mi~] mAU * s [ng lull 

-------l------l----------l----------l----------l--l------------------

2.442 VB 888.68726 1.49852e-2 13.31719 HF 

Totals 13.31719 

===================================================================== ~~~ E~d of Repor: ••• 

G::-cuc::o 5/9/97 9:4:3:16 AM BG!-: C-15 ?age 1 :c:: -
,-

.-

..... ~ ::: ,_,, ____ _ _,.:.. .. -

I:-:j ec::.i::)r_ Da-ce 

Samp:..e Name 

_:;:::c;. Ope::-a:.or 

Seq'.J.enc<::: F:.le 

Acq. Me~hod 

A.::a:..ys:..s Me:.hod. 

Las= cha:1ged. 

02-May-97, 2C:2S:35 Sec. Li:1e 

7048-08 *ll V~a: 

BG!-: ~-

F:\E?CHEM\2\SEQVENCE\0497-24A.S 

AlCONS .M 

? : \H?C:iEM\ 2 \ME':':lODS \. 0 4 9-:- 2 4-~-. M 

5 I 9 /9 7 9 : 3 7 : 2 9 A."l :Jy 3G:i: 

54 

2 

;..r.a::..ys:..s o: a::ions l:::)n by Wa':ers 430 IC - PR?-xlOO 2.S0x4.: c:;.:..'.liT'C. 

mA~ 

175-

150-

, 25 -= 

100 ~ 

75-

50-

25-

0 

0 

WJS1 A, Wavelength=280 nm (0497-24A\054-C502.D) 

"' "' "' 

2 4 € 8 

===================================================================== 

External Standard Report 

===================================================================== 

Soo:-ted By 

Calib. Daca Modified 

Multiplieo:-

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Res~lts obtained 

Wavelength=280 nm 

with enhanced integrator' 

RetTime Type Area Amt/Ao:-ea Amount Grp Name 

[min] rnAU *s [ng/ul] 

-------l------l----------l----------l----------1--l------------------

2.441 VB 871.13208 1.49818e-2 13.05115 HF 

Totals 13.05115 

===================================================================== 

*** End of Repc~t ~~* 

G:-ouc:;.o 5/9,/:::; 9:43:34 -~'V! 3GE C-16 ""= -
- --- = .--:__::- ~.-. ..:...·. 

Sarr.~~e Na:ne 

Ace;. Ope::-a::or 

Se~-.1e::ce F:.2.e 

Ace;: Me:::~oc 

~.:..a:.ys.:..s Me':.hod 

I..as<:: cha::ged 

~ '_.,.-.- ·'- ----- -·--

08-May-97, 20:42:2l Seq. ~~~e 

7048-09 ~1: V~aBGH ·-" 

F:\H?CSEM\2 1

\SEQUENCE\0497-24A.S 

ANIONS.M 

F:\HPCHEM\2\METHOCS\0497-24A.M 

5/9/97 9:37:29 AM by BGH 

?R~-x:·JG :.sex.;.:. ::::l'...lrn:". 

VVVD1 A. Wavelength=280 nm (0497-24A\055-0601.D} 

mAU ~ 

175-

150-

125-

100-

75-

50-

25-

0 

0 2 4 6 8 

ExteY~al Standa=d Repo~t 

;;===============;=================================================== 

Sorted By 

Calib. Data Modified 

Multiplier 

Dilutior.. 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *S [ng/ul] 

-------1------1 ----------l----------l----------l--l------------------

2.445 vo 952.83130 1.49966e-2 14.28927 HF 

Totals 14.28927 

*** End of Reporc *** 

G:-oucho 5/9 9:43:51 AM BGn C-17 :?age l c: ::.. 

,Y/ 
( 

\ 

Sa::cp:..e Nane 

Acq. Cpe::-at.cr 

Seque!:ce ?:..:..'= 

A::q. Me~hod 

A....."'lalys :..s Met.!lod 

Las~ cha::ged 

08-May-9~, 2C:55:04 Sec;:. 

7048-09 *::.: 

SGn 

?:\E?CHEM',2\SEQUENCE\0497-24A.S 

ANIONS.M 

F:\E?CHEM\2\METEODS\0497-24A.M 

5/9/97 9:37:29 AM by BGn 

Line 

Via::.. 

6 

2 

F .... "'la::..ys:.s cf anions Ion by Wa-cers 430 IC - PR:?-x:oo ::..sOx4 .l ::::J:;.u:n:: 

mAU 

175...:: 

150-

125-

100-

75-

50-

25-

0-

0 

W./01 A, Wave!ength-280 nm (0497-24A\055-0602.0) 

~ 

"-

<0 

.. .. 

N 

(• ,, 

' 

2 4 6 

I 

I 

8 

==========================~========================================== 

Exte~nal Standa~d Report 

===================================================================== 

Screed By 

Calib. Data Modified 

Multiplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 &~ 

l. 0 00 0 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type A~ea Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------1------1----------1----------1----------1--1------------------

2.446 va 917.41705 1.49905e-2 13.75258 EF 

Totals 13.75258 

===================================================================== 

*** End of Report *•* 

G!:'oucho 5/9/97 9:44:08 P-..1'1 BGH C-18 Page _ c: _ 

.. 

m: 
Sample Name 

Ace;. Operat.or 

OS-May-97, 2:.:c-.~, 

7048-10 *ll 

BGH 

Sequ.e:1::e File F: \EPC.HEM\2\S:SQt:-"ENCE\0497-24.~ .. S 

Ace;. Met.hod ~FIONS.M 

Ana:..ysis Met.hod F:\HPC2:EM\2\ME'::"HODS\0497-24A.M 

Last changed 5/9/9 7 9 : 3 7 : 2 9 AM by BGH 

Seq. L2.:1e 

Via:. 56 

_.. ~.: - --

.~"lalys:.s of ar_i.ons Ion by wa-:ers 43J ::::c - PEF-xl:JO 2..5·Jx4. 2.. ·:::J2.'..lrrw 

mAU 

175-

150-

125-

100-' 

75-

50-

25-

0 

VWD1 A. Wavelength-280 nm (0497-24A\056-070~ .:J) 

"' 

155_, 

2 6 

===================================================================== 

Exte=nal S~anda=d Repo~: 

===================================================================== 

Sor::ed By 

Calib. Dat.a Modified 

Mult.iplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not. reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------1----------l----------l----------l --1------------------

2.430 VB 767.52802 1.49585e-2 11.48107 HF 

Totals 11.48107 

===================================================================== **~ E~d of Report *** 

C·l9 

Groucho 5/9/97 9:44:25 AM BGH Page l c:: _ 

S3 

mrr 
===================================================================== 

:::::jecc:_:Jn :Ja~e 08-May-?'7, 21:28·:47 Seq. L:..:;.e 

Sam:t:=le Name 7048-10 •:.1 Vial 56 

.:..cc. O:Je~at.or 3GH I~j 2 

Seque!lce ?ile F: \ H:!?CHEM\ 2\ S2Ql'ENC2\ 04 9 ~- 2 4A. S 

Ace. Met~cd ~~:ONS.M 

J:._li2.ysis Met.~ ... od F: \HPCE3M\2\ME':'EODS\0491-24.:;..M 

Las:: cha?::ged 5/9/97 9:37:29 A.M by BGH 

_r..._'"la2.ysls o:: ar.;.ions Ion by Wacers 43C IC - ?i(.?-x:..oo 2.50x4 .l cclurn ... "": 

mAL: 

175-

150-

125-

100-

75-

50-

25-

0 

0 

VVV01 A. Wa~Je!ength-280 nm (04S7-24A\056-0702.D) 

2 

"' N 

" N 

4 6 8 

===================================================================== Ex::er~al Standard Report 

===================================================================== 

Sorted By 

Calib. Data Modified 

Multiplier 

DiL.ttion 

Uncalibrated Peaks 

Signa2. 

Friday, May 09, 1997 9:36:42 -~ 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator' 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------!----------!----------l----------l--l------------------

2.428 v~ 765.29181 1.49579e-2 11.44718 HF 

Totals 11.44718 

~** End of Report *•• 

9:44:42 ;.1~ BG:O C-20 ?age .-.~ , - .....,_ -

.. 

m1: 
::; :=-- J 5: :._.:: Sa..:n:;::..e ~Ja:r.:=: 

Ir~j ec':.ior-_ Sa:.e 

Samp=..e Name 

08-May-97, 2::33:4: 

7048-ll "A":.: 

Seq. L:..:1.e 

v:..a:.. Ac~. Ope~a:o= BGH Inj l 

Sec:::-.le::;.ce File F: \:,CPCH3M\2\SEQu""ENCE\0497-24A. S 

Ace. Me~~oc ~-~=ONS.M 

~-'a::.ys is Me::hod F: \H?C:n3M\ 2 \ME':'HODS\ 04? 7- 24A. M 

Las~ changed 5/9/97 9:37:29 AM by BGr. 

.~J.al.ysis o.: an:..ons :on by Wa-:.e::-s 43C :::c - P~:?-xlOO 3..50x4 .1 co~'..l:nr. 

\fl./l/01 A Wavelength-280 nm (049i -24A\057-0801.!J) 

mAU 

~iS150-

125- "-:I: 

100- "' 

"' 

.,. 

N 

75-

50-

25-

0 

0 2 4 6 8 

===================================================================== 

Ex-:.ernal Scanda::-d Report 

===================================================================== 

Sor::ed By 

Calib. Data Modified 

Mul':.iplie:::-

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.455 BB 1134.99304 1.50220e-2 17.04985 HF 

Totals 17.04985 

===================================================================== 

**"ll" End of Report *** 

Grouc~o 5/9/97 9:44:59 k~ BG:,C C-21 Page C; 1 c -
::1~2c':i:Jr: Da:.= 08-May-91, 2::46:30 Seq. 

Samp2..e Name 7048-l::... .,..::..l ~v·ia2.. 

• C BG·_,.;_ n.::c;. pe:-:~?=-

s - ·· "" "' \""DC'-~M\·' -~~'-"'NC-' 0'-~ 2'' • eqJe::..co::: .:'-~- ~: n- ::.~ .::.\;::.C:.'>c!i..,' ..... !!.\ --::;:::,- ~.'""l...,:, 

I'"'-i --" 

A:::: a. Me::hoC. JI.NIONS. M 

lL'"1i=._ys is Me::hod F: \B:?CHEM\ 2 \METHODS\ 0 4 9 '7- 2 4;.~. M 

Las': cha~9ed 5/9/97 9:37:29 ~~ bv BG2 .;....:-~a::..ys:..s ::.: ar:ions Ion by Wa:..e=s 430 IC - ?;.::-x::.oo ~5Cx4.2. 

mAU 

17:S15C125-

100-

75-

50-

VVVC1 A._ WaveJength-280 nm (0497-24A\057-0802.:J) 

8 

'" 

"' "' v 

N 

s 

25-

------~~~----------------_L------~-- 0 

c 2 4 5 8 

===================================================================== 

External Standa=d Report 

===================================================================== 

Sorted By 

Calib. Daca Moci=ied 

!VIu:. ciplie:::-

Dilutior. 

Ur.calibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not repo:::-:ed 

Signal l: VWD1 A, 

Resulcs obcained 

Wavelength=280 nm 

with enhanced inceg:::-acor' 

RecTime Type Area Arne/Area Amount Grp Name 

[min] mAU •s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.459 B3 1127.93579 1.50212e-2 16.94290 Hr 

Totals 16.94290 

====================================================================; ~~T End of Repor~ *~T 

C-22 G~~u.c~ ... o 5/9/97 9:45:17 F-..\1 BGH :=:age _;_ c: : 
:::::-1;ec=:..on Da::e 02-May-97, 2:.:::?:2l Seq. Line 9 

Sar.1p:.e Name 7048-:2 "'l: Via2. 52 

-~- Aca. Onerato= BGH I::j 1 

Seque:::ce • - F 'l F \'"""cu-"\21 --r;·•-N~-' 0"-a- 24' " :. e : n_ .r:..t:.1·: \~.::.;,.:C.!:..!.,_.:::.\ _.., 1- r~ .... 

Acq. Me~hod AN:ONS.M 

'· ' . M . d F \··or'-1-M' 2· M-~--oDS\0"-9- 24A M .'"u-:la~ys:..s etno : rL ~·-"- \ \ .. .::..:cl • !· .. 

• - ~ d "/9/97 9 3- •• 'M ~ -G·- .:...;aS ._ C_ .. ange ::: : I : L. '7 .-u . ...;y b n 

Ar.alysis of anions Ion by Wat:e:cs 430 IC - PRP-x100 150x4 .1 ·column 

mAU 

175-

150-

125-

100-

75-

50-

0 

VVV01 A. Wavelength-280 nm (0497-24A\C58-0901.~) 

"' "' '" 

2 4 

Exte:cnal Standard Report 

Sorted By Signal 

6 

Calib. Data Modified 

Multiplier 

F:ciday, May 09, 1997 9:36:42 AM 

1.0000 

Dilution 

Uncalibrated Peaks 

Signal 1: VWD1 A, 

Results obtained 

1.0000 

not reported 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount 

[min] mAU *s [ng/ul] 

Grp Name 

8 

-------1------1----------1----------1 1--1------------------

2.463 Vb 1154.25696 1.50242e-2 17.34179 HF 

Totals 17.34179 

===================================================================== 

"'"'* End of Repcrt 

C-23 G!'8t.;.C~'10 5/9/97 9:45:34 AM BGH Pa·;e l o: 

r . 
(" 

', 

:r..jec:.:..or: Da::e 03-May-97, ..::;.:..:~..::;:_.:.. 

Sam~~e Name 704S-l2 *ll 

Ace. Ooeca~~c BGE 

sec:rJ.enCe File F: \H?C:-12M\2\SEQGENCE\0497-2~.~. S 

Acq. Me~h~d ?~IONS.M 

F .... ·.1.alys:..s Method F: \H?CH:::M\2\ME:T30:JS\049/-24;.._.M 

~as~ cha~ged 5/9/97 9:37:29 -~by BGE 

Sec. 

-:l:_a:-_ 

I::j 

c 

ss 

?-~alys~s o: a~i~~s I~n by Wa~ecs 430 IC - ?~?-xlOO l50x4.l col urrc. 

mAU 

175-

150-

125 ~ 

100-

75-

so25-

0 

0 

VWD1 A, Wavelength-280 nm (0497-24A\058-0902.'J) 

"' "' " N 

• 

Ex~ernal Sta~dard Report 

€ 

===================================================================== 

S~rted By 

Calib. Da~a MoCified 

Multiplier 

Diluti~n 

U~calibrated Peaks 

Signal 

FriCay, May 09, l997 9:36:42 Pd"v'! 

1.0000 

1.0000 

n~t rep~rted 

Signal 1: VWD1 A, Wavelength;280 nm 

Results obtained with enhanced integrator' 

RetTime Type Area Am~/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.459 V3 1081.10022 1.50154e-2 16.23313 H= 

Totals 16.23313 

===================================================================== 

*** End of Report *~* 

Gcou:::ho 5/9/97 9:45:51 A."'l BGE ?age _ c; , 
.r---

' 

= --2 - -,--~--- _:;:; _,_-__ .. _ - -=---

===================================================================== 

Injec:io:: Da:9 

Samp::..e Na~e 

A:::q. Ope::::-a:::::::::-

Seq-J.e:lce ?:..:e 

Acq. Met~od 

08-May-9"7, 22:.25 

7G42-~3 ""l::. 

BGE 

cc 

: '-''' .. : 

F: \Z:PC::3M\ 2\ S:C~U=:)JCE\ 04 9-:-: 4:.~ _ S 

ANIGNS.M 

·A.."l.alysis Method F: \H?C:!EM\2\ME:':'E~2S\0497-24J:-__ M 

Last changed 5/9/97 9:37:29 P..M by BG:! 

Seq. Li::1e 

v:.al 

Ir ..j 

53 

1 

ll..nalysis of ar ..:..ons Ion by Wac.e::-s .:;30 IC - PRP-xlOO 150x4 .1 column 

mAU 

175-

150-

~ 

125- T 

" .,. 

~ 

100- N 

75-

50-

25-

0 

0 2 6 8 

===================================================================== 

Sor::ed By 

Calib. Data Mod~=ied 

Multiplier 

Dilution 

Un:::alibrated Peaks 

Ex~ernal Standa~d Report 

Signa: 

F::-iday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not repo:::-ted 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhan:::ed integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] rnAU * s [ng /ul] -- - - - - - I -- -- - - I -- -- - - - -- - I -- - --- - - -- I -- - - -- -- - -I -- I ---- ---- - -- -- --- - - 2.472 VB 1255.28821 1.50347e-2 18.87288 HF 

Totals 18.87288 

===================================================================== 

""*.,.. End o: Report ..... 

~:::-oucho 5/9/97 9:46:09 J:l..J.'1 BG!: Pag-e _ o: -

;-rw 
:::jec:.:..c·:-1 I:a':e 08-May-9'7, 22:37:48 Seq.~:.:;.:= .:..'.,· 

Sa:-r.p:..e Name 7C45-13 7:"11 Via:.. 59 

r- P._cc. Ooe::-a:or BGE Ir:j 2 

Seq,.le:'.ce File F: \ E?CHEM\ 2\ SEQUENCE\ 0 4 9 7- 2 4.'<. S 

Ac~. Me~~od .~V:ONS.M 

.~_-,alys is Mec:!lod F: \E?CHEM\ 2 \METHODS\ 04 9 7- 24A. M 

Las': c!-.a:'.ged 5/9 I 9 7 9: 3 7: 2 9 Jl.M by BGE 

A:la2.y·sis c: ar.ior:..s Ion by Wa:e~s 430 :c - PR?-x:.oo l50x4 .1 co_'Jrr-:: 

VW'::~ A Wave!engtn-280 nm (0497-24A\059-1002.0) 

mAU :1l 

"" 

150-

125-

100-

75-

50-

25-

0 :---~ 

___ ___,o'----------"2 _________ •=---------'6'---------"a _______ _.crr-,· 

===================================================================== Exce~nal Standard Repo~t 

===================================================================== 

Sorted By 

Calib. Da~a Modified 

Mul:i.p2..ier 

Dilucion 

Signal 

Friday, May 09, 1997 9:36:42 A.t'VJ 

1.0000 

1.0000 

Uncalibrated Peaks noc reported 

Signal 1: VWD1 A, Wavelength:280 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------1------1----------1----------1----------1--1------------------

2.477 v~ 1250.34436 1.50342e-2 18.79795 HF 

Totals 18.79795 

*** End of Reporc 

C-26 

Gr-:Jucl:o Page 1 cf 1 5 .' 9 .· 9 7 9 : 4 6 : 2 6 ;.Jv'! BGH 

90 
/ 

-..,.: - - -

Ir:jec::.i:J:: Date 08-May-97, 22:5:036 Seq. L:.ne 

Samf~e Name 7048-:~ *ll 

Ace. Ooe=ato~ BG2 

S eqJ.ence - • p·· 1...:..e F '--.,"--~"'· -~s~Qc--"c~\0'97 2"-A s : \n- -_r_.:...L·: \...::: \ .::. · !:...;." ..::. -:r. - _ • 

!r:j .... 

Ac~ Me~~od ~~:ONS.M 

.1\...-,a:.. ys ~ s Me :.hod F : \ :C:?CSEM\ 2 \ME:T:l:J'JS \ 0 4 9 7- 2 4." .. M 

- - 1-, • 5 I 9 '9 - 0 3 7 2 c 'M b B" '-' .!....las_ c .. a::1gea. 1 1 _, : : _, r-..!. y ~...:r ... 

