Area of Review and Corrective Action Plan for FutureGen Alliance Page B1 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### ATTACHMENT B: AREA OF REVIEW AND CORRECTIVE ACTION PLAN

Facility Information

Facility Name: FutureGen 2.0 Morgan County CO 2 

### Storage Site

IL -137-6A-0004 (W ell #4 )

Facility Contacts: Kenneth Humphreys, Chief Executive Officer,

FutureGen Industrial Alliance, Inc., Morgan County Office,

73 Central Park Plaza East, Jacksonville, IL 62650, 217-243-8215

L ocation of Injection Well: Morgan County, IL; 26−16N−9W; 39.80111oN and 90.07544oW

Computational Modeling

Model Name: STOMP-CO2 (Subsurface Transport Over Multiple Phases- CO 2) simulator

Model Authors/Institution: White et al. 2013 ; White and Oostrom 2006; White and McGrail

2005/Pacific Northwest National Laboratory (PNNL)

Description of Model:

The simulations conducted for this investigation were executed using the STOMP-CO2

simulator (White et al. 2013; White and Oostrom 2006; White and Oostrom 2000). STOMP-CO2

was verified against other codes used for simulation of geologic disposal of CO 2 

### as part of the

GeoSeq code intercomparison study (Pruess et al. 2002).

Partial differential conservation equations for fluid mass, energy, and salt mass compose the

funda mental equations for STOMP-CO2. Coefficients within the fundamental equations are

related to the primary variables through a set of constitutive relationships. The salt transport

equations are solved simultaneously with the component mass and energy conservation

equations. The solute and reactive species transport equations are solved sequentially after the

coupled flow and transport equations. The fundamental coupled flow equations are solved using

an integral volume finite-difference approach with the nonlinearities in the discretized equations

resolved through Newton-Raphson iteration. The dominant nonlinear functions within the

STOMP-CO2 simulator are the relative permeability-saturation-capillary pressure (k-s-p)

relationships.

The STOMP-CO2 simulator allows the user to specify these relationships through a large variety

of popular and classic functions. Two-phase (gas-aqueous) k-s-p relationships can be specified

with hysteretic or nonhysteretic functions or nonhysteretic tabular data. Entrapment of CO 2 

### with

imbibing water conditions can be modeled with the hysteretic two-phase k-s-p functions. Twophase k-s-p relationships span both saturated and unsaturated conditions. The aqueous phase is

assumed to never completely disappear through extensions to the s-p function below the residualArea of Review and Corrective Action Plan for FutureGen Alliance Page B2 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### saturation and a vapor pressure lowering scheme. Supercritical CO 2 

### has the function of a gas in

these two-phase k-s-p relationships.

For the range of temperature and pressure conditions present in deep saline reservoirs, four

phases are possible: 1) water-rich liquid (aqueous), 2) CO 2



### - rich vapor (gas), 3) CO 2 

### -rich liquid

(liquid- CO 2 

### ), and 4) crystalline salt (precipitated salt). The equations of state express 1) the

ex istence of phases given the temperature, pressure, and water, CO 2 

### , and salt concentration; 2)

the partitioning of components among existing phases; and 3) the density of the existing phases.

Thermodynamic properties for CO 2 

### are computed via interpolation from a property data table

stored in an external file. The property table was developed from the equation of state for CO 2 

### publi shed by Span and Wagner (1996). Phase equilibria calculations in STOMP-CO2 use the

for mulations of Spycher et al. (2003) for temperatures below 100°C and Spycher and Pruess

(2010 ) for temperatures above 100°C, with corrections for dissolved salt provided in Spycher

a nd Pruess (2010). The Spycher formulations are based on the Redlich-Kwong equation of state

with par ameters fitted from published experimental data for CO 2 

### -H2O systems. Additional

details regarding the equations of state used in STOMP-CO2 can be found in the guide by White

e t al. (2013).

A well model is defined as a type of source term that extends over multiple grid cells, where the

well diameter is smaller than the grid cell. A fully coupled well model in STOMP-CO2 was used

to simulate the injection of supercritical CO 2 

### (scCO 2 

### ) under a specified mass injection rate,

subject to a pressure limit. When the mass injection rate can be met without exceeding the

spe cified pressure limit, the well is considered to be flow controlled. Conversely, when the mass

inj ection rate cannot be met without exceeding the specified pressure limit, the well is considered

to be pr essure controlled and the mass injection rate is determined based on the injection

pre ssure. The well model assumes a constant pressure gradient within the well and calculates the

inj ection pressure at each cell in the well. The CO 2 

### injection rate is proportional to the pressure

g radient between the well and surrounding formation in each grid cell. By fully integrating the

well equations into the reservoir field equations, the numerical convergence of the nonlinear

conservation and constitutive equations is greatly enhanced.

M odel Inputs and Assumptions:

Conceptual Model

Site S tratigraphy

The regional geology of Illinois is well known from wells and borings drilled in conjunction with

hydrocarbon exploration, aquifer development and use, and coal and commercial mineral

exploration. Related data are largely publicly available through the Illinois State Geological

Survey (ISGS) 1 

### and the U.S. Geological Survey. 2 

### In addition, the U.S. Department of Energy has

sponsore d a number of studies by the Midwest Geologic Sequestration Consortium 3 

### to evaluate

subsurface strata in Illinois and adjacent states as possible targets for the containment of

anthropogenic CO 2



### .

1 http://www.isgs.uiuc.edu/

2 http://www.usgs.gov/

3 http://sequestration.org/Area of Review and Corrective Action Plan for FutureGen Alliance Page B3 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### To support the evaluation of the Morgan County site as a potential carbon storage site, a deep

stratigraphic well was drilled and extensively characterized. The FutureGen 2.0 stratigraphic

we ll, located at longitude 90.05298W, latitude 39.80681N, is approximately 1.24 mi (2 km)

northeast of the planned injection site. The stratigraphic well reached a total depth of 4,826 ft

(1,47 1 m) below ground surface (bgs) within the Precambrian basement ( F igure 1 ). The well

penetrated 479 ft (146 m) of the Eau Claire Formation and 512 ft (156 m) of the Mount Simon

S andstone. The stratigraphic well was extensively characterized, sampled, and geophysically

logged during drilling. A total of 177 ft of whole core were collected from the lower Eau Claire

Formation and upper Mount Simon Sandstone and 34 ft were collected from lower Mount Simon

Sandstone and Precambrian basement interval. In addition to whole drill core, a total of 130 sidewall core plugs were obtained from the combined interval of the Eau Claire Formation, Mount

Simon Sandstone, and the Precambrian basement. In Figure 2 , cored intervals are indicated with

re d bars; rotary side-wall core and core-plug locations are indicated to the left of the lithology

panel. Standard gamma ray and resistivity curves are shown in the second panel.Area of Review and Corrective Action Plan for FutureGen Alliance Page B4 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4)

Figure 1

. Stratigraphic Column of FutureGen 2.0 Stratigraphic WellArea of Review and Corrective Action Plan for FutureGen Alliance Page B5 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) Figure 2. Lithology, Mineralogy, and Hydrologic Units of the Proposed Injection Zone (Mount Simon,

Elmhurst and Lower Lombard member) and Lower Primary Confining Zone (Upper Lombard), as

Encountered Within the Stratigraphic Well



### Geologic Structures

Two orthogonal two-dimensional (2D) surface seismic lines, shown in F igure 3 , were acquired

along public roads near the site and processed in January and February 2011. Surface seismic

da ta were acquired as single-component data. The seismic data are not of optimal quality due to

loss of frequency and resolution below a two-way time depth of about 300 milliseconds (ms),

approximately coincident with the top of the Galena limestone at a depth of 1,400 ft. However,

they do not indicate the presence of obvious faults or large changes in thickness of the injection

or c onfining zones. Both profiles indicate a thick sequence of Paleozoic-aged rocks with a

contact between Precambrian and Mount Simon at 640 ms and a contact between Eau Claire and

Mount Simon at 580 ms.

S ome vertical disruptions, which extend far below the sedimentary basin, remain after

re processing in 2012, but their regular spatial periodicity has a high probability of being an

a rtifact during data acquisition and processing and is unlikely related to faults.

No discernable faults have been identified on the 2D data within the immediate area. A small

growth fault that affects the Mount Simon and Eau Claire formations is interpreted in the eastern

part of the L201 profile at an offset 28,000 ft. This growth fault is more than 1.5 miles away

from the outermost edge of the CO 2 

### plume and does not extend far upward in the overburden.

For these reasons, it is highly unlikely that it could affect the integrity of the injection zone.Area of Review and Corrective Action Plan for FutureGen Alliance Page B6 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) Figure 3

. Locations of Two 2D Seismic Survey Lines, L101 and L201, Vertical Seismic Profile Locations, and

the Knox Line Near the Proposed Morgan County CO 2 Storage Site



### A three-component vertical seismic profiling (VSP) data set ( Figure 3 ) was acquired in the

FutureGen stratigraphic well in March 2013, and processed by Schlumberger Carbon Services.

No discernable faults are present in the 15 short 2D seismic lines formed by the offset VSP

locations. These lines represent a lateral interrogation extent of 800−1600 ft radially from the

stratigraphic well. The high-resolution, low-noise VSP data also do not contain the vertical

disrupti ons observed in the 2D surface seismic profiles (Hardage 2013 4 

### ).

The ISGS recently shot a 120-mi long seismic reflection survey (the Knox Line) across central

Illinois as part of a Department of Energy-sponsored research project to characterize rock units

for geologic storage of CO 2 

### . The continuous east-west line extends from Meredosia to

sout hwestern Champaign County ( Figure 3 ). FutureGen Industrial Alliance, Inc., (FutureGen

Alliance) acquired these data from the ISGS with the intention of reprocessing the data, if

ne eded, to identify regional faults that might impact the proposed FutureGen 2.0 Morgan County

CO 2 

### Storage Site (FutureGen 2.0 S ite ). A review of the data by a geophysical expert on Illinois

reflection seismic data 5 

### , indicated that there was no discernable faulting west of Ashland,

4 Bob Hardage. Personal Communication with Charlotte Sullivan, August 1, 2013.

5 John McBride. Personal Communication with Charlotte Sullivan, October 29, 2013.Area of Review and Corrective Action Plan for FutureGen Alliance Page B7 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### Illinois; and that current plans to reprocess the ISGS Knox line would not likely result in a

greatly improved image.

The closest known earthquake to the FutureGen 2.0 S ite (Intensity VII, magnitude 4.8 – non

instrumented record) occurred on July 19, 1909, approximately 28 mi (45 km) north of the site; it

caused slight damage. Most of the events in Illinois occurred at depths greater than 1.9 mi (3

km).

Conceptual Model Domain

A stratigraphic conceptual model of the geologic layers from the Precambrian basement to

ground surface was constructed using the EarthVision® software package. The geologic setting

and site characterization data described in the Underground Injection Control (UIC) Permit

Supporting Documentation and later in this section were the basis for the Morgan County CO 2 

### storage site computational model. Borehole data from the FutureGen 2.0 stratigraphic well and

data from regional boreholes and published regional contour maps were used as input data

(F igure 4, step 1). There is a regional dip of approximately 0.25 degrees in the east-southeas t

direction (Figure 4, step 2). To define the numerical model domain, an expanded 100- by 100-

mi conceptual model was constructed to represent units below the Potosi dolomite interval,

including the formations of Franconia, Ironton, Eau Claire (Proviso, Lombard, and Elmhurst),

and Mount Simon. Each of these formation layers was further divided into multiple sub-layers

based on the data from the stratigraphic well. The elevations of Franconia top, Mount Simon top,

and Mount Simon Bottom were determined by EarthVision® based on borehole data and

regional contour maps. The elevations of the interfaces between sub-layers were determined by

the three bounding surfaces from EarthVision® and the stratigraphic well to make up the

boundary-fitted stratigraphic layers of the computational model. The numerical model grid in

the horizontal directions was designed to have constant grid spacing with higher resolution in the

a rea influenced by the CO 2 

### injection (3-mi by 3-mi area), with increasingly larger grid spacing

moving out toward the domain boundaries. The conceptual model hydrogeologic layers were

defined for each stratigraphic layer based on zones of similar hydrologic properties. The

hydrologic properties (permeability, porosity) were deduced from geophysical well logs and

side-wall cores. The lithology, deduced from wireline logs and core data, was also used to

subdivide each stratigraphic layer of the model. Based on these data, the Mount Simon

Sandstone was subdivided into 17 layers, and the Elmhurst Sandstone (member of the Eau Claire

Formation) was subdivided into 7 layers ( Figure 4 ). The Lombard and Proviso members of the

Eau Claire Formation were subdivided respectively into 14 and 5 layers. The Ironton Sandstone

was divided into four layers, the Davis Dolomite into three layers, and the Franconia Formation

int o one layer. Some layers (“split” label in Figure 4, step 2) have similar properties but have

been subdivided to maintain a reasonable thickness of layers within the injection zone as

represented in the computational model. The thickness of the layers varies from 4 to 172 ft, with

an average of 26 ft.

