# Support Documents for Significant New Use Rule (SNUR) on Premanufacture Notice (PMN)
P-11-561

EPA Docket EPA-HQ-OPPT-2012-0182

# Index A-001 Structure Activity Team (SAT) Report for PMN P-11-561 A-002 Initial Review Engineering Report for PMN P-11-561 A-003 Initial Review Exposure Report for PMN P-11-561 A-004 TSCA Section 5(e) Consent Order and Determinations Supporting Consent Order for PMN P-11-561

# A-001 Structure Activity Team (SAT) Report
for PMN P-11-561

## SAT Report PMN Number: P-11-0561 SAT Date: 8/30/2011 Print Date: 2/6/2012

Related cases : Health related cases: Ecotox related cases :

Concern levels : 

### Type of Concern: Health Eco Comments Level of Concern: 1-2 1

Persistence Bioaccum Toxicity Comments 3 1 1 PMN 3 2 Inc Pdt

Exposure Based Review : Health: N o Ecotox: N o Routes of exposure : Health: Dermal Inhalation Ecotox: N o releases to water Fate: ; Keywords : Keywords: MECH IRR-E,S,L LUNG Summary of Assessment :
Fate : Fate Summary: P-11-0561 FATE: Solid with MP = 239-251 C (M) S = N egl. VP < 1.0E-6 torr at 25 C (E) BP = Dec. > 413 C (M) H < 1.00E-8 (E) POTW removal (%) = 90 via sorption

### Time for complete ultimate aerobic biodeg > mo Sorption to soils/sediments = v.strong PBT Potential: PMN P3B1; Inc Pdt B3B2 *CEB FATE: Migration to ground water = negl

Health : Health Summary: Absorption is nil all routes, based on physical/chemical p roperties. There is concern for mechanical irritation to the eye, skin, and lung, based on information in the PMN MSDS. There also is concern for lung toxicity if inhaled based on lung overload for Test Data: Submitted with the PMN:
Salmonella assay negative with and without activation; E. coli reverse mutation assay negative with and without activation

Ecotox : Test Organism Test Type Test End Point Predicted Measured Comments

fish 96-h LC50 * daphnid 48-h LC50 * green algal 96-h EC50 * fish

_ chronic value * daphnid

_ chronic value *
algal

_ chronic value *
Sewage Sludge 3-h EC50

_ Sewage Sludge

_ Chronic Value _

Ecotox Values Comments: Predictions are based on SARs for

p H7; effective concentrations based on 100% active ingredients and nominal concentrations; hardness <150.0 mg/L as CaCO3; and TOC <2.0 mg/L;

Factors Values Comments Assessment Factor 10 Concentration of Concern ( p pb) *

SARs
Ecotox Category

### Ecotox Factors Comments:
SAT Chair: J. Kwiat

# A-002 Initial Review Engineering Report
for PMN P-11-561

### INITIAL REVIEW ENGINEERING REPORT PMN: 11-0561 Focus Ready Draft 9/8/2011
ENGINEER: El-Zoobi \ CLM PV (kg/yr):

SUBMITTER:

USE:

OTHER USES:

CRSS :

### Consumer Use: No
SAT (concerns) (08/30/2011):

Migration to groundwater: Negligible PBT rating: P3B2T1 PMN: P3B1T1 // Incin Pdt: P3B2 Health: 1-2 Dermal, Inhalation Eco: 1 No releases to Water

OCCUPATIONAL EXPOSURE RATING: 2-3B

NOTES & KEY ASSUMPTIONS: Generated by the 06/07/2005 version of ChemSTEER.

### POLLUTION PREVENTION CONSIDERATIONS: None.

EXPOSURE-BASED REVIEW: No

INITIAL REVIEW ENGINEERING REPORT PMN: 11-0561

Use:

Number of Sites/ Location: 7 unknown sites Days/yr: 200 Basis:

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium.

