, . '-." ' .. - , ' , 

TOTAL CHROMIUM E~SSIONS REPORT' 

AI Deftaed By TIle- .. 

Code ofll'eclenl RepJatfoas; Title 40 Part ctl. 

RMCEINC Project ##2006-13527 

ARMOLOY CORPORATION 

CHROME SCRUBBERS til '" ##3 

DEKALB, ILLINOIS 

PREPARED FOR: 

ARMOLOY CORPORAnON 

BY: 

RMC ENvDtONMENTALt INc. - CHICAGO REGIONAL OmCE 
Armoloy Corporation 

DeKaIb, minoa 

REPORT CERTIFICATION 

RMCElNC-Cbfeago Regional Omce 

Project #2006-13517 

The sampling, analysis, and data collection performed for this report were canied out under my direction and 

supervision. and I hereby catHY that the test report is authentic and ammdc, 10 the best of my knowledge. 
Armoloy CorporatioD 

DeKalb, mino. 

TABLE OF CONTENTS 

RMCEINCChlcago RegioDaI Omce 

Project ##2006-13527 

1.0 PROJECf IN'FORMATION •.•.. 1.1 .......................... _ .................................................................... '1 11.1.1 

1.1 COl\;U»ANY INFORMATION ....................................................................................................................................... 1 

1.2 TEs11NO FIRM INFoRMAnON ................................................................................................................................. 1 

1.3 TEST 1NFORMA11ON .................................. • ........... •• ... ••• .. • .. • .. • .. •• ............................................................................. 1 

%.0 SO'URCE mEN'TD'lCATION ••..•....••••• ..--.. ......................... .....-._ ............................... .......--. ......................... 2 

3.0 SUMMARY AND DISCUSSION OF RESULTS. I ..... 2 

4.0 POUUTANTS AND TEST METHODS_. .. ......... I ......... IU .............. , .2 

5.0 TEST PROCEDURES AND RESULTS ... ____ ... ~ .... ~I1~ .. ".' ... '... ~II_ .... Il ............... _ ..... _ .... , ..................................................... 11 ..... _ •• _ ............ 11 ......... ' .............. ___ 2 

S.10 SAMPImO PROCEDtJRES. ••.••••.••••••••••..•••••••..•..•••..•.•.••.•••.••..••••••.•••.••..•••••••••.•••••••••••..••.••••••..••..••••.••••.•••••••••••.••••••• 2 

5.11 'Y olunretric Flaw Rota .................................................................................................................................... J 

5.12 CIIROItIJUM CONCEJlI'RA770NS .......................................................................................................................... 3 

5.20 FJELD DATA SHEETs ............................................................................................................................................. 3 

6.0 EQUIPMENT CALIBRATION AND QUALITY ASSURANCE ......... n ......... n. , n .3 

APPENDIX As TEST SUMM.4aY SHEETS ........ , ... II. I. I .... " ........................... II .,. 1 •• I I Il"" , •• , •••••• , • • .. A 

TarAL CHROMIUM REsULTS SUMMARY ........................................................................................ : ............................ A 

,APPENDIX B. FIELD DATA ~ETS-.-....... ......... _ ........ " , •••. _ ............... .....-.-. ................................................ B 

M£n.IOD 1 • DATA SIIEEl" ........................................................................................................................................... B 

ME'nlOIlS 1-5 DATA SfIEE'I'S ....................................................................................................................................... B 

APPENDIJ( C. ANAL'Y'I'ICAL »ATA I. "'."'1 •• "'1 ••••••••• I", II II '1," '" J ........................ ., .. D 

APPENDIX: D. T'FS1' oNOC' fPRMS..~.,.,I. I. ,"., ....•..... I .. , ...... , .. " .. 1 .... ..--............ _ ......................................... D 

PRETEsr&: PosT TEST • MElERBox CALlBRAnON ..................................................................................................... 0 

PrrarlNSPECTION I •••••••••••••••••••• , ................................................................................................................................. C 
Armoloy Corporation 

DeKaIb, DUaols 

1.0 PROJECI' INFORMATION 

1.1 Company Informatioa 

Name and Address: 

Contac:t: 

Telephone Nwnber: 

Source Tested: 

Permit Number: 

1.2 TestiDg FIrm latormatioD 

Name and Address: 

Contact 

Telephone Number: 

1.3 Test InformatioD 

Test Requested By: 

Source CoDtact 

TelephOile Number: 

Test Objective: 

Test Methods: 

Test Dates: 

.EPA I State Represen1atives 

On-site: 

Source Test Coordinators: 

Test Personnel: 

Other Test Personnel: 

Armoloy Corpcr.ttion 

114 Simonds Avenue 

DeKalb. Illinois 60155 

Mr. William Cor2ene 

815-758-7486 Phone 

ArmoloyLab@msn.com 

RMCEINC-Chfeaao Regfoaal Oftlce 

Project #2006-13527 

Hard Chrome Taok Scrubbers - CMP Scrubber #2 &; #3 

95120329 

RMC f'.NVIRONMFNrAL, INC. 

9226 North -r Street 

Machesney Park, Dlinois 61115 

Gregory Chleborowicz . 

815-318-6155 Direct 800-S32-3391 Voice Mail 

RMCEGREG@aol.com 

ArmoJoy Corpondion 

Mr. William Comne 

815-758-7486 Phone 

Total Chromium Compliance Test 

EPA Methods 1-4.&306 

February 28 &: March 1.2006 

William Corzine Armoloy Corporation 

Eric QWncy RMCEInc 

Tony SegalJa RMCElnc 

Andrew McDennand RMCEInc 

Ii 

Page 1 
Armoloy CorporatioD 

DeKaJb, lDiDois 

1.0 SOURCE IDENTIFICATION 

Name and Address: 

Contaet: 

Telephone Number: 

Source Tested: 

Permit Number: 

Annoloy Corporation 

114 Simonds AVeIlue 

DeKaJb. IDiDois 60155 

Mr. William COI7.eDe 

815-758-7486 Phone 

AnnoloyLab@mso.com 

RMCEINC-chfcago RegIoual 0fIlc:e 

Project 1Il006-13!27 

Hard Chrome Tank Scrubbers - CMP Scrubber #2 & #3 

95120329 

3.0 SUMMARY AND DISCUSSlON OF RESULTS 

The RSUIIs of the emissions retesting performed on the large chrome tank stacks are preseoted in Table 2-1. 

Detailed results of all of 1he testing completed on this location are located in Appeadls A. The field data and the 

analytical results are pn:sented in Appendis B aDd C. n:speaively. Calibration sheets and equipment performance 

checks are presented in Appendix D. along with the cbain of custody. A cyclonic flow chec:k was conduc:ted and DO 

cyclonic flow auomalies were noted. 

As indicated by the average of tile three ~ the tested resul1s were below the MACl" regulation standards for newly 

installed chrome plating uniIs of 0.015 mglDSCM for composite mesh pad scrubber systems on bard chrome platina 

tanks. 

LocatioD 

Saubber Unit #2 

Scrubber Unit #3 

TABLEl-t 

SUMMARY OF TOTAL CHROMIUM RESULTS 

Armoloy Corpontioa 

February 18 '" March 1,2006 

Test Parameter Result S .- R 

mWOSCM 0.0042 =s 0.015 mglDSCM for bard chrome plating sources 

Flow rate ·DSCFM 15,574 

IbIHr 0.00005 

m&'DSCM 0.0047 !S 0.015 mglDSCM for hard chrome plating sources 

Flow rate DSCFM 16.849 

lbIHr 0.00003 

4.0 POLLUTANTS AND TEST METHODS 

PoUurant Tested: Total Chromium EPA Method 306 - 40 CFR 60, Appendix A 

5.0 TEST PROCEDURES AND RESULTS 

5.10 SampUng Procedures 

Testing was completed per EPA test methods 1.2.3, and 306 defined in 40 CFR Part 60 Appendix A. The sampling 

and analytical requirements for this proaram include the determination of total chrome. O;iCOz, moisture and 

I. 

Page 2 
Armoloy CorporadOD 

DeKaJb, DUnois 

RMCEINC-Chieago Regfoaal Omce 

Project #l~13S27 

volumetric flow rates from the stack etnuent The plating processes were operated at 1000.11 capacity. The specific 

equipment and procedures that WeR used are detailed below. 

5.11 Volumetric flow Rates 

RMCEINC determined the number and location of the traverse points for volumetric flow rate IIle8SURIJmlt 

acconting to tho procedures outlined in EPA Method 1. When determining the loc:ation and IlUIDbeI" of sample 

points, RMCElNC took into account the number of sample ports, duct configuration, and localion of upsaream and 

dowustream flow cUstmbances. 

The flue gas velocity and volumetric tJow rate were detennined accordiDg to the proc:edures of EPA Method 2. A 

~ S pitot tube with a Type K tbcrmocouple (EPA Method 5 Sample Probe) was used to measure velocity 

pn:ssure and stack gas b:mpelature at each sample point. Each pitot tube conformed to the geometric specifications 

of EPA Method 2 and was assigned a coefIicieDt of 0.84. An mnbilic:al cord cozmec:ted the pilot tube to the meter 

box inclined manometer and digital temperature readout. RMCEINC leak-checked the pilot tube prior to conducting 

the traverse aDd at random points during the test. 

RMCEINC determined the flue gas composition and molec:uJar weight using EPA Methods 3 aud 4 proc:edures. 

S.12 mc ConeentratioDi 

The total chrome samples were drawn isokinetically from the source usiDg an EPA method 306 sampling Crain. The 

sampling train consisted of a glass nozzle aad probe liner, aD attached Type S Pilot tube, four-gJass impinger chilled 

and a metering console. No fiIr.et is lued for this melhod. 

The first impinger is left~, the second and third impingers contain 100 ml of 0.1 N sodimn hydroxide (NaOH) 

in place of water, and the fourth impinger contains 200g of preweighed silica gel fOr moisture removal Each of the 

eight points was sampled for 15 minutes resulting in a net run time of 120 minutes. 

After sampling, the reagents were returned to their original container, weighed, the weights m:orded on the label and 

the liquid level marked. The silica gel was returned to the origiDal container, weighed and the weight recorded on 

the label. The volume ofwater vapor condensed in the impingers and the volume ofwater coUected in the silica gel 

were summed and entered into tho moisture consent calculations. All sampling componeuts exposed to the eftIueDt 

were rinsed thn:e times with NaOH and the rinses were added to the reagent comamers. 

The combined samples and rinses were iIIUIJyzM for total chrome usiDg Graphite Furnace. 

5.20 Field Data Sheets 

Field data sheets for the Method 1-4 data are enclosed in Appendix B. 

6.0 EQUIPMENT CALIBRATION AND QUALITY ASSURANCE 

RMCEINC foUowed the calibration and quality assurance procedures of EPA Methods I, 2, 3, 4, 5 and 306 

tbroughout the test program. A copy of the meter box calibrations, aua1yzer quality assurance checks and the ample 

Chain of Custody are included in Appendix C. 

Page 3 
Armoloy CorporatioD 

DeKaIb, lJIfaois 

RMCEJNC-Chicago RegIoaal omce 

Project t#2006-J3511 

APPENDIX At TEST SUMMARy SHEETS 

Total Chromiam Resalts SlUIlID8ry 
RMC environmental. Inc. 

Emissions Testing & Consulting 

Plant: Armoloy Date: 03123106 

Project#: 2006-13527 

Location: Chrome Scrubber #2 

Sample Identification 2-M306-1 2-M306-2 2-M306-3 

TestOate 02128106 03101106 03101106 

Start 1025 830 1110 

FInish 1227 1040 1315 

Total 120 120 120 

Cp Pilot Coefficient (CF) 0.84 0.84 0.84 

A Area of stack sq. Inches 804.2 804.2 804.2 

Pbar Barometric Pressure (in HG) 30.12 30.12 30.12 

Wm Volume of Condensate (mg) 25.8 32.4 33.8 

Ta Temperature of Effluent (F) 60.5 63 65 

Pavg Average Delta P 0.640 0.730 0.740 

Pg Static Pressure (In H2O) 0.17 0.17 0.17 

OH Delta H, Orfflce pressure differenl (In H2O) 2.06 2.42 2.47 

Tm Meterbox Temperature (F) 53.0 43.0 SO.O 

Vm Volume of sampte metered (CF) 97.163 100.797 102.423 

Y Meter correction factor 0.989 0.989 0.989 

On Nozzle Diameter (In) 0.239 0.239 0.239 

CO2 Percent Carbon Dioxide (%) 4.00 4.00 4.00 

02 Percent Oxygen (%) 20.00 20.00 20.00 

CO Percent Carbon Monoxide (%) 0 0 0 

N2 Percent Nitrogen (%) 76.00 76.00 76.00 

Ms Molecular Weight (wet) (Ibnb-m) 29.30 29.28 29.27 

Laboratory Results 

Total Chrome (mg) 4.40E-02 1.24E-02 1.25E-02 

AVERAGES 

Ps Absolute pressure of Flue Gas (in HG) 30.13 30.13 30.13 

Vwstd Volume of Water Vapor (SCF) 1.22 1.53 1.S9 

Vmstd Volume of Metered Gas (DSCF) 100.026 10S.922 106.167 

M Moisture (%) 1.20 1.42 1.46 

Va Velocity (FPS) 44.11 47.24 47.66 

Qaw Volumetirc Ftatl (ACFM) 14,781 1S.831 1S.971 

QscI Volumetric Flow (DSCF) 14,919 1S,867 15,937 1S,574 

Chromium Concentration (mgIDSCM) 0.0155 0.0041 0.0042 0.00418 

Chromium Concentration (lblHr) 8.88E-04 2.48E-04 2.48E-04 4.54E-04 

Isokenetlc (%) 100.16 99.73 99.52 
RMC Envlronmenta', Inc. 

