13339 Hagers Ferry Road

Huntersville, NC 28078-7929

McGuire Nuclear Complex - MG03A2

Phone: 980-875-5245 Fax: 980-875-4349

Order Summary Report

Analytical Laboratory

Order Number: J12080374

Project Name: Marshall HAPS/MACT

Lab Contact: Jason C Perkins

Date: 9/10/2012

Customer Address: 8320 NC Hwy 150 East

Customer Name(s): BILL KENNEDY, RON LAWS, ALLEN STOWE, DONNA BURRELL, GREG PHIL

Mail Code: Marshall Steam Station

Terrell, NC 28682

Phone: 980-875-5348

Report Authorized By:

(Signature)

Program Comments:

Please contact the Program Manager (Jason C Perkins) with any questions regarding this report.

Data Flags & Calculations:

Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality

system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) 

under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data 

included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the 

subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have

been qualified by Duke Energy to perform these analyses except where noted.

Data Package:

This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of 

the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except 

in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The 

order of individual sections within this report is as follows:

Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,

Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & 

Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)

Certification:

The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina 

(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of 

specific methods. 

Analytical Lab 

Page 1 of 33
Sample ID's & Descriptions:

Sample ID Plant/Station

Collection 

Date and Time Collected By Sample Description

2012018309 MARSHALL 21-Aug-12 2:00 PM David Morris (Prism) FGD Purge Eff 

2012018310 MARSHALL 21-Aug-12 2:50 PM David Morris (Prism) EQ TANK 

2012018311 MARSHALL 21-Aug-12 2:15 PM David Morris (Prism) Clarifier EFF. 

2012018312 MARSHALL 21-Aug-12 2:15 PM David Morris (Prism) CLarifier EFF. HG BLANK 

2012018313 MARSHALL 21-Aug-12 3:00 PM David Morris (Prism) VFW-EFF 

2012018314 MARSHALL 21-Aug-12 3:00 PM David Morris (Prism) VFW-EFF HG BLANK 

2012018315 MARSHALL 21-Aug-12 2:00 PM David Morris (Prism) FILTER BLANK 

2012018316 MARSHALL 21-Aug-12 9:00 AM David Morris (Prism) Trip blank 

8 Total Samples

Analytical Lab 

Page 2 of 33
COC and .pdf report are in agreement with sample totals 

and analyses (compliance programs and procedures).

All Results are less than the laboratory reporting limits.

All laboratory QA/QC requirements are acceptable.

Yes No

Technical Validation Review

Checklist:

Yes No

Yes No

Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results

Sample Identification Customer Specific Data Sheets, Reports, & Documentation

Technical Validation of Data Package Customer Database Entries

Analytical Laboratory Certificate of Analysis

Analytical Laboratory QC Report

Chain of Custody

Reviewed By: Mary Ann Ogle Date: 9/10/2012

Electronic Data Deliverable (EDD) Sent Separately

Analytical Lab 

Page 3 of 33
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J12080374

2012018309

Collection Date: 21-Aug-12 2:00 PM

Site: FGD Purge Eff 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

ALKALINITY - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

INORGANIC IONS BY IC

Bromide 120 mg/L EPA 10 100 300.0 8/27/2012 11:45:00 PM JAHERMA

Chloride 4400 mg/L EPA 100 1000 300.0 8/27/2012 11:45:00 PM JAHERMA

Sulfate 1600 mg/L EPA 100 1000 300.0 8/27/2012 11:45:00 PM JAHERMA

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) 58.1 ug/L EPA 2.5 50 245.1 8/23/2012 1:44:07 PM AGIBBS

Mercury Dissolved (cold vapor) in Water (Filtered)

Mercury (Hg) < 2.5 ug/L EPA 2.5 50 245.1 8/23/2012 1:58:13 PM AGIBBS

DISSOLVED METALS BY ICP

Manganese (Mn) 12.0 mg/L EPA 0.05 10 200.7 8/24/2012 11:13:00 AM DJSULL1

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 111 mg/L EPA 0.5 10 200.7 8/28/2012 12:27:00 PM MHH7131

Calcium (Ca) 4500 mg/L EPA 0.1 10 200.7 8/28/2012 12:27:00 PM MHH7131

Iron (Fe) 187 mg/L EPA 0.1 10 200.7 8/28/2012 12:27:00 PM MHH7131

Lithium (Li) 0.303 mg/L EPA 0.05 10 200.7 8/28/2012 12:27:00 PM MHH7131

Magnesium (Mg) 1090 mg/L EPA 0.05 10 200.7 8/28/2012 12:27:00 PM MHH7131

Manganese (Mn) 13.4 mg/L EPA 0.05 10 200.7 8/28/2012 12:27:00 PM MHH7131

Potassium (K) 73.0 mg/L EPA 1 10 200.7 8/28/2012 12:27:00 PM MHH7131

Sodium (Na) 40.1 mg/L EPA 0.5 10 200.7 8/28/2012 12:27:00 PM MHH7131

DISSOLVED METALS BY ICP-MS

Selenium (Se) 215 ug/L EPA 10 10 200.8 8/31/2012 12:40:00 PM KRICHAR

TOTAL RECOVERABLE METALS BY ICP-MS

Arsenic (As) 145 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Cadmium (Cd) < 10 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Chromium (Cr) 298 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Copper (Cu) 178 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Nickel (Ni) 296 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Selenium (Se) 1860 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Silver (Ag) < 10 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

