## Instructions for completing the Fuel Material Analysis Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. Th number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Data for multiple boilers should be handled by using separate spreadsheets. Fields that are highlighted in yellow are required fields. Green highlighted cells should be filled using the drop

-down boxes, included. Gray fields are automatically filled from other fields.

Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

Please refer to the following steps when using these spreadsheets.

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the test date on the Boiler Information worksheet. 3. Please choose the type of fuel being sampled using the drop

-down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865 04". 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units

measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. 6. Select the HAPs Test Group (i.e., HAP surrogate) for which the tab's data reflects (o range highlighted cell) 7. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have collected

more. 8. Provide the results of the analyses for each constituent requested. Use the drop

-down boxes to fill in the units of

measure.

## Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. Th is number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Fields that are highlighted in yellow are down boxes, included. Gray fields are automatically

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet.

down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865

- 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of

measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. range highlighted cell)

. 7. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have collected

down boxes to fill in the units of

### EIA

Facility Code Facility Name Boiler ID Fuel Type 1

2079 Hawthorn 5A 

## subbituminous

### Fuel Type 2 Fuel Type 3 Other Fuel Description



## bituminous other Natural Gas

### EIA

Facility Code Facility Name Boiler ID Basis An alyte



## 2079 Hawthorn 5A As Received Higher Heating Value 

## 2079 Hawthorn 5A As Received % Moisture 

## 2079 Hawthorn 5A As Received % Ash 

## 2079 Hawthorn 5A As Received % Sulfur 

## 2079 Hawthorn 5A Dry basis Higher Heating Value 

## 2079 Hawthorn 5A Dry basis % Ash 

## 2079 Hawthorn 5A Dry basis % Sulfur 

## 2079 Hawthorn 5A Dry basis Antim ony 

## 2079 Hawthorn 5A Dry basis Arsenic 

## 2079 Hawthorn 5A Dry basis Beryllium 

## 2079 Hawthorn 5A Dry basis Cadmium 

## 2079 Hawthorn 5A Dry basis Chlorine 

## 2079 Hawthorn 5A Dry basis Chromium 

## 2079 Hawthorn 5A Dry basis Cobalt 

## 2079 Hawthorn 5A Dry basis Fluorine 

## 2079 Hawthorn 5A Dry basis Lead 

## 2079 Hawthorn 5A Dry basis Manganese 

## 2079 Hawthorn 5A Dry basis Mercury 

## 2079 Hawthorn 5A Dry basis Nickel 

## 2079 Hawthorn 5A Dry basis Selenium

### An alysis M ethod for each Analyte

(example: ASTM D5865-04) 

## ASTM D5865 ASTM D3302 ASTM D3174 ASTM D4239B ASTM D5865 ASTM D3174 ASTM D4239B ASTM D6357 - ICP-MS ASTM D6357 - ICP-MS ASTM D6357 - ICP-MS ASTM D6357 - ICP-MS ASTM D6721 ASTM D6357 - ICP-MS ASTM D6357 - ICP-MS ASTM D5987 - IC ASTM D6357 - ICP-MS ASTM D6357 - ICP-MS ASTM D6722-01 - DCGA-AA ASTM D6357 - ICP-MS ASTM D4606 - ICP-AES-HYEIA

Facility Code Facility

Name Boiler ID 

### HAPs Test Group 

## 2079 Hawthorn 5A Non-dioxin/furan organic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units 

### R1 

## 4/21/2010 4/21/2010 9360.00 Btu/lb R2 

## 4/22/2010 4/22/2010 9216.00 Btu/lb R3 

## 4/22/2010 4/22/2010 9237.00 Btu/lb Fuel Testing Results% Moisture

(as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis) 

## 21.35 6.33 0.26 11901 Btu/lb 8.05 0.33 22.95 6.16 0.31 11961 Btu/lb 7.99 0.4 23.58 5.45 0.31 12087 Btu/lb 7.13 0.41Chlorine

(Dry Basis) Chlorine

Units (test results in ug/g) Mercury

(Dry Basis) Mercury

Units Antimony

(Dry Basis) Antimony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis) 

## 18 ppm 0.073 μg/g 0.16 μg/g 1.3 μg/g 0.2 9 ppm 0.075 μg/g 0.18 μg/g 1.4 μg/g 0.2 30 ppm 0.079 μg/g 0.14 μg/g 1.2 μg/g 0.2Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units 

## μg/g 0.12 μg/g 6 μg/g 3.1 μg/g 14 μg/g μg/g 0.11 μg/g 6 μg/g 2.7 μg/g 14 μg/g μg/g 0.08 μg/g 5 μg/g 2.2 μg/g 18 μg/gNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units(test results in ug/g) Cobalt (Dry

Basis) Cobalt Units Total Moisture 

## 5 μg/g 0.9 μg/g 77 ppm 2.3 μg/g 21.35 6 μg/g 1 μg/g 72 ppm 2.2 μg/g 22.95 5 μg/g 0.9 μg/g 66 ppm 1.8 μg/g 23.58 Proximate Analy

ses, % by

wt

### Note the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur 

## 42.8 8.05 49.15 68.54 4.57 0.69 0.33 42.96 7.99 49.05 68.38 4.66 0.87 0.4 44.41 7.13 48.46 69.13 4.73 0.91 0.41 Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wtOxygen