Em/ssions Testing & Consulting 

Plant: Armoloy Date: 03123/06 

Project#: 2006-13527 

Locat/on: Chrome Scrubber #3 

Sample Identification 3-M306-01 3-M306-2 3-M306-3 

Test Date 02128106 03101/06 03101106 

Start 1030 830 1110 

Finish 1240 1040 1320 

Total 120 120 120 

Cp Pitot Coefficient (CF) 0.84 0.84 0.84 

A Area of stack sq. Inches 804.2 804.2 804.2 

Pbar Barometric Pressure (in HG) 30.12 30.12 30.12 

Wm Volume of Condensate (mg) 29.1 29.1 36.8 

Ta Temperature of Effluent (F) 75 73 71 

Pavg Average Oelta P 0.840 0.860 0.850 

Pg Static Pressure (in H2O) 0.21 0.21 0.21 

DH Delta H, Orifice pressure differential (In H2O) 1.77 1.84 1.82 

Tm Meterbox Temperature (F) 53.0 51.0 58.0 

Vm Volume of sample metered (CF) 93.909 93.188 95.461 

Y Meter correction factor 0.955 0.955 0.955 

On Nozzle Diameter (in) 0.217 0.217 0.217 

':02 Percent Carbon Dioxide (%) 6.00 6.00 8.00 

02 Percent Oxygen (%) 20.00 20.00 20.00 

CO Percent Carbon Monoxide (%) 0 0 0 

N2 Percent Nitrogen (%) 74.00 74.00 74.00 

Ms Molecular Weight (wet) (lbIlb-m) 29.59 29.59 29.55 

Laboratory Results 

Total Chrome (mg) 1.25E-02 1.24E-02 1.25E'()2 . 

AVERAGES 

Pa Absolute pressure of Flue Gas (In HG) 30.14 30.14 30.14 

Vwstd Volume of Water Vapor (SCF) 1.37 1.37 1.74 

Vmstd Volume of Metered Gas (OSCF) 93.287 92.947 93.924 

M Moisture (%) 1.45 1.45 1.81 

Va Velocity (FPS) 50.98 51.49 51.13 

Qaw Volumetirc Flow (ACFM) 17,084 17,254 17,133 

Qsd Volumetric Flow (OSCF) 16,736 18,966 16,848 18,849 

Chromium Concentration (mglDSCM) 0.0047 0.0047 0.0047 0.00471 

Chromium Concentration (lbMr) 2. 97E-04 2.99E-04 2.97E-04 2.98E-04 

lsokenetic (%) 101.01 99.29 101.03 
Armoloy Corporation 

DeKalb, lJIiDols 

RMCElNC~ltago RegfoaaJ Omce 

Project #2006-13517 

APPENDIX B. FIELD DATA SHEETS 

Method 1-Data Sheet 

Method l-S Sampbg Dlta Sheet 

FaelUty Process Data 
METHOD 5 - DETERMINATION OF PARnCULATE EMISSIONS - RESULTS 

Plant Name Amtol~ 

Sampling LocatIon UnltZ 

Operator TS 

Hlstorfcal Data 

Run Number U2-M306-1 U2-M31l8-2 

Run Start Time 10:30 8:30 

Run Stop TIme 12:30 10:30 

Mater Calibration Factor (Y) 0.989 0.989 

PItat Tube CoeftIcient (~ 0.840 0.840 

AdUaJ Nozzle DIarMter (0,.) 0.239 0.239 

Stack Test Dcta 

initial Meter Vohnno (V".), 633.949 731.878 

Final Met ... Volume (V.,), 731.112 832.875 

Tatal Meter Volume (Vm> 97.163 100.797 

Total TIme (9) 120.0 120.0 

Average M .... TempualUre tY- 52.1 42.8 

Average Stack Temperature tl.>- 80.5 63.1 

Barometric Pressure (P.) 30.04 30.02 

Stllek Static Pressure (P..,) 0.17 0.17 

AbsDlute Stack Pressure (P,) 30.05 30.03 

Average OrIfIce Prosaure Drop (AH)M 2.18 2.42 

Absolute "..,. Pnsaure (P~ 30.20 30.20 

AV1J SqUlllll Raat PIlot Pressure (~'~- 0.80 0.85 

MoistIn eom.nt DIIta 

Implnaer- 1-3 Weter Volume tJaIn (V,,) 12.0 17.0 

Impn" ..... Sib Qet WeIght (JaIn rN") 13.8 15,4 

Total Water VDlume Collected (V,,,) 25.8 32.4 

Standard Water V8INX'Volume (V.J.,., 1.218 1.526 

Standard Mater Volume (v..>.t 99.992 105.702 

c.Jcu1aled Stack Moishlre _~ .. Jl 1.2 1.4 

SaturatH Stack MaistIInt (B..t .... ll 1.71 1.9 

Reported Stack Moisture COIIIent (e....> 1.2 1.4 

au Analysis Data 

Carbon DIoxIde Percentage ('%COz) 4.0 4.0 

Oxygen Percentage (%OZ) 20.0 20.0 

Carbon Monoxide Percentaae (%CO) 0.0 0.0 

Nitrogen Percentage ('!6Nz) 78.0 78.0 

Dfy ca.. MaIec:uIar WeIght (M.s) 29.44 29.44 

Wet Stack ca.. Molecular WeIght (MJ 29.30 29.28 

Cclculaled Fu.I FactDr (F..) 0.225 0.225 

Fuel F..flllCtor (Fill 0 a 

Percent Excess AIr ~EA) 31250.0 31250.0 

Vo/umeb1c Flow Rate Oat. 

Aver ... Stack Gas Velocity (VJ 44.44 47.17 

St.ldc Cross-secuon.l AIM (N 5.59 5.59 

ktuaI Stack Flow RIa (a..,) 1.ftm 15807 

Wet Standard Stack flow Rate (Q..) 910 981 

Dry Standard Stack Flow RIa (0.) 14991 15787 

Percent of isoldnetic Rate (I) 99.8 100.0 

Emfsslon Rate oar. 

Mass 01 PartIcu .... on Filter (lilt) 

Mass of Patticulide In Acetone (m.') 

... due to Acetone Blank (WJ 

Total Mass of Partlculatu (m,,) 

Stack PartJcuJate Concentrldtan (cJ 

(cJ 

Partlculcte Emission Rate (E) 

(E) 

(El 

IPt75~FSIoct. 5.2."Heat Input (HI) IONIOI ,olYlOl 

Armoloy-Unit 2 - M5 - Re&UIt& Page 1 

U2-M308-3 

11:10 

13:10 

0.989 

0.840 

0.239 

832..875 

935.298 

102.423 

120.0 

49.8 

64.9 

30.02 

0.17 

30.03 

2.47 

30.3) 

0.88 

18.0 

15.8 

33.8 

1.592 

105.949 

1.5 

2.1 

1.5 

4.0 

20.0 

0.0 

78.0 

29.44 

29.71 

0.225 

0 

31250.0 

47.84 

5.59 

15985 

987 

15881 

99.7 

tolVlO! 

Date 2i28-!I1/2008 

Project. 2006-13527 

Stack Type Cln:uIar 

Averaga 

hh:mm 

hh:mm 

In 

It' 

tt' 

100.128 tr 

120.0 min 

48.1 OF 

62.8 DJ: 

30.03 InH1a 

0.17 InHP 

30.04 In HII 

2.35 InHP 

30.20 In He 

0.84 (In Hp)'1l 

15.7 nil 

15.0 9 

30.7 mt 

1.445 set 

103.881 dscI 

1.4 % 

1.9 % 

1.4 % 

4.0 '16 

20.0 '16 

0.0 '16 

78.0 '16 

29.44 IblliHnolo 

29.28 Iblll>m% 

0.225 

0 datflmmBlu 

31250.0 % 

48.42 It/sac 

ft"_ 

15555 acfm 

948 Vt'bc:th 

15553 dsefm 

99.8 % 

mg 

mg 

rnu 

mg 

gJdscf 

gr/dscf 

k;/h! 

Ib&Ihr 

IbsImmBtu 

I1l/IISlUIHr 

Printed 3I28l2006 

V1.15 
METHOD 1 - SAMPLE AND VELOCITY TRAVERSES FOR CIRCULAR SO.URCES 

Plant Name """ ..... , Date 2I28-3I1J2008 

SampUJlI LocaUon Unit 2 Protect' 2006-13527 

Operator TS • of Ports Available 2 

Stack Type CircuJar • of Ports Used 2 

Stack Size llargo Port inside Diameter 5 

L,w Circular Stack or Duct Diameter 

DIstance to Far Wall of Stack (4.) 37.00 n V ~ f--LnWDIstance to Near WaD of Stack (L..) 5.00 n ;/ pUw-1IIW) DIame_ of Stack (0) 32.00 n I~-\ r-

(-.l. U(DllA:IftIa)21 Aru of Stack CA.) 5.59 it" 

IDlatance from Port to DIs1urbancQ 0 

I--

DlstanceU CBl 44.00 n 

I~-'i (-lID) Dlamet:en U (80) 1.38 cfiametBra ....... 

DIstance Downstream CA) 17.00 in 

f-M)) DIame ..... Downstream (Ao) 0.53 diametIn 

T'r- Downstream Number of Traverse PoInts Required 

Dlametento Minimum Number Ott A + Disturbance 

Flow DIsturbance Traverse Points 

Up Down PartIcUIaIe Velocity ~ -, Measurement 

strum strum PoInts PoInts ~ I--' Site 

2.00-4.99 0.50-1.24 24 16 

5.00-5.99 1.25-1.49 20 16 t 6.0~.99 1.50-1.74 16 12 

7.00-7.99 1.75-1.99 12 12 B 

>=8.00 >--2.00 8or1~ 8or1~ 

U SIHlC 24 16 

Downstresm IDee 24 16 ~ceQ,"" 

Traverse Pta Required 24 16 Disturbance 

Chock MInImum Number 01 PoInts far the Upstream ........ :r 

and DDwntJarMm condItJons, Ihun use the IalgISt. Number of Traverse Pamts Used 

Z 8 fat CImdar Stacks t 2 CD :u InchOG 2 portsiW 12 Across 

12 fat ctrwIar Stadls 0'IIf' 2'" Inches 24 PtsUsed 24 I Requlred 

[,,] ParUculace [] V.,ocftV 

Traverse PoInt LocaIIons 

lAa$a otTrn ... PalaU Ia ClrcIdIor .... FracUon DIstance Dbtance 

n_ rp_tieD of Stack Oiamdcr Ii .... "'tid .. Wd II> T .. _ Poinl\ Travene of tram Including 

Poi .. Number alTrav_ PoiaI. oa a Ci ___ PoInt Stack Insld. Nip.,. Numb .. 2 4 Ii II 10 12 

1 .1'" .fW1 .o.u .m .026 JlZl Number Dfameter Wall LenatIt 

2 .854 .1!0 .1-" .105 .oa .DIi7 In in 

.J .7!IJ ..%95 _1,. .1'*5 .us 1 0.021 5/8 55/8 .. 3.J,J .704 ..n.J .2l6 .177 

5 .15& .m .,3.C .l!IJ 2 0.067 21/8 71/8 

6 .9!6 .805 .6!1f .J!6 3 0.118 36/8 86/8 

7 .895 .77" .6-U 4 0.177 55/8 105/8 8 .9Qt .ss.a _7!IJ 

9 .918 .au 5 0.250 8 13 

10 ~ .. .-z 8 0.356 113/8 163/8 

11 -'lJ 7 0.644 20518 25518 12 -'" 

8 0.750 24 29 

9 0.823 26318 31318 

10 0.882 28218 33218 

11 0.933 297/8 34 7/8 

12 0.979 313/8 36318 

Armoloy-Unit 2 - M1 - Circular Page 1 Printed 312812006 

Vt.15 
METHOD 2 • DETERMINATION OF STACK GAS VELOCITY AND VOLUMETRIC FLOW RATE 

Plant Name AnnoIq Date 2Q8.3I112OO6 

SampUnaLocadon Unit 2 Project' 2006-135'Zl 

OperdOr T8 • of Pods Used 2 

StaclcType Circular PIlot lcIeIdItIcdIon 

PIlot Leak Check 0 I PleTest 1 0 1 PostTest PItcI Coellldenl (C~ 0.84 

Stack Dimensions Ve1oc1y Traverse Data 

DIameter or length of Stack (D) 32.00 in Run Number U2-M306-V1 

WIdth of StacIr lWl in Rlln1lme 

Aru of StacIe CAs) 5.59 tr T,..".,. Velocity Stack Local 

Point Head Temp Velocity 

Pressu .... (Ap) (tJ (v~ 

Baromatrtc PressUN (P~ 30.04 inHg in H20 0,: ftJsec 

StatIc Pressure (P....J 0.17 inH:zO A-1 0.78 72 49.4 

AbsoIUIe StacIt PressUN (P.) 30.05 inHg A-2 D.n 72 49.1 

A-3 0.72 72 47.4 

Stack Gas Com A-4 0.74 73 48.1 

Composition Data:1 Actual [,,] EstrmatacI [] A-5 0.68 73 46.1 

carbon DIoxide Conc.ntraIIon (%C02l 4.0 .. A-8 0.63 72 44.4 

OXygen Concentration ~~. 20.0 .. A-7 0.78 73 48.8 

carbon MonoXIde ConceIdraIIon (IlftCO) 3.0 .. A-8 0.73 73 47.8 

Nitrogen Conceldradon (Ilft~ 73.0 .. A-9 0.78 75 49.5 

StacIr MoIItUN Conrenl (B.) 2.000 A-10 0.82 75 50.8 

Stack Dry Mofecutar WeIght (Mill 29.44 !bAIHnoftt A-11 0.74 74 48.2 

Stack Wet Molecular Weltht (M.) 29.21 lbf1b.mole A-12 0.63 74 44.5 

B-1 0.78 75 48.9 

Resulis B-2 0.79 75 49.8 

Avg Stack Gas VeiocIly (v.) 47.8 ftIsec B-3 0.72 74 47.5 

Avg StacIr Dry 8td Row Rate (Q..) 931418 dac:fltr B-4 0.73 74 47.9 

Avg Stack Dry 8td Flow Rate CQ..) 15524 dac:fhnin B-5 0.88 73 48.1 

Avg Stacie Wet Flaw Rate (Q .. ) 15939 ascfAnin B-6 0.80 73 43.3 

B-7 0.66 73 45.5 

Stac:t Crass 8ectIon 8chemaItc B-8 0.69 75 48.6 

A. ::I DWIKu for Rectangular Stacks 

A. ::I (n(Df.2),)A<v for Circular Staclas 

where Ku .. 1 for metric units 

where Ku " 144 (In2mZ) for English unils 

p. ::I Pilii' + P1IIIIII13.6 

%N2 ::I 100 - %C02 - %02 - %CO 

Md::l .44{%COz) + .32(%02} + .2S(%N2 + %CO) 

M." Md(1 - B.> + 1SB.. 

