February 13, 2015 

Beverly Banister, Director 

Air, Pesticides and Toxics Management Division 

U.S. Environmental Protection Agency, Region 4 

Atlanta Federal Center 

61 Forsyth Street 

Atlanta, Georgia 30303 

Dear Ms. Banister: 

The Kentucky Division for Air Quality is respectfully submitting 2014 hourly ozone and 

sulfur dioxide data, as well as five-minute sulfur dioxide data, for certification. The data, for 

which certification is requested, is listed on the following attached AQS-generated reports: 

• AMP600: hourly averaged ozone data (parameter code 44201) and sulfur dioxide 

data (parameter code 42401) 

• AMP450nc: five-minute averaged sulfur dioxide data (parameter code 42406) 

I hereby certify that the ambient concentration data and the quality assurance data are 

completely submitted to AQS. I also certify that, to the best of my knowledge, the ambient air 

concentration data are accurate, taking into account the quality assurance findings. 

If there are any questions or concerns~ please contact Ms. Jennifer Miller, Environmental 

Scientist with our Technical Services Branch, at (502) 564-3999, extension 4050. 

SA/jfm 

Enclosures 

KentuckyUnbridledSpirit.com 

Sincerely, 

'.1~ /fJ1u/ 

Sean Alteri, 

Director 

1\..~/DLED 

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SP/RIT'q 

An Equal Opportunity Employer M/F/D 

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

User ID: FNX CERTIFICATION EVALUATION AND CONCURRENCE 

Report Request ID: 1297134 Report Code: AMP600 

GEOGRAPHIC SELECTIONS 

Tribal 

Code State County Site Parameter POC City AQCR UAR CBSA 

21 

PROTOCOL SELECTIONS 

Parameter 

Classification Parameter Method 

CRITERIA 

CRITERIA 

44201 

42401 

SELECTED OPTIONS 

Option Type 

MERGE PDF FILES 

AGENCY ROLE 

DATE CRITERIA 

Start Date End Date 

2014 2014 

Duration 

AGENCY SELECTIONS 

Kentucky Division For Air Quality 

Option Value 

YES 

CERTIFYING 

Selection Criteria Page 1 

CSA 

EPA 

Region 

Feb. 13, 2015 
Data Evaluation and Concurrence Report Summary Feb. 13, 20 1 5 

Certification Year: 2014 

Certifying Agency (CA): Kentucky Division For Air Quality (0584) 

Pollutants in Report: Monitors 

Evaluated 

Monitors Recommended for Monitors NOT Recommended 

Parameter Name 

Ozone 

Code 

44201 

Concurrence by AQS for Concurrence by AQS 

22 22 0 

Sulfur dioxide 42401 9 9 0 

PQAOs in Report: 

PQAO Name PQAO Code TSA Date 

Kentucky Division For Air Quality 0584 06/19/12 

Summary of 'N' flags for all pollutants: AQS Cert. Agency 

Parameter Recommended Recommended 

PQAO Code AQS Site-ID POC Flag J ~ Reason for AQS Recommendation 

Sign~u~~Moni~ringO~an~don~p~~n~~e=,v ~~~~~~~-~Q ~~~---------------~ 

Page 1 of 1 
Data Evaluation and Concurrence Report for Gaseous Pollutants 

Certifying Year 2014 

Certifying Agency Code Kentucky Division For Air Quality (0584) 

Parameter Ozone (44201) (ppm) 

PQAO Name Kentucky Division For Air Quality (0584) 

QAPP Approval Date 04/21/2011 

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met 

7 -1.2658 y 

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag 

~QS POC Monitor Mean Min Max Exceed. Outlier Perc. Precision Bias Complete Bias Complete Bias PQAO Level QAPP Aqs Rec CA Rec Epa 

~ite ID Type Count Count Comp. Criteria Appr. Flag Flag Concur 

~1 01 -000 2 1 SPM 0.045 0.01 3 0.071 0 0 97 2.06 +/-1 .90 94 - 2.48 100 y y y y s 

1-01 5-000 3 1 SLAMS 0.046 0.01 4 0.072 0 0 99 2.14 +/-1 .98 100 - 1.12 100 y y y y s 

