## SAFETY DATA SHEET

Solstice® 1234ze

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Solstice® 1234ze

MSDS Number : 000000012546

Product Use Description : Aerosol propellant, Foam blowing agent

Manufacturer or supplier's

details : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001

+1-973-455-6300 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887

: : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : colourless

Odor : slight ether-like

Classification of the substance or mixture

Classification of the

substance or mixture : Gases under pressure, Liquefied gas Simple Asphyxiant

GHS Label elements, including precautionary statements

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Symbol(s) :

Signal word : Warning

Hazard statements : Contains gas unde r pressure; may explode if heated. May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention: Use personal protective equipment as required.

Storage: Protect from sunlight. Store in a well-ventilated place.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Chemical nature : Substance

Chemical Name CAS-No. Concentration

trans-1,3,3,3-Tetrafluoroprop-1-ene 29118-24-9 100.00 %

SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If breathing is irregular or stopped, administer artificial respirat ion. Use oxygen as required, provided a qualified operator is present. Call a physician.

Skin contact : Rapid evapouration of the liquid may cause frostbite. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. Call a physician if irritation develops

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or persists.

Eye contact : Rinse immediately with plen ty of water, also under the eyelids,

for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately.

Notes to physician

Treatment : Treat frost-bitten areas as needed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Water mist Dry powder

Foam Carbon dioxide (CO2)

Unsuitable extinguishing

media : High volume water jet

Specific hazards during firefighting : Contents under pressure. Heating will cause pressure ri se with risk of bursting Cool closed containers exposed to fire with water spray.

Product is not combustible under normal conditions. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Some risk may be expected of corrosive and toxic decomposition products. Fire may cause evolution of: Hydrogen fluoride

Special protective equipment for firefighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

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Exposure to decomposition products may be a hazard to

health.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe.

Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evapourates readily. Prevent spreading over a wide area (e.g. by containment or oil barriers).

Methods for cleaning up : Do not direct water spray at the point of leakage. Allow to evapourate.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only.

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Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Advice on protection against fire and explosion : Do not spray on a naked flame or any incandescent material. Keep away from direct sunlight. Fire or intense heat may cause violent rupture of packages. Vapours may form explosive mixtures with air. The product is not easily combustible.

Storage

Requirements for storage

areas and containers : Keep containers tightly closed in a cool, well-ventilated place. Keep away from direct sunlight. Protect cylinders from physical damage. Store away from incompatible substances.

Further information on storage conditions : Keep only in the original container at temperature not exceeding 50°C

Advice on common storage : Do not store together with: Oxidizing agents

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to

the workstation location.

Engineering measures : Local exhaust

Eye protection : Goggles

Hand protection : Protective gloves

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Skin and body protection : impervious clothing Wear cold insulating gloves/ face shield/ eye protection.

Respiratory protection : In case of insu fficient ventilation wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator.

Hygiene measures : Avoid br eathing vapours, mist or gas. Keep working clothes separately.

Do not smoke.

Exposure Guidelines

Components CAS-No. Value Control
parameters Upda

te Basis

trans-1,3,3,3-Tetrafluoroprop1-ene 29118-24-9 TWA :

time weighted

average (800 ppm) 2012 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

trans-1,3,3,3-Tetrafluoroprop1-ene 29118-24-9 TWA :

time weighted

average (800 ppm) 31.03.

11 Honeywell : Limit established by Honeywell

International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas

Color : colourless

Odor : slight ether-like

pH : Note: neutral

Boiling point/boiling range : -19 °C

Flash point : Note: does not flash

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Lower explosion limit : Note: Exhibits flam e limits at temperatures in excess of 28  ̊ C.

Upper explosion limit : Note: Exhibits flame limits at temperatures in excess of 28  ̊ C.

Vapor pressure : 4,192 hPa at 20 °C(68 °F)
10,998 hPa at 54.4 °C(129.9 °F)

Vapor density : 4 Note: (Air = 1.0)

Density : 1.17 g/cm3 at 21.1 °C

Water solubility : 0.373 g/l

Partition coefficient: noctanol/water : log Pow: 1.6

Ignition temperature : 368 °C Method: Auto-ignition temperature

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Possibility of hazardous

reactions : Hazardous polymerisation does not occur.

Conditions to avoid : Pressurized cont ainer. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Can form a combustible mixture with air at pressures above

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atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure.

Incompatible materials to

avoid : Reactions with alkali metals.

Hazardous decomposition products : Pyrolysis products containing fluoride

Fluorocarbons Hydrogen fluoride

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : Species: mouse Note: Acute (4-Hour) Inhalation Toxicity Screening Study (mouse): No lethality at >100,000 ppm.

: LC50: > 207000 ppm Exposure time: 4 h Species: rat

Skin irritation : Species: rabbit

Result: No skin irritation

Method: OECD Test Guideline 404

Sensitisation : Cardiac sensitization Species: dogs Result: Did not cause sensitisation on laboratory animals.

Repeated dose toxicity : Species: rat Application Route: Inhalation Exposure time: 13 Weeks Note: Causes mild effects on the heart. NOEL 5,000 ppm

Genotoxicity in vitro : Test Method: Chromosome aberration test in vitro Cell type: Human lymphocytes Result: negative

: Test Method: Ames test Result: negative

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Genotoxicity in vivo : Test Method: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: mouse Cell type: Micronucleus Application Route: Inhalation Result: negative

Teratogenicity : Species: rabbit Method: Prenatal Developmental Inhalation Toxicity Study Note: Did not show teratogenic effects in animal experiments.

: Species: rat Method: Prenatal Developmental Inhalation Toxicity Study Note: Did not show teratogenic effects in animal experiments.

Further information : Note: Excessive ex posure may cause central nervous system effects including drowsiness and dizziness. Excessive exposure may also cause cardiac arrhythmia. Rapid evapouration of the liquid may cause frostbite.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish : NOEC: > 117 mg/l Exposure time: 96 h Species: Cyprinus carpio (Carp)

Toxicity to daphnia and other aquatic invertebrates : EC50: > 160 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

Toxicity to algae : Growth inhibition NOEC: > 170 mg/l Exposure time: 72 h Species: Algae

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Elimination information (persistence and degradability)

Biodegradability : aerobic Result: Not readily biodegradable.

Further information on ecology

Additional ecological

information : no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental regulations.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. (trans-1,3,3,3-Tetrafluoroprop-1-ene)

Class 2.2 Packing group

Hazard Labels 2.2

IATA UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (trans-1,3,3,3-Tetrafluoroprop-1-ene)

Class : 2.2

Hazard Labels : 2.2 Packing instruction (cargo aircraft) : 200

Packing instruction (passenger aircraft) : 200

IMDG UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE)

Class : 2.2

Hazard Labels : 2.2

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EmS Number : F-C, S-V Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : Not in compliance with the inventory

: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL) : All components of this product are on the Canadian DSL.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : Not in compliance with the inventory

: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : Not in compliance with the inventory

: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

China. Inventory of Existing

Chemical Substances : On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : Not in compliance with the inventory

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: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

National regulatory information

SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

WHMIS Classification : A : Compressed Gas This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 1 2 Flammability : 0 0 Physical Hazard : 0 Instability : 0

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Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publicati on. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous

versions.

Previous Issue Date : 01/24/2014 Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group