' . . . .. . . . . .._ ; 

.· .. . . . . · • 

.. . · .. ·' .· • ... · . ·.;.· . ,\ .· . 

ERC~R~ RA~ ~~ ~$ 'T~· ol~~: X.~ ~lit~ . . 

J • 

Pef'lonnel 

. . :· 

. . 

,. .·. 

. l '. ... . : . .• . - ' - . •; , ', 1 L • • I ,, • , • ', • I ' , 

.: .. 

... 

'· 

.. 

. ' 

) 

. ·. 

VES 003800 
-.. .. ... .. ·. ~· . .· : ..... .. .. \ '..; .: ··~ ~: . ·.· 

··.· ' . . : - :· ' . . :. -~i: . 

. .. . . ·. . . . . .. :: ::. .. · , . . . .. . . . . . ' . . . .. . ' .. _., : : .. . · . 

'· . ·.·. ·.: .. ::.' :.· ~ ... .. 

. LEAD NITRATE SPIKE BAGs - Taqjel ~ is"i>ouni!S-~ ---

)crew P..-s..,.;,~· . . . ' . . '·, .. a~ .,.----'"--_;_ 

·. 

Shift.._. ____ _ 

; Sc:ale ~ ..;._~- - . ·" . ' ·.· .... · ' • • • : t . 

. . - ~ ' .!- • .·' • ( • • • • ••• 

' ... . 

.... .· 

. 

.. •. 

•.• 

.. 

. , 

·. 

: :_. ... · . 

.. . · .. 

' ... ., 

.. . . . ;, ~ ·.· 

. ' 

_. '• 

·' 

. 

., 

.. .. 

•. 

. •,. 

.. . ·' 

: ... ~ i. ' .. 

..... ; •' \• .. ··. 

· .. 

· . 

, .. ' . 

_., 

-· 

: 

~ 

:-

. 

·: 

'\ .. 

.· . 

I, . .,.· . 

. .. . .. ~ 

.. .... , 

· . 

···. 

i 

.. 

·. 

' . 

. . · . 

. ·. 

.. 

. .... 

. .. 

.· 

., 

., 

' 

i 

VES 003801 
. . 

' • : ... 

., . : .. . , :· . . . . · . .. .. . . . 

.· . .. . . ..... · . ... .. 

... . . . .: . . •. . . •• ••• & • • • • •• • .• 

: . • . 

,1, • • 

.. . . ·.. . . . . . ·· .. ' ·: · .. . . . .. .. .. 

.. ' .. • • H~cH pRbETHAN~ sl>ti(~ a~Gs. ~W~~ x.X ~i.ds . ·. oat" _ ___ _ 

. . 

' . . . . . . . . . . . .. . . . . . : . · · · crfwP~rsonnef : ·,·_. · · · . · .. · .: . · ._- 1 •• •• • ~ :: :. ..,~-.......... ~.._,.;...· ..... ,_ .. . . ' .. 

. . . _·:_ .. . ; : 

. ·. . . . . . ;· _;_ . . ... ·. ·. . ·. . . . .·: . . . :· . . . .. 

. .. . I · . .. . ' ·. - -. :. 

' ' . : 

. . .. . .... , . . : . . . . :· ·. : .. 0 : • : : : .. 

:· ... · . [ .-_ . . ' . ... : ; . . ... ·: · . __,_. .. ·. . :. . •·. . . . . . ·:_:·· . 

.. . . . . 

,. . . .. ·. 

.... . ·:. . • . . 

--~----~--~----+----+~-- --~----~ 

. 

. 

I· . . . 

. . -' . 

:. 

--; . . 

. 

. . 

. . .. . . . 

. . 

. . .. . 

.· 

VES 003802 
·-.. CHROMIC ACID SPIKE FEED- Target Rale: X.X pounds/hoor ) . - . ·' Incinerator No. Test~ __ _ ·. O~e _ _ _ ______ _ 

0~~-----------

.. . ·-- ·, ,- - - -- -- . . - . - . . . • ' _-· • • • t- _, •• _ • - ' . ' - 1. ·' • .' • 

c •. - 1 • · . . • • • • · c · _ ' ' l l I, _ 

>. 

,. 

VES 003803 
... , .. ''\. -

· . .. ·. : . . · .. • ··-... :.· .. 

·. . . . . ... .. . . .. . · . . · . .· .... . . . . · . .. . : .· .· . .. .. . . ... . . ·: . .· . ·. ·: ~. 

.• , SQLIO FEED CHAAGES'-:farvei Rat~; 40 ~ _... . . .·· . ·o..·_ ---'--'-·:._ . ·- -.,-. -.. -· ...: _· .. ) Incinerator No. · . ~es! ~ . . Opetalor ___ _ _ _ _ 

; 

: . ... ... . . .. . . 

. . . •. --; .. I· . _.:, . . · · . 

I· . -:- .• 

·. . T·. · ..... ·. I · '.·: . . . .. I . • . .. . , ... "• 

: . . . .: ~ . . -;- \. 

. ' : . . . . . , " . ·. . . . . · . . .. · .. .. _; . : .. . .. . .. · .. 

I · . . '· . · .. i ... .... ... : . . -. . ·.. . · .

' . . . . -::-_ . 

. ·. . 1- .. . · . . .. ' · . . .. . 

I 

. . . . . . --;- . . . . . . . 'CC I· .. -: . .. -:- _ 

' 

•. . . . . . . . 

.. . · . 

.. · . · ... . . : 

. : 

. ·. . . .. I .' . 1-

.. . 

r .. , · .. 

VES 003804 
ENSR 

( : 

Appendix B · 

Reference Method Field Data and Calculations 

C

. 

"\ 

. ' 

~· .. . . . 

l '· •' 

VES 003805 
( 

Field Sheets and CalculationS 

C .. . -' 

.. '· 

- ----- . . 

... -·---. - - -- -·4 ------ . -· ·--. ----·--

( 

.. 

• ... 

,. 

~ 

' t 

VES 003806 
( · 

Rut No. 

~llme . 

StcpTrne 

Noizle, 

Veolla ES Technical Solutions 

Incinerator t4 

Method 29 Parameters 

1 2 3 

~ ~<"--+-~-"7' ==---!·-····-······ 

Unlls 15:37 ~ ~ AYGS 

~ ~ · ~;~ ~:.~ 

CO. %cay 5.00 5.00 .00 i.OO · 

0. . %dry 12.27 12.13 11.63 12.01 

CO+N, %cay 82.73 82.87 83.37 82

lliY ~ i C-. 

Inc Ill 48.0 

SCI 1809.6 1809.6 11 .6 11 .6 

. ' ' 

: . 

. ' 

~ .. ·, ' 

. . . 

. . 

-~ -- -· .. ······--· ... _ . .. ... .. - . ... ·---·-.. ·-· ... .. . ______ .. 

VES 003807 
< m 

C/l 

§ 

0> 

~ 

tr.'-

\ ·.· .. •

~ . ,: r"\ 

Method 29 "· 

RUN I A VGS •• METALS "I C.' I ::pI o:"M I= I o.bH I': 

' ./ 

Pa111mete111 

,.... RUNl AVGS - 1 

SORT I OQt I OOM 

Delli P IN OUT 

RUN3 

"""" STAQC I O.h, I 80RT I DOM I DCM 

TEMP o.b P IH OUT 

a. .. H ST.O.C:K 

,..... II 0.62 0.78H 81 81 UO 388 0.8 1 0.71110 82 13 UO :lee 0.056 O.toe2 83 82 1.19 384 

. 1 o.e:.z o.7Uf 12 st u o 381 o,M 0.7837 83 · 12 uo 317 0.10 o.a3e1 "" 82 2.03 * 

02 0.68 0.82A8 68 82 2.00 393 0 .65 0.8082 85 82 1.90 317 0.63 0.1937 87 63 1.63 383 

a:z o.10 o.1357 ee 12 2.00 392 0.64 01JCIC)) ae u uo ,., o.ee o.&t2A u a.c 1.t1 3t3 

113 0.69 o.e3or 87 83 2.oo 391 o.73 o.se•• se e2 2.10 388 o.ee o.&124 oo as 1.Dt 3D2 

o3 OS U307 68 83 2.00 391 CU7 0.8185 tl1 83 1.90 319 0.88 (1,812.<1 80 115 1.111 303 

.. o.68 o.u46 ell .. z.oo 383 ue 0.8307 &7 83 2.00 391 o... o.aooo 92 s1 1.88 394 

.. 0.11 0.6428 68 14 2.10 381 0.71 0.6428 81 83 2.10 3e1 0.111 0.812.<1 e2 81 1.81 384 

.. 0.86 0.812A 88 14 1.90 389 0.$7 0.8185 87 83 uo 368 0.82 0.7814 92 81 1.80 383 

.. 0.80 0.7748 88 14 1.70 390 0.67 0.8115 87 83 UO 368 0.85 0.8002 92 81 1.89 S93 

.. us o.a108 ell 85 1.ao 3IS o.oo 0.1011 68 14 uo 311 o.es 0.8082 os 68 1.00 m 

.e o .. 44 o.G633 ea 85 1...... .._ ... . .. .. ........ ..... ~ • ,,,.. ...... ... . . --·.. -.. .... ·- ... 

•1 I o.as I o.mr I as I 85 I 1.0 •.IOS2 

~1 I 0.84 I o.aooo I M I M I 1.90 I 391 0.62 I 0.7874 "' I 0.83 St37 

.. I O.M I U124 I II I 85 I 1.90 I 3M I o.M I o.8124 87_ 1 __ !_.@0 __ 319 I OM 0.8000 ~ _18_ _I.M 

., I o.eo I o.aoo1 o.81 I o.al85 IS 1.90 10 M OJ 1.8185 114 1.84 

-

3114 

.. I o.70 I 0.1381 I o.es I o.a1 I& 1.90 n ).8307 05 2.1 '" .. I o.ae I om<e 0.68 I 0.62« 2.00 1.8000 94 1J ~ 

.. I o.ra I o.eeao I oo I eo I 2.20 I >ts o.6o I 0.8307 68 15 I 2.00 liM 0.8115 93 60 1.114 302 

.. I o.70 I o.8387 I oo I ae I z.oo J ~ 0.74 J 0~ 68 H I 2.10 _ 3114 I o.85 I o.aoez 03 at 1.811 ~ 

.. [ 0.63 [ 0.783'7 I D1 I 87 . I 1,60 [ 39 I o.12 I _o.1_a1• 18 a• I 1.10 360 i 0,85 L O.eot\2 1M 90 1.89 . 397 

.. I O.M' I o.&ou I t l I 87 I 1JIO I 311 I o.or I o.e1&s 80 eo .Luo 388 I om J . o.,.,. 1M 80 1.110 :194 

.. I iu7 I o.liM- 1 Dil -l 67 I 1 . .0 1-se l o.« -1 0.8633 18 86 I uo 379 I o.12 J o.1a1• 1M 90 uo 303 

. . . 
< m 

(J) 

§ 

~ <0 

rENSR ·j AECOM 

-· 

"'*dl> 

"'"'""! 

~V) 

-(Zo) 

·-•• 

..!!.!... 

0.00 

....!&. 

0.00 

Giiii 

Giiii 

'"""' .. 

lU2 • 

0.00 

.... 

0.00 

.... 

11 

Multi-Metals Blaak Con'tdiool 

fllONTRAU' 

1v-: - <-> Is.::* "'" 

-

--

1,71 

IUJ 

1:1.71 - 1:3.11 - lUI -

ProtlliWt 

-... 

.... o:w 

0.00 

... 

.... 

aoo 

....... .. 

0,1 

4LO!! 

o.oo 

0.00 

lfP'HB. ~ 0 .. 11.11,. ._.,...,...,..__. 

II PHD'" 1,3.'18 11 • .-. UMblfalaofU.'ll PI« the ..... ...tucbdw«a nrBor .S~ofFHS . 

•·• w~ .. u.t fbrtlld:cotndl• (I.) • biMO C. I J.J4 • tn, ft'Jelr tiu 

_..., 

·-

FllOifT IIAU' 

BAO<IIAU' 

MUICVltY : 

.., ... , ,.., ... 

II tB .. ~ bu1 ~ ji.tlbtAI '* 0. fiB ¥tlllo to C'Cifn(t 

Jf FBill:>fN'*-a.,..-ot .... 6HotJKolfM 

.... ..., .... .... .... ..... 

( ) Nell n.oaw /llcponlb1c Dollc:Uia Undl .~~diet.-....... ., ......... 

""""' .. 

""" -2!:!?-

aoo 

.... 

IUCICBALI 

,.,._ I "'". v .... S..pk 

... .. 

1.00 

.l:2t 

1.00 

i.cif 

-

-

~ 

-

-

-"'~ "' 

.f,OO 

o.oo I tJ 

o.oo I "' I !: 1 ::1 rr8H9D)(I• • t N:6M•IkBRI.,...~a~ 

JIOKBit,.l H•lboi"*«OIIIIilwiN;otS%of8R 

( )NotO.......S ~0•-*•Liadc 

CLJVIT: v..u. rs Todtalatl Solvlloo• 

PROGJIAM: 011114 

RUN NO. Rl 

.... r · I';"· 

~ 
c·· 

I§ 

~ i I ~~~~~~ 13 

1• 

IH· 1~ I •I• I• 

~ 

~ 

IH= 

1::; 

; 

• 

l ~~,. 

' I ~ j 

H ;; "' ~ 

... 8~ ~ ' 

H ~ 

,. 

:1 

·' 

!.! I • • ,f "2 ... 

• 01 I"~~ > :::> 

;i I r!i. -' 6 J j ~ d J:: 

~· ~ ;z: 

..... ! 0 1§ 

n f "' ""' ~ 

11 1~1! 

l· " 

a 

IHI 1 al · 

1·1· 

I• 

i 

Iii· ~~~~~~ 

.. ~ I• I• 

~: 13 9 

J: 1~1 • 

~ 

J I] 

li 

~ 

u ~ " ~ ~ 

~ u 

ill J 

~ )i m ~ 

I J 

u !j .II !i -:! 

J ~ 

-· ~ ' • 

~ 8 ~ ~ 

- 1 

* !t g ~~ f:! ~ ~ 

~; 

Jii ~ 

t! 

, . 

r( fj ;.\ 

I · ~ .e . liJI ! .,. a• !.! JJ ! l j It 

F ' ~ i d 

,; 1 J! .. . f I g ~~ 

u ..... 

ff 

,. .. ; "'"' .. 

: 

VES 003810 
( 

~~~ I~ ~1~ 1~ 

J l 

ol .. 

~~~~~~~Ill lo 

'"I" 

IH· •1·1 ~ l!l~ ·I~ 

f o 

~ 

g 

111; ~ I§ 

I· I• I· 

~! . ~ 

I 

... 

! 

n l 

at 'i! 

g ~ !-

:1 

!lj- J • ... •l ,. .. I 2 ll .. > g;~ 

J'll ll i 

!J l 

t I J .. I 0 l::! l! 

