*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 1 of 149 6560 - 50 - P ENVIRONMENTAL PROTECTION 40 CFR Part 63 [EPA - HQ - OAR - 20 11 - 0797 ; FRL - ???]

RIN 2060 - AQ92 National Emissions Standards for Hazardous Air Pollutants: Primary Aluminum Reduction Plants
AGENCY: Environmental Protection Agency (EPA).
ACTION : Proposed rule. SUMMARY: The EPA is proposing amendments to the national emissions standards for hazardous air pollutants for Primary Aluminum Reduction Plants to address the results of the residual risk and technology review that the EPA is required to conduct by the Clean Air Act. If finalized , t hese proposed amendments would address previously unregulated emissions (i.e., carbonyl sulfide (COS) emissions from new and existing potlines and polycyclic organic matter (POM) emissions from new and existing prebake potlines and existing pitch storage tanks); remove the vertical stud Soderberg one (VSS1) potline subcategory; reduce the MACT limits for POM emissions fr om horizontal stud Soderberg (HSS) and VSS2 potlines; eliminate the startup, shutdown and malfunction exemption in accordance with recent actions by the United States Court of Appeals for the District of Columbia Circuit; add provisions for facilities to a vail themselves of an affirmative defense in the event of a malfunction under certain*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 2 of 149 conditions; and make certain technical and editorial changes. The proposed emissions limits for POM and COS are based on maximum achievable control technology ( MACT ) . Whi le the proposed modifications would result in some reduction in actual emissions of
POM from existing pitch storage tanks, reduce the potential emissions of POM from Soderberg potlines, and prevent increases in emissions of COS and sulfur dioxide, the heal th risks posed by actual emissions from this source category are currently within the acceptable range and would not be reduced appreciably by the proposed modifications. These proposed amendments :

 Reduc e e missions limits for Polycyclic Organic Matter ( POM ) for Soderberg potlines ;

 E stablish POM emission limits for existing and new prebake potlines , which were previously unregulated for POM ;

 Establish a carbonyl sulfide ( COS ) emission limit for potlines , which were previously unregulated for COS ;

 Requir e e xist ing pitch storage tanks to meet the same standard as new pitch storage tanks ;

 Add work practice standards for periods of startup for potlines ;

 Require anode bake furnaces and pitch storage tanks to comply with the MACT standards during periods of startup and modify the MACT standard for anode bake furnaces to include startup practices ;

 Revis e applicability to include existing pitch storage tanks ;*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 3 of 149

 Revis e the incorporation by reference section to include a method for measurement of sulfur in coke;

 Add a definition of affirmative defense and remov e the definition of Vertical stud Soderberg one ( VSS1 ) potlines ; and

 Make technical and editorial changes
. DATES: Comments must be received on or before [ INSERT THE DATE 45
DAYS AFTER THE DATE OF PUBLICATION OF THIS PROPOSED RULE IN THE
FEDERAL REGISTER ]. Under the Paperwork Reduction Act, comments on the information collection provisions are best assured of receiving having full consideration effect if the Office of Management and Budget (OMB) receives a copy of y our comments on or before [ INSERT THE DATE 30
DAYS AFTER THE DATE OF PUBLICATION OF THIS PROPOSED RULE IN THE
FEDERAL REGISTER ]. Public Hearing . If anyone contacts the EPA requesting to speak at a public hearing by [ INSERT THE DATE 10 DAYS AFTER THE DATE O F
PUBLICATION IN THE FEDERAL REGISTER ] , a public hearing will be held

on [ INSERT THE DATE 15 DAYS AFTER THE DATE OF PUBLICATION IN THE
FEDERAL REGISTER ]
. ADDRESSES: Submit your comments, identified by Docket ID Number EPA

HQ

- OAR

- 2011

- 0797 , by one of the fo llowing methods:

 http:// www.regulations.gov: Follow the on

- line instructions for submitting comments.

 Email : a - and

- r - docket@epa.gov , Attention Docket ID Number EPA

HQ

- OAR

- 2011

- 0797
.
 Fax: (202) 566

- 9744, Attention Docket ID Number EPA

- HQ

- OAR

- 2011

- 0797
.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 4 of 149

 Mail : U.S. Postal Service, send comments to: EPA Docket Center, EPA West (Air Docket), Attention Docket ID Number EPA

- HQ

- OAR

2011

- 0797 , U.S. Environmental Protection Agency, Mail C ode: code: 2822T, 1200 Pennsylvania Ave., NW, Washington, DC 20460. Please includ e a total of two copies. In addition, please mail a copy of your comments on the information collection provisions to the Office of Information and Regulatory Affairs, Office of Management and Budget (OMB), Attn: Desk Officer for EPA, 725 17 th Street, NW, Washington, DC 20503.

 Hand Delivery : U.S. Environmental Protection Agency, EPA West (Air Docket), Room 3334, 1301 Constitution Ave., NW, Washington, DC 20004, Attention Docket ID Number EPA

- HQ

- OAR

- 2011

- 0797 . Such deliveries are only accepted during the D ocket‘s normal hours of operation, and special arrangements should be made for deliveries of boxed information.

Instructions
. Direct your comments to Docket ID Number EPA

- HQ

OAR

- 2011

- 0797
. The EPA ‘s policy is that all comments received will be included in the public docket without change and may be made available on

- line at http:// www.regulations.gov , including any personal information provided, unless the comment includes information claimed to be confidential business information (CBI) or other information whose disclosure is restricted by statute. Do not submit information that you consider to be CBI or otherwise protected through http:// www.regulations.gov or email. Th e http:// www.regulations.gov website is an ―anonymous access‖ system, which means the EPA will not know your identity or contact information unless you provide it in the body of your comment. If you send an email co mment directly to the EPA without going through http:// www.regulations.gov , your email address will be automatically captured and included as part of the comment that is placed in the*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 5 of 149 public docket and made availabl e on the Internet. If you submit an electronic comment, the EPA recommends that you include your name and other contact information in the body of your comment and with any disk or CD

- ROM you submit. If the EPA cannot read your comment due to technical dif ficulties and cannot contact you for clarification, the
EPA may not be able to consider your comment. Electronic files should avoid the use of special characters, any form of encryption, and be free of any defects or viruses. For additional information abo ut the
EPA ‘s public docket, visit the EPA Docket Center homepage at http://www.epa.gov/epahome/dockets.htm.
Docket
. The EPA has established a docket for this rulemaking under Docket ID Number EPA

- HQ

- OAR

- 2011

- 0797
. All documents in the docket are listed in the http:// www.regulations.gov index. Although listed in the index, some information is not publicly available,
e.g. , CBI or other information whose disclosure is restricted by statute. Certain other material, such as copyrighted material, is not placed on the Internet and will be publicly available only in hard copy. Publicly available docket materials are available either electronically in http:// www.regulations.gov or in ha rd copy at the
EPA Docket Center, EPA West, Room 3334, 1301 Constitution Ave., NW, Washington, DC. The Public Reading Room is open from 8:30 a.m. to 4:30 p.m. , Monday through Friday, excluding legal holidays. The telephone number for the Public Reading Room is (202) 566

- 1744, and the telephone number for the EPA Docket Center is (202) 566

- 1742.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 6 of 149 Public Hearing . If a public hearing is held, it will begin at 10:00 a.m. on [ INSERT THE DATE 15 DAYS AFTER THE DATE OF PUBLICATION
OF THIS PROPOSED RULE IN THE FEDERAL REGISTER ] and will be held at the EPA ‘s campus in Research Triangle Park, North Carolina, or at an alternate facility nearby. Persons interested in present ing oral testimony or inquiring as to whether a public hearing is to be held should contact Ms. Virginia Hunt, Office of Air Quality Planning and Standards , Sector Policies and Programs Division, (D243

- 02), U.S. Environmental Protection Agency, Research Tr iangle Park, North Carolina 27711; telephone number: (919) 541

– 0832. FOR FURTHER INFORMATION CONTACT : For questions about this proposed action, c ontact Mr. David Putney, Sector Policies and Programs Division (D243

- 02), Office of Air Quality Planning and S tandards, U.S. Environmental Protection Agency, Research Triangle Park, North Carolina 27711, telephone (919) 541

- 2016; fax number: (919) 541

- 3207 ; and email address: p utney.david @epa. gov . For specific information regarding the risk modeling methodology, contact Dr . Michael Stewart , Office of Air Quality Planning and Standards, Health and Environmental Impacts Division, Air Toxics Assessment Group (C 504

– 0 6 ), U.S. Environmental Protection Agency, Research Triangle Park, NC 27711; telephone number : (919) 541

– 7524 ; fax number : (919) 541

– 0840; and e mail address: stewart.michael@epa.gov. For information about the applicability of the proposed or current national emission standards for hazardous air pollutants ( NESHAP ) for primary aluminum*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 7 of 149 reduction plants to a particular entity, contact the appropriate person listed in Table 1 of this preamble.
Table 1
. List o f E PA Contacts for the For The N ESHAP Addressed i n t his In This Proposed Action NESHAP for: OECA Contact 1 OAQPS Contact 2 Primary Aluminum Reduction Plants Patrick Yellin , (202) 564

- 2970 yellin.patrick @epa.gov David Putney, (919) 541

- 2016 , putney.david @epa.gov 1 EPA Office of Enforcement and Compliance Assurance. 2 EPA Office of Air Quality Planning and Standards. SUPPLEMENTARY INFORMATION : Preamble Acronyms and Abbreviations Several acronyms and terms used to describe industrial processes, data inventories, and risk modeling are included in this preamble. While th is may not be an exhaustive list, to ease the reading of this preamble and for reference purposes, the following terms and acronyms are defined here for reference : :
ADAF age - dependent adjustment factors AEGL acute exposure guideline levels AERMOD air dispersion model used by the HEM

- 3 model AMOS ample margin Ample Margin of safety Safety ANPRM advance notice of proposed rulemaking ATSDR Agency for Toxic Substan ces and Disease Registry BACT best available control technology BLDS bag leak detection system CAA Clean Air Act CBI Confidential Business Information CEMS continuous emissions monitoring system CFR Code of Federal Regulations COS c arbonyl Carbonyl sulfide CTE central tendency exposure EJ environmental justice*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 8 of 14 9
EPA Environmental Protection Agency ERP G Emergency Response Planning Guidelines ERT Electronic Reporting Tool HAP hazardous air pollutants HEM

- 3 Human Exposure Model, Version 3 HEPA high efficiency particulate air HHRAP Human Health Risk Assessment Protocols HI Hazard Index HQ Hazard Quotient ICR information collection request IRIS Integrated Risk Information System Km kilometer LAER lowest achievable emissions rate lb/yr pounds per year MACT maximum achievable control technology MACT Code Code within the NEI used to identify processes included

in a source category MDL method detection level mg/acm milligrams per actual cubic meter mg/dscm milligrams per dry standard cubic meter mg/m 3 milligrams per cubic meter MIR maximum individual risk MRL minimum risk level NAC/AEGL Committee National Adviso ry Committee for Acute Exposure Guideline

Levels for Hazardous Substances NAICS North American Industry Classification System NAS National Academy of Sciences NATA National Air Toxics Assessment NEI National Emissions Inventory NESHAP National Emissions St andard s for Hazardous Air Pollutants NOAEL no observed adverse effects level NRC National Research Council NTTAA National Technology Transfer and Advancement Act O&M operation and maintenance OAQPS Office of Air Quality Planning and Standards ODW Office of Drinking Water OECA Office of Enforcement and Compliance Assurance OHEA Office of Health and Environmental Assessment*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 9 of 149
OMB Office of Management and Budget PB

- HAP hazardous air pollutants known to be persistent and bio

accumulative in the environment PM particulate matter POM polycyclic organic matter ppmv parts per million volume RACT reasonably available control technology RBLC RACT/BACT/LAER Clearinghouse REL reference exposure level RFA Regulatory Flexibility Act RfC reference concentration RfD refere nce dose RIA Regulatory Impact Analysis RTR residual risk and technology review SAB Science Advisory Board SBA Small Business Administration SCC Source Classification Codes SOP standard operating procedures SSM startup, shutdown , and malfunction TEQ toxic equivalency quotient TOSHI target organ

- specific hazard index TPY tons per year TRIM Total Risk Integrated Modeling System TTN Technology Transfer Network UF uncertainty factor μg/m 3 microgram per cubic meter UL upper limit UMRA Unfunded Mandates Reform Act UPL upper predictive limit URE unit risk estimate WHO World Health Organization WWW worldwide web Organization of this Document
. The information in this preamble is organized as follows: I. General Information A. What is the statutory authority for this action? B. Does this action a pply to me?*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 10 of 149 C. Where can I get a copy of this document and other related information? D. What should I consider as I prepare my comments for the EPA ? II. Background A. What is this source category and how did the MACT standard regulate its HAP emissions? B. What data collection activities were conducted to support this action? III. Analyses Performed A. How did we address unregulated emission sources ? B. How did we estimate risks posed by the source category? C. How did we co nsider the risk results in making decisions for this proposal? D. How did we perform the technology review? E. What other issues are we addressing in this proposal? IV. Analytical Results and Proposed Decisions A. What are the results of our analyses and proposed decisions regarding unregulated emissions sources? B. What are the results of the risk assessments? C. What are our proposed decisions regarding risk acceptability and ample margin of safety? D. What are the results and proposed decisions based on our technology review? E. What other actions are we proposing? F. Compliance dates V. Summary of Cost, Environmental, and Economic Impacts A. What are the affected sources? B. What are the air quality impacts? C. What are the cost impacts? D. What are the economic impacts? E. What are the benefits? VI. Request for Comments VII. Submitting Data Corrections VIII. Statutory and Executive Order Reviews A. Executive Order 12866: Regula tory Planning and Review and Executive Order 13563: Improving Regulation and Regulatory Review B. Paperwork Reduction Act C. Regulatory Flexibility Act D. Unfunded Mandates Reform Act E. Executive Order 13132: Federalism F. E xecutive Order 13175: Consultation and Coordination with Indian Tribal Governments*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 11 of 149
G. Executive Order 13045: Protection of Children from Environmental Health Risks and Safety Risks H. Executive Order 13211: Actions Concerning Regulations That Significantly Affect Energy Supply, Distribution, or Use I. National Technology Transfer and Advancement Act J. Executive Order 12898: Federal Actions to Address Environmental Justice in Minority Populations and Low

- Income Populations
I . General Information
A. What is the statutory authority for this action?
Se ction 112 of the CAA establishes a two

- stage regulatory process to address emissions of hazardous air pollutants (H AP ) from stationary sources
. In the first stage, after the EPA has identified categories of s ources emitting one or more of the HAP listed in section 112(b) of the CAA, section 112(d) of the CAA calls for us to promulgate national emission standards for hazardous air pollutants ( NESHAP ) for those sources
. ―Major sources‖ are those that emit or have the potential to emit (PTE) 10 tons per year (tpy) or more of a single HAP or 25 tpy or more of any combination of HAP
. For major sources, these technology

- based standards must reflect the maximum degree of emission reductions of HAP achievable (after considering

cos t, energy requirements and non air quality health and environmental impacts) and are commonly referred to as maximum achievable control technology (MACT) standards.
MACT standards are to reflect application of measur es, processes, methods, s ystems or techniques including, but no t limited to, measures which (1 ) reduce the volume of or eliminate emissions of pollutants through process changes, substitution of mate rials or*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 12 of 149 other modifications, (2 ) enclose systems or proc esses to eliminate emissi ons, (3 ) capture or treat pollutants when released from a process, stack, storage or fugitive emissions point, (4 ) are d esign, equipment, work practice or operational standards (including requirements for operator t raining or certification) or (5 ) are a

co mbination of the above
. CAA section 112(d)(2)(A)

- (E)
. The MACT standard may take the form of a d esign, equipment, work practice or operational standard where the EPA first determines that either (1 ) a pollutant cannot be emitted through a conveyance design ed and constructed t o emit or capture the pollutant or that any requirement for , or use of , such a conveyance would be inconsistent with law , or (2 ) the application of measurement methodology to a particular class of sources is not practicable due to techn ological and economic limitations
. CAA sections 112(h)(1)

- (2)
. The MACT ―floor‖ is the minimum control level allowed for MACT standards promulgated under CAA section 112(d)(3) and may not be based on cost considerations
. For new sources, the MACT floor can not be less stringent than the emission control that is achieved in practice by the best

- controlled similar source
. The M ACT floors for existing sources can be less stringent than floors for new sources, but they cannot be less stringent than the average e mission limitation achieved by the best

- performing 12 percent of existing sources in the category or subcategory (or the best

- performing five sources for categories or subcategories with fewer than 30 sources)
.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 13 of 149 In developing MACT standards, we must also co nsider control options that are more stringent than the floor
. We may establish standards more stringent than the floor (―beyond the floor‖ standards) based on the consideration of the cost of achieving th e emissions reductions and any non air quality healt h and environmental impacts and energy requirements. No beyond the floor standards are proposed in this rulemaking action. The EPA is then required to review these technology

- based standards and to revise them ―as necessary (taking into account development s in practices, processes, and control technologies)‖ no less frequently than every 8 years, under CAA section 112(d)(6)
. In conducting this review, the EPA is not obliged to completely recalculate the prior MACT determination
. NRDC v. EPA , 529 F.3d 1077, 1084 (D .C. Cir
. 2008)
. The second stage in standard

- setting focuses on reducing any remaining ―residual‖ risk according to CAA section 112(f)
. This provision requires, first, that the EPA prepare a Report to Congress discussing (among other things) methods of calculating risk posed (or potentially posed) by sources after implementation of the MACT standards, the public health significance of those risks, and the EPA‘s recommendations as to legislation regarding such remaining risk . The EPA prepared and subm itted this report ( Residual Risk Report to Congress , EPA

– 453/R

– 99

– 001) in March 1999
. Congress did not act in response to the report, thereby triggering the EPA‘s*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 14 of 149 obligation under CAA section 112(f)(2) to analyze and address residual risk.
CAA section 112( f)(2) requires us to determine , for source categories subject to MACT standards, whether the emissions standards provide an ample margin of safety to protect public health
. If the MACT standards for HAP ―classified as a known, probable, or possible
human c arcinogen do not reduce lifetime excess cancer risks to the individual most exposed to emissions from a source in the category or subcategory to less than 1

- in

- 1 million,‖ the EPA must promulgate residual risk standards for the source category (or subcateg ory) , as necessary , to provide an ample margin of safety to protect public health
. In doing so, the EPA may adopt standards equal to existing MACT standards if the EPA determines that the existing standards are sufficiently protective
. NRDC v. EPA , 529 F.3 d 1077, 1083 (D .C. Cir. 2008)
. (―If EPA determines that the existing technol ogy - based standards provide an ―ample margin of safety,‖ then the a gency is free to readopt those standards during the residual risk rulemaking.‖) The EPA must also adopt more stri ngent standards, if necessary, to prevent an adverse environmental effect 1 but mus t consider cost, energy, safety and other relevant factors in doing so
.

1 ―Adverse environmental effect‖ is defined in CAA section 112(a)(7) as any significant and widespread adverse effect, which may be reasonably anticipated to wildlife, aquatic life or natural resources, including adverse impacts on populations of endangered or threatened species or significant degradation of environmental qualities over broad areas.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 15 of 149 Section 112(f)(2) of the CAA expressly preserves our use of a
two

- step process for developing standard s to address any residual risk and our interpretation of ―ample margin of safety‖ developed in
the National Emission Standards for Hazardous Air Pollutants : Benzene Emissions from Maleic Anhydride Plants, Ethylbenzene/Styrene Plants, Benzene Storage Vessels, Benzene Equipment Leaks, and Coke By

- Product Recovery Plants (Benzene NESHAP) (54 FR 38044, September 14, 1989)
. The first step in this process is the determination of acceptable risk
. The second step provides for an ample margin of safety to prot ect public health, which is the level at which the standards are set (unless a more stringent standard is required to prevent, taking into consideration costs, energy, safety, and other relevant factors, an adverse environmental effect). The terms ―individ ual most exposed,‖ ―acceptable level,‖ and ―ample margin of safety‖ are not specifically defined in the CAA
. However, CAA section 112(f)(2)(B) preserves the interpretation set out in the Benzene NESHAP, and the U nited States Court of Appeals for the D istri ct of Columbia Circuit in NRDC v. EPA , 529 F.3d 1077, concluded that the EPA‘s interpretation of subsection 112(f)(2) is a
reasonable one
. See NRDC v. EPA , 529 F.3d at 1083 (―[S]ubsection 112(f)(2)(B) expressly incorporates the EPA ‘s interpretation of the Clean Air Act from the Benzene standard, complete with a citation to the Federal Register ‖)
. (D .C. Cir. 2008)
. See also, A Legislative History of the Clean Air Act Amendments of 1990 , volume 1, p. 877*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 16 of 149 (Senate debate on Conference Report)
. We notified Congr ess in the Residual Risk Report to Congress that we intended to use the Benzene NESHAP approach in making CAA section 112(f) residual risk determinations (EPA

– 453/R

– 99

– 001, p. ES

– 11). In the Benzene NESHAP, we stated as an overall objective: * * * in prote cting public health with an ample margin of safety, we strive to provide maximum feasible protection against risks to health from hazardous air pollutants by , (1) protecting the greatest number of persons possible to an individual lifetime risk level no hi gher than approximately 1

- in

- 1 million; and (2) limiting to no higher than approximately 1

- in

- 10 thousand [ i.e. , 100

- in

- 1 million] the estimated risk that a person living near a facility would have if he or she were exposed to the maximum pollutant concent rations for 70 years. The a gency also stated that, ―The EPA also considers incidence (the number of persons estimated to suffer cancer or other serious health effects as a result of exposure to a pollutant) to be an important measure of the health risk to the exposed population
. Incidence measures the extent of health risk to the exposed population as a whole, by providing an estimate of the occurrence of cancer or other serious health effects i n the exposed population.‖
The a gency went on to conclude that ―estimated incidence would be weighed along with other health risk information in judging acceptability.‖ As explained more fully in our Residual Risk Report*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 17 of 149 to Congress , the EPA does not define ―rigid line[s] of acceptability,‖ but considers rather broad objectives to be weighed with a series of other health measures and factors (EPA

– 453/R

– 99

– 001, p. ES

– 11)
. The determination of what represents an ―acceptable‖ risk is based on a judgment of ―what risks are acceptable in the world in which we live‖ ( Residua l Risk Report to Congress , p. 178, quoting the Vinyl Chloride decision at 824 F.2d 1165) recognizing that our world is not risk

- free. In the Benzene NESHAP, we stated that ―EPA will generally presume that if the risk to [the maximum exposed] individual is no higher than approximately 1

