Kleinfelder, Inc. 

6200 Harris Technology Blvd. 

Charlotte, NC 28269

TECO: Mulberry, FL 

Client # 109381 

Analytical Report 

(0410-59)

EPA Method 18 

Methane 

Enthalpy Analytical, Inc. 

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 

2202 Ellis Road Durham, NC 27703 - 5518 
I certify that to the best of my knowledge all analytical data presented in this report: 

 Have been checked for completeness 

 Are accurate, error-free, and legible 

 Have been conducted in accordance with approved protocol, and that all deviations and analytical 

problems are summarized in the appropriate narrative(s) 

This analytical report was prepared in Portable Document Format (.PDF) and contains  pages. 

EA# 0410-59 Page 2 of 225
Summary of Results

EA# 0410-59 Page 3 of 225
Compound Sample ID / Adjusted Concentration (ppm)

R1 Backup R2 Stack R3 Stack

Methane 0.563 J 0.514 J 0.559 J

R1 Ambient R2 Ambient R3 Ambient

Methane 2.28 2.29 2.27 

Company

Analyst

Parameters

# Samples

Kleinfelder

TBO / STG

EPA Method 18

6 bags

Client #

Job #

PO #

Report Date

109381

0410-59

Verbal

4/22/2010

0410-59 Results 4/29/2010

EA# 0410-59 Page 4 of 225
Results

EA# 0410-59 Page 5 of 225
MDL 0.394 (ppm) Lower Curve Limit 0.499 (ppm)

LOQ 0.499 (ppm) Upper Curve Limit 10,200 (ppm)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Lab ID

 # 3

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ppm)

Conc

# 2

(ppm)

Conc

# 3

(ppm)

% Diff

Conc

R1 Backup 028B1801.D 028B1802.D 028B1803.D GC110P104_METHANE.M 1.15 1.15 1.15 0.3 0.489 0.491 0.471 2.6 

R2 Stack 029B1201.D 029B1202.D 029B1203.D GC110P104_METHANE.M 1.15 NA 1.15 NA 0.494 0.394 0.437 11.9 R3 Stack 026B1301.D 026B1302.D 026B1303.D GC110P104_METHANE.M 1.15 1.15 1.15 0.1 0.431 0.462 0.546 13.8 

R1 Ambient 028B1701.D 028B1702.D 028B1703.D GC110P104_METHANE.M 1.14 1.14 1.14 0.1 1.97 1.92 1.99 2.3 R2 Ambient 031B1801.D 031B1802.D 031B1803.D GC110P104_METHANE.M 1.14 1.14 1.14 0.2 1.96 1.90 2.05 4.2 R3 Ambient 032B1901.D 032B1902.D 032B1903.D GC110P104_METHANE.M 1.14 1.14 1.14 0.2 1.97 1.93 1.95 1.2 

He Blank 017B2001.D 017B2002.D 017B2003.D GC110P104_METHANE.M NA NA NA NA 0.394 0.394 0.394 0.0 

Run 1 backup spk 018B2501.D 018B2502.D 018B2503.D GC114P103_R_C1.M 1.42 1.42 1.42 0.1 6.64 6.68 6.36 3.1 

Methane

Company

Analyst

Parameters

# Samples

KleinfelderTBO / STGEPA Method 186 bags

Client #

Job #

PO #

Report Date

1093810410-59Verbal4/22/2010

0410-59 Results 

EA# 0410-59 Page 6 of 225
v 2.12 Validated by MSS 7/21/09

% Recovery = (T - U) / S x 100

T = after spike concentration U = before spike concentration S = theoretical spike concentration

Methane Ethane Propane

MW 16.04 MW 30.000 MW 34.000 MW 0.000

What was the conc of the Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3

bag before spiking? (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm)

U' (before spiking) 0.489 0.491 0.471 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

Avg ppm 0.484 Avg ppm 0.00 Avg ppm 0.00 Avg ppm 0.00

What was added to the bag?

ug/mL Total ug ug/mL Total ug ug/mL Total ug ug/mL Total ug

Liquid Spike #1 0 0 00 00 00

uL Added 0 00 0

ug/mL Total ug ug/mL Total ug ug/mL Total ug ug/mL Total ug

Liquid Spike #2 0 0 00 00 00

uL Added 0 00 0

ug/mL Total ug ug/mL Total ug ug/mL Total ug ug/mL Total ug

Liquid Spike #3 0 0 00 00 00

uL Added 0 00 0

Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F)

Gas Spike #1 0 29.59 72.5 100 29.59 72.5 100 29.59 72.5 0 29.59 72.5

Volume Added (mL) 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0

Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F)

Gas Spike #2 1,960 29.74 70.7 0 29.74 70.7 0 29.74 70.7 0 29.74 70.7

Volume Added (mL) 35.0 Total ug 45.2 35 Total ug 0.0 35 Total ug 0.0 35 Total ug 0.0

Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F) Conc. ppm Pbar (inHg) T (F)

Gas Spike #3 0 29.59 72.5 0 29.59 72.5 0 29.59 72.5 0 29.59 72.5

Volume Added (mL) 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0 0 Total ug 0.0

Total Vol (mL) vaporized 0.0 0.0 0.0 0.0

Total Vol (mL) added as gas 35 35 35 35

Other volume (mL) Added 0 00 0

Volume (mL) used in analysis 0 0 0 0

What volume was in the Sampled 4/7/10 10:14 AM Hours

bag before spiking? Wedge Volume 9.546 (L) Delta 218:03:00

Analyzed 4/16/10 12:17 PM

Spiked 4/16/10 1:45 PM Hours

Delta 219:08:51

Spike Analyzed 4/25/10 4:53 PM

Total Vol. After Spiking 9,581 (mL) Spike hold equal to or greater than original hold YES

Ending Volume in Bag (mL) 9,581

Original volume in the bag (mL) 9,546 9,546 9,546 9,546

Total volume added (mL) 35 35 35 35

Dilution Factor caused by addition 1.00 1.00 1.00 1.00

Dilution Adjusted Base Conc (ppm) "U" 0.482 0.00 0.00 0.00

Theoretical Spike Conc (ppm) "S" 7.08 0.00 0.00 #DIV/0!

What was the conc of the Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3 Inj 1 Inj 2 Inj 3

bag after spiking? (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm)

6.64 6.68 6.36 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

Final Concentration (ppm) "T" Avg ppm 6.56 Avg ppm 0.00 Avg ppm 0.00 Avg ppm 0.00

RECOVERY % 85.9 % NA % NA % #DIV/0! %

Company

Analyst

Parameters

Unspiked Sample ID

Kleinfelder

TBO / STG

Bag Spike & Recovery

Run 1 Back-up

Client #

Job #

PO #

Report Date

109381

0410-59

Verbal

4/22/2010

4/29/2010 11:03 AM 0410-59 Results % Recovery

EA# 0410-59 Page 7 of 225
Narrative Summary

EA# 0410-59 Page 8 of 225
Enthalpy Analytical Narrative Summary 

Company Kleinfelder Client # 109381 

Analyst TBO / STG Job # 0410-59 

Parameters EPA Method 18 Bags PO # Verbal 

# Samples 6 bags Report Date April 22, 2010 

Custody Scott Grosshandler received the samples on 4/9/10 after being 

relinquished by Kleinfelder, Inc. All of the samples were received at 

ambient temperature and in good condition. Prior to, during, and after 

analysis, the samples were kept under lock with access only to 

authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for methane using the analytical procedures 

in EPA Method 18, Measurement of Gaseous Organic Compound 

Emissions by Gas Chromatography (40 CFR Part 60, Appendix A). 

The standards and samples were analyzed following the procedures 

specified in section 8.2.1, Integrated Bag Sampling and Analysis. 

All samples and standards were introduced directly to the column using 

an automated 6-port Valco gas sampling valve equipped with a stainless 

steel loop. Methane was referenced to certified gas phase standards. 

The Agilent Technologies Model 6890N, Gas Chromatograph ("Betty" 

S/N US10430048) was equipped with a Flame Ionization Detector and a 

Restek Rtx-1, 30 m x 0.32 mm column (S/N 450928). 

Calibration The calibration curves are located in the back of this report and 

referenced in the Analysis Method column on the Detailed Results page. 

For each calibration curve used, the first page of the curve contains all 

method specific parameters (i.e., curve type, origin, weight, etc.) used to 

quantify the samples. The calibration curve section also includes a table 

with the Retention Time (RetTime), Level (Lvl), Amount 

(corresponding units), Area, Response Factor (Amt/Area) and the 

analyte Name. The calibration table is used to identify (by retention 

time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition method (GC110P144FAST.M) is included in the 

Calibration Curve Chromatograms section of this report. 

EA# 0410-59 Page 9 of 225
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes As required by section 8.4.2, Recovery Study for Bag Sampling, a 

recovery study is performed on a bag sample. The bag sample Run 1 

Back-up was spiked at 1:45 PM on 4/16/10. The recovery efficiency 

value meets the method-required limit of between 70 and 130%. The 

recovery efficiency value is used to adjust the results following equation 

18-7 from section 12.8. 

The sample, Run 1 Primary, did not meet the method’s 5% 

reproducibility criteria between injections before spiking. The sample 

Run 1 Backup was analyzed and met the method reproducibility 

criteria. Only the analysis of the backup bag has been reported. All 

method requirements were met. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

These analytical results are reported on a wet basis. The user of this 

report should determine the % moisture in the sample and correct the 

reported value to ppmvd as appropriate. 

Enthalpy Analytical, Inc. is accredited to perform this method for 

compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 

EA# 0410-59 Page 10 of 225
General Reporting Notes 

The following are general reporting notes that are applicable to all Enthalpy Analytical, Inc. data 

reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot 

determine the presence of the analyte of interest reliably. 

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot 

quantitate the analyte of interest within the criteria of the method. 

 The acronym ND following a value indicates a non-detect or analytical result below the MDL. 

 The letter J following a value indicates an analytical result between the MDL and the LOQ. A J flag 

indicates that the laboratory can positively identify the analyte of interest as present, but the value 

should be considered an estimate. 

 The letter E following a value indicates an analytical result exceeding 100% of the highest calibration 

point. The associated value should be considered as an estimate. 

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the 

preparation and/or analysis process. The analytical result taken from a laboratory instrument is 

multiplied by the DF to determine the final undiluted sample results. 

 The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is 

spiked with a known amount of analyte so that a percent recovery value can be determined. This shows 

what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample 

matrix interferes with the analysis of the analyte(s). 

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same 

manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality 

by showing the consistency of results gained by performing the same steps multiple times. 

 The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an 

additional aliquot of sample for testing and the results of the duplicate analysis are compared to the 

initial result. The result should have a difference value of within 10% of the initial result (if the results 

of the original analysis are greater than the LOQ). 

 The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an 

additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps 

confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of 

interest, as they would have a different response/absorbance than the analyte of interest. 

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample 

matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and 

procedures used for the client samples. The LCS is used to assess the control of the laboratory’s 

analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. 

The extras (randomly chosen) are labeled with the associated project number and kept in-house at the 

appropriate temperature conditions. When the project samples are received for analysis, the LCSs are 

analyzed to confirm that the analyte could be recovered from the media, separate from the samples 

which were used on the project and which may have been affected by source matrix, sample collection 

and/or sample transport. 

EA# 0410-59 Page 11 of 225
General Reporting Notes 

(continued) 

 Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, 

the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a 

value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no 

confidence should be placed on more than two significant digits. 

 Manual Integration: The data systems used for processing will flag manually integrated peaks with 

an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified 

by the following two letter designations. The peak was not integrated by the software “NI”, the peak 

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software 

“WP”. These codes will accompany the analyst’s manual integration stamp placed next to the 

compound name. 

EA# 0410-59 Page 12 of 225
Sample Custody

EA# 0410-59 Page 13 of 225
EA# 0410-59 Page 14 of 225
Sample 

Chromatograms

EA# 0410-59 Page 15 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 16-Apr-10, 12:17:10 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P157\028B1801.D)

 Area: 0.131969 Area: 0.0211804 1.124 1.148 - Methane 1.230

 6.592

 7.294

 7.984

 8.815

 9.388

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.148 MF 1.31969e-1 3.70546 4.89006e-1 Methane 

Totals : 4.89006e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\028B1801.D

Sample Name: R1 Backup 0410-59

Betty Reprocess 4/21/2010 12:09:49 PM Page 1 of 1

EA# 0410-59 Page 16 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 16-Apr-10, 12:36:09 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P157\028B1802.D) 1.119 1.145 - Methane

 6.596

 8.811

 9.379

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.145 PB 1.32436e-1 3.70546 4.90736e-1 Methane 

Totals : 4.90736e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\028B1802.D

Sample Name: R1 Backup 0410-59

Betty Reprocess 4/21/2010 12:10:04 PM Page 1 of 1

EA# 0410-59 Page 17 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 16-Apr-10, 12:55:11 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P157\028B1803.D) 1.123 1.149 - Methane

 6.593

 9.381

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.149 PB 1.27163e-1 3.70546 4.71199e-1 Methane 

Totals : 4.71199e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\028B1803.D

Sample Name: R1 Backup 0410-59

Betty Reprocess 4/21/2010 12:11:00 PM Page 1 of 1

EA# 0410-59 Page 18 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 12

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 09-Apr-10, 15:43:08 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\029B1201.D) 1.125 1.150 - Methane

 8.595

 8.806

 9.369

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.150 PB 1.33421e-1 3.70546 4.94388e-1 Methane 

Totals : 4.94388e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\029B1201.D

Sample Name: R2 Stack 0410-59

Betty Reprocess 4/16/2010 10:17:47 AM Page 1 of 1

EA# 0410-59 Page 19 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 12

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 09-Apr-10, 15:59:13 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\029B1202.D) 1.121 1.148 - Methane 1.772

 8.597

 8.811

 9.383

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.148 PB 8.45188e-2 3.70546 3.13182e-1 Methane 

Totals : 3.13182e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\029B1202.D

Sample Name: R2 Stack 0410-59

Betty Reprocess 4/16/2010 10:17:58 AM Page 1 of 1

EA# 0410-59 Page 20 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 12

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 09-Apr-10, 16:17:57 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\029B1203.D) 1.123 1.151 - Methane

 8.599

 8.810

 9.380

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.151 PB 1.17885e-1 3.70546 4.36820e-1 Methane 

Totals : 4.36820e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\029B1203.D

Sample Name: R2 Stack 0410-59

Betty Reprocess 4/16/2010 10:18:11 AM Page 1 of 1

EA# 0410-59 Page 21 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 13

Acq. Instrument : Betty online Location : Vial 26

Injection Date : 09-Apr-10, 16:35:48 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\026B1301.D) 1.120 1.149 - Methane

 8.393

 8.593

 8.807

 9.375

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.149 PB 1.16354e-1 3.70546 4.31146e-1 Methane 

Totals : 4.31146e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\026B1301.D

Sample Name: R3 Stack 0410-59

Betty Reprocess 4/16/2010 10:18:32 AM Page 1 of 1

EA# 0410-59 Page 22 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 13

Acq. Instrument : Betty online Location : Vial 26

Injection Date : 09-Apr-10, 16:54:33 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\026B1302.D) 1.121 1.148 - Methane

 8.394

 8.595

 8.809

 9.381

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.148 PB 1.24669e-1 3.70546 4.61958e-1 Methane 

Totals : 4.61958e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\026B1302.D

Sample Name: R3 Stack 0410-59

Betty Reprocess 4/16/2010 10:18:45 AM Page 1 of 1

EA# 0410-59 Page 23 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 13

Acq. Instrument : Betty online Location : Vial 26

Injection Date : 09-Apr-10, 17:12:12 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\026B1303.D) 1.120 1.150 - Methane

 8.391

 8.590

 8.806

 9.373

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.150 PV 1.48119e-1 3.68712 5.46132e-1 Methane 

Totals : 5.46132e-1

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\026B1303.D

Sample Name: R3 Stack 0410-59

Betty Reprocess 4/16/2010 10:19:00 AM Page 1 of 1

EA# 0410-59 Page 24 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Apr-10, 20:15:17 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\028B1701.D) 1.116 1.142 - Methane

 8.591

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.142 PB 5.55693e-1 3.55245 1.97407 Methane 

Totals : 1.97407

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\028B1701.D

Sample Name: R1 Ambient 0410-59

Betty Reprocess 4/16/2010 10:19:24 AM Page 1 of 1

EA# 0410-59 Page 25 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Apr-10, 20:34:03 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\028B1702.D) 1.114 1.141 - Methane

 8.590

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.141 PB 5.39391e-1 3.55393 1.91696 Methane 

Totals : 1.91696

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\028B1702.D

Sample Name: R1 Ambient 0410-59

Betty Reprocess 4/16/2010 10:19:37 AM Page 1 of 1

EA# 0410-59 Page 26 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Apr-10, 20:52:09 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\028B1703.D)

 Area: 0.561487 Area: 0.0476965 1.114 1.146 - Methane 1.172

 8.587

 8.801

 9.356

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.146 MF 5.61487e-1 3.55195 1.99438 Methane 

Totals : 1.99438

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\028B1703.D

Sample Name: R1 Ambient 0410-59

Betty Reprocess 4/23/2010 8:13:36 AM Page 1 of 1

EA# 0410-59 Page 27 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 31

Injection Date : 09-Apr-10, 21:10:45 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\031B1801.D)

 Area: 0.552473 Area: 0.0500326 1.113 1.143 - Methane 1.182

 3.355 3.458

 8.800

 9.359

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.143 MF 5.52473e-1 3.55274 1.96279 Methane 

Totals : 1.96279

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\031B1801.D

Sample Name: R2 Ambient 0410-59

Betty Reprocess 4/23/2010 8:14:17 AM Page 1 of 1

EA# 0410-59 Page 28 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 31

Injection Date : 09-Apr-10, 21:29:00 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\031B1802.D) 1.114 1.141 - Methane

 8.589

 8.797

 9.354

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.141 PB 5.33666e-1 3.55447 1.89690 Methane 

Totals : 1.89690

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\031B1802.D

Sample Name: R2 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:09 AM Page 1 of 1

EA# 0410-59 Page 29 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 31

Injection Date : 09-Apr-10, 21:47:40 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\031B1803.D) 1.112 1.139 - Methane

 8.589

 8.797

 9.353

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.139 PB 5.78423e-1 3.55053 2.05371 Methane 

Totals : 2.05371

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\031B1803.D

Sample Name: R2 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:20 AM Page 1 of 1

EA# 0410-59 Page 30 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 19

Acq. Instrument : Betty online Location : Vial 32

Injection Date : 09-Apr-10, 22:05:55 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\032B1901.D) 1.114 1.141 - Methane

 9.354

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.141 PB 5.55930e-1 3.55243 1.97490 Methane 

Totals : 1.97490

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\032B1901.D

Sample Name: R3 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:36 AM Page 1 of 1

EA# 0410-59 Page 31 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 19

Acq. Instrument : Betty online Location : Vial 32

Injection Date : 09-Apr-10, 22:24:24 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\032B1902.D) 1.112 1.139 - Methane

 8.586

 8.796

 9.347

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.139 PB 5.43262e-1 3.55357 1.93052 Methane 

Totals : 1.93052

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\032B1902.D

Sample Name: R3 Ambient 0410-59

Betty Reprocess 4/16/2010 11:05:47 AM Page 1 of 1

EA# 0410-59 Page 32 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 19

Acq. Instrument : Betty online Location : Vial 32

Injection Date : 09-Apr-10, 22:42:53 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\032B1903.D) 1.113 1.139 - Methane

 9.350

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.139 PB 5.49299e-1 3.55302 1.95167 Methane 

Totals : 1.95167

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\032B1903.D

Sample Name: R3 Ambient 0410-59

Betty Reprocess 4/16/2010 11:06:01 AM Page 1 of 1

EA# 0410-59 Page 33 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 20

Acq. Instrument : Betty online Location : Vial 17

Injection Date : 09-Apr-10, 23:00:51 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\017B2001.D)

 8.585

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.149 - - - Methane 

Totals : 0.00000

2 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\017B2001.D

Sample Name: He Blank

Betty Reprocess 4/16/2010 11:06:26 AM Page 1 of 2

EA# 0410-59 Page 34 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 20

Acq. Instrument : Betty online Location : Vial 17

Injection Date : 09-Apr-10, 23:19:19 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\017B2002.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.149 - - - Methane 

Totals : 0.00000

2 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\017B2002.D

Sample Name: He Blank

Betty Reprocess 4/16/2010 11:07:19 AM Page 1 of 2

EA# 0410-59 Page 35 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 20

Acq. Instrument : Betty online Location : Vial 17

Injection Date : 09-Apr-10, 23:37:01 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\017B2003.D)

 8.585

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.149 - - - Methane 

Totals : 0.00000

2 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\017B2003.D

Sample Name: He Blank

Betty Reprocess 4/16/2010 11:07:47 AM Page 1 of 2

EA# 0410-59 Page 36 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 25

Acq. Instrument : Gummo online Location : Vial 18

Injection Date : 25-Apr-10, 16:53:11 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

4

6

8

10

12

14

16

 FID2 B, (GC114P106\018B2501.D) 1.393 1.419 - Methane 1.552 1.865

 8.990

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.419 PB 1.62546 4.08661 6.64261 Methane 

Totals : 6.64261

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\018B2501.D

Sample Name: R1 Backup 0410-59

Gummo online 4/27/2010 9:24:11 AM stg Page 1 of 1

EA# 0410-59 Page 37 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 25

Acq. Instrument : Gummo online Location : Vial 18

Injection Date : 25-Apr-10, 17:08:47 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

4

6

8

10

12

14

16

 FID2 B, (GC114P106\018B2502.D) 1.394 1.420 - Methane 1.552

 8.988

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.420 PB 1.63528 4.08574 6.68131 Methane 

Totals : 6.68131

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\018B2502.D

Sample Name: R1 Backup 0410-59

Gummo online 4/27/2010 9:24:18 AM stg Page 1 of 1

EA# 0410-59 Page 38 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 25

Acq. Instrument : Gummo online Location : Vial 18

Injection Date : 25-Apr-10, 17:24:32 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

4

6

8

10

12

14

16

 FID2 B, (GC114P106\018B2503.D) 1.392 1.419 - Methane 1.552 1.863

 8.986

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.419 PB 1.55360 4.09330 6.35934 Methane 

Totals : 6.35934

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\018B2503.D

Sample Name: R1 Backup 0410-59

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EA# 0410-59 Page 39 of 225
Calibration 

Curve Chromatograms

EA# 0410-59 Page 40 of 225
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : 1/21/2010 9:48:15 AM

Rel. Reference Window : 2.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 2.000 %

Abs. Non-ref. Window : 0.200 min

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Quadratic (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: TCD1 A, 

Signal 2: FID2 B, 

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [%] 

-------|--|--|----------|----------|----------|---|--|---------------

 1.129 2 21 4.99000e-1 1.35402e-1 3.68533 Methane 

 22 1.99600 5.52639e-1 3.61176 

 23 9.98000 2.80187 3.56191 

 24 39.92000 11.06458 3.60791 

 25 99.80000 28.10567 3.55089 

 26 1020.00000 304.61028 3.34854 

 27 1.02000e4 2969.18937 3.43528 

More compound-specific settings:

Compound: Methane

 Time Window : From 1.049 min To 1.240 min

3 Warnings or Errors :

Warning : Overlapping peak time windows

Warning : Overlapping peak time windows

Warning : Curve requires more calibration points.

=====================================================================

 Peak Sum Table 

=====================================================================

Method G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

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EA# 0410-59 Page 41 of 225
Name StartTime EndTime Use Response Multiplier ISTD 

 [min] [min] Reference factor Peak 

----------|-------|-------|----------|--------|----------|-----------

as Ethane 1.200 1.700 None 2.2489 1.0000 None 

as Propane 1.700 3.750 None 1.5011 1.0000 None 

as Butane 3.750 5.700 None 1.1334 1.0000 None 

as Pentane 5.700 6.800 None 9.2380e-1 1.0000 None 

as Hexane 6.800 7.600 None 8.0371e-1 1.0000 None 

as Heptane 7.600 11.500 None 6.7616e-1 1.0000 None 

=====================================================================

=====================================================================

 Calibration Curves

=====================================================================

Amount[%]

0 5000 10000

Area

0

500

1000

1500

2000

2500

2123425

26

27

Methane at exp. RT: 1.129

FID2 B, 

Correlation: 0.99963

Residual Std. Dev.: 26.55855

Formula: y = mx + b

 m: 2.85428e-1 

 b: -7.76247e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.39332e-007

 Level 27 : 2.39332e-009

=====================================================================

Method G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

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EA# 0410-59 Page 42 of 225
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Monday, March 29, 2010 9:44:52 AM

Rel. Reference Window : 2.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 2.000 %

Abs. Non-ref. Window : 0.200 min

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Quadratic (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: TCD1 A, 

Signal 2: FID2 B, 

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [%] 

-------|--|--|----------|----------|----------|---|--|---------------

 0.811 1 91 8.50000e-1 4.44911 1.91049e-1 Hydrogen 

 92 4.25000 22.49751 1.88910e-1 

 93 8.50000 44.78257 1.89806e-1 

 1.129 2 21 4.99000e-1 1.35402e-1 3.68533 Methane 

 22 1.99600 5.52639e-1 3.61176 

 23 9.98000 2.80187 3.56191 

 24 39.92000 11.06458 3.60791 

 25 99.80000 28.10567 3.55089 

 26 1020.00000 304.61028 3.34854 

 27 1.02000e4 2969.18937 3.43528 

 1.354 2 21 4.99500e-1 2.47397e-1 2.01902 Ethane 

 22 1.99800 9.86084e-1 2.02620 

 23 9.99000 4.97993 2.00605 

 24 39.96000 19.68223 2.03026 

 25 99.90000 48.70662 2.05106 

 26 999.00000 528.59880 1.88990 

 27 9990.00000 5146.62077 1.94108 

 29 5.02000e4 2.51915e4 1.99274 

 2.130 2 21 4.99000e-1 3.61957e-1 1.37862 Propane 

 22 1.99600 1.52124 1.31209 

 23 9.98000 7.63784 1.30665 

 24 39.92000 30.00575 1.33041 

 25 99.80000 74.04200 1.34788 

 26 1002.00000 754.42265 1.32817 

 27 1.00200e4 7342.21875 1.36471 

 29 5.00000e4 3.80690e4 1.31340 

 3.403 1 8 1.98800e-1 75.06279 2.64845e-3 Oxygen 

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 43 of 225
RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [%] 

-------|--|--|----------|----------|----------|---|--|---------------

 4 9.94000e-1 370.93233 2.67973e-3 

 5 4.97000 1784.47870 2.78513e-3 

 6 9.94000 3885.63855 2.55814e-3 

 9 99.80000 3.74303e4 2.66629e-3 

 3.882 1 7 1.99600e-1 87.01833 2.29377e-3 Nitrogen 

 1 9.98000e-1 431.03604 2.31535e-3 

 2 4.99000 1973.00867 2.52913e-3 

 3 9.98000 4195.68652 2.37863e-3 

 9 100.00000 3.73785e4 2.67534e-3 

 4.772 2 21 5.00000e-1 5.05538e-1 9.89046e-1 Butane 

 22 2.00000 2.01181 9.94129e-1 

 23 10.00000 10.09618 9.90473e-1 

 24 40.00000 39.82943 1.00428 

 25 100.00000 98.24574 1.01786 

 26 999.00000 1029.92782 9.69971e-1 

 27 9990.00000 1.00171e4 9.97295e-1 

 5.160 1 7 2.02000e-1 92.56993 2.18213e-3 Carbon monoxide 

 1 1.01000 491.74663 2.05390e-3 

 2 5.05000 2208.96924 2.28613e-3 

 3 10.10000 4694.73730 2.15135e-3 

 9 99.00000 4.27557e4 2.31548e-3 

 6.364 2 21 4.94500e-1 6.07755e-1 8.13650e-1 Pentane 

 22 1.97800 2.49617 7.92415e-1 

 23 9.89000 12.44353 7.94791e-1 

 24 39.56000 48.97281 8.07795e-1 

 25 98.90000 120.68393 8.19496e-1 

 28 801.60000 1016.57615 7.88529e-1 

 29 2004.00000 2538.43888 7.89462e-1 

 7.281 2 21 5.15000e-1 7.44320e-1 6.91907e-1 Hexane 

 22 2.06000 2.99670 6.87422e-1 

 23 10.30000 15.01502 6.85980e-1 

 24 41.20000 59.00752 6.98216e-1 

 25 103.00000 145.23974 7.09172e-1 

 28 399.20000 604.13151 6.60783e-1 

 29 998.00000 1507.32475 6.62100e-1 

 7.472 1 7 1.61200e-1 69.03885 2.33492e-3 Methane 

 1 8.06000e-1 352.93555 2.28370e-3 

 2 4.03000 1585.03979 2.54252e-3 

 3 8.06000 3351.48865 2.40490e-3 

 9 99.00000 3.77759e4 2.62072e-3 

 7.964 2 21 4.85000e-1 7.89600e-1 6.14235e-1 Heptane 

 22 1.94000 3.23543 5.99611e-1 

 23 9.70000 16.20249 5.98673e-1 

 24 38.80000 63.69198 6.09182e-1 

 25 97.00000 156.62639 6.19308e-1 

 28 200.16000 354.62990 5.64419e-1 

 29 500.40000 883.83154 5.66171e-1 

 9.274 1 8 1.98800e-1 204.00780 9.74473e-4 Carbon dioxide 

 4 9.94000e-1 738.14764 1.34661e-3 

 5 4.97000 3153.63171 1.57596e-3 

 6 9.94000 7070.64453 1.40581e-3 

 9 99.80000 6.87727e4 1.45116e-3 

More compound-specific settings:

