# EMISSIONS TEST REPORT

POLK POWER STATION UNIT 1 FACILITY ID NUMBER: 1050233 EMISSION UNIT ID NO: -001

SULFURI C ACI D MIST (SAM) February 7, 2006

Prepared For: Tampa Electric Company Polk Po wer Station P.O. Box 111 Tampa, Florida 33601- 0111

Prepared By: Tampa Electric Company Environmental Affairs Department Environmental Servic es, Air Services Group

Envi ronme n tal Servi c es Ai r Servi c es Grou p 5010 Cau s e w ay Boul eva r d Tampa, Fl ori da 336 19- 6 1 30

## REPORT CERTIFICATION

I ha ve revi ewed the t e st perfor ma nce, associated quality assura nce activities, the resulta n t calculations, a n d the contents of this repor t , a n d certify that a ll proj ect quality obj ectives have been met. Th is r

e port is approved for submitta l.

Signature:__________________________ Raymond A

. McDarby, Jr. Senior Envi ronmenta l Technician Quality Assurance/Quality Control Specialist Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

The sampling and subseque nt da ta entry/reduction det a iled in this report were cond ucted at m y d i rection

, and I here by certif y

t h at t h is tes t report is authentic and accurate to t h e best of my knowledge.

Signature:__________________________ Charles R. Dufeny Enviro nme n tal Techni cian Test Team Lead Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

I ha ve revi ewed the t e sting deta ils and results subm itt e d in t h is r e port, and hereby certify that this test report is authenti c and accurate to the best of my k n owle dge.

Signature:__________________________ Davi d A

. S m ith Coordi nator – Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

## TABLE OF CONTENTS

SECTION PAGE NO. 1.0 INTRODUCTION 1 2.0 DISCUSSION OF RESULTS 2 3.0 SOURCE DESCRIPTION/TEST PROCEDURES 3 4.0 TABULATED RESULTS SULFURIC ACID MIST TEST SUMMARY 5 NITROGEN OXIDES & SULFUR DIOXIDE DATA FROM CEMS 6 HEAT INPUT CALCULATIONS 7 5.0 STACK SAMPLING LOCATION DIAGRAM 9

APPENDICES A. SULFURIC ACID MIST TEST INFORMATION CALCULATED RUN DATA LABORATORY ANALYSIS FIELD DATA SHEETS EQUIPMENT CALIBRATIONS

B. TURBINE DATA (PLANT INFORMATION SYSTEM) C. FUEL ANALYSIS D. CEMS DATA E. VISIBLE EMISSION DATA SHEET F. TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION
On February 7, 2006, Tampa El ectric Company’s, Environmental Services, Air Services Group performed Sulfuric Acid Mist (SAM) sour ce emission tests on Unit No. 1 at the Polk Power Station. Unit No. 1 is an integrated coal gas ification combined cycle (IGCC) generating unit. The combustion turbine was fired with syngas from the coal gasification system. A blend of petroleum coke and bituminous coal was gasified for this test. Testing was conducted according to United States Envi ronmental Protection Agency (USEPA) test methods stipulated in 40 CFR Part 60, Appendix A and Florida Department of Environmental Protecti on (FDEP) Permit No. 1050233-016-AV.

Nitrogen Oxides (NO x 

### ) and Sulfur Dioxide (SO 2 

### ) data was taken from the Continuous Emissions Monitoring System’s (CEMS) Da ta Acquisition and Handling System (DAHS) and is presented as averages over the test period.

### 2 

## 2.0 DISCUSSION OF RESULTS

The Sulfuric Acid Mist (H 2 

### SO 4 

### ) emission rate was derived from three 1-hour test runs. The calculated average H 2 

### SO 4 

### emission rate was 31 lbs/hr. The FDEP permitted emission rate is 55 lbs/hr based on a 30-day rolling average.

Sulfur Dioxide (SO 2 

### ) concentration and emissions during t he sulfuric acid mist testing were determined to be 0.19 lb/mmBtu and 339 lbs/hr.

Nitrogen Oxides (NOx) concentration and emissions during the sulfuric acid mist testing were determined to be 12 ppmvd @ 15% O 2 

### , 0.056 lbs/mmBtu, and 99 lbs/hr.

During the tests on February 7, 2006, Unit No. 1 Combustion Turbine was operated at an average load of 192 megawatts and an aver age heat input of 1774 mmBtu/hr. The FDEP permitted heat input is 1755 mmBtu/hr, at an ambient te mperature of 59o (corrected to 1751 mmBtu/hr based on an average inlet vane temperature of 73oF, and the manufacturer’s heat input correction curve for this unit). The calculated capacity factor during the test was 101%.

### 3 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES

Polk Power Electrical Generat ing Station is located at County Road 630 approximately 13 miles southwest of Bartow, Polk County, Florida. Unit No. 1 is an IGCC generating unit, with a net capacity of 192 MW when fir ed with Syngas fuel. The source sampling location consists of a circular stack 19 feet in diameter with four sample ports located 90 degrees apart on the stack circumfe rence. A diagram of the stack sampling location is included along with other pertinent information on the test site.

Sulfuric acid mist sampling and analysi s was performed in accordance with USEPA Reference Method 8 (40 CFR Part 60, Appendix A) "Determinati on of Sulfuric Acid Mist and Sulfur Dioxide Emissions from Stat ionary Sources”, and FDEP Permit No. 1050233- 016-AV, Condition A.56.

Sulfur Dioxide and Nitrogen Oxides emissions data were taken from the CEMS DAHS. This data was taken as 1-minute averages over the time frame from 9:12 through 13:49, representing the time frame of the sulfuric acid mist test.

Plant operational data was taken from the Plant Information (PI) server system. This data was taken as 1-minute averages over the time period from 9:12 through 13:49, representing time frame of t he sulfuric acid mist tes t. Data captured included the average unit load, average fuel flow, aver age inlet vane temperature, and average saturator readings. Details are included in Appendix B.

### 4 

## 4.0 TABULATED RESULTS

### Environmental Services Air Ser v ices Gro u p

40 C F R 60 , Append ix A - T e s t M e t h ods Re fe re nc e Me tho d 8 T e s t S u mma ry

Customer: P olk Pow e r Sta t io n Fa cility: Unit 1 Sa m p ling Loca t ion : S t a ck Operating Conditio ns: Full Loa d Te st D a t e : F eb rua r y 7, 20 06 Run #1 Run #2 R un #3 Ave r ag e Ga s Flow R a tes Q s , a c f m : 141308 7.9 13966 68.7 1 4 05512.1 1405089.5 9 Q s( st d ) , dscfm: 907742 .9 9029 94.6 9 02109.2 904282.2 2 Sa mpled V olume, V m(s t d) , dscf: 39.69 39.29 39.29 39.42 1 Stack Moisture, B ws x 100, %: 4.63 4.15 4.49 4.42 6 Isok inetic Sa m p l i n g R a t e , I, %: 97.6 9 7

. 1 97.2 97.3

C

H2S O 4, lb/dsc f : 6.255E -07 5 .493 E

- 07 5

. 092E -07 5 .613E -0 7 E H2SO4 , l b /mmBt u : 0.0166 0.01 44 0.0137 0.014 9 E H2S O 4 , lbs/hr: 34 3 0 28 3 1



### 5

### 7 

## POLK POWER STATIO N N O X 

## & S O 2 

## COMPLIANCE DATA FROM CEM S

NO x 

### SO 2 

### O 2 

### CO 2 

### NO x 1 

### NO x 2 

### SO 2 3 

### SO 2 4



### ppmvw ppmvw % w % w ppmvd @ 15% O 2 

### lbs/hr lb/mmBtu lbs/hr From CEMS Report: 17.62 43.47 10.46 8.72 12 99 0.19 339

1 

### NO x 

### , ppmvd @ 15% O 2 

### is calculated as: NO x 

### , ppmvw / (1 - % moisture) x (5.9 / (20.9 - (% O 2 

### w/ (1 - % moisture))) where: % moisture = 0.07 assumed by CEMS

2 

### NO x 

### , lbs/hr is calculated as: NO x 

### , ppmvw x 1.194E-07 x F c 

### x (100 / % CO 2 

### w) x Heat Input, mmBtu/hr where: F c 

### = 2310 scf/mmBtu, assigned F-fa ctor for synthetic gas Heat Input = 1774 mmBtu/hr NOx, lbs/mmBtu is calculated as: NO x 

### , ppmvw x 1.194E-07 x F c 

### x (100 / % CO 2 

### w) = 0.056 lbs/mmBtu 3 

### SO 2 

### , lb/mmBtu is calculated as: SO 2 

### , ppmvw x 1.660E-07 x F c 

### x (100 / % CO 2 

### w) where: F c 

### = 2310 scf/mmBtu, assigned F-fa ctor for synthetic gas

4 

### SO2, lbs/hr is calculated as: SO2, lb/mmbtu x Heat Input, mmBtu/hr where: Heat Input = 1774 mmBtu/hr CEMS Data are average of readings from 02/07/2006 09:11 through 13:49. 

### COMBINED CYCLE COMBUSTION TURBINE UNIT 1 February 7, 2006

CEM Data Calculated Data

## POL K

POWER STATIO N HEAT I N P U

T CAL C

UL AT I O N

Average fuel flow: 7306.5726 Kcfh Mole w e ight correc t ion to mete r cal: 0.98 83 mole w e ight co rrect io n fact o r Cor r ected fuel f l ow: 1 7221.0857 Kc fh, corrected for density Average moisture: 6 .282 8935 % H 2 

### 0 ad d e d t o

fuel Cor r ected fuel f l ow: 2 6767.3926 Ks cfh, corrected for moisture Gross heating va lue of fuel (HHV): 262.08 B tu/sc f Heat I n put: 177 4 mmBtu/hr

Av erage fuel flo w fro m P l ant In formation D a ta Base. Mole w e ight correc t ion factor to meter cali brat ion is taken from ratio of syngas mole weight to cali bration gas m o le weight. 1Avera ge fuel flow times mole weight corre ction factor

. 2Corre cted fuel flow times (1 - (Average moisture / 100 )). Gross Heating valu e of fuel (HHV) is from f u el analysis. Heat input is (HHV x Corrected fuel flow) / 1000. 

