# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\5897641389620858911\[EPA-HQ-OAR-2013-0290-DRAFT-0065.xls]Florim-RK MAY-Emission Calcs** Date: 12/1/14

Plant name: Florim Location: FACID: Test date: 5/25-26/2010 UNITID: Equipment: No. 1 Roller Kiln Control device: DIFF Gas Volum. Emission Process

Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor,
Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 19.1 202.2 16,174 141.029 1.08E-08 24.6264 190.1716.77E-04 #DIV/0!

2 19.3 198.3 16,280 151.309 1.18E-08 26.9437 234.0737.45E-04 #DIV/0! 3 19.3 205.7 16,704 137.291 1.03E-08 23.5620 204.69526.69E-04 #DIV/0! Average 19.2 202.1 16,386 1.09E-08 25.0440 209.6466.97E-04#DIV/0! #DIV/0! TEQ 1 M23 19.1 202.2 16,174 2.902277 2.21E-10 0.506792 3.9135641.39E-05 #DIV/0!

2 19.3 198.3 16,280 3.174575 2.47E-10 0.565299 4.9110381.56E-05 #DIV/0! 3 19.3 205.7 16,704 3.036343 2.28E-10 0.521102 4.5270761.48E-05 #DIV/0! Average 19.2 202.1 16,386 2.32E-10 0.531065 4.4505591.48E-05#DIV/0! #DIV/0! Notes: Clarksville, TN

1 of 1DIOXIN-FURAN PARTICLE CATCH

Measured wt, ng Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Compound Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 13.2 18.5 18.1 Total TCDD 13200 18500 18100 Total TCDD 13200 18500 18100 Total PeCDD 17.2 23 21 Total PeCDD 17200 23000 21000 Total PeCDD 17200 23000 21000 Total HxCDD 18.1 21.1 18.5 Total HxCDD 18100 21100 18500 Total HxCDD 18100 21100 18500 Total HpCDD 23.9 17.2 15.9 Total HpCDD 23900 17200 15900 Total HpCDD 23900 17200 15900 Total OCDD 68.4 71.2 63.5 Total OCDD 68400 71200 63500 Total OCDD 68400 71200 63500

Total dioxins 140.8 151 137 Total TCDF 0.144 0.155 0.162 Total TCDF 144 155 162 Total TCDF 144 155 162 Total PeCDF 0.0329 0.0608 0.0647 Total PeCDF 32.9 60.8 64.7 Total PeCDF 32.9 60.8 64.7 Total HxCDF 0.0242 0.0208 0.0369 Total HxCDF 24.2 20.8 36.9 Total HxCDF 24.2 20.8 36.9 Total HpCDF 0.0173 0.0243 0.0063 Total HpCDF 17.3 24.3 6.3 Total HpCDF 17.3 24.3 < 6.3 Total OCDF 0.011 0.048 0.0207 Total OCDF 11 48 20.7 Total OCDF < J, R 11 48 J 20.7

Total furans 0.2294 0.3089 0.2906 TOTAL CDD/CDF 141.0294151.3089137.2906

Measured wt, ng TEQ, ng Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 1.06 1.25 1.24 1.06 1.25 1.24 1 2,3,7,8-TCDD 1060 1250 1240 2,3,7,8-TCDD 1060 1250 1240 1,2,3,7,8 PeCDD 1.44 1.5 1.41 1.44 1.5 1.41 1 1,2,3,7,8-PeCDD 1440 1500 1410 1,2,3,7,8-PeCDD M 1440 M 1500 M 1410 1,2,3,4,7,8 HxCDD 0.401 0.507 0.448 0.0401 0.0507 0.0448 0.1 1,2,3,4,7,8-HxCDD 401 507 448 1,2,3,4,7,8-HxCDD M 401 M 507 M 448 1,2,3,6,7,8 HxCDD 0.935 1.01 0.885 0.0935 0.101 0.0885 0.1 1,2,3,6,7,8-HxCDD 935 1010 885 1,2,3,6,7,8-HxCDD M 935 M 1010 M 885 1,2,3,7,8,9 HxCDD 1.64 1.78 1.61 0.164 0.178 0.161 0.1 1,2,3,7,8,9-HxCDD 1640 1780 1610 1,2,3,7,8,9-HxCDD M 1640 M 1780 M 1610 1,2,3,4,6,7,8 HpCDD 7.91 6.73 6.68 0.0791 0.0673 0.0668 0.01 1,2,3,4,6,7,8-HpCDD 7910 6730 6680 1,2,3,4,6,7,8-HpCDD 7910 6730 6680 Total OCDD 68.4 71.2 63.50.020520.021360.01905 0.0003 OCDD 68400 71200 63500 OCDD 68400 71200 63500 Total CDD congeners 81.786 83.977 75.7732.897223.168363.03015 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.00848 0.00834 0.009650.000850.000830.00097 0.1 2,3,7,8-TCDF 8.48 8.34 9.65 2,3,7,8-TCDF M 8.48 M 8.34 M 9.65 1,2,3,7,8 PeCDF 0.00771 0.0058 0.00720.000230.000170.00022 0.03 1,2,3,7,8-PeCDF 7.71 5.8 7.2 1,2,3,7,8-PeCDF J 7.71< M, J, R 5.8< M, J, R 7.2 2,3,4,7,8 PeCDF 0.0069 0.00934 0.00920.00207 0.00280.00276 0.3 2,3,4,7,8-PeCDF 6.9 9.34 9.2 2,3,4,7,8-PeCDF < M, J, R 6.9 M, J 9.34< M, J, R 9.2 1,2,3,4,7,8 HxCDF 0.00392 0.0048 0.004950.000390.00048 0.0005 0.1 1,2,3,4,7,8-HxCDF 3.92 4.8 4.95 1,2,3,4,7,8-HxCDF M, J 3.92< M, U 4.8 J 4.95 1,2,3,6,7,8 HxCDF 0.0063 0.00717 0.006540.000630.000720.00065 0.1 1,2,3,6,7,8-HxCDF 6.3 7.17 6.54 1,2,3,6,7,8-HxCDF < M, J, R 6.3 M, J 7.17 J 6.54 2,3,4,6,7,8 HxCDF 0.0042 0.0046 0.004530.000420.000460.00045 0.1 2,3,4,6,7,8-HxCDF 4.2 4.6 4.53 2,3,4,6,7,8-HxCDF < M, J, R 4.2< U 4.6 J 4.53 1,2,3,7,8,9 HxCDF 0.0033 0.005 0.004870.00033 0.00050.00049 0.1 1,2,3,7,8,9-HxCDF 3.3 5 4.87 1,2,3,7,8,9-HxCDF < M, U 3.3< U 5 J 4.87 1,2,3,4,6,7,8 HpCDF 0.00965 0.019 0.0089 9.7E-050.00019 8.9E-05 0.01 1,2,3,4,6,7,8-HpCDF 9.65 19 8.9 1,2,3,4,6,7,8-HpCDF M, J 9.65 M, J 19< J, R 8.9 1,2,3,4,7,8,9 HpCDF 0.0036 0.0044 0.0068 3.6E-054.4E-05 6.8E-05 0.01 1,2,3,4,7,8,9-HpCDF 3.6 4.4 6.8 1,2,3,4,7,8,9-HpCDF< M, J, R 3.6< M, J, R 4.4< M, J, R 6.8 Total OCDF 0.011 0.048 0.0207 3.3E-06 1.4E-05 6.2E-06 0.0003 OCDF 11 48 20.7 OCDF < J, R 11 48 J 20.7 Total CDF congeners 0.06506 0.11645 0.083340.005060.006220.00619 **TOTAL CDD/CDF (TEQ)** 81.8510684.0934575.856342.902283.174583.03634 √7/17/12 √7/17/12 √7/17/12