Compound: Methane

 Time Window : From 1.049 min To 1.240 min

Compound: Oxygen

 Time Window : From 3.102 min To 3.820 min

Compound: Nitrogen

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 44 of 225
 Time Window : From 3.386 min To 4.557 min

Compound: Carbon monoxide

 Time Window : From 4.674 min To 5.614 min

Compound: Methane

 Time Window : From 7.076 min To 7.647 min

Compound: Heptane

 Time Window : From 7.921 min To 8.031 min

Compound: Carbon dioxide

 Time Window : From 8.911 min To 9.612 min

2 Warnings or Errors :

Warning : Overlapping peak time windows at 3.403 min, signal 1

Warning : Overlapping peak time windows at 1.129 min, signal 2

=====================================================================

 Peak Sum Table 

=====================================================================

Name StartTime EndTime Use Response Multiplier ISTD 

 [min] [min] Reference factor Peak 

----------|-------|-------|----------|--------|----------|-----------

as Ethane 1.200 1.630 None 2.2489 1.0000 None 

as Propane 1.630 3.450 None 1.5011 1.0000 None 

as Butane 3.450 5.570 None 1.1334 1.0000 None 

as Pentane 5.570 6.580 None 9.2380e-1 1.0000 None 

as Hexane 6.820 7.630 None 8.0371e-1 1.0000 None 

as Heptane 7.630 11.500 None 6.7616e-1 1.0000 None 

=====================================================================

=====================================================================

 Calibration Curves

=====================================================================

Amount[%]

0 5

Area

0

5

10

15

20

25

30

35

40

91

92

93

Hydrogen at exp. RT: 0.811

TCD1 A, 

Correlation: 0.99999

Residual Std. Dev.: 0.13854

Formula: y = mx + b

 m: 5.28793

 b: -4.41224e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 91 : 1

 Level 92 : 0.04

 Level 93 : 0.01

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 45 of 225
Amount[%]

0 5000 10000

Area

0

500

1000

1500

2000

2500

2123425

26

27

Methane at exp. RT: 1.129

FID2 B, 

Correlation: 0.99963

Residual Std. Dev.: 26.55855

Formula: y = mx + b

 m: 2.85428e-1 

 b: -7.76247e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.39332e-007

 Level 27 : 2.39332e-009

Amount[%]

0 20000 40000

Area

0

5000

10000

15000

20000

25000

21234526

27

29

Ethane at exp. RT: 1.354

FID2 B, 

Correlation: 0.99961

Residual Std. Dev.: 58.82996

Formula: y = mx + b

 m: 5.03398e-1 

 b: -5.16788e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.5e-007

 Level 27 : 2.5e-009

 Level 29 : 9.90065e-011

Amount[%]

0 20000 40000

Area

0

5000

10000

15000

20000

25000

30000

35000

21234526

27

29

Propane at exp. RT: 2.130

FID2 B, 

Correlation: 0.99986

Residual Std. Dev.: 189.74265

Formula: y = mx + b

 m: 7.53020e-1 

 b: -1.16335e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.48008e-007

 Level 27 : 2.48008e-009

 Level 29 : 9.96004e-011

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 46 of 225
Amount[%]

0 50 100

Area

0

5000

10000

15000

20000

25000

30000

35000

845

6

9

Oxygen at exp. RT: 3.403

TCD1 A, 

Correlation: 0.99947

Residual Std. Dev.: 107.48919

Formula: y = mx + b

 m: 374.55904

 b: 4.67522e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 8 : 1

 Level 4 : 0.04

 Level 5 : 0.0016

 Level 6 : 0.0004

 Level 9 : 3.968e-006

Amount[%]

0 50 100

Area

0

5000

10000

15000

20000

25000

30000

35000

712

3

9

Nitrogen at exp. RT: 3.882

TCD1 A, 

Correlation: 0.99849

Residual Std. Dev.: 1620.60813

Formula: y = mx + b

 m: 401.71654

 b: 7.72898

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

 Level 9 : 3.98402e-006

Amount[%]

0 5000 10000

Area

0

2000

4000

6000

8000

2123425

26

27

Butane at exp. RT: 4.772

FID2 B, 

Correlation: 0.99988

Residual Std. Dev.: 13.69326

Formula: y = mx + b

 m: 1.00419

 b: 3.46686e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.50501e-007

 Level 27 : 2.50501e-009

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 47 of 225
Amount[%]

0 50 100

Area

0

5000

10000

15000

20000

25000

30000

35000

40000

71 2

3

9

Carbon monoxide at exp. RT: 5.160

TCD1 A, 

Correlation: 0.99869

Residual Std. Dev.: 1214.92684

Formula: y = mx + b

 m: 453.05780

 b: 2.23707

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

 Level 9 : 4.16325e-006

Amount[%]

0 1000 2000

Area

0

500

1000

1500

2000

212232425

28

29

Pentane at exp. RT: 6.364

FID2 B, 

Correlation: 0.99988

Residual Std. Dev.: 13.81622

Formula: y = mx + b

 m: 1.25267

 b: -9.92474e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 28 : 3.80555e-007

 Level 29 : 6.08888e-008

Amount[%]

0 500 1000

Area

0

200

400

600

800

1000

1200

1400

2122324

25

28

29

Hexane at exp. RT: 7.281

FID2 B, 

Correlation: 0.99963

Residual Std. Dev.: 22.37468

Formula: y = mx + b

 m: 1.46455

 b: -1.09537e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 28 : 1.66431e-006

 Level 29 : 2.66289e-007

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 48 of 225
Amount[%]

0 50 100

Area

0

5000

10000

15000

20000

25000

30000

35000

712 3

9

Methane at exp. RT: 7.472

TCD1 A, 

Correlation: 0.99861

Residual Std. Dev.: 1278.41168

Formula: y = mx + b

 m: 403.86769

 b: 4.79529

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

 Level 9 : 2.6513e-006

Amount[%]

0 200 400

Area

0

100

200

300

400

500

600

700

800

21223

24

25

28

29

Heptane at exp. RT: 7.964

FID2 B, 

Correlation: 0.99933

Residual Std. Dev.: 18.19609

Formula: y = mx + b

 m: 1.69302

 b: -3.33323e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 28 : 5.87123e-006

 Level 29 : 9.39396e-007

Amount[%]

0 50 100

Area

0

10000

20000

30000

40000

50000

60000

845

6

9

Carbon dioxide at exp. RT: 9.274

TCD1 A, 

Correlation: 0.99873

Residual Std. Dev.: 998.51238

Formula: y = mx + b

 m: 671.57245

 b: 70.24338

 x: Amount

 y: Area

Calibration Level Weights:

 Level 8 : 1

 Level 4 : 0.04

 Level 5 : 0.0016

 Level 6 : 0.0004

 Level 9 : 3.968e-006

=====================================================================

Method G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

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EA# 0410-59 Page 49 of 225
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : 1/13/2010 10:14:02 PM

Rel. Reference Window : 2.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 2.000 %

Abs. Non-ref. Window : 0.200 min

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Quadratic (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: TCD1 A, 

Signal 2: FID2 B, 

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [%] 

-------|--|--|----------|----------|----------|---|--|---------------

 0.840 1 7 1.70000e-1 1.42436 1.19351e-1 Hydrogen 

 1 8.50000e-1 8.97445 9.47133e-2 

 2 4.25000 49.19996 8.63822e-2 

 3 8.50000 104.72226 8.11671e-2 

 1.129 2 21 4.99000e-1 1.35402e-1 3.68533 Methane 

 22 1.99600 5.52639e-1 3.61176 

 23 9.98000 2.80187 3.56191 

 24 39.92000 11.06458 3.60791 

 25 99.80000 28.10567 3.55089 

 26 1020.00000 304.61028 3.34854 

 27 1.02000e4 2969.18937 3.43528 

 1.354 2 21 4.99500e-1 2.47397e-1 2.01902 Ethane 

 22 1.99800 9.86084e-1 2.02620 

 23 9.99000 4.97993 2.00605 

 24 39.96000 19.68223 2.03026 

 25 99.90000 48.70662 2.05106 

 26 999.00000 528.59880 1.88990 

 27 9990.00000 5146.62077 1.94108 

 29 5.02000e4 2.51915e4 1.99274 

 2.130 2 21 4.99000e-1 3.61957e-1 1.37862 Propane 

 22 1.99600 1.52124 1.31209 

 23 9.98000 7.63784 1.30665 

 24 39.92000 30.00575 1.33041 

 25 99.80000 74.04200 1.34788 

 26 1002.00000 754.42265 1.32817 

 27 1.00200e4 7342.21875 1.36471 

 29 5.00000e4 3.80690e4 1.31340 

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

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EA# 0410-59 Page 50 of 225
RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [%] 

-------|--|--|----------|----------|----------|---|--|---------------

 2.783 1 8 1.98800e-1 91.55111 2.17146e-3 Oxygen 

 4 9.94000e-1 406.03781 2.44805e-3 

 5 4.97000 2054.37500 2.41923e-3 

 6 9.94000 4202.69116 2.36515e-3 

 9 99.80000 4.40149e4 2.26741e-3 

 3.410 1 7 1.99600e-1 110.10318 1.81284e-3 Nitrogen 

 1 9.98000e-1 451.79161 2.20898e-3 

 2 4.99000 2246.56348 2.22117e-3 

 3 9.98000 4561.85718 2.18771e-3 

 9 100.00000 4.71263e4 2.12196e-3 

 4.772 2 21 5.00000e-1 5.05538e-1 9.89046e-1 Butane 

 22 2.00000 2.01181 9.94129e-1 

 23 10.00000 10.09618 9.90473e-1 

 24 40.00000 39.82943 1.00428 

 25 100.00000 98.24574 1.01786 

 26 999.00000 1029.92782 9.69971e-1 

 27 9990.00000 1.00171e4 9.97295e-1 

 4.902 1 7 2.02000e-1 103.03305 1.96054e-3 Carbon monoxide 

 1 1.01000 491.75664 2.05386e-3 

 2 5.05000 2451.79663 2.05971e-3 

 3 10.10000 4965.58472 2.03400e-3 

 9 99.00000 5.46482e4 1.81159e-3 

 6.364 2 21 4.94500e-1 6.07755e-1 8.13650e-1 Pentane 

 22 1.97800 2.49617 7.92415e-1 

 23 9.89000 12.44353 7.94791e-1 

 24 39.56000 48.97281 8.07795e-1 

 25 98.90000 120.68393 8.19496e-1 

 28 801.60000 1016.57615 7.88529e-1 

 29 2004.00000 2538.43888 7.89462e-1 

 7.281 2 21 5.15000e-1 7.44320e-1 6.91907e-1 Hexane 

 22 2.06000 2.99670 6.87422e-1 

 23 10.30000 15.01502 6.85980e-1 

 24 41.20000 59.00752 6.98216e-1 

 25 103.00000 145.23974 7.09172e-1 

 28 399.20000 604.13151 6.60783e-1 

 29 998.00000 1507.32475 6.62100e-1 

 7.286 1 7 1.61200e-1 78.56514 2.05180e-3 Methane 

 1 8.06000e-1 364.52043 2.21112e-3 

 2 4.03000 1802.08862 2.23629e-3 

 3 8.06000 3648.10791 2.20936e-3 

 9 99.00000 4.90459e4 2.01852e-3 

 7.964 2 21 4.85000e-1 7.89600e-1 6.14235e-1 Heptane 

 22 1.94000 3.23543 5.99611e-1 

 23 9.70000 16.20249 5.98673e-1 

 24 38.80000 63.69198 6.09182e-1 

 25 97.00000 156.62639 6.19308e-1 

 28 200.16000 354.62990 5.64419e-1 

 29 500.40000 883.83154 5.66171e-1 

 8.950 1 8 1.98800e-1 159.71481 1.24472e-3 Carbon dioxide 

 4 9.94000e-1 769.09738 1.29242e-3 

 5 4.97000 3827.61816 1.29846e-3 

 6 9.94000 7677.67896 1.29466e-3 

 9 99.80000 8.26574e4 1.20739e-3 

More compound-specific settings:

Compound: Methane

 Time Window : From 1.049 min To 1.240 min

Compound: Oxygen

 Time Window : From 2.482 min To 3.200 min

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

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EA# 0410-59 Page 51 of 225
Compound: Nitrogen

 Time Window : From 2.914 min To 4.085 min

Compound: Carbon monoxide

 Time Window : From 4.416 min To 5.356 min

Compound: Methane

 Time Window : From 6.890 min To 7.461 min

Compound: Heptane

 Time Window : From 7.921 min To 8.031 min

Compound: Carbon dioxide

 Time Window : From 8.587 min To 9.288 min

2 Warnings or Errors :

Warning : Overlapping peak time windows at 2.783 min, signal 1

Warning : Overlapping peak time windows at 1.129 min, signal 2

=====================================================================

 Peak Sum Table 

=====================================================================

Name StartTime EndTime Use Response Multiplier ISTD 

 [min] [min] Reference factor Peak 

----------|-------|-------|----------|--------|----------|-----------

as Ethane 1.200 1.700 None 2.2489 1.0000 None 

as Propane 1.700 3.750 None 1.5011 1.0000 None 

as Butane 3.750 5.700 None 1.1334 1.0000 None 

as Pentane 5.700 6.800 None 9.2380e-1 1.0000 None 

as Hexane 6.800 7.600 None 8.0371e-1 1.0000 None 

as Heptane 7.600 11.500 None 6.7616e-1 1.0000 None 

=====================================================================

=====================================================================

 Calibration Curves

=====================================================================

Amount[%]

0 5

Area

0

20

40

60

80

7

1

2

3

Hydrogen at exp. RT: 0.840

TCD1 A, 

Correlation: 0.99906

Residual Std. Dev.: 3.41864

Formula: y = mx + b

 m: 11.82797

 b: -6.04222e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 3 of 7

EA# 0410-59 Page 52 of 225
Amount[%]

0 5000 10000

Area

0

500

1000

1500

2000

2500

2123425

26

27

Methane at exp. RT: 1.129

FID2 B, 

Correlation: 0.99963

Residual Std. Dev.: 26.55855

Formula: y = mx + b

 m: 2.85428e-1 

 b: -7.76247e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.39332e-007

 Level 27 : 2.39332e-009

Amount[%]

0 20000 40000

Area

0

5000

10000

15000

20000

25000

21234526

27

29

Ethane at exp. RT: 1.354

FID2 B, 

Correlation: 0.99961

Residual Std. Dev.: 58.82996

Formula: y = mx + b

 m: 5.03398e-1 

 b: -5.16788e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.5e-007

 Level 27 : 2.5e-009

 Level 29 : 9.90065e-011

Amount[%]

0 20000 40000

Area

0

5000

10000

15000

20000

25000

30000

35000

21234526

27

29

Propane at exp. RT: 2.130

FID2 B, 

Correlation: 0.99986

Residual Std. Dev.: 189.74265

Formula: y = mx + b

 m: 7.53020e-1 

 b: -1.16335e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.48008e-007

 Level 27 : 2.48008e-009

 Level 29 : 9.96004e-011

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

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EA# 0410-59 Page 53 of 225
Amount[%]

0 50 100

Area

0

5000

10000

15000

20000

25000

30000

35000

40000

845

6

9

Oxygen at exp. RT: 2.783

TCD1 A, 

Correlation: 0.99928

Residual Std. Dev.: 1205.98664

Formula: y = mx + b

 m: 420.03402

 b: 7.25096

 x: Amount

 y: Area

Calibration Level Weights:

 Level 8 : 1

 Level 4 : 0.04

 Level 5 : 0.0016

 Level 6 : 0.0004

 Level 9 : 3.968e-006

Amount[%]

0 50 100

Area

0

5000

10000

15000

20000

25000

30000

35000

40000

712

3

9

Nitrogen at exp. RT: 3.410

TCD1 A, 

Correlation: 0.99947

Residual Std. Dev.: 1068.40967

Formula: y = mx + b

 m: 452.57273

 b: 18.98391

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

 Level 9 : 3.98402e-006

Amount[%]

0 5000 10000

Area

0

2000

4000

6000

8000

2123425

26

27

Butane at exp. RT: 4.772

FID2 B, 

Correlation: 0.99988

Residual Std. Dev.: 13.69326

Formula: y = mx + b

 m: 1.00419

 b: 3.46686e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 26 : 2.50501e-007

 Level 27 : 2.50501e-009

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

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EA# 0410-59 Page 54 of 225
Amount[%]

0 50 100

Area

0

10000

20000

30000

40000

71 2

3

9 Carbon monoxide at exp. RT: 4.902

TCD1 A, 

Correlation: 0.99824

Residual Std. Dev.: 2679.96469

Formula: y = mx + b

 m: 505.14582

 b: 5.95181e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

 Level 9 : 4.16325e-006

Amount[%]

0 1000 2000

Area

0

500

1000

1500

2000

212232425

28

29

Pentane at exp. RT: 6.364

FID2 B, 

Correlation: 0.99988

Residual Std. Dev.: 13.81622

Formula: y = mx + b

 m: 1.25267

 b: -9.92474e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 28 : 3.80555e-007

 Level 29 : 6.08888e-008

Amount[%]

0 500 1000

Area

0

200

400

600

800

1000

1200

1400

2122324

25

28

29

Hexane at exp. RT: 7.281

FID2 B, 

Correlation: 0.99963

Residual Std. Dev.: 22.37468

Formula: y = mx + b

 m: 1.46455

 b: -1.09537e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 28 : 1.66431e-006

 Level 29 : 2.66289e-007

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

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EA# 0410-59 Page 55 of 225
Amount[%]

0 50 100

Area

0

10000

20000

30000

40000

712 3

9 Methane at exp. RT: 7.286

TCD1 A, 

Correlation: 0.99887

Residual Std. Dev.: 1952.10846

Formula: y = mx + b

 m: 461.23641

 b: 3.66109

 x: Amount

 y: Area

Calibration Level Weights:

 Level 7 : 1

 Level 1 : 0.04

 Level 2 : 0.0016

 Level 3 : 0.0004

 Level 9 : 2.6513e-006

Amount[%]

0 200 400

Area

0

100

200

300

400

500

600

700

800

21223

24

25

28

29

Heptane at exp. RT: 7.964

FID2 B, 

Correlation: 0.99933

Residual Std. Dev.: 18.19609

Formula: y = mx + b

 m: 1.69302

 b: -3.33323e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.0625

 Level 23 : 0.0025

 Level 24 : 0.000156

 Level 25 : 0.000025

 Level 28 : 5.87123e-006

 Level 29 : 9.39396e-007

Amount[%]

0 50 100

Area

0

10000

20000

30000

40000

50000

60000

70000

845

6

9

Carbon dioxide at exp. RT: 8.950

TCD1 A, 

Correlation: 0.99942

Residual Std. Dev.: 2420.17771

Formula: y = mx + b

 m: 786.23340

 b: 2.63777

 x: Amount

 y: Area

Calibration Level Weights:

 Level 8 : 1

 Level 4 : 0.04

 Level 5 : 0.0016

 Level 6 : 0.0004

 Level 9 : 3.968e-006

=====================================================================

Method G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Betty Reprocess 1/13/2010 10:42:23 PM Page 7 of 7

EA# 0410-59 Page 56 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 16:38:18 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 4:38:10 PM by JBB

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1601.D)

 Area: 1.33676 0.844 - Hydrogen

 3.560 - Nitrogen

 4.904 - Carbon monoxide

 7.288 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.844 MM 1.33676 1.20865e-1 1.61567e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.560 BB 145.15636 1.92061e-3 2.78789e-1 Nitrogen 

 4.904 BB 103.72206 1.97849e-3 2.05213e-1 Carbon monoxide 

 7.288 BB 79.22163 2.06789e-3 1.63822e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 8.09391e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1601.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:30:44 PM Page 1 of 2

EA# 0410-59 Page 57 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 17:01:16 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 4:45:00 PM

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1602.D)

 Area: 1.41738 0.831 - Hydrogen

 3.558 - Nitrogen

 4.903 - Carbon monoxide

 7.287 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.831 MM 1.41738 1.20587e-1 1.70917e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.558 BB 112.10709 1.83542e-3 2.05764e-1 Nitrogen 

 4.903 BB 104.80928 1.97850e-3 2.07365e-1 Carbon monoxide 

 7.287 BB 79.58950 2.06835e-3 1.64619e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 7.48666e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1602.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:30:49 PM Page 1 of 2

EA# 0410-59 Page 58 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 17:24:05 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 5:03:52 PM

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1603.D)

 Area: 1.43135 0.844 - Hydrogen

 3.556 - Nitrogen

 4.902 - Carbon monoxide

 7.286 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.844 MM 1.43135 1.20235e-1 1.72098e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.556 BB 108.09927 1.82588e-3 1.97376e-1 Nitrogen 

 4.902 BB 101.25681 1.97847e-3 2.00334e-1 Carbon monoxide 

 7.286 BB 77.54078 2.06634e-3 1.60225e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 7.30033e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1603.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:30:55 PM Page 1 of 2

EA# 0410-59 Page 59 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 17:46:51 Inj : 4

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 5:34:42 PM

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1604.D)

 Area: 1.43696 0.821 - Hydrogen

 3.544 - Nitrogen

 4.894 - Carbon monoxide

 7.284 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.821 MM 1.43696 1.20096e-1 1.72572e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.544 BB 104.50573 1.82588e-3 1.90814e-1 Nitrogen 

 4.894 BB 99.28066 1.97847e-3 1.96424e-1 Carbon monoxide 

 7.284 BB 75.62451 2.06634e-3 1.56266e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 7.16077e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1604.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:00 PM Page 1 of 2

EA# 0410-59 Page 60 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 18:09:38 Inj : 5

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 5:45:59 PM

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1605.D)

 Area: 1.2991 0.846 - Hydrogen

 3.564 - Nitrogen

 4.906 - Carbon monoxide

 7.286 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.846 MM 1.29910 1.20865e-1 1.57015e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.564 BB 110.33025 1.82940e-3 2.01838e-1 Nitrogen 

 4.906 BB 103.93967 1.97849e-3 2.05644e-1 Carbon monoxide 

 7.286 BB 79.14066 2.06779e-3 1.63646e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 7.28143e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1605.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:06 PM Page 1 of 2

EA# 0410-59 Page 61 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 18:32:27 Inj : 6

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 6:09:24 PM

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1606.D)

 Area: 1.35459 0.862 - Hydrogen

 3.581 - Nitrogen

 4.915 - Carbon monoxide

 7.288 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.862 MM 1.35459 1.20865e-1 1.63722e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.581 BB 113.53730 1.84014e-3 2.08924e-1 Nitrogen 

 4.915 BB 106.72567 1.97852e-3 2.11159e-1 Carbon monoxide 

 7.288 BB 81.08928 2.07020e-3 1.67871e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 7.51676e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1606.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:11 PM Page 1 of 2

EA# 0410-59 Page 62 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 16

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 19:27:12 Inj : 7

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 7:16:24 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

25 uV

-30

-20

-10

0

10

20

30

40

 TCD1 A, (GC110P104\012F1607.D)

 Area: 1.54166 0.803 - Hydrogen

 3.534 - Nitrogen

 4.889 - Carbon monoxide

 7.283 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.803 MM 1.54166 1.17681e-1 1.81424e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.534 BB 101.67350 1.82588e-3 1.85643e-1 Nitrogen 

 4.889 BB 98.01877 1.97847e-3 1.93927e-1 Carbon monoxide 

 7.283 BB 74.91630 2.06634e-3 1.54802e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 7.15797e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1607.D

Sample Name: gc110p104 #FG7 ENV(1=692.53,2=16.77)

Instrument 3 1/14/2010 4:31:17 PM Page 1 of 2

EA# 0410-59 Page 63 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 3

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 00:26:09 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

80

 TCD1 A, (GC110P104\012F0301.D) 0.787 - Hydrogen 3.513 - Nitrogen

 4.869 - Carbon monoxide

 7.273 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.787 BB 8.93214 9.02645e-2 8.06255e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.513 BB 451.74521 2.11673e-3 9.56225e-1 Nitrogen 

 4.869 BB 491.77716 1.97939e-3 9.73417e-1 Carbon monoxide 

 7.273 BB 364.50925 2.14631e-3 7.82350e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 3.51825

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0301.D

Sample Name: gc110p104 #FG1 ENV(1=636,2=83.86)

Betty Reprocess 1/12/2010 6:26:25 PM Page 1 of 2

EA# 0410-59 Page 64 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 3

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 00:50:03 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

80

 TCD1 A, (GC110P104\012F0302.D) 0.786 - Hydrogen 3.513 - Nitrogen

 4.870 - Carbon monoxide

 7.273 - Methane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.786 BB 9.01676 9.02108e-2 8.13410e-1 Hydrogen 

 2.783 - - - Oxygen 

 3.513 BB 451.83801 2.11675e-3 9.56430e-1 Nitrogen 

 4.870 BB 491.73611 1.97939e-3 9.73336e-1 Carbon monoxide 

 7.273 BB 364.53162 2.14631e-3 7.82398e-1 Methane 

 8.950 - - - Carbon dioxide 

Totals : 3.52557

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0302.D

Sample Name: gc110p104 #FG1 ENV(1=636,2=83.86)

Betty Reprocess 1/12/2010 6:26:34 PM Page 1 of 2

EA# 0410-59 Page 65 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 2

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 07-Jan-10, 23:11:22 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 11:12:17 PM by JBB

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-50

0

50

100

150

200

250

300

 TCD1 A, (GC110P104\012F0201.D) 0.786 - Hydrogen 3.476 - Nitrogen

 4.834 - Carbon monoxide

 7.245 - Methane

 9.104 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.786 BB 49.16809 8.55843e-2 4.20802 Hydrogen 

 2.783 - - - Oxygen 

 3.476 BB 2244.57520 2.19090e-3 4.91764 Nitrogen 

 4.834 BB 2452.32544 1.97958e-3 4.85457 Carbon monoxide 

 7.245 BB 1802.24854 2.16368e-3 3.89949 Methane 

 9.104 BB 8.13546 1.25078e-3 1.01757e-2 Carbon dioxide 

Totals : 17.88990

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0201.D

Sample Name: gc110p104 #FG2 ENV(1=318,2=377.39)

Betty Reprocess 1/12/2010 6:25:56 PM Page 1 of 2

EA# 0410-59 Page 66 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 2

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 07-Jan-10, 23:35:25 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 11:12:17 PM by JBB

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-50

0

50

100

150

200

250

300

 TCD1 A, (GC110P104\012F0202.D) 0.784 - Hydrogen 3.475 - Nitrogen

 4.833 - Carbon monoxide

 7.244 - Methane

 9.103 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.784 BB 49.23183 8.55830e-2 4.21341 Hydrogen 

