# EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -003

PARTICULATE MATTER, SULFUR DIOXIDE, AND, VISIBLE EMISSIONS EVALUATION August 27, 2008

Prepared For: Tampa Electric Company Polk Power Station P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Air Services Group

Environmental, Health & Safety Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Scott E. Given

Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith, QSTI Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1
2.0 DISCUSSION OF RESULTS 2
3.0 SOURCE DESCRIPTION/TEST PROCEDURES 4
4.0 TEST RESULTS PARTICULATE TEST SUMMARY (SOOT BLOWING) 7 PARTICULATE TEST SUMMARY (NON-SOOT BLOWING) 8
SULFUR DIOXIDE & NITROGRN OXIDES DATA SUMMARY 9
VISIBLE EMISSIONS DATA SU MMARY (SOOT BLOWING) 10
VISIBLE EMISSIONS DATA SU MMARY (NON-SOOT BLOWING) 11
HEAT INPUT AND FUEL CONSUMPTION SUMMARY 12
5.0 FIGURES
SAMPLING LOCATION DIAGRAM 14

APPENDICIES

A PARTICULTE TEST CALCULATIONS
B PARTICULATE LABORATORY ANALYTICAL DATA
C BOILER/PRECIPITATOR OPERATIONAL DATA
D FUEL ANALYSIS
E FIELD DATA SHEETS
F SAMPLING EQUIPMENT CALIBRATIONS
G CEM DATA
H CHAIN OF CUSTODY
I TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION
On August 27, 2008, the Envi ronmental, Health, & Safety Air Services Group of Tampa Electric Company, performed sour ce emission tests at the Big Bend Station, Boiler No. 3, emissions uni t I.D.# 0570039-003. Testing was conducted according to procedures stipulated by t he Florida Department of Environmental Protection (FDEP) for fossil fuel steam generators, and require ments in Title V
Permit # 0570039-028-AV.

### 2 

## 2.0 DISCUSSION OF RESULTS
The particulate matter emission rate under sootblowing conditions was derived
from three United States Environment al Protection Agency (USEPA) Reference Method 5-B test runs. The average of t he three test runs was 0.02 lb/mmBtu.
The FDEP allowable emission rate under soot blowing conditions is 0.3 lb/MMBtu, as listed in condition A.11 (3).

The particulate matter emission rate under non-sootblowing conditions was
derived from three USEPA Refe rence Method 5-B test runs. The average of the
three test runs was 0.02 lb/MMBtu. The FDEP allowable emission rate under non-sootblowing conditions is 0.03 lb/ MMBtu, as listed in condition A.7.

The sulfur dioxide emission rate wa s determined using data provided by the Continuous Emissions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was
determined to be 494 lbs/hr. The FDEP a llowable emission rate is 3374 lbs/hr,
based on scenario 3 as listed in condition A.9.e.

The nitrogen oxide emission rate was determined using data provided by the Continuous Emissions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was
determined to be 0.07 lbs/mmBtu and 271 lb s/hr. The FDEP Air Construction permit (0570039-035-AC) allowable emissi on rates are 0.12 lb/mmBtu and 494 lbs/hr, as listed in condition A.16.

Visible emissions were evaluated usi ng a Teledyne Instruments/Monitor Labs, LightHawk 560 transmissometer system (S/N 5600448), during both sootblowing and non-sootblowing testing. The 1- hour average opacity under sootblowing
conditions was 12.7%. The 1-hour average opacity under non-sootblowing
conditions was 12.7%. The FDEP allowabl e emission rate is 20%, as listed in
condition A.6.

### 3 

### During the tests performed on August 27, 2008, Boiler No. 3 was operated at an average heat input rate of 3955 mmB tu/hr and an average load of 395 megawatts. The average quantity of f uel burned was 170.9 tons per hour.

### 4 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The common stack 3 (CS003) source sampling location consists of a circular stack 28.83 feet in diameter with four sample ports located 90 degrees apart on t he stack circumference. Upstream and downstream gas flow disturbances were determined to be 8.51 and 2.99 stack diameters from the test ports, respec tively. Using these criteria, a total of 24 sampling points were chosen for particu late sampling, as stipulated in USEPA Method 1 – “Sample and Velocity Traverse s for Stationary Sour ces”. A diagram of the stack sampling location is incl uded in Figure 1 along with other pertinent
information on the test site.

Boiler No. 3 is serviced by an electrostatic precipitator for the control of flyash emissions, low NO X 

### burners and a Selective Catalytic Reduction (SCR) system for control of nitrogen oxide emissions , and a flue gas desulfurization (FGD) system for control of sulfur dioxide emissions.

During the test the unit com busted a solid fuel matrix comprised of 94% coal, 4.9% petroleum coke, and 1.1% Polk residual.

Particulate matter sampling was perfo rmed according to USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources". Particulate matter was collected on a high purity, borosilicate mi crofiber filter measuring 82mm in diameter. This data is included as Appendix A, and summarized on pages 7 (soot blowing c onditions), and 8 (non-soot blowing conditions) of this report. At the end of run number 2 (non s oot blowing run 2) the glass elbow used to connec t the filter apparatus to the umbilical (located in the filter hot box) was di scovered to be broken. It was thought that the elbow was broken when the probe/hot box assemb ly was removed from the sampling support system at the completion of the run. The sample was submitted for analysis. During the analysis the filter re turned abnormally low weight gain.

### 5 

### Subsequent quality assurance/cont rol follow ups and visual inspection of the filter
indicated that the filter was torn around the edge of the filter. The analysis was continued, and is presented wit h the data from the remaining runs, but was not included in the averaging for the non soot blowing test condition. During run number 3 (non soot blowing run 3) t he probe heater failed during the second point of the final port. Rather than risk condensable formation in the rapidly cooling probe and possible contamination on t he filter, testing wa s halted at that point. It was determined that enough sample volume was collected (31.118 scf), and the test run was called complete.

Diluent gas sampling and analysis was performed according to USEPA Method 3 "Gas Analysis for Determination of Emi ssion Rate Correction Factor, or Excess Air”. Gas analysis was performed on-site using an Orsat analyzer.

Sulfur Dioxide (SO 2 

### ), Nitrogen Oxides (NO X 

### ), and Carbon Dioxide (CO 2 

### ) data were provided by the Continuous Emissi ons Monitoring System (CEMS), Data Acquisition and Handling System (DAHS). Averages were derived from the time frame of 6:42 through 15:46 EST, corres ponding to the time frame of the particulate matter test. This data is included as Appendix B, and summarized on page 8 of this report.

Visible emissions were assessed using t he installed Continuous Opacity Monitor (COM) system. This data is summariz ed on pages 9 (soot blowing conditions), and 10 (non-soot blowing conditions).

### 6 

## 4.0 TEST RESULTS

### Environmental Services Air Services Group

Customer: T ampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 T est Date: August 27, 2008 Operating Conditions: Soot Blowing

Run 1s Run 2s Run 3s T est Average

V m(std) 

### , scf 36.6545 37.5214 36.7616 36.97919

B ws 

### , ratio 0.1595 0.1592 0.1611 0.15996

M

d 

### , lb/lb - mole 30.44 30.44 30.44 30.440

M

s 

### , lb/lb - mole 28.46 28.46 28.44 28.450

Q s 

### , acf/min 1289996.3 1322406.3 1294924.7 1302442.4

Q s(std) 

### , dscf/min 956317.38 980471.93 957471.11 964753.47

I, % 101.1 101 101.3 101.13

C, lbs/dscf 1.248E-06 1.469E-06 1.415E-06 1.377E-06

E R 

### , lbs/MMBtu 0.016 0.019 0.018 0.02

7

### Environmental Services Air Services Group

Customer: T ampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 T est Date: August 27, 2008 Operating Conditions: Non-Soot Blowing

Run 1 Run 2 Run 3 T est Average

V m(std) 

### , scf 36.3431 37.1694 31.1179 34.87677

B ws 

### , ratio 0.1607 0.1588 0.1637 0.16104

M

d 

### , lb/lb - mole 30.44 30.44 30.44 30.440

M

s 

### , lb/lb - mole 28.44 28.47 28.40 28.437

Q s 

### , acf/min 1289904.1 1307660.9 1283972.2 1293845.7

Q s(std) 

### , dscf/min 955559.27 971200.85 947932.67 958230.93

I, % 100.3 101 103.9 101.73

C, lbs/dscf 1.119E-06 5.249E-07 1.544E-06 1.063E-06

E M 

### , lbs/hr 64.1664 30.5874 87.8415 60.86510

E R 

### , lbs/MMBtu 0.014 0.007 0.020 0.02

Run #2 not included in average. Suspect filter/sampling problem.

8

## BIG BEND STATION SULFUR DIOXIDE and NITROGEN OXIDES DATA from CEMs

T est Period Information Start Time 6:42:00 Eastern Standard Time (EST) Stop Time 15:46:00 Eastern Standard Time (EST) T otal Time 9:04:00 Correspondin g to the time frame for the PM test.