- in

- 10 thousand, that risk level is considered acceptable.‖ 54 FR 38045
. We discussed the maximum individual lifetime cancer risk (or maximum individual risk (MIR)) as being ―the estimated risk that a person living near a plan t would have if he or she were exposed to the maximum pollutant concentrations for 70 years.‖ Id
. We explained that this measure of risk ―is an estimate of the upper bound of risk based on conservative assumptions, such as continuous exposure for 24 hours per day for 70 years.‖ Id
. We acknowledge that maximum individual lifetime cancer risk ―does not n ecessarily reflect the true risk, but displays a conservative risk level which is an upper

- bound that is unlikely to be exceeded.‖ Id
. Understanding that there are both benefits and limitations to using maximum individual lifetime cancer risk as a metric f or*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 18 of 149 determining acceptability, we acknowledged in the 1989 Benzene NESHAP that ―consideration of maximum individual risk * * * must take into account the strengths and weaknesses of this measure of risk.‖ Id. Consequently, the presumptive risk level of 100

- in

- 1 million (1

- in

- 10 thousand) provides a benchmark for judging the acceptability of maximum individual lifetime cancer risk, but does not constitute a rigid line for making that determination
. The a gency also explained in the 1989 Benzene NESHAP the foll owing : ―In establishing a presumption for MIR, rather than a rigid line for acceptability, the a gency intends to weigh it with a series of other health measures and factors
. These include the overall incidence of cancer or other serious health effects with in the exposed population, the numbers of persons exposed within each individual lifetime risk range and associated incidence within, typically, a 50

- kilometer (km) exposure radius around facilities, the science policy assumptions and estimation uncertaint ies associated with the risk measures, weight of the scientific evidence for human health effects, other quantified or unquantified health effects, effects d ue to co

- location of facilities and co

- emission of pollutants.‖ Id. In some cases, these health mea sures and factors taken together may provide a more realistic description of the magnitude of risk in the exposed population than that provided by maximum individual lifetime cancer risk alone
. As explained in the Benzene NESHAP,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 19 of 149 ―[e]ven though the risks j udged ―acceptable‖ by the EPA in the first step of the Vinyl Chloride inquiry are already low, the second step of the inquiry, determining an ―ample margin of safety,‖ again includes consideration of all of the health factors, and whether to reduce the ris ks even further.‖ In the ample margin of safety decision process, the a gency again considers all of the health risks and other health information considered in the first step
. Beyond that information, additional factors relating to the appropriate level of control will also be considered, including costs and economic impacts of controls, technolog ical feasibility, uncertainties and any other relevant factors
. Considering all of these factors, the a gency will establish the standard at a level that provides a n ample margin of safety to protect the public health, as required by CAA section 112(f)
. 54 FR 38046. As discussed in the previous section of this preamble, we apply
a two

- step process for developing standards to address residual risk
. In the first step, the EPA determines whether risks are acceptable
. This determination ―considers all health information, including risk estimation uncertainty, and includes a presumptive limit on maximum individual lifetime [cancer] risk (MIR) 2 of approximately 1

- in

- 10 thou sand [ i.e. , 100

- in

- 1 million].‖ 54 FR 38045
. In the second step of the process, the EPA sets the standard at a level that provides an

2 Although defined as ―maximum individual risk,‖ MIR refers only to cancer risk. MIR , one metric for assessing cancer risk, is the estimated risk were an individual exposed to the maximum level of a pollutant for a lifetime.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 20 of 149 ample margin of safety ―in consideration of all health information, including the number of persons at risk levels higher than approximately 1

- in

- 1 million, as well as other relevant factors, including cost s and economic impacts, technological feasibility, and other factors relevant to each particular decision.‖ Id. In past residual risk determinations, the EPA presented a number of human health risk metrics associated with emissions from the category under review, including : t he MIR; the numbers of persons in various risk ranges; cancer inciden ce; the maximum non cancer hazard index (HI); and the maximum acute non cancer hazard
. In estimating risks, the EPA considered source categories under review that are lo cated near each other and that affect the same population . The EPA provided estimates of the expected difference in actual emissions from the source category under review and emissions allowed pursuant to the source category MACT standard . The EPA also dis cussed and considered risk estimation uncertainties . The EPA is providing this same type of information in support of these actions. The a gency acknowledges that the Benzene NESHAP provides flexibility regarding what factors the EPA might consider in makin g our determinations and how they might be weighed for each source category . In responding to comment on our policy under the Benzene NESHAP, the EPA explained that : ―The policy chosen by the Administrator permits consideration of multiple measures of heal th risk
. Not only can the MIR figure be considered, but also incidence,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 21 of 149 the presence of noncancer health effects, and the uncertainties of the risk estimates
. In this way, the effect on the most exposed individuals can be reviewed as well as the impact on the general public
. These factors can then be weighed in each individual case
. This approach complies with the Vinyl Chloride mandate that the Administrator ascertain an acceptable level of risk to the public by employing [her] expertise to assess availabl e data
. It also complies with the Congressional intent behind the CAA, which did not exclude the use of any particular measure of public health risk from the EPA's consideration with respect to CAA section 112 regulations, and, thereby, implicitly permits consideration of any and all measures of health risk which the Administrator, in [her] judgment, believes are appropriate to determining what will  ̳protect the public health.‘‖
F o r example, the level of the MIR is only one factor to be weighed in determini ng acceptability of risks
. The Benzene NESHAP explains ―an MIR of approximately 1

- in

- 10 thousand should ordinarily be the upper end of the range of acceptability
. As risks increase above this benchmark, they become presumptively less acceptable under
CAA s ection 112, and would be weighed with the other health risk measures and information in making an overall judgment on acceptability
. Or, the a gency may find, in a particular case, that a risk that includes MIR less than the presumptively acceptable level i s unacceptable in the light of other health risk factors.‖ Similarly, with regard to the ample margin of safety analysis, the*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 22 of 149
Benzene NESHAP states that : ― EPA believes the relative weight of the many factors that can be considered in selecting an ample mar gin of safety can only be determined for each specific source category
. This occurs mainly because technological and economic factors (along with the health

- related factors) vary from source category to source category.‖
B. Does this action apply to me?
Th e regulated industrial source category that is the subject of this proposal is listed in Table 2 of this preamble. Table 2 of this preamble is not intended to be exhaustive, but rather provides a guide for readers regarding the entities likely to be affect ed by this proposed action. Th ese standard s , once finalized, will be directly applicable to affected sources. Federal, S tate, local, and tribal government entities are not affected by this proposed action. As defined in the source category list ing report p ublished by the EPA in 1992, the Primary Aluminum Reduction Plant source category is defined as any facility which produced primary aluminum by the electrolytic reduction process.
Table 2
. N ESHAP and Industrial Source Categories Affected b y t his By This Proposed Action Source Category NESHAP NAICS code 1 MACT

code 2 Primary Aluminum Reduction Plants Primary Aluminum Reduction Plants 331312 0023

1 North American Industry Classification System 2 Maximum Achievable Control Technology*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 23 of 149 C. Where can I get a copy of this document and other related information ? In addition to being available in the docket, an electronic copy of this proposal will also be available on the World Wide Web (WWW) through the EPA‘s Technology Transfer Network (TTN). Following signa ture by the EPA Administrator, a copy of this proposed action will be posted on the TTN‘s policy and guidance page for newly proposed or promulgated rules at the following address: http://www.epa.go v/ttn/atw/rrisk/rtrpg.html . The TTN provides information and technology exchange in various areas of air pollution control. Additional information is available on the residual risk and technology review (RTR) webpage at : http://www.epa.gov/ttn/atw/rrisk/rtrpg.html . This information includes source category descriptions and detailed emissions estimates and other data that were used as inputs to the risk
assessments. D. What should I consider as I prep are my comments for the EPA ? Submitting CBI . Do not submit information containing CBI to the EPA through http:// www.regulations.gov or email. Clearly mark the part or all of the information that you claim to be CBI. For CBI information on a disk or CD ROM that you mail to the EPA , mark the outside of the disk or CD ROM as CBI and then identify electronically within the disk or CD ROM the specific information that is claimed as*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 24 of 149 CBI. In addition to one complete version of the comment that includes information claimed as CBI, a copy of the comment that does not contain the information claimed as CBI must be submitted for inclusion in the public docket. If you submit a CD ROM or disk that does not contain CBI, mark the ou tside of the disk or CD ROM clearly that it does not contain CBI. Information not marked as CBI will be included in the public docket and the EPA ‘s electronic public docket without prior notice. Information marked as CBI will not be disclosed except in acc ordance with procedures set forth in 40 CFR part 2. Send or deliver information identified as CBI only to the following address: Roberto Morales, OAQPS Document Control Officer (C404

- 02), Office of Air Quality Planning and Standards, U.S. Environmental
Pro tection Agency, Research Triangle Park, North Carolina 27711, Attention Docket ID Number EPA

- HQ

- OAR

- 2011

- 0797
. II. Background
A. What is this source category and how did the MACT standard regulate its HAP emissions? The NESHAP (or MACT rule ) for the Primary Aluminum Reduction Plants was w ere promulgated on October 7, 199 7 (62 FR 52407) and

amen d ed on November 2, 2005 (70 FR 66285). The rule is applicable to facilities with affected sources associated with the production of aluminum by electrolytic red uction. Aluminum is produced from refined bauxite ore (also known as alumina) , using an electrolytic reduction process in a series of cells called a ―potline
. ‖ The raw materials*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 25 of 149 include alumina, coke, pitch and fluoride salts
. A ccording to information avai lable on the website of The Aluminum Association, Inc. ( www.aluminum.org ) a pproximately Approximately 50 percent of the aluminum produced in the U.S. comes from primary aluminum facilities
. The two main potline types are prebake (a newer, higher efficiency, lower

- emitting technology) and Soderberg (an older, lower efficiency, higher

- emitting technology)
. There are currently 15 facilities located in the United States that are subject to the re quirements of this NESHAP: 14 primary aluminum production plants and one carbon

only prebake anode production facility . The se 14 primary aluminum production plants have approximately 53 potlines that produce aluminum . E ach plant has a paste production oper ation, and 1 2 of the 14 plants have anode bake furnaces. Twelve of the 14 facilities utilize prebake potlines; the other 2 utilize Soderberg potlines
. According to The Aluminum Association , Inc., due to a decrease in demand for aluminum , f our Four of the 14 facilities are currently idle , including 1 Soderberg facility
. The major HAPs emitted by these facilities are carbonyl sulfide (COS), hydrogen fluoride ( HF ), and polycyclic organic matter ( POM ) , specifically polycyclic aromatic hydrocarbons (PAH )
. The standard s promulgated in 199 7 and 2005 appl y to emissions of HF, measured using total fluorides (TF) as a surrogate, from all potlines and anode bak e furnaces and POM (as measured by methylene chloride extractables) from Soderberg potlines, anode ba ke furnaces,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 26 of 149 paste production plants and pitch storage tanks associated with primary aluminum reduction. Affected sources under the rules are each potline, each anode bake furnace (except for one that is located at a facility that only produces anodes for use off

- site) , each paste production plant , and each new pitch storage tank. The NES H AP designated seven subcategories of existing potlines based primarily on differences in the process operation and configuration. The control of primary emissions from the reduction process is typically achieved by the installation of a dry alumina scrubber ( with a baghouse to collect the alumina and other particulate matter )
. The MACT control technology typically used for anode bake furnaces is a dry alumina scrubber, and a capture system vented to a dry coke scrubber is used for control of paste production plants
. See Table 3 for the emission limits.
T able 3
. Summary of Current MACT Emission Limits for Existing S ources under Under the 1997 NESHAP , and the 2005 Amendments
.
Source Pollutant Emission Limit Potlines 1 CWPB1 potlines CWPB2 potlines CWPB3 potlines SWPB potlines VSS1 potlines

VSS 2 potlines
HSS potlines TF TF TF TF TF POM TF POM TF POM 0.95 kg/Mg (1.9 lb/ton) of aluminum produced

1.5 kg/Mg (3.0 lb/ton) of aluminum produced 1.25 kg/Mg (2.5 lb/ton) of aluminum produced 0.8 kg/Mg (1.6 lb/ton) of aluminum produced 1.1 kg/Mg (2.2 lb/ton) of aluminum produced 1.2 kg/Mg ( 2.4 lb/ton) of aluminum produced 1.35 kg/Mg (2.7 lb/ton) of aluminum produced 2.85 kg/Mg ( 5.7 lb/ton) of aluminum produced 1 .35 kg/Mg (2.7 lb/ton) of aluminum produced 2.35 kg/Mg ( 4 .7 lb/ton) of aluminum produced Paste Production POM Install, operate, and maintain equipment for capture of emissions and vent to a dry coke*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 27 of 149

scrubber Anode Bake Fur na ce (collocated with a primary aluminum plant) TF POM 0.10 kg/Mg (0.20 lb/ton) of green anode

0.09 kg/Mg (0.18 lb/ton) of green anode

1 CWPB1=Center

- worked prebake potline with the most modern reduction cells; includes all center

- worked prebake potlines not specifically identified as CWPB2 or CWPB3. CWPB2=Center

- worked prebake potlines located at Alcoa in Rockdale, Texas; Kaiser Aluminum in Mead, Washington; Ormet C orporation in Hannibal, Ohio; Ravenswood Aluminum in Ravenswood, West Virginia; Reynolds Metals in Troutdale, Oregon; and Vanalco Aluminum in Vancouver, Washington. CWPB3=Center

- worked prebake potline that produces very high purity aluminum, has wet scrubb ers as the primary control system, and is located at the primary aluminum plant operated by NSA in Hawesville, Kentucky. HSS=Horizontal stud Sod erberg potline. SWPB=Side

- worked prebake potline. VSS1=Vertical stud Soderberg potline at Northwest Aluminum in The Dalles, Oregon, or at Columbia Aluminum in Goldendale, Washington. VSS2=Vertical stud Soderberg potlines at Columbia Falls Aluminum in Columbia Falls, Montana. Table 4
. Summary of Current MACT Emission Limits for New Sources under Under the 1997 NESHAP and 2005 Amendments

Source Pollutant Emission Limit
All Potlines TF 0. 6 kg/Mg ( 1.2 lb/ton) of aluminum produced

VSS1, VSS2, and HSS potlines POM 0.32 kg/Mg (0.63 lb/ton) of aluminum produced

Paste Production POM Install, operate, and maintain equipment for capture of emissions and vent to a dry coke scrubber Anode Bake Fur nace (co l located with a primary aluminum plant) TF POM 0. 01 kg/Mg (0. 02 0 lb/ton) of green anode

0. 025 kg/Mg (0. 05 lb/ton) of green anode
Pitch storage tanks POM Emission control system designed and operated to reduce inlet emissions by 95 percent or greater.
The 1997 NESHAP for primary aluminum reduction plants incorporates new source performance standards for potroom groups ; these emission limits are listed in Table 4. The limits for new Soderberg facilities apply to any Soderber g facility that adds a new potroom group to an existing potline or is associated with a potroom Formatted: Line spacing: single*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 28 of 149 group that meets the definition of a modified or reconstructed potroom group. Since these POM limit s are very stringent, they effectively preclude the operation of any new Soderberg potlines. Compliance with the emission limits in the current rule is demonstrated by performance testing which can be addressed individually for each affected source or acco rding to emissions averaging provisions. Monitoring requirements include monthly
measurements of TF secondary emissions , quarterly measurement of POM secondary emissions an d annual measurement of primary emissions, continuous parameter monitoring for each emission control device, a monitoring device to track daily weight of aluminum produced, daily inspection for visible emissions, and daily inspection of wet roof scrubbers. Recordkeeping for the rule is consistent with the General Provisions requirements w ith the addition of recordkeeping for daily production of aluminum, records supporting emissions averaging and records documenting the portion of TF measured as particulate matter or gaseous form. B. What data collection activities were conducted to suppor t this action? For the Primary Aluminum Reduction Plant source category, we compiled a preliminary dataset using available information, reviewed the data, and made changes where necessary. The preliminary dataset was based on data in the 2002 National Emis sions Inventory (NEI) Final Inventory, Version 1 (made publicly available on February 26,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 29 of 149 2006), and the 2005 National Emissions Inventory (NEI), version 2.0 (made publicly available in October 2008). The NEI is a database that contains information about s ources that emit criteria air pollutants, their precursors, and HAP. The NEI database includes estimates of annual air pollutant emissions from point and volume sources, emission release characteristic data such as height, velocity, temperature and locatio n latitude/longitude coordinates. We reviewed the NEI datasets, corrected geographic coordinates and stack parameters in consultation with the facilities , and made changes based on available information. We also reviewed the emissions and other data to identify data anomalies that could affect risk estimates. The 2005 NEI was then updated to develop the 2005 National Air Toxics Assessment (NATA) Inventory. Subsequently, in April 2011, we received test data and other information through an Information Col lection Request (ICR) from 11 of the 15 facilities in the source category. These ICR data were then used along with the 2005 NATA inventory data t o develop the emissions dataset for this source category , which includes our best estimates of actual emission s of HAP for the facilities. This dataset was then used in the risk modeling analyses t o estimate the risks due to actual emissions for the source category. POM emissions were allocated to specific POM compounds on the basis of the fractional contributions of these compounds to the actual POM emissions, as determined (as appropriate) from an average*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 30 of 149 of test data for two prebake potlines and an average of data from two Soderberg facilities. Based on knowledge of the industry and previous testing , we could re asonably expect emissions of approximately 23 POM speci fic POM compounds from primary aluminum production facilities. The allocation incorporated POM emissions at 50 percent of the detection limit for those compounds ―reported as below detection limit
. ‖ Th e use of 50 percent of the detection limit is more conservative than assuming that these compounds were not present; an assumption that the compounds were present at the detection limit would be an overestimation. The assumption that these compounds were
p resent at 50 percent of the detection limit represented the midpoint of two extreme options. For Soderberg potline stacks , six out of 38 measurements were below the detection limit. For Soderberg potroom roof vents, 10 out of 38 measurements were below the detection limit. For prebake potline stacks , 21 out of 38 measurements were below the detection limit. For prebake potroom roof vents, 25 out of 38 measurements were below the detection limit.
To estimate allowable emissions, we analyzed the emissions data gathered from the 2002 NEI, the 2005 NEI and responses to the ICR described above. Based on that analysis, we estimated that allowable emissions were generally about 1.5 t imes higher than actual emissions
. Therefore, to calculat e allowable emissions we assumed that allowable emissions were 1.5 times greater than actual emissions for all facilities except for one idle Soderberg facility (Columbia*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 31 of 149 Falls)
. For Columbia Falls, which has the highest potential for emissions of all the facilities, we evaluated site

- specific data and estimated that allowable emissions were about 1. 9 times higher than actual emissions. 1.8 times higher than actual emissions. The POM emissions were then allocated to specific compounds on the basis of the fra ctional contributions of these compounds to the actual POM emissions, as determined from an average of test data from two Soderberg facilities. The allocation incorporated POM emissions at 50 percent of the detection limit for those compounds for which

mea surements were below the detection limit
. A ctual e missions of COS for the industry are estimated to be about 4 , 400 tons per year ( tpy ) , with an average of about 330 tons per facility
. Actual emissions of HF are estimated to be about 1 , 900 tpy with an average of about 160 tpy per facility . Estimated emissions of speciated compounds of POM were much lower. Estimated actual e missions of identified POM species totaled approximately 180 tpy for the industry
. Moreover, POM emissions are much higher from Soderberg facilities compared to prebake facilities. The average POM emissions from prebake facilities are about 4.5 tpy per facility , and the average POM emissions for Soderberg facilities are about 60 tpy per facility
. We estimate that a pproximately one - third of the emissions of POM for both types of potrooms come from the control device stack , and the remainder are secondary emissions emitted from potroom vents. This estimate is based on a summary of emissions*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 32 of 149 derived from reports of emission testin g conducted at two prebake facilities and two Soderberg facilities (―Industry Review of Draft POM Speciation and Emissions Data,‖ December 19, 2007). fugitives emitted from potroom vents. The emissions data, calculations and risk assessment inputs for the P rimary Aluminum Reduction Plant source catego ry are described further in D raft D evelopment of the RTR Emissions Dataset for the Primary Aluminum Pro duction Source Category which is available in the docket for this proposed rulemaking. III. Analyses Performed In this section we describe the analyses performed to support the proposed decisions for the RTR for this source ca tegory.
A. How did we address u nregulated e missions s ources ?
I n the course of evaluating the Primary Aluminum Reduction Plant

sourc e category, we identified certain HAP for which we failed to establish emission standards in the original MACT. See National Lime
v. EPA , 233 F. 3d 625, 634 (D.C. Cir. 2000) ( the EPA has ―clear statutory obligation to set emissions standards for each liste d HAP‖).
W e evaluated establishing emissions limits for COS for the source category and for POM for various emissions points that had not been regulated in the 1997 MACT rule or in the 2005 amendments
. S ection 112(d)(3) (B) of the CAA requires that the MACT standards for existing sources be at least as stringent as the average emissions*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 33 of 149 limitation achieved by the best performing five sources (for which the Administrator has or could reasonably obtain emissions information) in a category with fewer than 30 sources. The Primary Aluminum source category con sists of fewer than 30 sources. The EPA must exercise its judgment, based on an ev aluation of the relevant factors and available data, to determine the level of emissions control that has been achieved by the best performing sources under variable conditions. It is recognized in the case law that the EPA may consider variability in esti mating the degree of emissions reduction achieved by best

- performing sources and in setting MACT floors. See Mossville Envt ‘ l Action Now v. EPA , 370 F.3d 1232, 1241

– 42 (D.C. Cir 2004) (holding that the EPA may consider emissions variability in estimating p erformance achieved by best

performing sources and may set the floor at a level that a best

performing source can expect to meet ― every day and under all operating conditions ‖ ). More details on how we calculate MACT floors and how we account for variabilit y are described in the Draft MACT Floor Analysis for the Primary Aluminum Source Category which is available in the docket for this proposed action
. C arbonyl sulfide (COS) was not regulated in the 1997 NESHAP or in the 2005 amendments for Primary Aluminum Reduction Plant s . In this action we analyzed the available data and evaluated options for developing MACT standards for this HAP
. As mentioned above , COS is the HAP emitted in largest quantities
. Based on all our analyses,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 34 of 149 which are described in section IV.A of this preamble , we concluded that establishing a standard based on a mass balance equation would be the most appropriate approa c h. Therefore, we are proposing MACT standards for COS in today‘s action based on use of a mass balance equation to deriv e COS emissions based on data on anode coke sulfur content, anode consumption and aluminum production
. . Polycyclic organic matter ( POM ) emissions from prebake potlines

were also not regulated in th e 1997 NESHAP or in the 2005 amendments. We are proposing M ACT limits for new and existing prebake potlines in today‘s action based on available data. Finally, the 1997 NESHAP included MACT standards for new pitch storage tanks, which required a 95 percent reduction in emissions. However, the rule had no limits fo r existing storage tanks. We are proposing that existing tanks will be subject to the same standard ( i.e. , minimum of 95 percent reduction of POM emissions)
. for these tanks. At least three facilities are currently achieving this level of control on existing tanks
. . F urther details about the analyses, t he results and proposed decisions regarding the proposed MACT limits pursuant to CAA section 112(d)(2) and 112(d)(3) are presented in section IV.A of this preamble.
B . How did we estimate risks pose d by the source category ? The EPA conducted risk assessments that provided estimates of the M I R posed by the HAP emissions for each source in the category ,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 35 of 149 the HI for chronic exposures to HAP with the potential to cause noncancer health effects, and the h azard quotient ( HQ ) for acute exposures to HAP with the potential to cause noncancer health effects. The assessments also provided estimates of the distribution of cancer risks within the expose d populations, cancer incidence and an evaluation of the poten tial for adverse environmental effects for each source category. The risk assessments consisted of seven primary steps, as discussed below. The docket for this rulemaking contains the following document which provides more information on the risk

assessmen t inputs and models: Draft Residual Risk Assessment for the Primary Aluminum Reduction Plant Source Categor y . The methods used to assess risks (as described in the seven primary steps below) are consistent with those peer

