# OAR Box 1875

Prepped by Ollie Stewart



## Document

Number: 

# 8 ) ll-E-2 6
Docket Number: 

# A-90-1 9

Printed 12/1/200811:12:44 AM Sheet 8of 86 p. 1T P. 2



# RADIA N A-90-1 9

MEETIN G NOTE S

I r? '- 

# 0 FROM : Bennet t King , Radia n ! : 

## p] r

## _LJ«I,J. ^ TO : Ja n Meyer , EPA/SD B |' r 

## ' | QJ: Q | 3 ^ DATE : Septembe r 14 , 199 2 '
REVIEWER : Juli e Ann e Probert , Radia n '-•-

- SUBJECT : Meetin g Note s fo r Jun e 11 , 199 1 wit h member s o f

th e Chemica l Manufacturer s Associatio n ATTENDEES : Se e Attachmen t 1

INTRODUCTION Th e suggeste d agend a fo r thi s meetin g i s include d a s Attachmen t 2
. On e ite m wa s adde d t o thi s suggeste d agenda : polycycli c organi c materia l (POM)
. Thes e meetin g notes.presen t th e highlight s o f th e discussio n i n th e orde r presente d o n the

. agenda

. 1. 0 SOURC E CATEGORY ISSUE S Th e discussio n unde r thi s topi c centere d o n th e possibilit y o f a phase d implementatio n o f th e Hazardou s Organi c NESHA P (HON)
. Th e Chemica l Manufacturer s Associatio n (CMA ) ha d prepare d a phase-i n pla n an

d provide d i t prio r t o th e meetin g (se e Attachmen t 3)
. I n general , th e CMA' s proposa l calle d fo r th e lis t o f SOCM I productio n processe s t o b e separate d int o thre e group s accordin g t o toxicity

. Thos e group s woul d b e subjec t t o th e requirement s o f th e HONaccordin g t o th e following schedule :

Grou p 1 : dat e o f promulgatio n Grou p 2 : 2 year s afte r dat e o f promulgatio n Grou p 3 : 5 year s afte r dat e o f promulgatio n
Thus , a s par t o f th e phase-i n proposal , th e CM Apropose d extendin g th e complianc e tim e beyond thre e year s afte r promulgation

. Representative s o f th e Environmenta l Protectio n Agenc y(EPA ) fel t thi s wa s no t permissibl e unde r th e Clea n Ai r

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## Ac t Amendment s (CAAA ) bu t woul d confirm thei r interpretatio n wit h th e Offic e o f Genera l Counci l (OGC)
. Th e CM Aals o suggeste d tyin g th e complianc e schedul e t o th e permittin g process . I n doin g so , delay s cause d b yth e permittin g proces s woul d no t b e considere d par t o f th e 3-yea r complianc e time

. Th e CM

Aals o provide d a n exampl e illustrating th e tim e an d step s involve d i n designin g an d buildin g a n incinerato r (se e Attachmen t 4 ) t o suppor t thei r clai mtha t th e 3-yea r complianc e tim e i s insufficient

. 2. 0 MAXIMUM ACHIEVABL E CONTRO L TECHNOLOGY (MACT ) ISSUE S 2. 1 Performanc e Testin g Alternative s Th e CM Aexpresse d a preferenc e tha t th e HONno t restric t source s t o a specifi c typ e o f tes t method , bu t rathe r allo wth e us e o f an

yapprove d EPAmethod

. Thi s discussio n centere d around EPAMethod s 1 8 an

d 25 Afo r measurin g th e concentratio n o f organi c compounds

. A s par t o f addressin g thi s issue , representative s fromth e EPA' s Emission s Measuremen t Branc h requeste d dat a from th e CM Atha t woul d compar e result s fo r Metho d 25 At o Metho d 18
. 2. 2 Applicability/Scop e o f HON Th e discussio n centere d o n ho wa sourc e woul d determin e whethe r o r no t the ywer e subjec t t o th e HON
. Currently , a sourc e i s subjec t t o th e HONi f i t produce s on e o r mor e chemical s o n a lis t o f approximatel y390
. Th e EPAmaypublis h thi s list , o r i t maypublis h th e lis t o f al l SOCM I chemical s (approximatel y660 )
an d designat e th e criteri a use d t o determin e whethe r o r no t a sourc e i s subjec t (i.e. , th e us e o f hazardou s ai r pollutant s [HAP's ] a s ra wmaterial s o r th e productio n o f HAP's)
. Th e CM A indicate d tha t thei r concer n wit h th e curren t applicabilit y definitio n la

y i n th e word s "production " an d "product. " Dependin g o n ho

w thi s wa s defined , th e scop e o f th e HONcoul d
varysignificantly

. Th e EPAindicate d i t wa s thei r inten t t o defin e thes e term s an d includ e th e caveat s necessaryt o clearl y indicat e wha t wa s mean t t o b e include d withi n th e scop e o f th e HON
.

