# An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale DE - FE0000833



# Final Scientific / Technical Report Report Date: June 30 , 2011

Team Members: Altela, Inc. Argonne National Laboratory BLX, Inc. CWM Environmental, Inc.

Point of Contact:

Matthew Bruff

Altela, Inc. Phone: 303
- 993
- 1951 Facsimile : 303
- 993
- 1955 Email: matthew.bruff@altelainc.com



## DISCLAIMER: “This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency there t o, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United State Government or any agen cy thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Gov ernment or any agency thereof.

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# TITLE PAGE

REPORT TITLE: An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale

TYPE OF REPORT: Scientific / Technical

REPORTING PERIOD START DATE: October 1, 2009

REPORTING PERIOD END DATE: April 10, 2011
PRINCIPAL AUTHOR(s): Matthew Bruff Ned Godshall Karen Evans DATE REPORT WAS ISSUED: July 30, 2011 ORGANIZATION : Altela, Inc. 7500 Meridian Pl. NW, Suite B Albuquerque, NM 87121

DISCLAIMER: “This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency there t o, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, p roduct, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitu te or imply its endorsement, recommendation, or favoring by the United State Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Gov ernment or any agency there of.

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## TABLE OF CONTENTS Page Abstract

................................ ................................ ................................ .......................... 4 Executive Summary .....................................................................

.. ...... 4 Report Details.................................................................................... 6 1. CONFIRM REGULATORY FRAMEWORK IS IN PLACE 1.1 National Pollution Discharge Elimination System (NPDES)

............................. 7 1.2 PA Department of Environmental Protection

................................ ..................... 9 1.3 Air Quality

................................ ................................ ................................ .......... 9 1.4 PA Bureau of Oil and Gas Management

................................ ........................... 10 1.5 UIC Injection

................................ ................................ ................................ .... 10 1.6 PA Water Quality Standards

................................ ................................ .............. 11 2. CONFIRM WATER QUALITY MEETS REGULATORY REQUIREMENTS 2.1 Baseline Water Quality Review and Site Selection

................................ ......... 14 2.2 Field Water Sampling, Analysis and Reporting for Baseline Bench Testing

... 15 2.3 Field Water Quality Analysis......................................................... 15 3 . CONFIRM SYSTEM TREATMENT EFFICACY 3.1 Bench Testing of Field Water

................................ ................................ .......... 17 3.2 Mass Balance Analysis

................................ ................................ .................... 19 3.3 Test Bench Treatment Summary

................................ ................................ ..... 20 4. SYSTEM OPERATIONS REPORT 4.1 Summary

................................ ................................ ................................ .......... 22 4.2 Gas and Electrical Usage

................................ ................................ ................. 2 6 4.3 Concentrate Disposal

................................ ................................ ....................... 2 6 4.4 Estimated Costs

................................ ................................ ................................ 27 5. LIFE CYCLE ANALYSIS REPORT 5.1 Approach

................................ ................................ ................................ .......... 29 5.2 Operations

................................ ................................ ................................ ........ 30 5.3 Capital Equipment Manufacturing

................................ ................................ ... 30 5.4 Transportation

................................ ................................ ................................ .. 31 5.5 Water Disposal

................................ ................................ ................................ . 31 5.6 Results

................................ ................................ ................................ .............. 31 5.7 Analysis

................................ ................................ ................................ ............ 32 Conclusi on ................................................................................ ....... 3 3 List of Acronyms and A bbreviations ....................................................... 35

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## APPENDICES
A. PA DEP Request f or Approval of Alternative Waste Management Practices
B. CWM Environmental, Inc. Sampling Procedures
C. Water Quality Reports (Produced Water, Frac Water and Frac Flow

- back Water)
D. Water Quality Reports (Test

- Bench Concentrate Water and Distilled Water)
E. Mass Balance Analysis
F. New Mexico Oil Conservation Division Approval for Marcellus Water
G. Photos of S ite H. Miscellaneous Charts and Graphs

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## ABSTRACT This Final S cientific / Technical Report submitted with respect to Project DE

- F E 0000 833 titled

“

An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale ” in support of final reporting requirements. This final report contains a compilation of previous reports with the most current data in order to produce one final complete document. The goal of this research was to provid e an integrated approach aimed at addressing the increasing water resource challenges between natural gas production and other water stakeholders in shale gas basins. The objective was to demonstrate that the AltelaRain ® 

## technology could be successfully deployed in the Marcellus Shale Basin to treat frac flow

- back water. That objective has been successfully met. EXECUTIVE SUMMARY The purpose of this research was to provide an integrated approach aimed at addressing the i ncreasing water resource challenges between natural gas production and other water stakeholders in shale g as basins. Pictures of the site can be found in Appendix G

. Specific goals of the project include d : 1) d eliver ing field

- proof tha t a water treatment technology wa s actually capable of treating this highly challenged Marcellus frac water to water quality standards required for discharge and/or applicable beneficial re

- use, 2) deliver ing field

- proof that the water treatment technology c ould economically treat the frac water at a cost equal to or lower than c urrent disposal methods, and 3) demonstrat ing that the regulatory environment w ould support implementation of the water treatment technology solution. With respect to verifying field

- proof that the t echnology was capable of treating Marcellus frac water to water quality standards required for discharge and/or applicable beneficial re

- use, numerous water quality analyses of the treated water were taken. Both bench

- scale water quality analyses and the first field

- based quarterly water sampling verified that the system wa s operating successfully and capable of treating the highly challenged Marcellus Shale frac flow

- back and produced water to requisite levels. With respect to those initial field water q uality analyses, the specific conductance of the untreated dirty water (PW) was 42,400 umhos/cm; the specific conductance of the clean water (DW) was 30.0 umhos/cm. Copies of the complete water quality analyses have been attached to this report as Appendi x C. Additionally , the report contains a comparison of PA DEP’s water quality requirements (as applied to latest NPDES permit

- TARM’s reporting requirements noted previously) with Altela’s water quality results from field sample s . This comparison furth er reinforces that the AltelaRain ® 

## te chnology met or exceeded required PA DEP water quality requirements. With respect to delivering proof that the treatment technology can economically treat the frac water at a cost equal to or lower than current disposal methods, the all in per barrel cost through

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## the reporting period was calculated to be $0.1 2 /gallon and $4. 88 /barrel, respectively

. This represents a minimum cost savings of 2 3 % as compared to conventional truck and disposal fees (at commercial facilities o r UIC reinjection wells). The total per barrel operating cost (OpEx) of $ 4.88 /barrel ($0. 12 /gal ) was calculated by summing the individual OpEx costs listed below:

**•** Gas Cost: $1. 74 /barrel of water eliminated
**•** Electric Cost: $0. 34 5/barrel of water eliminated
**•** Labor Cost: $2. 789 /barrel of water eliminated
**•** Consumables Cost: $0.01 /barrel of water eliminated This total per barrel operating cost (OpEx) of $ 4.88 /barrel ($0. 12 /gal) reflects the per barrel cost of the water eliminated from trucking and disposal (TR=PW

- CW). It does not include the cost of disposal of the concentrate, but it also did not divide these costs by the larger number of “how much input water was treated”. The cost calculations can (and should ) be done two different ways: (a) as above, based only on the net volume of water eliminated from trucking and disposal, TR = PW

- CW; and (b) based on the volume of water treated, PW. The latter method yields a total per barrel operating cost (OpEx) of $ 4.88 /barrel ($0. 12 /gal) and reflects the per barrel cost of the water brought into the system (PW). It therefore includes the cost of disposal of the Concentrate Water (CW). Total water treated (PW) equaled 7,120 barrels, and OpEx costs were:

**•** Total Gas Cost: $ 9,264 ($1. 74 /barrel TR X 5,324 barrels)
**•** Total Electric Cost: $ 1,837 ($0. 345/barrel TR X 5 , 324 barrels)
**•** Total Labor Cost: $ 1 4, 850 ($2. 789 /barrel TR X 5,324 barrels)
**•** Total Consumables Cost: $ 53 ($0.01 /barrel TR X 5,324 barrels)
**•** Total Disposal Cost : $ 11,315 ($6.30/barrel TR X 1,796 barrels) Total OpEx costs, including CW disposal, were therefore $ 37 , 319 . The resulting per gallon and per barrel costs were $0.1 25/gallon and $5.24 /barrel, respectively. This represents a savings of 17 % over trucking and disposal without t he Altela s ystem (1

- $ 5.24 /$6.30). This cost savings increases to 38% when trucking and disposal market pricing, post May 19 th 

## , 2011, is taken into account following Chapter 95 discharge limit enforcement. UIC disposal surcharges for out

- of

- district brine disposal are increasing total disposal costs to the E&P operators. For example, according to the Ohio Division of Mineral Resources Management (ODNR), “With the passage of Senate Bill 165 in 2010, some cha nges to the UIC Program include an increase in the Class II saltwater injection permit application fee from $100 to $1000, and an injection disposal fee of $.05 per barrel for brine originating in

- district and $.20 per barrel for brine originating out

- of

- d istrict.” In addition, January 2011, PA DEP amended Title 25, Chapter 95, Wastewater Treatment Requirements, to address the dramatic increase in Marcellus Shale wastewater that was being diluted and sent into Pennsylvania ’s surface water bodies. The

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## new 95 regulation included more stringent discharge standards including 500 mg/L for Total Dissolved Solids (TDS) and 250 mg/L each for Sulfates and Chlorides. As a result of PA DEP’s Chapter 95 regulation and ensuing enforcement efforts by PA DEP in May of 2011, the per barrel market price for disposal of Marcellus Shale wastewater has increased significantly due to increased costs to comply with the new discharge regulations. Operators have reported per barrel costs exceeding $8.50 per barrel with further increases based on proximity to Ohio or to limited disposal sites still available in Pennsylvania. This in turn, has made new technologies like the AltelaRain ® 

## process to be more economical and thereby gain additional market traction. Taking into account this new regulatory market dynamic, industry can currently realize a s avings of 38 % over trucking a nd disposal without the Altela s ystem (1

- $ 5.24 /$8.50). Moreover, as outlined in this report, t he life cycle assessment results show that experience gained from the Altela 4000 field tests have helped improve the system design and resulted in a 45% increase in overall energy efficiency for the newer Altela 600 system. In the future, if suitable sources of low grade waste heat can be located and system s co - located to take advantage of them (co

- generation projects) , the system efficiency can improve as much as 85% from the original test system. Altela is in discussion with several entities to pursue this co

- generation approach. Finally, with respect t o demonstrating that the regulatory environment support implementation of the water treatment technology solution, this report provides a review of the regulatory requirements as well as confirmation that supports implementation of the AltelaRain ® 

## water treatment technology solution in Pennsylvania’s Marcellus Shale Basin. Numerous Pennsylvania Commonwealth agencies responsible for both federal and state regulatory requirements have jurisdiction over the deployment and operation of this system dem onstration. In each case, where applicable, Recipient received approval or satisfied related permit/regulatory exemptions with respect to deploying and operating the system. Further, water quality samples taken in the field with respect to the demonstrat ion system support that the system indeed m et regulatory water quality requirements being imposed by regulators

. REPORT DETAILS By employing a technology

- based approach, Recipient demonstrate d how a water treatment technology solution can be deploy ed tha t successfully addresses perceived impediments and information gaps with respect to successfully treating flow

- back water. The research also highlight s the benefits associated with augmenting current water supply through re

- use and best water resource management. By proving such a ‘best

- practices’ approach is indeed available to industry, a transformational solution was created that does not merely mini mize potential impacts to water caused by natural gas development but rather expands and creates opportunities for water supply augmentation and associated re

- use/ conservation. The Recipient’s project team reviewed and provided written reports reflecting regulatory approvals, water quality, efficacy as well as summarizing the system operations relative to

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## project initial expectations found in the System Operations Report. Th is requ irement was stated in the Statement of Project Objectives in relation to the Milestone Review requirement for Phase I outlined below: Confirm Regulatory Framework is in Place C onfirm Water Quality Meets Regulatory Requirements. C onfirm System Treatment Efficacy System Operations 1. CONFIRM REGULATORY FRAMEWORK IS IN PLACE 1.1 National Pollution Discharge Elimination System (NPDES) This project did not require an NDPES permit as all treated, distilled water was recycled and re

used for subsequent well development and in the fracing process during the one year term of this demonstration . F ollowing the successful demonstration, future sites and projects deploying the technology may be interested in obtaining an N PDES

- based surface discharge permit. As such, a review of NPDES requirements has been included as part of this regulatory review. Produced water which is not re

- injected into the ground may be alternatively surface discharged pursuant to regulatory ov ersight. Surface discharge of produced water is governed by the United States Clean Water Act ( “ CWA ” ), also known as the Federal Water Pollution Control Act. In 1972, Congress enacted the CWA, "to restore and maintain the chemical, physical and biologica l integrity of the Nation's waters." 1 

## The CWA created both state and federal roles for the attainment of these goals. The EPA Administrator must "establish and enforce technology

- based limitations on individual discharges into the country's navigable wat ers from point sources," while each state must establish water quality standards with accompanying goals for all intrastate waters.” 2 

## Section 401 of the CWA requires oil and gas companies to apply for a NPDES permit if they are discharging produced w ater into surface waters of a state. Clean water regulations provide that there will be no discharge of water pollutants into navigable waters from any source associated with production, field exploration, drilling, well completion, or well treatment (i.e. pro duced water) without an NPDES permit. 3 

## The EPA has published federal NPDES regulations under the Clean Water Act, and may authorize states

– as well as territories and tribes

– to implement all or parts of the national program. Currently, the EPA has au thorized thirty

- seven states to implement and monitor the NPDES program. NPDES permits set specific requirements regulating the characteristics of the discharged water based on national technology

- based effluent limitations and applicable water quality st andards. The permits establish the level of performance the discharger must maintain

1 

### 33 U.S.C §§ 1251

- 1376 33 U.S.C. § 1251(a)(2002). 2 

### PUD No. 1 of Jefferson County v. Was. Dept. of Ecology, 511 U.S. 700, 704 (1994). 3 

### 40 C.F.R. § 435.32.

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## and specify monitoring, inspection, and reporting requirements and other actions necessary to achieve compliance. However, the EPA retains the opportunity to review the permits issued by the state, and formally object to elements deemed in conflict with federal requirements. NPDES permits are specifically tailored to individual facilities. General NPDES permits cover multiple facilities within a certain category located in a specific geographical area. The applicant must submit a complete application for a permit, which includes the application form and any supplemental information completed to the satisfaction of the Regional Administrator (NM

– Region 6, South Central ), who may seek further information by issuing a notice of deficiency. 4 

## The primary mechanism for regulating discharges of pollutants to receiving waters is through numerical effluent limits. The effluent limits describe the pollutants subject to monitori ng as well as quantity (concentration) of pollutants. Subpart C of 40 CFR Part 35 states that oil and gas companies located onshore may not discharge produced water into navigable waters of the United States. However, two exceptions exist: 1. Subpart E

– Allows for onshore discharge for those facilities located in the continental United States located west of the 98th meridian. Produced water with a maximum oil and grease limit of 35 mg/L may be discharged provided that the produced water is of sufficien t quality to be re

- used for wildlife or livestock watering or other agricultural uses. In addition, the produced water has to be put to use during actual discharge. 2. Subpart F

– Allows for onshore discharge for facilities that produce 10 barrels per day or less of crude oil (stripper well exception). PA DEP has issued a general NDPES permit that authorizes discharge of wastewater from stripper oil well facilities to surface waters at the site of the oil wells provided that the operator must have coverag e under the general NDPES permit or approval of an individual NPDES permit before treating waste water for discharge. See PA DEP General NPDES Permit No. PAG 310001. With respect to this project, neither exception applies since Recipient operated the demonstration directly on the pad

- site . However, following a successful demonstration, federal regulations do not preclude moving off the pad

- site to a centralized treatment facility. For example , recently the PA Department of Environmental Protection (“ DEP”) issued a NPDES individual permit to TerrAqua Resource Management, LLC authorizing the discharge into waters of Pennsylvania of treated process wastewater generated from the drilling, development and use of natural gas wells in north central Pennsylva nia (Permit No. PA0233650, Industrial Waste, SIC 1389). Based on the effluent requirements listed in this recently issued NPDES permit, Recipient’s water quality results demonstrate that it w as able to comply with such an NPDES framework. In addition, Re cipient has previously demonstrated its ability to meet stringent NPDES

- based effluent limitations when it received NPDES approval to discharge into the Colorado River Basin. Therefore, when and if applicable for future commercial deployments, Recipient i s confident that

4 

### 40 CFR § 122.21(e).

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## NPDES requirements can be achieved. It is important to note that the need for an NPDES permit may not be widely in demand. Both the regulatory community and natural gas operators have stressed the need and demand for every drop of clean water that can be achieved through treatment for re

- use and recycling efforts. 1.2 PA Department of Environmental Protection The Pennsylvania Department of Environmental Protection (“ PA DEP”), previously the Department of Environmental Resources, was created in 1995 to help protect the Commonwealth’s environment and to assure its residents of clean air and pure water. One method the DEP employs to meet its mission is through a system of permits, licenses, registrations, and certifications. Although some DEP authorizations are issued within the central office in Harrisburg, PA, the majority are issued through the department’s six regional offices. Based on the site selected for this project (Sleppy well located in Indiana County), the Southwestern Re gional DEP office has jurisdiction (located at 400 Waterfront Drive, Pittsburgh, PA 15222). In addition, Recipient had several regulatory meetings with PA DEP’s main office in Harrisburg beginning in early January 2010 to discuss and review the various re gulatory requirements and anticipated benefits associated with this NETL project. Representatives from water quality, air quality, waste management and the oil and gas attended and were very helpful in providing both policy and regulatory guidance. 1.3 Air Quality Pennsylvania’s Air Pollution Control Act provides that no person shall construct, assemble, install or modify any air contamination source, or install thereon any air pollution control equipment or device unless the person has applied to and received written approval from the Pennsylvania DEP. The process of obtaining an air permit generally consists of two steps. The first step is obtaining a pre

- construction permit authorization (known as a Plan Approval). The second step is obtaining an Operating Permit to allow actual operations at the facility. However, not all air contamination sources require a Plan Approval or Operating Permit. Some may be exempt under PA C ommonwealth regulations. Under 25 PA. Code § 127.14, if the air contaminati on sources being referenced are exempt based on the Air Quality Exemption List, or if the PA DEP determines the sources to be of minor significance, a Plan Approval and/or Operating Permit were not required. With respect to this project, the AltelaRain ® 

## System is exempt based on the Air Quality Exemption List. See Section 127.14(a)(8) Exemption No. 38

– Oil and gas exploration and production facilities and operations that include wells and associated equipment and processes used either to: a) drill or a lter oil and gas wells; b) extract, process and deliver crude oil and natural gas to the point of lease custody transfer; c) plug abandoned wells and restore well sites, or d) treat and dispose of associated wastes.

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## 1.4 PA Bureau of Oil and Gas Manage ment DEP’s Bureau of Oil and Gas Management is responsible for the statewide oil and gas conservation and environmental programs to facilitate the safe exploration, development, recovery of Pennsylvania's oil and gas reservoirs in a manner that will protect the commonwealth's natural reso urces and the environment. The B ureau develops policy and programs for the regulation of oil and gas development and production pursuant to the Oil and Gas Act, the Coal and Gas Resource Coordination Act, and the Oil and Gas Conservation Law; oversees the oil and gas permitting and inspection programs; develops statewide regulation and standards; conducts training programs for industry; and works with the Interstate Oil & Gas Compact Commission and the Technical Adviso ry Board. The Oil and Gas Bureau directed Recipient to complete and file a Request for Approval of Alternative Waste Management Practices (PA DEP Form No. 5500

- PM

- OG0071) with respect to deploying and using the AltelaRain ® 

## system at the Sleppy well

- pad i n support of the project. A copy of the approved application has been included as Appendix A. 1.5 UIC Injection The Altela ARS evaporation

- condensation process generates two liquid streams. The first stream consists of the clean, distilled water (“DW”). The second, or c oncentrate w ater stream (“CW”), is the residual liquid solution remaining after approximately 80 % of the pure H2O has been removed via the recycling process. This residual CW solution will contain nearly 100% of the salt products by weight contained in the original volume of the produced/frac water processed through the system in a 24

- hour period of time. The clean D W produced during the recycling process will be available for re - use by natural gas producers in on

- going drilling operations. The residual C W , containing nearly 100% of the salt products that enter the facility, will be removed from the site and transferred to an approved underground reinjection well or commercial disposa l facility

. Recipient is exploring other recycling uses for this CW as regulations permit (heavy brin e water or road salt). Regulatory control of the injection of produced water into injection wells is governed by the Federal Safe Drinking Water Act, Underground Injection Control (UIC) Program. The charter of this federal a ct is to ensure high quality drinking water by limiting the injection of produced water to injection zones that geologically will never serve as an Underground Source of Drinking Water ( “ USDW ” ). A USDW is an aquifer or portion of an aquifer that supplies any public water system or contains sufficient quantity of groundwater to supply a public water system; currently supplies drinking water for human consumption or contains fewer t han 10,000 milligrams/liter total dissolved solids; and is not an aquifer exempted from UIC regulations. 5

5 

### 40 C.F.R. § 144.3 

## Class I wells are used for the injection of hazardous and non

- hazardous fluids (industrial and municipal wastes).

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## Class II wells inject brines and o ther fluids associate d with oil and gas production. Class III wells inject mining fluids. Class IV wells deal with the injection of ha zardous or radioactive wastes. Class V wells govern injection not covered above. The EPA’s regulations establish mini mum standards for state programs to receive primacy for the UIC program under Section 1422 of the SDWA. In 1981, the federal government added Section 1425 to the SDWA to relieve oil and gas re

- injection well programs in the states of having to meet the te chnical requirements of the federal UIC program. Recipient received approval to dispose of the CW at the following UIC injection well s located in Ohio: Miller Co. (OH Injection Well Permit No. 4355), D

- 1 (OH Injection Well Permit No. 2403, Renshaw (OH In jection Well Permit No. 927), Ows (OH Injection Well Permit No. 682) and Clinton (OH Injection Well Permit No. 3262). D ue to geological limitations, very few underground injection wells are available in PA. In addition, Recipient received approval to uti lize Hart Resources Technologies, Inc. for fluid disposal, if needed. 1.6 PA Water Quality Standards Pen nsylvania Code, Chapter 93 sets forth the water quality standards for surface waters of the Commonwealth including wetlands. These standards are based upon water uses which are to be protected and will be considered by the Department in implementing its a uthority under the Clean Streams Law and other statutes that authorize protection of surface water quality. See generally t he Clean Streams Law, the Act of June 22, 1937 (P.L. 1987, No. 394), as amended, 35 P.S. § 691.1 et seq.; The Clean Water Act (33 U. S.C. § 1251 et seq.); regulatory cite: 25 Pa. Code Chapters 91 through 105 as applicable. No specific water quality effluent guidelines are provided in a simple regulatory chart. Rather, effluent guidelines are derived from a multitude of consideration s including critical uses, protective water uses, anti

- degradation, etc. With respect to Recipient’s project, a baseline water quality parameter list was developed by employing specific water quality criteria outlined in Table 3, § 93.7 of the PA Code as well as DEP Bureau of Waste Management Form 26R

– Chemical Analysis of Residual Waste. In addition, several parameters were added to assist in tracking treatment performance. The 118 P arameter List (increa sed to 121 parameters when Thorium 228, 230 and 2 32 were added) is included on the following page.

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## Parameter List:
1. Acidity 2. Hardness, Total 3. Calcium 4. Magnesium 5. Alkalinity 6. Bicarbonate 7. Total Dissolved Solids 8. Specific Conductance 9. Chloride 10. Fluoride 11. Sodium 12. Total Suspended Solids 13. Total Residual Chlorine 14. Ammonia Distillation 15. Ammonia Nitrogen 16. Total Kjeldahl Nitrogen 17. BOD 18. COD 19. E Coli 20. Total Coliform 21. Heterotrophic Plate Count 22. Color 23. MBAS 24. pH 25. Oil & Grease 26. Osmotic Pressure 27. Temperature (F), Field 28. Gross Alpha DW 29. Gross Beta DW 30. Barium 31. Boron 32. Bromide (EPA 300.1) 33. Bromide (EPA 300) 34. Cobalt 35. Copper 36. Iron 37. Iron, Dissolved 38. Lithium, Total 39. Manganese 40. Molybdenum 41. Phenolics 42. Potassium 43. Radium 226 44. Radium 228 45. Silica, Dissolved 46. Silicon, Total 47. Strontium 48. Sulfate 49. Acetone 50. Gasoline Range Organics 51. Benzene 52. mp - Xylene 53. o - Xylene 54. Total Xylenes 55. Toluene 56. Diesel Range Organic C10

- C28 57. Ethane 58. Formaldehyde 59. Methane 60. Methanol 61. Alkalinity, Carbonate 62. Alkalinity, Hydroxide 63. Alkalinity, Phenolphthalein 64. Aluminum 65. Antimony 66. Arsenic 67. Beryllium 68. Cadmium 69. Chromium 70. Lead 71. Mercury 72. Nickel 73. Nitrate 74. Nitrate / Nitrite 75. Nitrite 76. Selenium 77. Silver 78. Thallium 79. Tin 80. Titanium 81. Uranium 82. Vanadium 83. Vinyl Chloride 84. Zinc 85. 1,1,1

- Trichloroethane 86. 1,1,2,2

- Tetrachloroethane 87. 1,1,2

- Trichloroethane 88. 1,1

- Dichloroethane 89. 1,1

- Dichloroethene 90. 1,2 Dibromoethane 91. 1,2

- Dibromo

- 3

- chloropropane 92. 1,2

- Dichloroethane 93. 1,2

- Dichloropropane 94. 2

- Butanone (MEK) 95. 2

- Hexanone 96. 4

- Methyl

- 2

- Pentanone(MIBK) 97. Bromochloromethane 98. Bromodichloromethane 99. Bromoform 100. Bromomethane 101. Carbon Disulfide 102. Carbon Tetrachloride 103. Chlorobenzene 104. Chlorodibromomethane 105. Chloroethane 106. Chloroform 107. Chloromethane 108. cis

- 1,2

- Dichloroethene 109. cis

- 1,3

- Dichloropropene 110. Ethene 111. Ethylbenzene 112. Ethylene Glycol 113. Methylene Chloride 114. Styrene 115. Tetrachloroethene 116. trans

- 1,2

- Dichloroethene 117. trans

- 1,3

- Dichloropropene 118. Trichloroethene 119. Thorium 228 120. Thorium 230 121. Thorium 232



## This water quality parameter list was used to develop baseline water quality data for Marcellus Shale prod uced water, frac water and frac flow

- ba ck water (Appendix C). In addition, this baseline water quality parameter list was used in the analysis of the treated distilled water and concentrate water following test

- bench testing o f the prod uced water, frac water and frac flow

back water (Appendix D).

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## On February 27, 2010, PA DEP released the effluent limits for a precedent setting individual NPDES permit for process wastewater generated from the drilling, development, and use of natural gas wells in north central Pennsylvania and discharge of treated effluent (Marcellus Shale wastewater). As noted earlier, this permit was issued to TerrAqua Resource Management, LLC (PA0233650, Industrial Waste, SIC 1389) in late February 2010 aft er Recipient ’ s water analysis. The monitored parameters and related effluent limits for TerrAqua Resource Management, LLC are comprehensive based on the precedent

- setting nature of this permit and provide additional direction on what effluent requirements will be employed for any additional centralized Marcellus Shale waste water treatment facilities. In addition, it is important to note that many of the parameters included in this recently issued permit have no individual limit but rather have a “Monitor ” and report requirement. These parameters include:

1. BOD 5 

### 21. Iron, Dissolved 41. Lithium 2. Total Suspended Solids 22. Silver, Total 42. Magnesium 3. Oil & Grease 23. Boron, Total 43. MBAS (Surfactants) 4. pH (standard units) 24. Cobalt, Total 44. Molybdenum 5. Ammonia

- N 25. Arsenic, Total 45. Osmotic Pressure (mosm/kg) 6. Aluminum, Total 26. Cadmium, Total 46. Sodium 7. Acetone 27. Lead, Total 47. Specific Conductance (umho/cm) 8. Acetophenone 28. Mercury, Total 48. Total Dissolved Solids 9. 2

- Butanone 29. Nickel, Total 49. Chlorides 10. o - Cresol 30. Selenium, Total 50. Sulfates 11. p - Cresol 31. Benzene 51. Radium 226/228 (pCi/L) 12. Phenol 32. Toulene 52. Gross Alpha (pCi/L) 13. Pyridine 33. Alkalinity, Total as CaCO 3 

### 53. Acidity 14. 2,4,6

- Trichorophenol 34. Beryllium 54. Ammonia

- N 15. Copper, Total 35. Bromide 55. Kjeldahl

- N 16. Zinc, Total 36. Calcium 56. Nitrate

- Nitrite as N 17. Barium, Total 37. Chemical Oxygen Demand 57. Total Nitrogen 18. Strontium, Total 38. Chromium, Total 58. Total Phosphorus 19. Iron, Total 39. Ethylene Glycol 59. Net Total Nitrogen 20. Manganese, Total 40. Hardness, Total as CaCO 3 

### 60. Net Total Phosphorus 

## In addition to the above effluent limits, the permit contains Chesapeake Bay Nutrient Requirements. Though no surface discharge occurred as part of this technology demonstration, it is nonetheless important for future adoption of the technology that the t echnology is capable of meeting proposed effluent limit requirements. Based on the extensive water quality analysis performed to date for the project, the technology is capable of purifying this highly challenged Marcellus Shale frac and produced water to a quality commensurate with surface discharge in accordance with regulatory requirements. As highlighted above, the regulatory environment support s implementation of the AltelaRain ® 

## water treatment technology solution in Pennsylvania’s Marcellus Shale Basin

. Numerous

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## Pennsylvania Commonwealth agencies responsible for both federal and state regulatory requirements have jurisdiction over the deployment and operation of this system demonstration. In each case, where app licable, Recipient received approval or satisfied related permit/regulatory exemptions with respect to deploying and operating the system. Moreover, a lthough many factors create d potential barriers to implementation of the AltelaRain ® 

## technology in Pennsy lvania and later in other Marcellus Shale regional states, none of them were critical barriers. The Recipient collected data and interacted with the PA DEP to address concerns. No barriers interfere d with the successful completion of the full project. Water quality samples taken in the field with respect to the demonstration system support ed the system indeed m et regulatory water quality requirements being imposed by regulators. Beginning January of 2011, PA DEP amended Title 25, Chapter 95, Wastewa ter Treatment Requirements, to address the dramatic increase in Marcellus Shale wastewater that was being diluted and sent into PA’s surface water bodies. The new 95 regulation included more stringent discharge standards including 500 mg/L for Total Disso lved Solids (TDS) and 250 mg/L each for Sulfates and Chlorides. The previous PA administration had “grandfathered” 27 facilities that had been accepting Marcellus Shale wastewater prior to the promulgation of Chapter 95 regulations. Some of the “grandfat hered” facilities voluntarily ceased accepting Marcellus Shale wastewater following the new rulemaking. However, 1 6 facilities (either a publically owned treatment work (i.e. municipal sewer system) or commercial treatment facility (i.e. Franklin Brine or Warren Brine ) continued accepting Marcellus wastewater. On April 19, 2011, a press release was issued by PA DEP notifying the E&P industry that it would now begin enforcing the recently passed Chapter 95 regulations. PA DEP provided t hirty days for industry to comply. According to Kay Gresch, PA DEP, “M ore than half of those (16 ) facilities are now up for permit renewal. Now is the time to take action to end this practice.” As a result of PA DEP’s Chapter 95 regulation, the per barrel market price for disposal of Marcellus Shale wastewater has increased significantly due to increased costs to comply with the new discharge regulations. This in turn, has made new technologies like the AltelaRain ® 

## process to be more economical and thereby gain additional market traction. 2. CONFIRM WATER QUALITY MEETS REGULATORY REQUIREMENTS 2.1 Baseline Water Quality Review and Site Selection Recipient conducted a preliminary review of existing water quality analyses to assist in determining a demonstration site that produce d water w ith quality requirements that m et the specifications of the treatment system. Frac water and related produced water is highly

- complex in the wide variety of its inherent contaminates (e.g., metals, sulfates, chlo rides, proprietary constituents, etc.) . One common component is the highly challenged waters nearly always have high levels of TDS. Based on these existing water quality analyses, Western Pennsylvania was

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## targeted resulting in the selection of the demons tration

- site at the Sleppy well pad located in Indiana County (True Latitude: North 40 d, 36’ 16.60”, True Longitude: West 78 d, 5 7’ 39.45”). The well operator wa s BLX, Inc., DEP Id. No. 27365. The DEP Well Permit No. for the Sleppy well

- pad is 37

- 063

- 36534. 2.2 Field Water Sampling, Analysis and Reporting Field water samples were pulled from two well locations in Butler County, PA during the first week of February 2010. Based on the close geographic proximity of these wells, assumptions on the water samples possessing similar chemical constituents from the Marcellus Shale geologic formation are presumed valid. CWM Environmental, Inc.’s trained personnel collected these water samples. The produced water (PW) was pulled at the Ross Well site using the grab sample technique on 2/2/10 following CWM’s s tandard sampling procedure ( Appendix B). Four 55 gallon drums of PW were filled onsite and transported to Altela’s Albuquerque facility for testing. Additionally, a small quantity of this raw water was captured and analyzed at CWM Environmental, Inc.’s water te sting laboratory to determine chemical constituents bef ore Altela test

- bench testing. F our barrels each of frac and flow back water were also pulled from the Bergbigler Well on 2/2/10 and 2/7/10, respectively, for shipment to Altela. Similar to the Ross Well site, raw water samples were analyzed at CWM Environmental, Inc.’s water testing laboratory to determine chemical constituents before Altela ’s test

- bench testing. Prior to shipping, Altela coordinated with the New Mexico Oil Conservation Division (N M OCD) to acquire a regulatory approval to store and utilize real gas field produced water and frac water for the test

- bench testing and analysis (Appendix F). The laboratory results of the raw water constituent analysis for each sample water type are fo und in Appendix C. In addition, the chemical concentrations and resultant masses of each constituent were utlilized for the mass balance analysis found in section 3.2 of this report

. 2.3 Field Water Quality Analysis C onsistent with Milestone 7, the first field

- based quarterly water sampling was taken on September 13, 2010. These water samples were taken and analyzed by a certified wate r quality laboratory to verify the system wa s operating successfully and capable of treating the highly challenged Marcellus Shale frac flow

- back and produced water. These water quality analyses demonstrate d the system’s ability to treat highl y challenged water and produce extremely clean water output . The initial specific conductance o f the untreated dirty water (PW) was 42,400 umhos/cm; the specific conductance of the clean water (DW) was 30.0 umhos/cm. Copies of the complete water quality analyses have been attached to this report as Appendix C

.

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## The chart below compares PA DEP’s water quality requirements (as applied to latest NPDES permit

- TARM ’s r eporting requirements noted above) with Altela’s water quality results from quarterly samples taken. Additional parameters were tested as indicated in the chart below. The complete water quality analyses reinforces th at the AltelaRain technology met or exceeded required PA DEP water quality requirements.

