Grain sorghum ethanol lifecyce impacts calculations

Different plant types 92% wet DGs

## Life Cy**cle Greenhouse Gas Emissions per mmBtu**

**2022 LIFE CYCLE GHG EMISSIONS**

Sorghum Ethanol – Dry Mill NG Sorghum Ethanol – Dry Mill Coal Sorghum Ethanol – Dry Mill Biogas

## Life Cy**cle Greenhouse Gas Emissions per mmBtu 2022 LIFE CYCLE GHG EMISSIONS**  CH4 Other (fuel and feedstock transport) 31 Domestic Farm Inputs and Fert N2O 76 Domestic Land Use Change (For CO2 emissions, go to GHG per Btu DomLUC worksheet) 0 Domestic Livestock 572 Domestic Rice Methane 209 International Farm Input GHG 17 International Livestock -232 International Rice Methane -248 Fuel Production - No CHP, 92% Wet DG 406 - Yes CHP, 92% Wet DG 399 - No CHP, 92% Wet DG 344 - Yes CHP, 92% Wet DG 315 - No CHP, 92% Wet DG 66 - Yes CHP, 92% Wet DG 17**1.000**ethanol yield

metric tons g / mmBtu N2O CO2 B gal mmBtu GHG 1 26,934 0.1 7,592,400 **3,661** 31 54,965 0.1 7,592,400 **8,714** 0 0.1 7,592,400 0 0 0.1 7,592,400 **-1,798** 0 0 0.1 7,592,400 **577** 105 21,494 0.0 8,022,222 **6,772** -8 0 0.0 8,022,222 **-917** 0.0 8,022,222 **-649**
3 158,518 0.1 7,592,400 **22,111** 2 135,581 0.1 7,592,400 **19,062** 3 292,883 0.1 7,592,400 **39,648** 3 277,860 0.1 7,592,400 **37,577** 3 47,541 0.1 7,592,400 **6,548** 2 10,806 0.1 7,592,400 **1,563**

### An**nual Emissions**

**Domestic Land Use Change g C02 / mmBtu** 
**An nualized Year**  **0 1**  **2 3**  **4 5**  **6 2022**  -83,561 -2.2

**Cumulative Ethanol Volume Differences: [Sorghum Only] - [Control] Millions of Gallons**  **Case 2002**  **2007 2012**  **2017 2022**  Sorghum Only 4 11 49 176 300(Paste in from FASOM analysis summary xls - "Biofuels" tab) Control 4 11 33 117 200(Paste in from FASOM analysis summary xls - "Biofuels" tab) Difference 0 0 16 59 100 Cumulative Difference 0 0 16 75 175 **TOTA L**  **175 7**  **8 9**  **10 11**  **12 13**  **14 15**  **16**

-2.2 -2.2 -2.2 -2.2 -0.1 -0.1 -0.1 -0.1 -0.1 -1.3

(Paste in from FASOM analysis summary xls - "Biofuels" tab) (Paste in from FASOM analysis summary xls - "Biofuels" tab)**17 18**  **19 20**  **21 22**  **23 24**  **25 26** 

-1.3 -1.3 -1.3 -1.3 -0.4 -0.4 -0.4 -0.4 -0.4 0.3**27 28**  **29 30** 

0.3 0.3 0.3 0.3

## Results (Control minus Fuel Specific Case)

ID # **2022 Emissions (tons, or tonnes for GHG) & Energy (mmBtu)** A **Domestic A g Sector** 

**Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  A.1 On-Farm Combustion Emissions -7.007 -0.046 0.076 0.003 -0.272 A.2 Fuel Production Upstream Emissions 0.201 0.000 0.000 0.000 0.001 A.3 Farm Chemical Production / Transport Upstream Emissions 88.885 0.000 0.001 0.000 0.001 A.4 On-Farm Non-Combustion Non-GHG Emissions 130.361 0.719 3.179 1.778 22.013 A.5 Land Use Change GHG Emissions A.6 Livestock Changes GHG Emissions A.7 Rice Production GHG Emissions A.8 On-Farm Non-Combustion GHG Emissions **Total** 212.439 0.673 3.256 1.782 21.742 B **Domestic Biofuel Feedstock Transport**

**Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Sorghum Used for Ethanol 3.01E+00 1.83E-03 8.66E-02 1.05E-02 3.16E-02 Soybeans / Oil Used for Fuel 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 DDGS Produced 6.48E-02 3.95E-05 1.87E-03 2.27E-04 6.80E-04 Cellulosic Feedstock 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 **Total** 3.070 0.002 0.088 0.011 0.032 E **Domestic Non-Petro Fuel Transport (plant to bulk terminal)**

**Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Ethanol 37 0.02 0.17 0.02 0.04 Biodiesel 0 0.00 0.00 0.00 0.00 Renewable Diesel 0 0.00 0.00 0.00 0.00 **Total** 37.225 0.018 0.172 0.023 0.037 H **Int'l A g Sector** 

**Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Livestock Changes - CanadaLivestock Changes - Western Europe Livestock Changes - Eastern Europe Livestock Changes - Oceania Livestock Changes - Latin America Livestock Changes - Asia Livestock Changes - Africa and Middle East Livestock Changes - Indian Subcontinent **Total** 0.000 0.000 0.000 0.000 0.000**Ethanol Formaldehyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**

0.000 0.182 -321.312 35.370 0.588 0.589 -0.588 0.026 8.332 0.076 5583 0.000 0.002 0.901 2.839 0.560 0.226 1.467 0.000 9.632 0.013 827 0.000 0.667 90.474 86.255 28.143 13.116 164.256 0.000 57.874 21.281 47774 0.000 7.308 600.602 18.698 743.778 167.143 5.755 1184.795 0.000 0.000 0 0.000 0.000 572.381 0.000 0 208.571 0.000 0 0.000 9.597 780 0.000 8.159 370.666 143.162 773.068 181.074 170.889 1184.822 856.791 30.967 54965

**Ethanol Formaldehyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2** 0.00E+00 2.35E-01 3.70E+00 9.88E+00 1.76E+00 7.41E-01 4.64E+00 0.00E+00 1.95E+01 4.87E-01 17304 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0 0.00E+00 5.07E-03 8.52E-02 2.29E-01 4.37E-02 1.82E-02 1.19E-01 0.00E+00 4.99E-01 1.14E-02 443 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0 0.000 0.240 3.789 10.105 1.805 0.759 4.755 0.000 19.983 0.498 17747

**Ethanol Formaldehyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**

30 0.40 21.58 128.44 3.72 2.83 5.56 0.00 10.53 0.22 9186.70 0 0.00 0 0 0 0 0 0 0 0 0 0.00 0 0 0 0 0 0 0 0 30.181 0.401 21.579 128.445 3.724 2.828 5.561 0.000 10.533 0.221 9187
**Ethyl Benzene Formaldehyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2** -109.724 -1.255 07.216 0.193 0 -224.942 -2.689 0 -15.456 -0.398 0 150.963 3.184 0 -112.227 -4.026 0 -36.508 -1.479 0 108.259 1.054 0 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -232.420 -5.418 0**CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  5782 0 22689 53007 1034 1882 5014 4888 55587 90958 579955 76134 0 0 0 0 12020 4380 3755 82558 92840 607658 134028
**CO2-eq. Coal** 

**Energy NG Energy**  **Petroleum Energy**  17864 6017 11560 202623 0 0 0 0 457 145 280 5014 0 0 0 0 18321 6163 11840 207637
**CO2-eq. Coal** 

**Energy NG Energy**  **Petroleum Energy**  9477 2862 6965 106649 0 0 0 0 0 0 0 0 9477 2862 6965 106649
**CO2-eq. Coal** 

**Energy NG Energy**  **Petroleum Energy**  -2693 0 0 0211 0 0 0

-5557 0 0 0 -448 0 0 0 4157 0 0 0 -3605 0 0 0 -1225 0 0 0 2600 0 0 0 -6560 0 0 0

## Renew**able Fuel Volumes**

Sorghum Ethanol – Dry

Mill NG

Sorghum Ethanol – Dry

Mill Coal

Sorghum Ethanol – Dry

Mill Biogas**As sumptions for Crude Oil Types** 

International Crude Light Crude (Domestic) Bitumen (Canadian, Surface mining) Bitumen (Canadian, In-situ) Extra Heavy

Oil/Syncrude (Venezuelan)

Heavy Oil CA Crude Total

### - No CHP, 92% Wet DG

- Yes CHP, 92% Wet DG

- No CHP, 92% Wet DG - Yes CHP, 92% Wet DG

- No CHP, 92% Wet DG - Yes CHP, 92% Wet DGSorghum Ethanol Total = Cellulosic Ethanol Total =

Butanol Total = Biodiesel Total = Renewable Diesel Total = Imported Ethanol =

2005
Baseline Case 41.8% 30.2% 2.5% 2.0% 1.0% 22.5% 0.0% 100%International Light Crude

Domestic Light Crude Bitumen (Canadian, Surface mining) Bitumen (Canadian, In-situ) Extra Heavy

Oil/Syncrude (Venezuelan) Heavy CrudeFuels Volumes by Type Percentages Bgal 2022 2022FuelSpecific Case Control

Case Difference FuelSpecific Control 0.30 0.20 0.1 100.0% 100.0% 0.00 0.00 0.0 0.0% 0.0% 0.30 0.20 0.1 100.0% 100.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.30 0.20 0.1 100.0% 100.0% 0.00 0.00 0.0 0.0% 0.0% 0.30 0.20 0.1 100.0% 100.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.30 0.20 0.1 100.0% 100.0% 0.00 0.00 0.0 0.0% 0.0% 0.30 0.20 0.1 100.0% 100.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.00 0.00 0.0 0.0% 0.0% 0.0 0.00 0.0 0.0 **2022**0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00 0.0 0.00 0.00 0.0 0.00 0.00 0.0 0.00 0.00 0.0
0.30 0.20 0.10 16.00 16.00 0.00 0.00 0.00 0.00 1.00 1.00 0.00 0.00 0.00 0.00 3.14 3.14 0.00

2022FuelSpecific Case Control

Case Difference 41.8% 41.8% 30.2% 30.2% 2.5% 2.5% 2.0% 2.0% 1.0% 1.0% 22.5% 22.5% 0.0% 0.0% Okay OkayCanadian Oil Sands

(Surface Mining) Canadian Oil Sands (In-Situ Recovery)Venezuela

Extra Heavy Oil/Syncru de Heavy

Oil Conventio nal Light 2.5% 2.0% 1.0% 22.5% 72.0% 100.0%

41.8% 30.2% 2.5% 2.0% 1.0% 22.5% FASOM Volumes
Millions of Gallons BgalFuelSpecific Case Control

Case Difference Dry Mill Sorghum 299.7 199.8 0.10 Wet Mill Corn 0.0 Other Grain 0.0 CornRes Cell 0.0 Switchgrass Cell 0.0 Forestry Cell 0.0 Other Cell 0.0

Millions of Gallons BgalFuelSpecific Case Control

Case Difference Dry Mill SorghumEtOH 0.0 0.0 0.0 Wet Mill Corn EtOH 0.0 **2022 2022** Fuels Volumes by Type Percentages

## Ag**ricultural Inputs**

**Domestic A gricultural Inputs (from FA** **SOM)**
Calc Units Fuel-Specific Case Control Case Total N use Tons 15,058,922 15,047,165 Total P2O5 use Tons 4,346,918 4,345,398 Total K2O use Tons 5,274,466 5,269,380 Total Lime Use Tons 11,294,704 11,287,361 Herbicide Use Tons 199,968 199,863 Pesticide Use Tons 64,265 64,227 Total Diesel Fuel use gal ###################### Total Gasoline use gal 382,036,867 382,362,493 Total Electricity

Use kWh 204,637,056 204,644,331 Total Natural Gas Use Btu 6.6E+13 6.6E+13 Total Acres In Crop Production 000 Acres 310461.0868 310363.0572
Livestock # Dairy mmHead 5.756897 5.7570754 Beef mmHead 58.6350716 58.6380207 Poultry mmHead 4916.698172 4916.698172 Swine mmHead 136.5934893 136.5081788

**Non-Combustion GHG Emissions** N2O in pasture land 000 Tons 4,277 4,274 **2022**

N2O in cropped ag soil 000 Tons 3,869 3,870 C in cropped and pasture ag soil 000 tons 5,350 5,392 Domestic Ag Land Use Change 000 Tons 13,496 13,535
Methane from enteric fermentation 000 Tons 88,620 88,633 Manure N2O CH4 000 Tons 63,463 63,438 Domestic Livestock Changes000 Tons 152,083 152,070 C emissions from fertilizer production000 Tons 4,022 4,018 Agricultural residue burning and sludge000 Tons 1,028 1,027

Methane from rice cultivation000 Tons 9,362 9,358
C in continuous and afforested forest soils 000 tons 1,143 1,141 C in continuous forest above-ground biomass 000 Tons 3,861,599 3,864,907C in afforested forest above-ground biomass 000 Tons -1,511,983 -1,514,866

C from US-produced, -consumed forest products 000 tons -311,423 -311,423 C from US-produced, exported forest products 000 tons -3,500,324 -3,499,679 Cumulative Domestic Forest Land Use Change000 Tons -1,460,988 -1,459,921

C from forestry

use of fossil fuel000 Tons 597.7 604.7 Land Use Change Emission Streams - CO2 eq 2012 calc units 2012 US-produced Forest Products Fuel Specific Case 000 Tons US-produced Forest Products Control Case000 Tons Forest Soil Carbon Fuel Specific Case 000 Tons Forest Soil Carbon Control Case000 Tons C in cropped and pasture ag soil Fuel Specific Case 000 Tons C in cropped and pasture ag soil Control Case000 Tons 2017 US-produced Forest Products Fuel Specific Case 000 Tons US-produced Forest Products Control Case000 Tons Forest Soil Carbon Fuel Specific Case 000 Tons Forest Soil Carbon Control Case000 Tons C in cropped and pasture ag soil Fuel Specific Case 000 Tons C in cropped and pasture ag soil Control Case000 Tons 2022 US-produced Forest Products Fuel Specific Case 000 Tons US-produced Forest Products Control Case000 Tons Forest Soil Carbon Fuel Specific Case 000 Tons Forest Soil Carbon Control Case000 Tons C in cropped and pasture ag soil Fuel Specific Case 000 Tons C in cropped and pasture ag soil Control Case000 Tons **(Cumulative) YEA** **R: 0**  **2022** 2020 Difference US-produced Forest Products 000 Tons Annualized Difference US produced Forest Products 000 Tons Difference Forest Soil Carbon 000 Tons Annualized Difference Forest Soil Carbon 000 Tons Cumulative Domestic Forest LUC 000 Tons -1,066.65

Total Domestic Forest Land Use Change000 Tons -1,066.65 Difference C in cropped and pasture ag soil 000 TonsAnnualized Difference C cropped/pasture ag soil 000 Tons

Cumulative Domestic Ag LUC 000 Tons -42.53

Total Domestic Ag Land Use Change000 Tons -42.53 **Total Domestic Land Use Change**000 Tons **-1,109.18 Domestic Biofuel Feedstock Transport Tables**  For Domestic Use 2022 Fuel-Specific Case Control Case Sorghum Used for Ethanol bu 110590357.1 73726964.29 Soybeans / Oil Used for Fuel bu DDGS Produced tons 40007150 39693850 Cellulosic Feedstock - Farmed Trees tons - Switchgrass tons - Sorghum-SweetSorghum - Corn, Wheat, Sugar Residue tons - Forest Residue tons B&CTL Feedstock - Farmed Trees tons - Switchgrass tons - Corn Stover tons - Forest Residue tons **International A gricultural Inputs (from FA** **PRI and Foreign A g Inputs Estimates)**  2022 Fuel-Specific Case Control Case Total N use Tons Total P2O5 use Tons Total K2O use Tons Herbicide Use Tons Pesticide Use Tons N2O Emissions MT N2O Ag Energy

Use MT CO2-eq. Int'l Rice CH4 MT CH4 **Livestock Change** (From FAPRI) Canada Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head Western Europe Dairy 000 Head Beef 000 HeadSwine 000 Head

Sheep 000 Head Poultry 000 Head Eastern Europe Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head Oceania Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head Latin America Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head Asia Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head Africa and Middle East Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head India Dairy 000 Head Beef 000 Head Swine 000 Head Sheep 000 Head Poultry 000 Head **Livestock Emission Factors** Enteric Fermentation (kg CH4/head - year) Dairy Cattle North America 121 53 Western Europe 109 57 Eastern Europe 89 58Oceania 81 60

Latin America 63 56 Asia 61 47 Africa and Middle East 40 31 Indian Subcontinent 51 27 Manure Management (kg CH4/head - year) Dairy Cattle North America 78 2 Western Europe 51 15 Eastern Europe 27 13 Oceania 29 2 Latin America 1 1 Asia 18 1 Africa and Middle East 1.5 1 Indian Subcontinent 5 2 TAM (kg / head) Dairy Cattle North America 604 389 Western Europe 600 420 Eastern Europe 550 391 Oceania 500 330 Latin America 400 305 Asia 350 319 Africa and Middle East 275 173 Indian Subcontinent 275 110 N Rate (kg N / (1000 kg animal mass) - day) Dairy Cattle North America 0.44 0.31 Western Europe 0.48 0.33 Eastern Europe 0.35 0.35 Oceania 0.44 0.5 Latin America 0.48 0.36 Asia 0.47 0.34 Africa and Middle East 0.65 0.71 Indian Subcontinent 0.47 0.34 Nex (kg N / animal - year) Dairy Cattle North America 97.0024 44.01535 Western Europe 105.12 50.589 Eastern Europe 70.2625 49.95025 Oceania 80.3 60.225 Latin America 70.08 40.077 Asia 60.0425 39.5879 Africa and Middle East 65.24375 44.83295 Indian Subcontinent 47.17625 13.651 MS% Dairy Lagoon Liquid/Slurry Solid Storage North America 15.0% 27.0% 26.3% Western Europe 0.0% 35.7% 36.8% Eastern Europe 0.0% 17.5% 60.0% Oceania 16.0% 1.0% 0.0% Latin America 0.0% 1.0% 1.0%Asia 4.0% 38.0% 0.0%