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## 2. 3 Applicability/D e Minimi s Criteri a Th e specifi c applicabilit ycriteri a fo r eac h typ e o f emissio n poin t an

d an yassociate d d e minimi s criteri a wer e discussed

. Th e EPAstate d tha t criteri a simila r t o tha t from pas t rule s (e.g. , tank capacit yan d vapo r pressur e fo r storag e tanks ) woul d b e used

. Further , th e EPAwa s stil l considerin g whethe r t o develo p d e minimi s criteri a fo r eac h typ e o f emissio n point

. 2. 4 Applicabilit yBase d o n Tota l Organi c Compound (TOC ) vs . HA P and Multi-Medi a Impact s Neithe r o f thes e issue s wer e discusse d i n depth

. Th e CM A mentione d tha t the ywer e concerne d abou t thes e issues , an d th e EPAresponde d tha t the ywer e bein g considered

. 2. 5 PreliminaryResult s o f RegulatoryAnalysi s Th e CM Aexpresse d a n interes t i n seeing th e preliminary result s o f th e EPA' s analysis

. Th e EPAagree d t o sen d th e CM

A copie s o f th e draf t regulatoryalternativ e table s whic h sho wth e impact s o f th e regulatoryalternative s bein g evaluated

. Further , th e EPAagree d t o conside r providin g a draf t copyo f th e regulatio n an

d preamble

. 3. 0 POLYCYCLI C ORGANI C MATTE R Th e chemica l famil yo f POM appear s o n th e CAA Alis t o f HAP's
. Th e CM

Aexpresse d concer n ove r ho wth e presenc e o f POM i n a n emissio n strea

mwoul d affec t a source . Woul d th e presenc e o f
a POM forme d a s par t o f a combustio n proces s mak e a sourc e subjec t t o th e HON ? Th e EPAstate d tha t thi s wa s no t thei r intent

. Rather , th e HONwoul d onl yaffec t processe s producin g SOCM I chemicals

.

klJ-18 3 CMAmtg.n

tP. 5



## Attachmen t 1 CM AMEETIN

G - 6/11/9 2

Bennet t Kin g Lor i La y Gar y McAliste r Gi l Woo d Lind a Chapu t Davi dGustafso n Kathy Baile y Nanc y Cookson Bo bRosenstee l Lesli e Evan s Laszlo Takac s Ale xTurchin a Bruc e Wallingto n JanMeye r Richar dSigma n W.C . Holbroo k D.P . Anderso n Li z Fishe r Jo e Hoviou s Ki m Boudreau x Me l Keene r Radia n EPA/EMB EPA/EMB EPA/EMB EPA/SD B DO W CM A CM A EPA EPA Ox y Che m Procte r & Gambl e Merc k & Co . EPA/SD B CM A B F Goodric h Firs t Chemica l Roh m andHaa s UnionCarbid e Ethy l Corp . B P 919-541-910 0 919-541-482 5 919-541-106 2 919-541-554 4 919-541-535 8 517-636-295 3 202-887-118 6 202-887-124 1 919-541-560 8 919-541-541 0 716-286-310 3 513-634-716 1 908-302-781 5 919-541-525 4 202-887-131 3 216-447-792 5 601-938-222 7 215-592-254 5 203-794-518 3 504-388-777 6 202-785-488 8

klJ-18 3 CMAmtg.n

tP. 6

Attachmen t 2

Suggeste dAgend a fo r 6/11/9 1 Meetin g Betwee nCM A andEPA

1 . Sourc e Category Issue s

-. Federa l Registe r Notice o nSourc e Categor y Lis t

- CM A Recommendation s fo r Phased-i nComplianc e Schedul e
2 . MAC T Issue s

- Performanc e Testin g Alternative s

- Applicability/Scop e o f HON

- Applicability/D e Minimi s Criteri a

- TO C vs . HAP : Basi s fo r Determinin g Applicabilit y and/o r Complianc e

- Consideratio no f Multi-medi a Impact s inSettin g MAC T

- Discus s Preliminar y Result s o f EPA' s Regulator y Analysi s fo r Hazardou s Organi c NESHA PP. 7


### Attachmen t 3

CHEMICA L MANUFACTURER S ASSOCIATIO N



### Ma y 28 , 199 1

Dr

. Jane t

Meye r U.S

. Environmenta l Protectio nAgenc y Standard s Developmen t Branc h(MD-13 ) Researc hTriangl e Park , N C 2771 1 Dea r Dr