~ t;: c5 z .... !IJ!!! I ~ 1:~ 

~ { · . . z 

"--' LLl 

t~ :0 I" 

II : ~ I !l~l~l· 

~ 

IH= I I~ 

1

'la 

I' 

I 

IU= :;; I ::<1::<1 ~~~~ 

,_ 

~ I• I· 

~ ~ 

t~ ~~~ 

I! 

i 

1-. 

J 

PI~ 

tl/!1 If 

-, 

~ 

H 

'll 

~ ~ ~ ,.

fl JI 

t -1 - 1f 2 .g 

J ! 

.. ~ ;:; !I 

l 3 -· 

• 

~~ 8 ~ ! l 

- IE 

·-s h 

4€ ~ 

~ ~ s. ~~ I i: '. •l t 

lfJ !~ ~ a .~ .. I ; 8 Jl · H 1 ::! a 

r ! ~ ~ "• l ~ lt 

.0 A 

~ ~ ~ t:t 

u .... 

ee 

""' . ,, 

VES 003811 
( . 

0 '<)·· . - . 

f") • .·. '-· I 

tr. t· - .... . . 

- . ' · 

~~~~~~~~~~~-~ -

ol 

.· 

VES 003812 
·' -.. .. · . 

. ' j 

-. ~ ~14-'J; 

. ~~lli!JJ~ 

- .C) I 

VES003813 
c· .. ;·)·· .. 

f 

' 

VES 003814 
( 

' J 

ENSR AECOM 

SAMPLE TRAIN MOISTURE RECOVERY DATA SH~ 

1/ :Traia: 1)?.29 - mehds 1./, .q. 

l by t -:r: c. 1lr1 t :r;r Illy : J on 

lbo!v.. I D*: BOI I. I,__ cl _,,~ ..... 3 llMe : • $,-a '-6 

Y•n .. ..O..'tNe. : "''" XAD ,; H/11 XAD Mocllllol'lo.: ..J /II 

.-~v... cros,so:a . , : llA"> .. O~ 

r NA: . - VOiumo -~-

,_ _,.., =: ~ = No. .==:~ No. ~ ~ ~ ·- ·- ·- --· . 1 50 1110 1 so 1110 1 50 1145 

() 2 IOO 1:¥> 2 JOO 215 2 IOO 23o 

3 Jo·o 115 3 100 t 1·5 3 /00 115 

4 0 I 4 0 I 4 0 2 

5 1o·o 

too 

5 IOO 100 5 loo (00 

- 6 -loo· too 6 too IDO 6 too Joo 

7 .G 7 SG 7 $G ' Iliff' : IliFF: IliFf: T- 4/s-o '" "'" ~ 

' 

¥-so • lt.t.l lzll T- <,tso I I I Z.: I ~"'2-

r:·~el::.:~: '': ·:: ~ F: •)( 

-~: ~?~ ~ ·: ·~ ·-r,L,; DIFF: IliFF: 

+~ _.,.r< 12'1!3 13 Lt~ :J:/!1/i! : ~'1.3-l y.f · ;:-[U1:l z :n'l 1'3-1 

Final Not-Gain: .... ,.... Not....,_ Gain: IZZS. Flnolllet- Gain: tz75.1 Mlilf_T_,......teml•T~ 

c.. ·) 

• 

1' IJ< 

VES 003815 
( 

FacilitY Oxygen Data 

( •... 

·. i; 

... · 

C .. . 

,: 

' 

. t .. ~ 

; . . 

' 

. ' 

. ;; 

,• 

., 

! 

? 

' 

t 

I 

l 

I 

!: 

VES 003816 
( 

{ .: ""-· 

Unit4 

VES 003817 
( 

., ·~ 

{ ; ''· 

.. ..... 

VES 003818 
_______ ..... -

() 

VES 003819 
( 

•. 

(

o· .• 

. , 

. 

VES 003820 
•. 

VES 003821 
( .. 

. 

If'· .. \;../ 

{ ' \,;.. 

VES 003822 
c 

·• 

VES 003823 
' -

( 

( '; 

VES 003824 
( 

· ( : ~/ 

VES 003825 
ENSR \ AECOM 

( 

UNIT4 

(". 

c. 

VES 003826 
( 

Unit4: Run 1 

August 21, 2008 

13:25-15:37 

2-6 Molecular Weight of tM Stack Gas· 

ENSR IAECOM 

M.-= ((5.0lbl1b-mole' 0.44)+(12.27 lblll>-moie'0.32)+(82. 73 1b/1b-mole*0.28)' (1· 

0.390))+18'0.390 

M.= 24.89 lbllb-mOie 

2-7 Average Stack Gas Velocity 

V,= 85.49 ft/sec [((lbllb-mole)(ll Hg))l(~)(ln Hz())))112' (0.84){0.7938) .J 

{(390.5"1=+460)1((29.54 in Hg+0.1357 in Hg)' (24.891b111>-mole)) 

v,-= 61.17 ftlsec • 60 sec/min 

v." 3670 ftlmin 

2-8 Average Stack Gas Dry Volumetric Flow Rate 

a= (1-0.393)(3670 ftlmin)(1B09.6 in2)(1 ~/144 in2)[(52B"R'29.56 in Hg)/(29.92 in 

Hg'(390.5°F+<460))) 

a = 17255 n'lmin 

3-1 Dry Molecular Weight 

M.o = 0.440 (5 %)+0.320(12.27%)+0.280(100{5%+12.27%)) 

M.o = 29.29 lbllb-mole 

4-1 Volume of Water Vapor Condensed 

Vwr~.1114l= 0.04715 n'lml' ((1 110 m\+220 ml+1 15 mf+1 ml+248.9 g)-(250 ml+235.5 g)) 

Vwr~.~= 57.023 ~ 

4-2 Volume of Water Collected In Silica Gel 

V""= ((248.9 9- 235.5 9 (0.06236 mmHg)m'Jgmole)fi<)(293 "1<))/(760 mmg H9)(18.0 

g/gmole)(1.0g/~) 

v-=0.018m 

V._=0.635 ft' 

4-3 Sample Gas Volume 

v.-=1.85 • ((166.894 II'- 76.121 II'-(121.139 II' -121.304 11")(29.54 in Hg +0.1357 

· in Hg)(528~))/(29.92 in Hg' (86.2 °F+460) 

V,_=89.02n' 

~ ,. 

VES 003827 
C· 

{ : "·' 

4-" Moisture Content 

a..:: (57 .023 ft3+0.635 tf)l(57 .023 tf+0.635 tf+89.023 tn 

a,..:: 0.393"100(%) 

S..=39.3% 

5-8 1$oklnetic Variation from Raw Data or Intermediate Values 

ENSR \AECOM 

I= 144in21ft'*4fn"(10<r(390.5°F+460)(89.023 ft1•29.92 in Hg))I((528° R)(3692.7 

ft/min){0.313 int{29.56 in Hg)(120 min)(1-.390)) 

I" 101% 

~1 In-Stack Detection Limits 

A•BfC=D 

A! 

Front-Half 

D"' 0.00013.(30012.52) 

D = 0.016 uglm3 

Baci<-Half 

D = 0.00013.(15012.52) 

D = 0Jl079 uglm3 

Iii! " 

Front-Half 

o = o.oo0033•(300/2.52l 

0 = 0.0040 ug/m3 

BI»CC<-Half 

0 " 0.000033.(15012.52) 

0 = 0.0020 uglm3 

Front-Half 

0 = O.Ooo033"(300/2.52) 

VES 003828 
ENSR I"AECOM 

( 0 = 0.0040 uglm

3 

Back-Half 

D = 0.000033. (15012.52) 

0 ., 0.0020 ug/ ~ 

g 

Front-Half 

0 = 0.0001•(30012.52) 

0 == 0.012 uglm3 

Back-Half 1 

D = 0.0001. (15012.52) 

0 = 0.0060 ug/m3 

~ 

Front-Half 

( D = 0.000067'(30012.52) 

D = 0.0079 uglm3 

Back-Half 

o"' o.000067'(15012.S2) 

D = 0.0040 uglm3 

.1:!9 

Front-Half 

18 

o = o.oooo5•(30012.52) 

D = 0.0060 ug/m~ 

Back-Half 

28 

D = 0.00005*(150012.52) 

l. .. ~:/.0116 

VES 003829 
ENSRIAECOM 

( 0 = 0.030 ug/m3 

> 

3A 

0 = 0.00005"(10012.52) 

.. 

0 = 0.0020 uglm

3 

~ 

38 

0 = 0.0001*(500/2.52) 

0 = 0.020 ug/m3 " I 

3C 

0 = 0.0001*(50012.52) 

0 = 0.0099 ughn3 

29-2 Analytical Fraction 1A, Front-Half, Metals (Except Mercury) 

M.,. =c., Fd v-.• 

( A!. 

Mo. = 0.367"50*0.3 

Mo.= 5.51 ug 

~ 

M., = -0.005*50*0.3 

Mt. = -0.075 ug (NO) 

Cd 

Mt. = 0.049*50*0.3 

Me. = 0.74 ug (NO) .. 

£! 

Me. = 0.229*50*0.3 

Mo.= 37.8 ug 

( 

....... OGOtn'lber 2008 

VES 003830 
( Pb 

M., = 2.275"50"0.3 

M., = 34.125 ug 

29-3 Analytical Fraction 2A, Back-Half, Metals (Except Mercury) 

As 

M..= 0.094'10'0.15 

Mw. c 0.141 ug 

M,.. = .005'10'0 15 

Mbh = -0.0075 ug (NO) 

£!! 

...... = 0.091'10'0.15 

Mw. = 0.137 ug 

c &! 

•• \.: .. 

...... = 0.525'10"0.15 

Mt, = 0.79 ug 

Mt. = 0.385'10'0.15 

Mw. =0.58ug 

29-4 Total Train, Metals (Except Mercury) 

M, = (M,-M,.,) + (Mbh·M-) 

M 

Mt = (5.5-0.68) + (0.10-0.10) 

M, = 4.82 ug 

ENSR IAECOM 

VES 003831 
( 

( 

M1 = (0.25-0.05) + (0.025 - 0.025) 

M, =0.20ug 

Cd 

·M, .. (0.74- 0.05) + (0.137- 0.025) 

M, = 0.802ug 

M, = (3.4 - 0.65) + (0.79 - 0.42) 

M, = 3.12 ug 

f!! 

M, = (34.1 - 0.22) + (0.58- 0.14) 

M,= 34.32ug 

29-S Analytical Fraction 18; Front-Half Mercury 

HQt.= a., Fo v-.. 

Hga, = 3.158 •1•0.3 

Hg,= 0.947 ug 

29-6 Amount of Mercury Collected in Sample Fraction 2 

HQI.n2= 0t.a FoV-.2 

Hgbl\2= 3.90"10•1.5 

HQI.n2 = 58.5 ug 

ENSR IAECOM 

29·7 Back-Half Mercury Values for Analytical Fractions 3A, 38, and 3C 

Hg,., (A.B.Cl = 0 1>113 (A.B,C) F d V ~ (A.B,C) 

Hg,., <"l = 0.675•10'0.1 

H9b113<Al= 0.068 ug 

H91>113(B)= 0.126"1•0.5 

H91>113 t8l = 0.06 ug (NO) 

Hgbl\3 <Cl = 0.357'1•0.5 

HQbll3 (C)= 0.089 ug 

Ooce- 2008 

,. 

g 

VES 003832 
ENSR I AECOM 

01lh3(A,B.C) 

~ = 0:068+0.06+0.089 = 0.217 ug Total Amount of Mercury Collected In the Back-Half of the Sampling Train 

HQI,I = HQoh2 + Hg,.,v. + l-lg111139 + H9bN!C 

H9l>l = 58.5 + 0.068 + 0.06 + 0.089 

Hg.." 58.717 ug 

2:9-9 Total Train Mercury catch 

Hg, " (Hg., - Hgt..) + (Hgw.- Hg,t,.) 

Hg,= (0.947 -0.0075) + (58.717 - 0.175) 

Hg, = 59.48 ug 

29-10 Individual Metal concentratlOM In Stack Gas 

C.=( I<. M,)Nm<sldl 

A! 'C.c (10-3.4.82)/(89.023' 0.2832) 

c.= 0.002 mglm3 

A$ com!!<ted fO!" 7% Oa 

c.= (4.82'35.314'14)1((89.023' (21-12.27) 

C.= 3.07 uglm3 

Be c.= (10''*0.20)1(89.023*0.2832) 

c."' 0.!)001 mglm3 

Be corrected for 7% 0. 

c.c (0.20' 35.314'14)/((89.023'(21-12.27)) 

C.= 0.13 ug/m3 

9! C.= (1~3.12)1(89.023'0.2832) 

C.= 0.00035 mgfm3 

Cd cotTeCted for 7% Oa 

c.= (0.802'35.314'14)/(89.023'(21-1 2.27)) 

C.:= 0.51 ug/m3 

l 

f. 

,. 

~-

VES 003833 
( c." (10~.12V(89.023•o.2832) 

C.= 0.017 mg/!Jil 

Cr correeted for 7"!. Oa 

c,= (3.12*35.314*14)/((89.023"21-12.27)) 

c ... 1 .98 ughn3 . 

f!! c.= (10 ... 34.32)1(89.023*0.2832) 

c.= O.o136 mglrn3 

!!9 C.== (10'3.59.48)1~9.023'0.2832) 

c.== o.0236 mg1rn 

Hg corrected for 7°4 Oz 

c.= (59.48*35.314*14)1((89.023'21-12.27)) 

C.= 37.9ug/m3 

. ENSR I AECOM 

' ' 

; 

VES 003834 
) 

·. 

AppendixC · 

\ 

ENSR 

ReferenCe MethOd Calibrations, Verifications, and Certifications 

\ 

--

I 

I 

VES 003835 
-. 

Refer&nce Method Manual Equipment 

Pretest calibrations; VartftcaUons and Checks 

' . 

' . 

VES 003836 
.. ) 

) 

ENSR IAECOM 

--

-- -·-

-

DRY GAS ME1ER CAIIBRATlON 

l!.P 

..... 

...., .. Mo.: 80503 

- ..... -, ... """ ........ - • ..... k¥,...... 

• UlO 

a.n ,._ ... ...-.: ....... ··-

-"" - DIWGAS _...DAta. 

.. ...... - --- - .... .... .... .. 

!I , ... 

'·"' .. 611.400 ..,..., ...... uo .. ••• 1 ..... 

..... ,_ 

.. ::~~~ ...... 

.... o'l --- -.... • 

• 

' "' ,... • • 

' ... • •• i- 1.-m 

. ... ,.y Uti I 

' --"" -~ 

n 

" 

.. "

-- -~ -,. -· .. , R 

.. .. .. ,. 

-----

, ... 

- 4.t: 

... • __ t.__ O.tS 

I A :a. AMI ua 

.,_ 

·- --- ..... . .... .. .., 

..., 

•• ..,, .. "

.. 

_,. 

,. " 

"'*t: .,_.. ............ N/111111~ ...... , .. .1 ............... """""*'-.............. -... 

-c.-~~1(,.--..... ., ...... -.......t-..... •eo-e. . n...__ ....... .,_.,....._..,.,......,.. ........... ~ 

.. ., ,. ,., 

,._ , n 

n n 

...... ~,_.,., .. ,..., ....... ~~~. ......... _ ... !Wf ............................................ . 

• ,..o.~,..., .......... ~ ................ M,jll ......... o.n • ., ••• ,..., ......... . 

.................. ~ .................... .~. 

... .... "'" -- - ... ... .. ~ • _ ., .. n n .. ~ 

I • 

-.....:; IJ*-•'-" .. -.a• or•. 

:Q,_..._,.,.~ ....... .......-:•M"F ,,._ ............... ____ _..: .. ., 

l ' ,, ....,,. r;; 

-- 1,-. • ... ~ - .. , .... ..... 

~· 

.. 

.· 

VES 003837 
1s]§8 

' 

ywtl p!t9ll Cf' • •lllf QAXA fSWI 