Africa and Middle East 0.0% 0.5% 1.5% Indian Subcontinent 0.0% 1.0% 0.0% EF3 0 0.005 0.005 EF4 0.0035 0.004 0.003 MS% Cattle Lagoon Liquid/Slurry Solid Storage North America 0.0% 0.2% 0.0% Western Europe 0.0% 25.2% 39.0% Eastern Europe 0.0% 22.5% 44.0% Oceania 0.0% 0.0% 0.0% Latin America 0.0% 0.0% 0.0% Asia 0.0% 0.0% 0.0% Africa and Middle East 0.0% 0.0% 0.0% Indian Subcontinent 0.0% 1.0% 0.0% EF3 0 0.005 0.005 EF4 0.0035 0.004 0.0045 MS% Swine Lagoon Liquid/Slurry Solid Storage North America 32.8% 18.5% 4.2% Western Europe 8.7% 0.0% 13.7% Eastern Europe 3.0% 0.0% 42.0% Oceania 54.0% 0.0% 3.0% Latin America 0.0% 8.0% 10.0% Asia 0.0% 40.0% 0.0% Africa and Middle East 0.0% 10.0% 3.0% Indian Subcontinent 9.0% 22.0% 16.0% EF3 0 0.005 0.005 EF4 0.004 0.0048 0.0045 Weighted EF3 (kg N2O-n / kg N) Dairy Cattle North America 0.008765 0.01999 Western Europe 0.009075 0.01017 Eastern Europe 0.008175 0.008675 Oceania 0.01685 0.02 Latin America 0.0197 0.0199 Asia 0.0124 0.0198 Africa and Middle East 0.01845 0.019 Indian Subcontinent 0.01435 0.01455 Weighted EF4 (kg N2O-n / kg N) Dairy Cattle North America 0.0025984 0.0011305 Western Europe 0.002721 0.0029996 Eastern Europe 0.0026435 0.00302 Oceania 0.001188 0.000907 Latin America 0.000756 0.000693 Asia 0.002003 0.001744 Africa and Middle East 0.00066 0.0006495 Indian Subcontinent 0.000362 0.000454EF5 (kg N2O-n / kg N) Dairy Cattle

North America 0.00075 0.00075 Western Europe 0.00075 0.00075 Eastern Europe 0.00075 0.00075 Oceania 0.00075 0.00075 Latin America 0.00075 0.00075 Asia 0.00075 0.00075 Africa and Middle East 0.00075 0.00075 Indian Subcontinent 0.00075 0.00075Difference 11,757 1,520 5,086 7,343 105 38 686,517 (325,625) (7,275) 22,688,721,300
98.0296

-0.0001784 -0.0029491 4E-07 0.0853105

3 0 -43 -40
-13 25 12 -3381Less CH4 from cattle and cow fed with DGS (g CO2e/mmBtu EtOH)
0
1
4
3 -3,3072,883 0 -646 -1,067
-7

2015 2020 2025 2030 2035 2040 2045

-104 51 18 11 9 8 -104 51 18 11 9 8 18 15 24 61 93 85 18 15 24 61 93 85 1 1,424 -4 -1 0 0 1 1,424 -4 -1 0 0 **(Future Emission Stream ->) 1**  **2 3**  **4 5**  **6 7**  2025 0.00

0.00 0.00 0.01 0.00 0.00 0.00 0.00 -0.15-0.03 -0.03 -0.03 -0.03 **0.00 0.00**  **0.00 0.00**  **0.00 -0.03**  **-0.03**

Difference 3.69E+07 0 27946.36
0 Wet DGS % %transport associated with WDGS 0 92% 1% 0 0 0 0 0 0

Difference 3,519 1,877 962 10 16 98 8,740 -248

0.0 -0.2 -3.7 0.0 8.9
0.0 -0.21.0 0.2 -0.2
0.0 -3.2 0.5 0.0 79.5
-0.1 -0.1 0.0 0.1 -10.4
-0.7 3.4 0.5 0.0 0.9
-0.4 -1.1 1.5 -6.7 -97.1
-0.2 -1.0 0.7 0.0 -18.1
0.0 3.8 0.1 0.0 -60.7

Swine Sheep

1.5 8 1.5 8 1.5 81 5 1 5 1 5 1 5 1 5 Swine Sheep Poultry

23.5 0.28 0.02 15.5 0.28 0.02 6.5 0.28 0.02 18 0.15 0.02 1 0.15 0.02 4 0.15 0.02 2 0.15 0.02 4 0.15 0.02 Swine Sheep Poultry

122 48.5 0.9 124 48.5 0.9 115 48.5 0.9 112.5 28 0.9 28 28 0.9 28 28 0.9 28 28 0.9 28 28 0.9 Swine Sheep Poultry

0.5 0.42 1.1 0.68 0.85 1.1 0.74 0.9 1.1 0.73 1.13 1.1 1.64 1.17 1.1 0.5 1.17 1.1 1.64 1.17 1.1 0.5 1.17 1.1 Swine Sheep Poultry

22.265 7.43505 0.36135 30.7768 15.047125 0.36135 31.0615 15.93225 0.36135 29.975625 11.5486 0.36135 16.7608 11.9574 0.36135 5.11 11.9574 0.36135 16.7608 11.9574 0.36135 5.11 11.9574 0.36135 Drylot Pasture/Range/Paddock Daily Spread Digester Burned for Fuel Other 0.0% 10.8% 18.4% 0.0% 0.0% 2.6% 0.0% 20.0% 7.0% 0.0% 0.0% 0.5% 0.0% 18.0% 2.5% 0.0% 0.0% 2.0% 0.0% 76.0% 8.0% 0.0% 0.0% 0.0% 0.0% 36.0% 62.0% 0.0% 0.0% 0.0%0.0% 20.0% 29.0% 2.0% 7.0% 0.0% 0.0% 81.5% 3.5% 0.0% 11.5% 2.0% 0.0% 27.0% 19.0% 1.0% 51.0% 0.0% 0.02 0.02 0.02 0 0.01 0.01 0.002 0.0007 0.0007 0 0 0 Drylot Pasture/Range/Paddock Daily Spread Digester Burned for Fuel Other 18.4% 81.5% 0.0% 0.0% 0.0% 0.0% 0.0% 32.0% 1.8% 0.0% 0.0% 2.0% 0.0% 20.0% 0.0% 0.0% 0.0% 13.5% 9.0% 91.0% 0.0% 0.0% 0.0% 0.0% 0.0% 99.0% 0.0% 0.0% 0.0% 1.0% 46.0% 50.0% 2.0% 0.0% 2.0% 0.0% 1.0% 87.0% 1.5% 0.0% 10.0% 1.0% 4.0% 22.0% 20.0% 1.0% 53.0% 0.0% 0.02 0.02 0.02 0 0.01 0.01 0.003 0.0007 0.0007 0 0 0 Drylot Pit <1 month Pit .1 month Daily Spread Digester Other 4.0% 0.0% 40.6% 0.0% 0.0% 0.0% 0.0% 2.8% 69.8% 2.0% 0.0% 3.0% 0.0% 24.7% 24.7% 0.0% 0.0% 5.7% 15.0% 0.0% 0.0% 0.0% 0.0% 28.0% 41.0% 0.0% 0.0% 2.0% 0.0% 40.0% 54.0% 0.0% 0.0% 0.0% 7.0% 0.0% 78.0% 0.5% 8.5% 0.0% 0.0% 0.0% 30.0% 3.0% 0.0% 9.0% 8.0% 3.0% 0.02 0.002 0.002 0.02 0 0.01 0 0.0025 0.0025 0 0 0 Swine Sheep Poultry

0.002747 0.01 0.001 0.002837 0.01 0.001 0.003658 0.01 0.001 0.00595 0.01 0.001 0.0135 0.01 0.001 0.0128 0.01 0.001 0.01643 0.01 0.001 0.01006 0.01 0.001 Swine Sheep Poultry

0.003404 0.00200 0.00475 0.0027795 0.00200 0.00475 0.003245 0.00200 0.00475 0.002295 0.00200 0.00475 0.000834 0.00200 0.00475 0.00192 0.00200 0.00475 0.00084 0.00200 0.00475 0.002211 0.00200 0.00475Swine Sheep Poultry 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075 0.00075 0.00225 0.00075Less CH4 from cattle and cow fed with DGS (g CO2e/mmBtu EtOH)2050

7 7 153 153 0 0

**8 9**  **10 11**  **12 13**  2030 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00-0.03 -0.03 -0.03 0.00 0.00 0.00 -0.03 -0.03 -0.03 0.00 0.00 0.00 **-0.03 -0.03**  **-0.03 0.00**  **0.00 0.00** **14 15**  **16 17**  **18 19**  **20** 2035 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -0.08 0.00 0.00 -0.02 -0.02 -0.02 -0.02 -0.02 0.00 0.00 -0.02 -0.02 -0.02 -0.02 -0.02 0.000.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.00 **0.00 0.00**  **-0.02 -0.02**  **-0.02 -0.02**  **-0.02 21**  **22 23**  **24 25**  **26 27** 

2040 2045

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.02 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -0.03 0.00-0.01 -0.01 -0.01 -0.01 -0.01 0.00 0.00

-0.01 -0.01 -0.01 -0.01 -0.01 0.00 0.00 **-0.01 -0.01**  **-0.01 -0.01**  **-0.01 0.00**  **0.00**COUNTRY NPV of 30-Yr TotalIndonesia 0 0 Philippines 0 0 Malaysia 0 0**28 29**  **30**

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00

0.00 0.00 0.00 **0.00 0.00**  **0.00**0 #REF! Indonesia 0 #REF! Philippines 0 #REF! China #REF!Calculation of N2O emissions from application of manage manure to soils.

Does not include PRP or daily spread manure emissions, since these are accounted for in the original manure management methodology. **2022 Dairy** 

**Numbers Change (Head)** Lagoon Liquid/Slurry Solid Storage Drylot Pasture/Range /Paddock North America (4) (7) (7)
- (3) Western Europe
- 3 3
- 2 Eastern Europe
- (0) (0)
- (0) Oceania (19) (1)
- - (89) Latin America
- (7) (7)
- (245) Asia (16) (154)
- - (81) Africa and Middle East
- (1) (3)
- (146) Indian Subcontinent
- (0)
- - (0) **Cattle Numbers Change (Head)**Lagoon Liquid/Slurry Solid Storage Drylot Pasture/Range /Paddock North America
- (0)
- (43) (190)
Western Europe
- (44) (68)
- (56) Eastern Europe
- (730) (1,428)
- (649) Oceania
- - - (5) (52) Latin America
- - - - 3,359 Asia
- - - (490) (533) Africa and Middle East
- - - (10) (839) Indian Subcontinent
- 38
- 151 829 **Swine Numbers Change (Head)**  Lagoon Liquid/Slurry Solid Storage Drylot Pit <1 month North America (1,203) (678) (154) (147)
- Western Europe 87
- 137
- 28 Eastern Europe 15
- 213
- 125 Oceania 26
- 1 7 - Oceania Latin America
- 42 52 213
- Asia
- 596
- 804
- Africa and Middle East
- 71 21 556 4 Indian Subcontinent 5 11 8 15 2 **Dairy Nex Change (kg N)**  Lagoon Liquid/Slurry Solid Storage Drylot Pasture/Range /Paddock North America (395) (712) (693)
- (285) Western Europe
- 287 296
- 161 Eastern Europe
- (9) (31)
- (9) Oceania (1,511) (94)
- - (7,178) Latin America
- (476) (476)
- (17,135) Asia (975) (9,265)
- - (4,876) Africa and Middle East
- (58) (175)
- (9,532) Indian Subcontinent
- (1)
- - (15) % lost in Manure Management 77% 40% 40% 30% **Cattle Nex Change (kg N)** Lagoon Liquid/Slurry Solid Storage Drylot Pasture/Range /Paddock North America
- (21)
- (1,889) (8,367) Western Europe
- (2,211) (3,422)
- (2,808)Eastern Europe
- (36,487) (71,353)
- (32,433)

Oceania
- - - (311) (3,143) Latin America
- - - - 134,602 Asia
- - - (19,394) (21,081) Africa and Middle East
- - - (432) (37,596) Indian Subcontinent
- 514
- 2,058 11,317 % lost in Manure Management 40% 50% 40% **Swine Nex Change (kg N)** Lagoon Liquid/Slurry Solid Storage Drylot Pit <1 month North America (26,777) (15,103) (3,429) (3,266)
- Western Europe 2,669
- 4,203
- 859 Eastern Europe 472
- 6,613
- 3,889 Oceania 788
- 44 219
- Latin America
- 698 873 3,578
- Asia
- 3,044
- 4,109
- Africa and Middle East
- 1,194 358 9,314 60 Indian Subcontinent 24 58 42 78 8 % lost in Manure Management 78% 48% 50% 30% 25% **Manure N available for application (kg N) (not**  **including PRP and daily spread)**  Dairy Cattle Swine Sheep Poultry North America (934) (1,146) (42,604) NA 3,208 Western Europe 349 (3,038) 19,394 NA (55) Eastern Europe (24) (57,569) 9,244 NA 28,553 Oceania (404) (187) 348 NA (3,739) Latin America (571)
- 3,304 NA 311 Asia (5,895) (11,637) 4,576 NA (34,849) (5,895) (11,637) (34,849) Africa and Middle East (140) (259) 8,126 NA (6,506) Indian Subcontinent (0) 1,662 121 NA (21,781) **Change in direct N2O emissions (kg N2O)**  Dairy Cattle Swine Sheep Poultry North America (15) (18) (669) NA 50 Western Europe 5 (48) 305 NA (1) Eastern Europe (0) (905) 145 NA 449 Oceania (6) (3) 5 NA (59) Latin America (9)
- 52 NA 5 Asia (93) (183) 72 NA (548) Africa and Middle East (2) (4) 128 NA (102) Indian Subcontinent (0) 26 2 NA (342) **Change in indirect N2O emissions from volatilization**  **(kg N2O) (includes PRP and daily**  **spread)** Dairy Cattle Swine Sheep Poultry North America (5) (30) (134) NA 10 Western Europe 2 (19) 62 NA (0) Eastern Europe (0) (283) 29 NA 90 Oceania (26) (10) 1 NA (12) Latin America (128) 423 11 NA 1Asia (51) (105) 14 NA (110)

Africa and Middle East (31) (121) 26 NA (20) Indian Subcontinent (0) 66 0 NA (68) **Change in indirect N2O emissions from**  **leaching/runoff (kg N2O)** Dairy Cattle Swine Sheep Poultry North America (3) (4) (151) NA 11 Western Europe 1 (11) 69 NA (0) Eastern Europe (0) (204) 33 NA 101 Oceania (1) (1) 1 NA (13) Latin America (2)
- 12 NA 1 Asia (21) (41) 16 NA (123) Africa and Middle East (0) (1) 29 NA (23) Indian Subcontinent (0) 6 0 NA (77) **Total change in N2O emissions (kg N2O)**  Dairy Cattle Swine Sheep Poultry North America (23) (52) (954)
- 72 Western Europe 8 (77) 436
- (1) Eastern Europe (1) (1,391) 207
- 639 Oceania (33) (14) 8
- (84) Latin America (139) 423 74
- 7 Asia (165) (329) 102
- (780) Africa and Middle East (34) (126) 182
- (146) Indian Subcontinent (0) 98 3
- (488) **Total (386)**  **(1,468) 58**  **- (781)** Does not include PRP or daily spread manure emissions, since these are accounted for in the original manure management methodology.

Daily Spread Digester Burned for Fuel Other 1,000 Head (5)
- - (1) 0.01EF1 1
- - 0 1.6 convert N2O-N to N2O (0)
- - (0) 0.01 Volatilization EF [kg N2O–N/(kg NH3–N + NOX–N volatilised)] (9)
- - - 0.2 Volatilization from organic fertilizer & dung [(kg NH3–N + NOx–N)/kg N applied] (421)
- - - 0.0075 Leaching/Runoff EF (kg N20-N/kg N leaching or runoff) (118) (8) (28)
- 0.3 N losses by leaching/runoff (N losses by leaching or runoff/kg N addition) (6)
- (21) (4) (0) (0) (1)
- Daily Spread Digester Burned for Fuel Other

- - - - **TABLE 10.23 DEFAULT VALUES FOR TOTAL NITROGEN LOSS FROM MANURE MANAGEMENT** (3)
- - (3) **Animal category Manure**  **management sy**  **stem Total N loss from** 

**MMS FracLossMS**

- - - (438) Anaerobic lagoon 78%

- - - - Pit storage 25%

- - - 34 Deep bedding 50% (21)
- (21)
- Liquid/Slurry 48% (14)
- (96) (10) Solid storage 50% 754 38 1,997
- Anaerobic lagoon 77% Liquid/Slurry 40% Pit .1 month Daily

Spread Digester Other Pit storage 28% (1,489)
- - - Dry lot 30% 696 20
- 30 Solid storage 40% 125
- - 29 Daily spread 22%

- - - 14 Poultry without litter 55% Swine

Dairy Cow

- - - 14 Poultry without litter 55%

- 10
- 208 Anaerobic lagoon 77%

- - 104
- Poultry with litter 50% 61
- - - Dry lot 40%

- 5 4 2 Solid storage 50% Deep bedding 40% Daily Spread Digester Burned for Fuel Other Deep bedding 35% (485)
- - (69) Solid storage 15% 56
- - 4 From IPCC 2006 Guidelines (1)
- - (1) Lagoon Pit Storage (756)
- - - Dairy 77% 28% (29,511)
- - - Cattle (7,070) (488) (1,707)
- Swine 78% 25% (409)
- (1,345) (234) Sheep (10) (1) (28)
- Poultry 77% 22% 77% Daily Spread Digester Burned for Fuel Other

- - - - (158)
- - (175) Other Cattle Other (sheep, horses) Poultry- - - (21,892)

- - - -

- - - 1,360 (843)
- (843)
- (648)
- (4,321) (432) 10,288 514 27,264
- 22.0% 77.0%
Pit .1 month Daily

Spread Digester Other (33,145)
- - - 21,415 614
- 920 3,889
- - 897

- - - 408

- 175
- 3,491

- - 533
- 1,015
- - -

- 24 21 8 25% 22.0% 78%

Poultry Manure kg N2O-N emissions accounted for in MM calc

21 (0) 187 (24) 2 (228) (43) (143)**Total (957)**  **366 (545)**  **(123) 365**  **(1,171) (123)**  **(387) (2,576)** Volatilization EF [kg N2O–N/(kg NH3–N + NOX–N volatilised)] Volatilization from organic fertilizer & dung [(kg NH3–N + NOx–N)/kg N applied] N losses by leaching/runoff (N losses by leaching or runoff/kg N addition)

