OAR Box 1851 

Prepped by Keeia Richards 

Document Number: 

28) ll-A-2 

Docket Number: 

A-90-19 

Printed 11/19/2008 11:19:51 AM Sheet 28 of 41 

p.1 
P.2 

r

1 

J 

A-90-19 

ll-A-2 

SURVEY REPOR 

[^ ON ATMOSPHERIC EMISSIONS 

pi FROM THE PETROCHEMICAL 

J INDUSTRY 

VOLUME II 

by 

J. W. Pervier, R. C. Barley, D. E. Field, 

B. M. Friedman, R. B. Morris, W. A. Schwartz 

J

Houdry Division 

Air Products and Chemicals, Inc. 

P. O. Box 427 

Marcus Hook, Pennsylvania 19061 

Contract No. 68-02-0255 

EPA Project Officer: Leslie B . Evans 

Prepared for 

ENVIRONMENTAL PROTECTION AGENCY 

Office of Air and Water Programs 

Office of Air Quality Planning and Standards 

Research Triangle Park, N. C. 27711 

April 1974 
P.3 

This report is issued by the Environmental Protection Agency to report technical 

data of interest to a limited number of readers. Copies are available free of charge 

to Federal employees, current contractors and grantees, and nonprofit organizations 

as supplies permit - from the Air Pollution Technical Information Center, Environmental Protection Agency, Research Triangle Park, North Carolina 27711, or from 

the National Technical Information Service 5285 Port Royal Road, Springfield, 

Virginia 22151. 

This report was furnished to the Environmental Protection Agency by Air Products 

and Chemicals, Inc., Marcus Hook, Pennsylvania, in fulfillment of Contract 

No. 68-02-0255. The contents of this report are reproduced herein as received 

from Air Products and Chemicals, Inc. The opinions, findings, and conclusions 

expressed are those of the author and not necessarily those of the Environmental 

Protection Agency. Mention of company or product names is not to be considered 

as an endorsement by the Environmental Protection Agency. 

Publication No. EPA-450/3-73-005-b 

» 

1 
TABLE CD-III 

NATIONAL EMISSIONS INVENTORY 

CARBON DISULFIDE FROM 

METHANE AND SULFUR Pag* 1 of 4 

E.P.A. CODE.NO. 

CAPACITY TONS OF CARBON DISULFIDE 

AVERAGE PRODUCTION - TONS OF CARBON DISULFIDE 

EMISSIONS TO ATMOSPHERE 

8 - 1 

Approx. 5,00 0 (1) 

( 1 ) 

Fumes From Sulfu r Storag e 

Sulfur Pit Vent 

Not Specifie d Not Specifie d 

Continuous Continuous 

Flue Cas From 

Start-Up Flare 

Not Specified 

Intermittent 

50 

Flare Flue Cas 

Emergency Reactor Vent 

18,562 

Intermittent 

.66 

+ 

+ 

Steam 

Flow-Lbs./Yr. 

Flow Characteristics - Contlnuoua or Intermittent 

If Intermittent - Hrs./Yr. 

Composition Lbs./Hr. of Component 

Methane 

Ethane 

Propane 

Sulfur 

Carbonyl Sulfide 

Carbon Disulfide 

Thfophene 

Hydrogen Sulfide 

Sulfur Dioxide 

Nitrogen 

Nitrogen Dioxides 

Carbon Dioxide 

Oxygen 

Water 

Hydrocarbons 

Analysis 

Date of Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacks 

Flow SCFM Per Stack 

Number 

Height (Elev. @ tip) - Ft. 

Diameter - Inchea 

Exit Cas Temperature - F 

Emission Control Devices 

Type - Scrubber 

- Incinerator - Flare Yes 

Summary of Pollutants 

Hydrocarbons Lbs./Hr. + Other Sulfur Compounds + 

Besides S0X 

Particulates + (3) 

NQJJ - Lbs./Hr. + 

S0_ - Lbs./Hr. 

CO - Lbs./Hr. 

( 1 ) Exac t capacit y and production figure s ar e confidentia l 

( 2) Sinc e capacit y Is calsslfle d Information i t Is not possibl e t o represen t compositio n In the usua l manner of tona/ton s product. 

(3) Sublimed sulfur . 

( 4 ) Average o f 3. 7 SCFM. 

Storag e 

IM 

No 

No 

No 

+ 

None 

No 

Yes 

1 

30 

3 

250 

No 

+ 

+ 

+ 

+ 

+ 

None 

Yes 

Yes 

1 

12 

2 

1200 

14,04 1 

0 . 5 

2,486 

2,035 

None 

Yes 

Yes 

60 - 2000 

1 

150 

8 

3000 

Yes 

0 . 5 

14,04 1 

None 

No 

Yes 

0-1 2 

1 

30 

2 

Ambient 

No 

xnnnftvQiinnAo 
I „ 1 1_ ,_J J . 

TABLE CD-III 

NATIONAL EMISSIONS INVENTORY 

CARBON DISULFIDE 

FROM METHANE AND SULFUR Page 2 of 4 

EPA CODE NO. 

CAPACITY TONS OF CARBON DISULFIDE 

AVERAGE PRODUCTION - TONS OF CARBON DISULFIDE 

EMISSIONS TO ATMOSPHERE 

8-3 

119,000 

119,000 

St< 

Flow Lba/Yr. 

Flow Characteristic s - Continuous or Intermittent 

If Intermittent - Hrs./Yr. 

Composition Tons/Ton of Carbon Disulfide 

Particulate s 

Methane 

Ethane 

Propane 

Sulfur 

Carbonyl Sulfide 

Carbon Disulfide 

Thiophene 

Hydrogen Sulfide 

Sulfur Dioxides 

Nitrogen 

Nitrogen Dioxides 

Carbon Monoxide 

Carbon Dioxide 

Water 

Hydrocarbons 

Analysis 

Date of Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacks 

Flow SCFM Per Stack 

Number 

Height (Elev. 9 tip.) - Ft. 

Diameter - Inches 

Exit Gas Temperatures - F° 

Emission Control Devices 

Type - Scrubber 

Incinerator - Flare 

Summary of Pollutants 

Hydrocarbons + Sulfur Containing 

Compounds besides SO^ - Tons/Ton Carbon Disulfide 

Particulates - Tons/Ton Carbon Disulfide 

N0X - Tons/Ton Carbon Disulfide 

SO - Tons/Ton Carbon Disulfide 

CO* - Tons/Ton Carbon Disulfide 

(1) Not enough information to calculate - Incinerator burns claus tail 

(2) Converts harmful liquid waste to air pollutants 

*'""' **-nm Mould waste only. 

Boiler Fine 

Cas 

24,605 

Cont inuous 

.00004 

Flue Gas - Liquid 

Waste Incineration 

(D 

Continuous 

Flue Cas 

Emergency Flare 

Not Specified 

Intermittent 

1 

Storage 

Loss 

20 

Continuous 

Negligible 

.00014 

Negligible 

.46342 

.37918 

.00009 

None 

Calc'd. 

No 

Yes 

Not Specified 

1 

100 

50 

800 

No 

.00662 (3) 

+ 

(I) 

(I) 

Yea 

Once/Month 

Chramatagraph 

No 

Yea 

1 

150 

78 

1000 

Yes 

4 

+ 

+ 

None 

No 

Yes 

Yes (2) 

.00009 

.00004 

.00014 

Negligible 

Negligible 

gas also. 

0 

0 

+ 

.00662 

0 

No 

Yes 

0 

0 

+ 

Negligible 

Negligible 

None 

No 

Yes 

70 

35-50 

36 

Ambient 

No 

Negligible 

0 

0 

0 

E 
i -

TABLE CD-III 

NATIONAL EMISSIONS INVENTORY 

CARBON DISULFIDE FROM 

METHANE AND SULFUR Page 3 of 4 

EPA CODE NO. 8- 4 

CAPACITY TONS OF CARBON DISULFIDE 17 5.UOO 

AVERAGE PRODUCTION - TONS OF CARBON DISULFIDE 175,00 0 

EMISSIONS TO ATMOSPHERE 

Stream 

Flow-Lbs./Hr. 

Flow Characteristics - Continuous or Intermittent 

If Intermittent - Hrs./Yr. 

Composition Tons/Ton of Carbon Disulfide 

Methane 

Ethane 

Propane 

Sulfur 

Carbonyl Sulfide 

Carbon Disulfide 

Th+ophene 

Hydrogen Sulfide 

Sulfur Dioxide 

Nitrogen 

Nitrogen Dioxides 

Carbon Dioxide 

Water 

Analysis 

Date of Frequency of Sampling 

Type of Analysis 

Or dor Problem 

Vent Stacks 

Flow SCFM per Stack 

Number 

Height (elev. 9 tip) - Ft. 

Diameter - Inches 

Exit Gas Temperature - F° 

Emission Control Devices 

Type - Scrubber 

Incinerator - Flare 

Summary of Pollutants 

Hydrocarbons + Compounds Containing Sulfur 

besides SO, - Ions/Ton Carbon Disulfide 

Particulates - Ton6/Ton Carbon Disulfide 

NOx - Tons/Ton Carbon Disulfide 

Boiler Flue 

Gas 

13,221 

Continuous 

.00001 

.29025 

.23750 

Reactor Emergency 

Vent Flare 

20,800 

Intermittent 

72 

.00025 

.00369 

so„ Tons/Ton Carbon Disulfide 

CO - Tons/Ton Carbon Disulfide 

Not Specified 

No 

Not Specified 

No 

0 

0 

.00001 

0 

O 

Yes 

Once 

Chromatagraph 

Yes 

Yes 

1 

88 

18 

200 

Yes 

Yes 

0 

0 

0 

.00025 

0 

Emergency Storage 

Tank Vent 

47 

Intermittent 

12 

Negligible 

Negligible 

None 

No 

No 

No 

Negligible 

0 

0 

0 

0 

b> 
TABLE CD-III 

NATIONAL EMISSIONS INVENTORY 

CARBON DISULFIDE FROM 

METHANE AND SULFUR Page 4 of 4 

EPA CODE NO. 8- 5 

CAPACITY TONS OF CARBON DISULFIDE 26,50 0 

AVERAGE PRODUCTION - TONS OF CARBON DISULFIDE 26,50 0 

EMISSIONS TO ATMOSPHERE 

Stream 

Flow-Lbs./Hr. 

Flow Characteristics - Continuous or Intermittent 

If Intermittent - Hrs./Yr. 

Composition Tons/Ton of Carbon Disulfide 

Methane 

Ethane 

Propane 

Sulfur 

Carbonyl Sulfide 

Carbon Disulfide 

Thlophene 

Hydrogen Sulfide 

Sulfur Dioxide 

Nitrogen 

Nitrogen Dioxides 

Carbon Dioxide 

Water 

Oxygen 

Analysis 

Date of Frequency of Sampling 

Type of Analysis 

Ordor Problem 

Vent Stacks 

Flow SCFM per Stack 

Number 

Height (elev. <? tip) - Ft. 

Diameter - Inches 

Exit Gas Temperature - F° 

Emission Control Devices 

Type - Scrubber 

Incinerator - Flare 

Summary of Pollutants 

Hydrocarbons x Sulfur Contain Compounds 

bealdea SO, - Tons/Ton Carbon Disulfide 

Particulates - Tons/Ton Carbon Disulfide 

NOx - Tons/Ton Carbon Disulfide 

Sulfur Storage 

Vent 

1.7 

Continuous 

.00028 

None 

Calc'd. 

No 

No 

No 

.00028 

S0_ Tona/Ton Carbon Disulfide 

CO - Tons/Ton Carbon Disulfide 

0 

0 

0 

Flue Gas 

Emergency Flare 

33.758 

Intermittent 

30 

Storage Vent 

Continuous 

Fugitive Emissions 

Continuous 

.00478 

.01260 

.00005 

.00122 

.00685 

None 

Calc'd. 

No 

Yes 

6 780 

1 

110 

12 

1800 

Yes 

Yes 

0 

0 

0 

.00478 

0 

Negligible 

Negligible 

None 

No 

No 

No 

Negligible 

0 

0 

0 

0 

( ) 

(.00007) 

( ) 

None 

No 

No 

No 

.00007 

0 

0 

0 

0 
f

BPA Cod* Number 

y • Tons of Cyclohexanone/Yr. 

Production - Ton* of Cyclohexanone/Yr. 

ly Production Variation - 1 of Max. 

|ons t o Atmosphere 

tv - Ib./hr. 

\m Characteristic • Contlnuoua or Intermittent 

if Intermittent - hrs./yr. flov 

Imposition - Tons/ton of Cyclohexanone 

Cyclonesane 

Cyclohexanone 

Cycloneaanol 

Hathane 

Ethane 

Ethylene 

Nitrogen 

Oxygen 

Hydrogen 

Carbon Honoalda 

Carboo Dlxold* 

Water 

Mlac. Hydrocarbons 

•mla Tap Location 

j t e or Frequency of S 

kpa of Analyals 

Mor Problems 

•tacka 

lov - SCIM/Stack 

am* Ung 

•sight - r*«t 

Hamster - Inches 

txlt Gas Team - r ° 

talon Control Devices 

Bape - Incinerator 

Flare 

• Scrubber 

Other 

(

Catalog I.D. Number 

a l Hydrocarbon Ealesions 

a l Particulat e &> Aerosol 

al HO, 

a l SO, 

tal CO 

TABLE CO-IIL 

NATIONAL EMISSIONS INVENTORY 

CYCLOHEXANONE PRODUCTION 

5-2 

207,000 <5> 

Page 1 of 6 

Ton/ton of Cyclohexanone 

l.ov Preeaure 

Off-gas 

(Cyclohonana 

Recovery Section) 

1409 

Contlnuoua 

.01426 

.00016 

.00556 

.00096 

Every 2- 3 *•"• 

GLC fc Oraat 

No 

Yea 

250 

I 

65 

6 

as 

No 

.00926 

High Preesure 

0ff-ga» 

Cyclohexane 

RecoV«T, Section 

44,115" 

Contlnuoua 

.80195 

.00470 

.00370 

.00193 

.00740 

BI-weekly 

CLC a Oraat 

No 

Y*a 

10,000 

l 

8$ 

6 

as 

(7) 

5-3 

115,000 (8) 

Oxldlxer 

"Spent Air" & 

Vent 

50,000 

Contlnuoua 

1.56815 

.07577 

.02977 

Infrequent 

GLC 

No 

Yea 

/w 10,000 

1 

160 

10 

104 

Yea 

+ 

C0-11 

.03379 

.07637 

Purification 

Section 

Vent 

3000 

Contlnuoua 

.09474 

.00110 

.00457 

Infrequent 

CLC 

Ho 

Yea 

A/600 

1 

160 

24 (?) 

104 

Yea 

+ 

C0-12 
Plant - EMI Cod* Number 

Capacity - Tons of Cyclohexanone/Yr. 

Average Production - Tone of Cyclohexanone/Yr. 

Quarterly Production Varaltlon - 7. of Max. 

Emissions t o Atmosphere 

Stream 

TABLE CO-III 

NATIONAL EMISSIONS INVENTORY 

CYCLOHEXANONE PRODUCTION 

5-4 

31,000 (5) 

Oxidizer "Spent 

Air" Vent 

Page 2 of 6 

Deaorbed 

Gases from 

Storage & 

Purification 

Flow - lb./hr. 