M indicates that a peak has been manually integrated U indicates that this compound was not detected above the MDL J indicates that a target analyte was detected below the LQL R indicates that the ion abundance ratio for this compounds did not meet the acceptance criterion. Measured wt, pg Measured wt, pg Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0065 Florim-RK MAY D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\5897641389620858911\[EPA-HQ-OAR-2013-0290-DRAFT-0065.xls]Florim-RK MAY-Emission Calcs** Date: 12/1/14

Plant name: Florim Location: FACID: Test date: 10/11-12/2010 UNITID: Equipment: No. 1 Roller Kiln Control device: DIFF Gas Volum. Emission Process

Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor,
Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 18.3 196.0 15,550 

# 127.712 1.01E-08 23.0030 122.9776.08E-04 #DIV/0!

2 18.4 198.2 15,815 

# 129.142 1.01E-08 23.0095 127.9336.18E-04 #DIV/0! 3 18.2 203.6 16,123 

# 200.656 1.52E-08 34.8035 179.17359.54E-04 #DIV/0! Average 18.3 199.3 15,829 1.18E-08 26.9387 143.3617.27E-04#DIV/0! #DIV/0! TEQ 1 M23 18.3 196.0 15,550 

# 3.170467 2.50E-10 0.571050 3.0529201.51E-05 #DIV/0!

2 18.4 198.2 15,815 

# 3.359684 2.62E-10 0.598602 3.3282301.61E-05 #DIV/0! 3 18.2 203.6 16,123 

# 4.028000 3.05E-10 0.698652 3.596761 1.91E-05 #DIV/0! Average 18.3 199.3 15,829 2.72E-10 0.622768 3.3259701.68E-05#DIV/0! #DIV/0! Notes: Clarksville, TN

1 of 1DIOXIN-FURAN PARTICLE CATCH

Measured wt, ng Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Compound Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 25.5 25.6 27.9 Total TCDD 25500 25600 27900 Total TCDD 25500 25600 27900 Total PeCDD 24.4 24.8 30 Total PeCDD 24400 24800 30000 Total PeCDD 24400 24800 30000 Total HxCDD 20.1 22.2 28.5 Total HxCDD 20100 22200 28500 Total HxCDD 20100 22200 28500 Total HpCDD 14.1 14.4 23.7 Total HpCDD 14100 14400 23700 Total HpCDD 14100 14400 23700 Total OCDD 43.2 41.8 90.3 Total OCDD 43200 41800 90300 Total OCDD 43200 41800 90300

Total dioxins 127.3 128.8 200.4 Total TCDF 0.245 0.203 0.146 Total TCDF 245 203 146 Total TCDF 245 203 146 Total PeCDF 0.0992 0.0818 0.0322 Total PeCDF 99.2 81.8 32.2 Total PeCDF 99.2 81.8 32.2 Total HxCDF 0.0332 0.0332 0.0281 Total HxCDF 33.2 33.2 28.1 Total HxCDF 33.2 33.2 28.1 Total HpCDF 0.0203 0.0113 0.0269 Total HpCDF 20.3 11.3 26.9 Total HpCDF 20.3 11.3 26.9 Total OCDF 0.0147 0.0127 0.0226 Total OCDF 14.7 12.7 22.6 Total OCDF J 14.7 J 12.7 22.6

