# Patent

## Title
Negative differential resistance (NDR) memory device with reduced soft error rate

## Abstract

An active negative differential resistance element (an NDR FET) and a memory device (such as an SRAW using such elements is disclosed Soft error rate (SER) performance for NDR FETs and such memory devices are enhanced by adjusting a location of charge traps in a charge trapping layer that is responsible for effectuating an NDR behavior. Both an SER and a switching speed performance characteristic can be tailored by suitable placement of the charge traps.

## Background
CROSS REFERENCE TO RELATED APPLICATIONS
The present application claims priority to and is a continuation of application Ser. No. 10/298,700 Nov. 18, 2002 entitled Negative Differential Resistance (NDR) Element & Memory with Reduced Soft Error Rate, now U.S. Pat. No. 6,727,548 which in turn is a divisional of Ser. No. 10/185,569 filed Jun. 28, 2002, now U.S. Pat. No. 6,567,292, both of which are hereby incorporated by reference as if fully set forth herein.


FIELD OF THE INVENTION
This invention generally relates to semiconductor memory devices and technology, and in particular to negative differential resistance (DR) elements and static random access memory (SRAM devices that utilize the same.
BACKGROUND OF THE INVENTION
A new type of FET and SRAM device using the same (NDR FETs) is described in detail in a patent application Ser. No. 10/029,077 filed Dec. 21, 2001 assigned to the present assignee, and published on May 9, 2002 as Publication No.2002/0054502. The NDR FET structure, operation and method of making the same are discussed in detail in patent application Ser. No. 09/603,101 filed Jun. 22, 2000 by King of al, which is also assigned to the present assignee. Such details are also disclosed in a corresponding PCT application PCT/US01/19825 which was published as publication no. WO 01/99153 on Dec. 27, 2001. The above materials are hereby incorporated by reference.
As is well known, soft errors in memory devices are caused by, among other things, cosmic rays (neutrons), and alpha particles present in semiconductor materials and packaging. In typical SRAMs, the failure rate attributable to soft-errors (the so-called soft-error rate—SER) is measured by a metric known as Failures In Time (Fri); the basic unit of this benchmark refers to a function occurrence frequency, where 1 FIT represents one malfunction every one billion hours (approximately 100,000 years) per device. For a conventional SRAM operating under normal conditions an FIT value of up to several thousand is considered adequate, and a value of less than approximately 1000 FIT/Mbit is preferable for embedded memory applications. In some applications more stringent requirements may be needed (Le, on the order of 10-100 FIT/Mbit).
Soft errors can also influence SRAM embodiments which use NDR devices. Thus there is clearly a need for NDR FFT and an NDR FET based SRAM device that have superior soft error characteristics.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a memory device such as a static random access memory (SRAM) cell which utilizes NDR FETs, and which has improved soft error rate (SER) performance.
A first aspect of the invention concerns a method of forming a semiconductor field effect transistor (FET) for a memory device, the FET having a control gate, a source region, and a drain region. This method includes generally the following steps: forming 2 channel for carrying a current between the source and drain regions; and forming a trapping layer located proximate to and forming an interface with the channel. The trapping layer includes trapping sites adapted for trapping at least warm carriers from the channel so as to effectuate a negative differential resistance mode for the FET. To tailor characteristics of the FET, including an operational switching speed for the FET, the trapping sites are also tailored. In other words, the FET speed is directly related to a distance which the trapping sites are located from the interface, such that locating the trapping sites at a distance D1 results in a maximum operational switching speed S1, and such that locating the trapping sites at a distance D2 (D2>D1) results in a minimum operational switching speed S2 (S2<S1). Thus, the trapping sites are distributed within the trapping layer at an approximate distance D (D2>D>D1) in accordance with a target operational switching speed S for the FET (S1>S>S2) and a target soft error rate for the memory device.
The trapping sites are distributed at a particular distance by adjustment of an implant energy and dosage, and/or a thermal anneal operation. In a preferred embodiment, D1 is about 0.5 nm, and D2 is about 1.0 nm. Preferably no traps are included in the bulk of the trapping layer that forms a gate dielectric for the NDR FET. The operational speed of the FET is thus between about 10 nanoseconds ard 1 picosecond using contemporary conventional technology. This also achieves a soft error rate of less than about 1000 failures in time per Mbit.
In other variations, an additional set of trapping sites are formed at an approximate distance D′ from the interface where (D2>D′>D1).
To prevent them from achieving a high concentration in a bulk region, a rapid thermal anneal ETA) is performed after such implant. Alternatively the trapping layer can be formed by two distinct layers, including a first dielectric layer and a second dielectric layer, where the trapping sites are located only within the first dielectric layer.
In yet another variation, the trapping sites are located laterally along only a limited portion or region near the interface. Preferably this limited portion is nearer the source than the drain of the NDR capable FET.
Another aspect of the invention concerns a memory device which uses a trap layer in which charge traps are used to effectuate NDR characteristics for the load and driver elements. The charge traps are distributed in the trap layer so as to cause the memory cell to achieve a soft error rate of approximately 1,000 failures-in-time (PITs)/Mbit or less.
In a preferred embodiment, the memory device is a static random access memory (SRAM) cell and the load and driver elements are both NDR-capable FETs. The charge traps are distributed in the trap layer so that the NDR-capable PETs switch with a switching speed between 1 picosecond and 10 nanoseconds.
Other particular aspects of the invention pertain to the character of the traps, such as their material properties (preferably a doping impurity such as Boron), their density (preferably about 1 to 5*1014 traps/cm2 at a distance of about 0.5 nm from an interface of the trapping layer with a channel of the NDR-capable FEI) their energy (preferably about 0.5 eV above a conduction band edge of a channel of the NDR-capable FET), and methods for forming the same within a memory cell



