# Kleinfelder, Inc.

6200 Harris Technology Blvd. Charlotte, NC 28269



# TECO: Mulberry, FL Client # 109381



# Analytical Report (0410-59)

EPA Method 18

Methane



# Enthalpy Analytical, Inc.

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 2202 Ellis Road Durham, NC 27703 - 5518

### I certify that to the best of my knowledge a ll analytical data presented in this report:

 Have been checked for completeness

 Are accurate, error-free, and legible

 Have been conducted in accordance with approved prot ocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s)

This analytical report was prepared in Portable Document Format (.PDF) and contains  pages.

# Summary of Results

### Compound Sample ID / Adjusted Concentration (ppm)

R1 Backup R2 Stack R3 Stack Methane 0.563 J 0.514 J 0.559 J

R1 Ambient R2 Ambient R3 Ambient Methane 2.28 2.29 2.27 Company

Analyst Parameters # Samples Kleinfelder TBO / STG EPA Method 18 6 bags Client # Job # PO # Report Date 109381 0410-59 Verbal 4/22/2010

4/29/2010 0410-59 Results

# ResultsMDL 0.394 (ppm)Lower Curve Limit 0.499 (ppm)LOQ 0.499 (ppm)Upper Curve Limit 10,200 (ppm)CompoundSampleIDLab ID# 1Lab ID# 2Lab ID# 3AnalysisMethodRetTime(min)RetTime(min)RetTime(min)% DiffRetConc# 1(ppm)Conc# 2(ppm)Conc# 3(ppm)% DiffConcAvgConc(ppm)DFRecEff(%)AdjConc(ppm)QualR1 Backup 028B1801.D 028B1802.D 028B1803.D GC110P104_METHANE.M 1.15 1.15 1.15 0.3 0.489 0.491 0.471 2.6 0.484 1 85.9 0.563 JR2 Stack 029B1201.D 029B1202.D 029B1203.D GC110P104_METHANE.M 1.15 NA 1.15 NA 0.494 0.394 0.437 11.9 0.442 1 85.9 0.514 JR3 Stack 026B1301.D 026B1302.D 026B1303.D GC110P104_METHANE.M 1.15 1.15 1.15 0.1 0.431 0.462 0.546 13.8 0.480 1 85.9 0.559 JR1 Ambient 028B1701.D 028B1702.D 028B1703.D GC110P104_METHANE.M 1.14 1.14 1.14 0.1 1.97 1.92 1.99 2.3 1.96 1 85.9 2.28R2 Ambient 031B1801.D 031B1802.D 031B1803.D GC110P104_METHANE.M 1.14 1.14 1.14 0.2 1.96 1.90 2.05 4.2 1.97 1 85.9 2.29R3 Ambient 032B1901.D 032B1902.D 032B1903.D GC110P104_METHANE.M 1.14 1.14 1.14 0.2 1.97 1.93 1.95 1.2 1.95 1 85.9 2.27He Blank 017B2001.D 017B2002.D 017B2003.D GC110P104_METHANE.M NA NA NA NA 0.394 0.394 0.394 0.0 0.394 1 100 0.394 NDRun 1 backup spk 018B2501.D 018B2502.D 018B2503.D GC114P103_R_C1.M 1.42 1.42 1.42 0.1 6.64 6.68 6.36 3.1 6.56 1 100 6.56MethaneCompanyAnalystParameters# SamplesKleinfelderTBO / STGEPA Method 186 bagsClient #Job #PO #Report Date1093810410-59Verbal4/22/20100410-59 Results4/29/2010v 2.12 Validated by MSS 7/21/09

% Recovery = (T - U) / S x 100

T = after spike concentration U = before spike concentration S = theoretical spike concentration

Methane Ethane Propane MW 16.04 MW 30.000 MW 34.000 MW 0.000 What was the conc of the Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 bag before spiking? (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) U' (before spiking) 0.489 0.491 0.471 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Avg ppm 0.484 Avg ppm 0.00 Avg ppm 0.00 Avg ppm 0.00

What was added to the bag? ug/mL Total ug ug/mL Total ug ug/mL Total ug ug/mL Total ug Liquid Spike #1 0 0 00 00 00 uL Added 0 00 0

ug/mL Total ug ug/mL Total ug ug/mL Total ug ug/mL Total ug Liquid Spike #2 0 0 00 00 00 uL Added 0 00 0

ug/mL Total ug ug/mL Total ug ug/mL Total ug ug/mL Total ug Liquid Spike #3 0 0 00 00 00 uL Added 0 00 0

Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Gas Spike #1 0 29.59 72.5 100 29.59 72.5 100 29.59 72.5 0 29.59 72.5 Volume Added (mL) 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0

Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Gas Spike #2 1,960 29.74 70.7 0 29.74 70.7 0 29.74 70.7 0 29.74 70.7 Volume Added (mL) 35.0 Total ug 45.2 35 Total ug 0.0 35 Total ug 0.0 35 Total ug 0.0

Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Gas Spike #3 0 29.59 72.5 0 29.59 72.5 0 29.59 72.5 0 29.59 72.5 Volume Added (mL) 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0

Total Vol (mL) vaporized 0.0 0.0 0.0 0.0 Total Vol (mL) added as gas 35 35 35 35 Other volume (mL) Added 0 00 0 Volume (mL) used in analysis 0 0 0 0

What volume was in the Sampled 4/7/10 10:14 AM Hours bag before spiking? Wedge Volume 9.546 (L) Delta 218:03:00 Analyzed 4/16/10 12:17 PM

Spiked 4/16/10 1:45 PM Hours Delta 219:08:51 Spike Analyzed 4/25/10 4:53 PM Total Vol. After Spiking 9,581 (mL) Spike hold equal to or greater than original hold YES

Ending Volume in Bag (mL) 9,581 Original volume in the bag (mL) 9,546 9,546 9,546 9,546 Total volume added (mL) 35 35 35 35 Dilution Factor caused by addition 1.00 1.00 1.00 1.00 Dilution Adjusted Base Conc (ppm) "U" 0.482 0.00 0.00 0.00

Theoretical Spike Conc (ppm) "S" 7.08 0.00 0.00 #DIV/0!

What was the conc of the Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 bag after spiking? (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 6.64 6.68 6.36 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Final Concentration (ppm) "T" Avg ppm 6.56 Avg ppm 0.00 Avg ppm 0.00 Avg ppm 0.00

RECOVERY % 85.9 % NA % NA % #DIV/0! % Company

Analyst Parameters Unspiked Sample ID Kleinfelder TBO / STG Bag Spike & Recovery Run 1 Back-up Client # Job # PO # Report Date 109381 0410-59 Verbal 4/22/2010

4/29/2010 11:03 AM 0410-59 Results % Recovery

# Narrative Summary

# Enthalpy Analytical Narrative Summary

Company 

### Kleinfelder Client # 

### 109381

Analyst 

### TBO / STG Job # 

### 0410-59 Parameters 

### EPA Method 18 Bags PO # 

### Verbal

# Samples 

### 6 bags Report Date 

### April 22, 2010

Custody Scott Grosshandler received the samples on 4/9/10 after being relinquished by Kleinfelder, Inc. A ll of the samples were received at ambient temperature and in good c ondition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. Analysis The samples were analyzed for methane using the analytical procedures in EPA Method 18, Measurement of Gaseous Organic Compound Emissions by Gas Chromatography (40 CFR Part 60, Appendix A). The standards and samples were analyzed following the procedures specified in section 8.2.1, Integrated Bag Sampling and Analysis. All samples and standards were introduced directly to the column using an automated 6-port Valco gas sampli ng valve equipped with a stainless steel loop. Methane was referenced to certified gas phase standards. The Agilent Technologies Model 6890N, Gas Chromatograph ("Betty" S/N US10430048) was equipped with a Fl ame Ionization Detector and a Restek Rtx-1, 30 m x 0.32 mm column (S/N 450928).
Calibration The calibration curves are located in the back of this report and referenced in the Analysis Method column on the Detailed Results page. For each calibration curve used, the firs t page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. Chromatographic Conditions The acquisition method (GC110P144FAST.M) is included in the Calibration Curve Chromatograms section of this report.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes As required by section 8.4.2, Rec overy Study for Bag Sampling, a recovery study is performed on a bag sample. The bag sample Run 1 Back-up was spiked at 1:45 PM on 4/ 16/10. The recovery efficiency value meets the method-required limit of between 70 and 130%. The recovery efficiency value is used to adjust the results following equation 18-7 from section 12.8. The sample, Run 1 Primary, did not meet the method’s 5% reproducibility criteria between injections before spiking. The sample Run 1 Backup was analyzed and met the method reproducibility criteria. Only the analysis of the backup bag has been reported. All method requirements were met. Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory. These analytical results are reported on a wet basis. The user of this report should determine the % moisture in the sample and correct the reported value to ppmvd as appropriate. Enthalpy Analytical, Inc. is accredited to perform this method for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# General Reporting Notes

The following are general reporting notes that are a pplicable to all Enthalpy Analytical, Inc. data reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.

 The acronym ND following a value indicates a non-detect or analytical result below the MDL.

 The letter J following a value indicates an analytical r esult between the MDL and the LOQ. A J flag indicates that the laboratory can positively identify th e analyte of interest as present, but the value should be considered an estimate.

 The letter E following a value indicates an analytical r esult exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analyti cal result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results.

 The addition of MS to the Sample ID represents a Matrix Sp ike. An aliquot of an actual sample is spiked with a known amount of analyte so that a per cent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s).

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.

 The addition of LD to the Sample ID represents a Laborat ory Duplicate. The analyst prepares an additional aliquot of sample for testing and the resu lts of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).

 The addition of AD to the Sample ID represents an Alte rnate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usu ally double the initial factor). This analysis helps confirm that no additional compound is present and coel uting or sharing absorbance with the analyte of interest, as they would have a different res ponse/absorbance than the analyte of interest.

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laborator y using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. The extras (randomly chosen) are labeled with the asso ciated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection and/or sample transport.

# General Reporting Notes
(continued)

 Significant Figures : Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. Ther e are five significant digits displayed, but no confidence should be placed on more than two significant digits.

 Manual Integration : The data systems used for processing w ill flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations. The peak was not integrated by the software “NI” , the peak

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP” . These codes will accompany the analyst’s ma nual integration stamp placed next to the compound name.

# Sample Custody

# Sample Chromatograms===================================================================== Acq. Operator : kam Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 16-Apr-10, 12:17:10 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P157\028B1801.D)

A

r ea

: 0.

1 3 19

6 9

A

r ea

: 0.

0 2 11

8 041.1241.148 - Methane1.2306.5927.2947.9848.8159.388

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.148 MF 1.31969e-1 3.70546 4.89006e-1 Methane

Totals : 4.89006e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\028B1801.D Sample Name: R1 Backup 0410-59

Betty Reprocess 4/21/2010 12:09:49 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 16-Apr-10, 12:36:09 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P157\028B1802.D)1.1191.145 - Methane6.5968.8119.379

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.145 PB 1.32436e-1 3.70546 4.90736e-1 Methane

Totals : 4.90736e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\028B1802.D Sample Name: R1 Backup 0410-59

Betty Reprocess 4/21/2010 12:10:04 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 16-Apr-10, 12:55:11 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P157\028B1803.D)1.1231.149 - Methane6.5939.381

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.149 PB 1.27163e-1 3.70546 4.71199e-1 Methane

Totals : 4.71199e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\028B1803.D Sample Name: R1 Backup 0410-59

Betty Reprocess 4/21/2010 12:11:00 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 12 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 09-Apr-10, 15:43:08 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\029B1201.D)1.1251.150 - Methane8.5958.8069.369

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.150 PB 1.33421e-1 3.70546 4.94388e-1 Methane

Totals : 4.94388e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\029B1201.D Sample Name: R2 Stack 0410-59

Betty Reprocess 4/16/2010 10:17:47 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 12 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 09-Apr-10, 15:59:13 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\029B1202.D)1.1211.148 - Methane1.7728.5978.8119.383

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.148 PB 8.45188e-2 3.70546 3.13182e-1 Methane

Totals : 3.13182e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\029B1202.D Sample Name: R2 Stack 0410-59

Betty Reprocess 4/16/2010 10:17:58 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 12 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 09-Apr-10, 16:17:57 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\029B1203.D)1.1231.151 - Methane8.5998.8109.380

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.151 PB 1.17885e-1 3.70546 4.36820e-1 Methane

Totals : 4.36820e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\029B1203.D Sample Name: R2 Stack 0410-59

Betty Reprocess 4/16/2010 10:18:11 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 13 Acq. Instrument : Betty online Location : Vial 26 Injection Date : 09-Apr-10, 16:35:48 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\026B1301.D)1.1201.149 - Methane8.3938.5938.8079.375

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.149 PB 1.16354e-1 3.70546 4.31146e-1 Methane

Totals : 4.31146e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\026B1301.D Sample Name: R3 Stack 0410-59

Betty Reprocess 4/16/2010 10:18:32 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 13 Acq. Instrument : Betty online Location : Vial 26 Injection Date : 09-Apr-10, 16:54:33 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\026B1302.D)1.1211.148 - Methane8.3948.5958.8099.381

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.148 PB 1.24669e-1 3.70546 4.61958e-1 Methane

Totals : 4.61958e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\026B1302.D Sample Name: R3 Stack 0410-59

Betty Reprocess 4/16/2010 10:18:45 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 13 Acq. Instrument : Betty online Location : Vial 26 Injection Date : 09-Apr-10, 17:12:12 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\026B1303.D)1.1201.150 - Methane8.3918.5908.8069.373

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.150 PV 1.48119e-1 3.68712 5.46132e-1 Methane

Totals : 5.46132e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\026B1303.D Sample Name: R3 Stack 0410-59

Betty Reprocess 4/16/2010 10:19:00 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Apr-10, 20:15:17 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\028B1701.D)1.1161.142 - Methane8.591

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.142 PB 5.55693e-1 3.55245 1.97407 Methane

Totals : 1.97407

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\028B1701.D Sample Name: R1 Ambient 0410-59

Betty Reprocess 4/16/2010 10:19:24 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Apr-10, 20:34:03 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\028B1702.D)1.1141.141 - Methane8.590

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.141 PB 5.39391e-1 3.55393 1.91696 Methane

Totals : 1.91696

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\028B1702.D Sample Name: R1 Ambient 0410-59

Betty Reprocess 4/16/2010 10:19:37 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Apr-10, 20:52:09 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\028B1703.D)

A

r ea

: 0.

5 6 14

8 7

A

r ea

: 0.

0 4 76

9 651.1141.146 - Methane1.1728.5878.8019.356

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.146 MF 5.61487e-1 3.55195 1.99438 Methane

Totals : 1.99438

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\028B1703.D Sample Name: R1 Ambient 0410-59

Betty Reprocess 4/23/2010 8:13:36 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 31 Injection Date : 09-Apr-10, 21:10:45 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\031B1801.D)

A

r ea

: 0.

5 5 24

7 3

A

r ea

: 0.

0 5 00

3 261.1131.143 - Methane1.1823.3553.4588.8009.359

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.143 MF 5.52473e-1 3.55274 1.96279 Methane

Totals : 1.96279

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\031B1801.D Sample Name: R2 Ambient 0410-59

Betty Reprocess 4/23/2010 8:14:17 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 31 Injection Date : 09-Apr-10, 21:29:00 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\031B1802.D)1.1141.141 - Methane8.5898.7979.354

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.141 PB 5.33666e-1 3.55447 1.89690 Methane

Totals : 1.89690

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\031B1802.D Sample Name: R2 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:09 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 31 Injection Date : 09-Apr-10, 21:47:40 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\031B1803.D)1.1121.139 - Methane8.5898.7979.353

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.139 PB 5.78423e-1 3.55053 2.05371 Methane

Totals : 2.05371

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\031B1803.D Sample Name: R2 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:20 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 19 Acq. Instrument : Betty online Location : Vial 32 Injection Date : 09-Apr-10, 22:05:55 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\032B1901.D)1.1141.141 - Methane9.354

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.141 PB 5.55930e-1 3.55243 1.97490 Methane

Totals : 1.97490

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\032B1901.D Sample Name: R3 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:36 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 19 Acq. Instrument : Betty online Location : Vial 32 Injection Date : 09-Apr-10, 22:24:24 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\032B1902.D)1.1121.139 - Methane8.5868.7969.347

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.139 PB 5.43262e-1 3.55357 1.93052 Methane

Totals : 1.93052

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\032B1902.D Sample Name: R3 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:47 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 19 Acq. Instrument : Betty online Location : Vial 32 Injection Date : 09-Apr-10, 22:42:53 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\032B1903.D)1.1131.139 - Methane9.350

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.139 PB 5.49299e-1 3.55302 1.95167 Methane

Totals : 1.95167

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\032B1903.D Sample Name: R3 Ambient 0410-59

Betty Reprocess 4/16/2010 11:06:01 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 20 Acq. Instrument : Betty online Location : Vial 17 Injection Date : 09-Apr-10, 23:00:51 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\017B2001.D)8.585

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.149 - - - Methane

Totals : 0.00000

2 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing) Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\017B2001.D Sample Name: He Blank

Betty Reprocess 4/16/2010 11:06:26 AM Page 1 of 2===================================================================== Acq. Operator : kam Seq. Line : 20 Acq. Instrument : Betty online Location : Vial 17 Injection Date : 09-Apr-10, 23:19:19 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\017B2002.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.149 - - - Methane

Totals : 0.00000

2 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing) Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\017B2002.D Sample Name: He Blank

Betty Reprocess 4/16/2010 11:07:19 AM Page 1 of 2===================================================================== Acq. Operator : kam Seq. Line : 20 Acq. Instrument : Betty online Location : Vial 17 Injection Date : 09-Apr-10, 23:37:01 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\017B2003.D)8.585

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.149 - - - Methane

Totals : 0.00000

2 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing) Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\017B2003.D Sample Name: He Blank

Betty Reprocess 4/16/2010 11:07:47 AM Page 1 of 2===================================================================== Acq. Operator : stg Seq. Line : 25 Acq. Instrument : Gummo online Location : Vial 18 Injection Date : 25-Apr-10, 16:53:11 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

4 6 8 10 12 14 16 FID2 B, (GC114P106\018B2501.D)1.3931.419 - Methane1.5521.8658.990

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.419 PB 1.62546 4.08661 6.64261 Methane

Totals : 6.64261

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\018B2501.D Sample Name: R1 Backup 0410-59

Gummo online 4/27/2010 9:24:11 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 25 Acq. Instrument : Gummo online Location : Vial 18 Injection Date : 25-Apr-10, 17:08:47 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

4 6 8 10 12 14 16 FID2 B, (GC114P106\018B2502.D)1.3941.420 - Methane1.5528.988

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.420 PB 1.63528 4.08574 6.68131 Methane

Totals : 6.68131

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\018B2502.D Sample Name: R1 Backup 0410-59

Gummo online 4/27/2010 9:24:18 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 25 Acq. Instrument : Gummo online Location : Vial 18 Injection Date : 25-Apr-10, 17:24:32 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

4 6 8 10 12 14 16 FID2 B, (GC114P106\018B2503.D)1.3921.419 - Methane1.5521.8638.986

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.419 PB 1.55360 4.09330 6.35934 Methane

Totals : 6.35934

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\018B2503.D Sample Name: R1 Backup 0410-59

Gummo online 4/27/2010 9:24:46 AM stg Page 1 of 1

# Calibration Curve Chromatograms===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : 1/21/2010 9:48:15 AM

Rel. Reference Window : 2.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 2.000 % Abs. Non-ref. Window : 0.200 min Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Quadratic (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: TCD1 A, Signal 2: FID2 B,

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [%] -------|--|--|----------|----------|----------|---|--|--------------- 1.129 2 21 4.99000e-1 1.35402e-1 3.68533 Methane 22 1.99600 5.52639e-1 3.61176 23 9.98000 2.80187 3.56191 24 39.92000 11.06458 3.60791 25 99.80000 28.10567 3.55089 26 1020.00000 304.61028 3.34854 27 1.02000e4 2969.18937 3.43528

More compound-specific settings:

Compound: Methane Time Window : From 1.049 min To 1.240 min

3 Warnings or Errors :

Warning : Overlapping peak time windows Warning : Overlapping peak time windows Warning : Curve requires more calibration points.

===================================================================== Peak Sum Table

===================================================================== Method G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Betty Reprocess 4/16/2010 10:03:48 AM Page 1 of 2Name StartTime EndTime Use Response Multiplier ISTD [min] [min] Reference factor Peak ----------|-------|-------|----------|--------|----------|----------- as Ethane 1.200 1.700 None 2.2489 1.0000 None as Propane 1.700 3.750 None 1.5011 1.0000 None as Butane 3.750 5.700 None 1.1334 1.0000 None as Pentane 5.700 6.800 None 9.2380e-1 1.0000 None as Hexane 6.800 7.600 None 8.0371e-1 1.0000 None as Heptane 7.600 11.500 None 6.7616e-1 1.0000 None

=====================================================================

===================================================================== Calibration Curves

=====================================================================

Amount[%] 0 5000 10000 Area

0 500 1000 1500 2000 2500

21 2 3 4 25 26 27 Methane at exp. RT: 1.129 FID2 B, Correlation: 0.99963 Residual Std. Dev.: 26.55855 Formula: y = mx + b m: 2.85428e-1 b: -7.76247e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.39332e-007 Level 27 : 2.39332e-009

===================================================================== Method G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Betty Reprocess 4/16/2010 10:03:48 AM Page 2 of 2===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Monday, March 29, 2010 9:44:52 AM

Rel. Reference Window : 2.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 2.000 % Abs. Non-ref. Window : 0.200 min Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Quadratic (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: TCD1 A, Signal 2: FID2 B,

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [%] -------|--|--|----------|----------|----------|---|--|--------------- 0.811 1 91 8.50000e-1 4.44911 1.91049e-1 Hydrogen 92 4.25000 22.49751 1.88910e-1 93 8.50000 44.78257 1.89806e-1 1.129 2 21 4.99000e-1 1.35402e-1 3.68533 Methane 22 1.99600 5.52639e-1 3.61176 23 9.98000 2.80187 3.56191 24 39.92000 11.06458 3.60791 25 99.80000 28.10567 3.55089 26 1020.00000 304.61028 3.34854 27 1.02000e4 2969.18937 3.43528 1.354 2 21 4.99500e-1 2.47397e-1 2.01902 Ethane 22 1.99800 9.86084e-1 2.02620 23 9.99000 4.97993 2.00605 24 39.96000 19.68223 2.03026 25 99.90000 48.70662 2.05106 26 999.00000 528.59880 1.88990 27 9990.00000 5146.62077 1.94108 29 5.02000e4 2.51915e4 1.99274 2.130 2 21 4.99000e-1 3.61957e-1 1.37862 Propane 22 1.99600 1.52124 1.31209 23 9.98000 7.63784 1.30665 24 39.92000 30.00575 1.33041 25 99.80000 74.04200 1.34788 26 1002.00000 754.42265 1.32817 27 1.00200e4 7342.21875 1.36471 29 5.00000e4 3.80690e4 1.31340 3.403 1 8 1.98800e-1 75.06279 2.64845e-3 Oxygen Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 1 of 7RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [%] -------|--|--|----------|----------|----------|---|--|--------------- 4 9.94000e-1 370.93233 2.67973e-3 5 4.97000 1784.47870 2.78513e-3 6 9.94000 3885.63855 2.55814e-3 9 99.80000 3.74303e4 2.66629e-3 3.882 1 7 1.99600e-1 87.01833 2.29377e-3 Nitrogen 1 9.98000e-1 431.03604 2.31535e-3 2 4.99000 1973.00867 2.52913e-3 3 9.98000 4195.68652 2.37863e-3 9 100.00000 3.73785e4 2.67534e-3 4.772 2 21 5.00000e-1 5.05538e-1 9.89046e-1 Butane 22 2.00000 2.01181 9.94129e-1 23 10.00000 10.09618 9.90473e-1 24 40.00000 39.82943 1.00428 25 100.00000 98.24574 1.01786 26 999.00000 1029.92782 9.69971e-1 27 9990.00000 1.00171e4 9.97295e-1 5.160 1 7 2.02000e-1 92.56993 2.18213e-3 Carbon monoxide 1 1.01000 491.74663 2.05390e-3 2 5.05000 2208.96924 2.28613e-3 3 10.10000 4694.73730 2.15135e-3 9 99.00000 4.27557e4 2.31548e-3 6.364 2 21 4.94500e-1 6.07755e-1 8.13650e-1 Pentane 22 1.97800 2.49617 7.92415e-1 23 9.89000 12.44353 7.94791e-1 24 39.56000 48.97281 8.07795e-1 25 98.90000 120.68393 8.19496e-1 28 801.60000 1016.57615 7.88529e-1 29 2004.00000 2538.43888 7.89462e-1 7.281 2 21 5.15000e-1 7.44320e-1 6.91907e-1 Hexane 22 2.06000 2.99670 6.87422e-1 23 10.30000 15.01502 6.85980e-1 24 41.20000 59.00752 6.98216e-1 25 103.00000 145.23974 7.09172e-1 28 399.20000 604.13151 6.60783e-1 29 998.00000 1507.32475 6.62100e-1 7.472 1 7 1.61200e-1 69.03885 2.33492e-3 Methane 1 8.06000e-1 352.93555 2.28370e-3 2 4.03000 1585.03979 2.54252e-3 3 8.06000 3351.48865 2.40490e-3 9 99.00000 3.77759e4 2.62072e-3 7.964 2 21 4.85000e-1 7.89600e-1 6.14235e-1 Heptane 22 1.94000 3.23543 5.99611e-1 23 9.70000 16.20249 5.98673e-1 24 38.80000 63.69198 6.09182e-1 25 97.00000 156.62639 6.19308e-1 28 200.16000 354.62990 5.64419e-1 29 500.40000 883.83154 5.66171e-1 9.274 1 8 1.98800e-1 204.00780 9.74473e-4 Carbon dioxide 4 9.94000e-1 738.14764 1.34661e-3 5 4.97000 3153.63171 1.57596e-3 6 9.94000 7070.64453 1.40581e-3 9 99.80000 6.87727e4 1.45116e-3