Total furans 0.4124 0.342 0.2558 TOTAL CDD/CDF 127.7124 129.142200.6558

Measured wt, ng TEQ, ng Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 1.16 1.22 1.34 1.16 1.22 1.34 1 2,3,7,8-TCDD 1160 1220 1340 2,3,7,8-TCDD 1160 1220 1340 1,2,3,7,8 PeCDD 1.63 1.73 2.11 1.63 1.73 2.11 1 1,2,3,7,8-PeCDD 1630 1730 2110 1,2,3,7,8-PeCDD 1630 1730 2110 1,2,3,4,7,8 HxCDD 0.555 0.616 0.78 0.0555 0.0616 0.078 0.1 1,2,3,4,7,8-HxCDD 555 616 780 1,2,3,4,7,8-HxCDD 555 616 780 1,2,3,6,7,8 HxCDD 0.805 0.839 1.14 0.0805 0.0839 0.114 0.1 1,2,3,6,7,8-HxCDD 805 839 1140 1,2,3,6,7,8-HxCDD 805 839 1140 1,2,3,7,8,9 HxCDD 1.68 1.87 2.53 0.168 0.187 0.253 0.1 1,2,3,7,8,9-HxCDD 1680 1870 2530 1,2,3,7,8,9-HxCDD 1680 1870 2530 1,2,3,4,6,7,8 HpCDD 5.78 5.93 10.1 0.0578 0.0593 0.101 0.01 1,2,3,4,6,7,8-HpCDD 5780 5930 10100 1,2,3,4,6,7,8-HpCDD 5780 5930 10100 Total OCDD 43.2 41.8 90.30.012960.012540.02709 0.0003 OCDD 43200 41800 90300 OCDD 43200 41800 90300 Total CDD congeners 54.81 54.005 108.33.164763.354344.02309 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0139 0.0134 0.01350.001390.001340.00135 0.1 2,3,7,8-TCDF 13.9 13.4 13.5 2,3,7,8-TCDF 13.9 13.4 13.5 1,2,3,7,8 PeCDF 0.00639 0.00643 0.006920.000190.000190.00021 0.03 1,2,3,7,8-PeCDF 6.39 6.43 6.92 1,2,3,7,8-PeCDF J 6.39 J 6.43 J 6.92 2,3,4,7,8 PeCDF 0.00801 0.00705 0.00277 0.00240.002120.00083 0.3 2,3,4,7,8-PeCDF 8.01 7.05 2.77 2,3,4,7,8-PeCDF J 8.01 J 7.05 < 2.77 1,2,3,4,7,8 HxCDF 0.00532 0.00484 0.008620.000530.000480.00086 0.1 1,2,3,4,7,8-HxCDF 5.32 4.84 8.62 1,2,3,4,7,8-HxCDF J 5.32 J 4.84 J 8.62 1,2,3,6,7,8 HxCDF 0.00496 0.00528 0.00578 0.00050.000530.00058 0.1 1,2,3,6,7,8-HxCDF 4.96 5.28 5.78 1,2,3,6,7,8-HxCDF J 4.96 J 5.28 J 5.78 2,3,4,6,7,8 HxCDF 0.00416 0.00436 0.005940.000420.000440.00059 0.1 2,3,4,6,7,8-HxCDF 4.16 4.36 5.94 2,3,4,6,7,8-HxCDF < J 4.16 J 4.36 J 5.94 1,2,3,7,8,9 HxCDF 0.00148 0.00131 0.003270.000150.000130.00033 0.1 1,2,3,7,8,9-HxCDF 1.48 1.31 3.27 1,2,3,7,8,9-HxCDF < 1.48 < 1.31 < 3.27 1,2,3,4,6,7,8 HpCDF 0.00812 0.00631 0.008 8.1E-056.3E-050.00008 0.01 1,2,3,4,6,7,8-HpCDF 8.12 6.31 8 1,2,3,4,6,7,8-HpCDF J 8.12 J 6.31 J 8 1,2,3,4,7,8,9 HpCDF 0.00444 0.00499 0.007364.4E-05 5E-05 7.4E-05 0.01 1,2,3,4,7,8,9-HpCDF 4.44 4.99 7.36 1,2,3,4,7,8,9-HpCDF J 4.44 J 4.99 J 7.36 Total OCDF 0.0147 0.0127 0.02264.4E-06 3.8E-06 6.8E-06 0.0003 OCDF 14.7 12.7 22.6 OCDF J 14.7 J 12.7 J 22.6 Total CDF congeners 0.07148 0.06667 0.084760.00571 0.005340.00491 **TOTAL CDD/CDF (TEQ)** 54.8814854.07167108.38483.170473.35968 4.028

M indicates that a peak has been manually integrated U indicates that this compound was not detected above the MDL J indicates that a target analyte was detected below the LQL R indicates that the ion abundance ratio for this compounds did not meet the acceptance criterion. Measured wt, pg Measured wt, pg

Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0065 Florim-RK OCT D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\5897641389620858911\[EPA-HQ-OAR-2013-0290-DRAFT-0065.xls]Florim-RK MAY-Emission Calcs** Date: 12/1/14

Plant name: Florim Location: FACID: Test date: 10/13-14/2010 UNITID: Equipment: Vertical Dryer No. 1 Control device: Gas Volum. Emission Process

Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor,
Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 19.0 172.1 4,132 16.532 1.48E-09 3.3922 24.8172.38E-05 #DIV/0!

2 19.0 179.0 4,450 9.490 8.18E-10 1.8723 13.6971.42E-05 #DIV/0! 3 19.0 175.7 4,273 13.626 1.20E-09 2.7380 20.03041.99E-05 #DIV/0! Average 19.0 175.6 4,285 1.17E-09 2.6675 19.5151.93E-05#DIV/0! #DIV/0! TEQ 1 M23 19.0 172.1 4,132 0.083442 7.48E-12 0.017121 0.1252531.20E-07 #DIV/0!