Flow Characteristic - Continuous or Intermittent 

if Intermittent - hre./yr- flow 

Composition - Tons/ton of Cyclohexanone 

Cyclohaxane 

Cyclohexanone 

Cyclohexanol 

Methane 

Ethan* 

Ethylene 

NltrogaOxygen 

Hydrogen 

Carbon Monoxide 

Carbon Dioxide 

Water 

Mica. Hydrocarbon* 

Sampl* Tap Location 

Data or Fremusnyc of Sampling 

Type of Analysis 

Odor Problem* 

Vent Stacks 

Plow - SCFM/Stack 

Height - PM t 

Dla_mt*r - Inches 

Exit Cas Temp. - F° 

-mission Control Devices 

Typ* - Incinerator 

Flare 

Scrubber 

Other 

Catalog I.D. Number 

Total Hydrocarbon Emissions - Ton/ton of Cyclohexanone 

Total Particulate (. Aerosol - " " " 

Total NO ' 

Total SO, " " " 

Total CO 

12,958 

Continuous 

.02355 

<"500 (6) 

Continuous 

1.52394 

.02613 

.05560 

.02574 

.01274 

Stack 

Infrequently 

GLC 

Yes 

2870 

1 

19 

8 

No 

? 

+ 

+ 

Yes 

Yes 

• K. 0. Drum 

CO-10 

^.03629 

. 0257* 

CO 
frt - EPA Code Number 

cit y - Tone of Cyclohexanone/Yr. 

kage Production - Tons of Cyclohexanone/Yr. 

Irterly Production Variation - 7. of Max. 

laaiona to Atooaphere 

|St ream 

TABLE CO-111 

NATIONAL EMISSIONS INVENTORY 

CYCLOHEXANONE PRODUCTION 

9-3 

51,000 

Page 3 of 6 

(4) 

Oxidlrer "Spent 

Air" Vent 

Flov - lb./hr. 

Flov Characteristic - Contlnuoua or Intermittent 

If Intermittent - hra./yr. flov 

Coapoaltlon - Tona/ton of Cyclohexanone 

Cyclohexane 

Cyclohexanone 

Cyclohexanol 

Methane 

Ethane 

Ethylene 

Nitrogen 

Oxygen 

Hydrogen 

Carbon Monxlda 

Carbon Dioxide 

Water 

Miac. Hydrocarbons 

Saapla Tap Location 

Date or frequency of Saapllng 

Type of Analysis 

Odor Problems 

pant Stacks 

Plow - SCFM/Stack 

Number 

Height - Feet 

Diameter - Inches 

Bait Gas Temp. - F° 

•mission Control Devices 

Type - Incinerator 

Flare 

Scrubber 

Other 

Catalog I.D. Nuaber 

iTotal Hydrocarbon Ealaalona - Ton/ton of Cyclohexanone 

Total Particulate & Aerosol Emits long - Ton/ton of Cyclohexanone 

llotal HO, " " 

Total SO, " 

Total Co " 

31,560 

Contlnuoua 

.01913 

.00112 

.00029 

+ 

.01527 

? 

Irregular 

GLC 

Not Specified 

Yea 

CO-5 AfcB 

0 

(4) 

Oxidizer "Spent 

Air" Vent 

12,400 

Continuous 

.04208 

.00492 

.00043 

+ 

CO-6 AoB 

Diatlll./Purf. 

Vaste Stream 

Incinerator 

Flue Cas 

Cround Flare 

Flue Gaa 

Not Specified 

Continuous 

1750 Msx. 

Intermittent 

. UIDOX 

7 

Irregalar 

CLC 

Not Specified 

Yea 

+ 

+ 

Burner 

Yea 

Yea 

6814 

1 

36 

72 

1800 

Yea 

+ 

Stack 

+ 

Never 

Not Specified 

Yes 

9-1 

12.000 

Cyclohexanol Not Specified 

Dehydrosanatlon 

Vent 

Continuous 

.00071 

.00081 

c.00001 

_.00001 

.00002 

.02277 

CO-7 

. 06968 

.03089 

CO-8 

Irregular 

GLC 

No 

Yea 

846 

1 

12 

8 

70° 

Yea 

+ 

CO-9 
C - EPA Code Number 

:lty - Tone of Cyclohexanone/Yr. 

•ge Production - Tona of Cyclohexanone/Yr. 

terly Production Variation - I of Max. 

alone to Atmosphere 

traaa 

lov - lb./hr. 

low Characteristic - Continuous or Intermittent 

If Intermittent hra./yr. flov 

lomposltlon - Tons/ton of Cyclohexanone 

Cycloheaaoe 

Cyclohexanone 

Cyclohexanol 

Methane 

Ethane 

Ethylene 

Nitrogen 

Oxygen 

Hydrogen 

Carbon Monoxide 

Carbon Dioxide 

Water 

Misc. Hydrocarbons 

Sample Tap Location 

Data or Frequency of Sampling 

Type of Analysis 

Oder Pro*, lea -

it Stacka 

Plow SCFM/Stack 

Number 

Height - Feat 

Diameter - Inches 

Exit Cas Temp. F° 

lesion Control Devices 

Type - Incinerator 

Flare 

Scrubber 

Other 

Catalog I.D. Number 

tal Hydrocarbon Emissions - Ton/ton of cyclohexanone 

1 Particulat e e. Aerosol -

.tsl HO. 

,tal SOJ 

itsl CO Emissions - Ton/ton of Cyclohexanone 

TABLE CO-III 

NATIONAL EMISSIONS INVENTORY 

CYCLOHEXANONE PRODUCTION 

9-7 

75,000 

Page 4 of 6 

Unspeci fied 

Oxidatlion Section 

Vent 

Not Specified 

Continuous 

.00116 

None 

Never 

Calc'd. 

No 

Yea 

10 

1 

40 

1.5 

85° 

None 

Oxidation 

"Air" Vent 

76,675 

Continuous 

.00652 

.00253 

Purification 

Section Steam 

Jet Discharge 

Cyclohexanol 

Dehydrogenstlon 

Vent 

Flue ('as ex 

Incineration of VSrloua 

Vaste Streams 

1.42762 

.01445 

69 

Continuous 

.00051 

1970 

Mass 

No 

Yes 

6000 

1 

~ 1 5 

16 

70° 

Yea 

+ 

Spec 

C0-IA6.B 

& CLC 

Nona 

Never 

Estimate 

No 

Yea 

5 

3 

55 

1.5 

150 

No 

.01141 

.01459 

700 

Contlnuoua 

.00067 

^.00001 

-.00001 

..00001 

.00002 

/wlOOO (1) 

Contlnuoua 

.01088 

.00014 

1969 

Mass Spec 

No 

Yea 

630 ' 

1 

40 

3 

34 

Yea 

Condenser 

CO-2 

& CLC 

None 

Never 

No 

Yea 

<vl5.000 

1 

30 

72 

1750 

Yea 

+ • 

CO-3 
Plan

t - EPA Code Number 

Capacity - Tona of Cyclohexanone/Yr 

Average Production - Tona of Cyclohexanone/Yr. 

Quarterly Production Variation - 7. of Max. 

Ealaalone to Atmoaphere 

Stream 

Flov - lb./hr. 

Flov Characterlatlc - Contlnuoua or Intermittent 

If Intermittent hra./yr. flov 

Composition - Tons/ton of Cyclohexanone 

Cyclohexene 

Cyclohexenone 

Cyclohexanol 

Methane 

Ethane 

Ethylene 

Nitrogen 

Oxygen 

Hydrogen 

Carbon Monoxide 

Carbon Dioxide 

Water 

Misc. Hydrocarbona 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problems 

Vent Stscks 

Flov SCFM/Stack 

Number 

Height - Feet 

Diameter - Inchea 

Eslt Caa Temp. F° 

Emission Control Devices 

Type - Incinerator 

Flare 

Scrubber 

Other 

Catalog I.D. Number 

Total Hydrocarbon Emissions - Ton/ton of cyclohexanone 

Total Particulste & Aerosol - " " 

Totsl HO, 

Totsl SO, 

Totsl CO 

TABLE CO-III 

NATIONAL EMISSIONS INVENTORY 

CYCLOHEXANONE PRODUCTION 

9-4 

75,000 

Page 5 of 6 

Oxidation 

"Air" Vent 

38.837 

Continuous 

.00383 

1.88830 

.00649 

.10106 

.04069 

.02543 

Celc No 

Yes -

3750 ie 60 6" 

70° No 

d. 

2 

4580 

1<5> 

195 

Yea 

Purification 

Section Stream 

Jet Discharge 

Not Specified 

.01500 

None 

Estimate 

None 

None 

(2) 

CO-4 

.04426 . 10106 

TJ 
TABLE CO-III 

EXPLANATION OF NOTES 

NATIONAL EMISSIONS INVENTORY 

CYCLOHEXANONE PRODUCTION Page 6 of 6 

(1) Prior to combustion. 

(2) A portion of this stream vents through an unlit flare. 

(3) No entry. 

(4) The quantities listed below are believed to be the sum of the emissions 

from the two identical streams that make up this entry. 

(5) Capacity calculated by Houdry based on stated cyclohexane feed. Basis -

.7673 ton cyclohexanone per ton of cyclohexane feed; ratio from questionnaire data. 

(6) Flow prior to combustion in off-site flare. 

(7) Operator states flow is from scrubber but gives no details. 

(8) Capacity calculated by Houdry, based on pro-ration from EPA Code No. 5-2. 
nt EPA Code No. 

duc t 

acity . Tons of DMT o r (Enuivalen t DMTWYr. 

sslon a t o Atmospher e 

Stream 

Flov - Lbe./Hr. 

Flov - Contlnuoua or Intermittent 

if Intermittent - Hra./Yr. Flov 

Composition - Ton/Ton DMT or 'Enuivalent DMT) 

TPA 

Acetic Acid 

Water 

Carbon Monoxide 

Carbon Dioxide 

Oxygen 

Nitrogen 

Methyl Acetate 

Xylene 

Propyl Acetat e 

Acetaldehyd e 

Dimethyl Ethe r 

Methyl Alcoho l 

Sulfu r Dioxid e 

DMT 

Metal Oxldea 

Bensol c Aci d 

P-Tolui c Aci d 

P-Carboxyl Benaaldehyd e 

Hydrogen 

Mlac. Ligh t Hydrocarbons - a s Methane 

Vent Stacka 

Number 

Height - Fee t 

Diameter - Inche s 

Exit Cas Temp. - F° 

SCFM/Stack 

Type of Emission Contro l Devic e Employed 

Control Devic e I. D. No. 

Analysis 

Date or Frequency of Sampling 

Sample Tap Locatio n 

Type of Analysis 

Odor Problem 

•ry of Ai r Pollutant s - T/T of DMT or fKquivalent) 

Hydrocarbons 

Particulate s o r Aerosols 

NO, 

SO, 

CO 

TABLE DT-lIl 

NATIONAL EMISSION INVENTORY 

DMT AND TPA PRODUCTION 

VIA 

VARIOUS PROCESSES 

10- 1 (A) 

TPA 

(290,000) 

Oxidizer Vent 

256.000 

Continuous 

(.01886) 

(.11895) 

(.25946) 

(3.44695) 

(.00308) 

(.00077) 

(.00077) 

(.00039) 

(. 00980) 

(.00036) 

( .02017) 

Page 1 of 7 

Filter, Dryer. 

Silo Vent 

18,470 

Continuous 

(.00036) 

(.00348) 

(.00227) 

(.00131) 

(.00852) 

(.02167) 

(.24011) 

(.00005) 

Yes 

18 

31 to 64 

3 to 10 

None 

Monthly 

At Vent 

CLC 

No 

Distillation 

Section Vent 

(.00028) 

(.00259) 

(.00068) 

(. 00003) 

( 00066) 

Yes 

4 

21 to 40 

2 to 4 

None 

Monthly 

At Vent 

CLC 

No 

A) Planta 10-1 and 10-6 are part of tlio same overall facility. 
-f v «J 

• ,-* 

lent EPA Code No. 

Toduct 

apeclty, Tona of DMT or (Equivalent)*/Yr. 

missions to Atmosphere 

Stream 

Flo v - Lbs./Hr . 

Flo v - Contlnuoua or Intermitten t 

i f Intermitten t - Hrs./Yr . Flo v 

Composition - Ton/Ton DMT or (Equivalen t DMT) 

TPA 

Aceti c Acid 

Water 

Carbon Monoxide 

Carbon Dioxid e 

Oxygen 

Nitroge n 

Methyl Acetat e 

Xylene 

Propyl Acetat e 

Acetaldehyd e 

Dimethy l Ethe r 

Methyl Alcoho l 

Sulfu r Dioxid e 

DMT 

Natal Oxides 

sensol c Acid 

Para Tolul c Aci d 

Para Carboxyl Benxaldehyde 

Hydrogen 

Misc . Ligh t Hydrocarbons - a s Methane 

Vent Stack s 

Number 

Height - Fee t 

Diamete r - Inche s 

Exi t Gas Temp. - F° 

Flo v - SCFM/Stack 

Emiaslon Contro l Devic e 

Type 

I. D. Number 

Analysis 

Date or Frequency of Sempllng 

Sample Tap Location 

Type of Analyata 

Odor Problem 

Summary of Air Pollutants T/T of DMT or (Equivalent DMT) 

Hydrocarbons 

Particulates & Aerosols 

N O , 

•°x 

CO 

Oxidize r 

Vent 

Unknovn 

NATIONAL EMISSIONS INVENTORY 

DMT AND TPA PRODUCTION 

VIA 

VARIOUS PROCESSES 

10-2 

TPA 

(84.240 ) 

Condensatio n 

Sectio n 

97,03 5 

Continuou s 

(.00107 ) 

(.00024 ) 

(4.00158 ) 

(.00482 ) 

(00061 ) 

Yes 

1 

64 

24 

212 

Yes 

Scrubber 

DT-12 

(.02485) 

(.00021) 

(.00003) 

(.00146) 

(.01182) 

Yes 

1 

120 

72 

310 

73,000 

Yea 

Bag Filte r 

DT-13 

"Aa Required " 

(3 Platform 

EPA Method No. 5 & Desig n Calc'd . 

No 

(07757 ) 

(.00223 ) 

0 

0 

(.01007 ) 

Page 2 of 7 

Condensatio n 

Sectio n 

105,597 

Continuou s 

(.00116 ) 

(.00026 ) 

(4.35466 ) 

( 00525) 

(.00066 ) 

(.02704 ) 

(.00023 ) 

(.00003 ) 

(.00159 ) 

(.01286 ) 

Yes 

1 

120 

72 

310 

Yes 

Beg Filte r 

DT-14 

"As Required " 

(3 platfor m 

EPA Method No. 

No 

Incinerato r 

Flu e Gas 

Unknovn 

Yes 

1 

50 

52 

550 

No 

None 

5 & Desig n Calc'd . 
i r 3 1 

r

y

 r"7 

TABLE DT-III 

Plsnt EPA Code No. 

Product 

Capacity, Tona of DMT or (Equivalent DMT)*/Yr. 

Emissions t o Atmosphere 

Streea 

Flov - Lbs./Hr. 

Flov - Contlnuoua or Intermittent 

If Intermittent - Hrs./Yr. Flov 

Composition - Ton/Ton DMT or (Equivalent DMT) 

TPA 

Acetic Acid 

Water 

Carbon Monoxide 

Carbon Dioxide 

Oxygen 

Nitrogen 

Methyl Acetete 

Xylene 

Propyl Acetata 

Aceteldehyde 

Dimethyl Ether 

Methyl Alcohol 

Sulfur Dioxide 

DMT 

Natal Oxldea 

Bensolc Acid 

P-Tolulc Acid 

P-Carboxyl Bensaldehyde 

Hydrogen 

Misc. Light Hydrocarbons - as Methane 

Vent Stacka 

Number 

Height - Feet 

Diameter - Inches 

Exit Cas Tamp. - F° 

SCFM/Stack 

Type of Ealeelon Control Device Employed 

Control Device I. D. No. 