QUARTERLY RESULTS OF CHEMICAL ANALYSES OF PW & DW PARAMETERS TERRAQUA EFFLUENT LIMITATIONS / CONCENTRATIONS ALTELA RESULTS

Sample ID # Mo. Avg. Daily Max. Instan t Max. Pre Treated (PW) Altela Treated (DW) Pre Treated (PW) Altela Treated (DW) Pre Treated (PW) Altela Treated (DW) Pre Treated (PW) Altela Treated (DW) Sampling Date 9.13.2010 9.13.2010 2.15.11 2.15.11 3.31.2011 3.31.2011 4.6.2011 4.6.2011 1 PA Biochemical Oxygen Demand mg/L 53 163 204 76.8 <2 107 26.6 83.9 27.1 99.6 38.8 2 PA Total Suspended Solids mg/L 30 45 60 114 3 35 3 60 <3 54 <3 3 PA Oil and Grease mg/L 15 30 1.6 2.1 0.1 2.6 2.7 3.2 3.7 1 4 PA pH pH Units 9 7 7.87 6.5 4.73 6.9 6.24 6.51 5.77 5 PA Total Ammonia (N) mg/L 25 50 63 17.8 3.88 28.1 1.77 10.2 4.42 23.1 3.25 6 PA Total/Dissolved Aluminum (Al) mg/L 2 4 5 <1 <0.1 <1 <0.1 <5.0 <0.10 <5.0 <0.10 7 Acetone ug/L 7.97 30.2 37.8 13800 949 8710 524 11800 658 8 Acetophenone mg/L 0.056 0.114 0.14 9 2

- Butanone mg/L 1.85 4.81 6 ND ND ND ND ND ND 10 o - Cresol mg/L 0.561 1.92 2.4 11 p - Cresol mg/L 0.205 0.698 0.873 12 Phenol/Phenolics (Total) mg/L 1.08 3.65 4.56 0.01 0.03 ND 0.03 ND 0.02 ND 0.02 13 Pyridine mg/L 0.182 0.37 0.455 14 2,4,6

- Trichlorophenol mg/L 0.106 0.155 0.265 15 PA Total/Dissolved Copper (Cu) mg/L 0.321 0.501 0.803 0.33 <0.02 <0.2 0.07 <1.0 <0.02 <1.0 0.08 16 PA Total/Dissolved Zinc (Zn) mg/L 0.42 0.497 1.05 <0.2 <0.02 <0.2 0.05 <1.0 <0.02 < 1.0 0.04 17 PA Total/Dissolved Barium (Ba) mg/L 10 20 25 405.5 <0.1 332.2 0.33 284.7 2.47 260.5 4.54 18 PA Total/Dissolved Strontium (Sr) mg/L 10 20 25 379 0.026 317.8 0.35 264.2 2.28 233 3.93 19 PA Total Iron mg/L 3 6 7.5 23.1 <0.02 17.4 0.12 17.6 0.02 18.5 0.08 20 PA Total/Dissolved Manganese (Mn) mg/L 2 4 5 2.9 <0.02 2.1 <0.02 2 <0.02 2 0.04 21 PA Dissolved Iron (Fe) mg/L Monitor Monitor 7 22.9 <0.02 21.1 <0.02 13.9 0.03 14.3 0.06 22 PA Total/Dissolved Silver (Ag) mg/L 0.093 0.145 0.233 <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005 23 PA Total/Dissolved Boron (Bo) mg/L Monitor Monitor 3.12 0.02 2.7 0.05 2 0.06 <1.0 0 .06 24 PA Tota;/Dissolved Cobalt (Co) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 < 0.25 <0.005 <0.01 <0.005 25 PA Total/Dissolved Arsenic (As) mg/L Monitor Monitor 0.028 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005 26 PA Total/Dissolved Cadmium (Cd) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 < 0.25 <0.005 <1.0 <0.005 27 PA Total/Dissolved Lead (Pb) mg/L Monitor Monitor <0.2 <0.02 <0.02 <0.02 <1.0 <0.02 <1.0 <0.02 28 PA Total/Dissolved Mercury (Hg) mg/L Monitor Monitor ND ND ND ND ND ND 29 PA Total/Dissolved Nickel (Ni) mg/L Monitor Monitor <0.5 <0.05 <0.5 <0.05 <2.5 <0.05 <2.5 <0.05 30 PA Total/Dissolved Selenium (Se) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005 31 PA Benzene ug/L Monitor Monitor ND ND ND ND ND ND ND ND 32 PA Toluene ug/L Monitor Monitor ND ND 8.3 ND 10.9 1.3 15 1.1 33 PA Alkalinity (Total as CaCO3) mg/L Monitor Monitor 102 14 110 <5 88 <5.0 100 12 34 PA Dissolved Berylium (Be) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 < 0.005 <0.01 <0.005 35 PA Dissolved Bromide (Br

- ) mg/L Monitor Monitor 162.5 <0.3 118.5 <0.10 101 0.92 117 1.6 36 PA Dissolved Calcium (Ca+) mg/L Monitor Monitor 1933 0.36 1634 2.18 1186 11.1 1175 22.2 37 PA Chemical Oxygen Demand mg/L Monitor Monitor 289 < 10 344 48.3 220 35.8 265 51.4 38 PA Total/Dissolved Chromium (Cr) mg/L Monitor Monitor <0.2 <0.02 <0.2 <0.02 <1.0 <0.02 <1.0 <0.02 39 PA Ethylene Glycol mg/L Monitor Monitor ND ND ND ND ND ND ND ND 40 PA Hardness (CaCO3) mg/L Monitor Monitor 5555 <10 4655 <10 3461 32 3386 64 41 PA Dissolved Lithium (Li) mg/L Monitor Monitor 14.3 ND 10.7 ND 9.1 0.082 10.7 0.13 42 PA Dissolved Magnesium (Mg) mg/L Monitor Monitor 176.8 <0.1 139.5 0.36 121.3 1.1 109.8 2.04 43 PA MBAS (Surfactants) mg/L Monitor Monitor 0.18 ND ND ND ND ND ND ND 44 PA Dissolved Molybdenum (Mo) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.2 5 <0.005 <0.01 <0.005

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### Page 17 of 35 QUARTERLY RESULTS OF CHEMICAL ANALYSES OF PW & DW PARAMETERS TERRAQUA EFFLUENT LIMITATIONS / CONCENTRATIONS ALTELA RESULTS

Sample ID # Mo. Avg. Daily Max. Instant. Max. Pre Treated (PW) Altela Treated (DW) Pre Treated (PW) Altela Treated (DW) Pre Treated (PW) Altela Treated (DW) Pre Treated (PW) Altela Treated (DW) Sampling Date 9/13/2010 9/13/2010 2/15/2011 2/15/2011 3.31.2011 3.31.2011 4.6.2011 4.6.2011 45 PA Osmotic Pressure mosm/kg Monitor Monitor 808 ND 637 ND ND ND 589 ND 46 PA Dissolved Sodium (Na+) mg/L Monitor Monitor 7781 0.37 5868 6.42 4726 43.8 4712 87.9

47 PA Specific Conductance/Conductivi ty uS/cm Monitor Monitor 42400 30 34300 74.5 2845 0 375 31600 632 48 PA Total Dissolved Solids mg/L 500 1000 1250 37600 9 26055 33 22350 196 25560 400 49 PA Dissolved Chloride (Cl

- ) mg/L 250 500 625 16240 2.9 11670 14.6 9760 99.1 11352 184.2 50 PA Dissolved Sulfate (SO4

- ) mg/L 250 500 625 34 <1 20.4 2.2 <100.0 1 .98 <100 2.1 51 PA Radium 226 pCi/L Monitor Monitor 162 0.278 153 0.224 155 2.87 130 2.3 52 PA Radium 228 pCi/L Monitor Monitor 85.5 0.259 45 1.32 51.9 0.296 55 0.49 53 PA Gross Alpha pCi/L Monitor Monitor 352

- 0.409 664 0.841 161 1.93 249 6.49

54 PA Acidity mg/L Less than Alkalinit

y - 30 6 <5 16

- 26 <5.0

- 16 <5.0 55 Ammonia

- N Report 17.8 3.88 28.1 1.77 10.2 4.42 23.1 3.25 56 PA Total Kjeldahl Nitrogen mg/L Report 1.4 3.3 ND 1.5 30.1 4.5 19.7 4.1 57 PA Nitrate plus Nitrite Dissolved mg/L Report <2 <0.2 <2 <0.2 <20.0 <0.20 <20 < 0.20 58 Total Nitrogen Report 59 Total Phosphorus Report OTHER PARAMETERS TESTED BY ALTELA 60 PA Color pccu 200 <5 130 <5 55 <5 75 <5 61 PA Temperature F 62.3 136.1 63 135 51 109 61 97 62 PA Total Residual Chlorine mg/L <.10 <0.10 0 0.45 0 0.21 0 0 63 PA Dissolved Nitrate (N) mg/L <1 <.010 <1 <.10 <10.0 <0.10 <10 <0.10 64 PA Dissolved Nitrite (N) mg/L <1 <0.1 <1 <0.1 <10.0 <0.10 <10 <0.10 65 PA Alkalinity (PP as CaCO3) mg/L ND ND ND ND ND ND ND ND 66 Hydroxide (OH) mg/L ND ND ND ND ND ND ND ND 67 Carbonate (CO3) mg/L ND ND ND ND ND ND ND ND 68 Bicarbonate (HCO3) mg/L 102 14 110 <5 88 <5.0 100 12 69 Dissolved Fluoride (F

- ) mg/L 4.8 <0.2 <2 <0.2 <20.0 0.32 <20 0.42 70 Dissolved Potassium (K) mg/L 95.5 <0.1 66.2 <0.10 63.2 0.52 59.6 0.98 71 Dissolved Silica (SiO2)) mg/L 30 ND 25 ND 16 ND 19 ND 72 Total Silicon (Si) mg/L 7 0.19 6.4 0.19 5.1 0.16 6.4 0.22 73 Ethylbenzene ug/L ND ND ND ND ND ND ND ND 74 o - Xylene ug/L ND ND ND ND ND ND ND ND 75 m & p

- Xylene ug/L ND ND ND ND 2.3 ND ND ND 76 Xylenes (Total) ug/L ND ND ND ND ND ND ND ND 77 PA GRO (C5

- C12) Gasoline ug/L ND ND ND ND ND ND ND ND 78 PA DRO (C8

- C36) Diesel mg/L 5.4 0.99 7.1 2.3 4 4.9 4.3 3.1 79 PA Methane (CH4) ug/L 748 1.3 5490 ND 3570 ND 4550 ND 80 Methanol (CH4O) mg/L ND ND ND ND ND ND ND ND 81 Formaldehyde (CH2O) mg/L ND ND ND ND ND ND ND ND 82 PA Gross Beta pCi/L 189

- 0.141 847 0.259 79.7 1.57 178 0.754 83 PA Thorium 232 pCi/L

- 0.005 0.025 0.114 0.011 0.055 0.016 0.035

- 0.009 84 Dissolved Antimony (Sb) mg/L <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0. 005 85 Dissolved Thallium (Tl) mg/L <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005 86 Dissolved Tin (Sn) mg/L <0.05 <0.005 <0.05 <0.007 <0.25 <0.005 <0.01 <0.005 87 Dissolved Titanium (Ti) mg/L 0.037 <0.005 <0.05 <0.005 <0.25 <0.005 < 0.01 <0.005 88 PA Dissolved Uranium (U) mg/L ND ND ND ND ND ND ND ND 89 Dissolved Vanadium (V) mg/L ND ND ND ND ND ND ND ND


## 3. CONFIRM SYSTEM TREATMENT EFFICACY 3.1 Bench Testing of Field Water The purpose of bench testing the produ ced water, frac

- water, and flow

- back water was to determine the performance of the Altela ART

- 500 tower during concentration testing runs of the three water samples with respect to treatment efficacy

. The testing created CW and DW samples from each raw water grab for subsequent mass balance analysis. Tower treatment rate, volume reduction, and f

- values (a measure of tower efficiency referred to by Altela as the Energy Re

- Use Factor) were calculated from the data generated over a testing period spanning 6

- 8 h ours.

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## Test Details An ART

- 500 tower was used to perform the testing on Altela’s t est b ench a pparatus. During the testing, approximately 150 gallons of the test water was treated. The following data points were obtained throughout the series of testing a nd were used to calculate performance :

**•** PW Flow Rate
**•** Air Flow Rate
**•** Steam Rate
**•** Gas Consumption
**•** Time
**•** Produced Water Temperatures
**•** Tower Top Temperature
**•** Conductivity of Produced Water
**•** Conductivity of Concentrated Water
**•** Conductivity of Distilled Water
**•** Produced W ater Volume
**•** Distilled Water Volume The data listed above was obtained at the following PW/CW volume increments of 150, 125, 100, 75, 50, and 25 gallons. The first test data set was conducted on the produced water. The starting tank volume before recirculation of the produced water through the ART

- 500 Tower was 211.37 gallons. The end tank volume after draining the tower was 96.28 gallons, resulting in a 5 4% volume reduction. The overall amount of produced water treated over the 8.42 hour test period was 115.09 gallons for an average treatment rate of 13.7 GPH. An average f value of 1.57 was calculated. The second test set was per formed on the frac water . The starting tank volume b efore recirculation of the frac water through the tower was 193.55 gallons. The tank volume after the testing was completed and the tower was drained was 54.20 gallons, resulting in a 72% vo lume reducti on. The total frac wate r treated was 139.35 gallons over a 6.25 hour test period which results in an average treatment rate of 22.30 GPH. An average f value of 2.41 was calculated. The third set of testing done was on the flow

- back water. The starting tank volume was 194.04 g allons before recirculation of the flow

- back water through the tower. The tank volume after the testing was completed and the tower was drained was 53.96 gallons, resulting in a 73% vo lume reduction. The total flow

- back water treated was 140.08 gallons, with a treatment rate of 21.82 GPH over the 6.42 hour test period. An average f value of 2.32 was calculated. The standard ART

- 500 Tower test protocol uses a pure s odium c hloride solution at a 35,000 ppm concentration with an average treatment rate of 26.70 GPH and an average f value of 3.10. When comparing the test results from the Marcellus Shale produced water with t he tests results from the pure sodium c hloride solutio n, the treatment rate of the tower is 49% less. Compariso n

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## of the frac water and the flow

- b ack wa ter treatment rate to the pure sodium c hloride solution showed that the treatment rate of the tower decreased by 17% and 18% respectively. The 49% reduction in treatment efficiency of the ART

- 500 tower when treating the Marcellus produced water can be attributed to the 195,000 ppm initia l concentration of the water. The further increase in concentration of the produced water during the test drove the concentr ation of the water towards the saturation point o f the sodium c hloride solution. In other words, the Sodium Chloride salt would have begun to precipitate out of the water. Total volume reduction of PW, frac, and frac flow

- back water is dependent on init ial concentration of total dissolved solids, primarily salts, in the samples tested, and tower run time. T est bench testing and related analysis indicated tower test time for the frac and flow

- back water would further reduce the volume with minor negativ e effects on treatment rate or f factor. 3.2 Mass Balance Analysis As noted previously, three large

- volume samples of real

- world Marcellus Shale gas water were obta ined from three different well

- sites in western Pennsylvania. Their labels and initial volumes of brackish raw water are listed below: 1. Sample 1: Label "Frac Water"; PW =194 gallons. 2. Sample 2: Label "Produced Water"; PW =211 gallons. 3. Sample 3: Label "Flow

- Back Water"; PW =194 gallons. All three samples were shipped to Altela's f acility in Albuquerque NM, where they were successively processed through Altela's standard AltelaRain ® 

## towers. The amount of Concentrate Water (CW) and Distilled Water (DW) generated by each sample was measured upon completion of each test, and their res pective volumes are listed below: 4. Sample 1: Label "Frac Water"; CW = 54 gallons and DW = 140 gallons. 5. Sample 2: Label "Produced Water"; CW = 96 gallons and DW = 115 gallons. 6. Sample 3: Label "Flow

- Back Water"; CW = 54 gallons and DW = 140 gallons. The Treatment Rate (TR=PW

- CW) and Recovery Rate (RR=1

- CW/PW) from each of these three tests are easily calculated from the above PW and CW amounts and are listed below: 7. Sample 1: Label "Frac Water"; TR = 140 gallons and RR = 72.2%. 8. Sample 2: Label "Produce d Water"; TR = 115 gallons and RR = 54.5%. 9. Sample 3: Label "Flow

- Back Water"; TR = 140 gallons and RR = 72.2%.

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## Water Quality Measurements All six (6 ) water volumes listed above ( CW and DW samples each from the prod uced water, frac water and frac flow

- bac k water ) had representative water samples sent to a third

- party environmental water quality firm, CWM Environmental, Inc. Each of the se 6 water samples was measured for the individual baseline constituents developed for the project, less total residual ch lorine. CWM Environmental, Inc.’s water quality results for these six tests are included in Appendix D

. Mass Balance Calculations In addition, a mass balance analysis was conducted on the water quality samples. Each mass balance sample was measured for the 118 individual constituents. Results are included in Appendix E. The samples yielded mass balance calculations with the following overall results: 1. The right

- hand columns of the 3 tabs in the accompanying spreadsheet illustrate the mass balance calculations for each constituent. Total absolute mass, for both incoming and outgoing amounts of each constituent, were calculated by multiplying the respective concentration measured by CWM times the volume of respective PW, CW, or DW water. The last t wo columns indicate the difference between incoming and outgoing amounts. 2. Of the 118 constituents tested for each raw water sample, there were 57 constituents that tested below the detectable limit. In simple terms, nearly half the constituents tested were from a practical perspective, not in the raw water samples. This was true for the same 57 constituents across all three raw water samples. 3. An analysis of the mass balance results from the constituents labeled “General Parameters” shows good correlation b etween the achieved results and the theoretical calculated mass balance. Again this same comment holds across all three data sets. 4. Low

- boiling point organic constituents (vapor pressures higher than that of water) had higher positive discrepancies (less mass present in the outgoing CW and DW streams than in the incoming PW stream), as expected from previous Altela experience, indicating some volatilization and escape in the air exhaust. 5. In general, the Altela process produced distilled water from incoming frac water, flow

- back water, or gas well produced water. Concentrations of contaminant constituents in Altela DW water have been removed to levels generally better than 99.8% of their incoming raw water concentrations. 3.3 Test - Bench Summary and Conclus ions Three samples of “real world” waste water were obtained from two sites in the Marcellus Shale. These samples w ere from the sources as follows: (1) Frac Water

– a sample of the initial fracturing solution used to fracture a newly drilled natural gas well was pulled at the start of the fracturing process.

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## (2) Flow

- Back Water

– a sample of the solution that flows out of the well after the start of the frac turing process was pulled three days following the start of the fracturing process, this was pulled from the same site that used the initial Frac Water solution. (3) Produced Water (PW)

– a sample of the Produced Water that is brought to the surface of a natur al gas well once the well is “in production” was pulled on the same day the Flow

- Back Water sample was pulled. The PW sample was pulled from a well that was fractured in early October 2009 and been in constant production from early November 2009. CWM Envir onmental, Inc. ’s baseline water quality reports for these three samples are included in Appendix C. Once pulled, the raw water samples were sent to the Altela facility in New Mexico for process treatment testing on the Altela test apparatus. Each raw sam ple was “treated” using the same equipment and test tower over a 3

- day period, each requiring about 1 full da y on the test “tower. ” During the test of each raw water sample, the water was circulated through the Altela tower until a pre

- determined residual volume was obtained. During this process, pure H2O was evaporated from the raw water solution. As a result, the resultant solution is a “concentrated” version of the raw water solution, since the mass of the dissolved constituents should remain fairly c onsistent, assuming no chemistry changes take place during the process. The evaporated water (DW) is recovered through the condensation process occurring in the “tower”, and if successful, the DW should have little or no contaminants in the water. CWM ’s water quality reports for the CW and DW analyses are included in Appendix D. Upon completion of all three test

- bench tests , a sample was pulled from each test from the three net solutions, i.e. a raw water sample, CW sample, and a DW sample was pulled f or each test for applicable mass balance analysis (Appendix E). A thorough review and mass balance analysis of the sample results yielded the following conclusions. In general, the DW water quality was exceptional, regardless of the raw water solution mak e - up or net concentration of dissolved salts in the raw water. This result was as

- e xpected and serves to verify that the Altela Rain ® 

## technology is an excellent process for treating the various solutions involved with natural gas production on the Marcellu s Shale. The mass balance analysis performed on the raw water and concentrate water samples yielded, for the most part, results within expected levels. It should be noted that, as previously verified, there is some water chemistry taking place in the solu tions as the raw water solution is concentrated to higher and higher salt concentration levels. This result s in “changes” to the mass of specific constituents in the solutions. This is expected and the mass balance analysis simply provided verification of known water chemistry issues that have been obtained on the Altela test bench apparatus or from similar testing performed with Altela pilot systems used on other natural gas production sites. The Altela process is a useful process as it requires little t o no pre treatment. It allows for the treatment of deep well water on site. It helps reduce the amount of waste produced and transported off site. In order to keep the process up and running, a small

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## amount of acid may be used to extend the useful run l ife between maintenance. However, there is need for regularly scheduled distillation column maintenance. The scale which may be formed must be periodically removed. The design of the system must include the down time associated with such routine mainten ance. Recipient completed the system specification document and delivered it to DOE on April 12, 2010. As part of the final analysis of this water on the test

- bench scale , the testing produced clean DW and yielded results consistent with previous experience, and as such, field deployment of a test system for further process verification of Marcellus Shale produced and frac flow

- back waters was highly recommended as part of the Continuation Application

. Recipient received approval of a Go

- Decision on May 12, 2010 from the Contracting Officer that provided notification and authorization to proceed to the next phase of the project. 4. SYSTEM OPERATIONS REPORT 4.1 Summary The ARS

- 4000 System Specification document previously provided by Recipient to NETL outlines the technical approach employed by the AltelaRain ® 

## ARS

- 4000 water treatment system. A brief description of the demonstration system follows.
The Altela ARS

- 4000 System is a fully automated water treatment process designed to operate 24 hours a day, 7 days a week. In most cases the system will be installed in a remote area directly at a natural gas or oil well site. The operator should visit th e site daily for system monitoring or routine maintenance actions that should require approximately 1 hour per site visit. To assure continuous operation of the Altela system a reliable remote monitoring capability is installed to provide the remote operat or with a visual means of monitoring key system data. The remote monitoring system has an “auto

- dial” feature that will notify the operator any time an alarm situation occurs. The Altela ARS

- 4000 system is controlled by a Programmable Logic Controller ( PL C )

. The PLC has built

- in data logging capability and is programmed with a control logic that monitors many system outputs continuously during operation. The logic is designed so that any time a failure condition is sensed, the PLC automatically shuts dow n the system through one of two shutdown modes. The normal, or “controlled shutdown” will automatically turn off each piece of equipment in a methodical and controlled sequence. The “emergency shutdown” will turn off all operating equipment immediately. The operator can trigger either shutdown mode as required at the push of a button , either at the unit or computer from any remote location

. The Altela system treats produced water by a thermal distillation process. In simple terms , the Altela system con verts incoming dirty water into two components

– 

## clean distilled water plus a concentrated solution of dirty water (CW) . The Altela system is a waste reduction process, meaning the incoming dirty water volume is reduced by up to 80%. The remaining 20%, a

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## concentrate of the original dirty water, must be disposed of through conventional methods. T he process begins with the produced water that is collected in an on

- site holding tank. This water is transferred via pump into the Altela containerized s ystem
. Once inside the Altela ARS

- 4000 system, the produced water is circulated continuously through ten AltelaRain ® 

## “towers.” The towers are designed to evaporate pure water from the brackish produced water. The evaporated water is then condensed within the same tower , on the opposite side of thin plastic sheet . The condensed water, which is of distilled water quality , is collected and t ransferred from the towers to a “distilled water” (DW) holding tank. The con centrated water ( CW, the second component of water exiting the towers ) is eventually concentrated up to five times higher dissolved solids content and then pumped out of the Altela s ystem for eventual disposal. Likewise, the distilled water is also pumped from the system and available for recycling and related beneficial, productive uses. Milestone 6, “System installe d, tested and in full operation” was started on June 9, 2010 and was com pleted on July 22, 2010

. As of April 8, 2011, over 299,040 gallons of Marcellus Shale frac flow

- back water have been treated and purified at the well

- site, resulting in the production of 200,215 gallons of clean distilled water. The concentrated water generated during this time period equal 75,430 gallons (1,796 barrels), representing approximately 75% volume reduction in the original amount of brackish water. This percentage is known as the Re covery Rate (RR), and is defined as RR = 1

- CW/PW. Following Milestone 6, the System continuously treated water beginning July 26, 2010

. The volume of incoming water that is eliminated from trucking to a disposal site is known as the Treatment Rate (TR). The amount is given simply by TR = PW

- CW. The absolute amount of water eliminated from trucking during this time period was 2 23,610 gallons (5 , 324 barrels). The average daily TR for this reporting period is 27

. 46 Barrels per Day (BPD), normalized for the time the well

- site was operational (providing water to be treated a nd natural gas to the s ystem)

. Additional charts and graphs are included in Appendix H.

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## Several factors contributed to a lower Treatment Rate than initially projected. As outlined in the applicatio n, under optimum conditions, the ARS

- 4000 S ystem can p rocess approximately 100 BPD through the system . The system recovery rate is a function of water quality but a recovery rate of up to approximately eighty (80) barrels per day Treatment Rate was anticipated (80% recovery rate)

. T he actual field Treatment Rate had been adversely affected by different issues caused both by external well

- site problems and internal Altela s ystem mechanical problems. Mechanical issues that affected the Treatment Rate range from tower issues to individual mechanical components (e.g., off

- the

- shelf pump failures) operating inside the system. Other external issues contributing to a lower Treatment Rate included well

- site shut

- downs in either/both natural gas and water to treat . W eather conditions hindered the system performance as well. The figure above illustrates that the well

- site was co mpletely non

- operational on several occasions as outlined below , especially in the beginning of th e Phase I time period. In addition to the numerous well

- site problems, t he first internal issu e affect ing the Treatment Rate wa s that the system was designed to operate on 14 towers, however; we discovered that it is only able to operate on 10 towers at one time

. The first demonstration towers were found to accept more steam than originally thought

. Ironically, each tower yielded greater capacity at its maximum operating conditions than originally thought, but this in turn resulted in the System’s boiler being under

- sized for the full complement of 14 towers. Specifically, max imum steam output from t he 25 HP Ajax boiler wa s 863 lb/hr. Once the boiler is de

- rated to a now recommended operating efficiency of 80%, max imum output of the boiler was found to be only 690 lb/hr. This is equivalent to only 49.3 lb/hr (5.9 GPH) for 14 towers, still only 69 lb /hr (8.3 GPH) for a lessened 10

- tower operation. As originally designed, t he steam input needed to operate the 14 towers in the system wa s thought to be 583 lb/hr (41.6 lb/hr; 5.0 GPH ) , while the steam input for 10 tower operation s was 416 lb/hr (41.6 lb/hr; 5.0 GPH ) . Even though the boiler is sized to supply a steam output of 690 lb/hr, this is 15% higher than the amount of steam that is needed to operate the 14 towers. Therefore the Ajax boiler is operating at the high end of its operation li mits leading to

“ carryover ” from the boiler into the towers , lowering the performance of the towers significantly. The decision to operate on 10 towers was made . At a steam input requirement of 416 lb/hr, the boiler is able to supply the proper amount of steam to the towers. The towers operate d best when they were supplied with a constant supply of steam. We now know that this is not achieved using the Ajax boiler because as it is on/off style of boiler instead of the more preferable modulated flame boilers. The pressure differential is approximately 4 to 5 psi between the boiler flame coming on and shutting down with the Ajax boiler . This hinders the performance of the tower because of the change in steam temperature as the pressur e changes , leading to the tower temperatures changing a few degrees when the boiler is c ycling. These boiler issues le d to the Treatment Rate being lower on the s ystem than what we now know is possible using higher

- quality modulated boilers in the future

.

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### Page 25 of 35 

## The lower Treatment Rate may also be associated with scaling occurring on the tower gauze. The gauze located in the evaporation section of the tower helps to wick the PW across the evaporation area. Scaling on the gauze hinder s this wicking affect as we ll as limit s thermal heat transfer vital for the towers to o perate effectively. Previously, an injection of Muriatic Acid was added to the incoming PW to the towers to keep a pH of 4.5 which help s control the amount of sulfates that accumulate on the inte rnal gauze of the towers. An acid wash was completed on the system in an attempt to remove or reduce the amount of scale on the gauze. Investigations continue to better understand this field operational issue

. Future towers will likely be manufactured w ith a different wicking material. Additional factors that affected the Treatment rate included the down time required to fix or replace mechanical components. Several shut

- downs were related to gas interr uptions at the well

- head. These issues were addressed quickly and the system was turned back on and resumed treatm ent. In addition, Recipient had experienced a shut

- down during one quarter due to a system integration issue associated with the RS Logix program. A minor shut

- down was associated to a mechanical issue with a float in the boiler blow

- down tank. Periodic maintenance caused several brief, scheduled shut

- downs of the system. Other system shutdowns included mechanical component failures such as the Main CW Transfer pump, a DW Out Conductivity sensor reading improperly, and float failures on the transfer. These one - time ‘learning curve’ failures are expected due to the 24/7 operation as well as the harsh environment and materials that were treated by the system. Other issues af fecting the Treatment Rate were external to the system. One major reason for shutdowns were associated with the natural gas well. Initially , the gas well was only hooked up to the system and not to the collection pipeline, leading to failed controllers o n the gas well unit and eliminat ing the gas pressure required to operate the Ajax boiler. After a few months of operation , the gas well uni t was hooked up to the pipeline. C ontinued periodic shutdowns to the system were due to a lack of pressure from the gas well itself

. On occasion , w ater from the gas well entered the gas well line and caused a shut down . As temperatures dropped heading into winter, the presence of water in the natural gas well unit itself caused some problems as well

. Lower Treatment Rates were also related to suspended solids. As there was no pre

- treatment of PW prior to entering the system, there was concern about collection of sulfates , iron oxide as well as Total Suspended S olids (TSS) collecting on the gauze. T owards the beginning of field operations , maple seeds and other debris from the PW pond flowed into the system. This le d to shutdowns by the tower flo ws dropping below 2.0 GPM caused by flow meter obstruct ion of suspended solids . To address th e problem, a 100 micron mesh bag filter was p laced in the PW line before entering the system. Most but not all suspended so lids listed above were filtered

. T he filter was removed and cleaned every three days of accumulation of solids retained

. These types of issues are common in any new product development. The system operated in a continuous mode. During automatic shut

- downs that occurr ed , the PLC/SCADA components continued to report and track such events.

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## Consistent with Mileston e 7, the first quarterly water sampling was taken on September 13, 2010. These water samples were taken and analyzed by a certified water quality laboratory to verify that the system was operating successfully and capable of treating the highly challenged Marcellus Shale frac flow

- back and produced water. These water quality analyses demonstrate d the system’s ability to successfully treat highly challenged water and , at the same time, pr oduce d extremely clean water output. Copies of the complete water quality analyses have been attached to this quarterly report as Appendix C

. Tho ugh the demonstration system had not achieved the projected daily treatment rate, it is noteworthy that th e system is the first demonstration system that has successfully been operating in the field at a well

- site over such a period of time in the Marcellus. As verified by the field water quality analyses to date, the system is capable of treating highly chal lenged Marcellus Shale frac flow

- back and produced waters to a level of clean water purity necessary to be able to discharge the water directly into the Commonwealth’s surface water supply (i.e. stream discharge). The technology performed as anticipated w ith respect to purifying the water. Dec reases in treatment volumes had been engineering/well

- head system integration in nature rather than core science problems associated with the technology. 4.2 Gas and Electrical Usage Gas Usage The Altela process is unique among all water desalination techniques, in that it is driven by low

cost heat, rather than high

- cost electricity. In this demonstration setting, the System is powered nearly entirely by natural gas (to generate steam by boiling a fracti on of the cleaned water). The average gas usage was found to be 0. 485 MCF/bbl of water eliminated for the period. The average price of natural gas during that period was $3.59/MCF. This equates to $1.7 4/bbl of water eliminated. Although low by comparab le desalination techniques, this OpEx expense is likely to decrease further in future units with more efficient boilers. Electrical Usage Electrical usage, per gallon of water treated, is estimated below, since no electrical meter exists solely on our Syst em. Average wattage for ARS

- 4000 System is approximately 3.1 kW. Total runtime as of April 8 th 

## , 2011 was 4,358 hours. Electricity usage during that period is estimated to be 13,510 kWH

. Average cost of electricity in PA during that time period was approximately $0.136 kWH. Total cost of electricity for operating the system is estimated to $1,837

. This equates to a per gallon electricity OpEx of $0.008 2 /gallon ($0.345 /bbl). 4.3 Con centrate Disposal The Concentrate Water (CW) stream is the residual liquid solution remaining after approximately 80% of the pure distilled water has been removed via the AltelaRain ® 

## treatment

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## proc ess. The residual CW solution contains ne arly 100% of the salt s and other constituents contained in the original volume of Produced Water (PW) processed through the demonstration system. The residual CW is removed from the site and transferred to approved commercial produced water disposal facilities. Specifically, the CW is transported to Hart Resource Technologies, 5035 Route 100, Creekside, PA, 15732. Hart Resources has two facilities

– Josephine Brine and Franklin Brine. Depending on capacity, both facilities have been used for the disposal of the CW from the demonstration project. Prior to April 19 th 

## , Har t Resources Technologies charged $0.06 per gallon for disposal (2.52/bbl) . In addition, the trucking cost to ei ther site wa s approximately $0.0 8 to $0. 10 per gallon for a total CW disposal cost equal to $0.1 4 to $0.16 per gallon (equivalent to $5. 88 to $ 6.72 per barrel). Assuming a total average Trucking and Disposal cost of $0.15/gallon ($6.30/barrel), results in an absolute cost of $1 1 ,3 15 to dispose of the 75,43 0 gallons ( 1796 barrels) of CW during the period. The chart below outlines the volume of CW production from commencement of the system operations.

4.4 Estimated Costs Estimated Per Barrel Labor A total of approximately 495 hours of labor was required during the project

. Dividing the 2 23,6 10 gallons ( 5,324 barrels) of water eliminated (TR) by this results in an approximate per barrel labor rate of 0.0022 1 hours/gallon (0.0 9297 hours/bbl). An hourly maintenance wor ker at $30/hr results in total labor costs of approximately $14,8 50 and per gallo n and per barrel costs of $0.066 /gal and $2. 789 /bbl respectively. It should be noted that this amount is likely inordinately Cost

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## high because both (i) this initial demonstration testing was a first of its kind, and experience learning will reduce further in such installations and (ii) the very nature of this NETL project requires special labor costs not found in future real

- world on

- site water treatment. Estimated Per Barrel Consu mables Cost Consumable costs during the period were quite low. Final cost of consumable (filter bags) totaled $53.24

. The estimate of consumables per barrel costs equal $0.01/bbl. Estimated Total Per Barrel Cost The total per barrel operating cost (OpEx) during the period was $4. 88 /barrel ($0.1 2 /gal). This was calculated by summing the individual OpEx costs listed below:

**•** Gas Cost: $1.7 4/barrel of water eliminated
**•** Electric Cost: $0.345 /barrel of water eliminated
**•** Labor Cost: $2. 789 /barrel of water eliminated
**•** Consumables Cost: $0.01/barrel of water eliminated This total per barrel operating cost (OpEx) of $4. 88 /barrel ($0.1 2 /gal) reflects the per barrel cost of the water eliminated from trucking and disposal (TR=PW

- CW). It does not include the cost of disposal of the concentrate, but it also did not divide these costs by the larger number of “how much input water was treated ”. The cost calculations can (and should) be done two different ways: (a) as above, based only on the net volume of water eliminated from trucking and disposal, TR = PW

- CW; and (b) based on the volume of water treated, PW. The latter method yields a to tal per barrel operating cost (OpEx) of $4. 88/barrel ($0.12 /gal) and reflects the per barrel cost of the water brought into the System (PW). It therefore includes the cost of disposal of the Concentrate Water (CW). Total water treated (PW) equaled 7,120 barrels, and OpEx costs were:

**•** Total Gas Cost: $9, 264 ($1.7 4/barrel TR X 5,324 barrels)
**•** Total Electric Cost: $1, 837 ($0.345 /barrel TR X 5,324 barrels)
**•** Total Labor Cost: $ 14,850 ($2.789/barrel TR X 5,324 barrels)
**•** Total Consumables Cos t: $53 ($0.01/barrel TR X 5,324 barrels)
**•** Total Disposal Cost: $ 11,315 ($6.30/barrel TR X 1,796 barrels) Total OpEx costs, including CW disposal, were therefore $37 , 319

. The resulting per gallon and per barrel costs were $0.125/gallon and $5.24 /barrel, respectively. This rep resents a savings of 17 % over trucking and disposal wi thout the Altela System (1

- $5.24 /$6.30). Factors causing th e reduction of savings over the 28% reported during Phase 1 are noted in the Executive Summary. It is noteworthy that recent regulatory chan ges this past year have increased traditional trucking and disposal costs which are material to the above analysis. A significant volume of Marcellus

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## Shale wastewater is being disposed of in Ohio in UIC re

- injection wells. Ohio has passed regulations inc reasing the price for such disposal. For example, according to the Ohio Division of Mineral Resources Management (ODNR), “With the passage of Senate Bill 165 in 2010, some changes to the UIC Program include an increase in the Class II saltwater injection permit application fee from $100 to $1000, and an injection disposal fee of $.05 per barrel for brine originating in

- district and $.20 per barrel for brine originating out

- of

- district.” These UIC disposal surcharges for out

- of

- district brine disposal are increasing total disposal costs to the E&P operators. In addition, b eginning in January of 2011, PA DEP amended Title 25, Chapter 95, Wastewater Treatment Requirements, to address the dramatic increase in Marcellus Shale wastewater that was being diluted and sent into PA’s surface water bodies. The new 95 regulation included more stringent discharge standards including 500 mg/L for Total Dissolved Solids (TDS) and 250 mg/L each for Sulfates and Chlorides. As a result of PA DEP’s Chapter 95 regulation an d ensuing enforcement efforts by PA DEP in May of 2011, the per barrel market price for disposal of Marcellus Shale wastewater has increased significantly due to increased costs to comply with the new discharge regulations. Operators have reported per bar rel costs exceeding $8.50 per barrel with further increases based on proximity to Ohio or to limited disposal sites still available in Pennsylvania. This in turn, has made new technologies like the AltelaRain ® 

## process to be more economical and thereby gain additional market traction. Taking into account this new regulatory market dynamic, industry can currently realize a s avings of 3 8% over trucking and disposal without the Altela System (1

- $ 5.24 /$8.50).
5. LIFE CYCLE ANALYSIS REPORT 5 .1 Approach A hybrid life cycle assessment (LCA) approach was used to estimate the environmental performance of the system. Hybrid life cycle assessment combines a traditional process based life cycle assessment approach with an economic input

- output life cycle asses sment (EIO

- LCA) approach to expand the system boundaries and include impacts for process where detailed information is unavailable (Williams 2004). Using this approach energy consumption and greenhouse gas (GHG) emissions were calculated on a life cycle b asis. The Analysis will compare the Altela 4000 mobile test system with the improved Altela 600 stationary system as well as trucking produced water to Ohio for deep well injection. In addition a fourth scenario was analyzed assuming the Altela 600 coul d be paired with a waste heat source. Four main stages of the life cycle were analyzed: operations, capital equipment manufacturing, transportation, and waste disposal. Of the four stages, three, operations, transportation, and waste disposal were analyz ed using the process LCA approach. Capital equipment manufacturing was be analyzed using the EIO

- LCA methodology.