. Meyer :
On behal f o f the Chemica l Manufacturer s Association' s (CMA ) Ai r Toxic s Wor k Group , I woul d like t o than k yo u fo r the opportunit yt o mee t wit h yo u an

d othe r representative s o f EP A o n Februar

y28 , 199 1 an

d Marc h 13 , 199 1 t o discus s the Maximu mAchievabl e Contro l Technolog y (MACT ) Standard s fo r th e Syntheti c Organi c Chenlca l Manufacturing Industr y(SOCMI)
. A s a follow-u

p t o th e Februar

y2 8 meeting , the Ai r Toxic s Wor k Grou p ha s continue d t o evaluat e th e nee d fo r a phased-i n MAC T complianc e schedul e fo r SOCM I subcategorie s an d ha s develope d a phase-i n approac h tha t we . believ e voul d b e mos t aligne d wit h Congressiona l inten t fo r phasing l.: t th e MAC T regulations , EPA' s neo d t o promulgat e regulation s in a n efficien t manner , an d industry' s need t o b e abl e t o mee t the mandate d complianc e schedules

. Enclose d i s a doscripbio n o f CMA' s recommende d phase-i n approac h an d a discussio n o f wh ythi s approac h wil l hel p t o alleviat e the potentia l problem s associate d wit h a singl e complianc e schedul e fo r al l SOCM I subcategories

. W e loo k forward t o meeting wit h yo u t o discus s ou r recommendatio n on Jun e 11 , 1991
. I f yo u hav e an yquestions , pleas e fee l fre e t o cal l m e a t (202 ) 887-1313
. Sincerely ,

Richard Sigman Associat e Directo r Ai r Program s Enclosur e

cc : Rober t Rosenstee l Susan Wyat t

250 1 M Street , NW

, Washington
. DC 2003 7 202-887-110 0 Tele x8961 7 (CMA WSH )P. 8

CM A Recommendatio nfor Phasin g InMAC T Standard s

for SOCM I Subcategorie s

Introductio n

Ina lette r date dJanuar y 3 , 199 1 fro

m Richar dSigma no f CM A t o Rober t Rosenstee l o f EPA , CM A describe dit s concer ntha t membe r companie s ma

y b e unabl e t o mee t th e three-yea r MAC T complianc e tim e fram e i f MAC T standard s ar e applie dt o al l SOCM I processe s at on e time . Inthe letter , CM

A reporte dthe result s o f a surve y o f a limite dnumbe r o f CM A membe r companie s whic hforecaste da four-to-five-fol dincreas e inannua l demandfor contro l equipmen t i f MAC T standard s ar e applie dt o al l SOCM I processe s withi ntw o year s o f enactment . CM A expect s aneve n highe r increas e indemandfor contro l equipmen t whe nequipmen t requirement s resultin g fro m othe r Clea nAi r Ac t programs , e.g. , Titl e I , an dothe r compan

y voluntar y

program s ar e take nint o account . A s a result , CM

A questione dth e abilit y o f the SOCM I t o mee t the propose d complianc e deadline .
Inaddition , th e lette r note dCMA' s concer ntha t th e constructio n permi t demandcreate db y suc ha broa dapplicatio no f MAC T standard s coul dpotentiall y

overloa dth e permittin g syste m a t the Federal , State , an dloca l level s a t a tim e whe nState s ar e developin g an dimplementin g ne w operatin g permi t programs .
Congressiona l Directio nfor Phas e Ino f MAC T Standard s for SOCM I Subcategorie s
Bot hth e Hous e Committe e Repor t an dthe Explanator y Statemen t accompanyin g th e Conferenc e Repor t includ e statement s tha t suppor t CMA' s positio no nth e phase-i no f MAC T standard s for SOCMI . First , th e U.S . Congres s Join t Explanator y Statemen t o f the Committe e o f Conference , date dOctobe r 26 , 1990 , addresse s the schedul e for promulgatin g MAC T standards . Th e Conferenc e Committe e state s on page 33 8 o f thei r Report , "MAC T standard s for 4 0 sourc e categorie s shal l be promulgate dno t late r tha t 2 year s afte r th e date o f enactment , t

nselectin g categorie s for standard s inthi s group , th e Administrato r shall , a t th e Administrator' s discretion , pic k the priorit y

element s o f th e hazardou s organi c NESHA P whic hi s unde r development " (emphasi s added) . Late r onthe sam e page , the conferee s state , "[t]h e conferee s wis ht o emphasiz e tha t inpromulgatin g standards , th e EPA shoul ddevot e it s resource s firs t t o thos e pollutant s whic hpresent.th e greates t ris k t o the publi c healt han dthe environment. "
Th e significanc e o f thi s Statemen t i s enhance dan dmad e clea r ina discussio no f tha t Statemen t b y Congressma nDingell , inwhic hh e stated , "[i] t i s importan t t o stres s onc e agai ntha t th e statemen t o f manager s a s printe di nth e conferenc e repor t represent s th e view s o f al l th e manager s o r conferee s fro m the Hous e an

dSenat e wh o signe dth e conferenc e report.. . .. . Ingene t al , w e believ e tha t th e legislatio nP. 9