Based on knowledge of the regional and local geology, the Mount Simon Sandstone and the

Elmhurst form the main part of the injection zone. However, the computational model results

indicate that the Model Layer “Lombard 5” is the top unit containing a fraction of injected CO 2 

### during the 100-year simulation. Based on these results, the lower part of the Lombard (layers

Lombard 1 to 5 of the Computational Model), is considered to be part of the injection zoneArea of Review and Corrective Action Plan for FutureGen Alliance Page B8 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### (Figure 4). The top of the injection zone is set at 3,785 ft bgs (-3,153 ft elevation MSL) in the

stra tigraphic well. The upper part of the Lombard and the Proviso members form the primary

confining zone.

Figure 4, step 3, shows the numerical model grid for the entire 100- by 100-mi domain and also

for the 3- by 3-mi area with higher grid resolution and uniform grid spacing of 200 ft by 200 ft.

The model grid contains 125 nodes in the x-direction, 125 nodes in the y-direction, and 51 nodes

in the z-direction for a total number of nodes equal to 796,875. The expanded geologic model

was queried at the node locations of the numerical model to determine the elevation of each

surface for the stratigraphic units at the numerical model grid cell centers (nodes) and cell edges.

Then each of those layers was subdivided into the model layers by scaling the thickness to

preserve the total thickness of each stratigraphic unit. Once the vertical layering was defined,

material properties were mapped to each node in the model.Area of Review and Corrective Action Plan for FutureGen Alliance Page B9 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) Figure 4. Implementation of the Numerical Model: From the Geological Conceptual Model to the Numerical

ModelArea of Review and Corrective Action Plan for FutureGen Alliance Page B 10 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### Processes Modeled

Physical processes modeled in the reservoir simulations included isothermal multi-fluid flow and

transport for a number of components (e.g., water, salt, and CO 2 

### ) and phases (e.g., aqueous and

gas). Isothermal conditions were modeled because it was assumed that the temperature of the

inj ected CO 2 

### will be similar to the formation temperature. Formation salinity is considered

because salt precipitation can occur near the injection well in higher permeability layers as the

rock dries out during CO 2 

### injection. Porosity reduction due to salt precipitation is considered in

the model. However, permeability reduction was not modeled because the salinity is relatively

low in the injection formations at this site, resulting in low levels of salt precipitation.

Injected CO 2 

### partitions in the injection zone between the free (or mobile) gas, entrapped gas, and

a queous phases. Sequestering CO 2 

### in deep saline formations occurs through four mechanisms: 1)

struc tural trapping; 2) aqueous dissolution; 3) hydraulic trapping; and 4) mineralization.

S tructural trapping is the long-term retention of the buoyant gas phase in the pore space of the

permeable formation rock held beneath one or more impermeable or near impermeable confining

z ones. Aqueous dissolution occurs when CO 2 

### dissolves in the brine resulting in an aqueousphase density greater than the ambient conditions. Hydraulic trapping is the pinch-off trapping of

the gas phase in pores as the brine re-enters pore spaces previously occupied by the gas phase.

Generally, hydraulic trapping only occurs upon the cessation of CO 2 

### injection. Mineralization is

the chemical reaction that transforms formation minerals to carbonate minerals. In the Mount

Simon Sandstone, the most likely precipitation reaction is the formation of iron carbonate

pre cipitates. A likely reaction between CO 2 

### and shale is the dewatering of clays. Laboratory

investigations are currently quantifying the importance of these reactions at the Morgan County

CO 2 

### storage site. Based on its experiments, the FutureGen Alliance expects to see a small mass

of precipitates (KCl, NaCl) forming near the injection well from the scCO 2 

### displacement of

water, and does not expect to see the formation of any significant carbonate precipitates in the

year (or years) time scale. Iron does precipitate, but concentrations are too low (<0.6 mmol/L)

relative to carbonate mass to be a precipitate issue. Simulations by others (White et al. 2005) of

scCO 2 

### injection in a similar sandstone (also containing iron oxides) shows that over significantly

longer time scales (1000+ years), alumino silicate dissolution and alumino silicate precipitation

incorporating significant carbonate (dawsonite) is predicted, as well as precipitation of some

calcite. That predicted mineral trapping did permanently sequester 21 percent of the carbonate

mass, thus decreasing scCO 2 

### transport risk

. Therefore, the simulations described here did not

include mineralization reactions. However, the STOMP-CO2 simulator does account for

precipitation of salt during CO 2 

### injection. The CO 2 

### stream provided by the plant to the storage

site is no less than 97 percent dry basis CO 2 

### . Because the amount of impurities is small, for the

purposes of modeling the CO 2 

### injection and redistribution for this project, it was assumed that

the injectate was pure CO 2



### .Area of Review and Corrective Action Plan for FutureGen Alliance Page B 11 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### Rock Properties

Intrinsic Permeability

S ite Characterization Data

Permeability in the sandstones, as measured in rotary side-wall cores and plugs from whole core,

appears to be dominantly related to grain size and abundance of clay. In Figure 2 , ELAN

(Elemental Log Analysis)-calculated permeability (red curve) is in the third panel, along with

two different lab measurements of permeability for each rotary side-wall core. Horizontal

permeability (K

h 

### ) data in the stratigraphic well outnumber vertical permeability (K

v 

### ) data,

because K

v 

### could not be determined from rotary side-wall cores. However, K

v 

### /K h 

### ratios were

successfully determined for 20 vertical/horizontal siliciclastic core-plug pairs cut from intervals

of whole core. Within the Mount Simon Sandstone, the horizontal permeabilities of the lower

Mount Simon alluvial fan lithofacies range from 0.005 to 0.006 mD and average ratios of

vertical to horizontal permeabilities range from 0.635 to 0.722 (at the 4,304 to 4,3 74 ft bgs depth

or the elevation of -3, 685 to -3, 755 ft, Figure 2 ). Horizontal core-plug permeabilities range from

0.032 to 2.34 mD at the 3,838 to 3,9 04 ft bgs depth (elevation of -3, 219 to -3

, 285 ft); K

v 

### /K h 

### ratios for these same samples range from 0.081 to 0.833.

The computed lithology track for the primary confining zone indicates the upward decrease in

quartz silt and increase in carbonate in the Proviso member, along with a decrease in

permeability. The permeabilities of the rotary side-wall cores in the Proviso range from 0.000005

mD to 1 mD. Permeabilities in the Lombard member range from 0.001 mD to 28 mD, reflecting

the greater abundance of siltstone in this interval, particularly in the lowermost part of the

membe r. Whole core plugs and associated vertical permeabilities are available only from the

lowe rmost part of the Lombard. Thin (few inches/centimeters), high-permeability sandstone

streaks resemble the underlying Elmhurst; low-permeability siltstone and mudstone lithofacies

have vertical permeabilities of 0.0004 to 0.465 mD, and K

v 

### /K h 

### ratios of <0.0001 to 0.17.

The ELAN geophysical logs indicated permeabilities are generally less than the wireline tool

limit of 0.01 mD throughout the secondary confining zone. Two rotary side-wall cores were

taken from the Franconia, and three side-wall cores were cut in the Davis member. Laboratorymeasured rotary side-wall core (horizontal) permeabilities are very low (0.000005 to 0.001 mD).

The permeabilities of the two Franconia samples were measured with a special pulse decay

permeameter; the sample from 3,140 ft bgs (-2521 ft elevation) has a permeability less than the

lower instrument limit of 0.000005 mD. Vertical core plugs are required for directly determining

vertical permeability and there are no data from the stratigraphic well for vertical permeability or

for determining vertical permeability anisotropy in the secondary confining zone. However,

K

v 

### /K h 

### ratios of 0.007 have been reported elsewhere for Paleozoic carbonate mudstones (Saller et

al. 2004).Area of Review and Corrective Action Plan for FutureGen Alliance Page B 12 of 46

Permit Number: IL

- 137

- 6A -0004 (Well #4) 

### Model Parameters

Intrinsic permeability data sources for the FutureGen 2.0 stratigraphic well include computed

geophysical wireline surveys (CMR and ELAN logs), and where available, laboratory

measurements of rotary side-wall cores (SWC), core plugs from the whole core intervals,

h ydrologic tests (including wireline [MDT]), and packer tests. For the Mount Simon and

Elmhurst Sandstones model layers (3,838 to 4,418 ft bgs depth or elevation of -3219 to -3799 ft

a t the stratigraphic well), wireline ELAN permeability model permKCal produced by

S chlumberger (red curve on Figure 2 ) was used. This model, calibrated by rotary side-wall and

core-plug permeabilities, provides a continuous permeability estimate over the entire injection

z one. Th is calibrated permeability response was then slightly adjusted, or scaled, to match the

composite results obtained from the hydrologic packer tests over uncased intervals. For injection

zone model layers within the cased well portion of the model, no hydrologic test data are

available, and core-calibrated ELAN log response was used directly in assigning average model

layer permeabilities.

The hydraulic packer tests were conducted in two zones of the Mount Simon portion of the

injection zone. The Upper Zone (3,934 ft to 4,180 ft bgs depth or -3, 315 to -3

, 561 ft elevation )

equates to layers 6 through 17 of the model, while the Lower Zone (4,186 ft to 4,498 ft bgs depth

or -3

, 567 to -3, 879 ft elevation) equates to layers 1 through 5. The most recent ELAN-based

permeability- th ickness product values are 9,524 mD-ft for the 246- ft -thick section of the upper

Mount Simon corresponding to the Upper Zone and 3,139 mD-ft for the 312- ft

- thick section of

the lower Mount Simon corresponding to the Lower Zone. The total permeability-thickness

produ ct for the open borehole Mount Simon is 12,663 mD-ft, based on the ELAN logs. Results

of the field hydraulic tests suggest that the upper Mount Simon permeability-thickness product is

9,040 mD- ft and the lower Mount Simon interval permeability-thickness product is 775 mD-ft.

B y simple direct comparison, the packer test for the upper Mount Simon is nearly equivalent

(~ 95 percent) to the ELAN-predicted value, while the lower Mount Simon represents only ~25

pe rcent of the ELAN-predicted value.