**TABLE 10.23 DEFAULT VALUES FOR TOTAL NITROGEN LOSS FROM MANURE MANAGEMENT (Range of**  **FracLossMS)** (55 – 99) (15 – 30) (10 – 60) (15 – 60) (20 – 70) (55 – 99) (15 – 45) (10 – 40) (10 – 35) (10 – 65) (15 – 60) (40 – 70) (50 – 99) (20 – 80) (20 – 50) (20 – 70) (10 – 50) (15 – 40) (5 – 20) Deep Bedding Liquid/Slurry Solid Storage Drylot Daily Spread 40% 40% 30% 22% 40% 50% 40% 50% 48% 50% 35% 15% 50%

## Emissions Factors

Fuel Heating Value Density C ratio CO2 S ratio LHV (% by wt) (ppm by wt) **Liquid Fuels: Btu/gal**  **grams/gal g/mmBtu**  Crude oil 129670 3205 0.853 76532.197 16000 Conventional gasoline 115000 2819 0.863 76791.766 25.5 Reformulated or low-sulfur gasoline 115000 2829.577335 0.840463 75066.95 25.5 CA reformulated gasoline 115000 2828.193184 0.843402 75292.659 11 U.S. conventional diesel 130000 3167 0.865 76494.013 200 CA conventional diesel 120 Diesel for non-road engines 130000 3167 0.865 76494.013 163 Low-sulfur diesel 130000 3206 0.871 77973.126 11 Petroleum naphtha 116920 2745 0.85 72440.109 1 NG-based FT naphtha 111520 2651 0.842 72656.702 0 Residual oil 140352.5222 3752 0.868 84230.418 5000 Bunker fuel for ocean tanker 140352.5222 3752 0.868 84230.418 28000 Methanol 57250 3006 0.375 71474.541 0 Ethanol 76000 2988 0.522 74497.917 0.749999881 E-Diesel Additives 116090 2819 0.863 76070.748 25.5 Liquefied petroleum gas (LPG) 84950 1923 0.82 67380.833 0 Liquefied natural gas (LNG) 74720 1621 0.75 59062.801 0 Dimethyl ether (DME) 68930 2518 0.522 69218.881 0 Dimethoxy

methane (DMM) 72200 3255 0.474 77570.888 0 Methyl ester (biodiesel, BD) 118000 3361 0.776 80233.336 0 Fischer-Tropsch diesel (FTD) 123670 3017 0.853 75538.195 0 Liquid hydrogen 30500 268 0 0 0 Liquid hy Methyl tertiary

butyl ether (MTBE) 93540 2811 0.681 74287.752 0 Ethyl tertiary

butyl ether (ETBE) 96720 2810 0.706 74456.284 0 Tertiary amyl methyl ether (TAME) 100480 2913 0.706 74297.155 0 Butane 94970 2213 0.828 70037.71 0 Isobutane 90060 2118 0.828 70685.604 0 Isobutylene 95720 2253 0.857 73222.735 0 Propane 84250 1920 0.818 67669.232 0 Natural gas liquids 83686.11202 0 Still gas (in refineries) 128590 0 **Gaseous Fuels (at 32F and 1atm): Btu/ft3**  **gms/ft3** Natural gas 983 22 0.724 58818.555 6 Gaseous hydrogen 290 2.55 0 0 Still gas (in refineries) 1458 32.8 **Solid Fuels: Btu/ton**  Coal 19546300 0.637 107318.59 11100 Bituminous coal 22460600 0.755 110694.41 11800 Coking coal 24600497.14 0.747 99994.66 11800 Farmed trees 16811000 0.517 0 Herbaceous biomass 14797554.76 0.426 0Corn stover 14075990 0.445 0

Forest residue 13243490 0.517 0
Table D-6. Fertilizer Emission Factors Fertilizer Type SCC Emission Factor (lbs NH3/Ton Nitrogen) Anhydrous Ammonia 2801700001 24 0.707 Aqua Ammonia 2801700002 24 Nitrogen Solutions 2801700003 61 Urea 2801700004 364 0.211 AmmoniumNitrate 2801700005 49 0.082 AmmoniumSulfate 2801700006 194 AmmoniumThiosulfate 2801700007 64 Other Straight Nitrogen 2801700008 61 AmmoniumPhospates 280170009 97 N-P-K 28017000010 97 Source: Asman, William, A.H., Ammonia Emissions in Europe: Updated Emission and Emission Variations, National Institute of Public Health and Environmental Protection, Biltoven, The Netherlands, May 1992. kWh/mmBtu Electricity 293.07107
E10 111100 E85 86140

Liquid Fuels: Btu/gal grams/gal Butanol 99837 3065 0.6486 Renewable Diesel 117059 2835 0.863**Fuel Production Emissions / Energy Use (Well-to-Tank): Emissions - grams per mmBtu of Fuel, Energy - Btu per mmBtu of Fuel**

S ratio SOx Actual ratio by

wt 

### Conventional Gasoline (E0) **g/mmBtu Year**  **VOC 1,3-Butadiene**  0.016 790.930824 0.0000255 1.25016522 0.0000255 1.25485604 0.000011 0.54104565 0.0002 9.74461538 17.256 0.0015 0.00012 0.000163 7.94186154 **2012** #REF! #REF! 0.000011 0.54255385 0.000001 0.04695518 **2017** #REF! #REF! 0 0 0.005 267.326867 **2022** 17.214 0.001 0.028 1497.03045 0 0 

### Reformulated Gasoline Blendstock (E0) 7.5E-07 0.05897367 **Year VOC**  **1,3-Butadiene** 0.0000255 1.23842708

0 0 0 0 17.357 0.002 0 0 **2012** 17.357 0.002 0 0 **2017** 17.357 0.002 0 0 **2022** 17.357 0.002 0 0 

### CA **Reformulated Gasoline Blendstock (E0)** 0 **Year VOC**  **1,3-Butadiene** 0 0 0 0.000006 0.26856562 16.834 0.002 0 **2012** 16.834 0.002 0.0111 1030.34313 **2017** 16.834 0.002 0.0118 953.200182 0.0118 870.285177 **2022** 16.834 0.002 0 0 

### Low**Sulfur Diesel Fuel**0 **Year VOC**  **1,3-Butadiene** 0

7.853 0.002 g NH3/ton N 44357.544 **2012** 7.829 0.002 **2017** 7.818 0.001 **2022** 7.807 0.001 

### Natural Gas (For Stationary **Combustion) Year**  **VOC 1,3-Butadiene** 

5.759 **2012** 5.759 **2017** 5.759 **2022** 5.759 

### LPG (60% NG, 40% Petroleum) **Year VOC**  **1,3-Butadiene**

10.103 **2012** 10.103 **2017** 10.103 **2022** 10.103 

### Coal (For Stationary

**Combustion) Year**  **VOC 1,3-Butadiene** 7.658 **2012** 7.658 **2017** 7.658 **2022** 7.658 

### Biomass (For Stationary **Combustion) Year**  **VOC 1,3-Butadiene** 

**2012 2017**  **2022** 

### Gasious Hy**drogen (from Natural Gas) Year**  **VOC 1,3-Butadiene** 

11.884 **2012** 11.884 **2017** 11.884 **2022** 11.884**Fuel Production Emissions / Energy Use (Well-to-Tank): Emissions - grams per mmBtu of Fuel, Energy - Btu per mmBtu of Fuel**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10**

0.00560 0.00078 0.047 0.000 0.043 14.401 49.314 11.034 #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! 0.005 0.001 0.046 0.000 0.035 14.335 48.350 10.999 

### Reformulated Gasoline Blendstock (E0) **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10**

0.007 0.001 0.047 0.000 0.052 14.778 50.443 11.262 0.007 0.001 0.047 0.000 0.052 14.778 50.443 11.262 0.007 0.001 0.047 0.000 0.052 14.778 50.443 11.262 0.007 0.001 0.047 0.000 0.052 14.778 50.443 11.262 

### CA **Reformulated Gasoline Blendstock (E0) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx**  **PM 10** 

0.007 0.001 0.047 0.000 0.052 12.793 36.961 8.712 0.007 0.001 0.047 0.000 0.052 12.793 36.961 8.712 0.007 0.001 0.047 0.000 0.052 12.793 36.961 8.712 0.007 0.001 0.047 0.000 0.052 12.793 36.961 8.712**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10**

0.006 0.001 0.028 0.000 0.042 13.283 44.672 10.221 0.005 0.001 0.028 0.000 0.038 13.232 44.171 10.199 0.005 0.001 0.028 0.000 0.036 13.217 43.891 10.190 0.004 0.001 0.028 0.000 0.034 13.207 43.560 10.180 

### Natural Gas (For Stationary **Combustion) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx**  **PM 10** 

7.859 22.431 0.861 7.859 22.431 0.861 7.859 22.431 0.861 7.859 22.431 0.861

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10**

10.796 35.410 3.253 10.796 35.410 3.253 10.796 35.410 3.253 10.796 35.410 3.253 

### Coal (For Stationary

**Combustion)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10**2.617 14.518 169.665 2.617 14.518 169.665 2.617 14.518 169.665 2.617 14.518 169.665 

### Biomass (For Stationary **Combustion)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10**



### Gasious Hy**drogen (from Natural Gas) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx**  **PM 10** 

30.095 91.569 39.999 30.095 91.569 39.999 30.095 91.569 39.999 30.095 91.569 39.999**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

4.396 24.496 0.000 108.328 0.274 16,792 19,152 41,013 90,356 #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! 4.366 24.475 0.000 108.328 0.274 16,791 19,151 40,998 90,373

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

4.428 25.252 0.000 108.951 0.282 17,411 19,786 42,119 86,376 4.428 25.252 0.000 108.951 0.282 17,411 19,786 42,119 86,376 4.428 25.252 0.000 108.951 0.282 17,411 19,786 42,119 86,376 4.428 25.252 0.000 108.951 0.282 17,411 19,786 42,119 86,376

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

3.105 21.582 0.000 104.004 0.254 15,895 18,158 40,806 77,134 3.105 21.582 0.000 104.004 0.254 15,895 18,158 40,806 77,134 3.105 21.582 0.000 104.004 0.254 15,895 18,158 40,806 77,134 3.105 21.582 0.000 104.004 0.254 15,895 18,158 40,806 77,134**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

4.060 22.408 0.000 103.538 0.243 15,044 17,294 38,148 77,766 4.041 22.386 0.000 103.539 0.243 15,044 17,294 38,135 77,782 4.032 22.385 0.000 103.539 0.243 15,044 17,293 38,132 77,784 4.023 22.385 0.000 103.538 0.243 15,044 17,293 38,132 77,784

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

0.511 11.552 196.358 0.086 5,242 9,392 2,401 64,780 0.511 11.552 0.000 196.358 0.086 5,242 9,392 2,401 64,780 0.511 11.552 0.000 196.358 0.086 5,242 9,392 2,401 64,780 0.511 11.552 0.000 196.358 0.086 5,242 9,392 2,401 64,780

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

1.480 20.643 114.820 0.157 8,938 11,398 11,073 74,494 1.480 20.643 0.000 114.820 0.157 8,938 11,398 11,073 74,494 1.480 20.643 0.000 114.820 0.157 8,938 11,398 11,073 74,494 1.480 20.643 0.000 114.820 0.157 8,938 11,398 11,073 74,494

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 42.235 7.153 119.199 0.032 1,658 4,171 3,792 1,777

42.235 7.153 0.000 119.199 0.032 1,658 4,171 3,792 1,777 42.235 7.153 0.000 119.199 0.032 1,658 4,171 3,792 1,777 42.235 7.153 0.000 119.199 0.032 1,658 4,171 3,792 1,777

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

**PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy** 

20.099 65.923 221.746 0.670 111,258 116,123 151,512 540,454 20.099 65.923 0.000 221.746 0.670 111,258 116,123 151,512 540,454 20.099 65.923 0.000 221.746 0.670 111,258 116,123 151,512 540,454 20.099 65.923 0.000 221.746 0.670 111,258 116,123 151,512 540,454**Fuel Combustion Emissions / Energy Use: Emissions - grams/mmBtu of fuel burned, Energy - Btu per mmBtu fuel burned** 

### Gasoline: Farming Tractor (E10) **Petroleum Energy**  **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein**

107,111 #REF! **2012** 432.303 2.408 2.074 0.175 #REF! **2017** 355.530 1.897 1.634 0.138 107,110 **2022** 258.219 1.271 1.095 0.093



### Diesel Fuel: Farming Tractor **Petroleum Energy**  **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein**

111,697 111,697 **2012** 42.228 0.079 2.241 0.128 111,697 **2017** 30.551 0.057 1.622 0.093 111,697 **2022** 23.024 0.043 1.222 0.070



### NG: Farm Use (engine) **Petroleum Energy**  **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein** 52.000 52.000 52.000 46.560 103,769 41.120 41.120 103,769 **2012** 41.120 41.120 103,769 **2017** 41.120 103,769 **2022** 41.120



### LPG: Commercial Boiler**Petroleum**

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  1.890 1.890 1.890 1.890 98,679 1.890 1.890 98,635 **2012** 1.890 1.890 98,635 **2017** 1.890 98,635 **2022** 1.890



### Coal: Used in Biofuel Plants (industrial boiler) **Petroleum Energy**  **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein** 3.000 3.000 3.000 2.534 4,290 2.068 2.068 4,290 **2012** 2.068 2.068 4,290 **2017** 2.068 4,290 **2022** 2.068



### Biogas: Used in Biofuel Plants (based on NG) **Petroleum Energy**  **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein** 5.341 5.341 5.341 5.341 29,588 5.341 5.341 29,588 **2012** 5.341 5.341 29,588 **2017** 5.341 29,588 **2022** 5.341

**Petroleum Energy** 14,069

14,069 14,069 14,069

**Petroleum Energy** 

**Petroleum Energy** 

23,181 23,181 23,181 23,181**Fuel Combustion Emissions / Energy Use: Emissions - grams/mmBtu of fuel burned, Energy - Btu per mmBtu fuel burned**

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx** 

15.113 4.029 11374.346 265.477 7.352 6.764 15.850 11.904 3.174 10067.232 203.886 7.487 6.888 15.879 7.977 2.127 8417.518 131.315 7.648 7.036 15.914

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx** 

0.859 4.989 211.537 468.845 35.672 34.602 0.475 0.622 3.610 130.080 305.988 21.123 20.489 0.438 0.468 2.720 58.080 159.388 7.685 7.454 0.400

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  1006.365 2000.000 7.330 7.330 1006.365 1900.000 7.330 7.330 1006.365 1800.000 7.330 7.330 674.405 1500.000 6.430 6.430 342.445 1200.000 5.530 5.530 342.445 1050.000 5.530 5.530 342.445 1050.000 5.530 5.530 0.269 342.445 1000.000 5.530 5.530 342.445 1000.000 5.530 5.530 0.269 342.445 1000.000 5.530 5.530 0.269**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 0.000 10.800 84.619 2.430 2.430 10.800 84.619 2.430 2.430 0.000 10.800 84.619 2.430 2.430 0.000

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  96.100 211.400 170.000 70.000 600.000 96.100 205.000 165.000 68.000 580.000 96.100 200.000 155.000 65.000 530.000 86.143 185.000 120.000 60.000 349.293 76.185 155.249 100.000 50.000 200.000 76.185 120.000 85.000 45.000 130.000 76.185 120.000 85.000 45.000 130.000 76.185 105.700 80.000 40.000 100.000 76.185 105.700 80.000 40.000 100.000 76.185 105.700 80.000 40.000 100.000

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100 76.800 110.000 12.661 6.331 4.100**NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  12.846 1.104 1000000 12.846 1.104 1000000 10.313 1.104 1000000 7.393 1.104 1000000 5.193 1.104 1000000 3.575 1.104 1000000 1.009 3.095 1.104 76904.180 77311.415 1000000

2.615 1.104 1000000 1.009 2.615 1.104 77039.773 77436.928 1000000 1000000 1.009 2.615 1.104 77205.465 77602.620 1000000 1.25
**NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  0.630 0.920 1000000 0.630 0.920 1000000 0.630 0.920 1000000 0.630 0.920 1000000 0.630 0.920 1000000 0.630 0.920 1000000 0.679 0.630 0.920 78902.921 79201.351 1000000

0.630 0.920 1000000 0.679 0.630 0.920 78937.361 79235.791 1000000 1000000 0.679 0.630 0.920 78959.439 79257.869 1000000 1.22
**NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  368.940 1.500 1000000 368.940 1.500 1000000 368.940 1.500 1000000 368.940 1.500 1000000 368.940 1.500 1000000 368.940 1.500 1000000 368.940 1.500 58818.555 67031.295 1000000 368.940 1.500 1000000 368.940 1.500 58818.555 67031.295 1000000 1000000 368.940 1.500 58818.555 67031.295 1000000 1.30**NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  1.080 4.860 600000 400000 1.080 4.860 600000 400000 1.080 4.860 600000 400000 1.080 4.860 600000 400000 1.080 4.860 600000 400000 1.080 4.860 600000 400000 1.080 4.860 67380.833 68910.113 600000 400000 1.080 4.860 600000 400000 1.080 4.860 67380.833 68910.113 600000 400000 600000 400000 1.080 4.860 67380.833 68910.113 600000 400000 1.19
**NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  4.000 1.000 1000000 4.000 1.000 1000000 4.000 1.000 1000000 4.000 1.000 1000000 4.000 1.000 1000000 4.000 1.000 1000000 4.000 1.000 107318.592 107712.592 1000000 4.000 1.000 1000000 4.000 1.000 107318.592 107712.592 1000000 1000000 4.000 1.000 107318.592 107712.592 1000000 1.04
**NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  1.100 1.100 1.100 1.100 1.100 1.100 1.100 1.100 1.100 1.100 364.100 1.100 1.100 1.100 1.100 364.100 1.100 1.100 1.100 1.100 364.100 1.100 1.100 364.100

### Diesel Fuel: Used at Cellulosic Ethanol Plant (average of commercial boiler, stationary **engine, and turbine) Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene**