speak s for itsel f and , wher e i t wa s necessar y t o make , comments , th e conferenc e repor t include s specifi c statement s agree dupo nb y al l the conferee s o r managers " (emphasi s added) . Congressma nDingel l goe s o nt o state , " I presume tha t som e individua l conferee s inthe Hous e an dinthe Senat e ma y wan t t o expres s view s relativ e t o th e legislatio nan dt o offe r variou s interpretations . Tha t i s thei r right , an dI applaudthat . However , I wan t t o mak e i t clea r tha t onl y

th e statemen t o f managers , whic hi s par t o f th e conferenc e report , reflect s th e view s o f al l th e manager s o r conferee s i nth e Hous e an

dSenate . T o the exten t tha t th e managers ' statemen t i s silen t regardin g specifi c provision s an dtitles , tha t i s a deliberate decisio nonth e par t o f al l th e manager s wh o signe dth e conferenc e agreement . Silenc e shoul dno t b e give na differen t meaning " (emphasi s added) .
Base donth e foregoing , CM A conclude s tha t al l o f th e manager s an d conferee s wh o crafte dth e Clea nAi r Ac t Amendment s o f 199 0 instructe d th e Administrato r t o us e hi s discretio nt o pic k priorit y element s o f th e hazardou s organi c NESHAP , the nunde r developmen t b y EPA , for inclusio ninth e 4 1 sourc e categorie s fo r whic hMAC T woul db e promulgate db

y Novembe r 1992 . Th e Join t Statemen t i s consisten t wit hexpectation s expresse db y th e Hous e o f Representative s Committe e o nEnergy an dCommerc e o npag e 32 9 o f thei r repor t o nH R3030 , date dMay 17 , 1990 . Th e repor t states , "[t]h e Committe e woul dexpec t EP A t o phase-i nMAC T standard s t o allo w source s subjec t t o thos e standard s t o allocat e thei r resource s i nthe mos t effectiv e way. " Th e Repor t goe s ont o identif y factor s EP

A shoul d tak e int o accoun t i nprioritizin g an dschedulin g MAC T standards .

Recommende dPhase-I nApproac h
CM A recommend s a phase-i napproac hfor SOCM I MAC T regulation s wit h th e following features :
1 ) Th e approximatel y 38 8 subcategorie s withi nSOCM I shoul db e classifie dint o thre e groups , usin g a simila r approac ht o tha t take ndurin g th e regulator y negotiation s for equipmen t leak s t o grou paffecte dprocesses . Basically , thi s approac h groupe dth e lis t o f hazardou s ai r pollutant s int o five group s accordin g t o toxicity . Productio nprocesse s tha t produc e o r us e a s a reactan t an y o f th e mos t toxi c hazardou s ai r pollutant s wer e place dint o Grou p1 wit hth e earlies t applicabilit y

an dcomplianc e dates . Likewise , productio n processe s tha t produc e o r us e a s a reactan t an y o f th e nex t mos t toxi c hazardou s ai r pollutant s tha t wer e no t alread y designate dinGrou p1 wer e place dint o Grou p2 an ds o on . I t may be necessar y

t o adjus t th e hazardou s ai r pollutan t rankin g performe dunde r th e regulator y negotiation s t o tak e int o accoun t recen t wor k b y th e Agenc y

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### Wh yPhase-I n Approac h Wil l Alleviat e Problem s o f Singl e MAC T Complianc e Schedul e fo r Al l SOCM I Subcategorie s Provisio n fo r phased-i n complianc e wit h the SOCM I MAC T regulation s wil l allowfo r a mor e efficien t an d effectiv e allocatio n o f governmen t an d industr

yresources . In contras t t o a short-term , significan t increas e in deman

d .fo r design engineers , ccntro l equipment , an d permits , a longer , mor e sustained , les s drasti c chang e wil l allow "suppliers " t o prepar e fo r an d effectivel ymee t the demand

. I n addition , othe r factor s sugges t tha t availabl e resource s t o mee t deman

d fo r design engineers , contro l equipment , an d permit s wil l b e greate r in th e post-199 5 perio d than i n the pre-199 5 period

. Thi s i s becaus e state s wil l hav e mor e resource s t o issu e permit s afte r thei r Titl e V Operating Permi t Program s begi n generating fee s (b y1995)
. Finally , a phased-i n complianc e schedul e woul d encourag e an d provid e sufficien t time fo r companie s t o conside r sourc e reductio n techniques , (proces s redesign , materia l substitution , etc. ) fo r source s withi n subcategorie s wit h a late r applicabilit ydate

. Sourc e reductio n technique s generall yrequir e longe r lea d time for proces s an d produc t development

. EPA , throug h it s Pollutio n Preventio n .Program , ha s recognize d th e merit s o f sourc e reductio n a s a bette r environmenta l solutio n an

d i s encouraging it s us e throug h voluntar

yprogram s an

d throug h eliminatio n o f regulator yimpediment s t o pollutio n prevention

. Th e us e o f sourc e reductio n ha s th e adde d advantag e i n tha t i t ma y eliminat e the nee d fo r constructio n permit s fo r contro l equipment