Because no hydrologic test has been conducted in the Elmhurst Sandstone interval of the

injection zone, a conservative scaling factor of 1 has been assigned to this interval, based on

ELAN PermKCal data (The permeabilities used for this formation were the ELAN PermKCal

values without applying a scaling factor). The sources of data for confining zones (Franconia to

Uppe r part of the Lombard Formations) and the Upper part of the Injection zone (Lower part of

the Lombard) are similar to those for the injection zone, with the exception that no hydrologic or

MDT te st data are available. ELAN log-derived permeabilities are unreliable below about 0.01

mD ( personal communication from Bob Butsch, Schlumberger, 2012). Because the average logde rived permeabilities (permKCal wireline from ELAN log) for most of the confining zone

layers are at or below 0.01 mD, an alternate approach was applied. For each model layer the core

data were reviewed, and a simple average of the available horizontal Klinkenburg permeabilities

wa s then calculated for each layer. Core samples that were noted as having potential cracks

a nd/or were very small were eliminated if the results appeared to be unreasonable based on the

sa mpled lithology. If no core samples were available and the arithmetic mean of the PermKCal

wa s below 0.01 mD, a default value of 0.01 mD was applied (Lombard9 is the only layer with a

0.01 -mD default value). Because the sandstone intervals of the Ironton-Galesville Sandstone

have higher permeabilities that are similar in magnitude to the modeled injection zone layers, the

I ronton-Galesville Sandstone model layer permeabilities were derived from the arithmetic meanArea of Review and Corrective Action Plan for FutureGen Alliance Page B 13 of 46

Permit Number: IL

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- 6A -0004 (Well #4) 

### of the PermKCal permeability curve. Because no hydraulic test has been conducted in the

primary confining zone and the Upper part of the injection zone (Elmhurst Sandstone layers and

lowe r part of the Lombard – Lombard 1 to Lombard 5), the scaling factor was assigned to be 100

pe rcent in this interval and the overburden formations. Figure 5 shows the depth profile of the

horizontal permeability assigned to each layer of the model and actual values assigned are listed

in Table 1

. Figure 6 shows the distribution of horizontal and vertical permeability as it was

assigned to the numerical model layers.

B ecause the anisotropy of the model layers is not likely to be represented by the sparse data from

the stratigraphic well, the lithology-specific permeability anisotropy averages from literature

studies representing larger sample sizes were used for the model layers ( Ta ble 2 and Table 3 ).

Figure 5. Vertical Distribution of the Horizontal Permeability in the Model Layers at the Stratigraphic Well

LocationArea of Review and Corrective Action Plan for FutureGen Alliance Page B 14 of 46

Permit Number: IL

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### (a) (b)

Figure 6. Permeability Assigned to Numerical Model 1) Horizontal Permeability; b) Vertical PermeabilityArea of Review and Corrective Action Plan for FutureGen Alliance Page B 15 of 46

Permit Number: IL- 137

- 6A -0004 (well #4) Table 1. Summary of the Hydrologic Properties Assigned to Each Model Layer. Depths and Elevations Correspond to the Location of the Stratigraphic

Well

Simulation

-

CM22

Model Layer Top

Depth

(ft bgs ) Top

Elevation

(ft MSL) Bottom

Elevation

(ft MSL) Thickness

(ft) Porosity Horizontal

Permeability

(mD) Vertical

Permeability

(mD) Grain

Density

(g/cm3) Compresibility

(1/Pa)SecondaryConf. Zone Franconia 30 72 .00

- 2453

- 2625 172 0.0358 5.50E

- 06 3.85E

- 08 2.82 7.42E

- 10

Davis

- Ironton3 32 44 .00

- 2625

- 2649 24 0.0367 6.26E

- 02 6.26E

- 03 2.73 3.71E

- 10

Davis

- Ironton2 32 68 .00

- 2649

- 2673 24 0.0367 6.26E

- 02 6.26E

- 03 2.73 3.71E

- 10

Davis

- Ironton1 3 292 .00

- 2673

- 2697 24 0.0218 1.25E+01 1.25E+00 2.73 3.71E

- 10

Ironton

Galesville4 33 16 .00

- 2697

- 2725 28 0.0981 2.63E+01 1.05E+01 2.66 3.71E

- 10

Ironton

Galesville3 33 44 .00

- 2725

- 2752 27 0.0981 2.63E+01 1.05E+01 2.66 3.71E

- 10

Ironton

Galesville2 33 71 .00

- 2752

- 2779 27 0.0981 2.63E+01 1.05E+01 2.66 3.71E

- 10

Ironton

Galesville1 3 398 .00

- 2779

- 2806 27 0.0981 2.63E+01 1.05E+01 2.66 3.71E

- 10Primary Confining Zone Proviso5 34 25 .00

- 2806

- 2877 71 0.0972 1.12E

- 03 1.12E

- 04 2.72 7.42E

- 10

Proviso4 3 496 .00

- 2877

- 2891 14 0.0786 5.50E

- 03 5.50E

- 04 2.72 7.42E

- 10

Proviso3 35 10 .00

- 2891

- 2916 25 0.0745 8.18E

- 02 5.73E

- 04 2.77 7.42E

- 10

Proviso2 35 34 .50

- 2916

- 2926 10 0.0431 1.08E

- 01 7.56E

- 04 2.77 7.42E

- 10

Proviso1 35 44 .50

- 2926

- 2963 38 0.0361 6.46E

- 04 4.52E

- 06 2.77 7.42E

- 10

Lombard14 35 82 .00

- 2963

- 3003 40 0.1754 5.26E

- 04 5.26E

- 05 2.68 7.42E

- 10

Lombard13 36 22 .00

- 3003

- 3038 35 0.0638 1.53E

- 01 1.53E

- 02 2.68 7.42E

- 10

Lombard12 36 57 .00

- 3038

- 3073 35 0.0638 1.53E

- 01 1.53E

- 02 2.68 7.42E

- 10

Lombard11 3 692 .00

- 3073

- 3084 11 0.0878 9.91E+00 9.91E

- 01 2.68 7.42E

- 10

Lombard10 37 03 .00

- 3084

- 3094 10 0.0851 1.66E+01 1.66E+00 2.68 7.42E

- 10

Lombard9 37 13 .00

- 3094

- 3121 27 0.0721 1.00E

- 02 1.00E

- 03 2.68 7.42E

- 10

Lombard8 37 39 .50

- 3121

- 3138 17 0.0663 2.13E

- 01 2.13E

- 02 2.68 7.42E

- 10

Lombard7 37 56 .50

- 3138

- 3145 8 0.0859 7.05E+01 7.05E+00 2.68 7.42E

- 10

Lombard6 37 64 .00

- 3145

- 3153 8 0.0459 1.31E+01 1.31E+00 2.68 7.42E

- 10Area of Review and Corrective Action Plan for FutureGen Alliance Page B 16 of 46

Permit Number: IL- 137

- 6A -0004 (well #4) Table 1

. (contd)

Model Layer Top

Depth

(ft bgs ) Top

Elevation

(ft MSL) Bottom

Elevation

(ft MSL) Thickness

(ft) Porosity Horizontal

Permeability

(mD) Vertical

Permeability

(mD) Grain

Density

(g/cm3) Compresibility

(1/Pa)Injection Zone Lombard5 37 71 .50

- 3153

- 3161 9 0.0760 4.24E+02 4.24E+01 2.68 7.42E

- 10

Lombard4 37 80 .00

- 3161

- 3181 20 0.0604 3.56E

- 02 3.56E

- 03 2.68 7.42E

- 10

Lombard3 38 00 .00

- 3181

- 3189 8 0.0799 5.19E+00 5.19E

- 01 2.68 7.42E

- 10

Lombard2 38 07 .50

- 3189

- 3194 5 0.0631 5.71E

- 01 5.71E

- 02 2.68 7.42E

- 10

Lombard1 38 12 .50

- 3194

- 3219 26 0.0900 1.77E+00 1.77E

- 01 2.68 7.42E

- 10

Elmhurst7 38 38 .00

- 3219

- 3229 10 0.1595 2.04E+01 8.17E+00 2.64 3.71E

- 10

Elmhurst6 38 48 .00

- 3229

- 3239 10 0.1981 1.84E+02 7.38E+01 2.64 3.71E

- 10

Elmhurst5 38 58 .00

- 3239

- 3249 10 0.0822 1.87E+00 1.87E

- 01 2.64 3.71E

- 10

Elmhurst4 38 68 .00

- 3249

- 3263 14 0.1105 4.97E+00 1.99E+00 2.64 3.71E

- 10

Elmhurst3 38 82 .00

- 3263

- 3267 4 0.0768 7.52E

- 01 7.52E

- 02 2.64 3.71E

- 10

Elmhurst2 3 886 .00

- 3267

- 3277 10 0.1291 1.63E+01 6.53E+00 2.64 3.71E

- 10

Elmhurst1 3 896 .00

- 3277

- 3289 12 0.0830 2.90E

- 01 2.90E

- 02 2.64 3.71E

- 10

MtSimon17 39 08 .00

- 3289

- 3315 26 0.1297 7.26E+00 2.91E+00 2.65 3.71E

- 10

MtSimon16 39 34 .00

- 3315

- 3322 7 0.1084 3.78E

- 01 3.78E

- 02 2.65 3.71E

- 10

MtSimon15 39 41 .00

- 3322

- 3335 13 0.1276 5.08E+00 2.03E+00 2.65 3.71E

- 10

MtSimon14 39 54 .00

- 3335

- 3355 20 0.1082 1.33E+00 5.33E

- 01 2.65 3.71E

- 10

MtSimon13 39 74 .00

- 3355

- 3383 28 0.1278 5.33E+00 2.13E+00 2.65 3.71E

- 10

MtSimon12 40 02 .00

- 3383

- 3404 21 0.1473 1.59E+01 6.34E+00 2.65 3.71E

- 10

MtSimon11 40 23 .00

- 3404

- 3427 23 0.2042 3.10E+02 1.55E+02 2.65 3.71E

- 10

MtSimon10 40 46 .00

- 3427

- 3449 22 0.1434 1.39E+01 4.18E+00 2.65 3.71E

- 10

MtSimon9 40 68 .00

- 3449

- 3471 22 0.1434 1.39E+01 4.18E+00 2.65 3.71E

- 10

MtSimon8 4 090 .00

- 3471

- 3495 24 0.1503 2.10E+01 6.29E+00 2.65 3.71E

- 10

MtSimon7 41 14 .00

- 3495

- 3518 23 0.1311 6.51E+00 1.95E+00 2.65 3.71E

- 10

MtSimon6 41 37 .00

- 3518

- 3549 31 0.1052 2.26E+00 6.78E

- 01 2.65 3.71E

- 10

MtSimon5 41 68 .00

- 3549

- 3588 39 0.1105 4.83E

- 02 4.83E

- 03 2.65 3.71E

- 10

MtSimon4 42 07 .00

- 3588

- 3627 39 0.1105 4.83E

- 02 4.83E

- 03 2.65 3.71E

- 10

MtSimon3 42 46 .00

- 3627

- 3657 30 0.1727 1.25E+01 1.25E+00 2.65 3.71E

- 10

MtSimon2 42 76 .00

- 3657

- 3717 60 0.1157 2.87E+00 2.87E

- 01 2.65 3.71E

- 10

MtSimon1 43 36 .00

- 3717

- 3799 82 0.1157 2.87E+00 2.87E

- 01 2.65 3.71E

- 10Area of Review and Corrective Action Plan for FutureGen Alliance Page B 17 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4)

Table 2

. Lithology-Specific Permeability Anisotropy Averages from Literature

Facies or Lithology Kv/Kh Reference

1. Heterolithic, laminated shale/mudstone/siltstone/sandstone 0.1 Meyer and Krause (2006)

2. Herringbone cross

- stratified sandstone. Strat dips to 18 degrees 0.4 Meyer and Krause (2006 )

3. Paleo weathered sandstone (coastal flat) 0.4 Meyer and Krause (2006 )

4. Accretionary channel bar sandstones with minor shale laminations 0.5 Ringrose et al. (2005);

Meyer and Krause (2006)

6. Alluvial fan, alluvial braided stream plain to shallow marine

sandstones, low clay content 0 .3 Kerr et al. (1999)

7. Alluvial fan, alluvial plain sandstones, sheet floods, paleosols,

higher clay content 0.1 Hornung and Aigner (1999)

8. Dolomite mudstone 0.007 Saller et al. (2004)Area of Review and Corrective Action Plan for FutureGen Alliance Page B 18 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4)