58.003 58.003 46.746 33.731 24.316 16.725 **2012** 16.725

12.459 **2017** 12.459 **2022** 12.459 

### NG: Biofuel Plant Use (50 / 50 mix of large and small industrial boiler) **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene** 

2.700 2.700 2.700 2.344 1.987 1.987 **2012** 1.987

1.987 **2017** 1.987 **2022** 1.987

### Diesel Fuel: Used at Cellulosic Ethanol Plant (average of commercial boiler, stationary **engine, and turbine) Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3** 268.356 476.438 72.007 61.910 268.356 476.438 72.007 61.910 218.961 427.618 62.700 53.533 161.827 366.330 50.941 44.071 128.799 298.487 40.460 35.759 84.937 225.535 32.996 29.040 84.937 225.535 32.996 29.040 0.543 53.802 170.494 27.398 24.002 53.802 170.494 27.398 24.002 0.543 53.802 170.494 27.398 24.002 0.543 

### NG: Biofuel Plant Use (50 / 50 mix of large and small industrial boiler)**Ethanol Formaldehyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  41.100 65.500 3.700 3.700 41.100 65.000 3.700 3.700 41.100 61.500 3.700 3.700 31.861 53.517 3.392 3.392 22.621 43.804 3.083 3.083 22.621 38.500 3.083 3.083 22.621 38.500 3.083 3.083 0.269 22.621 36.500 3.083 3.083 22.621 36.500 3.083 3.083 0.269 22.621 36.500 3.083 3.083 0.269**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy** 1.848 1.463 1000000 1.848 1.463 1000000 1.848 1.463 1000000 1.848 1.463 1000000 1.848 1.463 492.441 1000000 1.848 1.463 1000000 1.848 1.463 77973.126 78465.567 1000000 1.848 1.463 1000000 1.848 1.463 77973.126 78465.567 1000000 1000000 1.848 1.463 77973.126 78465.567 1000000

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy** 1.100 1.100 1000000 1.100 1.100 1000000 1.100 1.100 1000000 1.100 1.100 1000000 1.100 1.100 364.100 1000000 1.100 1.100 1000000 1.100 1.100 58818.555 59182.655 1000000 1.100 1.100 1000000 1.100 1.100 58818.555 59182.655 1000000 1000000 1.100 1.100 58818.555 59182.655 1000000**Electricity Production Emissions / Energy Use: Btu or Grams per mmBtu of Electricity A vailable at User Sites (wall outlets)**  

### U.S. A **verage Electricity**

**Production Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

**2012** 18.726 0.00000 0.000 0.000 0.000 **2017** 18.726 0.00000 0.000 0.000 0.000 0.000 **2022** 18.446 0.00000 0.000 0.000 0.000**Electricity Production Emissions / Energy Use: Btu or Grams per mmBtu of Electricity A vailable at User Sites (wall outlets)** 

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

0.000 54.557 215.351 287.308 75.482 457.881 0.000 287.165 2.808 0.000 54.557 215.351 287.308 75.482 457.881 0.000 287.165 2.808 0.000 54.540 201.533 287.306 75.481 403.907 0.000 287.165 2.808**Ag ricultural Chemical Production & Transportation Emissions / Energy Use: Emissions - grams per ton of nutrient, Energy - mmBtu per ton of nutrient**  

### Ave**rage Nitrogen Fertilizer CO2**  **CO2-eq. Coal Energy**  **NG Energy Petroleum**  **Energy Year** 

212,923 219,823 1620432.854 535229.907 61871.390 **2012** 212,923 219,823 1620432.854 535229.907 61871.390 **2017** 212,923 219,824 1620432.854 535229.907 61871.390 **2022** 

### Phosphate (P2O5) Fertilizer **Year**

**2012 2017**  **2022** 

### Potash (K2O) Fertilizer **Year**

**2012 2017**  **2022** 

### Limestone (CaCO3) Fertilizer**Year**

**2012 2017**  **2022** 

### Herbicide **Year**

**2012 2017**  **2022** 

### Pesticide **Year**

**2012 2017**  **2022 Ag** **ricultural Chemical Production & Transportation Emissions / Energy Use: Emissions - grams per ton of nutrient, Energy - mmBtu per ton of nutrient** 

### Ave**rage Nitrogen Fertilizer**

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

6674.522 2789.630 0.018 0.009 6674.522 0.044 0.022 6674.522 0.044 0.022 

### Phosphate (P2O5) Fertilizer

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

406.648 318.825 0.002 0.001 406.648 0.002 0.001 406.648 0.002 0.001 

### Potash (K2O) Fertilizer

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

131.653 58.859 0.0002 0.0001 131.653 0.0005 0.0003 131.653 0.0005 0.0003 

### Limestone (CaCO3) Fertilizer**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

80.913 80.913 0.0005 0.0003 80.913 0.0005 0.0003 80.913 0.0005 0.0003 

### Herbicide **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

2783.301 1748.688 0.639 0.091 0.026 3.564 2783.301 1.017 0.145 0.042 5.672 2783.301 1.017 0.145 0.042 5.672 

### Pesticide **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

4095.883 2586.250 0.945 0.134 0.039 5.271 4095.883 1.496 0.213 0.062 8.347 4095.883 1.496 0.213 0.062 8.347**Ag ricultural Chemical Production & Transportation Emissions / Energy Use: Emissions - grams per ton of nutrient, Energy - mmBtu per ton of nutrient** 

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4** 

6288.803 3733.176 999.754 518.178 1957.503 3175.008 20.970 2726.041 2273.976 436.102 230.106 1007.003 0.000 3175.008 50.174 6288.803 3733.176 999.754 518.178 1957.503 0.000 3175.008 50.174 6288.803 3733.176 999.754 518.178 1957.503 0.000 3175.008

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4** 

1387.439 7895.807 1887.475 1158.839 70105.451 1942.027 2.056 1091.709 6206.539 1468.821 901.202 54455.110 0.000 1942.027 2.623 1387.439 7895.807 1887.475 1158.839 70105.451 0.000 1942.027 2.623 1387.439 7895.807 1887.475 1158.839 70105.451 0.000 1942.027

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4** 

470.444 2007.350 687.538 242.565 1465.740 1060.864 0.257 214.815 1103.381 137.636 57.107 423.171 0.000 1060.864 0.574 470.444 2007.350 687.538 242.565 1465.740 0.000 1060.864 0.574 470.444 2007.350 687.538 242.565 1465.740 0.000 1060.864**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4** 

287.593 915.225 653.894 218.391 1039.430 989.483 0.570 287.593 915.225 653.894 218.391 1039.430 0.000 989.483 0.570 287.593 915.225 653.894 218.391 1039.430 0.000 989.483 0.570 287.593 915.225 653.894 218.391 1039.430 0.000 989.483

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4** 

10385.543 36488.637 17937.557 8202.690 34420.298 32855.574 20.100 6582.288 23188.990 11269.596 5145.480 21979.480 0.000 32855.574 31.992 10385.543 36488.637 17937.557 8202.690 34420.298 0.000 32855.574 31.992 10385.543 36488.637 17937.557 8202.690 34420.298 0.000 32855.574

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4** 

15863.691 45885.015 20330.680 9682.709 26671.773 38665.257 29.727 10091.786 29312.653 12874.271 6113.065 17007.943 0.000 38665.257 47.079 15863.691 45885.015 20330.680 9682.709 26671.773 0.000 38665.257 47.079 15863.691 45885.015 20330.680 9682.709 26671.773 0.000 38665.257**On Farm Non-Combustion, Non-GHG Emissions** 

### Fertilizer A**pplication (g/ton applied) N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year** 

1794.159 2,668,549 3.09 44.75 1.92 1794.159 2,668,549 3,291,414 3.091 44.751 1.924 **2012** 1794.159 2,668,549 3,291,414 3.091 44.751 1.924 **2017** 1794.159 2,668,549 3,291,414 3.091 44.751 1.924 **2022** 

### Herbicide A**pplication (this table is empty since herbicides are included in Pesticide A** **pplication table below )**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG** 

**Energy Petroleum** 

**Energy Year** 

19.706 1,076,268 3.04 6.74 4.14 19.706 1,076,268 1,123,159 3.043 6.743 4.136 **2012** 19.706 1,076,268 1,123,159 3.043 6.743 4.136 **2017** 19.706 1,076,268 1,123,159 3.043 6.743 4.136 **2022** 

### Pesticide A**pplication (tons/ton applied) N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year** 

10.426 717,036 3.28 2.58 2.58 10.426 717,036 742,546 3.283 2.579 2.577 **2012** 10.426 717,036 742,546 3.283 2.579 2.577 **2017** 10.426 717,036 742,546 3.283 2.579 2.577 **2022** 

### Fugutive Dust & Crop Residue Burning (tons/1000 acres farmed)**N2O CO2**  **CO2-eq. Coal**  **Energy NG** 

**Energy Petroleum** 

**Energy Year** 

8.779 1,052,311 3.27 2.54 1.85

399,159 From Calcination 8.779 1,052,311 1,075,812 3.266 2.536 1.852 **2012** 8.779 1,052,311 1,075,812 3.266 2.536 1.852 **2017** 8.779 1,052,311 1,075,812 3.266 2.536 1.852 **2022** 

### Livestock (Beef Cattle) A**mmonia & PM (kg/Head) N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year** 

252.952 22,681,896 61.20 78.69 137.40 252.952 22,681,896 23,450,279 61.205 78.694 137.400 **2012** 252.952 22,681,896 23,450,279 61.205 78.694 137.400 **2017** 252.952 22,681,896 23,450,279 61.205 78.694 137.400 **2022** 

### Livestock (Dairy

**Cattle) A mmonia (kg/Head)**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG** 

**Energy Petroleum** 

**Energy Year** 

326.675 26,303,347 75.13 92.77 159.13 326.675 26,303,347 27,216,587 75.133 92.767 159.135 **2012** 326.675 26,303,347 27,216,587 75.133 92.767 159.135 **2017** 326.675 26,303,347 27,216,587 75.133 92.767 159.135 **2022** 

### Livestock (Sw**ine) A mmonia (kg/Head)**  **Year 2012**  **2017 2022**  

### Livestock (Poultry**) A mmonia (kg/Head)**  **Year**

**2012 2017**  **2022 On Farm Non-Combustion, Non-GHG Emissions**  

### Fertilizer A**pplication (g/ton applied)**

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**



### Herbicide A**pplication (this table is empty since herbicides are included in Pesticide A** **pplication table below )**  **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**



### Pesticide A**pplication (tons/ton applied)**

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**

0.543 0.0036 0.142
0.543 0.0036 0.142 0.543 0.0036 0.142 0.543 0.0036 0.142 

### Fugutive Dust & Crop Residue Burning (tons/1000 acres farmed)**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**

0.535 0.007 0.032 0.013 0.017 0.075
0.535 0.007 0.032 0.013 0.017 0.075 0.535 0.007 0.032 0.013 0.017 0.075 0.535 0.007 0.032 0.013 0.017 0.075 

### Livestock (Beef Cattle) A**mmonia & PM (kg/Head)**

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**



### Livestock (Dairy

**Cattle) A mmonia (kg/Head)**  **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**



### Livestock (Sw**ine) A mmonia (kg/Head)** 

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde**

### Livestock (Poultry**) A mmonia (kg/Head)** 

**VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2** 

57428.708
57428.708 57428.708 57428.708 

### Herbicide A**pplication (this table is empty since herbicides are included in Pesticide A** **pplication table below )**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**

**CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2** 

6.127 0.191 7.617 1.708 0.059 0.071
6.127 0.191 7.617 1.708 0.059 0.071 6.127 0.191 7.617 1.708 0.059 0.071 6.127 0.191 7.617 1.708 0.059 0.071

**CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**

0.888 0.089 9
0.888 0.089 9 0.888 0.089 9 0.888 0.089 9

**CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**

0.172 0.017 25
0.172 0.017 25 0.172 0.017 25 0.172 0.017 25

**CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**5
5 5 5

**CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2**

0.22
0.22 0.22 0.22**Biofuel Production Emissions / Energy Use: Btu or Grams per gal of fuel produced (combustion and non-combustion emissions) - Plant Only** 

### Corn Ethanol, Dry

**Mill NG - Base Plant (dry DDGS)**  **CO2-eq. Coal** 

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP (dry**  **DDGS) CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP and Fractionation (dry**  **DDGS) CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation and Membrane Seperation (dry**  **DDGS) CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **CO2-eq. Coal** 

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - Base Plant (w et DGS)**  **CO2-eq. Coal** 

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP (w** **et DGS) CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** **2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP and Fractionation (w** **et DGS) CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation and Membrane Seperation (w** **et DGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000**2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - Base Plant (dry DDGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP (dry**  **DDGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP and Fractionation (dry**  **DDGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation and Membrane Seperation (dry**  **DDGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - Base Plant (w et DGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP (w** **et DGS) Year**  **VOC 1,3-Butadiene** **2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP and Fractionation (w** **et DGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation and Membrane Seperation (w** **et DGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000**2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - Base Plant (dry DDGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP (dry**  **DDGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP and Fractionation (dry**  **DDGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation and Membrane Seperation (dry**  **DDGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - Base Plant (w et DGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP (w** **et DGS) Year**  **VOC 1,3-Butadiene** **2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP and Fractionation (w** **et DGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation and Membrane Seperation (w** **et DGS) Year**  **VOC 1,3-Butadiene** 

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)**  **Year VOC**  **1,3-Butadiene**

**2012** 4.000**2017** 4.000 **2022** 4.000 

### Corn Ethanol, Wet Mill NG **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Wet Mill Coal **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Corn Ethanol, Wet Mill Biomass **Year VOC**  **1,3-Butadiene**

**2012** 4.000 **2017** 4.000 **2022** 4.000 

### Cellulosic Ethanol, Enzy**matic, Sw itchgrass & Lignin** **Year VOC**  **1,3-Butadiene**

**2012** 1.120 **2017** 1.120 **2022** 1.120 

### Cellulosic Ethanol, Enzy**matic, Corn Stover & Lignin Year**  **VOC 1,3-Butadiene** 

**2012** 1.120 **2017** 1.120 **2022** 1.120 

### Cellulosic Ethanol, Enzy**matic, Forest w aste & Lignin**  **Year VOC**  **1,3-Butadiene**

**2012** 1.120 **2017** 1.120 **2022** 1.120 

### Cellulosic Ethanol, Enzy**matic, Farmed trees & Lignin Year**  **VOC 1,3-Butadiene** **2012** 1.120 **2017** 1.120 **2022** 1.120 

### Cellulosic Ethanol, Thermochemical, Sw**itchgrass Year**  **VOC 1,3-Butadiene** 

**2012** 0.000 **2017** 0.000 **2022** 0.000 

### Cellulosic Ethanol, Thermochemical, Corn Stover **Year VOC**  **1,3-Butadiene**

**2012** 0.000 **2017** 0.000 **2022** 0.000 

### Cellulosic Ethanol, Thermochemical, Forest Waste **Year VOC**  **1,3-Butadiene**

**2012** 0.000 **2017** 0.000**2022** 0.000 

### Cellulosic Ethanol, Thermochemical, Farmed trees **Year VOC**  **1,3-Butadiene**

**2012** 0.000 **2017** 0.000 **2022** 0.000 

### Bio-Butanol, Corn Fermentation **Year VOC**  **1,3-Butadiene**

**2012** 2.239 0.000 **2017** 2.239 0.000 **2022** 2.239 0.000 

### Biodiesel, Soy**bean oil Year**  **VOC 1,3-Butadiene** 

**2012** 0.000 0.000 **2017** 0.000 0.000 **2022** 0.000 0.000 

### Biodiesel, Yellow**grease/tallow Year**  **VOC 1,3-Butadiene** **2012** 0.000 0.000 **2017** 0.000 0.000 **2022** 0.000 0.000 

### Renew**able Diesel, Soy bean Oil**  **Year VOC**  **1,3-Butadiene**

**2012** 0.000 0.000 **2017** 0.000 0.000 **2022** 0.000 0.000 

### Renew**able Diesel, Yellow grease/tallow**  **Year VOC**  **1,3-Butadiene**

**2012 2017**  **2022** Biodiesel Material Use Production Emissions / Energy Use: Btu or Grams per kg Product 

### Biodiesel, Soy**bean oil Year**  **VOC 1,3-Butadiene** **2012** 0.580 0.000 **2017** 0.580 0.000 **2022** 0.580 0.000 

### Biodiesel, Yellow**grease/tallow Year**  **VOC 1,3-Butadiene** 

**2012** 0.777 0.000 **2017** 0.777 0.000 **2022** 0.777 0.000**Biofuel Production Emissions / Energy Use: Btu or Grams per gal of fuel produced (combustion and non-combustion emissions) - Plant Only** 

### Corn Ethanol, Dry

**Mill NG - Base Plant (dry DDGS)**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP and Fractionation (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation and Membrane Seperation (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - Base Plant (w et DGS)** 

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**0.233 0.010 0.008 1.655 0.040 1.900 5.500

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP and Fractionation (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation and Membrane Seperation (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill NG - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)** 

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.5000.233 0.010 0.008 1.655 0.040 1.900 5.500

0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - Base Plant (dry DDGS)**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP and Fractionation (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation and Membrane Seperation (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - Base Plant (w et DGS)** 

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**0.233 0.010 0.008 1.655 0.040 1.900 5.500

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP and Fractionation (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation and Membrane Seperation (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)** 

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.5000.233 0.010 0.008 1.655 0.040 1.900 5.500

0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - Base Plant (dry DDGS)**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP and Fractionation (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation and Membrane Seperation (dry**  **DDGS) Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - Base Plant (w et DGS)** 

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**0.233 0.010 0.008 1.655 0.040 1.900 5.500

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP and Fractionation (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation and Membrane Seperation (w** **et DGS)**

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)** 

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.5000.233 0.010 0.008 1.655 0.040 1.900 5.500

0.233 0.010 0.008 1.655 0.040 1.900 5.500

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 0.233 0.010 0.008 1.655 0.040 1.900 5.500 

### Cellulosic Ethanol, Enzy**matic, Sw itchgrass & Lignin** **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 0.000 0.000 0.233 0.010 0.008 1.655 0.040 0.000 0.000 0.233 0.010 0.008 1.655 0.040 0.000 0.000 

### Cellulosic Ethanol, Enzy**matic, Corn Stover & Lignin Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.233 0.010 0.008 1.655 0.040 0.000 0.000 0.233 0.010 0.008 1.655 0.040 0.000 0.000 0.233 0.010 0.008 1.655 0.040 0.000 0.000 

### Cellulosic Ethanol, Enzy**matic, Forest w aste & Lignin**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.233 0.010 0.008 1.655 0.040 0.000 0.000 0.233 0.010 0.008 1.655 0.040 0.000 0.000 0.233 0.010 0.008 1.655 0.040 0.000 0.000 

### Cellulosic Ethanol, Enzy**matic, Farmed trees & Lignin Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 0.282 0.009 0.009 2.376 0.046 0.000 0.000

0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000 

### Cellulosic Ethanol, Thermochemical, Sw**itchgrass Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000 

### Cellulosic Ethanol, Thermochemical, Corn Stover **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000 

### Cellulosic Ethanol, Thermochemical, Forest Waste **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.0000.282 0.009 0.009 2.376 0.046 0.000 0.000 

### Cellulosic Ethanol, Thermochemical, Farmed trees **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000 0.282 0.009 0.009 2.376 0.046 0.000 0.000

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**0.000 0.000 0.000 0.000 0.000 0.000 0.000

0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 

### Renew**able Diesel, Yellow grease/tallow**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx etaldehyde**  **Benzene Ethanol**  **Formaldehyde**

Biodiesel Material Use Production Emissions / Energy Use: Btu or Grams per kg Product

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**0.000 0.000 0.000 0.000 0.000 0.593 2.035

0.000 0.000 0.000 0.000 0.000 0.593 2.035 0.000 0.000 0.000 0.000 0.000 0.593 2.035

**Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx**

0.000 0.000 0.000 0.000 0.000 0.571 2.155 0.000 0.000 0.000 0.000 0.000 0.571 2.155 0.000 0.000 0.000 0.000 0.000 0.571 2.155**Biofuel Production Emissions / Energy Use: Btu or Grams per gal of fuel produced (combustion and non-combustion emissions) - Plant Only**

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.199 7.000 0.000 0.019 0.019 1,020 1,026 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.206 7.000 0.000 0.021 0.021 1,147 1,154 0**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!