~)'IZ_ • '/,.E(Jp'~ 

Armoloy-Unit 2 - M2 

8-9 o.n 74 49.1 

8-10 0.83 74 51.0 

8-11 0.79 74 49.8 

8-12 0.67 75 45.9 

Average 0.85 74 

PIMse r.port Il1o cmra;e fII tile sqtr8ID RIOIs 01 

olp. at. (jp) 'IZ _ .. '/,.t(,lp 'a, 

Formulas Used 

TI(I\9I"I/A + Tu 

where Tu ::I 273 OK for metric unita 

where Tu .. -480 OR for Engliih uniCa 

v •• Kp~)'IZ.., (r.,..q/f1»,Md)'1l 

when! K, " 34.97 for metric una 

where K, ... 85.49 for EngIlah units 

a..s ... 36OO(1-s..)veA.(T.JT~)(PJP~ 

whet8 T lilt '" 293 X p ... 760 mm Hg. for meflic units 

where T l1li = 528 'R. p ... 29.921n Hg. for English units 

, 

Page 1 Printed 312812006 

V1.1S 
METHOD 3 - GAS ANALYSIS FOR THE DETERMINATION OF DRY MOLECULAR WEIGHT 

Plant Name lA, .... Date 2J28..3I1J2008 

&Ulla Loc:atlon UnIl2 PrOJect" 2QC6.13527 

Operator TS , of Porta Used 2 

FueJType NlA I MInimum Fuel Factor I Maximum Fuel Factorl 

Oraat Leak Check ~ I PreTest I 

Run Number U2-M306-1 

Sample Carbon carbon 

Analysis DIoxide Oxygen Monoxide 

nme Volume Volume Volume 

(Veaz) (VgJ (VCQ) 

hh:mm mI m mI 

FYRITE 4.0 24.0 

4.0 24.0 

4.0 24.0 

Results Avera~es 

Average cafculated Fuel Factor (~ 

Average ExceN AIr (%EA>-

Run Number U2-M306-2 

Sample carbon C&rtMIn 

Analysis Dioxide Oxygen Monoxide 

nme Volume Volume Voluma 

(Veaz) (Voz) (Veo) 

hh:mm mI mI mI 

FYRITE 4.0 24.0 

4.0 24.0 

4.0 24.0 

Result. Averages 

Average calculated Fuel Factor (F.J ... 

Average ExCttN Air (%EA) ... 

Run Number U2-M308-3 

Sample Carbon carbon 

Analpls DIoxide Oxygen Monoxide 

nme Volume Volume Volume 

(Vc:ozl (Voz) (Veo) 

hh:mm ml mI mI 

FYRITE 4.0 24.0 

4.0 24.0 

4.0 24.0 

Resulb Averages 

Average caJculated Fuel Factor (FJ .... 

Averaae EJrceu AIr (%EA).., 

Fuel Factor Po 

FueJType Minimum MaxImum 

Coal, Anthraclt. 1.018 1.130 

CoaI,Ugntte 1.018 1.130 

Coal, BHumlnoua 1.083 1.230 

Oil, Distillate 1.260 1.413 

Oil, Residual 1.210 1.370 

Gu, Natura. 1.600 1.838 

Cas, f!ropane 1.434 1.588 

Gas, Butane 1.405 1.553 

Wood 1.000 1.120 

Wood Bark 1.003 1.130 

Armoloy-Unit 2 - M3 - Orsat 

~ I PostTest Ontat ldentltlcatloni 

GIla AnalysIs Data 

Run Start nme 10:30 RunStopnme 

carbon CaIbon DIy 

DIoxide Oxygen Monoxide Nitrogen Molecular 

Cone. Cone. Cone. Cone. Weight 

~ (%Oz) (%CO) (%Nz) (MJ 

percent pen;ent perad pen:ent lbmHnoIo 

4.0 20.0 0.0 76.0 29.44 

4.0 20.0 0.0 78.0 29.44 

4.0 20.0 0.0 78.0 29.44 

~.O 20.0 0.0 L8.0 29.44 

0.225 Molecular WI Deviation < 0.3? 

31250.0 peReflt Fuel Factor In Handbook Range? 

OUAnalysls Data 

Run StArt nme 8:30 RunStopnme 

carbon 

Dioxide Oxygen 

Cone. Cone. 

~ ('lOz) 

pen:cnt pen:ent 

4.0 20.0 

4.0 20.0 

4.0 20.0 

4.0 20.0 

0.225 

31250.0 ~ 

oaa Analysts Data 

Run Start nme 

Carbon 

Dioxide 0Xy;en 

Cone. Conc. 

(%COz) (%Oz) 

~ pen:ent 

4.0 20.0 

4.0 20.0 

4.0 20.0 

4.0 20.0 

0.225 

31250.0 pen:ent 

carbon Dfy 

Monoxide Nitrogen Molecular 

Cone. Cone. WeIght 

(%CO) (%Nz) (~ 

I)eR:eft ~ !bIIb-rnoIe 

0.0 78.0 29.44 

0.0 78.0 29.44 

0.0. 78.0 29.44 

0.0 78.0 29.44 

Molecular WI DevIaUon < 0.3? 

Fuel Factor In Handbook Range? 

11:10 RunStopnme 

carbon Dry 

Monoxide NItrogen Molecular 

Cone. Cone. WelQht 

(%CO) (%Nz) (IY 

percent ~ IIIJb.maIe 

0.0 78.0 29.44 

0.0 78.0 29.44 

0.0 78.0 29.44 

0.0 1'8.0 29.44 

Molecular WI DevIatIon < 0.3? 

Fuel Factor In Handbook Range? 

Formulas Used 

~"Vc:oz 

%Oz • VOl. -Vcoa 

%00:11 Veo - Vea 

%Nz = 100 - %COz - %~ - %CO 

12:30 

Molecular 

Weight 

DevIatIon 

(.1M~ 

IbIIIHnoIe 

0.00 

0.00 

0.00 

~ f 

[o!) 

10:30 

Molecular 

Weight 

Deviation 

(.l.M,,) 

lbIIb-mafe 

0.00 

0.00 

0.00 

~ 

~ I 

13:10 

Molecular 

Weight 

DeviatIon 

(~ 

Ib.1IHnaIe 

0.00 

0.00 

O.CO 

iii f 

iii 

~ = .44(~+ .32(%~)+ .28(%Nz+ %CO) 

Page 1 Printed 312812008 

V1.15 
METHOD 4 - DETERMINATION OF MOISTURE CONTENT IN STACK GASES 

Plant Name Annoloy Date 2128-31112006 

8ampBna LocatIon Unit 2 Projecttl 2006-13527 

r T5 "of Ports Used 2 

8tacIr~ Cin:uIar Meter Box Number 1 

Train Leak Check [,,] I PreTest I ["1 I PostTest Meter Cal Factor (y) 0.989 

Run Number U2-M306-1 

Total Meter Volume NrJ 97.163 

AvgMarTemp ttm>- 52 

AVV81ac1r Temp (tJ.., 61 

Implnger1 

mI 

Contents NaOH 

Final Value M}.~,) 110.00 

InJIIaI Value M).~,) 100.00 

Nit Value N,J.~,J 10.0 

ToCaIVoCuma N~ 12.00 

Total Weight ~~ 13.80 

Std Meter Valwne (V!I(") 99.992 

Calc Moisture Content (B.CIIt:,) 1.2 

Run Number U2-M306-2 

Total MeterVoIume NrJ 100.797 

Avg Meter Tem, <t.n>- 43 

Avg Stacie Temp (t.) .. 63 

fmplnger1 

mI 

contents NaOH 

FlnalValua M).C'N,) 112.00 

!nidal Value N,).(W,) 100.00 

Net Value (vnl.~nl 12.0 

Total VolUme (Vtl 17.00 

Total WeIght ~tl 15.40 

S1d M ... ,VoIuma (Vrr(aq) 105.702 

Calc Moisture content (B..) 1.4 

Ran Numbe, U2-M306-3 

Total Meter Volume J'ltn> 102.423 

AvgM ..... Temp ~ 50 

A'll Stack Temp tt.lwt 65 

1m"",.,' 

mI 

ContMts NaOH 

FlnalVaJ ... M).rNf) 111.00 

INUaIVafua (V,).~,) 100.00 

Net Value Nnl.rNrJ 11.0 

Total Volume (V~ 18.00 

TotaI_~ht ~~ 15.80 

Std Metar Volume "'-~~- 105.949 

calc Moisture Content (e.> 1.5 

Armoloy-Unit 2 - M4 

Moisture Content Data 

Run Start TIme! 10:30 Run StoP TIme 12:30 

dct Barometric Preu. (PtJ 30.04 InHg DF stack 8bIdc Press. (PIIIIIIJ 0.17 InHzO 

"'F Avg Orlftce Pntss. (M1lz.v 2.16 InHzO 

ImplnaarZ 1m1llnaer3 Impbtg.,,, ImJ'lngerl lmplnger6 Impfnger7 

mI rnI a mI mI mI 

NaOH Sil Gel 

102.00 163.80 

100.00 150.00 

2.0 13.8 

Ruub 

mI Water Vol Candennd NWQ'AII) 0.565 ac:f 

9 Water Vol WeIghed (V_san> 0.651 ad 

dad SaL Moisture COftIenI (8...ro.o') 1.8 

"- final MoIsture ConIanI (B..) 1.2 '" '" 

Moisture Content Data 

Run Start Tlmel 8:30 Run Stopnme 10:30 

dcf BarometrIc Press. (1\) 30.02 inHg ~ Stack StatIc Press. (P....J 0.17 inHzO 

"F Avg ormce Pm .. (~ 2.42 inHzO 

Implngerz Irnlllnfler 3 rml){ngar " Implnger' flnpfnger6 imPinge, 7 

mI "" a mI mI ml 

NaOH Sil Gel 

105.00 165.40 

100.00 150.00 

5.0 15.4 

ResufIs 

mI Water Vol Condensed (V-.1Id)) 0.800 sc:f 

9 WIler Vol WeIIhtId N .. -> 0.726 sc:f 

dsc:f Sat. Moisture CordInt ~ .. \ 1.9 % 

% final Moisture ContMt (B..) 1.4 % 

Moisture content Data 

Run Start TIme! 11:10 Run Stop TIme 13:10 

dcf 8aromeCrfc Press. (P,,) 30.02 inHg 

"F Stacfr StaIIc Press. (P..J 0.17 InHzO UF A'll OrHlce Press. (~ 2.47 inHzO 

hnpfnger2 Implng,r3 fmllfnler .. hnplngor5 flnplnferl lrnplnger7 

mI mI a 

NaOH Sit Gel 

107.00 165.80 

100.00 150.00 

7.0 15.8 

Results 

ml Water Vol Condensed 

0 WalarVoi Wefghed 

dsef Sat. Moisture Content 

'" FInal Moisture Canteftt 

Page 1 

mI mI 

(V'III:IatIIl 0.847 

N ... SIIJ)) 0.745 

.CB..III4I') 2.1 

(8".) 1.5 

mI 

set 

sc:f 

% 

% 

Printed 312812006 

V1.1S 
ISOKINETIC SAMPLING DATA 

Plant Name Annoloy 

SamSlGna Locatfon UnIl2 

18 

#I of Polms Acrau 12 

Ideal Nozzle DlMMtw and laoKInetIo Factor Setup 

PIlot Tube Coefllclent tOp) 0.840 

Avg Stack Temp (t.) 70 "F 

Avg Gal ....., Temp (t",) 38 of 

DH .0.71 SCFM (AHO) 1.87 "'HaO 

Avg PIlot Tube DIff. Preaure {~ 0.75 InHaO 

Stack IIGimn ConfIInt (B..) 2.0 

Stack Dry MoIecuI8r WeIght (M...) 29.44 ~ '" 