### CO MBI N ED CYCL E CO MBUS T I O N T U RBI N E UNI T 1 Fe b r uar y 7, 2006

7

### 8 

## 5.0 SAMPLING LOCATION TRAVERSE DIAGRAM

### 9 UN F I RE D H E AT

RE CO VE RY

BO I L E R T R AN SI T I O N

DU CT

EX HA US T F R O M TU R B I N E 1 4 FT.

3 8 FT. 15 0

F T

.

13 6

F T

.

P O RT L O CA T I O N P L A N 1 9

. 0 FT. I D

.

ST AC K D I AM ET ER S D O W N S T R E A M FR O M D I ST UR BAN CE = 2. 0 S T A C K D I AM ET ER S U P S T R E A M FR O M D I S T U R BA N C E = 0.7 ST AC K D I AM E T E R = 1 9

. 0 F T

. S T A C K A R E A = 28 3.5 29 S Q

. F T

. ST AC K A R E A = 4 0 8 2 8

. 1 38 SQ

. I N

.

TR A V ER S E P O I N T S 1

- 4.7 9 ” 2

- 1 5 .2 8 ” 3

- 2 6 .9 0 ” 4

- 4 0 .3 6 ” 5

- 5 7 .0 0 ” 6

- 8 0 .1 7 ”

AD D 1 3 ” PO RT L E NG T H TO P O I N T S 

### Po l k Po we r St a t io n Un i t No

. 1 IG CC T e st Lo ca t i on

## APPENDIX A

SULFURIC ACID MIST TEST INFORMATION

### CALCULATED RUN DATA

### Environmental Services A ir Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 8

Test Calculations

Customer: Polk Power Station Facility: Unit 1 Sampling Location: Stack Operating Conditions: Full Load Run Number: 1 Date: 02/07/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.197 inches Barometric Pressure, P b : 29.85 "Hg Nozzle Area, A n : 0.00021166 ft 2 Stack Pressure, P s : 29.78 "Hg Average Orifice Meter, ∆ H: 1.445 "H 2 O Effective Stack Area, A s : 283.529 ft 2 Sample Volume, V m : 39.682 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 71.8 o F Gas Analysis: 8.7 % CO 2 Average Stack Temp., T s : 320.3 o F 10.6 % O 2 Average √ ∆ p: 1.223 "H 2 O

0.0 % CO Condensate Volume, V lc : 40.9 ml 80.7 % N 2 Meter Box Y: 1.006 dimensionless

Data Calculated from Source Measurements: V w(std) = 4.714E-02 x V lc 1.928 scf V m(std) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 39.686 dscf B ws = V w(std) / (V m(std) + V w(std) ) 0.046 % FDA = 1.0 - B ws 0.954 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.82 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 29.27 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 83.07 ft/second Q s = v s x A s x 60 1413087.9 acf/minute Q s(std) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 907742.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60 97.6 %

Data from Laboratory Analysis: H 2 SO 4 Normality of Barium Chloride titrant, N 0.00969 Volume Titrant Blank, V tb 0.01 Volume Titrant Sample, V t 4.75 Volume of Sample Aliquot, V a 100 Total Volume of Solution, V soln 500

Calculated Concentration and Emission Rate Data:

C H2SO4 = 1.081E-04 x (N x (V t - V tb ) x (V soln / V a )) / V m(std) = 6.255E-07 lb/dscf F c -factor = 2310 dscf/mmBtu E H2SO4 = C H2SO4 x F c -factor x (100/%CO 2 ) = 0.01661 lb/mmBtu E H2SO4 = C H2SO4 x Q s(std) x 60 = 34 lb/hr

### Environmental Services A ir Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 8

Test Calculations

Customer: Polk Power Station Facility: Unit 1 Sampling Location: Stack Operating Conditions: Full Load Run Number: 2 Date: 02/07/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.197 inches Barometric Pressure, P b : 29.90 "Hg Nozzle Area, A n : 0.00021166 ft 2 Stack Pressure, P s : 29.83 "Hg Average Orifice Meter, ∆ H: 1.420 "H 2 O Effective Stack Area, A s : 283.529 ft 2 Sample Volume, V m : 39.304 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 72.9 o F Gas Analysis: 8.8 % CO 2 Average Stack Temp., T s : 320.5 o F 10.5 % O 2 Average √ ∆ p: 1.211 "H 2 O

0.0 % CO Condensate Volume, V lc : 36.1 ml 80.7 % N 2 Meter Box Y: 1.006 dimensionless

Data Calculated from Source Measurements: V w(std) = 4.714E-02 x V lc 1.702 scf V m(std) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 39.285 dscf B ws = V w(std) / (V m(std) + V w(std) ) 0.042 % FDA = 1.0 - B ws 0.958 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.83 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 29.34 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 82.10 ft/second Q s = v s x A s x 60 1396668.7 acf/minute Q s(std) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 902994.6 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x 97.1 %

Data from Laboratory Analysis: H 2 SO 4 Normality of Barium Chloride titrant, N 0.00969 Volume Titrant Blank, V tb 0.01 Volume Titrant Sample, V t 4.13 Volume of Sample Aliquot, V a 100 Total Volume of Solution, V soln 500

Calculated Concentration and Emission Rate Data:

C H2SO4 = 1.081E-04 x (N x (V t - V tb ) x (V soln / V a )) / V m(std) = 5.493E-07 lb/dscf F c -factor = 2310 dscf/MMBtu E H2SO4 = C H2SO4 x Q s(std) x 60 = 30 lb/hr

### Environmental Services A ir Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 8

Test Calculations

Customer: Polk Power Station Facility: Unit 1 Sampling Location: Stack Operating Conditions: Full Load Run Number: 3 Date: 02/07/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.197 inches Barometric Pressure, P b : 29.86 "Hg Nozzle Area, A n : 0.00021166 ft 2 Stack Pressure, P s : 29.79 "Hg Average Orifice Meter, ∆ H: 1.442 "H 2 O Effective Stack Area, A s : 283.529 ft 2 Sample Volume, V m : 39.733 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 78.0 o F Gas Analysis: 8.6 % CO 2 Average Stack Temp., T s : 322.4 o F 11.8 % O 2 Average √ ∆ p: 1.216 "H 2 O

0.0 % CO Condensate Volume, V lc : 39.2 ml 79.6 % N 2 Meter Box Y: 1.006 dimensionless

Data Calculated from Source Measurements: V w(std) = 4.714E-02 x V lc 1.848 scf V m(std) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 39.292 dscf B ws = V w(std) / (V m(std) + V w(std) ) 0.045 % FDA = 1.0 - B ws 0.955 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.85 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 29.32 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 82.62 ft/second Q s = v s x A s x 60 1405512.1 acf/minute Q s(std) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 902109.2 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x 97.2 %

Data from Laboratory Analysis: H 2 SO 4 Normality of Barium Chloride titrant, N 0.00969 Volume Titrant Blank, V tb 0.01 Volume Titrant Sample, V t 3.83 Volume of Sample Aliquot, V a 100 Total Volume of Solution, V soln 500

Calculated Concentration and Emission Rate Data:

C H2SO4 = 1.081E-04 x (N x (V t - V tb ) x (V soln / V a )) / V m(std) = 5.092E-07 lb/dscf F c -factor = 2310 dscf/MMBtu E H2SO4 = C H2SO4 x Q s(std) x 60 = 28 lb/hr

### LABORATORY ANALYSIS

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 Report For: 

## Laboratory ID: AA82175

Date and Time Collected: Sampled By: 

### Sample Information Description: 

### Location Code: 2/13/2006 Report Date:

Polk No. 1 Acid Mist Comp on Syngas 

### TE_PPS_1_SAM_SYNGAS

Project Account Code: 2/8/2006 Date of Sample Receipt: Sample Collection Method: 

### Laboratory Results 2/8/2006 12:00:00 AM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit Normality of BaCl2 * 2H2O 0.0001 MM 0.00969 2/8/2006 8:30:00 AM SO3 emission rate, lbs/hr lbs/hr EPA - RM8 RAM 31 2/13/2006 1:25:00 PM SO3, Avg. of Blank Titrations milliliters 0.01 EPA - Meth.8 MM 0.01 I 2/8/2006 8:30:00 AM SO3, Run #1, Avg. of Titrations milliliters 0.01 EPA - Meth.8 MM 4.75 2/8/2006 8:30:00 AM SO3, Run #2, Avg. of Titrations milliliters 0.01 EPA - Meth.8 MM 4.13 2/8/2006 8:30:00 AM SO3, Run #3, Avg. of Titrations milliliters 0.01 EPA - Meth.8 MM 3.83 2/8/2006 8:30:00 AM SO3, Volume of Contained Sample milliliters 1 EPA - Meth.8 MM 500 2/8/2006 8:30:00 AM SO3, Volume of Sample Aliquot milliliters 0.1 EPA - Meth.8 MM 100 2/8/2006 8:30:00 AM 

### Comments

Data Qualifier Codes Explanation:



### Robert Dorey, Manager, Laboratory Services I - The reported value is between the laboratory method detection limit (MDL) and the laboratory pr actical quantitation limit ( PQL). PQL = 4 x MDL. Subcontracted Laboratories:

A ll results calculated on a wet to wet basis

, unless otherwise indicated.