Sulfur Dioxide Data: RM - 19 SO 2 

### NO X 

### CO 2 

### SO 2 

### SO 2 

### NO X 

### ppmvw lb/mmBtu %, wet lb/mmBtu lbs/hr lbs/hr 49.0195 0.0686128 11.7448 0.125 494.27 271.36

Calculation Details SO 2 

### , lb/mmBtu = SO 2 

### , ppmvw x C f 

### x F c 

### x (100 / CO2 %, wet)
where: C f



### = 1.6635E-07 (lb/scf)/ppm SO 2 

### F c



### = 1800 scf/mmBtu SO 2 

### , lbs/hr = SO 2 

### , lb/mmBtu x Heat Input, mmBtu/hr NO X 

### , lbs/hr = NO X 

### , lb/mmBtu x Heat Input, mmBtu/hr
where: Heat Input = 3955 mmBtu/hr, from Heat Input Calculation 

### Boiler #3 WET-BOTTOM UTILITY BOILER August 27, 2008

CEM DATA

9

## BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY3 Record# DATE TIME OPACITY3 1 08/27/08 12:04 11.290 31 08/27/08 12:34 11.390 2 08/27/08 12:05 12.110 32 08/27/08 12:35 24.240 3 08/27/08 12:06 13.010 33 08/27/08 12:36 18.930 4 08/27/08 12:07 11.950 34 08/27/08 12:37 13.780 5 08/27/08 12:08 12.800 35 08/27/08 12:38 15.030 6 08/27/08 12:09 13.910 36 08/27/08 12:39 23.160 7 08/27/08 12:10 10.460 37 08/27/08 12:40 14.350 8 08/27/08 12:11 9.690 38 08/27/08 12:41 12.140 9 08/27/08 12:12 14.030 39 08/27/08 12:42 11.570 10 08/27/08 12:13 11.160 40 08/27/08 12:43 10.150 11 08/27/08 12:14 9.600 41 08/27/08 12:44 10.020 12 08/27/08 12:15 10.400 42 08/27/08 12:45 10.740 13 08/27/08 12:16 14.690 43 08/27/08 12:46 9.910 14 08/27/08 12:17 14.550 44 08/27/08 12:47 10.320 15 08/27/08 12:18 18.270 45 08/27/08 12:48 10.150 16 08/27/08 12:19 15.890 46 08/27/08 12:49 11.120 17 08/27/08 12:20 10.900 47 08/27/08 12:50 14.060 18 08/27/08 12:21 12.430 48 08/27/08 12:51 11.840 19 08/27/08 12:22 15.460 49 08/27/08 12:52 11.950 20 08/27/08 12:23 10.360 50 08/27/08 12:53 10.860 21 08/27/08 12:24 9.630 51 08/27/08 12:54 10.580 22 08/27/08 12:25 11.460 52 08/27/08 12:55 9.300 23 08/27/08 12:26 11.290 53 08/27/08 12:56 8.810 24 08/27/08 12:27 13.700 54 08/27/08 12:57 10.750 25 08/27/08 12:28 11.590 55 08/27/08 12:58 9.550 26 08/27/08 12:29 11.790 56 08/27/08 12:59 12.490 27 08/27/08 12:30 10.650 57 08/27/08 13:00 15.660 28 08/27/08 12:31 13.880 58 08/27/08 13:01 13.590 29 08/27/08 12:32 14.860 59 08/27/08 13:02 14.740 30 08/27/08 12:33 11.960 60 08/27/08 13:03 14.780

Test Average: 12.662 % Minimum One Minute Average: 8.810 % Maximum One Minute Average: 24.240 %

Maximum Six Minute Average: 18.248 % 

### Boiler #3 WET BOTTOM UTILITY BOILE R

SOOTBLOWING CONDITIONS

10

## BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY3 Record# DATE TIME OPACITY3 1 08/27/08 10:05 14.750 31 08/27/08 10:35 10.540 2 08/27/08 10:06 11.380 32 08/27/08 10:36 11.300 3 08/27/08 10:07 10.300 33 08/27/08 10:37 12.080 4 08/27/08 10:08 9.480 34 08/27/08 10:38 12.950 5 08/27/08 10:09 11.010 35 08/27/08 10:39 11.160 6 08/27/08 10:10 15.370 36 08/27/08 10:40 13.410 7 08/27/08 10:11 14.260 37 08/27/08 10:41 10.820 8 08/27/08 10:12 17.700 38 08/27/08 10:42 14.310 9 08/27/08 10:13 12.900 39 08/27/08 10:43 25.870 10 08/27/08 10:14 11.410 40 08/27/08 10:44 18.470 11 08/27/08 10:15 13.580 41 08/27/08 10:45 13.910 12 08/27/08 10:16 12.320 42 08/27/08 10:46 12.380 13 08/27/08 10:17 12.090 43 08/27/08 10:47 11.500 14 08/27/08 10:18 10.340 44 08/27/08 10:48 11.080 15 08/27/08 10:19 9.330 45 08/27/08 10:49 11.860 16 08/27/08 10:20 14.020 46 08/27/08 10:50 13.900 17 08/27/08 10:21 11.840 47 08/27/08 10:51 11.590 18 08/27/08 10:22 10.820 48 08/27/08 10:52 9.980 19 08/27/08 10:23 10.030 49 08/27/08 10:53 12.870 20 08/27/08 10:24 9.170 50 08/27/08 10:54 17.060 21 08/27/08 10:25 11.800 51 08/27/08 10:55 12.660 22 08/27/08 10:26 17.110 52 08/27/08 10:56 10.060 23 08/27/08 10:27 17.450 53 08/27/08 10:57 12.810 24 08/27/08 10:28 12.600 54 08/27/08 10:58 14.630 25 08/27/08 10:29 10.620 55 08/27/08 10:59 11.780 26 08/27/08 10:30 12.790 56 08/27/08 11:00 10.820 27 08/27/08 10:31 10.160 57 08/27/08 11:01 12.570 28 08/27/08 10:32 14.260 58 08/27/08 11:02 10.060 29 08/27/08 10:33 17.090 59 08/27/08 11:03 10.820 30 08/27/08 10:34 11.960 60 08/27/08 11:04 10.050

Test Average: 12.687 % Minimum One Minute Average: 9.170 % Maximum One Minute Average: 25.870 %

Maximum Six Minute Average: 16.132 % 

### Boiler #3 WET BOTTOM UTILITY BOILE R NON-SOOTBLOWING CONDITIONS

11

## BIG BEND GENERATING STATIO N HEAT INPUT CALCULATION S

Gross Heat Rate, Previous Month (July): 10014 KMBtu/MWh 1.0014E+07 MMBtu/MWh

Testing Start Time: 6:42

Testing End Time: 15:46

T otal Test Time: 9.07 hours

Average Unit Load, MWe: 394.9 MW Heat Input, MMBtu/h = MMBtu/MWh x MWe: 3954.5 mmBtu/hr

Laboratory Sample ID: AA96809 Btu as received: 11571 Btu/lb T ons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 170.9 

### T ons/hour Calculated Heat Input

Fuel Consumption Calculation Unit # 3 WET BOTTOM UTILITY BOILE R Au g ust 27, 2008

T est Time Information

12

### 13 

## 5.0 FIGURESFIGURE 1 EXHAUST STACK 245 FT. BIG BEND STATION

PARTICULATE TRAVERSE POINTS

OUTLET 

# N A

B C D

PORT LOCATION

REVISED 12-31-96 BOILER NO. 3 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 8.5

STACK DIAMETER = 28.8333 FT. STACK AREA = 652.948 SQ.

PORT LENGTH’S = 14 IN. TRAVERSE POINT

1

2

3

4

5

6 % OF STACK DIAMETER IN. FROM STACK WALL

2.1%

6.7%

11.8%

17.7%

25.0%

35.6% 7.27 IN.

