### BOBBY JINDAL GOVERNOR

# ~tate 

# of 1Louisiana PEGGY M. HATCH 

### SECRETARY



### DEPARTMENT OF ENVIRONMENTAL QUALITY 

## OFFICE OF ENVIRONMENTAL COMPLIANCE
Certified Mail No.: 7005 0390 0001 6882 0354

Mr. Alvin Kooiman Pelican Refining Company, LLC': 4646 Hwy. 3059 Lake Charles, LA 7061 5 RE: PermitModification, Lake Charles Refinery, Pelican Refining Co, LLC, Lake Charles, Calcasieu Parish, Louisiana Dear Mr. Kooiman: Activity No.: PER20100003 Agency InterestNo.: 13058

·This is to inform you that.the permit modification request for the above referenced facility has been approved under LAC 33:111.501. The submittal was approved on the basis ofthe emissions reported and the approval in no way guarantees the design scheme presented will 

## be capable ofcontrolling the emissions as to the types and quantities stated. A new application must'be submitted ifthe reported emissions are exceeded after operations begin. The synopsis, data sheets, and conditions are attached herewith.· It will be considered a violation ofthe permit ifall proposed control measures and/orequipment are not installed and properly operated and maintained as specified in the application. Also enclosed is a document entitled "General Information." Please be advised that this document contains a summary of**facility~**

### level information contained in LDEQ's TEMPO database and is not considered a part ofthe permit. ·Please review the information contained in this document for accuracy and completeness. Ifany changes are required or ifyou have questions regarding this document, you may email your changesto facupdate@la.gov. Please be advised that pursuant to provisions .ofthe Environmental Quality Act and the Administrative Procedure Act, the Department may initiate review ofa permit during its term. However, before it takes any action to modifY, suspend or revoke a permit, the Department shall, in accordance with applicable statutes and regulations, notifY the permittee by mail ofthe facts or operational conductthat warrant the intended action and provide the permittee with the opportunity to demonstrate compliance with all lawful requirements for the retention ofthe effective permit. The permit number cited below and agency interest number cited above should be referenced ·in future correspondence regarding this facility.
Done this / 

# f day of

# ~ , 2011. Permit No.: 0520-00027-05 Sincerely,

# rf~~w~ Sam L. 

### Phillips Assistant Secretary SLP:TVN

Post Office Box 4312 • Baton Rouge, Louisiana 70821-4312 • Phone 225-219-3715 • Fax 225-219-3708 www.deq.louisiana.gov

## AIR PERMIT BRIEFING**SH~ET** 

## AIR PERMITS DIVISION LOUISIANA DEPARTMENT OFENVIRONMENTAL QUALITY

I. 

## BACKGROUND Lake,CharlesRefinery 

## Agency InterestNo.: 13058

Pelican Refining Co LLC Lake Charles, Calcasieu Parish, Louisiana

This Lake Charles refinery was constructed in the late 70s. The ownership ofthe refinery was transferred from American International Refinery, Inc. (AIRI) to Gold Line Refinery;Ltd. on September 26, 1991. AIRI regained operational control of the refinery in March 1997. Ownership ofthe refinery was transferred to Pelican Refining Company, L.L.C. on March 10, 2005. The refinery was permitted under Part 70 Permit 0520-00027-VO issued February 4, 2003 and Title V Permit No. 0520-00027-VI dated June 21, 2005. The asphalt plant was constructed in 1996 and was permitted under State Permit 0520-000183-02 granted May 27, 1998 and a general Title V permit No
..2932-VO dated July 6, 2005. Since 2005 this facility including Lake Charles Refinery and Asphalt Plant, has been in the processes of resuming normal operation. Lake Charles Refinery and Asphalt Plant operated under same Permit No. 0520-00027-V2 dated January 8, 2007. But through refinery modification and permit reconciliation, emissions of each criteria pollutant are below the TV major source threshold. The Asphalt Plant and Lake Charles Refinery were permitted under two minor source permits. ·Currently, the Asphalt Plant operates under permit no. 2932-03, issued on April 12, 2010 and Lake Charles Refinery operates under permit no. 0520-00027-04 issued on July 21,2009.
II. ORIGIN A permit application dated December 15, 2010 was submitted requesting apermit modification. III. DESCRIPTION The petroleum refinery receives crude oil via barge. The crude oil is separated into various petroletim fractions, including liquefied petroleum gas (LPG), naphtha, refined petroleum products, and atmospheric tower bottoms (ATB) or reduced crude. The reduced crude is distilled further to produce vacuum gas oil (VGO) and vacuum tower bottoms (VTB). The VTB is used to produce an asphalt product. The petroleum products from the facility are transported off-site by barge. · The main petroleum refining process units at this facility are: • Atmospheric Distillation Unit (ADU), • Vacuum Distillation Unit (VDU), and • Asphalt Production Unit.

## AIR PERMIT BRIEFING SHEET AIR PERMITS DIVISION LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Lake Cbarles Refinery Agency Interest No.: .J3058

Pelican Refining Co LLC Lake (:harles,·Calcasieu Parish, Louisiana 

## In this modification, Pelican requested the following: 

## I. Delete: EQT006, EQT007, EQT009 and EQTOIO: Storage Tanks and EQT020: Tank Trucker Loading Rack; and 2. Updates emissions and the GCXVII based on current operations and calculation methodology. · Estimated emissions from the Refinery in tons peryear are as follows: Pollutant Before After Change PM1o 

## 6.36 0.86 -5.44 

# so2 13.39 1.59 -11.80 NOx 71.40 I0.31 -61.09 

# co 41.06 6.36 -34.70 

# voc 1 53.79 65.35 +11.56 Metal* <0.01 0.005 -0.005 1 VOC speciation in tons per year: LAC 33:1Il
..Chapter 51 Toxic AirPollutants TAP's: Pollutant Before After Change I,3- Butadiene 0.10 0.011 -0.089 2,2,4

-Trimethylpentane 0.02 0.25 +0.23 Benzene 0.66 1.75 +1.09 Biphenyl <0.01 0.17 +0.16 Cresols <0.01 0.16 +0.15 Cumene 0.07 0.38. +0.31 Ethyl benzene 0.19 0.60 +0.41 Forrnaldehyde <0.01 -0.01 n-Hexane 0.57 0.67 +0.10 Naphthalene < O.Ql 0.19 +0.18 Phenol <0.01 0.17 +0.16 Toluene 0.52 1.64 +1.12 Xylene 0.39 1.32 +0.93 Total VOC TAPs 2.57 7.311 +4.741 2

## Metals* Copper Nickel 

## AIR PERMIT BRIEFING SHEET AIR PERMITS DIVISION • c , ' r 

## LOUISIANA DEPARTJ\,1ENT OF ENVIRONMENTAL QUALITY Lake Charles Refinery

.**";~** ...

### Ag~ncy 

## Interest No.: 13058 Pelican Refining Co LLC Lake Charles, Calcas_ieu Parish, Louisiana

< 

## 0.01 < 

## 0.01 0.003 0.002 

## -O.OOT -0.008

Estimated emissions from each area, as well as the combined total emissions from the site,'intons peryear, are as follows: PermitNo. PMIO 

# so2 NOx 

# co VOC** PeliCan Refinery 0520-00027-05 0.86 1.59 10.31 6.36 73.19 Asphalt Blending Facility 2932-03 0.16 0.01 2.15 1.80 20.60 Total 1.02 1.60 12.46 8.16 93.79 VOC** include GCXVII Activity and Insignificant Activities Emissions. 

## IV. TYPE OF REVIEW This permit was reviewed for compliance with Louisiana Air Quality Regulations and New Source Performance Standards (NSPS). Prevention of Significant**Deterioratio~** 

## (PSD) and National Emission Standards for Hazardous Air Pollutants (NESHAP) do not apply. This facility is a minor source ofLAC 33:IIJ.Chapter 51 Toxic Air**Pollutan~s** 

## (TAPs). 

## V. PUBLIC NOTICE Public notice is not required to permit a minor source. 

## VI. EFFECTS ON AMBIENT AIR Emissions associated with the proposed modification were reviewed by the Air Permits Division to ensure compliance with the NAAQS and AAS. LDEQ did not require the applicant to model emissions. Dispersion Model(s) Used: None

3

## AIR PERMIT BRIEFING SHEET AIR PERMITS DIVISION LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Lake Charles Refinery Agency Interest No.: 

## 13058

Pelican Refining Co LLC Lake Charles, Calcasieu Parish, Louisiana VII. GENERAL CONDITION XVII ACTIVITIES Emission Rates

- tons Work Activity Schedule PM10 so2 NOx co voc H2S Laboratory Emissions 365 days/year 0.10 Pump & Valve Maintenance 4 times/year 0.08 0.01 Tank II0-15 Landing I days/year 0.11 Tank 110-16 Landing I days/year 0.06 Tank 15-05 Landing I days/year 0.21 Tank 15-06 Landing I days/year 0.21 Tank 55-01 Landing I days/year 0.08 Tank Cleaning 0.25 time/year 4.71 Unit Cleariing & 0.2 times/year 0.33 0.06 Maintenance Vacuum Truck Loading 2times/year 1.65 0.28 

## VIII. INSIGNIFICANT ACTIVITIES I D.: Description VOC (TPY) Citation Fresh Caustic Storage Tank (2,500 gal) Lube Oil Drums (55 gal) 3 Diesel Storage Tanks (500 gal/each) Diesel Storage Tank (300 gal) Water Soften System (three 200-gal tanks) Fresh Caustic Storage Tank (I0,500 gal) Caustic Mix Tank (I0,500 gal) Maintenance Sandblasting and Painting Vapor Degreaser (55 gal) Boiler Feed Water Tank (1,900 bbls)

4 

## LAC 33:111.501.B.5.A.4

. 0.003 LAC 33:111.501.8.5.A.3 <0.001 LAC 33:111.501.8.5.A.3 <0.0001 LAC 33:111.501.8.5.A.3 LAC 33:1I1.501.B.5.A.4 LAC 33:111.50 1.8.5.A.4**~** 

## LAC 33:111.501.8.5.A.4 0.294 LAC 33:111.501.8.5.8.3 0.006 LAC 33:111.501.8.5.A.3 LAC 33:111.501.8.5.8.8Also KnownAs: ID 0520-o0027 74-2570362 LAD092476126 GP9326 I.A0054399 LAG670039 WP0197
GD-Q19-2704 G-o19-3295 19450 31238 3391 47217 48879 68805 70616GLDLN4846H 

### wac o2o919-o4 Physical Location: 4846 Hwy 3059 lake Charles, LA 70601 MailingAddress: 4646 Hwy 3059 Lake Charles, LA 70601 

### General Information AIID: 13058 Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-00027-05 

## Air • Minor**(Synthe~ii:)** 

### Modification Name User Group Pelican Refining Co LLC CDS Number Federal Tax ID Federal Tax 10 Pelican Refining Co LLC Hazardous Waste Notification

· LPDES# LPDES Permit#

LPDES# LPDES Permit # LPDES# LPDES Permil # LWDPS# LWDPS Permll # Pelican Refining Co LLC Multimedia American International Refinery Inc Solid Waste Site ID # Solid Waste Facility No. American International Refinery -lake Charles Facility TEMPO Merge Gold Lilia Reflnlrig Ltd TEMPO Merge lake**Ch~utes** Refining Co TEMPO Merge Gold Line Refining ltd
- Lake Charles TEMPO Merge American International Refinery Inc TEMPO Merge American lntemationai Refinery Inc TEMPO Merge TRI# Toxic Release Inventory Water Quality Certification# Water Certification

Location of Front Gate: 30.285556.1atitude, -93.131389 longitude, Coordinate Method: Lat.\Long.:. OMS, Coordinate Datum: NA083 Related People: Name Betty Clark Ryan Giggar Byron Hamilton Byron Hamilton Byron Hamilton Alvin Kooiman Alvin Kooiman Alvin Kooiman · Mailing Address PO Drawer 16867 Lake Charles, LA 706166867 PO Drawer 16867 Lake Charles, LA 70616 8 Greenway Plaza Ste 930 Houston, TX 77046 8 Greenway Plaza Ste 930 Houston, TX 77046 8 Greenway Plaza Ste 930 Houston, TX 77046 4846 Hwy3059 (Old Town Rd) Lake Charles; LA 70615 4846 Hwy 3059 (Old Town Rd) Lake Charles, LA 70615 4846 Hwy 3059 (Did Town Rd) Lake Charles, LA 70615 Page 1 of 2 Phone (Typo) 3164394066 (WP) 3374394066 (WP) 7136776780 (WP) 7136776760 (WP) 7136776760 (WP) 3374918800 (WP) alvln.koolman@pelic alvin.koolman@pelic Main FAX: Main Phoile:

Relationship Start Data 08-o5-2002 11'21-1999 03-23-2006**11~21-1999** 06-25-2003 12-13-1999 06-25-2003 12-29-2004 01-o6-2002 11-21-1999

. 10-26-2000 02-15-2001 02-15-2001 02-15-2001 10-30-2000 10-30-2000 07-29-2004 01-13-2003
7136777192 7136776760

Acdd&nt Pr&v&ntion Billing Party for Hazardous Wasta Permit Contact For Water Permit Contact For Responsible Official for Air Permit Contact For Emission Inventory Facility Contact for Emission Inventory Facility Contact for Responsible Official for
TPOR0148Related People: Name Alvin Kooiman James Taylor James Taylor 

### General Information AIID: 13058 Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520..()002HJ5 Air • Minor (Synthetic) Modification

. Mailing Address 4046 Hwy 3059 (Old Town Rd) Lake**C~arles,** LA 70615 4046 Hwy 3059 (Old Town Rd) Lake Charles, LA 70615 4046 Hwy,3059 (Old Town Rd) Lake Charles, LA 70615 ·Phone (Type) 3374916600 (WP) 3374918806 (WP)**JT@PELICANREFI~** Relationship Responsible Official for Responsible Official for Responsible Official for Related Organizations: Name Address Phone (Type} Relationship

NAIC Codes: Pelican Refining Co LLC Pelican Refining Co LLC Pelican Refining Co LLC Pelican' Refining Co LLC Pelican Refining.Co LLC Pelican Refining Co LLC Spooner & Associates Inc Spooner & Associates Inc 32411, Petroleum Refineries 3355 W Alabama St Ste 575 Houston, TX 77098 3355 W I'Jabama 51 5te 575 Houston, TX 77098 3355 W Alabama St Ste 575 HouSton, TX 77098 500 Kirby 51 Lake Charles, LA 70601 3355 W Alabama St Ste 575 Houston, TX 77098 3355 W Alabama St Ste 575 Houston, TX 77098 PO Box 12685 Lake Charles, LA 706122685 PO Box 12685 Lake Charles, LA 706122685 7138776780 (WP) 7138776780 (WP) 7138776780 (WP)
7.138776780 (WP) 7138776780 (WP) 3375621568 (HP) 3375621569 (WP) Operates Emission Inventory Billing Party Air Billing Party for Operates Owns Water Billing Party for Provides environmental services for Provides environmental services for

Note: This report entitled "Generallnfonnatlon"' contains a summary offaCUlty-level Information contained In LDEQ's TEMPO databaseforthisfacility and Is notconsidered a part ofthe permit. Please review the Information contained In this documentfor accuracy and completeness._ Ifany changes are required or Ifyou have questions regarding this document,you may contact Ms. Tommie Milam, Permit Support Services Division, at (225) 219-3259 or email**yo~r** changestofacupdate@la.Qov.

