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## A/Wto& T The rmocoup l e 

### /:f'oo q_o1'/? obs, TC = 0. 

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M ln ebs :; 0.9 X Tells. TC**n.~** ·R M int!-=- Mln ,..M - 460 

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### ' R Y'Jo•F**Cf)S J** **~·** Pirot rube IMP«tkvt TC Co/ibrarlon Pv EM SONX J9 Rew'slon txJn: MJraR-2013 

## VES015600

## S · Ty pe Pitot Tube In spec ti on and Pro b e Th e rmocoup le Ca lib rat1on Check PltatiO : 

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### ltl_"F**COS~ISF ;**  Pitor Tube Inlp«fidn. TCCo/lbntM P.,- £.f.l SCJP · (X)9**lllt~ iliM**  Oar• :**...w~a** 2013 

## VESOI56011 

### 2 3

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a li pe r 10 N um ber 

## 100C(0'3> I n i tia ls

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Error f o r eac h o f t he th ree d et e r minations must be within ± 2%

CDS · 18 Cuflpt.rs Per EM SOP · OU Ret?Sion l)or e.: Ftbrwty 2012



## VE S015602

## Portable Baromet e r Calibration Por table Barometer I d ent i f i ca t ion Refe r ence Ba rome t er Identif icat ion In i tia l s C<llibrated by Date I n iti a l s R

e

viewed by Date 

### !"' l\,**~1"1- t.l** **l~** 

# £1Jr o/17/13 l.ab<l r ato ry barometer r e a d ing (refe ren ce) ( i n H g ) Porta b l e barometer r ead i n g aft er co.-r ectio n ( i n Hg ) D i ffe r ence betv . •een r efe r en c e and p o rt ab l e after correct i o n (in Hg) Is th e d i ffe r ence StO.l l n Hg (yes / no ) 

### 'VI-''l 

# t**'Z'l t~**  

# [£**Vt.~**

ct>S · ZO Porlobk Barometer Per EM SOP - 008 ltevlsiort O<Jte 1 J(J(IJJ(N"f2006 Revi<we<t -l""""'Y 2013 

# l

I .JS 

## VES015603

### Bastrop Sca l e 

### Co1i1pa ny, Inc. 

### P. O. Drawcr2JOO B>Si rop, TX 7860 2 CERTIFICATION OF CAUSRATION (877) 32 1 -3443 F

a x( S I 2) 321 ·1 11 4 emait l n(

o@bawo ps<a!e .com w

wwb o.stropscale .com
CU STOMER# : 132950 

### SCAI.E #: 100008 3 10

MAKE : MOOEL : 

### S'.N . : CU ST OMER NAME : URS C O RPORA TI O N SERVICE**ADDRESS ~**  9400 AMBERG LEN BLV.D. SERV I C E CITY ST ZIP : AUST I N TX. 78 7 · 29 SARTOA I US TE4101 

### 2 1 450056 CAPACITY : 4100G . 'GRAOUATlO N SIZE : . 1 G TOLERANCE : 

### l OCAJlON I DEP T : M OB ILE BEFORE SERVICE : AFTER SERVICE : Come r or &;¢ lion

# Erro**:** 

# Q @ {Q() (}; Test W <rigl\ts Ap plied Scale Reading as Found Co rn e r o r Se cllon E rror : 

## Q 

# e ( ()c} 

# dy_ Scale Reading lOG 

# fO. 

# 0 y 100G 1000 G 

# ruvu.o; 2000G 4000G as Le ft 

## _i.Q U . Oy 

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# "' !l-00 0 0<; , 

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. OJ

T he we i ght s used for this t .. t are tra ceable to the Nat iona l Institute of Standards & Technology ( NJST)
. Testing eq uipment is certified oach ye ar with standards traceable to NIST. Credentials may be obtained by vloltlng**http ://www.baotropocale.** **com /crt~dentlals.htm** **l** Techni cian 

# &1;1**~** f0;._ l.lce nse II 

### <] 

## 5 / 

# b / D•tc (, 

# /2 f / 

# J 

# 3 Certificate #s of weights used:

## -L..**r.t..i 3.t.J** **:..J. C4)kt(/uf_** **'ft...JLL _,** **~.._ s.L...\!!(..~-** **-------** 8a•trop SCale Co. , Inc. TDA S ervice 

## a Inopect lon License #245519 BSC I FORM:**~** 1 -38



## VES015604

# Ba lance Calibration Ba lance 10 ,-,:. 

### Lj I O!llf I ni

tials 

# II¥ 

# \f:> calrbtattd by O.to 

# 6-1.;·13 btema1 Contrllct« Oate Ini ti al (allbratlo n

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## "\o<S'-! zoo 

# <f."'' ot;3 500**~~()I)~** 1000

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## 10 01,.1.'-{ I n it ials 

# !X.- R.tvtewed by Dati**1-~-11** P e r EM SO P.010 , 1t1.11 b.al anc;c c.aflbratton i S

good f&r one v u r , Expiratio n Date: Q(p - 

### "2 '7-''Z. 

### Ol '{
B alance Re idl na**c::etf)~ble** R a na e (&) 

# ,,, c;o.o 49 . 9-501 

### too-0 99 . 9 . 100 1 

# <aoo .o 1.99.8 • 200 . 2 

# t;o o.o 499 . 5. 

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1
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## VES015605

## '

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### nAI**ra rDE** **__, i**  /l/I IJIJadoAmorica 

### J:L:I- - . $j)oclol!y Closes 

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# @Scott · RATA CLASS Dual-Analyzed C4/ibration Sta n dard 11426 FA I RMONT PKWY . LA PORTE. TX 775 71 Fox: 281-474-8419 

### CER T I FI CATE OF ACCURACY : EPA Protocol Gas Customer P . O . No. : IJRS UIIS CORPOM llON AIR UO U IOE AME!IICA S PEClAL TY GASES LLC D<lcumen< t : 4142955().001 1 1 4 26 FA IRMONT P K WY LA PO R TE, T X 77671 9400 AM BERG L EN BlVD A USTI N T X 7872 9 

### us
Prooedu ce 0 · 1;**Sep ~Wnber,**  1 997. CyllndOr Number: AAL4460 Cylinder Pres sure • • • : 2000 PSIG Certlflc otlon Dote : 2 6Apr201 1 COMPOI'IENT 

### PROPAN E AIR CERTIR ED CONCENTRATION 1-.1
•' • 0o**I** UU: wtlotl**G~ iodo** **l** PIM 1 \! rt ft bt l ow I SO pt}O . 

### 2 1.1 PPM · BALANCE 

## •• Anatv*• • accuracy i t bllseCI on l htleQIUhman\S oi GPA rtotooOI**~o~•** G1. Scp1emb.r 1897.

ANALYZEfl READINGS CONCEI'f!"RA TION &8.80 PPM E >tP . Doto : 26Apr2014 Batc h N o: LAP0039832 TRACEABIUTY 

### Direct NISI 

### elid VSL

tZ • Zoro Gas A· Refe.-ence G&s f l est Gas , .. correlat io n CoeH tCIOflf) pf!OPAHE o.ta: 28AQr2011**RM;~cnso** Unit: PPM Z, • 0.000 00 ft 1 •35 9S4. 00 T1•7865.000 R2-35947.oo z2-o.ooooo n-78 74 . 000 Z3 .. 0 . 00000 T3•7t70.000 R3-3!593:2..00 A!! ,**~t:-.1!5! :**  21 . 10 Pf'iN



# \
\ APPROVED ' Second Triad Anal'y&is Conc;<.tncration •A • 8x + C• 2.**+-O:~t'3** + EJ.4 r =0..8009H8 3 2 Conitang: 8 • 0 . 00269222 D•



# . ...... •.. ..._ 

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### •



## VES015606

### Air Liquide America Specialty Ga ses LLC

rJ AIR UOU I DE

114:1**F'A~l** PKWY. I.Af'OR'Tt. TX71S71 f't!Orlkeo:I.Z4U7J' r: • ;281 ... 74-i14 \t 

### RAT A C LA SS**Dua/..Ant~ly:;ed** C•librolitJtt Sttutdnrd 

## CERTI FICATE OF ACCURA C Y : EPA Protoco l Gas A s-uy l,.abQ r •tol'}' • PGVP V endor 10; A32010 AIR UOUlDE .V.'ERCA SKX: IAL T'V CASES U.C 1 1011 rAIWOHT PI<WY LA f'OIInt. nc nsn 

### Page I of I

!A NA LYT I C AL INFORMATION ,_,_ _ , G,

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___ _ _____ ___ ACC URAC Y '' "rr- 1\- EIQ:l
. Date : 22Ar'2011 8*'Ch Ho : Url't'OlStll TRA CE AB A. ITV**o~~e¢t** NlSt and vaL

T YP EISA. M NO. NTRU1Ht !XPIRAT IOH O A T

E 020cl:o' OU C YLINDER NUM BflR AI.M!Ha&.IO C ON CI!: N TR A T K>N 9UOPPM COMPO N E N T 

# ...... 

# _ ! N STRU MEN T A TI ON tNSTRUMe NU •OOEl/SERIAU**~YJHP~97ol** I!'< NALYZER READIN GS fltsl Ttt.d AIWIIysis PROPANE 0.**~fO~U.:JISIU 11~01111000** **R1-.»7«J.. OOn** **~IOO** RMlJIU 00 D.=O.OOXI) f2ooU01100 n-o ooooo n•·· •-4aooo**~1111 t3.oo**  A'9 ,**~liOn '**  U JIOPf't " Sp4tcla l N o te •: (Z•Ze ro Gat R-Rtf trtnot Gas T•T e at Ot• r=Cof rt l at.iOn Coef!'icitnt} Second T rf ld ArQiys,ls Cell)rttion Cwn**c:r...o.r.~--~ ·.£M** **,.._ ~-~-**  eorw.w. A*4..a:1"5199t7**~402001118** Qo**~ ~·**  Tlio**~10t'1411 •**  tw,a:s beW1**~~ ~** **•!lho llt** **~fliiiJ)'F«** £PA to01'1\2H.:,I$AZ. COU'I -'N O T A,OS URS JTEtM UR6005 Q UALITY A SSU RAN CE**AP~OVEO** BY . SARAH H EAOERT { !IIQIIGII.IO Of\ R.t)



### http :// 172.24 . 1 28 . 1 1 / 3lasglrxcarp 17?Doc"() 483367&Cyi • AL899 &Us r-S HOP 1-39 

### 1116/2013 

## VES015607

### r:J AIR LIQUIDE I A l r L i q"'ldo Amerlet**ll yGn** **t,sUC** 

## ':1 Scott 

# RATA CLASS Duai - Arullyr.ed 

### C4Jibralion StandiJrd**11 ~28**  FAIR MONT PKWY . LA PORTE. TX 7757 1 Phono : 8()0.248·'1427 • 

### Fox : 281-4 74-8419 

### CERTIFICATE OF ACCURACY: EPA Protocol Gas Auax ltboratorv • PGVP Vendor 10: A32011 Customet P.O. No .: U RS U RS CORPORA '!10N AIR U O UI OE AMERtCA S!'i;CIALTY GAS ES LLC Document I: 437 11 369 ·00 1 11426 FA I RM ONT PKWY LA PORTE , TX 77571 9400 AMB ER OLEN SI.VO AUST I N TX 78729 

### u

s
Procedl.W"e 0·1:**Septe~r .**  1997. Cylinder N ..,.bor: CC111634 Cylinder Prtnure • • • : 2000 PSIG 310ct2011 

### Exp. Date: 300ct20 14 Batch No : LAP0051851 CERTIFI£0 CONCENTRATION !Moloo) 

### 21.3 PPM ACCURACY"



### ... ). 1 'II> TRACEABRJTY 

### bored N I ST ond 

### VSl BALANC E

• • • Do I'IOt uu \lofMin cv lincl.,**~·Mot~•** I• bttow 150 ps !g , •• Ar\llyoc1ctll tec'Jiat:Yk bs!:.O ond'le r..-emenu o1 EPA PmtOOOI**~G1 .** **Stp~** 11:97 .**~)'UN)ER** N U MBE R A.LM0131540 CONCENTRATION tl . 80 PFM DATE !.MLCA LIBRATm OIOe.t2011 CO MPONEN T PR O P AN!; AN ALYDCAL ""INCtPLE G4$ OiltOMATOGRAPHY ANALY ZER READINGS**..!:>='-""=:!!..==== '-rr.** **ero** 

### GaSlt -;'Jlllet ence Gas 

### r • rost Ges r=Ccrrellitlon CoeR 1..; t enU Flut Tdad An •lytla PROPANE Ott• ! 310ct20U itupo n t• Unl 1 : PPM 21•0 . 00000 fill = .C.OS e-0.00 T1•88&1.000 R2•4 1012.00 22=0.00000 1 2 •1829 .000 

### u =- o.ooooo n .. es12.000 ft3• ·U on.oo Aw . Conc•"!'!tlon: 21.28 PPM**S~N otts** **:** Second Tffbd An•fpb: eone.rmatlott •A • 8K + CJc2 + D x3 +b4 r •O.ft"PHa:Ji04 Cotastann : A • 0..00'78« 213 B=0.0023 tat5 C= 0=**.2_· ---** 



## VES015608

### Air Li quide America Speci alty Gases LL C 

### Page I o f 

### I**AIR** 

### LIQU I DE 

# ":s.· scott

.. ll .f@fAIANON f .. M.W"t , LA I'O«ff. TX n$11 "'-: 100-Z4.i<t:l7 f'$11 2el-411-4-&41* 

### RATA CLASS Duoi-ANIIIy :.trd Ci lflbNition Stamhml 

### CERTIFI CATE OF ACCURA C Y: In te rf ere n ce FreeT" Multi-Compo n ent EPA Protocol 

### Ga s A&Ny**~** • POVP Vendof D; A320t t A'StliQUU N AIIIIICAIN.CIII\1.TYGASf.S.llC**1H~i FAI~** **U0t.frfJ/K'IN** lA POR 1!.TX 71&11 ft.O . No. : STOOC**~· ~001**  

# """- \IRS COfiiiiOAATlOH MC»AMio!MU.H ot.VO A UIT'H f)( l j'l'29 

# "' ANALYTICAL I NFORMATION Gil Type: C02,02,BALN !_

___ ________ _ ___ _ ...J Cyih:Mt NymtM r: CC11M6S Cyt..., P,..aurr- : tNO PS!I;i CO M PONI!.Nt C:AAIIOIJ I>l (IX I 1:e OXYG:Ctl Nl'!J.OGCN CERnFlEO CONCENTRATION ( Mole&) b.2 •**22.~** ' [OO.A9;£!
l}lEfER£NCE STANDARD
[ NSTRUMENTATION**ALYZER** READINGS OAT! LAST CAUBRATED 

# """""' 

# .. """"' ACCURACY''
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CO NCENTRA TION 17, 81 ,. COMPOHE'HT**A~6014** OI OXID£ O)C YGEH**20 ~** 
AHA.L. YllCAL PRINCIPLE 

# .,... ._, {VZoroGu R•Fte lerenoe Ges**Te~** Gat ,.Cctrel al on Coefficient) S.COnd Triad A nafyt; lf C aHbrad o" CuiV t

Special N ate li: llwo**to~ h!JOI\<UI.j**  Ml-. !'! ••wded -.tt\OUIIW$tiy Ptf [I'AWl"R2l-2':3lS42_ URSOaQ 00A5110 : Dt.WPT , 60 OEG.f !CiUAUTY ASSURANCE**~niiA•III•C!Ct~+~** r .., .

