# Prepared for : Blue Mountain Environmental

Project : 2265

Cogentrix



# Analytical Data Package

Analysis: CTM-033 / OTM-028

Maxxam Job 

# #: B036923

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

## I hereby certify that to the best of my knowledge all analytical data presented in this report:

3⁄4 Has been checked for completeness. 3⁄4 Is accurate, legible and error free. 3⁄4 Has been conducted in accordance with approved SO P’s and that all deviations are clearly listed in the Case Narrative. 3⁄4 This report has been generated in .pdf format.

Review Performed By:



# Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

# Glossary of Terms

3⁄4 MDL represents the Minimum Detection Li mit below which the laboratory cannot confirm the presence of the analyt e to the 95% confidence level. 3⁄4 RDL represents the Reportable Detection Li mit and is usually set at a value equivalent to the lowest calibration standard. 3⁄4 Acceptance Criteria are values used by the laborator y to determine that a process is in control. 3⁄4 Accuracy is the degree of agreemen t of a measured value with the true or expected value. 3⁄4 Calibration Standards are a set of solutions containing the analytes of interest at a specified concentration.
3⁄4 

# Calibration Verification Standard consists of a calibration standard solution of intermediate concentration (mid-point in itial calibration level) used to access whether the initial calibration is still valid
3⁄4 

# Certified Reference Material is a stable homogenous material that is certified by repetitive analysis from a supplier who is certified to genera te said materials.
3⁄4 

# Internal Standard a deuterated or 13 

# C-labelled analyte that is added to a sample extract prior to instrumental analysis to compensate for injection variablity.
3⁄4 

# Isomer is a member of a group of compounds that differ from each other only in the locations of a specific number of co mmon substituent atoms or groups of atoms on the parent compound.
3⁄4 

# Method Blank is a laboratory control sample using reagents that are known to be free of contamination.
3⁄4 

# Precision is the degree of agreement between the data generated from repetitive measurements under specific conditions.
3⁄4 

# Quality Assurance is a system of activities whos e purpose is to provide the producer or user of a product with the assurance that the product meets a defined standard of quality.
3⁄4 

# Quality Control is the overall system of activitie s whose purpose is to control the quality of a product so that it me ets the needs of the end user.
3⁄4 

# RSD is the relative standard deviation.
3⁄4 

# Blank Spike is a laboratory control sample that has been fortified with native analytes of interest.
3⁄4 

# Window Definng Mixture is a solution containing only the earliest and latest eluting congeners within each homologous gr oup of target analytes on a specified GC column.
3⁄4 

# RPD or Relative Percent Difference. A meas ure used to compare duplicate sample analysis.
3⁄4 

# EMPC/NDR – Peak detected does not meet ratio criteria and has resulted in a higher detection limit.

# 1.0 Project Narrative

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

### PROJECT NARRATIVE

Maxxam Analytics (Burlington ON) Maxxam Job #: B036923

Client: Blue Mountain Environmental Client Project: 2265 COGENTRIX

I. SAMPLE RECEIPT/ANALYSIS

a) Sample Listing

Maxxam Client Date Date Date Date ID Sample ID Sampled Received Prepped Run Hydrogen Cyanide in Impingers
FL2196 DI H2O BLANK-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07 FL2197 2N NAOH BLANK-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07 FL2198 RUN 1-IMP CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07 FL2199 RUN 2-IMP CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07
FL2200 RUN 2-IMP 4 CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07
FL2201 RUN 3-IMP CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07
FL2202 RUN 3-IMP 4 CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/06 2010/04/07 Hydrogen Halides in NaOH Imp.
FL2196 DI H2O BLANK-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10 FL2197 2N NAOH BLANK-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10 FL2198 RUN 1-IMP CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10 FL2199 RUN 2-IMP CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10
FL2200 RUN 2-IMP 4 CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10
FL2201 RUN 3-IMP CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10
FL2202 RUN 3-IMP 4 CATCH+RINSE-M26A 2010/03/23 2010/03/26 2010/04/10 2010/04/10 Inorganic Condensable PM (OTM28)
FL2120 BLANK-CONGENTRIX-M28 2010/03/23 2010/03/26 2010/04/08 2010/04/08
FL2121 RUN 1-CONGENTRIX-M28 2010/03/22 2010/03/26 2010/04/08 2010/04/08
FL2122 RUN 2-CONGENTRIX-M28 2010/03/22 2010/03/26 2010/04/08 2010/04/08
FL2123 RUN 3-CONGENTRIX-M28 2010/03/23 2010/03/26 2010/04/08 2010/04/08 Organic Condensable PM (OTM28)
FL2120 BLANK-CONGENTRIX-M28 2010/03/23 2010/03/26 2010/04/06 2010/04/06
FL2121 RUN 1-CONGENTRIX-M28 2010/03/22 2010/03/26 2010/04/06 2010/04/06
FL2122 RUN 2-CONGENTRIX-M28 2010/03/22 2010/03/26 2010/04/06 2010/04/06
FL2123 RUN 3-CONGENTRIX-M28 2010/03/23 2010/03/26 2010/04/06 2010/04/06