Report Number: -021306- 13 AA82175 Page 1 of 1 Laboratory Services certifies that the te st results in this report meet all require ments of the NELAC standards, unless indicat ed otherwise in the body of the report.

### FIELD DATA SHEETS

### EQUIPMENT CALIBRATIONS

### Environmental Services A ir Services Group



## SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS CONSOLE (MB 06) USEPA RM 5 INITIA L 01/04/2006 (ORIFICE) 1.006 POST TEST 02/09/2006 1.011 NOZZLE (SN06) CALIPER INITIA L 01/04/2006 MEASUREMENTS 0.197 POST TEST 02/09/2006 0.197

PYROMETER (PY 10) 01/04/2006 ASTM THERMOMETER + 2 o 

### F

PITOT TUBE (PT 10) 10/17/2005 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 02) 01/03/2006 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Red Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30 "Hg Instrument Code Number: ^MB06 Theoretical Critical Vacuum: 14.15 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.64 15 46.100 52.925 6.825 77 77 77 77 1.15 15 52.925 62.029 9.104 78 77 77 78 1.95 15 62.029 73.770 11.741 77 78 83 78 3.70 15 73.770 89.845 16.075 83 78 89 79

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3483 22.5 75 75 75.0 55 0.4660 20.0 75 75 75.0 63 0.5971 19.0 75 75 75.0 73 0.8177 16.0 75 75 75.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.736 6.776 6.851 1.006 0.000 1.739 -0.032 8.989 9.066 9.165 1.009 0.003 1.744 -0.027 11.583 11.617 11.744 1.003 -0.003 1.796 0.025 15.830 15.909 16.083 1.005 -0.001 1.806 0.035 Averages: 1.006 1.771

Review/Approval: Date: 18-Jan-06 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

1/4/2006

JAV

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice

### Environmental Services Air Services Group

Manufacturer: Thermo Calibration Date: Model Number:MST Barometric Pressure: 30.24 "Hg Instrument Code Number: MB06 Theoretical Critical Vacuum: 14.26 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: RED

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 1.15 10 978.800 984.870 6.070 80 75 80 76 1.15 10 984.870 990.952 6.082 80 76 80 77 1.15 10 990.952 997.042 6.090 80 77 80 77

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4660 21.0 73 72 72.5 55 0.4660 21.0 72 72 72.0 55 0.4660 21.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.038 6.107 6.096 1.011 0.001 1.721 0.002 6.044 6.110 6.093 1.011 0.000 1.718 -0.001 6.050 6.110 6.093 1.010 -0.001 1.717 -0.002 Averages: 1.011 1.719 Prior Y: 1.006 % Difference: -0.47%

Review/Approval: Date: IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

RAB 2/9/2006 

### POST - TEST CALIBRATION CHECK

2/10/2006 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Services A ir Services Group

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET

Calibration Date: 1/4/2005 Responsible Party: R.A. Barthelette Jr.

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches ^SN01 0.300 0.300 0.300 0.000 0.118 ^SN04 0.320 0.320 0.320 0.000 0.126 ^SN05 0.380 0.380 0.375 0.002 0.149 ^SN06 0.500 0.500 0.500 0.000 0.197 ^SN09 0.700 0.700 0.700 0.000 0.276 ^SN10 0.755 0.755 0.750 0.002 0.297 ^SN12 0.985 0.990 0.990 0.002 0.389 ^SN15 0.420 0.420 0.415 0.002 0.165 ^SN16 0.500 0.500 0.500 0.000 0.197 ^SN19 0.715 0.710 0.710 0.002 0.280 ^SN22 0.930 0.935 0.935 0.002 0.367 ^SN30 0.795 0.800 0.795 0.002 0.314 ^SN36 0.480 0.480 0.480 0.000 0.189 ^SN37 0.520 0.525 0.525 0.002 0.206 ^SN38 0.640 0.640 0.635 0.002 0.251 ^SN46 0.480 0.480 0.480 0.000 0.189 ^SN47 0.515 0.515 0.515 0.000 0.203 ^SN48 0.640 0.640 0.635 0.002 0.251 ^SN50 0.795 0.795 0.790 0.002 0.312 ^SN58 0.615 0.615 0.620 0.002 0.243 ^SN68 0.630 0.630 0.625 0.002 0.247 ^SN69 0.950 0.950 0.955 0.002 0.375 ^SN70 1.560 1.560 1.560 0.000 0.614 ^SN71 1.560 1.560 1.560 0.000 0.614 ^SN72 0.955 0.955 0.955 0.000 0.376 ^SN73 1.280 1.285 1.280 0.002 0.505 ^SN74 1.245 1.245 1.245 0.000 0.490 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".


### QA/QC Review by: Date: 18-Jan-06

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 2/9/2006 

### Calibration Personnel: RAB 

### Test Designation: Polk 1 SAM Compliance



### Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN06 0.500 0.500 0.500 0.000 0.197

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN06 was 0.197

Difference (Pre-test/Post-test) is: 0.000

QA/QC Review by: 2/10/06

### Environmental Services A ir Services Group Pyrometer Calibration Red Team Pyrometer Under Tes t Pyrometer Number: ^PY10 Labworks Sample # N/ A Calibration Date: 1/4/2006

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 10/6/2005 Calibration Personnel (Typed and Signature): Jorge A Varino

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 400 0 2 

### 212 211 1 3 

### 32 32 0

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: Date: 

### 18-Jan-06

### Environmental Services Air Services Group

_ _

s 

### PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT10 Calibration Date 10/17/2005 

### Operating Quarter/Year: 4 Shared Resource Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: AA79435

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.8 degrees 

### Pass Dt 0.48 < Dt > 0.95 cm

α 2 1.2 degrees 

### Pass α < 10 degrees β 1 0.1 degrees 

### Pass ( α 1 measured across top impact openings) β 2 0.2 degrees 

### Pass ( α 2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α
, Ζ , and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.1 degrees Ζ < 0.32 cm ( Α sin ψ ) Α 2.43 cm W < 0.08 cm (Asin ο ) Ζ 0.004 cm 

### Pass Α distance between tips

ο angle of plane on side of pitots

ο 1.3 degrees ψ angle between tips W 0.055 cm 

### Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.



### Comments: REMOVABLE

Calibrated by: Juan Ramirez

Q uality Assurance Review / Approval: 17-Oct-05

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR02 Calibration Date: 01/03/2006 Calibration Personnel: R.A. Barthelette Jr. Labworks #: Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 10:35 30.00 30.02 -0.02 12:10 29.98 30.02 -0.04

Avera g e Difference: -0.03

Note: Barometric readin g s must a g ree within + 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: Date: 18-Jan-06

## APPENDIX B

TURBINE DATA

### PI Ops Data

Plant Information Source: polk-1pisrv Start Time: 2/7/2006 9:12

End Time: 2/7/2006 13:49 Time Interval: 1 Min

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O Run Average: 191.518322 7306.57258 73.4711102 6.28289354 07-Feb-06 09:12:00 192.1288147 7252.82861 64.2213974 6.50704861 07-Feb-06 09:13:00 192.0754547 7251.17871 64.7196884 6.50666714 07-Feb-06 09:14:00 191.7931824 7249.52832 64.9516296 6.50628567 07-Feb-06 09:15:00 191.3609161 7277.23877 65.1835709 6.5059042 07-Feb-06 09:16:00 191.6625671 7322.8335 65.4155121 6.50552273 07-Feb-06 09:17:00 192.0321808 7292.20752 65.20224 6.50514126 07-Feb-06 09:18:00 192.1638336 7258.32861 65.0494995 6.50475979 07-Feb-06 09:19:00 191.526474 7263.60889 65.0697174 6.50437784 07-Feb-06 09:20:00 191.8067017 7273.20752 65.5274124 6.50399637 07-Feb-06 09:21:00 191.6235809 7267.4043 65.8332596 6.5036149 07-Feb-06 09:22:00 191.8021851 7264.8208 65.683548 6.50323343 07-Feb-06 09:23:00 191.8202057 7263.25098 65.6654358 6.50285196 07-Feb-06 09:24:00 191.7798309 7267.70166 66.1231384 6.50247049 07-Feb-06 09:25:00 192.409317 7261.15625 66.2096939 6.50208902 07-Feb-06 09:26:00 192.202179 7261.25586 66.3649597 6.50170755 07-Feb-06 09:27:00 191.5558319 7264.84961 66.8280182 6.50132608 07-Feb-06 09:28:00 192.04216 7259.37988 66.9820099 6.50094461 07-Feb-06 09:29:00 191.9876862 7253.91016 67.1104431 6.50056314 07-Feb-06 09:30:00 191.178421 7257.10059 66.9577026 6.50018167 07-Feb-06 09:31:00 191.2994537 7255.1416 66.7947769 6.49980021 07-Feb-06 09:32:00 191.8082733 7265.95898 66.3365479 6.49941874 07-Feb-06 09:33:00 192.0485687 7287.66943 65.8783264 6.49903727 07-Feb-06 09:34:00 191.6096954 7307.08496 66.7943954 6.4986558 07-Feb-06 09:35:00 191.1708374 7322.44873 67.0119553 6.49827433 07-Feb-06 09:36:00 191.0958099 7366.84131 67.2172775 6.49789286 07-Feb-06 09:37:00 192.1004333 7356.95361 67.4226074 6.49751139 07-Feb-06 09:38:00 192.5331268 7318.75781 67.2643356 6.49712992 07-Feb-06 09:39:00 191.458786 7317.12549 67.4183273 6.49674845 07-Feb-06 09:40:00 191.9042511 7320.34961 67.3008194 6.49636698 07-Feb-06 09:41:00 191.6746216 7312.83252 67.1474533 6.49598551 07-Feb-06 09:42:00 191.5156708 7297.19043 66.9940872 6.49560404 07-Feb-06 09:43:00 192.3639679 7279.85352 66.8407211 6.49522257 07-Feb-06 09:44:00 191.1596069 7279.57959 66.9322433 6.4948411 07-Feb-06 09:45:00 191.4785767 7279.30566 67.0849838 6.49445963