2 19.0 179.0 4,450 0.038723 3.34E-12 0.007640 0.0558915.78E-08 #DIV/0! 3 19.0 175.7 4,273 0.057395 5.04E-12 0.011533 0.0843728.37E-08 #DIV/0! Average 19.0 175.6 4,285 5.29E-12 0.012098 0.0885068.72E-08#DIV/0! #DIV/0! Notes: Clarksville, TN

1 of 1DIOXIN-FURAN PARTICLE CATCH

Measured wt, ng Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Compound Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.675 0.223 0.382 Total TCDD 675 223 382 Total TCDD 675 223 382 Total PeCDD 0.387 0.18 0.271 Total PeCDD 387 180 271 Total PeCDD 387 180 271 Total HxCDD 0.615 0.31 0.433 Total HxCDD 615 310 433 Total HxCDD 615 310 433 Total HpCDD 1.61 0.684 0.829 Total HpCDD 1610 684 829 Total HpCDD 1610 684 829 Total OCDD 13.2 8.05 11.7 Total OCDD 13200 8050 11700 Total OCDD 13200 8050 11700

Total dioxins 16.487 9.447 13.615 Total TCDF 0.00217 0.00107 0.00117 Total TCDF 2.17 1.07 1.17 Total TCDF < 2.17< 1.07< 1.17 Total PeCDF 0.00192 0.00327 0.00167 Total PeCDF 1.92 3.27 1.67 Total PeCDF < 1.92< 3.27 1.67 Total HxCDF 0.00356 0.00552 0.00191 Total HxCDF 3.56 5.52 1.91 Total HxCDF 3.56 5.52 1.91 Total HpCDF 0.00288 0.00182 0.00124 Total HpCDF 2.88 1.82 1.24 Total HpCDF < 2.88< 1.82< 1.24 Total OCDF 0.0349 0.0313 0.00491 Total OCDF 34.9 31.3 4.91 Total OCDF < 34.9< 31.3< 4.91

Total furans 0.04543 0.04298 0.0109 TOTAL CDD/CDF 16.53243 9.48998 13.6259

Measured wt, ng TEQ, ng Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.0305 0.0127 0.0222 0.0305 0.0127 0.0222 1 2,3,7,8-TCDD 30.5 12.7 22.2 2,3,7,8-TCDD 30.5 12.7 22.2 1,2,3,7,8 PeCDD 0.0285 0.0135 0.0195 0.0285 0.0135 0.0195 1 1,2,3,7,8-PeCDD 28.5 13.5 19.5 1,2,3,7,8-PeCDD J 28.5 J 13.5 J 19.5 1,2,3,4,7,8 HxCDD 0.0177 0.00858 0.01050.001770.000860.00105 0.1 1,2,3,4,7,8-HxCDD 17.7 8.58 10.5 1,2,3,4,7,8-HxCDD J 17.7 J 8.58 J 10.5 1,2,3,6,7,8 HxCDD 0.0296 0.0138 0.01820.002960.001380.00182 0.1 1,2,3,6,7,8-HxCDD 29.6 13.8 18.2 1,2,3,6,7,8-HxCDD J 29.6 J 13.8 J 18.2 1,2,3,7,8,9 HxCDD 0.0695 0.038 0.04890.00695 0.00380.00489 0.1 1,2,3,7,8,9-HxCDD 69.5 38 48.9 1,2,3,7,8,9-HxCDD 69.5 J 38 J 48.9 1,2,3,4,6,7,8 HpCDD 0.71 0.291 0.359 0.0071 0.00291 0.00359 0.01 1,2,3,4,6,7,8-HpCDD 710 291 359 1,2,3,4,6,7,8-HpCDD 710 291 359 Total OCDD 13.2 8.05 11.70.003960.002420.00351 0.0003 OCDD 13200 8050 11700 OCDD 13200 8050 11700 Total CDD congeners 14.0858 8.42758 12.17830.081740.037560.05656 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.00217 0.00107 0.001170.000220.00011 0.00012 0.1 2,3,7,8-TCDF 2.17 1.07 1.17 2,3,7,8-TCDF < 2.17 < 1.07 < 1.17 1,2,3,7,8 PeCDF 0.00192 0.001020.000897 5.8E-05 3.1E-052.7E-05 0.03 1,2,3,7,8-PeCDF 1.92 1.02 0.897 1,2,3,7,8-PeCDF < 1.92 < 1.02 < 0.897 2,3,4,7,8 PeCDF 0.00192 0.001030.0008860.000580.00031 0.00027 0.3 2,3,4,7,8-PeCDF 1.92 1.03 0.886 2,3,4,7,8-PeCDF < 1.92 < 1.03 < 0.886 1,2,3,4,7,8 HxCDF 0.00356 0.00383 0.00191 0.000360.000380.00019 0.1 1,2,3,4,7,8-HxCDF 3.56 3.83 1.91 1,2,3,4,7,8-HxCDF J 3.56 J 3.83 J 1.91 1,2,3,6,7,8 HxCDF 0.001160.0007790.0005730.00012 7.8E-05 5.7E-05 0.1 1,2,3,6,7,8-HxCDF 1.16 0.779 0.573 1,2,3,6,7,8-HxCDF < 1.16 < 0.779 < 0.573 2,3,4,6,7,8 HxCDF 0.001230.0008690.0006390.00012 8.7E-056.4E-05 0.1 2,3,4,6,7,8-HxCDF 1.23 0.869 0.639 2,3,4,6,7,8-HxCDF < 1.23 < 0.869 < 0.639 1,2,3,7,8,9 HxCDF 0.00182 0.00116 0.000820.000180.00012 8.2E-05 0.1 1,2,3,7,8,9-HxCDF 1.82 1.16 0.82 1,2,3,7,8,9-HxCDF < 1.82 < 1.16 < 0.82 1,2,3,4,6,7,8 HpCDF 0.00205 0.00182 0.001242.1E-05 1.8E-05 1.2E-05 0.01 1,2,3,4,6,7,8-HpCDF 2.05 1.82 1.24 1,2,3,4,6,7,8-HpCDF < 2.05 <J 1.82 <J 1.24 1,2,3,4,7,8,9 HpCDF 0.0043 0.00225 0.001764.3E-052.3E-05 1.8E-05 0.01 1,2,3,4,7,8,9-HpCDF 4.3 2.25 1.76 1,2,3,4,7,8,9-HpCDF < 4.3 < 2.25 < 1.76 Total OCDF 0.0349 0.0313 0.00491 1E-05 9.4E-06 1.5E-06 0.0003 OCDF 34.9 31.3 4.91 OCDF < 34.9 < 31.3 < 4.91 Total CDF congeners 0.055030.0451280.014805 0.00170.001160.00084 **TOTAL CDD/CDF (TEQ)** 14.140838.47270812.19311 0.083440.03872 0.0574