b) Shipping Problems: none encountered

c) Documentation Problems: none encountered Run Date is defined as the date of injection of the last calibration standard (12 hours or less) prior to the samples analyzed within that run sequence. Therefore the time of calibration injection that defines the run date is always within 12 hours of the time of sample injection.

### II. SAMPLE PREP:

No problems encountered

III. SAMPLE ANALYSIS:

See also comments within the appropriate Certificate of Analysis

a) Hold Times: all within recommended hold times

b) Instrument Calibration: all within control limits

c) Quality Control: All applicable QC meets control criteria, except where otherwise noted.

d) All analytes requiring manual intergration(s) are noted on the sample chromatograms

2010/04/30 Clayton Johnson, Project Manager Date I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for other than the
conditions detailed above.

In addition, I certify, that to the best of my knowledge and belief, the data as reported are true and accurate. Release of the data contained in this data package has been authorized by the cognizant laboratory official or his/her designee, as verified by this signature.

# 2.0 Summary Report

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

### Your Project #: 2265 Site: COGENTRIX Your C.O.C. #: 0813

Attention: Jim Phillippi Blue Mountain Environmental 1191 Pittsburgh Rd Valencia, PA USA 16059

Report Date: 2010/04/13



## CERTIFICATE

OF ANALYSIS

MAXXAM JOB #: B036923 Received: 2010/03/26, 19:39

Sample Matrix: Impinger Solution # Samples Received: 7

Date Date Method Analyses Quantity Extracted Analyzed Laboratory Method Reference Hydrogen Cyanide in Impingers 7 2010/04/06 2010/04/07 EPA CTM-33 Hydrogen Halides in NaOH Imp. (1 ) 7 2010/04/10 2010/04/10 BRL SOP-00108 EPA Modified M26A Volume of Sodium Hydroxide Impinger 7 N/A 2010/04/07



### Sample Matrix: Stack Sampling Train # Samples Received: 4

Date Date Method Analyses Quantity Extracted Analyzed Laboratory Method Reference Organic Condensable PM (OTM28) (2 ) 4 2010/04/06 2010/04/06 BRL SOP-00120 EPA OTM 28 Inorganic Condensable PM (OTM28) (2 ) 4 2010/04/08 2010/04/08 BRL SOP-00120 EPA OTM 28 Weight of DCM Received 4 N/A 2010/04/06 Weight of Water from Impingers 4 N/A 2010/04/06

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.

(1) This test was performed in Maxxam Mississauga under Maxxam Burlington SCC Accreditation (2) This is a non-accredited test.



### Encryption Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

CLAYTON JOHNSON, Project Manager Email: Clayton.Johnson@maxxamanalytics.com Phone# (905) 817-5769

====================================================================

Page 1 of 9

### Your Project #: 2265 Site: COGENTRIX Your C.O.C. #: 0813

Attention: Jim Phillippi Blue Mountain Environmental 1191 Pittsburgh Rd Valencia, PA USA 16059

Report Date: 2010/04/13



## CERTIFICATE

OF ANALYSIS
-2- Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 2

Page 2 of 9

### Blue Mountain Environmental Maxxam Job #: B036923 Client Project #: 2265 Report Date: 2010/04/13 Project name: COGENTRIX



### RESULTS OF ANALYSES OF IMPINGER SOLUTION

Maxxam ID F L 2 1 9 6 F L 2 1 9 7 F L 2 1 9 8 F L 2 1 9 8 Sampling Date 2010/03/23 2010/03/23 2010/03/23 2010/03/23

U n i t s DI H2O RDL 2N NAOH RDL RUN 1-IMP RUN 1-IMP RDL QC Batch BLANK-M26A BLANK-M26A CATCH+RINSE-M26A CATCH+RINSE-M26A Lab-Dup