Page 2 of2 TPOR0148Subject Item Inventory: ID Description lake Charles Refinery EQT0003 4-76- Plant Flare EQT0005 3-91- Crude Oil Storage.Tank (TK 110-16) EQT0008 7-78- Crude Oil Storage Tank {TK 55-01) EQT 0011 10-78- Crude Oil Storage Tank (TK 40-03) EQT 0012 11-78- Intermediate Petroleum Product Tank (TK 10-13) EQT 0013 12-78- Intermediate Petroleum Product Tank (TK 10-14) EQT0014 13-78- Intermediate Petroleum Product Tank (TK 30-04) EQT0015 14-78- Intermediate Petroleum Product Tank (TK 10-07) EQT 0016 15-78- Intermediate Petroleum Product Tank (TK 10-Q8) EQT 0018 17-78- Naphtha Storage Tank (TK 15-05) EQT 0019 18-78- Naphtha Storage Tank (TK 15-06) EQT0021 21-78- Barge Loading (Refinery) EQT0023 5-80- Crude Oil Storage Tank (TK 110-15) EQT0024 1-90 - Vacuum Distillation Unit Heater EQT0026 5-91- lntennedlate Petroleum Product Tank (TK 55-18) EQT0061 1-99- Slop Oil Tank (TK 1-02) EQT0063 3-99- Fire Water Pump
- Diesel Engine Driver EQT0064 4-99- Spent Caustic Storage Tank (TK-500) EQT0065 5-99- Spent Caustic Storage Tank (TK-503) EQT0067 7-99 - Instrument Back-up Compressor EQT 0069 11-99- Desalter w_ater Storage Tank (TK-103) I EQT 0070 2-78 -Boiler 8-482 EQT 0071 1-98 - Boiler 8-483 FUG 0003 12-99- Fugitive Equipment Leaks (VDU) FUG 0004 1-08- Fugitive Equipment Leaks {Docks) FUG 0005 2-08- Fugitive Equipment Leaks (Tanks) FUG 0006 3-08- Fugitive Equipment Leaks (Crude) TRT 0001 8-99- Wastewater Collection & Treatment Stack lnfonnation· ID Description Lake Charles Refinery EQT 0003 4-78- Plant Flare 

### INVENTORIES AIID: 13058 ·Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-00027.05 Air • Minor (Synthetic) Modification

TankVolume Max. Operating Rate Normal OperatJng Rate

1.77 MM BTU/hr 1.48 MM BTU/hr 4.62 million 25.2 MM gallons/yr

aallons 2.31 million 48.18 MM gallons/yr

aallons 1.68 million

gallons 420000 gallons 420000 gallons

1.26 million. 10.23 MM gallons/yr

aallons 420000 gallons 82.48 MM gallons/yr 420000 gallons 62.09 MM gallonslyr 630000 gallons 30.66 MM gallons/yr 630000 gallons 30.66 MM gallons/yr

_ 126000 gallons/hr 105000 gallonslhr 4.62 million 96.36 MM gallons/yr

gallons 47:52 MM BTU/hr 39.6 MM BTU/hr 2.31 million 10.23 MM gallons/yr

gallons 19170 gallons 355332 gallons/yr 296110 gallons/yr 270 horsepower 225 horsepower 10500 gallons 110000 gallons/yr 25200 gallons 260000 gallons/yr .2 MM BTU/hr 80 horsepower 42000 gallons 3.32 MM gaUons/yr 54 MM BTU/hr 45 MM BTU/hr 54 MM BTU/hr
- 45 MM BTU/hr

92000 gallons 66240 gallons/day**E-~~QO** gallons/day Velocity FloW Rate Diameter (ftlsec) (cubic ft/min-actual) (feet)

65.6 4369 1.2

Page 1 of 3 Contents OperatingTlme

8760 hr/yr Crude Oil 8760 hr/yr 8760 hr/yr 8760 hr/yr Intermediate Petroleum Product 8760 hr/yr Intermediate Petroleum Product 8760 hr/yr Intermediate Petroleum Product 8760 hr/yr Wastewater 8760 hr/yr Intermediate Petroleum Product 8760 hr/yr 8760 hr/yr 8760 hr/yr 280 hr/yr 8760 hr/yr 1152 hr/yr Intermediate Petroleum Product 8760 hr/yr 8760 hr/yr 500 hr/yr 8760 hc/yr 8760 hr/yr Diesel
- 500 hr/yr 8760 hr/yr 1152 hr/yr 1152 hr/yr 8760 hr/yr 8760 hr/yr

-- 8760 hr/yr 8760 hr/yr 8760 hr/yr Discharge Area Height Temperature

{square feet) (feet) (oF)
100 1832
TPOR0149St01ck Information: 

### INVENTORIES AIID: 13058 -Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-00027-05 Air , Minor (Synthetic) Modification**~--** - -ID 

### -------------- O.acriptkm Volodty (fllaec) f)ow Rate Diameter DIScharge Area Height Temperature I_Uke Char1ea Refinery (cubic**ftlmin~-~-1)**____**(~~-1)** (square feet) (feet) (of) 

### j

1 EOTOOOS

__

### ~-~~-:**~e-~iiSt~~-~-Ta_~k(TK** 110-16). · ---· _--·-··--···· 

### "f ·------ ··

### ------~~-- -------·

### --~-~- 1**EOT_~Il_** 7-78_- Crude Oil Storage Tank (TK 55-111)
___ ---------- __ _-------- 1 41 68 ' EOT 0011 1 D-78

- Crude Oil Storage Tank (TK 40-113) 1 41 68 '·E0T0012 11-78-**lntermediatePetroleumProdudTank(tff1o~13)**______ ---- - 1 -------· 41 68

EQT 0013 12:79- Intermediate Petroleum Product Tank (TK 10-14) 1 41 68

· EOT 0014 13-78- Intermediate Petroleum Product Tank·(TK-30:.o4)

___ · - · --· -- 1 41 

# ·-·sa----

EtlT 0015-14-78- lntermedi8te Petroleum Product Tank (TK**10~7)** --- ·· --- - ----- 1

--- -**·--------~** 68 ; EoT oo16 15-78·:- lntOiiiiOdTiiiiiF>iiirotiiirml'iOdiicitanli(ll<w::n---er----

-- · -- ------- · --1--

----- -------- -- 41 68

-· - o • •R --· EQT 0018 17-78 - Naphtha**.,tor.~ga** 1anK l'r.. 1:>-v:>J 41 

### -- -·- -- -- --68 EOT 0019 18-78- Naphtha Storage Tani<(n<**15~-)**------- -------- 

### -----------· 41 68 

### :-earoo21-21-:n:Bat-g8Lo8ding.(Re1tnery) ······· ··· ···- -------···---- ···- ···-· - 

### --··-2- 20 j EOT 0023

### ~_:_Crude Oil Storage Tank (TK 11D-15)

### _:-~~-~ 1

- - -- -

### -=~~-=**----~-1** ____ 

### i EQT 0024 1-90- Vacuum Distillation Unit Heater 20.33**2~~-~-:._27** 5 

### 50-.--- ! EOT 0026 5-91 - Intermediate Petroleum Product Tank (TK 55--18) 1 41**~0061** 1-99- Slop Oil Tank (TK 1-02) -----------.-1----------- 30 110



### ___68
____, --1000
___ 68 120 EOT 0063 3-99- Fire Water**Pu~T4>** - Diesel Englne Drtwr .5 25 550

# ~~~=-~:::::~:::**~=:: ~:~:** **::~~:** 

# ------- - -- --------

# > --- -------**--:~**

# ------...**-::-~** -EOT 0067"-7

### .gg-.:-

## "tnStrume·nt sa·Ck.:up·eo---mpres.sor---- --··- ----- - -- . - -

# ·-----:s·- -- ..--·---------- 15 550

.. i EOT 0069 11-99- Desalt"'Water Stonogo Tank (TK-103)

------- ---- 1 25 78 -Eciroo7ii2-7s:

### i!Oftoi**8~82--** 

### - ---- . - . ------ -- - -- -- ·44.82 19010.89

- --- ---3- ----------------------49---------sso
___ .---- ' EOT 0071 1-98- Boiler B-483 18.99 1541i2:4i 4.2 75
. 390 '

- -- .. -------- ---- - ---· -- . ----- - -- ---·-···- --.---. ------------- -------------- -- -- -- _j FUG 0003 12-99

- Fugitive Equipment Leeks (VDU) [

# :~~

# ::**~:i:::: ~;:;;;:** **~=:**

# -=:!-

-- ---- ----·-**-~------** 

# ------··-- ·-....----·-- ____...:....._...**~--**

# ---··--_·___

# -I

TRT 0001 8-99 • Wastewater Collection & Treatment 237 177840 20 20 Relationships: 

### : ao**-!~** 

### __ 

# -=_-_-_-----·-·**··---~crlptlon ·--~**  Rel•tlonshtp ·-- -- ____._____**~~** ___

### j

.. ___ ... ···- ··-----oncrtpt"ic:in ······**·----~---·]** fUG 0003 -··

# .L 12-99. Fugitive

### Equipme~_t_~~ (VOU)
-- ___ Controlled by

. ..!._OT

### ooo.:__~--~~**-=-~~n:~lam** I
Page 2 of 3 TPOR014GSubject Item Groups: 10 GroupType CRG 0001 Common Requirements Group CRG 0002 Common Requirements Group CRG 0003 Common Requirements Group UNF 0001 Unit or Facility Wide Group Membership: 

### INVENTORIES 

## AI iD: 13058 'Pelican Refining Co 

## i.LC Activity Number: PER20100003 Permit Number: OS20-00027-05 Air • Minor (Synthetic) Modification

CRG001 -Fugitive Group CRG002.:. External Floating RoofTanks CRG003 -Internal Floating RoofTanks Faclllty
- Lake Chartes Refinery Group Description

l 10**~** Description Member ofGroups 

### I EOT 0008 

### i 7-78- Crude Oil Storage Tank (TK 55-Q1) CRG0000000002 

# !EQT 0011 10-78- Crude Oil Storage Tank (TK 40-Q3) CRG0000000003

EQT 0018 17-78- Naphtha Storage Tank (TK 15-Q5) CRG0000000003 EQT 0019 18-78- Naphtha Storage Tank (TK 15-Q6) CRG0000000003 EQT 0023 5-80- Crude Oil Storage Tank (TK 110-15) CRG0000000002 FUG 0003 12-99- Fugitive Equipment Leaks (VDU) CRG0000000001 FUG 0004 1..{)8- Fugitive Equipment leaks (Docks) CRG0000000001 FUG 0005 2-Q8- Fugitive Equipment Leaks (Tanks) CRG0000000001 FUG 0006 3-08- Fugitive Equipment Leaks {Crude} CRG0000000001 NOTE: The UNF group relationship Is not piinted In this iable. Every subject Item Is a merriber ofthe UNF group
Annual Maintenance Fee: Fee Number Air Contaminant Source Multiplier Units Of Measure 0720 0720 Petroi8Um Refining (Rated Capacity) 18 M bbl/day 

# ' SIC Codes: 2911 Petroleum refining AI 13058 2911 Petroleum refining UNF 001

Page 3 of3 .

