EMISSIONS TEST REPORT 

BIG BEND STATION 

FACILITY ID NUMBER: 0570039 

EMISSION UNIT ID NO: -003 

PARTICULATE MATTER, SULFUR DIOXIDE, 

AND, 

VISIBLE EMISSIONS EVALUATION 

August 27, 2008 

Prepared For: 

Tampa Electric Company 

Polk Power Station 

P.O. Box 111 

Tampa, Florida 33601-0111 

Prepared By: 

Tampa Electric Company 

Environmental, Health & Safety 

Air Services Group 

Environmental, Health & Safety 

Air Services Group 

5010 Causeway Boulevard 

Tampa, Florida 33619- 6130 
REPORT CERTIFICATION 

 The sampling and subsequent data entry/reduction detailed in this report 

was conducted at my direction, and I hereby certify that this test report is 

authentic and accurate to the best of my knowledge. 

Signature:__________________________ 

Scott E. Given 

Technician 

Test Team Lead 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

 I have reviewed the test performance, associated quality assurance 

activities, the resultant calculations, and the contents of this report, and certify 

that all project quality objectives have been met. This report is approved for 

submittal. 

Signature:__________________________ 

Raymond A. McDarby, Jr. 

Senior Environmental Technician 

Quality Assurance/Quality Control Specialist 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

 I have reviewed the testing details and results submitted in this report, 

and hereby certify that this test report is authentic and accurate to the best of 

my knowledge. 

Signature:__________________________ 

David A. Smith, QSTI 

Coordinator – Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 
TABLE OF CONTENTS

SECTION PAGE

1.0 INTRODUCTION 1 

2.0 DISCUSSION OF RESULTS 2 

3.0 SOURCE DESCRIPTION/TEST PROCEDURES 4 

4.0 TEST RESULTS 

 PARTICULATE TEST SUMMARY (SOOT BLOWING) 7 

 PARTICULATE TEST SUMMARY (NON-SOOT BLOWING) 8 

 SULFUR DIOXIDE & NITROGRN OXIDES DATA SUMMARY 9 

 VISIBLE EMISSIONS DATA SUMMARY (SOOT BLOWING) 10 

 VISIBLE EMISSIONS DATA SUMMARY (NON-SOOT BLOWING) 11 

 HEAT INPUT AND FUEL CONSUMPTION SUMMARY 12 

5.0 FIGURES 

SAMPLING LOCATION DIAGRAM 14 

APPENDICIES

 A PARTICULTE TEST CALCULATIONS 

 B PARTICULATE LABORATORY ANALYTICAL DATA 

 C BOILER/PRECIPITATOR OPERATIONAL DATA 

 D FUEL ANALYSIS 

 E FIELD DATA SHEETS 

 F SAMPLING EQUIPMENT CALIBRATIONS 

 G CEM DATA 

 H CHAIN OF CUSTODY 

 I TEST PARTICIPANTS 
1 

1.0 INTRODUCTION

On August 27, 2008, the Environmental, Health, & Safety Air Services Group of 

Tampa Electric Company, performed source emission tests at the Big Bend 

Station, Boiler No. 3, emissions unit I.D.# 0570039-003. Testing was conducted 

according to procedures stipulated by the Florida Department of Environmental 

Protection (FDEP) for fossil fuel steam generators, and requirements in Title V 

Permit # 0570039-028-AV. 
2 

2.0 DISCUSSION OF RESULTS

The particulate matter emission rate under sootblowing conditions was derived 

from three United States Environmental Protection Agency (USEPA) Reference 

Method 5-B test runs. The average of the three test runs was 0.02 lb/mmBtu. 

The FDEP allowable emission rate under soot blowing conditions is 0.3 

lb/MMBtu, as listed in condition A.11 (3). 

The particulate matter emission rate under non-sootblowing conditions was 

derived from three USEPA Reference Method 5-B test runs. The average of the 

three test runs was 0.02 lb/MMBtu. The FDEP allowable emission rate under 

non-sootblowing conditions is 0.03 lb/MMBtu, as listed in condition A.7. 

The sulfur dioxide emission rate was determined using data provided by the 

Continuous Emissions Monitoring System’s (CEMS), Data Acquisition and 

Handling System (DAHS). The average emission rate for the test period was 

determined to be 494 lbs/hr. The FDEP allowable emission rate is 3374 lbs/hr, 

based on scenario 3 as listed in condition A.9.e. 

The nitrogen oxide emission rate was determined using data provided by the 

Continuous Emissions Monitoring System’s (CEMS), Data Acquisition and 

Handling System (DAHS). The average emission rate for the test period was 

determined to be 0.07 lbs/mmBtu and 271 lbs/hr. The FDEP Air Construction 

permit (0570039-035-AC) allowable emission rates are 0.12 lb/mmBtu and 494 

lbs/hr, as listed in condition A.16. 

Visible emissions were evaluated using a Teledyne Instruments/Monitor Labs, 

LightHawk 560 transmissometer system (S/N 5600448), during both sootblowing 

and non-sootblowing testing. The 1-hour average opacity under sootblowing 

conditions was 12.7%. The 1-hour average opacity under non-sootblowing 

conditions was 12.7%. The FDEP allowable emission rate is 20%, as listed in 

condition A.6. 
3 

During the tests performed on August 27, 2008, Boiler No. 3 was operated at an 

average heat input rate of 3955 mmBtu/hr and an average load of 395 

megawatts. The average quantity of fuel burned was 170.9 tons per hour. 
4 

3.0 SOURCE DESCRIPTION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM 

coordinates East 361.9 North 3075.0. The common stack 3 (CS003) source 

sampling location consists of a circular stack 28.83 feet in diameter with four 

sample ports located 90 degrees apart on the stack circumference. Upstream 

and downstream gas flow disturbances were determined to be 8.51 and 2.99 

stack diameters from the test ports, respectively. Using these criteria, a total of 

24 sampling points were chosen for particulate sampling, as stipulated in USEPA 

Method 1 – “Sample and Velocity Traverses for Stationary Sources”. A diagram 

of the stack sampling location is included in Figure 1 along with other pertinent 

information on the test site. 

Boiler No. 3 is serviced by an electrostatic precipitator for the control of flyash 

emissions, low NOX burners and a Selective Catalytic Reduction (SCR) system 

for control of nitrogen oxide emissions, and a flue gas desulfurization (FGD) 

system for control of sulfur dioxide emissions. 

During the test the unit combusted a solid fuel matrix comprised of 94% coal, 

4.9% petroleum coke, and 1.1% Polk residual. 

Particulate matter sampling was performed according to USEPA Method 5B 

"Determination of Nonsulfuric Acid Particulate Matter from Stationary Sources". 

Particulate matter was collected on a high purity, borosilicate microfiber filter 

measuring 82mm in diameter. This data is included as Appendix A, and 

summarized on pages 7 (soot blowing conditions), and 8 (non-soot blowing 

conditions) of this report. At the end of run number 2 (non soot blowing run 2) 

the glass elbow used to connect the filter apparatus to the umbilical (located in 

the filter hot box) was discovered to be broken. It was thought that the elbow 

was broken when the probe/hot box assembly was removed from the sampling 

support system at the completion of the run. The sample was submitted for 

analysis. During the analysis the filter returned abnormally low weight gain. 
5 

Subsequent quality assurance/control follow ups and visual inspection of the filter 

indicated that the filter was torn around the edge of the filter. The analysis was 

continued, and is presented with the data from the remaining runs, but was not 

included in the averaging for the non soot blowing test condition. During run 

number 3 (non soot blowing run 3) the probe heater failed during the second 

point of the final port. Rather than risk condensable formation in the rapidly 

cooling probe and possible contamination on the filter, testing was halted at that 

point. It was determined that enough sample volume was collected (31.118 scf), 

and the test run was called complete. 

Diluent gas sampling and analysis was performed according to USEPA Method 3 

"Gas Analysis for Determination of Emission Rate Correction Factor, or Excess 

Air”. Gas analysis was performed on-site using an Orsat analyzer. 

Sulfur Dioxide (SO2), Nitrogen Oxides (NOX), and Carbon Dioxide (CO2) data 

were provided by the Continuous Emissions Monitoring System (CEMS), Data 

Acquisition and Handling System (DAHS). Averages were derived from the time 

frame of 6:42 through 15:46 EST, corresponding to the time frame of the 

particulate matter test. This data is included as Appendix B, and summarized on 

page 8 of this report. 

