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M.-= ((5.0lbl1b-mole ' 0 . 44)+(12 . 27 lblll>-moie'0 . 32)+(82. 73 1b/1 b-mole*0.28) ' (1 · 0.390))+18'0 . 390 

### M. = 24 . 89 lbllb-mOie 2-7 Average Stack Gas Velocity V,= 85.49 ft/sec [((lbllb-mole)(ll

### Hg))l(~)(ln Hz()) )) 112 ' (0 . 84 ){0 . 7938) 

## .J {(390 . 5"1=+460)1((29 . 54 in Hg+0 . 1357 in Hg) ' (24.891b111>-mole)) 

# v, -= 61 . 17 ftl sec • 60 sec/min v. " 3670 ftlmin 2-8 Average Stack Gas Dry Volum e tric Flow Rate 

## a= (1-0.393)(3670 ftlmin)(1B09 .6 in 2 )(1

### ~/**144** in 2 )[(52B" R'29 .56 in Hg)/(29 .92 in Hg'(390.5° F +<460))) 

# a 

# = 17255 n'lmin 3- 1 Dry Molecular Weigh t 

### M.o = 0.440 (5 %)+0 . 320(12 . 27%)+0 . 280(100{5%+ 12.27%)) 

### M.o = 29 . 29 lbllb-mole 4-1 Volume of Water Vapor Co ndensed

### Vwr~.1114l**=** 0.04715 n'lml' ((1 110 m\+220 ml+1 1 5 mf+1 ml+248 .9 g)-(250 ml+ 235 . 5 g))

### Vwr~.~= 57.023

### ~ 4-2 Volume of Water Collected I n 

### Silica Gel V""= ((248 . 9 9- 23 5 . 5 9 (0.06236 mmHg) m 'Jgmole)fi<)(2 93 "1<))/(760 mm g H 9)(18. 0**g/g mol** **e)(1.0g/~)** v- =0. 018m V._=0 .635 ft' 

### 4-3 Sample Gas Vo lume v.-=1.85 • ((166.894 

## II'- 76 . 1 21 

## II'- (12 1 . 1 39 

## II' -121 . 304 11")(29.54 in Hg +0 . 1357

· in

### Hg**)(528~))/( 29.92**  in Hg ' (86.2 °F+460)

V,_=89.02n'**~** 

### ,.

VES 003827

# C ·

{ 

# : 

# " ·' 4-" Moisture Content 

## a..:: (57 .023 ft 3 +0 .63 5 tf)l(57 .023 tf+0 . 635 tf+89.023 

## tn a,.. :: 0.393"100(%) S..=39 . 3% 5-8 1$oklnetic Variation from Raw Data or Intermediate Values 

## ENSR \AEC OM

I= 144in 2 1ft' * 4fn"(10<r(390 . 5°F+460)(89 . 023 

### ft1•29.92 in Hg))I((528 ° R)(3692 . 7 ft/min){0.313 int{29.56 in Hg)(120 min)(1-.390)) I" 101%**~1** In-Stack Detecti on Limits 

### A

• BfC=D 

## A! Front-Half 

### D"' 0.00013 . (30012 . 52) D 

# = 0 .0 16 uglm 3 Baci<-Half D 

### = 0.00013.(15012.52) D 

### = 0Jl079 uglm 3 

### Iii! " Front-Half 

## o 

# = o .oo 0033•(300/2 . 52l 

### 0 

### = 0 . 0040 ug/m 3 BI»CC<-Half 

### 0 " 0 . 000033.(15012.52) 0 

### = 0.0020 uglm 3 Fro nt-H alf 

### 0 

### = O.Ooo033"(300/2.52)



### VES 003828

## EN S R 

## I " AECO M 

# ( 0 

# = 0.0 040 u gl m 3 Back-Half D 

### = 0.000033 . ( 150 12 . 52) 0 ., 0 . 00 20**ug/ ~**  

## g F

ro nt -H

a lf 0 

### = 0 . 0001 • (30012 . 52 ) 0 == 0 . 012 uglm 3 Back-Half 1 D 

# = 0.0001 . (15012 . 52) 0 

# = 0.0060 u g/m 3**~** Front - H alf 

# ( D 

### = 0.000067'(30012.52) D 

# = 0 . 00 7 9 uglm 3 Back -H

alf 

## o"' o . 000067' ( 15012.S2 ) D 

### = 0 . 0040 uglm 3 

### .1:!9 Fro n t

- H alf 

### 18 

# o 

# = o . oooo5 • (30012 . 52) D = 0 . 0060**ug/m~** Ba c k - Half 28 D 

# = 0 . 00005 * (150012 .5 2) 

# l. ..**~:/.0116**


### VES 003829

### ENSRIAECOM 

# ( 0 

# = 0.030 ug/m 3 > 3A 0 

### = 0 . 00005"(10012.52) 

# . . 0 

# = 0.0020 ugl m 3**~** 

### 38 0 

# = 0 . 0001*(500/2 . 52) 0 

### = 0 . 020 ug/ m 3 

# " I 3C 0 

### = 0 . 0001*(50012.52) 0 

### = 0 . 0099 ughn 3 29- 2 Analytical Fraction 1A, Fr o nt - Half, Metals (Except Mercury) M.,. 

### = c . , F d 

# v- . • 

# ( A!. Mo. = 0 . 367"50 *0 . 3 

### Mo.= 5.51 ug**~** M., 

### = -0.005*50* 0 . 3 

### Mt. 

### = -0 . 075 ug ( N O) 

### Cd Mt. 

# = 0 . 049 * 50* 0. 3 

### Me. = 0 . 74 

### ug (NO) 

# .. £! Me. 

# = 0 . 229*50* 0 . 3 

### Mo.= 37.8 ug 

## (

.... . . . OGOtn'lber 2008


### VES 00 3 830

# ( Pb M., = 2 . 275"50"0.3 M., 

### = 34.125 ug 29-3 Analytical Fraction 2A, Back-Half, Metals (Except Mercury) 

## As M..= 0.094'10'0 . 15 Mw. c 0 . 1 41 

### ug M,.. 

### =**.005 '10'0** **15** Mbh 

### = -0 . 0075 

### ug (NO) 

## £!!

...... = 0 . 091'10'0 . 15 Mw. 

### = 0.137 

### ug 

# c &!



## • • 

# \.: .. ...... = 0.525'10"0 . 15 Mt, 

# = 0 . 79 ug 

### Mt. = 0.385'10'0.15 Mw. =0.58ug 29-4 Total Train , Metals (Except Mercury) M, 

# = (M,-M,.,) + (Mbh · M- ) 

## M Mt 

# = (5.5-0.68) + (0.10-0.10) M, 

### = 4 . 82 

### ug 

### ENSR IAEC OM

VES 003831

# (



# ( M 1 = (0 . 25- 0.05) + (0.025 - 0.025) M, =0 . 20ug Cd

· M, .. (0 . 74- 0 . 05) + (0. 1 37- 0 . 025 ) M, = 0 . 802ug M, = (3.4 - 0 . 65) + (0 . 79 - 0 . 42) M, 