TPOR0149

## co Subject Item Avg lblhr Maxlb/hr Tons/Yaar Lake Charles Refinery

EQT 0003 0.47 0.57 2.07 4-78 EQT 0005 

# , 

# .., EQT 0008 7-78 EQT 0011 

## '

# '~"==+ i EOT 0012 11-78 EQT 001_3
__ 12-78 EQT 0014 13-78 EQT 0015 14-78 EQT 0016 15-78 EQT 0018 17-78 EQT 0019 18-78 EOT 0021 21-78 EQT 0023 

# ..., EQT 0024 3.26 3.91 1.88 

# , 

# .., EQT 0026 5-91 EQT 0061 

# , 

# ... EQT 0063 1.50 1.80 0.38 

# , 

# .., EQT 0064 4-99 EQT 0065 

## ! 

# , 

# ... EQT 0067 0.53 0.64 0.13 

# , 

# .., EQT 0069 11-99 EOT 0070 2-78 1.64 1.97 0.95 EQT 0071 I 1.64 1.97 0.95 

# , 

# .., I EMISSION RATES FOR CRITERIA-POLLUTANTS AIID: 13058 - Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-D0027

## -os Air- Minor (Synthetic) Modification
NOx PM10 502 Avg lb/hr Maxlb/hr Tons/Year Avg lb/hr Maxlb/hr Tons/Year Avg lb/hr

0.11 0.13 0.47 0.002 0.002 0.01 0.03



# - I

3.88 4.66 2.24 0.30 0.35 0.17 1.07

6.98 8.37 1.74 0.50 0.59 0.12 0.46

2.48 2.98 0.62 0.18 0.21 0.04 0.16
' 4.56 5.47 2.62 0.45 0.54 0.26 0.60 4.56 5.47 2.62 

# I 0.45 0.54 0.26
. 0.60 Page 1 of2 VOC Maxlb/hr Tons/Year Avg lb/hr 

### Max lblhr Tons/Year

0.04 0.14· 0.17 0.21 0.75 1.25 5.45 

### ' 0.37 1.62 

## l 0.07 0.30 

# I 0.01 0.04 0.01 0.04 "3.02 13.21 0.08 0.36 0.08 0.35 0.65 2.83 0.65 2.83 89.85 801.27 12.58 0.42 1.84 1.28 0.61 0.21 0.26 0.12 4.22 18.50 0.09 0.39 0.55 0.12 0.57 0.68 0.14 0.002. <0.01 0.003 0.02

. 0.20 0.04 0.20 0.24 0.05 

## o.oi 0.05 0.71 0.34 0.24 0.29 0.14 0.71 0.34 ·o.24 0.29 0.14 

# ' TPOR0145

## EMISSION RATES FOR CRITERIA POLLUTANTS AIID: 13058 ·Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520.00027.05 Air • Minor (Synthetic) Modification 

## fC:o !NOx 

### ·------T-F'iltll. S02**~··** 

## - 

## voc 

# r· Subject

# "•m I Avg lblhr 

## I Max fblhr 

## ITona/Yeai

## rAvg lblhr Max lblhr 

### ITona/Yur! Avg lblhr J Max lbntr J Tonai'Y

..r J Avg lbJhr J Max lb"'r J**To~IYear** Avg lblhr I 

## Max lblhr 1 Tons/Yoar 

### i 

# '

-- i... 

# ' 0.15 

# I ; 0.66 

### i 

### ' 

### --··· 

### : 0.005 

### I 0.02 n ng 

# __**j__o~~ -~**  002 

# ; 

# ___ ...

# ~~ ; 0.56 

# I 2.44

__!_.

------ -' Lako Char1oa Reftne_ry 

# I I 

# j I 

# I ! 

# I I I ) 1 I ---FUG 0003 

# I i ', 

## ! 

# I 

# I ! 

# I I : 12·1111 , I ; FUG 0004 ' 

### ;----1---t---+i- ' 

# I I



# -

# ~: :: -·l:--:-;

# ~i-- . 

# _j I
-- _______j______ ' , 

# 1:**---+-j--=--~1·** 

# .**----:~T** 0001
__ 

# -j

# ----1 ! -· __;- ___

# ~~~--i·--- [ i _- Note: EmJ
..Ion**~tn** In bold are from attemate scenarto. and.,.. not Included In permittedtobta unta•otherwtae noted In afootnote.

Page 2 of2 TPORC14SEmission Pl EOT 0003 

# ..,.

EOT 0005

## ~··

EOT 0008 7-78



## '
EOT 0011 10..78 

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 13058 - Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-00027-05 Air- Minor (Synthetic) Modification
Pollutant Avg lb/hr Max lb/hr Benzene <0.001 <0.001 TOluene 0.001 0.001 Xylene (mixed isomers) <0.001 <0.001 n-Hexane 0.01 O.D1 1,3-Butadiene <0.001 2,2,4-Trimethylpentane <0.001 Benzene 0.002 Biphenyl <0.001 CresOl <0.001 Cumene 0.004 Ethyl benzene 

### ·' <0.001 Naphthalene <0.001 Phenol <0.001 Toluene 0.001 Xylene (mixed isomers) .<0.001 n-Hexane 0.001 1,3-Butadiene ·<0.001 2,2,4-Trlmethylpentane <0.001 

### Benzene 0.002 Biphenyl <0.001 Cresol <0.001 Cumene <0.001 Ethyl benzene <0.001 Naphthalene <0.001 Phenol
. <0.001 Toluene 0.001 Xylene (mixed isomers) <0.001 n-Hexane 0.001



### ---- 1,3-Butadiene <0.001 2,2,4-Trimethylpentane <0.001 Benzene <0.001 Biphenyl <0.001 Cresol <0.001
Page 1 of 8 Tons/Year <0.01 <0.01 <0.01

0.03 <0.001 <0.01 <0.01 <0.01 <0.01

0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

·----- <0.01
----·-····· <0.01



### ------- <0,001 <0.01 <0.01 <0.01 <0.01

TPORD146

# L~~-~.~~~ pt 

# IEQT

# 0011 l 1().78 - 

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 13058 ·Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-00027-05 Air • Minor(Synthetic) Modification
Pollutant 

# Avglblhr Max lblhr 

# --,---------·· Tont/Year 

### '

# ~ I Cumena <0.001 

# I <0.01 ;

.



### --- ·- ·-·- 

# --j

,Elh)'1 benzene <0.001 

### ' 

# <0.01 I 

# !Naphthalene

------------. .Phonal 

# _j_-:_o**~~-** 

# -- 1· 

# <0.001

-- 

# ·--1--------

-----

# !_<0~01-·

, 1 

# <0.01 <0.001 <0.01 Xytono (rTlxod lsomors) n·Haxane. <0.001 <0.01



# ------ EOT 0012 

### .··--- .--r----- -----· ----------r-------;---------r------- 

# 2,2,4-Trimelhy!penlane <0001 

# I <0.01 11-71 

### 1-----------t------

----- ·-·------- 

# ··--·-·**+-~~:** -----1 

# ----+--------- 1 

# <0.01 ' Benzene 

# 0.003 Biphenyt <0.001 

## 1------------+-----·-

---- <0.001
1 erasol 

# <0.001 

# I <0.01 

# I 1-----t--·li---1_ 

# <0.001 <0.01**1------------+------1------~----~**

## ~~~~_ne 

# _____________----f--<_o._o_o1

___ -+--- _ 1 

# <O01
__j

# l-~=**01**

# =--~-~~===~----·_----_-_-:_·_--_··_·-===~~-------ij**1===<=oo =·.:oo=-2:~--------:l,-_-_-**  __

# ~ :- __

-_-_- __

# :~0-1:**=~==----I** Xylene(nixedisomers) .,

# ~; Eth)'1 benzene 

# Cumene 1---------------------



# ---.**-~---** 

## - 

## ·,·--- 

# '**i=~=o------+ -n-_H_e_xa_n_e** 

# ____________ --'-'
__ o_.oo1
______1 --1--<_o_.o_1
___ ---1 EOT 

# 0013 2,2,4-Trimelh"'penlane <0.001 <0.01 12-78 1' 

## 1---------- -1---. Bonzona <0.001



## ---------- -----1-----+- 

# ____**1__<0.0~---** l <0.01 

# Bipheny! <0.001 ' CresoJ


### .----- 

### ··--·-··-----+------- --···· <0.001 1 <0.01



### ··---------- 

# icumene <0.001 <0.01 !Eth)'1

# bonzene**<O.~~~----+-------t--<_o_.01**

# _____ /

# ;N_~-~~Iha-le_ne ___________

# l--~:::~----i-------+--:-:-:-:---~: --------1 Toluene 

# <0.01 <0.001 ·----------+---,----+--- 

## ----+-- ----

# :::~xed**l~rs)** -------_

# +-~:-0-:---+-------+--:-:-·:-:------**~~~**0014
.

# -------+~-.2--j-~:;;lhy!~~~-e-------+l----:·:~~---------~,-=-============::==~:--:-:----~~~---·:_ l Biphenyl 

# L --------+---------- 

# ----,--------+--·.. ---- Crosol 0.001 <0.01



# .**------~-----------~-----L-----~-----~** 

# 0.001 0.01

Page 2 of 8 TPORO,
...Emission Pl. EOT 0014**1~78**

EOT 0015 14-78

EQT 0016 15-78 '

EOT 0018 17-78 

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AJID: 130S8 ·Pelican Reflning.Co LLC Activity.Number: PER20100003 Permit Number: 0520..00027..05 Air· Minor (Synthetic)**~odiflcation** Pollutant Avg lb/hr Max lblhr Cumene· 0.01 Ethyl benzene 0.02**Naphthalen~** 0.003 Phenol 0.004 Toluene 0.10 Xylene (mixed isomers) 0.08 n-Hexane 0.04 2,2,4-Trirnethylpentane <0.001 Benzene 0.003 Biphenyl <0.001 Cresol <0.001 Cumene <0.001 Ethyl benzene 0.001 Naphthalene <0.001 Phenol <0.001 Toluene· 0.003 Xylene (mixed isomers} 0.002 n-Hexane 0.001

·. 2,2,4-Trimethylpentane <0.001 Benzene 0.003 Biphenyl <0.001 Cresol <0.001

·-·-

# -·---------- Cumene <0.001 Ethyl benzene
. <0.001 Naphthalene <0.001 Phenol <0.001 Toluene 0.003 Xylene (mixed isomers} 0.002 n-Hexane 0.001 1,3-Butadiene <0.001 2,2,4-Trimethylpentane <0.001 Benzene 0.003 

# -+-

------·---- ---------- ------------------- Biphenyl <0.001 <
Page 3 of 8 Tons/Year 0.05 0.10 0.01 0.02 0.44 0.36 0.17 <0.01

0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

0.01
. <0.01 <0.01 <0.01

O.Q1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

0.01 0.01 <0.01 <0.001 <0.01

0.01 <0.01 

# I

TPOR0145Emlasion Pt. 

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 13058 • Pelican Refining Co LLC

. Activity Number: PER20100003 Permit Number: 0520.00027**~5** 

### Air· Minor (Synthetic) Modification

----------..,-----.·-·---- ·-·--. Pollutant Avg lblhr Max lbhlr ToniiYear - .

## -! EQT 0018 

### ··--------;·-------·-·- 

## ·--
..· 

# I cresol 

# ,-- :Cumone I --<-o.o01--**------!--~-------+-<·o-.o-1**_______1 11-71 ------------+--<-0-.0-01
___**----~--·** <_0_0_1---·-j Ethyt benzene <0.001 < <0.01 

## ----·· 

# ---- .. Naphthalene <0.001 < <0.01 Phenol <0.001 < <0.01



# ---- Toluene 0.001 

# L , ___., r <••• ··-----... <

# I~~~ 0019

# ---------+n--1.-:-:xan-uta-:-,e-na-----------f_--~-:~~.---- ·-·

# ~~~~~~~~-~--~~+-'---f------~-<-:=·-:=1-~-----=--! I <o.o1

<0.01 ?·2,4-Tnmothytpontono 1**f----------+~-------r---·-** 

## ..---. .----· --· __.. !Benzene 0.003 1 0.01 :**i'-.,8-lpho_n_yt--------------i~--<-0-.00-1**_ ..__ 

# r-- -----· ·-___ <_0

___

0_1
___ ....;; 

# 1----------+---·---- ·----·---t------j Cresol <0.001 <0.01 J 0.002

<0.001 <0.01
·-----· ·- 

# I <0.001 <0.01

·--

# ~ <0.001



### -- 

# _ _j_ <0.01

·- 

# : <0.01 

### ' '**~·~~~_n•** 

# __________ _ 'Phenol ; <0.001 

### f---

..

# --------·--i----- ··- -·- .....___.. Toluene 0.001 0.01 Xytone (nixed Isomers) <0.001 <0.01



### -- . 

## - n-Hexane 0.002 0.01



# ---

# __....

# --·---- 

# -- --- ·---
.. 

# I 

# ----r··· _,_
---- EOT 0021 1.3-Butadieno 21·78 0.01 0.03 <0.001 2.2.4·Tr\molhytpontona 0.03 0.10 <0.01**1------------+-----~** 

# -----r-------·-- ·- 

# i 'Benzene 1.20 3.81 0.06

Biphenyl <o.oo1. 

# I <o.oo1 <0.01 

# 1-------------t------ C<asol

____ .... <0 0..oo

01 1
_____

# 1 1 .

## -~~~-----1--<_o_.o_1___ 

### --i Cumono 0.02 <0.01



### - ___......__ - i ·-!----·
----

:::::· -· <:::1
___,__ 0.20 -:.:. ;_

:_:_:

# --------J,
_-Ph_=·=,;;;-
...

# ~~-- .. ____ .. ____ '

# --~- _-_ 

# _I_ _<;_;______'
__ <001 

# -= Toluono 0.56 1.79 0.03 

### f---------------1------

- ..-----·---+------ Xylene (nixed Isomers) 0.14 0.44 001 f-;E

.. -;0;.-T--;002=3:------+1.-3--B_uta_d_ie-no------------· -·--<-0.0-0; _._.. 

## _._-_-_-_-_!.**~-------** -"--------------'·---· n-Hexane 0.76 2.42 0.04 1 -t--<0001 

# _j

_ 

## _[_

___ 

# ---- Page 4 

### ot 8 TPOR0148Emission pt EQT 0023 

# '""' '

EQT 0024 1·90

EOT 0026 >-91



### --- EOT 0061 1-99 

## EMISSION RATES FOR TAP/HAP &.OTHER POLLUTANTS AIID: 13058,• 

### J;>ellcari**~efiniiig.Co** 

### LLC Activity Number: PE,R20100003 

### Permit Number: 0520-00027-05 

### Air. Mino;(Synthetic) Modification
Pollutant Avg lb/hr Max lbfhr**2,2,4-Tri":~ethylpentane** <0.001 Benzene 0.002 Biphenyl <0.001.