Zinc (Zn) 369 ug/L EPA 10 10 200.8 8/29/2012 1:35:00 PM KRICHAR

PH IN WATER (NON-COMPLIANCE ANALYSIS) - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

SELENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC)

Vendor Parameter Complete Vendor Method V_AS&C

Analytical Lab 

Page 4 of 33
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J12080374

2012018309

Collection Date: 21-Aug-12 2:00 PM

Site: FGD Purge Eff 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

TOTAL DISSOLVED SOLIDS

TDS 21000 mg/L SM2540C 200 1 8/29/2012 4:30:00 PM TJA7067

TOTAL SUSPENDED SOLIDS

TSS 12000 mg/L SM2540D 250 1 8/23/2012 10:08:00 AM TJA7067

2012018310

Collection Date: 21-Aug-12 2:50 PM

Site: EQ TANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) < 2.5 ug/L EPA 2.5 50 245.1 8/23/2012 1:46:27 PM AGIBBS

Mercury Dissolved (cold vapor) in Water (Filtered)

Mercury (Hg) < 2.5 ug/L EPA 2.5 50 245.1 8/23/2012 2:00:33 PM AGIBBS

DISSOLVED METALS BY ICP

Manganese (Mn) 6.24 mg/L EPA 0.05 10 200.7 8/24/2012 11:17:00 AM DJSULL1

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 57.1 mg/L EPA 0.5 10 200.7 8/28/2012 12:31:00 PM MHH7131

Calcium (Ca) 980 mg/L 0.1 10 EPA 200.7 8/28/2012 12:31:00 PM MHH7131

Iron (Fe) < 0.1 mg/L EPA 0.1 10 200.7 8/28/2012 12:31:00 PM MHH7131

Lithium (Li) 0.060 mg/L EPA 0.05 10 200.7 8/28/2012 12:31:00 PM MHH7131

Magnesium (Mg) 555 mg/L EPA 0.05 10 200.7 8/28/2012 12:31:00 PM MHH7131

Manganese (Mn) 6.72 mg/L EPA 0.05 10 200.7 8/28/2012 12:31:00 PM MHH7131

Potassium (K) 11.2 mg/L EPA 1 10 200.7 8/28/2012 12:31:00 PM MHH7131

Sodium (Na) 22.5 mg/L EPA 0.5 10 200.7 8/28/2012 12:31:00 PM MHH7131

DISSOLVED METALS BY ICP-MS

Selenium (Se) 140 ug/L EPA 10 10 200.8 8/31/2012 12:44:00 PM KRICHAR

TOTAL RECOVERABLE METALS BY ICP-MS

Arsenic (As) < 10 ug/L EPA 10 10 200.8 8/29/2012 1:38:00 PM KRICHAR

Cadmium (Cd) < 10 ug/L 10 10 EPA 200.8 8/29/2012 1:38:00 PM KRICHAR

Chromium (Cr) < 10 ug/L EPA 10 10 200.8 8/29/2012 1:38:00 PM KRICHAR

Copper (Cu) < 10 ug/L EPA 10 10 200.8 8/29/2012 1:38:00 PM KRICHAR

Nickel (Ni) 70.5 ug/L EPA 10 10 200.8 8/29/2012 1:38:00 PM KRICHAR

Selenium (Se) 143 ug/L EPA 10 10 200.8 8/29/2012 1:38:00 PM KRICHAR

Silver (Ag) < 10 ug/L 10 10 EPA 200.8 8/29/2012 1:38:00 PM KRICHAR

Zinc (Zn) 16.4 ug/L EPA 10 10 200.8 8/29/2012 1:38:00 PM KRICHAR

Analytical Lab 

Page 5 of 33
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J12080374

2012018311

Collection Date: 21-Aug-12 2:15 PM

Site: Clarifier EFF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

ALKALINITY - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

INORGANIC IONS BY IC

Bromide 130 mg/L EPA 10 100 300.0 8/28/2012 12:03:00 AM JAHERMA

Chloride 4600 mg/L EPA 100 1000 300.0 8/28/2012 12:03:00 AM JAHERMA

Sulfate 1700 mg/L EPA 100 1000 300.0 8/28/2012 12:03:00 AM JAHERMA

MERCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC)

Vendor Parameter Complete Vendor Method V_BRAND

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 111 mg/L EPA 0.5 10 200.7 8/28/2012 12:35:00 PM MHH7131

