An Integrated Water Treatment Technology Solution for 

Sustainable Water Resource Management in the Marcellus Shale

DE-FE0000833

Final Scientific / Technical Report

Report Date: June 30, 2011

Team Members:

Altela, Inc.

Argonne National Laboratory

BLX, Inc.

CWM Environmental, Inc. 

Point of Contact:

Matthew Bruff

Altela, Inc.

Phone: 303-993-1951

Facsimile: 303-993-1955

Email: matthew.bruff@altelainc.com

DISCLAIMER:

“This report was prepared as an account of work sponsored by an agency of the United States 

Government. Neither the United States Government nor any agency thereto, nor any of their 

employees, makes any warranty, express or implied, or assumes any legal liability or 

responsibility for the accuracy, completeness, or usefulness of any information, apparatus, 

product, or process disclosed, or represents that its use would not infringe privately owned rights. 

Reference herein to any specific commercial product, process, or service by trade name, 

trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, 

recommendation, or favoring by the United State Government or any agency thereof. The views 

and opinions of authors expressed herein do not necessarily state or reflect those of the United 

States Government or any agency thereof.
DE-FE0000833 2010

TITLE PAGE

REPORT TITLE: An Integrated Water Treatment Technology 

Solution for Sustainable Water Resource 

Management in the Marcellus Shale

TYPE OF REPORT: Scientific / Technical

REPORTING PERIOD START DATE: October 1, 2009

REPORTING PERIOD END DATE: April 10, 2011

PRINCIPAL AUTHOR(s): Matthew Bruff

Ned Godshall

Karen Evans

DATE REPORT WAS ISSUED: July 30, 2011

ORGANIZATION: Altela, Inc.

7500 Meridian Pl. NW, Suite B

Albuquerque, NM 87121

DISCLAIMER:

“This report was prepared as an account of work sponsored by an agency of the United States 

Government. Neither the United States Government nor any agency thereto, nor any of their 

employees, makes any warranty, express or implied, or assumes any legal liability or 

responsibility for the accuracy, completeness, or usefulness of any information, apparatus, 

product, or process disclosed, or represents that its use would not infringe privately owned rights. 

Reference herein to any specific commercial product, process, or service by trade name, 

trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, 

recommendation, or favoring by the United State Government or any agency thereof. The views 

and opinions of authors expressed herein do not necessarily state or reflect those of the United 

States Government or any agency thereof. 
Page 2 of 35

TABLE OF CONTENTS

Page

Abstract..........................................................................................................................4

Executive Summary ............................................................................. 4

Report Details.................................................................................... 6

1. CONFIRM REGULATORY FRAMEWORK IS IN PLACE

1.1 National Pollution Discharge Elimination System (NPDES) ............................. 7

1.2 PA Department of Environmental Protection ..................................................... 9

1.3 Air Quality .......................................................................................................... 9

1.4 PA Bureau of Oil and Gas Management ........................................................... 10

1.5 UIC Injection .................................................................................................... 10

1.6 PA Water Quality Standards.............................................................................. 11

2. CONFIRM WATER QUALITY MEETS REGULATORY REQUIREMENTS

2.1 Baseline Water Quality Review and Site Selection ......................................... 14

2.2 Field Water Sampling, Analysis and Reporting for Baseline Bench Testing... 15

2.3 Field Water Quality Analysis......................................................... 15

3. CONFIRM SYSTEM TREATMENT EFFICACY

3.1 Bench Testing of Field Water .......................................................................... 17

3.2 Mass Balance Analysis .................................................................................... 19

3.3 Test Bench Treatment Summary ..................................................................... 20

4. SYSTEM OPERATIONS REPORT

4.1 Summary .......................................................................................................... 22

4.2 Gas and Electrical Usage ................................................................................. 26

4.3 Concentrate Disposal ....................................................................................... 26

4.4 Estimated Costs ................................................................................................ 27

5. LIFE CYCLE ANALYSIS REPORT

5.1 Approach .......................................................................................................... 29

5.2 Operations ........................................................................................................ 30

5.3 Capital Equipment Manufacturing ................................................................... 30

5.4 Transportation .................................................................................................. 31

5.5 Water Disposal ................................................................................................. 31

5.6 Results .............................................................................................................. 31

5.7 Analysis ............................................................................................................ 32

Conclusion ....................................................................................... 33

List of Acronyms and Abbreviations ....................................................... 35
DE-FE0000833 2010

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APPENDICES

A. PA DEP Request for Approval of Alternative Waste Management Practices 

B. CWM Environmental, Inc. Sampling Procedures 

C. Water Quality Reports (Produced Water, Frac Water and Frac Flow-back Water) 

D. Water Quality Reports (Test-Bench Concentrate Water and Distilled Water) 

E. Mass Balance Analysis 

F. New Mexico Oil Conservation Division Approval for Marcellus Water 

G. Photos of Site

H. Miscellaneous Charts and Graphs
DE-FE0000833 2010

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ABSTRACT

This Final Scientific / Technical Report submitted with respect to Project DE-FE0000833 titled 

“An Integrated Water Treatment Technology Solution for Sustainable Water Resource 

Management in the Marcellus Shale” in support of final reporting requirements. This final 

report contains a compilation of previous reports with the most current data in order to produce 

one final complete document.

The goal of this research was to provide an integrated approach aimed at addressing the 

increasing water resource challenges between natural gas production and other water 

stakeholders in shale gas basins. The objective was to demonstrate that the AltelaRain®

technology could be successfully deployed in the Marcellus Shale Basin to treat frac flow-back 

water. That objective has been successfully met.

EXECUTIVE SUMMARY

The purpose of this research was to provide an integrated approach aimed at addressing the 

increasing water resource challenges between natural gas production and other water 

stakeholders in shale gas basins. Pictures of the site can be found in Appendix G.

Specific goals of the project included: 1) delivering field-proof that a water treatment technology 

was actually capable of treating this highly challenged Marcellus frac water to water quality 

standards required for discharge and/or applicable beneficial re-use, 2) delivering field-proof that 

the water treatment technology could economically treat the frac water at a cost equal to or lower 

than current disposal methods, and 3) demonstrating that the regulatory environment would

support implementation of the water treatment technology solution. 

With respect to verifying field-proof that the technology was capable of treating Marcellus frac 

water to water quality standards required for discharge and/or applicable beneficial re-use, 

numerous water quality analyses of the treated water were taken. Both bench-scale water quality 

analyses and the first field-based quarterly water sampling verified that the system was operating 

successfully and capable of treating the highly challenged Marcellus Shale frac flow-back and 

produced water to requisite levels. With respect to those initial field water quality analyses, the 

specific conductance of the untreated dirty water (PW) was 42,400 umhos/cm; the specific 

conductance of the clean water (DW) was 30.0 umhos/cm. Copies of the complete water quality 

analyses have been attached to this report as Appendix C. Additionally, the report contains a 

comparison of PA DEP’s water quality requirements (as applied to latest NPDES permit -

TARM’s reporting requirements noted previously) with Altela’s water quality results from field 

samples. This comparison further reinforces that the AltelaRain® technology met or exceeded

required PA DEP water quality requirements.

 

With respect to delivering proof that the treatment technology can economically treat the frac 

water at a cost equal to or lower than current disposal methods, the all in per barrel cost through 
DE-FE0000833 2010

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the reporting period was calculated to be $0.12/gallon and $4.88/barrel, respectively. This 

represents a minimum cost savings of 23% as compared to conventional truck and disposal fees 

(at commercial facilities or UIC reinjection wells). The total per barrel operating cost (OpEx) of

$4.88/barrel ($0.12/gal) was calculated by summing the individual OpEx costs listed below:

• Gas Cost: $1.74/barrel of water eliminated

• Electric Cost: $0.345/barrel of water eliminated

• Labor Cost: $2.789/barrel of water eliminated

• Consumables Cost: $0.01/barrel of water eliminated

This total per barrel operating cost (OpEx) of $4.88/barrel ($0.12/gal) reflects the per barrel cost 

of the water eliminated from trucking and disposal (TR=PW-CW). It does not include the cost 

of disposal of the concentrate, but it also did not divide these costs by the larger number of “how 

much input water was treated”. The cost calculations can (and should) be done two different 

ways: (a) as above, based only on the net volume of water eliminated from trucking and 

disposal, TR = PW-CW; and (b) based on the volume of water treated, PW. 

The latter method yields a total per barrel operating cost (OpEx) of $4.88/barrel ($0.12/gal) and 

reflects the per barrel cost of the water brought into the system (PW). It therefore includes the 

cost of disposal of the Concentrate Water (CW). Total water treated (PW) equaled 7,120 barrels, 

and OpEx costs were:

• Total Gas Cost: $9,264 ($1.74/barrel TR X 5,324 barrels)

• Total Electric Cost: $1,837 ($0.345/barrel TR X 5,324 barrels)

• Total Labor Cost: $14,850 ($2.789/barrel TR X 5,324 barrels)

• Total Consumables Cost: $53 ($0.01/barrel TR X 5,324 barrels)

• Total Disposal Cost: $11,315 ($6.30/barrel TR X 1,796 barrels)

Total OpEx costs, including CW disposal, were therefore $37,319. The resulting per gallon and 

per barrel costs were $0.125/gallon and $5.24/barrel, respectively. This represents a savings of 

17% over trucking and disposal without the Altela system (1-$5.24/$6.30). This cost savings 

increases to 38% when trucking and disposal market pricing, post May 19th, 2011, is taken into 

account following Chapter 95 discharge limit enforcement.

UIC disposal surcharges for out-of-district brine disposal are increasing total disposal costs to the 

E&P operators. For example, according to the Ohio Division of Mineral Resources Management 

(ODNR), “With the passage of Senate Bill 165 in 2010, some changes to the UIC Program 

include an increase in the Class II saltwater injection permit application fee from $100 to $1000, 

and an injection disposal fee of $.05 per barrel for brine originating in-district and $.20 per barrel 

for brine originating out-of-district.” In addition, January 2011, PA DEP amended Title 25, 

Chapter 95, Wastewater Treatment Requirements, to address the dramatic increase in Marcellus 

Shale wastewater that was being diluted and sent into Pennsylvania’s surface water bodies. The 
DE-FE0000833 2010

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new 95 regulation included more stringent discharge standards including 500 mg/L for Total 

Dissolved Solids (TDS) and 250 mg/L each for Sulfates and Chlorides.

As a result of PA DEP’s Chapter 95 regulation and ensuing enforcement efforts by PA DEP in 

May of 2011, the per barrel market price for disposal of Marcellus Shale wastewater has 

increased significantly due to increased costs to comply with the new discharge regulations. 

Operators have reported per barrel costs exceeding $8.50 per barrel with further increases based 

on proximity to Ohio or to limited disposal sites still available in Pennsylvania. This in turn, has 

made new technologies like the AltelaRain® process to be more economical and thereby gain 

additional market traction. Taking into account this new regulatory market dynamic, industry 

can currently realize a savings of 38% over trucking and disposal without the Altela system (1-

$5.24/$8.50). 

Moreover, as outlined in this report, the life cycle assessment results show that experience gained 

from the Altela 4000 field tests have helped improve the system design and resulted in a 45% 

increase in overall energy efficiency for the newer Altela 600 system. In the future, if suitable 

sources of low grade waste heat can be located and systems co-located to take advantage of them

(co-generation projects), the system efficiency can improve as much as 85% from the original 

test system. Altela is in discussion with several entities to pursue this co-generation approach. 

Finally, with respect to demonstrating that the regulatory environment support implementation of 

the water treatment technology solution, this report provides a review of the regulatory 

requirements as well as confirmation that supports implementation of the AltelaRain® water 

treatment technology solution in Pennsylvania’s Marcellus Shale Basin. Numerous 

Pennsylvania Commonwealth agencies responsible for both federal and state regulatory 

requirements have jurisdiction over the deployment and operation of this system demonstration. 

In each case, where applicable, Recipient received approval or satisfied related permit/regulatory 

exemptions with respect to deploying and operating the system. Further, water quality samples 

taken in the field with respect to the demonstration system support that the system indeed met 

regulatory water quality requirements being imposed by regulators. 

REPORT DETAILS

By employing a technology-based approach, Recipient demonstrated how a water treatment 

technology solution can be deployed that successfully addresses perceived impediments and 

information gaps with respect to successfully treating flow-back water. The research also 

highlights the benefits associated with augmenting current water supply through re-use and best 

water resource management. By proving such a ‘best-practices’ approach is indeed available to 

industry, a transformational solution was created that does not merely minimize potential 

impacts to water caused by natural gas development but rather expands and creates opportunities 

for water supply augmentation and associated re-use/conservation.

The Recipient’s project team reviewed and provided written reports reflecting regulatory 

approvals, water quality, efficacy as well as summarizing the system operations relative to 
DE-FE0000833 2010

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project initial expectations found in the System Operations Report. This requirement was stated

in the Statement of Project Objectives in relation to the Milestone Review requirement for Phase 

I outlined below: 

Confirm Regulatory Framework is in Place 

Confirm Water Quality Meets Regulatory Requirements.

Confirm System Treatment Efficacy 

System Operations 

1. CONFIRM REGULATORY FRAMEWORK IS IN PLACE

1.1 National Pollution Discharge Elimination System (NPDES)

This project did not require an NDPES permit as all treated, distilled water was recycled and reused for subsequent well development and in the fracing process during the one year term of this 

demonstration. Following the successful demonstration, future sites and projects deploying the 

technology may be interested in obtaining an NPDES-based surface discharge permit. As such, a 

review of NPDES requirements has been included as part of this regulatory review. 

Produced water which is not re-injected into the ground may be alternatively surface discharged 

pursuant to regulatory oversight. Surface discharge of produced water is governed by the United 

States Clean Water Act (“CWA”), also known as the Federal Water Pollution Control Act. In 

1972, Congress enacted the CWA, "to restore and maintain the chemical, physical and biological 

integrity of the Nation's waters." 1

 The CWA created both state and federal roles for the 

attainment of these goals. The EPA Administrator must "establish and enforce technology-based 

limitations on individual discharges into the country's navigable waters from point sources," 

while each state must establish water quality standards with accompanying goals for all intrastate 

waters.”2

 Section 401 of the CWA requires oil and gas companies to apply for a NPDES permit 

if they are discharging produced water into surface waters of a state. Clean water regulations 

provide that there will be no discharge of water pollutants into navigable waters from any source 

associated with production, field exploration, drilling, well completion, or well treatment (i.e. 

produced water) without an NPDES permit.3

The EPA has published federal NPDES regulations under the Clean Water Act, and may 

authorize states – as well as territories and tribes – to implement all or parts of the national 

program. Currently, the EPA has authorized thirty-seven states to implement and monitor the 

NPDES program. NPDES permits set specific requirements regulating the characteristics of the 

discharged water based on national technology-based effluent limitations and applicable water 

quality standards. The permits establish the level of performance the discharger must maintain 

 

 1 33 U.S.C §§ 1251-1376 33 U.S.C. § 1251(a)(2002).

2 PUD No. 1 of Jefferson County v. Was. Dept. of Ecology, 511 U.S. 700, 704 (1994).

3 40 C.F.R. § 435.32.
DE-FE0000833 2010

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and specify monitoring, inspection, and reporting requirements and other actions necessary to 

achieve compliance. However, the EPA retains the opportunity to review the permits issued by 

the state, and formally object to elements deemed in conflict with federal requirements. NPDES 

permits are specifically tailored to individual facilities. General NPDES permits cover multiple 

facilities within a certain category located in a specific geographical area. The applicant must 

submit a complete application for a permit, which includes the application form and any

supplemental information completed to the satisfaction of the Regional Administrator (NM –

Region 6, South Central), who may seek further information by issuing a notice of deficiency.4

The primary mechanism for regulating discharges of pollutants to receiving waters is through 

numerical effluent limits. The effluent limits describe the pollutants subject to monitoring as 

well as quantity (concentration) of pollutants. Subpart C of 40 CFR Part 35 states that oil and 

gas companies located onshore may not discharge produced water into navigable waters of the 

United States. However, two exceptions exist:

1. Subpart E – Allows for onshore discharge for those facilities located in the continental 

United States located west of the 98th meridian. Produced water with a maximum oil and grease 

limit of 35 mg/L may be discharged provided that the produced water is of sufficient quality to 

be re-used for wildlife or livestock watering or other agricultural uses. In addition, the produced 

water has to be put to use during actual discharge.

2. Subpart F – Allows for onshore discharge for facilities that produce 10 barrels per day or 

less of crude oil (stripper well exception). PA DEP has issued a general NDPES permit that 

authorizes discharge of wastewater from stripper oil well facilities to surface waters at the site of 

the oil wells provided that the operator must have coverage under the general NDPES permit or 

approval of an individual NPDES permit before treating waste water for discharge. See PA DEP 

General NPDES Permit No. PAG 310001. 

With respect to this project, neither exception applies since Recipient operated the demonstration 

directly on the pad-site. However, following a successful demonstration, federal regulations do 

not preclude moving off the pad-site to a centralized treatment facility. For example, recently 

the PA Department of Environmental Protection (“DEP”) issued a NPDES individual permit to 

TerrAqua Resource Management, LLC authorizing the discharge into waters of Pennsylvania of 

treated process wastewater generated from the drilling, development and use of natural gas wells 

in north central Pennsylvania (Permit No. PA0233650, Industrial Waste, SIC 1389). Based on 

the effluent requirements listed in this recently issued NPDES permit, Recipient’s water quality 

results demonstrate that it was able to comply with such an NPDES framework. In addition, 

Recipient has previously demonstrated its ability to meet stringent NPDES-based effluent 

limitations when it received NPDES approval to discharge into the Colorado River Basin. 

Therefore, when and if applicable for future commercial deployments, Recipient is confident that 

 4 40 CFR § 122.21(e). 
DE-FE0000833 2010

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NPDES requirements can be achieved. It is important to note that the need for an NPDES permit 

may not be widely in demand. Both the regulatory community and natural gas operators have 

stressed the need and demand for every drop of clean water that can be achieved through 

treatment for re-use and recycling efforts. 

1.2 PA Department of Environmental Protection

The Pennsylvania Department of Environmental Protection (“PA DEP”), previously the 

Department of Environmental Resources, was created in 1995 to help protect the 

Commonwealth’s environment and to assure its residents of clean air and pure water. One 

method the DEP employs to meet its mission is through a system of permits, licenses, 

registrations, and certifications. Although some DEP authorizations are issued within the central 

office in Harrisburg, PA, the majority are issued through the department’s six regional offices. 

Based on the site selected for this project (Sleppy well located in Indiana County), the 

Southwestern Regional DEP office has jurisdiction (located at 400 Waterfront Drive, Pittsburgh, 

PA 15222). In addition, Recipient had several regulatory meetings with PA DEP’s main office 

in Harrisburg beginning in early January 2010 to discuss and review the various regulatory 

requirements and anticipated benefits associated with this NETL project. Representatives from 

water quality, air quality, waste management and the oil and gas attended and were very helpful 

in providing both policy and regulatory guidance. 

1.3 Air Quality

Pennsylvania’s Air Pollution Control Act provides that no person shall construct, assemble, 

install or modify any air contamination source, or install thereon any air pollution control 

equipment or device unless the person has applied to and received written approval from the 

Pennsylvania DEP. The process of obtaining an air permit generally consists of two steps. The 

first step is obtaining a pre-construction permit authorization (known as a Plan Approval). The 

second step is obtaining an Operating Permit to allow actual operations at the facility. However, 

not all air contamination sources require a Plan Approval or Operating Permit. Some may be 

exempt under PA Commonwealth regulations. Under 25 PA. Code § 127.14, if the air 

contamination sources being referenced are exempt based on the Air Quality Exemption List, or 

if the PA DEP determines the sources to be of minor significance, a Plan Approval and/or 

Operating Permit were not required. 

With respect to this project, the AltelaRain® System is exempt based on the Air Quality 

Exemption List. See Section 127.14(a)(8) Exemption No. 38 – Oil and gas exploration and 

production facilities and operations that include wells and associated equipment and processes 

used either to: a) drill or alter oil and gas wells; b) extract, process and deliver crude oil and 

natural gas to the point of lease custody transfer; c) plug abandoned wells and restore well sites, 

or d) treat and dispose of associated wastes. 
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1.4 PA Bureau of Oil and Gas Management

DEP’s Bureau of Oil and Gas Management is responsible for the statewide oil and gas 

conservation and environmental programs to facilitate the safe exploration, development, 

recovery of Pennsylvania's oil and gas reservoirs in a manner that will protect the 

commonwealth's natural resources and the environment. The Bureau develops policy and 

programs for the regulation of oil and gas development and production pursuant to the Oil and 

Gas Act, the Coal and Gas Resource Coordination Act, and the Oil and Gas Conservation Law; 

oversees the oil and gas permitting and inspection programs; develops statewide regulation and 

standards; conducts training programs for industry; and works with the Interstate Oil & Gas 

Compact Commission and the Technical Advisory Board.

The Oil and Gas Bureau directed Recipient to complete and file a Request for Approval of 

Alternative Waste Management Practices (PA DEP Form No. 5500-PM-OG0071) with respect to 

deploying and using the AltelaRain® system at the Sleppy well-pad in support of the project. A 

copy of the approved application has been included as Appendix A. 

1.5 UIC Injection

The Altela ARS evaporation-condensation process generates two liquid streams. The first

stream consists of the clean, distilled water (“DW”). The second, or concentrate water stream

(“CW”), is the residual liquid solution remaining after approximately 80% of the pure H2O has 

been removed via the recycling process. This residual CW solution will contain nearly 100% of 

the salt products by weight contained in the original volume of the produced/frac water 

processed through the system in a 24-hour period of time. The clean DW produced during the 

recycling process will be available for re-use by natural gas producers in on-going drilling 

operations. The residual CW, containing nearly 100% of the salt products that enter the facility, 

will be removed from the site and transferred to an approved underground reinjection well or 

commercial disposal facility. Recipient is exploring other recycling uses for this CW as 

regulations permit (heavy brine water or road salt). 

Regulatory control of the injection of produced water into injection wells is governed by the 

Federal Safe Drinking Water Act, Underground Injection Control (UIC) Program. The charter of 

this federal act is to ensure high quality drinking water by limiting the injection of produced 

water to injection zones that geologically will never serve as an Underground Source of Drinking 

Water (“USDW”). A USDW is an aquifer or portion of an aquifer that supplies any public water 

system or contains sufficient quantity of groundwater to supply a public water system; currently 

supplies drinking water for human consumption or contains fewer than 10,000 milligrams/liter 

total dissolved solids; and is not an aquifer exempted from UIC regulations.5

 5 40 C.F.R. § 144.3

 Class I wells are 

used for the injection of hazardous and non-hazardous fluids (industrial and municipal wastes). 
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Class II wells inject brines and other fluids associated with oil and gas production. Class III 

wells inject mining fluids. Class IV wells deal with the injection of hazardous or radioactive 

wastes. Class V wells govern injection not covered above. 

The EPA’s regulations establish minimum standards for state programs to receive primacy for 

the UIC program under Section 1422 of the SDWA. In 1981, the federal government added 

Section 1425 to the SDWA to relieve oil and gas re-injection well programs in the states of 

having to meet the technical requirements of the federal UIC program. 

Recipient received approval to dispose of the CW at the following UIC injection wells located in 

Ohio: Miller Co. (OH Injection Well Permit No. 4355), D-1 (OH Injection Well Permit No. 

2403, Renshaw (OH Injection Well Permit No. 927), Ows (OH Injection Well Permit No. 682) 

and Clinton (OH Injection Well Permit No. 3262). Due to geological limitations, very few 

underground injection wells are available in PA. In addition, Recipient received approval to 

utilize Hart Resources Technologies, Inc. for fluid disposal, if needed. 

1.6 PA Water Quality Standards

Pennsylvania Code, Chapter 93 sets forth the water quality standards for surface waters of the 

Commonwealth including wetlands. These standards are based upon water uses which are to be 

protected and will be considered by the Department in implementing its authority under the 

Clean Streams Law and other statutes that authorize protection of surface water quality. See 

generally the Clean Streams Law, the Act of June 22, 1937 (P.L. 1987, No. 394), as amended, 35 

P.S. § 691.1 et seq.; The Clean Water Act (33 U.S.C. § 1251 et seq.); regulatory cite: 25 Pa. 

Code Chapters 91 through 105 as applicable. 

No specific water quality effluent guidelines are provided in a simple regulatory chart. Rather, 

effluent guidelines are derived from a multitude of considerations including critical uses, 

protective water uses, anti-degradation, etc. With respect to Recipient’s project, a baseline water 

quality parameter list was developed by employing specific water quality criteria outlined in 

Table 3, § 93.7 of the PA Code as well as DEP Bureau of Waste Management Form 26R –

Chemical Analysis of Residual Waste. In addition, several parameters were added to assist in 

tracking treatment performance. The 118 Parameter List (increased to 121 parameters when 

Thorium 228, 230 and 232 were added) is included on the following page. 
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Parameter List:

1. Acidity

2. Hardness, Total

3. Calcium

4. Magnesium

5. Alkalinity

6. Bicarbonate

7. Total Dissolved Solids

8. Specific Conductance

9. Chloride

10. Fluoride

11. Sodium

12. Total Suspended Solids

13. Total Residual Chlorine

14. Ammonia Distillation

15. Ammonia Nitrogen

16. Total Kjeldahl Nitrogen

17. BOD

18. COD

19. E Coli

20. Total Coliform

21. Heterotrophic Plate Count

22. Color

23. MBAS

24. pH

25. Oil & Grease

26. Osmotic Pressure

27. Temperature (F), Field

28. Gross Alpha DW

29. Gross Beta DW

30. Barium

31. Boron

32. Bromide (EPA 300.1)

33. Bromide (EPA 300)

34. Cobalt

35. Copper

36. Iron

37. Iron, Dissolved

38. Lithium, Total

39. Manganese

40. Molybdenum

41. Phenolics

42. Potassium

43. Radium 226

44. Radium 228

45. Silica, Dissolved

46. Silicon, Total

47. Strontium

48. Sulfate

49. Acetone

50. Gasoline Range Organics

51. Benzene

52. mp-Xylene

53. o-Xylene

54. Total Xylenes

55. Toluene

56. Diesel Range Organic C10-C28

57. Ethane

58. Formaldehyde

59. Methane

60. Methanol

61. Alkalinity, Carbonate

62. Alkalinity, Hydroxide

63. Alkalinity, Phenolphthalein

64. Aluminum

65. Antimony

66. Arsenic

67. Beryllium

68. Cadmium

69. Chromium

70. Lead

71. Mercury

72. Nickel

73. Nitrate

74. Nitrate / Nitrite

75. Nitrite

76. Selenium

77. Silver

78. Thallium

79. Tin

80. Titanium

81. Uranium

82. Vanadium

83. Vinyl Chloride

84. Zinc

85. 1,1,1-Trichloroethane

86. 1,1,2,2-Tetrachloroethane

87. 1,1,2-Trichloroethane

88. 1,1-Dichloroethane

89. 1,1-Dichloroethene

90. 1,2 Dibromoethane

91. 1,2-Dibromo-3-chloropropane

92. 1,2-Dichloroethane

93. 1,2-Dichloropropane

94. 2-Butanone (MEK)

95. 2-Hexanone

96. 4-Methyl-2-Pentanone(MIBK)

97. Bromochloromethane

98. Bromodichloromethane

99. Bromoform

100. Bromomethane

101. Carbon Disulfide

102. Carbon Tetrachloride

103. Chlorobenzene

104. Chlorodibromomethane

105. Chloroethane

106. Chloroform

107. Chloromethane

108. cis-1,2-Dichloroethene

109. cis-1,3-Dichloropropene

110. Ethene

111. Ethylbenzene

112. Ethylene Glycol

113. Methylene Chloride

114. Styrene

115. Tetrachloroethene

116. trans-1,2-Dichloroethene

117. trans-1,3-Dichloropropene

118. Trichloroethene

119. Thorium 228

120. Thorium 230

121. Thorium 232

This water quality parameter list was used to develop baseline water quality data for Marcellus 

Shale produced water, frac water and frac flow-back water (Appendix C). In addition, this 

baseline water quality parameter list was used in the analysis of the treated distilled water and 

concentrate water following test-bench testing of the produced water, frac water and frac flowback water (Appendix D). 
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On February 27, 2010, PA DEP released the effluent limits for a precedent setting individual 

NPDES permit for process wastewater generated from the drilling, development, and use of 

natural gas wells in north central Pennsylvania and discharge of treated effluent (Marcellus Shale 

wastewater). As noted earlier, this permit was issued to TerrAqua Resource Management, LLC 

(PA0233650, Industrial Waste, SIC 1389) in late February 2010 after Recipient’s water analysis. 

The monitored parameters and related effluent limits for TerrAqua Resource Management, LLC 

are comprehensive based on the precedent-setting nature of this permit and provide additional 

direction on what effluent requirements will be employed for any additional centralized 

Marcellus Shale waste water treatment facilities. In addition, it is important to note that many of 

the parameters included in this recently issued permit have no individual limit but rather have a 

“Monitor” and report requirement. These parameters include:

1. BOD5 21. Iron, Dissolved 41. Lithium

2. Total Suspended Solids 22. Silver, Total 42. Magnesium

3. Oil & Grease 23. Boron, Total 43. MBAS (Surfactants)

4. pH (standard units) 24. Cobalt, Total 44. Molybdenum

5. Ammonia-N 25. Arsenic, Total 45. Osmotic Pressure (mosm/kg)

6. Aluminum, Total 26. Cadmium, Total 46. Sodium

7. Acetone 27. Lead, Total 47. Specific Conductance

(umho/cm)

8. Acetophenone 28. Mercury, Total 48. Total Dissolved Solids

9. 2-Butanone 29. Nickel, Total 49. Chlorides

10. o-Cresol 30. Selenium, Total 50. Sulfates

11. p-Cresol 31. Benzene 51. Radium 226/228 (pCi/L)

12. Phenol 32. Toulene 52. Gross Alpha (pCi/L)

13. Pyridine 33. Alkalinity, Total as CaCO3 53. Acidity

14. 2,4,6-Trichorophenol 34. Beryllium 54. Ammonia-N

15. Copper, Total 35. Bromide 55. Kjeldahl-N

16. Zinc, Total 36. Calcium 56. Nitrate-Nitrite as N

17. Barium, Total 37. Chemical Oxygen Demand 57. Total Nitrogen

18. Strontium, Total 38. Chromium, Total 58. Total Phosphorus

19. Iron, Total 39. Ethylene Glycol 59. Net Total Nitrogen

20. Manganese, Total 40. Hardness, Total as CaCO3 60. Net Total Phosphorus

In addition to the above effluent limits, the permit contains Chesapeake Bay Nutrient 

Requirements. Though no surface discharge occurred as part of this technology demonstration, 

it is nonetheless important for future adoption of the technology that the technology is capable of 

meeting proposed effluent limit requirements. Based on the extensive water quality analysis 

performed to date for the project, the technology is capable of purifying this highly challenged 

Marcellus Shale frac and produced water to a quality commensurate with surface discharge in 

accordance with regulatory requirements. 

As highlighted above, the regulatory environment supports implementation of the AltelaRain®

water treatment technology solution in Pennsylvania’s Marcellus Shale Basin. Numerous 
DE-FE0000833 2010

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Pennsylvania Commonwealth agencies responsible for both federal and state regulatory 

requirements have jurisdiction over the deployment and operation of this system demonstration. 

In each case, where applicable, Recipient received approval or satisfied related permit/regulatory 

exemptions with respect to deploying and operating the system. Moreover, although many 

factors created potential barriers to implementation of the AltelaRain® technology in 

Pennsylvania and later in other Marcellus Shale regional states, none of them were critical 

barriers. The Recipient collected data and interacted with the PA DEP to address concerns. No 

barriers interfered with the successful completion of the full project. Water quality samples 

taken in the field with respect to the demonstration system supported the system indeed met 

regulatory water quality requirements being imposed by regulators. 

Beginning January of 2011, PA DEP amended Title 25, Chapter 95, Wastewater Treatment 

Requirements, to address the dramatic increase in Marcellus Shale wastewater that was being 

diluted and sent into PA’s surface water bodies. The new 95 regulation included more stringent

discharge standards including 500 mg/L for Total Dissolved Solids (TDS) and 250 mg/L each for 

Sulfates and Chlorides. The previous PA administration had “grandfathered” 27 facilities that 

had been accepting Marcellus Shale wastewater prior to the promulgation of Chapter 95 

regulations. Some of the “grandfathered” facilities voluntarily ceased accepting Marcellus Shale 

wastewater following the new rulemaking. However, 16 facilities (either a publically owned 

treatment work (i.e. municipal sewer system) or commercial treatment facility (i.e. Franklin 

Brine or Warren Brine) continued accepting Marcellus wastewater. 

On April 19, 2011, a press release was issued by PA DEP notifying the E&P industry that it 

would now begin enforcing the recently passed Chapter 95 regulations. PA DEP provided thirty 

days for industry to comply. According to Kay Gresch, PA DEP, “More than half of those (16) 

facilities are now up for permit renewal. Now is the time to take action to end this practice.”

As a result of PA DEP’s Chapter 95 regulation, the per barrel market price for disposal of 

Marcellus Shale wastewater has increased significantly due to increased costs to comply with the 

new discharge regulations. This in turn, has made new technologies like the AltelaRain® process 

to be more economical and thereby gain additional market traction. 

2. CONFIRM WATER QUALITY MEETS REGULATORY REQUIREMENTS

2.1 Baseline Water Quality Review and Site Selection 

Recipient conducted a preliminary review of existing water quality analyses to assist in 

determining a demonstration site that produced water with quality requirements that met the 

specifications of the treatment system. Frac water and related produced water is highly-complex 

in the wide variety of its inherent contaminates (e.g., metals, sulfates, chlorides, proprietary 

constituents, etc.). One common component is the highly challenged waters nearly always have

high levels of TDS. Based on these existing water quality analyses, Western Pennsylvania was 
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targeted resulting in the selection of the demonstration-site at the Sleppy well pad located in 

Indiana County (True Latitude: North 40 d, 36’ 16.60”, True Longitude: West 78 d, 57’ 

39.45”). The well operator was BLX, Inc., DEP Id. No. 27365. The DEP Well Permit No. for 

the Sleppy well-pad is 37-063-36534. 

2.2 Field Water Sampling, Analysis and Reporting

Field water samples were pulled from two well locations in Butler County, PA during the first 

week of February 2010. Based on the close geographic proximity of these wells, assumptions on 

the water samples possessing similar chemical constituents from the Marcellus Shale geologic 

formation are presumed valid. 

CWM Environmental, Inc.’s trained personnel collected these water samples. The produced 

water (PW) was pulled at the Ross Well site using the grab sample technique on 2/2/10 following 

CWM’s standard sampling procedure (Appendix B). Four 55 gallon drums of PW were filled 

onsite and transported to Altela’s Albuquerque facility for testing. Additionally, a small quantity 

of this raw water was captured and analyzed at CWM Environmental, Inc.’s water testing 

laboratory to determine chemical constituents before Altela test-bench testing. Four barrels each 

of frac and flow back water were also pulled from the Bergbigler Well on 2/2/10 and 2/7/10, 

respectively, for shipment to Altela. Similar to the Ross Well site, raw water samples were 

analyzed at CWM Environmental, Inc.’s water testing laboratory to determine chemical 

constituents before Altela’s test-bench testing. 