···---·---- Cresol <0.001 Curnene <0.001 Ethyl benzene <0.001 Naphthalene <0.001 Phenol <0.001 Toluene <0.001 Xylene (mixed isomers} <0.001 n-Hexane • 0.001 Benzene ·<0.001 ·<0.001 Copper (and compounds) <0.001 <0.001 Nickel (and compounds) <0.001 <0.001 Toluene

. <0.001 <0.001 

### -·· 2,2,4-Trimethylpentane O.o1 

### Benzene 0.14



### ·--------- Biphenyl 0.002 Cresol

. <0.001 Cumene 0.02 Ethyl benzene 0.03 NSphthalene 

## o:oo4 Phenol O.o1 Toluene 0.14 Xylene (mixed isomers) 0.1 1



# - n-Hexane 0.06



## -- 2,2

### .4·Trimethylpentane <0.001 Benzene <0.001 Biphenyl <0.001 Cresol <0.001 Cumene <0.001 Ethyl benzene <0.001 Naphthalene <0.001



## -- Page 5 of 8 Tons/Year <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.01

0.05 0.63 0.01 <0.01

O.o7 0.14 0.02 0.02 0.61 0.50

. 0.24



## ·- <0.01 <O.o1

. <0.01

<0.01 <0.01 <0.01 <0.01

TPOR01<48

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 13058 • Pel.lcan Refining Co LLC Activity Number: PER20100003 Penni! Number: 0520-{10027-{15 

### Air· Minor (Synthetic) Modifieation
Pollutant Avg lblhr 

# I Max lbhlr Phenol <0.001 

# ----T

Toluene <0.001 

# I Xylene

# (mixed isomers) <0.001 

### ! Tona/Year <0.01 <0.01 

# _!_ <0.0_1 <0.001 <0.01 1 n-Hexane

# ~eai~~----------b---------------------------~--------------r-------------+-------------~ [

## ~" Benzene <0

## 00~--- _ 

# l- < <0 01 

# I

# ~~u~_ne __ . _____________________

## !._ <O

## oo_, ___

# --l---~

# ________**-,---<_o_o~** i iEthyt benzene 1 <0.001 1 < 

# i <0.01 

# I

# l:~:::edi~~~-~-----=r-::::-· 

# r.H:------**r::=~j** ··•en 0065 ;;-------------!,!-Be-nz

__

e_ne

_____ ---------- <0.001 <0.01 '


# ....

EOT 0069 11-119



## f-ror-oo-,o

--------- 2-ra ·Cumena <0.001 Ethyl benzene <0.001 Toluene <0.001 Xylene

# (mixed**isome~)** <0.001 -----+--<_o_.oo_1
_____

# ~~:-------+---- Benzene <0.001 

## r----- --·--·------t---- .. 

# ----+------ Biphenyl <0.001 :**'------~-----------+-----··--·------;-----** 2.2.4-T**~melhylpentane**

:cresol <0.001 Cumene <0.001 

# f------------+----------+----- Eihyl benzene <0.001**---------~---** Naphthalene <0.001 ·Phenol <0.001 <0.01 

### f----------··--· ·--1-------L ····----+------1 Toluene <0.001 <0.01 

# I <0.01 <0 01 <0.01



### ----- 

## ··----- <0.001 

### )xytene (n'lxed 

### isomers}**~----------·** 

# .. -----+------ In-Hexane

__.······---------- <O_oo
__

1
_______

### i

___

### -----------t·-------------1 

# I Benzene 

# r·**-~-0.001**______ 

# +__<_o_._oo_1
______ 

## +------ Copper(and compounds) <0.001 

### j <0.001 <0.001



## ·- <0.001 

# ! !Nicl<el (and co..:;,...,nds) <0.00_1
___

# Goo,·-·

# ~c;J**oo-~,.,.,**--------

# ·----+~'~=ol=:=ee=n:=====-===··=·-**-~=- -~=-=**  ..

# =-~--=~--=~--=~--=~--~:~--·__

# :_:·_:=::======--+·~!**===:=:=:=:~: --~-----·-----1---------·--**  Copper (and COITI)OUndS) <0.001 <0.001 . 

### - <0.01



# . <0.01 

# I --- <0.001 

# I <0.001



### ------- 

# i <0.01 ,__, N_icl<

__

el_(a_nd

__

co __

"""""
___ nd

__

sl

______________ , ___ <_0_.00
__

1
_____ JT.

_ <0.001 

### :roruone <0.001 <0.001
Page 6 of8 T'POR01.teEmission Pt. FUG 0003 12-99

FUG 0004 

# , 

# ...

FUG 0005 

# , 

# .., EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AJID:

### .1~o:S8. Pelican Refining co LLC Activity Number:**PE~0.1.00003** 

### Pe.rmit Number: 0520-0g027-05**Air~** 

### Minor (Synthetic) Modification
Pollutant Avglb/hr Max lb/hr 1,3-Butadlene <0.001 2,2,4-Trlmethylpenlene <0.001 Benzene 0.003 Biphenyl <0.001 Cresol <0.001 Cumene <0.001 Ethyl benzene 0.001 Naphthalene <0.001 Toluene 0.001 Xylene (mixed isomers) '0.002 n-Hexane 0.005 1,3-Butadiene <0.001 2,2,4-Trimethylpentane <0.001 Benzene <0.001 Cumene <0.001 <0.001 Toluene <0.001 Xylene (mixed isomers) <0.001 n-Hexane <0.001 1,3-Butadiene <0.001 2,2,4-Trimethylpentane <0.001 Benzene 0.002 Cumene <0.001 Ethyl ber:'zene <0.001 Naphthalene <0.001 Toluene <0.001 TonsfYear <0.001 <0.01

O.DI <0.01 <0.01 <0.01 <0.01 <0.01

0.01 0.01 0.02 <0.001 <0.01 <0.01 <0.01

. <0.01

<0.01 <0.01 <0.01 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01**r---------·-------------+----------+----------r---------~** 

## - Xylene (mixed isomers) <0.001 <0.01 

### 1----------------·

-----**·-·-------·-+--------~+-----------** 0.001 <0.01 ' 1 

### 'F"'u"'G"'o"'o"'oac--·---+--------
......... ·- ·----· - -------- · --------- ....... ·---------- ---------- 

# -1 3-0B i,3-Butadiene
----------- <0.001

_ <0.001

### ·-~ 2,2,4-Trimethylpentane <0.001 <0.01 

# !**r----------------------r----------1-~--------t~------C** Benzene <0.001 <0.01 Biphenyt <0.001 <0.01 Cumene <0.001 <0.01
Page 7 of 6 TPORD146

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AJID: 13058- Pelican Refining Co LLC Activity Number: PER20100003 Permit Number:**0520~0027~5** 

### Air- Minor(Synthetic) Modification 

# r**~~G :~~-lon--PL---~-+T--_-_-_-_-_-_-_-_-_-** _-_

# ~~-;-l_utan~-~---------fi--A_v_a_l_blh_r___ .

# --~~----~~ax**~-~-lh_r_ --~-~1-** **-----T~o--n--a/Y---~·-ar~-~**-i

.,..._ Elhyt benzene <0.001 <0.01 

# I 1----------··--------;,-------+,**-~** 

## -·------,------- : Naphthalene <0.001 

## I j <0.01 1

TRT 0001 

# ....

jBiphenyt

## b;;;;-i;~d~n:;~.md~l--- 

# '--·


# __ .

# __ -----

# r-1~-=-~------------·

# +--**---~----** 'Ett1yt benzene I INephlhalene

### ~- ----·



# - 'Nickel (end OOIT1)0Unda) 

# I iPhenol 

# I IToluane 

# I

-- 

### [Ee(ITixod

# isomen~) n-Hoxane 

# I 

# J

- __**~ ----~-·~-s** 

# __ .. ;

0.60 

# -·---· <0.19



## ··---·-- ----· 0.002 0.17 

## I 1.64 I**~** 

### ' 1.32 0.67
Nota: Emission rates In bokt are from alternate scenarios and are not lnctuded In permttted totals unless otherwtse noted In a footnote. Emlulon 111tes attrtbuted to the UNF reflecttheaum ofthe TAP/HAP llmlta ofthelndtvldualemlnlon polnta (or caps) underthla pennlt. but do not eonalltute an 

### emlaslon up. ·

Page 8 of 8 TPOA0140

### SPECIFIC REQUIREMENTS AIID; 13058 ' Pelican Refining Co LLC Activity Number; PER20100003 Permit Number: 0520-00027-05 Air •**Mlno~** 

### (Synthetic) Modification
CRG 0001 CRG001 ·Fugitive Group Group Members: FUG 0003FUG 0004FUG OOOSFUG 0006 [40 CFR 60.592(aJI 2 [40 CFR 60.592(dJI 3 (40 CFR 60.592(e)] 4 [LAC 33:111.2122.C.I.c] 

### 5 [LAC 33:111.2122.C.I.d]

6 [LAC 33:111.2122.C.2]

7 (LAC 33:111.2122.C.3] 8 [LAC 33:111.2122.C.4] 9 [LAC 33:Ill.2122.C.5] 10 (LAC 33:111.2122.D.I.a]

II (LAC 33:111.2122.D.I.b.i]

12 (LAC 33:111.2122.D.I.b.ii]

13 (LAC 33:111.2122.D.I.b.iii]

14 [LAC 33:Ill.2122.D.I.b.iv] 

### Comply with the requirements of40 CFR 60.482-1 to 482-10 as soon as practicable, but no later than 180 days after initial startup. Subpart GGG. [40 CFR 60.592(a)] Comply with the provisions of40 CFR 60.485 except as provided in 40 CFR 60.593. Subpart GGG. [40 CFR 60.592(d)] Comply with the provisions of40 CFR 60.486 and 60.487. Subpart GGG. [40 CFR 60.592(e}] Repair according to LAC 33:lll.2122.C.3 anyregulated component observed leaking by**sigh~** 

### sound, or smell, regardless ofthe leak's concentration, except those covered under LAC 33:fii.2122.C.I.d. 

### Pumps and valves in heavy liquid service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 within 5 days ifobserved leaking by sight, sound, or smell. Repair according to LAC 33:III.2122.C.3 ifthe pump orvalve is determined to be leaking in excess ofthe applicable limits given in LAC 33:lll.2122.
. · Which Months: All Year Statistical Basis: None specified Do not locate anyvalve. except safety pressure 

### reliefvalves, at the end ofa pipe or line containing volatile organic compounds unless the end of such line is sealed 

### with a second valve, a blind flange, a plug, or a cap. Remove such sealing devices only when the line is in use, for example, when a sample 

### is being 

### taken. When the line 

### has beenused and is subsequently resealed, close the upstream valve first, followed byihe sealing device. · 

### Make every reasonable effort to'repair a leaking component; as described in LAC 33:11l.2122, within 15 days, exceptas provided. Detennine the percent ofleaking components at a process Wlit for a test period using the equation in LAC 33:111.2122.C.4. 

### Determine the total percentofleaking and unrepairable components using the equation in. LAC 33:Ili.2122.C.5. Process drains: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 annually (one time per year). If

### a reading of 1,000 ppmv or greater is recorded, a leak is detected. Ifa leak is detected, initiate repairprovisions specified in LAC 33 :111.2122.C.3. Which Months: All Year Statistical Basis: None specified Compressor seals: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). Ifa reading of5,000 ppmv or greater is recorded, a leak is detected. Ifa leak isdetected, initiate repair provisions specified in LAC 33:ll1.2122.C.3. Which Months: All Year Statistical Basis: None specified Pressure reliefvalves in gas service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times ayear). Ifa reading 

### of 1,000 ppmv orgreater is recorded, a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:Ill.2I22.C.3. Which Months: All Year Statistical Basis: None specified · 

### Valves in light liquid service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). Ifa reading of I,000 ppmv or greater is recorded, a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:III.2122.C.3. Permittee may 

### elect to comply with the alternate standards for valves in LAC 33:11l.2122.E (skip period provisions). Which Months: All Year Statistical Basis: None specified Pumps in light liquid service: VOC, Toial monitored by40 CFR60, Appendix A, Method 21 quarterly (four times a year). If

### a reading of5,000 ppmv orgreater is recorded, a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:11l.2122.C.3. Which Months: All Year Statistical Basis: None specified
Page-1 of 15 TPOR0147

### SPECIFIC REQUIREMENTS AIID: 13058- Pelican Refining Co LLC Activity Number: ·PER20100003 Permit Number: 0520.00027.05 Air - Minor (Synthetic) Modification
CRG 0001 CRG001 - Fugitive Group

15 [LAC JJ:III.llll.D.I.b.v)

16 [LAC 33:11L2122.D.I.c] 17 [LAC 33:11L2122.D.I.d.i] 18 [LAC J3:111.2122.D.I.e] 19 [LAC J3:111.2122.D.3.a]

20 [LAC J3:111.2122.0.3.b]
21 [LAC 33:111.2122 D.J c] 22 [LAC JJ:III.2122.D.J.d)

23 [LAC 3J:IIL2122F.l]

24 [LAC J3:111.2122.F]

25 [LAC JJ:111.2122.G] 

### Valves in gas service: VOC, Total monitored by40 CFR 60, Appendix A, 

### Method 21 quarterly (four times a year). ifa reading of 1,000 ppmv or greater is recorded, a leak is detected. Ifa leak is detected. initiate repair provlsions specified in LAC 33:111.2122.C.3. Permittee may elect to 

### comply with the alternate sJandards for valves in LAC 33:iil.2122.E (skip period provisions). Which Months: All Ycar Statistical Basis: None specified Pumps: Seal or closure mechanism monitored by visual inspection/determination weekly (52 time< a year). Which Months: All Year Statistical Basis: None specified Flanged connectors: Presence ofa leak monitoredbyvisual, audible, and/orolfactory weekly. Which Months: All Year Statistical Basis: None specified Instrumenmtion sy>tcms: 

### Presence ofa leak monitoredbyvisual, audible, and/or olfactoryweekly. Which Months: All Year Statistical Basis: None specified Pressure reliefvalves: VOC, Tom! monitored by40 CFR 60, Appendix A, Method 21 within 24 bours after venting to the atmosphere. Ifa reading of 1,000 ppmv or gTeater (forpetroleum refineries, SOCM!, MTBE, and polymer manufacturing industry) or 2,500 ppmv orgreater (for oatural gas processing plants) is recorded, a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:III.2122.C.3. Which Months: Ail Year Smtistical Basis: None specified Ail components: VOC, Toml monitored by4{) 

### CFR 60, Appendix A, Method 21 upon each occurrence ofa leak detected by sight, smell, or sound. unless electing to implement actions as specified in LAC 33:111.2122.C.3. 

