# Patent

## Title
Color electrophoretic display

## Abstract

The present invention is directed to a color display device wherein each of the display cells is filled with an electrophoretic fluid comprising two types of charged pigment particles dispersed in a colored medium. Multiple colors of high quality may be achieved by the present invention.

## Background
This application is a continuation-in-part of U.S. application Ser. No. 13/482,913, filed May 29, 2012, which claims priority to U.S. Provisional Application No. 61/492,747, filed Jun. 2, 2011; the contents of the above-identified applications are incorporated herein by reference in their entirety.


FIELD OF THE INVENTION
This invention relates to a color electrophoretic display utilizing two types of charged pigment particles dispersed in a colored solvent or solvent mixture.
DESCRIPTION OF RELATED ART
In order to achieve a multicolor display, color filters are often used. The most common approach is to add color filters on top of black/white sub-pixels of a pixellated display to display the red, green and blue colors. When a red color is desired, the green and blue sub-pixels are turned to the black state so that the only color displayed is red. When the black state is desired, all three sub-pixels are turned to the black state. When the white state is desired, the three sub-pixels are turned to red, green and blue, respectively, and as a result, a white state is seen by the viewer.
A major disadvantage of such a technique is that since each of the sub-pixels has a reflectance of about one third of the desired white state, the white state is fairly dim. To compensate this, a fourth sub-pixel may be added which can display only the black and white states, so that the white level is doubled at the expense of the red, green or blue color level (where each sub-pixel is only one fourth of the area of the pixel).
Brighter colors can be achieved by adding light from the white pixel; but this is achieved at the expense of color gamut to cause the colors to be very light and unsaturated. A similar result can be achieved by reducing the color saturation of the three sub-pixels. Even with that, the white level is normally substantially less than half of that of a black and white display, rendering it an unacceptable choice for display devices, such as e-readers or displays that need well readable black-white brightness and contrast.
SUMMARY OF THE INVENTION
The present invention is directed to a display device comprising display cells, wherein each of said display cells is
a) sandwiched between a first layer comprising a common electrode and a second layer comprising a pixel electrode, and
b) filled with a display fluid comprising a first type of pigment particles which are white and a second type of pigment particles which are red, green or blue and said two types of pigment particles are oppositely charged and are dispersed in a colored solvent.
In one embodiment, the white pigment particles are formed from TiO2.
In one embodiment, at least one type of the pigment particles are encapsulated pigment particles.
In one embodiment, the display fluid further comprises a charge control agent.
In one embodiment, the colored solvent is a black solvent.
In one embodiment, the black solvent is a clear and colorless solvent with non-charged or slightly charged black particles dispersed therein.
In one embodiment, the non-charged or slightly charged black particles are substantially transparent.
In one embodiment, the non-charged or slightly charged black particles have a zeta potential of <20.
In one embodiment, the non-charged or slightly charged black particles are polymeric and are in the form of a transparent polymeric matrix, with dye molecules embedded in the matrix.
In one embodiment, the colored solvent has a color which is complementary to the second type of pigment particles.
In one embodiment, the colored solvent is a clear and colorless solvent with non-charged or slightly charged colored particles dispersed therein.
In one embodiment, the second layer further comprises at least one in-plane electrode and said device further comprises a white background layer.
In one embodiment, each display cell defines a sub-pixel and three sub-pixels forms a pixel.
In one embodiment, each display cell defines a sub-pixel and two sub-pixels form a pixel.
In one embodiment, a display fluid comprises a first type of pigment particles which is white and a second type of pigment particles which is colored, and said two types of pigment particles are oppositely charged and dispersed in a black solvent, wherein said black solvent comprises non-charged or slightly charged black particles dispersed in a clear and colorless solvent.
In one embodiment, a display fluid comprises a first type of pigment particles which is white and a second type of pigment particles which is colored, and said two types of pigment particles are oppositely charged and dispersed in a colored solvent, wherein the colored solvent comprises non-charged or slightly charged colored particles dispersed in a clear and colorless solvent and the color of the non-charged or slightly charged colored particles is complementary to the color of the second type of pigment particles.



BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1a-1c depict how an electrophoretic display of the present invention displays different color states.
FIGS. 2a-2c depict an alternative design.
FIGS. 3a-3e illustrate the color display application of the present invention.
FIGS. 4a-4d depict a further alternative design.
FIGS. 5a-5e illustrate the color display application utilizing the design of FIG. 4.



DETAILED DESCRIPTION OF THE INVENTION
The present invention is directed to an electrophoretic fluid comprising two types of charged pigment particles dispersed in a colored solvent or solvent mixture.
First Design
In the first aspect of the present invention, the display fluid comprises white charged pigment particles and a second type of charged pigment particles which may be red, green or blue. The two types of charged pigment particles are dispersed in a black solvent.
The white charged pigment particles may be any types of white pigment particles, including inorganic, organic or polymeric white particles. To achieve a high light scattering, pigments of a high refractive index are particularly useful. Suitable white pigment particles may include TiO2, BaSO4 and ZnO, with TiO2 being the most preferred. The white pigment particles may be positively charged or negatively charged.
The colored charged pigment particles may also be inorganic, organic or polymeric particles formed from a pigment, such as pigment red 254 (chemical group diketopyrrolopyrrole), pigment blue 15:6 (chemical group phthalocyanine), pigment green 36 (chemical group Cu phthalocyanine), pigment yellow 155 (chemical group bisacetoacetarylide), pigment red 122 (chemical group quinacridone), pigment blue 15:3 (chemical group phthalocyanine), pigment black 7 (chemical group carbon black) or the like.
The two types of charged pigment particles may also be encapsulated pigment particles.
The two types of charged pigment particles are oppositely charged, and they may exhibit a native charge, or may be charged explicitly using a charge control agent, or may acquire a charge when dispersed in a solvent.
Suitable charge control agents are well known in the art; they may be polymeric or non-polymeric in nature or may be ionic or non-ionic.
The ionic surfactants as charge control agent may include (a) the anionic type: alkane carboxylic salts, alkane sulfonic salts, such as Aerosol OT, alkyl-aromatic sulfonic salts, such as sodium dodecylbenzenesulfonate, isopropylamine, alkyl benzene sulfonate, phosphates, phosphoric salts or the like, and (b) the cationic type: fatty amine salts, quaternary ammonium salts, alkyl pyridium salts or the like.
The non-ionic surfactants as charge control agent may include sorbitan monoesters, polyethoxylated nonionics, polybutene succinimide, maleic anhydride copolymers, vinylpyridine copolymers, vinylpyrrolidone copolymer (such as GanexTM from International Specialty Products), (meth)acrylic acid copolymers, N,N-dimethylaminoethyl (meth)acrylate copolymers and the like.
Fluorosurfactants are particularly useful as charge controlling agent in a fluorocarbon solvent. These include FC fluorosurfactants such as FC-170CTM, FC-171TM, FC-176TM, FC430TM, FC431TM and FC740TM from 3M Company and ZonylTM fluorosurfactants such as ZonylTM FSA, FSE, FSN, FSN-100, FSO, FSO-100, FSD and UR from Dupont.
The solvent, in the context of the present invention, may be a colored solvent or solvent mixture or alternatively a clear and colorless solvent with non-charged or slightly charged colored particles dispersed therein.
In the case of a colored solvent or solvent mixture, it preferably has a low viscosity and a dielectric constant in the range of about 2 to about 30, preferably about 2 to about 15 for high particle mobility. Examples of suitable dielectric solvent include hydrocarbons such as isopar, decahydronaphthalene (DECALIN), 5-ethylidene-2-norbornene, fatty oils, paraffin oil, silicone oil, such as DC200 from Dow Corning, aromatic hydrocarbons such as toluene, xylene, phenylxylylethane, dodecylbenzene or alkylnaphthalene; halogenated solvents such as perfluorodecalin, perfluorotoluene, perfluoroxylene, dichlorobenzotrifluoride, 3,4,5-trichlorobenzotrifluoride, chloropentafluoro-benzene, dichlorononane or pentachlorobenzene; and perfluorinated solvents such as FC-43, FC-70 and FC-5060 from 3M Company, St. Paul Minn., low molecular weight halogen containing polymers such as poly(perfluoropropylene oxide) from TCI America, Portland, Oreg., poly(chlorotrifluoroethylene) such as Halocarbon Oils from Halocarbon Product Corp., River Edge, N.J., perfluoropolyalkylether such as Galden from Ausimont or Krytox Oils and Greases K-Fluid Series from DuPont, Del.
A black colorant is added to the solvent to generate the black color. Alternatively, the black color of the solvent may be achieved by a mixture of colorants to achieve the appearance of a black color.