### Page 1 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 09:46:00 191.7975464 7279.03174 66.8921814 6.49407816 07-Feb-06 09:47:00 191.2572021 7278.72217 67.2617645 6.49369669 07-Feb-06 09:48:00 192.2488708 7278.35547 67.4362946 6.49331522 07-Feb-06 09:49:00 191.8756714 7277.98877 68.0781937 6.49293375 07-Feb-06 09:50:00 191.845871 7265.46973 67.899559 6.49255228 07-Feb-06 09:51:00 191.7506866 7253.87451 68.1305466 6.49217081 07-Feb-06 09:52:00 191.5950623 7257.79102 68.3615341 6.49178934 07-Feb-06 09:53:00 191.7074585 7259.3252 68.5925293 6.49140787 07-Feb-06 09:54:00 191.5588837 7269.65332 69.0480881 6.4910264 07-Feb-06 09:55:00 191.4754791 7268.08252 69.086586 6.49064493 07-Feb-06 09:56:00 191.5470581 7307.62891 69.2405777 6.49026299 07-Feb-06 09:57:00 191.7560425 7302.99023 69.2354507 6.48988152 07-Feb-06 09:58:00 191.9650269 7277.59766 69.0814514 6.48950005 07-Feb-06 09:59:00 191.6876678 7285.26465 69.2948151 6.48911858 07-Feb-06 10:00:00 191.7206726 7275.18066 69.6826248 6.48873711 07-Feb-06 10:01:00 191.9111786 7272.55713 69.8037109 6.48835564 07-Feb-06 10:02:00 191.7337494 7278.2251 69.9247971 6.48797417 07-Feb-06 10:03:00 192.0595093 7277.48535 70.0458832 6.4875927 07-Feb-06 10:04:00 192.0592651 7273.79639 70.1669693 6.48721123 07-Feb-06 10:05:00 191.7153625 7265.36279 69.8368835 6.48682976 07-Feb-06 10:06:00 191.9688568 7256.9292 69.7047348 6.48644829 07-Feb-06 10:07:00 191.6097412 7252.78271 69.9345245 6.48606682 07-Feb-06 10:08:00 191.7392578 7255.5332 70.1643143 6.48568535 07-Feb-06 10:09:00 191.8681488 7252.44971 70.3941116 6.48530388 07-Feb-06 10:10:00 191.996521 7247.854 70.4729385 6.48492241 07-Feb-06 10:11:00 192.1248932 7248.75244 70.3996658 6.48454094 07-Feb-06 10:12:00 192.1385651 7245.2168 71.1160431 6.48415947 07-Feb-06 10:13:00 192.0296021 7253.10059 70.902565 6.483778 07-Feb-06 10:14:00 191.4155579 7251.1875 71.0339432 6.48339653 07-Feb-06 10:15:00 191.5024567 7265.42627 71.1653214 6.48301506 07-Feb-06 10:16:00 191.2958221 7311.85205 71.2966995 6.48263359 07-Feb-06 10:17:00 191.5341339 7304.51855 71.4280853 6.48225212 07-Feb-06 10:18:00 191.9154663 7282.88818 71.5594635 6.48187065 07-Feb-06 10:19:00 191.7777557 7281.91064 71.6908417 6.48148918 07-Feb-06 10:20:00 192.0355835 7280.93262 71.5049973 6.48110771 07-Feb-06 10:21:00 191.7624207 7276.39404 71.6076584 6.48072624 07-Feb-06 10:22:00 192.0516052 7271.88965 71.7103195 6.48034477 07-Feb-06 10:23:00 191.4102325 7276.65674 71.806221 6.4799633 07-Feb-06 10:24:00 191.4327393 7272.84912 71.5032043 6.47958183 07-Feb-06 10:25:00 192.0529938 7267.33691 71.8010025 6.47920036



### Page 2 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 10:26:00 192.1385345 7281.27051 71.6611786 6.47881889 07-Feb-06 10:27:00 191.7378082 7283.95996 71.5059204 6.47843742 07-Feb-06 10:28:00 191.4309845 7278.11768 71.523819 6.47805595 07-Feb-06 10:29:00 191.59375 7284.27783 71.1850357 6.47767448 07-Feb-06 10:30:00 191.7565155 7285.01074 71.2759399 6.47729301 07-Feb-06 10:31:00 191.919281 7281.80811 71.3595581 6.47691154 07-Feb-06 10:32:00 192.2622223 7280.21631 71.5648804 6.47653008 07-Feb-06 10:33:00 192.3158722 7291.40039 71.7702103 6.47614813 07-Feb-06 10:34:00 191.4996796 7289.72266 71.5648804 6.47576666 07-Feb-06 10:35:00 192.4039459 7297.85645 71.7394104 6.47538519 07-Feb-06 10:36:00 191.2481995 7404.49316 71.6941681 6.47500372 07-Feb-06 10:37:00 192.3108521 7348.31201 71.5414276 6.47462225 07-Feb-06 10:38:00 191.3013458 7349.7417 71.6737061 6.47424078 07-Feb-06 10:39:00 190.992157 7434.78955 71.918663 6.4740715 07-Feb-06 10:40:00 191.3721161 7500.07666 72.16362 6.47623158 07-Feb-06 10:41:00 192.4888611 7421.54688 72.408577 6.47839165 07-Feb-06 10:42:00 192.2049561 7318.70654 72.2843781 6.4805522 07-Feb-06 10:43:00 191.4058075 7304.4082 71.9464417 6.48271227 07-Feb-06 10:44:00 192.1710968 7297.07471 71.9122391 6.48487234 07-Feb-06 10:45:00 192.083725 7318.31152 72.080513 6.48703289 07-Feb-06 10:46:00 191.8710785 7309.0376 72.2487869 6.48919296 07-Feb-06 10:47:00 191.9635773 7296.75342 72.4170609 6.49135303 07-Feb-06 10:48:00 191.8784637 7327.17773 72.4033661 6.49351358 07-Feb-06 10:49:00 192.2067566 7310.27734 72.2194214 6.49567366 07-Feb-06 10:50:00 192.3373413 7326.04248 72.4983978 6.49783373 07-Feb-06 10:51:00 191.1014099 7379.39453 72.7770081 6.49999428 07-Feb-06 10:52:00 192.0639496 7402.92285 72.700325 6.50215435 07-Feb-06 10:53:00 192.5269318 7402.92529 72.623642 6.50431442 07-Feb-06 10:54:00 192.1761169 7320.42822 72.5469666 6.50647497 07-Feb-06 10:55:00 191.6178589 7332.61816 72.3612595 6.50863504 07-Feb-06 10:56:00 191.782135 7390.04053 72.2142105 6.51079559 07-Feb-06 10:57:00 191.8125458 7350.43896 72.4591675 6.51295567 07-Feb-06 10:58:00 192.0511932 7313.7793 72.7041245 6.51511574 07-Feb-06 10:59:00 191.723999 7303.59717 72.9490814 6.51727629 07-Feb-06 11:00:00 192.0197296 7295.82227 73.1246338 6.51943636 07-Feb-06 11:01:00 191.6981659 7312.7998 73.1246338 6.52159643 07-Feb-06 11:02:00 191.5386047 7310.8335 73.1246338 6.52375698 07-Feb-06 11:03:00 191.5522308 7308.86719 73.1246338 6.52579355 07-Feb-06 11:04:00 191.965744 7308.97266 73.1246338 6.5261035 07-Feb-06 11:05:00 191.6070862 7325.55322 73.1246338 6.52641392



### Page 3 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 11:06:00 191.908905 7318.21973 73.1246338 6.52672386 07-Feb-06 11:07:00 192.0616455 7311.66553 73.1246338 6.52703381 07-Feb-06 11:08:00 191.9385681 7313.68213 73.4377594 6.52734375 07-Feb-06 11:09:00 191.8154907 7315.04199 73.4377594 6.52765369 07-Feb-06 11:10:00 191.9438019 7313.03809 73.7457657 6.52796364 07-Feb-06 11:11:00 191.7696228 7353.52686 73.6690826 6.52827358 07-Feb-06 11:12:00 191.7493134 7386.33008 73.5923996 6.528584 07-Feb-06 11:13:00 192.5530243 7349.96533 73.5157166 6.52889395 07-Feb-06 11:14:00 192.4085236 7316.25781 73.4390411 6.52920389 07-Feb-06 11:15:00 192.0245972 7319.30029 73.5134735 6.52951384 07-Feb-06 11:16:00 191.179657 7381.8999 73.5904694 6.52982378 07-Feb-06 11:17:00 191.7066498 7355.49902 73.6674652 6.53013372 07-Feb-06 11:18:00 192.1019287 7330.39697 73.7444611 6.53044367 07-Feb-06 11:19:00 191.8305054 7321.19189 74.0013733 6.53075361 07-Feb-06 11:20:00 191.4325256 7326.46484 74.022934 6.53106403 07-Feb-06 11:21:00 191.9137726 7330.71533 73.801384 6.53137398 07-Feb-06 11:22:00 191.7647095 7323.71924 74.0162354 6.53168392 07-Feb-06 11:23:00 192.1398621 7316.72314 73.7508774 6.53199387 07-Feb-06 11:24:00 192.4851074 7309.72705 74.1882095 6.53230381 07-Feb-06 11:25:00 191.9763031 7303.63232 74.343483 6.53261375 07-Feb-06 11:26:00 192.2644806 7305.64893 74.2574692 6.5329237 07-Feb-06 11:27:00 191.7315063 7306.49023 74.1047287 6.53323364 07-Feb-06 11:28:00 192.0646973 7298.65088 74.0921707 6.53354406 07-Feb-06 11:29:00 191.7025757 7308.4541 74.1305923 6.53385401 07-Feb-06 11:30:00 192.1233826 7293.41602 74.1690063 6.53416395 07-Feb-06 11:31:00 191.1346741 7328.8457 74.207428 6.5344739 07-Feb-06 11:32:00 192.0785217 7380.8623 74.2458496 6.53478384 07-Feb-06 11:33:00 192.4195251 7348.30811 74.2842712 6.53509378 07-Feb-06 11:34:00 191.7227631 7323.82764 74.3226852 6.53540373 07-Feb-06 11:35:00 192.2797852 7321.32422 74.3611069 6.53571367 07-Feb-06 11:36:00 191.8362274 7357.11816 74.3995285 6.53602409 07-Feb-06 11:37:00 191.5427094 7366.62158 74.4379501 6.53633404 07-Feb-06 11:38:00 191.8920441 7337.2876 74.4763718 6.53664398 07-Feb-06 11:39:00 191.7332916 7322.31006 74.5147858 6.53695393 07-Feb-06 11:40:00 191.8720551 7322.67969 74.5532074 6.53726387 07-Feb-06 11:41:00 192.2187805 7326.34766 74.591629 6.53757381 07-Feb-06 11:42:00 192.2468262 7333.31494 74.6300507 6.53788376 07-Feb-06 11:43:00 192.1272125 7335.94531 74.6684647 6.53819418 07-Feb-06 11:44:00 191.8057556 7334.23877 74.5054474 6.53850412 07-Feb-06 11:45:00 191.6240387 7332.53223 74.4971466 6.53881407



