BOBBY JINDAL 

GOVERNOR 

~tate of 1Louisiana 

PEGGY M. HATCH 

SECRETARY 

DEPARTMENT OF ENVIRONMENTAL QUALITY 

OFFICE OF ENVIRONMENTAL COMPLIANCE 

Certified Mail No.: 7005 0390 0001 6882 0354 

Mr. Alvin Kooiman 

Pelican Refining Company, LLC': 

4646 Hwy. 3059 

Lake Charles, LA 7061 5 

RE: Permit Modification, Lake Charles Refinery, Pelican Refining Co, LLC, 

Lake Charles, Calcasieu Parish, Louisiana 

Dear Mr. Kooiman: 

Activity No.: PER20100003 

Agency Interest No.: 13058 

·This is to inform you that.the permit modification request for the above referenced facility has been approved under 

LAC 33:111.501. The submittal was approved on the basis of the emissions reported and the approval in no way 

guarantees the design scheme presented will be capable of controlling the emissions as to the types and quantities 

stated. A new application must 'be submitted if the reported emissions are exceeded after operations begin. The 

synopsis, data sheets, and conditions are attached herewith.· 

It will be considered a violation of the permit if all proposed control measures and/or equipment are not installed and 

properly operated and maintained as specified in the application. 

Also enclosed is a document entitled "General Information." Please be advised that this document contains a 

summary of facility~ level information contained in LDEQ's TEMPO database and is not considered a part of the 

permit. ·Please review the information contained in this document for accuracy and completeness. If any changes 

are required or if you have questions regarding this document, you may email your changes to facupdate@la.gov. 

Please be advised that pursuant to provisions .of the Environmental Quality Act and the Administrative Procedure 

Act, the Department may initiate review of a permit during its term. However, before it takes any action to modifY, 

suspend or revoke a permit, the Department shall, in accordance with applicable statutes and regulations, notifY the 

permittee by mail of the facts or operational conduct that warrant the intended action and provide the permittee with 

the opportunity to demonstrate compliance with all lawful requirements for the retention of the effective permit. 

The permit number cited below and agency interest number cited above should be referenced ·in future 

correspondence regarding this facility. 

Done this / f day of ~ , 2011. 

Permit No.: 0520-00027-05 

Sincerely, 

rf~~w~ Sam L. Phillips 

Assistant Secretary 

SLP:TVN 

Post Office Box 4312 • Baton Rouge, Louisiana 70821-4312 • Phone 225-219-3715 • Fax 225-219-3708 

www.deq.louisiana.gov 
AIR PERMIT BRIEFING SH~ET 

AIR PERMITS DIVISION 

LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY 

I. BACKGROUND 

Lake, Charles Refinery 

Agency Interest No.: 13058 

Pelican Refining Co LLC 

Lake Charles, Calcasieu Parish, Louisiana 

This Lake Charles refinery was constructed in the late 70s. The ownership of the refinery was 

transferred from American International Refinery, Inc. (AIRI) to Gold Line Refinery; Ltd. on 

September 26, 1991. AIRI regained operational control of the refinery in March 1997. 

Ownership of the refinery was transferred to Pelican Refining Company, L.L.C. on March 10, 

2005. The refinery was permitted under Part 70 Permit 0520-00027-VO issued February 4, 

2003 and Title V Permit No. 0520-00027-VI dated June 21, 2005. The asphalt plant was 

constructed in 1996 and was permitted under State Permit 0520-000183-02 granted May 27, 

1998 and a general Title V permit No . .2932-VO dated July 6, 2005. Since 2005 this facility 

including Lake Charles Refinery and Asphalt Plant, has been in the processes of resuming 

normal operation. Lake Charles Refinery and Asphalt Plant operated under same Permit No. 

0520-00027-V2 dated January 8, 2007. But through refinery modification and permit 

reconciliation, emissions of each criteria pollutant are below the TV major source threshold. 

The Asphalt Plant and Lake Charles Refinery were permitted under two minor source permits. 

·Currently, the Asphalt Plant operates under permit no. 2932-03, issued on April 12, 2010 and 

Lake Charles Refinery operates under permit no. 0520-00027-04 issued on July 21,2009. 

II. ORIGIN 

A permit application dated December 15, 2010 was submitted requesting a permit modification. 

III. DESCRIPTION 

The petroleum refinery receives crude oil via barge. The crude oil is separated into various 

petroletim fractions, including liquefied petroleum gas (LPG), naphtha, refined petroleum 

products, and atmospheric tower bottoms (A TB) or reduced crude. The reduced crude is 

distilled further to produce vacuum gas oil (VGO) and vacuum tower bottoms (VTB). The 

VTB is used to produce an asphalt product. The petroleum products from the facility are 

transported off-site by barge. · 

The main petroleum refining process units at this facility are: 

• Atmospheric Distillation Unit (ADU), 

• Vacuum Distillation Unit (VDU), and 

• Asphalt Production Unit. 
AIR PERMIT BRIEFING SHEET 

AIR PERMITS DIVISION 

LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY 

Lake Cbarles Refinery 

Agency Interest No.: .J3058 

Pelican Refining Co LLC 

Lake (:harles, ·Calcasieu Parish, Louisiana 

In this modification, Pelican requested the following: 

I. Delete: EQT006, EQT007, EQT009 and EQTOIO: Storage Tanks and EQT020: Tank 

Trucker Loading Rack; and 

2. Updates emissions and the GCXVII based on current operations and calculation 

methodology. · 

Estimated emissions from the Refinery in tons per year are as follows: 

Pollutant Before After Change 

PM1o 6.36 0.86 -5.44 

so2 13.39 1.59 -11.80 

NOx 71.40 I 0.31 -61.09 

co 41.06 6.36 -34.70 

voc1 53.79 65.35 +11.56 

Metal* <0.01 0.005 -0.005 

1

VOC speciation in tons per year: 

LAC 33:1Il .. Chapter 51 Toxic Air Pollutants TAP's: 

Pollutant Before After Change 

I ,3- Butadiene 0.10 0.011 -0.089 

2,2,4 -Trimethylpentane 0.02 0.25 +0.23 

Benzene 0.66 1.75 +1.09 

Biphenyl <0.01 0.17 +0.16 

Cresols <0.01 0.16 +0.15 

Cumene 0.07 0.38. +0.31 

Ethyl benzene 0.19 0.60 +0.41 

F orrnaldehyde <0.01 -0.01 

n-Hexane 0.57 0.67 +0.10 

Naphthalene < O.Ql 0.19 +0.18 

Phenol <0.01 0.17 +0.16 

Toluene 0.52 1.64 +1.12 

Xylene 0.39 1.32 +0.93 

Total VOC TAPs 2.57 7.311 +4.741 

2 
Metals* 

Copper 

Nickel 

AIR PERMIT BRIEFING SHEET 

AIR PERMITS DIVISION • c , ' r 

LOUISIANA DEP ARTJ\,1ENT OF ENVIRONMENTAL QUALITY 

Lake Charles Refinery . ";~ ... 

Ag~ncy Interest No.: 13058 

Pelican Refining Co LLC 

Lake Charles, Calcas_ieu Parish, Louisiana 

< 0.01 

< 0.01 

0.003 

0.002 

-O.OOT 

-0.008 

Estimated emissions from each area, as well as the combined total emissions from the site,' in tons 

per year, are as follows: 

Permit No. PMIO so2 NOx co VOC** 

PeliCan Refinery 0520-00027-05 0.86 1.59 10.31 6.36 73.19 

Asphalt Blending Facility 2932-03 0.16 0.01 2.15 1.80 20.60 

Total 1.02 1.60 12.46 8.16 93.79 

VOC** include GCXVII Activity and Insignificant Activities Emissions. 

IV. TYPE OF REVIEW 

This permit was reviewed for compliance with Louisiana Air Quality Regulations and New 

Source Performance Standards (NSPS). Prevention of Significant Deterioratio~ (PSD) and 

National Emission Standards for Hazardous Air Pollutants (NESHAP) do not apply. This 

facility is a minor source of LAC 33:IIJ.Chapter 51 Toxic Air Pollutan~s (TAPs). 

V. PUBLIC NOTICE 

Public notice is not required to permit a minor source. 

VI. EFFECTS ON AMBIENT AIR 

Emissions associated with the proposed modification were reviewed by the Air Permits 

Division to ensure compliance with the NAAQS and AAS. LDEQ did not require the applicant 

to model emissions. 

Dispersion Model(s) Used: None 

3 
AIR PERMIT BRIEFING SHEET 

AIR PERMITS DIVISION 

LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY 

Lake Charles Refinery 

Agency Interest No.: 13058 

Pelican Refining Co LLC 

Lake Charles, Calcasieu Parish, Louisiana 

VII. GENERAL CONDITION XVII ACTIVITIES 

Emission Rates - tons 

Work Activity Schedule PM10 so2 NOx co voc H2S 

Laboratory Emissions 365 days/year 0.10 

Pump & Valve Maintenance 4 times/year 0.08 0.01 

Tank II 0-15 Landing I days/year 0.11 

Tank 110-16 Landing I days/year 0.06 

Tank 15-05 Landing I days/year 0.21 

Tank 15-06 Landing I days/year 0.21 

Tank 55-01 Landing I days/year 0.08 

Tank Cleaning 0.25 time/year 4.71 

Unit Cleariing & 0.2 times/year 0.33 0.06 

Maintenance 

Vacuum Truck Loading 2 times/year 1.65 0.28 

VIII. INSIGNIFICANT ACTIVITIES 

I D.: Description VOC (TPY) Citation 

Fresh Caustic Storage Tank (2,500 gal) 

Lube Oil Drums (55 gal) 

3 Diesel Storage Tanks (500 gal/each) 

Diesel Storage Tank (300 gal) 

Water Soften System (three 200-gal tanks) 

Fresh Caustic Storage Tank (I 0,500 gal) 

Caustic Mix Tank (I 0,500 gal) 

Maintenance Sandblasting and Painting 

Vapor Degreaser (55 gal) 

Boiler Feed Water Tank (1,900 bbls) 

4 

LAC 33:111.501.B.5.A.4 

. 0.003 LAC 33:111.501.8.5.A.3 

<0.001 LAC 33:111.501.8.5.A.3 

<0.0001 LAC 33:111.501.8.5.A.3 

LAC 33:1I1.501.B.5.A.4 

LAC 33:111.50 1.8.5.A.4 

~ LAC 33:111.501.8.5.A.4 

0.294 LAC 33:111.501.8.5.8.3 

0.006 LAC 33:111.501.8.5.A.3 

LAC 33:111.501.8.5.8.8 
Also Known As: ID 

0520-o0027 

74-2570362 

LAD0924 76126 

GP9326 

I.A0054399 

LAG670039 

WP0197 

GD-Q19-2704 

G-o19-3295 

19450 

31238 

3391 

47217 

48879 

68805 

70616GLDLN4846H 

wac o2o919-o4 

Physical Location: 4846 Hwy 3059 

lake Charles, LA 70601 

Mailing Address: 4646 Hwy 3059 

Lake Charles, LA 70601 

General Information 

AIID: 13058 Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520-00027-05 

Air • Minor (Synthe~ii:) Modification 

Name User Group 

Pelican Refining Co LLC CDS Number 

Federal Tax ID Federal Tax 10 

Pelican Refining Co LLC Hazardous Waste Notification 

· LPDES# LPDES Permit # 

LPDES# LPDES Permit # 

LPDES# LPDES Permil # 

LWDPS# LWDPS Permll # 

Pelican Refining Co LLC Multimedia 

American International Refinery Inc Solid Waste 

Site ID # Solid Waste Facility No. 

American International Refinery -lake Charles Facility TEMPO Merge 

Gold Lilia Reflnlrig Ltd TEMPO Merge 

lake Ch~utes Refining Co TEMPO Merge 

Gold Line Refining ltd - Lake Charles TEMPO Merge 

American International Refinery Inc TEMPO Merge 

American lntemationai Refinery Inc TEMPO Merge 

TRI# Toxic Release Inventory 

Water Quality Certification# Water Certification 

Location of Front Gate: 30.285556.1atitude, -93.131389 longitude, Coordinate Method: Lat.\Long.:. OMS, Coordinate Datum: NA083 

Related People: Name 

Betty Clark 

Ryan Giggar 

Byron Hamilton 

Byron Hamilton 

Byron Hamilton 

Alvin Kooiman 

Alvin Kooiman 

Alvin Kooiman 

· Mailing Address 

PO Drawer 16867 Lake Charles, LA 706166867 

PO Drawer 16867 Lake Charles, LA 70616 

8 Greenway Plaza Ste 930 Houston, TX 77046 

8 Greenway Plaza Ste 930 Houston, TX 77046 

8 Greenway Plaza Ste 930 Houston, TX 77046 

4846 Hwy 3059 (Old Town Rd) Lake Charles; LA 70615 

4846 Hwy 3059 (Old Town Rd) Lake Charles, LA 70615 

4846 Hwy 3059 (Did Town Rd) Lake Charles, LA 70615 

Page 1 of 2 

Phone (Typo) 

3164394066 (WP) 

3374394066 (WP) 

7136776780 (WP) 

7136776760 (WP) 

7136776760 (WP) 

3374918800 (WP) 

alvln.koolman@pelic 

alvin.koolman@pelic 

Main FAX: 

Main Phoile: 

Relationship 

Start Data 

08-o5-2002 

11'21-1999 

03-23-2006 

11~21-1999 

06-25-2003 

12-13-1999 

06-25-2003 

12-29-2004 

01-o6-2002 

11-21-1999 

. 10-26-2000 

02-15-2001 

02-15-2001 

02-15-2001 

10-30-2000 

10-30-2000 

07-29-2004 

01-13-2003 

7136777192 

7136776760 

Acdd&nt Pr&v&ntion Billing Party for 

Hazardous Wasta Permit Contact For 

Water Permit Contact For 

Responsible Official for 

Air Permit Contact For 

Emission Inventory Facility Contact for 

Emission Inventory Facility Contact for 

Responsible Official for 

TPOR0148 
Related People: Name 

Alvin Kooiman 

James Taylor 

James Taylor 

General Information 

AIID: 13058 Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520..()002HJ5 

Air • Minor (Synthetic) Modification . 