Prior to shipping, Altela coordinated with the New Mexico Oil Conservation Division (NM 

OCD) to acquire a regulatory approval to store and utilize real gas field produced water and frac 

water for the test-bench testing and analysis (Appendix F). 

The laboratory results of the raw water constituent analysis for each sample water type are found 

in Appendix C. In addition, the chemical concentrations and resultant masses of each constituent 

were utlilized for the mass balance analysis found in section 3.2 of this report.

2.3 Field Water Quality Analysis 

Consistent with Milestone 7, the first field-based quarterly water sampling was taken on 

September 13, 2010. These water samples were taken and analyzed by a certified water quality 

laboratory to verify the system was operating successfully and capable of treating the highly 

challenged Marcellus Shale frac flow-back and produced water. These water quality analyses 

demonstrated the system’s ability to treat highly challenged water and produce extremely clean 

water output. The initial specific conductance of the untreated dirty water (PW) was 42,400 

umhos/cm; the specific conductance of the clean water (DW) was 30.0 umhos/cm. Copies of the 

complete water quality analyses have been attached to this report as Appendix C. 
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The chart below compares PA DEP’s water quality requirements (as applied to latest NPDES 

permit - TARM’s reporting requirements noted above) with Altela’s water quality results from 

quarterly samples taken. Additional parameters were tested as indicated in the chart below. The 

complete water quality analyses reinforces that the AltelaRain technology met or exceeded

required PA DEP water quality requirements. 

QUARTERLY RESULTS OF CHEMICAL ANALYSES OF PW & DW

PARAMETERS

TERRAQUA EFFLUENT 

LIMITATIONS / 

CONCENTRATIONS

ALTELA RESULTS

Sample ID #

Mo. 

Avg.

Daily 

Max.

Instan

t Max.

PreTreated 

(PW)

Altela 

Treated 

(DW)

PreTreated 

(PW)

Altela 

Treated 

(DW)

PreTreated 

(PW)

Altela 

Treated 

(DW)

PreTreated 

(PW)

Altela 

Treated 

(DW)

Sampling Date 9.13.2010 9.13.2010 2.15.11 2.15.11 3.31.2011 3.31.2011 4.6.2011 4.6.2011

1 PA

Biochemical Oxygen 

Demand mg/L 53 163 204 76.8 <2 107 26.6 83.9 27.1 99.6 38.8

2 PA

Total Suspended 

Solids mg/L 30 45 60 114 3 35 3 60 <3 54 <3

3 PA Oil and Grease mg/L 15 30 1.6 2.1 0.1 2.6 2.7 3.2 3.7 1

4 PA pH pH Units 9 7 7.87 6.5 4.73 6.9 6.24 6.51 5.77

5 PA Total Ammonia (N) mg/L 25 50 63 17.8 3.88 28.1 1.77 10.2 4.42 23.1 3.25

6 PA

Total/Dissolved 

Aluminum (Al) mg/L 2 4 5 <1 <0.1 <1 <0.1 <5.0 <0.10 <5.0 <0.10

7 Acetone ug/L 7.97 30.2 37.8 13800 949 8710 524 11800 658

8 Acetophenone mg/L 0.056 0.114 0.14

9 2-Butanone mg/L 1.85 4.81 6 ND ND ND ND ND ND

10 o-Cresol mg/L 0.561 1.92 2.4

11 p-Cresol mg/L 0.205 0.698 0.873

12

Phenol/Phenolics 

(Total) mg/L 1.08 3.65 4.56 0.01 0.03 ND 0.03 ND 0.02 ND 0.02

13 Pyridine mg/L 0.182 0.37 0.455

14 2,4,6-Trichlorophenol mg/L 0.106 0.155 0.265

15 PA

Total/Dissolved 

Copper (Cu) mg/L 0.321 0.501 0.803 0.33 <0.02 <0.2 0.07 <1.0 <0.02 <1.0 0.08

16 PA

Total/Dissolved Zinc 

(Zn) mg/L 0.42 0.497 1.05 <0.2 <0.02 <0.2 0.05 <1.0 <0.02 <1.0 0.04

17 PA

Total/Dissolved 

Barium (Ba) mg/L 10 20 25 405.5 <0.1 332.2 0.33 284.7 2.47 260.5 4.54

18 PA

Total/Dissolved 

Strontium (Sr) mg/L 10 20 25 379 0.026 317.8 0.35 264.2 2.28 233 3.93

19 PA Total Iron mg/L 3 6 7.5 23.1 <0.02 17.4 0.12 17.6 0.02 18.5 0.08

20 PA

Total/Dissolved 

Manganese (Mn) mg/L 2 4 5 2.9 <0.02 2.1 <0.02 2 <0.02 2 0.04

21 PA Dissolved Iron (Fe) mg/L Monitor Monitor 7 22.9 <0.02 21.1 <0.02 13.9 0.03 14.3 0.06

22 PA

Total/Dissolved Silver 

(Ag) mg/L 0.093 0.145 0.233 <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

23 PA

Total/Dissolved Boron 

(Bo) mg/L Monitor Monitor 3.12 0.02 2.7 0.05 2 0.06 <1.0 0.06

24 PA

Tota;/Dissolved 

Cobalt (Co) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

25 PA

Total/Dissolved 

Arsenic (As) mg/L Monitor Monitor 0.028 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

26 PA

Total/Dissolved 

Cadmium (Cd) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <1.0 <0.005

27 PA

Total/Dissolved Lead 

(Pb) mg/L Monitor Monitor <0.2 <0.02 <0.02 <0.02 <1.0 <0.02 <1.0 <0.02

28 PA

Total/Dissolved 

Mercury (Hg) mg/L Monitor Monitor ND ND ND ND ND ND

29 PA

Total/Dissolved 

Nickel (Ni) mg/L Monitor Monitor <0.5 <0.05 <0.5 <0.05 <2.5 <0.05 <2.5 <0.05

30 PA

Total/Dissolved 

Selenium (Se) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

31 PA Benzene ug/L Monitor Monitor ND ND ND ND ND ND ND ND

32 PA Toluene ug/L Monitor Monitor ND ND 8.3 ND 10.9 1.3 15 1.1

33 PA

Alkalinity (Total as 

CaCO3) mg/L Monitor Monitor 102 14 110 <5 88 <5.0 100 12

34 PA

Dissolved Berylium 

(Be) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

35 PA

Dissolved Bromide 

(Br-) mg/L Monitor Monitor 162.5 <0.3 118.5 <0.10 101 0.92 117 1.6

36 PA

Dissolved Calcium 

(Ca+) mg/L Monitor Monitor 1933 0.36 1634 2.18 1186 11.1 1175 22.2

37 PA

Chemical Oxygen 

Demand mg/L Monitor Monitor 289 <10 344 48.3 220 35.8 265 51.4

38 PA

Total/Dissolved 

Chromium (Cr) mg/L Monitor Monitor <0.2 <0.02 <0.2 <0.02 <1.0 <0.02 <1.0 <0.02

39 PA Ethylene Glycol mg/L Monitor Monitor ND ND ND ND ND ND ND ND

40 PA Hardness (CaCO3) mg/L Monitor Monitor 5555 <10 4655 <10 3461 32 3386 64

41 PA Dissolved Lithium (Li) mg/L Monitor Monitor 14.3 ND 10.7 ND 9.1 0.082 10.7 0.13

42 PA

Dissolved Magnesium 

(Mg) mg/L Monitor Monitor 176.8 <0.1 139.5 0.36 121.3 1.1 109.8 2.04

43 PA MBAS (Surfactants) mg/L Monitor Monitor 0.18 ND ND ND ND ND ND ND

44 PA

Dissolved 

Molybdenum (Mo) mg/L Monitor Monitor <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005
DE-FE0000833 2010

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QUARTERLY RESULTS OF CHEMICAL ANALYSES OF PW & DW

PARAMETERS

TERRAQUA EFFLUENT 

LIMITATIONS / 

CONCENTRATIONS

ALTELA RESULTS

Sample ID #

Mo. 

Avg.

Daily 

Max.

Instant. 

Max.

PreTreated 

(PW)

Altela 

Treated 

(DW)

PreTreated 

(PW)

Altela 

Treated 

(DW)

PreTreated 

(PW)

Altela 

Treated 

(DW)

PreTreated 

(PW)

Altela 

Treated 

(DW)

Sampling Date 9/13/2010 9/13/2010 2/15/2011 2/15/2011 3.31.2011 3.31.2011 4.6.2011 4.6.2011

45 PA Osmotic Pressure mosm/kg Monitor Monitor 808 ND 637 ND ND ND 589 ND

46 PA Dissolved Sodium (Na+) mg/L Monitor Monitor 7781 0.37 5868 6.42 4726 43.8 4712 87.9

47 PA

Specific 

Conductance/Conductivi

ty uS/cm Monitor Monitor 42400 30 34300 74.5 28450 375 31600 632

48 PA Total Dissolved Solids mg/L 500 1000 1250 37600 9 26055 33 22350 196 25560 400

49 PA Dissolved Chloride (Cl-) mg/L 250 500 625 16240 2.9 11670 14.6 9760 99.1 11352 184.2

50 PA Dissolved Sulfate (SO4-) mg/L 250 500 625 34 <1 20.4 2.2 <100.0 1.98 <100 2.1

51 PA Radium 226 pCi/L Monitor Monitor 162 0.278 153 0.224 155 2.87 130 2.3

52 PA Radium 228 pCi/L Monitor Monitor 85.5 0.259 45 1.32 51.9 0.296 55 0.49

53 PA Gross Alpha pCi/L Monitor Monitor 352 -0.409 664 0.841 161 1.93 249 6.49

54 PA Acidity mg/L

Less than 

Alkalinit

y -30 6 <5 16 -26 <5.0 -16 <5.0

55 Ammonia-N Report 17.8 3.88 28.1 1.77 10.2 4.42 23.1 3.25

56 PA Total Kjeldahl Nitrogen mg/L Report 1.4 3.3 ND 1.5 30.1 4.5 19.7 4.1

57 PA

Nitrate plus Nitrite 

Dissolved mg/L Report <2 <0.2 <2 <0.2 <20.0 <0.20 <20 <0.20

58 Total Nitrogen Report

59 Total Phosphorus Report

OTHER PARAMETERS TESTED BY ALTELA

60 PA Color pccu 200 <5 130 <5 55 <5 75 <5

61 PA Temperature F 62.3 136.1 63 135 51 109 61 97

62 PA Total Residual Chlorine mg/L <.10 <0.10 0 0.45 0 0.21 0 0

63 PA Dissolved Nitrate (N) mg/L <1 <.010 <1 <.10 <10.0 <0.10 <10 <0.10

64 PA Dissolved Nitrite (N) mg/L <1 <0.1 <1 <0.1 <10.0 <0.10 <10 <0.10

65 PA

Alkalinity (PP as 

CaCO3) mg/L ND ND ND ND ND ND ND ND

66 Hydroxide (OH) mg/L ND ND ND ND ND ND ND ND

67 Carbonate (CO3) mg/L ND ND ND ND ND ND ND ND

68 Bicarbonate (HCO3) mg/L 102 14 110 <5 88 <5.0 100 12

69 Dissolved Fluoride (F-) mg/L 4.8 <0.2 <2 <0.2 <20.0 0.32 <20 0.42

70 Dissolved Potassium (K) mg/L 95.5 <0.1 66.2 <0.10 63.2 0.52 59.6 0.98

71 Dissolved Silica (SiO2)) mg/L 30 ND 25 ND 16 ND 19 ND

72 Total Silicon (Si) mg/L 7 0.19 6.4 0.19 5.1 0.16 6.4 0.22

73 Ethylbenzene ug/L ND ND ND ND ND ND ND ND

74 o-Xylene ug/L ND ND ND ND ND ND ND ND

75 m & p-Xylene ug/L ND ND ND ND 2.3 ND ND ND

76 Xylenes (Total) ug/L ND ND ND ND ND ND ND ND

77 PA GRO (C5-C12) Gasoline ug/L ND ND ND ND ND ND ND ND

78 PA DRO (C8-C36) Diesel mg/L 5.4 0.99 7.1 2.3 4 4.9 4.3 3.1

79 PA Methane (CH4) ug/L 748 1.3 5490 ND 3570 ND 4550 ND

80 Methanol (CH4O) mg/L ND ND ND ND ND ND ND ND

81 Formaldehyde (CH2O) mg/L ND ND ND ND ND ND ND ND

82 PA Gross Beta pCi/L 189 -0.141 847 0.259 79.7 1.57 178 0.754

83 PA Thorium 232 pCi/L -0.005 0.025 0.114 0.011 0.055 0.016 0.035 -0.009

84

Dissolved Antimony 

(Sb) mg/L <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

85 Dissolved Thallium (Tl) mg/L <0.05 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

86 Dissolved Tin (Sn) mg/L <0.05 <0.005 <0.05 <0.007 <0.25 <0.005 <0.01 <0.005

87 Dissolved Titanium (Ti) mg/L 0.037 <0.005 <0.05 <0.005 <0.25 <0.005 <0.01 <0.005

88 PA Dissolved Uranium (U) mg/L ND ND ND ND ND ND ND ND

89 Dissolved Vanadium (V) mg/L ND ND ND ND ND ND ND ND

3. CONFIRM SYSTEM TREATMENT EFFICACY

3.1 Bench Testing of Field Water

The purpose of bench testing the produced water, frac-water, and flow-back water was to 

determine the performance of the Altela ART-500 tower during concentration testing runs of the 

three water samples with respect to treatment efficacy. The testing created CW and DW samples 

from each raw water grab for subsequent mass balance analysis. Tower treatment rate, volume 

reduction, and f-values (a measure of tower efficiency referred to by Altela as the Energy Re-Use 

Factor) were calculated from the data generated over a testing period spanning 6- 8 hours.
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Test Details

An ART-500 tower was used to perform the testing on Altela’s test bench apparatus. During the 

testing, approximately 150 gallons of the test water was treated. The following data points were

obtained throughout the series of testing and were used to calculate performance:

• PW Flow Rate

• Air Flow Rate

• Steam Rate

• Gas Consumption

• Time

• Produced Water Temperatures

• Tower Top Temperature

• Conductivity of Produced Water

• Conductivity of Concentrated Water

• Conductivity of Distilled Water

• Produced Water Volume

• Distilled Water Volume

The data listed above was obtained at the following PW/CW volume increments of 150, 125, 

100, 75, 50, and 25 gallons. 

The first test data set was conducted on the produced water. The starting tank volume before 

recirculation of the produced water through the ART-500 Tower was 211.37 gallons. The end 

tank volume after draining the tower was 96.28 gallons, resulting in a 54% volume reduction. 

The overall amount of produced water treated over the 8.42 hour test period was 115.09 gallons 

for an average treatment rate of 13.7 GPH. An average f value of 1.57 was calculated. 

The second test set was performed on the frac water. The starting tank volume before 

recirculation of the frac water through the tower was 193.55 gallons. The tank volume after the 

testing was completed and the tower was drained was 54.20 gallons, resulting in a 72% volume 

reduction. The total frac water treated was 139.35 gallons over a 6.25 hour test period which 

results in an average treatment rate of 22.30 GPH. An average f value of 2.41 was calculated. 

The third set of testing done was on the flow-back water. The starting tank volume was 194.04 

gallons before recirculation of the flow-back water through the tower. The tank volume after the 

testing was completed and the tower was drained was 53.96 gallons, resulting in a 73% volume 

reduction. The total flow-back water treated was 140.08 gallons, with a treatment rate of 21.82 

GPH over the 6.42 hour test period. An average f value of 2.32 was calculated. 

The standard ART-500 Tower test protocol uses a pure sodium chloride solution at a 35,000 ppm 

concentration with an average treatment rate of 26.70 GPH and an average f value of 3.10. 

When comparing the test results from the Marcellus Shale produced water with the tests results 

from the pure sodium chloride solution, the treatment rate of the tower is 49% less. Comparison 
DE-FE0000833 2010

Page 19 of 35

of the frac water and the flow-back water treatment rate to the pure sodium chloride solution 

showed that the treatment rate of the tower decreased by 17% and 18% respectively. The 49% 

reduction in treatment efficiency of the ART-500 tower when treating the Marcellus produced 

water can be attributed to the 195,000 ppm initial concentration of the water. The further 

increase in concentration of the produced water during the test drove the concentration of the 

water towards the saturation point of the sodium chloride solution. In other words, the Sodium 

Chloride salt would have begun to precipitate out of the water. 

Total volume reduction of PW, frac, and frac flow-back water is dependent on initial 

concentration of total dissolved solids, primarily salts, in the samples tested, and tower run time. 

Test bench testing and related analysis indicated tower test time for the frac and flow- back water 

would further reduce the volume with minor negative effects on treatment rate or f factor. 

3.2 Mass Balance Analysis

As noted previously, three large-volume samples of real-world Marcellus Shale gas water were 

obtained from three different well-sites in western Pennsylvania. Their labels and initial 

volumes of brackish raw water are listed below:

1. Sample 1: Label "Frac Water"; PW =194 gallons.

2. Sample 2: Label "Produced Water"; PW =211 gallons.

3. Sample 3: Label "Flow-Back Water"; PW =194 gallons.

All three samples were shipped to Altela's facility in Albuquerque NM, where they were 

successively processed through Altela's standard AltelaRain® towers. The amount of 

Concentrate Water (CW) and Distilled Water (DW) generated by each sample was measured 

upon completion of each test, and their respective volumes are listed below:

4. Sample 1: Label "Frac Water"; CW = 54 gallons and DW = 140 gallons.

5. Sample 2: Label "Produced Water"; CW = 96 gallons and DW = 115 gallons.

6. Sample 3: Label "Flow-Back Water"; CW = 54 gallons and DW = 140 gallons.

The Treatment Rate (TR=PW-CW) and Recovery Rate (RR=1-CW/PW) from each of these 

three tests are easily calculated from the above PW and CW amounts and are listed below:

7. Sample 1: Label "Frac Water"; TR = 140 gallons and RR = 72.2%.

8. Sample 2: Label "Produced Water"; TR = 115 gallons and RR = 54.5%.

9. Sample 3: Label "Flow-Back Water"; TR = 140 gallons and RR = 72.2%.
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Water Quality Measurements

All six (6) water volumes listed above (CW and DW samples each from the produced water, frac 

water and frac flow-back water) had representative water samples sent to a third-party 

environmental water quality firm, CWM Environmental, Inc. Each of these 6 water samples was 

measured for the individual baseline constituents developed for the project, less total residual 

chlorine. CWM Environmental, Inc.’s water quality results for these six tests are included in 

Appendix D. 

Mass Balance Calculations

In addition, a mass balance analysis was conducted on the water quality samples. Each mass 

balance sample was measured for the 118 individual constituents. Results are included in 

Appendix E. The samples yielded mass balance calculations with the following overall results:

1. The right-hand columns of the 3 tabs in the accompanying spreadsheet illustrate the mass 

balance calculations for each constituent. Total absolute mass, for both incoming and 

outgoing amounts of each constituent, were calculated by multiplying the respective 

concentration measured by CWM times the volume of respective PW, CW, or DW water. 

The last two columns indicate the difference between incoming and outgoing amounts.

2. Of the 118 constituents tested for each raw water sample, there were 57 constituents that 

tested below the detectable limit. In simple terms, nearly half the constituents tested were

from a practical perspective, not in the raw water samples. This was true for the same 57 

constituents across all three raw water samples. 

3. An analysis of the mass balance results from the constituents labeled “General Parameters” 

shows good correlation between the achieved results and the theoretical calculated mass 

balance. Again this same comment holds across all three data sets. 

4. Low-boiling point organic constituents (vapor pressures higher than that of water) had higher 

positive discrepancies (less mass present in the outgoing CW and DW streams than in the 

incoming PW stream), as expected from previous Altela experience, indicating some 

volatilization and escape in the air exhaust.

5. In general, the Altela process produced distilled water from incoming frac water, flow-back 

water, or gas well produced water. Concentrations of contaminant constituents in Altela DW 

water have been removed to levels generally better than 99.8% of their incoming raw water 

concentrations.

3.3 Test-Bench Summary and Conclusions

Three samples of “real world” waste water were obtained from two sites in the Marcellus Shale. 

These samples were from the sources as follows:

(1) Frac Water – a sample of the initial fracturing solution used to fracture a newly 

drilled natural gas well was pulled at the start of the fracturing process. 
DE-FE0000833 2010

Page 21 of 35

(2) Flow-Back Water – a sample of the solution that flows out of the well after the start 

of the fracturing process was pulled three days following the start of the fracturing 

process, this was pulled from the same site that used the initial Frac Water solution.

(3) Produced Water (PW) – a sample of the Produced Water that is brought to the surface 

of a natural gas well once the well is “in production” was pulled on the same day the 

Flow-Back Water sample was pulled. The PW sample was pulled from a well that 

was fractured in early October 2009 and been in constant production from early 

November 2009.

CWM Environmental, Inc.’s baseline water quality reports for these three samples are included 

in Appendix C. Once pulled, the raw water samples were sent to the Altela facility in New 

Mexico for process treatment testing on the Altela test apparatus. Each raw sample was 

“treated” using the same equipment and test tower over a 3-day period, each requiring about 1 

full day on the test “tower.” During the test of each raw water sample, the water was circulated 

through the Altela tower until a pre-determined residual volume was obtained. During this 

process, pure H2O was evaporated from the raw water solution. As a result, the resultant 

solution is a “concentrated” version of the raw water solution, since the mass of the dissolved 

constituents should remain fairly consistent, assuming no chemistry changes take place during 

the process. The evaporated water (DW) is recovered through the condensation process 

occurring in the “tower”, and if successful, the DW should have little or no contaminants in the 

water. CWM’s water quality reports for the CW and DW analyses are included in Appendix D. 

Upon completion of all three test-bench tests, a sample was pulled from each test from the three 

net solutions, i.e. a raw water sample, CW sample, and a DW sample was pulled for each test for 

applicable mass balance analysis (Appendix E). A thorough review and mass balance analysis of 

the sample results yielded the following conclusions.

In general, the DW water quality was exceptional, regardless of the raw water solution make-up 

or net concentration of dissolved salts in the raw water. This result was as-expected and serves 

to verify that the AltelaRain® technology is an excellent process for treating the various solutions 

involved with natural gas production on the Marcellus Shale.

The mass balance analysis performed on the raw water and concentrate water samples yielded, 

for the most part, results within expected levels. It should be noted that, as previously verified, 

there is some water chemistry taking place in the solutions as the raw water solution is 

concentrated to higher and higher salt concentration levels. This results in “changes” to the mass 

of specific constituents in the solutions. This is expected and the mass balance analysis simply 

provided verification of known water chemistry issues that have been obtained on the Altela test 

bench apparatus or from similar testing performed with Altela pilot systems used on other natural 

gas production sites. The Altela process is a useful process as it requires little to no pretreatment. It allows for the treatment of deep well water on site. It helps reduce the amount of 

waste produced and transported off site. In order to keep the process up and running, a small 
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amount of acid may be used to extend the useful run life between maintenance. However, there 

is need for regularly scheduled distillation column maintenance. The scale which may be formed 

must be periodically removed. The design of the system must include the down time associated 

with such routine maintenance. 

Recipient completed the system specification document and delivered it to DOE on April 12, 

2010. As part of the final analysis of this water on the test-bench scale, the testing produced 

clean DW and yielded results consistent with previous experience, and as such, field deployment 

of a test system for further process verification of Marcellus Shale produced and frac flow-back 

waters was highly recommended as part of the Continuation Application. Recipient received 

approval of a Go-Decision on May 12, 2010 from the Contracting Officer that provided 

notification and authorization to proceed to the next phase of the project. 

4. SYSTEM OPERATIONS REPORT

4.1 Summary

The ARS-4000 System Specification document previously provided by Recipient to NETL 

outlines the technical approach employed by the AltelaRain® ARS-4000 water treatment system. 

A brief description of the demonstration system follows. 

The Altela ARS-4000 System is a fully automated water treatment process designed to operate 

24 hours a day, 7 days a week. In most cases the system will be installed in a remote area 

directly at a natural gas or oil well site. The operator should visit the site daily for system 

monitoring or routine maintenance actions that should require approximately 1 hour per site visit. 

To assure continuous operation of the Altela system a reliable remote monitoring capability is 

installed to provide the remote operator with a visual means of monitoring key system data. The 

remote monitoring system has an “auto-dial” feature that will notify the operator any time an 

alarm situation occurs. The Altela ARS-4000 system is controlled by a Programmable Logic 

Controller (PLC). The PLC has built-in data logging capability and is programmed with a 

control logic that monitors many system outputs continuously during operation. The logic is 

designed so that any time a failure condition is sensed, the PLC automatically shuts down the 

system through one of two shutdown modes. The normal, or “controlled shutdown” will 

automatically turn off each piece of equipment in a methodical and controlled sequence. The 

“emergency shutdown” will turn off all operating equipment immediately. The operator can 

trigger either shutdown mode as required at the push of a button, either at the unit or computer 

from any remote location.

The Altela system treats produced water by a thermal distillation process. In simple terms, the 

Altela system converts incoming dirty water into two components – clean distilled water plus a 

concentrated solution of dirty water (CW). The Altela system is a waste reduction process, 

meaning the incoming dirty water volume is reduced by up to 80%. The remaining 20%, a 
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concentrate of the original dirty water, must be disposed of through conventional methods. The 

process begins with the produced water that is collected in an on-site holding tank. This water is 

transferred via pump into the Altela containerized system. Once inside the Altela ARS-4000 

system, the produced water is circulated continuously through ten AltelaRain® “towers.” The 

towers are designed to evaporate pure water from the brackish produced water. The evaporated 

water is then condensed within the same tower, on the opposite side of thin plastic sheet. The 

condensed water, which is of distilled water quality, is collected and transferred from the towers 

to a “distilled water” (DW) holding tank. The concentrated water (CW, the second component 

of water exiting the towers) is eventually concentrated up to five times higher dissolved solids 

content and then pumped out of the Altela system for eventual disposal. Likewise, the distilled 

water is also pumped from the system and available for recycling and related beneficial, 

productive uses.

Milestone 6, “System installed, tested and in full operation” was started on June 9, 2010 and was 

completed on July 22, 2010. As of April 8, 2011, over 299,040 gallons of Marcellus Shale frac 

flow-back water have been treated and purified at the well-site, resulting in the production of 

200,215 gallons of clean distilled water. The concentrated water generated during this time 

period equal 75,430 gallons (1,796 barrels), representing approximately 75% volume reduction 

in the original amount of brackish water. This percentage is known as the Recovery Rate (RR), 

and is defined as RR = 1-CW/PW. 

Following Milestone 6, the System continuously treated water beginning July 26, 2010. The 

volume of incoming water that is eliminated from trucking to a disposal site is known as the 

Treatment Rate (TR). The amount is given simply by TR = PW-CW. The absolute amount of 

water eliminated from trucking during this time period was 223,610 gallons (5,324 barrels). The 

average daily TR for this reporting period is 27.46 Barrels per Day (BPD), normalized for the 

time the well-site was operational (providing water to be treated and natural gas to the system). 

Additional charts and graphs are included in Appendix H.
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Several factors contributed to a lower Treatment Rate than initially projected. As outlined in the 

application, under optimum conditions, the ARS-4000 System can process approximately 100 

BPD through the system. The system recovery rate is a function of water quality but a recovery 

rate of up to approximately eighty (80) barrels per day Treatment Rate was anticipated (80% 

recovery rate). The actual field Treatment Rate had been adversely affected by different issues 

caused both by external well-site problems and internal Altela system mechanical problems. 

Mechanical issues that affected the Treatment Rate range from tower issues to individual 

mechanical components (e.g., off-the-shelf pump failures) operating inside the system. Other 

external issues contributing to a lower Treatment Rate included well-site shut-downs in 

either/both natural gas and water to treat. Weather conditions hindered the system performance 

as well. The figure above illustrates that the well-site was completely non-operational on several

occasions as outlined below, especially in the beginning of the Phase I time period.

In addition to the numerous well-site problems, the first internal issue affecting the Treatment 

Rate was that the system was designed to operate on 14 towers, however; we discovered that it is

only able to operate on 10 towers at one time. The first demonstration towers were found to 

accept more steam than originally thought. Ironically, each tower yielded greater capacity at its 

maximum operating conditions than originally thought, but this in turn resulted in the System’s 

boiler being under-sized for the full complement of 14 towers. Specifically, maximum steam 

output from the 25 HP Ajax boiler was 863 lb/hr. Once the boiler is de-rated to a nowrecommended operating efficiency of 80%, maximum output of the boiler was found to be only 

690 lb/hr. This is equivalent to only 49.3 lb/hr (5.9 GPH) for 14 towers, still only 69 lb/hr (8.3 

GPH) for a lessened 10-tower operation.

As originally designed, the steam input needed to operate the 14 towers in the system was 

thought to be 583 lb/hr (41.6 lb/hr; 5.0 GPH), while the steam input for 10 tower operations was

416 lb/hr (41.6 lb/hr; 5.0 GPH). Even though the boiler is sized to supply a steam output of 690 

lb/hr, this is 15% higher than the amount of steam that is needed to operate the 14 towers. 

Therefore the Ajax boiler is operating at the high end of its operation limits leading to 

“carryover” from the boiler into the towers, lowering the performance of the towers significantly. 

The decision to operate on 10 towers was made. At a steam input requirement of 416 lb/hr, the 

boiler is able to supply the proper amount of steam to the towers. 

The towers operated best when they were supplied with a constant supply of steam. We now 

know that this is not achieved using the Ajax boiler because as it is on/off style of boiler instead 

of the more preferable modulated flame boilers. The pressure differential is approximately 4 to 5 

psi between the boiler flame coming on and shutting down with the Ajax boiler. This hinders the 

performance of the tower because of the change in steam temperature as the pressure changes,

leading to the tower temperatures changing a few degrees when the boiler is cycling. These 

boiler issues led to the Treatment Rate being lower on the system than what we now know is 

possible using higher-quality modulated boilers in the future.
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The lower Treatment Rate may also be associated with scaling occurring on the tower gauze. 

The gauze located in the evaporation section of the tower helps to wick the PW across the 

evaporation area. Scaling on the gauze hinders this wicking affect as well as limits thermal heat 

transfer vital for the towers to operate effectively. Previously, an injection of Muriatic Acid was 

added to the incoming PW to the towers to keep a pH of 4.5 which helps control the amount of 

sulfates that accumulate on the internal gauze of the towers. An acid wash was completed on the 

system in an attempt to remove or reduce the amount of scale on the gauze. Investigations 

continue to better understand this field operational issue. Future towers will likely be 

manufactured with a different wicking material. Additional factors that affected the Treatment 

rate included the down time required to fix or replace mechanical components.

Several shut-downs were related to gas interruptions at the well-head. These issues were

addressed quickly and the system was turned back on and resumed treatment. In addition, 

Recipient had experienced a shut-down during one quarter due to a system integration issue 

associated with the RS Logix program. A minor shut-down was associated to a mechanical issue 

with a float in the boiler blow-down tank. Periodic maintenance caused several brief, scheduled 

shut-downs of the system. Other system shutdowns included mechanical component failures

such as the Main CW Transfer pump, a DW Out Conductivity sensor reading improperly, and 

float failures on the transfer. These one-time ‘learning curve’ failures are expected due to the

24/7 operation as well as the harsh environment and materials that were treated by the system. 

Other issues affecting the Treatment Rate were external to the system. One major reason for 

shutdowns were associated with the natural gas well. Initially, the gas well was only hooked up 

to the system and not to the collection pipeline, leading to failed controllers on the gas well unit 

and eliminating the gas pressure required to operate the Ajax boiler. After a few months of 

operation, the gas well unit was hooked up to the pipeline. Continued periodic shutdowns to the 

system were due to a lack of pressure from the gas well itself. On occasion, water from the gas 

well entered the gas well line and caused a shut down. As temperatures dropped heading into 

winter, the presence of water in the natural gas well unit itself caused some problems as well. 

Lower Treatment Rates were also related to suspended solids. As there was no pre-treatment of 

PW prior to entering the system, there was concern about collection of sulfates, iron oxide as 

well as Total Suspended Solids (TSS) collecting on the gauze. Towards the beginning of field 

operations, maple seeds and other debris from the PW pond flowed into the system. This led to 

shutdowns by the tower flows dropping below 2.0 GPM caused by flow meter obstruction of

suspended solids. To address the problem, a 100 micron mesh bag filter was placed in the PW 

line before entering the system. Most but not all suspended solids listed above were filtered. 

The filter was removed and cleaned every three days of accumulation of solids retained.

These types of issues are common in any new product development. The system operated in a 

continuous mode. During automatic shut-downs that occurred, the PLC/SCADA components 

continued to report and track such events. 
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Consistent with Milestone 7, the first quarterly water sampling was taken on September 13, 

2010. These water samples were taken and analyzed by a certified water quality laboratory to 

verify that the system was operating successfully and capable of treating the highly challenged 

Marcellus Shale frac flow-back and produced water. These water quality analyses demonstrated

the system’s ability to successfully treat highly challenged water and, at the same time, produced

extremely clean water output. Copies of the complete water quality analyses have been attached 

to this quarterly report as Appendix C. 

Though the demonstration system had not achieved the projected daily treatment rate, it is 

noteworthy that the system is the first demonstration system that has successfully been operating

in the field at a well-site over such a period of time in the Marcellus. As verified by the field 

water quality analyses to date, the system is capable of treating highly challenged Marcellus 

Shale frac flow-back and produced waters to a level of clean water purity necessary to be able to 

discharge the water directly into the Commonwealth’s surface water supply (i.e. stream 

discharge). The technology performed as anticipated with respect to purifying the water. 

Decreases in treatment volumes had been engineering/well-head system integration in nature 

rather than core science problems associated with the technology. 

4.2 Gas and Electrical Usage

Gas Usage

The Altela process is unique among all water desalination techniques, in that it is driven by lowcost heat, rather than high-cost electricity. In this demonstration setting, the System is powered 

nearly entirely by natural gas (to generate steam by boiling a fraction of the cleaned water). The 

average gas usage was found to be 0.485 MCF/bbl of water eliminated for the period. The 

average price of natural gas during that period was $3.59/MCF. This equates to $1.74/bbl of 

water eliminated. Although low by comparable desalination techniques, this OpEx expense is 

likely to decrease further in future units with more efficient boilers.

Electrical Usage

Electrical usage, per gallon of water treated, is estimated below, since no electrical meter exists 

solely on our System. Average wattage for ARS-4000 System is approximately 3.1kW. Total 

runtime as of April 8th, 2011 was 4,358 hours. Electricity usage during that period is estimated 

to be 13,510 kWH. Average cost of electricity in PA during that time period was approximately 

$0.136 kWH. Total cost of electricity for operating the system is estimated to $1,837. This 

equates to a per gallon electricity OpEx of $0.0082/gallon ($0.345/bbl).