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a circuit diagram of a preferred embodiment of a static random access memory (SRAM) cell consisting of the combination of two NDR-FET elements which form a bistable latch and one n channel enhancement-mode IGFET access element;
FIG. 2 is a plot of the current-vs.-voltage characteristic of the bistable latch formed by the combination of two NDR-FETs as shown in FIG. 1;
FIG. 3A is a schematic cross-sectional view of an NDR PET of a preferred embodiment of the present invention and which is preferably incorporated as one or both of the two NDR FET elements of the SRAM cell of FIG. 1;
FIG. 3B is a graph generally illustrating a relationship between SER and switching speed for an NDR FET and NDR based SRAM device constructed in accordance with the present teachings.



DETAILED DESCRIPTION OF THE INVENTION
As noted earlier, FIG. 1 is a circuit diagram of a preferred embodiment of a static memory (SRAM) cell 105 consisting of two NDR elements 102, 103 which form a bistable latch 104 and one enhancement-mode IGFET access element 101.
FIG. 2 is a current-vs.-voltage plot illustrating the operational characteristics of the static memory cell 105 of FIG. 1.
NDR elements 102, 103 of the present invention are preferably an NDR FET of the type referred to above in the aforementioned King et al. applications and constructed in accordance with such teachings except as noted below. The details of the same are provided for example in the aforementioned applications, and such documents are incorporated by reference herein primarily for the purpose of providing non-essential background information on representative types of environments in which the present inventions can be practiced.
The SRAM cell using NDR FETs described in application Ser. No. 10/029,077 is already believed to have superior SER performance over prior art SRAM cells due to its unique architecture and physical operation. This SRAM cell is particularly advantageous for embedded SRAM applications, which are becoming more and more critical for system on chip (SOC) devices.
Nonetheless, to achieve even better SER performance, the inventor has determined that the structure and manufacture of the basic NDR FETs 102, 103 used in the embodiment of FIG. 1 can be tailored to create different distributions of the charge traps (which assist in bringing about an NDR characteristic). Thus, for any particular desired design or needed performance characteristic, both a switching benchmark and an error benchmark can be controlled. While the description herein is presented in the context of a conventional bulk silicon based memory cell, it will be understood by those skilled in the art that the present teachings could also be exploited in so-called Silicon on Insulator (SOD) based SRAM cells. The advantages of SOI technology include the fact that the SER is generally lower as compared with bulk-Si technology because of the overall reduced p-n junction sizes.
As shown in FIG. 3A, the overall structure as shown in cross section of a preferred NDR FET 100 of the present invention is similar to that shown in the aforementioned Ser. No. 10/029,077 and includes generally a substrate 120 with a body bias terminal 125; a source region 140 (with a source terminal 145) coupled through a channel region 140 to a drain region 150 (with a drain terminal 155) by a channel region 140; a gate dielectric 130 and a gate electrode 110 connected to a bias signal through a gate terminal 115.
The primary difference, as described herein, is that the charge traps (131, 132) of the present invention are tailored to be placed at a particular location (or locations) in gate dielectric in accordance with a desired SER and switching speed for an NDR PET. It will be appreciated by those skilled in the art that the cross section of FIG. 3A is not to scale, and that certain features have been simplified and/or omitted to make the present discussion more germane to the claimed invention.