E.stfmated DrIftce Flow RIte (a".) 0.750 IIdm 

DP to DH Isoklnetlc FIICtor (K) 3.32 

Preuuru 

&.nMnetrIc: Pntuure (Pill 30.04 In Jig 

StIIdr Sratlo Pruaure (P-> 0.17 "'HaO 

AbsoIuIe stack Pntuun (P.) 30.05 In Jig 

Absolute Metv PreNunt (P..,) 30.18 InHg 

DryGaa DuIJed 

TraYeIM SanpIIng Clock ..... VeIocfly OrIfIce 

Point. TIme Time Rudin. Heed ~ 

(9) (V.,) (Jp) (~ 

mill hh:mm:8& It' IIIHzO inHzO 

A-1 0.0 10:30:00 633.949 0.580 1.928 

A-2 5.0 10:35:00 637.701 0.840 2.125 

A../3 10.0 10:40:00 841.821 0.710 2.358 

A-4 15.0 10:45:00 845.832 0.730 2.42" 

A-5 20.0 10:50:00 650.327 0.690 2.291 

A-6 25.0 10:55:00 654.<406 0.640 2.125 

A-7 30.0 11:00:00 65B.S40 0.750 2.490 

A~ 35.0 11:05:00 682.E$33 0.730 2.42" 

A-9 40.0 11:10:00 668.897 0.680 2.258 

A-10 45.0 11:15:00 671.023 0.840 2.125 

A-11 SO.O 11:20:00 675.021 0.580 1.928 

A-12 55.0 11:25:00 878.871 0.590 1.959 

8-1 60.0 11:30:00 682.776 0.590 1.959 

8-2 65.0 11:35:00 888.789 0.870 2.225 

B-3 70.0 11:40:00 690.781 0.720 2.391 

B-4 75.0 11:45:00 695.192 0.730 2.424 

B-S SO.O 11:50:00 699.483 0.880 2.258 

B-8 65.0 11:55:00 703.587 0.800 1.992 

B-7 90.0 12:00:00 707.893 0.580 1.959 

B-8 95.0 12:05:00 711.784 0.560 1.B60 

B-9 100.0 12:10:00 715.223 O.6Sl 2.158 

8-10 105.0 12:15:00 719.332 0.610 2.026 

8-11 110.0 12:20:00 723.218 0.580 1.928 

8-12 115.0 12:25:00 TZl.2B3 0.640 2.125 

LaatPt 120.0 12:30:00 731.112 

Last PI 120.0 12:30:00 731.112 

Average Values 0.65 1 

ArmDloy-Unit 2 - M5 - Run 1 Page 1 

Date 2J28.3I112C08 

Project. 200&-13527 

Run. UZ-M308-1 

#I of Porta U.1d 2 

SamplJnj I Equfoment 

..... , 

Maerbox CaL FIIdor (Y) 0.989 

Nozzle. 

~ Nozzle ct.n.t. (On.) I 0.2390 In 

Reel. Nozzle DIIIIMCer (Dr.) I 0.2274 In 

Probe ., LenGth 48.00 It LIner,...,.., Scm,.. Cue lOVen' 

Implnger Cae • 

.1v. LeakChacb 

Pre 0.002 rlnm • 1S InHg 

Mid ~hnin • lnHg 

Pat 0.001 r/mln • 1 .. InHo 

.1V. c 0.020 rlrnkl iii LHk Check OK? 

PltatOK? m OnatOK? ~ 

AcIuaI Meter ... ImpInger 

0riIIce Stack rn'-t OUtlet Filter Exit Pump 

JH Temp Temp Temp Temp Temp Vacuum 

(JH) (t,,) (t.,d ('t,.J 

InHP '"F OF or: OF "F InHO 

1.900 83 42 42 40 3.0 

2.100 83 48 43 40 3.0 

2.400 82 50 44 40 3.0 

2.400 81 52 45 40 3.0 

2.300 60 54 48 40 3.0 

2.100 60 55 47 40 3.0 

2.500 eo 54 48 40 3.0 

2.400 81 55 48 40 3.0 

2.300 eo 54 47 40 3.0 

2.100 58 55 49 40 3.0 

1.900 57 55 48 40 3.0 

2.000 57 66 50 40 3.0 

2.000 56 55 50 39 3.0 

2.200 56 54 49 39 3.0 

2.400 60 58 51 40 3.0 

2.400 58 59 51 39 3.0 

2.300 60 59 52 40 3.0 

2.000 81 59 51 40 3.0 

2.000 64 59 52 41 3.0 

1.900 65 60 53 41 3.0 

2.200 83 59 53 41 3.0 

2.000 62 60 53 '" 3.0 

1.900 82 59 54 41 3.0 

2.100 83 59 53 .f2 3.0 

Maxlmum V*'IUm 3.0 

2.18 j 61 I 55 491 I 40 

I 52 I 

Printed 312812008 

V1.1S 
.SDKINETIC SAMPUNG DATA 

PlantNamo Annolov 

SemDftlus Location Unit 2 

TS 

• of PoInts Acrou 12 

Ideal Nozzle DIametw and lsoKlneClc Fac:tvr Setup 

Pilot Tube Coefficient ~~ 0.840 

Ava Stack Temp (I.) 70 "F 

Avg Gas Meter Temp (t",) 38 OF 

DH .0.76 SCAI (..UfO) 1.87 InHP 

Avg PIlat Tube DIlL Pressure (Ap..J 0.75 InHP 

st.cIc IIIDIstIn CGrI1ent (B.) 2.0 '" Stack Dry Molecular w.tght (M,.) 29.44 IbIIb-mDie 

EatImated OrifIce Flow Rde (0..,) 0.810 acfm 

DP to DH Isakfnetlc Factat (K) 3.32 

Preuuru 

Barometrtc Pressure (Pt,) 30.02 InHg 

Steck Sialic PrcIAure (P-J 0.17 InHP 

Absolute Stack PrHsunI (PJ 30.03 In HI 

Absolute Meter Preuure (P.,,) 30.18 InH. 

Dry Gas DesIred Actual 

Traverse Sampling CIocIc ....... Vdocfty CrtfIce OrIfIce 

PoInt. Time Time Reading Hud .iH .\If 

(8) (V.,) (41') (.1H) (.ut) 

min hh:mm:sa It' InHP InHP InHP 

A-1 0.0 8:30:00 '731.878 0.830 2.758 2.700 

A-2 5.0 8:36:00 738.283 0.820 2.723 2.700 

1.-3 10.0 8:40:00 740.602 0.750 2.480 2.500 

A-4 15.0 8:46:00 745.078 0.710 2.358 2.400 

A-5 20.0 8:50:00 748.978 0.670 2.225 2.200 

A-6 25.0 8:55:00 752.888 0.&40 2.125 2.100 

A-7 30.0 9:00:00 758.952 0.740 2.457 2.500 

MJ 35.0 9:05:00 781.ose 0.780 2.524 2.500 

A-9 40.0 9:10:00 785.421 0.660 2.192 2.200 

A-10 46.0 9:15:00 769.454 0.600 1.992 2.000 

A-11 50.0 9:20:00 173.384 0.690 2.291 2.300 

A-12 55.0 9:25:00 777.424 0.890 2.955 3.000 

B-1 60.0 9:30:00 782.112 0.760 2.524 2.500 

B-2 85.0 9:35:00 788.389 0.790 2.823 2.600 

B-3 70.0 9:40:00 791.089 0.720 2.391 2.400 

B-4 75.0 9:45:00 795.000 0.130 2.424 2.400 

B-6 SO.O 9:50:00 799.212 0.680 2.258 2.300 

8-6 85.0 9:55:00 803.223 0.600 1.992 2.000 

B-7 90.0 10:00:00 807.128 0.660 2.192 2.200 

B-8 95.0 10:05:00 811.193 0.690 2.291 2.300 

8-9 100.0 10:10:00 815.221 0.770 2.567 2.600 

B-10 105.0 10:15:00 819.873 0.830 2.758 2.800 

8-11 110.0 10:20:00 824.189 0.790 2.823 2.600 

8-12 115.0 10:25:00 828.455 0.670 2.225 2.200 

Last Pt 120.0 10:30:00 832.875 

FlnalVaJue 120.0 10:30:00 832.875 

Average Values 0.73 J I 2.42 1 

Armo/oy--Unit 2 - MS - Run 2 Page 1 

Dam 2128-31112008 

Praject. 2008-13527 

Run. U2-M308-2 

• of POIts Used 2 

Samplinl E ... .i-.U...i 

Mar. 1 

MeteIbox CaL Fector M 0.989 

Nozzle. 

Aau-' Nazzle oc.mew (D"J 0.2390 In 

Reel. Nozzle ~ ~ 10.2363 In 

Prabo ., Lenath 48.00 It 

U.,., MaterIal 

Sample Cue I Oven tI 

Can. 

olV .. Lukcttecb 

life 0.001 rmm • 1S inti; 

IIld rlmln • In HI 

Post 0.001 rlmln • 1~ InHg 

olV. < 0.G20 rhnln ~ LeIk Check OK? 

PttDtOK? 

..... StIIcIc fnfe 

Temp Temp 

(t.) (Y 

OF OF 

81 34 

65 36 

65 :fl 

88 39 

fil 41 

fil 42 

68 43 

85 43 

58 47 

69 47 

61 47 

60 47 

59 48 

B3 47 

82 47 

62 47 

63 48 

62 47 

64 49 

B3 49 

64 49 

83 50 

64 50 

64 50 

831 45 

1 43 

eJ orsatOK? ~ 

.... 1mpIngOutlet Fibr exit Pump 

Temp Temp Temp Vacuum 

(t...,) 

. OF OF OF InHg 

32 «> 3.0 

34 40 3.0 

35 40 3.0 

:fl 40 3.0 

38 40 3.0 

«> 39 3.0 

39 39 3.0 

40 39 3.0 

38 39 3.0 

39 39 3.0 

40 40 3.0 

«> 40 3.0 

«> 40 3.0 

42 40 3.0 

42 39 3.0 

42 39 3.0 

41 39 3.0 

42 40 3.0 

42 40 3.0 

41 40 3.0 

44 41 3.0 

44 41 3.0 

43 41 3.0 

45 41 3.0 

MaxImum Vaewm 3.0 

401 1 

1 

40 

Printed 3I28l2OO8 

V1.15 
ISOKINETlC SAMPUNG DATA 

PfantNamo AmtrAay 

Sampling Locdan Unil2 

TS 

#I of Polnb Acfou 12 

ldell Nozzle Clunetv' and Isol<tnetic Factor Setup 

Pltat Tube CoelftcJent <c..> 0.840 

Avg Stack Temp (tJ 70 of 

Avg Gas Meter Temp (Y 38 "F 

DH .. 0.7& SCFU (.UfO) 1.87 InHzO 

Avg PItct Tube DIfI'. Prusan (~ 0.83 InHzO 

Sblde Moisture Content (8.) 2.0 'It. 

Stacll Dry Mvlecular 'NeIgtd <M..) 29.44 IbIIb-maIe 

EatImat1td Oriftc:e Flow RIde (0,.) 0.840 acfrn 

DP to OM Isoldnetlc Factor (IQ 3.32 

Pnssuru 

8aramebtc Pressure (Ptol 30.02 In", 

Sblde Stade Prenure (P.-) 0.11 InHP 

Ab8ofu1e Stack~ (P,,) 30.03 In HI 

AbIIo/Ufe Meter Presatn (P",) 30.18 InHt 

DlyGu DesIred Actual 

Traver •• Sampling Clock Meter VeioclIy OrifIce Orifice 

Pointt TIme TIme ReadIng Had JH JH 

(9) (V",) (~) (~ (Mi) 

min Ith:mm:ss ~ InHzO InHzO IntlzO 

A-1 0.0 11:10:00 832.875 0.79 2.82 2.80 

A-2 5.0 11:15:00 a:r7.289 0.78 2.62 2.50 

PrJ 10.0 11:20:00 841.632 0.72 2.38 2.40 

A-4 15.0 11:25:00 &45.815 0.14 2.48 2.50 

A-5 :!D.O 11:30:00 850.117 0.68 2.28 2.30 

A-6 25.0 11:35:00 854.212 0.83 2.09 2.10 

A-7 30.0 11:40:00 858.329 0.78 2.52 2.50 

A-8 35.0 11:45:00 882.832 0.74 2.48 2.50 

A-9 40.0 11:50:00 868.721 0.71 2.58 2.60 

A-10 45.0 11:55:00 871.223 0.80 2.68 2.10 

A-11 50.0 12:00:00 815.788 0.78 2.59 2.60 

A-12 55.0 12:05:00 880.228 0.87 2.22 2.20 

B-1 60.0 12:10:00 884.013 0.12 2.39 2.40 

B-2 85.0 12:15:00 888.214 0.75 2.49 2.50 

B-3 70.0 12:20:00 892.004 0.88 2.28 2.30 

B-4 75.0 12:25:00 898.528 0.85 2.18 2.20 

8-5 SO.D 12:30:00 900.978 0.73 2.42 2.40 

B-8 85.0 12:35:00 905.318 0.71 2.58 2.60 

8-7 SO.D 12:40:00 909.704 0.81 2.69 2.70 

B-8 95.0 12:45:00 914._ 0.80 2.68 2.70 

8-9 100.0 12:50:00 918.897 0.78 2.59 2.60 

8-10 105.0 12:55:00 923.273 0.75 2.49 2.50 

8-11 110.0 13:00:00 927.385 0.14 2.48 2.50 

8-12 115.0 13:05:00 931.483 0.69 2.29 2.30 

lastPt 120.0 13:10:00 935.298 

0-8 

0-7 

Last Pt 

FfnalValue 120.0 13:10:00 935.298 

Aver~. Values 0.74 J 1 2.41 I 

Armdoy-Unit 2 - M5 - Run 3 Page 1 

Date 2128-31112006 

Pro.Lect. 1008-13527 Run. U2-M30&-3 

#I of Pons Used 2 

Sampllm E~~_ent 

Meter. 1 

MeleIbox Cal. Flldor m I 0.989 I 

Nozzle' 

ActwII Houle DIameter (D,.) 0.2390 In 

Reel. NDUIe DIametw (D,.,) 0.2514 In 

Probe. I LongIh 48.00 ft 

lJnIr IIateriaI 

s.mple Caal Oven. 