More compound-specific settings:

Compound: Methane Time Window : From 1.049 min To 1.240 min

Compound: Oxygen Time Window : From 3.102 min To 3.820 min

Compound: Nitrogen Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 2 of 7Time Window : From 3.386 min To 4.557 min

Compound: Carbon monoxide Time Window : From 4.674 min To 5.614 min

Compound: Methane Time Window : From 7.076 min To 7.647 min

Compound: Heptane Time Window : From 7.921 min To 8.031 min

Compound: Carbon dioxide Time Window : From 8.911 min To 9.612 min

2 Warnings or Errors :

Warning : Overlapping peak time windows at 3.403 min, signal 1 Warning : Overlapping peak time windows at 1.129 min, signal 2

===================================================================== Peak Sum Table

=====================================================================

Name StartTime EndTime Use Response Multiplier ISTD [min] [min] Reference factor Peak ----------|-------|-------|----------|--------|----------|----------- as Ethane 1.200 1.630 None 2.2489 1.0000 None as Propane 1.630 3.450 None 1.5011 1.0000 None as Butane 3.450 5.570 None 1.1334 1.0000 None as Pentane 5.570 6.580 None 9.2380e-1 1.0000 None as Hexane 6.820 7.630 None 8.0371e-1 1.0000 None as Heptane 7.630 11.500 None 6.7616e-1 1.0000 None

=====================================================================

===================================================================== Calibration Curves

=====================================================================

Amount[%] 0 5 Area

0 5 10 15 20 25 30 35 40

91 92 93 Hydrogen at exp. RT: 0.811 TCD1 A, Correlation: 0.99999 Residual Std. Dev.: 0.13854 Formula: y = mx + b m: 5.28793 b: -4.41224e-2
x: Amount y: Area Calibration Level Weights: Level 91 : 1 Level 92 : 0.04 Level 93 : 0.01 Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 3 of 7Amount[%] 0 5000 10000 Area

0 500 1000 1500 2000 2500

21 2 3 4 25 26 27 Methane at exp. RT: 1.129 FID2 B, Correlation: 0.99963 Residual Std. Dev.: 26.55855 Formula: y = mx + b m: 2.85428e-1 b: -7.76247e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.39332e-007 Level 27 : 2.39332e-009

Amount[%] 0 20000 40000 Area

0 5000 10000 15000 20000 25000

21 2 3 4 5 26 27 29 Ethane at exp. RT: 1.354 FID2 B, Correlation: 0.99961 Residual Std. Dev.: 58.82996 Formula: y = mx + b m: 5.03398e-1 b: -5.16788e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.5e-007 Level 27 : 2.5e-009 Level 29 : 9.90065e-011

Amount[%] 0 20000 40000 Area

0 5000 10000 15000 20000 25000 30000 35000

21 2 3 4 5 26 27 29 Propane at exp. RT: 2.130 FID2 B, Correlation: 0.99986 Residual Std. Dev.: 189.74265 Formula: y = mx + b m: 7.53020e-1 b: -1.16335e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.48008e-007 Level 27 : 2.48008e-009 Level 29 : 9.96004e-011 Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 4 of 7Amount[%] 0 50 100 Area

0 5000 10000 15000 20000 25000 30000 35000

8 4 5 6 9 Oxygen at exp. RT: 3.403 TCD1 A, Correlation: 0.99947 Residual Std. Dev.: 107.48919 Formula: y = mx + b m: 374.55904 b: 4.67522e-1
x: Amount y: Area Calibration Level Weights: Level 8 : 1 Level 4 : 0.04 Level 5 : 0.0016 Level 6 : 0.0004 Level 9 : 3.968e-006

Amount[%] 0 50 100 Area

0 5000 10000 15000 20000 25000 30000 35000

7 1 2 3 9 Nitrogen at exp. RT: 3.882 TCD1 A, Correlation: 0.99849 Residual Std. Dev.: 1620.60813 Formula: y = mx + b m: 401.71654 b: 7.72898
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Level 9 : 3.98402e-006

Amount[%] 0 5000 10000 Area

0 2000 4000 6000 8000

21 2 3 4 25 26 27 Butane at exp. RT: 4.772 FID2 B, Correlation: 0.99988 Residual Std. Dev.: 13.69326 Formula: y = mx + b m: 1.00419 b: 3.46686e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.50501e-007 Level 27 : 2.50501e-009 Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 5 of 7Amount[%] 0 50 100 Area

0 5000 10000 15000 20000 25000 30000 35000 40000

7 1 2 3 9 Carbon monoxide at exp. RT: 5.160 TCD1 A, Correlation: 0.99869 Residual Std. Dev.: 1214.92684 Formula: y = mx + b m: 453.05780 b: 2.23707
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Level 9 : 4.16325e-006

Amount[%] 0 1000 2000 Area

0 500 1000 1500 2000

21 2 23 24 25 28 29 Pentane at exp. RT: 6.364 FID2 B, Correlation: 0.99988 Residual Std. Dev.: 13.81622 Formula: y = mx + b m: 1.25267 b: -9.92474e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 28 : 3.80555e-007 Level 29 : 6.08888e-008

Amount[%] 0 500 1000 Area

0 200 400 600 800 1000 1200 1400

21 2 23 24 25 28 29 Hexane at exp. RT: 7.281 FID2 B, Correlation: 0.99963 Residual Std. Dev.: 22.37468 Formula: y = mx + b m: 1.46455 b: -1.09537e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 28 : 1.66431e-006 Level 29 : 2.66289e-007 Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 6 of 7Amount[%] 0 50 100 Area

0 5000 10000 15000 20000 25000 30000 35000

7 1 2 3 9 Methane at exp. RT: 7.472 TCD1 A, Correlation: 0.99861 Residual Std. Dev.: 1278.41168 Formula: y = mx + b m: 403.86769 b: 4.79529
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Level 9 : 2.6513e-006

Amount[%] 0 200 400 Area

0 100 200 300 400 500 600 700 800

21 2 23

24 25 28 29 Heptane at exp. RT: 7.964 FID2 B, Correlation: 0.99933 Residual Std. Dev.: 18.19609 Formula: y = mx + b m: 1.69302 b: -3.33323e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 28 : 5.87123e-006 Level 29 : 9.39396e-007

Amount[%] 0 50 100 Area

0 10000 20000 30000 40000 50000 60000

8 4 5 6 9 Carbon dioxide at exp. RT: 9.274 TCD1 A, Correlation: 0.99873 Residual Std. Dev.: 998.51238 Formula: y = mx + b m: 671.57245 b: 70.24338
x: Amount y: Area Calibration Level Weights: Level 8 : 1 Level 4 : 0.04 Level 5 : 0.0016 Level 6 : 0.0004 Level 9 : 3.968e-006

===================================================================== Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/14/2010 4:02:40 AM stg/tbo Page 7 of 7===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : 1/13/2010 10:14:02 PM

Rel. Reference Window : 2.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 2.000 % Abs. Non-ref. Window : 0.200 min Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Quadratic (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: TCD1 A, Signal 2: FID2 B,

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [%] -------|--|--|----------|----------|----------|---|--|--------------- 0.840 1 7 1.70000e-1 1.42436 1.19351e-1 Hydrogen 1 8.50000e-1 8.97445 9.47133e-2 2 4.25000 49.19996 8.63822e-2 3 8.50000 104.72226 8.11671e-2 1.129 2 21 4.99000e-1 1.35402e-1 3.68533 Methane 22 1.99600 5.52639e-1 3.61176 23 9.98000 2.80187 3.56191 24 39.92000 11.06458 3.60791 25 99.80000 28.10567 3.55089 26 1020.00000 304.61028 3.34854 27 1.02000e4 2969.18937 3.43528 1.354 2 21 4.99500e-1 2.47397e-1 2.01902 Ethane 22 1.99800 9.86084e-1 2.02620 23 9.99000 4.97993 2.00605 24 39.96000 19.68223 2.03026 25 99.90000 48.70662 2.05106 26 999.00000 528.59880 1.88990 27 9990.00000 5146.62077 1.94108 29 5.02000e4 2.51915e4 1.99274 2.130 2 21 4.99000e-1 3.61957e-1 1.37862 Propane 22 1.99600 1.52124 1.31209 23 9.98000 7.63784 1.30665 24 39.92000 30.00575 1.33041 25 99.80000 74.04200 1.34788 26 1002.00000 754.42265 1.32817 27 1.00200e4 7342.21875 1.36471 29 5.00000e4 3.80690e4 1.31340 Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 1 of 7RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [%] -------|--|--|----------|----------|----------|---|--|--------------- 2.783 1 8 1.98800e-1 91.55111 2.17146e-3 Oxygen 4 9.94000e-1 406.03781 2.44805e-3 5 4.97000 2054.37500 2.41923e-3 6 9.94000 4202.69116 2.36515e-3 9 99.80000 4.40149e4 2.26741e-3 3.410 1 7 1.99600e-1 110.10318 1.81284e-3 Nitrogen 1 9.98000e-1 451.79161 2.20898e-3 2 4.99000 2246.56348 2.22117e-3 3 9.98000 4561.85718 2.18771e-3 9 100.00000 4.71263e4 2.12196e-3 4.772 2 21 5.00000e-1 5.05538e-1 9.89046e-1 Butane 22 2.00000 2.01181 9.94129e-1 23 10.00000 10.09618 9.90473e-1 24 40.00000 39.82943 1.00428 25 100.00000 98.24574 1.01786 26 999.00000 1029.92782 9.69971e-1 27 9990.00000 1.00171e4 9.97295e-1 4.902 1 7 2.02000e-1 103.03305 1.96054e-3 Carbon monoxide 1 1.01000 491.75664 2.05386e-3 2 5.05000 2451.79663 2.05971e-3 3 10.10000 4965.58472 2.03400e-3 9 99.00000 5.46482e4 1.81159e-3 6.364 2 21 4.94500e-1 6.07755e-1 8.13650e-1 Pentane 22 1.97800 2.49617 7.92415e-1 23 9.89000 12.44353 7.94791e-1 24 39.56000 48.97281 8.07795e-1 25 98.90000 120.68393 8.19496e-1 28 801.60000 1016.57615 7.88529e-1 29 2004.00000 2538.43888 7.89462e-1 7.281 2 21 5.15000e-1 7.44320e-1 6.91907e-1 Hexane 22 2.06000 2.99670 6.87422e-1 23 10.30000 15.01502 6.85980e-1 24 41.20000 59.00752 6.98216e-1 25 103.00000 145.23974 7.09172e-1 28 399.20000 604.13151 6.60783e-1 29 998.00000 1507.32475 6.62100e-1 7.286 1 7 1.61200e-1 78.56514 2.05180e-3 Methane 1 8.06000e-1 364.52043 2.21112e-3 2 4.03000 1802.08862 2.23629e-3 3 8.06000 3648.10791 2.20936e-3 9 99.00000 4.90459e4 2.01852e-3 7.964 2 21 4.85000e-1 7.89600e-1 6.14235e-1 Heptane 22 1.94000 3.23543 5.99611e-1 23 9.70000 16.20249 5.98673e-1 24 38.80000 63.69198 6.09182e-1 25 97.00000 156.62639 6.19308e-1 28 200.16000 354.62990 5.64419e-1 29 500.40000 883.83154 5.66171e-1 8.950 1 8 1.98800e-1 159.71481 1.24472e-3 Carbon dioxide 4 9.94000e-1 769.09738 1.29242e-3 5 4.97000 3827.61816 1.29846e-3 6 9.94000 7677.67896 1.29466e-3 9 99.80000 8.26574e4 1.20739e-3

More compound-specific settings:

Compound: Methane Time Window : From 1.049 min To 1.240 min

Compound: Oxygen Time Window : From 2.482 min To 3.200 min Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 2 of 7Compound: Nitrogen Time Window : From 2.914 min To 4.085 min

Compound: Carbon monoxide Time Window : From 4.416 min To 5.356 min

Compound: Methane Time Window : From 6.890 min To 7.461 min

Compound: Heptane Time Window : From 7.921 min To 8.031 min

Compound: Carbon dioxide Time Window : From 8.587 min To 9.288 min

2 Warnings or Errors :

Warning : Overlapping peak time windows at 2.783 min, signal 1 Warning : Overlapping peak time windows at 1.129 min, signal 2

===================================================================== Peak Sum Table

=====================================================================

Name StartTime EndTime Use Response Multiplier ISTD [min] [min] Reference factor Peak ----------|-------|-------|----------|--------|----------|----------- as Ethane 1.200 1.700 None 2.2489 1.0000 None as Propane 1.700 3.750 None 1.5011 1.0000 None as Butane 3.750 5.700 None 1.1334 1.0000 None as Pentane 5.700 6.800 None 9.2380e-1 1.0000 None as Hexane 6.800 7.600 None 8.0371e-1 1.0000 None as Heptane 7.600 11.500 None 6.7616e-1 1.0000 None

=====================================================================

===================================================================== Calibration Curves

=====================================================================

Amount[%] 0 5 Area

0 20 40 60 80

7 1 2 3 Hydrogen at exp. RT: 0.840 TCD1 A, Correlation: 0.99906 Residual Std. Dev.: 3.41864 Formula: y = mx + b m: 11.82797 b: -6.04222e-1
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 3 of 7Amount[%] 0 5000 10000 Area

0 500 1000 1500 2000 2500

21 2 3 4 25 26 27 Methane at exp. RT: 1.129 FID2 B, Correlation: 0.99963 Residual Std. Dev.: 26.55855 Formula: y = mx + b m: 2.85428e-1 b: -7.76247e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.39332e-007 Level 27 : 2.39332e-009

Amount[%] 0 20000 40000 Area

0 5000 10000 15000 20000 25000

21 2 3 4 5 26 27 29 Ethane at exp. RT: 1.354 FID2 B, Correlation: 0.99961 Residual Std. Dev.: 58.82996 Formula: y = mx + b m: 5.03398e-1 b: -5.16788e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.5e-007 Level 27 : 2.5e-009 Level 29 : 9.90065e-011

Amount[%] 0 20000 40000 Area

0 5000 10000 15000 20000 25000 30000 35000

21 2 3 4 5 26 27 29 Propane at exp. RT: 2.130 FID2 B, Correlation: 0.99986 Residual Std. Dev.: 189.74265 Formula: y = mx + b m: 7.53020e-1 b: -1.16335e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.48008e-007 Level 27 : 2.48008e-009 Level 29 : 9.96004e-011 Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 4 of 7Amount[%] 0 50 100 Area

0 5000 10000 15000 20000 25000 30000 35000 40000

8 4 5 6 9 Oxygen at exp. RT: 2.783 TCD1 A, Correlation: 0.99928 Residual Std. Dev.: 1205.98664 Formula: y = mx + b m: 420.03402 b: 7.25096
x: Amount y: Area Calibration Level Weights: Level 8 : 1 Level 4 : 0.04 Level 5 : 0.0016 Level 6 : 0.0004 Level 9 : 3.968e-006

Amount[%] 0 50 100 Area

0 5000 10000 15000 20000 25000 30000 35000 40000

7 1 2 3 9 Nitrogen at exp. RT: 3.410 TCD1 A, Correlation: 0.99947 Residual Std. Dev.: 1068.40967 Formula: y = mx + b m: 452.57273 b: 18.98391
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Level 9 : 3.98402e-006

Amount[%] 0 5000 10000 Area

0 2000 4000 6000 8000

21 2 3 4 25 26 27 Butane at exp. RT: 4.772 FID2 B, Correlation: 0.99988 Residual Std. Dev.: 13.69326 Formula: y = mx + b m: 1.00419 b: 3.46686e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 26 : 2.50501e-007 Level 27 : 2.50501e-009 Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 5 of 7Amount[%] 0 50 100 Area

0 10000 20000 30000 40000

7 1 2 3 9 Carbon monoxide at exp. RT: 4.902 TCD1 A, Correlation: 0.99824 Residual Std. Dev.: 2679.96469 Formula: y = mx + b m: 505.14582 b: 5.95181e-2
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Level 9 : 4.16325e-006

Amount[%] 0 1000 2000 Area

0 500 1000 1500 2000

21 2 23 24 25 28 29 Pentane at exp. RT: 6.364 FID2 B, Correlation: 0.99988 Residual Std. Dev.: 13.81622 Formula: y = mx + b m: 1.25267 b: -9.92474e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 28 : 3.80555e-007 Level 29 : 6.08888e-008

Amount[%] 0 500 1000 Area

0 200 400 600 800 1000 1200 1400

21 2 23 24 25 28 29 Hexane at exp. RT: 7.281 FID2 B, Correlation: 0.99963 Residual Std. Dev.: 22.37468 Formula: y = mx + b m: 1.46455 b: -1.09537e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 28 : 1.66431e-006 Level 29 : 2.66289e-007 Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 6 of 7Amount[%] 0 50 100 Area

0 10000 20000 30000 40000

7 1 2 3 9 Methane at exp. RT: 7.286 TCD1 A, Correlation: 0.99887 Residual Std. Dev.: 1952.10846 Formula: y = mx + b m: 461.23641 b: 3.66109
x: Amount y: Area Calibration Level Weights: Level 7 : 1 Level 1 : 0.04 Level 2 : 0.0016 Level 3 : 0.0004 Level 9 : 2.6513e-006

Amount[%] 0 200 400 Area

0 100 200 300 400 500 600 700 800

21 2 23

24 25 28 29 Heptane at exp. RT: 7.964 FID2 B, Correlation: 0.99933 Residual Std. Dev.: 18.19609 Formula: y = mx + b m: 1.69302 b: -3.33323e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.0625 Level 23 : 0.0025 Level 24 : 0.000156 Level 25 : 0.000025 Level 28 : 5.87123e-006 Level 29 : 9.39396e-007

Amount[%] 0 50 100 Area

0 10000 20000 30000 40000 50000 60000 70000

8 4 5 6 9 Carbon dioxide at exp. RT: 8.950 TCD1 A, Correlation: 0.99942 Residual Std. Dev.: 2420.17771 Formula: y = mx + b m: 786.23340 b: 2.63777
x: Amount y: Area Calibration Level Weights: Level 8 : 1 Level 4 : 0.04 Level 5 : 0.0016 Level 6 : 0.0004 Level 9 : 3.968e-006

===================================================================== Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 7 of 7===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 16:38:18 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 4:38:10 PM by JBB (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1601.D)

A

r ea

: 1.

3 3 67

60.844 - Hydrogen3.560 - Nitrogen4.904 - Carbon monoxide7.288 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.844 MM 1.33676 1.20865e-1 1.61567e-1 Hydrogen 2.783 - - - Oxygen 3.560 BB 145.15636 1.92061e-3 2.78789e-1 Nitrogen 4.904 BB 103.72206 1.97849e-3 2.05213e-1 Carbon monoxide 7.288 BB 79.22163 2.06789e-3 1.63822e-1 Methane 8.950 - - - Carbon dioxide

Totals : 8.09391e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1601.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:30:44 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 17:01:16 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 4:45:00 PM (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1602.D)

A

r ea

: 1.

4 1 73

80.831 - Hydrogen3.558 - Nitrogen4.903 - Carbon monoxide7.287 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.831 MM 1.41738 1.20587e-1 1.70917e-1 Hydrogen 2.783 - - - Oxygen 3.558 BB 112.10709 1.83542e-3 2.05764e-1 Nitrogen 4.903 BB 104.80928 1.97850e-3 2.07365e-1 Carbon monoxide 7.287 BB 79.58950 2.06835e-3 1.64619e-1 Methane 8.950 - - - Carbon dioxide

Totals : 7.48666e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1602.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:30:49 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 17:24:05 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 5:03:52 PM (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1603.D)

A

r ea

: 1.

4 3 13

50.844 - Hydrogen3.556 - Nitrogen4.902 - Carbon monoxide7.286 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.844 MM 1.43135 1.20235e-1 1.72098e-1 Hydrogen 2.783 - - - Oxygen 3.556 BB 108.09927 1.82588e-3 1.97376e-1 Nitrogen 4.902 BB 101.25681 1.97847e-3 2.00334e-1 Carbon monoxide 7.286 BB 77.54078 2.06634e-3 1.60225e-1 Methane 8.950 - - - Carbon dioxide

Totals : 7.30033e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1603.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:30:55 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 17:46:51 Inj : 4 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 5:34:42 PM (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1604.D)

A

r ea

: 1.

4 3 69

60.821 - Hydrogen3.544 - Nitrogen4.894 - Carbon monoxide7.284 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.821 MM 1.43696 1.20096e-1 1.72572e-1 Hydrogen 2.783 - - - Oxygen 3.544 BB 104.50573 1.82588e-3 1.90814e-1 Nitrogen 4.894 BB 99.28066 1.97847e-3 1.96424e-1 Carbon monoxide 7.284 BB 75.62451 2.06634e-3 1.56266e-1 Methane 8.950 - - - Carbon dioxide

Totals : 7.16077e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1604.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:00 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 18:09:38 Inj : 5 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 5:45:59 PM (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1605.D)

A

r ea

: 1.

2 9 910.846 - Hydrogen3.564 - Nitrogen4.906 - Carbon monoxide7.286 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.846 MM 1.29910 1.20865e-1 1.57015e-1 Hydrogen 2.783 - - - Oxygen 3.564 BB 110.33025 1.82940e-3 2.01838e-1 Nitrogen 4.906 BB 103.93967 1.97849e-3 2.05644e-1 Carbon monoxide 7.286 BB 79.14066 2.06779e-3 1.63646e-1 Methane 8.950 - - - Carbon dioxide

Totals : 7.28143e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1605.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:06 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 18:32:27 Inj : 6 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 6:09:24 PM (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1606.D)

A

r ea

: 1.

3 5 45

90.862 - Hydrogen3.581 - Nitrogen4.915 - Carbon monoxide7.288 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.862 MM 1.35459 1.20865e-1 1.63722e-1 Hydrogen 2.783 - - - Oxygen 3.581 BB 113.53730 1.84014e-3 2.08924e-1 Nitrogen 4.915 BB 106.72567 1.97852e-3 2.11159e-1 Carbon monoxide 7.288 BB 81.08928 2.07020e-3 1.67871e-1 Methane 8.950 - - - Carbon dioxide

Totals : 7.51676e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1606.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:11 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 16 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 19:27:12 Inj : 7 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 7:16:24 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 25 uV

-30 -20 -10

0 10 20 30 40 TCD1 A, (GC110P104\012F1607.D)

A

r ea

: 1.