Analysis 

Date or Frequency of Sampling 

Sample Tap Location 

Type of Analysis 

Odor Problem 

ry of Air Pollutants - T/T of DMT or (Equivalent) 

Hydrocarbona 

Particulates or Aerosols 

NOx 

SO, 

CO 

Oxidize r 

Vent 

229,00 0 

Continuous 

NATIONAL EMISSIONS INVENTORY 

DMT AND TPA PRODUCTION 

VIA 

VARIOUS PROCESSES 

Incinerato r 

Flue Gas 

69,85 0 

Continuous 

10- 4 

DMT 

300,00 0 

Purificatio n Sectio n 

Scrubbe r Vent 

5,03 4 

Continuou s 

Purificatio n 

Emergency Vent 

Unknovn 

Intermitten t 

Page 3 of 7 

Reacto r Sectio n 

Ejecto r Discharg e 

942 

Continuous 

Purificatio n 

Vent 

8 

Continuous 

Other 

Emission s 

5,72 0 

Unknovn 

.00938 

15 Sec./Incident 

.01395 

.03096 

) 

)3.14856 

) 

.29230 

.00223 

) 

).67985 

) 

.00022 

.00068 

) 

).0691 9 

) 

TR 

.00031 

.00255 

Yes 

27 

100 

30 

8 5 

25.00 0 

Absorbe r 

DT-4 

Weekly 

Stac k Base 

CLC 

No 

Yes 

1 

100 

60 

4 5 0 

1,80 0 

Incinerato r 

DT-5 

Weekly 

@ WHB 

Various 

No 

Yes 

1 

90 

12 

50 

6 0 0 

Scrubbe r 

DT-6 

Semi-Weekly 

Scrubbe r Outle t 

CLC & Cas Part i t lone r 

No 

.0904 7 

+ 

.0025 5 

.0338 9 

+ 

+ 

Not Specified 

None 

None 

No 

.00031 

.00002 

) 

).01209 

) 

00075 

Yes 

2? 

60 

6 

85 

100 

Scrubber 

DT-7 

None 

At Scrubber 

Calc'd. 

No 

.00001 

).00006 

) 

.00003 

.0800 

Not Specified No 

None None 

None i None 

Calc'd 

No 

Calc'd 

XI 
' ' ( 

I

at EPA Code No. 

duc t 

iclty , Tona of DMT or <Eaulvelent)*/Yr. 

[aslon s t o Atmospher e 

Strea a 

Flov - Lbs./Hr. 

Flov - Contlnuoua or Intermittent 

If Intermittent - Hra./Yr. Flov 

Composition - Ton/Ton DMT or (Equivalent DMT) 

TPA 

Acetic Acid 

Water 

Carbon Monoxide 

Carbon Dioxide 

Oxygon 

Nitrogen 

Methyl Acatete 

Xylene 

Propy l Acetat e 

Aceteldahyd e 

Dlaathy l Ethe r 

Methyl Alcohol 

Sulfu r Dioxide 

DMT 

Metal Oxide s 

Benzoi c Acid 

Pare Tolul c Aci d 

Pare Carboxyl Bensaldehyd e 

Hydrogen 

Misc . Light Hydrocarbons - a a Methane 

Vent Steck a 

Number 

Height - Fee t 

Diamete r - Inche s 

Exi t Gas Temp. - F° 

Flo v - SCFM/Stack 

Emissio n Contro l Devic e 

Type 

I. D. Number 

Analysis 

Dst e or Frequency of Samplin g 

Sample Tap Locatio n 

Type of Analysis 

Odor Problem 

Sum—try o f Ai r Pollutants T/T o f DMT or (Equivalen t DMT) 

Hydrocarbons 

particulate s U Aerosols 

NO, 

S O, 

CO 

TABLE DT-U l 

NATIONAL EMISSIONS INVENTORY 

DMT AND TPA PRODUCTION 

VIA 

VARIOUS PROCESSES 

10-5 

TPA 

(241,000 ) 

Oxidize r 

Vent 

5,72 0 

Continuou s 

(.00163 ) 

+ 

(.01591 ) 

) 

)(2.43726) 

) 

(.00513) 

Surg e Tenk 

Vent 

1,23 8 

Continuous 

(.00024) 

(.00229) 

) 

)(.01823 ) 

) 

(.00020 ) 

Psge 4 of 7 

Storag e Sil o 

Vent 

11,42 8 

Intermitten t 

82 

(< .00001 ) 

«.0000l ) 

) 

) ( .19346 ) 

) 

Residue Incinereto r 

Flue Gas 

74,50 8 

Intermitten t 

7.344 

(1.13502 ) 

(.00012) 

Yes 

1 

77 

18 

116 

32,15 0 

Yes 

High Pressur e Absorbe r 

DT-8 

Occeslona l 

Accessibl e 

CLC 

No 

Yes 

1 

65 

18 

120 

3 0 0 

Yes 

Scrubbe r 

DT-9 

Occeslona l 

Accessibl e 

GLC 

No 

Yes 

1 

140 

12 

275 

1,00 0 

Yes 

Bag Filte r 

DT-10 

Never 

Accessibl e 

Calc' d 

No 

(.00855 ) 

(.00012 ) 

0 

0 

(01591 ) 

Yes 

1 

125 

4 2 

600 

16.55 0 

Yes 

Precipitato r 

DT-ll 

Never 

Calc'd . 

No 

Solven t 

De hydrator 

15.650 

Continuous 

(.00025) 

(26357) 

(.00110 ) 

No 

No 

Once/Shift 

Accessible 

Titration 

No 
i r 

Plant BPA Code No. 

Product 

Capacity, Tons of DMT or (Equivalent DMT)*/Yr. 

Emissions to Atmosphere 

Stream. 

Flov - Lbs./Hr. 

Flov - Continuous or Intermittent 

if Intermittent - Hra./Yr. Floy 

Composition - Ton/Ton DMT or (Equivalent DMT) 

TPA 

Acetic Acid 

Water 

Carbon Monoxide 

Carbon Dioxide 

Oxygen 

Nitrogen 

Methyl Acetete 

Xylene 

Propy l Acetat e 

Acetaldehyd e 

Dlaathy l Ethe r 

Methyl Alcoho l 

Sulfu r Dioxid e 

DMT 

Metal Oxldaa 

Bensolc Acid 

P-Tolui* Acid 

P-Carboxyl Bensaldehyde 

Hydrogen 

Misc . Light Hydrocarbons - a s Methane 

Vent Stack s 

Number 

Height - Fee t 

Diamete r - Inche s 

Exi t Cas Teap. - F° 

SCFM/Stack 

Type o f Emissio n Contro l Devic e Employed 

Contro l Devic e I. D. No. 

Analysi s 

Data or Frequency o f Sampling 

Sample Tap Locatio n 

Type o f Analysis 

Odor Problem 

Summary o f Ai r Pollutants - T/T of DMT or (Equivalent) 

Hydrocarbons 

Particulate s or Aerosols 

NO, 

SO, 

CO 

(A) Plants 10-1 and 10-6 are part of tlie same overall facility. 

(B) Thla stream never sampled, but estimated to be essentially the 

TABLE DT-111 

NATIONAL EMISSIONS INVENTORY 

DMT AND TPA PRODUCTION 

VIA 

VARIOUS PROCESSES 

10- 6 (A) 

DMT 

290,00 0 

Reactor Vent 

2 

Continuous 

<.00001 

<.00001 

.00002 

.00001 

Yea 

1 

50 

2 

70° 

None 

One Session 

At Vent 

Unknovn 

No 

Methanol Recovery 

Vent (B) 

~ 2 

Continuous 

.<.0000l 

^x<. 00001 

^/. 00002 

os/. 00001 

Yes 

1 

100 

3 

70° 

None 

Never 

Estimate 

No 

Page 5 of 7 

Methenol Recovery 

Vent 

415 

Continuous 

.00107 

.00055 

.00433 

.00031 

Yes 

I 

50 

4 

70° 

None 

One Session 

At Vent 

Unknovn 

No 

.00651 

.00077 

Crude Product 

"Hold-Up" Vent 

3 

Continuous 

00005 

Yes 

1 

30 

3 

70° 

Condenser 

DT-1 

Never 

Estimate 

No 

lame as the on preceedlnK it in the tabulation fl0-6 react or vent). 
len t EPA Code No. 

•redact 

-peclty , Tons o f DMT o r (Equivalen t DMT)*/Yr. 

Emissions t o Atmospher e 

Stream . 

|lov - Lbs./Hr. 

Flov <• Continuous or Intermittent 

if Intermittent - Hra./Yr. Flov 

Composition - Ton/Ton DMT or (Equivalent DMT) 

TPA 

Acetic Acid 

Water 

Carbon Monoxide 

Carbon Dioxide 

Oxygen 

Nitrogen 

Methyl Acetate 

Xylene 

Propy l Acetet e 

Acetaldehyde 

Dimethy l Ethe r 

Methyl Alcoho l 

Sulfu r Dioxid e 

DMT 

Metal Oxlde a 

Benzoi c Ad d 

P-Tolul c Aci d 

P-Cerboxy l Bensaldehyd e 

Hydrogen 

Mac . Ligh t Hydrocarbons - a s Methane 

Vent Steck a 

Number 

- Height - Fee t 

Diamete r - Inche a 

Exit Cas Temp. - F° 

SCFM/Stack 

Type o f Emlaalon Contro l Devic e Employed 

Cootro l Devic e I. D. No. 

Analysis 

Dat e or Frequenc y of Sampling 

Sample Tap Locatio n 

Type o f Analyal a 

Odor Proble a 

Summary o f Ai r Follutant a - T/T of DMT or (Equivalent ) 

Hydrocarbone 

partlculate a o r Aeroaols 

NO, 

SO, 

CO 

TABLE DT-III 

NATIONAL EMISSIONS INVENTORY 

DMT AND TPA PRODUCTION 

' VIA 

VARIOUS PROCESSES 

10- 6 (A) 

DMT 

290,00 0 

Crude Product 

"Hold-Up" Vent 

Continuous 

.00005 

Yes 

1 

30 

3 

70° 

10 

Scrubber 

DT-2 

Never 

Estimate 

No 

Sludge 

Recovery Vent 

Continuous 

.00005 

Yes 

1 

30 

3 

70° 

10 

Condenser 

DT-3 

Never 

Estimate 

No 

SEE OTHER SHEET 

Page 6 of 7 

Methanol Stg . & 

Slurr y Prep. Vent 

10.40 0 

Continuous 

.00077 

.00602 

.00875 

. 14086 

No 

No 

Dall y 

Oraat 

No 

Sludg e 

Recovery Vent 

Unknovn 

Continuous 

Yes 

1 

10 

10 

70° 

Yes 

Scrubber 

DT-17 

Never 

None 

No 

(A) Planta 10-1 and 10-6 are part of the same overall facility. 
Plan t EPA Code No. 

Produc t 

Capacity , Tons of DMT or (Equivalent)*/Yr . 

Emission s t o Atmosphere 

Strae a 

Flov - Lbs./Hr. 

Flov - Continuous or Intermittent 

if Intermittent - Hrs./Yr. Flov 

Composition - Ton/Ton DMT or (Equivalent DMT) 

TPA 

Acetic Acid 

Weter 

Carbon Monoxide 

Carbon Dioxide 

Oxygen 

Nitrogen 

Methyl Acetete 

Xylene 

Propyl Acetst e 

Aceteldehyd e 

Dimethyl Bth a r 

Methyl Alcoho l 

Sulfu r Dioxid e 

DMT 

Metal Ox Ida a 

Benzoi c Acid 

Para Tolul c Acid 

Par s carboxy l Bensaldehyd e 

Hydrogen 

Misc. Light Hydrocarbons - as Methane 

Vent Stacka 

Nuaber 

Height - Feet 

Dlaaeter - Inches 

Exit Caa Teap. - F° 

Flov - SCFM/Stack 

Ealaslon Control Device 

Type 

I. D. Nuafcer 

Analysis 

Date or Frequency o f Samplin g 

Sample Tap Locatio n 

Type o f Analysis 

Odor Problem 

try of Ai r Pollutants T/T of DMT or (Equivalen t DMT) 

Hydrocarbons 

Particulate s 4 Aerosols 

NO, 

S O , 

CO 

TABLE DT-111 

NATIONAL EMISSIONS INVENTORY 

DMT AND TPA PRODUCTION 

VIA 

VARIOUS PROCESSES 

10-7 

DMT 

180.00 0 

Vent 

52,59 0 

Continuous 

.0010 0 

.0016 3 

.0338 8 

.1477 1 

.8607 1 

NO, .00021 

Purificatio n 

Sectio n Vent 

Unknovn 

NH3 - .00017 

N20 - .05033 

Yea 

1 

120 

24 

351 

10,500 

Yea 

Catalytic Incinerator 

DT-15 

Weekly (NO,) 

Accessible 

Colorlmetrlc 

No 

Yes 

1 

80 

8" 

Yes 

Flare 

DT-16 

Never 

None 

No 

.00225 

.00017 

.00021 

Page 7 of 7 

Emergency 

Vent 

Unknovn 

Intermittent 

Unknovn 

Air Oxidizer 

Vent 

88.500 

Continuous 

Yes 

2 

100 

24 

No 

Never 

No 

.0044 6 

.0147 1 

.06938 

.04538 

I 6875 

00225 

Yes 

2 

50 

10 

50 

9.000 

No 

Semi-Annual 

Accessibl e 

I.R. 

No 

.01634 
TABLE E-.— X11 

NATIONAL EMISSIONS"~INVENTORY 

ETHYLENE PRODUCTION Page 1 of 13 

pany 

atlon 

Code Number 

e on-atream 

aclty - Tons of Ethylene/Yr. 

irage Production - Ethylene. T/Yr. 

ige In Production - TL of Max. (f) 

aslons to Atmosphere 

Stream 

Flov - Lb./Hr. 

Flov CharacteriseIc - Continuous/Intermittent 

If Intermittent - Hrs.'Yr. of Flov 

Coapoaltlon - Tons/Ton Ethylene 

Hydrogen 

Methane 

Ethane 

Ethene 

Propane 

Propene 

C A + Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxide 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacks 

Flow, SCFM Per Stack 

Number 

Height - Feet 

Diameter - Inches 

Exit Caa Temperature - F° 

Emission Control Devices 

1 Type - Flare 

Water Scrubber 

Refrlgereted Condenaer 6 K. 0. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emlasions - Ton/Ton of Ethylene (g) 

Total Partlculate/Aeroeol Emissions - Ton/Ton of Ethylene 

Totel NO, 

Totel SO, 

Total CO 

11-1 

600,000 

540,000 

5 

Propane Vaporizer 

Vent 

<l 

Intermittent 

340 

.00001 

^.00001 

- .00001 

-•. 00001 

Quench Water 

Off-gas 

2850 

Contlnuoua 

*.00001 

-.00001 

_. 00001 

.00001 

.0208 

Emergency 

Vent 

15,000 

Intermittent 

0.05 

- . 00001 

•* . 00001 

_.. 00001 

•t.00001 

-.00001 

^.00001 

-.00001 

-.00001 

Cas Purlf. Section 

1,025 

Continuous 

Flare Sveep 

Gas 

720 (a) 

Contlnuoua 

(After Burning) 

.00749 .01356 

.01132 

C3 Storage 

GLC 

No 

.008 

1 

30' 

2" 

- 40 

No 

Tenk Not Specified 

1971 

Not Specified 

No 

111 

9 

12' 

8" 

194 

No 

Source 

Source 

GLC 

Yea 

7,000 

1 

100' 

30" 

113 

No 

Stream 

- 15 Mln. 

Not Sampled 

Aeaumed 

No 

146 

1 

240* 

30" 

Ambient 

Yea 

X 

Not Specified 

Every 15 Mln. 