## 17.63 17.7 17.69EIA

Facility Code Facility

Name Boiler ID 

### HAPs Test Group 

## 2079 Hawthorn 5A Acid gas HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date

(MM/DD/YYYY) Higher Heating

Value (HHV) (as received) HHV Units 

### 1 

## 4/22/2010 4/22/2010 9301.00 Btu/lb 2 4/23/2010 4/24/2010 9086.00 Btu/lb 3 4/24/2010 4/24/2010 9225.00 Btu/lb Fuel Testing Results% Moisture

(as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis) 

## 22.27 6.22 0.34 11966 Btu/lb 8 0.44 22.98 6.77 0.37 11797 Btu/lb 8.79 0.48 22.59 8.13 0.49 11917 Btu/lb 8.13 0.49Chlorine

(Dry Basis) Chlorine

Units (test results in ug/g) Mercury

(Dry Basis) Mercury

Units Antimony

(Dry Basis) Antimony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis) 

## 14 ppm 0.079 μg/g 0.17 μg/g 1.4 μg/g 0.3 10 ppm 0.086 μg/g 0.2 μg/g 1.6 μg/g 0.3 7 ppm 0.076 μg/g 0.2 μg/g 1.7 μg/g 0.3Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units 

## μg/g 0.11 μg/g 6 μg/g 2.4 μg/g 14 μg/g μg/g 0.14 μg/g 7 μg/g 3 μg/g 14 μg/g μg/g 0.11 μg/g 6 μg/g 2.7 μg/g 16 μg/gNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units(test results in ug/g) Cobalt (Dry

Basis) Cobalt Units 

## 6 μg/g 0.9 μg/g 73 ppm 1.9 μg/g 6 μg/g 1 μg/g 77 ppm 2.2 μg/g 7 μg/g 1 μg/g 69 ppm 2.3 μg/g

### Note the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Total Moisture Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur



## 22.27 43.41 8 48.59 68.42 4.75 0.88 0.44 22.98 43.44 8.79 47.77 67.9 4.6 0.86 0.48 22.59 43.66 8.13 48.21 68.45 4.7 0.86 0.49 Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wt

### Note the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Oxygen 

## 17.51 17.37 17.37EIA Facility Code Facility Name Boiler ID HAPs Test Group 2079 Hawthorn 5A Mercury and non-mercury metalic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) % Ash

(as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Ash (Dry Basis) % Sulfur

(Dry Basis) 1 4/26/2010 4/26/2010 9233.00 Btu/lb 23.64 5.29 0.32 12091 Btu/lb 6.93 0.42 2 4/26/2010 4/26/2010 9066.00 Btu/lb 25.48 6.67 0.4 12166 Btu/lb 6.67 0.4 3 4/26/2010 4/26/2010 9231.00 Btu/lb 24.47 5 0.29 12222 Btu/lb 6.62 0.38 Fuel Testing ResultsChlorine (Dry Basis) Chlorine

Units (test results in ug/g) Mercury

(Dry Basis) Mercury

Units Antimony

(Dry Basis) Antimony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis) Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units(test results in ug/g) Cobalt (Dry

Basis) Cobalt Units 11 ppm 0.076 μg/g 0.14 μg/g 1.1 μg/g 0.2 μg/g 0.07 μg/g 5 μg/g 2.6 μg/g 21 μg/g 4 μg/g 0.9 μg/g 62 ppm 1.7 μg/g 8 ppm 0.084 μg/g 0.14 μg/g 1.2 μg/g 0.2 μg/g 0.07 μg/g 4 μg/g 2.1 μg/g 22 μg/g 4 μg/g 1 μg/g 56 ppm 1.9 μg/g 13 ppm 0.09 μg/g 0.15 μg/g 1 μg/g 0.2 μg/g 0.06 μg/g 4 μg/g 2.3 μg/g 23 μg/g 4 μg/g 0.9 μg/g 63 ppm 1.7 μg/gNote the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Total Moisture Volatiles Ash Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur Oxygen

23.64 44.57 6.93 48.5 69.43 4.71 0.91 0.42 17.6 25.48 44.07 6.67 49.26 69.55 4.72 0.93 0.3 17.73 24.47 44.53 6.62 48.85 69.81 4.75 0.93 0.38 17.51 Proximate Analyses, % by wt Ultimate Analyses, % by wtEIA

Facility Code Facility

Name Boiler ID 

### HAPs Test Group 

## 2079 Hawthorn 5A

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units 

### Fuel Testing Results% Moisture

(as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis)Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Antimony

(Dry Basis) Antimony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis)Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

UnitsNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units Cobalt (Dry

Basis) Cobalt Units Total Moisture Proximate Analy ses, % by

wt

### Note the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur Oxygen Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wt

### Units of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the

Fuel Units of Measure - HHV anthracite Btu/lb bitum inous Btu/gallon subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C) Units of Measure - Metals synfuel mg/g petroleum coke μg/g other mg/Kg

### Units of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the orangehightlighted cell, if necessary

.

Units of Measure - Cl, Fl % ppm