TWI! •a•IJ'O'OT J\.1118 ASIEIB.Y AICJ NOZZU 

........ ---

I 

.. t·Mr"•-.lf•tO'J 

"-' f.WII '" • ta') 

.. (A" II &,£ • f') 

.. ..... , .. .., 

• 

'l • AT.-yC&.t CUW') 

W • Al'lret&•OJIIQI') 

• 

13Bl 

• --- -

-

r 

---

VES 003838 
ENSR IAECOM :· 

. , 

.. ---

• 

) 

. ) 

VES 003839 
ENSR IAECOM 

- - ..,.L- - ... 211 ~ -· ~· 2 

~ .. D • 

LMt 

I""" I .. .. -• 

........ 1 "" ~· I • .1 ... 1 ... ~ . .... • 

I "' I I .. .. I • I ""' I .. .. ; 

.... ... I T • ... I ·~ , .. r , 

~ I • ..... """I .. - I • 

.... ... I ... ~· • ..I u ... • 

10...1 .. "' , ""' I • 

Uol - ,.,; ... '" I 2 ~ .... 1 ... 1 ... "' ' " .. I n I ~I " " , 

lU ... I ... ... • ... I .... ~· "' •• 

= ~I .. .. , Colo! I .. ~ • - ...,.1 .... 1 '" I ... I , i£: ... I ... I _.:t 

'I •. d H I - I • .. I - -, 2 

IE liil I I . I , .. ~· 2 .... I I • """I .. n • 

... - .... I ... ,., I • ...,.1 .... 1 ... I ... , 

•· I , .. I -• 1 ...... 1 w I .. • • 

E :1= : . ....,1 .... 1 ... ... I , 1M .... I ... ... I ' 'I-I .. .. I , I ""' I .. - I ' 

= 1-r""l ~• I '" • .1 .... 1 ... .. . , 

~ • , I ""' I .. .. I 

• , . 

VES 003840 
) 

ENSR I AECOM 

BAROMETER CAIJBRATION DATA FORM 

F.eld Barometer 10#: Serial No. 51111291 

Reference Barometer 10 # : Serial No. 188841 

Pre-Test Calibration data · 

Calibnotion Pe<fcnned By : Ryan Bums 

Dille Reference Barometer Foeld lvnlracy 

in.Ha ln. Ha . ln. Ha 

3-Jon-08 29.16 29.16 ~ +/- 0.10 ln. Hg 

Post-Test Calibration data 

cailtlnllion Perfo<med By: R.Bwns 

I Date I AccuracY ln.Hg I ~ +I· 0.10 in. Hg 

Note: The field barometer Is adjusted to agree with the reference barometer 

alter eam calibration. The refarvnoe barometer is ched<ed and re-<:alibrated 

by the vendor on an annual basis. 

j: 

~ 

VES 003841 
... 

) 

) 

Reference Method Manual Equipment 

Post-Test Calibration CIMH:ks 

' ' 1 

i 

; 

< 

' 

... 

' 

I 

' t 

' . 

VES 003842 
) 

\ 

' 

~:c:ms 522 SW'-....., 8CIC Clfitlrlllion 

___ ,..., .... Orb .__!(', IMiw:ld ...... 

IAiriiO '.9!1' li 

[*"dol@ !!ITA I 

= HGtp '~: • = Nrlltc ht~F'«WY,hl:llloff bfMIII:9d .. ~-IID .. ft:yQIIe...,. 

~......,. ........ ~ .. --~...o.oz. 

.,.. I 

t#Q 

.iii 

f<ll'~c.RatianF.-........................ ~~~~Indrl.flfl-QOI'MII~IID0.15ctr.affW 

aaF•a.tzw-<~.-. ........ ~of~""'*hitl .. ._.ilo..cu. 

.... Cole. 

..... 

R O..W, 

.. .... ,. ..... 

1 • • 

VES 003843 
ENSR 

Appendix D 

Laboratory Data 

(

, , 

. .. ·.= 

\ 

; 

' 

i 

j : 

' I ·. 

i 

t 

. 

VES003844 
c 

~· ' .. . 

. .f ·.;.• 

c . 

Method 29 Results 

i 

~ I 

~ 1 

... 

VES 003845 
( 

M a a~.!!!-----'"-------------'----.;!"~:;-';;.;:.::;;-;;;,'"'~;;;~~6;\i;!;:r.;:;· .. ;:;;.:· 

5015 Ca~Dr 

Suile 104 

EasiS~ NY 

USA 1.~74232 

-F.K.InFIW•-(eo20lA 

Your Project#: 10002-022 

Si18:CPT·VEOUA 

~Date: 2008109103 

This report sypersedeS aD previouS reports wilh the same Maxxam job mmber 

CERJJFJCAII OF ANALVSJS 

{1) TltlltMt..,. perfotmlld b>' ~ANtytic:l" t woe 

(2)-.... -perfotmlld ln-·-·9' --SUrfin!IIOn soc- ·-

·. 

< 

Digitally 

signed by Mike 

Challis 

Date: 

2008.09.03 

16:09:00 

-04'00' 

Total·cover pages: 1 

Paoge I oliO l

'' 

.. Thil doc:lUMf'i. ~ ~ fCim8t twd copy ls availat:l$e G' -..-a. 5665----~~ L71.!iH7 Tot•(005)$0U118 'Toi,_(IOO)_...... Floc(OOS)--

VES 003846 
( ·.·. -..Joblf:~ • Rl!>o<t Dlllr. 2008/oMl3 

MERCURY BY COLD VAPouR M (SAMPUNG TIWN) 

t. J ' 

• A:tp21 ... Dllldan L)nl -·a.tyt:-..-

0.847 

.... ____ .,._._ l1l&Kl' 

1.09 o.ae 

Poilt2ol10 

VES 003847 
M a a~.!f.! -------------------'»;;:·.;;;""";;:Z:~-ii$:;;:;;;':;-i;ciis;:;•_;;:;-· EHSR-onol 

c 

~ 

t,; .• 

"' 

Cion! Plojod 1: 10002-= 

Project nome; CPT·VEOUA 

ELEMEHTS BY ICP/1111$ (So\MPUNG TRAIN) 

~ 

*-CA-l "" 0.88 5.5 &.A 10.S 

.... 8aoyiFbn (llo) ug 10 <ll.fO <l).fO 4fO 

.... c::oo-(Col) ug <11.10 10 0.74 o:rs 1.29 

.... a-NomiC>) "" O.M .30 3.4 4.2 11.3 

Ololl.ood (I'll) 1111 o.22 20 34.1 54.1 4.2 1.0 

- • Rlpoallilitlte DMidon lbl 

- - ~Cci<Oiol-

"" !S.S <0.20 <0.20 G..20 151192158 

"" <0.110 <UI!O <1).0150 om ·-

"" 1.34 

- 0.134 

"' 7.0 Cl.A2 o.n 0.15 

-·-

1-

"" ... ,1.0 15892M .... OS 0.10 ISI!mll 

a RCipOI1IIM OMedlon Ul'lil 

EtCh . (May~ "'*"' 

.... _(Ao) "' <1).20 <0.20 

.... .,...(Do). "" - -

·-

111G82158 

.... Catnkl1l (Cd) "" 0.122 0.051 

.... a-u.~ - ~-

"" OM t .llf5 0..7 158912158 

.... ~11'1>) "" 0.58 Q.25 0.15 0,10 ~- • AcJOellbl8 ~ u-r. 

-·~COr;rclPoge3ofl0 

; . 

" 

.. 

VES 003848 
M a ~~.!T.!------...;_-------~!';;:;;=·;t~ .... 5·~·~z~zm==-: EHSRirololr...,.oal . ' 

(

: .· . -

~ Job ao:A8948116 ~: 2008IIliW3 

(\ ' •' 

( ,: 

-~~ ._.. .. M2H1l Rl 

- -...G'IlWN 

_.,_ 

-ll~fl< --liWH 

_.,_ 

-~~~ ... - SAMPUH9 'IIWN 

-~~ _., -... - SAM'UHG TIWN 

-----..... c::..- U1.1H7 

Pogo4af10 

Clonl Projoct " , (1002.(122 

Pro;tct -: CP'T·VEOI.IA 

• !. 

VES 003849 
(

· ·· . -Jobii:A894896 

· Ripaf!Dolo:200111l8100 

-1)- _ _, ...... 10 ~1BH Sllr,M --11WN -- . 1" ~ 

a= m : 

' - ., NC2I29 Dl.9 ~ 20QIIIII,'IlVl1 1 

_.,..D -..u.RIBH ~ 

- SNoiPIJNO TIWN • - "''M'882f 

-~~~- - D M2&-UO-R3 BH --8111- ---"llWN --

C.; Pogo 5"' 10 

1655 __ ..__"""""',__ L7UH1 T"' -OOU788 Tol----__ _... 

VES 003850 
M a a~ .. ----------- ------~!;;•.;;,.;;•_;; ... =-iis .. ;:;·"'*;...,iil'IJ;';·i;";;_;:. 

~-..- ~ PIOjocl .. 100CXI.o22 ( Pn>jod-a>T·VEOI.I.\ 

MERCURY 1tY COUl VAPOUR M \SAMPUHO "--

loteocoA'; 3C In HO-(M29t.----lowond-...... ~pool""""',_.,.,..,..,--. 

IU!IEIITa IIY ICM8 ~ TIIAIII 

.._.. F .H. irl ..... ~ Rtlaes (8020): AIIUft S:lAIIIon-NqUiNd non .... Ni2924-28 ct._, .. mllr'il ..,..._,....,_...., ___ .,....,..AH292 •. 

-

___ B.H.In~llnp.{OOIIO): , ~...-----... --

·-

Pogo hi \0 

____ _,..,...._,..... Ln.IHJ 

VES 003851 
M a a~.!!!.----------------:-:-:-------;!";;~;;':-~oz;:;;:..,iiii-ii -:i;_,:ii ;ii·i;.';-:;;;- EHSR lrUmationol 

( J 

,... 

\,_.,f 

r.IATR!X I!I'I<E 

Wf292t) 

Wo\TAIX SPI<E Talol~ 

Dtl' (N121129) Talol~ 

S!>bd- T .... """"'Y-38 • --DUP Tolll~ 

--RPO rolll~ T-~ 

1!5M335 FI'S *TJUXSPI<E 

_, 

*T'AIX sPIKE 

TOOOI........,.a 

DUP (Hilti29J Tabl folol<uy-28 

-- T .... Moo<ury-28 

--Dtl' Tolol-.y.3 -- Talol lolonllq-28 

RPO Totollolonllq-28 

1-FI'S tu.miXSPII<E 

1AH2$21) . 

WATAIXSPI<E T<Qf~ 

DUP (Nt2*29j Tabl~ 

-- Tolol--3.'. 

--DUPT"""~ 

-- Oiol~ 

RPO TOiol~ 

fi7~FF8 

..... 

REAG9lT 

miX SPII<I! 

lllAHK Tolll ~ 

-) Tolol Mll<:oq3C 

MAlRIX SI'I><E 

llUP(IIItme) 

-- Totol~ 

TOiol-.y.3(: 

--OUP TOioiMII<:oq3C 

-- Tolol~ 

RPO T*-·3C 1518244 FFS llei.GEH'TBI.NIK Totol-18 .... TNXSN<E 

INI28Z<) TOiol-1& 

MATRIX 61'00! 

OU>c-) T"""-18 

-- T .... -18 

Si>bdBiriDIJP TOiol-18 -·"'* TOiol-18 

RPO T .... -18 

15882SIILR W.TRIXI!I'I<E 

-) TOioi-(As) 

MATRIX SPJI<E OUP~ T""'-IMI -) ... TRIXII'IKE 

Mil miX SPIKE 

T .... 8o<)IQo {lie) 

llUP(.AH292SI) 

... TRIX SPII<E 

TCOII!Iwyllwn (Bo) 

r.IA 

~ TRIX SPI<E 

T .... Codn'Uo (Cell 

llUP (N121129) Oioi~ !Cd) 

-Jelf- Ciont ""''o<t t: 100112.(122 

P.O. t: . ""'iec:c,_ CPT·\IEOUA 

2llOIW08I29 10< 104 

- 103 103 

- ... • - 87.0 81 

- <0.011 

- NC 

2llOoloom 1Ge 1Ge 

- 111 UtA 

2fX1IIIOII7J 100 ItO 

- 100 100 

200110&'27 <Ohl 

200110&'27 " 

200111118128 100 1Cl6 

3'"*?'0! 108 ,.. ~ 108 ... - 107 107 

-

~ 

cO.OOI5 

1.5 

- <0.!125 

- 10.0 1011) 

- 81.0 81(1) 

- 108 108 

20011081211 1011 105 

-

- -

NC 

200Ml8l29 <O.ol5 

- 115 115 

20011081211 ta.o • - 108 1011 

- lOS 1011 

20011081211 <0.015 

20011081211 3.0 

- ..... • 

20011081211 48.0 • 

- .os.s t1 

20011081211 48.0 12 

2008100129 25.0 100 

200M)8I29 23.& liS 

"" 85·115 

"" 16-115 

"" 10·110 

"" . 10-110 

"" ,. 20 

"" 16·115 

'II 16· 115 

"'I 00-110 

"'I 80· 110 

"'I 

,. 20 

"" 16-1t5 

"" 15-115 

"" 8G- t10 

"" 10 - 110 

"" ,. 20 

"" 

"" 815-115 

"'I •· ·u.s 

"" 10. 110 

"" to-110 

"" ,. 20 

"" "" 15-115 

"'I 115 - 115 

"" to-110 

'II 10-110 

"" ,. 20 

"" JO. 130 

"'I JO - 130 

"" I0-1SO 

"" 10 - 190 

uo .,._ 130 

"" 10· 130 

__ .... ____ Pogo7ol10 ,_ ... _ 

MMNorll ..... Ro14 ~ ~ et..a LJL tiH7 ill:~~ Tolrt,_: (IIXJ)tll8o08SII F.: (lOS) 332-81. 

,• 

VES 003852 
( 

~ ( ' 

c 

M a~~!:.!---=-- ---------!;;~~$~ EHSR --oliliollal 

Alleolllon: Jei!Gonnon 

Cllonl Poojoct 1: 10002.()22 

P.O. 1: 

Poojeol-CPT .vEOllA 

i· 

TOIII aw.n.lum (Col 

- 52.5 lOG 'IV 10· t30 

''""~tol 3lOMi8l2!l 411.5 17 1111 10 · 130 

(AK292S) Toall.tod (1'1>) 

- 51.5 lOS .. 10· t30 

W.TNXIIP11<E 

OUP (loH2t2l) T* Lt.! Cl'li) 

- •u • ___ .. 10-130 T'*'-CAo! - 52.0 10< .. • · 115 

--OUP T*-CAo 

- 53.& >08 .. 85-115 

-- '!0111 a.yiUol (llo) 

- 4&.5 • .. 85. 115 

--OOJP r• 8orylln (llo) 

- 50.4 .01 .. 15· 1t.5 

-llook Tolill c.o.-. (<:d) 20- 25.5 1012 "'I 15· 115 

llpl<ed-OUP T'*'~(Cd) 

- 20.$ 1015 1.111 e5 · 11S 

-- T*a-MICCol 

- 115.0 110 1111 N·115 

--OUP T ... a...-(Qj ·- 61.0 101 "'I 1111·115 

-- =L*CI'Io) 

- 52.5 105 .. • · 115 SpiW Bloonk OUP !.*(!'b) 

- 5U 1QI ug • · us 

--- T*-CAo) 

- <0.20 "'I 

--OUPT*-CAol 

- <0.20 "'I 

-- T ... _ .. l - 41.!150 ug 

--OUPT .... IIorylln(llo) 

- 41.ll50 ug 

-- Tolill ~ (Cd) 

- <1).!150 "'I 

--OUP T ... o.rootn (Cd) 

- 41.050 "'I 

-- TOOoi~(Qj 3lOMi8l2!l ~15 ug 

--OUP T*Cion>II'Uol to1 

- o.:ts, A:Ot..JQ.1S ug -- TOioll*(1'1>! 