Implnger CUe. 

.lV. LeIlkChecb 

Pre 0.001 tt'lmln • 1" InHg 

MId ~lmln 0 InHg 

Put 0 r/mln • 13 InHG 

J.V.,. < 0.020 ~lmln ~ Leak Check OK? 

PttotOK? 

Meter 

S ... Inlet 

TCIIIIJ' Temp 

('t.) Ita) 

OF OF 

84 48 

85 49 

85 49 

84 48 

63 48 

83 49 

84 <48 

63 49 

63 48 

68 49 

87 50 

84 51 

87 51 

65 51 

84 52 

68 53 

65 53 

53 54 

f{l 55 

68 55 

88 55 

f{l 58 

64 58 

65 frT 

65 51 

50 

eI orsatOK? iii 

- impingei' 

0UdIt FIbr ExIt Pump 

Temp Temp Temp Vaewm 

('t..,) 

"F "F "F InHg 

45 41 3.0 

48 41 3.0 

48 41 3.0 

48 41 3.0 

48 41 3.0 

45 41 3.0 

45 41 3.0 

48 41 3.0 

45 41 3.0 

45 41 3.0 

48 40 3.0 

48 40 3.0 

47 40 3.0 

48 40 3.0 

48 40 3.0 

49 41 3.0 

50 41 3.0 

50 41 3.0 

50 41 3.0 

51 42 3.0 

51 41 3.0 

52 42 3.0 

52 42 3.0 

52 42 3.0 

Maximum Vacuum 3.0 

481 J 

I 

41 

Printed 3I28l2OO8 

V1.15 
METHOD 5 - DETERMINATION OF PARTICULATE EMISSIONS - RESULTS 

HbtoricaI Data 

Run Number U3-M3Q8.01 U3-M3Q6.0Z tJ3.M306-3 Average 

Run Start nme 10:30 8:30 11:10 hh:mm 

RunStDpnme 12:40 10:40 13:20 hh:mm 

Meter Calibration Factot (V) 0.955 0.955 0.956 

PItot Tube CoeflIc:MnI (<;) 0.840 0.840 0.840 

Actual Nozzfe DIameter (Dt.) 0.217 0.217 0.217 In 

Stack Teat Data 

initial Meter VDfume (V"". 223.048 882.967 984.397 r 

FInal Meter VoWlnO (V~ 318.955 976.153 1019.858 r 

Total Meter Volume (VrJ 93.909 93.188 95.481 9·'-185 Ir 

Total Samllflna TIme (9) 120.0 120.0 120.0 120.0 min 

Average MtIter TempendUre (Y_ 52.5 51.2 57.8 53.8 or: 

Aver-ae Stack Tem.,.cture <tJ- 75.'- 73.3 71.1 73.3 of 

8arDmeIrtc Prasunt (P~ 30.04 30.24 30.26 30.18 In Hg 

Stack StatIc Prusure (P-> 0.21 0.21 0.21 0.21 lnHzO 

Absolute Stacie Pressure (PO> 30.06 30.26 30.28 30.20 In Hg 

Average Ortftce Preuure Drop (~ 1.77 1.84 1.82 1.81 inHzO 

Absolute ..... Pru.ute (P,.) 30.17 30.38 30.39 30.31 lnHg 

Avg Square Root PIlat Pressure (~''").." 0.92 0.93 0.92 0.92 (In Hp)11l 

Mobtin CoIant Data 

Implngen 1-3 Water VDlume Galn (V,.) 18.0 15.0 19.0 18.7 mI 

Impfngv" SI8ca Gel Weight GaIn (W,.) 13.1 14.1 17.8 15.0 g 

Total Wider VDIume CoUected (V-.) 29.1 29.1 38.8 31.7 /III 

Standard Water Vapor VoIuIM (V.J.s 1.371 1.371 1.734 1.482 sci 

Standard Meter VDluru (V.J"" 93.181 93.322 94.435 93.839 dscI 

Calculated Stack MoIaIunt ca... .... J>_ 1.5 1.4 1.8 1.8 ." 

Satumad Stack Mafature (B..~ 2.95 2.7 2.5 2.7 % 

Reported Stack MoIsbn Cont.nl (8.) 1.5 1.4 1.8 1.8 % 

caaa AnaIy.1s Data 

Carbon DIoxfde Pen:entage rAtCOV 8.0 8.0 6.0 8.0 % 

Oxygen Pemtntage ~ 20.0 20.0 20.0 20.0 .% 

Carbon Monoxide ('l6CO) 0.0 0.0 0.0 0.0 

NI1rogen Pen:elltage (%Nz) 74.0 74.0 74.0 74.0 " % 

Dry caaa lfoIecuIar WeIght (M.s) 29.78 29.78 29.18 29.78 lbI1IHnoIe 

Wet Stack Gu Molecular Weight (M.) 29.59 29.59 29.55 29.58 IbItIHnoIo 

carculated Fuel Factor (F.) 0.150 0.150 0.150 0.150 

Fuel F.f=adDt (F.s) d5cU1nmBlu 

Percent Exc:eA ,. -("I.~- -4310.3 -4310.3 -4310.3 -4310.3 % 

VDlumetric FlDw Rate DIa 

Average Stack Qu Vefocity (YO> 51.03 51.42 51.08 51.17 ftINC 

SbIck Cron..sectlonal Ar. (A.) 4.28 4.28 4.28 r 

Actual Stack Flow Rata (Q..,) 13093 13192 13100 13128 adm 

Wet Standard Stack Flow Rate (e..,) 178 792 . 791 m wbcIh 

Dry Standard Stack Flow Rata (Oo.s) 12782 13017 12941 12913 dsdin 

Percent of Isoldnellc Rata (I) 101.1 99.5 101.2 100.8 % 

EmJa.ron Rate DIU 

..... of Puticulala on FItter (me) mg 

..... of PattIcufate In Aatone (m.') mg 

..... due to Acelane s.ntr (We> mg 

ToUI ..... of partlcuJatn (m,,) mg 

Slack PIII1k:uIete Conc:entndIon (c;) g/dscI 

(c;) trldscf 

PaJ1lcu/al. Emission Rate (E) kglhr 

(E) Ib6Itt 

(E) IbsImmSIu 

\,. 7S ~, led. U. It Heat 'nput (HI) "'AlUEI IVALUE! "'ALUEI mmBtunir 

ArmcIoy-unit 3 - M5 - Results Page 1 Printed 3J28I2OO8 

V1.15 
METHOD 1 - SAMPLE AND VELOCITY TRAVERSES FOR CIRCULAR SOURCES 

PlantN...,. ArmcIOY. Date 2128-311Q1YJ6 

SampUng Locallon Unit 3 PraJect. 2008-135ZT 

0 EQ II of Ports Avallallie 2 

8tactType Circular # of Ports Used 2 

StactSlze large Port inside DIameter 5 

L,w Circular Stack or Duct Clamefer 

DIstance to Far Wall of Stact (L,.) 33.00 In ~LnWDIstance to Near Wall of Staclt (L..) 5.00 In / ~ 

! \ - (-3.f4(~~ma 

(wUIr.lM) Diamttlll' 

of 

of 

Staclr 

stact 

(A.) 

(01 28.00 

4.28 ft'" 

In V\ I---

Dlltance from Port to DIsturbuM:ttI D 

t--

DbtanceU (8l 54.50 In 

\~-~ (alloO) DIameters U (So) 1.95 cfiamatars '-

DIstance Downstream CA) 15.00 In 

(-MIl Dlametln Downstntam (Ae) 0.54 diametI!rs 

T .--- Down streon"'l Number of Traverse Polnts Required 

Minimum Number ofl t 

Disturbance 

DIameters to A Flow DIsturbance Traverse Pornts 

Up Down PartIcuI;a Velocity P Meosuren-'l en t SIreanI Stream PoInts PoInts Site 2. OQ.4. 99 0.50-1.24 24 16 

5.00-5.99 1.25-1.49 20 16 

6.00-6.99 t 1.50-1.74 16 12 

7.00-7.99 1.75-1.99 12 12 B 

>=S.OO >--2.00 Sor1~ Sor1~ 

U s.-: 24 16 

Downatrum Spec 24 16 I ~reo"., Traverse Pts Required 24 16 Disturbon ce 

Check MInImum Numb« "'- =-l vi Points for the Up$tnNUn 

and Down5IrHrn condIIIcns, then USIt thelargo&t. Number of Traverse PoInD Used 

z 8 fw ClrcWu Staclcl12 to 241nchas 2 ParbbV 12 Across 

12 far CIA:uIer StIIcb 0Wf 24 indies 24 PtsUsed 24 IReclulred 

[0!1 PartIcUIatIe [] Veloc:ltY 

Traverse PoInt Locallons 

~m.~_T~p~q~"b Fraction DIstance DIstance 

lhv_ l1"r&ctiOil o(Sl8oi: Di~ &aaaliuill" W.D CD Tn_ Point} Traverse of tram Including Point Numbor alT_PoidaollaOi.- PoInt Stacie inside Nipple Numbor 2 4 6 II 10 Il 

1 .1'" .067 .044 .an .026 .IW Number DIameter Wall Length 

2 . ut .J!O .1'" .1OS •• JWT In in 

oJ .750 .l!J6 .~ .J'" .UI 1 0.021 5/8 55/8 4 .W .704 ..513 .ll6 .177 

5 JJM .677 ..uz .l5O 2 0.067 1718 6718 

6 .Hi JI06 .651 ,)56 3 0.118 32/8 82/8 7 .895 .774 .ut 4 0.177 5 10 I .!IQI .S54 .758 

9 .911 Ja.J 5 0.250 7 12 

10 ".,4 JIG 8 0.356 10 15 1.1 .!W 

u .!n9 7 0.644 18 23 

8 0.750 21 26 

9 0.823 23 28 

10 0.882 24618 296/8 

11 0.933 261/8 311/8 

12 0.979 273/S 32 318 

Armoloy-unit 3 - M1 - Circular Page 1 Printed 312812006 

Vl.IS 
METHOD 2 • DETERMINATION OF STACK GAS VELOCITY AND VOLUMETRIC FLOW RATE 

Plant Name Arrnoloy Date ~/2008 

Sampllna Locadon Unit 3 Prajec:t' 2006-13527 

OperalOr EQ ., of Ports UncI 2 

stackTwe Circulw PItGt IdeIdHIcadon 

PIlot Leak Check .~. 1 PreTest , [-!) I PostTest Pttot CoeftIdW (CPJ 0.84 

Stack DImensIons Velodly Traverse Data 

Dlmneter or Lenatfl of Stack (D) 28.00 in Run Number U3-M3Q6-V1 

WIdIh of Stack (W) In RunTIme 

Area of Stack (A.) 4.28 ft" Traverse VeIocfty Stack Local 

PoInt Head Temp Velocfty 

Pressures (Jp) (tJ (vslt 

BaromeIrIc Pressure (PIJ 30.08 inHg in H20 ~ ftJ&ec 

Stade Pressure (P..J 0.21 inH~ A-1 0.82 69 50.1 

Absolute Stack Pressure (Pal 30.10 inHg A-2 0.85 74 51.3 

A-3 0.89 75 52.5 

Stact Gas Com A-4 0.86 75 51.6 

ComDQSlllon Data:1 Actual [.I] EstImated [] A-5 0.82 75 50.4 

Carbon Dloxlde ConceJ1traIfon (%COz) 6.0 % J\.6 0.73 76 47.6 

OXygen Concentration J%O:z) 21.0 % A-7 0.71 75 46.9 

Carbon Monoxide ConcenbaIIon (%CO) 0.0 % A-8 0.78 75 49.2 

Nlbogen ConcenlJadon (%~ 73.0 % A-9 0.89 75 52.5 

Stact Moisture Contw1t (8.) 2.000 A-10 0.94 75 54.0 

Stack Dry Molecular WeIght (Mill 29.80 IbllHnole A-11 1.10 75 58.4 

Stack Wet Molecular WeIght (M.) 29.56 IbJIb.moIe A-12 1.00 75 55.7 

8-1 0.85 72 51.2 a ... _._ 

8-2 0.93 74 53.7 

A'll Stack Gas VeiocIly (val 51.8 ftIsec B-3 '0.91 75 53.1 

Avg 8tacfr Dry ltd FlGW Rate (Qm) n5469 d&c:fJhr 8-4 0.90 75 52.8 

Ave Stack Dry 8td Flow Rate (a..d 12924 dscfhnin 8-5 0.87 75 51.9 

Avg Stack Wet Flow RaSe (Q.> 13278 asdhnin ~ 0.85 76 51.4 

8-7 0.83 75 50.7 

Stack Crass Sec:tton SdlemaIk: B-8 0.82 75 50.4 

A. .. DWIKu fOf' Rectangular Stac:k8 

A. .. (lr(DJ2)2}JKy for Circular Stac:ka 

where Ku =: 1 for metric unita 

where Ku =: 144 frn2,onZ) for Engfaah units 

p ... p. + P_tJ13.6 

%Nz .. 100 - %COz -"°2 - "CO 

Md ... 44(%C~ + .32(%02) + .28(%N2 + %CO) 

M." M~1- Sw) + 1SB. 