- reviewed by a panel of the EPA‘s Science Advisory Board (SAB) in 2009 and described in their peer review report issued in 2010 3 ; they are also consistent with the key recommendations contained in that report. 1. Establishing the nature and magnitude of actual emissions and identifying the emissions release c haracteristics As discussed in s ection II.B of this preamble, we used a dataset consisting of based on the estimated actual and allowable emissions as the basis for the risk assessment. In addition to the quality

3 U.S. EPA SAB. Risk and Technology Review (RTR) Risk Assessment Methodologies: For Review by the EPA‘s Science Adv isory Board with Case Studies

– MACT I Petroleum Refining Sources and Portland Cement Manufacturing , May 2010.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 36 of 149 assurance ( QA ) of th e emissions and associated parameters facilities contained in the dataset, we also checked the coordinates of every facility in the dataset through visual observations using tools such as Google Earth and ArcView. Where coordinates were found to be incorrec t, we identified and corrected them to the extent possible. We also performed QA of the emissions data and release characteristics to ensure there were no outliers. 2. Establishing the relationship between actual emissions and MACT

allowable emissions l evels The available emissions data in the MACT dataset include estimates of the mass of HAP actually emitted during the specified annual time period. These ―actual‖ emission levels are often lower than the emission levels that a facility might be allowed t o emit and still comply with the MACT standards. The emissions level allowed to be emitted by the MACT standards is referred to as the ―MACT

allowable‖ emissions level. This represents the highest emissions level that could be emitted by the facility witho ut violating the MACT standards. We discussed the use of both MACT

- allowable and actual emissions in the final Coke Oven Batteries residual risk rule (70 FR 19998

– 19999, April 15, 2005) and in the proposed and final Hazardous Organic NESHAP residual risk r ules (71 FR 34428, June 14, 2006, and 71 FR 76609, December 21, 2006, respectively). In those previous actions, we noted that assessing the risks at the MACT

- allowable*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 37 of 149 level is inherently reasonable since these risks reflect the maximum level sources could emit and still comply with national emission standards. But we also explained that it is reasonable to consider actual emissions, where such data are available, in both steps of the risk analysis, in accordance with the Benzene NESHAP. (54 FR 38044, Septe mber 14, 1989.) Further explanation is provided in the document Draft
D evelopment of the RTR Emissions Dataset for the Primary Aluminum Production Source Category which is available in the docket for this proposed rulemaking. 3. Conducting dispersion model ing , determining inhalation exposures and estimating i ndividual and population i nhalation r isks Both long

- term and short

- term inhalation exposure concentrations and health risks from each facility in the source categor y addressed in this proposal were esti mated using the Human Exposure Model ( HEM ) (Community and Sector HEM

– 3 version 1.1.0). The HEM

– 3 performs three primary r isk assessment activities: (1) c onducting dispersion modeling to estimate the concentrations of HAP in ambient air, (2) estimating long

- term and short

- term inhalation exposures to individuals residing with in 50 km of the modeled sources and (3) estimating individual and population

- level inhalation risks using the exposure estimates and quantitative dose

- response information. The dispersion model used by HEM

– 3 is AERMOD, which is one of the EPA‘s preferred models for assessing pollutant concentrations*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 38 of 149
from industrial facilities. 4 To perform the dispersion modeling and to develop the preliminary risk estimates, HEM

– 3 draws on th ree data libraries. The first is a library of meteorological data, which is used for dispersion calculations. This library includes 1 year (1991) of hourly surface and upper air observations for more than 158 meteorological stations, selected to provide co verage of the United States and Puerto Rico. A second library of U nited States Census
Bureau census block 5 internal point locations and populations provides the basis of human exposure calculations (Census, 2000). In addition, for each census block, the ce nsus library includes the elevation and controlling hill height, which are also used in dispersion calculations. A third library of pollutant unit risk factors and other health benchmarks is used to estimate health risks. These risk factors and health benc hmarks are the latest values recommended by the EPA for HAP and other toxic air pollutants. These values are available at http://www.epa.gov/ttn/atw/toxsource/summary.html and are discussed in more detail later in this section. In developing the risk assessment for chronic exposures, we used the estimated annual average ambient air concentration of each of the HAP emitted by each source for which we have emissions data in the source category. T he air concentrations at each nearby census block

4 U.S. EPA. Revision to the Guideline on Air Quality Models: Adoption of a Preferred General Purpose (Flat and Complex Terrain) Dispersion Model and Other Revisions (70 FR 68218, November 9, 2005). 5 A census block is generally the smallest geographic area for which census statistics are tabulated.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 39 of 149 centroid were used as a surrogate for the chronic inhalation exposure concentration for all the people who reside in that census block. We calculated the MIR for each facility as the cancer risk associated with a continuous lifetime (24 hours per day, 7 days per week, and 52 weeks per year for a 70

- year period) exposure to the maximum concentration at the centroid of an inhabited census block. Individual cancer risks were calculated by multiplying the estima ted lifetime exposure to the ambient concentration of each of the HAP (in micrograms per cubic meter) by its unit risk estimate ( URE ) , which is an upper bound estimate of an individual‘s probability of contracting cancer over a lifetime of exposure to a co ncentration of 1 microgram of the pollutant per cubic meter of air. For residual risk assessments, we generally use URE values from the EPA‘s Integrated Risk Information System ( IRIS ) . For carcinogenic pollutants without the EPA IRIS values, we look to oth er reputable sources of cancer dose

- response values, often using California EPA ( CalEPA ) URE values, where available. In cases where new, scientifically credible dose

response values have been developed in a manner consistent with the EPA guidelines and ha ve undergone a peer review process similar to that used by the EPA, we may use such dose

- r esponse values in place of , or in addition to , other values, if appropriate.
P olycyclic organic matter ( POM ) , a carcinogenic HAP with a mutagenic mode of action, is emitted by the facilities in th is source*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 40 of 149 categor y . 6 For this compound group, 7 the age - dependent adjustment factors ( ADAF ) described in the EPA‘s Supplemental Guidance for Assessing Susceptibility from Early

- Life Exposure to Carcinogens 8 were applied. This adjustment has the effect of increasing the estimated lifetime risks for POM by a factor of 1.6. In addition, although only a small fraction of the total POM emissions were not reported as individual compounds, the EPA expresses carcinogenic potency for

co mpounds in this group in terms of benzo[a]pyrene equivalence, based on evidence that carcinogenic POM has the same mutagenic mechanism of action as benzo[a]pyrene. For this reason, the EPA‘s Science Policy Council 9 recommends applying the Supplemental Gui dance to all carcinogenic polycyclic aromatic hydrocarbons for which risk estimates are based on relative potency. Accordingly, we have applied the ADAF to the benzo[a]pyrene equivalent portion of all POM mixtures. Incremental individual lifetime cancer ri sks associated with emissions from the source category were estimated as the sum of the

6 U.S. EPA. Performing risk assessments that include carcinogens described in the Supplemental Guidance as having a mutagenic mode of action. Science Policy Council Cancer Guidelines Implementation Work Group Communication II : Memo from W.H. Farland, dated October 4, 2005. 7 See the Risk Assessment for Source Categories document available in the doc ket for a list of HAP with a mutagenic mode of action. 8 U.S. EPA. Supplemental Guidance for Assessing Early

- Life Exposure to Carcinogens
. EPA/630/R

- 03/003F, 2005. http://www.epa.gov/t tn/atw/childrens_supplement_final.pdf
. 9 U.S. EPA. Science Policy Council Cancer Guidelines Implementation Workgroup Communication II : Memo from W.H. Farland, dated June 14, 2006.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 41 of 149 risks for each of the carcinogenic HAP (including those classified as carcinogenic to humans, likely to be carcinogenic to humans and suggestive evidence of carcinogeni c potential 10 ) emitted by the modeled source. Cancer incidence and the distribution of individual cancer risks for the population within 50 km of any source were also estimated for the source category as part of these assessments by summing individual risks . A distance of 50 km is consistent with both the analysis supporting the 1989 Benzene NESHAP (54 FR 38044) and the limitations of Gaussian dispe rsion models, including AERMOD. To assess risk of noncancer health effects from chronic exposures, we summed the HQ for each of the HAP that affects a common target organ system to obtain the HI for that target organ system (or target organ - specific HI, TOSHI). The HQ for chronic exposures is the estimated chronic exposure divided by the chronic reference level, which is either the EPA reference concentration ( RfC ) , defined as ―an estimate (with uncertainty spanning perhaps an order of magnitude) of a continuous inhalation exposure to the human population (including sensitive subgroups) that is likely to be withou t an appreciable risk

10 These classifications also coincide with the terms "known carcinogen, probable carcinogen and possible carcinogen," respectively, which are the terms advocated in the EPA's previous Guidelines for Carcinogen Risk Assessment , published in 1986 (51 FR 33992, September 24, 1986). Summing the risks of these individual compounds to obtain the cumulative cancer risks is an approach that was recommended by the EPA's SAB in their 2002 peer review of EPA's NATA entitled, NATA

- Evaluating the National

- scale Air Toxi cs Assessment 1996 Data

-- an SAB Advisory , available at: http://yosemite.epa.gov/sab/sabproduct.nsf/214C6E915BB04E14852570CA007A682C/ $File/ecadv02001.pdf.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 42 of 149 of deleterious effects during a lifetime,‖ or, in cases where an RfC from the EPA‘s IRIS database is not available, a value from the following prioritized sources : (1) t he a gency for Toxic Substances and Disease Registry Minimum Risk Level , which is defined as ―an estimate of daily human exposure to a substance that is likely to be without an appreciable risk of adverse effects (other than cancer) over a specified duration of exposure‖; ( 2) the CalEPA Chronic Reference Exposure Level ( REL ) , which is defined as ―the concentration level at or below which no adverse health effects are anticipated for a specified exposure duration ; ‖ or ( 3) as noted above, a scientifically credible dose

- response value that ha s been developed in a manner cons istent with the EPA guidelines and ha s undergone a peer review process similar to that used by the EPA, in place of or in concert with other values. Screening estimates of acute exposures and risks were also evaluated for each of the HAP at the point of hi ghest off

- site exposure for each facility ( i.e. , not just the census block centroids) , assuming that a person is located at this spot at a time when both the peak (hourly) emission rate s from each emission point at the facility and worst

- case dispersion co nditions occur. The acute HQ is the estimated acute exposure divided by the acute dose

- response value. In each case, acute HQ values were calculated using best available, short

- term dose

- response values. These acute dose

- response values, which are describe d below, include the acute REL, acute*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 43 of 149 exposure guideline levels (AEGL) and emergency response planning guidelines ( ERPG ) for 1

- hour exposure durations. As discussed below, we used conservative assumptions for emission rates, meteorology and exposure locati on fo r our acute analysis. As described in the CalEPA‘s Air Toxics Hot Spots Program Risk Assessment Guidelines, Part I, The Determination of Acute Reference Exposure Levels for Airborne Toxicants , an acute REL value (http:// www.oehha.ca.gov/air/pdf/acuterel.pdf ) is defined as ―the concentration level at or below which no adverse health effects are anticipated for a specified exposure duration.‖ Acute REL values are based on the most sensitive, rele vant, adverse health effect reported in the medical and toxicological literature. Acute REL values are designed to protect the most sensitive sub

- population s (e.g., asthmatics) by the inclusion of margins of safety. Since margins of safety are incorporated to address data gaps and uncertainties, exceeding the acute REL does not automatically indicate an adverse health impact.
AEGL values were derived in response to recommendations from the National Research Council ( NRC ) . As described in Standing Operating Procedures (SOP) of the National Advisory Committee on Acute Exposure Guideline Levels for Hazardous Substances ( http:// www.epa.gov/opptintr/aegl/pubs/ sop.pdf ), 11 ―the NRC‘s previous

11 NAS , 2001. Standing Operating Procedures for Developing Acute Exposure Levels for Hazardous Chemic als , page 2.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 44 of 149 name for acute exposu re levels

— community emergency exposure levels

— was replaced by the term AEGL to reflect the broad application of these values to planning, response, and prevention in the community, the workplace, transportation, the military, and the remediation of Superfu nd sites.‖ This document also states that AEGL values ―represent threshold exposure limits for the general public and are applicable to emergency exposures ranging from 10 minutes to eight hours.‖ The document lays out the purpose and objectives of AEGL by stating (page 21) that ―the primary purpose of the AEGL program and the National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances is to develop guideline levels for once

- in

a - lifetime, short

- term exposures to airborne concen trations of acutely toxic, high

- priority chemicals.‖ In detailing the intended application of AEGL values, the document states (page 31) that ―[i]t is anticipated that the AEGL values will be used for regulatory and nonregula tory purposes by U.S. Federal a nd state agencies and possibly the international community in conjunction with chemical emergency response, planning, and prevention programs. More specifically, the AEGL values will be used for conducting various risk assessments to aid in the development of emergency preparedness and prevention plans, as well as real

- time emergency response actions, for accidental chemical releases at fixed facilities and from transport carriers.‖*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 45 of 149
The AEGL

– 1 value is then specifically defined as ―the airborne concentratio n of a substance above which it is predicted that the general population, including susceptible individuals, could experience notable discomfort, irritation, or certain asymptomatic nonsensory effects. However, the effects are not disabling and are transie nt and reversible upon cessation of exposure.‖ The document also notes (page 3) that, ―Airborne concentrations below AEGL

– 1 represent exposure levels that can produce mild and progressively increasing but transient and nondisabling odor, taste, and sensory irritation or certain asymptomatic, nonsensory effects.‖ Similarly, the document defines AEGL

– 2 values as ―the airborne concentration (expressed as ppm or mg/m 3 ) of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long

lasting adverse health effects or an impaired ability to escape.‖
ERPG values are derived for use in emergency response, as described in the American Industrial Hygiene Association‘s docume nt entitled, Emergency Response Planning Guidelines (ERPG) Procedures and Responsibilities ( http://www.aiha.org/1documents/committees/ERPSOPs2006.pdf )which states that, ―Emergency Resp onse Planning Guidelines were developed for emergency planning and are intended as health based guideline*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 46 of 149 concentrations for single exposures to chemicals.‖ 12 The ERPG

– 1 value is defined as ―the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing other than mild transient adverse health effects or without perceiving a clearly defined, objectionable odor.‖ Similarly, the ERPG

– 2 value is defined as ―the maximum airborne

co ncentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing or developing irreversible or other serious health effects or symptoms which could impair an individual‘s ability to take protective a ction.‖ As can be seen from the definitions above, the AEGL and ERPG values include the similarly defined severity levels 1 and 2. For many chemicals, a severity level 1 value AEGL or ERPG has not been developed; in these instances, higher severity level A EGL

– 2 or ERPG

– 2 values are compared to our modeled exposure levels to assess potential for acute concerns. Acute REL values for 1

- hour exposure durations are typically lower than their corresponding AEGL

– 1 and ERPG

– 1 values. Even though their definitions a re slightly different, AEGL

– 1 values are often similar to the corresponding ERPG

– 1 values, and AEGL

– 2 values are often similar to ERPG

– 2 values. Maximum HQ values from our acute screening risk assessments typically result when basing them on the

12 ERP Committee Procedures and Responsibilities . November 1, 2006. American Industrial Hygiene Association.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 47 of 149
acute REL value for a particular pollutant. In cases where our maximum acute HQ value exceeds 1, we also report the HQ value based on the next highest acute dose

- response value (usually the AEGL

– 1 and/or the ERPG

– 1 value). To develop screening estimates of acute exp osures, we developed estimates of maximum hourly emission rates by multiplying the average actual annual hourly emission rates by a factor to cover routinely variable emissions. Acute risk modeling is conducted under the assumption that peak emissions are ten times greater than long term average emissions, in the absence of information regarding the variability of the emissions. With respect to routine variable emissions, p rimary aluminum potlines have a more consistent emissions profile than many other sources because these emissions actually reflect the average of the emissions from approximately 100 individual pots which operate in cycles that are not in phase with each o ther . Thus any variability associated with aluminum levels or electrode replacement for a particular pot may be damped out by the other pots at different stages. Alcoa provided to EPA a series of hourly hydrogen fluoride concentration data for two potlines at their Wenatchee facility. Approximately 2 , 075 consecutive hourly readings were provided based on Fourier Transform Infrared measurements at the roof vents. Alcoa found that the ratio of the maximum HAP emission rate to the average HAP emission rate for these two potlines were 2.7 and 5.6. Only one*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 48 of 149 value out 2 , 075 consecutive hour samples (0.05 percent ) was more than 5 times the average (i.e., 99.95 percent of values were less than 5 times the average )
. Th is dataset was then combined and subjected to two statistical analysis techniques: the upper prediction limit (UPL) calculated assuming a log

- normal distribution after adjusting for temporal correction and extreme value theory. The average of the concentration values is 514 μg/m 3 . The 99 percent UPL was calculated at 2 , 215 μg/m, which corresponds to 4.3 times the mean. Using the extreme value theory, the 99.9 percentile estimate of the generalized extreme value distribution (corresponding to 1 observation in 1000) was 2 , 306 μg/m 3 , which corresponds to 4.5 times the mean. Based on these data, a source category factor of 5 times the average hourly emissions rate, rather than the default factor of 10, was used in the acute screening assessment
. When worst

- case HQ values from the initial acute screen step

were less than 1, acute impacts were deemed negligibl e and no further analysis was performed. In cases where an acute HQ value from the screening step indicated the potential for acute risk, we further analyzed these values by considering additional site

- speci fic data to develop a relatively more refined estimate of the potential for acute impacts of concern. This site

- specific data includes the facility layout that was used to distinguish facility property from an area where the public could be exposed. These refinements are discussed in*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 49 of 149
the Draft Residual Risk Assessment for the Primary Aluminum Production Source Category document, which is available in the docket for this p roposed rulemaking
. Ideally, we would prefer to have continuous measurements over time to see how the emissions vary by each hour over an entire year. Having a frequency distribution of hourly emission rates over a year would allow us to perform a probabil istic analysis to estimate potential threshold exceedances and their frequency of occurrence. Such an evaluation could include a more complete statistical treatment of the key parameters and elements adopted in this screening analysis. However, we recogniz e that having this level of data is rare, hence our use of the multiplier approach. To better characterize the potential health risks associated with estimated acute exposures to HAP, and in response to a key recommendation from the SAB‘s peer review of th e EPA‘s RTR risk assessment methodologies , 13 we generally examine a wider range of available acute health metrics than we do for our chronic risk assessments. This is in response to the SAB‘s acknowledgement that there are generally more data gaps and incon sistencies in acute reference values than there are in chronic reference values. Comparisons of the estimated maximum off

- site 1

- hour exposure levels are not typically made to occupational levels for the purpose of

13 The SAB peer review of RTR Risk Assessment Methodologies is available at: http://yosemite.epa.gov/sab/sabproduct.nsf/4AB3966E263D943A 8525771F00668381/ $File/EPA

- SAB

- 10

- 007

- unsigned.pdf.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 50 of 149 characterizing public health risks in RTR assessments. This is because they are developed for working age adults and are not generally considered protective for the general public. We note that occupational ceiling values are, for most chemicals, set at levels higher than a 1

- hour AEGL

- 1.
4 . Cond ucting multi

- pathway exposure and risk screening The potential for significant human health risks due to exposures via routes other than inhalation ( i.e. , multi

- pathway exposures) and the potential for adverse environmental impacts were evaluated in a thre e - step process. In the first step, we determined whether any facilities emitted any PB

- HAP (HAP known to be persistent and bio

- accumulative in the environment ) . There are 14 PB

- HAP compounds or compound classes identified for this screening in the EPA‘s Ai r Toxics Risk Assessment Library (available at http://www.epa.gov/ttn/fera/risk_atra_vol1.html ). They are cadmium compounds, chlordane, chlorinated dibenzodioxins and furans, dichlorodiphenyldic hloroethylene, heptachlor, hexachlorobenzene, hexachlorocyclohexane, lead compounds, mercury compounds, methoxychlor, polychlorinated biphenyls, POM, toxaph ene and trifluralin. Since POM is a PB

- HAP and is emitted by all facilities in this source category , we proceeded to the second step of the evaluation to screen for potentially significant multi

- pathway risks due to POM emissions . In this step, we determined whether the facility

- specific*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 51 of 149 emission rates of POM were large enough to create the potential for significant non

- inhalation human or environmental risks under reasonable worst

- case conditions. To facilitate this step, we have developed emission rate thresholds for each PB

– HAP using a hypothetical worst

- case screening exposure scenario developed for u se in conjunction with the EPA‘s TRIM.FaTE model. The hypothetical screening scenario was subjected to a sensitivity analysis to ensure that its key design parameters were established such that environmental media concentrations were not underestimated ( i. e. , to minimize th e occurrence of false negatives or results that suggest that risks might be acceptable when, in fact, actual risks are high) and to also minimize the occurrence of false positives for human health endpoints. We call this application of th e TRIM.FaTE model
TRIM

- Screen. The facility

- specific emission rates of POM were compared to the TRIM

- Screen emission threshold values for POM to assess the potential for significant human health risks or environmental risks via non

- inhalation pathways. 5
. Assessin g risks considering e missions control o ptions In addition to assessing baseline inhalation risks and screening for potential multi

- pathway risks, where appropriate, we also estimated risks considering the potential emission reductions that would b e achieved by the particular control options under consideration. In these cases, the expected emissions reductions were applied to the specific HAP and emissions sources in the source*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 52 of 149 category dataset to develop corresponding estimates of risk reductions. 6 . Cond ucting other risk

- related analyses : facility wide a ssessments To put the source category risks in context, for our residual risk review s , we also typically examine the risks from the entire ―facility,‖ where the facility includes all HAP

