November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 90

Avon Lake

33587 Walker Rd

PolyOne Corp

309-364-9108

Scott.Johnson@polyone.com

PolyOne Henry

1546 County Road, 1450N

Henry

Scott Johnson
ers (PVC) Production Process Wastewater

State: OH Zip Code: 44012

hes, and related establishments owned):

State: ILL Zip Code: 61537
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: P-11

Process Equipment ID: U-2

Wastewater Feed Rate (lb/hr): 20000

Feed Temperature (°F): 200

Feed Inlet Pressure (psia): NA

Liquid Loading Rate (liters/m2): NA

Steam Feed Rate (lb/hr): NA

Steam to Feed Ratio (kg steam/liter of wastewater): NA

Operating Temperature (°F): 226

Operating Pressure (psig): 5

Total Number of Stages: 0

Overall Calculated Tray Efficiency: 0

Stripping Factor: NA

Flow configuration (countercurrent, cocurrent): cocurrent

Number of Actual Trays: 0

Column Height (meters): 6.1

Year Equipment Installed: 1978

Equipment Currently Regulated Under (cite regulations): 61.65 b 9i

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: 9463 liters/hour

 liters

m design rate or capacity, please provide those values:

 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production 

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process w

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3 4 5

Min Max

P1 W1 6048 8467

P2 W1 6221 8294

P4 W2 14976 22464

P5 W2 10368 15552

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

2

Permeate

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

Permeate

Centrate

PVC Process 

Wastewater 

Stream ID

Centrate
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6 7 8

Min Max Average

P1,2,4,5 P-11 Steam Stripping Continuous 720 1200 960

Table 3. PVC Process Wastewater Destination Codes Table

Type of Process 

Wastewater 

Treatment System

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

PVC Process Wastewater Stream Flow Rate 

(gallons per day)
Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2 3 4 5

Min Max Average

Destination Description

1

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

Flow Rate 

Determination 

Method

its a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

eatment system.

 that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

6 7 8 9 10

Average

7258 Measured 305 U3 Ultrafiltration

7258 Measured 261 U5 Ultrafiltration

18720 Measured 190 U5 Centrifuge

12960 Measured 132 U6 Centrifuge

Operating Days Per 

Year

Originating PVC Process 

Equipment Description

Flow Rate 

Determination 

Method

Originating PVC Process 

Equipment ID

ewater Stream Flow Rate 
9 10 11 12 13

Measured 305 WWT Yes

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination 

Information

(Refer to Table 3 below)

Operating Days 

Per Year

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Flow Rate 

Determination 

Method
Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

6 7

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

PVC Process 

Wastewater 

Treatment 

System ID

Operating Days 

Per Year

11 12 13

WWT Yes

WWT Yes

WWT Yes

WWT Yes

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system
able 1 and Column 11 of Table 2
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

Resin Type (suspension, dispersion, bulk, etc.) -->
110543 n-Hexane

108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

PolyOne

Henry

P-11

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 10 Non-detect

SW-846-8015C 0.045 Non-detect

SW-846-8315A 0.149

SW-846-8315A 0.238

SW-846-8270D 0.017 Non-detect

SW-846-8270D 0.0642

SW-846-8270D 0.001

SW-846-8270D 0.005 Non-detect

SW-846-8270D 0.0013 Non-detect

SW-846-8260B 0.00021 Non-detect

SW-846-8260B 0.0019 Non-detect

SW-846-8260B 0.00023 Non-detect

SW-846-8260B 0.00036

SW-846-8260B 0.00023 Non-detect

SW-846-8260B 0.0002 Non-detect

SW-846-8260B 0.00021 Non-detect

SW-846-8260B 0.00045 Non-detect

SW-846-8260B 0.407

SW-846-8260B 0.00023 Non-detect

SW-846-8260B 0.114

SW-846-8260B 0.00049

SW-846-8260B 0.908

SW-846-8260B 0.004

Sample Date -->

Suspension/Blending/Dispersion

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

01/07/13

JB25203-1

JB25203

See Lab Report

Flow Rate Determination Method --> Measured
SW-846-8260B 0.00046 Non-detect

SW-846-8260B 0.00023 Non-detect

SW-846-8260B 0.00024 Non-detect

SW-846-8260B 0.0011

SW-846-8260B 0.0011 Non-detect

SW-846-8260B 0.00027 Non-detect

EPA Method 107 0.084

SW-846-8260B 0.00019 Non-detect

SW-846-8260B 0.00024 Non-detect
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