- 41.10 "'I 

-Biri0UPTOI011.*(1'1> 

- <0.10 "" APO , __ 

""' - )IC "' 20 

T ... loo)an (llo) 

- HC "' 20 

T ... cu.-(Cd) 

- HC "' 20 

, ... a-...(Col 

- 2.1 'l1o 20 

TOioi~CI'Io) 2001101129 u "' 20 

1_1l_R ... TRIXSPI<E 

CAHm41 T--(Ao) 

- 411.5 19 ug 10 - 130 

W.TRIX SPII<E 

OUP-) Toiiii-(Ao) 

- .u • uo 10-130 

W.lRDCSPt<E 

(AH211:14) TOIII 9eo)4l<n (llo) 

- 41.0 • .. 10· 130 

W.TliiXIIP11<E 

DUP-) 

.... TRIXSPI<E 

TCOII-(IIo) 

- 47.5 M "" 10·130 

(N-Im4) TCOII CodmLm (01) 

- 25.3 101 ... 70- 130 

W.TRIX SPII<E 

OUP WQU:Iol) r..., Ca<blom cc.t 

- 26.3 101 ug 70 · 100 

W.TRIX SPIKE 

(AH211:14) 

W.TR»<SPR 

-~(Ql 

- 52.o 10< ... 70- 130 

OUP (AH28al) 

.... moe SPII<I! 

, .... ~(Ct) 

- 30.5 1gl ug 10·130 

(AH211:14) TCOII ~ (1'1>) 

- 5<.0 101 ... 10· t30 

W.TRIX SPto<E 

DUP(AH211:14) ,.,.. Lood Cl'bl - $1.5 101 UQ 70- 130 

-- T*-CAol 

- 49.0 88 uo es. 115 

--DUP T*-CAol 20oeooal03 51.5 103 uo 85- 115 

Pogo 8ol10 l!:jo_lo, ___ ...,,_ .. _ 

..... __ .....__._....,_ UL- Til:--- T .. FJM: (IJOQt .... F..:(UOI)aa.ettl 

VES 003853 
( .'; . 

---

Quality Assulance Report (Continued) 

-Job-~ 

1 ) --.. -~_ .... _ .... 3 

TIOo-lolrl ____ PogUol10 lo_cn_ 

---Rood,_on.to,.,.,_ l7LIIH7 

I 

t 

VES 003854 
M a a~.!.~ ! --------------------- ""'m; .;.;G;i#;;;;i':;;-;~~_;i;~;;:;-;;.;-

( vaa!dat!on Slallltu!! Pw 

Muxam Job t: A8114896 

( ., 

; 

~ ' 

.......,.,.,.-~ap~ooo .. .,wo~..., __ .,., __ _,..,..,........,__.-,.,,..-s.IO.lot ISOIIIIC110>5-~ ................ SOC""'CAI!Al._..,..,... .. ,._..,.,....._. __ _ 

,.. 10ol10 

_ ____ ...._.,._ L1'1.-

. 

i 

VES 003855 
( 

Waste Feed Results 

( ··: 

-

.. 

l .· 

·, 

f 

. > 

; 

I 

. ' 

.· 

;. 

VES 003856 
M a ,§j";:;,,.r;!J----- ---------------2"':!'~"'!2:.! .... ~'""~-~i!l·!!!·!!!!!. 

YourPI'"ojecljJ: 10002~ 

Sile:CPT-VEOUA . ·' 

A&tantton: Jeff Gorman 

ENSR lntematicnal 

5015~1lr 

S..lle104 

e.-t Syraalse, NY 

USA 13057~ 

"AXXA" .JQBt; AfMI39 

Recatved: 20NIDII25.11:30 

Sa,.,a. lolalrbc UQUID 

• Samples Rec:afyed: 8 

~ Dat.: 2011111f16 

This report""'" 1 '" all pnMous reports with the - ~~ -job ....-

C§RifiCAJ'E OF ANALYSIS 

( ... , 

f . .. . Sltnple MM1X: Sell 

II Samples Recetved: 6 

-Inti t.,Co/Mf 

T* -In 8ol bf-ICI'-'ESt 

EPA 1WIIt81010;C 

,,,_ 

~, ___ .... -~ ... .. --_. ....,.b....,...d_ln .... -'41" ____ ... ICI' ........... """""0> 

Total.....,. pages: 1 

___ _,.,,. .. ___ r:ovyis_ ... _ 

Digitally 

signed by 

Mike Olallis 

~.;.:= - Date: 

~ 2008.09.16 

10'.16:33 

.()4'00' 

VES 003857 
c 

:~ 

M a ~ J:J a ------- -------~,-:. ___ ........ !!!:1!!!!!..!""~ .... ~!!!· ~-!!;~-2!~· ...•.... ENSRI-

~ Projod ,, 1ooo:!o022 

l'nljecl nomo: C!>lWEOUA 

RESULTS Of AHA!. YSES OF LIQUID 

~(Q) I~ 1. u 

Pago2ofM 

-----"""""' ,_ i11.!1H7 

t 

' 

'• 

VES 003858 
( .i 

. 

. . 

__ 

M a {;;hft -a a .I)Mtc• ------- ---------- ---'Do'='-!!!.!"'~ ... =""~~~= ,_ R~ Dole: Z008/0Q/15 

ENSR lnl-'<lnel 

Clenl "'*"'Ill: 10002-022 

PIOjod namo: Cl''l'.VEOUA 

ELEMENTS BY ATOioiC SP£CTROSCOPY (UCIUKI) 

= il 

*-"") oro\ 210 o.oe 110 

- ll'O -tiiiZ70 

"'"'llor)OUo jllo) 11'0\ 

- ~- <0- 0.005 

- -tiiiZ743 

*--ICdl 11'0\ u 0.02 t.t O.lll! 2.5 0.02 110210 

0101 Choom&Nn (Col II¢ 2.3 0.05 2.0 0.05 t2 o.os 11021.., 

""'Uoolll'b) II¢ ,. 0.09 23 0.08 100 0.09 1102143 

~~ 11'0\ O.ts1 ~ G.0\5 b.oot$ 0.0111 

Dolottlonu.ot 

-- -·~OooodPago3Gf.14 

_____ .._c-. L7LIH7 

' l 

l 

' 

' 

. ·' 

,. 

·' 

VES003859 
, ( '\ ' .. :.. 

.. 

M a ;..,/()a m __ ______ _ ___________ .!!,.,!!!""~·!J"!I:.:!....,!!: .... ~-~ .. ~·!!!· m. . M ....... . ENSR -.wlonal 

Cion! Plojecl"' 10002.o22 

Pmjecl..,..: CPT·VEOUA 

RESULTS OF ANALYSES OF SOIL 

VES 003860 
( 

c l 

M a 65J.~X!J-- -------- ----------"""''"'"::-:.!r=s-,.o:-=.,J=,-='""'-' • EH$R lnlotnalional 

Clienl Projec:t II: 1 OCICn.(IZ2 

ProjeGt nome: CPT·'IEOLIA 

ELEMENTS BY ATOMIC SPB:TROSCOPY (SOL) 

1!)6 •e4h~(Hg) IIIII!! 0 T.ll lA Q.5 111028(2 

e. 2 ! ' NMWJ~} ... 17 11 14 1803131 

.,..._~(Be) ... <0.5 <0.5 <0.5 0.5 1CI8311 

eoo 2 ~(QI) ... 1200 1200 ... IU 

-~CCI) -

"""' 1100 I3ClO 7000 o.5 1110:18S -l.ood (1'1>) uglg 1300 1400 1100 1-

~-.l>nll 

BMch. Qally Cor*d B*h 

-~__ IHill uglg 0.841 o.eo o..sa D.82 .ll5 11102142 "'"

, ..... 31 ""' 1& 18 1 

--...(8o) """' <0.5 IliA <0.5 <0.5 o.s 

-

11021311 

ecnc:oio:o Comb!~ (Cd) ..... .., NIA 110 1711 0-3 1eo2831 

-a-.-(0) uglg """ - 8:20 UlJD o.s 

-l.ood(l'l>) 

-

"""' 130 ""' __ 140 ~ 1 1-

.....,.._ • Rt:;c: bible Olledlon Lml 

. a.My Ccnlrd llk:tt 

~ 

~--~ -QCilold_ -blo-(llo) ..... 1fT 1 1102831 

~'<*! ----(8o) uglg <0.5 0.5 1102S311 

- El<1rocOiblo c.m-(QI) ug/g 100 0.3 11Q2831 

- -a-wn(Ct) ug/g 9110 0.5 10112831 

--PAod (1'1>) ..... 220 1 

~--~--Liml -

QC -. <MIPJOorO!dPago5ol14 

i· 

VES 003861 
c· 

.~ 

M a ,§1.~-m--~-~ ---------------.;.. · _.,.. !!A=:~.,., .... =:• ..,-~ !!!!!t. 

ENSR~"'"roa!ic>iOI 

Clonl Plojed It , 0002-«12 

Projocl- CPT·VEOUA 

ELEMENTS BY ATOMIC &PECTROSCOI'Y (WATER) 

-----_.,....""'""" L7LIH7 

,. 

VES 003862 
( 

c. ·; ' 

M a...,<; ~ .a 

....... rn . ____ _______ ..:.... ---------~"'~·!:!!"'"'~"'"' .... ~:= .. !!!•~-'~~= 

- ION13047 ...... .,~ 

.- UOUID 

-~~- ...... .,~ 

-LIQUID 

-II!IK30<9 

- II l.8TU>U>I>RI 

- UQUI) 

-10 AH3049DIC> _.,..., LBTU-UW<I 

- UQUII) 

THI Su.........y 

EHSR-.. 

Cfionl P!ojocl II< 10002.()22 

Pn>jocl-; CPT.VEOI.IA 

~ 

.......... -

- ~ 

- 20011011121 

.......... 

- 200Ml8l25 

VES003863 
M a ~ ../J .a ...... rn. --'--------------------... -=-=>i'-' ..... ="•"'·"'-=- ==· 

( .

. ......... Job 1: A5<939 

~Oolo:2008109116 

r:·. '<..) 

-~~ ._..., AH

~~ 

:IOI52 

- Sol 

_., NOOII2 Dio> 

-~~- Sol ~~ 

-~~ -~~- Soil ~ 

_.,_ - ., cs.U4-R3 - SOl 

-10 -ID -8S-U4.fU 

- So!l 

Pogo8 ol14 

ENSRinltmCionl Poojod 1: 10002.()22 

Pn>joct - : CPT-YEOI.IA 

. . 

•· ' 

VES 003864 
( 

c·· 

{ . "-..· 

M a .../J a rn -----------~---------1.,..~-~f""'s.~..._!e.:.:_,~..,o!!!!!'"''"'!!!. . M•••n••• 

-10 -E>co ._10 _, 

-Sol 

-10 - ._ 10 BS4J4.R2 -... 

-10 Nl3051 ._D._ -Sol 

-10 NI:IOGO 

........ 10 -

--

-----~"- 1.1LI5H7 

ENSR-..lonal 

Clenl Projoct" 10002~ 

Prcjoclowno: Cf'T·veotl4 

' 

• 

~ 

' 

.. 

·. 

!. 

VES 003865 
Teol Summary 

( i '· 

P1go tOoiM 

_____ ._.....,_, L'II.IH7 

EHSRk-101 

C&ont Prqoa t: 10002-<122 

Projoa n.._ CPT-VEOUA 

' 

,. 

·. 

VES 003866 
( 

t> . • ....... 

M _a ?52~m----- ----------- --~-""'"''"'-~ ... =-=· """=-= =. 

0-IUIL COMIIEHTS 

EHSR.,__ 

Clent Projeol #; 10002.(122 

Plojocl-CPT·IIEOUA 

&lmplo AH304e-01: --Due ID Ole ..,.P.. MOIIIx, 08m!>fo--(lolocton --OCiiiCiod -·~· 

~ AH3047-o1:--DuoiDh--------...-~· So.,.. AH3041>41:-- O.eiDh--. ----.--...-.-dl~. 

s....,.. ~,, __ Duobllw------.---...-......... . 

s...p. ....,.,..,.,, __ DuoiDh-----------·ISIII'· 

...... -~, --Duoloh---------- :: ·~· 

--

. . 

; 

VES 003867 
( 

Ouolity As9Urence Repocl 

-Job Nun- BA89<939 

ENSR_,._ 

A....,liorc Jell Gorman 

Clef'll~f: 10002.(722 

P.O.f: 

Projod name: CPT-VEOIJ.o\ 

VES 003868 
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( · 

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M a .N a rn .,.,.,.;.w!t~~s-..- •" ·-,-~---------------~~~~=~!!!!!!!!. 

~ConlldENSR•••-111 

AOenlon:JefGomwn 

. Cllont Plojld #; 10002.()22 

P.O.#: 

Projec;loamo: C:I'1'.VEOUA 

Quallly Assurance RIOPO<I (Continued) 

~Job .... MtJtt:~9 

--...... 1) Ttoo.....,.. __ ... ______ o.._.blot .. ....,._.. ...... opedtc~ FO<-Ihol 

.... - C)IO~ .. """""' .......... - • 2) '""' 

___ .............. ,_ __ ... _INC). _ ..... licl>«>-·-· ..... _ ...... __ .... .... _ .... ......, ... _. __ ...... ~.-.. -·---

__ .... ____ Pogo 13 cl14 .,_ ... _ 

VES 003869 
. M a ~ 

A a rrl ----~---- --.:.- --- ---__!!A!!C!!m~'r!.:!"""!!!!!!!! ""~...,!!! ~:~·~ ...... ~ 

( ·Validation Slgllltur! PaGe 

-

; 

( ... ,. . 

" : FRANJ( MO, B.SC, IIIarpoi< ~ ~ 

Scieutific: Sp • 5 st 

(_j Pogo 14 "' 14 

VES 003870 
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1!!1!!!!!11 --

..... --"' -- llr.-Po.- l)'l)lt~(fol<JII$.8Z24:1!1l C.rtifit•t• or A»alytl<al Results 

Mo...,. Aul)'tlu l S.rvlca 

"•c.-..... u. Reed 

Mloolaa- Oalario L5N ZLf 

m0900so 

AJ94939 

~~Halt PQL Ualls 

AIIJtt' l lR \ J\Jn'u..u4-RJ 

LaU D: ROI09CJOSG.OIA 

Dol&~; 0112112001 0:00 

' 

Dote ...... ..,, 09111112001 

ASH, OIL 

- 1.05 0.01 

HI!!ATIHO VALUE BT\MUI - vu ,_ .. 4,1130s.-01B I LBTU-U4-R2 

LablD: R-S0-02A 

Dolo~: 0112112001 0:00 Dlte Recefvecl: 09/1112008 

ASH; OIL ...... 0.0200 0.01 

HUTIHO VALUE BTUILB -v- 2. .. 0 50 

< llldi"*"l<ss ,_tile liroii of q.wUIDool 

JWIT-~ 

"' 

-

" 

-

Dale: 29-&p-/)8 

Dolo 

Matrix: AQUEOUS 

040l Z2oSoo-Ot VJO 

0240 

·~ -

M.ltrtx: AQUEOUS 

0412 ~ VJO 

112<0 

·~ MRIP 

Plplofl 

VES 003871 
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c. . .-... 180«1 

1)102t5.-(teo<)21S-m.tl!JI Certlflute or Aulyllcol .Resells 

Mono. A»l)1bb s.m-

--- ......... o ... r~o ... L7L!87 

RW090001 

At94939 

~1Dt47~1R I RB1 U-U4-R2 

.... ~Ill: Rtl1090001-li2A 

Dolo S..,tod: 0&12112008 0:00 o. ......... d: 09/0212008 

ASH, OIL 

- tM 0.01 

HEAl11G _,_ VALU£ B1Uil.B 

3)170 50 

&JJ 041 OIR I RBTU-U4-R3 

l..obiD: R08090001~3A 