23.18 IN.

40.83 IN.

61.24 IN.

86.50 IN.

123.18 IN. 499 FT.

254 FT.

168 FT. 86 FT.

FGD

PRESSURIZED ANNULUS



### 14

## APPENDIX A PARTICULTE TEST CALCULATIONS

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Big Bend 3 Stack Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 1s Date:

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.275 inches Barometric Pressure, P b : 29.72 "Hg Nozzle Area, A n : 0.000412 ft 2 Stack Pressure, P s : 29.64 "Hg Average Orifice Meter, Δ H: 1.272 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.292 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 97.2 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 133.0 o F 5.0 % O 2 Average √ Δ p: 0.547 "H 2 O 0.0 % CO Condensate Volume, V lc : 147.6 ml 81.0 % N 2 Meter Box Y: 0.988 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V lc 6.958 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.655 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.160 % FDA = 1.0 - B w s 0.840 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B w s ) 28.46 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 32.93 ft/second Q s = v s x A s x 60 1289996.3 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 956317.4 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.1 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02075 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.009 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.248E-06 lbs/dscf E M = C x Q s(std) x 60 71.6 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.016 lbs/MMBtu 08/27/2008

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Big Bend 3 Stack Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 2s Date:

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.275 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000412 ft 2 Stack Pressure, P s : 29.67 "Hg Average Orifice Meter, Δ H: 1.346 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 40.525 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 102.1 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 133.8 o F 5.0 % O 2 Average √ Δ p: 0.561 "H 2 O 0.0 % CO Condensate Volume, V lc : 150.7 ml 81.0 % N 2 Meter Box Y: 0.988 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V lc 7.104 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 37.521 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.159 % FDA = 1.0 - B w s 0.841 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B w s ) 28.46 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 33.75 ft/second Q s = v s x A s x 60 1322406.3 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 980471.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.0 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02500 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.010 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.008 grains/acf C = c s / 7000 1.469E-06 lbs/dscf E M = C x Q s(std) x 60 86.4 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.019 lbs/MMBtu 08/27/2008

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Big Bend 3 Stack Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 3s Date:

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.275 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000412 ft 2 Stack Pressure, P s : 29.67 "Hg Average Orifice Meter, Δ H: 1.294 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.900 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 103.3 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 134.0 o F 5.0 % O 2 Average √ Δ p: 0.549 "H 2 O 0.0 % CO Condensate Volume, V l c : 149.8 ml 81.0 % N 2 Meter Box Y: 0.988 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 7.062 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.762 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.161 % FDA = 1.0 - B ws 0.839 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.44 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 33.05 ft/second Q s = v s x A s x 60 1294924.7 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 957471.1 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02360 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.010 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.007 grains/acf C = c s / 7000 1.415E-06 lbs/dscf E M = C x Q s(std) x 60 81.3 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.018 lbs/MMBtu 08/27/2008

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Big Bend 3 Stack Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 1 Date:

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.275 inches Barometric Pressure, P b : 29.74 "Hg Nozzle Area, A n : 0.000412 ft 2 Stack Pressure, P s : 29.66 "Hg Average Orifice Meter, Δ H: 1.272 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 38.932 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 97.2 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 133.0 o F 5.0 % O 2 Average √ Δ p: 0.547 "H 2 O 0.0 % CO Condensate Volume, V l c : 147.6 ml 81.0 % N 2 Meter Box Y: 0.988 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.958 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.343 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.161 % FDA = 1.0 - B ws 0.839 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.44 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 32.93 ft/second Q s = v s x A s x 60 1289904.1 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 955559.3 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01845 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.008 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.119E-06 lbs/dscf E M = C x Q s(std) x 60 64.2 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.014 lbs/MMBtu 08/27/2008

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Big Bend 3 Stack Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 2 Date:

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.275 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000412 ft 2 Stack Pressure, P s : 29.67 "Hg Average Orifice Meter, Δ H: 1.317 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.984 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 99.8 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 133.0 o F 5.0 % O 2 Average √ Δ p: 0.555 "H 2 O 0.0 % CO Condensate Volume, V l c : 148.8 ml 81.0 % N 2 Meter Box Y: 0.988 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 7.014 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 37.169 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.159 % FDA = 1.0 - B ws 0.841 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.47 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 33.38 ft/second Q s = v s x A s x 60 1307660.9 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 971200.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.0 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.00885 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.004 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.003 grains/acf C = c s / 7000 5.249E-07 lbs/dscf E M = C x Q s(std) x 60 30.6 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.007 lbs/MMBtu 08/27/2008

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Big Bend 3 Stack Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 3 Date:

Sample Time, θ : 50 minutes Nozzle Diameter, D n : 0.275 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000412 ft 2 Stack Pressure, P s : 29.67 "Hg Average Orifice Meter, Δ H: 1.269 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 33.670 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 103.0 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 133.1 o F 5.0 % O 2 Average √ Δ p: 0.544 "H 2 O 0.0 % CO Condensate Volume, V l c : 129.2 ml 81.0 % N 2 Meter Box Y: 0.988 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.090 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 31.118 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.164 % FDA = 1.0 - B ws 0.836 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.40 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 32.77 ft/second Q s = v s x A s x 60 1283972.2 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 947932.7 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 103.9 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02180 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0108 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0080 grains/acf C = c s / 7000 1.544E-06 lbs/dscf E M = C x Q s(std) x 60 87.8 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.020 lbs/MMBtu 08/27/2008

## APPENDIX B PARTICULATE LABORATORY ANALYTICAL DATACustomer AIR SERVICES Plant BIG BEND Unit3Method 5B Stack Test Completion Date08/27/2008Analyst SS/PPSample NumberAA96809ACETONE BEAKER1st weighing Date 08/30/2008 Time 15:20 % RH 42.5%2nd weighing Date 09/02/2008 Time 10:10 % RH 42.0%3rd weighing Date 09/02/2008 Time 16:25 % RH 42.0%4th weighing Date 09/03/2008 Time 9:45 % RH 41.5%***Blank***Run 1 Run 2 Run 3 Run 1S Run 2S Run 3SAcetone Container IDAIR 16 AIR 55 AIR 45 AIR IE AIR IK AIR J2 AIR 69Acetone Rinse Vol.(Va), mls 200.0000 200 200 200 200 200 2001st Gross Wt., grams 105.2284 107.4931 107.9505 106.2436 97.4682 101.3388 105.10942nd Gross Wt., grams 105.1908 107.4895 107.9439 106.2413 97.4627 101.3367 105.10783rd Gross Wt., grams 105.1903 107.4886 107.9435 106.2410 97.4617 101.3351 105.10764th Gross Wt., grams 105.1903 107.4885 97.4619 101.3354Avg. Gross Wt., grams 105.19055 107.48855 107.94370 106.24115 97.46180 101.33525 105.10770Tare Wt., grams 105.18980 107.48225 107.93890 106.23350 97.45315 101.32515 105.09805Acetone Blank Wt.,mg0.75 0.75 0.75 0.75 0.75 0.75 0.75Acetone Particulate Wt.,mg5.55 4.05 6.90 7.90 9.35 8.90Acetone Residue, mg/g0.0047Acetone Blank CriteriaFILTER1st weighingDate 08/29/2008 Time 15:30 % RH 41.0%Date 08/30/2008 Time 7:30 % RH 42.0%3rd weighing Date 08/30/2008 Time 15:20 % RH 42.5%4th weighing Date 09/02/2008 Time 10:10 % RH 42.0%Filter/Thimble ID 203133 203125 203126 203124 203131 203128 2031321st Gross Wt., grams 0.2461 0.2619 0.2549 0.2655 0.2626 0.2659 0.26482nd Gross Wt., grams 0.2463 0.2625 0.2555 0.2651 0.2622 0.2661 0.26453rd Gross Wt., grams 0.2460 0.2624 0.2553 0.2651 0.2625 0.2672 0.26514th Gross Wt., grams 0.2461 0.2628 0.2551 0.2649 0.2624 0.2674 0.2647Avg. Gross Wt., grams 0.24620 0.26245 0.25540 0.26530 0.26240 0.26600 0.26465Tare Wt., grams 0.24600 0.24955 0.25060 0.25040 0.24955 0.25035 0.24995Filter Particulate Wt.,mg0.20 12.90 4.80 14.90 12.85 15.65 14.70Difference, milligramsTotal Sample Particulate Wt.,mg18.45 8.85 21.80 20.75 25.00 23.60OK to subtract acetone blankStart Here

## APPENDIX C BOILER/PRECIPITATOR OPERATIONAL DATA

## APPENDIX D FUEL ANALYSIS

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 Report For: 

## Laboratory ID: AA96809

Date and Time Collected: Sampled By: 

### Sample Information
GEROLD HAYDEN Description: 

### Location Code: 09/24/08 Report Date:

Big Bend 3 Compliance 

### TE_BB_3_COMP_COAL

Project Account Code: 09/02/08 Date of Sample Receipt: Sample Collection Method: 