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# ....._**~.u.t.OOf~ ~-7t.:I!IOOC.**  o: £2;



### htlp : l/ 1 72.24.128.11/alasglrxcarp 17?Doc=0 40 1904&Cyi=CC 189665 &Us r=S HOP 1 -4 I 

### 111 6/20 1 3 

## VES015609

### Air Liqui de Am eri ca Sp ec i a lty Gas es 

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27Jun2012 E xp.Dat• : 27Jun2015 Ba1 oh No : TR0 0 0609 70 COMPONeNT P

ROPAN E A I R CERT 1Fiet>**CO CENTJIA~ON**  ( Moles ! 

### 8 .43 PfS ACCURACY• • +I· \ 'i VSL BALANCE • • • Co net w.e**~~Ind.,** ptu&foll'l Ia below 1 ISO,....., • • Aft' I V'k<lt • tC\II'IKJV 1:$ bOIJ
- td 01\ t hl r•qu lr4 m c wnt o f EP A ProtOI.tO I ,.. OCtdiJI• G1 , 8op1.embtt \ 997 .**ONC ENTRAnON**  

### -. ; . so P"Pt.! PA 1'E LAS T CAUOAATED**l4Jt~,2012** ANAL YT&CAL PfiiNCJPt.E t eti ll'\D ANALYZER READING S (Z • Z ero Gn R- Ftiiferen e11 Oas f • f est Ga. r • Cor:elauon Co efhetenU

### !82.~~~~--**==~~7-H~-- o.,~** **:** 2 7 Jon 2012 Rd;IOM:e U nlh AR.I!A Z1 • 0.AlOCXlO AI =2:84 10h. Tl -22:2 818.0 ft2•M4Ca6J . U•O .OOOOO T2•2219$4 , 0 Z3•0.00000 'f'3 c221 1'1'1. 0 Al • 2B23S81 . Avo.**Co'leenu~vol'l: &A:Z~**  PPM



# (___

# OM~~ IS 4 N073 92 A PPR OV ED BY: 

# --. ,.,.,,.,_, n-- - - - - JE F F dtOTEAO Pal.)O 1 o t 1 Conc tnl rodM• ii.**~e~~"' C.** **~t l·**  .. V d"' f.lt.& 1•0.9 999**ec~c~ u:**  A •0.0441IIt33 8•3 . 851181-05 C•O**~51** 

## VES015619

### Air Liquide America Specia lty Gases LLC 

### Pa ge I of I

lt QBFNIWOHTPI<WV . lAPOft'f'ft , 1)( 71$11 Pt'<OI'W**C!U~~ <.Vt'rf.;**  ::ut-c'l6·&4l0 

### RATA C LASS D uui -.A naly- ..e

d Co librr.rdtm S uuulai'J 

### CERTIFI CATE OF ACCURACY: Interference Frc eTM Multi-Compone n t E PA Protoco l 

## Cas**AI••~** labor110ry . PGVP Vtndot 1&. A320 11 o\!M LI DUIOE ,\M[It(;A SI"ECW.T'V OA&ES U.C**11 ~,~fi!M"(**  LA ltQIIn£. 1X IT1f t PO . N o.:lSl OCK**~~** f : +f<Oil!&C01

@ ALYTICALINFORNATION Gas TYJ>t : C0 2, 02, , BALN C)'lln6ef N umbe r: CC16MIS C)l tlndw P te:Huft• -: li50NICJ CO MPONENT CM9o to DI OXIC! 

# . .,. 

# ... C!! RTIFlEDCOHteNTRATtoH (MOles) 11'. i • 

### u.s • 

# ·- .,....,.,.

REf ERENCE STANDARD TYPEISRM N O ,**Nl~** 1e00 

# ·-- ) NSTRUMENTATION INITfWMEHTIMOOEliSEftlAU 

# ............... ...**~Xlt&4N701tt•** li\NAL YZER READ I NGS

' QUALITY ASSURANCE APP R OVED BY : SARA H HE R8 S H T**~-gnetwc** on tile) CYliHOER NUMO ER ICO:tftn 

# ........
OATE LAST CALIB RATED 

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### c .......... URS COWOftAliON t400 ..... i!.MI..C:N at\10**~lXJt'2t** 

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Exp. D11to: 1 $ tlkl0tll Sitch**No! ~**  ACCURACY"' • 1- u . TRA CEABILITY Pirect N I $1**~d** V S L Di roct lU51**~.nd** \I$L •1- lt

COHCI'!N T RAT K>N t 7 .&1tf COMPONENT CAAIION OICOOOE 20.e:IS 

# '""'"""

ANALYT .C: AL PftlNctPLE rn• 

# -•me**COIIOIII'U*~--911•ClQ-tOJ:l.*EM** MQOIIrfE · I Ccn Mw.U: 4 :0.0(1()00C•O 14 CI!III\!· 1 C)o1.t13 UE.Z**o-o~~ f-o.oooooE** **~ C~o9w~;)-~**  

# ,._,. COMI.,U:A;:.o(I.OOtO ] eG**24~7 15&1111**  C• 

# ... .**http ://** **l72 .24.** **128 .1** **alasgloccarpi7?Doc=040 904** **Cyi CC**  

### 18966 5 &Usr=SHOP 11 1 6/2 013 

## VES015620

# r.I.AIR uau1oe: 

# I ""UQ""'""'"""'"

# ~s**·** 

# .·l s cott · u.:1 Sj>odol\y GasQ U.C 

# RATA CLASS Duai-A11alyzed Calib ra lio11 St011dard 1 280 COMBERMER E STR EET. TROY , Ml43083 PhOno: 2411-689·2950 fox: 246 · 589 · 2134 

### CERTIFICATE OF ACCURACY: EPA Prot oco l Ga s Assey Lllboratorv • PGVP Vel'ldot 10: A22012 AIR LIOUIOE AMERICA SPECIALTY GASES U.C 1 290 COMBERMERE STR EE T TROY, Ml 48oa3

Pn>cedwo G-1; Sopteml>e<, 1987. Cylinder NOO>bor : CC 43355 Cy l inder Prenura• • • : 2000 PSIG P . O. No .: 69561·70.85000 Ooovmunt # :**4~936248·042**

C.rtification Date : Cutsgme r ClEAN AIR INSTRUMENT RENTAL JACK B I ONDA 1 10 TECHI..O LOGV DRIVE RIO PARK. FINLA Y TOWNS HIP CORAOPOLIS PA 15108 

### us 16May2012 Elcp. Date: 16M<oy2015 Botch N o : TR00057923 COMPO NENT 

### OXYGEN CARBON DIOXIDE NITROGE N CERTIAED CO N CENTflATIO N !Mol .. I 

### 10 . 

### i " AC CURA CY " +7·1% TRACEABILIT Y Direct NtST end VS L D;rcct NIST ond VSL 10.0 " 

# +I·'" BALANCE • • • Do Mt ww wMn cy llndef presour• is bek)w 1 &0 pa.ig. • • A.Miytictll KCWII:Y tl bisad on en.**rtQIMf~t** ot EPA Protocol Procedure 01. So!plM'Ibtf 1 997 . CONCENTRATION 23.20 " 2.3.04 " D

ATE LAST CALIBRA TED 07MtyZ012 07Miy201 2 CAMOH DOOXIOE ANA LVnC A L P RI N CIPlE PAR A . MA.G N ETIC 

# """' ANALYZER R E

ADINGS**..:::== ===** **==='-,.,~-=-ze ,;:;o** **-r or.os** **..- uR** **-;;.-• Rilerence**  Go s l • Test Gns 

### r = Corroio tton 

### Cooificle n d
OXYGEN**~101** 1"Mey20 1 2 Response Unit:% Zl•O .OOOOO R1•23..210000 r1•10.09000 R.2•23.20000 U•O.ooooo**n~to.oeooo** Z3 •0.COOOO T3•10.0&000 R3•23.20000 Ava. Collt: l! n -rati on: t O .O fl % CARBON DIOXIDE**oar.~:** 17May2012 RdponM Url't.: aN z-t •0 .00000 R 1 •88. 10000 Tl =00 .30000 A2•99 . 1 0000 Z2•0.00000 T2•60.SOOOO !.3•0.00000 13•80. 3-0000 R3•99. 1 0000 A\00 . Conct-ntmlcn : 10.01 "

Page 1 of 1 Conc.enc r a tloi\ •A • Bx + CX 2**+0~t3** + hA**f•0.99t~7** Comune.t : a • 1.ocn 10&266 0 = 0 A•o0.04233.Nt C•O 

### <•0 ConoMV&tiol'I•A +Bal. +Otl+ 01C3 + b4 r•0..99't887**Ccnn~nu: A•.0** **11411!1** 8 •0.138 0164952. 

### c**-..0.0002~7%** D • 1. p741E.·OS C .. 

### o

1 · 53



## VES015621

# VES015622
. pdfOg ul e i , D avid from: Ogul ei , 

### David Sent : Wednesday , March 

### 2 6 , 2 0 14 2 :27 PM Woo klms, Jan e To : 

### Cc: Ogulet. 

### David Subject : RE : Ph one Ca ll Reco rd 

### 3/26/ 1 4
- Da t e COt r ected


### Call R eco rd Caller. D avid**~lei** 

## Date of call: 

### 3 / 26/ 14 

### Time o f 

### eall : I :49 p m PutpQse 

### of CaU: To obtain update d information on th e co mmercial av:Ul ab llity of the multi-m e tal s CEMS. Call wi th : 

### Krag Pett e rso n 

### Ph one no. ( 503 ) 

### 670-83 3 5 

### Companr : C.oopcr Environmental Services, P onlaoJ,**O~p,<>n** I) 

### Any**ddition al**  u pdat es on th e co mme rc ial a vail a bility 

### of the**mul ti** **et:~ s**  C!Th !S tha t you would U k

c 

### to ad d 

### t o 

### i\ k Coo per's? • A Chinue company {Sale Hero) has purchased a majority stake of Cooper Environmental Services • Cooper Envoronmental will be shipping one stack unit In April/early May to be insta lled at a Chevron facility In Nigeria .**E~pect** the unrt to be& l n operating 1n mid-5ummer • Currently working on 

### a spectal project for SCAQMD {2 secondary lead smelters) . SCAQMD wUI 

### be renting the units for a period of 10 months starting around Decemb4tr 

### 2014 . Plan to do side 

### by stde method 29 tutina . Also hope to deploy the Quantitative Aerosol Generator {QAG) at this locat ion at some point while the unJtis deployed there. SCAQMO contact Is: p hi lli p fi ne 

### 310·486
-4 2 9 5. Email: pfine@agmd . gov . • No stack unit is currently runnlnc at a facility. • Currently have a number of 1mbient units in China, Australia and othe r countnes . 

### Z) What w o uld 

### be the approximntc: cost of installing and testing the three unitS? How much would i t 

### be fo r on< unit ? 

### Do you 

### ha\'e a sample invoice you can shar e with 

### us?
• Each unit's purchase cos t Is about $2SOk. Approx . $900k ballpark t otill for 3 untts includong onstallotion and testlna . Would ne ed 

### to visit the focllity a n d do an appraisal o f what is nee ded . • Operating costs primar i ly come from filter tape . For continuous operation (15 min samp les), filter tape would cost $780 per roll per week {S4lk per year) per unit. Total operating c<»t Is approximately $50k per yeir per 

### unit • Kraa will look Into possibly shaflni a copy of the quote they recently did for Chevron (S3SOk project) but that project Included 

### a number of spare pans that m•ght not be needed for the average project. • Krag will share the rental quote estimate for the SCAQMD. That quote Is public information.

l 

## VE S015 62 2

# VES015623
. pdf

### Og ule i , 

### Davi d From : Sent : To: Cc: Subject : Paddock, 

### Nancy <nancy.paddocl<@veolia
. com> 

### Tues(l ay , March 

### 04, 201 4 6:2.8 AM Ogulel, David 

### Denn is Warcho l Re : T itle V Request 

### regarding m ateria l 

### processing areas a nd emissions cal cula t ions 

### Yes, Da v id, old habits 

### die bard. We' v e been through many name changes but TWl was the ori gin al. I am i o fac.t, 

### referring to 

### Veoli a in my origina l 

### e-mail message. Pl ease l et me know 

### i f you n ee d additional infonnatio n regardi n g this request . Th ank s and have a great 

### da y ! 

### N ancy Nancy Paddod< Environmenta l Engineering Specialis t Veolia ES Technica l Solutions, L.L.C. 

### 7 Mobile Avenue Sauget, IL 62201 618.27 1.2804 (x-115) 618.271.2128 (fax) 

## Please note that my e-mail address has changed : Nancy.Paddoc k @Veolla.com This e-mail message from Veolia E5 Technica l So lutions, L.L.C. is for the sole use of the i ntended redpient(s) and may contain confidentia l and privi l eged inform ation. Any unauthorized review, use, disclosur e or distribution Is prohibited. If you are not the inten d ed recipient, please communicate with the sender by reply e-mai l and destroy all cop i es of the o r iginal message and de l ete it f rom all computers. Oo Mon , Mar 3, 2014 at4 : 28 PM, Ogule i, David <O!..'ulei Da\ldiU epa.go' > 

### wrote :

Nancr ,
The**~mail** 

### below rdc rs tO ' "1'\ X.T' 

### in m ulti p le loc ati ons. I'm assuming 

# rou are referring 

### to Veoli a 's 

### pcnnit 

### ond cs n mated emis s ions. I ( thi s r equest 

### i ndeed p e rtai ns to 

### Ve,., l ia, we will rev ie w th e r equest as pa r t nf th e re n ew a l perm i t appl ic a tion .
Th a n k you. 

## VESOI5623

### U.S. Emironmenrnl Pro«cti on Agency Re j1ion 5 J 

### Air & 

### Radiation D ivision 

## I A
- 18J 77 

### Wrst Jackson H lvd. 

## I Chicago, I ll in ois 60604 

### Ph one: (3 12) 35 3
-0987 

## I Fa!< : (3 1 2) 692
-2080

F

rom: Paddodl, 

### Nancy (mail t o: oaocv,paddock@yeoloa 

### coml Sent : Mond ay , March 

### 03, 201 4 1 :43 PM To : 

### Ogulei, 

### David Cc: 

### Dennis Warchol 

### Subject: Ti tle V Request rega rd in g mat eria l 

### processing a reas and em ission s ca lrulatlons


### H ello David , S eetion 2 .2(E)(3) o fTWr s 200 8 

### T itle V 

### permi t s tates tlJa t t h e 

### TA NKS program mu st b e use d to calcu l ate emissions 

## from MPI, 

### MP2 and 

### LPR.
Last year, a 

### consultan t rev i ewed our emissions i nve n t ory p rocess. T h e S u rface Evaporation Mo de l 

### r rom EPA GuldMCe E IIP Volo.me II:Chal)ler 8 Sec:Uon 4 .1 4. Prelerred and Altema Uve Methods lor Estimating Air Emissions from 

### Pai n t an d In k Manufactu ri n g Faci li ti es, Marc h 1998 . Eq uation 8 . 4-18 was used 

### to calcu l ate e,.ssions from 

### MPl, MP2 and L

PR . 