U 5.18

0.179

0.321

U 0.017 Non-detect U

0.21

J 0.00059 U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.00021 Non-detect U

U 0.0019 Non-detect U

U 0.00023 Non-detect U

J 0.00048 J

U 0.00023 Non-detect U

U 0.0002 Non-detect U

U 0.00021 Non-detect U

U 0.00053 J

1.28

U 0.00023 Non-detect U

0.304

J 0.0019

1.52

0.0007 Non-detect U

uspension/Blending/Dispersion Suspension/Blending/Dispersion

See Lab Report

JB25204-1

1

221

40

01/07/13

2

220

42

JB25203-1

JB25203

See Lab Report

01/08/13

JB25204

Measured Measured
U 0.00046 Non-detect

U

U 0.00023 Non-detectU

U 0.00024U

0.0015

U 0.0011 Non-detectU

U 0.00027 Non-detectU

0.896

U 0.00019 Non-detectU

U 0.00024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

2 15.9

0.117 0.547

0.075 1.37

0.017 Non-detect U 0.017 Non-detect

0.0984 0.802

0.00059 Non-detect U 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.00021 Non-detect U 0.00021 Non-detect

0.0019 Non-detect U 0.0019 Non-detect

0.00023 Non-detect U 0.00023 Non-detect

0.00037 J 0.0004

0.00023 Non-detect U 0.00023 Non-detect

0.0002 Non-detect U 0.0002 Non-detect

0.00021 Non-detect U 0.00021 Non-detect

0.00045 Non-detect U 0.00061

0.526 0.521

0.00023 Non-detect U 0.00023 Non-detect

0.112 0.177

0.0006 J 0.00091

1.16 0.867

0.0032 0.0007 Non-detect

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

See Lab Report

JB25205-1 JB25206-1

3

221 219.6

38

01/09/13 01/10/13

JB25205 JB25206

See Lab Report

Measured Measured
0.00049

J 0.00046 Non-detect

0.00029

J 0.00023 Non-detect

0.00024 Non-detect

U 0.00024 Non-detect

0.0013 0.0011

0.0011 Non-detect

U 0.0011 Non-detect

0.00027 Non-detect

U 0.00027 Non-detect

13.185 7.601

0.00019 Non-detect

U 0.00019 Non-detect

0.00024 Non-detect

U 0.00024 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

0.847

0.123

0.0334

U 0.017 Non-detect U

0.0374

U 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0024 Non-detect

U 0.0054 Non-detect U

U 0.048 Non-detect U

U 0.0056 Non-detect U

J 0.0059 Non-detect U

U 0.0057 Non-detect U

U 0.0051 Non-detect U

U 0.0052 Non-detect U

J 0.011 Non-detect U

0.222

U 0.0057 Non-detect U

0.0679

J 0.0027 Non-detect U

0.425

U 0.018 Non-detect U

uspension/Blending/Dispersion Suspension/Blending/Dispersion

JB25206-1 JB25207-1

4 5

219.6 221

39 40

01/10/13 01/11/13

JB25206 JB25207

See Lab Report See Lab Report

Measured Measured
U 0.012 Non-detect

U

U 0.0057 Non-detectU

U 0.0059 Non-detectU

0.0072 Non-detect

U

U 0.028 Non-detectU

U 0.0067 Non-detectU

0 6.8410

U 0.0048 Non-detectU

U 0.006 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

9.67 17.6

0.301 0.651

0.0243 0.793

0.017 Non-detect U 0.017 Non-detect

0.985 1.01

0.0011 J 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.0054 Non-detect U 0.0054 Non-detect

0.048 Non-detect U 0.048 Non-detect

0.0056 Non-detect U 0.0056 Non-detect

0.0059 Non-detect U 0.0059 Non-detect

0.0057 Non-detect U 0.0057 Non-detect

0.0051 Non-detect U 0.0051 Non-detect

0.0052 Non-detect U 0.0052 Non-detect

0.011 Non-detect U 0.011 Non-detect

0.0527 1.24

0.0057 Non-detect U 0.0057 Non-detect

0.0723 0.549

0.0027 Non-detect U 0.0027 Non-detect

0.226 1.34

0.018 Non-detect U 0.018 Non-detect

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

223

41

See Lab Report

JB25209-1 JB25210-1

01/15/13 01/16/13