5 4 16

60.803 - Hydrogen3.534 - Nitrogen4.889 - Carbon monoxide7.283 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.803 MM 1.54166 1.17681e-1 1.81424e-1 Hydrogen 2.783 - - - Oxygen 3.534 BB 101.67350 1.82588e-3 1.85643e-1 Nitrogen 4.889 BB 98.01877 1.97847e-3 1.93927e-1 Carbon monoxide 7.283 BB 74.91630 2.06634e-3 1.54802e-1 Methane 8.950 - - - Carbon dioxide

Totals : 7.15797e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1607.D Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:17 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 3 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 00:26:09 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 80 TCD1 A, (GC110P104\012F0301.D)0.787 - Hydrogen3.513 - Nitrogen4.869 - Carbon monoxide7.273 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.787 BB 8.93214 9.02645e-2 8.06255e-1 Hydrogen 2.783 - - - Oxygen 3.513 BB 451.74521 2.11673e-3 9.56225e-1 Nitrogen 4.869 BB 491.77716 1.97939e-3 9.73417e-1 Carbon monoxide 7.273 BB 364.50925 2.14631e-3 7.82350e-1 Methane 8.950 - - - Carbon dioxide

Totals : 3.51825

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0301.D Sample Name: gc110p104 #FG1 ENV(1=636,2=83.86)

Betty Reprocess 1/12/2010 6:26:25 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 3 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 00:50:03 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 80 TCD1 A, (GC110P104\012F0302.D)0.786 - Hydrogen3.513 - Nitrogen4.870 - Carbon monoxide7.273 - Methane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.786 BB 9.01676 9.02108e-2 8.13410e-1 Hydrogen 2.783 - - - Oxygen 3.513 BB 451.83801 2.11675e-3 9.56430e-1 Nitrogen 4.870 BB 491.73611 1.97939e-3 9.73336e-1 Carbon monoxide 7.273 BB 364.53162 2.14631e-3 7.82398e-1 Methane 8.950 - - - Carbon dioxide

Totals : 3.52557

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0302.D Sample Name: gc110p104 #FG1 ENV(1=636,2=83.86)

Betty Reprocess 1/12/2010 6:26:34 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 2 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 07-Jan-10, 23:11:22 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 11:12:17 PM by JBB (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-50

0 50 100 150 200 250 300 TCD1 A, (GC110P104\012F0201.D)0.786 - Hydrogen3.476 - Nitrogen4.834 - Carbon monoxide7.245 - Methane9.104 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.786 BB 49.16809 8.55843e-2 4.20802 Hydrogen 2.783 - - - Oxygen 3.476 BB 2244.57520 2.19090e-3 4.91764 Nitrogen 4.834 BB 2452.32544 1.97958e-3 4.85457 Carbon monoxide 7.245 BB 1802.24854 2.16368e-3 3.89949 Methane 9.104 BB 8.13546 1.25078e-3 1.01757e-2 Carbon dioxide

Totals : 17.88990

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0201.D Sample Name: gc110p104 #FG2 ENV(1=318,2=377.39)

Betty Reprocess 1/12/2010 6:25:56 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 2 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 07-Jan-10, 23:35:25 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 11:12:17 PM by JBB (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-50

0 50 100 150 200 250 300 TCD1 A, (GC110P104\012F0202.D)0.784 - Hydrogen3.475 - Nitrogen4.833 - Carbon monoxide7.244 - Methane9.103 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.784 BB 49.23183 8.55830e-2 4.21341 Hydrogen 2.783 - - - Oxygen 3.475 BB 2248.55176 2.19093e-3 4.92643 Nitrogen 4.833 BB 2451.26782 1.97958e-3 4.85248 Carbon monoxide 7.244 BB 1801.92871 2.16368e-3 3.89880 Methane 9.103 BB 7.57725 1.25078e-3 9.47747e-3 Carbon dioxide

Totals : 17.90059

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0202.D Sample Name: gc110p104 #FG2 ENV(1=318,2=377.39)

Betty Reprocess 1/12/2010 6:26:04 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 1 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 07-Jan-10, 21:58:46 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:58:39 PM by JBB (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 100 200 300 400 500 TCD1 A, (GC110P104\012F0101.D)0.786 - Hydrogen3.441 - Nitrogen4.798 - Carbon monoxide7.217 - Methane9.098 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.786 BB 104.96503 8.50321e-2 8.92539 Hydrogen 2.783 - - - Oxygen 3.441 BB 4581.13867 2.20043e-3 10.08049 Nitrogen 4.798 BB 4986.64502 1.97960e-3 9.87158 Carbon monoxide 7.217 BB 3661.30444 2.16592e-3 7.93008 Methane 9.098 BB 15.16464 1.25078e-3 1.89676e-2 Carbon dioxide

Totals : 36.82651

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0101.D Sample Name: gc110p104 #FG3 ENV(1=0,2=377.39)

Betty Reprocess 1/12/2010 6:25:14 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 1 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 07-Jan-10, 22:23:00 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:58:39 PM by JBB (modified after loading) Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 100 200 300 400 500 TCD1 A, (GC110P104\012F0102.D)0.784 - Hydrogen3.436 - Nitrogen4.796 - Carbon monoxide7.215 - Methane9.098 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.784 BB 104.47949 8.50343e-2 8.88434 Hydrogen 2.783 - - - Oxygen 3.436 BB 4542.57568 2.20036e-3 9.99528 Nitrogen 4.796 BB 4944.52441 1.97960e-3 9.78819 Carbon monoxide 7.215 BB 3634.91138 2.16590e-3 7.87286 Methane 9.098 BB 13.99536 1.25078e-3 1.75051e-2 Carbon dioxide

Totals : 36.55818

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0102.D Sample Name: gc110p104 #FG3 ENV(1=0,2=377.39)

Betty Reprocess 1/12/2010 6:25:39 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 19:49:58 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 7:16:24 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1701.D)3.124 - Oxygen3.548 - Nitrogen7.286 - Methane9.101 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.124 BB 92.88748 2.19491e-3 2.03880e-1 Oxygen 3.548 BB 23.51696 1.82588e-3 4.29390e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 BB 5.73110 2.06634e-3 1.18424e-2 Methane 9.101 BB 157.23827 1.25078e-3 1.96670e-1 Carbon dioxide

Totals : 4.55332e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1701.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:55:27 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 20:12:36 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 7:16:24 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1702.D)3.134 - Oxygen3.558 - Nitrogen9.102 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.134 BB 90.21473 2.19054e-3 1.97619e-1 Oxygen 3.558 BB 15.57372 1.82588e-3 2.84357e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.102 BB 162.19136 1.25120e-3 2.02934e-1 Carbon dioxide

Totals : 4.28989e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1702.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:03 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 20:58:03 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 8:47:38 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1703.D)3.142 - Oxygen3.567 - Nitrogen9.100 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.142 BB 86.68782 2.19054e-3 1.89893e-1 Oxygen 3.567 BB 14.82982 1.82588e-3 2.70774e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.100 BB 168.58168 1.25199e-3 2.11062e-1 Carbon dioxide

Totals : 4.28033e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1703.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:11 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 21:20:40 Inj : 4 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 8:47:38 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1704.D)3.138 - Oxygen3.565 - Nitrogen9.098 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.138 BB 86.56775 2.19054e-3 1.89630e-1 Oxygen 3.565 BB 13.95775 1.82588e-3 2.54851e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.098 BB 167.37762 1.25184e-3 2.09530e-1 Carbon dioxide

Totals : 4.24646e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1704.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:19 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 21:43:19 Inj : 5 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 8:47:38 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 0 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1705.D)3.160 - Oxygen3.585 - Nitrogen9.099 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.160 BB 89.77115 2.19054e-3 1.96648e-1 Oxygen 3.585 BB 14.05143 1.82588e-3 2.56562e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.099 BB 174.80219 1.25269e-3 2.18974e-1 Carbon dioxide

Totals : 4.41277e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1705.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:28 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 22:05:57 Inj : 6 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 8:47:38 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1706.D)3.142 - Oxygen3.568 - Nitrogen9.100 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.142 BB 88.20757 2.19054e-3 1.93223e-1 Oxygen 3.568 BB 13.20723 1.82588e-3 2.41148e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.100 BB 171.04898 1.25227e-3 2.14200e-1 Carbon dioxide

Totals : 4.31537e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1706.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:36 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 17 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 22:32:23 Inj : 7 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 11:55:20 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F1707.D)3.142 - Oxygen3.570 - Nitrogen9.099 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 11:55:08 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.142 BB 88.74271 2.19054e-3 1.94395e-1 Oxygen 3.570 BB 12.88785 1.82588e-3 2.35316e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.099 BB 171.22386 1.25229e-3 2.14422e-1 Carbon dioxide

Totals : 4.32349e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1707.D Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:44 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 6 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 04:09:45 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-25

0 25 50 75 100 125 150 TCD1 A, (GC110P104\012F0601.D)3.098 - Oxygen3.525 - Nitrogen9.085 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.098 BB 406.26132 2.33827e-3 9.49948e-1 Oxygen 3.525 BB 7.74942 1.82588e-3 1.41495e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.085 BB 769.99377 1.26753e-3 9.75990e-1 Carbon dioxide

Totals : 1.94009

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0601.D Sample Name: gc110p104 #FG4 ENV(1=636,3=79.71)

Betty Reprocess 1/12/2010 6:27:42 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 6 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 04:33:25 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-25

0 25 50 75 100 125 150 TCD1 A, (GC110P104\012F0602.D)3.096 - Oxygen3.521 - Nitrogen9.086 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.096 BB 405.81430 2.33822e-3 9.48883e-1 Oxygen 3.521 BB 5.81061 1.82588e-3 1.06095e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.086 BB 768.20099 1.26752e-3 9.73710e-1 Carbon dioxide

Totals : 1.93320

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0602.D Sample Name: gc110p104 #FG4 ENV(1=636,3=79.71)

Betty Reprocess 1/12/2010 6:27:50 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 5 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 02:58:25 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 100 200 300 400 500 600 TCD1 A, (GC110P104\012F0501.D)3.071 - Oxygen9.044 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.071 BB 2052.44409 2.37235e-3 4.86911 Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.044 BB 3824.38086 1.27101e-3 4.86083 Carbon dioxide

Totals : 9.72994

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0501.D Sample Name: gc110p104 #FG5 ENV(1=318.2,3=358.71)

Betty Reprocess 1/12/2010 6:27:18 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 5 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 03:22:16 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 100 200 300 400 500 600 TCD1 A, (GC110P104\012F0502.D)3.073 - Oxygen9.045 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.073 BB 2056.30591 2.37236e-3 4.87831 Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.045 BB 3830.85547 1.27101e-3 4.86906 Carbon dioxide

Totals : 9.74737

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0502.D Sample Name: gc110p104 #FG5 ENV(1=318.2,3=358.71)

Betty Reprocess 1/12/2010 6:27:26 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 4 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 01:37:30 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 200 400 600 800 1000 TCD1 A, (GC110P104\012F0401.D)3.038 - Oxygen3.507 - Nitrogen4.892 - Carbon monoxide7.282 - Methane9.008 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.038 BV 4226.03662 2.37667e-3 10.04391 Oxygen 3.507 VB 138.33720 1.90637e-3 2.63722e-1 Nitrogen 4.892 BB 8.33619 1.97847e-3 1.64929e-2 Carbon monoxide 7.282 BB 6.94967 2.06634e-3 1.43604e-2 Methane 9.008 BB 7668.27734 1.27145e-3 9.74983 Carbon dioxide

Totals : 20.08832

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0401.D Sample Name: gc110p104 #FG6 ENV(1=0,3=358.71)

Betty Reprocess 1/12/2010 6:26:52 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 4 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 08-Jan-10, 02:10:23 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 200 400 600 800 1000 TCD1 A, (GC110P104\012F0402.D)3.040 - Oxygen9.007 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.040 BB 4179.34570 2.37663e-3 9.93275 Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 9.007 BB 7687.08057 1.27145e-3 9.77374 Carbon dioxide

Totals : 19.70650

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0402.D Sample Name: gc110p104 #FG6 ENV(1=0,3=358.71)

Betty Reprocess 1/12/2010 6:27:00 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 26 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 11-Jan-10, 19:03:47 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/11/2010 6:49:52 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 80 TCD1 A, (GC110P104\012F2601.D)0.767 - Hydrogen3.519 - Nitrogen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.767 BB 624.30151 8.46272e-2 52.83289 Hydrogen 2.783 - - - Oxygen 3.519 BB 8.61831 1.82588e-3 1.57360e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 52.84863

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F2601.D Sample Name: H2 40% AX13607 ENV(1=424,5=396) #10

Betty Reprocess 1/12/2010 6:37:24 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 26 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 11-Jan-10, 19:41:37 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/11/2010 6:49:52 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

-20

0 20 40 60 TCD1 A, (GC110P104\012F2602.D)0.767 - Hydrogen3.528 - Nitrogen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.767 BB 624.25305 8.46272e-2 52.82879 Hydrogen 2.783 - - - Oxygen 3.528 BB 8.83441 1.82588e-3 1.61305e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 52.84493

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F2602.D Sample Name: H2 40% AX13607 ENV(1=424,5=396) #10

Betty Reprocess 1/12/2010 6:37:32 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 3 Injection Date : 09-Jan-10, 00:03:21 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 50 100 150 200 250 TCD1 A, (GC110P104\003F1801.D)0.791 - Hydrogen3.568 - Nitrogen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.791 BB 1886.04126 8.45725e-2 159.50716 Hydrogen 2.783 - - - Oxygen 3.568 BB 24.72860 1.82588e-3 4.51513e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 159.55231

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F1801.D Sample Name: H2 UHP Matheson AX13607 #9

Betty Reprocess 1/12/2010 6:33:54 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 18 Acq. Instrument : Betty online Location : Vial 3 Injection Date : 09-Jan-10, 00:25:08 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 50 100 150 200 250 TCD1 A, (GC110P104\003F1802.D)0.798 - Hydrogen3.574 - Nitrogen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.798 BB 1906.76587 8.45722e-2 161.25933 Hydrogen 2.783 - - - Oxygen 3.574 BB 25.35750 1.82588e-3 4.62996e-2 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 161.30563

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F1802.D Sample Name: H2 UHP Matheson AX13607 #9

Betty Reprocess 1/12/2010 6:34:03 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 39 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 12-Jan-10, 17:17:37 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 4:41:41 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 TCD1 A, (GC110P104\012F3901.D)2.785 - Oxygen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.785 BB 4.39550e4 2.38037e-3 104.62906 Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 104.62906

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F3901.D Sample Name: O2 AX38764 ENV(1=0,6=450) #9

Betty Reprocess 1/12/2010 6:43:31 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 39 Acq. Instrument : Betty online Location : Vial 12 Injection Date : 12-Jan-10, 17:39:57 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 4:41:41 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 TCD1 A, (GC110P104\012F3902.D)2.783 - Oxygen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 BB 4.40748e4 2.38037e-3 104.91421 Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 104.91421

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F3902.D Sample Name: O2 AX38764 ENV(1=0,6=450) #9

Betty Reprocess 1/12/2010 6:43:39 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 38 Acq. Instrument : Betty online Location : Vial 3 Injection Date : 12-Jan-10, 15:55:23 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 1:33:58 AM by JBB Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 TCD1 A, (GC110P104\003F3801.D)3.003 - Oxygen3.126 - Nitrogen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.003 BV 4.95237 2.19054e-3 1.08484e-2 Oxygen 3.126 VB 4.72424e4 2.20870e-3 104.34448 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 104.35533

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F3801.D Sample Name: House cryo N2

Betty Reprocess 1/12/2010 6:43:06 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 38 Acq. Instrument : Betty online Location : Vial 3 Injection Date : 12-Jan-10, 16:16:39 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 3:55:58 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 TCD1 A, (GC110P104\003F3802.D)2.998 - Oxygen3.125 - Nitrogen

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.998 BV 55.69423 2.19054e-3 1.22001e-1 Oxygen 3.125 VB 4.70101e4 2.20870e-3 103.83102 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 103.95302

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F3802.D Sample Name: House cryo N2

Betty Reprocess 1/12/2010 6:43:14 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 21 Acq. Instrument : Betty online Location : Vial 10 Injection Date : 09-Jan-10, 03:35:37 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 TCD1 A, (GC110P104\010F2101.D)3.1393.545 - Nitrogen4.502 - Carbon monoxide9.105 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.545 BB 165.80986 1.95661e-3 3.24425e-1 Nitrogen 4.502 BB 5.46928e4 1.97962e-3 108.27112 Carbon monoxide 7.286 - - - Methane 9.105 BB 15.69188 1.25078e-3 1.96271e-2 Carbon dioxide

Totals : 108.61518

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\010F2101.D Sample Name: CO 99+% Aldrich 03611BJ #9

Betty Reprocess 1/12/2010 6:35:18 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 21 Acq. Instrument : Betty online Location : Vial 10 Injection Date : 09-Jan-10, 03:57:37 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 TCD1 A, (GC110P104\010F2102.D)3.1413.548 - Nitrogen4.504 - Carbon monoxide9.106 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.548 BB 165.22366 1.95571e-3 3.23130e-1 Nitrogen 4.504 BB 5.46037e4 1.97962e-3 108.09478 Carbon monoxide 7.286 - - - Methane 9.106 BB 14.99084 1.25078e-3 1.87502e-2 Carbon dioxide

Totals : 108.43666

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\010F2102.D Sample Name: CO 99+% Aldrich 03611BJ #9

Betty Reprocess 1/12/2010 6:35:27 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 22 Acq. Instrument : Betty online Location : Vial 4 Injection Date : 09-Jan-10, 04:41:17 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 2500 3000 TCD1 A, (GC110P104\004F2201.D)3.1473.567 - Nitrogen6.934 - Methane9.107 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.567 BB 124.35021 1.87226e-3 2.32816e-1 Nitrogen 4.902 - - - Carbon monoxide 6.934 BB 4.91733e4 2.16792e-3 106.60407 Methane 9.107 BB 5.12652 1.25078e-3 6.41214e-3 Carbon dioxide

Totals : 106.84330

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\004F2201.D Sample Name: CH4 99+% Aldrich MKBB4558 #9

Betty Reprocess 1/12/2010 6:35:44 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 22 Acq. Instrument : Betty online Location : Vial 4 Injection Date : 09-Jan-10, 05:03:07 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 500 1000 1500 2000 2500 3000 TCD1 A, (GC110P104\004F2202.D)3.1433.562 - Nitrogen6.934 - Methane9.110 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.562 BB 123.43662 1.86977e-3 2.30798e-1 Nitrogen 4.902 - - - Carbon monoxide 6.934 BB 4.89184e4 2.16792e-3 106.05134 Methane 9.110 BB 5.01183 1.25078e-3 6.26870e-3 Carbon dioxide

Totals : 106.28840

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\004F2202.D Sample Name: CH4 99+% Aldrich MKBB4558 #9

Betty Reprocess 1/12/2010 6:35:53 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 20 Acq. Instrument : Betty online Location : Vial 6 Injection Date : 09-Jan-10, 02:30:00 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 1000 2000 3000 4000 TCD1 A, (GC110P104\006F2001.D)3.1503.564 - Nitrogen8.735 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.564 BB 634.06775 2.14343e-3 1.35908 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.735 BB S 8.31270e4 1.27185e-3 105.72481 Carbon dioxide

Totals : 107.08389

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\006F2001.D Sample Name: CO2 99.8+% Adlrich 01629AJ #9

Betty Reprocess 1/12/2010 6:34:52 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 20 Acq. Instrument : Betty online Location : Vial 6 Injection Date : 09-Jan-10, 02:51:55 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/12/2010 6:16:57 PM

min 2 4 6 8 10 25 uV

0 1000 2000 3000 4000 TCD1 A, (GC110P104\006F2002.D)3.1553.565 - Nitrogen8.737 - Carbon dioxide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/12/2010 6:10:49 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A,

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.565 BB 901.61365 2.16307e-3 1.95025 Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.737 BB S 8.21878e4 1.27185e-3 104.53026 Carbon dioxide

Totals : 106.48051

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 - - - Methane 1.354 - - - Ethane 2.130 - - - Propane 4.772 - - - Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\006F2002.D Sample Name: CO2 99.8+% Adlrich 01629AJ #9

Betty Reprocess 1/12/2010 6:35:01 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 11 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 10:00:19 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1101.D)

A

r ea

: 0.

2 4 90

8 3

A

r ea

: 0.

3 6 24

2 71.0991.129 - Methane1.354 - Ethane2.136 - Propane4.774 - Butane6.364 - Pentane7.281 - Hexane7.964 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PB 1.32972e-1 3.70546 4.92723e-1 Methane 1.354 MM 2.49083e-1 2.02772 5.05069e-1 Ethane 2.136 MM 3.62427e-1 1.37041 4.96676e-1 Propane 4.774 BB 5.10125e-1 9.89060e-1 5.04544e-1 Butane 6.364 BB 5.96716e-1 8.11293e-1 4.84112e-1 Pentane 7.281 BB 7.47089e-1 6.92816e-1 5.17595e-1 Hexane 7.964 BB 7.89259e-1 6.15604e-1 4.85871e-1 Heptane

Totals : 3.48659

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1101.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Betty Reprocess 1/12/2010 4:03:07 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 11 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 10:23:30 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1102.D)

A r ea

: 0.

4 9 28

3 51.0991.129 - Methane1.354 - Ethane2.131 - Propane4.769 - Butane6.364 - Pentane7.281 - Hexane7.964 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PB 1.33097e-1 3.70546 4.93187e-1 Methane 1.354 BB 2.50025e-1 2.02756 5.06940e-1 Ethane 2.131 BB 3.71790e-1 1.36954 5.09182e-1 Propane 4.769 MM 4.92835e-1 9.88999e-1 4.87414e-1 Butane 6.364 BB 6.09468e-1 8.11293e-1 4.94458e-1 Pentane 7.281 BB 7.40346e-1 6.92867e-1 5.12961e-1 Hexane 7.964 BB 7.87899e-1 6.15647e-1 4.85068e-1 Heptane

Totals : 3.48921

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1102.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Betty Reprocess 1/12/2010 4:03:15 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 11 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 10:46:37 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1103.D)

A r ea

: 0.

5 1 36

5 41.0991.129 - Methane1.354 - Ethane2.129 - Propane4.773 - Butane6.363 - Pentane7.281 - Hexane7.964 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PB 1.40135e-1 3.69758 5.18163e-1 Methane 1.354 BB 2.43084e-1 2.02818 4.93020e-1 Ethane 2.129 BB 3.51653e-1 1.37041 4.81910e-1 Propane 4.773 MM 5.13654e-1 9.89107e-1 5.08058e-1 Butane 6.363 BB 6.17081e-1 8.11133e-1 5.00535e-1 Pentane 7.281 BB 7.45524e-1 6.92837e-1 5.16527e-1 Hexane 7.964 BB 7.91644e-1 6.15529e-1 4.87280e-1 Heptane

Totals : 3.50549

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1103.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Betty Reprocess 1/12/2010 4:03:22 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 20:20:03 Inj : 5 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4005.D)1.0961.125 - Methane1.350 - Ethane2.122 - Propane4.771 - Butane6.362 - Pentane6.9047.0417.1707.279 - Hexane7.3667.4447.6087.7487.8667.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.125 PB 1.38697e-1 3.69960 5.13121e-1 Methane 1.350 BB 2.60857e-1 2.02586 5.28459e-1 Ethane 2.122 BB 3.77518e-1 1.36891 5.16788e-1 Propane 4.771 BB 4.99911e-1 9.88999e-1 4.94412e-1 Butane 6.362 BB 5.72031e-1 8.11291e-1 4.64084e-1 Pentane 7.279 VV 9.75770e-1 6.90469e-1 6.73739e-1 Hexane 7.962 VV 8.96783e-1 6.12613e-1 5.49381e-1 Heptane

Totals : 3.73998

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4005.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:20 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 20:42:25 Inj : 6 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4006.D)1.0951.124 - Methane1.349 - Ethane2.116 - Propane4.772 - Butane6.362 - Pentane7.279 - Hexane7.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.124 PB 1.39506e-1 3.69846 5.15956e-1 Methane 1.349 BB 2.52463e-1 2.02716 5.11783e-1 Ethane 2.116 BB 3.83528e-1 1.36827 5.24769e-1 Propane 4.772 BB 5.44910e-1 9.89493e-1 5.39184e-1 Butane 6.362 BB 6.27735e-1 8.10914e-1 5.09039e-1 Pentane 7.279 BB 7.17647e-1 6.92867e-1 4.97234e-1 Hexane 7.962 BB 7.86459e-1 6.15651e-1 4.84184e-1 Heptane

Totals : 3.58215

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4006.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:25 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 21:04:45 Inj : 7 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4007.D)1.0951.124 - Methane1.349 - Ethane2.124 - Propane4.767 - Butane6.362 - Pentane7.279 - Hexane7.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.124 PB 1.36451e-1 3.70282 5.05252e-1 Methane 1.349 BB 2.51474e-1 2.02732 5.09820e-1 Ethane 2.124 BB 3.90087e-1 1.36759 5.33480e-1 Propane 4.767 BB 5.11370e-1 9.89077e-1 5.05784e-1 Butane 6.362 BB 6.21943e-1 8.11031e-1 5.04415e-1 Pentane 7.279 BB 7.59313e-1 6.92654e-1 5.25942e-1 Hexane 7.962 BB 7.95051e-1 6.15423e-1 4.89293e-1 Heptane

Totals : 3.57399

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4007.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:31 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 21:26:59 Inj : 8 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4008.D)1.0961.126 - Methane1.351 - Ethane2.119 - Propane4.763 - Butane6.362 - Pentane7.279 - Hexane7.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.126 PB 1.33128e-1 3.70546 4.93300e-1 Methane 1.351 BB 2.56826e-1 2.02647 5.20452e-1 Ethane 2.119 BB 4.63798e-1 1.36130 6.31366e-1 Propane 4.763 BB 5.33102e-1 9.89352e-1 5.27426e-1 Butane 6.362 BB 6.15952e-1 8.11155e-1 4.99632e-1 Pentane 7.279 BB 7.49470e-1 6.92784e-1 5.19221e-1 Hexane 7.962 BB 8.91693e-1 6.12739e-1 5.46375e-1 Heptane

Totals : 3.73777

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4008.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:36 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 21:54:14 Inj : 9 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4009.D)1.0951.125 - Methane1.350 - Ethane2.116 - Propane4.768 - Butane6.362 - Pentane7.279 - Hexane7.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.125 PB 1.37988e-1 3.70060 5.10640e-1 Methane 1.350 BB 2.73482e-1 2.02404 5.53538e-1 Ethane 2.116 BB 3.91750e-1 1.36742 5.35688e-1 Propane 4.768 BB 5.15858e-1 9.89136e-1 5.10254e-1 Butane 6.362 BB 6.18196e-1 8.11108e-1 5.01424e-1 Pentane 7.279 BB 7.74488e-1 6.92461e-1 5.36303e-1 Hexane 7.962 BB 8.24252e-1 6.14545e-1 5.06540e-1 Heptane