### Laboratory Results 08/27/08 3:00:00 PM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 4.15 09/10/08 8:56:00 AM

Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 10.24 09/10/08 8:56:00 AM

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 9.50 09/10/08 3:22:00 PM
Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 10.68 09/10/08 3:22:00 PM
BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 12463 09/10/08 9:29:00 AM
BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 11571 09/10/08 3:39:00 PM
BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 13003 09/10/08 3:39:00 PM
BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14558 09/10/08 3:39:00 PM
Calculated Heat Input, mmBtu/hr mmBtu/hr KARAM 3955 09/23/08 9:33:00 AM
Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 E PA Method 5B/1 7 KARAM 5.55 09/04/08 8:55:00 AM
Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 E PA Method 5B/1 7 KARAM 4.05 09/04/08 8:55:00 AM
Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 E PA Method 5B/1 7 KARAM 6.90 09/04/08 8:55:00 AM
Particulate Wt., Acetone Beaker, Run 4 mg 0.0001 E PA Method 5B/1 7 KARAM 7.90 09/04/08 8:55:00 AM
Particulate Wt., Acetone Beaker, Run 5 mg 0.0001 E PA Method 5B/1 7 KARAM 9.35 09/04/08 8:55:00 AM
Particulate Wt., Acetone Beaker, Run 6 mg 0.0001 E PA Method 5B/1 7 KARAM 8.90 09/04/08 8:55:00 AM
Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 E PA Method 5B/1 7 KARAM 12.90 09/04/08 8:55:00 AM
Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 E PA Method 5B/1 7 KARAM 4.80 09/04/08 8:55:00 AM
Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 E PA Method 5B/1 7 KARAM 14.90 09/04/08 8:55:00 AM
Particulate Wt., Filter/Thimble, Run 4 mg 0.0001 E PA Method 5B/1 7 KARAM 12.85 09/04/08 8:55:00 AM
Particulate Wt., Filter/Thimble, Run 5 mg 0.0001 E PA Method 5B/1 7 KARAM 15.65 09/04/08 8:55:00 AM
Particulate Wt., Filter/Thimble, Run 6 mg 0.0001 E PA Method 5B/1 7 KARAM 14.70 09/04/08 8:55:00 AM
Particulate Wt., Total Sample, Run 1 mg 0.0001 E PA Method 5B/1 7 KARAM 18.45 09/04/08 8:55:00 AM
Particulate Wt., Total Sample, Run 2 mg 0.0001 E PA Method 5B/1 7 KARAM 8.85 09/04/08 8:55:00 AM
Particulate Wt., Total Sample, Run 3 mg 0.0001 E PA Method 5B/1 7 KARAM 21.80 09/04/08 8:55:00 AM
Particulate Wt., Total Sample, Run 4 mg 0.0001 E PA Method 5B/1 7 KARAM 20.75 09/04/08 8:55:00 AM
Particulate Wt., Total Sample, Run 5 mg 0.0001 E PA Method 5B/1 7 KARAM 25.00 09/04/08 8:55:00 AM
Particulate Wt., Total Sample, Run 6 mg 0.0001 E PA Method 5B/1 7 KARAM 23.60 09/04/08 8:55:00 AM
PM non-sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.02 09/23/08 9:33:00 AM
Report Number: Page 1 of 2 "General Report" AA96809-092408-09

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit PM sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.02 09/23/08 9:33:00 AM

Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated KAPXJ 5.09 09/10/08 3:39:00 PM

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KARAM 494.3 09/23/08 9:33:00 AM

Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 3.34 09/10/08 10:27:00 AM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 3.10 09/10/08 3:22:00 PM
Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.48 09/10/08 3:22:00 PM

Total Moisture % 0.1 ASTM D-3173 KAPXJ 11.01 09/10/08 3:22:00 PM 

### Comments

Designee for Peggy Penner, Manager, Laboratory Services All results calculated on a wet to we t basis, unless otherwise indicated. #3 Stack Test Should there be any questions regarding this report, please contact:

(813) 630-7490 Ellen Demers,

Report Number: Page 2 of 2 "General Report" AA96809-092408-09

## APPENDIX E FIELD DATA SHEETS

## APPENDIX F SAMPLING EQUIPMENT CALIBRATIONS

### Environmental, Health, & Safet y A ir Services Grou p



## SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS
CONSOLE (MB 07) INITIA L 08/22/2008 USEPA RM 5 0.988 POST TEST 09/04/2008 (ORIFICE) 0.980
NOZZLE (SN 09) INITIA L CALIPER 0.275 POST TEST 09/04/2008 MEASUREMENTS 0.275

PYROMETER (PY 09) 08/21/2008 ASTM THERMOMETER + 2 o 

### F
PITOT TUBE (PT 10) 08/21/2008 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 07) 08/11/2008 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Blue Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 29.82 "Hg Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.07 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.60 15 623.800 630.760 6.960 79 78 79 78 1.15 15 632.600 641.846 9.246 80 77 81 78 1.90 15 644.500 656.366 11.866 82 78 83 79 3.50 15 574.200 590.272 16.072 86 74 87 75

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3448 22.0 72 72 72.0 55 0.4593 20.5 72 72 72.0 63 0.5917 18.5 72 72 72.0 73 0.8101 16.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.809 6.687 6.763 0.982 -0.006 1.660 -0.084 9.049 8.907 9.008 0.984 -0.003 1.791 0.047 11.602 11.475 11.605 0.989 0.001 1.778 0.034 15.777 15.710 15.889 0.996 0.008 1.747 0.003 Averages: 0.988 1.744

Review/Approval: 

### USEPA Reference Method 5 Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

08/22/2008

GDB

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2.



### 25-Aug-08 Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice

### Environmental Services Air Services Group

Manufacturer: Thermo Andersen Calibration Date: Model Number:MST-C1 Barometric Pressure: 29.8 "Hg Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.06 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: BLUE

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 1.15 10 61.510 67.680 6.170 75 77 76 76 1.15 10 67.680 73.840 6.160 76 77 77 75 1.15 10 73.840 79.978 6.138 77 75 77 75

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4593 20.0 72 72 72.0 55 0.4593 20.0 72 72 72.0 55 0.4593 20.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.068 5.934 6.006 0.978 -0.002 1.802 0.000 6.056 5.934 6.006 0.980 0.000 1.801 -0.001 6.037 5.934 6.006 0.983 0.003 1.802 0.000 Averages: 0.980 1.802 Prior Y: 0.988 % Difference:(+/-5%) 0.78% PASS

Review/Approval: Date: 5-Sep-08 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

GDB/RN 09/04/2008 

### POST - TEST CALIBRATION CHECK

Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.

### Environmental Services A ir Services Group

Shared Resource

Calibration Date: Responsible Party:

Nozzle Maximum 

### Average

I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.286 0.287 0.289 0.001 0.113 ^SN04 0.312 0.315 0.314 0.001 0.123 ^SN05 0.376 0.376 0.380 0.002 0.149 ^SN06 0.496 0.497 0.497 0.000 0.196 ^SN09 0.698 0.702 0.699 0.002 0.275 ^SN10 0.753 0.748 0.750 0.002 0.295 ^SN12 0.990 0.989 0.991 0.001 0.390 ^SN15 0.415 0.412 0.417 0.002 0.163 ^SN16 0.490 0.491 0.493 0.001 0.193 ^SN19 0.710 0.706 0.711 0.002 0.279 ^SN22 0.934 0.938 0.942 0.003 0.369 ^SN30 0.791 0.790 0.790 0.000 0.311 ^SN36 0.470 0.471 0.473 0.001 0.186 ^SN37 0.525 0.525 0.524 0.000 0.207 ^SN38 0.640 0.641 0.636 0.002 0.252 ^SN46 0.478 0.476 0.473 0.002 0.187 ^SN47 0.513 0.513 0.515 0.001 0.202 ^SN48 0.633 0.635 0.636 0.001 0.250 ^SN50 0.689 0.690 0.687 0.001 0.271 ^SN58 0.615 0.618 0.620 0.002 0.243 ^SN68 0.623 0.623 0.631 0.003 0.246 ^SN69 0.950 0.950 0.950 0.000 0.374 ^SN70 1.560 1.562 1.565 0.002 0.615 ^SN71 1.562 1.567 1.565 0.002 0.616 ^SN72 0.951 0.956 0.953 0.002 0.375 ^SN73 1.275 1.273 1.273 0.001 0.501 ^SN74 1.232 1.235 1.228 0.003 0.485 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by: 25-Aug-08 Nozzle Diameter, D n 

### (cm) QUARTERLY NOZZLE CALIBRATIONS

STEEL NOZZLE SET

08/21/2008 RJN

### Environmental Service s A ir Services Grou p

Shared Resource Calibration Date: Calibration Personnel: Test Designation:

Maximum 

### Average D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
0.275 0.277 0.274 0.003 0.275

Data Notations: Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN-09 was 0.275

Difference (Pre-test/Post-test) is: 0.000 PASS

QA/QC Review by: 5-Sep-08 SN-09 POST TEST NOZZLE CALIBRATION

Nozzle Identifier Nozzle Diameter, D n 

### (in) 09/04/2008 GDB/RN BB#3 Compliance

### Environmental Services A ir Services Group

Blue Team Pyrometer Under Tes t Pyrometer Number: ^PY09 Labworks Sample # Calibration Date: 08/21/2008

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 04/28/2008 Calibration Personnel (Typed and Signature):

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 402 -2 2 

### 212 215 -3 3 

### 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: 

### SEG-RN

SEG-RN 

### Pyrometer Calibration

22-Aug-08Environmental Services Air Services Group

Pitot Tube ID # Calibration Date Operating Quarter/Year: 3-08 Openings Damaged? ___ Y __