(olp)'Q_ a '/~''i 

Arrnoloy-unit 3 - M2 

B-9 0.84 76 51.1 

8-10 0.96 75 54.6 

B-11 0.98 75 55.1 

B-12 0.97 76 54.9 

Av ..... 0.93 75 

Please report 1ho averago filth. SqtIaI'8 ~ fII 

olP. or. up}'fl __ ," '/"E(.lp'~ 

Formulas Used 

Ts(I\1I} = '/nIt. +Tu 

where Tu .. 273 OK for metric units 

where Tu = 460 OR for English units 

VI·ICp~)'Q .. (T .. ..I(P.M.»IQ 

where Kp .. 34.97 for metriG units 

where Kp .. 85.49 for Engllah uniIs 

a... .. 38:0(1 - 8w)v.A.(T sJT SC-.vI)(PJPsW 

where T SId .. 293 oK. PSId .. 760 mm Hg, for metric units 

where T", .. 528 OR, Pstd = 29.92 In Hg, for EngI'l&h units 

, 

Page 1 Printed 312812006 

V1.15 
METHOD 4 - DETERMINAT10N OF MOISTURE CONTENT IN STACK GASES 

PfantNamo 

aam,ana location 

Operator 

StacIrTypl 

Train Leak Check 

Run Number 

Total MtterVolume 

AvgMlterTemp 

Avg S1acIr Temp 

Contents 

FInal Value 

In.IIIaIValue 

Net Value 

Total Volume 

Totaf WeIght 

Std Meter Volume 

Calc Moisture Content 

RunNumbe 

Total Meter Vofwne 

Avg Meter Temp 

Avg Stack Temp 

Contents 

Final Value 

fnJtIaI Value 

Net Value 

Total Volume 

Total WeIght 

Std Mete, Volume 

calc Moisture Content 

Run Number 

Totat MeterVofum, 

Avg Meter Temp 

Avg Stack Temp 

CCMdeftts 

FtnaiVaJue 

InftIaI Value 

Net Value 

Total Volume 

Total Yftlght 

8td Mete,Vo!ume 

Calc Mafslure content 

Armoloy-unit 3 - M4 

Armoloy OGle 2f.Z8.3I1Q006 

Unit 3 PrOIecI. ~135'Z1 

EQ • of Ports Used 2 

CRuIar Meter Box Number .. 

[-!I I PreTest I [-!I I PostTest Meter Cal FactorM 0.955 

U3-M306-01 

(Vm) 93.909 

Ct..J- 53 

tt.>.. 75 

ImDlg,r1 

mJ 

01 

(V,),fN,) 110.00 

(VI)'(W~ 100.00 

(V.,),(Wn) 10.0 

(V,) 16.00 

(W,) 13.10 

(Vmeatlll 93.161 

(8...cS:.) 1.5 

U3-M306-02 

(V,.,) 93.188 

<tn.>- 51 

(t.).yg 73 

Implnaer1 

ml 

01 

(V,).(W,) 110.00 

(VI).(WI) 100.00 

(V.,),(W.,) 10.0 

(V.) 15.00 

(W.) 14.10 

(Vn(.,) 93.322 

(B.) 1.4 

U3-M306-3 

(V,J 95.481 

(t...>- 58 

~ 71 

1mp(nger1 

mJ 

01 

(V,),(W,) 112.00 

(VI).(W.) 100.00 

(V.,),~.,) 12.0 

(V~ 19.00 

CN~ 17.80 

(Vrrtflltll) 94.435 

(B.) 1.8 

Mofature ContIIIt Data 

Run Start 11me1 10:30 RunStoDTfme 12:40 

ck:f BarorneIrfc Press. (F\) 30.04 in Hg 

DF Stack SIalIc PrHL CP-l 0.21 InHP 

"F A'll Oriftce Press. (.»f).g 1.n InH~ 

rn'llMaer2 lniplftjer 3 1m1ibiGii4 Imlifiiier • Im"""iiliiir I bnpll1l.,7 

nil mI CI mI mI mI 

01 SilGef 

106.00 163.10 

100.00 150.QO 

6.0 13.1 

Raub 

mt Water Vol Condennd (V.,..,,) 0.753 set 

9 Water Vol WeIghed 1'1.1 -, 0.618 set 

dacf Sat. Moisture Content m:;-~ 3.0 "At 

or. Fhd Moisture content (B.) 1.5 % 

Moisture Contert Data 

Run Stan nmef 8:30 Run StoD TIme 10:40 

dcf BarometrIc PrestI. (P.,) 30.24 inHg 

DF Stact 8tadc Press. -(P...J 0.21 In H20 

"F Avg Ortllc:e Pross. (~ 1.84 InHzO 

ImPlnPr2 Impllller3 Implnger4 impInGe,' fml)lnler' ImpinJer7 

mI mI a mJ mI ml 

01 SIlGeI 

105.00 164.10 

100.00 150.00 

5.0 14.1 

Resds 

mI Wider Vol Condensed (V.,-) 0.708 scf 

g Wafer Vol WeIghed -tV~~) 0.665 ad 

dscf sat. MoI5IUre Content (8.,_11 2.7 or. 

"At final MoIstUre Content (8.) 1.4 or. 

Moisture Content Data 

Run StaItTlme 11:10 Run StoD Time 13:20 

dcf Barametrtc Press. . (P;) 30.28 inHg 

Df Stack Stdc Press. CP-l 0.21 inHzO 

VF Avg Orftlce Press. (~ 1.82 inHzO 

ImDlnaer2 3 ImDIMer4 ImDrMer. rmDlnaerl Implnger7 

mI mI a 

01 Sil Gel 

107.00 187.80 

100.00 150.00 

7.0 17.8 

Resufts 

mI Water Vol Condensed 

9 Water Vol-weilhed 

dad SaL Moisture Content 

" final MoIstUre Content 

Page 1 

mI mI 

(\1.,_) 0.894 

(V~ 0.839 

(e.."._~ 2.5 

(B.) 1.8 

mJ 

Id 

Id 

" or. 

Printed 312812006 

V1.1S 
ISOKINETIC SAMPUNG DATA 

Plant Name ArmO/OV Date 2128031112006 

SamplinG location Unit 3 Project' ~13S27 

EQ Run. U3-M308-01 

• 0' PoInts Acrou 12 • or Ports Used 2 

Ideal Nozzle DIameter .... d IsoKlnetIc Factor Setup Sam~ Equipment 

PIlat Tube Coefficient (~ 0.840 

Ava Stack Temp (tJ 75 

Ava CJaa Meter Temp <Y 45 

DH e 0.71 SCFII (Mf0) 1.78 

Avg Pbt Tube DItl Pruaure (~ 0.85 

Stade MoIsture Contmd (B.) 2.0 

Stack Dry MoIecur.r Weight tu.) 29.80 

EstfmGed Ortftce Flow Rate (a",) 0.750 

DP to OM Isoklnedc Factor (IQ 2.15 

Pressures 

8atomeIrfc Pressure (P~ 30.04 

Stade Static Pressure (P.-.) 0.21 

Absolute St&dl Presan (P.) 30.08 

Absolute Meter Pressure (P..,) 30.17 

DryOU 

TravetH SarnpUng Clock .... Velocity 

Polnt. nlM nme Rudlng Heed 

(9) (v~_ (.) 

min hh:rnm:ss !t" InHzO 

A-1 0.0 10:30:00 223.048 0.750 

A-2 5.0 10:35:00 228.694 0.730 

A-3 10.0 10:40:00 230.475 0.860 

A .... 15.0 10:45:00 234.253 0.820 

A-5 20.0 10:50:00 237.958 0.800 

A-8 25.0 10:55:00 2"'.123 0.710 

A-1 30.0 11:00:00 245.458 0.700 

A-8 35.0 11:05:00 249.352 0.780 

A-9 40.0 11:10:00 253.158 0.840 

A-10 45.0 11:15:00 258.908 0.920 

A-11 50.0 11:20:00 260.312 1.000 

A-12 55.0 11:25:00 264.758 0.940 

8-1 60.0 11:40:00 268.957 0.810 

8-2 85.0 11:45:00 272.840 0.900 

B-3 70.0 11:50:00 278.833 0.880 

B-4 75.0 11:55:00 280.812 0.890 

8-5 SO.O 12:00:00 284.723 0.850 

8-8 85.0 12:05:00 288.784 0.830 

8-7 90.0 12:10:00 292.765 0.800 

B-8 95.0 12:15:00 298.691 0.810 

8-9 100.0 12:20:00 300.645 0.830 

8-10 105.0 12:25:00 304.684 0.940 

8-11 110.0 12:30:00 308.822 0.910 

8-12 115.0 12:35:00 312.951 0.870 

LastPt 120.0 12:40:00 318.955 

LastPt 120.0 12:40:00 316.955 

Avereve Values 0.84 I 

Armcloy-unit 3 • M5 - Run 1 

M ........ 

~F Ueterbox Cal. Factor (Y) I 0.955 

OF Nozzle • 

lnHP Adu-' Nozzle Dfameta' (0.,.) 0.2170 in 

Inttp Req. Nozzle DIameter ~ 10.2200 In 

'" Probe ./ Length 48.00 ft lbIfb.mol. u.,., MaterIal 88 

ICfrn Sample Cue / Oven II 1m.,.,., Case • 

elV. LHkchec:ks 

InHg Pre 0 _rlmln " 15 InHa 

InHzO MId tt"1mln • In Hg 

In Hg Post 0 r/mln " 10 "'HI 

InH; .lV. < 0.020 r/mln eJ Lak Check OK? 

PitDtOK? ~ QrsatOK? 0 

DesIred Actual Meter M.ur _naw 

0I'Ita OrifIce StIIdc Inlet 0Utfet Fill. Exit Pump 

.»i .sH Temp Temp Temp Tamp Temp Vacuum 

(.ut) (.sH) (tJ (t".) It-) 

InHzO InHzO OF OF OF OF OF InHg 

1.811 1.600 78 44 44 43 3.0 

1.568 1.600 T1 47 46 44 3.0 

1.848 1.800 78 48 46 44 3.5 

1.782 1.700 78 48 47 44 3.5 

1.719 1.700 15 49 47 44 3.5 

1.525 1.500 15 49 47 45 3.0 

1.504 1.500 78 52 51 45 3.0 

1.878 1.600 78 52 50 45 3.0 

1.805 1.800 75 53 51 48 3.5 

1.978 2.COO 78 54 51 48 3.5 

2.148 2.100 75 55 52 41 4.0 

2.019 2.000 75 56 53 47 3.5 

1.740 1.700 14 54 52 41 3.0 

1.933 1.900 704 54 52 47 3.0 

1.891 1.800 75 55 53 48 3.0 

1.912 1.900 75 58 53 48 3.0 

1.828 1.800 78 56 53 48 3.0 

1.783 1.700 76 57 54 48 3.0 

1.719 1.700 78 57 55 49 3.0 

1.740 1.700 78 57 55 49 3.0 

1.783 1.700 75 58 56 49 3.0 

2.019 2.000 75 58 56 49 3.5 

1.955 1.900 75 58 58 49 3.0 

1._ 1.BOO 75 58 fiT 50 3.0 

MaxImum Vecwm 4.0 

I 1.n 1 75 I 54 521 1 41 

I 53 

Page 1 

J 

Printed 3128/2008 

\l1.1S 
ISOKINETlC SAMPUNG DATA 

Pfan'Name MndtIy 

Sampling location Unit 3 

EQ 

• of Pomta Acrus 12 

Ideal Nozzle Diameter and IloKinetic Fact. Setup 

Pltot Tube Coefflclent (CJ 0.840 

Ava Stack Tamp (t.) 75 OJ: 

Avg Oas Meter Tamp (Y 45 of 

DH e 0.76 SCFM (AMet> 1.78 In HaC 

Avg PItot Tube Diff. Prusul'e (~ 0.85 "'HaC 

at.cIc IIDiatunt content (B..) 2.0 ,. 

Stack Dry MoIeculir WeIght lMm) 29.78 lbIIIHnoie 

Eatlmated Oriftce Flow Rata (Q,,) 0.783 aclm 

DP to DH lsoldneClc Factor (K) 2.15 

Pressures 

a.ram.tr/c Preaure <P..) 30.24 InHg 

StacIe Stdc PruIure (P-.) 0.21 In HaC 

AbaoIute Stack Preslure (PJ 30.28 InHg 

Absolute Meter Pressure (P..,) 30.37 InHg 

DryOU DesIred Actual 

TraverM SarnpUna Clock ,.., Vllocly OrifIce 0rIIIce 

PaInt. TImtI "TIIM ReadIng Head ~ .lIf 

(8) (V",) (~) (Mil (AH) 

min hb:mm;ss It" IJtHaC In HaC InHP 

A-1 0.0 8:30:00 882.967 0.750 1.611 1.600 

A-2 5.0 8:35:00 888.803 0.820 1.782 1.700 

A.:J 10.0 8:40:00 890.452 0.870 1.889 1.900 

A-4 15.0 8:45:00 894.358 0.830 1.783 1.800 

A-5 20.0 8:50:00 898.241 0.810 1.740 1.700 

A-6 25.0 8:55:00 901.853 0.730 1.568 1.600 

A-7 30.0 9:00:00 905.458 0.700 1.SU 1.500 

A-8 . 35.0 9:05:00 909.253 0.750 1.811 1.600 

A-9 40.0 9:10:00 912.958 0.870 1.869 1.900 

A-10 45.0 9:15:00 916.553 0.930 1.998 2.000 

A-11 SO.O 9:20:00 920.154 1.100 2.383 2.400 

A-12 SS.O 9".25:00 924.857 0.980 2.105 2.100 

B-1 60.0 9:40:00 928.986 0.870 1.889 1.800 

B-2 65.0 9:45:00 932.872 0.910 1.955 1.900 

8-3 70.0 9:50:00 937.042 0.880 1.891 1.900 

B-4 75.0 9:55:00 941.343 0.920 1.978 2.000 

B-5 SO.O 10:00:00 945.587 0.850 1.828 1.800 

8-6 85.0 10:05:00 949.757 0.810 1.7040 1.700 

B-7 90.0 10:10:00 953.453 0.850 1.828 1.800 

B-8 95.0 10:15:00 951.257 0.800 1.719 1.700 

B-9 100.0 10".20:00 561.048 0.820 1.182 1.700 

B-10 105.0 10:25:00 964.859 0.950 2.041 2.000 

8-11 110.0 10:30:00 S68.852 0.910 2.084 2.000 

8-12 115.0 10:35:00 972.351 0.9040 2.019 2.000 

LastPt 120.0 10:40:00 978.153 

FInal Value 120.0 10:40:00 978.153 

Average Values 0.88 I 1.84 I 

ArmoIoy-unit 3 • M5 - Run 2 Pag., 

Dale 2J28-!I112OO8 

Pro}ect. 2C06-13527 

Run. U3-M3Q8.02 

• of Potts Uled 2 

Samplin, Egul~ 

Meter. 4 

M .... Cal. Factor (Y) 0.955 

Nozzle. 