2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 1.013 7.000 0.000 0.087 0.022 2,326 2,335 21,676

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 1.151 7.000 0.000 0.101 0.025 2,696 2,706 25,126**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0 

### Corn Ethanol, Dry

**Mill Coal - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!

2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.256 7.000 0.000 0.019 0.019 0 6 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.269 7.000 0.000 0.021 0.021 0 7 0**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (dry DDGS)**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0 

### Corn Ethanol, Dry

**Mill Biomass - w / CHP, Fractionation, Membrane Seperation, and Raw** **Starch Hy droly** **sis (w et DGS)**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF!

2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 #REF! 7.000 #REF! #REF! #REF! #REF! #REF! #REF! 2.200 0.146 7.000 0.000 0.000 0.000 0 0 0**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0

0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 00.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0 0.856 0.146 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.** 

0 0 0

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 0.285 0.265 1.081 0.000 3.331 0.008 499 572 177

0.285 0.265 1.081 0.000 3.331 0.008 499 572 177 0.285 0.265 1.081 0.000 3.331 0.008 499 572 177

**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy** 

0.259 0.241 1.886 0.000 3.135 0.008 514 582 333 0.259 0.241 1.886 0.000 3.135 0.008 514 582 333 0.259 0.241 1.886 0.000 3.135 0.008 514 582 333**Biofuel Feedstock & Co-Product Transport Emissions / Energy Use: Emissions - grams/bushel or ton, Energy - Btu per bushel or ton** 

### Corn Transport per Bushel **NG Energy**  **Petroleum**

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
0.209 0.127 0.103 0.086 #REF! #REF! **2012** 0.083 0.00005 0.0024 0.078 #REF! #REF! **2017** 0.074 0.00005 0.0021 17,341 0 **2022** 0.074 0.00005 0.0021 

### Soy**bean Transport per Bushel NG**  **Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
0.209 0.127 0.103 0.086 #REF! #REF! **2012** 0.083 0.00005 0.0024 0.078 #REF! #REF! **2017** 0.077 0.00005 0.0022 0 0 **2022** 0.074 0.00005 0.0021 

### DDGS Transport per Ton **NG Energy**  **Petroleum**

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
7.116 3.189 2.701 2.345 #REF! #REF! **2012** 2.279 0.0014 0.0656 2.181 #REF! #REF! **2017** 2.166 0.0013 0.0624 19,497 0 **2022** 2.107 0.0013 0.0607 

### Farmed Trees Transport per Ton**NG**

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
6.698 3.002 2.542 2.207 #REF! #REF! **2012** 2.145 0.0013 0.0618 2.053 #REF! #REF! **2017** 2.039 0.0012 0.0587 0 0 **2022** 1.983 0.0012 0.0571 

### Switchgrass Transport per Ton **NG Energy**  **Petroleum**

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
4.186 1.876 1.589 1.379 #REF! #REF! **2012** 1.341 0.0008 0.0386 1.283 #REF! #REF! **2017** 1.274 0.0008 0.0367 0 0 **2022** 1.239 0.0008 0.0357 

### Corn Stover Transport per Ton **NG Energy**  **Petroleum**

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
3.140 1.407 1.191 1.034 #REF! #REF! **2012** 1.006 0.0006 0.0290 0.962 #REF! #REF! **2017** 0.956 0.0006 0.0275 0 0 **2022** 0.930 0.0006 0.0268 

### Forest Residue Transport per Ton **NG Energy**  **Petroleum**

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 
11.7735.276 4.468 3.879 #REF! #REF! **2012** 3.771 0.0023 0.1086 3.608 #REF! #REF! **2017** 3.584 0.0022 0.1032 0 0 **2022** 3.486 0.0021 0.1004

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**Energy**

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**Energy**10,773 737

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**Energy**

10,927 792 10,927 792 10,927 792**Biofuel Feedstock & Co-Product Transport Emissions / Energy Use: Emissions - grams/bushel or ton, Energy - Btu per bushel or ton**

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
0.925 2.039 0.078 0.052 0.445 1.350 0.084 0.056 0.304 0.982 0.067 0.039 0.172 0.548 0.052 0.026 0.0003 0.0009 0.0000 0.0065 0.150 0.464 0.049 0.024 0.117 0.339 0.045 0.020 0.0003 0.0008 0.0000 0.0058 0.112 0.320 0.045 0.020 0.0003 0.0008 0.0000 0.0058 0.091 0.244 0.043 0.018

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
0.925 2.039 0.078 0.052 0.445 1.350 0.084 0.056 0.304 0.982 0.067 0.039 0.172 0.548 0.052 0.026 0.0003 0.0009 0.0000 0.0065 0.150 0.464 0.049 0.024 0.117 0.339 0.045 0.020 0.0003 0.0008 0.0000 0.0061 0.112 0.320 0.045 0.020 0.0003 0.0008 0.0000 0.0058 0.091 0.244 0.043 0.018

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
33.877 71.849 2.627 1.758 11.289 31.808 2.387 1.474 7.682 23.623 1.969 1.071 4.531 13.850 1.616 0.762 0.0080 0.0239 0.0000 0.1782 4.044 12.028 1.555 0.709 3.313 9.294 1.463 0.629 0.0076 0.0227 0.0000 0.1694 3.204 8.925 1.455 0.621 0.0074 0.0221 0.0000 0.1648 2.771 7.449 1.422 0.591**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
31.884 67.623 2.473 1.655 10.625 29.937 2.247 1.388 7.230 22.233 1.853 1.008 4.264 13.036 1.521 0.717 0.0075 0.0225 0.0000 0.1678 3.806 11.320 1.464 0.667 3.118 8.747 1.377 0.592 0.0071 0.0214 0.0000 0.1594 3.016 8.400 1.369 0.585 0.0069 0.0208 0.0000 0.1551 2.608 7.010 1.339 0.556

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
19.928 42.264 1.545 1.034 6.641 18.711 1.404 0.867 4.519 13.896 1.158 0.630 2.665 8.147 0.951 0.448 0.0047 0.0141 0.0000 0.1048 2.379 7.075 0.915 0.417 1.949 5.467 0.861 0.370 0.0045 0.0134 0.0000 0.0996 1.885 5.250 0.856 0.365 0.0043 0.0130 0.0000 0.0969 1.630 4.382 0.837 0.348

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
14.946 31.698 1.159 0.776 4.980 14.033 1.053 0.650 3.389 10.422 0.869 0.472 1.999 6.110 0.713 0.336 0.0035 0.0106 0.0000 0.0786 1.784 5.306 0.686 0.313 1.461 4.100 0.646 0.277 0.0033 0.0100 0.0000 0.0747 1.414 3.937 0.642 0.274 0.0033 0.0098 0.0000 0.0727 1.222 3.286 0.628 0.261

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**
56.047 118.868 4.347 2.90918.676 52.623 3.950 2.439 12.709 39.082 3.258 1.772 7.496 22.914 2.674 1.261 0.0132 0.0396 0.0000 0.2949 6.690 19.899 2.573 1.173 5.480 15.376 2.421 1.040 0.0125 0.0376 0.0000 0.2803 5.301 14.766 2.407 1.028 0.0122 0.0366 0.0000 0.2726 4.584 12.323 2.353 0.978**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
0.146 0.529 0.013 466 481 163.232 313.600 5497 0.131 0.526 0.013 466 0.120 0.529 0.013 469 485 163.232 313.600 5497 0.115 0.529 0.013 469 0.115 0.000 0.529 0.013 469 485 163.232 313.600 5497 0.114 0.529 0.013 469 0.114 0.000 0.529 0.013 469 485 163.232 313.600 5497 0.114 0.000 0.529 0.013 469 485 163.232 313.600 5497

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
0.146 0.529 0.013 466 0.131 0.526 0.013 466 0.120 0.529 0.013 469 485 163.232 313.600 5497 0.115 0.529 0.013 469 0.115 0.000 0.529 0.013 469 485 163.232 313.600 5497 0.114 0.529 0.013 469 0.114 0.000 0.529 0.013 469 485 163.232 313.600 5497 0.114 0.000 0.529 0.013 469 485 163.232 313.600 5497

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
4.939 17.872 0.407 15,738 4.423 17.765 0.407 15,774 4.060 17.860 0.409 15,867 16,369 5204.562 10021.102 179401 3.880 17.857 0.409 15,869 3.873 0.000 17.856 0.409 15866.797 16,369 5204.562 10021.102 179401 3.864 17.854 0.409 15,863 3.864 0.000 17.853 0.409 15863.355 16,369 5204.562 10021.102 179401 3.864 0.000 17.852 0.409 15,864 16,369 5204.562 10021.102 179401**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
4.649 16.820 0.383 14,812 4.162 16.720 0.383 14,846 3.821 16.809 0.385 14,934 15,406 5191.643 9974.148 174821 3.651 16.807 0.385 14,936 3.645 0.000 16.806 0.385 14933.456 15,406 5191.643 9974.148 174821 3.637 16.803 0.385 14,930 3.637 0.000 16.803 0.385 14930.216 15,402 5191.643 9974.148 174821 3.637 0.000 16.802 0.385 14,931 15,403 5191.643 9974.148 174821

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
2.906 10.513 0.239 9,257 2.601 10.450 0.239 9,279 2.388 10.506 0.241 9,334 9,629 3244.777 6233.843 109263 2.282 10.504 0.241 9,335 2.278 0.000 10.503 0.241 9333.410 9,629 3244.777 6233.843 109263 2.273 10.502 0.241 9,331 2.273 0.000 10.502 0.241 9331.385 9,627 3244.777 6233.843 109263 2.273 0.000 10.501 0.241 9,332 9,627 3244.777 6233.843 109263

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
2.179 7.885 0.179 6,943 1.951 7.837 0.179 6,959 1.791 7.879 0.180 7,000 7,222 2433.583 4675 81947.284 1.712 7.878 0.180 7,001 1.709 0.000 7.878 0.180 7000.058 7,221 2433.583 4675 81947.284 1.705 7.877 0.180 6,998 1.705 0.000 7.876 0.180 6998.539 7,220 2433.583 4675 81947.284 1.705 0.000 7.876 0.180 6,999 7,220 2433.583 4675 81947.284

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**
8.172 29.567 0.673 26,0377.317 29.390 0.673 26,096

6.716 29.548 0.677 26,251 27,081 9125.935 17533 307302 6.418 29.543 0.677 26,254 6.408 0.000 29.541 0.677 26250.216 27,080 9125.935 17533 307302 6.393 29.537 0.677 26,244 6.393 0.000 29.537 0.677 26244.521 27,075 9125.935 17533 307302 6.393 0.000 29.534 0.677 26,246 27,076 9125.935 17533 307302**International Sugarcane Ethanol Production Emissions / Energy Use: Emissions - grams/mmBtu, Energy - Btu per mmBtu** 

### Sugarcane Production & Transport per mmBtu Fuel **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol**

733.115 **2012** 733.115 0.000 0.000 0.000 0.000 0.000 **2017** 733.115 0.000 0.000 0.000 0.000 0.000 **2022** 733.115 0.000 0.000 0.000 0.000 0.000 

### Sugarcane Ethanol Production & Transport to the U.S. per mmBtu Fuel **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol**

57.395 **2012** 57.395 0.000 0.000 0.000 0.000 0.000 **2017** 57.395 0.000 0.000 0.000 0.000 0.000 **2022** 57.395 0.000 0.000 0.000 0.000 0.000**International Sugarcane Ethanol Production Emissions / Energy Use: Emissions - grams/mmBtu, Energy - Btu per mmBtu**

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

9570.472 300.632 814.060 407.044 51.560 292.337 20.535 0.000 9570.472 300.632 814.060 407.044 51.560 0.000 292.337 20.535 0.000 9570.472 300.632 814.060 407.044 51.560 0.000 292.337 20.535 0.000 9570.472 300.632 814.060 407.044 51.560 0.000 292.337 20.535

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

94.164 142.507 107.537 50.508 35.271 37.851 4.661 0.000 94.164 142.507 107.537 50.508 35.271 0.000 37.851 4.661 0.000 94.164 142.507 107.537 50.508 35.271 0.000 37.851 4.661 0.000 94.164 142.507 107.537 50.508 35.271 0.000 37.851 4.661**CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 

8,182 20,687 13,063 43,248 46,981 8,182 20,687 13,063 43,248 46,981 8,182 20,687 13,063 43,248 46,981 8,182 20,687 13,063 43,248 46,981

**CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 

2,696 4,936 29,247 -28,877 34,864 2,696 4,936 29,247 -28,877 34,864 2,696 4,936 29,247 -28,877 34,864 2,696 4,936 29,247 -28,877 34,864

### Fuel Transportation, Distribution, and Storage Emissions **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO NOx** 

10.440 0.00011 0.00577 0.00075 0.0204 0.0000 0.0410 0.863 4.778 10.426 0.00010 0.00541 0.00070 0.0203 0.0000 0.0385 0.807 4.373 10.410 0.768 4.044 **2012** 10.404 0.00009 0.00486 0.00063 0.0201 0.0000 0.0346 0.761 3.931

10.396 0.750 3.761 **2017** 10.393 0.00008 0.00459 0.00059 0.0200 0.0000 0.0326 0.748 3.691 **2022** 10.384 0.00008 0.00434 0.00056 0.0199 0.0000 0.0309 0.741 3.409

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Petro Fuel Prod EF page 1 of 2 printed 6/4/2012 2:08 PM**PM 10**  **PM 2.5**  **SOx NH3**  **CH4 N2O** 

0.253 0.194 0.985 0.665 0.012 0.236 0.178 0.907 0.668 0.012 0.221 0.165 0.887 0.669 0.012 0.217 0.162 0.887 0.000 0.669 0.012 0.211 0.157 0.886 0.668 0.012 0.209 0.155 0.886 0.000 0.668 0.012 0.201 0.148 0.886 0.668 0.012

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Petro Fuel Prod EF page 2 of 2 printed 6/4/2012 2:08 PM

## International Petroluem Fuel Production Emissions Factors

**Crude Oil Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel** 

### International Conventional Crude Oil Production and Transport to International Refineries **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol**

3.766 **2012** 3.766 0.000 0.000 0.000 0.000 0.000 **2017** 3.766 0.000 0.000 0.000 0.000 0.000 **2022** 3.766 0.000 0.000 0.000 0.000 0.000**Crude Oil Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel** 

### International Conventional Crude Oil Production and Transport to International Refineries **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

7.861 32.482 2.141 1.045 12.821 91.461 0.081 0.000 7.861 32.482 2.141 1.045 12.821 0.000 91.461 0.081 0.000 7.861 32.482 2.141 1.045 12.821 0.000 91.461 0.081 0.000 7.861 32.482 2.141 1.045 12.821 0.000 91.461 0.081**Conventional Gasoline Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel** 

### Refinery **Energy Use Upstream Emissions**  **CO2 CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC**

4,117 6,063 7,132 17,607 15,575 0.602 4,117 6,063 7,132 17,607 15,575 **2012** 0.602 4,117 6,063 7,132 17,607 15,575 **2017** 0.602 4,117 6,063 7,132 17,607 15,575 **2022** 0.602 

### Refinery **On-Site Emissions Year**  **VOC**

2.560 **2012** 2.560 **2017** 2.560 **2022** 2.560 

### Fuel Transportation, Distribution, and Storage Emissions **Year VOC** 

42.600 **2012** 42.600 **2017** 42.600 **2022** 42.600

### Total Well-to-Tank Emissions **Year VOC** 

49.527 **2012** 49.527 **2017** 49.527 **2022** 49.527 Assumptions: International Crude Domestic Crude Tar Sand CA Crude**Conventional Gasoline Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel** 

### Refinery **Energy Use Upstream Emissions**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO**

0.872 0.000 0.000 0.000 0.000 0.000 0.000 0.872 0.000 0.000 0.000 0.000 0.000 0.000 0.872 0.000 0.000 0.000 0.000 0.000 0.000 0.872 

