Steven L. Beshear Governor Energy and Environment Cabinet Department for Environmental Protection Division for Air Quality 200 Fair Oaks Lane,

1 51 Floor Frankfort, Kentucky 40601-1403 air.ky.gov February 13, 2015 Beverly Banister, Director Air, Pesticides and Toxics Management Division U.S. Environmental Protection Agency, Region 4 Atlanta Federal Center 61 Forsyth Street Atlanta, Georgia 30303 Dear Ms. Banister:

Leonard K. Peters Secretary The Kentucky Division for Air Quality is respectfully submitting 2014 hourly ozone and sulfur dioxide data, as well as five-minute sulfur dioxide data, for certification. The data, for which certification

is requested,

is listed on the following attached AQS-generated reports: • AMP600: hourly averaged ozone data (parameter code 44201) and sulfur dioxide data (parameter code 42401) • AMP450nc: five-minute averaged sulfur dioxide data (parameter code 42406) I hereby certify that the ambient concentration data and the quality assurance data are completely submitted to AQS.

I also certify that, to the best of my knowledge, the ambient air concentration data are accurate, taking into account the quality assurance findings. If there are any questions or **concerns~** please contact Ms. Jennifer Miller, Environmental Scientist with our Technical Services Branch, at (502) 564-3999, extension 4050. SA/jfm Enclosures KentuckyUnbridledSpirit.com Sincerely, **'.1~** /fJ1u/ Sean Alteri, Director **~ tu~**  **1\..~/DLED** SP/RIT'q

An Equal Opportunity Emp lo yer M/F/DMs. Beverly Banister February 13,2015 Page 2 c: Darren Palmer, USEPA Region 4 Daniel Garver, USEP A Region 4 Keith Goff

, USEP A Region 4UNITED STATES ENVIRONMENTAL PROTECTION AGENCY User ID: FNX CERTIFICATION EVALUATION AND CONCURRENCE Report Request ID: 129713 4 Report Code: AMP600 GEOGRAPHIC SELECTIONS Tribal

Code State County Site Parameter POC City AQCR UAR CBSA 21 PROTOCOL SELECTIONS Parameter Classification Parameter Method CRITERIA CRITERIA 44201 42401 SELECTED OPTIONS Option Type MERGE PDF FILES

AGENCY ROLE DATE CRITERIA Start Date End Date 2014 2014 Duration AGENCY SELECTIONS Kentucky Division For Air Quality

Option Value YES CERTIFYING

Selection Criteria Page 1 CSA EPA Region Feb. 13, 2015Data Evaluation and Concurrence Report Summary Feb. 13, 20 1 5 Certification Year: 2014 Certifying Agency (CA): Kentucky Division For Air Quality (0584) Pollutants in Report: Monitors Evaluated Monitors Recommended for Monitors NOT Recommended Parameter Name Oz one Code 44201 Concurrence by AQS for Concurrence by AQS 22 22 0 Sulfur dioxide 42401 9 9 0 PQAOs in Report: PQAO Name PQAO Code TSA Date Kentu cky Divis i on For Air Quality 0584 06/19/12 Summary of 'N' flags for all pollutants: AQS Cert. Agency Parameter Recommended Recommended PQAO Code AQS Site-ID POC Flag J **~** Reason for AQS Recommendation **Sign~u~~Moni~ringO~an~don~p~~n~~e=,**

**~~ ~~~**  **~~- ~Q**  **~~~ ---------------~**  v Page 1 of 1

# Data Evaluation and Concurrence Report for Gaseous Pollutants Certifying Year 20 14 Certifying Agency Code K en tuc k y Divis ion For Air Quality 

# (0584) Parameter Ozo ne 

# (4420 1 ) (ppm) PQAO Name K entucky Divis ion Fo r Air Qua li ty 

# (0584) QAPP App roval Date 04/21/2011

NPAP Audi t Summary: Number of Val id A ud its N PAP B ias Criteri a Met 

### 7 -1.2658 y Ro utine Data O ne Poi nt Q ua l ity Check Annual P E NPAP Concur. Flag



### ~QS POC Monitor Mean M in Max Exceed . Out lie r Pe rc. Prec i s ion Bias Complete Bias Complete B ias PQAO Level QAPP Aqs Rec CA Rec Epa