1-01 -0 017 1 SLAMS 0.049 0.019 0.083 0 0 99 1.48 +3.94 100 - 1.62 100 y y y y s 

121 -029-0006 1 SLAMS 0.047 0.015 0.088 0 0 90 1.57 +2.44 94 - 3.56 100 y y y y s 

~1 -0 37-3002 1 SLAMS 0.051 0.022 0.082 0 0 99 3.77 +/-4.29 94 - 2.38 100 y y y y s 

21 -043-0500 1 SPM 0.045 0.017 0.068 0 0 99 1.27 +/-1 .00 100 - 1.67 100 y y y y s 

-047-00 6 2 SLAMS 0.047 0.014 0.075 0 0 99 1.17 +/-1 .13 100 - 0.84 100 y y y y s 

21-059-0005 1 SLAMS 0.048 0.017 0.077 0 0 98 3.32 +4.42 100 - 1.07 100 y y y y s 

21-067-0012 1 SLAMS 0.049 0.01 4 0.074 0 0 99 1.60 +2.62 100 - 0.90 100 y y y y s 

21-089-0007 1 SLAMS 0.047 0.010 0.075 0 0 99 0.99 +1.42 100 - 0.27 100 y y y y s 

21-091-0012 1 SLAMS 0.049 0.018 0.082 0 0 96 1.76 +/-1 .88 100 - 1.72 100 y y y y s 

21-093-0006 1 SLAMS 0.047 0.019 0.072 0 0 90 4.46 +/-4.22 94 - 2.32 100 y y y y s 

21-101-0014 1 SPM 0.050 0.019 0.080 0 0 98 1.49 +3.25 100 0.37 100 y y y y s 

1- 001 1 SLAMS 0.049 0.019 0.074 0 0 99 1.50 +3.95 100 - 2.23 100 y y y y s 

1- 139-0 03 1 SLAMS 0.049 0.01 9 0.074 0 0 100 1.17 +2.08 100 - 0.86 100 y y y y s 

1- 145 24 1 SLAMS 0.047 0.016 0.077 0 0 99 2.24 +/-1 .50 100 - 2.08 100 y y y y s 

~1 -18 004 1 SLAMS 0.049 0.021 0.083 0 0 99 3.39 -3.43 100 - 0.61 100 y y y y s 

1- 193-0 00 3 1 SPM 0.043 0.01 4 0.067 0 0 100 1.40 +3.33 100 - 1.72 100 - 4.17 y y y y s 

~1 195-0002 1 SPM 0.044 0.01 4 0.084 0 0 99 0.79 +2.90 100 - 1.32 100 - 2.86 y y y y s 

121-1 99-0003 1 SPM 0.047 0.01 6 0.074 0 0 99 1.30 +1 .78 100 0.78 100 y y y y s 

21 -213-0004 1 SPM 0.047 0.01 3 0.074 0 0 99 2.23 +/-2.05 88 - 2.38 100 - 3.77 y y y y s 

21-227-0009 1 SLAMS 0.048 0.016 0.075 0 0 98 I 2.46 +/-2.15 94 - 1.17 100 3.77 y y y y s - - -
Data Evaluation and Concurrence Report for Gaseous Pollutants 

Certifying Year 2014 

Certifying Agency Code Kentucky Division For Air Quality (0584) 

Parameter Sulfur dioxide (42401) (ppb) 

PQAO Name Kentucky Division For Air Quality (0584) 

QAPP Approval Date 04/21/2011 

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met 

2 -5.0725 y 

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag 

AQS POC Monitor Mean Min Max Exceed. Outlier Perc. Precision Bias Complete Bias Complete Bias PQAO Level QAPP Aqs Rec CA Rec Epa 