Mailing Address 

4046 Hwy 3059 (Old Town Rd) Lake C~arles, LA 70615 

4046 Hwy 3059 (Old Town Rd) Lake Charles, LA 70615 

4046 Hwy,3059 (Old Town Rd) Lake Charles, LA 70615 

·Phone (Type) 

3374916600 (WP) 

3374918806 (WP) 

JT@PELICANREFI~ 

Relationship 

Responsible Official for 

Responsible Official for 

Responsible Official for 

Related Organizations: Name Address Phone (Type} Relationship 

NAIC Codes: 

Pelican Refining Co LLC 

Pelican Refining Co LLC 

Pelican Refining Co LLC 

Pelican' Refining Co LLC 

Pelican Refining. Co LLC 

Pelican Refining Co LLC 

Spooner & Associates Inc 

Spooner & Associates Inc 

32411, Petroleum Refineries 

3355 W Alabama St Ste 575 Houston, TX 77098 

3355 W I'Jabama 51 5te 575 Houston, TX 77098 

3355 W Alabama St Ste 575 HouSton, TX 77098 

500 Kirby 51 Lake Charles, LA 70601 

3355 W Alabama St Ste 575 Houston, TX 77098 

3355 W Alabama St Ste 575 Houston, TX 77098 

PO Box 12685 Lake Charles, LA 706122685 

PO Box 12685 Lake Charles, LA 706122685 

7138776780 (WP) 

7138776780 (WP) 

7138776780 (WP) 

7.138776780 (WP) 

7138776780 (WP) 

3375621568 (HP) 

3375621569 (WP) 

Operates 

Emission Inventory Billing Party 

Air Billing Party for 

Operates 

Owns 

Water Billing Party for 

Provides environmental services for 

Provides environmental services for 

Note: This report entitled "Generallnfonnatlon"' contains a summary of faCUlty-level Information contained In LDEQ's TEMPO database for this facility and Is not considered a part of the permit. 

Please review the Information contained In this document for accuracy and completeness._ If any changes are required or If you have questions regarding this document, you may contact Ms. 

Tommie Milam, Permit Support Services Division, at (225) 219-3259 or email yo~r changes to facupdate@la.Qov. 

Page 2 of 2 TPOR0148 
Subject Item Inventory: 

ID Description 

lake Charles Refinery 

EQT0003 4-76- Plant Flare 

EQT0005 3-91- Crude Oil Storage .Tank (TK 110-16) 

EQT0008 7-78- Crude Oil Storage Tank {TK 55-01) 

EQT 0011 10-78- Crude Oil Storage Tank (TK 40-03) 

EQT 0012 11-78- Intermediate Petroleum Product Tank (TK 10-13) 

EQT 0013 12-78- Intermediate Petroleum Product Tank (TK 10-14) 

EQT0014 13-78- Intermediate Petroleum Product Tank (TK 30-04) 

EQT0015 14-78- Intermediate Petroleum Product Tank (TK 10-07) 

EQT 0016 15-78- Intermediate Petroleum Product Tank (TK 10-Q8) 

EQT 0018 17-78- Naphtha Storage Tank (TK 15-05) 

EQT 0019 18-78- Naphtha Storage Tank (TK 15-06) 

EQT0021 21-78- Barge Loading (Refinery) 

EQT0023 5-80- Crude Oil Storage Tank (TK 110-15) 

EQT0024 1-90 - Vacuum Distillation Unit Heater 

EQT0026 5-91- lntennedlate Petroleum Product Tank (TK 55-18) 

EQT0061 1-99- Slop Oil Tank (TK 1-02) 

EQT0063 3-99- Fire Water Pump - Diesel Engine Driver 

EQT0064 4-99- Spent Caustic Storage Tank (TK-500) 

EQT0065 5-99- Spent Caustic Storage Tank (TK-503) 

EQT0067 7-99 - Instrument Back-up Compressor 

EQT 0069 11-99- Desalter w_ater Storage Tank (TK-103) 

I EQT 0070 2-78 -Boiler 8-482 

EQT 0071 1-98 - Boiler 8-483 

FUG 0003 12-99- Fugitive Equipment Leaks (VDU) 

FUG 0004 1-08- Fugitive Equipment Leaks {Docks) 

FUG 0005 2-08- Fugitive Equipment Leaks (Tanks) 

FUG 0006 3-08- Fugitive Equipment Leaks (Crude) 

TRT 0001 8-99- Wastewater Collection & Treatment 

Stack lnfonnation· 

ID Description 

Lake Charles Refinery 

EQT 0003 4-78- Plant Flare 

INVENTORIES 

AIID: 13058 ·Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520-00027.05 

Air • Minor (Synthetic) Modification 

Tank Volume Max. Operating Rate Normal OperatJng Rate 

1. 77 MM BTU/hr 1.48 MM BTU/hr 

4.62 million 25.2 MM gallons/yr 

aallons 

2.31 million 48.18 MM gallons/yr 

aallons 

1.68 million 

gallons 

420000 gallons 

420000 gallons 

1.26 million. 10.23 MM gallons/yr 

aallons 

420000 gallons 82.48 MM gallons/yr 

420000 gallons 62.09 MM gallonslyr 

630000 gallons 30.66 MM gallons/yr 

630000 gallons 30.66 MM gallons/yr _ 

126000 gallons/hr 105000 gallonslhr 

4.62 million 96.36 MM gallons/yr 

gallons 

47:52 MM BTU/hr 39.6 MM BTU/hr 

2.31 million 10.23 MM gallons/yr 

gallons 

19170 gallons 355332 gallons/yr 296110 gallons/yr 

270 horsepower 225 horsepower 

10500 gallons 110000 gallons/yr 

25200 gallons 260000 gallons/yr 

.2 MM BTU/hr 80 horsepower 

42000 gallons 3.32 MM gaUons/yr 

54 MM BTU/hr 45 MM BTU/hr 

54 MM BTU/hr - 45 MM BTU/hr 

92000 gallons 66240 gallons/day E-~~QO gallons/day 

Velocity FloW Rate Diameter 

(ftlsec) (cubic ft/min-actual) (feet) 

65.6 4369 1.2 

Page 1 of 3 

Contents Operating Tlme 

8760 hr/yr 

Crude Oil 8760 hr/yr 

8760 hr/yr 

8760 hr/yr 

Intermediate Petroleum Product 8760 hr/yr 

Intermediate Petroleum Product 8760 hr/yr 

Intermediate Petroleum Product 8760 hr/yr 

Wastewater 8760 hr/yr 

Intermediate Petroleum Product 8760 hr/yr 

8760 hr/yr 

8760 hr/yr 

280 hr/yr 

8760 hr/yr 

1152 hr/yr 

Intermediate Petroleum Product 8760 hr/yr 

8760 hr/yr 

500 hr/yr 

8760 hc/yr 

8760 hr/yr 

Diesel - 500 hr/yr 

8760 hr/yr 

1152 hr/yr 

1152 hr/yr 

8760 hr/yr 

8760 hr/yr --

8760 hr/yr 

8760 hr/yr 

8760 hr/yr 

Discharge Area Height Temperature 

{square feet) (feet) (oF) 

100 1832 

TPOR0149 
St01ck Information: 

INVENTORIES 

AIID: 13058 -Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520-00027-05 

Air , Minor (Synthetic) Modification 

~-- - -ID -------------- O.acriptkm Volodty 

(fllaec) 

f)ow Rate Diameter DIScharge Area Height Temperature 

I_Uke Char1ea Refinery 

(cubic ftlmin~-~-1) ____ (~~-1) (square feet) (feet) (of) j 

1 EOTOOOS __ ~-~~-: ~e-~iiSt~~-~-Ta_~k(TK 110-16). · ---· _ --·-··--···· "f ·------ ·· ------~~-- -------· --~-~-

1 EOT_~Il_ 7-78_- Crude Oil Storage Tank (TK 55-111) ___ ---------- _ _ _ -------- 1 41 68 

' EOT 0011 1 D-78 - Crude Oil Storage Tank (TK 40-113) 1 41 68 

'·E0T0012 11-78- lntermediatePetroleumProdudTank(tff1o~13) ______ ---- - 1 -------· 41 68 

EQT 0013 12:79- Intermediate Petroleum Product Tank (TK 10-14) 1 41 68 

· EOT 0014 13-78- Intermediate Petroleum Product Tank·(TK-30:.o4) ___ · - · --· -- 1 41 ·-·sa----

EtlT 0015-14-78- lntermedi8te Petroleum Product Tank (TK 10~7) --- ·· --- - ----- 1 --- - ·--------~ 68 

; EoT oo16 15-78·:- lntOiiiiOdTiiiiiF>iiirotiiirml'iOdiicitanli(ll<w::n---er---- -- · -- ------- · --1-- ----- -------- -- 41 68 

-· - o • •R --· EQT 0018 17-78 - Naphtha .,tor.~ga 1 anK l' r.. 1:>-v:>J 41 -- -·- -- -- --68 

EOT 0019 18-78- Naphtha Storage Tani<(n< 15~-) ------- -------- -----------· 41 68 

:-earoo21-21-:n:Bat-g8Lo8ding.(Re1tnery) ······· ··· ···- -------···---- ···- ···-· - --··-2- 20 

j EOT 0023 ~_:_Crude Oil Storage Tank (TK 11D-15) _:-~~-~ 1 - --- - -=~~-= ----~-1 ___ _ 