### = 3 . 12 ug 

### f!! M, = (34 . 1 - 0.22 ) + (0.58- 0 .14 ) M,= 34. 32ug 29-S A nalytical Fraction 18 ; Front-Half Mer cury 

### HQt.= 

# a., Fo 

# v-.. Hga, 

### = 3.158 • 1 • 0 . 3 Hg, = 0 . 947 ug 29-6 Amount of Mercury Coll ec t ed in Sample Fraction 2 

### HQI.n2 = 

### 0t.a F o V- .2 Hgbl\2= 3.90"10•1 . 5 

### HQI.n2 = 58.5 

### ug 

## ENSR IA ECOM

29·7 Back-Half Mercury Values for A nalytical Fractions 3A, 3 8, and 3C 

### Hg,., (A.B.Cl 

# = 0 1>113 (A.B,C) 

### F d 

### V**~** (A.B,C) 

### Hg,., < " l = 0 . 675 •1 0'0 . 1 

### H9b113<Al= 0 . 068 

### ug H 91>113(B)= 0 .1 26"1•0 . 5 H91>113 t8l 

# = 0 . 06 

### ug (NO) Hgbl\3 <Cl = 0.357' 1•0 . 5 

### HQbll3 (C)= 

### 0.089 

### ug Ooce - 2008 

### , . g

VES 00 3832

## ENSR I AECOM 01lh3(A,B.C) 

### = 0 : 068+0.06+0 . 089 

### = 0 . 217 

### ug

## ~ Total Amount of Mercury Collected In the Back-Half o f the Sampling Train 

### HQI,I 

### = HQoh2 + 

### Hg,.,v. + l-lg111139 + 

### H9bN!C 

### H9l>l 

### = 58 . 5 + 0.068 + 0 . 06 + 0 . 089 Hg.." 58.717 

### ug 2:9-9 T ota l Tra in Mercury catch 

### Hg, " (Hg., - Hgt..) + (Hgw.- 

### Hg,t,.) Hg,= (0 . 947 -0.0075) + (58 . 717 - 0 . 175) 

### Hg, 

### = 59 . 48 ug 29-10 Individual 

### Metal concentratlOM I n Stac k Gas 

### C.=( 

### I<. M,)Nm<sldl 

## A! ' C.c (10-3.4 . 82)/(89.023 ' 0.2832) 

# c.= 0 . 002 mglm 3 A$ com!!<ted fO!" 7% Oa 

# c.= (4 . 82'35.31 4'14 )1((89 . 023 ' (21 - 12 . 27) 

### C. = 3.07 uglm 3 

### Be 

# c.= (10''*0.20)1(89.023*0 . 2832) 

# c."' 0 . !)001 

### mglm 3 

### Be co rrected for 7% 

### 0. 

# c.c (0 . 20 ' 35.314 '14 )/((89.023 ' (21 - 12 . 27)) 

### C.= 0 . 13 ug/m 3 

## 9! C. =**(1~3.12)1(89 .023** **'0 .2832** **)** C.= 0 . 00035 mgfm 3 Cd cotTeCted 

### for 

### 7% Oa 

## c.= (0 . 802'35 . 314'14 )/(89.023 ' (21 -1 2.27)) 

### C. := 0 . 51 ug/m 3 

### l f. 

### ,.**~-**



### VES 003833

# ( c."**(10~.12V(89.023•o.2832)** 

### C.= 0 . 017 

### mg/!Jil C r correeted for 7"!. 

### Oa c, = (3 . 12* 35 . 31 4* 14)/((89.023"21-12 . 27)) 

# c ... 1 . 98 ughn 3

. 

## f!! 

## c.= ( 10 ...

34 . 32)1(89 . 023*0 .2 832 ) 

## c.= O.o136 mglrn 3


## !!9 C.==**(10 '3.59.48)1~9** **.023 '0.28** **32)** 

## c.== o . 0236 

### mg1rn Hg corrected for 7 °4 Oz 

## c. = (59.48*35 . 3 14* 14)1((89.023'21 - 12 . 27)) 

### C.= 37 . 9ug/m 3 

### . ENSR 

# I AECOM 

# ' '

;



### VES 003834

## )



# · . AppendixC · \ 

# ENS R

ReferenCe 

## MethOd Calibrations, Verifications, and Certifications

\



# -- I I

VES 003835

# - . Refer&nce Method Manual Equipment Pretest calibrations ; VartftcaUons 

### and Checks ' .



### ' 

## .

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# ENSR 

# I AECOM BAROMETER CAIJBRATION DATA FORM F.eld Barometer 10# : Serial No. 5111 1 291 Reference Barometer 10 

### # : Seria l No. 188841
Pr e- Test 

### Ca libr atio n data · Calibnotion Pe<fcnned By : Ryan Bums Dille Reference Barometer Foeld lvnlracy in.Ha ln . Ha . ln. Ha 3-Jon-08 29.16 29.16**~** +/- 0.10 ln. Hg
Po s t - Test 

### C alibration data cailtlnllion Perfo<med By: R.Bwns 

# I Date 

# I AccuracY 

# I ln.Hg

## ~ +I · 0.10 in . Hg
Not e : The field barometer Is adjusted to agree with the reference barometer alter eam calibration . The refarvnoe barometer is ched<ed and re-<:alibrated by the vendor on an annual basis . j:**~**



### VES 003841

## ... )



# ) Reference 

### Method Manual Equipment Post - Test Calibration CIMH:ks



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# E N SR

Appendix D Laboratory Data 

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# .. ;:;;.: ·**5015 Ca~** **Dr** Suile 104**EasiS~ NY**  USA**1. ~74232** 

-F. K.In FIW•-(eo20lA Your Project#: 10002-022 Si18:CPT·VEOUA**~Date :**  2008109103 This report syper sedeS aD previouS reports wilh the same Maxxam job 

### mmber 

## CERJJFJCAII OF ANALVSJS

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### woe (2)- .... -perfotmlld 

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### soc- ·-

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### Digitally s igned by 

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### Challis Date: 

### 2008.09.03 1 6:09:00 

### -04'00 ' Tota l · cov er pages: 1 Paoge I oliO 

# l ''

. . Thil doc:lUMf'i.**~ ~**  fCim8t twd copy ls availat:l$e G' 

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### VES 003846( ·. · .**-..Joblf:~**

• Rl!>o<t Dlllr. 

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# --**Totol~** TOiol-.y.3(: --OUP TOioiMII<:oq3C 

# --**Tolol~** RPO 

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# - 103 103 

# - ... • 

# - 87.0 81 

# - <0.011 

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### 2llOoloom 1Ge 1Ge 

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# " 200111118128 100 1Cl6 3'"*?'0! 108 

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# - <0.!125 

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# - 108 108 20011081211 1011 105 

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# - 115 115 20011081211 ta.o 

# • 

# - 108 1011 

# - lOS 1011 20011081211 <0.015 20011081211 3.0 

# - ..... • 20011081211 48.0 

# • 

# - .os.s t1 20011081211 48.0 12 2008100129 25.0 100 200M)8I29 23.& liS 

# "" 85·115 

# "" 16-115 

# "" 10·110 

# "" . 10-110 

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# "" 16·115 'II 16 · 115 "'I 00-110 "'I 80· 110 "'I 

# ,. 20 

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# _ MMNorll ..... Ro14**~ ~**  et..a LJL tiH7**ill:~~** Tolrt,_ : (IIXJ)tll8o08SII F .:

(lOS) 332-81. , •



### VES 003852

# (**~** 

# ( '



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# a~~**!:.!- --=--** **---------!;;~~$~** EHSR --oliliollal Alleolllon : Jei!Gonnon Cllonl Poojoct 1: 10002.()22 P . O. 1: Poojeol- CPT .vEOllA i · TOIII aw.n.lum (Col 

# - 52.5 lOG 'IV 10· t30

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# - 50.4 .01 

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# - 20.$ 1015 1.111 e5 · 11S 

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# · - 61 . 0 101 "'I 1111·115

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# - 52.5 105 

# .. • · 115 SpiW Bloonk OUP !.*(!'b ) 

# - 5U 1QI ug • · us 

# --- T*-CAo) 

# - <0.20 "'I --OUPT*-CAol 

# - <0.20 "'I 

# -- T ... _ .. l 

# - 41.!150 ug --OUPT .... IIorylln(llo) 

# - 41.ll50 ug 

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# - <1).!150 "'I

-- OUP T ... o.rootn (Cd) 

# - 41.050 "'I 

# --**TOOoi~(Qj** 3lOMi8l2!l**~15** ug

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# - o .:ts , A:Ot..JQ.1S ug

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# - HC 

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# - 2.1 'l1o 20**TOioi~CI'Io )**  2001101129 u 

# "' 20 1_1l_R ... TRIXSPI<E CAHm41 T--(Ao) 

# - 411.5 19 ug 10 - 130 W.TRIX SPII<E OUP-) Toiiii-(Ao) 

# - .u 

# • uo 10-130 W.lRDCSPt<E (AH211:14) TOIII 9eo)4l<n (llo) 

# - 41.0 

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# - 47.5 M 

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# - 25.3 101 

# ... 70- 130 W.TRIX SPII<E OUP WQU:Iol) 

### r..., Ca<blom 

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# - 26.3 101 ug 70 · 100 W.TRIX SPIKE (AH211:14) W.TR»<SPR**-~(Ql** 

# - 52.o 10< 

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# - 5<.0 101 

# ... 10 · t30 W.TRIX SPto<E ,.,.. Lood Cl'bl DUP(AH211:14) 

# - $1.5 101 UQ 70 - 130 

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# ..... __ .....__._....,_ UL- 

# Til:--- T .. FJM: (IJOQt .... F..:(UOI)aa.ettl


### VES 00385 3

# ( .';

.