4.3 Concentrate Disposal

The Concentrate Water (CW) stream is the residual liquid solution remaining after 

approximately 80% of the pure distilled water has been removed via the AltelaRain® treatment 
DE-FE0000833 2010

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process. The residual CW solution contains nearly 100% of the salts and other constituents 

contained in the original volume of Produced Water (PW) processed through the demonstration 

system. The residual CW is removed from the site and transferred to approved commercial 

produced water disposal facilities. Specifically, the CW is transported to Hart Resource 

Technologies, 5035 Route 100, Creekside, PA, 15732. Hart Resources has two facilities –

Josephine Brine and Franklin Brine. Depending on capacity, both facilities have been used for 

the disposal of the CW from the demonstration project. Prior to April 19th, Hart Resources 

Technologies charged $0.06 per gallon for disposal (2.52/bbl). In addition, the trucking cost to 

either site was approximately $0.08 to $0.10 per gallon for a total CW disposal cost equal to 

$0.14 to $0.16 per gallon (equivalent to $5.88 to $6.72 per barrel). Assuming a total average 

Trucking and Disposal cost of $0.15/gallon ($6.30/barrel), results in an absolute cost of $11,315

to dispose of the 75,430 gallons (1796 barrels) of CW during the period.

The chart below outlines the volume of CW production from commencement of the system 

operations.

4.4 Estimated Costs

Estimated Per Barrel Labor

A total of approximately 495 hours of labor was required during the project. Dividing the 

223,610 gallons (5,324 barrels) of water eliminated (TR) by this results in an approximate per 

barrel labor rate of 0.00221 hours/gallon (0.09297 hours/bbl). An hourly maintenance worker at 

$30/hr results in total labor costs of approximately $14,850 and per gallon and per barrel costs of 

$0.066/gal and $2.789/bbl respectively. It should be noted that this amount is likely inordinately 

Cost
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high because both (i) this initial demonstration testing was a first of its kind, and experience 

learning will reduce further in such installations and (ii) the very nature of this NETL project 

requires special labor costs not found in future real-world on-site water treatment.

Estimated Per Barrel Consumables Cost

Consumable costs during the period were quite low. Final cost of consumable (filter bags) 

totaled $53.24. The estimate of consumables per barrel costs equal $0.01/bbl.

Estimated Total Per Barrel Cost

The total per barrel operating cost (OpEx) during the period was $4.88/barrel ($0.12/gal). This 

was calculated by summing the individual OpEx costs listed below:

• Gas Cost: $1.74/barrel of water eliminated

• Electric Cost: $0.345/barrel of water eliminated

• Labor Cost: $2.789/barrel of water eliminated

• Consumables Cost: $0.01/barrel of water eliminated

This total per barrel operating cost (OpEx) of $4.88/barrel ($0.12/gal) reflects the per barrel cost 

of the water eliminated from trucking and disposal (TR=PW-CW). It does not include the cost 

of disposal of the concentrate, but it also did not divide these costs by the larger number of “how 

much input water was treated”. The cost calculations can (and should) be done two different 

ways: (a) as above, based only on the net volume of water eliminated from trucking and 

disposal, TR = PW-CW; and (b) based on the volume of water treated, PW.

The latter method yields a total per barrel operating cost (OpEx) of $4.88/barrel ($0.12/gal) and 

reflects the per barrel cost of the water brought into the System (PW). It therefore includes the 

cost of disposal of the Concentrate Water (CW). Total water treated (PW) equaled 7,120 barrels, 

and OpEx costs were:

• Total Gas Cost: $9,264 ($1.74/barrel TR X 5,324 barrels)

• Total Electric Cost: $1,837 ($0.345/barrel TR X 5,324barrels)

• Total Labor Cost: $14,850 ($2.789/barrel TR X 5,324 barrels)

• Total Consumables Cost: $53 ($0.01/barrel TR X 5,324 barrels)

• Total Disposal Cost: $11,315 ($6.30/barrel TR X 1,796 barrels)

Total OpEx costs, including CW disposal, were therefore $37,319. The resulting per gallon and 

per barrel costs were $0.125/gallon and $5.24/barrel, respectively. This represents a savings of 

17% over trucking and disposal without the Altela System (1-$5.24/$6.30). Factors causing the

reduction of savings over the 28% reported during Phase 1 are noted in the Executive Summary. 

It is noteworthy that recent regulatory changes this past year have increased traditional trucking 

and disposal costs which are material to the above analysis. A significant volume of Marcellus 
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Shale wastewater is being disposed of in Ohio in UIC re-injection wells. Ohio has passed 

regulations increasing the price for such disposal. For example, according to the Ohio Division 

of Mineral Resources Management (ODNR), “With the passage of Senate Bill 165 in 2010, some 

changes to the UIC Program include an increase in the Class II saltwater injection permit 

application fee from $100 to $1000, and an injection disposal fee of $.05 per barrel for brine 

originating in-district and $.20 per barrel for brine originating out-of-district.” These UIC 

disposal surcharges for out-of-district brine disposal are increasing total disposal costs to the 

E&P operators. In addition, beginning in January of 2011, PA DEP amended Title 25, Chapter 

95, Wastewater Treatment Requirements, to address the dramatic increase in Marcellus Shale 

wastewater that was being diluted and sent into PA’s surface water bodies. The new 95 

regulation included more stringent discharge standards including 500 mg/L for Total Dissolved 

Solids (TDS) and 250 mg/L each for Sulfates and Chlorides.

As a result of PA DEP’s Chapter 95 regulation and ensuing enforcement efforts by PA DEP in 

May of 2011, the per barrel market price for disposal of Marcellus Shale wastewater has 

increased significantly due to increased costs to comply with the new discharge regulations. 

Operators have reported per barrel costs exceeding $8.50 per barrel with further increases based 

on proximity to Ohio or to limited disposal sites still available in Pennsylvania. This in turn, has 

made new technologies like the AltelaRain® process to be more economical and thereby gain

additional market traction. Taking into account this new regulatory market dynamic, industry 

can currently realize a savings of 38% over trucking and disposal without the Altela System (1-

$5.24/$8.50). 

5. LIFE CYCLE ANALYSIS REPORT

5.1 Approach

A hybrid life cycle assessment (LCA) approach was used to estimate the environmental 

performance of the system. Hybrid life cycle assessment combines a traditional process based 

life cycle assessment approach with an economic input-output life cycle assessment (EIO-LCA) 

approach to expand the system boundaries and include impacts for process where detailed 

information is unavailable (Williams 2004). Using this approach energy consumption and 

greenhouse gas (GHG) emissions were calculated on a life cycle basis. 

The Analysis will compare the Altela 4000 mobile test system with the improved Altela 600 

stationary system as well as trucking produced water to Ohio for deep well injection. In addition 

a fourth scenario was analyzed assuming the Altela 600 could be paired with a waste heat source. 

Four main stages of the life cycle were analyzed: operations, capital equipment manufacturing, 

transportation, and waste disposal. Of the four stages, three, operations, transportation, and 

waste disposal were analyzed using the process LCA approach. Capital equipment 

manufacturing was be analyzed using the EIO-LCA methodology. 
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The functional unit for the analysis is a single barrel of produced water entering the system. 

Energy consumption is calculated as total primary energy consumption in BTUs and GHG 

emissions are calculated in g CO2e. For the Altela systems a treatment rate of 75% is assumed 

for all systems based upon the field results for the Altela 4000. This means for each barrel 

entering the system 0.75 bbl are fully treated by the system and 0.25 bbl must be disposed of by 

conventional methods. In this analysis trucking to Ohio for deep well injection was the assumed 

disposal method. 

The Argonne National Laboratory Greenhouse Gases, Regulatory Emissions, and Energy Use in 

Transportation (GREET) model was used to develop life cycle energy and emissions factors. 

These emissions factors incorporate upstream impacts such as fuel production and processing. 

The emissions factors used for the energy sources included in this analysis are shown below:

Impact Factors (From GREET v1.8d.1)

Energy Source Primary Energy 

(btu/btu)

GHG 

g/mmbtu

Natural Gas 1.07 69,815

Diesel 1.13 83700

Electricity 2.51 211,754

5.2 Operations

Operations impacts were calculated based upon measured energy consumption values. The 

sources of energy consumption included in the analysis were natural gas to feed the boiler which 

drives the treatment process and electricity to run additional equipment such as pumps, blowers, 

sensors, and control electronics. For the Altela 4000 system operational performance data used 

was from a 58 day period in September and October of 2010. Energy consumptions values for 

both systems are shown below. For the Altela 600 scenario where waste heat is utilized, natural 

gas consumption is assumed to be zero. 

Operational Energy Consumption per barrel of water treated

System Natural Gas 

(MCF/bbl)

Electricity 

(kWh/bbl)

Altela 4000 0.45 2.03

Altela 600 0.20 2.48

5.3 Capital Equipment Manufacturing

Impacts for capital equipment manufacturing were calculated based upon the EIO-LCA 

methodology. A detailed cost breakdown of the system was combined with economic sector 

specific impact factors obtained by the EIOLCA.net life cycle assessment model (CMUGDI 
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2011). Impact factors in the EIOLCA.net model were in 2002 dollars so they had to be adjusted 

to 2010 dollars using the latest producer price index values (Economagic 2011). A lifetime of 10 

years was assumed for all equipment. A utilization rate of 60% was assumed for the Altela 600 

system and the average treatment rate of 37 bbl/day was used for the Altela 4000.

5.4 Transportation

Transportation impacts are included for the Altela 600 system. Since the system is at a 

centralized location, water will need to be trucked from surrounding wells to this location. The 

average distance from well pads to the treatment facility was assumed to be 30 miles. Fuel 

consumption was calculated for a round trip, with trucks were assumed to get 5 mpg while fully 

loaded and 7 mpg on the return trip. 

5.5 Waste Disposal

Waste disposal is assumed to be trucking to deep well injection sites in Ohio. This disposal 

method was selected due to recent regulatory actions in Pennsylvania restricting the use of 

conventional treatment and disposal facilities that do not remove TDS. In addition, in order for 

the Altela systems to effectively reduce salt loads to surface waters, the highly concentrated 

waste brines should be disposed of through deep well injection. The transportation distance for 

disposal was estimated based upon the average distance between the location of the Altela 4000 

test site and the five nearest disposal wells in Ohio (Veil 2010). This distance was calculated to 

be approximately 150 miles. Fuel consumption was calculated assuming the same fuel 

efficiency used for determining the transportation impacts. 

Energy required for deep well injection was previous calculated by Argonne for a yet to be 

published study based upon the average injection pressure of a number of injection wells in the 

western United States. From this analysis the energy requirements for injection were estimated 

to be 0.6 kWh/bbl. 

5.6 Results

The results of this analysis are shown in the figures below. Figure A shows the life cycle energy 

consumption for the four scenarios. For the Altela 4000 and 600 systems the energy 

consumption is dominated by the operations stage, specifically from natural gas consumed to 

generate steam. The waste heat scenario illustrates that there is a significant opportunity to 

reduce energy demand (and costs) by pairing the Altela 600 with a low-grade waste heat source. 

The energy consumption for manufacturing the system itself is quite small, at least when 

averaged over the entire expected lifetime of the system. Energy for transportation is not 

insignificant, but small relative to the operational energy consumption and the significantly 

higher efficiency of the centralized Altela 600 systems appears to outweigh the lack of 

transportation required for the Altela 4000. However it is possible that this efficiency difference 

could be narrowed with an improved, optimized version of the mobile system. 
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Figure A. Life Cycle Energy Consumption for Water Treatment

Figure B shows the life cycle GHG emissions for each scenario. The GHG emissions data

largely track the energy consumption trends. This is not surprising given that the majority of 

GHG emissions result directly from combustion of fossil fuels. 

Figure B. Life Cycle GHG Emissions for Water Treatment

5.7 Analysis

While both the Altela 4000 and 600 systems are still currently more energy and GHG intensive 

than simply trucking water for disposal there are additional benefits beyond energy and 

emissions. Both systems would significantly reduce truck traffic required for water 

management. Increased truck traffic is one of the largest complaints of citizens in areas of active 

0

50,000

100,000

150,000

200,000

250,000

300,000

350,000

400,000

450,000

4000 600 600 waste 

heat

injection

Life cycle energy BTU/bbl

Life Cycle Energy Consumption

Waste Disposal

Tranportation

Capital

Operations

0

5,000

10,000

15,000

20,000

25,000

30,000

4000 600 600 waste 

heat

injection

Life cycle GHG emissions g CO2e/bbl

Life Cycle GHG Emissions

Waste Disposal

Tranportation

Capital

Operations
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gas development. The availability of disposal wells is also likely to decline in the future as 

demand increases, potentially increasing costs and the distance to available wells. 

The Altela systems also produce as much 0.66 bbl of purified water for every barrel of produced 

water treated. This water can be returned to operators reducing stress on fresh water resource. 

The exact amount of purified water produced varies somewhat depending on operating 

conditions since the clean water is utilized for steam production which drives the system and 

some of this water is exhausted from the system as saturated water vapor. 

The life cycle assessment results show that experience gained from the Altela 4000 field tests 

have helped improve the system design and resulted in a 45% increase in overall energy 

efficiency for the newer Altela 600 system. In the future, if suitable sources of low grade waste 

heat can be located and systems co-located to take advantage of them (co-generation projects), 

the system efficiency can improve as much as 85% from the original test system. 

CONCLUSION

This project successfully delivered field-proof that the AltelaRain® technology is capable of 

treating Marcellus frac water to water quality standards required for discharge and/or applicable 

beneficial re-use, numerous water quality analyses of the treated water were taken. Both benchscale water quality analyses and the first field-based quarterly water sampling verified the system 

was operating successfully and capable of treating the highly challenged Marcellus Shale frac 

flow-back and produced water to requisite levels. 

The project delivered field proof that the treatment technology can economically treat the frac 

water at a cost equal to or lower than current disposal methods. Specifically, the resulting per 

gallon and per barrel costs were $0.125/gallon and $5.24/barrel, respectively. This represents a 

savings of 17% over trucking and disposal without the Altela System. This cost savings 

increases to 38% when trucking and disposal market pricing, post May 19th 2011, is taken into

account following Chapter 95 discharge limit enforcement.

As a result of PA DEP’s Chapter 95 regulation and ensuing enforcement efforts by PA DEP in 

May of 2011, the per barrel market price for disposal of Marcellus Shale wastewater has 

increased significantly due to increased costs to comply with the new discharge regulations. 

Operators have reported per barrel costs exceeding $8.50 per barrel with further increases based 

on proximity to Ohio or to limited disposal sites still available in Pennsylvania. 

UIC disposal surcharges for out-of-district brine disposal are increasing total disposal costs to the 

E&P operators. For example, according to the Ohio Division of Mineral Resources Management 

(ODNR), “With the passage of Senate Bill 165 in 2010, some changes to the UIC Program 

include an increase in the Class II saltwater injection permit application fee from $100 to $1000, 

and an injection disposal fee of $.05 per barrel for brine originating in-district and $.20 per barrel 

for brine originating out-of-district.” In addition, January of 2011, PA DEP amended Title 25, 
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Chapter 95, Wastewater Treatment Requirements, to address the dramatic increase in Marcellus 

Shale wastewater that was being diluted and sent into PA’s surface water bodies. The new 95 

regulation included more stringent discharge standards including 500 mg/L for Total Dissolved 

Solids (TDS) and 250 mg/L each for Sulfates and Chlorides.

As outlined in this report, the life cycle assessment results indicate that experience gained from 

the Altela 4000 field tests have helped improve the system design and resulted in a 45% increase 

in overall energy efficiency for the newer Altela 600 system. In the future, if suitable sources of 

low grade waste heat can be located and systems co-located to take advantage of them (cogeneration projects), the system efficiency can improve as much as 85% from the original test 

system. Altela is in discussion with several entities to pursue this co-generation approach. 

Finally, with respect to demonstrating that the regulatory environment support implementation of 

the water treatment technology solution, this report provides a review of the regulatory

requirements as well as confirmation that the regulatory environment supports implementation of 

the AltelaRain® water treatment technology solution in Pennsylvania’s Marcellus Shale Basin. 

References

Carnegie Mellon University Green Design Institute, 2011, Economic Input-Output Life Cycle Assessment (EIOLCA), US 2002 purchaser model [Internet], Available from:<http://www.eiolca.net> Accessed July 18, 2011.

Economagic, 2011, “Browse US Producer Price Index Data.” http://www.economagic.com/blsppi.htm (accessed 7-

18-11).

Veil, J.A., 2010, “Water Management Technologies Used by Marcellus Shale Gas Producers,” ANL/EVS/R-10/3, 

prepared for the U.S. Department of Energy, National Energy Technology Laboratory, July, 59 pp. Available at 

http://www.ead.anl.gov/pub/dsp_detail.cfm?PubID=2537. 

Williams, E., 2004, “Energy Intensity of Computer Manufacturing: Hybrid Assessment Combining Process and 

Economic Input-Output Methods.” Environmental Science & Technology 38: 6166-74.
DE-FE0000833 2010

Page 35 of 35

LIST OF ACRONYMS AND ABBREVIATIONS

CW Concentrated Water

CWA Clean Water Act

DW Distilled Water

EPA Environmental Protection Agency

GPH Gallons per hour

NDPES National Pollution Discharge Elimination System

NETL National Energy Technology Laboratory

NM OCD New Mexico Oil Conservation Division

OpEx Operating Expenses

PA DEP Pennsylvania Department Environmental Protection

PW Produced Water

SOPO Statement of Project Objectives

TR Treatment Rate

UIC Underground Injection Control

USDW Underground Source of Drinking Water
APPENDIX A

PA DEP REQUEST FOR APPROVAL 

OF ALTERNATIVE WASTE 

MANAGEMENT PRACTICES



APPENDIX B

CWM ENVIRONMENTAL, INC. 

SAMPLING PROCEDURES
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 1 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

Sampling Procedure 

Approvals/Date: 

Ryan Shafer, Technical Director 

Anagha Lele, Quality Assurance Officer 

CONTROLLED DISTRIBUTION

Copy No.: MASTER COPY 

Issued To: QAO Desk (accessible 

to all lab personnel) 

1.0 PURPOSE 

1.1 This procedure describes the general requirements for sampling and field measurements 

when obtaining a specimen sample for subsequent analytical testing. 

1.2 The objective of sampling is to collect a portion of material small enough in volume to be 

transported conveniently and handled in the laboratory while still accurately representing 

the material being sampled. 

1.3 Samples may be biological, wastewater, potable water, groundwater, surface water, or 

domestic or industrial wastes. 

1.4 Deviations, additions, or exclusions from this procedure must be documented. 

2.0 SCOPE 

This procedure is applicable to all sampling events planned and conducted by CWM. 

Clients are encouraged to adhere to this procedure. 

3.0 RESPONSIBILITIES 

3.1 Safety is the responsibility of all involved in the planning, collection and handling of the 

samples. Because sample constituents can be toxic, take adequate precautions during 

sampling and sample handling. Precautions may be limited to wearing gloves or may 

include coveralls, aprons, or other protective apparel. Always wear eye protection. 

Label adequately any sample known or suspected to be hazardous because of 

flammability, corrosivity, toxicity, or radioactivity, so that appropriate precautions can be 

taken during sample handling, storage, and disposal. 

3.2 The sampler is responsible for maintenance of a field logbook, with entries printed neatly 

and legibly in ink. Logbooks may be used as evidentiary records in a court of law at 

some future date. 

3.3 The sampler is responsible for documenting any deviations, additions, or exclusions 

applied to a sample set in the field record log, and ensuring that this information is 

forwarded to the laboratory along with routine sample identification information. This 

shall be applicable regardless of the whether changes were initiated due to client request 

or due to conditions in the field. Additionally, these changes must be brought to the 

attention of the project manager as soon as is practicable. 
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 2 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

3.4 The project manager is responsible for transmitting any client-requested deviations, 

additions, or exclusions to this procedure to the sampler, and ensuring that these changes 

are reported with the resultant data. 

3.5 The project manager must notify the client of any deviations, additions, or exclusions to 

this procedure that were not requested by the client, and ensure that these changes are 

reported with the resultant data. 

3.6 The laboratory manager is responsible for ensuring that samplers have been properly 

trained in the techniques appropriate to the requested sampling event. This training must 

be documented. 

4.0 RELATED DOCUMENTS 

4.1 Standard Methods for the Examination of Water and Wastewater, 19th Edition, 

APHA/AWWA/WEF, 1995. Method 1060 F 

4.2 Field Procedures Manual for Water Data Acquisition, NJDEP Division of Water 

Resources, 1987. 

4.3 National Environmental Laboratory Accreditation Conference Standards, Chapter 7, 

Field Activities, Proposed Changes, May 2002 

4.4 CWM cross-referenced documents: 

Document Number Title (may be abbreviated) 

MS Notebook Material Safety Data Sheets (MSDS) Notebook 

QS-001M Laboratory Quality Manual 

SM-001T Sample Containers, Preservation, Holding Time 

SM-101P Sample Acceptance Policy 

SM-102P Sample Receipt & Tracking 

SM-002P Sampling Procedure - Micro 

SM-003P Sampling Procedure - Oil & Gas Plat Collection 

SM-004P Sampling Procedure - Atlas Oil & Gas Plat Collection 

5.0 PROCEDURE 

5.1 Planning 

5.1.1 Parameters 

Determine what pollutants and/or physical environmental conditions are to be 

monitored. Make a list of analytical requests based on applicable client permits, 

regulatory requirements, review of provided data, and/or specific client input. 

5.1.2 Sample Scheduling 

Develop a projected sampling schedule, taking into consideration factors such as 

laboratory workload, periodic monitoring requirements (e.g., is the project for 
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 3 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

quarterly compliance monitoring?), hold times, analysis time (will you need to 

pay overtime to have someone read results on the weekend or a holiday?), and 

client expectations. 

5.1.3 Sample Containers 

5.1.3.1 Refer to work instruction SM-001T, Sample Containers, Preservation, 

and Hold Time to determine the type, size and quantity of sample 

containers for all analyses identified in Section 5.1.1. The volumes 

identified in SM-001T are the minimum quantities required. It does 

not provide enough sample volume for reanalysis or for laboratory 

duplicates and matrix spikes. For one in every 10 or 20 samples, 

collect enough volume to perform the analysis three times (one for the 

sample, one for the duplicate, and one for the matrix spike). 

When determining what containers are needed, also take into 

consideration what parameters can be grouped together from the same 

bottle to minimize the number of sample containers needed. 

5.1.3.2 Obtain the needed bottles and label them with the appropriate 

parameters to be tested from the respective bottles. If the analysis 

requires chemical preservation, add the preservative to the bottle prior 

to leaving the laboratory and clearly mark the bottle with the 

preservative added. 

Note 1: Be sure to use pre-cleaned bottles if requested by the client. Ensure that 

a copy of the certificate is forwarded to the project file for the sampling event. 

Record the lot numbers of any preservatives added to the bottles. 

Note 2: For litigation samples, or if requested by the client, initiate the chain-ofcustody at the time bottles are prepared, and ensure that the sampler signs the 

receipt from the laboratory. 

Note 3: For volatiles and if required for other analytes by the client, include a 

trip blank with the bottle order. If field blanks are to be collected, provide 

laboratory reagent water to prepare the blanks. 

Note 4: If soluble components are requested, and the samples are to be field 

filtered, provide extra bottles to collect total and soluble samples. If the sample 

is to be filtered for soluble components, DO NOT preserve until AFTER 

filtering. 

5.1.4 Sampling Equipment 

Determine what type of sampling equipment will be needed. Ensure that it will 

be available when needed and is clean, in working condition, and ready for use. 

This includes verifying and documenting that calibrations are current and/or the 

materials needed to calibrate in the field are available and traceable, as 

appropriate. Cleaning of sampling equipment is addressed in the respective 

equipment procedures. 
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 4 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

5.1.5 Field Measurements 

If any field measurements are planned, ensure that the necessary instruments are 

available and that required quality control has been performed. Ensure that 

appropriate materials needed to calibrate in the field are available and traceable, 

as appropriate. 

5.1.6 Field Log 

Field records shall be recorded on a sample chain-of-custody form. Records shall 

include the following, as appropriate, for the interpretation of test results. 

5.1.6.1 Sampling/field measurement organization, including address, phone 

number, and email address 

5.1.6.2 Printed name and signature of technician, plus names of all members 

of the sampling team 

5.1.6.3 Sample type (grab, composite, etc.), including an identification of the 

matrix sampled; (aqueous, solids, etc.) 

5.1.6.4 Sample identification number including a unique field identification 

code for each sample container 

5.1.6.5 Reason for sampling/measurement 

5.1.6.6 Date and time of sampling/measurement 

5.1.6.7 Location of sampling, including any diagrams, sketches, or 

photographs; name of sampling station, and/or latitude, longitude, and 

altitude when sample point is not otherwise identified 

5.1.6.8 For water sampling: the water level measure, sample depth, and water 

discharge rate, if appropriate or required 

5.1.6.9 Reference to the sampling plan and procedures used, including field 

blanks, spikes and duplicates; field instrument calibration, span, drift, 

and calibration standards; sampling system bias and response time; 

and field test standards and reagents as required by the standard/test 

method 

5.1.6.10 Sample preservation, transportation, and storage, including a 

description of sample containers and chain of custody 

5.1.6.11 Details of any conditions during sampling that may affect the outcome 

or interpretation of the test results 
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 5 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

5.1.6.12 Any standard or other specification for the sampling method or 

procedure, plus any deviations, additions to or exclusions from the 

specification concerned 

5.1.6.13 Certification from the organization collecting the samples that samples 

and field measurements were collected in accordance with NELAC 

standards or provide reasons and/or justification if they were not. 

5.2 Sample Collection 

5.2.1 Samples will generally be a grab or composite. 

 Grab: a sample collected at a particular time and place. 

 Composite: a combination of grab samples collected at the same point over 

different times. The procedure for compositing must be documented for each 

sampling event. 

5.2.2 Obtain a sample that meets the requirements of the sampling program and handle 

it so that it does not deteriorate or become contaminated before it reaches the 

laboratory. In water sampling, before filling the sample bottle, rinse it two or 

three times with the water being collected, unless the bottle contains a 

preservative or dechlorinating agent. If the bottle already contains preservative, 

take care not to overfill the bottle to prevent loss or dilution of the preservative. 

5.2.3 Representative samples of some sources can be obtained only by making 

composites of samples collected over a period of time or at many different 

sampling points. 

5.2.4 Collect the sample carefully to ensure that analytical results represent the actual 

sample composition. Important factors affecting results are the presence of 

suspended matter or turbidity, the method chosen for its removal, and the physical 

and chemical changes brought about by storage or aeration. 

5.3 Sample Handling, Preservation and Labeling 

5.3.1 General Sample Handling 

5.3.1.1 Obtain a sample that meets the requirements of the sampling program 

and handle it so that it does not deteriorate or become contaminated 

before it reaches the laboratory. In water sampling, before filling the 

sample bottle, rinse it two or three times with the water being 

collected, unless the bottle contains a preservative or dechlorinating 

agent. If the bottle already contains preservative, take care not to 

overfill the bottle to prevent dilution or loss of the preservative. 

5.3.1.2 Representative samples of some sources can be obtained only by 

making composites of samples collected over a period of time or at 

many different sampling points. 
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 6 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

5.3.1.3 Sample carefully to insure that analytical results represent the actual 

sample composition. Important factors affecting results are the 

presence of suspended matter or turbidity, the method chosen for its 

removal, and the physical and chemical changes brought about by 

storage or aeration. 

5.3.2 Special Sample Handling 

5.3.2.1 Bacteriological Samples. Sterile bottles containing sodium thiosulfate 

must be used. 

5.3.2.1.1 Choose a tap that is frequently used for drinking. Remove 

the screen or aerator and allow the cold water to run for 2-3 minutes. 

Remove the lid and fill the bottle without rinsing. Do not overfill. Do 

not touch the inside of the bottle or lid. Secure the lid tightly and 

refrigerate. Relevant COC information must be completed. 

5.3.2.2 Dissolved Oxygen Samples 

3.3.2.2.1 If dissolved oxygen is not done in the field, a glass BOD 

bottle must be used. Fill the bottle to the top and stopper and cap the 

bottle immediately. Preferably, the bottle should be completely 

immersed in the water being tested; after the bottle fills, cap and 

stopper the bottle while continuing to immerse it. 

5.3.2.3 Volatile Organic Samples 

5.3.2.3.1 VOCs must be collected in glass 40-ml vials with no 

headspace. Do not rinse the bottles. Refer to SM-001T for 

preservation and hold time requirements. 

5.3.2.4 Composite Samples. The following cannot be analyzed from a 

composite sampler: 

Dissolved Oxygen Volatile Organics 

Bacteriological Temperature 

Oil & Grease Phenols 

Petroleum Hydrocarbons 

5.3.3 Sample Preservation 

Refer to work instructions SM-001T, Sample Containers, Preservation, and Hold 

Time. Samples must be shipped and stored with proper preservation. Holding 

time commences with the collection of the sample. If hold time is less than 48 

hours, time of analysis must be recorded and verified to meet requirements with 

collection of the sample. 

When fixing a sample (with an acid or base) to a specific pH, use the following 

steps to check the sample pH: 
Sample Management 

Sampling Procedure 

Document No.: SM-001P_03 

Effective Date: 01/01/09 

Page No.: 7 of 7 

Controlled Copy on Gray Paper, Do Not Duplicate 

5.3.3.1 Use the appropriate prepared acid or base solution from the lab to 

preserve the sample. Make sure the acid preservatives dispenser is 

labeled correctly to directly tie it to its preparation. 

5.3.3.2 For acid preservation, a pH of less than 2 is required. For basic 

(alkaline) preservation, a pH of greater than 10 is required. Use 

appropriate pH strips to test a small portion of the preserved sample to 

verify that the required pH has been achieved. 

5.3.4 Acid Preservatives Preparation: 

5.3.4.1 Laboratory uses (1:1) HN03, (1:1) HCl & (1:1) H2S04 acid 

preservatives for pH preservation. 

5.3.4.2 A separate acid preservatives preparation log is maintained to record 

the preparation details. 

5.3.4.3 Acid dispensers are clearly labeled with date of preparation, details of 

stock solution and recent calibration check. 

6.0 RECORDKEEPING 

Records generated as a result of the sampling and/or field testing process are included 

with the chain of custody. 

7.0 QUALITY CONTROL

Records kept for sampling include the chain of custody, field data sheets and LIMS 

generated data sheets (where applicable – Ground Water Field data is entered in LIMS 

directly from COCs) that are used for reportable field measurements. COCs are reviewed 

to ensure all information is present. 

8.0 REVISION SUMMARY

No. Summary of Changes 

00 Initial release 

01 Revised to include the reference to Microbiological Sampling SOP, Section 4.4 

02 Revised header effective 01/01/05, Section 7.0 to include LIMS data sheets. 

03 Replaces SM -001P_02 eff 01/01/05. Annual Review 2009. Updated to correct 

the deficiencies identified during Reliant Audit (NOV 08). Added section 5.3.4. 
APPENDIX C

WATER QUALITY REPORTS 

(PRODUCED WATER, FRAC WATER 

AND FRAC FLOW-BACK WATER)
WATER QUALITY REPORT

#02100194

PRODUCED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

pH 6.17 SU SU SM4500 H+B 2/5/10 13:10 AML

Total Dissolved 

Solids

195,130 mg/l 5 mg/l SM 2540 C 2/5/10 14:49 RCS

Total Suspended 

Solids

403 mg/L 3 mg/L SM 2540 D 2/5/10 11:44 RCS

Oil & Grease 0.9 mg/l 5 mg/l EPA 1664 Rev A 2/5/10 10:20 NJD

COD 6270 mg/L 10 mg/L HACH 8000 2/11/10 10:11 NJD

Surfactants 

(MBAS)

0.344 mg/L 0.025 mg/L SM20-5540 C 2/6/10 2:15 22-293

Heterotrophic 

Plate Count

21 /ml 1 /ml SM 9215B 2/4/10 16:55 WEH

Color 150 pccu 5 pccu 2/4/10 13:36 WEH

Temperature (F), 

Field

40 deg F deg F na 2/4/10 9:27 RCS

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 2/4/10 9:26 RCS

Acidity 404 mg/L 3 mg/L SM 2310 B 2/5/10 0:00 AML

Alkalinity 94.0 mg/l 5 mg/l SM 2320 B 2/5/10 13:11 AML

Hardness, Total 44,431 mg/l 10 mg/l EPA 200.7 2/5/10 10:15 AML

Printed: 3/10/2010 2:58:07PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Bicarbonate 94.0 mg/L 5 mg/L SM4500 CO2 D 2/12/10 11:55 AML

Sulfate 130.0 mg/l 1 mg/l EPA 300.0 2/5/10 13:39 AML

Chloride 108600 mg/L 1 mg/L EPA 300.0 2/5/10 13:35 AML

Fluoride 8.5 mg/l 0.20 mg/l EPA 300.0 2/5/10 13:39 AML

Calcium 15460 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:05 AML

Bromide 1,060 mg/l 0.10 mg/l EPA 300.1 2/5/10 13:41 AML

Iron 68.0 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:10 AML

Magnesium 1415 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:06 AML

Potassium 465.0 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:14 AML

Sodium 21,200 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:15 AML

Gross Alpha DW 3009 PCi/L 3 PCi/L EPA 900 2/17/10 17:44 6502103

Gross Beta DW 416 PCi/L 4 PCi/L EPA 900 2/17/10 17:44 6502103

Radium 226 1448 pCi/L .6 pCi/L EPA 903.1 2/25/10 13:14 6502103

Printed: 3/10/2010 2:58:08PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Radium 228 715 pCi/L .9 pCi/L EPA 904.0 2/24/10 13:53 6502103

Aluminum <2.0 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:07 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:02 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Barium 158.0 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:13 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:01 AML

Boron 11.0 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:13 AML

Cadmium 0.012 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:01 AML

Chromium <0.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:11 AML

Cobalt 0.012 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Lead <0.4 mg/L 0.02 mg/L EPA 200.7 2/5/10 10:12 AML

Lithium, Total 152 mg/L 5.0 mg/L EPA 200.7 2/12/10 9:23 22-293

Manganese 5.2 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:09 AML

Printed: 3/10/2010 2:58:08PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Mercury, Total ND 0.020 mg/L EPA 200.8 2/14/10 15:08 22-293

Molybdenum 0.003 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Nickel <1.0 mg/l 0.05 mg/l EPA 200.7 2/5/10 10:11 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:00 AML

Strontium, Total 2190 mg/L 0.25 mg/L EPA 200.7 2/12/10 9:23 22-293

Thallium 0.006 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:00 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Titanium 0.0058 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Vanadium, Total ND 0.25 mg/L EPA 200.7 2/12/10 9:23 22-293

Uranium ND 1.0 mg/L SW846 6020A 2/18/10 23:53 22-293

Zinc <0.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:12 AML

Osmotic Pressure 2990 mOs/kg 10 mOs/kg PA DEP 2/6/10 6:12 22-293

Printed: 3/10/2010 2:58:08PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Phenolics 0.07 mg/L 0.01 mg/L EPA 420.4 2/17/10 4:39 22-293

BOD >77.9 2 mg/L SM5210B 2/4/10 12:37 TO

Thorium 228 31.0 pCi/L pCi/L HSL-300M 2/26/10 15:15 6502103

Thorium 230 0.181 pCi/L pCi/L HSL-300m 2/26/10 15:15 6502103

Thorium 232 0.058 pCi/L pCi/L HSL-300m 2/26/10 15:15 6502103

Specific 

Conductance

194,800 umhos/cm 2 umhos/cm EPA 120.1 2/8/10 0:00 TO

Iron, Dissolved 16.0 mg/l 0.02 mg/l EPA 200.7 2/18/10 16:02 AML

Copper 0.8 mg/l 0.02 mg/l EPA 200.7 2/5/10 14:09 AML

1,1,2,2-Tetrachloro

ethane

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Printed: 3/10/2010 2:58:08PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

2-Hexanone ND 25.0 ug/L SW846 8260B 2/11/10 19:02 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Acetone ND 50.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Bromide 1140 mg/L 600 mg/L EPA 300 2/10/10 5:03 22-293

Bromochlorometha

ne

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Bromoform ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Carbon Disulfide ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Chloroform ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Chloromethane 10.9 ug/L 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Printed: 3/10/2010 2:58:08PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Diesel Range 

Organics C10-C28

5.9 mg/L 3.1 mg/L SW846 8015D 2/11/10 23:50 22-293

Ethane 120 ug/L 30.0 ug/L RSK 175 2/8/10 21:40 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/9/10 22:27 22-293

Gasoline Range 

Organics

6690 ug/L 2500 ug/L SW846 8015D 2/16/10 22:09 22-293

Methane 52.6 ug/L 10.0 ug/L RSK 175 2/8/10 21:40 22-293

Silica, Dissolved 52 mg/L 5 mg/L SM20-4500SiD 2/17/10 0:44 22-293

Silicon, Total 7.0 mg/L 5.0 mg/L EPA 200.7 2/16/10 13:12 22-293

Total Kjeldahl 

Nitrogen

17.0 mg/L 1.0 mg/L SM20-4500-N C 2/16/10 9:00 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

mp-Xylene 294 ug/L 10.0 ug/L SW846 8260B 2/11/10 19:02 22-293

o-Xylene 60.1 ug/L 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

trans-1,2-Dichloroe

thene

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

trans-1,3-Dichlorop

ropene

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Printed: 3/10/2010 2:58:08PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/6/10 5:48 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/6/10 5:48 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/6/10 5:48 22-293

Ethene ND 30.0 ug/L RSK 175 2/8/10 21:40 22-293

Formaldehyde 9890 mg/L 100 mg/L SW846 8015D 2/18/10 12:01 22-293

Methanol 4330 mg/L 100 mg/L SW846 8015D 2/18/10 20:21 22-293

Benzene 756 ug/L 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Methylene 

Chloride

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,2-Dichloropropan

e

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Printed: 3/10/2010 2:58:08PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Ethylbenzene 27.3 ug/L 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Styrene ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Tetrachloroethene ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Toluene 948 ug/L 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Vinyl Chloride ND 5.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Total Xylenes 354 ug/L 15.0 ug/L SW846 8260B 2/11/10 19:02 22-293

Nitrate <5.0 mg/l 0.10 mg/l EPA 300.0 2/5/10 13:40 AML

Nitrite <5.0 mg/l 0.10 mg/l EPA 300.0 2/5/10 13:41 AML

Nitrate / Nitrite <10.0 mg/l 0.20 mg/l EPA 300.0 2/5/10 13:41 AML

Printed: 3/10/2010 2:58:08PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100194

Altela

NETL Grant

PW

N/A

02/03/10 07:30

02/04/10 08:50

N/A

Grab

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/4/10 16:54 WEH

E Coli NA +/- SM 9223B 2/4/10 16:54 WEH

Sample Comments:

BOD: Duplicate analysis recovery was outside established control limits.