Table 3

. Summary of the K

v /K h Ratios Applied to Model Layers

Model Layer Kv/Kh Applied to

Model Layers (a) * Kv/Kh

Determined

from Core

Pairs (b) Successfully

Analyzed Core

Pairs

Franconia carbonate 0.007 ND ND

Davis

- Ironton 0.1 ND ND

Ironton

- Galesville 0.4 ND ND

Proviso (Layers 4 and 5) 0.1 ND ND

Proviso ([carbonate] Layers 1

to 3) 0.007 ND ND

Lombard Total Interval 0.1 0.029 12

Lombard (Layer 7) 0.1 .098 2

Lombard (Layer 6) 0.1 0.003 2

Lombard (Layer 5) 0.1 ND ND

Lombard (Layer 4) 0.1 0.016 2

Lombard (Layer 3) 0.1 0.064 2

Lombard (Layer 2) 0.1 0.009 1

Lombard (Layer 1) 0.1 0.104 3

Elmhurst Total Interval 0.4 0.06 4

Elmhurst (Layer 7) 0.4 ND ND

Elmhurst (Layer 6) 0.4 0.023 1

Elmhurst (Layer 5) 0. 1 ND ND

Elmhurst (Layer 4) 0.4 0.902 1

Elmhurst (Layer 3) 0. 1 ND ND

Elmhurst (Layer 2) 0.4 0.022 1

Elmhurst (Layer 1) 0. 1 0.037 1

Mt. Simon (Layer 17) 0.4 0.233 2

Mt. Simon (Layer 16) 0.1 ND ND

Mt. Simon (layer 13) 0.4 0.643 2

Mt. Simon (Layers 12, 14, and

15) 0.4 ND ND

Mt. Simon (Layer 11,

Injection) zone) 0.5 ND ND

Mt. Simon (Layers 6, 7, 8, 9,

10) 0.3 ND ND

Mt. Simon (Layers 1, 2, 3, 4,

5) 0.1 ND ND

(a) Value from literature, referenced in the Supporting Documentation of the UIC permit application

(b) Geometric mean of successful core pairs.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 19 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### Porosity

Total (or absolute) porosity is the ratio of void space to the volume of whole rock. Effective

porosity is the ratio of interconnected void space to the volume of the whole rock. As a first step

in assig ning porosity values for the FutureGen 2.0 numerical model layers, Schlumberger ELAN

porosit y log results were compared with laboratory measurements of porosity as determined

fr om SWC and core plugs for specific sampling depth within the Mount Simon. The

Schlumberger ELAN porosity logs examined include PIGN (Gamma-Neutron Porosity), PHI T

(Total Porosity), and PIGE (Effective Porosity). The PIGN and PIGE wireline log surveys use

diff erent algorithms to identify clay- or mineral-bound fluid/porosity in calculating an effective

porosit y value. SWC porosity measurements are listed as “total porosity,” but their measurement

c an be considered to be determinations of “effective porosity,” because the measurement

technique (weight measurements of heated/oven-dried core samples) primarily measures the

a mount of “free” or connected pore liquid contained within the SWC sample as produced by the

heating process. It should be noted that the SWC porosity measurements were determined under

a mbient pressure conditions.

In Figure 2 , neutron - and density-crossplot porosity is shown in the fourth panel, along with labmeasured porosity for core plugs and rotary SWC

. An available porosity measurement data set

for a conventional Mount Simon Sandstone co re -plug sample taken near the top of the formation

(de pth of 3,9 12 ft bgs or elevation of -3,293 ft) indicates only minor changes in porosity for

measurements taken over a wide range in pressure (i.e., ambient to 1,730 psi). This suggests that

a mbient SWC porosity measurements of the Mount Simon may be representative of in situ

for mation pore pressure conditions. The ELAN porosity log results generally underestimate the

S WC porosity measured values. As a result of the poor visual correlation of the PIGE survey

re sults with SWC measurements, this ELAN log was omitted from subsequent correlation

evaluations. To aid in the correlations, the gamma ray survey log (GR) was used as a screening

tool for development of linear-regression correlation relationships between ELAN log responses

and SWC porosity measurements. This helps account for the shale or clay content that can cause

the inclusion of “bound water” porosity. To assign model layer porosities, the regression model

relationships used to calibrate the EL AN measurement results ( Figure 7 ) were applied to the

ELAN survey results over the formational depths represented by the Mount Simon (3,904 to

4,4 16 ft bgs depth or -3

, 285 to -3, 797 ft elevation) and overlying Eau Clai re -Elmhurst member

(3,838 to 3,9 04 ft bgs depth or -3, 219 to -3

, 285 ft elevation) based on the gamma response

criteria. The ELAN survey results are reported at 0.5-ft depth intervals. For stratigraphic units

above the Elmhurst and/or depth intervals exhibiting gamma readings >64 API units, the unc alibrated, average ELAN log result for that depth interval was used. An average porosity was

then a ssigned to the model layer based on the average of the calibrated ELAN values within the

model la yer depth range. Figure 8 shows the depth profile of the assigned model layer porosities

based on the average of the calibrated ELAN values. The actual values assigned for each layer

a re listed in Table 1

.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 20 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 7. Comparison of SWC Porosity Measurements and Regression-Calibrated ELAN Log Porosities: ≤64

Gamma API UnitsArea of Review and Corrective Action Plan for FutureGen Alliance Page B 21 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 8. Vertical Distribution of Porosity in the Model Layers at the Stratigraphic Well Location



### Rock (Bulk) Density and Grain Density

Grain density data were calculated from laboratory measurements of SWCs. The data were then

a veraged (arithmetic mean) for each main stratigraphic layer in the model. Only the Proviso

member (Eau Claire Formation) has been divided in two sublayers to be consistent with the

li thology changes. Figure 9 shows the calculated grain density with depth. The actual values

assigned to each layer of the model are listed in Ta ble 1 . Grain density is the input parameter

specified in the simulation input file, and STOMP-CO2 calculates the bulk density from the

g rain density and porosity for each model layer.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 22 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 9. Vertical Distribution of the Grain Density in the Model Layer at the Stratigraphic Well Location



### Formation Compressibility

L imited information about formation (pore) compressibility estimates is available. The best

e stimate for the Mount Simon Sandstone ( Ta ble 4 ) is that back-calculated by Birkholzer et al.

(2008) from a pumping test at the Hudson Field natural-gas storage site, found 80 mi (129 km)

northe ast of the Morgan County CO 2 

### storage site. The back-calculated pore-compressibility

estimate for the Mount Simon Sandstone of 3.71E−10 Pa

− 1 

### was used as a spatially constant value

for their basin-scale simulations. In other simulations, Birkholzer et al. (2008) assumed a porec ompressibility value of 4.5E−10 Pa −1 

### for aquifers and 9.0E−10 Pa −1 

### for aquitards. Zhou et al.

(2010) in a later publication used a pore-compressibility value of 7.42E−10 Pa

− 1 

### for both the Eau

Claire Formation and Precambrian granite, which were also used for these initial simulationsArea of Review and Corrective Action Plan for FutureGen Alliance Page B 23 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### ( Table 4 ). Because the site -specific data are limited to a single reservoir sample, only these two

published values have been used for the model. The first value (3.71E-10 Pa

− 1 

### ) has been used for

sand s that are compressible because of the presence of porosity. The second value (7.42E-10

Pa −1 

### ) is assigned for all other rocks that are less compressible (dolomite, limestone, shale, and

rh yolite). Table 1 lists the hydrologic parameters assigned to each model layer.

Table 4. Formation Compressibility Values Selected from Available Sources

Hydrogeologic Unit Formation (Pore) Compressibility, Pa

- 1

Franconia 7.42E

- 10 Pa

1

Davis

- Ironton 3.71E

- 10 Pa

- 1

Ironton

- Galesville 3.71E

- 10 Pa

- 1

Eau Claire Formation (Lombard and Proviso) 7.42E

- 10 Pa

- 1

Eau Claire Formation (Elmhurst) 3.71E

- 10 Pa

- 1

Mount Simon Sandstone 3.71E

- 10 Pa

- 1



### Constitutive Relationships

Capillary Pressure and Saturation Functions

Capillary pressure is the pressure difference across the interface of two immiscible fluids (e.g.,

CO 2 

### and water). The entry capillary pressure is the minimum pressure required for an immiscible

non -wetting fluid (i.e., CO 2 

### ) to ove rcome the capillary force and enter pore space containing the

we tting fluid (i.e., saline formation water). Capillary pressure data determined from site-specific

c ores were not available at the time the model was constructed. However, tabulated capillary

pre ssure data were available for several Mount Simon gas storage fields in the Illinois Basin. The

da ta for the Manlove Hazen well (FutureGen Alliance 2006) were the most complete. Therefore,

t hese aqueous saturation and capillary pressure values were plotted and a user-defined curve

fitting was performed to generate Brooks-Corey parameters for four different permeabilities

( Figure 10 ). These parameters were then assigned to layers based on a permeability range as

shown in Table 5

.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 24 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 10

. Aqueous Saturation Versus Capillary Pressure Based on Mercury Injection Data from the Hazen

No. 5 Well at the Manlove Gas Field in Champagne County, Illinois

Table 5. Permeability Ranges Used to Assign Brooks-Corey Parameters to Model Layers

Permeability (mD) Psi Lambda (  ) Residual Aqueous

Saturation

< 41.16 4.116 0.83113 0.059705

41.16 to 231 1.573 0.62146 0.081005

231 to 912.47 1.450 1.1663 0.070762

> 912.47 1.008 1.3532 0.044002



### The Brooks-Corey (1964) saturation function is given as

where S

ew 

### is effective aqueous saturation, P

c 

### is capillary pressure, P

e 

### is gas entry pressure, and λ

is the pore-size distribution parameter. Combined with the Burdine (1953) relative permeability

model, the relative permeability for the aqueous phase, k

rw 

### , and that for the non-aqueous phase,

k

rn 

### , are

Values for the residual aqueous saturation ( S

rw 

### ) and the two other parameters used in the BrooksCorey capillary pressure-saturation function (i.e., the non-wetting fluid entry pressure and a

pore-size distribution parameter) were all obtained by fitting mercury (Hg) intrusion-capillary

pre ssure data from the Manlove gas storage site in Champaign County. The fitting was applied

after scaling the capillary pressures to account for the differences in interfacial tensions and

contact angles for the brine- CO 2 

### fluid pair, relative to vapor-liquid Hg used in the measurements.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 25 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### This approach has the major advantage that the three fitted parameters are consistent as they are

obtained from the same original data set. The use of consistent parameter values is not the norm

for brine- CO 2 

### flow simulations in the Mount Simon Sandstone.

The S

rw 

### values used in the modeling ( Table 2 ) are indeed lower than the values found in the

literature. The FutureGen Alliance was aware of these differences but opted to use a consistent

data set for all retention parameter values instead of selecting parameter values from different

data sources. An additional reason for using this approach is the considerable uncertainty in S

rw 

### values for Mt. Simon rock in the literature. In general, using a lower S

rw 

### value for the injection

zone will possibly result in a somewhat smaller predicted CO 2 

### plume size and a smaller spatial

extent of the pressure front compared to using a higher value of S

rw 

### . Variation of S

rw 

### in the

confining zone (cap rock) likely has relatively little impact on CO 2 

### transport and pressure

development owing to the typically much lower permeability of this zone relative to the

underlying formation.