A.."1a2.ys~s of ar.ions Ion by Wa::e=s 430 IC - PR?-xlOO 150x~.l colaiTL-: 

WV01 A. Wavelength=280 nm (0467-24A\06C-110~.D) 

mAU ~ 

150-

125-

100-

75-

50-

25-

/ 

0 

0 2 6 8 

==============================================:====================== 

Exte=nal Standard Repo~c 

========================================:============================ 

so~:.ed By 

Cal~b. Data Modified 

Multiplie!:" 

Di2.ution 

Uncalibrated Peaks 

Signal 

Fr:.day, May 09, 1997 9:36:42 A.t"l 

1.0000 

1.0000 

not: reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integ=ator! 

RecTime Type Area Amt/A=ea Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.387 HF 

Totals 0.00000 

1 War~i~gs or Errors 

Warr.:.ng Calibrated compound(s) not found 

Groucho 5/9/97 9:46:44 AM 3G2 C-27 
r·-

' ' 

=--~ - ,::.=_::...::....·; .- --'·-·-·-· -/.t"". ---. ... -:.-. 

========================================~=========================---

::::~:::::l::::: ::a::~ 08-May-97, 23:03:25 

Samp~e ~ame 7C4S-:4 ~:: 

rlca. Ooe~a~o~ BGH secru.e:1~e File F: \H?CHEM\2\SEQUENCE\049'7-24?.. S 

.:;.c~·. Me::~-::;d 1-..N::JNS. M 

~-"lalys.:. s Method F: \!-::?C?.EM\ 2 \ME:'rtCI::·S \0 4 9 7- 2 4A. M 

Last c!"' ... a::ged 5 /9/9 7 9 : 3 7 : 2 9 .Z:U'\1 by 3G~ 

Seq. Li.::e 

Vial 

T-,~ 

-·· . .: 

6C 

2 

?~a~ys~s of ar.ior.s Ion by Wa::~~s 430 IC - PRP-xlOO 15Cx4. l coluw.!"' .. 

\/V'v'lJ~ .;., Wavelength-280 nm (C497·24A\060·~ 102.0) 

mAL' lll 

,.,. 

17=.-

~50-

125-

100-

75-

50-

25-

0 

0 2 4 6 8 

Exte~r.al Standa=d Repo=t 

===================================================================== 

So:-::~d 3y Signa~ 

ca:~~. 0ata Modified Mul::ipl~er 

Dilu:ion 

Unca~ibratad Peaks 

E'ricay, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not repo:-ted 

Signal 1: VWD1 A, Wavelength=280 nm 

Results obtained with enhanced integrator! 

Ret':'ime 

[min] 

-------: 

2.387 

Tota:s 

~tpe Area Amt/Area Amount Grp Name 

mAU *s [ng/ul] 

------1----------1----------1----------1--l ------------------

HF 

0.00000 

Calibrated compound(s) not four.d 

G~cuc:hc 5/9. 97 9:47:05 .Al'V! ~Gr: C-28 Page _ o: .:.. 
Curve(s)/QA Point(s) 

Chromatograms 

,-~ 

:::~ 1 . C-29 

........: ~ ENTHALPY analyt1cal. 1nc. 
~a:.2. 

:njec:.:..on Date 08-May-97, l8:34:C5 

Samp::..e Name 5.162 ug/rr~ Hr 

Ace. One~ator BGE 

Se(iue:J.Ce File F: \EPCEiEM\2\SEQUENCZ\0437 -24A. S 

Acq. Me~hod ANIONS.M 

;:._,a'..ys:..s Method F: \H?CHEM\2\ME':'H:JuS\0437-24A.M 

T - • ""d -/a I 9- , · 0 7 • 7 AM b BG" ~as_ cna:1g- ~ ~- ' _.:.: :.:. . y -~ 

Seq. L~r:e 

v:..a: 

Ir:" 

l 

1 

fl~alysis c: anions Ion by Wat:e~s 430 IC - ?R?-x'..OO l50x-±.l cclurr.n 

mAU 

175-

150-

125-

100-

75-

50-

0-

0 

VVV01 A, Wavelength=280 nm (0497-24A\051-0101 .D) 

'""' "' '""' 

\ 

2 4 6 8 

===================================================================== 

External Standard Report 

===================================================================== 

So~t:ed By 

Calib. Data Modified 

Mult.iplier 

D:.lut.ion 

Uncalib~ated Peaks 

Signal 

F~iday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, Wavelength=280 nm 

Results obtained with enhanced integ~ator! 

RetTime Type Area Amt/A~ea Amount Grp Name 

[min] mAU *s [ng/ul] 

--- -- -- I - - ---- I -- -- -- - - -- I -- - --- ---- I -- - -- ----- I -- I ---------- ----- -- - 2.398 PBA 513.70020 1.48616e-2 7.63441 HF 

Totals 7.63441 

===================================================================== *~~ End of Report *** 

Groucho 5/9..-97 11:18:31 AM BGH C-30 ?age 1 cf ::. 

9Y 
:::~ec:.:.·::Jr-_ :0a:.e 08-Ma::··-~7, 18:46:53 Seq. L:..::e 

Sam:;:le Name 5.162 ug/mL :S:F Vial :o-2.. 

Acq. Ope=a:o= BGE Inj 2 

Seq"-.1e:1ce Fi.l.e F: \H?CEZM\ 2 \SEQu-;;:NCE\ 0497- 24A. S 

A~~. Me~~od ~~:ONS.M 

_n,_,a:..ys ;_ s Me':hod F: \H?CE:OM\ 2 \ME':':iCDS \04 9 7- 2 4A. M 

Last cl::a:1g-ed 5/9/97 :'..:!.:07:17 k"! by BGH 

.n..na:ysis of a:::..or:s lor .. by Wat.ers 430 ~C - PRP-xlOO 150x4 .1 cc:i..um.!1 

WJD1 A. Wavelength-280 nm {0497-24A\051-01C2..D) 

mAU 

175-

150-

125-

100-

75-

50-

25-

0-

~ 

0 2 6 a 

====================================================================: 

Sor-ceC. By 

Calib. Data Modified 

Mul-ciplieo:-

Diluti::Jn 

Uncalibrated Peaks 

Ex~ernal S~a~Card Report 

Signal 

Friday, May 09, 1997 9:36:42 k~ 

1.0000 

1.0000 

not repc:.-t:ed 

Signal 1: VWDl A, 

Results obtained 

Wavelength=280 nm 

with er~anced intego:-ator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] ------ -I ---- --I ------ --- -I ---- ------ I ----------I -- I --------- --------- 2.392 PEA 411.50070 1.47888e-2 6.08562 HF 

Totals 6.08562 

===================================================================== **~ End of Report 

G=oucl'w 5/9/97 1:!.::.9:18 AM BG!': 

*** 

Page _ cf 

o--' 

/J 
( -

=--2 -. - ,-r--.-- . ~ -c:..-. '. ~::- - -:; - - . -

===================================================================== 

Ir.j e:::..:.cr. Da:e 

Samp2.e Name 

_:;.cq. Ope:r-a::o.:-

Seque:-tce F:.le 

_.;.::~. Me::I:od 

. Jl~-:a.:..ys :i.s Me::hod 

:..as:. c!-'.~.anged 

09-Ma.y-97, 00:58:4'- Seq. 

5. :..62 ug l:n.L H? 

BGH 

F: \HPCHEM\ 2 \SEQL~NCE\ 049--;- 24.:. .. S 

AN:CONS.M 

F:\HPCHEM\2\ME~30DS\049--2~A.M 

5 I 9 I 9 7 :2. : 0 7 : 17 .l'J1 by BG2 

Li~e 

V::..a2. 

I :;.j 

.1'-.r,a.lys:..s o: a.:c.ions Ion by Wate::-s 430 IC - PR?-x:..oo l50x4.::. cc:.·J.rrc:: 

mAU 

VVVD~ A, Wavelength:280 nm (0497-24A\051-1601.D) 

,., 

1': 

175-

150 _.: 

125-

100-

75-

~ 

50- ~ 

.,. 

"' 25- "' "' 

-"-. 

0 

------'"-----------=------------'4"------------'5'----------'8'--------.....!!"~ 0 2 

===================================================================== 

Sorted By 

Calib. Data Modified 

Multiplier 

Dilution 

Uncalibrated Peaks 

Excernal S~anda=d Repo=t 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator~ 

RetTime Type Area AmtiArea Amount Grp Name 

[min] mAU * s [ng lull - --- -- - I --- --- I -- - -- --- - - I -- -- - - - --- I -- - --- ---- I -- I ---- --- - - -- -- -- --- 2.384 PBA 234.06892 1.45116e-2 3.39672 H? 

Totals 3.39672 

===================================================================== 

*** End of Repo~: ~~* 

Groucl;.o 5/9/97 1::11:05 .A.M 3G2 of :.. 
:..c..:.s.. ~ -~--~~~ 

_:;::;- . ..../.!""----~ 

:!'.~ec:ci.8:-. Da:.e 09-Mc.y-S7, 02-:1::28 

Samp2.e Name 5.162 ug/m:... E? 

Aca. 0De=~co= BG~ 

Sec::Je::cce Fi~ e F: \E?CHEM\ 2\ SEQl.i3NCE\ 0 4 9 7- 2 4A. S A::~. Me::~oc ~~cONS.M 

.2\...'l.a:':.ys:_s Me:.hod F: \HPC:1EM\2\M=:~:-:ODS\0497-24F .. M 

Las:: cha:1gec 5/9/97 l1:07:l7 AM by BGE 

Seq. L:..:1e 

v:.a: 

:::j 

• r .l..o 

5:. 

2 

A..-.a~ys:;.s o:: ar_ior.s :lor.. by Wa:.ers 430 IC - PR?-x~OO l5Cx4.l colu:-r.:1 

VWD1 A. Wave!ength=280 nm (0497 -24A\051-16C2. J,l 

mAU 

175-

150-

125-

100-

75-

50-

25-

0 2 4 6 6 

Ex:erna~ sca:1dard Repo=c 

~==~===~===============~============~====~=========================== 

Sor:ed By 

Calib Da:a Modified Mul~iplier 

Dilu::ion 

Uncalibra:ed Peaks 

Sigr.a.l 

Friday, May 09, 1997 9:36:42 ~.M 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced i~tegrator! 

RetTime Type Area Amt/A=ea Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------1--l------------------

2.387 PBA 241.46312 1.45313e-2 3.50877 HF 

Tota:!.s 3.50877 

=~=================================================================== 

*** End of Reporc 

G:r-oucho 5/9/91 1l.: 2.::.: 23 Al"'1 BGH C-33 ?age _ o: -

m:: 
,.·· 

I:--.j e..::.2.::n: ~a::e 

SaiT.F:..e Naiile 

Ace_. Ope::a::o:: 

Seque:1ce Fi:!..e 

Acq. Method 

.:. ... 1a:l.ys:. s Met:. hod ... ~~- ...... -..,~ .... ,-...=.;:l LIO..::. '- \,..J.J.C..-.~ _.._... 

08-May-97, 18:59:42 Sec;:. 

10.13 ug/mL EF 

BGE 

F:\HPCHEM\2\SEQUENCE\0497-24A.S 

JI.NIONS. M 

" \··oc··"M' 21 M-~·Jor-\04~- 24A M - : n_ :i .... . \ \ !!. .... ~ .... .:;:; • _, l - - .• 

5/9/97 l:..:C .... :::.""! AM by 3GE 

L:.:1e 

v:.a::.. 

2 

J...na2.ysis of anions Ion by Waters 430 :::::: - PR:?-x100 150x4 .1 colurrc:. 

VWD1 A, Wavetength=280 nm (0497-24A\052-D201.D) 

mAU 

17:::-

150-

125- !; 

,. 

N 

100- ,. 

N 

75-

50-

25-

·---------- 0- " i 

0 2 4 6 

Ex::ernal Scandard Reporc 

Sorted By Signal 

Cali=. Data Modified 

Multiplie:: 

Friday, May 09, 1997 9:36:42 JI.M 

1.0000 

D:...lu:ion 

Uncalibrated Peaks 

Signal l: VWD1 A, 

Results obtained 

1.0000 

not reporced 

Wavelength=280 nm 

with er~anced integrator! 

Re::T~me Type Area Arnt/Area Arnoun:: Grp Name 

[min] rnAU *s [ng/ul] 