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## The functional unit for the analysis is a single barrel of produced water entering the system. Energy consumption is calculated as total p rimary energy consumption in BTUs and GHG emissions are calculated in g CO2e. For the Altela systems a treatment rate of 75% is assumed for all systems based upon the field results for the Altela 4000. This means for each barrel entering the system 0.75 bbl are fully treated by the system and 0.25 bbl must be disposed of by conventional methods. In this analysis trucking to Ohio for deep well injection was the assumed disposal method. The Argonne National Laboratory Greenhouse Gases, Regulatory Emissio ns, and Energy Use in Transportation (GREET) model was used to develop life cycle energy and emissions factors. These emissions factors incorporate upstream impacts such as fuel production and processing. The emissions factors used for the energy sources included in this analysis are shown below: Impact Factors (From GREET v1.8d.1) Energy Source Primary Energy (btu/btu) GHG g/mmbtu Natural Gas 1.07 69,815 Diesel 1.13 83700 Electricity 2.51 211,754

5.2 Operations Operations impacts were calculated based upon measured energy consumption values. The sources of energy consumption included in the analysis were natural gas to feed the boiler which drives the treatment process and electricity to run additional equipment such as pumps, blowers, sensors, and control electronics. For the Altela 4000 system operational performance data used was from a 58 day period in September and October of 2010. Energy consumptions values for both systems are shown below . For the Alte la 600 scenario where waste heat is utilized, natural gas consumption is assumed to be zero. Operational Energy Consumption per barrel of water treated System Natural Gas (MCF/bbl) Electricity (kWh/bbl) Altela 4000 0.45 2.03 Altela 600 0.20 2.48

5.3 Capital Equipment Manufacturing Impacts for capital equipment manufacturing were calculated based upon the EIO

- LCA methodology. A detailed cost breakdown of the system was combined with economic sector specific impact factors obtained by the EIOLCA.ne t life cycle assessment model (CMUGDI

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## 2011). Impact factors in the EIOLCA.net model were in 2002 dollars so they had to be adjusted to 2010 dollars using the latest producer price index values (Economagic 2011). A lifetime of 10 years was assumed for all equipment. A utilization rate of 60% was assumed for the Altela 600 system and the average treatment rate of 37 bbl/day was used for the Altela 4000. 5.4 Transportation Transportation impacts are included for the Altela 600 system. Since the system i s at a centralized location, water will need to be trucked from surrounding wells to this location. The average distance from well pads to the treatment facility was assumed to be 30 miles. Fuel consumption was calculated for a round trip, with trucks we re assumed to get 5 mpg while fully loaded and 7 mpg on the return trip. 5.5 Waste Disposal Waste disposal is assumed to be trucking to deep well injection sites in Ohio. This disposal method was selected due to recent regulatory actions in Pennsylvania restricting the use of conventional treatment and disposal facilities that do not remove TDS. In addition, in order for the Altela systems to effectively reduce salt loads to surface waters, the highly concentrated waste brines should be disposed of through deep well injection. The transportation distance for disposal was estimated based upon t he average distance between the location of the Altela 4000 test site and the five nearest disposal wells in Ohio (Veil 2010). This distance was calculated to be approximately 150 miles. Fuel consumption was calculated assuming the same fuel efficiency u sed for determining the transportation impacts. Energy required for deep well injection was previous calculated by Argonne for a yet to be published study based upon the average injection pressure of a number of injection wells in the western United Stat es. From this analysis the energy requirements for injection were estimated to be 0.6 kWh/bbl. 5.6 Results The results of this analysis are shown in the figures below

. Figure A shows the life cycle energy consumption for the four scenarios. For the Altela 4000 and 600 systems the energy consumption is dominated by the operations stage, specifically from natural gas consumed to generate steam. The waste heat scenario illustrate s that there is a significant opportunity to reduce energy demand (and costs) by pairing the Altela 600 with a low

- grade waste heat source. The energy consumption for manufacturing the system itself is quite small, at least when averaged over the entire e xpected lifetime of the system. Energy for transportation is not insignificant, but small relative to the operational energy consumption and the significantly higher efficiency of the centralized Altela 600 systems appears to outweigh the lack of transpor tation required for the Altela 4000. However it is possible that this efficiency difference could be narrowed with an improved, optimized version of the mobile system.

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### Page 32 of 35 Figure A . Life Cycle Energy Consumption for Water Treatment 

## Figure B shows the life cycle GHG emissions for each scenario. The GHG emissions data largely track the energy consumption trends. This is not surprising given that the majority of GHG emissions result directly from combustion of fossil fuels.

Figure B. Life Cycle GHG Emissions for Water Treatment 

## 5.7 Analysis While both the Altela 4000 and 600 systems are still currently more energy and GHG intensive than simply trucking water for disposal there are additional benefits beyond energy and emissions. B oth systems would significantly reduce truck traffic required for water management. Increased truck traffic is one of the largest complaints of citizens in areas of active 0 50,000 100,000 150,000 200,000 250,000 300,000 350,000 400,000 450,000

4000 600 600 waste heat injectionLife cycle energy BTU/bbl 

# Life Cycle Energy Consumption

Waste Disposal Tranportation Capital Operations

0 5,000 10,000 15,000 20,000 25,000 30,000

4000 600 600 waste heat injectionLife cycle GHG emissions g CO2e/bbl 

# Life Cycle GHG Emissions

Waste Disposal Tranportation Capital Operations

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## gas development. The availability of disposal wells is also likely to decline in t he future as demand increases, potentially increasing costs and the distance to available wells. The Altela systems also produce as much 0.66 bbl of purified water for every barrel of produced water treated. This water can be returned to operators reduc ing stress on fresh water resource. The exact amount of purified water produced varies somewhat depending on operating conditions since the clean water is utilized for steam production which drives the system and some of this water is exhausted from the s ystem as saturated water vapor. The life cycle assessment results show that experience gained from the Altela 4000 field tests have helped improve the system design and resulted in a 45% increase in overall energy efficiency for the newer Altela 600 syst em. In the future, if suitable sources of low grade waste heat can be located and systems co

- located to take advantage of them (co

- generation projects) , the system efficiency can improve as much as 85% from the original test system. CONCLUSION This proj ect successfully delivered field

- proof that the AltelaRain ® 

## technology is capable of treating Marcellus frac water to water quality standards required for discharge and/or applicable beneficial re

- use, numerous water quality analyses of the treated water were taken. Both bench

scale water quality analyses and the first field

- b ased quarterly water sampling verified the system wa s operating successfully and capable of treating the highly challenged Marcellus Shale frac flow

- back and produced water to requisite levels. The project delivered field proof that the treatment technol ogy can economically treat the frac water at a cost equal to or lower than current disposal methods . Specifically, t he resulting per gallon and per barrel costs were $0.125/gallon and $5.24/barrel, respectively. This represents a savings of 17 % over truc king and disposal without t he Altela System. This cost savings increases to 38% when trucking and disposal market pricing, post May 19 th 

## 2011, is taken into account following Chapter 95 discharge limit enforcement. As a result of PA DEP’s Chapter 95 regulation and ensuing enforcement efforts by PA DEP in May of 2011, the per barrel market price for disposal of Marcellus Shale wastewater has increased significantly due to increased costs to comply with the new dischar ge regulations. Operators have reported per barrel costs exceeding $8.50 per barrel with further increases based on proximity to Ohio or to limited disposal sites still available in Pennsylvania. UIC disposal surcharges for out

- of

- district brine disposa l are increasing total disposal costs to the E&P operators. For example , according to the Ohio Division of Mineral Resources Management (ODNR), “With the passage of Senate Bill 165 in 2010, some changes to the UIC Program include an increase in the Class II saltwater injection permit application fee from $100 to $1000, and an injection disposal fee of $.05 per barrel for brine originating in

- district and $.20 per barrel for brine originating out

- of

- district.” In addition, January of 2011, PA DEP amended T itle 25,

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### Page 34 of 35 

## Chapter 95, Wastewater Treatment Requirements, to address the dramatic increase in Marcellus Shale wastewater that was being diluted and sent into PA’s surface water bodies. The new 95 regulation included more stringent discharge standards includ ing 500 mg/L for Total Dissolved Solids (TDS) and 250 mg/L each for Sulfates and Chlorides. A s outlined in this report, t he life cycle assessment results indicate that experience gained from the Altela 4000 field tests have helped improve the system desi gn and resulted in a 45% increase in overall energy efficiency for the newer Altela 600 system. In the future, if suitable sources of low grade waste heat can be located and systems co

- located to take advantage of them (co

generation projects) , the system efficiency can improve as much as 85% from the original test system. Altela is in discussion with several entities to pursue this co

- generation approach. Finally, with respect to demonstrating that the regulatory environment support impleme ntation of the water treatment technology solution, this report provides a review of the regulatory r equirements as well as confirmation that the regulatory environment supports implementation of the AltelaRain ® 

## water treatment technology solution in Penns ylvania’s Marcellus Shale Basin. References Carnegie Mellon University Green Design Institute, 2011, Economic Input

- Output Life Cycle Assessment (EIO

LCA), US 2002 purchaser model [Internet], Available from:<http://www.eiolca.net> Accessed July 18, 2011. Economagic, 2011, “Browse US Producer Price Index Data.” http://www.economagic.com/blsppi.htm (accessed 7

- 18

- 11). Veil, J.A., 2010, “Water Management Technologies Used by Marcellus Shale Gas Producers,” ANL/EVS/R

- 10/3, prepared for the U.S. Department of Energy, National Energy Technology Laboratory, July, 59 pp. Available at http://www.ead.anl.gov/pub/dsp_detail.cfm?PubID=2537

. Williams, E., 2004, “Energy Intensity of Computer Manufacturing: Hybrid Assessment Combining Process and Economic Input

- Output Methods.” Environmental Science & Technology 38: 6166

- 74.

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## LIST OF ACRONYMS AND ABBREVIATIONS

CW Concentrated Water CWA Clean Water Act DW Distilled Water EPA Environmental Protection Agency GPH Gallons per hour NDPES National Pollution Discharge Elimination System NETL National Energy Technology Laboratory NM OCD New Mexico Oil Conservation Division OpEx Operating Expenses PA DEP Pennsylvania Department Environmental Protection PW Produced Water SOPO Statement of Project Objectives TR Treatment Rate UIC Underground Injection Control USDW Underground Source of Drinking Water

# APPENDIX A

PA DEP REQUEST FOR APPROVAL OF ALTERNATIVE WASTE MANAGEMENT PRACTICES

# APPENDIX B

CWM ENVIRONMENTAL, INC. SAMPLING PROCEDURES

## Sample Mana g ement Sampling Procedure Document No.: SM-001P_03 Effective Date: 01/01/09 Page No.: 

## 1 of 

## 7

Controlled Copy on Gray Paper, Do Not Duplicate 

# Sampling Procedure Approvals/Date: Ryan Shafer, Technical Director Anagha Lele, Quality Assurance Officer C ONTROLLED 

## D ISTRIBUTION 

## Copy No.: MASTER COPY Issued To: QAO Desk (accessible to all lab personnel) 1.0 PURPOSE 1.1 This procedure describes the general requirements for sampling and field measurements when obtaining a specimen sample for subsequent analytical testing. 1.2 The objective of sampling is to collect a portion of material small enough in volume to be transported conveniently and handled in the laboratory while still accurately representing the material being sampled. 1.3 Samples may be biological, wastewater, potable water, groundwater, surface water, or domestic or industrial wastes. 1.4 Deviations, additions, or exclusions from this procedure must be documented. 2.0 SCOPE This procedure is applicable to all sampling events planned and conducted by CWM. Clients are encouraged to adhere to this procedure. 3.0 RESPONSIBILITIES 3.1 Safety is the responsibility of all involved in the planning, collection and handling of the samples. Because sample constituents can be toxic, take adequate precautions during sampling and sample handling. Precautions may be limited to wearing gloves or may include coveralls, aprons, or other protective apparel. Always wear eye protection. Label adequately any sample known or suspected to be hazardous because of flammability, corrosivity, toxicity, or radioactivity, so that appropriate precautions can be taken during sample handling, storage, and disposal. 3.2 The sampler is responsible for maintenance of a field logbook, with entries printed neatly and legibly in ink. Logbooks may be used as evidentiary records in a court of law at some future date. 3.3 The sampler is responsible for documenting any deviations, additions, or exclusions applied to a sample set in the field record log, and ensuring that this information is forwarded to the laboratory along with routine sample identification information. This shall be applicable regardless of the whether changes were initiated due to client request or due to conditions in the field. Additionally, these changes must be brought to the attention of the project manager as soon as is practicable.

## Sample Mana g ement Sampling Procedure Document No.: SM-001P_03 Effective Date: 01/01/09 Page No.: 

## 2 of 

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Controlled Copy on Gray Paper, Do Not Duplicate 3.4 The project manager is responsible for transmitting any client-requested deviations, additions, or exclusions to this procedure to the sampler, and ensuring that these changes are reported with the resultant data. 3.5 The project manager must notify the client of any deviations, additions, or exclusions to this procedure that were not requested by the client, and ensure that these changes are reported with the resultant data. 3.6 The laboratory manager is responsible for ensuring that samplers have been properly trained in the techniques appropriate to the requested sampling event. This training must be documented. 4.0 RELATED DOCUMENTS 4.1 Standard Methods for the Examination of Water and Wastewater , 19th Edition, APHA/AWWA/WEF, 1995. Method 1060 F 4.2 Field Procedures Manual for Water Data Acquisition , NJDEP Division of Water Resources, 1987. 4.3 National Environmental Laboratory Accreditation Conference Standards, Chapter 7, Field Activities, Proposed Changes, May 2002 4.4 CWM cross-referenced documents: Document Number Title (may be abbreviated) MS Notebook Material Safety Data Sheets (MSDS) Notebook QS-001M Laboratory Quality Manual SM-001T Sample Containers, Preservation, Holding Time SM-101P Sample Acceptance Policy SM-102P Sample Receipt & Tracking SM-002P Sampling Procedure - Micro SM-003P Sampling Procedure - Oil & Gas Plat Collection SM-004P Sampling Procedure - Atlas Oil & Gas Plat Collection
5.0 PROCEDURE 5.1 Planning 5.1.1 Parameters Determine what pollutants and/or physical environmental conditions are to be monitored. Make a list of analytical requests based on applicable client permits, regulatory requirements, review of provide d data, and/or specific client input. 5.1.2 Sample Scheduling Develop a projected sampling schedule, taking into consideration factors such as laboratory workload, periodic monitoring requirements (e.g., is the project for

## Sample Mana g ement Sampling Procedure Document No.: SM-001P_03 Effective Date: 01/01/09 Page No.: 

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Controlled Copy on Gray Paper, Do Not Duplicate quarterly compliance monitoring?), hold times, analysis time (will you need to pay overtime to have someone read results on the weekend or a holiday?), and client expectations. 5.1.3 Sample Containers 5.1.3.1 Refer to work instruction SM-001T, Sample Containers, Preservation, and Hold Time to determine the type, size and quantity of sample containers for all analyses identified in Section 5.1.1. The volumes identified in SM-001T are the minimum quantities required. It does not provide enough sample volume for reanalysis or for laboratory duplicates and matrix spikes. For one in every 10 or 20 samples, collect enough volume to perform the analysis three times (one for the sample, one for the duplicate, and one for the matrix spike). When determining what containers are needed, also take into consideration what parameters can be grouped together from the same bottle to minimize the number of sample containers needed. 5.1.3.2 Obtain the needed bottles and label them with the appropriate parameters to be tested from the respective bottles. If the analysis requires chemical preservation, add the preservative to the bottle prior to leaving the laboratory and clearly mark the bottle with the preservative added. Note 1 : Be sure to use pre-cleaned bottles if requested by the client. Ensure that a copy of the certificate is forwarded to th e project file for the sampling event. Record the lot numbers of any preservatives added to the bottles. Note 2 : For litigation samples, or if requested by the client, initiate the chain-ofcustody at the time bottles are prepared, and ensure that the sampler signs the receipt from the laboratory. Note 3 : For volatiles and if required for other analytes by the client, include a trip blank with the bottle order. If field blanks are to be collected, provide laboratory reagent water to prepare the blanks. Note 4 : If soluble components are requested, and the samples are to be field filtered, provide extra bottles to collect total and soluble samples. If the sample is to be filtered for soluble components, DO NOT preserve until AFTER filtering. 5.1.4 Sampling Equipment Determine what type of sampling equipment will be needed. Ensure that it will be available when needed and is clean, in working condition, and ready for use. This includes verifying and documenting that calibrations are current and/or the materials needed to calibrate in the field are available and traceable, as appropriate. Cleaning of sampling equipment is addressed in the respective equipment procedures.

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Controlled Copy on Gray Paper, Do Not Duplicate 5.1.5 Field Measurements If any field measurements are planned, ensure that the necessary instruments are available and that required quality control has been performed. Ensure that appropriate materials needed to calibrate in the field are available and traceable, as appropriate. 5.1.6 Field Log Field records shall be recorded on a sample chain-of-custody form. Records shall include the following, as appropriate, for the interpretation of test results. 5.1.6.1 Sampling/field measurement organization, including address, phone number, and email address 5.1.6.2 Printed name and signature of technician, plus names of all members of the sampling team 5.1.6.3 Sample type (grab, composite, etc.), including an identification of the matrix sampled; (aqueous, solids, etc.) 5.1.6.4 Sample identification number including a unique field identification code for each sample container 5.1.6.5 Reason for sampling/measurement 5.1.6.6 Date and time of sampling/measurement 5.1.6.7 Location of sampling, including any diagrams, sketches, or photographs; name of sampling station, and/or latitude, longitude, and altitude when sample point is not otherwise identified 5.1.6.8 For water sampling: the water level measure, sample depth, and water discharge rate, if appropriate or required 5.1.6.9 Reference to the sampling plan and procedures used, including field blanks, spikes and duplicates; field instrument calibration, span, drift, and calibration standards; sampling system bias and response time; and field test standards and reagents as required by the standard/test method 5.1.6.10 Sample preservation, transportation, and storage, including a description of sample containers and chain of custody 5.1.6.11 Details of any conditions during sampling that may affect the outcome or interpretation of the test results

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Controlled Copy on Gray Paper, Do Not Duplicate 5.1.6.12 Any standard or other specification for the sampling method or procedure, plus any deviations, additions to or exclusions from the specification concerned 5.1.6.13 Certification from the organization collecting the samples that samples and field measurements were collected in accordance with NELAC standards or provide reasons and/or justification if they were not. 5.2 Sample Collection 5.2.1 Samples will generally be a grab or composite.
 

## Grab: a sample collected at a particular time and place.
 

## Composite: a combination of grab samples collected at the same point over different times. The procedure for compositing must be documented for each sampling event. 5.2.2 Obtain a sample that meets the requirements of the sampling program and handle it so that it does not deteriorate or become contaminated before it reaches the laboratory. In water sampling, before filling the sample bottle, rinse it two or three times with the water being collected, unless the bottle contains a preservative or dechlorinating agent. If the bottle already contains preservative, take care not to overfill the bottle to prevent loss or dilution of the preservative. 5.2.3 Representative samples of some sources can be obtained only by making composites of samples collected over a period of time or at many different sampling points. 5.2.4 Collect the sample carefully to ensure that analytical results represent the actual sample composition. Important factors affecting results are the presence of suspended matter or turbidity, the method chosen for its removal, and the physical and chemical changes brought about by storage or aeration. 5.3 Sample Handling, Preservation and Labeling 5.3.1 General Sample Handling 5.3.1.1 Obtain a sample that meets the requirements of the sampling program and handle it so that it does not deteriorate or become contaminated before it reaches the laboratory. In water sampling, before filling the sample bottle, rinse it two or three times with the water being collected, unless the bottle contains a preservative or dechlorinating agent. If the bottle already contains preservative, take care not to overfill the bottle to prevent dilution or loss of the preservative. 5.3.1.2 Representative samples of some sources can be obtained only by making composites of samples collected over a period of time or at many different sampling points.

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Controlled Copy on Gray Paper, Do Not Duplicate 5.3.1.3 Sample carefully to insure that analytical results represent the actual sample composition. Important factors affecting results are the presence of suspended matter or turbidity, the method chosen for its removal, and the physical and chemical changes brought about by storage or aeration. 5.3.2 Special Sample Handling 5.3.2.1 Bacteriological Samples. Sterile bottles containing sodium thiosulfate must be used. 5.3.2.1.1 Choose a tap that is frequently used for drinking. Remove the screen or aerator and allow the cold water to run for 2-3 minutes. Remove the lid and fill the bottle without rinsing. Do not overfill. Do not touch the inside of the bottle or lid. Secure the lid tightly and refrigerate. Relevant COC information must be completed. 5.3.2.2 Dissolved Oxygen Samples 3.3.2.2.1 If dissolved oxygen is not done in the field, a glass BOD bottle must be used. Fill the bottle to the top and stopper and cap the bottle immediately. Preferably, the bottle should be completely immersed in the water being tested; after the bottle fills, cap and stopper the bottle while continuing to immerse it. 5.3.2.3 Volatile Organic Samples 5.3.2.3.1 VOCs must be collected in glass 40-ml vials with no headspace. Do not rinse the bottles. Refer to SM-001T for preservation and hold time requirements. 5.3.2.4 Composite Samples. The following cannot be analyzed from a composite sampler: Dissolved Oxygen Volatile Organics Bacteriological Temperature Oil & Grease Phenols Petroleum Hydrocarbons 5.3.3 Sample Preservation Refer to work instructions SM-001T, Sample Containers, Preservation, and Hold Time. Samples must be shipped and stored with proper preservation. Holding time commences with the collection of the sample. If hold time is less than 48 hours, time of analysis must be recorded and verified to meet requirements with collection of the sample. When fixing a sample (with an acid or base) to a specific pH, use the following steps to check the sample pH:

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Controlled Copy on Gray Paper, Do Not Duplicate 5.3.3.1 Use the appropriate prepared acid or base solution from the lab to preserve the sample. Make sure the acid preservatives dispenser is labeled correctly to directly tie it to its preparation. 5.3.3.2 For acid preservation, a pH of less than 2 is required. For basic (alkaline) preservation, a pH of greater than 10 is required. Use appropriate pH strips to test a small portion of the preserved sample to verify that the required pH has been achieved. 5.3.4 Acid Preservatives Preparation: 5.3.4.1 Laboratory uses (1:1) HN03, (1:1) HCl & (1:1) H2S04 acid preservatives for pH preservation. 5.3.4.2 A separate acid preservatives preparation log is maintained to record the preparation details. 5.3.4.3 Acid dispensers are clearly labeled with date of preparation, details of stock solution and recent calibration check. 6.0 RECORDKEEPING Records generated as a result of the sampling and/or field testing process are included with the chain of custody. 7.0 QUALITY CONTROL Records kept for sampling include the chain of custody, field data sheets and LIMS generated data sheets (where applicable – Ground Water Field data is entered in LIMS directly from COCs) that are used for reportable field measurements. COCs are reviewed to ensure all information is present. 8.0 REVISION SUMMARY No. Summary of Changes 00 Initial release 01 Revised to include the reference to Microbiological Sampling SOP, Section 4.4 02 Revised header effective 01/01/05, Section 7.0 to include LIMS data sheets. 03 Replaces SM -001P_02 eff 01/01/05. Annual Review 2009. Updated to correct the deficiencies identified during Reliant Audit (NOV 08). Added section 5.3.4.

# APPENDIX C

WATER QUALITY REPORTS (PRODUCED WATER, FRAC WATER AND FRAC FLOW - BACK WATER)

# WATER QUALITY REPORT #02100194 P RODUCED W ATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

pH SM4500 H+B 2/5/10 13:10 AML 6.17 SU SU Total Dissolved Solids SM 2540 C 2/5/10 14:49 RCS 195,130 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/5/10 11:44 RCS 403 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/5/10 10:20 NJD 0.9 mg/l 5 mg/l COD HACH 8000 2/11/10 10:11 NJD 6270 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/6/10 2:15 22-293 0.344 mg/L 0.025 mg/L Heterotrophic Plate Count SM 9215B 2/4/10 16:55 WEH 21 /ml 1 /ml Color 2/4/10 13:36 WEH 150 pccu 5 pccu Temperature (F), Field na 2/4/10 9:27 RCS 40 deg F deg F Total Residual Chlorine HACH 8167 2/4/10 9:26 RCS <0.10 mg/L 0.10 mg/L Acidity SM 2310 B 2/5/10 0:00 AML 404 mg/L 3 mg/L Alkalinity SM 2320 B 2/5/10 13:11 AML 94.0 mg/l 5 mg/l Hardness, Total EPA 200.7 2/5/10 10:15 AML 44,431 mg/l 10 mg/l

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Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Bicarbonate SM4500 CO2 D 2/12/10 11:55 AML 94.0 mg/L 5 mg/L Sulfate EPA 300.0 2/5/10 13:39 AML 130.0 mg/l 1 mg/l Chloride EPA 300.0 2/5/10 13:35 AML 108600 mg/L 1 mg/L Fluoride EPA 300.0 2/5/10 13:39 AML 8.5 mg/l 0.20 mg/l Calcium EPA 200.7 2/5/10 10:05 AML 15460 mg/l 0.10 mg/l Bromide EPA 300.1 2/5/10 13:41 AML 1,060 mg/l 0.10 mg/l Iron EPA 200.7 2/5/10 10:10 AML 68.0 mg/l 0.02 mg/l Magnesium EPA 200.7 2/5/10 10:06 AML 1415 mg/l 0.10 mg/l Potassium EPA 200.7 2/5/10 10:14 AML 465.0 mg/l 0.10 mg/l Sodium EPA 200.7 2/5/10 10:15 AML 21,200 mg/l 0.10 mg/l Gross Alpha DW EPA 900 2/17/10 17:44 6502103 3009 PCi/L 3 PCi/L Gross Beta DW EPA 900 2/17/10 17:44 6502103 416 PCi/L 4 PCi/L Radium 226 EPA 903.1 2/25/10 13:14 6502103 1448 pCi/L .6 pCi/L

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Radium 228 EPA 904.0 2/24/10 13:53 6502103 715 pCi/L .9 pCi/L Aluminum EPA 200.7 2/5/10 10:07 AML <2.0 mg/l 0.10 mg/l Antimony EPA 200.7 2/19/10 14:02 AML <0.5 mg/L 0.001 mg/L Arsenic EPA 200.7 2/19/10 13:59 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/5/10 10:13 AML 158.0 mg/l 0.10 mg/l Beryllium EPA 200.7 2/19/10 14:01 AML <0.5 mg/L 0.001 mg/L Boron EPA 200.7 2/5/10 10:13 AML 11.0 mg/l 0.02 mg/l Cadmium EPA 200.7 2/19/10 14:01 AML 0.012 mg/L 0.001 mg/L Chromium EPA 200.7 2/5/10 10:11 AML <0.4 mg/l 0.02 mg/l Cobalt EPA 200.7 2/19/10 13:58 AML 0.012 mg/L 0.001 mg/L Lead EPA 200.7 2/5/10 10:12 AML <0.4 mg/L 0.02 mg/L Lithium, Total EPA 200.7 2/12/10 9:23 22-293 152 mg/L 5.0 mg/L Manganese EPA 200.7 2/5/10 10:09 AML 5.2 mg/l 0.02 mg/l

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Mercury, Total EPA 200.8 2/14/10 15:08 22-293 ND 0.020 mg/L Molybdenum EPA 200.7 2/19/10 13:59 AML 0.003 mg/L 0.001 mg/L Nickel EPA 200.7 2/5/10 10:11 AML <1.0 mg/l 0.05 mg/l Selenium EPA 200.7 2/19/10 13:59 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 2/19/10 14:00 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 2/12/10 9:23 22-293 2190 mg/L 0.25 mg/L Thallium EPA 200.7 2/19/10 14:00 AML 0.006 mg/L 0.001 mg/L Tin EPA 200.7 2/19/10 13:58 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 2/19/10 13:58 AML 0.0058 mg/L 0.001 mg/L Vanadium, Total EPA 200.7 2/12/10 9:23 22-293 ND 0.25 mg/L Uranium SW846 6020A 2/18/10 23:53 22-293 ND 1.0 mg/L Zinc EPA 200.7 2/5/10 10:12 AML <0.4 mg/l 0.02 mg/l Osmotic Pressure PA DEP 2/6/10 6:12 22-293 2990 mOs/kg 10 mOs/kg

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Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Phenolics EPA 420.4 2/17/10 4:39 22-293 0.07 mg/L 0.01 mg/L BOD SM5210B 2/4/10 12:37 TO >77.9 2 mg/L Thorium 228 HSL-300M 2/26/10 15:15 6502103 31.0 pCi/L pCi/L Thorium 230 HSL-300m 2/26/10 15:15 6502103 0.181 pCi/L pCi/L Thorium 232 HSL-300m 2/26/10 15:15 6502103 0.058 pCi/L pCi/L Specific Conductance EPA 120.1 2/8/10 0:00 TO

194,800 umhos/cm 2 umhos/cm Iron, Dissolved EPA 200.7 2/18/10 16:02 AML 16.0 mg/l 0.02 mg/l Copper EPA 200.7 2/5/10 14:09 AML 0.8 mg/l 0.02 mg/l 1,1,2,2-Tetrachloro ethane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/11/10 19:02 22-293 ND 35.0 ug/L 1,2-Dibromoethan e SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 2/11/10 19:02 22-293 ND 50.0 ug/L

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Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

2-Hexanone SW846 8260B 2/11/10 19:02 22-293 ND 25.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/11/10 19:02 22-293 ND 25.0 ug/L Acetone SW846 8260B 2/11/10 19:02 22-293 ND 50.0 ug/L Bromide EPA 300 2/10/10 5:03 22-293 1140 mg/L 600 mg/L Bromochlorometha ne SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Bromoform SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Carbon Disulfide SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Chlorodibromomet hane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Chloroform SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Chloromethane SW846 8260B 2/11/10 19:02 22-293 10.9 ug/L 5.0 ug/L

Page 6 of 10 3/10/2010 2:58:08PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Diesel Range Organics C10-C28 SW846 8015D 2/11/10 23:50 22-293 5.9 mg/L 3.1 mg/L Ethane RSK 175 2/8/10 21:40 22-293 120 ug/L 30.0 ug/L Ethylene Glycol SW846 8015D 2/9/10 22:27 22-293 ND 10.0 mg/L Gasoline Range Organics SW846 8015D 2/16/10 22:09 22-293 6690 ug/L 2500 ug/L Methane RSK 175 2/8/10 21:40 22-293 52.6 ug/L 10.0 ug/L Silica, Dissolved SM20-4500SiD 2/17/10 0:44 22-293 52 mg/L 5 mg/L Silicon, Total EPA 200.7 2/16/10 13:12 22-293 7.0 mg/L 5.0 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 2/16/10 9:00 22-293 17.0 mg/L 1.0 mg/L cis-1,3-Dichloropro pene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L mp-Xylene SW846 8260B 2/11/10 19:02 22-293 294 ug/L 10.0 ug/L o-Xylene SW846 8260B 2/11/10 19:02 22-293 60.1 ug/L 5.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Alkalinity, Carbonate SM20-2322 2/6/10 5:48 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/6/10 5:48 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/6/10 5:48 22-293 ND 5 mg/L Ethene RSK 175 2/8/10 21:40 22-293 ND 30.0 ug/L Formaldehyde SW846 8015D 2/18/10 12:01 22-293 9890 mg/L 100 mg/L Methanol SW846 8015D 2/18/10 20:21 22-293 4330 mg/L 100 mg/L Benzene SW846 8260B 2/11/10 19:02 22-293 756 ug/L 5.0 ug/L Carbon Tetrachloride SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 1,2-Dichloropropan e SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L

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Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Ethylbenzene SW846 8260B 2/11/10 19:02 22-293 27.3 ug/L 5.0 ug/L Chlorobenzene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Styrene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Tetrachloroethene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Toluene SW846 8260B 2/11/10 19:02 22-293 948 ug/L 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Vinyl Chloride SW846 8260B 2/11/10 19:02 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 2/11/10 19:02 22-293 354 ug/L 15.0 ug/L Nitrate EPA 300.0 2/5/10 13:40 AML <5.0 mg/l 0.10 mg/l Nitrite EPA 300.0 2/5/10 13:41 AML <5.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/5/10 13:41 AML <10.0 mg/l 0.20 mg/l

Page 9 of 10 3/10/2010 2:58:08PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100194 Altela

NETL Grant PW N/A 02/03/10 07:30 02/04/10 08:50 N/A Grab

Total Coliform SM 9223B 2/4/10 16:54 WEH 0 /100 mls 0 /100 mls E Coli SM 9223B 2/4/10 16:54 WEH NA +/- 

## Sample Comments: BOD: Duplicate analysis recovery was outside established control limits.

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# WATER QUALITY REPORT #02100193 FRAC WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

pH SM4500 H+B 2/5/10 13:10 AML 7.53 SU SU Total Dissolved Solids SM 2540 C 2/5/10 14:49 RCS 19,630 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/5/10 11:44 RCS 15 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/5/10 10:20 NJD 3.2 mg/l 5 mg/l COD HACH 8000 2/11/10 10:11 NJD 1253 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/6/10 2:15 22-293 0.328 mg/L 0.025 mg/L Heterotrophic Plate Count SM 9215B 2/4/10 16:55 WEH 24,600 /ml 1 /ml Color 2/4/10 13:36 WEH 100 pccu 5 pccu Temperature (F), Field na 2/4/10 9:27 RCS 71 deg F deg F Osmotic Pressure PA DEP 2/6/10 6:12 22-293 533 mOs/kg 10 mOs/kg Acidity SM 2310 B 2/5/10 0:00 AML - 136 mg/L 3 mg/L Hardness, Total EPA 200.7 2/5/10 10:15 AML 2621 mg/l 10 mg/l Alkalinity SM 2320 B 2/5/10 13:11 AML 230.0 mg/l 5 mg/l

Page 1 of 10 3/3/2010 10:21:56AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Bicarbonate SM4500 CO2 D 2/12/10 11:55 AML 229.0 mg/L 5 mg/L Sulfate EPA 300.0 2/5/10 13:39 AML 155.0 mg/l 1 mg/l Chloride EPA 300.0 2/5/10 13:35 AML 9,500 mg/L 1 mg/L Fluoride EPA 300.0 2/5/10 13:39 AML 27.0 mg/l 0.20 mg/l Calcium EPA 200.7 2/5/10 10:05 AML 915.0 mg/l 0.10 mg/l Bromide EPA 300.1 2/5/10 13:41 AML 141.0 mg/l 0.10 mg/l Iron, Dissolved EPA 200.7 2/18/10 16:00 AML 4.2 mg/l 0.02 mg/l Iron EPA 200.7 2/5/10 10:10 AML 5.6 mg/l 0.02 mg/l Magnesium EPA 200.7 2/5/10 10:06 AML 81.6 mg/l 0.10 mg/l Potassium EPA 200.7 2/5/10 10:14 AML 55.3 mg/l 0.10 mg/l Sodium EPA 200.7 2/5/10 10:15 AML 5250 mg/l 0.10 mg/l Silicon, Total EPA 200.7 2/16/10 13:08 22-293 6.7 mg/L 1.3 mg/L Gross Alpha DW EPA 900 2/17/10 17:44 6502103 27.0 PCi/L 3 PCi/L