Calcium (Ca) 1840 mg/L EPA 0.1 10 200.7 8/28/2012 12:35:00 PM MHH7131

Iron (Fe) < 0.1 mg/L EPA 0.1 10 200.7 8/28/2012 12:35:00 PM MHH7131

Lithium (Li) 0.118 mg/L EPA 0.05 10 200.7 8/28/2012 12:35:00 PM MHH7131

Magnesium (Mg) 1070 mg/L EPA 0.05 10 200.7 8/28/2012 12:35:00 PM MHH7131

Manganese (Mn) 12.4 mg/L EPA 0.05 10 200.7 8/28/2012 12:35:00 PM MHH7131

Potassium (K) 19.1 mg/L EPA 1 10 200.7 8/28/2012 12:35:00 PM MHH7131

Sodium (Na) 39.0 mg/L EPA 0.5 10 200.7 8/28/2012 12:35:00 PM MHH7131

TOTAL RECOVERABLE METALS BY ICP-MS

Arsenic (As) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Cadmium (Cd) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Chromium (Cr) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Copper (Cu) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Nickel (Ni) 136 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Selenium (Se) 197 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Silver (Ag) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

Zinc (Zn) 29.2 ug/L EPA 5 5 200.8 8/29/2012 1:41:00 PM KRICHAR

PH IN WATER (NON-COMPLIANCE ANALYSIS) - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

TOTAL DISSOLVED SOLIDS

TDS 15000 mg/L SM2540C 40 1 8/29/2012 4:30:00 PM TJA7067

TOTAL SUSPENDED SOLIDS

TSS 9.0 mg/L SM2540D 5 1 8/23/2012 10:08:00 AM TJA7067

Analytical Lab 

Page 6 of 33
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J12080374

2012018312

Collection Date: 21-Aug-12 2:15 PM

Site: CLarifier EFF. HG BLANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

MERCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC)

Vendor Parameter Complete Vendor Method V_BRAND

2012018313

Collection Date: 21-Aug-12 3:00 PM

Site: VFW-EFF 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

ALKALINITY - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

INORGANIC IONS BY IC

Bromide 81 mg/L EPA 10 100 300.0 8/27/2012 11:27:00 PM JAHERMA

Chloride 2500 mg/L EPA 100 1000 300.0 8/27/2012 11:27:00 PM JAHERMA

Sulfate 700 mg/L EPA 10 100 300.0 8/27/2012 11:27:00 PM JAHERMA

MERCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC)

Vendor Parameter Complete Vendor Method V_BRAND

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 56.7 mg/L EPA 0.5 10 200.7 8/28/2012 12:39:00 PM MHH7131

Calcium (Ca) 1010 mg/L EPA 0.1 10 200.7 8/28/2012 12:39:00 PM MHH7131

Iron (Fe) 0.115 mg/L 0.1 10 EPA 200.7 8/28/2012 12:39:00 PM MHH7131

Lithium (Li) 0.061 mg/L EPA 0.05 10 200.7 8/28/2012 12:39:00 PM MHH7131

Magnesium (Mg) 541 mg/L EPA 0.05 10 200.7 8/28/2012 12:39:00 PM MHH7131

Manganese (Mn) 6.06 mg/L EPA 0.05 10 200.7 8/28/2012 12:39:00 PM MHH7131

Potassium (K) 13.3 mg/L EPA 1 10 200.7 8/28/2012 12:39:00 PM MHH7131

Sodium (Na) 22.6 mg/L 0.5 10 EPA 200.7 8/28/2012 12:39:00 PM MHH7131

TOTAL RECOVERABLE METALS BY ICP-MS

Arsenic (As) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

Cadmium (Cd) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

Chromium (Cr) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

Copper (Cu) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

Nickel (Ni) < 5 ug/L 5 5 EPA 200.8 8/29/2012 1:44:00 PM KRICHAR

Selenium (Se) 13.1 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

Silver (Ag) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

Zinc (Zn) < 5 ug/L EPA 5 5 200.8 8/29/2012 1:44:00 PM KRICHAR

PH IN WATER (NON-COMPLIANCE ANALYSIS) - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

Analytical Lab 

Page 7 of 33
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J12080374

2012018313

Collection Date: 21-Aug-12 3:00 PM

Site: VFW-EFF 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

TOTAL DISSOLVED SOLIDS

TDS 8300 mg/L SM2540C 40 1 8/29/2012 4:30:00 PM TJA7067

TOTAL SUSPENDED SOLIDS

TSS < 5 mg/L SM2540D 5 1 8/23/2012 10:08:00 AM TJA7067

2012018314

Collection Date: 21-Aug-12 3:00 PM

Site: VFW-EFF HG BLANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

MERCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC)