8 

-------l------l----------l----------l----------l--l------------------

2.424 PBA 833.04645 1.49739e-2 12.47398 HF 

Totals 12.47398 

~~~==~=============================================================== 

*** End of Report *** 

Grouc::--.. o 5/9/97 1.:..:19:42 Jl.Jvl 3GH C-3-l Page _ c: :. 
/ 

- - - = ---= _::....:..'. - . _._-.. ____ '..;.. ;:':::: --------- '~ -- ... c:.-. 

Samp:.e Name 

_:;.cc. Ooera:.or 

secru.enCe ?:.le 

Ace. Mec!"10d 

. A .. ncl~ys :.s Me:.hod 

08-May-97, 19:12:34 

:.o. 13 ug/rr.L E? 

BGH 

F: \H?CHEM\2 \S2QlJENCE\ 049 7-2 4.Z\.. S 

ANIONS.M 

- \H:oc··-M·. 2\M-,..:.r~"-' 04°- -" M .t' : ·- !"' •.:. •• \ .!:.. - •• UJ.....;:::, \ • _, ! - L. '%i-l... 

Las-: cl-.a:1ged 5/9/9 7 1:.. : 0 "7 : l '7 k'V! by BG:E 

Sec;:. L:..ne 2 

'J i a: 

Inl 2 

-~-::.a2.ysis of anior.s Ion by Wa~e::-s 43C IC - PR?-x::.oo l50x4.l c:::lumr. 

VWDi A, Wavelengtn=280 nm (0497-24A\C52-C202.Q) 

mAU iii 

175-

150-

"' 

125-

"-

100-

:I: 

"' 

~ 

75- N 

50-

25-

0 ........----

0 2 4 6 8 

Externa~ Scanda=d Report 

===================================================================== 

So!:ted By 

Calib. Data Modified 

Mult.iplie::-

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 k~ 

1.0000 

l. 0000 

not repo!:ted 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------1------1----------1 ----------l-·--------l--l------------------

2.419 PBA 766.99170 l.49584e-2 11.47294 HF 

Totals 11.47294 

===================================================================== *~* End of Report **~ 

Groucho 5/9/97 11:20:06 JI.M BGE C-35 Page 1 o: :. 

rrw 
I:--.jec::2..or: :)a-=e 09-May··-97 I 0::24: :s 

Sample Name 10.13 us/mL EF 

Acq. Cpe~ato~ BGE 

Sequence Fi:!.e F: \Hl?C!':i::M\2\SEQUENC:0:\0497-24i' .. S 

Acq. Methoc ANIONS.M 

ALa:ysis Method F:\HPCHEM\2\M:O:~HODS\0497-24A.M 

Las:. cha:1ged 5/9/91 ll:07:l7 &"1 by 3G2 

Seq. I..::.:1e 

V:.a...:... 

Ir:J 

i'~calysis o: anions Ion by Wate~s 430 ~C - PRP-x:oo 150x4 .1 colum."":. 

mAU 

175-

150-

125-

100-

75-

50-

25 -

D 

0 

VWO~ A_ Waveiengtli-280 nm (0497-24A\052-i 701.0) 

"' l'l 

"-I 

:g 

.,. 

N 

2 4 6 8 

===================================================================== 

Ex=ernal Standa~d Repo=t 

===================================================================== 

Sor~ed By 

Ca:ib. Data Modified 

Mul:.ipli.er 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, Wavelength=280 nm 

Results obtained with enhanced integ~ator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.406 v~A 589.25447 1.48992e-2 8.77956 HF 

Totals 8.77956 

~*~ End of Report *** 

G::-oucjo 5/9/97 12.:11:41 P..L'\1 BG;.{ C-36 ?age - cf ~ 

/1/Z) 
:1:.:--.~ec:::.:Jn 0ace 09-May-97, 01:3/:C:. 

Sam;:~e Name :.c .13 uc/m:.. H~ 

Acq. Oper~~o~ BGE 

Seque::1ce File F: \HPCHEM\2 \SEQl.JENCE\ 04 97- 24_2:._. S 

Acq. Method ANIONS.M 

~alysis Me:chod F:\E:?CHEM,2\METHODS\049"7-24A.M 

Last: cha::ged 5/9/97 11:07::.7 -~by BGr. 

Seq. L:..::.e 

·~J.:.a::. 

Ir.J 

~-

52 

2 

Analysis cf a~io~s Ion by Waters 430 IC - PR:?-x100 lSOx4 .1 eel urn_.,..,. 

mAU 

175 ~ 

150-

125-

100-

75-

50-

25-

VWOi A, Wavelength-280 nm (049/.24A\052-i702.0) 

ill 

'"' 

0 

v 

N 

o-:-----

0 2 4 5 

'" 

0 

"' 

8 

===================================================================== 

External Standa=d Repo=~ 

===================================================================== 

Sort:ed By 

Calib. Dat:a Modified 

Mult:iplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, Wavelength=280 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU ~s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.401 VBA 585.75067 1.48977e-2 8.72631 HF 

Totals 8.72631 

===================================================================== *** E~d of Report *~~ 

G!""O'-.J.C~O 5/ 9; 11:11:59 AM BGE C-37 Page 1 c: :_ 

/Ol 
,-

Ir.j ec:.:.::r.:. Da::e 

Sample Name 

.::..cq. Ope::-a:.or 

Se~.J.ence F:!..2.e 

-~cq ·. Met:.hoC. 

.::: ... alys:.s Me:.hod 

Las:: c::.ar..ged 

..__, ___ ---- - --- . '..!::: __;; - ·,_. .;) ·~ - --

02-Mav-SI, 19:25:25 Seq. ~i::-.e 

l9. 50 .. ug 1m.I. HF v:.a.: 

BGE ~~j 

F: \H?CH~M\ 2 \S2Q\JENC~\ 04 9 7- 24A. S 

ANIONS.M 

- \~cor---M' 2·· M--"'00" 1 0' c~ 2'' M t' : n _ _ ::..::.. \ \ L • .::. • ;J. ...., ·, ""= _., i - -:r- .• . 

5/9/97 1:!.:07:17 AM jy BG2 

53 

1 

A..:.:..a::..ys:.s c: a!" .. :.:Jr:s .=on by wa:e:rs 43C :c - P?.?-x:oo 2.50x4.: c:::l~rr.r. 

mAU 

175-

150-

125-

iOC-

?S50-

25-

0 

0 

VVVDi .A.. Wavelength-280 nm (0497-24A\053-030~ .D) 

0>• 

0> 

n_; 

2 4 

Ex:.ernal Standard Report 

6 8 

===================================================================== 

Sor::ed By 

Calib. Data Mod~fied 

Mul::ipl:'..er 

!J i l ',.l':. ion 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integra:or! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.464 VBA 1325.48840 1.50410e-2 19.93673 HF 

Totals 19.93673 

===================================================================== 

*** End of Report **~ 

Groucho 5 '='' 97 11: C9: 23 AJ-1 3GZ.: C-38 ?age c: ' 

/0;).. 
· . .. 

=--'== - ::~r-~:;~.r ~ '--- ----·. '~ 

===================================================================== 

:r...je::-:.:..~n Da:.e 

Samp=..e Name 

Ac~. Ope~a..~c::­

Seque!lce Fi::.e 

Acq. Me~hod 

Analysis Method 

~as': changed 

OE-May-97, 13:38:::.6 Seq. 

l9. 50 ug/mL F.F 

BGE 

F: \HPCEEM\2\SEQlJENCE\0497-24A. S 

AN:ONS.M 

F: \EPCHEM\2 \ME':':"'!ODS\ 049 7- 24."'-. M 

5/9/97 11:07:17 A.M. by BG2 

L:.::e 

v:..a::.. 

I:::j 

3 

53 

2 

.~ .. a:ys:.s c: ar:ions Ion by Wate~s 43C IC - PF.P-x:.OC l5Cx4 .l c::; . .l·.J.rnr: 

\fiNO; A. Wavelength-280 nm (0497-24A\053-03C2.D) 

mAU ~ 

175-

150- "-r 

"' 

125- "' .,. 

N 

I 

100- I •' 

75-

50-

25-

0 

0 2 4 6 8 

.., 

"' .,. 

"' 

===================================================================== 

Excernal sc~~dard Report 

===================================================================== 

Sorced By 

Calib. Data Modified 

Multiplie:::.-

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWDl A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator' 

RetTime Type Area Amt/Area Amount Grp Name 

[min] m.ZI.U *s [ng/ul] 

-------l------l----------l----------l~---------1--l ------------------ 2.458 VBA 1321.37598 1.50407e-2 19.87441 HF 

Totals 19.87441 

===================================================================== 

*** End of Report **T 

G:::-cu::;,.o 5/9/97 11:C9:41 Al<l BGH C-39 Page 1 or · 

/0.3 
I" 

!n:ec~io~ Dace 09-May-97, 01:49:52 Seq. Line 

Sample Name :'.9.50 u;/mL H? -~Jia.::.. 

Ace. Opera~or BGH 

Sequence File F:\HPCHEM\2\S3QuENCE\0497-24A.S I!".~ 

Acq. Me~hod ANIONS.M 

A.""lalysis Method F:\HPCHEM\2\METH0DS\0497-24A.M 

Las: changed 5/9/97 11:07:17 A.~ by BGH 

.A.n.a.::..ysis of anions Ion by Wace!:"s 430 IC - PRP-x:oo 15 Ox4. 2. eel urnn 

mAU 

175-

150-

125-

100-

75-

50~ 

25-

\fiNO~ A Waveiength-260 nm (0497-24A\053-180~ _Q) 

"'' "' "' 

!!: 

.. .. "' 

N 

0 

·,!i 

I 

>---~~------~----------------~/~--------~------

0 2 4 6 8 

===================================================================== 

External Standard Report 

===================================================================== 

Sorted By 

ca:ib. Data Modified 

Multiplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AI-1 

1.0000 

1.0000 

not reported 

Signal 1: VWDl A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------1--l------------------

2.449 VBA 1261.49463 1.50353e-2 18.96693 HF 

Totals 18.96693 

===================================================================== *~* End of Report **~ 

Grouc:w 5/9/97 11:12:17 AN BGE C-40 Page l c: 

/cYl 
=--e: - ,.., ' -- ~ ' - ' ·- "": :: - ..:. -::: ..... _ ,--,-- --~-

~::...:--~ ..... .:. ·-' 

:::::r.~ec-.:2.:):: Da::e 09-May-97, 02:C2:39 Seq. 18 

Sam:;:le Na.:ne l9. 50 ug/mL H? v:..al 53 

Acq. Ope~a~or BGH 2 

Seq-..1ence File F:\HPCHEM\2\SEQU2NC3\0497-24A.S 

Acq. Me~hod ANIONS.M 

A.:l.alysis Me~hod F: \HPClEM\ 2 \METHODS\ 04 9 7-2 4.:. .. M Las~ cha::1ged 5/9/97 11:07: l7 AM by BGE 

Analysis o: anions Ion by Wa~e~s 430 IC - PR?-xlOO 150x4.1 co:u~' 

mAU 

, 75-

: 

150-

125-

100-

75 _: 

50-

25-

0 

0 

VVV'J~ A. Wavelength 280 nm {0497-24A\053-1802.0) 

'I 

c' 0 

.,. 

2 

"-:I: 

"' "' .,. 

N 

4 6 8 

c 

a . .,. 

"' 

===================================================================== 

Sor:.ed By 

Calib. Data Modified 

Multiplie!."" 

Dilution 

Uncalibrated Peaks 

Ex~ernal Standard Repo=~ 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not repon:ed 

Signal 1: VWD1 A, 

Results obtained 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ng/ul] 

-------1------1----------1----------1----------1--1------------------

2.453 v~A 1272.74597 1.50363e-2 19.13744 HF 

Totals 19.13744 

=:=================================================================== 

*** End o: Report *** 

3:coucho 5/9/97 11:12:35 AM BGH C-41 Page 1 o= 1 
( 

2::-:jec=:i.or: Da:.e 08-May-9'7, 19:5::06 

Sarrr;:=.e Name 34.34 ug/mL HF 

Ace. Ooe~~to~ BGH Seque~ce 2ile F:\H?CH3M\2\SEQUENCE\0497-24A.S 

Acq. Method ANIONS.M 

Analysis Met!:lod F:\H?CH3M\2\ME'CHODS\0497-24A.M 

Last changed 5/9/97 l1:07:17 AM by BGH 

,:,eq. 

v:..a~ 

- ~ . - -

63 

l 

?~alysis of anions Ion by Wate~s 430 ~C - PRP-xlOO l50x4.l col:unr. 

mAU 

175-

150--

125 ~ 

- 100-

75-

50-

25-

o0 

W..JD1 A. Wavelength-280 nm (0497-24A\06~401.0) 

"' 

~ 

' '; 

/ 

\ 

2 4 6 6 

===================================================================== Exte~nal Standa=d Repo=t 

===================================================================== 

Sorted By 

Calib. Data Modified 

Multiplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, wavelength=280 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/A~ea Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------1--l------------------

2.525 BBA 2360.42920 1.50908e-2 35.62084 HF 

Totals 35.62084 

===================================================================== 

*** End of Report *** 

-

Groucho 5/9/97 11:10:00 Al'J! BGH C-42 Page - cf :.. 

;ob 
=:__e --

:::~e:::.:..c.:--~ ::a::e 08-Mav-97, 20:C3:52 

Sam~:e Name 34.34-ug/mL HF 

Acq. Ope~a~o~ BGE 

Sequence F:.le F: \HPCHEM\ 2 \SE:Ql.J"ENCE\ 0497-2 4JI .. S 

Acq. Me~hod AN:ONS.M 

.1\.nalys:.s Met.hod F: \HPCHEM\2\M2'C'HODS\0497-24.:0,..M 

Last changed 5/9/97 .l.l:07:17 AM by BGE 

Sea. Line 

V-"--

"' -l 

l!lJ 

4 

55 

2 

A.:.-::.a2.ysis o: a::ions Ion by Wate:::-s 430 IC - PRP-xlOO l50x4 _ 1 colu!'n.i..J. 

mAU 

VVVD1 A. Vvavelength-280 nm (049i·24A\065-04C2.0) 

"' 

175-

150-

125-

100-

75-

5C25-

0-

'--.----

0 

Sor:ed By 

;;: 

"' N 

"' 

2 

Ext.ernal Standard Report 

Signal 

6 

Cal:.b. Data Modi:ied 

Multiplier 

Friday, May 09, .l997 9:36:42 Jl~ 

1.0000 

Dilut.ion 

Uncalibra=ed Peaks 

1.0000 

not repo:::-ted 

Signal 1: VWD1 A, Wavelength;280 nm 

Results obtained wit.h enhanced int.egrator! 

Ret.Time Type Area Amt/Area Amount Grp Name 

[min] mAU * s [ng /ul] 

8 

·a> 

·a> 

"' 

-------l------l----------l----------l----------1--l------------------

2.529 VBA 2318.62378 1.5089/e-2 34.98729 HF 

Tota::.s 34.98729 

===================================================================== 

*** End of Report *** 

Groc:::~-:o 5/9:97 11:::.0:17 -~~ 3GH C--13 Page 

/07 
/ 

?:....:.e ?: 

:::j9ct2.~~ Da-:e 09-May-9"7, 02:2.5:25 ~c. r..:..::.e :..9 

Sample Name 34.34 ug/mL HF v::.a:. 6S 

Ace. Ooe~ato~ BGE Inj 1 

Seciuence FEe F: \EPCHE:M\2 \SEQuENCE\ 049 7-2 4.Z1 .. S 

Acq. Method ANIONS.M 

A!".~.al vsi.s Met. hod F: \li?CHEM\2 \ME':'SODS \0497-2 4A. M 

Las::· changed 5/9/97 11:07:17 AM by BGH 

Ana'-ys:'..s of anions Ion by Wate:r-s 430 IC - PR?-x:.oo 150x4.1 ca:.'-'ITL": 

\1\NOi A. WaiJelength-280 nm (0497-24A\065-~ 901.0) 

mAU ~ 

175--= 

!j: 

' 

150 _: N 

N 

"' N 

125- ,\ 

II 

100 ~ 

75-

50-

25 _; 

0 

0 2 4 6 8 

Extecnal Standard Repor:: 

====================================================================~ 

Sorted By 

Calib. Data Modified 

Multiplier 

Dilution 

Uncalibrated Peaks 

Signal 

Friday, May 09, 1997 9:36:42 k~ 

1.0000 

1.0000 

not reported 

Signal 1: VWD1 A, Wavelength;280 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/A:r-ea Amount Grp Name 

[min] mAU *s [ng/ul] 

-------l------l----------l----------l----------l--l------------------

2.522 VBA 2200.03882 1.50862e-2 33.19019 HF 

Totals 33.19019 

==~=========================================================~======== 

*** End of Report *** 

Gco'-Ocho 5/9/97 '-'-: l2: 53 Al'-1 BGH C--1-l Page _ c:: :.. 

;oY 
-..."' ,--,....-

\.._..,4-- ---- -.,;,.-;:'':;! -.~---.-- _, _____ -. '-,.:.: -L-_ 

I~~ec~io~ ~a:e 09-May-97, 02:22:13 

Sample Name 34.34 ug/mL HF 

Acq. Oneracor BGE 

Sequ.ence F:'..le F: \H:?C5EM\2\SEQuENCE\0497-24A. S 

Acq. Method AN=ONS.M 

· A..'lalys:._s Method F: \HPCHEM\2\ME':'HODS\0497-24A.M 

Lase= changed 5/9/97 ll: 07:17 .1'.1'1 by BGE 

Se~. 

V:._a:. 

:Cnj 

1'0' 

65 

2 

-~.alys~s of a~ions Icn by Wate~s 430 IC - PR?-xlOO 150x4.l co2_uiTL-: 

mAU 

VWD~ A. Wavelength-280 nm (049i-24A\065-1902.:J) 

0 

;; 

, 15-

150-

125-

100-

75-

50-

25-

o-____ _ 

0 

Sorced Ey 

2 

"' N 

N "' 

' 

4 

External Standard Report 

Signal 

6 

Calib. Data Modified 

Multiplier 

Friday, May 09, 1997 9:36:42 AM 

1.0000 

Dilution 

Uncalibrated Peaks 

Signal 1: VWD1 A, 

Results obtained 

1.0000 

not reported 

Wavelength=280 nm 

with enhanced integrator! 

RetTime Type Area Amt/Area Amounc Grp Name 

[min] mAU Ts [ng/ul] 

--~--

e 

-------1------1----------1 ----------l----------l--l------------------

2.526 VBA 2209.78418 1.50865e-2 33.33787 HF 

Totals 33.33787 

;;;;:==~=======;==============================;================;===== 

*** End of Report T** 

Groucho 5/9/97 ll: :3: ll fu"'1 BGH C--15 Page _ ,__ 
APPE:"iDIX D 

PRODUCTION DATA 

D-1 
P.O. Box 1027 • Sanford, North Carolina 27331-1027 

TOLL FREE (NC, SC, VA) 1-800-672-7559 • 

April 25, 1997 

Trigon Engineering 

Attn: Mr. Robert F. Callahan 

6200 Harris Technology Blvd. 

Charlotte, N.C. 28269 

Re: Your Letter April 23, 1997 

Stack Testing. 

Dear Sir; 

FRANK G. PERRY, SR. 

Pres1dent 

J.R. HOLTON 

Secretary/Treasurer 

CJ 

• Telephone: (919) 774-4800 

Facsimile: 919-774-7557 

As you requested the production for kiln 2 on the day of stack test 

and all other times is as follows: 

Green Brick (unfired) 89,136 x 5 lbs. = 445,680 lb- 2,000 = 222.84 

tons. Fired bric% 89,136 x 4 lbs = 356,544 lbs - 2,000 = 187.27 

tons. If any other documentation is required please advise either 

myself or Bobby McCoy. 

y~ 

Holton 

S cr tary and Treasure 

JRH: jn 