### Refinery **On-Site Emissions**

**1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO**

0.001 0.000 0.000 0.026 0.000 0.004 5.475 0.001 0.000 0.000 0.026 0.000 0.004 5.475 0.001 0.000 0.000 0.026 0.000 0.004 5.475 0.001 0.000 0.000 0.026 0.000 0.004 5.475 

### Fuel Transportation, Distribution, and Storage Emissions **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO**

0.139 1.110 0.000 0.000 0.000 0.078 0.000 0.000 1.110 0.000 0.000 0.000 0.078 0.000 0.000 1.110 0.000 0.000 0.000 0.078 0.000 0.000 1.110

### Total Well-to-Tank Emissions

**1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO**

0.001 0.000 0.000 0.026 0.000 0.004 15.318 0.001 0.000 0.000 0.105 0.000 0.004 15.318 0.001 0.000 0.000 0.105 0.000 0.004 15.318 0.001 0.000 0.000 0.105 0.000 0.004 15.318
100.0% 0.0% 0.0% 0.0%**Conventional Gasoline Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel**

**NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2**  **CO2-eq.**

3.155 5.547 1.427 4.245 14.521 0.026 1,767 2,080 3.155 5.547 1.427 4.245 0.000 14.521 0.026 1,767 2,080 3.155 5.547 1.427 4.245 0.000 14.521 0.026 1,767 2,080 3.155 5.547 1.427 4.245 0.000 14.521 0.026 1,767 2,080

**NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2**  **CO2-eq.**

14.038 3.065 1.770 9.677 0.347 0.179 11,639 11,702 14.038 3.065 1.770 9.677 0.000 0.347 0.179 11,639 11,702 14.038 3.065 1.770 9.677 0.000 0.347 0.179 11,639 11,702 14.038 3.065 1.770 9.677 0.000 0.347 0.179 11,639 11,702

**NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2**  **CO2-eq.**

5.274 0.180 0.112 1.359 0.670 0.011 540 557 5.274 0.180 0.112 1.359 0.000 0.670 0.011 540 557 5.274 0.180 0.112 1.359 0.000 0.670 0.011 540 557 5.274 0.180 0.112 1.359 0.000 0.670 0.011 540 557**NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2**  **CO2-eq.**

54.949 10.933 4.354 28.102 0.000 106.999 0.297 18,063 20,402 54.949 10.933 4.354 28.102 0.000 106.999 0.297 18,063 20,402 54.949 10.933 4.354 28.102 0.000 106.999 0.297 18,063 20,402 54.949 10.933 4.354 28.102 0.000 106.999 0.297 18,063 20,402**RFG Blendstock Gasoline Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel** 

### Refinery **Energy Use Upstream Emissions**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 

0.627 0 0 0 **2012** 0.627 0.000 0.000 0 0 0 **2017** 0.627 0.000 0.000 0 0 0 **2022** 0.627 0.000 0.000 

### Refinery **On-Site Emissions Coal**  **Energy NG** 

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 

32,665 57,288 88,809 2.584 0.001 0.000 32,665 57,288 88,809 **2012** 2.584 0.001 0.000 32,665 57,288 88,809 **2017** 2.584 0.001 0.000 32,665 57,288 88,809 **2022** 2.584 0.001 0.000 

### Fuel Transportation, Distribution, and Storage Emissions **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 

313 805 5,671 42.600 313 805 5,671 **2012** 42.600 0.000 0.000 313 805 5,671 **2017** 42.600 0.000 0.000 313 805 5,671 **2022** 42.600 0.000 0.000

### Total Well-to-Tank Emissions

**Coal Energy**  **NG**

**Energy Petroleum** 

**Energy Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde** 

40,109 75,700 110,055 49.576 0.001 0.000 40,109 75,700 110,055 **2012** 49.576 0.001 0.000 40,109 75,700 110,055 **2017** 49.576 0.001 0.000 40,109 75,700 110,055 **2022** 49.576 0.001 0.000 Assumptions: International Crude 100.0% Domestic Crude 0.0% Tar Sand 0.0% CA Crude 0.0%**RFG Blendstock Gasoline Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel**

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**

0.908 3.286 5.778 1.486 0.000 0.000 0.000 0.000 0.908 3.286 5.778 1.486 0.000 0.000 0.000 0.000 0.908 3.286 5.778 1.486 0.000 0.000 0.000 0.000 0.908 3.286 5.778 1.486

**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**

0.000 0.026 0.000 0.004 5.662 14.575 3.181 1.838 0.000 0.026 0.000 0.004 5.662 14.575 3.181 1.838 0.000 0.026 0.000 0.004 5.662 14.575 3.181 1.838 0.000 0.026 0.000 0.004 5.662 14.575 3.181 1.838 

### Fuel Transportation, Distribution, and Storage Emissions **Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**

0.139 1.138 5.410 0.185 0.115 0.000 0.078 0.000 0.000 1.138 5.410 0.185 0.115 0.000 0.078 0.000 0.000 1.138 5.410 0.185 0.115 0.000 0.078 0.000 0.000 1.138 5.410 0.185 0.115**Ac rolein**  **Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5**

0.000 0.026 0.000 0.004 15.570 55.753 11.286 4.484 0.000 0.105 0.000 0.004 15.570 55.753 11.286 4.484 0.000 0.105 0.000 0.004 15.570 55.753 11.286 4.484 0.000 0.105 0.000 0.004 15.570 55.753 11.286 4.484**RFG Blendstock Gasoline Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel**

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy**

4.422 15.127 0.027 1,841 2,167 4.422 0.000 15.127 0.027 1,841 2,167 0 0 0 4.422 0.000 15.127 0.027 1,841 2,167 0 0 0 4.422 0.000 15.127 0.027 1,841 2,167 0 0 0

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy**

9.922 0.361 0.187 12,117 12,183 34,029 59,680 92,517 9.922 0.000 0.361 0.187 12,117 12,183 34,029 59,680 92,517 9.922 0.000 0.361 0.187 12,117 12,183 34,029 59,680 92,517 9.922 0.000 0.361 0.187 12,117 12,183 34,029 59,680 92,517

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy**

1.394 0.688 0.012 553 571 321 826 5,776 1.394 0.000 0.688 0.012 553 571 321 826 5,776 1.394 0.000 0.688 0.012 553 571 321 826 5,776 1.394 0.000 0.688 0.012 553 571 321 826 5,776**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy**

28.560 0.000 107.637 0.306 18,628 20,984 41,481 78,113 113,868 28.560 0.000 107.637 0.306 18,628 20,984 41,481 78,113 113,868 28.560 0.000 107.637 0.306 18,628 20,984 41,481 78,113 113,868 28.560 0.000 107.637 0.306 18,628 20,984 41,481 78,113 113,868**Low Sulfur Diesel Fuel Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel**



### Refinery **Energy Use Upstream Emissions**  **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol**

0.552 **2012** 0.552 0.000 0.000 0.000 0.000 0.000 **2017** 0.552 0.000 0.000 0.000 0.000 0.000 **2022** 0.552 0.000 0.000 0.000 0.000 0.000 

### Refinery **On-Site Emissions Year**  **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Ethanol** 

2.511 0.001 0.000 0.000 0.026 0.000 **2012** 2.511 0.001 0.000 0.000 0.026 0.000 **2017** 2.511 0.001 0.000 0.000 0.026 0.000 **2022** 2.511 0.001 0.000 0.000 0.026 0.000 

### Fuel Transportation, Distribution, and Storage Emissions **Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol**

0.139 1.350 **2012** 1.350 0.000 0.000 0.000 0.078 0.000 **2017** 1.350 0.000 0.000 0.000 0.078 0.000 **2022** 1.350 0.000 0.000 0.000 0.078 0.000

### Total Well-to-Tank Emissions

**Year VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol**

8.178 0.001 0.000 0.000 0.026 0.000 **2012** 8.178 0.001 0.000 0.000 0.105 0.000 **2017** 8.178 0.001 0.000 0.000 0.105 0.000 **2022** 8.178 0.001 0.000 0.000 0.105 0.000 Assumptions: International Crude 100.0% Domestic Crude 0.0% Tar Sand 0.0% CA Crude 0.0%**Low Sulfur Diesel Fuel Production Emissions / Energy Use: Emissions - grams per mmBtu of Finished Fuel, Energy - Btu per mmBtu of Finished Fuel**

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

0.799 2.893 5.087 1.308 3.893 13.319 0.024 0.000 0.799 2.893 5.087 1.308 3.893 0.000 13.319 0.024 0.000 0.799 2.893 5.087 1.308 3.893 0.000 13.319 0.024 0.000 0.799 2.893 5.087 1.308 3.893 0.000 13.319 0.024

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

0.004 5.103 12.972 2.834 1.635 9.187 0.318 0.164 0.004 5.103 12.972 2.834 1.635 9.187 0.000 0.318 0.164 0.004 5.103 12.972 2.834 1.635 9.187 0.000 0.318 0.164 0.004 5.103 12.972 2.834 1.635 9.187 0.000 0.318 0.164

**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

1.090 5.202 0.178 0.109 1.195 0.692 0.012 0.000 1.090 5.202 0.178 0.109 1.195 0.000 0.692 0.012 0.000 1.090 5.202 0.178 0.109 1.195 0.000 0.692 0.012 0.000 1.090 5.202 0.178 0.109 1.195 0.000 0.692 0.012**Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O**

0.004 14.854 53.549 10.240 4.097 27.097 0.000 105.789 0.281 0.004 14.854 53.549 10.240 4.097 27.097 0.000 105.789 0.281 0.004 14.854 53.549 10.240 4.097 27.097 0.000 105.789 0.281 0.004 14.854 53.549 10.240 4.097 27.097 0.000 105.789 0.281**CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy**

1,621 1,908 1,621 1,908 0 0 0 1,621 1,908 0 0 0 1,621 1,908 0 0 0

**CO2 CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy**

10,688 10,746 29,960 52,544 81,455 10,688 10,746 29,960 52,544 81,455 10,688 10,746 29,960 52,544 81,455 10,688 10,746 29,960 52,544 81,455

**CO2 CO2-eq.**  **Coal**

**Energy NG** 

**Energy Petroleum** 

**Energy**

498 516 323 832 5,055 498 516 323 832 5,055 498 516 323 832 5,055 498 516 323 832 5,055**CO2 CO2-eq.**  **Coal Energy**  **NG**

**Energy Petroleum** 

**Energy**

16,924 19,233 37,415 70,983 102,085 16,924 19,233 37,415 70,983 102,085 16,924 19,233 37,415 70,983 102,085 16,924 19,233 37,415 70,983 102,085

## Domestic A**gricultural Changes**

**2022 Emissions (tons, or tonnes for GHG) & Energy (mmBtu) Deltas (Control Case minus Fuel-Specific Case)** On-Farm Combustion Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Diesel fuel 2.260 0.004 0.120 0.007 0.046 Gasoline -10.294 -0.051 -0.044 -0.004 -0.318 Natural Gas 1.026 0.000 0.000 0.000 0.000 **Total** -7.007 -0.046 0.076 0.003 -0.272 Fuel Production Upstream Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Diesel fuel 0.766 0.000 0.000 0.000 0.003 Gasoline -0.709 0.000 0.000 0.000 -0.002 Natural Gas 0.144 0.000 0.000 0.000 0.000 Electricity -0.001 0.000 0.000 0.000 0.000 **Total** 0.201 0.000 0.000 0.000 0.001 Farm Chemical Production / Transport Upstream Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Nitrogen as N 86.321 0.000 0.001 0.000 0.000 Phosphorous as P2O 0.680 0.000 0.000 0.000 0.000 Potasium as K2O 0.736 0.000 0.000 0.000 0.000 Limestone as CaCO3 0.654 0.000 0.000 0.000 0.000 Herbicide 0.322 0.000 0.000 0.000 0.001 Pesticide 0.171 0.000 0.000 0.000 0.000 **Total** 88.885 0.000 0.001 0.000 0.001 On-Farm Non-Combustion Non-GHG Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Fugutive Dust & Field Burning 52.462 0.719 3.179 1.264 1.642 Herbicide Application Pesticide Application 77.899 0.000 0.000 0.514 20.370 Fertilizer App NH3 0.000 0.000 0.000 0.000 0.000 Livestock PM & NH3 **Total** 130.361 0.719 3.179 1.778 22.013 On-Farm Non-combustion GHG Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  Land Use Change Livestock Changes Fertilizer Application Residue Burning Rice Cultivation **Total** 0.000 0.000 0.000 0.000 0.000 Total Domestic Agricultural Sector Emissions **VOC 1,3-Butadiene**  **Ac etaldehyde**  **Ac rolein**  **Benzene Total**  212.439 0.673 3.256 1.782 21.742
EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 1 of 17 printed 6/4/2012 2:08 PM**2022**

Total Domestic Land Use Change **YEA R:**  **0 1**  **2 3**  **Tons CO2 for total cumulative gals EtOH**  -1,109,180.10

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 2 of 17 printed 6/4/2012 2:08 PM**Ethanol Formaldehyde**  **CO NOx**  **PM10 PM2.5**  **SOx NH3** 

0.000 0.267 5.702 15.647 0.754 0.732 0.039 0.067 0.000 -0.085 -335.560 -5.235 -0.305 -0.280 -0.634 -0.040 0.000 0.000 8.547 24.958 0.138 0.138 0.007 0.000 0.000 0.182 -321.312 35.370 0.588 0.589 -0.588 0.026

**Ethanol Formaldehyde**  **CO NOx**  **PM10 PM2.5**  **SOx NH3**  0.000 0.003 1.297 4.276 0.999 0.395 2.198 0.000 0.000 -0.001 -0.590 -1.992 -0.453 -0.180 -1.008 0.000 0.000 0.000 0.196 0.560 0.021 0.013 0.288 0.000 0.000 0.000 -0.001 -0.006 -0.008 -0.002 -0.011 0.000 0.000 0.002 0.901 2.839 0.560 0.226 1.467 0.000

**Ethanol Formaldehyde**  **CO NOx**  **PM10 PM2.5**  **SOx NH3**  0.000 0.649 81.332 48.281 12.930 6.702 25.32 0.000 0.000 0.004 2.320 13.204 3.156 1.938 117.24 0.000 0.000 0.003 2.632 11.230 3.846 1.357 8.20 0.000 0.000 0.005 2.323 7.393 5.282 1.764 8.40 0.000 0.000 0.004 1.203 4.228 2.078 0.950 3.99 0.000 0.000 0.002 0.664 1.920 0.851 0.405 1.12 0.000 0.000 0.667 90.474 86.255 28.143 13.116 164.26 0.000

**Ethanol Formaldehyde**  **CO NOx**  **PM10 PM2.5**  **SOx NH3**  0.000 7.308 600.60 18.698 746.691 167.43 5.755 6.973 0.000 0.000 0.00 0.000 0.000 0.00 0.000 0.000 0.000 0.000 0.00 0.000 0.000 0.00 0.000 742.717 -2.914 -0.291 435.106 0.000 7.308 600.60 18.698 743.778 167.14 5.755 1184.795

**Ethanol Formaldehyde**  **CO NOx**  **PM10 PM2.5**  **SOx NH3** 

0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Ethanol Formaldehyde**  **CO NOx**  **PM10 PM2.5**  **SOx NH3**  0.000 8.159 370.666 143.162 773.068 181.074 170.889 1184.822
EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 3 of 17 printed 6/4/2012 2:08 PM**4 5**  **6 7**  **8 9**  **10 11**  -28.62 -28.62 -28.62 -28.62 -28.62 -0.81

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 4 of 17 printed 6/4/2012 2:08 PM**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy** 0.056 0.082 7,047 7,074 0 0 89,247 -0.095 -0.040 -2,798 -2,812 0 0 -36,240 8.371 0.034 1,335 1,521 0 22,689 0 8.332 0.076 5,583 5,782 0 22,689 53,007

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy** 9.241 0.022 1,343 1,543 3,403 6,942 8,803 -4.057 -0.010 -629 -717 -1,535 -3,384 -4,011 4.455 0.002 119 213 54 1,470 97 -0.007 0.000 -5 -5 -40 -13 -2 9.632 0.013 827 1,034 1,882 5,014 4,888

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy** 37.329 21.094 31,374 38,698 36,345 526,144 22,617 2.952 0.030 1,636 1,708 4,626 10,252 6,288 5.395 0.053 3,647 3,776 16,697 13,117 13,105 7.266 0.064 7,727 7,900 23,985 18,624 13,597 3.461 0.027 2,389 2,470 6,447 8,289 14,472 1.471 0.012 1,001 1,035 2,858 3,529 6,054 57.874 21.281 47,774 55,587 90,958 579,955 76,134

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy**

0 0 0 0.000 0.000 0 0 0 0 0

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy** 572.381 12,020

9.597 2,975

780 780 208.571 4,380 780.952 9.597 780 20,155 0 0 0

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy**  **NG Energy Petroleum**  **Energy** 856.791 30.967 54,965 82,558 92,840 607,658 134,028
EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 5 of 17 printed 6/4/2012 2:08 PM**12 13**  **14 15**  **16 17**  **18 19** 

-0.81 -0.81 -0.81 -0.81 -16.92 -16.92 -16.92 -16.92

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 6 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 7 of 17 printed 6/4/2012 2:08 PM**20 21**  **22 23**  **24 25**  **26** -16.92 -5.81 -5.81 -5.81 -5.81 -5.81 3.53

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 8 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 9 of 17 printed 6/4/2012 2:08 PM**27 28**  **29 30** 

3.53 3.53 3.53 3.53

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 10 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 11 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 12 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 13 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 14 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 15 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 16 of 17 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Domestic Ag Change page 17 of 17 printed 6/4/2012 2:08 PM

## Domestic Biofuel Feedstock Transport Changes **2022 Emissions (tons, or tonnes for GHG) & Energy (mmBtu) Deltas (Conrol minus Fuel-Specific Case)**
**Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein Benzene**  **Ethanol Formaldehyde**  **CO** Corn Used for Ethanol 3.01E+00 1.83E-03 8.66E-02 1.05E-02 3.16E-02 0.00E+00 2.35E-01 3.70E+00 Soybeans / Oil Used for Fuel 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 DDGS Produced 6.48E-02 3.95E-05 1.87E-03 2.27E-04 6.80E-04 0.00E+00 5.07E-03 8.52E-02 Cellulosic Feedstock 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 B&CTL Feedstock 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 **Total** 3.070 0.002 0.088 0.011 0.032 0.000 0.240 3.789