Printed: 3/10/2010 2:58:08PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100193

FRAC WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

pH 7.53 SU SU SM4500 H+B 2/5/10 13:10 AML

Total Dissolved 

Solids

19,630 mg/l 5 mg/l SM 2540 C 2/5/10 14:49 RCS

Total Suspended 

Solids

15 mg/L 3 mg/L SM 2540 D 2/5/10 11:44 RCS

Oil & Grease 3.2 mg/l 5 mg/l EPA 1664 Rev A 2/5/10 10:20 NJD

COD 1253 mg/L 10 mg/L HACH 8000 2/11/10 10:11 NJD

Surfactants 

(MBAS)

0.328 mg/L 0.025 mg/L SM20-5540 C 2/6/10 2:15 22-293

Heterotrophic 

Plate Count

24,600 /ml 1 /ml SM 9215B 2/4/10 16:55 WEH

Color 100 pccu 5 pccu 2/4/10 13:36 WEH

Temperature (F), 

Field

71 deg F deg F na 2/4/10 9:27 RCS

Osmotic Pressure 533 mOs/kg 10 mOs/kg PA DEP 2/6/10 6:12 22-293

Acidity - 136 mg/L 3 mg/L SM 2310 B 2/5/10 0:00 AML

Hardness, Total 2621 mg/l 10 mg/l EPA 200.7 2/5/10 10:15 AML

Alkalinity 230.0 mg/l 5 mg/l SM 2320 B 2/5/10 13:11 AML

Printed: 3/3/2010 10:21:56AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Bicarbonate 229.0 mg/L 5 mg/L SM4500 CO2 D 2/12/10 11:55 AML

Sulfate 155.0 mg/l 1 mg/l EPA 300.0 2/5/10 13:39 AML

Chloride 9,500 mg/L 1 mg/L EPA 300.0 2/5/10 13:35 AML

Fluoride 27.0 mg/l 0.20 mg/l EPA 300.0 2/5/10 13:39 AML

Calcium 915.0 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:05 AML

Bromide 141.0 mg/l 0.10 mg/l EPA 300.1 2/5/10 13:41 AML

Iron, Dissolved 4.2 mg/l 0.02 mg/l EPA 200.7 2/18/10 16:00 AML

Iron 5.6 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:10 AML

Magnesium 81.6 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:06 AML

Potassium 55.3 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:14 AML

Sodium 5250 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:15 AML

Silicon, Total 6.7 mg/L 1.3 mg/L EPA 200.7 2/16/10 13:08 22-293

Gross Alpha DW 27.0 PCi/L 3 PCi/L EPA 900 2/17/10 17:44 6502103

Printed: 3/3/2010 10:21:57AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Gross Beta DW 36.0 PCi/L 4 PCi/L EPA 900 2/17/10 17:44 6502103

Radium 226 46.0 pCi/L .6 pCi/L EPA 903.1 2/25/10 13:14 6502103

Radium 228 17.0 pCi/L .9 pCi/L EPA 904.0 2/24/10 13:53 6502103

Aluminum <2.0 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:07 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Barium 17.1 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:13 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:01 AML

Chromium <0.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:11 AML

Cobalt 0.031 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:01 AML

Boron 4.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:13 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:02 AML

Lead <0.4 mg/L 0.02 mg/L EPA 200.7 2/5/10 10:12 AML

Printed: 3/3/2010 10:21:57AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Lithium, Total 10.7 mg/L 1.3 mg/L EPA 200.7 2/12/10 9:07 22-293

Manganese 0.8 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:09 AML

Mercury, Total ND 0.0020 mg/L EPA 200.8 2/14/10 15:45 22-293

Molybdenum 0.018 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Nickel <1.0 mg/l 0.05 mg/l EPA 200.7 2/5/10 10:11 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:00 AML

Strontium, Total 97.5 mg/L 0.063 mg/L EPA 200.7 2/12/10 9:07 22-293

Thallium 0.015 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:00 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Titanium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Zinc <0.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:12 AML

Uranium ND 0.10 mg/L SW846 6020A 2/18/10 23:49 22-293

Printed: 3/3/2010 10:21:57AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Vanadium, Total ND 0.063 mg/L EPA 200.7 2/12/10 9:07 22-293

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 2/4/10 9:26 RCS

Phenolics 0.05 mg/L 0.01 mg/L EPA 420.4 2/17/10 4:38 22-293

BOD >76.0 2 mg/L SM5210B 2/4/10 12:37 TO

Thorium 228 1.10 pCi/L pCi/L HSL-300M 2/26/10 15:15 6502103

Thorium 230 0.773 pCi/L pCi/L HSL-300m 2/26/10 15:15 6502103

Thorium 232 -0.031 pCi/L pCi/L HSL-300m 2/26/10 15:15 6502103

Specific 

Conductance

29,400 umhos/cm 2 umhos/cm EPA 120.1 2/8/10 0:00 TO

Copper 0.46 mg/l 0.02 mg/l EPA 200.7 2/5/10 14:09 AML

Silica, Dissolved 54 mg/L 5 mg/L SM20-4500SiD 2/17/10 0:44 22-293

1,1,2,2-Tetrachloro

ethane

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Printed: 3/3/2010 10:21:57AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 2/9/10 23:26 22-293

2-Hexanone ND 25.0 ug/L SW846 8260B 2/9/10 23:26 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Acetone 304 ug/L 50.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Bromide 150 mg/L 30.0 mg/L EPA 300 2/10/10 4:48 22-293

Bromochlorometha

ne

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Bromoform ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Carbon Disulfide ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Printed: 3/3/2010 10:21:57AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Chloroform ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Chloromethane ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Diesel Range 

Organics C10-C28

28.4 mg/L 3.7 mg/L SW846 8015D 2/11/10 23:20 22-293

Ethane 140 ug/L 30.0 ug/L RSK 175 2/8/10 21:24 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/9/10 22:06 22-293

Gasoline Range 

Organics

2100 ug/L 100 ug/L SW846 8015D 2/13/10 1:36 22-293

Methane 848 ug/L 10.0 ug/L RSK 175 2/8/10 21:24 22-293

Total Kjeldahl 

Nitrogen

29.6 mg/L 1.0 mg/L SM20-4500-N C 2/16/10 9:00 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

mp-Xylene 47.5 ug/L 10.0 ug/L SW846 8260B 2/9/10 23:26 22-293

o-Xylene 18.8 ug/L 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

trans-1,2-Dichloroe

thene

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

trans-1,3-Dichlorop

ropene

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Printed: 3/3/2010 10:21:57AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/6/10 5:41 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/6/10 5:41 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/6/10 5:41 22-293

Ethene ND 30.0 ug/L RSK 175 2/8/10 21:24 22-293

Formaldehyde 110 mg/L 5.0 mg/L SW846 8015D 2/18/10 12:31 22-293

Methanol 50.1 mg/L 1.0 mg/L SW846 8015D 2/18/10 20:05 22-293

Benzene 218 ug/L 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Methylene 

Chloride

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,2-Dichloropropan

e

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Printed: 3/3/2010 10:21:57AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Ethylbenzene ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Styrene ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Tetrachloroethene ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Toluene 228 ug/L 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Vinyl Chloride ND 5.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Total Xylenes 66.2 ug/L 15.0 ug/L SW846 8260B 2/9/10 23:26 22-293

Nitrate <5.0 mg/l 0.10 mg/l EPA 300.0 2/5/10 13:40 AML

Nitrite <5.0 mg/l 0.10 mg/l EPA 300.0 2/5/10 13:41 AML

Nitrate / Nitrite <10.0 mg/l 0.20 mg/l EPA 300.0 2/5/10 13:41 AML

Printed: 3/3/2010 10:21:57AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100193

Altela

NETL Grant

Frac Water

N/A

02/03/10 07:00

02/04/10 08:37

N/A

Grab

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/4/10 16:54 WEH

E Coli NA +/- SM 9223B 2/4/10 16:54 WEH

Sample Comments:

BOD: Duplicate analysis recovery was outside established control limits.

Printed: 3/3/2010 10:21:57AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100197

FRAC FLOW-BACK WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

pH 7.39 SU SU SM4500 H+B 2/5/10 13:10 AML

Total Dissolved 

Solids

40,530 mg/l 5 mg/l SM 2540 C 2/5/10 14:49 RCS

Total Suspended 

Solids

22 mg/L 3 mg/L SM 2540 D 2/5/10 11:44 RCS

Oil & Grease 1.1 mg/l 5 mg/l EPA 1664 Rev A 2/5/10 10:20 NJD

BOD >74.2 2 mg/L SM5210B 2/5/10 9:31 TO

COD 1042 mg/L 10 mg/L HACH 8000 2/11/10 10:11 NJD

Surfactants 

(MBAS)

0.239 mg/L 0.025 mg/L SM20-5540 C 2/6/10 2:15 22-293

Heterotrophic 

Plate Count

4,810,000 /ml 1 /ml SM 9215B 2/4/10 16:55 WEH

Color 125 pccu 5 pccu 2/4/10 13:36 WEH

Temperature (F), 

Field

74 deg F deg F na 2/4/10 13:35 RCS

Osmotic Pressure 1110 mOs/kg 10 mOs/kg PA DEP 2/6/10 6:12 22-293

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 2/4/10 13:36 RCS

Acidity - 114 mg/L 3 mg/L SM 2310 B 2/5/10 0:00 AML

Printed: 3/3/2010 10:26:39AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Alkalinity 196.0 mg/l 5 mg/l SM 2320 B 2/5/10 13:11 AML

Hardness, Total 7040 mg/l 10 mg/l EPA 200.7 2/5/10 10:15 AML

Bicarbonate 196.0 mg/L 5 mg/L SM4500 CO2 D 2/12/10 11:55 AML

Sulfate 155.0 mg/l 1 mg/l EPA 300.0 2/5/10 13:39 AML

Chloride 20100 mg/L 1 mg/L EPA 300.0 2/5/10 13:35 AML

Fluoride 9.5 mg/l 0.20 mg/l EPA 300.0 2/5/10 13:39 AML

Calcium 2465 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:05 AML

Bromide 291.0 mg/l 0.10 mg/l EPA 300.1 2/5/10 13:41 AML

Iron 8.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:10 AML

Magnesium 215 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:06 AML

Potassium 94.8 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:14 AML

Sodium 10,380 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:15 AML

Gross Alpha DW 76.4 PCi/L 3 PCi/L EPA 900 2/19/10 17:41 6502103

Printed: 3/3/2010 10:26:39AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Gross Beta DW 240 PCi/L 4 PCi/L EPA 900 2/13/10 16:14 6502103

Radium 226 33.1 pCi/L .6 pCi/L EPA 903.1 2/25/10 13:24 6502103

Radium 228 27.3 pCi/L .9 pCi/L EPA 904.0 2/24/10 13:53 6502103

Aluminum <2.0 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:07 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:02 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Barium 52.9 mg/l 0.10 mg/l EPA 200.7 2/5/10 10:13 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:01 AML

Boron 6.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:13 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:01 AML

Chromium <0.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:11 AML

Cobalt 0.033 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Lead <0.4 mg/L 0.02 mg/L EPA 200.7 2/5/10 10:12 AML

Printed: 3/3/2010 10:26:39AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Lithium, Total 21.5 mg/L 1.3 mg/L EPA 200.7 2/12/10 9:02 22-293

Manganese 2.0 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:09 AML

Mercury, Total ND 0.0050 mg/L EPA 200.8 2/14/10 15:37 22-293

Molybdenum 0.016 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Nickel <1.0 mg/l 0.05 mg/l EPA 200.7 2/5/10 10:11 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:59 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:00 AML

Strontium, Total 265 mg/L 0.063 mg/L EPA 200.7 2/12/10 9:02 22-293

Thallium 0.009 mg/L 0.001 mg/L EPA 200.7 2/19/10 14:00 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Titanium 0.0094 mg/L 0.001 mg/L EPA 200.7 2/19/10 13:58 AML

Uranium ND 0.25 mg/L SW846 6020A 2/18/10 23:45 22-293

Zinc <0.4 mg/l 0.02 mg/l EPA 200.7 2/5/10 10:12 AML

Printed: 3/3/2010 10:26:39AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Vanadium, Total ND 0.063 mg/L EPA 200.7 2/12/10 9:02 22-293

Thorium 228 1.21 pCi/L pCi/L HSL-300M 2/26/10 11:07 6502103

Thorium 230 0.567 pCi/L pCi/L HSL-300m 2/26/10 11:07 6502103

Thorium 232 0.096 pCi/L pCi/L HSL-300m 2/26/10 11:07 6502103

Specific 

Conductance

56,700 umhos/cm 2 umhos/cm EPA 120.1 2/8/10 0:00 TO

Iron, Dissolved 8.3 mg/l 0.02 mg/l EPA 200.7 2/18/10 16:02 AML

Copper 0.52 mg/l 0.02 mg/l EPA 200.7 2/5/10 14:09 AML

1,1,2,2-Tetrachloro

ethane

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 2/9/10 22:55 22-293

2-Hexanone ND 25.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Printed: 3/3/2010 10:26:39AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Acetone 2090 ug/L 50.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Bromide 270 mg/L 150 mg/L EPA 300 2/10/10 5:18 22-293

Bromochlorometha

ne

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Bromoform ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Carbon Disulfide ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Chloroform ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Chloromethane ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Diesel Range 

Organics C10-C28

17.4 mg/L 3.2 mg/L SW846 8015D 2/11/10 22:49 22-293

Printed: 3/3/2010 10:26:39AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Ethane 133 ug/L 6.0 ug/L RSK 175 2/8/10 20:35 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/9/10 21:46 22-293

Gasoline Range 

Organics

928 ug/L 100 ug/L SW846 8015D 2/13/10 1:01 22-293

Methane 390 ug/L 2.0 ug/L RSK 175 2/8/10 20:35 22-293

Silica, Dissolved 49 mg/L 5 mg/L SM20-4500SiD 2/17/10 0:44 22-293

Silicon, Total 9.2 mg/L 1.3 mg/L EPA 200.7 2/16/10 13:03 22-293

Phenolics 0.04 mg/L 0.01 mg/L EPA 420.4 2/17/10 4:37 22-293

Total Kjeldahl 

Nitrogen

9.2 mg/L 1.0 mg/L SM20-4500-N C 2/16/10 9:00 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

mp-Xylene 27.2 ug/L 10.0 ug/L SW846 8260B 2/9/10 22:55 22-293

o-Xylene 8.9 ug/L 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

trans-1,2-Dichloroe

thene

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

trans-1,3-Dichlorop

ropene

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Printed: 3/3/2010 10:26:39AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/6/10 5:35 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/6/10 5:35 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/6/10 5:35 22-293

Ethene ND 6.0 ug/L RSK 175 2/8/10 20:35 22-293

Formaldehyde 75.4 mg/L 1.0 mg/L SW846 8015D 2/18/10 1:26 22-293

Methanol 35.2 mg/L 1.0 mg/L SW846 8015D 2/13/10 1:21 22-293

Benzene 55.3 ug/L 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Methylene 

Chloride

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,2-Dichloropropan

e

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Printed: 3/3/2010 10:26:39AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Ethylbenzene ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Styrene ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Tetrachloroethene ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Toluene 85.3 ug/L 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Vinyl Chloride ND 5.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Total Xylenes 36.2 ug/L 15.0 ug/L SW846 8260B 2/9/10 22:55 22-293

Nitrate <5.0 mg/l 0.10 mg/l EPA 300.0 2/5/10 13:40 AML

Nitrite <5.0 mg/l 0.10 mg/l EPA 300.0 2/5/10 13:41 AML

Nitrate / Nitrite <10.0 mg/l 0.20 mg/l EPA 300.0 2/5/10 13:41 AML

Printed: 3/3/2010 10:26:39AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100197

Altela

NETL Grant

Flow Back Water

N/A

02/04/10 10:14

02/04/10 11:30

N/A

Grab

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/4/10 16:54 WEH

E Coli NA +/- SM 9223B 2/4/10 16:54 WEH

Sample Comments:

None

Printed: 3/3/2010 10:26:39AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#09100467

PRODUCED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

pH 7.00 SU SU SM4500 H+B 9/14/10 13:17 AML

Total Dissolved 

Solids

37,600 mg/l 5 mg/l SM 2540 C 9/17/10 11:46 TSA

Total Suspended 

Solids

114 mg/L 3 mg/L SM 2540 D 9/14/10 14:25 TSA

Oil & Grease 1.6 mg/l 5 mg/l EPA 1664 Rev A 9/17/10 0:00 NJD

BOD 76.8 mg/L 2 mg/L SM5210B 9/15/10 9:16 TSA

COD 289 mg/L 10 mg/L HACH 8000 9/24/10 13:50 NJD

Surfactants 

(MBAS)

0.180 mg/L 0.025 mg/L SM20-5540 C 9/15/10 21:00 22-293

Color 200 pccu 5 pccu 9/13/10 14:54 WEH

Temperature (F), 

Field

62.3 deg F deg F na 9/13/10 17:13 RCJ

Osmotic Pressure 808 mOs/kg 10 mOs/kg PA DEP 9/16/10 6:05 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 9/14/10 8:52 WEH

Ammonia 

Nitrogen

17.8 mg/L .10 mg/L SM 4500 NH3 D 9/14/10 13:27 WEH

Nitrate <1.0 mg/l 0.10 mg/l EPA 300.0 9/14/10 13:38 AML

Printed: 11/1/2010 7:46:06AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Nitrite <1.0 mg/l 0.10 mg/l EPA 300.0 9/14/10 13:37 AML

Nitrate / Nitrite <2.0 mg/l 0.20 mg/l EPA 300.0 9/14/10 13:37 AML

Acidity -30.0 mg/L 3 mg/L SM 2310 B 9/14/10 13:16 AML

Alkalinity 102.0 mg/l 5 mg/l SM 2320 B 9/14/10 13:17 AML

Bicarbonate 102.0 mg/L 5 mg/L SM4500 CO2 D 9/14/10 13:25 AML

Sulfate 34.0 mg/l 1 mg/l EPA 300.0 9/14/10 13:38 AML

Chloride 16,240 mg/L 1 mg/L EPA 300.0 9/14/10 13:38 AML

Fluoride 4.8 mg/l 0.20 mg/l EPA 300.0 9/14/10 13:39 AML

Calcium 1,933 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:18 AML

Iron 23.1 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:21 AML

Iron, Dissolved 22.9 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:24 AML

Magnesium 176.8 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:19 AML

Potassium 95.5 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:19 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Sodium 7,781 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:19 AML

Aluminum <1.0 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:23 AML

Arsenic 0.028 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:54 AML

Barium 405.5 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:17 AML

Beryllium <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:56 AML

Cadmium <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:53 AML

Chromium <0.2 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:22 AML

Cobalt <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:57 AML

Manganese 2.9 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:20 AML

Molybdenum <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:53 AML

Nickel <0.5 mg/l 0.05 mg/l EPA 200.7 9/17/10 16:22 AML

Selenium <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:52 AML

Silver <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:55 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Strontium, Total 379 mg/L 0.13 mg/L EPA 200.7 9/21/10 11:27 22-293

Thallium <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:55 AML

Tin <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:52 AML

Titanium 0.037 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:52 AML

Zinc <0.2 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:24 AML

Gross Alpha DW 352 PCi/L 3 PCi/L EPA 900 9/26/10 10:56 6502103

Gross Beta DW 189 PCi/L 4 PCi/L EPA 900 9/25/10 10:57 6502103

Radium 226 162 pCi/L .6 pCi/L EPA 903.1 9/27/10 11:02 6502103

Radium 228 85.5 pCi/L .9 pCi/L EPA 904.0 10/11/10 11:02 6502103

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 9/13/10 15:54 RCJ

Phenolics 0.01 mg/L 0.01 mg/L EPA 420.4 9/21/10 11:38 22-293

Uranium, Total ND 0.11 mg/L SW846 6020A 9/27/10 17:40 22-293

Lead <0.2 mg/L 0.02 mg/L EPA 200.7 9/17/10 16:23 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Lithium, Total 14.3 mg/L 2.5 mg/L EPA 200.7 9/21/10 11:27 22-293

Boron 3.12 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:24 AML

Antimony <0.05 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:56 AML

Silicon, Total 7.0 mg/L 0.50 mg/L EPA 200.7 9/20/10 14:40 22-293

Hardness, Total 5,555 mg/l 10 mg/l EPA 200.7 9/17/10 16:17 AML

Heterotrophic 

Plate Count

5,900 /ml 1 /ml SM 9215B 9/13/10 15:37 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 9/13/10 15:33 TSA

E Coli NA +/- SM 9223B 9/13/10 15:33 TSA

Specific 

Conductance

42,400 umhos/cm 2 umhos/cm EPA 120.1 9/14/10 11:36 AML

Gasoline Range 

Organics

ND 500 ug/L SW846 8015D 9/23/10 8:14 22-293

Diesel Range 

Organics C10-C28

5.4 mg/L 1.6 mg/L SW846 8015D 9/23/10 8:53 22-293

Methane 748 ug/L 1.0 ug/L RSK 175 9/17/10 20:09 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 9/18/10 0:54 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 9/16/10 9:57 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 9/16/10 9:57 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 9/16/10 9:57 22-293

Total Kjeldahl 

Nitrogen

1.4 mg/L 1.0 mg/L SM20-4500-N C 9/28/10 9:30 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 9/23/10 19:33 22-293

Acetone 9520 ug/L 500 ug/L SW846 8260B 9/22/10 9:25 22-293

Silica, Dissolved 30 mg/L 5 mg/L SM20-4500SiO2C 9/22/10 23:35 22-293

2-Hexanone ND 25.0 ug/L SW846 8260B 9/21/10 13:52 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 9/21/10 13:52 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Ethene ND 3.0 ug/L RSK 175 9/17/10 20:09 22-293

Methanol ND 1.0 mg/L SW846 8015D 9/21/10 20:55 22-293

o-Xylene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

mp-Xylene ND 10.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Chloromethane ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Ethane 3.8 ug/L 3.0 ug/L RSK 175 9/17/10 20:09 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Chloroform ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Carbon Disulfide ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Bromide 162.5 mg/L 0.3 mg/L EPA 300 9/14/10 13:36 AML

Bromochlorometha

ne

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

1,1,2,2-Tetrachloro

ethane

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Methylene 

Chloride

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,2-Dichloropropan

e

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Tetrachloroethene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

trans-1,2-Dichloroe

thene

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

trans-1,3-Dichlorop

ropene

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Benzene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Ethylbenzene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Styrene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Toluene ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Vinyl Chloride ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Total Xylenes ND 15.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Vanadium, Total ND 0.13 mg/L EPA 200.7 9/21/10 11:27 22-293

Copper 0.33 mg/l 0.02 mg/l EPA 200.7 9/22/10 13:22 AML

Bromoform ND 5.0 ug/L SW846 8260B 9/21/10 13:52 22-293

Thorium 228 5.273 pCi/L pCi/L HSL-300M 9/28/10 11:03 6502103

Printed: 11/1/2010 7:46:07AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100467

Altela

4011

PW Entry Point

N/A

09/13/10 10:45

09/13/10 14:35

N/A

Grab

Thorium 230 0.048 pCi/L pCi/L HSL-300m 9/28/10 11:04 6502103

Thorium 232 -0.005 pCi/L pCi/L HSL-300m 9/28/10 11:04 6502103

Sample Comments:

Cadmium: Matrix Spike recovery was outside established control limits. Silver: Matrix Spike recovery was outside 

established control limits.

Printed: 11/1/2010 7:46:07AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#09100468

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

pH 7.87 SU SU SM4500 H+B 9/14/10 13:17 AML

Total Dissolved 

Solids

9 mg/l 5 mg/l SM 2540 C 9/17/10 11:46 TSA

Total Suspended 

Solids

3 mg/L 3 mg/L SM 2540 D 9/14/10 14:25 TSA

Oil & Grease 2.1 mg/l 5 mg/l EPA 1664 Rev A 9/17/10 0:00 NJD

BOD < 2.0 mg/L 2 mg/L SM5210B 9/15/10 9:16 TSA

COD <10 mg/L 10 mg/L HACH 8000 9/24/10 13:50 NJD

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 9/15/10 21:00 22-293

Color < 5 pccu 5 pccu 9/13/10 14:54 WEH

Temperature (F), 

Field

136.1 deg F deg F na 9/13/10 17:13 RCJ

Osmotic Pressure ND 10 mOs/kg PA DEP 9/16/10 6:05 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 9/15/10 9:15 WEH

Ammonia 

Nitrogen

3.88 mg/L .10 mg/L SM 4500 NH3 D 9/16/10 11:04 WEH

Nitrate <0.10 mg/l 0.10 mg/l EPA 300.0 9/14/10 13:38 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Nitrite <0.10 mg/l 0.10 mg/l EPA 300.0 9/14/10 13:37 AML

Nitrate / Nitrite <0.20 mg/l 0.20 mg/l EPA 300.0 9/14/10 13:37 AML

Acidity 6.0 mg/L 3 mg/L SM 2310 B 9/14/10 13:16 AML

Alkalinity 14.0 mg/l 5 mg/l SM 2320 B 9/14/10 13:17 AML

Bicarbonate 14.0 mg/L 5 mg/L SM4500 CO2 D 9/14/10 13:25 AML

Sulfate <1.0 mg/l 1 mg/l EPA 300.0 9/14/10 13:38 AML

Chloride 2.9 mg/L 1 mg/L EPA 300.0 9/14/10 13:38 AML

Fluoride <0.20 mg/l 0.20 mg/l EPA 300.0 9/14/10 13:39 AML

Calcium 0.36 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:18 AML

Iron <0.02 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:21 AML

Iron, Dissolved <0.02 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:24 AML

Magnesium <0.10 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:19 AML

Potassium <0.10 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:19 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Sodium 0.37 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:19 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:23 AML

Arsenic <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:54 AML

Barium <0.10 mg/l 0.10 mg/l EPA 200.7 9/17/10 16:17 AML

Beryllium <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:56 AML

Cadmium <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:53 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:22 AML

Cobalt <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:57 AML

Manganese <0.02 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:20 AML

Molybdenum <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:53 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 9/17/10 16:22 AML

Selenium <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:52 AML

Silver <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:55 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Strontium, Total 0.026 mg/L 0.0025 mg/L EPA 200.7 9/21/10 11:37 22-293

Thallium <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:55 AML

Tin <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:52 AML

Titanium <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:52 AML

Zinc <0.02 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:24 AML

Gross Alpha DW -0.409 PCi/L 3 PCi/L EPA 900 9/25/10 10:57 6502103

Gross Beta DW -0.141 PCi/L 4 PCi/L EPA 900 9/25/10 10:57 6502103

Radium 226 0.278 pCi/L .6 pCi/L EPA 903.1 9/27/10 11:02 6502103

Radium 228 0.259 pCi/L .9 pCi/L EPA 904.0 10/11/10 11:02 6502103

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 9/13/10 15:54 RCJ

Phenolics 0.03 mg/L 0.01 mg/L EPA 420.4 9/21/10 11:39 22-293

Uranium, Total ND 0.11 mg/L SW846 6020A 9/27/10 17:46 22-293

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 9/17/10 16:23 AML

Printed: 11/1/2010 7:46:07AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Lithium, Total ND 0.050 mg/L EPA 200.7 9/21/10 11:37 22-293

Boron 0.02 mg/l 0.02 mg/l EPA 200.7 9/17/10 16:24 AML

Antimony <0.005 mg/L 0.005 mg/L EPA 200.7 10/1/10 13:56 AML

Silicon, Total 0.19 mg/L 0.050 mg/L EPA 200.7 9/20/10 15:03 22-293

Hardness, Total <10.0 mg/l 10 mg/l EPA 200.7 9/17/10 16:17 AML

Heterotrophic 

Plate Count

< 100 /ml 1 /ml SM 9215B 9/13/10 15:37 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 9/13/10 15:33 TSA

E Coli NA +/- SM 9223B 9/13/10 15:33 TSA

Specific 

Conductance

30.0 umhos/cm 2 umhos/cm EPA 120.1 9/14/10 11:36 AML

Gasoline Range 

Organics

ND 100 ug/L SW846 8015D 9/23/10 0:17 22-293

Diesel Range 

Organics C10-C28

0.99 mg/L 0.16 mg/L SW846 8015D 9/21/10 21:21 22-293

Methane 1.3 ug/L 1.0 ug/L RSK 175 9/17/10 20:24 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 9/18/10 1:15 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 9/16/10 10:05 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 9/16/10 10:05 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 9/16/10 10:05 22-293

Total Kjeldahl 

Nitrogen

3.3 mg/L 1.0 mg/L SM20-4500-N C 9/28/10 9:30 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 9/23/10 19:15 22-293

Acetone 174 ug/L 10.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Silica, Dissolved ND 1 mg/L SM20-4500SiO2C 9/22/10 23:35 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 9/23/10 2:08 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 9/23/10 2:08 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Ethene ND 3.0 ug/L RSK 175 9/17/10 20:24 22-293

Methanol ND 1.0 mg/L SW846 8015D 9/21/10 21:10 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

mp-Xylene ND 2.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Ethane ND 3.0 ug/L RSK 175 9/17/10 20:24 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Chloroform ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Carbon Disulfide 2.8 ug/L 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Bromide <0.30 mg/L 0.3 mg/L EPA 300 9/14/10 13:36 AML

Bromochlorometha

ne

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

1,1,2,2-Tetrachloro

ethane

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,2-Dichloropropan

e

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

trans-1,2-Dichloroe

thene

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

trans-1,3-Dichlorop

ropene

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Benzene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Printed: 11/1/2010 7:46:07AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Styrene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Toluene ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Vinyl Chloride ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 9/21/10 11:37 22-293

Copper <0.02 mg/l 0.02 mg/l EPA 200.7 9/22/10 13:22 AML

Bromoform ND 1.0 ug/L SW846 8260B 9/23/10 2:08 22-293

Thorium 228 0.096 pCi/L pCi/L HSL-300M 9/28/10 11:03 6502103

Printed: 11/1/2010 7:46:07AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

09100468

Altela

4011

DW Basin

N/A

09/13/10 11:30

09/13/10 14:39

N/A

Grab

Thorium 230 0.087 pCi/L pCi/L HSL-300m 9/28/10 11:04 6502103

Thorium 232 0.025 pCi/L pCi/L HSL-300m 9/28/10 11:04 6502103

Sample Comments:

Cadmium: Matrix Spike recovery was outside established control limits. Silver: Matrix Spike recovery was outside 

established control limits.