Totals : 3.65439

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4009.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:42 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 22:16:25 Inj : 10 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4010.D)1.0941.124 - Methane1.349 - Ethane2.128 - Propane4.772 - Butane6.362 - Pentane7.279 - Hexane7.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.124 PB 1.32027e-1 3.70546 4.89220e-1 Methane 1.349 BB 2.58097e-1 2.02628 5.22976e-1 Ethane 2.128 BB 4.11002e-1 1.36558 5.61254e-1 Propane 4.772 BB 5.22762e-1 9.89224e-1 5.17129e-1 Butane 6.362 BB 6.25905e-1 8.10951e-1 5.07578e-1 Pentane 7.279 BB 7.63898e-1 6.92595e-1 5.29072e-1 Hexane 7.962 BB 8.23590e-1 6.14565e-1 5.06149e-1 Heptane

Totals : 3.63338

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4010.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:53 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 40 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 12-Jan-10, 22:38:35 Inj : 11 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/12/2010 6:01:04 PM Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M Last changed : 1/13/2010 10:18:19 PM

min 2 4 6 8 10 pA

4 6 8 10 12 14 16 18 20 FID2 B, (GC110P104\028B4011.D)1.0941.123 - Methane1.348 - Ethane2.124 - Propane4.770 - Butane6.362 - Pentane7.279 - Hexane7.962 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/13/2010 10:14:02 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.123 PB 1.44223e-1 3.69208 5.32484e-1 Methane 1.348 BB 2.82534e-1 2.02284 5.71520e-1 Ethane 2.124 BB 4.16284e-1 1.36510 5.68269e-1 Propane 4.770 BB 5.15308e-1 9.89129e-1 5.09706e-1 Butane 6.362 BB 5.94757e-1 8.11291e-1 4.82521e-1 Pentane 7.279 BB 7.37672e-1 6.92867e-1 5.11108e-1 Hexane 7.962 BB 8.00652e-1 6.15249e-1 4.92601e-1 Heptane

Totals : 3.66821

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 2.783 - - - Oxygen 3.410 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4011.D Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:16:00 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 10 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 08:50:47 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1001.D)1.0991.129 - Methane1.354 - Ethane2.128 - Propane4.774 - Butane6.365 - Pentane7.282 - Hexane7.965 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PB 5.53671e-1 3.55263 1.96699 Methane 1.354 BB 9.79376e-1 1.99698 1.95580 Ethane 2.128 BB 1.51869 1.33816 2.03225 Propane 4.774 BB 1.99415 9.94097e-1 1.98238 Butane 6.365 BB 2.50332 8.01436e-1 2.00625 Pentane 7.282 BB 2.99717 6.85300e-1 2.05396 Hexane 7.965 BB 3.22493 5.96764e-1 1.92452 Heptane

Totals : 13.92215

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1001.D Sample Name: gc110p104 #C2 ENV(1=692.53,4=20)

Betty Reprocess 1/12/2010 4:02:43 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 10 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 09:13:58 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1002.D)1.0981.128 - Methane1.353 - Ethane2.126 - Propane4.773 - Butane6.365 - Pentane7.282 - Hexane7.965 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.128 PB 5.57310e-1 3.55231 1.97974 Methane 1.353 BB 9.87823e-1 1.99689 1.97258 Ethane 2.126 BB 1.49927 1.33829 2.00645 Propane 4.773 BB 2.00242 9.94104e-1 1.99061 Butane 6.365 BB 2.50754 8.01431e-1 2.00962 Pentane 7.282 BB 2.98740 6.85308e-1 2.04729 Hexane 7.965 BB 3.23920 5.96737e-1 1.93295 Heptane

Totals : 13.93924

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1002.D Sample Name: gc110p104 #C2 ENV(1=692.53,4=20)

Betty Reprocess 1/12/2010 4:02:51 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 10 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 09:37:07 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1003.D)1.0981.128 - Methane1.353 - Ethane2.127 - Propane4.773 - Butane6.365 - Pentane7.282 - Hexane7.964 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.128 PB 5.46936e-1 3.55324 1.94339 Methane 1.353 BB 9.91052e-1 1.99686 1.97899 Ethane 2.127 BB 1.54576 1.33798 2.06819 Propane 4.773 BB 2.03886 9.94135e-1 2.02691 Butane 6.365 BB 2.47764 8.01469e-1 1.98575 Pentane 7.282 BB 3.00554 6.85293e-1 2.05967 Hexane 7.964 BB 3.24216 5.96732e-1 1.93470 Heptane

Totals : 13.99761

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1003.D Sample Name: gc110p104 #C2 ENV(1=692.53,4=20)

Betty Reprocess 1/12/2010 4:02:59 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 07:41:03 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B0901.D)1.0991.128 - Methane1.354 - Ethane2.127 - Propane4.774 - Butane6.364 - Pentane7.1577.282 - Hexane7.965 - Heptane8.182

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.128 PB 2.77840 3.51330 9.76135 Methane 1.354 BB 4.97499 1.98856 9.89309 Ethane 2.127 BB 7.60298 1.33002 10.11210 Propane 4.774 BB 10.06287 9.95485e-1 10.01744 Butane 6.364 BB 12.41950 7.98903e-1 9.92198 Pentane 7.282 BB 14.95311 6.83305e-1 10.21753 Hexane 7.965 BB 16.14325 5.91879e-1 9.55485 Heptane

Totals : 69.47834

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0901.D Sample Name: gc110p104 #C3 ENV(1=636,4=100)

Betty Reprocess 1/12/2010 4:02:19 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 08:04:20 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B0902.D)1.1011.130 - Methane1.355 - Ethane2.129 - Propane4.774 - Butane6.0546.364 - Pentane7.282 - Hexane7.965 - Heptane8.180

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.130 PB 2.78876 3.51327 9.79764 Methane 1.355 BB 4.99637 1.98856 9.93555 Ethane 2.129 BB 7.65755 1.33000 10.18457 Propane 4.774 BB 10.16584 9.95489e-1 10.11997 Butane 6.364 BB 12.49228 7.98899e-1 9.98007 Pentane 7.282 BB 15.06768 6.83301e-1 10.29576 Hexane 7.965 BB 16.31054 5.91866e-1 9.65366 Heptane

Totals : 69.96723

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0902.D Sample Name: gc110p104 #C3 ENV(1=636,4=100)

Betty Reprocess 1/12/2010 4:02:27 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 08:27:32 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B0903.D)1.1001.129 - Methane1.355 - Ethane2.128 - Propane4.773 - Butane6.0526.364 - Pentane7.281 - Hexane7.5237.964 - Heptane8.178

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PB 2.83845 3.51309 9.97175 Methane 1.355 BB 4.96842 1.98857 9.88003 Ethane 2.128 BB 7.65300 1.33001 10.17853 Propane 4.773 BB 10.05984 9.95485e-1 10.01442 Butane 6.364 BB 12.41880 7.98903e-1 9.92142 Pentane 7.281 BB 15.02427 6.83302e-1 10.26612 Hexane 7.964 BB 16.15368 5.91878e-1 9.56101 Heptane

Totals : 69.79328

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0903.D Sample Name: gc110p104 #C3 ENV(1=636,4=100)

Betty Reprocess 1/12/2010 4:02:35 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 8 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 06:30:58 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B0801.D)1.1031.131 - Methane1.356 - Ethane2.129 - Propane4.774 - Butane6.0506.365 - Pentane7.0237.1597.281 - Hexane7.5247.8257.965 - Heptane8.1808.231

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.131 PB 11.04649 3.50598 38.72872 Methane 1.356 BB 19.70167 1.98702 39.14764 Ethane 2.129 BB 30.00404 1.32850 39.86042 Propane 4.774 BB 39.87003 9.95742e-1 39.70025 Butane 6.365 BB 48.98482 7.98426e-1 39.11074 Pentane 7.281 BB 59.01889 6.82931e-1 40.30584 Hexane 7.965 VB 63.80853 5.90968e-1 37.70879 Heptane

Totals : 274.56240

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0801.D Sample Name: gc110p104 #C4 ENV(1=424,4=400)

Betty Reprocess 1/12/2010 4:01:55 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 8 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 06:54:24 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B0802.D)1.1051.133 - Methane1.358 - Ethane2.132 - Propane4.775 - Butane6.0506.365 - Pentane7.0317.1587.281 - Hexane7.5237.8247.9037.965 - Heptane8.1818.229

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.133 PB 11.11530 3.50596 38.96978 Methane 1.358 BB 19.74178 1.98702 39.22731 Ethane 2.132 BB 30.09650 1.32850 39.98320 Propane 4.775 BB 39.94662 9.95742e-1 39.77652 Butane 6.365 BB 49.11836 7.98425e-1 39.21734 Pentane 7.281 BB 59.16596 6.82931e-1 40.40626 Hexane 7.965 VB 63.81134 5.90968e-1 37.71046 Heptane

Totals : 275.29088

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0802.D Sample Name: gc110p104 #C4 ENV(1=424,4=400)

Betty Reprocess 1/12/2010 4:02:03 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 8 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 07:17:43 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B0803.D)1.1021.130 - Methane1.355 - Ethane2.129 - Propane4.774 - Butane6.0526.365 - Pentane7.0287.1587.282 - Hexane7.5237.8237.9057.965 - Heptane8.180

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.130 PB 11.03196 3.50598 38.67781 Methane 1.355 BB 19.60324 1.98702 38.95210 Ethane 2.129 BB 29.91669 1.32850 39.74443 Propane 4.774 BB 39.67163 9.95741e-1 39.50268 Butane 6.365 BB 48.81525 7.98426e-1 38.97538 Pentane 7.282 BB 58.83771 6.82932e-1 40.18213 Hexane 7.965 VB 63.45609 5.90970e-1 37.50062 Heptane

Totals : 273.53514

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0803.D Sample Name: gc110p104 #C4 ENV(1=424,4=400)

Betty Reprocess 1/12/2010 4:02:11 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 19 Acq. Instrument : Betty online Location : Vial 32 Injection Date : 09-Jan-10, 01:24:43 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\032B1901.D)1.1051.131 - Methane1.356 - Ethane2.128 - Propane4.773 - Butane6.0496.362 - Pentane7.0267.1557.279 - Hexane7.5207.8217.8947.962 - Heptane8.1778.226

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.131 PB 28.19965 3.50448 98.82505 Methane 1.356 BB 48.87247 1.98671 97.09544 Ethane 2.128 BB 74.27017 1.32819 98.64526 Propane 4.773 BB 98.56340 9.95793e-1 98.14877 Butane 6.362 BB 121.06608 7.98329e-1 96.65058 Pentane 7.279 BB 145.70467 6.82856e-1 99.49527 Hexane 7.962 VB 157.17064 5.90785e-1 92.85400 Heptane

Totals : 681.71437

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\032B1901.D Sample Name: gc110p104 #C5 A019379 #9

Betty Reprocess 1/12/2010 4:07:32 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 19 Acq. Instrument : Betty online Location : Vial 32 Injection Date : 09-Jan-10, 01:46:24 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\032B1902.D)1.1021.129 - Methane1.354 - Ethane2.126 - Propane4.770 - Butane6.0506.361 - Pentane7.0297.1557.279 - Hexane7.5207.8217.8967.962 - Heptane8.1778.227

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PB 28.06611 3.50448 98.35718 Methane 1.354 BB 48.61981 1.98671 96.59354 Ethane 2.126 BB 73.93579 1.32820 98.20121 Propane 4.770 BB 98.08015 9.95793e-1 97.66754 Butane 6.361 BB 120.51656 7.98329e-1 96.21193 Pentane 7.279 BB 145.06584 6.82856e-1 99.05907 Hexane 7.962 VB 156.45099 5.90785e-1 92.42893 Heptane

Totals : 678.51940

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\032B1902.D Sample Name: gc110p104 #C5 A019379 #9

Betty Reprocess 1/12/2010 4:07:40 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 19 Acq. Instrument : Betty online Location : Vial 32 Injection Date : 09-Jan-10, 02:08:12 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\032B1903.D)1.1011.127 - Methane1.352 - Ethane2.124 - Propane3.6714.768 - Butane6.0476.361 - Pentane7.0257.1547.278 - Hexane7.5207.7737.8227.8947.961 - Heptane8.1768.227

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.127 PB 28.05125 3.50448 98.30512 Methane 1.352 BB 48.62759 1.98671 96.60899 Ethane 2.124 BB 73.92005 1.32820 98.18030 Propane 4.768 BB 98.09365 9.95793e-1 97.68098 Butane 6.361 BB 120.46914 7.98330e-1 96.17407 Pentane 7.278 BB 144.94872 6.82856e-1 98.97910 Hexane 7.961 VB 156.25754 5.90785e-1 92.31467 Heptane

Totals : 678.24323

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\032B1903.D Sample Name: gc110p104 #C5 A019379 #9

Betty Reprocess 1/12/2010 4:07:48 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 13 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 12:18:59 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1301.D)1.0991.128 - Methane1.2651.353 - Ethane2.126 - Propane3.6754.771 - Butane5.0596.0496.366 - Pentane7.967 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.128 PV 304.26312 3.50360 1066.01718 Methane 1.353 VB 527.98383 1.98652 1048.85032 Ethane 2.126 BB 753.53271 1.32801 1000.69697 Propane 4.771 BV 1028.94653 9.95825e-1 1024.65057 Butane 6.366 BB 6.38529e-2 8.11293e-1 5.18034e-2 Pentane 7.281 - - - Hexane 7.967 BB 3.19884e-2 6.15651e-1 1.96937e-2 Heptane

Totals : 4140.28653

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1301.D Sample Name: gc110p104 #C6 ENV(1=636,5=105.54)

Betty Reprocess 1/12/2010 4:04:08 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 13 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 12:41:58 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1302.D)1.1001.129 - Methane1.2651.354 - Ethane2.126 - Propane3.6774.770 - Butane5.0606.049

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.129 PV 306.09540 3.50360 1072.43658 Methane 1.354 VB 531.21765 1.98652 1055.27431 Ethane 2.126 BB 758.24438 1.32801 1006.95401 Propane 4.770 BV 1035.10571 9.95825e-1 1030.78405 Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 4165.44895

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1302.D Sample Name: gc110p104 #C6 ENV(1=636,5=105.54)

Betty Reprocess 1/12/2010 4:04:16 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 13 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 13:04:57 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1303.D)1.0971.126 - Methane1.2631.351 - Ethane2.124 - Propane3.6714.769 - Butane5.0566.049

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.126 PV 303.47232 3.50360 1063.24659 Methane 1.351 VB 526.59491 1.98652 1046.09124 Ethane 2.124 BB 751.49084 1.32801 997.98540 Propane 4.769 BV 1025.73120 9.95825e-1 1021.44865 Butane 6.364 - - - Pentane 7.281 - - - Hexane 7.964 - - - Heptane

Totals : 4128.77187

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1303.D Sample Name: gc110p104 #C6 ENV(1=636,5=105.54)

Betty Reprocess 1/12/2010 4:04:24 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 12 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 11:09:45 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1201.D)1.1061.133 - Methane1.2701.357 - Ethane2.129 - Propane3.6774.770 - Butane5.0615.3005.8466.0506.365 - Pentane6.5837.0337.1567.282 - Hexane7.3297.4357.5127.7117.7597.964 - Heptane8.375

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.133 PV 2963.98413 3.50352 1.03844e4 Methane 1.357 VB S 5138.85498 1.98650 1.02083e4 Ethane 2.129 BB 7331.60645 1.32799 9736.29227 Propane 4.770 BV 1.00028e4 9.95828e-1 9961.03503 Butane 6.365 BB 6.35256e-1 8.10765e-1 5.15044e-1 Pentane 7.282 BV 2.05575e-1 6.92867e-1 1.42436e-1 Hexane 7.964 BB 3.01710e-1 6.15651e-1 1.85748e-1 Heptane

Totals : 4.02909e4

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1201.D Sample Name: gc110p104 #C7 ENV(1=0,5=474.93)

Betty Reprocess 1/12/2010 4:03:30 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 12 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 11:32:54 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1202.D)1.1041.131 - Methane1.2681.355 - Ethane2.127 - Propane3.6774.769 - Butane5.0605.2985.8476.0506.364 - Pentane6.5827.0337.156 - Hexane7.5107.7607.966 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.131 PV 2976.04688 3.50352 1.04266e4 Methane 1.355 VB S 5158.12598 1.98650 1.02466e4 Ethane 2.127 BB 7359.58887 1.32799 9773.45255 Propane 4.769 BV 1.00386e4 9.95828e-1 9996.67479 Butane 6.364 BB 5.52414e-1 8.11293e-1 4.48169e-1 Pentane 7.156 BB 1.21364e-1 6.92867e-1 8.40890e-2 Hexane 7.966 VB 3.18806e-1 6.15651e-1 1.96273e-1 Heptane

Totals : 4.04441e4

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1202.D Sample Name: gc110p104 #C7 ENV(1=0,5=474.93)

Betty Reprocess 1/12/2010 4:03:52 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 12 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 08-Jan-10, 11:55:55 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\ GC110P104.M Last changed : 1/7/2010 9:50:54 PM by JBB Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B1203.D)1.1051.131 - Methane1.2681.356 - Ethane2.128 - Propane3.6774.770 - Butane5.0615.2995.8496.0506.364 - Pentane6.5837.0337.1577.282 - Hexane7.5117.7607.967 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.131 PV 2967.53711 3.50352 1.03968e4 Methane 1.356 VB S 5142.88135 1.98650 1.02163e4 Ethane 2.128 BB 7335.46094 1.32799 9741.41098 Propane 4.770 BV 1.00100e4 9.95828e-1 9968.21297 Butane 6.364 BB 5.37764e-1 8.11293e-1 4.36284e-1 Pentane 7.282 BV 9.08920e-2 6.92867e-1 6.29760e-2 Hexane 7.967 BB 1.32513e-1 6.15651e-1 8.15820e-2 Heptane

Totals : 4.03234e4

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1203.D Sample Name: gc110p104 #C7 ENV(1=0,5=474.93)

Betty Reprocess 1/12/2010 4:04:00 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 24 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Jan-10, 06:56:31 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B2401.D)1.1031.131 - Methane1.2671.354 - Ethane2.124 - Propane3.6714.768 - Butane5.0595.2985.8416.0486.361 - Pentane6.7407.0127.1547.278 - Hexane7.5197.7667.8217.8967.962 - Heptane8.173

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.131 PB 1.78757e-1 3.65565 6.53475e-1 Methane 1.354 VB S 1.01553e4 1.98650 2.01736e4 Ethane 2.124 BB 1.53434e4 1.32799 2.03759e4 Propane 4.768 BV 4139.53223 9.95827e-1 4122.25966 Butane 6.361 BB 1023.66614 7.98271e-1 817.16335 Pentane 7.278 BB 608.37439 6.82817e-1 415.40819 Hexane 7.962 VB 357.16541 5.90715e-1 210.98279 Heptane

Totals : 4.61159e4

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2401.D Sample Name: gc110p104 #C8 ENV(1=424.6,6=467.62)

Betty Reprocess 1/12/2010 4:09:19 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 24 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Jan-10, 07:19:20 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B2402.D)1.1001.128 - Methane1.2641.351 - Ethane2.121 - Propane3.6694.767 - Butane5.0575.2975.8436.0476.361 - Pentane6.7357.0127.1547.278 - Hexane7.5207.7657.8217.8957.962 - Heptane8.1738.226

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.128 PB 1.68154e-1 3.66525 6.16325e-1 Methane 1.351 VB S 1.00861e4 1.98650 2.00360e4 Ethane 2.121 BB 1.52366e4 1.32799 2.02341e4 Propane 4.767 BV 4109.86621 9.95827e-1 4092.71740 Butane 6.361 BB 1016.26355 7.98271e-1 811.25413 Pentane 7.278 BB 603.96399 6.82817e-1 412.39675 Hexane 7.962 VB 354.54391 5.90715e-1 209.43438 Heptane

Totals : 4.57965e4

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2402.D Sample Name: gc110p104 #C8 ENV(1=424.6,6=467.62)

Betty Reprocess 1/12/2010 4:09:27 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 24 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Jan-10, 07:42:11 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B2403.D)1.1021.130 - Methane1.2661.352 - Ethane2.122 - Propane3.6714.768 - Butane5.0575.2945.8406.0486.360 - Pentane6.7327.0127.1547.278 - Hexane7.5207.7657.8217.8957.962 - Heptane8.173

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.130 PB 1.42857e-1 3.69389 5.27696e-1 Methane 1.352 VB S 1.00209e4 1.98650 1.99066e4 Ethane 2.122 BB 1.51388e4 1.32799 2.01041e4 Propane 4.768 BV 4083.37500 9.95827e-1 4066.33671 Butane 6.360 BB 1009.79877 7.98271e-1 806.09353 Pentane 7.278 BB 600.05615 6.82817e-1 409.72846 Hexane 7.962 VB 352.18039 5.90715e-1 208.03834 Heptane

Totals : 4.55014e4

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2403.D Sample Name: gc110p104 #C8 ENV(1=424.6,6=467.62)

Betty Reprocess 1/12/2010 4:09:36 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 23 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Jan-10, 05:47:58 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B2301.D)1.1061.132 - Methane1.2681.353 - Ethane2.122 - Propane3.6734.767 - Butane5.0585.2955.8486.0476.360 - Pentane6.7357.0117.1547.278 - Hexane7.5197.7647.8207.8947.961 - Heptane8.0718.1728.2268.543

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.132 PB 6.49008e-1 3.54542 2.30101 Methane 1.353 VB S 2.50756e4 1.98650 4.98127e4 Ethane 2.122 BB S 3.78892e4 1.32799 5.03164e4 Propane 4.767 BV 1.02189e4 9.95828e-1 1.01762e4 Butane 6.360 BB 2526.08008 7.98267e-1 2016.48569 Pentane 7.278 VB 1499.85876 6.82809e-1 1024.11764 Hexane 7.961 VB 879.06067 5.90682e-1 519.24513 Heptane

Totals : 1.13867e5

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2301.D Sample Name: gc110p104 #C9 ENV(1=0,6=467.62)

Betty Reprocess 1/12/2010 4:08:55 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 23 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Jan-10, 06:10:50 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B2302.D)1.1031.130 - Methane1.2661.350 - Ethane2.119 - Propane3.6694.5464.767 - Butane5.0575.2955.8456.0476.361 - Pentane6.5756.7357.0127.1547.278 - Hexane7.5207.7647.8217.8957.962 - Heptane8.0698.1738.226

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.130 PB 3.70220e-1 3.57697 1.32427 Methane 1.350 VB S 2.52360e4 1.98650 5.01313e4 Ethane 2.119 BB S 3.81401e4 1.32799 5.06496e4 Propane 4.767 VV 1.02852e4 9.95828e-1 1.02423e4 Butane 6.361 BB 2543.53394 7.98267e-1 2030.41847 Pentane 7.278 VB 1510.39673 6.82809e-1 1031.31300 Hexane 7.962 VV 885.69989 5.90682e-1 523.16664 Heptane

Totals : 1.14609e5

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2302.D Sample Name: gc110p104 #C9 ENV(1=0,6=467.62)

Betty Reprocess 1/12/2010 4:09:03 PM Page 1 of 2===================================================================== Acq. Operator : JBB Seq. Line : 23 Acq. Instrument : Betty online Location : Vial 28 Injection Date : 09-Jan-10, 06:33:39 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M Last changed : 1/8/2010 10:11:49 PM Analysis Method : G:\GC110P104.M Last changed : 1/12/2010 3:58:31 PM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P104\028B2303.D)1.1051.132 - Methane1.2681.352 - Ethane2.121 - Propane3.6734.5374.767 - Butane5.0595.2985.8456.0486.360 - Pentane6.5796.7367.0127.1547.278 - Hexane7.5207.7657.8217.8957.962 - Heptane8.1738.2278.4098.545

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.132 PB 2.54820e-1 3.61024 9.19962e-1 Methane 1.352 VB S 2.52629e4 1.98650 5.01848e4 Ethane 2.121 BB S 3.81777e4 1.32799 5.06996e4 Propane 4.767 VV 1.02960e4 9.95828e-1 1.02530e4 Butane 6.360 BV 2545.70264 7.98267e-1 2032.14967 Pentane 7.278 BB 1511.71875 6.82809e-1 1032.21569 Hexane 7.962 VB 886.73407 5.90682e-1 523.77749 Heptane

Totals : 1.14726e5

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name [min] [25 uV*s] [%] -------|------|----------|----------|----------|--|------------------ 0.840 - - - Hydrogen 3.115 - - - Oxygen 3.556 - - - Nitrogen 4.902 - - - Carbon monoxide 7.286 - - - Methane 8.950 - - - Carbon dioxide