Vendor Parameter Complete Vendor Method V_BRAND

2012018315

Collection Date: 21-Aug-12 2:00 PM

Site: FILTER BLANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

Mercury Dissolved (cold vapor) in Water (Filtered)

Mercury (Hg) < 0.05 ug/L EPA 0.05 1 245.1 8/23/2012 2:02:54 PM AGIBBS

DISSOLVED METALS BY ICP

Manganese (Mn) < 0.005 mg/L EPA 0.005 1 200.7 8/24/2012 10:30:00 AM DJSULL1

DISSOLVED METALS BY ICP-MS

Selenium (Se) < 1 ug/L EPA 1 1 200.8 8/31/2012 12:25:00 PM KRICHAR

2012018316

Collection Date: 21-Aug-12 9:00 AM

Site: Trip blank 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) < 0.05 ug/L EPA 0.05 1 245.1 8/23/2012 1:48:49 PM AGIBBS

Analytical Lab 

Page 8 of 33
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J12080374

2012018316

Collection Date: 21-Aug-12 9:00 AM

Site: Trip blank 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

TOTAL RECOVERABLE METALS BY ICP

Boron (B) < 0.05 mg/L EPA 0.05 1 200.7 8/28/2012 1:16:00 PM MHH7131

Calcium (Ca) 0.026 mg/L EPA 0.01 1 200.7 8/28/2012 1:16:00 PM MHH7131

Iron (Fe) < 0.01 mg/L EPA 0.01 1 200.7 8/28/2012 1:16:00 PM MHH7131

Lithium (Li) < 0.005 mg/L EPA 0.005 1 200.7 8/28/2012 1:16:00 PM MHH7131

Magnesium (Mg) < 0.005 mg/L EPA 0.005 1 200.7 8/28/2012 1:16:00 PM MHH7131

Manganese (Mn) < 0.005 mg/L EPA 0.005 1 200.7 8/28/2012 1:16:00 PM MHH7131

Potassium (K) < 0.1 mg/L EPA 0.1 1 200.7 8/28/2012 1:16:00 PM MHH7131

Sodium (Na) < 0.05 mg/L EPA 0.05 1 200.7 8/28/2012 1:16:00 PM MHH7131

TOTAL RECOVERABLE METALS BY ICP-MS

Arsenic (As) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Cadmium (Cd) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Chromium (Cr) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Copper (Cu) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Nickel (Ni) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Selenium (Se) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Silver (Ag) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Zinc (Zn) < 1 ug/L EPA 1 1 200.8 8/29/2012 12:51:00 PM KRICHAR

Analytical Lab 

Page 9 of 33
 

September 4, 2012 

Jay Perkins 

Duke Energy Analytical Laboratory 

Mail Code MGO3A2 (Building 7405) 

13339 Hagers Ferry Rd. 

Huntersville, NC 28078 

(704) 875-5245 

Project: HAPS/MACT Testing Marshall (LIMS #J12080374) 

Dear Mr. Perkins, 

Attached is the report associated with one (1) aqueous sample submitted for selenium speciation 

analysis on August 23, 2012. The sample was received in a sealed cooler at -0.1°C on August 

24, 2012. Selenium speciation analysis was performed via ion chromatography inductively 

coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS). Any issues 

associated with the analysis are addressed in the following report. 

If you have any questions, please feel free to contact me at your convenience. 

 Sincerely, 

 

 Russell Gerads 

 Vice President 

 Applied Speciation and Consulting, LLC 

 

Analytical Lab 

Page 10 of 33
Applied Speciation and Consulting, LLC 

Report prepared for: 

Jay Perkins 

Duke Energy Analytical Laboratory 

Mail Code MGO3A2 (Building 7405) 

13339 Hagers Ferry Rd. 

Huntersville, NC 28078 

Project: HAPS/MACT Testing Marshall (LIMS #J12080374) 

September 4, 2012 

1. Sample Reception 

One (1) aqueous sample in a 125mL HDPE bottle (provided by Applied Speciation and 

Consulting) was submitted for selenium speciation analysis on August 23, 2012. The sample 

was received on August 24, 2012 in a sealed container at -0.1°C. 

The sample was received in a laminar flow clean hood, void of trace metals contamination 

and ultra-violet radiation, and was designated a discrete sample identifier. An aliquot of the 

sample was filtered (0.45μm) and the filtrate was stored in a secure, monitored cryofreezer 

(maintained at a temperature of -80oC) until selenium speciation analysis could be performed 

via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry 

(IC-ICP-CRC-MS). 

2. Sample Preparation 

All sample preparation is performed in laminar flow clean hoods known to be free from trace 

metals contamination. All applied water for dilutions and sample preservatives are 

monitored for contamination to account for any biases associated with the sample results. 

Selenium Speciation Analysis by IC-ICP-CRC-MS Prior to analysis, an aliquot of the sample 

was filtered with a syringe filter (0.45μm) and injected directly into a sealed autosampler 

vial. No further sample preparation was performed as any chemical alteration of a sample 

may shift the equilibrium of the system, resulting in changes in speciation ratios. 