### The cons ultant compiled a n 

### average of 

## 5 years 

### of the most reecnt TRI 

### conc e ntrat i on data to determine 

### tile concemration of VOC 

### and 

### HAP in the waste, which was 

### then used in the E P A Surface Evapordlion Model ref erenced above.
TANKS is based on ro utin e displacement of liquids . The surface e vapora tion model is**ba~ed** 

### on the volatility and ability of a compound to evaporate from th e surface of solids and then be pick ed up 

### by the air in the building and carried to the atmosphere. 

### lbe evaporation method seems to be 

### more ap propriate for MP

### J , 

### MP2 and LPR; 

### TW I would like to ch a nge see t ion 2.2(E)(3) of the upcomin g pe nnit (or th e equiv al ent secti on thereof) to indicate the Surface Evap oration Mode l will be 

### used to calculate e missi ons f ro m thes e**so urc** **e-~ .**  

### This table compares e mi ssio ns calc ulated by botb methods for tbe same calendar year: 2 

## VES 0 1 5624

### TANKS Model 3tea 

### TPY lb MP-1 0 . 06 117 MP
- 2 0.02 44 

### LABPACKIREPACK 0.03 68 

### Evaporative model TPY l b 

### 0.21 424 0.1 I 212 

### 0.04 85


### I hope tbis makes sense . Please let me know if yo u h ave questions.
Thank you, 

### Nancy Nancy Paddock Environmenta l Engineering Specialist Veol i a 

### ES Technical Solutions , L.L.C. 

## 7 Mobile Avenue sauget, 

### IL 62 20 

### 1 618.271.2804 ( x-115) 618.271.2128 (fax)



## Please note that my e-mail address has changed : Nancy . paddock@\/eol!a.com
This e-mail message from Veolia 

### ES Technical Solutions, L.L.C. is 

### for the sole use of the intended redpient(s) and may contain confidential and privileged Information . Any unauthor ized review, use, disclosure or distribution is prohibited. 

## If you are not the intended recipient, please communicate with the sender by reply e-mail and destroy all copies of the original message and delete it from all computers.
3 

## VES0156254 

## VESOI5626

# VES015627
. pdf

### Og ul e i, D av id From: Sent 

### To: Ga m el! , Kim Wed n esday, Octobe r OS , 2 0 1 4 1 0 : 27 AM Ogulei , David FW: 2 0 1 3 ses presentations Subject: Attachments: Q AG S E S po ster presenta t ion 2013rev1.pptx; Sources of U n certainty in HAP Me t al Emiss i on Esllmates 0 327 1 3ggggggg . pp t

From : John Coope r [ ma i tto:jacooper@cooper en vi r onme n tal.com ] Se nt : Monday, Sep te mber 16, 2013 11:03 AM To : Garnett, Kim ; Bivins, Da n Subject: 2013 ses presentations Give me a ca ll and I ca n go thro ug h t h ese p r ese n ta t i o n s w i th yo u. J ohn A Cooper, P h . D. P resid en t Cooper E nv i ronmental Services L LC 1 0180 SW Nimb us Ave . Su i te J 6 Port l a n d, OR 

### 97223



## VES015627

# VES015628
. pdf

# Cooper Environmental Services LLC 

# Sources of Uncertainty in HAP Metal Emission Estimates: Assumptions, Probes, CEMS and Surrogates Source**Evaluat~~" So** **~iety ----..**  ....... .· r ___,. ... 

# March**28 2013** 

Cooper Environmen t al Services LL C 

# VES0l5628

# Outline • HAP Metal Emissions 

# "' • Uncertainties in Metal iss ions

- Actual emissions

- Measured emissions • Session 9: Uncertainty Details**App~icabfe** 

# Sources : Incinerators Coal-fired Boilers Mills Mineral Processing Plating Portland Cement Cooper Environmen tal Services 

# Smelters Kilns Welding 2 

## VES015629

# Key HAP Metals are Different • They typically occur at trace levels in feed, fuel, additives and emissions • Concentrations and potency

# ar**hly** variable • Ma y partition between vapor and particulate phase s to varying degrees depending on source chemistr y

Coop e r Env i ronmen tal Services 

## 3 

## VES015630

# EPA-Designated HAP Metals Tran s ition El ement C ancer To x i c**PM ~** * 

# N AA O S M e tal ** A ntimon y ..J 

# A r se ni c ..J ..J ..J 

# B e r y llium ..J ..J 

# C admium 

# " " C hromium 

# ...; ...; 

# y ..J 

# C oba l t 

# y ..J 

# Le ad ..J 

# ..J ..J 

# M an g an ese 

# " 

# " M e r c ur y 

# " N ick e l ..J 

# " y ..J 

# Se l e nium ..J 

# ..J 

# Other Non-HAP Metals of Concern Th a llium ..J ..J 

# Vanadium ..J 

# ..J ..J 

# Iro n ..J 

# Y ..J 

# C opp er ..J 

# ..J ..) 

# M ol y bd e num ..J 

# ..J 

# Zin c ..J 

# * Identified as a significant contributor to observed PM bealtb effects . **Ge n e rate r e a c tive o xy gen s peci es, w h ich cau se damage to cell structur es. 4 

## VES 015 631

# Data Quality Objectives of Emissions Monitoring for Metals
Congress EPA 

# ........ Protec t P ublic Health 

# " MACT § 

# 112 of with Adequate M argin of S afety 

# "'**~** 

# AAA ( 1990 ) "\ 

# -<...,7 ' 

# c. Res id ua l R isk Metals are a significant contributor to PM Heal th Effec ts**/~** 

# PM Hea l th Effects 

# <:

Cooper Envi ro nmental Services 

## 5 

# VES015632

# EPA Has Said:
• Monitoring is part of the emissions reduction and control process 

# • Uncertainty minimization is best ac'hieved with more measurements of emissions • Reducing 

# uncertainty in compliance mea s urements produces quantifiable benefits 

# Knowing sources of uncertainty and their general magnitude is important to reducing those uncertainties. Cooper Environmen t al Serv i ces 

## 6 VE S O J 5633

# Examples of Uncertainties • Typically Small (<10°/o) • CEMS single point samplin • FRM sample recovery • Deviations from lsokinetic sampling • Analytical sensor /procedure 

# • Potentially Large ("'lOO + o/o) • Feed/ fuel composition variability • Process / aerosol variability • Probe loss variability • Surrogacy assumptions Cooper Environme nt al Se rvices 

## 7 VESOJ563 4

# Actual Metal Emissions Variability

Feed

F u el 

# and Measurement Uncertain Differences between measured (PM or Metals) and actual metals emissions Meta l s Em i ss i ons Mea s urements
Pro cess 

# 1 )j Emissions Controls 

# I >I

Additives Cooper Environmental Services 

# Stack

8 

## VES0 1 5635

# Example: HWI Compliance Demonstration 

# • Initial Tests-**Performanc~** 

# "Trial Burn"

- Determine transmission**effici y**  

# (T) • Metal spiking (F s

) 

# • Method 29 measurements (C = M/U)

- Define plant operating parameters 

# • Continued compliance demonstration

- Maintain plant operating parameters

- Monitor Feed Rate (FCi) 

# • Periodic "Stack Tests"- years between tests Cooper Environmen t al Services 

## 9 

## VES015636

# HWI Stack Emissions Model 

# E TF VA

.. 

# \ Emissions 

# Feed Rate Area Velocity Stack Concentration Assumptions: 

# Transmission Efficiency -Transmission efficiency is constant and independent -Metal feed rate is accurately known Cooper Environmental Services 

## 1 0 VESOI5637

# Assumed/Calculated Concentration of ith Metal 

# / ck Velocity & 

# Area**~** 

# ........... *"**c~** l 

# F.oT.o 

# I z z 

# VoA

Metal Feed Rate ith 

# Meta1 Transmission Efficiency (Performance .tests) Current Operating Conditions 

# r )

Cooper Environmen tal Services 

## 11 

## VESOI5638

# Calculated Concentration Based on Feed and Performance Test Data Measured Method 29**.,sumed** 

# = 1.0 

# c o = F °C ( l 

# v t

- 

# M : ls g s J R e 

# u t F / C : 

# v o Gas Sampling Bias Feed Sampling Bias Efficiency Representation Bias

Cooper Environmental Services 

## 1 2 

## VES015639

# Uncertainty (a) in Current Calculated Gas Concentration for ith Element

- -- 1to1 0 % (j 

# =Co C

o . i 1 

# O" p 0 

# F o 2 

# +1 -.**M~** l 

## () f 

# C ; 

# c ! l 

## (J 

## U' 

# + .**u~** 2

2 ()



# +I 

# F; 

# F ' s 2



## 2

## ~ 

# 1to10 %

Cooper Environmental Services 

# a s f 

# sf 2 

# <> v, 

# +.**~** 

# 2

1

# h l (J 

## R e 

# R e

, 

# .. --- 

# .. + .....



# .... 2 (jvo 

# vo

1 3



# VESOI564 0

# HWI Uncertainties e Measured Parameters ( <1 

# 0°/o, small) • Bias
- Sampling Stack Gas**lO~mall)** 

# • Bias
- Sampling feed, fuel , etc. (--100 + 0 

# /o, 

# large) • Bias -Representation of process , controls, etc. during trial burn testing (
-- 100+ 0 

# /o, 

# large) • Deviations from Assumptions (
-- 100 + 0 

# /o, 

# large)

- PM 

# surrogate for metals emissions Sma ll 

# t

L ' arge 

# -99o/o of Uncertainty in Actual Metals Emissions is Due to These Large Sources Cooper Environmental Services 

## 14 

## VES015641

# Estimating Magnitudes of Variability ali.d Metals Emissions Uncertainties -E MPLESCooper Environmental Services 

## I 5 

## VES015642

# 1 PM (173) 

# w SPM 

# (2.4) 3PM 

# (11) 

# Arr ;:;;' 1 , 000 E


# ..... 

# .., 

# .=. 100

.... c 

# 8

.... 

# ·c: 

# .. .. ¢ 10 1 

### 0 

## • • _::._ 2,3 4 5 ng/m3 - 4%o f 70 year 

## one in million concentration

0 2 4 6 8 

# w 12 " 16 18 20 22**~** 

### Time of Day 

# Louis E 

# Monitor 

# xam e 11 AM - - 

# ind Dire (2,345)(Concentra s 

# tion ng/m 3 ) 9AM 

# (0.76)

Cooper Environmental Services LL C 

## 1 6 

## VE S0 15643

# Time 

# WD 

# ws - 9 118 0 . 9

Cooper Environmental Services L L C 

# 2,345.00 173.00
1 7



## VES01564 4

# Hourly Lead (11/23/09) 45 350 40 35 

# Two thirds of totallead**~ ~**  

## 300



# - "' E 

# ' 30

# ~ 

# - 25 u 1: 

### 0 

## 20 u 

# , nl Cll 

## 15 ...J 

## 10 

# W irul Direction

'

# ~ ' 

# .. -- - • Jl 

# - / 

# - - 

# -- -
... 

# _., v

.... 

# • 2 5 0 

# c 0 

# · - 

# ... u 

## 200 Cll 

# ... 

# c 

# , 150 1:

# ~ 100 5 0 

# 24- h o ur ave r a g e :;: 4 .6**~Jg /m3**  

# LLa 

# . J J r- 

# .-- 

# . - li - . - - .- - ' 

## • 

# so 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0**~** 0 0 0 0**~** 0**~** 0**~** 0 0 0 0 0 0 0 0 0 0 ,...; N <n <t Ill \0 

# " 00 

### en 0 ,...; N <n <t Ill \0 

# " 00 

### en 0 

## ..... N <n 0



## ..... ,...; ,...; 

## ..... ,...; ,...; ,...; 

## ..... ,...; ,...; N N N N 

# Ti me of 

# D ay
Coo per Environmental Serv i ces 

## 1 8 

## VES015645

### 60 %
S

O

% 

# Percent of total Mass 

# & Samples for Pb

40 %


# _ D Pb Mass _ 

# ' - II 1 6% 

# of samples represent 

# 87 °/ d of Pb Mass 

# % 

# r N o . Sa m ples I**~** 

# I V"l

# ~ 

# - -- -. · - - e t e 1-hour 

# sample Q 

### 30 % 

# - 0 1- 

# 1 re resents >11% 

# of 

# - 0**~** 

# _ 1 Pb mass 20 % j
### 1 0 % 

# 11 T L[

0 % 

# J f;)"" f;)., <:)">- 1:)'\. 1:)., .... --:. .... <:> "" " ""I:) '\.1:)

### ::~,l:l <:S <:S ••• " ........ 

## o .... o o 0.., t- · 0 · 

## .._o .._o .._o .._o '"o <, 

### ">- 

## c.. "" 0 ..,**~** <;; 

# f;)" <:)..., 1:)'\. 1:)" .... 

## '>- 1:) . -' 

### "> 

### 9<:)**~** 

### • • . " M ass Category (t-tg) 

## Cooper Environmental Services 

## 19 

## VES015646**~80 .0**  

# = "'**~** 

### 60.0

# ~ 

# I ,§, "' 40 . 0 . 

# = 0 

# Probe Losses And BAM-Based PM CEMS Correlations QAG C orre l ation 

# 1 ! I 

### ' 

# QAG Co rre l at ion I I



## --**~** I 

# I 5 80 . 0**~ ~**  

### 70.0**~,.~** I 

### y 

### l.O Sx- 

# r:rs**x~** y 

# = l.0 7x
- 2 96**o-!'":~T~** ;. 

### I I 

## < 60 . 0 

# 1 It ' = 0 . 994 

### R ' 

# = 0 . 985 .... 

# ! so.o

· I I I '

### ~ 

### 40 . 0 

## -- ' I 

# 2**~** 

### 30 . 0

# ~20**.0** -- i ' I 

## <-' 20 . 0 

# < 

# 6 0 . 0 

# l 0 . 00

# ~ 80 . 0 

# I**~** 

### 60 .0 Cl, 

## ,§, 40 . 0 u 

# = 0 

# u 20.0 0 

# < 0' 0 . 00.00 

## --**~** 

### 2 0 . 00 4 0 . 00 60 . 00 80 . 00



## B e t a # I Co n e { m g/ w s e m ) 

# QAG C o r re l ation 

# 3
y 

# = 1. 06x - 0.364

__ ...:.._ R ' 

# = 0 ; ')93'-

• • 4 _

.. 