Page 2 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Gross Beta DW EPA 900 2/17/10 17:44 6502103 36.0 PCi/L 4 PCi/L Radium 226 EPA 903.1 2/25/10 13:14 6502103 46.0 pCi/L .6 pCi/L Radium 228 EPA 904.0 2/24/10 13:53 6502103 17.0 pCi/L .9 pCi/L Aluminum EPA 200.7 2/5/10 10:07 AML <2.0 mg/l 0.10 mg/l Arsenic EPA 200.7 2/19/10 13:59 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/5/10 10:13 AML 17.1 mg/l 0.10 mg/l Cadmium EPA 200.7 2/19/10 14:01 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/5/10 10:11 AML <0.4 mg/l 0.02 mg/l Cobalt EPA 200.7 2/19/10 13:58 AML 0.031 mg/L 0.001 mg/L Beryllium EPA 200.7 2/19/10 14:01 AML <0.5 mg/L 0.001 mg/L Boron EPA 200.7 2/5/10 10:13 AML 4.4 mg/l 0.02 mg/l Antimony EPA 200.7 2/19/10 14:02 AML <0.5 mg/L 0.001 mg/L Lead EPA 200.7 2/5/10 10:12 AML <0.4 mg/L 0.02 mg/L

Page 3 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Lithium, Total EPA 200.7 2/12/10 9:07 22-293 10.7 mg/L 1.3 mg/L Manganese EPA 200.7 2/5/10 10:09 AML 0.8 mg/l 0.02 mg/l Mercury, Total EPA 200.8 2/14/10 15:45 22-293 ND 0.0020 mg/L Molybdenum EPA 200.7 2/19/10 13:59 AML 0.018 mg/L 0.001 mg/L Nickel EPA 200.7 2/5/10 10:11 AML <1.0 mg/l 0.05 mg/l Selenium EPA 200.7 2/19/10 13:59 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 2/19/10 14:00 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 2/12/10 9:07 22-293 97.5 mg/L 0.063 mg/L Thallium EPA 200.7 2/19/10 14:00 AML 0.015 mg/L 0.001 mg/L Tin EPA 200.7 2/19/10 13:58 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 2/19/10 13:58 AML <0.5 mg/L 0.001 mg/L Zinc EPA 200.7 2/5/10 10:12 AML <0.4 mg/l 0.02 mg/l Uranium SW846 6020A 2/18/10 23:49 22-293 ND 0.10 mg/L

Page 4 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Vanadium, Total EPA 200.7 2/12/10 9:07 22-293 ND 0.063 mg/L Total Residual Chlorine HACH 8167 2/4/10 9:26 RCS <0.10 mg/L 0.10 mg/L Phenolics EPA 420.4 2/17/10 4:38 22-293 0.05 mg/L 0.01 mg/L BOD SM5210B 2/4/10 12:37 TO >76.0 2 mg/L Thorium 228 HSL-300M 2/26/10 15:15 6502103 1.10 pCi/L pCi/L Thorium 230 HSL-300m 2/26/10 15:15 6502103 0.773 pCi/L pCi/L Thorium 232 HSL-300m 2/26/10 15:15 6502103 -0.031 pCi/L pCi/L Specific Conductance EPA 120.1 2/8/10 0:00 TO 29,400 umhos/cm 2 umhos/cm Copper EPA 200.7 2/5/10 14:09 AML 0.46 mg/l 0.02 mg/l Silica, Dissolved SM20-4500SiD 2/17/10 0:44 22-293 54 mg/L 5 mg/L 1,1,2,2-Tetrachloro ethane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/9/10 23:26 22-293 ND 35.0 ug/L

Page 5 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

1,2-Dibromoethan e SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 2/9/10 23:26 22-293 ND 50.0 ug/L 2-Hexanone SW846 8260B 2/9/10 23:26 22-293 ND 25.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/9/10 23:26 22-293 ND 25.0 ug/L Acetone SW846 8260B 2/9/10 23:26 22-293 304 ug/L 50.0 ug/L Bromide EPA 300 2/10/10 4:48 22-293 150 mg/L 30.0 mg/L Bromochlorometha ne SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Bromoform SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Carbon Disulfide SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Chlorodibromomet hane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L

Page 6 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Chloroform SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Chloromethane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Diesel Range Organics C10-C28 SW846 8015D 2/11/10 23:20 22-293 28.4 mg/L 3.7 mg/L Ethane RSK 175 2/8/10 21:24 22-293 140 ug/L 30.0 ug/L Ethylene Glycol SW846 8015D 2/9/10 22:06 22-293 ND 10.0 mg/L Gasoline Range Organics SW846 8015D 2/13/10 1:36 22-293 2100 ug/L 100 ug/L Methane RSK 175 2/8/10 21:24 22-293 848 ug/L 10.0 ug/L Total Kjeldahl Nitrogen SM20-4500-N C 2/16/10 9:00 22-293 29.6 mg/L 1.0 mg/L cis-1,3-Dichloropro pene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L mp-Xylene SW846 8260B 2/9/10 23:26 22-293 47.5 ug/L 10.0 ug/L o-Xylene SW846 8260B 2/9/10 23:26 22-293 18.8 ug/L 5.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L

Page 7 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Alkalinity, Carbonate SM20-2322 2/6/10 5:41 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/6/10 5:41 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/6/10 5:41 22-293 ND 5 mg/L Ethene RSK 175 2/8/10 21:24 22-293 ND 30.0 ug/L Formaldehyde SW846 8015D 2/18/10 12:31 22-293 110 mg/L 5.0 mg/L Methanol SW846 8015D 2/18/10 20:05 22-293 50.1 mg/L 1.0 mg/L Benzene SW846 8260B 2/9/10 23:26 22-293 218 ug/L 5.0 ug/L Carbon Tetrachloride SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 1,2-Dichloropropan e SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L

Page 8 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Ethylbenzene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Chlorobenzene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Styrene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Tetrachloroethene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Toluene SW846 8260B 2/9/10 23:26 22-293 228 ug/L 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Vinyl Chloride SW846 8260B 2/9/10 23:26 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 2/9/10 23:26 22-293 66.2 ug/L 15.0 ug/L Nitrate EPA 300.0 2/5/10 13:40 AML <5.0 mg/l 0.10 mg/l Nitrite EPA 300.0 2/5/10 13:41 AML <5.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/5/10 13:41 AML <10.0 mg/l 0.20 mg/l

Page 9 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100193 Altela

NETL Grant Frac Water N/A 02/03/10 07:00 02/04/10 08:37 N/A Grab

Total Coliform SM 9223B 2/4/10 16:54 WEH 0 /100 mls 0 /100 mls E Coli SM 9223B 2/4/10 16:54 WEH NA +/- 

## Sample Comments: BOD: Duplicate analysis recovery was outside established control limits.

Page 10 of 10 3/3/2010 10:21:57AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #02100197 FRAC FLOW - BACK WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

pH SM4500 H+B 2/5/10 13:10 AML 7.39 SU SU Total Dissolved Solids SM 2540 C 2/5/10 14:49 RCS 40,530 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/5/10 11:44 RCS 22 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/5/10 10:20 NJD 1.1 mg/l 5 mg/l BOD SM5210B 2/5/10 9:31 TO >74.2 2 mg/L COD HACH 8000 2/11/10 10:11 NJD 1042 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/6/10 2:15 22-293 0.239 mg/L 0.025 mg/L Heterotrophic Plate Count SM 9215B 2/4/10 16:55 WEH 4,810,000 /ml 1 /ml Color 2/4/10 13:36 WEH 125 pccu 5 pccu Temperature (F), Field na 2/4/10 13:35 RCS 74 deg F deg F Osmotic Pressure PA DEP 2/6/10 6:12 22-293 1110 mOs/kg 10 mOs/kg Total Residual Chlorine HACH 8167 2/4/10 13:36 RCS <0.10 mg/L 0.10 mg/L Acidity SM 2310 B 2/5/10 0:00 AML - 114 mg/L 3 mg/L

Page 1 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Alkalinity SM 2320 B 2/5/10 13:11 AML 196.0 mg/l 5 mg/l Hardness, Total EPA 200.7 2/5/10 10:15 AML 7040 mg/l 10 mg/l Bicarbonate SM4500 CO2 D 2/12/10 11:55 AML 196.0 mg/L 5 mg/L Sulfate EPA 300.0 2/5/10 13:39 AML 155.0 mg/l 1 mg/l Chloride EPA 300.0 2/5/10 13:35 AML 20100 mg/L 1 mg/L Fluoride EPA 300.0 2/5/10 13:39 AML 9.5 mg/l 0.20 mg/l Calcium EPA 200.7 2/5/10 10:05 AML 2465 mg/l 0.10 mg/l Bromide EPA 300.1 2/5/10 13:41 AML 291.0 mg/l 0.10 mg/l Iron EPA 200.7 2/5/10 10:10 AML 8.4 mg/l 0.02 mg/l Magnesium EPA 200.7 2/5/10 10:06 AML 215 mg/l 0.10 mg/l Potassium EPA 200.7 2/5/10 10:14 AML 94.8 mg/l 0.10 mg/l Sodium EPA 200.7 2/5/10 10:15 AML 10,380 mg/l 0.10 mg/l Gross Alpha DW EPA 900 2/19/10 17:41 6502103 76.4 PCi/L 3 PCi/L

Page 2 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Gross Beta DW EPA 900 2/13/10 16:14 6502103 240 PCi/L 4 PCi/L Radium 226 EPA 903.1 2/25/10 13:24 6502103 33.1 pCi/L .6 pCi/L Radium 228 EPA 904.0 2/24/10 13:53 6502103 27.3 pCi/L .9 pCi/L Aluminum EPA 200.7 2/5/10 10:07 AML <2.0 mg/l 0.10 mg/l Antimony EPA 200.7 2/19/10 14:02 AML <0.5 mg/L 0.001 mg/L Arsenic EPA 200.7 2/19/10 13:59 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/5/10 10:13 AML 52.9 mg/l 0.10 mg/l Beryllium EPA 200.7 2/19/10 14:01 AML <0.5 mg/L 0.001 mg/L Boron EPA 200.7 2/5/10 10:13 AML 6.4 mg/l 0.02 mg/l Cadmium EPA 200.7 2/19/10 14:01 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/5/10 10:11 AML <0.4 mg/l 0.02 mg/l Cobalt EPA 200.7 2/19/10 13:58 AML 0.033 mg/L 0.001 mg/L Lead EPA 200.7 2/5/10 10:12 AML <0.4 mg/L 0.02 mg/L

Page 3 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Lithium, Total EPA 200.7 2/12/10 9:02 22-293 21.5 mg/L 1.3 mg/L Manganese EPA 200.7 2/5/10 10:09 AML 2.0 mg/l 0.02 mg/l Mercury, Total EPA 200.8 2/14/10 15:37 22-293 ND 0.0050 mg/L Molybdenum EPA 200.7 2/19/10 13:59 AML 0.016 mg/L 0.001 mg/L Nickel EPA 200.7 2/5/10 10:11 AML <1.0 mg/l 0.05 mg/l Selenium EPA 200.7 2/19/10 13:59 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 2/19/10 14:00 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 2/12/10 9:02 22-293 265 mg/L 0.063 mg/L Thallium EPA 200.7 2/19/10 14:00 AML 0.009 mg/L 0.001 mg/L Tin EPA 200.7 2/19/10 13:58 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 2/19/10 13:58 AML 0.0094 mg/L 0.001 mg/L Uranium SW846 6020A 2/18/10 23:45 22-293 ND 0.25 mg/L Zinc EPA 200.7 2/5/10 10:12 AML <0.4 mg/l 0.02 mg/l

Page 4 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Vanadium, Total EPA 200.7 2/12/10 9:02 22-293 ND 0.063 mg/L Thorium 228 HSL-300M 2/26/10 11:07 6502103 1.21 pCi/L pCi/L Thorium 230 HSL-300m 2/26/10 11:07 6502103 0.567 pCi/L pCi/L Thorium 232 HSL-300m 2/26/10 11:07 6502103 0.096 pCi/L pCi/L Specific Conductance EPA 120.1 2/8/10 0:00 TO 56,700 umhos/cm 2 umhos/cm Iron, Dissolved EPA 200.7 2/18/10 16:02 AML 8.3 mg/l 0.02 mg/l Copper EPA 200.7 2/5/10 14:09 AML 0.52 mg/l 0.02 mg/l 1,1,2,2-Tetrachloro ethane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/9/10 22:55 22-293 ND 35.0 ug/L 1,2-Dibromoethan e SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 2/9/10 22:55 22-293 ND 50.0 ug/L 2-Hexanone SW846 8260B 2/9/10 22:55 22-293 ND 25.0 ug/L

Page 5 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/9/10 22:55 22-293 ND 25.0 ug/L Acetone SW846 8260B 2/9/10 22:55 22-293 2090 ug/L 50.0 ug/L Bromide EPA 300 2/10/10 5:18 22-293 270 mg/L 150 mg/L Bromochlorometha ne SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Bromoform SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Carbon Disulfide SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Chlorodibromomet hane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Chloroform SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Chloromethane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Diesel Range Organics C10-C28 SW846 8015D 2/11/10 22:49 22-293 17.4 mg/L 3.2 mg/L

Page 6 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Ethane RSK 175 2/8/10 20:35 22-293 133 ug/L 6.0 ug/L Ethylene Glycol SW846 8015D 2/9/10 21:46 22-293 ND 10.0 mg/L Gasoline Range Organics SW846 8015D 2/13/10 1:01 22-293 928 ug/L 100 ug/L Methane RSK 175 2/8/10 20:35 22-293 390 ug/L 2.0 ug/L Silica, Dissolved SM20-4500SiD 2/17/10 0:44 22-293 49 mg/L 5 mg/L Silicon, Total EPA 200.7 2/16/10 13:03 22-293 9.2 mg/L 1.3 mg/L Phenolics EPA 420.4 2/17/10 4:37 22-293 0.04 mg/L 0.01 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 2/16/10 9:00 22-293 9.2 mg/L 1.0 mg/L cis-1,3-Dichloropro pene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L mp-Xylene SW846 8260B 2/9/10 22:55 22-293 27.2 ug/L 10.0 ug/L o-Xylene SW846 8260B 2/9/10 22:55 22-293 8.9 ug/L 5.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L

Page 7 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Alkalinity, Carbonate SM20-2322 2/6/10 5:35 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/6/10 5:35 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/6/10 5:35 22-293 ND 5 mg/L Ethene RSK 175 2/8/10 20:35 22-293 ND 6.0 ug/L Formaldehyde SW846 8015D 2/18/10 1:26 22-293 75.4 mg/L 1.0 mg/L Methanol SW846 8015D 2/13/10 1:21 22-293 35.2 mg/L 1.0 mg/L Benzene SW846 8260B 2/9/10 22:55 22-293 55.3 ug/L 5.0 ug/L Carbon Tetrachloride SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 1,2-Dichloropropan e SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L

Page 8 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Ethylbenzene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Chlorobenzene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Styrene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Tetrachloroethene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Toluene SW846 8260B 2/9/10 22:55 22-293 85.3 ug/L 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Vinyl Chloride SW846 8260B 2/9/10 22:55 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 2/9/10 22:55 22-293 36.2 ug/L 15.0 ug/L Nitrate EPA 300.0 2/5/10 13:40 AML <5.0 mg/l 0.10 mg/l Nitrite EPA 300.0 2/5/10 13:41 AML <5.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/5/10 13:41 AML <10.0 mg/l 0.20 mg/l

Page 9 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100197 Altela

NETL Grant Flow Back Water N/A 02/04/10 10:14 02/04/10 11:30 N/A Grab

Total Coliform SM 9223B 2/4/10 16:54 WEH 0 /100 mls 0 /100 mls E Coli SM 9223B 2/4/10 16:54 WEH NA +/- 

## Sample Comments: None

Page 10 of 10 3/3/2010 10:26:39AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 9100467 PRODUCED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

pH SM4500 H+B 9/14/10 13:17 AML 7.00 SU SU Total Dissolved Solids SM 2540 C 9/17/10 11:46 TSA 37,600 mg/l 5 mg/l Total Suspended Solids SM 2540 D 9/14/10 14:25 TSA 114 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 9/17/10 0:00 NJD 1.6 mg/l 5 mg/l BOD SM5210B 9/15/10 9:16 TSA 76.8 mg/L 2 mg/L COD HACH 8000 9/24/10 13:50 NJD 289 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 9/15/10 21:00 22-293 0.180 mg/L 0.025 mg/L Color 9/13/10 14:54 WEH 200 pccu 5 pccu Temperature (F), Field na 9/13/10 17:13 RCJ 62.3 deg F deg F Osmotic Pressure PA DEP 9/16/10 6:05 22-293 808 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 9/14/10 8:52 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 9/14/10 13:27 WEH 17.8 mg/L .10 mg/L Nitrate EPA 300.0 9/14/10 13:38 AML <1.0 mg/l 0.10 mg/l

Page 1 of 10 11/1/2010 7:46:06AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Nitrite EPA 300.0 9/14/10 13:37 AML <1.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 9/14/10 13:37 AML <2.0 mg/l 0.20 mg/l Acidity SM 2310 B 9/14/10 13:16 AML -30.0 mg/L 3 mg/L Alkalinity SM 2320 B 9/14/10 13:17 AML 102.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 9/14/10 13:25 AML 102.0 mg/L 5 mg/L Sulfate EPA 300.0 9/14/10 13:38 AML 34.0 mg/l 1 mg/l Chloride EPA 300.0 9/14/10 13:38 AML 16,240 mg/L 1 mg/L Fluoride EPA 300.0 9/14/10 13:39 AML 4.8 mg/l 0.20 mg/l Calcium EPA 200.7 9/17/10 16:18 AML 1,933 mg/l 0.10 mg/l Iron EPA 200.7 9/17/10 16:21 AML 23.1 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 9/17/10 16:24 AML 22.9 mg/l 0.02 mg/l Magnesium EPA 200.7 9/17/10 16:19 AML 176.8 mg/l 0.10 mg/l Potassium EPA 200.7 9/17/10 16:19 AML 95.5 mg/l 0.10 mg/l

Page 2 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Sodium EPA 200.7 9/17/10 16:19 AML 7,781 mg/l 0.10 mg/l Aluminum EPA 200.7 9/17/10 16:23 AML <1.0 mg/l 0.10 mg/l Arsenic EPA 200.7 10/1/10 13:54 AML 0.028 mg/L 0.005 mg/L Barium EPA 200.7 9/17/10 16:17 AML 405.5 mg/l 0.10 mg/l Beryllium EPA 200.7 10/1/10 13:56 AML <0.05 mg/L 0.005 mg/L Cadmium EPA 200.7 10/1/10 13:53 AML <0.05 mg/L 0.005 mg/L Chromium EPA 200.7 9/17/10 16:22 AML <0.2 mg/l 0.02 mg/l Cobalt EPA 200.7 10/1/10 13:57 AML <0.05 mg/L 0.005 mg/L Manganese EPA 200.7 9/17/10 16:20 AML 2.9 mg/l 0.02 mg/l Molybdenum EPA 200.7 10/1/10 13:53 AML <0.05 mg/L 0.005 mg/L Nickel EPA 200.7 9/17/10 16:22 AML <0.5 mg/l 0.05 mg/l Selenium EPA 200.7 10/1/10 13:52 AML <0.05 mg/L 0.005 mg/L Silver EPA 200.7 10/1/10 13:55 AML <0.05 mg/L 0.005 mg/L

Page 3 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Strontium, Total EPA 200.7 9/21/10 11:27 22-293 379 mg/L 0.13 mg/L Thallium EPA 200.7 10/1/10 13:55 AML <0.05 mg/L 0.005 mg/L Tin EPA 200.7 10/1/10 13:52 AML <0.05 mg/L 0.005 mg/L Titanium EPA 200.7 10/1/10 13:52 AML 0.037 mg/L 0.005 mg/L Zinc EPA 200.7 9/17/10 16:24 AML <0.2 mg/l 0.02 mg/l Gross Alpha DW EPA 900 9/26/10 10:56 6502103 352 PCi/L 3 PCi/L Gross Beta DW EPA 900 9/25/10 10:57 6502103 189 PCi/L 4 PCi/L Radium 226 EPA 903.1 9/27/10 11:02 6502103 162 pCi/L .6 pCi/L Radium 228 EPA 904.0 10/11/10 11:02 6502103 85.5 pCi/L .9 pCi/L Total Residual Chlorine HACH 8167 9/13/10 15:54 RCJ <0.10 mg/L 0.10 mg/L Phenolics EPA 420.4 9/21/10 11:38 22-293 0.01 mg/L 0.01 mg/L Uranium, Total SW846 6020A 9/27/10 17:40 22-293 ND 0.11 mg/L Lead EPA 200.7 9/17/10 16:23 AML <0.2 mg/L 0.02 mg/L

Page 4 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Lithium, Total EPA 200.7 9/21/10 11:27 22-293 14.3 mg/L 2.5 mg/L Boron EPA 200.7 9/17/10 16:24 AML 3.12 mg/l 0.02 mg/l Antimony EPA 200.7 10/1/10 13:56 AML <0.05 mg/L 0.005 mg/L Silicon, Total EPA 200.7 9/20/10 14:40 22-293 7.0 mg/L 0.50 mg/L Hardness, Total EPA 200.7 9/17/10 16:17 AML 5,555 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 9/13/10 15:37 TSA 5,900 /ml 1 /ml Total Coliform SM 9223B 9/13/10 15:33 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 9/13/10 15:33 TSA NA +/- Specific Conductance EPA 120.1 9/14/10 11:36 AML 42,400 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 9/23/10 8:14 22-293 ND 500 ug/L Diesel Range Organics C10-C28 SW846 8015D 9/23/10 8:53 22-293 5.4 mg/L 1.6 mg/L Methane RSK 175 9/17/10 20:09 22-293 748 ug/L 1.0 ug/L Ethylene Glycol SW846 8015D 9/18/10 0:54 22-293 ND 10.0 mg/L

Page 5 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Alkalinity, Carbonate SM20-2322 9/16/10 9:57 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 9/16/10 9:57 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 9/16/10 9:57 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 9/28/10 9:30 22-293 1.4 mg/L 1.0 mg/L Formaldehyde SW846 8015D 9/23/10 19:33 22-293 ND 1.0 mg/L Acetone SW846 8260B 9/22/10 9:25 22-293 9520 ug/L 500 ug/L Silica, Dissolved SM20-4500SiO2C 9/22/10 23:35 22-293 30 mg/L 5 mg/L 2-Hexanone SW846 8260B 9/21/10 13:52 22-293 ND 25.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 9/21/10 13:52 22-293 ND 25.0 ug/L 2-Butanone SW846 8260B 9/21/10 13:52 22-293 ND 50.0 ug/L Ethene RSK 175 9/17/10 20:09 22-293 ND 3.0 ug/L Methanol SW846 8015D 9/21/10 20:55 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L

Page 6 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

mp-Xylene SW846 8260B 9/21/10 13:52 22-293 ND 10.0 ug/L Chloromethane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Ethane RSK 175 9/17/10 20:09 22-293 3.8 ug/L 3.0 ug/L Chlorodibromomet hane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Chloroform SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Carbon Disulfide SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Bromide EPA 300 9/14/10 13:36 AML 162.5 mg/L 0.3 mg/L Bromochlorometha ne SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 9/21/10 13:52 22-293 ND 35.0 ug/L 1,2-Dibromoethan e SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L

Page 7 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

1,1,2,2-Tetrachloro ethane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,2-Dichloropropan e SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Chlorobenzene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Tetrachloroethene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Benzene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L

Page 8 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Carbon Tetrachloride SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Ethylbenzene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Styrene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Toluene SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Vinyl Chloride SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 9/21/10 13:52 22-293 ND 15.0 ug/L Vanadium, Total EPA 200.7 9/21/10 11:27 22-293 ND 0.13 mg/L Copper EPA 200.7 9/22/10 13:22 AML 0.33 mg/l 0.02 mg/l Bromoform SW846 8260B 9/21/10 13:52 22-293 ND 5.0 ug/L Thorium 228 HSL-300M 9/28/10 11:03 6502103 5.273 pCi/L pCi/L

Page 9 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100467 Altela

4011 PW Entry Point N/A 09/13/10 10:45 09/13/10 14:35 N/A Grab

Thorium 230 HSL-300m 9/28/10 11:04 6502103 0.048 pCi/L pCi/L Thorium 232 HSL-300m 9/28/10 11:04 6502103 -0.005 pCi/L pCi/L 

## Sample Comments: Cadmium: Matrix Spike recovery was outside established control limits. Silver: Matrix Spike recovery was outside established control limits.

Page 10 of 10

11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT # 09100468 D ISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

pH SM4500 H+B 9/14/10 13:17 AML 7.87 SU SU Total Dissolved Solids SM 2540 C 9/17/10 11:46 TSA 9 mg/l 5 mg/l Total Suspended Solids SM 2540 D 9/14/10 14:25 TSA 3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 9/17/10 0:00 NJD 2.1 mg/l 5 mg/l BOD SM5210B 9/15/10 9:16 TSA < 2.0 mg/L 2 mg/L COD HACH 8000 9/24/10 13:50 NJD <10 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 9/15/10 21:00 22-293 ND 0.025 mg/L Color 9/13/10 14:54 WEH < 5 pccu 5 pccu Temperature (F), Field na 9/13/10 17:13 RCJ 136.1 deg F deg F Osmotic Pressure PA DEP 9/16/10 6:05 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 9/15/10 9:15 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 9/16/10 11:04 WEH 3.88 mg/L .10 mg/L Nitrate EPA 300.0 9/14/10 13:38 AML <0.10 mg/l 0.10 mg/l

Page 1 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Nitrite EPA 300.0 9/14/10 13:37 AML <0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 9/14/10 13:37 AML <0.20 mg/l 0.20 mg/l Acidity SM 2310 B 9/14/10 13:16 AML 6.0 mg/L 3 mg/L Alkalinity SM 2320 B 9/14/10 13:17 AML 14.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 9/14/10 13:25 AML 14.0 mg/L 5 mg/L Sulfate EPA 300.0 9/14/10 13:38 AML <1.0 mg/l 1 mg/l Chloride EPA 300.0 9/14/10 13:38 AML 2.9 mg/L 1 mg/L Fluoride EPA 300.0 9/14/10 13:39 AML <0.20 mg/l 0.20 mg/l Calcium EPA 200.7 9/17/10 16:18 AML 0.36 mg/l 0.10 mg/l Iron EPA 200.7 9/17/10 16:21 AML <0.02 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 9/17/10 16:24 AML <0.02 mg/l 0.02 mg/l Magnesium EPA 200.7 9/17/10 16:19 AML <0.10 mg/l 0.10 mg/l Potassium EPA 200.7 9/17/10 16:19 AML <0.10 mg/l 0.10 mg/l

Page 2 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Sodium EPA 200.7 9/17/10 16:19 AML 0.37 mg/l 0.10 mg/l Aluminum EPA 200.7 9/17/10 16:23 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 10/1/10 13:54 AML <0.005 mg/L 0.005 mg/L Barium EPA 200.7 9/17/10 16:17 AML <0.10 mg/l 0.10 mg/l Beryllium EPA 200.7 10/1/10 13:56 AML <0.005 mg/L 0.005 mg/L Cadmium EPA 200.7 10/1/10 13:53 AML <0.005 mg/L 0.005 mg/L Chromium EPA 200.7 9/17/10 16:22 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 10/1/10 13:57 AML <0.005 mg/L 0.005 mg/L Manganese EPA 200.7 9/17/10 16:20 AML <0.02 mg/l 0.02 mg/l Molybdenum EPA 200.7 10/1/10 13:53 AML <0.005 mg/L 0.005 mg/L Nickel EPA 200.7 9/17/10 16:22 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 10/1/10 13:52 AML <0.005 mg/L 0.005 mg/L Silver EPA 200.7 10/1/10 13:55 AML <0.005 mg/L 0.005 mg/L

Page 3 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Strontium, Total EPA 200.7 9/21/10 11:37 22-293 0.026 mg/L 0.0025 mg/L Thallium EPA 200.7 10/1/10 13:55 AML <0.005 mg/L 0.005 mg/L Tin EPA 200.7 10/1/10 13:52 AML <0.005 mg/L 0.005 mg/L Titanium EPA 200.7 10/1/10 13:52 AML <0.005 mg/L 0.005 mg/L Zinc EPA 200.7 9/17/10 16:24 AML <0.02 mg/l 0.02 mg/l Gross Alpha DW EPA 900 9/25/10 10:57 6502103 -0.409 PCi/L 3 PCi/L Gross Beta DW EPA 900 9/25/10 10:57 6502103 -0.141 PCi/L 4 PCi/L Radium 226 EPA 903.1 9/27/10 11:02 6502103 0.278 pCi/L .6 pCi/L Radium 228 EPA 904.0 10/11/10 11:02 6502103 0.259 pCi/L .9 pCi/L Total Residual Chlorine HACH 8167 9/13/10 15:54 RCJ <0.10 mg/L 0.10 mg/L Phenolics EPA 420.4 9/21/10 11:39 22-293 0.03 mg/L 0.01 mg/L Uranium, Total SW846 6020A 9/27/10 17:46 22-293 ND 0.11 mg/L Lead EPA 200.7 9/17/10 16:23 AML <0.02 mg/L 0.02 mg/L

Page 4 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Lithium, Total EPA 200.7 9/21/10 11:37 22-293 ND 0.050 mg/L Boron EPA 200.7 9/17/10 16:24 AML 0.02 mg/l 0.02 mg/l Antimony EPA 200.7 10/1/10 13:56 AML <0.005 mg/L 0.005 mg/L Silicon, Total EPA 200.7 9/20/10 15:03 22-293 0.19 mg/L 0.050 mg/L Hardness, Total EPA 200.7 9/17/10 16:17 AML <10.0 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 9/13/10 15:37 TSA < 100 /ml 1 /ml Total Coliform SM 9223B 9/13/10 15:33 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 9/13/10 15:33 TSA NA +/- Specific Conductance EPA 120.1 9/14/10 11:36 AML 30.0 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 9/23/10 0:17 22-293 ND 100 ug/L Diesel Range Organics C10-C28 SW846 8015D 9/21/10 21:21 22-293 0.99 mg/L 0.16 mg/L Methane RSK 175 9/17/10 20:24 22-293 1.3 ug/L 1.0 ug/L Ethylene Glycol SW846 8015D 9/18/10 1:15 22-293 ND 10.0 mg/L

Page 5 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Alkalinity, Carbonate SM20-2322 9/16/10 10:05 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 9/16/10 10:05 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 9/16/10 10:05 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 9/28/10 9:30 22-293 3.3 mg/L 1.0 mg/L Formaldehyde SW846 8015D 9/23/10 19:15 22-293 ND 1.0 mg/L Acetone SW846 8260B 9/23/10 2:08 22-293 174 ug/L 10.0 ug/L Silica, Dissolved SM20-4500SiO2C 9/22/10 23:35 22-293 ND 1 mg/L 2-Hexanone SW846 8260B 9/23/10 2:08 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 9/23/10 2:08 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 9/23/10 2:08 22-293 ND 10.0 ug/L Ethene RSK 175 9/17/10 20:24 22-293 ND 3.0 ug/L Methanol SW846 8015D 9/21/10 21:10 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L

Page 6 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

mp-Xylene SW846 8260B 9/23/10 2:08 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Ethane RSK 175 9/17/10 20:24 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Chloroform SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 9/23/10 2:08 22-293 2.8 ug/L 1.0 ug/L Bromide EPA 300 9/14/10 13:36 AML <0.30 mg/L 0.3 mg/L Bromochlorometha ne SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 9/23/10 2:08 22-293 ND 7.0 ug/L 1,2-Dibromoethan e SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L

Page 7 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

1,1,2,2-Tetrachloro ethane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,2-Dichloropropan e SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Benzene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L

Page 8 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Carbon Tetrachloride SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Styrene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Toluene SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Vinyl Chloride SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 9/23/10 2:08 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 9/21/10 11:37 22-293 ND 0.0025 mg/L Copper EPA 200.7 9/22/10 13:22 AML <0.02 mg/l 0.02 mg/l Bromoform SW846 8260B 9/23/10 2:08 22-293 ND 1.0 ug/L Thorium 228 HSL-300M 9/28/10 11:03 6502103 0.096 pCi/L pCi/L

Page 9 of 10 11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 09100468 Altela

4011 DW Basin N/A 09/13/10 11:30 09/13/10 14:39 N/A Grab

Thorium 230 HSL-300m 9/28/10 11:04 6502103 0.087 pCi/L pCi/L Thorium 232 HSL-300m 9/28/10 11:04 6502103 0.025 pCi/L pCi/L 

## Sample Comments: Cadmium: Matrix Spike recovery was outside established control limits. Silver: Matrix Spike recovery was outside established control limits.