i EQT 0024 1-90- Vacuum Distillation Unit Heater 20.33 2~~-~-:._27 5 50-.---

! EOT 0026 5-91 - Intermediate Petroleum Product Tank (TK 55--18) 1 41 

~0061 1-99- Slop Oil Tank (TK 1-02) -----------.-1----------- 30 

___ 110 68 ____ , 

--1000 __ _ 

68 

120 

EOT 0063 3-99- Fire Water Pu~T4> - Diesel Englne Drtwr .5 25 550 

~~~=-~:::::~::: ~=:: ~:~: ::~~: ------- --- --------> --- --- ---- --:~ --- --- ... -::-~ -EOT 0067"-7 .gg-.:- "tnStrume·nt sa·Ck.:up·eo---mpres.sor---- --··- ----- - --. - - ·-----:s· - -- .. -- ·---------- 15 550 .. i 

EOT 0069 11-99- Desalt"' Water Stonogo Tank (TK-103) ------- ---- 1 25 78 

-Eciroo7ii2-7s: i!Oftoi 8~82-- - ---- . - . ------ -- - -- -- ·44.82 19010.89 - --- ---3- ----------------------49---------sso ___ . ----

' EOT 0071 1-98- Boiler B-483 18.99 1541i2:4i 4.2 75 . 390 ' - -- .. -------- ---- - ---· -- . ----- - -- ---·-···- --.---. ------------- -------------- -- -- -- _j FUG 0003 12-99 - Fugitive Equipment Leeks (VDU) [ 

:~~ :: ~:i:::: ~;:;;;: ~=: -=:!- -- -- -- ----·- -~------ ------··-- ·- .... ----·-- ____ ...:....._ ... ~-- ---··--_· ___ -I 

TRT 0001 8-99 • Wastewater Collection & Treatment 237 177840 20 20 

Relationships: 

: ao -!~ __ -=_-_-_-----·-· ··---~crlptlon ·--~ Rel•tlonshtp ·-- -- ___ _. _____ ~~ ___ j .. ___ ... ···- ··-----oncrtpt"ic:in · ····· ·----~---·] 

fUG 0003 -·· .L 12-99. Fugitive Equipme~_t_~~ (VOU) -- ___ Controlled by . ..!._OT ooo.:__~--~~ -=-~~n:~lam I 

Page 2 of 3 TPOR014G 
Subject Item Groups: 

10 Group Type 

CRG 0001 Common Requirements Group 

CRG 0002 Common Requirements Group 

CRG 0003 Common Requirements Group 

UNF 0001 Unit or Facility Wide 

Group Membership: 

INVENTORIES 

AI iD: 13058 'Pelican Refining Co i.LC 

Activity Number: PER20100003 

Permit Number: OS20-00027-05 

Air • Minor (Synthetic) Modification 

CRG001 -Fugitive Group 

CRG002.:. External Floating Roof Tanks 

CRG003 -Internal Floating Roof Tanks 

Faclllty - Lake Chartes Refinery 

Group Description 

l 10 ~ Description Member of Groups 

I EOT 0008 i 7-78- Crude Oil Storage Tank (TK 55-Q1) CRG0000000002 ! EQT 0011 10-78- Crude Oil Storage Tank (TK 40-Q3) CRG0000000003 

EQT 0018 17-78- Naphtha Storage Tank (TK 15-Q5) CRG0000000003 

EQT 0019 18-78- Naphtha Storage Tank (TK 15-Q6) CRG0000000003 

EQT 0023 5-80- Crude Oil Storage Tank (TK 110-15) CRG0000000002 

FUG 0003 12-99- Fugitive Equipment Leaks (VDU) CRG0000000001 

FUG 0004 1..{)8- Fugitive Equipment leaks (Docks) CRG0000000001 

FUG 0005 2-Q8- Fugitive Equipment Leaks (Tanks) CRG0000000001 

FUG 0006 3-08- Fugitive Equipment Leaks {Crude} CRG0000000001 

NOTE: The UNF group relationship Is not piinted In this iable. Every subject Item Is a merriber of the UNF group 

Annual Maintenance Fee: 

Fee Number Air Contaminant Source Multiplier Units Of Measure 

0720 0720 Petroi8Um Refining (Rated Capacity) 18 M bbl/day 

' SIC Codes: 

2911 Petroleum refining AI 13058 

2911 Petroleum refining UNF 001 

Page 3 of 3 

. 

TPOR0149 
co 

Subject Item Avg lblhr Maxlb/hr Tons/Yaar 

Lake Charles Refinery 

EQT 0003 0.47 0.57 2.07 4-78 

EQT 0005 

, .. , 

EQT 0008 7-78 

EQT 0011 ' 

'~"==+ i 

EOT 0012 11-78 

EQT 001_3 __ 

12-78 

EQT 0014 13-78 

EQT 0015 14-78 

EQT 0016 15-78 

EQT 0018 17-78 

EQT 0019 18-78 

EOT 0021 21-78 

EQT 0023 ... , 

EQT 0024 , .. , 3.26 3.91 1.88 

EQT 0026 5-91 

EQT 0061 , ... 

EQT 0063 

, .. , 1.50 1.80 0.38 

EQT 0064 4-99 

EQT 0065 , ... ! 

EQT 0067 , .. , 0.53 0.64 0.13 

EQT 0069 11-99 

EOT 0070 2-78 1.64 1.97 0.95 

EQT 0071 I , .. , 1.64 1.97 0.95 I 

EMISSION RATES FOR CRITERIA-POLLUTANTS 

AIID: 13058 - Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520-D0027 -os 

Air- Minor (Synthetic) Modification 

NOx PM10 502 

Avg lb/hr Maxlb/hr Tons/Year Avg lb/hr Maxlb/hr Tons/Year Avg lb/hr 

0.11 0.13 0.47 0.002 0.002 0.01 0.03 

- I 

3.88 4.66 2.24 0.30 0.35 0.17 1.07 

6.98 8.37 1.74 0.50 0.59 0.12 0.46 

2.48 2.98 0.62 0.18 0.21 0.04 0.16 

' 4.56 5.47 2.62 0.45 0.54 0.26 0.60 

4.56 5.47 2.62 I 0.45 0.54 0.26 . 0.60 

Page 1 of2 

VOC 

Maxlb/hr Tons/Year Avg lb/hr Max lblhr Tons/Year 

0.04 0.14· 0.17 0.21 0.75 

1.25 5.45 

' 0.37 1.62 l 

0.07 0.30 

I 0.01 0.04 

0.01 0.04 

"3.02 13.21 

0.08 0.36 

0.08 0.35 

0.65 2.83 

0.65 2.83 

89.85 801.27 12.58 

0.42 1.84 

1.28 0.61 0.21 0.26 0.12 

4.22 18.50 

0.09 0.39 

0.55 0.12 0.57 0.68 0.14 

0.002. <0.01 

0.003 0.02 

. 0.20 0.04 0.20 0.24 0.05 

o.oi 0.05 

0.71 0.34 0.24 0.29 0.14 

0.71 0.34 ·o.24 0.29 0.14 

' TPOR0145 
EMISSION RATES FOR CRITERIA POLLUTANTS 

AIID: 13058 ·Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520.00027.05 

Air • Minor (Synthetic) Modification 

fC:o !NOx ·------T-F'iltll. S02 ~·· - voc 

r· Subject "•m I Avg lblhr I Max fblhr I Tona/Yeai rAvg lblhr Max lblhr I Tona/Yur! Avg lblhr J Max lbntr J Tonai'Y .. r J Avg lbJhr J Max lb"'r J To~IYear Avg lblhr I Max lblhr 1 Tons/Yoar 

i 

-- i... ' 

' 0.15 I ; 0.66 i ' --··· : 0.005 I 0.02 

n ng __ j__o~~ -~ 

002 ; ___ ... ~~ ; 

0.56 I 2.44 __ !_. ------ -' 

Lako Char1oa Reftne_ry I I j I I ! I I I ) 1 I 

---FUG 0003 I i ', ! I I ! I I : 12·1111 , I ; 

FUG 0004 ' ;----1---t---+i- ' I I 

-~: :: -·l:--: -; ~i-- . _j I -- _______ j______ ' , 1: ---+-j--=--~1· . ----:~T 0001 __ -j ----1 ! -· __ ;-___ ~~~--i ·--- [ i _-

Note: EmJ .. Ion ~tn In bold are from attemate scenarto. and.,.. not Included In permitted tobta unta• otherwtae noted In a footnote. 

Page 2 of 2 TPORC14S 
Emission Pl 

EOT 0003 .. ,. 

EOT 0005 

~·· 

EOT 0008 

7-78 

' 

EOT 0011 10..78 

EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AIID: 13058 - Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520-00027-05 

Air- Minor (Synthetic) Modification 

Pollutant Avg lb/hr Max lb/hr 

Benzene <0.001 <0.001 

TOluene 0.001 0.001 

Xylene (mixed isomers) <0.001 <0.001 

n-Hexane 0.01 O.D1 

1,3-Butadiene <0.001 

2,2,4-Trimethylpentane <0.001 

Benzene 0.002 

Biphenyl <0.001 

CresOl <0.001 

Cumene 0.004 

Ethyl benzene ·' <0.001 

Naphthalene <0.001 

Phenol <0.001 

Toluene 0.001 

Xylene (mixed isomers) .<0.001 

n-Hexane 0.001 

1,3-Butadiene ·<0.001 

2,2,4-Trlmethylpentane <0.001 

Benzene 0.002 

Biphenyl <0.001 

Cresol <0.001 

Cumene <0.001 

Ethyl benzene <0.001 

Naphthalene <0.001 

Phenol . <0.001 

Toluene 0.001 

Xylene (mixed isomers) <0.001 

n-Hexane 0.001 

---- 1 ,3-Butadiene <0.001 

2,2,4-T rimethylpentane <0.001 

Benzene <0.001 

Biphenyl <0.001 

Cresol <0.001 

Page 1 of 8 

Tons/Year 

<0.01 

<0.01 

<0.01 

0.03 

<0.001 

<0.01 

<0.01 

<0.01 

<0.01 

0.02 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.001 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

·-----

<0.01 

----·-····· 

<0.01 

-------

<0,001 

<0.01 

<0.01 

<0.01 

<0.01 

TPORD146 
L~~-~.~~~ pt I EQT 0011 l 1().78 

-

EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AIID: 13058 ·Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520-00027-05 

Air • Minor (Synthetic) Modification 

Pollutant Avg lblhr Max lblhr 

--,---------·· 

Tont/Year ' 

Cumena <0.001 

I ~ I <0.01 ; . 

--- ·- ·-·- --j , Elh)'1 benzene <0.001 ' <0.01 

I 

!Naphthalene 

------------. 

.Phonal 

_j_-:_o ~~- -- 1· <0.001 --

·--1-------- ----- !_<0~01 -· , 1 <0.01 

<0.001 <0.01 

Xytono (rTlxod lsomors) 

n·Haxane. <0.001 <0.01 

------ EOT 0012 . ··--- . --r----- -----· ----------r-------;---------r------- 2,2,4-Trimelhy!penlane <0 001 I <0.01 11-71 1-----------t------ -----·-·-------

··--·-· +-~~: -----1 

----+---------

1 <0.01 

' 

Benzene 0.003 

Biphenyt 

<0.001 

1------------+-----·----- <0.001 

1

erasol 

<0.001 I <0.01 I 

1-----t--·li---1_ <0.001 <0.01 1------------+------1------~----~ 

~~~~_ne _____________ ----f--<_o._o_o1 ___ -+--- _ 1 <O 01 _ _j 

l-~= 01=--~-~~===~----·_----_-_-:_·_--_··_·-===~~-------ij1===<=oo=·.:oo=-2:~--------:l,-_-_-__ ~ :-__ -_-_-__ :~0-1: =~==----I Xylene (nixed isomers) ., ~; 

Eth)'1 benzene 

Cumene 

1---------------------

---. -~--- - ·,·--- i=~=o------+-n-_H_e_xa_n_e ____________ ' --'-' __ o_.oo1 ______ 1 --1--<_o_.o_1 ___ ---1 

EOT 0013 2,2,4-Trimelh"'penlane <0.001 <0.01 12-78 1' 1-----------1---. 

Bonzona <0.001 

---------- -----1-----+- ____ 1__<0.0~---

Bipheny! <0.001 l <0.01 

' 