Printed: 11/1/2010 7:46:07AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02110642

PRODUCED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

pH 6.50 SU SU SM4500 H+B 2/15/11 16:38 AML

Total Dissolved 

Solids

26,055 mg/l 5 mg/l SM 2540 C 2/18/11 15:33 WEH

Total Suspended 

Solids

35 mg/L 3 mg/L SM 2540 D 2/15/11 15:32 WEH

Oil & Grease 0.1 mg/l 5 mg/l EPA 1664 Rev A 2/21/11 0:00 TO

BOD 107 mg/L 2 mg/L SM5210B 2/16/11 11:30 TSA

COD 344 mg/L 10 mg/L HACH 8000 2/23/11 9:53 WEH

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 2/16/11 21:45 22-293

Color 130 pccu 5 pccu 2/15/11 15:19 WEH

Temperature (F), 

Field

63 deg F deg F na 2/15/11 0:00 ZW

Osmotic Pressure 637 mOs/kg 10 mOs/kg PA DEP 2/17/11 5:15 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 2/16/11 14:09 WEH

Ammonia 

Nitrogen

28.1 mg/L .10 mg/L SM 4500 NH3 D 2/17/11 9:03 WEH

Nitrate <1.0 mg/l 0.10 mg/l EPA 300.0 2/16/11 13:03 AML

Printed: 3/2/2011 9:08:03AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Nitrite <1.0 mg/l 0.10 mg/l EPA 300.0 2/16/11 13:02 AML

Nitrate / Nitrite <2.0 mg/l 0.20 mg/l EPA 300.0 2/16/11 13:03 AML

Acidity < 5 mg/L 3 mg/L SM 2310 B 2/15/11 16:38 AML

Alkalinity 110 mg/l 5 mg/l SM 2320 B 2/15/11 16:38 AML

Bicarbonate 110 mg/L 5 mg/L SM4500 CO2 D 2/15/11 16:38 AML

Sulfate 20.4 mg/l 1 mg/l EPA 300.0 2/16/11 13:04 AML

Chloride 11,670 mg/L 1 mg/L EPA 300.0 2/16/11 13:04 AML

Fluoride <2.0 mg/l 0.20 mg/l EPA 300.0 2/16/11 13:01 AML

Calcium 1,634 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:09 AML

Iron 17.4 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:11 AML

Iron, Dissolved 21.1 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:23 AML

Magnesium 139.5 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:10 AML

Potassium 66.2 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:12 AML

Printed: 3/2/2011 9:08:03AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Sodium 5,868 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:09 AML

Aluminum <1.0 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:11 AML

Arsenic <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:11 AML

Barium 332.2 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:10 AML

Beryllium <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:10 AML

Cadmium <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:10 AML

Chromium <0.2 mg/l 0.02 mg/l EPA 200.7 2/18/11 13:37 AML

Cobalt <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:09 AML

Manganese 2.1 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:13 AML

Molybdenum <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:09 AML

Nickel <0.5 mg/l 0.05 mg/l EPA 200.7 2/18/11 13:36 AML

Selenium <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:09 AML

Silver <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:08 AML

Printed: 3/2/2011 9:08:03AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Strontium 317.8 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:10 AML

Thallium <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:08 AML

Tin <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:08 AML

Titanium <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:07 AML

Zinc <0.2 mg/l 0.02 mg/l EPA 200.7 2/18/11 13:36 AML

Gross Alpha DW 664 PCi/L 3 PCi/L EPA 900 2/25/11 13:51 6502103

Gross Beta DW 847 PCi/L 4 PCi/L EPA 900 2/21/11 13:51 6502103

Radium 226 153 pCi/L .6 pCi/L EPA 903.1 2/22/11 13:53 6502103

Radium 228 45.0 pCi/L .9 pCi/L EPA 904.0 2/25/11 14:00 6502103

Total Residual 

Chlorine

0.00 mg/L 0.10 mg/L HACH 8167 2/15/11 0:00 RCJ

Phenolics ND 0.01 mg/L EPA 420.4 3/1/11 4:09 22-293

Uranium, Total ND 0.14 mg/L SW846 6020A 2/28/11 17:06 22-293

Mercury ND 0.001 mg/l EPA 200.8 2/23/11 8:45 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 2/18/11 12:11 AML

Lithium, Total 10.7 mg/L 4.0 mg/L EPA 200.7 2/22/11 11:28 22-293

Boron 2.7 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:13 AML

Antimony <0.05 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:11 AML

Silicon, Total 6.4 mg/L 4.0 mg/L EPA 200.7 2/22/11 14:14 22-293

Bromide 118.5 mg/l 0.10 mg/l EPA 300.1 2/16/11 13:04 AML

Hardness, Total 4,655 mg/l 10 mg/l EPA 200.7 2/18/11 12:08 AML

Heterotrophic 

Plate Count

18,600 /ml 1 /ml SM 9215B 2/15/11 16:10 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/15/11 16:14 TSA

E Coli NA +/- SM 9223B 2/15/11 16:14 TSA

Specific 

Conductance

34,300 umhos/cm 2 umhos/cm EPA 120.1 2/17/11 13:15 AML

Gasoline Range 

Organics

ND 500 ug/L SW846 8015D 2/16/11 22:51 22-293

Diesel Range 

Organics C10-C28

7.1 mg/L 1.6 mg/L SW846 8015D 2/23/11 8:32 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Methane 5490 ug/L 1.0 ug/L RSK 175 2/18/11 17:59 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/18/11 19:46 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/17/11 8:52 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/17/11 8:52 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/17/11 8:52 22-293

Total Kjeldahl 

Nitrogen

ND 1.0 mg/L SM20-4500-N C 2/17/11 12:30 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 2/25/11 21:37 22-293

Acetone 13800 ug/L 250 ug/L SW846 8260B 2/23/11 21:26 22-293

Silica, Dissolved 25 mg/L 10 mg/L SM20-4500SiO2C 2/23/11 3:17 22-293

2-Hexanone ND 25.0 ug/L SW846 8260B 2/18/11 23:57 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 2/18/11 23:57 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Ethene ND 3.0 ug/L RSK 175 2/18/11 17:59 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Methanol ND 1.0 mg/L SW846 8015D 3/1/11 0:24 22-293

o-Xylene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

mp-Xylene ND 10.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Chloromethane ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Ethane 8.9 ug/L 3.0 ug/L RSK 175 2/18/11 17:59 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Chloroform ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Carbon Disulfide ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Bromochlorometh

ane

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,1,2,2-Tetrachlor

oethane

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Methylene 

Chloride

22.0 ug/L 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,2-Dichloropropa

ne

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Tetrachloroethene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

trans-1,2-Dichloro

ethene

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

trans-1,3-Dichloro

propene

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Benzene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Ethylbenzene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Styrene ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Toluene 8.3 ug/L 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Vinyl Chloride ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Total Xylenes ND 15.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Vanadium, Total ND 0.20 mg/L EPA 200.7 2/22/11 11:28 22-293

Copper <0.2 mg/l 0.02 mg/l EPA 200.7 2/18/11 14:34 AML

Bromoform ND 5.0 ug/L SW846 8260B 2/18/11 23:57 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110642

Altela

4011

PW Water

N/A

02/15/11 12:30

02/15/11 14:38

N/A

Grab

Thorium 228 10.760 pCi/L pCi/L HSL-300M 2/21/11 14:00 6502103

Thorium 230 -0.135 pCi/L pCi/L HSL-300m 2/22/11 14:01 6502103

Thorium 232 0.114 pCi/L pCi/L HSL-300m 2/22/11 14:01 6502103

Sample Comments:

None

Printed: 3/2/2011 9:08:03AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02110641

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

pH 4.73 SU SU SM4500 H+B 2/15/11 16:38 AML

Total Dissolved 

Solids

33 mg/l 5 mg/l SM 2540 C 2/18/11 15:33 WEH

Total Suspended 

Solids

3 mg/L 3 mg/L SM 2540 D 2/15/11 15:32 WEH

Oil & Grease 2.6 mg/l 5 mg/l EPA 1664 Rev A 2/21/11 0:00 TO

BOD 26.6 mg/L 2 mg/L SM5210B 2/16/11 11:30 TSA

COD 48.3 mg/L 10 mg/L HACH 8000 2/23/11 9:53 WEH

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 2/16/11 21:45 22-293

Color < 5 pccu 5 pccu 2/15/11 15:19 WEH

Temperature (F), 

Field

135 deg F deg F na 2/15/11 0:00 ZW

Osmotic Pressure ND 10 mOs/kg PA DEP 2/17/11 5:15 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 2/16/11 14:09 WEH

Ammonia 

Nitrogen

1.77 mg/L .10 mg/L SM 4500 NH3 D 2/17/11 9:03 WEH

Nitrate <0.10 mg/l 0.10 mg/l EPA 300.0 2/16/11 13:03 AML

Printed: 3/2/2011 9:08:03AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Nitrite <0.10 mg/l 0.10 mg/l EPA 300.0 2/16/11 13:02 AML

Nitrate / Nitrite <0.20 mg/l 0.20 mg/l EPA 300.0 2/16/11 13:03 AML

Acidity 16 mg/L 3 mg/L SM 2310 B 2/15/11 16:38 AML

Alkalinity < 5 mg/l 5 mg/l SM 2320 B 2/15/11 16:38 AML

Bicarbonate < 5 mg/L 5 mg/L SM4500 CO2 D 2/15/11 16:38 AML

Sulfate 2.2 mg/l 1 mg/l EPA 300.0 2/16/11 13:04 AML

Chloride 14.6 mg/L 1 mg/L EPA 300.0 2/16/11 13:04 AML

Fluoride <0.20 mg/l 0.20 mg/l EPA 300.0 2/16/11 13:01 AML

Calcium 2.18 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:09 AML

Iron 0.12 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:11 AML

Iron, Dissolved <0.02 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:23 AML

Magnesium 0.36 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:10 AML

Potassium <0.10 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:12 AML

Printed: 3/2/2011 9:08:03AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Sodium 6.42 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:09 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:11 AML

Arsenic <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:11 AML

Barium 0.33 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:10 AML

Beryllium <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:10 AML

Cadmium <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:10 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 2/18/11 13:37 AML

Cobalt <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:09 AML

Manganese <0.02 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:13 AML

Molybdenum <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:09 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 2/18/11 13:36 AML

Selenium <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:09 AML

Silver <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:08 AML

Printed: 3/2/2011 9:08:03AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Strontium 0.35 mg/l 0.10 mg/l EPA 200.7 2/18/11 12:10 AML

Thallium <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:08 AML

Tin 0.007 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:08 AML

Titanium <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:07 AML

Zinc 0.05 mg/l 0.02 mg/l EPA 200.7 2/18/11 13:36 AML

Gross Alpha DW 0.841 PCi/L 3 PCi/L EPA 900 2/21/11 13:51 6502103

Gross Beta DW 0.259 PCi/L 4 PCi/L EPA 900 2/21/11 13:51 6502103

Radium 226 0.224 pCi/L .6 pCi/L EPA 903.1 2/22/11 13:53 6502103

Radium 228 1.32 pCi/L .9 pCi/L EPA 904.0 2/25/11 14:00 6502103

Total Residual 

Chlorine

0.45 mg/L 0.10 mg/L HACH 8167 2/15/11 0:00 RCJ

Phenolics 0.03 mg/L 0.01 mg/L EPA 420.4 2/23/11 14:55 22-293

Uranium, Total ND 0.028 mg/L SW846 6020A 2/28/11 16:36 22-293

Mercury ND 0.001 mg/l EPA 200.8 2/23/11 8:45 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 2/18/11 12:11 AML

Lithium, Total ND 0.050 mg/L EPA 200.7 2/18/11 16:15 22-293

Boron 0.05 mg/l 0.02 mg/l EPA 200.7 2/18/11 12:13 AML

Antimony <0.005 mg/L 0.005 mg/L EPA 200.7 3/1/11 14:11 AML

Silicon, Total 0.19 mg/L 0.050 mg/L EPA 200.7 2/22/11 14:10 22-293

Bromide <0.10 mg/l 0.10 mg/l EPA 300.1 2/16/11 13:04 AML

Hardness, Total <10.0 mg/l 10 mg/l EPA 200.7 2/18/11 12:08 AML

Heterotrophic 

Plate Count

20 /ml 1 /ml SM 9215B 2/15/11 16:10 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/15/11 16:14 TSA

E Coli NA +/- SM 9223B 2/15/11 16:14 TSA

Specific 

Conductance

74.5 umhos/cm 2 umhos/cm EPA 120.1 2/17/11 13:15 AML

Gasoline Range 

Organics

ND 100 ug/L SW846 8015D 2/16/11 23:25 22-293

Diesel Range 

Organics C10-C28

2.3 mg/L 0.31 mg/L SW846 8015D 2/23/11 4:51 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Methane ND 1.0 ug/L RSK 175 2/18/11 17:06 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/18/11 19:24 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/17/11 8:46 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/17/11 8:46 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/17/11 8:46 22-293

Total Kjeldahl 

Nitrogen

1.5 mg/L 1.0 mg/L SM20-4500-N C 2/17/11 12:30 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 2/25/11 20:52 22-293

Acetone 949 ug/L 50.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Silica, Dissolved ND 1 mg/L SM20-4500SiO2C 2/23/11 3:17 22-293

2-Hexanone ND 25.0 ug/L SW846 8260B 2/19/11 0:27 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 2/19/11 0:27 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Ethene ND 3.0 ug/L RSK 175 2/18/11 17:06 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Methanol ND 1.0 mg/L SW846 8015D 2/28/11 23:26 22-293

o-Xylene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

mp-Xylene ND 10.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Chloromethane ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Ethane ND 3.0 ug/L RSK 175 2/18/11 17:06 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Chloroform ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Carbon Disulfide ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Bromochlorometh

ane

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,1,2,2-Tetrachlor

oethane

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Methylene 

Chloride

9.0 ug/L 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,2-Dichloropropa

ne

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Tetrachloroethene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

trans-1,2-Dichloro

ethene

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

trans-1,3-Dichloro

propene

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Benzene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Ethylbenzene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Styrene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Toluene ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Vinyl Chloride ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Total Xylenes ND 15.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 2/18/11 16:15 22-293

Copper 0.07 mg/l 0.02 mg/l EPA 200.7 2/18/11 14:34 AML

Bromoform ND 5.0 ug/L SW846 8260B 2/19/11 0:27 22-293

Printed: 3/2/2011 9:08:03AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02110641

Altela

4011

DW Water

N/A

02/15/11 12:00

02/15/11 14:37

N/A

Grab

Thorium 228 0.118 pCi/L pCi/L HSL-300M 2/21/11 14:00 6502103

Thorium 230 0.085 pCi/L pCi/L HSL-300m 2/22/11 14:01 6502103

Thorium 232 0.011 pCi/L pCi/L HSL-300m 2/22/11 14:01 6502103

Sample Comments:

None

Printed: 3/2/2011 9:08:03AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#03111242

PRODUCED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Total Residual 

Chlorine, Field

0.00 mg/L 0.1 mg/L HACH 8167 3/31/11 0:00 RCJ

pH 6.90 SU SU SM4500 H+B 4/1/11 15:44 AML

Total Dissolved 

Solids

22,350 mg/l 5 mg/l SM 2540 C 4/1/11 13:12 TSA

Total Suspended 

Solids

60 mg/L 3 mg/L SM 2540 D 4/1/11 15:25 TSA

Oil & Grease 2.7 mg/l 5 mg/l EPA 1664 Rev A 4/1/11 0:00 TO

BOD 83.9 mg/L 2 mg/L SM5210B 4/1/11 11:10 TO

COD 220 mg/L 10 mg/L HACH 8000 4/11/11 0:00 TO

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 4/1/11 21:00 22-293

Color 55 pccu 5 pccu 4/1/11 8:20 WEH

Temperature (F), 

Field

51 deg F deg F na 3/31/11 0:00 RCJ

Osmotic Pressure ND 10 mOs/kg PA DEP 4/2/11 5:00 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 4/4/11 8:23 WEH

Ammonia 

Nitrogen

10.2 mg/L .10 mg/L SM 4500 NH3 D 4/4/11 13:49 WEH

Printed: 4/27/2011 9:19:05AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Nitrate <10.0 mg/l 0.10 mg/l EPA 300.0 4/1/11 13:04 AML

Nitrite <10.0 mg/l 0.10 mg/l EPA 300.0 4/1/11 13:04 AML

Nitrate / Nitrite <20.0 mg/l 0.20 mg/l EPA 300.0 4/1/11 13:04 AML

Acidity -26.0 mg/L 3 mg/L SM 2310 B 4/1/11 15:44 AML

Alkalinity 88.0 mg/l 5 mg/l SM 2320 B 4/1/11 15:43 AML

Bicarbonate 88.0 mg/L 5 mg/L SM4500 CO2 D 4/1/11 15:44 AML

Sulfate <100.0 mg/l 1 mg/l EPA 300.0 4/1/11 13:03 AML

Chloride 9,760 mg/L 1 mg/L EPA 300.0 4/1/11 13:05 AML

Fluoride <20.0 mg/l 0.20 mg/l EPA 300.0 4/1/11 13:03 AML

Calcium 1,186 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:34 AML

Iron 17.6 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:37 AML

Iron, Dissolved 13.9 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:36 AML

Magnesium 121.3 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:35 AML

Printed: 4/27/2011 9:19:05AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Potassium 63.2 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:59 AML

Sodium 4,726 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:41 AML

Aluminum <5.0 mg/l 0.10 mg/l EPA 200.7 4/1/11 15:16 AML

Arsenic <0.25 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:35 AML

Barium 284.7 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:36 AML

Beryllium, Total <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:35 AML

Cadmium <0.25 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:36 AML

Chromium <1.0 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:40 AML

Cobalt <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:35 AML

Manganese 2.0 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:37 AML

Molybdenum <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:36 AML

Nickel <2.5 mg/l 0.05 mg/l EPA 200.7 4/1/11 15:16 AML

Selenium <0.25 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:37 AML

Printed: 4/27/2011 9:19:05AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Silver <0.25 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:35 AML

Strontium 264.2 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:38 AML

Thallium <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:36 AML

Tin <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:34 AML

Titanium <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:34 AML

Zinc <1.0 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:41 AML

Gross Alpha DW 161 PCi/L 3 PCi/L EPA 900 4/7/11 16:06 6502103

Gross Beta DW 79.7 PCi/L 4 PCi/L EPA 900 4/7/11 16:06 6502103

Radium 226 155 pCi/L .6 pCi/L EPA 903.1 4/15/11 16:07 6502103

Radium 228 51.9 pCi/L .9 pCi/L EPA 904.0 4/15/11 16:07 6502103

Phenolics ND 0.01 mg/L EPA 420.4 4/11/11 14:19 22-293

Uranium, Total ND 0.25 mg/L SW846 6020A 4/16/11 6:47 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 4/8/11 9:27 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Lead <1.0 mg/L 0.02 mg/L EPA 200.7 4/1/11 15:17 AML

Lithium, Total 9.1 mg/L 1.5 mg/L EPA 200.7 4/7/11 16:14 22-293

Boron 2.0 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:40 AML

Antimony <0.25 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:36 AML

Silicon, Total 5.1 mg/L 1.5 mg/L EPA 200.7 4/11/11 15:51 22-293

Bromide 101.0 mg/l 0.10 mg/l EPA 300.1 4/1/11 13:05 AML

Hardness, Total 3,461 mg/l 10 mg/l EPA 200.7 4/1/11 14:48 AML

Heterotrophic 

Plate Count

2,970 /ml 1 /ml SM 9215B 3/31/11 15:47 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 3/31/11 15:45 TSA

E Coli NA +/- SM 9223B 3/31/11 15:45 TSA

Specific 

Conductance

28,450 umhos/cm 2 umhos/cm EPA 120.1 4/1/11 11:47 AML

Gasoline Range 

Organics

ND 5000 ug/L SW846 8015D 4/5/11 22:49 22-293

Diesel Range 

Organics C10-C28

4.0 mg/L 0.78 mg/L SW846 8015D 4/7/11 17:31 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Methane 3570 ug/L 1.0 ug/L RSK 175 4/11/11 16:39 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 4/9/11 3:26 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 4/2/11 5:38 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 4/2/11 5:38 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 4/2/11 5:38 22-293

Total Kjeldahl 

Nitrogen

30.1 mg/L 4.0 mg/L SM20-4500-N C 4/5/11 12:37 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 4/11/11 22:33 22-293

Acetone 8710 ug/L 500 ug/L SW846 8260B 4/11/11 17:57 22-293

Silica, Dissolved 16 mg/L 5 mg/L SM20-4500SiO2C 4/9/11 1:34 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 4/9/11 20:04 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 4/9/11 20:04 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Ethene ND 3.0 ug/L RSK 175 4/11/11 16:39 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Methanol ND 1.0 mg/L SW846 8015D 4/8/11 17:47 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

mp-Xylene 2.3 ug/L 2.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Ethane 6.4 ug/L 3.0 ug/L RSK 175 4/11/11 16:39 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Chloroform ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Carbon Disulfide ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Bromochlorometh

ane

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,1,2,2-Tetrachlor

oethane

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,2-Dichloropropa

ne

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

trans-1,2-Dichloro

ethene

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

trans-1,3-Dichloro

propene

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Benzene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Styrene ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Toluene 10.9 ug/L 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Vinyl Chloride ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Vanadium, Total ND 0.075 mg/L EPA 200.7 4/7/11 16:14 22-293

Copper <1.0 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:38 AML

Bromoform ND 1.0 ug/L SW846 8260B 4/9/11 20:04 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111242

Altela

PW Water

PW Influent

Discharge

03/31/11 11:00

03/31/11 12:59

N/A

Grab

Thorium 228 11.408 pCi/L pCi/L HSL-300M 4/19/11 16:08 6502103

Thorium 230 0.035 pCi/L pCi/L HSL-300m 4/19/11 16:08 6502103

Thorium 232 0.055 pCi/L pCi/L HSL-300m 4/19/11 16:09 6502103

Sample Comments:

None

Printed: 4/27/2011 9:19:05AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#03111241

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Total Residual 

Chlorine, Field

0.21 mg/L 0.1 mg/L HACH 8167 3/31/11 0:00 RCJ

pH 6.24 SU SU SM4500 H+B 4/1/11 15:44 AML

Total Dissolved 

Solids

196 mg/l 5 mg/l SM 2540 C 4/1/11 13:12 TSA

Total Suspended 

Solids

< 3 mg/L 3 mg/L SM 2540 D 4/1/11 15:25 TSA

Oil & Grease 3.2 mg/l 5 mg/l EPA 1664 Rev A 4/1/11 0:00 TO

BOD 27.1 mg/L 2 mg/L SM5210B 4/1/11 11:10 TO

COD 35.8 mg/L 10 mg/L HACH 8000 4/11/11 0:00 TO

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 4/1/11 21:00 22-293

Color < 5 pccu 5 pccu 4/1/11 8:20 WEH

Temperature (F), 

Field

109 deg F deg F na 3/31/11 0:00 RCJ

Osmotic Pressure ND 10 mOs/kg PA DEP 4/2/11 5:00 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 4/4/11 8:23 WEH

Ammonia 

Nitrogen

4.42 mg/L .10 mg/L SM 4500 NH3 D 4/4/11 13:49 WEH

Printed: 4/27/2011 9:19:05AM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Nitrate <0.10 mg/l 0.10 mg/l EPA 300.0 4/1/11 13:04 AML

Nitrite <0.10 mg/l 0.10 mg/l EPA 300.0 4/1/11 13:04 AML

Nitrate / Nitrite <0.20 mg/l 0.20 mg/l EPA 300.0 4/1/11 13:04 AML

Acidity <5.0 mg/L 3 mg/L SM 2310 B 4/1/11 15:44 AML

Alkalinity <5.0 mg/l 5 mg/l SM 2320 B 4/1/11 15:43 AML

Bicarbonate <5.0 mg/L 5 mg/L SM4500 CO2 D 4/1/11 15:44 AML

Sulfate 1.98 mg/l 1 mg/l EPA 300.0 4/1/11 13:03 AML

Chloride 99.1 mg/L 1 mg/L EPA 300.0 4/1/11 13:05 AML

Fluoride 0.32 mg/l 0.20 mg/l EPA 300.0 4/1/11 13:03 AML

Calcium 11.1 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:34 AML

Iron 0.02 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:37 AML

Iron, Dissolved 0.03 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:36 AML

Magnesium 1.10 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:35 AML

Printed: 4/27/2011 9:19:05AM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Potassium 0.52 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:36 AML

Sodium 43.8 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:41 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 4/1/11 15:16 AML

Arsenic <0.005 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:35 AML

Barium 2.47 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:36 AML

Beryllium, Total <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:35 AML

Cadmium <0.005 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:36 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:40 AML

Cobalt <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:35 AML

Manganese <0.02 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:37 AML

Molybdenum <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:36 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 4/1/11 15:16 AML

Selenium <0.005 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:37 AML

Printed: 4/27/2011 9:19:05AM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Silver <0.005 mg/L 0.005 mg/L EPA 200.7 4/5/11 16:35 AML

Strontium 2.28 mg/l 0.10 mg/l EPA 200.7 4/1/11 14:38 AML

Thallium <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:36 AML

Tin <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:34 AML

Titanium <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:34 AML

Zinc <0.02 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:41 AML

Gross Alpha DW 1.93 PCi/L 3 PCi/L EPA 900 4/7/11 16:06 6502103

Gross Beta DW 1.57 PCi/L 4 PCi/L EPA 900 4/7/11 16:06 6502103

Radium 226 2.87 pCi/L .6 pCi/L EPA 903.1 4/15/11 16:07 6502103

Radium 228 0.296 pCi/L .9 pCi/L EPA 904.0 4/15/11 16:07 6502103

Phenolics 0.02 mg/L 0.01 mg/L EPA 420.4 4/11/11 13:43 22-293

Uranium, Total ND 0.25 mg/L SW846 6020A 4/16/11 6:26 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 4/8/11 9:26 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 4/1/11 15:17 AML

Lithium, Total 0.082 mg/L 0.050 mg/L EPA 200.7 4/5/11 14:12 22-293

Boron 0.06 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:40 AML

Antimony <0.005 mg/L 0.005 mg/L EPA 200.7 4/6/11 10:36 AML

Silicon, Total 0.16 mg/L 0.050 mg/L EPA 200.7 4/11/11 14:54 22-293

Bromide 0.92 mg/l 0.10 mg/l EPA 300.1 4/1/11 13:05 AML

Hardness, Total 32.0 mg/l 10 mg/l EPA 200.7 4/1/11 14:48 AML

Heterotrophic 

Plate Count

8,100 /ml 1 /ml SM 9215B 3/31/11 15:47 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 3/31/11 15:45 TSA

E Coli NA +/- SM 9223B 3/31/11 15:45 TSA

Specific 

Conductance

375.0 umhos/cm 2 umhos/cm EPA 120.1 4/1/11 11:47 AML

Gasoline Range 

Organics

ND 500 ug/L SW846 8015D 4/5/11 23:24 22-293

Diesel Range 

Organics C10-C28

4.9 mg/L 0.77 mg/L SW846 8015D 4/7/11 16:26 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Methane ND 1.0 ug/L RSK 175 4/11/11 16:30 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 4/9/11 3:04 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 4/2/11 5:31 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 4/2/11 5:31 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 4/2/11 5:31 22-293

Total Kjeldahl 

Nitrogen

4.5 mg/L 1.0 mg/L SM20-4500-N C 4/5/11 12:37 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 4/11/11 22:16 22-293

Acetone 524 ug/L 10.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Silica, Dissolved ND 1 mg/L SM20-4500SiO2C 4/9/11 1:34 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 4/9/11 19:35 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 4/9/11 19:35 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Ethene ND 3.0 ug/L RSK 175 4/11/11 16:30 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Methanol ND 1.0 mg/L SW846 8015D 4/8/11 17:32 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

mp-Xylene ND 2.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Ethane ND 3.0 ug/L RSK 175 4/11/11 16:30 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Chloroform ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Carbon Disulfide ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Bromochlorometh

ane

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,1,2,2-Tetrachlor

oethane

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,2-Dichloropropa

ne

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

trans-1,2-Dichloro

ethene

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

trans-1,3-Dichloro

propene

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Benzene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Styrene ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Toluene 1.3 ug/L 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Vinyl Chloride ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 4/5/11 14:12 22-293

Copper <0.02 mg/l 0.02 mg/l EPA 200.7 4/1/11 14:38 AML

Bromoform ND 1.0 ug/L SW846 8260B 4/9/11 19:35 22-293

Printed: 4/27/2011 9:19:05AM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

03111241

Altela

D W Water

DW Tank

N/A

03/31/11 10:00

03/31/11 12:57

N/A

Grab

Thorium 228 0.103 pCi/L pCi/L HSL-300M 4/19/11 16:08 6502103

Thorium 230 0.169 pCi/L pCi/L HSL-300m 4/19/11 16:08 6502103

Thorium 232 0.016 pCi/L pCi/L HSL-300m 4/19/11 16:09 6502103

Sample Comments:

None

Printed: 4/27/2011 9:19:05AM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#04110152

PRODUCED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Total Residual 

Chlorine, Field

0.00 mg/L 0.1 mg/L HACH 8167 4/6/11 0:00 RCJ

pH 6.51 SU SU SM4500 H+B 4/6/11 16:39 AML

Total Dissolved 

Solids

25560 mg/l 5 mg/l SM 2540 C 4/7/11 14:17 TSA

Total Suspended 

Solids

54 mg/L 3 mg/L SM 2540 D 4/6/11 16:23 MH

Oil & Grease 3.7 mg/l 5 mg/l EPA 1664 Rev A 4/8/11 0:00 TO

BOD 99.6 mg/L 2 mg/L SM5210B 4/7/11 10:46 TSA

COD 265 mg/L 10 mg/L HACH 8000 4/11/11 0:00 TO

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 4/7/11 22:00 22-293

Color 75 pccu 5 pccu 4/6/11 10:35 WEH

Temperature (F), 

Field

61 deg F deg F na 4/6/11 0:00 RCJ

Osmotic Pressure 589 mOs/kg 10 mOs/kg PA DEP 4/8/11 4:25 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 4/6/11 15:09 WEH

Ammonia 

Nitrogen

23.1 mg/L .10 mg/L SM 4500 NH3 D 4/7/11 10:05 WEH

Printed: 4/28/2011 4:46:20PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Nitrate <10 mg/l 0.10 mg/l EPA 300.0 4/7/11 15:04 AML

Nitrite <10 mg/l 0.10 mg/l EPA 300.0 4/7/11 15:03 AML

Nitrate / Nitrite <20 mg/l 0.20 mg/l EPA 300.0 4/7/11 15:03 AML

Acidity -16.0 mg/L 3 mg/L SM 2310 B 4/7/11 12:58 AML

Alkalinity 100.0 mg/l 5 mg/l SM 2320 B 4/6/11 16:39 AML

Bicarbonate 100.0 mg/L 5 mg/L SM4500 CO2 D 4/7/11 10:47 AML

Sulfate <100 mg/l 1 mg/l EPA 300.0 4/7/11 15:02 AML

Chloride 11,352 mg/L 1 mg/L EPA 300.0 4/7/11 15:05 AML

Fluoride <20 mg/l 0.20 mg/l EPA 300.0 4/7/11 15:04 AML

Calcium 1,175 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:01 AML

Iron 18.5 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:11 AML

Iron, Dissolved 14.3 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:09 AML

Magnesium 109.8 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:00 AML

Printed: 4/28/2011 4:46:20PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Potassium 59.6 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:10 AML

Sodium 4,712 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:01 AML

Aluminum <5.0 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:13 AML

Arsenic <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:27 AML

Barium 260.5 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:09 AML

Beryllium, Total <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:26 AML

Cadmium <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:27 AML

Chromium <1.0 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:14 AML

Cobalt <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:28 AML

Manganese 2.0 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:12 AML

Molybdenum <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:28 AML

Nickel <2.5 mg/l 0.05 mg/l EPA 200.7 4/8/11 16:14 AML

Selenium <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:28 AML

Printed: 4/28/2011 4:46:20PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Silver <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:29 AML

Strontium 233.0 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:10 AML

Thallium <0.01 mg/L 0.005 mg/L EPA 200.7 4/14/11 14:29 AML

Tin <0.01 mg/L 0.005 mg/L EPA 200.7 4/14/11 14:29 AML

Titanium <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:30 AML

Zinc <1.0 mg/l 0.02 mg/l EPA 200.7 4/8/11 11:17 AML

Gross Alpha DW 249 PCi/L 3 PCi/L EPA 900 4/15/11 16:10 6502103

Gross Beta DW 178 PCi/L 4 PCi/L EPA 900 4/11/11 16:11 6502103

Radium 226 130 pCi/L .6 pCi/L EPA 903.1 4/20/11 16:12 6502103

Radium 228 55.0 pCi/L .9 pCi/L EPA 904.0 4/27/11 16:13 6502103

Phenolics ND 0.01 mg/L EPA 420.4 4/11/11 13:48 22-293

Uranium, Total ND 0.11 mg/L SW846 6020A 4/16/11 6:54 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 4/13/11 11:43 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Lead <1.0 mg/L 0.02 mg/L EPA 200.7 4/8/11 16:16 AML

Lithium, Total 10.7 mg/L 2.5 mg/L EPA 200.7 4/14/11 14:31 22-293

Boron <1.0 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:10 AML

Antimony <0.01 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:30 AML

Silicon, Total 6.4 mg/L 2.5 mg/L EPA 200.7 4/15/11 10:48 22-293

Bromide 117.0 mg/l 0.10 mg/l EPA 300.1 4/7/11 15:05 AML

Hardness, Total 3,386 mg/l 10 mg/l EPA 200.7 4/8/11 16:07 AML

Heterotrophic 

Plate Count

140 /ml 1 /ml SM 9215B 4/6/11 15:00 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 4/6/11 15:00 TSA

E Coli NA +/- SM 9223B 4/6/11 15:00 TSA

Specific 

Conductance

31,600 umhos/cm 2 umhos/cm EPA 120.1 4/6/11 15:08 AML

Gasoline Range 

Organics

ND 500 ug/L SW846 8015D 4/9/11 0:35 22-293

Diesel Range 

Organics C10-C28

4.3 mg/L 0.79 mg/L SW846 8015D 4/18/11 12:51 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Methane 4550 ug/L 1.0 ug/L RSK 175 4/12/11 16:47 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 4/14/11 12:25 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 4/8/11 11:59 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 4/8/11 11:59 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 4/8/11 11:59 22-293

Total Kjeldahl 

Nitrogen

19.7 mg/L 4.0 mg/L SM20-4500-N C 4/11/11 11:11 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 4/11/11 22:50 22-293

Acetone 11800 ug/L 500 ug/L SW846 8260B 4/15/11 7:45 22-293

Silica, Dissolved 19 mg/L 5 mg/L SM20-4500SiO2C 4/9/11 1:34 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 4/14/11 23:51 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 4/14/11 23:51 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Ethene ND 6.0 ug/L RSK 175 4/12/11 16:44 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Methanol ND 1.0 mg/L SW846 8015D 4/20/11 20:57 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

mp-Xylene ND 2.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Ethane 6.3 ug/L 3.0 ug/L RSK 175 4/12/11 16:47 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Chloroform ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Carbon Disulfide ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Bromochlorometh

ane

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,1,2,2-Tetrachlor

oethane

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,2-Dichloropropa

ne

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

trans-1,2-Dichloro

ethene

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

trans-1,3-Dichloro

propene

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Benzene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Styrene ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Toluene 15.0 ug/L 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Vinyl Chloride ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Vanadium, Total ND 0.13 mg/L EPA 200.7 4/14/11 14:31 22-293

Copper <1.0 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:13 AML

Bromoform ND 1.0 ug/L SW846 8260B 4/14/11 23:51 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110152

Altela

PW Water

PW Influent

Discharge

04/06/11 08:00

04/06/11 10:06

N/A

Grab

Thorium 228 11.082 pCi/L pCi/L HSL-300M 4/19/11 16:14 6502103

Thorium 230 0.100 pCi/L pCi/L HSL-300m 4/19/11 16:15 6502103

Thorium 232 0.035 pCi/L pCi/L HSL-300m 4/19/11 16:15 6502103

Sample Comments:

BOD: Duplicate analysis recovery was outside established control limits.