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Feed Trans Change page 1 of 2 printed 6/4/2012 2:08 PM**NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2**  **CO2-eq. Coal**  **Energy NG Energy**  **Petroleum Energy**  9.88E+00 1.76E+00 7.41E-01 4.64E+00 0.00E+00 1.95E+01 4.87E-01 17304 17864 6017 11560 202623 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0 0 0 0 0 2.29E-01 4.37E-02 1.82E-02 1.19E-01 0.00E+00 4.99E-01 1.14E-02 443 457 145 280 5014 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0 0 0 0 0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0 0 0 0 0 10.105 1.805 0.759 4.755 0.000 19.983 0.498 17747 18321 6163 11840 207637

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Feed Trans Change page 2 of 2 printed 6/4/2012 2:08 PM

## Domestic Biofuel Production Changes

**Biofuel production energy use (Control minus Fuel-Specific Case)**  Inputs (from GREET/EPA Modeling) 2022 Plant Energy Balance (Btu/gal Produced) **NG Use** Sorghum Ethanol – Dry Mill NG - No CHP, 92% Wet DG 17,341 - Yes CHP, 92% Wet DG 19,497

Sorghum Ethanol – Dry Mill Coal - No CHP, 92% Wet DG - Yes CHP, 92% Wet DG

Sorghum Ethanol – Dry Mill Biogas - No CHP, 92% Wet DG - Yes CHP, 92% Wet DG

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 1 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 2 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 3 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 4 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 5 of 20 printed 6/4/2012 2:08 PM2022 2022 Plant Energy Balance (Btu/gal Produced) Bgal

**Coal Use Biogas Use**  **Diesel Fuel Use Purchased Elec**  **Sold Elec Other Inputs**  **(kg/gal)** Reference Case Policy Case Difference 2,235 0.3 0.2 0.1 0.0 0.0 0.0 508 0.3 0.2 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 21,676 2,675 0.3 0.2 0.1 0.0 0.0 0.0 25,126 203 0.3 0.2 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 17,341 2,235 0.3 0.2 0.1 0.0 0.0 0.0 19,497 508 0.3 0.2 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 6 of 20 printed 6/4/2012 2:08 PM0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 7 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 8 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 9 of 20 printed 6/4/2012 2:08 PMEPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 10 of 20 printed 6/4/2012 2:08 PM**2022 Emissions (tons, or tonnes for GHG) Deltas (Control minus Fuel-Specific Case)**

**Sorghum Ethanol – Dry Mill NG - No CHP, 92%** **Wet DG Source**  **VOC 1,3-Butadiene**  **Acetaldehy de**  **Acrolein Benzene**  **Ethanol Formaldehy** **de CO**  **NOx PM10**  **PM2.5** On-Site 439.560 0.000 25.655 1.110 0.837 181.898 4.414 208.791 604.395 241.758 21.919 Upstream 15.505 0.000 0.000 0.000 0.000 0.000 0.000 28.372 92.243 72.204 19.512

**Total** 455.065 0.000 25.655 1.110 0.837 181.898 4.414 237.163 696.638 313.962 41.431 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill NG - Yes CHP, 92%** **Wet DG Source**  **VOC 1,3-Butadiene**  **Acetaldehy de**  **Acrolein Benzene**  **Ethanol Formaldehy** **de CO**  **NOx PM10**  **PM2.5** On-Site 439.560 0.000 25.655 1.110 0.837 181.898 4.414 208.791 604.395 241.758 22.649 Upstream 13.369 0.000 0.000 0.000 0.000 0.000 0.000 19.884 59.310 17.883 5.308

**Total** 452.929 0.000 25.655 1.110 0.837 181.898 4.414 228.675 663.705 259.641 27.957 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 11 of 20 printed 6/4/2012 2:08 PM**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill NG**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal - No CHP, 92%** **Wet DG Source**  **VOC 1,3-Butadiene**  **Acetaldehy de**  **Acrolein Benzene**  **Ethanol Formaldehy** **de CO**  **NOx PM10**  **PM2.5** On-Site 439.560 0.000 25.655 1.110 0.837 181.898 4.414 208.791 604.395 241.758 111.323 Upstream 23.664 0.000 0.000 0.000 0.000 0.000 0.000 22.267 93.823 488.594 122.791

**Total** 463.224 0.000 25.655 1.110 0.837 181.898 4.414 231.058 698.218 730.352 234.114 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal - Yes CHP, 92%** **Wet DG Source**  **VOC 1,3-Butadiene**  **Acetaldehy de**  **Acrolein Benzene**  **Ethanol Formaldehy** **de CO**  **NOx PM10**  **PM2.5** On-Site 439.560 0.000 25.655 1.110 0.837 181.898 4.414 208.791 604.395 241.758 126.488 Upstream 21.557 0.000 0.000 0.000 0.000 0.000 0.000 8.444 44.581 474.872 118.299

**Total** 461.117 0.000 25.655 1.110 0.837 181.898 4.414 217.235 648.976 716.630 244.787 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 12 of 20 printed 6/4/2012 2:08 PM**Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Coal**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas - No CHP, 92%** **Wet DG Source**  **VOC 1,3-Butadiene**  **Acetaldehy de**  **Acrolein Benzene**  **Ethanol Formaldehy** **de CO**  **NOx PM10**  **PM2.5** On-Site 439.560 0.000 25.655 1.110 0.837 181.898 4.414 208.791 604.395 241.758 28.107 Upstream 4.531 0.000 0.000 0.000 0.000 0.000 0.000 13.395 49.497 70.563 18.538

**Total** 444.091 0.000 25.655 1.110 0.837 181.898 4.414 222.186 653.892 312.321 46.646
EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 13 of 20 printed 6/4/2012 2:08 PM**Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas - Yes CHP, 92%** **Wet DG Source**  **VOC 1,3-Butadiene**  **Acetaldehy de**  **Acrolein Benzene**  **Ethanol Formaldehy** **de CO**  **NOx PM10**  **PM2.5** On-Site 439.560 0.000 25.655 1.110 0.837 181.898 4.414 208.791 604.395 241.758 29.607 Upstream 1.030 0.000 0.000 0.000 0.000 0.000 0.000 3.045 11.250 16.039 4.214

**Total** 440.590 0.000 25.655 1.110 0.837 181.898 4.414 211.836 615.645 257.797 33.821 **Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas**  EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 14 of 20 printed 6/4/2012 2:08 PM**Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5** 

On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 **Sorghum Ethanol – Dry Mill Biogas**  **Source VOC**  **1,3-Butadiene Acetaldehy** **de Acrolein**  **Benzene Ethanol**  **Formaldehy de**  **CO NOx**  **PM10 PM2.5**  On-Site 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Upstream 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Total** 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 15 of 20 printed 6/4/2012 2:08 PM**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**

769.230 0.000 1.906 1.906 101895 102526 0 1732366 0 121.215 0.000 404.280 0.775 56623 65353 365965 231727 21246 890.445 0.000 406.186 2.681 158518 167879 365965 1964093 21246
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 769.230 0.000 2.143 2.143 114564 115273 0 1947750 0 47.298 0.000 397.029 0.309 21017 29450 86913 153338 11495 816.528 0.000 399.171 2.452 135581 144723 86913 2101088 11495
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 16 of 20 printed 6/4/2012 2:08 PM0.000 0.000 0.000 0.000 0 0 0 0 0

**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 769.230 0.000 8.662 2.165 232392 233245 2165436 0 0 135.770 0.000 334.857 0.819 60491 67777 441244 146878 46999 905.000 0.000 343.519 2.985 292883 301022 2606681 146878 46999
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 769.230 0.000 10.040 2.510 269379 270368 2510091 0 0 28.761 0.000 305.024 0.137 8480 14928 42381 15314 36568 797.991 0.000 315.064 2.647 277860 285297 2552472 15314 36568
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 17 of 20 printed 6/4/2012 2:08 PM**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**

0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 769.230 0.000 1.906 1.906 0 631 0 0 0 99.201 0.000 64.117 0.627 47541 49082 361805 119504 13814 868.431 0.000 66.023 2.533 47541 49712 361805 119504 13814
EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 18 of 20 printed 6/4/2012 2:08 PM**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**

0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 769.230 0.000 2.143 2.143 0 709 0 0 0 22.548 0.000 14.573 0.143 10806 11156 82236 27162 3140 791.778 0.000 16.716 2.285 10806 11865 82236 27162 3140
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 19 of 20 printed 6/4/2012 2:08 PM**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**

0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0
**SOx NH3**  **CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy** 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0 0.000 0.000 0.000 0.000 0 0 0 0 0

EPA-HQ-OAR-2011-0542-DRAFT-0418.xls: Dom Biofuel Prod Change page 20 of 20 printed 6/4/2012 2:08 PM

## Domestic Renew**able Fuel Transportation and Distribution Changes**

**Grams of emissions or fuel use per mmBtu of fuel transported (Control minus Fuel Specific Case)** Change volumes in Fuel Volumes sheet

For Domestic Use Corn Ethanol bgal Cellulsic Ethanol bgal Biodiesel bgal Renewable Diesel bgal FT Diesel bgal Imported Ethanol bgal **Transportation Mode A ssumptions**  Miles (One-way) Corn Ethanol Corn Ethanol Ocean tanker Barge Pipeline Rail Truck Local Truck **2012** 520 600 800 80
- **2017** 520 600 800 80
- **2022** 336.2 0.0 629.1 67.9 6.5 Cellulosic Ethanol Ocean Local tanker Barge Pipeline Rail Truck Local Truck **2012** 520 600 800 80
- **2017** 520 600 800 80
- **2022** 336.2 0.0 629.1 67.9 6.5 Biodiesel Ocean tanker Barge Pipeline Rail Truck Local Truck **2012** 520 400 800 50
- **2017** 520 400 800 50
- **2022** 520 400 800 50
- Renewable Diesel Ocean tanker Barge Pipeline Rail Truck Local Truck **2012** 520 400 800 50
- **2017** 520 400 800 50
- **2022** 520 400 800 50
-FT Diesel Ocean tanker Barge Pipeline Rail Truck Local Truck **2012** 5,000 520 400 800 30
- **2017** 5,000 520 400 800 30
- **2022** 5,000 520 400 800 30
- Imported Ethanol (U.S. transport only)

Ocean tanker Barge Pipeline Rail Truck Local Truck **2012** 7,416 520 600 800 100
- **2017** 7,416 520 600 800 100
- **2022** 7,416 336.2 0.0 629.1 67.9 6.5 

### Energy **Consumption and Emissions from Fuel Transportation (Updated for GREET1_8c_0) Feedstock/Fuel**  **Transportation Mode** Distance (Miles, one-way)

Energy Consumption: Btu/mmBtu of fuel transported

Total energy Fossil energy Coal Natural gas **Ocean Tanker** 5,000 9,222 9,200 165 447 **Barge** 520 11,192 11,166 201 543 **Pipeline** 400 3,288 3,226 309 895 **Rail** 800 11,484 11,468 133 6,981 **Truck** 30 1,954 1,949 49 119 **Truck** 30 1,954 1,949 49 119 **Ocean Tanker** 7,416 11,622 11,595 208 564 **Barge** 520 17,959 17,917 322 871 **Pipeline** 600 7,915 7,765 744 1,172 **FT Diesel**
**Pipeline** 600 7,915 7,765 744 1,172 **Rail** 800 15,056 15,014 379 914 **Truck** 100 10,454 10,424 263 635 **Truck** 30 3,136 3,127 79 190 **Barge** 520 12,898 12,868 231 625 **Pipeline** 400 3,790 3,718 356 1,031 **Rail** 800 10,813 10,783 272 657 **Truck** 50 3,754 3,743 94 228 **Truck** 30 2,252 2,246 57 137 **Barge** 520 17,959 17,917 322 871 **Pipeline** 600 7,915 7,765 744 1,172 **Rail** 800 15,056 15,014 379 914 **Truck** 80 8,363 8,340 210 508 **Truck** 30 3,136 3,127 79 190 **Barge** 520 11,006 10,980 197 534 **Pipeline** 400 3,234 3,173 304 880 **Rail** 800 9,227 9,201 232 560 **Truck** 50 3,203 3,194 81 194 **Truck** 30 1,922 1,916 48 117
**Toxic Fractions of exhaust VOC Renewable Diesel**  **Imported Ethanol (U.S. Transport and Ocean**  **Voy age Only** **)**

**Biodiesel**

**U.S. Produced Ethanol**Mode Source 1,3-Butadiene Acetaldehyde

Acrolein Benzene Ethanol Formaldehyde Rail Diesel Locomotive 0.003247 0.018786 0.003124 0.0025875 0.043287 Barge Marine Diesel -- Distillate 0.00061 0.074298 0.0035 0.020344 0.1496 Ocean Tanker Residual Boiler 0 0.003858 0 0.0001654 0.026457 Truck HDD Trucks 0.00061 0.0288 0.0035 0.0105 0.0782 Pipeline Natural Gas Turbines 0 0.019048 0.003048 0.0057143 0.338095Preliminary
2022FuelSpecific Case Control

Case Difference 0.30 0.20 0.10 0.00 16.00 0.00 0.00 0.00 0.00 1.00 1.00 0.00 3.14 3.14 0.00

Percentage of Fuel Transported by A Given Mode Truck (Distributi on) Ocean

tanker Barge Pipeline Rail Truck Local Truck Truck (Distributio n) 30 0% 10% 0% 60% 30% 0% 100% 30 0% 10% 0% 60% 30% 0% 100% 30 0% 11.7% 0.0% 76.8% 17.3% 83.3% 100%
Truck (Distributi Ocean Truck (Distributio on) tanker Barge Pipeline Rail Truck Local Truck (Distributio n) 30 0% 10% 0% 60% 30% 0% 100% 30 0% 10% 0% 60% 30% 0% 100% 30 0% 11.7% 0.0% 76.8% 17.3% 83.3% 100%
Truck (Distributi on) Ocean

tanker Barge Pipeline Rail Truck Local Truck Truck (Distributio n) 30 0% 5% 0% 45% 50% 0% 100% 30 0% 5% 0% 45% 50% 0% 100% 30 0% 5% 0% 45% 50% 0% 100%
Truck (Distributi on) Ocean

tanker Barge Pipeline Rail Truck Local Truck Truck (Distributio n) 30 0% 5% 0% 45% 50% 0% 100% 30 0% 5% 0% 45% 50% 0% 100% 30 0% 5% 0% 45% 50% 0% 100%Truck

(Distributi on) Ocean

tanker Barge Pipeline Rail Truck Local Truck Truck (Distributio n) 30 0% 6% 87% 7% 0% 100% 30 0% 6% 87% 7% 0% 100% 30 0% 6% 87% 7% 0% 100%

Truck (Distributi on) Ocean

tanker Barge Pipeline Rail Truck Local Truck Truck (Distributio n) 30 100% 10% 0% 60% 30% 0% 100% 30 100% 10% 0% 60% 30% 0% 100% 30 0% 11.7% 0.0% 76.8% 17.3% 83.3% 100% 

### Energy **Consumption and Emissions from Fuel Transportation (Updated for GREET1_8c_0) VOC, CO, NOx, PM, SOx, etc. need to vary by year: See new tables below.**  PetroleumTotal Emissions VOC 1,3-ButadieneAcetaldehyde Acrolein Benzene Ethanol Formaldehyde 8,588 0.816 0.0000 0.0031 0.0000 0.0001 0.0000 0.0216 10,423 0.467 0.0003 0.0347 0.0016 0.0095 0.0000 0.0698 2,023 0.114 0.0000 0.0022 0.0003 0.0007 0.0000 0.0385 4,354 0.670 0.0022 0.0126 0.0021 0.0017 0.0000 0.0290 1,781 0.062 0.0000 0.0018 0.0002 0.0007 0.0000 0.0049 1,781 0.062 0.0000 0.0018 0.0002 0.0007 0.0000 0.0049 10,823 1.029 0.0000 0.0040 0.0000 0.0002 0.0000 0.0272 16,725 0.749 0.0005 0.0557 0.0026 0.0152 0.0000 0.1121 5,849 0.274 0.0000 0.0052 0.0008 0.0016 0.0000 0.0927 13,721 1.042 0.0034 0.0196 0.0033 0.0027 0.0000 0.0451 9,527 0.334 0.0002 0.0096 0.0012 0.0035 0.0000 0.0261 2,858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 12,011 0.538 0.0003 0.0400 0.0019 0.0109 0.0000 0.0805 2,331 0.131 0.0000 0.0025 0.0004 0.0008 0.0000 0.0444 9,854 0.748 0.0024 0.0141 0.0023 0.0019 0.0000 0.0324 3,421 **0.120** 0.0001 0.0035 0.0004 0.0013 0.0000 0.0094 2,053 **0.072** 0.0000 0.0021 0.0003 0.0008 0.0000 0.0056 16,725 0.749 0.0005 0.0557 0.0026 0.0152 0.0000 0.1121 5,849 0.274 0.0000 0.0052 0.0008 0.0016 0.0000 0.0927 13,721 1.042 0.0034 0.0196 0.0033 0.0027 0.0000 0.0451 7,621 0.267 0.0002 0.0077 0.0009 0.0028 0.0000 0.0209 2,858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 10,249 0.459 0.0003 0.0341 0.0016 0.0093 0.0000 0.0687 1,989 0.112 0.0000 0.0021 0.0003 0.0006 0.0000 0.0379 8,409 0.638 0.0021 0.0120 0.0020 0.0017 0.0000 0.0276 2,919 0.102 0.0001 0.0029 0.0004 0.0011 0.0000 0.0080 1,751 0.061 0.0000 0.0018 0.0002 0.0006 0.0000 0.0048Formaldehyde2012 Emissions (tons, or tonnes for GHG) & Energy (mmBtu)
**Source** Corn Ethanol Cellulsic Ethanol Biodiesel Renewable Diesel FT Diesel Imported Ethanol
FUEL TRANSPORT (to terminal, exhaust emissions only) grams/mmBtu or Btu/mmBtu of fuel transportedCO NOx PM10 PM2.5 SOx CH4 N2O CO2 3.605 20.605 0.647 0.470 12.394 0.848 0.018 774 1.275 10.779 0.315 0.153 2.843 1.004 0.022 946 0.574 2.449 0.099 0.051 0.492 0.472 0.006 256 1.849 12.525 0.378 0.327 0.235 1.210 0.017 778 0.274 0.815 0.027 0.018 0.042 0.174 0.004 153 0.274 0.815 0.027 0.018 0.042 0.174 0.004 153 4.543 25.969 0.816 0.592 15.621 1.069 0.022 976 2.045 17.297 0.506 0.246 4.562 1.611 0.035 1518 1.382 5.895 0.239 0.123 1.185 1.137 0.014 615 2.878 19.890 0.561 0.454 0.356 1.370 0.028 1175 1.465 4.362 0.146 0.097 0.222 0.929 0.020 818 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 1.469 12.422 0.363 0.176 3.277 1.157 0.025 1090 0.661 2.823 0.115 0.059 0.567 0.545 0.007 295 2.067 14.285 0.403 0.326 0.256 0.984 0.020 844 0.526 1.566 0.052 0.035 0.080 0.334 0.007 294 0.316 0.940 0.031 0.021 0.048 0.200 0.004 176 2.045 17.297 0.506 0.246 4.562 1.611 0.035 1518 1.382 5.895 0.239 0.123 1.185 1.137 0.014 615 2.878 19.890 0.561 0.454 0.356 1.370 0.028 1175 1.172 3.489 0.116 0.078 0.178 0.743 0.016 654 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 1.253 10.600 0.310 0.151 2.796 0.987 0.021 930 0.564 2.408 0.098 0.050 0.484 0.465 0.006 251 1.764 12.189 0.344 0.278 0.218 0.839 0.017 720 0.449 1.336 0.045 0.030 0.068 0.285 0.006 251 0.269 0.802 0.027 0.018 0.041 0.171 0.004 150Emissions (tons, or tonnes for GHG) & Energy (mmBtu) **Total energy**  **Fossil**