### Which Months: Ail Year Smtistical Basis: None specified Inaccessible valves: VOC, Tomi monitored by40 CFR 60, Appendix A, Method 21 annually (at a minimum). Which Months: Ail Year Statistical Basis: None specified Unsafe-to-monitor valves: VOC, Tomi monitoredby40 CFR 60, Appendix A, Method 2I upon each occurrence ofconditions allowing these valves to bemonitored safely. Which Months: All Year Statistical Basis: None specified When a component which hils a leak that cannot he repaired, as de<cribed in LAC 33:iil.2122.C, is located, affix to the leaking component a weatherproofand readily visible tag bearing an identification number and the date the leak is located. Remove the tag after the leak has 

### been 

### repaired. Equipment/operational data recordkeeping by survey log upon each occurrence ofa leak. Include the leaking component information specified in LAC 33:11L2122.F.2.a tluoughj. Retain the survey log for 

### two years after the latter date specified in LAC 33:11L2122.F.2 and make said l.og available to DEQ upon request Submit report: Due semiannually, by the 31st ofJanuary aod July, to the Office ofEnvironmental Assessment, Air Quality Assessment Division. Include the information specified in LAC 33:111.2122.G.I through 6 for each calendar quarterduring the reporting period. 

### CRG 0002 CRG002 - External Floating RoofTanks Group**Mem~n:** EQT OOOIEQT 0023



### 26 (40 CFR 60.Jil(a)(l)) 

### Crude service: Equip with a floating roof, a vapor recovery systent, ortheir equivalents. Subpart 

### K. (40 CFR 60.112(a)(l)]

Page 2 of 15 TPOR01•7

### SPECIFIC REQUIREMENTS · AIID: 13058 'Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-40027-45 Air
- Minor (Synthetic) Modification
CRG 0002 CRG002 -External Floating RoofTanks

27 [40 CFR 60.113}

28 [LAC 33:111.2103.8] 29 [LAC 33:111.2103.D.2.a} 30 [LAC 33:111.2103.D.2.b] 31 [LAC 33:111.2103.D.2.c}
32 [LAC 33:111.2!03.D.2.d]
33 [LAC 33:111.2103.D.2.e] 34 [LAC 33:III.2103.D.2.e]

35 [LAC 33:III.2!03.D.2.e] 36 [LAC 33:III.2103.D.2.e] 37 [LAC 33:11L2103.D.2.e] 38 [LAC 33:III.2103.D.3] 39 [LAC 33:111.2103.0.3]

40 [LAC 33:III.2i03.D.4.a] 41 [LAC 33:III.2103.D.4.a] Petroleum liquid storage data recordkeeping byelectronic or hard copy at the approved frequency.Crude Service: Maintain a record ofthe petroleum liquid stored, the period ofstorage, and the rriaximurn true vaporpressure ofthat liquid during the respective storageperiod, except as provided iri 40 CFR 60.113(d). Subpart K. Equip with a submerged fill pipe. Seal closure devices required in LAC 33:111.2103.0 shall have no visible holes, tears, orother openings in the seals or seai fabric. Seal closure devices required in LAC 33:111.2103.0 shall beintact anduniformly in place around the circumference ofthe floating roofand the tank wall. Seal gap area<= I inA2/ft oftarik diameter (6.5 cm2/0.3 m), for gaps betweenthe secondary seal andtarik wall that exceed 1/8 inch (0.32 em) in width. Which Months: All Year Statistical Basis: None specified Seal gap area<= IO.inA2/ft oftank diameter (65 cm2/0.3 m), for gaps between the primary seal arid tarik wall that exceed 1/8 inch (0.32 em) in width. Which Months: All Year Statistical Basis: None specified Primary seals: Seal gap area & width monitored bymeasuretrient once everyfive years at any tank level, providedthe roofis offits legs. Which Months: All Year Statistical Basis: None specified · Equipment/operational 

### data recordkCeping 

## by electronic orhard copyupon occurrence ofevent. Keep records ofconditions that are not up to the standards described in LAC 33:111.2103.0.2, and the date(s) that the standands are not met. Noticy the administrative authority within seven days ofnoncompliance with LAC 33:Ili.2103.D.2. Secondary seals: Seal gap area 

### & width monitored bymeasurement annuallyat any tarik level, provided the roofis offits legs. Which Months: All Year StatisticalBasis: None specified Secoitdary Seal or closure mechanism monitored 

### by visual inspection/determination semiannually. Which Months: All Year Statistical Basis: None specified · Initiate repairs ofseals within seven working days ofrecognition ofdefective conditionsby ordering approp·riate parts, to avoid noncompliance with LAC 33:111.2103. Complete repairs within three months ofthe ordering ofthe repair parts. Equip all covers, seals, lids, automatic bleeder vents and rim spacevents with gaskets. 

### Provide all openings in the external floating roof(except for automatic bleeder vents, rim space Vent, and leg sleeves) with a projection below the liquid surface. Equip eachopening in the roof(except for automatic bleeder vents, rim spacevents, roofdrains, and leg sleeves) with a cover, seal or lid that is to be maintained in a closed position at all times except wheh the device is in aciual use. Keep automatic bleedervents closed at all times except when the roofis being floated offthe roofleg supports. Set rim vents tO openwhen the roofis being floated offthe roofleg supports or at the manufacturer's reconunended setting. Equip 

### imy emergency roofdrain with a slottedmembrane fabric cover orequivalent coverthat covers at least 90 percent ofthe opening. Control nonslotted guide poles andstilling wells using pole wipers and gasketing between the well and sliding cover. Control slotted guide poles using a float with wiper, pole wiper, and gasketing betweenthe well and sliding cover. . Submit notification: Due to the Office o.fEnvironmental Assessment; Air Quality Assessment Division, prior to installation ofguide poles and stilling well systems. Submit a description ofthe method ofcontrol and supporting calculations based Upon the Addendum to American Petroleum Institute Publication Number 2517 Evaporative Loss from External Floating RoofTanks, May 1994, for approval. Page 3 of 15 TPOR0147

### SPECIFIC REQUIREMENTS AIID: 13058 ·Pelican Refining Co LLC Activity Number: PER20100003 Permit Nuniber: 0520-G0027-G5 Air , Minor (Synthetic) Modification
CRG 0002 CRG002 ·External Floating RoofTanks

42 [lAC 33:111.2103.D.4.dJ

43 [lAC 33:111.2103.D.4.dJ

44 [lAC 33:111.2103.0[ 45 [lAC 33:111.2103.DJ

46 [lAC 33:111.2103.H.IJ 

### 47 [LAC 33:1l1.2103.H.3J 48 [lAC 33:1l1.2103.1[ Equipment/operaiional dala monitored by visual inspection/determination semiaJUlually. Inspect control systems required by LAC

. 33:111.2103.0.4 for rips, tear.;, visible gaps in the pole orfloat wiper, and/or missmg sliding cover gaskets.

Which Months: All Year Slatistical Basis: None spectfied Initiate repairs ofany rips, tears, visible gaps in the pole or float wiper, and/or missing sliding cover gaskets by ordering appropriate 

### parts withrn seven worlcing days afterdefect is identified, to avoid noncompliance with LAC 33:111.2103.0.4. Complete repairs within three months ofthe ordering ofthe repair 

### parts. Equip external floating roofwith a primary closure seal, consisting ofa liquid mounted seal or a mechanical shoe seal, as defined in LAC 33:!11.2103.C.I.a and b. Equip 

### with an external floari!)g roofconsisting ofa pontoon 

### type roof, double deck type roof, orexternal floating cover which will rest or float on the surface ofthe liquid contents and is equipped with a primary closure seal to close 

### the space between the roofedge and lank wall and a continuous secondary seal (a 

### rim mounted secondary) extending from 

### the floating roofto the lank wall. Determine compliance with LAC 33:!11.2103.0.2 and 4 using the methods m LAC 33:111.2103.H.I. Determine VOC maximumtrue vapor pressure using the methods in LAC 33:111.2103.H.3.a-e. 

### Equipment/operational datarecordkeeping by 

### electronic or hard 

### copycontinuously. Keep records ofthe information specified in LAC 33:111.2103.1.1

- 7, as applicable. 

### CRG 0003 CRG003 • Internal Floating RoofTanks Croup Mrmbe": £QT0011 £QT OOJIEQT 0019

49 [40 CFR 60.112(a)(I)J 50 [40CFR60.113)

51 [lAC JJ:Ili.2103.8J 52 [lAC 33:1l1.2103.C.I.aJ 53 [lAC 33:ni.2103.C.I.bJ
54 [lAC33:111.2103.C.I.cJ


### 55 [lAC 33:ni.2103.C.2J Equip with a floating roof, a vaporrecovery system, ortheir equivalents. Subpart K. [40 CFR 60.112(a)(l)] Petroleum liquid storage dala recordkeeping byelectronic orhard copy at the approved frequency. Mainlain a record ofthe petroleum liqurd stored, the period ofstorage, and the maximum true vapor prcssufc ofthat liquid during the respective storage period, except as provided in 40 CFR 60.113(d). Subpart K. Equip with a submerged fill pipe. Equip internal floating roof

### with~ liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in conlact with the liquid between

### the wall ofthe storage vessel and the floating roofcontinuously around the circwnference ofthe tank. Equip internal floating roofwith a mechanical shoe seal (melallic-type shoe seal) consisting ofa metal sheet held venically against the wall ofthe
· storage vessel by springs orweighted levers and connected by braces to the floating roof. A flexible coated fabric (envelope) spans the annular

space between the melal sheet

## and the floating roof. Equip internal floating roofwith two seals mounted one above the other so that each forms a 

### cOntinuous closure that completely covers the space between 

### the wall of

### the storage vessel and the edge of

### the internal floating roof. The lower seal maybe vapor-mounted, bul both must be 

### continuous. ·**Pro~ide** each opening in 

### the internal floating roof(except rim space vents and automatic bleeder vents) 

### with a projection below the liquid surface. In addition, provide each opening (except for leg sleeves, bleeder vents, rim space vents, column wells, ladder wells, sample wells, and stub drains) with a coverequipped with a gasket.· F..quip automatic bleedervents and rim space yents with gaskets and equip ladder wells with a sliding cover. Page 4 of 15 TPOR0,.1

### " SPECIFIC REQUIREMENTS AIID: 13058 '·Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: OS20.00027.05 Air- Minor (Synthetic) Modification
CRG 0003 CRG003 • Internal Floating Roof Tanks

56 [LAC 33:111.2103.C)

57 [LAC 33:111.2103.E.2]

58 [LAC 33:1il.2103.H.3] 59 [LAC 33:111.2103.1],


### EQT 0003 4-78 - Plant Flare

60 [40 CFR 60.104(a)(l)] 61 [40 CFR 60.105(a)(4)]

62 [40 CFR 60.106(a)] 63 [ 40 CFR 60.106] 64 [40 CFR 60.18(c)(l)] 65 [40 CFR 60.18(c)(2)] 66 [40 CFR 60.18(c)(3)(ii)]

67 [40CFR60.18(c)(4)(ii)]

68 [40 CFR 60.18(d)] 69 [40 CFR 60.18(<)] 70 [40 CFR 60.18(!)(2)] 

### Equip with an internal floating roofconsisting ofa pontoon type roof, double deck roof, orinternal flo3.ting cover which Will rest or float onthe surface ofthe liquid contents and is equipped with a closure seal to close the space between the roofedge and tank wall. All tank gaugingand sampling devices will be gas-tight except when gauging or sampling is taking place. VOC, Total

# >= 90 %control efficiencyusing a vapor loss coittrol system. This limitation does 

### !lOt apply during periods ofplannedroutine maintenance which may not exceed 240 hours-per year. Which Months: All Year Statistical Basis: None specified Determine VOC maximum true vapor pressure using the methods in LAC 33:11L2103.H.3.a-e. Eqqipritent/operational data 

### recordkeeping 

### by electronic orhard copy continuously. Keep records ofthe infonnation specified in LAC 33:Ill.2103.1.1 -7, as applicable.

Fuel gas: Hydrogen**sulfide<~** 

### 0.1 gr/dscf(230 mgldscm). Subpart

### J. [40 CFR 60.104(a)(1)] Which Months: All Year Statistical Basis: None specified Hydrogen sulfide monitored bycontinuous emission monitor (CEM) Continuously. Monitor the H2S in fuel gases before being burned in any fuel gas combustion device. Subpart

### J. [40 CFR 60.105(a)(4)] Which Months: All Year Statistical Basis: None specified Use

# as reference methods and procedures the test methods in 40 CFR 60 appendix A orother methods and procedures as specified in 40 CFR 60.106, except as provided in 40CFR 60.8(b), in conducting the performance tests required in 40 CFR 60.8. SubpartJ. 

### [40 CFR 60.106(a)] ·Determine compliance with standards using the test methods andprocedures specified in 40 CFR 60.106(a) through (k). SubpartJ. Design and operate for no visible emissions, as determined by 

### the methods specified in 40 CFR 60.18(f), except for periods not to exceeda total of5 minutes during any two consecutive hours. Subpart A. [40 CFR 60.18(c)(l)] Operate with a flame present.at all times, as determined bythe methods specified in 40 CFR 60.18({)(2). Subpart A. [40 CFR 60.18(c)(2)] Heat**content>~** 

### 200 BTU/scf(7.45 MJ/scm). Determine the net heating value ofthe gas being combusted by the methods specified in 40 CFR 60.18({)(3). Subpart A 

### [40 CFR 60.18(c)(3)(ii)] Which Months: All Year Statistical Basis: None specified Exit**Velocity>~** 

### 60and < 400 ftlsec (18.3 rnlsec and 112 rnlsec), as determined

### by the method specified in 40 CFR 60.18(f)(4). Subpart A. 

### [40 CFR 60.18(c)(4)(ii)] Which Months: All Year Statistical Basis: None specified Monitor flares to ensure that theyare operated and maintained in conformance with their designs. Applicable subparts will provide provisions stating how to monitor flares. Subpart A. 