Volume ml 360 1 200 1 950 N/A 1 2116906
Cyanide (CN) ug <40 40 <400 400 <2000 <2000 2000 2116905
Hydrochloric Acid ug <24000 24000 <24000 24000 <110000 <110000 110000 2121248
Hydrofluoric Acid ug <16000 16000 <16000 16000 <76000 <76000 76000 2121248

N/A = Not Applicable RDL = Reportable Detection Limit QC Batch = Quality Control Batch

Maxxam ID F L 2 1 9 9 F L 2 2 0 0 F L 2 2 0 1 Sampling Date 2010/03/23 2010/03/23 2010/03/23

U n i t s RUN 2-IMP RDL RUN 2-IMP 4 RDL RUN 3-IMP RDL QC Batch CATCH+RINSE-M26A CATCH+RINSE-M26A CATCH+RINSE-M26A

Volume ml 810 1 360 1 910 1 2116906
Cyanide (CN) ug <1000 1000 1200 500 <1000 1000 2116905
Hydrochloric Acid ug <78000 78000 <30000 30000 <78000 78000 2121248
Hydrofluoric Acid ug <52000 52000 <20000 20000 <52000 52000 2121248

RDL = Reportable Detection Limit QC Batch = Quality Control Batch

Maxxam ID F L 2 2 0 2 Sampling Date 2010/03/23

U n i t s RUN 3-IMP 4 RDL QC Batch CATCH+RINSE-M26A

Volume ml 440 1 2116906
Cyanide (CN) ug 1000 600 2116905
Hydrochloric Acid ug <36000 36000 2121248
Hydrofluoric Acid ug <24000 24000 2121248

RDL = Reportable Detection Limit QC Batch = Quality Control Batch

Page 3 of 9

### Blue Mountain Environmental Maxxam Job #: B036923 Client Project #: 2265 Report Date: 2010/04/13 Project name: COGENTRIX



### RESULTS OF ANALYSES OF STACK SAMPLING TRAIN

Maxxam ID F L 2 1 2 0 F L 2 1 2 1 F L 2 1 2 2 Sampling Date 2010/03/23 2010/03/23 2010/03/22 COC Number 0813 0813 0813 U n i t s BLANK-CONGENTRIX-M28 RUN RUN RDL QC Batch 1-CONGENTRIX-M28 2-CONGENTRIX-M28

Weight g 280 410 400 0.1 2116643
DCM Weight g 360 230 190 0.1 2116642
Inorganic Condensible PM mg 9.0 11 12 0.50 2119512
Organic Condensible PM mg <1.0 2.5 2.5 1.0 2116641

RDL = Reportable Detection Limit QC Batch = Quality Control Batch

Maxxam ID F L 2 1 2 3 Sampling Date 2010/03/23 COC Number 0813 U n i t s RUN RDL QC Batch 3-CONGENTRIX-M28

Weight g 360 0.1 2116643
DCM Weight g 190 0.1 2116642
Inorganic Condensible PM mg 9.9 0.50 2119512
Organic Condensible PM mg 1.1 1.0 2116641

RDL = Reportable Detection Limit QC Batch = Quality Control Batch

Page 4 of 9

### Blue Mountain Environmental Maxxam Job #: B036923 Client Project #: 2265 Report Date: 2010/04/13 Project name: COGENTRIX



### Test Summary

Maxxam ID FL2120 Collected 2010/03/23 Sample ID BLANK-CONGENTRIX-M28 Shipped Matrix Stack Sampling Train Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Organic Condensable PM (OTM28) 2116641 2010/04/06 2010/04/06 MGE Inorganic Condensable PM (OTM28) 2119512 2010/04/08 2010/04/08 FMO Weight of DCM Received 2116642 N/A 2010/04/06 Weight of Water from Impingers 2116643 N/A 2010/04/06 FMO

Maxxam ID FL2121 Collected 2010/03/22 Sample ID RUN 1-CONGENTRIX-M28 Shipped Matrix Stack Sampling Train Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Organic Condensable PM (OTM28) 2116641 2010/04/06 2010/04/06 MGE Inorganic Condensable PM (OTM28) 2119512 2010/04/08 2010/04/08 FMO Weight of DCM Received 2116642 N/A 2010/04/06 Weight of Water from Impingers 2116643 N/A 2010/04/06 FMO