Totals : 0.00000 Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2303.D Sample Name: gc110p104 #C9 ENV(1=0,6=467.62)

Betty Reprocess 1/12/2010 4:09:11 PM Page 1 of 2===================================================================== Acq. Operator : kam Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 09-Apr-10, 12:57:54 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 1/21/2010 9:48:47 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\025B0901.D)1.148 - Methane1.3762.1574.8015.8356.0696.3806.5937.0437.1717.2947.5367.7837.8367.9097.9778.1948.2448.4298.584

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/21/2010 9:48:15 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.148 PB 27.46096 3.50450 96.23704 Methane

Totals : 96.23704

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B0901.D Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 10:15:24 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 09-Apr-10, 13:16:01 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 1/21/2010 9:48:47 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\025B0902.D)1.146 - Methane1.3011.3742.1554.8015.8366.0686.3806.5997.0457.1717.2947.5367.7827.8367.9127.9778.1938.2448.4258.591

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/21/2010 9:48:15 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.146 PB 26.16014 3.50455 91.67961 Methane

Totals : 91.67961

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B0902.D Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 10:15:42 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 09-Apr-10, 13:34:55 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 1/21/2010 9:48:47 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\025B0903.D)1.145 - Methane1.3011.3732.1574.8035.8376.0696.3816.5967.0467.1727.2957.5367.7777.8387.9107.9788.1938.243

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/21/2010 9:48:15 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.145 PB 26.08904 3.50456 91.43050 Methane

Totals : 91.43050

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B0903.D Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 10:16:01 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 21 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 09-Apr-10, 23:55:39 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 1/21/2010 9:48:47 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\025B2101.D)1.1111.138 - Methane1.3662.1484.7975.8346.0666.3787.0447.1697.2937.5357.7807.8347.9087.9758.1908.241

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/21/2010 9:48:15 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.138 PB 25.98668 3.50456 91.07189 Methane

Totals : 91.07189

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B2101.D Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 9:41:45 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 21 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 10-Apr-10, 00:13:17 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 1/21/2010 9:48:47 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\025B2102.D)1.1121.139 - Methane1.2951.3662.1474.7945.8326.0646.3777.0417.1687.2927.5337.8357.9117.9748.1898.2388.5838.962

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/21/2010 9:48:15 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.139 PB 26.26382 3.50455 92.04283 Methane

Totals : 92.04283

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B2102.D Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 9:42:13 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 21 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 10-Apr-10, 00:31:55 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 1/21/2010 9:48:47 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P150\025B2103.D)1.1111.138 - Methane1.2931.3662.1494.7975.8346.0666.3797.0437.1707.2937.5357.7237.7847.8367.9107.9758.1918.241

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 1/21/2010 9:48:15 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.138 PB 26.10215 3.50456 91.47642 Methane

Totals : 91.47642

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B2103.D Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 9:42:27 AM Page 1 of 1===================================================================== Acq. Operator : cjt Seq. Line : 2 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 13-Apr-10, 14:08:10 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P154\029B0201.D)1.1191.145 - Methane1.3732.1524.7966.0656.3766.4977.0407.1677.2917.5327.8327.9087.9738.1898.240

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.145 PB 27.85868 3.50449 97.63044 Methane

Totals : 97.63044

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0201.D Sample Name: Unit1 R1 Spk 0410-59

Betty Reprocess 4/16/2010 11:15:07 AM Page 1 of 1===================================================================== Acq. Operator : cjt Seq. Line : 2 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 13-Apr-10, 14:26:57 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P154\029B0202.D)1.1191.146 - Methane1.3742.1563.3524.7996.0676.3786.5027.0377.1697.2927.5347.7847.8357.9107.9758.1908.240

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.146 PB 27.78938 3.50449 97.38766 Methane

Totals : 97.38766

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0202.D Sample Name: Unit1 R1 Spk 0410-59

Betty Reprocess 4/16/2010 11:15:20 AM Page 1 of 1===================================================================== Acq. Operator : cjt Seq. Line : 2 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 13-Apr-10, 14:45:10 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P154\029B0203.D)1.1161.142 - Methane1.3702.1504.7946.0646.3766.4967.0387.1677.2907.5327.7837.8337.9067.9738.1898.238

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.142 PB 27.72069 3.50449 97.14702 Methane

Totals : 97.14702

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0203.D Sample Name: Unit1 R1 Spk 0410-59

Betty Reprocess 4/16/2010 11:15:32 AM Page 1 of 1===================================================================== Acq. Operator : cjt Seq. Line : 4 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 13-Apr-10, 15:59:25 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P154\029B0401.D)1.1151.141 - Methane1.3692.1514.7956.0646.3766.4977.0377.1687.2917.5317.7837.8337.9077.9738.1888.239

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.141 PB 27.66737 3.50450 96.96020 Methane

Totals : 96.96020

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0401.D Sample Name: gc110p104 #C5

Betty Reprocess 4/16/2010 11:16:06 AM Page 1 of 1===================================================================== Acq. Operator : cjt Seq. Line : 4 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 13-Apr-10, 16:18:16 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P154\029B0402.D)1.1161.143 - Methane1.3702.1514.7956.0656.3776.5007.0387.1687.2927.5337.7827.8337.9087.9748.1908.241

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.143 PB 27.81940 3.50449 97.49282 Methane

Totals : 97.49282

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0402.D Sample Name: gc110p104 #C5

Betty Reprocess 4/16/2010 11:16:18 AM Page 1 of 1===================================================================== Acq. Operator : cjt Seq. Line : 4 Acq. Instrument : Betty online Location : Vial 29 Injection Date : 13-Apr-10, 16:36:50 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Last changed : 3/29/2010 9:45:19 AM by stg/tbo Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P154\029B0403.D)1.1141.140 - Methane1.3692.1514.7976.0656.3786.5016.5947.0387.1687.2927.5347.7837.8347.9748.1908.240

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.140 PB 27.71966 3.50449 97.14339 Methane

Totals : 97.14339

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0403.D Sample Name: gc110p104 #C5

Betty Reprocess 4/16/2010 11:16:30 AM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 15 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 16-Apr-10, 09:24:32 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P157\025B1501.D)1.1171.144 - Methane1.3722.1533.7354.7986.0676.3796.6007.0367.1697.2937.5347.7207.7877.8357.9097.9758.1918.241

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.144 PB 27.51565 3.50450 96.42864 Methane

Totals : 96.42864

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\025B1501.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:35:12 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 15 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 16-Apr-10, 09:43:52 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P157\025B1502.D)1.1181.144 - Methane1.3722.1544.7996.0686.3797.0387.1707.2947.5357.7227.7837.8367.9117.9768.1918.241

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.144 PB 27.38393 3.50451 95.96718 Methane

Totals : 95.96718

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\025B1502.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:35:26 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 15 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 16-Apr-10, 10:02:51 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P157\025B1503.D)1.1171.144 - Methane1.3722.1554.8016.0686.3806.6047.0397.1717.2947.5357.7217.7857.8367.9087.9768.1928.2428.388

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.144 PB 27.50084 3.50450 96.37677 Methane

Totals : 96.37677

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\025B1503.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:35:40 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 1 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 16-Apr-10, 17:28:33 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P158\025B0101.D)1.1251.152 - Methane1.3802.1624.8026.0696.3807.0407.1707.2947.5357.7217.7857.8367.9117.9768.1938.2438.392

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.152 PB 26.85933 3.50453 94.12921 Methane

Totals : 94.12921

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P158\025B0101.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:36:04 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 1 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 16-Apr-10, 17:47:57 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P158\025B0102.D)1.1221.148 - Methane1.3772.1604.8046.0706.3817.0447.1717.2957.5367.7237.8367.9127.9778.1948.2448.394

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.148 PB 27.04746 3.50452 94.78834 Methane

Totals : 94.78834

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P158\025B0102.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:36:17 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 1 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 16-Apr-10, 18:07:13 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P158\025B0103.D)1.1221.149 - Methane1.3782.1614.8036.0706.3817.0427.1717.2957.5367.7237.7867.8377.9127.9778.1938.2428.391

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.149 PB 27.06506 3.50452 94.85001 Methane

Totals : 94.85001

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P158\025B0103.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:36:29 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 8 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 20-Apr-10, 02:21:44 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P160\025B0801.D)1.1101.137 - Methane1.3652.1454.7926.0646.3777.0417.1687.2927.5337.7197.8347.9087.9748.1908.2418.388

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.137 PB 27.38877 3.50451 95.98412 Methane

Totals : 95.98412

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P160\025B0801.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:40:50 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 8 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 20-Apr-10, 02:41:36 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P160\025B0802.D)1.1091.136 - Methane1.3642.1444.7926.0646.3767.0397.1687.2927.5337.7207.7827.8347.9077.9748.1908.238

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.136 PB 27.59999 3.50450 96.72412 Methane

Totals : 96.72412

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P160\025B0802.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:41:04 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 8 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 20-Apr-10, 03:01:26 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P160\025B0803.D)1.1111.137 - Methane1.3652.1464.7936.0656.3767.0427.1687.2917.5337.7207.7847.8347.9057.9748.1908.240

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.137 PB 27.80467 3.50449 97.44124 Methane

Totals : 97.44124

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P160\025B0803.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:00 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 20-Apr-10, 16:59:13 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P161\025B0901.D)1.1161.142 - Methane1.3702.1493.6924.7936.0636.3757.0387.1677.2907.5327.7197.7837.8337.9077.9738.1898.2398.390

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.142 PB 27.25276 3.50451 95.50762 Methane

Totals : 95.50762

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P161\025B0901.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:23 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 20-Apr-10, 17:18:08 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P161\025B0902.D)1.1131.139 - Methane1.2781.3672.1464.1294.7916.0636.3757.0367.1677.2917.5327.7197.7817.8337.9087.9748.1908.2408.390

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.139 PB 27.20691 3.50451 95.34699 Methane

Totals : 95.34699

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P161\025B0902.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:36 PM Page 1 of 1===================================================================== Acq. Operator : kam Seq. Line : 9 Acq. Instrument : Betty online Location : Vial 25 Injection Date : 20-Apr-10, 17:37:10 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M Last changed : 4/16/2010 10:16:59 AM

min 0 2 4 6 8 10 pA

0 10 20 30 40 50 60 70 80 FID2 B, (GC110P161\025B0903.D)1.1161.142 - Methane1.3702.1513.7174.7966.0646.3776.5997.0357.1687.2927.5347.7207.8347.9107.9748.1908.2418.389

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/16/2010 10:16:51 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [%] -------|------|----------|----------|----------|--|------------------ 1.142 PB 27.41913 3.50451 96.09048 Methane

Totals : 96.09048

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

===================================================================== *** End of Report *** Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P161\025B0903.D Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:47 PM Page 1 of 1===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : 4/27/2010 9:23:44 AM

Rel. Reference Window : 0.000 % Abs. Reference Window : 0.100 min Rel. Non-ref. Window : 0.000 % Abs. Non-ref. Window : 0.050 min Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Quadratic (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: FID1 A, Signal 2: FID2 B,

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ppm] -------|--|--|----------|----------|----------|---|--|--------------- 1.416 2 21 1.99600 4.59440e-1 4.34442 Methane 22 4.99000 1.16257 4.29222 23 9.98000 2.34951 4.24770 24 39.92000 9.75827 4.09089 25 99.80000 24.78041 4.02737 26 200.40000 51.53413 3.88869 27 1002.00000 258.23882 3.88013 28 4008.00000 1050.82975 3.81413 29 1.00200e4 2649.91488 3.78125

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Zeppo online 4/29/2010 10:39:57 AM kam Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ppm] 0 5000 10000 Area

0 500 1000 1500 2000 2500

21 2 3 4 25 26 27 28 29 Methane at exp. RT: 1.416 FID2 B, Correlation: 0.99933 Residual Std. Dev.: 42.86542 Formula: y = mx + b m: 2.53683e-1 b: -5.96580e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 26 : 0.000099 Level 27 : 3.96813e-006 Level 28 : 2.48008e-007 Level 29 : 3.96813e-008

===================================================================== Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Zeppo online 4/29/2010 10:39:57 AM kam Page 2 of 2===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : 4/27/2010 8:45:10 AM

Rel. Reference Window : 0.000 % Abs. Reference Window : 0.100 min Rel. Non-ref. Window : 0.000 % Abs. Non-ref. Window : 0.050 min Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Quadratic (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: FID1 A, Signal 2: FID2 B,

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ppm] -------|--|--|----------|----------|----------|---|--|--------------- 1.416 2 21 1.99600 4.59440e-1 4.34442 Methane 22 4.99000 1.16257 4.29222 23 9.98000 2.34951 4.24770 24 39.92000 9.75827 4.09089 25 99.80000 24.78041 4.02737 26 200.40000 51.53413 3.88869 27 1002.00000 258.23882 3.88013 28 4008.00000 1050.82975 3.81413 29 1.00200e4 2649.91488 3.78125 1.548 2 21 1.99800 8.61155e-1 2.32014 Ethane 22 4.99500 2.22649 2.24344 23 9.99000 4.44665 2.24664 24 39.96000 18.20522 2.19498 25 99.90000 45.39942 2.20047 26 199.80000 93.04124 2.14743 27 999.00000 468.59173 2.13192 28 3996.00000 1906.96370 2.09548 29 9990.00000 4763.75700 2.09708 1.862 2 21 1.99600 1.34641 1.48246 Propane 22 4.99000 3.38922 1.47231 23 9.98000 6.69953 1.48966 24 39.92000 27.36625 1.45873 25 99.80000 68.40306 1.45900 26 200.40000 131.11295 1.52845 27 1002.00000 660.00492 1.51817 28 4008.00000 2688.26644 1.49092 29 1.00200e4 6719.99756 1.49107 Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 1 of 4RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ppm] -------|--|--|----------|----------|----------|---|--|--------------- 2.731 2 21 2.00000 1.80194 1.10992 Butane 22 5.00000 4.48111 1.11579 23 10.00000 8.93176 1.11960 24 40.00000 36.20221 1.10490 25 100.00000 90.34531 1.10686 26 199.80000 177.85641 1.12338 27 999.00000 895.77543 1.11523 28 3996.00000 3646.21436 1.09593 29 9990.00000 9109.86035 1.09661 4.253 2 21 1.97800 2.18589 9.04893e-1 Pentane 22 4.94500 5.53759 8.92988e-1 23 9.89000 10.96673 9.01819e-1 24 39.56000 44.71787 8.84658e-1 25 98.90000 111.39845 8.87804e-1 32 501.00000 538.66221 9.30082e-1 33 901.80000 991.07831 9.09918e-1 34 2004.00000 2319.63127 8.63930e-1 5.842 2 21 2.06000 2.68594 7.66957e-1 Hexane 22 5.15000 6.66708 7.72452e-1 23 10.30000 13.15435 7.83011e-1 24 41.20000 53.59436 7.68738e-1 25 103.00000 133.59519 7.70986e-1 32 249.50000 319.81046 7.80150e-1 33 449.10000 587.99013 7.63788e-1 34 998.00000 1375.34237 7.25638e-1 7.003 2 21 1.94000 2.68402 7.22797e-1 Heptane 22 4.85000 6.87506 7.05449e-1 23 9.70000 13.64087 7.11098e-1 24 38.80000 56.91320 6.81740e-1 25 97.00000 141.64313 6.84820e-1 32 125.10000 187.12543 6.68536e-1 33 225.18000 343.90698 6.54770e-1 34 500.40000 805.27352 6.21404e-1

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

=====================================================================

===================================================================== Calibration Curves

=====================================================================

Amount[ppm] 0 5000 10000 Area

0 500 1000 1500 2000 2500

21 2 3 4 25 26 27 28 29 Methane at exp. RT: 1.416 FID2 B, Correlation: 0.99933 Residual Std. Dev.: 42.86542 Formula: y = mx + b m: 2.53683e-1 b: -5.96580e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 26 : 0.000099 Level 27 : 3.96813e-006 Level 28 : 2.48008e-007 Level 29 : 3.96813e-008 Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 2 of 4Amount[ppm] 0 5000 10000 Area

0 1000 2000 3000 4000

21 2 3 4 25 26 27 28 29 Ethane at exp. RT: 1.548 FID2 B, Correlation: 0.99978 Residual Std. Dev.: 48.16411 Formula: y = mx + b m: 4.65076e-1 b: -7.71591e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 26 : 0.0001 Level 27 : 4e-006 Level 28 : 2.5e-007 Level 29 : 4e-008

Amount[ppm] 0 5000 10000 Area

0 1000 2000 3000 4000 5000 6000

21 2 3 4 25 26 27 28 29 Propane at exp. RT: 1.862 FID2 B, Correlation: 0.99985 Residual Std. Dev.: 5.18186 Formula: y = mx + b m: 6.71077e-1 b: 1.25882e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 26 : 0.000099 Level 27 : 3.96813e-006 Level 28 : 2.48008e-007 Level 29 : 3.96813e-008

Amount[ppm] 0 5000 10000 Area

0 1000 2000 3000 4000 5000 6000 7000 8000

21 2 3 4 25 26 27 28 29 Butane at exp. RT: 2.731 FID2 B, Correlation: 0.99996 Residual Std. Dev.: 41.16267 Formula: y = mx + b m: 9.01871e-1 b: -8.03223e-3
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 26 : 0.0001 Level 27 : 4.00801e-006 Level 28 : 2.50501e-007 Level 29 : 4.00801e-008 Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 3 of 4Amount[ppm] 0 1000 2000 Area

0 250 500 750 1000 1250 1500 1750 2000

21 2 3 24 25 32 33 34 Pentane at exp. RT: 4.253 FID2 B, Correlation: 0.99971 Residual Std. Dev.: 34.56928 Formula: y = mx + b m: 1.11745 b: -2.04734e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 32 : 0.000016 Level 33 : 4.81096e-006 Level 34 : 9.7422e-007

Amount[ppm] 0 500 1000 Area

0 200 400 600 800 1000 1200

21 2 23 24 25 32 33 34 Hexane at exp. RT: 5.842 FID2 B, Correlation: 0.99965 Residual Std. Dev.: 28.59674 Formula: y = mx + b m: 1.30826 b: -2.87214e-2
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 32 : 0.000068 Level 33 : 0.000021 Level 34 : 4.26063e-006

Amount[ppm] 0 200 400 Area

0 100 200 300 400 500 600 700

21 22 23

24 25 32 33 34 Heptane at exp. RT: 7.003 FID2 B, Correlation: 0.99919 Residual Std. Dev.: 22.38684 Formula: y = mx + b m: 1.50120 b: -2.77507e-1
x: Amount y: Area Calibration Level Weights: Level 21 : 1 Level 22 : 0.16 Level 23 : 0.04 Level 24 : 0.0025 Level 25 : 0.0004 Level 32 : 0.00024 Level 33 : 0.000074 Level 34 : 0.000015

===================================================================== Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 4 of 4===================================================================== Acq. Operator : Seq. Line : 5 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 01:40:29 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 FID2 B, (GC114P103\030B0501.D)1.416 - Methane1.549 - Ethane1.863 - Propane2.730 - Butane4.254 - Pentane5.843 - Hexane7.004 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PB 4.66863e-1 4.44565 2.07551 Methane 1.549 BB 8.87043e-1 2.33722 2.07321 Ethane 1.863 BP 1.34239 1.47627 1.98172 Propane 2.730 BB 1.85906 1.11360 2.07024 Butane 4.254 BB 2.17213 9.03261e-1 1.96200 Pentane 5.843 BB 2.61647 7.72607e-1 2.02150 Hexane 7.004 BB 2.65465 7.35768e-1 1.95321 Heptane

Totals : 14.13740

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0501.D Sample Name: gc114p102 #C1 ENV(1=980,2=20)

Gummo online 4/27/2010 8:57:53 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 5 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 01:58:53 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 FID2 B, (GC114P103\030B0502.D)

A

r ea

: 0.

4 5 09

7 2

A

r ea

: 1.

3 1 74

51.416 - Methane1.549 - Ethane1.863 - Propane2.733 - Butane4.256 - Pentane5.843 - Hexane7.004 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 MM 4.50972e-1 4.46340 2.01287 Methane 1.549 BP 8.28461e-1 2.34490 1.94266 Ethane 1.863 MM 1.31745 1.47627 1.94490 Propane 2.733 BB 1.76890 1.11377 1.97013 Butane 4.256 BB 2.22362 9.03134e-1 2.00823 Pentane 5.843 BV 2.74363 7.72375e-1 2.11911 Hexane 7.004 BB 2.72386 7.33999e-1 1.99931 Heptane

Totals : 13.99722

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0502.D Sample Name: gc114p102 #C1 ENV(1=980,2=20)

Gummo online 4/27/2010 8:57:56 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 5 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 02:17:18 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 FID2 B, (GC114P103\030B0503.D)1.416 - Methane1.548 - Ethane1.862 - Propane2.730 - Butane4.253 - Pentane5.842 - Hexane7.003 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PB 4.60485e-1 4.45262 2.05037 Methane 1.548 BB 8.67962e-1 2.34133 2.03219 Ethane 1.862 BB 1.37939 1.47654 2.03673 Propane 2.730 BB 1.77785 1.11377 1.98011 Butane 4.253 BB 2.16193 9.03261e-1 1.95279 Pentane 5.842 BB 2.69772 7.72511e-1 2.08402 Hexane 7.003 BB 2.67354 7.35276e-1 1.96579 Heptane

Totals : 14.10199

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0503.D Sample Name: gc114p102 #C1 ENV(1=980,2=20)

Gummo online 4/27/2010 8:57:59 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 4 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 00:45:05 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 FID2 B, (GC114P103\030B0401.D)

A

r ea

: 1.