. Conclusio n CM Arecommend s a phase-i n approac h tha t woul d retai n the feature s included i n the negotiate d MAC T standard s fo r equipmen t leaks

. Th e phase-i n approac h woul d establis h thre e grouping s o f SOCM I subcategorie s base d o n toxicit yo f hazardou s ai r pollutant s emitted

. Phased-i n complianc e woul d b e accomplishe d b ysettin

g applicabilit y date s o f 1992 , 1994 , an d 199 7 (assumin

g promulgatio n o f the hazardou s organi c NESHAP b

y1992 ) withi n a singl e rulemaking

. CM Abelieve s thi s approac h i s consisten t wit h Congressiona l directio n an

d wil l hel p t o alleviat e potentia l problem s associate d wit h a singl e complianc e schedul e fo r al l SOCM I sources .P.1 2


### ATTACHMEN

T Productio

nProcesse s i

nPropose

dGrou pI
Aceton e Acetonitril e Acetonphenon

e Acrylamid

e Acrylonitril e Adiponitril e Allyl alcoho l Aminophenol(p-isomer ) Anilin e Azobenzen

e Benzene(includin

g benzen

e fro m gasoline ) Benzenedisulfoni c acid Benzenesulfoni c acid Benzophenone(POM ) Biphenyl Bis(Chloromethyl)Ether(dichloromethy l ether ) Bromobenzen

e Butanedio l (1,4-isomer ) Butyrolacton

e Carbo ntetrachlorid

e Chloroacetophenon

e (2- ) Chloroanilin

e (o-isomer ) Chlorobenzen

e Chlorodifluormethan e Chlorofor

m Chloronitrobenzen

e (1,3- ) Chloronitrobenzen

e (o-isomer ) Chloronitrobenzene(p-isomer ) Cumen e hydroperoxid

e Cumen e (isopropyl benzene ) Cyclohexan

e Cyclohexano l Cyclohexanon

e Dichloroanilin

e (al l isomers ) Dichlorobenzene(1,4-Isomer)(p-isomer ) Dichlorobenzene(m-isomer ) Dichlorobenzene(o-isomer ) Dichlorodifluoromethan e Dichloroethane(1,2-isomer)(EDC ) Dichloroethylethe r (bis(2-chloroethyl)ether ) Diethanolaain

e Diethylen

e glyco l Diethylen

e glyco l dibuty l ether Diethylen

e glyco l diethy l ether (glyco l ether ) Diethylen

e glyco l dimethy l either (glyco l ether ) Diethylen

e glyco l aonobuty l either acetate(glyco l ether ) Diethylen

e glyco l aonobuty l ether (glyco l either ) Diethylen

e glyco l monoethy l ether acetat e (glyco l ether ) Diethylen

e glyco l monoethy l ether (glyco l either ) Diethylen

e glyco l monomethy l ether (glyco l ether ) Dimethy l sulfat e Dimethylaminoethanol(2-isomer ) Dinitrobenzene sP 1 3 

### Propose d Productio n Processe s i n Grou p I (Cont'd ) Dioxane(l,4-Diethyleneoxide ) Dioxlian e Dipheny l methan e Dipheny l oxid e (POM ) Dipropylen e glyco l Epichlorohydrin(l-Chloro-2,3-epoxypropane ) Ethanolamines(al l isomers ) Ethy l benzen e Ethylen e carbonat e Ethylen e dibromide(Dibromoethane)(EDB ) Ethylen e glyco l Ethylen e glyco l diacetat e Ethylen e Glyco l Diethy l Ethe r Ethylen e glyco l dimethy l ether(glyco l ether ) Ethylen e glyco l monobuty l ethe r acetate(glyco l ether ) Ethylen e glyco l monobuty l ethe r (glyco l ether ) Ethylen e glyco l monoethy l ethe r acetat e (glyco l ether ) Ethylen e glyco l monomethy l ether(glyco l ether ) Ethylen e glyco l monopheny l ether(glyco l ether ) Ethylen e glyco l monopropy l ether(glyco l ether ) Ethylen e oxid e Formaldehyd e Fumari c aci d Hexamethylenetetramin e Hydroguinon e Linea r alkylbenzene(linea r dodecylbenzene ) Malei c anhydrid e Malei c Hydrazid e Mali c aci d Metanili c aci d Methionin e Methylen e chloride(Dichloromethane ) Methylen e dianiline(4,4-isomer)(MDA ) MethyIstyrene(a-isomer ) Nitroaniline(o-isomer ) Nitroaniline(p-isomer ) Nitrobenzen e Octene- 1 Paraformaldehyd e Pentaerythrito l Perchloroethylene (Tetrachloroethylene ) Phenylenediamine(p-Isomer ) Piperazin