Water or Air or Incineration or Landfill Output 2: 1.4E+0 kg/site-day over 200 days/yr from 7 sites or 2.0E+3 kg/yr

Water or Incineration or Landfill Output 2: 2.9E+0 kg/site-day over 200 days/yr from 7 sites or 4.0E+3 kg/yr

### Water or Incineration or Landfill Conservative: 5.7E+0 kg/site-day over 200 days/yr from 7 sites or 8.0E+3 kg/yr

Water or Landfill Output 2: 2.9E+0 kg/site-day over 200 days/yr from 7 sites or 4.0E+3 kg/yr

RELEASE TOTAL 1.8E+4 kg/yr - all sites

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

# A-003 Initial Review Exposure Report
for PMN P-11-561

### INITIAL REVIEW EXPOSURE REPORT (IRExR)

Chemical ID: P-11-0561 Reviewer: Kwon/JB Results Table: Dose, Concentration, and Days Exceeded Results Summary

Exposure Scenario 1 Water Landfill Stack Air Fugitive Air Drinking Water Fish Ingestion ADR LADD ADR LADD 7Q10 4 CC = 1000 PDM Days Exceeded LADD ADR LADD ADR LADD

Release activity(ies) 2 ; exposure calculation(s) 3 mg/kg/day mg/kg/day mg/kg/day mg/kg/day μg/l # Days mg/kg/day mg/kg/day mg/kg/day mg/kg/day mg/kg/day

Use: Max ADR: max acute eco 7.86E-03 --- --- --- --- --- --- 1.24E-05 --- 3.49E-02 ---

Use: PDM1 --- --- --- --- 1.66E+02 1 --- --- --- --- --- Use: Max LADD --- 1.39E-04 --- --- --- --- --- --- 5.43E-07 --- 6.16E-04

1 Exposure scenario titles consist of release activity followed by exposure calculation abbreviation. 2 Release activities are from engineering report's Manuf acturing (Mfg), Processing (Proc) and Use release activity labels. Multiple release activities are combined in one exposure scenario if their releases occur at same location. 3 Exposure calculations are Acute Dose Rate (A DR), Lifetime Average Daily Dose (LADD), and Probabilistic Dilution Model (PDM). There may be one, two, or all three exposure calculations per exposure scenario. CC is the aquatic concentration of concern. 4 This column displays concentration values for the 7Q 10 streamflow, which is defined as the average daily streamflow of the seven consecutive days of lowest flow within a ten year period.

Remarks: 

### Results Table: Exposure Based (X B)/Persistent (P2B2) Criteria

Parameter Exp Based Persistent Exceedance Value Drinking (Surface) Wate r Dose (mg/kg/day) NA No Fish Ingestion Dose (mg/kg/day) NA No Inhalation Dose (mg/kg/day) NA No Groundwater Dose (mg/kg/day) NA No Surface Water Release After Treatment (kg/yr) NA Yes 1.81E+03 Total Release After Treatment (kg/yr) NA Yes 3.57E+03 Consumer Use? No 

### Fate test recommendations?: (default is NA)INITIA L REV IEW EXPOSURE REPORT

Chemical ID: P-11-0561 Assessor: Kwon/JB

ENVIRONMENTAL RELEASES
Scenario#:1 Number of Release Sites: 7. Release Activity: Use: Max ADR Release Description: WATER LANDFILL Non-sludge/Sludge STACK FUGITIVE

Total Releases: 1.81E+04 N/A 1.40E+04 1960.00 (kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge Release Days/yr: 200.00 0.00/0.00 200.00 200.00
Per Site Release: 12.90 N/A/0.00 10.00 1.40 (kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:September 7, 2011 Page of

INITIAL REVIEW EX POSURE REPORT

Chemical ID: P-11-0561

SIC-CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 1 Number of Site s: 7 RELEASE ACTIVITY:Use: Max ADR
SIC-CODE DESCRIPTION: SIC-CODE (S): EXPOSED POPULATION: Adult