 2.783 - - - Oxygen 

 3.475 BB 2248.55176 2.19093e-3 4.92643 Nitrogen 

 4.833 BB 2451.26782 1.97958e-3 4.85248 Carbon monoxide 

 7.244 BB 1801.92871 2.16368e-3 3.89880 Methane 

 9.103 BB 7.57725 1.25078e-3 9.47747e-3 Carbon dioxide 

Totals : 17.90059

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0202.D

Sample Name: gc110p104 #FG2 ENV(1=318,2=377.39)

Betty Reprocess 1/12/2010 6:26:04 PM Page 1 of 2

EA# 0410-59 Page 67 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 1

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 07-Jan-10, 21:58:46 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:58:39 PM by JBB

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

100

200

300

400

500

 TCD1 A, (GC110P104\012F0101.D) 0.786 - Hydrogen 3.441 - Nitrogen

 4.798 - Carbon monoxide

 7.217 - Methane

 9.098 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.786 BB 104.96503 8.50321e-2 8.92539 Hydrogen 

 2.783 - - - Oxygen 

 3.441 BB 4581.13867 2.20043e-3 10.08049 Nitrogen 

 4.798 BB 4986.64502 1.97960e-3 9.87158 Carbon monoxide 

 7.217 BB 3661.30444 2.16592e-3 7.93008 Methane 

 9.098 BB 15.16464 1.25078e-3 1.89676e-2 Carbon dioxide 

Totals : 36.82651

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0101.D

Sample Name: gc110p104 #FG3 ENV(1=0,2=377.39)

Betty Reprocess 1/12/2010 6:25:14 PM Page 1 of 2

EA# 0410-59 Page 68 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 1

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 07-Jan-10, 22:23:00 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:58:39 PM by JBB

 (modified after loading)

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

100

200

300

400

500

 TCD1 A, (GC110P104\012F0102.D) 0.784 - Hydrogen 3.436 - Nitrogen

 4.796 - Carbon monoxide

 7.215 - Methane

 9.098 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.784 BB 104.47949 8.50343e-2 8.88434 Hydrogen 

 2.783 - - - Oxygen 

 3.436 BB 4542.57568 2.20036e-3 9.99528 Nitrogen 

 4.796 BB 4944.52441 1.97960e-3 9.78819 Carbon monoxide 

 7.215 BB 3634.91138 2.16590e-3 7.87286 Methane 

 9.098 BB 13.99536 1.25078e-3 1.75051e-2 Carbon dioxide 

Totals : 36.55818

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0102.D

Sample Name: gc110p104 #FG3 ENV(1=0,2=377.39)

Betty Reprocess 1/12/2010 6:25:39 PM Page 1 of 2

EA# 0410-59 Page 69 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 19:49:58 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 7:16:24 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1701.D) 3.124 - Oxygen 3.548 - Nitrogen

 7.286 - Methane

 9.101 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.124 BB 92.88748 2.19491e-3 2.03880e-1 Oxygen 

 3.548 BB 23.51696 1.82588e-3 4.29390e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 BB 5.73110 2.06634e-3 1.18424e-2 Methane 

 9.101 BB 157.23827 1.25078e-3 1.96670e-1 Carbon dioxide 

Totals : 4.55332e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1701.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:55:27 PM Page 1 of 2

EA# 0410-59 Page 70 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 20:12:36 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 7:16:24 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1702.D) 3.134 - Oxygen 3.558 - Nitrogen

 9.102 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.134 BB 90.21473 2.19054e-3 1.97619e-1 Oxygen 

 3.558 BB 15.57372 1.82588e-3 2.84357e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.102 BB 162.19136 1.25120e-3 2.02934e-1 Carbon dioxide 

Totals : 4.28989e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1702.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:03 PM Page 1 of 2

EA# 0410-59 Page 71 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 20:58:03 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 8:47:38 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1703.D) 3.142 - Oxygen 3.567 - Nitrogen

 9.100 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.142 BB 86.68782 2.19054e-3 1.89893e-1 Oxygen 

 3.567 BB 14.82982 1.82588e-3 2.70774e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.100 BB 168.58168 1.25199e-3 2.11062e-1 Carbon dioxide 

Totals : 4.28033e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1703.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:11 PM Page 1 of 2

EA# 0410-59 Page 72 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 21:20:40 Inj : 4

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 8:47:38 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1704.D) 3.138 - Oxygen 3.565 - Nitrogen

 9.098 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.138 BB 86.56775 2.19054e-3 1.89630e-1 Oxygen 

 3.565 BB 13.95775 1.82588e-3 2.54851e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.098 BB 167.37762 1.25184e-3 2.09530e-1 Carbon dioxide 

Totals : 4.24646e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1704.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:19 PM Page 1 of 2

EA# 0410-59 Page 73 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 21:43:19 Inj : 5

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 8:47:38 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

0 2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1705.D) 3.160 - Oxygen 3.585 - Nitrogen

 9.099 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.160 BB 89.77115 2.19054e-3 1.96648e-1 Oxygen 

 3.585 BB 14.05143 1.82588e-3 2.56562e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.099 BB 174.80219 1.25269e-3 2.18974e-1 Carbon dioxide 

Totals : 4.41277e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1705.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:28 PM Page 1 of 2

EA# 0410-59 Page 74 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 22:05:57 Inj : 6

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 8:47:38 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1706.D) 3.142 - Oxygen 3.568 - Nitrogen

 9.100 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.142 BB 88.20757 2.19054e-3 1.93223e-1 Oxygen 

 3.568 BB 13.20723 1.82588e-3 2.41148e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.100 BB 171.04898 1.25227e-3 2.14200e-1 Carbon dioxide 

Totals : 4.31537e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1706.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:36 PM Page 1 of 2

EA# 0410-59 Page 75 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 17

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 22:32:23 Inj : 7

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 11:55:20 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F1707.D) 3.142 - Oxygen 3.570 - Nitrogen

 9.099 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 11:55:08 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.142 BB 88.74271 2.19054e-3 1.94395e-1 Oxygen 

 3.570 BB 12.88785 1.82588e-3 2.35316e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.099 BB 171.22386 1.25229e-3 2.14422e-1 Carbon dioxide 

Totals : 4.32349e-1

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F1707.D

Sample Name: gc110p104 #FG8 ENV(1=692.53,3=15.94)

Betty Reprocess 1/12/2010 11:56:44 PM Page 1 of 2

EA# 0410-59 Page 76 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 6

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 04:09:45 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-25

0

25

50

75

100

125

150

 TCD1 A, (GC110P104\012F0601.D) 3.098 - Oxygen 3.525 - Nitrogen

 9.085 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.098 BB 406.26132 2.33827e-3 9.49948e-1 Oxygen 

 3.525 BB 7.74942 1.82588e-3 1.41495e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.085 BB 769.99377 1.26753e-3 9.75990e-1 Carbon dioxide 

Totals : 1.94009

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0601.D

Sample Name: gc110p104 #FG4 ENV(1=636,3=79.71)

Betty Reprocess 1/12/2010 6:27:42 PM Page 1 of 2

EA# 0410-59 Page 77 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 6

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 04:33:25 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-25

0

25

50

75

100

125

150

 TCD1 A, (GC110P104\012F0602.D) 3.096 - Oxygen 3.521 - Nitrogen

 9.086 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.096 BB 405.81430 2.33822e-3 9.48883e-1 Oxygen 

 3.521 BB 5.81061 1.82588e-3 1.06095e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.086 BB 768.20099 1.26752e-3 9.73710e-1 Carbon dioxide 

Totals : 1.93320

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0602.D

Sample Name: gc110p104 #FG4 ENV(1=636,3=79.71)

Betty Reprocess 1/12/2010 6:27:50 PM Page 1 of 2

EA# 0410-59 Page 78 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 5

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 02:58:25 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

100

200

300

400

500

600

 TCD1 A, (GC110P104\012F0501.D) 3.071 - Oxygen

 9.044 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.071 BB 2052.44409 2.37235e-3 4.86911 Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.044 BB 3824.38086 1.27101e-3 4.86083 Carbon dioxide 

Totals : 9.72994

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0501.D

Sample Name: gc110p104 #FG5 ENV(1=318.2,3=358.71)

Betty Reprocess 1/12/2010 6:27:18 PM Page 1 of 2

EA# 0410-59 Page 79 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 5

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 03:22:16 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

100

200

300

400

500

600

 TCD1 A, (GC110P104\012F0502.D) 3.073 - Oxygen

 9.045 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.073 BB 2056.30591 2.37236e-3 4.87831 Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.045 BB 3830.85547 1.27101e-3 4.86906 Carbon dioxide 

Totals : 9.74737

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0502.D

Sample Name: gc110p104 #FG5 ENV(1=318.2,3=358.71)

Betty Reprocess 1/12/2010 6:27:26 PM Page 1 of 2

EA# 0410-59 Page 80 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 4

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 01:37:30 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

200

400

600

800

1000

 TCD1 A, (GC110P104\012F0401.D) 3.038 - Oxygen 3.507 - Nitrogen

 4.892 - Carbon monoxide

 7.282 - Methane

 9.008 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.038 BV 4226.03662 2.37667e-3 10.04391 Oxygen 

 3.507 VB 138.33720 1.90637e-3 2.63722e-1 Nitrogen 

 4.892 BB 8.33619 1.97847e-3 1.64929e-2 Carbon monoxide 

 7.282 BB 6.94967 2.06634e-3 1.43604e-2 Methane 

 9.008 BB 7668.27734 1.27145e-3 9.74983 Carbon dioxide 

Totals : 20.08832

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0401.D

Sample Name: gc110p104 #FG6 ENV(1=0,3=358.71)

Betty Reprocess 1/12/2010 6:26:52 PM Page 1 of 2

EA# 0410-59 Page 81 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 4

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 08-Jan-10, 02:10:23 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

200

400

600

800

1000

 TCD1 A, (GC110P104\012F0402.D) 3.040 - Oxygen

 9.007 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.040 BB 4179.34570 2.37663e-3 9.93275 Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 9.007 BB 7687.08057 1.27145e-3 9.77374 Carbon dioxide 

Totals : 19.70650

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F0402.D

Sample Name: gc110p104 #FG6 ENV(1=0,3=358.71)

Betty Reprocess 1/12/2010 6:27:00 PM Page 1 of 2

EA# 0410-59 Page 82 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 26

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 11-Jan-10, 19:03:47 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/11/2010 6:49:52 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

80

 TCD1 A, (GC110P104\012F2601.D) 0.767 - Hydrogen 3.519 - Nitrogen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.767 BB 624.30151 8.46272e-2 52.83289 Hydrogen 

 2.783 - - - Oxygen 

 3.519 BB 8.61831 1.82588e-3 1.57360e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 52.84863

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F2601.D

Sample Name: H2 40% AX13607 ENV(1=424,5=396) #10

Betty Reprocess 1/12/2010 6:37:24 PM Page 1 of 2

EA# 0410-59 Page 83 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 26

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 11-Jan-10, 19:41:37 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/11/2010 6:49:52 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

-20

0

20

40

60

 TCD1 A, (GC110P104\012F2602.D) 0.767 - Hydrogen 3.528 - Nitrogen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.767 BB 624.25305 8.46272e-2 52.82879 Hydrogen 

 2.783 - - - Oxygen 

 3.528 BB 8.83441 1.82588e-3 1.61305e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 52.84493

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F2602.D

Sample Name: H2 40% AX13607 ENV(1=424,5=396) #10

Betty Reprocess 1/12/2010 6:37:32 PM Page 1 of 2

EA# 0410-59 Page 84 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 3

Injection Date : 09-Jan-10, 00:03:21 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

50

100

150

200

250

 TCD1 A, (GC110P104\003F1801.D) 0.791 - Hydrogen 3.568 - Nitrogen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.791 BB 1886.04126 8.45725e-2 159.50716 Hydrogen 

 2.783 - - - Oxygen 

 3.568 BB 24.72860 1.82588e-3 4.51513e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 159.55231

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F1801.D

Sample Name: H2 UHP Matheson AX13607 #9

Betty Reprocess 1/12/2010 6:33:54 PM Page 1 of 2

EA# 0410-59 Page 85 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 18

Acq. Instrument : Betty online Location : Vial 3

Injection Date : 09-Jan-10, 00:25:08 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

50

100

150

200

250

 TCD1 A, (GC110P104\003F1802.D) 0.798 - Hydrogen 3.574 - Nitrogen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.798 BB 1906.76587 8.45722e-2 161.25933 Hydrogen 

 2.783 - - - Oxygen 

 3.574 BB 25.35750 1.82588e-3 4.62996e-2 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 161.30563

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F1802.D

Sample Name: H2 UHP Matheson AX13607 #9

Betty Reprocess 1/12/2010 6:34:03 PM Page 1 of 2

EA# 0410-59 Page 86 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 39

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 12-Jan-10, 17:17:37 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 4:41:41 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

 TCD1 A, (GC110P104\012F3901.D) 2.785 - Oxygen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.785 BB 4.39550e4 2.38037e-3 104.62906 Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 104.62906

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F3901.D

Sample Name: O2 AX38764 ENV(1=0,6=450) #9

Betty Reprocess 1/12/2010 6:43:31 PM Page 1 of 2

EA# 0410-59 Page 87 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 39

Acq. Instrument : Betty online Location : Vial 12

Injection Date : 12-Jan-10, 17:39:57 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 4:41:41 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

 TCD1 A, (GC110P104\012F3902.D) 2.783 - Oxygen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 BB 4.40748e4 2.38037e-3 104.91421 Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 104.91421

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\012F3902.D

Sample Name: O2 AX38764 ENV(1=0,6=450) #9

Betty Reprocess 1/12/2010 6:43:39 PM Page 1 of 2

EA# 0410-59 Page 88 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 38

Acq. Instrument : Betty online Location : Vial 3

Injection Date : 12-Jan-10, 15:55:23 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 1:33:58 AM by JBB

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

 TCD1 A, (GC110P104\003F3801.D) 3.003 - Oxygen 3.126 - Nitrogen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.003 BV 4.95237 2.19054e-3 1.08484e-2 Oxygen 

 3.126 VB 4.72424e4 2.20870e-3 104.34448 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 104.35533

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F3801.D

Sample Name: House cryo N2

Betty Reprocess 1/12/2010 6:43:06 PM Page 1 of 2

EA# 0410-59 Page 89 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 38

Acq. Instrument : Betty online Location : Vial 3

Injection Date : 12-Jan-10, 16:16:39 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 3:55:58 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

 TCD1 A, (GC110P104\003F3802.D) 2.998 - Oxygen 3.125 - Nitrogen

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.998 BV 55.69423 2.19054e-3 1.22001e-1 Oxygen 

 3.125 VB 4.70101e4 2.20870e-3 103.83102 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 103.95302

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\003F3802.D

Sample Name: House cryo N2

Betty Reprocess 1/12/2010 6:43:14 PM Page 1 of 2

EA# 0410-59 Page 90 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 21

Acq. Instrument : Betty online Location : Vial 10

Injection Date : 09-Jan-10, 03:35:37 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

 TCD1 A, (GC110P104\010F2101.D) 3.139 3.545 - Nitrogen

 4.502 - Carbon monoxide

 9.105 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.545 BB 165.80986 1.95661e-3 3.24425e-1 Nitrogen 

 4.502 BB 5.46928e4 1.97962e-3 108.27112 Carbon monoxide 

 7.286 - - - Methane 

 9.105 BB 15.69188 1.25078e-3 1.96271e-2 Carbon dioxide 

Totals : 108.61518

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\010F2101.D

Sample Name: CO 99+% Aldrich 03611BJ #9

Betty Reprocess 1/12/2010 6:35:18 PM Page 1 of 2

EA# 0410-59 Page 91 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 21

Acq. Instrument : Betty online Location : Vial 10

Injection Date : 09-Jan-10, 03:57:37 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

 TCD1 A, (GC110P104\010F2102.D) 3.141 3.548 - Nitrogen

 4.504 - Carbon monoxide

 9.106 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.548 BB 165.22366 1.95571e-3 3.23130e-1 Nitrogen 

 4.504 BB 5.46037e4 1.97962e-3 108.09478 Carbon monoxide 

 7.286 - - - Methane 

 9.106 BB 14.99084 1.25078e-3 1.87502e-2 Carbon dioxide 

Totals : 108.43666

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\010F2102.D

Sample Name: CO 99+% Aldrich 03611BJ #9

Betty Reprocess 1/12/2010 6:35:27 PM Page 1 of 2

EA# 0410-59 Page 92 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 22

Acq. Instrument : Betty online Location : Vial 4

Injection Date : 09-Jan-10, 04:41:17 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

2500

3000

 TCD1 A, (GC110P104\004F2201.D) 3.147 3.567 - Nitrogen

 6.934 - Methane

 9.107 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.567 BB 124.35021 1.87226e-3 2.32816e-1 Nitrogen 

 4.902 - - - Carbon monoxide 

 6.934 BB 4.91733e4 2.16792e-3 106.60407 Methane 

 9.107 BB 5.12652 1.25078e-3 6.41214e-3 Carbon dioxide 

Totals : 106.84330

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\004F2201.D

Sample Name: CH4 99+% Aldrich MKBB4558 #9

Betty Reprocess 1/12/2010 6:35:44 PM Page 1 of 2

EA# 0410-59 Page 93 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 22

Acq. Instrument : Betty online Location : Vial 4

Injection Date : 09-Jan-10, 05:03:07 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

500

1000

1500

2000

2500

3000

 TCD1 A, (GC110P104\004F2202.D) 3.143 3.562 - Nitrogen

 6.934 - Methane

 9.110 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.562 BB 123.43662 1.86977e-3 2.30798e-1 Nitrogen 

 4.902 - - - Carbon monoxide 

 6.934 BB 4.89184e4 2.16792e-3 106.05134 Methane 

 9.110 BB 5.01183 1.25078e-3 6.26870e-3 Carbon dioxide 

Totals : 106.28840

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\004F2202.D

Sample Name: CH4 99+% Aldrich MKBB4558 #9

Betty Reprocess 1/12/2010 6:35:53 PM Page 1 of 2

EA# 0410-59 Page 94 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 20

Acq. Instrument : Betty online Location : Vial 6

Injection Date : 09-Jan-10, 02:30:00 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

1000

2000

3000

4000

 TCD1 A, (GC110P104\006F2001.D) 3.150 3.564 - Nitrogen

 8.735 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.564 BB 634.06775 2.14343e-3 1.35908 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.735 BB S 8.31270e4 1.27185e-3 105.72481 Carbon dioxide 

Totals : 107.08389

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\006F2001.D

Sample Name: CO2 99.8+% Adlrich 01629AJ #9

Betty Reprocess 1/12/2010 6:34:52 PM Page 1 of 2

EA# 0410-59 Page 95 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 20

Acq. Instrument : Betty online Location : Vial 6

Injection Date : 09-Jan-10, 02:51:55 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/12/2010 6:16:57 PM

2 4 6 8 10 min

25 uV

0

1000

2000

3000

4000

 TCD1 A, (GC110P104\006F2002.D) 3.155 3.565 - Nitrogen

 8.737 - Carbon dioxide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/12/2010 6:10:49 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: TCD1 A, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.565 BB 901.61365 2.16307e-3 1.95025 Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.737 BB S 8.21878e4 1.27185e-3 104.53026 Carbon dioxide 

Totals : 106.48051

Signal 2: FID2 B, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 - - - Methane 

 1.354 - - - Ethane 

 2.130 - - - Propane 

 4.772 - - - Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\006F2002.D

Sample Name: CO2 99.8+% Adlrich 01629AJ #9

Betty Reprocess 1/12/2010 6:35:01 PM Page 1 of 2

EA# 0410-59 Page 96 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 11

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 10:00:19 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1101.D)

 Area: 0.249083

 Area: 0.362427

 1.099 1.129 - Methane

 1.354 - Ethane

 2.136 - Propane

 4.774 - Butane

 6.364 - Pentane

 7.281 - Hexane

 7.964 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PB 1.32972e-1 3.70546 4.92723e-1 Methane 

 1.354 MM 2.49083e-1 2.02772 5.05069e-1 Ethane 

 2.136 MM 3.62427e-1 1.37041 4.96676e-1 Propane 

 4.774 BB 5.10125e-1 9.89060e-1 5.04544e-1 Butane 

 6.364 BB 5.96716e-1 8.11293e-1 4.84112e-1 Pentane 

 7.281 BB 7.47089e-1 6.92816e-1 5.17595e-1 Hexane 

 7.964 BB 7.89259e-1 6.15604e-1 4.85871e-1 Heptane 

Totals : 3.48659

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1101.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Betty Reprocess 1/12/2010 4:03:07 PM Page 1 of 2

EA# 0410-59 Page 97 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 11

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 10:23:30 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1102.D)

 Area: 0.492835

 1.099 1.129 - Methane

 1.354 - Ethane

 2.131 - Propane

 4.769 - Butane

 6.364 - Pentane

 7.281 - Hexane

 7.964 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PB 1.33097e-1 3.70546 4.93187e-1 Methane 

 1.354 BB 2.50025e-1 2.02756 5.06940e-1 Ethane 

 2.131 BB 3.71790e-1 1.36954 5.09182e-1 Propane 

 4.769 MM 4.92835e-1 9.88999e-1 4.87414e-1 Butane 

 6.364 BB 6.09468e-1 8.11293e-1 4.94458e-1 Pentane 

 7.281 BB 7.40346e-1 6.92867e-1 5.12961e-1 Hexane 

 7.964 BB 7.87899e-1 6.15647e-1 4.85068e-1 Heptane 

Totals : 3.48921

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1102.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Betty Reprocess 1/12/2010 4:03:15 PM Page 1 of 2

EA# 0410-59 Page 98 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 11

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 10:46:37 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1103.D)

 Area: 0.513654

 1.099 1.129 - Methane

 1.354 - Ethane

 2.129 - Propane

 4.773 - Butane

 6.363 - Pentane

 7.281 - Hexane

 7.964 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PB 1.40135e-1 3.69758 5.18163e-1 Methane 

 1.354 BB 2.43084e-1 2.02818 4.93020e-1 Ethane 

 2.129 BB 3.51653e-1 1.37041 4.81910e-1 Propane 

 4.773 MM 5.13654e-1 9.89107e-1 5.08058e-1 Butane 

 6.363 BB 6.17081e-1 8.11133e-1 5.00535e-1 Pentane 

 7.281 BB 7.45524e-1 6.92837e-1 5.16527e-1 Hexane 

 7.964 BB 7.91644e-1 6.15529e-1 4.87280e-1 Heptane 

Totals : 3.50549

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1103.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Betty Reprocess 1/12/2010 4:03:22 PM Page 1 of 2

EA# 0410-59 Page 99 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 20:20:03 Inj : 5

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4005.D) 1.096 1.125 - Methane 1.350 - Ethane 2.122 - Propane

 4.771 - Butane

 6.362 - Pentane

 6.904 7.041 7.170 7.279 - Hexane 7.366 7.444

 7.608 7.748 7.866 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.125 PB 1.38697e-1 3.69960 5.13121e-1 Methane 

 1.350 BB 2.60857e-1 2.02586 5.28459e-1 Ethane 

 2.122 BB 3.77518e-1 1.36891 5.16788e-1 Propane 

 4.771 BB 4.99911e-1 9.88999e-1 4.94412e-1 Butane 

 6.362 BB 5.72031e-1 8.11291e-1 4.64084e-1 Pentane 

 7.279 VV 9.75770e-1 6.90469e-1 6.73739e-1 Hexane 

 7.962 VV 8.96783e-1 6.12613e-1 5.49381e-1 Heptane 

Totals : 3.73998

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4005.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:20 PM Page 1 of 2

EA# 0410-59 Page 100 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 20:42:25 Inj : 6

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4006.D) 1.095 1.124 - Methane 1.349 - Ethane 2.116 - Propane

 4.772 - Butane

 6.362 - Pentane

 7.279 - Hexane

 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.124 PB 1.39506e-1 3.69846 5.15956e-1 Methane 

 1.349 BB 2.52463e-1 2.02716 5.11783e-1 Ethane 

 2.116 BB 3.83528e-1 1.36827 5.24769e-1 Propane 

 4.772 BB 5.44910e-1 9.89493e-1 5.39184e-1 Butane 

 6.362 BB 6.27735e-1 8.10914e-1 5.09039e-1 Pentane 

 7.279 BB 7.17647e-1 6.92867e-1 4.97234e-1 Hexane 

 7.962 BB 7.86459e-1 6.15651e-1 4.84184e-1 Heptane 

Totals : 3.58215

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4006.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:25 PM Page 1 of 2

EA# 0410-59 Page 101 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 21:04:45 Inj : 7

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4007.D) 1.095 1.124 - Methane 1.349 - Ethane 2.124 - Propane

 4.767 - Butane

 6.362 - Pentane

 7.279 - Hexane

 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.124 PB 1.36451e-1 3.70282 5.05252e-1 Methane 

 1.349 BB 2.51474e-1 2.02732 5.09820e-1 Ethane 

 2.124 BB 3.90087e-1 1.36759 5.33480e-1 Propane 

 4.767 BB 5.11370e-1 9.89077e-1 5.05784e-1 Butane 

 6.362 BB 6.21943e-1 8.11031e-1 5.04415e-1 Pentane 

 7.279 BB 7.59313e-1 6.92654e-1 5.25942e-1 Hexane 

 7.962 BB 7.95051e-1 6.15423e-1 4.89293e-1 Heptane 

Totals : 3.57399

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4007.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:31 PM Page 1 of 2

EA# 0410-59 Page 102 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 21:26:59 Inj : 8

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4008.D) 1.096 1.126 - Methane 1.351 - Ethane 2.119 - Propane

 4.763 - Butane

 6.362 - Pentane

 7.279 - Hexane

 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.126 PB 1.33128e-1 3.70546 4.93300e-1 Methane 

 1.351 BB 2.56826e-1 2.02647 5.20452e-1 Ethane 

 2.119 BB 4.63798e-1 1.36130 6.31366e-1 Propane 

 4.763 BB 5.33102e-1 9.89352e-1 5.27426e-1 Butane 

 6.362 BB 6.15952e-1 8.11155e-1 4.99632e-1 Pentane 

 7.279 BB 7.49470e-1 6.92784e-1 5.19221e-1 Hexane 

 7.962 BB 8.91693e-1 6.12739e-1 5.46375e-1 Heptane 

Totals : 3.73777

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4008.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:36 PM Page 1 of 2

EA# 0410-59 Page 103 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 21:54:14 Inj : 9

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4009.D) 1.095 1.125 - Methane 1.350 - Ethane 2.116 - Propane

 4.768 - Butane

 6.362 - Pentane

 7.279 - Hexane

 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.125 PB 1.37988e-1 3.70060 5.10640e-1 Methane 

 1.350 BB 2.73482e-1 2.02404 5.53538e-1 Ethane 

 2.116 BB 3.91750e-1 1.36742 5.35688e-1 Propane 

 4.768 BB 5.15858e-1 9.89136e-1 5.10254e-1 Butane 

 6.362 BB 6.18196e-1 8.11108e-1 5.01424e-1 Pentane 

 7.279 BB 7.74488e-1 6.92461e-1 5.36303e-1 Hexane 

 7.962 BB 8.24252e-1 6.14545e-1 5.06540e-1 Heptane 

Totals : 3.65439

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4009.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:42 PM Page 1 of 2

EA# 0410-59 Page 104 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 22:16:25 Inj : 10

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4010.D) 1.094 1.124 - Methane 1.349 - Ethane 2.128 - Propane

 4.772 - Butane

 6.362 - Pentane

 7.279 - Hexane

 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.124 PB 1.32027e-1 3.70546 4.89220e-1 Methane 

 1.349 BB 2.58097e-1 2.02628 5.22976e-1 Ethane 

 2.128 BB 4.11002e-1 1.36558 5.61254e-1 Propane 

 4.772 BB 5.22762e-1 9.89224e-1 5.17129e-1 Butane 

 6.362 BB 6.25905e-1 8.10951e-1 5.07578e-1 Pentane 

 7.279 BB 7.63898e-1 6.92595e-1 5.29072e-1 Hexane 

 7.962 BB 8.23590e-1 6.14565e-1 5.06149e-1 Heptane 

Totals : 3.63338

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4010.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:15:53 PM Page 1 of 2