.t.ctu.I NouJo Dfamcar (Dr.) 0.2170 In 

Req. Nozzle DIaneW ~ 0.2251 In 

Pralle ., Length 48.00 It 

LIner IIateIIII sa 

Sample Cue I OVen. 

Case. 

J.V,. LukChec:b 

Pre 0.001 rlrnln 0 12 In Hg 

Mld rlmln • In Hg 

Post 0.002 rlmln • 10 InHg 

J.Vm C 0.020 r/mln ItJ Leak Check 01<7 

PitatOK? 

Meter 

Stade In ... 

Ta!!p Temp 

(tJ t't...) 

of "F 

70 48 

70 48 

71 47 

71 47 

72 48 

72 48 

72 49 

13 50 

13 50 

74 51 

74 51 

74 52 

·13 53 

13 53 

74 53 

75 54 

75 55 

75 55 

75 58 

74 57 

74 57 

74 57 

75 58 

75 58 

13 I 52 

I 51 

I!I orsatOK? ~ 

....., ImplnQor 

Outlet FlIer ExIt Pump 

Temp Temp Temp Vacuum 

(t".,) 

"F ·F of lnHl 

48 34 2.5 

48 34 2.5 

48 34 3.0 

48 34 3.0 

47 35 2.5 

47 35 2.5 

47 35 2.5 

48 35 2.5 

48 36 3.0 

49 36 3.0 

49 38 3.5 

49 36 3.0 

SO 37 2.5 

51 37 2.5 

51 37 2.5 

51 37 3.0 

52 38 2.5 

53 38 2.5 

54 38 2.5 

54 38 2.5 

54 39 2.5 

55 39 3.0 

58 39 3.0 

58 40 3.0 

MaxImum Vacuum 3.5 

SOl I 

I 

37 

Printed 3I28l2OO8 

V1.1S 
ISO KINETIC SAMPUNG DATA 

Plant Name Almoiay 

Sampling l.ocdon Unit 3 

EQ 

• of Polnts Acrou 12 

Ideal Nozzle Dfametllr and IsoKlnetic Factor htup 

Pltol Tube Coefficient <Cp) 0.840 

AvgStackTemp (t.) 75 DF 

Avg CJaa Meter Temp (t",) 45 of 

DH • 0.76 SCFU (Mf. 1.78 InHP 

Avg PIlat Tube Dllr. Pranura <~ 0.85 In HzO 

S .. Mobture Content (B.) 2.0 

Stack Dry Molecular Weight tM.tJ 29.78 IbIIIHnoIo '" 

EstImIIled Ortftc:e Flow Rate (Q.,J o.m 8I:fm 

DP 10 DH Isoldnetlc Factor (1g~ 2.15 

Pressures 

Barometric Pressure (P.,) 30.2.8 InHg 

Stade Static Pressure (P.-) 0.21 InHzO 

Absolute S" Pressure (Pal 30.28 InHg 

Abaalute M .... Pressure (P.,) 30.39 Intis 

Dry CJaa Dafred AduIJ 

Travern SamplIng Clock .... Ve!odty OrifIce Oriftce 

Point. TIme nme Radlng Had JH .iff 

(9) (V.,) (Jp) (Ali) C.1H) 

min hh:mm:ss tt' InHP InHzO inHP 

A-1 0.0 11:10:00 984.397 0.77 1.85 1.60 

A-2 5.0 11:15:00 988.087. 0.83 1.78 1.eo 

A-3 10.0 11:20:00 991.956 0.88 1.89 1.SO 

A-4 15.0 11:25:00 995.952 0.85 1.83 1.80 

A-5 20.0 11:30:00 999.758 0.81 1.74 1.70 

A-6 25.0 11:35:00 1003.551 0.75 1.61 1.60 

A-7 30.0 11:40:00 1001.259 0.72 1.55 1.60 

A-8 35.0 11:45:00 1011.057 0.77 1.85 1.60 

A-9 40.0 11:50:00 1014.853 0.88 1.85 1.80 

A-10 45.0 11:55:00 1018.652 0.92 1.98 2.00 

1.-11 50.0 1200:00 1022.412 0.88 1.88 1.SO 

1.-12 55.0 1205:00 1028.208 0.14 2.02 2.00 

8-1 60.0 12:20:00 1030.558 0.82 1.78 1.80 

8-2 85.0 12:25:00 1034.759 0.89 1.91 1.90 

B-3 70.0 12:30:00 1038.953 0.92 1.98 2.00 

B-4 75.0 12:35:00 1042.703 0.87 1.87 1.90 

8-5 SO.O 12:40:00 1048.954 0.84 1.SO 1.80 

B-6 85.0 12:45:00 1051.158 0.81 1.74 1.70 

8-7 90.0 12:50:00 1055.352 0.84 1.SO 1.80 

8-8 95.0 12:55:00 1059.543 0.80 1.72 1.70 

8-8 100.0 13:00:00 1083.252 0.82 1.78 1.70 

8-10 105.0 13:05:00 1067.353 0.93 2.00 2.00 

8-11 110.0 13:10:00 1011.552 0.98 2.08 2.00 

8-12 115.0 13:15:00 1015.741 0.99 2.13 2.10 

LastPt 120.0 13:20:00 1079.858 

Final Value: 120.0 13:20:00 1079.858 

Aver~@VaIuu 0.85 I I 1.82 I 

ArmoIoy-unit 3 - M5 - Run 3 Page 1 

Dcte 2128-31112008 

Project. 2006-13527 

Run. U3-M306-3 

• of PoIb UI. 2 

Sam~ Equipment 

Meter. 4 

Meterbox Cal Factor ('I) I 0.955 I ~. 

AcIuaI Noule DIameter (Q.) I 0.2170 In 

R.q. Nozzle DIamaIr (tY I 0.2242 In 

Probe III Length 48.00 It 

Una MIderi8I sa 

Sample caae I OVen II 

I Case II 

.1V. LeakChocka 

". 0.001 r/mln CD 12 In Hg 

MId ~lmln CD In HI 

Stoat 0.001 rlmln • 10 In HI 

.1V,. < 0.020 ~Imln B Leak Check OK? 

PitDtOK? 

Meter 

Stack Inlet 

Temp T.,. 

(I.) (Y 

"F of 

68 49 

68 49 

89 50 

89 50 

70 51 

70 52 

71 52 

71 52 

72 53 

72 54 

69 57 

69 64 

70 64 

70 84 

71 85 

71 65 

72 sa 

72 (f'f 

13 (f'f 

13 (f'f 

13 67 

74 68 

74 68 

75 68 

71 1 60 

J 58 

~ orsatOK? B 

Meter Impfnget 

0UUd FIlter Eldl Pump 

Temp Temp Temp Vacuum 

~ 

of of of In HI 

.48 4S 2.5 

48 45 2.5 

.48 4S 3.0 

48 45 2.5 

48 48 2.5 

49 46 2.5 

50 46 2.5 

50 47 2.5 

50 47 2.5 

52 47 3.0 

54 48 3.0 

55 47 3.0 

57 47 2.5 

58 47 3.0 

59 48 3.0 

60 48 3.0 

80 48 2.5 

82 48 2.5 

82 49 2.5 

63 49 2.5 

64 50 2.5 

65 50 3.0 

68 50 3.0 

68 50 3.0 

MaxImum Vacuum 3.0 

581 I 

I 

47 

Printed 3I2BI2OO8 

V1.15 
Armoloy Corporation 

DeKaIb, llUDois 

RMCElNC-Chfeago Regional OftIce 

Project #2006-13527 

APPENDIX C. ANALYTICAL DATA 

Laboratory AalIyD 

QAlQCData 
ENVIRONMENTAL 

MONITORING AND 

TECHNOLOGIES, INC. 

8100 North Austin Avenue· Morton Grove, tL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735 • www.emt.com 

Rachel Chleborowicz 

RMC ENVIRONMENTAL 

9226 North 2nd Street 

Machesney Park, IL 61115 

RE: Armology Labs 

Dear Ms. Rachel Chleborowicz: 

Lab Orders: 

06030084 

March 14, 2006 

Enclosed are the analytical reports for the EMT Lab Order listed. Also included with this 

analytical report is a copy of the chain of custody associated with these samples. If you have 

any questions, please contact me at 847-967-6666. 

Sincerely, 

Arminta P Priddy 

Project Manager 

This Report Contains .-!.L pages 

Approved by, 

Mitchell Ostrowski 

Laboratory Director 

The Contenls of this report apply to the sample(s) analyzed. No duplicalfon is allowed except in lis enUrety. 

State of illinois Chemical Analysls In Drinking Water Accredited Lab. No. 100256 

Slate of Wisccnsln Wasrewater and Hazardous Waste No. 999888890 

J 

environmental laboratory and testing servic,es :~~ 

I water I soil, t air.l product f~,~~~_l ____ .--. __ No. 100:ZS=-
ENVIRONMENTAL 

MONITORING AND 

TECHNOLOGIES, INC. 

------------------~----------------.-------------------------.--~~--.- 8100 North Austin Avenue • Morton Grove, IL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735 • www.emt.com 

CUENT: RMCENV1RONMENTAL Date: I4-Mar-06 

Project: Armology Labs CASE NARRATIVE 

Lab Order: 06030084 

Unless other wise noted, analysis conducted according to the Methods specified in 40 CFR Parts 60 or 

63. 

Unless otherwise noted, all method blanks, laboratory spikes, andlor matrix spikes met quality 

assurance objectives. 

Sample results relate only to the analytes of interest tested and to the sample received at the 

laboratory. 

Prep Comments for METHOD 306CR, 06030084-01A: initial volume was 308.2 ml. 

Prep Comments for METHOD 306CR, 06030084-02A: .initial volume was 295.5 mL. 

Prep Comments for METHOD 306CR, 06030084-03A: initial volume was 298.3 ml. 

Prep Comments for METHOD 306CR, 06030084-04A: initial volume was 291.7ml. 

Prep Comments for METHOD 306CR, 06030084-05A: initial volume was 303.2 mL. 

Prep Comments for METHOD 306CR. 06030084-06A: initial volume was 298.9 mL. 

Prep Comments for METHOD 306CR, 06030084-07A: initial volume was 30.9 mL. 
ENVIRONMENTAL 

MONITORING AND 

TECHNOLOGIES, INC. 

--------------------.------------------.----------------,------------.------.--------

8100 North Austin Avenue • Morton Grove, IL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735 • www.emt.com 

Report of Laboratory Analysis 

CLIENT: RMC ENVIRONMENTAL 

Project: Armology Labs Report Date: 3/14/2006 

Lab Order: 06030084 

CII~nt Sample ID: UNm-l Collecdon Date: 3/3/2006 

Lab 10: 06030084-01 EMT Matra: Air 

Reporting 

Analyses Result Limit Qual Units Date Analyzed Batch Analyst 

ICP Metals Total Method: METHOD 3081 METHOD 308 

Chromium 0.144 0.041 C JlglmL 3/9108 29503 ES 

Client Sample ID: Unit2-2 Collecdon Date: 3/3/2006 

Lab ID: 06030084-02 EMT Matra: Air 

Reporting 

Analyses Result Limit Qual Units Date Analyzed Batch Analyst 

ICP Metals Total Method: METHOD 3081 METHOD 308 

Chromium < 0.042 0.042 C JlglmL 319106 29503 ES 

Client Sample ID: Unit2-3 CoUecdon Date: 3/312006 

Lab ID: 06030084-03 EMT Matm: Air 

Reporting 

Analyses Result Limit Qual Units Date Analyzed Batch Analyst 

lep Metal. Total Method: METHOD 3081 METHOD 308 

Chromium <0.042 0.042 C JlglmL 3/9/06 29503 ES 

Client Sample ID: Unit3-1 Collection Date: 3/3/2006 

LablD: 06030084-04 EMT Matrix: Air 

Reporting 

Analyses Result Limit Qual Units Date Analyzed Batcb Analyst 

ICP Metals Total Method: METHOD 3081 METHOD 308 

Chromium <0.043 0.043 C JJglmL 319106 29503 ES 

Qualifiers: B • Analyte detected in Ihe associated Melhod Blank 

E • Eslimaled 

s . Spike Recovery outside accepted recovery limits 

R· RPD out.dde accepled recovery limits 

H • Holding Time Exceeded 

C • Laboralory not accredited for this parameter j 

environmental laboratory and testing services __ ~~ 

. I water I soil lair l product waste L_. __ . __ .--.-. ___ _. : No. 1002158 = 
ENVIRONMENTAL 

MONITORING AND 

TECHNOLOGIES, INC. 