Page 10 of 10

11/1/2010 7:46:07AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 2110642 PRODUCED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

pH SM4500 H+B 2/15/11 16:38 AML 6.50 SU SU Total Dissolved Solids SM 2540 C 2/18/11 15:33 WEH 26,055 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/15/11 15:32 WEH 35 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/21/11 0:00 TO 0.1 mg/l 5 mg/l BOD SM5210B 2/16/11 11:30 TSA 107 mg/L 2 mg/L COD HACH 8000 2/23/11 9:53 WEH 344 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/16/11 21:45 22-293 ND 0.025 mg/L Color 2/15/11 15:19 WEH 130 pccu 5 pccu Temperature (F), Field na 2/15/11 0:00 ZW 63 deg F deg F Osmotic Pressure PA DEP 2/17/11 5:15 22-293 637 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 2/16/11 14:09 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 2/17/11 9:03 WEH 28.1 mg/L .10 mg/L Nitrate EPA 300.0 2/16/11 13:03 AML <1.0 mg/l 0.10 mg/l

Page 1 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Nitrite EPA 300.0 2/16/11 13:02 AML <1.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/16/11 13:03 AML <2.0 mg/l 0.20 mg/l Acidity SM 2310 B 2/15/11 16:38 AML < 5 mg/L 3 mg/L Alkalinity SM 2320 B 2/15/11 16:38 AML 110 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/15/11 16:38 AML 110 mg/L 5 mg/L Sulfate EPA 300.0 2/16/11 13:04 AML 20.4 mg/l 1 mg/l Chloride EPA 300.0 2/16/11 13:04 AML 11,670 mg/L 1 mg/L Fluoride EPA 300.0 2/16/11 13:01 AML <2.0 mg/l 0.20 mg/l Calcium EPA 200.7 2/18/11 12:09 AML 1,634 mg/l 0.10 mg/l Iron EPA 200.7 2/18/11 12:11 AML 17.4 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 2/18/11 12:23 AML 21.1 mg/l 0.02 mg/l Magnesium EPA 200.7 2/18/11 12:10 AML 139.5 mg/l 0.10 mg/l Potassium EPA 200.7 2/18/11 12:12 AML 66.2 mg/l 0.10 mg/l

Page 2 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Sodium EPA 200.7 2/18/11 12:09 AML 5,868 mg/l 0.10 mg/l Aluminum EPA 200.7 2/18/11 12:11 AML <1.0 mg/l 0.10 mg/l Arsenic EPA 200.7 3/1/11 14:11 AML <0.05 mg/L 0.005 mg/L Barium EPA 200.7 2/18/11 12:10 AML 332.2 mg/l 0.10 mg/l Beryllium EPA 200.7 3/1/11 14:10 AML <0.05 mg/L 0.005 mg/L Cadmium EPA 200.7 3/1/11 14:10 AML <0.05 mg/L 0.005 mg/L Chromium EPA 200.7 2/18/11 13:37 AML <0.2 mg/l 0.02 mg/l Cobalt EPA 200.7 3/1/11 14:09 AML <0.05 mg/L 0.005 mg/L Manganese EPA 200.7 2/18/11 12:13 AML 2.1 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/1/11 14:09 AML <0.05 mg/L 0.005 mg/L Nickel EPA 200.7 2/18/11 13:36 AML <0.5 mg/l 0.05 mg/l Selenium EPA 200.7 3/1/11 14:09 AML <0.05 mg/L 0.005 mg/L Silver EPA 200.7 3/1/11 14:08 AML <0.05 mg/L 0.005 mg/L

Page 3 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Strontium EPA 200.7 2/18/11 12:10 AML 317.8 mg/l 0.10 mg/l Thallium EPA 200.7 3/1/11 14:08 AML <0.05 mg/L 0.005 mg/L Tin EPA 200.7 3/1/11 14:08 AML <0.05 mg/L 0.005 mg/L Titanium EPA 200.7 3/1/11 14:07 AML <0.05 mg/L 0.005 mg/L Zinc EPA 200.7 2/18/11 13:36 AML <0.2 mg/l 0.02 mg/l Gross Alpha DW EPA 900 2/25/11 13:51 6502103 664 PCi/L 3 PCi/L Gross Beta DW EPA 900 2/21/11 13:51 6502103 847 PCi/L 4 PCi/L Radium 226 EPA 903.1 2/22/11 13:53 6502103 153 pCi/L .6 pCi/L Radium 228 EPA 904.0 2/25/11 14:00 6502103 45.0 pCi/L .9 pCi/L Total Residual Chlorine HACH 8167 2/15/11 0:00 RCJ 0.00 mg/L 0.10 mg/L Phenolics EPA 420.4 3/1/11 4:09 22-293 ND 0.01 mg/L Uranium, Total SW846 6020A 2/28/11 17:06 22-293 ND 0.14 mg/L Mercury EPA 200.8 2/23/11 8:45 22-293 ND 0.001 mg/l

Page 4 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Lead EPA 200.7 2/18/11 12:11 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 2/22/11 11:28 22-293 10.7 mg/L 4.0 mg/L Boron EPA 200.7 2/18/11 12:13 AML 2.7 mg/l 0.02 mg/l Antimony EPA 200.7 3/1/11 14:11 AML <0.05 mg/L 0.005 mg/L Silicon, Total EPA 200.7 2/22/11 14:14 22-293 6.4 mg/L 4.0 mg/L Bromide EPA 300.1 2/16/11 13:04 AML 118.5 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/18/11 12:08 AML 4,655 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/15/11 16:10 TSA 18,600 /ml 1 /ml Total Coliform SM 9223B 2/15/11 16:14 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 2/15/11 16:14 TSA NA +/- Specific Conductance EPA 120.1 2/17/11 13:15 AML 34,300 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 2/16/11 22:51 22-293 ND 500 ug/L Diesel Range Organics C10-C28 SW846 8015D 2/23/11 8:32 22-293 7.1 mg/L 1.6 mg/L

Page 5 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Methane RSK 175 2/18/11 17:59 22-293 5490 ug/L 1.0 ug/L Ethylene Glycol SW846 8015D 2/18/11 19:46 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/17/11 8:52 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/17/11 8:52 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/17/11 8:52 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 2/17/11 12:30 22-293 ND 1.0 mg/L Formaldehyde SW846 8015D 2/25/11 21:37 22-293 ND 1.0 mg/L Acetone SW846 8260B 2/23/11 21:26 22-293 13800 ug/L 250 ug/L Silica, Dissolved SM20-4500SiO2C 2/23/11 3:17 22-293 25 mg/L 10 mg/L 2-Hexanone SW846 8260B 2/18/11 23:57 22-293 ND 25.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/18/11 23:57 22-293 ND 25.0 ug/L 2-Butanone SW846 8260B 2/18/11 23:57 22-293 ND 50.0 ug/L Ethene RSK 175 2/18/11 17:59 22-293 ND 3.0 ug/L

Page 6 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Methanol SW846 8015D 3/1/11 0:24 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L mp-Xylene SW846 8260B 2/18/11 23:57 22-293 ND 10.0 ug/L Chloromethane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Ethane RSK 175 2/18/11 17:59 22-293 8.9 ug/L 3.0 ug/L Chlorodibromomet hane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Chloroform SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Carbon Disulfide SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Bromochlorometh ane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/18/11 23:57 22-293 ND 35.0 ug/L

Page 7 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

1,2-Dibromoethan e SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L 1,1,2,2-Tetrachlor oethane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 2/18/11 23:57 22-293 22.0 ug/L 5.0 ug/L 1,2-Dichloropropa ne SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Chlorobenzene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Tetrachloroethene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L trans-1,2-Dichloro ethene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L trans-1,3-Dichloro propene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L

Page 8 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Benzene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Carbon Tetrachloride SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Ethylbenzene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Styrene SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Toluene SW846 8260B 2/18/11 23:57 22-293 8.3 ug/L 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Vinyl Chloride SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 2/18/11 23:57 22-293 ND 15.0 ug/L Vanadium, Total EPA 200.7 2/22/11 11:28 22-293 ND 0.20 mg/L Copper EPA 200.7 2/18/11 14:34 AML <0.2 mg/l 0.02 mg/l Bromoform SW846 8260B 2/18/11 23:57 22-293 ND 5.0 ug/L

Page 9 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110642 Altela

4011 PW Water N/A 02/15/11 12:30 02/15/11 14:38 N/A Grab

Thorium 228 HSL-300M 2/21/11 14:00 6502103 10.760 pCi/L pCi/L Thorium 230 HSL-300m 2/22/11 14:01 6502103 -0.135 pCi/L pCi/L Thorium 232 HSL-300m 2/22/11 14:01 6502103 0.114 pCi/L pCi/L 

## Sample Comments: None

Page 10 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 2110641 DISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

pH SM4500 H+B 2/15/11 16:38 AML 4.73 SU SU Total Dissolved Solids SM 2540 C 2/18/11 15:33 WEH 33 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/15/11 15:32 WEH 3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/21/11 0:00 TO 2.6 mg/l 5 mg/l BOD SM5210B 2/16/11 11:30 TSA 26.6 mg/L 2 mg/L COD HACH 8000 2/23/11 9:53 WEH 48.3 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/16/11 21:45 22-293 ND 0.025 mg/L Color 2/15/11 15:19 WEH < 5 pccu 5 pccu Temperature (F), Field na 2/15/11 0:00 ZW 135 deg F deg F Osmotic Pressure PA DEP 2/17/11 5:15 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 2/16/11 14:09 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 2/17/11 9:03 WEH 1.77 mg/L .10 mg/L Nitrate EPA 300.0 2/16/11 13:03 AML <0.10 mg/l 0.10 mg/l

Page 1 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Nitrite EPA 300.0 2/16/11 13:02 AML <0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/16/11 13:03 AML <0.20 mg/l 0.20 mg/l Acidity SM 2310 B 2/15/11 16:38 AML 16 mg/L 3 mg/L Alkalinity SM 2320 B 2/15/11 16:38 AML < 5 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/15/11 16:38 AML < 5 mg/L 5 mg/L Sulfate EPA 300.0 2/16/11 13:04 AML 2.2 mg/l 1 mg/l Chloride EPA 300.0 2/16/11 13:04 AML 14.6 mg/L 1 mg/L Fluoride EPA 300.0 2/16/11 13:01 AML <0.20 mg/l 0.20 mg/l Calcium EPA 200.7 2/18/11 12:09 AML 2.18 mg/l 0.10 mg/l Iron EPA 200.7 2/18/11 12:11 AML 0.12 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 2/18/11 12:23 AML <0.02 mg/l 0.02 mg/l Magnesium EPA 200.7 2/18/11 12:10 AML 0.36 mg/l 0.10 mg/l Potassium EPA 200.7 2/18/11 12:12 AML <0.10 mg/l 0.10 mg/l

Page 2 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Sodium EPA 200.7 2/18/11 12:09 AML 6.42 mg/l 0.10 mg/l Aluminum EPA 200.7 2/18/11 12:11 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 3/1/11 14:11 AML <0.005 mg/L 0.005 mg/L Barium EPA 200.7 2/18/11 12:10 AML 0.33 mg/l 0.10 mg/l Beryllium EPA 200.7 3/1/11 14:10 AML <0.005 mg/L 0.005 mg/L Cadmium EPA 200.7 3/1/11 14:10 AML <0.005 mg/L 0.005 mg/L Chromium EPA 200.7 2/18/11 13:37 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 3/1/11 14:09 AML <0.005 mg/L 0.005 mg/L Manganese EPA 200.7 2/18/11 12:13 AML <0.02 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/1/11 14:09 AML <0.005 mg/L 0.005 mg/L Nickel EPA 200.7 2/18/11 13:36 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 3/1/11 14:09 AML <0.005 mg/L 0.005 mg/L Silver EPA 200.7 3/1/11 14:08 AML <0.005 mg/L 0.005 mg/L

Page 3 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Strontium EPA 200.7 2/18/11 12:10 AML 0.35 mg/l 0.10 mg/l Thallium EPA 200.7 3/1/11 14:08 AML <0.005 mg/L 0.005 mg/L Tin EPA 200.7 3/1/11 14:08 AML 0.007 mg/L 0.005 mg/L Titanium EPA 200.7 3/1/11 14:07 AML <0.005 mg/L 0.005 mg/L Zinc EPA 200.7 2/18/11 13:36 AML 0.05 mg/l 0.02 mg/l Gross Alpha DW EPA 900 2/21/11 13:51 6502103 0.841 PCi/L 3 PCi/L Gross Beta DW EPA 900 2/21/11 13:51 6502103 0.259 PCi/L 4 PCi/L Radium 226 EPA 903.1 2/22/11 13:53 6502103 0.224 pCi/L .6 pCi/L Radium 228 EPA 904.0 2/25/11 14:00 6502103 1.32 pCi/L .9 pCi/L Total Residual Chlorine HACH 8167 2/15/11 0:00 RCJ 0.45 mg/L 0.10 mg/L Phenolics EPA 420.4 2/23/11 14:55 22-293 0.03 mg/L 0.01 mg/L Uranium, Total SW846 6020A 2/28/11 16:36 22-293 ND 0.028 mg/L Mercury EPA 200.8 2/23/11 8:45 22-293 ND 0.001 mg/l

Page 4 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Lead EPA 200.7 2/18/11 12:11 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 2/18/11 16:15 22-293 ND 0.050 mg/L Boron EPA 200.7 2/18/11 12:13 AML 0.05 mg/l 0.02 mg/l Antimony EPA 200.7 3/1/11 14:11 AML <0.005 mg/L 0.005 mg/L Silicon, Total EPA 200.7 2/22/11 14:10 22-293 0.19 mg/L 0.050 mg/L Bromide EPA 300.1 2/16/11 13:04 AML <0.10 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/18/11 12:08 AML <10.0 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/15/11 16:10 TSA 20 /ml 1 /ml Total Coliform SM 9223B 2/15/11 16:14 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 2/15/11 16:14 TSA NA +/- Specific Conductance EPA 120.1 2/17/11 13:15 AML 74.5 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 2/16/11 23:25 22-293 ND 100 ug/L Diesel Range Organics C10-C28 SW846 8015D 2/23/11 4:51 22-293 2.3 mg/L 0.31 mg/L

Page 5 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Methane RSK 175 2/18/11 17:06 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 2/18/11 19:24 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/17/11 8:46 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/17/11 8:46 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/17/11 8:46 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 2/17/11 12:30 22-293 1.5 mg/L 1.0 mg/L Formaldehyde SW846 8015D 2/25/11 20:52 22-293 ND 1.0 mg/L Acetone SW846 8260B 2/19/11 0:27 22-293 949 ug/L 50.0 ug/L Silica, Dissolved SM20-4500SiO2C 2/23/11 3:17 22-293 ND 1 mg/L 2-Hexanone SW846 8260B 2/19/11 0:27 22-293 ND 25.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/19/11 0:27 22-293 ND 25.0 ug/L 2-Butanone SW846 8260B 2/19/11 0:27 22-293 ND 50.0 ug/L Ethene RSK 175 2/18/11 17:06 22-293 ND 3.0 ug/L

Page 6 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Methanol SW846 8015D 2/28/11 23:26 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L mp-Xylene SW846 8260B 2/19/11 0:27 22-293 ND 10.0 ug/L Chloromethane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Ethane RSK 175 2/18/11 17:06 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Chloroform SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Carbon Disulfide SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Bromochlorometh ane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/19/11 0:27 22-293 ND 35.0 ug/L

Page 7 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

1,2-Dibromoethan e SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,1,2,2-Tetrachlor oethane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 2/19/11 0:27 22-293 9.0 ug/L 5.0 ug/L 1,2-Dichloropropa ne SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Chlorobenzene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Tetrachloroethene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L trans-1,2-Dichloro ethene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L trans-1,3-Dichloro propene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L

Page 8 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Benzene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Carbon Tetrachloride SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Ethylbenzene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Styrene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Toluene SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Vinyl Chloride SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 2/19/11 0:27 22-293 ND 15.0 ug/L Vanadium, Total EPA 200.7 2/18/11 16:15 22-293 ND 0.0025 mg/L Copper EPA 200.7 2/18/11 14:34 AML 0.07 mg/l 0.02 mg/l Bromoform SW846 8260B 2/19/11 0:27 22-293 ND 5.0 ug/L

Page 9 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02110641 Altela

4011 DW Water N/A 02/15/11 12:00 02/15/11 14:37 N/A Grab

Thorium 228 HSL-300M 2/21/11 14:00 6502103 0.118 pCi/L pCi/L Thorium 230 HSL-300m 2/22/11 14:01 6502103 0.085 pCi/L pCi/L Thorium 232 HSL-300m 2/22/11 14:01 6502103 0.011 pCi/L pCi/L 

## Sample Comments: None

Page 10 of 10 3/2/2011 9:08:03AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 3111242 PRODUCED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Total Residual Chlorine, Field HACH 8167 3/31/11 0:00 RCJ 0.00 mg/L 0.1 mg/L pH SM4500 H+B 4/1/11 15:44 AML 6.90 SU SU Total Dissolved Solids SM 2540 C 4/1/11 13:12 TSA 22,350 mg/l 5 mg/l Total Suspended Solids SM 2540 D 4/1/11 15:25 TSA 60 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 4/1/11 0:00 TO 2.7 mg/l 5 mg/l BOD SM5210B 4/1/11 11:10 TO 83.9 mg/L 2 mg/L COD HACH 8000 4/11/11 0:00 TO 220 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 4/1/11 21:00 22-293 ND 0.025 mg/L Color 4/1/11 8:20 WEH 55 pccu 5 pccu Temperature (F), Field na 3/31/11 0:00 RCJ 51 deg F deg F Osmotic Pressure PA DEP 4/2/11 5:00 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 4/4/11 8:23 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 4/4/11 13:49 WEH 10.2 mg/L .10 mg/L

Page 1 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Nitrate EPA 300.0 4/1/11 13:04 AML <10.0 mg/l 0.10 mg/l Nitrite EPA 300.0 4/1/11 13:04 AML <10.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 4/1/11 13:04 AML <20.0 mg/l 0.20 mg/l Acidity SM 2310 B 4/1/11 15:44 AML -26.0 mg/L 3 mg/L Alkalinity SM 2320 B 4/1/11 15:43 AML 88.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 4/1/11 15:44 AML 88.0 mg/L 5 mg/L Sulfate EPA 300.0 4/1/11 13:03 AML <100.0 mg/l 1 mg/l Chloride EPA 300.0 4/1/11 13:05 AML 9,760 mg/L 1 mg/L Fluoride EPA 300.0 4/1/11 13:03 AML <20.0 mg/l 0.20 mg/l Calcium EPA 200.7 4/1/11 14:34 AML 1,186 mg/l 0.10 mg/l Iron EPA 200.7 4/1/11 14:37 AML 17.6 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 4/1/11 14:36 AML 13.9 mg/l 0.02 mg/l Magnesium EPA 200.7 4/1/11 14:35 AML 121.3 mg/l 0.10 mg/l

Page 2 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Potassium EPA 200.7 4/1/11 14:59 AML 63.2 mg/l 0.10 mg/l Sodium EPA 200.7 4/1/11 14:41 AML 4,726 mg/l 0.10 mg/l Aluminum EPA 200.7 4/1/11 15:16 AML <5.0 mg/l 0.10 mg/l Arsenic EPA 200.7 4/5/11 16:35 AML <0.25 mg/L 0.005 mg/L Barium EPA 200.7 4/1/11 14:36 AML 284.7 mg/l 0.10 mg/l Beryllium, Total EPA 200.7 4/6/11 10:35 AML <0.25 mg/L 0.005 mg/L Cadmium EPA 200.7 4/5/11 16:36 AML <0.25 mg/L 0.005 mg/L Chromium EPA 200.7 4/1/11 14:40 AML <1.0 mg/l 0.02 mg/l Cobalt EPA 200.7 4/6/11 10:35 AML <0.25 mg/L 0.005 mg/L Manganese EPA 200.7 4/1/11 14:37 AML 2.0 mg/l 0.02 mg/l Molybdenum EPA 200.7 4/6/11 10:36 AML <0.25 mg/L 0.005 mg/L Nickel EPA 200.7 4/1/11 15:16 AML <2.5 mg/l 0.05 mg/l Selenium EPA 200.7 4/5/11 16:37 AML <0.25 mg/L 0.005 mg/L

Page 3 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Silver EPA 200.7 4/5/11 16:35 AML <0.25 mg/L 0.005 mg/L Strontium EPA 200.7 4/1/11 14:38 AML 264.2 mg/l 0.10 mg/l Thallium EPA 200.7 4/6/11 10:36 AML <0.25 mg/L 0.005 mg/L Tin EPA 200.7 4/6/11 10:34 AML <0.25 mg/L 0.005 mg/L Titanium EPA 200.7 4/6/11 10:34 AML <0.25 mg/L 0.005 mg/L Zinc EPA 200.7 4/1/11 14:41 AML <1.0 mg/l 0.02 mg/l Gross Alpha DW EPA 900 4/7/11 16:06 6502103 161 PCi/L 3 PCi/L Gross Beta DW EPA 900 4/7/11 16:06 6502103 79.7 PCi/L 4 PCi/L Radium 226 EPA 903.1 4/15/11 16:07 6502103 155 pCi/L .6 pCi/L Radium 228 EPA 904.0 4/15/11 16:07 6502103 51.9 pCi/L .9 pCi/L Phenolics EPA 420.4 4/11/11 14:19 22-293 ND 0.01 mg/L Uranium, Total SW846 6020A 4/16/11 6:47 22-293 ND 0.25 mg/L Mercury, Total EPA 245.1 4/8/11 9:27 22-293 ND 0.00050 mg/L

Page 4 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Lead EPA 200.7 4/1/11 15:17 AML <1.0 mg/L 0.02 mg/L Lithium, Total EPA 200.7 4/7/11 16:14 22-293 9.1 mg/L 1.5 mg/L Boron EPA 200.7 4/1/11 14:40 AML 2.0 mg/l 0.02 mg/l Antimony EPA 200.7 4/6/11 10:36 AML <0.25 mg/L 0.005 mg/L Silicon, Total EPA 200.7 4/11/11 15:51 22-293 5.1 mg/L 1.5 mg/L Bromide EPA 300.1 4/1/11 13:05 AML 101.0 mg/l 0.10 mg/l Hardness, Total EPA 200.7 4/1/11 14:48 AML 3,461 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 3/31/11 15:47 TSA 2,970 /ml 1 /ml Total Coliform SM 9223B 3/31/11 15:45 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 3/31/11 15:45 TSA NA +/- Specific Conductance EPA 120.1 4/1/11 11:47 AML 28,450 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 4/5/11 22:49 22-293 ND 5000 ug/L Diesel Range Organics C10-C28 SW846 8015D 4/7/11 17:31 22-293 4.0 mg/L 0.78 mg/L

Page 5 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Methane RSK 175 4/11/11 16:39 22-293 3570 ug/L 1.0 ug/L Ethylene Glycol SW846 8015D 4/9/11 3:26 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 4/2/11 5:38 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 4/2/11 5:38 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 4/2/11 5:38 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 4/5/11 12:37 22-293 30.1 mg/L 4.0 mg/L Formaldehyde SW846 8015D 4/11/11 22:33 22-293 ND 1.0 mg/L Acetone SW846 8260B 4/11/11 17:57 22-293 8710 ug/L 500 ug/L Silica, Dissolved SM20-4500SiO2C 4/9/11 1:34 22-293 16 mg/L 5 mg/L 2-Hexanone SW846 8260B 4/9/11 20:04 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 4/9/11 20:04 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 4/9/11 20:04 22-293 ND 10.0 ug/L Ethene RSK 175 4/11/11 16:39 22-293 ND 3.0 ug/L

Page 6 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Methanol SW846 8015D 4/8/11 17:47 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 4/9/11 20:04 22-293 2.3 ug/L 2.0 ug/L Chloromethane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Ethane RSK 175 4/11/11 16:39 22-293 6.4 ug/L 3.0 ug/L Chlorodibromomet hane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Chloroform SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Bromochlorometh ane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 4/9/11 20:04 22-293 ND 7.0 ug/L

Page 7 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

1,2-Dibromoethan e SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachlor oethane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,2-Dichloropropa ne SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L trans-1,2-Dichloro ethene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L trans-1,3-Dichloro propene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L

Page 8 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Benzene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Styrene SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Toluene SW846 8260B 4/9/11 20:04 22-293 10.9 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Vinyl Chloride SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 4/9/11 20:04 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 4/7/11 16:14 22-293 ND 0.075 mg/L Copper EPA 200.7 4/1/11 14:38 AML <1.0 mg/l 0.02 mg/l Bromoform SW846 8260B 4/9/11 20:04 22-293 ND 1.0 ug/L

Page 9 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111242 Altela

PW Water PW Influent Discharge 03/31/11 11:00 03/31/11 12:59 N/A Grab

Thorium 228 HSL-300M 4/19/11 16:08 6502103 11.408 pCi/L pCi/L Thorium 230 HSL-300m 4/19/11 16:08 6502103 0.035 pCi/L pCi/L Thorium 232 HSL-300m 4/19/11 16:09 6502103 0.055 pCi/L pCi/L 

## Sample Comments: None

Page 10 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 3111241 DISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Total Residual Chlorine, Field HACH 8167 3/31/11 0:00 RCJ 0.21 mg/L 0.1 mg/L pH SM4500 H+B 4/1/11 15:44 AML 6.24 SU SU Total Dissolved Solids SM 2540 C 4/1/11 13:12 TSA 196 mg/l 5 mg/l Total Suspended Solids SM 2540 D 4/1/11 15:25 TSA < 3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 4/1/11 0:00 TO 3.2 mg/l 5 mg/l BOD SM5210B 4/1/11 11:10 TO 27.1 mg/L 2 mg/L COD HACH 8000 4/11/11 0:00 TO 35.8 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 4/1/11 21:00 22-293 ND 0.025 mg/L Color 4/1/11 8:20 WEH < 5 pccu 5 pccu Temperature (F), Field na 3/31/11 0:00 RCJ 109 deg F deg F Osmotic Pressure PA DEP 4/2/11 5:00 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 4/4/11 8:23 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 4/4/11 13:49 WEH 4.42 mg/L .10 mg/L

Page 1 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Nitrate EPA 300.0 4/1/11 13:04 AML <0.10 mg/l 0.10 mg/l Nitrite EPA 300.0 4/1/11 13:04 AML <0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 4/1/11 13:04 AML <0.20 mg/l 0.20 mg/l Acidity SM 2310 B 4/1/11 15:44 AML <5.0 mg/L 3 mg/L Alkalinity SM 2320 B 4/1/11 15:43 AML <5.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 4/1/11 15:44 AML <5.0 mg/L 5 mg/L Sulfate EPA 300.0 4/1/11 13:03 AML 1.98 mg/l 1 mg/l Chloride EPA 300.0 4/1/11 13:05 AML 99.1 mg/L 1 mg/L Fluoride EPA 300.0 4/1/11 13:03 AML 0.32 mg/l 0.20 mg/l Calcium EPA 200.7 4/1/11 14:34 AML 11.1 mg/l 0.10 mg/l Iron EPA 200.7 4/1/11 14:37 AML 0.02 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 4/1/11 14:36 AML 0.03 mg/l 0.02 mg/l Magnesium EPA 200.7 4/1/11 14:35 AML 1.10 mg/l 0.10 mg/l

Page 2 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Potassium EPA 200.7 4/1/11 14:36 AML 0.52 mg/l 0.10 mg/l Sodium EPA 200.7 4/1/11 14:41 AML 43.8 mg/l 0.10 mg/l Aluminum EPA 200.7 4/1/11 15:16 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 4/5/11 16:35 AML <0.005 mg/L 0.005 mg/L Barium EPA 200.7 4/1/11 14:36 AML 2.47 mg/l 0.10 mg/l Beryllium, Total EPA 200.7 4/6/11 10:35 AML <0.005 mg/L 0.005 mg/L Cadmium EPA 200.7 4/5/11 16:36 AML <0.005 mg/L 0.005 mg/L Chromium EPA 200.7 4/1/11 14:40 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 4/6/11 10:35 AML <0.005 mg/L 0.005 mg/L Manganese EPA 200.7 4/1/11 14:37 AML <0.02 mg/l 0.02 mg/l Molybdenum EPA 200.7 4/6/11 10:36 AML <0.005 mg/L 0.005 mg/L Nickel EPA 200.7 4/1/11 15:16 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 4/5/11 16:37 AML <0.005 mg/L 0.005 mg/L

Page 3 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Silver EPA 200.7 4/5/11 16:35 AML <0.005 mg/L 0.005 mg/L Strontium EPA 200.7 4/1/11 14:38 AML 2.28 mg/l 0.10 mg/l Thallium EPA 200.7 4/6/11 10:36 AML <0.005 mg/L 0.005 mg/L Tin EPA 200.7 4/6/11 10:34 AML <0.005 mg/L 0.005 mg/L Titanium EPA 200.7 4/6/11 10:34 AML <0.005 mg/L 0.005 mg/L Zinc EPA 200.7 4/1/11 14:41 AML <0.02 mg/l 0.02 mg/l Gross Alpha DW EPA 900 4/7/11 16:06 6502103 1.93 PCi/L 3 PCi/L Gross Beta DW EPA 900 4/7/11 16:06 6502103 1.57 PCi/L 4 PCi/L Radium 226 EPA 903.1 4/15/11 16:07 6502103 2.87 pCi/L .6 pCi/L Radium 228 EPA 904.0 4/15/11 16:07 6502103 0.296 pCi/L .9 pCi/L Phenolics EPA 420.4 4/11/11 13:43 22-293 0.02 mg/L 0.01 mg/L Uranium, Total SW846 6020A 4/16/11 6:26 22-293 ND 0.25 mg/L Mercury, Total EPA 245.1 4/8/11 9:26 22-293 ND 0.00050 mg/L

Page 4 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Lead EPA 200.7 4/1/11 15:17 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 4/5/11 14:12 22-293 0.082 mg/L 0.050 mg/L Boron EPA 200.7 4/1/11 14:40 AML 0.06 mg/l 0.02 mg/l Antimony EPA 200.7 4/6/11 10:36 AML <0.005 mg/L 0.005 mg/L Silicon, Total EPA 200.7 4/11/11 14:54 22-293 0.16 mg/L 0.050 mg/L Bromide EPA 300.1 4/1/11 13:05 AML 0.92 mg/l 0.10 mg/l Hardness, Total EPA 200.7 4/1/11 14:48 AML 32.0 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 3/31/11 15:47 TSA 8,100 /ml 1 /ml Total Coliform SM 9223B 3/31/11 15:45 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 3/31/11 15:45 TSA NA +/- Specific Conductance EPA 120.1 4/1/11 11:47 AML 375.0 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 4/5/11 23:24 22-293 ND 500 ug/L Diesel Range Organics C10-C28 SW846 8015D 4/7/11 16:26 22-293 4.9 mg/L 0.77 mg/L

Page 5 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Methane RSK 175 4/11/11 16:30 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 4/9/11 3:04 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 4/2/11 5:31 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 4/2/11 5:31 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 4/2/11 5:31 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 4/5/11 12:37 22-293 4.5 mg/L 1.0 mg/L Formaldehyde SW846 8015D 4/11/11 22:16 22-293 ND 1.0 mg/L Acetone SW846 8260B 4/9/11 19:35 22-293 524 ug/L 10.0 ug/L Silica, Dissolved SM20-4500SiO2C 4/9/11 1:34 22-293 ND 1 mg/L 2-Hexanone SW846 8260B 4/9/11 19:35 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 4/9/11 19:35 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 4/9/11 19:35 22-293 ND 10.0 ug/L Ethene RSK 175 4/11/11 16:30 22-293 ND 3.0 ug/L

Page 6 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Methanol SW846 8015D 4/8/11 17:32 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 4/9/11 19:35 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Ethane RSK 175 4/11/11 16:30 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Chloroform SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Bromochlorometh ane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 4/9/11 19:35 22-293 ND 7.0 ug/L

Page 7 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

1,2-Dibromoethan e SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachlor oethane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,2-Dichloropropa ne SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L trans-1,2-Dichloro ethene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L trans-1,3-Dichloro propene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L

Page 8 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Benzene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Styrene SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Toluene SW846 8260B 4/9/11 19:35 22-293 1.3 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Vinyl Chloride SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 4/9/11 19:35 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 4/5/11 14:12 22-293 ND 0.0025 mg/L Copper EPA 200.7 4/1/11 14:38 AML <0.02 mg/l 0.02 mg/l Bromoform SW846 8260B 4/9/11 19:35 22-293 ND 1.0 ug/L

Page 9 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 03111241 Altela

D W Water DW Tank N/A 03/31/11 10:00 03/31/11 12:57 N/A Grab

Thorium 228 HSL-300M 4/19/11 16:08 6502103 0.103 pCi/L pCi/L Thorium 230 HSL-300m 4/19/11 16:08 6502103 0.169 pCi/L pCi/L Thorium 232 HSL-300m 4/19/11 16:09 6502103 0.016 pCi/L pCi/L 

## Sample Comments: None

Page 10 of 10 4/27/2011 9:19:05AM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT # 04110152 PRODUCED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Total Residual Chlorine, Field HACH 8167 4/6/11 0:00 RCJ 0.00 mg/L 0.1 mg/L pH SM4500 H+B 4/6/11 16:39 AML 6.51 SU SU Total Dissolved Solids SM 2540 C 4/7/11 14:17 TSA 25560 mg/l 5 mg/l Total Suspended Solids SM 2540 D 4/6/11 16:23 MH 54 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 4/8/11 0:00 TO 3.7 mg/l 5 mg/l BOD SM5210B 4/7/11 10:46 TSA 99.6 mg/L 2 mg/L COD HACH 8000 4/11/11 0:00 TO 265 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 4/7/11 22:00 22-293 ND 0.025 mg/L Color 4/6/11 10:35 WEH 75 pccu 5 pccu Temperature (F), Field na 4/6/11 0:00 RCJ 61 deg F deg F Osmotic Pressure PA DEP 4/8/11 4:25 22-293 589 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 4/6/11 15:09 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 4/7/11 10:05 WEH 23.1 mg/L .10 mg/L

Page 1 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Nitrate EPA 300.0 4/7/11 15:04 AML <10 mg/l 0.10 mg/l Nitrite EPA 300.0 4/7/11 15:03 AML <10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 4/7/11 15:03 AML <20 mg/l 0.20 mg/l Acidity SM 2310 B 4/7/11 12:58 AML -16.0 mg/L 3 mg/L Alkalinity SM 2320 B 4/6/11 16:39 AML 100.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 4/7/11 10:47 AML 100.0 mg/L 5 mg/L Sulfate EPA 300.0 4/7/11 15:02 AML <100 mg/l 1 mg/l Chloride EPA 300.0 4/7/11 15:05 AML 11,352 mg/L 1 mg/L Fluoride EPA 300.0 4/7/11 15:04 AML <20 mg/l 0.20 mg/l Calcium EPA 200.7 4/8/11 16:01 AML 1,175 mg/l 0.10 mg/l Iron EPA 200.7 4/8/11 16:11 AML 18.5 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 4/8/11 16:09 AML 14.3 mg/l 0.02 mg/l Magnesium EPA 200.7 4/8/11 16:00 AML 109.8 mg/l 0.10 mg/l

Page 2 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Potassium EPA 200.7 4/8/11 16:10 AML 59.6 mg/l 0.10 mg/l Sodium EPA 200.7 4/8/11 16:01 AML 4,712 mg/l 0.10 mg/l Aluminum EPA 200.7 4/8/11 16:13 AML <5.0 mg/l 0.10 mg/l Arsenic EPA 200.7 4/13/11 14:27 AML <0.01 mg/L 0.005 mg/L Barium EPA 200.7 4/8/11 16:09 AML 260.5 mg/l 0.10 mg/l Beryllium, Total EPA 200.7 4/13/11 14:26 AML <0.01 mg/L 0.005 mg/L Cadmium EPA 200.7 4/13/11 14:27 AML <0.01 mg/L 0.005 mg/L Chromium EPA 200.7 4/8/11 16:14 AML <1.0 mg/l 0.02 mg/l Cobalt EPA 200.7 4/13/11 14:28 AML <0.01 mg/L 0.005 mg/L Manganese EPA 200.7 4/8/11 16:12 AML 2.0 mg/l 0.02 mg/l Molybdenum EPA 200.7 4/13/11 14:28 AML <0.01 mg/L 0.005 mg/L Nickel EPA 200.7 4/8/11 16:14 AML <2.5 mg/l 0.05 mg/l Selenium EPA 200.7 4/13/11 14:28 AML <0.01 mg/L 0.005 mg/L

Page 3 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Silver EPA 200.7 4/13/11 14:29 AML <0.01 mg/L 0.005 mg/L Strontium EPA 200.7 4/8/11 16:10 AML 233.0 mg/l 0.10 mg/l Thallium EPA 200.7 4/14/11 14:29 AML <0.01 mg/L 0.005 mg/L Tin EPA 200.7 4/14/11 14:29 AML <0.01 mg/L 0.005 mg/L Titanium EPA 200.7 4/13/11 14:30 AML <0.01 mg/L 0.005 mg/L Zinc EPA 200.7 4/8/11 11:17 AML <1.0 mg/l 0.02 mg/l Gross Alpha DW EPA 900 4/15/11 16:10 6502103 249 PCi/L 3 PCi/L Gross Beta DW EPA 900 4/11/11 16:11 6502103 178 PCi/L 4 PCi/L Radium 226 EPA 903.1 4/20/11 16:12 6502103 130 pCi/L .6 pCi/L Radium 228 EPA 904.0 4/27/11 16:13 6502103 55.0 pCi/L .9 pCi/L Phenolics EPA 420.4 4/11/11 13:48 22-293 ND 0.01 mg/L Uranium, Total SW846 6020A 4/16/11 6:54 22-293 ND 0.11 mg/L Mercury, Total EPA 245.1 4/13/11 11:43 22-293 ND 0.00050 mg/L

Page 4 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Lead EPA 200.7 4/8/11 16:16 AML <1.0 mg/L 0.02 mg/L Lithium, Total EPA 200.7 4/14/11 14:31 22-293 10.7 mg/L 2.5 mg/L Boron EPA 200.7 4/8/11 16:10 AML <1.0 mg/l 0.02 mg/l Antimony EPA 200.7 4/13/11 14:30 AML <0.01 mg/L 0.005 mg/L Silicon, Total EPA 200.7 4/15/11 10:48 22-293 6.4 mg/L 2.5 mg/L Bromide EPA 300.1 4/7/11 15:05 AML 117.0 mg/l 0.10 mg/l Hardness, Total EPA 200.7 4/8/11 16:07 AML 3,386 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 4/6/11 15:00 TSA 140 /ml 1 /ml Total Coliform SM 9223B 4/6/11 15:00 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 4/6/11 15:00 TSA NA +/- Specific Conductance EPA 120.1 4/6/11 15:08 AML 31,600 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 4/9/11 0:35 22-293 ND 500 ug/L Diesel Range Organics C10-C28 SW846 8015D 4/18/11 12:51 22-293 4.3 mg/L 0.79 mg/L

Page 5 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Methane RSK 175 4/12/11 16:47 22-293 4550 ug/L 1.0 ug/L Ethylene Glycol SW846 8015D 4/14/11 12:25 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 4/8/11 11:59 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 4/8/11 11:59 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 4/8/11 11:59 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 4/11/11 11:11 22-293 19.7 mg/L 4.0 mg/L Formaldehyde SW846 8015D 4/11/11 22:50 22-293 ND 1.0 mg/L Acetone SW846 8260B 4/15/11 7:45 22-293 11800 ug/L 500 ug/L Silica, Dissolved SM20-4500SiO2C 4/9/11 1:34 22-293 19 mg/L 5 mg/L 2-Hexanone SW846 8260B 4/14/11 23:51 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 4/14/11 23:51 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 4/14/11 23:51 22-293 ND 10.0 ug/L Ethene RSK 175 4/12/11 16:44 22-293 ND 6.0 ug/L

Page 6 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Methanol SW846 8015D 4/20/11 20:57 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 4/14/11 23:51 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Ethane RSK 175 4/12/11 16:47 22-293 6.3 ug/L 3.0 ug/L Chlorodibromomet hane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Chloroform SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Bromochlorometh ane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 4/14/11 23:51 22-293 ND 7.0 ug/L

Page 7 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

1,2-Dibromoethan e SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachlor oethane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,2-Dichloropropa ne SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L trans-1,2-Dichloro ethene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L trans-1,3-Dichloro propene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L