### [40 CFR 60.18(d)] ' Operate at all times when emissions may be vented to the flare. Subpart A. [

### 40 CFR 60.18(e)] Presence ofa flame monitored by flame monitor continuously. Use a thermocouple or any other equivalent device to detect the presence ofa flare pilot flame. Subpart A. 

### [40 CFR 60.18(f)(2)] Which Months: All Year Statistical Basis: Norie specified
Page 5 of 15 TPOR0147

### EQT 0003 4-78 • Plant Flare 71 (LAC 33:111.1105}


### 72 (lAC 33:111.1105}

73 (LAC 33:111.1107}

74 (LAC 33:111509} 75 (LAC 33:111.509} 

### SPECIFIC 

### REQUIREMENTS AIID: 13058 ·Pelican Refining Co LLC Activity Number:· PER20100003 Permit Number: 0520.00027.05 Air • Minor (Synthetic) Modification**Opacity<~** 

### 20 percent, except for a combined total ofsix hours in any I 0 consecutive day period, for burning in connection 

### with pressure valve releases for control over process upsets. Which Monlhs: All Year Statislical Basis: None specified 

### Submit notification: Due to the Office ofEnvironmental Compliance as soon as possible after the start ofbuining ofpresslne valve releases for control over process upsets. Notify in accordance 

### with LAC 33:1.3923. Notification is required only if

### the upset cannot be controlled in six hours. 

### Submil report: Due in writing to the Office ofEnvironmental Compliance, Surveillance Division, within seven calendar days 

### after startup or**shutdo~** 

### if

### flaring was not the result offailure to maintain or repair equipment. Submit report 

### if

### requesting exemption from the provisions of LAC 33:11!.1105. Explain the conditions and duration ofthe startup or shutdown and list the steps necessary 10 remedy, prevent and limllthe 

### excess emissions. Minimize flaring 

### and ensure that no ambient air quality standards arejeopardized. Shall nor have visible emissions more 

### than 3 minutes/hour. Shall maintain combustion gas less than 

### or equal 0.05 percenl sulfur by byweight- PSD-LA-503. 

### EQT 0005 3·91 • Crude 

### 011 Storage Tank (TK 110-16)

76 (40 CFR 60.112b(a)(2)(ii)J

77 (40CFR60.112b(a)(2)J

78 (40CFR60.113b(b)(l)(i)J 

### Except for automatic bleeder vents and 

### rim space vents, each opening in a noncontact external floating roofstlall provide a projection below the liquid surface. Except for automatic bleeder vents, rim space 

### vents. roofdrains, and leg sleeves. equip each opening in the roofwith a gasketed cOver, seal, or lid and maintain in aclosed position at all times (i.e., no visible gap) except when the device is in actual use. Close automatic bleedervents at all times when the 

### roofis floating except when the roofis being floated offor is being landed on the roofleg supports. Set rim 

### vents to open when the roofis being floated offthe rooflegs supports orat the manufacrurer's reconunended setting. Equip aUtomatic bleeder
· vents and rim space vents with gaskets. Provide each emergency roofdrain with aslotted membrane fabric cover that covers at least 90 percent

ofthe area ofthe opening. Subpart Kb. (40 CFR 60.112b(a)(2)(ii)] Equip with an external floating roofconsisiing ofa pontoon-type or**double-<lec~** 

### type cover that rests on the 

### liquid surface in a vessel with no fixed roof. Equip with a closure device between the wall ofthe storage vessel and the roofedge. Theclosure device consisis of

### two seals, secondary above the 

### primary. The primary seal shall be either a mechanical shoe seal or a liquid-mounted seal. Exccpl as provided in 40 CFR 60.113b(b)(4), the primary seal shall completelycoverthe 

### annular space between the edge oftbe floatmg roofand tank wall. The secondary seal 

### shall completely cover the annular space between the external floating roofand the wall ofthe storage vessel in a continuous fashion except as allowed in40 CFR 60.113b(b)(4). The roofshall be floating onthe liquid at all times (i.e., offthe roofleg supports) except during inilial fill until the roofis lifted offleg supports and when the 

### tank is completelyemptied and subsequently nofilled. 

### 1beprocess offilling, emptying, or refilling wheo the roofis resting on the leg supports shall be continuous and 

### sball be accomplishro asrapidly as possible. Subpart Kb. [40 

### CFR 60.112b(a)(2)] Seal gap area & 

### width monitored by measurement atthe regulation's specified frequency. Using the procedures in 40 CFR 60.113b(b)(2) determine the gap areas and maximum gap widths between the primary seal and the wall ofthe storage vessel during the hydrostatic testing of1he vessel orwithin 60 days 

### ofthe in1tial fill with VOL and at least once every 

### 5years 

### thereafter. Subpart Kb. [40 CFR 60.113b(b)(l)(i)] 

### Which Months: All Year Statistical Basis: None specified

Page 6 of 15 TPOR0147

### SPECIFIC REQUIREMENTS AIID: 13058 ·Pelican Refining Co LLC Activity Number: PER20100003 Permit Number:**0520~0027~5** 

### Air· Minor (Synthetic) Modification
EQT 0005 3·91 • Crude Oil Storage Tank (TK 110·16)

79 [40 CFR 60.113b(b)(l)(ii))

80 [40 CFR 60.113b(b)(3)) 81 [40 CFR 60.113b(b)(4)(i)(A)] · 82 [40 CFR 60.113b(b)(4)(i)(B)] 83 [40 CFR 60.113b(b)(4)(i))
84 [40 CFR 60.113b(b)(4)(i)]

85 [40 CFR 60.113b(b)(4)(ii)(A)] 86 [40 CFR 60.113b(b)(4)(ii)(B)]
87 [40 CFR 60.113b(b)(4)(ii)(B)]

88 [40 CFR 60.113b(b)(4)(ii)(C)] 89 · [40 CFR 60.113b(b)(4)] 90 [40 CFR 60.113b(b)(5)) 91 [40 CFR 60.113b(b)(6)(i))
92 [40 CFR 60.113b(b)(6)(ii)] Seal gap area &·width monitored bymeasurement atthe regulation's specified frequency. Using the procedures in 40 CFR60.113b(b)(2) determine the gap areas and maximum gap widths between the secondary seal and the wall ofthe storage vessel within 60 days ofthe initial fill with VOL and at least once peryear thereafter. Subpart Kb. [40 CFR 60.113b(b)(l)(ii)] Which Months: All Year Statistical Basis: None specified Add the gap surface area ofeachgap location for the primary seal and the secondary seal individually and divide the sum for each seal by the nominal diameter ofthe tank and compareeachratio to the respective standards in 40 CFR 60.113b(b)(4). Subpart Kb. [40 CFR 60.113b(b)(3)] 

### Oneend ofthe mechanical shoe is to extend into the stored**liquid~** 

### and the other end is to extend a minimum vertical distance of61 em above the stored liquid sUrface. Subpart Kb. [40 CFR 60.113b(b)(4)(i)(A)] There are to be no holes, tears, orotheropenings in the shoe, primary seal fabric, or seal envelope, Subpart Kb. [40 CFR 60.113b(b)(4)(i)(B)] Seal gap area<= 212 cm"2/m oftank diameter (accumulated area) for gapsbetween the tank wall and the mechanical shoe Or liquid-mounted primary seal. Subpart Kb. [40 CFR 60.113b(b)(4)(i)] Which Months: All Year Statistical Basis: None specified Seal gap width<= 3.81 em for the width ofany portion ofany gap betweenthe tank wall and the mechanical shoe or liquid-mounted primary seai. Subpart Kb. [40 CFR 60.113b(b)(4)(i)] Which Months: All Year Statistical Basis: None specified Install the secondary seal above the primary seal so that it completelycovers the space betweenthe roofedge and the tank wall except as provided in 60.113b(b)(2)(iii). Subpart Kb
.. [40 CFR60.113b(b)(4)(ii)(A)] Seal gap width<= 1.27 em for the width ofanyportion ofany gap between the tank wall and the secondary seaL Subpart Kb. [40 CFR 60.113b(b)(4)(ii)(B)] Which Months: All Year Statistical Basis: None specified Seal gap area <= 21.2 cm'2/rilof

## tank diameter (accumulatedarea) for gaps between the tankwall andthe secondary seaL Subpart Kb. [40 CFR 60.113b(b)(4)(ii)(B)] Which Months: All Year Statistical Basis: None specified There are to.be no holes, tears, orotheropenings in the secondary seal or seal fabric. Subpart Kb,. [40 CFR 60.

## i 13b(b)(4)(ii)(C)] Make necessary repairs or

### empty the storage vessel within 45 days ofidentification in any inspection for 

### seats not meetirig the requirements listed in 40CFR60.113b(b)(4) (i) and (ii) except as specified in 40 CFR60.113b(b)(4)(iii). Subpart Kb. [40 CFR 60.113b(b)(4)] Submit notification: Due at least 30 days in advance ofany gap measurements required by40 CFR 60.113b(b)(l) to afford DEQ the opportunity to have ari observerpresent. Subpart Kb. [40 CFR 60.113b(b)(5)] Ifthe external floating roofhas defectS, the primaryseal has holes; tears, orother openings in the seal or the seal fabric, or the secondary seal has holes, tears; orotheropenings 

### in the seal orthe seal fabric, repair**~e** items as necessary so that none ofthe conditions specified in this paragraph. existbefore filling or refilling the storage vessel with VOL. Subpart Kb. [40 CFR 60.113b(b)(6)(i)] Submitnotification 

### in 

### Wfiting: Due ai least 30 days prior to the filling orrefilling ofeach storage vessel for which aninspection is required

### by 40 CFR 60.113b(6) to afford DEQ an opportunity to inspect the storage vessel prior to refilling. 

### Ifthe inspection required by paragraph40 CFR 60.113b(b)(6) is notplanned and the owner oroperatorcould not have known aboui the inspection 30 days in advance orrefilling the 

### tank, notify DEQ at least 7 days priorto the refilling ofthe storage vesseL Notifybytelephone immediately followed by written documentation
. demonstrating whythe inspection was unplarined. Alternatively, submit notification in writing including the written documentation and send by express mail so that it is received byDEQ at least 7 days priorto the refilling. Subpart Kb. [40 CFR 60.113b(b)(6)(ii)] Page 7 of 15 TPOR0147

### SPECIFIC REQUIREMENTS Al 10: 

### 13058 - Pelican Refining Co LLC Activity Number: PER20100003 PennIt Number: 0520-40027-45 Alr , Minor (Synthetic) Modification
EQT 0005 3-91 - Crude Oil Storage Tank (TK 110-16)

93 (40 CFR 60.113b(b)(6)1
94 [40CFR60.11Sb(b)(l)]

95 (40 CFR 60.11Sb(b)(2)]

96 [40 CFR 60.11Sb(b)(3))

97 [40 CFR 60.11Sb(b)(4)]

98 (40 CFR 60.116b(b)]

99 [40 CFR 60.116b(c)]

100 [LAC 33:1n.2103.B] 101 (LAC 33:111.2103.D.2.a] 102 (LAC 33:111.2103.D.2.b) )03 (LAC 33:111.2103.D.2.c)
104 [LAC 33:111.2103.D.2.d)

105 [LAC 33:1!1.2103.D.2.e] 106 [LAC 33:111.2103.D.2.e] Tank roofand seals monitored byvisual inspection/detennination at the regulation's specified frequency. Inspect the external floating roof, the primary seal, the secondary seal, and fittings each rime the storage vessel is emptied and degassed. Subpart Kb. [40 CFR 60.113b(b)(6)] Which Months: All 

### Year Statistical Basis: None specified Submit a report: Due to DEQ as an attaclunent to the notification required by40 CFR 60.7(a)(3). This report shall describe the control equipment and certifythat 

### the control equipment meets the specifications of40 CFR 60.112b(a)(2) and 60.113b(b)(2), (b)(3), and (b](4). Keep copies ofall reports for at least two years. SubpartKb. [40 CFR 60.115b(b)(1 )]
. ., Submit a report: Due to DEQ within 60 days ofperfonrring the seal gap measurements required by40 CFR 60.113b(b)(1 ). The report shall contain: I) 

### the date**ofmeasuremen~** 2) the rawdata obtained in the**measuremen~** 3) the calculations described in 40 CFR 60.113b(b)(2) and (b)(J). Keep copies ofall reports for at least two years. SubpartKb. [40 CFR 60.11 Sb(b)(2)] Gap measurement(s) recordkeeping byelectronic orbard copyupon each occurrence ofgap measurement performance, as required by40 CFR 60.113b(b). Each record shall identify the storage vessel in which 

### the measurement 

### was performed and shall contain: I] the date of**measuremen~** 2) the raw data obtained in the measurement, 3) the calculations described in 40 CFR 60.113b(b)(2) 

### and (b)(J). Keep copies of all records for at least two years. Subpart Kb. [40 CFR 60.115b(b)(3)] Submit a report: Due to DEQ within 30 days after each seal gap measurement that detects gaps exceeding the limitations specified by40 CFR 60.113b(b)(4). The report will identify the vessel and contain the information specified in 40 CFR 60.115b(b)(2) and the date the vessel 

### was emptied or

### the repairs made 

### and date ofrepair. Keep copies ofall reports for at least two years. Subpart Kb. [40 CFR 60.115b(b)(4)] Equipment/operational datarecordkeeping byelectronic orbard copycontinuously. Keep readilyaccessible records showing the dimension of the storage vessel and an analysis showing