As stated, the solvent may also be a clear and colorless solvent with non-charged or slightly charged colored particles dispersed therein. The non-charged or slightly charged colored particles are substantially transparent and the color transparency comes from the refractive index similarity between the colored non-charged or slightly charged particles and the solvent in which the particles are dispersed. The non-charged or slightly charged colored particles may have, for example, a zeta potential of <20, preferably <10, more preferably <5 and most preferably <2.
If the refractive index of the non-charged or slightly charged colored particles is not matched to that of the solvent in which the particles are dispersed, the particles may scatter light in the display fluid. In order to eliminate problems associated with the mismatch of the refractive indices, the size of the non-charged or slightly charged colored particles is preferably in the nanometer range, more preferably less than 100 nanometers. Materials for this type of non-charged or slightly charged colored particles may include, but are not limited to, commercially available colorants used in the LCD industry for color filter applications, such as Clariant's Hostaperm Red D2B-COF VP 3781 (i.e., red 254) which is in the class of diketopyrrolopyrrole, Hostaperm Blue E3R-COF VP3573 (i.e., blue 15:6) which is in the class of phthalocyanine, or Hostaperm Violet RL-COF O2 VP3101 (i.e., violet 23) which is in the class of dioxazine.
Alternatively, the non-charged or slightly charged colored particles may be polymeric and are in the form of a transparent polymeric matrix, with dye molecules embedded (e.g., solubilized or dispersed) in the matrix. Since it is easier to match the refractive indices of a polymer matrix and the surrounding solvent, the size of the non-charged or slightly charged particles does not need to be tightly controlled. Examples of this type of non-charged or slightly charged colored particles may include, but are not limited to, dyed polymeric microparticles supplied by Merck Chemicals Ltd.; dyed polystyrene particles supplied by Spherotech Inc. or the like. For the colored particles with a transparent polymeric matrix, the dye embedded (soluble or dispersible) therein is much more dilute and adjustable. For example, the concentration of the red dye in the red particles may be adjusted to allow only the blue or green colors to be absorbed and the red color to pass through. With a white background to reflect the red color, the red color brightness can be maximized.
FIGS. 1a-1c depict an example of how a display cell filled with such a display fluid may display three different color states.
As shown in FIG. 1a, a display cell (10) is sandwiched between a first layer (11) comprising a common electrode (11a) and a second layer (12) comprising a pixel electrode (12a) and the display cell is filled with an electrophoretic fluid comprising white charged pigment particles (13) and blue charged pigment particles (14), dispersed in a black solvent.
The white and blue pigment particles are oppositely charged. For example, if the white pigment particles are positively charged, then the blue pigment particles are negatively charged. Accordingly, the two types of charged pigment particles (13 and 14) may move towards the common electrode (11a) or the pixel electrode (12a), depending on the charge polarity of the particles and the voltage potential difference applied to the common electrode and the pixel electrode.
In this example, the common electrode is on the viewing side.
In FIG. 1a, when proper voltages are applied to the common electrode (11a) and the pixel electrode (12a), the charged blue particles (14) would move to be near or at the common electrode (11a) and the oppositely charged white pigment particles (13) would move to be near or at the pixel electrode (12a), causing the blue color to be seen at the viewing side.
In FIG. 1b, when proper voltages are applied to the common electrode (11a) and the pixel electrode (12a), the charged blue particles (14) would move to be near or at the pixel electrode (12a) and the oppositely charged white pigment particles (13) would move to be near or at the common electrode (11a), causing the white color to be seen at the viewing side.
In FIG. 1c, both the blue (14) and the white particles (13) are dispersed throughout the volume of the black solvent. In this case, the viewer sees the black color state. The voltages applied to the common and pixel electrodes, after the particles are dispersed, may be positive, negative or zero as long as they are substantially the same.
Second Design
FIGS. 2a-2c illustrate an alternative design of the present invention. As shown in FIG. 2a, a display cell (20) is sandwiched between a first layer (21) comprising a common electrode (21a) and a second layer (22) comprising one pixel electrode (22a).
The display cell (20) is filled with an electrophoretic fluid comprising two types of charged particles, white charged pigment particles (23) and colored charged pigment particles (24), dispersed in a colored solvent. In FIG. 2, the colored pigment particles are blue.