Gas Entry Pressure

No site-specific data were available for gas entry pressure; therefore, this parameter was

estimated using the Davies (1991) developed empirical relationships between air entry pressure,

Pe , and intrinsic permeability, k , for different types of rock:

Pe = a k

b



### where Pe takes the units of MPa and k the units of m 2



### , a and b are constants and are summarized

below for shale, sandstone, and carbonate (Davies 1991; Ta ble 3 ). The dolomite found at the

Morgan County site is categorized as a carbonate. The Pe for the a ir -water system is further

converted to that for the CO 2 

### -brine system by multiplying the interfacial tension ratio of a CO 2



### - brine system β cb 

### to an air-water system β

aw 

### . An approximate value of 30 mN/m was used for β cb 

### and 72 mN/m for β

aw 

### .

Table 6. Values for Constants a and b for Different Lithologies

Shale Sandstone Carbonate

a 7.60E

- 07 2.50E

- 07 8.70E

- 07

b

- 0.344

- 0.369

- 0.336



### CO 2 

### Entrapment

The entrapment option available in STOMP-CO2 was used to allow for entrapment of CO 2 

### when

the aqueous phase is on an imbibition path (i.e., increasing aqueous saturation). Gas saturation

can be free or trapped:

s g 

### = 1

- s l 

### = s gf 

### + s gt



### where the trapped gas is assumed to be in the form of aqueous occluded ganglia and immobile.

The potential effective trapped gas saturation varies between zero and the effective maximum

trapped gas saturation as a function of the historical minimum value of the apparent aqueous

saturation. No site-specific data were available for the maximum trapped gas saturation, so this

value was taken from the literature. Suekane et al. (2009) used micro-focused x-ray CT to imageArea of Review and Corrective Action Plan for FutureGen Alliance Page B 26 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### a chip of Berea Sandstone to measure the distribution of trapped gas bubbles after injection of

sc CO 2 

### and then water, under reservoir conditions. Based on results presented in the literature, a

va lue of 0.2 was used in the model, representing the low end of measured values for the

maximum trapped gas saturation in core samples.

Formation Properties

Flui d Pressure

An initial fluid sampling event from the Mount Simon formation was conducted on December

14, 2011, in the stratigraphic well during the course of conducting open-hole logging. Sampling

was attempted at 22 discrete depths using the MDT tool in the Quicksilver Probe configuration

and from one location using the conventional (dual-packer) configuration. Pressure data were

obtained at 7 of the 23 attempted sampling points, including one duplicated measurement at a

depth of 4,034 ft bgs or elevation of -3415 ft (Table 7).

F igure 11 shows the available regional potentiometric surfaces for the Mount Simon Sandstone.

The figure contains pre-development hydraulic head measurements (e.g., before widespread

pumping from the Mount Simon Sandstone, particularly in Northern Illinois) and simulation

results for predicting the post-development (i.e., 1980) potentiometric surface. As shown in

Figure 11 , data are sparse around the area of the FutureGen 2.0 Site, and it is situated in an area

whe re the regional gradients are very low and the flow directions are not constrained (pre- or

post -development). For these reasons, a regional horizontal flux for the Moun t Simon Sandstone

was not specified in the computational model.

Vertical flow potential at the FutureGen 2.0 Site was evaluated based on an analysis of discrete

pre ssure/depth measurements obtained within the pilot characterization borehole over the depth

interval of 1,134 to 4,249 ft bgs depth (-515 to -3 ,630 ft elevation). The results indicate that there

is a posit ive head difference in the Mount Simon that ranges from 47.8 to 61.6 ft above the

calculated St. Peter observed static hydraulic head condition (i.e., 491.1 ft above MSL). This

positive head difference suggests a natural vertical flow potential from the Mount Simon to the

ove rlying St. Peter if hydraulic communication is afforded (e.g., an open communicative well). It

shoul d also be noted, however, that the higher head within the unconsolidated Quaternary aquifer

(~ 611 ft above MSL), indicates a downward vertical flow potential from this surficial aquifer to

both the underlying St. Peter and Mount Simon bedrock aquifers. The dispari ty in the calculated

hydraulic head measurements (together with the significant differences in formation fluid

sa linity) also suggests that groundwater within the St. Peter and Mount Simon bedrock aquifers

is ph ysically isolated from one another. This is an indication that there are no significant conduits

(open well bores or fracturing) between these two formations and that the Eau Claire forms an

effective confining layer.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 27 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 11

. Approximate Pre-Development Potentiometric Surface (a) for the Mount Simon Aquifer (from

Young 1992, modified from Mandel and Kontis 1992) and (b) Simulated 1980 Freshwater Head in

the Mount Simon Aquifer showing Impact of Withdrawals in Northern portion of Illinois

(Mandel and Kontis 1992)Area of Review and Corrective Action Plan for FutureGen Alliance Page B 28 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) Table 7. Pressure Data Obtained from the Mount Simon Formation Using the MDT Tool Where the

Red Line Delimits the Samples Within the Injection Zone

Sample Number Sample Depth (ft bgs ) Absolute Pressure (psia)

7 4

, 1 16 1

, 828

8 4

, 1 17 1

, 827.7

9 4

, 096 .5 1

, 818.3

11 4

, 0 34 1

, 790.2

17 4

, 0 34 (duplicated) 1

, 790.3

21 4

, 2 34 .5 1

, 889.2

22 4

, 2 32 1

, 908.8

23 4

, 2 49 1

, 896.5 (a)

(a) Sample affected by drilling fluids (not representative)



### Temperature

The best fluid temperature depth profile was performed on February 9, 2012, as part of the static

borehole flow meter/fluid temperature survey that was conducted prior to the constant-rate

injection flow meter surveys. Two confirmatory discrete probe depth measurements that were

taken prior to the active injection phase (using colder brine) corroborate the survey results. The

discrete static measurement for the depth of 3,698 ft bgs (elevation of -3, 079 ft) was 95.9°F. The

second discrete static probe temperature measurement is from the MDT probe for the successful

sampling interval of 4,0 34 ft bgs depth (elevation of -3

, 415 ft). A linear-regression

temperature/depth relationship was developed for use by modeling. The regression data set

analyzed was for temperature data over the depth interval of 1,286 to 4,533 ft bgs (elevation of -

667 to -3, 914 ft). Based on this regression, a projected temperature for the reference datum at the

top of the Mount Simon (3,904 ft bgs depth or -3

, 285 ft elevation) of 96.60°F is indicated. A

slope ( gradient) of 6.72 10 -3 

### °F/ft and intercept of 70.27°F is also calculated from the regression

analysis.

Brine Density

Although this parameter is determined by the simulator using pressure, temperature, and salinity,

based on the upper and lower Mount Simon injection zone tests, the calculated in situ injection

z one fluid density is 1.0315 g/cm 3



### .

Salinity and Water Quality

Dur ing the process of drilling the well, fluid samples were obtained from discrete-depth intervals

in the St. Peter Formation and the Mount Simon Formation using wireline-deployed sampling

tools (MDTs) on December 14, 2011. After the well had been drilled, additional fluid samples

were obtained from the open borehole section of the Mount Simon Formation by extensive

pumping using a submersible pump. The assigned salinity value for the Mount Simon (upper

zone) 47,500 ppm is as indicated by both the MDT sample (depth 4,034 ft bgs or elevation of -Area of Review and Corrective Action Plan for FutureGen Alliance Page B 29 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### 3

, 415 ft) and the multiple samples collected during extensive composite pumping of the open

borehole section.

A total of 20 groundwater samples were collected between October 25 and November 10, 2011,

including duplicate samples and blanks (Dey et al. in press as of 2013). General water-quality

pa rameters were measured along with organic and major inorganic constituents. Values of pH

ranged from 7.08 to 7.66. Values for specific conductance ranged from 545 to 1,164 μS/cm, with

an average of 773 μS/cm. Values of Eh ranged from 105 to 532 mV with an average of 411 mV.

Va lues of dissolved oxygen (DO) ranged from below detection limit to 3.3 mg/L O 2 

### . Most

dissolved inorganic constituent concentrations are within primary and secondary drinking water

standards. However, the constituent concentration in water is elevated with respect to iron (Fe),

manganese (Mn), nitrate (NO3), and the total dissolved salt (TDS). In some cases these

constituents exceed the U.S. Environmental Protection Agency (EPA) secondary standards.

Frac ture Pressure in the Injection Zone

At the time the computational model was developed, n o site-specific hydraulic fracturing tests

had been conducted in the stratigraphic well and no site-specific fracture pressure values were

available for the confining zone and the injection zone. Other approaches (listed below) have

thus b een chosen to determine an appropriate value for the fracture pressure.

 Triaxial tests were conducted on eight samples from the stratigraphic well. Samples 3 to

7 are located within the injection zone. Fracture gradients were estimated to range from

0.647 to 0.682 psi/ft, which cannot directly be compared to the fracture pressure gradient

required for the permit. Triaxial tests alone cannot provide accurate measurement of

fracture pressure.

 Existing regional values. Similar carbon storage projects elsewhere in Illinois (in Macon

and Christian counties) provide data for fracture pressure in a comparable geological

context. In Macon County (CCS#1 well at Decatur), about 65 mi east of the FutureGen

2.0 Site, a fracture pressure gradient of 0.715 psi/ft was obtained at the base of the Mount

Simon Sandstone Formation using a step-rate injection test (EPA 2011a). In Christian

C ounty, a “conservative” pressure gradient of 0.65 psi/ft was used for the same injection

zone (EP A 2011b ). No site-specific data were available.

 Last, the regulation relating to the “Determination of Maximum Injection Pressure for

Class I Wells” in EPA Region 5 is based on the fracture closure pressure, which has been

chosen to be 0.57 psi/ft for the Mount Simon Sandstone (EPA 1994).

B ased on these considerations, a fracture pressure gradient of 0.65 psi/ft was chosen. The EPA

Geologic Sequestration Rule requires that “Except during stimulation, the owner or operator

must ensure that injection pressure does not exceed 90 percent of the fracture pressure of the

inj ection zone(s) so as to ensure that the injection does not initiate new fractures or propagate

e xisting fractures in the injection zone(s)...” Therefore, a value of 0.585 psi/ft (90 percent of

0. 65 psi/ft) was used in the model to calculate the maximum injection pressure permitted.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 30 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### In November and December 2013, hydraulic tests were conducted in the Mount Simon

Sandstone and in the Precambrian basement. The first results of these tests verify that the

fracture gradient used in the model for the injection zone remains conservative and appropriate.

Site Evaluation of Mineral Resources

Other subsurface geochemical considerations include the potential for mineral or hydrocarbon

resources beneath the proposed CO 2 

### storage site. While no significant mineral deposits are

known to exist within Morgan County, natural gas has been recovered in the region, including at

the Prentice and Jacksonville fields located within several miles of the stratigraphic well. ISGS

oil and gas website data indicate that the Prentice Field contained more than 25 wells drilled

during the 1950s; re -exploration occurred in the 1980s. Both oil and gas have been produced

from small stratigraphic traps in the shallow Pennsylvanian targets, at depths of 250 to 350 ft (75

to 105 m ) bgs. It is important to note that gas produced from these wells may contain around 16

pe rcent CO 2 

### (Meents 1981). More than 75 wells have been drilled in the Jacksonville Field. Gas

was discovered in the Jacksonville Field as early as 1890 (Bell 1927), but most oil and gas

produ ction from the Prentice and Jacksonville fields occurred between the late 1920s and late

1980s. The most productive formations in the Illinois Basin (lower Pennsylvanian and

Mis sissippian siliciclastics and Silurian reefs) are not present in Morgan County. Only two

bore holes in the vicinity of the Prentice Field and five boreholes near the Jacksonville Field

pe netrate through the New Albany Shale into Devonian and Silurian limestone. Cumulative

production from the Prentice and Jacksonville fields is not available, and both fields are largely

a bandoned. The Waverly Storage Field natural-gas storage site in the southeast corner of Morgan

County originally produced oil from Silurian carbonates. This field no longer actively produces

oil, but since 1954 it has been successfully used for natural-gas storage in the St. Peter and the

Ga lesville/Ironton Sandstone formations (Buschbach and Bond 1974).