From theoretical calculations, simulations and experiments the inventor has determined that the speed of the NDR mechanism is directly related to, among other things, the trap density and physical location of the trap states: in other words, the farther the traps are from the interface (d2>d1) the slower the NDR mechanism. Preliminary data suggests that if charge traps are incorporated as a charge trap distribution 131—I.e., right at or very near the channel/dielectric interface (i.e., d1 is almost 0) during a manufacturing process using a concentration (preferably Boron) greater than 1*1014/cm3, then the switching speed (to go in/out of an NDR mode) is on the order of 1 picosecond. Tis concentration of Boron in fact yields a trap density of about 2*1014/cm2 which is more than adequate for significant charge trapping behavior. However, if the charge traps are incorporated instead as a charge trap distribution 132—ie., positioned slightly away from such interface (I.e., about 1 nm into the dielectric as noted at d2) during a manufacturing process then the switching speed is on the order of 1 nanosecond. It will be understood of course that other alternative locations and distributions for the charge traps can be provided for NDR FIT 100, and that locations d1 and d2 are merely representative. Moreover, for some applications it may be desirable to form distributions at more than one general location with different processing steps.
In any event, this mechanism limits the speed at which data can be written into an SRAM cell of the type shown in FIG. 1—I.e., the slower the NDR mechanism, the longer the write access time. From the above it can be seen that the switching speed can be controlled by a factor of 1000 or more simply by adjusting the traps to be distributed in locations 131 or 132.
Nonetheless, the inventor has also noted that one positive side effect of moving the charge traps farther from the semiconductor-insulator interface is that immunity to soft-errors increases concomitantly with the distance. The location of the traps can still be adapted to provide an extremely fast switching speed as may be required for a particular application.
This phenomenon is illustrated basically in the graph of FIG. 3B, which for a particular switching speed (S1) there is a corresponding soft error rate (SER1), and for a lower switching speed (S2) there is a corresponding lower soft error rate (SER2). While the precise relationship between these parameters will vary, it is expected nonetheless that it should be roughly linear as shown, or at least its form easily determinable for any particular set of given process parameters without undue experimentation.
Accordingly, for any particular design and process, both a switching benchmark and an error benchmark can be satisfied through routine modeling and testing. Where it is appropriate, a trade-off between fast write speed and high immunity to soft-errors can be tailored by adjusting the fabrication process to adjust the physical location of the charge traps. The specific location of the traps to achieve a particular SER benchmark and write speed benchmark will vary of course based on geometry, process variations, and desired performance characteristics.
To actually distribute the traps in a particular location and with a particular concentration, the teachings of the aforementioned King et al applications can be used, in which the energy and concentration of an ion implant (preferably Boron) into the channel region are adjusted through any conventional means. For example, an implant of Boron at 20 KeV and at 2 to 3*104/cm2 into channel region 140 results in an acceptable concentration of charge traps into the trapping layer 130 as noted above and with the requisite amount of energy. In a preferred approach, the traps have an energy preferably about 0.5 eV above a conduction band edge of channel 140 so that it is not necessary for the electrons in the channel to be “hot,” but rather only slightly energized, or “warm” to be trapped. This further ensures that they easily de-trapped as well. The traps are incorporated into a channel/dielectric interface region and the bulk of gate dielectric layer 130 through the process of forming the latter using conventional gate oxidation processes as explained in the former King et al application. Thus, by controlling how they are initially implanted into channel region 140, the final distribution and location of the traps is also determined within trapping layer 130.
In another variation, trapping sites are located along only a limited portion of the channel/dielectric layer interface. In other words, the channel implant is masked to ensure that only a portion of dielectric layer 130 (in the horizontal direction parallel to channel 140) includes traps, and thus a trapping mechanism will only occur in such region. Fox some applications for example it may be desirable to have a trapping activity occur closer to a source region than a drain region, as this avoids trapping hot carriers (generated excessively on the drain side) and thus it makes it more easy to control a threshold voltage of NDR FET 100.
