Part II - Section A, d – Manufacturing Diagram

Samples a-b Analysis a-b Release 1-2

Pack out to drums 

Release 3 (incineration)

 Pack out of filter cake to drums (incineration)

Release 4

Pack out to trailer (WWTP)

Release 5

Sample f Analysis f Release 6

Sample g Analysis g Release 7

Pack out to trailer (WWTP)

Sample h Analysis h Release 8 Release 9

Samples i,j

Product Batch size: 78151 kg

PMN substance: 21726 kg

Reactant 1: 7224 kg/batch

Solvent 1: 12697 kg/batch

Reactant 2: 

15811 kg/batch

Solvent 1: 6776 kg/batch

Solvent 1 (rinse): 1785 

kg/batch

Water for washing

Solvent 2: 5983 kg/batch

Solvent 3: 5983 kg/batch

Water: 1777 kg/batch

Reactant 3: 7589 kg/batch

Vessel 1

Heat to drive off water 

(optional) 88-110 °C

Vessel 1

Reaction 1

20 - 70 °C

Filter 1

Filtration

70 °C

Reactant 1 / HCl (filter cake) drums

Vessel 2

Distillation

98 °C (vacuum)

Vessel 1

Washing / Decantation

72 °C

Vessel 2

Bottom phase decantation

72 °C

Vessel 1

Washing / Decantation

72 °C

Vessel 2

Bottom phase decantation

72 °C

W ater for washing

NaCl

Solvent 1 (condensed) organic waste 

tank - for incineration 

Vessel 1 water waste - WWTP

 Vessel 1 water waste / NaCl - WWTP

Vessel 1

Distillation/Drying 

98°C/Vacuum,

Reaction 2, 103 °C

Vessel 3

Standartization / pH 

adjustment, 20-60 °C

W ater waste (condensed): 900 kg

Filter 1

Filtration

90-100 °C

 Water (rinse) Filter 1 rinse water waste - WW TP

NaCl / Filter aid (filter cake) d

Water (rinse)

W ater: 29470 kg/batch

25% NaOH aqueous 

solution

 Water waste / NaCl,

Vessel 2 water waste - WWTP

Vessel 1 rinse water waste c: Ethanol: 908 kg

Water: 3632 kg (every campaign)

Vessel 3 rinse water waste l - to WW TP

Tank truck 

Drums/Totes/Pails

pack out of PMN Substance k

Filter 1 rinse water waste e - to WWTP

Waste water (condensed) with Reactant 1

Filter aid: 700 kg/batch

Na2CO3 (optional) 319 kg

Solvent 2: 9246 kg/batch

Solvent 3: 3263 kg/batch

Solvent 2 (rinse): 1450 kg/batch

Solvent 3 (rinse): 725 kg/batch

Water (rinse)

Reactant 1: 1,3-Propanediamine, N1,N1-dimethyl-, [109-55-7] 

Reactant 2: 1-Octanesulfonyl chloride, 3,3,4,4,5,5,6,6,7,7,8,8,8-

tridecafluoro-, [27619-89-2] 

Reactant 3: 1-Propanesulfonic acid, 3-chloro-2-hydroxy-, sodium salt 

(1:1), [126-83-0] 

Water [7732-18-5] 

Solvent 1: Toluene [108-88-3] 

Solvent 2: 2,4-Pentanediol, 2-methyl-, [107-41-5] 

Solvent 3: 1,2-Propanediol, [57-55-6] 

Filter aid: Diatomaceous earth, [61790-53-2] 

Sodium hydroxide (25% in Water) [1310-73-2] 

Sodium carbonate (Na2CO3) [497-19-8] 

Operator Exposures: 

Samples a-b

Analysis a-b

Vessel 1 ethanol/water rinse c

Pack out of NaCl filter cake d

Filter 1 water rinse e

Samples f,g

Analyses f,g

Sample h 

Analysis h

Sample i,j 

Pack out of PMN Substance k

Vessel 3 water rinse l

Sample/Analysis a-b: Reaction completion 

Sample/Analysis f-g: pH/solids 

Sample/Analysis h: Release sample/Retain 

Sample i: Building Retain 

Sample j: Technical Retain 

Release 1, 2: Sample Disposal (0.1 kg/batch each)

Release 3: Vessel 1 Ethanol/water rinse 

 (1.5 kg/batch per Vessel) 

Release 4: Filter cake disposal 

 (780 kg/batch per Vessel each) 

Release 5: Filter 1 Rinse 

 (0.7 kg/Batch per Vessel each) 

Release 6, 7: Sample Disposal (0.04 kg/batch each)

Release 8: Sample Disposal (0.04 kg/batch each)

Release 9: Vessel 3 Rinse (2 kg/Batch per Vessel each)