3. Sample Analysis 

All sample analysis is preceded by a minimum of a five-point calibration curve spanning the 

entire concentration range of interest. Calibration curves are performed at the beginning of 

each analytical day. All calibration curves, associated with each species of interest, are 

Analytical Lab 

Page 11 of 33
standardized by linear regression resulting in a response factor. All sample results are 

instrument blank corrected to account for any operational biases associated with the 

analytical platform. 

Prior to sample analysis, all calibration curves are verified using second source standards 

which are identified as initial calibration verification standards (ICV). 

Ongoing instrument performance is identified by the analysis of continuing calibration 

verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval 

of every ten analytical runs. 

Selenium Speciation Analysis by IC-ICP-CRC-MS Each sample for selenium speciation 

analysis was analyzed by ion chromatography inductively coupled plasma collision reaction 

cell mass spectrometry (IC-ICP-CRC-MS) on August 29, 2012. An aliquot of each sample is

injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The 

eluting selenium species are then introduced into a radio frequency (RF) plasma where 

energy-transfer processes cause desolvation, atomization, and ionization. The ions are 

extracted from the plasma through a differentially-pumped vacuum interface and travel 

through a pressurized chamber (CRC) containing a reaction gas which preferentially reacts 

with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector 

detects ions transmitted through the mass analyzer and the resulting current is processed by a 

data handling system. 

Retention times for each eluting species are compared to known standards for species 

identification. 

4. Analytical Issues 

The overall analyses went well and no significant analytical issues were encountered. All 

quality control parameters associated with the samples were within acceptance limits.

The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are 

generated from replicate analyses of the lowest standard in the calibration curve. Not all 

selenium species are present in preparation blanks; therefore, eMDL calculations based on 

preparation blanks are artificially biased low. 

The eMDL for methylseleninic acid and selenomethionine is calculated from the average 

eMDL of selenite, selenate, and selenocyanate. The calibration does not contain 

methylseleninic acid or selenomethionine due to impurities in these standards which would 

bias the results for other selenium species. 

Analytical Lab 

Page 12 of 33
If you have any questions or concerns regarding this report, please feel free to contact me. 

Sincerely, 

Russell Gerads 

Vice President 

Applied Speciation and Consulting, LLC 

Analytical Lab 

Page 13 of 33
Sample Results

Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe

Unknown Se 

Species (n)

FGD Purge Eff 198 23.2 ND (<2.1) ND (<3.4) ND (<3.4) 0.0 (0)

All results reflect the applied dilution and are reported in μg/L

ND = Not detected at the applied dilution

SeCN = Selenocyanate

MeSe(IV) = Methylseleninic acid

SeMe = Selenomethionine

Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS

n = number of unknown Se species observed

Report Generated by: Russell Gerads

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: HAPS/MACT Testing Marshall

Contact: Jay Perkins

Date: September 4, 2012

LIMS #J12080374

Analytical Lab 

Page 14 of 33
Quality Control Summary - Preparation Blank Summary

Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 1000x

Se(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.0068 6.8

Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.0014 1.4

SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.0021 2.1

MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.0034 3.4

SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.0034 3.4

eMDL = Estimated Method Detection Limit

*Please see narrative regarding eMDL calculations

Quality Control Summary - Certified Reference Materials

Analyte (μg/L) CRM True Value Result Recovery

Se(IV) LCS 9.57 9.47 99.0

Se(VI) LCS 9.48 9.33 98.4

SeCN LCS 8.92 8.63 96.7

MeSe(IV) LCS 6.47 6.14 95.0

SeMe LCS 9.32 8.81 94.5

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: HAPS/MACT Testing Marshall

Contact: Jay Perkins

LIMS #J12080374

Date: September 4, 2012

Report Generated by: Russell Gerads

Analytical Lab 

Page 15 of 33
Quality Control Summary - Matrix Duplicates

Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD

Se(IV) Batch QC ND (<6.8) ND (<6.8) NC NC

Se(VI) Batch QC 2.0 1.8 1.9 10.0

SeCN Batch QC ND (<2.1) ND (<2.1) NC NC

MeSe(IV) Batch QC ND (<3.4) ND (<3.4) NC NC

SeMe Batch QC ND (<3.4) ND (<3.4) NC NC

ND = Not detected at the applied dilution

NC = Value was not calculated due to one or more concentrations below the eMDL

Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate

Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD

Se(IV) Batch QC 5560 5310 95.5 5560 5309 95.5 0.0

Se(VI) Batch QC 5045 4710 93.3 5045 4676 92.7 0.7

SeCN Batch QC 4575 4187 91.5 4575 4180 91.4 0.2

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: HAPS/MACT Testing Marshall