### the capacityofthe stonlge vesseL Keep copies ofall records for the life ofthe source as specifiedby 40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)) VOL storage data recordkeeping byelectronic or hard copycontinuously. Records consis1 ofthe VOL stored, the period ofstorage, and the maximum true vaporpressure ofthat VOL during the respective s1orage period. Keep copies ofall records for at leas1 two years. Subpart Kb. [40 CFR 60.116b(c))
. Equip with a submerged fill pipe. Seal closure devicesrequired in LAC 33:11!.2103.D shall have no visible holes, tears, orother openings in the seals or seal fabric. Seal closure devices required in LAC 33:11!.2103.D shall be intact and uniformly in place around the circumference ofthe floating roofand the tank wall. Seal gap area<= I in'

### 21ft oftank diameter(6.5 cm2/0.3 m), for gaps between the secondary seal and tank wall that exceed 1/8 inch (0.32 em) in width. Which Months: All 

### Year StatiStical Basis: None specified

. Seal gap area <• 10 in'2/ft oftank diamerer (65 cm2/0.3 m), for gaps between the primary 

### seal and tank wall that exceed 118 inch (0.32 em) in

width. Which Months: All Year Statistical Basis: None specified Primary seals: Seal gap area 

### & width monirored bymeasurement onceevery five 

### years at any tank level, provided the roofis offirs legs. Which Months: All 

### Year Statistical Basis:None specified 

### Secondary Seal or closure mechanism monitored by 

### visual inspection/determination scmiannual1y. Which Months: All Year Sratistical Basis: None specified Page 8 of 15 TPORO,A1

### SPECIFIC REQUIREMENTS AIID: 13058 • Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-{10027-{15 Air • Minor (Synthetic) Modification
EQT 0005 3-91- Crude 

### 011 Storage Tank (TK 110-16) 107 [LAC 33:111.2103.D.2.e]

108 [LAC 33:111.2103.D.2.e] 109 [LAC 33:111.2103.D.2.e) 110 [LAC 33:111.2103.0.3) ·

Ill [LAC 33:111.2103.0.3) 112 [LAC 33:111.2103.D.4.a] 113 [LAC 33:111.2103.D.4.a)

114 [LAC 33:111.2103.D.4.d]
115 [LAC 33:111.2103.D.4.d]

116 [LAC 33:111.2103.D) 117 [LAC 33:lll.2103.D]

118 [LAC 33:111.2103.H.I] 119 [LAC 33:111.2103.11.3] 120 [LAC 33:111.2103.1] Equipment/operational 

### data recordkeeping 

### by electronic or hard cop)' upon occurrence ofevent. Keep records ofconditions that are not up to the standards described in LAC 33:111.2103.0.2, and the date(s) that the standards are not met. NotifY the administrative authority within seven days ofnoncompliance with LAC 33:111.2103.0.2. Initiate repairs ofseals within seven working days ofrecognition ofdefective conditions 

### by ordering appropriate parts, to avoid noncompliance with LAC 33:111.2103. Complete repairs within ihree months ofthe ordering ofthe repair parts. Secondary seals: Seal gap area & width mOnitored 

### by measureme.nt annually at any tank level, provided the roofis ofTits legs. Which Months: All Year Statistical Basis: None specified Provide all openings 

### in 

### the: external floating roof(except for automatic bleeder vents, rim space vent, and leg sleeves) with a projectionbelowthe liquid surface. Equip eachopening inthe roof(except for automatic bleeder vents, rim space vents, roofdrains, and leg sleeves) with a cover, seal or lid that is to be mairitained in a closedposition at all times except when the device is 

### in actual use. Keep automatic bleeder Vents closed at all iimes exceptWhen the roofis being floated offthe roofleg supports. Setrim vents 

### to openwhen the roofis being floated offthe roofleg supports or at the manufacturer's reCommended setting. Equip

## any emergency roofdrain with a slotted membrane fabric cover orequivalent coverthat coyers at least 90 percent Ofthe opening. Equip all covers, seals, 

### lids," automatic bleedervents and rim sj:Jace vents with gaskets. Control nonslotted guide poles and stilling wells using pole wipers and gasketing betweenthe well and sliding cover. Control slotted guide poles using a float 

### with wiper, pole wiper, and gasketingbetweenthe well and sliding**cove~.** Submitnotification: Due to the Office ofEnvironmental Assessment, 

### Air Quality Assessment**Divisio~** prior 

### to installation ofguide poles and stilling well systems. Submit a description ofthe method ofcontrol and supporting calculations basedupon the Addendum to American Petroleum Institute Publication Number 2517 EvaporativeLoss from External Floating RoofTanks, May 1994, for approval. Equipment/operational 

### data monitored byvisual**insp~ction/determination** semiannually. Inspect control systems required by LAC 33:II1.2103.D.4 for rips, tears, visible gaps in the pole or float wiper, and/or missing sliding cover gaskets. Which Months: All Year Statistical Basis: None specified Initiate repairs ofany rips, tears, visible gaps in the pole or float wiper, and/or missing sliding cover gaskets by ordering appropriate parts within seven working days after defect is identified, to avoid noncompliance with LAC 33:111.2103.0.4. Complete repairs within three months ofthe ordering ofthe repair parts. Equip external floating roofwith a primaryclosure seal, consisting ofa liquid mounted seal**~r** a mechanical shoe seal, as**~efined** in LAC 33 :Ill.2103.C.l.a andb. Equip with an external floating roofconsisting ofa pontoon type roof, double deck type roof, orexternal floating cover which will rest or float on the surface ofthe liquid contents and is equipped with a primary closure seal to close the space betweenthe roofedge and tank wall and a continuous secondary seal (a rim mounted secondary) extending from the floating roofto the tank wall. Detemiine compliance with LAC 33:Ill.2103.D.2 and4 using the methods in LAC 33:1ll.2103.H.l. Determine VOC maximum true vaporpressureusing the methods in LAC 33:!ll.2103.H.3.a-e. Equipment/operational data record.keej>ing byelectronic orhard copy continuously. Keep records ofthe information specified in LAC 33:III.2103.1.1 -7, as applicable. · 

### EQT 0008 7-78 • Crude 

### 011 Storage Tank (TK 55-{11) Page 9 of 15 TPOR0147

### SPECIFIC REQUIREMENTS AIID: 13058, Pelican Reflnlng·Co LLC Activity Number: PER20100003 Permit Number: ·**0520~0027 ~5**  

### Air
- Minor (Synthetic) Modlfli:atlon
EQT 0008 7-78- Crude Oil Storage Tank (TK**55~1)** 121 (LAC 33:111.509) Shall design, operate, monitor, test, and maintain records as required by40 CFR 60 Subpart 

### K.a- PSD-LA-73. 

### EQT0011 10-78 -Crude Oil Storage Tank 

### (TK**40~3)**

122 [LAC 33:111.509) Shall design, operate, monitor,**tes~** and maintain records as required by 40 CFR 60 Subpart 

### K.a- PSD-LA-73. 

### EQT 0014 13-78- Intermediate Petroleum Product Tank 

### (TK**30~4)** 123 [40CFR60.113)

124 [LAC 33:111.509) Petroleum liquid storage data recordkeeping by electronic or hard copy atthe approved frequency. Maintain a record ofthe petroleum liquid stored, the period ofstorage, and the maximum true vaporpressure ofthat liquid dining the respective storage period, except as provided in 40 CFR 60.113(d). Subpart K. Shall design, operate, monitor, test, and maintain records as required by 40 CFR 60 Subpart Ka- PSD-LA-73. 

### EQT 0021 21-78- Barge Loading (Refinery) 125 (LAC 33:111.501.C.6) 126 (LAC 33:111.501.C.6) 127 [LAC 33:111.501.C.6)

128 [lAC 33:111501.C.6) Ceaseusing equipment when brealcthmugh occurs and do not reswnc usc until the carbon adsorption unit has been regenerated or replaced. Submit re(l!Jrt: Due annually, bythe 

### Jist ofMarch. Submit the number ofbreakthroughs and repaires for the preceding calendar year to the Office ofEnvironnlental Compliance, Enforcement Division. Within ninety days from the issuance date ofthis permit, permitte shall submit a monitoring plan for the barge loading activities to the LDEQ-Air Quality Assessment Division. Pennitte shall implement the approved monitoring plan as soon as possible but no later than ninety days from the date ofapproval. Equipment/operational data recordkecping byelectronic or hard copyupon each occurrence ofb[eakthrough and repair. Keep records ofthe repair and number ofbreakthroughs and on site and available for inspection

### by the Offic;:c ofEnvironmental Compliance, Surveillance Division. 

### EQT 0024 1-90 -Vacuum Distillation Unit Heater 129 {40CFR60.104(a)(l)) 130 [40CFR60.105(a)(4))

131 [LAC33:111.1101.B)

132 (LAC 33:111.1311.C) Fuel gas: Hydrogen**sulfide<~** 0.1 gTidscf(230 mg/dscm). Subpart 

### 1, (40 CFR 60.104(a)(l)] Which Months: All Year Statistical Basis: Three-hour rolling average Hydrogen sulfide monitored bycontinuous emission monitor (CEM) continuously. Monitorthe H2S in fuel gases before being burned in any fuel gas combustion device. Subpart 

### 1. [40 CFR 60.105(a)(4)] Which Months: All Year Statistical Basis: None specified Opacity <= 20 percent, exceptduring the cleaning ofa fire box or building ofa new fire, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal orrapping ofprecipitators, which may have an opacity in excess of20percent for not more than one six-minute periodin any 60 consecutive minutes (U>mplies by using 

### sweet nanual gas as fuel). Which Months: All Year Statistical Basis: None specified Opacity<= 20 percent; exceptemissions mayhave an average opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes (Complies by using sweet natural gas as fuel). 

### Which Months: All Year Statistical Basis: Six-minute average Page 10 of 15 TPOR01A7

### SPECIFIC REQUIREMENTS AIID: 13058 ' Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520-00027-05- Air • Minor (Synthetic) Modification
EQT 0024 1-90 ·Vacuum Distillation Unit Heater 133 [LAC 33:11LI513] Equipment/operational datarecordkeeping 

### byelectronic orhard copycontinuously. Record and keep on site for at least two years the data required to demoristrate exemption from the prov_isions ofLAC 33:III.Chapter 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPA on request. 

### EQT 0026 5-91 • Intermediate Petroleum Product Tank (TK 55-18) 134 [40 CFR 60.116b] 

### Shall keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vessel for at least 2 years. 

### EQT 0061 1-99 ·Slop Oil Tank (TK 1-02) 135 [40CFR60.116b] 

### Shall keep readily accessible records showing the dimension ofthe storage

### vessei aDd an analysis showing the capacity ofthe storage vessel for at least 

### 2years. 

### EQT 0063 3-99 • Fire Water Pump ·Diesel Engine Driver 136 [LAC33:1ILIIOI.B] Opacity<= 20 percent, except during the cleaning ofa fire box orbuilding ofa new fire, sootblowing or lancing, charging ofan incinerator, equipment changes. ashremoval or rapping ofprecipitators, which mayhave an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. WhichMonths: All Year Statistical Basis: None specified 137 [LAC 

### 33:111.13ll.C] Opacity<=20 percent; except emissions may have an average opacityin excess of20percent for not more than one six-miriute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: Six-minUte average 

### EQT 0067 7-99 • Instrument Back-up Compressor 138 {LAC 

### 33:111.1101.8] · Opacity<=20 percent, except during the cleaning ofa fire box orbuilding ofa newfire, sootblowing or lancing, charging ofan incinerator, equipment changes, ashremoval orrapping ofprecipitators; which 

### may have an opacity in excess of20 perCent for not more than one six-minute
139 [LAC 33:l!LI31 LC]



### EQT 0070 2-78 ·Boiler B-482 period in any

### 60 consecutive minutes. · Which Months: All Year Statistical Basis: None specified Opacity<= 20 percent; exceptemissions may have an average opacity inexcess of20 percent for not more 

### than one six-minute period 

### in any 60 consecutive minutes. Which Months: All Year Statistical Basis: Six-minute average

Page11 

### of 15 TPOR0147

### EQT 0070 2·78 ·Boiler B-482 140 (LAC 33:111.1101.B)

141 (LAC 33:111.1313.C)


### EQT 0071 1·98 • Boiler B-483 142 (LAC 33:111.1101.8)

143 (LAC 33:111.1313.C) 

### SPECIFIC REQUIREMENTS

.AIID: 13058 ·Pelican Refining Co LLC Activity Number: PER20100003 PennIt Number: 0520-G0027-GS Air • Minor (Synthetic) Modification

Opacity<= 20**percenl~** except during lhe cleaning ofa fire box or building ofa new fire, sool blowing or lancing, charging ofan incinerator, equipment changes, ash removal orrapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0.6ib!MMBTU ofheat input. Which Months: All Year Statistical Basis: None specified
Opacity <= 20**percent~** except during the cleaning ofa fire box or building ofa new fire, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one six-minute 

### period in any 

### 60consecutive minutes. Which**~onths:** All Year Statistical Basis: None specified Total suspeodedpantculate <=0.61b/MMBTU ofheat input. Which Months: All Year Statistical Basis: None specified 

### TRT 0001 8·99 • Wastewater Collection & 

### Treatment

144 (40CFR60.692-2(a)(ll) 145 (40 CFR 60.692-2(•)(2))

146 (40 CFR 60.692-2(a)(3))
147 (40 CFR 60.692-2(a)(4))
148 (40 CFR 60.692-2(a)(5)) 149 (40 CFR 60.692-2(b)(l)) 150 (40 CFR 60.692-2(b)(2)) 151 (40 CFR 60.692-2(b)(l)j Equip each drain with water seal controls. Subpan QQQ. [40 CFR 60.692-2(a)(I)] Equipment/operational data monitored by visual inspection/determination once initially and monthly thereafter. Monitor drains in active service for indications oflow water levels orotherconditions that would reduce the effectiveness ofthe water seal controls. Subpart QQQ. [40 CFR 60.692·2(a)(2)) Which Months: All Year Statistical Basis: None specified Equipment/operational data monitored by visual inspection/determination once initiallyand weekly thereafter. Monitor drains out ofactive service for indications oflow water levels orotherproblems that could result in VOC emissions. Subpan QQQ. [40 CFR 60.692-2(a)(3)] Which Months: All Year Statistical Basis: Nooe specified**Eq~ipment/operational** data monitored by technically sound method once initially and semiannually thereafter. Monitor the tightly sealed cap or plug over a drain that ts out ofservice to ensure cap or plug are in place and properly installed. Subpart 

