Product Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Print Date: 10 Sep 2012

®(TM)*Trademark

Page 1 of 9 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS,

as there is important information throughout the document. We expect you to follow the precautions

identified in this document unless your use conditions would necessitate other appropri ate methods or

actions.



## 1. Product and Company Identification

Product Name

SPECFLEX* NF 857 Polyol DA

COMPANY IDENTIFICATI ON

The Dow Chemical Company

2030 Willard H. Dow Center

Midland

, MI 48674

United States

Customer Information Number: 800

- 258

- 2436



### EMERGENCY TELEPHONE NUMBER

24

- Hour Emergency Contact: 989

- 636

- 4400

Local Emergency Contact: 989

- 636

- 4400



## 2. Hazards Identification

Emergency Overview

Color: White

Physical State: Liquid.

Odor: Characteristic

Hazards of product:

CAUTION! May cause eye irritation. Isolate area. Possible cancer hazard. May

cause cancer based on animal data.



### OSHA Hazard Communication Standard

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29

CFR 1910.1200.



### Potential Health Effects

Eye Contact: May cause slight temporary eye irritation. May cause slight temporary corneal injury.

Skin Contact: Prolonged exposure not likely to cause significant skin irritation.

Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts.

Inhalation: At room temperature, exposure to vapor is minimal due to low volatility; single exposure is

not likely to be hazardous. Vapor from heated material may cause respiratory irritation. 

# Material Safety Data Sheet

The Dow Chemical CompanyProduct Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 2 of 9 Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal

handling operations are not likely to cause injury; however, swallowing larger amoun ts may cause

injury.

Aspiration hazard: Based on physical properties, not likely to be an aspiration hazard.

Cancer Information: Findings from a chronic diethanolamine skin painting study by NTP include liver

a nd kidney tumors in mice; no tumors were observed in rats. Mechanistic studies indicate that tumor

formation is of questionable relevance to humans.



### Component CAS # Amount

Polyether Polyol Blend Trade secret > 90.0 %

Water 7732

- 18

- 5 >= 1.0

- <= 5.0 %

N,N

- Diethanolamine 111

- 42

- 2 >= 0.5

- <= 1.5 %



## 4. First

- aid measures

Description of first aid measures

General advice: If potential for exposure exists refer to Section 8 for specific personal protective

equipment.

Inhalation: Move person to fresh air; if effects occur, consult a physician.

Skin Contact: Wash skin wi th plenty of water.

Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the

initial 1

- 2 minutes and continue flushing for several additional minutes. If effects occur, consult a

physician, preferabl y an ophthalmologist. Suitable emergency eye wash facility should be available in

work area.

Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by

medical personnel.



### Most important symptoms and effects, both acute and delayed

Aside from the information found under Description of first aid measures (above) and Indication of

immediate medical attention and special treatment needed (below), no additional symptoms and

eff ects are anticipated.



### Indication of immediate medical attention and special treatment needed

No specific antidote. Treatment of exposure should be directed at the control of symptoms and the

clinical condition of the patient.



## 5. Fire Fighting Measures

Suitable extinguishing media

Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam.

Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF)

or protein foams may function, but will be less effective.

Extinguis hing Media to Avoid: Do not use direct water stream. May spread fire.



### Special hazards arising from the substance or mixture

Hazardous Combust ion Products: During a fire, smoke may contain the original material in addition

to combustion products of varying composition which may be toxic and/or irritating. Combustion

products may include and are not limited to: Nit rogen oxides. Carbon monoxide. Carbon dioxide. 

## 3. Composition InformationProduct Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 3 of 9 Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation.

Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.



### Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water

spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has

passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose

holders or monitor nozzles. I mmediately withdraw all personnel from the area in case of rising sound

from venting safety device or discoloration of the container. Do not use direct water stream. May

spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be

moved by flushing with water to protect personnel and minimize property damage. Contain fire water

run

- off if possible. Fire water run

- off, if not contained, may cause environmental damage. Review the

"Ac cidental Release Measures" and the "Ecological Information" sections of this (M)SDS.

Special Protective Equipment for Firefighters: Wear positive

- pressure self

- contained breathing

apparatus (SCBA) and p rotective fire fighting clothing (includes fire fighting helmet, coat, trousers,

boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,

change to full chemical resistant fire fighting clothing wit h self

- contained breathing apparatus. If this is

not available, wear full chemical resistant clothing with self

- contained breathing apparatus and fight fire

from a remote location. For protective equipment in post

- fire or non

- fire clean

- up situatio ns, refer to

the relevant sections.



## 6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Isolate area. Refer to

Section 7, Handling, for additional precautionary measures. Keep unnecessary and unprotected

personnel from entering the area. Spilled material may cause a slipping hazard. Use appropriate

safety equipment. For additio nal information, refer to Section 8, Exposure Controls and Personal

Protection.