Page 8 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Benzene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Styrene SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Toluene SW846 8260B 4/14/11 23:51 22-293 15.0 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Vinyl Chloride SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 4/14/11 23:51 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 4/14/11 14:31 22-293 ND 0.13 mg/L Copper EPA 200.7 4/8/11 16:13 AML <1.0 mg/l 0.02 mg/l Bromoform SW846 8260B 4/14/11 23:51 22-293 ND 1.0 ug/L

Page 9 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110152 Altela

PW Water PW Influent Discharge 04/06/11 08:00 04/06/11 10:06 N/A Grab

Thorium 228 HSL-300M 4/19/11 16:14 6502103 11.082 pCi/L pCi/L Thorium 230 HSL-300m 4/19/11 16:15 6502103 0.100 pCi/L pCi/L Thorium 232 HSL-300m 4/19/11 16:15 6502103 0.035 pCi/L pCi/L 

## Sample Comments: BOD: Duplicate analysis recovery was outside established control limits.

Page 10 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 4110153 DISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Total Residual Chlorine, Field HACH 8167 4/6/11 0:00 RCJ 0.00 mg/L 0.1 mg/L pH SM4500 H+B 4/6/11 16:39 AML 5.77 SU SU Total Dissolved Solids SM 2540 C 4/7/11 14:17 TSA 400 mg/l 5 mg/l Total Suspended Solids SM 2540 D 4/6/11 16:23 MH < 3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 4/8/11 0:00 TO 1.0 mg/l 5 mg/l BOD SM5210B 4/7/11 10:46 TSA 38.8 mg/L 2 mg/L COD HACH 8000 4/11/11 0:00 TO 51.4 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 4/7/11 22:00 22-293 ND 0.025 mg/L Color 4/6/11 10:35 WEH < 5 pccu 5 pccu Temperature (F), Field na 4/6/11 0:00 RCJ 97 deg F deg F Osmotic Pressure PA DEP 4/8/11 4:25 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 4/6/11 15:09 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 4/7/11 10:05 WEH 3.25 mg/L .10 mg/L

Page 1 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Nitrate EPA 300.0 4/7/11 15:04 AML <0.10 mg/l 0.10 mg/l Nitrite EPA 300.0 4/7/11 15:03 AML <0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 4/7/11 15:03 AML <0.20 mg/l 0.20 mg/l Acidity SM 2310 B 4/7/11 12:58 AML <5.0 mg/L 3 mg/L Alkalinity SM 2320 B 4/6/11 16:39 AML 12.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 4/7/11 10:47 AML 12.0 mg/L 5 mg/L Sulfate EPA 300.0 4/7/11 15:02 AML 2.1 mg/l 1 mg/l Chloride EPA 300.0 4/7/11 15:05 AML 184.2 mg/L 1 mg/L Fluoride EPA 300.0 4/7/11 15:04 AML 0.42 mg/l 0.20 mg/l Calcium EPA 200.7 4/8/11 16:01 AML 22.2 mg/l 0.10 mg/l Iron EPA 200.7 4/7/11 14:53 AML 0.08 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 4/8/11 16:09 AML 0.06 mg/l 0.02 mg/l Magnesium EPA 200.7 4/7/11 14:52 AML 2.04 mg/l 0.10 mg/l

Page 2 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Potassium EPA 200.7 4/7/11 14:51 AML 0.98 mg/l 0.10 mg/l Sodium EPA 200.7 4/8/11 16:01 AML 87.9 mg/l 0.10 mg/l Aluminum EPA 200.7 4/7/11 14:48 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 4/13/11 14:27 AML <0.005 mg/L 0.005 mg/L Barium EPA 200.7 4/7/11 14:50 AML 4.54 mg/l 0.10 mg/l Beryllium, Total EPA 200.7 4/13/11 14:26 AML <0.005 mg/L 0.005 mg/L Cadmium EPA 200.7 4/13/11 14:27 AML <0.005 mg/L 0.005 mg/L Chromium EPA 200.7 4/7/11 14:47 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 4/13/11 14:28 AML <0.005 mg/L 0.005 mg/L Manganese EPA 200.7 4/7/11 15:00 AML 0.04 mg/l 0.02 mg/l Molybdenum EPA 200.7 4/13/11 14:28 AML <0.005 mg/L 0.005 mg/L Nickel EPA 200.7 4/7/11 14:48 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 4/13/11 14:28 AML <0.005 mg/L 0.005 mg/L

Page 3 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Silver EPA 200.7 4/13/11 14:29 AML <0.005 mg/L 0.005 mg/L Strontium EPA 200.7 4/7/11 14:49 AML 3.93 mg/l 0.10 mg/l Thallium EPA 200.7 4/14/11 14:29 AML <0.005 mg/L 0.005 mg/L Tin EPA 200.7 4/14/11 14:29 AML <0.005 mg/L 0.005 mg/L Titanium EPA 200.7 4/13/11 14:30 AML <0.005 mg/L 0.005 mg/L Zinc EPA 200.7 4/7/11 14:45 AML 0.04 mg/l 0.02 mg/l Gross Alpha DW EPA 900 4/12/11 16:10 6502103 6.49 PCi/L 3 PCi/L Gross Beta DW EPA 900 4/12/11 16:11 6502103 0.754 PCi/L 4 PCi/L Radium 226 EPA 903.1 4/20/11 16:12 6502103 2.30 pCi/L .6 pCi/L Radium 228 EPA 904.0 4/20/11 16:13 6502103 0.490 pCi/L .9 pCi/L Phenolics EPA 420.4 4/11/11 13:53 22-293 0.02 mg/L 0.01 mg/L Uranium, Total SW846 6020A 4/16/11 7:02 22-293 ND 0.25 mg/L Mercury, Total EPA 245.1 4/13/11 11:44 22-293 ND 0.00050 mg/L

Page 4 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Lead EPA 200.7 4/7/11 14:47 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 4/12/11 15:05 22-293 0.13 mg/L 0.050 mg/L Boron EPA 200.7 4/7/11 14:46 AML 0.06 mg/l 0.02 mg/l Antimony EPA 200.7 4/13/11 14:30 AML <0.005 mg/L 0.005 mg/L Silicon, Total EPA 200.7 4/15/11 10:53 22-293 0.22 mg/L 0.050 mg/L Bromide EPA 300.1 4/7/11 15:05 AML 1.60 mg/l 0.10 mg/l Hardness, Total EPA 200.7 4/8/11 16:07 AML 64.0 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 4/6/11 15:00 TSA 7,020 /ml 1 /ml Total Coliform SM 9223B 4/6/11 15:00 TSA 0 /100 mls 0 /100 mls E Coli SM 9223B 4/6/11 15:00 TSA NA +/- Specific Conductance EPA 120.1 4/6/11 15:08 AML 632.0 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 4/8/11 23:59 22-293 ND 100 ug/L Diesel Range Organics C10-C28 SW846 8015D 4/18/11 13:33 22-293 3.1 mg/L 0.77 mg/L

Page 5 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Methane RSK 175 4/12/11 16:36 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 4/14/11 12:46 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 4/8/11 12:04 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 4/8/11 12:04 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 4/8/11 12:04 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 4/12/11 21:00 22-293 4.1 mg/L 2.0 mg/L Formaldehyde SW846 8015D 4/11/11 23:07 22-293 ND 1.0 mg/L Acetone SW846 8260B 4/14/11 18:59 22-293 658 ug/L 10.0 ug/L Silica, Dissolved SM20-4500SiO2C 4/9/11 1:34 22-293 ND 1 mg/L 2-Hexanone SW846 8260B 4/14/11 18:59 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 4/14/11 18:59 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 4/14/11 18:59 22-293 ND 10.0 ug/L Ethene RSK 175 4/12/11 16:44 22-293 ND 6.0 ug/L

Page 6 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Methanol SW846 8015D 4/20/11 21:42 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 4/14/11 18:59 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Ethane RSK 175 4/12/11 16:36 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Chloroform SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Bromochlorometh ane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 4/14/11 18:59 22-293 ND 7.0 ug/L

Page 7 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

1,2-Dibromoethan e SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachlor oethane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,2-Dichloropropa ne SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L trans-1,2-Dichloro ethene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L trans-1,3-Dichloro propene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L

Page 8 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Benzene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Styrene SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Toluene SW846 8260B 4/14/11 18:59 22-293 1.1 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Vinyl Chloride SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 4/14/11 18:59 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 4/12/11 15:05 22-293 ND 0.0025 mg/L Copper EPA 200.7 4/7/11 14:46 AML 0.08 mg/l 0.02 mg/l Bromoform SW846 8260B 4/14/11 18:59 22-293 ND 1.0 ug/L

Page 9 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 04110153 Altela

DW Tank DW Water Discharge 04/06/11 08:30 04/06/11 10:28 N/A Grab

Thorium 228 HSL-300M 4/20/11 16:14 6502103 0.128 pCi/L pCi/L Thorium 230 HSL-300m 4/20/11 16:15 6502103 0.113 pCi/L pCi/L Thorium 232 HSL-300m 4/20/11 16:15 6502103 -0.009 pCi/L pCi/L 

## Sample Comments: BOD: Duplicate analysis recovery was outside established control limits.

Page 10 of 10 4/28/2011 4:46:20PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# APPENDIX D

WATER QUALITY REPORTS ( TEST - BENCH CONCENTRATE WATER AND DISTILLED WATER )

# WATER QUALITY REPORT #02100762 P RODUCED W ATER TEST - BENCH CONCENTRATE WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Thorium 232 HSL-300m 3/19/10 13:34 6502103 0.150 pCi/L pCi/L Thorium 228 HSL-300M 3/19/10 13:32 6502103 22.7 pCi/L pCi/L Thorium 230 HSL-300m 3/19/10 13:34 6502103 0.465 pCi/L pCi/L Copper EPA 200.7 2/26/10 14:16 AML 2.0 mg/l 0.02 mg/l Benzene SW846 8260B 3/1/10 7:00 22-293 1.2 ug/L 1.0 ug/L pH SM4500 H+B 2/24/10 15:21 AML 5.96 SU SU Total Dissolved Solids SM 2540 C 2/23/10 11:49 RCS 345,680 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/23/10 13:00 RCS 176 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/26/10 12:40 NJD 2.2 mg/l 5 mg/l BOD SM5210B 2/24/10 10:35 TO 62.7 mg/L 2 mg/L COD HACH 8000 3/10/10 7:22 NJD 3800 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/24/10 21:45 22-293 0.184 mg/L 0.025 mg/L Color 2/23/10 11:16 WEH 20 pccu 5 pccu

Page 1 of 10 3/25/2010 3:52:05PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Temperature (F), Field na 3/5/10 9:02 RCS NA deg F Osmotic Pressure PA DEP 2/25/10 6:00 22-293 2970 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 2/25/10 8:42 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 2/25/10 9:40 WEH 267 mg/L .10 mg/L Nitrate EPA 300.0 2/24/10 12:52 AML <5.0 mg/l 0.10 mg/l Nitrite EPA 300.0 2/24/10 12:51 AML <5.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/24/10 12:51 AML <10.0 mg/l 0.20 mg/l Acidity SM 2310 B 2/24/10 16:13 AML 236.0 mg/L 3 mg/L Alkalinity SM 2320 B 2/24/10 15:20 AML 32.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/25/10 10:46 AML 32.0 mg/L 5 mg/L Sulfate EPA 300.0 2/24/10 12:52 AML 550.0 mg/l 1 mg/l Chloride EPA 300.0 2/24/10 12:53 AML 205200 mg/L 1 mg/L Fluoride EPA 300.0 2/24/10 12:52 AML 10.5 mg/l 0.20 mg/l

Page 2 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Calcium EPA 200.7 2/26/10 14:52 AML 29,800 mg/l 0.10 mg/l Iron EPA 200.7 2/26/10 14:26 AML 2.4 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 3/12/10 13:47 AML <0.4 mg/l 0.02 mg/l Magnesium EPA 200.7 2/26/10 14:52 AML 3120.0 mg/l 0.10 mg/l Potassium EPA 200.7 2/26/10 14:53 AML 1320 mg/l 0.10 mg/l Sodium EPA 200.7 2/26/10 14:53 AML 85,600 mg/l 0.10 mg/l Aluminum EPA 200.7 2/26/10 14:25 AML <2.0 mg/l 0.10 mg/l Arsenic EPA 200.7 3/10/10 14:01 AML <1.0 mg/L 0.001 mg/L Barium EPA 200.7 2/26/10 14:28 AML 148.0 mg/l 0.10 mg/l Beryllium EPA 200.7 3/10/10 14:00 AML <1.0 mg/L 0.001 mg/L Cadmium EPA 200.7 3/10/10 14:00 AML <1.0 mg/L 0.001 mg/L Chromium EPA 200.7 2/26/10 14:49 AML <0.4 mg/l 0.02 mg/l Cobalt EPA 200.7 3/10/10 13:59 AML <1.0 mg/L 0.001 mg/L

Page 3 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Manganese EPA 200.7 2/26/10 14:26 AML 8.2 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/10/10 13:59 AML <1.0 mg/L 0.001 mg/L Nickel EPA 200.7 2/26/10 14:51 AML <1.0 mg/l 0.05 mg/l Selenium EPA 200.7 3/10/10 13:58 AML <1.0 mg/L 0.001 mg/L Silver EPA 200.7 3/10/10 13:57 AML <1.0 mg/L 0.001 mg/L Strontium, Total EPA 200.7 3/5/10 9:10 22-293 4970 mg/L 1.5 mg/L Thallium EPA 200.7 3/10/10 14:59 AML <1.0 mg/L 0.001 mg/L Tin EPA 200.7 3/10/10 14:02 AML <1.0 mg/L 0.001 mg/L Titanium EPA 200.7 3/10/10 14:01 AML <1.0 mg/L 0.001 mg/L Zinc EPA 200.7 2/26/10 14:49 AML <0.4 mg/l 0.02 mg/l Gross Alpha DW EPA 900 3/3/10 11:49 6502103 1,912 PCi/L 3 PCi/L Gross Beta DW EPA 900 3/3/10 11:49 6502103 529 PCi/L 4 PCi/L Radium 226 EPA 903.1 3/19/10 11:47 6502103 1,527 pCi/L .6 pCi/L

Page 4 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Radium 228 EPA 904.0 3/18/10 11:48 6502103 751 pCi/L .9 pCi/L Total Residual Chlorine HACH 8167 2/23/10 15:39 RCS <0.10 mg/L 0.10 mg/L Phenolics EPA 420.4 3/1/10 10:11 22-293 ND 0.01 mg/L Uranium SW846 6020A 3/8/10 14:52 22-293 ND 1.1 mg/L Mercury, Total EPA 245.1 3/1/10 12:01 22-293 ND 0.013 mg/L Lead EPA 200.7 2/26/10 14:51 AML <0.4 mg/L 0.02 mg/L Lithium, Total EPA 200.7 3/5/10 9:10 22-293 319 mg/L 30.0 mg/L Boron EPA 200.7 2/26/10 14:48 AML 17.4 mg/l 0.02 mg/l Antimony EPA 200.7 3/10/10 14:01 AML <1.0 mg/L 0.001 mg/L Silicon, Total EPA 200.7 3/3/10 11:07 22-293 10.0 mg/L 10.0 mg/L Bromide EPA 300.1 2/24/10 12:53 AML 2360.0 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/26/10 13:43 AML 87,259 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/23/10 15:14 WEH 32 /ml 1 /ml

Page 5 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Total Coliform SM 9223B 2/23/10 15:14 WEH 0 /100 mls 0 /100 mls E Coli SM 9223B 2/23/10 15:14 WEH NA +/- Specific Conductance EPA 120.1 2/23/10 0:00 WEH

234,000 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 3/1/10 20:52 22-293 ND 500 ug/L Diesel Range Organics C10-C28 SW846 8015D 2/28/10 1:53 22-293 1.0 mg/L 0.15 mg/L Methane RSK 175 2/26/10 20:39 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 2/25/10 2:54 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/25/10 8:31 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/25/10 8:31 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/25/10 8:31 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 2/27/10 11:00 22-293 42.3 mg/L 1.0 mg/L Formaldehyde SW846 8015D 3/4/10 17:41 22-293 34.5 mg/L 1.0 mg/L Acetone SW846 8260B 3/1/10 7:00 22-293 978 ug/L 10.0 ug/L

Page 6 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Silica, Dissolved SM20-4500SiD 3/2/10 0:15 22-293 15 mg/L 1 mg/L 2-Hexanone SW846 8260B 3/1/10 7:00 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 3/1/10 7:00 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 3/1/10 7:00 22-293 74.0 ug/L 10.0 ug/L Ethene RSK 175 2/26/10 20:39 22-293 ND 3.0 ug/L Methanol SW846 8015D 3/7/10 20:54 22-293 11.3 mg/L 1.0 mg/L o-Xylene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 3/1/10 7:00 22-293 3.3 ug/L 2.0 ug/L Chloromethane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Ethane RSK 175 2/26/10 20:39 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Chloroform SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L

Page 7 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Bromomethane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Bromide EPA 300 3/2/10 6:42 22-293 2000 mg/L 1000 mg/L Bromochlorometha ne SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 3/1/10 7:00 22-293 ND 7.0 ug/L 1,2-Dibromoethan e SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachloro ethane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,2-Dichloropropan e SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L

Page 8 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Chlorobenzene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Styrene SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L Toluene SW846 8260B 3/1/10 7:00 22-293 3.0 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L

Page 9 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100762 Altela

NETL Ross PW Resutant CW N/A 02/18/10 17:25 02/23/10 11:03 N/A Grab

Vinyl Chloride SW846 8260B 3/1/10 7:00 22-293 24.8 ug/L 1.0 ug/L Total Xylenes SW846 8260B 3/1/10 7:00 22-293 4.1 ug/L 3.0 ug/L Vanadium, Total EPA 200.7 3/5/10 9:10 22-293 ND 1.5 mg/L Bromoform SW846 8260B 3/1/10 7:00 22-293 ND 1.0 ug/L 

## Sample Comments: BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Page 10 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #02100 763 PRODUCED WATER TEST - BENCH DISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Thorium 232 HSL-300m 3/18/10 13:35 6502103 0.000 pCi/L pCi/L Copper EPA 200.7 2/26/10 14:16 AML <0.02 mg/l 0.02 mg/l Thorium 228 HSL-300M 3/18/10 13:32 6502103 0.177 pCi/L pCi/L Thorium 230 HSL-300m 3/18/10 13:34 6502103 0.400 pCi/L pCi/L Benzene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L pH SM4500 H+B 2/24/10 15:21 AML 8.58 SU SU Total Dissolved Solids SM 2540 C 2/23/10 11:49 RCS 88 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/23/10 13:00 RCS <3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/26/10 12:40 NJD 2.9 mg/l 5 mg/l BOD SM5210B 2/24/10 10:35 TO > 75.3 2 mg/L COD HACH 8000 3/10/10 7:22 NJD 185 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/24/10 21:45 22-293 ND 0.025 mg/L Color 2/23/10 11:16 WEH < 5 pccu 5 pccu

Page 1 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Temperature (F), Field na 3/5/10 9:02 RCS NA deg F Osmotic Pressure PA DEP 2/25/10 6:00 22-293 27 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 2/25/10 8:42 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 2/25/10 9:40 WEH 6.99 mg/L .10 mg/L Nitrate EPA 300.0 2/24/10 12:52 AML <0.10 mg/l 0.10 mg/l Nitrite EPA 300.0 2/24/10 12:51 AML <0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/24/10 12:51 AML <0.20 mg/l 0.20 mg/l Acidity SM 2310 B 2/24/10 16:13 AML -18.0 mg/L 3 mg/L Alkalinity SM 2320 B 2/24/10 15:20 AML 30.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/25/10 10:46 AML 29.0 mg/L 5 mg/L Sulfate EPA 300.0 2/24/10 12:52 AML 3.1 mg/l 1 mg/l Chloride EPA 300.0 2/24/10 12:53 AML 45.1 mg/L 1 mg/L Fluoride EPA 300.0 2/24/10 12:52 AML 0.16 mg/l 0.20 mg/l

Page 2 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Calcium EPA 200.7 2/26/10 14:52 AML 5.12 mg/l 0.10 mg/l Iron EPA 200.7 2/26/10 14:26 AML <0.02 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 3/12/10 13:47 AML <0.02 mg/l 0.02 mg/l Magnesium EPA 200.7 2/26/10 14:52 AML 0.47 mg/l 0.10 mg/l Potassium EPA 200.7 2/26/10 14:53 AML 0.35 mg/l 0.10 mg/l Sodium EPA 200.7 2/26/10 14:56 AML 24.8 mg/l 0.10 mg/l Aluminum EPA 200.7 2/26/10 14:25 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/26/10 14:28 AML <0.10 mg/l 0.10 mg/l Beryllium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Cadmium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/26/10 14:49 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L

Page 3 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Manganese EPA 200.7 2/26/10 14:26 AML <0.02 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L Nickel EPA 200.7 2/26/10 14:51 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 3/10/10 13:58 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 3/10/10 13:57 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 3/1/10 14:34 22-293 0.70 mg/L 0.0025 mg/L Thallium EPA 200.7 3/10/10 14:59 AML <0.5 mg/L 0.001 mg/L Tin EPA 200.7 3/10/10 14:02 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Zinc EPA 200.7 2/26/10 14:49 AML <0.02 mg/l 0.02 mg/l Gross Alpha DW EPA 900 3/3/10 11:49 6502103 0.685 PCi/L 3 PCi/L Gross Beta DW EPA 900 3/3/10 11:49 6502103 0.429 PCi/L 4 PCi/L Radium 226 EPA 903.1 3/17/10 11:47 6502103 0.231 pCi/L .6 pCi/L

Page 4 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Radium 228 EPA 904.0 3/11/10 11:48 6502103 0.434 pCi/L .9 pCi/L Total Residual Chlorine HACH 8167 2/23/10 15:39 RCS <0.10 mg/L 0.10 mg/L Phenolics EPA 420.4 3/1/10 10:12 22-293 0.06 mg/L 0.01 mg/L Uranium SW846 6020A 3/8/10 14:54 22-293 ND 1.1 mg/L Mercury, Total EPA 245.1 3/1/10 12:02 22-293 ND 0.00050 mg/L Lead EPA 200.7 2/26/10 14:51 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 3/1/10 14:34 22-293 ND 0.050 mg/L Boron EPA 200.7 2/26/10 14:48 AML <0.02 mg/l 0.02 mg/l Antimony EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Silicon, Total EPA 200.7 3/3/10 11:11 22-293 0.20 mg/L 0.050 mg/L Bromide EPA 300.1 2/24/10 12:53 AML 0.40 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/26/10 13:43 AML 15 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/23/10 15:14 WEH 5400 /ml 1 /ml

Page 5 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Total Coliform SM 9223B 2/23/10 15:14 WEH 0 /100 mls 0 /100 mls E Coli SM 9223B 2/23/10 15:14 WEH NA +/- Specific Conductance EPA 120.1 2/23/10 0:00 WEH 211 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 2/27/10 0:36 22-293 ND 100 ug/L Diesel Range Organics C10-C28 SW846 8015D 2/28/10 3:52 22-293 0.53 mg/L 0.15 mg/L Methane RSK 175 2/26/10 20:54 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 2/25/10 3:15 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/25/10 8:40 22-293 9 mg/L 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/25/10 8:40 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/25/10 8:40 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 2/27/10 11:00 22-293 6.0 mg/L 1.0 mg/L Formaldehyde SW846 8015D 3/4/10 19:22 22-293 1870 mg/L 500 mg/L Acetone SW846 8260B 2/26/10 19:36 22-293 195 ug/L 10.0 ug/L

Page 6 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Silica, Dissolved SM20-4500SiD 3/2/10 0:15 22-293 ND 1 mg/L 2-Hexanone SW846 8260B 2/26/10 19:36 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/26/10 19:36 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 2/26/10 19:36 22-293 ND 10.0 ug/L Ethene RSK 175 2/26/10 20:54 22-293 ND 3.0 ug/L Methanol SW846 8015D 3/3/10 19:07 22-293 1030 mg/L 100 mg/L o-Xylene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 2/26/10 19:36 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Ethane RSK 175 2/26/10 20:54 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Chloroform SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L

Page 7 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Bromomethane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Carbon Disulfide SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Bromide EPA 300 2/25/10 9:03 22-293 0.43 mg/L 0.30 mg/L Bromochlorometha ne SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/26/10 19:36 22-293 ND 7.0 ug/L 1,2-Dibromoethan e SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachloro ethane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,2-Dichloropropan e SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L

Page 8 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Chlorobenzene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Tetrachloroethene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Styrene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Toluene SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L

Page 9 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100763 Altela

NETL Ross PW Resultant DW N/A 02/18/10 17:25 02/23/10 11:06 N/A Grab

Vinyl Chloride SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 2/26/10 19:36 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 3/1/10 14:34 22-293 ND 0.0025 mg/L Bromoform SW846 8260B 2/26/10 19:36 22-293 ND 1.0 ug/L 

## Sample Comments: BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Page 10 of 10 3/25/2010 3:52:06PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 2100809 FRAC WATER

TEST - BENCH CONCENTRATE WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Thorium 230 HSL-300m 3/18/10 13:34 6502103 0.554 pCi/L pCi/L Thorium 232 HSL-300m 3/18/10 13:35 6502103 0.111 pCi/L pCi/L Bromoform SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Copper EPA 200.7 2/26/10 14:16 AML 0.8 mg/l 0.02 mg/l Thorium 228 HSL-300M 3/18/10 13:32 6502103 2.07 pCi/L pCi/L pH SM4500 H+B 2/24/10 15:21 AML 7.58 SU SU Total Dissolved Solids SM 2540 C 2/26/10 12:55 RCS 52,504 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/25/10 14:00 RCS 338 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/26/10 12:40 NJD 6.4 mg/l 5 mg/l BOD SM5210B 2/25/10 9:38 TO 373 mg/L 2 mg/L COD HACH 8000 3/10/10 7:22 NJD 2275 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/25/10 23:00 22-293 0.395 mg/L 0.025 mg/L Color 2/24/10 11:47 WEH 150 pccu 5 pccu

Page 1 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Temperature (F), Field na 3/5/10 9:02 RCS NA deg F Osmotic Pressure PA DEP 2/26/10 6:50 22-293 1620 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 2/25/10 8:42 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 2/25/10 9:40 WEH 9.04 mg/L .10 mg/L Nitrate EPA 300.0 2/24/10 0:00 AML < 5.0 mg/l 0.10 mg/l Nitrite EPA 300.0 2/24/10 0:00 AML < 5 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/24/10 0:00 AML < 10 mg/l 0.20 mg/l Acidity SM 2310 B 2/24/10 16:13 AML 14.0 mg/L 3 mg/L Alkalinity SM 2320 B 2/24/10 15:20 AML 160.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/25/10 10:46 AML 159.0 mg/L 5 mg/L Sulfate EPA 300.0 2/24/10 0:00 AML 240 mg/l 1 mg/l Chloride EPA 300.0 2/24/10 0:00 AML 32400 mg/L 1 mg/L Fluoride EPA 300.0 2/24/10 0:00 AML 15.5 mg/l 0.20 mg/l

Page 2 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Calcium EPA 200.7 2/26/10 14:52 AML 2540 mg/l 0.10 mg/l Iron EPA 200.7 2/26/10 14:26 AML 10.8 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 3/12/10 13:47 AML 11.1 mg/l 0.02 mg/l Magnesium EPA 200.7 2/26/10 14:52 AML 240.0 mg/l 0.10 mg/l Potassium EPA 200.7 2/26/10 14:53 AML 180.0 mg/l 0.10 mg/l Sodium EPA 200.7 2/26/10 14:53 AML 15,840 mg/l 0.10 mg/l Aluminum EPA 200.7 2/26/10 14:25 AML <2.0 mg/l 0.10 mg/l Arsenic EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/26/10 14:28 AML 25.4 mg/l 0.10 mg/l Beryllium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Cadmium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/26/10 14:49 AML <0.4 mg/l 0.02 mg/l Cobalt EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L

Page 3 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Manganese EPA 200.7 2/26/10 14:26 AML <0.4 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L Nickel EPA 200.7 2/26/10 14:51 AML <1.0 mg/l 0.05 mg/l Selenium EPA 200.7 3/10/10 13:58 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 3/10/10 13:57 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 3/4/10 14:10 22-293 305 mg/L 0.13 mg/L Thallium EPA 200.7 3/10/10 14:59 AML <0.5 mg/L 0.001 mg/L Tin EPA 200.7 3/10/10 14:02 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Zinc EPA 200.7 2/26/10 14:49 AML <0.4 mg/l 0.02 mg/l Gross Alpha DW EPA 900 3/3/10 11:53 6502103 -92.601 PCi/L 3 PCi/L Gross Beta DW EPA 900 3/3/10 11:53 6502103 2.46 PCi/L 4 PCi/L Radium 226 EPA 903.1 3/17/10 11:54 6502103 86.2 pCi/L .6 pCi/L

Page 4 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Radium 228 EPA 904.0 3/11/10 11:54 6502103 16.9 pCi/L .9 pCi/L Phenolics EPA 420.4 3/1/10 11:26 22-293 0.06 mg/L 0.01 mg/L Uranium SW846 6020A 3/3/10 21:46 22-293 ND 0.050 mg/L Mercury, Total EPA 245.1 3/1/10 12:03 22-293 ND 0.00050 mg/L Lead EPA 200.7 2/26/10 14:51 AML <0.4 mg/L 0.02 mg/L Lithium, Total EPA 200.7 3/4/10 14:10 22-293 32.0 mg/L 2.5 mg/L Boron EPA 200.7 2/26/10 14:48 AML 10.0 mg/l 0.02 mg/l Antimony EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Silicon, Total EPA 200.7 3/3/10 11:34 22-293 22.1 mg/L 2.5 mg/L Bromide EPA 300.1 2/24/10 0:00 AML 467.5 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/26/10 13:43 AML 7331 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/24/10 15:30 WEH 58000 /ml 1 /ml Total Coliform SM 9223B 2/24/10 15:50 WEH 0 /100 mls 0 /100 mls

Page 5 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

E Coli SM 9223B 2/24/10 15:50 WEH NA +/- Specific Conductance EPA 120.1 2/26/10 0:00 TO 76,600 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 3/4/10 1:55 22-293 2560 ug/L 2500 ug/L Diesel Range Organics C10-C28 SW846 8015D 3/3/10 10:17 22-293 3.5 mg/L 0.76 mg/L Methane RSK 175 2/26/10 21:12 22-293 5.5 ug/L 1.0 ug/L Ethylene Glycol SW846 8015D 3/5/10 20:01 22-293 33.2 mg/L 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/26/10 11:22 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/26/10 11:22 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/26/10 11:22 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 3/1/10 19:44 22-293 5.4 mg/L 1.0 mg/L Formaldehyde SW846 8015D 3/4/10 18:02 22-293 ND 1.0 mg/L Acetone SW846 8260B 2/26/10 21:08 22-293 1850 ug/L 50.0 ug/L Silica, Dissolved SM20-4500SiD 3/2/10 0:15 22-293 142 mg/L 10 mg/L

Page 6 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

2-Hexanone SW846 8260B 2/26/10 21:08 22-293 ND 25.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/26/10 21:08 22-293 ND 25.0 ug/L 2-Butanone SW846 8260B 2/26/10 21:08 22-293 ND 50.0 ug/L Ethene RSK 175 2/26/10 21:12 22-293 ND 3.0 ug/L Methanol SW846 8015D 9/8/10 21:51 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 2/26/10 21:08 22-293 6.4 ug/L 5.0 ug/L mp-Xylene SW846 8260B 2/26/10 21:08 22-293 34.2 ug/L 10.0 ug/L Chloromethane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Ethane RSK 175 2/26/10 21:12 22-293 3.5 ug/L 3.0 ug/L Chlorodibromomet hane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Chloroethane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Chloroform SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Bromomethane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L

Page 7 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Carbon Disulfide SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Bromide EPA 300 2/26/10 5:06 22-293 425 mg/L 150 mg/L Bromochlorometha ne SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Bromodichloromet hane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/26/10 21:08 22-293 ND 35.0 ug/L 1,2-Dibromoethan e SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,1,2,2-Tetrachloro ethane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,1-Dichloroethane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,1-Dichloroethene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Methylene Chloride SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,2-Dichloropropan e SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Chlorobenzene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L

Page 8 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Tetrachloroethene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Trichloroethene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Benzene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Carbon Tetrachloride SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,2-Dichloroethane SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Ethylbenzene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Styrene SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Toluene SW846 8260B 2/26/10 21:08 22-293 11.8 ug/L 5.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L

Page 9 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100809 Altela

NETL Frac water Resultant CW N/A 02/22/10 14:45 02/24/10 10:20 N/A Grab

Vinyl Chloride SW846 8260B 2/26/10 21:08 22-293 ND 5.0 ug/L Total Xylenes SW846 8260B 2/26/10 21:08 22-293 40.6 ug/L 15.0 ug/L Vanadium, Total EPA 200.7 3/4/10 14:10 22-293 ND 0.13 mg/L 

## Sample Comments: BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Page 10 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 2100810 FRAC WATER

TEST - BENCH DISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Thorium 230 HSL-300m 3/18/10 13:34 6502103 0.244 pCi/L pCi/L Thorium 232 HSL-300m 3/18/10 13:35 6502103 0.027 pCi/L pCi/L Bromoform SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Copper EPA 200.7 2/26/10 14:16 AML <0.02 mg/l 0.02 mg/l Thorium 228 HSL-300M 3/18/10 13:32 6502103 0.236 pCi/L pCi/L pH SM4500 H+B 2/24/10 15:21 AML 9.22 SU SU Total Dissolved Solids SM 2540 C 2/26/10 12:55 RCS 198 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/25/10 14:00 RCS <3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/26/10 12:40 NJD 1.3 mg/l 5 mg/l BOD SM5210B 2/25/10 9:38 TO 74.3 mg/L 2 mg/L COD HACH 8000 3/10/10 7:22 NJD 194 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/25/10 23:00 22-293 ND 0.025 mg/L Color 2/24/10 11:47 WEH < 5 pccu 5 pccu

Page 1 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Temperature (F), Field na 3/5/10 9:02 RCS NA deg F Osmotic Pressure PA DEP 2/26/10 6:50 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 2/25/10 8:42 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 2/25/10 9:40 WEH 8.22 mg/L .10 mg/L Nitrate EPA 300.0 2/24/10 0:00 AML < 0.10 mg/l 0.10 mg/l Nitrite EPA 300.0 2/24/10 0:00 AML < 0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/24/10 0:00 AML < 0.20 mg/l 0.20 mg/l Acidity SM 2310 B 2/24/10 16:13 AML -118.0 mg/L 3 mg/L Alkalinity SM 2320 B 2/24/10 15:20 AML 38.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/25/10 10:46 AML 32.0 mg/L 5 mg/L Sulfate EPA 300.0 2/24/10 0:00 AML 2.4 mg/l 1 mg/l Chloride EPA 300.0 2/24/10 0:00 AML 23.2 mg/L 1 mg/L Fluoride EPA 300.0 2/24/10 0:00 AML 0.14 mg/l 0.20 mg/l

Page 2 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Calcium EPA 200.7 2/26/10 14:52 AML 1.91 mg/l 0.10 mg/l Iron EPA 200.7 2/26/10 14:26 AML <0.02 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 3/12/10 13:47 AML 0.04 mg/l 0.02 mg/l Magnesium EPA 200.7 2/26/10 14:52 AML 0.17 mg/l 0.10 mg/l Potassium EPA 200.7 2/26/10 14:53 AML 0.14 mg/l 0.10 mg/l Sodium EPA 200.7 2/26/10 14:56 AML 14.3 mg/l 0.10 mg/l Aluminum EPA 200.7 2/26/10 14:25 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/26/10 14:28 AML <0.10 mg/l 0.10 mg/l Beryllium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Cadmium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/26/10 14:49 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L

Page 3 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Manganese EPA 200.7 2/26/10 14:26 AML <0.02 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L Nickel EPA 200.7 2/26/10 14:51 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 3/10/10 13:58 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 3/10/10 13:57 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 3/1/10 19:48 22-293 0.23 mg/L 0.0025 mg/L Thallium EPA 200.7 3/10/10 14:59 AML <0.5 mg/L 0.001 mg/L Tin EPA 200.7 3/10/10 14:02 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Zinc EPA 200.7 2/26/10 14:49 AML <0.02 mg/l 0.02 mg/l Gross Alpha DW EPA 900 3/3/10 11:53 6502103 -0.127 PCi/L 3 PCi/L Gross Beta DW EPA 900 3/3/10 11:53 6502103 0.481 PCi/L 4 PCi/L Radium 226 EPA 903.1 3/17/10 11:54 6502103 0.144 pCi/L .6 pCi/L