Site ID Type Count Count Comp. Criteria Appr. Flag Flag Concur 

1-019-0017 1 SLAMS 0.5 0.0 51.0 0 99 1.86 -3.89 100 - 0.89 100 y y y y s 

1-037-3002 1 SLAMS 1.5 0.0 93.0 0 99 2.19 -3.43 100 - 2.36 100 y y y y s 

~1-047-0006 2 SPM 0.6 0.0 31.0 0 99 4.49 +4.48 85 6.83 100 y y y y s 

~ 1-059-0005 1 SLAMS 1.6 0.0 65.0 0 99 4.05 +/-3.18 100 3.34 100 y y y y s 

~1 -06 7-0012 1 SLAMS 0.3 0.0 28.0 0 99 2.13 -2.49 100 - 0.32 100 y y y y s 

~1-089-0007 1 SPM 0.6 0.0 23.0 0 99 2.05 +1 .99 100 1.10 100 y y y y s 

21-101-0014 1 SLAMS 0.9 0.0 38.0 0 99 0.87 -1 .34 100 2.29 100 y y y y s 

21-113-0001 1 SPM 0.4 0.0 19.0 0 99 2.13 -4.35 100 3.27 100 y y y y s 

21 -145-1024 1 SLAMS 0.4 0.0 38.0 0 98 I 4.54 -4.59 96 - 0.36 100 y y y y s 
Data Evaluation and Concurrence Report for Particulate Matter 
Data Concurrence and Evaluation Report for Lead 
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

User ID: FNX QUICKLOOK ALL PARAMETERS 

Report Request ID: 1297136 Report Code: AMP450NC 

GEOGRAPHIC SELECTIONS 

Tribal 

Code State County Site Parameter POC City AQCR UAR CBSA 

21 

PROTOCOL SELECTIONS 

Parameter 

Classification 

ALL 

Parameter Method 

42406 

SELECTED OPTIONS 

Duration 

CSA 

EPA 

Region 

Feb. 13, 2015 

SCR GROUP SELECTIONS 

I 

SORT ORDER I' L_ _______ o_p __ t_i_o_n~T_yp __ e __________________________________ o_p_t_~_·o~n~V~a_l_u_e ____________________ ~Lo __ r_d_e_r _______________ c_o_l_u_m_n ____________ ~ L--------~ e_n_t _c~k~y----------~ 

MERGE PDF FILES YES 1 STATE CODE 

EVENTS PROCESSING EXCLUDE REGIONALLY CONCURRED EVENTS 2 COUNTY CODE 

AGENCY ROLE PQAO 3 SITE ID 

4 

5 

6 

7 

PARAMETEJ:l._CODE 

POC 

DATES 

EDT ID 

DATE CRITERIA APPLICABLE STANDARDS 

Start Date End Date Standard Description 

2014 2014 

Selection Criteria Page 1 
IEDT DE$CRIPTION 

0 NO EVENTS 

1 EVENTS EXCLUDED 

2 EVENTS INCLUDED 

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

AIR QUALITY SYSTEM 

QUICKLOOK ALL PARAMETERS 

EXCEPTIONAL DATA TYPES 

5 EVENTS WITH CONCURRENCE EXCLUDED 

Feb. 13, 2015 
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

AIR QUALITY SYSTEM 

QUICKLOOK ALL PARAMETERS 

Feb . 13, 2015 

Parameter 

Site ID : 21- 01 9-0017 

42406 S02 max 5-min avg 

Site ID: 21 - 037-3002 

42406 S02 max 5-min avg 

Site ID: 21- 047-0006 

42406 S02 max 5-min avg 

Site ID : 21-059-0005 

42406 S02 max 5 - min avg 

Site ID : 21 - 067-0012 

42406 S02 max 5-min avg 

Site ID: 21-089-0007 

42406 S02 max 5-min avg 

Site ID: 21-101-0014 

42406 S02 max 5-min avg 

Site ID: 21-113-0001 

42406 S02 max 5-min avg 

Unit 

p 

0 

c PQAO 

City: Ashland County: Boyd 

Parts per billion 1 0584 

City: Highland Heights County: Campbel l 

Parts per billion 1 0584 

City: Not in a c i ty County: Christian 

Parts per billion 2 0584 

City: Not in a city County : Daviess 

Parts per billion 1 0584 

City: Lexington-Fayette 

(corporate name for 

County: Fayette 

Lexington) Parts per billion 1 0584 

City: Worthington County: Greenup 

Parts per billion 1 0584 

City: Not in a city County : Henderson 

Parts per billion 1 0584 

City : Nicholasville County: Jessamine 

Parts per billion. 1 0584 

Site ID: 21-145-1024 ° City: Paducah County : McCracken 

42406 S02 max 5-min avg Parts per billion 

Note: The * indicates that the mean "does not 

satisfy summary criteria. 