r s 6it5~-o C>J A2 i !leo. -e If, -/J {) o 

D-2 Ill 
APPE~DIXE 

CALIBRATION DATA 

E-1 

. jlb .. 
QUALITY ASSURANCE AND EQUIPMENT CALIBRATION PROCEDURES 

General. Each item of field or laboratory test equipment purchased or fabricated by Trigon 

Engineering Consultants is assigned a unique, permanent identification number. New items 

for which calibration is required are calibrated before initial field use. Equipment whose 

calibration status may change with use or with time is inspected in the field before testing 

begins, and again upon return from each field use. When an item of equipment is found 

to be out of calibration, it is adjusted and recalibrated or retired from service. All 

equipment is periodically recalibrated in full, regardless of the outcome of these regular 

inspections. 

Calibrations are conducted in accordance with United States Environmental Protection 

Agency (US EPA) specifications. Trigon follows the calibration procedures outlined in EPA 

Reference Methods found in the Code of Federal Regulations (Volume 40, Part 60) and 

those recommended in the Quality Assurance Handbook for Air Pollution Measurement 

Systems: Volume III (EPN600/R-94/038c). When the Reference Methods do not detail 

procedures, Trigon uses methods such as those prescribed by the American Society for 

Testing and Materials (ASTM). 

Data obtained during calibrations are recorded on standardized forms, which are verified 

for completeness and accuracy by the Quality Assurance Manager. Data reduction and 

subsequent calculations are performed using Trigon's Air Quality Data System. Calibration 

calculations are performed by an environmental scientist, independently audited by the 

Project Manager, and reviewed by the Quality Assurance Manager for verification of data. 

Copies of calibration data are included in each test or project report. 

Inspection and Maintenance. An effective preventative maintenance program is necessary 

to ensure equipment performance quality prior to, during, and following every test. Each 

item of equipment returning from the field is inspected before it is returned to storage. 

During the course of these inspections, items are cleaned, repaired, reconditioned, and 

recalibrated when necessary. 

Each item of equipment transported to the field for a test project is inspected again prior 

to being packed. Trigon performs these quality assurance checks prior to departure for the 

project site to detect equipment problems which may occur during periods of storage. 

Trigon transports adequate back-up equipment to each project so as to avoid any 

unforeseen circumstances. 

Calibration. Source sampling equipment that require calibration include nozzles, pitot 

tubes, thermometers, flow meters, dry gas meters, and barometers. The following sections 

detail the calibration procedures followed by Trigon for each item. 

E-2 
Nozzles. Each probe nozzle is uniquely and permanently identified at the time of purchase 

or fabrication, and it is calibrated before initial field use and prior to each test. The inside 

diameter of the nozzle is measured to the nearest 0.001 inch using a digital micrometer. 

Three measurements are made using different diameters each time. If the difference 

between the high and the low measurements do not exceed 0.004 inch, the average of the 

three measurements is used. If the difference exceeds this amount, or when the nozzle 

becomes nicked, dented, or corroded, the nozzle is reshaped, sharpened, and recalibrated. 

Regardless of usage, all nozzles are inspected and recalibrated on a yearly basis. 

Pitot Tubes. All Type S pitot tubes are constructed and calibrated in strict accordance with 

the procedures contained in EPA Reference Method 2. A Type S pitot tube will have a 

coefficient of 0.84 ::!::0.02. A standard pi tot tube will have a coefficient of 0.99. Each pitot 

tube is visually inspected prior to any field use. If the inspection indicates damage, it is 

recalibrated. Regardless of usage, all pi tot tubes are inspected and recalibrated on a yearly 

basis. 

Drv Gas Meter and Orifice. Each metering system receives a full calibration at the time 

of purchase and annually, thereafter. Post-test calibrations are performed after each source 

test. If the calibration factor, y (gamma), deviates by less than five percent from the initial 

value, the· test data are acceptable. If y deviates by more than five percent, the meter is 

recalibrated and the meter coefficient (initial or recalibrated) that yields the lowest sample 

volume for the test runs is used. Standard practice at Trigon is to recalibrate the dry gas 

meter anytime y is found to be outside the range of 0.98 ~ y < 1.02. 

Barometer. Each field barometer is calibrated to agree within ± 0.1 inches Hg of a 

reference mercury barometer. The barometric pressure is corrected for pressure and 

temperature. Prior to and following each field test the field barometer is verified. 

Thermometers. Each new thermometer, pyrometer and thermocouple purchased or 

fabricated by Trigon is calibrated in strict accordance with US EPA Protocol. Calibration 

tolerance limits are as follow: 

Impinger Temperature Gauge 

Dry Gas Meter Temperature Gauge 

Stack Thermocouples 

::!:l°C or 2°F 

::!:3°C or 5.4°F 

::!:: 1.5% of absolute temperature 

All thermometers and thermocouples are inspected and calibrated prior to and following 

each field test. Regardless of usage, all thermometers and thermocouples are inspected and 

recalibrated on a yearly basis. 

Laboratorv Equipment. Trigon Engineering Consultants has a written quality assurance 

document that covers calibration and maintenance of laboratory equipment. This includes 

calibration of each analytical balance against Class S weights. Calibration of thermometers, 

barometers, and wet test meters are traceable to NIST. A copy of our quality assurance 

document may be obtained by written request. 

E-3 
PRETEST - POSTEST C.-\LIBR.-\TION OAT.-\ FOR.\! 

Client_~·~·-~~r_-~>-~~·------------ City ;State __ _;_( .;:-::-:-'. ~:o....::,.;,.;:; -~';;:.' ----;.___:_' 'v.:::..c1 _:C::__ ____ _ 

Pretest Date '-' 1

·' 

1

' ' Calibrator --"'0;..:(:...-~< __ Postest Date o~ ( 2-1/,; 7 Calibrator .-;;;-- -:;·I' 

Refe renee Thermometer ____ .._1 0"'0"'."'0"'2"'2'----- Reference Barometer ____ 6!£0"-!0cL·!L00~3L.. ___ _ 

Pretest Postest 

Temoernture. "F Ret: Temn. "F Temoernture. "F Ret: Temn. "F 

Omega Red Team DB!WB #100.025 I 

Omeoa Green Team DB/WB #100.031 

Omega Blue Team DB!WB #100.017 c.<;- It- 7 6"'; /tc; ! c;r, //<i ,; (, ~('; 

Omega Gold Team DB!WB #100.032 '"f·h 7 ;,:~!/~ 0! /:,;, /_,3/ ',: _3 

Omega Grev Team DB!WB #100.033 

Omeoa CEM DBM'B #100.026 

Drv Gas Meter Inlet/Outlet #300.035 0 3 /< 3 {: lt!:i. t.;. 1/_, I G3 

Drv Gas Meter Inlet/Outlet #300.045 I I 

Drv Gas \leter Inlet/Outlet #300.067 

Drv Gas Meter Inlet/Outlet #300.100 t;l/(,1 c; )../{). i l,) . I '/'I \.J , (,3 

Drv Gas Meter Inlet/Outlet #300.200 /.)/~l 1- J. /£}. I l,oZ./ul 1-3 I 

Drv Gas \leter Inlet/Outlet #300.2I4 ~I /£I t. 1 /.:. -2. I I,Z./·cZ- (, 1 I 

Drv Gas \leter Inlet/Outlet #300.241 

Drv Gas Meter Inlet/Outlet #300.248 t.~l/5 ~ l /~ l I v31G3 &3 

Drv Gas Meter Inlet/Outlet #300. I 

Drv Gas Meter Inlet/Outlet #300. 

Umbilical Adaotor # f #300. Ci..Jr.J ( l !'?. l,l- G3 

Umbilical Adanror # 7 #300. I ZJ I.-

' ) /) iJZ.. 03 

Umbilical Adaoror # "' #300. I 5 ~- (,). tJ. t, ~ ~]' 

Umbilical Adaotor # ~ #300. ~ c I (, J t. ' '· 3 {,< 

Umbilical Adaotor # 1 C #300. (4 ,:;;, G,7., (. '3 

Umbilical Adantor # !\ #300. ). I I. t;~ I 5 - (;I. 1..3 I 

Probe #200. Co7 "' 3 /_ <:' &I f., j 

Probe #200. ("<") ~ o. I < &1 (;) 

Probe #200. OO'i (.. 3 .: 3 1.:2-- &3 

Probe #200. 0 'l :;l &. i ~3 t 1 ::?- (.;'3 

Probe #200. ,., .\ '{ t ' ,;. 3 &7 VI 

Probe #200. 

Pi tot #200. "~ e < C: G l {,< c.;~ fo 3 

Pitot #200. f') ,. 1./ (,. 3 (. 3 (..."). (,3 

Field Baro in. HI> Ref. Baro ln. H• Field Baro in. Ho· Ref.Baro in. H2 

Barometer Red Team #600.00\ 

Barometer Green Team #600.0!4 

Barometer Blue Team #600.010 '~·"' ). ~ .. v· z.~. 50 Z..i.J5 

Barometer Gold Team #600.02 ](0\ l s. 3 ' 

.. , I .! '1' ::;,z ;;.~'. :: . ) . Barometer CEM #600.02010) 

Were all postest calibrations within the specified EPA Quality Assurance criteria? z'Yes D No 

E-4 

!15' 
PRETEST- POSTEST C.-\LIBRATIOC'i DATA FOR.\! 

/ . \ Cll.ent ' - ·-' .'-" .~ .ir - --~~-~~-~-~~---~-~-~-·~·~-~·---------------

Pretest Date '" '-"' /' ' ' Calibrator -~-- .J J! Postest Date C't/J1 /'ti Calibrator JJ I -J~·' 

Reference The rm om e te r _______ _.1-'"0-'"0'-'. 0"'2"'2'------- Reference Barometer ________ 6~0"-!0"-.'"00~3._ ____ _ 

Pretest Postest I 

Temoerature "F Ref. Temn_ "F Temperature. "F Ref. Temn. "F 

Omeoa Red Team DB/WB #100.025 I 

Omega Green Team DB/WB #100.031 I I 

Omeoa Blue Team DB!WB #100.0!i 

Ome.a Gold Team DB!WB #100.032 

Omega Grev Team DB!WB #100.033 I 

Ome•a CEM DB!WB #100.026 

Drv Gas \feter Inlet/Outlet #300.035 I 

Drv Gas Meter Inlet/Outlet #300.045 

Drv Gas Meter Inlet/Outlet #300.0/ii ! I 

Drv Gas Meter Inlet/Outlet #300.100 I I I 

Drv Gas Meter Inlet/Outlet #300.200 I I 

Drv Gas Meter lnlet/Outlet #300.214 I 

Drv Gas \!eter lnlet/Outlet #300.241 I 

Drv Gas Meter Inlet/Outlet #300.248 I I 

Drv Gas Meter Inlet/Outlet #300. I 

Drv Gas Meter Inlet/Outlet #300. I 

Umbilical Adaptor# 1). #300. -"111 ~., ~ ~- {,;i., h ~ 

Umbilical Adaptor # 1 3 #300. :)..{.. 4 ') (, 5 - 63 c; 5 

Umbilical Adaotor # #300. 

Umbilical Adaotor # #300. 

Umbilical Adaptor # #300. 

L:mbilical Adantor # #300. I I 

Probe #200. =') ~~ ~"" &1 (,) 

Probe #200. c ' r, n (. ~ l/1 L.· 3 

Probe #200. (') ' 7 (,4 ~ 3 !;L v3 

Probe #200. 

Probe #200. 

Probe #200. 

Pitot #200. 

Pitot #200. 

Field Baro in. H.,. Ref. Baro in. Ho Field Baro in.Ho Ref. Baro in• Ho 

Barometer Red Team #600.001 

Barometer Green Team #600.014 

Barometer Blue Team #600.010 

Barometer Gold Team #600.0211 D\ 

Barometer CEM #600.020(0) ( 

Were all postest calibrations within the specified EPA Quality Assurance criteria? 1<1 Yes a No 

E-5 
ISO KINETIC CON'TROL CONSOLE CALIBRATION FOR..\1 

Console Number: 300.100 Calibrator: BLS 

Calibration Date: 12/24i96 Dry Gas Meter .'iumber: 1557648 

Expiration Date: 12/24/97 Barometric Pressure, in. Hg: 29.070 

Console Gas Volume 1'rfeter Temperatures Time Console I 

Orifice Wet Test Dry Gas Wet Test Dry Gas Meter DGM DGM Orifice 

Setting Meter Meter Meter Avg. B Factor Yferer 

-il.H vw ~~ t,. Inlet Outlet td Minutes y :.IH@ 

in. H,O tt3 •F 

tdj tao 

•F in. H,O 

•F •F 

0.50 I 5 5.11 69.2 I 79.0 77.0 78.0 I 12.45 0.993 I 1.760 I 

1.00 5 5.11 69.3 83.5 78.0 I 80.8 8.96 0.997 1.814 I 

1.50 10 10.22 69.3 86.5 78.5 82.5 14.71 0.999 I 1.828 

2.00 10 10.22 69.2 86.5 79.0 82.8 I 12.97 0.998 1.893 I 

3.00 10 10.24 69.4 90.5 80.0 85.3 10.59 0.998 1.886 I 

4.00 10 10.23 69.3 93.0 81.0 87.0 9.21 1.000 1.895 I 

Average 1.00 1.85 

y t.H@ 

Tolerances: 1.00 1.84 

::!:0.02 =0.15 

Y and D.~ are calculated as follows: 

Vw * P, * (t0 + 460) 

y = ·------------------------------------------- = 1.00 

v" • (P, + t.H/13.6) • (t.. + 460) 

0.0317 * t.H (t,. + 460) * B 

t.H@ = --------------------- • ( ----------------------)

2 

= 1.85 

P, * (t0 + 460) Vw 

E-6 

//7 
.:::::. 

"\; 

ISOKINETIC CONSOLE CALIIHtATION DATA SHEET 

Client L:ee fsf'lcJ\ City/State ~N.-fcwd tJ.r. Project No. 046-97- ottr Emissio

r:n 

__, 

Date ()lf- fJ 5 !9 2 Darometric Pressure, Pb '2<1. 3 3 in. Hg Wet Test Meter Number 600.002 

lsokinetic Console ldentirication Number 100. Z?IJS-- Dry Gas Meter Identirication Number / 5 S 7 6 

Or lOco 

M<l<t 

(All) 

ln. 1110 

I:J :2:> 

))~ 

) ]~ 317>- 100 JYV ; 'C;. · ·.· i .' .. · ··. I nlllal Settings; V11hnne$ 1111d Tecnper11lures . . . .· ,. . Isoklnetlc Consoli! ··.• .... ,. Wet Test Meter .. ··· Dry Gal M~~·~ V~clluni, Y~h111it •nil Ten•peralur~ · .. •. ~· Vacuuaa Voluoie ...... ()IJIIel A•<rac• ln. llu (V .> rt' .· "F "ff (I.J "F 70 Cl. Ln 1'1._5_ 7'l 0 co 3. 7_S 7.o cFi7 Cf)_ 0 'lO .0 ?rG o --, ) i.C /0()\f- C() 5 '?Jo ?:7 75 

V., = Gas volume of wet test meter, ft1 

V • = Gas volume of dry gas meter, re 

lw = Tempera lure of wet test meier, oF 

Meier 

Volume 

(V.) 

rc• 

10.0 

10.0 

10.0 

t• = Average Temperature of dry gas meter, or 

All = Pressure differential across orifice, in. 1120 

. . M<le~ Tenip, 

(C.l . 

"ff· 

67 0 

(C] (J 

(?.o 

1'hue 

(6) 

1nln. 

1', 

0.3 II. O):J 

jl ? ~ ,J I ;lJ'I 

IJ 3 I.O]r; 

r = /.CQC 

Yi = Ratio of accuracy of wet test meter to dry gas meter for each replicate 

•.. . v

v, (I'• + 

.·· 

IO • 2'L 

< '2'i. n 

10. 2'\ '7 

. > 

( )'(. -z,-, 

IOxl•(

~ ' 

< 'J'l. 5 ·,, 

Y = Average ratio of accurncy of wet lesl meier lo dry gas meter for all replicates; tolerance 

Pb = Darometric Pressure, in. Jig 

0 = Time of calibration run, minutes 
ISOKINETIC CONTROL CONSOLE CALffiRATION FOR.'-1 

Console Number: 300.200 Calibrator: PRJ 

Calibration Date: 04/01/97 Dry Gas Meter Number: 1523437 

E-qJiration Date: 04/01/98 Barometric Pressure, in. Hg: 29.261 

Console Gas Volume Meter Temperatures Time Console 

Orifice Wet Test Dty Gas Wet Test Dry Gas Meter DGM DGM 

Setting Meter Meter Meter Avg. e Factor 

<l.H vw ~ t.. Inlet Outlet td Minutes y 

in. H,O rr' 'F tdi [do 'F 

'F 'F 

0.50 5 5.21 70.1 92.0 86.0 89.0 12.67 0.993 

1.00 5 5.21 70.2 95.0 86.0 90.5 9.15 0.994 

1.50 10 10.41 70.0 97.0 87.0 92.0 15.28 0.997 

2.00 10 10.42 70.0 99.0 87.0 93.0 13.29 0.996 

3.00 10 10.43 70.0 102.0 88.0 95.0 10.88 0.996 

4.00 10 10.43 69.7 103.5 88.5 96.0 9.51 0.996 

Average 1.00 

y 

Tolerances: 1.00 

±0.02 

Y and llH@ are calculated as follows: 

Vw * P. * (td + 460) 

y = -------------------------------------------- = 1.00 

vd • (P. + t.R'l3.6) • (t.. + 460) 

o.0317 • t.H (t.. + 460) • e 

t.H® = --------------------- • ( ----------------------)

2 

= 1.91 

P• * (td + 460) Vw 

E·8 

Orifice 

Meter 

<l.H@ 

in. H,O 

1.780 

1.853 

1.931 

1.944 

1.947 

1.978 

1.91 

ll}i@ 

1.84 

±0.15 

II 
10 

ISOKINETIC CONSOLE CALillRATION DATA SHEET 

Client Lj'e Rr:ck v-T: (e, City/State S4rd . ./'/(' Project No. 046- 97 _{'yi{) Emission 

Date 0 1/ I Z'l !9 7 Barometric Pressure, Pb 21 

1 

in. Hg Wet Test Meter Numl>er 

Isokinetic Console Identification Number 300. ZGO Dry Gas Meter Identification Numl>er 

Initial SeUtrigs, and 

.. •······ Test Meter 

Ory Gu V•(!!PIJI; •11cl Meter 

Meter Telt\peral111"1! . 

(.111) . ..• . .• . . (V.) (1.) 

ln. 11 0 Voi:uum Volume lnlel ·· Oullel Average ft' •r 1 In, llg (V.,) ft' "F "F. (1,.) "F 

_, ' 10.0 (ok 

(8) 

, .. , .. _ 

Y, 

600.002 

/5Z3L/3

v

v, u•. + 

lOx 