The nearest active coal mine is approximately 10 mi (16 km) away in Menard County and does

not penetrate more than 200 ft (61 m) bgs (ISGS 2012). A review of the known coal geology

within a 5

- mi (8 -km) radius of the proposed drilling site indicates that the Pennsylvanian coals,

the Herrin, Springfield, and Colchester coals, are very thin or are absent from the project area

(ISGS 2010, 2011; Hatch and Affolter 2008). During continuous coring of a shallow

g roundwater monitoring well located immediately adjacent to the stratigraphic well, only a

sing le thin (5-ft [1.5-m]) coal seam was encountered at about 200 ft (61 m) depth.

Initial Conditions

The injection zone is assumed to be under hydrostatic conditions with no regional or local flow

conditions. Therefore the hydrologic flow system is assumed to be at steady state until the start

of injection. To achieve this with the STOMP-CO2 simulator one can either run an initial

simulation (executed for a very long time period until steady-state conditions are achieved) to

generate the initial distribution of pressure, temperature, and salinity conditions in the model

from an initial guess, or one can specify the initial conditions at a reference depth using the

hydrostatic option in the STOMP-CO2 input file, allowing the simulator to calculate and assign

the init ial conditions to all the model nodes. Site-specific data were available for pressure,

temperature, and salinity, and therefore the hydrostatic option was used to assign initial

conditions. A temperature gradient was specified based on the geothermal gradient, but the initialArea of Review and Corrective Action Plan for FutureGen Alliance Page B 31 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### salinity was considered to be constant for the entire domain. A summary of the initial conditions

is presented in Table 8

.

T able 8. Summary of Initial Conditions

Parameter Reference Depth (ft bgs ) Elevation (ft) Value

Reservoir Pressure 4,0 34

- 3,415 1,790.2 psi

Aqueous Saturation 1.0

Reservoir Temperature 3,9 04

- 3,285 96.6 °F

Temperature Gradient 0.00672 °F/ft

Salinity 47,500 ppm



### Boundary Conditions

Boundary conditions were established with the assumption that the injection zone and confining

zone are continuous throughout the region and that the underlying Precambrian unit is

im permeable. Therefore, the bottom boundary was set as a no-flow boundary for aqueous fluids

and for the CO 2 

### -rich phase. The lateral and top boundary conditions were set to hydrostatic

pressure using the initial condition with the assumption that each of these boundaries is distant

enough from the injection zone to have minimal to no effect on the CO 2 

### plume migration and

pressure distribution.

Wells within the Survey Area

A detailed survey was completed over a 25 mi 2 

### (65 km 2 

### ) area, termed the “Survey Area.” This

area is centered on the proposed injection location (labeled as “Injection Site”) and encompasses

the predicted maximum extent of the CO 2 

### plume (Figure 12). Wells, surface bodies of water and

other pertinent surface features, administrative boundaries, and roads within the Survey Area are

shown in Figure 12. There are no subsurface cleanup sites, mines, quarries, or Tribal lands

within this area. The Survey Area is near the center of the AoR (Figure 15).

A total of 129 wells are located within the Survey Area. However, no well but the FutureGen

Alliance’s stratigraphic well penetrates the injection zone (Mount Simon Sandstone and the

lower Eau Claire [Elmhurst Sandstone Member and lower portion of the Lombard Member]), the

confining zone (Upper portion of Lombard Member and Proviso Member of the Eau Claire

Formation), or the secondary confining zone (Franconia Dolomite).

Shallow domestic water wells with depths of less than 50 ft (15 m) are the most common well

type within the Survey Area. Five slightly deeper water wells were identified that range in

depths from 110 ft (33 m) to 405 ft (123 m). Other wells include stratigraphic test holes, coal

test hol es, and oil and gas wells.

Twenty four of the 129 wells in the Survey Area are identified with only a general location

(center of a section) in the ISWS database. These wells are included in Table 9 but are not shown

on the map.

A general survey of the AoR outside the Survey Area was conducted by reference of publicly

available information. Maps of existing water wells, oil and gas wells, miscellaneous wells, coal

mines, surface water, and geologic structures were submitted to complete the permit

re quirements.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 32 of 46

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### There are 4,386 water wells and 740 oil and gas wells within the AoR, but only two of

these penetrate the confining zone. These two wells identified in the AoR are

a pproximately 16 miles from the injection site, but they are adequately plugged.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 33 of 46

Permit Number: IL- 137

- 6A -0004 (well #4) Table 9

. List of Wells Located Within the Survey Area

Map ID API Number ISWS ID Latitude

NAD1983 Longitude

NAD1983 Public Land Survey

System Total

Depth ft Elev

ft Completion

Date Owner Well

Num Well Type Status Confining Zone

Penetration

Well

0 121372213200 39.806064

- 90.052919 T16n,R9w,Sec 25 4812 633 TBD FutureGen Industrial Alliance, Inc. 1 Monitoring Active Yes

1 121372118200 116519 39.778074

- 90.078443 T15N,R9W,Sec 2 25 19780712 A.A. Negus Estate 1 Water Private Water Well No

4 1 21370018700 115778 39.811025

- 90.065241 T16N,R9W,Sec 25 115 Beilschmidt, William H. Water No

8 121370028500 115740 39.800661

- 90.078386 T16N,R9W,Sec 26 127 1950 Martin, L. E. 1 Water No

9 115741 39.800661

- 90.078386 T16N,R9W,Sec 26 127 Martin, L. E. Water No

10 121372128600 115779 39.801129

- 90.07342 T16N,R9W,Sec 26 25 19781213 Martin, Marvin & Jean 1 Water Private Water Well No

14 115763 39.792894

- 90.078875 T16N,R9W,Sec 35 28 E Clemons Water No

15 115764 39.792894

- 90.078875 T16N,R9W,Sec 35 25 B Sister Water No

16 115765 39.792837

- 90.060294 T16N,R9W,Sec 36 35 J M Dunlap Water No

17 121370051100 39.792893

- 90.078984 T16N,R9W,Sec 35 1056 643 O'Rear, Judge 1 Oil & Gas / Water No

18 121370009900 39.808545

- 90.06614 T16N,R9W,Sec 25 1530 630 19391001 Beilschmidt, Wm. 1 Oil & Gas Dry and Abandoned, No Shows No

19 121370023500 39.779153

- 90.077325 T15N,R9W,Sec 2 338 644 19231101 Conklin 1 Oil & Gas Dry and Abandoned, No Shows No

20 121370023600 39.781298

- 90.075082 T15N,R9W,Sec 2 348 646 19231101 Conklin 2 Oil & Gas Dry and Abandoned, No Shows No

21 121370023700 39.778057

- 90.080754 T15N,R9W,Sec 3 342 645 19231001 Harris, A. J. 1 Oil & Gas Gas Producer No

22 121370023900 39.7779

- 90.080756 T15N,R9W,Sec 3 334 644 19231107 Harris, A. J. 3 Oil & Gas Gas Producer No

25 121370036300 39.805251

- 90.075597 T16N,R9W,Sec 26 1205 19670330 Martin 1 Oil & Gas Dry and Abandoned, No Shows No

26 121370036301 39.805251

- 90.075597 T16N,R9W,Sec 26 1400 19731029 Martin 1 Oil & Gas Junked and Abandoned, Plugged No

27 121372088500 39.800861

- 90.073017 T16N,R9W,Sec 26 302 630 Coal Test No

115735 39.807386

- 90.060378 T16N,R9W,Sec 25 27 Beilschmidt, William H. Water No

115736 39.807386

- 90.060378 T16N,R9W,Sec 25 30 W R Fowler Water No

115737 39.807386

- 90.060378 T16N,R9W,Sec 25 28 Mason Water No

115739 39.807478

- 90.079049 T16N,R9W,Sec 26 25 C H Matin Water No

115738 39.807478

- 90.079049 T16N,R9W,Sec 26 22 T Gondall Water No

1 15650 39.807193

- 90.041413 T16N,R8W,Sec 30 19 1930 R Allison Water No

115651 39.792765

- 90.041512 T16N,R8W,Sec 31 28 W J Huston Water No

1 15652 39.792765

- 90.041512 T16N,R8W,Sec 31 28 E Robinson Water No

116450 39.777005

- 90.052023 T15N,R9W,Sec 1 25 A Harris Water No

1 16453 39.776968

- 90.070521 T15N,R9W,Sec 2 32 A Harris Water No

116451 39.776968

- 90.070521 T15N,R9W,Sec 2 22 W R Conklin Water No

1 16452 39.776968

- 90.070521 T15N,R9W,Sec 2 30 B Negus Water No

116454 39.77688

- 90.088996 T15N,R9W,Sec 3 28 C Negus Water No

116455 39.77688

- 90.088996 T15N,R9W,Sec 3 30 L B Trotter Water No

115727 39.821881

- 90.078925 T16N,R9W,Sec 23 30 D Flinn Water No

115728 39.821881

- 90.078925 T16N,R9W,Sec 23 30 Hazel Dell School Water No

11 5729 39.821881

- 90.078925 T16N,R9W,Sec 23 35 K Haneline Water No

115733 39.821811

- 90.060168 T16N,R9W,Sec 24 30 J L Icenagle Water No

11 5734 39.821811

- 90.060168 T16N,R9W,Sec 24 30 G Lewis Water No

1157 75 39.821811

- 90.060168 T16N,R9W,Sec 24 200 1944 E C Lewis Water No

115742 39.807531

- 90.097566 T16N,R9W,Sec 27 23 J Stewart Water No

1157 43 39.807531

- 90.097566 T16N,R9W,Sec 27 23 l J Stewart Water No

115761 39.792917

- 90.097513 T16N,R9W,Sec 34 28 T Harrison Water No

11 5762 39.792917

- 90.097513 T16N,R9W,Sec 34 30 J Mahon Water NoArea of Review and Corrective Action Plan for FutureGen Alliance Page B 34 of 46

Permit Number: IL- 137

- 6A -0004 (well #4) Map ID API Number ISWS ID Latitude

(NAD 83) Longitude

(NAD 83) Public Land Survey

System

(PLSS) Total

Depth

(ft) Elevation

(ft) Completion

Date Owner Well # Well Type Status Confining

Zone

Penetration

Well

2 121372155200 237387 39.815638

- 90.084967 T16N,R9W,Sec 23 41 19920313 Nickel, Gerald 1 Water Private Water Well No

3 121372182100 300966 39.815638

- 90.084967 T16N,R9W,Sec 23 46 19971104 Nickel, Gerald & Diane 1 Water Private Water Well No

13 121372173400 297871 39.811987

- 90.07805 T16N,R9W,Sec 26 37 19960213 Keltner, Dale Water Private Water Well No

23 121370024000 39.780186

- 90.094859 T15N,R9W,Sec 3 402 642 19230101 Trotter, L.B. 1 Oil & Gas Dry and Abandoned, No Shows No