Printed: 4/28/2011 4:46:20PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#04110153

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Total Residual 

Chlorine, Field

0.00 mg/L 0.1 mg/L HACH 8167 4/6/11 0:00 RCJ

pH 5.77 SU SU SM4500 H+B 4/6/11 16:39 AML

Total Dissolved 

Solids

400 mg/l 5 mg/l SM 2540 C 4/7/11 14:17 TSA

Total Suspended 

Solids

< 3 mg/L 3 mg/L SM 2540 D 4/6/11 16:23 MH

Oil & Grease 1.0 mg/l 5 mg/l EPA 1664 Rev A 4/8/11 0:00 TO

BOD 38.8 mg/L 2 mg/L SM5210B 4/7/11 10:46 TSA

COD 51.4 mg/L 10 mg/L HACH 8000 4/11/11 0:00 TO

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 4/7/11 22:00 22-293

Color < 5 pccu 5 pccu 4/6/11 10:35 WEH

Temperature (F), 

Field

97 deg F deg F na 4/6/11 0:00 RCJ

Osmotic Pressure ND 10 mOs/kg PA DEP 4/8/11 4:25 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 4/6/11 15:09 WEH

Ammonia 

Nitrogen

3.25 mg/L .10 mg/L SM 4500 NH3 D 4/7/11 10:05 WEH

Printed: 4/28/2011 4:46:20PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Nitrate <0.10 mg/l 0.10 mg/l EPA 300.0 4/7/11 15:04 AML

Nitrite <0.10 mg/l 0.10 mg/l EPA 300.0 4/7/11 15:03 AML

Nitrate / Nitrite <0.20 mg/l 0.20 mg/l EPA 300.0 4/7/11 15:03 AML

Acidity <5.0 mg/L 3 mg/L SM 2310 B 4/7/11 12:58 AML

Alkalinity 12.0 mg/l 5 mg/l SM 2320 B 4/6/11 16:39 AML

Bicarbonate 12.0 mg/L 5 mg/L SM4500 CO2 D 4/7/11 10:47 AML

Sulfate 2.1 mg/l 1 mg/l EPA 300.0 4/7/11 15:02 AML

Chloride 184.2 mg/L 1 mg/L EPA 300.0 4/7/11 15:05 AML

Fluoride 0.42 mg/l 0.20 mg/l EPA 300.0 4/7/11 15:04 AML

Calcium 22.2 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:01 AML

Iron 0.08 mg/l 0.02 mg/l EPA 200.7 4/7/11 14:53 AML

Iron, Dissolved 0.06 mg/l 0.02 mg/l EPA 200.7 4/8/11 16:09 AML

Magnesium 2.04 mg/l 0.10 mg/l EPA 200.7 4/7/11 14:52 AML

Printed: 4/28/2011 4:46:20PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Potassium 0.98 mg/l 0.10 mg/l EPA 200.7 4/7/11 14:51 AML

Sodium 87.9 mg/l 0.10 mg/l EPA 200.7 4/8/11 16:01 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 4/7/11 14:48 AML

Arsenic <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:27 AML

Barium 4.54 mg/l 0.10 mg/l EPA 200.7 4/7/11 14:50 AML

Beryllium, Total <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:26 AML

Cadmium <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:27 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 4/7/11 14:47 AML

Cobalt <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:28 AML

Manganese 0.04 mg/l 0.02 mg/l EPA 200.7 4/7/11 15:00 AML

Molybdenum <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:28 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 4/7/11 14:48 AML

Selenium <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:28 AML

Printed: 4/28/2011 4:46:20PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Silver <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:29 AML

Strontium 3.93 mg/l 0.10 mg/l EPA 200.7 4/7/11 14:49 AML

Thallium <0.005 mg/L 0.005 mg/L EPA 200.7 4/14/11 14:29 AML

Tin <0.005 mg/L 0.005 mg/L EPA 200.7 4/14/11 14:29 AML

Titanium <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:30 AML

Zinc 0.04 mg/l 0.02 mg/l EPA 200.7 4/7/11 14:45 AML

Gross Alpha DW 6.49 PCi/L 3 PCi/L EPA 900 4/12/11 16:10 6502103

Gross Beta DW 0.754 PCi/L 4 PCi/L EPA 900 4/12/11 16:11 6502103

Radium 226 2.30 pCi/L .6 pCi/L EPA 903.1 4/20/11 16:12 6502103

Radium 228 0.490 pCi/L .9 pCi/L EPA 904.0 4/20/11 16:13 6502103

Phenolics 0.02 mg/L 0.01 mg/L EPA 420.4 4/11/11 13:53 22-293

Uranium, Total ND 0.25 mg/L SW846 6020A 4/16/11 7:02 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 4/13/11 11:44 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 4/7/11 14:47 AML

Lithium, Total 0.13 mg/L 0.050 mg/L EPA 200.7 4/12/11 15:05 22-293

Boron 0.06 mg/l 0.02 mg/l EPA 200.7 4/7/11 14:46 AML

Antimony <0.005 mg/L 0.005 mg/L EPA 200.7 4/13/11 14:30 AML

Silicon, Total 0.22 mg/L 0.050 mg/L EPA 200.7 4/15/11 10:53 22-293

Bromide 1.60 mg/l 0.10 mg/l EPA 300.1 4/7/11 15:05 AML

Hardness, Total 64.0 mg/l 10 mg/l EPA 200.7 4/8/11 16:07 AML

Heterotrophic 

Plate Count

7,020 /ml 1 /ml SM 9215B 4/6/11 15:00 TSA

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 4/6/11 15:00 TSA

E Coli NA +/- SM 9223B 4/6/11 15:00 TSA

Specific 

Conductance

632.0 umhos/cm 2 umhos/cm EPA 120.1 4/6/11 15:08 AML

Gasoline Range 

Organics

ND 100 ug/L SW846 8015D 4/8/11 23:59 22-293

Diesel Range 

Organics C10-C28

3.1 mg/L 0.77 mg/L SW846 8015D 4/18/11 13:33 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Methane ND 1.0 ug/L RSK 175 4/12/11 16:36 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 4/14/11 12:46 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 4/8/11 12:04 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 4/8/11 12:04 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 4/8/11 12:04 22-293

Total Kjeldahl 

Nitrogen

4.1 mg/L 2.0 mg/L SM20-4500-N C 4/12/11 21:00 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 4/11/11 23:07 22-293

Acetone 658 ug/L 10.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Silica, Dissolved ND 1 mg/L SM20-4500SiO2C 4/9/11 1:34 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 4/14/11 18:59 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 4/14/11 18:59 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Ethene ND 6.0 ug/L RSK 175 4/12/11 16:44 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Methanol ND 1.0 mg/L SW846 8015D 4/20/11 21:42 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

mp-Xylene ND 2.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Ethane ND 3.0 ug/L RSK 175 4/12/11 16:36 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Chloroform ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Carbon Disulfide ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Bromochlorometh

ane

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,1,2,2-Tetrachlor

oethane

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,2-Dichloropropa

ne

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

trans-1,2-Dichloro

ethene

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

trans-1,3-Dichloro

propene

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Benzene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Styrene ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Toluene 1.1 ug/L 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Vinyl Chloride ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 4/12/11 15:05 22-293

Copper 0.08 mg/l 0.02 mg/l EPA 200.7 4/7/11 14:46 AML

Bromoform ND 1.0 ug/L SW846 8260B 4/14/11 18:59 22-293

Printed: 4/28/2011 4:46:20PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

04110153

Altela

DW Tank

DW Water

Discharge

04/06/11 08:30

04/06/11 10:28

N/A

Grab

Thorium 228 0.128 pCi/L pCi/L HSL-300M 4/20/11 16:14 6502103

Thorium 230 0.113 pCi/L pCi/L HSL-300m 4/20/11 16:15 6502103

Thorium 232 -0.009 pCi/L pCi/L HSL-300m 4/20/11 16:15 6502103

Sample Comments:

BOD: Duplicate analysis recovery was outside established control limits.

Printed: 4/28/2011 4:46:20PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
APPENDIX D

WATER QUALITY REPORTS 

(TEST-BENCH CONCENTRATE 

WATER AND DISTILLED WATER)
WATER QUALITY REPORT

#02100762

PRODUCED WATER

TEST-BENCH

CONCENTRATE WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Thorium 232 0.150 pCi/L pCi/L HSL-300m 3/19/10 13:34 6502103

Thorium 228 22.7 pCi/L pCi/L HSL-300M 3/19/10 13:32 6502103

Thorium 230 0.465 pCi/L pCi/L HSL-300m 3/19/10 13:34 6502103

Copper 2.0 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:16 AML

Benzene 1.2 ug/L 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

pH 5.96 SU SU SM4500 H+B 2/24/10 15:21 AML

Total Dissolved 

Solids

345,680 mg/l 5 mg/l SM 2540 C 2/23/10 11:49 RCS

Total Suspended 

Solids

176 mg/L 3 mg/L SM 2540 D 2/23/10 13:00 RCS

Oil & Grease 2.2 mg/l 5 mg/l EPA 1664 Rev A 2/26/10 12:40 NJD

BOD 62.7 mg/L 2 mg/L SM5210B 2/24/10 10:35 TO

COD 3800 mg/L 10 mg/L HACH 8000 3/10/10 7:22 NJD

Surfactants 

(MBAS)

0.184 mg/L 0.025 mg/L SM20-5540 C 2/24/10 21:45 22-293

Color 20 pccu 5 pccu 2/23/10 11:16 WEH

Printed: 3/25/2010 3:52:05PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Temperature (F), 

Field

NA deg F na 3/5/10 9:02 RCS

Osmotic Pressure 2970 mOs/kg 10 mOs/kg PA DEP 2/25/10 6:00 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 2/25/10 8:42 WEH

Ammonia 

Nitrogen

267 mg/L .10 mg/L SM 4500 NH3 D 2/25/10 9:40 WEH

Nitrate <5.0 mg/l 0.10 mg/l EPA 300.0 2/24/10 12:52 AML

Nitrite <5.0 mg/l 0.10 mg/l EPA 300.0 2/24/10 12:51 AML

Nitrate / Nitrite <10.0 mg/l 0.20 mg/l EPA 300.0 2/24/10 12:51 AML

Acidity 236.0 mg/L 3 mg/L SM 2310 B 2/24/10 16:13 AML

Alkalinity 32.0 mg/l 5 mg/l SM 2320 B 2/24/10 15:20 AML

Bicarbonate 32.0 mg/L 5 mg/L SM4500 CO2 D 2/25/10 10:46 AML

Sulfate 550.0 mg/l 1 mg/l EPA 300.0 2/24/10 12:52 AML

Chloride 205200 mg/L 1 mg/L EPA 300.0 2/24/10 12:53 AML

Fluoride 10.5 mg/l 0.20 mg/l EPA 300.0 2/24/10 12:52 AML

Printed: 3/25/2010 3:52:06PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Calcium 29,800 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Iron 2.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Iron, Dissolved <0.4 mg/l 0.02 mg/l EPA 200.7 3/12/10 13:47 AML

Magnesium 3120.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Potassium 1320 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Sodium 85,600 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Aluminum <2.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:25 AML

Arsenic <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Barium 148.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:28 AML

Beryllium <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Cadmium <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Chromium <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Cobalt <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Printed: 3/25/2010 3:52:06PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Manganese 8.2 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Molybdenum <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Nickel <1.0 mg/l 0.05 mg/l EPA 200.7 2/26/10 14:51 AML

Selenium <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:58 AML

Silver <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:57 AML

Strontium, Total 4970 mg/L 1.5 mg/L EPA 200.7 3/5/10 9:10 22-293

Thallium <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:59 AML

Tin <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:02 AML

Titanium <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Zinc <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Gross Alpha DW 1,912 PCi/L 3 PCi/L EPA 900 3/3/10 11:49 6502103

Gross Beta DW 529 PCi/L 4 PCi/L EPA 900 3/3/10 11:49 6502103

Radium 226 1,527 pCi/L .6 pCi/L EPA 903.1 3/19/10 11:47 6502103

Printed: 3/25/2010 3:52:06PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Radium 228 751 pCi/L .9 pCi/L EPA 904.0 3/18/10 11:48 6502103

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 2/23/10 15:39 RCS

Phenolics ND 0.01 mg/L EPA 420.4 3/1/10 10:11 22-293

Uranium ND 1.1 mg/L SW846 6020A 3/8/10 14:52 22-293

Mercury, Total ND 0.013 mg/L EPA 245.1 3/1/10 12:01 22-293

Lead <0.4 mg/L 0.02 mg/L EPA 200.7 2/26/10 14:51 AML

Lithium, Total 319 mg/L 30.0 mg/L EPA 200.7 3/5/10 9:10 22-293

Boron 17.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:48 AML

Antimony <1.0 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Silicon, Total 10.0 mg/L 10.0 mg/L EPA 200.7 3/3/10 11:07 22-293

Bromide 2360.0 mg/l 0.10 mg/l EPA 300.1 2/24/10 12:53 AML

Hardness, Total 87,259 mg/l 10 mg/l EPA 200.7 2/26/10 13:43 AML

Heterotrophic 

Plate Count

32 /ml 1 /ml SM 9215B 2/23/10 15:14 WEH

Printed: 3/25/2010 3:52:06PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/23/10 15:14 WEH

E Coli NA +/- SM 9223B 2/23/10 15:14 WEH

Specific 

Conductance

234,000 umhos/cm 2 umhos/cm EPA 120.1 2/23/10 0:00 WEH

Gasoline Range 

Organics

ND 500 ug/L SW846 8015D 3/1/10 20:52 22-293

Diesel Range 

Organics C10-C28

1.0 mg/L 0.15 mg/L SW846 8015D 2/28/10 1:53 22-293

Methane ND 1.0 ug/L RSK 175 2/26/10 20:39 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/25/10 2:54 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/25/10 8:31 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/25/10 8:31 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/25/10 8:31 22-293

Total Kjeldahl 

Nitrogen

42.3 mg/L 1.0 mg/L SM20-4500-N C 2/27/10 11:00 22-293

Formaldehyde 34.5 mg/L 1.0 mg/L SW846 8015D 3/4/10 17:41 22-293

Acetone 978 ug/L 10.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Silica, Dissolved 15 mg/L 1 mg/L SM20-4500SiD 3/2/10 0:15 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 3/1/10 7:00 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 3/1/10 7:00 22-293

2-Butanone 74.0 ug/L 10.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Ethene ND 3.0 ug/L RSK 175 2/26/10 20:39 22-293

Methanol 11.3 mg/L 1.0 mg/L SW846 8015D 3/7/10 20:54 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

mp-Xylene 3.3 ug/L 2.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Ethane ND 3.0 ug/L RSK 175 2/26/10 20:39 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Chloroform ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Bromomethane ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Carbon Disulfide ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Bromide 2000 mg/L 1000 mg/L EPA 300 3/2/10 6:42 22-293

Bromochlorometha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,1,2,2-Tetrachloro

ethane

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,2-Dichloropropan

e

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Chlorobenzene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

trans-1,2-Dichloroe

thene

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

trans-1,3-Dichlorop

ropene

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Styrene ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Toluene 3.0 ug/L 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100762

Altela

NETL Ross PW

Resutant CW

N/A

02/18/10 17:25

02/23/10 11:03

N/A

Grab

Vinyl Chloride 24.8 ug/L 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Total Xylenes 4.1 ug/L 3.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Vanadium, Total ND 1.5 mg/L EPA 200.7 3/5/10 9:10 22-293

Bromoform ND 1.0 ug/L SW846 8260B 3/1/10 7:00 22-293

Sample Comments:

BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Printed: 3/25/2010 3:52:06PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100763

PRODUCED WATER

TEST-BENCH

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Thorium 232 0.000 pCi/L pCi/L HSL-300m 3/18/10 13:35 6502103

Copper <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:16 AML

Thorium 228 0.177 pCi/L pCi/L HSL-300M 3/18/10 13:32 6502103

Thorium 230 0.400 pCi/L pCi/L HSL-300m 3/18/10 13:34 6502103

Benzene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

pH 8.58 SU SU SM4500 H+B 2/24/10 15:21 AML

Total Dissolved 

Solids

88 mg/l 5 mg/l SM 2540 C 2/23/10 11:49 RCS

Total Suspended 

Solids

<3 mg/L 3 mg/L SM 2540 D 2/23/10 13:00 RCS

Oil & Grease 2.9 mg/l 5 mg/l EPA 1664 Rev A 2/26/10 12:40 NJD

BOD > 75.3 2 mg/L SM5210B 2/24/10 10:35 TO

COD 185 mg/L 10 mg/L HACH 8000 3/10/10 7:22 NJD

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 2/24/10 21:45 22-293

Color < 5 pccu 5 pccu 2/23/10 11:16 WEH

Printed: 3/25/2010 3:52:06PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Temperature (F), 

Field

NA deg F na 3/5/10 9:02 RCS

Osmotic Pressure 27 mOs/kg 10 mOs/kg PA DEP 2/25/10 6:00 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 2/25/10 8:42 WEH

Ammonia 

Nitrogen

6.99 mg/L .10 mg/L SM 4500 NH3 D 2/25/10 9:40 WEH

Nitrate <0.10 mg/l 0.10 mg/l EPA 300.0 2/24/10 12:52 AML

Nitrite <0.10 mg/l 0.10 mg/l EPA 300.0 2/24/10 12:51 AML

Nitrate / Nitrite <0.20 mg/l 0.20 mg/l EPA 300.0 2/24/10 12:51 AML

Acidity -18.0 mg/L 3 mg/L SM 2310 B 2/24/10 16:13 AML

Alkalinity 30.0 mg/l 5 mg/l SM 2320 B 2/24/10 15:20 AML

Bicarbonate 29.0 mg/L 5 mg/L SM4500 CO2 D 2/25/10 10:46 AML

Sulfate 3.1 mg/l 1 mg/l EPA 300.0 2/24/10 12:52 AML

Chloride 45.1 mg/L 1 mg/L EPA 300.0 2/24/10 12:53 AML

Fluoride 0.16 mg/l 0.20 mg/l EPA 300.0 2/24/10 12:52 AML

Printed: 3/25/2010 3:52:06PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Calcium 5.12 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Iron <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Iron, Dissolved <0.02 mg/l 0.02 mg/l EPA 200.7 3/12/10 13:47 AML

Magnesium 0.47 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Potassium 0.35 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Sodium 24.8 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:56 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:25 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Barium <0.10 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:28 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Cobalt <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Printed: 3/25/2010 3:52:06PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Manganese <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Molybdenum <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 2/26/10 14:51 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:58 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:57 AML

Strontium, Total 0.70 mg/L 0.0025 mg/L EPA 200.7 3/1/10 14:34 22-293

Thallium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:59 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:02 AML

Titanium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Zinc <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Gross Alpha DW 0.685 PCi/L 3 PCi/L EPA 900 3/3/10 11:49 6502103

Gross Beta DW 0.429 PCi/L 4 PCi/L EPA 900 3/3/10 11:49 6502103

Radium 226 0.231 pCi/L .6 pCi/L EPA 903.1 3/17/10 11:47 6502103

Printed: 3/25/2010 3:52:06PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Radium 228 0.434 pCi/L .9 pCi/L EPA 904.0 3/11/10 11:48 6502103

Total Residual 

Chlorine

<0.10 mg/L 0.10 mg/L HACH 8167 2/23/10 15:39 RCS

Phenolics 0.06 mg/L 0.01 mg/L EPA 420.4 3/1/10 10:12 22-293

Uranium ND 1.1 mg/L SW846 6020A 3/8/10 14:54 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 3/1/10 12:02 22-293

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 2/26/10 14:51 AML

Lithium, Total ND 0.050 mg/L EPA 200.7 3/1/10 14:34 22-293

Boron <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:48 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Silicon, Total 0.20 mg/L 0.050 mg/L EPA 200.7 3/3/10 11:11 22-293

Bromide 0.40 mg/l 0.10 mg/l EPA 300.1 2/24/10 12:53 AML

Hardness, Total 15 mg/l 10 mg/l EPA 200.7 2/26/10 13:43 AML

Heterotrophic 

Plate Count

5400 /ml 1 /ml SM 9215B 2/23/10 15:14 WEH

Printed: 3/25/2010 3:52:06PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/23/10 15:14 WEH

E Coli NA +/- SM 9223B 2/23/10 15:14 WEH

Specific 

Conductance

211 umhos/cm 2 umhos/cm EPA 120.1 2/23/10 0:00 WEH

Gasoline Range 

Organics

ND 100 ug/L SW846 8015D 2/27/10 0:36 22-293

Diesel Range 

Organics C10-C28

0.53 mg/L 0.15 mg/L SW846 8015D 2/28/10 3:52 22-293

Methane ND 1.0 ug/L RSK 175 2/26/10 20:54 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 2/25/10 3:15 22-293

Alkalinity, 

Carbonate

9 mg/L 5 mg/L SM20-2322 2/25/10 8:40 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/25/10 8:40 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/25/10 8:40 22-293

Total Kjeldahl 

Nitrogen

6.0 mg/L 1.0 mg/L SM20-4500-N C 2/27/10 11:00 22-293

Formaldehyde 1870 mg/L 500 mg/L SW846 8015D 3/4/10 19:22 22-293

Acetone 195 ug/L 10.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Silica, Dissolved ND 1 mg/L SM20-4500SiD 3/2/10 0:15 22-293

2-Hexanone ND 5.0 ug/L SW846 8260B 2/26/10 19:36 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 2/26/10 19:36 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Ethene ND 3.0 ug/L RSK 175 2/26/10 20:54 22-293

Methanol 1030 mg/L 100 mg/L SW846 8015D 3/3/10 19:07 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

mp-Xylene ND 2.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Ethane ND 3.0 ug/L RSK 175 2/26/10 20:54 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Chloroform ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Bromomethane ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Carbon Disulfide ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Bromide 0.43 mg/L 0.30 mg/L EPA 300 2/25/10 9:03 22-293

Bromochlorometha

ne

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,1,2,2-Tetrachloro

ethane

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,2-Dichloropropan

e

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Chlorobenzene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Tetrachloroethene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

trans-1,2-Dichloroe

thene

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

trans-1,3-Dichlorop

ropene

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Styrene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Toluene ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Printed: 3/25/2010 3:52:06PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100763

Altela

NETL Ross PW

Resultant DW

N/A

02/18/10 17:25

02/23/10 11:06

N/A

Grab

Vinyl Chloride ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 3/1/10 14:34 22-293

Bromoform ND 1.0 ug/L SW846 8260B 2/26/10 19:36 22-293

Sample Comments:

BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Printed: 3/25/2010 3:52:06PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100809

FRAC WATER

TEST-BENCH

CONCENTRATE WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Thorium 230 0.554 pCi/L pCi/L HSL-300m 3/18/10 13:34 6502103

Thorium 232 0.111 pCi/L pCi/L HSL-300m 3/18/10 13:35 6502103

Bromoform ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Copper 0.8 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:16 AML

Thorium 228 2.07 pCi/L pCi/L HSL-300M 3/18/10 13:32 6502103

pH 7.58 SU SU SM4500 H+B 2/24/10 15:21 AML

Total Dissolved 

Solids

52,504 mg/l 5 mg/l SM 2540 C 2/26/10 12:55 RCS

Total Suspended 

Solids

338 mg/L 3 mg/L SM 2540 D 2/25/10 14:00 RCS

Oil & Grease 6.4 mg/l 5 mg/l EPA 1664 Rev A 2/26/10 12:40 NJD

BOD 373 mg/L 2 mg/L SM5210B 2/25/10 9:38 TO

COD 2275 mg/L 10 mg/L HACH 8000 3/10/10 7:22 NJD

Surfactants 

(MBAS)

0.395 mg/L 0.025 mg/L SM20-5540 C 2/25/10 23:00 22-293

Color 150 pccu 5 pccu 2/24/10 11:47 WEH

Printed: 3/25/2010 3:53:35PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Temperature (F), 

Field

NA deg F na 3/5/10 9:02 RCS

Osmotic Pressure 1620 mOs/kg 10 mOs/kg PA DEP 2/26/10 6:50 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 2/25/10 8:42 WEH

Ammonia 

Nitrogen

9.04 mg/L .10 mg/L SM 4500 NH3 D 2/25/10 9:40 WEH

Nitrate < 5.0 mg/l 0.10 mg/l EPA 300.0 2/24/10 0:00 AML

Nitrite < 5 mg/l 0.10 mg/l EPA 300.0 2/24/10 0:00 AML

Nitrate / Nitrite < 10 mg/l 0.20 mg/l EPA 300.0 2/24/10 0:00 AML

Acidity 14.0 mg/L 3 mg/L SM 2310 B 2/24/10 16:13 AML

Alkalinity 160.0 mg/l 5 mg/l SM 2320 B 2/24/10 15:20 AML

Bicarbonate 159.0 mg/L 5 mg/L SM4500 CO2 D 2/25/10 10:46 AML

Sulfate 240 mg/l 1 mg/l EPA 300.0 2/24/10 0:00 AML

Chloride 32400 mg/L 1 mg/L EPA 300.0 2/24/10 0:00 AML

Fluoride 15.5 mg/l 0.20 mg/l EPA 300.0 2/24/10 0:00 AML

Printed: 3/25/2010 3:53:35PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Calcium 2540 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Iron 10.8 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Iron, Dissolved 11.1 mg/l 0.02 mg/l EPA 200.7 3/12/10 13:47 AML

Magnesium 240.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Potassium 180.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Sodium 15,840 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Aluminum <2.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:25 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Barium 25.4 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:28 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Chromium <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Cobalt <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Printed: 3/25/2010 3:53:35PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Manganese <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Molybdenum <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Nickel <1.0 mg/l 0.05 mg/l EPA 200.7 2/26/10 14:51 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:58 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:57 AML

Strontium, Total 305 mg/L 0.13 mg/L EPA 200.7 3/4/10 14:10 22-293

Thallium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:59 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:02 AML

Titanium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Zinc <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Gross Alpha DW -92.601 PCi/L 3 PCi/L EPA 900 3/3/10 11:53 6502103

Gross Beta DW 2.46 PCi/L 4 PCi/L EPA 900 3/3/10 11:53 6502103

Radium 226 86.2 pCi/L .6 pCi/L EPA 903.1 3/17/10 11:54 6502103

Printed: 3/25/2010 3:53:35PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Radium 228 16.9 pCi/L .9 pCi/L EPA 904.0 3/11/10 11:54 6502103

Phenolics 0.06 mg/L 0.01 mg/L EPA 420.4 3/1/10 11:26 22-293

Uranium ND 0.050 mg/L SW846 6020A 3/3/10 21:46 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 3/1/10 12:03 22-293

Lead <0.4 mg/L 0.02 mg/L EPA 200.7 2/26/10 14:51 AML

Lithium, Total 32.0 mg/L 2.5 mg/L EPA 200.7 3/4/10 14:10 22-293

Boron 10.0 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:48 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Silicon, Total 22.1 mg/L 2.5 mg/L EPA 200.7 3/3/10 11:34 22-293

Bromide 467.5 mg/l 0.10 mg/l EPA 300.1 2/24/10 0:00 AML

Hardness, Total 7331 mg/l 10 mg/l EPA 200.7 2/26/10 13:43 AML

Heterotrophic 

Plate Count

58000 /ml 1 /ml SM 9215B 2/24/10 15:30 WEH

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/24/10 15:50 WEH

Printed: 3/25/2010 3:53:35PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

E Coli NA +/- SM 9223B 2/24/10 15:50 WEH

Specific 

Conductance

76,600 umhos/cm 2 umhos/cm EPA 120.1 2/26/10 0:00 TO

Gasoline Range 

Organics

2560 ug/L 2500 ug/L SW846 8015D 3/4/10 1:55 22-293

Diesel Range 

Organics C10-C28

3.5 mg/L 0.76 mg/L SW846 8015D 3/3/10 10:17 22-293

Methane 5.5 ug/L 1.0 ug/L RSK 175 2/26/10 21:12 22-293

Ethylene Glycol 33.2 mg/L 10.0 mg/L SW846 8015D 3/5/10 20:01 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/26/10 11:22 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/26/10 11:22 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/26/10 11:22 22-293

Total Kjeldahl 

Nitrogen

5.4 mg/L 1.0 mg/L SM20-4500-N C 3/1/10 19:44 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 3/4/10 18:02 22-293

Acetone 1850 ug/L 50.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Silica, Dissolved 142 mg/L 10 mg/L SM20-4500SiD 3/2/10 0:15 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

2-Hexanone ND 25.0 ug/L SW846 8260B 2/26/10 21:08 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 25.0 ug/L SW846 8260B 2/26/10 21:08 22-293

2-Butanone ND 50.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Ethene ND 3.0 ug/L RSK 175 2/26/10 21:12 22-293

Methanol ND 1.0 mg/L SW846 8015D 9/8/10 21:51 22-293

o-Xylene 6.4 ug/L 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

mp-Xylene 34.2 ug/L 10.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Chloromethane ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Ethane 3.5 ug/L 3.0 ug/L RSK 175 2/26/10 21:12 22-293

Chlorodibromomet

hane

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Chloroethane ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Chloroform ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Bromomethane ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Carbon Disulfide ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Bromide 425 mg/L 150 mg/L EPA 300 2/26/10 5:06 22-293

Bromochlorometha

ne

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Bromodichloromet

hane

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,2-Dibromo-3-chl

oropropane

ND 35.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,2-Dibromoethan

e

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,1,2,2-Tetrachloro

ethane

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,1-Dichloroethane ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,1-Dichloroethene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

cis-1,2-Dichloroeth

ene

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Methylene 

Chloride

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,2-Dichloropropan

e

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Chlorobenzene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Tetrachloroethene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Trichloroethene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

trans-1,2-Dichloroe

thene

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

trans-1,3-Dichlorop

ropene

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

cis-1,3-Dichloropro

pene

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Benzene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Carbon 

Tetrachloride

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,2-Dichloroethane ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Ethylbenzene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Styrene ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Toluene 11.8 ug/L 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,1,1-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

1,1,2-Trichloroetha

ne

ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100809

Altela

NETL Frac water

Resultant CW

N/A

02/22/10 14:45

02/24/10 10:20

N/A

Grab

Vinyl Chloride ND 5.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Total Xylenes 40.6 ug/L 15.0 ug/L SW846 8260B 2/26/10 21:08 22-293

Vanadium, Total ND 0.13 mg/L EPA 200.7 3/4/10 14:10 22-293

Sample Comments:

BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Printed: 3/25/2010 3:53:35PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100810

FRAC WATER

TEST-BENCH

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Thorium 230 0.244 pCi/L pCi/L HSL-300m 3/18/10 13:34 6502103

Thorium 232 0.027 pCi/L pCi/L HSL-300m 3/18/10 13:35 6502103

Bromoform ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Copper <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:16 AML

Thorium 228 0.236 pCi/L pCi/L HSL-300M 3/18/10 13:32 6502103

pH 9.22 SU SU SM4500 H+B 2/24/10 15:21 AML

Total Dissolved 

Solids

198 mg/l 5 mg/l SM 2540 C 2/26/10 12:55 RCS

Total Suspended 

Solids

<3 mg/L 3 mg/L SM 2540 D 2/25/10 14:00 RCS

Oil & Grease 1.3 mg/l 5 mg/l EPA 1664 Rev A 2/26/10 12:40 NJD

BOD 74.3 mg/L 2 mg/L SM5210B 2/25/10 9:38 TO

COD 194 mg/L 10 mg/L HACH 8000 3/10/10 7:22 NJD

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 2/25/10 23:00 22-293

Color < 5 pccu 5 pccu 2/24/10 11:47 WEH

Printed: 3/25/2010 3:53:35PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Temperature (F), 

Field

NA deg F na 3/5/10 9:02 RCS

Osmotic Pressure ND 10 mOs/kg PA DEP 2/26/10 6:50 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 2/25/10 8:42 WEH

Ammonia 

Nitrogen

8.22 mg/L .10 mg/L SM 4500 NH3 D 2/25/10 9:40 WEH

Nitrate < 0.10 mg/l 0.10 mg/l EPA 300.0 2/24/10 0:00 AML

Nitrite < 0.10 mg/l 0.10 mg/l EPA 300.0 2/24/10 0:00 AML

Nitrate / Nitrite < 0.20 mg/l 0.20 mg/l EPA 300.0 2/24/10 0:00 AML

Acidity -118.0 mg/L 3 mg/L SM 2310 B 2/24/10 16:13 AML

Alkalinity 38.0 mg/l 5 mg/l SM 2320 B 2/24/10 15:20 AML

Bicarbonate 32.0 mg/L 5 mg/L SM4500 CO2 D 2/25/10 10:46 AML

Sulfate 2.4 mg/l 1 mg/l EPA 300.0 2/24/10 0:00 AML

Chloride 23.2 mg/L 1 mg/L EPA 300.0 2/24/10 0:00 AML

Fluoride 0.14 mg/l 0.20 mg/l EPA 300.0 2/24/10 0:00 AML

Printed: 3/25/2010 3:53:35PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Calcium 1.91 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Iron <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Iron, Dissolved 0.04 mg/l 0.02 mg/l EPA 200.7 3/12/10 13:47 AML

Magnesium 0.17 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Potassium 0.14 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Sodium 14.3 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:56 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:25 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Barium <0.10 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:28 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Cobalt <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Printed: 3/25/2010 3:53:35PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Manganese <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Molybdenum <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 2/26/10 14:51 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:58 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:57 AML

Strontium, Total 0.23 mg/L 0.0025 mg/L EPA 200.7 3/1/10 19:48 22-293

Thallium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:59 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:02 AML

Titanium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Zinc <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Gross Alpha DW -0.127 PCi/L 3 PCi/L EPA 900 3/3/10 11:53 6502103

Gross Beta DW 0.481 PCi/L 4 PCi/L EPA 900 3/3/10 11:53 6502103

Radium 226 0.144 pCi/L .6 pCi/L EPA 903.1 3/17/10 11:54 6502103

Printed: 3/25/2010 3:53:35PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Radium 228 0.238 pCi/L .9 pCi/L EPA 904.0 3/11/10 11:54 6502103

Phenolics 0.06 mg/L 0.01 mg/L EPA 420.4 3/1/10 11:27 22-293

Uranium ND 0.0050 mg/L SW846 6020A 3/3/10 21:17 22-293

Mercury, Total ND 0.00050 mg/L EPA 245.1 3/1/10 12:04 22-293

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 2/26/10 14:51 AML

Lithium, Total ND 0.050 mg/L EPA 200.7 3/1/10 19:48 22-293

Boron <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:48 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Silicon, Total 0.12 mg/L 0.050 mg/L EPA 200.7 3/3/10 11:55 22-293

Bromide 0.23 mg/l 0.10 mg/l EPA 300.1 2/24/10 0:00 AML

Hardness, Total <10 mg/l 10 mg/l EPA 200.7 2/26/10 13:43 AML

Heterotrophic 

Plate Count

5000 /ml 1 /ml SM 9215B 2/24/10 15:30 WEH

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/24/10 15:50 WEH

Printed: 3/25/2010 3:53:35PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

E Coli NA +/- SM 9223B 2/24/10 15:50 WEH

Specific 

Conductance

130 umhos/cm 2 umhos/cm EPA 120.1 2/26/10 0:00 TO

Gasoline Range 

Organics

266 ug/L 100 ug/L SW846 8015D 3/2/10 5:54 22-293

Diesel Range 

Organics C10-C28

1.4 mg/L 0.15 mg/L SW846 8015D 3/2/10 19:28 22-293

Methane ND 1.0 ug/L RSK 175 3/2/10 14:54 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 3/5/10 20:21 22-293

Alkalinity, 

Carbonate

15 mg/L 5 mg/L SM20-2322 2/26/10 11:30 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/26/10 11:30 22-293

Alkalinity, 

Phenolphthalein

7 mg/L 5 mg/L SM20-2320 B 2/26/10 11:30 22-293

Total Kjeldahl 

Nitrogen

7.2 mg/L 1.0 mg/L SM20-4500-N C 3/2/10 12:30 22-293

Formaldehyde 71.4 mg/L 1.0 mg/L SW846 8015D 3/4/10 18:14 22-293

Acetone 985 ug/L 10.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Silica, Dissolved ND 1 mg/L SM20-4500SiD 3/2/10 0:15 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

2-Hexanone ND 5.0 ug/L SW846 8260B 2/26/10 20:37 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 2/26/10 20:37 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Ethene ND 3.0 ug/L RSK 175 3/2/10 14:54 22-293

Methanol 22.3 mg/L 1.0 mg/L SW846 8015D 9/8/10 22:07 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

mp-Xylene ND 2.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Ethane ND 3.0 ug/L RSK 175 3/2/10 14:54 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Chloroform ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Carbon Disulfide ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Bromide 0.21 mg/L 0.10 mg/L EPA 300 2/26/10 5:21 22-293

Bromochlorometha

ne

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,1,2,2-Tetrachloro

ethane

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,2-Dichloropropan

e

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Tetrachloroethene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

trans-1,2-Dichloroe

thene

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

trans-1,3-Dichlorop

ropene

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Benzene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Styrene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Toluene ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Printed: 3/25/2010 3:53:35PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100810

Altela

NETL Frac Water

Resultant DW

N/A

02/22/10 14:45

02/24/10 10:21

N/A

Grab

Vinyl Chloride ND 1.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 2/26/10 20:37 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 3/1/10 19:48 22-293

Sample Comments:

BOD: Unseeded Blank depletion was greater than 0.2 mg/L limit.