_ N Repaired? ___

_ Y ___ N ___ N/A

Labworks #:

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0 degrees Dt 0.48 < Dt > 0.95 cm

α 2 0.6 degrees α < 10 degrees β 1 1.4 degrees β 2 1.3 degrees β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α
, Ζ
, and W Determination s β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.5 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.43 cm W < 0.08 cm (Asin ο )
Ζ 0.021 cm Α distance between tips

ο angle of plane on side of pitots

ο 0.1 degrees ψ angle between tips W 0.004 cm

Comments:

Calibrated by:

Q uality Assurance Review / Approval: Pass

NOTES All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

22-Aug-08 Pass 0

Pass ( α 2 measured across bottom impact openings)

REMOVABLE Pass Pass Pass ( α 1 measured across top impact openings)

PITOT TUBE CALIBRATION DATA SHEET

PT10 Shared Resource

08/21/2008

### Environmental Services Air Services Group

Blue Team Instrument Number: Calibration Date: Calibration Personnel: Labworks #: Difference T ime "H g 9:00 -0.06 10:30 -0.05 11:30 -0.01

Avera g e Difference: -0.04

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA.
Comments (Note any ad j ustments):

QA/QC Review by: Date: 12-Au g -08 Current Conditions at Tampa International Airport 29.95 29.96 29.90 29.96 29.92 29.97 Barometer Readin g Reference Readin g Inches Mercury Inches Mercury BAROMETER CALIBRATION

^BR07 08/11/2008 SEG

## APPENDIX G DAILY SULFUR DIOXIDE DATA SUMMARY

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 6:42 11.83 68.9 0.067 08/27/2008 6:43 11.79 74.8 0.071 08/27/2008 6:44 11.92 79.9 0.071 08/27/2008 6:45 11.95 82.9 0.067 08/27/2008 6:46 11.89 89.6 0.066 08/27/2008 6:47 11.96 97.5 0.064 08/27/2008 6:48 11.84 92.5 0.064 08/27/2008 6:49 11.64 90.6 0.071 08/27/2008 6:50 11.87 102.2 0.074 08/27/2008 6:51 12.09 105.8 0.069 08/27/2008 6:52 11.86 94.9 0.068 08/27/2008 6:53 11.71 87 0.07 08/27/2008 6:54 11.77 89.6 0.074 08/27/2008 6:55 11.84 80.3 0.075 08/27/2008 6:56 11.92 72.7 0.073 08/27/2008 6:57 11.89 70.4 0.071 08/27/2008 6:58 11.72 74.3 0.076 08/27/2008 6:59 11.84 81.1 0.077 08/27/2008 7:00 11.78 83.7 0.076 08/27/2008 7:01 11.75 91.5 0.079 08/27/2008 7:02 11.91 94.4 0.078 08/27/2008 7:03 11.85 91.9 0.076 08/27/2008 7:04 11.84 89.9 0.079 08/27/2008 7:05 11.82 73.7 0.075 08/27/2008 7:06 11.73 59.8 0.075 08/27/2008 7:07 11.72 52.5 0.078 08/27/2008 7:08 11.69 52 0.081 08/27/2008 7:09 11.9 58.1 0.08 08/27/2008 7:10 11.93 60.8 0.074 08/27/2008 7:11 11.81 63.9 0.073 08/27/2008 7:12 11.81 67.9 0.073 08/27/2008 7:13 11.78 70 0.073 08/27/2008 7:14 11.78 76 0.073 08/27/2008 7:15 11.81 81.4 0.074 08/27/2008 7:16 11.84 86.7 0.073 08/27/2008 7:17 11.85 89.9 0.071 08/27/2008 7:18 11.85 95 0.067 08/27/2008 7:19 11.7 96.9 0.07 08/27/2008 7:20 11.75 103.4 0.073 08/27/2008 7:21 11.86 102.6 0.073

Page 1 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 7:22 11.87 87.9 0.071 08/27/2008 7:23 11.76 75.4 0.068 08/27/2008 7:24 11.67 70.9 0.068 08/27/2008 7:25 11.69 70.2 0.07 08/27/2008 7:26 11.78 72.1 0.071 08/27/2008 7:27 11.79 78.5 0.074 08/27/2008 7:28 11.74 81.4 0.075 08/27/2008 7:29 11.91 88.5 0.075 08/27/2008 7:30 11.95 92.5 0.074 08/27/2008 7:31 11.82 91.6 0.076 08/27/2008 7:32 11.66 85.2 0.079 08/27/2008 7:33 11.69 85 0.08 08/27/2008 7:34 11.89 88.4 0.081 08/27/2008 7:35 11.89 78.2 0.082 08/27/2008 7:36 11.83 67.3 0.08 08/27/2008 7:37 11.79 61.4 0.08 08/27/2008 7:38 11.74 57.9 0.082 08/27/2008 7:39 11.66 55.8 0.085 08/27/2008 7:40 11.8 58.6 0.081 08/27/2008 7:41 11.91 59 0.074 08/27/2008 7:42 11.73 59.8 0.075 08/27/2008 7:43 11.64 59.4 0.078 08/27/2008 7:44 11.65 60.8 0.079 08/27/2008 7:45 11.7 69.2 0.083 08/27/2008 7:46 11.91 70.9 0.076 08/27/2008 7:47 11.73 68.7 0.076 08/27/2008 7:48 11.66 73.5 0.078 08/27/2008 7:49 11.87 79.3 0.073 08/27/2008 7:50 11.62 68.4 0.072 08/27/2008 7:51 11.56 67.4 0.075 08/27/2008 7:52 11.76 72.6 0.076 08/27/2008 7:53 11.69 71.9 0.076 08/27/2008 7:54 11.67 71.7 0.075 08/27/2008 7:55 11.86 67.1 0.075 08/27/2008 7:56 11.81 61.4 0.076 08/27/2008 7:57 11.65 59.5 0.078 08/27/2008 7:58 11.72 62.2 0.075 08/27/2008 7:59 11.81 70.6 0.076 08/27/2008 8:00 11.89 73.2 0.077 08/27/2008 8:01 11.78 77.6 0.074

Page 2 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 8:02 11.65 79.4 0.079 08/27/2008 8:03 11.73 80.7 0.08 08/27/2008 8:04 11.81 79.8 0.079 08/27/2008 8:05 11.66 75.1 0.076 08/27/2008 8:06 11.63 70.6 0.081 08/27/2008 8:07 11.69 61 0.083 08/27/2008 8:08 11.82 57.7 0.083 08/27/2008 8:09 11.75 57.2 0.085 08/27/2008 8:10 11.73 59.3 0.081 08/27/2008 8:11 11.71 53.8 0.079 08/27/2008 8:12 11.61 47.6 0.083 08/27/2008 8:13 11.75 48.6 0.083 08/27/2008 8:14 11.85 47.7 0.077 08/27/2008 8:15 11.59 47.8 0.075 08/27/2008 8:16 11.58 49.6 0.075 08/27/2008 8:17 11.51 54.3 0.08 08/27/2008 8:18 11.75 60.8 0.08 08/27/2008 8:19 11.85 64.7 0.075 08/27/2008 8:20 11.71 65 0.072 08/27/2008 8:21 11.58 67.6 0.072 08/27/2008 8:22 11.61 71.2 0.073 08/27/2008 8:23 11.68 78.7 0.077 08/27/2008 8:24 11.77 84.2 0.073 08/27/2008 8:25 11.66 82.9 0.072 08/27/2008 8:26 11.59 84.3 0.075 08/27/2008 8:27 11.77 92.8 0.075 08/27/2008 8:28 11.97 88.7 0.071 08/27/2008 8:29 11.74 68.2 0.07 08/27/2008 8:30 11.65 57.1 0.074 08/27/2008 8:31 11.72 53.4 0.077 08/27/2008 8:32 11.77 52.4 0.076 08/27/2008 8:33 11.92 52.8 0.072 08/27/2008 8:34 11.78 53.1 0.072 08/27/2008 8:35 11.57 54.2 0.078 08/27/2008 8:36 11.81 60.1 0.078 08/27/2008 8:37 11.81 62.5 0.077 08/27/2008 8:38 11.79 64.4 0.077 08/27/2008 8:39 11.83 66.3 0.078 08/27/2008 8:40 11.91 70.3 0.074 08/27/2008 8:41 11.7 69.2 0.076