# --- Quality Assulance Report (Continued)

### -Job-~

1 ) -- ..**-~_** .... _ .... 3

PogUol10 TIOo-lolrl ____ lo_cn_

--- Rood,_on.to,.,.,_ l7LIIH7 I t



### VES 00 38 54

## M a**a~.! .~** **! ---------------------** **""'m; .;.;** **G;i#;;;;i': ;;-;~~** **_;i;~ ;;:;-;;.;-**  

# ( vaa!dat!on Slallltu!! 

## Pw Mux am Job t: A8114896



# ( . , ; 

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_ ____ ...._.,._ L1'1.- 

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### VES 003855

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Waste Feed Results 

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### VES 003856

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## a**,§j";:;,,.r;!J- --** **-- ----** **---- ---** **----2"':!'~"'!2:.!** 

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## . ·'
A&tantton: Jeff 

### Gorman ENSR lntematicnal**5015~1lr** S..lle104 e.-t Syraalse , NY USA**13057~** 

### "AXXA" .JQBt; 

### AfMI39 Recatved: 20NIDII25.11:30 

## Sa,.,a. lolalrbc UQUID • Samples Rec:afyed: 8**~** Dat. : 2011111f16 This report""'" 1 '" all pnMous reports with the -

### ~~**-job** ....- C§RifiCAJ'E OF 

### ANALYSIS 

# ( .. . 

# , f .
.. . Sltnple MM1X: Sell II Samples Recetved: 6
-Inti t.,Co/Mf 

### T* -In 8ol bf-ICI'-'ESt EPA 1WIIt81010;C

,,,_ ....**-~** .. -- . ... -'41"**~,** 

# ___ ... _. ....,.b....,...d_ln ____ ... ICI' ........... """""0>
Total.....,. pages: 1 

# _,.,,.
___ .. ___ r:ovyis_ ... _ Digitally signed by Mike 

### Olallis

### ~.;.:= - Date:**~** 2008 . 09 .16 10'.16:33 .()4'00'



### VES 003857

# c**:~** M 

## a J:J 

## a**----- --** **-------~,-:.** 

## ___ ........**!!!:1!!!!!..!""~** ....

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# . . .•.. . . ENSRI-**~** Projod ,, 1ooo:!o022 l'nljecl nomo: C!>lWEOUA RESULTS Of AHA!. YSES OF LIQUID

# ~(Q)**I~** 1 . u

Pago2ofM

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### VES 00 3 858

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# __ ,_**R~** Dole: Z008/0Q/15 ENSR lnl-'<lnel Clenl 

# "'*"'Ill: 10002-022 PIOjod namo : Cl''l'.VE OUA ELEMENTS BY ATOioiC SP£CTROSCOPY (UCIUKI ) 

# = il *-"" ) oro\ 210 

### o.oe 110 

# - ll'O 

# - tiiiZ70 "'"'llor)OUo jllo) 11'0\ 

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### o.os 11021 .., ""'Uoolll'b) II¢ 

# ,. 0.09 23 0.08 100 0.09 1102143**~~** 11'0\ O.ts1**~** G.0\5 b.oot$ 0.0111 

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# . M .. . ... . . ENSR -.wlonal Cion! Plojecl"' 10002.o2 2 Pmjecl..,.. : CPT·VEOUA RESULTS OF ANALYSES OF SOIL



### V E S 003860

# (



# c l 

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# 65J.~X!J--**-------- --** **-------- """''"'"::-:.!r=s-,.o:-=.,J=,-='""'-'**  • EH$R lnlotnalional Clienl Projec:t II: 1 OCICn.(IZ2 ProjeGt nome: CPT ·'IEOL IA E LEMENT S BY ATOMIC SPB:TROSCOPY (SOL)

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# ... 17 11 14 1803131**.,..._~(Be)** 

# ... <0.5 <0.5 <0.5 0 .5 1CI8311 

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# ... 1200 1200 

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# """' 1100 I3ClO 7000 o.5 1110:18S -l.ood (1'1> ) uglg 1300 1400 1100 1-**~-.l>nll** BMch. Qally Cor*d B*h**-~ IHill**  uglg 0.841 

### o.eo o..sa D.82 .ll5 1 1102142 

# __ "'" , ..... 31 

# ""' 1& 18 1 

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### o.s 1 1021311 

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# .., NIA 110 1711 0-3 1eo2831 -a-.- (0) uglg 

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# __ .....,.._ • Rt:;c: bible Olledlon Lml**.** a.My Ccnlrd llk:tt

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# ..... 1fT 1 1102831

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### - -a-wn(Ct) ug/g 9110 0.5 10112831

-- PAod (1'1>) 

# ..... 220 1 

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# QC -.<MIPJOorO!dPago5ol1 4 

### i ·

VES 00 3861

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## a**,§1.~-m-- ~-~** **----- ----------** **.;.. ·**  

# _., ..**!!A=:~.,.,** 

## .... =:•**..,-~ !!!!!t.** **ENSR~"'"roa!ic>iOI** Clonl Plojed It , 0002-«12 Projocl- CPT·VEOUA ELEMENTS BY ATO M IC &PECTROSCOI'Y (WATER )

----- _.,....""'""" L7LIH7 

### ,.

VES 003862

# (



# c ·;

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## EHSR-.. Cfionl P!ojocl II< 10002.()22 Pn>jocl- ; CPT.VEOI.IA**~** 

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# r: ·. '<.. )**-~~** AH :IOI52 

# ._...,**~~**

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_., NOOII2 Dio>**-~~ ~~**  - Sol

## -~~**-~~ ~**  - Soil 

# _., _

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Pogo8 ol14 ENSRinltmCionl Poojod 1: 1 0002 .()22 Pn>joct - : CPT - YEOI.IA



# . . 

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# (



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# - ...
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# --**-----~"-** 1.1LI5H7 ENSR-..lonal Clenl Projoct"**10002~** Prcjoclowno: Cf'T·veotl4



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### V E S 003865T eo l Summary



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## '

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### VES 003866

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### VES 003867

# ( Ouolity As9Urence Repocl -Job Nun- BA89<939 ENSR_,._ A....,liorc Jell Gorman**Clef'll~f:** 10002.(722 P . O.f: Projod name: CPT-VEOIJ.o\



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### VES 003870

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## ' Dote ...... ..,, 09111112001 ASH, OIL



# - 1 . 05 0.01 HI!!A TIHO VALUE BT\MUI



# - vu ,_ 

# .. 4, 1130s.-01B I LBTU-U4-R2 LablD : R-S0-02A**Dolo~ :**  0112112001 0:00 Dlt e Re cefvecl: 09/1112008 AS H; OIL



# ...... 0.02 00 0 . 01 HU TIHO V ALUE BTUILB 

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## ·~ 

# - M.ltrtx: AQUEOUS 0412**~** VJO 112<0

### ·~ MRIP

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### VES 003871

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# - ..... ""' HEA l11G VALUI! B1\IIUI



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# - 0.01tKJ , 1.01**HI!A~O** VALUE BTIM.II HtolfnGV- < !0.000 50

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........ OolarioL7LSH1 RCl$090001 A89ol939 

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### Suoflod: 0812112001 0:00 Dole Jl.e<eiYecl: 0910212008 ASH, OIL

All> HEATING VALUE 81UIUI 

### AB3062=91R/CA-41-R2 Lobi!): R0109000J-o7A 

### o.oeoo 0 . 01 t,BOO
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# -
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### VES 003873

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. Date: C lJINI" : Man- Aaalytko l Sortlocs 5555l'l • '*s.m..Rd

.. .......... - L7L5B7 LabOnlm 1\08090002 l'rojod: Al94939 A.UiyJto A<Reedndllull Drylluls AB3052-0IB I**~IU-RI** Lob IJ) : R O

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# VES 003878.pdf

### VEOLIA ES TECHNlCAL SO LUTION S , L.LC RllSPONSES tO Tim 

### UNITED STATES ENVIRONMENTAL PROTECTION AGENCY'S REQUEST TO PROVID E INFORMATION PURSUANT TO THE CLEAN AIR Acr DATED JANUARY 29 , 2009 

# Exhibits K - 

# N

VES 003878

## K

VES 003879

# .. . . 

# . . '· 

## VEOLiA .ES TECHNICAL SOlUTIONS, L.L.C .
. . .**~',.** 

## • ..•. ' . . SAUGET , IL . . . · . . .
.. 

## . ' . .. 

## . · . 

## · · :. oocuMENt 

# oF**C9MPi.J~c.; ooc>**  ··.:· . .NATIONAL EMISSION STANDARDS .

_ . .. f.OR HAZAR(>OUS AlB POLLUTANTS : FROM - HAZADOUS 

# W ASTE . COMBUSTORS



# .. · : :· \' 40 CFR ' PART 

# 63 ' SUBPARt 

# EEE .

. · · . 

## · .. 

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## ui...;s.....t..ci<..~~**~~ i!~"d**  VES 003880

## ...



# . , . VEOLIA ES TECHNICAL SOLUilONS, LLC .

. . SAUGET, IL . ·. DoCUMENT OF COMPUANCE NATtON : At- . EMisSiON · stANDAfUlS FOR . H/aARDOUS AIR POLLUTANTS FROM HAZARDOUS WASTE COMBUSTORS : .. _. ·. 40 CFR 

# PART 63, S!JBPART EEE OCTOBER 14 , 2008 

## '

· ;· ;- . 

## .

. . .. ' ! · .. 

# .. Veolla ES Techni - cal Soh.rtlons , LLC. , certifies that : 

# . . 

## . .· . . . 

# . . . . .
. 

## . . 

## . 

## .. 

## (1) . . · .**R~uiMd c~**  and CMS 

# are ln$talled, calibrated , and

· _. - · .. c

_ omlnuo\lsly**o~atlng** 

## 111 coinpllance · wlth the

.. ·

### ~uirerne~**.** of this subpart; and ·

.**~** . . · ·. ·**·~·:·:** ,; · ; 

### .... : . 

# : 

# . . . . 

# · : . .. ' . . . . . 

## . ..

. . . · · (II) . 