M indicates that a peak has been manually integrated U indicates that this compound was not detected above the MDL J indicates that a target analyte was detected below the LQL R indicates that the ion abundance ratio for this compounds did not meet the acceptance criterion. Measured wt, pg Measured wt, pg

Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0065 Florim-VD#1 D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\5897641389620858911\[EPA-HQ-OAR-2013-0290-DRAFT-0065.xls]Florim-RK MAY-Emission Calcs** Date: 12/1/14

Plant name: Florim Location: FACID: Test date: 10/12-13/2010 UNITID: Equipment: Spray

Dryer No. 2 Control device: Gas Volum. Emission Process

Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor,
Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 18.3 152.1 15,605 568.285 5.76E-08 131.8874 705.0903.50E-03 #DIV/0!

2 18.5 131.0 16,444 377.252 4.44E-08 101.6900 588.9552.84E-03 #DIV/0! 3 18.3 132.0 16,391 444.904 5.20E-08 119.0308 636.35683.32E-03 #DIV/0! Average 18.4 138.4 16,147 5.14E-08 117.5360 643.4673.22E-03#DIV/0! #DIV/0! TEQ 1 M23 18.3 152.1 15,605 3.498024 3.55E-10 0.811820 4.3401172.15E-05 #DIV/0!

2 18.5 131.0 16,444 2.577510 3.04E-10 0.694779 4.0239291.94E-05 #DIV/0! 3 18.3 132.0 16,391 1.901325 2.22E-10 0.508685 2.7195101.42E-05 #DIV/0! Average 18.4 138.4 16,147 2.94E-10 0.671762 3.6945191.84E-05#DIV/0! #DIV/0! Notes: Clarksville, TN

1 of 1DIOXIN-FURAN PARTICLE CATCH

Measured wt, ng Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Compound Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 19.6 14 9.22 Total TCDD 19600 14000 9220 Total TCDD 19600 14000 9220 Total PeCDD 20.6 15.6 10.4 Total PeCDD 20600 15600 10400 Total PeCDD 20600 15600 10400 Total HxCDD 26.3 20 16.1 Total HxCDD 26300 20000 16100 Total HxCDD 26300 20000 16100 Total HpCDD 34.7 26.6 29.1 Total HpCDD 34700 26600 29100 Total HpCDD 34700 26600 29100 Total OCDD 467 301 380 Total OCDD 467000 301000 380000 Total OCDD 467000 301000 380000

Total dioxins 568.2 377.2 444.82 Total TCDF 0.00159 0.00327 0.00432 Total TCDF 1.59 3.27 4.32 Total TCDF < 1.59< 3.27 4.32 Total PeCDF 0.0014 0.00206 0.00636 Total PeCDF 1.4 2.06 6.36 Total PeCDF < 1.4< 2.06 6.36 Total HxCDF 0.00151 0.00273 0.00473 Total HxCDF 1.51 2.73 4.73 Total HxCDF < 1.51< 2.73 4.73 Total HpCDF 0.0122 0.00742 0.0154 Total HpCDF 12.2 7.42 15.4 Total HpCDF 12.2< 7.42 15.4 Total OCDF 0.0681 0.0368 0.0532 Total OCDF 68.1 36.8 53.2 Total OCDF J 68.1 J 36.8 J 53.2