- emitting o perations within a contiguous area and under common control. In these facility wide assessments w e examine the HAP emissions not only from the source category of interest, but also emissions of HAP from all other emissions sources at the facility. Eleven of the primary aluminum reduction plants are collocated with secondary aluminum production operations. Based on a general knowledge of these facilities , we believe that the Primary Aluminum sources are the largest sources of HAP emissions at each of them
. Moreover, we plan to do a facility wide assessment for each of these eleven facilities in an upcoming
RTR rulemaking for the Secondary Aluminum source category. Therefore, we did not perform a facility wide risk assessment for these eleven facilitie s as part of today‘s action
. For the four primary aluminum facilities that are not collocated with secondary aluminum production operations, the risk assessment performed as part of today‘s action contained herein is a facility wide risk assessment.
7 . Cons idering uncertainties in risk a ssessment Uncertainty and the potential for bias are inherent in all risk assessments, including those performed for the Primary Aluminum*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 53 of 149 source categor y addressed in this proposal. Although uncertainty exists, we believe tha t our approach, which used conservative tools and assumptions, ensures that our decisions are health

- protective. A brief discussion of the uncertainties in the emissions datasets, dispersion modeling , inhalation exposure estimates and dose

- response relatio nships follows below. A more thorough discussion of these uncertainties is included in the risk assessment documentation (referenced earlier) available in the docket for this action.

a . Uncertainties in the e miss ions d atasets Although the development of the MACT dataset involved QA/ quality control processes, the accuracy of emissions values will vary depending on the source of the data, the degree to which data are incomplete or missing, the degree to which assumptions made to complete the datasets are in accurate, errors in estimating emissions values and other factors. The emission estimates considered in this analysis generally are annual totals for certain years that do not reflect short

- term fluctuations during the course of a year or variations from y ear to year. The estimates of peak hourly emission rates for the acute effects screening assessment were based on a multiplication factor of 5 applied to the average annual hourly emission rate, which is intended to account for emission fluctuations due to normal facility operations. b . Uncertainties in dispersion m odeling*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 54 of 149 While the analysis employed the EPA‘s recommended regulatory dispersion model, AERMOD, we recognize that there is uncertainty in ambient concentration estimates associated with any mode l, including AERMOD. In circumstances where we had to choose between various model options, where possible, model options ( e.g. , rural/urban, plume depletion, chemistry) were selected to provide an overestimate of ambient air concentrations of the HAP rath er than underestimates. However, because of practicality and data limitation reasons, some factors ( e.g. , meteorology, building downwash) have the potential in some situations to overestimate or underestimate ambient impacts. For example, meteorological da ta were taken from a single year (1991) , and facility locations can be a significant distance from the site s where these data were taken. Despite these uncertainties, we believe that at off

- site locations and census block centroids, the approach considered in the dispersion modeling analysis should generally yield overestimates of ambient HAP concentrations.

c . Uncertainties in inhalation exposure The effects of human mobility on exposures were not included in the assessment. Specifically, short

- term mobil ity and long

- term mobility between census blocks in the modeling domain were not
considered. 14 The assumption of not considering short or long

- term population mobility does not bias the estimate of the theoretical

14 Short

- term mobility is movement from one micro

- environment to another over the course of hours or days. Long

- term mobility is movement from one residence to another over the course of a lifetime.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 55 of 149
MIR , nor does it affect the estimate of can cer incidence since the total population number remains the same. It does, however, affect the shape of the distribution of individual risks across the affected population, shifting it toward higher estimated individual risks at the upper end and reducing the number of people estimated to be at lower risks, thereby increasing the estimated number of people at specific risk levels. In addition, the assessment predicted the chronic exposures at the centroid of each populated census block as surrogates for th e exposure concentrations for all people living in that block. Using the census block centroid to predict chronic exposures tends to over

predict exposures for people in the census block who live further from the facility, and under

- predict exposures for p eople in the census block who live closer to the facility. Thus, using the census block centroid to predict chronic exposures may lead to a potential understatement or overstatement of the true maximum impact, but it is an unbiased estimate of average risk and incidence. The assessments evaluate the cancer inhalation risks associated with continuous pollutant exposures over a 70

- year period, which is the assumed lifetime of an individual. In reality, both the length of time that modeled emissions sources at facilities actually operate ( i.e. , more or less than 70 years) and the domestic growth or decline of the modeled industry ( i.e. , the increase or decrease in the number or size of United States facilities) will influence the risks posed*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 56 of 149 by a given source c ategory. Depending on the characteristics of the industry, these factors will, in most cases, result in an overestimate both in individual risk levels and in the total estimated number of cancer cases. However, in rare cases, where a facility maintains or increases its emission levels beyond 70 years, residents live beyond 70 years at the same location, and the residents spend most of their days at that location, then the risks could potentially be underestimated. Annual cancer incidence estimates from expo sures to emissions from these sources would not be affected by uncertainty in the length of time emissions sources operate. The exposure estimates used in these analyses assume chronic exposures to ambient levels of pollutants. Because most people spend th e majority of their time indoors, actual exposures may not be as high, depending on the characteristics of the pollutants modeled. For many of the HAP, indoor levels are roughly equivalent to ambient levels, but for very reactive pollutants or larger parti cles, these levels are typically lower. This factor has the potential to result in an overstatement of 25 to 30 percent of exposures. 15 In addition to the uncertainties highlighted above, there are several other factors specific to the acute exposure assessment. The accuracy of an acute inhalation exposure assessment depends on the

15 U.S. EPA. National

- Scale Air Toxics Assessment for 1996 . (EPA 453/R

– 01

– 003; January 2001; page 85.)*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 57 of 149 simultaneous occurrence of independent factors that may vary greatly, such as hourly emissions rates, meteorology, and human activity patterns. In this assessment, we assume that individuals remain for 1 hour at the point of maximum ambient concentration as determined by the co

- occurrence of peak emissions and worst

- case meteorological conditions. These assumptions would tend to overesti mate actual exposures since it is unlikely that a person would be located at the point of maximum exposure during the time of worst

- case impact. d . Uncertainties in dose

- response r elationships There are uncertainties inherent in the development of the dose

response values used in our risk assessments for cancer effects from chronic exposures and noncancer effects from both chronic and acute exposures. Some uncertainties may be considered quantit atively, and others generally are expressed in qualitative terms. We note as a preface to this discussion a point on dose

- response uncertainty that is brought out in the EPA 2005 Cancer Guidelines ; namely, that ―the primary goal of the EPA actions is prote ction of human health; accordingly, as an a gency policy, risk assessment procedures, including default options that are used in the absence of scientific data to the contrary, should be health protective.‖ ( EPA 2005 Cancer Guidelines , pages 1

– 7.) This is t he approach followed here as summarized in the next several paragraphs. A complete detailed discussion of uncertainties and variability in dose

- response*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 58 of 149 relationships is given in the residual risk documentation, which is available in the docket for this ac tion. Cancer URE values used in our risk assessments are those that have been developed to generally provide an upper bound estimate of risk. That is, they represent a ―plausible upper limit to the true value of a quantity‖ (although this is usually not a true statistical confidence limit). 16 In some circumstances, the true risk could be as low as zero; however, in other circumstances , the risk could also be greater. 17 When developing an upper bound estimate of risk and to provide risk values that do not unde restimate risk, health

- protective default approaches are generally used. To err on the side of ensuring adequate health

- protection, the EPA typically uses the upper bound estimates rather than lower bound or central tendency estimates in our risk assessmen ts, an approach that may have limitations for other uses ( e.g. , priority

- setting or expected benefits analysis). Chronic noncancer reference (RfC and reference dose ( RfD ) ) values represent chronic exposure levels that are intended to be health

- protective l evels. Specifically, these values provide an estimate (with uncertainty spanning perhaps an order of magnitude) of daily oral exposure (RfD) or of a continuous inhalation exposure (RfC) to the human population (including sensitive subgroups) that is

16 IRIS glossary (http://www.epa.gov/NCEA/iris/help_gloss.htm). 17 An exception to this is the URE for benzene, which is considered to cover a range of values, each end of which is considered to be equally plausible and which is based on maximum likelihood estimates.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 59 of 149 likely to be without an appreciable risk of deleterious effects during a lifetime. To derive values that are intended to be ―without appreciable risk,‖ the methodology relies upon an uncertainty factor ( UF ) approach (U.S. EPA, 1993, 1994) which includes consider ation of both uncertainty and variability. When there are gaps in the available information, UF are applied to derive reference values that are intended to protect against appreciable risk of deleterious effects. The UF are commonly default values, 18 e.g. , factors of 10 or 3, used in the absence of compound

- specific data; where data are available, UF may also be developed using compound

- specific information. When data are limited, more assumptions are needed and more UF are used. Thus, there may be a greater tendency to overestimate risk in the sense that further study might support development of reference values that are higher ( i.e. , less potent) because fewer default assumptions are needed. However, for some

18 According to the NRC report, Science and Judgment in Risk Assessment (NRC, 1994) ―[Default] options are generic approaches, based on general scien tific knowledge and policy judgment, that are applied to various elements of the risk assessment process when the correct scientific model is unknown or uncertain.‖ The 1983 NRC report, Risk Assessment in the Federal Government: Managing the Process , defin ed default option as ―the option chosen on the basis of risk assessment policy that appears to be the best choice in the absence of data to the contrary‖ (NRC, 1983a, p. 63). Therefore, default options are not rules that bind the Agency; rather, the Agency may depart from them in evaluating the risks posed by a specific substance when it believes this to be appropriate. In keeping with EPA‘s goal of protecting public health and the environment, default assumptions are used to ensure that risk to chemicals i s not underestimated (although defaults are not intended to overtly overestimate risk). See EPA, 2004, An Examination of EPA Risk Assessment Principles and Practices , EPA/100/B

– 04/001 available at: http://www.epa.gov/osa/pdfs/ratf

- final.pdf.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 60 of 149 pollutants, it is possible that risks may be un derestimat ed. While collectively termed ―uncertainty factor ,‖ these factors account for a number of different quantitative considerations when using observed animal (usually rodent) or human toxicity data in the development of the RfC. The UF ar e intended to account for: (1) v ariation in susceptibility among the members of the human population ( i.e. , inter

- individual variability); (2) uncertainty in extrapolating from experimental animal data to humans ( i.e. , interspecies differences); (3) uncertainty in ex trapolating from data obtained in a study with less

- than

- lifetime exposure ( i.e. , extrapolating from sub

- chronic to chronic exposure); (4) uncertainty in extrapolating the observed data to obtain an estimate of the exposure associated with no adverse effec ts; and (5) uncertainty when the database is incomplete or there are problems with the applicability of available studies. Many of the UF used to account for variability and uncertainty in the development of acute reference values are quite similar to thos e developed for chronic durations, but they more often use individual UF values that may be less than 10. UF are applied based on chemical

- specific or health effect

- specific information ( e.g. , simple irritation effects do not vary appreciably between human individuals, hence a value of 3 is typically used), or based on the purpose for the reference value (see the following paragraph). The UF applied in acute reference value derivation include: (1) h eterogeneity among humans; (2) uncertainty in extrapolating from animals to humans; (3) uncertainty*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 61 of 149 in lowest observed adverse effect (exposure) level to no observed adverse effect (exposure) level adjustments; and (4) uncertainty in accounting for an incomplete database on toxic effects of potential concern. Addi tional adjustments are often applied to account for uncertainty in extrapolation from observations at one exposure duration ( e.g. , 4 hours) to derive an acute reference value at another exposure duration ( e.g. , 1 hour). Not all acute reference values are developed for the same
purpose , and care must be taken when interpreting the results of an acute assessment of human health effects relative to the reference value or values being exceeded. Where relevant to the estimated exposures, the lack of short

- term dose

- response values at different levels of severity should be factored into the risk characterization as potential uncertainties. Although every effort is made to identify peer

- reviewed reference values for cancer and noncancer effects for all pollutants emitted by the sources included in this assessment, some HAP continue to have no reference values for cancer or chronic noncancer or acute effects. Since exposures to these pollutants cannot be included in a quantitative risk estimate, an understatement o f risk for these pollutants at environmental exposure levels is possible. For a group of compounds that are either unspeciated or do not have reference values for every individual compound ( e.g. , glycol ethers), we*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 62 of 149 conservatively use the most protective re ference value to estimate risk from individual compounds in the group of compounds. Additionally, chronic reference values for several of the compounds included in this assessment are curr ently under the EPA IRIS review , and revised assessments may determi ne that these pollutants are more or less potent than the current value. We may re

evaluate residual risks for the final rulemaking if these reviews are completed prior to our taking final action for th i s source categor y and a dose

- response metric changes enough to indicate that the risk assessment supporting this notice may significantly understate human health risk.

e . Uncertainties in the multi

- pathway and environmental effects screening a ssessment We generally assume that when exposure levels are not

an ticipated to adversely affect human health, they also are not anticipated to adversely affect the environment. For each source category, we generally rely on the site

- specific levels of PB

- HAP emissions to determine whether a full assessment of the multi

- p athway and environmental effects is necessary. For this source category , we only performed a multi

- pathway screening assessment for PB

- HAP. Thus, it is important to note that potential PB

- HAP multi

- pathway risks are biased high
. C. How did we consider the risk results in making decisions for this proposal?*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 63 of 149 In evaluating and developing standards under section 112(f)(2),

a s discussed in section I.A of this preamble, we apply a two

- step process to address residual risk. In the first step, the EPA determines wh ether risks are acceptable. This determination ―considers all health information, including risk estimation uncertainty, and includes a presumptive limit on maximum individual lifetime [cancer] risk (MIR) 19 of approximately 1

- in

- 10 thousand [ i.e., 100

- in

- 1 million]‖ ( 54 FR 38045 ) . In the second step of the
process, the EPA sets the standard at a level that provides an ample margin of safety ―in consideration of all health information, including the number of persons at risk levels higher than
appro ximately 1

- in

- 1 million, as well as other relevant factors, including costs and economic impacts, technological feasibility, and other factors relevant to each particular decision‖ ( Id. ) In past residual risk actions, the EPA has presented and considered a number of human health risk metrics associated with emissions from the category under review, including: the MIR; the numbers of persons in various risk ranges; cancer incidence; the maximum non

- cancer hazard index (HI); and the maximum acute non

cancer h azard ( 72 FR 25138, May 3, 2007; 71 FR 42724, July 27, 2006)
. In more recent proposals (75 FR 65068, October 21, 2010 , and 75 FR

19 Although def ined as ―maximum individual risk,‖ MIR refers only to cancer risk. MIR, one metric for assessing cancer risk, is the estimated risk were an individual exposed to the maximum level of a pollutant for a lifetime.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 64 of 149 80220, December 21, 2010), the EPA also presented and considered additional measures of health information, such as estimates o f the risks associated with the maximum level of emissions which might be allowed by the current MACT standards ( see, e.g., 75 FR 65068, October 21, 2010 , and 75 FR 80220, December 21, 2010). The EPA also discussed and considered risk estimation uncertaint ies. The EPA is providing this same type of information in support of the proposed actions described in this Federal Register notice. The a gency is considering all available health information to inform our determinations of risk acceptability and ample ma rgin of safety under CAA section 112(f). Specifically, as explained in the Benzene NESHAP, ― the first step judgment on acceptability cannot be reduced to any single factor‖ and thus ―[t]he Administrator believes that the acceptability of risk under [previo us] section 112 is best judged on the basis of a broad set of health risk measures and information‖ ( 54 FR 38046 ) . Similarly, with regard to making the ample margin of safety determination, as stated in the Benzene NESHAP ―[ i n the ample margin decision, th e a gency again considers all of the health risk and other health information considered in the first step. Beyond that information, additional factors relating to the appropriate level of control will also be considered, including cost and economic impacts of controls, technological feasibility, uncertainties, and any other relevant factors.‖ Id.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 65 of 149
T he a gency acknowledges tha t the Benzene NESHAP provides flexibility regarding what factors the EPA might consider in making determinations and how the se factors might be weighed for each source category. In responding to comment on our policy under the Benzene NESHAP, the EPA explained that: ―The policy chosen by the Administrator permits consideration of multiple measures of health risk. Not only can the MIR fig ure be considered, but also incidence, the presence of non

- cancer health effects, and the uncertainties of the risk estimates. In this way, the effect on the most exposed individuals can be reviewed as well as the impact on the general public. These factor s can then be weighed in each individual case. This approach complies with the Vinyl Chloride mandate that the Administrator ascertain an acceptable level of risk to the public by employing [her] expertise to assess available data. It also complies with th e Congressional intent behind the CAA, which did not exclude the use of any particular measure of public health risk from the
EPA 's consideration with respect to CAA section 112 regulations, and, thereby, implicitly permits consideration of any and all mea sures of health risk which the Administrator, in [her] judgment, believes are appropriate to determining what will  ̳protect the public health‘‖ ( 54 FR 38057 )
. Thus , the level of the MIR is only one factor to be weighed in determining acceptability of risks
. The Benzene NESHAP explained that ―an MIR of approximately 1

- in

- 10 thousand should ordinarily be the*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 66 of 149 upper end of the range of acceptability. As risks increase above this benchmark, they become presumptively less acceptable under CAA section 112, and wou ld be weighed with the other health risk measures and information in making an overall judgment on acceptability. Or, the a gency may find, in a particular case, that a risk that includes MIR less than the presumptively acceptable level is unacceptable in
t he light of other health risk factors‖ ( Id. at 38045 ) . Similarly, with regard to the ample margin of safety analysis, the EPA stated in the Benzene NESHAP that: ―... the EPA believes the relative weight of the many factors that can be considered in selecting an ample margin of safety can only be determined for each specific source category. This occurs mainly because technological and economic factors (along with the health

- related factors) vary from source category to source category‖ ( Id. at 38061 )
. D . How d id we perform the technology review? Our technology review focused on the identification and evaluation of developments in practices, processes, and control technologies that have occurred since the Primary Aluminum Reduction Plant NESHAP was promulgated
. Based on our analyses of the data and information collected from industry and the trade organization representing all facilities subject to the NESHAP , our general understanding of the industry , and other available information in the literature on potentia l controls for this industry , we identif ied no new developments in practices,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 67 of 149 processes, and control technologies. For the purpose of this exercise, we considered any of the following to be a ―development‖:

 Any add

- on control technology or other equipment that was not identified and considered during development of the 1997 Primary Aluminum Reduction Plant NESHAP .

 Any improvements in add

- on control technology or other equipment (that were identified and considered during development of the 1997 Primary Aluminum Reduction Plant NESHAP ) that could result in significant additional emissions reduction
.

 Any work practice or operational procedure that was not identified or considered during development of the 1997 Primary Aluminum Reduction Plant NESHAP .

 Any p rocess change or pollution prevention alternative that could be broadly applied to the industry and that was not identified or considered during development of the 1997 Primary Aluminum Reduction Plant NESHAP . We also consulted the EPA ‘s RACT/BACT/LAER Cle aringhouse (RBLC) to identify potential technology advances . Control technologies classified as RACT (Reasonably Available Control Technology), BACT (Best Available Control Technology), or LAER (Lowest Achievable Emissions Rate) apply to stationary sources depending on whether the

sources exist or new and on the size, age, and location of the facility. BACT and LAER (and sometimes RACT) are determined on a*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 68 of 149

case - by

- case basis, usually by State or local permitting agencies. The EPA established the RBLC to pro vide a central database of air pollution technology information (including technologies required in

source - specific permits) to promote the sharing of information among permitting agencies and to aid in identifying future possible control technology option s that might apply broadly to numerous sources within a category or apply only on a source

- by

- source basis. The RBLC contains over 5,000 air pollution control permit determinations that can help identify appropriate technologies to mitigate many air pollut ant emissions streams. We searched this database to determine whether it contained any practices, processes, or control technologies for the types of processes covered by the Primary Aluminum Reduction Plant NESHAP . No such practices, processes, or control technologies were identified in this database.
E . What other issues are we addressing in this proposal? In addition to the analyses described above, we also reviewed other aspects of the MACT standards for possible revision as appropriate and necessary. Based on this review we have identified aspects of the MACT standards that we believe need revision. This includes proposing revisions to the startup, shutdown and malfunction (SSM) provisions of the MACT rule in order to ensure that they are consistent wi th a recent court decision in Sierra Club v.
EPA , 551 F. 3d 1019 (D.C. Cir. 2008). In addition, we are proposing other changes to the rule which are not based on residual risk. These*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 69 of 149 include establishing MACT floor

- based standards for POM emissions from pr ebake potlines, COS emissions from all potlines, and design standards for control of POM emissions from existing pitch storage tanks. We are also proposing changes to the rule related to

a ffirmative defense for exceedance of an emission limit during a malf unction
. The analyses and proposed decisions for these actions are presented in section I V of this preamble.
IV. Analy tical Results and Proposed Decisions This section of the preamble provides the results of o ur RTR for the Primary Aluminum Reduction Plant source category and our proposed decisions concerning changes to the Primary Aluminum Reduction Plant
NESHAP . A. What are the results of our analyses and proposed decisions regarding unregulated emissions sources? The current MACT rule has no standards fo r POM from prebake potlines. Prebake facilities have significantly lower POM emission s compared to Soderberg facilities
. Nevertheless, these emissions are
not negligible
. W e are proposing to establish MACT emission limits for POM from prebake potlines in this action. The typical controls used on these prebake potlines to limit the primary (i.e., stack) emissions, and which reflect the MACT floor level of control, are dry alumina scrubbers (with a baghouse). We calculated MACT floor limits for these potline s based on the limited available data. We also considered possible controls beyond the MACT floor, such as wet roof*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 70 of 149 scrubbers, but we estimated that these beyond

- the

- floor controls would only achieve approximately an additional 30 percent reduction in seco ndary (i.e., roof vent) emissions and that the costs of these additional controls would be quite high (e.g., well over $100 million in capit a l costs for the industry)
. We estimate that the cost of controlling POM from prebake potroom secondary emissions wo uld be approximately $800,000 per ton. Therefore, we are proposing emission limit s for POM from prebake potlines , after considering variability in emissions using a 99% upper prediction level approach, based on the MACT floor. We are proposing a POM emission limit for new prebake potlines equal to the lowest limit for existing prebake potlines (developed from data obtained from the best performing sources (center

- worked prebake one ) facilit ies ). More details about the data and a nalyses used to derive the MACT limits, and explanation of the beyond

- the

- floor an a ly s es, are provided in the technical document Draft M ACT Floor Analysis for the Primary Aluminum Production Sou rce Category which is available in the docket for this propose d action
. The proposed limits for prebake potlines are shown in Table 5
. Table 5. Proposed Emission Limits for New and Existing Prebake Potlines
Source Pollutant Emission Limit*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 71 of 149 Existing Prebake CWPB1 potlines CWPB2 potlines CWPB3 potlines SWPB potlines