EA# 0410-59 Page 105 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 40

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 12-Jan-10, 22:38:35 Inj : 11

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/12/2010 6:01:04 PM

Analysis Method : G:\GC2010Q1\BETTY\METHODS\GC110P104A.M

Last changed : 1/13/2010 10:18:19 PM

2 4 6 8 10 min

pA

4

6

8

10

12

14

16

18

20

 FID2 B, (GC110P104\028B4011.D) 1.094 1.123 - Methane 1.348 - Ethane 2.124 - Propane

 4.770 - Butane

 6.362 - Pentane

 7.279 - Hexane

 7.962 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/13/2010 10:14:02 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.123 PB 1.44223e-1 3.69208 5.32484e-1 Methane 

 1.348 BB 2.82534e-1 2.02284 5.71520e-1 Ethane 

 2.124 BB 4.16284e-1 1.36510 5.68269e-1 Propane 

 4.770 BB 5.15308e-1 9.89129e-1 5.09706e-1 Butane 

 6.362 BB 5.94757e-1 8.11291e-1 4.82521e-1 Pentane 

 7.279 BB 7.37672e-1 6.92867e-1 5.11108e-1 Hexane 

 7.962 BB 8.00652e-1 6.15249e-1 4.92601e-1 Heptane 

Totals : 3.66821

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 2.783 - - - Oxygen 

 3.410 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B4011.D

Sample Name: gc110p104 #C1 ENV(1=1406.26,4=10)

Instrument 3 1/14/2010 4:16:00 PM Page 1 of 2

EA# 0410-59 Page 106 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 10

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 08:50:47 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1001.D) 1.099 1.129 - Methane 1.354 - Ethane 2.128 - Propane

 4.774 - Butane

 6.365 - Pentane

 7.282 - Hexane

 7.965 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PB 5.53671e-1 3.55263 1.96699 Methane 

 1.354 BB 9.79376e-1 1.99698 1.95580 Ethane 

 2.128 BB 1.51869 1.33816 2.03225 Propane 

 4.774 BB 1.99415 9.94097e-1 1.98238 Butane 

 6.365 BB 2.50332 8.01436e-1 2.00625 Pentane 

 7.282 BB 2.99717 6.85300e-1 2.05396 Hexane 

 7.965 BB 3.22493 5.96764e-1 1.92452 Heptane 

Totals : 13.92215

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1001.D

Sample Name: gc110p104 #C2 ENV(1=692.53,4=20)

Betty Reprocess 1/12/2010 4:02:43 PM Page 1 of 2

EA# 0410-59 Page 107 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 10

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 09:13:58 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1002.D) 1.098 1.128 - Methane 1.353 - Ethane 2.126 - Propane

 4.773 - Butane

 6.365 - Pentane

 7.282 - Hexane

 7.965 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.128 PB 5.57310e-1 3.55231 1.97974 Methane 

 1.353 BB 9.87823e-1 1.99689 1.97258 Ethane 

 2.126 BB 1.49927 1.33829 2.00645 Propane 

 4.773 BB 2.00242 9.94104e-1 1.99061 Butane 

 6.365 BB 2.50754 8.01431e-1 2.00962 Pentane 

 7.282 BB 2.98740 6.85308e-1 2.04729 Hexane 

 7.965 BB 3.23920 5.96737e-1 1.93295 Heptane 

Totals : 13.93924

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1002.D

Sample Name: gc110p104 #C2 ENV(1=692.53,4=20)

Betty Reprocess 1/12/2010 4:02:51 PM Page 1 of 2

EA# 0410-59 Page 108 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 10

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 09:37:07 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1003.D) 1.098 1.128 - Methane 1.353 - Ethane 2.127 - Propane

 4.773 - Butane

 6.365 - Pentane

 7.282 - Hexane

 7.964 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.128 PB 5.46936e-1 3.55324 1.94339 Methane 

 1.353 BB 9.91052e-1 1.99686 1.97899 Ethane 

 2.127 BB 1.54576 1.33798 2.06819 Propane 

 4.773 BB 2.03886 9.94135e-1 2.02691 Butane 

 6.365 BB 2.47764 8.01469e-1 1.98575 Pentane 

 7.282 BB 3.00554 6.85293e-1 2.05967 Hexane 

 7.964 BB 3.24216 5.96732e-1 1.93470 Heptane 

Totals : 13.99761

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1003.D

Sample Name: gc110p104 #C2 ENV(1=692.53,4=20)

Betty Reprocess 1/12/2010 4:02:59 PM Page 1 of 2

EA# 0410-59 Page 109 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 07:41:03 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B0901.D) 1.099 1.128 - Methane 1.354 - Ethane 2.127 - Propane

 4.774 - Butane

 6.364 - Pentane

 7.157 7.282 - Hexane

 7.965 - Heptane

 8.182

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.128 PB 2.77840 3.51330 9.76135 Methane 

 1.354 BB 4.97499 1.98856 9.89309 Ethane 

 2.127 BB 7.60298 1.33002 10.11210 Propane 

 4.774 BB 10.06287 9.95485e-1 10.01744 Butane 

 6.364 BB 12.41950 7.98903e-1 9.92198 Pentane 

 7.282 BB 14.95311 6.83305e-1 10.21753 Hexane 

 7.965 BB 16.14325 5.91879e-1 9.55485 Heptane 

Totals : 69.47834

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0901.D

Sample Name: gc110p104 #C3 ENV(1=636,4=100)

Betty Reprocess 1/12/2010 4:02:19 PM Page 1 of 2

EA# 0410-59 Page 110 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 08:04:20 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B0902.D) 1.101 1.130 - Methane 1.355 - Ethane 2.129 - Propane

 4.774 - Butane

 6.054

 6.364 - Pentane

 7.282 - Hexane

 7.965 - Heptane

 8.180

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.130 PB 2.78876 3.51327 9.79764 Methane 

 1.355 BB 4.99637 1.98856 9.93555 Ethane 

 2.129 BB 7.65755 1.33000 10.18457 Propane 

 4.774 BB 10.16584 9.95489e-1 10.11997 Butane 

 6.364 BB 12.49228 7.98899e-1 9.98007 Pentane 

 7.282 BB 15.06768 6.83301e-1 10.29576 Hexane 

 7.965 BB 16.31054 5.91866e-1 9.65366 Heptane 

Totals : 69.96723

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0902.D

Sample Name: gc110p104 #C3 ENV(1=636,4=100)

Betty Reprocess 1/12/2010 4:02:27 PM Page 1 of 2

EA# 0410-59 Page 111 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 08:27:32 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B0903.D) 1.100 1.129 - Methane 1.355 - Ethane 2.128 - Propane

 4.773 - Butane

 6.052

 6.364 - Pentane

 7.281 - Hexane

 7.523

 7.964 - Heptane

 8.178

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PB 2.83845 3.51309 9.97175 Methane 

 1.355 BB 4.96842 1.98857 9.88003 Ethane 

 2.128 BB 7.65300 1.33001 10.17853 Propane 

 4.773 BB 10.05984 9.95485e-1 10.01442 Butane 

 6.364 BB 12.41880 7.98903e-1 9.92142 Pentane 

 7.281 BB 15.02427 6.83302e-1 10.26612 Hexane 

 7.964 BB 16.15368 5.91878e-1 9.56101 Heptane 

Totals : 69.79328

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0903.D

Sample Name: gc110p104 #C3 ENV(1=636,4=100)

Betty Reprocess 1/12/2010 4:02:35 PM Page 1 of 2

EA# 0410-59 Page 112 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 8

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 06:30:58 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B0801.D) 1.103 1.131 - Methane 1.356 - Ethane 2.129 - Propane

 4.774 - Butane

 6.050

 6.365 - Pentane

 7.023 7.159 7.281 - Hexane

 7.524 7.825 7.965 - Heptane

 8.180 8.231

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.131 PB 11.04649 3.50598 38.72872 Methane 

 1.356 BB 19.70167 1.98702 39.14764 Ethane 

 2.129 BB 30.00404 1.32850 39.86042 Propane 

 4.774 BB 39.87003 9.95742e-1 39.70025 Butane 

 6.365 BB 48.98482 7.98426e-1 39.11074 Pentane 

 7.281 BB 59.01889 6.82931e-1 40.30584 Hexane 

 7.965 VB 63.80853 5.90968e-1 37.70879 Heptane 

Totals : 274.56240

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0801.D

Sample Name: gc110p104 #C4 ENV(1=424,4=400)

Betty Reprocess 1/12/2010 4:01:55 PM Page 1 of 2

EA# 0410-59 Page 113 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 8

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 06:54:24 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B0802.D) 1.105 1.133 - Methane 1.358 - Ethane 2.132 - Propane

 4.775 - Butane

 6.050

 6.365 - Pentane

 7.031 7.158 7.281 - Hexane

 7.523 7.824 7.903 7.965 - Heptane

 8.181 8.229

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.133 PB 11.11530 3.50596 38.96978 Methane 

 1.358 BB 19.74178 1.98702 39.22731 Ethane 

 2.132 BB 30.09650 1.32850 39.98320 Propane 

 4.775 BB 39.94662 9.95742e-1 39.77652 Butane 

 6.365 BB 49.11836 7.98425e-1 39.21734 Pentane 

 7.281 BB 59.16596 6.82931e-1 40.40626 Hexane 

 7.965 VB 63.81134 5.90968e-1 37.71046 Heptane 

Totals : 275.29088

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0802.D

Sample Name: gc110p104 #C4 ENV(1=424,4=400)

Betty Reprocess 1/12/2010 4:02:03 PM Page 1 of 2

EA# 0410-59 Page 114 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 8

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 07:17:43 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B0803.D) 1.102 1.130 - Methane 1.355 - Ethane 2.129 - Propane

 4.774 - Butane

 6.052

 6.365 - Pentane

 7.028 7.158 7.282 - Hexane

 7.523 7.823 7.905 7.965 - Heptane

 8.180

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.130 PB 11.03196 3.50598 38.67781 Methane 

 1.355 BB 19.60324 1.98702 38.95210 Ethane 

 2.129 BB 29.91669 1.32850 39.74443 Propane 

 4.774 BB 39.67163 9.95741e-1 39.50268 Butane 

 6.365 BB 48.81525 7.98426e-1 38.97538 Pentane 

 7.282 BB 58.83771 6.82932e-1 40.18213 Hexane 

 7.965 VB 63.45609 5.90970e-1 37.50062 Heptane 

Totals : 273.53514

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B0803.D

Sample Name: gc110p104 #C4 ENV(1=424,4=400)

Betty Reprocess 1/12/2010 4:02:11 PM Page 1 of 2

EA# 0410-59 Page 115 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 19

Acq. Instrument : Betty online Location : Vial 32

Injection Date : 09-Jan-10, 01:24:43 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\032B1901.D) 1.105 1.131 - Methane 1.356 - Ethane 2.128 - Propane

 4.773 - Butane

 6.049

 6.362 - Pentane

 7.026 7.155 7.279 - Hexane

 7.520

 7.821 7.894 7.962 - Heptane

 8.177 8.226

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.131 PB 28.19965 3.50448 98.82505 Methane 

 1.356 BB 48.87247 1.98671 97.09544 Ethane 

 2.128 BB 74.27017 1.32819 98.64526 Propane 

 4.773 BB 98.56340 9.95793e-1 98.14877 Butane 

 6.362 BB 121.06608 7.98329e-1 96.65058 Pentane 

 7.279 BB 145.70467 6.82856e-1 99.49527 Hexane 

 7.962 VB 157.17064 5.90785e-1 92.85400 Heptane 

Totals : 681.71437

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\032B1901.D

Sample Name: gc110p104 #C5 A019379 #9

Betty Reprocess 1/12/2010 4:07:32 PM Page 1 of 2

EA# 0410-59 Page 116 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 19

Acq. Instrument : Betty online Location : Vial 32

Injection Date : 09-Jan-10, 01:46:24 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\032B1902.D) 1.102 1.129 - Methane 1.354 - Ethane 2.126 - Propane

 4.770 - Butane

 6.050

 6.361 - Pentane

 7.029 7.155 7.279 - Hexane

 7.520

 7.821 7.896 7.962 - Heptane

 8.177 8.227

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PB 28.06611 3.50448 98.35718 Methane 

 1.354 BB 48.61981 1.98671 96.59354 Ethane 

 2.126 BB 73.93579 1.32820 98.20121 Propane 

 4.770 BB 98.08015 9.95793e-1 97.66754 Butane 

 6.361 BB 120.51656 7.98329e-1 96.21193 Pentane 

 7.279 BB 145.06584 6.82856e-1 99.05907 Hexane 

 7.962 VB 156.45099 5.90785e-1 92.42893 Heptane 

Totals : 678.51940

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\032B1902.D

Sample Name: gc110p104 #C5 A019379 #9

Betty Reprocess 1/12/2010 4:07:40 PM Page 1 of 2

EA# 0410-59 Page 117 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 19

Acq. Instrument : Betty online Location : Vial 32

Injection Date : 09-Jan-10, 02:08:12 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\032B1903.D) 1.101 1.127 - Methane 1.352 - Ethane 2.124 - Propane

 3.671

 4.768 - Butane

 6.047

 6.361 - Pentane

 7.025 7.154 7.278 - Hexane

 7.520

 7.773 7.822 7.894 7.961 - Heptane

 8.176 8.227

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.127 PB 28.05125 3.50448 98.30512 Methane 

 1.352 BB 48.62759 1.98671 96.60899 Ethane 

 2.124 BB 73.92005 1.32820 98.18030 Propane 

 4.768 BB 98.09365 9.95793e-1 97.68098 Butane 

 6.361 BB 120.46914 7.98330e-1 96.17407 Pentane 

 7.278 BB 144.94872 6.82856e-1 98.97910 Hexane 

 7.961 VB 156.25754 5.90785e-1 92.31467 Heptane 

Totals : 678.24323

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\032B1903.D

Sample Name: gc110p104 #C5 A019379 #9

Betty Reprocess 1/12/2010 4:07:48 PM Page 1 of 2

EA# 0410-59 Page 118 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 13

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 12:18:59 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1301.D) 1.099 1.128 - Methane 1.265 1.353 - Ethane 2.126 - Propane

 3.675

 4.771 - Butane

 5.059

 6.049

 6.366 - Pentane

 7.967 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.128 PV 304.26312 3.50360 1066.01718 Methane 

 1.353 VB 527.98383 1.98652 1048.85032 Ethane 

 2.126 BB 753.53271 1.32801 1000.69697 Propane 

 4.771 BV 1028.94653 9.95825e-1 1024.65057 Butane 

 6.366 BB 6.38529e-2 8.11293e-1 5.18034e-2 Pentane 

 7.281 - - - Hexane 

 7.967 BB 3.19884e-2 6.15651e-1 1.96937e-2 Heptane 

Totals : 4140.28653

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1301.D

Sample Name: gc110p104 #C6 ENV(1=636,5=105.54)

Betty Reprocess 1/12/2010 4:04:08 PM Page 1 of 2

EA# 0410-59 Page 119 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 13

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 12:41:58 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1302.D) 1.100 1.129 - Methane 1.265 1.354 - Ethane 2.126 - Propane

 3.677

 4.770 - Butane

 5.060

 6.049

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.129 PV 306.09540 3.50360 1072.43658 Methane 

 1.354 VB 531.21765 1.98652 1055.27431 Ethane 

 2.126 BB 758.24438 1.32801 1006.95401 Propane 

 4.770 BV 1035.10571 9.95825e-1 1030.78405 Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 4165.44895

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1302.D

Sample Name: gc110p104 #C6 ENV(1=636,5=105.54)

Betty Reprocess 1/12/2010 4:04:16 PM Page 1 of 2

EA# 0410-59 Page 120 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 13

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 13:04:57 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1303.D) 1.097 1.126 - Methane 1.263 1.351 - Ethane 2.124 - Propane

 3.671

 4.769 - Butane

 5.056

 6.049

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.126 PV 303.47232 3.50360 1063.24659 Methane 

 1.351 VB 526.59491 1.98652 1046.09124 Ethane 

 2.124 BB 751.49084 1.32801 997.98540 Propane 

 4.769 BV 1025.73120 9.95825e-1 1021.44865 Butane 

 6.364 - - - Pentane 

 7.281 - - - Hexane 

 7.964 - - - Heptane 

Totals : 4128.77187

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1303.D

Sample Name: gc110p104 #C6 ENV(1=636,5=105.54)

Betty Reprocess 1/12/2010 4:04:24 PM Page 1 of 2

EA# 0410-59 Page 121 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 12

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 11:09:45 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1201.D) 1.106 1.133 - Methane 1.270 1.357 - Ethane 2.129 - Propane

 3.677

 4.770 - Butane

 5.061

 5.300

 5.846

 6.050

 6.365 - Pentane

 6.583

 7.033 7.156 7.282 - Hexane 7.329 7.435 7.512

 7.711 7.759

 7.964 - Heptane

 8.375

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.133 PV 2963.98413 3.50352 1.03844e4 Methane 

 1.357 VB S 5138.85498 1.98650 1.02083e4 Ethane 

 2.129 BB 7331.60645 1.32799 9736.29227 Propane 

 4.770 BV 1.00028e4 9.95828e-1 9961.03503 Butane 

 6.365 BB 6.35256e-1 8.10765e-1 5.15044e-1 Pentane 

 7.282 BV 2.05575e-1 6.92867e-1 1.42436e-1 Hexane 

 7.964 BB 3.01710e-1 6.15651e-1 1.85748e-1 Heptane 

Totals : 4.02909e4 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1201.D

Sample Name: gc110p104 #C7 ENV(1=0,5=474.93)

Betty Reprocess 1/12/2010 4:03:30 PM Page 1 of 2

EA# 0410-59 Page 122 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 12

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 11:32:54 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1202.D) 1.104 1.131 - Methane 1.268 1.355 - Ethane 2.127 - Propane

 3.677

 4.769 - Butane

 5.060

 5.298

 5.847

 6.050

 6.364 - Pentane

 6.582

 7.033 7.156 - Hexane

 7.510

 7.760

 7.966 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.131 PV 2976.04688 3.50352 1.04266e4 Methane 

 1.355 VB S 5158.12598 1.98650 1.02466e4 Ethane 

 2.127 BB 7359.58887 1.32799 9773.45255 Propane 

 4.769 BV 1.00386e4 9.95828e-1 9996.67479 Butane 

 6.364 BB 5.52414e-1 8.11293e-1 4.48169e-1 Pentane 

 7.156 BB 1.21364e-1 6.92867e-1 8.40890e-2 Hexane 

 7.966 VB 3.18806e-1 6.15651e-1 1.96273e-1 Heptane 

Totals : 4.04441e4 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1202.D

Sample Name: gc110p104 #C7 ENV(1=0,5=474.93)

Betty Reprocess 1/12/2010 4:03:52 PM Page 1 of 2

EA# 0410-59 Page 123 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 12

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 08-Jan-10, 11:55:55 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : C:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\GC110P104 2010-01-07 21-50-55\

 GC110P104.M

Last changed : 1/7/2010 9:50:54 PM by JBB

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B1203.D) 1.105 1.131 - Methane 1.268 1.356 - Ethane 2.128 - Propane

 3.677

 4.770 - Butane

 5.061

 5.299

 5.849

 6.050

 6.364 - Pentane

 6.583

 7.033 7.157 7.282 - Hexane

 7.511

 7.760

 7.967 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.131 PV 2967.53711 3.50352 1.03968e4 Methane 

 1.356 VB S 5142.88135 1.98650 1.02163e4 Ethane 

 2.128 BB 7335.46094 1.32799 9741.41098 Propane 

 4.770 BV 1.00100e4 9.95828e-1 9968.21297 Butane 

 6.364 BB 5.37764e-1 8.11293e-1 4.36284e-1 Pentane 

 7.282 BV 9.08920e-2 6.92867e-1 6.29760e-2 Hexane 

 7.967 BB 1.32513e-1 6.15651e-1 8.15820e-2 Heptane 

Totals : 4.03234e4 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B1203.D

Sample Name: gc110p104 #C7 ENV(1=0,5=474.93)

Betty Reprocess 1/12/2010 4:04:00 PM Page 1 of 2

EA# 0410-59 Page 124 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 24

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Jan-10, 06:56:31 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B2401.D) 1.103 1.131 - Methane 1.267 1.354 - Ethane 2.124 - Propane

 3.671

 4.768 - Butane

 5.059

 5.298 5.841

 6.048

 6.361 - Pentane

 6.740

 7.012 7.154 7.278 - Hexane

 7.519

 7.766 7.821 7.896 7.962 - Heptane

 8.173

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.131 PB 1.78757e-1 3.65565 6.53475e-1 Methane 

 1.354 VB S 1.01553e4 1.98650 2.01736e4 Ethane 

 2.124 BB 1.53434e4 1.32799 2.03759e4 Propane 

 4.768 BV 4139.53223 9.95827e-1 4122.25966 Butane 

 6.361 BB 1023.66614 7.98271e-1 817.16335 Pentane 

 7.278 BB 608.37439 6.82817e-1 415.40819 Hexane 

 7.962 VB 357.16541 5.90715e-1 210.98279 Heptane 

Totals : 4.61159e4 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2401.D

Sample Name: gc110p104 #C8 ENV(1=424.6,6=467.62)

Betty Reprocess 1/12/2010 4:09:19 PM Page 1 of 2

EA# 0410-59 Page 125 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 24

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Jan-10, 07:19:20 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B2402.D) 1.100 1.128 - Methane 1.264 1.351 - Ethane 2.121 - Propane

 3.669

 4.767 - Butane

 5.057

 5.297

 5.843

 6.047

 6.361 - Pentane

 6.735

 7.012 7.154 7.278 - Hexane 7.520

 7.765 7.821 7.895 7.962 - Heptane

 8.173 8.226

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.128 PB 1.68154e-1 3.66525 6.16325e-1 Methane 

 1.351 VB S 1.00861e4 1.98650 2.00360e4 Ethane 

 2.121 BB 1.52366e4 1.32799 2.02341e4 Propane 

 4.767 BV 4109.86621 9.95827e-1 4092.71740 Butane 

 6.361 BB 1016.26355 7.98271e-1 811.25413 Pentane 

 7.278 BB 603.96399 6.82817e-1 412.39675 Hexane 

 7.962 VB 354.54391 5.90715e-1 209.43438 Heptane 

Totals : 4.57965e4 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2402.D

Sample Name: gc110p104 #C8 ENV(1=424.6,6=467.62)

Betty Reprocess 1/12/2010 4:09:27 PM Page 1 of 2

EA# 0410-59 Page 126 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 24

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Jan-10, 07:42:11 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B2403.D) 1.102 1.130 - Methane 1.266 1.352 - Ethane 2.122 - Propane

 3.671

 4.768 - Butane

 5.057

 5.294 5.840

 6.048

 6.360 - Pentane

 6.732

 7.012 7.154 7.278 - Hexane

 7.520

 7.765 7.821 7.895 7.962 - Heptane

 8.173

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.130 PB 1.42857e-1 3.69389 5.27696e-1 Methane 

 1.352 VB S 1.00209e4 1.98650 1.99066e4 Ethane 

 2.122 BB 1.51388e4 1.32799 2.01041e4 Propane 

 4.768 BV 4083.37500 9.95827e-1 4066.33671 Butane 

 6.360 BB 1009.79877 7.98271e-1 806.09353 Pentane 

 7.278 BB 600.05615 6.82817e-1 409.72846 Hexane 

 7.962 VB 352.18039 5.90715e-1 208.03834 Heptane 

Totals : 4.55014e4 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2403.D

Sample Name: gc110p104 #C8 ENV(1=424.6,6=467.62)

Betty Reprocess 1/12/2010 4:09:36 PM Page 1 of 2

EA# 0410-59 Page 127 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 23

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Jan-10, 05:47:58 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B2301.D) 1.106 1.132 - Methane 1.268 1.353 - Ethane 2.122 - Propane

 3.673

 4.767 - Butane

 5.058

 5.295

 5.848

 6.047

 6.360 - Pentane

 6.735

 7.011 7.154 7.278 - Hexane

 7.519

 7.764 7.820 7.894 7.961 - Heptane 8.071 8.172 8.226

 8.543

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.132 PB 6.49008e-1 3.54542 2.30101 Methane 

 1.353 VB S 2.50756e4 1.98650 4.98127e4 Ethane 

 2.122 BB S 3.78892e4 1.32799 5.03164e4 Propane 

 4.767 BV 1.02189e4 9.95828e-1 1.01762e4 Butane 

 6.360 BB 2526.08008 7.98267e-1 2016.48569 Pentane 

 7.278 VB 1499.85876 6.82809e-1 1024.11764 Hexane 

 7.961 VB 879.06067 5.90682e-1 519.24513 Heptane 

Totals : 1.13867e5 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2301.D

Sample Name: gc110p104 #C9 ENV(1=0,6=467.62)

Betty Reprocess 1/12/2010 4:08:55 PM Page 1 of 2

EA# 0410-59 Page 128 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 23

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Jan-10, 06:10:50 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B2302.D) 1.103 1.130 - Methane 1.266 1.350 - Ethane 2.119 - Propane

 3.669

 4.546

 4.767 - Butane

 5.057

 5.295

 5.845

 6.047

 6.361 - Pentane

 6.575

 6.735

 7.012 7.154 7.278 - Hexane

 7.520

 7.764 7.821 7.895 7.962 - Heptane 8.069 8.173 8.226

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.130 PB 3.70220e-1 3.57697 1.32427 Methane 

 1.350 VB S 2.52360e4 1.98650 5.01313e4 Ethane 

 2.119 BB S 3.81401e4 1.32799 5.06496e4 Propane 

 4.767 VV 1.02852e4 9.95828e-1 1.02423e4 Butane 

 6.361 BB 2543.53394 7.98267e-1 2030.41847 Pentane 

 7.278 VB 1510.39673 6.82809e-1 1031.31300 Hexane 

 7.962 VV 885.69989 5.90682e-1 523.16664 Heptane 

Totals : 1.14609e5 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2302.D

Sample Name: gc110p104 #C9 ENV(1=0,6=467.62)

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EA# 0410-59 Page 129 of 225
=====================================================================

Acq. Operator : JBB Seq. Line : 23

Acq. Instrument : Betty online Location : Vial 28

Injection Date : 09-Jan-10, 06:33:39 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q1\BETTY\SEQUENCE\GC110P104.S

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Last changed : 1/8/2010 10:11:49 PM

Analysis Method : G:\GC110P104.M

Last changed : 1/12/2010 3:58:31 PM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P104\028B2303.D) 1.105 1.132 - Methane 1.268 1.352 - Ethane 2.121 - Propane

 3.673

 4.537

 4.767 - Butane

 5.059

 5.298

 5.845

 6.048

 6.360 - Pentane

 6.579

 6.736

 7.012 7.154 7.278 - Hexane

 7.520

 7.765 7.821 7.895 7.962 - Heptane

 8.173 8.227

 8.409 8.545

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, January 12, 2010 2:40:00 PM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.132 PB 2.54820e-1 3.61024 9.19962e-1 Methane 

 1.352 VB S 2.52629e4 1.98650 5.01848e4 Ethane 

 2.121 BB S 3.81777e4 1.32799 5.06996e4 Propane 

 4.767 VV 1.02960e4 9.95828e-1 1.02530e4 Butane 

 6.360 BV 2545.70264 7.98267e-1 2032.14967 Pentane 

 7.278 BB 1511.71875 6.82809e-1 1032.21569 Hexane 

 7.962 VB 886.73407 5.90682e-1 523.77749 Heptane 

Totals : 1.14726e5 

Signal 2: TCD1 A, not found

RetTime Type Area Amt/Area Amount Grp Name

 [min] [25 uV*s] [%] 

-------|------|----------|----------|----------|--|------------------

 0.840 - - - Hydrogen 

 3.115 - - - Oxygen 

 3.556 - - - Nitrogen 

 4.902 - - - Carbon monoxide 

 7.286 - - - Methane 

 8.950 - - - Carbon dioxide 

Totals : 0.00000

Data File G:\GC2010Q1\BETTY\DATA\JAN10\GC110P104\028B2303.D

Sample Name: gc110p104 #C9 ENV(1=0,6=467.62)