Maxxam ID FL2122 Collected 2010/03/22 Sample ID RUN 2-CONGENTRIX-M28 Shipped Matrix Stack Sampling Train Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Organic Condensable PM (OTM28) 2116641 2010/04/06 2010/04/06 MGE Inorganic Condensable PM (OTM28) 2119512 2010/04/08 2010/04/08 FMO Weight of DCM Received 2116642 N/A 2010/04/06 Weight of Water from Impingers 2116643 N/A 2010/04/06 FMO

Maxxam ID FL2123 Collected 2010/03/23 Sample ID RUN 3-CONGENTRIX-M28 Shipped Matrix Stack Sampling Train Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Organic Condensable PM (OTM28) 2116641 2010/04/06 2010/04/06 MGE Inorganic Condensable PM (OTM28) 2119512 2010/04/08 2010/04/08 FMO Weight of DCM Received 2116642 N/A 2010/04/06 Weight of Water from Impingers 2116643 N/A 2010/04/06 FMO

Maxxam ID FL2196 Collected 2010/03/23 Sample ID DI H2O BLANK-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Page 5 of 9

### Blue Mountain Environmental Maxxam Job #: B036923 Client Project #: 2265 Report Date: 2010/04/13 Project name: COGENTRIX



### Test Summary

Maxxam ID FL2197 Collected 2010/03/23 Sample ID 2N NAOH BLANK-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Maxxam ID FL2198 Collected 2010/03/23 Sample ID RUN 1-IMP CATCH+RINSE-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Maxxam ID FL2198 D u p Collected 2010/03/23 Sample ID RUN 1-IMP CATCH+RINSE-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S

Maxxam ID FL2199 Collected 2010/03/23 Sample ID RUN 2-IMP CATCH+RINSE-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Maxxam ID FL2200 Collected 2010/03/23 Sample ID RUN 2-IMP 4 CATCH+RINSE-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Maxxam ID FL2201 Collected 2010/03/23 Sample ID RUN 3-IMP CATCH+RINSE-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Page 6 of 9

### Blue Mountain Environmental Maxxam Job #: B036923 Client Project #: 2265 Report Date: 2010/04/13 Project name: COGENTRIX



### Test Summary

Maxxam ID FL2202 Collected 2010/03/23 Sample ID RUN 3-IMP 4 CATCH+RINSE-M26A Shipped Matrix Impinger Solution Received 2010/03/26

Test Description Instrumentation Batch Extracted Analyzed Analyst Hydrogen Cyanide in Impingers IC 2116905 2010/04/06 2010/04/07 LLE Hydrogen Halides in NaOH Imp. IC/SPEC 2121248 2010/04/10 2010/04/10 A_S Volume of Sodium Hydroxide Impinger 2116906 N/A 2010/04/07 LLE

Page 7 of 9

### Blue Mountain Environmental Maxxam Job #: B036923 Client Project #: 2265 Report Date: 2010/04/13 Project name: COGENTRIX

GENERAL COMMENTS

DI water rinse received in plastic bottles.

Sample FL2120-01: INORGANIC EXTRACTION : Whitish residue found in aluminum dish.

Sample FL2121-01: ORGANIC EXTRACTION : Oily material found in vial. INORGANIC EXTRACTION : Whitish residue with brown particles found in aluminum dish.

Sample FL2122-01: ORGANIC EXTRACTION : Oily material found in vial. INORGANIC EXTRACTION : Whitish residue found in aluminum dish.

Sample FL2123-01: ORGANIC EXTRACTION : Whitish residue found in vial. INORGANIC EXTRACTION : Whitish residue with brown particles found in aluminum dish.

RESULTS OF ANALYSES OF IMPINGER SOLUTION

Hydrogen Cyanide in Impingers: Except Reagent blank, All other samples are Improperly preserved, pH<12.0

Results relate only to the items tested.

Page 8 of 9

### Blue Mountain Environmental Attention: Jim Phillippi Client Project #: 2265 P.O. #: Project name: COGENTRIX



### Quality Assurance Report

Maxxam Job Number: GB036923

QA/QC Date Batch Analyzed Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits 2116641 MGE Spiked Blank Organic Condensible PM 2010/04/06 91 % 70 - 130

Spiked Blank DUP Organic Condensible PM 2010/04/06 90 % 70 - 130 RPD Organic Condensible PM 2010/04/06 1.2 % 20 Method Blank Organic Condensible PM 2010/04/06 <1.0 mg 2116905 LLE Matrix Spike

(FL2198) Cyanide (CN) 2010/04/07 93 % 80 - 120 Spiked Blank Cyanide (CN) 2010/04/07 96 % 90 - 110 Method Blank Cyanide (CN) 2010/04/07 <40 ug RPD - Sample/Sample Dup Cyanide (CN) 2010/04/07 NC % 20 2119512 MGE Method Blank Inorganic Condensible PM 2010/04/08 <0.50 mg 2121248 A_S Matrix Spike