### '


### 20 . 00 40 . 00 6000

B e t a 

### # 3 

## Cone (mg/wsc m ) 80 . 00 

# I o- 10 . 0 0 . 00 . 00 20 . 00 40.00 60.00 80 . 00 

## B

eta # 

## 2 Co ne (mg/wscm) 

# SloRe CEMS QAG PS-11 

# R 2 1 1.07 1 . 17 >0 . 98 

# 2 1 . 05 1 . 19 >0 . 98 

# 3 1 . 06 1 . 63 >0.98
20

VES015647

# QAG Calibration of BAM PM CEMS

Stack 

# Aerosol

M S 

# M ea s u r ed Con e . Gravimetric Mea s urement of PM Depo s it

Probe Transport Filter 

# PS-11 CALIBRATION

Probe Tran s port Filt e r Tap e 

## \ I 

# y PM D e po s it Not M e a s ure d PM M e a s ure d via BAM - Ba se d CEMS R es pon se 

# Probe Loss Cone
. 

# :PIC CEMS Measured Cone
. 

# ? Cooper E nvironmental S erv i ces 

## VES01564814**I~ ~**  10 

# ! e •**~** ::10

### ~ G ;;; 

# .**~** 0 0 

# Light Scattering PM CEMS on HWI Method 5 vs Sigrist CEMS



# - 

# --- • - 

## • • • • 

## • 

## • 

# __5 1ope 

# = - 0.2 'l__



# - - 5 1 0 t S**~0** S l!lfls l mg ! m l



## -g :.1 

## a. §. I) <( 0 ::10 

# ... •**~** 

## •



# -



# -

- -

-**~5** 

# QAG vs Sigrist CEMS

• . ., 00 1 . 200 1 . 000 

### y_ 

## = 3.03 1 X • 

### 0.032

# · 0 , 800 0 . 600 0 .400 0 . 200 

### R •= 0.989

# ~ 

# - 

# __,./**~** 

# / 0 .000 0 . 000 0 .050 0 . 100 0 . 1 50 0 . 200 0 . 250 0 . 300 0.350 0400 0 . 4 50 Sig<isl Response ( PLA) 

### Cooper Environmental Services 

# 22 VES 015649

# Comparison of Light Scattering PM CEMS (PS-11 Calib.) with Series ofM5B Measurements (Wet.Stack) CEMS S lop e Int e rc e pt R 2



# - 1 + 0.19 + 2 . 7 0 . 74 2 + 0.24 + 1.8 0.80 M5B**c--~ 0.36**  

# + 6 . 2 0.38 

# % M5B Probe Deposit = 95%

Cooper Environmental Services 

## 23 

## VES015650

# PM May Be Dominated by Sources Independent of HAP Metal Sources**~** 

# PM can

# ~ ... 

# by s l urry bl ow -b y

Feed Sc r ubber S l u rry Process 

# I 

# ;l Co ntro l s F G D 

# Stack Fuel Add iti ves Cooper Environmental Services 

# 2 4 VES0 1 565 1

# 1



# -**~** v

0

E 

# !



# - c 

# Coal-Fired Boiler - Wet Stack
M29 PM v 

## M29 Cr y . 

### l .8 8 1.oc . 2.'J977 R ' : 

### 0 . 9996 

# • 

# •

Ht1 tM &/rt'IJ I 

## M29 PM 

# v M29 As 

# •

· •



# ....**"""~"** 

# •



# • 1'\ 

# E

...... CD**~** 

# - Ql 

# "'

:; 

# i Jt 0 

# Method 29 Se v As



# . ... y 

# = 3.598x + 

# 7.1769 R

2 

# =0 . 9954

A

s**~J g/m** **)** 

## M29 PM v M29 Se 

# • •

I'M ( '"'",... J) 

## Cooper Environmental Services 

# •

25



## VES015652

# 10 5 I 

# 0 4

........ M ] 

# O J

# ~**~** 

# J0 2 (.) 

# g 10 1 

# u



# -**~** 

# w o**~** C5 

# l 

# O · l**~** 

# c.. 

# I 0 -2 

# 10 -3 

# Hypothetical Va riabilit y of 

# PM and HAP Metal E 1 n i ss ion s from 

# C FPP

A. 

# j'-' A C oal Blend C oal from A ddi t i v e Time (months) ........_...._ 

# _____ _ P M

--- S e 

# Co, 

# C r

VES015653

# 95°/o CONFIDENCE INERVALS FOR METALS Data Quality Objectives : Process Optimization, Compliance or Health? H W I 

# PM HW I M e t a l s
CFB 

# P M PM 2.s CFB Metals 

# I I

1 0 • 1 

# 10 ° 10 1 

# 10 2 

# 1 0 3 

# 104 

# 105 

# Confidence Interval**(J,~g/m )**  Cooper Environmental Services 

# 27 VES015654

# Estimated 

# Metals Uncerta i nties for Compliance Demonstration Options Opt i on s MMCEMS PMCPMS (w ith M29) P er iodic M29



# PMCEMS --BAM 

# -L . 

# Scat PMCPMS (w ith MS) P e riod ic MS S mall Prob e Sources Deposit *



# < 5% < 20% < 5% < 20% 15%

< 5% < 20% <5% < 

# 20°/c, < 5% <20% 15 % * Due to Probe deposit variability. 

# Process Metals Total Variability S urrogacy U n ce rt a inty 

# < 10 % 

# -- - 3 0 % > 1 00%
- 300% > 400 %
> 300% > 3 00 %

< 10 %

- 1000 % > 1000 %

- 50%
- 1000 % > 1000 % > 50%
- 1000% > 1000 % >3 00 %
- 1000% > 1000 %

VESOI5655

# Conclusions and Recommendations • Focus on obtaining a more representative samp l e by developing a probe with minimal P'Woss- < 5°/o 

# in e ith er wet or dry stacks 

# ' " • U ncertainty minimization is best achieved w it h 

# more, direct measurements - Multi-Metals CEMS • If the first two can be achieved , concern for p rocess varia bility is minimized Focus on largest sources of uncertainty • Process variability • Probe loss variability • Surrogacy assumption
Cooper Env ironmental Services 

# 29 VESO I 5656

# Clear Improvements

1925 

# Acentu - Pittsburg, PA, ()SA**1925** 1957 

# me 1957
1998 • Cooper Environmental Services From AWMA flies 

## 30 VES015657

# C\•

# VES015659
. pdfPROBLEM Tl'leff! i$ no NIST• l"rKM* c.-radon Met audl tundard to dial ... PM CEMS OBJECTIVES Evatuat. Md ck\1Sot;l 

### cu • HIST·l'nl<e•bto qu:tnUtattve aerosol t•n•r•tor (QAG) to cat lbfate PM CI!! M S owr a 

### tats• rMge (I( PM ooncentttdon• · APPROACH F · OCUt researd\ on fh• two mlin PM CE. M S'**t.chno~l••·** light tc:afleflrtg and Nta attenuaeion wttlkt inclfll•ln!l thl utllty of 

# u,. QAG. !valul!te the QAG wilt!. lg:hl AUtMorlfll tnd tMtta llttWluation PM Cftl$**~ posaiblil** **•~~** cNwacwl•1kt lilodiry theQAO 110 fit l !l'k Jfic ... FI: &l i on ftMdt OPERAT I NG PRINCIPLE

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### c-no.-. ( C J llleasured nebUib:.adon r11 t. (R ) Dried i n N IST ·T

ratn ble fle w ( F ) Produc. a N IST ·T racu b .. • ro.o4**CO~I!fltration** ( C J 

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Field evaluautd with 3 dlff•Nnt PM CEMS**Highl~** linear tflltiOMht p {tl,. O .t$) RESULTS Btta •tteonu-ation 

### PM CQ!S lnltlll evaluation at**~ervy'a Bruct~**  Mansfiekl Pow. Ptant

H ur 1:1 eomp.arlson betw. e n factory ealiibratlon and QAO on 3 dlfftn.nt unU• PS·1 1 and QAO col"f'detlons very dlfftttnl Aerosol eharacterls tl ea n"d adJuatmtnl Good eomparb4n wtth 2 ou t of l**PS~11** c;:orrot.tion.$ 

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# .....**-~~** ........... 4 ... ........ 

# --**L- ----------------** **----------------------------------------------------------------------------------~ ~** 

# VES015660
. pdf

### Ogulei , Davi d From: Sent: To: 

### Cc: Subject: 

### Oavtd , K ta g Pe«erson**tagp@coop en** **onmenta l.** **com>** T h ursday, July 18 , 2013 1 :30 PM Og u l ei, 

### David 'Joh n**Coope~;** and r eag@cooperenviro n mental.com FW :

I wanted to add a lottie clarification on my response to your l•rst question . We would be able to deliver a unit on site wit hi n d to 

### 5 m o n ths t h en we should a ll ow 2 to 

### 3 mont h s to get the RA TA s c he du led and completed . Please d on 't h esi t a t e to co nt act me If y ou have any q u est i ons. Best Regar d s, Krag Krag Penerson Vice President Coope r En viron mental Serv i ces, LLC 10180 SW Nim b u s Ave Ste. J6 Po rt l an d , OR 9 72 23 5 0 3·6 7 0· 8 33 5 

### From : Krag 

### Petterson [ ma ilto:kra g p@ cooperenvironmental.com] 

### Sent: WedneSday , July 

### 17, 20 13 3:3 2 PM To : ' Ogulei
. David@ epa.gov' 

### Cc: ' andreag@cooperen vi ronrnenta l. com '; ' John Cooper' Subject: M r . O gule i , And re a as k e d m e t o provide you wit h some r espons es t o t he ques ti o ns yo u s e nt to h e r I n y our email d a t ed Jun e 

### 21, 2013. M y r espo n ses to each que>t l on are give n in r ed. In addition I have at t ache d seve ra l flies in respo n se to these questions 

### as well . I am particularly interested In receiving an update on the followu>g areas: 

### 1 . Commercial availabohty of 

### the Xact multi-metals CEMS. The 

### Xact CEMS is**avao ab~**  commercially from Cooper Envoronmental Services, llC
. (CES) Pall Corpotatioo dl><:o n tlnue d 

### fts license In early february of I his year and since ! h a l time C£5 has been marketing and ma nu facturing both the Xact625 a nd Xact 640 an d 645 (CE MS models) . Xact 

### 640 (M u l ti · Meta l s CEMS) - All CEMS sales have been In the U n ite d Sta l es . Eli Li lly - 1 un i t US Army- 

### 3 units CES - Th i s demonstnatlon unit ha s been used f or testing sponsored 

### by various organlullons including U . S. EPA. Electri c Power Research Institute (EPRI) and Ell lilly . 

### X

act 620/625 Korea- 6 units purchased by National Institute of Envoronmental Resear c h


## VES015660

### China
- 9 units p urcha sed by varco us En v oro nmental Monitoring C e nters C

a n ada
- 8 

### uni ts O ntario M inistry of E n

v

iro nment, Environment C a n ada , Quebec Mimstry of E nvironment , University of Toronto, University ol Dalho u sie, and a 

### sme l ting facili t y New Zealand - 1 

### unit
- se c ondary lead smelter Austro il a 1 

### umt - Queensland EPA Unit.ci Stotes 3 

### units
- U . Mus ., Mossouri DEQ. U . S

. EPA We have known co m petition for t h e ambient market i n China f ro

m FPI and Skyray (bot h Chone s e c

ompanoes) . We h a v

e al so heard t h at FPI p roduces a mufti
- m

eta ls C EM S b u

t ca nn ot co n fir m this . We have no k nown competotlon outside of Ch i na . 2 . 

### Applicability/feasibility/reliability of the Xact 

### multi-metals CEMS for measuring emissio ns ftom heterogeneous waste streams. 

### The Xact and the filter chemistry utilized by**~he Xa~**  

### h a ve demonstrated the ability to**~ke** 

### measurements in wide variety of stack c o nditions . Testin g with the Kact a nd its filter chemi stry has occ ur r e d on stacks burnin g ffla n y different fuel types includin g coal (sub · bi t , li gn it e and bitu m i n

o u s) , n a tural gas, a n d di esel fue l a nd te sting h as occ u rre d at facili ti es wi th different poll u tion controls like ES P 's, baghouses, and w et scrubbers . The x act has been tested on facili t ies with stack temperatures r anging from lee 

### to 450 

### degrees Fahrenheit and ranging in .aisture content up to at 

### leas t 29S . 

### In addition the**Xa~** 

### has de.onstrated accuracy i n the presence of a wide range che.ical species likely to be present in stack effluent. On e of the stren g ths o f the xact is t ha t t h e saMple co l lect i o n is separat e d fro m the K · ray anal y sis . This m eans t h at t h e more se n s itiv e co m ponen t s of 

### t h e analysis s yst em ar e neve r exp o sed to stack effluent . In additi o n beca use the Xact collects 

### a sample for a defined l e ngt h of**ti~e** 

### (for**xa ple**  15 

### minutes) this**~eans** 

### that the filter trapping cheo i stry is refreshed wit h every**sa~ple** 

### eliodnating the**proble~s** 

### wit h the cheaistry becoolna spent over**tl~ .**  

### Also the Xact employs sample dilution prior to the filter trapping allowing many of 

### the stack gas components and the d ew point to be dil u ted to their optimal ranges. Fin a lly, we 

### would r e coa.end**dyna~ic** 

### s p iking procedures in**erfo ~lng**  

### RATA ' s, similar to those used by Ell Lilly in their al t e rnative monitorin g petition . Dy n amic spiking allows th e X act to b e ch al l e nged by a 

### known conc e ntration of metals in the presen c e o f potentially int er fering compone nt s f rom the stack ga s . I ' ve attached two files with details on the range of stack conditions over which the Xact has been tested . l ) Method 301**Repor~ pdf**  

### - please s ee section 7 

### 2 ) P all Comments o n the Secondary Lea d Smelter MACT R ul e . pdf
- these giv e a dd itional details on places t h e Xac t has b e e n tested . 3. Case studies documenting application and/or deployment of t he Xact multi · metafs C E

MS . Please see the files above . In addi toon I would a dd the folfowin& documents flst.cl below 1) Yanca
-2006 · Paper published I n the Journal of the Air and Waste M anagement Assodatoon documentmg the M ethod 30 1 validation of the Xact . 

### 2) EP-0·07 · 026 Fi nal re p o rt and Appendix A. p df- paper docum e nting the Xact ' s performance du r ing an E

P

A sponso r e d S mall Bu si n ess Inno vat ive Re search g ran t . The R AT A procedures u sed at Ell lilly were per f ormed on a coal fired source . 3) Xact 625 ETV Report . pdf- th i s was st\Jdy was done on an a m bient un it but demonstrates the accu ra cy of the technology 2 

## VES0156614) Xcem.pdf- an Army Corps of Engineers study of the Xact's performan c e on Army's hazardous waste Incinerators . 

### S) Feas i bility of u sing the Xact Mult i -me tals CEMS as a Mercury Monitor on C oal Ftred Power P l ants.pdf presentation given 

### at the EUEC conference i n 

### 2011 and documents our compar i son with Method 

### 308 for mercury . 

### 4 . list of locations/ f acilities where the Xact muit• · metals CEMS is cu rr ently deployed and operati ng for any reason . I ' ve li sted the**f~c ili** **es** were the xact CEMS 

### was deployed 1 . Eli llllv's Tippecanoe lilborntories, lilfayette IN- Deployed and opernted for 6 years. The facility Is under new owncrsh1p and the Xact i s no loncer operated . 

### 2 . U . S
. Army - Tooele 

### UT munitions test fumace - It operated per i odically at this facility as the U . S
. Army tested procedures for burning different types of munitions. 

### 3 . U . S . Army - Tooe le , UT production furnace . 

### The Xact was installed at this facility but was never operated because regulations were never required for 

### it . 4 . 

### U .S
. Army - Crane , IN production furnace . The Xact was Insta lle d at this facility but was neve r operated because reaulations were never requ ired for lt . 