Contact: Jay Perkins

LIMS #J12080374

Date: September 4, 2012

Report Generated by: Russell Gerads

Analytical Lab 

Page 16 of 33
Analytical Lab 

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3958 6th Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • brl@brooksrand.com

August 31, 2012

Duke Energy

ATTN: Jay Perkins

Scientific Support-Laboratory

13339 Hagers Ferry Road

Huntersville NC 28078

jcperkins@duke-energy.com

labcustomer@duke-energy.com

RE: Project DUK-HV1201 Client Project: J12080374

Dear Mr. Perkins,

On August 24, 2012, Brooks Rand Labs (BRL) received two (2) wastewater samples and two 

(2) corresponding field blanks. The samples were logged-in for total mercury (Hg) analysis 

according to the chain-of-custody form. All samples were received, prepared, analyzed, and 

stored according to BRL SOPs and EPA methodology.

The results were blank-corrected as described in the calculations section of the relevant SOP(s) 

and may have been evaluated using reporting limits that have been adjusted to account for 

sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, 

and other details. 

All data was reported without qualification, aside from concentration qualifiers, and all

associated quality control sample results met the acceptance criteria.

BRL, an accredited laboratory, certifies the reported results of all analyses for which BRL is 

NELAP accredited meet all NELAP requirements. For more details, see the Report Information

page of the report. 

Please feel free to contact me if you have any questions regarding this report.

Sincerely,

 

Tiffany Stilwater

Project Manager 

tiffany@brooksrand.com 

Analytical Lab 

Page 18 of 33
Project ID: DUK-HV1201

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Definition of Data Qualifiers

(Effective 9/23/09)

Laboratory Accreditation

BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida 

Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is 

also certified by many other states to perform environmental analyses. For a current list of our accreditations /certifications, 

please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results reported relate only to the 

samples listed in the report.

Report Information

BLK

BRL

BS

CAL

CCV

CRM

D

DUP

ICV

MSD

ND

NR

PS

REC

RPD

RSD

SCV

SOP

method blank 

Brooks Rand Labs

laboratory fortified blank

calibration standard

continuing calibration verification

certified reference material

dissolved fraction

duplicate

initial calibration verification

matrix spike duplicate

non-detect

non-reportable

post preparation spike

percent recovery

relative percent difference

relative standard deviation

secondary calibration verification

standard operating procedure

MDL

MRL

MS

method detection limit

method reporting limit

matrix spike

SRM

T

COC

standard reference material

total recoverable fraction

chain of custody record 

Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand Labs, those found in the EPA SOW ILM03.0, 

Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic 

Superfund Data Review; USEPA; January 2010. These supersede all previous qualifiers ever employed by BRL.

B Detected by the instrument, the result is > the MDL but ≤ the MRL. Result is reported and considered an estimate.

E An estimated value due to the presence of interferences. A full explanation is presented in the narrative.

H Holding time and/or preservation requirements not met. Result is estimated.

J Estimated value. A full explanation is presented in the narrative.

J-M Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated.

J-N Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated.

M Duplicate precision (RPD) was not within acceptance criteria. Result is estimated.

N Spike recovery was not within acceptance criteria. Result is estimated.

R Rejected, unusable value. A full explanation is presented in the narrative.

U Result is ≤ the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL.

X Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. 

Result is estimated.

Field Quality Control Samples

Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type 

and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be 

done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field 

quality control samples.

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Lab 

Page 19 of 33
Project ID: DUK-HV1201

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Sample Information

Sample Lab ID Report Matrix Type Sampled Received

Clarifier Eff 1234030-01 Effluent Sample 08/21/2012 08/24/2012

Clarifier Eff Hg Blank 1234030-02 DIW Field Blank 08/21/2012 08/24/2012

VFW Eff 1234030-03 Effluent Sample 08/21/2012 08/24/2012

VFW Eff Hg Blank 1234030-04 FGD Wastewater Field Blank 08/21/2012 08/24/2012

Batch Summary

Analyte Lab Matrix Method Prepared Analyzed Batch Sequence

Hg Water EPA 1631 08/27/2012 08/29/2012 B121562 1200671

Sample Results

Sample Analyte Report Matrix Basis Result Qualifier MDL MRL Unit Batch Sequence

Clarifier Eff

1234030-01 Hg Effluent T 451 3.03 8.08 ng/L B121562 1200671

Clarifier Eff Hg Blank

1234030-02 Hg DIW T 0.15 U 0.15 0.40 ng/L B121562 1200671

VFW Eff

1234030-03 Hg Effluent T 8.02 0.77 2.05 ng/L B121562 1200671

VFW Eff Hg Blank

1234030-04 Hg FGD Wastewater T 0.15 U 0.15 0.40 ng/L B121562 1200671

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Lab 

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Project ID: DUK-HV1201

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Accuracy & Precision Summary

Batch: B121562

Analyte Native Spike Result Units REC & Limits RPD & Limits

Method: EPA 1631

Lab Matrix: Water

Sample

B121562-SRM1 Certified Reference Material (1232065, NIST 1641d 1000x dilution)