New Prebake All prebake potline types POM

POM

POM

POM

POM 0.31 0. 33 kg/Mg (0. 6 2 (0.66 lb/ton) of aluminum

produced
0.65 0.73 kg /Mg (1. 3 (1.45 lb/ton) of aluminum produced
0.6 3 0.73 kg /Mg (1. 26 (1.45 lb/ton) of aluminum produced
0.33 kg/Mg ( 0. 65 (0.66 lb/ton) of aluminum produced

0.31 0.32 kg/Mg ( 0. 62 (0.63 lb/ton) of aluminum produced As mentioned above, t he current MACT rule has no standards for
COS . I t is very difficult and quite expensive to measure total COS emission s because the concentration s of secondary emissions are below the detection limit of the EPA reference method
. However, stack tests are feasible and have been completed. Moreover, emissions studies have been completed using an experimental test method to estimate CO S emissions from these secondary emissions sources ( Determination of
COS to SO 2 Ratio in Smelting Process Emissions at the Alcoa Warrick Operations, 4 August 1995)
. . W e have been able to use the experimental test results along with stack test data to estim ate total COS emissions. B ased on these studies and data on sulfur content of input materials to estimate total COS emissions. W e , we have determined that there is a direct relationship between the COS emissions and the sulfur content of raw materials
. The results of these studies indicate that an estimated 8 percent of the sulfur Formatted: Line spacing: single*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 72 of 149 present in the coke (used to make anodes) is converted to COS emissions
. Given the technical difficulties of measuring secondary fugitive COS emissions directly, and given that there is a direct relationship between sulfur content of input materials and COS emissions , we developed a mass balance equation for cal culating COS emissions
. Using this approach, w e developed calculated a proposed MACT standard for COS using via the mass b alance equation . The equation derives monthly COS emission rates based and available data on anode coke sulfur content , anode consumption production and aluminum production , as follows : from each facility using the following equation:

Where:
E COS = the facility wide emission rate of COS during the calendar month in pounds per ton of aluminum produced; K = factor accounting for molecular weights and conversion of sulfur to carbonyl sulfide = 234; Y = the tons of anode used at the facility during the calendar month; Z = the tons of aluminum produced at the facility during the calendar month; and %S = the weighted average sulfur content of the anode coke utilized in the production of aluminum during the calendar month (e. g., if the*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 73 of 149 weighted average sulfur content of the anode coke utilized during the calendar month was 2.5%, then %S = 0.025). Using this method, w e are proposing a have determined that the
MACT floor limit for COS for existing facilities at is 3 .9 pounds of
CO S per ton of aluminum produced (lb/ton Al) , based on data obtained from the five facilities with the lowest calculated COS emissions and adjustment to account for variability using a 99% upper prediction limit approach
. . With regard to costs for this standard, we estimate that all facilities will be able to meet this limit with minimal adjustments of their raw materials and with minimal additional costs (e.g., calculating COS emissions and the associated monitoring, record keeping and reporting)
. . With regard to new sources, t he MACT floor limit for COS for new facilities is proposed at 3.1 lb COS/ton Al, based on data obtained from the facility with the lowest calculated COS emissions and adjustment to account for variabili ty . W e also considered beyond

- the

- floor options for COS. For example, we assessed the feasibility and costs of proposing that all existing facilities meet a limit of 3.1 lb COS/ton Al
. We estimate that a limit at this level would impact 5 facilities, resul t in 220 tpy reductions of COS emissions, at a total cost of $13,000,000 (or $2.6 million per facility) per year . However, there are significant uncertainties regarding the future availability and costs of the associated required lower

- sulfur anode coke
. The Primary Alumi n um industry obtains most of their coke as a by

- product from the gas and*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 74 of 149 oil refinery industry. It is our understanding that currently available coke with low sulfur contents could be very hard to obtain in the future and will likely be mu ch more expensive
. This situation is expected due to the following: (1) t he type of crude oil input at refineries in the future is generally expected to be heavier and, therefore, less likely to result in ―anode grade coke ‖ that ha s the structure necessary for use in anode production ; (2) t he type of crude oil input at refineries in the future is generally expected to have higher sulfur content because the per barrel cost of heavy sour (i.e., high

- sulfur) crude oil is so much lower than light sweet (i.e., low

- sulfur) crude oil ; ( 3 ) r efineries initially designed to process light sweet crude oil are being converted to process heavy sour crude oil at a rapid pace worldwide due to refinery economics; ( 4 ) r efineries are designed to desulfurize the product streams (gasoline, diesel, etc.), not the crude oil input, and the sulfur in the crude oil tends to concentrate in the petroleum coke (i.e., the ―bottoms‖) ; ( 5 ) unwillingness of r efiner ies to preferentially process light sweet crude oil in place of heavy sour crude oil due to unfavorable economics ( i.e., refineries will not modify their operations to change the quality of a by

- product such as petroleum coke ) ; and ( 6 ) t he lack of leverage that primary aluminum companies have over the quality of this by

- prod uct, as coke is a very low profit item for refineries and anode grade coke represents less than 20% of all the petroleum coke produced worldwide
. Thus , based on*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 75 of 149 future availability of low

- sulfur coke, the true long term costs could exceed the present estim ated cost of $13,000,000 per year
. We also evaluated the feasibility and costs of another beyond

the

- floor option of requiring proposing that all existing facilities meet a limit of 3.5 lb COS/ton Al
. We estimate that a limit at this level would impact 2 facilities, result in 52 tpy reductions of COS emissions, at a total cost of $ 2 ,000,000 (or $ 1 million per facility)
per year . Once again , these estimated costs could be significant underestimates of the true long

- term costs. T he uncertainties and

concern s about the future availability and costs of the required low

sulfur content coke that are described above for the 3.1 lb COS/ton
Al option are also a concern for this 3.5 lb COS/ton Al option
. We also considered control options including incineration and scrubbing of COS. The cost of incineration would be quite high due to the volume (typically millions of cubic feet per minute) and the relatively low temperature of the exhaust stream (typically less than
200 ° F). Incineration also involves the disadvantag e of the generation of sulfur dioxide and other pollutants. Similarly, the cost of scrubbers would be quite high and involve the disadvantage of generating a waste sludge stream.
G iven the analyses and conclusions described above, we are propos ing a MACT standard for COS for existing facilities based on the MACT floor analysis, which is a limit of 3.9 lb COS/ton Al
. With*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 76 of 149 regard to new sources, we are proposing a MACT standard for COS based on the MACT floor analysis, which is a limit of 3.1 lb COS/t on Al
. With regard to POM emissions from pitch storage tanks, the 1997 NESHAP included MACT standards for new pitch storage tanks, which required a 95 percent reduction in POM emissions. However, the 1997
NESHAP had no limits for existing storage tanks. We are proposing in today‘s action that existing tanks will be subject to the same standard ( i.e. , minimum of 95 percent reduction of POM emissions)
. for these tanks. At least three facilities are currently achieving this level of control. We estimate that e ight facilities would be affected by this standard and would need to add controls, at a total annualized cost of about $21,000 per facility
. year. We also estimate that this would achieve 1.6 2.3 tons reductions in POM emissions per
year. A non

- contact single stage, refrigerated, water cooled condenser system was considered as a beyond the floor option for POM from pitch storage tanks. However, we believe the associated cost (estimated at $184,000 per year, per facility) is not justified by the increment al control of HAP (estimated at 0.081 tons per year for the industry).
B. What are the results of the risk assessments?
F or the Primary Aluminum source category, we conducted an inhalation risk assessment for all HAP emitted
. We also conducted multi

- pathwa y screening analyses for PB

- HAP emitted (i.e., POM ). Results of the risk assessment are presented briefly below and in*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 77 of 149
more d etail in the residual risk documentation referenced in section
II I of this preamble, which is available in the docket for this acti on . Table 6 of this preamble provides an overall summary of the results of the inhalation risk assessment.
Table 6
. Primary Aluminum Reduction Plant Inhalation Risk Assessment Results Maximum Individual Cancer Risk (in 1 million) 1 Estimated Population at increased Risk of cancer ≥ 1

- in

- 1 Million Estimated

Annual Cancer Incidence (cases per year) Maximum

Chronic Non

- cancer TOSHI 2 Worst

case Maximum Refined Screening Acute Non

cancer HQ 3 Based on Actual Emissions Level Based on

Allowable Emissions Level 4 ,5 Based on Actual Emissions Level Based on

Allowable Emissions Level

30 100 41,000 0.005 0.4 0.6 HQ REL 10 (HF ) HQ AEGL

- 1 4 (HF) 1 Estimated maximum individual excess lifetime cancer risk due to HAP emissions from the source category. 2 Maximum TOSHI. The target organ with the highest TOSHI for the primary aluminum source category is the skeletal system
. 3 See section III.B of this preamble for explanation s of acute dose

- response values. 4 The facility with the highest MIR based on allowable emissions is the Columbia Falls facility. Notably, this facility has not operated in approximately 2 years and therefore, the EPA did not generate risk estimates (i.e., MIR, TOSHI, and acute screening v alues) based on actual emissions for this facility
. 5 The highest MIR based on allowable emissions from an operating facility is estimated to be up to 50 in one million, for the operating Soderberg facility. The results of the chronic inhalation cancer ris k assessment indicate that, based on estimates of current actual emissions, the maximum individual lifetime c ancer risk (MIR) could be up to 30 in

one million , with emissions of POM 20 primarily from potline roof vents (secondary emissions) and anode bake furnaces driving these risks. The highest MIR of up to 30 in one million based on actual emissions

20 Most all POM emitted by this source catego ry are PAHs. Formatted: Space After: 0 pt*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 78 of 149 is due to POM emissions from the one currently operating S oderberg facility. The highest MIR due to actual emissions from prebake facilities was estimated to be up to 20 in one million ; the next highest MIR for an operating prebake facility is estimated to be up to 6 in one million
. million. The total estimated cancer incidence from this source category based on actual emission l evels is 0.005

excess cancer cas es per year or one case in every 200 years , with emissions of POM contributing approximately 99 90 percent to this cancer incidence
. In addition, we note that approximately 41,000 people a re estimated to have cancer risks greater than 1 in one million, and approximately 900 people a re estimated to have risks greater than 10 in one million. When considering the risks associated with MACT

- allowable emissions , the MIR could be up to 100 in one million if the Columbia Falls facility (a Soderberg ty pe facility)
were t o resume its primary aluminum operations (see note 4 on Table 6 ). The MIR based on allowable emissions from the one currently operating Soderberg facility (Mas s ena East facility ) was up to 50 in one million. The highest MIR based on allo wable emissions from any of the prebake facilities was up to 30 in one million. The maximum modeled chronic non

- cancer TOSHI value is 0.4 based on actual emissions , driven primarily by HF emissions
. When considering MACT allowable emissions , the maximum chronic non

- cancer TOSHI value could be up to 0.6. For this source category, there were
two HAP that had relevant acute health effect screening values:*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 79 of 149 carbonyl sulfide (COS) and hydrofluoric acid (HF)
. Acute health effect screening is performed using actu al emissions data . The Columbia Falls facility has not operated in about 2 years and has not operated at capacity since about 1999. Therefore, suitable actual emission data was not available for this facility and its acute health effects are not included i n this discussion
. Further, the carbon

- only prebake anode production facility does not emit COS or HF. Therefore, this discussion addresses the acute health effects of only the 13 remaining facilities subject to this NESHAP. With respect
to COS , we did not find any potential for acute health concerns for the 1 3 facilities based on their actual emissions. However, HF emissions did not screen out w ith respect to potential acute health effects . T he highest refined worst

- case HQ for HF based on a REL is 10 , bas ed on an AEGL

- 1 is 4, and based o n an ERPG

- 1 is 2. Moreover, 8 of the 1 3 facilities show the potential for worst

- case acute HQ values greater than 1 based on the REL, 4 6 of the 1 3 facilities show the potential for worst

- case acute HQ values greater than or equal to 1 based on the AEGL

- 1 and 4 of the 1 3 facilities show the potential for worst

- case acute HQ values greater than or equal to 1 based on the ERPG

- 1. 21 Nevertheless, it is important to note that all the

21 Individual facility acute HQ values for all facilities can be found in Appendix 5, Table 4, of the risk assessment document that is included in the docket for this proposed rulemaking. Acute HQ values exceeding a value of 1 based on the REL were as follows: 10, 10, 9, 9, 5, 3, 2 and 2. Acute HQ values greater than a value of 1 based on the AEGL

- 1 were as follows: 4, 4, 3 and 3 . Acute HQ values greater than or equal to a value of 1 based on the ERPG

- 1 were as follows: 2, 2, 1 and 1.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 80 of 149

w orst

- case acute HQs are based on conservati ve assumptions (e.g.,
worst

- case meteorology coinciding with peak short

- term one - hour emissions from each emission point , with a person located at the point of max imum concentration during that hour )
. In addition to the analyses presented above, to screen for potential multi

- pathway effects from emissions of POM , we compared the estimated actual PAH emission rates from 14 facilities in this source category to the multi

- pathway screening rate for PAHs des cribed in section III.B . Resul ts of this worst

- case screen estimate that actual PAH emissions from all 14 facilities exceed the
PAH multi

- pathway screening rate. With respect to these exceeda nces of the worst

- case multi

- pathway screening rate for PAHs, we note that this only indicates the potential for mult i

- pathway

- related cancer risks of concern from PAHs. Moreover, d ue to data limitations, we were not able to refine our multi

- pathway analysis beyond the wo rst

case screening assessment. Thus, we note that these results are biased high for purposes of scree ning and are subject to significant uncertainties. As such, they do not necessarily indicate that multi

pathway risks from POM are significant, only that we cannot rule out the possibility that they might be significant.
C. What are our proposed decisions regarding risk acceptability and ample margin of safety ? 1. Risk acceptability*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 81 of 149
A s noted in section III.C of this preamble, we weigh all health risk factors in our risk acceptability determination, including the MIR, the numbers of persons in various risk ranges, cancer incidence, the maximum noncancer HI, the maximum acute noncancer hazard, the extent of noncancer risks, the potential for adverse environmental effects, distribution of risks in the exposed population, and risk estimation uncertainties (54 F R 38044, September 14, 1989). For the Primary Aluminum Re duction source category, the risk analysis we performed indicates that the cancer risk to the individual most exposed due to actual emissions is well below 100 in

one million , and the cancer incidenc e is low (1 case in every 200 years)
. T he potential risks due to allowable emissions are higher with an estimated MIR of up to 100 in one million which is the presumptive upper limit of acceptab le risk
. With regard to noncancer risks, the analysis indicate s that chronic noncancer health risks are negligible due to both actual and allowable emissions
. T he assessment o f potential acute noncancer effects (described in the previous section) suggests that there may be potential for some acute risks due to HF emissions with worst

- case HQ s up to 10 (based on the REL). In characterizing the potential for acute noncancer impacts of concern, it is important to remember the upward bias of these wors t

- case exposure estimates and to consider the results along with the rather large uncertainties related to the emissions estimates and screening methodology
.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 82 of 149 With regard to multi

- pathway exposures and risks, r esul ts of the screening analysis indicate that actual PAH emissions from all the facilities exceed the worst

- case multi

- pathway screening rate for
PAHs , indicat ing the potential for possible multi

- pathway

- related cancer risks of concern from PAHs. We note that t hese screening results do not necessar il y indicate that significant multi

- pathway risks actual ly exist at primary al uminum facilities , only that we cannot rule them out as a possibility
. Overall, i n determining whether risk is acceptable, we considered all the available health risk information, a s described above
. In this case, because the MIR s due to actual emissions are well below 100

- in

- 1 million risk, and since the one facility that could pose possible risks due to allowable emissions of up to 100 in

one million is not operating, and because a number of other factors indicate relatively low risk concern ( e.g. , low cancer incidence and low potential for chronic noncancer risks ) , and given the conservative, worst

- case screening level characteristics of the acute and multi

- pathway assessments , an d various uncertainties, we are proposing to determine that the risks due to HAP emissions from this source category are acceptable
. 2
. Ample m argin of s afety analysis
W e next considered whether the existing MACT standard provides an ample margin of safety (AMOS)
. Under the ample margin of safety analysis, we evaluate the cost and feasibility of available control*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 83 of 149 technologies and other measures (including the controls, measures and costs reviewed under the technology review) that could be applied in this so urce category to further reduce the risks (or potential risks) due to emissions of HAP identified in our risk assessment , along with all of the health risks and other health information considered in the risk acceptability determination described above
. First, we evaluated the feasibility to reduce the potential risks due to allowable POM emissions from Soderberg facilities. As described above, the potential cancer MIR from Soderberg facilities is estimated to be up to 100 in one million due to allowable emissions
. These risks are driven by POM emissions from a Soderberg facility within the vertical stud Soderberg ( VSS2 ) subcategory. The current emissions limit (from the 2005 NESHAP amendments) for POM from potlines in this VSS2 subcategory is 2.85 kg of P OM per Mg of Aluminum produced (2.85 kg/Mg, or 5.7 lbs/ton). Based on site

specific emissions data submitted by the company in early 2008 for this facility, the estimated actual emissions from this facility were about 2 lbs/ton during the most recent years of operation (see
Document EPA

- HQ

- OAR

- 2002

- 0031

- 0029, which is available in the docket for this rulemaking). After considering variability in emissions, which is appropriate for establishing MACT limits (as described in s ection III.A above), we calculate d , using a 99% upper prediction level approach, that an emissions limit of 3.8 lbs/ton could be achieved by this facility*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 84 of 149 without any additional controls and therefore no additional costs. This would result in a reduction of approximately 33 percent for the allowable emissions from VSS2 potlines, and would reduce the potential cancer MIR due to allowable emissions to about 70 in one million. We also evaluated potential controls to reduce these risks further (such as requiring wet roof scrubbers)
. W e determin ed that these controls would be quite costly (approximately $4 million per ton of organic HAP) , with estimated capital costs of about $40 million for this one facility , and would only achieve about an additional 9.6 tons of HAP per year ( 30 percent ) reduct ion in POM emissions . These controls and costs are described in more detail below. We also evaluated the POM emissions from the one operating Soderberg facility (which is in the HSS subcategory) as part of our
AMOS analyses
. Based on the risk assessment, w e estimated that this facility posed a cancer MIR of up to 30 in one million based on actual emissions and an MIR of up to 50 in one million based on allowable emissions. The current emissions limit for POM from potlines for this HSS subcategory is 2.35 kg/Mg (or 4.7 lbs/ton). Based on site specific emissions data for this facility, the actual emissions from this facility are estimated to be about 1.5 lbs/ton. After conside ring variability in emissions, we determined that an emissions limit of 3.0 lbs/ton could be achieved by this facility with no additional controls and , therefore , no additional costs. This*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 85 of 14 9 would result in a reduction of approximately 36 percent for the all owable emissions from these HSS potlines, and would reduce the potential cancer MIR due to allowable emissions from this facility to about 30 in one million. We identified wet roof scrubbers as one possible control technology that could be applied to furth er reduce allowable and actual emissions of POM from potline s , to reduce the cancer risks due to actual and allowable POM emissions , and to reduce the potential risks due to multi

- pathway exposures to POM. One facility in the source category currently has this type of scrubber. These controls can also be used to reduce HF emissions and , thus , would reduce the potential for acute noncancer risks. However, the costs for the se controls are high. For example, we estimate that the capital costs for the typical f acility would be more than $ 40 million , with annualized costs of $ 13 million
. Industry wide this would result in total capital costs of over $ 400 million , w ith estimated annualized costs of over $ 150 million
. These controls would achieve reductions of secondary emissions of about 30 to 50 percent. Given the high
costs (estimated at approximately $140,000 per ton of HAP) and relatively low emissions and risk reductions, we propose conclude that it is not appropriate or necessary to establish propose these additional controls under 112(f)(2). Therefore, based our AMOS analysis, we are proposing under section 112(f)(2) of the CAA to lower the POM emissions limit for VSS2 potlines from 5.7 to 3.8*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 86 of 149 lbs/ton and to lower reduce the POM limit for HSS potlines from 4 .7 to 3.0 lbs/ton. Pursuant to CAA section 112(f)(4), we are proposing that these changes apply 90 days after the effective date of this rulemaking. We did not identify any other cost

- effective controls to further reduce HAP emissions for this source categ ory under the AMOS analyses
. I n accordance with the approach established in the Benzene NESHAP, the EPA weighed all health risk measures and information considered in the risk acceptability determination, along with the costs and economic impacts of emissi ons controls, technolog ical feasibility, uncertainties and other relevant factors in proposing making our ample margin of safety determination. Considering the health ris k information and the costs of the option s identified, we propose that the existing MAC T standards, along with the proposed lower POM limits for potlines at Soderberg facilities (VSS2 and HSS subcategories) described above, will provide an ample margin of

sa fety to protect public health. Pursuant to CAA section 112(f)(4), we are proposing th at these changes ( i.e. , lower emission limits for potlines at Soderberg facilities) apply 90 days after the effective date of this rulemaking. See CAA section 112(f)(4)(A). Nevertheless, w e solicit comment and information on the feasibility, costs and appropriateness of any additional controls or*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 87 of 149 options to further reduce the potential risks due to emissions of
HAP , especially POM and or HF . D . What are the results and proposed decisions based on our technology review ? As described above, dry alumina scrubbers (with baghouses) are the typical controls used to minimize primary emissions of HF and POM from the potlines
. However, some facilities use wet scrubbers and ESPs to control these emissions
. The MACT control technol ogy typically used for anode bake furnaces is also a dry alumina scrubber, and a capture system vented to a dry coke scrubber is used for control of paste production plants
. These facilities further reduce HAP emissions from anode bake furnaces by implementation of certain practices during periods of startup (e.g., development of an anode bake furnace startup schedule, operation of the associated control system(s) within norma l parametric limits prior to the startup of the anode bake furnace)
. To further control potline secondary emissions, one facility has wet roof scrubbers to get additional control of HF and POM. As described in the AMOS section above, it would be quite cost ly to require wet roof scrubbers on other facilities.
O verall, b ased on our technology review, w e determined that there have been no developments in practices, processes, and control technologies that would be considered feasible and cost