6

JB25209 JB25210

See Lab Report

Measured Measured
0.012 Non-detect

U 0.012 Non-detect

0.0057 Non-detect

U 0.0057 Non-detect

0.0059 Non-detect

U 0.0059 Non-detect

0.0072 Non-detect

U 0.0072 Non-detect

0.028 Non-detect

U 0.028 Non-detect

0.0067 Non-detect

U 0.0067 Non-detect

6.793

0 7.205

0.0048 Non-detect

U 0.0048 Non-detect

0.006 Non-detect

U 0.006 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

0.045 Non-detect U

0.112

0.0371

U 0.017 Non-detect U

0.0389

U 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.0054 Non-detect U

U 0.048 Non-detect U

U 0.0056 Non-detect U

U 0.0059 Non-detect U

U 0.0057 Non-detect U

U 0.0051 Non-detect U

U 0.0052 Non-detect U

U 0.011 Non-detect U

0.33

U 0.0057 Non-detect U

0.121

U 0.0027 Non-detect U

0.549

U 0.018 Non-detect U

uspension/Blending/Dispersion Suspension/Blending/Dispersion

42 38

See Lab Report See Lab Report

JB25210-1

01/16/13 01/17/13

7 8

223 223

JB25210 JB25211

JB25211-1

Measured Measured
U 0.012 Non-detect

U

U 0.0059J

U 0.0059 Non-detectU

U 0.0072 Non-detectU

U 0.028 Non-detectU

U 0.0067 Non-detectU

6.565

U 0.0048 Non-detectU

U 0.006 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

6.11 1.85

0.193 0.33

0.021 0.155

0.017 Non-detect U 0.017 Non-detect

0.591 0.0252

0.0015 J 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.0054 Non-detect U 0.0054 Non-detect

0.048 Non-detect U 0.048 Non-detect

0.0056 Non-detect U 0.0056 Non-detect

0.0059 Non-detect U 0.0059 Non-detect

0.0057 Non-detect U 0.0057 Non-detect

0.0051 Non-detect U 0.0051 Non-detect

0.0052 Non-detect U 0.0052 Non-detect

0.011 Non-detect U 0.011 Non-detect

0.268 0.811

0.0057 Non-detect U 0.0057 Non-detect

0.073 0.415

0.0027 Non-detect U 0.0027 Non-detect

0.651 1.13

0.018 Non-detect U 0.018 Non-detect

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

Measured

39

See Lab Report

Measured

01/18/13 01/21/13

9

224.5

See Lab Report

JB25212

JB25212-1 JB25213-1

JB25213
0.012 Non-detect

U 0.012 Non-detect

0.0057 Non-detect

U 0.0057 Non-detect

0.0059 Non-detect

U 0.0059 Non-detect

0.0072 Non-detect

U 0.0072 Non-detect

0.028 Non-detect

U 0.028 Non-detect

0.0067 Non-detect

U 0.0067 Non-detect

6.479 4.861

0.0048 Non-detect

U 0.0048 Non-detect

0.006 Non-detect

U 0.006 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 0.01 Non-detect U

1.95

0.125

0.0477

U 0.017 Non-detect U

0.0581

U 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.0054 Non-detect U

U 0.048 Non-detect U

U 0.0056 Non-detect U

U 0.0059 Non-detect U

U 0.0057 Non-detect U

U 0.0051 Non-detect U

U 0.0052 Non-detect U

U 0.011 Non-detect U

0.478

U 0.0057 Non-detect U

0.122

U 0.0027 Non-detect U

0.967

U 0.018 Non-detect U

uspension/Blending/Dispersion Suspension/Blending/Dispersion

Measured Measured

01/21/13 01/22/13

10 11

222

See Lab Report

39 40

221

See Lab Report

JB25213-1 JB25214-1

JB25213 JB25214
U 0.012 Non-detect

U

U 0.0057 Non-detectU

U 0.0059 Non-detectU

U 0.0072 Non-detectU

U 0.028 Non-detectU

U 0.0067 Non-detectU

7.447

U 0.0048 Non-detectU

U 0.006 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

4.36 5.03

0.116 0.856

0.059 0.583

0.017 Non-detect U 0.017 Non-detect

0.595 0.0142

0.00059 U 0.0042

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.00021 Non-detect U 0.0021 Non-detect