Jlu.Benpb'· Of/21120011 0:00 Dote ... ei:Yod: 0910212001 

AIH, Oil 

- ..... ""' 

HEAl11G VALUI! B1\IIUI tlo_,_ •• 350 50 

AII304!::!21B l LBT U-l!"-Bl 

IAI>ID: -l.o4A 

ASH, 

Oli

OIL 

: 01/21120011 0:00 Dstc-od: ~ 

- 0.01tKJ, 1.01 

HI!A~O VALUE BTIM.II 

HtolfnGV- < !0.000 50 

< ltll!ic*llcss Ibm the liril of 'i''"ntrlatjoo 

Rold,_~ 

Dote: /().&~ 

Mat1U: AQUEOUS 

.,. D4l2 ~ VJO 

- 024D 

- IIRP 

M...Ut AQUEOUS 

" D4l2 ~ VJO 

e..-.. 0240 

- IIRIP 

MMrU; AQUEOUS 

" D4l2 

- VJO 

- D2AO 

- -

Pogo I ofl 

VES 003872 
( 

' 

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(_ 

llliliii

1!!!!1!1 --

--~ILC 

illlsi-Dr.-Pe.IIO«l 

(111)21~("'(J!1S«Z2-131 

CLIENT: 

Lob Onion 

.... jod: 

MIIXUI ANI)1ital SemSMSN-S.rtleeiW 

li ........ OolarioL7LSH1 

RCl$090001 

A89ol939 

AB3051=91R ILB'l1J-U4-R3 

Lob ID: R0109000Hl6A 

Dale Suoflod: 0812112001 0:00 Dole Jl.e<eiYecl: 0910212008 

ASH, OIL 

All> 

HEATING VALUE 81UIUI 

AB3062=91R/CA-41-R2 

Lobi!): R0109000J-o7A 

o.oeoo 0.01 

t,BOO 

Dale Suoplecl: 0112112008 &:00 Dole Re«lvecl: 0910212008 

ASH, OIL 

< Jodlcllesless tb&n the limitof~tllatloo 

If ~Hold 'lime~ 

2U 

Mdiod 

Malril:AQUEOUS 

-

Molrh: AQUEOUS 

44\8 POTTSVLLE PI(E. RE.At»~G. PENNSYLVANIA 19$05 61o.t21-8833 FA:X.&1o-921-4667 

~· 

VJO 

rop2of2 

VES 003873 
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--llr(1~5-Q2.12lD .-h. ·-

Certilieate of Aaalytical Re.Jts . Date: 

ClJINI": Man- Aaalytkol Sortlocs 

5555l'l•'*s.m..Rd 

............ - L7L5B7 

LabOnlm 1\08090002 

l'rojod: Al94939 

A.UiyJto A<Reedndllull Drylluls 

AB3052-0IB I ~IU-RI 

Lob IJ): ROI090002.01A 

DalOS..,W: 0812112008 

PI!RCBIT MOISTURE --· 

-.T- 7U 

ASH, COAL 

,... . .... H&ATIHOVALUE, COAL 

,.....v_ ,.., 

AB3053-41B £ CS-U4-R2 

LabiD: R01090002-021\ 

o ... s......,, 0812112003 Datellooolml: 

PERC _T ENT MOISTURE .... 71.2 

ASH, COAL ,... $.76 

HEA,_ VALUE, COAL 

-- 1180 

< lndlcatosloss dJao the limit of qiWJ!iiOI!oo 

Y-Holdl'be~ 

0910712008 

21.2 

$.320 

0910212ll08 

24.2 

•.&70 

UIIIU Melllod Date 

Moab: SOLID 

" 02218 

-

" 03tT4 

-

- 058115 

-

)lotril:SOLID . 

" 0 2216 

-

" 03114 -

- 058115 

-

}~ 

, 

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Aaal:l>t 

VJO 

'· VJO 

-

VJO 

VJO 

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VES 003874 
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CUINT: MuuaAaa1)11a1Serricoo 

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..,....._, 01IDrie L 1L .5117 

[MOnier. Ithojod: A894939 Au.,_ Ala-trod Bodo 

< lodicatos less thu lbc U10it of~ . 

I·H*Tae~~ 

Date /O&p-()8 

Dry Bull tJolls Ill- Dolo Aloatyot 

Poce2or• 

VES 003875 
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--llr.- PL1-

t)oj)21 (looe)215m-1lll Certillcate or ~CIIl -

CLI!NT: Mu:ua *tt'ytk:lll~ 

555511--a.l. 

-. .... - L1l.Sil'7 

l..otb()nler: R01090002 

ProJt<t: A19:1939 

Allllyou Al-ediMio Dryllub 

~IR BS-U4-it2 lAb I]), R01090002Al5A 

--.- ou.ll/lOOI DolePERCSIT~ 

"*'-.Totlf no 

AIIH,COAL 

..... 72.3 

HEA,_VAI.UE, COAL 

""-,_ 2<0 

AliJOS8.4)lB 1-Bs-1!4-Rl 

IAbiD: ROI-A 

Oak~ ou.ll/2001 n.a.-. 

PERCSIT-TUR£ 

- r0111 su 

ASH, COAL 

.... •a.o · 

tEAllNO VALUE, COAl. Ho"""v- 1300 

,&IIJK3.41Rl Lti C4 Rl ..... 1]), ROI091J002.07A 

-s-.w: 0812112001 

~03302 

Yoidure, T.-

--

2.32 

AIIH,COAL 

.... 62.4 

< lod"'-ieu -lbo ~ af quaolilolioo 

H .. RoN 'IDe C:UC.S.CC 

0910212001 

92.1 

310 

0910212001 

74JI 

2,110 

0910212001 

&3.1 

' 

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l)o.IJJ MdHcl Do to 

SOUI> 

" 0 22:11 

-

" 03174 ~ 

- DeliS _...,. 

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" D 22:1& 

-

" 03174 

-

""""' OS8e$ 

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M.otrtc SOLID 

" 03302 

-

" 03174 m.,... 

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MRIP 

VJO 

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Pl&e3aF4 

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--Dr.-PII.Iti<O (lei)21U2)81115(~$822.12!13 

CLIENT: 

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Pro jed: 

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5555l'lonlt s.rrtc.IW 

~O.IIrio L7LSII7 

RO».llOOl . 

A894939 

bR3064 OlR/BCJ=if-Rl 

Lito (J): R08090002.oiA 

DIU~ 01/ll/21101 

PEIIC81T 1IIOIST\JII£ 

-. .... AIIH, COAL 

HI!ATINO 

- VAL~ cOAL ........ .,_ 

O.lt~ 

... 

O.D100 

<!0.0000 

<!ndicll<slealhalboliMofqo-jbtjon 

lWIIn.t~ 

lloto: I O.S.p-08 

Dale 

09102121101 M.u:SOUD 

,. ' 0 22'18 C>oSopotO VJO 

0.50 ,. 03174 ~ .vJO 

- OGIIt6 

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VES 003877 
VES 003878.pdf 
VEOLIA ES TECHNlCAL SOLUTIONS, L.LC RllSPONSES tO Tim UNITED STATES 

ENVIRONMENTAL PROTECTION AGENCY'S REQUEST TO PROVIDE 

INFORMATION PURSUANT TO THE CLEAN AIR Acr DATED JANUARY 29, 2009 

Exhibits K - N 

VES 003878 
K 

VES 003879 
.. .. . . 

'· 

VEOLiA .ES TECHNICAL SOlUTIONS, L.L.C. . . . ~',. • ..•. ' . . SAUGET, IL. . .· . . . .. . ' . .. 

. · . 

· · :. oocuMENt oF C9MPi.J~c.; ooc> ··.:· . .NATIONAL EMISSION STANDARDS . 

_ ... f.OR HAZAR(>OUS AlB POLLUTANTS 

: FROM -HAZADOUS W ASTE.COMBUSTORS .. ·: :· \' 40 CFR'PART 63' SUBPARt EEE . · . ·. · .. - ~ . ~ "· '' ,• , . . . ... -· . . 

, , : ::_-: . . QCTOBER 14, ~OO.S · .. . : .: . . . ~ 

. . . .. > .·.·-\; __ ·: ' 

; '. 

'... . . ;: ; . : . 

. : .... ' ..... -'- : . : .. -· :_: .. ·... . 

. · . . .. . : -. . . . : . -· .. 

. ·--: .,'·': . . · .· . . . · .. . . ·.· :.: . . .. -. ·. __ 

... . ~ 

.· . 

. . 

' . 

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. . : 

·. · .. . . . . . : ' : 

~ . - . 

_:. ·. -~ ~ . 

: , 

.• . 

. . '. ' 

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-... 

'· 

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.. ... ·· .. , ... ·· -~-.. :: .. ~ · .. ~::.i::~~::er-t~i::;::.:'izt_ ... ~;~.:. ::~ ::~-. ~:i-:: .. :-:I~:Jii;,[;J~?/1 ': .. :: :::~·-::·: -~ :. ... ui...;s.....t..ci<..~~ ~~i!~"d 

VES 003880 
... 

. ,

.VEOLIA ES TECHNICAL SOLUilONS, LLC. 

. .SAUGET, IL . 

·. DoCUMENT OF COMPUANCE 

NATtON:At-.EMisSiON ·stANDAfUlS FOR .H/aARDOUS AIR 

POLLUTANTS FROM HAZARDOUS WASTE COMBUSTORS 

: .. _. ·. 40 CFR PART 63, S!JBPART EEE 

OCTOBER 14, 2008 

' ·;· ;- . . . . .. ' ! · .. 

.. 

Veolla ES Techni-cal Soh.rtlons, LLC., certifies that: . . . .·. . . . . . . . . . . . .. (1) .. · . R~uiMd c~ and CMS are ln$talled, calibrated, and 

·_. -· .. c_omlnuo\lsly o~atlng 111 coinpllance·wlth the 

.. · ~uirerne~. of this subpart; and · 

. ~ . . · ·.· ·~·:·: ,;·; .... :. : . . . . ·: ... ' . . . . . . .. . .. · · (II) . ·l:liiSed 'em an engineering evaJ1.1ati0n prepared under 

· • · r ; . iriy tfl~tiOn ~r sul*'fision .II) ~ccordail~e with a 

·: .:·· /: system d8stgo8d to·ensure thirt qtiallfled personnel 

·: · properly ga~red· and evaluated the Information and 

: .i . . supporting dOcumentation,. and considering at a . ·• _'mlitlrrium lhe, design, operation, and_ maintenance 

.. ; chatacterlstlcs of the combustor and emission 

.· . .· 

. -':c:OOtr'ol equipment; the types, ·quantitieS, and · 

. ·•· ~ractenstlc of teedstreams,: a·nd available · · emisSions ciata: · · · 

. ~ • :· : (A) yeo11a E~ Teehnl~l ~utloi'ls Is in tOmpllance 

· ·· · · with the emission standards of this subP.ar:t; a.nd . . · ': . . . . . . . . ' . 

(~)The ilmlts·qn the oi)eratlng pa.i'ameters under 

· . 63.121:19 ens.ure·complianee with the emission· 

. . . . ~ '... . , stand8rd~ of thiS subpart . . . 

. . IJ·: · ··.< ¢..MJJ < ~4~'8 .. · 

Geoerill Manager 

··' .. ·

loiN los Date I 

\ J 

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I 

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. ~ 

I 

. 

~ 

,· 

:; 

VES 003881 
:_ ) 

DOCUMENT OF COMPLIANCE 

TABLE OF CONTENT 

Applicable Emission Standards 

And Operating Parameters 

Start-up, Shutdown and 

Malfunction Plan 

Operating and Maintenance Plan 

CMS Plan 

ESVPian 

AWFCO Pian 

Feed Stream Analysis Plan 

CEMs Plan (QA/QC Plan) 

Relative Accuracy Test Audit 

ForCEMs 

Specification Sheets for Hydrated Lime 

Specification Sheets for Carbon 

Residence Time Calculations 

OJ)erator Certification Training 

Soction 1 

Section 2 

Section 3 

Section 4 

Section 5 

VES 003882 
HWC MACT Emission Standards 

Parameter .\.!J1ili! Standard £@7% 02> Method of GomnUance 

Dioxin!Furan (DIF) ngldscmTEQ 0.20 Operating Parameter 

Limils 

Mercury (Hg} ug/dscm 130 Operating Parameter 

Limils 

Semivolatile Metals (SVM) ug/dscm 230 Operating Parameu:.. 

Cadmium. Lead Umils 

Low Volatile Metals (L VM) ugldscm 92 Opcraling Parameter 

Arsenic, Beryllium, Orromiwn Limils 

Carbon Monoxide (CO) ppmv 100 Continuous Emissions 

Monitor 

Hydrogen Olloride/Chlorine ppmv 77 Operating Parameter 

<.")(HCI/Cl2) Limils 

Particulate gr/dscf 0.013 Operating Pat111llmr 

Limits 

•. ) 

VES 003883 
.. ·, 

i 

...... . · 

Opsqting Ppmeter ~ : Umiis:·:s.: ·. ·' "':-L Test rHt1! 

=~~-- MJximumTctalHazardO\ls ·Lb/br. · > .ot~fJti ~, .· .v~·~ May 2004 

· Waste (Hourly Rollmg Total) •: :j[~;~:!L~~t ·. ' .·. 

Maximum Stade Gas Flow Aeful 15,147 '" ·· ·:• •·:';. SePt. 2001 

Rak{HN~RollmgA--se) · . :::~{ , .;~· · 

MlnJmum PliriwyCombustion Degf 1734:<:-: .. , .. ·:;·,·May 2004 