Total furans 0.0848 0.05228 0.08401 TOTAL CDD/CDF568.2848377.2523 444.904

Measured wt, ng TEQ, ng Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 1.29 0.919 0.603 1.29 0.919 0.603 1 2,3,7,8-TCDD 1290 919 603 2,3,7,8-TCDD 1290 919 603 1,2,3,7,8 PeCDD 1.52 1.16 0.793 1.52 1.16 0.793 1 1,2,3,7,8-PeCDD 1520 1160 793 1,2,3,7,8-PeCDD 1520 1160 793 1,2,3,4,7,8 HxCDD 0.605 0.461 0.387 0.0605 0.0461 0.0387 0.1 1,2,3,4,7,8-HxCDD 605 461 387 1,2,3,4,7,8-HxCDD 605 461 387 1,2,3,6,7,8 HxCDD 0.981 0.719 0.628 0.0981 0.0719 0.0628 0.1 1,2,3,6,7,8-HxCDD 981 719 628 1,2,3,6,7,8-HxCDD 981 719 628 1,2,3,7,8,9 HxCDD 2.4 1.79 1.65 0.24 0.179 0.165 0.1 1,2,3,7,8,9-HxCDD 2400 1790 1650 1,2,3,7,8,9-HxCDD 2400 1790 1650 1,2,3,4,6,7,8 HpCDD 14.8 10.9 12.3 0.148 0.109 0.123 0.01 1,2,3,4,6,7,8-HpCDD 14800 10900 12300 1,2,3,4,6,7,8-HpCDD 14800 10900 12300 Total OCDD 467 301 380 0.1401 0.0903 0.114 0.0003 OCDD 467000 301000 380000 OCDD 467000 301000 380000 Total CDD congeners 488.596 316.949 396.361 3.4967 2.5753 1.8995 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.00159 0.00327 0.004320.000160.000330.00043 0.1 2,3,7,8-TCDF 1.59 3.27 4.32 2,3,7,8-TCDF < 1.59 < 3.27 J 4.32 1,2,3,7,8 PeCDF 0.00143 0.0021 0.00134.3E-056.3E-05 3.9E-05 0.03 1,2,3,7,8-PeCDF 1.43 2.1 1.3 1,2,3,7,8-PeCDF < 1.43 < 2.1 < 1.3 2,3,4,7,8 PeCDF 0.00138 0.00203 0.001260.00041 0.00061 0.00038 0.3 2,3,4,7,8-PeCDF 1.38 2.03 1.26 2,3,4,7,8-PeCDF < 1.38 < 2.03 < 1.26 1,2,3,4,7,8 HxCDF 0.00141 0.00259 0.004730.000140.000260.00047 0.1 1,2,3,4,7,8-HxCDF 1.41 2.59 4.73 1,2,3,4,7,8-HxCDF < 1.41 2.59 J 4.73 1,2,3,6,7,8 HxCDF 0.00139 0.00241 0.001170.000140.000240.00012 0.1 1,2,3,6,7,8-HxCDF 1.39 2.41 1.17 1,2,3,6,7,8-HxCDF < 1.39 < 2.41 < 1.17 2,3,4,6,7,8 HxCDF 0.00138 0.00259 0.001270.000140.000260.00013 0.1 2,3,4,6,7,8-HxCDF 1.38 2.59 1.27 2,3,4,6,7,8-HxCDF < 1.38 < 2.59 < 1.27 1,2,3,7,8,9 HxCDF 0.00197 0.00348 0.00175 0.00020.000350.00018 0.1 1,2,3,7,8,9-HxCDF 1.97 3.48 1.75 1,2,3,7,8,9-HxCDF < 1.97 < 3.48 < 1.75 1,2,3,4,6,7,8 HpCDF 0.00362 0.00355 0.00396 3.6E-05 3.6E-05 4E-05 0.01 1,2,3,4,6,7,8-HpCDF 3.62 3.55 3.96 1,2,3,4,6,7,8-HpCDF < J 3.62 < 3.55 J 3.96 1,2,3,4,7,8,9 HpCDF 0.00367 0.00577 0.00285 3.7E-05 5.8E-052.9E-05 0.01 1,2,3,4,7,8,9-HpCDF 3.67 5.77 2.85 1,2,3,4,7,8,9-HpCDF < 3.67 < 5.77 < 2.85 Total OCDF 0.0681 0.0368 0.0532 2E-05 1.1E-05 1.6E-05 0.0003 OCDF 68.1 36.8 53.2 OCDF J 68.1 J 36.8 J 53.2 Total CDF congeners 0.08594 0.06459 0.07581 0.001320.00221 0.00183 **TOTAL CDD/CDF (TEQ)** 488.6819317.0136396.43683.498022.57751 1.90133

M indicates that a peak has been manually integrated U indicates that this compound was not detected above the MDL J indicates that a target analyte was detected below the LQL R indicates that the ion abundance ratio for this compounds did not meet the acceptance criterion. Measured wt, pg Measured wt, pg

Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0065 Florim-SD#2 D-F Data 12/1/2014

# Source Compound Run 1 Mass (pg)Run 1 FlagRun 1 Comments

Spray Dryer No. 2 - Method 23 2,3,7,8-TCDD 1290 Spray Dryer No. 2 - Method 23 1,2,3,7,8-PeCDD 1520 Spray Dryer No. 2 - Method 23 1,2,3,4,7,8-HxCDD 605 Spray Dryer No. 2 - Method 23 1,2,3,6,7,8-HxCDD 981 Spray Dryer No. 2 - Method 23 1,2,3,7,8,9-HxCDD 2400 Spray Dryer No. 2 - Method 23 1,2,3,4,6,7,8-HpCDD 14800 Spray Dryer No. 2 - Method 23 OCDD 467000

Spray Dryer No. 2 - Method 23 2,3,7,8-TCDF 1.59 DL Spray Dryer No. 2 - Method 23 1,2,3,7,8-PeCDF 1.43 DL Spray Dryer No. 2 - Method 23 2,3,4,7,8-PeCDF 1.38 DL Spray Dryer No. 2 - Method 23 1,2,3,4,7,8-HxCDF 1.41 DL Spray Dryer No. 2 - Method 23 1,2,3,6,7,8-HxCDF 1.39 DL Spray Dryer No. 2 - Method 23 2,3,4,6,7,8-HxCDF 1.38 DL Spray Dryer No. 2 - Method 23 1,2,3,7,8,9-HxCDF 1.97 DL Spray Dryer No. 2 - Method 23 1,2,3,4,6,7,8-HpCDF 3.62 DL Spray Dryer No. 2 - Method 23 1,2,3,4,7,8,9-HpCDF 3.67 DL Spray Dryer No. 2 - Method 23 OCDF 68.1

Spray Dryer No. 2 - Method 23 Total Dioxins 488596 Spray Dryer No. 2 - Method 23 Total Furans 85.9