Betty Reprocess 1/12/2010 4:09:11 PM Page 1 of 2

EA# 0410-59 Page 130 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 09-Apr-10, 12:57:54 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 1/21/2010 9:48:47 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\025B0901.D) 1.148 - Methane 1.376 2.157

 4.801

 5.835

 6.069

 6.380

 6.593 7.043 7.171 7.294

 7.536

 7.783 7.836 7.909 7.977

 8.194 8.244

 8.429

 8.584

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/21/2010 9:48:15 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.148 PB 27.46096 3.50450 96.23704 Methane 

Totals : 96.23704

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B0901.D

Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 10:15:24 AM Page 1 of 1

EA# 0410-59 Page 131 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 09-Apr-10, 13:16:01 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 1/21/2010 9:48:47 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\025B0902.D) 1.146 - Methane 1.301 1.374 2.155

 4.801

 5.836

 6.068

 6.380

 6.599

 7.045 7.171 7.294

 7.536

 7.782 7.836 7.912 7.977

 8.193 8.244

 8.425

 8.591

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/21/2010 9:48:15 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.146 PB 26.16014 3.50455 91.67961 Methane 

Totals : 91.67961

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B0902.D

Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 10:15:42 AM Page 1 of 1

EA# 0410-59 Page 132 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 09-Apr-10, 13:34:55 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 1/21/2010 9:48:47 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\025B0903.D) 1.145 - Methane 1.301 1.373 2.157

 4.803

 5.837

 6.069

 6.381

 6.596

 7.046 7.172 7.295

 7.536

 7.777 7.838 7.910 7.978

 8.193 8.243

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/21/2010 9:48:15 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.145 PB 26.08904 3.50456 91.43050 Methane 

Totals : 91.43050

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B0903.D

Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 10:16:01 AM Page 1 of 1

EA# 0410-59 Page 133 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 21

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 09-Apr-10, 23:55:39 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 1/21/2010 9:48:47 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\025B2101.D) 1.111 1.138 - Methane 1.366 2.148

 4.797

 5.834

 6.066

 6.378

 7.044 7.169 7.293

 7.535

 7.780 7.834 7.908 7.975

 8.190 8.241

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/21/2010 9:48:15 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.138 PB 25.98668 3.50456 91.07189 Methane 

Totals : 91.07189

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B2101.D

Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 9:41:45 AM Page 1 of 1

EA# 0410-59 Page 134 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 21

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 10-Apr-10, 00:13:17 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 1/21/2010 9:48:47 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\025B2102.D) 1.112 1.139 - Methane 1.295 1.366 2.147

 4.794

 5.832

 6.064

 6.377

 7.041 7.168 7.292

 7.533 7.835 7.911 7.974

 8.189 8.238

 8.583

 8.962

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/21/2010 9:48:15 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.139 PB 26.26382 3.50455 92.04283 Methane 

Totals : 92.04283

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B2102.D

Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 9:42:13 AM Page 1 of 1

EA# 0410-59 Page 135 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 21

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 10-Apr-10, 00:31:55 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 1/21/2010 9:48:47 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P150\025B2103.D) 1.111 1.138 - Methane 1.293 1.366 2.149

 4.797

 5.834

 6.066

 6.379

 7.043 7.170 7.293

 7.535

 7.723 7.784 7.836 7.910 7.975

 8.191 8.241

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 1/21/2010 9:48:15 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.138 PB 26.10215 3.50456 91.47642 Methane 

Totals : 91.47642

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P150\025B2103.D

Sample Name: gc111p104 #C5

Betty Reprocess 4/16/2010 9:42:27 AM Page 1 of 1

EA# 0410-59 Page 136 of 225
=====================================================================

Acq. Operator : cjt Seq. Line : 2

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 13-Apr-10, 14:08:10 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P154\029B0201.D) 1.119 1.145 - Methane 1.373 2.152

 4.796

 6.065

 6.376 6.497

 7.040 7.167 7.291

 7.532

 7.832 7.908 7.973

 8.189 8.240

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.145 PB 27.85868 3.50449 97.63044 Methane 

Totals : 97.63044

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0201.D

Sample Name: Unit1 R1 Spk 0410-59

Betty Reprocess 4/16/2010 11:15:07 AM Page 1 of 1

EA# 0410-59 Page 137 of 225
=====================================================================

Acq. Operator : cjt Seq. Line : 2

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 13-Apr-10, 14:26:57 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P154\029B0202.D) 1.119 1.146 - Methane 1.374 2.156 3.352

 4.799

 6.067

 6.378 6.502

 7.037 7.169 7.292

 7.534

 7.784 7.835 7.910 7.975

 8.190 8.240

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.146 PB 27.78938 3.50449 97.38766 Methane 

Totals : 97.38766

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0202.D

Sample Name: Unit1 R1 Spk 0410-59

Betty Reprocess 4/16/2010 11:15:20 AM Page 1 of 1

EA# 0410-59 Page 138 of 225
=====================================================================

Acq. Operator : cjt Seq. Line : 2

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 13-Apr-10, 14:45:10 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P154\029B0203.D) 1.116 1.142 - Methane 1.370 2.150

 4.794

 6.064

 6.376 6.496

 7.038 7.167 7.290

 7.532

 7.783 7.833 7.906 7.973

 8.189 8.238

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.142 PB 27.72069 3.50449 97.14702 Methane 

Totals : 97.14702

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0203.D

Sample Name: Unit1 R1 Spk 0410-59

Betty Reprocess 4/16/2010 11:15:32 AM Page 1 of 1

EA# 0410-59 Page 139 of 225
=====================================================================

Acq. Operator : cjt Seq. Line : 4

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 13-Apr-10, 15:59:25 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P154\029B0401.D) 1.115 1.141 - Methane 1.369 2.151

 4.795

 6.064

 6.376 6.497

 7.037 7.168 7.291

 7.531

 7.783 7.833 7.907 7.973

 8.188 8.239

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.141 PB 27.66737 3.50450 96.96020 Methane 

Totals : 96.96020

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0401.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/16/2010 11:16:06 AM Page 1 of 1

EA# 0410-59 Page 140 of 225
=====================================================================

Acq. Operator : cjt Seq. Line : 4

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 13-Apr-10, 16:18:16 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P154\029B0402.D) 1.116 1.143 - Methane 1.370 2.151

 4.795

 6.065

 6.377 6.500

 7.038 7.168 7.292

 7.533

 7.782 7.833 7.908 7.974

 8.190 8.241

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.143 PB 27.81940 3.50449 97.49282 Methane 

Totals : 97.49282

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0402.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/16/2010 11:16:18 AM Page 1 of 1

EA# 0410-59 Page 141 of 225
=====================================================================

Acq. Operator : cjt Seq. Line : 4

Acq. Instrument : Betty online Location : Vial 29

Injection Date : 13-Apr-10, 16:36:50 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Last changed : 3/29/2010 9:45:19 AM by stg/tbo

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P154\029B0403.D) 1.114 1.140 - Methane 1.369 2.151

 4.797

 6.065

 6.378 6.501 6.594

 7.038 7.168 7.292

 7.534

 7.783 7.834 7.974

 8.190 8.240

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.140 PB 27.71966 3.50449 97.14339 Methane 

Totals : 97.14339

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P154\029B0403.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/16/2010 11:16:30 AM Page 1 of 1

EA# 0410-59 Page 142 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 15

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 16-Apr-10, 09:24:32 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P157\025B1501.D) 1.117 1.144 - Methane 1.372 2.153

 3.735

 4.798

 6.067

 6.379

 6.600

 7.036 7.169 7.293

 7.534

 7.720 7.787 7.835 7.909 7.975

 8.191 8.241

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.144 PB 27.51565 3.50450 96.42864 Methane 

Totals : 96.42864

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\025B1501.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:35:12 PM Page 1 of 1

EA# 0410-59 Page 143 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 15

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 16-Apr-10, 09:43:52 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P157\025B1502.D) 1.118 1.144 - Methane 1.372 2.154

 4.799

 6.068

 6.379

 7.038 7.170 7.294

 7.535

 7.722 7.783 7.836 7.911 7.976

 8.191 8.241

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.144 PB 27.38393 3.50451 95.96718 Methane 

Totals : 95.96718

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\025B1502.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:35:26 PM Page 1 of 1

EA# 0410-59 Page 144 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 15

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 16-Apr-10, 10:02:51 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P157\025B1503.D) 1.117 1.144 - Methane 1.372 2.155

 4.801

 6.068

 6.380

 6.604

 7.039 7.171 7.294

 7.535

 7.721 7.785 7.836 7.908 7.976

 8.192 8.242 8.388

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.144 PB 27.50084 3.50450 96.37677 Methane 

Totals : 96.37677

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P157\025B1503.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:35:40 PM Page 1 of 1

EA# 0410-59 Page 145 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 1

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 16-Apr-10, 17:28:33 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P158\025B0101.D) 1.125 1.152 - Methane 1.380 2.162

 4.802

 6.069

 6.380

 7.040 7.170 7.294

 7.535

 7.721 7.785 7.836 7.911 7.976

 8.193 8.243

 8.392

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.152 PB 26.85933 3.50453 94.12921 Methane 

Totals : 94.12921

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P158\025B0101.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:36:04 PM Page 1 of 1

EA# 0410-59 Page 146 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 1

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 16-Apr-10, 17:47:57 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P158\025B0102.D) 1.122 1.148 - Methane 1.377 2.160

 4.804

 6.070

 6.381

 7.044 7.171 7.295

 7.536

 7.723 7.836 7.912 7.977

 8.194 8.244

 8.394

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.148 PB 27.04746 3.50452 94.78834 Methane 

Totals : 94.78834

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P158\025B0102.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:36:17 PM Page 1 of 1

EA# 0410-59 Page 147 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 1

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 16-Apr-10, 18:07:13 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P158\025B0103.D) 1.122 1.149 - Methane 1.378 2.161

 4.803

 6.070

 6.381

 7.042 7.171 7.295

 7.536

 7.723 7.786 7.837 7.912 7.977

 8.193 8.242

 8.391

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.149 PB 27.06506 3.50452 94.85001 Methane 

Totals : 94.85001

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P158\025B0103.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:36:29 PM Page 1 of 1

EA# 0410-59 Page 148 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 8

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 20-Apr-10, 02:21:44 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P160\025B0801.D) 1.110 1.137 - Methane 1.365 2.145

 4.792

 6.064

 6.377

 7.041 7.168 7.292

 7.533

 7.719 7.834 7.908 7.974

 8.190 8.241 8.388

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.137 PB 27.38877 3.50451 95.98412 Methane 

Totals : 95.98412

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P160\025B0801.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:40:50 PM Page 1 of 1

EA# 0410-59 Page 149 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 8

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 20-Apr-10, 02:41:36 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P160\025B0802.D) 1.109 1.136 - Methane 1.364 2.144

 4.792

 6.064

 6.376

 7.039 7.168 7.292

 7.533

 7.720 7.782 7.834 7.907 7.974

 8.190 8.238

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.136 PB 27.59999 3.50450 96.72412 Methane 

Totals : 96.72412

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P160\025B0802.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:41:04 PM Page 1 of 1

EA# 0410-59 Page 150 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 8

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 20-Apr-10, 03:01:26 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P160\025B0803.D) 1.111 1.137 - Methane 1.365 2.146

 4.793

 6.065

 6.376

 7.042 7.168 7.291

 7.533

 7.720 7.784 7.834 7.905 7.974

 8.190 8.240

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.137 PB 27.80467 3.50449 97.44124 Methane 

Totals : 97.44124

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P160\025B0803.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:00 PM Page 1 of 1

EA# 0410-59 Page 151 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 20-Apr-10, 16:59:13 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P161\025B0901.D) 1.116 1.142 - Methane 1.370 2.149

 3.692

 4.793

 6.063

 6.375

 7.038 7.167 7.290

 7.532

 7.719 7.783 7.833 7.907 7.973

 8.189 8.239

 8.390

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.142 PB 27.25276 3.50451 95.50762 Methane 

Totals : 95.50762

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P161\025B0901.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:23 PM Page 1 of 1

EA# 0410-59 Page 152 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 20-Apr-10, 17:18:08 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P161\025B0902.D) 1.113 1.139 - Methane 1.278 1.367 2.146

 4.129

 4.791

 6.063

 6.375

 7.036 7.167 7.291

 7.532

 7.719 7.781 7.833 7.908 7.974

 8.190 8.240

 8.390

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.139 PB 27.20691 3.50451 95.34699 Methane 

Totals : 95.34699

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P161\025B0902.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:36 PM Page 1 of 1

EA# 0410-59 Page 153 of 225
=====================================================================

Acq. Operator : kam Seq. Line : 9

Acq. Instrument : Betty online Location : Vial 25

Injection Date : 20-Apr-10, 17:37:10 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Analysis Method : G:\GC2010Q2\BETTY\METHODS\GC110P104_METHANE.M

Last changed : 4/16/2010 10:16:59 AM

0 2 4 6 8 10 min

pA

0

10

20

30

40

50

60

70

80

 FID2 B, (GC110P161\025B0903.D) 1.116 1.142 - Methane 1.370 2.151

 3.717

 4.796

 6.064

 6.377

 6.599

 7.035 7.168 7.292

 7.534

 7.720 7.834 7.910 7.974

 8.190 8.241 8.389

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/16/2010 10:16:51 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [%] 

-------|------|----------|----------|----------|--|------------------

 1.142 PB 27.41913 3.50451 96.09048 Methane 

Totals : 96.09048

1 Warnings or Errors :

Warning : Calibration warnings (see calibration table listing)

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\BETTY\DATA\APR10\GC110P161\025B0903.D

Sample Name: gc110p104 #C5

Betty Reprocess 4/21/2010 12:59:47 PM Page 1 of 1

EA# 0410-59 Page 154 of 225
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : 4/27/2010 9:23:44 AM

Rel. Reference Window : 0.000 %

Abs. Reference Window : 0.100 min

Rel. Non-ref. Window : 0.000 %

Abs. Non-ref. Window : 0.050 min

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Quadratic (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: FID1 A, 

Signal 2: FID2 B, 

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ppm] 

-------|--|--|----------|----------|----------|---|--|---------------

 1.416 2 21 1.99600 4.59440e-1 4.34442 Methane 

 22 4.99000 1.16257 4.29222 

 23 9.98000 2.34951 4.24770 

 24 39.92000 9.75827 4.09089 

 25 99.80000 24.78041 4.02737 

 26 200.40000 51.53413 3.88869 

 27 1002.00000 258.23882 3.88013 

 28 4008.00000 1050.82975 3.81413 

 29 1.00200e4 2649.91488 3.78125 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Zeppo online 4/29/2010 10:39:57 AM kam Page 1 of 2

EA# 0410-59 Page 155 of 225
=====================================================================

 Calibration Curves

=====================================================================

Amount[ppm]

0 5000 10000

Area

0

500

1000

1500

2000

2500

212342526

27

28

29

Methane at exp. RT: 1.416

FID2 B, 

Correlation: 0.99933

Residual Std. Dev.: 42.86542

Formula: y = mx + b

 m: 2.53683e-1 

 b: -5.96580e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 26 : 0.000099

 Level 27 : 3.96813e-006

 Level 28 : 2.48008e-007

 Level 29 : 3.96813e-008

=====================================================================

Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Zeppo online 4/29/2010 10:39:57 AM kam Page 2 of 2

EA# 0410-59 Page 156 of 225
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : 4/27/2010 8:45:10 AM

Rel. Reference Window : 0.000 %

Abs. Reference Window : 0.100 min

Rel. Non-ref. Window : 0.000 %

Abs. Non-ref. Window : 0.050 min

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Quadratic (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: FID1 A, 

Signal 2: FID2 B, 

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ppm] 

-------|--|--|----------|----------|----------|---|--|---------------

 1.416 2 21 1.99600 4.59440e-1 4.34442 Methane 

 22 4.99000 1.16257 4.29222 

 23 9.98000 2.34951 4.24770 

 24 39.92000 9.75827 4.09089 

 25 99.80000 24.78041 4.02737 

 26 200.40000 51.53413 3.88869 

 27 1002.00000 258.23882 3.88013 

 28 4008.00000 1050.82975 3.81413 

 29 1.00200e4 2649.91488 3.78125 

 1.548 2 21 1.99800 8.61155e-1 2.32014 Ethane 

 22 4.99500 2.22649 2.24344 

 23 9.99000 4.44665 2.24664 

 24 39.96000 18.20522 2.19498 

 25 99.90000 45.39942 2.20047 

 26 199.80000 93.04124 2.14743 

 27 999.00000 468.59173 2.13192 

 28 3996.00000 1906.96370 2.09548 

 29 9990.00000 4763.75700 2.09708 

 1.862 2 21 1.99600 1.34641 1.48246 Propane 

 22 4.99000 3.38922 1.47231 

 23 9.98000 6.69953 1.48966 

 24 39.92000 27.36625 1.45873 

 25 99.80000 68.40306 1.45900 

 26 200.40000 131.11295 1.52845 

 27 1002.00000 660.00492 1.51817 

 28 4008.00000 2688.26644 1.49092 

 29 1.00200e4 6719.99756 1.49107 

Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 1 of 4

EA# 0410-59 Page 157 of 225
RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ppm] 

-------|--|--|----------|----------|----------|---|--|---------------

 2.731 2 21 2.00000 1.80194 1.10992 Butane 

 22 5.00000 4.48111 1.11579 

 23 10.00000 8.93176 1.11960 

 24 40.00000 36.20221 1.10490 

 25 100.00000 90.34531 1.10686 

 26 199.80000 177.85641 1.12338 

 27 999.00000 895.77543 1.11523 

 28 3996.00000 3646.21436 1.09593 

 29 9990.00000 9109.86035 1.09661 

 4.253 2 21 1.97800 2.18589 9.04893e-1 Pentane 

 22 4.94500 5.53759 8.92988e-1 

 23 9.89000 10.96673 9.01819e-1 

 24 39.56000 44.71787 8.84658e-1 

 25 98.90000 111.39845 8.87804e-1 

 32 501.00000 538.66221 9.30082e-1 

 33 901.80000 991.07831 9.09918e-1 

 34 2004.00000 2319.63127 8.63930e-1 

 5.842 2 21 2.06000 2.68594 7.66957e-1 Hexane 

 22 5.15000 6.66708 7.72452e-1 

 23 10.30000 13.15435 7.83011e-1 

 24 41.20000 53.59436 7.68738e-1 

 25 103.00000 133.59519 7.70986e-1 

 32 249.50000 319.81046 7.80150e-1 

 33 449.10000 587.99013 7.63788e-1 

 34 998.00000 1375.34237 7.25638e-1 

 7.003 2 21 1.94000 2.68402 7.22797e-1 Heptane 

 22 4.85000 6.87506 7.05449e-1 

 23 9.70000 13.64087 7.11098e-1 

 24 38.80000 56.91320 6.81740e-1 

 25 97.00000 141.64313 6.84820e-1 

 32 125.10000 187.12543 6.68536e-1 

 33 225.18000 343.90698 6.54770e-1 

 34 500.40000 805.27352 6.21404e-1 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

=====================================================================

 Calibration Curves

=====================================================================

Amount[ppm]

0 5000 10000

Area

0

500

1000

1500

2000

2500

212342526

27

28

29

Methane at exp. RT: 1.416

FID2 B, 

Correlation: 0.99933

Residual Std. Dev.: 42.86542

Formula: y = mx + b

 m: 2.53683e-1 

 b: -5.96580e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 26 : 0.000099

 Level 27 : 3.96813e-006

 Level 28 : 2.48008e-007

 Level 29 : 3.96813e-008

Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 2 of 4

EA# 0410-59 Page 158 of 225
Amount[ppm]

0 5000 10000

Area

0

1000

2000

3000

4000

212342526

27

28

29

Ethane at exp. RT: 1.548

FID2 B, 

Correlation: 0.99978

Residual Std. Dev.: 48.16411

Formula: y = mx + b

 m: 4.65076e-1 

 b: -7.71591e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 26 : 0.0001

 Level 27 : 4e-006

 Level 28 : 2.5e-007

 Level 29 : 4e-008

Amount[ppm]

0 5000 10000

Area

0

1000

2000

3000

4000

5000

6000

212342526

27

28

29

Propane at exp. RT: 1.862

FID2 B, 

Correlation: 0.99985

Residual Std. Dev.: 5.18186

Formula: y = mx + b

 m: 6.71077e-1 

 b: 1.25882e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 26 : 0.000099

 Level 27 : 3.96813e-006

 Level 28 : 2.48008e-007

 Level 29 : 3.96813e-008

Amount[ppm]

0 5000 10000

Area

0

1000

2000

3000

4000

5000

6000

7000

8000

212342526

27

28

29

Butane at exp. RT: 2.731

FID2 B, 

Correlation: 0.99996

Residual Std. Dev.: 41.16267

Formula: y = mx + b

 m: 9.01871e-1 

 b: -8.03223e-3 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 26 : 0.0001

 Level 27 : 4.00801e-006

 Level 28 : 2.50501e-007

 Level 29 : 4.00801e-008

Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 3 of 4

EA# 0410-59 Page 159 of 225
Amount[ppm]

0 1000 2000

Area

0

250

500

750

1000

1250

1500

1750

2000

21232425

32

33

34

Pentane at exp. RT: 4.253

FID2 B, 

Correlation: 0.99971

Residual Std. Dev.: 34.56928

Formula: y = mx + b

 m: 1.11745

 b: -2.04734e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 32 : 0.000016

 Level 33 : 4.81096e-006

 Level 34 : 9.7422e-007

Amount[ppm]

0 500 1000

Area

0

200

400

600

800

1000

1200

2122324

25

32

33

34

Hexane at exp. RT: 5.842

FID2 B, 

Correlation: 0.99965

Residual Std. Dev.: 28.59674

Formula: y = mx + b

 m: 1.30826

 b: -2.87214e-2 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 32 : 0.000068

 Level 33 : 0.000021

 Level 34 : 4.26063e-006

Amount[ppm]

0 200 400

Area

0

100

200

300

400

500

600

700

212223

24

25

32

33

34 Heptane at exp. RT: 7.003

FID2 B, 

Correlation: 0.99919

Residual Std. Dev.: 22.38684

Formula: y = mx + b

 m: 1.50120

 b: -2.77507e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 21 : 1

 Level 22 : 0.16

 Level 23 : 0.04

 Level 24 : 0.0025

 Level 25 : 0.0004

 Level 32 : 0.00024

 Level 33 : 0.000074

 Level 34 : 0.000015

=====================================================================

Method G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Gummo online 4/27/2010 9:03:46 AM stg Page 4 of 4

EA# 0410-59 Page 160 of 225
=====================================================================

Acq. Operator : Seq. Line : 5

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 01:40:29 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

 FID2 B, (GC114P103\030B0501.D) 1.416 - Methane 1.549 - Ethane 1.863 - Propane 2.730 - Butane

 4.254 - Pentane

 5.843 - Hexane

 7.004 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PB 4.66863e-1 4.44565 2.07551 Methane 

 1.549 BB 8.87043e-1 2.33722 2.07321 Ethane 

 1.863 BP 1.34239 1.47627 1.98172 Propane 

 2.730 BB 1.85906 1.11360 2.07024 Butane 

 4.254 BB 2.17213 9.03261e-1 1.96200 Pentane 

 5.843 BB 2.61647 7.72607e-1 2.02150 Hexane 

 7.004 BB 2.65465 7.35768e-1 1.95321 Heptane 

Totals : 14.13740

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0501.D

Sample Name: gc114p102 #C1 ENV(1=980,2=20)

Gummo online 4/27/2010 8:57:53 AM stg Page 1 of 1

EA# 0410-59 Page 161 of 225
=====================================================================

Acq. Operator : Seq. Line : 5

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 01:58:53 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

 FID2 B, (GC114P103\030B0502.D)

 Area: 0.450972 Area: 1.31745 1.416 - Methane 1.549 - Ethane 1.863 - Propane 2.733 - Butane

 4.256 - Pentane

 5.843 - Hexane

 7.004 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 MM 4.50972e-1 4.46340 2.01287 Methane 

 1.549 BP 8.28461e-1 2.34490 1.94266 Ethane 

 1.863 MM 1.31745 1.47627 1.94490 Propane 

 2.733 BB 1.76890 1.11377 1.97013 Butane 

 4.256 BB 2.22362 9.03134e-1 2.00823 Pentane 

 5.843 BV 2.74363 7.72375e-1 2.11911 Hexane 

 7.004 BB 2.72386 7.33999e-1 1.99931 Heptane 

Totals : 13.99722

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0502.D

Sample Name: gc114p102 #C1 ENV(1=980,2=20)

Gummo online 4/27/2010 8:57:56 AM stg Page 1 of 1

EA# 0410-59 Page 162 of 225
=====================================================================

Acq. Operator : Seq. Line : 5

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 02:17:18 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

 FID2 B, (GC114P103\030B0503.D) 1.416 - Methane 1.548 - Ethane 1.862 - Propane 2.730 - Butane

 4.253 - Pentane

 5.842 - Hexane

 7.003 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PB 4.60485e-1 4.45262 2.05037 Methane 

 1.548 BB 8.67962e-1 2.34133 2.03219 Ethane 

 1.862 BB 1.37939 1.47654 2.03673 Propane 

 2.730 BB 1.77785 1.11377 1.98011 Butane 

 4.253 BB 2.16193 9.03261e-1 1.95279 Pentane 

 5.842 BB 2.69772 7.72511e-1 2.08402 Hexane 

 7.003 BB 2.67354 7.35276e-1 1.96579 Heptane 

Totals : 14.10199

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0503.D

Sample Name: gc114p102 #C1 ENV(1=980,2=20)

Gummo online 4/27/2010 8:57:59 AM stg Page 1 of 1

EA# 0410-59 Page 163 of 225
=====================================================================

Acq. Operator : Seq. Line : 4

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 00:45:05 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

 FID2 B, (GC114P103\030B0401.D)

 Area: 1.18699 1.417 - Methane 1.550 - Ethane 1.864 - Propane

 2.733 - Butane

 4.255 - Pentane

 5.844 - Hexane

 7.005 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 MM 1.18699 4.14005 4.91420 Methane 

 1.550 BB 2.28231 2.22288 5.07330 Ethane 

 1.864 BB 3.41579 1.48465 5.07125 Propane 

 2.733 BB 4.49303 1.11079 4.99080 Butane 

 4.255 BB 5.57625 8.98180e-1 5.00848 Pentane 

 5.844 BB 6.70458 7.67648e-1 5.14676 Hexane 

 7.005 BB 6.84763 6.93129e-1 4.74629 Heptane 

Totals : 34.95107

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0401.D

Sample Name: gc114p102 #C2 ENV(1=950,2=50)

Gummo online 4/27/2010 8:57:43 AM stg Page 1 of 1

EA# 0410-59 Page 164 of 225
=====================================================================

Acq. Operator : Seq. Line : 4

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 01:03:35 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

 FID2 B, (GC114P103\030B0402.D) 1.416 - Methane 1.549 - Ethane 1.863 - Propane 2.732 - Butane

 4.253 - Pentane

 5.843 - Hexane

 7.004 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PB 1.14850 4.14669 4.76247 Methane 

 1.549 BB 2.17730 2.22638 4.84750 Ethane 

 1.863 BP 3.37285 1.48458 5.00727 Propane 

 2.732 BB 4.47439 1.11080 4.97014 Butane 

 4.253 BB 5.51015 8.98220e-1 4.94933 Pentane 

 5.843 BV 6.70256 7.67649e-1 5.14522 Hexane 

 7.004 BB 6.85960 6.93082e-1 4.75426 Heptane 

Totals : 34.43618

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0402.D

Sample Name: gc114p102 #C2 ENV(1=950,2=50)

Gummo online 4/27/2010 8:57:46 AM stg Page 1 of 1

EA# 0410-59 Page 165 of 225
=====================================================================

Acq. Operator : Seq. Line : 4

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 01:22:02 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