(FL2198) Hydrochloric Acid 2010/04/10 100 % 80 - 120

Hydrofluoric Acid 2010/04/10 107 % 80 - 120 Spiked Blank Hydrochloric Acid 2010/04/10 100 % 90 - 110

Hydrofluoric Acid 2010/04/10 99 % 90 - 110 Method Blank Hydrochloric Acid 2010/04/10 <24000 ug

Hydrofluoric Acid 2010/04/10 <16000 ug RPD - Sample/Sample Dup Hydrochloric Acid 2010/04/10 NC % 20

Hydrofluoric Acid 2010/04/10 NC % 20

Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement. Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference. Spiked Blank: A blank matrix to which a known amount of the analyte has been added. Used to evaluate analyte recovery. Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination. NC (RPD): The RPD was not calculated. The level of analyte detected in the parent sample and its duplicate was not sufficiently significant to permit a reliable calculation.

Page 9 of 9

# 3.0 Sample Custody

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

# 4. 3 Sample Chromatograms

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

# CTM-033

- 

# Draft Method for Sampling and Analysis of Hydrogen Cyanide Emissions from Stationary Sources

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

### Maxxam Analytics CAM FCD-00839/01 Data Package

* Please note any action or anomalies Client ID: impacting this set of samples Maxxam Job #: B036923

Analysis Worksheet Run Date Run # Start Lab ID End Lab ID START END 

### Analyst ID Hydrogen Cyanide 2116905 

### 2010/04/07 1 FL2196 FL2202 27 35 

### LLE

Actions: *Impacted Sample ID's

Bottle discrepancies NO

Interferences observed NO

Reintegrations performed YES

Dilutions performed NO

Field / Trip blanks missing NO

Othe r

Explanation/comments:

Re-integrated due to poor automated baseline construction . Inorganic Analysis Action / Comment For m

Blue Mountain Environmental

Autosampler IndexMaxxam Analytics CAM FCD-00839/01

M33-CN

RUN DAT E 2010/04/07 Prepared Traceability ANALYS T L L e 2010/03/15 good INSTRUMENT DX 600 2009/11/03 good 2010/04/06 good TESTCODE CNM33-IP 2010/04/06 good 2010/04/06 good COMPONENT 2010/04/06 good 2010/04/07 good Spike (mg/L ) 0.500 Units factor 1.038

St d Actua l Count s Method Criteri a Limit s Expecte d Result s ID Amoun t - > 0.995 0.9999 1 0.000 0.0000 ± 0.075 1.500 1.5253 2 0.100 1.2914 ± 0.15 1.500 1.5351 3 0.500 14.4281 - < 0.025 4 1.000 31.0856 ± 0.050 0.500 5 1.500 46.7362 25

- 6 2.000 62.7087 80 - 1.20 100 - < 0.025
± 0.150 1.000 Hydrogen Cyanide Intermediate Mixed Ref. Standard (IR) Working Calibration Standards Working Reference Standards Standard / Reagent Stock Calibration Standard Stock Reference Standard Intermediate Mixed Cal. Standard (IS)

Working Eluent Solution

1st Order Correlation ICV (ppm)

Matrix Spike (%) CCB CCV ERA Blank (ppm) Blank Spike (ppm)

Duplicates ( ±% )

0.0000 10.0000 20.0000 30.0000 40.0000 50.0000 60.0000 70.0000

0.000 0.500 1.000 1.500 2.000 2.500 Cyanide concentration (mg/L)Area Counts

2
B036923 BLUE MOUNTAIN CNMaxxam Analytics CAM FCD-00839/01

M33-CN

Job # Worksheet # Maxxa m Sampl e CN - Dilutio n HCN RDL Spike o r Pas s ID Volum e readin g at in sampl e Dups Fail ( mL ) (mg/L ) IC (ug) (ug) (%)