~~~~=~(Honey ,. . . ='1,:ft;i~~; . ·_. 

Min!mlim Secondary Combuslidn Dei ~ ·· · · . 1_.~;: i: .. ';• .: .'•:::Nov., 1996 . 

,;j;;;.~;~ verise> . ... ; 'l . tf.ll.. 

.:.:l· ..~l. :--·'"" Mai<. PUmp.LowVolalileM.ellls Lblhr: 46 "- ;:y:>,-.. . -:; ~2008 

Fcedialc( 2~RoUingJ"otal) • ·" {·~·>:.~;} ... MaX. .Totall..owVolati.leMetliS t.bn.r 47., .,. ·--d Sept_ 200& 

F«draae ( 12 How RoUini TOuQ • 'g.~:\ ·~~-~;: ' .. Maximum Semi VoiJtile Metals LbiJir 6~. ." ~·~:: .:, Sej>t.,20QS 

:::·::::~> Whr -:,~;f0~z{}: Aag, 2008 

DIU!, DIP 

DJ.l.B, j)/F, 

Part, SVM, 

L\IM 

oRE, DIP 

DIF,SVM,: 

LVM 

.LVM 

SVM 

(12 Hoor ~~Ding Toia!) . : .:; ':(.:;_;;:ff: . Maximunia.torineFeecbte Lblhr· 21F· ·l . ·.,. , Ailg 2008 siiM.LVM 

~~~= Lbltba; · · '~1.76,~ti'c~ :..•.,,: . .-;,.;.:~ Nov.,~·''" 996 ·~ HCI!Cil 

;;,-;.~~ ~;. c 7f--'f ~· '" .. -. 

1 bp<nling .-meter limits in cable refleet ~ ~. Wiieen Uni12 and Unh 3 tesl.dala. j . ' . . ··:· .;. · •.. ·; ·: . . . 

. y::;;-y .. ··· 

.. 

·: ... ... . ~ 

·. 

VES 003884 
UNIT !t Ol'ERA!ING PA:BAMET!i;B, J,IMITS 

.. 

Pcrfonnanco 

Opcn!jna ParaedP' .IIDill .Limila ~ SUrvlen1t 

M1ximu1n Total P1.1mpable Lblhr POC- 3156 s.,c.. 2003 ORE, DIP 

Wuto (Hourly RollinS TOIII) SCC-1006 Cond. I 

MMimum Toral Huatdous Lblbr · POC- 13,7% Sop<.. 2003 DR£, DIP 

Wute (Hourly Rolli"' Totel) soc-t006 C4nd. I 

Muim.um Stldc Oas flow Acfm 3&.016 ""'' 2008 ORE, DIP. 

~law (ll.,..rly 11411i"' 1\-) p_.,SVM, 

LVM 

M iAimtn~ Prirury Combustioa. Dq,F 1507 Sopt.. 2003 ORE, 0/F 

a-.berT..,.,.._e(Hourly Cond. I 

RDIIiosA-l 

ni.~n~.n Scc:on4ary Combustion DqF 1116 Sept.. 2003 ORE, Ill!' 

O..mbc<T-e(Hourly Cond. I 

R.olllnl A..,.ap) 

Muinwm 0-.c'MM.LSe {nlet DeaF .34 Aq.,2008 DIF.SVM, 

-r.....,......"' (Hourly 11411ing LVM 

1\"""80) 

~u. Pump. Low- Volatih: Mc:tab t.bllw 47 AAI&-.2008 LVM 

.: .. r•<l2-Rotun,Tooal) 

Max. Total Low Volarilot.fctab U>/br ~ ....... 2008 LVM 

F-oe ( 12 Hoot Rolliog Tooal) 

Muitnwn Suni Voluile Metals Lblhr 64 Au" 2008 SVM 

F-(12 HourRoii ... Tocal) 

M-M"""'Y Food- Lb/11< 0.016 Aoa-2008 Ha 

(121lou< Rolf"" Tocal) 

Muimwm Qlorilc Food n&e Lblbc 2S2 Aue.. 2008 SVM. LVM, 

{12 Hour Rollhoc Tocal) KCI/Cil 

Maxim""' Mil Food Ruo(l1 Lblhr sm Do;., 1995 Port. 

Hour Rollins Tocall 

Corbon lnjcecioo f- Lbllw 

(llourly Rolling AV<nge) 

6.2 Aug., 2008 OIF,11g 

Minimum Sorbalt Feodralc. LbllbO, 1.01 Do;., 1995 HCI/Cil ... (Hourly Rolling Avcnp) 

Min.imum Catricr Flaid Flowmte OolllbO, 1.61 ~1995 HCI!CI2 

(Hou<iy Romna A-l 

VES 003885 
( 

·' ·"' 

·. 

. ' . • 

. ,j 

c. 

i 

CONTINUOUS MONJTOIUNG SYSTEM 

QUAlJTY CONTROLPROGRAM 

Prepared for: 

Veolia ES Technical Solutions, LLC : 

Sauget, Illinois 

Prepared by: 

Franklin Engineering Group, lnc. 

Franklin, Tennessee 

. . . . . 

' . . :: 

··. ' ' .. . ·. 

' .::: ' ' •' .. ' 

... . . ' . . ...... .. . \ ., . . ·•. . ·' . . ' .. .- . . . . .. .... .. . . .. . . . . . . . . _:' .. . . . . . .. ' . . . 

\ 

October ~oos 

. .. 

'· . 

•' 

! -~r.:t -:L,. . . . ~" .· .~·:· 

·.:. · .. :· . 

':-·. =.:· . 

- .. .. .. . 

'. · .. 

'. 

.. .. ' 

.. · 

. . ' . ' .· .. . 

VES 003886 
·' 

.··. 

. •' · .... 

·c. ··<t ·--. .. 

~ ... · . . . ·. ~- . ··... ' 

: ·. •, ... .. .. . · : . . . ' • 

·~ ... . ::. '• 

. ··: . ~- ... ·. . .' •. : .. 

·! ·.· 

TABLE OF CONTENTS 

1.0 JNTRODlJCTJON AND BACl<GROlJND ......................................................... ) 

1.] SUMMARY OJ' FACIUTY INFORMATION .......... ....................................... ....... .4 

1.1.1 Fixed Hearth Incinerators ............................................................... 4 

1./.2 Rotary Kiln 1ncinerator .................................................................... 5 

1.2 CMS lNSlRUMENTATION ............................... _ ........................................... 6 

2.0 CMS CAJ.JlJRATION AND PREVENTIVE MAlNTENANCE ........... _ ...... 13 

2.1 CMS CALm!lATION ..................................................................................... I3 

2.1.1 1nitial CMS Ozlibration ................................................................. JJ 

2.1.2 S-ubsf!'{UDII CMS Ozlibrl11ion ..................................... _.,_ .............. J3 

2.1:3 CEMS Ca/ibraJion Audits and Calibration ................................... 14 

2.2 · CMS CAUBI\ATION AUDrrs .................... : ................................................. :l4 

2.3 · ~MAIN'I;BNANCI! ..... : .................................................................. ~9 

3.0 . CMS RECORD KEEPI NG AND lU.:Po RTING ..... .., .. - .... ~ ................ ~ ......... 20 

3.)· Rl!cOlU>Kl!EPING ... ~ ......... : .......................... ~ ........... : ...... - ............ : ............ 20 

3.2 REPOR'imo .. : ........ : ..................................................................................... 21 

4.0 CMS CORRECTIVE ACI'IONS .. _ ....... : ...... ---·---- --···--- .............. 24 

. ·:· :. ... ; .:.>. :-· 1.' • • 

'\ ·: . ••'. , . . . : ·. ~ , . .. '. · . .. . .. ·,· ' 

. , . . ' .. .. , 

:· .. . · .. . ·· ... · ·:". .. ~: . 

~ .... ·· .. : . . . . . . ·,· -~·· ,: ... : • ' - ···. . . : . . . . .. .. . . ·.: •'' ·. · .. · ·... . .. · . ' 

'· •. 

. ·•.··. 

.· 

. . ... ... ~ .. . · . . ... : · ... '• ,· L .. ,.-..· .·.=-.::~ . .'::' ,,. .. r, 'l. • ·, ·, ; · • •r • ,. , ,• . •, .· : :, 

· . . '. .· .~. . " . ... · . :· . . . ' : . 

(. ) 

. .. . . . . . , . . 

il 

. . . 

• v 

. · . . . .- . : .. . . ··.· . . .. 

VES 003887 
( · 

. ····.:: 

·.:. 

.· 

., 

TABlE 1-1 

TABLE 1-2 

TABU!2-l 

TADU!:l-1 

·=· , . : ,",,•. 

·.·· 

.· 

·. 

. ,• 

INDEX OF TABLES 

REGUt.ATOJIY OI£CXJJST roR nlE CMS QA l'ROGRJ•M .............................. 2 

CMS INsTRUMENT SPI!Cil'ICA TIONS ............................................................. ? 

CMS CAUBRATION AUDITRI!QUJR!!MENTS ............................................... JS 

REPoRTING REQUlR!llitENTS ....................................................................... 23 

' . ., . . .·· ·~ ' . ':, ... .· .. " . -. I. ' -" ' ' ' ,!. ::. ' . ' . ... .. .. . · .... 

.. ,: 

. - ..... 

.' · 

ill 

VES 003888 
.. 

1.0 INTRODUCTION AND BACKGROUN~ 

Veolia ES Technical Solutions, LLC (Veolia) owns and operates two fixed hearth 

incinerators (Units 2 and 3) and a rotary kiln incinerator (Unit 4) at its facility loeated in 

Sauget, Illinois. The incinerators are subject to 'the National Emissions Standards for 

Hazardous Air PoUutants (NESHAP) for Hll7.ardous Waste CombuStors (HWC), Part 63, 

Subpart EEE (§ 63.1200 to § 63.1221). The NESHAP specifies emissioos standards 

· which reflect emissions perfonnance of Maximum Achievable Control 'Technologies 

(MACT), and is commonly referred to as the HWC MACT. 

H82Mdous waste combustOIS are required (per § 63.8(d)(2)) to establish and implement a 

Continuous Monitoring S)'stem (CMS) Quality Control (QC) Program. The pmpose of 

the QC Program ·;s to outlioe procedures used to verify that the CMS are propeTiy 

installed, cab'braied, and coUocting accurate da1a on an ongoing basis. The CMS • 

pcriormance evaluation test plan was submitted as part of the Comprehensive 

. Performance Test Plan. 

·. ·The QC Progra'm .demonstrates. Veoli(l's compliance with the !equireJnents set fo:rth in 

.. § 63.8td)(2), as. welt as the additional quality assl~ (QA) requirements. The QC· 

Program is requ'imf to contain descriptions of initial and ·subseqUent CMS calibl'Biion, 

calibration drift, preventive maintenance, data recording. calculations and reporting; and 

" corrective action plan for maLfunctioning CMS. Table H presents the regulatOtY· 

imerences related to the QC JAO&IWU. foUowcd by the section of this plan that addresses each.· . . specific rcquiremeot. Some references aro made to other HWC MACJ' required facility 

operating plans. 

•• t •• 

,· _' :~ .:_ . ·;_ .. 'Ibis-.QC hogram iS int'codc;d to fulfill the roquirements of§ 6~.8(d)(2), and iDcludi:s. 

:· ... :- , ~ .. ··: __ ':U!f~J<:~totheprocedurcafOfeachOf~.fG)I~openlioos: · 

~ ·~ :~· ... ~ ... :~ ~--~) . :: . : .. ~ .'::(':'. .: ·.:· .. ·. _::·:~ ..... ·, ~-. _: ~~· . ·. .. . .. . :·. < ~. . . ! • • . • •• • 

•. ·, .-. ,,. •. · .• .-.:;• .·lnilta!.and. .subseqn<;ot calib!'alion oflbc~S · · • . . , . · .: . . . ' .. . . , . . ... '· .. . . . . · ... . . . . . . . . . : .. ' ' · :':· . . · ·::·· .... · .. '.·• '' Dtt~andiadlUsfmCotoflbocalilJrati.ondriftoftb8CMS' ·' < •• • • • • • • • ... • ., .·! • • . • • • • . • • • : ' · . . . · 

., .• . 

. . ·.'·. ·.·., · .. :·:. '.;·. : ~e.itiVe~o(.thoc:MS; ioclil!fuigsperepartSinventory 

..._ .:. : ,~ --~~ :: ·.\ :V.:"i :oiti ~.ca~ciii~os: asid~· . ·, . - :. . . . . . .. .. . . :: . : .. , . _: -~~ .. 

· · · · · ·• : Piogr.~mof '»neclive ac!iOa' .ro.-~8 C:Ms. .. . . . ' . ·. : . 

.' . . . , . . ~ . : . . ' , ., 

f' .· .· 

• .. i 

VES 003889 
Table 1-1 

( Regulatory Checklist for tbe'CMS QA Program 

.Regulatory - Description Plan Sectioa Citatioa 

Section 1.2, 2.3 

§ 63.8(c)(l)(i) Operation and maintenance of each CMS O&MPlan 

CEMSPJan 

§ 63.8(c)(l}(ili) Startup, shutdown, and malfunction plan for CMS SSMPPian 

§ 63.8(c)(3) Verification of operational stlltll$ CM.S PET Plan 

§ 63.8(c)(7)(ii) Out-of-control CMS data will not be used in averages Section 4.0 

and calculations. 

§ 63.8(c)(7)(ii) Corrective actions for an out-of-control CMS 

Section 4.0 and 

.SSMPPlan 

§ 63.8(c)(8) Out-of-control CMS informatiop to be submitted Section4.0 

§ 63.8(d}(2) Develop and implement QC portion ofCM.S QA Section 1.0 . J)IOI(Talll 

..• QA program includes the development and submittal of .§ '63.8(d)(2) the" PerfOrmance evaluation test pllw .. · Section 2.1.1 

' 

.( · § 63.8(d)(2)(i) . Develop written procedliies for initial and subsequent Sections 2.1.1, 

cah'bralions 2.1.2 

§ 63.8(d){2)(Jj) Develop written procedures for dctc:Qnination and Section 2.2 3di11Stment of calibration drifts . 

§ 63.8(d)(2}(.W) Develop written procedures for preventive maintenance 

and spare parts inventory_ · Section 2.3 