8100 North Austin Avenue· Morton Grove. IL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735 • www.emt.com 

CUENT: 

Report of Laboratory Analysis 

RMC ENVIRONMEN1'AL 

Project: Annology Labs Report Date: 3/14/2006 

Lab Order: 06030084 

Client Sample ID: Unit3-2 CoUectlon Date: 3/312006 

LablD: 0603008+05 EMT Matrix: Air 

Reporting 

Analyses Result Limit Qllal Units Date ADalyzed Batcb Analyst 

ICP Metals Total Method: METHOD 3081 METHOD 308 

Chromium <0.041 0.041 C J,lglmL 319/06 29503 ES 

Client Sample ID: Unitl-3 CoUeetfon Date: 31312006 

Lab ID: 06030084-06 EMT Matrix: Air 

Reporting 

Analyses Result LJmlt Qual Units Date ADalyzed Batcb Analyst 

ICP Metal. Total Method: METHOD 3081 METHOD 308 

Chromium < 0.042 0.042 C Jlg/mL 319106 29503 ES 

CUent Sample ID: blank (NaOH) CoUectlon Date: 3/3/2006 

Lab ID: 06030084-07 EMT Matrix: Air 

Reporting 

Analyses Result LJmit Qual Units Date Analyzed Batcb Analyst 

ICP Metals Total Method: METHOD 3081 METHOD 308 

Chromium <0.405 0.405 C IJglmL 319106 29503 ES 

QUI/lfien: B • Ana/y1e detected in the associated Method Blank 

E· Estimated 

S· Spike Recovery outside accepted recovery limits 

R· RPD outside accePted recovery limits 

H • Holding nme Exceeded 

C • Laboratory not acmdiled (or this panuneter 

environmental laboratory and testing services 

__________ ... I_w_~e~_1 soil , air L~roduct I waste i No 1002&8 
E.NVI RONMENTAL 

MONITORING AND 

TECHNOLOGI£S.INC. 

8100 North Austin Avenue 

Morton Grove.lIJinois60053-3203 

Company: __ Wl_C. __ =E.:...;;.ltfU""'~/..:..;II""'~~~uf-:%S.I-I ______ _ 

Address: f2.z. " IV. 2 !WI s/-. 

U/4P/.....,HU,¥ ,l?A, CL ull'~ 

Dote: 

Time: 

Relinquished By: Dote: 

Time: 

PEClAL INSTRUCTIONS: 

-.1 - 0 (, Recetved By: 

: ZO 

Received By: 

Chain of Custody Record 

847-967-6666 

FAX: 847-967-6735 

www.emt.com 

7. 1rI Ace 

S.Other 

Date: 

TIme: 

Date: 

TURNARA JD TIME: 

o RUSH 

__ day turnaround 

o ROUTINE 
ENVIRONMENTAL rn 

MONITORING AND CIl-1 

TECHNOLOGIES, INC. c:.J . -----------------_._---_ .... _._--------_._---_. -- 8100 Nort,-. Austin Avenue • Morton Grove, IL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735 • www.emt.com 

Rachel ChJeborowicz March 22, 2006 

RMC ENVIRONMENTAL 

9226 North 2nd Street 

Machesney Park, IL 61115 

RE: Armology Labs 

Dear Ms. Rachel Chleborowicz: 

Lab Orders: 

06030084 

Enclosed are the QC reports for the EMT Lab Order listed. If you have any questions, please 

contact me at 847-967-6666. 

Sincerely, 

~('. r.~~ Arminta P Priddy 

Project Manager 

The Contents of this report apply to the sample(s) analyzed. No dupllcallon Is allowed except in Its enUrety. 

..~ ..... , "oJ. 

State of illinois ChamrM~lIltowd~Nilrmtz!IBstj n9 services.~~\ 

Slate ofWlsc:onsln wastew;tter and H:fJCUS Wa:sta r' ~; IlE5DI. __ L water sOil air product waste I No 100258 

. ...- ~ ... ... ~~-----.--------.-...... - -
ENVIRONMENTAL 

MONITORING AND 

TECHNOLOGIES, INC. 

8100 North Austin Avenue • Morton Grove, IL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735· www.emt.com 

CLIENT: RMC ENVIRONMENTAL Date: 22-Mar-06 

ProJec:t: Armology Labs CASE NARRATIVE 

Lab Order: 06030084 

Unless other wise noted, analysis conducted according to the Methods specified in 40 CFR Parts BO or 

B3. 

Unless otherwise noted, all method blanks, laboratory spikes, andlor matrix spikes met quality 

assurance objedives. 

Sample results relate only to the analytes of interest tested and to the sample received at the 

laboratory. 

Prep Comments for METHOD 30BCR, OB030084-01A: initial volume was 308.2 mL. 

Prep Comments for METHOD 306CR, 06030084-02A: initial volume was 295.5 mL. 

Prep Comments for METHOD 30BeR, 060300B4-03A: initial volume was 298.3 mL. 

Prep Comments for METHOD 306CR, 06030084-04A: initial volume was 291.7mL. 

Prep Comments for METHOD 30BCR, 06030084-05A: initial volume was 303.2 mL. 

Prep Comments for METHOD 306CR, 06030084-06A: initial volume was 298.9 mL. 

Prep Comments for METHOD 30BCR, 06030084-07A: initial volume was 30.9 mL. 

For air samples a duplicate lCS is prepared to calculate the % recoveries and RSD. 

No problems with the run. 

2 

.. ," ·~r:Q·c 

environmental laboratory and testing services ,,:B'!o 

---_-________ 1 w~ter I soil L:i~ 1 prOd~ct I waste l ___ -.:.°Noo loo:ZlJe_.~ 
ENVIRONMENTAL 

MONITORING AND 

TECHNOLOGIES, INC. 

----------------------------------------------------------------------------------- 8100 North Austin Avenue • Morton Grove, IL 60053-3203 

847.967.6666 • 800.246.0663 • fax: 847.967.6735 • www.emt.com 

Client: RMC 

Work Order Number(s): 06030084 

'Duplicate run on on LeS for RPD% 

"in raw data package·· Initial calibration standard results are at start of runs, linear correlation factors listed below 

Method 01l1li. Initial 

Date or ICV% CCVOA. MS% MSO% Ica (MOLK) MOL LCS% Calibratio

Analytc Anal~. Rcco,,-en' Recovery ~~ Recovery I RPD% Jjn Jll)m) (in DlJrn) (in ppm) Recovery. w'uc:s 

Cr 319106 97.9 100.3 SeeLCS 107 2.36 <0.0032 <0.0083 0.0032 105 0.9994

Comments: 

l:OOGC3 

environmental laboratory and testing services 

__________ ~ __ . _______ L~vv __ a_t_e_r~l_s_o __ il~l __ a_i_r~l~p_r._o_d __ u_c_t~l_vv __ a_s_t_e __ •• I _______________ ~_·,_oo_2a_e 

ita• '.,J "'::·:'·"""""·· .:. .... .. . . 
Environmental Monitoring & Technologies, Inc. Date: 22-Mar-06 

CLIENT: 

Project: 

RMC 

Chrome 

Lab Order: 06030084 

Sample 10: 118-21503 

Client 10: 

Analyte 

Batch /0: 29503 

Result 

QC SUMMARY REPORT 

Method Blank 

Test Code: METHOD 308 Units: pglmL Analysis Date: 319108 Prep Date: 316106 

Run 10: T_ICP _060309A SeqNo: 765409 

pal. SPK value SPK Ref %REC Low Urnlt High Umit RPD Ref %RPD RPDUmit Qual 

Val Val .- ---_._------_. --_ .. _ ... -... _ .. _ .. _. __ ... -.. _._-_._-----

Chromium < 0.0083 0.00833 

-----_ .. _---_._---_._------- ----- --_._------ Quallnen: NO • Not Dacctcd at the Reporting Limit 

J • Analyte detected below quantilation limil5 

S • Spike Recovay OU15idc accepted recovay limil5 

R • RPO ou15idc ac:ceplCd recovery limil5 

B • Analyte detected in the wocialCd Method Blank 

I 
C' 

o 

C..,) 

c· 

Cc:, 

Environmental Monitoring & Technologies, Inc. Date: 22-Mar-06 

CLIENT: 

Project: 

RMC 

Chrome 

Lab Order: 06030084 

Sample 10: LCS-29S03 

CllenllO: 

Analyte 

Batch 10: 28503 

Result 

• _ .. - • 0- •• 

. ~.- . -- .... 

QC SUMMARY REPORT 

Laboratory Control Spike - generic 

Test Code: METHOD 306 Units: &IQImL Analysis Date: 319108 

Run 10: T_ICP _O&0309A SeqNo: 765410 

PQl SPK value SPK Ref 

Val 

%REC Low Umlt High Urnll RPD Ref 

Val 

Prep Date: 316106 

%RPO RPDUmlt Qual 

.------.. -- ---- -- --------_._-_ .... _-_. -_._-_. __ .. --.--_. 

Chromium 

SampleIO:LCSDUP~503 

ClIent 10: 

Analyte 

0_1747 0_00833 0.1667 o 105 88.6 116 0 

Batch 10: 28503 Tesl Coda: METHOD 308 Units: lIg/mL Analysis Date: 319108 

Run 10: T_lCP _060309A SeqNo: 765418 

Prep ~ate: 316108 

Result PQl SPK value SPK Ref %REC Low Umlt High Urnlt RPO Ref %RPD RPDUmll Qual 

- . _______ 0--- _______________ Val . ____ . Val _____________ ... --.0----

Chromium 

QuaUOen: 

0.1788 0.00833 0.1667 0 107 88.6 116 0.1747 2.36 20 

NO - Not Dctccled at the Reportins Limit 

J - Analyte detected below quantitation limits 

5 - Spike Recovery outside accepted recovery limits 

R - RPD outside acc:cpted recovery limits 

B - Analyte detected in the associated Method Blank 

2 
Environmental Monitoring Technologies, Inc. 

Prep Batch 29503 Prep Code: 306_GFAAPR Technician: Mariana Dlmltrova 

SamplalD Matrix pH wtCKg) Inlvol (mL) SoIAddad 

MB-29503 300 0 

LCS-29503 300 0 

Q603OO84.()1A Air 308.2 0 

06030084-02A /tJt 295.5 0 

06030Q84.03A Nt 298.3 0 

06030084-04A AJt 291.7 0 

06030084-05A AJt 303.2 0 

06030084-06A AJt 298.9 0 

06030084-07A Nt 30.9 0 

LCSDUP-29503 300 0 

SpkAddad 

PREP BATCH REPORT 

Paga:1of1 

Prep Start Date: 3/612006 8:34:45 A 

Prep End Date: 316120064:10:13 P 

Sol Racov Fin Vol (mL) factor 

0 50 0.1666667 

0 50 0.1666667 

0 50 0.1622323 

0 50 0.1692047 

0 50 0.1676165 

0 50 0.171409 

0 50 0.1649077 

0 50 0.1672800 

0 50 1.618123 

0 50 0.1666667 
. 

, 

I 

I 

I 

\ 

Date: .. ; (. ::: Time In: Timeout: Run. 

Methodtl 3[' ;.:.- OmeDa's batch # 

TI3f:ealJlllty .nd • ~ mI. 01', Rnal Vessel WI. (aJ VaN. M(g} Loa" IJ 

~ow.,. •• tUng number. 

_------r------+----

Powet%: / i 

... m'D' l' I , e _r..' \., .. ~'. 

1 Blank 

2 LCS 

/ 

I 

I 

3 L (.~,) (./u P );.iiJ ,/ .--- ~~--~~~~+_~~r_--_+----~------~--~~~--_+-

~ (" .~? /1; '/ 4 ~JhC.J)!'{Jdlf -PI j) I !I){ J- /1 

LCS: 

~ ,; : J 5 , ;/)!l ) 1 tj j - / / '_ .. _. _./ . -. ~+_----------i~~._F--'-~----~----+---~--_+-

I (3 fl. I ;g,J 3 ;"1 I . {~ 1"'} 1. 6 r-- .. _ . ..: .. -.~~6 ., I 

7 

/ 

/' .,._ .. _ .. .. 

.-.. -- --., ... ---- B / 

9 ! ---- ----

10 () I j) I 3tJ B --- _. 

..---.,---. -".-. -_.-+---1--'- - --7 11~------------+_4---~----+_-----·-~--·---------·+_·--~~ 

12 

/ 

/ 

/ 

/ 

/; 

~we"'.!..._. ____ .~1:.:3+_------_f__iI__--_+---+---+_---__1~--__4_-

HN03: 14 MS 

'f,isnjl{acturer. 

~ t I Shpt 15 MSD 

~/number 

.ilO .'1-ltJ) 16 

~CL 17 ~ufac:tuiei. ---~-+------------~1--f---f.--+----I------.;~--4-

F, J),rr 18 

~fu~r .~~----------~~~---+----~-----~---~I-----+~ 

~(~~t·~~~1~9~-----------_f~~--_+----_I_-----+_----__1~--__4_~ 

H202 20 ~n~~r.--·~~------------+-~---I----+----~-----+----1~~ 

//:/ 21 I. I, 

alnumbsr 

':(1 '1.) / (' /t? 22 

~+-------------r-r---~--~~----~----~~--4-~ 

23 

24 
" 

.' 

• ,J: ; 0"': .. , , 

lt o:' ~:-

';, r \ .. :-

•.. Ii : ;: , ,;.! 

'. ~ . , ·'i l . 

. , - , :'.'-

", 

... ~-

, " .• ~ :.: 1·-·: 

~ .. 

. . ~,,-

.q-

: ,.; 

, , 

GDOOeS