24 121372097800 39.776078

- 90.080727 T15N,R9W,Sec 3 327 632 0 Harris Unknown / other Unknown, Plugged No

28 115642 39.82166

- 90.041238 T16N,R8W,Sec 19 25 1870 W W Robertson Water No

38 116456 39.776761

- 90.107843 T15N,R9W,Sec 4 30 Rayburn Water No

39 116457 39.776761

- 90.107843 T15N,R9W,Sec 4 32 Greene Water No

40 115725 39.821959

- 90.097446 T16N,R9W,Sec 22 18 K Brown Water No

41 115726 39.821959

- 90.097446 T16N,R9W,Sec 22 30 E C Trotter Water No

52 115640 39.836203

- 90.022343 T16N,R8W,Sec 17 25 J H Hubbs Water No

53 115641 39.83617

- 90.041154 T16N,R8W,Sec 18 32 1850 H Robinson Water No

54 115643 39.821671

- 90.022214 T16N,R8W,Sec 20 26 1900 S Weinfeldt Water No

55 115644 39.821671

- 90.022214 T16N,R8W,Sec 20 30 1904 Robinson Water No

56 115649 39.807149

- 90.022402 T16N,R8W,Sec 29 26 M Walbaum Water No

57 1 15653 39.793

- 90.022 T16N,R8W,Sec 32 18 Beggs Water No

58 121 372070800 116522 39.77156

- 90.0878 T15N,R9W,Sec 3 50 19770320 Linebarger, David Water No

59 121 372118300 116520 39.769673

- 90.080523 T15N,R9W,Sec 3 42 Harris, Frank R. Water Private Water Well No

60 121372070700 116521 39.769673

- 90.080523 T15N,R9W,Sec 3 40 harris F R Water No

61 1 16458 39.777

- 90.126 T15N,R9W,Sec 5 30 Gary S. B. Water No

62 1 16464 39.761

- 90.126 T15N,R9W,Sec 8 30 Cleray W Water No

63 116465 39.761

- 90.126 T15N,R9W,Sec 8 40 Coons A Water No

64 116466 39.761

- 90.107 T15N,R9W,Sec 9 30 Wallbaum W M Water No

65 1 16467 39.761

- 90.107 T15N,R9W,Sec 9 35 Trotter l B Water No

66 2 27314 39.761

- 90.107 T15N,R9W,Sec 9 40 Carl Shinnall #1 Water No

67 1 16468 39.761

- 90.089 T15N,R9W,Sec 10 30 Orear R Water No

68 121372070900 116525 39.765755

- 90.080645 T15N,R9W,Sec 10 40 Linebarger D Water No

69 1 16469 39.761

- 90.07 T15N,R9W,Sec 11 30 Collins W Water No

70 1 16470 39.761

- 90.07 T15N,R9W,Sec 11 32 Lockhart G Water No

71 1 16393 39.776799

- 90.032936 T15N,R8W,Sec 6 25 1923 Water No

72 116394 39.776799

- 90.032936 T15N,R8W,Sec 6 28 C Smith Water No

73 121 372116800 116436 39.784526

- 90.041604 T15N,R8W,Sec 6 54 19770226 Becker, Carl J. 1 Water Livestock Watering Well No

74 121 372116900 116435 39.784526

- 90.041604 T15N,R8W,Sec 6 43 19781010 Becker, Carl J. 1 Water Private Water Well No

75 121 372117000 116434 39.782453

- 90.041567 T15N,R8W,Sec 6 27 19761213 Smith, Lloyd E. 1 Water Livestock Watering Well No

76 121372161900 39.766277

- 90.041266 T15N,R8W,Sec 7 26 Walpole, Ron Water No

77 1 16395 39.763

- 90.033 T15N,R8W,Sec 7 30 Water No

78 1 15696 39.836221

- 90.059875 T16N,R9W,Sec 13 25 V R Mc Clure Water NoArea of Review and Corrective Action Plan for FutureGen Alliance Page B 35 of 46

Permit Number: IL- 137

- 6A -0004 (well #4) Map ID API Number ISWS ID Latitude

(NAD 83) Longitude

(NAD 83) Public Land Survey

System (PLSS) Total

Depth

(ft) Elevation

(ft) Completion

Date Owner Well # Well Type Status Confining

Zone

Penetration

Well

79 115697 39.836221

- 90.059875 T16N,R9W,Sec 13 27 U B Fox Water No

80 115698 39.836221

- 90.059875 T16N,R9W,Sec 13 27 G W Lewis Water No

81 115699 39.836362

- 90.078662 T16N,R9W,Sec 14 30 J Parrat Water No

82 115700 39.836362

- 90.078662 T16N,R9W,Sec 14 28 C W Lewis Water No

83 115701 39.836362

- 90.078662 T16N,R9W,Sec 14 28 J W Parrat Water No

84 115702 39.836362

- 90.078662 T16N,R9W,Sec 14 32 J Hodgeson Water No

85 121372203900 356742 39.830101

- 90.102984 T16N,R9W,Sec 15 47 20030910 Lomar Hager Construction Water Private Water Well No

86 115703 39.836486

- 90.097369 T16N,R9W,Sec 15 24 G Noulty Water No

87 115704 39.836486

- 90.097369 T16N,R9W,Sec 15 30 L Lamkaular Water No

88 115705 39.836486

- 90.097369 T16N,R9W,Sec 15 35 E E Hart Water No

89 115706 39.8365

- 90.116151 T16N,R9W,Sec 16 23 S Jumper Water No

90 115707 39.8365

- 90.116151 T16N,R9W,Sec 16 25 H Wester Water No

91 115722 39.821967

- 90.116263 T16N,R9W,Sec 21 30 T J Ward Water No

92 115724 39.821967

- 90.116263 T16N,R9W,Sec 21 30 C Trotter Water No

93 216249 39.821967

- 90.116263 T16N,R9W,Sec 21 28 1934 Wm Noulty Water No

94 121370028400 39.822767

- 90.073164 T16N,R9W,Sec 23 405 19540301 Keltner 1 Water No

95 121372155100 237377 39.820978

- 90.077895 T16N,R9W,Sec 23 42 19920414 Allen, John D. 1 Water Private Water Well No

96 121372207600 365042 39.822764

- 90.075515 T16N,R9W,Sec 23 46 20040715 Burton, Larry Water Private Water Well No

97 121372128400 115776 39.826288

- 90.058992 T16N,R9W,Sec 24 40 19760220 Robinson, Leroy A. 1 Water Private Water Well No

98 121372128500 115777 39.828869

- 90.059535 T16N,R9W,Sec 24 37 19781214 Romine, Buddy 1 Water Private Water Well No

99 121372211600 420169 39.813876

- 90.103667 T16N,R9W,Sec 27 35 20060809 Donnan, Jeff Water Private Water Well No

100 115744 39.807541

- 90.116512 T16N,R9W,Sec 28 110 Noah B Fox Water No

101 115745 39.807541

- 90.116512 T16N,R9W,Sec 28 28 Noah B Fox Water No

102 115746 39.807541

- 90.116512 T16N,R9W,Sec 28 30 C Holdbrook Water No

103 115723 39.807541

- 90.116512 T16N,R9W,Sec 28 28 W Noulty Water No

104 121372203000 348692 39.806645

- 90.122622 T16N,R9W,Sec 28 42 Kendra Swain Water No

105 115759 39.792956

- 90.116724 T16N,R9W,Sec 33 30 H Swain Water No

106 115760 39.792956

- 90.116724 T16N,R9W,Sec 33 28 L L Hart Water No

107 121372155000 39.822856

- 90.119949 T16N,R9W,Sec 21 Spradlin, Jack Water No

108 121370011400 39.833775

- 90.10777 T16N,R9W,Sec 16 385 616 19551101 Wolfe, Eliz 1 Oil & Gas Dry and Abandoned, No Shows, Plugged No

109 121370011500 39.80091

- 90.040421 T16N,R8W,Sec 30 420 635 19560101 Beilschmidt 1 Oil & Gas Dry and Abandoned, No Shows, Plugged No

110 121370011600 39.815108

- 90.028322 T16N,R8W,Sec 20 365 610 19551201 Robinson, Howard 1 Oil & Gas Dry and Abandoned, No Shows, Plugged No

111 121370018900 39.825408

- 90.062536 T16N,R9W,Sec 24 200 19440101 Lewis, E. C. Oil & Gas Dry Hole No

112 121370024100 39.769077

- 90.111454 T15N,R9W,Sec 4 580 Rayborn 1 Oil & Gas Gas Producer No

113 121370044200 39.770193

- 90.110273 T15N,R9W,Sec 4 350 Rayburn 1 Oil & Gas Gas Producer No

114 121372086900 39.769679

- 90.098565 T15N,R9W,Sec 4 301 Coal Test No

115 121370024200 39.778927

- 90.119618 T15N,R9W,Sec 5 423 Green, Laura & Effie 1 Oil & Gas Gas Producer No

116 121370024600 39.764523

- 90.098492 T15N,R9W,Sec 9 293 Baxter 2 Oil & Gas Dry and Abandoned, Gas Shows No

117 121372094800 39.767065

- 90.11144 T15N,R9W,Sec 9 325 Beilschmidt 1 Oil&Gas Temporarily Abandoned No

118 121372105200 39.763524

- 90.104346 T15N,R9W,Sec 9 Leinberger 2 Oil&Gas Permit to Drill Issued No

119 121370007900 39.766464

- 90.091366 T15N,R9W,Sec 10 295 Dunlap 8 Oil & Gas Gas Producer No

120 121372084800 39.766422

- 90.065678 T15N,R9W,Sec 11 243 Coal Test No

121 121370030900 39.806625

- 90.105838 T16N,R9W,Sec 27 324 610 19591001 Fox, Lyman 1 Oil & Gas Dry and Abandoned, No Shows, Plugged No

122 121370033200 39.788212

- 90.03349 T16N,R8W,Sec 31 323 641 19271001 Corrington 1 Oil & Gas Dry and Abandoned, No Shows NoArea of Review and Corrective Action Plan for FutureGen Alliance Page B 36 of 46

Permit Number: IL- 137

- 6A -0004 (well #4) Map ID API Number ISWS ID Latitude

(NAD 83) Longitude

(NAD 83) Public Land Survey

System (PLSS) Total

Depth

(ft) Elevation

(ft) Completion

Date Owner Well # Well Type Status Confining

Zone

Penetration

Well

123 121370062300 39.828772

- 90.06935 T16N,R9W,Sec 24 814 624 19700701 #MA

- 3 Stratigraphic or

Structure Test Structure Test, Plugged No

124 121372068000 39.792709

- 90.039363 T16N,R8W,Sec 31 142 641 19700518 Flynn, Robert Coal Test No

125 121372088400 39.829096

- 90.098826 T16N,R9W,Sec 22 318 621 0 Coal Test No

126 121372088600 39.801122

- 90.108499 T16N,R9W,Sec 28 301 621 0 Coal Test No

127 121372067800 39.814431

- 90.023514 T16N,R8W,Sec 20 130 610 19700507 Newberry, Lucille Coal Test No

128 121372086000 39.83138

- 90.055009 T16N,R9W,Sec 13 301 619 0 Coal Test NoArea of Review and Corrective Action Plan for FutureGen Alliance Page B 37 of 46 Page B 37 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 12

. Wells Located Within the Survey AreaArea of Review and Corrective Action Plan for FutureGen Alliance Page B 38 of 46 Page B 38 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### Proposed Operating Data (Operational Information)

Figure 13 and Figure 14 show the well design for the representative case for the refined area of

the model domain in plan view, in 3D view, and in cross section view, respectively. Injection

into four lateral wells with a well-bore radius of 4.5 in. was modeled with the lateral leg of each

well located within the best layer of the injection zone to maximize injectivity. Only the noncased open sections of the wells are specified in the model input file because only those sections

are delivering CO 2 

### to the formation. The well design modeled in this case is the open borehole

design 6 

### , therefore part of the curved portion of each well is open and thereby represented in the

model in additi on to the lateral legs. The orientation and lateral length of the wells, as well as

CO 2 

### mass injection rates, were chosen so that the resulting modeled CO 2 

### plume would avoid

sensitive areas. The coordinates of the screened portion of the injection wells are shown in Table

10 . The injection rate was assigned to each well according to the values in Table 11 for a total

injection rate of 1.1 MMT/yr for 20 years. A maximum injection pressure of 2,252.3 psi (2,237.6

psig) was assigned at the top of the open interval (depth of 3,850 ft bgs or an elevation of -3, 2 20

ft ), based on 90 percent of the fracture gradient described in Section 3 .5 (0.65 psi/ft).