e Propiolactone( bisomer ) Propioni c acid Propylen

e glyco l Propylen

e glyco l monomethy l ether Propylen

e oxid e Resorcino l Styrene(Viny l Benzene ) Succini c aci dP.1 4


### Propose dProductio

nProcesse s i

nGrou pI (Cont'd ) Succinonitril e Tartari c Aci d tetrachlorobenzene(1,2,4,5-isomer ) Tetraethylen

e Glyco l Trichlorobenzene(1,2,4-isomer ) Trichloroethylen

e Trichlorogluoromethan e Trichlorophenol(2,4,5,- ) Trichlorotrifluoroethane(1,2,2-1,1,2,isomer ) Triethanolamin

e Triethylen

e glyco l Triethylen

e glyco l dimethy l ether(glyco l ether ) Triethylen

e Glyco l Monomethy l Ether Trimethylopropan

e Viny l chloride(Chloro Ethylene ) Xylenes(Mixtures ) Xylenes(o-isomer ) Xylenes(p-isomer )P.1 5



### Propose dProductio

nProcesse s i

nGrou pI I Acetaldehyd

e Acetaldo l Acetamid

e Acetanilid

e Aceti c acid Aceti c anhydrid

e Acetyl chlorid

e Anisidine(o-isomer ) Butadiene(1,3-isomer ) Butylen e glyco l (1,3-isomer ) Caprolacta

m Carbo nTetrabromid

e Carbo ntetrafluorid

e Chlora l Chloraceti c aci d Chloroanilin

e (p-isomer ) Chloropren

e (2-Chloro-l,3-Butadiene ) Chlorotrifluoromethan e Crotonaidehyd

e Cyclooctadien

e Cyclooctadien

e (1,5-isomer ) Dichloropropen

e (1,3-isomer ) Dichloro-1-butene(3,4-isomer ) Diethy l sulfat e Dimethy l benzidine(3,3-isomer ) Dimethy l formamide(NN-isomer)(DMF ) Dimethyl Hydrazin

e (1,1-isomer ) Dimethy l terephthalat e Ethyl acetat e Ethy l acrylat e Ethyl chloroacetat e Ethylenediamin

e Ethylhexy l acrylate(2-isoemr ) Formamid

e Formi c acid Glycero l Glycero l dichlorohydri n Glycin e Glyoxa l Hexachlorobenzen

e Hexachlorobutadlen

e Hexachloroethan

e Hexadiene(1,4-isomer ) Methy l format e Paraldehyd

e Picoline(b-isomer ) Pyridin e Sodiu m chloroacetat e Sulfolan

e Terephthali c aci d Tetrachloroethane(1,1,2,2-isomer ) Tetrahydrophthall c anhydrid e Tetramethylenediamln eP.1 6


### Propose dProductio

nProcesse s i

nGrou pI I (Cont'd )
Toluen e 2,4 , diamin

e Toluen e 2, 4 diisocyanat e Toluen e disocyanates(mixture ) Toluidine(o-isomer ) Trichloroethane(1,1,1-isomer)(methylchloroform ) Trichloroethane(1,1,2-isomer)(Vinyl Trichloride ) Vinyl acetat e Vinylcyclohexene(4-isomer ) Vinyliden

e chloride(1,1-Dichloroethylene )

### Propose dProductio

nProcesse s i

nGrou pI I (Cont'd ) Acetoacetanilid

e Anilin e hydrochlorid

e Anthraquinon

e (POM ) Benzaldehyd

e Benzi l (POM ) Benzili c aci d(POM ) Benzoi c aci d Benzoi n(POM ) Benzoyl chlorid

e Benzyl acetat e Benzyl alcoho l Benzyl benzoat e (POM ) Benzyl chlorid

e Benzyl dichorid

e Bispheno l A(POM ) Butylbenzy l phthalat e Chlorotoluen

e (m-isomer ) Chlorotoluen

e (o-isomer ) Creso l (m-isomer ) Cresol s cresyli c acid(mixed ) Cresol s (o-isomer ) Cresol s (p-isomer ) Cyclohexylamin

e Dichloropheno l (2,4-isomer ) Diethy l phthalat e Dilsodecylphthalat e 

### Dimethy l Phthalat e Dimethylaniline-N,N(N, N Diethylaniline ) Dinitropheno l (2,4-isomer ) Dinitrotolunene(2,4-isomer)(DNT ) Dipheny l thiourea (POM ) Diphenylamine(POM ) Di-o-tolyguanidin

e Dodecylpheno l Ethylanilin

e (N-Isomer ) Ethylaniline(o-isomer ) Isophthali c aci d Isopropylpheno 1 Methlaniline(n-isomer ) Methylcyclohexan

e Methylen

e dipheny l diisocyanat e (MDI ) Nitroanisole(p-iosaer ) Nitrophenol(4-)(p- ) Nitrophenol(o-isoaer)(2-Nitrophenol ) Nitrotoluen

e Nitrotoluene(2-Isomer)(o- ) Nitrololuene(3-isoaer)(a- ) Nitrotoluene(4-isomer)(P- ) Octylpheno l Pentachloropheno l Phenetidine(p-isoaer ) Pheno l Phenolphthalei nP.1 8