Visible emissions were assessed using the installed Continuous Opacity Monitor 

(COM) system. This data is summarized on pages 9 (soot blowing conditions), 

and 10 (non-soot blowing conditions). 
6 

4.0 TEST RESULTS
Environmental Services

Air Services Group

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: CS003 - Common Stack 3

Unit Under Test: Boiler # 3

Test Date: August 27, 2008

Operating Conditions: Soot Blowing

Run 1s Run 2s Run 3s Test Average

Vm(std), scf 36.6545 37.5214 36.7616 36.97919

Bws, ratio 0.1595 0.1592 0.1611 0.15996

Md, lb/lb - mole 30.44 30.44 30.44 30.440

Ms, lb/lb - mole 28.46 28.46 28.44 28.450

Qs, acf/min 1289996.3 1322406.3 1294924.7 1302442.4

Qs(std), dscf/min 956317.38 980471.93 957471.11 964753.47

I, % 101.1 101 101.3 101.13

C, lbs/dscf 1.248E-06 1.469E-06 1.415E-06 1.377E-06

ER, lbs/MMBtu 0.016 0.019 0.018 0.02

7 
Environmental Services

Air Services Group

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: CS003 - Common Stack 3

Unit Under Test: Boiler # 3

Test Date: August 27, 2008

Operating Conditions: Non-Soot Blowing

Run 1 Run 2 Run 3 Test Average

Vm(std), scf 36.3431 37.1694 31.1179 34.87677

Bws, ratio 0.1607 0.1588 0.1637 0.16104

Md, lb/lb - mole 30.44 30.44 30.44 30.440

Ms, lb/lb - mole 28.44 28.47 28.40 28.437

Qs, acf/min 1289904.1 1307660.9 1283972.2 1293845.7

Qs(std), dscf/min 955559.27 971200.85 947932.67 958230.93

I, % 100.3 101 103.9 101.73

C, lbs/dscf 1.119E-06 5.249E-07 1.544E-06 1.063E-06

EM, lbs/hr 64.1664 30.5874 87.8415 60.86510

ER, lbs/MMBtu 0.014 0.007 0.020 0.02

Run #2 not included in average. Suspect filter/sampling problem. 

8 
BIG BEND STATION

SULFUR DIOXIDE and NITROGEN OXIDES DATA from CEMs

Test Period Information

Start Time 6:42:00 Eastern Standard Time (EST)

Stop Time 15:46:00 Eastern Standard Time (EST)

Total Time 9:04:00

Corresponding to the time frame for the PM test.

Sulfur Dioxide Data:

RM - 19

SO2 NOX CO2 SO2 SO2 NOX

ppmvw lb/mmBtu %, wet lb/mmBtu lbs/hr lbs/hr

49.0195 0.0686128 11.7448 0.125 494.27 271.36

Calculation Details

SO2, lb/mmBtu = SO2, ppmvw x Cf x Fc x (100 / CO2 %, wet)

where:

Cf = 1.6635E-07 (lb/scf)/ppm SO2

Fc = 1800 scf/mmBtu

SO2, lbs/hr = SO2, lb/mmBtu x Heat Input, mmBtu/hr

NOX, lbs/hr = NOX, lb/mmBtu x Heat Input, mmBtu/hr

where:

Heat Input = 3955 mmBtu/hr, from Heat Input Calculation

Boiler #3

WET-BOTTOM UTILITY BOILER

August 27, 2008

CEM DATA

9 
BIG BEND STATION

VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY3 Record# DATE TIME OPACITY3

1 08/27/08 12:04 11.290 31 08/27/08 12:34 11.390

2 08/27/08 12:05 12.110 32 08/27/08 12:35 24.240

3 08/27/08 12:06 13.010 33 08/27/08 12:36 18.930

4 08/27/08 12:07 11.950 34 08/27/08 12:37 13.780

5 08/27/08 12:08 12.800 35 08/27/08 12:38 15.030

6 08/27/08 12:09 13.910 36 08/27/08 12:39 23.160

7 08/27/08 12:10 10.460 37 08/27/08 12:40 14.350

8 08/27/08 12:11 9.690 38 08/27/08 12:41 12.140

9 08/27/08 12:12 14.030 39 08/27/08 12:42 11.570

10 08/27/08 12:13 11.160 40 08/27/08 12:43 10.150

11 08/27/08 12:14 9.600 41 08/27/08 12:44 10.020

12 08/27/08 12:15 10.400 42 08/27/08 12:45 10.740

13 08/27/08 12:16 14.690 43 08/27/08 12:46 9.910

14 08/27/08 12:17 14.550 44 08/27/08 12:47 10.320

15 08/27/08 12:18 18.270 45 08/27/08 12:48 10.150

16 08/27/08 12:19 15.890 46 08/27/08 12:49 11.120

17 08/27/08 12:20 10.900 47 08/27/08 12:50 14.060

18 08/27/08 12:21 12.430 48 08/27/08 12:51 11.840

19 08/27/08 12:22 15.460 49 08/27/08 12:52 11.950

20 08/27/08 12:23 10.360 50 08/27/08 12:53 10.860

21 08/27/08 12:24 9.630 51 08/27/08 12:54 10.580

22 08/27/08 12:25 11.460 52 08/27/08 12:55 9.300

23 08/27/08 12:26 11.290 53 08/27/08 12:56 8.810

24 08/27/08 12:27 13.700 54 08/27/08 12:57 10.750

25 08/27/08 12:28 11.590 55 08/27/08 12:58 9.550

26 08/27/08 12:29 11.790 56 08/27/08 12:59 12.490

27 08/27/08 12:30 10.650 57 08/27/08 13:00 15.660

28 08/27/08 12:31 13.880 58 08/27/08 13:01 13.590

29 08/27/08 12:32 14.860 59 08/27/08 13:02 14.740

30 08/27/08 12:33 11.960 60 08/27/08 13:03 14.780

Test Average: 12.662 %

Minimum One Minute Average: 8.810 %

Maximum One Minute Average: 24.240 %

Maximum Six Minute Average: 18.248 %

Boiler #3

WET BOTTOM UTILITY BOILER

SOOTBLOWING CONDITIONS

10 
BIG BEND STATION

VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY3 Record# DATE TIME OPACITY3

1 08/27/08 10:05 14.750 31 08/27/08 10:35 10.540

2 08/27/08 10:06 11.380 32 08/27/08 10:36 11.300

3 08/27/08 10:07 10.300 33 08/27/08 10:37 12.080

4 08/27/08 10:08 9.480 34 08/27/08 10:38 12.950

5 08/27/08 10:09 11.010 35 08/27/08 10:39 11.160

6 08/27/08 10:10 15.370 36 08/27/08 10:40 13.410

7 08/27/08 10:11 14.260 37 08/27/08 10:41 10.820

8 08/27/08 10:12 17.700 38 08/27/08 10:42 14.310

9 08/27/08 10:13 12.900 39 08/27/08 10:43 25.870

10 08/27/08 10:14 11.410 40 08/27/08 10:44 18.470

11 08/27/08 10:15 13.580 41 08/27/08 10:45 13.910

12 08/27/08 10:16 12.320 42 08/27/08 10:46 12.380

13 08/27/08 10:17 12.090 43 08/27/08 10:47 11.500

14 08/27/08 10:18 10.340 44 08/27/08 10:48 11.080

15 08/27/08 10:19 9.330 45 08/27/08 10:49 11.860

16 08/27/08 10:20 14.020 46 08/27/08 10:50 13.900

17 08/27/08 10:21 11.840 47 08/27/08 10:51 11.590

18 08/27/08 10:22 10.820 48 08/27/08 10:52 9.980

19 08/27/08 10:23 10.030 49 08/27/08 10:53 12.870

20 08/27/08 10:24 9.170 50 08/27/08 10:54 17.060

21 08/27/08 10:25 11.800 51 08/27/08 10:55 12.660

22 08/27/08 10:26 17.110 52 08/27/08 10:56 10.060

23 08/27/08 10:27 17.450 53 08/27/08 10:57 12.810

24 08/27/08 10:28 12.600 54 08/27/08 10:58 14.630

25 08/27/08 10:29 10.620 55 08/27/08 10:59 11.780

26 08/27/08 10:30 12.790 56 08/27/08 11:00 10.820

27 08/27/08 10:31 10.160 57 08/27/08 11:01 12.570

28 08/27/08 10:32 14.260 58 08/27/08 11:02 10.060

29 08/27/08 10:33 17.090 59 08/27/08 11:03 10.820

30 08/27/08 10:34 11.960 60 08/27/08 11:04 10.050

Test Average: 12.687 %

Minimum One Minute Average: 9.170 %

Maximum One Minute Average: 25.870 %

Maximum Six Minute Average: 16.132 %

Boiler #3

WET BOTTOM UTILITY BOILER

NON-SOOTBLOWING CONDITIONS

11 
BIG BEND GENERATING STATION

HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (July): 10014 KMBtu/MWh

1.0014E+07 MMBtu/MWh

Testing Start Time: 6:42

Testing End Time: 15:46

Total Test Time: 9.07 hours

Average Unit Load, MWe: 394.9 MW

Heat Input, MMBtu/h = MMBtu/MWh x MWe: 3954.5 mmBtu/hr

Laboratory Sample ID: AA96809

Btu as received: 11571 Btu/lb

Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 170.9 Tons/hour

Calculated Heat Input

Fuel Consumption Calculation

Unit # 3

WET BOTTOM UTILITY BOILER

August 27, 2008

Test Time Information

12 
13 

5.0 FIGURES
FIGURE 1 

EXHAUST STACK 

245 FT. 

 BIG BEND STATION 

PARTICULATE TRAVERSE POINTS 

OUTLET 

N

A

B C 

D 

PORT LOCATION 

REVISED 12-31-96 

BOILER NO. 3 TEST LOCATION 

STACK DIAMETERS DOWNSTREAM 

FROM DISTURBANCE = 3.0 

STACK DIAMETERS UPSTREAM 

FROM DISTURBANCE = 8.5 

STACK DIAMETER = 28.8333 FT. 

STACK AREA = 652.948 SQ. 

PORT LENGTH’S = 14 IN. 

