# Patent

## Title
Discharge lamp provided with a getter

## Abstract

In a discharge lamp comprising a discharge vessel surrounded by an outer bulb filled with nitrogen, a hydrogen getter is used comprising more than 80% by weight of Zr and Co and one or more elements chosen from the rare earth elements. The getter effectively removes hydrogen from the outer bulb and is not poisoned by nitrogen.

## Background
This application is a continuation of application Ser. No. 10/135,343 filed Apr. 30, 2002 now U.S. Pat. No. 6,800,998.


The invention concerns a discharge lamp, provided with a discharge vessel surrounded, at some distance, by an outer bulb filled with gas and provided with a getter.
Such a discharge lamp is known. An example of such a discharge lamp is a metal halide lamp. In such a known discharge lamp, the outer bulb is often filled with nitrogen, the pressure of which at room temperature is selected to be in the range 250 mbar-600 mbar. The getter is present in the lamp in order to remove hydrogen that comes to be in the outer bulb during lamp manufacture. If this hydrogen is not removed from the outer bulb, this hydrogen also enters the discharge vessel by diffusion through the discharge vessel wall. In this case re-ignition of the discharge lamp will be problematic. In practice it is difficult to find a getter with which in a nitrogen atmosphere small quantities of hydrogen can be removed for the greater part from the outer bulb. The getter must meet the requirement that hydrogen is effectively removed while the getter at the same time must not become poisoned by the nitrogen. The latter requirement often has the consequence that the getter cannot be activated by heating the getter for a certain time at a relatively high temperature. Such activation would increase the “getter activity” for gettering nitrogen to such extent that the getter would become poisoned by nitrogen.
It is an object of the invention to provide a discharge lamp provided with an outer bulb filled with gas and provided with a getter, in which hydrogen is removed in an effective manner from the outer bulb by the getter.
To achieve this a discharge lamp as mentioned in the opening is characterized in accordance with the invention in that the getter comprises more than 80% by weight Zr and Co and moreover one or more elements are chosen from among the rare earth elements.
It has been found that in a discharge lamp in accordance with the invention hydrogen is effectively removed from the outer bulb of the discharge lamp. It was found to be unnecessary to activate the getter, and the getter did not become so poisoned by other gases present in the outer bulb that the hydrogen gettering activity dropped significantly.
In a preferred embodiment of a discharge lamp in accordance with the invention, the gas composition contains nitrogen. It has been found that the getter that is used in the outer bulb of a discharge lamp in accordance with the invention is able to effectively getter hydrogen without becoming saturated with nitrogen and without it being necessary to activate the getter.
Good results have been obtained for embodiments of a discharge lamp in accordance with the invention in which the rare earth metals present in the getter are chosen from the group comprising Ce, La and Nd.
Good results have likewise been obtained for embodiments of a discharge lamp in accordance with the invention in which the percentage by weight of Zr in the getter is selected to be between 75% and 85%, the percentage by weight of Co in the getter between 10% and 20% and the percentage by weight of the rare earth metals between 1% and 10%. Discharge lamps in accordance with the invention with which good results have been obtained are metal halide lamps. It has been found that the quantity of hydrogen in the outer bulb of these lamps after a relatively low number of burning hours has fallen to virtually nil.
An example of the invention will be explained in more detail with reference to a drawing.



In the drawing, an example of a discharge lamp in accordance with the invention is shown.