WWT REMOVAL (%) RELEASE DAYS PRETREATMENT RELEASE (kg/site/day) POSTTREATMENT RELEASE (kg/site/day) DWT (%) BCF (L/kg)
90.00 200. 12.9 1.29 0.00 0.00

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER
PLANT TYPE % ILE FACILITY STREAM FLOW (MLD) STREAM CONC. ( μ g/l)

Harmonic

Mean 30Q5 7Q10 1Q10 Harmonic Mean 30Q5 7Q10 1Q10
ALL 50
ALL 10

DRINKING WATER AND FISH IN GESTION EXPOSURE ESTIMATES

Exposure Units Drinking Water Results Drinking Water Units Fish Ingestion Results Fish Ingestion

Units 50% 10% 50% 10%
Cancer
LADD pot 4.17E-06 1.24E-04 mg/kg/day 0.00 0.00 mg/kg/day
LADC pot 2.14E-04 6.35E-03 mg/L 0.00 0.00 mg/kg
Acute
ADR pot 1.78E-04 7.86E-03 mg/kg/day 0.00 0.00 mg/kg/day

SIC Code Comments:INITIAL REV IEW EX POSURE REPORT

Chemical ID: P-11-0561

SIC CODE EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 1 RELEASE ACTIVITY: Use: Max ADR
SIC CODE DESCRIPTION
ASSOCIATED SIC CODES:

SIC CODE RESULTS

COC ( μ g/L) Percent of Year COC Exceeded Number of Days COC Exceeded Release days/year Loading (kg/site/day) Waste Water Treatment (%) High/Avg Analysis

1000.00 0 2 200.00 12.90 90.00 HighINITI A L REVIEW EX POSURE REPORT Chemical ID: P-11-0561

INHALATION EXPOSURE ESTIMATES (POST-TREATMENT)

SCENARIO #: 1 RELEASE ACTIVITY:Use: Max ADR
RELEASE DESCRIPTION:
METHOD OF CALCULATION: Screen3
EXPOSED POPULATION: Adult

Number of Sites: 7. Per Site Fugitive Release: 1.40 kg/site/day Fugitive Release Days per Year: 200.00 days % Removal via Fugitive Release: 0.00 % Total Fugitive Release: 1960.00 kg/yr Max Annual Average Air Concentration (Fugitive): 8.38 μg/m 3

Max 24 Hour Average Air Concentration(Fugitive): 190.00 μg/m 3

Per Site Stack Release: 10.00 kg/site/day Stack Release Days per Year: 200.00 days
% Removal via Stack Release: 99.90 %
Total Stack Release: 1.40E+04 kg/yr Max Annual Average Air Concen tration (Stack): 7.38E-03 μg/m 3 Max 24 Hour Average Air Concentration (Stack): 6.74E-02 μg/m 3

ASSUMPTIONS Exposure Units Results (Stack) Results (Fugitive) ED (years) AT (years) BW (kg) Inh. Rate (m 3 /hr)
Cancer
LADD pot (mg/kg/day) 5.43E-07 6.16E-04 30.00 75.00 71.80 0.55
LADC pot (mg/m 3 ) 2.95E-06 3.35E-03 30.00 75.00 NA NA
Acute
ADR pot (mg/kg/day) 1.24E-05 3.49E-02 NA 1 day 71.80 0.55

Inhalation Comments:Stack Parameter Data Fugitive Parameter Data Stack Height 10.00 m Release Height: 3.00 m
Inside Stack Diameter: 0.10 m Length of Release Opening: 10.00 m

Stack Gas Exit Velocity: 0.10 m/sec Width of Release Opening: 10.00 m

Stack Gas Temperature: 293.00 K

Meteorological and Terrain Information:
Surrounding Land Use: Rural Terrain Height: 0.00 m
Distance to Residence of Interest: 100.00 m Meteorological Class: Full Stability Class: NA Wind Speed: NA

