## MATERIAL SAFETY DATA SHEET

Product Name: (Directive 91/155/ EEC) Issue : 21 th Feb. 2014

i so PDG MSDS No : R 4209

1. Identification of Substance/Preparation and of the company/Undertaking

PRODUCT NAME : i so PDG

SUPPLIER : NIPPON NYUKAZAI CO.,LTD

ADDRESS :4

- 1 N ihonbashi K obunacho C huo

- ku TOKYO 103

- 0024 JAPAN

TELEPHONE NUMBER : +81

- 3

- 5651

- 5640

EMURGENCY TELEPHONE NUMBER : +81

- 44

- 266

- 8916

REC OMMENDED USE AND RESTRICTION ON USE :

2 . Hazards Identification

EMERGENCY OVERVIEW

Harmful if inhaled. Causes eye burns. Causes respiratory tract and skin irritation.

Combustible liquid and vapor. Do not get in eyes, on skin, or on clothing. Keep away all ignition s ources.

Avoid breathing vapor or mist. Keep container tightly closed.

Wash thoroughly after handling. Use only with adequate ventilations.

POTENTIAL HEALTH EFFECTS :

INHALATION : May be harmful if inhaled. May cause irritation. Additional effects may i nclude nausea,

blood in the urine, difficulty breathing, headache and dizziness.

SKIN CONTACT : May cause irritation. Additional effects may include nausea, headache and dizziness.

EYE CONTACT : May cause burns. Additional effects may include eye damage.

INGESTION : May cause vomiting, stomach pain, headache, dizziness and liver and kidney damage.

3 . Composition/Information on Ingredients

PRODUCT NAME : i so PDG

CHEMICAL NAME : Diethyleneglycol isopropyl ether

CHEMICAL FAMILY : Aliphatic ether alcohol

FORMU LA : (CH3)2CHO(CH2CH2O)2H

SUBSTANCE OR MIXTURE : SUBSTANCE

INGREDIENT AND CONCENTRATION RANGE

Ingredient Range CAS No.

Diethyleneglycol isopropyl ether 100 % 5412

- 01

- 1

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## MATERIAL SAFETY DATA SHEET

Product Name: (Directive 91/155/EEC) Issue : 21 th Feb. 2014

i so PDG MSDS No : R4209

4. First Aid Measures

INHALATION : Remove victim exposure area to safe area immediately. Perform artificial respiration if

necessary. Keep person warm and at rest.

Treat symptomatically and supportively. Get medical attention immediately.

SKIN CONTACT : Remove contaminated clothing and shoes immediately. Wash with soap or mild

detergent and large amounts of water until no evidence of chemical remains ( at least 15

- 20 minutes). Get

medical attention immediat ely.

EYE CONTACT : Wash eye immediately with large amounts of water or normal saline, occasionally

lifting upper and lower lids, until no evidence of chemical remains ( at least 15

- 20 minutes). Get medical

attention immediately.

INGESTION : If victim is cons cious, immediately give 2 to 4 glasses of water, and induce vomiting by

touching finger to back of throat. Get medical attention immediately.

NOTE TO PHYSICIAN : No specific antidote. Treat symptomatically and supportively.

5. Fire Fighting Measures

Modera te fire hazard when exposed to heat or flame. Vapor

- air mixture are explosive above flash point.

FLASH POINT (°C): 98

EXPLOSION LIMIT ( vol. %): LEL ; 1.7 UEL ; 20

AUTO IGNITION LIMIT (°C): not determined.

EXTINGUISH MEDIA : Dry chemical, carbon dioxide, water spra y or regular foam.

FIRE FIGHTING INSTRACTION : Move container from fire area if you can do it without risk. Apply

cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from

ends of tanks. For massive fire i n cargo area, use unmanned hose holder or monitor nozzles ; if this is

impossible, withdraw from area and let fire burn.

Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due

to fire. Isolate for 1/2 mile in all directions if tank, rail car tank truck is involved in fire. Do not extinguish

unless flow can be stopped. Apply water from as far a distance as possible in flooding quantities as a fog,

as solid streams may be ineffective.

Keep containers cool with w ater in flooding quantities. Avoid contaminating water sources and sewers.

Do not breath vapors ; Keep upwind.

HAZARDOUS COMBUSTION PRODUCTS : Thermal decomposition products may include toxic oxides

of carbon.

6. Accidental Release Measures

OCCUPATIONAL SPILL : Shut off ignition sources. Stop leak if you can do it without r isk.

Use water spray to reduce vapors. For small spills, take up with sand or other absorbent material and

place into containers for later disposal. For larger spills, dike far ahead of spill for later disposal.

No smoking, flames in hazard area. Keep unn e cessary people away ; isolate hazard area and restrict

entry.

7. Handling and Storage

Observe all federal, state and local regulations when storing this substance.