# · l:liiSed ' em 

# an engineering evaJ1.1ati0n prepared under · • · r ; . 

# iriy**tfl~ tiOn** **~r** 

### sul*'fision . II)**~ccordail~e** 

### with a 

# · : .:·· /: system d8stgo8d to · ensure 

## thirt qtiallfled personnel

· : · properly

## ga~red**·** and evaluated the Information and 

## : .

i .

. supporting dOcumentation, . and considering at 

## a

. · • _' mlitlrrium lhe, design, operation , and _ maintenance

.. ; chatacterlstlcs of the 

### combustor and emission



# . · .· . 

# . -': c:OOtr'ol equipmen t; 

# the types , · quantitieS, and ·

. ·

• ·

## ~ractenstlc of 

## teedstreams, : a · nd available · ·**emisSions ciata** **:** 

### · · ·

.

## ~ • :· : (A) yeo11a

## E~**Teeh nl~l** **~utloi'ls** 

# Is in tOmpllance

· ·· · · with the emission standards of this subP.ar:t; a.nd

. . · ': . . . . . . 

## . . ' 

## .

## (~)The ilmlts · qn the oi)eratlng pa.i'ameters under 

## · . 63.121:19 ens . ure · complianee 

## with the emission ·



# . . . .

# ~ '... . ,

# stand8rd~ of thiS 

# subpart . . . 

# IJ ·**<** . . · : ··. < ¢..MJJ

# ~4~'8 

# .. · Geoerill Manager

· · ' 

# . .

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# los Date I \ J**~** t I i r

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# .**~** ,· :;



### VES 003881

### :_ 

# ) DOCUMENT OF COMPLIANCE TAB LE OF CO NT ENT Applicable Emission Standards And Operati ng Parameters Start-up, Shutdown and M alfunction Plan Operating and Maint enance Plan CMS P la n ESVP i an AWF CO Pian Feed Strea m An alysis P lan CE M s Plan (QA/QC P l an) Rel ativ e Acc ur acy Test Au dit ForCEM s Specificatio n Sheets for Hydrated Lime Specification Sheets for C arb on Residence Time Ca l culations OJ)erato r Certificatio n Training Soction 1 Sectio n 2

Sectio n 

### 3 Sectio n 4
Section 5



### VES 003882

## HWC MACT E mi ssion Standards
Parameter 

### .\.!J1ili! Standard £@7 % 02> Method of GomnUance Dioxin!Furan (DIF) ngldscmTEQ 0.20 

### Operating Parameter Limils Mercury (Hg} 

### ug/dscm 130 

### Operating Parameter Limils Semivolatile Metals ( SVM) 

### ug/dscm 

### 230 Operating Parameu:.. 

## Cadmium. Lead 

### Umils Low Volatile Metals (L VM) 

### u gl dscm 92 Opcraling 

### Parameter 

### Arsenic, Beryllium, Orromiwn 

### Limils Carbon Monoxide (CO) ppmv 1 00 

### Continuous Emissions Monitor Hydrogen Olloride/Chlorine ppmv 

### 77 Operating Parameter <. ") (HCI/Cl2) Limils Particulate gr/dscf 0.013 

### Operating Pat111llmr Limits

•. 

### )

VES 003883

## .. · , i .. .... . ·

Opsqting Ppmeter**~** : Umiis :· : s.: ·. · ' "':-L Test rHt1!

# =~~--**· ~fJti** **~·~** MJximum T ctalHazardO\ls · Lb/br . 

## >**.ot ~,** **.· .v** **May** 2004 · Waste (Hourly Rollmg Total) • :

# :j[~;~:!L~~t 

# · . ' .·. Maximum 

### Stade Gas Flow Aeful 1 5 , 1

47 '" · · · :• • · : '; . 

### SePt. 2001

## Rak{HN~RollmgA--se) · .

## :::~{**, .;~·**  · MlnJmum PliriwyCombustion Degf 

### 1734 :<:-: .. , . . · : ; ·,· May 

### 2004

# ~~~~=~(Honey ,. . .

# ='1,:ft;i~~; 

# . · _. Min!mlim Secondary Combuslidn

### Dei**~** 

## · · · · .**1_.~ ;:**  

### i: . . ' ; • . : .' •: : : Nov., 1996 .

# ;;;.~;~ 

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..

# ~l**:--·'""** ,; j verise > . . . . Mai< . PUmp.LowVolalileM.ellls Lblhr : 46 "- ;:y:>,- .. .**-:; ~2008** 

# Fcedialc(**2~RoUingJ"otal)** • · "

# {·~**·> :.~;}**  

# . . . MaX. . Totall..owVolati.leMetliS 

## t.bn.r 47 ., .,.**·--d Sept_**  200& F«draae ( 12 H ow RoUini TOuQ •

# 'g.~**:\ ·~~** **-~ ;:**  

# ' . . Maximum Semi VoiJtile Metals LbiJi r**6~. ."** **~·~::** . : , Sej>t.,20QS

# :::·::::~> Whr

# -:,~;f0~z{}:**Aag,**

# 2008 DIU!, DIP DJ.l.B, j)/F, Part, SVM,

L\IM 

### oRE, DIP

DIF,SVM, :

LVM

. LVM
SVM (12 Hoor

# ~~Ding Toia!) . : . : ; 

# ':( . :;_; ; :ff: . Maximunia.torineFeecbte Lblhr· 21F · · l . · ., . , Ailg 2008 siiM.LVM

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### bp<nling 

## .-meter limits in cable refleet

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VES 003884UNIT 

### !t Ol'ERA!ING PA:BAMET!i;B, J,IMITS


# . . Pcrfonnanco Opcn!jna ParaedP' .IIDill 

### .Limila**~** SUrvlen1t M

1ximu1n Total P 1.1 mpable Lblhr POC - 3156 

### s.,c.. 2003 ORE, DIP Wuto (Hourly R ollinS TOIII) SCC-1006 Cond. I MM i mum Tora l Huatdous Lblbr · POC - 13,7% Sop<.. 2003 DR£, DIP Wute (Hourly Rolli"' Totel) 

### soc - t006 C4nd. I Mu im.um S tldc Oas flow Acfm 3&.016 ""' ' 2008 ORE, DIP.**~law** (ll.,..rly 11411i"' 1\-) p_.,SVM, LVM M**iAimtn~** Prirury Combustioa. Dq , F 1507 Sopt.. 2003 ORE, 0/F a-.ber T ..,.,.._e(Hourly Cond. I RDIIiosA-l**ni.~n~.n** Scc:on4ary Combustion DqF 1116 Sept.. 2003 ORE, Ill!' O..mbc<T-e(Hourly Cond. I R.olllnl A..,.ap) Muinwm 0-.c'MM.LSe {nlet DeaF .34 Aq.,2008 DIF.SVM , 

## -r.....,......"' (Hourly 11411ing LVM 1\"""80)**~u .**  Pump . Low- Volatih: Mc:tab t.bllw 47 AAI&-.2008 LVM .: ..

r•<l2- Rotun,Tooal) Max . Total Low Volarilot.fctab U>/br**~** ..... . . 2008 LV M F-oe ( 1 2 Hoot Rolliog Tooal) Muitnwn Suni Voluile Metals Lblhr 64 

## Au" 2008 SVM F-(12 HourRoii ... Tocal) M- M"""'Y Food- Lb/11< 0.016 Aoa-2008 Ha (121lou< Rolf"" Tocal) Muimwm Qlorilc Food n&e Lblbc 2S2 Aue.. 2008 SV M. LVM, { 12 Hour Rollhoc Tocal) KCI/Cil Max im""' Mil Food Ruo(l1 Lblhr 

## sm Do;., 1 995 Port. Hour Rollins Tocall Corbon l njcecioo 

## f- Lbll w (l lourl y Rolling AV<nge ) 6.2 Au g., 2008 O IF,11g Minimum Sorbalt Feodralc. LbllbO, 1 .0 1 Do;., 199 5 HCI/Cil 

### ... ( Hourly Ro lli ng Avcnp) M

in.imum Catricr Flaid Flowmte OolllbO, 1 . 61**~1995** HCI!CI2 (Hou<iy Romna A-l



### VES 003885

## (

· ' 

# · " '

·.

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## .