- effective to appl y to this source category since promulgation of the Primary*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 88 of 149 Aluminum Reduction Plant NESHAP , other than the anode bake furnace startup practices mentioned above
. We propose to modify the MACT requirements for anode bake furnaces to include implementation o f the startup practices mentioned above
. Further , based on an analysis of recent emission s data, we believe that the practices, processes and control technologies currently in use by this source category allow for a reduction in the POM emission limits for Soderberg potlines (please refer to the ample margin of safety analysis in section IV.C.2 of this preamble). Additional details regarding these analyses can be found in the following technical document for this action which is available in the docket: Dra ft Technology Review for the Primary Aluminum Reduction Plant Source Category . E . What other actions are we proposing? 1. Startup, shutdown and m alfunction s The United States Court of Appeals for the District of Columbia Circuit vacated portions of two provisions in the EPA ‘s CAA section 112 regulations governing the emissions of HAP during periods of startup, shutdown and malfunction (SSM). Sierra Club v. EPA , 551 F.3d 1019 (D.C. Cir. 2008), cert. denied , 130 S. Ct. 1735 (U.S. 2010)
. Specifically, the Court vacated the SSM exemption contained in 40 CFR 63.6(f)(1) and 40 CFR 63.6(h)(1), that are part of a regulation, commonly referred to as the ―General Provisi ons Rule,‖ that the EPA promulgated under CAA section 112. When incorporated into CAA section*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 89 of 149 112(d) regulations for specific source categories, these two provisions exempt sources from the requirement to comply with the otherwise applicable CAA section 11 2(d) emissions standard during periods of SSM. We are proposing the elimination of the SSM exemption in this rule. Consistent with Sierra Club v. EPA , the EPA is proposing standards in this rule that apply at all times. We are also proposing several revisi ons to Appendix A to subpart LL of p art 63 (the General Provisions Applicability table). For example, we are proposing to eliminate the incorporation of the General Provisions‘ requirement that the source develop an SSM plan. We also are proposing to elimi nate or revise certain recordkeeping and reporting requirements related to the SSM exemption. The EPA has attempted to ensure that we have not included in the proposed regulatory language any provisions that are inappropriate, unnecessary, or redundant in the absence of the SSM exemption. We are specifically seeking comment on whether there are any such provisions that we have inadvertently incorporated or overlooked. In proposing the standards in this rule, the EPA has taken into account startup and shutdo wn periods and, for the reasons explained below, the EPA is propos ing in some cases different standards for startup periods.
T h e 1997 MACT rule allow ed for periods of up to six months for startup of existing potlines that ha d been previously shutdown
. These*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 90 of 149 long startup periods for potlines are recognized as part of the normal operations during which emissions testing is not feasible
. The current MACT emission limits are not applicable during these startup periods
. Thus, we are proposing MACT standards for these periods in today‘s action. Given that it is economically and technically infeasible to measure emissions during these startup periods, we are proposing detailed work practice standards that will minimize HAP emissions and ensure proper operation of the processes and control equipment during startup periods
. The proposed work practices include b ring ing the potline scrubbers and exhaust fans on line prior to energizing the first cell being restarted , e nsur ing that the primary capture and control sys tem is operating at all times during startup, and k eep ing pots covered during startup as much as practicable to include , but not limited to , minimizing the removal of covers or panels of the pots on which work is being performed
. Moreover, facilities must i nspect potlines daily during startup and perform additional work practices , including r eseal ing pot crust as often and as soon as practicable , r educ ing cell temperatures to as low as practicable , and a djust ing pot parameters to their optimum levels to include , but not limited to , the following parameters: alumina addition rate, exhaust air flow, cell voltage, feeding level, anode current, and liquid and solid bath levels.
T h e 1997 MACT rule allow ed for startup periods for new or reconstructed anode bake furnaces and pitch storage tanks and for*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 91 of 149
anode bake furnaces that ha d been previously shutdown
. Based on information received from industry, we believe that these sources can comply with the ir MACT standard s duri ng startup periods. T herefore, we are removing the provisions for startup of anode bake furnaces and pitch storage tanks . However, we have added startup work practices for anode bake furnace startup periods to help ensure that the standards will be are met. These startup work practices will minimize HAP emissions and ensure proper operation of the processes and control equipment during startup periods (please refer to the discussion of the technology review in section IV.D of this preamble)
. Sh u tdown emissions are not expected to be different from those during normal operation; therefore, no separate standard or work practice is warranted
. We propose that the numerical MACT limits described in previous sections of this preamble (established for

n ormal operations) will apply during shutdown periods. We also propose that the MACT limits for all other affected units besides potlines (bake furnaces, pitch tanks, and paste production plants ) apply at all times, including during startups and shutdowns.
I nformation on periods of startup and shutdown received from the industry indicate that emissions during startup (except for potlines) and shutdown periods are no greater than emissions during normal operations. Therefore, the continued operation of the ex isting control devices and emission capture systems will, in conjunction with the detailed proposed startup practices and work practices*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 92 of 149 described above , be consistent with maximum achievable control technology and will be adequate , along with all the othe r standards described above, to ensure that risks will be acceptable and the rule will provide an ample margin of safety
. Periods of startup, normal operations, and shutdown are all predictable and routine aspects of a source‘s operations. However, by
cont rast, malfunction is defined as a ―sudden, infrequent, and not reasonably preventable failure of air pollution control and monitoring equipment, process equipment or a process to operate in a normal or usual manner * * *‖ (40 CFR 63.2). The EPA has determi ned that CAA section 112 does not require that emissions that occur during periods of malfunction be factored into development of CAA section 1 12 standards . Under CAA section 112, emissions standards for new sources must be no less stringent than the level ―achieved‖ by the best controlled similar source and for existing sources generally must be no less stringent than the average emissions limitation ―achieved‖ by the best performing 12 percent of sources in the category . There is nothing in CAA section 112 that directs the a gency to consider malfunctions in determining the level ―achieved‖ by the best performing or best controlled sources when setting emissions standards. Moreover, while the EPA accounts for variability in setting emissions stand ards consistent with the CAA section 112 case law, nothing in that case law requires the a gency to consider malfunctions as part of that analysis. Section 112 of the CAA uses*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 93 of 149 the concept of ―best controlled‖ and ―best performing‖ unit in defining the level of stringency that CAA section 112 performance standards must meet. Applying the concept of ―best controlled‖ or ―best performing‖ to a unit that is malfunctioning presents significant difficulties, as malfunctions are sudden and unexpected
events. Furthe r, accounting for malfunctions would be difficult, if not impossible, given the myriad different types of malfunctions that can occur across all sources in the category and given the difficulties associated with predicting or accounting for the frequency, degree, and duration of various malfunctions that might occur. As such, the performance of units that are malfunctioning is not ―reasonably‖
foreseeable. See, e.g., Sierra Club v
. EPA , 167 F. 3d 658, 662 (D.C. Cir. 1999) (EPA typically has wide latitude in determining the extent of data

- gathering necessary to solve a problem. We generally defer to an agency's decision to proceed on the basis of imperfect scientific information, rather than to "invest the resources to conduct the perfect study."). See also , Weyerhaeuser v
. Costle , 590 F.2d 1011, 1058 (D.C. Cir. 1978) (―In the nature of things, no general limit, individual permit, or even any upset provision can anticipate all upset situations. After a certain point, the transgression of regulatory limits caus ed by  ̳uncontrollable acts of third parties,‘ such as strikes, sabotage, operator intoxication or insanity, and a variety of other eventualities, must be a matter for the Formatted: No underline*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 94 of 149 administrative exercise of case

- by

- case enforcement discretion, not for specification in advance by regulation‖). In addition, the goal of a best controlled or best performing source is to operate in such a way as to avoid malfunctions of the source , and accounting for malfunctions could lead to standards that are significantly less string ent than levels that are achieved by a well

- performing non

malfunctioning source. The EPA‘s approach to malfunctions is consistent with CAA section 112 and is a reasonable interpretation of the statute. In the event that a source fails to comply with the a pplicable CAA section 112(d) standards as a result of a malfunction event, the
EPA would determine an appropriate response based on, among other things, the good faith efforts of the source to minimize emissions during malfunction periods, including preven tative and corrective actions, as well as root cause analyses to ascertain and rectify excess emissions. The EPA would also consider whether the source's failure to comply with the CAA section 112(d) standard was, in fact, ―sudden, infrequent, not reasonab ly preventable‖ and was not instead ―caused in part by poor maintenance or careless operation‖ 40 CFR 63.2 (definition of malfunction). Finally, the EPA recognizes that even equipment that is properly designed and maintained can sometimes fail and that suc h failure can sometimes cause an exceedance of the relevant emissions standard. ( See, e.g., State Implementation Plans: Policy Regarding Excessive*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 95 of 149 Emissions During Malfunctions, Startup, and Shutdown (Sept. 20, 1999); Policy on Excess Emissions During Star tup, Shutdown, Maintenance, and Malfunctions (Feb. 15, 1983)). The EPA is therefore proposing to add to the final rule an affirmative defense to civil penalties for exceedances of emissions limits that are caused by malfunctions. See 40 CFR 63. 842 (defining ―affirmative defense‖ to mean, in the context of an enforcement proceeding, a response or defense put forward by a defendant, regarding which the defendant has the burden of proof, and the merits of which are independently and objectively evalua ted in a judicial or administrative proceeding). We also are proposing other regulatory provisions to specify the elements that are necessary to establish this affirmative defense; the source must prove by a preponderance of the evidence that it has met al l of the elements set forth in 40 CFR 63. 8 55 (see also 40 CFR 22.24) . The criteria ensure that the affirmative defense is available only where the event that causes an exceedance of the emissions limit meets the narrow definition of malfunction in 40 CFR 6 3.2 (sudden, infrequent, not reasonabl y preventable and not caused by poor maintenance and or careless operation). For example, to successfully assert the affirmative defense, the source must prove by a preponderance of the evidence that excess emissions ― [w] ere caused by a sudden, infrequent, and unavoidable failure of air pollution control and monitoring equipment, process equipment, or a process to operate in a normal or usual manner ....‖ The criteria also are designed*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 96 of 149 to ensure that steps are taken to cor rect the malfunction, to minimize emissions in accordance with 40 CFR sections 63. 843 ( f ) and 63. 844(f) to prevent future malfunctions. For example, the source
must prove by a preponderance of the evidence that ―[r] epairs were made as expeditiously as possi ble when the applicable emissions limitations were being exceeded ...‖ and that ―[a] ll possible steps were taken to minimize the impact of the excess emissions on ambient air quality, the environment and human health ....‖ In any judicial or administrative proce eding, the Administrator may challenge the assertion of the affirmative defense and, if the respondent has not met its burden of proving all of the requirements in the affirmative defense, appropriate penalties may be assessed in accordance with CAA

s ectio n 113 (see also 40 CFR 22 .27 ).

The EPA included an affirmative defense in the proposed rule in an attempt to balance a tension, inherent in many types of air regulation, to ensure adequate compliance while simultaneously recognizing that despite the most diligent of efforts, emission limits may be exceeded under circumstances beyond the cont rol of the

source. The EPA must establish emission standards that ―limit the quantity, rate, or concentration of emissions of air pollutants on a continuous basis.‖ 42 U.S.C. §7602(k)(defining ―emission limitation and emission standard‖). See generally Sie rra Club v. EPA , 551 F.3d 1019, 1021 (D.C. Cir. 2008) Thus, the EPA is required to ensure that section 112 emissions limitations are continuous. The affirmative*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 97 of 149
defense for malfunction events meets this requirement by ensuring that even where there is a ma lfunction, the emission limitation is still enforceable through injunctive relief. While ―continuous‖ limitations, on the one hand, are required, there is also case law indicating that in many situations it is appropriate for EPA to account for the practic al realities of technology. For example, in Essex Chemical v. Ruckelshaus , 486 F.2d 427, 433 (D.C. Cir. 1973), the D.C. Circuit acknowledged that in setting standards under CAA section 111 ―variant provisions‖ such as provisions allowing for upsets during startup, shutdown and equipment malfunction ―appear necessary to preserve the reasonableness of the standards as a whole and that the record does not support the  ̳never to be exceeded‘ standard currently in force.‖ See also, Portland Cement Association v. Ruckelshaus, 486 F.2d 375 (D.C. Cir. 1973) . Though intervening

case law such as Sie rra Club v. EPA and the CAA 1977 amendments undermine the relevance of these cases today, they support the EPA‘s view that a system that incorporates some level of flexibility is reasonable. The affirmative defense simply provides for a defense to civil pe nalties for excess emissions that are proven to be beyond the control of the source. By incorporating an affirmative defense, the EPA has formalized its approach to upset events. In a Clean Water Act setting, the Ninth Circuit required this type of formali zed approach when regulating ―upsets beyond the control of the permit holder.‖ Marathon Oil Co. v. EPA , 564 F.2d 1253, 1272

- 73 (9 th Cir. 1977). But see, Weyerhaeuser Co. v. Costle , 590 F.2d 1011, 1057

- 58 (D.C. Cir.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 98 of 149
1978) (holding that an informal approach is adequate). The affirmative defense provisions give the EPA the flexibility to both ensure that its emission limitations are ―continuous‖ as required by 42 U.S.C. § 7602(k), and account for unplanned upsets and thus support the reasonableness of the stan dard as a whole. Specifically, we are proposing the following rule changes :

 Add general duty requirements in 40 CFR sections 63.843 and 63.844 to replace General Provision requirements that reference vacated SSM provisions.

 Add replacement language that el iminates the reference to SSM exemptions applicable to performance tests in 40 CFR section 63.847(d)
.

 Add paragraphs in 40 CFR section 63.850 (d) requiring the reporting of malfunctions as part of the affirmative defense provisions.

 Add paragraphs in 40 CFR section 63.850(e) requiring the keeping of certain records during malfunctions as part of the affirmative defense provisions.

 Revise Appendix A to subpart LL of part 63 to reflect changes in the applicability of the General Provisi ons to this subpart resulting from a court vacatur of certain SSM requirements in the General Provisions. 2 . Electronic reporting.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 99 of 149
The EPA must have performance test data to conduct effective reviews of CAA sections 112 and 129 standards, as well as for many other purposes including compliance determinations, emissions factor development, and annual emissions rate determinations. In condu cting these required reviews, the EPA has found it ineffective and time consuming, not only for us, but also for regulatory agencies and source owners and operators, to locate, collect, and submit performance test data because of varied locations for data storage and varied data storage methods. In recent years, though, stack testing firms have typically collected performance test data in electronic format, making it possible to move to an electronic data submittal system that would increase the ease and ef ficiency of data submittal and improve data accessibility. Through this proposal the EPA is presenting a step to increase the ease and efficiency of data submittal and improve data accessibility . Specifically, the EPA is proposing that owners and operators of Primary Aluminum Reduction Plant facilities submit electronic copies of required performance test reports to the EPA ‘s WebFIRE database. The WebFIRE database was constructed to store performance test data for use in developing emissions factors. A desc ription of the WebFIRE database is available at
h ttp://cfpub.epa.gov/oarweb/index.cfm?action=fire.main
. As proposed above, data entry would be through an electronic emissions test report structure called the Electronic Reporting Tool.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 100 of 149 The ERT would be able to transmit the electronic report through the
EPA ‘s Central Data Exchange network for storage in the We bFIRE database making submittal of data very straightforward and easy. A description of the ERT can be found at http://www.epa.gov/ttn/chief/ert/ert

_ tool.html
. The proposal to submit performance test data electronically to the EPA would apply only to those performance tests conducted using test methods that will be supported by the ERT. The ERT contains a specific electronic data entry form for most of the commonly used EPA reference methods. A listing of the pollutants and test methods supported by the ERT is available at http://www.epa.gov/ttn/chief/ert/ert

_ tool.html . We believe that industry would benefit from this proposed approach to electronic data submittal. Having these data, the EPA would be able to develop improved emissions factors, make fewer inf ormation requests, and promulgate better informed regulations. One major advantage of the proposed submittal of performance test data through the ERT is a standardized method to compile and store much of the documentation required to be reported by this ru le. Another advantage is that the ERT clearly states what testing information would be required. Another important proposed benefit of submitting these data to the EPA at the time the source test is conducted is that it should substantially reduce the effo rt involved in data collection activities in the future. When the EPA has*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 101 of 149 performance test data in hand, there will likely be fewer or less substantial data collection requests in conjunction with prospective required residual risk assessments or technolog y reviews. This would result in a reduced burden on both affected facilities (in terms of reduced manpower to respond to data collection requests) and the EPA (in terms of preparing and distributing data collection requests and assessing the results).
Stat e, local, and tribal agencies could also benefit from more streamlined and accurate review of electronic data submitted to them. The ERT would allow for an electronic review process rather than a manual data assessment making review and evaluation of the s ource provided data and calculations easier and more efficient. Finally, another benefit of the proposed data submittal to WebFIRE electronically is that these data would greatly improve the overall quality of existing and new emissions factors by suppleme nting the pool of emissions test data for establishing emissions factors and by ensuring that the factors are more representative of current industry operational procedures. A common complaint heard from industry and regulators is that emissions factors ar e outdated or not representative of a particular source category. With timely receipt and incorporation of data from most performance tests, the EPA would be able to ensure that emissions factors, when updated, represent the most current range of operation al practices. In summary, in addition to supporting regulation development, control strategy development,*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 102 of 149 and other air pollution control activities, having an electronic database populated with performance test data would save industry, state, local, trib al agencies, and the EPA significant time, money, and effort while also improving the quality of emissions inventories and, as a result, air quality regulations. Records must be maintained in a form suitable and readily available for expeditious review, ac cording to 63.10(b)(1). Electronic recordkeeping and reporting is available for many records, and is the form considered most suitable for expeditious review if available. Electronic recordkeeping and reporting is encouraged in this proposal and some recor ds and reports are required to be kept in electronic format.
F . Compliance d ates We are proposing that existing facilities must comply with the proposed revised emissions limits for Soderberg potlines (which are being proposed under CAA sections 112(f)(2) for all affected sources) , no later than 90 days after the date of publication of the final rule. W e are proposing that existing facilities must comply with all other changes proposed in this action (other than affirmative defense provisions and electronic reporting which are effective upon promulgation of the final rule) no later than 3 years after the date of publication of the final rule. All new or reconstructed facilities must comply with all requirements in this rule u pon startup .*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 103 of 149 V. Summary of Cost, Environmental, and Economic Impacts
A. What are the affected sources ? The affected sources are new and existing potlines , new and existing pitch storage tanks , new and existing anode bake furnace s (except for one that is located at a facility that only pro duces anodes for use off

- site), and new and existing paste production plant s . B. What are the air quality impacts ? The proposed rule will require the POM emissions from existing uncontrolled pitch storage tanks to be reduced by a minimum of 95 percent . This is estimated to result in a reduction of 1.6 2 .3 tons
per year (tpy) of POM . In addition, the proposed lower Soderberg potline POM limits would reduce POM emissions from the two Soderberg facilities, assuming production at plant capacity, by approxim ately 300 tpy, combined. C. What are the cost impacts ? Under the proposed amendments, 8 facilities would be required to install or upgrade, and operate emissions control systems (such as activated carbon adsorbers or condensers ) to control emissions of HAP from pitch storage tanks at total estimated cost of $ 1 67 , 832 per year, or $2 0 , 979 per facility
. In addition, 12 facilities will have to conduct periodic perfo r mance tests for POM emissions from 45 prebake potlines at an estimated total cost of $ 9 0,000 per year for*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 104 of 149 the source category, or $ 7,5 00 per year per facility. The total estimated cost of the rule is $258,000 per year. D. What are the economic impacts ? We performed an economic impact analysis for the proposed modifications in this rulemaking . That analysis estimates total annualized costs of approximately $2 57 , 832 at 13 facilities and cost to revenue of less than 0.02% for the Primary Aluminum Production source category . For more information, please refer to the Draft Economic Impact Analysis for this proposed rulemaking that is available in the public docket for this proposed rulemaking
. E. What are the benefits? This proposed rule will achieve about 1.6 2.3 tons per year reductions in POM emissions , which may result in a slight health benefit
. emissions. The proposed limit s of 3.9 pounds of COS per ton of aluminum produced (lb COS/ton Al) for existing facilities and 3.1 lb COS/ton Al for new facilities will prevent increases in COS emissions and prevent increases in SO 2 emissions as a co

- benefi t. The proposed COS standard will likely result in the use of lower sulfur content coke in the anode production processes. This reduction in anode coke sulfur content would result in decreases in emissions of both COS and sulfur dioxide (SO 2 ). We estimate that SO 2 emissions will decrease by 12 tons for each ton of COS reduction. VI. Request for Comments*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 105 of 149 We are soliciting comments on all aspects of this proposed action. In addition to general comments on this proposed action, we are also interested in any ad ditional data that may help to reduce the uncertainties inherent in the risk assessments and other analyses. We are specifically interested in receiving corrections to the site

- specific emissions profiles used for risk modeling. Such data should include su pporting documentation in sufficient detail to allow characterization of the quality and representativeness of the data or information. Section VII of this preamble provides more information on submitting data. VII. Submitting Data Corrections The site

- specific emissions profiles used in the source category risk and demographic analyses are available for download on the RTR

w eb p age at: http://www.epa.gov/ttn/atw/rrisk/rtrpg.html . The data files include detailed information for each HAP emissions release point for the facility included in the source category. If you believe that the data are not representative or are inaccurate, please identify the data in question, provide your reason for concern, and provide any ―improved‖ data that you have, if available. When you submit data, we request that you provide documentation of the basis for the revised values to support your suggested changes. To submit comments on the data downloaded from the RTR Web page, complete the following steps:*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 106 of 149
1
. Within this downloaded file, enter suggested revisions to the data fields appropriate for that information. The data fields that may be revised include the following:

Data Element Definition Control Measu re Are control measures in place? (yes or no) Control Measure Comment Select control measure from list provided, and briefly describe the control measure Delete Indicate here if the facility or record should be deleted Delete Comment Describes the reason for deletion Emissions Calculation Method Code For Revised Emissions Code description of the method used to derive emissions. For example, CEM, material balance, stack test, etc. Emissions Process Group Enter the general type of emissions process associated with the specified emissions point
Fugitive Angle Enter release angle (clockwise from true North); orientation of the y