1 8 69

91.417 - Methane1.550 - Ethane1.864 - Propane2.733 - Butane4.255 - Pentane5.844 - Hexane7.005 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 MM 1.18699 4.14005 4.91420 Methane 1.550 BB 2.28231 2.22288 5.07330 Ethane 1.864 BB 3.41579 1.48465 5.07125 Propane 2.733 BB 4.49303 1.11079 4.99080 Butane 4.255 BB 5.57625 8.98180e-1 5.00848 Pentane 5.844 BB 6.70458 7.67648e-1 5.14676 Hexane 7.005 BB 6.84763 6.93129e-1 4.74629 Heptane

Totals : 34.95107

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0401.D Sample Name: gc114p102 #C2 ENV(1=950,2=50)

Gummo online 4/27/2010 8:57:43 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 4 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 01:03:35 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 FID2 B, (GC114P103\030B0402.D)1.416 - Methane1.549 - Ethane1.863 - Propane2.732 - Butane4.253 - Pentane5.843 - Hexane7.004 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PB 1.14850 4.14669 4.76247 Methane 1.549 BB 2.17730 2.22638 4.84750 Ethane 1.863 BP 3.37285 1.48458 5.00727 Propane 2.732 BB 4.47439 1.11080 4.97014 Butane 4.253 BB 5.51015 8.98220e-1 4.94933 Pentane 5.843 BV 6.70256 7.67649e-1 5.14522 Hexane 7.004 BB 6.85960 6.93082e-1 4.75426 Heptane

Totals : 34.43618

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0402.D Sample Name: gc114p102 #C2 ENV(1=950,2=50)

Gummo online 4/27/2010 8:57:46 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 4 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 01:22:02 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 FID2 B, (GC114P103\030B0403.D)1.416 - Methane1.549 - Ethane1.863 - Propane2.732 - Butane4.254 - Pentane5.843 - Hexane7.004 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PB 1.15222 4.14603 4.77714 Methane 1.549 BB 2.21987 2.22492 4.93905 Ethane 1.863 BP 3.37902 1.48459 5.01646 Propane 2.732 BB 4.47591 1.11080 4.97182 Butane 4.254 BB 5.52637 8.98210e-1 4.96384 Pentane 5.843 BB 6.59411 7.67703e-1 5.06232 Hexane 7.004 BB 6.91794 6.92855e-1 4.79313 Heptane

Totals : 34.52376

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0403.D Sample Name: gc114p102 #C2 ENV(1=950,2=50)

Gummo online 4/27/2010 8:57:49 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 3 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 23:47:43 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:49:13 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 11 12 FID2 B, (GC114P103\030B0301.D)1.3901.417 - Methane1.549 - Ethane1.864 - Propane2.733 - Butane4.255 - Pentane5.844 - Hexane7.005 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PB 2.35631 4.04173 9.52356 Methane 1.549 PB 4.48523 2.18718 9.80999 Ethane 1.864 BB 6.66628 1.48733 9.91494 Propane 2.733 BB 8.90265 1.10981 9.88021 Butane 4.255 BB 10.93730 8.96570e-1 9.80606 Pentane 5.844 BB 13.12355 7.66046e-1 10.05324 Hexane 7.005 BB 13.80329 6.79525e-1 9.37969 Heptane

Totals : 68.36770

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0301.D Sample Name: gc114p102 #C3 ENV(1=900,2=100)

Gummo online 4/27/2010 8:57:34 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 3 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 00:08:00 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 11 12 FID2 B, (GC114P103\030B0302.D)1.3901.416 - Methane1.549 - Ethane1.863 - Propane2.732 - Butane4.253 - Pentane5.843 - Hexane7.004 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PB 2.31135 4.04367 9.34634 Methane 1.549 BB 4.41684 2.18775 9.66293 Ethane 1.863 BP 6.74525 1.48736 10.03262 Propane 2.732 BB 8.92647 1.10980 9.90663 Butane 4.253 BB 10.94999 8.96568e-1 9.81741 Pentane 5.843 BB 13.15136 7.66043e-1 10.07450 Hexane 7.004 BB 13.31667 6.80015e-1 9.05553 Heptane

Totals : 67.89596

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0302.D Sample Name: gc114p102 #C3 ENV(1=900,2=100)

Gummo online 4/27/2010 8:57:37 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 3 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 00:26:33 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 6 7 8 9 10 11 12 FID2 B, (GC114P103\030B0303.D)1.3911.417 - Methane1.550 - Ethane1.864 - Propane2.734 - Butane4.255 - Pentane5.844 - Hexane7.005 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PB 2.38087 4.04070 9.62037 Methane 1.550 BB 4.43787 2.18757 9.70816 Ethane 1.864 PP 6.68704 1.48734 9.94588 Propane 2.734 BB 8.96616 1.10980 9.95064 Butane 4.255 BB 11.01288 8.96558e-1 9.87369 Pentane 5.844 BB 13.18814 7.66038e-1 10.10262 Hexane 7.005 BB 13.80264 6.79526e-1 9.37925 Heptane

Totals : 68.58061

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0303.D Sample Name: gc114p102 #C3 ENV(1=900,2=100)

Gummo online 4/27/2010 8:57:40 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 2 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 22:51:44 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:49:13 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 10 15 20 25 30 FID2 B, (GC114P103\030B0201.D)1.3901.416 - Methane1.549 - Ethane1.864 - Propane2.733 - Butane4.255 - Pentane5.844 - Hexane7.005 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 9.84903 3.96581 39.05936 Methane 1.549 VB 18.29117 2.15926 39.49534 Ethane 1.864 PB 27.46699 1.48946 40.91093 Propane 2.733 BB 36.29591 1.10905 40.25403 Butane 4.255 BB 44.79753 8.95304e-1 40.10739 Pentane 5.844 BB 53.67492 7.64782e-1 41.04963 Hexane 7.005 BB 56.89149 6.69382e-1 38.08217 Heptane

Totals : 278.95885

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0201.D Sample Name: gc114p102 #C4 ENV(1=600,2=400)

Gummo online 4/27/2010 8:57:26 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 2 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 23:10:26 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:49:13 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 10 15 20 25 30 FID2 B, (GC114P103\030B0202.D)1.417 - Methane1.550 - Ethane1.864 - Propane2.733 - Butane4.255 - Pentane5.844 - Hexane7.004 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 VV 9.65206 3.96629 38.28292 Methane 1.550 VB 18.12866 2.15934 39.14591 Ethane 1.864 PP 27.29549 1.48945 40.65538 Propane 2.733 BB 36.22779 1.10905 40.17849 Butane 4.255 BB 44.76125 8.95304e-1 40.07492 Pentane 5.844 BB 53.62891 7.64783e-1 41.01447 Hexane 7.004 BB 57.12166 6.69369e-1 38.23549 Heptane

Totals : 277.58758

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0202.D Sample Name: gc114p102 #C4 ENV(1=600,2=400)

Gummo online 4/27/2010 8:57:29 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 2 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 23:29:05 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:49:13 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

5 10 15 20 25 30 FID2 B, (GC114P103\030B0203.D)1.416 - Methane1.549 - Ethane1.864 - Propane2.733 - Butane4.255 - Pentane5.844 - Hexane7.005 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PB 9.77371 3.96599 38.76244 Methane 1.549 BB 18.19582 2.15930 39.29030 Ethane 1.864 BP 27.33627 1.48946 40.71615 Propane 2.733 BB 36.08293 1.10905 40.01787 Butane 4.255 BB 44.59484 8.95306e-1 39.92601 Pentane 5.844 BB 53.47924 7.64784e-1 40.90007 Hexane 7.005 BB 56.72643 6.69392e-1 37.97222 Heptane

Totals : 277.58504

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0203.D Sample Name: gc114p102 #C4 ENV(1=600,2=400)

Gummo online 4/27/2010 8:57:31 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 1 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 21:31:31 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:24:52 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P103\030B0101.D)1.415 - Methane1.548 - Ethane1.861 - Propane2.3442.729 - Butane3.8234.250 - Pentane5.6205.840 - Hexane7.001 - Heptane7.322

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.415 VV 25.39332 3.95119 100.33385 Methane 1.548 VB 45.75543 2.15381 98.54860 Ethane 1.861 BB 68.94132 1.48987 102.71355 Propane 2.729 BB 90.79992 1.10890 100.68838 Butane 4.250 BB 111.88972 8.95058e-1 100.14784 Pentane 5.840 BB 134.09064 7.64537e-1 102.51727 Hexane 7.001 BB 141.53911 6.67439e-1 94.46875 Heptane

Totals : 699.41824

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0101.D Sample Name: gc114p102 #C5 ENV(1=0,2=450)

Gummo online 4/27/2010 8:57:14 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 1 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 21:55:45 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:49:13 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P103\030B0102.D)1.416 - Methane1.549 - Ethane1.862 - Propane2.3462.730 - Butane3.8264.251 - Pentane5.6225.841 - Hexane7.003 - Heptane7.324

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 BV 24.47537 3.95154 96.71534 Methane 1.549 VB 45.12350 2.15386 97.18985 Ethane 1.862 BB 67.98146 1.48987 101.28322 Propane 2.730 BB 89.94241 1.10890 99.73758 Butane 4.251 BB 110.83764 8.95060e-1 99.20634 Pentane 5.841 BB 132.98512 7.64538e-1 101.67225 Hexane 7.003 BB 141.10301 6.67443e-1 94.17825 Heptane

Totals : 689.98282

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0102.D Sample Name: gc114p102 #C5 ENV(1=0,2=450)

Gummo online 4/27/2010 8:57:18 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 1 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 19-Apr-10, 22:14:21 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 9:49:13 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P103\030B0103.D)1.415 - Methane1.548 - Ethane1.862 - Propane2.3472.731 - Butane3.8194.252 - Pentane5.6245.842 - Hexane7.003 - Heptane7.325

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.415 PV 24.47255 3.95154 96.70423 Methane 1.548 VB 45.31932 2.15385 97.61088 Ethane 1.862 BB 68.28639 1.48987 101.73761 Propane 2.731 BB 90.29361 1.10890 100.12698 Butane 4.252 BB 111.46798 8.95059e-1 99.77043 Pentane 5.842 BB 133.70982 7.64538e-1 102.22619 Hexane 7.003 BB 142.28728 6.67432e-1 94.96713 Heptane

Totals : 693.14345

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0103.D Sample Name: gc114p102 #C5 ENV(1=0,2=450)

Gummo online 4/27/2010 8:57:21 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 15 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 13:26:42 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P103\030B1501.D)1.3901.417 - Methane1.5021.550 - Ethane1.864 - Propane2.3502.734 - Butane2.904

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 51.72902 3.94648 204.14732 Methane 1.550 VB 92.76137 2.15197 199.62013 Ethane 1.864 BB 130.74174 1.49000 194.80490 Propane 2.734 BV 176.81252 1.10886 196.05965 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 794.63200

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1501.D Sample Name: gc114p102 #C6 ENV(1=980,3=21.11)

Gummo online 4/27/2010 8:59:12 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 15 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 13:45:33 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P103\030B1502.D)1.416 - Methane1.5011.549 - Ethane1.863 - Propane2.3482.732 - Butane2.907

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 51.41105 3.94650 202.89389 Methane 1.549 VB 93.14619 2.15197 200.44756 Ethane 1.863 BB 131.27135 1.49000 195.59409 Propane 2.732 BV 178.33121 1.10886 197.74358 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 796.67912

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1502.D Sample Name: gc114p102 #C6 ENV(1=980,3=21.11)

Gummo online 4/27/2010 8:59:15 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 15 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 14:04:36 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P103\030B1503.D)1.3901.417 - Methane1.5021.550 - Ethane1.864 - Propane2.3492.733 - Butane2.905

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 51.46231 3.94650 203.09598 Methane 1.550 VB 93.21617 2.15197 200.59804 Ethane 1.864 BB 131.32574 1.49000 195.67515 Propane 2.733 BV 178.42551 1.10886 197.84814 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 797.21730

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1503.D Sample Name: gc114p102 #C6 ENV(1=980,3=21.11)

Gummo online 4/27/2010 8:59:18 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 14 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 12:30:13 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 50 100 150 200 250 300 FID2 B, (GC114P103\030B1401.D)1.417 - Methane1.5021.550 - Ethane1.864 - Propane2.3502.734 - Butane2.9083.830

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 257.67484 3.94284 1015.97116 Methane 1.550 VB 467.66586 2.15054 1005.73463 Ethane 1.864 BB 658.80994 1.49011 981.70108 Propane 2.734 BV 894.21729 1.10882 991.52221 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 3994.92909

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1401.D Sample Name: gc114p102 #C7 ENV(1=900,3=105.54)

Gummo online 4/27/2010 8:59:03 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 14 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 12:49:04 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 50 100 150 200 250 300 FID2 B, (GC114P103\030B1402.D)1.417 - Methane1.5021.550 - Ethane1.864 - Propane2.3502.733 - Butane2.9053.828

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 258.61874 3.94284 1019.69199 Methane 1.550 VV 469.24182 2.15054 1009.12324 Ethane 1.864 VB 660.79333 1.49011 984.65662 Propane 2.733 BV 896.86700 1.10882 994.46024 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 4007.93208

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1402.D Sample Name: gc114p102 #C7 ENV(1=900,3=105.54)

Gummo online 4/27/2010 8:59:06 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 14 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 13:07:53 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 50 100 150 200 250 300 FID2 B, (GC114P103\030B1403.D)1.416 - Methane1.5021.550 - Ethane1.864 - Propane2.3492.733 - Butane2.9063.827

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 258.42288 3.94284 1018.91991 Methane 1.550 VB 468.86749 2.15054 1008.31836 Ethane 1.864 PB 660.41150 1.49011 984.08763 Propane 2.733 BV 896.24200 1.10882 993.76724 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 4005.09314

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1403.D Sample Name: gc114p102 #C7 ENV(1=900,3=105.54)

Gummo online 4/27/2010 8:59:09 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 13 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 11:33:27 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 200 400 600 800 1000 1200 FID2 B, (GC114P103\030B1301.D)1.416 - Methane1.5021.549 - Ethane1.863 - Propane2.3492.732 - Butane2.9063.827

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 1053.24146 3.94215 4152.03857 Methane 1.549 VV 1910.97864 2.15027 4109.12597 Ethane 1.863 VB 2694.15405 1.49013 4014.65122 Propane 2.732 BV 3655.23804 1.10881 4052.95803 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 1.63288e4

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1301.D Sample Name: gc114p102 #C8 ENV(1=600,3=422.16)

Gummo online 4/27/2010 8:58:54 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 13 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 11:52:19 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 200 400 600 800 1000 1200 FID2 B, (GC114P103\030B1302.D)1.417 - Methane1.5021.550 - Ethane1.864 - Propane2.3502.733 - Butane2.9073.828

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 1052.45667 3.94215 4148.94499 Methane 1.550 VV 1909.96826 2.15027 4106.95348 Ethane 1.864 VB 2693.09570 1.49013 4013.07413 Propane 2.733 BV 3650.95190 1.10881 4048.20554 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 1.63172e4

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1302.D Sample Name: gc114p102 #C8 ENV(1=600,3=422.16)

Gummo online 4/27/2010 8:58:57 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 13 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 12:11:18 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 200 400 600 800 1000 1200 FID2 B, (GC114P103\030B1303.D)1.417 - Methane1.5021.550 - Ethane1.864 - Propane2.3502.733 - Butane2.9073.827

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 1046.79114 3.94215 4126.61188 Methane 1.550 VV 1899.94421 2.15027 4085.39991 Ethane 1.864 VB 2677.54956 1.49013 3989.90819 Propane 2.733 BV 3632.45313 1.10881 4027.69398 Butane 4.253 - - - Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 1.62296e4

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1303.D Sample Name: gc114p102 #C8 ENV(1=600,3=422.16)

Gummo online 4/27/2010 8:59:00 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 12 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 10:17:48 Inj : 1 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 500 1000 1500 2000 2500 3000 FID2 B, (GC114P103\030B1201.D)1.416 - Methane1.5011.548 - Ethane1.861 - Propane2.3482.729 - Butane2.9053.8254.253 - Pentane5.4125.845 - Hexane7.005 - Heptane

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 2666.64136 3.94202 1.05119e4 Methane 1.548 VV 4736.15137 2.15022 1.01838e4 Ethane 1.861 VV 6682.08643 1.49014 9957.23360 Propane 2.729 VV 9055.44922 1.10881 1.00407e4 Butane 4.253 BB 6.79823e-1 9.03261e-1 6.14058e-1 Pentane 5.845 BV 3.51739e-1 7.72607e-1 2.71756e-1 Hexane 7.005 BB 6.07927e-1 7.36292e-1 4.47612e-1 Heptane

Totals : 4.06950e4

===================================================================== Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1201.D Sample Name: gc114p102 #C9 ENV(1=0,3=474)

Gummo online 4/27/2010 8:58:44 AM stg Page 1 of 1===================================================================== Acq. Operator : Seq. Line : 12 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 10:36:44 Inj : 2 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 500 1000 1500 2000 2500 3000 FID2 B, (GC114P103\030B1202.D)1.416 - Methane1.5021.549 - Ethane1.862 - Propane2.3492.731 - Butane2.9063.8274.256 - Pentane5.403

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 2645.77344 3.94202 1.04297e4 Methane 1.549 VV 4775.39893 2.15022 1.02682e4 Ethane 1.862 VV 6736.43750 1.49014 1.00382e4 Propane 2.731 BV 9133.31836 1.10881 1.01271e4 Butane 4.256 BB 5.07836e-1 9.03261e-1 4.58709e-1 Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 4.08636e4

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1202.D Sample Name: gc114p102 #C9 ENV(1=0,3=474)

Gummo online 4/27/2010 8:58:47 AM stg Page 1 of 2===================================================================== Acq. Operator : Seq. Line : 12 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 20-Apr-10, 10:55:39 Inj : 3 Inj Volume : External Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/19/2010 11:59:29 PM Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M Last changed : 4/27/2010 8:54:51 AM by stg

min 2 4 6 8 10 Norm.

0 500 1000 1500 2000 2500 3000 FID2 B, (GC114P103\030B1203.D)1.416 - Methane1.5011.548 - Ethane1.862 - Propane2.3492.730 - Butane2.9063.8264.258 - Pentane5.414

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 8:45:10 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 BV 2637.32983 3.94202 1.03964e4 Methane 1.548 VV 4779.72070 2.15022 1.02775e4 Ethane 1.862 VV 6741.46875 1.49014 1.00457e4 Propane 2.730 VV 9140.81348 1.10881 1.01354e4 Butane 4.258 BB 4.76975e-1 9.03261e-1 4.30833e-1 Pentane 5.842 - - - Hexane 7.003 - - - Heptane

Totals : 4.08554e4

1 Warnings or Errors : Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1203.D Sample Name: gc114p102 #C9 ENV(1=0,3=474)

Gummo online 4/27/2010 8:58:50 AM stg Page 1 of 2===================================================================== Acq. Operator : stg Seq. Line : 1 Acq. Instrument : Gummo online Location : Vial 28 Injection Date : 24-Apr-10, 08:13:49 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 80 FID2 B, (G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0101.D)1.3911.418 - Methane1.5501.8642.3442.7303.8214.2505.6235.8407.0017.323

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.418 PV 25.57154 3.95113 101.03637 Methane

Totals : 101.03637

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0101.D Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Harpo 4/29/2010 11:13:29 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 1 Acq. Instrument : Gummo online Location : Vial 28 Injection Date : 24-Apr-10, 08:32:24 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 80 FID2 B, (G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0102.D)1.416 - Methane1.5491.8632.3452.7313.8254.2525.6205.8427.0037.3238.952

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 25.26629 3.95124 99.83310 Methane

Totals : 99.83310

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0102.D Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Harpo 4/29/2010 11:13:41 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 1 Acq. Instrument : Gummo online Location : Vial 28 Injection Date : 24-Apr-10, 08:51:07 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 80 FID2 B, (G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0103.D)1.3901.417 - Methane1.5501.8642.3442.7323.8214.2535.6265.8437.0047.325

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.417 PV 24.75986 3.95143 97.83678 Methane

Totals : 97.83678

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0103.D Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Harpo 4/29/2010 11:13:53 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 30 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 26-Apr-10, 10:46:13 Inj : 1 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P106\030B3001.D)1.3911.418 - Methane1.5511.8642.3462.7323.8194.2525.6235.8427.0037.326

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.418 PV 23.35993 3.95200 92.31835 Methane

Totals : 92.31835

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\030B3001.D Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Gummo online 4/27/2010 9:29:12 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 30 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 26-Apr-10, 11:04:56 Inj : 2 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P106\030B3002.D)1.3901.416 - Methane1.5491.8632.3472.7323.8274.2545.6285.8457.0057.327

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 23.04785 3.95213 91.08818 Methane

Totals : 91.08818

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\030B3002.D Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Gummo online 4/27/2010 9:29:20 AM stg Page 1 of 1===================================================================== Acq. Operator : stg Seq. Line : 30 Acq. Instrument : Gummo online Location : Vial 30 Injection Date : 26-Apr-10, 11:23:49 Inj : 3 Inj Volume : External Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Last changed : 4/24/2010 8:07:26 AM by stg Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M Last changed : 4/27/2010 9:23:53 AM by stg

min 2 4 6 8 10 Norm.

10 20 30 40 50 60 70 FID2 B, (GC114P106\030B3003.D)1.3901.416 - Methane1.5491.8642.3512.7333.8284.2555.6295.8457.006

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/27/2010 9:23:44 AM Multiplier: : 1.0000 Dilution: : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B,

RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 1.416 PV 22.67966 3.95230 89.63679 Methane

Totals : 89.63679

===================================================================== *** End of Report *** Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\030B3003.D Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Gummo online 4/27/2010 9:29:28 AM stg Page 1 of 1Injection Source and Location

Injection Source: 6890 GC Valve

Injection Location: Dual

============================================================================= 6890 GC METHOD

=============================================================================

OVEN Initial temp: 35 'C (On) Maximum temp: 250 'C Initial time: 2.20 min Equilibration time: 0.20 min Ramps: # Rate Final temp Final time 1 15.00 70 0.07 2 30.00 250 1.00 3 0.0(Off) Post temp: 50 'C Post time: 0.00 min Run time: 11.60 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS) Mode: Split Mode: Split Initial temp: 160 'C (On) Initial temp: 160 'C (On) Pressure: 4.99 psi (On) Pressure: 5.14 psi (On) Split ratio: 5:1 Split ratio: 5:1 Split flow: 10.6 mL/min Split flow: 10.4 mL/min Total flow: 18.9 mL/min Total flow: 18.7 mL/min Gas saver: Off Gas saver: Off Gas type: Hydrogen Gas type: Hydrogen

COLUMN 1 COLUMN 2 Capillary Column Capillary Column Model Number: Restek 10970 Model Number: Restek 10198 Rtx-624 30m x 0.32mm x 1.8um SN 92682 Rtx-1 30m x 0.32mm x 4.0um Max temperature: 240 'C Max temperature: 280 'C Nominal length: 30.0 m Nominal length: 30.0 m Nominal diameter: 320.00 um Nominal diameter: 320.00 um Nominal film thickness: 1.80 um Nominal film thickness: 4.00 um Mode: constant flow Mode: constant flow Initial flow: 2.1 mL/min Initial flow: 2.1 mL/min Nominal init pressure: 5.00 psi Nominal init pressure: 5.14 psi Average velocity: 39 cm/sec Average velocity: 40 cm/sec Inlet: Front Inlet Inlet: Back Inlet Outlet: Front Detector Outlet: Back Detector Outlet pressure: ambient Outlet pressure: ambient

FRONT DETECTOR (FID) BACK DETECTOR (FID) Temperature: 250 'C (On) Temperature: 250 'C (On) Hydrogen flow: 40.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On) Air flow: 450.0 mL/min (On) Air flow: 450.0 mL/min (On) Mode: Constant makeup flow Mode: Constant makeup flow Makeup flow: 45.0 mL/min (On) Makeup flow: 45.0 mL/min (On) Makeup Gas Type: Nitrogen Makeup Gas Type: Nitrogen Flame: On Flame: On Electrometer: On Electrometer: On Lit offset: 2.0 Lit offset: 2.0

SIGNAL 1 SIGNAL 2 method: G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Modified on: 4/27/2010 at 8:44:53 AM

Gummo online 4/27/2010 9:02:37 AM stg Page 1 of 2Data rate: 20 Hz Data rate: 20 Hz Type: front detector Type: back detector Save Data: On Save Data: On Zero: 0.0 (Off) Zero: 0.0 (Off) Range: 0 Range: 0 Fast Peaks: Off Fast Peaks: Off Attenuation: 0 Attenuation: 0

COLUMN COMP 1 COLUMN COMP 2 Derive from front detector Derive from back detector

THERMAL AUX 1 Use: Unspecified Description: Initial temp: 50 'C (Off) Initial time: 0.00 min # Rate Final temp Final time 1 0.0(Off)

VALVES POST RUN Valve 1 Gas Sampling Post Time: 0.00 min Description: Loop Volume: 0.250 mL Load Time: 1.50 min Inject Time: 0.50 min Inlet: Front Inlet Valve 2 Gas Sampling Description: Loop Volume: 0.250 mL Load Time: 1.50 min Inject Time: 0.50 min Inlet: Back Inlet Valve 7 Multiposition 1 Description: BCD input: inverted Switch Time: 1.0 sec

TIME TABLE Time Specifier Parameter & Setpoint method: G:\GC2010Q2\GUMMO\METHODS\GC114P103.M Modified on: 4/27/2010 at 8:44:53 AM

Gummo online 4/27/2010 9:02:37 AM stg Page 2 of 2Sequence: G:\GC2010Q2\Gummo\sequence\GC114P103.TXT Sequence: G:\GC2010Q2\Gummo\sequence\GC114P103.TXT Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 14 gc114p102 #C5 ENV(1=0,2=450) GC114P103 4 Sample 1 Vial 30 gc114p102 #C5 ENV(1=0,2=450) GC114P103 4 Sample 2 Vial 14 gc114p102 #C4 ENV(1=600,2=400) GC114P103 3 Sample 2 Vial 30 gc114p102 #C4 ENV(1=600,2=400) GC114P103 3 Sample 3 Vial 14 gc114p102 #C3 ENV(1=900,2=100) GC114P103 3 Sample 3 Vial 30 gc114p102 #C3 ENV(1=900,2=100) GC114P103 3 Sample 4 Vial 14 gc114p102 #C2 ENV(1=950,2=50) GC114P103 3 Sample 4 Vial 30 gc114p102 #C2 ENV(1=950,2=50) GC114P103 3 Sample 5 Vial 14 gc114p102 #C1 ENV(1=980,2=20) GC114P103 3 Sample 5 Vial 30 gc114p102 #C1 ENV(1=980,2=20) GC114P103 3 Sample 6 Vial 14 gc114p102 #C0 ENV(1=1990,2=10) GC114P103 8 Sample 6 Vial 30 gc114p102 #C0 ENV(1=1990,2=10) GC114P103 8 Sample 7 Vial 14 gc114p102 #C14 ENV(1=0,5=492.93) GC114P103 4 Sample 7 Vial 30 gc114p102 #C14 ENV(1=0,5=492.93) GC114P103 4 Sample 8 Vial 14 gc114p102 #C13 ENV(1=550,5=492.93) GC114P103 3 Sample 8 Vial 30 gc114p102 #C13 ENV(1=550,5=492.93) GC114P103 3 Sample 9 Vial 14 gc114p102 #C12 ENV(1=750,5=273.85) GC114P103 3 Sample 9 Vial 30 gc114p102 #C12 ENV(1=750,5=273.85) GC114P103 3 Sample 10 Vial 14 gc114p102 #C11 ENV(1=0,4=377) GC114P103 4 Sample 10 Vial 30 gc114p102 #C11 ENV(1=0,4=377) GC114P103 4 Sample 11 Vial 14 gc114p102 #C10 ENV(1=500,4=318.69) GC114P103 3 Sample 11 Vial 30 gc114p102 #C10 ENV(1=500,4=318.69) GC114P103 3 Sample 12 Vial 14 gc114p102 #C9 ENV(1=0,3=474) GC114P103 4 Sample 12 Vial 30 gc114p102 #C9 ENV(1=0,3=474) GC114P103 4 Sample 13 Vial 14 gc114p102 #C8 ENV(1=600,3=422.16) GC114P103 3 Sample 13 Vial 30 gc114p102 #C8 ENV(1=600,3=422.16) GC114P103 3 Sample 14 Vial 14 gc114p102 #C7 ENV(1=900,3=105.54) GC114P103 3 Sample 14 Vial 30 gc114p102 #C7 ENV(1=900,3=105.54) GC114P103 3 Sample 15 Vial 14 gc114p102 #C6 ENV(1=980,3=21.11) GC114P103 3 Sample 15 Vial 30 gc114p102 #C6 ENV(1=980,3=21.11) GC114P103 3 SampleSequence: G:\GC2010Q2\Gummo\sequence\GC114P106.TXT Sequence: G:\GC2010Q2\Gummo\sequence\GC114P106.TXT Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 14 gc114p102 #C5 ENV(1=0,2=450) GC114P103 3 Sample 1 Vial 28 gc114p102 #C5 ENV(1=0,5=450) GC114P103 3 Sample 2 Vial 1 N2 Blank PAUSE 1 Sample 2 Vial 17 N2 Blank PAUSE 1 Sample 3 Vial 7 Inlet R1 0410-126 GC114P103 3 Sample 3 Vial 23 gc114p105 #A3 ENV(1=900,5=100) GC114P103 3 Sample 4 Vial 4 Outlet R1 0410-126 GC114P103 3 Sample 4 Vial 20 gc114p105 #H3 ENV(1=900,6=100) GC114P103 3 Sample 5 Vial 3 GC114P103 3 Sample 5 Vial 19 Inlet R2 0410-126 GC114P103 3 Sample 6 Vial 3 GC114P103 3 Sample 6 Vial 19 Inlet R2 0410-126 GC114P103 3 Sample 7 Vial 10 GC114P103 3 Sample 7 Vial 26 Inlet R3 0410-126 GC114P103 3 Sample 8 Vial 2 GC114P103 3 Sample 8 Vial 18 Outlet R2 0410-126 GC114P103 3 Sample 9 Vial 6 GC114P103 3 Sample 9 Vial 22 Outlet R3 0410-126 GC114P103 3 Sample 10 Vial 10 GC114P103 3 Sample 10 Vial 26 Inlet R3 0410-126 GC114P103 3 Sample 11 Vial 2 GC114P103 3 Sample 11 Vial 18 Run 1 0410-124 GC114P103 3 Sample 12 Vial 2 GC114P103 3 Sample 12 Vial 19 Run 2 0410-124 GC114P103 3 Sample 13 Vial 2 GC114P103 3 Sample 13 Vial 20 Run 3 0410-124 GC114P103 3 Sample 14 Vial 1 N2 Blank GC114P103 3 Sample 14 Vial 17 N2 Blank GC114P103 3 Sample 15 Vial 14 gc114p102 #C5 ENV(1=0,2=450) GC114P103 3 Sample 15 Vial 30 gc114p102 #C5 ENV(1=0,5=450) GC114P103 3 Sample 16 Vial 14 gc114p104 #B4 ENV(1=650,2=450) GC114P103 3 Sample 16 Vial 30 gc114p104 #B4 ENV(1=650,2=450) GC114P103 3 Sample