0.0019 Non-detect U 0.019 Non-detect

0.00023 Non-detect U 0.0023 Non-detect

0.00086 J 0.0024 Non-detect

0.00023 Non-detect U 0.0023 Non-detect

0.0002 Non-detect U 0.002 Non-detect

0.00021 Non-detect U 0.0021 Non-detect

0.00095 J 0.0045 Non-detect

0.242 1.69

0.00023 Non-detect U 0.0023 Non-detect

0.0969 0.423

0.00011 Non-detect U 0.0011 Non-detect

0.565 1.77

0.0007 Non-detect U 0.007 Non-detect

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

Measured Measured

01/28/13

12

02/04/13

37

223

See Lab Report See Lab Report

JB25215-1 JB25216-1

JB25215 JB25216
0.00046 Non-detect

U 0.0046 Non-detect

0.00023 Non-detect

U 0.0023 Non-detect

0.00024 Non-detect

U 0.0024 Non-detect

0.00082

J 0.0029 Non-detect

0.0011 Non-detect

U 0.011 Non-detect

0.00027 Non-detect

U 0.0027 Non-detect

6.092 6.691

0.00019 Non-detect

U 0.0019 Non-detect

0.00024 Non-detect

U 0.0024 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

9.35

0.604

0.578

U 0.017 Non-detect U

0.38

0.0015 J

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.0021 Non-detect U

U 0.019 Non-detect U

U 0.0023 Non-detect U

U 0.0024 Non-detect U

U 0.0023 Non-detect U

U 0.002 Non-detect U

U 0.0021 Non-detect U

U 0.0045 Non-detect U

0.675

U 0.0023 Non-detect U

0.184

U 0.0011 Non-detect U

1.01

U 0.007 Non-detect U

uspension/Blending/Dispersion Suspension/Blending/Dispersion

221

Measured Measured

13 14

02/04/13 02/05/13

40 41

221

See Lab Report See Lab Report

JB25216-1 JB25217-1

JB25216 JB25217
U 0.0046 Non-detect

U

U 0.0023 Non-detectU

U 0.0024 Non-detectU

U 0.0029 Non-detectU

U 0.011 Non-detectU

U 0.0027 Non-detectU

7.217

U 0.0019 Non-detectU

U 0.0024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

0.045 Non-detect U 0.635

0.121 0.112

0.017 J 0.0558

0.017 Non-detect U 0.017 Non-detect

0.0247 0.04

0.001 J 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.011 Non-detect U 0.0043 Non-detect

0.095 Non-detect U 0.038 Non-detect

0.011 Non-detect U 0.0045 Non-detect

0.012 Non-detect U 0.0047 Non-detect

0.011 Non-detect U 0.0046 Non-detect

0.01 Non-detect U 0.0041 Non-detect

0.01 Non-detect U 0.0042 Non-detect

0.022 Non-detect U 0.0089 Non-detect

0.322 0.272

0.011 Non-detect U 0.0046 Non-detect

0.121 0.0962

0.0053 Non-detect U 0.0021 Non-detect

0.633 0.547

0.035 Non-detect U 0.014 Non-detect

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

15

02/06/13 02/07/13

219

Measured Measured

See Lab Report

JB25218 JB25219

JB25218-1 JB25219-1

See Lab Report

39
0.023 Non-detect

U 0.0093 Non-detect

0.011 Non-detect

U 0.0045 Non-detect

0.012 Non-detect

U 0.0047 Non-detect

0.014 Non-detect

U 0.0057 Non-detect

0.056 Non-detect

U 0.022 Non-detect

0.013 Non-detect

U 0.0054 Non-detect

7.831 9.898

0.0096 Non-detect

U 0.0038 Non-detect

0.012 Non-detect

U 0.0048 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

3.28

0.0422

0.0068 J

U 0.017 Non-detect U

0.0418

U 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.00021 Non-detect U

U 0.0019 Non-detect U

U 0.00023 Non-detect U

U 0.00073 J

U 0.00023 Non-detect U

U 0.0002 Non-detect U

U 0.00021 Non-detect U

U 0.00045 Non-detect U

0.619

U 0.00023 Non-detect U

0.184

U 0.001 Non-detect

0.946

U 0.0007 Non-detect U

uspension/Blending/Dispersion Suspension/Blending/Dispersion

16 17

02/07/13 02/08/13

Measured Measured

221 222

JB25219 JB25220

JB25219-1 JB25220-1

See Lab Report See Lab Report

42 36
U 0.00046 Non-detect

U

U 0.00023 Non-detectU

U 0.00024 Non-detectU

U 0.0009 Non-detectJ

U 0.0011 Non-detectU

U 0.00027 Non-detectU

8.662

U 0.00019 Non-detectU

U 0.00024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

4.4 7.14

0.952 0.217

0.492 0.0216

0.017 Non-detect U 0.017 Non-detect

0.0222 0.478

0.00059 Non-detect U 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.0021 Non-detect U 0.0021 Non-detect

0.019 Non-detect U 0.019 Non-detect