### ~ite ID Type Coun t Coun t Comp. Crite ria A ppr. Fl ag Flag Concur



### ~1 **01 -000**  **2** 1 SP M 0 .04 5 0 .01 3 0 .071 0 0 97 2.06 +/-1 . 90 94 - 2.48 100 

### y y y y 

# s

**1-01 5-0**  **00 3**  1 SLAM S 0 .046 0 .01 4 0 .072 0 0 99 2 . 14 +/-1 .98 100 - 1 . 12 100 

### y y y y 

# s

**1-01 -0**  **017** 1 SLAM S 0.049 0 .019 0.083 0 0 99 1.48 +3 .94 100 - 1.62 100 

### y y y y 

# s 121 - 02 9-000 6 1 S LAM S 0 .047 0.015 0 .088 0 0 90 1.57 +2 .44 94 - 3.56 100 

### y y y y 

# s

**~1 -0**  **37- 3002**  1 SLAM S 0 .051 0 .022 0 .082 0 0 99 3 .77 +/-4.29 94 - 2.38 1 00 

### y y y y 

# s 21 -04 3-0 500 1 S P M 0 .045 0 .017 0 .068 0 0 99 1 .27 +/-1 .00 100 - 1 .67 100 

### y y y y 

# s

**-047- 00**  **6** 2 SLAM S 0 .047 0 .014 0 .075 0 0 99 1 . 17 +/-1 . 13 100 - 0 .84 100 

### y y y y 

# s 2 1 -0 59-000 5 

### 1 SLAM S 0 .048 0 .017 0 .077 0 0 98 3 .32 +4.42 100 - 1.07 100 

### y y y y 

# s 2 1-067-00 12 1 SLAM S 0 .049 0 .01 4 0 .074 0 0 99 1 .60 +2.62 100 - 0 . 90 100 

### y y y y 

# s 2 1-089-000 7 1 SLAM S 0 .047 0 .010 0 .075 0 0 99 0.99 +1.42 100 - 0 .27 100 

### y y y y 

# s 2 1-091-0 0 12 1 SLAM S 0 .049 0 .018 0 .082 0 0 96 1 .76 +/-1 .88 100 - 1.72 100 

### y y y y 

# s 21-093-0006 1 SLAM S 0 .047 0 .019 0 .072 0 0 90 4.46 +/-4.2 2 94 - 2.32 100 

### y y y y 

# s 2 1- 1 0 1 - 00 14 1 S P M 0 .050 0 .019 0.080 0 0 98 1.49 +3.25 100 0.37 100 

### y y y y 

# s

**1- 001**  1 SLAM S 0 .049 0.019 0 .074 0 0 99 1.50 +3 . 95 100 - 2 .23 100 

### y y y y 

# s

**1- 139-0**  **03** 1 SLAM S 0 .049 0 .01 9 0 .074 0 0 100 1 . 17 +2 .08 100 - 0 .86 100 

### y y y y 

# s

**1- 145**  **24** 1 SLAM S 0 .047 0 .016 0 .077 0 0 99 2 .24 +/-1 .50 100 - 2 .08 100 

### y y y y 

# s

**~1 -18**  **00 4**  1 SLAM S 0.049 0 .021 0 .083 0 0 99 3 .39 -3.43 100 - 0 .61 100 

### y y y y 

# s

**1- 193-0**  **00 3**  1 S P M 0 .043 0 .01 4 0.067 0 0 100 1.40 +3.33 100 - 1 .72 100 - 4 . 17 

### y y y y 

# s

**~1 195-**  **00 02**  1 S P M 0 .044 0 .01 4 0 .084 0 0 99 0 .79 +2.90 100 - 1.32 100 - 2 .8 6 

### y y y y 

# s 121-1 99-000 3 1 SPM 0 .047 0 .01 6 0 .074 0 0 99 1 .30 +1 .78 100 0 .78 100 

### y y y y 

# s 21 -213-0 004 1 S P M 0 .047 0 .01 3 0 .074 0 0 99 2 .23 +/-2.05 88 - 2 .38 100 - 3.77 

### y y y y 

# s 2 1 -227-0 009 1 SLAM S 0.048 0 .016 0.075 0 0 98 I 2.46 +/-2.15 94 - 1.17 100 3 .77 

### y y y y 

# s

- - -Data Evaluation and Concurrence Report for Gaseous Pollutants Certifying Year 2014 Certifying Agency Code Kentucky Division For Air Quality (0584) Parameter Sulfur dioxide (42401) (ppb) PQAO Name Kentucky Division For Air Quality (0584) QAPP Approval Date 04/21/2011 NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met 2 -5 . 