CresoJ 

.----- ··--·-··-----+------- --···· <0.001 1 <0.01 

··---------- icumene <0.001 <0.01 

!Eth)'1 bonzene <O.~~~----+-------t--<_o_.01 _____ / 

;N_~-~~Iha-le_ne ___________ l--~:::~----i-------+--:-:-:-:---~: --------1 

Toluene <0.001 <0.01 

·----------+---,----+--- ----+------

:::~xed l~rs) ------- _ +-~:-0-:---+-------+--:-:-·:-:------

~~~ 0014 . -------+~-.2--j-~:;;lhy!~~~-e-------+l----:·:~~---------~,-=-============::==~:--:-:----~~~---·:_ 

l Biphenyl 

L --------+--------------,--------+--· .. ---- Crosol 0.001 <0.01 

. ------~-----------~-----L-----~-----~ 

0.001 0.01 

Page 2 of 8 TPORO, ... 
Emission Pl. 

EOT 0014 

1~78 

EOT 0015 14-78 

EQT 0016 15-78 

' 

EOT 0018 

17-78 

EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AJID: 130S8 ·Pelican Reflning.Co LLC 

Activity .Number: PER201 00003 

Permit Number: 0520..00027..05 

Air· Minor (Synthetic) ~odiflcation 

Pollutant Avg lb/hr Max lblhr 

Cumene· 0.01 

Ethyl benzene 0.02 

Naphthalen~ 0.003 

Phenol 0.004 

Toluene 0.10 

Xylene (mixed isomers) 0.08 

n-Hexane 0.04 

2,2, 4-Trirnethylpentane <0.001 

Benzene 0.003 

Biphenyl <0.001 

Cresol <0.001 

Cumene <0.001 

Ethyl benzene 0.001 

Naphthalene <0.001 

Phenol <0.001 

Toluene· 0.003 

Xylene (mixed isomers} 0.002 

n-Hexane 0.001 ·. 

2,2,4-Trimethylpentane <0.001 

Benzene 0.003 

Biphenyl <0.001 

Cresol <0.001 

·-·- -·---------- Cumene <0.001 

Ethyl benzene . <0.001 

Naphthalene <0.001 

Phenol <0.001 

Toluene 0.003 

Xylene (mixed isomers} 0.002 

n-Hexane 0.001 

1,3-Butadiene <0.001 

2,2,4-Trimethylpentane <0.001 

Benzene 0.003 -+- ------·---- ---------- -------------------

Biphenyl <0.001 < 

Page 3 of 8 

Tons/Year 

0.05 

0.10 

0.01 

0.02 

0.44 

0.36 

0.17 

<0.01 

0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

0.01 . 

<0.01 

<0.01 

<0.01 

O.Q1 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

0.01 

0.01 

<0.01 

<0.001 

<0.01 

0.01 

<0.01 I 

TPOR0145 
Emlasion Pt. 

EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AIID: 13058 • Pelican Refining Co LLC . 

Activity Number: PER201 00003 

Permit Number: 0520.00027 ~5 

Air· Minor (Synthetic) Modification 

----------..,-----. ·-·---- ·-·--. 

Pollutant Avg lblhr Max lbhlr ToniiYear - . -! 

EQT 0018 ··--------;·-------·-·- ·--.. · I cresol 

,--

:Cumone 

I 

--<-o.o01-- ------!--~-------+-<·o-.o-1 _______ 1 

11-71 

------------+--<-0-.0-01 ___ ----~--· <_0_0_1---·-j 

Ethyt benzene <0.001 < <0.01 

----·· ----.. 

Naphthalene <0.001 < <0.01 

Phenol <0.001 < <0.01 

---- L Toluene 0.001 

, ___ ., r < ••• ··-----... < 

I~~~ 0019 ---------+n--1.-:-:xan-uta-:-,e-na-----------f_--~-:~~.---- ·-· ~~~~~~~~-~--~~+-'---f------~-<-:=·-:=1-~-----=--! 

I <o.o1 

?·2,4-Tnmothytpontono 1 <0.01 

f----------+~-------r---·-.. ---. . ----· --· __ .. !Benzene 0.003 1 0.01 : 

i'-.,8-lpho_n_yt--------------i~--<-0-.00-1 _ .. __ r-- -----· ·-___ <_0 ___ 0_1 ___ ....;; 

1----------+---·----·----·---t------j 

Cresol <0.001 <0.01 J 

0.002 

<0.001 <0.01 

·-----· ·-

I <0.001 <0.01 ·--

~ <0.001 -- _ _j_ <0.01 

·-

: <0.01 ' 

' 

~·~~~_n• __________ _ 'Phenol ; <0.001 

f---.. --------·--i-----··--·- ..... ___ .. Toluene 0.001 0.01 

Xytone (nixed Isomers) <0.001 <0.01 

-- . - n-Hexane 0.002 0.01 --- __ .... --·---- -- ---·---.. I ----r··· _,_ ---- EOT 0021 1.3-Butadieno 21·78 0.01 0.03 <0.001 

2.2.4· Tr\molhytpontona 0.03 0.10 <0.01 

1------------+-----~ -----r-------·-- ·- i 'Benzene 1.20 3.81 0.06 

Biphenyl <o.oo1. I <o.oo1 <0.01 

1-------------t------

C<asol ____ .... <0

0 

.. oo

01

1 _____ 

1

1 . -~~~-----1--<_o_.o_1 ___ --i 

Cumono 0.02 <0.01 - ___ ...... __ - i ·-!----· ----

:::::· -· <:::1 ___ , __ 0.20 -:.:. ;_ :_:_: --------J, 

_-Ph_=·=,;;;-... ~~-- .. ____ .. ____ ' --~- _-_ _I_ _<;_;_ _____ ' __ <001 -= 

Toluono 0.56 1.79 0.03 

f---------------1------ - .. -----·---+------

Xylene (nixed Isomers) 0.14 0.44 001 

f-;E ..-;0;.-T--;002=3:------+1.-3--B_uta_d_ie-no------------· -·--<-0.0-0; _._ .. _._-_-_-_-_!. 

~------- -"--------------'·---· 

n-Hexane 0.76 2.42 0.04 1 

-t--<0001 _j _ _[_ ___ ----

Page 4 ot 8 TPOR0148 
Emission pt 

EQT 0023 

'""' 

' 

EQT 0024 

1·90 

EOT 0026 >-91 

---

EOT 0061 1-99 

EMISSION RATES FOR TAP/HAP &.OTHER POLLUTANTS 

AIID: 13058, • J;>ellcari ~efiniiig.Co LLC 

Activity Number: PE,R20100003 

Permit Number: 0520-00027-05 

Air. Mino; (Synthetic) Modification 

Pollutant Avg lb/hr Max lbfhr 

2,2,4-Tri":~ethylpentane <0.001 

Benzene 0.002 

Biphenyl <0.001. 

···---·----

Cresol <0.001 

Curnene <0.001 

Ethyl benzene <0.001 

Naphthalene <0.001 

Phenol <0.001 

Toluene <0.001 

Xylene (mixed isomers} <0.001 

n-Hexane • 0.001 

Benzene ·<0.001 ·<0.001 

Copper (and compounds) <0.001 <0.001 

Nickel (and compounds) <0.001 <0.001 

Toluene . <0.001 <0.001 

-·· 2,2,4-Trimethylpentane O.o1 

Benzene 0.14 

·---------

Biphenyl 0.002 

Cresol . <0.001 

Cumene 0.02 

Ethyl benzene 0.03 

NSphthalene o:oo4 

Phenol O.o1 

Toluene 0.14 

Xylene (mixed isomers) 0.1 1 

- n-Hexane 0.06 

-- 2,2 .4· T rimethylpentane <0.001 

Benzene <0.001 

Biphenyl <0.001 

Cresol <0.001 

Cumene <0.001 

Ethyl benzene <0.001 

Naphthalene <0.001 

--

Page 5 of 8 

Tons/Year 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.001 

<0.001 

<0.01 

0.05 

0.63 

0.01 

<0.01 

O.o7 

0.14 

0.02 

0.02 

0.61 

0.50 

. 

0.24 

·- <0.01 

<O.o1 

. <0.01 

<0.01 

<0.01 

<0.01 

<0.01 

TPOR01<48 
EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AIID: 13058 • Pel.lcan Refining Co LLC 

Activity Number: PER20100003 

Penni! Number: 0520-{10027-{15 

Air· Minor (Synthetic) Modifieation 

Pollutant Avg lblhr I Max lbhlr 

Phenol <0.001 ----T 

Toluene <0.001 I 

Xylene (mixed isomers) <0.001 ! 

Tona/Year 

<0.01 

<0.01 

_!_ <0.0_1 

<0.001 <0.01 1 n-Hexane 

~eai~~----------b---------------------------~--------------r-------------+-------------~ [ ~" Benzene <0 00~--- _ l- < <0 01 

I ~~u~_ne __ . _____________________ !._ <O oo_, ___ --l---~ ________ -,---<_o_o~ i iEthyt benzene 1 <0.001 1 < i <0.01 

I l:~:::edi~~~-~-----=r-::::-· r.H:------ r::=~j ··•en 0065;;-------------!,!-Be-nz __ e_ne _____ ---------- <0.001 <0.01 ' 

.... 

EOT 0069 11-119 

f-ror-oo-,o --------- 2-ra 

·Cumena <0.001 

Ethyl benzene <0.001 

Toluene <0.001 

Xylene (mixed isome~) <0.001 

-----+--<_o_.oo_1 _____ ~~:-------+---- Benzene <0.001 

r-------·--·------t---- .. ----+------

Biphenyl <0.001 : '------~-----------+-----··--·------;-----

2.2.4-T ~melhylpentane 

:cresol <0.001 

Cumene <0.001 

f------------+----------+-----

Eihyl benzene <0.001 

---------~---

Naphthalene <0.001 

·Phenol <0.001 <0.01 

f----------··--· ·--1-------L ····----+------1 

Toluene <0.001 <0.01 

I <0.01 

<0 01 

<0.01 

----- ··----- <0.001 

)xytene (n'lxed isomers} 

~----------· .. -----+------

In-Hexane __ . ······---------- <O_oo __ 1 _______ i ___ -----------t·-------------1 

I 

Benzene r· -~-0.001 ______ + __ <_o_._oo_1 ______ +------

Copper (and compounds) <0.001 j <0.001 

<0.001 

·- <0.001 ! !Nicl<el (and co..:;,...,nds) <0.00_1 ___ Goo,·-· 

~c;J oo-~,.,., --------·----+~'~=ol=:=ee=n:=====-===··=·--~=--~=-= .. =-~--=~--=~--=~--=~--~:~--· __ :_:·_:=::======--+·~! ===:=:=:=:~: --~-----·-----1---------·-- Copper (and COITI)OUndS) <0.001 <0.001 

. -

<0.01 . 

<0.01 

I --- <0.001 

I <0.001 

-------

i <0.01 

,__, N_icl< __ el_(a_nd __ co __ """"" ___ nd __ sl ______________ , ___ <_0_.00 __ 1_____ JT. _ < 0.001 

:roruone <0.001 <0.001 

Page 6 of8 T'POR01.te 
Emission Pt. 

FUG 0003 

12-99 

FUG 0004 , ... 

FUG 0005 , .. , 

EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AJID: .1~o:S8. Pelican Refining co LLC 

Activity Number: PE~0.1.00003 

Pe.rmit Number: 0520-0g027-05 

Air~ Minor (Synthetic) Modification 

Pollutant Avglb/hr Max lb/hr 

1 ,3-Butadlene <0.001 

2,2,4-T rlmethylpenlene <0.001 

Benzene 0.003 

Biphenyl <0.001 

Cresol <0.001 

Cumene <0.001 

Ethyl benzene 0.001 

Naphthalene <0.001 

Toluene 0.001 

Xylene (mixed isomers) '0.002 

n-Hexane 0.005 

1,3-Butadiene <0.001 

2,2,4-Trimethylpentane <0.001 

Benzene <0.001 

Cumene <0.001 

<0.001 

Toluene <0.001 

Xylene (mixed isomers) <0.001 

n-Hexane <0.001 

1 ,3-Butadiene <0.001 

2,2,4-T rimethylpentane <0.001 

Benzene 0.002 

Cumene <0.001 

Ethyl ber:'zene <0.001 

Naphthalene <0.001 

Toluene <0.001 

TonsfYear 

<0.001 

<0.01 

O.DI 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

0.01 

0.01 

0.02 

<0.001 

<0.01 

<0.01 

<0.01 . 

<0.01 

<0.01 

<0.01 

<0.01 

<0.001 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

<0.01 

r---------·-------------+----------+----------r---------~ - Xylene (mixed isomers) <0.001 <0.01 

1----------------· ----- ·-·-------·-+--------~+-----------

0.001 <0.01 ' 

1'F"'u"'G"'o"'o"'oac--·---+-------- ......... ·-·----· - -------- · ---------....... ·---------- ---------- -1 

3-0B i,3-Butadiene ----------- <0.001 _ <0.001 ·-~ 

2,2,4-Trimethylpentane <0.001 <0.01 ! r----------------------r----------1-~--------t~------C 

Benzene <0.001 <0.01 

Biphenyt <0.001 <0.01 

Cumene <0.001 <0.01 

Page 7 of 6 TPORD146 
EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS 

AJID: 13058- Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520~0027~5 

Air- Minor (Synthetic) Modification 

r ~~G :~~-lon--PL---~-+T--_-_-_-_-_-_-_-_-_-_-_ ~~-;-l_utan~-~---------fi--A_v_a_l_blh_r ___ . --~~----~~ax ~-~-lh_r_ --~-~1------T~o--n--a/Y---~·-ar~-~ -i 

.,..._ Elhyt benzene <0.001 <0.01 I 

1----------·· --------;,-------+, -~ -·------,------- : 

Naphthalene <0.001 I j <0.01 1 

TRT 0001 

.... 

jBiphenyt 

b;;;;-i;~d~n:;~.md~l--- '--· __ . __ -----

r-1~-=-~------------· +-- ---~----

'Ett1yt benzene 

I 

INephlhalene ~- ----· 

- 'Nickel (end OOIT1)0Unda) I 

iPhenol I 

IToluane I --

[Ee (ITixod isomen~) n-Hoxane I 

J -__ ~ ----~-·~-s __ .. ; 

0.60 

-·---· <0.19 

··---·------· 

0.002 

0.17 

I 1.64 I ~ 

1.32 ' 

0.67 

Nota: Emission rates In bokt are from alternate scenarios and are not lnctuded In permttted totals unless otherwtse noted In a footnote. Emlulon 111tes 

attrtbuted to the UNF reflect theaum of the TAP/HAP llmlta of thelndtvldualemlnlon polnta (or caps) under thla pennlt. but do not eonalltute an 

emlaslon up. · 

Page 8 of 8 TPOA0140 
SPECIFIC REQUIREMENTS 

AIID; 13058 ' Pelican Refining Co LLC 

Activity Number; PER201 00003 

Permit Number: 0520-00027-05 

Air • Mlno~ (Synthetic) Modification 

CRG 0001 CRG001 ·Fugitive Group 

Group Members: FUG 0003FUG 0004FUG OOOSFUG 0006 

[40 CFR 60.592(aJI 

2 [40 CFR 60.592(dJI 

3 (40 CFR 60.592(e)] 

4 [LAC 33:111.2122.C.I.c] 

5 [LAC 33:111.2122.C.I.d] 

6 [LAC 33:111.2122.C.2] 

7 (LAC 33:111.2122.C.3] 

8 [LAC 33:111.2122.C.4] 

9 [LAC 33:Ill.2122.C.5] 

10 (LAC 33:111.2122.D.I.a] 

II (LAC 33:111.2122.D.I.b.i] 

12 (LAC 33:111.2122.D.I.b.ii] 

13 (LAC 33:111.2122.D.I.b.iii] 

14 [LAC 33:Ill.2122.D.I.b.iv] 

Comply with the requirements of 40 CFR 60.482-1 to 482-10 as soon as practicable, but no later than 180 days after initial startup. Subpart 

GGG. [40 CFR 60.592(a)] 

Comply with the provisions of 40 CFR 60.485 except as provided in 40 CFR 60.593. Subpart GGG. [40 CFR 60.592(d)] 

Comply with the provisions of 40 CFR 60.486 and 60.487. Subpart GGG. [40 CFR 60.592(e}] 

Repair according to LAC 33:lll.2122.C.3 any regulated component observed leaking by sigh~ sound, or smell, regardless of the leak's 

concentration, except those covered under LAC 33:fii.2122.C.I.d. 

Pumps and valves in heavy liquid service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 within 5 days if observed leaking by 

sight, sound, or smell. Repair according to LAC 33:III.2122.C.3 if the pump or valve is determined to be leaking in excess of the applicable 

limits given in LAC 33:lll.2122. . · 

Which Months: All Year Statistical Basis: None specified 

Do not locate any valve. except safety pressure relief valves, at the end of a pipe or line containing volatile organic compounds unless the end of 

such line is sealed with a second valve, a blind flange, a plug, or a cap. Remove such sealing devices only when the line is in use, for example, 

when a sample is being taken. When the line has been used and is subsequently resealed, close the upstream valve first, followed by ihe sealing 

device. · 

Make every reasonable effort to'repair a leaking component; as described in LAC 33:11l.2122, within 15 days, except as provided. 

Detennine the percent of leaking components at a process Wlit for a test period using the equation in LAC 33:111.2122.C.4. 

Determine the total percent of leaking and unrepairable components using the equation in. LAC 33:Ili.2122.C.5. 

Process drains: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 annually (one time per year). If a reading of 1,000 ppmv or 

greater is recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in LAC 33 :111.2122.C.3. 

Which Months: All Year Statistical Basis: None specified 

Compressor seals: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). If a reading of5,000 ppmv or 

greater is recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in LAC 33:ll1.2122.C.3. 

Which Months: All Year Statistical Basis: None specified 

Pressure relief valves in gas service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). If a reading 

of 1,000 ppmv or greater is recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in LAC 33:Ill.2I22.C.3. 

Which Months: All Year Statistical Basis: None specified · 

Valves in light liquid service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). If a reading of I ,000 

ppmv or greater is recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in LAC 33:III.2122.C.3. Permittee may 

elect to comply with the alternate standards for valves in LAC 33:11l.2122.E (skip period provisions). 

Which Months: All Year Statistical Basis: None specified 