 FID2 B, (GC114P103\030B0403.D) 1.416 - Methane 1.549 - Ethane 1.863 - Propane 2.732 - Butane

 4.254 - Pentane

 5.843 - Hexane

 7.004 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PB 1.15222 4.14603 4.77714 Methane 

 1.549 BB 2.21987 2.22492 4.93905 Ethane 

 1.863 BP 3.37902 1.48459 5.01646 Propane 

 2.732 BB 4.47591 1.11080 4.97182 Butane 

 4.254 BB 5.52637 8.98210e-1 4.96384 Pentane 

 5.843 BB 6.59411 7.67703e-1 5.06232 Hexane 

 7.004 BB 6.91794 6.92855e-1 4.79313 Heptane 

Totals : 34.52376

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0403.D

Sample Name: gc114p102 #C2 ENV(1=950,2=50)

Gummo online 4/27/2010 8:57:49 AM stg Page 1 of 1

EA# 0410-59 Page 166 of 225
=====================================================================

Acq. Operator : Seq. Line : 3

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 23:47:43 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:49:13 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

11

12

 FID2 B, (GC114P103\030B0301.D) 1.390 1.417 - Methane 1.549 - Ethane 1.864 - Propane 2.733 - Butane

 4.255 - Pentane

 5.844 - Hexane

 7.005 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PB 2.35631 4.04173 9.52356 Methane 

 1.549 PB 4.48523 2.18718 9.80999 Ethane 

 1.864 BB 6.66628 1.48733 9.91494 Propane 

 2.733 BB 8.90265 1.10981 9.88021 Butane 

 4.255 BB 10.93730 8.96570e-1 9.80606 Pentane 

 5.844 BB 13.12355 7.66046e-1 10.05324 Hexane 

 7.005 BB 13.80329 6.79525e-1 9.37969 Heptane 

Totals : 68.36770

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0301.D

Sample Name: gc114p102 #C3 ENV(1=900,2=100)

Gummo online 4/27/2010 8:57:34 AM stg Page 1 of 1

EA# 0410-59 Page 167 of 225
=====================================================================

Acq. Operator : Seq. Line : 3

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 00:08:00 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

11

12

 FID2 B, (GC114P103\030B0302.D) 1.390 1.416 - Methane 1.549 - Ethane 1.863 - Propane 2.732 - Butane

 4.253 - Pentane

 5.843 - Hexane

 7.004 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PB 2.31135 4.04367 9.34634 Methane 

 1.549 BB 4.41684 2.18775 9.66293 Ethane 

 1.863 BP 6.74525 1.48736 10.03262 Propane 

 2.732 BB 8.92647 1.10980 9.90663 Butane 

 4.253 BB 10.94999 8.96568e-1 9.81741 Pentane 

 5.843 BB 13.15136 7.66043e-1 10.07450 Hexane 

 7.004 BB 13.31667 6.80015e-1 9.05553 Heptane 

Totals : 67.89596

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0302.D

Sample Name: gc114p102 #C3 ENV(1=900,2=100)

Gummo online 4/27/2010 8:57:37 AM stg Page 1 of 1

EA# 0410-59 Page 168 of 225
=====================================================================

Acq. Operator : Seq. Line : 3

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 00:26:33 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

6

7

8

9

10

11

12

 FID2 B, (GC114P103\030B0303.D) 1.391 1.417 - Methane 1.550 - Ethane 1.864 - Propane 2.734 - Butane

 4.255 - Pentane

 5.844 - Hexane

 7.005 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PB 2.38087 4.04070 9.62037 Methane 

 1.550 BB 4.43787 2.18757 9.70816 Ethane 

 1.864 PP 6.68704 1.48734 9.94588 Propane 

 2.734 BB 8.96616 1.10980 9.95064 Butane 

 4.255 BB 11.01288 8.96558e-1 9.87369 Pentane 

 5.844 BB 13.18814 7.66038e-1 10.10262 Hexane 

 7.005 BB 13.80264 6.79526e-1 9.37925 Heptane 

Totals : 68.58061

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0303.D

Sample Name: gc114p102 #C3 ENV(1=900,2=100)

Gummo online 4/27/2010 8:57:40 AM stg Page 1 of 1

EA# 0410-59 Page 169 of 225
=====================================================================

Acq. Operator : Seq. Line : 2

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 22:51:44 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:49:13 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

10

15

20

25

30

 FID2 B, (GC114P103\030B0201.D) 1.390 1.416 - Methane 1.549 - Ethane 1.864 - Propane 2.733 - Butane

 4.255 - Pentane

 5.844 - Hexane

 7.005 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 9.84903 3.96581 39.05936 Methane 

 1.549 VB 18.29117 2.15926 39.49534 Ethane 

 1.864 PB 27.46699 1.48946 40.91093 Propane 

 2.733 BB 36.29591 1.10905 40.25403 Butane 

 4.255 BB 44.79753 8.95304e-1 40.10739 Pentane 

 5.844 BB 53.67492 7.64782e-1 41.04963 Hexane 

 7.005 BB 56.89149 6.69382e-1 38.08217 Heptane 

Totals : 278.95885

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0201.D

Sample Name: gc114p102 #C4 ENV(1=600,2=400)

Gummo online 4/27/2010 8:57:26 AM stg Page 1 of 1

EA# 0410-59 Page 170 of 225
=====================================================================

Acq. Operator : Seq. Line : 2

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 23:10:26 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:49:13 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

10

15

20

25

30

 FID2 B, (GC114P103\030B0202.D) 1.417 - Methane 1.550 - Ethane 1.864 - Propane 2.733 - Butane

 4.255 - Pentane

 5.844 - Hexane

 7.004 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 VV 9.65206 3.96629 38.28292 Methane 

 1.550 VB 18.12866 2.15934 39.14591 Ethane 

 1.864 PP 27.29549 1.48945 40.65538 Propane 

 2.733 BB 36.22779 1.10905 40.17849 Butane 

 4.255 BB 44.76125 8.95304e-1 40.07492 Pentane 

 5.844 BB 53.62891 7.64783e-1 41.01447 Hexane 

 7.004 BB 57.12166 6.69369e-1 38.23549 Heptane 

Totals : 277.58758

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0202.D

Sample Name: gc114p102 #C4 ENV(1=600,2=400)

Gummo online 4/27/2010 8:57:29 AM stg Page 1 of 1

EA# 0410-59 Page 171 of 225
=====================================================================

Acq. Operator : Seq. Line : 2

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 23:29:05 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:49:13 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

5

10

15

20

25

30

 FID2 B, (GC114P103\030B0203.D) 1.416 - Methane 1.549 - Ethane 1.864 - Propane 2.733 - Butane

 4.255 - Pentane

 5.844 - Hexane

 7.005 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PB 9.77371 3.96599 38.76244 Methane 

 1.549 BB 18.19582 2.15930 39.29030 Ethane 

 1.864 BP 27.33627 1.48946 40.71615 Propane 

 2.733 BB 36.08293 1.10905 40.01787 Butane 

 4.255 BB 44.59484 8.95306e-1 39.92601 Pentane 

 5.844 BB 53.47924 7.64784e-1 40.90007 Hexane 

 7.005 BB 56.72643 6.69392e-1 37.97222 Heptane 

Totals : 277.58504

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0203.D

Sample Name: gc114p102 #C4 ENV(1=600,2=400)

Gummo online 4/27/2010 8:57:31 AM stg Page 1 of 1

EA# 0410-59 Page 172 of 225
=====================================================================

Acq. Operator : Seq. Line : 1

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 21:31:31 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:24:52 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P103\030B0101.D) 1.415 - Methane 1.548 - Ethane 1.861 - Propane 2.344 2.729 - Butane

 3.823

 4.250 - Pentane

 5.620

 5.840 - Hexane

 7.001 - Heptane

 7.322

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.415 VV 25.39332 3.95119 100.33385 Methane 

 1.548 VB 45.75543 2.15381 98.54860 Ethane 

 1.861 BB 68.94132 1.48987 102.71355 Propane 

 2.729 BB 90.79992 1.10890 100.68838 Butane 

 4.250 BB 111.88972 8.95058e-1 100.14784 Pentane 

 5.840 BB 134.09064 7.64537e-1 102.51727 Hexane 

 7.001 BB 141.53911 6.67439e-1 94.46875 Heptane 

Totals : 699.41824

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0101.D

Sample Name: gc114p102 #C5 ENV(1=0,2=450)

Gummo online 4/27/2010 8:57:14 AM stg Page 1 of 1

EA# 0410-59 Page 173 of 225
=====================================================================

Acq. Operator : Seq. Line : 1

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 21:55:45 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:49:13 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P103\030B0102.D) 1.416 - Methane 1.549 - Ethane 1.862 - Propane 2.346 2.730 - Butane

 3.826

 4.251 - Pentane

 5.622

 5.841 - Hexane

 7.003 - Heptane

 7.324

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 BV 24.47537 3.95154 96.71534 Methane 

 1.549 VB 45.12350 2.15386 97.18985 Ethane 

 1.862 BB 67.98146 1.48987 101.28322 Propane 

 2.730 BB 89.94241 1.10890 99.73758 Butane 

 4.251 BB 110.83764 8.95060e-1 99.20634 Pentane 

 5.841 BB 132.98512 7.64538e-1 101.67225 Hexane 

 7.003 BB 141.10301 6.67443e-1 94.17825 Heptane 

Totals : 689.98282

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0102.D

Sample Name: gc114p102 #C5 ENV(1=0,2=450)

Gummo online 4/27/2010 8:57:18 AM stg Page 1 of 1

EA# 0410-59 Page 174 of 225
=====================================================================

Acq. Operator : Seq. Line : 1

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 19-Apr-10, 22:14:21 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 9:49:13 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P103\030B0103.D) 1.415 - Methane 1.548 - Ethane 1.862 - Propane 2.347 2.731 - Butane

 3.819

 4.252 - Pentane

 5.624

 5.842 - Hexane

 7.003 - Heptane

 7.325

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.415 PV 24.47255 3.95154 96.70423 Methane 

 1.548 VB 45.31932 2.15385 97.61088 Ethane 

 1.862 BB 68.28639 1.48987 101.73761 Propane 

 2.731 BB 90.29361 1.10890 100.12698 Butane 

 4.252 BB 111.46798 8.95059e-1 99.77043 Pentane 

 5.842 BB 133.70982 7.64538e-1 102.22619 Hexane 

 7.003 BB 142.28728 6.67432e-1 94.96713 Heptane 

Totals : 693.14345

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B0103.D

Sample Name: gc114p102 #C5 ENV(1=0,2=450)

Gummo online 4/27/2010 8:57:21 AM stg Page 1 of 1

EA# 0410-59 Page 175 of 225
=====================================================================

Acq. Operator : Seq. Line : 15

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 13:26:42 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P103\030B1501.D) 1.390 1.417 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.350 2.734 - Butane

 2.904

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 51.72902 3.94648 204.14732 Methane 

 1.550 VB 92.76137 2.15197 199.62013 Ethane 

 1.864 BB 130.74174 1.49000 194.80490 Propane 

 2.734 BV 176.81252 1.10886 196.05965 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 794.63200

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1501.D

Sample Name: gc114p102 #C6 ENV(1=980,3=21.11)

Gummo online 4/27/2010 8:59:12 AM stg Page 1 of 2

EA# 0410-59 Page 176 of 225
=====================================================================

Acq. Operator : Seq. Line : 15

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 13:45:33 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P103\030B1502.D) 1.416 - Methane 1.501 1.549 - Ethane 1.863 - Propane 2.348 2.732 - Butane

 2.907

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 51.41105 3.94650 202.89389 Methane 

 1.549 VB 93.14619 2.15197 200.44756 Ethane 

 1.863 BB 131.27135 1.49000 195.59409 Propane 

 2.732 BV 178.33121 1.10886 197.74358 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 796.67912

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1502.D

Sample Name: gc114p102 #C6 ENV(1=980,3=21.11)

Gummo online 4/27/2010 8:59:15 AM stg Page 1 of 2

EA# 0410-59 Page 177 of 225
=====================================================================

Acq. Operator : Seq. Line : 15

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 14:04:36 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P103\030B1503.D) 1.390 1.417 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.349 2.733 - Butane

 2.905

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 51.46231 3.94650 203.09598 Methane 

 1.550 VB 93.21617 2.15197 200.59804 Ethane 

 1.864 BB 131.32574 1.49000 195.67515 Propane 

 2.733 BV 178.42551 1.10886 197.84814 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 797.21730

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1503.D

Sample Name: gc114p102 #C6 ENV(1=980,3=21.11)

Gummo online 4/27/2010 8:59:18 AM stg Page 1 of 2

EA# 0410-59 Page 178 of 225
=====================================================================

Acq. Operator : Seq. Line : 14

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 12:30:13 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

50

100

150

200

250

300

 FID2 B, (GC114P103\030B1401.D) 1.417 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.350 2.734 - Butane

 2.908

 3.830

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 257.67484 3.94284 1015.97116 Methane 

 1.550 VB 467.66586 2.15054 1005.73463 Ethane 

 1.864 BB 658.80994 1.49011 981.70108 Propane 

 2.734 BV 894.21729 1.10882 991.52221 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 3994.92909

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1401.D

Sample Name: gc114p102 #C7 ENV(1=900,3=105.54)

Gummo online 4/27/2010 8:59:03 AM stg Page 1 of 2

EA# 0410-59 Page 179 of 225
=====================================================================

Acq. Operator : Seq. Line : 14

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 12:49:04 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

50

100

150

200

250

300

 FID2 B, (GC114P103\030B1402.D) 1.417 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.350 2.733 - Butane

 2.905

 3.828

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 258.61874 3.94284 1019.69199 Methane 

 1.550 VV 469.24182 2.15054 1009.12324 Ethane 

 1.864 VB 660.79333 1.49011 984.65662 Propane 

 2.733 BV 896.86700 1.10882 994.46024 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 4007.93208

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1402.D

Sample Name: gc114p102 #C7 ENV(1=900,3=105.54)

Gummo online 4/27/2010 8:59:06 AM stg Page 1 of 2

EA# 0410-59 Page 180 of 225
=====================================================================

Acq. Operator : Seq. Line : 14

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 13:07:53 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

50

100

150

200

250

300

 FID2 B, (GC114P103\030B1403.D) 1.416 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.349 2.733 - Butane

 2.906

 3.827

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 258.42288 3.94284 1018.91991 Methane 

 1.550 VB 468.86749 2.15054 1008.31836 Ethane 

 1.864 PB 660.41150 1.49011 984.08763 Propane 

 2.733 BV 896.24200 1.10882 993.76724 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 4005.09314

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1403.D

Sample Name: gc114p102 #C7 ENV(1=900,3=105.54)

Gummo online 4/27/2010 8:59:09 AM stg Page 1 of 2

EA# 0410-59 Page 181 of 225
=====================================================================

Acq. Operator : Seq. Line : 13

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 11:33:27 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

200

400

600

800

1000

1200

 FID2 B, (GC114P103\030B1301.D) 1.416 - Methane 1.502 1.549 - Ethane 1.863 - Propane 2.349 2.732 - Butane

 2.906

 3.827

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 1053.24146 3.94215 4152.03857 Methane 

 1.549 VV 1910.97864 2.15027 4109.12597 Ethane 

 1.863 VB 2694.15405 1.49013 4014.65122 Propane 

 2.732 BV 3655.23804 1.10881 4052.95803 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 1.63288e4 

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1301.D

Sample Name: gc114p102 #C8 ENV(1=600,3=422.16)

Gummo online 4/27/2010 8:58:54 AM stg Page 1 of 2

EA# 0410-59 Page 182 of 225
=====================================================================

Acq. Operator : Seq. Line : 13

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 11:52:19 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

200

400

600

800

1000

1200

 FID2 B, (GC114P103\030B1302.D) 1.417 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.350 2.733 - Butane

 2.907

 3.828

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 1052.45667 3.94215 4148.94499 Methane 

 1.550 VV 1909.96826 2.15027 4106.95348 Ethane 

 1.864 VB 2693.09570 1.49013 4013.07413 Propane 

 2.733 BV 3650.95190 1.10881 4048.20554 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 1.63172e4 

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1302.D

Sample Name: gc114p102 #C8 ENV(1=600,3=422.16)

Gummo online 4/27/2010 8:58:57 AM stg Page 1 of 2

EA# 0410-59 Page 183 of 225
=====================================================================

Acq. Operator : Seq. Line : 13

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 12:11:18 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

200

400

600

800

1000

1200

 FID2 B, (GC114P103\030B1303.D) 1.417 - Methane 1.502 1.550 - Ethane 1.864 - Propane 2.350 2.733 - Butane

 2.907

 3.827

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 1046.79114 3.94215 4126.61188 Methane 

 1.550 VV 1899.94421 2.15027 4085.39991 Ethane 

 1.864 VB 2677.54956 1.49013 3989.90819 Propane 

 2.733 BV 3632.45313 1.10881 4027.69398 Butane 

 4.253 - - - Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 1.62296e4 

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1303.D

Sample Name: gc114p102 #C8 ENV(1=600,3=422.16)

Gummo online 4/27/2010 8:59:00 AM stg Page 1 of 2

EA# 0410-59 Page 184 of 225
=====================================================================

Acq. Operator : Seq. Line : 12

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 10:17:48 Inj : 1

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

500

1000

1500

2000

2500

3000

 FID2 B, (GC114P103\030B1201.D) 1.416 - Methane 1.501 1.548 - Ethane 1.861 - Propane 2.348 2.729 - Butane

 2.905

 3.825

 4.253 - Pentane 5.412 5.845 - Hexane 7.005 - Heptane

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 2666.64136 3.94202 1.05119e4 Methane 

 1.548 VV 4736.15137 2.15022 1.01838e4 Ethane 

 1.861 VV 6682.08643 1.49014 9957.23360 Propane 

 2.729 VV 9055.44922 1.10881 1.00407e4 Butane 

 4.253 BB 6.79823e-1 9.03261e-1 6.14058e-1 Pentane 

 5.845 BV 3.51739e-1 7.72607e-1 2.71756e-1 Hexane 

 7.005 BB 6.07927e-1 7.36292e-1 4.47612e-1 Heptane 

Totals : 4.06950e4 

=====================================================================

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1201.D

Sample Name: gc114p102 #C9 ENV(1=0,3=474)

Gummo online 4/27/2010 8:58:44 AM stg Page 1 of 1

EA# 0410-59 Page 185 of 225
=====================================================================

Acq. Operator : Seq. Line : 12

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 10:36:44 Inj : 2

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

500

1000

1500

2000

2500

3000

 FID2 B, (GC114P103\030B1202.D) 1.416 - Methane 1.502 1.549 - Ethane 1.862 - Propane 2.349 2.731 - Butane

 2.906

 3.827

 4.256 - Pentane 5.403

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 2645.77344 3.94202 1.04297e4 Methane 

 1.549 VV 4775.39893 2.15022 1.02682e4 Ethane 

 1.862 VV 6736.43750 1.49014 1.00382e4 Propane 

 2.731 BV 9133.31836 1.10881 1.01271e4 Butane 

 4.256 BB 5.07836e-1 9.03261e-1 4.58709e-1 Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 4.08636e4 

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1202.D

Sample Name: gc114p102 #C9 ENV(1=0,3=474)

Gummo online 4/27/2010 8:58:47 AM stg Page 1 of 2

EA# 0410-59 Page 186 of 225
=====================================================================

Acq. Operator : Seq. Line : 12

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 20-Apr-10, 10:55:39 Inj : 3

 Inj Volume : External

Sequence File : G:\GC2010Q2\GUMMO\SEQUENCE\GC114P103.S

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/19/2010 11:59:29 PM

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1-C7.M

Last changed : 4/27/2010 8:54:51 AM by stg

2 4 6 8 10 min

Norm.

0

500

1000

1500

2000

2500

3000

 FID2 B, (GC114P103\030B1203.D) 1.416 - Methane 1.501 1.548 - Ethane 1.862 - Propane 2.349 2.730 - Butane

 2.906

 3.826

 4.258 - Pentane 5.414

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 8:45:10 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 BV 2637.32983 3.94202 1.03964e4 Methane 

 1.548 VV 4779.72070 2.15022 1.02775e4 Ethane 

 1.862 VV 6741.46875 1.49014 1.00457e4 Propane 

 2.730 VV 9140.81348 1.10881 1.01354e4 Butane 

 4.258 BB 4.76975e-1 9.03261e-1 4.30833e-1 Pentane 

 5.842 - - - Hexane 

 7.003 - - - Heptane 

Totals : 4.08554e4 

1 Warnings or Errors :

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P103\030B1203.D

Sample Name: gc114p102 #C9 ENV(1=0,3=474)

Gummo online 4/27/2010 8:58:50 AM stg Page 1 of 2

EA# 0410-59 Page 187 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 1

Acq. Instrument : Gummo online Location : Vial 28

Injection Date : 24-Apr-10, 08:13:49 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

80

 FID2 B, (G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0101.D) 1.391 1.418 - Methane 1.550 1.864 2.344 2.730 3.821 4.250 5.623

 5.840

 7.001

 7.323

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.418 PV 25.57154 3.95113 101.03637 Methane 

Totals : 101.03637

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0101.D

Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Harpo 4/29/2010 11:13:29 AM stg Page 1 of 1

EA# 0410-59 Page 188 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 1

Acq. Instrument : Gummo online Location : Vial 28

Injection Date : 24-Apr-10, 08:32:24 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

80

 FID2 B, (G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0102.D) 1.416 - Methane 1.549 1.863 2.345 2.731 3.825 4.252 5.620

 5.842

 7.003

 7.323

 8.952

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 25.26629 3.95124 99.83310 Methane 

Totals : 99.83310

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0102.D

Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Harpo 4/29/2010 11:13:41 AM stg Page 1 of 1

EA# 0410-59 Page 189 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 1

Acq. Instrument : Gummo online Location : Vial 28

Injection Date : 24-Apr-10, 08:51:07 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

80

 FID2 B, (G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0103.D) 1.390 1.417 - Methane 1.550 1.864 2.344 2.732 3.821 4.253 5.626

 5.843

 7.004

 7.325

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.417 PV 24.75986 3.95143 97.83678 Methane 

Totals : 97.83678

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\028B0103.D

Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Harpo 4/29/2010 11:13:53 AM stg Page 1 of 1

EA# 0410-59 Page 190 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 30

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 26-Apr-10, 10:46:13 Inj : 1

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P106\030B3001.D) 1.391 1.418 - Methane 1.551 1.864 2.346 2.732

 3.819

 4.252

 5.623

 5.842

 7.003

 7.326

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.418 PV 23.35993 3.95200 92.31835 Methane 

Totals : 92.31835

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\030B3001.D

Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Gummo online 4/27/2010 9:29:12 AM stg Page 1 of 1

EA# 0410-59 Page 191 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 30

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 26-Apr-10, 11:04:56 Inj : 2

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P106\030B3002.D) 1.390 1.416 - Methane 1.549 1.863 2.347 2.732

 3.827

 4.254

 5.628

 5.845

 7.005

 7.327

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 23.04785 3.95213 91.08818 Methane 

Totals : 91.08818

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\030B3002.D

Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Gummo online 4/27/2010 9:29:20 AM stg Page 1 of 1

EA# 0410-59 Page 192 of 225
=====================================================================

Acq. Operator : stg Seq. Line : 30

Acq. Instrument : Gummo online Location : Vial 30

Injection Date : 26-Apr-10, 11:23:49 Inj : 3

 Inj Volume : External

Acq. Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Last changed : 4/24/2010 8:07:26 AM by stg

Analysis Method : G:\GC2010Q2\GUMMO\METHODS\GC114P103_R_C1.M

Last changed : 4/27/2010 9:23:53 AM by stg

2 4 6 8 10 min

Norm.

10

20

30

40

50

60

70

 FID2 B, (GC114P106\030B3003.D) 1.390 1.416 - Methane 1.549 1.864 2.351 2.733

 3.828

 4.255

 5.629

 5.845

 7.006

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/27/2010 9:23:44 AM

Multiplier: : 1.0000

Dilution: : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: FID2 B, 

RetTime Type Area Amt/Area Amount Grp Name

 [min] [pA*s] [ppm] 

-------|------|----------|----------|----------|--|------------------

 1.416 PV 22.67966 3.95230 89.63679 Methane 

Totals : 89.63679

=====================================================================

 *** End of Report ***

Data File G:\GC2010Q2\GUMMO\DATA\APR10\GC114P106\030B3003.D

Sample Name: gc114p102 #C5 ENV(1=0,5=450)

Gummo online 4/27/2010 9:29:28 AM stg Page 1 of 1

EA# 0410-59 Page 193 of 225
 Injection Source and Location

 Injection Source: 6890 GC Valve

 Injection Location: Dual

=============================================================================

 6890 GC METHOD

=============================================================================

OVEN

 Initial temp: 35 'C (On) Maximum temp: 250 'C

 Initial time: 2.20 min Equilibration time: 0.20 min

 Ramps:

 # Rate Final temp Final time

 1 15.00 70 0.07

 2 30.00 250 1.00

 3 0.0(Off)

 Post temp: 50 'C

 Post time: 0.00 min

 Run time: 11.60 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS)

 Mode: Split Mode: Split

 Initial temp: 160 'C (On) Initial temp: 160 'C (On)

 Pressure: 4.99 psi (On) Pressure: 5.14 psi (On)

 Split ratio: 5:1 Split ratio: 5:1

 Split flow: 10.6 mL/min Split flow: 10.4 mL/min

 Total flow: 18.9 mL/min Total flow: 18.7 mL/min

 Gas saver: Off Gas saver: Off

 Gas type: Hydrogen Gas type: Hydrogen

COLUMN 1 COLUMN 2

 Capillary Column Capillary Column

 Model Number: Restek 10970 Model Number: Restek 10198

 Rtx-624 30m x 0.32mm x 1.8um SN 92682 Rtx-1 30m x 0.32mm x 4.0um

 Max temperature: 240 'C Max temperature: 280 'C

 Nominal length: 30.0 m Nominal length: 30.0 m

 Nominal diameter: 320.00 um Nominal diameter: 320.00 um

 Nominal film thickness: 1.80 um Nominal film thickness: 4.00 um

 Mode: constant flow Mode: constant flow

 Initial flow: 2.1 mL/min Initial flow: 2.1 mL/min

 Nominal init pressure: 5.00 psi Nominal init pressure: 5.14 psi

 Average velocity: 39 cm/sec Average velocity: 40 cm/sec

 Inlet: Front Inlet Inlet: Back Inlet

 Outlet: Front Detector Outlet: Back Detector

 Outlet pressure: ambient Outlet pressure: ambient

FRONT DETECTOR (FID) BACK DETECTOR (FID)

 Temperature: 250 'C (On) Temperature: 250 'C (On)

 Hydrogen flow: 40.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On)

 Air flow: 450.0 mL/min (On) Air flow: 450.0 mL/min (On)

 Mode: Constant makeup flow Mode: Constant makeup flow

 Makeup flow: 45.0 mL/min (On) Makeup flow: 45.0 mL/min (On)

 Makeup Gas Type: Nitrogen Makeup Gas Type: Nitrogen

 Flame: On Flame: On

 Electrometer: On Electrometer: On

 Lit offset: 2.0 Lit offset: 2.0

SIGNAL 1 SIGNAL 2

 method: G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Modified on: 4/27/2010 at 8:44:53 AM

Gummo online 4/27/2010 9:02:37 AM stg Page 1 of 2

EA# 0410-59 Page 194 of 225
 Data rate: 20 Hz Data rate: 20 Hz

 Type: front detector Type: back detector

 Save Data: On Save Data: On

 Zero: 0.0 (Off) Zero: 0.0 (Off)

 Range: 0 Range: 0

 Fast Peaks: Off Fast Peaks: Off

 Attenuation: 0 Attenuation: 0

COLUMN COMP 1 COLUMN COMP 2

 Derive from front detector Derive from back detector

THERMAL AUX 1

 Use: Unspecified

 Description:

 Initial temp: 50 'C (Off)

 Initial time: 0.00 min

 # Rate Final temp Final time

 1 0.0(Off)

VALVES POST RUN

 Valve 1 Gas Sampling Post Time: 0.00 min

 Description:

 Loop Volume: 0.250 mL

 Load Time: 1.50 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

 Valve 2 Gas Sampling

 Description:

 Loop Volume: 0.250 mL

 Load Time: 1.50 min

 Inject Time: 0.50 min

 Inlet: Back Inlet

 Valve 7 Multiposition 1

 Description:

 BCD input: inverted

 Switch Time: 1.0 sec

TIME TABLE

 Time Specifier Parameter & Setpoint

 method: G:\GC2010Q2\GUMMO\METHODS\GC114P103.M

Modified on: 4/27/2010 at 8:44:53 AM

Gummo online 4/27/2010 9:02:37 AM stg Page 2 of 2

EA# 0410-59 Page 195 of 225
Sequence: G:\GC2010Q2\Gummo\sequence\GC114P103.TXT Sequence: G:\GC2010Q2\Gummo\sequence\GC114P103.TXT

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 14 gc114p102 #C5 ENV(1=0,2=450) GC114P103 4 Sample 1 Vial 30 gc114p102 #C5 ENV(1=0,2=450) GC114P103 4 Sample

2 Vial 14 gc114p102 #C4 ENV(1=600,2=400) GC114P103 3 Sample 2 Vial 30 gc114p102 #C4 ENV(1=600,2=400) GC114P103 3 Sample

3 Vial 14 gc114p102 #C3 ENV(1=900,2=100) GC114P103 3 Sample 3 Vial 30 gc114p102 #C3 ENV(1=900,2=100) GC114P103 3 Sample

4 Vial 14 gc114p102 #C2 ENV(1=950,2=50) GC114P103 3 Sample 4 Vial 30 gc114p102 #C2 ENV(1=950,2=50) GC114P103 3 Sample

5 Vial 14 gc114p102 #C1 ENV(1=980,2=20) GC114P103 3 Sample 5 Vial 30 gc114p102 #C1 ENV(1=980,2=20) GC114P103 3 Sample

6 Vial 14 gc114p102 #C0 ENV(1=1990,2=10) GC114P103 8 Sample 6 Vial 30 gc114p102 #C0 ENV(1=1990,2=10) GC114P103 8 Sample

7 Vial 14 gc114p102 #C14 ENV(1=0,5=492.93) GC114P103 4 Sample 7 Vial 30 gc114p102 #C14 ENV(1=0,5=492.93) GC114P103 4 Sample

8 Vial 14 gc114p102 #C13 ENV(1=550,5=492.93) GC114P103 3 Sample 8 Vial 30 gc114p102 #C13 ENV(1=550,5=492.93) GC114P103 3 Sample

9 Vial 14 gc114p102 #C12 ENV(1=750,5=273.85) GC114P103 3 Sample 9 Vial 30 gc114p102 #C12 ENV(1=750,5=273.85) GC114P103 3 Sample

10 Vial 14 gc114p102 #C11 ENV(1=0,4=377) GC114P103 4 Sample 10 Vial 30 gc114p102 #C11 ENV(1=0,4=377) GC114P103 4 Sample

11 Vial 14 gc114p102 #C10 ENV(1=500,4=318.69) GC114P103 3 Sample 11 Vial 30 gc114p102 #C10 ENV(1=500,4=318.69) GC114P103 3 Sample

12 Vial 14 gc114p102 #C9 ENV(1=0,3=474) GC114P103 4 Sample 12 Vial 30 gc114p102 #C9 ENV(1=0,3=474) GC114P103 4 Sample

13 Vial 14 gc114p102 #C8 ENV(1=600,3=422.16) GC114P103 3 Sample 13 Vial 30 gc114p102 #C8 ENV(1=600,3=422.16) GC114P103 3 Sample

14 Vial 14 gc114p102 #C7 ENV(1=900,3=105.54) GC114P103 3 Sample 14 Vial 30 gc114p102 #C7 ENV(1=900,3=105.54) GC114P103 3 Sample

15 Vial 14 gc114p102 #C6 ENV(1=980,3=21.11) GC114P103 3 Sample 15 Vial 30 gc114p102 #C6 ENV(1=980,3=21.11) GC114P103 3 Sample

EA# 0410-59 Page 196 of 225
Sequence: G:\GC2010Q2\Gummo\sequence\GC114P106.TXT Sequence: G:\GC2010Q2\Gummo\sequence\GC114P106.TXT

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 14 gc114p102 #C5 ENV(1=0,2=450) GC114P103 3 Sample 1 Vial 28 gc114p102 #C5 ENV(1=0,5=450) GC114P103 3 Sample

2 Vial 1 N2 Blank PAUSE 1 Sample 2 Vial 17 N2 Blank PAUSE 1 Sample

3 Vial 7 Inlet R1 0410-126 GC114P103 3 Sample 3 Vial 23 gc114p105 #A3 ENV(1=900,5=100) GC114P103 3 Sample

4 Vial 4 Outlet R1 0410-126 GC114P103 3 Sample 4 Vial 20 gc114p105 #H3 ENV(1=900,6=100) GC114P103 3 Sample

5 Vial 3 GC114P103 3 Sample 5 Vial 19 Inlet R2 0410-126 GC114P103 3 Sample

6 Vial 3 GC114P103 3 Sample 6 Vial 19 Inlet R2 0410-126 GC114P103 3 Sample

7 Vial 10 GC114P103 3 Sample 7 Vial 26 Inlet R3 0410-126 GC114P103 3 Sample

8 Vial 2 GC114P103 3 Sample 8 Vial 18 Outlet R2 0410-126 GC114P103 3 Sample

9 Vial 6 GC114P103 3 Sample 9 Vial 22 Outlet R3 0410-126 GC114P103 3 Sample

10 Vial 10 GC114P103 3 Sample 10 Vial 26 Inlet R3 0410-126 GC114P103 3 Sample

11 Vial 2 GC114P103 3 Sample 11 Vial 18 Run 1 0410-124 GC114P103 3 Sample

12 Vial 2 GC114P103 3 Sample 12 Vial 19 Run 2 0410-124 GC114P103 3 Sample

13 Vial 2 GC114P103 3 Sample 13 Vial 20 Run 3 0410-124 GC114P103 3 Sample

14 Vial 1 N2 Blank GC114P103 3 Sample 14 Vial 17 N2 Blank GC114P103 3 Sample

15 Vial 14 gc114p102 #C5 ENV(1=0,2=450) GC114P103 3 Sample 15 Vial 30 gc114p102 #C5 ENV(1=0,5=450) GC114P103 3 Sample

16 Vial 14 gc114p104 #B4 ENV(1=650,2=450) GC114P103 3 Sample 16 Vial 30 gc114p104 #B4 ENV(1=650,2=450) GC114P103 3 Sample

EA# 0410-59 Page 197 of 225
This Is The Last Page

Of This Report.

EA# 0410-59 Page 198 of 225
=============================================================================

 6890 GC METHOD

=============================================================================

OVEN

 Initial temp: -10 'C (On) Maximum temp: 330 'C

 Initial time: 4.00 min Equilibration time: 0.20 min

 Ramps:

 # Rate Final temp Final time CRYO (N2)

 1 40.00 210 0.50 Cryo: On

 2 35.00 260 0.20 Cryo fault: On

 3 0.0(Off) Cryo timeout: 20.00 min (On)

 Post temp: 50 'C Quick cryo cool: On

 Post time: 0.00 min Ambient temp: 22 'C

 Run time: 11.63 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS)

 Mode: Splitless Mode: Split

 Initial temp: 150 'C (On) Initial temp: 200 'C (On)

 Pressure: 44.00 psi (On) Pressure: 5.84 psi (On)

 Purge flow: 0.0 mL/min Split ratio: 7:1

 Purge time: 0.00 min Split flow: 22.0 mL/min

 Total flow: 15.3 mL/min Total flow: 31.7 mL/min

 Gas saver: Off Gas saver: Off

 Gas type: Helium Gas type: Hydrogen

COLUMN 1 COLUMN 2

 Packed Column Capillary Column

 Model Number: Restek 19808 Model Number: Restek 10198

 Shin Carbon ST 2m x 1mm Rtx-1 30m x 0.32mm x 4.0um SN450928

 Max temperature: 330 'C Max temperature: 280 'C

 Mode: constant pressure Nominal length: 30.0 m

 Pressure: 44.00 psi Nominal diameter: 320.00 um

 Inlet: Front Inlet Nominal film thickness: 4.00 um

 Outlet: Front Detector Mode: constant flow

 Outlet pressure: ambient Initial flow: 3.1 mL/min

 Nominal init pressure: 5.84 psi

 Average velocity: 50 cm/sec

 Inlet: Back Inlet

 Outlet: Back Detector

 Outlet pressure: ambient

FRONT DETECTOR (TCD) BACK DETECTOR (FID)

 Temperature: 275 'C (On) Temperature: 300 'C (On)

 Reference flow: 25.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On)

 Mode: Constant makeup flow Air flow: 450.0 mL/min (On)

 Makeup flow: 7.0 mL/min (On) Mode: Constant makeup flow

 Makeup Gas Type: Helium Makeup flow: 45.0 mL/min (On)

 Filament: On Makeup Gas Type: Nitrogen

 Negative polarity: On Flame: On

 Electrometer: On

 Lit offset: 2.0

SIGNAL 1 SIGNAL 2

 Data rate: 20 Hz Data rate: 20 Hz

 Type: front detector Type: back detector

 Save Data: On Save Data: On

 Zero: 0.0 (Off) Zero: 0.0 (Off)

 Range: 0 Range: 0

 Fast Peaks: Off Fast Peaks: Off

 Attenuation: 0 Attenuation: 0

 method: G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Modified on: 1/14/2010 at 4:35:53 PM

Betty online 1/14/2010 4:35:57 PM JBB Page 1 of 2

EA# 0410-59 Page 199 of 225
COLUMN COMP 1 COLUMN COMP 2

 Derive from front detector Derive from back detector

THERMAL AUX 1

 Use: Valve Box Heater

 Description:

 Initial temp: 150 'C (On)

 Initial time: 0.00 min

 # Rate Final temp Final time

 1 0.0(Off)

VALVES POST RUN

 Valve 1 Gas Sampling Post Time: 0.00 min

 Description:

 Loop Volume: 0.250 mL

 Load Time: 4.00 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

 Valve 2 Gas Sampling

 Description:

 Loop Volume: 1.000 mL

 Load Time: 4.00 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

TIME TABLE

 Time Specifier Parameter & Setpoint

 1.60 Front Detector Polarity: Off

 GC Injector

 Front Injector:

 Injector not configured, use these parameters if it becomes configured

 Sample Washes 0

 Sample Pumps 0

 Injection Volume 1.00 microliters

 Syringe Size 10.0 microliters

 PostInj Solvent A Washes 0

 PostInj Solvent B Washes 0

 Viscosity Delay 0 seconds

 Plunger Speed Fast

 Back Injector:

 Injector not configured, use these parameters if it becomes configured

 Sample Washes 0

 Sample Pumps 0

 Injection Volume 1.00 microliters

 Syringe Size 10.0 microliters

 PostInj Solvent A Washes 0

 PostInj Solvent B Washes 0

 Viscosity Delay 0 seconds

 Plunger Speed Fast

 method: G:\GC2010Q1\BETTY\METHODS\GC110P104.M

Modified on: 1/14/2010 at 4:35:53 PM

Betty online 1/14/2010 4:35:57 PM JBB Page 2 of 2

EA# 0410-59 Page 200 of 225
 Injection Source and Location

 Injection Source: 6890 GC Valve

 Injection Location: Dual

=============================================================================

 6890 GC METHOD

=============================================================================

OVEN

 Initial temp: -10 'C (On) Maximum temp: 330 'C

 Initial time: 4.00 min Equilibration time: 0.20 min

 Ramps:

 # Rate Final temp Final time CRYO (N2)

 1 40.00 210 0.50 Cryo: On

 2 35.00 260 0.20 Cryo fault: On

 3 0.0(Off) Cryo timeout: 20.00 min (On)

 Post temp: 50 'C Quick cryo cool: On

 Post time: 0.00 min Ambient temp: 22 'C

 Run time: 11.63 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS)

 Mode: Splitless Mode: Split

 Initial temp: 150 'C (On) Initial temp: 200 'C (On)

 Pressure: 44.00 psi (On) Pressure: 5.83 psi (On)

 Purge flow: 0.0 mL/min Split ratio: 7:1

 Purge time: 0.00 min Split flow: 21.9 mL/min

 Total flow: 15.3 mL/min Total flow: 31.7 mL/min

 Gas saver: Off Gas saver: Off

 Gas type: Helium Gas type: Hydrogen

COLUMN 1 COLUMN 2

 Packed Column Capillary Column

 Model Number: Restek 19808 Model Number: Restek 10198

 Shin Carbon ST 2m x 1mm Rtx-1 30m x 0.32mm x 4.0um SN450928

 Max temperature: 330 'C Max temperature: 280 'C

 Mode: constant pressure Nominal length: 30.0 m

 Pressure: 44.00 psi Nominal diameter: 320.00 um

 Inlet: Front Inlet Nominal film thickness: 4.00 um

 Outlet: Front Detector Mode: constant flow

 Outlet pressure: ambient Initial flow: 3.1 mL/min

 Nominal init pressure: 5.83 psi

 Average velocity: 50 cm/sec

 Inlet: Back Inlet

 Outlet: Back Detector

 Outlet pressure: ambient

FRONT DETECTOR (TCD) BACK DETECTOR (FID)

 Temperature: 275 'C (On) Temperature: 300 'C (On)

 Reference flow: 25.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On)

 Mode: Constant makeup flow Air flow: 450.0 mL/min (On)

 Makeup flow: 7.0 mL/min (On) Mode: Constant makeup flow

 Makeup Gas Type: Helium Makeup flow: 45.0 mL/min (On)

 Filament: On Makeup Gas Type: Nitrogen

 Negative polarity: On Flame: On

 Electrometer: On

 Lit offset: 2.0

SIGNAL 1 SIGNAL 2

 method: G:\GC2010Q1\BETTY\METHODS\GC110P128FAST.M

Modified on: 3/10/2010 at 4:14:00 PM

Betty online 3/11/2010 9:53:15 AM stg Page 1 of 2

EA# 0410-59 Page 201 of 225
 Data rate: 20 Hz Data rate: 20 Hz

 Type: front detector Type: back detector

 Save Data: On Save Data: On

 Zero: 0.0 (Off) Zero: 0.0 (Off)

 Range: 0 Range: 0

 Fast Peaks: Off Fast Peaks: Off

 Attenuation: 0 Attenuation: 0

COLUMN COMP 1 COLUMN COMP 2

 Derive from front detector Derive from back detector

THERMAL AUX 1

 Use: Valve Box Heater

 Description:

 Initial temp: 150 'C (On)

 Initial time: 0.00 min

 # Rate Final temp Final time

 1 0.0(Off)

VALVES POST RUN

 Valve 1 Gas Sampling Post Time: 0.00 min

 Description:

 Loop Volume: 0.250 mL

 Load Time: 1.50 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

 Valve 2 Gas Sampling

 Description:

 Loop Volume: 1.000 mL

 Load Time: 4.00 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

TIME TABLE

 Time Specifier Parameter & Setpoint

 1.60 Front Detector Polarity: Off

 GC Injector

 Front Injector:

 Injector not configured, use these parameters if it becomes configured

 Sample Washes 0

 Sample Pumps 0

 Injection Volume 1.00 microliters

 Syringe Size 10.0 microliters

 PostInj Solvent A Washes 0

 PostInj Solvent B Washes 0

 Viscosity Delay 0 seconds

 Plunger Speed Fast

 Back Injector:

 Injector not configured, use these parameters if it becomes configured

 Sample Washes 0

 Sample Pumps 0

 Injection Volume 1.00 microliters

 Syringe Size 10.0 microliters

 PostInj Solvent A Washes 0

 PostInj Solvent B Washes 0

 Viscosity Delay 0 seconds

 Plunger Speed Fast

 method: G:\GC2010Q1\BETTY\METHODS\GC110P128FAST.M

Modified on: 3/10/2010 at 4:14:00 PM

Betty online 3/11/2010 9:53:15 AM stg Page 2 of 2

EA# 0410-59 Page 202 of 225
 Injection Source and Location

 Injection Source: 6890 GC Valve

 Injection Location: Dual

=============================================================================

 6890 GC METHOD

=============================================================================

OVEN

 Initial temp: -10 'C (On) Maximum temp: 330 'C

 Initial time: 4.00 min Equilibration time: 0.20 min

 Ramps:

 # Rate Final temp Final time CRYO (N2)

 1 40.00 210 0.50 Cryo: On

 2 35.00 260 0.20 Cryo fault: On

 3 0.0(Off) Cryo timeout: 20.00 min (On)

 Post temp: 50 'C Quick cryo cool: On

 Post time: 0.00 min Ambient temp: 22 'C

 Run time: 11.63 min

FRONT INLET (SPLIT/SPLITLESS) BACK INLET (SPLIT/SPLITLESS)

 Mode: Splitless Mode: Split

 Initial temp: 150 'C (On) Initial temp: 200 'C (On)

 Pressure: 44.00 psi (On) Pressure: 5.83 psi (On)

 Purge flow: 0.0 mL/min Split ratio: 7:1

 Purge time: 0.00 min Split flow: 21.9 mL/min

 Total flow: 15.3 mL/min Total flow: 31.7 mL/min

 Gas saver: Off Gas saver: Off

 Gas type: Helium Gas type: Hydrogen

COLUMN 1 COLUMN 2

 Packed Column Capillary Column

 Model Number: Restek 19808 Model Number: Restek 10198

 Shin Carbon ST 2m x 1mm Rtx-1 30m x 0.32mm x 4.0um SN450928

 Max temperature: 330 'C Max temperature: 280 'C

 Mode: constant pressure Nominal length: 30.0 m

 Pressure: 44.00 psi Nominal diameter: 320.00 um

 Inlet: Front Inlet Nominal film thickness: 4.00 um

 Outlet: Front Detector Mode: constant flow

 Outlet pressure: ambient Initial flow: 3.1 mL/min

 Nominal init pressure: 5.83 psi

 Average velocity: 50 cm/sec

 Inlet: Back Inlet

 Outlet: Back Detector

 Outlet pressure: ambient

FRONT DETECTOR (TCD) BACK DETECTOR (FID)

 Temperature: 275 'C (On) Temperature: 300 'C (On)

 Reference flow: 25.0 mL/min (On) Hydrogen flow: 40.0 mL/min (On)

 Mode: Constant makeup flow Air flow: 450.0 mL/min (On)

 Makeup flow: 7.0 mL/min (On) Mode: Constant makeup flow

 Makeup Gas Type: Helium Makeup flow: 45.0 mL/min (On)

 Filament: On Makeup Gas Type: Nitrogen

 Negative polarity: On Flame: On

 Electrometer: On

 Lit offset: 2.0

SIGNAL 1 SIGNAL 2

 method: G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/16/2010 9:56:23 AM kam Page 1 of 2

EA# 0410-59 Page 203 of 225
 Data rate: 20 Hz Data rate: 20 Hz

 Type: front detector Type: back detector

 Save Data: On Save Data: On

 Zero: 0.0 (Off) Zero: 0.0 (Off)

 Range: 0 Range: 0

 Fast Peaks: Off Fast Peaks: Off

 Attenuation: 0 Attenuation: 0

COLUMN COMP 1 COLUMN COMP 2

 Derive from front detector Derive from back detector

THERMAL AUX 1

 Use: Valve Box Heater

 Description:

 Initial temp: 150 'C (On)

 Initial time: 0.00 min

 # Rate Final temp Final time

 1 0.0(Off)

VALVES POST RUN

 Valve 1 Gas Sampling Post Time: 0.00 min

 Description:

 Loop Volume: 0.250 mL

 Load Time: 1.50 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

 Valve 2 Gas Sampling

 Description:

 Loop Volume: 1.000 mL

 Load Time: 4.00 min

 Inject Time: 0.50 min

 Inlet: Front Inlet

TIME TABLE

 Time Specifier Parameter & Setpoint

 1.60 Front Detector Polarity: Off

 GC Injector

 Front Injector:

 Injector not configured, use these parameters if it becomes configured

 Sample Washes 0

 Sample Pumps 0

 Injection Volume 1.00 microliters

 Syringe Size 10.0 microliters

 PostInj Solvent A Washes 0

 PostInj Solvent B Washes 0

 Viscosity Delay 0 seconds

 Plunger Speed Fast

 Back Injector:

 Injector not configured, use these parameters if it becomes configured

 Sample Washes 0

 Sample Pumps 0

 Injection Volume 1.00 microliters

 Syringe Size 10.0 microliters

 PostInj Solvent A Washes 0

 PostInj Solvent B Washes 0

 Viscosity Delay 0 seconds

 Plunger Speed Fast

 method: G:\GC2010Q1\BETTY\METHODS\GC110P144FAST.M

Betty online 4/16/2010 9:56:23 AM kam Page 2 of 2

EA# 0410-59 Page 204 of 225
Sequence: G:\GC2010Q1\betty\sequence\gc110p104.txt Sequence: G:\GC2010Q1\betty\sequence\gc110p104.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 12 gc110p104 #FG3 ENV(1=0,2=377.39) GC110P104 3 Sample 1 Vial 28 gc110p104 #FG3 ENV(1=0,2=377.39) GC110P104 3 Sample

2 Vial 12 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104 3 Sample 2 Vial 28 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104 3 Sample

3 Vial 12 gc110p104 #FG1 ENV(1=636,2=83.86) GC110P104 3 Sample 3 Vial 28 gc110p104 #FG1 ENV(1=636,2=83.86) GC110P104 3 Sample

4 Vial 12 gc110p104 #FG6 ENV(1=0,3=358.71) GC110P104 3 Sample 4 Vial 28 gc110p104 #FG6 ENV(1=0,3=358.71) GC110P104 3 Sample

5 Vial 12 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104 3 Sample 5 Vial 28 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104 3 Sample

6 Vial 12 gc110p104 #FG4 ENV(1=636,3=79.71) GC110P104 3 Sample 6 Vial 28 gc110p104 #FG4 ENV(1=636,3=79.71) GC110P104 3 Sample

7 Vial 12 gc110p104 #C5 ENV(1=0,4=450) GC110P104 3 Sample 7 Vial 28 gc110p104 #C5 ENV(1=0,4=450) GC110P104 3 Sample X

8 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104 3 Sample 8 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104 3 Sample

9 Vial 12 gc110p104 #C3 ENV(1=636,4=100) GC110P104 3 Sample 9 Vial 28 gc110p104 #C3 ENV(1=636,4=100) GC110P104 3 Sample

10 Vial 12 gc110p104 #C2 ENV(1=692.53,4=20) GC110P104 3 Sample 10 Vial 28 gc110p104 #C2 ENV(1=692.53,4=20) GC110P104 3 Sample

11 Vial 12 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 3 Sample 11 Vial 28 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 3 Sample

12 Vial 12 gc110p104 #C7 ENV(1=0,5=474.93) GC110P104 3 Sample 12 Vial 28 gc110p104 #C7 ENV(1=0,5=474.93) GC110P104 3 Sample

13 Vial 12 gc110p104 #C6 ENV(1=636,5=105.54) GC110P104 3 Sample 13 Vial 28 gc110p104 #C6 ENV(1=636,5=105.54) GC110P104 3 Sample

14 Vial 12 gc110p104 #C9 ENV(1=0,6=526.07) GC110P104 3 Sample 14 Vial 28 gc110p104 #C9 ENV(1=0,6=526.07) GC110P104 3 Sample X

15 Vial 12 gc110p104 #C8 ENV(1=318,6=526.07) GC110P104 3 Sample 15 Vial 28 gc110p104 #C8 ENV(1=318,6=526.07) GC110P104 3 Sample X

16 Vial 12 gc110p104 #FG7 ENV(1=692.53,2=16.77) GC110P104 7 Sample 2,3 16 Vial 28 gc110p104 #FG7 ENV(1=692.53,2=16.77) GC110P104 7 Sample

17 Vial 12 gc110p104 #FG8 ENV(1=692.53,3=15.94) GC110P104 7 Sample 17 Vial 28 gc110p104 #FG8 ENV(1=692.53,3=15.94) GC110P104 7 Sample

18 Vial 3 H2 UHP Matheson AX13607 #9 GC110P104 3 Sample 18 Vial 19 H2 UHP Matheson AX13607 #9 GC110P104 3 Sample

19 Vial 16 gc110p104 #C5 A019379 #9 GC110P104 3 Sample 19 Vial 32 gc110p104 #C5 A019379 #9 GC110P104 3 Sample

20 Vial 6 CO2 99.8+% Adlrich 01629AJ #9 GC110P104 3 Sample 20 Vial 22 CO2 99.8+% Adlrich 01629AJ #9 GC110P104 3 Sample

21 Vial 10 CO 99+% Aldrich 03611BJ #9 GC110P104 3 Sample 21 Vial 26 CO 99+% Aldrich 03611BJ #9 GC110P104 3 Sample

22 Vial 4 CH4 99+% Aldrich MKBB4558 #9 GC110P104 3 Sample 22 Vial 20 CH4 99+% Aldrich MKBB4558 #9 GC110P104 3 Sample

23 Vial 12 gc110p104 #C9 ENV(1=0,6=467.62) GC110P104 3 Sample 23 Vial 28 gc110p104 #C9 ENV(1=0,6=467.62) GC110P104 3 Sample

24 Vial 12 gc110p104 #C8 ENV(1=424.6,6=467.62) GC110P104 3 Sample 24 Vial 28 gc110p104 #C8 ENV(1=424.6,6=467.62) GC110P104 3 Sample

25 Vial 12 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample leak 25 Vial 28 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample

26 Vial 12 H2 40% AX13607 ENV(1=424,5=396) #10 GC110P104 3 Sample 26 Vial 28 H2 40% AX13607 ENV(1=424,5=396) #10 GC110P104 3 Sample

27 Vial 3 House cryo N2 GC110P104 3 Sample leak 27 Vial 19 House cryo N2 GC110P104 3 Sample

28 Vial 12 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 7 Sample 28 Vial 28 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 7 Sample X

29 Vial 12 gc110p106 #A4 ENV(1=0,5=450) GC110P104 3 Sample 29 Vial 28 gc110p106 #A4 ENV(1=0,5=450) GC110P104 3 Sample

30 Vial 12 gc110p106 #A3 ENV(1=494.66,5=300) GC110P104 3 Sample 30 Vial 28 gc110p106 #A3 ENV(1=494.66,5=300) GC110P104 3 Sample

31 Vial 12 gc110p106 #A2 ENV(1=636,5=100) GC110P104 3 Sample 31 Vial 28 gc110p106 #A2 ENV(1=636,5=100) GC110P104 3 Sample

32 Vial 12 gc110p106 #A1 ENV(1=692.53,5=20) GC110P104 3 Sample 32 Vial 28 gc110p106 #A1 ENV(1=692.53,5=20) GC110P104 3 Sample

33 Vial 12 gc110p106 #B5 ENV(1=0,6=450) GC110P104 3 Sample 33 Vial 28 gc110p106 #B5 ENV(1=0,6=450) GC110P104 3 Sample

34 Vial 12 gc110p106 #B4 ENV(1=565.33,6=200) GC110P104 3 Sample 34 Vial 28 gc110p106 #B4 ENV(1=565.33,6=200) GC110P104 3 Sample

35 Vial 12 gc110p106 #B3 ENV(1=671.33,6=50) GC110P104 3 Sample 35 Vial 28 gc110p106 #B3 ENV(1=671.33,6=50) GC110P104 3 Sample

36 Vial 12 gc110p106 #B2 ENV(1=692.53,6=20) GC110P104 3 Sample 36 Vial 28 gc110p106 #B2 ENV(1=692.53,6=20) GC110P104 3 Sample

37 Vial 12 gc110p106 #B1 ENV(1=1406.26,6=10) GC110P104 3 Sample 37 Vial 28 gc110p106 #B1 ENV(1=1406.26,6=10) GC110P104 3 Sample

38 Vial 3 House cryo N2 GC110P104 3 Sample 38 Vial 19 House cryo N2 GC110P104 3 Sample

39 Vial 12 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample 39 Vial 28 O2 AX38764 ENV(1=0,6=450) #9 GC110P104 3 Sample