3D View Plan View

Figure 13

. Operational Well Design for Representative Case Scenario as Implemented in the

Numerical Model (with lateral legs of the injection wells shown in red and the cross section

lines shown in yellow)

6 Despite the models use of an open-hole design, the actual proposed construction is a cased hole with perforations.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 39 of 46 Page B 39 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 14

. Cross Sections of CO 2 Injection We lls

Table 10

. Coordinates (NAD1983 UTM Zone 16N) of Open Portions of the Injection Wells

Coordinate 1(ft) Coordinate 2(ft) Coordinate 3(ft) Coordinate 4(ft)

x y z x y z x y z x y z

Well1 777079 14468885

- 3220 777263 14468901

- 3330 777592 14468929

- 3387 779086 14469060

- 3394

Well2 776898 14468571

- 3220 776976 14468404

- 3330 777116 14468105

- 3388 778172 14465839

- 3396

Well3 776617 14468578

- 3220 776530 14468416

- 3330 776375 14468124

- 3382 775202 14465917

- 3377

Well4 776451 14468829

- 3220 776267 14468813

- 3330 775938 14468785

- 3377 774444 14468654

- 3368Area of Review and Corrective Action Plan for FutureGen Alliance Page B 40 of 46 Page B 40 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4)

Table 11

. Mass Rate of CO 2 Injection for Each of the Four Lateral Injection Wells

Well Length of Lateral leg (ft) Mass Rate of CO 2 Injection (MMT/yr)

Injection well #1 1,500 0.2063

Injection well #2 2,500 0.3541

Injection well #3 2,500 0.3541

Injection well #4 1,500 0.1856



### Computational Modeling Results

At the end of the simulation period, 100 years, most of the CO 2 

### mass occurs in the CO 2 

### -rich (or

separate) phase, with 20 percent occurring in the dissolved phase. Note that residual trapping

begins to take place once injection ceases, resulting in about 15 percent of the total CO 2 

### mass being immobile at the end of 100 years. The CO 2 

### plume forms a cloverleaf pattern as a result of

the four lateral injection-well design. The plume grows both laterally and vertically as injection

c ontinues. Most of the CO 2 

### resides in the Mount Simon Sandstone. A small amount of CO 2 

### enters into the Elmhurst and the lower part of the Lombard. When injection ceases at 20 years,

the lateral growth becomes negligible but the plume continues to move slowly, primarily

upward. Once CO 2 

### reaches the low-permeability zone in the upper Mount Simon it begins to

move laterally. There is no CO 2 

### entering the confining zone. The maximum extent of the CO 2 

### plume, at 22 years, is in the center of Figure 15.

Pre ssure Front Delineation

As shown in Figure 16 , the calculated hydraulic heads from the pressures and fluid densities

measured in the Mount Simon Sandstone during drilling of the stratigraphic well range from 47.8

to 61.6 ft hi gher than the calculated hydraulic head in the lowermost USDW (St. Peter

Sandstone). Based on these measurements, it was expected that the equation 1 suggested in the

EPA AoR Guidance document (EPA 2013) for determination of the pressure front AoR would

not be applicable for the FutureGen 2.0 Site since it would be in the “over-pressured” category.

Thus alternative methods for assessment of the impacts of the pressure front would be needed for

the “ over-pressured” case at the FutureGen 2.0 Site.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 41 of 46 Page B 41 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 15

. FutureGen Area of Review inclusive of the 

### CO 2 plume and the area of elevated pressure

delineated as the 10 psi contour at 60 yearsArea of Review and Corrective Action Plan for FutureGen Alliance Page B 42 of 46 Page B 42 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 16 . Observed Hydraulic Head Comparison between the Unconsolidated Quaternary Aquifer, St. Peter

Sandstone, and Mount Simon Sandstone within the FutureGen Stratigraphic Well



### Alternative approach es considered for delineation of an AoR inclusive of an area of elevated

pressure

The FutureGen Alliance considered the applicability of and evaluated the project using an

analytical solution (Cihan et al., 2011; 2013 ) and a range of other approaches (Table 13). The

objec tive of the se analyses w as to assess, calculate, and account for critical pressure, which is the

pressure great enough to mobilize fluids up an open conduit (i.e., an artificial penetration, fault,

or f racture) from the injection zone into the overlying USDW. Methods evaluated are presented

in Table 13.

Table 13. Methods Evaluated for Pressure Front Delineation

Approach Results

AoR Guidance Equation 1 Not applicable

Nicot (200 8 ) 13.76 psi

Birkholzer (2011) 9.65 psi

Cihan (2011) : Assuming thief zones Plume

- sized AoR

Cihan (2011) Conservative: Assuming no thief zones Large AoRArea of Review and Corrective Action Plan for FutureGen Alliance Page B 43 of 46 Page B 43 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### Pressure delineated AoR

Each of the pressure front analysis methodologies evaluated by the FutureGen Alliance (Table

13) are mathematical approximations applicable under prescribed conditions and subjected to

simplifying assumptions. The simplified critical pressure calculations based on the open conduit

c oncept are not applicable under site conditions because the ambient conditions in the lowermost

USDW at the FutureGen site are under-pressured relative to the reservoir. Although the open

conduit approaches are not strictly applicable under FutureGen site conditions, results from these

conservative and protective approaches were used by EPA to delineate the pressure front AoR as

the maximum extent of the 10 psi contour of pressure differential during the life of the project,

wh ich occurs 60 years after injection commences and is shown in Figure 15.

Corrective Action Plan and Schedule

No wells have been identified within the AoR that require corrective action.

Area of Review Re evaluation Plan and Schedule

Re evaluation Cycle

The FutureGen Alliance will reevaluate the AoR on an annual basis for the first 5 years

following the initiation of injection operations (Figure 17). After the fifth year of injection, the

AoR wil l be updated at a minimum of every 5 years as required by 40 CFR 146.84(b)(2)(i). An

annual reevaluation in the first 5 years is intended to account for any operational variation during

the startup period.

Some conditions will warrant reevaluation prior to the next scheduled cycle. To meet the intent

of the regulations and protect USDWs, the following six conditions will warrant reevaluation of

the A oR:

1. Exceeding Fracture Pressure Conditions: Pressure in any of the injection or monitoring

wells exceeding 90 percent of the geologic formation fracture pressure at the point of

mea surement. This would be a violation of the permit conditions. The Testing and

Monitoring Plan provides discussion of pressure monitoring.

Action: The computational model will be calibrated to match measured pressures. Model

output s that calculate the change in AoR will be provided to EPA.

2. Exceeding Established Baseline Hydrochemical/Physical Parameter Patterns: A

statistically significant difference between observed and baseline hydrochemical/physical

parameter patterns (e.g., fluid conductivity, pressure, temperature) within the Ironton

F ormation immediately above the confining zone (ACZ1 and ACZ2 wells). The Student’s ttest st atistical procedure will be used to compare background (baseline) with observedArea of Review and Corrective Action Plan for FutureGen Alliance Page B 44 of 46 Page B 44 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### results. The Testing and Monitoring Plan provides extended information regarding how

pre ssure, temperature, and fluid conductivity will be monitored within the Ironton Formation.

Action: In the event that hydrochemical/physical parameter trends suggest that leakage may

be occurring, either the computational model or other models will be used to understand the

obs ervational parameter behavior.

3. Compromise in Injection Well Mechanical Integrity: A significant change in pressure

within the protective annular pressurization system surrounding each injection well that

indicates a loss of mechanical integrity at an injection well.

Action: Injection wells suspected of mechanical integrity issues will be shut down and the

c ause of the pressure deviation determined. Mechanical integrity testing will be conducted

a nd the computational model will be updated with mechanical integrity results to determine

the se verity and extent of the loss of containment. The Testing and Monitoring Plan provides

extended information about the mechanical integrity tests that will be conducted in the

inj ection wells.

4. Departure in Anticipated Surface Deformation Conditions: Surface deformation

measurements that indicate an asymmetric or otherwise heterogeneous evolution of the

injection zone pressure front, resulting in larger than predicted surface deformation outside

the CO 2 

### plume. Areal surface deformation will be monitored using several technologies

including differential synthetic aperture radar interferometry (DInSAR), which is a radarba sed method that can measure very small changes in ground-surface elevation linked to

pressure variations at depth. The area surveyed will extend beyond the predicted maximum

extent of the CO 2 

### plume. If a measurable rise in the ground surface occurs outside the

predicted extent, the AoR will be re-evaluated. The Testing and Monitoring Plan provides

e xtended information about surface deformation monitoring.

Ac tion: The computational model will be calibrated to match observed pressures if they vary

fr om the predicted deformation/pressure calculations.

5. Seismic Monitoring Identification of Subsurface Structural Features: Seismic

monitoring data indicate the possible presence of a fault or fracture near the CO 2 

### injection

zone in the sedimentary cover or in the basement (concentration of microearthquakes of

M< <1 in elongated clusters). The Testing and Monitoring Plan provides extended

infor mation about the microseismic monitoring network.

Ac tion: The cause of the indicated microseismicity patterns will be evaluated. In

c onjunction, various operational parameters will be tested using the computational model to

determine if the microseismic activity can be controlled to acceptable levels

6. Seismic Monitoring Identification of Unexpected Plume Pattern: Seismic monitoring

data indicate a CO 2 

### plume migration outside the predicted extent. The observation of

microearthquakes (M<<1) may also help define the actual shape of the maximum pressure

field associated with the plume extensions.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 45 of 46 Page B 45 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) 

### Action: The computational model will be calibrated to match the location of observed

microseismicity patterns indicative of plume extensions

.



### 7. Other triggers for reevaluation may include: facility operating changes; new injection

activities or other deep wells added in the AoR; new owner/operators; new site

characterization data; a seismic event or other emergency; and unexpected changes in rate,

direction, and extent of plume/pressure front movement.

Reevaluation Strategy

If any of these conditions occurs, the FutureGen Alliance will reevaluate the AoR to comply with

requirements at 40 CFR 146.84 as described below. Ongoing direct and indirect monitoring data,

which provide relevant information for understanding the development and evolution of the CO 2 

### plume, will be used to support reevaluation of the AoR. These data include: 1) the chemical and

ph ysical characteristics of the CO 2 

### injection stream based on sampling and analysis;

2) continuous monitoring of injection mass flow rate, pressure, temperature, and fluid volume;

3) measurements of pressure response at all site monitoring wells; and 4) CO 2 

### arrival and

transport response at all site monitoring wells based on direct aqueous measurements and

selected indirect monitoring method(s). The FutureGen Alliance will compare these

obse rvational data with predicted responses from the computational model and if significant

discrepancies between the observed and predicted responses exist, the monitoring data will be

used to recalibrate the model (Figure 17 ). In cases where the observed monitoring data agree

wi th model predictions, an AoR reevaluation will consist of a demonstration that monitoring data

are consistent with modeled predictions. As additional characterization data are collected, the site

conceptual model will be revised and the modeling steps described above will be repeated to

incorporate new knowledge about the site.

The FutureGen Alliance will submit a report notifying the UIC Program Director of the results of

thi s reevaluation within 90 days of detection. At that time, the FutureGen Alliance will either:

1) submit the monitoring data and modeling results to demonstrate that no adjustment to the AoR

is required; or 2) modify its Corrective Action, Emergency and Remedial Response, and other

plans to account for the revised AoR. All modeling inputs and data used to support AoR

reevaluations will be retained by the FutureGen Alliance for the period of the project.

To the extent that the reevaluated AoR is different from the one identified in this supporting

documentation, the FutureGen Alliance will identify all active and abandoned wells and

underground mines that penetrate the confining zone (the Eau Claire Formation) in the

reevaluated AoR and will perform corrective actions on those wells. As needed, the FutureGen

Alliance will revise all other plans, such as the Emergency and Remedial Response Plan, to take

into account the reevaluated AoR and will submit those plans to the UIC Program Director for

review and approval.

Note that seismic events are covered under the Emergency and Remedial Response Plan. A

tiered approach to responding to seismic events will be based on magnitude and location. A

notification procedure is provided in that plan.Area of Review and Corrective Action Plan for FutureGen Alliance Page B 46 of 46 Page B 46 of 48

Permit Number: IL- 137

- 6A -0004 (Well #4) Figure 17

. AoR Correction Action Plan Flowchart