0.0023 Non-detect U 0.0023 Non-detect

0.0024 Non-detect U 0.0024 Non-detect

0.0023 Non-detect U 0.0023 Non-detect

0.002 Non-detect U 0.002 Non-detect

0.0021 Non-detect U 0.0021 Non-detect

0.0045 Non-detect U 0.0045 Non-detect

1.84 0.769

0.0023 Non-detect U 0.0023 Non-detect

0.375 0.0961

0.0011 Non-detect U 0.0011 Non-detect

1.78 1.5

0.007 Non-detect U 0.007 Non-detect

02/12/13

Suspension/Blending/Dispersion

Measured

See Lab Report

JB25222

JB25222-1

Suspension/Blending/Dispersion

18

02/11/13

Measured

221

See Lab Report

JB25221

JB25221-1

40
0.0046 Non-detect

U 0.0046 Non-detect

0.0023 Non-detect

U 0.0023 Non-detect

0.0024 Non-detect

U 0.0024 Non-detect

0.0029 Non-detect

U 0.0029 Non-detect

0.011 Non-detect

U 0.011 Non-detect

0.0027 Non-detect

U 0.0027 Non-detect

8.586 6.533

0.0019 Non-detect

U 0.0019 Non-detect

0.0024 Non-detect

U 0.0024 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

3.79

0.314

0.294

U 0.017 Non-detect U

0.0703

U 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.0021 Non-detect U

U 0.019 Non-detect U

U 0.0023 Non-detect U

U 0.0024 Non-detect U

U 0.0023 Non-detect U

U 0.002 Non-detect U

U 0.0021 Non-detect U

U 0.0045 Non-detect U

0.797

U 0.0023 Non-detect U

0.225

U 0.0011 Non-detect U

1.24

U 0.007 Non-detect U

19

02/12/13

uspension/Blending/Dispersion

41

Measured

223

See Lab Report

JB25222

JB25222-1

Suspension/Blending/Dispersion

20

02/13/13

39

Measured

222

See Lab Report

JB25223

JB25223-1
U 0.0046 Non-detect

U

U 0.0023 Non-detectU

U 0.0024 Non-detectU

U 0.0029 Non-detectU

U 0.011 Non-detectU

U 0.0027 Non-detectU

9.583

U 0.0019 Non-detectU

U 0.0024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

4.08 0.045

0.308 0.0972

0.274 0.0129

0.017 Non-detect U 0.017 Non-detect

0.021 0.0526

0.00059 Non-detect U 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.0021 Non-detect U 0.0021 Non-detect

0.019 Non-detect U 0.019 Non-detect

0.0023 Non-detect U 0.0023 Non-detect

0.0024 Non-detect U 0.0024 Non-detect

0.0023 Non-detect U 0.0023 Non-detect

0.002 Non-detect U 0.002 Non-detect

0.0021 Non-detect U 0.0021 Non-detect

0.0045 Non-detect U 0.0045 Non-detect

1.06 0.307

0.0023 Non-detect U 0.0023 Non-detect

0.302 0.187

0.0011 Non-detect U 0.0011 Non-detect

1.3 0.713

0.007 Non-detect U 0.007 Non-detect

JB25224-1 JB25225-1

Measured Measured

02/14/13 02/15/13

JB25225

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

21

221

JB25224

See Lab Report See Lab Report

42
0.0046 Non-detect

U 0.0046 Non-detect

0.0023 Non-detect

U 0.0023 Non-detect

0.0024 Non-detect

U 0.0024 Non-detect

0.0029 Non-detect

U 0.0029 Non-detect

0.011 Non-detect

U 0.011 Non-detect

0.0027 Non-detect

U 0.0027 Non-detect

7.89 8.818

0.0019 Non-detect

U 0.0019 Non-detect

0.0024 Non-detect

U 0.0024 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

U 9.07

0.163

J 0.0221

U 0.017 Non-detect U

0.0644

U 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.00021 Non-detect U

U 0.0019 Non-detect U

U 0.00023 Non-detect U

U 0.00059 J

U 0.00023 Non-detect U

U 0.0002 Non-detect U

U 0.00021 Non-detect U

U 0.00045 Non-detect U

0.196

U 0.00023 Non-detect U

0.0753

U 0.00011 Non-detect U

0.575

U 0.0007 Non-detect U

JB25225-1 JB25226-1

Measured

220

02/15/13 02/19/13

JB25225 JB25226

uspension/Blending/Dispersion Suspension/Blending/Dispersion

222

Measured

See Lab Report See Lab Report

39 40

22 23
U 0.00046 Non-detect

U

U 0.00023 Non-detectU

U 0.00024 Non-detectU

U 0.00068J

U 0.0011 Non-detectU

U 0.00027 Non-detectU

7.024

U 0.00019 Non-detectU

U 0.00024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

25.2 12.2

0.607 0.138

0.912 0.0904

0.017 Non-detect U 0.017 Non-detect

0.188 0.569

0.00059 Non-detect U 0.00059 Non-detect

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.0021 Non-detect U 0.0054 Non-detect