Page 4 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Radium 228 EPA 904.0 3/11/10 11:54 6502103 0.238 pCi/L .9 pCi/L Phenolics EPA 420.4 3/1/10 11:27 22-293 0.06 mg/L 0.01 mg/L Uranium SW846 6020A 3/3/10 21:17 22-293 ND 0.0050 mg/L Mercury, Total EPA 245.1 3/1/10 12:04 22-293 ND 0.00050 mg/L Lead EPA 200.7 2/26/10 14:51 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 3/1/10 19:48 22-293 ND 0.050 mg/L Boron EPA 200.7 2/26/10 14:48 AML <0.02 mg/l 0.02 mg/l Antimony EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Silicon, Total EPA 200.7 3/3/10 11:55 22-293 0.12 mg/L 0.050 mg/L Bromide EPA 300.1 2/24/10 0:00 AML 0.23 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/26/10 13:43 AML <10 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/24/10 15:30 WEH 5000 /ml 1 /ml Total Coliform SM 9223B 2/24/10 15:50 WEH 0 /100 mls 0 /100 mls

Page 5 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

E Coli SM 9223B 2/24/10 15:50 WEH NA +/- Specific Conductance EPA 120.1 2/26/10 0:00 TO 130 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 3/2/10 5:54 22-293 266 ug/L 100 ug/L Diesel Range Organics C10-C28 SW846 8015D 3/2/10 19:28 22-293 1.4 mg/L 0.15 mg/L Methane RSK 175 3/2/10 14:54 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 3/5/10 20:21 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/26/10 11:30 22-293 15 mg/L 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/26/10 11:30 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/26/10 11:30 22-293 7 mg/L 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 3/2/10 12:30 22-293 7.2 mg/L 1.0 mg/L Formaldehyde SW846 8015D 3/4/10 18:14 22-293 71.4 mg/L 1.0 mg/L Acetone SW846 8260B 2/26/10 20:37 22-293 985 ug/L 10.0 ug/L Silica, Dissolved SM20-4500SiD 3/2/10 0:15 22-293 ND 1 mg/L

Page 6 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

2-Hexanone SW846 8260B 2/26/10 20:37 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 2/26/10 20:37 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 2/26/10 20:37 22-293 ND 10.0 ug/L Ethene RSK 175 3/2/10 14:54 22-293 ND 3.0 ug/L Methanol SW846 8015D 9/8/10 22:07 22-293 22.3 mg/L 1.0 mg/L o-Xylene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 2/26/10 20:37 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Ethane RSK 175 3/2/10 14:54 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Chloroform SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L

Page 7 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Carbon Disulfide SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Bromide EPA 300 2/26/10 5:21 22-293 0.21 mg/L 0.10 mg/L Bromochlorometha ne SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 2/26/10 20:37 22-293 ND 7.0 ug/L 1,2-Dibromoethan e SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachloro ethane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,2-Dichloropropan e SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L

Page 8 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Tetrachloroethene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Benzene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Styrene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Toluene SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L

Page 9 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100810 Altela

NETL Frac Water Resultant DW N/A 02/22/10 14:45 02/24/10 10:21 N/A Grab

Vinyl Chloride SW846 8260B 2/26/10 20:37 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 2/26/10 20:37 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 3/1/10 19:48 22-293 ND 0.0025 mg/L 

## Sample Comments: BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Page 10 of 10 3/25/2010 3:53:35PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 21008 64 FRAC FLOW - BACK WATER TEST - BENCH CONCENTRATE WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Thorium 228 HSL-300M 3/19/10 13:35 6502103 5.31 pCi/L pCi/L Thorium 230 HSL-300m 3/19/10 13:36 6502103 0.635 pCi/L pCi/L Thorium 232 HSL-300m 3/19/10 13:36 6502103 0.276 pCi/L pCi/L Copper EPA 200.7 2/26/10 14:16 AML 0.8 mg/l 0.02 mg/l Bromoform SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L pH SM4500 H+B 2/25/10 15:10 AML 6.90 SU SU Total Dissolved Solids SM 2540 C 2/26/10 12:55 RCS 113,460 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/25/10 14:00 RCS 32 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/26/10 12:40 NJD 1.4 mg/l 5 mg/l BOD SM5210B 2/26/10 9:13 TO > 379 2 mg/L COD HACH 8000 3/10/10 7:22 NJD 1040 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/26/10 21:45 22-293 0.184 mg/L 0.025 mg/L Color 2/25/10 11:36 WEH 250 pccu 5 pccu

Page 1 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Temperature (F), Field na 3/5/10 9:02 RCS NA deg F Osmotic Pressure PA DEP 2/27/10 4:35 22-293 3440 mOs/kg 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 3/3/10 13:51 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 3/4/10 14:58 WEH 28.2 mg/L .10 mg/L Nitrate EPA 300.0 2/26/10 10:43 AML <5.0 mg/l 0.10 mg/l Nitrite EPA 300.0 2/26/10 10:44 AML <5.0 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/26/10 10:43 AML <10.0 mg/l 0.20 mg/l Acidity SM 2310 B 2/25/10 15:09 AML 50.0 mg/L 3 mg/L Alkalinity SM 2320 B 2/25/10 15:10 AML 148.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/25/10 10:46 AML 148.0 mg/L 5 mg/L Sulfate EPA 300.0 2/26/10 10:45 AML 275.0 mg/l 1 mg/l Chloride EPA 300.0 2/26/10 10:42 AML 64,800 mg/L 1 mg/L Fluoride EPA 300.0 2/26/10 10:45 AML 12.0 mg/l 0.20 mg/l

Page 2 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Calcium EPA 200.7 2/26/10 14:52 AML 6780 mg/l 0.10 mg/l Iron EPA 200.7 2/26/10 14:26 AML 16.6 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 3/12/10 13:47 AML 16.7 mg/l 0.02 mg/l Magnesium EPA 200.7 2/26/10 14:52 AML 660.0 mg/l 0.10 mg/l Potassium EPA 200.7 2/26/10 14:53 AML 360.0 mg/l 0.10 mg/l Sodium EPA 200.7 2/26/10 14:53 AML 32,200 mg/l 0.10 mg/l Aluminum EPA 200.7 2/26/10 14:25 AML <2.0 mg/l 0.10 mg/l Arsenic EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/26/10 14:28 AML 45.4 mg/l 0.10 mg/l Beryllium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Cadmium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/26/10 14:49 AML <0.4 mg/l 0.02 mg/l Cobalt EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L

Page 3 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Manganese EPA 200.7 2/26/10 14:26 AML 2.6 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L Nickel EPA 200.7 2/26/10 14:51 AML <1.0 mg/l 0.05 mg/l Selenium EPA 200.7 3/10/10 13:58 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 3/10/10 13:57 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 3/4/10 10:25 22-293 788 mg/L 0.25 mg/L Thallium EPA 200.7 3/10/10 14:59 AML <0.5 mg/L 0.001 mg/L Tin EPA 200.7 3/10/10 14:02 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Zinc EPA 200.7 2/26/10 14:49 AML <0.4 mg/l 0.02 mg/l Gross Alpha DW EPA 900 3/3/10 11:56 6502103 15.8 PCi/L 3 PCi/L Gross Beta DW EPA 900 3/3/10 11:57 6502103 86.5 PCi/L 4 PCi/L Radium 226 EPA 903.1 3/17/10 11:58 6502103 46.6 pCi/L .6 pCi/L

Page 4 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Radium 228 EPA 904.0 3/18/10 11:58 6502103 17.9 pCi/L .9 pCi/L Phenolics EPA 420.4 3/1/10 11:48 22-293 0.02 mg/L 0.01 mg/L Uranium SW846 6020A 3/3/10 21:56 22-293 ND 0.050 mg/L Mercury, Total EPA 200.8 3/4/10 8:29 22-293 ND 0.010 mg/L Lead EPA 200.7 2/26/10 14:51 AML <0.4 mg/L 0.02 mg/L Lithium, Total EPA 200.7 3/4/10 10:25 22-293 66.1 mg/L 5.0 mg/L Boron EPA 200.7 2/26/10 14:48 AML 17.0 mg/l 0.02 mg/l Antimony EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Silicon, Total EPA 200.7 3/3/10 11:59 22-293 26.6 mg/L 5.0 mg/L Bromide EPA 300.1 2/26/10 10:44 AML 995.0 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/26/10 13:43 AML 19,648 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/25/10 15:37 WEH 8,200 /ml 1 /ml Total Coliform SM 9223B 2/25/10 15:35 WEH 0 /100 mls 0 /100 mls

Page 5 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

E Coli SM 9223B 2/25/10 15:35 WEH NA +/- Specific Conductance EPA 120.1 2/26/10 0:00 TO

143,500 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 3/4/10 1:21 22-293 2850 ug/L 2500 ug/L Diesel Range Organics C10-C28 SW846 8015D 3/3/10 11:16 22-293 5.1 mg/L 0.75 mg/L Methane RSK 175 3/2/10 15:10 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 3/6/10 1:13 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/27/10 7:14 22-293 ND 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/27/10 7:14 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/27/10 7:14 22-293 ND 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 3/8/10 11:20 22-293 47.0 mg/L 4.0 mg/L Formaldehyde SW846 8015D 3/4/10 18:25 22-293 ND 1.0 mg/L Acetone SW846 8260B 3/1/10 23:39 22-293 661 ug/L 10.0 ug/L Silica, Dissolved SM20-4500SiD 3/2/10 0:15 22-293 14 mg/L 1 mg/L

Page 6 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

2-Hexanone SW846 8260B 3/1/10 23:39 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 3/1/10 23:39 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 3/1/10 23:39 22-293 46.6 ug/L 10.0 ug/L Ethene RSK 175 3/2/10 15:10 22-293 ND 3.0 ug/L Methanol SW846 8015D 9/8/10 22:22 22-293 ND 1.0 mg/L o-Xylene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 3/1/10 23:39 22-293 3.5 ug/L 2.0 ug/L Chloromethane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Ethane RSK 175 3/2/10 15:10 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Chloroform SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L

Page 7 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Carbon Disulfide SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Bromide EPA 300 2/27/10 9:17 22-293 825 mg/L 150 mg/L Bromochlorometha ne SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 3/1/10 23:39 22-293 ND 7.0 ug/L 1,2-Dibromoethan e SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachloro ethane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,2-Dichloropropan e SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L

Page 8 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Tetrachloroethene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Benzene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Styrene SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Toluene SW846 8260B 3/1/10 23:39 22-293 1.3 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L

Page 9 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100864 Altela

NETL Flowback Water Resultant CW N/A 02/23/10 17:55 02/25/10 11:10 N/A Grab

Vinyl Chloride SW846 8260B 3/1/10 23:39 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 3/1/10 23:39 22-293 4.3 ug/L 3.0 ug/L Vanadium, Total EPA 200.7 3/4/10 10:25 22-293 ND 0.25 mg/L 

## Sample Comments: None

Page 10 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

# WATER QUALITY REPORT #0 21008 65 FRAC FLOW - BACK WATER TEST - BENCH DISTILLED WATER

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Thorium 228 HSL-300M 3/18/10 13:35 6502103 0.143 pCi/L pCi/L Thorium 230 HSL-300m 3/18/10 13:36 6502103 0.126 pCi/L pCi/L Thorium 232 HSL-300m 3/18/10 13:37 6502103 0.000 pCi/L pCi/L Copper EPA 200.7 2/26/10 14:16 AML <0.02 mg/l 0.02 mg/l Bromoform SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L pH SM4500 H+B 2/25/10 15:10 AML 9.94 SU SU Total Dissolved Solids SM 2540 C 2/26/10 12:55 RCS 76 mg/l 5 mg/l Total Suspended Solids SM 2540 D 2/25/10 14:00 RCS <3 mg/L 3 mg/L Oil & Grease EPA 1664 Rev A 2/26/10 12:40 NJD 1.2 mg/l 5 mg/l BOD SM5210B 2/26/10 9:13 TO > 75.3 2 mg/L COD HACH 8000 3/10/10 7:22 NJD 410 mg/L 10 mg/L Surfactants (MBAS) SM20-5540 C 2/26/10 21:45 22-293 ND 0.025 mg/L Color 2/25/10 11:36 WEH < 5 pccu 5 pccu

Page 1 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Temperature (F), Field na 3/5/10 9:02 RCS NA deg F Osmotic Pressure PA DEP 2/27/10 4:35 22-293 ND 10 mOs/kg Ammonia Distillation SM 4500 NH3 B 3/3/10 13:51 WEH Completed mg/L Ammonia Nitrogen SM 4500 NH3 D 3/4/10 14:58 WEH 9.64 mg/L .10 mg/L Nitrate EPA 300.0 2/26/10 10:43 AML 0.19 mg/l 0.10 mg/l Nitrite EPA 300.0 2/26/10 10:44 AML <0.10 mg/l 0.10 mg/l Nitrate / Nitrite EPA 300.0 2/26/10 10:43 AML 0.29 mg/l 0.20 mg/l Acidity SM 2310 B 2/25/10 15:09 AML - 22.0 mg/L 3 mg/L Alkalinity SM 2320 B 2/25/10 15:10 AML 48.0 mg/l 5 mg/l Bicarbonate SM4500 CO2 D 2/25/10 10:46 AML 24.0 mg/L 5 mg/L Sulfate EPA 300.0 2/26/10 10:45 AML 2.2 mg/l 1 mg/l Chloride EPA 300.0 2/26/10 10:42 AML 35.4 mg/L 1 mg/L Fluoride EPA 300.0 2/26/10 10:45 AML 0.15 mg/l 0.20 mg/l

Page 2 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Calcium EPA 200.7 2/26/10 14:52 AML 3.81 mg/l 0.10 mg/l Iron EPA 200.7 2/26/10 14:26 AML <0.02 mg/l 0.02 mg/l Iron, Dissolved EPA 200.7 3/12/10 13:47 AML 0.02 mg/l 0.02 mg/l Magnesium EPA 200.7 2/26/10 14:52 AML 0.36 mg/l 0.10 mg/l Potassium EPA 200.7 2/26/10 14:53 AML 0.19 mg/l 0.10 mg/l Sodium EPA 200.7 2/26/10 14:56 AML 18.6 mg/l 0.10 mg/l Aluminum EPA 200.7 2/26/10 14:25 AML <0.10 mg/l 0.10 mg/l Arsenic EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Barium EPA 200.7 2/26/10 14:28 AML <0.10 mg/l 0.10 mg/l Beryllium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Cadmium EPA 200.7 3/10/10 14:00 AML <0.5 mg/L 0.001 mg/L Chromium EPA 200.7 2/26/10 14:49 AML <0.02 mg/l 0.02 mg/l Cobalt EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L

Page 3 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Manganese EPA 200.7 2/26/10 14:26 AML <0.02 mg/l 0.02 mg/l Molybdenum EPA 200.7 3/10/10 13:59 AML <0.5 mg/L 0.001 mg/L Nickel EPA 200.7 2/26/10 14:51 AML <0.05 mg/l 0.05 mg/l Selenium EPA 200.7 3/10/10 13:58 AML <0.5 mg/L 0.001 mg/L Silver EPA 200.7 3/10/10 13:57 AML <0.5 mg/L 0.001 mg/L Strontium, Total EPA 200.7 3/4/10 12:30 22-293 0.47 mg/L 0.0025 mg/L Thallium EPA 200.7 3/10/10 14:59 AML <0.5 mg/L 0.001 mg/L Tin EPA 200.7 3/10/10 14:02 AML <0.5 mg/L 0.001 mg/L Titanium EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Zinc EPA 200.7 2/26/10 14:49 AML 0.16 mg/l 0.02 mg/l Gross Alpha DW EPA 900 3/3/10 11:56 6502103 -0.125 PCi/L 3 PCi/L Gross Beta DW EPA 900 3/3/10 11:57 6502103 -0.088 PCi/L 4 PCi/L Radium 226 EPA 903.1 3/17/10 11:58 6502103 0.0917 pCi/L .6 pCi/L

Page 4 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Radium 228 EPA 904.0 3/11/10 11:59 6502103 -0.134 pCi/L .9 pCi/L Phenolics EPA 420.4 3/1/10 11:49 22-293 0.05 mg/L 0.01 mg/L Uranium SW846 6020A 3/3/10 21:37 22-293 ND 0.0050 mg/L Mercury, Total EPA 200.8 3/4/10 8:19 22-293 ND 0.0010 mg/L Lead EPA 200.7 2/26/10 14:51 AML <0.02 mg/L 0.02 mg/L Lithium, Total EPA 200.7 3/4/10 12:30 22-293 ND 0.050 mg/L Boron EPA 200.7 2/26/10 14:48 AML <0.02 mg/l 0.02 mg/l Antimony EPA 200.7 3/10/10 14:01 AML <0.5 mg/L 0.001 mg/L Silicon, Total EPA 200.7 3/3/10 12:04 22-293 0.089 mg/L 0.050 mg/L Bromide EPA 300.1 2/26/10 10:44 AML 0.40 mg/l 0.10 mg/l Hardness, Total EPA 200.7 2/26/10 13:43 AML 11 mg/l 10 mg/l Heterotrophic Plate Count SM 9215B 2/25/10 15:37 WEH 55,000 /ml 1 /ml Total Coliform SM 9223B 2/25/10 15:35 WEH 0 /100 mls 0 /100 mls

Page 5 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

E Coli SM 9223B 2/25/10 15:35 WEH NA +/- Specific Conductance EPA 120.1 2/26/10 0:00 TO 184 umhos/cm 2 umhos/cm Gasoline Range Organics SW846 8015D 3/2/10 5:19 22-293 154 ug/L 100 ug/L Diesel Range Organics C10-C28 SW846 8015D 3/2/10 22:31 22-293 1.7 mg/L 0.15 mg/L Methane RSK 175 2/26/10 21:26 22-293 ND 1.0 ug/L Ethylene Glycol SW846 8015D 3/6/10 1:34 22-293 ND 10.0 mg/L Alkalinity, Carbonate SM20-2322 2/27/10 7:22 22-293 20 mg/L 5 mg/L Alkalinity, Hydroxide SM20-2320 B 2/27/10 7:22 22-293 ND 5 mg/L Alkalinity, Phenolphthalein SM20-2320 B 2/27/10 7:22 22-293 10 mg/L 5 mg/L Total Kjeldahl Nitrogen SM20-4500-N C 3/3/10 14:00 22-293 9.8 mg/L 1.0 mg/L Formaldehyde SW846 8015D 3/4/10 18:37 22-293 41.4 mg/L 1.0 mg/L Acetone SW846 8260B 3/2/10 0:40 22-293 5230 ug/L 200 ug/L Silica, Dissolved SM20-4500SiD 3/2/10 0:15 22-293 ND 1 mg/L

Page 6 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

2-Hexanone SW846 8260B 3/1/10 12:09 22-293 ND 5.0 ug/L 4-Methyl-2-Pentan one(MIBK) SW846 8260B 3/1/10 12:09 22-293 ND 5.0 ug/L 2-Butanone SW846 8260B 3/1/10 12:09 22-293 ND 10.0 ug/L Ethene RSK 175 2/26/10 21:26 22-293 ND 3.0 ug/L Methanol SW846 8015D 9/8/10 22:37 22-293 27.4 mg/L 1.0 mg/L o-Xylene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L mp-Xylene SW846 8260B 3/1/10 12:09 22-293 ND 2.0 ug/L Chloromethane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Ethane RSK 175 2/26/10 21:26 22-293 ND 3.0 ug/L Chlorodibromomet hane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Chloroethane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Chloroform SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Bromomethane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L

Page 7 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Carbon Disulfide SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Bromide EPA 300 2/27/10 9:32 22-293 0.38 mg/L 0.30 mg/L Bromochlorometha ne SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Bromodichloromet hane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,2-Dibromo-3-chl oropropane SW846 8260B 3/1/10 12:09 22-293 ND 7.0 ug/L 1,2-Dibromoethan e SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,1,2,2-Tetrachloro ethane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,1-Dichloroethane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,1-Dichloroethene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L cis-1,2-Dichloroeth ene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Methylene Chloride SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,2-Dichloropropan e SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Chlorobenzene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L

Page 8 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Tetrachloroethene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Trichloroethene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L trans-1,2-Dichloroe thene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L trans-1,3-Dichlorop ropene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L cis-1,3-Dichloropro pene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Benzene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Carbon Tetrachloride SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,2-Dichloroethane SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Ethylbenzene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Styrene SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Toluene SW846 8260B 3/1/10 12:09 22-293 2.2 ug/L 1.0 ug/L 1,1,1-Trichloroetha ne SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L 1,1,2-Trichloroetha ne SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L

Page 9 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

.

## 11931 State Route 85 Kittanning, Pennsylvania 16201 724-543-3011 

# CWM Environmental

Lab Analysis Report Lab # 03-457



## Method Analysis Date Analyst Customer: Site: Collection Date: Received Date:



## Reporting Limit Result Monitoring Pt: Source Type: Matrix: Collection Method: 

## 02100865 Altela

NETL Flowback Water Resultant DW N/A 02/23/10 17:55 02/25/10 11:11 N/A Grab

Vinyl Chloride SW846 8260B 3/1/10 12:09 22-293 ND 1.0 ug/L Total Xylenes SW846 8260B 3/1/10 12:09 22-293 ND 3.0 ug/L Vanadium, Total EPA 200.7 3/4/10 12:30 22-293 ND 0.0025 mg/L 

## Sample Comments: None

Page 10 of 10 3/25/2010 3:54:21PM Printed: Confidential Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory ' s current NELAP scope of accreditation

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# APPENDIX E

MASS BALANCE ANALYSIS

# MASS BALANCE ANALYSIS OF FRAC WATER194.0054.00140.00Delta % DeltaGENERAL PARAMETERSAcidity mg/L -136.000 14.000 -18.000Hardness, Total mg/L 2621.000 7331.000 15.000 1927.12 1500.36 7.96 1508.32 418.80 21.73Calcium mg/L 915.000 2540.000 5.120 672.76 519.84 2.72 522.55 150.21 22.33Magnesium mg/L 81.600 240.000 0.470 60.00 49.12 0.25 49.37 10.63 17.72Alkalinity mg/L 230.000 160.000 30.000Bicarbonate mg/L 229.000 159.000 29.000 168.37 32.54 15.39 47.93 120.45 71.53Total Dissolved Solids mg/L 19630.000 52504.000 88.000 14433.15 10745.47 46.69 10792.16 3640.99 25.23Specific Conductance uS/CM 29400.000 76600.000 211.000Chloride mg/L 9500.000 32400.000 45.100 6984.97 6630.98 23.93 6654.91 330.06 4.73Distilled Water (DW); Lab #02100810 >Altela Mass Balance of Frac WaterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSCW + DWMass (g)ParametergalsRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)RW Mass(g)CW Mass (g) DW Mass (g)galsgalsRaw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >Fluoride mg/L 27.000 15.500 0.160 19.85 3.17 0.08 3.26 16.59 83.59Sodium mg/L 5250.000 15840.000 24.800 3860.12 3241.81 13.16 3254.97 605.14 15.68Total Suspended Solids mg/L 15.000 338.000 0.000 11.03 69.18 0.00 69.18 -58.15 -527.22Total Residual Chlorine mg/L < 0.100 0.000 0.000Ammonia Distillation mg/L 0.000 Completed CompletedAmmonia Nitrogen mg/L 0.000 9.040 6.990Total Kjeldahl Nitrogen 29.600 5.400 6.000 21.76 1.11 3.18 4.29 17.47 80.29BOD mg/L > 76.000 373.000 373.000COD mg/L 1253.000 2275.000 185.000E Coli NA NA NATotal Coliform /100 mls 0.000 0.000 0.000Heterotrophic Plate Count /ml 24600.000 58000.000 5400.000Color pccu 100.000 150.000 0.000MBAS mg/L 0.328 0.395 0.000pH SU 7.530 7.580 8.580Oil & Grease mg/L 3.200 6.400 2.900 2.35 1.31 1.54 2.85 -0.50 -21.07Osmotic Pressure mOs/KG 533.000 1620.000 27.000Temperature (F), Field deg F 71.000Gross Alpha DW pCi/L 27.000 0.000 0.685 19.85 0.00 0.36 0.36 19.49 98.17Gross Beta DW pCi/L 36.000 2.460 0.429 26.47 0.50 0.23 0.73 25.74 97.24194.0054.00140.00Delta % DeltaDistilled Water (DW); Lab #02100810 >Altela Mass Balance of Frac WaterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSCW + DWMass (g)ParametergalsRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)RW Mass(g)CW Mass (g) DW Mass (g)galsgalsRaw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >SPECIFIC IONSBarium mg/L 17.100 25.400 0.000 12.57 5.20 0.00 5.20 7.37 58.65Boron mg/L 4.400 10.000 0.000 3.24 2.05 0.00 2.05 1.19 36.74Bromide mg/L 141.000 467.500 0.430 103.67 95.68 0.23 95.91 7.76 7.49Bromide mg/L 150.000 467.500 0.430 110.29 95.68 0.23 95.91 14.38 13.04Cobalt mg/L 0.031 < 0.500 0.000 0.02 < 0.10 # 0.00 # 0.10 -0.08 -348.95Copper mg/L 0.460 0.800 0.000 0.34 0.16 0.00 0.16 0.17 51.59Iron mg/L 5.600 10.800 0.000 4.12 2.21 0.00 2.21 1.91 46.32Iron, Dissolved mg/L 4.200 11.100 0.000 3.09 2.27 0.00 2.27 0.82 26.44Lithium, Total mg/L 10.700 32.000 0.000 7.87 6.55 0.00 6.55 1.32 16.75Manganese mg/L 0.800 < 0.400 0.000 0.59 < 0.08 # 0.00 # 0.08 0.51 86.08M l bd/L0 0180 5000 0000 010 10#0 00#0 100 09673 20Molybdenum mg/L0.018<0.5000.0000.01<0.10#0.00#0.10-0.09-673.20Phenolics mg/L 0.050 0.060 0.060 0.04 0.01 0.03 0.04 -0.01 -20.00Potassium mg/L 55.300 180.000 0.350 40.66 36.84 0.19 37.02 3.64 8.94Radium 226 pCi/L 46.000 0.000 0.231 33.82 0.00 0.12 0.12 33.70 99.64Radium 228 pCi/L 17.000 0.000 0.434 12.50 0.00 0.23 0.23 12.27 98.16Silica, Dissolved mg/L 54.000 142.000 0.000 39.70 29.06 0.00 29.06 10.64 26.80Silicon, Total mg/L 6.700 22.100 0.200 4.93 4.52 0.11 4.63 0.30 6.03Strontium mg/L 97.500 305.000 0.700 71.69 62.42 0.37 62.79 8.90 12.41Sulfate mg/L 155.000 240.000 3.100 113.97 49.12 1.64 50.76 63.20 55.46ORGANICSAcetone mg/L 0.304 1.850 0.195 0.22 0.38 0.10 0.48 -0.26 -115.68Gasoline Range Organics mg/L 2.100 2.560 0.000 1.54 0.52 0.00 0.52 1.02 66.07Benzene mg/L 0.218 0.000 0.000 0.16 # 0.00 # 0.00 # 0.00 0.16 100.00mp-Xylene mg/L 0.048 0.034 0.000 0.03 0.01 0.00 0.01 0.03 79.96o-Xylene mg/L 0.019 0.006 0.000 0.01 0.00 0.00 0.00 0.01 90.52Total Xylenes mg/L 0.066 0.041 0.000 0.05 0.01 0.00 0.01 0.04 82.93Toluene mg/L 0.228 0.012 0.000 0.17 0.00 0.00 0.00 0.17 98.56Diesel Range Organic C10-C28 mg/L 28.400 3.500 0.530 20.88 0.72 0.28 1.00 19.88 95.22Ethane mg/L 0.140 0.004 0.000 0.10 0.00 0.00 0.00 0.10 99.30Formaldehyde mg/L 110.000 1.000 1.870 80.88 # 0.20 # 0.99 # 1.20 79.68 98.52Methane mg/L 0.848 0.006 0.000 0.62 0.00 0.00 0.00 0.62 99.82Methanol mg/L 50.100 0.000 1.030 36.84 # 0.00 # 0.55 # 0.55 36.29 98.52194.0054.00140.00Delta % DeltaDistilled Water (DW); Lab #02100810 >Altela Mass Balance of Frac WaterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSCW + DWMass (g)ParametergalsRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)RW Mass(g)CW Mass (g) DW Mass (g)galsgalsRaw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >CONSTITUENTS TESTED BELOW DETECTABLE LIMITS IN THE PRIMARY SOLUTION - NO MASS BALANCE CALCULATIONS PROVIDEDSPECIFIC IONSAlkalinity, Carbonate mg/L < 5.000 < 5.000 9.000Alkalinity, Hydroxide mg/L < 5.000 < 5.000 < 0.000Alkalinity, Phenolphthalein mg/L < 5.000 < 5.000 < 0.000Aluminum mg/L < 2.000 < 2.000 < 0.100Antimony mg/L < 0.500 < 0.500 < 0.500Arsenic mg/L < 0.500 < 0.500 < 0.500Beryllium mg/L < 0.500 < 0.500 < 0.100Cadmium mg/L < 0.500 < 0.500 < 0.500Chromium mg/L < 0.400 < 0.400 < 0.020Lead mg/L < 0.400 < 0.400 < 0.020Mercury mg/L < 0.002 < 0.002 < 0.002Nickel mg/L < 0.050 < 0.050 < 0.050Nitrate mg/L < 0.100 < 5.000 < 0.100Nitrate / Nitrite mg/L < 0.200 < 10.000 < 0.200Nitrite mg/L < 0.100 < 5.000 < 0.100Selenium mg/L < 0.500 < 0.500 < 0.500Silver mg/L < 0.500 < 0.500 < 0.500Thallium mg/L 0.015 < 0.500 0.000Tin mg/L < 0.500 < 0.500 < 0.500Titanium mg/L < 0.500 < 0.500 < 0.500Uranium mg/L < 0.100 < 0.050 < 0.000Vanadium mg/L < 0.063 < 0.130 < 0.130Vinyl Chloride mg/L < 0.005 < 0.005 < 0.005Zinc mg/L < 0.400 < 0.400 < 0.020ORGANICS1,1,1-Trichloroethane mg/L < 0.005 < 0.005 < 0.0051,1,2,2-Tetrachloroethane mg/L < 0.005 < 0.005 < 0.0051,1,2-Trichloroethane mg/L < 0.005 < 0.005 < 0.0051,1-Dichloroethane mg/L < 0.005 < 0.005 < 0.0051,1-Dichloroethene mg/L < 0.005 < 0.005 < 0.0051,2 Dibromoethane mg/L < 0.005 < 0.005 < 0.005194.0054.00140.00Delta % DeltaDistilled Water (DW); Lab #02100810 >Altela Mass Balance of Frac WaterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSCW + DWMass (g)ParametergalsRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)RW Mass(g)CW Mass (g) DW Mass (g)galsgalsRaw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >1,2-Dibromo-3-chloropropane mg/L < 0.035 < 0.035 < 0.0351,2-Dichloroethane mg/L < 0.005 < 0.005 < 0.0051,2-Dichloropropane mg/L < 0.005 < 0.005 < 0.0052-Butanone (MEK) mg/L < 0.050 < 0.050 < 0.0502-Hexanone mg/L < 0.025 < 0.025 < 0.0254-Methyl-2-Pentanone(MIBK) mg/L < 0.025 < 0.025 < 0.025Bromochloromethane mg/L < 0.005 < 0.005 < 0.005Bromodichloromethane mg/L < 0.005 < 0.005 < 0.005Bromoform mg/L < 0.005 < 0.005 < 0.005Bromomethane mg/L < 0.005 < 0.005 < 0.005Carbon Disulfide mg/L < 0.005 < 0.005 < 0.005C b T t hl id/L0 0050 0050 005CarbonTetrachloride mg/L<0.005<0.005<0.005Chlorobenzene mg/L < 0.005 < 0.005 < 0.005Chlorodibromomethane mg/L < 0.005 < 0.005 < 0.005Chloroethane mg/L < 0.005 < 0.005 < 0.005Chloroform mg/L < 0.005 < 0.005 < 0.005Chloromethane mg/L < 0.005 < 0.005 < 0.005cis-1,2-Dichloroethene mg/L < 0.005 < 0.005 < 0.005cis-1,3-Dichloropropene mg/L < 0.005 < 0.005 < 0.005Ethene mg/L < 0.030 < 0.030 < 0.030Ethylbenzene mg/L < 0.005 < 0.005 < 0.005Ethylene Glycol mg/L < 10.000 < 10.000 < 10.000Methylene Chloride mg/L < 0.005 < 0.005 < 0.005Styrene mg/L < 0.005 < 0.005 < 0.005Tetrachloroethene mg/L < 0.005 < 0.005 < 0.005trans-1,2-Dichloroethene mg/L < 0.005 < 0.005 < 0.005trans-1,3-Dichloropropene mg/L < 0.005 < 0.005 < 0.005Trichloroethene mg/L < 0.005 < 0.005 < 0.005