Page 3 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 8:42 11.68 68.8 0.079 08/27/2008 8:43 11.88 69.8 0.078 08/27/2008 8:44 11.73 67.8 0.08 08/27/2008 8:45 11.84 71.6 0.076 08/27/2008 8:46 11.73 69.5 0.078 08/27/2008 8:47 11.69 75.3 0.085 08/27/2008 8:48 11.91 73.9 0.08 08/27/2008 8:49 11.84 62.4 0.077 08/27/2008 8:50 11.72 56.2 0.076 08/27/2008 8:51 11.7 55.9 0.078 08/27/2008 8:52 11.77 62.3 0.081 08/27/2008 8:53 11.85 64.5 0.078 08/27/2008 8:54 11.89 65.7 0.074 08/27/2008 8:55 11.84 70 0.074 08/27/2008 8:56 11.71 70.9 0.077 08/27/2008 8:57 11.72 69.8 0.078 08/27/2008 8:58 11.72 72.9 0.08 08/27/2008 8:59 11.93 83 0.077 08/27/2008 9:00 11.88 80.9 0.076 08/27/2008 9:01 11.62 76.5 0.078 08/27/2008 9:02 11.72 84.3 0.078 08/27/2008 9:03 11.92 88.8 0.076 08/27/2008 9:04 11.85 91.1 0.074 08/27/2008 9:05 11.68 86.1 0.077 08/27/2008 9:06 11.74 74 0.076 08/27/2008 9:07 12.02 63.2 0.076 08/27/2008 9:08 11.9 46.8 0.075 08/27/2008 9:09 11.71 44 0.077 08/27/2008 9:10 11.72 47.3 0.085 08/27/2008 9:11 11.97 54.4 0.082 08/27/2008 9:12 11.76 53.6 0.082 08/27/2008 9:13 11.76 57.7 0.08 08/27/2008 9:14 11.66 59.2 0.084 08/27/2008 9:15 11.66 63.7 0.082 08/27/2008 9:16 11.83 69.2 0.081 08/27/2008 9:17 11.89 73 0.076 08/27/2008 9:18 11.67 76.4 0.078 08/27/2008 9:19 11.73 85.7 0.082 08/27/2008 9:20 11.83 90.9 0.079 08/27/2008 9:21 11.71 85.8 0.079

Page 4 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3

08/27/2008 9:22 11.8 76.3 0.077 08/27/2008 9:23 11.82 69.4 0.075 08/27/2008 9:24 11.75 64.7 0.076 08/27/2008 9:25 11.71 66.8 0.079 08/27/2008 9:26 11.9 71.8 0.077 08/27/2008 9:27 11.91 71.7 0.075 08/27/2008 9:28 11.82 66.9 0.073 08/27/2008 9:29 11.68 65.1 0.081 08/27/2008 9:30 11.92 71.6 0.078 08/27/2008 9:31 11.88 70.2 0.074 08/27/2008 9:32 11.66 69.7 0.075 08/27/2008 9:33 11.73 78 0.081 08/27/2008 9:34 11.91 81.4 0.08 08/27/2008 9:35 11.86 75.9 0.078 08/27/2008 9:36 11.8 69.4 0.078 08/27/2008 9:37 11.69 64.4 0.082 08/27/2008 9:38 11.77 61 0.081 08/27/2008 9:39 11.73 59.2 0.08 08/27/2008 9:40 11.78 62.1 0.078 08/27/2008 9:41 11.73 63.7 0.08 08/27/2008 9:42 11.81 67.9 0.081 08/27/2008 9:43 11.97 75.6 0.076 08/27/2008 9:44 11.71 73.9 0.076 08/27/2008 9:45 11.72 79.1 0.078 08/27/2008 9:46 11.77 81.5 0.079 08/27/2008 9:47 11.85 86.2 0.076 08/27/2008 9:48 11.84 87.1 0.074 08/27/2008 9:49 11.68 88.8 0.076 08/27/2008 9:50 11.78 92.8 0.073 08/27/2008 9:51 11.66 88.6 0.074 08/27/2008 9:52 11.75 77.9 0.075 08/27/2008 9:53 11.9 70.8 0.078 08/27/2008 9:54 11.91 64.8 0.076 08/27/2008 9:55 11.88 65.8 0.073 08/27/2008 9:56 11.7 62.2 0.074 08/27/2008 9:57 11.6 66.7 0.079 08/27/2008 9:58 11.83 74.4 0.078 08/27/2008 9:59 11.82 74.3 0.075 08/27/2008 10:00 11.88 79 0.076 08/27/2008 10:01 11.85 83 0.069

Page 5 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 10:02 11.81 80.5 0.012 08/27/2008 10:03 11.79 74.7 0.265 08/27/2008 10:04 11.88 72.2 0.084 08/27/2008 10:05 11.78 66.5 0.076 08/27/2008 10:06 11.74 61.7 0.079 08/27/2008 10:07 11.85 57.5 0.077 08/27/2008 10:08 11.84 58.9 0.075 08/27/2008 10:09 11.85 57.9 0.075 08/27/2008 10:10 11.88 48.4 0.073 08/27/2008 10:11 11.68 44.9 0.077 08/27/2008 10:12 11.76 45.4 0.079 08/27/2008 10:13 11.85 47.7 0.079 08/27/2008 10:14 11.86 49.6 0.079 08/27/2008 10:15 11.76 51.1 0.076 08/27/2008 10:16 11.66 52.6 0.077 08/27/2008 10:17 11.7 58.5 0.08 08/27/2008 10:18 11.89 64.5 0.08 08/27/2008 10:19 11.89 67.1 0.077 08/27/2008 10:20 11.65 66.1 0.076 08/27/2008 10:21 11.63 69.8 0.081 08/27/2008 10:22 11.87 80.6 0.08 08/27/2008 10:23 11.8 82.5 0.08 08/27/2008 10:24 11.83 82.8 0.077 08/27/2008 10:25 11.84 72.1 0.075 08/27/2008 10:26 11.71 64.2 0.076 08/27/2008 10:27 11.65 63.5 0.079 08/27/2008 10:28 11.69 58.5 0.079 08/27/2008 10:29 11.88 62.7 0.078 08/27/2008 10:30 11.97 65.6 0.075 08/27/2008 10:31 11.82 67.2 0.073 08/27/2008 10:32 11.66 68.1 0.075 08/27/2008 10:33 11.56 73.3 0.081 08/27/2008 10:34 11.8 76 0.078 08/27/2008 10:35 11.96 70.3 0.075 08/27/2008 10:36 11.79 66.7 0.076 08/27/2008 10:37 11.73 71.7 0.075 08/27/2008 10:38 11.73 73.3 0.076 08/27/2008 10:39 11.76 75.4 0.081 08/27/2008 10:40 11.89 71.5 0.078 08/27/2008 10:41 11.93 66.6 0.076

Page 6 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 10:42 11.84 64.8 0.074 08/27/2008 10:43 11.67 65.6 0.078 08/27/2008 10:44 11.89 77.3 0.079 08/27/2008 10:45 11.9 76.9 0.077 08/27/2008 10:46 11.66 75.7 0.077 08/27/2008 10:47 11.68 80.7 0.083 08/27/2008 10:48 11.87 75.3 0.08 08/27/2008 10:49 11.83 67.2 0.079 08/27/2008 10:50 11.81 64.8 0.078 08/27/2008 10:51 11.83 67 0.078 08/27/2008 10:52 11.77 68.5 0.076 08/27/2008 10:53 11.66 69.7 0.079 08/27/2008 10:54 11.8 75.6 0.082 08/27/2008 10:55 11.86 80.8 0.081 08/27/2008 10:56 11.84 79.5 0.08 08/27/2008 10:57 11.84 83.4 0.078 08/27/2008 10:58 11.75 82.2 0.077 08/27/2008 10:59 11.65 81.3 0.082 08/27/2008 11:00 11.75 77.9 0.084 08/27/2008 11:01 11.94 73.4 0.078 08/27/2008 11:02 11.83 70.1 0.075 08/27/2008 11:03 11.57 62.9 0.08 08/27/2008 11:04 11.78 66 0.081 08/27/2008 11:05 11.88 61.3 0.076 08/27/2008 11:06 11.71 55.7 0.078 08/27/2008 11:07 11.82 54.5 0.076 08/27/2008 11:08 11.89 55.4 0.075 08/27/2008 11:09 11.74 55.4 0.079 08/27/2008 11:10 11.67 59.1 0.083 08/27/2008 11:11 11.92 66.2 0.079 08/27/2008 11:12 11.81 64.1 0.076 08/27/2008 11:13 11.68 58.2 0.076 08/27/2008 11:14 11.71 59.8 0.077 08/27/2008 11:15 11.75 60.6 0.078 08/27/2008 11:16 11.75 52.9 0.079 08/27/2008 11:17 11.82 50 0.077 08/27/2008 11:18 11.99 52.2 0.074 08/27/2008 11:19 11.96 50.6 0.071 08/27/2008 11:20 11.66 52 0.075 08/27/2008 11:21 11.54 54.1 0.08