Pumps in light liquid service: VOC, Toial monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). If a reading of 5,000 

ppmv or greater is recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in LAC 33:11l.2122.C.3. 

Which Months: All Year Statistical Basis: None specified 

Page-1 of 15 TPOR0147 
SPECIFIC REQUIREMENTS 

AIID: 13058- Pelican Refining Co LLC 

Activity Number: · PER201 00003 

Permit Number: 0520.00027.05 

Air - Minor (Synthetic) Modification 

CRG 0001 CRG001 - Fugitive Group 

15 [LAC JJ:III.llll.D.I.b.v) 

16 [LAC 33:11L2122.D.I.c] 

17 [LAC 33:11L2122.D.I.d.i] 

18 [LAC J3:111.2122.D.I.e] 

19 [LAC J3:111.2122.D.3.a] 

20 [LAC J3:111.2122.0.3.b] 

21 [LAC 33:111.2122 D.J c] 

22 [LAC JJ:III.2122.D.J.d) 

23 [LAC 3J:IIL2122F.l] 

24 [LAC J3:111.2122.F] 

25 [LAC JJ:111.2122.G] 

Valves in gas service: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quarterly (four times a year). if a reading of 1,000 ppmv 

or greater is recorded, a leak is detected. If a leak is detected. initiate repair provlsions specified in LAC 33:111.2122.C.3. Permittee may elect to 

comply with the alternate sJandards for valves in LAC 33:iil.2122.E (skip period provisions). 

Which Months: All Y car Statistical Basis: None specified 

Pumps: Seal or closure mechanism monitored by visual inspection/determination weekly (52 time< a year). 

Which Months: All Year Statistical Basis: None specified 

Flanged connectors: Presence of a leak monitored by visual, audible, and/or olfactory weekly. 

Which Months: All Year Statistical Basis: None specified 

Instrumenmtion sy>tcms: Presence of a leak monitored by visual, audible, and/or olfactory weekly. 

Which Months: All Year Statistical Basis: None specified 

Pressure relief valves: VOC, Tom! monitored by 40 CFR 60, Appendix A, Method 21 within 24 bours after venting to the atmosphere. If a 

reading of 1,000 ppmv or gTeater (for petroleum refineries, SOCM!, MTBE, and polymer manufacturing industry) or 2,500 ppmv or greater (for 

oatural gas processing plants) is recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in LAC 33:III.2122.C.3. 

Which Months: Ail Year Smtistical Basis: None specified 

Ail components: VOC, Toml monitored by 4{) CFR 60, Appendix A, Method 21 upon each occurrence of a leak detected by sight, smell, or 

sound. unless electing to implement actions as specified in LAC 33:111.2122.C.3. 

Which Months: Ail Year Smtistical Basis: None specified 

Inaccessible valves: VOC, Tomi monitored by 40 CFR 60, Appendix A, Method 21 annually (at a minimum). 

Which Months: Ail Year Statistical Basis: None specified 

Unsafe-to-monitor valves: VOC, Tomi monitored by 40 CFR 60, Appendix A, Method 2 I upon each occurrence of conditions allowing these 

valves to be monitored safely. 

Which Months: All Year Statistical Basis: None specified 

When a component which hils a leak that cannot he repaired, as de<cribed in LAC 33:iil.2122.C, is located, affix to the leaking component a 

weatherproof and readily visible tag bearing an identification number and the date the leak is located. Remove the tag after the leak has been 

repaired. 

Equipment/operational data recordkeeping by survey log upon each occurrence of a leak. Include the leaking component information specified 

in LAC 33:11L2122.F.2.a tluoughj. Retain the survey log for two years after the latter date specified in LAC 33:11L2122.F.2 and make said l.og 

available to DEQ upon request 

Submit report: Due semiannually, by the 31st of January aod July, to the Office of Environmental Assessment, Air Quality Assessment Division. 

Include the information specified in LAC 33:111.2122.G.I through 6 for each calendar quarter during the reporting period. 

CRG 0002 CRG002 - External Floating Roof Tanks 

Group Mem~n: EQT OOOIEQT 0023 

26 (40 CFR 60.Jil(a)(l)) Crude service: Equip with a floating roof, a vapor recovery systent, or their equivalents. Subpart K. (40 CFR 60.112(a)(l)] 

Page 2 of 15 TPOR01•7 
SPECIFIC REQUIREMENTS · 

AIID: 13058 'Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520-40027-45 

Air - Minor (Synthetic) Modification 

CRG 0002 CRG002 -External Floating Roof Tanks 

27 [40 CFR 60.113} 

28 [LAC 33:111.2103.8] 

29 [LAC 33:111.2103.D.2.a} 

30 [LAC 33:111.2103.D.2.b] 

31 [LAC 33:111.2103.D.2.c} 

32 [LAC 33:111.2!03.D.2.d] 

33 [LAC 33:111.2103.D.2.e] 

34 [LAC 33:III.2103.D.2.e] 

35 [LAC 33:III.2!03.D.2.e] 

36 [LAC 33:III.2103.D.2.e] 

37 [LAC 33:11L2103.D.2.e] 

38 [LAC 33:III.2103.D.3] 

39 [LAC 33:111.2103.0.3] 

40 [LAC 33:III.2i03.D.4.a] 

41 [LAC 33:III.2103.D.4.a] 

Petroleum liquid storage data recordkeeping by electronic or hard copy at the approved frequency.Crude Service: Maintain a record of the 

petroleum liquid stored, the period of storage, and the rriaximurn true vapor pressure of that liquid during the respective storage period, except as 

provided iri 40 CFR 60.113(d). Subpart K. 

Equip with a submerged fill pipe. 

Seal closure devices required in LAC 33:111.2103.0 shall have no visible holes, tears, or other openings in the seals or seai fabric. 

Seal closure devices required in LAC 33:111.2103.0 shall be intact and uniformly in place around the circumference of the floating roof and the 

tank wall. 

Seal gap area<= I inA2/ft oftarik diameter (6.5 cm2/0.3 m), for gaps between the secondary seal and tarik wall that exceed 1/8 inch (0.32 em) in 

width. 

Which Months: All Year Statistical Basis: None specified 

Seal gap area<= IO.inA2/ft of tank diameter (65 cm2/0.3 m), for gaps between the primary seal arid tarik wall that exceed 1/8 inch (0.32 em) in 

width. 

Which Months: All Year Statistical Basis: None specified 

Primary seals: Seal gap area & width monitored by measuretrient once every five years at any tank level, provided the roof is off its legs. 

Which Months: All Year Statistical Basis: None specified · 

Equipment/operational data recordkCeping by electronic or hard copy upon occurrence of event. Keep records of conditions that are not up to 

the standards described in LAC 33:111.2103.0.2, and the date(s) that the standands are not met. Noticy the administrative authority within seven 

days of noncompliance with LAC 33:Ili.2103.D.2. 

Secondary seals: Seal gap area & width monitored by measurement annually at any tarik level, provided the roof is off its legs. 

Which Months: All Year Statistical Basis: None specified 

Secoitdary Seal or closure mechanism monitored by visual inspection/determination semiannually. 

Which Months: All Year Statistical Basis: None specified · 

Initiate repairs of seals within seven working days of recognition of defective conditions by ordering approp·riate parts, to avoid noncompliance 

with LAC 33:111.2103. Complete repairs within three months of the ordering of the repair parts. 

Equip all covers, seals, lids, automatic bleeder vents and rim space vents with gaskets. 

Provide all openings in the external floating roof (except for automatic bleeder vents, rim space Vent, and leg sleeves) with a projection below the 

liquid surface. Equip each opening in the roof(except for automatic bleeder vents, rim space vents, roof drains, and leg sleeves) with a cover, 

seal or lid that is to be maintained in a closed position at all times except wheh the device is in aciual use. Keep automatic bleeder vents closed 

at all times except when the roof is being floated off the roof leg supports. Set rim vents tO open when the roof is being floated off the roof leg 

supports or at the manufacturer's reconunended setting. Equip imy emergency roof drain with a slotted membrane fabric cover or equivalent 

cover that covers at least 90 percent of the opening. 

Control nons lotted guide poles and stilling wells using pole wipers and gasketing between the well and sliding cover. Control slotted guide poles 

using a float with wiper, pole wiper, and gasketing between the well and sliding cover. . 

Submit notification: Due to the Office o.f Environmental Assessment; Air Quality Assessment Division, prior to installation of guide poles and 

stilling well systems. Submit a description of the method of control and supporting calculations based Upon the Addendum to American 

Petroleum Institute Publication Number 2517 Evaporative Loss from External Floating Roof Tanks, May 1994, for approval. 

Page 3 of 15 TPOR0147 
SPECIFIC REQUIREMENTS 

AIID: 13058 ·Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Nuniber: 0520-G0027 -G5 

Air , Minor (Synthetic) Modification 

CRG 0002 CRG002 ·External Floating Roof Tanks 

42 [lAC 33:111.2103.D.4.dJ 

43 [lAC 33:111.2103.D.4.dJ 

44 [lAC 33:111.2103.0[ 

45 [lAC 33:111.2103.DJ 

46 [lAC 33:111.2103.H.IJ 

47 [LAC 33:1l1.2103.H.3J 

48 [lAC 33:1l1.21 03.1[ 

Equipment/operaiional dala monitored by visual inspection/determination semiaJUlually. Inspect control systems required by LAC 

. 33:111.2103.0.4 for rips, tear.;, visible gaps in the pole or float wiper, and/or missmg sliding cover gaskets. 

Which Months: All Year Slatistical Basis: None spectfied 

Initiate repairs of any rips, tears, visible gaps in the pole or float wiper, and/or missing sliding cover gaskets by ordering appropriate parts withrn 

seven worlcing days after defect is identified, to avoid noncompliance with LAC 33:111.2103.0.4. Complete repairs within three months of the 

ordering of the repair parts. 

Equip external floating roof with a primary closure seal, consisting of a liquid mounted seal or a mechanical shoe seal, as defined in LAC 

33:!11.2103.C.I.a and b. 

Equip with an external floari!)g roof consisting of a pontoon type roof, double deck type roof, or external floating cover which will rest or float 

on the surface of the liquid contents and is equipped with a primary closure seal to close the space between the roof edge and lank wall and a 

continuous secondary seal (a rim mounted secondary) extending from the floating roof to the lank wall. 

Determine compliance with LAC 33:!11.2103.0.2 and 4 using the methods m LAC 33:111.2103.H.I. 

Determine VOC maximum true vapor pressure using the methods in LAC 33:111.2103.H.3.a-e. 

Equipment/operational data recordkeeping by electronic or hard copy continuously. Keep records of the information specified in LAC 

33:111.2103.1.1 - 7, as applicable. 

CRG 0003 CRG003 • Internal Floating Roof Tanks 

Croup Mrmbe": £QT 0011 £QT OOJIEQT 0019 

49 [40 CFR 60.112(a)(I)J 

50 [40CFR60.113) 

51 [lAC JJ:Ili.2103.8J 

52 [lAC 33:1l1.2103.C.I.aJ 

53 [lAC 33:ni.2103.C.I.bJ 

54 [lAC33:111.2103.C.I.cJ 

55 [lAC 33:ni.2103.C.2J 

Equip with a floating roof, a vaporrecovery system, or their equivalents. Subpart K. [40 CFR 60.112(a)(l )] 

Petroleum liquid storage dala recordkeeping by electronic or hard copy at the approved frequency. Mainlain a record of the petroleum liqurd 

stored, the period of storage, and the maximum true vapor prcssufc of that liquid during the respective storage period, except as provided in 40 

CFR 60.113(d). Subpart K. 

Equip with a submerged fill pipe. 

Equip internal floating roof with~ liquid mounted seal consisting of a foam- or liquid-filled seal mounted in conlact with the liquid between the 

wall of the storage vessel and the floating roof continuously around the circwnference of the tank. 

Equip internal floating roof with a mechanical shoe seal (melallic-type shoe seal) consisting of a metal sheet held venically against the wall of the 

· storage vessel by springs or weighted levers and connected by braces to the floating roof. A flexible coated fabric (envelope) spans the annular 

space between the melal sheet and the floating roof. 

Equip internal floating roof with two seals mounted one above the other so that each forms a cOntinuous closure that completely covers the space 

between the wall of the storage vessel and the edge of the internal floating roof. The lower seal may be vapor-mounted, bul both must be 

continuous. · 

Pro~ide each opening in the internal floating roof(except rim space vents and automatic bleeder vents) with a projection below the liquid 

surface. In addition, provide each opening (except for leg sleeves, bleeder vents, rim space vents, column wells, ladder wells, sample wells, and 

stub drains) with a cover equipped with a gasket.· F..quip automatic bleeder vents and rim space yents with gaskets and equip ladder wells with a 

sliding cover. 

Page 4 of 15 TPOR0,.1 
" 

SPECIFIC REQUIREMENTS 

AIID: 13058 '·Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: OS20.00027 .05 

Air- Minor (Synthetic) Modification 

CRG 0003 CRG003 • Internal Floating Roof Tanks 

56 [LAC 33:111.2103.C) 

57 [LAC 33:111.2103.E.2] 

58 [LAC 33:1il.2103.H.3] 

59 [LAC 33:111.2103.1], 

EQT 0003 4-78 - Plant Flare 

60 [40 CFR 60.104(a)(l)] 

61 [40 CFR 60.105(a)(4)] 

62 [40 CFR 60.106(a)] 

63 [ 40 CFR 60.1 06] 

64 [40 CFR 60.18(c)(l)] 

65 [40 CFR 60.18(c)(2)] 

66 [40 CFR 60.18(c)(3)(ii)] 

67 [40CFR60.18(c)(4)(ii)] 

68 [40 CFR 60.18(d)] 

69 [40 CFR 60.18(<)] 

70 [40 CFR 60.18(!)(2)] 

Equip with an internal floating roof consisting of a pontoon type roof, double deck roof, or internal flo3.ting cover which Will rest or float on the 

surface of the liquid contents and is equipped with a closure seal to close the space between the roof edge and tank wall. All tank gauging and 

sampling devices will be gas-tight except when gauging or sampling is taking place. 

VOC, Total >= 90 %control efficiency using a vapor loss coittrol system. This limitation does !lOt apply during periods of planned routine 

maintenance which may not exceed 240 hours-per year. 

Which Months: All Year Statistical Basis: None specified 

Determine VOC maximum true vapor pressure using the methods in LAC 33:11L2103.H.3.a-e. 

Eqqipritent/operational data recordkeeping by electronic or hard copy continuously. Keep records of the infonnation specified in LAC 

33:Ill.2103.1.1 -7, as applicable. 

Fuel gas: Hydrogen sulfide<~ 0.1 gr/dscf (230 mgldscm). Subpart J. [40 CFR 60.104(a)(1 )] 