Environmental precautions : Prevent from entering into soil, ditches, sewers, waterways and/or

groundwater. See Section 12, Ecological Information.

Methods and materials for containment and cleaning up : Contain spilled material if possible.

Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled

containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional

information.



## 7. Handlin g and Storage

Handling

General Handling: Avoid contact with eyes. Wash thoroughly after handling. Use with adequate

ventilation. Keep container closed. This material is hygroscopic in nature. See Section 8,

EXPOSURE CONTROLS AND PERSONAL PROTECTION.

Other Precautions: Spills of these organic materials on hot fibrous insulations may lead to lowering of

the autoignition temperatures possibly resulting in spontaneous combustion.



### Storage

Protect from atmospheric moisture. Store in a dry place. Avoid prolonged exposure to heat and air.

Store in the following material(s): Carbon steel. Stainless steel. Polypropylene. Polyethylene

- lined

container. Teflon. Glass

- lined container. Aluminum. Plasite 3066 lined container. Plasite 3070 lined

co ntainer. 316 stainless steel. See Section 10 for more specific information.

Storage Period: Storage temperature:

6 Months 15

- 25 °CProduct Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 4 of 9 

## 8. Exposure Controls / Personal Protection

Exposure Limits

Component List Type Value

| N,N

- Diethanolamine ACGIH TWA

Inhalable

fraction and

vapor. 1 mg/m3 SKIN

A "skin" notation following the inhalation exposure guideline refers to the potential for dermal

absorption of the material including mucous membranes and the eyes either by conta ct with vapors or

by direct skin contact.

It is intended to alert the reader that inhalation may not be the only route of exposure and that

measures to minimize dermal exposures should be considered.



### Personal Protection

Eye/Face Protection: Use safety glasses (with side shields).

Skin Protection: No precautions other than clean body

- covering clothing should be needed.

Hand protection: Chemi cal protective gloves should not be needed when handling this

material. Consistent with general hygienic practice for any material, skin contact should be

minimized.

Respiratory Protection: Respiratory protection should be wor n when there is a potential to exceed

the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements

or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or

discomfort have been experienced, or where indicated by your risk assessment process. For most

conditions, no respiratory protection should be needed; however, if handling at elevated temperatures

without sufficient ventilation, use an approved air

- purifying respir ator. The following should be

effective types of air

- purifying respirators: Organic vapor cartridge.

Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands

before smoking or eating.



### Engineering Controls

Ventilation: Use local exhaust ventilation, or othe r engineering controls to maintain airborne levels

below exposure limit requirements or guidelines. If there are no applicable exposure limit

requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust

ve ntilation may be necessary for some operations.



## 9. Physical and Chemical Properties

Appearance

Physical State Liquid.

Color White

Odor Characteristic

Odor Threshold No test data available

pH No test data available

Melting Point No test data available

Freezing Point No test data available

Boiling Point (760 mmHg) No test data available

. Flash Point

- Closed Cup > 100 °C ( > 212 °F ) Estimated.

Evaporation Rate (Butyl

Acetate = 1) No test data available

Flammability (solid, gas) Not applicable to liquids

Flammable Limits In Air Lower : No test data available

Upper : No test data available

Vapor Pressure No test data available

Vapor Density (air = 1) No test data available

Specific Gravity (H2O = 1) 1.02

- 1.06 20 °C / 20 °C ASTM D891Product Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 5 of 9 Solubility in water (by

weight) Partially soluble

Partition coefficient, n

octanol/water (log Pow) No data available for this product. See S ection 12 for individual

component data.

Autoignition Temperature No test data available

Decomposition

Temperature No test data available

Kinematic Viscosity 1,400

- 2,600 mm2/s @ 25 °C ASTM D445

Explosive properties Not explosive

Oxidizing properties No



## 10. Stability and Reactivity

Reactivity

No dangerous reaction known under conditions of normal use.



### Chemical stability

Stable under recommended storage conditions. See Storage, Section 7.



### Possibility of hazardous reactions

Polymerization will not occur by itself.



### Conditions to Avoid: P roduct can oxidize at elevated temperatures. Generation of gas during

decomposition can cause pressure in closed systems.



### Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.

Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates

generates heat.



### Hazardous decomposition products

Decomposition products depend upon temperature, air supply and the presence of other materials.

Decomposition products can include and are not limited to: Carbon dioxide. Alcohols. Ethers.

Hydrocarbons. Ketones. Polymer fragments.



## 11

. Toxicological Information

Acute Toxicity

Ingestion

As product: Single dose oral LD50 has not been determined.

Estimated. LD50

, rat > 2,000 mg/kg

Dermal

As product: The dermal LD50 has not been determined.