CLC 

No 

284 

EL - 22 

<•. 00001 

.00001 
TABLE EL-111 

NATIONAL HHISST6HB INVENTORY 

ETHYLENE PRODUCTION Page 2 of 13 

hpsny 

tat Ion 

Code Number 

fee on-atream 

aclty - Tona of Ethylene/Yr. 

•rage Production - Ethylene , T/Yr. 

age In Production - X of Max. (*) 

Isalone t o Atmosphere 

Stream 

Flov - Lb./Hr. 

Flov Characterlatic - Continuous/Intermittent 

If Intermittent - Hre./Yr. of Flov 

Composition - Tons/Ton Ethylene 

Hydrogen 

Methane 

Ethane 

Ethane 

Propane 

Propane 

C + Hydrocarbona 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxide 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Seaple Tap Location 

Data or Frequency of Sampling 

Type of-Analysis 

Odor Problem 

Vent Stacks 

Flov, SCFM Per Stack 

Number 

Height - Feet 

Oleaster - inches 

Exit Cas Temperature - F° 

Emission Control Devices 

Type - Flare 

Water Scrubber 

Refrigerated Condenaer 6> K. 0. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton of Ethylene 

Total Partlculate/Aerosol Emissions - Ton/Ton of Ethylene 

Total NO, 

Total SO, 

Total CO 

11-2 

385.000 

0 

Acid Gas 

Vent 

9,180 (a) 

Continuous 

(After Burning) 

Distillation 

Emergency Vent 

800,000 (a) 

Intermittent 

Not Specified 

(After Burning) 

Not Specified 

Miscellaneous 

Leake 

20,000/Yr. 

Intermittent 

Not Specified 

.00003 

.22201 

.00065 

.15835 

None 

Calculated 

No 

None 

No 

None 

N. A. 

None 

(8) 

Not Specified 

I 

120' 

42 @ Tip 

1600 

Yea 

X 

EL - 18 

.00003 

.00065 

L 
TABLE EL-III 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 3 of 13 

any 

tlon 

Code Number 

on-atream 

city - Tone of Ethylene/Yr. 

age Production - Ethylene Tons/Yr. 

e In Production - % of Max. (f) 

alone to Atmoaphere 

Stream 

Flov - Lbs./Hr. 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - Hrs./Yr. Flov 

Coapoaltlon - Tona/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethene 

Propane 

Propene 

C,+ Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxides 

Sulfur Oxldea 

Hydrogen Sulfide 

Water 

Saaple Tap Location 

Date or Frequency of Sampling 

Type of Analyala 

Odor Problem 

nt Stacks 

Flov. SCFM Per Stack 

Nuaber 

Height - Feet 

Diameter - Inchea 

Exit Gee Teaperaturea - F° 

lias Ion Control Devices 

Type - Flare 

Water Scrubber 

Refrigerated Condenser 6. K. 0. Drum 

Other 

Catalog l. D. Number 

otal Hydrocarbon Emissions - Ton/Ton Ethylene (g) 

otal Particulate 6 Aerosol Emissions Ton/Ton Ethylene 

otal NO, 

otal SO, 

otal CO 

11-4 

145,000 

25 

Emergency Vent 

Prod. Frsct. 

(a) 36,000 (Max.) 

Intermi ttent 

Not Specified 

After Burning 

/ .00001 

Not Specified 

.00001 

Not Specified 

(coke) - .00001 

Weekly 

CLC 

No 

Yes 

Not Specified 

1 

Ground Level 

Yes 

X Smoke Suppressor 

El - 21 

Emergency Vent 

Prod. Frect. 

(a) 36,000 (Max.) 

Intermittent 

Not Specified 

After Burning 

_, 00001 

Not Specified 

.00001 

Not Specified 

(coke) -.00001 

Weekly 

CLC 

No 

Yea 

Not Specified 

1 

Ground Level 

Yes 

X Smoke Suppressor 

EL '?? 

.£.00001 

.00002 

.00001 

11-5 

450,000 

0 

Emergency Vent 

Methanator 

34 Lb./Yr. 

Intermittent 

Not Specified 

*- . 00001 

*.00001 

-.00001 

<-. 00001 

-.00001 

-.00001 

None 

Calculated 

No 

Not Specified 

No 

-• . 00001 

_.. 00001 

11-7 

325,000 

325,000 

18 

11-8 

127,500 

0 

Plant Flare 

System 

(a) 5,740 (Avg.) 

Continuous 

After Burning 

.00373 

.18298 

.10466 

Tvice Month 

GLC 

No 

Yes 

1500 

1 

225 

36 

400 

Yes 

X 

EL - 20 

Plsnt Flsre 

System 

Not Specified 

No 

Yes 

Not Specified 

1 

200 

24 (8 Tip 

Yes 

EL - 21 

Not Speci fied 

ro 
ny 

Ion 

!ode Number 

on-stream 

:lty - Tona of Ethylene/Yr. 

ige Production - Ethylene Tona/Yr. 

I in Production - X of Max. (f) 

lions to Atmosphere 

treaa 

lov • tba./Hr . 

lov Characterletlc - Contlnuoua or Intermitten t 

If Intermittent - Hra./Yr. Flov 

oaposltlon - Tone/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethane 

Propane 

Propane C4 + Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxides 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

I Odor Problem 

|nt Stacks 

Flov. SCFM Per Stack 

Number 

Height - Feat 

Diameter - Inchea 

Exit Cas Teaperaturea • F° 

•lesion Control Devices 

Type - Flere 

Water Scrubber 

Refrigerated Condenser & K. O. Drum 

Other 

Catalog 1. D. Number 

otal Hydrocsrbon Emissions - Ton/Ton Ethylene (g) 

otal Particulate & Aerosol Emissions Ton/Ton Ethylene 

otal NO, 

'otal SO, 

[otal CO 

TABLE EL-lIl 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION 

11-6 

100,000 

0 

Page 4 of 13 

(h) 

Unspeci fled 

Intermitten t 

Unspecified 

Flere Vent 

Unspecified 

Continuous 

One Is provided 

None 

None 

None 

Unspecified 

1 12 above scrubber 

6 

212 

Yes 

+ 

+ 

None 

EL-31 

Unspecified 

Unspecified 

Yea 

+ 

EL-32 

None 

None 

None 

None 

None 

ajasgE—wn»ii|u j—> iiipiiiasiwJtsufttf'i\ 

ro 
= r. i i i i 

1 j 

TABLE EL-111 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 5 of 13 

ompany 

ocatlon 

PA Code Number 

at e on-atream 

apaclty - Tons of Ethylene/Yr. 

verage Production - Ethylene Tons/Yr. 

ange In Production - X of Max. (£> 

alaalons t o Atmosphere 

Stream 

Flov - Lba./Hr. 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - Hrs./Yr. Flov 

Compoaltlon - Tons/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethane 

Propane 

Propane 

C,+ Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxides 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Sample Tap Location 

bate or Frequency of Sampling 

Type of Analyels 

Odor Problem 

Vent Stacks 

Flov - SCFM Per Stack 

Number 

Height - Feet 

Diameter - Inches 

Exit Gas Teaperaturea - F° 

Emission Control Devlcaa 

Type - Flare 

Weter Scrubber 

Refrigerated Condenser & K. 0. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton Ethylene 18' 

Total Particulate 4 Aerosol Emissions Ton/Ton Ethylene 

Total NO, 

Total SO, 

Total CO 

11-9 

600,000 

600,000 

D 

Plant Flare 

System 

9,000 

Continuous 

After Burning 

.00504 

.02374 

.06799 

None 

No 

Yes 

1 

360 

60 

1,000 

Yes 

X 

(b) 

Hydrogenatlon 

Catalyst Regeneration Vent 

8,150 

Intermittent 

216 

Not Specified 

_EL. _L7_ 

None 

Not Sampled 

Yes 

300,000 (d) 

1 

260 

192 

260 - 300 

Yea 

X K. 0. Drum 

EL - 12 

Cannot be Determined 

Acid Cas 

Vent 

1800 - 2600 

Contlnuous 

(c) 

.00492 

.00820 

.00028 

Cj to C7 HC .00197 

Not Specified 

Not Specified 

Mass Spec. 

No 

Not Specified 

Yes 

X Clsus Unit 

N. A. 
TABLE EL-111 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 6 of 13 

ny 

tlon 

Code Number 

on-atream 

cit y - Tons of Ethylene/Yr. 

age Production - Ethylene Torts/Yr. 

a In Production - 7. of Max 

alens to Atmosphere 

treea 

(t 

'lov - Lbs./Hr. 

'lov Characteristic - Continuous/Intermittent 

if Intermittent - Hrs./Yr. Flov 

Coapoaltlon - Tons/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethene 

Propane 

Propane 

C.+ Hydrocarbona 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxldea 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Sample Tap Location 

Date or Frequency of Sampling 

Typo of Analysis 

Odor Problem 

ant Stacks 

Flov - SCFM Per Stack 

Number 

Height - Feet 

Diameter - inchea 

Exit Cas Teaperaturea - F° 

lesion Control Devices 

Type - Flare 

Water Scrubber 

Refrigerated Condenser 6 K. 0. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton Ethylene (fO 

Total Particulat e 4 Aerosol Emissions Ton/Tone Ethylene 

Totsl NO, 

Total SO, 

Total CO 

Vent From 

Furnace Decoking 

3,179 

Intermittent 

Not Specified 

11-10 

330 000 

0 

Acid Gas 

Vent 

Not Specified 

Continuous 

1968 

CLC 

No 

Yes 

1,000 

1 

200 

24 

200 

No 

Not Specified except SO. 

.00121 

T 

Incinerator Feed 

2 or 3 tlmea/10 Yr. 

CLC, Orsat, Wet 

No 

Yes 

24,000 

1 

120 

36 

780 

Yes 

X Incinerator 

EL ' 9 

.00108 

.00121 

Demethanizer 

Emergency Vent 

505 Ton/Yr. 

Intermittent 

Not Specified 

Ct

+ HC 

None 

No 

Yes 

.00153 

1 

160 

10 

200 

No 

C„ Splitter 

Emergency Vent 

358 Ton/Yr. 

Intermittent 

Not Specified 

"2 

None 
TABLE EL-111 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 7 of 13 

any 

tlon 

Cade Number 

a-stream 

iclty - Tons of Ethylene/Yr. 

rege Production - Ethylene Tona/Yr. 

(e In Production - X of Max. (f) 

islons to Ataoephera 

Itream 

Flov - Lbs./Hr. 

Plow Chsracterletl c - Contlnuoua or Intermittent 

i f Intermittent - Hre./Yr. Flov 

Composition • Tons/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

•sbylene 

Propane 

Prepylaoa 

C4 + Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbarn Mdalda 

Nitrogen Oxides 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Seapla Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

snt Stacks 

Flov. SCFM Par Stack 

Number 

Height - Feat 

Diameter • inchea 

'Exit Caa Teaparaturea - F° 

ialsalon Control Davlcee 

Type - Flare 

Water Scrubber 

Refrigerated Condenser 6> K. 0. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton Ethylene (g) 

Total Particulate 4 Aeroaol Eraiseions Ton/Ton Ethylene 

tota l NO, 

Total SO, 

Total CO 

Flare Stack 

Unspecified (Variable) 

Cont1nuoua 

+ 

+ 

11-11 

197,500 

0 

Safety Valve 

Dlacharge Stack 

Unspecified 

Intermittent 

Unspecified 

§0.00006 (j) 

lo.0005 (j) 

jo.0011 (j) 

)0.00008 (j) 

Ges Turbine 

Lube 011 Vent 

225 

Continuous 

Z 0.000002 

^0.000001 

0.00013 

Z 0.000002 

JO. 005 

Compressor Oil 

Reserves* Vent 

78 

Contlnuoua 

£0.000001 

^0.000004 

^ 0.000005 

- 0.00002 

lo.0017 

+ 

None 

None 

Unspecified 

1 

300 

36 

Unspecified 

Yea 

X 

EL-33 

Compressor Sour 

Drum K. 0. Vent 

80 

Contlnuoua 

0 00016 

0.001 

0 0005 

Trace 

$0.00013 

Not Specified 

Not Specified 

Not Specified 

None 

Unspecified 

1 

150 

20 

Unspecified 

None 

See Continuation 

Not Specified 

Once 

Mass 

None 

49 

1 

50 

2 

80 

None 

Spectrom 

(Simple) 

seter 

Not Specified 

Once 

Mass 

None 

17 

1 

60 

4 

80 

None 

(Staple) 

Spectrometer 

Not Specified 'Simple) 

Once 

Maaa Spectrograph 

No 

17 

1 

60 

4 

80 

None 

I 
TABLE EL-111 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 8 of 13 

Company 

Location 

EPA Code Number 

Date on-atream 

Capacity - Tona of Ethylene/Yr. 

Averege Production - Ethylene Tons/Yr. 

Range In Production - 7. of Max. (f) 

Emissions to Atmosphere 

Stream 

Flov - Lbs./Hr. 

Flov Characteristic - Contlnuoua or Intermittent 

If Intermittent - Hrs./Yr. Flov 

Composition - Tons/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethylene 

Propane 

Propylene 

C^ + Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxldaa 

Sulfur Oxldaa 

Hydrogen Sulfide 

Weter 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stecke 

Flov, SCFM Per Stack 

Number 

Height - Feet 

Dlaaatar - Inchea 

Exit Caa Teaperaturea - F° 

Emission Control Devices 

• Type - Flare 

Water Scrubber 

Refrigerated Condenaer t. K. 0. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton Ethylene (g) 

Total Particulate 6» Aerosol Emissions Ton/Ton Ethylene 

Total NO, 

Total SO, 

Total CO 

11-11 

197,500 

0 

Sour Seal 

Oil Vent 

150 

Contlnuoua 

0.0003 

.00074 

1.00148 5° 

T 

0.00053 

0.00028 

Not Specified (Simple) 

Once 

Maaa Spectrograph 

No 

26 

1 

50 

1 

80 

None 

Anelyeer 

Vent 

.£0.01 

Continuous 

u? 3*.ld6 

v_id6 

Not Specified (Simple) 

Not Specified 

Maaa Spectrograph 

No 

0.1 SCFH 

1 

10 

1/4 

80 

None 

See Continuation 

Fourth Stage Relief 

Valve Vent 

245 000 

Intermittent 

0.25 (i) 

Il66 

10.000155 

Not Specified (Simple) 

Not Specified 

Mass Spectrometer 

No 

35,000 

•el 196 

None 

00 
TABLE EL-111 

pany 

atlo n 

Code Number 

a on-strea a 

taclt y » Tons o f Ethylene/Yr . 

irage Production - Ethylen e Tona/Yr . 

lge i n Productio n - I o f Max. (f ) 

Lsslons t o Atmosphere 

Stream 

Flov - Lbs./Hr. 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - Hra./Yr. Flov 

Composition - Tons/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethylene 

Propane 

Propylene 

CA + Hydrocsrbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxides 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Sample Tap Locatio n 

Dat e or Frequency o f Sampling 

Type o f Analysis 

Odor Problem 

rent Steck e 

Flov , SCFM Per Stack 

Number 

Height - Feet 

Disaste r - Inchea 

Exit Cas Teapersture s - F° 

Emission Contro l Device s 

Type - Flar s 

Wste r Scrubbe r 

Refrigerate d Condense r 4 K. 0 . Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions 

Total Particulate 4 Aeroaol 

Total NO, 

Total SO, 

Total CO 

- Ton/Ton Ethylene (g) 

Emissions Ton/Ton Ethylene 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION 

Depropanizer Relief 

Valve Vent (Bottom) 

214.000 

Intermittent 

0.25 (i) 

>0.00003 

30.000053 

»0.000035 

0.000018 

11 

197 

-11 

,500 

0 

Depropanizer Relief 

Valve Vent (Top) 

230.000 

Intermittent 

0.5 (1) 

10.00003 

IP 00013 

Vo.00014 

<.io-° 

Page 9 of 13 

Not Specifie d (Simple ) 

Not Specifie d 

Maaa Spectromete r 

No 

None 

46,000 

^ 4 0 

None 

Not Specifie d (Simple ) 

Not Specifie d 

Maaa Spectromete r 

No 

None 

46,000 

^1-5 

None 

See Continuatio n 

Depropenlze r 

Overheed Relie f Vent 

230,00 0 

Intermitten t 

0.2 5 (1 ) 

>0 000015 

tO 000065 

10.00007 

_:io-6 

Not Specified (Simple) 

Not Specified 

Masa Spectrometer 

No 

None 

45,300 

-.50 

None 

Debutanlzer 

Overhead Relief Vent 

36,000 

Intermittent 

0 25 (i) 

-6 l<uo 

0 000023 

Not Specified (Simple) 

Tvice Weekly 

Gas Chromatograph 

No 

None 

3,900 

None 

CO 
I I 1 1 » ' 

Company 

Location 

EPA Code Number 

Date on-atream 

Capacity - Tona of Ethylene/Yr. 