Which Months: All Year Statistical Basis: None specified 

Hydrogen sulfide monitored by continuous emission monitor (CEM) Continuously. Monitor the H2S in fuel gases before being burned in any 

fuel gas combustion device. Subpart J. [40 CFR 60.105(a)(4)] 

Which Months: All Year Statistical Basis: None specified 

Use as reference methods and procedures the test methods in 40 CFR 60 appendix A or other methods and procedures as specified in 40 CFR 

60.106, except as provided in 40 CFR 60.8(b), in conducting the performance tests required in 40 CFR 60.8. Subpart J. [40 CFR 60.106(a)] 

·Determine compliance with standards using the test methods and procedures specified in 40 CFR 60.106(a) through (k). Subpart J. 

Design and operate for no visible emissions, as determined by the methods specified in 40 CFR 60.18(f), except for periods not to exceed a total 

of 5 minutes during any two consecutive hours. Subpart A. [40 CFR 60.18(c)(l)] 

Operate with a flame present.at all times, as determined by the methods specified in 40 CFR 60.18({)(2). Subpart A. [40 CFR 60.18(c)(2)] 

Heat content>~ 200 BTU/scf(7.45 MJ/scm). Determine the net heating value of the gas being combusted by the methods specified in 40 CFR 

60.18({)(3). Subpart A [40 CFR 60.18(c)(3)(ii)] 

Which Months: All Year Statistical Basis: None specified 

Exit Velocity>~ 60 and < 400 ftlsec ( 18.3 rnlsec and 112 rnlsec), as determined by the method specified in 40 CFR 60.18(f)( 4). Subpart A. [40 

CFR 60.18(c)(4)(ii)] 

Which Months: All Year Statistical Basis: None specified 

Monitor flares to ensure that they are operated and maintained in conformance with their designs. Applicable subparts will provide provisions 

stating how to monitor flares. Subpart A. [40 CFR 60.18(d)] ' 

Operate at all times when emissions may be vented to the flare. Subpart A. [ 40 CFR 60.18( e)] 

Presence of a flame monitored by flame monitor continuously. Use a thermocouple or any other equivalent device to detect the presence of a 

flare pilot flame. Subpart A. [40 CFR 60.18(f)(2)] 

Which Months: All Year Statistical Basis: Norie specified 

Page 5 of 15 TPOR0147 
EQT 0003 4-78 • Plant Flare 

71 (LAC 33:111.1105} 

72 (lAC 33:111.1105} 

73 (LAC 33:111.1107} 

74 (LAC 33:111509} 

75 (LAC 33:111.509} 

SPECIFIC REQUIREMENTS 

AIID: 13058 ·Pelican Refining Co LLC 

Activity Number:· PER20100003 

Permit Number: 0520.00027.05 

Air • Minor (Synthetic) Modification 

Opacity<~ 20 percent, except for a combined total of six hours in any I 0 consecutive day period, for burning in connection with pressure valve 

releases for control over process upsets. 

Which Monlhs: All Year Statislical Basis: None specified 

Submit notification: Due to the Office of Environmental Compliance as soon as possible after the start ofbuining of presslne valve releases for 

control over process upsets. Notify in accordance with LAC 33:1.3923. Notification is required only if the upset cannot be controlled in six 

hours. 

Submil report: Due in writing to the Office of Environmental Compliance, Surveillance Division, within seven calendar days after startup or 

shutdo~ if flaring was not the result of failure to maintain or repair equipment. Submit report if requesting exemption from the provisions of 

LAC 33:11!.1105. Explain the conditions and duration of the startup or shutdown and list the steps necessary 10 remedy, prevent and limllthe 

excess emissions. Minimize flaring and ensure that no ambient air quality standards are jeopardized. 

Shall nor have visible emissions more than 3 minutes/hour. 

Shall maintain combustion gas less than or equal 0.05 percenl sulfur by by weight- PSD-LA-503. 

EQT 0005 3·91 • Crude 011 Storage Tank (TK 110-16) 

76 (40 CFR 60.112b(a)(2)(ii)J 

77 (40CFR60.112b(a)(2)J 

78 (40CFR60.113b(b)(l)(i)J 

Except for automatic bleeder vents and rim space vents, each opening in a noncontact external floating roof stlall provide a projection below the 

liquid surface. Except for automatic bleeder vents, rim space vents. roof drains, and leg sleeves. equip each opening in the roof with a gasketed 

cOver, seal, or lid and maintain in a closed position at all times (i.e., no visible gap) except when the device is in actual use. Close automatic 

bleeder vents at all times when the roof is floating except when the roof is being floated off or is being landed on the roof leg supports. Set rim 

vents to open when the roof is being floated off the roof legs supports or at the manufacrurer's reconunended setting. Equip aUtomatic bleeder 

· vents and rim space vents with gaskets. Provide each emergency roof drain with a slotted membrane fabric cover that covers at least 90 percent 

of the area of the opening. Subpart Kb. (40 CFR 60.112b(a)(2)(ii)] 

Equip with an external floating roof consisiing of a pontoon-type or double-<lec~ type cover that rests on the liquid surface in a vessel with no 

fixed roof. Equip with a closure device between the wall of the storage vessel and the roof edge. The closure device consisis of two seals, 

secondary above the primary. The primary seal shall be either a mechanical shoe seal or a liquid-mounted seal. Exccpl as provided in 40 CFR 

60.113b(b)( 4), the primary seal shall completely cover the annular space between the edge of tbe floatmg roof and tank wall. The secondary seal 

shall completely cover the annular space between the external floating roof and the wall of the storage vessel in a continuous fashion except as 

allowed in 40 CFR 60.113b(b)(4). The roof shall be floating on the liquid at all times (i.e., off the roof leg supports) except during inilial fill 

until the roof is lifted off leg supports and when the tank is completely emptied and subsequently nofilled. 1be process of filling, emptying, or 

refilling wheo the roofis resting on the leg supports shall be continuous and sball be accomplishro as rapidly as possible. Subpart Kb. [40 CFR 

60.112b(a)(2)] 

Seal gap area & width monitored by measurement at the regulation's specified frequency. Using the procedures in 40 CFR 60.113b(b)(2) 

determine the gap areas and maximum gap widths between the primary seal and the wall of the storage vessel during the hydrostatic testing of1he 

vessel or within 60 days of the in1tial fill with VOL and at least once every 5 years thereafter. Subpart Kb. [40 CFR 60.113b(b)(l )(i)] 

Which Months: All Year Statistical Basis: None specified 

Page 6 of 15 TPOR0147 
SPECIFIC REQUIREMENTS 

AIID: 13058 ·Pelican Refining Co LLC 

Activity Number: PER20100003 

Permit Number: 0520~0027~5 

Air· Minor (Synthetic) Modification 

EQT 0005 3·91 • Crude Oil Storage Tank (TK 11 0·16) 

79 [40 CFR 60.113b(b)(l)(ii)) 

80 [40 CFR 60.113b(b)(3)) 

81 [40 CFR 60.113b(b)(4)(i)(A)] · 

82 [40 CFR 60.113b(b)(4)(i)(B)] 

83 [40 CFR 60.113b(b)(4)(i)) 

84 [40 CFR 60.113b(b)(4)(i)] 

85 [40 CFR 60.113b(b)(4)(ii)(A)] 

86 [40 CFR 60.113b(b)(4)(ii)(B)] 

87 [40 CFR 60.113b(b)(4)(ii)(B)] 

88 [40 CFR 60.113b(b)(4)(ii)(C)] 

89 · [40 CFR 60.113b(b)(4)] 

90 [40 CFR 60.113b(b)(5)) 

91 [40 CFR 60.113b(b)(6)(i)) 

92 [40 CFR 60.113b(b)(6)(ii)] 

Seal gap area &·width monitored by measurement at the regulation's specified frequency. Using the procedures in 40 CFR 60.113b(b)(2) 

determine the gap areas and maximum gap widths between the secondary seal and the wall of the storage vessel within 60 days of the initial fill 

with VOL and at least once per year thereafter. Subpart Kb. [40 CFR 60.113b(b)(l)(ii)] 

Which Months: All Year Statistical Basis: None specified 

Add the gap surface area of each gap location for the primary seal and the secondary seal individually and divide the sum for each seal by the 

nominal diameter of the tank and compare each ratio to the respective standards in 40 CFR 60.113b(b)(4). Subpart Kb. [40 CFR 60.113b(b)(3)] 

One end of the mechanical shoe is to extend into the stored liquid~ and the other end is to extend a minimum vertical distance of61 em above the 

stored liquid sUrface. Subpart Kb. [40 CFR 60.113b(b)(4)(i)(A)] 

There are to be no holes, tears, or other openings in the shoe, primary seal fabric, or seal envelope, Subpart Kb. [40 CFR 60.113b(b)(4)(i)(B)] 

Seal gap area<= 212 cm"2/m of tank diameter (accumulated area) for gaps between the tank wall and the mechanical shoe Or liquid-mounted 

primary seal. Subpart Kb. [40 CFR 60.113b(b)(4)(i)] 

Which Months: All Year Statistical Basis: None specified 

Seal gap width<= 3.81 em for the width of any portion of any gap between the tank wall and the mechanical shoe or liquid-mounted primary 

seai. Subpart Kb. [40 CFR 60.113b(b)(4)(i)] 

Which Months: All Year Statistical Basis: None specified 

Install the secondary seal above the primary seal so that it completely covers the space between the roof edge and the tank wall except as 

provided in 60.113b(b)(2)(iii). Subpart Kb .. [40 CFR 60.113b(b)(4)(ii)(A)] 

Seal gap width<= 1.27 em for the width of any portion of any gap between the tank wall and the secondary seaL Subpart Kb. [40 CFR 

60.113b(b)(4)(ii)(B)] 

Which Months: All Year Statistical Basis: None specified 

Seal gap area <= 21.2 cm'2/ril of tank diameter (accumulated area) for gaps between the tank wall and the secondary seaL Subpart Kb. [40 CFR 

60.113b(b)(4)(ii)(B)] 

Which Months: All Year Statistical Basis: None specified 

There are to. be no holes, tears, or other openings in the secondary seal or seal fabric. Subpart Kb,. [40 CFR 60. i 13b(b)(4)(ii)(C)] 

Make necessary repairs or empty the storage vessel within 45 days of identification in any inspection for seats not meetirig the requirements listed 

in 40 CFR 60.113b(b)(4) (i) and (ii) except as specified in 40 CFR 60.113b(b)(4)(iii). Subpart Kb. [40 CFR 60.113b(b)(4)] 

Submit notification: Due at least 30 days in advance of any gap measurements required by 40 CFR 60.113b(b)(l) to afford DEQ the opportunity 

to have ari observer present. Subpart Kb. [40 CFR 60.113b(b)(5)] 

If the external floating roof has defectS, the primary seal has holes; tears, or other openings in the seal or the seal fabric, or the secondary seal has 

holes, tears; or other openings in the seal or the seal fabric, repair ~e items as necessary so that none of the conditions specified in this paragraph. 

exist before filling or refilling the storage vessel with VOL. Subpart Kb. [40 CFR 60.113b(b)(6)(i)] 

Submit notification in Wfiting: Due ai least 30 days prior to the filling or refilling of each storage vessel for which an inspection is required by 

40 CFR 60.113b(6) to afford DEQ an opportunity to inspect the storage vessel prior to refilling. If the inspection required by paragraph 40 CFR 

60.113b(b)(6) is not planned and the owner or operator could not have known aboui the inspection 30 days in advance or refilling the tank, notify 

DEQ at least 7 days prior to the refilling of the storage vesseL Notify by telephone immediately followed by written documentation . 

demonstrating why the inspection was unplarined. Alternatively, submit notification in writing including the written documentation and send by 

express mail so that it is received by DEQ at least 7 days prior to the refilling. Subpart Kb. [40 CFR 60.113b(b)(6)(ii)] 

Page 7 of 15 TPOR0147 
SPECIFIC REQUIREMENTS 

Al 10: 13058 - Pelican Refining Co LLC 

Activity Number: PER201 00003 

Penn It Number: 0520-40027-45 

Alr , Minor (Synthetic) Modification 

EQT 0005 3-91 - Crude Oil Storage Tank (TK 110-16) 

93 (40 CFR 60.113b(b)(6)1 

94 [40CFR60.11Sb(b)(l)] 

95 (40 CFR 60.11Sb(b)(2)] 

96 [40 CFR 60.11Sb(b)(3)) 

97 [40 CFR 60.11Sb(b)(4)] 

98 (40 CFR 60.116b(b)] 

99 [40 CFR 60.116b(c)] 

100 [LAC 33:1n.2103.B] 

101 (LAC 33:111.2103.D.2.a] 

102 (LAC 33:111.2103.D.2.b) 

)03 (LAC 33:111.2103.D.2.c) 

104 [LAC 33:111.2103.D.2.d) 

105 [LAC 33:1!1.2103.D.2.e] 

106 [LAC 33:111.2103.D.2.e] 

Tank roof and seals monitored by visual inspection/detennination at the regulation's specified frequency. Inspect the external floating roof, the 

primary seal, the secondary seal, and fittings each rime the storage vessel is emptied and degassed. Subpart Kb. [40 CFR 60.113b(b)(6)] 

Which Months: All Year Statistical Basis: None specified 

Submit a report: Due to DEQ as an attaclunent to the notification required by 40 CFR 60.7(a)(3). This report shall describe the control 

equipment and certify that the control equipment meets the specifications of 40 CFR 60.112b(a)(2) and 60.113b(b)(2), (b)(3), and (b](4). Keep 

copies of all reports for at least two years. SubpartKb. [ 40 CFR 60.115b(b)( 1 )] . . , 

Submit a report: Due to DEQ within 60 days of perfonrring the seal gap measurements required by 40 CFR 60.113b(b)( 1 ). The report shall 

contain: I) the date ofmeasuremen~ 2) the raw data obtained in the measuremen~ 3) the calculations described in 40 CFR 60.113b(b)(2) and 

(b)(J ). Keep copies of all reports for at least two years. Subpart Kb. [ 40 CFR 60.11 Sb(b)(2)] 

Gap measurement(s) recordkeeping by electronic or bard copy upon each occurrence of gap measurement performance, as required by 40 CFR 

60.113b(b). Each record shall identify the storage vessel in which the measurement was performed and shall contain: I] the date of 

measuremen~ 2) the raw data obtained in the measurement, 3) the calculations described in 40 CFR 60.113b(b)(2) and (b)(J). Keep copies of 

all records for at least two years. Subpart Kb. [40 CFR 60.115b(b)(3)] 

Submit a report: Due to DEQ within 30 days after each seal gap measurement that detects gaps exceeding the limitations specified by 40 CFR 

60.113b(b)(4). The report will identify the vessel and contain the information specified in 40 CFR 60.115b(b)(2) and the date the vessel was 

emptied or the repairs made and date of repair. Keep copies of all reports for at least two years. Subpart Kb. [40 CFR 60.115b(b)(4)] 

Equipment/operational data recordkeeping by electronic or bard copy continuously. Keep readily accessible records showing the dimension of 

