# Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 

### Report For: David Smith 

# Laboratory ID: AB06305

Date and Time Collected: Sampled By: 

## Sample Information SAM RUIS Description: 

## Location Code: 09/15/2010 Report Date:

Big Bend ICR Fuel Analysis 

## TE_BB_ICR_FUEL

W4 Project Account Code: 03/12/2010 Date of Sample Receipt: Sample Collection Method: grab 

## Laboratory Results 03/10/2010 12:00:00 AM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit 60 Mesh Residual Moisture % ASTM D-5142 KAPXJ 2.58 0 3/16/2010 10:30:00 AM Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 9.60 03/24/2010 9:32:00 AM BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 12934 0 3/17/2010 11:12:00 AM Chlorine as Cl, as Received % 0.01 ASTM4208/300 KASZS 0.16 0 3/24/2010 10:26:00 AM Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KASZS 0.18 0 3/24/2010 10:26:00 AM Chlorine by Bomb/IC, as Determd. % 0.01 ASTM D-4208 KASZS 0.18 03/23/2010 7:53:00 PM Fixed Carbon % ASTM D-5142 KAPXJ 52.86 03/24/2010 9:32:00 AM Fluorine as F, as Received % 0.01 ASTM D-3761 KASZS 0.01 I 03/23/2010 7:53:00 PM Fluorine as F, Dry Basis % 0.01 ASTM D-3761 KASZS 0.0082 03/23/2010 7:53:00 PM Fluorine in Coal, Dry Basis ug/g 2 ASTM3761/300 KASZS 82 03/23/2010 7:53:00 PM Mercury - Direct Combustion ug/g dry basis 0.03 ASTM D6722 KAMCR 0.148 03/26/2010 3:51:00 PM Mercury in Coal, 1st result ug/g 0.02 ASTM D3684 KAMCR 0.144 03/26/2010 9:42:00 AM Selenium mg/kg 1.0 EPA 6010 KAMCR < 1.0 U 03/30/2010 6:32:00 PM Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 3.40 0 3/22/2010 10:23:00 AM Total Moisture % 0.1 ASTM D-3173 KAPAP 10.16 03/30/2010 2:39:00 PM 

### Trace Metals in Coal by ICP Chromium ug/g dry basis ASTM 3682 KAMCR 22.7 04/01/2010 2:55:00 PM Arsenic ug/g dry basis 0.8 ASTM 6357 KAPAP 2.9 I 04/01/2010 3:44:00 PM Cadmium ug/g dry basis ASTM 6357 KAPAP 1.5 04/01/2010 3:44:00 PM Manganese ug/g dry basis ASTM 3682 KAMCR 29.2 04/01/2010 2:55:00 PM Lead ug/g dry basis 0.3 ASTM 6357 KAPAP 8.1 04/01/2010 3:44:00 PM Nickel ug/g dry basis 0.5 ASTM 6357 KAPAP 15.1 04/01/2010 3:44:00 PM Beryllium ug/g dry basis 80 ASTM 3682 KAMCR < 80 U 04/01/2010 2:55:00 PM Volatiles, Dry Basis % 1.40 ASTM D-5142 KAPXJ 35.89 03/24/2010 9:32:00 AM

Report Number: 

### Page 1 of 2 "General Report" AB06305-091510-12 Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicat ed otherwise in the body of the report. Unless otherwise noted, all methods followed are per the most current published version of 40 CFR P art 136, Table B. Results reported on this report pertain to the above referenced sample only.

# Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 

## Comments

Manager, Laboratory Services U - Indicates that the compound was analyzed for but not detected. I - The reported value is between the laborat ory method detection limit (MDL) and t he laboratory practical quantitation limit ( PQL). PQL = 4 x MDL. All results calculated on a wet to wet basis, unless otherwise indicated.
Data Qualifier Codes Explanation: 

### #2 BB Stack Test collected 3-10-10

Should there be any questions regarding this report, please contact:

(813) 630-7490 Patrice Jackson,, Designee for Peggy Penner

Report Number: 

### Page 2 of 2 "General Report" AB06305-091510-12 Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicat ed otherwise in the body of the report. Unless otherwise noted, all methods followed are per the most current published version of 40 CFR P art 136, Table B. Results reported on this report pertain to the above referenced sample only.

# Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 

### Report For: David Smith 

# Laboratory ID: AB06306

Date and Time Collected: Sampled By: 

## Sample Information SAM RUIS Description: 

## Location Code: 09/15/2010 Report Date:

Big Bend ICR Fuel Analysis 

## TE_BB_ICR_FUEL

W4 Project Account Code: 03/12/2010 Date of Sample Receipt: Sample Collection Method: grab 

## Laboratory Results 03/11/2010 12:00:00 AM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit 60 Mesh Residual Moisture % ASTM D-5142 KAPXJ 2.48 0 3/16/2010 10:30:00 AM Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 8.27 03/24/2010 9:32:00 AM BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 13170 0 3/17/2010 11:12:00 AM Chlorine as Cl, as Received % 0.01 ASTM4208/300 KASZS 0.16 0 3/24/2010 10:26:00 AM Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KASZS 0.18 0 3/24/2010 10:26:00 AM Chlorine by Bomb/IC, as Determd. % 0.01 ASTM D-4208 KASZS 0.18 03/23/2010 7:53:00 PM Fixed Carbon % ASTM D-5142 KAPXJ 53.76 03/24/2010 9:32:00 AM Fluorine as F, as Received % 0.01 ASTM D-3761 KASZS 0.01 I 03/23/2010 7:53:00 PM Fluorine as F, Dry Basis % 0.01 ASTM D-3761 KASZS 0.0063 03/23/2010 7:53:00 PM Fluorine in Coal, Dry Basis ug/g 2 ASTM3761/300 KASZS 63 03/23/2010 7:53:00 PM Mercury - Direct Combustion ug/g dry basis 0.03 ASTM D6722 KAMCR 0.128 03/26/2010 3:51:00 PM Mercury in Coal, 1st result ug/g 0.02 ASTM D3684 KAMCR 0.125 03/26/2010 9:42:00 AM Selenium mg/kg 1.0 EPA 6010 KAMCR < 1.0 U 03/30/2010 6:42:00 PM Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 3.35 03/22/2010 9:48:00 AM Total Moisture % 0.1 ASTM D-3173 KAPAP 8.70 03/30/2010 2:39:00 PM 

### Trace Metals in Coal by ICP Chromium ug/g dry basis ASTM 3682 KAMCR 19.9 04/01/2010 2:56:00 PM Arsenic ug/g dry basis ASTM 6357 KAPAP 2.7 04/01/2010 3:45:00 PM Cadmium ug/g dry basis ASTM 6357 KAPAP 1.2 04/01/2010 3:45:00 PM Manganese ug/g dry basis ASTM 3682 KAMCR 25.4 04/01/2010 2:56:00 PM Lead ug/g dry basis ASTM 6357 KAPAP 8.4 04/01/2010 3:45:00 PM Nickel ug/g dry basis ASTM 6357 KAPAP 12.6 04/01/2010 3:45:00 PM Beryllium ug/g dry basis 80 ASTM 3682 KAMCR < 80 U 04/01/2010 2:56:00 PM Volatiles, Dry Basis % 1.40 ASTM D-5142 KAPXJ 36.39 03/24/2010 9:32:00 AM

Report Number: 

### Page 1 of 2 "General Report" AB06306-091510-12 Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicat ed otherwise in the body of the report. Unless otherwise noted, all methods followed are per the most current published version of 40 CFR P art 136, Table B. Results reported on this report pertain to the above referenced sample only.

# Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 

## Comments

Manager, Laboratory Services U - Indicates that the compound was analyzed for but not detected. I - The reported value is between the laborat ory method detection limit (MDL) and t he laboratory practical quantitation limit ( PQL). PQL = 4 x MDL. All results calculated on a wet to wet basis, unless otherwise indicated.
Data Qualifier Codes Explanation: 

### #2 BB Stack Test collected 3-11-10

Should there be any questions regarding this report, please contact:

(813) 630-7490 Patrice Jackson,, Designee for Peggy Penner

Report Number: 

### Page 2 of 2 "General Report" AB06306-091510-12 Laboratory Services certifies that the test results in this report meet all requirements of the NELAC standards, unless indicat ed otherwise in the body of the report. Unless otherwise noted, all methods followed are per the most current published version of 40 CFR P art 136, Table B. Results reported on this report pertain to the above referenced sample only.