# MASS BALANCE ANALYSIS OF PRODUCED WATER211.0096.00115.00Delta % DeltaGENERAL PARAMETERSAcidity mg/L 404.000 236.000Hardness, Total mg/L 44431.000 87259.000 15.000 35531.03 31748.31 6.54 31754.85 3776.17 10.63Calcium mg/L 15460.000 29800.000 5.120 12363.21 10842.43 2.23 10844.66 1518.54 12.28Magnesium mg/L 1415.000 3120.000 0.470 1131.56 1135.18 0.20 1135.39 -3.82 -0.34Alkalinity mg/L 94.000 32.000Bicarbonate mg/L 94.000 32.000 29.000 75.17 11.64 12.64 24.28 50.89 67.70Total Dissolved Solids mg/L 195130.000 345680.000 88.000 156043.51 125772.21 38.35 125810.57 30232.94 19.37Specific Conductance uS/CM 194800.000 234000.000Chloride mg/L 108600.000 205200.000 45.100 86846.33 74659.97 19.66 74679.62 12166.71 14.01Fl id/L8 50010 5000 1606 803 820 073 892 9142 77DW Mass(g)CW + DWMass (g)Altela Mass Balance of Produced WaterRW Mass (g)DW Conc(mg/L)CW Conc(mg/L)RW Conc(mg/L)ParameterDistilled Water (DW); Lab #02100763 >Concentrate Water (CW); Lab #02100762 >Raw Water (RW); Lab #02100194 > galsgalsgalsCW Mass (g)CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSFluoride mg/L8.50010.5000.1606.803.820.073.892.9142.77Sodium mg/L 21200.000 85600.000 24.800 16953.43 31144.70 10.81 31155.51 -14202.09 -83.77Total Suspended Solids mg/L 403.000 176.000 < 0.000 322.28 64.04 0.00 64.04 258.24 80.13Total Residual Chlorine mg/L < 0.100 < 0.100Ammonia Distillation mg/L 0.000 Completed CompletedAmmonia Nitrogen mg/L 0.000 267.000 6.990Total Kjeldahl Nitrogen 17.000 42.300 6.000 13.59 15.39 2.62 18.01 -4.41 -32.44BOD mg/L > 77.900 62.700 > 75.300COD mg/L 6270.000 3800.000 185.000E Coli NA NA NATotal Coliform /100 mls 0.000 0.000 0.000Heterotrophic Plate Count /ml 21.000 32.000 5400.000Color pccu 150.000 20.000 0.000MBAS mg/L 0.344 0.184 < 0.000pH SU 6.170 5.960 8.580Oil & Grease mg/L 0.900 2.200 2.900 0.72 0.80 1.26 2.06 -1.34 -186.84Osmotic Pressure mOs/KG 2990.000 2970.000 27.000Temperature (F), Field deg F 40.000 NA NAGross Alpha DW pCi/L 3009.000 0.000 0.000Gross Beta DW pCi/L 416.000 0.000 0.000211.0096.00115.00Delta % DeltaDW Mass(g)CW + DWMass (g)Altela Mass Balance of Produced WaterRW Mass (g)DW Conc(mg/L)CW Conc(mg/L)RW Conc(mg/L)ParameterDistilled Water (DW); Lab #02100763 >Concentrate Water (CW); Lab #02100762 >Raw Water (RW); Lab #02100194 > galsgalsgalsCW Mass (g)CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSSPECIFIC IONSBarium mg/L 158.000 148.000 0.000 126.35 53.85 0.00 53.85 72.50 57.38Boron mg/L 11.000 17.400 0.000 8.80 6.33 0.00 6.33 2.47 28.03Bromide mg/L 1060.000 2360.000 0.400 847.67 858.66 0.17 858.84 -11.17 -1.32Bromide mg/L 1060.000 2360.000 0.400 847.67 858.66 0.17 858.84 -11.17 -1.32Cobalt mg/L 0.012 0.012 0.000 0.01 # 0.00 0.00 0.00 0.01 54.50Copper mg/L 0.800 2.000 0.000 0.64 0.73 0.00 0.73 -0.09 -13.74Iron mg/L 68.000 2.400 0.000 54.38 0.87 0.00 0.87 53.51 98.39Iron, Dissolved mg/L 16.000 0.400 0.000 12.80 # 0.15 0.00 0.15 12.65 98.86Lithium, Total mg/L 152.000 319.000 0.000 121.55 116.06 0.00 116.06 5.49 4.51Manganese mg/L 5.200 8.200 0.000 4.16 2.98 0.00 2.98 1.17 28.25Molybdenummg/L0 0030 0000 0000 00#0 000 000 000 00100 00Molybdenummg/L0.0030.0000.0000.00#0.000.000.000.00100.00Phenolics mg/L 0.070 0.010 0.060 0.06 # 0.00 0.03 0.03 0.03 46.78Potassium mg/L 465.000 1320.000 0.350 371.86 480.27 0.15 480.42 -108.57 -29.20Radium 226 pCi/L 1448.000 0.000 0.000 1157.95 0.00 0.00 0.00 1157.95 100.00Radium 228 pCi/L 715.000 0.000 0.000 571.78 0.00 0.00 0.00 571.78 100.00Silica, Dissolved mg/L 52.000 15.000 0.000 41.58 5.46 0.00 5.46 36.13 86.88Silicon, Total mg/L 7.000 10.000 0.200 5.60 3.64 0.09 3.73 1.87 33.45Strontium mg/L 2190.000 4970.000 0.700 1751.32 1808.28 0.31 1808.59 -57.27 -3.27Sulfate mg/L 130.000 550.000 3.100 103.96 200.11 1.35 201.46 -97.50 -93.79ORGANICSAcetone mg/L < 0.050 0.978 0.195 < 0.04 0.36 < 0.08 0.44 -0.40 -1002.49Gasoline Range Organics mg/L 6.690 < 0.500 < 0.100 5.35 < 0.18 0.04 0.23 5.12 95.78Benzene mg/L 756.000 1.200 0.000 604.57 0.44 0.00 0.44 604.13 99.93mp-Xylene mg/L 0.294 0.003 < 0.002 0.24 0.00 0.00 0.00 0.23 99.12o-Xylene mg/L 0.060 < 0.001 < 0.001 0.05 < 0.00 0.00 0.00 0.05 98.33Total Xylenes mg/L 0.354 0.004 < 0.003 0.28 0.00 0.00 0.00 0.28 99.01Toluene mg/L 0.984 0.003 < 0.001 0.79 0.00 0.00 0.00 0.79 99.81Diesel Range Organic C10-C28 mg/L 5.900 1.000 0.530 4.72 0.36 0.23 0.59 4.12 87.39Ethane mg/L 0.120 < 0.003 < 0.003 0.10 < 0.00 0.00 0.00 0.09 97.50Formaldehyde mg/L 9.890 0.035 1.870 7.91 0.01 0.82 0.83 7.08 89.54Methane mg/L 0.053 < 0.001 < 0.001 0.04 < 0.00 0.00 0.00 0.04 98.10Methanol mg/L 4330.000 11.300 1030.000 3462.66 4.11 448.93 453.04 3009.62 86.92211.0096.00115.00Delta % DeltaDW Mass(g)CW + DWMass (g)Altela Mass Balance of Produced WaterRW Mass (g)DW Conc(mg/L)CW Conc(mg/L)RW Conc(mg/L)ParameterDistilled Water (DW); Lab #02100763 >Concentrate Water (CW); Lab #02100762 >Raw Water (RW); Lab #02100194 > galsgalsgalsCW Mass (g)CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSCONSTITUENTS TESTED BELOW DETECTABLE LIMITS IN THE PRIMARY SOLUTION - NO MASS BALANCE CALCULATIONS PROVIDEDSPECIFIC IONSAlkalinity, Carbonate mg/L < 5.000 < 5.000 9.000Alkalinity, Hydroxide mg/L < 5.000 < 5.000 < 5.000Alkalinity, Phenolphthalein mg/L < 5.000 < 5.000 < 5.000Aluminum mg/L < 2.000 < 2.000 < 0.100Antimony mg/L < 0.500 < 1.000 < 0.500Arsenic mg/L < 0.500 < 1.000 < 0.500Beryllium mg/L < 0.500 < 1.000 < 0.500Cadmium mg/L 0.012 0.012 0.000Chromium mg/L < 0.400 < 0.400 < 0.020Leadmg/L<0 4000 0000 000Leadmg/L<0.4000.0000.000Mercury mg/L < 0.020 < 0.013 < 0.001Nickel mg/L < 1.000 < 1.000 < 0.050Nitrate mg/L < 5.000 < 5.000 < 0.100Nitrate / Nitrite mg/L < 10.000 < 10.000 < 0.200Nitrite mg/L < 5.000 < 5.000 < 0.100Selenium mg/L < 0.500 < 1.000 < 0.500Silver mg/L < 0.500 < 1.000 < 0.500Thallium mg/L 0.006 < 1.000 < 0.500Tin mg/L < 0.500 < 1.000 < 0.500Titanium mg/L 0.006 < 1.000 < 0.500Uranium mg/L < 1.000 < 1.100 < 1.100Vanadium mg/L < 0.250 < 1.500 < 0.003Vinyl Chloride mg/L < 0.005 < 0.001 < 0.001Zinc mg/L < 0.400 < 0.400 < 0.020ORGANICS1,1,1-Trichloroethane mg/L < 0.005 < 0.005 < 0.0011,1,2,2-Tetrachloroethane mg/L < 0.005 < 0.005 < 0.0011,1,2-Trichloroethane mg/L < 0.005 < 0.005 < 0.0011,1-Dichloroethane mg/L < 0.005 < 0.005 < 0.0011,1-Dichloroethene mg/L < 0.005 < 0.005 < 0.0011,2 Dibromoethane mg/L < 0.005 < 0.005 < 0.001211.0096.00115.00Delta % DeltaDW Mass(g)CW + DWMass (g)Altela Mass Balance of Produced WaterRW Mass (g)DW Conc(mg/L)CW Conc(mg/L)RW Conc(mg/L)ParameterDistilled Water (DW); Lab #02100763 >Concentrate Water (CW); Lab #02100762 >Raw Water (RW); Lab #02100194 > galsgalsgalsCW Mass (g)CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS1,2-Dibromo-3-chloropropane mg/L < 0.035 < 0.035 < 0.0071,2-Dichloroethane mg/L < 0.005 < 0.005 < 0.0011,2-Dichloropropane mg/L < 0.005 < 0.005 < 0.0012-Butanone (MEK) mg/L < 0.050 < 0.050 < 0.0102-Hexanone mg/L < 0.025 < 0.025 < 0.0054-Methyl-2-Pentanone(MIBK) mg/L < 0.025 < 0.025 < 0.005Bromochloromethane mg/L < 0.005 < 0.001 < 0.001Bromodichloromethane mg/L < 0.005 < 0.001 < 0.001Bromoform mg/L < 0.005 < 0.001 < 0.001Bromomethane mg/L < 0.005 < 0.001 < 0.001Carbon Disulfide mg/L < 0.005 < 0.001 < 0.001Carbon Tetrachloridemg/L<0 005<0 001<0 001CarbonTetrachloridemg/L<0.005<0.001<0.001Chlorobenzene mg/L < 0.005 < 0.001 < 0.001Chlorodibromomethane mg/L < 0.005 < 0.001 < 0.001Chloroethane mg/L < 0.005 < 0.001 < 0.001Chloroform mg/L < 0.005 < 0.001 < 0.001Chloromethane mg/L 0.011 < 0.001 < 0.001cis-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001cis-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Ethene mg/L < 0.030 < 0.003 < 0.003Ethylbenzene mg/L 0.027 < 0.001 < 0.001Ethylene Glycol mg/L < 10.000 < 10.000 < 10.000Methylene Chloride mg/L < 0.005 < 0.001 < 0.001Styrene mg/L < 0.005 < 0.001 < 0.001Tetrachloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Trichloroethene mg/L < 0.005 < 0.001 < 0.001

# MASS BALANCE ANALYSIS OF FRAC FLOW - BACK WATERRaw Water (RW); Lab #02100197; 194 galsConcentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 galsRW Mass(g)Delta % DeltaGENERAL PARAMETERSAcidity mg/L -114.000 50.000 -22.000 -83.82 10.23 -11.67 -1.44 -82.38 98.28Hardness, Total mg/L 7040.000 19648.000 11.000 5176.23 4021.16 5.84 4027.00 1149.23 22.20Calcium mg/L 2465.000 6780.000 3.810 1812.42 1387.59 2.02 1389.62 422.80 23.33Magnesium mg/L 215.000 660.000 0.360 158.08 135.08 0.19 135.27 22.81 14.43Alkalinity mg/L 196.000 148.000 48.000 144.11 30.29 25.47 55.76 88.35 61.31Bicarbonate mg/L 196.000 148.000 24.000 144.11 30.29 12.73 43.02 101.09 70.15Total Dissolved Solids mg/L 40530.000 113460.000 76.000 29800.09 23220.72 40.33 23261.05 6539.04 21.94Specific Conductance uS/CM 56700.000 143500.000 184.000 41689.24 29368.71 97.63 29466.34 12222.90 29.32Chloride mg/L 20100.000 64800.000 35.400 14778.73 13261.97 18.78 13280.75 1497.97 10.14/DW Mass(g)CW + DWMass (g)Altela Mass Balance of Frac Flow Back WaterRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)CW Mass(g)ParameterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSFluoride mg/L9.50012.0000.1506.982.460.082.544.4563.70Sodium mg/L 10380.000 32200.000 18.600 7632.00 6590.05 9.87 6599.92 1032.08 13.52Total Suspended Solids mg/L 22.000 32.000 < 3.000 16.18 6.55 < 1.59 8.14 8.03 49.67Total Residual Chlorine mg/L < 0.100 0.000 0.000Ammonia Distillation mg/L 0.000 Completed CompletedAmmonia Nitrogen mg/L 0.000 28.200 9.640Total Kjeldahl Nitrogen 9.200 47.000 9.800 6.76 9.62 5.20 14.82 -8.05 -119.07BOD mg/L > 74.200 > 379.000 > 75.300COD mg/L 1042.000 1040.000 410.000E Coli NA NA NATotal Coliform /100 mls 0.000 0.000 0.000Heterotrophic Plate Count /ml 4,810,0008200.000 55000.000Color pccu 125.000 250.000 < 5.000MBAS mg/L 0.239 0.184 < 0.025pH SU 7.390 6.900 9.940Oil & Grease mg/L 1.100 1.400 1.200 0.81 0.29 0.64 0.92 -0.11 -14.15Osmotic Pressure mOs/KG 1110.000 3440.000 < 10.000Temperature (F), Field deg F 74.000 NA NAGross Alpha DW pCi/L 76.400 0.000 0.000 56.17 0.00 0.00 0.00 56.17 100.00Gross Beta DW pCi/L 240.000 0.000 0.000 176.46 0.00 0.00 0.00 176.46 100.00Raw Water (RW); Lab #02100197; 194 galsConcentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 galsRW Mass(g)Delta % DeltaDW Mass(g)CW + DWMass (g)Altela Mass Balance of Frac Flow Back WaterRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)CW Mass(g)ParameterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSSPECIFIC IONSBarium mg/L 52.900 45.400 < 0.100 38.90 9.29 < 0.05 9.34 29.55 75.97Boron mg/L 6.400 17.000 < 0.020 4.71 3.48 < 0.01 3.49 1.22 25.84Bromide mg/L 270.000 995.000 0.400 198.52 203.64 0.21 203.85 -5.33 -2.68Bromide mg/L 291.000 995.000 0.400 213.96 203.64 0.21 203.85 10.11 4.73Cobalt mg/L 0.033 < 0.500 < 0.500 0.02 < 0.10 < 0.27 < 0.37 -0.34 -1415.15Copper mg/L 0.520 0.800 < 0.020 0.38 0.16 < 0.01 0.17 0.21 54.40Iron mg/L 8.400 16.600 < 0.020 6.18 3.40 < 0.01 3.41 2.77 44.82Iron, Dissolved mg/L 8.300 16.700 0.020 6.10 3.42 0.01 3.43 2.67 43.82Lithium, Total mg/L 21.500 66.100 < 0.050 15.81 13.53 < 0.03 13.55 2.25 14.26Manganese mg/L 2.000 2.600 < 0.020 1.47 0.53 < 0.01 0.54 0.93 63.09Molybdenummg/L0 016<0 500<0 5000 01<0 10<0 27<0 370 363025 00Molybdenummg/L0.016<0.500<0.5000.01<0.10<0.27<0.37-0.36-3025.00Phenolics mg/L 0.040 0.020 0.050 0.03 0.00 0.03 0.03 0.00 -4.12Potassium mg/L 94.800 360.000 0.190 69.70 73.68 0.10 73.78 -4.08 -5.85Radium 226 pCi/L 33.100 0.000 0.000 24.34 0.00 0.00 0.00 24.34 100.00Radium 228 pCi/L 27.300 0.000 0.000 20.07 0.00 0.00 0.00 20.07 100.00Silica, Dissolved mg/L 49.000 14.000 < 1.000 36.03 2.87 < 0.53 3.40 32.63 90.57Silicon, Total mg/L 9.200 26.600 0.089 6.76 5.44 0.05 5.49 1.27 18.82Strontium mg/L 265.000 788.000 0.470 194.84 161.27 0.25 161.52 33.32 17.10Sulfate mg/L 155.000 275.000 2.200 113.97 56.28 1.17 57.45 56.52 49.59ORGANICSAcetone mg/L 2.090 0.661 5.230 1.54 0.14 2.78 2.91 -1.37 -89.39Gasoline Range Organics mg/L 0.928 2.850 0.154 0.68 0.58 0.08 0.66 0.02 2.54Benzene mg/L 0.055 < 0.001 < 0.001 0.04 < 0.00 < 0.00 < 0.00 0.04 98.19mp-Xylene mg/L 0.027 0.004 < 0.002 0.02 0.00 < 0.00 0.00 0.02 91.05o-Xylene mg/L 0.009 < 0.001 < 0.001 0.01 < 0.00 < 0.00 < 0.00 0.01 88.76Total Xylenes mg/L 0.036 0.004 < 0.003 0.03 0.00 < 0.00 0.00 0.02 90.71Toluene mg/L 0.085 0.001 0.002 0.06 0.00 0.00 0.00 0.06 97.71Diesel Range Organic C10-C28 mg/L 17.400 5.100 1.700 12.79 1.04 0.90 1.95 10.85 84.79Ethane mg/L 0.133 < 0.003 < 0.003 0.10 < 0.00 < 0.00 < 0.00 0.10 97.74Formaldehyde mg/L 75.400 < 1.000 41.400 55.44 < 0.20 21.97 22.17 33.27 60.01Methane mg/L 0.390 < 0.001 < 0.001 0.29 < 0.00 < 0.00 < 0.00 0.29 99.74Methanol mg/L 35.200 < 0.001 0.027 25.88 < 0.00 0.01 0.01 25.87 99.94Raw Water (RW); Lab #02100197; 194 galsConcentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 galsRW Mass(g)Delta % DeltaDW Mass(g)CW + DWMass (g)Altela Mass Balance of Frac Flow Back WaterRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)CW Mass(g)ParameterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONSCONSTITUENTS TESTED BELOW DETECTABLE LIMITS IN THE PRIMARY SOLUTION - NO MASS BALANCE CALCULATIONS PROVIDEDSPECIFIC IONSAlkalinity, Carbonate mg/L < 5.000 < 5.000 20.000Alkalinity, Hydroxide mg/L < 5.000 < 5.000 < 5.000Alkalinity, Phenolphthalein mg/L < 5.000 < 5.000 10.000Aluminum mg/L < 2.000 < 2.000 < 0.100Antimony mg/L < 0.500 < 0.500 < 0.500Arsenic mg/L < 0.500 < 0.500 < 0.500Beryllium mg/L < 0.500 < 0.500 < 0.500Cadmium mg/L < 0.500 < 0.500 < 0.500Chromium mg/L < 0.400 < 0.400 < 0.020L d/L<0 4000 0000 000Leadmg/L<0.4000.0000.000Mercury mg/L < 0.005 < 0.010 < 0.001Nickel mg/L < 1.000 < 1.000 < 0.050Nitrate mg/L < 5.000 < 5.000 0.190Nitrate / Nitrite mg/L < 10.000 < 10.000 0.290Nitrite mg/L < 5.000 < 5.000 < 0.100Selenium mg/L < 0.500 < 0.500 < 0.500Silver mg/L < 0.500 < 0.500 < 0.500Thallium mg/L 0.009 < 0.500 < 0.500Tin mg/L < 0.500 < 0.500 < 0.500Titanium mg/L 0.009 < 0.500 < 0.500Uranium mg/L < 0.250 < 0.050 < 0.005Vanadium mg/L < 0.063 < 0.250 < 0.003Vinyl Chloride mg/L < 0.005 < 0.001 < 0.001Zinc mg/L < 0.400 < 0.400 0.160ORGANICS1,1,1-Trichloroethane mg/L < 0.005 < 0.001 < 0.0011,1,2,2-Tetrachloroethane mg/L < 0.005 < 0.001 < 0.0011,1,2-Trichloroethane mg/L < 0.005 < 0.001 < 0.0011,1-Dichloroethane mg/L < 0.005 < 0.001 < 0.0011,1-Dichloroethene mg/L < 0.005 < 0.001 < 0.0011,2 Dibromoethane mg/L < 0.005 < 0.001 < 0.001Raw Water (RW); Lab #02100197; 194 galsConcentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 galsRW Mass(g)Delta % DeltaDW Mass(g)CW + DWMass (g)Altela Mass Balance of Frac Flow Back WaterRW Conc(mg/L)CW Conc(mg/L)DW Conc(mg/L)CW Mass(g)ParameterCWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS1,2-Dibromo-3-chloropropane mg/L < 0.035 < 0.007 < 0.0071,2-Dichloroethane mg/L < 0.005 < 0.001 < 0.0011,2-Dichloropropane mg/L < 0.005 < 0.001 < 0.0012-Butanone (MEK) mg/L < 0.005 0.047 < 0.0102-Hexanone mg/L < 0.025 < 0.005 < 0.0054-Methyl-2-Pentanone(MIBK) mg/L < 0.025 < 0.005 < 0.005Bromochloromethane mg/L < 0.005 < 0.001 < 0.001Bromodichloromethane mg/L < 0.005 < 0.001 < 0.001Bromoform mg/L < 0.005 < 0.001 < 0.001Bromomethane mg/L < 0.005 < 0.001 < 0.001Carbon Disulfide mg/L < 0.005 < 0.001 < 0.001Carbon Tetrachloridemg/L<0 005<0 001<0 001CarbonTetrachloridemg/L<0.005<0.001<0.001Chlorobenzene mg/L < 0.005 < 0.001 < 0.001Chlorodibromomethane mg/L < 0.005 < 0.001 < 0.001Chloroethane mg/L < 0.005 < 0.001 < 0.001Chloroform mg/L < 0.005 < 0.001 < 0.001Chloromethane mg/L < 0.005 < 0.001 < 0.001cis-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001cis-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Ethene mg/L < 0.006 < 0.003 < 0.003Ethylbenzene mg/L < 0.005 < 0.001 < 0.001Ethylene Glycol mg/L < 0.010 < 0.010 < 0.010Methylene Chloride mg/L < 0.005 < 0.001 < 0.001Styrene mg/L < 0.005 < 0.001 < 0.001Tetrachloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Trichloroethene mg/L < 0.005 < 0.001 < 0.001

# APPENDIX F

NEW MEXICO OIL CONSERVATION DIVISION APPROVAL FOR MARCELLUS WATER

# APPENDIX G

PHOTOS OF SITE

# Sleepy Well Site

• Site location

– Laurel Run Rd, Penn Run, PA 15765

Produced Water Tanks Well Head

Altela Rain Treatment Trailer Treated Water and Brine Holding Tanks

Flowback Holding Pit

# The Well

The Wellhead, pressure ~1400 PSI Produced Water Holding Tanks Vents for NG, unflared

# Pressure Reduction and Water Separation

Series of control valves used to reduce pressure before feeding to the production pipeline
Series of tanks and valves used to reduce pressure and remove water

# Frac Flowback Holding Pit Pit, slightly frozen over and collecting rainwater Submersible pump feeding pipeline that feeds the treatment system

# Treatment System

Pipeline from flowback holding pit Treatment Trailer Concentrate Holding Tank

Treated Water Holding Tank Exhaust of hot, water saturated air

# Altela Rain Units

A row of units Pipes carrying saturated air from the system and tanks collecting treated water at the side Insulated Steam Pipe

# Steam Generation

Natural gas boiler to generate steam used to drive the system - Treated water holding tank

Treated water used as water source for steam generation

# Heat Exchanger

Blower drives air flow through heat exchanger Heat exchanger, constructed of same material as treatment towers, to pre
- heat inlet air and cool saturated outlet air (water condensing out of outlet air in heat exchanger is collected)

# Miscellaneous Equipment

Monitoring and Control system

Pump, pressure gauges , and meter in boiler room Valves controlling brine flow to treatment towers

Blower in boiler room Batch brine recirculation tank

# APPENDIX H

MISCELLANEOUS CHARTS AND GRAPHS

### As of 9/1/2010 10/1/2010 11/1/2010 12/1/2010 1/1/2011 2/1/2011 3/1/2011 3/31/2011 4/7/2011 Actual Treatment Rate (avg. BPD) 31.37 34.39 27.09 24.64 16.77 12.20 12.86 11.56 3.45 Normalized Treatment Rate (BPD) 44.82 40.19 32.58 29.65 24.01 26.26 23.58 23.31 24.83 Total Recovery Rate (%) 76.11 76.76 75.50 72.11 73.12 75.11 73.11 72.67 72.50 PW In (bbls) 1,236.31 1,344.05 1,112.26 1,059.29 710.83 503.69 545.36 477.38 33.33 CW Out (bbls) 283.33 312.38 272.50 295.48 191.07 125.36 146.67 130.48 9.17 DW Out (bbls) 263.93 253.69 121.31 114.40 48.93 46.19 71.19 44.52 4.88 Average PW Cond. 33,835 41,314 41,580 40,815 35,481 36,548 28,201 12,133 33,918 Average CW Cond. 60,519 73,804 70,761 72,001 63,251 64,418 49,249 21,480 58,341 Average DW Cond. 35 35 583 44 50 674 38 57 256 NETL DEMONSTRATION SYSTEM TREATMENT SUMMARY

### As of 7/29/2010 8/24/2010 8/25/2010 8/26/2010 8/27/2010 8/30/2010 8/31/2010 9/1/2010 9/2/2010 Actual Treatment Rate (avg. BPD) 19.55 38.10 46.55 45.00 42.98 41.67 38.93 38.45 45.00 Normalized Treatment Rate (BPD) 33.51 38.10 46.74 45.00 42.98 41.67 38.93 39.10 45.76 Total Recovery Rate (%) 94.94 75.47 76.37 76.38 76.48 76.42 75.69 76.18 77.78 PW In (bbls) 20.59 50.48 60.95 58.57 56.19 54.52 51.43 50.48 57.86 CW Out (bbls) 1.04 12.38 14.40 13.57 13.21 12.86 12.50 12.02 12.86 DW Out (bbls) 6.95 13.33 13.33 11.31 12.26 11.19 10.00 10.24 11.31 Average PW Cond. 31,450 32,390 33,290 35,980 38,130 38,950 39,040 39,210 39,179 Average CW Cond. 59,764 61,650 56,560 60,860 65,785 65,290 78,230 56,760 69,426 Average DW Cond. 90 32 32 34 36 35 31 32 41

### 9/3/2010 9/7/2010 9/8/2010 9/9/2010 9/10/2010 9/13/2010 9/14/2010 9/15/2010 9/16/2010 9/17/2010 9/20/2010 9/21/2010 41.07 0.00 31.19 25.24 44.17 40.71 42.98 39.29 39.17 39.40 39.29 36.19 41.24 0.00 43.50 43.58 44.17 40.71 42.98 39.29 39.17 39.90 39.29 36.19 76.16 0.00 76.61 76.26 77.29 76.17 78.48 76.74 76.51 76.80 76.92 76.96 53.93 0.00 40.71 33.10 57.14 53.45 54.76 51.19 51.19 51.31 51.07 47.02 12.86 0.00 9.52 7.86 12.98 12.74 11.79 11.90 12.02 11.90 11.79 10.83 10.12 0.00 6.90 8.21 12.98 11.31 11.31 10.00 9.05 10.36 8.81 7.74 39,464 40,385 40,502 40,530 40,930 41,325 41,396 41,549 41,806 41,967 41,992 42,060 69,975 84,169 72,756 73,168 72,656 73,398 73,215 73,756 74,516 74,570 74,898 74,939 30 30 34 38 38 33 33 34 33 34 34 34

### 9/22/2010 9/23/2010 9/24/2010 9/25/2010 9/27/2010 9/28/2010 9/29/2010 9/30/2010 10/1/2010 10/4/2010 10/5/2010 10/6/2010 39.05 10.60 29.29 37.98 33.81 25.71 29.64 34.17 30.60 32.38 29.40 26.31 40.75 40.36 40.16 37.98 33.81 37.63 38.46 40.20 39.91 32.38 29.40 29.10 73.10 72.95 76.64 76.13 76.14 76.33 77.81 76.94 76.72 77.94 78.41 78.09 51.31 14.52 38.21 49.88 44.40 33.69 38.10 44.40 39.88 41.55 37.50 33.69 12.26 3.93 8.93 11.90 10.60 7.98 8.45 10.24 9.29 9.17 8.10 7.38

8.33 3.21 5.95 8.21 8.21 4.76 5.95 7.26 6.55 2.26 1.07 0.24 41,963 42,024 42,006 41,960 42,099 41,953 41,997 41,612 41,430 41,432 41,521 41,601 74,149 64,210 72,150 75,077 75,735 74,583 75,179 74,319 57,360 74,149 74,720 74,322 35 34 37 35 39 38 38 40 38 36 34 33

### 10/7/2010 10/8/2010 10/11/2010 10/12/2010 10/13/2010 10/14/2010 10/15/2010 10/18/2010 10/19/2010 10/20/2010 10/21/2010 7.98 29.64 37.38 34.64 37.98 33.93 15.95 0.00 29.40 46.79 34.29 17.56 33.88 37.38 34.79 37.98 35.87 36.46 0.00 40.79 46.79 34.29 70.53 77.09 77.53 75.98 78.00 77.45 68.37 0.00 96.48 94.93 71.64 11.31 38.45 48.21 45.60 48.69 43.81 23.33 0.00 30.48 49.29 47.86

3.33 8.81 10.83 10.95 10.71 9.88 7.38 0.00 1.07 2.50 13.57 1.43 5.36 5.60 5.24 5.36 6.43 2.14 0.00 8.10 7.62 7.38 41,574 41,476 41,544 41,396 41,443 41,536 41,741 42,674 42,250 41,481 41,517 73,610 74,044 73,714 73,941 73,881 73,959 38,563 58,592 66,038 73,106 73,476 59 55 159 77 78 91 70 5,004 2,419 74 171

### 10/22/2010 10/25/2010 10/26/2010 10/27/2010 10/28/2010 10/29/2010 11/1/2010 11/2/2010 11/3/2010 11/4/2010 11/5/2010 11/8/2010 21.79 30.60 30.12 22.74 31.31 32.02 26.31 21.31 18.69 36.31 32.38 25.95 24.09 30.60 30.12 26.75 31.31 32.29 26.31 21.31 37.38 36.31 32.28 25.95 52.29 73.01 72.91 70.22 74.08 73.90 74.66 73.06 70.40 72.10 74.32 72.19 41.67 41.90 41.31 32.38 42.26 43.33 35.24 29.17 26.55 50.36 43.57 35.95 19.88 11.31 11.19 9.64 10.95 11.31 8.93 7.86 7.86 14.05 11.19 10.00

4.76 4.52 3.33 2.02 3.33 3.10 0.24 0.00 5.48 10.00 5.36 1.07 41,609 41,497 41,324 41,054 41,041 41,216 41,790 41,855 41,743 41,310 41,395 41,506 73,779 73,203 73,357 73,792 73,198 73,233 73,230 75,176 78,190 73,113 73,031 7,334 211 46 46 169 88 44 34 34 130 47 39 36

### 11/9/2010 11/10/2010 11/11/2010 11/15/2010 11/16/2010 11/17/2010 11/18/2010 11/23/2010 11/30/2010 12/1/2010 12/2/2010 26.90 24.76 21.79 0.00 30.12 33.45 32.26 31.43 42.14 20.60 18.81 26.90 24.76 25.38 0.00 55.60 33.45 32.26 31.43 43.04 25.48 21.91 76.61 73.24 73.49 0.00 45.42 76.15 75.07 73.54 74.21 69.20 71.49 35.12 33.81 29.64 0.00 66.31 43.93 42.98 42.74 56.79 29.76 26.31

8.21 9.05 7.86 0.00 36.19 10.48 10.71 11.31 14.64 9.17 7.50 0.00 0.24 1.90 0.00 4.52 8.93 6.55 3.69 6.43 2.14 4.29 41,392 41,400 41,350 41,965 41,711 40,773 39,933 40,156 38,690 35,750 34,522 72,754 73,418 72,341 74,000 65,483 72,162 70,629 71,055 68,321 46,530 61,133 34 129 475 0 13 13 13 13 13 0 0 NETL DEMONSTRATION SYSTEM TREATMENT

### 12/3/2010 12/6/2010 12/7/2010 12/8/2010 12/9/2010 12/10/2010 12/13/2010 12/14/2010 12/15/2010 12/16/2010 12/17/2010 8.45 27.50 24.64 21.55 21.31 15.95 20.95 20.36 25.83 25.95 21.31 28.17 27.50 24.64 21.55 21.31 29.68 20.95 21.52 26.38 25.95 25.19 75.53 74.76 74.46 74.49 73.06 72.04 74.26 72.77 70.92 72.19 72.76 11.19 36.79 33.10 28.93 29.17 22.14 28.21 27.98 36.43 35.95 29.29

2.74 9.29 8.45 7.38 7.86 6.19 7.26 7.62 10.60 10.00 7.98 2.14 4.17 2.62 1.43 0.12 2.14 0.95 0.24 3.21 2.26 2.26 33,355 33,438 34,198 35,428 35,903 36,280 35,110 34,147 34,315 34,475 34,608 59,848 58,163 59,509 62,203 62,304 64,692 61,300 59,446 59,325 59,167 59,085 0 0 0 0 0 0 12 16 12 47 58

### 12/20/2010 12/21/2010 12/22/2010 12/27/2010 12/28/2010 1/1/2011 1/10/2011 1/20/2011 1/21/2011 1/24/2011 1/25/2011 1/26/2011 21.07 20.60 20.60 0.00 0.00 0.00 16.79 5.71 17.26 2.50 0.00 0.00 21.07 20.60 20.86 0.00 0.00 0.00 20.66 22.12 21.58 16.30 0.00 0.00 73.44 73.00 74.25 0.00 0.00 0.00 70.50 65.75 79.23 77.78 0.00 0.00 28.69 28.21 27.74 0.00 0.00 0.00 23.81 8.69 21.79 3.21 0.00 0.00

7.62 7.62 7.14 0.00 0.00 0.00 7.02 2.98 4.52 0.70 0.00 0.00 1.19 0.24 1.19 0.00 0.00 0.00 2.26 0.12 1.55 0.00 0.00 0.00 34,522 35,019 36,880 36,986 37,368 36,540 35,954 36,536 36,745 36,791 37,071 37,085 60,127 60,950 63,580 73,018 73,794 58,460 62,565 65,085 64,900 61,052 61,426 63,163 57 71 77 60 60 316 38 4,105 284 38 5 359

### 1/27/2011 1/28/2011 1/31/2011 2/1/2011 2/2/2011 2/3/2011 2/4/2011 2/7/2011 2/8/2011 2/25/2011 2/28/2011 3/1/2011 3/2/2011 0.00 6.55 20.00 22.62 20.24 19.05 22.98 20.12 14.52 19.40 19.17 19.40 8.81 0.00 22.58 25.00 28.27 25.30 23.81 28.72 25.15 20.08 24.26 19.17 24.26 21.31 0.00 67.07 75.68 74.80 74.89 70.80 76.89 74.78 71.76 74.77 75.23 70.56 61.16 0.00 9.76 26.43 30.24 27.02 26.90 29.88 26.90 20.24 25.95 25.48 27.50 14.40 0.00 3.21 6.43 7.62 6.79 7.86 6.90 6.79 5.71 6.55 6.31 8.10 5.60 0.00 1.31 2.50 4.52 4.52 5.60 4.76 2.50 2.74 3.81 2.38 2.26 2.26 37,084 37,396 38,115 38,580 38,218 36,845 36,627 35,641 35,591 21,292 17,711 14,600 14,465 67,895 70,279 67,519 64,400 67,161 65,048 64,143 62,739 62,390 36,913 30,747 23,710 26,309 691 569 66 40 38 35 67 31 73 40 24 22 27

### 3/3/2011 3/4/2011 3/7/2011 3/8/2011 3/9/2011 3/10/2011 3/14/2011 3/15/2011 3/16/2011 3/17/2011 3/21/2011 3/23/2011 3/24/2011 20.48 20.71 19.17 17.02 17.26 16.19 14.52 15.24 18.81 7.86 0.00 0.00 0.00 25.60 25.89 23.96 21.28 21.58 20.24 18.15 19.05 23.51 9.82 0.00 0.00 0.00 75.77 77.68 73.52 72.59 75.52 71.96 74.85 69.19 77.45 75.86 0.00 0.00 0.00 27.02 26.67 26.07 23.45 22.86 22.50 19.40 22.02 24.29 10.36 0.00 0.00 0.00

6.55 5.95 6.90 6.43 5.60 6.31 4.88 6.79 5.48 2.50 0.00 0.00 0.00 3.33 3.57 1.31 2.14 1.43 2.26 0.00 1.19 1.19 0.24 0.00 0.00 0.00 14,446 14,635 13,181 12,767 12,692 12,384 8,051 8,116 8,346 8,396 7,428 8,369 8,310 24,911 25,246 23,021 21,889 21,989 21,480 13,829 13,925 14,385 14,440 14,929 13,643 13,799 38 40 21 21 24 37 17 19 27 34 34 175 176

### 3/25/2011 3/28/2011 3/29/2011 3/31/2011 4/6/2011 4/7/2011 4/8/2011 12.02 0.00 14.40 18.57 5.12 14.76 23.69 31.64 0.00 31.09 25.56 28.98 25.02 29.61 63.52 0.00 85.21 76.10 70.49 73.37 76.83 18.93 0.00 16.90 24.40 7.26 20.12 30.83

6.90 0.00 2.50 5.83 2.14 5.36 7.14 2.26 0.00 3.45 4.17 0.83 3.10 4.88 7,621 6,417 22,752 36,446 30,799 31,860 32,367 12,843 16,634 33,365 62,897 58,068 56,134 56,174 138 39 90 202 321 368 418Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10 20 30 40 50 60 70 80 90TREATMENT RATE (BBLS PER DAY)



### TIME 

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NORMALIZEDAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10 20 30 40 50 60 70 80 90 100RECOVERY RATE (%)



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RECOVERY RATEAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 1,000 2,000 3,000 4,000 5,000 6,000TDS (microSiemens/cm)



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DW TDSAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10,000 20,000 30,000 40,000 50,000 60,000 70,000 80,000 90,000TDS (microSiemens/cm)



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PW CWAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10,000 20,000 30,000 40,000 50,000 60,000 70,000 80,000 90,000TDS (microSiemens/cm)



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PW TDS CW TDS DW TDSAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10 20 30 40 50 60 70 80 90TREATMENT RATE (BBLS PER DAY)



### TIME 

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NORMALIZEDAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 0 10 20 30 40CW (BBLS PER DAY)



### TIME 

# CW DISPOSAL VOLUME

- TIME GRAPH

CW OUTAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10 20 30 40 50 60 70 80 90 100RECOVERY RATE (%)



### TIME 

# RECOVERY RATE

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RECOVERY RATEAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 1,000 2,000 3,000 4,000 5,000 6,000TDS (microSiemens/cm)



### TIME 

# TOTAL DISSOLVED SOLIDS

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DW TDSAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10,000 20,000 30,000 40,000 50,000 60,000 70,000 80,000 90,000TDS (microSiemens/cm)



### TIME 

# TOTAL DISSOLVED SOLIDS

- TIME GRAPH

PW TDS CW TDSAltela, Inc. Report © 2011, Altela Inc., All Rights Reserved 

### Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information 

## 0 10,000 20,000 30,000 40,000 50,000 60,000 70,000 80,000 90,000TDS (microSiemens/cm)



### TIME 

# TOTAL DISSOLVED SOLIDS

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PW TDS CW TDS DW TDS