Propose dProductio nProcesse s i nGrou pI I (Cont'd )
Phenoisulfoni c acids(al l isomers ) Phloroglucino l Phthali c aci d Phthali c anhydrid e Phthalimid e Phthalonitril e P-tert-Buty l toluen e Quinon e Sallcycli c aci d Sodiu m phenat e Stilben e Sulfanili c aci d Tetrabromophthali c anhydrid e Tetrachlorophthali c anhydrid e Toluenesulfoni c acid s (al l isomers ) Toluenesulfony l chlorid e Trichloraniline(2,4,6-isomer ) Viny l toluen e Xylen e Sulfoni c Aci d xylene(m-isomer )P.1 9

Propose dProductio nProcesse s i nGrou pII I
Acrolei n Acryli c aci d Ally l chlorid e Ally l cyanid e Ammoniu m thiocyanat e Bromonaphthalen e (POM ) Carbo ndisulfide Chloronaphthalen e (POM ) Decahydronaphthalat e Dially l Phthalat e Diethylamin e Dimethy l ether-N, N Diemthylamin e Ethy l chloride(Chloroethane ) Glutaraldehyde Hexanetriol(l,2,6-isomer ) Isophoron e Methano l Methy l acetat e Methy l bromide(Bromomethane ) Methy l chloride(Chloromethane ) Methy l Hydrazine Methy l isobuty l carbino l Methy l isbuty l ketone(Hexone ) Methy l isocyanat e Methy l mercapta n Methy l methacrylat e Methylamine Naphthalen e Naphthalen e sulfoni c acid(a-isomer)(POM ) Naphthalene sulfoni c acid(b-isoraer)(POM ) Naphthol(a-isomer)(POM ) Naphthol(b-isomer)(POM ) 

### Nitronaphthalene(l-)(POM ) Perchloromethy l mercapta n Phosgen e Proplona l dehyde Propylen e dichloride(1,2-Dichloropropane ) Sodiu m Methooxid e Tetraethy l lead Tetrahydronaphthalene(Tetralin)(POM ) Triethylamin e Trimethylaraine Trimethylcyclohexano l Trimethylcyciohexanon ePropose dProductio nProcesse s i nGrou pII I (Cont'd )

Aceta l Aceton e cyanohydri n(C N compound ) Bromofor

m Buty l acrylat e (n-isomer ) Carbary l Chlorodifluoroethan e Diaminopheno l Hydrochlorid e Diethylaniline(2,6-isomer ) Dllsoocty l phthalat e Dodecylanilin e Ethylamin e Ethylcellulos e Hexachlorocyclopentadien e Isobuty l acrylat e Isobutylen e Methy l acrylat e Methy l ethy l ketone(2-Butanone ) Methy l Ter t Buty l Ethe r Methylpentyno l Nonylpheno l N-Vinyl-2-Pyrrolidin e Polyethylen e glyco l Polypropylen e glyco l Sodiu m format e Tetramethylethlen e diamin e Trimethylpentane(2,2,4- )P.2 1 

### Propose dProductio

nProcesse s i

nGrou pII I (Cont'd ) Acenaphthene(POM ) Alizarin(POM ) Alky l anthraguineone s Alkyl napthalen

e sulfonate s Aminopheno l sulfoni c acid Anthroacene(POM ) Carbazol e Chrysen e (PON ) Diacetoxy-2-Butene(l,4- ) Dibromomethan

e Dibutoxyethylphthalat e Dichlorotetrafluoroethan e Dichloro-2-butene(1,4- ) Diethylen

e glyco l monohexy l ether(GE ) Diethylen

e glyco l monomethy l ether acetat e (GE ) Di(2-methoxyethyl)phthalat e Dodecy l benzen

e (branched ) Dodecy l pheno l (branched ) Ethylen e glyco l dibuty l ether(GE ) Ethylen e glyco l monoacetat e Ethylen e glyco l monohexyl ether(GE ) Ethylen e glyco l monoocty l ether (GE ) Ethylenediamin

e Tetraaceti c acid Ethylnaphthalene(2-isomer)(alky l naphthalene ) Fluoranthene(POM ) Glyceraldehyd

e Hydroxyadipaldehyd

e iminodiethanol(2,2- ) Isophoron

e nitril e Lea dphthalat e Methylcyclohexano l Methylionones(a-isomer ) Methyinaphthalene(l-isomer)(alky l naphthalene ) Methylnaphthalene(2-isomer)(alky l naphthalene ) Naphtholsulfoni c acid(l-)(POM ) Naphthylamin

e sulfoni c acid(l,4-)(P0M ) Naphthylamin

e sulfoni c acid(2,l-)(P0M ) Naphthylamine(l-)(POM ) Naphthylamine(2-)(POM ) Nitropropane(2- ) Nitroxylen

e Nonylbenzene(branched ) Pentanol(2- ) Phenanthrene(POM ) Propylen

e carbonat e Pyrene(POM ) Tetraethylenepentamln e Thiocarbanilid

e Thiourea Triethylen

e glyco l monoethy l ether Trimethylcyclohexylamin e Tripropylen

e glyco l Xanthates(potassiu

m ethyl xanthate )P.2 2



## Attachmen t 4

CHEMICAL MANUFACTURER S ASSOCIATION
REGULATORYCOMPLIANC E TIMELIN E EXAMPLE S

(Jun e 7 , 1991 )