Average Production - Ethylene Tons/Yr. 

Range In Production - I of Max. (f) 

Emissions to. Atmosphere 

Stream 

plov Chirlcteri.tlc - Continuous or Intermittent 

if Intermittent - Hrs./Yr. Flov 

Composition - Tons/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethylene 

Propane 

Propylene 

C. • Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxides 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analyele 

Odor Problem 

Vent Stocks 

Flov. SCFM Per Stack 

Number 

Height - Feet 

Diameter - Inches 

Exit Cas Temperaturea - F~ 

Emlsslon Control Devlcea 

Type - Flare 

Water Scrubber 

Refrigerated Conden.er 4 K. 0. Drum 

Other 

Catalog I. D. «"-ber _ Ton8 /T o n Ethylene (g) ES Knsr. x_r.. _r.;--. ^ r.th,i.n. 

Totsl NO, 

Totsl SO, 

Total CO 

I 1 > 

TABLE El.-III 

NATIONAL EMISSIONS INVENTORY 

FTHYI.ENE PRODUCTION 

11-11 

197,500 

0 

Remote Operated 

Valve Vent 

320 

Continuous 

0.006 

0.0004 

0.00013 

0.00014 

lo.00045 

Not Specified (Simple) 

Once 

Maaa Spectrograph 

No 

115 

1 

50 

6 

80 

None 

Page 10 of 13 

Lube Oil 

Reservoir Vent 

6,100 

Continuous 

0.001 

^0.00001 

^0.00001 

0.0001 

\0 134 

Not Specified (Simple) 

Once 

Mass Spectrograph 

No 

1,320 

I 

50 

6 

80 

None 

0 00753 

None 

None 

None 

None 

m 

I 

1 

J^B 

n IH 1 

Seal Oil 1 

Reservoir Vent 

40 

Continuous 

^.O.OOOOl 

^0.00001 

zs> 00001 

_: 0 ooooi 

2^o ooi 

Not Specified (Simple) 

Once 

Haas Spectrograph 

No 

8 

1 

8 

* 

80 

None 

• ..ni >——— a i 

| 
TABLE EL-111 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 11 Of 13 

ompany 

ocation 

PA Code Number 

at e on-atream 

—pacity - Tons of Ethylene/Yr. 

.verage Production - Ethylene Tons/Yr. 

tange in Production - 7. of Max. (O 

jalaalons to Atmosphere 

Stream 

Flov - Lbs./Hr. 

Flov Characteristic - Continuous or intermittent 

if Intermittent - Hrs./Yr. Flov 

Composition - Tona/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethene 

Propane 

Propane 

C4+ Hydrocarbona 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxldee 

Sulfur Oxldea 

Hydrogen Sulfide 

Water 

Seaple Tap Location 

Date or Frequency of Sempling 

Type of Analyala 

Odor Problem 

Vent Stacka 

Flov - SCFM per Stack 

Number 

Height - Feet 

Diameter - lnchea 

Exit Gas Temperatures - F° 

Emlaslon Control Devices 

Type - Flare 

Water Scrubber 

Refrigerated Condenser 6. i:. O. Drum 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton Ethylene (S^ 

Total Particulate 4 Aerosol Emissions Ton/Ton Ethylene 

Total N0_ 

11-12 

225,000 

225,000 

0 

11-3 

800,000 

Total 

Total 

S°x CO 

Emergency Vent 

Prod. Fract. 

50,000 (Max.) 

Intermittent 

Not Specified 

Weekly 

CLC 

No 

Yes 

Not Specified 

1 

Ground Level 

Yes 

X 

X Smoke Suppressor 

EL - 24 

Not Specified 

Emergency Vent 

Prod. Fract. 

50,000 (Max.) 

Intermittent 

Not Specified 

1ST" 

Not Specified 

Weekly 

CLC 

No 

Yes 

Not Specified 

1 

Ground Level 

Yes 

X 

X Smoke Suppressor 

EL - 24 

TJ 

CO 
TABLE EL-111 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION 

ny 

Ion 

lode Nunber 

lon-straea 

pity - Tons of Ethylene/Yr. 

In Production - X of Max. (f) 

lions t o Atmosphere 

>t ream 

Flov - Lbs./Hr. 

Flov Characterlatlc - Continuous or Intermittent 

If Intermittent - Hss./Yr. Flov 

Coapealtlon - Tona/Ton of Ethylene 

Hydrogen 

Methane 

Ethane 

Ethene 

Propane 

Propane 

C.+ Hydrocarbons 

Acetylene 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Nitrogen Oxides 

Sulfur Oxides 

Hydrogen Sulfide 

Water 

Seaple Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

nt Stocks 

Flov - SCFM Per Stsck 

Number 

Height - Feet 

Diameter - Inches 

Exit Gaa Temperatures - F° 

ilsslon Control Devices 

Type - Flsre 

Water Scrubber 

Refrigerated Condenser 4 1". 0. Drum 

Other 

Catalog I. D. Number 

ota l Hydrocarbon Emissions - Ton/Ton Ethylene (g) 

ota l Particulate 6> Aeroaol Emissions - Ton/Ton Ethylene 

otal NOx 

'otal SO, 

otal CO 

11-13 

300,000 

Vent From 

Furnace Decoking 

Intermittent 

Not Specified 

Not Specified 

.02400 

Coke .00001 

(3 Furnace 

1969 

Coulter Counter 

No 

Yes 

4,290 

1 

78.5 

14 

212 

Yes 

EL 10 

Acetylene Converter 

Regeneration Vent 

460 

Intermittent 

408 

Not Specified 

Not Specified 

Not Specified 

Not Specified 

Not 

Not 

No 

Yes 

1 

42 

8 

140 

Yes 

Specified 

Sampled 

Page 12 of 13 

Caustic Neutrallz . 

Vent 

20,672 

Continuous 

Plant Flare 

System 

910 (s) 

Contlnuous 

'After. Burning) 

.06693 

.22406 

.00017 

Not Sampled 

Engr. Est. 

No 

Yes 

4,500 

1 

93 

8 

Ambient 

Yes 

EL 15 

X Vapor Collectors 4 Dilution Device 

EL - 11 

.03486 

.02852 

Not Sampled 

Calcuated 

No 

Yes 

I 

130 

36 

1800 - 2500 

Yes 

X 

EL - 30 

co 

ro 
TABLE EL-III 

EXPLANATION OF FOOTNOTES 

NATIONAL EMISSIONS INVENTORY 

ETHYLENE PRODUCTION Page 13 of 13 

(a) The flow rate given describes the stream prior to combustion. 

(b) 80,000 lb./hr. of a 927. methane stream - most probably the demethanizer 

overhead - is used to supplement the fuel to the pyrolysis furnace. 

This stream and it's resultant atmospheric emissions (CO2 & H2O) are 

not detailed elsewhere in this report. 

(c) This stream is not emitted to the atmosphere, it is sent to a Claus 

plant. 

(d) Boiler stack used. 

(e) Although there is a wealth of Information in this report; quantitative 

data on emissions are conspicuous by their absence, (with exception of 

motor exhaust data) 

(f) Difference between maximum and minimum quarterly production divided by 

maximum quarterly production. 

(g) Includes H2S. Excludes CH4 & Hj. 

(h) Three identical scrubbers are provided on the acetylene converter, 

propadiene converter and hydrogenation catalyst regeneration vents. 

The emissions from each are essentially the same. 

(i) Estimated maximum per year. 

(j) Calculated on basis of total of maximum estimated releases from each 

relief valve in circuit. 
EPA Code No. 

Capacity - Tons of EDC 

Average Production - Tons of EDC 

Emissions to Atmosphere 

Stream 

Flov - Lbs./Hr. 

Flov Character 1 atlc - Continuous or Intermittent 

If Intermittent - Hra./Yr. Flov 

Composition - Tons/Ton of EDC 

1,2 Dlchloroethane 

Vinyl Chloride 

Ethyl Chloride 

Methane 

Ethylene 

Oxygen 

Nitrogen 

Carbon Dioxide 

Carbon Monoxide 

Water 

Air 

Hydrogen Chloride 

Chlorine 

Hydrogen 

Analysis 

Sample Location 

Date or Frequency of Sampling 

Type of Analyaia 

Odor Problem 

Vent Stacke 

Number 

Height - Feet 

Diameter - Inches 

Exit Gas Temperature - F° 

Flov - SCFM 

Emission Control Devices 

Condenser 

Water Scrubber 

Spray Tover 

Total Hydrocarbon Emissions - Ton/Ton EDC 

Total Particulate 4 Aerosol Emissions 

Total NO Emissions - Ton/Ton EDC 

Total SO„ Emissions - Ton/Ton EDC 

Total CO Emissions - Ton/Ton EDC 

Ton/Ton EDC 

TABLE EDC-III 

NATIONAL EMISSIONS INVENTORY 

DICHLOROETHANE BY 

DIRECT CHLORINATION 

Scrubber Vent 

351 

Continuous 

.002675 

.003789 

.008658 

.007579 

.003965 

.000325 

.000184 

No 

Estimate 

On-Plant 

Yes 

1 

38 

4 

50 

65 

Yea 

Yes 

.006464 

0 

0 

0 

0 

12-1 

47,500 

47,500 

Primary Decanter Vent 

100 

Continuous 

.000588 

.000430 

.007754 

No 

Estimate 

On-Plant 

Yea 

3 

12 

1.5, 

90 

23 

No 

2.25 , 2 (D 

.000588 

0 

0 

0 

0 

Page 1 of 3 

Secondary Decanter Vent 

20 

Continuous 

.000118 

Fugitive Emissions 

Continuous 

( ) 

( 00009) 

( ) 

.000086 

.001550 

No 

Estimate 

On-Plant 

Yes 

2 

20 

1.54, 1.54 <l> 

80 

4.7 

No 

.000118 

0 

0 

0 

0 

.000091 

0 

0 

0 

0 

(1) Equivalent diameter. 

co 
TABLE EDC-III 

NATIONAL EMISSIONS INVENTORY 

DICHLOROETHANE BY 

DIRECT CHLORINATION Page 2 of 3 

PA Code No. 

apaclty - Tons of EDC 

verage Production - Tons of EDC 

Ealesions t o Atmosphere 

Stream 

12-2 

401,300 

401,500 

Scrubber Vent Scrubber Vent 

Flov - Lbs./Hr. 

Flov Characteristic - Continuous or Intermittent 

if Intermittent - Hrs./Yr. Flov 

Composition - Tons/Ton of EDC 

1,2 Dlchloroethane 

Vinyl Chloride 

Ethyl Chloride 

Methane 

Ethane 

Ethylene 

Oxygen 

Nitrogen 

Carbon Dioxide 

Carbon Monoxide 

Water 

Hydrogen Chloride 

Chlorine 

Air 

Analysis 

Sample Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacka 

Number 

Height - Feet 

Oleaster - laches 

Exit Cas Teaperature - F° 

Flov - SCFM 

EalBalon Control Device 

Condenser 

Water Scrubber 

Spray Tover 

Totel Hydrocarbon Emissions - Ton/Ton EDC 

Total Particulate 6. Aerosol Emissions - Ton/Ton EDC 

Total NO, Emissions - Ton/Ton EDC 

Total SO, Emissions - Ton/Ton EDC 

Total CO Emissions - Ton/Ton EDC 

422 

Continuous 

.000231 

.000022 

.000576 

.000157 

.000879 

.000795 

.000053 

.001879 

Yes 

In Vent 

Four times per veek for six veeke 

Chromatograph 

No 

Yes 

1 

95 

505 

Ambient 

75 

Yes 

Yes 

.001865 

0 

0 

0 

0 

702 

Continuous 

.000775 

.000023 

.000406 

.000812 

.000127 

.001476 

.001504 

.000282 

.002311 

Yes 

In Vent 

Four times per veek for six veeks 

Chromatograph 

No 

Yes 

1 

120 

.505 

Ambient 

150 

Yes 

Yes 

.002807 

0 

0 

0 

0 

[VK\v\n W$\ «P^V\«"W4 

CO 

en 
Code No. 

specify - Tona of EDC 

|veraga Production - Tons of EDC 

lesions tp Atmosphere 

Stream 

Flov - Lbs./Hr. 

Flov Chsracterlstlc - Continuous or Intermittent 

If Intermittent - Hrs./Yr. Flov 

Composition - Tons/Ton of EDC 

1.2 Dlchloroethane 

Vinyl Chloride 

Ethyl Shlorlde 

Methane 

Ethylene 

Oaygao 

Nitrogen 

Carbon Dioxide 

Carbon Monoxide 

Water 

Hydrogen Chloride 

Chlorine 

Analysis 

Sample Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacks 

Number 

Height - Feet 

Diameter - Inches 

Exit Gas Temperature 

Flov - SCFM 

•mission Control Device 

Condenser 

Water Scrubber 

Spray Tover 

Total Hydrocarbon Ealaslona - Ton/Ton EDC 

Total Particulat e 6. Aerosol Emissions - Ton/Ton EDC (4) 

Total NO, Ealaslona - Ton/Ton EDC 

Totsl SO, Emlaalona • Ton/Ton EDC 

Total CO Emissions - Ton/Ton EDC 

TABLE EDC-III 

NATIONAL EMISSIONS~TOVENTORY 

DICHLOROETHANE BY 

DIRECT CHLORINATION Page 3 of 3 

31-1 

238,000 

Not Specified (V) 

Scrubber Vent 

649 

Contlnuoua 

(2) 

,000156 

.000018 

.000014 

.001232 

.000262 

.002274 

.003983 

.002689 

.000193 

.000062 

.000020 

Yea 

In Vent 

Once a veex 

Chromatograph titration for Cl. 

Yes 

Yes (3) 

1 

148 

3 

90 

11,000 

Yes 

Yes 

Yes 

.000450 

.000082 

0 

0 

0 

Fugitive Emissions 

42 

Continuous 

.000706 

None 

Estimate 

No 

.000706 

0 

0 

0 

0 

(1) Approximate capacity based on total capacity for oxychlorlnatlon and direct chlorlnation unite and approximate oxychlorlnatlon capeclty. 

(2) Approxlaate composition based on percentage of combined oxychlorlnatlon and direct chlorlnation feed stream to the scrubber and assumption (1). 

(3) Unit used by oxychlorlnatlon process alao. 