1 0584 

Year Meth 

2014 100 

2014 1 00 

2014 100 

20 14 100 

2014 100 

201 4 100 

2014 100 

2014 100 

2014 100 

# 

Obs 

1st Max 

Value 

2nd Max 

Value 

3rd Max 

Value 

4th Max 

Value 

Arith. 

Mean Duration 

Address: FIVCO HEALTH DEPARTMENT, 2924 HOLT STREET 

8690 76.0 52.0 42.0 40.0 . 79 1 HOUR 

Address: 524A JOHN'S HILL ROAD 

8673 218.0 163.0 140.0 125.0 2.30 1 HOUR 

Address: WILLIAMSON RESIDENCE, 10800 PILOT ROCK ROAD 

7240 36.0 31. 0 29.0 27.0 . 85 1 HOUR 

Address: 716 PLEASANT VALLEY ROAD 

8703 133.0 124.0 121.0 101.0 2.95 1 HOUR 

Address : FAYETTE COUNTY HEALTH DEPT, 650 NEWTOWN PIKE 

8714 35.0 22.0 22.0 21.0 . 52 1 HOUR 

Address: SCOTT STREET & CENTER AVENUE 

8694 31.0 30.0 22.0 22.0 .88 1 HOUR 

Address: BASKETT ·FIRE DEPARTMENT, 7492 DR. HODGE ROAD 

8694 66.0 60.0 59.0 57.0 1.71 1 HOUR 

Address: KYTC MAINTENANCE GARAGE, 260 WILSON DRIVE 

87 10 32.0 19 . 0 19.0 17 . 0 . 55 1 HOUR 

Address : JACKSON PURCHASE RECC, 2901 POWELL STREET 

8588 46.0 40.0 38.0 34.0 .70 1 HOUR 

Page 2 of 5 

Cert& l':l 

tJ Eval >-3 

0 

0 

0 

0 

0 

0 

0 

0 

0 
PARAMETER 

42406 

METHOD 

CODE 

100 

Note: ' The * indicates that the mean does not 

satisfy summary criteria. 

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

AIR QUALITY SYSTEM 

QUICKLOOK ALL PARAMETERS 

METHODS USED IN THIS REPORT 

COLLECTION METHOD ANALYSIS METHOD 

INSTRUMENTAL ULTRAVIOLET FLUORESCENCE 

Page 3 of 5 

Feb. 13, 2015 
IPQM 

0584 

Note: The * indicates that the mean does not 

satisfy summary criteria. 

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

AIR QUALITY SYSTEM 

QUICKLOOK ALL PARAMETERS 

PQAOS USED IN THIS REPORT 

AGENCY DESCRIPTION 

Kentucky Division For Air Quality 

Page 4 of 5 

Feb. 13, 201"5 
FLAG 

M 

N 

s 

u 

X 

y 

MEANING 

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 

AIR QUALITY SYSTEM 

QUICKLOOK ALL PARAMETERS 

CERTIFICATION EVALUATION AND CONCURRENCE FLAG MEANINGS 

The monitoring organization has revised data from this monitor since the 

most recent certification letter received from the state. 

The certifying agency has submitted the certification letter and required 

summary reports, but the certifying agency and/or EPA has determined 

that issues regarding the quality of the ambient concentration data cannot 

be resolved due to data completeness, the lack of performed quality 

assurance checks or the results o f uncertainty statistics shown in the 

AMP255 r eport or the certification and quality assurance report. 

The certifying agency has submitted the certification letter and required 

summa,ry reports. A value of "S" conveys no Regional assessment regarding 

data quality per se. This flag will remain until the Region provides an "N" or 

uyn concurrence flag. 

Uncertified. The certifying agency did not submit a required certification 

letter and summary reports for this monitor even though the due date has 

passed, or the state's certification letter specifically did not apply the 

certification to this monitor. 

Certification is not required by 4 0 CFR 58.15 and no conditions apply to be 

the basis for assigning another flag value 

The certifying agency has submitted a certification letter, and EPA has no 

unresolved reservations about data quality (after reviewing the letter, the 

attached summary reports, the amount of quality assurance data 

submitted to AQS, the quality statistics, and the highest reported 

concentrations). 

Note: The * indicates that the mean does not 

satisfy summary criteria. Page 5 of 5 

Feb. 13, 2015