### QQQ. [40CFR 60.692-2(a)(4)] Which Months: All Year Statistical Basis: None specified

- Add water or make 

### first attempts at repair as soon as practicable, but not later than 24 hours after low water levels or missing or improperly installed caps orpiuS" are detected, except as specified in 40 CFR**60.692~.** Subpan QQQ. [40 CFR 60.692·2(a)(5)] Junction boxes: Eqmp with a cover. Ensure vent pipes are at least 

### 90 em (3 

### II) in 

### length and do not exceed 10.2 em (4 in) in diameter. Subpart 

### QQQ. 

### [40 CFR 60.692-2(b)(l)] Junction boxes: Cover must have a tight seal around the edge and he kept io place at all times, except duriog inspection 

### and maintenance. Subpart 

### QQQ. [40 CFR 60.692-2(b)(2)] Junction boxes: Equipment/operational**~ta** monitored by**vis~l** inspectionldeteimination once initially and semiannuallythereafter. Monitor to ensure the cover is in place and to ensure that the coverhas a tight seal around the edge. Subpart QQQ. [40 CFR 60.692·2(b)(3)] Which Months: All Year Statistical Basis: None specified Page t2 of 15 

## fPORO'"

### SPECIFIC REQUIREMENTS AIID: 13058' Pelican Refining Co LLC Activity Number: PER20100003 Permit Number: 0520'(10027..IJ5 Air· Minor (Syntheticj Modification
TRT 0001 8-99 • Wastewater Collection & 

### Treatment

i52 [40 CFR 60.692-2(b)(4)] i53 [40 CFR 60.692-2(c)(l)] 154 [40 CFR 60.692-2(c)(2)]

155 [40 CFR 60.692-2(c)(3)] i56 [40 CFR 60.692-2(e)] 157 [40 CFR 60.692-J(a)]

158 [40 CFR 60.692-J(b)]
159 [40 CFR 60.692-J(c)]
160 [40 CFR 60.692-J(e)]
161 [40 CFR 60.696(a)]

162 [40 CFR 60.697(a)] 163 [40 CFR 60.697(b)] 164 [40 CFR 60.697(c)]
165 [40 CFR 60.697(e)] Junction boxes: Make a ftrst effort at repair as soon as practicable, but not later thaD 15 calendardays after a broken seal orgap is identified, except as provided in 40 CFR 60.692-{i. Subpart QQQ. [40 CFR 60.692-2(b)(4)] Sewerlines: Ensure that sewerlines are not open to the atmosphere and are covered or enclosed in a manner so as to have no visual gaps or cracks injoints, seals, orotheremission interfaces. Subpart QQQ. [40 CFR 60.692-2(c)(l)] Sewerlines: Equipment/operational data monitored byvisual inspection/determination once initially and semiannually thereafter. Monitor the portion ofeach unburied sewer line for indication ofcracks, gaps, orotherproblems thatcouldresult in VOC emissions. Subpart QQQ. [40 CFR 60.692-2(c)(2)] Which Months: 

### All Year Statistical Basis: None specified Sewerlines: Make repairs as soon as practicable, bUt not later than 15 calendardays aftercracks, gaps, orotherproblems are detected, except as specified in 40 CFR 60.692-{i. Subpart QQQ. [40 CFR 60.692-2(c)(3)] Do not route refinery wasteY{ater routed through new drains and a newfirst commondownstreamjunctiori box, either as part ofa new orexisting individual drain system, through a downstream catch basin. Subpart QQQ. [40 CFR 60.692-2(e)] Equip and operate each oil-water separator

### tank, slop oil tank, storage vessel, orother auxiliarY equipment

### ~th a fixed roof, which meets the specifications in 40 CFR 60.692-3(a)(l) through (a)(5), except as provided in 40 CFR 60.692-3(d) or 60.693-2. Subpart QQQ. [40 CFR 60.692- 3(a)] Equip and operateeach oil-water separatortankor auxiliary equipment with a design capacityto treat more 

### than 16 liters per second (250 gpm) with a closedvent system and control device, which meet the requirements 40 CFR 60.692-5, except as provided in 40 CFR 60.692-3(c) or 60.693-2. Subpart QQQ. [40 CFR 60.692-3(b)] Meet the requirements of40 CFR 60.692-3(a), orcoinply with the requirements of40 CFR 60.692-3(a) for the existing fixed roofcovering a portion ofthe separatortank and complywith the requirements for floating roofs in 40 CFR 60.693-2 for 

### the remainder ofthe separator tank. Subpart QQQ. [40 CFR 60.692-3(c)] Ensure that slop oil from an oil-water separatortank and oily wastewater from slop oil handling equipmentis collected, stored, transported, recycled, reused, ordisposed ofin an enclosed system. Equip equipmentused in handling slop oil with a ftxed roofmeeting 

### the requirements of 40 CFR 60.692-3(a). Subpart QQQ. [40 CFR 60.692-3(e)] Before using any equipment installed in compliance with 40 CFR 60.692-2, 60.692-3, 60.692-4, 60.692-5, or 60.693, inspect such equipment for indication ofpotential emissions, defects, orotherproblems that may cause requirements of40 CFR 60 Subpart QQQ not to be met. Subpart QQQ. [40 CFR 60.696(a)] Retain all records required by40 CFR 60 Subpart QQQ for a period of2 years after beingrecorded unless otherwise noted. Subpart QQQ. [40 CFR 60.697(a)] Inspection records recordkeeping byeJectronic orhard copy atthe regulation's specified frequency. Keep therecords specified in 40 CPR 60.697(b)(l) through (b)(3). Subpart QQQ. [40 CFR 60.697(b)] , Inspection records recordkeeping byelectronic or hard copy attheregulatioO's specified frequency. Keep records ofthe location, date, and corrective action for inspections required by40 CFR 60.692-3(a) when a problem is identified that could result in VOC emissions.- Subpart QQQ. [40 CFR 60.697(c)] Equipment/operatiooal datarecordkeeping byelectroilicorbardeopy at the regulation's specified frequency. Keep therecords specified in 40 CFR 60.697(e)(l) through (e)(4), as applicable. Subpart QQQ. [40 CFR 60.697(e)] Page 

### h of 15 TPOR01•7

### SPECIFIC.REQUIREMENTS AI 10: 

### 13058 , Pelican Refining Co LLC Activity Number: PER20100003 Permit Number:**0520~002Hl5** 

### Air
- Minor(Synthetic) Modification
TRT 0001 8-99 , Wastewater Collection & Treatment

166 (40 CFR 60.697(1)] 167 (40 CFR 60.697(g)J

168 (40CFR60.698(b)(l)j

169 (40 CFR 60.698(c)j
170 (LAC 33:111.2109.A.Ij 171 (LAC3J:Ili.2109.A.2j

172 (LAC 33:l11.2109.A.3j
173 (LAC 33:111.2109.Cj 174 (LAC 33:111.2109.0] Equipmen!loperational datarecordkeeping by electronic orhard copycontinuously. Keep the records specified in 40CFR 60.697(1)(1] through (f)(3) for the life ofthe source in a readily accessible location. Subpart QQQ. [40 CFR 60.697(1)] Equipmen!loperational data recordkeeping by electronic or hard copy at the regulation's specified frequency. Keep plans or specifications which indicate the location ofout of. active service**~ins** covered by tightly sealed caps or plugs for the life ofthe facility in a readily accessible location. Subpart QQQ. [40 CFR 60.697(g)] Submit Notification: Due within 60 days after initial startup. Submit a certification that tbe equipment necessary to complywith 40 CFR 60 Subpart 

### QQQ has been installed arid that the required initial inspeCtions or tests ofprocess drains, sewer lines,junction boxes, oil·water separator.l, 

### and closed vent systems and control devices have beencarried out in accordance with 40 CFR 60 Subpart QQQ, Thereafter, submit a certification semiannually that all ofthe required inspections have 

### been cartiedout in accordance with 40CFR 60 Subpart QQQ. Subpart QQQ. [40 CFR 60.698(b)(l)]
. Submit report: Due initially and semiannuallythereafter. Submit a report that summarizes all inspections when a water seal

### was dryorotherwise breached, when a drain cap orplug

### was missing or improperly installed, orwhen cracks, gaps, orother problems were identified that could result in VOC emissions, including information about the repairs orcorrective action taken. Subpart QQQ. [40 CFR 60.698(c)J Equip with a container having all openings sealed 

### and totally enclosed liquid contents. All gauging and sampling devices will 

### be gas-tight except when gauging or sampling is taking place. Equip with a container furnished with a floating roof. Floatingroofshall consist ofa pontoon type, double deck type roof. or internal floating cover which rests or floats on the surface ofthe contents and is equipped with a closure seal or seals to close the space between the roofedge and
·container wall. All gauging and sampling devices will be gas-tight except when gauging or sampling is taking place. Equip with a container furnished with a vapordisposal system capable ofprocessing organic vapon and gases so as to limit their emission to the atmosphere to the sameextent as LAC 33:111.2109.A.I 

### and 2. All gaugingand sampling devices will 

### be gas-tight except when gauging or sampling is taking place. Determine compliance with LAC 33:111.2109.A using monthlyvisual inspections orone ofthe test methods in LAC**33:!11.2109.C.I~.** where appropriate. Equipmen!loperational data recordkeeping by electronic or 

### hard copycontinuously. Keep records ofthe information specified in LAC 33:111.2109.D.I and 3.


### UNF 0001 Facility- Leke Charles Refinery 175 (40 CFR 60.1 All affected facilities shall complywith all applicable provisions in 40 CFR 60 Subpart A. 176 (40 CFR 61.] All affected facilines shall complyWith all applicable provisions m 40 CFR 61 Subpart A. 177 (LAC 33:111.1103] Emissions ofsmoke which pass onto or across a public 

### road and create a traffic 

### hazard by impairment ofvisibility as defined in LAC 33:nl.lll orintensify an existing traffic hazard condition are prohibited. 178 (LAC 33:111.1109.8] Outdoor burning ofwaste material orothercombustible material is prohibited. 179 (LAC 33:111.1303.8J Emissions ofparticulate maner which pass onto·or across a public road and create a traffic hazardby impairment ofvisibiliry or intensify an existing traffic hazard condition areprohibited. Page t4 of 15 Tl"'RR147

### SPECIFIC REQUIREMENTS AIID: 13058 'Pelican Refining Co LLC Activity Number:
.PER20100003 Permit Number: 0520-00027-05 Air

- Minor (Synthetic) Modification

UNF 0001 Facility- Lake Charles Refinery



### 180 [LAC 33:111.2I13.A] Maintain best practical housekeeping and maintenance practices at the highest possible standards to reduce the quantity oforganic compounds emissions. Good housekeeping shall include, but not be limited to, the practices listed in LAC 33:lll.2113.A.l-5. 

### 181 [LAC 33:111.219) Failure to 

### pay 

### the prescribed application fee orannual fee as provided herein, within 

### 90 days after the 

### due date, 

### will constitute a violation of these regulations and shall subject the personto applicable enforcement actions under the Louisiana Environmental Quality Act including, but not limited to, revocation of sUspension ofthe applicable permit, license, registration, orvariance. · 182 [LAC 33:IU.501.C.2] No construction, modification, oroperation ofa facility which ultimately

## maY result in an initiation or increase in emission ofair contaminants as defined in LAC 33 :Ill.III shall commence until the permit application bas been approved, an appropriate permit fee paid (in accordance with LAC 33:lll.Chapter 2), and a permit (certificate ofapproval) has been issued by the permitting authority. 183 [LAC 33:IIl.50l.C.4] Operate the source in accordance with all tenns and condiiions ofthis permit. 184 [LAC 33:IIl.501.C.6] Crude oil**Throughput<~** 

### 18000 bbllday Pelican Refinery Crude Oil Throughput<= 18000 bbl/day (30- dayrolling average). Throughput shall be recorded daily. Noncompliance with this limitation is a reportable vioiation ofthe permit. Notify the Office ofEnvironmental Compliance, Enforcement Divisioit iftotal crude oil throughput exceeds the rruiximutn listed 

### in this specific condition for any 30 consecutive day period. 185 [LAC 33:IIl.50I.C.6] 186 [LAC 33:111.501.C.6] 187 [LAC 33:IIl.501.C.6] 188 [LAC 33:lll.537] 189 [LAC 33:111.5611.A] 190 [LAC 33:111.5611.8] Which Months: All Year Statistical Basis: I Dayaverage Crude oil Throughput recordkeeping byelectronic or bal-d copydaily. Keep records dfthe total crude oil throughput each day, as well as the total crude oil througbput for the last twelve 1110nths. Make records available for inspection by DEQ personnel. Throughput Crude oil Submitreport: Due annually, by the 31stofMarch. Repnrt the crude oil throughput for the preceding calendaryear to the Office ofEnvironmental Compliance, Enforcement Division. ComplY with terms and conditions incorpOrated in the permitto ensure compliance with 

### all state arid federally applicable airquality requirements and standards at the source.; and such otherpermit terms and conditions as determined bythe permitting authority to 

### be reasonable and necessary. Peimittee shall comply with the Louisiana General Conditions as set forth in LAC 33:lll.537. Submit standby plan for the reduction orelimination ofemissions during an Air Pollution Alert. Air PollutionWarning. or Air Pollution

. Emergency: Due within 30 days afterrequested by the administrative authority.

During an Air Pollution Alert, AirPollution Warning orAir Pollution Emergency, make the standbyplan available oit the premises to any person authorized by the department to enforce these regulations.

Page 15 of 15 TPOR0147