In practice, the colored pigment particles may be red, green or blue and the color of the colored charged pigment particles and the color of the solvent in which the particles are dispersed are complementary. For example, if the color of the particles is red, the color of the solvent would be green or blue. Likewise, if the color of the particles is blue, the color of the solvent then may be red or green.
Therefore the term “complementary color” refers to red, green or blue color and they are complementary to each other. For example, a red color is considered complementary to green or blue; a green color is considered complementary to red or blue; and a blue color is considered complementary to red or green.
Other features (e.g., charge controlling agents and medium) described above for the system of FIG. 1 are also applicable to this design.
Colorants for generating the color of the solvent include a variety of dyes or pigments which are well-known in the art, for example, they may be, but are not limited to, azo or phthalocyanine dyes or the like.
The colored solvent may be replaced with a clear and colorless solvent with non-charged or slightly charged colored particles solubilized or dispersed therein, as described above.
The white pigment particles may be positively or negatively charged and the blue pigment particles are oppositely charged. In this example, the common electrode is on the viewing side.
In FIG. 2a, when proper voltages are applied to the common electrode (21a) and the pixel electrode (22a), the charged blue pigment particles (24) would move to be near or at the common electrode (21a), causing the blue color to be seen at the viewing side.
In FIG. 2b, when proper voltages are applied to the common electrode (21a) and the pixel electrode (22a), the charged white particles (23) would move to be near or at the common electrode (21a), causing the white color to be seen at the viewing side.
In FIG. 2c, both types of pigment particles are dispersed in the green solvent. In this case, a black color is seen at the viewing side because the blue and green colors are complementary colors so that the green reflected light is absorbed by the blue particles and there are enough of the blue particles to absorb the light reflected off the white particles.
While in the examples of FIGS. 1 and 2, the color of the charged pigment particles and the color of the solvent may be varied, as required by the display application.
The display cells as shown in FIGS. 1 and 2 therefore are ideal for a color display device wherein each pixel consists of three sub-pixels.
For the design of FIG. 1, one of the display cells (sub-pixel) may be filled with a fluid comprising white charged pigment particles and blue charged pigment particles dispersed in a black solvent, a second display cell may be filled with a fluid comprising white charged pigment particles and green charged pigment particles dispersed in a black solvent and the third display cell may be filled with a fluid comprising white charged pigment particles and red charged pigment particles dispersed in a black solvent.
FIG. 3 illustrates how multiple colors are displayed with a display device comprising the display fluid of the present invention. Each display cell represents a sub-pixel and each pixel has three sub-pixels. The three display cells, each representing a sub-pixel, are filled with display fluids as described above.
In FIG. 3a, when a white pixel is desired, all three sub-pixels are turned to the white color state. In FIG. 3b, when a black pixel is desired, all three sub-pixels are turned to the black state. FIG. 3c, when a red color is desired, one of the sub-pixels is turned to red and the remaining two sub-pixels are turned to the black state for maximum color saturation. Similarly, FIG. 3d and FIG. 3e display the green and blue colors respectively. Alternatively, in FIGS. 3c, 3d and 3e, one of the sub-pixels is driven to the color state while the remaining two sub-pixels are driven to the white state for maximum brightness (at the expense of the color saturation). Further alternatively, in FIGS. 3c, 3d and 3e, one of the sub-pixels is driven to the color state while the remaining two sub-pixels are driven to the black and white states respectively. Such a full color display can have the same black and white characters of a good black and white display, but also show red, green and blue colors of high quality.
FIG. 3 may also be applicable to the design of FIG. 2. The advantage of the scheme in FIG. 2 is that the achievable white state will be higher than that achievable in the scheme in FIG. 1 because the interstitial absorption in the white state will be one third of that in FIG. 1. On the other hand, in order to achieve the best possible black state, the absorption of the colored fluid, the depth of the display cell and the particle concentration will have to be tightly controlled.