### 5 . How beryllium emisSIOns are typic.alfy handled given that the X a

ct multi - metals CEMS cannot quantify beryllium . Efi Ully was only client that utlhted the Xact CEMS for comp l i ance purposes It**handl~d** the beryllium issue 

### as follows (quoted from Ully's AMP) "Beca use the XACT is Incapable of measuring bery11ium (Be) , Lilly has developed a delaull value for be r yllium emissions Fortunately , beryllium i s 

### a s carce elemen t that 

### Is nol 

### used I n Lilly pharmaceutical manufacturing processes. Lilly has examtned all 

### its manufacturing processes an d associated process construction materials ( e . g . alloy steels) and found no lndlcallon that beryllium should be present. T herefore . Lilly believes that a conservatively calculated default value for beryllium os t echnically defensible Trace levels of betyflum are possible 11'1 raw mate ri als and ground water Uly has sampled its liquid waste and found only $p0flldic " hits" of beryl hum 

### at levels close ID the detecilon hmiiS Lilly has also done some lomlled sampling of plant trash . some of which might 

### be proCessed I n th$ solid-iqu i d lnanerator , and some low-levels of beryllium were reported Fa< the purposes or calcula ting a conservabve default ermsSJon eoncentrabOn , Lilly has assumed that an loquid and solid wastes fed to the solid-IJCiuld Incinerator contain 

### Be at the maximum levels detected : 1 0 ppm In the solid waste and 0 . 01pprn In the liquid wastes The default emission concentration was then calculated using the maximum waste feed rates from the CP T p l an , and an LVM system remova l eff ic ie ncy (SRE) of 98% ( which i s a factor of t wo less lha n the design SRE of 99 % and a f actor of 20 less Ihan l he SRE of 99 . 9% obtaine d during lhe CPT of another Lilly lnclneratOf with a virt u ally Identical scrubber system) T he resulbng value was just over 1 ug/dscm
. To be more conservative , Ll"y has chosen 2 ug/dscm as a default val u e . T herefore , a**~alue** or 2 ugldscm will be added to the measured LVM emission before compar ison to the emi55 1 on standard llmK II the CPT data o r any other evidence lnd•cates tile default va l ue Is not appropriate . H will be &djUSied accordingly ." 6. Estimate d timeline lor deploymen t or the X.>ct multo - metals CEMS at an e x isting facility. i . e . , from order date to operation . What are the potential challenges? We believe that a 9 month t i me line I s sufficient and I ncludes manufactur i ng , sh i pping i nstallation and RATA testing . Krag Petterson Vi ce Presiden t Cooper Environmen t a l Services , U C 10180 SW Nimbus Ave S te . J6 Port l and , OR 97223 3 

## VES015662

### 503-670-8335



## VES015663

# VES015664
. pdf

### Ogu le i, David From : Sen t : To : Subject : Ga rnett , Kim Wednesda y , O o t obe r 08 , 20 1 4 10 : 2 5 AM Ogulei , David FW : Questio n

From : A n drea Geige r [ ma il to:andreag@coope re nviron me n ta l. co m] Sent : Mo n day , Septem ber 1 6,2013 3 : 53PM To : G a rnett, Kim Cc : ' Jo hn Coop er' Subject : Q u est i o n 

### llcllo Kim . Please accept 

### my apologies for the delay in our**~ponse.** 

### I bavc filled in the b l anks below 3> 

### well n> offered a lttt l c bit of extra inforrua t ion, j ust in cnsc. It 's n l ways di J!icult to give a price wi t hout a few qualtficrs on instruments like these ... Tlw l'ir s l co s t s fot'j)urchasc / in sta ll:lll on /cc rtiO cnt ion / tmiuing of 

### a MM CEMS are ant icip at ed t o be 

### a ppr oxi m lltcl y $ 365 .00 0
-**$40 000** **~.** 

### Th e in s t ru m ent ru ns about 

### $260.0 00 of th: ll co st. 

### Annu al co s t s will 

### likel y b e nbo ut 

### $ 25.1100 .** *Facrors such a.< transpo r tll?llgllt. IY!/110/1' contmllpolling options. sampling intr:n•al (i.e. shorter sompling iflfl'r'l·ol• require more rape). and iMrallmion complesitie.< n·i/1 haw? art impact 011 thl' t'II'CI'tlll initi11/ budge/for M.lfCEMS. 

### ••,rnmml cos ts depe11d**large~v** 011 

### .rampling illlerw1l. For a 30 

### min me sampling i111e11·al. filter ltlpe costs run uboul**S/9.5/JOI~ear.** 

### 1 

### 5
-

mbm/e sampling inflm·aL• double 1l101amoun1**mmtml~t·.** 

### In adtfwun, 

### n·e recommend 1ha1 comJXmh•s hudge1 for an ammal X-ru y luhe replacemem and re-<·alibrotion (app.1· Ji5-6K). Amwallabor general(• requirf!< one tedmif'ion appmximarelt•**.~-10** 

### lmurs per rnomh for tape change.< 0111/ 

### general operatio11 (111(/ 

### mttlllll'trance task< . I hope 

### tbh he l p$ . 

### P l ea>e do n 't h esi ta te 1 0 

### con tac t m e i f yo u l mvc q u es t ions . 

### !l est R eg ar ds, A ndre n G e iger Pm)••t ' l MartuJ:tn·!£m •i romnc!!11al Scterrti.\1 

### COO I JCr Envii\> I UllCOtn l Se r vices, 

### L LC 1 01**~0** SW N> n>bll' Aw. Sunc J6 

### l'unlun<l . OR Q722J 303-670-8127. ""' 0 <UldQ;dC I! 'i'-'l(lrro:O\ U))ftiDeflL'IlCOin \\"'\\'\to SOOJ'!C!!'n\**tror~ntalrom** 

### l nnu.·utiun ,., ; it

o lli tori n g Conlidcnualny NQri<:e Titl\**~·mall** and an)' anachmaw. may contam contidcmiaJ information**inl~ndOO** ,.nl'l!l) ror the \I'IC nfthc: addrc,<.tC. I rthoc reader of this**mc:,~!,"t** 

### is not lht Intended rtti p 1cn1. •my diS.1ribuliOtL cop)•ing. or**u~e** o( lhitt- e---mail or its a nachmeniS IS prohib • h:d . If you received this**mt'Ssa~·** in «:rror. p lt:L\C nuufy I be sender imox.."d iately by e-.ma1l o1ttl delete thi_, mc:Ro.tgc ;and any COf ll l!':". 

### Thank yo\1,


## VES0156642 

## VES015665

# VES015666
. pdf

## '' UN ITED STATES E N VI R O NM E NTA L PR OTEC TI O N A G E N CY REGIO N S 77 WEST JACKSON BOUL EVARD CH I CAGO, IL 60604-35 90

R E P L Y TOl H e ATTEHliON O F' 

### Douglas Harris , General Manager Veolia ES Technical Solut i o n s, L.L.C . 

### 7 Mobile Avenue Sauget, Jllinois 6220 1 Re : Notification of locompletcncss of40 C . l' . R.. Part 71 P e rmit Renewal Application 

### Dear Mr. Harris: The U. S . Envir onmental Protection Agency h as reviewed the C l ean Air Act (CM) Ti tl e V 

### ptmn.it re ne wal app lication that Ve olia ES**Te ~hnica** **l** 

### Solu t ion s , L.L.C ., Sauget,**lll in** **~** 

### {Veo l i a) subrni ned on April9, 20 1 3. Veolia opera te s undet · a federal Title V P e nn it t o Opera te No . V
lL
- 127 16 300 103-08
- 0 1 , whi ch EPA**i~ d**  

### oo Sep te m ber 12 , 20 08, p ursu a nt t o Tit l e V of the CAA an d its i.mple m entiog r egulations at 40 C.F. R . Part 71. Veolia's penni! expires on October 12,2013 . Pursuant t o 40 C.F . R . 

### § ?l .S (a) (l )(iii ), Veolia's r ene wal application is timely. EPA has 

### reviewed Veolia ' s Title V pem1it reoewal application for completeness pursuant to the criteria 

### ill 40 C.F . R. 

### § 71 .5(aX2) , which requires , among other things, that the iof o rmatioo in the application must 

### be sufficient to evaluate the subject source 

### and i ts application 

### and to detennioe al l**applicab l~**  

### require me nts . EPA ha s determined tha t Veolia's Title V peirnit renewal application i s inc ompl ete . I n order for EPA to deem th e renewal application complete and for Veolia to contin u e to operate 1mder 

### its existi n g per mit u ntil EPA i ssues a rene wed permi t , Veolia must subnlit the fo ll owing information no late r than A ugu s t I , 2 013: I. Citation and d escri p tio n of all applicab l e requirements. Pur. ;u ant t o 40 C . F.R. 

### § 71.5( c)( 4) , tb e renewal application must ioclude: 

### ( i ) citations to and descriptions of al l applicable requirements, and (ii) a description of, or re ference to, any app li cable test metho d fo r determioiog compliance with each applicable r equirement . Pursuant to 40 C.P.R.. 

### § 71.5 (cX3Xvi), Vc:olia mw."l identify any restrictions on source operation that 

### affect emissions or any w o rk practice standards ,**wh~** 

### awlicablo , for all regulated pollutants at the source .



## VES015666

### 2. Initial compliance plan and compliance certification . Pursuant to 40 C . F.R. 

### § 7I.5(cX8) and (9), Veolia must provide the faci li ty's comp liance status and compl ian ce plao for eac h u ni que comb i nation of applicable requirements and e m issions units at the facility. You must l ist all comp l iance methods (e . g. , moni toring, recordkee p ing and reporting) you used to de term i ne compliance**"~th** 

### each applicable r equire me nt. For all requirements for which the source i s not in c om plian ce , you must include a com p liance schedule. Veolia ma y submit the information required by 40 C.P. R. 

### § 71.5(c)(8) and (9) on EPA Form 5900-86 (I-CO MP ), which is avai l able at: http://www. epa . gov/air /oaqpslperm i ts/p71tonns. h tml. 3. Descrip t ion and justificat i on of emis s i ons estimation methods. Pursuant t o 40 C.F.R. 

### § 71.5(cX3Xviii) , Veolia must provide sample calcul ations an d the necessary documenwion upon which yo u re lied to estima te emissions from each emissions un it (e.g., copies of relevant pages of stack test reports , AP
-42 sect i on( s ), industry pub li ca tio n s , etc) . 1 

### If emission factors arc u s ed , Veo l ia must expl ain whether or oot more accurate emissions estimation methods are available for the source , and how you determined that the emiss io n factors yo u chose are applicab l e t o your specific s omce . 

### See In the Matter of**~1ited** 

### State s Steel Corporation
- Grani te City Works , Petition Nwnber V -2 009
- 03 (January 31 , 2011) at 1 4. 4. A l i sting of all active air permi t s an d consent orders ( if 

### appl i cab l e) issued by a state or fed e ral a gen cy. EPA be li eves that V eolia bas rece i ved several construction pen n its, andtherefore, tha t tbe i nformation provided in Section 

### K, Form 5900· 79 (GIS) i s no t complete. For each active permit, pl ease i den tifY the permitting authority , the date the permit was issued , d a te of exp i ration 

### (if applicable) , and type ofpennit (e.g. , construc tion, operating, etc). 5. Process flow diagrams showing all emissions u nits 

### and air po llu tion co ntrol equipment, and a pl ot p l an showing buil d ings and process areas . Veo lia must label the emi ssion points, process equi pme nt, air pollution control eq u ipme nt , stacks and vents. 6 . A li sting aod descrip t ion of an y i napplicab l e requirements, for whic h Veo l ia desires a nonapp l icabi l ity dete rmin atio n in the permit. Veolia mu st i dentify and include a con c i se s ununary o f any inapplicable r equirements as well as a complete explanat ion of why Veolia belie v es each is not app li cable to yo u r source . Pursuant to 4 0 C.F . R. 

### § 7 1. 6(f) , EPA may only exte n d a p e rmit shi eld to requirements that are included a n d are specifically identified in the pem1it, or EPA, in acti n g on the perm i t application or

1 

### Note t b a

t the S3111pl o volat i l

e organic mater ial (VOM) 

### en ussions c a lcul a ti on p rovided oo page 2 0 

### (Appendix A) f or the "Drum Qusher" 

### r efer s to " Summatio n of Pou n ds VOM 

### from Col u m

n 

### 1 abo ve;" 

### however, Column 

### J of th e 

### tabl e on Page 1 9 is titled " Commen ts . " Thi• 

### is prob a b ly a 

### t ypographical etr o r. 

### 2


## VES01566 7

### revision, determines in writing t h at other requirementS specifically ident ified are not app licable to the source , and 

### the perm it inclu de s t h

e determinati on or a 

### concise summary 

### thereof. 

### S hould Veolia wi sh to req u est confidential treatment for business information, such infom1ation 

### musl be submi tt ed separatel y alo ng with 

### a claim 

### of confi dentiality**a~** 

### p rovi d ed i n 

### 40 C.F. R . l'art 

### 2, Subpart 

### B . All co n fidential bu s iness i.uJormation must 

### be c learl y 

### and proper l y marked , 

### and copies of the renewal ap plica ti on su itab l e for public in spection must 

### be submined . EPA will process al l**b~iness** 

### confidentiality cla im s follo wing the procedures fo und in 

### 40 C. F . R . Part 2. Consistent with 

### 40 C . F .R. § 7 1 .5(d), the responsible official must certify 

### all info rmation Voolia submitS in response to this request. EPA 

### is available to meet or teleconference with you to clarify any ofthe information requested in this letter. To arrange a meeting or teleconference, or if yo u have any questions, please contact David Ogulei, of my staff, 

### at (312) 353-0987. Sincere ly , ') 

# ' ,i . . - ·

# L~/JU**?t.U~** G. nevieve Damico 

### (. · hief

Air 

## Penn i ts 

### Section



### 3


## VES0!5668

# VES015669
. pdf

### Ogulei , Dav i d From: Sent: To: Cc: Subject: Nancy L 

### Paddock <nancy . peddock@veoliaes
.com> Tuesday , Oeoember 10, 20 1 3 8:29AM Ogu l ei , David 

### Dennis J 

### Warchol 

### Title V Revisions Attachments: Emiss i ons Ca l es from Application f rom Veolla 1 2·9 · 13 . xlsx; A4 Form PT E Summary( 1 or 2 ) rev 5dean.do c ; AS Form PTE Summary(2 of 2)rev5dean . doc ; cU nl t 3 ( 1 of 2)rev5 . doc; aUnit 2 (1 of 2) rev5.doc ; I Drum Crusherrev5
. doc; eUn it 4 ( 1 of 2) rev5.doc ; VeOIIa Page 1 8rev5 clean . pdf 

### David , We've corrected errors/typos and hopefully all the numbers add up now . We've also ad dressed organic compounds as HAPs . Your spreadsheet has been modifted as well , hopefully you'll find this helpful. Attached you will find the following ; lers see 

### if these items will get the job done for us! 1 . Your spreadsheet with our updates in RED . 2 . Revised FORM PTE 's 3 . Revised FORM EM ISS's for Unlt2, Unit3, Unit4 and Drum Crusher 4 . Revised Page 18 from the N arrative . Let me know if you need anyth in g e l se. N

ancy Paddock Environmenta l Engineeri ng Speciali st Veol l a ES Technical Solutions, L. L C. 7 Mobile Avenue 

### Sauget, 

### I L 62201 618 . 27 1. 2804 {X-115) 618.271 . 2128 {fax) Nancy ,Paddoc;k®Veo!Ji! ES.com WWW,\feo!tiiES cpm 

### This e - mail message from Veolla ES Technical Solutrons, L.L.C. 

### is 

### for the sole use of

### the I ntended redpient(s) and may conta i n confidentia l and privileged Information. Any 

### u nauthorized review, use, d l sdosure or distribution Is proh i bited . I f you a re not the i ntended recipien t , please communicat e with the sender by reply e-mail a nd destroy a ll copies 

### of the origina l message and delete 

### It from all computers.



## VES015669

# VES015670
. pdfPTE 

### a s reported byVeolia o n EPA Form 5900·85 (tp y ) 1 Unit 

# 1 "**'~' ""**  

# . , .. 

# r soz 

# 1 . !Aold 

### 1 HAP (To!!!) 0.6156 2 .8 . 7 2, ,8 7 . 7 7 0 .022 1 t 1.04 

### VOCI ' ' NOll [ UNIT N2 [ UH IT#3 

## M l 41 0.64041 2 .91 1 2 . 911 7 . 7 1 0.02211 10.4 3 . 1 1 6 1. 61 1.941 8.82 1 16 .921 51.761 0 .0695 1 11 .49 1.45 0 . 24 1 [ UH I TI4 13.1 IMP · ! I I 0.2387 1 

# I I I I I I 0 . 041**~87** 0.041 MP · Z DRU M CRUSHER 3 ,87 0 . 2481 ITANK •2 0 . 1348 0 .00021 -ANK N4 0 .0 203 3.65 £ · 0 51 TANKM6 

# I I 0.0 1 33 TANK §8 0 .025! TAN K #10 0.0 1 2 ! TA NK 420 

### I I 0 . 041 TANK # 30 

### I I 0 .0203 TA NK # 40 

### I I 0 .0143 rA NK HSO 

### I I 0.0 085 TANK M6 0 

### I I 0.025< rANK #300 

### I I 0 .1 454 TANK #3 02 

### I I 0.422' TAN K #304 

### I I 0 . 3094 :TANK #306 

### I I 1.29 I TANK #308 

### I I 1 . 6 2 [ TA NK # 3 10 

### I I 2 .1 8 I TANK #312 

### I I 3.23 [ T

ANK #3 14 

### I I 0. 47 36 4.6 0.0001 1 3 . 65E · OS 2 .58E · O 1 . 53 1 l· O: 4 . 62E · ) . 00 

### O

. OO OQ ). 0006 ) .00

_ 2:!