Page 7 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 11:22 11.77 59.3 0.082 08/27/2008 11:23 11.97 63 0.076 08/27/2008 11:24 11.75 61.2 0.075 08/27/2008 11:25 11.71 65.7 0.076 08/27/2008 11:26 11.7 59.9 0.081 08/27/2008 11:27 11.68 57 0.083 08/27/2008 11:28 11.91 56.7 0.079 08/27/2008 11:29 11.84 52.8 0.077 08/27/2008 11:30 11.66 52.7 0.08 08/27/2008 11:31 11.69 53.2 0.083 08/27/2008 11:32 11.79 52.3 0.08 08/27/2008 11:33 11.73 51.7 0.079 08/27/2008 11:34 11.84 51 0.076 08/27/2008 11:35 11.74 51.2 0.076 08/27/2008 11:36 11.67 48.9 0.078 08/27/2008 11:37 11.67 49.5 0.081 08/27/2008 11:38 11.94 51.5 0.075 08/27/2008 11:39 11.83 50.7 0.074 08/27/2008 11:40 11.71 50.9 0.075 08/27/2008 11:41 11.71 52 0.076 08/27/2008 11:42 11.71 56.2 0.078 08/27/2008 11:43 11.79 62.7 0.079 08/27/2008 11:44 11.81 63.7 0.077 08/27/2008 11:45 11.76 65.5 0.079 08/27/2008 11:46 12 70.4 0.075 08/27/2008 11:47 11.77 59.7 0.073 08/27/2008 11:48 11.69 57.7 0.074 08/27/2008 11:49 11.58 51.6 0.079 08/27/2008 11:50 11.73 54.4 0.081 08/27/2008 11:51 11.91 54 0.077 08/27/2008 11:52 11.82 51.2 0.075 08/27/2008 11:53 11.65 54.1 0.08 08/27/2008 11:54 11.69 59.1 0.082 08/27/2008 11:55 11.85 62.3 0.078 08/27/2008 11:56 11.83 62.2 0.077 08/27/2008 11:57 11.75 64.9 0.079 08/27/2008 11:58 11.69 61.4 0.081 08/27/2008 11:59 11.7 61.3 0.082 08/27/2008 12:00 11.8 63.6 0.084 08/27/2008 12:01 11.92 66.7 0.08

Page 8 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 12:02 11.74 62.1 0.08 08/27/2008 12:03 11.62 59 0.081 08/27/2008 12:04 11.76 63.6 0.085 08/27/2008 12:05 11.96 61.3 0.082 08/27/2008 12:06 11.76 53.4 0.081 08/27/2008 12:07 11.56 50.9 0.079 08/27/2008 12:08 11.56 55 0.083 08/27/2008 12:09 11.8 61.1 0.081 08/27/2008 12:10 11.77 60.8 0.078 08/27/2008 12:11 11.68 69 0.079 08/27/2008 12:12 11.7 69.9 0.077 08/27/2008 12:13 11.55 67.6 0.082 08/27/2008 12:14 11.83 73.3 0.077 08/27/2008 12:15 11.69 72 0.075 08/27/2008 12:16 11.47 72.4 0.078 08/27/2008 12:17 11.69 81.6 0.081 08/27/2008 12:18 11.98 88.7 0.073 08/27/2008 12:19 11.64 74.9 0.073 08/27/2008 12:20 11.52 66.1 0.075 08/27/2008 12:21 11.64 63 0.075 08/27/2008 12:22 11.77 62.5 0.073 08/27/2008 12:23 11.92 56.5 0.071 08/27/2008 12:24 11.8 47.7 0.072 08/27/2008 12:25 11.74 44.7 0.07 08/27/2008 12:26 11.73 45.1 0.073 08/27/2008 12:27 11.53 44.1 0.077 08/27/2008 12:28 11.74 50 0.077 08/27/2008 12:29 11.75 50.2 0.074 08/27/2008 12:30 11.67 52.9 0.076 08/27/2008 12:31 11.61 54.6 0.078 08/27/2008 12:32 11.64 56.9 0.078 08/27/2008 12:33 11.75 62 0.076 08/27/2008 12:34 11.79 64.2 0.077 08/27/2008 12:35 11.58 66.8 0.08 08/27/2008 12:36 11.66 66.4 0.078 08/27/2008 12:37 11.76 60.6 0.078 08/27/2008 12:38 11.77 57.1 0.079 08/27/2008 12:39 11.62 55.4 0.078 08/27/2008 12:40 11.55 56.3 0.083 08/27/2008 12:41 11.84 62.5 0.082

Page 9 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 12:42 11.89 64.3 0.077 08/27/2008 12:43 11.62 60.7 0.076 08/27/2008 12:44 11.68 65.5 0.077 08/27/2008 12:45 11.73 68.7 0.078 08/27/2008 12:46 11.67 71.8 0.08 08/27/2008 12:47 11.73 74 0.075 08/27/2008 12:48 11.62 73.3 0.075 08/27/2008 12:49 11.48 74 0.079 08/27/2008 12:50 11.6 79.5 0.083 08/27/2008 12:51 11.91 88.1 0.077 08/27/2008 12:52 11.81 79.1 0.071 08/27/2008 12:53 11.57 70 0.071 08/27/2008 12:54 11.48 66 0.076 08/27/2008 12:55 11.67 68.1 0.078 08/27/2008 12:56 11.81 69.9 0.074 08/27/2008 12:57 11.65 68.8 0.072 08/27/2008 12:58 11.66 71.6 0.074 08/27/2008 12:59 11.71 74.7 0.075 08/27/2008 13:00 11.65 78.3 0.079 08/27/2008 13:01 11.82 80.8 0.077 08/27/2008 13:02 11.8 77.3 0.075 08/27/2008 13:03 11.77 79.5 0.076 08/27/2008 13:04 11.68 84.2 0.08 08/27/2008 13:05 11.69 85.9 0.082 08/27/2008 13:06 11.73 84.5 0.082 08/27/2008 13:07 11.72 77.5 0.082 08/27/2008 13:08 11.76 73 0.084 08/27/2008 13:09 11.67 67.4 0.086 08/27/2008 13:10 11.74 68.9 0.086 08/27/2008 13:11 11.57 66.1 0.092 08/27/2008 13:12 11.77 65 0.089 08/27/2008 13:13 11.68 59.6 0.086 08/27/2008 13:14 11.63 57 0.083 08/27/2008 13:15 11.68 56 0.083 08/27/2008 13:16 11.59 52.9 0.085 08/27/2008 13:17 11.77 59 0.082 08/27/2008 13:18 11.81 60.6 0.077 08/27/2008 13:19 11.79 60.4 0.072 08/27/2008 13:20 11.61 60 0.073 08/27/2008 13:21 11.56 63.4 0.075

Page 10 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 13:22 11.66 68.9 0.074 08/27/2008 13:23 11.62 72.5 0.078 08/27/2008 13:24 11.83 74.2 0.074 08/27/2008 13:25 11.81 68.1 0.071 08/27/2008 13:26 11.55 61.7 0.074 08/27/2008 13:27 11.63 63.6 0.076 08/27/2008 13:28 11.59 64.7 0.078 08/27/2008 13:29 11.81 66.5 0.076 08/27/2008 13:30 11.87 62.3 0.075 08/27/2008 13:31 11.83 57.5 0.073 08/27/2008 13:32 11.58 54 0.076 08/27/2008 13:33 11.55 58.1 0.078 08/27/2008 13:34 11.6 60.2 0.078 08/27/2008 13:35 11.71 61.9 0.076 08/27/2008 13:36 11.61 63 0.078 08/27/2008 13:37 11.53 69.1 0.083 08/27/2008 13:38 11.76 77.3 0.083 08/27/2008 13:39 11.77 79 0.078 08/27/2008 13:40 11.69 80.4 0.079 08/27/2008 13:41 11.74 82 0.081 08/27/2008 13:42 11.69 73 0.081 08/27/2008 13:43 11.48 66.1 0.083 08/27/2008 13:44 11.56 66.3 0.081 08/27/2008 13:45 11.69 72.3 0.082 08/27/2008 13:46 11.84 80.7 0.08 08/27/2008 13:47 11.69 82.1 0.077 08/27/2008 13:48 11.47 82.3 0.077 08/27/2008 13:49 11.63 91.9 0.079 08/27/2008 13:50 11.74 97 0.078 08/27/2008 13:51 11.64 98.1 0.079 08/27/2008 13:52 11.7 104.1 0.076 08/27/2008 13:53 11.69 107.5 0.073 08/27/2008 13:54 11.77 113.1 0.073 08/27/2008 13:55 11.75 110.4 0.074 08/27/2008 13:56 11.58 97.2 0.07 08/27/2008 13:57 11.44 89.5 0.076 08/27/2008 13:58 11.73 78.3 0.077 08/27/2008 13:59 11.77 73.6 0.077 08/27/2008 14:00 11.72 70.6 0.073 08/27/2008 14:01 11.68 69.6 0.071