the storage vessel and an analysis showing the capacity of the stonlge vesseL Keep copies of all records for the life of the source as specified by 

40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)) 

VOL storage data recordkeeping by electronic or hard copy continuously. Records consis1 of the VOL stored, the period of storage, and the 

maximum true vapor pressure of that VOL during the respective s1orage period. Keep copies of all records for at leas1 two years. Subpart Kb. 

[40 CFR 60.116b(c)) . 

Equip with a submerged fill pipe. 

Seal closure devices required in LAC 33:11!.2103.D shall have no visible holes, tears, or other openings in the seals or seal fabric. 

Seal closure devices required in LAC 33:11!.2103.D shall be intact and uniformly in place around the circumference of the floating roof and the 

tank wall. 

Seal gap area<= I in' 21ft of tank diameter (6.5 cm2/0.3 m), for gaps between the secondary seal and tank wall that exceed 1/8 inch (0.32 em) in 

width. 

Which Months: All Year StatiStical Basis: None specified 

. Seal gap area <• 10 in'2/ft of tank diamerer (65 cm2/0.3 m), for gaps between the primary seal and tank wall that exceed 118 inch (0.32 em) in 

width. 

Which Months: All Year Statistical Basis: None specified 

Primary seals: Seal gap area & width monirored by measurement once every five years at any tank level, provided the roof is off irs legs. 

Which Months: All Year Statistical Basis: None specified 

Secondary Seal or closure mechanism monitored by visual inspection/determination scmiannual1y. 

Which Months: All Year Sratistical Basis: None specified 

Page 8 of 15 TPORO,A1 
SPECIFIC REQUIREMENTS 

AIID: 13058 • Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520-{10027 -{15 

Air • Minor (Synthetic) Modification 

EQT 0005 3-91- Crude 011 Storage Tank (TK 110-16) 

107 [LAC 33:111.2103.D.2.e] 

108 [LAC 33:111.2103.D.2.e] 

109 [LAC 33:111.2103.D.2.e) 

110 [LAC 33:111.2103.0.3) · 

Ill [LAC 33:111.2103.0.3) 

112 [LAC 33:111.2103.D.4.a] 

113 [LAC 33:111.2103.D.4.a) 

114 [LAC 33:111.2103.D.4.d] 

115 [LAC 33:111.2103.D.4.d] 

116 [LAC 33:111.2103.D) 

117 [LAC 33:lll.2103.D] 

118 [LAC 33:111.2103.H.I] 

119 [LAC 33:111.2103.11.3] 

120 [LAC 33:111.2103.1] 

Equipment/operational data recordkeeping by electronic or hard cop)' upon occurrence of event. Keep records of conditions that are not up to 

the standards described in LAC 33:111.2103.0.2, and the date(s) that the standards are not met. NotifY the administrative authority within seven 

days of noncompliance with LAC 33:111.2103.0.2. 

Initiate repairs of seals within seven working days of recognition of defective conditions by ordering appropriate parts, to avoid noncompliance 

with LAC 33:111.2103. Complete repairs within ihree months of the ordering of the repair parts. 

Secondary seals: Seal gap area & width mOnitored by measureme.nt annually at any tank level, provided the roof is ofT its legs. 

Which Months: All Year Statistical Basis: None specified 

Provide all openings in the: external floating roof(except for automatic bleeder vents, rim space vent, and leg sleeves) with a projection below the 

liquid surface. Equip each opening in the roof(except for automatic bleeder vents, rim space vents, roof drains, and leg sleeves) with a cover, 

seal or lid that is to be mairitained in a closed position at all times except when the device is in actual use. Keep automatic bleeder Vents closed 

at all iimes except When the roof is being floated off the roofleg supports. Set rim vents to open when the roofis being floated off the roof leg 

supports or at the manufacturer's reCommended setting. Equip any emergency roof drain with a slotted membrane fabric cover or equivalent 

cover that coyers at least 90 percent Of the opening. 

Equip all covers, seals, lids," automatic bleeder vents and rim sj:Jace vents with gaskets. 

Control nonslotted guide poles and stilling wells using pole wipers and gasketing between the well and sliding cover. Control slotted guide poles 

using a float with wiper, pole wiper, and gasketing between the well and sliding cove~. 

Submit notification: Due to the Office of Environmental Assessment, Air Quality Assessment Divisio~ prior to installation of guide poles and 

stilling well systems. Submit a description of the method of control and supporting calculations based upon the Addendum to American 

Petroleum Institute Publication Number 2517 Evaporative Loss from External Floating Roof Tanks, May 1994, for approval. 

Equipment/operational data monitored by visual insp~ction/determination semiannually. Inspect control systems required by LAC 

33:II1.2103.D.4 for rips, tears, visible gaps in the pole or float wiper, and/or missing sliding cover gaskets. 

Which Months: All Year Statistical Basis: None specified 

Initiate repairs of any rips, tears, visible gaps in the pole or float wiper, and/or missing sliding cover gaskets by ordering appropriate parts within 

seven working days after defect is identified, to avoid noncompliance with LAC 33:111.2103.0.4. Complete repairs within three months of the 

ordering of the repair parts. 

Equip external floating roof with a primary closure seal, consisting of a liquid mounted seal ~r a mechanical shoe seal, as ~efined in LAC 

33 :Ill.21 03.C.l.a and b. 

Equip with an external floating roof consisting of a pontoon type roof, double deck type roof, or external floating cover which will rest or float 

on the surface of the liquid contents and is equipped with a primary closure seal to close the space between the roof edge and tank wall and a 

continuous secondary seal (a rim mounted secondary) extending from the floating roof to the tank wall. 

Detemiine compliance with LAC 33:Ill.2103.D.2 and 4 using the methods in LAC 33:1ll.2103.H.l. 

Determine VOC maximum true vapor pressure using the methods in LAC 33:!ll.2103.H.3.a-e. 

Equipment/operational data record.keej>ing by electronic or hard copy continuously. Keep records of the information specified in LAC 

33:III.2103.1.1 -7, as applicable. · 

EQT 0008 7-78 • Crude 011 Storage Tank (TK 55-{11) 

Page 9 of 15 TPOR0147 
SPECIFIC REQUIREMENTS 

AIID: 13058, Pelican Reflnlng·Co LLC 

Activity Number: PER20100003 

Permit Number: · 0520~0027 ~5 

Air - Minor (Synthetic) Modlfli:atlon 

EQT 0008 7-78- Crude Oil Storage Tank (TK 55~1) 

121 (LAC 33:111.509) Shall design, operate, monitor, test, and maintain records as required by 40 CFR 60 Subpart K.a- PSD-LA-73. 

EQT 0011 10-78 -Crude Oil Storage Tank (TK 40~3) 

122 [LAC 33:111.509) Shall design, operate, monitor, tes~ and maintain records as required by 40 CFR 60 Subpart K.a- PSD-LA-73. 

EQT 0014 13-78- Intermediate Petroleum Product Tank (TK 30~4) 

123 [40CFR60.113) 

124 [LAC 33:111.509) 

Petroleum liquid storage data recordkeeping by electronic or hard copy at the approved frequency. Maintain a record of the petroleum liquid 

stored, the period of storage, and the maximum true vapor pressure of that liquid dining the respective storage period, except as provided in 40 

CFR 60.113(d). Subpart K. 

Shall design, operate, monitor, test, and maintain records as required by 40 CFR 60 Subpart Ka- PSD-LA-73. 

EQT 0021 21-78- Barge Loading (Refinery) 

125 (LAC 33:111.501.C.6) 

126 (LAC 33:111.501.C.6) 

127 [LAC 33:111.501.C.6) 

128 [lAC 33:111501.C.6) 

Cease using equipment when brealcthmugh occurs and do not reswnc usc until the carbon adsorption unit has been regenerated or replaced. 

Submit re(l!Jrt: Due annually, by the Jist of March. Submit the number of breakthroughs and repaires for the preceding calendar year to the 

Office of Environnlental Compliance, Enforcement Division. 

Within ninety days from the issuance date of this permit, permitte shall submit a monitoring plan for the barge loading activities to the LDEQ-Air 

Quality Assessment Division. Pennitte shall implement the approved monitoring plan as soon as possible but no later than ninety days from the 

date of approval. 

Equipment/operational data recordkecping by electronic or hard copy upon each occurrence ofb[eakthrough and repair. Keep records of the 

repair and number of breakthroughs and on site and available for inspection by the Offic;:c of Environmental Compliance, Surveillance Division. 

EQT 0024 1-90 -Vacuum Distillation Unit Heater 

129 {40CFR60.104(a)(l)) 

130 [40CFR60.105(a)(4)) 

131 [LAC33:111.1101.B) 

132 (LAC 33:111.1311.C) 

Fuel gas: Hydrogen sulfide<~ 0.1 gTidscf(230 mg/dscm). Subpart 1, (40 CFR 60.104(a)(l )] 

Which Months: All Year Statistical Basis: Three-hour rolling average 

Hydrogen sulfide monitored by continuous emission monitor (CEM) continuously. Monitor the H2S in fuel gases before being burned in any 

fuel gas combustion device. Subpart 1. [40 CFR 60.105(a)(4)] 

Which Months: All Year Statistical Basis: None specified 

Opacity <= 20 percent, except during the cleaning of a fire box or building of a new fire, soot blowing or lancing, charging of an incinerator, 

equipment changes, ash removal or rapping of precipitators, which may have an opacity in excess of 20 percent for not more than one six-minute 

period in any 60 consecutive minutes (U>mplies by using sweet nanual gas as fuel). 

Which Months: All Year Statistical Basis: None specified 

Opacity<= 20 percent; except emissions may have an average opacity in excess of 20 percent for not more than one six-minute period in any 60 

consecutive minutes (Complies by using sweet natural gas as fuel). 

Which Months: All Year Statistical Basis: Six-minute average 

Page 10 of 15 TPOR01A7 
SPECIFIC REQUIREMENTS 

AIID: 13058 ' Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520-00027-05-

Air • Minor (Synthetic) Modification 

EQT 0024 1-90 ·Vacuum Distillation Unit Heater 

133 [LAC 33:11LI513] Equipment/operational data recordkeeping by electronic or hard copy continuously. Record and keep on site for at least two years the data 

required to demoristrate exemption from the prov_isions of LAC 33:III.Chapter 15. Record all emissions data in the units of the standard using 

the averaging time of the standard. Make records available to a representative ofDEQ or the U.S. EPA on request. 

EQT 0026 5-91 • Intermediate Petroleum Product Tank (TK 55-18) 

134 [40 CFR 60.116b] Shall keep readily accessible records showing the dimension of the storage vessel and an analysis showing the capacity of the storage vessel for 

at least 2 years. 

EQT 0061 1-99 ·Slop Oil Tank (TK 1-02) 

135 [40CFR60.116b] Shall keep readily accessible records showing the dimension of the storage vessei aDd an analysis showing the capacity of the storage vessel for 

at least 2 years. 

EQT 0063 3-99 • Fire Water Pump ·Diesel Engine Driver 

136 [LAC33:1ILIIOI.B] Opacity<= 20 percent, except during the cleaning of a fire box or building of a new fire, soot blowing or lancing, charging of an incinerator, 

equipment changes. ash removal or rapping of precipitators, which may have an opacity in excess of 20 percent for not more than one six-minute 

period in any 60 consecutive minutes. 

Which Months: All Year Statistical Basis: None specified 

137 [LAC 33:111.13ll.C] Opacity<= 20 percent; except emissions may have an average opacity in excess of20 percent for not more than one six-miriute period in any 60 

consecutive minutes. 

Which Months: All Year Statistical Basis: Six-minUte average 

EQT 0067 7-99 • Instrument Back-up Compressor 

138 {LAC 33:111.1101.8] · Opacity<= 20 percent, except during the cleaning of a fire box or building of a new fire, soot blowing or lancing, charging of an incinerator, 

equipment changes, ash removal or rapping of precipitators; which may have an opacity in excess of 20 perCent for not more than one six-minute 

139 [LAC 33:l!LI31 LC] 

EQT 0070 2-78 ·Boiler B-482 

period in any 60 consecutive minutes. · 

Which Months: All Year Statistical Basis: None specified 

Opacity<= 20 percent; except emissions may have an average opacity in excess of 20 percent for not more than one six-minute period in any 60 

consecutive minutes. 

Which Months: All Year Statistical Basis: Six-minute average 

Page11 of 15 TPOR0147 
EQT 0070 2·78 ·Boiler B-482 

140 (LAC 33:111.1101.B) 

141 (LAC 33:111.1313.C) 

EQT 0071 1·98 • Boiler B-483 

142 (LAC 33:111.1101.8) 

143 (LAC 33:111.1313.C) 

SPECIFIC REQUIREMENTS 

. AIID: 13058 ·Pelican Refining Co LLC 

Activity Number: PER201 00003 

Penn It Number: 0520-G0027 -GS 

Air • Minor (Synthetic) Modification 

Opacity<= 20 percenl~ except during lhe cleaning of a fire box or building of a new fire, sool blowing or lancing, charging of an incinerator, 

equipment changes, ash removal or rapping of precipitators, which may have an opacity in excess of 20 percent for not more than one six-minute 

period in any 60 consecutive minutes. 

Which Months: All Year Statistical Basis: None specified 

Total suspended particulate<= 0.6ib!MMBTU of heat input. 

Which Months: All Year Statistical Basis: None specified 

Opacity <= 20 percent~ except during the cleaning of a fire box or building of a new fire, soot blowing or lancing, charging of an incinerator, 

equipment changes, ash removal or rapping of precipitators, which may have an opacity in excess of 20 percent for not more than one six-minute 

period in any 60 consecutive minutes. 

Which ~onths: All Year Statistical Basis: None specified 

Total suspeoded pantculate <= 0.61b/MMBTU of heat input. 

Which Months: All Year Statistical Basis: None specified 

TRT 0001 8·99 • Wastewater Collection & Treatment 

144 (40CFR60.692-2(a)(ll) 

145 (40 CFR 60.692-2(•)(2)) 

146 (40 CFR 60.692-2(a)(3)) 

147 (40 CFR 60.692-2(a)(4)) 

148 (40 CFR 60.692-2(a)(5)) 

149 (40 CFR 60.692-2(b)(l)) 

150 (40 CFR 60.692-2(b)(2)) 

151 (40 CFR 60.692-2(b)(l)j 

Equip each drain with water seal controls. Subpan QQQ. [40 CFR 60.692-2(a)( I)] 