B036057 2116904 Blan k 96 0.0000 0.0 9.6 Blank pas s

2116904 Spik e 96 0.4789 47.7 9.6 95.8 Spike pas s

2116904 FK7767-01R 96 0.0000 1 0.0 9.6

2116904 FK7768-01R 2850 0.0000 1 0.0 285.0

2116904 FK7769-01R 3000 0.0000 1 0.0 300.0

2116904 FK776901R:D1 0.0000 0.0 300.0 #DIV/0! #DIV/0!

2116904 MATSPK 0.4815 1499.4 96.3 MATSPK pas s

2116904 FK7770-01R 3000 0.0000 1 0.0 300.0

2116904 FK7771-01R 3000 0.0000 1 0.0 300.0

2116904 FK7772-01R 3000 0.0000 1 0.0 300.0

2116904 FK7773-01R 3000 0.0000 1 0.0 300.0

2116904 FK7774-01R 3000 0.0000 1 0.0 300.0

0 CCB 0.0000 CCB pas s CC V 0.9813 CCV pas s

CCB CC V

3
B036923 BLUE MOUNTAIN CNMaxxam Analytics CAM FCD-00839/01

M33-CN

B036923 2116905 Blan k 355 0.0000 0.0 35.5 Blank pas s

2116905 Spik e 355 0.4818 177.5 35.5 96.4 Spike pas s

2116905 FL2196-01 R 355 0.0000 1 0.0 35.5

2116905 FL2197-01 R 4000 0.0000 1 0.0 400.0

2116905 FL2198-01 R 19000 0.0621 1 1224.7 1900.0

2116905 FL219801R:D1 0.0777 1532.4 1900.0 22.3 Dup pas s

2116905 MATSPK 0.5290 10432.9 93.4 MATSPK pas s

2116905 FL2199-01 R 13000 0.0644 1 869.0 1300.0

2116905 FL2200-01 R 5000 0.2234 1 1159.4 500.0

2116905 FL2201-01 R 13000 0.0000 1 0.0 1300.0

2116905 FL2202-01 R 6000 0.1631 1 1015.8 600.0

0

CCB 0.0000 CCB pas s CC V 0.9832 CCV pas s

CCB CC V

4
B036923 BLUE MOUNTAIN CNMaxxam AnalyticsB036923 BLUE MOUNTAIN CNCAM FCD-00839/01AdjustmentsRUN DATE2010/04/06ANALYSTLLECOMPONENTVolumeJob # Worksheet # MaxxampH Sample Conc. ChargedWeight of Weight of Measured Volume Volume Sample Sample# Type of ImpingerBottle + EmptyBottle RemovedAdjusted AliquotAliquotenterBase Volume Sample Bottle Contents At Source Theoretical to 50 mls to 25 mlsblankNmLgmgmmLmLmLmLmLB0357932116906FK6666-01R 14BLANK4.00150.00150.0060001.2500.6252116906FK6667-01R 4.5BLANK0.10150.00150.0015050.00025.0002116906FK6668-01R 114.0150600.00600.0060005.0002.5002116906FK6669-01R 4.50.1150305.00305.0030550.00025.0002116906FK6670-01R 114.0150630.00630.0060005.2502.6252116906FK6671-01R 4.50.1150295.00295.0029550.00025.0002116906FK6672-01R 114.0150630.00630.0060005.2502.6252116906FK6673-01R 4.50.1150290.00290.0029050.00025.000B0360572116906FK7767-01R 5BLANK0.1096.0096.009650.00025.0002116906FK7768-01R 14BLANK1.00285.00285.0028505.0002.5002116906FK7769-01R 13.51.0300645.00645.00300010.7505.3752116906FK7770-01R 13.51.0300675.00675.00300011.2505.6252116906FK7771-01R 11.51.0300675.00675.00300011.2505.6252116906FK7772-01R 11.51.0300687.00687.00300011.4505.7252116906FK7773-01R 121.0300685.00685.00300011.4175.7082116906FK7774-01R 11.51.0300663.00663.00300011.0505.525B0369232116906FL2196-01R 5.5BLANK0.10355.00355.0035550.00025.0002116906FL2197-01R 14BLANK2.00200.00200.0040002.5001.2502116906FL2198-01R 102.0950950.00950.00190002.5001.2502116906FL2199-01R 102.0650810.00810.00130003.1151.5582116906FL2200-01R 112.0250355.00355.0050003.5501.7752116906FL2201-01R 102.0650910.00910.00130003.5001.7502116906FL2202-01R 112.0300440.00440.0060003.6671.833