Source Compound Run 1 Mass (pg)Run 1 FlagRun 1 Comments Vertical Dryer No. 1 - Method 23 2,3,7,8-TCDD 30.5 Vertical Dryer No. 1 - Method 23 1,2,3,7,8-PeCDD 28.5 Vertical Dryer No. 1 - Method 23 1,2,3,4,7,8-HxCDD 17.7 Vertical Dryer No. 1 - Method 23 1,2,3,6,7,8-HxCDD 29.6 Vertical Dryer No. 1 - Method 23 1,2,3,7,8,9-HxCDD 69.5 Vertical Dryer No. 1 - Method 23 1,2,3,4,6,7,8-HpCDD 710 Vertical Dryer No. 1 - Method 23 OCDD 13200

Vertical Dryer No. 1 - Method 23 2,3,7,8-TCDF 2.17 DL Vertical Dryer No. 1 - Method 23 1,2,3,7,8-PeCDF 1.92 DL Vertical Dryer No. 1 - Method 23 2,3,4,7,8-PeCDF 1.92 DL Vertical Dryer No. 1 - Method 23 1,2,3,4,7,8-HxCDF 3.56 Vertical Dryer No. 1 - Method 23 1,2,3,6,7,8-HxCDF 1.16 DL Vertical Dryer No. 1 - Method 23 2,3,4,6,7,8-HxCDF 1.23 DL Vertical Dryer No. 1 - Method 23 1,2,3,7,8,9-HxCDF 1.82 DL Vertical Dryer No. 1 - Method 23 1,2,3,4,6,7,8-HpCDF 2.05 DL Vertical Dryer No. 1 - Method 23 1,2,3,4,7,8,9-HpCDF 4.3 DL Vertical Dryer No. 1 - Method 23 OCDF 34.9 DL

Vertical Dryer No. 1 - Method 23 Total Dioxins 14086 Vertical Dryer No. 1 - Method 23 Total Furans 55

Source Compound Run 1 Mass (pg)Run 1 FlagRun 1 Comments Roller Kiln No. 1 May

- Method 23 2,3,7,8-TCDD 1060 Roller Kiln No. 1 May

- Method 23 1,2,3,7,8-PeCDD 1440 M

# Roller Kiln No. 1 May - Method 23 1,2,3,4,7,8-HxCDD 401 M Roller Kiln No. 1 May

- Method 23 1,2,3,6,7,8-HxCDD 935 M Roller Kiln No. 1 May

- Method 23 1,2,3,7,8,9-HxCDD 1640 M Roller Kiln No. 1 May

- Method 23 1,2,3,4,6,7,8-HpCDD 7910 Roller Kiln No. 1 May

- Method 23 OCDD 68400

Roller Kiln No. 1 May

- Method 23 2,3,7,8-TCDF 8.48 M Roller Kiln No. 1 May

- Method 23 1,2,3,7,8-PeCDF 7.71 J Roller Kiln No. 1 May

- Method 23 2,3,4,7,8-PeCDF 6.9 ND M J R Roller Kiln No. 1 May

- Method 23 1,2,3,4,7,8-HxCDF 3.92 M J Roller Kiln No. 1 May

- Method 23 1,2,3,6,7,8-HxCDF 6.3 ND M J R Roller Kiln No. 1 May

- Method 23 2,3,4,6,7,8-HxCDF 4.2 ND M J R Roller Kiln No. 1 May

- Method 23 1,2,3,7,8,9-HxCDF 3.3 ND M U Roller Kiln No. 1 May

- Method 23 1,2,3,4,6,7,8-HpCDF 9.65 J Roller Kiln No. 1 May

- Method 23 1,2,3,4,7,8,9-HpCDF 3.6 ND M J R Roller Kiln No. 1 May

- Method 23 OCDF 11 ND J R

Roller Kiln No. 1 May

- Method 23 Total Dioxins 81786 Roller Kiln No. 1 May

- Method 23 Total Furans 65.1

Source Compound Run 1 Mass (pg)Run 1 FlagRun 1 Comments Roller Kiln #1 October - Method 23 2,3,7,8-TCDD 1160 Roller Kiln #1 October - Method 23 1,2,3,7,8-PeCDD 1630 Roller Kiln #1 October - Method 23 1,2,3,4,7,8-HxCDD 555 Roller Kiln #1 October - Method 23 1,2,3,6,7,8-HxCDD 805 Roller Kiln #1 October - Method 23 1,2,3,7,8,9-HxCDD 1680 Roller Kiln #1 October - Method 23 1,2,3,4,6,7,8-HpCDD 5780 Roller Kiln #1 October - Method 23 OCDD 43200

Roller Kiln #1 October - Method 23 2,3,7,8-TCDF 13.9 Roller Kiln #1 October - Method 23 1,2,3,7,8-PeCDF 6.39 Roller Kiln #1 October - Method 23 2,3,4,7,8-PeCDF 8.01 Roller Kiln #1 October - Method 23 1,2,3,4,7,8-HxCDF 5.32 Roller Kiln #1 October - Method 23 1,2,3,6,7,8-HxCDF 4.96 Roller Kiln #1 October - Method 23 2,3,4,6,7,8-HxCDF 4.16 DL Roller Kiln #1 October - Method 23 1,2,3,7,8,9-HxCDF 1.48 DL Roller Kiln #1 October - Method 23 1,2,3,4,6,7,8-HpCDF 8.12 Roller Kiln #1 October - Method 23 1,2,3,4,7,8,9-HpCDF 4.44 Roller Kiln #1 October - Method 23 OCDF 14.7

Roller Kiln #1 October - Method 23 Total Dioxins 54810 Roller Kiln #1 October - Method 23 Total Furans 71.5

# Run 2 Mass (pg)Run 2 FlagRun 2 CommentsRun 3 Mass (pg)Run 3 FlagRun 3 Comments

919 603 1160 793 461 387 719 628 1790 1650 10900 12300 301000 380000

3.27 DL 4.32 2.1 DL 1.3 DL 2.03 DL 1.26 DL 2.59 4.73 2.41 DL 1.17 DL 2.59 DL 1.27 DL 3.48 DL 1.75 DL 3.55 DL 3.96 5.77 DL 2.85 DL 36.8 53.2