TRAVERSE 

 POINT 

 1 

 2 

 3 

 4 

 5 

 6 

 % OF 

STACK DIAMETER 

 IN. FROM 

STACK WALL 

 2.1% 

 6.7% 

11.8% 

17.7% 

25.0% 

35.6% 

 7.27 IN. 

 23.18 IN. 

 40.83 IN. 

 61.24 IN. 

 86.50 IN. 

123.18 IN. 

499 FT. 

254 FT. 

168 FT. 

86 FT. 

FGD 

PRESSURIZED 

 ANNULUS 

14 
APPENDIX A 

PARTICULTE TEST CALCULATIONS 
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Big Bend 3 Stack

Unit Under Test: Boiler # 3

Operating Conditions: Soot Blowing

Run Number: 1s

Date:

Sample Time, θ: 60 minutes Nozzle Diameter, Dn: 0.275 inches

Barometric Pressure, Pb: 29.72 "Hg Nozzle Area, An: 0.000412 ft2

Stack Pressure, Ps: 29.64 "Hg Average Orifice Meter, ΔH: 1.272 "H2O

Effective Stack Area, As: 652.948 ft2 Sample Volume, Vm: 39.292 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 97.2 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 133.0 o

F

5.0 % O2 Average √Δp: 0.547 "H2O

0.0 % CO Condensate Volume, Vlc: 147.6 ml

81.0 % N2 Meter Box Y: 0.988 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 6.958 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 36.655 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.160 %

FDA = 1.0 - Bws 0.840 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.46 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 32.93 ft/second

Qs = vs x As x 60 1289996.3 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 956317.4 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 101.1 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.02075 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.009 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.006 grains/acf

C = cs / 7000 1.248E-06 lbs/dscf

EM = C x Qs(std) x 60 71.6 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.016 lbs/MMBtu

08/27/2008
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Big Bend 3 Stack

Unit Under Test: Boiler # 3

Operating Conditions: Soot Blowing

Run Number: 2s

Date:

Sample Time, θ: 60 minutes Nozzle Diameter, Dn: 0.275 inches

Barometric Pressure, Pb: 29.75 "Hg Nozzle Area, An: 0.000412 ft2

Stack Pressure, Ps: 29.67 "Hg Average Orifice Meter, ΔH: 1.346 "H2O

Effective Stack Area, As: 652.948 ft2 Sample Volume, Vm: 40.525 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 102.1 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 133.8 o

F

5.0 % O2 Average √Δp: 0.561 "H2O

0.0 % CO Condensate Volume, Vlc: 150.7 ml

81.0 % N2 Meter Box Y: 0.988 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 7.104 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 37.521 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.159 %

FDA = 1.0 - Bws 0.841 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.46 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 33.75 ft/second

Qs = vs x As x 60 1322406.3 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 980471.9 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 101.0 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.02500 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.010 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.008 grains/acf

C = cs / 7000 1.469E-06 lbs/dscf

EM = C x Qs(std) x 60 86.4 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.019 lbs/MMBtu

08/27/2008
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Big Bend 3 Stack

Unit Under Test: Boiler # 3

Operating Conditions: Soot Blowing

Run Number: 3s

Date:

Sample Time, θ: 60 minutes Nozzle Diameter, Dn: 0.275 inches

Barometric Pressure, Pb: 29.75 "Hg Nozzle Area, An: 0.000412 ft2

Stack Pressure, Ps: 29.67 "Hg Average Orifice Meter, ΔH: 1.294 "H2O

Effective Stack Area, As: 652.948 ft2 Sample Volume, Vm: 39.900 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 103.3 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 134.0 o

F

5.0 % O2 Average √Δp: 0.549 "H2O

0.0 % CO Condensate Volume, Vlc: 149.8 ml

81.0 % N2 Meter Box Y: 0.988 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 7.062 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 36.762 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.161 %

FDA = 1.0 - Bws 0.839 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.44 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 33.05 ft/second

Qs = vs x As x 60 1294924.7 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 957471.1 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 101.3 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.02360 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.010 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.007 grains/acf

C = cs / 7000 1.415E-06 lbs/dscf

EM = C x Qs(std) x 60 81.3 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.018 lbs/MMBtu

08/27/2008
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Big Bend 3 Stack

Unit Under Test: Boiler # 3

Operating Conditions: Non-Soot Blowing

Run Number: 1

Date:

Sample Time, θ: 60 minutes Nozzle Diameter, Dn: 0.275 inches

Barometric Pressure, Pb: 29.74 "Hg Nozzle Area, An: 0.000412 ft2

Stack Pressure, Ps: 29.66 "Hg Average Orifice Meter, ΔH: 1.272 "H2O

Effective Stack Area, As: 652.948 ft2 Sample Volume, Vm: 38.932 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 97.2 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 133.0 o

F

5.0 % O2 Average √Δp: 0.547 "H2O

0.0 % CO Condensate Volume, Vlc: 147.6 ml

81.0 % N2 Meter Box Y: 0.988 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 6.958 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 36.343 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.161 %

FDA = 1.0 - Bws 0.839 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.44 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 32.93 ft/second

Qs = vs x As x 60 1289904.1 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 955559.3 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.3 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01845 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.008 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.006 grains/acf

C = cs / 7000 1.119E-06 lbs/dscf

EM = C x Qs(std) x 60 64.2 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.014 lbs/MMBtu

08/27/2008
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Big Bend 3 Stack

Unit Under Test: Boiler # 3

Operating Conditions: Non-Soot Blowing

Run Number: 2

Date:

Sample Time, θ: 60 minutes Nozzle Diameter, Dn: 0.275 inches

Barometric Pressure, Pb: 29.75 "Hg Nozzle Area, An: 0.000412 ft2

Stack Pressure, Ps: 29.67 "Hg Average Orifice Meter, ΔH: 1.317 "H2O

Effective Stack Area, As: 652.948 ft2 Sample Volume, Vm: 39.984 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 99.8 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 133.0 o

F

5.0 % O2 Average √Δp: 0.555 "H2O

0.0 % CO Condensate Volume, Vlc: 148.8 ml

81.0 % N2 Meter Box Y: 0.988 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 7.014 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 37.169 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.159 %

FDA = 1.0 - Bws 0.841 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.47 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 33.38 ft/second

Qs = vs x As x 60 1307660.9 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 971200.9 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 101.0 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.00885 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.004 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.003 grains/acf

C = cs / 7000 5.249E-07 lbs/dscf

EM = C x Qs(std) x 60 30.6 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.007 lbs/MMBtu

08/27/2008
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Big Bend 3 Stack

Unit Under Test: Boiler # 3

Operating Conditions: Non-Soot Blowing

Run Number: 3

Date:

Sample Time, θ: 50 minutes Nozzle Diameter, Dn: 0.275 inches

Barometric Pressure, Pb: 29.75 "Hg Nozzle Area, An: 0.000412 ft2

Stack Pressure, Ps: 29.67 "Hg Average Orifice Meter, ΔH: 1.269 "H2O

Effective Stack Area, As: 652.948 ft2 Sample Volume, Vm: 33.670 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 103.0 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 133.1 o

F

5.0 % O2 Average √Δp: 0.544 "H2O

0.0 % CO Condensate Volume, Vlc: 129.2 ml

81.0 % N2 Meter Box Y: 0.988 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 6.090 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 31.118 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.164 %

FDA = 1.0 - Bws 0.836 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.40 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 32.77 ft/second

Qs = vs x As x 60 1283972.2 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 947932.7 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 103.9 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.02180 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.0108 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.0080 grains/acf

C = cs / 7000 1.544E-06 lbs/dscf

EM = C x Qs(std) x 60 87.8 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.020 lbs/MMBtu

08/27/2008
APPENDIX B 

PARTICULATE LABORATORY ANALYTICAL DATA 
Customer AIR SERVICES Plant BIG BEND Unit 3

Method 5B Stack Test Completion Date 08/27/2008Analyst SS/PP Sample Number AA96809

ACETONE BEAKER 1st weighing Date 08/30/2008 Time 15:20 % RH 42.5%

2nd weighing Date 09/02/2008 Time 10:10 % RH 42.0%

3rd weighing Date 09/02/2008 Time 16:25 % RH 42.0%

4th weighing Date 09/03/2008 Time 9:45 % RH 41.5%

***Blank*** Run 1 Run 2 Run 3 Run 1S Run 2S Run 3S

Acetone Container ID AIR 16 AIR 55 AIR 45 AIR IE AIR IK AIR J2 AIR 69

Acetone Rinse Vol.(Va), mls 200.0000 200 200 200 200 200 200

1st Gross Wt., grams 105.2284 107.4931 107.9505 106.2436 97.4682 101.3388 105.1094

2nd Gross Wt., grams 105.1908 107.4895 107.9439 106.2413 97.4627 101.3367 105.1078

3rd Gross Wt., grams 105.1903 107.4886 107.9435 106.2410 97.4617 101.3351 105.1076

4th Gross Wt., grams 105.1903 107.4885 97.4619 101.3354

Avg. Gross Wt., grams 105.19055 107.48855 107.94370 106.24115 97.46180 101.33525 105.10770

Tare Wt., grams 105.18980 107.48225 107.93890 106.23350 97.45315 101.32515 105.09805