0725 y Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS POC Monitor M ean Min Max Exceed. Outlier Perc. Precision Bias Complete Bias Complete Bias PQAO Level QAPP Aqs Rec CA R ec Epa S i te ID Type Count Count Comp. Criteria Appr. Flag Flag Conc ur **1-019-0017** 1 SLAMS 0.5 0 . 0 51.0 0 99 1 . 86 -3 . 89 100 - 0 . 89 100 y y y y s **1-037 -30**  **02** 1 SLAMS 1 . 5 0 . 0 93 . 0 0 99 2 . 19 -3.43 100 - 2.36 100 y y y y s **~1-047-0006** 2 SPM 0 . 6 0.0 31.0 0 99 4.49 +4 . 48 85 6 . 83 100 y y y y s **~** 1-059-0005 1 SLAMS 1.6 0 . 0 65.0 0 99 4 . 05 +/-3.18 100 3 . 34 100 y y y y s **~1 -06**  **7-0012** 1 SLAMS 0 . 3 0 . 0 28.0 0 99 2 . 13 -2.49 100 - 0.32 100 y y y y s **~1-089-0007** 1 SPM 0 . 6 0 . 0 23.0 0 99 2 . 05 +1 . 99 100 1 . 10 100 y y y y s 21-101-0014 1 SLAMS 0 . 9 0 . 0 38.0 0 99 0 . 87 -1 . 34 100 2 . 29 100 y y y y s 21-113-0001 1 SPM 0.4 0.0 19.0 0 99 2 . 13 -4.35 100 3 . 27 100 y y y y s 21 - 145-102 4 1 SLAMS 0.4 0.0 38 . 0 0 98 I 4 . 54 -4 . 59 96 - 0 . 36 100 y y y y s

# Data Evaluation and Concurrence Report for Particulate MatterData Concurrence and Evaluation Report for LeadUNITED STATES ENVIRONMENTAL PROTECTION AGENCY User ID: FNX QUICKLOOK ALL PARAMETERS Report Request ID: 1297136 Rep ort Code: AMP450NC GEOGRAPHIC SELECTIONS Tribal

Code State County Site Parameter POC City AQCR UAR CBSA 21 PROTOCOL SELECTIONS Parameter Classification ALL Parameter Method 42406 SELECTED OPTIONS Duration CSA EPA Region Feb. 13, 2015

SCR GROUP SELECTIONS 

# I SORT ORDER 

# I' L_

_______ o

_p

__



# t_i_o_n~T_yp __

e __________________________________ 

# o_p_t_~_·o~n~V~a_l_u_e ____________________ 

# ~Lo __

r_d_e_r _______________ c_o_l_u_m_n ____________ 

# ~ **L--------~ e_n_t**  **_c~k~y----------~** MERGE PDF FILES YES 1 STATE CODE EVENTS PROCESSING EXCLUDE REGIONALLY CONCURRED EVENTS 2 COUNTY CODE AGENCY ROLE PQAO 3 SITE ID 4 5 6 7 PARAMETEJ:l._CODE POC DATES EDT ID DATE CRITERIA APPLICABLE STANDARDS Start Date End Date Standard Description 2014 2014

Selection Criteria Page 1IEDT DE$CRIPTION 0 NO EVENTS 1 EVENTS EXCLUDED 2 EVENTS INCLUDED UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICKLOOK ALL PARAMETERS

EXCEPTIONAL DATA TYPES

5 EVENTS WITH CONCURRENCE EXCLUDED Feb. 13, 2015UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICKLOOK ALL PARAMETERS Feb . 13, 2015 Parameter Site ID : 2 1- 0 1 9-0017 42406 S02 max 5-min avg Site ID: 21 - 037-3002 42406 S02 max 5-min avg Site ID: 2 1- 047-0006 42406 S02 max 5-min avg Site ID : 21-059-0005 42406 S02 m ax 5 - min avg Site ID : 21 - 067-0012 42406 S02 max 5-min avg Site ID: 21-089-0007 42406 S02 max 5-min avg Site ID: 21-101-0014 42406 S02 max 5-min avg Site ID: 21-113-0001 42406 S02 max 5-min avg Unit p 0 