### Page 4 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 11:46:00 192.0630493 7330.82568 74.9818649 6.53912401 07-Feb-06 11:47:00 191.6002045 7329.11914 74.9204712 6.53943396 07-Feb-06 11:48:00 191.9951782 7327.41309 74.8590775 6.5397439 07-Feb-06 11:49:00 191.5269318 7314.09521 74.7976837 6.54005384 07-Feb-06 11:50:00 191.6515045 7297.26318 74.7362823 6.54036379 07-Feb-06 11:51:00 191.1468964 7337.10303 74.7288971 6.54067421 07-Feb-06 11:52:00 191.6325989 7360.55762 74.883522 6.54098415 07-Feb-06 11:53:00 192.360321 7339.04297 75.038147 6.5412941 07-Feb-06 11:54:00 192.0806122 7317.52832 75.1927719 6.54160404 07-Feb-06 11:55:00 191.392868 7323.35547 75.0221786 6.54191399 07-Feb-06 11:56:00 191.2852783 7397.20459 75.1248398 6.54222393 07-Feb-06 11:57:00 191.5014038 7370.89941 75.2275009 6.54253387 07-Feb-06 11:58:00 191.6573944 7338.79297 75.0509338 6.54284382 07-Feb-06 11:59:00 191.3853912 7330.11621 75.4587326 6.54315424 07-Feb-06 12:00:00 191.0116577 7324.84326 75.8665314 6.54346418 07-Feb-06 12:01:00 190.8314056 7328.62598 76.239006 6.54377413 07-Feb-06 12:02:00 191.6056671 7320.26758 76.117012 6.54408407 07-Feb-06 12:03:00 191.4607849 7318.15869 75.995018 6.53987885 07-Feb-06 12:04:00 191.315918 7317.79199 75.8730164 6.5356741 07-Feb-06 12:05:00 191.7461548 7307.3418 75.7510223 6.53146887 07-Feb-06 12:06:00 191.0330505 7318.25049 75.6290283 6.52726412 07-Feb-06 12:07:00 191.7238464 7333.83447 75.7658157 6.52305889 07-Feb-06 12:08:00 191.4428711 7365.95215 75.9210815 6.51885366 07-Feb-06 12:09:00 191.7355499 7375.31787 75.7127914 6.51464891 07-Feb-06 12:10:00 192.1906433 7380.08496 75.8148956 6.50690222 07-Feb-06 12:11:00 191.0988617 7427.39844 75.9169998 6.29022074 07-Feb-06 12:12:00 191.7406464 7437.77832 76.4647293 6.07688808 07-Feb-06 12:13:00 191.9567871 7410.71777 76.3110428 6.06112003 07-Feb-06 12:14:00 192.1729126 7346.94727 76.3877258 6.04535246 07-Feb-06 12:15:00 191.5245209 7322.94287 76.4644012 6.02958441 07-Feb-06 12:16:00 191.6937714 7390.21582 76.5410843 6.01381636 07-Feb-06 12:17:00 191.8768921 7307.39551 76.6177673 5.99804878 07-Feb-06 12:18:00 190.974762 7263.29736 76.6944504 5.98228073 07-Feb-06 12:19:00 191.0355225 7279.49219 76.7711334 5.96651268 07-Feb-06 12:20:00 191.1706085 7254.96143 76.8478165 5.95074511 07-Feb-06 12:21:00 190.9497833 7255.3584 76.560257 5.93497705 07-Feb-06 12:22:00 190.1144257 7239.95801 76.9709091 5.919209 07-Feb-06 12:23:00 190.5642395 7232.979 77.1249008 5.90344143 07-Feb-06 12:24:00 190.6993256 7251.75928 77.0046844 5.88767338 07-Feb-06 12:25:00 190.8344116 7256.8501 77.0508118 5.87190533



### Page 5 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 12:26:00 190.9241333 7265.85156 77.0427704 5.85613775 07-Feb-06 12:27:00 191.0013123 7249.88477 77.0222397 5.8403697 07-Feb-06 12:28:00 191.0080719 7246.45361 77.1864929 5.82460165 07-Feb-06 12:29:00 190.9363251 7272.2002 77.4996185 5.80883408 07-Feb-06 12:30:00 190.6751556 7261.42432 77.6697922 5.79337025 07-Feb-06 12:31:00 191.0834045 7305.67676 77.3634796 5.79585981 07-Feb-06 12:32:00 190.6339569 7332.99512 77.0571594 5.79834938 07-Feb-06 12:33:00 190.7735443 7286.14844 76.9986267 5.80083942 07-Feb-06 12:34:00 190.3050385 7251.93994 77.5581665 5.80332899 07-Feb-06 12:35:00 190.8195953 7260.54102 77.710907 5.80581856 07-Feb-06 12:36:00 191.0744019 7350.4375 77.6039886 5.80830812 07-Feb-06 12:37:00 191.4274139 7341.58984 77.1355896 5.81079769 07-Feb-06 12:38:00 191.3181 7300.87598 76.9828415 5.81328773 07-Feb-06 12:39:00 190.9672394 7303.53613 76.6988525 5.8157773 07-Feb-06 12:40:00 191.5496063 7313.23926 76.3986511 5.81826687 07-Feb-06 12:41:00 191.1195679 7296.1748 75.934021 5.82075644 07-Feb-06 12:42:00 191.0581512 7290.65869 75.934021 5.82324648 07-Feb-06 12:43:00 191.0864563 7265.82471 76.1006775 5.82573605 07-Feb-06 12:44:00 191.0505066 7269.40625 76.8498917 5.82822561 07-Feb-06 12:45:00 190.6607513 7272.98779 76.6933289 5.83071518 07-Feb-06 12:46:00 191.1077881 7276.56934 76.2060776 5.83320475 07-Feb-06 12:47:00 190.9682159 7280.15088 75.9699554 5.83569479 07-Feb-06 12:48:00 191.1983032 7288.2041 76.2063599 5.83818436 07-Feb-06 12:49:00 191.8518677 7300.30469 75.7985611 5.84067392 07-Feb-06 12:50:00 191.6623077 7289.97363 75.3907623 5.84316349 07-Feb-06 12:51:00 191.0696716 7322.00684 75.3214264 5.84565306 07-Feb-06 12:52:00 190.6565552 7364.08887 75.4699249 5.8481431 07-Feb-06 12:53:00 191.576767 7323.49854 75.6184235 5.85063267 07-Feb-06 12:54:00 191.5561676 7283.83984 76.5294571 5.85312223 07-Feb-06 12:55:00 191.0885468 7293.39355 76.560257 5.8556118 07-Feb-06 12:56:00 191.5198669 7345.68896 75.9750824 5.85810137 07-Feb-06 12:57:00 192.5502777 7351.36768 75.934021 5.86059141 07-Feb-06 12:58:00 191.5783997 7314.38184 75.691597 5.86308098 07-Feb-06 12:59:00 191.8723145 7317.31543 75.8952026 5.86557055 07-Feb-06 13:00:00 190.9351196 7324.26318 76.2057343 5.86806011 07-Feb-06 13:01:00 191.9304047 7338.55371 76.1958084 5.87055016 07-Feb-06 13:02:00 191.4748688 7329.22021 76.1876221 5.87303972 07-Feb-06 13:03:00 191.0193176 7307.30078 76.4981537 5.87552929 07-Feb-06 13:04:00 191.2298889 7309.74512 77.23526 5.87801886 07-Feb-06 13:05:00 190.7212982 7312.18994 77.6972427 5.88050842