316949 396361 64.6 75.8

Run 2 Mass (pg)Run 2 FlagRun 2 CommentsRun 3 Mass (pg)Run 3 FlagRun 3 Comments 12.7 22.2 13.5 19.5 8.58 10.5 13.8 18.2 38 48.9 291 359 8050 11700

1.07 DL 1.17 DL 1.02 DL 0.897 DL 1.03 DL 0.886 DL 3.83 1.91 0.779 DL 0.573 DL 0.869 DL 0.639 DL 1.16 DL 0.82 DL 1.82 DL 1.24 DL 2.25 DL 1.76 DL 31.3 DL 4.91 DL

8428 12178 45.1 14.8

Run 2 Mass (pg)Run 2 FlagRun 2 CommentsRun 3 Mass (pg)Run 3 FlagRun 3 Comments 1250 1240 1500 M 1410 M

# 507 M 448 M

1010 M 885 M 1780 M 1610 M 6730 6680 71200 63500

8.34 M 9.65 M 5.8 ND M J R 7.2 ND M J R 9.34 M J 9.2 ND M J R 4.8 ND M U 4.95 J 7.17 M J 6.54 J 4.6 ND U 4.53 J 5 ND U 4.87 J 19 M J 8.9 ND J R 4.4 ND M J R 6.8 ND M J R 48 20.7

83977 75773 116.5 83.3

Run 2 Mass (pg)Run 2 FlagRun 2 CommentsRun 3 Mass (pg)Run 3 FlagRun 3 Comments 1220 1340 1730 2110 616 780 839 1140 1870 2530 5930 10100 41800 90300

13.4 13.5 6.43 6.92 7.05 2.77 DL 4.84 8.62 5.28 5.78 4.36 5.94 1.31 DL 3.27 DL 6.31 8 4.99 7.36 12.7 22.6

54005 108300 66.7 84.8

# Roller Kiln May

FROM ERT FROM LAB REPORT PAGES 197-199 Compound Run 1 Mass (pg) Compound Run 1 Mass (pg) 2,3,7,8-TCDD 1060 2,3,7,8-TCDD 1060 1,2,3,7,8-PeCDD 1440 1,2,3,7,8-PeCDD 1440 1,2,3,4,7,8-HxCDD 401 1,2,3,4,7,8-HxCDD 401 1,2,3,6,7,8-HxCDD 935 1,2,3,6,7,8-HxCDD 935 1,2,3,7,8,9-HxCDD 1640 1,2,3,7,8,9-HxCDD 1640 1,2,3,4,6,7,8-HpCDD 7910 1,2,3,4,6,7,8-HpCDD 7910 OCDD 68400 OCDD 68400 2,3,7,8-TCDF 8.48 2,3,7,8-TCDF 8.48 1,2,3,7,8-PeCDF 7.71 1,2,3,7,8-PeCDF 7.71 2,3,4,7,8-PeCDF 6.9 2,3,4,7,8-PeCDF 6.9 1,2,3,4,7,8-HxCDF 3.92 1,2,3,4,7,8-HxCDF 3.92 1,2,3,6,7,8-HxCDF 6.3 1,2,3,6,7,8-HxCDF 6.3 2,3,4,6,7,8-HxCDF 4.2 2,3,4,6,7,8-HxCDF 4.2 1,2,3,7,8,9-HxCDF 3.3 1,2,3,7,8,9-HxCDF 3.3 1,2,3,4,6,7,8-HpCDF 9.65 1,2,3,4,6,7,8-HpCDF 9.65 1,2,3,4,7,8,9-HpCDF 3.6 1,2,3,4,7,8,9-HpCDF 3.6 OCDF 11 OCDF 11 Total Dioxins 81786 Total TCDD 13200 Total Furans 65.1 Total PeCDD 17200 Total HxCDD 18100 Total HpCDD 23900 Calculation Check Total OCDD 68400 Total Dioxins 81786 Total Furans 65.06 Total TCDF 144 Total PeCDF 32.9 Total HxCDF 24.2 Total HpCDF 17.3 Total OCDF 11

Total Dioxins 140800 Total Furans 229.4

# Roller Kiln October From ERT Compound 2,3,7,8-TCDD 1,2,3,7,8-PeCDD 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD 1,2,3,4,6,7,8-HpCDD OCDD 2,3,7,8-TCDF 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF OCDF Total Dioxins Total Furans

Calculation Check Total Dioxins Total Furans

# Roller Kiln October FROM PAGE 193 Run 1 Mass (pg) Compound 1160 2,3,7,8-TCDD 1630 1,2,3,7,8-PeCDD 555 1,2,3,4,7,8-HxCDD 805 1,2,3,6,7,8-HxCDD 1680 1,2,3,7,8,9-HxCDD 5780 1,2,3,4,6,7,8-HpCDD 43200 OCDD 13.9 2,3,7,8-TCDF 6.39 1,2,3,7,8-PeCDF 8.01 2,3,4,7,8-PeCDF 5.32 1,2,3,4,7,8-HxCDF 4.96 1,2,3,6,7,8-HxCDF 4.16 2,3,4,6,7,8-HxCDF 1.48 1,2,3,7,8,9-HxCDF 8.12 1,2,3,4,6,7,8-HpCDF 4.44 1,2,3,4,7,8,9-HpCDF 14.7 OCDF 54810 Total Dioxins 71.5 Total Furans

54810 71.48

# Run 1 Mass (pg) 1160 1630 555 805 1680 5780 43200 13.9 6.39 8.01 5.32 4.96 4.16 1.48 8.12 4.44 14.7 54810 71.48