Estimated. LD50

, rabbit > 2,000 mg/kg

Inhalation

As product: The LC50 has not been determined.



### Eye damage/eye irritation

May cause slight temporary eye irritation. May cause slight temporary corneal injury.



### Skin corrosion/irritation

Prolonged exposure not likely to cause significant skin irritation.



### Sensitization

Skin

No relevant data found.

Respiratory

No relevant data found.



### Repeated Dose Toxicity

No relevant data found.Product Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 6 of 9 

### Chronic Toxicity and Carcinogenicity

Findings from a chronic diethanolamine skin painting study by NTP include liver and kidney tumors in

mice; no tumors were observed in rats. Mechanistic studies indicat e that tumor formation is of

questionable relevance to humans.

Carcinogenicity Classifications:

Component List Classification

N,N

- Diethanolamine IARC Possibly carcinogenic to humans. ; 2B

ACGIH Confirmed animal carcinogen with

unknown relevance to humans. ; Group A3



### Developmental Toxicity

No relevant data found.



### Reproductive Toxicity

No relevant data found.



### Genetic Toxicology

No relevant data found.



## 12

. Ecological Information

Toxicity

Data for Component: N,N

- Diethanolamine

Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1

and 10 mg/L in the most sensitive species tested). May increase pH of aquatic systems to >

pH 10 which may be toxic to aquatic organisms.

Fish Acute & Prolonged Toxicity

LC50

, Pimephales promelas (fathead minnow)

, static test

, 96 h : 1,460 mg/l

Aquatic Invertebrate Acute Toxicity

EC50

, Daphnia magna (Water flea)

, static test

, 48 h : 55 mg/l

Aquatic Plant Toxicity

ErC50

, Pseudokirchneriella subcapitata (green algae)

, Growth rate inhibition

, 96 h : 2.2 mg/l

Toxicity to Micro

- organisms

EC50

, OECD 209 Test ; activated sludge

, 3 h : > 1,000 mg/l

Aquatic Invertebrates Chronic Toxicity Value

Daphnia magna (Water flea)

, semi

- static test

, 21 d

, NOEC: 0.78 mg/l

, LOEC: 1.56 mg/l

Data for Component: Copolymer dispersion in polyether polyol

For simil ar material(s): Material is practically non

- toxic to aquatic invertebrates on an acute

basis (LC50/EC50 > 100 mg/L).

Data for Component: Polyether polyol "C"

For this family of materials: Material is practically non

- toxic to aquatic organisms on an acute

basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

Data for Component: Polyeth er polyol "F"

Based on information for a similar material: Material is practically non

- toxic to aquatic

organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species

tested).



### Persistence and Degradability

Data for Component: N,N

- Diethanolamine

Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is

ultimately biodegradable (reaches > 70% biodegradation in OECD test(s) for inherent

biodegra dability).

OECD Biodegradation Tests:

Biodegradation Exposure Time Method 10 Day Window

93 % 28 d OECD 301F Test passProduct Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 7 of 9 Indirect Photodegradation with OH Radicals

Rate Constant Atmospheric Half

- life Method

8.90E

- 11 cm3/s 0.167 d Estimated.

Theoretical Oxygen Demand: 2.13 mg/mg

Data for Component: Copolymer dispersion in polyether polyol

The polymeric component is not expected to biodegrade.

Data for Component: Polyether polyol "C"

For this family of materials: Material is readily biodegradable. Passes OECD test(s) for ready

biodegradability.

Data for Component: Polyether polyol "F"

Based on information for a similar material: Material is expected to be readily biodegradable.



### Bioaccumulative potential

Data for Component: N,N

- Diethanolamine

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).

Partition coefficient, n

- octanol/water (log Pow):

- 2.18 Shake flask (OECD 107 Test)

Data for Component: Copolymer dispersion in polyether polyol

Bioaccumulation: No bioconcentration of the polymeric component is expected because of

its high molecular weight.

Data for Component: Polyether polyol "C"

Bioaccumulation: No bioconcentration is expected because of the relatively high molecular

weight (MW greater than 1000).

Data for Component: Polyether polyol "F"

Bioaccumulation: No bioconcentration is expected because of the relatively high molecular

weight (MW greater than 1000).



### Mobility in soil

Data for Component: N,N

- Diethanolamine

Mobility in soil: Given its very low Henry's constant, volatilization from natural bodies of water

or moist soil is not expected to be an important fate process., Potential for mobility in soil is

very high (Koc between 0 and 50).

Partition coefficient, soil organic carbon/water (Koc): 1 Estimated.

Henry's Law Constant (H): 5.35E

- 14 atm*m3/mole ; 25 °C Measured

Data for Component: Copolymer dispersion in polyether polyol

Mobility in soil: No data available.