z. 31 1 o. z.._n 1 ?s s 1 11 o 1 n 3 J,J /2.05 I oYl\,> fO LO ( 

'<) 2 37 1 o. zq Ins 171 o 1 ?o. 3 r . .) 10.0 17.10 )0 X 

0. r-('{ S 10.Z1/ ( Z 'i\1 

--

10.0 )0 X 

Z. 37 I 3.5 liOlq I S\U 171/.5 I 8/.S l.t.....<"j lliZ- IL I 0.9'<3 ,a.z'l ( z 

Vw = Gas volume of wet test meter, fe Vd = Gas volume of dry gas meter, fe 

t,. = Temperature of wet test meter, op 

td = Average Temperature of dry gas meter, op 

aH = Pressure differential across orifice, in. H20 

y = 0. qq 5 

Yi = Ratio of accuracy of wet test meter to dry gas meter for each replicate 

Y = Average ratio of accuracy• of wet test meter to dry gas meter for all replicates; tolerance 

1\ = Barometric Pressure, in. 1-Ig 

0 = Time of calibration run, minutes 
ISOKJNETIC CONTROL CONSOLE CALIBRATION FOR.t'\-1 

Console Number: 300.214 Calibrator: DAC 

Calibration Date: 07/25/96 Dry Gas Meter Number: 2547128 

Expiration Date: 07!25/97 Barometric Pressure, in. Hg: 29.234 

Console 

Orifice 

Setting 

AH 

in.Hp 

0.50 

1.00 

1.50 

2.00 

3.00 

4.00 

Gas Volume Meter Temperatures Time Console 

Wet Test Dry Gas Wet Test Dry Gas Meter DGM DGM 

Meter Meter Meter Avg. I} Factor 

vw ~~ tN Inlet Outlet !d Minutes y 

-rtl •F 

tdi !do 

•F 

•F "F 

5 5.08 80.7 89.0 85.5 87.3 12.62 0.995 

5 5.09 80.9 94.5 87.0 90.8 9.15 0.998 

10 10.20 81.1 96.5 88.0 92.3 14.82 0.997 

10 10.23 81.2 99.0 89.5 94.3 12.98 0.996 

10 10.24 81.2 101.5 90.5 96.0 10.54 0.996 

10 10.24 81.3 104.0 91.0 97.5 9.17 0.996 

Average 1.00 

y 

Tolerances: 1.00 

::::0.02 

Y and D.H@ are calculated as follows: 

v w • pb .. (td + 460) 

y = -------------------------------------------- = 1.00 

vd • (Pb + D.H/13.6) • (~ + 460) 

0.0317 • D.H (~ + 460) • 9 

D.H@ = -----:-------------- • ( ----------------------/ = 1.90 

pb (td + 460) vw 

E-10 

Orifice 

Meter 

llH@ 

in. H,O 

1.845 

1.929 

1.894 

1.931 

1.904 

1.917 

1.90 

D.H@ 

1.84 

::::0.15 

ld-1 

~ 

ISOKINETIC CONSOLE CALIBRATION DATA SHEET 

Client Ler ISr~rk ~---n I"-- City/State SaV\-furrl /VC Project No. 046 - 9 7- \)lit Emission 

Date nlj I z.<; !9 7 Darometric Pressure, P b Z. <? • Z- ( in. llg Wet Test Meter Number 600.002 

lsokinetic Console Identification Number 300. L/ 1( Dry Gas Meter Identification Number 2 ",i((/

Orlnce 

Mcltr 

(4.11) 

ln. 11 10 

Initial Seltlngs, Volu1ne~ ll'll! Temperahn·es 

lsoklnellc Consoli) 

no- Gu M(l•r V•~•!ulll, Va!~tQit ~'"' 

T~mperiilur~ · · 

V•cuna• I Volua•• I lnleJ ·1 Ollllel I Averos• 

ln. IlK (V J fl' "F "F (IJ "F 

5. 3 I 0.17 I i)Lj S n.D 1 o<.>.3 

~.3 

tn.L7 ln.5 lz~.D 1:?3.'6 

(" ' ) ,_) to.3Z-I03.o lgo.s lcot...~ 

V w = Gas volume of wet test meter, ft 1 

Vd =Gas volume of dry gas meter, fe ~ = Temperature of wet test meter, °F 

Wet Test Meter 

Meter Mtler 

Volu1n~ T••IP• 

(V.) (t.) 

fl' "F 

10.0 

(,~.0 

10.0 

lo'l.q 

10.0 

iD~ 0 

td = Average Temperature of dry gas meter, or 

~II = Pressure differential across orifice, in. 1120 

1'illlt 

(8) 

....... 

1', 

((.27. II 0(0 I 

II. zZ I o_qq~. I 

11. 3s lo.tWII 

Y= i. 00( 

Yi = natio of accuracy of wet test meter to dry gas meter for each replicate 

v. 

V, u>, + 

10. l'l Z

iD.(I ( 29.? I + 

10 x z-'i .z

iD. 2 7 ( Z'l.ll + 

10 x zq a 

10. ~ 1- ( Z'l.Z I + 

Y = Average ratio of accuracy of wet test meter to dry gas meter for all replicates; tolerance 

Pb = Barometric Pressure, in. llg 

0 = Time of calibration n111, minutes 
ISOKlNETIC CONTROL CONSOLE CALIBRATION FOR.'>! 

Console Number: 300.248 Calibrator: RID 

Calibration Date: 08/15/96 Dry Gas Meter Number: 008761 

Expiration Date: 08/15/97 Barometric Pressure, in. Hg: 29.304 

Console Gas Volume Meter Temperatures Time Console 

Orifice Wet Test Dry Gas Wet Test Dry Gas Meter DGM 

Setting Meter Meter Meter Avg. (} 

M1 vw ~~ 1w Inlet Outlet td Minutes 

in. H,O ttl 'F tdi "0 'F 

'F 'F 

0.50 5 5.06 76.0 84.5 81.0 82.8 12.45 

1.00 5 5.09 76.0 89.8 83.8 86.8 9.32 

1.50 10 10.15 76.5 92.0 85.3 88.7 15.40 

2.00 10 10.18 77.0 96.0 87.5 91.8 13.25 

3.00 10 10.19 77.0 98.8 89.8 94.3 10.94 

4.00 10 10.15 77.0 97.0 89.0 93.0 9.45 

Average 

Tolerances: 

Y and ~H@ are calculated as follows: 

vw. pb. (td + 460) 

y = -------------------------------------------- = 1.00 

vd • (Pb + ~H/13.6) • (lw + 460) 

0.0317 • ~H (lw + 460) * IJ 

~H® = -----:--------------- • ( ----------------------/ = 1.96 

pb (td + 460) vw 

E-12 

DGM 

Factor 

y 

0.999 

1.000 

1.004 

1.004 

1.005 

1.004 

1.00 

y 

1.00 

Orifice 

Meter 

Mi@ 

in. H,O 

1.775 

1.975 

2.019 

1.985 

2.021 

2.015 

1.96 

±0.02 ±0.15 

/~3 
\jj " 

~ 

ISOKINETIC CONSOLE CALIBRATION OATA SHEET 

Client Ur fSrirlr .r-}; k City/State Su'fl£d !IG Project No. 046- 97- 0 1\ ~ Emissio

I 

z v 

Date ll'/ I 21( /9 1 naromehic Pressure, 1\ 2f/f3 in. Ilg Wet Test Meter Number 600.002 

lsokinetic Console Identification Number 300. 2_li '6 Dry Gas Meter Identification Number (Xl/j 7 

Orifice 

Meier 

(<111) 

ln. 11 10 

210 

?_2'1 

z. 7-<f 

lnlllal SelllilllSjVoluule$ lllld Telilperah•re!! 

. lsoklne!lc CQ!l~o!~ > . 

.· .. ·. ······· 

Wet Test Meier 

llry (;u Meier V~oulllll, V~tiuu~ •~d ·.·· 

Teniperalut~ ... 

Vacuna1 Votunoe Intel outlet Averoge 

ln. llg (V .J n• "F "(I (I.J "I' 

(Q.O tO.IL fi.O 17.0 ?3.0 

(,. 0 I() .t S I{ 0 ') 71')0 ¥11. ~ 1.,,0 (0.11 qz.O '?/.0 S'£. s 

V w = Gas volume of wet test meter, ft 1 

V d = Gas volume of dry gas meter, ft 1 ~ = Temperature of wei lest meter, •r 

Meter 

Vohuue 

(V,) 

ft' 

10.0 

10.0 

10.0 

td = Average Temperature of dry gas meter, •r 

6.11 = Pressure differential across orifice, ln. liP 

Meter 

Te••P• 

(I.) 

"F 

(p '{I) 

l91 (( 

{.,~.o 

11~·· 

(9) 

n•ln. 

1', 

I 2-. ~) j.OIO 

I z_,_<; o (. D ( \ 

rz. so (011-

Y = /.01\ 

Yi = Ratio of accuracy of wet test meter to dry gas meter for each replicate 

V

V, (1'. + 

IO x Z'l 

to.tl- < :a 'fl 

10. l y 

JO.f5 ( U.'t] 

10. z y 

/0.1'7 ( 21i3 

Y = Average ratio of accuracy of wet test meter to dry gas meter for all replicates; tolerance 

Pb = Barometric Pressure, in. Jig 

0 = Time of calibration run, minutes 
TYPE "S" PITOT TCBE CALIBRATION FOR:\1 

Date: 01/03/97 Calibrator: JJT 

Specifications: 

A.) Pilot tube assembly must be level. 

B.) If pitot tube is damaged explain under co=ents section. 

C.) Z = A Sin 1 ( <0.125) and W = A Sin 9 ( <0.03125) 

D.) a .::_10" and /3 .::_5' 

I .D. Lengtb a1° aZO /310 /320 ,. go A, in. Z. in. W, in. P . .\, in. PB, in. 

Individual Pitot Tubes 

200.057 l' 1.0 1.0 0.5 1.0 0.0 0.0 0.630 0.000 0.00000 0.315 0.315 

200.019 2' 1.0 1.0 0.0 0.0 1.0 1.0 0.936 0.016 0.01634 0.468 0.468 

200.058 30" 0.0 1.0 2.0 4.0 3.0 0.0 0.918 0.048 0.00000 0.459 0.-+59 

200.049 3' 3.0 0.0 1.0 1.0 1.0 1.5 0.949 0.017 O.D2~ 0.474 0.-+75 

200.028 3' 2.0 7.0 1.0 1.0 3.0 1.0 0.977 0.051 0.01705 0.488 0.489 

200.025** 5' 1.0 2.0 2.0 2.0 1.0 1.5 0.931 0.016 0.02437 0.466 0.465 

200.054 5' 2.0 1.0 0.5 0.5 1.0 1.5 0.784 0.01-+ 0.02052 0.392 0.392 

200.044 tr 2.0 1.0 1.0 1.0 3.0 1.0 0.984 0.051 0.01717 0.492 0.492 

200.038 7' 3.0 0.0 0.0 0.0 0.0 1.5 0.951 0.000 0.02489 0.476 0.475 

200.030 7' 6.0 7.0 1.0 1.0 2.0 1.0 0.978 0.034 0.01707 0.489 0.489 

200.055 7' 1.0 1.0 0.0 1.0 0.0 1.0 0.841 0.000 0.01468 0.421 0.420 

200.031 10' 4.0 8.0 1.0 0.0 1.0 1.5 0.943 0.016 0.02468 0.471 0.472 

300.164 And. 3.0 3.0 1.0 3.0 3.0 1.0 1.113 0.058 0.01942 0.556 0.557 

Co=ents: Pitol Tubes Required Only Minor Maintenance · Further Calibration Not Required 

•• Inconel 300.164 =Anderson Pitol Tube Extension 

E-14 

Dt. in. 

0.2-+7 

0.377 

0.377 

0.375 

0.375 

0.379 

0.377 

0.376 

0.376 

0.374 

0.375 

0.372 

0.374 
TYPE "S"' PITOT TL"BE CALIBR.HION FOR:\! 

Date: 01;03/97 Calibrator: JJT 

Spec1fications: 

A.) Pitot tube assembly must be level. 

B.) If pitot tube is damaged explain under comments section. 

C) Z = A Sin i' (.:;:0.125) and W = A Sin 9 (.:;:0.03125) 

D.) a _:s!O' and /3 .:;:5' 

I.D. Length go ~ in. Z. in. W, in. P.~ in. PB, in. Dt, in. 

P!tot Tubes Attached to Probes 

200.020 2' 2.0 2.0 0.0 

200.021 2' 0.0 0.0 0.0 

200.036 2' 

200.037 2' 

200.004 3' 

200.005 3' 

200.006 3' 

200.015 3' 

200.016 3' 

200.017 3' 

200.007 5' 

200.008 5' 

200.009 5' 

200.022 5' 

200.027 5' 

200.034 5' 

200.056 5' 

200.061 5' 

200.024. 6' 

200.010 7' 

200.011 7' 

200.012 7' 

200.039 7' 

200.040 7' 

200.059 7' 

200.060 7' 

200.041 8' 

200.045 8' 

200.013 10' 

200.014 10' 

200.050 12' 

200.051 12' 

200.052 12' 

200.053 12' 

0.0 1.0 0.0 

0.0 1.0 1.0 

0.0 1.0 0.0 

1.0 4.0 0.0 

2.0 2.0 2.0 

3.0 6.0 1.0 

1.0 2.0 1.0 

0.0 0.0 0.0 

2.0 2.0 1.0 

2.0 2.0 0.5 

0.0 2.0 2.0 

5.0 5.0 3.0 

0.0 1.0 2.0 

2.0 2.0 3.0 

0.0 1.0 0.0 

0.0 0.0 0.0 

4.0 5.0 2.0 

0.0 1.0 0.0 

0.0 0.0 0.0 

0.0 1.0 0.0 

2.0 2.0 1.0 

2.0 0.0 2.0 

0.0 1.0 1.0 

0.0 0.0 o.o 

0.0 

0.0 

2.0 

2.0 

0.0 

0.0 

3.0 

0.0 

0.0 

1.0 

2.0 

2.0 

0.0 

0.0 

2.0 

0.0 

0.0 

1.0 

2.0 

1.0 

0.0 

0.0 

1.0 

0.0 

1.0 

0.0 

2.0 

1.0 

1.0 

1.0 

2.0 

0.0 

2.0 

0.0 

2.0 

0.0 

1.0 

3.0 

3.0 

4.0 

1.0 

1.0 

3.0 

1.0 

0.0 

0.0 

0.0 

2.0 

1.0 

1.0 

1.0 

2.0 

3.0 

1.0 

0.0 

0.0 

1.0 

1.0 

0.0 

3.0 

0.0 

3.0 

1.0 

1.0 

3.0 

1.0 

2.0 

1.0 

2.0 

1.0 

2.0 

2.0 

1.0 

5.0 

0.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

2.0 

0.0 

1.0 

!.0 

2.0 

1.0 

1.0 

0.0 

0.0 

0.0 

1.0 

0.0 

1.5 

0.0 

1.0 

1.0 

1.0 

1.0 

0.5 

1.0 

1.0 

1.5 

1.5 

0.0 

1.0 

1.0 

1.5 

1.5 

0.0 

2.0 

1.0 

1.0 

1.0 

0.5 

1.0 

1.0 

0.0 

1.0 

1.0 

1.0 

1.0 

0.0 

2.0 

1.0 

0.0 

1.063 

1.054 

0.990 

0.969 

0.936 

0.948 

0.934 

0.943 

0.946 

0.939 

0.948 

0.950 

0.938 

0.949 

0.940 

0.934 

0.935 

0.597 

0.580 

0.938 

0.942 

0.943 

0.955 

0.944 

0.598 

0.604 

0.931 

0.937 

0.937 

0.955 

0.964 

0.917 

0.907 

0.961 

0.000 

0.055 

0.000 

0.051 

0.016 

0.017 

0.049 

0.016 

0.033 

0.016 

0.033 

0.017 

0.033 

0.033 

0.016 

0.081 

0.000 

0.010 

0.010 

0.016 

0.016 

0.016 

0.017 

0.033 

0.000 

0.011 

0.016 

0.033 

0.016 

0.017 

0.000 

0.000 

0.000 

0.017 

0.00000 

0.02759 

0.00000 

0.01691 

0.01634 

0.01654 

0.01630 

0.00823 

0.01651 

0.01639 

0.02482 

0.02487 

0.00000 

0.01656 

0.01641 

0.02445 

0.02448 

0.00000 

0.02024 

0.01637 

0.01644 

0.01646 

0.00833 

0.01648 

0.01044 

0.00000 

0.01625 

0.01635 

0.01635 

0.01667 

0.00000 

0.03200 

0.01583 

0.00000 

0.531 

0.527 

0.495 

0.485 

0.468 

0.474 

0.467 

0.471 

0.473 

0.469 

0.474 

0.475 

0.469 

0.474 

0.470 

0.467 

0.467 

0.299 

0.290 

0.469 

0.471 

0.471 

0.477 

0.472 

0.299 

0.302 

0.465 

0.468 

0.468 

0.478 

0.482 

0.458 

0.454 

0.480 

Comments: Pitot Tubes Required Only Minor Maintenance . Further Cllibration Not Required 

• Water Cooled 

E-15 

0.532 

0.527 

0.495 

0.484 

0.468 

0.474 

0.467 

0.472 

0.473 

0.470 

0.474 

0.475 

0.469 

0.475 

0.470 

0.467 

0.468 

0.298 

0.290 

0.469 

0.471 

0.472 

0.478 

0.472 

O.Z99 

0.302 

0.466 

0.469 

0.469 

0.477 

0.482 

0.459 

0.453 

0.481 

0.371 

0.373 

0.375 

0.372 

0.377 

0.378 

0.374 

0.378 

0.374 

0.374 

0.375 

0.378 

0.375 

0.376 

0.374 

0.373 

0.374 

0.252 

0.251 

0.375 

0.375 

0.375 

0.375 

0.373 

0.253 

0.251 

0.376 

0.375 

0.374 

0.375 

0.375 

0.376 

0.376 

0.376 
STAINLESS STEEL NOZZLE CALIBRATION DATA 

SET THREE 

Date Calibrated: 01/03/97 Calibrated By: ELB 

Nozzle Diameter (a) 

Nozzle Davg(c) Dl 02 03 Diff. 

Number (in.) (in.) (in.) (in.) (b) 

5/8" Nozzle 

300.118 0.684 0.685 0.684 0.683 0.002 

1/2" Nozzles 

300.115(1) 0.494 0.495 0.493 0.494 0.002 

300.116(2) 0.495 0.495 0.495 0.494 0.001 

300.117(3) 0.495 0.494 0.494 0.497 0.003 

7/lll' Nozzles 

300.131(1) 0.439 0.438 0.439 0.440 0.002 

300.132(2) 0.425 0.424 0.424 0.427 0.003 

300.133(3) 0.426 0.426 0.425 0.427 0.002 

3/8" Nozzles 

300.125(1) 0.372 0.371 0.373 0.371 0.002 

300.126(2) 0.370 0.372 0.369 0.369 0.003 

300.127(3) 0.371 0.370 0.371 0.372 0.002 

5/16" Nozzles 

300.109(1) 0.300 0.300 0.300 0.301 0.001 

300.110(2) 0.300 0.299 0.300 0.300 0.001 

300.111(3) 0.299 0.300 0.299 0.298 0.002 

1/4" Nozzles 

300.112(1) 0.249 0.248 0.250 0.250 0.002 

300.113(2) 0.246 0.246 0.246 0.246 0.000 

300.114(3) 0.250 0.250 0.250 0.249 0.001 

3/11l' Nozzles 

300.128(1) 0.174 0.176 0.173 0.17'~ 0.003 

300.129(2) 0.174 0.173 0.175 0.174 0.002 

300.130(3) 0.171 0.170 0.171 0.173 0.003 

where: 

(a) 01, 02 and 03 = three differ.,t noz::l• inskie diameters, measured to neatest 0.001 in. 

(b) 0 = maximum difference between arry two diameters, (in.) 0 < 0.004 in. 

(c) Oavg .:a av«age of 01, 02, and 03 

E·I6 

/:?7 
STAJNLESS STEEL NOZZLE CALIBRUION DATA 

SET FOUR 

Date Calibrated: 01/03/97 Calibrated By: ELB 

Nozzle Diameter (a) 

Nozzle Davg(c) D1 D2 D3 Diff. 

Number (in.) (in.) (in.) (in.) (b) 

3/4" Nozzle 

300.236(1) 0.758 0.759 0.758 0.758 0.001 

5!8" Nozzle 

300.235(1) 0.618 0.617 0.618 0.618 0.001 

1/2" Nozzles 

300.189(1) 0.488 0.488 0.489 0.487 0.002 

300.190(2) 0.493 0.492 0.494 0.494 0.002 

300.251(3) 0.494 0.492 0.494 0.495 0.003 

7/16" Nozzles 

300.234(1) 0.430 0.429 0.430 0.430 0.001 

300.233(2) 0.430 0.428 0.430 0.431 0.003 

3/8" Nozzles 

300.187(1) 0.375 0.374 0.375 0.376 0.002 

300.188(2) 0.372 0.373 0.373 0.371 0.002 

300.252(3) 0.367 0.368 0.368 0.365 0.003 

5!16" Nozzles 

300.193(1) 0.308 0.308 0.309 0.307 0.002 

300.194(2) 0.307 0.307 0.307 0.307 0.000 

300.195(3) 0.313 0.313 0.315 0.312 0.003 

114" Nozzles 

300.191(1) 0.239 0.239 0.239 0.238 0.001 

300.192(2) 0.235 0.235 0.235 0.236 0.001 

300.253(3) 0.234 0.234 0.234 0.235 0.001 

7 /32" Nozzle 

300.255(1) 0.222 0.221 0.221 0.223 0.002 

3/16" Nozzles 

300.232(1) 0.174 0.173 0.173 0.176 0.003 

300.231(2) 0.177 0.176 0.177 0.177 0.001 

300.254(3) 0.183 0.184 0.183 0.181 0.003 

5!32" Nozzle 

300.256(1) 0.149 0.149 0.149 0.148 0.001 

where: 

(a) 01, 02 and 03 "" thr" different noz:te inside diameters, measuntd to nearest 0.001 in. 

(b) 0 a maximum difference between any two dlameters. (in.) 0 < 0.004 in. 

(c) Oav~ "" av•aQe of 01, 02, and 03 

E-17 

I 
P'\7

REX NOZZLE CALIBRATION DATA 

5/8" S~'iK 

Date Caliorated: 01/03/97 Caliorated By: PRJ 

Nozzle Diameter (a) 

Nozzle Davg(c) Dl D2 D3 Diff. 

Number (in.) (in.) (in.) (in.) (b) 

1.25" ~ozzles 

300.283 1.225 1.224 1.226 1.226 0.002 

300.284 1.228 1.~28 1.227 1.229 0.002 

1" Nozzles 

300.218 0.999 0.999 0.998 0.999 0.001 

300.219 0.995 0.995 0.995 0.996 0.001 

5/8" Nozzles 

300.101 0.623 0.623 0.625 0.622 0.003 

300.102 0.623 0.623 0.622 0.623 0.001 