(4) Classifies HC1 and Cl2 as aerosol because both are vapor at emitted conditions. 

pMW Q »*«-» •nM»W«"0.4 

fo 

Ico 

lot 
TABLE FS-III 

NATIONAL EMISSIONS INVENTORY 

FORMALDEHYDE VIA SILVER CATALYST PROCESS Page 1 of' 6 

PA Code Number 

ate on-atream 

apaclty - Tone of 377. HCHO/Yr. 

varage Production - Tone of 377. HCHO/Yr. 

ange in Production - 7. of Max. 

slsslona t o Atmosphere 

Strasa 

Flov • lba./hr. 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - hra/yr. 

Coaposltlon - Tona/Ton of 377. HCHO 

Formaldehyde 

Methanol 

Methyl Formate 

Dl-methyl Ether 

Methylal 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Methane 

Water 

Hydrogen 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Ivent Stacka 

Flov - SCFM per stack 

Number 

Height - Feet (elev. @ tip) 

Diameter - Inches 

Exit Gas Temperature - F° 

lEalaalon Control Devices 

Type - Water Scrubber 

Incinerator 

Catalog I. D. No. 

Total Hydrocarbon Emissions - Ton/Ton HCHO (377.) 

Total Particulate 4 Aerosol Emissions - Ton/Ton HCHO (377.) 

Total NO, - Ton/Ton HCHO (377.) 

Total SO, - Ton/Ton HCHO (37*4) 

Total CO - Ton/Ton HCHO (371) 

14-1 

154,000 

17 

Absorber Vent 

Not Specified 

Continuous 

+ 

+ 

None 

Never 

No 

Yes 

1 

43.8 

42 

Yes 

X 

FS-1 

Not Specified 

Converter Emergency Vent 

Not Specified 

Intermittent 

0.10 

+ 

+ 

+ 

None 

Never 

Not Specified 

>500o 

No 

14-3 

47,500 

47,500 

0 

Converter 

2620 

Start-up Vent 

Intermittent 

5 

.00011 

.00003 

None 

Never 

Not Specified 

No 

.00489 

0 

0 

0 

.00159 

Abaorber Vent 

Not Specified 

Contlnuoua 

.00114 

.00364 

+ 

+ 

.00159 

+ 

.01193 

.00755 

Yea 

718 

1 

6 '68) 

.67 

82° 

No 

3 
TABLE FS-III 

NATIONAL EMISSIONS INVENTORY 

EPA Code No. 

Date oo-etream 

Capacity - Tons of 377. HCHO/Yr. 

Average Production - Tons of 377. HCHO/Yr. 

Range In Production - 7. of Max. 

Emissions t o Atmosphere 

Streaa 

Flov - lba./hr. 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - hrs./yr. 

Coapoaltlon - Tone/Ton of 37*4 HCHO 

Formaldehyde 

Methanol 

Methyl Formate 

Dl-mathyl Ether 

Methylal 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Methane 

Water 

Hydrogen 

Seaple Tap Location 

Data or Frequency of Sampling 

Type of Analyala 

Odor Problem 

Vent Stacks 

Flov - SCFM per stsck 

Number 

Height • Feet (elev . @ tip) 

Diameter - Inches 

Exit Cas Temperature - F° 

Emission Control Devices 

Type - Water Scrubber 

Incinerator 

Catalog I. D. No. 

Total Hydrocarbon Emissions - Ton/Ton HCHO (377.) 

Total Particulat e 4 Aerosol Emissions - Ton/Ton HCHO (377.) 

Totel NO, - Ton/Ton HCHO (377.) 

Total SO, - Ton/Ton HCHO (3 77.) 

Total CO - Ton/Ton HCHO (377.) 

FORMALDEHYDE 

Absorbet 

Vent 

4040 

VIA SILV 

*1 

Continuous 

.00035 

.00111 

.00269 

.25569 

.00238 

.03354 

.00946 

.00523 

None 

Never 

Calc. 

No 

Yea 

1090 to 

1 

60 

.9 

104° to 

No 

\ 

1152 

140° 

rER CATALYST PROCESS 

Abaorber 

Vent 

1350 

14 

52 

52 

page 2 of 6 

-4 

500 

500 

0 

#2 

Continuous 

.00012 

.00037 

.00090 

.08523 

.00080 

.01115 

.00315 

.00174 

Never 

Calc. 

No 

Yea 

363 to 384 

1 

50 

.6 

104° to 

No 

140° 

.00348 

0 

0 

0 

.00556 

Abaorber 

Vent 

4040 

#3 

Contlnuoua 

.00035 

.00111 

.00269 

.25569 

.00238 

.03354 

.00946 

.00523 

None 

Never 

Calc. 

No 

Yea 

1090 to 

1 

65 

9 

104° to 

No 

1152 

140° 

; 

Stripper 

Overhead Vent 

54 

Continuous 

.00002 

.00005 

+ 

+ .00372 

+ 

.00038 

None 

Never 

Estimate 

No 

Yes 

5 to 20 

1 

65 

4 

78° to 110° 

No 
t 

r 

i 

TABLE FS-III 

NATIONAL EMISSIONS INVENTORY 

FORMALDEHYDE VIA SILVER CATALYST PROCESS Page 3 of 6 

A Code Number 

t e on-streem 

paclty - Tons of 377. HCHO 

erage Production - Tons of 3 77. HCHO 

nge In Production - 7. of Max. 

lsslons to Atmosphere 

Stream . 

Flov - lbs./hr . 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - hrs./y r 

Composition - Tons/Ton of 377. HCHO 

Formaldehyde 

Methanol 

Methyl Formate 

Dl-methyl Ether 

Methylal 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Methane 

Water 

Hydrogen 

Seaple Tap Location 

Data or Frequency of Sampling 

Type of Analysis 

Odor Problem 

it Stacks 

Flov - SCFM per atack 

Number 

Height - Feet (elev. (? tip) 

Dlaaater - Inches 

Exit Gas Temperature • F° 

salon Control Devices 

Type - Water Scrubber 

Incinerator 

Deaister 

Other 

Catalog I. D. No. 

Jl Hydrocarbon Emissions - Ton/Ton of 377 HCHO 

si Particulate 4 Aerosol Emissions - Ton/Ton of 377. HCHO 

Si NO Emisalons - Ton/Ton of 377 HCHO 

al SO* Emissions - Ton/Ton of 377 HCHO 

•1 CO Emissions - Ton/Ton of 37" HCHO 

14-7 

50,000 

0 

Absorber Vent 

7369 

Continuous 

.00035 

.00340 

.00230 

.53000 

.00100 

.03850 

.02750 

.01100 

None 

Never 

Calc'd. 

No 

Yes 

2000 

1 

98 

8 

95 

Yes 

FS-3 

.00605 

0 

0 

0 

.00100 

ex Design 

14-8 

75,000 

75,000 

0 

Absorber Vent 

11.600 

Continuous 

,00067 

.56129 

.00529 

.05920 

.00634 

.01263 

Stack 

1972 

GLC + Titration 

No 

Yea 

3200 

1 

100 

16 

54 

Yes 

+ 

FS-5 

.00100 

0 

0 

0 

.00529 

Jet Exhaust 

Continuous 

.00033 

None . 

Never 

Celc'd. 

No 

Yea 

1 

43 

1.5 

200 

Yes 

+ (condenser) 

FS-6 

14-9 

30,919 

30,919 

0 

Absorber Emerg. Vente 

Manual/Auto 

Intermittent 

Absorber Vent 

Not Specified 

Process 

Random 

Orsat + 7 

No 

Yea 

1/1 

30/20 

8/8 

500/50° 

No Yes 

FS-2 

Not Specified 
i > i 

TABLE FS-III 

NATIONAL EMISSION INVENTORY 

FORMALDEHYDE VIA SILVER CATALYST PROCESS Page 4 of 6 

EPA Code Number 

Capacity - Tons of 377. HCHO/Yr. 

Average Production - Tons of 377. HCHO/Yr. 

Range in Production - 7. of Max. 

Emissions t o Atmosphere 

Streaa 

Flov - lbs./hr. 

Flov Characteristic - Continuous or Intermittent 

If Intermittent - hrs./yr. 

Composition - Toas/ton of 377. HCHO 

Formaldehyde 

Methanol 

Methyl Formate 

Dl-methyl Ether 

Methylal 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Methane 

Water 

Hydrogen 

Seaple Tap Location 

Date or Frequency of Sampling 

Type of Ana ly el a 

Odor Probeam 

Vent Stacks 

Flov - SCFM per stack 

Number 

Height - Feet (elev. (° tip ) 

Diemeter - Inches 

Exit Cas Tempersture - F° 

Emission Control Devices 

Type - Water Scrubber 

Incinerator 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton HCHO (377.) 

Total Particulat e & Aerosol Emissions - Ton/Ton HCHO (377.) 

Total NO, - Ton/Ton HCHO (377.) 

Total SO,, - Ton/Ton HCHO (377.) 

Total CO - Ton/Ton HCHO (377.) 

14-10 

240.000 

Absorber Vent Incinerator 

Flue gas 

39,727 

Continuous 

TR 

TR 

.01005 

.47940 

.04269 

.18491 

TR 

Never 

GLC 

No 

Yes 

10,050 

1 

85 

60 

900 

Yes 

FS-7 

0 

0 

0 

0 

0 

14-6 

200,000 1 

Not Specified 

Yes 

+ Boiler 

FS-6 

Cannot Be Determined 
i i 

TABLE FS-III 

NATIONAL EMISSIONS~INVENTORY 

FORMALDEHYDE V U SILVER CATALYST PROCESS Page 5 of 6 

>A Code No. 

i t e on-a t ream 

ipaclt y - Tona o f 377. HCHO 

rerage Productio n - Tons o f 377. HCHO 

Inge i n Productio n - X o f Max. 

•1 salon s t o Atmospher e 

Strae a 

Flov - lba./hr. 

Flov Character1 atlc - Contlnuoua or Intermittent 

If Interalttent - hra./yr. 

Coapoaltlon - Tona/Ton of 377. HCHO 

Formaldehyde 

Methanol 

Msthyl Formate 

Dl-methyl Ether 

Methylel 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Methane 

Weter 

Hydrogen 

Seaple Tap Location 

Date or Frequency of Sempllng 

Type of Analysts 

Odor Problem 

nt Stecke 

Flov - SCFM per atack 

Number 

Height - Feet (elev. 0 tip) 

Diameter - Inches 

Exit Gaa Temperature - F° 

alealon Control Davlcea 

Type - Water Scrubber 

Incinerator 

Dealster 

Other 

Catalog I. D. No. 

otal Hydrocarbon Emissions - Ton/Ton of 3 77. HCHO 

otal Particulate & Aerosol Emissions - Ton/Ton of 377. HCHO 

ll NO, Emissions - Ton/Ton of 377 HCHO 

otal SO, Emissions - Ton/Ton of 377. HCHO 

otal CO Emissions - Ton/Ton of 377. HCHO 

14-12 

35,000 

35,000 

0 

Absorber Vent 

5,855 

Continuous 

.00041 

.00082 

.00276 

.00191 

.01390 

Dally 

Calc'd. 

Yes 

.460 

1 

73 

18 

80 

Yes 

+ 

FS-4 

.00123 

0 

0 

0 

.00276 

Jet Exhauat 

1000 

Continuous 

.18519 

None 

Never 

No 

Yes 

1 

22 

1 

200 

No 

14-18 

20,000 

20,000 

0 

0 

0 

0 

0 

00292 

Absorber Vent 

3360 

Continuous 

.00250 

.54828 

.00292 

.05856 

.00167 

.00989 

Top of Tover 

Bl-ennual 

Oraat + 7 

No 

Yea 

891 

1 

44 

6 

50 

No 

Abaorber 

7386 

14-20 

50.000 

50.000 

0 

Vent 

Continuous 

.00035 

.00326 

.00224 

.51016 

.00104 

.03688 

.02656 

.01040 

Random 

Calc'd. 

No 

Yea 

1 

95 

132 

95 

No 

.00825 

0 

0 

0 

.00104 

Distillation To m 

Overhead Vent 

30 

Continuous 

.00120 

.00120 

Never 

Not Specified 

No 

1 

95 

132 

95 

No 

F 

TJ 
TABLE FS-III 

NATIONAL EMISSIONS INVENTORY 

FORMALDEHYDE VIA SILVER CATALYST fMQCESS Page 6 of 6 

EPA Code No. 

Dat e on-atrea m 

Capacit y - Tons o f 377.. HCHO/Yr. 

Average Production - Tons o f 377 HCHO/Yr. 

Range i n Production - 7. o f Max. 

Emlaalona t o Atmosphere 

Stream 

Flo v - Lbe./Hr . 

Flo v Characteristi c - Continuous or Intermitten t 

If Intermitten t - Hre./Yr . 

Compoaltlon - Tons/Ton o f 377. HCHO 

Formaldehyde 

Methanol 

Methyl Formate 

Dl-aethyl Ether 

Methylal 

Oxygen 

Nitrogen 

Carbon Monoxide 

Carbon Dioxide 

Methane 

Water 

Hydrogen 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacka 

Flov - SCFM per stack 

Number 

Height - Feet (elev. 0 tip) 

Dlaaeter - inchea 

Exit Cas Temperature - F° 

Emission Control Devices 

Type - Water Scrubber 

Incinerator 

Catalog 1. D. No. 

Total Hydrocarbon Emissions - Ton/Ton HCHO (377) 

Total Particulate 4 Aerosol Emissions - Ton/Ton HCHO (377.) 

Total N0X - Ton/Ton HCHO (3 77.) 

Total SO, - Ton/Ton HCHO (3 77.) 

Total CO - Ton/Ton HCHO (377.) 

14-11 

427,500 

0 

Absorber Vent 

54,640 

Continuous 

<•00001 

.00076 

.00829 

.00120 

.396975 

.021010 

.092096 

.000126 

.016271 

Ground Level 

Daily 

Chromatograph 

No 

• Yes 

4200 3600 10,000 

1 I 1 

90 93 95 

10 12 14 

50 50 50 

No 

.01025 

.02101 

14-20 

50,000 

50,000 

0 

Absorber Vent 

7386 

Continuous 

.00035 

.0326 

.00224 

.51016 

.00104 

.03688 

.02656 

.01040 

Random 

Calc'd. 

No 

Yes 

1 

95 

132 

95 

No 

.00825 

0 

0 

0 

.00104 

Dlsti11st ion 

Tover Overhead Vent 

30 

Continuous 

00120 

00120 

Never 

Not Specified 

No 

1 

95 

132 

95 

No 

1 
mipany 

icatio n and/or EPA Coded Number 

i t e on-stream 

lameplate" capacit y in shor t tons 

: glycero l product per year 

)proxlmste averag e production rate , 

>ns glycero l per yea r 

asona l variatio n In production rate , 

rcent of nameplat e capacit y 

•uplifted flo v 

iscrlptlo n diagram stream designatio n 

lly l chlorid e 

ilorin e 

o-propyl alcoho l 

o-and n-propyl chloride s 

2 , 3 trlchloropropan e 

:rolel n 

3 dlchloropropen e 

jlchlorohydrl n 

cetone 

ite r 

Ir 

yrdrocarbon, non-substitute d 

for example , ethane , propene , butene ) 

'2 

3 dlchlorohydrl n 

TABLE G-III 

NATIONAL ATMlSPHERIC EMISSIONS INVENTORY 

FOR • 

CI.YCF.ROl. PIANTS USING EPICHI-OROHYDRIN AND/OR ALLYL CHLORIDE (NOTE 1) 

15-1 

47,500 

Note 3 

DtaL Tons per ton of glycerol cspaclty 

330 operating days/Cy assumed) 

otal, pounds per stream hour (note 2) 

otal. SCFM at 60° F and 14.7 PSIA 

empereture, °F 

emperature, C 

reesurc, PSIG 

ampllng location 

ate or frequency of sampling 

ype of Analysis 

dor preaence 

ent stacks 

Number 

Height, Feet 

Diameter, Inches 

Temperature, Stack exit, °F 

°C 

None 

B 

Incl'd in propyl chlorides 

0.02631 

0.008238 

Note 4 

0.03455 

414 

300 

250 

121 

Atm. 