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### CONTINUOU S MONJTOIUNG SYSTEM QUAlJTY CONTR OLPROGRAM Prepared for: Veolia ES Technica l Solutions, L LC : Sauget, Illinois

Prepared by : 

### Franklin Engineering Group, lnc. 

## Franklin, Tenn essee



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T S 

### 1.0 JNTRODlJCTJON AND BA C l<GROlJND ......... ....... . .. . ....... . ..... . ....................... ) 1 .] SUMMARY OJ' FA CI U TY IN FO RMATION . . . . ...... .... .... ... . . . .. .......... . .... .. ...... ....... .4 1.1.1 Fixed Hearth Incinerators . .. . .. ............................. . .. .. ....................... 4 1 ./ .2 Rotary Kiln 1n ci n era t or .......... .. ........ .. .... .. . .... . ............... ............ ...... . 5 1 .2 CMS lN SlRUME NT ATION .... .......... ... ..... .. . ..... . _ ........ . ... ....... .......... ...... . . ...... 6 

## 2. 0 CMS CAJ.JlJRA TI ON AND PREVENTIVE MAlNTENANCE ........... _ ...... 13 

### 2.1 CMS CALm!lATION .................. . .... ......... . ........................................... ......... 

### I3 2. 1 . 1 1nitial CMS Ozlibration .................. ... ............. ......... ..... ................. JJ 2.1.2 S-ubsf!'{UDII CMS Ozlibrl11ion .. .............. ................ ... .. _.,_ .............. J3 2.1: 3 CEMS Ca/ibraJion Aud its and Calibration ............. ...................... 14 2.2 · CMS CAUBI\ATI ON AUDrrs ...... ........ ...... : ....... .. . ............... . ................. ... ... :l 4 2.3 ·**~MAIN'I;BNAN CI!**  ..... : ...... ........ .... ...... ...... ......... . ...................... ....**~9** 3. 0 . CMS RECORD KE E P I N G AN D lU.:P o RTIN G .. . .. .., .. - ....**~** ................**~** .. .. . .... 2 0 3 . ) · Rl!cOlU>Kl!EPING ...**~** ......... : ......... . ...... .. .... ....**~** .... . .. .... : ..... . - . ..... ...... : ............ 20 3.2 REPOR'imo .. : ...... .. : ...................... ......... . . ..................... ... .... ...... ... ............... 2 1 

### 4. 0 CMS C O RRECTIVE ACI' I ON S .. _ ....... : ...... ---·--- - --···-- - .............. 24

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# ( ·

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## ·=· , . : ,",,•. 

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### INDEX OF TABLES REGUt.ATOJIY OI£CXJJST roR nlE CMS QA l'R OGRJ•M ..... . . .... .. ..... .. .... .... .. 2 CMS INsTRUMENT SPI!Cil'ICA TI ONS . . . .. ... . ..... . ... . ... ......... . . . . .. ... ...... .... .... ..... .. 

### ? CMS CAUBRA TI ON AUDITRI!QUJR!!MENTS ................... ...... .... .................. JS REPoRTING REQUlR!llitENTS .... ......... ............ ....... .... .. . ........... .......... .. ......... 23

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### VES 003888

# .. 1 .0 INTRODUCTION AND**BACKGROUN~** 

### Veolia ES Technical Solutions, LLC (Veolia) owns and operates two fixed hearth in cinerators (Uni t s 2 and 3 ) and a 

### ro t ary ki ln incinerator (Unit 4) 

### at it s facilit y loeated in 

### Sauget, Illinois . The inci nerator s are su b jec t to 'the 

### National Emissions Stand ards for Hazardous Air 

### PoUutants (NESHAP) for Hll7.ardous Waste CombuStors (HWC) , 

### Part 63, Subpart EEE (§ 

### 63.1200 t o § 

### 63.1221). The NESHAP specifies emissioos standards · which reflect emissions perfonnance o f Maximum Achievable Control ' Technologies

(MACT), and is 

### commonly re ferred 

### t o as 

### the HW C MACT . H82Mdous waste combustOIS are required 

### (per § 

### 63.8(d)(2)) to establish and implement a Continuous Monitoring S)'s tem (CMS) Quality Control (QC) Program. 

### The pmpose 

### of the 

### QC Program · ;s t o outlioe procedures used 

### to verify that 

### the CMS are 

### propeTiy installed, cab'braied, and 

### coUocting accurate 

### da1a on an ongoing 

### basis. The 

### CMS • pcriormance evaluation test plan 

### was submitted as part 

### of the Comprehensive

. Performance Test Plan.

·. · The 

### QC Progra'm . demon strates . V eoli(l's co mpliance with the 

### !equireJnents set 

### fo:rth 

### in

.. § 63.8td)(2), 

### as . welt 

### as the 

### additional quality**assl~** 

### (QA) requirements. The QC ·



### Program is 

### requ'imf to contain descriptions of initial and 

### ·subseqUent CMS 

### calibl'Biion, calibration drift, 

### pre ventive maintenan ce, data recording. calculations 

### and reporting; and " corrective action plan for maLfunctioning 

### CMS. Table H presents the 

### regulatOtY · 

### imerences related 

### to the 

### QC JAO&IWU. 

### foUowcd by the 

### section of 

### this p lan that addresses each. · . 

## . specific 

### rcquiremeot. Some references aro made to 

### other HWC MACJ' required 

### f acility operating plans.

• • t •• 

## ,· _'**:~** 

## .:_ . ·;_ . . 'Ibis-
. QC 

# hogram iS int'codc;d to 

### fulfill the 

### roquirements 

## of§**6~.8(d)(2),** and 

### iDcludi:s . :· . . . :- ,

### ~ .. ··: __

### ':**U!f~J<:~ totheprocedurcafOfeachOf~.fG)I~openlioos:**  ·

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# _:**~~·** 

# . · . .

. .

.. . :· . <**~.** 

# . . ! • • . • •• • 

### •. ·, .-. ,,. •. · . • . -.:; • . · lnilta! . and

. .subseqn<;ot**calib!'alion oflbc~S**  · · • . . , . · .: . 

## . . ' 

# .. . . , 

## . 

# . ... ' · 

## .. . 

# . . . · 

## .. . . . . 

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## . . : 

# .. ' ' · : ':· . . · ·:: · · ... . · .. '.·

•**'' Dtt~andiadlUsfmCotoflbocalilJrati.ondriftoftb8CMS** **'** 

### · ' < •• • • • • • • • ... • ., .·! • • . • • • • . • • • : ' · 

## . . . · ., .• .

. . 

### ·.'·. ·.·., · .. :·:. '.;· . :**~e.itiVe~o(.thoc:MS; ioclil!fuigsperepartSinventory**  

# ..._ . :. :**,~ --** **~~** 

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# . ·, . - :. . . . . . 

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.. . . . ' . 

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# . . . , 

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• .. i

VES 003889

### Table 1- 1 

## ( R egu l atory Ch ecklist for t b e ' CMS QA Pr ogra m



# - .Regulatory De s cr i ption Plan Sectio a Citatioa Sec tion 1.2 , 2 .3 § 63.8(c)(l)(i) Opera t ion and 

### maintenance o f each CMS O&MPlan CE MSPJan § 63.8(c)(l}(ili) Startup , sh utdo wn, and malfunction plan for CMS SS MPPian 

### § 63.8(c)(3) Verification of operational stll tll$ 

### CM.S PET Plan § 63 . 8(c)(7)(ii) Out -of - contro l CM S data will 

### not be used 

### in 

### averag es Section 4 .0 and calculations. § 

### 63.8(c)(7)(ii) Corrective actions for an out-of - contro l CM S Section 4.0 and



### . SS MP P l an § 63. 8 (c)(8) Ou t -of-control CMS informatiop to be submitted Section4 . 0 § 6 3 .8(d}(2) Devel o p and 

### implem ent 

### QC portion of CM.S 

### QA Section 1.0

. J)IOI(Talll

.. • 

### QA program i ncl u des the d evelopmen t 

## and submittal of

. § '

63.8( d

)(2) 

### the" PerfOrmance evaluation t est pllw .. · Section 2.1.1 '



# . ( · § 6 3. 8(d)(2)(i) . Develop written procedliies for 

### initial and subsequent 

### Sections 2. 1 . 1, cah'bralions 2.1.2 § 

### 63. 8 (d){2)(Jj) Develop wri tten procedures for dctc:Qninatio n and Section 2.2 3di11Stment of calibration drifts . 

### § 63.8(d)(2}(.W) Develop written 

### procedures for preventive maintenance and 

### spare parts 

### inventory_ · Section 2.3 § 

### 63.8(d)(2.}(iv} Data recording. calculations, and 

### 'reporting Sections 3 .1 , 3 . 2 § 63 . 8( d)(2)(vi) Corrective'actions for m alfun ctioning CMS Section 4 .0 >**§.63-:~)(3)** 