Hg 15.68 16.89 ng/L 108% 85-115

B121562-MS2 Matrix Spike (1234026-05)

Hg 278.6 1389 1959 ng/L 121% 71-125

B121562-MSD2 Matrix Spike Duplicate (1234026-05)

Hg 278.6 1389 1763 ng/L 107% 71-125 2411%

Method Blanks & Reporting Limits

Batch: B121562

Method: EPA 1631

Matrix: Water

Analyte: Hg

Sample Result Units

B121562-BLK1 0.12 ng/L

B121562-BLK2 0.10 ng/L

B121562-BLK3 0.09 ng/L

B121562-BLK4 0.05 ng/L

Average: 0.09 Standard Deviation: 0.03 MDL: 0.15

Limit: 0.50 Limit: 0.10 MRL: 0.40

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Lab 

Page 21 of 33
Project ID: DUK-HV1201

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Instrument Calibration

Sequence: 1200671

Instrument: THG-05 Method: EPA 1631

Date: 08/29/2012

Total Mercury and Mercury Speciation by CVAFS

Analyte: Hg

Lab ID True Value Result Units REC & Limits

1200671-IBL1 6.03 pg of Hg

1200671-IBL2 9.30 pg of Hg

1200671-IBL3 7.52 pg of Hg

1200671-IBL4 13.33 pg of Hg

1200671-CAL1 25.00 23.49 pg of Hg 94%

1200671-CAL2 100.0 103.5 pg of Hg 103%

1200671-CAL3 500.0 541.1 pg of Hg 108%

1200671-CAL4 2500 2214 pg of Hg 89%

1200671-CAL5 10000 10910 pg of Hg 109%

1200671-ICV1 1568 1689 pg of Hg 108% 85-115

1200671-CCV1 500.0 528.4 pg of Hg 106% 77-123

1200671-CCB1 14.8 pg of Hg

1200671-ICB1 17.47 pg of Hg

1200671-CCV2 500.0 533.1 pg of Hg 107% 77-123

1200671-CCV3 500.0 493.3 pg of Hg 99% 77-123

1200671-CCV4 500.0 525.1 pg of Hg 105% 77-123

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Lab 

Page 22 of 33
Project ID: DUK-HV1201

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Sample Containers

Lab ID: 1234030-01 Report Matrix: Effluent

Sample: Clarifier Eff Sample Type: Sample Received: 08/24/2012

Collected: 08/21/2012

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71666330

10

Bottle FLPE Hg-T 500 mL None N/A Cooler

Lab ID: 1234030-02 Report Matrix: DIW

Sample: Clarifier Eff Hg Blank Sample Type: Field Blank Received: 08/24/2012

Collected: 08/21/2012

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71666330

10

Bottle FLPE Hg-T 500 mL None N/A Cooler

Lab ID: 1234030-03 Report Matrix: Effluent

Sample: VFW Eff Sample Type: Sample Received: 08/24/2012

Collected: 08/21/2012

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71520010

10

Bottle FLPE Hg-T 250 mL None N/A Cooler

Lab ID: 1234030-04 Report Matrix: FGD Wastewater

Sample: VFW Eff Hg Blank Sample Type: Field Blank Received: 08/24/2012

Collected: 08/21/2012

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71520010

10

Bottle FLPE Hg-T 250 mL None N/A Cooler

Shipping Containers

Cooler

Tracking No: 5353 0519 3476 via FedEx

Temperature: 0.5 °C

Coolant Type: Ice

Description: Cooler

Damaged in transit? No

Returned to client? No

Custody seals present? Yes

Custody seals intact? Yes

COC present? Yes

Received: August 24, 2012 9:00

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Lab 

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Analytical Lab 

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This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample 

Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed 

according to the referenced methods. 

Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case 

narrative.

NC Certification No. 402

SC Certification No. 99012

NC Drinking Water Cert No. 37735

Case Narrative

08/30/2012

Duke Energy Corporation (04)

Jay Perkins

13339 Hagers Ferry Road

Huntersville, NC 28078

Project: HAPS/MACT Testing Marshall

Project No.: J12080374

Lab Submittal Date: 08/22/2012

Prism Work Order: 2080575

VA Certification No. 1287

Please call if you have any questions relating to this analytical report.

Respectfully,

PRISM LABORATORIES, INC.

VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:

HT Sample received and analyzed outside of the hold time.