Page 11 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 14:02 11.75 73 0.07 08/27/2008 14:03 11.55 75 0.075 08/27/2008 14:04 11.62 79.4 0.075 08/27/2008 14:05 11.62 76.2 0.075 08/27/2008 14:06 11.75 84.5 0.073 08/27/2008 14:07 11.66 87.5 0.072 08/27/2008 14:08 11.54 84.9 0.078 08/27/2008 14:09 11.75 92.9 0.077 08/27/2008 14:10 11.81 97.9 0.072 08/27/2008 14:11 11.69 98 0.074 08/27/2008 14:12 11.72 87.8 0.076 08/27/2008 14:13 11.66 81.9 0.074 08/27/2008 14:14 11.48 77.2 0.078 08/27/2008 14:15 11.8 80.3 0.076 08/27/2008 14:16 11.64 81.1 0.077 08/27/2008 14:17 11.54 88 0.078 08/27/2008 14:18 11.6 93.7 0.079 08/27/2008 14:19 11.72 97.6 0.078 08/27/2008 14:20 11.86 105.2 0.076 08/27/2008 14:21 11.79 107.4 0.074 08/27/2008 14:22 11.59 106 0.078 08/27/2008 14:23 11.7 110.3 0.078 08/27/2008 14:24 11.76 114.1 0.078 08/27/2008 14:25 11.76 101.7 0.073 08/27/2008 14:26 11.63 88.9 0.073 08/27/2008 14:27 11.63 85.1 0.077 08/27/2008 14:28 11.66 83.7 0.076 08/27/2008 14:29 11.63 81.5 0.079 08/27/2008 14:30 11.83 87.4 0.076 08/27/2008 14:31 11.75 87.2 0.075 08/27/2008 14:32 11.64 88.2 0.074 08/27/2008 14:33 11.54 90.1 0.077 08/27/2008 14:34 11.63 95.2 0.081 08/27/2008 14:35 11.79 94.9 0.079 08/27/2008 14:36 11.75 93 0.075 08/27/2008 14:37 11.58 92.8 0.08 08/27/2008 14:38 11.68 98.4 0.083 08/27/2008 14:39 11.79 102.3 0.082 08/27/2008 14:40 11.74 102 0.081 08/27/2008 14:41 11.77 103.6 0.078

Page 12 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 14:42 11.76 97.7 0.079 08/27/2008 14:43 11.78 90.7 0.078 08/27/2008 14:44 11.6 81.9 0.075 08/27/2008 14:45 11.57 78.3 0.079 08/27/2008 14:46 11.78 82.5 0.081 08/27/2008 14:47 11.94 82.8 0.073 08/27/2008 14:48 11.65 79.2 0.073 08/27/2008 14:49 11.65 86.2 0.078 08/27/2008 14:50 11.87 89 0.072 08/27/2008 14:51 11.73 86.5 0.07 08/27/2008 14:52 11.7 87.9 0.071 08/27/2008 14:53 11.61 91.4 0.074 08/27/2008 14:54 11.7 94 0.073 08/27/2008 14:55 11.72 97 0.075 08/27/2008 14:56 11.88 94.1 0.072 08/27/2008 14:57 11.72 81.6 0.071 08/27/2008 14:58 11.64 74.8 0.077 08/27/2008 14:59 11.77 69 0.075 08/27/2008 15:00 11.67 63.6 0.078 08/27/2008 15:01 11.77 61.1 0.08 08/27/2008 15:02 11.92 63.5 0.078 08/27/2008 15:03 11.71 61.8 0.077 08/27/2008 15:04 11.56 60.9 0.079 08/27/2008 15:05 11.65 64.7 0.082 08/27/2008 15:06 11.8 71.6 0.081 08/27/2008 15:07 11.79 75.8 0.08 08/27/2008 15:08 11.79 76.5 0.078 08/27/2008 15:09 11.73 76.6 0.079 08/27/2008 15:10 11.81 79.7 0.078 08/27/2008 15:11 11.8 76.4 0.072 08/27/2008 15:12 11.65 76 0.078 08/27/2008 15:13 11.75 83.6 0.082 08/27/2008 15:14 11.88 85.2 0.077 08/27/2008 15:15 11.85 83.7 0.072 08/27/2008 15:16 11.71 82.9 0.075 08/27/2008 15:17 11.62 86.6 0.08 08/27/2008 15:18 11.78 88.1 0.078 08/27/2008 15:19 11.84 88.6 0.073 08/27/2008 15:20 11.8 89.6 0.072 08/27/2008 15:21 11.79 91.9 0.075

Page 13 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 15:22 11.68 82.3 0.08 08/27/2008 15:23 11.85 78.7 0.079 08/27/2008 15:24 11.92 76.5 0.073 08/27/2008 15:25 11.7 73.8 0.075 08/27/2008 15:26 11.72 79.2 0.08 08/27/2008 15:27 11.89 82.9 0.079 08/27/2008 15:28 11.87 76.6 0.076 08/27/2008 15:29 11.86 72.1 0.074 08/27/2008 15:30 11.69 69.5 0.081 08/27/2008 15:31 11.76 69.2 0.083 08/27/2008 15:32 11.86 66.4 0.08 08/27/2008 15:33 11.87 64.5 0.077 08/27/2008 15:34 11.8 63.6 0.077 08/27/2008 15:35 11.59 62.5 0.084 08/27/2008 15:36 11.73 65.7 0.083 08/27/2008 15:37 11.94 67.7 0.079 08/27/2008 15:38 11.87 65.6 0.079 08/27/2008 15:39 11.65 63.5 0.08 08/27/2008 15:40 11.71 68.3 0.08 08/27/2008 15:41 11.76 71.5 0.082 08/27/2008 15:42 11.86 69.8 0.078 08/27/2008 15:43 11.88 65.3 0.074 08/27/2008 15:44 11.69 60.7 0.079 08/27/2008 15:45 11.75 64.9 0.08 08/27/2008 15:46 11.87 69.4 0.078 08/27/2008 15:47 11.87 70.4 0.072 08/27/2008 15:48 11.63 70.3 0.075 08/27/2008 15:49 11.8 76.9 0.074 08/27/2008 15:50 11.79 80.8 0.073 08/27/2008 15:51 11.73 84.2 0.072 08/27/2008 15:52 11.82 93.2 0.073 08/27/2008 15:53 11.8 90.4 0.073 08/27/2008 15:54 11.73 76.5 0.072 08/27/2008 15:55 11.82 64.9 0.073 08/27/2008 15:56 11.83 59.1 0.075 08/27/2008 15:57 11.86 56.2 0.076 08/27/2008 15:58 11.85 56.6 0.074 08/27/2008 15:59 11.76 58 0.075 08/27/2008 16:00 11.68 59.1 0.08 08/27/2008 16:01 11.77 62.7 0.073

Page 14 of 15

### iTrends Data

Date Time CO2_S2 SO2_S2 NOXLRT3 08/27/2008 16:02 11.86 66.3 0.014 08/27/2008 16:03 11.92 68.3 0.257 08/27/2008 16:04 11.69 67.2 0.086 08/27/2008 16:05 11.64 69.9 0.08 08/27/2008 16:06 11.77 75.5 0.084 08/27/2008 16:07 11.88 79.8 0.08 08/27/2008 16:08 11.83 82.1 0.078 08/27/2008 16:09 11.86 83.9 0.077 08/27/2008 16:10 11.68 71.9 0.08 08/27/2008 16:11 11.71 66.1 0.082 08/27/2008 16:12 11.92 64.7 0.077 08/27/2008 16:13 11.82 63.1 0.075 08/27/2008 16:14 11.64 62 0.077 08/27/2008 16:15 11.8 68.9 0.079 08/27/2008 16:16 11.85 76.2 0.08 08/27/2008 16:17 11.91 81.9 0.075 08/27/2008 16:18 11.84 80.8 0.072 08/27/2008 16:19 11.74 85.5 0.075 08/27/2008 16:20 11.7 91.1 0.079

Page 15 of 15

## APPENDIX H CHAIN OF CUSTODY

## APPENDIX I TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL, HEALTH, & SAFETY AIR SERVICES GROUP – TEST TEAM Scott Given Technician – Test Team Lead Jorge Varino Environmental Technician Ryan Newell Associate Technician David A. Smith, QSTI Coordinator – Air Services Group

PROCESS DATA Adam Ballans Associate Engineer –Big Bend Station R.A. McDarby Senior Environmental Technician

FUEL ANALYSIS Patrice Jackson Envi ronmental Technician Ellen Demers Environmental Technician

PARTICULATE LABORATORY Sam Soth Environmental Technician

SUPPORTING DATA COLLECTION AND ANALYSIS R.A. McDarby Senior Environmental Technician

PROJECT QUALITY OBJECTIVES & REPORTING R.A. McDarby Senior Environmental Technician

TEST COORDINATION Karen Zwolak Senior Environmental Consultant – Big Bend Station Adam Ballans Associate Engineer –Big Bend Station David A. Smith, QSTI Coordinator – Air Services Group