Data for Component: Polyether polyol "C"

Mobility in soil: No data available.

Data for Component: Polyether polyol "F"

Mobility in soil: No data available.



## 13. Disposal Considerations

DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All

disposal practices must be in compliance with all Federal, State/Provincial and local laws and

regulations. Regulations may vary in different locations. Waste characterizations and compliance with

applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE

NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF

PARTIES HANDLING OR USING THIS MATERIAL. THE INFOR MATION PRESENTED HERE

PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS

DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED

PRODUCT, the preferred options include sending to a licensed, perm itted: Recycler. Reclaimer.

Incinerator or other thermal destruction device. For additional information, refer to: Handling &Product Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 8 of 9 Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section 10 Regulatory

Information, MSDS Section 15



## 14. Transport Information

DOT Non

- Bulk

NOT REGULATED



### DOT Bulk

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S

Technical Name: DIETHANOLAMINE

Hazard Class: 9 ID Number: UN3082 Packing Group: PG III



### IMDG

NOT REGULATED



### ICAO/IATA

NOT REGULATED

Additional Information

Reportable quantity:

– 100 lb

- DIETHANOLAMINE

- RQ

This info rmation is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Additional transportation system information can be

obtained through an authorized sales or customer service representative. It is the responsibility of the

transporting organization to follow all applicable laws, regulations and rules relating to the

transportation of the material.



## 15. Regulatory Information

OSHA Hazard Communication Standard

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29

CFR 1910.1200.



### Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning

and Community Ri ght

- to

- Know Act of 1986) Sections 311 and 312

Immediate (Acute) Health Hazard No

Delayed (Chronic) Health Hazard Yes

Fire Hazard No

Reactive Hazard No

Sudden Release of Pressure Hazard No

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and

Community Right

- to

- Know Act of 1986) Section 313

To the best of our knowledge, this product does not contain chemicals at levels which require reporting

under this statute.

Pennsylvania (Worker and Community Right

- To

- Know Act): Pennsylvania Hazardous

Substances List and/or Pennsylvania Environmental Hazardous Substance List:

To the best of our knowledge, this product does not contain chemicals at levels which require reporting

under this statute.

Pennsylvania (Worker and Community Right

- To

- Know Act): Pennsyl vania Special Hazardous

Substances List:

To the best of our knowledge, this product does not contain chemicals at levels which require reporting

under this statute.Product Name: SPECFLEX* NF 857 Polyol DA Issue Date: 09/07/2012

Page 9 of 9 California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)

WARNING: This product contains a chemical(s) known to the State of California to cause cancer.

Component CAS # Amount

N,N

- Diethanolamine 111

- 42

- 2 >= 0.5

- <= 1.5 %

US. Toxic Substances Control Act

All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory

requirements under 40 CFR 720.30

CEPA

- Domestic Substances List (DSL)

All substances contained in this product are listed on the Canad ian Domestic Substances List (DSL) or

are not required to be listed.



## 16. Other Information

Product Literature

Additional information on this product may be obtained by calling your sales or customer service

contact.



### Recommended Uses and Restrictions

Identified uses

Component(s) for the manufacture of urethane polymers. We recommend that you use this product in

a manner consistent with the listed use. If your intended use is not consistent with the stated use,

please contact your sales or technical service representative.



### Revision

Identification Number: 1012225 / 0000 / Issue Date 09/07/2012 / Version: 2

. 0

Most recent revision(s) are noted by the bold, double bars in left

- hand margin throughout this

document.



### Legend

N/A Not available

W/W Weight/Weight

OEL Occupational Exposure Limit

STEL Short Term Exposure Limit

TWA Time Weighted Average

ACGIH American Conference of Governmental Industrial Hygienists, Inc.

DOW IHG Dow Industrial Hygiene Guideline

WEEL Workplace Environmental Exposure Level

HAZ_DES Hazard Designation

Action Level A value set by OSHA that is lower than the PEL which will trigger the need for

activities such as exposure monitoring and medical surveillance if exceeded.

The Dow Chemical Compan y urges each customer or recipient of this (M)SDS to study it carefully and

consult appropriate expertise, as necessary or appropriate, to become aware o f and understand the

data contained in this (M)SDS and any hazards associated with the product. The information herein is

provided in good faith and believed to be accurate as of the effective date shown above. However, no

warranty, express or implied, i s given. Regulatory requirements are subject to change and may differ

between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with

all federal, state, provincial or local laws. The information presented here pertains only to the product

as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is

the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to

the proliferation of sources for information such as manufacturer

- specific (M)SDSs, we are not and

cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have

obtained an (M)SDS from another source or if you a re not sure that the (M)SDS you have is current,

please contact us for the most current version.