MDL Method Detection Limit

BRL Below Reporting Limit

RPD Relative Percent Difference

*

Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and 

reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 8

Analytical Lab 

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Sample Receipt Summary

08/30/2012

Prism Work Order: 2080575

Client Sample ID Lab Sample ID Matrix Date Sampled Date Received

2012018309/FGD Purge Eff 2080575-01 Water 08/21/12 08/22/12

2012018311/Clarifier Eff 2080575-02 Water 08/21/12 08/22/12

2012018313/VFW Eff 2080575-03 Water 08/21/12 08/22/12

Samples received in good condition at 1.3 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 8

Analytical Lab 

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Laboratory Report

08/30/2012

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Project: HAPS/MACT Testing 

Marshall

Duke Energy Corporation (04)

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 2080575-01

Prism Work Order: 2080575

Time Collected: 08/21/12 14:00

Time Submitted: 08/22/12 16:00

2012018309/FGD Purge Eff

J12080374

General Chemistry Parameters

pH 6.9 HT pH Units 1 *SM4500-H B 8/28/12 11:00 JAB P2H0613

Total Alkalinity 56 mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0610

Carbonate Alkalinity BRL mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0611

Bicarbonate Alkalinity 56 mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0612

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 8

Analytical Lab 

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Laboratory Report

08/30/2012

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Project: HAPS/MACT Testing 

Marshall

Duke Energy Corporation (04)

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 2080575-02

Prism Work Order: 2080575

Time Collected: 08/21/12 14:15

Time Submitted: 08/22/12 16:00

2012018311/Clarifier Eff

J12080374

General Chemistry Parameters

pH 6.9 HT pH Units 1 *SM4500-H B 8/28/12 11:00 JAB P2H0613

Total Alkalinity 44 mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0610

Carbonate Alkalinity BRL mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0611

Bicarbonate Alkalinity 44 mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0612

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 8

Analytical Lab 

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Laboratory Report

08/30/2012

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Project: HAPS/MACT Testing 

Marshall

Duke Energy Corporation (04)

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 2080575-03

Prism Work Order: 2080575

Time Collected: 08/21/12 15:00

Time Submitted: 08/22/12 16:00

2012018313/VFW Eff

J12080374

General Chemistry Parameters

pH 7.1 HT pH Units 1 *SM4500-H B 8/28/12 11:00 JAB P2H0613

Total Alkalinity 200 mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0610

Carbonate Alkalinity BRL mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0611

Bicarbonate Alkalinity 200 mg/L 5.0 0.66 1 *SM2320 B 8/28/12 11:00 JAB P2H0612

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 8

Analytical Lab 

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8/30/12

Level II QC Report

13339 Hagers Ferry Road Project No: J12080374

Duke Energy Corporation (04) Project: HAPS/MACT Testing Marshall

Huntersville, NC 28078

Attn: Jay Perkins

Prism Work Order: 2080575

Time Submitted: 8/22/2012 4:00:00PM

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

General Chemistry Parameters - Quality Control

Batch P2H0610 - NO PREP

Blank (P2H0610-BLK1) Prepared & Analyzed: 08/28/12 

Total Alkalinity BRL 5.0 mg/L

LCS (P2H0610-BS1) Prepared & Analyzed: 08/28/12 

Total Alkalinity 243 5.0 mg/L 250.0 97 90-110

LCS Dup (P2H0610-BSD1) Prepared & Analyzed: 08/28/12 

Total Alkalinity 249 5.0 mg/L 250.0 100 90-110 2 200

Batch P2H0611 - NO PREP

Blank (P2H0611-BLK1) Prepared & Analyzed: 08/28/12 

Carbonate Alkalinity BRL 5.0 mg/L

LCS (P2H0611-BS1) Prepared & Analyzed: 08/28/12 

Carbonate Alkalinity 243 5.0 mg/L 90-110

LCS Dup (P2H0611-BSD1) Prepared & Analyzed: 08/28/12 

Carbonate Alkalinity 249 5.0 mg/L 90-110 2 200

Batch P2H0612 - NO PREP

Blank (P2H0612-BLK1) Prepared & Analyzed: 08/28/12 

Bicarbonate Alkalinity BRL 5.0 mg/L

LCS (P2H0612-BS1) Prepared & Analyzed: 08/28/12 

Bicarbonate Alkalinity 243 5.0 mg/L 250.0 97 90-110

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 8

Analytical Lab 

Page 30 of 33
8/30/12

Level II QC Report

13339 Hagers Ferry Road Project No: J12080374

Duke Energy Corporation (04) Project: HAPS/MACT Testing Marshall

Huntersville, NC 28078

Attn: Jay Perkins

Prism Work Order: 2080575

Time Submitted: 8/22/2012 4:00:00PM

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

General Chemistry Parameters - Quality Control

Batch P2H0612 - NO PREP

LCS Dup (P2H0612-BSD1) Prepared & Analyzed: 08/28/12 

Bicarbonate Alkalinity 249 5.0 mg/L 250.0 100 90-110 2 200

Batch P2H0613 - NO PREP

LCS (P2H0613-BS1) Prepared & Analyzed: 08/28/12 

pH 6.91 pH Units 6.860 101 99-101

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

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Analytical Lab 

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Page 8 of 8

Analytical Lab 

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Analytical Lab 

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