### Pe:rf011D311C4 ev aluation ofCMS · 

# -**~PET** 

### P lan 

### .. , . § . 63.8(&)**Redlle~** o f monitoring 

### data :·. 

## . .**oo 3.2**  § 

### 6 3'.1 0{1) )( 1) .. MainWnin g · ,fil es 

# . .. .. Secti o n 3.1 

## · 

# . . :: · ·**Miiinlain=ros or~enta.fromperl'~**  

### ·.

. . §**6~. O(b)(2){i'i** **}: ,** **~tiOI)s** 

## . .. _ · .·: . . -. : : · .... ' ·-. : .. . ..·_ seclion . 3 . t 

## ... . · 

# ... . 

## .. . ·.



### .. .. §**63.1 o(b** **)(2~) ·** **~1m** teqmls 

### of**~ch ddurin&**  

## which a CMS ' is-**~Qn4 aod**  '· 

## .: : 

## . . : : · 

## .... ..; 

### .

## nill&o~~**eiloii' iofcon** **·** .. ·. . SSMPl>lan 

## . .**~** 

## ... Ma ibtain.retoros ofmea$'Gremeuts to**·** 

### § 63. 1 0(b)(2){vb) . . Section 3.. 1 

### I COIDI>lialicc : 

## . :·



## ...**~** •' 

## . ..



# ..**Maintain~** 

### of result$ 

### of CMS . pcrfoqn3D<» ·


## .. § 

### 63. 1 0(b)(2)(vili )**~M~~uai.ions** 

### m d op acity ·and vis.t'b l c emissio n S ectio n · 3 ..1 ' 

### ob savaticSiis 

## . .

. § 

### 63. 1 

### X) M aiDWD 

### records. of 

## CMS .cahlnation chects SeCtion 2 : 1 .2

2 

### VES 003690

### { \

· . 

## .. · .'' . . . 

# :

6 '

. . . .

·::-: .:\' 

# .. . 

## .. . .,. 

## .. , 

## .



# . .

.**:~** 

### '

' . 

### '
' 

# . .
.. . . .. 

# : r,

. , 

## .. Table J - l (co-u tiou ed) Regulatory Cbe:dtlist for tb e CMS QA Program


# · - - ·· - --- - R<gulatory D escription Plan Section

Citation 

### § 63 . 10(b)(2)(xi) Maintain recotds o f all 

### adjustments and 

### maintenance Section 3.1 performed on the 

### CMS Recordkeepillg requirements for CMS measurements § 

### 6 3. JO(c){J) (includin g unavoidabl e breakdowns and out - of - c o nlrol si tuatio ns) Sec tion 3. 1 §63.10(c)(13) Maintain records of total 

### process operating time during Sec tion 3. 1 the reporting period 

### § 

### 63 . 10(c)(l4) Develop and implement 

### eMS QA program procedures Section 1.0 § 63.10(c)(5) Maintain recotds of date and 

### time for 

### CMS Seetion3.1**ill~ility** 

### ( exceot for zero and 

### hi_gh-level checks) § 

### 63.JO(c)(6) 

### Maintain records of c;late and 

### time for CMS**ou~f-** 

### Section 3.1 control oeriods Maintain records of identification of each time period 

### § 

### 63 . 10(c)(8) of ex c eedaoces - do es not include periods of 

### Startup, Sciction 3 · . 1 ShutdoWn Malfuoc tion (SSM) . 

### § 63 . 10(e){3)(i) Submittal of semiannual . exc.ess emissi ons and 

### CMS Section 3 . 1 · performance 

### reoort § 

### 63 . 10(e)(3)(v) Content :mel 

### submittal data 

### of excess emissions and 

### Section 3.2 CMS pcrfollll8Qce J;CJ>Ort 

### § 63 : JO(e)(3)(vi) Content <ifSUJJl11l31')' 

### report requin:d 

### by (c){ 3)(vii) and · Section 3.2 (c)(3){viii) to 

### Ibis section 

### § 63.10(e)(3)(vii) Condition for submitting ooJy 

### the SWlllllal)' 

### report Section3 . 2 §**63.10(e)(3)(v~)** 

### Condition for S)llimitting both 

### the 

### summary report and

. Section 3 . 2 .eitcess emiaf\ions and · CMS penounancen:port 

## . . § ' 63 . 12 1) 

### . Cah'bmion o f and Section2.. i 

### F of 

### CMS 

## liD& ahlatio · • . · 

### §**63'.1209(b)(~)** 

### . ,**~Y** . ...**·· .** **~** ...**n; ~&**  .. : 

### Secti on 3 : 1 - and tee , ordiilg, 

### of**re8uJated ~et** **r** 

### · . · ·. : ·:' · § 63. t2Q9(b)(5) caiculaticmio(tolliDg**~** 

## . · Section3.J.,
, §**63.1211~)** 

### requi= that**CM~hre** 

### imtalled; 

### § .**1209(f}(J.)** 

# . . . 

### ' . . 

## . 

## . . . · . 

### CMS l!ET Plim . '' : . • calibrjlled; and opcratimlal by 

### tbc**wmp1i~** dllt& · ': 

### ' i · ; ' . . . . 

## . . · 

# .. . 

## · •' ' - "**~** 

## ·.·

.. PIIT · . PaiOtllliiDOCEvahlatiqo Test - . · SS..fP 'Siartnp,**~"""~unCtion** Plan SOP ·**s~~Pnclic:e$** : . ,.

... 3 :·· ··''" . • , • ' 

## . 

## .

. 

# ··• • .. . 

## · 

## ......... : . 

### :; .. ·**:·!.~** 

## ..**~:** 

## > . 

# ·-;,:·?/ .. : :•: 

## . . ' ; '·:. •'
'· .



### VES 003891

## l



# · ( i . . The data collected from CMS in s lrumentation is us ed t o dem o nstrate the 

### unit ' s compliance wi th th e performance requirements promulgated in the Interim HW C Maximum Ac hiev ab l e Contro l Technology (MACT) standard . The Q A Program out l i n es proc edures u s ed 

### t o ve rify 

### \b at th e CMS are properly 

### cali brated and co ll ecting accurate data 

### on an ongoing basi s . Due t o the simi l arity of Ole three 

### CMS systems (one fo r eac h incinerator . sy stem) , g eneral refa ences 

### t o a CMS system o r incinerator system in this documen t will imply 

### all three sys t ems . Jnfonnation t bnt i s on l y applicab l e to 

### one or tw o of the three 

### systems will 

### be clearly**i~entified.** 

### This document i s organized as follow s :

.· · · 

### Section 1. 0 Section2.0 Section 3.0



### . Section 4 , 0 Introducti o n and ,B ackgro un d 

### CMS Cali bmion 

### and Preventi v e Maintenanc e 

### C

MS Rc:c0rdkceping 

## a¢ RePorting

. CMS Corrective Actio m . ' ' • • I

# ~plan also assimilates infoimation . .

# and**~~** foun d 

### in other doe wn en ts. As 

### requlred by § 63".6(eX :iX v i), other 

### docw:nents containing 

### procedures or IDfonnation refUTed . I Q 

### in this p lao will be 

### m'l(le . avru1 ab lc

..

f or insp ecti o n wben . requested by 

### the 

### ·.**AdminiS~cir .**  

### ' . · · '-" · ·

. . 

# ...

.. . . •.**~** ' '**~** 

# . ....**~.** . : 

### .... . : ' 

# . . : . 

# . .



# .. . .. . 

## ...



## . · . 

# · . . ·.

VE S 003892• . .



## . . :.



## . ·. 

## · . . ' · 

## ..**;**

. ' 

# .. · . .

:t'.·. · · ' 

### • Primary and secondary combustion c hambers • Lime inject i on system • Spro y dryer absorber (SDA) • F abric lilter ba g llouse • Solids and ash removal systems • lnduced draft (ID) 

### fan and stack • In s trumentation, contro ls , and data acqui sition systems Vari ous solid and liquid wastes and ga seou s feedsueams a re lh ermally trea ted in the fixed hearth 