### Page 6 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 13:06:00 191.6824188 7317.82861 77.8127365 5.88299847 07-Feb-06 13:07:00 190.9794922 7327.16064 77.1612473 5.88548803 07-Feb-06 13:08:00 191.2124176 7314.14355 77.3013077 5.887918 07-Feb-06 13:09:00 191.1034546 7296.46338 77.3969574 5.88684082 07-Feb-06 13:10:00 191.149292 7281.42969 77.7049408 5.88576412 07-Feb-06 13:11:00 190.1622925 7345.82666 77.5642853 5.88468695 07-Feb-06 13:12:00 190.9564667 7373.06104 77.6663895 5.88360977 07-Feb-06 13:13:00 190.4791412 7335.5376 77.7684937 5.8825326 07-Feb-06 13:14:00 191.0767517 7298.01416 77.6963882 5.88145542 07-Feb-06 13:15:00 191.3264465 7290.86523 77.491066 5.88037825 07-Feb-06 13:16:00 190.9606476 7372.64893 77.2857437 5.87930107 07-Feb-06 13:17:00 190.8740845 7324.62451 77.3456268 5.8782239 07-Feb-06 13:18:00 190.7875061 7296.02344 77.6536102 5.8771472 07-Feb-06 13:19:00 190.8662262 7270.41699 77.4996185 5.87607002 07-Feb-06 13:20:00 190.3953857 7286.73438 77.4996185 5.87499285 07-Feb-06 13:21:00 190.8666687 7299.71484 77.1865005 5.87391567 07-Feb-06 13:22:00 190.7293396 7268.11914 77.6248627 5.8728385 07-Feb-06 13:23:00 190.8137665 7266.46924 77.5468445 5.87176132 07-Feb-06 13:24:00 190.9866333 7266.54492 77.6700363 5.87068415 07-Feb-06 13:25:00 190.9321594 7289.11475 77.7932358 5.86961651 07-Feb-06 13:26:00 190.2860565 7293.33154 77.9164276 5.86908865 07-Feb-06 13:27:00 190.3977051 7300.35254 78.0396271 5.86856127 07-Feb-06 13:28:00 190.9952698 7336.04053 77.9014587 5.86803389 07-Feb-06 13:29:00 190.6485138 7341.17383 77.8319855 5.86750603 07-Feb-06 13:30:00 191.2536774 7347.57861 77.9089813 5.86697865 07-Feb-06 13:31:00 191.0563965 7382.68945 77.9859848 5.86645126 07-Feb-06 13:32:00 191.6238861 7428.4248 78.0629807 5.8659234 07-Feb-06 13:33:00 190.9552307 7382.74316 77.9256668 5.86539602 07-Feb-06 13:34:00 191.3014984 7321.41602 78.1027603 5.86486864 07-Feb-06 13:35:00 190.6795349 7294.59375 77.9487686 5.86434078 07-Feb-06 13:36:00 191.2492676 7370.85107 77.8308487 5.8638134 07-Feb-06 13:37:00 190.8860626 7308.66699 77.9861221 5.86328602 07-Feb-06 13:38:00 190.2096558 7251.43506 78.4326172 5.86275864 07-Feb-06 13:39:00 190.6796722 7263.53564 78.3562469 5.86223078 07-Feb-06 13:40:00 190.0146484 7275.63574 78.2798767 5.8617034 07-Feb-06 13:41:00 190.5704651 7285.75635 78.2035065 5.86117601 07-Feb-06 13:42:00 190.8991699 7268.15576 78.1271362 5.86064816 07-Feb-06 13:43:00 191.129776 7251.26416 78.7416611 5.86012077 07-Feb-06 13:44:00 190.8372955 7245.23389 78.7418289 5.85959339 07-Feb-06 13:45:00 190.4442291 7250.85693 78.4389801 5.85906553



### Page 7 of 8

### PI Ops Data

Tag Name: 1pwrji900 1TSYFI100 1tmsti922m 1tsyai202 Tag Explanation: Unit Load Fuel Flow Inlet Temp Satuator Tag Units: Mwe KCFH oF % H2O 07-Feb-06 13:46:00 190.1539307 7242.58643 78.4389801 5.85853815 07-Feb-06 13:47:00 189.9719238 7260.48096 78.4389801 5.85801077 07-Feb-06 13:48:00 189.7588654 7231.14551 78.2165451 5.85748291 07-Feb-06 13:49:00 190.5630493 7230.41211 78.3192062 5.85695553



### Page 8 of 8

## APPENDIX C

FUEL ANALYSISSource:Unit 1 CALCULATION OF DENSITY AND HEATING VALUE @ 60°F and 30 in H g% volumeComponentGross*Volume% MolecularDensity*xGross Weight Heating Value Fract.Component Volume Wt.(lb/ft3)Density weight % Btu/lb Fract. Btu (Btu/SCF) BtuHydrogen35.8300 2.016 0.0053 0.00190 3.3695 61100 2058.77 325.0 116.4475Oxygen0.0000 32.000 0.0846 0.00000 0.0000 0 0.00 0.0 0Argon0.9770 39.948 0.1065 0.00104 1.8462 0 0.00 0.0 0Nitrogen2.6000 28.016 0.0744 0.00193 3.4323 0 0.00 0.0 0CO215.4900 44.010 0.1170 0.01812 32.1574 0 0.00 0.0 0CO45.0500 28.010 0.0740 0.03334 59.1521 4347 2571.34 322.0 145.061COS0.0000 60.070 0.1602 0.00000 0.0000 0 0.00 0.0 0Methane0.0563 16.041 0.0424 0.00002 0.0424 23879 10.11 1013.0 0.570319Ethane0.000 30.067 0.0803 0.00000 0.0000 22320 0.00 1792.0 0Ethylene0.000 28.051 0.0746 0.00000 0.0000 21644 0.00 1614.0 0Propane0.000 44.092 0.1196 0.00000 0.0000 21661 0.00 2590.0 0propylene0.000 42.077 0.1110 0.00000 0.0000 21041 0.00 2336.0 0Isobutane0.000 58.118 0.1582 0.00000 0.0000 21257 0.00 3363.0 0n-butane0.000 58.118 0.1582 0.00000 0.0000 21308 0.00 3370.0 0Isobutene0.000 56.102 0.1480 0.00000 0.0000 20730 0.00 3068.0 0Isopentane0.000 72.144 0.1904 0.00000 0.0000 21052 0.00 4008.0 0n-pentane72.144 0.1904 0.00000 0.0000 21091 0.00 4016.0 0n-hexane86.169 0.2274 0.00000 0.0000 20940 0.00 4762.0 0H2S34.076 0.0911 0.00000 0.0000 7100 0.00 647.0 0Total: 100.00Average Density0.05636 100.0000Gross Heating ValueSpecific Gravity0.73671Btu/lb 4640 Btu/SCF 262.08Btu/lb 4327 Btu/SCF 244*Density (lb/ft3) and Gross Heating Value (Btu/scf) data from Perry's Chemical Engineering Hanbook.Net Heating Value (Lower Heating Value), Btu/lb, calculated as Gross Heating Value (Higher Heating Value) - 10.30 (%H2x 8.94)Net Heating ValuesCoal Derived Gas and HeatingValue CalculationsCustomer:Tampa Electric CompanySample ID:Polk GCFacility:Polk Power StationAnalysis Date:2/7/2006Facility:Polk Power StationAnalysis Date:2/7/2006Source:Unit 1 CALCULATION OF F FACTORSWeight PercentsComponentMol. Wt. C Factor H Factor % volume Fract. Wt. Carbon Hydrogen Nitrogen OxygenHydrogen 2.016 01 35.830 72.23333.393508Oxygen 32.000 00 0.000 0.00000Argon 39.948 00 0.977 39.0292Nitrogen 28.016 00 2.600 72.84163.422086733CO2 44.010 0.272273 0 15.490 681.7149 8.7200484723.283525CO28.010 0.42587 0 45.050 1261.8505 25.246227334.069098COS 60.070 0.1998 0 0.000 0.0000 00Methane 16.041 0.75 0.25 0.056 0.9031 0.03182091 0.010607Ethane 30.067 0.8 0.2 0.000 0.0000 00Ethylene 28.051 0.85714 0.14286 0.000 0.0000 00Propane 44.092 0.81818 0.181818 0.000 0.0000 00Propene 42.077 0.85714 0.14286 0.000 0.0000 00Isobutane 58.118 0.82759 0.17247 0.000 0.0000 00n-butane 58.118 0.82759 0.17247 0.000 0.0000 00Isobutene 56.102 0.85714 0.14286 0.000 0.0000 00Isopentane 72.144 0.83333 0.16667 0.000 0.0000 00n-pentane 72.144 0.83333 0.16667 0.000 0.0000 00n-hexane 86.169 0.83721 0.16279 0.000 0.0000 00H2S34.076 0 0.0586923 0.000 0.0000 00Totals100.00330 2128.5726 33.9980967 3.40 3.422086733 57.352623 CALCULATED VALUESO2 F Factor (dry), Fd8298DSCF of Exhaust/MM Btu of Fuel Burned @ 0% excess airO2 F Factor (wet), Fw9714SCF of Exhaust/MM Btu of Fuel Burned @ 0% excess airMoisture F Factor1416SCF of Water/MM Btu of Fuel Burned @ 0% excess airCombust. Moisture14.58volume % water in flue gas @ 0% excess airCO2 F Factor, Fc2352DSCF of CO2/MM Btu of Fuel Burned @ 0% excess airCarbon Dioxide28.34volume % CO2 in flue gas @ 0% O2Predicted Fo Factor0.74EPA Method 3a Fo valueCoal Derived Gas and HeatingValue CalculationsCustomer:Tampa Electric CompanySample ID:Polk GC