Acetone Blank Wt., mg 0.75 0.75 0.75 0.75 0.75 0.75 0.75

Acetone Particulate Wt., mg 5.55 4.05 6.90 7.90 9.35 8.90

Acetone Residue, mg/g 0.0047

Acetone Blank Criteria

 FILTER 1st weighing Date 08/29/2008 Time 15:30 % RH 41.0%

 Date 08/30/2008 Time 7:30 % RH 42.0%

3rd weighing Date 08/30/2008 Time 15:20 % RH 42.5%

4th weighing Date 09/02/2008 Time 10:10 % RH 42.0%

Filter/Thimble ID 203133 203125 203126 203124 203131 203128 203132

1st Gross Wt., grams 0.2461 0.2619 0.2549 0.2655 0.2626 0.2659 0.2648

2nd Gross Wt., grams 0.2463 0.2625 0.2555 0.2651 0.2622 0.2661 0.2645

3rd Gross Wt., grams 0.2460 0.2624 0.2553 0.2651 0.2625 0.2672 0.2651

4th Gross Wt., grams 0.2461 0.2628 0.2551 0.2649 0.2624 0.2674 0.2647

Avg. Gross Wt., grams 0.24620 0.26245 0.25540 0.26530 0.26240 0.26600 0.26465

Tare Wt., grams 0.24600 0.24955 0.25060 0.25040 0.24955 0.25035 0.24995

Filter Particulate Wt., mg 0.20 12.90 4.80 14.90 12.85 15.65 14.70

Difference, milligrams

Total Sample Particulate Wt., mg 18.45 8.85 21.80 20.75 25.00 23.60

OK to subtract acetone blank

Start Here
APPENDIX C 

BOILER/PRECIPITATOR OPERATIONAL DATA 



APPENDIX D 

FUEL ANALYSIS 
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Report For:

Laboratory ID: AA96809

Date and Time Collected:

Sampled By:

Sample Information

Description: GEROLD HAYDEN

Location Code:

Report Date: 09/24/08

Big Bend 3 Compliance

TE_BB_3_COMP_COAL

Project Account Code:

Sample Collection Method: Date of Sample Receipt: 09/02/08

Laboratory Results

08/27/08 3:00:00 PM

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 4.15 09/10/08 8:56:00 AM

Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 10.24 09/10/08 8:56:00 AM

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 9.50 09/10/08 3:22:00 PM

Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 10.68 09/10/08 3:22:00 PM

BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 12463 09/10/08 9:29:00 AM

BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 11571 09/10/08 3:39:00 PM

BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 13003 09/10/08 3:39:00 PM

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14558 09/10/08 3:39:00 PM

Calculated Heat Input, mmBtu/hr mmBtu/hr KARAM 3955 09/23/08 9:33:00 AM

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 5.55 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 4.05 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 6.90 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Acetone Beaker, Run 4 mg 0.0001 7.90 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Acetone Beaker, Run 5 mg 0.0001 9.35 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Acetone Beaker, Run 6 mg 0.0001 8.90 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 12.90 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 4.80 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 14.90 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Filter/Thimble, Run 4 mg 0.0001 12.85 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Filter/Thimble, Run 5 mg 0.0001 15.65 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Filter/Thimble, Run 6 mg 0.0001 14.70 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Total Sample, Run 1 mg 0.0001 18.45 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Total Sample, Run 2 mg 0.0001 8.85 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Total Sample, Run 3 mg 0.0001 21.80 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Total Sample, Run 4 mg 0.0001 20.75 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Total Sample, Run 5 mg 0.0001 25.00 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

Particulate Wt., Total Sample, Run 6 mg 0.0001 23.60 09/04/08 8:55:00 AM EPA Method 5B/17 KARAM

PM non-sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.02 09/23/08 9:33:00 AM

Report Number: Page 1 of 2 "General Report" AA96809-092408-09
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

PM sootblowing, lbs/mmBtu 0.02 09/23/08 9:33:00 AM lb/mmBtu EPA RM-5/17 KARAM

Pounds SO2 / Million BTU Lbs. 

SO2/MMBTU

5.09 09/10/08 3:39:00 PM Calculated KAPXJ

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KARAM 494.3 09/23/08 9:33:00 AM

Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 3.34 09/10/08 10:27:00 AM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 3.10 09/10/08 3:22:00 PM

Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.48 09/10/08 3:22:00 PM

Total Moisture % 0.1 ASTM D-3173 KAPXJ 11.01 09/10/08 3:22:00 PM

Comments

Designee for Peggy Penner,

Manager, Laboratory Services

All results calculated on a wet to wet basis, unless otherwise indicated.

#3 Stack Test

Should there be any questions regarding this report, please contact:

(813) 630-7490

Ellen Demers,

Report Number: Page 2 of 2 "General Report" AA96809-092408-09
APPENDIX E 

FIELD DATA SHEETS 






APPENDIX F 

SAMPLING EQUIPMENT CALIBRATIONS 
Environmental, Health, & Safety

Air Services Group

SUMMARY OF EQUIPMENT CALIBRATIONS

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 07)

INITIAL 08/22/2008 USEPA RM 5 0.988

POST TEST 09/04/2008 (ORIFICE) 0.980

NOZZLE (SN 09)

INITIAL CALIPER 0.275

POST TEST 09/04/2008 MEASUREMENTS 0.275

PYROMETER (PY 09) 08/21/2008 ASTM THERMOMETER + 2o

 F

PITOT TUBE (PT 10) 08/21/2008 USEPA RM 2 Cp = 0.84

BAROMETER (BR 07) 08/11/2008 NWS COMPARISON + 0.01" Hg
Environmental Services

Air Services Group

Blue Team

Manufacturer: Thermo Anderson Calibration Date:

Model Number:MST-C1 Barometric Pressure: 29.82 "Hg

Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.07 "Hg

LabWorks Sample Number: Calibrated By:

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

0.60 15 623.800 630.760 6.960 79 78 79 78

1.15 15 632.600 641.846 9.246 80 77 81 78

1.90 15 644.500 656.366 11.866 82 78 83 79

3.50 15 574.200 590.272 16.072 86 74 87 75

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

48 0.3448 22.0 72 72 72.0

55 0.4593 20.5 72 72 72.0

63 0.5917 18.5 72 72 72.0

73 0.8101 16.0 72 72 72.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.809 6.687 6.763 0.982 -0.006 1.660 -0.084

9.049 8.907 9.008 0.984 -0.003 1.791 0.047

11.602 11.475 11.605 0.989 0.001 1.778 0.034

15.777 15.710 15.889 0.996 0.008 1.747 0.003

Averages: 0.988 1.744

Review/Approval:

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

Quarterly Calibration

08/22/2008

GDB

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

The Critical Orifice Coefficient, K', should be in English units.

IMPORTANT

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

25-Aug-08

Critical Orifice Readings

Ambient Temperatures

CALCULATED DATA

Critical Orifice
Environmental Services

Air Services Group

Manufacturer: Thermo Andersen Calibration Date:

Model Number:MST-C1 Barometric Pressure: 29.8 "Hg

Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.06 "Hg

LabWorks Sample Number: Calibrated By:

Associated Test: Team: BLUE

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

1.15 10 61.510 67.680 6.170 75 77 76 76

1.15 10 67.680 73.840 6.160 76 77 77 75

1.15 10 73.840 79.978 6.138 77 75 77 75

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

55 0.4593 20.0 72 72 72.0

55 0.4593 20.0 72 72 72.0

55 0.4593 20.0 72 72 72.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.068 5.934 6.006 0.978 -0.002 1.802 0.000

6.056 5.934 6.006 0.980 0.000 1.801 -0.001

6.037 5.934 6.006 0.983 0.003 1.802 0.000

Averages: 0.980 1.802

Prior Y: 0.988

% Difference:(+/-5%) 0.78% PASS

Review/Approval: Date: 5-Sep-08

CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

Critical Orifice

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

GDB/RN

09/04/2008

POST - TEST CALIBRATION CHECK

Ambient Temperatures

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

Critical Orifice Readings

IMPORTANT

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

The Critical Orifice Coefficient, K', should be in English units.
Environmental Services

Air Services Group

Shared Resource

Calibration Date: Responsible Party:

Nozzle Maximum Average

I.D. D1 D2 D3 Difference, " Dn, inches

^SN01 0.286 0.287 0.289 0.001 0.113

^SN04 0.312 0.315 0.314 0.001 0.123

^SN05 0.376 0.376 0.380 0.002 0.149

^SN06 0.496 0.497 0.497 0.000 0.196

^SN09 0.698 0.702 0.699 0.002 0.275

^SN10 0.753 0.748 0.750 0.002 0.295

^SN12 0.990 0.989 0.991 0.001 0.390

^SN15 0.415 0.412 0.417 0.002 0.163

^SN16 0.490 0.491 0.493 0.001 0.193

^SN19 0.710 0.706 0.711 0.002 0.279

^SN22 0.934 0.938 0.942 0.003 0.369

^SN30 0.791 0.790 0.790 0.000 0.311

^SN36 0.470 0.471 0.473 0.001 0.186

^SN37 0.525 0.525 0.524 0.000 0.207

^SN38 0.640 0.641 0.636 0.002 0.252

^SN46 0.478 0.476 0.473 0.002 0.187

^SN47 0.513 0.513 0.515 0.001 0.202

^SN48 0.633 0.635 0.636 0.001 0.250

^SN50 0.689 0.690 0.687 0.001 0.271

^SN58 0.615 0.618 0.620 0.002 0.243

^SN68 0.623 0.623 0.631 0.003 0.246

^SN69 0.950 0.950 0.950 0.000 0.374

^SN70 1.560 1.562 1.565 0.002 0.615

^SN71 1.562 1.567 1.565 0.002 0.616

^SN72 0.951 0.956 0.953 0.002 0.375

^SN73 1.275 1.273 1.273 0.001 0.501

^SN74 1.232 1.235 1.228 0.003 0.485

Data Notations: All micometer readings are converted from cm to inches by multiplying by

0.393700787. Maximum Difference must be < 0.004".

QA/QC Review by:

25-Aug-08

Nozzle Diameter, Dn (cm)

QUARTERLY NOZZLE CALIBRATIONS

STEEL NOZZLE SET

08/21/2008 RJN
Environmental Services

Air Services Group

Shared Resource

Calibration Date:

Calibration Personnel:

Test Designation:

Maximum Average

D1 D2 D3 Difference, " Dn, inches

0.275 0.277 0.274 0.003 0.275

Data Notations: 

Maximum Difference must be < 0.004".