### incinerato n. Solid waste is fed to 

### the primary (Iowa) 

### combustion cbambe:r via a feed 

### conveyor system and 

### pnellmatic ram . Liquid waste from tanks and tanker trucks 

### are fed to the 

### p rimary combustion chamber through two atomized liquid injectors. Liquid waste from 

### containers are 

### fed t o the 

### . primary c.ombustioo chamber through a specialty . feed 

### injector . A 

### gaseous 

### feedstream is fed to the Unit 2 

### primary com bustion chamber directly from 

### 8)lli cylinders. Off gases from 

### a 

### hooded feed emission control
, sys)cm · and from a waste handling glove box · are fed 

### directly to the Unit 3 seco ndary

· combusti on chamber . Combustion chauibe:r

### temper~ are maintained using naturai ; gas fired 

### to a dedicated . blliDcr in both the primary and**s~ ndary**  chambers . 

# . . .



# .. Combustion gas . . exits the secondary combustion cbambei and 

### rotlllS the SD A,. 

### which provides acid gas rem ov al and 

### cooling of lhe combustion**~** 

### Combqstion gas exits the SD;A and 

### is distribpted to the 

### fi>bric filler l!agbouses, 

### wbich provide particulate mal1er ·



### · removal. The .**indue~)(~** 

## diaft fan, located**~s~** 

### of the baghouses, moves the Combustion gas 

### througli the 

### system and 

### axhausts the gas 

### through the main 

## siack. .



# .. . 

## s 

# ..

VES 003893\ 

### • Caroon injection system • Fabri c filter baghouse • Solids an d a sb removal system s • 1D fan and s tac k 

### •**~tation,** 

### conlro ls, and 

### data acquisition systems Various s olid and 

### liquid wastes are thtrmally treated in 

### the rotary lciln 

### incinerator. Solid wastes are 

### fed to a ram f eed er via a c lamsbeD, a drum feed 

### conveyor, and an auxili ary feed 

### conveyor . A 

### hydraulic ram pushes the solid 

### waste int o the kiln. Liquid waste fr om 

### tank s and 

### tanker lr)lcks 

### is fed to 

## the primlu'y and 

### secon dary co mbustio n chambers through aiA)mized 

### liquid inj ectors. Combustion chamber temperatures 

### are maintained 

### using nalmal gas 

### fired 

### t? a dedicated .burner in both the primary and 

### secondary cham ben. 

### Coni.bustion gas exitB the secondary combustion 

### chamber and 

### enters the 

### tempering chambe\', which provides cooling of the combustion 

### gases. The

### com~ustioo giiS ex:i1s

### ~ tempering chamber and is 

### dislnlmtcd between two identi cal sPAs, 

### which provide. acid ·. , : , · gas 

### J;eDlOval 

### ani! additi onal gas 

### cooling. A carbon**inj~Oll** system 

### is . uti.lizeii.: for 

### ·.: : .:_.-: · :' cootrolling mox:iri!J\lran and mercury 

### ClllisSlon.. The 

### activated caroon is 

### a ir' injected 

### int o

# ~ . the

# conibusti~ gas immedi'!'ely downs1ream o f the

# conv~ence of combustion 

### gases \... ' ftUm the SDA&. From the SD.A:s,

### combu.~on gas 

### i s mstxibntcd 

### to fabric fillca"

### bagbou~,

. · · :whi ch . provid e 

### particulat e matter . 

### remo:"at 'The ID fan, lcx:ated 

### doWllStream of the · · bagbooses, moves 

### the combustion gas 

### througb the system .and exhausts the 

### ll!"' through the main 

### stack .


## . .

6 · 

## . . VES 003894

## < m (/) 0 0 

### w CD 

# "' 0>**~** 

# ,. ..**.1** 

# '

# '~~~· <;· . · '

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## .. . ;,• , • 

### ..,- , _ ' ·. 

# . ' 'V · . . . t. ,.,/ ' 

### · Table l- 2 ' 

### CMS 

### Iilstrument SpeCifications 

## - ApplkaU on · 

# . . · II Iiltrument · I Ta& Number 

### I Manuf acturer · Mode l UPIINo.l 

## .. High BTU 

### UqQid**Feed~Uo .**  ·. 

### Maui'!owme!c< PT-2 1 5 MkloMotion 0405-SS Hlgh 

## BTU Ucjui d**~ liVectW~**  SO&lo . • Wf-2 1 501 WeisJ>,Twni• W I • . I JO Fee<lr&lo 

## ... Low BTu UqWd Feedroto ' · 

### MUI Plowme!or Fr-216 MlcroModon D 4 0S..SS Low BTU UcjuidOirectlojec!ion Scal e WT-21501 Woiah- Tronix WI-.130 Feccble Specialty Feed Weight**~- Wc;,h~~**  Wf-204 Toledo . 814 0BXP Drummed Solids Peed Wolpt . Wolfh Scale WT-210 Toledo Al40


# ..**~** Gu Peidrlte 

### di> 

# een FT-21 7 Yolo:lgawa YAIIF**PCCT~** T»>•K TT-lO OAIB . Modieon 8883-2 00

. • UDic 

## sec Tempcrataro TypOK . 'l'b«mo<cul>ic TT·219 AIB Modicon 8883-2 00 PCC Prcoourc Preoa1ue PT-200 Rosemom IISIDP BSY POliti on· · Pc»ition Switch ZS-22 4 Sqoare-D 9007CG2 Bl Baabowoe Inlet**Tomp~ ture**  

### TypO 

### X. TT-270 Modicon 833-200 CombuldoD 0.. Plow RallO dPCcD ·· PT.liJ 

### 1\oa..,.,unt ll SID R St&cJ< Ou**Oxygc:>Co~** . 

## z.m:om- Oxide AT-lS9 COSA ZPN-llYAl·lZ l 

### AMI.Z.. S'ta<:k Gu Car bo n M ono xkiO Conoentmion Multico.,.,.,.zu Slack HJidroi"" Chloride ID!iaml AT-28&1! EooChem MC3 i Coi:IO<llltiUol!**p~** 

### I Sta<:k Ou Moimr• CoDCODiradoo

Limo SIU!tY Plow Rate I Mag.P!oWIIlller PT-288 Fllc:hcr & Porter !OD 1 4 75 Limo Shury Density De!Wt;y AT-*8 Sola:tron Mobtey 7846 r-sduc«

.. •.



# ·.

# :-:**:iii·:::.:i_}: :}** **_':}~ ~;:.,;:** **\** 7 

### . .. 

## -. . Operatlni R••&• 

### I Locotlon

0.3,600 lblhr Feed Line 0-60,000 lb Feed Line 0.3,600 lblbr Feed L i ne 0.60,000 lb Feed Lin e ().4,000 lb**~** 204 Spce ioll y Foe<ler 0-400 lb S olid Charge Conv eyor 0.10 in.

### "'i~i Cylinder Gas 10 -60 lblmin FcedS VI!Cm

0-2 500 •f Primary Cham ber 0-2500 ' F Sccoodary Ch amber

- 7 . 5 to 2.5 in. w.c . Pnmary Cha mber open/ c lose Em ergency StacJ< 0-2500 'I'**SD AOu~et**  0- 2 0,000 acfm St&O t 0-lS% CEMS Buildin2 0.200 I 0- 3000 ppmv CE MS 0.1000 ppm• Buiklillg ' 0-60% 0 - IOOPM SOA Pe n thouse ' 0 - 100 L bll'r' SDA Pen t house ·

## < m (/) 0 0 

### w 0:> <0**~** 

# , -... '. 

# . . \ : 

# .... . : 

## . 

# ...**~** ,. . . 1 . . .**~**
. .**~-** ' . TAble**1~2(eontftiued)**

# , 

# . ' .. : : i lzgi 2: ·: :: CMS Ins trument Specifications 

## I Appllea tlon . · ·.' / · .'·\·**(. ;s** **l'g,tr~l** 

## . .. - 

# r'l'll c R.imb--.riManucOotOrer 

# r Unit NO., . . .. 

## _ --

,. . t . :: > .\

.**:/: -.** **~: >:** **·. :**  

## ....**~. F.,:**  .•.**~- -.**  · · • Hl&hBnl**Llquld~~ <'** **':· -:** **·** 

## I**~w FlOWJ~~Cte<**  I Yr-315 I Micro Motion

### Hi&hB'lVLlqllfdDiiecfliljoOtr~**:~·s~ <**  · .: · 

### 1 WT-315 DI 

### 1 Woigh-Tronix Feedlale . . : .' . • .. · :. ·. · .. ,**Lo BTU** **Liquld P~**  , .. 

## : I MOHP!owmoter I Yr-316 

### I MieroMotien

## ~~**LlqUld-Plroc!~~~~~** 

# I**~~~~ :.:·**  

# . . 1 WT-315 Dl I W e!gh -Tronix

### s~ Fe<!! Wolcht , · .:· . . . 

## . •'· 

### . . ...**V{ei,b~~ ~SOuclaP~~~** **.** 

## . . 

## - - · ·- .**w;iiJ,~;** 

# ·. 

# .-. 

# . . .

### PCCTcmpeta**~** •

### :;~**,..** . ' ·

### ~J.o',**·** 

# 1 · ·

# r~·K..' 

# ·

. . . K . . 

# sccr_.,..ur . · · ·**~· :**  

# · .**~le** FCCPnasure 

# .. . : ; ._ 

# ,. 

# ... . .

. .: 

# .. 

# . .

. 

### ltv Pooitio•

## -~ 

# >- > ; .. ·**.f' ~q.!tis+** **~** 

# . . . · , . . : l l)poK:. .. . . ·**B~I!>i ~I** **T~~ .'.**  :, , ; 'I'DOmiO&Unlc Combuat!on Ou Flb'!l'**~** - :; · : '. 