# This Is The Last Page Of This Report.============================================================================= 6890 GC METHOD

=============================================================================

OVEN Initial temp: -10 'C (On) Maximum temp: 330 'C Initial time: 4.00 min Equilibration time: 0.20 min Ramps: # Rate Final temp Final time CRYO (N2) 1 40.00 210 0.50 Cryo: On 2 35.00 260 0.20 Cryo fault: On 3 0.0(Off) Cryo timeout: 20.00 min (On) Post temp: 50 'C Quick cryo cool: On Post time: 0.00 min Ambient temp: 22 'C Run time: 11.63 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS) Mode: Splitless Mode: Split Initial temp: 150 'C (On) Initial temp: 200 'C (On) Pressure: 44.00 psi (On) Pressure: 5.84 psi (On) Purge flow: 0.0 mL/min Split ratio: 7:1 Purge time: 0.00 min Split flow: 22.0 mL/min Total flow: 15.3 mL/min Total flow: 31.7 mL/min Gas saver: Off Gas saver: Off Gas type: Helium Gas type: Hydrogen

COLUMN 1 COLUMN 2 Packed Column Capillary Column Model Number: Restek 19808 Model Number: Restek 10198 Shin Carbon ST 2m x 1mm Rtx-1 30m x 0.32mm x 4.0um SN450928 Max temperature: 330 'C Max temperature: 280 'C Mode: constant pressure Nominal length: 30.0 m Pressure: 44.00 psi Nominal diameter: 320.00 um Inlet: Front Inlet Nominal film thickness: 4.00 um Outlet: Front Detector Mode: constant flow Outlet pressure: ambient Initial flow: 3.1 mL/min Nominal init pressure: 5.84 psi Average velocity: 50 cm/sec Inlet: Back Inlet Outlet: Back Detector Outlet pressure: ambient

FRONT DETECTOR (TCD) BACK DETECTOR (FID) Temperature: 275 'C (On) Temperature: 300 'C (On) Reference flow: 25.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On) Mode: Constant makeup flow Air flow: 450.0 mL/min (On) Makeup flow: 7.0 mL/min (On) Mode: Constant makeup flow Makeup Gas Type: Helium Makeup flow: 45.0 mL/min (On) Filament: On Makeup Gas Type: Nitrogen Negative polarity: On Flame: On Electrometer: On Lit offset: 2.0

SIGNAL 1 SIGNAL 2 Data rate: 20 Hz Data rate: 20 Hz Type: front detector Type: back detector Save Data: On Save Data: On Zero: 0.0 (Off) Zero: 0.0 (Off) Range: 0 Range: 0 Fast Peaks: Off Fast Peaks: Off Attenuation: 0 Attenuation: 0 method: G:\GC2010Q1\BETTY\METHODS\GC110P104.M Modified on: 1/14/2010 at 4:35:53 PM

Betty online 1/14/2010 4:35:57 PM JBB Page 1 of 2COLUMN COMP 1 COLUMN COMP 2 Derive from front detector Derive from back detector

THERMAL AUX 1 Use: Valve Box Heater Description: Initial temp: 150 'C (On) Initial time: 0.00 min # Rate Final temp Final time 1 0.0(Off)

VALVES POST RUN Valve 1 Gas Sampling Post Time: 0.00 min Description: Loop Volume: 0.250 mL Load Time: 4.00 min Inject Time: 0.50 min Inlet: Front Inlet Valve 2 Gas Sampling Description: Loop Volume: 1.000 mL Load Time: 4.00 min Inject Time: 0.50 min Inlet: Front Inlet

TIME TABLE Time Specifier Parameter & Setpoint 1.60 Front Detector Polarity: Off

GC Injector

Front Injector: Injector not configured, use these parameters if it becomes configured Sample Washes 0 Sample Pumps 0 Injection Volume 1.00 microliters Syringe Size 10.0 microliters PostInj Solvent A Washes 0 PostInj Solvent B Washes 0 Viscosity Delay 0 seconds Plunger Speed Fast

Back Injector: Injector not configured, use these parameters if it becomes configured Sample Washes 0 Sample Pumps 0 Injection Volume 1.00 microliters Syringe Size 10.0 microliters PostInj Solvent A Washes 0 PostInj Solvent B Washes 0 Viscosity Delay 0 seconds Plunger Speed Fast method: G:\GC2010Q1\BETTY\METHODS\GC110P104.M Modified on: 1/14/2010 at 4:35:53 PM

Betty online 1/14/2010 4:35:57 PM JBB Page 2 of 2Injection Source and Location

Injection Source: 6890 GC Valve

Injection Location: Dual

============================================================================= 6890 GC METHOD

=============================================================================

OVEN Initial temp: -10 'C (On) Maximum temp: 330 'C Initial time: 4.00 min Equilibration time: 0.20 min Ramps: # Rate Final temp Final time CRYO (N2) 1 40.00 210 0.50 Cryo: On 2 35.00 260 0.20 Cryo fault: On 3 0.0(Off) Cryo timeout: 20.00 min (On) Post temp: 50 'C Quick cryo cool: On Post time: 0.00 min Ambient temp: 22 'C Run time: 11.63 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS) Mode: Splitless Mode: Split Initial temp: 150 'C (On) Initial temp: 200 'C (On) Pressure: 44.00 psi (On) Pressure: 5.83 psi (On) Purge flow: 0.0 mL/min Split ratio: 7:1 Purge time: 0.00 min Split flow: 21.9 mL/min Total flow: 15.3 mL/min Total flow: 31.7 mL/min Gas saver: Off Gas saver: Off Gas type: Helium Gas type: Hydrogen

COLUMN 1 COLUMN 2 Packed Column Capillary Column Model Number: Restek 19808 Model Number: Restek 10198 Shin Carbon ST 2m x 1mm Rtx-1 30m x 0.32mm x 4.0um SN450928 Max temperature: 330 'C Max temperature: 280 'C Mode: constant pressure Nominal length: 30.0 m Pressure: 44.00 psi Nominal diameter: 320.00 um Inlet: Front Inlet Nominal film thickness: 4.00 um Outlet: Front Detector Mode: constant flow Outlet pressure: ambient Initial flow: 3.1 mL/min Nominal init pressure: 5.83 psi Average velocity: 50 cm/sec Inlet: Back Inlet Outlet: Back Detector Outlet pressure: ambient

FRONT DETECTOR (TCD) BACK DETECTOR (FID) Temperature: 275 'C (On) Temperature: 300 'C (On) Reference flow: 25.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On) Mode: Constant makeup flow Air flow: 450.0 mL/min (On) Makeup flow: 7.0 mL/min (On) Mode: Constant makeup flow Makeup Gas Type: Helium Makeup flow: 45.0 mL/min (On) Filament: On Makeup Gas Type: Nitrogen Negative polarity: On Flame: On Electrometer: On Lit offset: 2.0

SIGNAL 1 SIGNAL 2 method: G:\GC2010Q1\BETTY\METHODS\GC110P128FAST.M Modified on: 3/10/2010 at 4:14:00 PM

Betty online 3/11/2010 9:53:15 AM stg Page 1 of 2Data rate: 20 Hz Data rate: 20 Hz Type: front detector Type: back detector Save Data: On Save Data: On Zero: 0.0 (Off) Zero: 0.0 (Off) Range: 0 Range: 0 Fast Peaks: Off Fast Peaks: Off Attenuation: 0 Attenuation: 0

COLUMN COMP 1 COLUMN COMP 2 Derive from front detector Derive from back detector

THERMAL AUX 1 Use: Valve Box Heater Description: Initial temp: 150 'C (On) Initial time: 0.00 min # Rate Final temp Final time 1 0.0(Off)

VALVES POST RUN Valve 1 Gas Sampling Post Time: 0.00 min Description: Loop Volume: 0.250 mL Load Time: 1.50 min Inject Time: 0.50 min Inlet: Front Inlet Valve 2 Gas Sampling Description: Loop Volume: 1.000 mL Load Time: 4.00 min Inject Time: 0.50 min Inlet: Front Inlet

TIME TABLE Time Specifier Parameter & Setpoint 1.60 Front Detector Polarity: Off

GC Injector

Front Injector: Injector not configured, use these parameters if it becomes configured Sample Washes 0 Sample Pumps 0 Injection Volume 1.00 microliters Syringe Size 10.0 microliters PostInj Solvent A Washes 0 PostInj Solvent B Washes 0 Viscosity Delay 0 seconds Plunger Speed Fast

Back Injector: Injector not configured, use these parameters if it becomes configured Sample Washes 0 Sample Pumps 0 Injection Volume 1.00 microliters Syringe Size 10.0 microliters PostInj Solvent A Washes 0 PostInj Solvent B Washes 0 Viscosity Delay 0 seconds Plunger Speed Fast method: G:\GC2010Q1\BETTY\METHODS\GC110P128FAST.M Modified on: 3/10/2010 at 4:14:00 PM

Betty online 3/11/2010 9:53:15 AM stg Page 2 of 2Injection Source and Location

Injection Source: 6890 GC Valve

Injection Location: Dual

============================================================================= 6890 GC METHOD

=============================================================================

OVEN Initial temp: -10 'C (On) Maximum temp: 330 'C Initial time: 4.00 min Equilibration time: 0.20 min Ramps: # Rate Final temp Final time CRYO (N2) 1 40.00 210 0.50 Cryo: On 2 35.00 260 0.20 Cryo fault: On 3 0.0(Off) Cryo timeout: 20.00 min (On) Post temp: 50 'C Quick cryo cool: On Post time: 0.00 min Ambient temp: 22 'C Run time: 11.63 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS) Mode: Splitless Mode: Split Initial temp: 150 'C (On) Initial temp: 200 'C (On) Pressure: 44.00 psi (On) Pressure: 5.83 psi (On) Purge flow: 0.0 mL/min Split ratio: 7:1 Purge time: 0.00 min Split flow: 21.9 mL/min Total flow: 15.3 mL/min Total flow: 31.7 mL/min Gas saver: Off Gas saver: Off Gas type: Helium Gas type: Hydrogen

COLUMN 1 COLUMN 2 Packed Column Capillary Column Model Number: Restek 19808 Model Number: Restek 10198 Shin Carbon ST 2m x 1mm Rtx-1 30m x 0.32mm x 4.0um SN450928 Max temperature: 330 'C Max temperature: 280 'C Mode: constant pressure Nominal length: 30.0 m Pressure: 44.00 psi Nominal diameter: 320.00 um Inlet: Front Inlet Nominal film thickness: 4.00 um Outlet: Front Detector Mode: constant flow Outlet pressure: ambient Initial flow: 3.1 mL/min Nominal init pressure: 5.83 psi Average velocity: 50 cm/sec Inlet: Back Inlet Outlet: Back Detector Outlet pressure: ambient

FRONT DETECTOR (TCD) BACK DETECTOR (FID) Temperature: 275 'C (On) Temperature: 300 'C (On) Reference flow: 25.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On) Mode: Constant makeup flow Air flow: 450.0 mL/min (On) Makeup flow: 7.0 mL/min (On) Mode: Constant makeup flow Makeup Gas Type: Helium Makeup flow: 45.0 mL/min (On) Filament: On Makeup Gas Type: Nitrogen Negative polarity: On Flame: On Electrometer: On Lit offset: 2.0

SIGNAL 1 SIGNAL 2 method: G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/16/2010 9:56:23 AM kam Page 1 of 2Data rate: 20 Hz Data rate: 20 Hz Type: front detector Type: back detector Save Data: On Save Data: On Zero: 0.0 (Off) Zero: 0.0 (Off) Range: 0 Range: 0 Fast Peaks: Off Fast Peaks: Off Attenuation: 0 Attenuation: 0

COLUMN COMP 1 COLUMN COMP 2 Derive from front detector Derive from back detector

THERMAL AUX 1 Use: Valve Box Heater Description: Initial temp: 150 'C (On) Initial time: 0.00 min # Rate Final temp Final time 1 0.0(Off)

VALVES POST RUN Valve 1 Gas Sampling Post Time: 0.00 min Description: Loop Volume: 0.250 mL Load Time: 1.50 min Inject Time: 0.50 min Inlet: Front Inlet Valve 2 Gas Sampling Description: Loop Volume: 1.000 mL Load Time: 4.00 min Inject Time: 0.50 min Inlet: Front Inlet

TIME TABLE Time Specifier Parameter & Setpoint 1.60 Front Detector Polarity: Off

GC Injector

Front Injector: Injector not configured, use these parameters if it becomes configured Sample Washes 0 Sample Pumps 0 Injection Volume 1.00 microliters Syringe Size 10.0 microliters PostInj Solvent A Washes 0 PostInj Solvent B Washes 0 Viscosity Delay 0 seconds Plunger Speed Fast

Back Injector: Injector not configured, use these parameters if it becomes configured Sample Washes 0 Sample Pumps 0 Injection Volume 1.00 microliters Syringe Size 10.0 microliters PostInj Solvent A Washes 0 PostInj Solvent B Washes 0 Viscosity Delay 0 seconds Plunger Speed Fast method: G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/16/2010 9:56:23 AM kam Page 2 of 2Sequence: G:\GC2010Q1\betty\sequence\gc110p104.txt Sequence: G:\GC2010Q1\betty\sequence\gc110p104.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 12 gc110p104 #FG3 ENV(1=0,2=377.39) GC110P104 3 Sample 1 Vial 28 gc110p104 #FG3 ENV(1=0,2=377.39) GC110P104 3 Sample 2 Vial 12 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104 3 Sample 2 Vial 28 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104 3 Sample 3 Vial 12 gc110p104 #FG1 ENV(1=636,2=83.86) GC110P104 3 Sample 3 Vial 28 gc110p104 #FG1 ENV(1=636,2=83.86) GC110P104 3 Sample 4 Vial 12 gc110p104 #FG6 ENV(1=0,3=358.71) GC110P104 3 Sample 4 Vial 28 gc110p104 #FG6 ENV(1=0,3=358.71) GC110P104 3 Sample 5 Vial 12 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104 3 Sample 5 Vial 28 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104 3 Sample 6 Vial 12 gc110p104 #FG4 ENV(1=636,3=79.71) GC110P104 3 Sample 6 Vial 28 gc110p104 #FG4 ENV(1=636,3=79.71) GC110P104 3 Sample 7 Vial 12 gc110p104 #C5 ENV(1=0,4=450) GC110P104 3 Sample 7 Vial 28 gc110p104 #C5 ENV(1=0,4=450) GC110P104 3 Sample X 8 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104 3 Sample 8 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104 3 Sample 9 Vial 12 gc110p104 #C3 ENV(1=636,4=100) GC110P104 3 Sample 9 Vial 28 gc110p104 #C3 ENV(1=636,4=100) GC110P104 3 Sample 10 Vial 12 gc110p104 #C2 ENV(1=692.53,4=20) GC110P104 3 Sample 10 Vial 28 gc110p104 #C2 ENV(1=692.53,4=20) GC110P104 3 Sample 11 Vial 12 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 3 Sample 11 Vial 28 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 3 Sample 12 Vial 12 gc110p104 #C7 ENV(1=0,5=474.93) GC110P104 3 Sample 12 Vial 28 gc110p104 #C7 ENV(1=0,5=474.93) GC110P104 3 Sample 13 Vial 12 gc110p104 #C6 ENV(1=636,5=105.54) GC110P104 3 Sample 13 Vial 28 gc110p104 #C6 ENV(1=636,5=105.54) GC110P104 3 Sample 14 Vial 12 gc110p104 #C9 ENV(1=0,6=526.07) GC110P104 3 Sample 14 Vial 28 gc110p104 #C9 ENV(1=0,6=526.07) GC110P104 3 Sample X 15 Vial 12 gc110p104 #C8 ENV(1=318,6=526.07) GC110P104 3 Sample 15 Vial 28 gc110p104 #C8 ENV(1=318,6=526.07) GC110P104 3 Sample X 16 Vial 12 gc110p104 #FG7 ENV(1=692.53,2=16.77) GC110P104 7 Sample 2,3 16 Vial 28 gc110p104 #FG7 ENV(1=692.53,2=16.77) GC110P104 7 Sample 17 Vial 12 gc110p104 #FG8 ENV(1=692.53,3=15.94) GC110P104 7 Sample 17 Vial 28 gc110p104 #FG8 ENV(1=692.53,3=15.94) GC110P104 7 Sample 18 Vial 3 H2 UHP Matheson AX13607 #9 GC110P104 3 Sample 18 Vial 19 H2 UHP Matheson AX13607 #9 GC110P104 3 Sample 19 Vial 16 gc110p104 #C5 A019379 #9 GC110P104 3 Sample 19 Vial 32 gc110p104 #C5 A019379 #9 GC110P104 3 Sample 20 Vial 6 CO2 99.8+% Adlrich 01629AJ #9 GC110P104 3 Sample 20 Vial 22 CO2 99.8+% Adlrich 01629AJ #9 GC110P104 3 Sample 21 Vial 10 CO 99+% Aldrich 03611BJ #9 GC110P104 3 Sample 21 Vial 26 CO 99+% Aldrich 03611BJ #9 GC110P104 3 Sample 22 Vial 4 CH4 99+% Aldrich MKBB4558 #9 GC110P104 3 Sample 22 Vial 20 CH4 99+% Aldrich MKBB4558 #9 GC110P104 3 Sample 23 Vial 12 gc110p104 #C9 ENV(1=0,6=467.62) GC110P104 3 Sample 23 Vial 28 gc110p104 #C9 ENV(1=0,6=467.62) GC110P104 3 Sample 24 Vial 12 gc110p104 #C8 ENV(1=424.6,6=467.62) GC110P104 3 Sample 24 Vial 28 gc110p104 #C8 ENV(1=424.6,6=467.62) GC110P104 3 Sample 25 Vial 12 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample leak 25 Vial 28 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample 26 Vial 12 H2 40% AX13607 ENV(1=424,5=396) #10 GC110P104 3 Sample 26 Vial 28 H2 40% AX13607 ENV(1=424,5=396) #10 GC110P104 3 Sample 27 Vial 3 House cryo N2 GC110P104 3 Sample leak 27 Vial 19 House cryo N2 GC110P104 3 Sample 28 Vial 12 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 7 Sample 28 Vial 28 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 7 Sample X 29 Vial 12 gc110p106 #A4 ENV(1=0,5=450) GC110P104 3 Sample 29 Vial 28 gc110p106 #A4 ENV(1=0,5=450) GC110P104 3 Sample 30 Vial 12 gc110p106 #A3 ENV(1=494.66,5=300) GC110P104 3 Sample 30 Vial 28 gc110p106 #A3 ENV(1=494.66,5=300) GC110P104 3 Sample 31 Vial 12 gc110p106 #A2 ENV(1=636,5=100) GC110P104 3 Sample 31 Vial 28 gc110p106 #A2 ENV(1=636,5=100) GC110P104 3 Sample 32 Vial 12 gc110p106 #A1 ENV(1=692.53,5=20) GC110P104 3 Sample 32 Vial 28 gc110p106 #A1 ENV(1=692.53,5=20) GC110P104 3 Sample 33 Vial 12 gc110p106 #B5 ENV(1=0,6=450) GC110P104 3 Sample 33 Vial 28 gc110p106 #B5 ENV(1=0,6=450) GC110P104 3 Sample 34 Vial 12 gc110p106 #B4 ENV(1=565.33,6=200) GC110P104 3 Sample 34 Vial 28 gc110p106 #B4 ENV(1=565.33,6=200) GC110P104 3 Sample 35 Vial 12 gc110p106 #B3 ENV(1=671.33,6=50) GC110P104 3 Sample 35 Vial 28 gc110p106 #B3 ENV(1=671.33,6=50) GC110P104 3 Sample 36 Vial 12 gc110p106 #B2 ENV(1=692.53,6=20) GC110P104 3 Sample 36 Vial 28 gc110p106 #B2 ENV(1=692.53,6=20) GC110P104 3 Sample 37 Vial 12 gc110p106 #B1 ENV(1=1406.26,6=10) GC110P104 3 Sample 37 Vial 28 gc110p106 #B1 ENV(1=1406.26,6=10) GC110P104 3 Sample 38 Vial 3 House cryo N2 GC110P104 3 Sample 38 Vial 19 House cryo N2 GC110P104 3 Sample 39 Vial 12 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample 39 Vial 28 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample 40 Vial 12 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 11 Sample 40 Vial 28 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 11 Sample MDL5-11

