# Part II - Section A, d – Manufacturing Diagram

Samples a-b Analysis a-b Release 1-2

Pack out to drums Release 3 (incineration)

Pack out of filter cake to drums (incineration) Release 4

Pack out to trailer (WWTP) Release 5

Sample f Analysis f Release 6 Sample g Analysis g Release 7 Pack out to trailer (WWTP) Sample h Analysis h Release 8 Release 9 Samples i,j

Product Batch size: 78151 kg PMN substance: 21726 kg Reactant 1: 7224 kg/batch Solvent 1: 12697 kg/batch

Reactant 2: 15811 kg/batch Solvent 1: 6776 kg/batch Solvent 1 (rinse): 1785 kg/batch

Water for washing

Solvent 2: 5983 kg/batch Solvent 3: 5983 kg/batch Water: 1777 kg/batch Reactant 3: 7589 kg/batch Vessel 1 Heat to drive off water (optional) 88-110 °C

Vessel 1 Reaction 1 20 - 70 °C

Filter 1 Filtration 70 °C Reactant 1 / HCl (filter cake) drums

Vessel 2 Distillation 98 °C (vacuum)

Vessel 1 Washing / Decantation 72 °C

Vessel 2 Bottom phase decantation

72 °C

Vessel 1 Washing / Decantation 72 °C

Vessel 2 Bottom phase decantation

72 °C W ater for washing NaCl Solvent 1 (condensed) organic waste tank - for incineration

Vessel 1 water waste - WWTP

Vessel 1 water waste / NaCl - WWTP

Vessel 1 Distillation/Drying 98°C/Vacuum, Reaction 2, 103 °C

Vessel 3 Standartization / pH adjustment, 20-60 °C W ater waste (condensed): 900 kg

Filter 1 Filtration 90-100 °C Water (rinse) Filter 1 rinse water waste - WW TP

NaCl / Filter aid (filter cake) d

Water (rinse)

W ater: 29470 kg/batch 25% NaOH aqueous solution Water waste / NaCl, Vessel 2 water waste - WWTP

Vessel 1 rinse water waste c : Ethanol: 908 kg Water: 3632 kg (every campaign)

Vessel 3 rinse water waste l - to WW TP

Tank truck Drums/Totes/Pails pack out of PMN Substance k Filter 1 rinse water waste 

### e - to WWTP Waste water (condensed) with Reactant 1

Filter aid: 700 kg/batch Na 2 CO 3 (optional) 319 kg Solvent 2: 9246 kg/batch Solvent 3: 3263 kg/batch Solvent 2 (rinse): 1450 kg/batch Solvent 3 (rinse): 725 kg/batch

Water (rinse) 

# Reactant 1: 1,3-Propanediamine, N1,N1-dimethyl-, [109-55-7] Reactant 2: 1-Octanesulfonyl chloride, 3,3,4,4,5,5,6,6,7,7,8,8 ,8- tridecafluoro-, [27619-89-2] Reactant 3: 1-Propanesulfonic acid, 3-chloro-2-hydroxy-, sodiu m salt (1:1), [126-83-0] Water [7732-18-5] Solvent 1: Toluene [108-88-3] Solvent 2: 2,4-Pentanediol, 2-methyl-, [107-41-5] Solvent 3: 1,2-Propanediol, [57-55-6] Filter aid: Diatomaceous earth, [61790-53-2] Sodium hydroxide (25% in Water) [1310-73-2] Sodium carbonate (Na 2 

# CO 3 

# ) [497-19-8]

Operator Exposures: Samples a-b Analysis a-b Vessel 1 ethanol/water rinse c Pack out of NaCl filter cake d Filter 1 water rinse e Samples f,g Analyses f,g Sample h Analysis h Sample i,j Pack out of PMN Substance k Vessel 3 water rinse l Sample/Analysis a

- b : Reaction completion Sample/Analysis f-g : pH/solids Sample/Analysis h : Release sample/Retain Sample i : Building Retain Sample j : Technical Retain Release 1, 2 : Sample Disposal (0.1 kg/batch each) 

## Release 3 : Vessel 1 Ethanol/water rinse (1.5 kg/batch per Vessel) 

## Release 4 : Filter cake disposal (780 kg/batch per Vessel each) 

## Release 5 : Filter 1 Rinse (0.7 kg/Batch per Vessel each) 

## Release 6, 7 : Sample Disposal (0.04 kg/batch each) 

## Release 8 : Sample Disposal (0.04 kg/batch each) 

## Release 9 : Vessel 3 Rinse (2 kg/Batch per Vessel each)