# OTM-028 – Dry Impinger Method for Determination of Condensible Particulate Emissions from Stationary Sources

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com

### * Please note any action or anomalies Client ID impacting this set of samples Maxxam Job #

start Maxxam Sample ID's FL2120-03R

Analytical Worksheet(s) - solvent 2116641

Analytical Worksheet(s) - water 2119512

Analysis

Analyst ID - solvent

Analyst ID - water

Actions: *Impacted Sample ID's

Bottle discrepancies No

Solvent rinse anomalies No

Water impinger anomalies No

Solvent blank submitted Yes

Water blank submitted Yes

Other No

Comments

No anomalies were noted in this submission M Gera OTM 28

M Gera Inorganic Analysis Action / Comment Form

Blue Mountain

B036923

Maxxam Analytics Inorganic Air Data Package Page 1 of 3 B036923 M28 Blue Mountain CAM FCD-00822/03Solvent Particulate Weight Log

0.0005 MAXXAM

Job # Solvent Blank Submitted Yes Solven t Client Date of Dessication 2010/04/07 Lab Supplier Date Prepared Analysis Time of Dessication 4:10 PM lot # Date Expired Balance ID Date Extracted 2010/04/06 Na 2 SO 4 Supplie r p/n lot #

solvent Analyst M Gera M Gera M Gera
blank Weighing Date 2010/04/07 2010/04/08 2010/04/09
correction Weighing Time 2:17 PM 5:51 PM 7:15 AM
FL2120-03R Tem p erature ( o C ) 20. 0 19. 0 22. 0 0.8 Humidity (%) 40 39 37

Worksheet # # Maxxam # Spike Solvent Weight Solvent Weight Solvent Weight Pre Weight Weight
#1 Weight
#2 Weight
#3 Weight
#4 Weight
#5 Weight
#6 Weight
#7 Final Weight Residue RDL

Before

gm After

gm gm gm gm gm gm gm gm gm gm gm mg mg

2116641 1 Blank 12.0863 12.0864 12.0865 12.0865 0.2 1.0 2116641 2 Spike 91.3 12.0325 12.0688 12.0690 12.0690 36.5 1.0 2116641 3 Spike:D1 90.2 12.0249 12.0613 12.0610 12.0610 36.1 1.0
2116641 4 FL2120-03R 646.8 285.0 362 12.0228 12.0238 12.0236 12.0236 0.8 1.0
2116641 5 FL2121-03R 400.7 174.5 226 12.0613 12.0638 12.0638 12.0638 2.5 1.0
2116641 6 FL2122-03R 365.2 177.0 188 12.0899 12.0925 12.0924 12.0924 2.5 1.0
2116641 7 FL2123-03R 365.4 177.0 188 12.0232 12.0245 12.0243 12.0243 1.1 1.0
8
9
10

zero 0.0000 0.0000 0.0000

0.3000 gm 0.3000 0.3000 0.3000
11
12
13
14
15
16
17
18
19
20

zero
0.3000 gm 21 Blank 22 Spike 23 Spike:D1
24
25
26
27
28
29
30

zero
0.3000 gm 31
32
33
34
35
36
37
38
39
40

zero
0.3000 gm

The residue appearance is noted in the appropriate cell. Vials are not be exposed to lab atmosphere for > 2 minutes at a relative humidity of 50 %. The residue appearance is noted. Apearance of residue is noted in the appropriate column (light/dark/minimal/copious -"l""d""m""c") B036923 Blue Mountain Acetone

2010/03/05 Fisher Solvent Spike Dichloromethane

2010/09/05 M28 Extractable PM

Not Applicable Fisher 96978

S415-10S 220-BALANAL4 Mettler XS105

Maxxam Analytics Inorganic - Air M28-DCM Page 2 of 3 B036923 M28 Blue Mountain

CAM FCD-00822/03Water Particulate Weight Log

0.0005 MAXXAM

Job # Water Blank Submitted Yes Client Date of Dessication 2010/04/09 Analysis Time of Dessication 8:05 AM Balance ID Normality

water M Gera M Gera M Gera
blank 2010/04/08 2010/04/12 2010/04/12
correction 3:33 PM 8:35 AM 3:25 PM
FL2120-02R 19.0 22.0 23.0 9.0 42 34 35

Worksheet # # Maxxam # Water Weight Water Weight Water Weight Volume
NH

4 OH
Added Pre Weight Weight
#1 Weight
#2 Weight
#3 Weight
#4 Weight
#5 Weight
#6 Weight
#7 Final Weight N on Extractable Condensibles RDL