Finally, the inventor has discovered that there is another reason why it is desirable to try to keep the traps confined to the channel/dielectric interface region. Namely, if the dopant concentration is too high in gate dielectric layer 130, this can result in unacceptable leakage characteristics. To prevent the traps from achieving a high concentration in the bulk of the remainder of trapping layer 130, a variety of different techniques can be used. For example, a rapid thermal anneal (RTA) step (or an equivalent heat treatment step) tends to mince such diffusion by annealing out implantation induced defects (after the channel region is implanted)1 and thus is preferable for most applications. Thus the traps can be further manipulated and distributed by adjusting a time, temperature, or ramping characteristic of such heat process.
Alternatively the trapping layer 130 can be formed as two separate dielectric layers, such as a deposited SiO2 layer followed by a thermally grown SiO2 layer. Other materials are also possible, of course, including mixtures of SiN, SiON, etc. The traps are then primarily distributed only at the channel interface, within the deposited SiO2 layer and an interface with the thermal SiO2 layer. Yet another v=artion would be to directly implant the charge traps into a particular location and concentration only after channel region 140 and gate dielectric layer 130 are formed.
Other techniques will be apparent to those skilled in the art, and the present invention is not limited by such considerations. Accordingly, the particular details can be determined for any particular architecture and can be implemented in the same in silicon form with conventional techniques known to those skilled in the art such as through routine simulations, process experiments, etc.
Thus for 6-T SRAM technologies below 0.13 um, where soft-error rate is emerging as a very serious problem in embedded applications, this aspect of the invention can be exploited to form embedded soft-error rate optimized SRAMs. Conventional error-correction techniques can also be supplementally employed with such embodiments to bring the overall FIT rate to acceptable levels.
Other embodiments of the same will be apparent from the present teachings, and the present invention is by no means limited to the examples herein. Other supporting structures may also be incorporated within an SRAM cell 105 as operational elements, including NDR diodes. In such instances, only one NDR FET may be used, and only such NDR FET may require trap tailoring.
While the invention has been described with reference to illustrative embodiments, this description is not intended to be construed in a limiting sense. It will be clearly understood by those skilled in the art that foregoing description is merely by way of example and is not a limitation on the scope of the invention, which may be utilized in many types of integrated circuits made with conventional processing technologies. Various modifications and combinations of the illustrative embodiments, as well as other embodiments of the invention, will be apparent to persons skilled in the art upon reference to the description. Such modifications and combinations, of course, may use other features that are already known in lieu of or in addition to what is disclosed herein. It is therefore intended that the appended claims encompass any such modifications or embodiments. While such claims have been formulated based on the particular embodiments described herein, it should be apparent the scope of the disclosure herein also applies to any novel and non-obvious feature (or combination thereof) disclosed explicitly or implicitly to one of skill in the art, regardless of whether such relates to the claims as provided below, and whether or not it solves and/or mitigates all of the same technical problems described above. Finally, the applicants further reserve the right to pursue new and/or additional claims directed to any such novel and non-obvious features during the prosecution of the present application (and/or any related applications).