## 'J. 4P Cell ' '· ..

## sta:~c**a.; ~~~~~;~** **T~~c:" Stao!<O..~~**  

### .. ..- CoaoenlratiQII ' . : . '·

### Multi~~**S~Hy<liOiOD Chloiidi** **.:· :**  . .

· . '**.** .**~entl)doh** . · · · ,: .. . ; · · · Pbot01lj$r Slick 

## ou Mollt=**'CO~oti** 

### · , .. . , Lime 

### ShaY**Plow~·** .. Limo S,IUny DOO»it,- ••



# . .. . .. ,**MW.~~><** : I 

### Xleasllif**~** 

# . . . ..



# . .**~** 

# ,:**~~ ;.,i,'** **;** 

# F ;: . WT-304 Toledo · WT - 310 Toledo TT-300Aill Modi""" TT·319Aill Modioon



## Pr-300 RD<emouill ZS-324 SqowW> TT-370 

### M<!dieon

. FT-383 Rosemount

AT-389 COSA AT·388B EcoChom

FT-388 F"lid>or & Porter AT-969 . So1utron Mobroy



## a · Model DS-040 WI -13 0 DS-040 WI - 130 AI40BXP

Al40 883-200 883-200 midF 9007CGlB2

833-200 11 5 1 DR ZI'N·IIYA1·2ZI MC3 1001475

7 846 

### , -· ·
Oporatln& Rance 

## I Location

0-3,600 lblbr I Feed Line G-60,000 1b I Feed Line G-3,600 lblbr I Feed L in e ().60,000 lb I F eed Line 0-2 ,00 0 lb 0-400 lb 0

- 2500 •p 0-2500 • p

- 1 . 5 to2.S ill. w .e . open/elo,. '().2500 •p ().20,000 aoftn ().25% 1). 200 / 1).3000 ppmv 0.1000 ppmv 1).60% 0 - IOGPM 0 - 100 

### LbiFt' ;;304 Hooded Feeder Solid Cbar1•

Coa ve yor Primary Chamber Secondary Chamber Feed Line Emer;ene y Stack SDAOutlet Stack CEMS Bu il ding CEMS B u i ld ing SDA Penthowe $0APon th01Ue

## < rn U> 0 0 

### w CD <D 

# .... . -C"""\ • .**~** .• .**~** ... : r:: . . : d .. . ., ••**.-:~:::.'~\** • • :: • 

## •**~~·** 

## t-. ... ,. , : •. .:. •**~** 

## ... . - . , .. . : , I , . 

# ; ' : ' \**··'?{~': ~·;j>~:**  

# ..**/·.~_.,** 

# .:. : >**'<·.~·)··** 

### · . . ...**~: :**  

### .· \: .... . , Application 

## J**Initr J~Mnl**  · UDIINo. 4 

## . ..
. ' 

## . .. Wute Fooclnte oo X -IO . Nocz!e**Ma..~** Wute Peodrato to X-ll ' Nozzlo Mut Plowmote: Wasco Focdra co to 

## x.u NozziO MaiaF!owmoter Wute Poodnto 

### tO X-22 Noz:z l e Mus Ftowmet« Oam Sholl Peed WeiJhs · Load Cell (shuddcclaolids) Dram CoDve)'Or Solids Wetcht Load Cell AwciliAry Co nveyor Solids LoadCoU WoJaht PCC 1'cq>entme Pyromoter S CC Temper ature TypeR le PCCP-. 

## I !,..1\UO 'l'raDimlller**~** VCIIII P..mion Porl ticm SwliOh TR V Porltion P osition S)lritcb
I Cl:bonPudnte Peocler 

## .. ' Cari>oD IzUootion Ca:rier Ou**Supp ly~** **.** l':<s111n> Swltcb Carbon F eedw Discharge PxemiJo PI'OII\It$ Switch

" 

## .



# . . 

# .**~:-**



# ..

. · 

## , 

# ... ,. '• 

## .**\· :**  

## .. ·

. . .

· 

# •.. .- -. ·" Tabl e 

## i**eo)Jiin~ed )**  

### CMS Itutrument Specifications 

# - Ta& Number 

## I Manufactur'tr 

## I Model OporotJne Rang• 

## I Loea tion PT-129 Mien> Motion DS IOOS IU 0-7,000 lbih< Fted Une PT-1 3 8 Mien> Motion DIOOS · HY 0 · 6,000 lbih< Feed Line PT· 1 4 5 Mioro Moti o n D L! OOS- SS 0..8 , 000 lbibr Feed Line PT-212 Mioro Motion D ID OOS..SS 0-1 ,00 0 l

blhr Fe e d Line WT.OOI Toledo 81 40 0.2,000 lb Ram Feed Hopper WT..014A Toledo 8140 0-1,000 lb Drum Conve x.2r WT-14 8 · Tole do 814 0 0.200 lb Auxiliary Conv eyor TT-30SAIB beon Mcx\Hne4 44 - 99·P· ().3 , 000 ., Kiln**~Uet** J.().J TT-317AIB C..ssel 35 10 0·3,000 'F 

### sec Ou tle t

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### 9007 00282 openloloa e E<n<raency Staek C-17 K-Tto n K2U5 0- 1 00 C a t bO I\ l n jee 1 . System PS1A38A 

## Dwyer 333 0 Trip Points: Carbon ± Sin. w . e. InJection Line Trip Pointl: ca r bon PSH-438B Dwyer 3215 < 3 

### p.siJ l nj oct i on Li ne > 1 3 P>ig

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## au Carbon 

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# . 

# , operating parameter measurement devices at the Veolia facility are installed in compliance wi01 

# l . this requirement. 

### A description of the types 

### of 

### CMS instrumentation follows: Mass/Feedrate Monitors : .Liquid waste feedr.lles from tank s 

### are**m~ured** b y 

### coriolis mass flowmeters. Direct inject liquid feedrates from tanker truck 

### are calculated using the continuously monitored weight of the tanker . All solid waste charges 

### are weighed using 

### a scalelload cell prior to being feed to the incinerator. These m=urerileots are 

### used to calculate pumpable waste, total waste, and 

### constituent feedrates. For Unit 4, 

### the output of 

### a cabl>rated feeder 

### is uti lized · to**calc~ e**  

### the feedrate of 

### powdered activated 

### carbon, wruch 

### is injected into the plemnn 

### upstream of the 

### bnghouses . Pressure/Differe n tia l P ressu r e Mo nitors:**~** 

### combustion cham ber pressure is measured by diaphragm actuated pressure transmitters. The position. of the dm!per 

### immediately upstream of tbe 

### ID fan 

### is v aried to 

### cOntro l stack gas flowrate 

### and to maintain 

### laln combustion chaplber

..

negative pressure (draft) . 

# The prlznary

## coinb~on cbaniber

## J)~ is 

### inter l ocked 

### with-



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### in the

# CY.**~de;r** gas

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### a feedrate. 

## \. , . .. L · . ' The feedra te is used 

### to calcuJate this 

### feedstieam's.

### ~tributiOn to 

### the chiOJine , 

### low volatile metals; 81!.d 

### semivolati!e 

### meWs feedrates 

### to 

## tbC inciDerator . · . · 

### For Unit 4, 

### preSsure

### ~tches are 

## utiiizCd to

### C:nsur~**th e**  carbon feeder discharge pressure, 

## aDd the carbon injeetion ' 

### air blower discharge pressure an; 

## V(itbin tlie 

### design 

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### ouilet is 

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# • · ... . , , · theimoCOOples**med'fo~ t~** **coilti:olandmoniiciring ~the** **~gbouse inlet'** **tempeca~** . ; . : . . • . . • . . . . • • • ' . • . . . : '· :t . .. ·,· . . .**~** . :. ... 

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# . . · 

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### n VES 003899

### Emergency S2 fety Yeo t Po.sitioo Mooilors : 

### The position of the 

### emergen cy safety vent (ESV) ( is indica ted 

### as open or 

### closed by a position transminer. No waste or 

### fuel can 

## bt fed 

### if th e 

### ESV positio n i s "open" . The Emergency S afety Vent (ESV) Plan provides d eta i l s on the ESV sys tem s. 

## B

•e Leak D e tection Sys te m: A triboelectric sensor is 

### locat ed doWJJstreiun of the ID fan and monitors the relative particulate matter l oading of the com bustion gas 

### exiting th e bag bouses . Alanns and interlocks based on this re l ative measurement are indi cations of a potent ia

l bag I calc 

### or faihrre. 

### Procedures for 

### setUp and 

### adjustments to the bag leak detection system are not 

### cov ered by this QC program . The Operation md 

### Maintenance Plan provides 

### details on the bag leak detection system. Co ntiaaous Emissions Moaito rbo g System: The 

### CEMS Cootinuously samples 

### and analyz.c:s stack 

### gas for the coocemrations of carbo n monoxide (CO), Hydrogen Chloride (HCl) , and



### . moisture usiDg a

### ~ticomponent 

### i.nftved photometer. )he 

### oxygen concentration is analyzed

.

### imnltaneously using a zirconium . oxid e anlllyzer: These data 

### are used to calculate lhc stack gas · CO cocqcentration on a dry 

### basis, corr ec ted, to 7% 

### 0. . The ,CEMS 

### QA Plan provid eS 

### additional · ·· · . :· : · . details on · the 

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