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# Document

Number: 

# 28 ) ll-A- 2
Docket Number: 

# A-90-1 9

Printed 11/19/2008 11:19:51 AM 

## Sheet 28of 41 p. 1P. 2


# r 1



# J A-90-1 9 ll-A- 2



# SURVE Y REPOR [ ^ O

N ATMOSPHERIC EMISSIONS p i FRO

M TH E PETROCHEMICA

L J INDUSTR Y VOLUM E II

b y J

. W

. Pervier , R

. C

. Barley , D

. E

. Field , B

. M

. Friedman , R

. B

. Morris , W

. A

. Schwart z 

# J Houdr y Divisio n Ai r Product s an dChemicals , Inc

. P

. O

. Bo x 42 7 Marcu s Hook , Pennsylvani a1906 1
Contrac t No

. 68-02-025 5
EP A Projec t

Officer : Lesli e B

. Evan s Prepare dfo r 

# ENVIRONMENTAL PROTECTIO NAGENC Y Offic e o f Ai r an dWate r

Program s Offic e o f Ai r Qualit y Plannin g an dStandard s Researc hTriangl e Park , N

. C

. 2771 1

Apri l 197 4P. 3



## Thi s repor t

i s issue db y th e Environmenta l Protectio n Agenc y t o repor t technica l dat aof interes t t o alimite dnumbe r

o f readers

. Copie s ar e availabl e fre e of charg e t o Federa l employees , curren t contractor s an dgrantees , an dnonprofi t organization s a s supplie s permi t

- fro mth e Ai r

Pollutio n Technica l Informatio n Center , Environ

menta l Protectio n Agency , Researc hTriangl e Park , Nort hCarolin a27711 , o r fro m th e Nationa l Technica l Informatio n Servic e 528 5 Por t Roya l Road , Springfield , Virgini a22151

.

Thi s repor t

wa s furnishe dt o th e Environmenta l Protectio n Agenc y b y Ai r Product s an dChemicals , Inc. , Marcu s Hook , Pennsylvania , i n fulfillmen t o f Contrac t No

. 68-02-0255

. Th e content s o f thi s repor t

ar e reproduce dherei n a s receive d fro mAi r Product s an dChemicals , Inc

. Th e opinions , findings , an dconclusion s expresse dar e thos e o f th e autho r

an dno t necessaril y thos e of

th e Environmenta l Protectio n Agency

. Mentio n of compan y o r

produc t name s i s no t

t o b e considere d a s a n endorsemen t

b y th e Environmenta l Protectio n Agency

.

Publicatio n No

. EPA-450/3-73-005- b

»


# 1

### TABLE CD-II I NATIONA L EMISSION S INVENTOR Y CARBO N DISULFIDE FRO

M METHAN E AN D SULFU R Pag * 1 of 4 E.P.A . CODE.NO . CAPACITYTON S OF CARBO N DISULFID

E AVERAGE PRODUCTIO

N - TON S O

F CARBO N DISULFIDE EMISSION S T O ATMOSPHER E 8 - 1 Approx . 5,00 0 (1 ) ( 1 )
Fume s Fro m Sulfu rStorag e

Sulfu rPi tVen t No tSpecifie d No tSpecifie d Continuou s Continuou s 

### Flu e Ca s Fro

m Start-U p Flare No t Specifie

d Intermitten

t 5 0 Flar e Flu e Ca s Emergenc

y Reactor Ven

t 18,56 2 Intermitten

t .6 6

+ + Stea m Flow-Lbs./Yr . Flo w Characteristic s - Contlnuou a o r Intermitten t I f Intermittent - Hrs./Yr . Compositio

nLbs./Hr . o f Componen t Methane Ethane Propane Sulfur Carbony l Sulfide CarbonDisulfide Thfophen e HydrogenSulfide Sulfu r Dioxide Nitrogen Nitroge nDioxide s CarbonDioxide Oxygen Wate r Hydrocarbon s Analysi s Dat e o f Frequency

o f Samplin

g Typ e o f Analysi s Odo r Proble

m Ven t Stack s Flo w SCF M Per Stack Numbe r Heigh t (Elev . @ tip ) - Ft . Diamete r - Inchea Exi t Ca s Temperatur e - F Emissio nContro l Device s Type - Scrubbe r

- Incinerator - Flare Ye s Summar y o f Pollutant s Hydrocarbon s Lbs./Hr . + Other Sulfu r Compound s + Beside s S0 X 

### Particulate s + (3 ) NQJ J - Lbs./Hr . + 

### S0

_- Lbs./Hr . C O - Lbs./Hr . ( 1 ) Exac tcapacit y an d productio n figure s ar e confidentia l ( 2 ) Sinc e capacit y I s calsslfle d Informatio n i tI s no tpossibl e t o represen tcompositio n I n th e usua l manne ro f tona/ton s product . (3 ) Sublime d sulfur . ( 4 ) Averag e o f

3. 7 SCFM . Storag e

I M



### N o N o

N o +

Non e

No Ye s 1 3 0 3 25 0 N o 

## +

+ + + + Non e

Ye s Ye s 1 1 2 2 120 0 14,04 1 0 . 5 2,48 6 2,03 5 Non e
Ye s Ye s 6 0 - 200 0 1 15 0 8 300 0