40 Vial 12 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 11 Sample 40 Vial 28 gc110p104 #C1 ENV(1=1406.26,4=10) GC110P104 11 Sample MDL5-11

line 7 inj 3 accidentally overwritten by partial sequence - rerun line 19

lines 14 and 15 bad EI command -- environics did not run -- rerun lines 23 + 24

lines 25 , 28, and 40 contamination due to sample cans on ports 8, 9, 11

line 39 Matheson Oxygen zero grade lot 1059413064 cylinder AX38764 >99.8%

EA# 0410-59 Page 205 of 225
Sequence: G:\GC2010Q1\betty\sequence\gc110p106.txt Sequence: G:\GC2010Q1\betty\sequence\gc110p106.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 12 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample 1 Vial 28 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample

2 Vial 12 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample 2 Vial 28 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample

3 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 3 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample

4 Vial 8 1209-01 Run 1 can 1374 GC110P104A 3 Sample 4 Vial 24 1209-01 Run 1 can 1374 GC110P104A 3 Sample

5 Vial 9 1209-01 Run 2 can 1093 GC110P104A 3 Sample 5 Vial 25 1209-01 Run 2 can 1093 GC110P104A 3 Sample

6 Vial 11 1209-01 Run 3 can 1372 GC110P104A 3 Sample 6 Vial 27 1209-01 Run 3 can 1372 GC110P104A 3 Sample

7 Vial 3 1109-84 Run 1 can 1362 GC110P104A 3 Sample 7 Vial 19 1109-84 Run 1 can 1362 GC110P104A 3 Sample

8 Vial 10 1109-84 Run 2 can 1370 GC110P104A 3 Sample 8 Vial 26 1109-84 Run 2 can 1370 GC110P104A 3 Sample

9 Vial 7 1109-84 Run 3 can 1012 GC110P104A 3 Sample 9 Vial 23 1109-84 Run 3 can 1012 GC110P104A 3 Sample

10 Vial 12 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample 10 Vial 28 gc110p104 #FG2 ENV(1=318,2=377.39) GC110P104A 2 Sample

11 Vial 12 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample 11 Vial 28 gc110p104 #FG5 ENV(1=318.2,3=358.71) GC110P104A 2 Sample

12 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 12 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample

13 Vial 12 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample 13 Vial 28 gc110p104 #C4 ENV(1=424,4=400) GC110P104A 3 Sample

14 Vial 1 He Blank GC110P104A 3 Sample 14 Vial 17 He Blank GC110P104A 3 Sample

15 Vial 12 gc110p106 #D4 ENV(1=0,6=450) GC110P104A 3 Sample 15 Vial 28 gc110p106 #D4 ENV(1=0,6=450) GC110P104A 3 Sample

16 Vial 12 gc110p106 #D3 ENV(1=494.66,6=300) GC110P104A 3 Sample 16 Vial 28 gc110p106 #D3 ENV(1=494.66,6=300) GC110P104A 3 Sample

17 Vial 12 gc110p106 #D2 ENV(1=678.4,6=40) GC110P104A 3 Sample 17 Vial 28 gc110p106 #D2 ENV(1=678.4,6=40) GC110P104A 3 Sample

18 Vial 12 gc110p106 #D1 ENV(1=699.6,6=10) GC110P104A 3 Sample 18 Vial 28 gc110p106 #D1 ENV(1=699.6,6=10) GC110P104A 3 Sample

19 Vial 8 gc110p106 #E3 GC110P104A 3 Sample 19 Vial 24 gc110p106 #E3 GC110P104A 3 Sample

20 Vial 9 gc110p106 #E2 GC110P104A 3 Sample 20 Vial 25 gc110p106 #E2 GC110P104A 3 Sample

21 Vial 11 gc110p106 #E1 GC110P104A 3 Sample 21 Vial 27 gc110p106 #E1 GC110P104A 3 Sample

22 Vial 11 gc110p106 #E0 GC110P104A 3 Sample 22 Vial 27 gc110p106 #E0 GC110P104A 3 Sample

EA# 0410-59 Page 206 of 225
Sequence: G:\GC2010Q1\Betty\sequence\gc110p150.txt Sequence: G:\GC2010Q1\Betty\sequence\gc110p150.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 15 #1172 0410-27 GC110P144FAST 2 Sample 1 Vial 31 #1172 0410-27 GC110P144FAST 2 Sample

2 Vial 16 #1626 0410-27 GC110P144FAST 2 Sample 2 Vial 32 #1626 0410-27 GC110P144FAST 2 Sample

3 Vial 12 #1326 0410-27 GC110P144FAST 2 Sample 3 Vial 28 #1326 0410-27 GC110P144FAST 2 Sample

4 Vial 10 #1628 0410-27 GC110P144FAST 2 Sample 4 Vial 26 #1628 0410-27 GC110P144FAST 2 Sample

5 Vial 8 #1624 0410-27 GC110P144FAST 2 Sample 5 Vial 24 #1624 0410-27 GC110P144FAST 2 Sample

6 Vial 14 gc110p104 #FG6 ENV(1=0,2=358) GC110P144FAST 2 Sample 6 Vial 30 gc110p104 #FG6 ENV(1=0,2=358) GC110P144FAST 2 Sample

7 Vial 9 gc111p104 #C5 GC110P144FAST 3 Sample 7 Vial 25 gc111p104 #C5 GC110P144FAST 3 Sample

8 Vial 2 pause PAUSE 1 Sample 8 Vial 18 pause PAUSE 1 Sample

9 Vial 9 gc111p104 #C5 GC110P144FAST 3 Sample 9 Vial 25 gc111p104 #C5 GC110P144FAST 3 Sample

10 Vial 2 pause PAUSE 1 Sample 10 Vial 18 pause PAUSE 1 Sample

11 Vial 8 R1 Stack 0410-59 GC110P144FAST 3 Sample 11 Vial 24 R1 Stack 0410-59 GC110P144FAST 3 Sample

12 Vial 13 R2 Stack 0410-59 GC110P144FAST 3 Sample 12 Vial 29 R2 Stack 0410-59 GC110P144FAST 3 Sample

13 Vial 10 R3 Stack 0410-59 GC110P144FAST 3 Sample 13 Vial 26 R3 Stack 0410-59 GC110P144FAST 3 Sample

14 Vial 11 W7-M18-1 0410-56 GC110P144FAST 3 Sample 14 Vial 27 W7-M18-1 0410-56 GC110P144FAST 3 Sample

15 Vial 8 W7-M18-2 0410-56 GC110P144FAST 3 Sample 15 Vial 24 W7-M18-2 0410-56 GC110P144FAST 3 Sample

16 Vial 13 W7-M18-3 0410-56 GC110P144FAST 3 Sample 16 Vial 29 W7-M18-3 0410-56 GC110P144FAST 3 Sample

17 Vial 12 R1 Ambient 0410-59 GC110P144FAST 3 Sample 17 Vial 28 R1 Ambient 0410-59 GC110P144FAST 3 Sample

18 Vial 15 R2 Ambient 0410-59 GC110P144FAST 3 Sample 18 Vial 31 R2 Ambient 0410-59 GC110P144FAST 3 Sample

19 Vial 16 R3 Ambient 0410-59 GC110P144FAST 3 Sample 19 Vial 32 R3 Ambient 0410-59 GC110P144FAST 3 Sample

20 Vial 1 He Blank GC110P144FAST 3 Sample 20 Vial 17 He Blank GC110P144FAST 3 Sample

21 Vial 9 gc111p104 #C5 GC110P144FAST 3 Sample 21 Vial 25 gc111p104 #C5 GC110P144FAST 3 Sample

22 Vial 2 pause PAUSE 1 Sample 22 Vial 18 pause PAUSE 1 Sample

EA# 0410-59 Page 207 of 225
Sequence: G:\GC2010Q2\Betty\sequence\gc110p154.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p154.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 1 He Blank GC110P104FAST 3 Sample 1 Vial 17 He Blank GC110P104FAST 3 Sample

2 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 2 Vial 29 Unit1 R1 Spk 0410-59 GC110P104FAST 3 Sample

3 Vial 13 Unit1 R1 Spk 0410-59 GC110P104FAST 3 Sample 3 Vial 29 Unit1 R1 Spk 0410-59 GC110P144FAST 3 Sample

4 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 4 Vial 29 gc110p104 #C5 GC110P144FAST 3 Sample

5 Vial 2 pause PAUSE 1 Sample 5 Vial 18 pause PAUSE 1 Sample

6 Vial 10 GC110P144FAST 3 Sample 6 Vial 26 GC110P144FAST 3 Sample

7 Vial 10 GC110P144FAST 3 Sample 7 Vial 26 GC110P144FAST 3 Sample

8 Vial 10 GC110P144FAST 3 Sample 8 Vial 26 GC110P144FAST 3 Sample

9 Vial 13 R1 Spk 0410-56 GC110P144FAST 3 Sample 9 Vial 29 R1 Spk 0410-56 GC110P144FAST 3 Sample

10 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 10 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

EA# 0410-59 Page 208 of 225
Sequence: G:\GC2010Q2\Betty\sequence\gc110p157.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p157.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 1 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

2 Vial 2 pause PAUSE 1 Sample 2 Vial 18 pause PAUSE 1 Sample

3 Vial 13 THC R1 0410-80 GC110P144FAST 3 Sample 3 Vial 29 THC R1 0410-80 GC110P144FAST 3 Sample

4 Vial 8 THC R2 0410-80 GC110P144FAST 3 Sample 4 Vial 24 THC R2 0410-80 GC110P144FAST 3 Sample

5 Vial 16 THC R3 0410-80 GC110P144FAST 3 Sample 5 Vial 32 THC R3 0410-80 GC110P144FAST 3 Sample

6 Vial 14 N2 Blank ENV(1=450,2=0) GC110P144FAST 3 Sample 6 Vial 30 N2 Blank ENV(1=450,2=0) GC110P144FAST 3 Sample

7 Vial 2 pause PAUSE 1 Sample 7 Vial 18 pause PAUSE 1 Sample

8 Vial 10 Run 1 lean 0410-85 GC110P144FAST 3 Sample 8 Vial 26 Run 1 lean 0410-85 GC110P144FAST 3 Sample

9 Vial 10 Run 2 lean 0410-85 GC110P144FAST 3 Sample 9 Vial 26 Run 2 lean 0410-85 GC110P144FAST 3 Sample

10 Vial 15 Run 2 lean 0410-85 GC110P144FAST 3 Sample 10 Vial 30 Run 3 lean 0410-85 GC110P144FAST 3 Sample

11 Vial 14 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 1 Sample 11 Vial 30 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 1 Sample

12 Vial 2 pause PAUSE 1 Sample 12 Vial 18 pause PAUSE 1 Sample

13 Vial 14 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 2 Sample 13 Vial 30 gc110p104 #B3 ENV(1=900,2=111.98) GC110P144FAST 2 Sample

14 Vial 2 pause PAUSE 1 Sample 14 Vial 18 pause PAUSE 1 Sample

15 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 15 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

16 Vial 8 21-08 Run 3 Spk 0410-60 GC110P144FAST 3 Sample 16 Vial 24 21-08 Run 3 Spk 0410-60 GC110P144FAST 3 Sample

17 Vial 16 1045-2002-R2 0410-57 GC110P144FAST 3 Sample 17 Vial 32 1045-2002-R2 0410-57 GC110P144FAST 3 Sample

18 Vial 12 R1 Backup 0410-59 GC110P144FAST 3 Sample 18 Vial 28 R1 Backup 0410-59 GC110P144FAST 3 Sample

19 Vial 13 VP-1 0310-35 GC110P144FAST 3 Sample 19 Vial 29 VP-1 0310-35 GC110P144FAST 3 Sample

20 Vial 2 pause PAUSE 1 Sample 20 Vial 8 VP-2 0310-35 GC110P144FAST 3 Sample

21 Vial 8 VP-2 0310-35 GC110P144FAST 3 Sample 21 Vial 16 VP-3 0310-35 GC110P144FAST 3 Sample

22 Vial 16 VP-3 0310-35 GC110P144FAST 3 Sample 22 Vial 18 pause PAUSE 1 Sample

EA# 0410-59 Page 209 of 225
Sequence: G:\GC2010Q2\Betty\sequence\gc110p158.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p158.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 1 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

2 Vial 3 1045-2002-R2 Spk 0410-60 GC110P144FAST 3 Sample 2 Vial 19 1045-2002-R2 Spk 0410-60 GC110P144FAST 3 Sample

3 Vial 8 VP-2 0310-35 GC110P144FAST 3 Sample 3 Vial 24 VP-2 0310-35 GC110P144FAST 3 Sample

4 Vial 16 VP-3 0310-35 GC110P144FAST 3 Sample 4 Vial 32 VP-3 0310-35 GC110P144FAST 3 Sample

5 Vial 13 EPN 03 1 0410-93 GC110P144FAST 3 Sample 5 Vial 29 EPN 03 1 0410-93 GC110P144FAST 3 Sample

6 Vial 12 EPN 03 2 0410-93 GC110P144FAST 3 Sample 6 Vial 28 EPN 03 2 0410-93 GC110P144FAST 3 Sample

7 Vial 7 EPN 03 3 0410-93 GC110P144FAST 3 Sample 7 Vial 23 EPN 03 3 0410-93 GC110P144FAST 3 Sample

8 Vial 5 EPN 04 1 0410-93 GC110P144FAST 3 Sample 8 Vial 21 EPN 04 1 0410-93 GC110P144FAST 3 Sample

9 Vial 11 EPN 04 2 0410-93 GC110P144FAST 3 Sample 9 Vial 27 EPN 04 2 0410-93 GC110P144FAST 3 Sample

10 Vial 4 EPN 04 3 0410-93 GC110P144FAST 3 Sample 10 Vial 20 EPN 04 3 0410-93 GC110P144FAST 3 Sample

11 Vial 6 R3 0410-59 GC110P144FAST 3 Sample 11 Vial 22 R3 0410-59 GC110P144FAST 3 Sample

12 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 12 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

13 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 13 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample

14 Vial 14 N2 Blank ENV(1=450,2=0)) GC110P144FAST 3 Sample 14 Vial 30 N2 Blank ENV(1=450,2=0)) GC110P144FAST 3 Sample

15 Vial 8 THC R1 Spk 0410-80 GC110P104FAST 3 Sample 15 Vial 24 THC R1 Spk 0410-80 GC110P104FAST 3 Sample

16 Vial 10 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample 16 Vial 26 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample

17 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 17 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample

18 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 18 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

19 Vial 2 pause PAUSE 1 Sample 19 Vial 18 pause PAUSE 1 Sample

20 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 20 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample

21 Vial 8 THC R1 Spk 0410-80 GC110P104FAST 3 Sample 21 Vial 24 THC R1 Spk 0410-80 GC110P104FAST 3 Sample

22 Vial 10 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample 22 Vial 26 Run 1 Lean Spk 0410-85 GC110P104FAST 3 Sample

23 Vial 14 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample 23 Vial 30 gc110p156 #B3 ENV(1=900,2=111.98) GC110P144FAST 3 Sample

24 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 24 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

EA# 0410-59 Page 210 of 225
Sequence: G:\GC2010Q2\Betty\sequence\gc110p160.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p160.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 8 EPN 03 1 0410-93 GC110P144FAST 3 Sample 1 Vial 24 EPN 03 1 0410-93 GC110P144FAST 3 Sample

2 Vial 12 EPN 03 2 0410-93 GC110P144FAST 3 Sample 2 Vial 28 EPN 03 2 0410-93 GC110P144FAST 3 Sample

3 Vial 7 EPN 03 3 0410-93 GC110P144FAST 3 Sample 3 Vial 23 EPN 03 3 0410-93 GC110P144FAST 3 Sample

4 Vial 5 EPN 04 1 0410-93 GC110P144FAST 3 Sample 4 Vial 21 EPN 04 1 0410-93 GC110P144FAST 3 Sample

5 Vial 11 EPN 04 2 0410-93 GC110P144FAST 3 Sample 5 Vial 27 EPN 04 2 0410-93 GC110P144FAST 3 Sample

6 Vial 4 EPN 04 3 0410-93 GC110P144FAST 3 Sample 6 Vial 20 EPN 04 3 0410-93 GC110P144FAST 3 Sample

7 Vial 6 R3 0410-59 GC110P144FAST 3 Sample 7 Vial 22 R3 0410-59 GC110P144FAST 3 Sample

8 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 8 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

9 Vial 2 pause PAUSE 1 Sample 9 Vial 18 pause PAUSE 1 Sample

10 Vial 14 N2 Blank ENV(1=450,2=0)) GC110P144FAST 3 Sample

EA# 0410-59 Page 211 of 225
Sequence: G:\GC2010Q2\Betty\sequence\gc110p161.txt Sequence: G:\GC2010Q2\Betty\sequence\gc110p161.txt

Sequence Table (Front Injector): Sequence Table (Back Injector):

Line Vial Sample Name Method Inj Type Line Vial Sample Name Method Inj Type

1 Vial 8 EPN 02 1 0410-98 GC110P144FAST 3 Sample 1 Vial 24 EPN 02 1 0410-98 GC110P144FAST 3 Sample

2 Vial 12 EPN 02 2 0410-98 GC110P144FAST 3 Sample 2 Vial 28 EPN 02 2 0410-98 GC110P144FAST 3 Sample

3 Vial 6 Run 1 backup spk 0410-56 GC110P144FAST 3 Sample 3 Vial 22 Run 1 backup spk 0410-56 GC110P144FAST 3 Sample

4 Vial 7 EPN 02 3 0410-98 GC110P144FAST 3 Sample 4 Vial 23 EPN 02 3 0410-98 GC110P144FAST 3 Sample

5 Vial 5 EPN 01 1 0410-98 GC110P144FAST 3 Sample 5 Vial 21 EPN 01 1 0410-98 GC110P144FAST 3 Sample

6 Vial 11 EPN 01 2 0410-98 GC110P144FAST 3 Sample 6 Vial 27 EPN 01 2 0410-98 GC110P144FAST 3 Sample

7 Vial 4 EPN 01 3 0410-98 GC110P144FAST 3 Sample 7 Vial 20 EPN 01 3 0410-98 GC110P144FAST 3 Sample

8 Vial 16 N2 Blank GC110P144FAST 3 Sample 8 Vial 32 N2 Blank GC110P144FAST 3 Sample

9 Vial 9 gc110p104 #C5 GC110P144FAST 3 Sample 9 Vial 25 gc110p104 #C5 GC110P144FAST 3 Sample

10 Vial 2 pause PAUSE 1 Sample 10 Vial 18 pause PAUSE 1 Sample

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Product Name Carbon monoxide, 

≥99.0%

Product Number 295116

Product Brand ALDRICH

CAS Number 630-08-0

Molecular Formula CO

Molecular Weight 28.01

TEST SPECIFICATION LOT 03611BJ RESULTS

VENDOR INFORMATION GUARANTEED PURITY OF 99.00% 

(MINIMUM) BY

PURITY OF 99.00% GUARANTEED BY 

SUPPLIER

QC RELEASE DATE FEBRUARY 2008

Certificate Of Analysis Page 1 of 1

http://www.sigmaaldrich.com/catalog/CertOfAnalysisPage.do?symbol=295116&LotNo=03... 1/8/2010

EA# 0410-59 Page 219 of 225
 

Product Name Carbon dioxide, 

≥99.8%

Product Number 295108

Product Brand ALDRICH

CAS Number 124-38-9

Molecular Formula CO2

Molecular Weight 44.01

TEST SPECIFICATION LOT 01629AJ RESULTS

VENDOR INFORMATION GUARANTEED PURITY OF 99.80% 

(MINIMUM) BY

PURITY OF 99.80% GUARANTEED BY 

SUPPLIER

QC RELEASE DATE FEBRUARY 2008

Certificate Of Analysis Page 1 of 1

http://www.sigmaaldrich.com/catalog/CertOfAnalysisPage.do?symbol=295108&LotNo=01... 1/8/2010

EA# 0410-59 Page 220 of 225
 

Product Name Methane, 

≥99.0%

Product Number 295477

Product Brand ALDRICH

CAS Number 74-82-8

Molecular Formula CH4

Molecular Weight 16.04

TEST SPECIFICATION LOT MKBB4558 RESULTS

Vendor Information Conforms Conforms

Guaranteed Purity Of 99.00% (Minimum) 

By Supplier

Specification Date: MAY 2009

Date of QC Release: MAY 2009

Print Date: MAY 14 2009

Certificate Of Analysis Page 1 of 1

http://www.sigmaaldrich.com/catalog/CertOfAnalysisPage.do?symbol=295477&LotNo=M... 1/8/2010

EA# 0410-59 Page 221 of 225
Pure Gases

Pure Gases

52

www.mathesontrigas.com

Gas Grade Purity Product Cylinder Content Equipment Model Page

Specifications Code Size US Metric Recommendations No. No.

Nitrous Oxide, Ultra High Purity 99.99% G1969101 1A 60 lb 27.22 kg Dual Stage Reg. Series 3120-326 299

Guaranteed Specifications G1969140 2 20 lb 9.07 kg Single Stage Reg. Series 3530-326 313

Carbon Dioxide < 2 ppm G1969150 3 6 lb 2.72 kg LB Regulator Series 3550-170 314

Carbon Monoxide < 2 ppm G1969175 LB 0.5 lb 227 gm Gas Warmer 6284-326 435

Nitrogen < 10 ppm

Oxygen < 4 ppm

THC as CH4 < 2 ppm

A lot analysis will be provided with each cylinder. Please inquire for individual cylinder analysis.

Caution: Not for human consumption.

Nitrous Oxide,CP Grade 99% G1570101 1A 60 lb 27.22 kg Dual Stage Reg. Series 81-326 293

G1570140 2 20 lb 9.07 kg Single Stage Reg. Series 18-326 292

G1570150 3 6 lb 2.72 kg LB Regulator Series 3320-170 302

G1570175 LB 0.5 lb 227 gm Gas Warmer 6284-326 435

A Certificate of Conformance will be provided on request. Caution: Not for human consumption.

Oxygen

Description

Formula: O2

Gas Data

Molecular Weight: 32.00

Density: 1.326 kg/m3 @ 21.1°C, 101.325 kPa

0.08279 lb/ft3 @ 70°F, 14.696 psia

Specific Volume: 0.7541 m3

/kg @ 21.1°C, 101.325 kPa

12.08 ft3

/lb @ 70°F, 14.696 psia

Shipping Information

CAS Registry Number: 7782-44-7

UN Number: UN 1072

ECCN Number: EAR99

DOT Proper Shipping Name: Oxygen, Compressed

DOT Classification: 2.2 (Nonflammable Gas)

DOT Label: NON-FLAMMABLE GAS, OXIDIZER

TC Shipping Name: Oxygen, Compressed

TC Classification: 2.2, 5.1

TC Label: NON-FLAMMABLE GAS, 

NON-POISONOUS GAS, OXIDIZER

Cylinder Specifications

Approximate 

Cylinder Valve Outlet Pressure Pressure Ship Weight

Size CGA No. psig @ 70°F kPa @ 21.1°C lb kg

1L 540 2,640 18,202 173 78

1A 540 2,200 15,168 153 69

2 540 1,600 11,032 80 36

3 540 1,600 11,032 41 19

4 540 1,600 11,032 13 6

6 540 1,585 10,928 20 9

7B 540 1,650 11,376 6 3

7A 540 825 5,688 6 3

7 540 225 1,551 6 3

LB 170 1,600 11,032 6 3

Gas Grade Purity Product Cylinder Content Equipment Model Page

Specifications Code Size US Metric Recommendations No. No.

Oxygen, Research Purity 99.998% G2182101 1A 249 ft3 7.05 m3 Dual Stage Reg. Series 3810-540 318

Guaranteed Specifications G2182140 2 70 ft3 1.98 m3 Single Stage Reg. Series 3510-540 312

Argon < 5 ppm G2182150 3 28 ft3 0.79 m3 Flash Arrestor 6104A 434

Carbon Dioxide < 0.1 ppm G2182165 4 10 ft3 0.28 m3 Leak Detector 8081A 404

Carbon Monoxide < 0.1 ppm G2182178 6 3.53 ft3 100 L Detector Tube 8014-159SC 392

Hydrogen < 0.1 ppm G2182183 7B 1.76 ft3 50 L

Krypton < 1 ppm G2182182 7A 0.88 ft3 25 L

Nitrogen < 5 ppm G2182181 7 0.25 ft3 7 L

Nitrous Oxide < 2 ppm

THC < 0.1 ppm

Water < 1 ppm

A Certificate of Analysis is available on request at a nominal charge. 

Caution: Not for human consumption.

Oxygen, Matheson Purity 99.997% G1885112 1L 337 ft3 9.54 m3 Dual Stage Reg. Series 3810-540 318

Guaranteed Specifications G1885101 1A 249 ft3 7.05 m3 Single Stage Reg. Series 3510-540 312

Argon < 15 ppm G1885140 2 70 ft3 1.98 m3 LB Regulator Series 3570-170 314

Carbon Dioxide < 1 ppm G1885150 3 28 ft3 0.79 m3 Flash Arrestor 6104A 434

Carbon Monoxide < 1 ppm G1885165 4 10 ft3 0.28 m3 Leak Detector 8081A 404

Krypton < 10 ppm G1885175 LB 2 ft3 56 L Detector Tube 8014-159SC 392

Nitrogen < 10 ppm

THC < 0.5 ppm

Water < 1 ppm

A Certificate of Analysis is available on request at a nominal charge. 

Caution: Not for human consumption.

Oxygen, Ultra High Purity 99.98% G1979112 1L 337 ft3 9.54 m3 Dual Stage Reg. Series 3120-540 299

Guaranteed Specifications G1979101 1A 249 ft3 7.05 m3 Single Stage Reg Series 3530-540 313

Carbon Dioxide < 1 ppm G1979140 2 70 ft3 1.98 m3 LB Regulator Series 3570-170 314

Carbon Monoxide < 1 ppm G1979150 3 28 ft3 0.79 m3 Flash Arrestor 6103A-O 434

Nitrogen < 15 ppm G1979165 4 10 ft3 0.28 m3 Leak Detector 8081A 404

THC < 1 ppm G1979175 LB 2 ft3 56 L Detector Tube 8014-159SC 392

Water < 5 ppm

A lot analysis is available on request. Please inquire for individual cylinder analysis. 

Caution: Not for human consumption.

EA# 0410-59 Page 222 of 225
Pure Gases

Pure Gases

53

www.mathesontrigas.com

Oxygen (continued)

Gas Grade Purity Product Cylinder Content Equipment Model Page

Specifications Code Size US Metric Recommendations No. No.

Oxygen, Zero Gas 99.8% G2060112 1L 337 ft3 9.54 m3 Dual Stage Reg. Series 3120-540 299

THC as CH4 < 0.5 ppm G2060101 1A 249 ft3 7.05 m3 Single Stage Reg. Series 3530-540 313

G2060140 2 70 ft3 1.98 m3 LB Regulator Series 3570-170 314

G2060150 3 28 ft3 0.79 m3 Flash Arrestor 6103A-O 434

G2060165 4 10 ft3 0.28 m3 Leak Detector 8081A 404

G2060175 LB 2 ft3 56 L Detector Tube 8014-159SC 392

A lot analysis will be provided with each cylinder. Please inquire for individual cylinder analysis. 

Caution: Not for human consumption

Oxygen, Extra Dry 99.6% G1177201 1A 249 ft3 7.05 m3 Dual Stage Reg. Series 3120-540 299

G1177240 2 70 ft3 1.98 m3 Single Stage Reg. Series 3530-540 313

G1177250 3 28 ft3 0.79 m3 LB Regulator Series 3550-170 314

G1177265 4 10 ft3 0.28 m3 Flash Arrestor 6103A-O 434

G1177275 LB 2 ft3 56 L Leak Detector 8081A 404

Detector Tube 8014-159SC 392

A Certificate of Conformance will be provided on request. 

Caution: Not for human consumption.

EA# 0410-59 Page 223 of 225
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This Is The Last Page

Of This Report.

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