Printed: 3/25/2010 3:53:35PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100864

FRAC FLOW-BACK WATER

TEST-BENCH

CONCENTRATE WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Thorium 228 5.31 pCi/L pCi/L HSL-300M 3/19/10 13:35 6502103

Thorium 230 0.635 pCi/L pCi/L HSL-300m 3/19/10 13:36 6502103

Thorium 232 0.276 pCi/L pCi/L HSL-300m 3/19/10 13:36 6502103

Copper 0.8 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:16 AML

Bromoform ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

pH 6.90 SU SU SM4500 H+B 2/25/10 15:10 AML

Total Dissolved 

Solids

113,460 mg/l 5 mg/l SM 2540 C 2/26/10 12:55 RCS

Total Suspended 

Solids

32 mg/L 3 mg/L SM 2540 D 2/25/10 14:00 RCS

Oil & Grease 1.4 mg/l 5 mg/l EPA 1664 Rev A 2/26/10 12:40 NJD

BOD > 379 2 mg/L SM5210B 2/26/10 9:13 TO

COD 1040 mg/L 10 mg/L HACH 8000 3/10/10 7:22 NJD

Surfactants 

(MBAS)

0.184 mg/L 0.025 mg/L SM20-5540 C 2/26/10 21:45 22-293

Color 250 pccu 5 pccu 2/25/10 11:36 WEH

Printed: 3/25/2010 3:54:21PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Temperature (F), 

Field

NA deg F na 3/5/10 9:02 RCS

Osmotic Pressure 3440 mOs/kg 10 mOs/kg PA DEP 2/27/10 4:35 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 3/3/10 13:51 WEH

Ammonia 

Nitrogen

28.2 mg/L .10 mg/L SM 4500 NH3 D 3/4/10 14:58 WEH

Nitrate <5.0 mg/l 0.10 mg/l EPA 300.0 2/26/10 10:43 AML

Nitrite <5.0 mg/l 0.10 mg/l EPA 300.0 2/26/10 10:44 AML

Nitrate / Nitrite <10.0 mg/l 0.20 mg/l EPA 300.0 2/26/10 10:43 AML

Acidity 50.0 mg/L 3 mg/L SM 2310 B 2/25/10 15:09 AML

Alkalinity 148.0 mg/l 5 mg/l SM 2320 B 2/25/10 15:10 AML

Bicarbonate 148.0 mg/L 5 mg/L SM4500 CO2 D 2/25/10 10:46 AML

Sulfate 275.0 mg/l 1 mg/l EPA 300.0 2/26/10 10:45 AML

Chloride 64,800 mg/L 1 mg/L EPA 300.0 2/26/10 10:42 AML

Fluoride 12.0 mg/l 0.20 mg/l EPA 300.0 2/26/10 10:45 AML

Printed: 3/25/2010 3:54:21PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Calcium 6780 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Iron 16.6 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Iron, Dissolved 16.7 mg/l 0.02 mg/l EPA 200.7 3/12/10 13:47 AML

Magnesium 660.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Potassium 360.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Sodium 32,200 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Aluminum <2.0 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:25 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Barium 45.4 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:28 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Chromium <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Cobalt <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Printed: 3/25/2010 3:54:21PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Manganese 2.6 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Molybdenum <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Nickel <1.0 mg/l 0.05 mg/l EPA 200.7 2/26/10 14:51 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:58 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:57 AML

Strontium, Total 788 mg/L 0.25 mg/L EPA 200.7 3/4/10 10:25 22-293

Thallium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:59 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:02 AML

Titanium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Zinc <0.4 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Gross Alpha DW 15.8 PCi/L 3 PCi/L EPA 900 3/3/10 11:56 6502103

Gross Beta DW 86.5 PCi/L 4 PCi/L EPA 900 3/3/10 11:57 6502103

Radium 226 46.6 pCi/L .6 pCi/L EPA 903.1 3/17/10 11:58 6502103

Printed: 3/25/2010 3:54:21PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Radium 228 17.9 pCi/L .9 pCi/L EPA 904.0 3/18/10 11:58 6502103

Phenolics 0.02 mg/L 0.01 mg/L EPA 420.4 3/1/10 11:48 22-293

Uranium ND 0.050 mg/L SW846 6020A 3/3/10 21:56 22-293

Mercury, Total ND 0.010 mg/L EPA 200.8 3/4/10 8:29 22-293

Lead <0.4 mg/L 0.02 mg/L EPA 200.7 2/26/10 14:51 AML

Lithium, Total 66.1 mg/L 5.0 mg/L EPA 200.7 3/4/10 10:25 22-293

Boron 17.0 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:48 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Silicon, Total 26.6 mg/L 5.0 mg/L EPA 200.7 3/3/10 11:59 22-293

Bromide 995.0 mg/l 0.10 mg/l EPA 300.1 2/26/10 10:44 AML

Hardness, Total 19,648 mg/l 10 mg/l EPA 200.7 2/26/10 13:43 AML

Heterotrophic 

Plate Count

8,200 /ml 1 /ml SM 9215B 2/25/10 15:37 WEH

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/25/10 15:35 WEH

Printed: 3/25/2010 3:54:21PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

E Coli NA +/- SM 9223B 2/25/10 15:35 WEH

Specific 

Conductance

143,500 umhos/cm 2 umhos/cm EPA 120.1 2/26/10 0:00 TO

Gasoline Range 

Organics

2850 ug/L 2500 ug/L SW846 8015D 3/4/10 1:21 22-293

Diesel Range 

Organics C10-C28

5.1 mg/L 0.75 mg/L SW846 8015D 3/3/10 11:16 22-293

Methane ND 1.0 ug/L RSK 175 3/2/10 15:10 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 3/6/10 1:13 22-293

Alkalinity, 

Carbonate

ND 5 mg/L SM20-2322 2/27/10 7:14 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/27/10 7:14 22-293

Alkalinity, 

Phenolphthalein

ND 5 mg/L SM20-2320 B 2/27/10 7:14 22-293

Total Kjeldahl 

Nitrogen

47.0 mg/L 4.0 mg/L SM20-4500-N C 3/8/10 11:20 22-293

Formaldehyde ND 1.0 mg/L SW846 8015D 3/4/10 18:25 22-293

Acetone 661 ug/L 10.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Silica, Dissolved 14 mg/L 1 mg/L SM20-4500SiD 3/2/10 0:15 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

2-Hexanone ND 5.0 ug/L SW846 8260B 3/1/10 23:39 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 3/1/10 23:39 22-293

2-Butanone 46.6 ug/L 10.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Ethene ND 3.0 ug/L RSK 175 3/2/10 15:10 22-293

Methanol ND 1.0 mg/L SW846 8015D 9/8/10 22:22 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

mp-Xylene 3.5 ug/L 2.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Ethane ND 3.0 ug/L RSK 175 3/2/10 15:10 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Chloroform ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Carbon Disulfide ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Bromide 825 mg/L 150 mg/L EPA 300 2/27/10 9:17 22-293

Bromochlorometha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,1,2,2-Tetrachloro

ethane

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,2-Dichloropropan

e

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Tetrachloroethene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

trans-1,2-Dichloroe

thene

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

trans-1,3-Dichlorop

ropene

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Benzene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Styrene ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Toluene 1.3 ug/L 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100864

Altela

NETL Flowback Water

Resultant CW

N/A

02/23/10 17:55

02/25/10 11:10

N/A

Grab

Vinyl Chloride ND 1.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Total Xylenes 4.3 ug/L 3.0 ug/L SW846 8260B 3/1/10 23:39 22-293

Vanadium, Total ND 0.25 mg/L EPA 200.7 3/4/10 10:25 22-293

Sample Comments:

None

Printed: 3/25/2010 3:54:21PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
WATER QUALITY REPORT

#02100865

FRAC FLOW-BACK WATER

TEST-BENCH

DISTILLED WATER
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Thorium 228 0.143 pCi/L pCi/L HSL-300M 3/18/10 13:35 6502103

Thorium 230 0.126 pCi/L pCi/L HSL-300m 3/18/10 13:36 6502103

Thorium 232 0.000 pCi/L pCi/L HSL-300m 3/18/10 13:37 6502103

Copper <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:16 AML

Bromoform ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

pH 9.94 SU SU SM4500 H+B 2/25/10 15:10 AML

Total Dissolved 

Solids

76 mg/l 5 mg/l SM 2540 C 2/26/10 12:55 RCS

Total Suspended 

Solids

<3 mg/L 3 mg/L SM 2540 D 2/25/10 14:00 RCS

Oil & Grease 1.2 mg/l 5 mg/l EPA 1664 Rev A 2/26/10 12:40 NJD

BOD > 75.3 2 mg/L SM5210B 2/26/10 9:13 TO

COD 410 mg/L 10 mg/L HACH 8000 3/10/10 7:22 NJD

Surfactants 

(MBAS)

ND 0.025 mg/L SM20-5540 C 2/26/10 21:45 22-293

Color < 5 pccu 5 pccu 2/25/10 11:36 WEH

Printed: 3/25/2010 3:54:21PM Confidential Page 1 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Temperature (F), 

Field

NA deg F na 3/5/10 9:02 RCS

Osmotic Pressure ND 10 mOs/kg PA DEP 2/27/10 4:35 22-293

Ammonia 

Distillation

Completed mg/L SM 4500 NH3 B 3/3/10 13:51 WEH

Ammonia 

Nitrogen

9.64 mg/L .10 mg/L SM 4500 NH3 D 3/4/10 14:58 WEH

Nitrate 0.19 mg/l 0.10 mg/l EPA 300.0 2/26/10 10:43 AML

Nitrite <0.10 mg/l 0.10 mg/l EPA 300.0 2/26/10 10:44 AML

Nitrate / Nitrite 0.29 mg/l 0.20 mg/l EPA 300.0 2/26/10 10:43 AML

Acidity - 22.0 mg/L 3 mg/L SM 2310 B 2/25/10 15:09 AML

Alkalinity 48.0 mg/l 5 mg/l SM 2320 B 2/25/10 15:10 AML

Bicarbonate 24.0 mg/L 5 mg/L SM4500 CO2 D 2/25/10 10:46 AML

Sulfate 2.2 mg/l 1 mg/l EPA 300.0 2/26/10 10:45 AML

Chloride 35.4 mg/L 1 mg/L EPA 300.0 2/26/10 10:42 AML

Fluoride 0.15 mg/l 0.20 mg/l EPA 300.0 2/26/10 10:45 AML

Printed: 3/25/2010 3:54:21PM Confidential Page 2 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Calcium 3.81 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Iron <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Iron, Dissolved 0.02 mg/l 0.02 mg/l EPA 200.7 3/12/10 13:47 AML

Magnesium 0.36 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:52 AML

Potassium 0.19 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:53 AML

Sodium 18.6 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:56 AML

Aluminum <0.10 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:25 AML

Arsenic <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Barium <0.10 mg/l 0.10 mg/l EPA 200.7 2/26/10 14:28 AML

Beryllium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Cadmium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:00 AML

Chromium <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Cobalt <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Printed: 3/25/2010 3:54:21PM Confidential Page 3 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Manganese <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:26 AML

Molybdenum <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:59 AML

Nickel <0.05 mg/l 0.05 mg/l EPA 200.7 2/26/10 14:51 AML

Selenium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:58 AML

Silver <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 13:57 AML

Strontium, Total 0.47 mg/L 0.0025 mg/L EPA 200.7 3/4/10 12:30 22-293

Thallium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:59 AML

Tin <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:02 AML

Titanium <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Zinc 0.16 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:49 AML

Gross Alpha DW -0.125 PCi/L 3 PCi/L EPA 900 3/3/10 11:56 6502103

Gross Beta DW -0.088 PCi/L 4 PCi/L EPA 900 3/3/10 11:57 6502103

Radium 226 0.0917 pCi/L .6 pCi/L EPA 903.1 3/17/10 11:58 6502103

Printed: 3/25/2010 3:54:21PM Confidential Page 4 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Radium 228 -0.134 pCi/L .9 pCi/L EPA 904.0 3/11/10 11:59 6502103

Phenolics 0.05 mg/L 0.01 mg/L EPA 420.4 3/1/10 11:49 22-293

Uranium ND 0.0050 mg/L SW846 6020A 3/3/10 21:37 22-293

Mercury, Total ND 0.0010 mg/L EPA 200.8 3/4/10 8:19 22-293

Lead <0.02 mg/L 0.02 mg/L EPA 200.7 2/26/10 14:51 AML

Lithium, Total ND 0.050 mg/L EPA 200.7 3/4/10 12:30 22-293

Boron <0.02 mg/l 0.02 mg/l EPA 200.7 2/26/10 14:48 AML

Antimony <0.5 mg/L 0.001 mg/L EPA 200.7 3/10/10 14:01 AML

Silicon, Total 0.089 mg/L 0.050 mg/L EPA 200.7 3/3/10 12:04 22-293

Bromide 0.40 mg/l 0.10 mg/l EPA 300.1 2/26/10 10:44 AML

Hardness, Total 11 mg/l 10 mg/l EPA 200.7 2/26/10 13:43 AML

Heterotrophic 

Plate Count

55,000 /ml 1 /ml SM 9215B 2/25/10 15:37 WEH

Total Coliform 0 /100 mls 0 /100 mls SM 9223B 2/25/10 15:35 WEH

Printed: 3/25/2010 3:54:21PM Confidential Page 5 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

E Coli NA +/- SM 9223B 2/25/10 15:35 WEH

Specific 

Conductance

184 umhos/cm 2 umhos/cm EPA 120.1 2/26/10 0:00 TO

Gasoline Range 

Organics

154 ug/L 100 ug/L SW846 8015D 3/2/10 5:19 22-293

Diesel Range 

Organics C10-C28

1.7 mg/L 0.15 mg/L SW846 8015D 3/2/10 22:31 22-293

Methane ND 1.0 ug/L RSK 175 2/26/10 21:26 22-293

Ethylene Glycol ND 10.0 mg/L SW846 8015D 3/6/10 1:34 22-293

Alkalinity, 

Carbonate

20 mg/L 5 mg/L SM20-2322 2/27/10 7:22 22-293

Alkalinity, 

Hydroxide

ND 5 mg/L SM20-2320 B 2/27/10 7:22 22-293

Alkalinity, 

Phenolphthalein

10 mg/L 5 mg/L SM20-2320 B 2/27/10 7:22 22-293

Total Kjeldahl 

Nitrogen

9.8 mg/L 1.0 mg/L SM20-4500-N C 3/3/10 14:00 22-293

Formaldehyde 41.4 mg/L 1.0 mg/L SW846 8015D 3/4/10 18:37 22-293

Acetone 5230 ug/L 200 ug/L SW846 8260B 3/2/10 0:40 22-293

Silica, Dissolved ND 1 mg/L SM20-4500SiD 3/2/10 0:15 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 6 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

2-Hexanone ND 5.0 ug/L SW846 8260B 3/1/10 12:09 22-293

4-Methyl-2-Pentan

one(MIBK)

ND 5.0 ug/L SW846 8260B 3/1/10 12:09 22-293

2-Butanone ND 10.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Ethene ND 3.0 ug/L RSK 175 2/26/10 21:26 22-293

Methanol 27.4 mg/L 1.0 mg/L SW846 8015D 9/8/10 22:37 22-293

o-Xylene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

mp-Xylene ND 2.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Chloromethane ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Ethane ND 3.0 ug/L RSK 175 2/26/10 21:26 22-293

Chlorodibromomet

hane

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Chloroethane ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Chloroform ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Bromomethane ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 7 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Carbon Disulfide ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Bromide 0.38 mg/L 0.30 mg/L EPA 300 2/27/10 9:32 22-293

Bromochlorometha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Bromodichloromet

hane

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,2-Dibromo-3-chl

oropropane

ND 7.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,2-Dibromoethan

e

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,1,2,2-Tetrachloro

ethane

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,1-Dichloroethane ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,1-Dichloroethene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

cis-1,2-Dichloroeth

ene

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Methylene 

Chloride

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,2-Dichloropropan

e

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Chlorobenzene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 8 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Tetrachloroethene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Trichloroethene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

trans-1,2-Dichloroe

thene

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

trans-1,3-Dichlorop

ropene

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

cis-1,3-Dichloropro

pene

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Benzene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Carbon 

Tetrachloride

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,2-Dichloroethane ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Ethylbenzene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Styrene ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Toluene 2.2 ug/L 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,1,1-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

1,1,2-Trichloroetha

ne

ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Printed: 3/25/2010 3:54:21PM Confidential Page 9 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
11931 State Route 85

Kittanning, Pennsylvania 16201

724-543-3011

CWM Environmental

Lab Analysis Report 

Lab # 03-457

Method Analysis Date Analyst 

Customer:

Site:

Collection Date:

Received Date:

Result Reporting Limit

Monitoring Pt:

Source Type:

Matrix:

Collection Method:

02100865

Altela

NETL Flowback Water

Resultant DW

N/A

02/23/10 17:55

02/25/10 11:11

N/A

Grab

Vinyl Chloride ND 1.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Total Xylenes ND 3.0 ug/L SW846 8260B 3/1/10 12:09 22-293

Vanadium, Total ND 0.0025 mg/L EPA 200.7 3/4/10 12:30 22-293

Sample Comments:

None

Printed: 3/25/2010 3:54:21PM Confidential Page 10 of 10

Ryan C Shafer, Technical Director

Analyte names in bold are listed under the laboratory's current NELAP scope of accreditation.
APPENDIX E

MASS BALANCE ANALYSIS
MASS BALANCE ANALYSIS

OF

FRAC WATER
194.00

54.00

140.00

Delta % Delta

GENERAL PARAMETERS

Distilled Water (DW); Lab #02100810 >Acidity mg/L -136.000 14.000 -18.000Hardness, Total mg/L 2621.000 7331.000 15.000 1927.12 1500.36 7.96 1508.32 418.80 21.73Calcium mg/L 915.000 2540.000 5.120 672.76 519.84 2.72 522.55 150.21 22.33Magnesium mg/L 81.600 240.000 0.470 60.00 49.12 0.25 49.37 10.63 17.72Alkalinity mg/L 230.000 160.000 30.000Bicarbonate mg/L 229.000 159.000 29.000 168.37 32.54 15.39 47.93 120.45 71.53Total Dissolved Solids mg/L 19630.000 52504.000 88.000 14433.15 10745.47 46.69 10792.16 3640.99 25.23Specific Conductance uS/CM 29400.000 76600.000 211.000Chloride mg/L 9500.000 32400.000 45.100 6984.97 6630.98 23.93 6654.91 330.06 4.73

Altela Mass Balance of Frac Water

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

CW + DW 

Mass (g)

Parameter

gals

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

RW Mass 

(g) CW Mass (g) DW Mass (g)

galsgals

Raw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >

Fluoride mg/L 27.000 15.500 0.160 19.85 3.17 0.08 3.26 16.59 83.59Sodium mg/L 5250.000 15840.000 24.800 3860.12 3241.81 13.16 3254.97 605.14 15.68Total Suspended Solids mg/L 15.000 338.000 0.000 11.03 69.18 0.00 69.18 -58.15 -527.22Total Residual Chlorine mg/L < 0.100 0.000 0.000Ammonia Distillation mg/L 0.000 Completed CompletedAmmonia Nitrogen mg/L 0.000 9.040 6.990Total Kjeldahl Nitrogen 29.600 5.400 6.000 21.76 1.11 3.18 4.29 17.47 80.29BOD mg/L > 76.000 373.000 373.000COD mg/L 1253.000 2275.000 185.000E Coli NA NA NATotal Coliform /100 mls 0.000 0.000 0.000Heterotrophic Plate Count /ml 24600.000 58000.000 5400.000Color pccu 100.000 150.000 0.000MBAS mg/L 0.328 0.395 0.000pH SU 7.530 7.580 8.580Oil & Grease mg/L 3.200 6.400 2.900 2.35 1.31 1.54 2.85 -0.50 -21.07Osmotic Pressure mOs/KG 533.000 1620.000 27.000Temperature (F), Field deg F 71.000Gross Alpha DW pCi/L 27.000 0.000 0.685 19.85 0.00 0.36 0.36 19.49 98.17Gross Beta DW pCi/L 36.000 2.460 0.429 26.47 0.50 0.23 0.73 25.74 97.24
194.00

54.00

140.00

Delta % Delta

Distilled Water (DW); Lab #02100810 >

Altela Mass Balance of Frac Water

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

CW + DW 

Mass (g)

Parameter

gals

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

RW Mass 

(g) CW Mass (g) DW Mass (g)

galsgals

Raw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >

SPECIFIC IONS

Barium mg/L 17.100 25.400 0.000 12.57 5.20 0.00 5.20 7.37 58.65Boron mg/L 4.400 10.000 0.000 3.24 2.05 0.00 2.05 1.19 36.74Bromide mg/L 141.000 467.500 0.430 103.67 95.68 0.23 95.91 7.76 7.49Bromide mg/L 150.000 467.500 0.430 110.29 95.68 0.23 95.91 14.38 13.04Cobalt mg/L 0.031 < 0.500 0.000 0.02 < 0.10 # 0.00 # 0.10 -0.08 -348.95Copper mg/L 0.460 0.800 0.000 0.34 0.16 0.00 0.16 0.17 51.59Iron mg/L 5.600 10.800 0.000 4.12 2.21 0.00 2.21 1.91 46.32Iron, Dissolved mg/L 4.200 11.100 0.000 3.09 2.27 0.00 2.27 0.82 26.44Lithium, Total mg/L 10.700 32.000 0.000 7.87 6.55 0.00 6.55 1.32 16.75Manganese mg/L 0.800 < 0.400 0.000 0.59 < 0.08 # 0.00 # 0.08 0.51 86.08

M l bd /L 0 018 0 500 0 000 0 01 0 10 # 0 00 # 0 10 0 09 673 20 Molybdenum mg/L 0.018 < 0.500 0.000 0.01 < 0.10 # 0.00 # 0.10 -0.09 -673.20Phenolics mg/L 0.050 0.060 0.060 0.04 0.01 0.03 0.04 -0.01 -20.00Potassium mg/L 55.300 180.000 0.350 40.66 36.84 0.19 37.02 3.64 8.94Radium 226 pCi/L 46.000 0.000 0.231 33.82 0.00 0.12 0.12 33.70 99.64Radium 228 pCi/L 17.000 0.000 0.434 12.50 0.00 0.23 0.23 12.27 98.16Silica, Dissolved mg/L 54.000 142.000 0.000 39.70 29.06 0.00 29.06 10.64 26.80Silicon, Total mg/L 6.700 22.100 0.200 4.93 4.52 0.11 4.63 0.30 6.03Strontium mg/L 97.500 305.000 0.700 71.69 62.42 0.37 62.79 8.90 12.41Sulfate mg/L 155.000 240.000 3.100 113.97 49.12 1.64 50.76 63.20 55.46

ORGANICS

Acetone mg/L 0.304 1.850 0.195 0.22 0.38 0.10 0.48 -0.26 -115.68Gasoline Range Organics mg/L 2.100 2.560 0.000 1.54 0.52 0.00 0.52 1.02 66.07Benzene mg/L 0.218 0.000 0.000 0.16 # 0.00 # 0.00 # 0.00 0.16 100.00mp-Xylene mg/L 0.048 0.034 0.000 0.03 0.01 0.00 0.01 0.03 79.96o-Xylene mg/L 0.019 0.006 0.000 0.01 0.00 0.00 0.00 0.01 90.52Total Xylenes mg/L 0.066 0.041 0.000 0.05 0.01 0.00 0.01 0.04 82.93Toluene mg/L 0.228 0.012 0.000 0.17 0.00 0.00 0.00 0.17 98.56Diesel Range Organic C10-C28 mg/L 28.400 3.500 0.530 20.88 0.72 0.28 1.00 19.88 95.22Ethane mg/L 0.140 0.004 0.000 0.10 0.00 0.00 0.00 0.10 99.30Formaldehyde mg/L 110.000 1.000 1.870 80.88 # 0.20 # 0.99 # 1.20 79.68 98.52Methane mg/L 0.848 0.006 0.000 0.62 0.00 0.00 0.00 0.62 99.82Methanol mg/L 50.100 0.000 1.030 36.84 # 0.00 # 0.55 # 0.55 36.29 98.52
194.00

54.00

140.00

Delta % Delta

Distilled Water (DW); Lab #02100810 >

Altela Mass Balance of Frac Water

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

CW + DW 

Mass (g)

Parameter

gals

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

RW Mass 

(g) CW Mass (g) DW Mass (g)

galsgals

Raw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >

CONSTITUENTS TESTED BELOW DETECTABLE LIMITS IN THE PRIMARY SOLUTION - NO MASS BALANCE CALCULATIONS PROVIDED

SPECIFIC IONS

Alkalinity, Carbonate mg/L < 5.000 < 5.000 9.000Alkalinity, Hydroxide mg/L < 5.000 < 5.000 < 0.000Alkalinity, Phenolphthalein mg/L < 5.000 < 5.000 < 0.000Aluminum mg/L < 2.000 < 2.000 < 0.100Antimony mg/L < 0.500 < 0.500 < 0.500Arsenic mg/L < 0.500 < 0.500 < 0.500Beryllium mg/L < 0.500 < 0.500 < 0.100Cadmium mg/L < 0.500 < 0.500 < 0.500Chromium mg/L < 0.400 < 0.400 < 0.020

Lead mg/L < 0.400 < 0.400 < 0.020Mercury mg/L < 0.002 < 0.002 < 0.002Nickel mg/L < 0.050 < 0.050 < 0.050Nitrate mg/L < 0.100 < 5.000 < 0.100Nitrate / Nitrite mg/L < 0.200 < 10.000 < 0.200Nitrite mg/L < 0.100 < 5.000 < 0.100Selenium mg/L < 0.500 < 0.500 < 0.500Silver mg/L < 0.500 < 0.500 < 0.500Thallium mg/L 0.015 < 0.500 0.000Tin mg/L < 0.500 < 0.500 < 0.500Titanium mg/L < 0.500 < 0.500 < 0.500Uranium mg/L < 0.100 < 0.050 < 0.000Vanadium mg/L < 0.063 < 0.130 < 0.130Vinyl Chloride mg/L < 0.005 < 0.005 < 0.005Zinc mg/L < 0.400 < 0.400 < 0.020

ORGANICS

1,1,1-Trichloroethane mg/L < 0.005 < 0.005 < 0.0051,1,2,2-Tetrachloroethane mg/L < 0.005 < 0.005 < 0.0051,1,2-Trichloroethane mg/L < 0.005 < 0.005 < 0.0051,1-Dichloroethane mg/L < 0.005 < 0.005 < 0.0051,1-Dichloroethene mg/L < 0.005 < 0.005 < 0.0051,2 Dibromoethane mg/L < 0.005 < 0.005 < 0.005
194.00

54.00

140.00

Delta % Delta

Distilled Water (DW); Lab #02100810 >

Altela Mass Balance of Frac Water

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

CW + DW 

Mass (g)

Parameter

gals

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

RW Mass 

(g) CW Mass (g) DW Mass (g)

galsgals

Raw Water (RW); Lab #02100193 >Concentrate Water (CW); Lab #02100809 >

1,2-Dibromo-3-chloropropane mg/L < 0.035 < 0.035 < 0.0351,2-Dichloroethane mg/L < 0.005 < 0.005 < 0.0051,2-Dichloropropane mg/L < 0.005 < 0.005 < 0.0052-Butanone (MEK) mg/L < 0.050 < 0.050 < 0.0502-Hexanone mg/L < 0.025 < 0.025 < 0.0254-Methyl-2-Pentanone(MIBK) mg/L < 0.025 < 0.025 < 0.025Bromochloromethane mg/L < 0.005 < 0.005 < 0.005Bromodichloromethane mg/L < 0.005 < 0.005 < 0.005Bromoform mg/L < 0.005 < 0.005 < 0.005Bromomethane mg/L < 0.005 < 0.005 < 0.005Carbon Disulfide mg/L < 0.005 < 0.005 < 0.005C b T t hl id /L 0 005 0 005 0 005 Carbon Tetrachloride mg/L < 0.005 < 0.005 < 0.005Chlorobenzene mg/L < 0.005 < 0.005 < 0.005Chlorodibromomethane mg/L < 0.005 < 0.005 < 0.005Chloroethane mg/L < 0.005 < 0.005 < 0.005Chloroform mg/L < 0.005 < 0.005 < 0.005Chloromethane mg/L < 0.005 < 0.005 < 0.005cis-1,2-Dichloroethene mg/L < 0.005 < 0.005 < 0.005cis-1,3-Dichloropropene mg/L < 0.005 < 0.005 < 0.005Ethene mg/L < 0.030 < 0.030 < 0.030Ethylbenzene mg/L < 0.005 < 0.005 < 0.005Ethylene Glycol mg/L < 10.000 < 10.000 < 10.000Methylene Chloride mg/L < 0.005 < 0.005 < 0.005Styrene mg/L < 0.005 < 0.005 < 0.005Tetrachloroethene mg/L < 0.005 < 0.005 < 0.005trans-1,2-Dichloroethene mg/L < 0.005 < 0.005 < 0.005trans-1,3-Dichloropropene mg/L < 0.005 < 0.005 < 0.005Trichloroethene mg/L < 0.005 < 0.005 < 0.005
MASS BALANCE ANALYSIS

OF

PRODUCED WATER
211.00

96.00

115.00

Delta % Delta

GENERAL PARAMETERS

Acidity mg/L 404.000 236.000Hardness, Total mg/L 44431.000 87259.000 15.000 35531.03 31748.31 6.54 31754.85 3776.17 10.63Calcium mg/L 15460.000 29800.000 5.120 12363.21 10842.43 2.23 10844.66 1518.54 12.28Magnesium mg/L 1415.000 3120.000 0.470 1131.56 1135.18 0.20 1135.39 -3.82 -0.34Alkalinity mg/L 94.000 32.000Bicarbonate mg/L 94.000 32.000 29.000 75.17 11.64 12.64 24.28 50.89 67.70Total Dissolved Solids mg/L 195130.000 345680.000 88.000 156043.51 125772.21 38.35 125810.57 30232.94 19.37Specific Conductance uS/CM 194800.000 234000.000Chloride mg/L 108600.000 205200.000 45.100 86846.33 74659.97 19.66 74679.62 12166.71 14.01

Fl id /L 8 500 10 500 0 160 6 80 3 82 0 07 3 89 2 91 42 77

DW Mass 

(g) CW + DW Mass (g)

Altela Mass Balance of Produced Water

RW Mass (g) DW Conc (mg/L) CW Conc (mg/L) RW Conc (mg/L) Parameter

Raw Water (RW); Lab #02100194 > galsConcentrate Water (CW); Lab #02100762 >Distilled Water (DW); Lab #02100763 >

galsgals

CW Mass (g)

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

Fluoride mg/L 8.500 10.500 0.160 6.80 3.82 0.07 3.89 2.91 42.77Sodium mg/L 21200.000 85600.000 24.800 16953.43 31144.70 10.81 31155.51 -14202.09 -83.77Total Suspended Solids mg/L 403.000 176.000 < 0.000 322.28 64.04 0.00 64.04 258.24 80.13Total Residual Chlorine mg/L < 0.100 < 0.100Ammonia Distillation mg/L 0.000 Completed CompletedAmmonia Nitrogen mg/L 0.000 267.000 6.990Total Kjeldahl Nitrogen 17.000 42.300 6.000 13.59 15.39 2.62 18.01 -4.41 -32.44BOD mg/L > 77.900 62.700 > 75.300COD mg/L 6270.000 3800.000 185.000E Coli NA NA NATotal Coliform /100 mls 0.000 0.000 0.000Heterotrophic Plate Count /ml 21.000 32.000 5400.000Color pccu 150.000 20.000 0.000MBAS mg/L 0.344 0.184 < 0.000pH SU 6.170 5.960 8.580Oil & Grease mg/L 0.900 2.200 2.900 0.72 0.80 1.26 2.06 -1.34 -186.84Osmotic Pressure mOs/KG 2990.000 2970.000 27.000Temperature (F), Field deg F 40.000 NA NAGross Alpha DW pCi/L 3009.000 0.000 0.000Gross Beta DW pCi/L 416.000 0.000 0.000
211.00

96.00

115.00

Delta % Delta DW Mass (g) CW + DW Mass (g)

Altela Mass Balance of Produced Water

RW Mass (g) DW Conc (mg/L) CW Conc (mg/L) RW Conc (mg/L) Parameter

Raw Water (RW); Lab #02100194 > galsConcentrate Water (CW); Lab #02100762 >Distilled Water (DW); Lab #02100763 >

galsgals

CW Mass (g)

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

SPECIFIC IONS

Barium mg/L 158.000 148.000 0.000 126.35 53.85 0.00 53.85 72.50 57.38Boron mg/L 11.000 17.400 0.000 8.80 6.33 0.00 6.33 2.47 28.03Bromide mg/L 1060.000 2360.000 0.400 847.67 858.66 0.17 858.84 -11.17 -1.32Bromide mg/L 1060.000 2360.000 0.400 847.67 858.66 0.17 858.84 -11.17 -1.32Cobalt mg/L 0.012 0.012 0.000 0.01 # 0.00 0.00 0.00 0.01 54.50Copper mg/L 0.800 2.000 0.000 0.64 0.73 0.00 0.73 -0.09 -13.74Iron mg/L 68.000 2.400 0.000 54.38 0.87 0.00 0.87 53.51 98.39Iron, Dissolved mg/L 16.000 0.400 0.000 12.80 # 0.15 0.00 0.15 12.65 98.86Lithium, Total mg/L 152.000 319.000 0.000 121.55 116.06 0.00 116.06 5.49 4.51Manganese mg/L 5.200 8.200 0.000 4.16 2.98 0.00 2.98 1.17 28.25