Quarterly (pre-test) value for nozzle ID SN-09 was 0.275

Difference (Pre-test/Post-test) is: 0.000 PASS

QA/QC Review by: 5-Sep-08

SN-09

POST TEST NOZZLE CALIBRATION 

Nozzle

Identifier

Nozzle Diameter, Dn (in)

09/04/2008

GDB/RN

BB#3 Compliance
Environmental Services

Air Services Group

Blue Team

Pyrometer Under Test

Pyrometer Number: ^PY09

Labworks Sample #

Calibration Date: 08/21/2008

Calibrator Information

Calibrator Type/Manufacturer: Hart Scientific

Calibrator Serial Number: AOA024

Date of Last Calibration: 04/28/2008

Calibration Personnel (Typed and Signature):

Calibration Data

Calibration Reference Pyrometer

Point Temperature Indication Difference

1 400 402 -2

2 212 215 -3

3 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points

should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit.

Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration

Point Difference

1 Pass

2 Pass

3 Pass

Reviewer:

SEG-RN

SEG-RN

Pyrometer Calibration

22-Aug-08
Environmental Services

Air Services Group

Pitot Tube ID #

Calibration Date Operating Quarter/Year: 3-08

Openings Damaged? ___ Y ___N Repaired? ____Y ___ N ___ N/A

Labworks #:

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0 degrees Dt 0.48 < Dt > 0.95 cm

α 2 0.6 degrees α < 10 degrees

β 1 1.4 degrees

β 2 1.3 degrees

β1 < 5 degrees (alongside top impact openings)

Gamma, Theta, Α, Ζ, and W Determinationsβ2 < 5 degrees (alongside bottom impact openings)

ψ 0.5 degrees Ζ < 0.32 cm (Αsinψ)

Α 2.43 cm W < 0.08 cm (Asinο)

Ζ 0.021 cm Α distance between tips

ο angle of plane on side of pitots

ο 0.1 degrees ψ angle between tips

W 0.004 cm

Comments:

Calibrated by:

Quality Assurance Review / Approval:

Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, 

Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement

details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems:

Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

22-Aug-08

Pass

0

Pass (α2 measured across bottom impact openings)

REMOVABLE

Pass

Pass

Pass (α1 measured across top impact openings)

PITOT TUBE CALIBRATION

DATA SHEET

PT10

08/21/2008 Shared Resource
Environmental Services

Air Services Group

Blue Team

Instrument Number:

Calibration Date:

Calibration Personnel:

Labworks #:

Difference

Time "Hg

9:00 -0.06

10:30 -0.05

11:30 -0.01

Average Difference: -0.04

Note: Barometric readings must agree within ± 0.1 "Hg.

Current Reference is National Weather Service, TIA.

Comments (Note any adjustments):

QA/QC Review by: Date: 12-Aug-08

Current Conditions at Tampa International Airport

29.95 29.96

29.90 29.96

29.92 29.97

Barometer Reading Reference Reading

Inches Mercury Inches Mercury

BAROMETER CALIBRATION

^BR07

08/11/2008

SEG
APPENDIX G 

DAILY SULFUR DIOXIDE DATA SUMMARY 
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 6:42 11.83 68.9 0.067

08/27/2008 6:43 11.79 74.8 0.071

08/27/2008 6:44 11.92 79.9 0.071

08/27/2008 6:45 11.95 82.9 0.067

08/27/2008 6:46 11.89 89.6 0.066

08/27/2008 6:47 11.96 97.5 0.064

08/27/2008 6:48 11.84 92.5 0.064

08/27/2008 6:49 11.64 90.6 0.071

08/27/2008 6:50 11.87 102.2 0.074

08/27/2008 6:51 12.09 105.8 0.069

08/27/2008 6:52 11.86 94.9 0.068

08/27/2008 6:53 11.71 87 0.07

08/27/2008 6:54 11.77 89.6 0.074

08/27/2008 6:55 11.84 80.3 0.075

08/27/2008 6:56 11.92 72.7 0.073

08/27/2008 6:57 11.89 70.4 0.071

08/27/2008 6:58 11.72 74.3 0.076

08/27/2008 6:59 11.84 81.1 0.077

08/27/2008 7:00 11.78 83.7 0.076

08/27/2008 7:01 11.75 91.5 0.079

08/27/2008 7:02 11.91 94.4 0.078

08/27/2008 7:03 11.85 91.9 0.076

08/27/2008 7:04 11.84 89.9 0.079

08/27/2008 7:05 11.82 73.7 0.075

08/27/2008 7:06 11.73 59.8 0.075

08/27/2008 7:07 11.72 52.5 0.078

08/27/2008 7:08 11.69 52 0.081

08/27/2008 7:09 11.9 58.1 0.08

08/27/2008 7:10 11.93 60.8 0.074

08/27/2008 7:11 11.81 63.9 0.073

08/27/2008 7:12 11.81 67.9 0.073

08/27/2008 7:13 11.78 70 0.073

08/27/2008 7:14 11.78 76 0.073

08/27/2008 7:15 11.81 81.4 0.074

08/27/2008 7:16 11.84 86.7 0.073

08/27/2008 7:17 11.85 89.9 0.071

08/27/2008 7:18 11.85 95 0.067

08/27/2008 7:19 11.7 96.9 0.07

08/27/2008 7:20 11.75 103.4 0.073

08/27/2008 7:21 11.86 102.6 0.073

Page 1 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 7:22 11.87 87.9 0.071

08/27/2008 7:23 11.76 75.4 0.068

08/27/2008 7:24 11.67 70.9 0.068

08/27/2008 7:25 11.69 70.2 0.07

08/27/2008 7:26 11.78 72.1 0.071

08/27/2008 7:27 11.79 78.5 0.074

08/27/2008 7:28 11.74 81.4 0.075

08/27/2008 7:29 11.91 88.5 0.075

08/27/2008 7:30 11.95 92.5 0.074

08/27/2008 7:31 11.82 91.6 0.076

08/27/2008 7:32 11.66 85.2 0.079

08/27/2008 7:33 11.69 85 0.08

08/27/2008 7:34 11.89 88.4 0.081

08/27/2008 7:35 11.89 78.2 0.082

08/27/2008 7:36 11.83 67.3 0.08

08/27/2008 7:37 11.79 61.4 0.08

08/27/2008 7:38 11.74 57.9 0.082

08/27/2008 7:39 11.66 55.8 0.085

08/27/2008 7:40 11.8 58.6 0.081

08/27/2008 7:41 11.91 59 0.074

08/27/2008 7:42 11.73 59.8 0.075

08/27/2008 7:43 11.64 59.4 0.078

08/27/2008 7:44 11.65 60.8 0.079

08/27/2008 7:45 11.7 69.2 0.083

08/27/2008 7:46 11.91 70.9 0.076

08/27/2008 7:47 11.73 68.7 0.076

08/27/2008 7:48 11.66 73.5 0.078

08/27/2008 7:49 11.87 79.3 0.073

08/27/2008 7:50 11.62 68.4 0.072

08/27/2008 7:51 11.56 67.4 0.075

08/27/2008 7:52 11.76 72.6 0.076

08/27/2008 7:53 11.69 71.9 0.076

08/27/2008 7:54 11.67 71.7 0.075

08/27/2008 7:55 11.86 67.1 0.075

08/27/2008 7:56 11.81 61.4 0.076

08/27/2008 7:57 11.65 59.5 0.078

08/27/2008 7:58 11.72 62.2 0.075

08/27/2008 7:59 11.81 70.6 0.076

08/27/2008 8:00 11.89 73.2 0.077

08/27/2008 8:01 11.78 77.6 0.074

Page 2 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 8:02 11.65 79.4 0.079