## Claims

1. A memory device comprising:
a first negative differential resistance (NDR) field effect transistor (FET) coupled to a storage node and a first voltage potential, wherein said first NDR FET is adapted to operate with a first NDR characteristic between said storage node and said first voltage potential; and 
said first NDR FET having a first gate terminal coupled to a first voltage bias that is adapted to switch said first NDR FET; 
a second NDR FET coupled to said first NDR FET, said storage node and a second voltage potential wherein said second NDR FET is adapted to operate with a second NDR characteristic between said storage node and said second voltage potential; 
said second NDR FET having a second gate terminal coupled to a second voltage bias that is adapted to switch said second NDR FET; 
a transfer field effect transistor (FET), coupled to said first NDR FET and second NDR FET, and adapted for transferring data to and from said storage node; 
said first NDR FET and said second NDR FET both including a trap layer in which charge traps are used to effectuate said first NDR characteristic and said second NDR characteristics; 
wherein said charge traps are distributed so as to cause the memory device to achieve a soft error rate (SER) of approximately 1,000 failures-in-time (FITs)/Mbit or less.

2. The memory device of claim 1, wherein said first voltage bias and said second voltage bias are the same.

3. The memory device of claim 1, wherein said charge traps are formed from a p-type impurity such as Boron.

4. The memory device of claim 1, wherein a switching speed of the device can be reduced to further reduce said SER.

5. The memory device of claim 1, wherein said charge traps are formed along only limited regions of said charge trap layer adjoining channels of said first NDR FET and said second NDR FET.

6. The memory device of claim 1, wherein multiple charge trap distributions are used in said charge trap layer.

7. The memory device of claim 1, wherein said first NDR FET and said second NDR FET are located on a silicon on insulator (SOD substrate.

8. The memory device of claim 1, wherein said charge traps have a concentration of about 1 to 5*1014 atoms/cm2 near an interface with channels of said respective first NDR FET and said second NDR FET.

9. The memory cell of claim 1, wherein said trapping layer is comprised of two separate layers, including a first dielectric layer with a high concentration of said charge traps, and a second dielectric layer with a substantially smaller concentration of said charge traps.

10. The memory device of claim 1, wherein the memory device is embedded within a system on chip (SOC) device.

11. A memory device comprising:
a first negative differential resistance (NDR) field effect transistor (FET) coupled to a storage node and a first voltage potential, wherein said first NDR FET is adapted to operate with a first NDR characteristic in a first channel region between said storage node and said first voltage potential; and 
said first NDR FET having a first gate terminal coupled to a first voltage bias that is adapted to switch said first NDR FET; 
a second NDR FET coupled to said first NDR FET, said storage node and a second voltage potential wherein said second NDR FET is adapted to operate with a second NDR characteristic in a second channel region between said storage node and said second voltage potential; 
said second NDR FET having a second gate terminal coupled to a second voltage bias that is adapted to switch said second NDR FET; 
a transfer field effect transistor (FET), coupled to said first NDR FET and second NDR FET, and adapted for transferring data to and from said storage node; 
said first NDR FET and said second NDR FET both including a trap layer in which charge traps are used to effectuate said first NDR characteristic and said second NDR characteristics by a combination of charge trapping and de-trapping in said first channel region and second channel region respectively; 
wherein said charge traps are distributed so as to enable said first NDR FET and said second NDR FET to switch to said first NDR characteristic and said second NDR characteristic respectively in about 1 picosecond in response to a drain bias voltage change and so as to cause the memory device to achieve a soft error rate (SER) of approximately 1,000 failures-in-time (FITs)/Mbit or less.

12. The memory device of claim 11, wherein said charge traps are formed by a doping impurity including Boron.

13. The memory device of claim 11, wherein said charge traps have a trap density of approximately 1 to 5*1014 traps/cm2 at a distance of about 0.5 nm from an interface of said trapping layer with said first channel region of said first NDR FET.

14. The memory cell of claim 11, wherein said trapping layer is comprised of two separate layers, including a first dielectric layer with a high concentration of said charge traps, and a second dielectric layer with a substantially smaller concentration of said charge traps.

15. The memory cell of claim 11, wherein said first NDR FET and said second NDR FET are located on a silicon on insulator (SOI) substrate.

16. The memory cell of claim 11, wherein the memory cell is embedded within a system on chip (SOC) device.