In order to achieve better whiteness, a fourth sub-pixel may be added in FIG. 3, which sub-pixel can only display either white or black color state.
Third Design
FIG. 4 illustrates a further alternative design. This design is similar to the design of FIG. 2, except that in the second layer (42), there is at least one in-plane electrode (42b and 42c) and the pixel electrode (42a) is sandwiched between the two in-plane electrodes. There are gaps between the electrodes.
In addition, there is a white background layer (45), which may be above or underneath the second layer. Alternatively, the second layer may serve as the background layer.
In the example of FIGS. 4a-4d, white and blue charged pigment particles are dispersed in a green solvent.
The operations of FIGS. 4a-4d are similar to those of FIG. 2a-2c, when proper voltages are applied to the common, pixel and in-plane electrodes.
In FIG. 4a, the blue charged pigment particles move to be at or near the common electrode (41a), the blue color is seen. In FIG. 4b, the white charged pigment particles move to be at or near the common electrode (41a), the white color is seen. In FIG. 4c, the white and blue pigment particles are dispersed in the green solvent and as a result, the black color state is seen.
In this alternative design, there is an additional color state (see FIG. 4d), that is, when proper voltages are applied to the common (41a), pixel (42a) and in-plane (42b and 42c) electrodes, the white and blue pigment particles move separately to be at or near the in-plane electrodes. In this case, the green color is seen at the viewing side.
Therefore in this alternative design, each display cell can display four color states, black, white, the color of the colored particles and the color of the solvent. The color of the colored pigment particles and the color of the solvent are complementary to each other.
The colored solvent in this design may also be replaced with a clear and colorless solvent with non-charged or slightly charged colored particles embedded therein, as described above.
In this case, each pixel only needs to have two sub-pixels. FIG. 5 is an example illustrating this scenario. Each display cell represents a sub-pixel. Display cell X in the figure is filled with a fluid comprising white charged pigment particles and red charged pigment particles dispersed in a green solvent and display cell Y is filled with a fluid comprising white charged pigment particles and red charged pigment particles dispersed in a blue solvent.
When a white pixel is desired, both display cells are turned to the white (W) state (see FIG. 5a) and when a black pixel is desired, both display cells are turned to the black (K) state (see FIG. 5b). When a blue pixel is desired, cell X is turned to the black (K) state while cell Y is turned to the blue (B) state (see FIG. 5c). When a green pixel is desired, cell X is turned to the green (G) state while cell Y is turned to the black (K) state (see FIG. 5d). When a red pixel is desired, cell X is turned to the red (R) color state while cell Y is turned to the black (K) state (see FIG. 5e). Alternatively, cell X in FIG. 5c, cell Y in FIG. 5d or cell Y in FIG. 5e may be turned to the white state instead of black, providing a brighter but less saturated color.
As stated, FIG. 5 is an example, and alternative combinations are also possible to achieve the five color states.
It is also noted that the voltages applied to the electrodes illustrated in the designs of FIGS. 1, 2 and 4 are usually in the form of waveforms. In other words, the images displayed by the display devices of the present invention may be achieved by the application of a series of waveforms. It should also be noted that the electrode configurations of 42a, 42b and 42c in FIG. 4 may be of any size and shape as long as they can collect both sets of particles to different portions of the display cell.
The display cells referred to in the present application may be of a conventional walled or partition type, a microencapsulated type or a microcup type. In the microcup type, the electrophoretic display cells may be sealed with a top sealing layer. There may also be a primer layer between the electrophoretic display cells and the common electrode. The term “display cell” is intended to refer to a micro-container which is individually filled with a display fluid. Examples of “display cell” include, but are not limited to, microcups, microcapsules, micro-channels, other partition-typed display cells and equivalents thereof.
While particular forms of the invention have been illustrated and described, it will be apparent that various modifications can be made without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation, materials, compositions, processes, process step or steps, to the objective, spirit and scope of the present invention. All such modifications are intended to be within the scope of the claims appended hereto.