### c PQAO City: Ashland County: Boyd Parts per billion 1 0584 City: Highland Heights County: Campbel l Parts per billion 1 0584 City: Not in a c i ty County: Christian Parts per billion 2 0584 City: Not in a city County : Daviess Parts per billion 1 0584 City: Lexington-Fayette (corporate name for County: Fayette Lexington) Parts per bil li on 1 0584 City: Worthington County: Greenup Parts per billion 1 0584 City: Not in a city County : Henderson Parts per billion 1 0584 City : Nicholasville County: Jessamine Parts per billion. 1 0584 Site ID: 21-145-1024 ° City: Paducah County : McCracken 42406 S02 max 5-min avg Parts per billion

Note: The 

## * indicates that the mean " does not satisfy summary criteria. 1 0584 Year Meth 2014 100 2014 1 00 2014 100 20 14 100 2014 100 20 1 4 100 2014 100 2014 100 2014 100 # Obs 1st Max Value 2nd Max Value 3rd Max Value 4th Max Value Arith. Mean Duration Address: FIVCO HEALTH DEPARTMENT, 2924 HOLT STREET 8690 76.0 52.0 42.0 40.0 . 79 1 HOUR Address: 524A JOHN'S HILL ROAD 8673 218.0 163.0 140.0 125.0 2.30 1 HOUR Address: WILLIAMSON RESIDENCE, 10800 PILOT ROCK ROAD 7240 36.0 31. 0 29.0 27.0 . 85 1 HOUR Address: 716 PLEASANT VALLEY ROAD 8703 133.0 124.0 121.0 101.0 2.95 1 HOUR Address : FAYETTE COUNTY HEALTH DEPT, 650 NEWTOWN PIKE 8714 35.0 22.0 22.0 21.0 . 52 1 HOUR Address: SCOTT STREET & CENTER AVENUE 8694 31.0 30.0 22.0 22.0 .88 1 HOUR Address: BASKETT ·FIRE DEPARTMENT, 7492 DR. HODGE ROAD 8694 66.0 60.0 59.0 57.0 1.7 1 1 HOUR Address: KYTC MAINTENANCE GARAGE, 260 WILSON DRIVE 87 10 32.0 19 . 0 19.0 17 . 0 . 55 1 HOUR Address : JACK SON PURCHASE RECC, 2901 POWELL STREET 8588 46.0 40.0 38.0 34.0 .70 1 HOUR

Page 2 of 5 Cert& l':l tJ Eval >-3 0 0 0 0 0 0 0 0 0PARAMETER 42406 METHOD CODE 100

Note: ' The 

### * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICKLOOK ALL PARAMETERS METHODS USED IN THIS REPORT COLLECTION METHOD ANALYSIS METHOD INSTRUMENTAL ULTRAVIOLET FLUORESCENCE

Page 3 of 5 Feb. 13, 2015

# IPQM 0584

Note: The 

### * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICKLOOK ALL PARAMETERS PQAOS USED IN THIS REPORT AGENCY DESCRIPTION Kentucky Division For Air Quality

Page 4 of 5 Feb. 13, 201"5FLAG M N



### s

u

X y MEANING UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICKLOOK ALL PARAMETERS CERTIFICATION EVALUATION AND CONCURRENCE FLAG MEANINGS

The monitoring organization has revised data from this monitor since the most recent certification let ter received from the state. The certifying agency has submitted the certification letter and required summary reports, but the certifying agency and/or EPA has determined that issues regarding the quality of the ambient concentrat ion data cannot be resol ved due to data completeness, the lack of performed quality assurance checks or the results o f uncertainty statist ics shown in the AMP255 r eport or the certification and quality assurance report. The certifying agency has submitted the certification letter and required summa,ry reports. A value of "S" conveys no Regional assessment regarding data quality per se. This flag will remain until the Region provides an "N" or uyn concurrence flag. Uncertified. The certifying agency did not submit a required certification letter and summary reports for this monitor even though the due date has passed, or the state's certification le tter specifically did not apply the certification to this monitor. Certification is not required by 4 0 CFR 58.15 and no conditions apply to be the basis for assigning another flag value The cert ifying agency has submitted a certification letter, and EPA has no unresolved reservations about data quality (after reviewing the letter, the attached summary reports, the amount of quality assurance data submitted to AQS, the quality statistics, and the highest reported concentrations).

Note: The 

### * indicates that the mean does not satisfy summary criteria. Page 5 of 5 Feb. 13, 2015