08/27/2008 8:03 11.73 80.7 0.08

08/27/2008 8:04 11.81 79.8 0.079

08/27/2008 8:05 11.66 75.1 0.076

08/27/2008 8:06 11.63 70.6 0.081

08/27/2008 8:07 11.69 61 0.083

08/27/2008 8:08 11.82 57.7 0.083

08/27/2008 8:09 11.75 57.2 0.085

08/27/2008 8:10 11.73 59.3 0.081

08/27/2008 8:11 11.71 53.8 0.079

08/27/2008 8:12 11.61 47.6 0.083

08/27/2008 8:13 11.75 48.6 0.083

08/27/2008 8:14 11.85 47.7 0.077

08/27/2008 8:15 11.59 47.8 0.075

08/27/2008 8:16 11.58 49.6 0.075

08/27/2008 8:17 11.51 54.3 0.08

08/27/2008 8:18 11.75 60.8 0.08

08/27/2008 8:19 11.85 64.7 0.075

08/27/2008 8:20 11.71 65 0.072

08/27/2008 8:21 11.58 67.6 0.072

08/27/2008 8:22 11.61 71.2 0.073

08/27/2008 8:23 11.68 78.7 0.077

08/27/2008 8:24 11.77 84.2 0.073

08/27/2008 8:25 11.66 82.9 0.072

08/27/2008 8:26 11.59 84.3 0.075

08/27/2008 8:27 11.77 92.8 0.075

08/27/2008 8:28 11.97 88.7 0.071

08/27/2008 8:29 11.74 68.2 0.07

08/27/2008 8:30 11.65 57.1 0.074

08/27/2008 8:31 11.72 53.4 0.077

08/27/2008 8:32 11.77 52.4 0.076

08/27/2008 8:33 11.92 52.8 0.072

08/27/2008 8:34 11.78 53.1 0.072

08/27/2008 8:35 11.57 54.2 0.078

08/27/2008 8:36 11.81 60.1 0.078

08/27/2008 8:37 11.81 62.5 0.077

08/27/2008 8:38 11.79 64.4 0.077

08/27/2008 8:39 11.83 66.3 0.078

08/27/2008 8:40 11.91 70.3 0.074

08/27/2008 8:41 11.7 69.2 0.076

Page 3 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 8:42 11.68 68.8 0.079

08/27/2008 8:43 11.88 69.8 0.078

08/27/2008 8:44 11.73 67.8 0.08

08/27/2008 8:45 11.84 71.6 0.076

08/27/2008 8:46 11.73 69.5 0.078

08/27/2008 8:47 11.69 75.3 0.085

08/27/2008 8:48 11.91 73.9 0.08

08/27/2008 8:49 11.84 62.4 0.077

08/27/2008 8:50 11.72 56.2 0.076

08/27/2008 8:51 11.7 55.9 0.078

08/27/2008 8:52 11.77 62.3 0.081

08/27/2008 8:53 11.85 64.5 0.078

08/27/2008 8:54 11.89 65.7 0.074

08/27/2008 8:55 11.84 70 0.074

08/27/2008 8:56 11.71 70.9 0.077

08/27/2008 8:57 11.72 69.8 0.078

08/27/2008 8:58 11.72 72.9 0.08

08/27/2008 8:59 11.93 83 0.077

08/27/2008 9:00 11.88 80.9 0.076

08/27/2008 9:01 11.62 76.5 0.078

08/27/2008 9:02 11.72 84.3 0.078

08/27/2008 9:03 11.92 88.8 0.076

08/27/2008 9:04 11.85 91.1 0.074

08/27/2008 9:05 11.68 86.1 0.077

08/27/2008 9:06 11.74 74 0.076

08/27/2008 9:07 12.02 63.2 0.076

08/27/2008 9:08 11.9 46.8 0.075

08/27/2008 9:09 11.71 44 0.077

08/27/2008 9:10 11.72 47.3 0.085

08/27/2008 9:11 11.97 54.4 0.082

08/27/2008 9:12 11.76 53.6 0.082

08/27/2008 9:13 11.76 57.7 0.08

08/27/2008 9:14 11.66 59.2 0.084

08/27/2008 9:15 11.66 63.7 0.082

08/27/2008 9:16 11.83 69.2 0.081

08/27/2008 9:17 11.89 73 0.076

08/27/2008 9:18 11.67 76.4 0.078

08/27/2008 9:19 11.73 85.7 0.082

08/27/2008 9:20 11.83 90.9 0.079

08/27/2008 9:21 11.71 85.8 0.079

Page 4 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 9:22 11.8 76.3 0.077

08/27/2008 9:23 11.82 69.4 0.075

08/27/2008 9:24 11.75 64.7 0.076

08/27/2008 9:25 11.71 66.8 0.079

08/27/2008 9:26 11.9 71.8 0.077

08/27/2008 9:27 11.91 71.7 0.075

08/27/2008 9:28 11.82 66.9 0.073

08/27/2008 9:29 11.68 65.1 0.081

08/27/2008 9:30 11.92 71.6 0.078

08/27/2008 9:31 11.88 70.2 0.074

08/27/2008 9:32 11.66 69.7 0.075

08/27/2008 9:33 11.73 78 0.081

08/27/2008 9:34 11.91 81.4 0.08

08/27/2008 9:35 11.86 75.9 0.078

08/27/2008 9:36 11.8 69.4 0.078

08/27/2008 9:37 11.69 64.4 0.082

08/27/2008 9:38 11.77 61 0.081

08/27/2008 9:39 11.73 59.2 0.08

08/27/2008 9:40 11.78 62.1 0.078

08/27/2008 9:41 11.73 63.7 0.08

08/27/2008 9:42 11.81 67.9 0.081

08/27/2008 9:43 11.97 75.6 0.076

08/27/2008 9:44 11.71 73.9 0.076

08/27/2008 9:45 11.72 79.1 0.078

08/27/2008 9:46 11.77 81.5 0.079

08/27/2008 9:47 11.85 86.2 0.076

08/27/2008 9:48 11.84 87.1 0.074

08/27/2008 9:49 11.68 88.8 0.076

08/27/2008 9:50 11.78 92.8 0.073

08/27/2008 9:51 11.66 88.6 0.074

08/27/2008 9:52 11.75 77.9 0.075

08/27/2008 9:53 11.9 70.8 0.078

08/27/2008 9:54 11.91 64.8 0.076

08/27/2008 9:55 11.88 65.8 0.073

08/27/2008 9:56 11.7 62.2 0.074

08/27/2008 9:57 11.6 66.7 0.079

08/27/2008 9:58 11.83 74.4 0.078

08/27/2008 9:59 11.82 74.3 0.075

08/27/2008 10:00 11.88 79 0.076

08/27/2008 10:01 11.85 83 0.069

Page 5 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 10:02 11.81 80.5 0.012

08/27/2008 10:03 11.79 74.7 0.265

08/27/2008 10:04 11.88 72.2 0.084

08/27/2008 10:05 11.78 66.5 0.076

08/27/2008 10:06 11.74 61.7 0.079

08/27/2008 10:07 11.85 57.5 0.077

08/27/2008 10:08 11.84 58.9 0.075

08/27/2008 10:09 11.85 57.9 0.075

08/27/2008 10:10 11.88 48.4 0.073

08/27/2008 10:11 11.68 44.9 0.077

08/27/2008 10:12 11.76 45.4 0.079

08/27/2008 10:13 11.85 47.7 0.079

08/27/2008 10:14 11.86 49.6 0.079

08/27/2008 10:15 11.76 51.1 0.076

08/27/2008 10:16 11.66 52.6 0.077

08/27/2008 10:17 11.7 58.5 0.08

08/27/2008 10:18 11.89 64.5 0.08

08/27/2008 10:19 11.89 67.1 0.077

08/27/2008 10:20 11.65 66.1 0.076

08/27/2008 10:21 11.63 69.8 0.081

08/27/2008 10:22 11.87 80.6 0.08

08/27/2008 10:23 11.8 82.5 0.08

08/27/2008 10:24 11.83 82.8 0.077

08/27/2008 10:25 11.84 72.1 0.075

08/27/2008 10:26 11.71 64.2 0.076

08/27/2008 10:27 11.65 63.5 0.079

08/27/2008 10:28 11.69 58.5 0.079

08/27/2008 10:29 11.88 62.7 0.078

08/27/2008 10:30 11.97 65.6 0.075

08/27/2008 10:31 11.82 67.2 0.073

08/27/2008 10:32 11.66 68.1 0.075

08/27/2008 10:33 11.56 73.3 0.081

08/27/2008 10:34 11.8 76 0.078

08/27/2008 10:35 11.96 70.3 0.075

08/27/2008 10:36 11.79 66.7 0.076

08/27/2008 10:37 11.73 71.7 0.075

08/27/2008 10:38 11.73 73.3 0.076

08/27/2008 10:39 11.76 75.4 0.081

08/27/2008 10:40 11.89 71.5 0.078

08/27/2008 10:41 11.93 66.6 0.076

Page 6 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 10:42 11.84 64.8 0.074

08/27/2008 10:43 11.67 65.6 0.078

08/27/2008 10:44 11.89 77.3 0.079

08/27/2008 10:45 11.9 76.9 0.077

08/27/2008 10:46 11.66 75.7 0.077

08/27/2008 10:47 11.68 80.7 0.083

08/27/2008 10:48 11.87 75.3 0.08

08/27/2008 10:49 11.83 67.2 0.079

08/27/2008 10:50 11.81 64.8 0.078

08/27/2008 10:51 11.83 67 0.078

08/27/2008 10:52 11.77 68.5 0.076

08/27/2008 10:53 11.66 69.7 0.079

08/27/2008 10:54 11.8 75.6 0.082

08/27/2008 10:55 11.86 80.8 0.081

08/27/2008 10:56 11.84 79.5 0.08

08/27/2008 10:57 11.84 83.4 0.078

08/27/2008 10:58 11.75 82.2 0.077

08/27/2008 10:59 11.65 81.3 0.082

08/27/2008 11:00 11.75 77.9 0.084

08/27/2008 11:01 11.94 73.4 0.078

08/27/2008 11:02 11.83 70.1 0.075

08/27/2008 11:03 11.57 62.9 0.08

08/27/2008 11:04 11.78 66 0.081

08/27/2008 11:05 11.88 61.3 0.076

08/27/2008 11:06 11.71 55.7 0.078

08/27/2008 11:07 11.82 54.5 0.076

08/27/2008 11:08 11.89 55.4 0.075

08/27/2008 11:09 11.74 55.4 0.079

08/27/2008 11:10 11.67 59.1 0.083

08/27/2008 11:11 11.92 66.2 0.079

08/27/2008 11:12 11.81 64.1 0.076

08/27/2008 11:13 11.68 58.2 0.076

08/27/2008 11:14 11.71 59.8 0.077

08/27/2008 11:15 11.75 60.6 0.078

08/27/2008 11:16 11.75 52.9 0.079

08/27/2008 11:17 11.82 50 0.077

08/27/2008 11:18 11.99 52.2 0.074

08/27/2008 11:19 11.96 50.6 0.071

08/27/2008 11:20 11.66 52 0.075

08/27/2008 11:21 11.54 54.1 0.08

Page 7 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 11:22 11.77 59.3 0.082