- dimension relative to true North, measured positive for clockwise starting at 0 degrees (maximum 89 degrees) Fugitive Length Enter dimension of the source in the east

west (x

- ) direction, commonly referred to as length (ft) Fugitive Width Enter dimension of the source in the north

south (y

- ) direction, commonly referred to as width (ft) Malfunction Emissions Enter total annual emissions due to malfunctions ( tpy ) Malfunction Emissions Max Hourly Enter maximum hourly malfunction emissions here (lb/hr)
North American Datum Enter datum for latitude/longitude coordinates (NAD27 or NAD83); if left blank, NAD83 is assumed Process Comment Enter general comments about process sources of emissions REVISED Address Enter revised physical street address for MACT facility here REVISED City Enter revised city name here REVISED County Name Enter revised county name here REVISED Emissions Release Point Type Enter revised Emissions Release Point Type here REVISED End Date Enter revised End Date here REVISED Exit Gas Flow Rate Enter revised Exit Gas Flowrate here (ft 3 /sec)*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 107 of 149
Data Element Definition REVISED Exit Gas Temperature Enter revised Exit Gas Temperature here (F) REVISED Exit Gas Velocity Enter revised Exit Gas Velocity here (ft/sec) REVISED Facility Category Code Enter revised Facility Category Code here, which indicates whether facility is a major or area source REVISED Facility Name Enter revised Facility Name here REVISED Facility Registry Identifier Enter revised Facility Registry Identifier here, which is an ID assigned by the EPA Facility Registry System REVISED HAP Emissions Performance Level Code Enter revised HAP Emissions Performance Level here REVISED Latitude Enter revised Latitude here (decimal degrees) REVISED Longitude Enter revised Longitude here (decimal degrees) REVISED MACT Code Enter revised MACT Code here REVISED Pollutant Code Enter revised Pollutant Code here REVISED Routine Emissions Enter revised routine emissions value here ( tpy ) REVISED SCC Code Enter revised SCC Code here REVISED Stack Diameter Enter revised Stack Diameter here (ft) REVISED Stack Height Enter revised Stack Height here (ft) REVISED Start Date Enter revised Start Date here REVISED State Enter revised State here REVISED Tribal Code Enter revised Tribal Code here REVISED Zip Code Enter revised Zip Code here Shutdown Emissions Enter total annual emissions due to shutdown events ( tpy ) Shutdown Emissions Max Hourly Enter maximum hourly shutdown emissions here (lb/hr) Stack Comment Enter general comments about emissions release points Startup Emissions Enter total annual emissions due to startup events ( tpy ) Startup Emissions Max Hourly Enter maximum hourly startup emissions here (lb/hr) Year Closed Enter date facility stopped operations 2. Fill in the commenter information fields for each suggested revision (i.e., commenter name, commenter organization, commenter email address, commenter phone number, and revision comments).*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 108 of 149 3. Gather documentation for any suggested emissions revisions (e.g., performance test reports, material balance calculations). 4. Send the entire downloaded file with suggested revisions in Mic rosoft® Access format and all accompanying documentation to Docket ID Number EPA

- HQ

- OAR

- 2011

- 0797 (through one of the methods described in the ADDRESSES section of this preamble). To expedite review of the revisions, it would also be helpful if you submitt ed a copy of your revisions to the EPA directly at RTR@epa.gov in addition to submitting them to the docket. 5. If you are providing comments on a facility, you need only submit one file for that facility, which should cont ain all suggested changes for all sources at that facility. We request that all data revision comments be submitted in the form of updated Microsoft® Access files, which are provided on the RTR Web Page at: http://www.epa.gov/ttn/atw/rrisk/rtrpg.html
. V III . Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review and Executive Order 13563: Improving Regulation and Regulatory Review Under Executive Order 12866 (58 FR 51735, October 4, 1993), this action is a significant regulatory action because it raises novel legal and policy issues. Accordingly, the EPA submitted this action to the Office of Management and Budget (OMB) for review under Executive Order s 12866 and 13563 (76 FR 3821, January 21, 2011) and*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 1 09 of 149 any changes made in response to OMB recommendations have been documented in the docket for this action
. B. Paperwork Reduction Act. The information collection requirements in this rule have been submitted for approval to the Office of Management and Budget (OMB) under the Paperwork Reduction Act , 44 U.S.C. 3501 et seq . The Information Collection Request (ICR) document prepared by the E PA has been assigned the EPA ICR number 2447.01
. The information collection requirements are not enforceable until OMB approves them. The information requirements are based on notification, recordkeeping, and reporting requirements in the NESHAP General Pr ovisions (40 CFR part 63, subpart A), which are mandatory for all operators subject to national emissions standards. These recordkeeping and reporting requirements are specifically authorized by CAA section 114 (42 U.S.C. 7414). All information submitted t o the EPA pursuant to the recordkeeping and reporting requirements for which a claim of confidentiality is made is safeguarded according to a gency policies set forth in 40 CFR part 2, subpart B. We are proposing new paperwork requirements for to the Primary Aluminum Reduction Plant source category in the form of a one - time requirement to prepare design specifications for existing pitch storage tank controls , and submissions of test reports and calculations for demonstration of compliance with prebake potline POM limits
.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 110 of 149
For th is proposed rule, the EPA is adding affirmative defense to the estimate of burden in the ICR. To provide the public with an estimate of the relative magnitude of the burden associated with an assertion of the affirmative defense position adopted by a source, the EPA has provided administrative adjustments to this ICR to show what the notification, recordkeeping and reporting requirements associated with the assertion of the affirmative defense might entail. The EPA‘s estimate for the requ ired notification, reports and records for any individual incident, including the root cause analysis, totals $ 3,141 and is based on the time and effort required of a source to review relevant data, interview plant employees, and document the events surrou nding a malfunction that has caused an exceedance of an emissions limit. The estimate also includes time to produce and retain the record and reports for submission to the EPA
. The EPA provides this illustrative estimate of this burden because these costs are only incurred if there has been a violation and a source chooses to take advantage of the affirmative defense. Given the variety of circumstances under which malfunctions could occur, as well as differences among sources' operation and maintenance prac tices, we cannot reliably predict the severity and frequency of malfunction

- related excess emissions events for a particular source. It is important to note that the EPA has no basis currently for estimating the number of malfunctions that would qualify fo r an affirmative defense. Current historical records would*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 111 of 149 be an inappropriate basis, as source owners or operators previously operated their facilities in recognition that they were exempt from the requirement to comply with emissions standards during mal functions. Of the number of excess emissions events reported by source operators, only a small number would be expected to result from a malfunction (based on the definition above), and only a subset of excess emissions caused by malfunctions would result in the source choosing to assert the affirmative defense. Thus we believe the number of instances in which source operators might be expected to avail themselves of the affirmative d efense will be extremely small.
W ith respect to the Primary Aluminum Production source categor y , the emissions controls are operational before the associated emission source(s) commence operation and remain operational until after the associated emission source(s) cease operation. Also, production operations would not proce ed or continue if there is a malfunction of a control device and the time required to shut down production operations (i.e., on the order of a day) is small compared to the averaging time of the emission standards (i.e., monthly, quarterly and annual avera ges). T hus, we believe it is unlikely that a control device malfunction would cause an exceedance of any emission limit. Therefore, sources within th is source categor y are not expected to have any need or use for the affirmative defense and we believe that there is no burden to the industry for the affirmative defense provisions in the proposed rule.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 112 of 149 We expect to gather information on such events in the future and will revise this estimate as better information becomes available. We estimate 15 regulate d entities are currently subject to subpart LL and will be subject to all proposed standards. The annual monitoring, reporting, and recordkeeping burden for this collection (averaged over the first 3 years after the effective date of the standards) for the se amendments to subpart LL is estimated to be $ 148,000 per year. This includes 1,558 labor hours per year at a total labor cost of $148,000 per year, and total non

- labor capital and operation and maintenance (O&M) costs of $ 500 per year. This estimate inc ludes performance tests, notifications, reporting, and recordkeeping associated with the new requirements for existing pitch storage tanks and new and existing potlines . The total burden for the Federal government (averaged over the first 3 years after the effective date of the standard) is estimated to be 120 hours per year at a total labor cost of $ 11,400 per year. Burden is defined at 5 CFR 1320.3(b). An agency may not conduct or sponsor, and a person is not required to respond to, a collection of inform ation unless it displays a currently valid OMB control number. The OMB control numbers for the EPA 's regulations in 40 CFR are listed in 40 CFR part 9. When these ICRs are approved by OMB, the a gency will publish a technical amendment to 40 CFR part 9 in the Federal Register to display the OMB control numbers for the approved information collection requirements contained in the final rules.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 113 of 149
To comment on the a gency's need for this information, th e accuracy of the provided burden estimates, and any suggested methods for minimizing respondent burden, the EPA has established a public docket for this rule, which includes this ICR, under Docket ID number
EPA

- HQ

- OAR

- 2011

- 0797 . Submit any comments relate d to the ICR to the
EPA and OMB. S ee the ADDRESSES section at the beginning of this notice for where to submit comments to the EPA . Send comments to OMB at the Office of Information and Regulatory Affairs, Office of Management and Budget, 725 17th Street, NW, Washington, DC 20503, Attention: Desk Office for the EPA . Since OMB is required to make a decision concerning the ICR between 30 and 60 days after [ INSERT THE
DATE OF PUBLICATION OF THIS PROPOSED RULE IN THE FEDERAL REGISTER ], a comment to OMB is best assured of having its full effect if OMB receives it by [ INSERT THE DATE 30 DAYS AFTER THE DATE OF PUBLICATION
IN THE FEDERAL REGISTER ] . The final rule will respond to any OMB or public comments on the information collection requirements contained in this proposal. C. Regulatory Flexibility Act. The Regulatory Flexibility Act (RFA) generally requires an agency to prepare a regulatory flexibility analysis of any rule subject to notice and comment rulemaking requirements under the Administrative Procedure Act or any other statute unless the agency certifies that the rule will not have a significant economic impact on a substantial number of small entities. Small entities include*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 114 of 149 small businesses, small organizations, and small governmental jurisdictions. For p urposes of assessing the impacts of this proposed rule on small entities, small entity is defined as: (1) a small business as defined by the Small Business Administration‘s (SBA) regulations at 13 CFR 121.201; (2) a small governmental jurisdiction that is a government of a city, county, town, school district or special district with a population of less than 50,000; and (3) a small organization that is any not

- for

- profit enterprise that is independently owned and operated and is not dominant in its field.
F or this source category, which has the N AICS code 331312 , the SBA small business size standard is 1,000 employees according to the SBA small business standards definitions
. There are no small entities subject to subpart LL. After considering the economic i mpacts of today‘s proposed rule on small entities, I certify that this action will not have a significant economic impact on a substantial number of small entities. This proposed rule will not impose any requirements on small entities. We continue to be in terested in the potential impacts of the proposed rule on small entities and welcome comment on issues related to such impacts. D. Unfunded Mandates Reform Act. This proposed rule does not contain a Federal mandate under the provisions of Title II of the Unfunded Mandates Reform Act of 1995*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 115 of 149 (UMRA), 2 U.S.C. 1531

- 1538 for State, local, or tribal governments or the private sector. The proposed rule would not result in expenditures of $100 million or more for State, local, and tribal governments, in aggregate , or the private sector in any 1 year. The proposed rule imposes no enforceable duties on any State, local or tribal governments or the private sector. Thus, this proposed rule is not subject to the requirements of sections 202 or 205 of the UMRA. This pro posed rule is also not subject to the requirements of section 203 of UMRA because it contains no regulatory requirements that might significantly or uniquely affect small governments because it contains no requirements that apply to such governments nor do es it impose obligations upon them. E. Executive Order 13132: Federalism. This proposed rule does not have federalism implications. It will not have substantial direct effects on the States, on the relationship between the national government and the State s, or on the distribution of power and responsibilities among the various levels of government, as specified in Executive Order 13132. None of the facilities subject to this action are owned or operated by State governments, and, because no new requirement s are being promulgated, nothing in this propos ed rule will supersede State regulations. Thus, Executive Order 13132 does not apply to this proposed rule. In the spirit of Executive Order 13132, and consistent with the
EPA policy to promote communications between the EPA and State and*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 116 of 149 local governments, the EPA specifically solicits comment on this proposed rule from State and local officials. F. Executive Order 13175: Consultation and Coordination with Indian Tribal Governments.
T his proposed rule does not have tribal implications, as specified in Executive Order 13175 (65 FR 67249, November 9, 2000)
. None of the provisions of this proposed rule will result in increase d emissions of any hazardous air pollutant from any facility. The more stringent limitatio ns of POM emissions from horizontal stud Soderberg potlines may result in decreased risk to Indian tribal populations. Thus, Executive Order 13175 does not apply to this action. The EPA specifically solicits additional comment on this proposed action from tribal officials. G. Executive Order 13045: Protection of Children from Environmental Health Risks and Safety Risks. This proposed rule is not subject to Executive Order 13045 (62 FR 19885, April 23, 1997) because it is not economically significant as defi ned in Executive Order 12866. Moreover, the a gency does not believe the environmental health risks or safety risks addressed by this action present a disproportionate risk to children. Nevertheless, the public is invited to submit comments or identify
peer - reviewed studies and data that assess effects of early life exposure to HAP from Primary Aluminum sources. The EPA will typically*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 117 of 149 accord greater weight to studies and data that have been peer reviewed. H. Executive Order 13211: Actions Concerning Regulations That Significantly Affect Energy Supply, Distribution, or Use. This action is not a ―significant energy action‖ as defined under Executive Order 13211, ―Actions Concerning Regulations That Significantly Affect Energy Supply, Distribution, or Us e‖ (66 FR 28355, May 22, 2001), because it is not likely to have significant adverse effect on the supply, distribution, or use of energy. This action will not create any new requirements and therefore no additional costs for sources in the energy supply, distribution, or
use sectors. I. National Technology Transfer and Advancement Act. Section 12(d) of the National Technology Transfer and Advancement Act of 1995 (―NTTAA‖), Public Law No. 104

- 113 (15 U.S.C. 272 note), directs the EPA to use voluntary consensus standards (VCS) in its regulatory activities unless to do so would be inconsistent with applicable law or otherwise impractical. VCS are technical standards (e.g., materials specifications, test methods, sampling procedures, and business practices) that are developed or adopted by voluntary consensus standards bodies. NTTAA directs the EPA to provide Congress, through OMB, explanations when the a gency decides not to use available and applicable VCS.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 118 of 149 This proposed rulemaking invo lves technical standards. The EPA proposes to use ASTM D3177

- 02 (2007) Standard Test Methods for Total Sulfur in the Analysis Sample of Coal and Coke. This is a voluntary consensus method. This method can be obtained from the American Society for Testing a nd Materials, 100 Bar Harbor Harbour Drive, West Conshohocken, Pennsylvania 19428 (tel ephone number (610) 832

- 9500). This method was proposed because it is commonly used by primary aluminum reduction facilities to demonstrate compliance with sulfur dioxide emission limitations imposed in their current Title V permits. T he EPA welcomes comments on this aspect of this proposed rulemaking and, specifically, invites the public to identify potentially

- applicable voluntary consensus standards and to explain why su ch standards should be used in this regulation. J. Executive Order 12898: Federal Actions to Address Environmental Justice in Minority Populations and Low

- Income Populations
. Executive Order 12898 (59 FR 7629, February 16, 1994) establishes Federal executi ve policy on environmental justice. Its main provision directs Federal agencies, to the greatest extent practicable and permitted by law, to make environmental justice part of their mission by identifying and addressing, as appropriate, disproportionately high and adverse human health or environmental effects of their programs, policies, and activities on minority populations and low

- income populations in the United States.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 119 of 149 For the primary aluminum source category, EPA has determined that the current health risks posed to anyone by actual emissions from this source category are within the acceptable range, and that the proposed rulemaking will not appreciably reduce these risks further. As a result, this proposed rule will not have disproportionately high an d adverse human health or environmental effects on minority or low

- income populations.
T o examine the potential for any environmental justice issues that might be associated with each source category, we evaluated the distributions of HAP

- related cancer an d non

- cancer risks across different social, demographic, and economic groups within the populations living near the facilities where this source category is located. The methods used to conduct demographic analyses for this rule are described in the document Draft Residual Risk Assessment for the Primary Aluminum Reduction Plant Source Category which may be found in the docket for this rulemaking . The development of demographic analyses to inform the consideration of environmental justice issues i n the EPA rulemakings is an evolving science. The EPA offers the demographic analyses in today‘s proposed rulemaking as examples of how such analyses might be developed to inform such consideration, and invites public comment on the approaches used and the interpretations made from the results, with the hope that this will support the refinement and improve utility of such analyses.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 120 of 149
In the demographics analysis, we focused on populations within 50 km of the facilities in this source category with emissions sources subject to the MACT standard. More specifically, for these populations we evaluated exposures to HAP that could result in cancer risks of 1 in one million or greater. We compared the percentages of particular demographic groups within the focused p opulations to the total percentages of those demographic groups nationwide. The results of this analysis are documented in the document Draft Residual Risk Assessment for the Primary Aluminum Reduction Plant Source Category in the docket for this proposed rulemaking
. Formatted: Font: Bold, Underline*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 121 of 149*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 122 of 149

National Emission St andards for Hazardous Air Pollutants: Primary Aluminum Reduction Plants

List of Subjects in 40 CFR Part 63 Environmental protection, Air pollution control, Hazardous substances, Incorporation by reference, Reporting and recordkeeping requirements.

____________________________ Dated:

____________________________ Lisa P. Jackson, Administrator
.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 123 of 149 For the reasons stated in the preamble, part 63 of title 40, chapter I, of the Code of Federal Regulations is proposed to be amended as follows: PART 63 — [AMENDED] 1. The authority citation for part 63 continues to read as follows: Authority: 42 U.S.C. 7401, et seq. Subpart LL

– [AMENDED] 2. Section 63.840 is amended by revising paragraph (a) to read as follows: Section 63 .840 Applicability (a) Except as provided in paragraph (b) of this section, the requirements of this subpart apply to the owner or operator of each new or existing pitch storage tank, potline, paste production plant and anode bake furnace associated with p rimary aluminum production and located at a major source as defined in section 63.2. 3. Section 63.841 is amended by adding paragraph (a)(3) to read as follows: Section 63.841 Incorporation by reference.
* * * * * (a) * * * (3) ASTM D3177

- 02 (2007) Standard Test Methods for Total Sulfur in the Analysis Sample of Coal and Coke.
* * * * **** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 124 of 149 4. Section 63.842 is amended by removing the definition for ―Vertical stud Soderberg one (VSS1)‖ and adding definition s for ―affirmative defense‖ and ―startup of an anode bake furnace‖ to read as follows: Section 63.842 Definitions.
* * * * * Affirmative defense means, in the context of an enforcement proceeding , a response or defense put forward by a defendant, regarding which the defendant has the burden of proof, and the merits of which are independently and objectively evaluated in a judicial or administrative proceeding.
* * * * * Startup of an anode bake furnace means the process of initiating heating to the anode baking furnace where all sections of the furnace have previously been at ambient temperature. The startup or re - start of the furnace begins when the heating begins. The startup or re start concludes at the start of the second anode bake cycle. when fires begin to move to additional furnace s. * * * * * 5. Section 63.843 is amended by revising paragraphs (a)(1)(v) and (a)(2)(i) through (iii) and adding paragraphs (a)(2)(iv) through (a)(2)(vii), (d) , (e) , and (f) read as follows: Section 63.843 Emission limits for existing sources.
* * * * **** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 125 of 149 (a) * * * (a) ( 1 ) Emissions of TF must not exceed:
* * * * * (v) Reserved;
* * * * * (a) (2) Emissions of POM must not exceed: (i) 1.5 kg/Mg (3.0 lb/ton) of aluminum produced for each HSS potline; (ii) Reserved; (iii) 1.9 kg/Mg (3.8 lb/ton) of aluminum produced for each VSS2 potline; (iv) 0.31 0.33 kg/Mg (0. 62 (0.66 lb/ton) of aluminum produced for each existing CWPB1 prebake potline ; (v) 0.65 0.73 kg/Mg (1. 3 (1.45 lb/ton) of aluminum produced for each existing CWPB2 prebake potline ; (vi) 0.63 0.73 kg/Mg (1. 26 (1.45 lb/ton) of aluminum produced for each existing CWPB3 prebake potline ; (vii) 0.33 kg/Mg (0. 65 (0.66 lb/ton) of aluminum produced for each existing SWPB prebake potline ; * * * * * (d) Pitch storage tanks . Each pitch storage tank shal l be equipped with an emission control system designed and operated to reduce inlet emissions of POM by 95 percent or greater.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 126 of 149 (e) COS limit
. Emissions of COS must not exceed 3.9 lb/ton of aluminum produced
. ( f ) At all times, the owner or operator must operate and maintain any affected source, including associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such ope ration and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, review of operation and maintenance procedures, review of operation and maintenance r ecords, and inspection of the

source. 6. Section 63.844 is amended by revising paragraph (a)(2) and adding paragraphs (a)(3), (e) and (f) to read as follows: Section 63.844 Emission limits for new or reconstructed sources.
* * * * * (a) * * * ( 3 ) (2) POM limit . Emissions of POM from Soderberg and prebake potlines must not exceed 0.31 0.32 kg/Mg (0. 62 (0.6 3 lb/ton) of aluminum produced.
* * * * * (e) COS limit
. Emissions of COS must not exceed 3.1 lb/ton of aluminum produced.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 127 of 149 ( f ) At all times, the owner or operator must operate and maintain any affected source, including associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing

e missions. Determination of whether such operation and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, review of operation and maintenance proced ures, review of operation and maintenance records, and inspection of the

source. 7. Section 63.846 is amended by revising paragraph s (b) and (d) and adding paragraphs (e) and (f) to read as follows: Section 63.84 6 Emission averaging
. * * * * * (b) Sode rberg Potlines. The owner or operator may average TF emissions from potlines and demonstrate compliance with the limits in Table 1 of this subpart using the procedures in paragraphs (b)(1) and (b)(2) of this section. The owner or operator also may average POM emissions from potlines and demonstrate compliance with the limits in Table 2 of this subpart using the procedures in paragraphs (b)(1) and (b)(3) of this section. * * * (d) * * * (2) * * **** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 128 of 149 (iv) The test plan for the measurement of TF or POM emissions in accordance with the requirements in section s 63.847(b) and (k) ; * * * ( 4 ) * * * (ii) The inclusion of any emission source other than an existing potline or existing anode bake furnace or the inclusion of any potline or anode bake furnace not subject to the same operating permit; or (iii) T he inclusion of any potline or anode bake furnace while it is shut down, in the emission calculations. (iv) Reserved.
* * * * * (e) TF emissions f rom Prebake Potlines . The owner or operator may average TF emissions from potlines and demonstrate compliance with the limits in Table 1 of this subpart using the procedures in paragraphs (e) (1) and (e)(2) of this section. (1) Monthly average emissions of TF must not exceed the applicable emission limit in Table 1 of this subpart. The emission
rate must be calculated based on the total emissions from all potlines over the period divided by the quantity of aluminum produced during the period, from all potlin es comprising the averaging group. (2) To determine compliance with the applicable emission limit in Table 1 of this subpart for TF emissions, the owner or operator
must determine the monthly average emissions (in lb/ton) from each potline from at least th ree runs per potline each month for TF*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 129 of 149 secondary emissions using the procedures and methods in section s 63.847 and 63.849. The owner or operator must combine the results of secondary TF monthly average emissions with the TF results for the primary control system and divide total emissions by total aluminum production. (f) POM Emissions from Prebake Potlines . The owner or operator also may average POM emissions from potlines and demonstrate compliance with the limits in Table 2 of this subpart using the
proc edures in paragraphs (f)(1) and (f)(2) of this section. (1) Average emissions of POM for each compliance demonstration period, must not exceed the applicable emission limit in Table 2 of this subpart. The emission rate must be calculated based on the total emissions from all potlines divided by the quantity of aluminum produced during the period, from all potlines comprising the averaging group. (2) To determine compliance with the applicable emission limit in Table 2 of this subpart for POM emissions, the owner or operator
must determine the emissions (in lb/ton) from each potline using the procedures and methods in section s 63.847 and 63.849. The owner or operator must combine the results of measured or calculated secondary POM emissions with the POM emiss ions from the primary control system and divide total emissions by total aluminum production. 8 . Section 63.847 is amended by revising paragraphs (a), (b), (b)(6), (c)(1), (c)(2), (c)(2)(i) through (iii), (c)(3), (c)(3) (i)*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 130 of 14 9
and (ii), (d)(2), (e)(2) and (g) and adding paragraphs (d)(5),(e)(8), (i),(j) , (k) and (l) to read as follows: Section 63.847 Compliance Provisions. (a) Compliance dates . The owner operator of a primary aluminum reduction plant must comply with the requirements of this subpart by: ( 1 ) Exc ept as noted in paragraph ( 2 ) of this section, the compliance date for an owner or operator of an existing plant or source subject to the provisions of this subpart is October 7, 1999. ( 2 ) The compliance dates for existing plants and sources are: (i) [Inse rt date 90