## APPENDIX D

CEMS DATA

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 1 2/7/2006 91200 42.09 17.1 8.8 10.5 2 2/7/2006 91300 41.26 17.2 8.8 10.5 3 2/7/2006 91400 41.91 17.2 8.8 10.5 4 2/7/2006 91500 42.39 17.2 8.8 10.5 5 2/7/2006 91600 43.11 17.2 8.8 10.5 6 2/7/2006 91700 44.21 17.3 8.8 10.5 7 2/7/2006 91800 44.63 17.4 8.8 10.5 8 2/7/2006 91900 45.45 17.4 8.8 10.5 9 2/7/2006 92000 45.78 17.4 8.8 10.5 10 2/7/2006 92100 45.92 17.2 8.8 10.5 11 2/7/2006 92200 43.6 16.3 8.7 10.5 12 2/7/2006 92300 41.16 17.2 8.8 10.5 13 2/7/2006 92400 41.69 17.5 8.8 10.5 14 2/7/2006 92500 41.64 17.6 8.8 10.5 15 2/7/2006 92600 41.6 17.6 8.8 10.5 16 2/7/2006 92700 42.34 17.5 8.8 10.5 17 2/7/2006 92800 42.65 17.4 8.8 10.5 18 2/7/2006 92900 43.42 17.6 8.8 10.5 19 2/7/2006 93000 44.4 17.8 8.8 10.5 20 2/7/2006 93100 45.02 17.6 8.8 10.4 21 2/7/2006 93200 44.37 17.4 8.8 10.4 22 2/7/2006 93300 43.52 17.1 8.8 10.4 23 2/7/2006 93400 42.84 17 8.8 10.4 24 2/7/2006 93500 42.63 17 8.8 10.4 25 2/7/2006 93600 43.39 17.1 8.8 10.4 26 2/7/2006 93700 44.45 17.1 8.8 10.4 27 2/7/2006 93800 45.37 17.1 8.8 10.4 28 2/7/2006 93900 45.35 17 8.8 10.4 29 2/7/2006 94000 45.61 17 8.8 10.4 30 2/7/2006 94100 46.6 16.7 8.8 10.4 31 2/7/2006 94200 46.18 15.9 8.7 10.4 32 2/7/2006 94300 44.93 16.6 8.8 10.4 33 2/7/2006 94400 46.19 16.9 8.8 10.4 34 2/7/2006 94500 46.78 17 8.8 10.4 35 2/7/2006 94600 46.46 17.1 8.8 10.4 36 2/7/2006 94700 46.35 17.3 8.8 10.4 37 2/7/2006 94800 47.62 17.5 8.8 10.4 38 2/7/2006 94900 48.22 17.5 8.8 10.4 39 2/7/2006 95000 47.24 17.5 8.8 10.5 40 2/7/2006 95100 46.29 17.6 8.8 10.4 41 2/7/2006 95200 46.31 17.7 8.8 10.4 42 2/7/2006 95300 45.69 17.8 8.8 10.5

Page 1 of 7

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 43 2/7/2006 95400 44.74 17.6 8.8 10.5 44 2/7/2006 95500 44.35 17.5 8.8 10.5 45 2/7/2006 95600 44.27 17.6 8.8 10.5 46 2/7/2006 95700 45.22 17.6 8.8 10.5 47 2/7/2006 95800 46.29 17.7 8.8 10.5 48 2/7/2006 95900 46.69 17.9 8.8 10.5 49 2/7/2006 100000 46.94 18 8.7 10.5 50 2/7/2006 100100 47.52 17.8 8.7 10.4 51 2/7/2006 100200 47 17.2 8.7 10.5 52 2/7/2006 100300 44.91 18 8.7 10.5 53 2/7/2006 100400 44.31 18.1 8.7 10.5 54 2/7/2006 100500 43.63 18 8.7 10.5 55 2/7/2006 100600 42.94 17.9 8.7 10.5 56 2/7/2006 100700 43.96 17.8 8.7 10.5 57 2/7/2006 100800 45.48 17.8 8.7 10.5 58 2/7/2006 100900 47.36 17.9 8.7 10.5 59 2/7/2006 101000 47.98 18 8.7 10.5 60 2/7/2006 101100 48.12 18.1 8.7 10.5 61 2/7/2006 101200 47.64 18.2 8.7 10.5 62 2/7/2006 101300 47.05 18.3 8.7 10.5 63 2/7/2006 101400 44.9 18.4 8.7 10.5 64 2/7/2006 101500 42.96 18.3 8.7 10.5 65 2/7/2006 101600 42.64 18.3 8.7 10.5 66 2/7/2006 101700 42.37 18.3 8.7 10.5 67 2/7/2006 101800 43.35 18.3 8.7 10.5 68 2/7/2006 101900 44.77 18.4 8.7 10.5 69 2/7/2006 102000 45.14 18.4 8.7 10.5 70 2/7/2006 102100 46.73 18.3 8.7 10.5 71 2/7/2006 102200 47.69 17.1 8.7 10.5 72 2/7/2006 102300 46.51 17.8 8.8 10.5 73 2/7/2006 102400 46.49 18 8.8 10.5 74 2/7/2006 102500 46.28 18.2 8.7 10.5 75 2/7/2006 102600 46.03 18.3 8.8 10.5 76 2/7/2006 102700 44.27 18.3 8.8 10.5 77 2/7/2006 102800 43.39 18.5 8.7 10.5 78 2/7/2006 102900 43.93 18.6 8.7 10.5 79 2/7/2006 103000 45.33 18.5 8.7 10.5 80 2/7/2006 103100 45.33 18.5 8.7 10.5 81 2/7/2006 103200 45.51 18.3 8.8 10.5 82 2/7/2006 103300 44.41 18.2 8.8 10.5 83 2/7/2006 103400 43.87 18.2 8.7 10.5 84 2/7/2006 103500 43.57 18.2 8.7 10.5

Page 2 of 7

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 85 2/7/2006 103600 43.5 18.1 8.8 10.5 86 2/7/2006 103700 43.41 18 8.8 10.5 87 2/7/2006 103800 44.43 18 8.8 10.5 88 2/7/2006 103900 45.67 18.1 8.7 10.5 89 2/7/2006 104000 45.92 18.1 8.7 10.5 90 2/7/2006 104100 46.83 18 8.8 10.5 91 2/7/2006 104200 46.27 17.2 8.8 10.5 92 2/7/2006 104300 45.69 18 8.8 10.5 93 2/7/2006 104400 46.14 17.4 8.7 10.5 94 2/7/2006 104500 45.23 16.4 8.7 10.4 95 2/7/2006 104600 42.63 15.9 8.7 10.4 96 2/7/2006 104700 41.21 17.1 8.8 10.5 97 2/7/2006 104800 42.22 18.2 8.8 10.5 98 2/7/2006 104900 44.1 18.2 8.8 10.4 99 2/7/2006 105000 44.08 17.8 8.8 10.4 100 2/7/2006 105100 44.6 17.5 8.8 10.4 101 2/7/2006 105200 45.39 17.3 8.8 10.4 102 2/7/2006 105300 45.73 17.3 8.8 10.4 103 2/7/2006 105400 45.86 17.2 8.8 10.4 104 2/7/2006 105500 45.21 17.4 8.8 10.4 105 2/7/2006 105600 45.07 17.3 8.8 10.4 106 2/7/2006 105700 45.28 16.6 8.7 10.4 107 2/7/2006 105800 43.83 16.7 8.8 10.4 108 2/7/2006 105900 44.25 17.3 8.8 10.4 109 2/7/2006 110000 46.21 17.4 8.8 10.4 110 2/7/2006 110100 47.7 17.1 8.8 10.4 111 2/7/2006 110200 46.43 16.4 8.7 10.4 112 2/7/2006 110300 45.23 17.1 8.8 10.4 113 2/7/2006 110400 45.84 17.5 8.8 10.4 114 2/7/2006 110500 45.99 17.5 8.8 10.4 115 2/7/2006 110600 46.52 17.6 8.8 10.4 116 2/7/2006 110700 45.55 17.6 8.8 10.4 117 2/7/2006 110800 44.28 17.7 8.8 10.4 118 2/7/2006 110900 43.51 17.6 8.8 10.5 119 2/7/2006 111000 43.97 17.7 8.8 10.5 120 2/7/2006 111100 44.29 17.8 8.8 10.4 121 2/7/2006 111200 45.04 17.7 8.8 10.4 122 2/7/2006 111300 45.35 17.6 8.8 10.4 123 2/7/2006 111400 44.87 17.6 8.8 10.4 124 2/7/2006 111500 44.92 17.6 8.8 10.4 125 2/7/2006 111600 44.77 17.6 8.8 10.4 126 2/7/2006 111700 45.09 16.9 8.8 10.4