300.186 0.622 0.621 0.622 0.622 0.001 

112" Nozzles 

300.103 0.497 0.496 0.497 0.498 0.002 

300.104 0.502 0.502 0.502 0.503 0.001 

300.270 0.496 0.495 0.496 0.497 0.002 

7/16" Nozzles 

300.078 0.432 0.431 0.432 0.432 0.001 

300.095 0.442 0.443 0.441 0.441 0.002 

300.096 0.436 0.436 0.434 0.437 0.003 

3/8" Nozzles 

300.077 0.382 0.381 0.382 0.383 0.002 

300.093 0.378 0.378 0.379 0.376 0.003 

300.094 0.381 0.382 0.381 0.381 0.001 

5/16" Nozzles 

300.088 0.311 0.312 0.311 0.311 0.001 

300.089 0.309 0.308 0.310 0.310 0.002 

300.092 0.311 0.310 0.310 0.313 0.003 

1/4" Nozzles 

300.075 0.255 0.255 0.255 0.254 0.001 

300.121 0.253 0.252 0.253 0.253 0.001 

300.122 0.241 0.241 0.241 0.241 0.000 

3/16" Nozzles 

300.183 0.192 0.192 0.192 0.191 0.001 

300.184 0.191 0.191 0.190 0.191 0.001 

300.185 0.190 0.190 0.191 0.190 0.001 

1/8" Nozzles 

300.239 0.128 0.126 0.128 0.130 0.004 

300.240 0.133 0.134 0.132 0.133 0.002 

"""'"' 

(a) 01. 02 and D3 • ttl,... dltf...,t ncz:i• 1nS1da diamM~ mee.sured to nMtast 0.001 1n. 

(r;)) D • I"NJUmum diff...n<:a r;,_......, any twa diamlll:~. (in.) D < 0.004 1n. 

(c) Davg • averaga at 01, 02. and D3 

E-lS 

/2 '/ 
PYREX NOZZLE CALIBR.\TION DATA 

5/8" SHA..t~X 

Date Calibrated: 01/03/97 Calibrated By: PRJ 

Nozzle Diameter (a) 

Nozzle 

Number 

300.282 

300.272 

300.280 

300.271 

300.274 

300.275 

300.279 

300.273 

300.278 

300.091 

300.276 

300.281 

where: 

Davg(c) 

(in.) 

0.995 

0.622 

0.627 

0.496 

0.497 

0.500 

0.435 

0.375 

0.376 

0.242 

0.245 

0.125 

01 02 03 Diff. 

(in.) (in.) (in.) (b) 

1" Nozzles 

0.995 0.995 0.996 0.001 

5/8" Nozzles 

0.623 0.623 0.621 0.002 

0.627 0.627 0.627 0.000 

1/2" Nozzles 

0.496 0.496 0.497 0.001 

0.496 0.497 0.499 0.003 

0.499 0.501 0.500 0.002 

7/16" Nozzles 

0.434 0.435 0.435 0.001 

3/8" Nozzles 

0.373 0.376 0.376 0.003 

0.376 0.377 0.375 0.002 

5/16" Nozzles 

1/4" Nozzles 

0.242 0.242 0.242 0.000 

0.243 0.245 0.246 0.003 

3/16" Nozzles 

1/8" Nozzles 

0.124 0.124 0.126 0.002 

(a) 01, 02 and 03 ,. three different nozzle inside diameters. me.asured to nurest 0.001 in. 

(b) D '"' max1mum difference between any two diameters, (in.) 0 < 0.004 in. 

(c) Oavg == average of 01, 02, and 03 

E-19 

!30 
TEMPERATURE SENSOR CALIBRATION FORM 

NIST REFERENCE THERMOMETER TRANSFER CALIBRATION 

Tolerance: +/~ 1.5% of Absolute Temperature 

Date: 01!03/97 Barometric Pressure, In. Hg: 

Ambient Temperature. Deg. F: 76 Reference Thermometer No.: 

Cllibrated By: PRJ Reference Thermometer No.: 

NIST Reference Transfer 

Thermocouple 

lD No. 

Reference Thermometer 

Temperature 

Degrees F 

·30 to 120 Deg. F Thermometer Serial Number 97133 

Point Source 

Instrument 

Temperature 

Degrees F 

100.022 1 Water Bath 46 

2 WaterBath 74 

3 Water Bath 120 

·5 to 400 Deg. C Thermometer Serial Number U38717 

46 

74 

120 

100.024 1 Water Bath 74 23 Deg. C 

2 Water Bath 120 49 Deg. C 

3 Oil Bath 274 134 Deg. C 

·120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T·124997 Red Team 

100.025 1 Water Bath 4 7 4 7 

2 Water Bath 72 72 

3 Water Bath 181 181 

·120 to 2000 Deg. F Omega Hll25 KF Pyrometer Serial Number T-151625 Green Team 

100.031 1 Water Bath 46 46 

2 ~~&ili u ~ 

3 Water Bath 208 207 

·120 to 2000 Deg. F Omega Hll25 KF Pyrometer Serial Number T·98180 Blue Team 

100.017 1 Water Bath 46 46 

2 Water Bath 74 74 

3 Water Bath 186 187 

-120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T·l56311 Gold Team 

100.032 1 Water Bath 46 46 

2 

3 

Water Bath 

Water Bath 

74 

186 

74 

186 

·120 to 2000 Deg. F Omega HH2S KF Pyrometer Serial Number T·156877 Grey Team 

100.033 1 Water &th 4 7 4 7 

2 Water Bath 76 76 

3 Water Bath 193 193 

·120 to 2000 Deg. F Omega HII25 KF Pyrometer Serial Number T-148889 CEM 

100.026 1 Water Bath 46 46 

2 %~r&ili 74 U 

3 Water Bath 186 186 

Source =Type of calibration system used. 

Temper:1ture Difference Cllculation; 

(Ref. Temp. Deg. F + 460) ·(Test Temp. Deg. F + 460) 

X 100 = <1.5% 

Ref. Temp. Deg. F + 460 

E-20 

29..l55 

100.02.1 

100.028 

Temperature 

Difference 

Calculation 

Percent.% 

0.00 

0.00 

0.00 

0.11 

-0.03 

0.11 

0.00 

0.00 

0.00 

0.00 

.0.19 

0.15 

0.00 

0.00 

.0.15 

o.oo 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

;3! 
TE:\'1PERATURE SENSOR CALIBRATION FORM 

THER:VlOCOUPLES 

Tolerance: +/- 1.5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure. In. Hg: 

Ambient Temperature. Deg. F: 76 Reference Thermometer No.: 

C.11ibrated By: PRJ Reference Thermometer No.: 

Reference Ther-mocouple 

Thermocouple Reference Thermometer Potentiometer 

ID No. Point Source Temperature Temperature 

Degrees F Degrees F 

Omega HH-25 KF Dry Bulb· Red Team 

100.o25 1 Water Bath 72 72 

2 Water Bath 181 181 

3 Oil Bath 290 289 

Omega HH-25 KF Wet Bulb • Red Team 

100.o2S 1 Water Bath 72 72 

2 Water Bath 135 135 

3 Water Bath 173 173 

Omega HH-25 KF Dr-y Bulb· Green Team 

100.031 1 Water Bath 76 75 

2 Water Bath 175 175 

3 Oil Bath 295 296 

Omega HH-25 KF Wet Bulb· Green Team 

100.031 l Water Bath 76 75 

2 Water Bath 138 137 

3 Water Bath lii 177 

Omega HH-25 KF Dry Bulb· Blue Team 

100.017 l Water Bath 76 76 

2 Water Bath 175 !75 

3 Oil Bath 295 296 

Omega HH-25 KF Wet Bulb· Blue Team 

100.017 l Water Bath 76 76 

2 Water Bath 138 137 

3 Water Bath 177 177 

Omega HH-25 KF Dry Bulb· Gold Team 

100.032 l Water Bath 76 76 

2 Water Bath 175 175 

3 Oil Bath 295 295 

Omega HH-25 KF Wet Bulb· Gold Team 

100.032 1 Water Bath 76 76 

2 Water Bath 138 138 

3 Water Bath !77 177 

Source = Type of calibration system used. 

Temperature Difference C.llculation: 

(Rei. Temp. Deg. F + 460) ·(Test Temp. Oeg. F + 460) 

···········-·····---------·····--·-··-·-········ X 100 = < 1.5% 

Ref. Temp. Deg. F + ~60 

E-21 

29.455 

!00.024 

!00.028 

Temperature 

Difference 

CaJculation 

Pereent,% 

0.00 

0.00 

0.13 

0.00 

0.00 

0.00 

0.19 

0.00 

-0.13 

0.19 

0.17 

0.00 

0.00 

0.00 

-0.13 

0.00 

0.17 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

!32 
TEMPER.\.TURE SENSOR CALIBRATION FOR-"1 

THERMOCOUPLES 

Toler:mce: ?/- 1.5% of Absolute TemperJ.ture 

Date; 01/03/97 Barometric Pressure. In. Hg: 

Ambient Tempenture, Deg. F: 76 Reference Thermometer No.: 

Calibrated By: PRJ Reference Thermometer No.: 

Reference Thermocouple 

Thermocouple ReCerence Thermometer Potentiometer 

IDNo. Point Source Temp ern t ure Temperature 

Degrees F Degrees F 

r Pitot Tube 

200.019 1 Water Bath 73 73 

2 Water Bath 190 190 

3 Oil Bath 393 391 

30~ Pitot Tube 

200.058 1 Water Bath 55 55 

2 Water Bath 187 186 

3 Oil Bath 376 375 

3' Pitot Tube 

200.049 1 Water Bath 73 73 

2 Water Bath 190 190 

3 Oil Bath 392 390 

3' Pitot Tube 

200.028 1 Water Bath 74 74 

2 Water Bath 188 188 

3 Oil Bath 391 392 

S' Pitot Tube- lnC"oneJ 

200.025 1 Water Bath 73 73 

2 Water Bath 188 188 

3 Oil Bath 389 387 

4 Muffle Furnace 520 5" .. 5 Muffle Furnace 857 855 

6 Muffle Furnace 1ll5 1ll6 

5' Pitot Tube 

200.054 1 Water Bath 75 75 

2 Water Bath 188 188 

3 Oil Bath 388 387 

6' Pi tot Tube 

200.044 1 Water Bath 73 73 

2 Water Bath 186 185 

3 Oil Bath 386 385 

7' Pitot Tube 

200.038 1 Water Bath 73 73 

2 Water Bath 186 186 

3 Oil Bath 383 382 

7' PI tot Tube 

200.030 1 Water Bath 73 73 

2 Water Bath 184 184 

3 Oil Bath 391 391 

7' Pltot Tube 

200.055 1 Water Bath 73 73 

2 Water Bath 184 183 

3 Oil Bath 386 385 

10' Pitot Tube 

200.031 1 Water Bath 73 73 

2 Water Bath 183 183 

3 Oil Bath 388 388 

Source ,. Type of c:liibratiou system used. 

Temperature Difference CaiC"uiation: 

_(Ref. Temp. Deg. F + 460) ·(fest Temp. De g. F + ~60) 

X 100 =- <1.5% 

Ref. Temp. De g. F + 460 

29A55 

100.023 

100.02~ 

Tempen1ure 

Difference 

C.J.icul.:llion 

Percen4% 

0.00 

0.00 

0.:3 

0.00 

0.15 

0.12 

0.00 

0.00 

0.23 

0.00 

0.00 

-{).12 

0.00 

0.00 

0.24 

-o.:o 

0.15 

·0.06 

0.00 

0.00 

0.1: 

0.00 

0.15 

0.12 

0.00 

0.00 

0.11 

0.00 

0.00 

0.00 

0.00 

0.16 

0.11 

0.00 

0.00 

0.00 

133 
TE:VIPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Toler:1nce: +/- 1.5% of Absolute Ternper:lture 

Date: 01!03/97 Barometric Pressure, In. Hg: 29.455 

Ambient Temperature. Deg. F: 76 Reference Thermometer No.: 100.024 

C>librated By: ELB Reference Thermometer No.: 100.023 

Reference Thermocouple Temper::tture 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature Calculation 

Degrees F Degrees F Percent,% 

3' Probe (l) 

200.004 Water Bath 70 71 -0.19 

2 Water Bath 191 192 ·0.15 

3 Oil Bath 384 385 -0.12 

3' Probe (2) 

200.005 1 Water Bath 77 78 ·0.19 

2 Water Bach 133 183 0.00 

3 Oil Bath 385 387 ·0.24 

3' Probe (3) 

200.006 1 Water Bath 74 75 -0.19 

2 Water Bath 175 176 ·0.16 

3 Oil Bath 385 387 -0.24 

3' Probe (4) 

200.015 1 Water Bath 69 69 0.00 

2 Water Bath 173 175 -0.32 

3 Oil Bath 387 387 0.00 

3' Probe (5) 

200.016 1 Water Bath 65 65 0.00 

2 Water Bath 165 165 0.00 

3 Oil Bath 385 385 0.00 

3' Probe (6) 

200.017 1 Water Bath 71 71 0.00 

2 Water Bath 167 167 0.00 

3 Oil Bath 384 384 0.00 

Source = Type of c.1libration system used. 

Temper:uure Difference Cllculation: 

(Ref. Temp. Deg. F + 460) . (Test Temp. Deg. F + 460) 

X 100 = <1.5% 

Ref. Temp. Deg. F + 460 

E-23 

/3t/ 
TE.lVIPERATURE SENSOR CALIBRATION FOR:Yl 

THER:YIOCOUPLES 

TolerJ.nce: +/· 1.5% of Absolute Tempenture 

Date: 01/03/97 Barometric Pressure. In. Hg: 29.455 

Ambient Temper:J.ture. Deg. F: 76 Reference Thermometer No.; 100.024 

Calibrated By: PRJ Reference Thermometer No.: 100.023 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature Calculation 

Degrees F Degrees F Percent,% 

5' Probe (1) 

200.007 1 Water Bath 78 78 0.00 

2 Water Bath 203 204 ·0.15 

3 Oil Bath 385 384 0.12 

5' Probe (2) 

200.008 1 Water Bath 76 76 0.00 

2 Water Bath 195 196 ·0.15 

3 Oil Bath 388 388 0.00 

5' Probe (3) 

200.009 1 Water Bath 80 80 0.00 

2 Water Bath 171 173 -0.32 

3 Oil Bath 386 384 0.24 

5' Probe (4) 

200.022 1 Water Bath 81 82 -0.18 

2 Water Bath 193 191 0.31 

3 Oil Bath 384 383 0.12 

5' Probe (5) 

200.027 1 Water Bath 79 78 0.19 

2 Water Bath 191 192 -0.15 

3 Oil Bath 385 384 0.12 

5' Probe (6) 

200.034 1 Water Bath 75 75 o.oo 

2 Water Bath 186 188 -0.31 

3 Oil Bath 387 385 0.24 

5' Probe (7) 

200.056 1 Water Bath 67 66 0.19 

2 Water Bath 177 177 0.00 

3 Oil Bath 383 382 0.12 

Source = Type of Qlibration system used. 

Temperature Difference Calculation: 

(Rei. Temp. Deg. F + 460)- (Test Temp. Deg. F + 460) 

----------------------· X 100 = <1.5% 

Rei. Temp. Deg. F + 460 

E-24 
TEl\'lPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Tolerance: +/· 1.5% of Absolute Temperature 

DJ.te: 01/03/97 BJ.rometric Pressure. In. Hg: 29.455 

Ambient Temperature. Deg. F: 76 Reference Thermometer No.: 100.G23 

Calibr3ted By: JJT Reference Thermometer No.: 100.G23 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temper<:~ture C:llculutlon 

Degrees F Degrees F Percent.% 

300.035 

DGM Inlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 182 182 0.00 

300.035 

DGM Outlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 184 183 0.16 

300.045 

DGM Inlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 182 182 0.00 

300.045 

DGM Outlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 186 186 0.00 

300.067 

DGM Inlet 1 Water Bath 33 34 .0.20 

2 Water Bath 72 72 0.00 

3 Water Bath 149 148 0.16 

300.067 

DGM Outlet 1 Water Bath 33 33 0.00 

2 Water Bath 72 72 0.00 

3 WJ.ter Bath 150 150 0.00 

300.100 

DGM Inlet 1 Water Bath 33 35 ·0.41 

2 Water Bath 71 71 0.00 

3 W:lter Bath 198 197 0.15 

300.100 

DGM Outlet 1 Water B:lth 33 34 ·0.20 

2 Water Bath 71 71 0.00 

3 Water Both 196 194 0.30 

Source = Type of ~iibr:Hion system used. 

TernperJ.ture Difference C.liculation: 

(Ref. Temp. Deg. F + 460) ·(Test Temp. De g. F + 460) 

X 100 = <1.5% 

Ref. Temp. Deg. F + 460 

E-25 
TEMPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Toler:mce: +i- 1.5% of Absolute Temperature 

Date: 01103/97 Barometric Pressure. In. Hg: 19A55 

Ambient Temperature. Deg. F: 76 Reference Thermometer No.: 100.023 

Calibrated By: JJT Reference Thermometer No.; 100.028 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID :-<o. Point Source Temperature Temperature Calculation 

Degrees F Degr~s F Percent,% 

300.ZOO 

DGM Inlet 1 Water Bath 33 34 ·0.20 

2 Water Bath 73 73 0.00 

3 Water Bath 182 182 0.00 

300.ZOO 

DGM Outlet 1 Water Bath 33 34 -0.20 

2 Water Bath 73 73 0.00 

3 Water Bath 184 184 0.00 

300.214 

DGM Inlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 182 183 ·0.16 

300 . .::14 

DGM Outlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 186 186 0.00 

300.241 

DGM Inlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 184 184 0.00 

300.241 

DGM Outlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 182 182 0.00 

300.248 

DGM Inlet 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath !82 182 0.00 

300.248 

DGM Outlet l Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 185 !85 0.00 

Source =Type of ~libr:~.tion system used. 

Temperature Difference Calculation: 

(Ref. Temp. Deg. F + -160) ·(Test Temp. Deg. F + 460) 

X 100 = < !.5% 

Ref. Temp. Deg. F + 460 

E-26 

/37 
TE;\-lPERATURE SENSOR CALIBRATION FORM 

THER~IOCOUPLES 

Tolerance: +I- 1.5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure. In. Hg: 29.455 

Ambient Temperature. De g. F: 76 Reference Thermometer No.: 100.023 

Glibroted By: PRJ Reference Thermometer No.: 100.028 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature Calculation 

Degr~s F Degrees F Percent,% 

Umblllcal Adaptor #1 

300.030 1 Water Bath 32 33 -0.20 

2 Water Bath 74 74 0.00 

3 Water Bath 124 124 0.00 

Umbilical Adaptor #2 

300.031 1 Water Bath 32 33 -0.20 

2 Water Bath 74 74 0.00 

3 Water Bath 124 124 0.00 

Umblllcal Adaptor #3 

300.032 1 Water Bath 33 34 -0.20 

2 Water Bath 74 74 0.00 

3 Water Bath 127 127 0.00 

Umbilical Adaptor #4 

300.042 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 127 127 0.00 

Umbilical Adaptor #5 

300.043 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 127 127 0.00 

Umbilical Adaptor #6 

300.044 1 Water Bath 33 34 -0.20 

2 Water Bath 74 74 0.00 

3 Water '"; 1th 127 127 0.00 

Umbilical Adaptor #7 

300.134 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 126 126 0.00 

Umblllcal Adaptor #8 

300.135 1 Water Bath 33 34 -0.20 

2 Water Bath 74 74 0.00 

3 Water Bath 126 126 0.00 

Source = Type of ~libration system used. 

Temper:lture Difference Clicub.tion: 

·. (Ref. Temp. Deg. F + 460) ·(Test Temp. Deg. F + 460) 