Downwash Information:
Facility Length: NA m Facility Width: NA m Facility Height: NA mINITIA L REV IEW EXPOSURE REPORT

Chemical ID: P-11-0561 Assessor: Kwon/JB

ENVIRONMENTAL RELEASES
Scenario#:2 Number of Release Sites: 7. Release Activity: Use: PDM1 Release Description: WATER LANDFILL Non-sludge/Sludge STACK FUGITIVE

Total Releases: 1.81E+04 N/A 0.00 0.00 (kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge Release Days/yr: 200.00 0.00/0.00 0.00 0.00
Per Site Release: 12.90 N/A/0.00 0.00 0.00 (kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:September 7, 2011 Page of

INITIAL REVIEW EX POSURE REPORT

Chemical ID: P-11-0561

SIC-CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 2 Number of S ites: 7 RELEASE ACTIVITY:Use: PDM1 SIC-CODE DESCRIPTION: POTW (Indust., incl udes POTWs which receive ind. disch.) SIC-CODE (S): Subset of 49 52 EXPOSED POPULATION: Adult

WWT REMOVAL (%) RELEASE DAYS PRETREATMENT RELEASE (kg/site/day) POSTTREATMENT RELEASE (kg/site/day) DWT (%) BCF (L/kg)
90.00 200. 12.9 1.29 0.00 0.00

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER
PLANT TYPE % ILE FACILITY STREAM FLOW (MLD) STREAM CONC. ( μ g/l)

Harmonic

Mean 30Q5 7Q10 1Q10 Harmonic Mean 30Q5 7Q10 1Q10
ALL 50 288.00 123.84 78.18 66.05 4.48 10.42 16.50 19.53
ALL 10 39.60 13.29 7.76 7.57 32.58 97.07 166.24 170.41

DRINKING WATER AND FISH IN GESTION EXPOSURE ESTIMATES

Exposure Units Drinking Water Results Drinking Water Units Fish Ingestion Results Fish Ingestion

Units 50% 10% 50% 10%
Cancer
LADD pot 1.91E-05 1.39E-04 mg/kg/day 0.00 0.00 mg/kg/day
LADC pot 9.82E-04 7.14E-03 mg/L 0.00 0.00 mg/kg
Acute
ADR pot 8.70E-04 8.11E-03 mg/kg/day 0.00 0.00 mg/kg/day

SIC Code Comments:INITI A L REVIEW EX POSURE REPORT

Chemical ID: P-11-0561

SIC CODE EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 2 RELEASE ACTIVITY: Use: PDM1 SIC CODE DESCRIPTION: POTW (Indust., includes POTWs which receive ind. disch.)
ASSOCIATED SIC CODES: Subset of 4952

SIC CODE RESULTS

COC ( μ g/L) Percent of Year COC Exceeded Number of Days COC Exceeded Release days/year Loading (kg/site/day) Waste Water Treatment (%) High/Avg Analysis

1000.00 0 1 200.00 12.90 90.00 HighINITIA L REV IEW EXPOSURE REPORT

Chemical ID: P-11-0561 Assessor: Kwon/JB

ENVIRONMENTAL RELEASES
Scenario#:3 Number of Release Sites: 7. Release Activity: Use: Max LADD Release Description: WATER LANDFILL Non-sludge/Sludge STACK FUGITIVE

Total Releases: 1.81E+04 N/A 1.40E+04 1960.00 (kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge Release Days/yr: 1.00 0.00/0.00 1.00 1.00
Per Site Release: 2580.00 N/A/0.00 2000.00 280.00 (kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:September 7, 2011 Page of