• B LDG 

# I I 2 .561 

# I I I I I I 0 . 1 11 3.79 0.248 + .5 1 0.343 

## o . oz; U

GI T I VB EQU I P LEAKS 

## I I 0.039 1 I I I I I I 0.0014**~** l.095 I 0.03 1 0 .4 21 

### I 0.031 I 0.03 1 01 0.000 1 EGENZ 0 . 0 95 0.03 0.4 2 0 .03 0.03 0 0.000 11 FA CILITY TOTALS 3 1 .0 4 23.6 74.95 3.19 6 14.93 22.63 67.25 0.11 37 33 . 61 TotaJHromarmlltadcin 3 0 , 94 23.6 . ·,**1~95** ·:**.q,;·•w~,;.?.v- .1'4.93**  wt!-'"111. '1<·,. 67, , 25 ' · 0 . 1137 33 .41



### VESOI5670PTE •• reported byVeoUa for Fee P urposes on EPA F orm 5900·8 4 (q>y) [mission tinlt 

# co VOC .

## ~ PMZ " ;$ ,.# 

### PMl!l !'?-**~"''' PM**  502 ' 

### Uacl 

### HAP 

### !Tor.! UNIT 112 6 . 6 0 .9 4 0 . 6 1 56 2.8 2. 8 7.7 0 . 022 1 1 0.0207 UNI T 113 6 . 6 0 .9 4 0.6404 2.91 2 . 91 7 .7 0.0229 10 . 134 8 UNI T 114 13 . 86 3 . 1 6!.6 1 . 9 4 16 . 92 1 6.92 50.76 0 . 0695 10 .7173 LABPA C K R£PACK 1 .45 0 . 2418 MP · I 0.2387 0 .0495 MP- 2 0.2387 0 .0495 lRUM CRUSHE R 3 , 87 0 . 248 BFBLO G 2 . 56 00188 BOILER Ill 3.79 0 . . 2 48 4 .51 0 . 343 0 . 343 0.343 0.027 EGENI 0 . 095 0 . 03 0 .4 2 0.03 0.03 0.03 

### O.o3 0.0001 EGEN2 0 .095 0.03 042 0 . 03 0.03 

### O.oJ 0.03 o . ooo · 1 FACILITY TOTAL 3 1 .04 13 . 57 74 . 95 3.60 23.03 23.03 66.25 0.1145 31.5 Breakdown of HAP Emissions :t py)



# . Bulk Fee d Total Drum LabPack Building Polhatant UnltU UnlUJ Unit 114 Crusber Repack M P·l M P-2 (SF Bldril HC 1f'l: l2 9.92 10 .03 1 0 ,4 30.4 

### Hg 0 .012 5 0.013 0 . 0393 0.06 As 00088 0 . 009 2 0 . 0278 0.05 Be 

### 0.0080 0.0092 0 . 0278 

## o.os Ben1.ene 0 .2 46 0.2418 0.0495 0 .049 5 0 . 0!86 0.61 

### C

d 0 .02 2 1 0 . 0229 0 . 0695 0 .11 Cr 0 . 0080 0 . 00 92 0.02 7 8 

### o.os S

b 0 .0066 0 .0092 0.0278 0 .05 Pb 0 .0221 0 . 0229 0 . 069 5 0 . 11 Nl 0 .0088 0 .0092 0 . 0278 0.05 D

lo xlns/Furons 1.92 E
- 08 1 .2 0£
- 07 6 . 65£-07 0 .0 00001 Notes: 1 . No emissions re ported lor th e rest oftbe emission units li . sted in Form 5900-85 . 2 . N o HAl' emiss io ns w e re re ported fo r Boile r # L NH3 emissio n s of0 . 144 tp y r epo rted for Boll or •r . 3 . N o bre akd own ofHAP emissions p rovi ded lor EGEN I and EGEN2.



## VES015671

### Pollutant HC1/C12**H~** 

### As Be PTE 

### as reporte d b y 

### Ve olia on EPA Form EMI SS (tp y ) 

### (August 2013 Ad den dum)

Br eakdown of HAP Emission s tpy) 

### Drum Lab P ack Uni tll 2 Unlt #J U n it#4 C rusher R e oac k MP · l 4.09 4.09 

### 11.57 0.00114 0.00114 0.0319

0.0081 0 . 0081 0.0226 0.0081 0 . 0081 0.0226


## VES015672

### Benzene 0.00006 0.2418 0.04 95 Cd 0.0202 0.0202 0.0564 

### Cr 0 .0081 0 . 0081 0.0226 Sb l.SE
- 05 1 . 5E-05 4.9E
- OS 

### Pb 0.0202 0.0202 0.0564 Ni 0.00002 0.00002 4.8E-OS Se 3.7E-05 3 . 7E-05 0.00012 Met ha no l 0.4069 Dioxins/ Furan s 1 . 92E-08 2.00E · 08 6.05£ -0 8 Org am c H AP Compo u n ds Notes: 0 . 5287 1. No em i ssions reported for t he rest of the emiss i on units Us t ed in For 2. No HAP emissions were reported for Boiler #1. NH3 emiss ion s of 0. 3. No b reakdown of HAP emis s ions provi d e d fo r EGEN1 and EGE N2 . 

### TANKS T ankiD B e n zene 

### TAN K 112 2.18E · 05 TANK 114 2.47E · 04 T

ANK 116 7.73E · 06 T ANK#S 9.61E-06 TANK11 1 0 l.B2E -04 TANK 1120 3.11E-05 T

ANK 1130 2.55E-04 TANK #40 3.07E · 05 TANK #50 B.03E · 06 TAN K#60 4.98E
- OS TANK#300 2.71E
- OS TANK#302 1.84£
- 04 TANK #304 5.4SE·OS TANK#306 9 .5 9E · OS TANK#308 2 . 15£-04 TANK#310 2 .4 8E-04 TANK#312 3 . 42E
- 04 TANK #314 2 . 05E·04 2 . 21E·03



## VES015673

# so z Lead 

### HAP(T o tall 7.7 0 . 0202 4.17 

### 7.7 0 . 0202 4 . 1 6 

### 50 . 76 0.0564 11.78 0.24-18 0.0495 0.0495 0.9356 2 . 18E·OS 2.47£-04 7.73£-06 9 .6 1£
- 06 1.82£
- 05 3.11E·OS 2.55E·04 3 .0 7£
- 05 8.03 E- 06 4 .98E
- 05 2.71£
- 05 1.84E-0 4 5.4SE-05 9 . 59E·OS 2 . 14E·04 2 . 84£
- 04 3.42E-04 2.05E-04

0.0188 0 . 027 0.0001 0 . 029 0.0071 0.029 0 . 0071 66.25 0 . 0 9 68 2 1 . 4 6 6 . 1 9 0 . 0968 2 1.41

Bulk Feed Total

B uilding MP -2 

### (B f Bldl! ) 19 .8 0.03 0 . 04 0.04 Sum o f H AP s 

### t see b e lowl 4.16 4.16 11 . 78 0.2418 0.0495 0.0495 0 .93566 2 . 18E ·0 5 2 .

47E-04 7 .7 3£-06 9.61 E-06 1.82 E
- 04 3.11E·05 2 .SSE-04 3.07E-05 8 . 03E-06 4 .98E·05 2 . 71E-05 1.84B
- 04 5.45£
- 05 9 . 59E-05 Z . ISE
- 04 2 .

48E
- 04 3 . 42E·04 2 .

05E · 04 0.0188 0.0001 0.0071 0.0071 2 1 . 4 22 .41 Revised Unit #2 FORM EM I SS (rtv5) & 

### FOR I Revised Unit #3 FORM EM IS S (rev51 

### & FOR I Revised Un it #4 FORM EM IS S (rev51 & 

### FOR I



## V E S 0 15 6 7 4

### 0.0495 0.0188 0.36 0 . 10 0.04 0.0001 0 . 0968 0 . 0001 0 . 0002 9 .

97E
- 08 Revised Drum Crusher FORM EMISS t revS)
'U1 

### 5900-85 . 144 tpy 

### reported for Bo ll er Ill.



## VES015675

### M PT E for 

### plant M PTil for 

### plant M PTE for plant



## VES0!5676

### TPY**Emis.~ions** 

### Pollutant P otential to Emit 2012 Actual 2011 Actual 2010 Actual 

### (PTE) Emissions Emissions Emissions PM 1 3.93 107 1.12 1.1 PM 10 

### 12 . 55 1.07 PM 2. 5 

### 1.07 

# so2 66.19 0 .53 0.49 0.49 

### NOx 74 . 11 56 . 56 58.16 57. 1 VOM 15.63 

### 1.93 1.5 1 1.62 

# co 30.85 1.16 1.2 1 1.4 1 Lead 0.0968 0 . 000 1 8 Tota l HAPs 21.41

Antimony (Sb) 0 . 00001 (NR ) Arsenic (As) 

### <0.10 0 . 0000251 Benzene < 0.40 0 . 0019 Beryllium (Be) < 0.05 l. 76E
- 0 7 Cadmium (Cd) 3 . 11E-05 Chromium (Cr) 5.46E
- 0 5 Dioxins/Furan s 6 . 35E - OR 

### Hydrogen Chl oride 1.89 2.03 Lead 

### see above Mercury (Hg) 0.055 0 . 0017 Nickel (Ni) 0 . 0000 I (NR) 

### Se l enium (Se) 0 . 0001 

## <NRJ Organic HAP s 0 . 04



## VESOI5677

### 2009 Actual 2008 Ac tual E mi ss i o n s E m is s i o n s

1. 07 1.04
0 .5 2 0. 496 

### 55 . 23 54.76 1. 74 1. 7 1. 67 1.95

2 .09 

### 3.56



## VESOI56784 . 1 66 4 . 166 11.78 

### O.l41 K 0 . 0495 0 . 0495 0.9356 2 .1 8£-0S**2. 7E~**  7.7JE-06 9.6LLU\6**t. 2E~S**  3.1 LL !-oS 2.SS i l .Q4 3.07E..(JS K.OJ I S· 06 4 . 98E · OS 2. 7 1 E· OS 

### 1.846 · 04 S.4Sl l· 05 

### 9 . 59E · OS 2 . 1 51l · 04 2.481!·04 3.421l·04 2 .0SE · 04**0.0 18~** 

0.000 1 0.0142 21.42355 2 .56 7.7 4 

### 2.5 3 7 . 7 4 7 .15 50 . 76 61.6 0.343 

### 0 . 021 4.51 0.03 1 0.029 0.441 0 .0 31 0 .029 0.441 12.645 66 .245 74 . 992 2.78 1 9



## VE S0 156790 .05 1 2 0 .9 

### 6.6 

### 0 . 0202 0.02 8 7 0.9 

### 6 . 6 

### 0 . 0202 0.1894 3.1 

### 13 . 86 0.0564 0.0561 1.45 

### 3.79 0.0993 023 81 

### 0 . 095 0.2218 023 8 7 

### 0 . 095 0.2569 3. 8 7 

### 3 1. 04 0.0968 0.3517 0.023 0.2117 0.0252

2.56 0 . 0019 0 . 0138 0.01 0 .241! 0 . 1R 71 O

.o35 0 .0316 O

.Q35 0.2584 0.9 0 . 0 323 0.9 0 . 0088 3. 1 0 . 0 51 2 1.45**O.o2~ 7**  02387 0 . 189 4 0 . 2387 0 . 0 5 6 7

3. 87 0 .09 93 0. 0 23 0 . 22 1 & 0 .02 52 0 .2569 0 .00 7 9 0 .3517 0. 0 1 0 2 1 17 0 . 18 7 1 2.56 0 .0 3 1 6 0 .0 ?3 8 0 2584 0 . 248 0 .0323 0.035 0.0088 0.035 

### 15 . 7009 1 5.7 009



## VES0l5680

# VES015681
. pdfOM S Con tro l N o .**l0 60~** **336** U.S. ENVIRONMENTA L PROTEC TI ON AGENCY APPLI CATI ON F OR FEOERAL OF£RATI NG P€RM FT, 40 CFR PAR T 71 FORM EMJSS • E MlSSIONS CALCULATIO N S
INSTRUC TIONS, U se til's f orm to ca l rula te po tEf'ltiaf kl emi l (PTE} lor a pplica bili ty purp oses and actua l ernissWJns fof- l&e p4..1p01S&$ tor each**~** u ni t CON.I'Of d &Wee, or**et ~ve**  ope:ro1.1ng**~ lf** **ted** In sec:tlo n l o f l oon G I S. If fo rm FEE does not need t o be aobn ll ted w' l h th e a wka:tion. m n ot calculate actual f.f1'\is sions.
A. Em i ssions Unit 1 0 

### U nit 3 (I 

### of 2)
8. lden li llcati on a nd Oua ntifica lioo of Em i ssion$ t nst ru cOOos: Fnt. l i&t each a ir p OIMo n t lhe1. is eitl"l:er rtgufMtd b l l'le u n l l CH prestnt I n m&J or amounts . Second, lis t arvy o ther reg ula 6ed**pol~** { f or lee calculation) emined at t he u M that h ave not already bee n l i sied . Eac h HA P added 10 tfle l &t in th is s tep**m:~y** be simply li&t ed n .. HAP ". Next , <:ak: ul tJte PTE fO¥ applic&bCi t y**pwpos~H** znc1 .ctua l emissions tor fee purpo ses f OC" eam listed a i r po llu tan t. Do not calc u l:lkl PTE for ai r pcA.stants listed sot-ely f o r tee p urpo ses . l n dude a1 f ug iives. iw.: l octng tho se t hat dtl not eou n 1 toward$**a~b !ll** **ty,** w hen ca l c ulating actua l emlss i OflS. A1 a min lm iiTI, rou nd 1 0 !he neares t &e n rn of a too fo r yearly values or tent h o f a pound fof OOUty va be:s. Allac h •x.-omp l e$ 

### « ca l a.Aatlons th at if t.tstrates be meth odol ogy used .
Air P ollutants {ln d udl ng t'f!9Uiat P.d air**pol nts**  a nd Emissio n Rates CAS No. po lll . • tbnt$ lot' wh l eh the $0urce Is maj Of} AcW al Potential t() Emi t Am va

l Eriss i ons Hourty A oo ue l (tons/yr) ( b/hr) (to n s/y r ) 