X 100 = <1.5% 

Ref. Temp. Deg. F + -!60 

[-27 
TE:\'1PERATURE SENSOR CALIBRATION FORM 

THER:\'lOCOUPLES 

Tolero.nce: +:'· 1.5% of Absolute Ternpero.ture 

Date: 01/03/97 Barometric Pressure. In. Hg: l9.-155 

Ambient Temperature. Deg. F: 76 Reference Thermometer No.: !OO.Q23 

C.:llibrated By: PRJ Reference Thermometer ~a.: 100.D28 

Reference Thermocouple Tcmpcr:lture 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature C;JJcuJatlon 

Degrees F Degrees F Percent~% 

Umblllcal Adaptor #9 

300.207 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 126 126 0.00 

Umbilical Adaptor # 10 

300.208 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 126 126 0.00 

Umbilical Adaptor #11 

300.216 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 125 125 0.00 

Umbilical Adaptor #12 

300.217 1 Water Bath 33 33 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 125 125 0.00 

Umblllcal Adaptor #13 

300.264 1 Water Bath 33 34 -0.20 

, Water Bath 74 74 0.00 

• 

3 Water 83th 125 124 0.17 

Umbilical Adaptor M26 

300.079 1 Water Bath 32 31 0.20 

2 Water Bath 74 74 0.00 

3 Water Bath 125 124 0.17 

Umbilical Adaptor M26 

300.166 1 Water Bath 32 32 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 125 123 0.34 

Source =Type of calibration system used. 

Temperature Difference Calculation: 

. (Ref. Temp. Deg. F + 460) ·(Test Temp. Deg. F + 460) 

-------------------------------------------------------- X 100 = <1.5% 

Ref. Temp. Deg. F + ~60 
E'l"2:?, RE_;o_:;·f T!-iE?.MCME':'E?. C:J. , I::-JC. 

2 2 3 LAC:<AW.f:..NNA A VS"'w=: WES~ ?AT~ERSON 1 ~J 07424 

(20:.) 812-7474 

R E ? 0 R T 0 F C A L I 3 R A T I 0 N 

L:QUID-IN-GLASS-L~E~~CMETER 

C..1\..LI3R.Z\.':'SD BY SVER READY THE?.MCMETER CO. FOR: 

TRIGON ENGINEERING 

MARKED: ERTCO CAT 1002-3FC S/N-2890 R.~~GE: +30 TO +:24 DEGREES F IN 0.2 DEGREE GR.;DGATIONS. 

THER."!OME'!ER 

READING 

32.00 F 

40.00 

60.00 

100.00 

120.00 

CORRECTION 

(ITS-90) ** 

0.00 F 

-0.06 

-0.06 

0.00 

-0.06 

** ALL TEMPERATURES IN THIS REPORT ~~ BASED ON THE INTERNATIONAL 

TZMPERATJ?E SCALE OF 1990 (ITS-90) PUoLISHED IN T.~E METROLGIA 27, 

NO.1, 3/10/90. 

THIS T.~ZRMOMETER WAS C..l\..L:BRATZD AGAINST A S~~~ARD CALIBRATED AT TdE 

NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY (NIST) FORMERLY THE 

NATIONAL BL'REAU OF ST.'lliD~'illS (NBS) IN ACCORDANCE WITH ASTM METHOD 

E 77, &~NBS MONOGRAPH 174. 

FOR A DISCUSSION OF ACCURACIES ATTAINABLE WITH SUCH THERMOMETERS SEE 

NBS MONOGRAPH 250-23. 

IF NO SIGN IS GIVEN ON THE COR.~ECTION, T.~E TRUE TEMPERATJRE IS HIGHER 

T.-iAN T.~E INDICATED TEMPERATURE; IF THE SIGN GIVEN IS NEGATIVE, THE TRUE 

TEMPERATURE IS LOWER T:-iAN THE INDIC..Z\.TED TEMPER.Z\.TURE. TO USE THE COR.~ECTIONS PROPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GIVEN BELOW. 

THE THERMOMETER WAS TESTED IN A LARGE, CLOSED-TOP, ELECTRICALLY HEATED, 

LIQUID BATH, BEING "IMMERSED" 76MM. THE TZMPERATURE OF THE ROOM WAS 

ABOUT 25 DEGREES C (77 DEGREES F). IF THE THERMOMETER IS USED UNDER 

CONDITIONS WHICH WOULD CAUSE THE AVERAGE TEMPERATURE OF THE EMERGENT 

LIQUID COLUMN TO DIFFER MARKEDLY F?.OM THAT PREVAILING IN THE TEST, 

APPRECIABLE DIFFERENCES IN THE INDICATIONS OF THE THERMOMETER WOULD 

RESULT. 

TEST NL~BER: 154161 

DATE: .11/26/96 

STANDARD SERIAL NO. 128239 

NIST IDENTIFICATION NO. 88024 

E-29 

CONTINUED 

lt/o 
?AG2 2 OF -

R E P 0 R T 0 2 C A L I 3 R A T I 0 N 

LIQUID-IN-GLASS-TH~~~OME~~R 

THE TABu~TED CORRECTIONS APPLY PROVI~ED TH~ ICE-POINT RE~~ING, TAK~N 

AFTER EX?OSURE FOR NOT LESS THlu~ 3 DAYS TO A TEMPERAruKE OF ABOUT 20 

DEGREES C (70 DEGREES F) IS 32.00 DEGREES F. IF THE ICE-POINT READING 

IS FOUND TO BE HIGHER (OR LOWER) TFJlli STATED, ALL OTHER READINGS WILL 

BE HIGH~R (OR LOWER) TO THE SA."'E EXTENT. I2 THE rdERMOMETER IS USED 

AT A GIVEN TEMPERATURE SHORTLY AFTER BEING F£ATED TO A HIGHER TEMPERA~E. 

A.~ ERROR OF 0.01 DEGREES OR LESS, FOR EACH 10 DEGREE DIFFERENCE BE~NEEN 

THE TWO TEMPERATURES, MAY BE INTRODUCED. THE TABULATED CORB.ECTIONS A? PLY 

IF THE THER~OMETER IS USED IN THE UPRIGHT POSITION; IF USED IN A HORIZONT~ 

POSITION, THE INDICATIONS MAY BE A FEW HUriDREDTHS OF A DEGREE HIGHER. 

TEST NUMBER: 154151 

DATE: 11/26/95 

STANDARD SERIAL NO. 128239 

NIST IDENTIFICATION NO. 88024 

E-30 

Charles Tang-Nian I 

QUALITY CONTROL ~ER 
=:v=:?.. RE:..JC: :'?:E:P_"v!cM=:-::::::. ::: . , :)Jc. 

2 2 8 LAC:Qtl&'l""Nrl .:o..·;:::c.JUE 

WEST ?A~~ERSCN, N~ 07424 

(20l) 8:2-7474 

R E P 0 R 7 0 2 C A ~ : 3 R ;;. T - 0 N 

LIQUID-IN-GLASS-7EE~~CME7ER 

C~:3RA~E:D BY EVER READY TEE:RMOME7ER CO. 

~ARK2D: ER7CO CAT 612-3FC S/N-2775 ~~GE: 0 TO +300 DEGREES F IN 2 DEGREE: GRADUATIONS. 

THERMOMETER 

RE:rlDIOJG 

32.6 F 

100.0 

200.0 

300.0 

** ALL TEMPER..~~ES IN THIS REPORT 

TEMPERAPJRE SCALE OF 1990 (ITS-90) 

NO. l, 3/10/90. 

COR..'<.ECTION 

(:i:TS-90) ** 

-0.6 F 

-1.6 

-1.4 

-1.0 

ARE BASED ON THE I~ERNA~!ONAL 

PUBLISHED IN THE METROLGIA 27, 

THIS THERMOMETER WAS CALIBRATED AGAINST A S7ANDARD CALIBRATED AT THE 

NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY (NIST) FORMERLY THE 

NATIONAL Bu~U OF STANDARDS (NBS) IN ACCORD&~CE WITH ASTM MET.~OD 

E 77, AND NBS MONOGRAPH 174. 

FOR A DISCUSSiON OF ACCURACIES ATTAINABLE WITH SUCH TdER..~OMETERS SEE 

NBS MONOGRAPH 250-23. 

IF NO SIGN IS GIVEN ON THE CORRECTION, THE TRUE TEMPERATURE IS HIGHER 

TF..AN THE INDICATED TEMPERATURE; IF THE SIGN GIVE.L'J IS NEGATIVE, THE TRUE 

TEMPERATuKE IS LOWER THAN THE INDICATED TEMPERATURE. TO USE THE CORRECTIONS PROPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GI'TEN BELOW. 

THE THERMOMETER WAS TESTED IN A LARGE, CLOSED-TOP, ELECTRICALLY HEATED, 

LIQUID BATH, BEING "IMMERSED" 76MM. THE TEMPERATURE OF THE ROOM WAS .~Ou7 25 DEGREES C (77 DEGREES F). IF THE THERMOMETER IS USED UNDER 

CONDITIONS WHICH WOULD CAUSE THE AVERAGE TEMPERATURE OF THE EMERGENT 

LIQUID COLUMN TO DIFFER MARKEDLY FROM THAT PREVAILING IN THE TEST, 

APPRECIABLE DIFFERENCES IN THE INDICATIONS OF THE THERMOMETER WOULD 

RESULT. 

TEST NUMBER: 155404 

DATE: 04/22/97 

ST&'JDARD SERIAL NO. 48511 

NIST.IPENTIFICATION NO. 92564 

CONTINUED 

E-31 
?AGE 2 CF ~ 

R E P 0 R T 0 F C A L I B R A T I 0 N 

LIQUID-IN-GLASS-THER~OMETER 

TH:::: TABul-ATED COR.'<.ECTIONS A.?PLY PROVIDED TI'!E ICE POINT READING IS 

32.6 DEGREES F. IF THE ICE-POINT READING IS FOG~ TO BE HIGHER (OR LOWER) 

TF.JI..,'l STATED, P...!..L OTHER READINGS WILL BE HIGHER (OR LOWER) TO TEE SAHE 

EXTENT. 

TEST NUMBER: 155404 

DATE: 04/22/97 

STANuARD SERIAL NO. 48511 

NIST. IDENTIFIC~T!ON NO. 92564 

E-32 

_e__._~~k'~/ __ { _____ _ 

Charles Tang-Nian // 

QUALITY CONTROL MANAGER 

;t/.3 
Bulletin 0-01-82 

NATIONAL WEATHER SERVICE TYPE 

MERCURIAL BAROMETERS 

Usable up to 900 metres (3,000 feet) 

Tne Naticnal Weatr:er Sar,ica :yce ::=arcme!s-r is .P~JNCO's Mighest 

g:-ace ,--r.erc:.;riai :arc~er:r. It is '.JSec' ::y weat:-:er sar1ices ar.C 

air;:cf""':s ~r:e wcr!c ever. Tne ·;lass :uce ;"':as a :..1r.ifcrm insiCa 

Ciarr.et:r of 7 mm ~or c::nsrant caoilrary ~ecress:cn tr:rcugncut :ne 

len<;th oi the scale. Scales are set at the fac:o'Y ~Y ccmpanson 

with a barometer csrtirleC Cy tr.a i'\Ja~fcnal Sureau ::f StatlCarC:s. ar.d 

read :r.e local pressure witr.o~t the necessity ol correc:in<; fer 

capiilal"f decress;cn. The vern1er can :=e smccthly and prec1

sely set 

by means oi a rae:< and ;::inion ~.we. c:::ntrcllee :y a <nurlee 

adjusting :<nee. White ;::lasctc bac!<<;rouncs en :r.e mounting .oanel 

fac;litate observation ol the Fcrtm :YJ:e c:ster:1 anc merc~l"f column. 

Tne vem:er .'1as a s1ghting eege. frcnt ai'C rear. tc avcid J:arallax. 

A sus::ensicn brac~<et anc an aC:fus~ac!e nn~ ·.::amp .'or the c!s~am 

hc!C: tr:e !:aromerar firmly in the ver::ica! :csit:cn en :r:e mcut:rir.~ 

panel. A C(;aJ scale Cels;us/Fahrennelt merc-:cmetar 'Nith a -25 to 

50 "C/-10 :o 120 "F ra~<;e indicates the proper temperatura to t:e 

usee ~~cr tem.cera[TJre cor:-ec:ior.s. An ins~rtJc!icn :cck!et witr: 

infcrma!icn ~or ur.terstanc::n~ and .orccer use of tne barometer is 

supcliee with eac:O instrument Ccmctete ccrrec~cn tables tcr 

temperatura and ;ravity ara includee. 

Tms Oarcrr.eter is ac::::...tra!s ~c ::0.3 me. 0.2 r:-:m. or 0.01 inc:"! of 

merCI.ll"f wnen carefullv set and read. and after tem.cerature and 

gravity c:::rrec:icns :,a,,e ~een apcli~. For graatest ac::urac·; a 

Cert1iicate or Calit:raoon may ce obtainee al'd the ccrrecdcn 

containec there1n also apciiee. Eac:1 NaacnaJ Weather Service 

barometer has a serial nurr:t:er. 

The rug<;ec construc:ion of the NaticnaJ Weather Service type 

barometer is sue:-: t.~at it can be s.'11pcec safely by U n1tec Parcel 

Serv1ce or excress. Tne kidskin bag, in the For:in tyee reservoir, 

dampens mercul"f column oscmaoons during shipment Tne lower 

part of me glass tube is narrcwee dcwn to minimize mercul"f 

weight. anc is protec:ec by fcam cushions. tnus offering accee 

resistance to damage dunng st1icment. Tne cistern may be ~enec 

in the field fer cteamng of the cistern glass and c;s:em mercul"f. The 

barometer contains accroximately sao grams (1.5 pounds) ct mercul"f 

total. It is ;n1ppec completely assemc1ee. filled with :nerc:..r; and 

reacty to use. Mcunt1ng panel dimensions are 19 x 76 x 1072 mm 

(3/4 x 3 x .12 1nc.~es). The shipping we1gnt is 5 k<; (11 pounds) and box 

dimensions are 235 x 250 x 1197 mm (9 x 10 x 47 inc:1es). 

Catalog Number 

~453 

45381 

453MB 

E-33 

Scales 

inc.~ and millimetre 

inc~ and millibar 

millibar and millimetre 

ents 
00 

{-"'"~'-~--\ ~-

:'; ~\ '1o :.. '0 , - ':SQqQ\l~ 

sartcj>rius 

BALANCE CERTIFICATE of CAIJBRATION 

CL'STOME..q; ~,.,c C\.. CERTIF1C\.TE #: S20-15813 

( Z.CC ·r~'-' ~~':.\'='c.\., \)\vc:\DATE OF CALIBRATION: 2. !2,-[ !"'.'f 

C\,\clv \_~ "' C -z._<;-.z_~.'\ NEXT CALIBRATION DCE: '2_ .'"-,''C ---===--:-;::::::::;;=...,,------

DEPT: L'\/VlRONMEYrAL CONDITIONS: ·~,:O~e'~' 'eoc•i 

This certifies that the test weights used are traceable to the 

Natianal Institute of Standards & Technology 

Sartorius Weight set ID#: _'L, ~_l·--=-<::,~?-,._~-'----------

Calibrated to Class: _,0-=.",:,:,..... ________ _ 

Date weight set calibrated: ____,z_=---,_t w-'-·. _c_:-\._:'l'---------

Date weight set due: 

N.I.S.T. Test number: 

CORNER LOAD ERROR WEIGHT USED : TOLERANCE : \'-

- ") "''':) -

A B ~s I n* A B " I c TOl.E;(ANCE 

s I YN 

I I 

BEFORE ADJ. .L-1~1-~ 'ic- '-· . ....__, ----- -

I 

AFTER ADJ. ~ 1-~ I~ * cj 

FROI:'<'T *:-lot applicable ro circular pans 

LINEARITY CHECK: • RANGE: - ' ~~ TOLERANCE.- ' ., "'-' RA N G" e: TOLERANCE 

IN IN 

Nominal Value Before Adjustment TOL.BlANCE After Adjustment 'C\..ffiANC:E 

;o ..._,c., _ a_ c\c\t,Q 

'- 0() 6C\ ~ c\ '\ "2._ '. \• 

\ ")""' I (....\ C\ <._, "'1. c\ "\ G '· \ \ . -~ .r_CG '- "\ c.: ' \. <:.;, c, 'e_. '\ 

~~-~r I 

'-~ \ \ x. _..,__ r'v;)." v' '2. : "2 '-! 

~o~r,P,ce Ref ~esentative Date 

l~l He3.rtiand B . 

Ed g ewood • N~ Yor ll 7 l 7 

(800) 545-3108 

(516) 244249 

Fa.:'<: (516) 254-4252 E-34 

y N y N ., ~ '--, "'\ , '\ "\ c\ <\ -~ 

··~ j... \ 0 C· . ~· cc--,n •' 

\/ \)C: (") (\ C'-C / 

tr-v ~ c:.~ C'· . c: C..) (\ l ./ 

"'" \ I 

RE= S2CCO 195 

It/) 
sart<j>rius 

BALANCE CERTIFICATE of CALIBRATION 

DEPT.:-----------

This certifies that the test weights used are traceable to the 

National Institute of Standards & Technology 

Sartorius Weight set ID#: IC(S~ ~ 

Calibrated to Class: 

Date weight set calibrated: --="::._-_:'-_:'-1.~--q_~'l.:..._ ______ _ 

Date weight set due: a- \'-I - Ci. 'C, 

N IS T T t b '2..b2.-\ ?.S''-V--L~O . . . . es num er: t 

WEIGHT US"D c : TOLERANce+ ~: 

-

~I I n* N I A B c TCl£ilANC; 

I I Y Ni 

I i I 

BEFORE ADJ. I& -& 1-B I~ I'-" 

I 

I 

AFTER ADJ. -s-j-G I-sI r[1 

LINEARITY CHECK: RANGE: I I \ · DOG "'- TOLERANCE:- • ""'C 

N aminal Value Before Adjustment 

2CJ c. t.-..0.oao_3 

50 ;;: 50::::. . aa CYl 

'lO ? ;lG. Ooc::.~ 

LOu ;:: too. ooa8 

---7 ' C\----\ \)~~ ~ 3-5' 

Q;ln:orius ~Sen ~ce ReJ :fesentative 

131 Heartia.n.d 

Ed<ewood· N~ 11717 

(800} 645-3108 

(516) 254.4249 

Date 

TOI.EJt'.NCE '" 

YN 

j./ 

v 

IV' 

Jv' 

-~1 

* :-io< applic:able w circular pans 

RANGE: TOLERANCE: 

After Adjustment 

2._ O,oc:.oc. 

'3U -GOe, \ 

'l 0 . 0<:,() \ 

laG , ~a 

I 

I 

I 

N 

~Cl.S<ANCE 

YN 

'....-' 

, ........ 

, ....... 

, ...... }--

Fax: (516) 254.4252 

E-3:' 

REF S2CCO 195 
_W_e_ig.;__n_' t_C_a f_i b_r_a_tJ_·o_n_C_e_rt_i_fi_ca_t_e __ ~~ -!Me- r121Jt1 

SECTION 1: NA ... 'v!E . .>u~L) ADDRESS OF Ct;STOMER 

Sartorius Corp 

8106 Counrrv Oaks Rd 

Charlotte NC 28227 

Page 1 of 7 Pages 

Certificate Number: 94962 

· SECTI~A.PPROvcD SIGNATORY 

~ / ~--:. o--?v· -~- 4c.::, ~----- Robert Thompson 7 

SECTION 3: PERSON PERFO&'.-llNG WORK 

Gayle Carsey 

SECTION 4: CERTIFICATE INF0&\1ATION 

Description of :V!asses: Troe=er Sartorius lOOg-lmg Weight Set Class 1 

Accuracy Class 

Order Number 

Construction 

Material 

Serial Number 

ASTM E617 -91 Class 1 

S31705 

One Piece, Two Piece 

Stainless S reel 

Stainless Steel (mg) 

Aluminum 

19333 

Dare Received 

Date of Calibration 

Date of Issue 

Weight Range 

SECTION 5: ENVIRONMENTAL CONDmONS DURING TEST 

13-JAJ.'<-1997 

14-FEB-1997 

14-FEB-1997 

1 gram & greater 

500 mg- 50 mg 

30 mg & below 

Temperature: 22.00°C Pressure: 774.48 = Hg Relative Humidity: 44% 

SECTION 6: PERTINENT INF0&\1ATION 

The Weights listed on this calibration report have been compared to reference mass standards that are 

directly traceable to the National Instirure of Standards and Technology under Test No. 822/254480. 

Reference standards and balances used to perform the calibration are listed in Section 10. 

The weights calibrated for this report have been calibrated in accordance with Troe=er' s 

calibration process. The calibration performed meets Level I criteria as described in the 

NIST/NYLAP Technical Guide 150-2. 

This calibration also meets specifications as outlined in ISO 9001. ISO Guide 25. 

AJ.'<SIINCSL Z540-1-1994, NCR Document 10CFR50 Appendix B, and applicable documents. 

This certific:ue ofc::tlibrJ.rion shalt not be reproduced except in full. wirolithe written approval ofTroemner. Inc. This certificate of 

c::tlibr::trion musr not be used by the customer :o c!::tun product endorsemt:nt by :"lvtAP or Jny Jgency of the U.S. government. it/7 
7ROeMNER 

-~.....:; ;~"" _,-

Weight Calibration Certificate §:.4..; --------~~---------------------------------------------------------------------- ------~ 

NA.i'v!E A.t~D ADDRESS OF CUSTOlYIER 

Sartorius Corp Plge 2 of 7 Pages 

8106 Coumrv Oaks Rd 

Charlotte NC 28227 Cer.ificare Number: 