INITIAL REVIEW EX POSURE REPORT

Chemical ID: P-11-0561

SIC-CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 3 Number of Site s: 7 RELEASE ACTIVITY:Use: Max LADD SIC-CODE DESCRIPTION: POTW (Indust., incl udes POTWs which receive ind. disch.) SIC-CODE (S): Subset of 49 52 EXPOSED POPULATION: Adult

WWT REMOVAL (%) RELEASE DAYS PRETREATMENT RELEASE (kg/site/day) POSTTREATMENT RELEASE (kg/site/day) DWT (%) BCF (L/kg)
90.00 1. 2580. 258.00 0.00 0.00

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER
PLANT TYPE % ILE FACILITY STREAM FLOW (MLD) STREAM CONC. ( μ g/l)

Harmonic

Mean 30Q5 7Q10 1Q10 Harmonic Mean 30Q5 7Q10 1Q10
ALL 50 288.00 123.84 78.18 66.05 N/A N/A N/A N/A
ALL 10 39.60 13.29 7.76 7.57 N/A N/A N/A N/A

DRINKING WATER AND FISH IN GESTION EXPOSURE ESTIMATES

Exposure Units Drinking Water Results Drinking Water Units Fish Ingestion Results Fish Ingestion

Units 50% 10% 50% 10%
Cancer
LADD pot 1.91E-05 1.39E-04 mg/kg/day 0.00 0.00 mg/kg/day
LADC pot 9.82E-04 7.14E-03 mg/L 0.00 0.00 mg/kg
Acute
ADR pot N/A N/A mg/kg/day N/A N/A mg/kg/day

SIC Code Comments:INITI A L REVIEW EX POSURE REPORT Chemical ID: P-11-0561

INHALATION EXPOSURE ESTIMATES (POST-TREATMENT)

SCENARIO #: 3 RELEASE ACTIVITY:Use: Max LADD
RELEASE DESCRIPTION:
METHOD OF CALCULATION: Screen3
EXPOSED POPULATION: Adult

Number of Sites: 7. Per Site Fugitive Release: 280.00 kg/site/day Fugitive Release Days per Year: 1.00 days % Removal via Fugitive Release: 0.00 % Total Fugitive Release: 1960.00 kg/yr Max Annual Average Air Concentration (Fugitive): 8.38 μg/m 3

Max 24 Hour Average Air Concentration(Fugitive): N/A μg/m 3

Per Site Stack Release: 2000.00 kg/site/day Stack Release Days per Year: 1.00 days
% Removal via Stack Release: 99.90 %
Total Stack Release: 1.40E+04 kg/yr Max Annual Average Air Concen tration (Stack): 7.38E-03 μg/m 3 Max 24 Hour Average Air Concentration (Stack): N/A μg/m 3

ASSUMPTIONS Exposure Units Results (Stack) Results (Fugitive) ED (years) AT (years) BW (kg) Inh. Rate (m 3 /hr)
Cancer
LADD pot (mg/kg/day) 5.43E-07 6.16E-04 30.00 75.00 71.80 0.55
LADC pot (mg/m 3 ) 2.95E-06 3.35E-03 30.00 75.00 NA NA
Acute
ADR pot (mg/kg/day) N/A N/A NA 1 day 71.80 0.55

Inhalation Comments:September 7, 2011 Page of

Stack Parameter Data Fugitive Parameter Data Stack Height 10.00 m Release Height: 3.00 m
Inside Stack Diameter: 0.10 m Length of Release Opening: 10.00 m

Stack Gas Exit Velocity: 0.10 m/sec Width of Release Opening: 10.00 m

Stack Gas Temperature: 293.00 K

Meteorological and Terrain Information:
Surrounding Land Use: Rural Terrain Height: 0.00 m
Distance to Residence of Interest: 100.00 m Meteorological Class: Full Stability Class: NA Wind Speed: NA

Downwash Information:
Facility Length: NA m Facility Width: NA m Facility Height: NA m

# A-004 TSCA Section 5(e) Consent Order and Determinations Supporting Consent Order
for PMN P-11-561