Note 5 

Scrubber Vent 

One spot sample 

Mass spectro. 

C, Chlorides 

1 

60 

8 

250 

121 

D 

0.001665 

0.003269 

0.001539 

0.005151 

Note 6 

0.01162 

140 

2.10 0 

220 - 240 

104 - 116 

3 - 7 

Note 7 

1 

100 

8 

2 3 0 

110 

Page 1 of 4 

Incl' d in propyl chloride s 

0.0004283 

0 001791 

0.001681 

0 003622 

Note 8 

0.007522 

91 

54 

150 

66 

Atm. 

1 

100 

10 

150 

66 

0.00184 0 

0-0102 6 

Note 9 

0.012 1 

14 6 

400 

250 

12) 

Atm 

5 vacoam Jets/ 

accumulator vent* 

50/3 0 

4 / 2 

250/20 0 

121/9 3 

missio n Control Device s 

Type 

Catalog Identificatio n No.; see Table IV 

ota l emission s expresse d as tons/to n ulvcero l cspaclt y 

Hydrocarbon 

"articulate . Aeroso l 

Scrubber 

15-1-101 

0.0345 5 

None 

None 

None 

None 

Scrubber 

15-1-102 

0.01162 

None 

None 

None 

None 

Scrubber 

15-1-10 3 

0.007522 

None 

None 

None 

None 

0 0121 

None 

None 

None 

None 

Sei- |ISI.IH i -S lhruii( • -h lor explanatio n ul 
Company 

Location and/or EPA Coded Number 

Date on-8tream 

'Nameplate" capacit y in shor t tons 

of glycero l product per year 

Approximate average production rate . 

tons glycero l per year 

Seasonal variatio n In production rate , 

percent of nameplate capacit y 

Simplifie d flo v 

Descriptio n diagram stream designatio n 

Ally l chlorid e 

chlorin e 

Iso-propy l alcoho l 

Iso-and n-propyl chloride s 

1, 2 , 3 trlchloropropane 

Acrolei n 

2 , 3 dlchloropropeo e 

Eplchlorohydrln 

Acetone 

Water 

Ai r 

Hydrocarbon, non-substitute d 

(fo r example, ethane , propene , hutene ) 

CO, 

2 , 3 dlchlorohydrin 

Totel , tons per ton of glycero l capacit y 

(330 operating days/c y assumed) 

Total , pounda per stream hour (not e 2) 

Total , SCFN a t 60° F and 14. 7 PSIA 

Temperature, °F 

Temperature, °C 

Pressure , PSIG 

Sampling location 

Date or frequency of sampling 

Type of analysis 

Odor presenc e 

Vent stacks 

Number 

Height, Feet 

Diameter. Inches 

Temperature. Stack exit . °F 

"C 

TABLE C-ll l 

NATIONAL ATMOSPHERIC EMISSIONS INVENTORY 

FOR 

H.YCKROL PIANTS USING EPICHLOROHYDRIN AND/OR ALLYL CHLORIDE (NOTE 1) 

15-2 

Page 2 o f 4 

llypochlorinat ion vent 

0 0009467 

0.0000152 7 

0.00003627 

0.00316 5 

0.0498 2 

Note 10 

0 0540 

750 

167.4 

86 - 122 

30 - 50 

0 - 3 

None 

None 

None 

Chlorine 

1 

70 

8 

113 

45 

55.000 

Hydrollzer vent 

0.0001717 

0.00002015 

0.001425 

0.02286 

C D 

EPI. Lights dirt'n . vent EPI. finlshln g dlst" n vent 

0.000105 6 

0.0001894 

0.00004284 

0.000009720 

0.00001332 

Note 11 

0.02448 

340 

76.4 

69 - 104 

20 - 40 

0 - 1 

Not Given 

Infrequent 

Flame VPC 

None 

1 

42 

4 

104 

40 

Note 12 

0.00036 

5 

Amb. 

Amb. 

0 - 1 

None 

None 

None 

None 

1 

55 

2 

Amb. 

Amb. 

0 000002882 

0.0001355 

0.0001499 

Note 13 

0.000288 

4 

86 - 104 

30 - 40 

0 - 1 

None 

None 

None 

None 

1 

58 

2 

104 

40 

Clycerol reactor »ei 

Trace 

Trace 

Majority 

Trace 

Mote 14 

0.000205 

2 85 

1 

104 

40 

Atm 

Not Given 

Once 

VPC 

None 

1 

30 

10 

104 

40 

Emission Control Device s 

Type 

Catalog Identificatio n No. , se e Tabl e IV 

Total emleslois expressed «» tons/to n glycero l capacit y 

Hydrocarbon 

Particulate . Aerosol 

SO 

let Fume Scrubber 

Glycerol 15-2.101 

0 001015, lncl. chlorine 0.000195 

None None 

None None 

None None 

None 

See pa, es .-r. tor expiauac ion ol notes. 

None 

0 00036 

None 

None 

None 

None 

0 000138 

None 

None 

None 

None 

None 

None 

None 

None 

None 
1 1 a 1 1 1 1 1 

- - - -

Company 

Location and/or EPA Coded Number 

Date on-stream 

"Nameplate" capacity in short tons 

of glycerol product per year 

Approximate average production rate. 

tons glycerol per year 

Seasonal variation in production rate, 

percent of nameplate capacity 

Simplified flov 

Description diagram stream designation 

Allyl chloride 

chlorine 

Iso-propyl alcohol 

Tsn-and n-propyl chlorides 

1, 2, 3, trlchloropropane 

Acrolein 

2, 3 dlchloropropeae 

Fpichlorohydrln 

Acetone 

Water 

Air 

Hydrocarbon, non-substituted 

(for example, ethane, propene, butene) 

CO, 

2 , 3 dlchlorohydrln 

Total, tons per ton of glycerol capacity 

(330 operating days/cy assumed) 

total, pounds per stream hour (note 2) 

Total. SCFM at 60°F and 14.7 PSIA 

Temperature, °F 

Temperature, °C 

Pressure. PSIG 

Sampling Location 

Date or frequency of sampling 

Type of analysis 

Odor presence 

Vent stscks 

Number 

Height.. Feet 

Diameter, Inches 

Temperature, Stack exit, °F 

°C 

Emission Control Devices 

Type 

Catalog Identification No.. See Tahli- IV 

i • ; I . 1 . L .- 1 ... i . 1 1 

TABLE G-IU 

NATIONAL ATMOSPHERIC EMISSIONS INVENTORY 

FOR 

GLYCEROL PIANTS USING EPICHLOROHYDRIN AND/OR ALLYL CHLORIDE (NOTE 1) 

15-2 

55,000 

None 

F G 

Glycerol Evap. Vent Glycerol Dist'n. Vent 

1007. 1007. 

Note 15 Note 16 

0.0216 Unknovn 

300 "Very Small" 

105.3 

212 95 - 100 

100 35 - 38 

0 - 3 Atm. 

None None 

None None 

None None 

None None 

1 No Information 

49 

1 

104 

40 

Total emissions expressed as tuns/ton glycerol capacity 

Hydrocarbon 

• Particulate, aerosol 

M ) , 

S,,x 

CO 

See pagrs t;-i through <.-H lor i:x|> 1 iinat i on ol not 

None Hone 

None None 

None None 

.None None 

None None 

eS . 

I _ i i • m 

Page 3 of 4 1 

II 

Glycerol Light Dist'n Vent 

1007. 

Note 17 

0.03600 

500 

175.5 

212 

100 

5 

None 

None 

None 

None 

supplied 

None 

None 

None 

None 

None 

-* 

-

-
P.46 

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X i 

w

1 

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1 ft 

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0 0 

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X 

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ft 

71 

_t 

ft 

__ 

3) 

7) 

rr 

3 

3 

7) 

r^-t * 

0 

3 

a 

0 

30 

Q. 

ft 

3 

B * **) . 

n 

aa 

- ? 

3 

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Z 

0 

73 

ft 

ft 

_ ^ — j 

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3 
1 I 

TABLE HCN-lIl 

NATIONAL EMISSIONS INVENTORY 

HYDROGEN CYANIDE (ANDRUSSOH PROCESS) Page 1 of 4 

Plant EPA Code No. 

Capacit y - Tons o f HCN/Yr. 

Average Production - Tons HCN/Yr. 

Quarterl y Production Variation . 7. of Max. 

Emission s t o Atmosphere 

Stream 

Plant Train No. 

Flow - Lb./Hr . 

Flow Characteristic s - Continuous or Intermitten t 

If Intermitten t - Hrs./Yr . Flow 

Composition - Tons/Ton of Hydrogen Cyanide 

Methane 

Ammonia 

Nitroge n 

Oxygen 

Hydrogen 

Hydrogen Cyanide 

Carbon Dioxide 

Carbon Monoxide 

Water 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysts 

Odor Problem 

Vent Stacks 

Flow - SCFM/Stack 

Number 

Height - Feet 

Diameter - Inches 

Exit Caa Temperature, °F 

Emission Control Devices 

Type - Incinerator 

Flare 

Scrubber 

Other 

Catalo g I. D. Number 

Tota l Hydrocarbon Emission s - Ton/Ton Hydrogen Cyanide 

Tota l Particulate s 4 Aeroso l - Ton/Ton Hvdro^en Cyanide 

Tota l Nn. I"} - Ion/Ton Hydroien Cyanide 

Tota l SCV • - Ton/Ton liydrui i-n Cyanide 

Tota l CO (.missions Ion/Ton ilvclro.cn Cvani.UProduct Recovery & Purificatio n 

Sectio n Off-Gas 

(Ai r Heate r Fuel) 

1 

5,35 0 

Cont inuous 

.140 8 

.050 5 

.047 7 

None 

Never 

Calc'd. 

( 1 ) 1250 

1 

85 

54 

A ir Heater 

HN-1 

0 

0 

.0000 2 (8 ) 

D 

II 

16- 1 

83,00 0 

Start-Up and 

Emergency Feed 

Cas Venting 

I 

21,60 0 

Intermitten t 

16 

.5396 

.179 4 

.2468 

None 

Never 

Calc'd. 

5250 

1 

76.5 

24 

? 

Yes 

Start-U p & Emergency Reacto r Effluen t 

& Continuous Process Tank 4 

Off-Gas Vents 

1 

112,90 0 

Intermittent 

48 

(3) 

None 

Never 

Calc'd. 

Not Applicabl e 

27,40 0 

1 

76.5 

24 

HN-2 

0 

0 

.00 9 

0 

0 

( 3 ) (8 ) 

IIN-3 

0 

0 

.00 6 

0 

0 

Process Tsnk ; 

Process off-Ci 

Vents 

1 

95.20 0 

Continuous 

3.2022 

.4193 

.6290 

None 

Never 

Calc'd. 

22,550 

1 

76.5 

24 

'3) (8) 

Yes 

HN-3 

0 

0 

.0001

 (8 ) 

0 

0 

J> 

^1 
TABLE HCN-III 

NATIONAL EMISSIONS INVENTORY 

HYDROGEN CYANIDE (ANDRUSSOW PROCESS) 

Page 2 of 4 

Plant EPA Code No. 

Capacity - Tons of HCN/Yr. 

Average Production - Tons HCN/Yr. 

Quarterly Production Variation, 7 of Max. 

Emissions to Atmosphere 

S t ream 

Plant Train No. 

Flow - Lb./Hr. 

Flow Characteristics - Continuous or Intermittent 

If Intermittent - Hrs./Yr. Flow 

Composition - Tons/Ton of Hydrogen Cyanide 

Methane 

Ammonia 

Nitrogen 

Cvygen 

Hydrogen 

Hydrogen Cyanide 

Carbon Dioxide 

Carbon Monoxide 

Water 

Sample Tap Location 

Date or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stacks 

Flow - SCFM/Stack 

Number 

Height - Feet 

Diameter - Inches 

Exit Gas Temperature, °F 

Emission Control Devices 

Type - Incinerator 

Flare 

Scrubber 

Other 

Catalog I. D. Number 

Total Hydrocarbon Emissions - Ton/Ton Hydrogen Cyanide 

Total Particulate s i> Aerosol - Ton/Ton Hydrogen Cyanide 

Total' NO (8) - Ton/Ton Hydrogen Cyanide 

Total S0„ - Ton/Ton Hydrogen Cyanide 

Total CO F.mlsaions - Ton/Ton llvdrogen Cyanide 

Process 

Sample Pot 

Vents 

1 

296,000 

Continuous 

10.1493 

3.0660 

.0006 

Accessible 

Veekly 

GLC 

No 

65.000 

1 

150 

60 

Ambient 

None 

.0006 <4> 

0 

0 

0 

0 

16-1 

83.000 

0 

Product Recovery & Purlficstion 

Section Off-Gas 

(Air Heater Fuel) 

2 

137.000 

Continuous 

3.6042 

1.2927 

1.2210 

None 

Never 

Calc'd. 

16,000 (5~> 

2 

Air Heater 

Process 

Off-Gas 

Vent 

2 

17 800 

Continuous 

.5977 

.0006 

Yes 

HN-4 

0 (6) 

0 

.00004 

0 

0 

Process Tank i> 

Process Off-Gas 

Vents 

2 6. 3 

48.700 

Continuous 

1.6367 

.0783 

.1174 

None 

Never 

Calc'd. 

Not Applicable 

4.200 

1 

74 

24 

.2143 

.3215 

None 

Never 

Calc'd. 

Not Applicable 

11,500 

1 

110 

48 

HN-5 

0 

0 

.00005 

0 

0 
I -» 

TABLE HCn-III 

NATIONAL EMISSIONS INVENTORY 

HYDROGEN CYANIDE (ANDRUSSOW PROCESS) Page 3 of 4 

mt EPA Code No. 

laclt y - Tons o f HCN/Yr. 

irage Production - Tons HCN/Yr. 

irterl y Production Variation , 7. o f Max. 

sslon s t o Atmosphere 

Stream 

Plant Train No. 

Flow - Lb./Hr . 

Flow Characteristic s - Continuou s or Intermitten t 

If Intermitten t - Hrs./Yr . Flow 

Composition - Tons/Ton o f Hydrogen Cyanide 

Methane 

Ammonia 

Nitroge n 

Oxygen 

Hydrogen 

Hydrogen Cyanide 

Carbon Dioxid e 

Carbon Monoxide 

Water 

Sample Tap Locatio n 

Date or Frequency o f Sampling 

Type of Analysis 

Odor Problem 

mt Stacka . 

Flow - SCFM/Stack 

Number 

Height - Feet 

Diameter - Inche s 

Exit Cas Temperatur e - °F 

salo n Contro l Device s 

Type - Incinerato r 

Flar e 

Scrubbe r 

Other 

Catalo g I. D. Number 

ota l Hydrocarbon Emlsalons - Ton/Ton Hydrogen Cyanide 

ota l particulate s 4 Aeroso l - Ton/Ton Hydrogen Cyanide 

ota l NO (8 ) - TonATon Hydrogen Cyanide 

ota l S0„ - Ton/Ton Hydrogen Cyanide 

ota l CO Emissions - Ton/Ton Hydrogen Cyanide 

Start-U p or Emergency Feed-Gas Relie f 

4 Continuou s Process Tank & 

Process Off-Ga s Vents 

2 

66,300 

Intermitten t 

12 

+ 

+ 

None 

Never 

Calc'd . <6> 

Not Applicabl e 

15,90 0 

1 

110 

48 

Yes 

HN-5 

0 (<>) 

0 

. 0 2 

0 

0 

(3) (8) 

16- 1 

83.00 0 

Start-U p or Emergency Feed Gas Relie f 

& Continuous Process Tank 4 

Process Off-Gas 

3 

66.300 

Intermittent 

8 

+ 

+ 

None 

Never 

Calc'd. <6> 

Not Applicable 

15,900 

1 

110 

48 

HN-5 

0 (6) 

0 

.02 

0 

0 

O ) (8) 

Start-Up or Emergency Reactor Effluent 

Relief &, Continuous Process Tsnk (• 

Process Off-Gas Vent6 

2 

66.400 

Intermittent 

40 

None 

Never 

Calc'd. 