§ 63.8(d)(2.}(iv} Data recording. calculations, and 'reporting Sections 3.1, 3.2 

§ 63.8(d)(2)(vi) Corrective'actions for malfunctioning CMS Section4.0 > 

§.63-:~)(3) Pe:rf011D311C4 evaluation ofCMS· .. - ~PET Plan 

,. §.63.8(&) Redlle~ of monitoring data:·. . . oo 3.2 

§ 63'.10{1))(1) .. MainWning·,files . .. .. · .. Section 3.1 

::·· Miiinlain=ros or~enta.fromperl'~ ·. 

. . § 6~. O(b)(2){i'i}: , ~tiOI)s ... _· .·:. . -. : :· .... ' ·-.: .. . ..·_ seclion.3.t 

... . 

· ... . .. . ·. 

.. .. § 63.1 o(b)(2~)· ~1m teqmls of ~ch ddurin& which a CMS 'is- ~Qn4 aod 

'· .: : . . : :· .... ..; . nill&o~~eiloii' iofcon · .. ·. . SSMPl>lan . . ~ ... Maibtain.retoros ofmea$'Gremeuts to · § 63.10(b)(2){vb) .. Section 3..1 I COIDI>lialicc : 

. :· 

... 

~ •' . .. 

.. Maintain~ of result$ ofCMS.pcrfoqn3D<»· .. § 63.10(b)(2)(vili) ~M~~uai.ions md opacity·and vis.t'blc emission Section·3..1 

' obsavaticSiis . . 

. § 63.1 X) MaiDWD records. of CMS .cahlnation chects SeCtion 2:1.2 

2 

VES 003690 
{ 

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·. 

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·::-: .:\' .. . .. . .,. .. , . 

.. 

. :~ 

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:r, 

. , .. 

Table J-l (co-utioued) 

Regulatory Cbe:dtlist for tbe CMS QA Program 

·- - ··- ---- R<gulatory Description Plan Section Citation 

§ 63.10(b)(2)(xi) Maintain recotds of all adjustments and maintenance Section 3.1 performed on the CMS 

Recordkeepillg requirements for CMS measurements 

§ 63.JO(c){J) (including unavoidable breakdowns and out-of-conlrol 

situations) 

Section 3.1 

§63.10(c)(13) Maintain records of total process operating time during Section 3.1 the reporting period 

§ 63.10(c)(l4) Develop and implement eMS QA program procedures Section 1.0 

§ 63.10(c)(5) Maintain recotds of date and time for CMS Seetion3.1 ill~ility ( exceot for zero and hi_gh-level checks) 

§ 63.JO(c)(6) Maintain records of c;late and time for CMS ou~f- Section 3.1 control oeriods 

Maintain records of identification of each time period 

§ 63.10(c)(8) of exceedaoces- does not include periods of Startup, Sciction 3·.1 

ShutdoWn Malfuoction (SSM) . 

§ 63.10(e){3)(i) Submittal of semiannual.exc.ess emissions and CMS Section 3.1 · performance reoort 

§ 63.10(e)(3)(v) Content :mel submittal data of excess emissions and Section 3.2 CMS pcrfollll8Qce J;CJ>Ort 

§ 63:JO(e)(3)(vi) 

Content <ifSUJJl11l31')' report requin:d by (c){3)(vii) and· Section 3.2 (c)(3){viii) to Ibis section 

§ 63.10(e)(3)(vii) Condition for submitting ooJy the SWlllllal)' report Section3.2 

§ 63.10(e)(3)(v~) Condition for S)llimitting both the summary report and . Section 3.2 .eitcess emiaf\ions and·CMS penounancen:port . . 

§'63.12 1) . Cah'bmion of and Section2..i 

F of CMS liD& ahlatio · • . · § 63'.1209(b)(~) . , ~Y . ... ·· . ~ ... n; ~& .. : Section 3:1- and tee,ordiilg, of re8uJated ~et r · . · ·. : ·:' · 

§ 63. t2Q9(b)(5) caiculaticmio(tolliDg ~ .· Section3.J., 

,§ 63.1211~) requi= that CM~hre imtalled; §. 1209(f}(J.) .. . ' . . . . . .·. CMS l!ET Plim . '' :. • calibrjlled; and opcratimlal by tbc wmp1i~ dllt&·': 'i ·; ' . . . . .. · .. . · •' ' - " 

~ ·.· .. PIIT · .PaiOtllliiDOCEvahlatiqo Test - . · 

SS..fP 'Siartnp, ~"""~unCtion Plan 

SOP · s~~Pnclic:e$ 

: .,. 

... 

3 

:····''" .• ,• ' . . 

. ··• • .. . · ......... :. 

:; .. · :·!.~ .. ~: > . 

·-;,:·?/ .. : :•: .. ' ; '·:. 

•' 

'·. 

VES 003891 
l 

·( i .. 

The data collected from CMS inslrumentation is used to demonstrate the unit's 

compliance with the performance requirements promulgated in the Interim HWC 

Maximum Achievable Control Technology (MACT) standard. The QA Program outlines 

procedures used to verify \bat the CMS are properly calibrated and collecting accurate 

data on an ongoing basis. 

Due to the similarity of Ole three CMS systems (one for each incinerator. system), general 

refaences to a CMS system or incinerator system in this document will imply all three 

systems. Jnfonnation tbnt is only applicable to one or two of the three systems will be 

clearly i~entified. 

This document is organized as follows: 

.· ·· 

Section 1.0 

Section2.0 

Section 3.0 

. Section 4,0 

Introduction and ,Background 

CMS Calibmion and Preventive Maintenance 

CMS Rc:c0rdkceping a¢ RePorting 

. CMS Corrective Actiom . 

' '• • I 

~plan also assimilates infoimation .. and ~~ found in other doewnents. As 

requlred by § 63".6(eX:iXvi), other docw:nents containing procedures or IDfonnation 

refUTed. IQ in this plao will be m'l(le. avru1ablc .. for inspection wben. requested by the 

·. AdminiS~cir. ' . · ·'-" · · . . ... 

.. . .•. ~ ' ' ~ ..... ~. . : ..... : ' .. : . . . 

..... 

. ... 

. · . 

· .. ·. 

VES 003892 
• .. 

.. :. 

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• Primary and secondary combustion chambers 

• Lime injection system 

• Sproy dryer absorber (SDA) 

• Fabric lilter bagllouse 

• Solids and ash removal systems 

• lnduced draft (ID) fan and stack 

• Instrumentation, controls, and data acquisition systems 

Various solid and liquid wastes and gaseous feedsueams are lhermally treated in the 

fixed hearth incineraton. Solid waste is fed to the primary (Iowa) combustion cbambe:r 

via a feed conveyor system and pnellmatic ram. Liquid waste from tanks and tanker 

trucks are fed to the primary combustion chamber through two atomized liquid injectors. 

Liquid waste from containers are fed to the .primary c.ombustioo chamber through a 

specialty. feed injector. A gaseous feedstream is fed to the Unit 2 primary combustion 

chamber directly from 8)lli cylinders. Off gases from a hooded feed emission control 

, sys)cm· and from a waste handling glove box ·are fed directly to the Unit 3 secondary 

·combustion chamber. Combustion chauibe:r temper~ are maintained using naturai 

; gas fired to a dedicated .blliDcr in both the primary and s~ndary chambers . . . . 

.. 

Combustion gas .. exits the secondary combustion cbambei and rotlllS the SDA,. which 

provides acid gas removal and cooling of lhe combustion ~ Combqstion gas exits the 

SD;A and is distribpted to the fi>bric filler l!agbouses, wbich provide particulate mal1er· 

·removal. The. indue~)(~ diaft fan, located ~s~ of the baghouses, moves the 

Combustion gas througli the system and axhausts the gas through the main siack. . 

.. . 

s 

.. 

VES 003893 
\ 

• Caroon injection system 

• Fabric filter baghouse 

• Solids and asb removal systems 

• 1D fan and stack 

• ~tation, conlrols, and data acquisition systems 

Various solid and liquid wastes are thtrmally treated in the rotary lciln incinerator. Solid 

wastes are fed to a ram feeder via a clamsbeD, a drum feed conveyor, and an auxiliary 

feed conveyor. A hydraulic ram pushes the solid waste into the kiln. Liquid waste from 

tanks and tanker lr)lcks is fed to the primlu'y and secondary combustion chambers through 

aiA)mized liquid injectors. Combustion chamber temperatures are maintained using 

nalmal gas fired t? a dedicated .burner in both the primary and secondary cham ben. 

Coni.bustion gas exitB the secondary combustion chamber and enters the tempering 

chambe\', which provides cooling of the combustion gases. The com~ustioo giiS ex:i1s ~ 

tempering chamber and is dislnlmtcd between two identical sPAs, which provide. acid 

·. , : , · gas J;eDlOval ani! additional gas cooling. A carbon inj~Oll system is. uti.lizeii.: for 

·.: :.:_.-: · :'cootrolling mox:iri!J\lran and mercury ClllisSlon.. The activated caroon is air' injected into 

~ . the conibusti~ gas immedi'!'ely downs1ream of the conv~ence of combustion gases 

\... ' ftUm the SDA&. From the SD.A:s, combu.~on gas is mstxibntcd to fabric fillca" bagbou~, 

. · ·:which. provide particulate matter. remo:"at 'The ID fan, lcx:ated doWllStream of the 

· · bagbooses, moves the combustion gas througb the system .and exhausts the ll!"' through 

the main stack . 

. . 

6 

· .. 

VES 003894 
< m 

(/) 

0 

0 

w 

CD 

"' 0> 

,. .. .1 ~ 

' '~~~· <;·.· ' ~li;\: .. , .. . ;,•, • 

..,-,_ ' ·. . ' 'V · .. . t. ,.,/ 

' · Table l-2' 

CMS Iilstrument SpeCifications - ApplkaUon · .. · IIIiltrument · I Ta& Number I Manufacturer · Model 

UPIINo.l .. High BTU UqQid Feed~Uo . ·. Maui'!owme!c< PT-215 MkloMotion 0405-SS 

Hlgh BTU Ucjuid ~ liVectW~ SO&lo . • Wf-21501 WeisJ>,Twni• WI •. IJO Fee<lr&lo ... Low BTu UqWd Feedroto' · MUI Plowme!or Fr-216 MlcroModon D 40S..SS 

Low BTU UcjuidOirectlojec!ion Scale WT-21501 Woiah-Tronix WI-.130 Feccble 

Specialty Feed Weight ~- Wc;,h~~ Wf-204 Toledo . 8140BXP 

Drummed Solids Peed Wolpt . Wolfh Scale WT-210 Toledo Al40 .. ~ Gu Peidrlte di> een FT-217 Yolo:lgawa YAIIF 

PCCT~ T»>•K TT-lOOAIB .Modieon 8883-200 . •UDic 

sec Tempcrataro TypOK . 

'l'b«mo<cul>ic TT·219AIB Modicon 8883-200 

PCC Prcoourc Preoa1ue PT-200 Rosemom IISIDP 

BSY POliti on· ·Pc»ition Switch ZS-224 Sqoare-D 9007CG2Bl 

Baabowoe Inlet Tomp~ture TypO X. TT-270 Modicon 833-200 

CombuldoD 0.. Plow RallO dPCcD ·· PT.liJ 1\oa..,.,unt llSIDR 

St&cJ< Ou Oxygc:>Co~ . z.m:om-Oxide AT-lS9 COSA ZPN-llYAl·lZl AMI.Z.. 

S'ta<:k Gu Carbon MonoxkiO 

Conoentmion Multico.,.,.,.zu 

Slack HJidroi"" Chloride ID!iaml AT-28&1! EooChem MC3 

i Coi:IO<llltiUol! p~ 

I Sta<:k Ou Moimr• CoDCODiradoo 

Limo SIU!tY Plow Rate I Mag.P!oWIIlller PT-288 Fllc:hcr & Porter !OD1475 

Limo Shury Density De!Wt;y AT-*8 Sola:tron Mobtey 7846 r-sduc« .. •. 

·. :-::iii·:::.:i_}::}_':}~ ~;:.,;:\ 7 

... -.. 

Operatlni R••&• I Locotlon 

0.3,600 lblhr Feed Line 

0-60,000 lb Feed Line 

0.3,600 lblbr Feed Line 

0.60,000 lb Feed Line 

().4,000 lb ~ 204 Spceiolly 

Foe<ler 

0-400 lb Solid Charge 

Conveyor 

0.10 in. "'i~i Cylinder Gas 

10-60 lblmin FcedSVI!Cm 

0-2500 •f Primary 

Chamber 

0-2500 ' F Sccoodary 

Chamber 

-7.5 to 2.5 in. w.c. Pnmary 

Chamber 

open/close Emergency 

StacJ< 

0-2500 'I' SDAOu~et 

0-20,000 acfm St&Ot 

0-lS% CEMS 

Buildin2 

0.200 I 0-3000 ppmv 

CEMS 

0.1000 ppm• Buiklillg 

' 0-60% 

0 - IOOPM SOA Penthouse ' 

0- 100 Lbll'r' SDA Penthouse · 
< m 

(/) 

0 

0 

w 

0:> 

<0 

~ 

,-... '. .. \ : ..... : . ... ~ ,. . . 1 . . . ~ 