SECTION 7: MASS IN A VAC1.Jl.TlY1 (TRUE MASS) CALIBRATION DATA 

Nominal Serial 

Mass Value Number 

100 q 

50 q 

20 q 

20 q • 

10 q 

5 q 

2 q 

2 q • 

1 q 

500 mg 

200 :ng • 

200 mg 

100 mg 

50 mg 

20 mg • 

20 mg 

10 mg 

5 mg 

2 mg 

2 mg • 

1 mg 

l Density is Jssumed unless olherwise stated 

• Denotes weight is mJ.r!ced wuh a doc 

---- Mass in Vacuum ------ As Found As Left 

100.00022738 q 100.00022738 

50.00014405 g 5J. 00014405 

20.00005846 g 20.00005846 

20.00007663 q 20.00007663 

10.00001712 g 10.00001712 

5. 00001542 q 5. 00001542 

2.00001906 g 2.00001906 

2.00003807 q 2.00001647 

l. 00002740 q 1. 00002740 

0.49999957 q 0. 49999957 

0.20000545 q 0.20000545 

0.20001228 g 0.20000112 

0. 09999479 q 0.09999479 

0.05000362 q 0.05000362 

0. 02001431 q 0. 02001431 

0.02001798 q 0.02001131 

0. 01000644 g 0. 01000644 

0.00500716 q 0. 00500716 

0.00200529 q 0.00200529 

0.00199295 q 0. 001992 95 

0.00100800 g 0.00100800 

[-37 

Densirvl 

ofWeighr 

g 7.8500 q/ c:n.3 

g 7.8500 q/ c:n.3 

q 7.8500 q/ c:n.3 

g 7.8500 q/ c:n.3 

g 7.8500 g/ c:n.3 

q 7.8500 q/ c:n.3 

q 7.8500 g/c:n.3 

q 7.8500 g/c:n.3 

q 7.8500 q/ c:n.3 

g 7.9500 q/ c:n.3 

g 7.9500 g/c:n.3 

q 7.9500 q/ c:n.3 

q 7.9500 q/ c:n.3 

q 7. 9500 q/ c:n.3 

q 2.7000 g/c:n.3 

q 2.7000 q/ c:n.3 

q 2.7000 q/ c:n.3 

q 2.7000 g/c:n.3 

q 2.7000 g/c:n.3 

q 2.7000 g/c:n.3 

g 2.7000 g/c:n.3 

-t..c-tiBQ1.2. 

94962 

uncenaimy 

0.0774: :::g 

0.0395 :::.g 

0.0345 :ng 

0. 0345 :::g 

0.0254 mg 

0.0063 :::g 

0.0037 :~>g 

0.0115 :ng 

0.0036 :::g 

0.0025 :ng 

0.0022 :ng 

O.OOlS :ng 

0.0027 :ng 

O.OOH mg 

O.OOH mg 

0.0022 mg 

o.oo:4 mg 

0.0015 mg 

0.0013 mg 

0.0013 :ng 

0.0022 :ng 
TRO!:MNER 

· . ..:~~~7-: /-"'' 

Weight Calibration Certificate ~~ ------~:-----------------------------------------------------------------------~~~~ ....-e-a~---., 

- tM' C::dr 'ta7T~ 

NA..t'v!E Ac'ID ADDRESS OF CUSTOMER 

Sartorius Corp Page 3 of 7 Pages 

8106 Country Oaks Rd 

Charlotte NC 28227 Certificate Number: 94962 

SECTION 8: MASS IN AlR CALIBRATION VALliE VS. REFERE:-.ICE DENSITY 8.0 gicm3 

Nominal Serial -Conventional Mass Value ----

Mass Value Number As Found As Left Uncertainty Tolerance 

100 g 99.9999407 g 99.9999407 g 0.0774 mg 0.2SOOOO :ng 

sa g 50.0000007 g S0.0000007 g 0.039S mg 0.120000 mg 

2a g 2a.aaooou g 2a.aaaoou g a.a34S mg a. a74ooo mg 

20 g • 20.000a193 g 20.0000193 g a.0345 mg 0. 074000 :ng 

1a g 9.999988S g 9.9999885 g 0.02S4 mg a.asaaao mg 

s g s.aaoao21 g s. aaaoo21 g a.a058 mg 0.0340a0 mg 

2 g 2.000a133 g 2.0000133 g o.aa37 mg a.03400a mg 

2 g • 2.0000323 g 2.000a107 g a. allS mg 0.034oaa mg 

1 g 1.aaaa24S g 1.a000245 g a.aa35 mg a. oHooo mg 

sao mg a.4999991 g a.4999991 g a.aa25 mg 0.01aOOO mg 

2aa mg • a.2aaoos3 g a.2aoaos3 g a.aa22 mg a.alaooa mg 

2aO mg a. 2aaa121 g 0.2aooao9 g a. aa18 mg a.o:ooaa mg 

1aa mg a.a999947 g a.a999947 g a. aa21 mg O.Oloaaa mg 

so mg a.asaaa35 g a.asooa35 g a. a au mg a.a1aaaa mg 

20 mg • a.a2aaa84 g a.a200084 g a.aal4 mg 0.01aooo mg 

20 mg a.o2a0121 g 0.0200aS4 g a.aa22 mg 0.01aaoo :ng 

1a mg a.a1aao35 g a.a1aa035 g 0. 0014 mg 0.010000 mg 

s mg a.aosoa57 g a.aasao57 g o.a015 mg a.a1aaoo mg 

2 mg a.ao2aa47 g a.aa20047 g 0. aa18 mg a.Olaoao mg 

2 mg • o.aa19924 g a.oa19924 g a. aal8 mg a. 01aooa mg 

1 mg a. aa1aan g a.aa1a077 g a.oa22 mg a.Oloaao mg 

E-38 

• DenQ(eS weight is marked with a dQ( 
.-- ..;-, /. 

_v.,...-Ve_j~g_h_t_C_a_f_j b_r_a_t I_·o_n_C_e_rt_j{_j c_a_t_e __ ~~ -UDc- rOIII:nl. 

NAJ.vlE AND ADDRESS OF CUSTOtvlER 

Sanorius Coro Page 4 of 7 Pages 

8106 Coumri Oaks Rd 

Charlotte NC 28227 Certificate Number: 94962 

SECTION 9: :YIASS IN AIR CALIBRA.TION DATA VS. REFERENCE DENSITY 8.0 g/cm3 

Nominal Serial - Conventional Mass Correction --

Mass Value Number As Found As Left U ncenainry Tolerance 

100 g -O.OS93 mq -O.OS93 mg 0. 07 74 mg 0.2SOOOO :ng 

so g ~0.0007 mq +0.0007 mg 0.039S mg 0.120000 :ng 

20 g +0.0011 mq +0.0011 mg 0. 034S mg 0.074000 :ng 

20 g • +0.0193 mg +0.0193 :ng 0.0345 mq 0.074000 mg 

10 g -0. 011S mq -0.011S mg 0.02S4 mg o.osoooo mq 

s g +0.0021 mq ~0.0021 mg 0.0068 mg 0.034000 mg 

2 g +0.0133 mq +0.0133 mg 0.0037 mg 0.034000 :ng 

2 g • +0.0323 mq +0.0107 mg 0. OllS mg 0.034000 :ng 

1 g +0.024S mq +0.024S mq 0.0036 mg 0.034000 mg 

soo mg -0.0009 mg -0.0009 mg 0.0026 mg 0.010000 mg 

200 mg • +0.00S3 mg ~o.OOS3 mg 0.0022 mg 0.010000 :ng 

200 mg +0.0121 mq +0.0009 mg 0. 0018 mg 0.010000 mg 

100 mg -O.OOS3 mg -O.OOS3 mg 0.0027 mg 0.010000 mg 

so mg +0.0036 mq +0.0036 mq 0. 0014 mg 0.010000 mg 

20 mg • +0.0084 mg +0.0084 mq 0. 0014 mg 0.010000 mg 

20 mg +0.0121 mq +0.00S4 mg 0.0022 mg 0.010000 mg 

10 mg +0.003S mg +0.003S mg 0. 0014 mg 0.010000 mg 

s mg +0.00S7 mg +0.00S7 mg 0.0015 mg 0.010000 mg 

2 mg +0.0047 mg +0.0047 mg 0.0018 mg 0.010000 mg 

2 mg • -0.0076 mg -0.0076 mq 0. 0018 mg 0.010000 mg 

1 mg +0.0077 mg +0.0077 mg 0.0022 mg 0.010000 mg 

E-39 

• Denmes weight ~s marked with ::1 Jot 
-----·' 

vVejght Calibration Certificate ::.4..~ ---------=~---------------------------------------------------------------------~--~~ 

NA.v!E A."'D ADDRESS OF CUSTOi.V!ER 

Sartorius Corp 

8106 Counrry Oaks Rd 

Charlorte NC 28227 

SECTION 10: CALIBRATION PROCEDURE DATA 

Nominal Serial Standard Balance 

Mass Value Nwnber Set No. Used 

100 g S007 AT106-007 

50 g. S007 A':'l06-007 

20 g S007 ATl06-007 

20 g • S007 AT106-007 

10 g S007 AT106-007 

5 g SOl3 1lM'l"5-013 

2 g S013 1lM'l"5-0l3 

2 g • soo8 MT5-008 

1 g S0l3 1lM'l"5-013 

500 mg soo8 MTS-008 

200 mg • soo8 MTS-008 

200 mg soo8 MTS-008 

100 mg soo8 MTS-008 

50 mg soo8 MTS-008 

20 mg • soo8 MTS-008 

20 mq soo8 MTS-008 

10 mg soo8 MTS-008 

5 mg soo8 MTS-008 

2 mg soo8 MTS-008 

2 mq • soo8 MTS-008 

1 mg soo8 MTS-008 

• Denou:s weight is marked with l dot 

..-Lata-rQSM.1. 

Page 5 of 7 Pages 

C<!rtificate Nwnber: 94962 

Procedure Finish 

Used Grade Type 

3-1 Modi:!ied 

3-1 Modi!ied 

3-1 Modi!ied 

3-1 Modi!ied 

3-1 Modi!ied 

3-1 Modi:!ied 

3-1 Modi!ied 

3-1 Modi!ied 

3-1 Modified 

3-1 Modified 

3-1 Modi!ied 

3-1 Modified 

3-1 Modi!ied 

3-1 Modi:ied 

3-1 Modified 

3-1 Modified 

3-1 Modi!ied 

3-1 Modified 

3-1 Modi:ied 

3-1 Modi:ied 

3-1 Modified 
7ROEMNE:R 

-:-_---. # -

~--' 

Weight Calibration Certificate ~~ --------~----------------------------------------------------------------------------

NPuY1E A . .;'lD .WDRESS OF CUSTOMER 

Sanorius Corp 

8106 C oumrv Oaks Rd 

Charlotte NC 28227 

SECTION 11: GENER.-\1. INFOR.'<fA TION 

-lM C.. r~Sr.L 

Page 6 of 7 Pages 

Certificate Number: 94962 

This calibration was performed in Troemner's High Precision Level I Mass Metrology Laboratory at 

6825 Greenway Avenue, Philadelphia, Pennsylvania 19142 unless otherwise noted on page one. 

SECTION 12: DEFThlTIONS Pu'ffi TER.\-IS 

MASS IN A VACUt:M -The mass of a weight as if it were measured in a vacuum. Also known as True Mass. 

MASS IN AIR- Is the mass value of a weight based on conventional mass versus material density 8.0 g/cm3 at 

zo• C with air density of .0012 g/cmJ. This value takes into account the buoyant effect of air on the weight. 

The Mass in Air values are reported as corrections above or below nominal value in the calibration report. 

AS FOUND MASS IN A VACUUM - The estimated value of the mass(es) as they were received by Troemner. 

If the customer requires cleaning prior to calibration, the after cleaning value would be reported. 

AS LEFT MASS IN A VACUUM - The estimated value of the mass(es) after they were adjusted, repaired 

or replaced when necessary. The As Found Mass in a Vacuum will equal the As Left Mass in a Vacuum 

if the mass(es) did not require adjustment, repair or replacement. 

NOMINAL MASS - The mass value as marked on the weight. 

CORRECTION - the difference berween the mass value of a weight and its nominal value. A positive 

correction indicates that the mass value is greater than the nominal value by the amount of the correction. 

AS FOUND CONVENTIONAL MASS CORRECTION- The estimated correction of the mass(es) as they 

were received by Troemner, taking into account the buoyant effect of air. If the customer requires cleaning 

prior to calibration, the after cleaning value would be reported. The correction is based on mass in Air. 

AS LEFT CONVENTIONAL MASS CORRECTION -The esrirnated correction of the mass(es) after they 

were adjusted, repaired or replaced when necessary, taking into account the buoyant effect of air. The 

As Found Conventional Mass Correction will equal the As Left Conventional Mass Correction if the 

mass(es) did not require adjustment, repair or replacement. 

UNCERTAINTY- The error in assignment of the correction due to the measurement process. Uncertainty 

is calculated per NIST Technical Note 1297 using a coverage factor of K = 2 ( K = 2 defines an interval 

having a level of confidence of approximately 95 percent). 

TOLERANCE - Defines the limits in which the correction value must fall to meet the tolerance specification 

for the .given Class. 

(continued on next page) 

E-41 
!·zrr. 

Weight Calibration Certificate §::.#_:; --~--~~------------------------------------------------------------------ --~d~ 

NAJ.viE AND ADDRESS OF CuSTOiYIER 

Sanorius Corp 

8106 Counrrv Oaks Rd 

Charlotte NC 28227 

SECTION 12: DEFL'fiTIONS AND TER.VIS (continued) 

.... ~c-t~ 

Page 7 of 7 Pages 

Certificate Number: 94962 

AS FOUND CONVENTIONAL MASS VALUE- The estimated value of the rnass(es) as they were received 

by Troemner, taking imo account the buoyant effect of air. If the customer requires cleaning prior to 

calibration, the after clean value would be reponed. 

AS LEFT CONVENTIONAL MASS VALUE- The estimated value of the mass(es) after they were adjusted, 

repaired or replaced when necessary, caking into account the buoyant effect of air. The As Found 

Conventional :V[ass Value will equal the As Left Conventional Mass Value if the rnass(es) did not 

require adjusrmem, repair or replacement. 

SECTION 13: ADDENDUM 

Next Calibration Due Dace: 8/14/98 

Regina McHale 

Krishna Bishnach 

E-42 
.. ~ 

JamesA.Graham ..;-~ ----- ~arl~ a!arnlimx 

comnu.,,on,. \...):s::;_,__..-- ~eparlnumt af ci\gri.culture 

-- -- ~tzmllm-11!5 ~ iDil5 iun 

N. David Smith 

Direcroc 

CERTIFICATE OF TRACEABILITY 

AND 

REPORT OF CALIBRATION 

The standard(s) described on the following page have been compared 

to standards of the State of North Carolina and have been found to 

have values as listed. Traceability to the National Institute of 

Standards and Technology, NIST (formerly The National Bureau of 

Standards, NBS) is via the NIST test number listed on the report. 

Adjustments of precision laboratory standards are not recommended. 

Therefore, no adjustments have been made to these standards and 

certification to any tolerance classification is neither stated nor 

implied. The user(s) of these standards should examine the deviation 

from nominal value and the associated uncertainty to ascertain if these 

standards meet their precision requirements. 

The uncertainty is an expression of the overall uncertainty using three 

standard deviations as the limit of random errors of measurement plus 

the uncertainty of the State Standard used in comparison. 

The primary testing methodology used is the Double Substitution 

Method, NIST Handbook 145, Handbook for the Quality Assurance 

of Metrological Measurements, SOP number 4. Three double 

substitution weighings are averaged to arrive at the listed value. 
NORTH CAROLINA DEPARTMENT OF AGRICULTURE 

JAMES A. GRAHA...~ 

COMMISSIONER OF AGRICULTURE 

STANDARDS DIVISION 

P.O. BOX 27647, RALEIGH, N.C. 27611 

(919)733-4411 

N.DAVIDSMUTH,DlllECTOR 

STATE:MENT OF TRACEABILITY 

SUBMI'IIED BY: Trigon Engineering Consultants 

1920 Starita Road, Suite J 

Charlotte, NC 28206 

DATE OF TEST: September 24, 1996 

TEST NUMBER: NC0996W052 

TOLERANCE: ASTM Class 4 

PO NUMBER: AM7275 

DESCRIPTION: One (1) Set of Ohaus (brand) Weights, Serial Number 6640 

1 • 50 g weight 1 • 200 mg. weight 

1 • 30 g weight 1 • 100 mg weight 

1 • 20 g weight 1 • 50 mg weight 

1 • 10 g weight 1 • 20 mg weight 

1 • 5 g weight 1 • 20 mg. weight 

1 . 3 g weight 1 • 10 mg weight 

1 • 2 g weight 1 • 5 mg weight 

1 • 1 g weight 1 • 2 mg weight 

1 • 500 mg weight 

1 • 200 mg weight 

The items described above have been compared with the standards of the State of North Carolina, and are 

traceable to the National Institute of Standards and Technology, NIST via the test number shown above. All 

tests were performed in the North Carolina Standards Laboratory. Environmental conditions are maintained 

at a temperature of 2ZOC ± 2°C and a relative humidity of 50%± 10%. 

J4L 

METROLOGIST 

L.F. Eason Sherry Teachey 

Sharon Denning Van Hyder Karen Bryan 

page l Ori,UW C.:rtific:atc Has The NCDA Seal Emboued Above 

Fn.EN AME: F:IOROUPS\ST ANDLAB\Fll.ESYSI TRIGON\ 199610996W052. WPD 

E-14 
:--.-CDA ST.-\..'iDARDS L\BORA.TORY l<:!.St ~umber: 

DEViCE TEST DATA SHEET NCO Q~ Wosz., 

!I IultbN E tJ &i.Hml/lll, Q clAl.So Lr .A:AtT ~ Date: CJmpany: I 

!I Address: lqw 2~li~ ((.o.+di !,vitc T r.r-z~-r~ ' 

City, ~h~tlcr+ Q ?..W State, Zip: Date Scheduled: 

:I CJunry: Mtctlef.l bo Phone: ( 'fD4 Jsr{8- [ o4 Ext 6-e ZD ej q 

Representative: Pt1uf 2.. ~ Purchase Order No: tt m '7 2. '75 page _j_ oi _J _ 

Itemized Description 

I! a ... Description Apd C.d Adj R.<j Can I Cu.• I Description - I Apd I c.J I Adi I R.; lev• I 

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Dare Met Wor1c Completed Date Met Work Completed 

lq-/q-% 50 tEcsioJed Ws'ah+-s q/:;.;'/or, /Q) f//;-1) I/;# /r /, .I ./ I 

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I 

I 

Remarks:------------------------------

Tolerance Class Number of Devices I 

or I I I I 11 Calibration O.nly Approved Cal.ibr.ued Adjusted RCOJeeted Condemced Ice Point 

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E-47 
Greensboro 

\ronh C,lroltnd 

336-668-0093 

Trigon Services 

• Geotechnical Engineering 

• Construction Materials Engineering/Testing 

• Roof Engineering/Inspection 

• Forensic Engineering 

• Environmental Audits/Site Assessmerts 

• Environmental Drilling 

• Groundwater Studies/Remediation 

• Storrnwater Permitting 

• Water Treatment Design 

• Mechanical Engineering 

• Waste Minimization Studies 

• Air Permitting 

• Atmospheric Computer Dispersion Modeling 

• Stack Testing 

• Indoor Air Monitoring 

OFFICE LOCATIONS 

Raleigh 

l\:llrth Carolina 

919-755-5011 

Charlotte 

Nurth Carolma 

704-598-1049 

Greenville 

South Carnllna 

cJ64-2n-Js57 

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