### PMIP M10/PM2.5 0.5775 2 . 53 HCI/C L 2 0.9340 4.09 NO x 

## NA 4.0 

# co 2.31 

### 6.6 S02 

## NA 7 . 7 VOM 

### 8.0 0 .9 0 Hg 0.0026 0.00114 7439-97-6 As 0 . 00 18 0.0081 7440-38
- 2 

## Be 0.00 18 0.0081 7440-41
- 7 Cd 0.0046 0.0202 7440-43-9 

### Cr 0.0018 0.0081 7440-47
- 3 Sb 

### 0.0000342 0. 0000 L 

### 5 7440-31-5 

## VES015681

## VES015682

# VES015683
. pdfOMS CM ro l N o. 2060 · 0l36 U.S. ENIIlRONM ENTAI. PRO TEC'TI ON A GE N C

Y A.PPLICAHON F OR FE DERAL OPERATI NG**Pf IT** **,** 40 CF R P AR T 7 1 F ORM EM I SS • EM I SStONS CALCULATIO N S

I NST R U CTI ON S : Use tljs fo r m to ea l o.Aat e po t en ti a l lO emit (PTE ) lOr app l bbii t y pu rpose$ and acwa l etr\issiotl$ t o r See p urposes f or e&dl emissions u n i t oon1 rol de oke. or alte m rive operating soe n a ri o id 8f166ed in secti on 1 ol f orm GIS
. ff fonn FeE Cloes noc nee d**~o** be wbn i tt.ed w 1 1h 1M o PI)Ieb tion. do n ot**Ct~lc::ul() te**  t1 Clu3 1 emi$S I On s.
A. Emiss i ons lAW 10 

### Unit 4 

### (I 

### of 2)
B. ldenllflcalio n and Oue nt if lca1J on of Etnlssloos l nstruc1 l ons : F irs t, lsi escn arr polkltan t t hat is Hh er reg ul a \ed at !he wVt or**res«~ t**  in maj or eroount&. Seoonc:l, fi st any oche r r e g ul * d Fdtll o:I N (rot' fee eak:Oiat lon) em n te d at tOO uni t tha t h ave not * e&dv been isWd . E ac h HAP added &o the ls t ln l'l ls s t ep may be s fn ply l is .OO as - HAP" . Next , calc\A& t e PTE tor ap pli cablity pwposes an d a ctual em ission s for fee pwpos.es for aa d't li6t ed a ir**.** Oo no l caJcut!ltO PTE f Of air po ll u tant$ li t t td sote l y W se e purposes. I nclu de a ll**T.iv e$,**  ln c:k.IC i n g tho9e Ch at do not c ou nt l owacds ep p l lca bil lt}• , wh en calc ul a tn;J ac.1.ual erni&OOns
. At a m ini rrun , round 10 l h e Mare S!**h** ol a**n** f Of y-&&r l y \';!! l u es or tenth 

### o r a pound lOt' hO u r l y va lues. Attac h exafll) l es of calCu l at iOns tha t llklsr'a l.eS t h e med'IOOO iOO Y U$00.
Ai r Pollu l ..,.s Orte:lucfing rCJ91.U t cd air p otlul: &n l $ end Emi $'$kl0 Fl&t es CAS No . pollutartts for wtl k h the so u roe i s majoc) Actu al Po t en ti a l to Emit Annual Emissions H o ll'ly Amua l**t~/yr)** ( l b/h r) ( tons/yr) 

### PM 

### 1.63 7.15 HC VC L2 

### 2 . 64 11. 5 7 

## NOx NA 61.6 

# co 6 . 52 13.86 

### S02 INA 

### 50.76 

## VOM 8 . 0 3.1 

# IJ-Ig 0 . 0073 0.0319 7439
- 97-6 As 

### 0.0052 0.0226 7440-38
- 2 

# !Be 0.0052 0 . 02 26 7440-41
- 7 Cd 

### 0.0129 0.0564 744 0-43-9 C r 

### 0 . 0052 0.02 26 7440-47
- 3 Sb

### ~.00001**1** 

### 0.0000486 7440-3 1 -5 

## V E $ 0 15683

## VES015684

# VES015685
. pdfOMB Conlrof No . Z 0 60.0 33 6 U .$
. E N VJ RO NM E NT A L PROTEC TIO N AG£NC Y APP U CA DO N FOR FE DE RAL OPERA T j N Q P ERMIT , 40 CF R P AAT 71 FORM P TE
- POTEHTIAl T O EMrT SUMMARY**STRUC TI** **ONS :**  Com ple te l:hi & fo r m onoe f or the**it .**  Y ou may lind il h elpM ' 0 oom pl - f or m E MJ SS fo r e:&eh eml ssiMs un il ber or

e comp let ing

' h i$ fO r m. F or ea c h em i $$ 1 0 ns ri**h** e ml $sioi"'S thai ooln! t ow a r ds**1\W'~ ty** **.** fs t t he**em ~sicns**  u ni t 1 0 a nd t he PTE fof the air pc6.rta n ts li ste d below . If there are other air pol lu tants no1 l iMe d b tlow for wt'lk:h lhe source I $ a m a jof**~.** p ro vide ana c:twn eo t s nom i n g 1M**~** pOik.r l an t 8nd $ ho \\itlg c a i OJ tac l on ol t h e 1Q tai for t ha i polol a nl . R ou nd v al ues t o t h e neares t t enth o f a to n . A d d a n v a lu e s together il**~** col um n 00<1 ent e r th e t OUIJ in ' h e space p roWdecJ a t the boltc:m of th e teble. Al to**repot~** fte se to lal s in aecci oo J at tonn GI'S .

Em l s$1 on s Uni t 1 0 R e gula led Ak**ant s**  end P oll utants f or w hi ch the So u rc e is Ma j o r N

Ox 

### voc 

### soz P h il O 

### co 

# .._ HAP ( tons/ y r) {tons/ yr) { r o n s/yr) { t ons /y r) { t cns/ y r ) h o ns /y r ) Uo n s t'yr) 

### Unit2 4 .0 0. 9 7 . 7 2 . 53 6.6 

### 0 .0 2 02 4 . 1 66 

### Unit3 4. 0 0 . 9 7 . 7 2 .53 

### 6 .6 0 .0202 4 . 1 66 

### Unit 4 6 1. 6 3 . 1 5 0 . 76 7. 15 1 3.86 0 . 0 5 64 11.78 

### Lab Pack R e pack 1 .45 

### 0 . 2 41 8 

### Materi al Proc essing 1 0 .2 3 87 0 .0495 

### Mater i al Pro c ess in g 2 0 .2 3 8 7 0 .0495 

### Drum C ru sher 3.8 7 0 .935 6 

### Tank2 0 . 0230 2.1 8 &0 5 

### Tank 4 0.0 252 2 . 4 7E-04 

### Tank6 0 . 0079 7 .73 £-06 

### Tank S 0 . 01 0 0 9 .61£-06 

### Tank 10 0 . 1 871 1. 8 2E-05 

### Tank 2 0 0 . 031 6 3 . 11E-05 

### T a nk3 0 0 . 25 84 2.55 E
- 04 

### Tank 4 0 0 . 03 23 3 .07E-05 

## V E S O I568 5

# I Tank 50 

# ls . OJE
- 061
T OTALS TOTAL ON 2Nb F ORM



## VESOI5686

# VES01568 7. pdfOM8 C ont t OI N() , l060-0 336 U.$
. E NV I R ONM E N TAl. PROTECTIOtl AGE NC Y APPUCATI O N F OR F EDERAl. OPERATI N G PER M I T , 40 Cffi P AR T 7 1 F ORM EMISS • EM I SS I O NS CAL CU LATI ONS

I NSTR UCTIONS: U$e lhi & for m \o Q!l tcu lale po l eni& ! l o emi l (PT E) kit &pp!lcabi lil y QU' PQSe$ and actus l emi$Si:lns for tee fdPOSE!S f or each em i ssions u M. c on trol de'VIce. o r a l ttma ti ve operati ng sce n ario iden t ifi ed i n secllo n I of form GIS. I t fonn FEE do ss I'M)1 need to be submit ted wi l h fl e**a;»~ lon** **.** dO no l Cllleulcla actual eml 3$ 1

ons.

A Em i ssi on s U nit 1 0 

### Uni t 2 (1 

### of2 )

B. ldenl.ifl c allon and Q ua nlift c s tion ol Em issk>ns**n&truefioos ~**  F i mt. 1 16 1 each air polllla n t that is either**eg~Aated** a t lhe u n it or**pr S«~** **t** i n 

### rra;or am ou n ts . Seconi, li s t a n y oltte r reg ul o\ed**po llu** **~l'll** ( f o r foe ca i C\I I aOon) emiUed a t t h e u ni t that have not ateacty been l i$ted
. E ach HAP added to t he li st In lhie. st ep m a y be sin pl y list ed as " HAP ". Nexa , cal ctJ a le PTE for**appl cab~ity**  pu rposes and aau al emissioos for fee p..rposes for eadl i&ted ai r pot: u tarrt. Oo no t e&leukne PTE lOr oir I)Oiutenu l i$ t t<l $dt ly for t ee purpo ses . I nc l ude t!ll l f\tgll l ves . W'd udl ng those thai do not ClOIXrt KIWa tds ap pka bill 1y , whe n calc ut a q actual em i ssions. At a min i rmm, round l o t h e ON r el!l l enlh of a ton t()r yea rl y va l u es 01 " n th ol a pounO f Of h owty 1/akles. Anach exa mp l es d caw auoos th& l lklstrat es th e mectlOOOklOY u sed.

Ai**$** ( i n ducin g r e g iAe l cd air pclu ta nts a nd Emiss i on Riles CAS No . pollJtants fof Yttlkh t he 50 uroe is maj( : d 

# """"' Poten ti al lO Emit A nnu a l Emissions Hou"y An n ual**(~n /yr)**  ( l b/h r) (100$ / )T) 

### PMIPM I OIPM2.5 0.5775 2 . 53 HCI/C L2 

### 0.9340 4 . 09 

## N

O

x NA 4.0 

# co 2 .31 6.6 

### S02 

## NA 7.7 VOM 8 .0 0. 90 

## Hg 0.0026 0.00114 7439-97-6 As 0.0018 0.0081 7440
-38-2 Be 

### 0.0018 0.0081 7440-41
- 7

### d 0.0046 0.0202 7 440-43-9

### r 0.0018 0.0081 7440-47 -3 Sb 0.0000342 0 . 000015 7440-31-5 

## VES015687

## VES015688

# VES015689
. pdf

### POLLUTANT 

### PTE P OLLUfANT 

### PTE (ton s/y r) ( ton sly r) 

### PM 12.62 BENZENE 0.36 PMIO 12.62 BERYLLTUM 

## O.o4 PM.1..s 12.62 DIOXIN/FURAN 9.97 X 

### J0 ' 8 

# so2 66.25 HCI/ Ch 19.8 NOx 74.99 L EAD 0.0968 VOM(OZONE) 15.70 MERCURY 0.03 

# co 31.04 METHANOL 0.4069 TOTAL HAPS 2 1. 4 NICKEL 0.0001 ANTIMONY 0 . 0001 ORGANIC HAP 0.5287 COMPOUNDS ARSENIC 0.04 SELENIUM 0 . 0002 The curre n t facility 's PTE is a summation of the potential to emit of each emiss i on u nit. 

### B. Incinerat ors: U nit 

### 2 , Unit 

### 3, a nd U nit 

### 4 Emi ss ion S tandard Requirements The regulations applicable to the i ncinerators are l isted below. A listing of any n on app l icable requ irements and the reasons for the non-applicability are provided in Appendix 

## B. 1. Visible Emissions 

### a. Vi s ible E mi ss ions Limitation s 1 35 lAC 2 J2.12 3( a) J The emission of smok e or other part i c u late matter , with an opacity greater than 30 percent, into the atmosphere from any emission source shall not be caused or allowed, except as allowed by 35 lAC 212. 1 23(b ) and 212. 1 24. 

### b . Fu g itive Par tic ulate Matter ( 35 

### lAC 212.301 and 2U.3 14J T h e facility s h all n ot cause o r allow the emi ssio n of fugitive particu l ate matter from any process, inclu ding any material han dling or sto rage activity, that is visible by an observer looking generally overhead at a point beyond the propeny line of the source unless the wind speed is greater than 40 . 2 kilometers per hour (25 miles per hour.) except as described in 351AC 212.314.



### 18 

## VES015689

# VES015690
. pdfOMB C o nc ro l No . 2060oo033 6 U . S
. E NV I RO N MENTA L PROT E C n ON AGENC Y APPU CATIO N F O R FCOERAJ. O PE RA T ING PERM I T . 4

0 CFR P ART 71 FOR M PT E • P OT EOITIAI. TO E MIT SU M MARY**NS RV** **llON$ ~**  Co ffiC)Iele IJi.i9 f orm ooce t or t he taclf«y . Y ou ma y l i nd l t hef;:A u l to c o mp6e t e bm EM I SS tor e &eh P.ml ss lon s ri. before**c~tintJ** this farm . f« eac h em i ss i ons u rit wil h enis sl ons th at OO U'It lOwards app k e bil ity, l ist the emissio ns u n i t 1 0 encf t h e P TE bf til e 

### a !, pol h .nenl$ li sted below . If t heft**~** othe r si r p ollutants no t lls:ted betow f or w hl c:h t he sotl'c e is a majof so u rce. pro vide a tt<leh mM ts na ming t he a ir po l luta n t and s howi ng ca l ct.iation o f th e tota l for that pollu ta n t Ro mcl v a l ues to th e ne a r est t enth ol a ton . Add al l V111ue$ togeth er i n each <: olu m n an4 erner the I Oi a l in t h e s pa t» prov ide d a t th e bott om o f ttte lab le . A l so re port th e se to tals in secOOo J of form GIS .

Em i s sio ns U rit 10 R a gu l a kMJ Ai Polkltants an d Polvtaru for vd1ich the SO\I'c. is M a j or N

Ox 

### v oc so z PM I O 

## co Lead HAP (tons/)• r ) ( t ons/y r ) ( t o n s/ y r) (tons/ yo) (tons /yr) (..,s/yr) ( to n s / yr) 

### Tank 60 0 . 05 1 2 4 .9 8E
- 05 

### Tank 3 00 0. 02 8 7 2 .7 1 E -OS 

### Ta nk 302 0 . 1 894 1. 84E
- 04 

### Tank 304 0. 05 67 5 .45E
- 05 

### Tank 306 0 .09 9 3 9. 5 9E
- 05 

### Tank 3 0 8 0 . 22 1 8 2 .1 5 E
- 0

4 

### Tank 3 10 0. 2 569 2 . 4 8 E- 0 4 

### Tan k 312 0. 35 1 7 3 . 42E -04 

### Tank 31 4 0 .21 1 7 2 .05 E
- 04 

### B u lk So lid s S torage 2 .56 0. 01 88 

### Fugitiv e Eq ui p m

ent Lea k

s 0 .07 3 8 0.0 00 1 

### Boiler I 4 .5 1 0. 248 0. 027 0.3 43 3.79 Emerg ency Gener ato r # 1 0 .441 0 ,03 5 0.02 9 0.031 0. 095 0 .0071 Em ergen c y General o r #2 0.44 1 0. 03 5 0 .02 9 0. 03 1 0 .095 0. 00 7 1



## V E S01 5 69 0TOTAl.$ 74.99 15 .63 66.25 1 2.62 30.85 0 .0968 21.4



## V E SOI569 1

# VES015692.pdfU . S
. ENV I R O N M E NTAL PR OTECT I O N AGE.NCY APPL I CATI ON FOR F EOE:RAI. OI'EAATING PERM rT. 40 CfR PAR T 7 1 FORM E MISS • EM I SSIONS CAI.CUl.ATIONS

I NSTRUCT I ONS' V&e N f o:m tO ca l cU& le po tenr la l to e mil CPTE} f()(**bllfy** I)Urpos e s: and aciUal**em~lone** f o r t ee pt.rpC!68 S tor each emissions u ni t.. contro l de'oice . or allern etivo opera tirlg sctAar i O kM nOO M i n $eCCiOn I of fo rm G.f$
. I form FEE does no1 Mle d t o be subn l t !ed wi: h th e a PQication
. 00 no t caleda t e act ua l**~s.** A. Em i ss i ons Uni t 10 