Before

gm After

gm gm mL gm gm gm gm gm gm gm gm gm mg mg

2119512 1 Blank 200 1.7347 1.7350 1.7350 1.7350 0.3 0.5

2119512 2 FL2120-02R 338.1 54.4 284 0.000 1.6987 1.7079 1.7077 1.7077 9.0 0.5
2119512 3 FL2121-02R 462.9 54.9 408 0.280 1.7494 1.7615 1.7613 1.7613 11.4 0.5
2119512 4 FL2122-02R 451.7 54.4 397 1.260 1.7270 1.7417 1.7416 1.7416 12.4 0.5
2119512 5 FL2123-02R 413.2 54.6 359 0.100 1.6698 1.6798 1.6799 1.6799 9.9 0.5
6
7
8

zero 0.0000 0.0000 0.0000

0.3000 gm 0.3000 0.3000 0.3000
9
10
11
12
13
14
15
16
17
18

zero
0.3000 gm 19 Blank 200

20
21
22
23
24
25
26

zero
0.3000 gm
27
28
29
30
31
32
33
34
35
36

zero
0.3000 gm

The residue appearance is noted in the appropriate cell. Vials are not be exposed to lab atmosphere for > 2 minutes at a relative humidity of 50 %. The residue appearance is noted. Appearance of residue is noted in the appropriate column (light/dark/minimal/copious -"l""d""m""c") 220-BALANAL4 Mettler XS105 0.101

M28 - Non-Extractable PM B036923 Blue Mountain Caledon

LC11080-2

9013-23 NH

4 OH Supplie r p/n Lot#

Humidity (%) Analyst Weighing Date Weighing Time Temperature (oC)

Maxxam Analytics Inorganic - Air M28-WATER Page 3 of 3 B036923 M28 Blue Mountain

CAM FCD-00822/03

# This is the last page of the report and is intentionally left blank

Maxxam Analytics International 6740 Campobello Rd. Mississauga, Ontario, Canada L5N 2L8 1-800-668-0639 www.maxxamanalytics.com1 

## Cole, Jeffrey D.

From: EUMACTICR Support Sent: Friday, March 04, 2011 11:56 AM To: Cole, Jeffrey D.; Wellard, Jennifer; Bullock, David; Kilinski, Robert Subject: FW: Question about some EU MACT ICR Da ta from your ICR submission for the Scrubbgrass Plant

------------------------------------------- From: RJ Shaffer [SMTP:RJ.SHAFFER@SCRUBGRASS.COM] Sent: Friday, March 04, 2011 11:56:37 AM To: EUMACTICR Support Subject: RE: Question about some EU MACT ICR Data from your ICR submission for the Scrubbgrass Plant Auto forwarded by a Rule



## Jeff, The documents referenced below were not intended to be CBI. Thank You,

R. J. Shaffer Environmental Manager Scrubgrass Generating Co. L.P. Phone: 814

‐ 385

‐ 4365
Fax: 814

‐ 385

‐ 6704 Email: rj.shaffer@scrubgrass.com

‐

From: EUMACTICR Support [mailto:EUMACTICRSupport@rti.org] Sent: Thursday, March 03, 2011 2:17 PM To: RJ Shaffer Subject: Question about some EU MACT ICR Data from your ICR submission for the Scrubbgrass Plant



## Richard,

In going through the ICR Part III data that you sent us in support of the EU MACT ICR effort (while preparing to enter the data into the federal docket for public access) we examined 4 PDF reports you uploaded. These are titled:

CTM033 and OTM028 Data Pack.pdf ‐ Prepared for: Blue Mountain Environmental, Project: 2265, Cogentrix, Analytical
Data Package, Analysis: CTM

‐ 033 / OTM

‐ 028, Maxxam Job #: B036923

Method 0010 Data Pack.pdf

– Prepared for: Blue Mountain Environmental, Project: 2265, Cogentrix, Analytical Data Package, Analysis: Method 0010, Maxxam Job #: B037521

Method 29 Data Pack.pdf ‐ Prepared for: Blue Mountain Environmental, Project: 2265, Cogentrix, Analytical Data Package, Analysis: Method 29, Maxxam Job #: B037052

Method 0031 Data Pack.pdf ‐ Prepared for: Blue Mountain Environmental, Project: 2265, Cogentrix, Analytical Data Package, Analysis: Method 0031, Maxxam Job #: B0372312 

## When we scroll through the pages we see the word, “CONFIDENTIAL” printed on each of the report’s pages. Did you

mean these reports to be classified as Confidential Business Information (CBI)? If not, could you please note in a reply to this email that these documents were not intended to be Confidential Business Information (CBI). Thank you.

Jeff,

EU MACT ICR Support Team
RTI International eumacticrsupport@rti.org