08/27/2008 11:23 11.97 63 0.076

08/27/2008 11:24 11.75 61.2 0.075

08/27/2008 11:25 11.71 65.7 0.076

08/27/2008 11:26 11.7 59.9 0.081

08/27/2008 11:27 11.68 57 0.083

08/27/2008 11:28 11.91 56.7 0.079

08/27/2008 11:29 11.84 52.8 0.077

08/27/2008 11:30 11.66 52.7 0.08

08/27/2008 11:31 11.69 53.2 0.083

08/27/2008 11:32 11.79 52.3 0.08

08/27/2008 11:33 11.73 51.7 0.079

08/27/2008 11:34 11.84 51 0.076

08/27/2008 11:35 11.74 51.2 0.076

08/27/2008 11:36 11.67 48.9 0.078

08/27/2008 11:37 11.67 49.5 0.081

08/27/2008 11:38 11.94 51.5 0.075

08/27/2008 11:39 11.83 50.7 0.074

08/27/2008 11:40 11.71 50.9 0.075

08/27/2008 11:41 11.71 52 0.076

08/27/2008 11:42 11.71 56.2 0.078

08/27/2008 11:43 11.79 62.7 0.079

08/27/2008 11:44 11.81 63.7 0.077

08/27/2008 11:45 11.76 65.5 0.079

08/27/2008 11:46 12 70.4 0.075

08/27/2008 11:47 11.77 59.7 0.073

08/27/2008 11:48 11.69 57.7 0.074

08/27/2008 11:49 11.58 51.6 0.079

08/27/2008 11:50 11.73 54.4 0.081

08/27/2008 11:51 11.91 54 0.077

08/27/2008 11:52 11.82 51.2 0.075

08/27/2008 11:53 11.65 54.1 0.08

08/27/2008 11:54 11.69 59.1 0.082

08/27/2008 11:55 11.85 62.3 0.078

08/27/2008 11:56 11.83 62.2 0.077

08/27/2008 11:57 11.75 64.9 0.079

08/27/2008 11:58 11.69 61.4 0.081

08/27/2008 11:59 11.7 61.3 0.082

08/27/2008 12:00 11.8 63.6 0.084

08/27/2008 12:01 11.92 66.7 0.08

Page 8 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 12:02 11.74 62.1 0.08

08/27/2008 12:03 11.62 59 0.081

08/27/2008 12:04 11.76 63.6 0.085

08/27/2008 12:05 11.96 61.3 0.082

08/27/2008 12:06 11.76 53.4 0.081

08/27/2008 12:07 11.56 50.9 0.079

08/27/2008 12:08 11.56 55 0.083

08/27/2008 12:09 11.8 61.1 0.081

08/27/2008 12:10 11.77 60.8 0.078

08/27/2008 12:11 11.68 69 0.079

08/27/2008 12:12 11.7 69.9 0.077

08/27/2008 12:13 11.55 67.6 0.082

08/27/2008 12:14 11.83 73.3 0.077

08/27/2008 12:15 11.69 72 0.075

08/27/2008 12:16 11.47 72.4 0.078

08/27/2008 12:17 11.69 81.6 0.081

08/27/2008 12:18 11.98 88.7 0.073

08/27/2008 12:19 11.64 74.9 0.073

08/27/2008 12:20 11.52 66.1 0.075

08/27/2008 12:21 11.64 63 0.075

08/27/2008 12:22 11.77 62.5 0.073

08/27/2008 12:23 11.92 56.5 0.071

08/27/2008 12:24 11.8 47.7 0.072

08/27/2008 12:25 11.74 44.7 0.07

08/27/2008 12:26 11.73 45.1 0.073

08/27/2008 12:27 11.53 44.1 0.077

08/27/2008 12:28 11.74 50 0.077

08/27/2008 12:29 11.75 50.2 0.074

08/27/2008 12:30 11.67 52.9 0.076

08/27/2008 12:31 11.61 54.6 0.078

08/27/2008 12:32 11.64 56.9 0.078

08/27/2008 12:33 11.75 62 0.076

08/27/2008 12:34 11.79 64.2 0.077

08/27/2008 12:35 11.58 66.8 0.08

08/27/2008 12:36 11.66 66.4 0.078

08/27/2008 12:37 11.76 60.6 0.078

08/27/2008 12:38 11.77 57.1 0.079

08/27/2008 12:39 11.62 55.4 0.078

08/27/2008 12:40 11.55 56.3 0.083

08/27/2008 12:41 11.84 62.5 0.082

Page 9 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 12:42 11.89 64.3 0.077

08/27/2008 12:43 11.62 60.7 0.076

08/27/2008 12:44 11.68 65.5 0.077

08/27/2008 12:45 11.73 68.7 0.078

08/27/2008 12:46 11.67 71.8 0.08

08/27/2008 12:47 11.73 74 0.075

08/27/2008 12:48 11.62 73.3 0.075

08/27/2008 12:49 11.48 74 0.079

08/27/2008 12:50 11.6 79.5 0.083

08/27/2008 12:51 11.91 88.1 0.077

08/27/2008 12:52 11.81 79.1 0.071

08/27/2008 12:53 11.57 70 0.071

08/27/2008 12:54 11.48 66 0.076

08/27/2008 12:55 11.67 68.1 0.078

08/27/2008 12:56 11.81 69.9 0.074

08/27/2008 12:57 11.65 68.8 0.072

08/27/2008 12:58 11.66 71.6 0.074

08/27/2008 12:59 11.71 74.7 0.075

08/27/2008 13:00 11.65 78.3 0.079

08/27/2008 13:01 11.82 80.8 0.077

08/27/2008 13:02 11.8 77.3 0.075

08/27/2008 13:03 11.77 79.5 0.076

08/27/2008 13:04 11.68 84.2 0.08

08/27/2008 13:05 11.69 85.9 0.082

08/27/2008 13:06 11.73 84.5 0.082

08/27/2008 13:07 11.72 77.5 0.082

08/27/2008 13:08 11.76 73 0.084

08/27/2008 13:09 11.67 67.4 0.086

08/27/2008 13:10 11.74 68.9 0.086

08/27/2008 13:11 11.57 66.1 0.092

08/27/2008 13:12 11.77 65 0.089

08/27/2008 13:13 11.68 59.6 0.086

08/27/2008 13:14 11.63 57 0.083

08/27/2008 13:15 11.68 56 0.083

08/27/2008 13:16 11.59 52.9 0.085

08/27/2008 13:17 11.77 59 0.082

08/27/2008 13:18 11.81 60.6 0.077

08/27/2008 13:19 11.79 60.4 0.072

08/27/2008 13:20 11.61 60 0.073

08/27/2008 13:21 11.56 63.4 0.075

Page 10 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 13:22 11.66 68.9 0.074

08/27/2008 13:23 11.62 72.5 0.078

08/27/2008 13:24 11.83 74.2 0.074

08/27/2008 13:25 11.81 68.1 0.071

08/27/2008 13:26 11.55 61.7 0.074

08/27/2008 13:27 11.63 63.6 0.076

08/27/2008 13:28 11.59 64.7 0.078

08/27/2008 13:29 11.81 66.5 0.076

08/27/2008 13:30 11.87 62.3 0.075

08/27/2008 13:31 11.83 57.5 0.073

08/27/2008 13:32 11.58 54 0.076

08/27/2008 13:33 11.55 58.1 0.078

08/27/2008 13:34 11.6 60.2 0.078

08/27/2008 13:35 11.71 61.9 0.076

08/27/2008 13:36 11.61 63 0.078

08/27/2008 13:37 11.53 69.1 0.083

08/27/2008 13:38 11.76 77.3 0.083

08/27/2008 13:39 11.77 79 0.078

08/27/2008 13:40 11.69 80.4 0.079

08/27/2008 13:41 11.74 82 0.081

08/27/2008 13:42 11.69 73 0.081

08/27/2008 13:43 11.48 66.1 0.083

08/27/2008 13:44 11.56 66.3 0.081

08/27/2008 13:45 11.69 72.3 0.082

08/27/2008 13:46 11.84 80.7 0.08

08/27/2008 13:47 11.69 82.1 0.077

08/27/2008 13:48 11.47 82.3 0.077

08/27/2008 13:49 11.63 91.9 0.079

08/27/2008 13:50 11.74 97 0.078

08/27/2008 13:51 11.64 98.1 0.079

08/27/2008 13:52 11.7 104.1 0.076

08/27/2008 13:53 11.69 107.5 0.073

08/27/2008 13:54 11.77 113.1 0.073

08/27/2008 13:55 11.75 110.4 0.074

08/27/2008 13:56 11.58 97.2 0.07

08/27/2008 13:57 11.44 89.5 0.076

08/27/2008 13:58 11.73 78.3 0.077

08/27/2008 13:59 11.77 73.6 0.077

08/27/2008 14:00 11.72 70.6 0.073

08/27/2008 14:01 11.68 69.6 0.071

Page 11 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 14:02 11.75 73 0.07