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## MATERIAL SAFETY DATA SHEET

Product Name: (Dire ctive 91/155/EEC) Issue : 21 th Feb. 2014

i so PDG MSDS No : R4209

8. Exposure controls/Personal Protection

CONTROL PARAMETER : ACGIH : not established.

PERSONAL PROTECTIVE EQUIPMENT :

VENTI LATION : Provide local exhaust or process enclosure ventilation to meet the published exposure

limits.

EYE/FACE PROTECTION : Employee must wear splash

- proof or dust

- resistant safety goggles to

prevent contact with this substance.

Emergency wash facilities : Where there is any possibility that an Employee’s eyes and/or skin may be

exposed to this substances, the employer should provide an eye wash fountain and quick drench shower

within the immediate work area for emergency use.

CLOTHING : Employee must wear ap propriate protective ( impervious ) clothing and equipment to

prevent repeated or prolonged skin contact with this substance.

HAND PROTECTION : Employee must wear impervious gloves

. RESPIRATOR : The following respirators are recommended based on information found in the physical

data, toxicity and health effects sections. They are ranked in order from minimum to maximum

respiratory protection.

The specific respirator selected must be based on contamination levels found in the work place, must be

based on the speci fic operation, must not exceed the working limits of the respirator and must be jointly

approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health

Administration ( NIOSH

- MSHA).

Any chemical cartridge respirator with organic vapor cartridge ( s) and a full face piece

. Any gas mask with organic vapor canister ( chin

- style or front

- or back

- mounted canister), which a full

face piece

. Any type ‘C’ supplied

- air respirator with a full face piece operated in pressure

- demand or other positive

pressure mode or with a full face piece , helmet or hood operated in a continuous flow mode. Any

self

- contained breathing apparatus with a full face piece operated in pressure demand

or other positive pressure mode.

9. Physical and Chemical Property

PHYSICAL FORM AND ODOR : Colorless liquid with a characteristic odor.

BOILING POINT (°C): 207 ( 760 mmHg )

REFREEZING POINT (°C): <

- 70

VAPOR PRESSURE ( kPa at 20 °C): 0.066

SPECIFIC GRAVITY ( 20 °C): 0.963

DECOMPOSITION TEMPERATURE °C ) : Not available.

HAZARD DECOMPOSIT ION PRODUCTS : Carbon monoxide, carbon dioxide.

SOLBILITY IN WATER : Soluble.

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## MATERIAL SAFETY DATA SHEET

Product Name: (Directive 91/155/EEC) Issue : 21 th Feb. 2014

i so PDG MSDS No : R4209

10. Stability and Reactivates

STABILITY : Stable under normal temperature and pressure.

HAZARDOUS POLYMERIZATION : Will not occur.

CONDITION TO AVOID : Avoid contact with heat, sparks, flames, or other so urces of ignition. Vapors

may be explosive. Avoid overheating of containers ; containers may violently rupture in heat of fire. Avoid

contamination of water sources.

INCOMPATIBILITIES : No data available.

HAZARDOUS DECOMPOSITION : Thermal decomposition produc ts may include toxic oxides of carbon.

11. Toxicological Information

TOXICOLOGICAL INFORMATION :

IRRITATION DATA : ( eye

- rabbit ) 5 ul/24H Standard Draize test Moderate ( 1 )

TOXICITY DATA : LD50 ( oral

- rat ) 11300 ul/kg ( 1 )

LD50 ( skin

- rabbit ) 16 ml/kg ( 1 )

12. Eco logical Information

BIODEGRADABILITY : No data available

BIOACCUMULATION : No data available

13. Disposal Consideration

Review federal, provincial and local government requirements prior to disposal. Disposal by incineration

or landfill may be acceptable.

14. Transport Information

Ensure this material in compliance with federal requirements and ensure conformity to local regulations.

15. Regulation Information

Follow all regulations in your country or region

INVENTRY ENCS(JAP AN) Yes

TSCA(USA) No

EINECS(EU) Yes

16. Other Information

SELECTED BIBLIOGRAPHY

(1)Registry of Toxic Effects of Chemical Substances 2006 edition NO. KL7370650

To the best of the manufacturer's knowledge, the information contained herein is accurate. However, neither the manufactu rer, nor any of

its affiliates, make any representations or warranties (expressed or implied), nor assumes any liability (in cluding liability for any dire ct,

incidental, consequential, or other damages) with respect to the accuracy or completeness of the information contained herein. Such

informat ion may be (without limitation) invalid if the specified material is used in combi nation with another, in a particular process, or

under unusual conditions. De termination of suitability of ny material for any given purpose is the sole responsibility of the user who

assumes all risk and responsibility there fore. All materials may prese nt unknown hazards and should be used with appropriate caution.

The manufacturer cannot and does not guarantee that the hazards described herein are the only one that exist s

.

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