(6) 

Not Applicable 

16,400 

1 

110 

48 

HN-5 

0 

0 

.006 (3) (8) 

0 

0 
,_J 

TABLE HCN-III 

NATIONAL EMISSIONS XNVENTORY 

HYDROGEN CYANIDE (ANDRUSSOW PROCESS) Page 4 of 4 

ant EPA Code No. 

pecit y - Tons of HCN/Yr. 

erag e Production - Tons HCN/Yr. 

tarterl y Production Variation , 7 o f 

ilsslon s t o Atmosphere 

Stream 

Plan t Trai n No. 

Flow - Lb./Hr . 

Flow Characteristic s - Continuou s or intermitten t 

If Intermitten t - Hrs./Yr . Flo v 

Composition - Tons/Ton of Hydrogen Cyanide 

Methane 

Ammonia 

Nitroge n 

Oxygen 

Hydrogen 

Hydrogen Cyanide 

Carbon Dioxide 

Carbon Monoxide 

Water 

Sample Tap Locatio n 

Dat e or Frequency of Sampling 

Type of Analysis 

Odor Problem 

Vent Stack s 

Flow - SCFM/Stack 

Number 

Height - Feet 

Diamete r - inche s 

Exi t Gas Temperature - °F 

Emissio n Contro l Device s 

Type - Incinerato r 

Flar e 

Scrubber 

Other 

Catalo g I. D. Number 

Tota l Hydrocarbon Emission s - ion/To n Hydrogen Cyanide 

Tota l Particulate s 4 Aeroso l - Ton/Ton Hydrogai Cysnide 

Tota l N0X (8 ) - Ton/Ton Hydrogen Cyanide 

Tota l SOx - Ton/Ton Hydrogen Cyanide 

Tota l CO Emissions - Ton/Ton Hydrogen Cyanide 

16- 1 

83,00 0 

Start-U p or 

Emergency Reacto r Effluen t Relie f 

& Continuous Process Tank t. 

Process Off-Gas Vents 

3 

66,40 0 

Intermitten t 

24 

None 

Never 

Calc'd. 

(6) 

Not Applicable 

16,400 

1 

110 

48 

HN-5 

0 

0

006 <3> <8> 

0 

0 

Process 

Sample Pot 

Vents 

296,000 

Continuous 

10.1493 

3.0660 

.0006 

Accessible 

Weekly 

GLC 

No 

65.000 

1 

150 

60 

Ambient 

None 

0006 <*) 

0 

0 

0 

0 

Process 

Ssmple Pot 

Vents 

3 

18.200 

Continuous 

6246 

.1887 

.00004 

None 

Never 

Calc'd 

No 

4.000 

2 (alternating) 

120 

16 

Ambient 

None 

00004 (4) 

TJ 

bi 
i . -

.- iPlant EPA Code No. 

Capacit y Tons Isocyanates/Yr . 

Range o f Productio n - 7. of Max. 

Emission s t o Atmospher e 

Stream 

Flow - Lb./Hr. (SCFM) 

Flow Characteristic - Continuous or Intermittent 

If Intermittent - Hrs./Yr. 

Composition - Ton/Ton I so. 

Hydrocarbons 

Nitrogen (Air) 

CO 

CO2 

Steam 

C0C12-Phosgene 

Chlorinated Hydrocarbons 

HC1 

Aniline 

Isocyanates 

H2S, SO,, 

Particulate s 

Vent Stack s 

Number 

Height - Ft. 

Diamete r - Inche s 

Exi t Gas Temperatur e - K° 

SCFM/Stack 

Emissio n Contro l Device s 

TABLE TDI-III 

NATIONAL EMISSIONS INVENTORY 

ISOCYANATES 

Phosgene Decomposer Vent Gas 

Psge 1 of 5 

17-1 

100,00 0 

0 

Residue Gas Scrubber Vent 

(9000 ) 

Continuous 

0.01621 2 

0.00562 8 

0.00880 0 

0.00029 6 

0.00243 1 

No Data 

1 

725 

12 

212 

1000 

Scrubbe r 

1 

700 

6 

70 

? 

Scrubbe r 

Analysis 

Dat e o r Frequency o f Sampling 

Tap Locatio n 

Type of Analysis 

Odor Problem 

Summary of Ai r Pollutants 

Hydrocarbons - Ton/Ton I s o 

Aerosols - Ton/Ton Iso . 

N0X - Ton/Ton Iso . 

S0X - Ton/Ton Iso. 

CO - Ton/Ton Iso . 

Once pe r yea r 

In Stac k 

GC, IR 

N. C. N. C. 

0 002431 

0.000296 

0.00562 8 

cn 
L_. 

TABLE TDI-III 

NATIONAL KHlSSIONK INVENTORY 

Plant EPA Code No. 

Capacit y Tons Isocyanates/Yr . 

Range o f Production - 7. o f Max. 

Emissions t o Atmosphere 

Stream 

Flow - Lb./Hr . (SCFM) 

Flo v Characteristi c - Continuou s or Intermitten t 

If Intermitten t - Hrs./Yr . 

Composition - Ton/Ton Iso . 

Hydrocarbons 

Nitroge n (Air ) 

CO 

CC7 

Steam 

COCl, - Phosgene 

Chlorinated Hydrocarbons 

HC1 

Anilin e 

Iaocyanates 

HjS, S0X 

Particulate s 

vent Stack s 

Number 

Height - Ft. 

Dlaamter - Inche s 

Exit Cas Temperatur e - F° 

SCFM/Stack 

Emission Control Device s 

Analysis 

Date or Frequency of Sampling 

Tap Location 

Type of Analysis 

Odor Problem 

sry of Ai r Pollutants 

Hydrocarbons - Ton/Ton Iso . 

Aerosols - Ton/Ton Iso . 

NO, - Ton/Ton Iso . 

S0„ - Ton/Ton Iso . 

CO - Ton/Ton Iso. 

Phosgene Decomposer 

Vent Gas 

( 8 ) 

Continuous 

ISOCYANATES 

HC1 Absorber 

(27) 

Continuous 

17-2 

20.00 0 

±

8 

TDI Scrubb 

(28 ) 

Continuous 

0.000200 

0.011560 

0.006400 

0.029800 

1 

45 

3 

125 

8 

Scrubber 

Occasional 

In Stack 

GC 

No 

Pape 2 of 5 

Residue Cats 

Scrubber Vent 

(870) 

Continuous 

0.024234 0.843343 

1 

50 

4 

100 

27 

Absorber 

Never 

No 

1 

70 

6 

100 

28 

Scrubbe r 

Occasiona l 

In Stack 

GC 

No 

Never 

Est. 

No 

CO Furnace 

Purge Vent 

(180) 

Intermittent 

TR 

0.266760 

CO, Removal 

Regenerator Vent 

(414) 

Continuous 

TR 

1 

12 

8 

80 

870 

Scrubber 

1 

98 

8 

1 

0 

None 

Never 

Est. 

No 

0 236571 

TR 

1 

66 

4 

250 

309 

None 

Occasional 

Wet 

No 

TR 

TR 

cn 

ro 
t EPA Code No. 

cit y Tons Iaocyanates/Yr . 

e of Production - 7. o f Max. 

slons to Atmosphere 

Stream 

Flow - Lb./Hr. (SCFM) 

Flow Characteristic - Continuous or Intermittent 

If Intermittent - Hrs./Yr. 

Composition - Ton/Ton Iso. 

Hydrocarbons 

Nitrogen (Air) 

CO 

COj 

Steam 

COCI2 - Phosgene 

Chlorinated Hydrocarbons 

HC1 

Aniline 

Isocyanates 

HjS, SO 

particulates 

Vent Stacka 

Number 

Height - Ft. 

Diameter - Inches 

Exit Cas Temperature - F° 

SCFM/Stack 

Emission Control Devices 

Analysis 

Date or Frequency of Sampling 

Tap Locatio n 

Type of Analysis 

Odor Problem 

t r y of Ai r Pollutants 

Hydrocarbons "Ton/To — ''*•"•n' Iso . 

Aerosol a - Ton/Ton Iso . 

NO, - Ton/Ton Iso . 

TABLE TDI-III 

NATIONAL EMISSIONS INVENTORY 

ISOCYANATES 

17-3 

33,50 0 

0 

page 3 of 5 

Phosgene Decomposer 

Vent Gas 

1151 

Continuous 

0.00354 8 

0.01175 9 

0.10136 8 

TR 

No Data 

Scrubbe r 

No 

MDI Fume 

Scrubber Vent 

2080 

Continuous 

1.02088 

TR 

No Data 

Scrubber 

No 

Distillatio n 

Scrubbe r Vent 

223 

Continuous 

0.01165 7 

0.01084 6 

0.000023 

No Data 

11 •* 

n it 

11 n 

•1 •* 

Scrubbe r 

No 

0.00002 3 

TR 

0.01175 9 

Phosgene Decomposer 

Vent Gas 

(22) 

Continuous 

17-8 

15.500 

0 

TDI Scrubber Vent 

242 

Residue 

Incinerator Vent 

(8300) 

0.021292 

TR 

0.006654 

CO 

- Ton/Ton Iso . 

Ton/Ton lao . 

1 

55 

6 

150 

7 

Scrubber 

No 

0.05865 0 

1 

76 

4 

125 

7 

Scrubbe r 

No 

8.28672 

0.695137 

0.33849 5 

TR 

No Data 

Incinerato r 

No 

0.006654 

0.716429 
Plant EPA Code No. 

Capacit y Tons Isocyanates/Yr . 

Range of Production - 7. of Max. 

Emissions t o Atmosphere 

Stream 

Flow - Lb./Hr (SCFM) 

Flow Characteristi c - Continuous or Intermitten t 

If Intermitten t - Hrs./Yr . 

Composition - Ton/Ton Iso . 

Hydrocarbons 

Nitrogen (Air ) 

CO 

CO2 

Steam 

COCl, - Phosgene 

Chlorinated Hydrocarbons 

HC1 

Anilin e 

Iaocyanates 

H 2 S , SO 

particulate s 

Vent Stacks 

Number 

Height - Ft. 

Diameter - Inche s 

Exit Gas Temperature - F° 

SCFM/Stack 

Emission Control Device s 

Analysis 

Date or Frequency of Sampling 

Tap Location 

Type of Analysis 

Odor Problem 

• ry of Air Pol Intents 

Hydrocarbons - Ton/Ton Iso . 

Aerosols - Ton/Ton Iso . 

N0X - Ton/Ton Iso . 

SO - Ton/Ton Iso . 

CO - Tpn/Ton Iso. 

17-4 

13,000 

0 

Mil Recovery 

Unit Vent 

(50) 

Intermitten t 

675 est . 

0.00487 5 

0.000141 

0.000044 

0.000150 

TR 

I 

50 

2 

Ambient 

50 

None 

Never 

None 

Estimate 

Yes 

0.000291 

0.000044 

TABLE TDI-III 

NATIONAL EMISSIONS INVENTORY 

ISOCYANATES 

17- 9 

85,00 0 

0 

Reactor Vent 

100 

Continuous 

0.003517 

0.000085 

0.000636 

TR 

I 

Ground 

10 

110° 

None 

Never 

None 

Estimate 

Yes 

Amine Scrubber Vent 

1200 

Continuous 

0.406780 

0.144068 

TR 

1 

50 

6 

110° 

Scrubber 

Never 

None 

Estimat e 

Yes 

0.000291 

0.000044 

Reactor Vent 

(375 ) 

Continuous 

0.02144 2 

0.04951 3 

0 185965 

Pege 4 of 5 

17-6 

20,00 0 

+ 8, - 16 

Phosgene Destructio n 

Reactor Cond. Vent Unit Off-Gas 

(39.5 ) 

Continuous 

TR 

0.027875 

0.005263 

(1833 ) 

Continuous 

0 041326 

1 614425 

0 062183 

1 

175 

18 

2000 ° 

Flar e 

Never 

None 

Calcul a 

No 

ted 

1 

Ground 

3 ' x 5' 

130° 

None 

Never 

In Line 

Calculated 

Yes 

1 

130 

12" 

102° 

Scrubbe r 

Never 

None 

Calculate d 

No 

Tnci nerator 

Stack Cas 

(9000) 

Intermi trent 

TR 

8.507602 

0.115010 

0 024951 

TR 

Ground 

8' x 8' 

Pit Incinerstui 

Never 

None 

Calculated 

Yes 

0 041326 

I 
TABLE TDI-III 

NATIONAL EMISSIONSTKVENTOR Y 

ISOCYANATES Page 5 of 5 

lent EPA Code No. 

apacity Tons lsocyanates/vr. 

ange of Production - 'I. of Max. 

aiaaiona to Atmosphere 

Stream 

Flow - Lb./Hr. 'SCFM) 

Flow Characteristic - Continuous or Intermittent 

If Intermittent - Hrs./Yr. 

Composition - Ton/Ton Iso. 

Hydrocarbons 

Nitrogen (Air) 

CO 

Staam 

C0C12 - Phosgene 

Chlorinated Hydrocarbons 

HCl 

Aniline 

Isocyanatea 

HjS. SO 

particulates 

Vent Stacks 

Number 

Height - Ft. 

Diameter - Inchee 

Exit Gas Temperature - F° 

SCFM/Stack 

Emission Control Devices 

Analysis 

Date or Frequency of Sampling 

Tap Locatio n 

Type o f Analysis 

Odor Problem 

Summary of Ai r Pollutants 

Hydrocarbons - Ton/Ton Iso . 

Aerosols - Ton/Ton Iso . 

N0X - Ton/Ton iso . 

SO - Ton/Ton Iso . 

CO - Ton/Ton Iso . 

17-7 

52,50 0 

0 

Plant Scrubber Stack 

(10,000 ) 

Continuous 

4.10312 0 

0.01042 9 

0.000083 

TR 

Residue Vent Gas 

(200) 

Continuous 

0.002419 

0.047555 

0.000083 

2 

160 

30" 

Ambient 

5000 

Scrubber 

Continuous 

In Line 

Calc'd 

Yes 

for C0C12 

4 

60 

4" 

200° 

50 

None 

Never 

None 

Est. 

Yes 

0.000166 

0.010429 

Plant Flare 

1000 

Continuous 

(Calc'd.) 

0.12631 6 

0.003211 

0.00092 1 (Cl 2 ) 

0.00131 6 

1 

110 

1 

1600<> 

Scrubber 4 Incinereto r 

Never 

None 

Calc'd . 

No 

17-10 

30.000 

0 

TDI Reactor 

Emergency Vent 

600 

Intermittent 

8 

0.000002 

0.000070 

0.000006 

0.000001 

0.000001 

Residue Gss Vent 

250 

Conti nuous 

0.006184 

0.000493 

0 026316 

TR 

TR 

TR 

HCl Neul . 

Off-f.ss 

22.876 

Cont i nuous 

2.69394 7 

0.258816 

0 060132 

0 001210 

1 

60 

2" 

212° 

None 

1 

80 

2" 

120° 

None 

Never 

None 

Calc'd. 

No 

Never 

None 

Calc'd 

Yes 

0.00009 2 

3 

20 

10" 

100° 

Limestone 

Neut . 

Never 

None 

Calc'd 

Yes 

0.000002 

0 003448 

0 000092