Equipment/operational data monitored by visual inspection/determination once initially and monthly thereafter. Monitor drains in active service 

for indications of low water levels or other conditions that would reduce the effectiveness of the water seal controls. Subpart QQQ. [ 40 CFR 

60.692·2(a)(2)) 

Which Months: All Year Statistical Basis: None specified 

Equipment/operational data monitored by visual inspection/determination once initially and weekly thereafter. Monitor drains out of active 

service for indications of low water levels or other problems that could result in VOC emissions. Subpan QQQ. [40 CFR 60.692-2(a)(3)] 

Which Months: All Year Statistical Basis: Nooe specified 

Eq~ipment/operational data monitored by technically sound method once initially and semiannually thereafter. Monitor the tightly sealed cap or 

plug over a drain that ts out of service to ensure cap or plug are in place and properly installed. Subpart QQQ. [40 CFR 60.692-2(a)(4)] 

Which Months: All Year Statistical Basis: None specified -

Add water or make first attempts at repair as soon as practicable, but not later than 24 hours after low water levels or missing or improperly 

installed caps or piuS" are detected, except as specified in 40 CFR 60.692~. Subpan QQQ. [40 CFR 60.692·2(a)(5)] 

Junction boxes: Eqmp with a cover. Ensure vent pipes are at least 90 em (3 II) in length and do not exceed 10.2 em (4 in) in diameter. Subpart 

QQQ. [40 CFR 60.692-2(b)(l)] 

Junction boxes: Cover must have a tight seal around the edge and he kept io place at all times, except duriog inspection and maintenance. 

Subpart QQQ. [40 CFR 60.692-2(b)(2)] 

Junction boxes: Equipment/operational ~ta monitored by vis~l inspectionldeteimination once initially and semiannually thereafter. Monitor to 

ensure the cover is in place and to ensure that the cover has a tight seal around the edge. Subpart QQQ. [40 CFR 60.692·2(b)(3)] 

Which Months: All Year Statistical Basis: None specified 

Page t2 of 15 fPORO'" 
SPECIFIC REQUIREMENTS 

AIID: 13058' Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520'(10027 ..IJ5 

Air· Minor (Syntheticj Modification 

TRT 0001 8-99 • Wastewater Collection & Treatment 

i52 [40 CFR 60.692-2(b)(4)] 

i53 [40 CFR 60.692-2(c)(l)] 

154 [40 CFR 60.692-2(c)(2)] 

155 [40 CFR 60.692-2(c)(3)] 

i56 [40 CFR 60.692-2(e)] 

157 [40 CFR 60.692-J(a)] 

158 [40 CFR 60.692-J(b)] 

159 [40 CFR 60.692-J(c)] 

160 [40 CFR 60.692-J(e)] 

161 [40 CFR 60.696(a)] 

162 [40 CFR 60.697(a)] 

163 [40 CFR 60.697(b)] 

164 [40 CFR 60.697(c)] 

165 [40 CFR 60.697(e)] 

Junction boxes: Make a ftrst effort at repair as soon as practicable, but not later thaD 15 calendar days after a broken seal or gap is identified, 

except as provided in 40 CFR 60.692-{i. Subpart QQQ. [40 CFR 60.692-2(b)(4)] 

Sewer lines: Ensure that sewer lines are not open to the atmosphere and are covered or enclosed in a manner so as to have no visual gaps or 

cracks in joints, seals, or other emission interfaces. Subpart QQQ. [40 CFR 60.692-2(c)(l)] 

Sewer lines: Equipment/operational data monitored by visual inspection/determination once initially and semiannually thereafter. Monitor the 

portion of each unburied sewer line for indication of cracks, gaps, or other problems that could result in VOC emissions. Subpart QQQ. [40 CFR 

60.692-2( c)(2)] 

Which Months: All Year Statistical Basis: None specified 

Sewer lines: Make repairs as soon as practicable, bUt not later than 15 calendar days after cracks, gaps, or other problems are detected, except as 

specified in 40 CFR 60.692-{i. Subpart QQQ. [40 CFR 60.692-2(c)(3)] 

Do not route refinery wasteY{ater routed through new drains and a new first common downstreamjunctiori box, either as part of a new or existing 

individual drain system, through a downstream catch basin. Subpart QQQ. [40 CFR 60.692-2(e)] 

Equip and operate each oil-water separator tank, slop oil tank, storage vessel, or other auxiliarY equipment ~th a fixed roof, which meets the 

specifications in 40 CFR 60.692-3(a)(l) through (a)(5), except as provided in 40 CFR 60.692-3(d) or 60.693-2. Subpart QQQ. [40 CFR 60.692-

3(a)] 

Equip and operate each oil-water separator tank or auxiliary equipment with a design capacity to treat more than 16 liters per second (250 gpm) 

with a closed vent system and control device, which meet the requirements 40 CFR 60.692-5, except as provided in 40 CFR 60.692-3(c) or 

60.693-2. Subpart QQQ. [40 CFR 60.692-3(b)] 

Meet the requirements of 40 CFR 60.692-3(a), or coinply with the requirements of 40 CFR 60.692-3(a) for the existing fixed roof covering a 

portion of the separator tank and comply with the requirements for floating roofs in 40 CFR 60.693-2 for the remainder of the separator tank. 

Subpart QQQ. [40 CFR 60.692-3(c)] 

Ensure that slop oil from an oil-water separator tank and oily wastewater from slop oil handling equipment is collected, stored, transported, 

recycled, reused, or disposed of in an enclosed system. Equip equipment used in handling slop oil with a ftxed roof meeting the requirements of 

40 CFR 60.692-3(a). Subpart QQQ. [40 CFR 60.692-3(e)] 

Before using any equipment installed in compliance with 40 CFR 60.692-2, 60.692-3, 60.692-4, 60.692-5, or 60.693, inspect such equipment for 

indication of potential emissions, defects, or other problems that may cause requirements of 40 CFR 60 Subpart QQQ not to be met. Subpart 

QQQ. [40 CFR 60.696(a)] 

Retain all records required by 40 CFR 60 Subpart QQQ for a period of2 years after being recorded unless otherwise noted. Subpart QQQ. [40 

CFR 60.697(a)] 

Inspection records recordkeeping by eJectronic or hard copy at the regulation's specified frequency. Keep the records specified in 40 CPR 

60.697(b)(l) through (b)(3). Subpart QQQ. [40 CFR 60.697(b)] , 

Inspection records recordkeeping by electronic or hard copy at the regulatioO's specified frequency. Keep records of the location, date, and 

corrective action for inspections required by 40 CFR 60.692-3(a) when a problem is identified that could result in VOC emissions.- Subpart 

QQQ. [40 CFR 60.697(c)] 

Equipment/operatiooal data recordkeeping by electroilic or bard eopy at the regulation's specified frequency. Keep the records specified in 40 

CFR 60.697(e)(l) through (e)(4), as applicable. Subpart QQQ. [40 CFR 60.697(e)] 

Page h of 15 TPOR01•7 
SPECIFIC. REQUIREMENTS 

AI 10: 13058 , Pelican Refining Co LLC 

Activity Number: PER201 00003 

Permit Number: 0520~002Hl5 

Air - Minor (Synthetic) Modification 

TRT 0001 8-99 , Wastewater Collection & Treatment 

166 (40 CFR 60.697(1)] 

167 (40 CFR 60.697(g)J 

168 (40CFR60.698(b)(l)j 

169 (40 CFR 60.698(c)j 

170 (LAC 33:111.2109.A.Ij 

171 (LAC3J:Ili.2109.A.2j 

172 (LAC 33:l11.2109.A.3j 

173 (LAC 33:111.2109.Cj 

174 (LAC 33:111.2109.0] 

Equipmen!loperational data recordkeeping by electronic or hard copy continuously. Keep the records specified in 40 CFR 60.697(1)(1] through 

(f)(3) for the life of the source in a readily accessible location. Subpart QQQ. [40 CFR 60.697(1)] 

Equipmen!loperational data recordkeeping by electronic or hard copy at the regulation's specified frequency. Keep plans or specifications which 

indicate the location of out of. active service ~ins covered by tightly sealed caps or plugs for the life of the facility in a readily accessible 

location. Subpart QQQ. [40 CFR 60.697(g)] 

Submit Notification: Due within 60 days after initial startup. Submit a certification that tbe equipment necessary to comply with 40 CFR 60 

Subpart QQQ has been installed arid that the required initial inspeCtions or tests of process drains, sewer lines, junction boxes, oil·water 

separator.l, and closed vent systems and control devices have been carried out in accordance with 40 CFR 60 Subpart QQQ, Thereafter, submit a 

certification semiannually that all of the required inspections have been cartied out in accordance with 40 CFR 60 Subpart QQQ. Subpart QQQ. 

[40 CFR 60.698(b)(l)] . 

Submit report: Due initially and semiannually thereafter. Submit a report that summarizes all inspections when a water seal was dry or otherwise 

breached, when a drain cap or plug was missing or improperly installed, or when cracks, gaps, or other problems were identified that could result 

in VOC emissions, including information about the repairs or corrective action taken. Subpart QQQ. [40 CFR 60.698(c)J 

Equip with a container having all openings sealed and totally enclosed liquid contents. All gauging and sampling devices will be gas-tight except 

when gauging or sampling is taking place. 

Equip with a container furnished with a floating roof. Floating roof shall consist of a pontoon type, double deck type roof. or internal floating 

cover which rests or floats on the surface of the contents and is equipped with a closure seal or seals to close the space between the roof edge and 

· container wall. All gauging and sampling devices will be gas-tight except when gauging or sampling is taking place. 

Equip with a container furnished with a vapor disposal system capable of processing organic vapon and gases so as to limit their emission to the 

atmosphere to the same extent as LAC 33:111.2109.A.I and 2. All gauging and sampling devices will be gas-tight except when gauging or 

sampling is taking place. 

Determine compliance with LAC 33:111.2109.A using monthly visual inspections or one of the test methods in LAC 33:!11.2109.C.I~. where 

appropriate. 

Equipmen!loperational data recordkeeping by electronic or hard copy continuously. Keep records of the information specified in LAC 

33:111.2109.D.I and 3. 

UNF 0001 Facility- Leke Charles Refinery 

175 (40 CFR 60.1 All affected facilities shall comply with all applicable provisions in 40 CFR 60 Subpart A. 

176 (40 CFR 61.] All affected facilines shall comply With all applicable provisions m 40 CFR 61 Subpart A. 

177 (LAC 33:111.1103] Emissions of smoke which pass onto or across a public road and create a traffic hazard by impairment of visibility as defined in LAC 33:nl.lll 

or intensify an existing traffic hazard condition are prohibited. 

178 (LAC 33:111.1109.8] Outdoor burning of waste material or other combustible material is prohibited. 

179 (LAC 33:111.1303.8 J Emissions of particulate maner which pass onto ·or across a public road and create a traffic hazard by impairment of visibiliry or intensify an 

existing traffic hazard condition are prohibited. 

Page t4 of 15 Tl"'RR147 
SPECIFIC REQUIREMENTS 

AIID: 13058 'Pelican Refining Co LLC 

Activity Number: . PER201 00003 

Permit Number: 0520-00027-05 

Air - Minor (Synthetic) Modification 

UNF 0001 Facility- Lake Charles Refinery 

180 [LAC 33:111.2 I 13.A] Maintain best practical housekeeping and maintenance practices at the highest possible standards to reduce the quantity of organic compounds 

emissions. Good housekeeping shall include, but not be limited to, the practices listed in LAC 33:lll.2113.A.l-5. 

181 [LAC 33:111.219) Failure to pay the prescribed application fee or annual fee as provided herein, within 90 days after the due date, will constitute a violation of 

these regulations and shall subject the person to applicable enforcement actions under the Louisiana Environmental Quality Act including, but 

not limited to, revocation of sUspension of the applicable permit, license, registration, or variance. · 

182 [LAC 33:IU.501.C.2] No construction, modification, or operation of a facility which ultimately maY result in an initiation or increase in emission of air contaminants as 

defined in LAC 33 :Ill. III shall commence until the permit application bas been approved, an appropriate permit fee paid (in accordance with 

LAC 33:lll.Chapter 2), and a permit (certificate of approval) has been issued by the permitting authority. 

183 [LAC 33:IIl.50l.C.4] Operate the source in accordance with all tenns and condiiions of this permit. 

184 [LAC 33:IIl.501.C.6] Crude oil Throughput<~ 18000 bbllday Pelican Refinery Crude Oil Throughput<= 18000 bbl/day (30- day rolling average). Throughput shall 

be recorded daily. Noncompliance with this limitation is a reportable vioiation of the permit. Notify the Office of Environmental Compliance, 

Enforcement Divisioit if total crude oil throughput exceeds the rruiximutn listed in this specific condition for any 30 consecutive day period. 

185 [LAC 33:IIl.50 I.C.6] 

186 [LAC 33:111.501.C.6] 

187 [LAC 33:IIl.501.C.6] 

188 [LAC 33:lll.537] 

189 [LAC 33:111.5611.A] 

190 [LAC 33:111.5611.8] 

Which Months: All Year Statistical Basis: I Day average 

Crude oil Throughput recordkeeping by electronic or bal-d copy daily. Keep records dfthe total crude oil throughput each day, as well as the 

total crude oil througbput for the last twelve 1110nths. Make records available for inspection by DEQ personnel. 

Throughput Crude oil Submit report: Due annually, by the 31st of March. Repnrt the crude oil throughput for the preceding calendar year to the 

Office of Environmental Compliance, Enforcement Division. 

ComplY with terms and conditions incorpOrated in the permit to ensure compliance with all state arid federally applicable air quality requirements 

and standards at the source.; and such other permit terms and conditions as determined by the permitting authority to be reasonable and necessary. 

Peimittee shall comply with the Louisiana General Conditions as set forth in LAC 33:lll.537. 

Submit standby plan for the reduction or elimination of emissions during an Air Pollution Alert. Air Pollution Warning. or Air Pollution 

. Emergency: Due within 30 days after requested by the administrative authority. 

During an Air Pollution Alert, Air Pollution Warning or Air Pollution Emergency, make the standby plan available oit the premises to any person 

authorized by the department to enforce these regulations. 

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