- days after date of publication of final rule] for Soderberg potlines subject to emission limits in sections 63.843(a)(2)(i) and (iii) which became effective [insert date of publication of final rule]. (ii) [Insert date 3 years after date of publ ication of final rule] for prebake potlines subject to emission limits in sections 63.843(a)(2)(iv) through (vii) and section 63.8 48 ( n ) which became effective [insert date of publication of final rule]. (i i i) [Insert date 3 years after date of publication of final rule] for potlines subject to the work practice standards in section 63.854 which became effective [insert date of publication of final rule]. (i v ) [Insert date 3 years after date of publication of final rule] for anode bake furnaces subject to the startup practice s in*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 131 of 149 section 63.8 47(m) which became effective [insert date of publication of final rule]. (v) [Insert date 3 years after date of publication of final rule] for compliance with the pitch storage tank POM limit provisions of se ction 63.8 43(d) and the COS emission limit provisions of sections 63.8 43(e) and 63.8 44(e). (v i ) [Insert date of publication of final rule] for the malfunction provision s of sections 63.85 0(d)(2) and (e)(4)(xvi) and (xvii), the affirmative defense provision s of section 63. 855, and the electronic reporting provisions of sections 63.85 0(c) and (f). (3) Upon startup, for an owner or operator of a new or reconstructed source.
* * * * * (b) Test plan for TF from all anode bake furnaces and potlines and POM from Soderberg p otlines . The owner or operator shall prepare a site

- specific test plan prior to the initial performance test according to the requirements of s ec tion 63.7(c) of this part. The test plan must include procedures for conducting the initial performance test and for subsequent performance tests required in

s ec tion 63.848 for emission monitoring. In addition to the information required by section 63.7, the t est plan shall include: *
* * (6) Reserved.
* * * * **** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 132 of 149 (c) * * *
(1) During the first month following the compliance date for an existing potline (or potroom group), anode bake furnace or pitch storage tank; (2) By the 180 th day following startup for a potline or potroom
group for which the owner or operator elects to conduct an initial performance test . The 180

- day period starts when the first pot in a potline or potroom group is energized
. * * * * * (2)(i) Reserved. (2)(ii) Reserved. (2)(iii) Reserved. ( 3 ) By the 180 th day following startup for a potline or potroom
group that was shut down at the time compliance would have otherwise been required and is subsequently restarted . The 180

- day period starts when the first pot in a potline or potroo m group is energized
. ( 3 )(i) Reserved. (3)(ii) Reserved.
* * * * * (d) Performance test requirements . The initial performance test and all subsequent performance tests must be conducted in accordance with the requirements of the general provisions in s ubpart A of this part, the approved test plan, and the procedures in this section.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 133 of 149
Performance tests must be conducted under such conditions as the Administrator specifies to the owner or operator based on representative performance of the affected source for the period being tested. Upon request, the owner or operator must make available to the Administrator such records as may be necessary to determine the conditions of performance tests. * * *
* * * * * (2) POM emissions from Soderberg potlines . Fo r each Soderberg (HSS, and VSS2) potline, the owner or operator must measure and record the emission rate of POM exiting the primary emission control system and the rate of secondary emissions exiting through each roof monitor, or for a plant with roof scr ubbers, exiting through the scrubbers. Using the equation in paragraph (e)(2) of this section, the owner or operator must compute and record the average of at least three runs each quarter (one run per month) for secondary emissions and at least three runs each year for the primary control system to determine compliance with the applicable emission limit. Compliance is demonstrated when the emission rate of POM is equal to or less than the applicable emission limit in sections 63.843, 63.844 or 63.846.
* * * * * (d) * * * (5) POM emission from prebake potlines . POM emission s from prebake Prebake potlines . For each prebake potline, the owner or Formatted: Underline, Complex Script Font: 11 pt Formatted: Underline, Complex Script Font: 11 pt*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 134 of 149 operator shall measure and record the emission rate of POM exiting the primary emission control system. The own er or operator shall compute and record the average of at least three runs every five years. For each prebake potline for which the owner or operator chooses to demonstrate compliance using the provisions of section 63.847(e)(2), the owner or operator shal l measure and record the emission rate of secondary emissions exiting through each roof monitor, or for a plant with roof scrubbers, exiting through the scrubbers. The owner or operator shall compute and record the average of at least three runs every five years for secondary emissions. The owner or operator shall calculate POM emissions in accordance with sections 63. 847(e)(2) or (8). Compliance is demonstrated when the emission rate of POM is equal to or less than the applicable emission limit in sections 63.843, 63.844 or 63.846.
* * * * * (e) * * * (2) Compute the emission rate of POM from each Soderberg potline, and from those prebake potlines for which the owner or operator chooses to measure secondary emissions, using Equation 1, Where:
E p = emission rate of POM from the potline, kg/mg (lb/ton); and
C s = concentration of POM, mg/dscm (mg/dscf). POM emission data collected during the installation and startup of a cathode must not be included in C s .*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 135 of 149
* * * * * (8) Compute the rate of POM from each prebake potline for which the owner or operator does not choose to determine the measure the secondary emissions using Equation 3:

(Equation 3)
Where:
E pp = emission rate of POM from a po tline, kg/Mg (lb/ton) ; C pp1 = concentration of POM from the primary control system, mg/dscm (mg/dscf) ; Q 1 = volumetric flow rate of effluent gas from the primary control system dscm/hr (dscf/hr) ; C pF2 = concentration of TF from the secondary control system or roof monitor, mg/dscm (mg/dscf) ; C pF1 = concentration of TF from the primary control system, mg/dscm (mg/dscf) ; and Q 2 = volumetric flow rate of effluent gas from the secondary control system or roof monitor, dscm/hr (dscf/hr).
* * * * * (g) Pitch storage tanks . The owner or operator must demonstrate initial compliance with the standard for pitch storage tanks in sections 63.843(d) and 63.844(d) by preparing a design evaluation or by conducting a performance test. The owner or operator shall submit for approval by the regulatory authority the information specified in*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 136 of 149 paragraph (g)(1) of this section, along with the information specified in paragraph (g)(2) of this section where a design evaluation is performed or the information specified in paragrap h (g)(3) of this section where a performance test is conducted.
* * * * * (i) Reserved. (j) COS Emissions . The owner operator of each plant must calculate the facility wide emission rate of COS for each calendar month of operation using the following e quation:

Where:
E COS = the facility wide emission rate of COS during the calendar month in pounds per ton of aluminum produced; K = factor accounting for molecular weights and conversion of sulfur to carbonyl sulfide = 234;
Y = the tons of anode used at the facility during the calendar month;
Z = the tons of aluminum produced at the facility during the calendar month; and %S = the weighted average sulfur content of the anode coke utilized in the production of aluminum during th e calendar month (e.g., if the weighted average sulfur content of the anode coke utilized during the calendar month was 2.5%, then %S = 0.025).*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 137 of 149 Compliance is demonstrate d if the calculated value of E COS is less than the applicable standard for COS emission s in sections 63.843(e) and 63.844(e). (k) Test plan POM from p rebake p otlines . The owner or operator must prepare a site

- specific test plan prior to the initial performance test according to the requirements of section 63.7(c) of this part. The test plan mu st include procedures for conducting the initial performance test and for subsequent performance tests required in section 63.848 for emission monitoring. In addition to the information required by section 63.7 the test plan shall include: (1) Procedures t o ensure a minimum of three runs are performed for the primary control system for each source; (2) For a source with a single control device exhausted through multiple stacks, procedures to ensure that at least three runs are performed by a representative sample of the stacks satisfactory to the applicable regulatory authority; (3) For multiple control devices on a single source, procedures to ensure that at least one run is performed for each control device by a representative sample of the stacks satisfac tory to the applicable regulatory authority; (4) For plants with roof scrubbers, procedures for rotating sampling among the scrubbers or other procedures to obtain representative samples as approved by the applicable regulatory authority.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 138 of 149 (l) Potlines . The owner or operator shall develop a written startup plan as described in section 63.854 that contains specific procedures to be followed during startup periods of potline(s). Compliance with the applicable standards in section 63.854 will be demonstrat ed through site inspection(s) and review of site records by the applicable regulatory authority. ( m ) A node bake furnaces
. If you own or operate a new or existing primary aluminum reduction affected source, you must develop a written startup plan as describ ed in paragraphs ( m )(1) through ( 4 ) of this section. Compliance with the startup plan will be demonstrated through site inspection(s) and review of site records by the applicable regulatory authority. The written startup plan must contain specific procedur es to be followed during startup periods of anode b ake furnaces , includ ing the following: (1) A requirement to develop a n anode bake furnace startup schedule prior to startup of the first anode bake furnace
. (2) Record s of time, date, duration and any nonr outine actions taken during startup of the furnace s. (3) A requirement that the associated emission control system should be operating within normal parametric limits prior to startup of the first anode bake furnace
. (4) A requirement to shut down the anod e bake furnace s immediately i f the associated emission control system is off line at any time during startup .*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 139 of 149 9. Section 63.848 is amended by revising paragraph (b) and adding paragraph (n) to read as follows: Section 63.848 Emission monitoring requirements.
* * * * * (b) POM emissions from Soderberg potlines . Using the procedures in section 63.847 and in the approved test plan, the owner or operator shall monitor emissions of POM from each Soderberg (HSS and VSS2) potline every three months. The owner or operator shall compute and record the quarterly (3

- month) average from at least one run per month for secondary emissions and the previous 12

- month average of all runs for the primary control systems to determine compliance with the applicabl e emission limit. The owner or operator must include all valid runs in the quarterly (3

- month) average. The duration of each run for secondary emissions must represent a complete operating cycle. The primary control system must be sampled over an 8

- hour
pe riod, unless site

- specific factors dictate an alternative sampling time subject to the approval of the regulatory authority.
* * * * * (n) POM emissions from prebake potlines . Using the procedures in section 63.847 and in the approved test plan, the ow ner or operator
must monitor emissions of POM from each prebake potline every five years. The owner or operator must compute and record the sum of the average pri ma ry and secondary emissions using the procedures of section s 63. 847 (e) (2) or (e) (8).*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 140 of 149 10
. Section 63.849 is amended by adding paragraph (f) to read as follows: Section 63.849 Test methods and procedures.
* * * * * (f) The owner or operator must use ASTM Method D3177

– 02 (2007) for determination of the sulfur content in anode coke shipment s to determine compliance with the applicable facility wide emission limit for COS emissions. 11. Section 63.850 is amended by revising paragraph s (c), (d) and (e)(iii) and adding paragraphs (e)(xvi) and (xvii) and (f) to read as follows: Section 63.850 No tification, reporting and recordkeeping requirements.
* * * * * ( c ) As of January 1, 2012 and within 60 days after the date of completing each performance test, as defined in section 63.2, and as required in this subpart, the owner or operator must sub mit performance test data, except opacity data, electronically to the
EPA ‘s Central Data Exchange by using the ERT (see http://www.epa.gov/ttn/chief/ert/erttool.html/) or other compatible electronic spreadsheet. Only data collected using test methods
compa tible with ERT are subject to this requirement to be submitted electronically into the EPA ‘s WebFIRE database.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 141 of 149 (d) Reporting
. In addition to the information required under section 63.10 of the General Provisions, the owner or operator must provide semi

- ann ual reports containing the information specified in paragraphs ( d )(1) through ( d )(2) of this section to the Administrator or designated authority. (1) Excess emissions report . As required by section 63.10(e)(3), the owner or operator must submit a report ( or a summary report) if measured emissions are in excess of the applicable standard. The report must contain the information specified in section 63.10(e)(3)(v) and be submitted semiannually unless quarterly reports are required as a result of excess emiss ions. (2 ) If there was a malfunction during the reporting period, the owner or operator must submit a report that includes the number, duration, and a brief description for each type of malfunction which occurred during the reporting period and which caus ed or may have caused any applicable emission limitation to be exceeded. The report must also include a description of actions taken by an owner or operator during a malfunction of an affected source to minimize emissions in accordance with sections 63. 843(f) and 63.844(f) , including actions taken to correct a malfunction.
* * * * * (e) * * * (e)(4) * * * (iii) Reserved.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 142 of 149 (e)(4) * * * ( xvi) Records of the occurrence and duration of each malfunction of operation (i.e., process equipment) or the air pollution control equipment and monitoring equipment. (xvii) Records of actions taken during periods of malfunction to minimize emissions in accordance with sections 63. 843 and 63. 844 , including corrective actions to restore malfunctioning proces s and air pollution control and monitoring equipment to its normal or usual manner of operation. ( f ) All reports required by this subpart not subject to the requirements in paragraph ( b ) of this section must be sent to the Administrator at the appropriate address listed in section 63.13. If acceptable to both the Administrator and the owner or operator of a source, these reports may be submitted on electronic media. The Administrator retains the right to require submittal of reports subject to paragraph ( b) of this section i n paper format. 12. Section 63.854 is added to read as follows: Section 63.854 Work Practice Standards for Periods of Startup. ( a ) Startup of potlines
. If you own or operate a new or existing primary aluminum reduction affected source, you must comply with the requirements of paragraph s ( a )(1) through (7) of this section during startup for each affected potline. (1) Develop a potline startup schedule bef ore starting up the potline.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 143 of 149 (2) Keep records of number of pots started per day. (3) Bring the potline scrubbers and exhaust fans on line prior to energizing the first cell being restarted. (4) Ensure that the primary capture and control system is operatin g at all times during startup. (5) Keep pots covered during startup as much as practicable to include but not limited to minimizing the removal of covers or panels of the pots on which work is being performed. (6) Inspect potlines daily during startup and perform the following work practices as specified in paragraphs ( a )(6)(i) through (iv) of this section. (i) Identify unstable pots as soon as practicable but in no case more than 12 hours from the time the pot became unstable ; (ii) Reduce cell temperatures to as low as p racticable , but no higher than the maximum temperature specified in the operating plan described in paragraph (a)(7) of this section ; (iii) Reseal pot crust s that have been broken as often and as soon as practicable but in no case more than 24 hours from the time the crust was broken ; and (iv) Adjust pot parameters to their optimum levels , as specified in the operating plan described in paragraph (a)(7) of this section, includ ing , but not limited to , the following parameters: alumina addition rate, exhaust air flow, cell voltage, feeding level, anode current and liquid and solid bath levels.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 144 of 149 (7) Prepare a writte n operating plan to minimize emissions during startup to include , but not limited to , the r equirements in ( a )(1) th rough (6) of this section. 13. Section 63.855 is added to read as follows: Section 63.855 Affirmative defense for exceedance of emission limit during malfunction
. In response to an action to enforce the standards set forth in this s ubpart, you may assert an affirmative defense to a claim for civil penalties for exceedances of such standards that are caused by malfunction, as defined at section 63.2
. Appropriate penalties may be assessed, however, if you fail to meet your burden of pr oving all of the requirements in the affirmative defense. The affirmative defense shall not be available for claims for injunctive relief. (a) To establish the affirmative defense in any action to enforce such a limit, you must timely meet the notification requirements in section 63. 850 of this subpart, and must prove by a preponderance of evidence that: ( 1 ) The excess emissions: ( i ) Were caused by a sudden, infrequent, and unavoidable failure of air pollution control and monitoring equipment, process equip ment, or a process to operate in a normal or usual manner ; and ( ii ) Could not have been prevented through careful planning, proper design or better operation and maintenance practices; and*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 145 of 149 ( iii ) Did not stem from any activity or event that could have been foreseen and avoided, or planned for. ( iv ) Were not part of a recurring pattern indicative of inadequate design, operation, or maintenance; and ( 2 ) Repairs were made as expeditiously as possible when the applicable emissions limitations were being exceeded
. Off

- shift and overtime labor were used, to the extent practicable to make these repairs ; and ( 3 ) The frequency, amount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of such emi ssions; and ( 4 ) If the excess emissions resulted from a bypass of control equipment or a process, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage; and ( 5 ) All possible steps were taken to minimize the imp act of the excess emissions on ambient air quality, the environment and human health; and ( 6 ) All emissions monitoring and control systems were kept in operation if at all possible, consistent with safety and good air pollution control practices; and ( 7 ) All of the actions in response to the excess emissions were documented by properly signed, contemporaneous operating logs; and ( 8 ) At all times, the affected source was operated in a manner consistent with good practices for minimizing emissions; and*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 146 of 149 ( 9 ) A written root cause analysis has been prepared, the purpose of which is to determine, correct, and eliminate the primary causes of the malfunction and the excess emissions resulting from the malfunction event at issue. The analysis shall also specify, usin g best monitoring methods and engineering judgment, the amount of excess emissions that were the result of the malfunction. ( b ) Notification
. The owner or operator of the affected source experiencing an exceedance of its emissions limit(s) during a malfunc tion, shall notify the Administrator by telephone or facsimile transmission as soon as possible, but no later than two business days after the initial occurrence of the malfunction, if it wishes to avail itself of an affirmative defense to civil penalties for that malfunction. The owner or operator seeking to assert an affirmative defense, shall also submit a written report to the Administrator within 45 days of the initial occurrence of the exceedance of the standard s in this subpart to demonstrate, with a ll necessary supporting documentation, that it has met the requirements set forth in paragraph (e) of this section. The owner or operator may seek an extension of this deadline for up to 30 additional days by submitting a written request to the Administrat or before the expiration of the 45 day period. Until a request for an extension has been approved by the Administrator, the owner or operator is subject to the requirement to submit such report within 45 days of the initial occurrence of the exceedance.*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 147 of 149
1 4
. Reserved sections are amended to read as follows: Sections 63.85 6 - 63.85 9 [Reserved]
1 5
. Table 1 to Subpart LL of Part 63 is amended to read as follows: Table 1 to Subpart LL of Part 63

— Potline TF Limits for Emission Averaging

Type Monthly TF limit (1b/ton) [for given number of potlines] 2 lines 3 lines 4 lines 5 lines 6 lines 7 lines 8 lines CWPB1 1.7 1.6 1.5 1.5 1.4 1.4 1.4 CWPB2 2.9 2.8 2.7 2.7 2.6 2.6 2.6 CWPB3 2.3 2.2 2.2 2.1 2.1 2.1 2.1 VSS2 2.6 2.5 2.5 2.4 2.4 2.4 2.4 HSS 2.5 2.4 2.4 2.3 2.3 2.3 2.3 SWPB 1.4 1.3 1.3 1.2 1.2 1.2 1.2
1 6
. Table 2 to Subpart LL of Part 63 is amended to read as follows: Table 2 to Subpart LL of Part 63

— Potline POM Limits for Emission Averaging

Type POM limit (lb/ton) [for given number of potlines] 2 lines 3 lines 4 lines 5 lines 6 lines 7 lines 8 lines HSS 3.5 3.2 3. 1 3. 0 3. 0 2.9 2.8 VSS2 3.5 3.3 3.2 3.1 3.0 2.9 2.9 CWPB1 0.63 0.56 0.52 0.52 0.48 0.48 0.48 CWBP2 1.4 1.35 1.31 1.31 1.26 1.26 1.26 CWBP3 1.33 1.28 1.28 1.26 1.26 1.26 1.26 SWPB 0.63 0.56 0.52 0.52 0.48 0.48 0.48
1 7 . Appendix A to subpart LL of part 63 is amended to read as follows:*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 148 of 149 Appendix A to Subpart LL of Part 63

— Applicability of General Provisions (40 CFR Part 63, Subpart A)

Reference Section(s) ... Applies to subpart LL Comment

63.1 Yes 63.2 Yes 63.3 Yes 63.4 Yes 63.5 Yes 63.6(a), (b), (c) Yes 63.6(d) No Section reserved. 63.6(e)(1)(i) No See sections 63. 843(f) and 63. 844(f) for general duty requirement. 63.6(e)(1)(ii) No 63.6(e)(1)(iii) Yes 63.6(e)(2) No Section reserved. 63.6(e)(3) No 63.6(f)(1) No 63.6(g) Yes 63.6(h) No No opacity limits in rule. 63.6(i) Yes 63.6(j) Yes 63.7(a) through (d) Yes 63.7(e)(1) No See section 63.847(d) 63.7(e)(2) through (e)(4) Yes 63.7(f), (g), (h) Yes 63.8(a) and (b) Yes 63.8(c)(1)(i) No See sections 63. 843(f) and 63. 844(f) for general duty requirement. 63.8(c)(1)(ii) Yes 63.8(c)(1)(iii) No 63.8(c)(2) through (d)(2) Yes 63.8(d)(3) Yes, except for last sentence 63.8(e) through (g) Yes 63.9(a),(b),(c),(e),(g),(h)(1) through (3), (h)(5) and (6), Yes Formatted Table*** E.O. 12866 Review – Draft ( 11 / 04 /2011) ( 10 / 13 /2011) – Do Not Cite, Quote or Release During Review ***

Page 149 of 149
Reference Section(s) ... Applies to subpart LL Comment (i) and (j) 63.9(f) No 63.9(h)(4) No Reserved 63.10(a) Yes 63.10(b)(1) Yes 63.10(b)(2)(i) No 63.10(b)(2)(ii) No See sections 63.850(e) (4) (xvi) and (xvii) for recordkeeping of occurrence and duration of malfunctions and recordkeeping of actions taken during malfunction. 63.10(b)(2)(iii) Yes 63.10(b)(2)(iv) and (b)(2)(v) No 63.10(b)(2)(vi) through (b)(2)(xiv) Yes 63.(10)(b)(3) Yes 63.10(c)(1) through (9) Yes 63.10(c)(10) and (11) No See sections 63.850(e) (4) (xvi) and (xvii) for recordkeeping of malfunctions. 63.10(c)(12) through (c)(14) Yes 63.10(c)(15) No 63.10(d)(1) through (4) Yes 63.10(d)(5) No See section 63. 850(d)(2) for reporting of malfunctions. 63.10(e) and (f) Yes 63.11 No Flares will not be used to comply with the emission limits
. 63.12 through 63.15 Yes Formatted Table