Molybdenum mg/L 0 003 0 000 0 000 0 00 # 0 00 0 00 0 00 0 00 100 00 Molybdenum mg/L 0.003 0.000 0.000 0.00 # 0.00 0.00 0.00 0.00 100.00Phenolics mg/L 0.070 0.010 0.060 0.06 # 0.00 0.03 0.03 0.03 46.78Potassium mg/L 465.000 1320.000 0.350 371.86 480.27 0.15 480.42 -108.57 -29.20Radium 226 pCi/L 1448.000 0.000 0.000 1157.95 0.00 0.00 0.00 1157.95 100.00Radium 228 pCi/L 715.000 0.000 0.000 571.78 0.00 0.00 0.00 571.78 100.00Silica, Dissolved mg/L 52.000 15.000 0.000 41.58 5.46 0.00 5.46 36.13 86.88Silicon, Total mg/L 7.000 10.000 0.200 5.60 3.64 0.09 3.73 1.87 33.45Strontium mg/L 2190.000 4970.000 0.700 1751.32 1808.28 0.31 1808.59 -57.27 -3.27Sulfate mg/L 130.000 550.000 3.100 103.96 200.11 1.35 201.46 -97.50 -93.79

ORGANICS

Acetone mg/L < 0.050 0.978 0.195 < 0.04 0.36 < 0.08 0.44 -0.40 -1002.49Gasoline Range Organics mg/L 6.690 < 0.500 < 0.100 5.35 < 0.18 0.04 0.23 5.12 95.78Benzene mg/L 756.000 1.200 0.000 604.57 0.44 0.00 0.44 604.13 99.93mp-Xylene mg/L 0.294 0.003 < 0.002 0.24 0.00 0.00 0.00 0.23 99.12o-Xylene mg/L 0.060 < 0.001 < 0.001 0.05 < 0.00 0.00 0.00 0.05 98.33Total Xylenes mg/L 0.354 0.004 < 0.003 0.28 0.00 0.00 0.00 0.28 99.01Toluene mg/L 0.984 0.003 < 0.001 0.79 0.00 0.00 0.00 0.79 99.81Diesel Range Organic C10-C28 mg/L 5.900 1.000 0.530 4.72 0.36 0.23 0.59 4.12 87.39Ethane mg/L 0.120 < 0.003 < 0.003 0.10 < 0.00 0.00 0.00 0.09 97.50Formaldehyde mg/L 9.890 0.035 1.870 7.91 0.01 0.82 0.83 7.08 89.54Methane mg/L 0.053 < 0.001 < 0.001 0.04 < 0.00 0.00 0.00 0.04 98.10Methanol mg/L 4330.000 11.300 1030.000 3462.66 4.11 448.93 453.04 3009.62 86.92
211.00

96.00

115.00

Delta % Delta DW Mass (g) CW + DW Mass (g)

Altela Mass Balance of Produced Water

RW Mass (g) DW Conc (mg/L) CW Conc (mg/L) RW Conc (mg/L) Parameter

Raw Water (RW); Lab #02100194 > galsConcentrate Water (CW); Lab #02100762 >Distilled Water (DW); Lab #02100763 >

galsgals

CW Mass (g)

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

CONSTITUENTS TESTED BELOW DETECTABLE LIMITS IN THE PRIMARY SOLUTION - NO MASS BALANCE CALCULATIONS PROVIDED

SPECIFIC IONS

Alkalinity, Carbonate mg/L < 5.000 < 5.000 9.000Alkalinity, Hydroxide mg/L < 5.000 < 5.000 < 5.000Alkalinity, Phenolphthalein mg/L < 5.000 < 5.000 < 5.000Aluminum mg/L < 2.000 < 2.000 < 0.100Antimony mg/L < 0.500 < 1.000 < 0.500Arsenic mg/L < 0.500 < 1.000 < 0.500Beryllium mg/L < 0.500 < 1.000 < 0.500Cadmium mg/L 0.012 0.012 0.000Chromium mg/L < 0.400 < 0.400 < 0.020

Lead mg/L < 0 400 0 000 0 000 Lead mg/L < 0.400 0.000 0.000Mercury mg/L < 0.020 < 0.013 < 0.001Nickel mg/L < 1.000 < 1.000 < 0.050Nitrate mg/L < 5.000 < 5.000 < 0.100Nitrate / Nitrite mg/L < 10.000 < 10.000 < 0.200Nitrite mg/L < 5.000 < 5.000 < 0.100Selenium mg/L < 0.500 < 1.000 < 0.500Silver mg/L < 0.500 < 1.000 < 0.500Thallium mg/L 0.006 < 1.000 < 0.500Tin mg/L < 0.500 < 1.000 < 0.500Titanium mg/L 0.006 < 1.000 < 0.500Uranium mg/L < 1.000 < 1.100 < 1.100Vanadium mg/L < 0.250 < 1.500 < 0.003Vinyl Chloride mg/L < 0.005 < 0.001 < 0.001Zinc mg/L < 0.400 < 0.400 < 0.020

ORGANICS

1,1,1-Trichloroethane mg/L < 0.005 < 0.005 < 0.0011,1,2,2-Tetrachloroethane mg/L < 0.005 < 0.005 < 0.0011,1,2-Trichloroethane mg/L < 0.005 < 0.005 < 0.0011,1-Dichloroethane mg/L < 0.005 < 0.005 < 0.0011,1-Dichloroethene mg/L < 0.005 < 0.005 < 0.0011,2 Dibromoethane mg/L < 0.005 < 0.005 < 0.001
211.00

96.00

115.00

Delta % Delta DW Mass (g) CW + DW Mass (g)

Altela Mass Balance of Produced Water

RW Mass (g) DW Conc (mg/L) CW Conc (mg/L) RW Conc (mg/L) Parameter

Raw Water (RW); Lab #02100194 > galsConcentrate Water (CW); Lab #02100762 >Distilled Water (DW); Lab #02100763 >

galsgals

CW Mass (g)

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

1,2-Dibromo-3-chloropropane mg/L < 0.035 < 0.035 < 0.0071,2-Dichloroethane mg/L < 0.005 < 0.005 < 0.0011,2-Dichloropropane mg/L < 0.005 < 0.005 < 0.0012-Butanone (MEK) mg/L < 0.050 < 0.050 < 0.0102-Hexanone mg/L < 0.025 < 0.025 < 0.0054-Methyl-2-Pentanone(MIBK) mg/L < 0.025 < 0.025 < 0.005Bromochloromethane mg/L < 0.005 < 0.001 < 0.001Bromodichloromethane mg/L < 0.005 < 0.001 < 0.001Bromoform mg/L < 0.005 < 0.001 < 0.001Bromomethane mg/L < 0.005 < 0.001 < 0.001Carbon Disulfide mg/L < 0.005 < 0.001 < 0.001Carbon Tetrachloride mg/L < 0 005 < 0 001 < 0 001 Carbon Tetrachloride mg/L < 0.005 < 0.001 < 0.001Chlorobenzene mg/L < 0.005 < 0.001 < 0.001Chlorodibromomethane mg/L < 0.005 < 0.001 < 0.001Chloroethane mg/L < 0.005 < 0.001 < 0.001Chloroform mg/L < 0.005 < 0.001 < 0.001Chloromethane mg/L 0.011 < 0.001 < 0.001cis-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001cis-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Ethene mg/L < 0.030 < 0.003 < 0.003Ethylbenzene mg/L 0.027 < 0.001 < 0.001Ethylene Glycol mg/L < 10.000 < 10.000 < 10.000Methylene Chloride mg/L < 0.005 < 0.001 < 0.001Styrene mg/L < 0.005 < 0.001 < 0.001Tetrachloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Trichloroethene mg/L < 0.005 < 0.001 < 0.001
MASS BALANCE ANALYSIS

OF

FRAC FLOW-BACK WATER
Raw Water (RW); Lab #02100197; 194 gals

Concentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 gals

RW Mass 

(g) Delta % Delta

GENERAL PARAMETERS

Acidity mg/L -114.000 50.000 -22.000 -83.82 10.23 -11.67 -1.44 -82.38 98.28Hardness, Total mg/L 7040.000 19648.000 11.000 5176.23 4021.16 5.84 4027.00 1149.23 22.20Calcium mg/L 2465.000 6780.000 3.810 1812.42 1387.59 2.02 1389.62 422.80 23.33Magnesium mg/L 215.000 660.000 0.360 158.08 135.08 0.19 135.27 22.81 14.43Alkalinity mg/L 196.000 148.000 48.000 144.11 30.29 25.47 55.76 88.35 61.31Bicarbonate mg/L 196.000 148.000 24.000 144.11 30.29 12.73 43.02 101.09 70.15Total Dissolved Solids mg/L 40530.000 113460.000 76.000 29800.09 23220.72 40.33 23261.05 6539.04 21.94Specific Conductance uS/CM 56700.000 143500.000 184.000 41689.24 29368.71 97.63 29466.34 12222.90 29.32

Chloride mg/L 20100.000 64800.000 35.400 14778.73 13261.97 18.78 13280.75 1497.97 10.14

/

DW Mass 

(g)

CW + DW 

Mass (g)

Altela Mass Balance of Frac Flow Back Water

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

CW Mass 

(g) Parameter

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

Fluoride mg/L 9.500 12.000 0.150 6.98 2.46 0.08 2.54 4.45 63.70Sodium mg/L 10380.000 32200.000 18.600 7632.00 6590.05 9.87 6599.92 1032.08 13.52Total Suspended Solids mg/L 22.000 32.000 < 3.000 16.18 6.55 < 1.59 8.14 8.03 49.67Total Residual Chlorine mg/L < 0.100 0.000 0.000Ammonia Distillation mg/L 0.000 Completed CompletedAmmonia Nitrogen mg/L 0.000 28.200 9.640Total Kjeldahl Nitrogen 9.200 47.000 9.800 6.76 9.62 5.20 14.82 -8.05 -119.07BOD mg/L > 74.200 > 379.000 > 75.300COD mg/L 1042.000 1040.000 410.000E Coli NA NA NATotal Coliform /100 mls 0.000 0.000 0.000Heterotrophic Plate Count /ml 4,810,000 8200.000 55000.000Color pccu 125.000 250.000 < 5.000MBAS mg/L 0.239 0.184 < 0.025pH SU 7.390 6.900 9.940Oil & Grease mg/L 1.100 1.400 1.200 0.81 0.29 0.64 0.92 -0.11 -14.15Osmotic Pressure mOs/KG 1110.000 3440.000 < 10.000Temperature (F), Field deg F 74.000 NA NAGross Alpha DW pCi/L 76.400 0.000 0.000 56.17 0.00 0.00 0.00 56.17 100.00Gross Beta DW pCi/L 240.000 0.000 0.000 176.46 0.00 0.00 0.00 176.46 100.00
Raw Water (RW); Lab #02100197; 194 gals

Concentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 gals

RW Mass 

(g) Delta % Delta DW Mass (g) CW + DW Mass (g)

Altela Mass Balance of Frac Flow Back Water

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

CW Mass 

(g) Parameter

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

SPECIFIC IONS

Barium mg/L 52.900 45.400 < 0.100 38.90 9.29 < 0.05 9.34 29.55 75.97Boron mg/L 6.400 17.000 < 0.020 4.71 3.48 < 0.01 3.49 1.22 25.84Bromide mg/L 270.000 995.000 0.400 198.52 203.64 0.21 203.85 -5.33 -2.68Bromide mg/L 291.000 995.000 0.400 213.96 203.64 0.21 203.85 10.11 4.73Cobalt mg/L 0.033 < 0.500 < 0.500 0.02 < 0.10 < 0.27 < 0.37 -0.34 -1415.15Copper mg/L 0.520 0.800 < 0.020 0.38 0.16 < 0.01 0.17 0.21 54.40Iron mg/L 8.400 16.600 < 0.020 6.18 3.40 < 0.01 3.41 2.77 44.82Iron, Dissolved mg/L 8.300 16.700 0.020 6.10 3.42 0.01 3.43 2.67 43.82Lithium, Total mg/L 21.500 66.100 < 0.050 15.81 13.53 < 0.03 13.55 2.25 14.26Manganese mg/L 2.000 2.600 < 0.020 1.47 0.53 < 0.01 0.54 0.93 63.09

Molybdenum mg/L 0 016 < 0 500 < 0 500 0 01 < 0 10 < 0 27 < 0 37 0 36 3025 00 Molybdenum mg/L 0.016 < 0.500 < 0.500 0.01 < 0.10 < 0.27 < 0.37 -0.36 -3025.00Phenolics mg/L 0.040 0.020 0.050 0.03 0.00 0.03 0.03 0.00 -4.12Potassium mg/L 94.800 360.000 0.190 69.70 73.68 0.10 73.78 -4.08 -5.85Radium 226 pCi/L 33.100 0.000 0.000 24.34 0.00 0.00 0.00 24.34 100.00Radium 228 pCi/L 27.300 0.000 0.000 20.07 0.00 0.00 0.00 20.07 100.00Silica, Dissolved mg/L 49.000 14.000 < 1.000 36.03 2.87 < 0.53 3.40 32.63 90.57Silicon, Total mg/L 9.200 26.600 0.089 6.76 5.44 0.05 5.49 1.27 18.82Strontium mg/L 265.000 788.000 0.470 194.84 161.27 0.25 161.52 33.32 17.10Sulfate mg/L 155.000 275.000 2.200 113.97 56.28 1.17 57.45 56.52 49.59

ORGANICS

Acetone mg/L 2.090 0.661 5.230 1.54 0.14 2.78 2.91 -1.37 -89.39Gasoline Range Organics mg/L 0.928 2.850 0.154 0.68 0.58 0.08 0.66 0.02 2.54Benzene mg/L 0.055 < 0.001 < 0.001 0.04 < 0.00 < 0.00 < 0.00 0.04 98.19mp-Xylene mg/L 0.027 0.004 < 0.002 0.02 0.00 < 0.00 0.00 0.02 91.05o-Xylene mg/L 0.009 < 0.001 < 0.001 0.01 < 0.00 < 0.00 < 0.00 0.01 88.76Total Xylenes mg/L 0.036 0.004 < 0.003 0.03 0.00 < 0.00 0.00 0.02 90.71Toluene mg/L 0.085 0.001 0.002 0.06 0.00 0.00 0.00 0.06 97.71Diesel Range Organic C10-C28 mg/L 17.400 5.100 1.700 12.79 1.04 0.90 1.95 10.85 84.79Ethane mg/L 0.133 < 0.003 < 0.003 0.10 < 0.00 < 0.00 < 0.00 0.10 97.74Formaldehyde mg/L 75.400 < 1.000 41.400 55.44 < 0.20 21.97 22.17 33.27 60.01Methane mg/L 0.390 < 0.001 < 0.001 0.29 < 0.00 < 0.00 < 0.00 0.29 99.74Methanol mg/L 35.200 < 0.001 0.027 25.88 < 0.00 0.01 0.01 25.87 99.94
Raw Water (RW); Lab #02100197; 194 gals

Concentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 gals

RW Mass 

(g) Delta % Delta DW Mass (g) CW + DW Mass (g)

Altela Mass Balance of Frac Flow Back Water

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

CW Mass 

(g) Parameter

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

CONSTITUENTS TESTED BELOW DETECTABLE LIMITS IN THE PRIMARY SOLUTION - NO MASS BALANCE CALCULATIONS PROVIDED

SPECIFIC IONS

Alkalinity, Carbonate mg/L < 5.000 < 5.000 20.000Alkalinity, Hydroxide mg/L < 5.000 < 5.000 < 5.000Alkalinity, Phenolphthalein mg/L < 5.000 < 5.000 10.000Aluminum mg/L < 2.000 < 2.000 < 0.100Antimony mg/L < 0.500 < 0.500 < 0.500Arsenic mg/L < 0.500 < 0.500 < 0.500Beryllium mg/L < 0.500 < 0.500 < 0.500Cadmium mg/L < 0.500 < 0.500 < 0.500Chromium mg/L < 0.400 < 0.400 < 0.020

L d /L < 0 400 0 000 0 000 Lead mg/L < 0.400 0.000 0.000Mercury mg/L < 0.005 < 0.010 < 0.001Nickel mg/L < 1.000 < 1.000 < 0.050Nitrate mg/L < 5.000 < 5.000 0.190Nitrate / Nitrite mg/L < 10.000 < 10.000 0.290Nitrite mg/L < 5.000 < 5.000 < 0.100Selenium mg/L < 0.500 < 0.500 < 0.500Silver mg/L < 0.500 < 0.500 < 0.500Thallium mg/L 0.009 < 0.500 < 0.500Tin mg/L < 0.500 < 0.500 < 0.500Titanium mg/L 0.009 < 0.500 < 0.500Uranium mg/L < 0.250 < 0.050 < 0.005Vanadium mg/L < 0.063 < 0.250 < 0.003Vinyl Chloride mg/L < 0.005 < 0.001 < 0.001Zinc mg/L < 0.400 < 0.400 0.160

ORGANICS

1,1,1-Trichloroethane mg/L < 0.005 < 0.001 < 0.0011,1,2,2-Tetrachloroethane mg/L < 0.005 < 0.001 < 0.0011,1,2-Trichloroethane mg/L < 0.005 < 0.001 < 0.0011,1-Dichloroethane mg/L < 0.005 < 0.001 < 0.0011,1-Dichloroethene mg/L < 0.005 < 0.001 < 0.0011,2 Dibromoethane mg/L < 0.005 < 0.001 < 0.001
Raw Water (RW); Lab #02100197; 194 gals

Concentrate Water (CW); Lab #02100864; 54 galsDistilled Water (DW); Lab #02100865; 140 gals

RW Mass 

(g) Delta % Delta DW Mass (g) CW + DW Mass (g)

Altela Mass Balance of Frac Flow Back Water

RW Conc 

(mg/L)

CW Conc 

(mg/L)

DW Conc 

(mg/L)

CW Mass 

(g) Parameter

CWM WATER QUALITY RESULTS MASS BALANCE CALCULATIONS

1,2-Dibromo-3-chloropropane mg/L < 0.035 < 0.007 < 0.0071,2-Dichloroethane mg/L < 0.005 < 0.001 < 0.0011,2-Dichloropropane mg/L < 0.005 < 0.001 < 0.0012-Butanone (MEK) mg/L < 0.005 0.047 < 0.0102-Hexanone mg/L < 0.025 < 0.005 < 0.0054-Methyl-2-Pentanone(MIBK) mg/L < 0.025 < 0.005 < 0.005Bromochloromethane mg/L < 0.005 < 0.001 < 0.001Bromodichloromethane mg/L < 0.005 < 0.001 < 0.001Bromoform mg/L < 0.005 < 0.001 < 0.001Bromomethane mg/L < 0.005 < 0.001 < 0.001Carbon Disulfide mg/L < 0.005 < 0.001 < 0.001Carbon Tetrachloride mg/L < 0 005 < 0 001 < 0 001 Carbon Tetrachloride mg/L < 0.005 < 0.001 < 0.001Chlorobenzene mg/L < 0.005 < 0.001 < 0.001Chlorodibromomethane mg/L < 0.005 < 0.001 < 0.001Chloroethane mg/L < 0.005 < 0.001 < 0.001Chloroform mg/L < 0.005 < 0.001 < 0.001Chloromethane mg/L < 0.005 < 0.001 < 0.001cis-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001cis-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Ethene mg/L < 0.006 < 0.003 < 0.003Ethylbenzene mg/L < 0.005 < 0.001 < 0.001Ethylene Glycol mg/L < 0.010 < 0.010 < 0.010Methylene Chloride mg/L < 0.005 < 0.001 < 0.001Styrene mg/L < 0.005 < 0.001 < 0.001Tetrachloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,2-Dichloroethene mg/L < 0.005 < 0.001 < 0.001trans-1,3-Dichloropropene mg/L < 0.005 < 0.001 < 0.001Trichloroethene mg/L < 0.005 < 0.001 < 0.001
APPENDIX F

NEW MEXICO OIL CONSERVATION 

DIVISION APPROVAL FOR 

MARCELLUS WATER


APPENDIX G

PHOTOS OF SITE
Sleepy Well Site

• Site location – Laurel Run Rd, Penn Run, P

Produc

Well Head

Altela Rain Treatment Trailer 

Treated Water and Brine Holding Tanks

Flowback Hold
The Well

The Wellhead, p

Produced Water Holding Tanks

Vents for NG, unflared 
Pressure Reduction and Water Se

Series of con

reduce press

to the pro

Series of tanks and valves used to reduce pressure 

and remove water 
Frac Flowback Holding Pit

Pit, slightly frozen over and collecting 

rainwater

Submersible pump feed

feeds the treatm
Treatment System

Pipeline from flow

Treatment Trailer Concentrate Holding Tank

Treated Water Holding Tank

Ex

sa
Altela Rain Units

A row 

Pipes carrying saturated air 

from the system and tanks 

collecting treated water at 

the side

Insulated Steam Pipe
Steam Generation

Natural gas bo

generate steam 

drive the sys

-Treated water holding tankTreated water used as water 

source for steam generation 
Heat Exchanger

Blower drives ai

heat exch

Heat exchanger, constructed of same material 

as treatment towers, to pre-heat inlet air and 

cool saturated outlet air (water condensing out 

of outlet air in heat exchanger is collected)
Miscellaneous Equipment

Monitoring and Control system

Pump, pressure gauges, and 

meter in boiler room

Valves controlling brine flow 

to treatment towers

Blower in boiler room

Batc





APPENDIX H

MISCELLANEOUS CHARTS

AND GRAPHS
As of 9/1/2010 10/1/2010 11/1/2010 12/1/2010 1/1/2011 2/1/2011 3/1/2011 3/31

Actual Treatment Rate (avg. BPD) 31.37 34.39 27.09 24.64 16.77 12.20 12.86 

Normalized Treatment Rate (BPD) 44.82 40.19 32.58 29.65 24.01 26.26 23.58 

Total Recovery Rate (%) 76.11 76.76 75.50 72.11 73.12 75.11 73.11 

PW In (bbls) 1,236.31 1,344.05 1,112.26 1,059.29 710.83 503.69 545.36 4

CW Out (bbls) 283.33 312.38 272.50 295.48 191.07 125.36 146.67 

DW Out (bbls) 263.93 253.69 121.31 114.40 48.93 46.19 71.19 

Average PW Cond. 33,835 41,314 41,580 40,815 35,481 36,548 28,201 

Average CW Cond. 60,519 73,804 70,761 72,001 63,251 64,418 49,249 2

Average DW Cond. 35 35 583 44 50 674 38 

NETL DEMONSTRATION SYSTEM TREATMENT SUMMARY 
As of 7/29/2010 8/24/2010 8/25/2010 8/26/2010 8/27/2010 8/30/2010 8/31/2010 9/

Actual Treatment Rate (avg. BPD) 19.55 38.10 46.55 45.00 42.98 41.67 38.93 

Normalized Treatment Rate (BPD) 33.51 38.10 46.74 45.00 42.98 41.67 38.93 

Total Recovery Rate (%) 94.94 75.47 76.37 76.38 76.48 76.42 75.69 

PW In (bbls) 20.59 50.48 60.95 58.57 56.19 54.52 51.43 

CW Out (bbls) 1.04 12.38 14.40 13.57 13.21 12.86 12.50 

DW Out (bbls) 6.95 13.33 13.33 11.31 12.26 11.19 10.00 

Average PW Cond. 31,450 32,390 33,290 35,980 38,130 38,950 39,040 

Average CW Cond. 59,764 61,650 56,560 60,860 65,785 65,290 78,230 

Average DW Cond. 90 32 32 34 36 35 31 
9/3/2010 9/7/2010 9/8/2010 9/9/2010 9/10/2010 9/13/2010 9/14/2010 9/15/2010 9/16/2010 9/17/2010 9/20/201

41.07 0.00 31.19 25.24 44.17 40.71 42.98 39.29 39.17 39.40 39.2

41.24 0.00 43.50 43.58 44.17 40.71 42.98 39.29 39.17 39.90 39.2

76.16 0.00 76.61 76.26 77.29 76.17 78.48 76.74 76.51 76.80 76.9

53.93 0.00 40.71 33.10 57.14 53.45 54.76 51.19 51.19 51.31 51.0

12.86 0.00 9.52 7.86 12.98 12.74 11.79 11.90 12.02 11.90 11.7

10.12 0.00 6.90 8.21 12.98 11.31 11.31 10.00 9.05 10.36 8.8

39,464 40,385 40,502 40,530 40,930 41,325 41,396 41,549 41,806 41,967 41,99

69,975 84,169 72,756 73,168 72,656 73,398 73,215 73,756 74,516 74,570 74,89

30 30 34 38 38 33 33 34 33 34 3
9/22/2010 9/23/2010 9/24/2010 9/25/2010 9/27/2010 9/28/2010 9/29/2010 9/30/2010 10/1/2010 10/4/2010 10/5/

39.05 10.60 29.29 37.98 33.81 25.71 29.64 34.17 30.60 32.38 2

40.75 40.36 40.16 37.98 33.81 37.63 38.46 40.20 39.91 32.38 2

73.10 72.95 76.64 76.13 76.14 76.33 77.81 76.94 76.72 77.94 7

51.31 14.52 38.21 49.88 44.40 33.69 38.10 44.40 39.88 41.55 3

12.26 3.93 8.93 11.90 10.60 7.98 8.45 10.24 9.29 9.17 

8.33 3.21 5.95 8.21 8.21 4.76 5.95 7.26 6.55 2.26 

41,963 42,024 42,006 41,960 42,099 41,953 41,997 41,612 41,430 41,432 41

74,149 64,210 72,150 75,077 75,735 74,583 75,179 74,319 57,360 74,149 74

35 34 37 35 39 38 38 40 38 36 
10/7/2010 10/8/2010 10/11/2010 10/12/2010 10/13/2010 10/14/2010 10/15/2010 10/18/2010 10/19/2010 10/20/20

7.98 29.64 37.38 34.64 37.98 33.93 15.95 0.00 29.40 46

17.56 33.88 37.38 34.79 37.98 35.87 36.46 0.00 40.79 46

70.53 77.09 77.53 75.98 78.00 77.45 68.37 0.00 96.48 94

11.31 38.45 48.21 45.60 48.69 43.81 23.33 0.00 30.48 49

3.33 8.81 10.83 10.95 10.71 9.88 7.38 0.00 1.07 2

1.43 5.36 5.60 5.24 5.36 6.43 2.14 0.00 8.10 7

41,574 41,476 41,544 41,396 41,443 41,536 41,741 42,674 42,250 41,4

73,610 74,044 73,714 73,941 73,881 73,959 38,563 58,592 66,038 73,1

59 55 159 77 78 91 70 5,004 2,419 
10/22/2010 10/25/2010 10/26/2010 10/27/2010 10/28/2010 10/29/2010 11/1/2010 11/2/2010 11/3/2010 11/4/2010 

21.79 30.60 30.12 22.74 31.31 32.02 26.31 21.31 18.69 36.31 

24.09 30.60 30.12 26.75 31.31 32.29 26.31 21.31 37.38 36.31 

52.29 73.01 72.91 70.22 74.08 73.90 74.66 73.06 70.40 72.10 

41.67 41.90 41.31 32.38 42.26 43.33 35.24 29.17 26.55 50.36 

19.88 11.31 11.19 9.64 10.95 11.31 8.93 7.86 7.86 14.05 

4.76 4.52 3.33 2.02 3.33 3.10 0.24 0.00 5.48 10.00 

41,609 41,497 41,324 41,054 41,041 41,216 41,790 41,855 41,743 41,310 

73,779 73,203 73,357 73,792 73,198 73,233 73,230 75,176 78,190 73,113 

211 46 46 169 88 44 34 34 130 47 
11/9/2010 11/10/2010 11/11/2010 11/15/2010 11/16/2010 11/17/2010 11/18/2010 11/23/2010 11/30/2010 12/1/20

26.90 24.76 21.79 0.00 30.12 33.45 32.26 31.43 42.14 20

26.90 24.76 25.38 0.00 55.60 33.45 32.26 31.43 43.04 25

76.61 73.24 73.49 0.00 45.42 76.15 75.07 73.54 74.21 69

35.12 33.81 29.64 0.00 66.31 43.93 42.98 42.74 56.79 29

8.21 9.05 7.86 0.00 36.19 10.48 10.71 11.31 14.64 9

0.00 0.24 1.90 0.00 4.52 8.93 6.55 3.69 6.43 2

41,392 41,400 41,350 41,965 41,711 40,773 39,933 40,156 38,690 35,7

72,754 73,418 72,341 74,000 65,483 72,162 70,629 71,055 68,321 46,5

34 129 475 0 13 13 13 13 13 

NETL DEMONSTRATION SYSTEM TREATMENT 
12/3/2010 12/6/2010 12/7/2010 12/8/2010 12/9/2010 12/10/2010 12/13/2010 12/14/2010 12/15/2010 12/16/2010 

8.45 27.50 24.64 21.55 21.31 15.95 20.95 20.36 25.83 25.95 

28.17 27.50 24.64 21.55 21.31 29.68 20.95 21.52 26.38 25.95 

75.53 74.76 74.46 74.49 73.06 72.04 74.26 72.77 70.92 72.19 

11.19 36.79 33.10 28.93 29.17 22.14 28.21 27.98 36.43 35.95 

2.74 9.29 8.45 7.38 7.86 6.19 7.26 7.62 10.60 10.00 

2.14 4.17 2.62 1.43 0.12 2.14 0.95 0.24 3.21 2.26 

33,355 33,438 34,198 35,428 35,903 36,280 35,110 34,147 34,315 34,475 

59,848 58,163 59,509 62,203 62,304 64,692 61,300 59,446 59,325 59,167 

0 0 0 0 0 0 12 16 12 47 
12/20/2010 12/21/2010 12/22/2010 12/27/2010 12/28/2010 1/1/2011 1/10/2011 1/20/2011 1/21/2011 1/24/2011 1

21.07 20.60 20.60 0.00 0.00 0.00 16.79 5.71 17.26 2.50 

21.07 20.60 20.86 0.00 0.00 0.00 20.66 22.12 21.58 16.30 

73.44 73.00 74.25 0.00 0.00 0.00 70.50 65.75 79.23 77.78 

28.69 28.21 27.74 0.00 0.00 0.00 23.81 8.69 21.79 3.21 

7.62 7.62 7.14 0.00 0.00 0.00 7.02 2.98 4.52 0.70 

1.19 0.24 1.19 0.00 0.00 0.00 2.26 0.12 1.55 0.00 

34,522 35,019 36,880 36,986 37,368 36,540 35,954 36,536 36,745 36,791 

60,127 60,950 63,580 73,018 73,794 58,460 62,565 65,085 64,900 61,052 

57 71 77 60 60 316 38 4,105 284 38 
1/27/2011 1/28/2011 1/31/2011 2/1/2011 2/2/2011 2/3/2011 2/4/2011 2/7/2011 2/8/2011 2/25/2011 2/28/2011 

0.00 6.55 20.00 22.62 20.24 19.05 22.98 20.12 14.52 19.40 19.17 

0.00 22.58 25.00 28.27 25.30 23.81 28.72 25.15 20.08 24.26 19.17 

0.00 67.07 75.68 74.80 74.89 70.80 76.89 74.78 71.76 74.77 75.23 

0.00 9.76 26.43 30.24 27.02 26.90 29.88 26.90 20.24 25.95 25.48 

0.00 3.21 6.43 7.62 6.79 7.86 6.90 6.79 5.71 6.55 6.31 

0.00 1.31 2.50 4.52 4.52 5.60 4.76 2.50 2.74 3.81 2.38 

37,084 37,396 38,115 38,580 38,218 36,845 36,627 35,641 35,591 21,292 17,711 

67,895 70,279 67,519 64,400 67,161 65,048 64,143 62,739 62,390 36,913 30,747 

691 569 66 40 38 35 67 31 73 40 24 
3/3/2011 3/4/2011 3/7/2011 3/8/2011 3/9/2011 3/10/2011 3/14/2011 3/15/2011 3/16/2011 3/17/2011 3/21/2011 

20.48 20.71 19.17 17.02 17.26 16.19 14.52 15.24 18.81 7.86 0.00 

25.60 25.89 23.96 21.28 21.58 20.24 18.15 19.05 23.51 9.82 0.00 

75.77 77.68 73.52 72.59 75.52 71.96 74.85 69.19 77.45 75.86 0.00 

27.02 26.67 26.07 23.45 22.86 22.50 19.40 22.02 24.29 10.36 0.00 

6.55 5.95 6.90 6.43 5.60 6.31 4.88 6.79 5.48 2.50 0.00 

3.33 3.57 1.31 2.14 1.43 2.26 0.00 1.19 1.19 0.24 0.00 

14,446 14,635 13,181 12,767 12,692 12,384 8,051 8,116 8,346 8,396 7,428 

24,911 25,246 23,021 21,889 21,989 21,480 13,829 13,925 14,385 14,440 14,929 

38 40 21 21 24 37 17 19 27 34 34 
3/25/2011 3/28/2011 3/29/2011 3/31/2011 4/6/2011 4/7/2011 4/8/2011

12.02 0.00 14.40 18.57 5.12 14.76 23.69

31.64 0.00 31.09 25.56 28.98 25.02 29.61

63.52 0.00 85.21 76.10 70.49 73.37 76.83

18.93 0.00 16.90 24.40 7.26 20.12 30.83

6.90 0.00 2.50 5.83 2.14 5.36 7.14

2.26 0.00 3.45 4.17 0.83 3.10 4.88

7,621 6,417 22,752 36,446 30,799 31,860 32,367

12,843 16,634 33,365 62,897 58,068 56,134 56,174

138 39 90 202 321 368 418
Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

0

90

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30

20

10

TREATMENT RATE (BBLS PER DAY)

TIME

TREATMENT RATE-TIME GRAPH

NORMALIZED
Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

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RECOVERY RATE (%)

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Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

0

6,000

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TDS (microSiemens/cm)

TIME

TOTAL DISSOLVED SOLIDS-TIME GRAPH

DW TDS
Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

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Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

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TIME

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Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

0

90

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TREATMENT RATE (BBLS PER DAY)

TIME

TREATMENT RATE-TIME GRAPH

NORMALIZED
Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

0

40

30

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CW (BBLS PER DAY)

TIME

CW DISPOSAL VOLUME-TIME GRAPH

CW OUT
Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

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RECOVERY RATE (%)

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Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

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TDS (microSiemens/cm)

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Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

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Altela, Inc. Report © 2011, Altela Inc., All Rights Reserved

Daily Operating Report (DOR) 4011 TR vs Time Graph

Altela Proprietary and Confidential Information

0

90,000

80,000

70,000

60,000

50,000

40,000

30,000

20,000

10,000

TDS (microSiemens/cm)

TIME

TOTAL DISSOLVED SOLIDS-TIME GRAPH

PW TDS CW TDS DW TDS