In the FIGURE, there are contacts 9 for securing the discharge lamp to a power supply. The contacts 9 are secured to a lamp base 8. At the lamp base 8, an outer bulb 4 formed from hard glass is secured that surrounds a gas-tight area filled with nitrogen. The filling pressure of the nitrogen at room temperature is approximately 500 mbar. In this area a discharge vessel 1 is present that is formed from quartz glass and is secured to supply conductors 5. At one of the supply conductors 5, also a getter 6 is secured. The getter 6 is manufactured by SAES, is referred to as St 787/DF25 and comprises approximately 80% by weight Zr, 15% by weight Co and 5% by weight a mixture of rare earths elements comprising La, Nd and Ce. The discharge lamp is a metal halide lamp and the discharge vessel comprises 60 mbar Ar and a mixture of metal iodides. Reference numeral 2 refers to electrodes of the discharge lamp that are connected via current supply conductors 3 with the supply conductors 5. For a discharge lamp as shown in the FIGURE, it has been found that the quantity of hydrogen present in the outer bulb after 100 hours of burning and after 200 hours of burning is less than 0.001 mol %.
Table 1 shows the results of an experiment in which the nitrogen-sensitivities of both the St 787/DF25 getter and the PH/DF50 getter from SAES are evaluated. The getter PH/DF50 is a getter that is often used in discharge lamps with an outer bulb filled with nitrogen. The getter PH/DF50 comprises 70% by weight Zr2Ni, 20% by weight Ni and 10% by weight W. Each of the getters was placed in a nitrogen atmosphere of 1000 mbar at a temperature of 500° C. for varying time intervals. Then the activity for hydrogen absorption was measured in an argon flow comprising 1 mol % hydrogen. The table shows the maximum hydrogen getter speed Jmax of the two getters after 0, 1, 19, 70 and 384 hours contact with nitrogen at 500° C. The table also shows how long it took before this maximum getter speed was reached: timemax, as well as the value Q of the capacity of the getter. It can be seen that the maximum hydrogen getter speed of St787/DF25 is in all cases higher than that of PH/DF50. Furthermore, it can be seen that after a relatively long exposure to the nitrogen atmosphere this maximum getter speed is reached considerably more quickly by the St787/Df25 getter than by the PH/DF50 getter. Finally, it can be seen that the capacity of the getter for hydrogen after all the measured time intervals in which the getter was in contact with a nitrogen atmosphere of 500° C., is considerably higher in the case of St787/DF25 than in the case of PH/DF50. The data in Table I therefore clearly show that St787/Df25 is a more effective hydrogen getter in a nitrogen atmosphere than PH/DF50.











TABLE 1









Jmax (mbar.ml/





min.mg)
timemax (min)
Q(mbar.ml/mg)













Time (h) in N2
St787
PH/DF
St787
PH/DF
St787
PH/DF
















0
5.60
5.20
4
3
149.7
82.1


1
5.53
4.87
6
6
151.5
84.3


19
5.12
1.61
12
60
133.4
76.9


70
4.70
1.96
22
62
120.7
68.7


384
3.94
1.96
29
76
119.2
71.7

## Claims

1. A discharge lamp, provided with a discharge vessel surrounded by an outer bulb filled with gas containing nitrogen and provided with a non-activated getter, wherein the non-activated getter comprises more than about 80 percent by weight Zr and Co and furthermore comprises one or more elements chosen from among the rare earth metals, and wherein the non-activated getter is configured to remove an effective amount of hydrogen present in the outer bulb to a quantity of less than 0.001 molecular percent of hydrogen in the gas of the outer bulb without becoming saturated with nitrogen.

2. A discharge lamp as claimed in claim 1, wherein the discharge vessel contains an inert gas and a mixture of metal iodides.

3. A discharge lamp as claimed in claim 1, wherein the rare earth metals in the getter are chosen from the group comprising Ce, La, Nd and mixtures thereof.

4. A discharge lamp as claimed in claim 1, wherein the percentage by weight of Zr in the getter is between 75% and 85%, the percentage by weight of Co in the getter is between 10% and 20% and the percentage by weight of the rare earth metals is between 1% and 10%.

5. A discharge lamp as claimed in claim 1, wherein the discharge lamp is a metal halide lamp.

6. A discharge lamp which comprises:
a discharge vessel comprising argon and a mixture of metal iodides; 
an outer bulb filled with gas containing nitrogen, wherein the discharge vessel is surrounded, at a distance, by the outer bulb filled with gas, and 
a non-activated getter disposed within the outer bulb and configured to remove an effective amount of hydrogen present in the outer bulb to a quantity of less than 0.001 molecular percent of hydrogen in the gas of the outer bulb, wherein the non-activated getter comprises more than 80 percent by weight Zr and Co and further comprises one or more rare earth metals.

7. A discharge lamp as claimed in claim 6, wherein the argon is present at a pressure of 60 mbar.

8. A discharge lamp as claimed in claim 6, wherein the rare earth metals in the getter are chosen from the group comprising Ce, La, Nd and mixtures thereof.

9. A discharge lamp as claimed in claim 6, wherein the getter comprises about 80% by weight of Zr, about 15% by weight of Co, and about 5% by weight of a mixture of rare earth elements comprising Ce, La and Nd.

10. A discharge lamp as claimed in claim 9, wherein the getter is effective to remove hydrogen disposed in the outer bulb to a quantity of less than 0.001 molecular percent after 200 hours of burning.