# Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 

### Report For: David Smith 

# Laboratory ID: AB07065

Date and Time Collected: Sampled By: 

## Sample Information G. HAGAN Description: 

## Location Code: 09/15/2010 Report Date:

Big Bend ICR Fuel Analysis 

## TE_BB_ICR_FUEL

W4 Project Account Code: 04/26/2010 Date of Sample Receipt: Sample Collection Method: 

## Laboratory Results 04/22/2010 10:00:00 AM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit 60 Mesh Residual Moisture % ASTM D-5142 KAPXJ 3.04 05/24/2010 9:57:00 AM Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 8.36 05/24/2010 9:57:00 AM BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 13060 0 5/07/2010 10:23:00 AM BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 12416 09/15/2010 9:55:00 AM Carbon, as Determd., by CHN % 0.1 ASTM D-5373 KAPXJ 71.53 09/14/2010 3:42:00 PM Chlorine as Cl, as Received % 0.01 ASTM4208/300 KAPXJ 0.18 05/24/2010 4:39:00 PM Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KAPXJ 0.19 05/24/2010 4:39:00 PM Chlorine by Bomb/IC, as Determd. % 0.01 ASTM D-4208 KASZS 0.18 05/05/2010 1:36:00 PM Fixed Carbon % ASTM D-5142 KAPXJ 52.88 05/24/2010 9:57:00 AM Fluorine as F, as Received % 0.01 ASTM D-3761 KASZS 0.01 I 05/05/2010 1:36:00 PM Fluorine as F, Dry Basis % 0.01 ASTM D-3761 KASZS 0.0068 05/05/2010 1:36:00 PM Fluorine in Coal, Dry Basis ug/g 2 ASTM3761/300 KASZS 68 05/05/2010 1:36:00 PM Hydrogen, as Received % 0.14 ASTM D-5373 KAPXJ 4.51 09/15/2010 9:55:00 AM Mercury - Direct Combustion ug/g dry basis 0.03 ASTM D6722 KAMCR 0.123 0 6/16/2010 10:01:00 AM Mercury in Coal, 1st result ug/g 0.02 ASTM D3684 KAMCR 0.119 06/14/2010 9:00:00 AM Net Heat of Combustion, COAL, (LHV) BTU/Lb. ASTM D-5865 KAPXJ 11998 09/15/2010 9:55:00 AM Nitrogen, as Determd., by CHN % 0.1 ASTM D-5373 KAPXJ 1.42 09/14/2010 3:42:00 PM Selenium mg/kg 1.0 EPA 6010 KAMCR < 1.0 U 05/18/2010 1:15:00 PM Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 3.22 0 5/11/2010 11:44:00 AM Total Moisture % 0.1 ASTM D-3173 KAPXJ 7.82 05/24/2010 4:39:00 PM 

### Trace Metals in Coal by ICP Manganese ug/g dry basis ASTM 6357 KAPXJ 0.2 05/24/2010 4:39:00 PM Beryllium ug/g dry basis ASTM 6357 KAPXJ 0.2 05/24/2010 4:39:00 PM Chromium ug/g dry basis ASTM 6357 KAPXJ 0.2 05/24/2010 4:39:00 PM Arsenic ug/g dry basis ASTM 6357 KAPXJ 2.7 05/24/2010 4:39:00 PM Chromium ug/g dry basis ASTM 3682 KAPAP 21.5 06/29/2010 4:09:00 PM

Report Number: 

### Page 1 of 2 "General Report" AB07065-091510-12 Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicat ed otherwise in the body of the report. Unless otherwise noted, all methods followed are per the most current published version of 40 CFR P art 136, Table B. Results reported on this report pertain to the above referenced sample only.

# Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272



### Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit Manganese ug/g dry basis ASTM 3682 KAPAP 27.2 06/29/2010 4:09:00 PM Cadmium ug/g dry basis ASTM 6357 KAPXJ 0.8 05/24/2010 4:39:00 PM Lead ug/g dry basis ASTM 6357 KAPXJ 7.4 05/24/2010 4:39:00 PM Beryllium ug/g dry basis ASTM 3682 KAPAP <0.1 06/29/2010 4:09:00 PM Nickel ug/g dry basis ASTM 6357 KAPXJ 7.4 05/24/2010 4:39:00 PM Volatiles, Dry Basis % 1.40 ASTM D-5142 KAPXJ 36.83 05/24/2010 9:57:00 AM 

## Comments

Manager, Laboratory Services U - Indicates that the compound was analyzed for but not detected. I - The reported value is between the laboratory method detection limit (MDL) and t he laboratory practical quantitation limit ( PQL). PQL = 4 x MDL. All results calculated on a wet to wet basis, unless otherwise indicated.
Data Qualifier Codes Explanation: 

### Unit #1 Stack Test collected 4-22-10

Should there be any questions regarding this report, please contact:

(813) 630-7490 Patrice Jackson,, Designee for Peggy Penner

Report Number: 

### Page 2 of 2 "General Report" AB07065-091510-12 Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicat ed otherwise in the body of the report. Unless otherwise noted, all methods followed are per the most current published version of 40 CFR P art 136, Table B. Results reported on this report pertain to the above referenced sample only.