Page 3 of 7

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 127 2/7/2006 111800 43.85 17 8.8 10.4 128 2/7/2006 111900 43.63 17.7 8.8 10.5 129 2/7/2006 112000 44.57 17.8 8.8 10.5 130 2/7/2006 112100 45.45 17.9 8.8 10.4 131 2/7/2006 112200 45.37 16.9 8.8 10.4 132 2/7/2006 112300 45.06 17.4 8.8 10.5 133 2/7/2006 112400 45.08 17.5 8.8 10.4 134 2/7/2006 112500 45.01 17.4 8.8 10.5 135 2/7/2006 112600 44 17.5 8.8 10.4 136 2/7/2006 112700 43.42 17.6 8.8 10.5 137 2/7/2006 112800 43.48 17.8 8.8 10.5 138 2/7/2006 112900 44.72 17.9 8.8 10.5 139 2/7/2006 113000 45.78 18.1 8.8 10.5 140 2/7/2006 113100 46.81 18.1 8.8 10.5 141 2/7/2006 113200 47.94 17.9 8.8 10.5 142 2/7/2006 113300 48.32 18 8.8 10.5 143 2/7/2006 113400 48.03 17.9 8.8 10.5 144 2/7/2006 113500 46.89 17.8 8.8 10.5 145 2/7/2006 113600 44.93 17.8 8.8 10.4 146 2/7/2006 113700 44.25 17.1 8.8 10.4 147 2/7/2006 113800 41.86 17 8.8 10.4 148 2/7/2006 113900 40.98 17.7 8.8 10.5 149 2/7/2006 114000 42.68 17.8 8.8 10.5 150 2/7/2006 114100 44.14 17.9 8.8 10.4 151 2/7/2006 114200 45.92 17 8.8 10.5 152 2/7/2006 114300 45.7 17.6 8.8 10.5 153 2/7/2006 114400 44.91 17.9 8.8 10.5 154 2/7/2006 114500 44.36 17.8 8.8 10.5 155 2/7/2006 114600 43.88 17.8 8.8 10.5 156 2/7/2006 114700 43.54 17.7 8.8 10.5 157 2/7/2006 114800 42.86 17.7 8.8 10.5 158 2/7/2006 114900 41.22 17.7 8.8 10.5 159 2/7/2006 115000 41.1 17.8 8.8 10.4 160 2/7/2006 115100 42.43 17.7 8.8 10.4 161 2/7/2006 115200 43.09 17.7 8.8 10.5 162 2/7/2006 115300 44.28 17.8 8.8 10.5 163 2/7/2006 115400 45.03 18 8.8 10.5 164 2/7/2006 115500 45.17 18 8.8 10.5 165 2/7/2006 115600 44.98 18 8.8 10.5 166 2/7/2006 115700 45.15 17.3 8.8 10.4 167 2/7/2006 115800 43.07 17.2 8.8 10.5 168 2/7/2006 115900 41.27 17.7 8.8 10.5

Page 4 of 7

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 169 2/7/2006 120000 41.33 17.9 8.8 10.5 170 2/7/2006 120100 43.42 17.9 8.8 10.4 171 2/7/2006 120200 43.48 17 8.8 10.5 172 2/7/2006 120300 42.28 17.7 8.8 10.5 173 2/7/2006 120400 43.19 17.9 8.8 10.5 174 2/7/2006 120500 43.47 18 8.8 10.5 175 2/7/2006 120600 43.01 18 8.8 10.5 176 2/7/2006 120700 43.78 17.8 8.8 10.5 177 2/7/2006 120800 42.85 17.7 8.8 10.4 178 2/7/2006 120900 42.95 17.5 8.8 10.4 179 2/7/2006 121000 44.34 17.3 8.8 10.4 180 2/7/2006 121100 45.29 17.3 8.8 10.4 181 2/7/2006 121200 46.22 17.2 8.7 10.4 182 2/7/2006 121300 46.22 17.2 8.8 10.4 183 2/7/2006 121400 45.62 17.2 8.8 10.4 184 2/7/2006 121500 44.67 17.1 8.8 10.4 185 2/7/2006 121600 44.22 16.9 8.8 10.4 186 2/7/2006 121700 44.86 16.6 8.8 10.4 187 2/7/2006 121800 44.04 16.9 8.8 10.4 188 2/7/2006 121900 45.16 17.5 8.8 10.4 189 2/7/2006 122000 47.08 17.7 8.8 10.4 190 2/7/2006 122100 49.18 17.7 8.8 10.4 191 2/7/2006 122200 48.88 17.2 8.8 10.4 192 2/7/2006 122300 47.67 17.7 8.8 10.5 193 2/7/2006 122400 49.29 17.9 8.7 10.5 194 2/7/2006 122500 49.94 18.2 8.8 10.5 195 2/7/2006 122600 40.08 12.3 3.8 10.5 196 2/7/2006 122700 3.99 0.4 0.1 10.5 197 2/7/2006 122800 16.92 10.9 6.3 10.5 198 2/7/2006 122900 43.15 18.3 8.6 10.5 199 2/7/2006 123000 44.83 18.4 8.7 10.5 200 2/7/2006 123100 44.64 18.4 8.7 10.5 201 2/7/2006 123200 44.51 18.4 8.7 10.5 202 2/7/2006 123300 44.22 18.4 8.7 10.5 203 2/7/2006 123400 44.39 18.4 8.7 10.5 204 2/7/2006 123500 43.66 18.4 8.7 10.5 205 2/7/2006 123600 44.24 18.5 8.7 10.5 206 2/7/2006 123700 44.39 18.1 8.7 10.5 207 2/7/2006 123800 42.95 18.1 8.8 10.5 208 2/7/2006 123900 41.77 18.7 8.8 10.5 209 2/7/2006 124000 42.5 18.8 8.8 10.5 210 2/7/2006 124100 44.3 18.6 8.8 10.5

Page 5 of 7

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 211 2/7/2006 124200 44.7 17.7 8.8 10.5 212 2/7/2006 124300 43.92 18.2 8.8 10.5 213 2/7/2006 124400 44.8 18.4 8.8 10.5 214 2/7/2006 124500 45.58 18.5 8.8 10.5 215 2/7/2006 124600 45.97 18.8 8.8 10.5 216 2/7/2006 124700 45.88 18.5 8.8 10.5 217 2/7/2006 124800 43.8 18.6 8.8 10.5 218 2/7/2006 124900 43.88 18.7 8.8 10.5 219 2/7/2006 125000 45.51 18.7 8.8 10.5 220 2/7/2006 125100 46.37 18.7 8.8 10.5 221 2/7/2006 125200 45.69 18.6 8.8 10.5 222 2/7/2006 125300 45.6 18.6 8.8 10.5 223 2/7/2006 125400 46.12 18.6 8.8 10.5 224 2/7/2006 125500 47.71 18.6 8.7 10.5 225 2/7/2006 125600 49.45 18.5 8.7 10.5 226 2/7/2006 125700 49.88 18.1 8.8 10.5 227 2/7/2006 125800 48.62 17.8 8.8 10.5 228 2/7/2006 125900 47.1 18.3 8.8 10.5 229 2/7/2006 130000 47.06 18.5 8.8 10.5 230 2/7/2006 130100 47.92 18.5 8.8 10.5 231 2/7/2006 130200 48.29 17.7 8.8 10.5 232 2/7/2006 130300 47 18.1 8.8 10.5 233 2/7/2006 130400 46.87 18.5 8.8 10.5 234 2/7/2006 130500 45.02 18.5 8.8 10.5 235 2/7/2006 130600 42.29 18.3 8.8 10.5 236 2/7/2006 130700 39.62 18.2 8.8 10.5 237 2/7/2006 130800 36.15 18.2 8.8 10.5 238 2/7/2006 130900 34.34 18.1 8.8 10.5 239 2/7/2006 131000 32.94 18.1 8.8 10.5 240 2/7/2006 131100 32.03 17.8 8.8 10.4 241 2/7/2006 131200 30.57 17.8 8.8 10.5 242 2/7/2006 131300 30.35 18 8.8 10.5 243 2/7/2006 131400 31.17 18.1 8.8 10.5 244 2/7/2006 131500 33.94 18.2 8.7 10.5 245 2/7/2006 131600 36.17 18.2 8.8 10.5 246 2/7/2006 131700 35.49 17.8 8.8 10.4 247 2/7/2006 131800 31.64 17.4 8.8 10.5 248 2/7/2006 131900 29.96 17.9 8.8 10.5 249 2/7/2006 132000 30.51 18.1 8.8 10.5 250 2/7/2006 132100 32.84 18.2 8.8 10.4 251 2/7/2006 132200 35.24 17.5 8.7 10.4 252 2/7/2006 132300 35.16 17.8 8.8 10.5

Page 6 of 7

### CEMS Data

Record# DATE TIME SO211 NOX12 CO213 OXY14 253 2/7/2006 132400 34.28 18.1 8.8 10.5 254 2/7/2006 132500 34.91 18.2 8.8 10.5 255 2/7/2006 132600 35.54 18.1 8.8 10.4 256 2/7/2006 132700 34.84 17.9 8.8 10.4 257 2/7/2006 132800 35.55 17.8 8.7 10.4 258 2/7/2006 132900 37.36 17.7 8.7 10.4 259 2/7/2006 133000 38.28 17.6 8.7 10.4 260 2/7/2006 133100 38.33 17.6 8.7 10.4 261 2/7/2006 133200 37.74 17.5 8.7 10.4 262 2/7/2006 133300 38.17 17.5 8.7 10.4 263 2/7/2006 133400 39.48 17.3 8.7 10.4 264 2/7/2006 133500 40.08 17.2 8.7 10.4 265 2/7/2006 133600 42.56 17.1 8.7 10.4 266 2/7/2006 133700 44.32 16.8 8.7 10.4 267 2/7/2006 133800 43.42 16.7 8.8 10.4 268 2/7/2006 133900 41.85 17.3 8.8 10.4 269 2/7/2006 134000 43.31 17.5 8.8 10.4 270 2/7/2006 134100 43.49 17.6 8.8 10.4 271 2/7/2006 134200 42.63 17.3 8.8 10.4 272 2/7/2006 134300 42.07 17.6 8.7 10.4 273 2/7/2006 134400 42.01 17.8 8.7 10.4 274 2/7/2006 134500 42.39 17.9 8.7 10.4 275 2/7/2006 134600 42.13 17.9 8.7 10.4 276 2/7/2006 134700 41.01 17.8 8.7 10.4 277 2/7/2006 134800 40.55 17.9 8.7 10.4 278 2/7/2006 134900 40.41 17.9 8.7 10.4 279 / / 280 / / A VE 43.467 17.619 8.716 10.462

Page 7 of 7

## APPENDIX F

TEST PARTICIPANTS

## TEST PARTICIPANTS

AIR SERVICES GROUP ENVIRONMENTAL SERVICES

Robert Barthelette Environmental Technician Charles Dufeny Environmental Technician Juan Ramirez Environmental Technician Jorge Varino Technician

POLK POWER STATION

Michael Perkins Environmental Coordinator