Smal l Liqui dIncinerato r
Attache di s the timelin e (pg . 2 ) discusse ddurin g a CM A meetin g wit hEP

A i nFebruar y

o f thi s year . Thi s timelin e represent s the actua l histor y

t o date o f a smal l RCR A liqui dwast e incinerato r (MSDO33417031) . Som e activitie s wil l probabl y no t b e complete dunti l 1992 . Thi s particula r uni t i s simila r (excep t for th e burne r assemblies ) t o tw o othe r unit s installe dinth e Southwes t tha t ar e designe dt o incinerat e ven t gase s fro m refinerie s an

dfro m chemica l manufacturin g plants . Th e genera l detail s o f th e uni t show nonthe attache ddrawing s (pgs . 3,4,5) , wer e take ndirectl y fro m th e permi t applicatio nfor the unit . Th e siz e o f th e uni t woul dapproximat e th e siz e o f a larg e ven t ga s incinerato r for a larg e multipurpos e facility . Pleas e not e ther e i s no scrubbe r an

dn o particulat e contro l device s becaus e o f th e uniqu e natur e o f the liqui dwastes . Thi s informatio ni s par t o f the publi c recor dfor th e incinerato r an dm y b e freel y

distributed .MS003W1703 1 SMAL L LIQUI DINCINERATOR

TIN E ACTIVIT Y

IDENTIF Y1 SELEC T CONSULTAN T T O REVIEW

ft RECOMMEND EQUIPMEN T SELEC T ft REVIEW

EQUIPMEN T PRELIMINAR YENGINEERING PREPAR E PERMI T APPLICATIO N SUBMI T APPLICATIO N
1 PERMI T REVIEW

ft CHANGE S PUBLI C HEARING S DRAF T PERMI T PERMI T APPROVE D t o ' EQUIPMEN T CONTRAC T SIGHE D I 10/8 6 10/8 7 10/8 8 10/8 9 10/9 0 10/9 1

DETAI L DESIGN EQUIPMEN T PROCURNENT/DELIVERY SIT E PREPARATION CONSTRUCTION COMMISSION START-U P TRIAL BUR

N PLA N (ANALYTICAL ) REVIEW ft APPROVAL STAC KTES T ANALYSI S O F STAC KSAMPLE S PREPAR E ft SUBMI T REPOR T REGULATORYREVIEW

O F REPOR T APPROVE D? RETES T & RESUBMI T

r oP.2 4

1 

### & 

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Timelin e Base do nQuestionnaire
Th e response s t o th e CM A questionnair e tha t follow s ar e bes t understoo dwhe nplace di nthe contex t o f th e proces s tha t i s generall y utilize dfor engineerin g desig nan dconstruction . Th e seriousnes s o f extremel y

shor t complianc e deadline s i s magnifie db y the realizatio n tha t stop s i

nthe proces s ar e essentiall y performe di

nseries ; therefore , simila r task s mus t b e complete db y the sam

e discipline s simultaneousl y

acros s al l projects . Char t 1 (pg . 7 ) graphicall y illustrate s the constructio nproces s for thre e kind s o f projects ; a simpl e projec t done o nanAs-Soon-As-Possibl e basi s (Projec t 1) , a simpl e projec t done ona nAs-Late-As-Possibl e basi s (Projec t 3) , an da comple xprojec t done As-Soon-As-Possibl e wit hno t tim e for slippag e i

n schedul e (Projec t 2) . As indicate donthe chart , majo r task s group s (suc ha s permittin g an dequipmen t procurement ) compris e onl y a fractio n o f the tim

e withi nthe overal l complianc e tim e perio dan

doverla p projects . A s th e numbe r o f project s withi na give ntim e perio di s increase d(i.e. , shorte r complianc e tim e periods) , th e probabilit y o f meetin g require dobjective s b y complianc e deadline s i s reduce dan da t som e poin t may

become impossibl e t o accomplish .
Th e concer no f meetin g schedul e i s commont o al l tas k element s sinc e overloa do f tas k resource s may b e possibl e inan y tas k group . Th e response s t o th e questionnair e therefor e provid e a samplin g o f dat a tha t ca nbe utilize dt o anticipate th e likelihoo do f tas k resourc e overloa dinth e area s of :Engineerin g Concep t Developmen t Detaile dEngineerin g Permittin g Equipmen t Procuremen t Constructio n Shakedow

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