08/27/2008 14:03 11.55 75 0.075

08/27/2008 14:04 11.62 79.4 0.075

08/27/2008 14:05 11.62 76.2 0.075

08/27/2008 14:06 11.75 84.5 0.073

08/27/2008 14:07 11.66 87.5 0.072

08/27/2008 14:08 11.54 84.9 0.078

08/27/2008 14:09 11.75 92.9 0.077

08/27/2008 14:10 11.81 97.9 0.072

08/27/2008 14:11 11.69 98 0.074

08/27/2008 14:12 11.72 87.8 0.076

08/27/2008 14:13 11.66 81.9 0.074

08/27/2008 14:14 11.48 77.2 0.078

08/27/2008 14:15 11.8 80.3 0.076

08/27/2008 14:16 11.64 81.1 0.077

08/27/2008 14:17 11.54 88 0.078

08/27/2008 14:18 11.6 93.7 0.079

08/27/2008 14:19 11.72 97.6 0.078

08/27/2008 14:20 11.86 105.2 0.076

08/27/2008 14:21 11.79 107.4 0.074

08/27/2008 14:22 11.59 106 0.078

08/27/2008 14:23 11.7 110.3 0.078

08/27/2008 14:24 11.76 114.1 0.078

08/27/2008 14:25 11.76 101.7 0.073

08/27/2008 14:26 11.63 88.9 0.073

08/27/2008 14:27 11.63 85.1 0.077

08/27/2008 14:28 11.66 83.7 0.076

08/27/2008 14:29 11.63 81.5 0.079

08/27/2008 14:30 11.83 87.4 0.076

08/27/2008 14:31 11.75 87.2 0.075

08/27/2008 14:32 11.64 88.2 0.074

08/27/2008 14:33 11.54 90.1 0.077

08/27/2008 14:34 11.63 95.2 0.081

08/27/2008 14:35 11.79 94.9 0.079

08/27/2008 14:36 11.75 93 0.075

08/27/2008 14:37 11.58 92.8 0.08

08/27/2008 14:38 11.68 98.4 0.083

08/27/2008 14:39 11.79 102.3 0.082

08/27/2008 14:40 11.74 102 0.081

08/27/2008 14:41 11.77 103.6 0.078

Page 12 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 14:42 11.76 97.7 0.079

08/27/2008 14:43 11.78 90.7 0.078

08/27/2008 14:44 11.6 81.9 0.075

08/27/2008 14:45 11.57 78.3 0.079

08/27/2008 14:46 11.78 82.5 0.081

08/27/2008 14:47 11.94 82.8 0.073

08/27/2008 14:48 11.65 79.2 0.073

08/27/2008 14:49 11.65 86.2 0.078

08/27/2008 14:50 11.87 89 0.072

08/27/2008 14:51 11.73 86.5 0.07

08/27/2008 14:52 11.7 87.9 0.071

08/27/2008 14:53 11.61 91.4 0.074

08/27/2008 14:54 11.7 94 0.073

08/27/2008 14:55 11.72 97 0.075

08/27/2008 14:56 11.88 94.1 0.072

08/27/2008 14:57 11.72 81.6 0.071

08/27/2008 14:58 11.64 74.8 0.077

08/27/2008 14:59 11.77 69 0.075

08/27/2008 15:00 11.67 63.6 0.078

08/27/2008 15:01 11.77 61.1 0.08

08/27/2008 15:02 11.92 63.5 0.078

08/27/2008 15:03 11.71 61.8 0.077

08/27/2008 15:04 11.56 60.9 0.079

08/27/2008 15:05 11.65 64.7 0.082

08/27/2008 15:06 11.8 71.6 0.081

08/27/2008 15:07 11.79 75.8 0.08

08/27/2008 15:08 11.79 76.5 0.078

08/27/2008 15:09 11.73 76.6 0.079

08/27/2008 15:10 11.81 79.7 0.078

08/27/2008 15:11 11.8 76.4 0.072

08/27/2008 15:12 11.65 76 0.078

08/27/2008 15:13 11.75 83.6 0.082

08/27/2008 15:14 11.88 85.2 0.077

08/27/2008 15:15 11.85 83.7 0.072

08/27/2008 15:16 11.71 82.9 0.075

08/27/2008 15:17 11.62 86.6 0.08

08/27/2008 15:18 11.78 88.1 0.078

08/27/2008 15:19 11.84 88.6 0.073

08/27/2008 15:20 11.8 89.6 0.072

08/27/2008 15:21 11.79 91.9 0.075

Page 13 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 15:22 11.68 82.3 0.08

08/27/2008 15:23 11.85 78.7 0.079

08/27/2008 15:24 11.92 76.5 0.073

08/27/2008 15:25 11.7 73.8 0.075

08/27/2008 15:26 11.72 79.2 0.08

08/27/2008 15:27 11.89 82.9 0.079

08/27/2008 15:28 11.87 76.6 0.076

08/27/2008 15:29 11.86 72.1 0.074

08/27/2008 15:30 11.69 69.5 0.081

08/27/2008 15:31 11.76 69.2 0.083

08/27/2008 15:32 11.86 66.4 0.08

08/27/2008 15:33 11.87 64.5 0.077

08/27/2008 15:34 11.8 63.6 0.077

08/27/2008 15:35 11.59 62.5 0.084

08/27/2008 15:36 11.73 65.7 0.083

08/27/2008 15:37 11.94 67.7 0.079

08/27/2008 15:38 11.87 65.6 0.079

08/27/2008 15:39 11.65 63.5 0.08

08/27/2008 15:40 11.71 68.3 0.08

08/27/2008 15:41 11.76 71.5 0.082

08/27/2008 15:42 11.86 69.8 0.078

08/27/2008 15:43 11.88 65.3 0.074

08/27/2008 15:44 11.69 60.7 0.079

08/27/2008 15:45 11.75 64.9 0.08

08/27/2008 15:46 11.87 69.4 0.078

08/27/2008 15:47 11.87 70.4 0.072

08/27/2008 15:48 11.63 70.3 0.075

08/27/2008 15:49 11.8 76.9 0.074

08/27/2008 15:50 11.79 80.8 0.073

08/27/2008 15:51 11.73 84.2 0.072

08/27/2008 15:52 11.82 93.2 0.073

08/27/2008 15:53 11.8 90.4 0.073

08/27/2008 15:54 11.73 76.5 0.072

08/27/2008 15:55 11.82 64.9 0.073

08/27/2008 15:56 11.83 59.1 0.075

08/27/2008 15:57 11.86 56.2 0.076

08/27/2008 15:58 11.85 56.6 0.074

08/27/2008 15:59 11.76 58 0.075

08/27/2008 16:00 11.68 59.1 0.08

08/27/2008 16:01 11.77 62.7 0.073

Page 14 of 15
iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 16:02 11.86 66.3 0.014

08/27/2008 16:03 11.92 68.3 0.257

08/27/2008 16:04 11.69 67.2 0.086

08/27/2008 16:05 11.64 69.9 0.08

08/27/2008 16:06 11.77 75.5 0.084

08/27/2008 16:07 11.88 79.8 0.08

08/27/2008 16:08 11.83 82.1 0.078

08/27/2008 16:09 11.86 83.9 0.077

08/27/2008 16:10 11.68 71.9 0.08

08/27/2008 16:11 11.71 66.1 0.082

08/27/2008 16:12 11.92 64.7 0.077

08/27/2008 16:13 11.82 63.1 0.075

08/27/2008 16:14 11.64 62 0.077

08/27/2008 16:15 11.8 68.9 0.079

08/27/2008 16:16 11.85 76.2 0.08

08/27/2008 16:17 11.91 81.9 0.075

08/27/2008 16:18 11.84 80.8 0.072

08/27/2008 16:19 11.74 85.5 0.075

08/27/2008 16:20 11.7 91.1 0.079

Page 15 of 15
APPENDIX H 

CHAIN OF CUSTODY 

APPENDIX I 

TEST PARTICIPANTS 
TEST PARTICIPANTS

ENVIRONMENTAL, HEALTH, & SAFETY 

AIR SERVICES GROUP – TEST TEAM

Scott Given Technician – Test Team Lead 

Jorge Varino Environmental Technician 

Ryan Newell Associate Technician 

David A. Smith, QSTI Coordinator – Air Services Group 

PROCESS DATA

Adam Ballans Associate Engineer –Big Bend Station 

R.A. McDarby Senior Environmental Technician 

FUEL ANALYSIS

Patrice Jackson Environmental Technician 

Ellen Demers Environmental Technician 

PARTICULATE LABORATORY

Sam Soth Environmental Technician 

SUPPORTING DATA COLLECTION AND ANALYSIS

R.A. McDarby Senior Environmental Technician 

PROJECT QUALITY OBJECTIVES & REPORTING

R.A. McDarby Senior Environmental Technician 

TEST COORDINATION

Karen Zwolak Senior Environmental Consultant – Big Bend Station 

Adam Ballans Associate Engineer –Big Bend Station 

David A. Smith, QSTI Coordinator – Air Services Group