0.019 Non-detect U 0.048 Non-detect

0.0023 Non-detect U 0.0056 Non-detect

0.0024 Non-detect U 0.0059 Non-detect

0.0023 Non-detect U 0.0057 Non-detect

0.002 Non-detect U 0.0051 Non-detect

0.0021 Non-detect U 0.0052 Non-detect

0.0045 Non-detect U 0.011 Non-detect

0.726 0.67

0.0023 Non-detect U 0.0057 Non-detect

0.218 0.214

0.0011 Non-detect U 0.0027 Non-detect

0.67 0.86

0.007 Non-detect U 0.018 Non-detect

JB25227-1 JB25228-1

Measured

223

02/20/13 02/25/13

37

Suspension/Blending/Dispersion Suspension/Blending/Dispersion

Measured

See Lab Report See Lab Report

JB25227 JB25228

24
0.0046 Non-detect

U 0.012 Non-detect

0.0023 Non-detect

U 0.0057 Non-detect

0.0024 Non-detect

U 0.0059 Non-detect

0.0029 Non-detect

U 0.0072 Non-detect

0.011 Non-detect

U 0.028 Non-detect

0.0027 Non-detect

U 0.0067 Non-detect

5.658 17.841

0.0019 Non-detect

U 0.0048 Non-detect

0.0024 Non-detect

U 0.006 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 0.01 Non-detect U

3.2

0.208

0.211

U 0.017 Non-detect U

0.0609

U 0.0012 J

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.00021 Non-detect U

U 0.0019 Non-detect U

U 0.00023 Non-detect U

U 0.00093 J

U 0.00023 Non-detect U

U 0.0002 Non-detect U

U 0.00021 Non-detect U

U 0.00045 Non-detect U

0.638

U 0.00023 Non-detect U

0.377

U 0.0012 Non-detect

0.766

U 0.0007 Non-detect U

JB25228-1

02/25/13 03/01/13

38

uspension/Blending/Dispersion Suspension/Blending/Dispersion

Measured

26

See Lab Report

JB25228

25

39

221 222

JB25229-1

See Lab Report

JB25229

Measured
U 0.00046 Non-detect

U

U 0.00023 Non-detectU

U 0.00024 Non-detectU

U 0.0015 U 0.0011 Non-detect

U

U 0.00027 Non-detectU

7.874

U 0.00019 Non-detectU

U 0.00024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U 10 Non-detect

3.22 4.37

4.89 0.204

0.108 0.288

0.017 Non-detect U 0.017 Non-detect

0.0513 0.0832

0.0051 0.0011

0.005 Non-detect U 0.005 Non-detect

0.0013 Non-detect U 0.0013 Non-detect

0.0021 Non-detect U 0.00021 Non-detect

0.019 Non-detect U 0.0019 Non-detect

0.0023 Non-detect U 0.00023 Non-detect

0.0024 Non-detect U 0.00098

0.0023 Non-detect U 0.00023 Non-detect

0.002 Non-detect U 0.0002 Non-detect

0.0021 Non-detect U 0.00021 Non-detect

0.0076 J 0.00045

0.488 0.666

0.0023 Non-detect U 0.00023 Non-detect

0.245 0.338

0.0011 Non-detect U 0.0012 Non-detect

0.648 0.714

0.007 Non-detect U 0.0007 Non-detect

03/04/13

Suspension/Blending/Dispersion

38

223

03/05/13

Suspension/Blending/Dispersion

Measured

See Lab Report

JB25231

JB25230-1

See Lab Report

JB25230

Measured

27

JB25231-1
0.0046 Non-detect

U 0.00046 Non-detect

0.0023 Non-detect

U 0.00023 Non-detect

0.0024 Non-detect

U 0.00024 Non-detect

0.0029 Non-detect

U 0.0015

0.011 Non-detect

U 0.0011 Non-detect

0.0027 Non-detect

U 0.00027 Non-detect