## Claims

1. A display fluid comprising a first type of pigment particles which is white and a second type of pigment particles which is colored, and said two types of pigment particles are oppositely charged and dispersed in a black solvent, wherein said black solvent comprises non-charged or slightly charged black particles dispersed in a clear and colorless solvent.

2. The fluid of claim 1, wherein said second type of pigment particles is non-white and non-black.

3. The fluid of claim 1, wherein said second type of pigment particles is red, green, blue, cyan, magenta or yellow.

4. The fluid of claim 1, wherein said second type of pigment particles is red, green or blue.

5. The fluid of claim 1, wherein said non-charged or slightly charged black particles are substantially transparent.

6. The fluid of claim 1, wherein the non-charged or slightly charged black particles have a size of less than 100 nanometers.

7. The fluid of claim 1, wherein the non-charged or slightly charged black particles have a zeta potential of <20.

8. The fluid of claim 1, wherein the non-charged or slightly charged black particles are polymeric and in the form of a transparent polymeric matrix, with dye molecules embedded in the matrix.

9. A display device comprising the display fluid of claim 1, wherein said fluid is sandwiched between a first layer comprising a common electrode and a second layer comprising pixel electrodes.

10. A display fluid comprising a first type of pigment particles which is white and a second type of pigment particles which is colored and said two types of pigment particles are oppositely charged and dispersed in a colored solvent, wherein the colored solvent comprises non-charged or slightly charged colored particles dispersed in a clear and colorless solvent and the color of the non-charged or slightly charged colored particles is complementary to the color of the second type of pigment particles.

11. The fluid of claim 10, the second type of pigment particles dispersed in the colored solvent gives the appearance of a black color.

12. The fluid of claim 10, wherein said second type of pigment particles is non-white and non-black.

13. The fluid of claim 10, wherein said second type of pigment particles is red, green, blue, cyan, magenta or yellow.

14. The fluid of claim 10, wherein said second type of pigment particles is red, green or blue.

15. The fluid of claim 10, wherein said non-charged or slightly charged colored particles are substantially transparent.

16. The fluid of claim 10, wherein said non-charged or slightly charged colored particles have a size of less than 100 nanometers.

17. The fluid of claim 10, wherein the non-charged or slightly charged colored particles have a zeta potential of <20.

18. The fluid of claim 10, wherein the non-charged or slightly charged colored particles are polymeric and in the form of a transparent polymeric matrix, with dye molecules embedded in the matrix.

19. A display device comprising the display fluid of claim 10, wherein said fluid is sandwiched between a first layer comprising a common electrode and a second layer comprising pixel electrodes.

20. A display device which comprises a display fluid of claim 10 and said fluid is sandwiched between a first layer comprising a common electrode and a second layer comprising pixel electrodes and in-plane electrodes.