line 7 inj 3 accidentally overwritten by partial sequence - rerun line 19 lines 14 and 15 bad EI command -- environics did not run -- rerun lines 23 + 24 lines 25 , 28, and 40 contamination due to sample cans on ports 8, 9, 11 line 39 Matheson Oxygen zero grade lot 1059413064 cylinder AX38764 >99.8%Sequence: G:\GC2010Q1\betty\sequence\gc110p106.txt Sequence: G:\GC2010Q1\betty\sequence\gc110p106.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 12 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample 1 Vial 28 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample 2 Vial 12 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample 2 Vial 28 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample 3 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 3 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 4 Vial 8 1209-01 Run 1 can 1374 GC110P104A 3 Sample 4 Vial 24 1209-01 Run 1 can 1374 GC110P104A 3 Sample 5 Vial 9 1209-01 Run 2 can 1093 GC110P104A 3 Sample 5 Vial 25 1209-01 Run 2 can 1093 GC110P104A 3 Sample 6 Vial 11 1209-01 Run 3 can 1372 GC110P104A 3 Sample 6 Vial 27 1209-01 Run 3 can 1372 GC110P104A 3 Sample 7 Vial 3 1109-84 Run 1 can 1362 GC110P104A 3 Sample 7 Vial 19 1109-84 Run 1 can 1362 GC110P104A 3 Sample 8 Vial 10 1109-84 Run 2 can 1370 GC110P104A 3 Sample 8 Vial 26 1109-84 Run 2 can 1370 GC110P104A 3 Sample 9 Vial 7 1109-84 Run 3 can 1012 GC110P104A 3 Sample 9 Vial 23 1109-84 Run 3 can 1012 GC110P104A 3 Sample 10 Vial 12 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample 10 Vial 28 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample 11 Vial 12 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample 11 Vial 28 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample 12 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 12 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 13 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 13 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 14 Vial 1 He Blank GC110P104A 3 Sample 14 Vial 17 He Blank GC110P104A 3 Sample 15 Vial 12 gc110p106 #D4 ENV(1=0,6=450) GC110P104A 3 Sample 15 Vial 28 gc110p106 #D4 ENV(1=0,6=450) GC110P104A 3 Sample 16 Vial 12 gc110p106 #D3 ENV(1=494.66,6=300) GC110P104A 3 Sample 16 Vial 28 gc110p106 #D3 ENV(1=494.66,6=300) GC110P104A 3 Sample 17 Vial 12 gc110p106 #D2 ENV(1=678.4,6=40) GC110P104A 3 Sample 17 Vial 28 gc110p106 #D2 ENV(1=678.4,6=40) GC110P104A 3 Sample 18 Vial 12 gc110p106 #D1 ENV(1=699.6,6=10) GC110P104A 3 Sample 18 Vial 28 gc110p106 #D1 ENV(1=699.6,6=10) GC110P104A 3 Sample 19 Vial 8 gc110p106 #E3 GC110P104A 3 Sample 19 Vial 24 gc110p106 #E3 GC110P104A 3 Sample 20 Vial 9 gc110p106 #E2 GC110P104A 3 Sample 20 Vial 25 gc110p106 #E2 GC110P104A 3 Sample 21 Vial 11 gc110p106 #E1 GC110P104A 3 Sample 21 Vial 27 gc110p106 #E1 GC110P104A 3 Sample 22 Vial 11 gc110p106 #E0 GC110P104A 3 Sample 22 Vial 27 gc110p106 #E0 GC110P104A 3 SampleSequence: G:\GC2010Q1\Betty\sequence\gc110p150.txt Sequence: G:\GC2010Q1\Betty\sequence\gc110p150.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 15 #1172 0410-27 GC110P144FAST 2 Sample 1 Vial 31 #1172 0410-27 GC110P144FAST 2 Sample 2 Vial 16 #1626 0410-27 GC110P144FAST 2 Sample 2 Vial 32 #1626 0410-27 GC110P144FAST 2 Sample 3 Vial 12 #1326 0410-27 GC110P144FAST 2 Sample 3 Vial 28 #1326 0410-27 GC110P144FAST 2 Sample 4 Vial 10 #1628 0410-27 GC110P144FAST 2 Sample 4 Vial 26 #1628 0410-27 GC110P144FAST 2 Sample 5 Vial 8 #1624 0410-27 GC110P144FAST 2 Sample 5 Vial 24 #1624 0410-27 GC110P144FAST 2 Sample 6 Vial 14 gc110p104 #FG6 ENV(1=0,2=358) GC110P144FAST 2 Sample 6 Vial 30 gc110p104 #FG6 ENV(1=0,2=358) GC110P144FAST 2 Sample 7 Vial 9 gc111p104 #C5 GC110P144FAST 3 Sample 7 Vial 25 gc111p104 #C5 GC110P144FAST 3 Sample 8 Vial 2 pause PAUSE 1 Sample 8 Vial 18 pause PAUSE 1 Sample 9 Vial 9 gc111p104 #C5 GC110P144FAST 3 Sample 9 Vial 25 gc111p104 #C5 GC110P144FAST 3 Sample 10 Vial 2 pause PAUSE 1 Sample 10 Vial 18 pause PAUSE 1 Sample 11 Vial 8 R1 Stack 0410-59 GC110P144FAST 3 Sample 11 Vial 24 R1 Stack 0410-59 GC110P144FAST 3 Sample 12 Vial 13 R2 Stack 0410-59 GC110P144FAST 3 Sample 12 Vial 29 R2 Stack 0410-59 GC110P144FAST 3 Sample 13 Vial 10 R3 Stack 0410-59 GC110P144FAST 3 Sample 13 Vial 26 R3 Stack 0410-59 GC110P144FAST 3 Sample 14 Vial 11 W7-M18-1 0410-56 GC110P144FAST 3 Sample 14 Vial 27 W7-M18-1 0410-56 GC110P144FAST 3 Sample 15 Vial 8 W7-M18-2 0410-56 GC110P144FAST 3 Sample 15 Vial 24 W7-M18-2 0410-56 GC110P144FAST 3 Sample 16 Vial 13 W7-M18-3 0410-56 GC110P144FAST 3 Sample 16 Vial 29 W7-M18-3 0410-56 GC110P144FAST 3 Sample 17 Vial 12 R1 Ambient 0410-59 GC110P144FAST 3 Sample 17 Vial 28 R1 Ambient 0410-59 GC110P144FAST 3 Sample 18 Vial 15 R2 Ambient 0410-59 GC110P144FAST 3 Sample 18 Vial 31 R2 Ambient 0410-59 GC110P144FAST 3 Sample 19 Vial 16 R3 Ambient 0410-59 GC110P144FAST 3 Sample 19 Vial 32 R3 Ambient 0410-59 GC110P144FAST 3 Sample 20 Vial 1 He Blank GC110P144FAST 3 Sample 20 Vial 17 He Blank GC110P144FAST 3 Sample 21 Vial 9 gc111p104 #C5 GC110P144FAST 3 Sample 21 Vial 25 gc111p104 #C5 GC110P144FAST 3 Sample 22 Vial 2 pause PAUSE 1 Sample 22 Vial 18 pause PAUSE 1 SampleSequence: G:\GC2010Q2\Betty\sequence\gc110p154.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p154.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 1 He Blank GC110P104FAST 3 Sample 1 Vial 17 He Blank GC110P104FAST 3 Sample 2 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 2 Vial 29 Unit1 R1 Spk 0410-59 GC110P104FAST 3 Sample 3 Vial 13 Unit1 R1 Spk 0410-59 GC110P104FAST 3 Sample 3 Vial 29 Unit1 R1 Spk 0410-59 GC110P144FAST 3 Sample 4 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 4 Vial 29 gc110p104 #C5 GC110P144FAST 3 Sample 5 Vial 2 pause PAUSE 1 Sample 5 Vial 18 pause PAUSE 1 Sample 6 Vial 10 GC110P144FAST 3 Sample 6 Vial 26 GC110P144FAST 3 Sample 7 Vial 10 GC110P144FAST 3 Sample 7 Vial 26 GC110P144FAST 3 Sample 8 Vial 10 GC110P144FAST 3 Sample 8 Vial 26 GC110P144FAST 3 Sample 9 Vial 13 R1 Spk 0410-56 GC110P144FAST 3 Sample 9 Vial 29 R1 Spk 0410-56 GC110P144FAST 3 Sample 10 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 10 Vial 25 gc110p104 #C5 GC110P144FAST 3 SampleSequence: G:\GC2010Q2\Betty\sequence\gc110p157.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p157.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 1 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 2 Vial 2 pause PAUSE 1 Sample 2 Vial 18 pause PAUSE 1 Sample 3 Vial 13 THC R1 0410-80 GC110P144FAST 3 Sample 3 Vial 29 THC R1 0410-80 GC110P144FAST 3 Sample 4 Vial 8 THC R2 0410-80 GC110P144FAST 3 Sample 4 Vial 24 THC R2 0410-80 GC110P144FAST 3 Sample 5 Vial 16 THC R3 0410-80 GC110P144FAST 3 Sample 5 Vial 32 THC R3 0410-80 GC110P144FAST 3 Sample 6 Vial 14 N2 Blank ENV(1=450,2=0) GC110P144FAST 3 Sample 6 Vial 30 N2 Blank ENV(1=450,2=0) GC110P144FAST 3 Sample 7 Vial 2 pause PAUSE 1 Sample 7 Vial 18 pause PAUSE 1 Sample 8 Vial 10 Run 1 lean 0410-85 GC110P144FAST 3 Sample 8 Vial 26 Run 1 lean 0410-85 GC110P144FAST 3 Sample 9 Vial 10 Run 2 lean 0410-85 GC110P144FAST 3 Sample 9 Vial 26 Run 2 lean 0410-85 GC110P144FAST 3 Sample 10 Vial 15 Run 2 lean 0410-85 GC110P144FAST 3 Sample 10 Vial 30 Run 3 lean 0410-85 GC110P144FAST 3 Sample 11 Vial 14 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 1 Sample 11 Vial 30 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 1 Sample 12 Vial 2 pause PAUSE 1 Sample 12 Vial 18 pause PAUSE 1 Sample 13 Vial 14 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 2 Sample 13 Vial 30 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 2 Sample 14 Vial 2 pause PAUSE 1 Sample 14 Vial 18 pause PAUSE 1 Sample 15 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 15 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 16 Vial 8 21-08 Run 3 Spk 0410-60 GC110P144FAST 3 Sample 16 Vial 24 21-08 Run 3 Spk 0410-60 GC110P144FAST 3 Sample 17 Vial 16 1045-2002-R2 0410-57 GC110P144FAST 3 Sample 17 Vial 32 1045-2002-R2 0410-57 GC110P144FAST 3 Sample 18 Vial 12 R1 Backup 0410-59 GC110P144FAST 3 Sample 18 Vial 28 R1 Backup 0410-59 GC110P144FAST 3 Sample 19 Vial 13 VP-1 0310-35 GC110P144FAST 3 Sample 19 Vial 29 VP-1 0310-35 GC110P144FAST 3 Sample 20 Vial 2 pause PAUSE 1 Sample 20 Vial 8 VP-2 0310-35 GC110P144FAST 3 Sample 21 Vial 8 VP-2 0310-35 GC110P144FAST 3 Sample 21 Vial 16 VP-3 0310-35 GC110P144FAST 3 Sample 22 Vial 16 VP-3 0310-35 GC110P144FAST 3 Sample 22 Vial 18 pause PAUSE 1 SampleSequence: G:\GC2010Q2\Betty\sequence\gc110p158.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p158.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 1 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 2 Vial 3 1045-2002-R2 Spk 0410-60 GC110P144FAST 3 Sample 2 Vial 19 1045-2002-R2 Spk 0410-60 GC110P144FAST 3 Sample 3 Vial 8 VP-2 0310-35 GC110P144FAST 3 Sample 3 Vial 24 VP-2 0310-35 GC110P144FAST 3 Sample 4 Vial 16 VP-3 0310-35 GC110P144FAST 3 Sample 4 Vial 32 VP-3 0310-35 GC110P144FAST 3 Sample 5 Vial 13 EPN 03 1 0410-93 GC110P144FAST 3 Sample 5 Vial 29 EPN 03 1 0410-93 GC110P144FAST 3 Sample 6 Vial 12 EPN 03 2 0410-93 GC110P144FAST 3 Sample 6 Vial 28 EPN 03 2 0410-93 GC110P144FAST 3 Sample 7 Vial 7 EPN 03 3 0410-93 GC110P144FAST 3 Sample 7 Vial 23 EPN 03 3 0410-93 GC110P144FAST 3 Sample 8 Vial 5 EPN 04 1 0410-93 GC110P144FAST 3 Sample 8 Vial 21 EPN 04 1 0410-93 GC110P144FAST 3 Sample 9 Vial 11 EPN 04 2 0410-93 GC110P144FAST 3 Sample 9 Vial 27 EPN 04 2 0410-93 GC110P144FAST 3 Sample 10 Vial 4 EPN 04 3 0410-93 GC110P144FAST 3 Sample 10 Vial 20 EPN 04 3 0410-93 GC110P144FAST 3 Sample 11 Vial 6 R3 0410-59 GC110P144FAST 3 Sample 11 Vial 22 R3 0410-59 GC110P144FAST 3 Sample 12 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 12 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 13 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 13 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 14 Vial 14 N2 Blank ENV(1=450,2=0)) GC110P144FAST 3 Sample 14 Vial 30 N2 Blank ENV(1=450,2=0)) GC110P144FAST 3 Sample 15 Vial 8 THC R1 Spk 0410-80 GC110P104FAST 3 Sample 15 Vial 24 THC R1 Spk 0410-80 GC110P104FAST 3 Sample 16 Vial 10 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample 16 Vial 26 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample 17 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 17 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 18 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 18 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 19 Vial 2 pause PAUSE 1 Sample 19 Vial 18 pause PAUSE 1 Sample 20 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 20 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 21 Vial 8 THC R1 Spk 0410-80 GC110P104FAST 3 Sample 21 Vial 24 THC R1 Spk 0410-80 GC110P104FAST 3 Sample 22 Vial 10 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample 22 Vial 26 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample 23 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 23 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 24 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 24 Vial 25 gc110p104 #C5 GC110P144FAST 3 SampleSequence: G:\GC2010Q2\Betty\sequence\gc110p160.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p160.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 8 EPN 03 1 0410-93 GC110P144FAST 3 Sample 1 Vial 24 EPN 03 1 0410-93 GC110P144FAST 3 Sample 2 Vial 12 EPN 03 2 0410-93 GC110P144FAST 3 Sample 2 Vial 28 EPN 03 2 0410-93 GC110P144FAST 3 Sample 3 Vial 7 EPN 03 3 0410-93 GC110P144FAST 3 Sample 3 Vial 23 EPN 03 3 0410-93 GC110P144FAST 3 Sample 4 Vial 5 EPN 04 1 0410-93 GC110P144FAST 3 Sample 4 Vial 21 EPN 04 1 0410-93 GC110P144FAST 3 Sample 5 Vial 11 EPN 04 2 0410-93 GC110P144FAST 3 Sample 5 Vial 27 EPN 04 2 0410-93 GC110P144FAST 3 Sample 6 Vial 4 EPN 04 3 0410-93 GC110P144FAST 3 Sample 6 Vial 20 EPN 04 3 0410-93 GC110P144FAST 3 Sample 7 Vial 6 R3 0410-59 GC110P144FAST 3 Sample 7 Vial 22 R3 0410-59 GC110P144FAST 3 Sample 8 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 8 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 9 Vial 2 pause PAUSE 1 Sample 9 Vial 18 pause PAUSE 1 Sample 10 Vial 14 N2 Blank ENV(1=450,2=0)) GC110P144FAST 3 SampleSequence: G:\GC2010Q2\Betty\sequence\gc110p161.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p161.txt Sequence Table (Front Injector): Sequence Table (Back Injector): Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type 1 Vial 8 EPN 02 1 0410-98 GC110P144FAST 3 Sample 1 Vial 24 EPN 02 1 0410-98 GC110P144FAST 3 Sample 2 Vial 12 EPN 02 2 0410-98 GC110P144FAST 3 Sample 2 Vial 28 EPN 02 2 0410-98 GC110P144FAST 3 Sample 3 Vial 6 Run 1 backup spk 0410-56 GC110P144FAST 3 Sample 3 Vial 22 Run 1 backup spk 0410-56 GC110P144FAST 3 Sample 4 Vial 7 EPN 02 3 0410-98 GC110P144FAST 3 Sample 4 Vial 23 EPN 02 3 0410-98 GC110P144FAST 3 Sample 5 Vial 5 EPN 01 1 0410-98 GC110P144FAST 3 Sample 5 Vial 21 EPN 01 1 0410-98 GC110P144FAST 3 Sample 6 Vial 11 EPN 01 2 0410-98 GC110P144FAST 3 Sample 6 Vial 27 EPN 01 2 0410-98 GC110P144FAST 3 Sample 7 Vial 4 EPN 01 3 0410-98 GC110P144FAST 3 Sample 7 Vial 20 EPN 01 3 0410-98 GC110P144FAST 3 Sample 8 Vial 16 N2 Blank GC110P144FAST 3 Sample 8 Vial 32 N2 Blank GC110P144FAST 3 Sample 9 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 9 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample 10 Vial 2 pause PAUSE 1 Sample 10 Vial 18 pause PAUSE 1 SampleProduct Name Carbon monoxide,

≥ 99.0%

Product Number 295116
Product Brand ALDRICH
CAS Number 630-08-0
Molecular Formula CO Molecular Weight 28.01

TEST SPECIFICATION LOT 03611BJ RESULTS

VENDOR INFORMATION GUARANTEED PURITY OF 99.00% (MINIMUM) BY PURITY OF 99.00% GUARANTEED BY SUPPLIER
QC RELEASE DATE FEBRUARY 2008 

### Pa g e 1 of 1 Certificate Of Anal y sis

1/8/2010 htt p ://www.si g maaldrich.com/catalo g /CertOfAnal y sisPa g e.do?s y mbol=295116&LotNo=03

...Product Name Carbon dioxide,

≥ 99.8%

Product Number 295108
Product Brand ALDRICH
CAS Number 124-38-9
Molecular Formula CO 2 Molecular Weight 44.01

TEST SPECIFICATION LOT 01629AJ RESULTS

VENDOR INFORMATION GUARANTEED PURITY OF 99.80% (MINIMUM) BY PURITY OF 99.80% GUARANTEED BY SUPPLIER
QC RELEASE DATE FEBRUARY 2008 

### Pa g e 1 of 1 Certificate Of Anal y sis

1/8/2010 htt p ://www.si g maaldrich.com/catalo g /CertOfAnal y sisPa g e.do?s y mbol=295108&LotNo=01

...Product Name Methane,
≥ 99.0%

Product Number 295477
Product Brand ALDRICH
CAS Number 74-82-8
Molecular Formula CH 4 Molecular Weight 16.04

TEST SPECIFICATION LOT MKBB4558 RESULTS
Vendor Information Conforms Conforms Guaranteed Purity Of 99.00% (Minimum) By Supplier Specification Date: MAY 2009
Date of QC Release: MAY 2009
Print Date: MAY 14 2009 

### Pa g e 1 of 1 Certificate Of Anal y sis

1/8/2010 htt p ://www.si g maaldrich.com/catalo g /CertOfAnal y sisPa g e.do?s y mbol=295477&LotNo=M

...

## Pure GasesPure Gases 

## 52

**www.mathesontrigas.com Gas Grade Purity**  **Product Cylinder Content**  **Equipment Model Page**  **Specifications Code Size US**  **Metric Recommendations No. No.**  **Nitrous Oxide, Ultra High Purity 99.99%** G1969101 1A 60 lb 27.22 kg Dual Stage Reg. Series 3120-326 299 Guaranteed Specifications G1969140 2 20 lb 9.07 kg Single Stage Reg. Series 3530-326 313 Carbon Dioxide < 2 ppm G1969150 3 6 lb 2.72 kg LB Regulator Series 3550-170 314 Carbon Monoxide < 2 ppm G1969175 LB 0.5 lb 227 gm Gas Warmer 6284-326 435 Nitrogen < 10 ppm Oxygen < 4 ppm THC as CH 4 < 2 ppm A lot analysis will be provided with each cylinder. Please inquire for individual cylinder analysis. Caution: Not for human consumption.
**Nitrous Oxide,CP Grade 99%** G1570101 1A 60 lb 27.22 kg Dual Stage Reg. Series 81-326 293 G1570140 2 20 lb 9.07 kg Single Stage Reg. Series 18-326 292 G1570150 3 6 lb 2.72 kg LB Regulator Series 3320-170 302 G1570175 LB 0.5 lb 227 gm Gas Warmer 6284-326 435 A Certificate of Conformance will be provided on request. Caution: Not for human consumption. 

# Oxygen

**Description** Formula: O 2 **Gas Data** M olecular W eight: 32.00 Density: 1.326 kg/m 3 @ 21.1°C, 101.325 kPa 0.08279 lb/ft 3 @ 70°F, 14.696 psia Specific Volume: 0.7541 m 3 /kg @ 21.1°C, 101.325 kPa 12.08 ft 3 /lb @ 70°F, 14.696 psia
**S hipping Information**  CAS Registry Number: 7782-44-7 UN Number: UN 1072 ECCN Number: EAR99 DOT Proper Shipping Name: Oxygen, Compressed DOT Classification: 2.2 (Nonflammable Gas) DOT Label: NON-FLAMMABLE GAS, OXIDIZER TC Shipping Name: Oxygen, Compressed TC Classification: 2.2, 5.1 TC Label: NON-FLAMMABLE GAS, NON-POISONOUS GAS, OXIDIZER **C ylinder Specifications**  **Approximate Cylinder Valve Outlet Pressure Pressure Ship Weight** 

**Size CGA No. psig @ 70°F kPa @ 21.1°C lb kg** 1L 540 2,640 18,202 173 78 1A 540 2,200 15,168 153 69 2 540 1,600 11,032 80 36 3 540 1,600 11,032 41 19 4 540 1,600 11,032 13 6 6 540 1,585 10,928 20 9 7B 540 1,650 11,376 6 3 7A 540 825 5,688 6 3 7 540 225 1,551 6 3 L B 170 1,600 11,032 6 3

**Gas Grade Purity Product Cylinder**  **Content Equipment**  **Model Page Specifications**  **Code Size US Metric Recommendations**  **No. No. Oxygen, Research Purity 99.998%**  G2182101 1A 249 ft 3 7.05 m 3 Dual Stage Reg. Series 3810-540 318 Guaranteed Specifications G2182140 2 70 ft 3 1.98 m 3 Single Stage Reg. Series 3510-540 312 Argon < 5 ppm G2182150 3 28 ft 3 0.79 m 3 Flash Arrestor 6104A 434 Carbon Dioxide < 0.1 ppm G2182165 4 10 ft 3 0.28 m 3 Leak Detector 8081A 404 Carbon Monoxide < 0.1 ppm G2182178 6 3.53 ft 3 100 L Detector Tube 8014-159SC 392 Hydrogen < 0.1 ppm G2182183 7B 1.76 ft 3 50 L Krypton < 1 ppm G2182182 7A 0.88 ft 3 25 L Nitrogen < 5 ppm G2182181 7 0.25 ft 3 7 L Nitrous Oxide < 2 ppm THC < 0.1 ppm W

ater < 1 ppm A Certificate of Analysis is available on request at a nominal charge. Caution: Not for human consumption. **Oxygen, Matheson Purity 99.997%** G1885112 1L 337 ft 3 9.54 m 3 Dual Stage Reg. Series 3810-540 318 Guaranteed Specifications G1885101 1A 249 ft 3 7.05 m 3 Single Stage Reg. Series 3510-540 312 Argon < 15 ppm G1885140 2 70 ft 3 1.98 m 3 LB Regulator Series 3570-170 314 Carbon Dioxide < 1 ppm G1885150 3 28 ft 3 0.79 m 3 Flash Arrestor 6104A 434 Carbon Monoxide < 1 ppm G1885165 4 10 ft 3 0.28 m 3 Leak Detector 8081A 404 Krypton < 10 ppm G1885175 LB 2 ft 3 56 L Detector Tube 8014-159SC 392 Nitrogen < 10 ppm THC < 0.5 ppm Water < 1 ppm A Certificate of Analysis is available on request at a nominal charge. Caution: Not for human consumption. **Oxygen, Ultra High Purity 99.98%** G1979112 1L 337 ft 3 9.54 m 3 Dual Stage Reg. Series 3120-540 299 Guaranteed Specifications G1979101 1A 249 ft 3 7.05 m 3 Single Stage Reg Series 3530-540 313 Carbon Dioxide < 1 ppm G1979140 2 70 ft 3 1.98 m 3 LB Regulator Series 3570-170 314 Carbon Monoxide < 1 ppm G1979150 3 28 ft 3 0.79 m 3 Flash Arrestor 6103A-O 434 Nitrogen < 15 ppm G1979165 4 10 ft 3 0.28 m 3 Leak Detector 8081A 404 THC < 1 ppm G1979175 LB 2 ft 3 56 L Detector Tube 8014-159SC 392 Water < 5 ppm A lot analysis is available on request. Please inquire for individual cylinder analysis. Caution: Not for human consumption.

## Pure GasesPure Gases 

## 53

**www.mathesontrigas.com** 

# Oxygen (continued)

**G as Grade Purity**  **Product Cylinder Content**  **Equipment Model Page**  **Specifications Code Size US**  **Metric Recommendations No. No.**  **Oxygen, Zero Gas 99.8%** G2060112 1L 337 ft 3 9.54 m 3 Dual Stage Reg. Series 3120-540 299 THC as CH 4 < 0.5 ppm G2060101 1A 249 ft 3 7.05 m 3 Single Stage Reg. Series 3530-540 313 G2060140 2 70 ft 3 1.98 m 3 LB Regulator Series 3570-170 314 G2060150 3 28 ft 3 0.79 m 3 Flash Arrestor 6103A-O 434 G2060165 4 10 ft 3 0.28 m 3 Leak Detector 8081A 404 G2060175 LB 2 ft 3 56 L Detector Tube 8014-159SC 392 A lot analysis will be provided with each cylinder. Please inquire for individual cylinder analysis. Caution: Not for human consumption **Oxygen, Extra Dry 99.6%** G1177201 1A 249 ft 3 7.05 m 3 Dual Stage Reg. Series 3120-540 299 G1177240 2 70 ft 3 1.98 m 3 Single Stage Reg. Series 3530-540 313 G1177250 3 28 ft 3 0.79 m 3 LB Regulator Series 3550-170 314 G1177265 4 10 ft 3 0.28 m 3 Flash Arrestor 6103A-O 434 G1177275 LB 2 ft 3 56 L Leak Detector 8081A 404 Detector Tube 8014-159SC 392 A Certificate of Conformance will be provided on request. Caution: Not for human consumption.

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