7.404 5.658

0.0019 Non-detect

U 0.00019 Non-detect

0.0024 Non-detect

U 0.00024 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 10 Non-detect U

2.38

0.163

0.0878

U 0.017 Non-detect U

0.0349

J 0.00059 Non-detect U

U 0.005 Non-detect U

U 0.0013 Non-detect U

U 0.0021 Non-detect U

U 0.019 Non-detect U

U 0.0023 Non-detect U

J 0.0024 Non-detect U

U 0.0023 Non-detect U

U 0.002 Non-detect U

U 0.0021 Non-detect U

U 0.0045 Non-detect U

0.457

U 0.0023 Non-detect U

0.179

0.0011 Non-detect U

0.606

U 0.007 Non-detect U

03/06/13

Suspension/Blending/Dispersion

39

222

28

03/05/13

uspension/Blending/Dispersion

41

Measured

221

See Lab Report

JB25231

JB25232-1

See Lab Report

JB25232

Measured

29

JB25231-1
U 0.0046 Non-detect

U

U 0.0023 Non-detectU

U 0.0024 Non-detectU

0.0029 Non-detect

U

U 0.011 Non-detectU

U 0.0027 Non-detectU

6.653

U 0.0019 Non-detectU

U 0.0024 Non-detectU
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect U

1.97

0.209

0.0108 J

0.017 Non-detect U

0.0865

0.0014 J

0.005 Non-detect U

0.0013 Non-detect U

0.00021 Non-detect U

0.0019 Non-detect U

0.00023 Non-detect U

0.00055 J

0.00023 Non-detect U

0.0002 Non-detect U

0.00021 Non-detect U

0.00045 Non-detect U

0.232

0.00023 Non-detect U

0.0857

0.00011 Non-detect U

0.646

0.0007 Non-detect U

See Lab Report

JB26507

Measured

Suspension/Blending/Dispersion

JB26507-1

30

03/07/13

39

221
0.00046 Non-detect

U

0.00023 Non-detect

U

0.00024 Non-detect

U

0.00029 Non-detect

U

0.0011 Non-detect

U

0.00027 Non-detect

U

7.069

0.00019 Non-detect

U

0.00024 Non-detect

U
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

31 32

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

33

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

34 35

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

36

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

37 38

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

39

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

40 41

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

42

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

43 44

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

45

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

46 47

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

48

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

49 50

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

51

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

52 53

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

54

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

55 56

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

57

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

58 59

Concentration 

(ppmw) Non-Detect? Note(s)

60