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **Ac etaldeh** 

**yde Ac** **rolein** 0 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0 0.00 0.00 0.00
FUEL TRANSPORT (to terminal, exhaust emissions only) grams/mmBtu or Btu/mmBtu of fuel transported **Corn Ethanol**  **Total**

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **2012** 13338 13302 322 788 12191 0.780 0.0021 **2017** 13338 13302 322 788 12191 0.780 0.0021 **2022** 12248 12214 298 727 11189 0.743 0.0021 grams/mmBtu or Btu/mmBtu of fuel transported **Cellulosic Ethanol**  **Total Fossil**  **Natural 1,3-** 

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **2012** 13338 13302 322 788 12191 0.780 0.0021 **2017** 13338 13302 322 788 12191 0.780 0.0021 **2022** 12248 12214 298 727 11189 0.743 0.0021 grams/mmBtu or Btu/mmBtu of fuel transported **Biodiesel Total** 

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **2012** 7388 7367 181 441 6745 0.424 0.0011 **2017** 7388 7367 181 441 6745 0.424 0.0011 **2022** 7388 7367 181 441 6745 0.424 0.0011 grams/mmBtu or Btu/mmBtu of fuel transported **Renewabl e Diesel**  **Total**

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **2012** 6304 6286 155 376 5756 0.361 0.0010 **2017** 6304 6286 155 376 5756 0.361 0.0010 **2022** 6304 6286 155 376 5756 0.361 0.0010grams/mmBtu or Btu/mmBtu of fuel transported **FT Diesel Total** 

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **2012** 4336 4280 290 1300 2690 0.174 0.0002 **2017** 4336 4280 290 1300 2690 0.174 0.0002 **2022** 4336 4280 290 1300 2690 0.174 0.0002 grams/mmBtu or Btu/mmBtu of fuel transported **Imported Ethanol**  **(U.S. transport**  **only) Total** 

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleum VOC**  **1,3- Butadiene**  **2012** 25588 25522 547 1390 23586 1.829 0.0021 **2017** 25588 25522 547 1390 23586 1.829 0.0021 **2022** 12248 12214 298 727 11189 0.743 0.0021**Benzene Ethanol**  **Formalde hyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  0.00 0 0.00 0 0 0 0 0 0.00 0 0.00 0 0 0 0 0 0.00 0.00 0 0 0 0 0 0.00 0.00 0 0 0 0 0 0.00 0.00 0 0 0 0 0 0.00 0 0.00 0 0 0 0 0

**Ac etaldeh**  **yde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde CO**  **NOx PM** **10 PM** **2.5** 0.0196 0.0025 0.0040 0.0000 0.0445 2.283 14.711 0.422 0.320 0.0196 0.0025 0.0040 0.0000 0.0445 2.283 14.711 0.422 0.320 0.0177 0.0024 0.0034 0.0000 0.0402 2.144 14.071 0.402 0.309

**Ac etaldeh**  **Formalde yde**  **Ac rolein**  **Benzene Ethanol**  **Formalde hyde**  **CO NOx**  **PM 10**  **PM 2.5**  0.0196 0.0025 0.0040 0.0000 0.0445 2.283 14.711 0.422 0.320 0.0196 0.0025 0.0040 0.0000 0.0445 2.283 14.711 0.422 0.320 0.0177 0.0024 0.0034 0.0000 0.0402 2.144 14.071 0.402 0.309

**Ac etaldeh**  **yde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde CO**  **NOx PM** **10 PM** **2.5** 0.01 0.00 0.00
- 0.0233 1.267 7.832 0.226 0.173 0.01 0.00 0.00
- 0.0233 1.267 7.832 0.226 0.173 0.01 0.00 0.00
- 0.0233 1.267 7.832 0.226 0.173

**Ac etaldeh**  **yde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde CO**  **NOx PM** **10 PM** **2.5** 0.0086 0.0012 0.0017 0.0000 0.0199 1.081 6.683 0.193 0.148 0.0086 0.0012 0.0017 0.0000 0.0199 1.081 6.683 0.193 0.148 0.0086 0.0012 0.0017 0.0000 0.0199 1.081 6.683 0.193 0.148**Ac etaldeh** 

**yde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde CO**  **NOx PM** **10 PM** **2.5** 0.0049 0.0005 0.0013 0.0000 0.0397 0.705 3.654 0.132 0.077 0.0049 0.0005 0.0013 0.0000 0.0397 0.705 3.654 0.132 0.077 0.0049 0.0005 0.0013 0.0000 0.0397 0.705 3.654 0.132 0.077

**Ac etaldeh**  **yde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde CO**  **NOx PM** **10 PM** **2.5** 0.0242 0.0026 0.0044 0.0000 0.0733 6.914 40.941 1.247 0.918 0.0242 0.0026 0.0044 0.0000 0.0733 6.914 40.941 1.247 0.918 0.0177 0.0024 0.0034 0.0000 0.0402 2.144 14.071 0.402 0.3092017 Emissions (tons, or tonnes for GHG) & Energy (mmBtu)
**CH4 N2O**  **CO2 CO2-eq.**  **Source Total**  **energy Fossil** 

**energy Coal**  **Natural gas**  0 0 0 0 Corn Ethanol 0 0 0 0 0 0 0 0 Cellulsic Ethanol 0 0 0 0 0 0 0 0 Biodiesel 0 0 0 0 0 0.0 0 0 Renewable Diesel 0 0 0 0 0 0 0 0 FT Diesel 0 0 0 0 0 0 0 0 Imported Ethanol 0 0 0 0
FUEL DISTRIBUTION (from terminal, just exhaust, all by truck) grams/mmBtu or Btu/mmBtu of fuel distributed
**SOx CH4**  **N2O CO2**  **CO2-eq. Corn**  **Ethanol Total** 

**energy Fossil** 

**energy Coal**  0.723 1.206 0.025 1053 1086 **2012** 3136 3127 79 0.723 1.206 0.025 1053 1086 **2017** 3136 3127 79 0.599 1.109 0.023 965 995 **2022** 3136 3127 79 grams/mmBtu or Btu/mmBtu of fuel distributed **Cellulosi c Ethanol**  **Total Fossil**  **SOx CH4**  **N2O CO2**  **CO2-eq. c Ethanol**  **Total energy**  **Fossil**

**energy Coal**  0.723 1.206 0.025 1053 1086 **2012** 3136 3127 79 0.723 1.206 0.025 1053 1086 **2017** 3136 3127 79 0.599 1.109 0.023 965 995 **2022** 3136 3127 79 grams/mmBtu or Btu/mmBtu of fuel distributed
**SOx CH4**  **N2O CO2**  **CO2-eq. Biodiesel**  **Total energy**  **Fossil**

**energy Coal**  0.319 0.667 0.014 581 599 **2012** 2252 2246 57 0.319 0.667 0.014 581 599 **2017** 2252 2246 57 0.319 0.667 0.014 581 599 **2022** 2252 2246 57 grams/mmBtu or Btu/mmBtu of fuel distributed
**SOx CH4**  **N2O CO2**  **CO2-eq. Renewabl**  **e Diesel Total** 

**energy Fossil** 

**energy Coal**  0.272 0.569 0.012 496 511 **2012** 1922 1916 48 0.272 0.569 0.012 496 511 **2017** 1922 1916 48 0.272 0.569 0.012 496 511 **2022** 1922 1916 48grams/mmBtu or Btu/mmBtu of fuel distributed

**SOx CH4**  **N2O CO2**  **CO2-eq. FT Diesel**  **Total energy**  **Fossil**

**energy Coal**  0.615 0.556 0.008 334 348 **2012** 1954 1949 49 0.615 0.556 0.008 334 348 **2017** 1954 1949 49 0.615 0.556 0.008 334 348 **2022** 1954 1949 49 grams/mmBtu or Btu/mmBtu of fuel distributed

**SOx CH4**  **N2O CO2**  **CO2-eq. Imported**  **Ethanol (U.S.**  **transport only)**  **Total**

**energy Fossil** 

**energy Coal**  16.357 2.330 0.049 2078 2142 **2012** 3136 3127 79 16.357 2.330 0.049 2078 2142 **2017** 3136 3127 79 0.599 1.109 0.023 965 995 **2022** 3136 3127 79**Petroleu**

**m VOC**  **1,3-**

**Butadiene Ac** **etalde**

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde CO**  0 0 0.00 0.00 0.00 0.00 0 0.00 0 0 0 0.00 0.00 0.00 0.00 0 0.00 0 0 0 0.00 0.00 0.00 0.00 0.00 0 0 0 0.00 0.00 0.00 0.00 0.00 0 0 0 0.00 0.00 0.00 0.00 0.00 0 0 0 0.00 0.00 0.00 0.00 0 0.00 0
FUEL DISTRIBUTION (from terminal, just exhaust, all by truck) 3 4 5 6 7 8 **Natural gas**  **Petroleu**

**m VOC**  **1,3-**

**Butadien e**  **Ac etalde** 

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde** 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 grams/mmBtu or Btu/mmBtu of fuel distributed**Natural Petroleu**  **1,3- Butadien**  **Ac etalde**  **Formalde Natural**  **gas Petroleu** 

**m VOC**  **Butadien e**  **Ac etalde** 

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde** 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 grams/mmBtu or Btu/mmBtu of fuel distributed**Natural gas**  **Petroleu**

**m VOC**  **1,3-**

**Butadien e**  **Ac etalde** 

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde** 137 2053 0.072 0.0000 0.0021 0.0003 0.0008 0.0000 0.0056 137 2053 0.072 0.0000 0.0021 0.0003 0.0008 0.0000 0.0056 137 2053 0.072 0.0000 0.0021 0.0003 0.0008 0.0000 0.0056 grams/mmBtu or Btu/mmBtu of fuel distributed**Natural gas**  **Petroleu**

**m VOC**  **1,3-**

**Butadien e**  **Ac etalde** 

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde** 117 1751 0.061 0.0000 0.0018 0.0002 0.0006 0.0000 0.0048 117 1751 0.061 0.0000 0.0018 0.0002 0.0006 0.0000 0.0048 117 1751 0.061 0.0000 0.0018 0.0002 0.0006 0.0000 0.0048grams/mmBtu or Btu/mmBtu of fuel distributed**Natural**

**gas Petroleu** 

**m VOC**  **1,3-**

**Butadien e**  **Ac etalde** 

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde** 119 1781 0.062 0.0000 0.0018 0.0002 0.0007 0.0000 0.0049 119 1781 0.062 0.0000 0.0018 0.0002 0.0007 0.0000 0.0049 119 1781 0.062 0.0000 0.0018 0.0002 0.0007 0.0000 0.0049 grams/mmBtu or Btu/mmBtu of fuel distributed

**Natural gas**  **Petroleu**

**m VOC**  **1,3-**

**Butadien e**  **Ac etalde** 

**hyde Ac** **rolein Benzene**  **Ethanol Formalde**  **hyde** 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078 190 2858 0.100 0.0001 0.0029 0.0004 0.0011 0.0000 0.0078**NOx PM** **10 PM** **2.5 SOx**  **NH3 CH4**  **N2O CO2**  **CO2-eq.**

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

**CO NOx**  **PM 10**  **PM 2.5**  **SOx CH4**  **N2O CO2**  **CO2-eq.** 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253

**CO NOx**  **PM 10**  **PM 2.5**  **SOx CH4**  **N2O CO2**  **CO2-eq.** 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253

**CO NOx**  **PM 10**  **PM 2.5**  **SOx CH4**  **N2O CO2**  **CO2-eq.** 0.316 0.940 0.031 0.021 0.048 0.200 0.004 176 182 0.316 0.940 0.031 0.021 0.048 0.200 0.004 176 182 0.316 0.940 0.031 0.021 0.048 0.200 0.004 176 182

**CO NOx**  **PM 10**  **PM 2.5**  **SOx CH4**  **N2O CO2**  **CO2-eq.** 0.269 0.802 0.027 0.018 0.041 0.171 0.004 150 155 0.269 0.802 0.027 0.018 0.041 0.171 0.004 150 155 0.269 0.802 0.027 0.018 0.041 0.171 0.004 150 155**CO NOx**  **PM 10**  **PM 2.5**  **SOx CH4**  **N2O CO2**  **CO2-eq.**

0.274 0.815 0.027 0.018 0.042 0.174 0.004 153 158 0.274 0.815 0.027 0.018 0.042 0.174 0.004 153 158 0.274 0.815 0.027 0.018 0.042 0.174 0.004 153 158

**CO NOx**  **PM 10**  **PM 2.5**  **SOx CH4**  **N2O CO2**  **CO2-eq.** 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 253 0.439 1.309 0.044 0.029 0.067 0.279 0.006 245 2532022

Emissions (tons, or tonnes for GHG) & Energy (mmBtu)
**Source Total** 

**energy Fossil** 

**energy Coal**  **Natural gas**  **Petroleu**

**m VOC**  **1,3-**

**Butadien e**  **Ac etalde** 

**hyde** Corn Ethanol 116800 116476 2862 6965 106649 37 0.02 0.17 Cellulsic Ethanol 0 0 0 0 0 0 0.00 0.00 Biodiesel 0 0 0 0 0 0 0.00 0.00 Renewable Diesel 0 0 0 0 0 0 0.00 0.00 FT Diesel 0 0 0 0 0 0 0.00 0.00 Imported Ethanol 0 0 0 0 0 0 0.00 0.00**Ac rolein**  **Benzene Ethanol**  **Formalde hyde**  **CO NOx**  **PM 10**  **PM 2.5**  **SOx NH3**  0.02 0.04 30 0.40 22 128 4 3 6 0.00 0.00 0 0.00 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0.00 0.00 0.00 0 0 0 0 0 0.00 0.00 0.00 0.00 0 0 0 0 0**CH4 N2O**  **CO2 CO2-eq.** 

11 0 9187 9477 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

## International A**gricultural Changes**

**2022 Emissions (tons, or tonnes for GHG) & Energy (mmBtu) Deltas (Control minus Fuel-Specific Case)** Farm Chemical Production / Transport Upstream Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein** Nitrogen as N 25.839 0.000 0.000 0.000 Phosphorous as P2O 0.840 0.000 0.000 0.000 Potasium as K2O 0.139 0.000 0.000 0.000 Herbicide 0.030 0.000 0.000 0.000 Pesticide 0.074 0.000 0.000 0.000 **Total** 26.922 0.000 0.000 0.000 On-Farm Non-combustion GHG Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein** Fertilizer Application Rice Cultivation **Total** 0.000 0.000 0.000 0.000 International Ag Sector Emissions **Source VOC**  **1,3-Butadiene Ac** **etaldehyde Ac** **rolein** Livestock Changes - Canada Livestock Changes - Western Europe Livestock Changes - Eastern Europe Livestock Changes - Oceania Livestock Changes - Latin America Livestock Changes - Asia Livestock Changes - Africa and Middle East Livestock Changes - Indian Subcontinent**Total** 0.000 0.000 0.000 0.000**2022 Emissions (tons, or tonnes for GHG) & Energy (mmBtu) Deltas (Control minus Fuel-Specific Case)**

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3** 0.000 0.000 0.194 24.346 14.452 3.870 2.006 7.578 0.000 0.000 0.000 0.005 2.865 16.302 3.897 2.393 144.742 0.000 0.000 0.000 0.001 0.498 2.125 0.728 0.257 1.552 0.000 0.000 0.000 0.000 0.111 0.390 0.192 0.088 0.368 0.000 0.000 0.000 0.001 0.287 0.830 0.368 0.175 0.482 0.000 0.000 0.000 0.201 28.106 34.099 9.055 4.918 154.72 0.000

**Benzene Ethanol**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3**
0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

**Benzene Ethyl Benzene**  **Formaldehyde CO**  **NOx PM** **10 PM** **2.5 SOx**  **NH3**

0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**  11.174 6.314 9391.629 11,584 0 0 0 3.645 0.037 2020.083 2,108 0 0 0 1.021 0.010 690.092 715 0 0 0 0.319 0.002 220.514 228 0 0 0 0.635 0.005 432.309 447 0 0 0 16.795 6.369 12,755 15,082 0 0 0

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**  0.000 0 208.571 4,380 208.571 0.000 0 4,380 0 0 0

**CH4 N2O**  **CO2 CO2-eq.**  **Coal Energy NG Energy**  **Petroleum Energy**  -109.724 -1.255 -2693 7.216 0.193 211 -224.942 -2.689 -5557 -15.456 -0.398 -448 150.963 3.184 4157 -112.227 -4.026 -3605 -36.508 -1.479 -1225 108.259 1.054 2600 -232.420 -5.418 0.000 -6560 0.000 0.000 0.000