. . ~- '. 

, . TAble 1~2(eontftiued) ' .. : :ilzgi 2:·: :: 

CMS Instrument Specifications 

I Applleatlon . ··.' / ·.'·\· (.;s l'g,tr~l ... - r'l'llc R.imb--.riManucOotOrer r 

Unit NO., .... _--,. .t .::>.\ . :/:-. ~: >: ·.: .... ~. F.,: .•. ~- -. ·· • 

Hl&hBnl Llquld~~<' ':· -:· I ~wFlOWJ~~Cte< I Yr-315 I Micro Motion 

Hi&hB'lVLlqllfdDiiecfliljoOtr~:~·s~< · .: · 1 WT-315 DI 1 Woigh-Tronix Feedlale . . : .' .• .. · :. ·. · .. , 

Lo BTU Liquld P~ , .. :I MOHP!owmoter I Yr-316 I MieroMotien 

~~ LlqUld-Plroc!~~~~~ I ~~~~ :.:· . . 1 WT-315 Dl I We!gh-Tronix 

s~ Fe<!! Wolcht ,· .:· . . . . •'· ..... V{ei,b~~ 

~SOuclaP~~~ . . . --··- . w;iiJ,~; ·. .-. . . . 

1 PCCTcmpeta~ • :;~ ,.. ·· . '· r~·K..' ~J.o',· · . . . K . . sccr_.,..ur. · · · ~· : ·. ~le 

FCCPnasure ... : ; ._ ,. ... ... .: .. .. .

ltv Pooitio• -~ >->; .. · .f'~q.!tis+ ~ .. . · ,.. : ll)poK:. .... · B~I!>i~I T~~.'. :,, ; 'I'DOmiO&Unlc 

Combuat!on Ou Flb'!l' ~ -:; ·: '. 'J.4P Cell ' '· .. 

sta:~c a.;~~~~~;~ T~~c:" 

Stao!<O..~~ .. ..-

CoaoenlratiQII' . : . '· Multi~~ 

S~Hy<liOiOD Chloiidi .:·: . . ·. ' . . 

~entl)doh .· · · ,: ... ; · · · Pbot01lj$r 

Slick ou Mollt= 'CO~oti ·, .. ., 

Lime ShaY Plow~· .. 

Limo S,IUny DOO»it,- •• 

... . .. , 

MW.~~>< 

: I Xleasllif 

~ 

..... 

. . ~ ,: ~~;.,i,' ; F ;: . 

WT-304 Toledo · 

WT-310 Toledo 

TT-300Aill Modi""" 

TT·319Aill Modioon 

Pr-300 RD<emouill 

ZS-324 SqowW> 

TT-370 M<!dieon 

. FT-383 Rosemount 

AT-389 COSA 

AT·388B EcoChom 

FT-388 F"lid>or & Porter 

AT-969 . So1utron Mobroy 

a 

· Model 

DS-040 

WI-130 

DS-040 

WI-130 

AI40BXP 

Al40 

883-200 

883-200 

midF 

9007CGlB2 

833-200 

1151 DR 

ZI'N·IIYA1·2ZI 

MC3 

1001475 

7846 

,-·· 

Oporatln& Rance I Location 

0-3,600 lblbr I Feed Line 

G-60,000 1b I Feed Line 

G-3,600 lblbr I Feed Line 

().60,000 lb I Feed Line 

0-2,000 lb 

0-400 lb 

0-2500 •p 

0-2500 •p 

-1.5 to2.S ill. w.e . 

open/elo,. 

'().2500 •p 

().20,000 aoftn 

().25% 

1).200 / 1).3000 

ppmv 

0.1000 ppmv 

1).60% 

0 - IOGPM 

0 - 100 LbiFt' 

;;304 Hooded 

Feeder 

Solid Cbar1• 

Coaveyor 

Primary 

Chamber 

Secondary 

Chamber 

Feed Line 

Emer;eney 

Stack 

SDAOutlet 

Stack 

CEMS 

Building 

CEMS 

Building 

SDA Penthowe 

$0APonth01Ue 
< 

rn 

U> 

0 

0 

w 

CD 

<D 

.... 

. -C"""\ • . ~ .• . ~ ... :r:: . . : d .. . ., •• .-:~:::.'~\ • • :: • 

• ~~· t-. ... ,. ,: •. .:. • ~ .... -., .. . : , I, . 

;':' \ ··'?{~': ~·;j>~: .. /·.~_., .:.:> '<·.~·)·· · ..... ~:: .·\: .... ., 

Application J Initr J~Mnl · 

UDIINo. 4 ... . ' . .. Wute Fooclnte oo X-IO.Nocz!e Ma..~ 

Wute Peodrato to X-ll'Nozzlo Mut Plowmote: 

Wasco Focdraco to x.u NozziO MaiaF!owmoter 

Wute Poodnto tO X-22 Noz:zle Mus Ftowmet« 

Oam Sholl Peed WeiJhs · Load Cell (shuddcclaolids) 

Dram CoDve)'Or Solids Wetcht Load Cell 

AwciliAry Conveyor Solids LoadCoU WoJaht 

PCC 1'cq>entme Pyromoter 

SCC Temperature TypeR 

le 

PCCP-. I !,..1\UO 

'l'raDimlller 

~ VCIIII P..mion Porlticm SwliOh 

TRV Porltion Position S)lritcb 

I Cl:bonPudnte Peocler .. 

' Cari>oD IzUootion Ca:rier Ou Supply~ . l':<s111n> Swltcb 

Carbon Feedw Discharge PxemiJo PI'OII\It$ Switch 

" . . . . ~:-

.. 

.· 

, ... ,. 

'• . 

\· : .. · ... · •.. .--. 

·" 

Table i eo)Jiin~ed) 

CMS Itutrument Specifications - Ta& Number I Manufactur'tr I Model OporotJne Rang• I Loeation 

PT-129 Mien> Motion DSIOOS IU 0-7,000 lbih< Fted Une 

PT-138 Mien> Motion DIOOS·HY 0·6,000 lbih< Feed Line 

PT·145 Mioro Motion DL!OOS-SS 0..8,000 lbibr Feed Line 

PT-212 Mioro Motion DIDOOS..SS 0-1,000 lblhr Feed Line 

WT.OOI Toledo 8140 0.2,000 lb Ram Feed 

Hopper 

WT..014A Toledo 8140 0-1,000 lb Drum 

Convex.2r 

WT-148 · Toledo 8140 0.200 lb Auxiliary 

Conveyor 

TT-30SAIB beon Mcx\Hne4 44-99·P· ().3,000 ., Kiln ~Uet J.().J 

TT-317AIB C..ssel 3510 0·3,000 'F sec Outlet 

PT·300 R.ooem<>unt l151DR.2F ·9.0 to 1.0 in. w.c. Kiln Hood I 

ZSC426 Squa:M> 9007.cG2B2 openlcloae Kiln Face 

ZSC-316 Sq1111.,.D 9007 00282 openloloae E<n<raency 

Staek 

C-17 K-Tton K2U5 0-100 CatbOI\ lnjee1. 

System 

PS1A38A Dwyer 3330 Trip Points: Carbon 

± Sin. w.e. InJection Line 

Trip Pointl: carbon PSH-438B Dwyer 3215 < 3 p.siJ lnjoction Line > 13 P>ig 

9. 
< m 

(/) 

0 

0 

0> 

~ 

·> 

··; ......... • • •• ; • -¥'"'. • • , :,. - ... 

Applloatlop · .. :· ... IDslnUIWlt .. . UnUN .4(eoqU~uo ) ·;:Y:.>. •· . .'··· · .> • 

SDA X.18 OuOet Tcmpqature 

(Ba&f>oUIOlnlet Tem;>miiiJe). Tl1>• 1C . 

SDAX·190utlotTcmp~e · (Ba&f>o...,lnlet'Tempci-a6ue) TYP•~ 

'lhaDQoouplc 

Co!llboodon Ou l'lownle : .. Pilot TllbeldP Coli 

Stack Ou Oxn.., Conc~llnn Zlr-m.m Ox!do 

A.caly= 

Stack au Carbon Monoiido 

Conconnllon 

Slack Elydrop Ollmide Mulli<>omp'ODeal 

lmtued CoDceolratlon PI>-

Stack au Moisture Co-lion 

U1110 Slmy Plow !We Maa· Plowmotor 

Limo Slun:y Density Density 

Traosduc:er 

.. 

. . ·. . .. · .... .' 

• I .... . ·' .... . 

·.. .: :.~ .-· .. .. .. . .. •.· 

.. ·. .. •· :' ·. ·> ..... . : :: ~. 

. . . . ...... ~ ~· · ........ ~ :' . :.: :. ···· 

.... ·. :>;·· ,.: .. : .::;.. ~~::·: ..... ,. ·, 

\r) ·: .... ::-• 

,-

·. ·.··· 

Tibte l '(eontmued) 

OMS Wtrument Speclftcatioils , . 

Toe Number Manufactunr Model Opera«ng Range Location 

TT·417AIB Modicon 8883-200 0-2,SOO 'F SDA X-18 

Outlet 

TT..oii8AIB Moqicon 8883·200 0-2,500 'F SDAX·19 

Outlet I 

fT-5S9AIB Autcmali<>n Service IISIDRF2283 0-SS,OOO actin Stack 

AT-~AIB COSA ZFN·IIYAI·2ZI G-20% CEMS 

Bllildi"i 

0.200 I 0.3000 ppmv 

CEMS AT·SS6B EcoChom MC3 0-1000 ppmv Building 

0-60% 

fT-615 Fiscbtr & PO>ICr IODI47S 0 - SOGPM SOANoulea 

DIT-609 S<>larlron Mobrey 7846 0- tOO Lbll'F Lime Silo 

10 
. , 

operating parameter measurement devices at the Veolia facility are installed in compliance wi01 

l . this requirement. A description of the types of CMS instrumentation follows: 

Mass/Feedrate Monitors: .Liquid waste feedr.lles from tanks are m~ured by coriolis mass 

flowmeters. Direct inject liquid feedrates from tanker truck are calculated using the continuously 

monitored weight of the tanker. All solid waste charges are weighed using a scalelload cell prior 

to being feed to the incinerator. These m=urerileots are used to calculate pumpable waste, total 

waste, and constituent feedrates. 

For Unit 4, the output of a cabl>rated feeder is utilized· to calc~e the feedrate of powdered 

activated carbon, wruch is injected into the plemnn upstream of the bnghouses. 

Pressure/Differential Pressur e Monitors: ~ combustion chamber pressure is measured 

by diaphragm actuated pressure transmitters. The position. of the dm!per immediately upstream 

of tbe ID fan is varied to cOntrol stack gas flowrate and to maintain laln combustion chaplber 

.. negative pressure (draft). The prlznary coinb~on cbaniber J)~ is interlocked with-

.. :reeds . . . ;)· .: . .. ·-: . . .. 

/'1'::-- · : P~r Un.lt'2, pressure drop in the CY. ~de;r gas fe~ ~ ;;;~d and ~verted tO a feedrate. 

\., ... L · . 'The feedrate is used to calcuJate this feedstieam's. ~tributiOn to the chiOJine, low volatile 

metals; 81!.d semivolati!e meWs feedrates to tbC inciDerator. ·.· 

For Unit 4, preSsure ~tches are utiiizCd to C:nsur~ the carbon feeder discharge pressure, aDd 

the carbon injeetion' air blower discharge pressure an; V(itbin tlie design liniits. . . : ... 

. . . 

:: <: :: Tho~drop ~a piti>ftube(ni Uul ~a.:;ki;~USb'~nitoreel mid-used tO ~alculate 

: <:·:. :::: ,. · r \. ~~ :: ,~ :~{:~;;;~~ ;; L: .. !~~~~~~~~ :; ·:~~I~;~;; :.; >)/:.' ::: ... :;:; ... :. .· . ·': .,=:.:>· ·.: .

. : · ->· -.: :r~pet;mre M~' ;For:lJ.oits _2 . ;md 3, ~t:tb~oro~ $ used to~ the .. , · ·, · .:·:' 

... ~;: .. '·; '. ;: ··ooili ~~Ji'litiW;y;~ .i\ ~~Bpi~ ak<i J~at.t&: e:xii t.> tkSDA .. ~ ~'· .. ~; 

· ~;: : :} :::andi&1&pri.:bary.aem~irorfut;sDA hn·t~coDirott~. . ; : -' · . .. . · :. i·' . . .~ 

;??-~~:~:::·~~i:. .· i; ~ ;·~~;; ~~z:r~ ~iJt; ::LFk\~~~.~~· '. · ~. . ~~~ ,.·;: .' ' .ilrermOcOiipleB; in .. the secoildary·.cJ;amller •. · :Each ' SDA ouilet is eqUipped with redundant. 

· ;> •· .... ,, · theimoCOOples med'fo~ t~ coilti:olandmoniiciring ~the ~gbouse inlet' tempeca~ . ; . : .. • . . • . . . . •• • ' . • . .. :'· :t ... ·,· . . . 

~ . :. ... : 

.. ·.. : ... : .. .. 

:· . n 

VES 003899 
Emergency S2fety Yeot Po.sitioo Mooilors: The position of the emergency safety vent (ESV) 

( is indicated as open or closed by a position transminer. No waste or fuel can bt fed if the ESV 

position is "open". The Emergency Safety Vent (ESV) Plan provides details on the ESV 

systems. 

B•e Leak Detection System: A triboelectric sensor is located doWJJstreiun of the ID fan and 

monitors the relative particulate matter loading of the combustion gas exiting the bagbouses. 

Alanns and interlocks based on this relative measurement are indications of a potential bag I calc 

or faihrre. Procedures for setUp and adjustments to the bag leak detection system are not covered 

by this QC program. The Operation md Maintenance Plan provides details on the bag leak 

detection system. 

Contiaaous Emissions Moaitorbog System: The CEMS Cootinuously samples and analyz.c:s 

stack gas for the coocemrations of carbon monoxide (CO), Hydrogen Chloride (HCl), and 

.moisture usiDg a ~ticomponent i.nftved photometer. )he oxygen concentration is analyzed 

. imnltaneously using a zirconium .oxide anlllyzer: These data are used to calculate lhc stack gas 

· CO cocqcentration on a dry basis, corrected, to 7% 0.. The ,CEMS QA Plan provideS additional · ·· ·. :· : · .details on ·the CJiMs. · .· ~ . : •, . . . 

( ' . ..., . ~ . •. 

. ·..:'· 

..' 

: ·.. ~ 

: . .. : .. : 

r .... t· ' 

. , ·' • •:0·· .... ~~ ...... • ~ •• 

~ ;_..: :,.::.::: ~:: ~ ;~.~ .. :·:.:. . . .. \ ·, 

. . .... .. . . . ~ .· . 

' . ' 

... ,: -:.~ 

~; ··.:: • ..... :. ' . : . 

... ;' . ~: ·.:·~· · .. !·.· ... ·:: ·.·., .. ·; : ... . .. .. ·. '·.-:: 

.· :.: . . ... . . ·..... . .. ·"· .. 

. . . ' · .. .· 

~ .. . . . ........ ·. ·: ··.: ·~ · ' .. . J • • ;:., •• : ... • •• 

·12 .. 

. ' .. ... · .. ·~·~·-~: ... 

· . . }. : . . .; . .· ...... :~· ·. .. 

.. ····.· 

.. -- ~' 

VES 003900