## Drum Crusher
8 . lden liication aocl Quantific ation of Em i ssi o ns I nstruct io ns: First. l ist each a i r polluLan t that i s eithar reg ul at ed at the uni t or prese n t in ma jor amounts . Second, iSl My other**regu~D td**  poiUiaN (fof fee ca6eolat lon) em h ted M lhe u nil that h ave n ot M'eady been l i s ted . Each HAP adde d t o**he ~**  i n !his s.a p may be**sin~** li sted as**AP" .**  Next, ca i Nil te PTE fo r appicabi:ity pt.l1)(ll.i85 and act u a l elris6ions tor**~** purpo ses fo r ach l i$ted 8ir poiU:&nt . 00 n ot ta i CU:ne PTE t()f' air po llu t a n ts lrseed sol ety f or Me putp<)!leS. I ncl u d e &!I fughive-s. lncldng those thaJ do not comt towatds ap pl lcabi lty ,**~ c..ak::~Aating**  edual emi&s. i OO$ , At t1 mini lft.lm , rounct '<> !he nearosc t et'W h of a t on to r yeerty values or tenth ot a po..m k> r hou rl y values . Anac:h ex a ll'C)Ie s ol calculaelons t hat ltllstrs t es the methodology used.
Ait Polk.catlls**~** regtja ! ed a1r po !l u !aO!s: and Emission Aal es CAS N o . I)Oit.M n lS f<> r \'lflieh lhe l$oOU"C. i s major) A<: IUal Po4e n lia l to Em it**Annut.~ l**  Em i ss ion s 

# - Annu al (IOO$/y1) ( lb/IYI (IOns/Yr) 

### YOM 

### 0.8833 3.87 Benzene 

### 0.000157 0 . 00006 71-43-2 Med1anol 

### 0.0929 0.4069 67-56-1 Organic Compounds 

### 0.1207 0.5287



## V E S015692

## VES015693

# VES015694
. pdf

### Ogulei , David F ro m : 

### Sent: To: Su b ject: 

### David , K l aric h , D av id <davld.k l arlch@veolia.com> Monday , Ma r ch 10 , 201 4 3 :1 1 PM Ogulei , David 

### UnHs 2 and 3 Operatio n



### Re garding the in-serv i ce dates fo r Unit 2 and Unit 3 , Uni t 2 came on-line i n October , 1986 and Unit 3 came on li ne 

### in N ovem ber , 1987. Please cont act me if you have any furt her questi ons. Dave



## VES015694

# VES015695.pdf

# ~T**HO MPSON**  

# ra cosuRNLLP J os ep h M. Kellme ve : p 31 4.552 . &166 F 3 1 4. 552 . 7166**ellmey~r@lthomp so** **"coburo .c** **m**


### September 9 , 2013 

### VIA E L ECTRONI C ANO 

### CERTD!l'lE D MAIL Robe 1 t A. Kaplan Regional Counse l U.S . Environmental Protection Agency 77 West J ackson Boulevard Chicago, Illino i s 60604 kap lan. robert @epa.gov Re: ReSPonse to USEPA Correspond ence Dated Au gust27 , 20 1 3 Regard ing Veolia ES Technical So lutions, L.L .C.**("Veolia~)** 

### Dear Bob: T h ank you f or your follow-up regarding your correspondence dated August 27 , 2013 (" Au gust 27th Letter") concerning communicat i ons between Veolia and U SEPA Re gio n 5 (''Region 5" or "Agency " ) . 1 belie v e our te lephone conversations have been p roductive and I look forwar d to working with you to resolve thi s matter. Veo l ia's respo nse to the Au g ust 27th Letter is set forth below. As I re la ted in our c o nversations, t he informat i on contained i n August 27th Letter answered some of our questi on s concerni ng why we had not rece i ve d any response from Region 

### 5 regarding our submis sions. As yo u know, on Marc h 28 , 2013, Veolia s ub mitted its co mments pertaining to Regio nS 's proposal to reopen and modi!)' V e o lia's Clean Air Act Title V operat in g perm i t ("Titl e V permit " ). The foll ow i ng day , Marc h 29, 20 13, Veolia mai l ed a letter to Re g ion 5 in an effo rt to c ont i nue to negotiate and resolve t he various open issues concerning Veolia's Title V perm i t ("March 29 th Letter " ). Among o t her items, the March 29th Letter i n cluded an o!Ter 

### b y Veolia to SPend signi:l icant resources on additional po ll ution contro l equ ip

ment at it s Sa u

ge t fucility . The . .M arch 29th Letter a l so conveyed Veo lia' s reques t for a me e t in g wi th Region 5 to furthe r dlsc\ISS Veolia ' s olfers at resolution. In ad d i tion, because Veo li a's Tit l e V permit is essential to its busi ness operat ions-an d cri t ical to Veol.ia's ability to remain a v i able regional cmp l oyerVeol i a carbon copied bo t h U.S. Re p resen tat i ve William Enyart and U.S. Rep resentative John Shimkus on t h e Marc h 29th Letter. After send in g the Marc h 29th Letter, we l earned that both congressmeu re ceived th e letter shortly after it was mailed a nd , t here f ore, we also assumed that Region 5 rece i ved th e March 29t h Letter a few days after its' mailin g. l ho mp•or: Coburn LLP 

### I Attomoys Cl Law 

### I O M U S Bo n k Pl aza 

### I S 7. Lou i s . Mi» ov ri 63 10 1 f 3l4.552 . 60CO I F 314 .55 2 . 700a ) www .th ompsonc o b u m.co m 

## VESOI5695

### September9, 201 3 Page2
Havi ng no indication that Region 5 did not, in fact, receiv e the Marc h 29th Le tter, Veolia assumed that Region 

## 5 would eventually respond. However, a$ the mo n ths passed, and still hav ing not received a res ponse from Region 5, 

### Veolia reached out to various e le cted officia l s to establish a line of co m municat ion with the Agency. The first lime Veolia had any indication that USEPA d id no t recei ve the March 29th Letter was 

### at a Ju ne 

### 5 , 2013 meeting w i th George C.r.crniak . However , at th at time, Veol ia had already reached out to the 

### Agency thro ugh various elected officia ls and understood th a t Regional Admini,trator Hedman ha d agreed to mee t with Veolia co ncerning the reopening ofVeol i a's Title V permit. Veolia also beli e ved that 

### Regional Administrator Hedman requested that Veolia provide her w i t h a document plior to the 

### m eeting setting forth the backgr ou nd for t he permit reopening and Veolia ' s positions on vario us important iss u es involved with Veolia's Title V penn it. Veolia drafted a letter and m e moran dum in response to what 

### it believed was Regional Administrator Hedman's request(" Augus t 2nd Letter"). Veo lia did not mail the 

### August 2nd Le tter to the Regional Administrator. Rather, Veo li a again reached out through various elected officia l s to communicate with the Agency. Ba.ed on this series of eve nts , we were surprised to learn that Reg io nal Administrator H edman had not agreed to meet w ith Veolia and had not requested t h e Augus t 2nd Letter. As you indicate, there bas 

### apparen t ly bee n a mi sunderstanding and a 

### m i scomm u nication regarding these issues. While there may have been a mi sunderstanding, I can assure you that-at no time-{)id Veol ia try 

### to make a false record co ncerning the would
- be m eeting between it and the Regional Administrator. Veolla was merely exp ressing its thanks to the Regional Administrator fo r agreeing to mcet·-a fac t that it believed to 

### be true 

### at the time the August 2nd Letter was drafted. To t h e extent that the Regional Administrator nev e r agreed to suc h a meeting, we apologize for this misunderstanding. As you point out, the August 2nd Letter also incl ude s Veolia's concern t hat the Agency breached i t s verbal agreeme n t concerni n g the t imi.ug of Veolia's C omprehensive Performance Testi n g (" CPT') . Unlike the meeting issue , the events surro u nding the CPT have nothing to do with the misunderstanding or miscommunication noted above . To this end, V eolia stands by its assertion that the Agency did indeed 

### faiJ to honor a verbal agreement made to Veolia in t he fall of 2008 concerning the t iming of t he CPT testing . As we discussed, this, an d the other issues set f orth in the Augus t 2nd Letter, continue to be points of contention between USE PA an d V eolia Because we have alway s believed that these issues should be addressed-and po tentially reso lved- in a high- l evel meeting between Veolia and USEPA , I was pleased when you informed me that Regional Administrator Hedman would now be open to meeting with us .



## VES015696

### September 9, 20 13 

### Pagc3 However, despite th e Reg i onal Adm i ni strator 's offer t o acconunodate our requ e st, 

### I remain hope ful that we can 

### Tesolv e th e i ssues between 

### counsel, wi tho u t th e Regional Administrator ' s interveotioo. In s u m, the August 2 7th Letter shed light o n a mi s communica ti on issue that had al s o perplexed us and 

### we apologize for the misunderstanding . Moreover, 

### we a gree t o send all f u rther corres p o nd e n ce to 

### Mr . Co h en, as sugges t ed i n your l etter . (However , as w e discussed, 

### I h ope that we can cont i nue to conununicat e di r e c t l y, by te l ephone or o therwise , about a n y i ssues th at arise as we work t oward a so lu tion f or our cl i ent s.) Please l et me know if yo u have a ny questions a n d 

### I look fo r ward to speaking wi th y o u again soon abo u t th e CPT P l an an d o t her pend ing issues . 

### V cry 

### truly yours , Tho mpso n Cob u rn 

### LLP

# }--t-1~~ J oseph 

### M. Kellmey e r

cc: 

### Mr. Do u g Harris 

### Mr . Eric Cohen Multi
- Media Branch 

### II 

### U . S. En'lir onme n tal P r otect i o n Ag ency - Region 

### 5 

### 77 W. Jackson Bouleva rd Chicago , Illino is 60604 cohen.eric@ e pa.gov



## VE S 01569 7

# VESO 15698.pdf

### Ogulel, David From: Sent : To: 

### Cc : Sub j ect: Hi David, Nan cy L Paddock < n ancy . pa d dock@veol i aes . com> T h u rsday, December 

### OS. 20 1 3 1 1:5 1 AM Ogu l e i, D a v i d Den ni s J Warcho i 

### TW I boi l er desig na t i o n

Dennis and I spoke this mom l ng abo u t !he possib ili ty of o ur bo il er b e in g an area source as opposed to a maj or so urce. Thi s i s a d i ffe r e n t pe rspect i ve for us and we'd like to un derst and a ll aspects of t hi s app r o a ch before mak in g a dec i s i o n . I w ill g et bac k t o yo u as soo n as possib le once we've had an o ppo rt un ity t o d ig e st t hing s . Thank yo u! Na n cy 

### L. Pad d ock Environmental Engi n eering Specialis t Veo li a 

### ES Tec h nica l So l u t ions, 

### L.L.C. 7 Mob il e Avenue Sauget, IL 6 2201 618.2 7 1.2804 ( ext · llS) 6 1 8 . 271.2128 ( fax) Na n cy . Paddock<iilVeo li a ES.com www . Veolia E S
.com Th i s e -ma il message fr om Veo ll a E ST ech nl cal So lu llons , LL C Is fo r lh e sole u se o f lh e I nt e nded reci p ie nt (s) and may co nt a in con fi de nt ia l and priv il eged i n f orma ti o n . Any u n a ut hor i ze d rev ie w, use , disclosure or dis t ribu tio n i s p rohi b it ed. I f yo u a r e n o t t h e inte nded r ec i pien t , p l ease com mu ni cate wit h th e se nd er by rep l y e-ma i l and d es tr oy a ll cop ie s o f th e o r igina l m essage a nd de l e t e i t f rom all comp uters.



## VES015698

# VES015699
. pdf

### Ogulei, D av id F r om: Sent T o : Subject Attachments ;

sara h Marsh a ll Mars h all , S ara h Mo nd ay , J un e 1 7 , 2 0 1 3 1 2 :24 PM Dow n ey, Shan non ; Og ul e i , Davi d FW : tE P A 6/ 1 1 / 1 3 1 ette r r esponse Ni ghti ng a l e 6 - 1 1 - 13 Leiter Respo n se. pd f

U .S. E nv ir o nm en t a l P ro tecti o n A ge ncy , R e

g i o n 5 Ai r E n f

o r cement and Comp li ance Ass u rance B ra n ch 3 1 2-886-6797 

### From: Qem i ak. GeOO'ge 

### Sent: Thu rsday, Ju ne 1 3, 20 1 3 3:53 PM To: M a rsha ll , Sa r a h Subject: FW : !EPA 6/ll/13 letter response

F rom: D o u g Har ris [ mailto:doug,harrjs@veo li aes com ) Sent: Th ursday , Ju ne 13, 20 13 3:29 PM To: Q emiak, Geo r g e Subject: FW: !EPA 6/11/13 letter r espons e Geo r ge, Attac h ed be l ow i s a adva n ced copy o f a res p onse to Mr. Nighti nga l e 6/11/ 1 3 lette r I sent yo u a copy of t h is morn in g . D on't h esit a te t o call me at t he num b ers be l ow if yo u have any qu estio n s . Do u g Ha r ri s G en era l Ma n a g er Veo li a ES Techn i ca l So l u t i o n s, L LC 7 Mo bil e Ave . S a uge t , I L 6220 1 Office 6 1 8 -2 71 -2 804 E xt. 1 0 1 Cel l : 618 · 6 1 6 - 7 420 Fax : 618·271- 2 1 2 8 Doug . harr i s@veo l i aes . com www . veo f iaes.com Serv i ce F i rs t. Saf e t y Always Th i s e-m ai messag e from Veo l i a E n viro n m e nta l Se rv i ce s North Am erica C orp. is for t he so le u s e of th e int ended r ec i pient and m a y co nt a in con fide nti a l an d pri vi lege d I nformati o n . An y u nauthorized review , u se d i sclosu r e o r di str i but i on is prohi b i t ed. If yo u a re n ot t h e i n tended r ec i pien t , pl ea s e comm u nica te w ilh t he sen der b y rep l y e -ma il an d des tro y all copies o f t he o ri gin a l m essage an d de l e t e s am e from all com p ute rs . From : Do u g Ha rr i s Sent: Th ursday, J une 13 , 2013 3:25 PM


## VES015699

### To : 'Steve.Nig htf nga l e@ll lln o i s.gov' 

### Subject: !EPA 6/11/13 letter response Mr. Nigh t ingal e, Attached i s an a dvanced copy o f a lette r I sent ou t today responding to your 6/11/13 1 etter. I f you have any que st io ns don't hes itat e to ca ll me at the n umbers be l ow . Doug Ha r ri s Genera l Manager Veol i a ES T ech n i ca l Solu t ions, 

### LLC 7 Mobi l e Ave.**Sa ge~**  I L 62201 Office 6 1 8 -2 7 1 -2804 Ext. 10 1 Ce ll: 618-616-7420 Fax: 6 1 8
- 271-2 1 28 Doug . harris@veol i aes . com VIWW . veo f iaes . com Serv i ce First. Safety Atways This**e-ma~** message from Veolia Enviro n me n tal Serv i ces No rth A m erica Co r p . 

### Is for t he sole use o f the In t e n ded recip ie nt and m ay conta i n c onfidential and privileged informatio n . A ny una u tho ri zed review , use disclos ure o r d i stribution is p roh ib it ed . I f yo u a re n ot the i nte nded recip i ent , please comm un i cate wi th th e sender by reply e-ma il and destroy all copies of t h e orig i na l message and de le t e same fr om all computers .



### VES015700