Ye s

0 . 5 14,04 1 Non e

N o Ye s 0-1 2 1 3 0 2 Ambien t N o

xnnnftvQiinnA o

### I



### „ 1 1

_ 

## ,_ J 

## J
.

TABL E CD-II I NATIONAL EMISSION S INVENTOR Y CARBO N DISULFID E FRO M METHAN

E AN D SULFUR Pag e 2 o f 4 EP A COD E NO . CAPACITY TONS O

F CARBO

N DISULFID E AVERAG E PRODUCTIO

N - TONS O

F CARBO

N DISULFID E EMISSION S T

O ATMOSPHER

E 8- 3 119,00 0 119,00 0
St < Flo w Lba/Yr . Flo w Characteristic s - Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Compositio n Tons/To n o f Carbo n Disulfid e Particulate s Methan e Ethan e Propan e Sulfu r Carbony l Sulfid e Carbo n Disulfid e Thiophen e Hydroge nSulfid e Sulfu r Dioxide s Nitroge n Nitroge nDioxide s Carbo nMonoxid e Carbo nDioxid e Wate r Hydrocarbon s Analysi s Dat e o f Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Stack s Flow SCF M Pe r Stac k Numbe r Heigh t (Elev . 9 tip. ) - Ft . Diamete r - Inche s Exi t Ga s Temperature s - F ° Emissio nContro l Device s Typ e - Scrubbe r

Incinerato r - Flar e Summar y

o f Pollutant s Hydrocarbon s + Sulfu r Containin g Compound s beside s SO ^ - Tons/To nCarbo nDisulfid e Particulate s - Tons/To nCarbo nDisulfid e N0 X- Tons/To nCarbo nDisulfid e S O - Tons/To nCarbo nDisulfid e CO * - Tons/To nCarbo nDisulfid e (1 ) No t enoug hinformatio nt o calculat e - Incinerato r burn s clau s tai l (2 ) Convert s harmfu l liqui d wast e t o ai r pollutant s *'"" ' **-n

m Moul d wast e only . Boile r Fin e Ca s 24,60 5 Con t inuou s

.0000 4 Flu e Ga s - Liqui d

Wast e Incineratio n

( D Continuou s Flu e Ca s Emergenc

y Flare No t Specifie

d Intermittent 1 Storag e Los s 2 0 Continuous

Negligibl e .0001 4 Negligibl e .4634 2 .3791 8 .0000 9 Non e Calc'd . N o Ye s No t Specified 1 10 0 5 0 80 0 N o .0066 2 (3 )

+ (I ) (I )
Yea Once/Month Chramatagrap

h N o Ye a 1 15 0 7 8 100 0 Ye s 4

+

+

Non e

N o Ye s

Ye s (2 )

.0000 9 .0000 4 .0001 4 Negligibl e Negligibl e ga s also . 0 0 + .0066 2 0 N o
Ye s

0 0 + Negligibl e

Negligibl e
Non e

N o Ye s 7 0 35-5 0 3 6 Ambien t N o

Negligibl e 0 0 0 

# E

## i -
TABLE CD-II I NATIONAL EMISSION S INVENTOR Y CARBO N DISULFID E FRO

M METHAN E AN D SULFU

R Pag e 3 o f 4

EP A COD E NO . 8- 4 CAPACITY TON

S O F CARBO

N DISULFID E 1 7 5.UO O AVERAG E PRODUCTIO

N - TON

S OF CARBO

N DISULFID E 175,00 0 EMISSION S T

O ATMOSPHER

E 

### Strea m Flow-Lbs./Hr . Flo w Characteristic s - Continuou s o r Intermittent I f Intermittent - Hrs./Yr . Compositio

nTons/To

no f CarbonDisulfide Methan e Ethan e Propan e Sulfu r Carbonyl Sulfid

e Carbo nDisulfide Th+ophen

e Hydroge nSulfide Sulfu r Dioxide Nitroge n Nitroge nDioxide s Carbo nDioxid

e Wate r Analysi s Dat e of Frequenc

y o f Samplin

g Typ e o f Analysi s O r do r Proble

m Vent Stack s Flo w SCF M pe r Stack Number Heigh t (elev . 9 tip ) - Ft . Diameter - Inche s Exi t Ga s Temperatur e - F ° Emissio nContro l Device s Typ e - Scrubbe r Incinerator - Flare Summar y o f Pollutant s Hydrocarbon s + Compound s Containin g Sulfu r beside s SO , - Ions/To nCarbonDisulfid

e Particulate s - Ton6/To nCarbonDisulfid

e NO x- Tons/To

nCarbo nDisulfide Boiler Flu e Ga s 13,22 1 Continuou s

.0000 1 .2902 5 .2375 0 Reacto r Emergenc y Ven t Flar e 20,80 0 Intermittent 7 2

.0002 5

.0036 9



## so „ Tons/To n Carbo n Disulfid e C O - Tons/To n Carbo n Disulfid e No t Specifie

d

N o No t Specifie

d

N o

0 0 .0000 1 0 O 

### Ye s Onc e Chromatagrap

h Ye s Ye s 1 8 8 1 8 20 0 Ye s Ye s 0 0 0 .0002 5 0 Emergenc y Storag e Tan k Ven t 4 7 Intermitten

t 1 2

Negligibl e

Negligibl e

Non e

N o N o

N o
Negligibl e 0 0 0 0

b >TABL E CD-II I NATIONA

L EMISSION S INVENTOR Y CARBO N DISULFID E FRO

M METHAN E AN D SULFUR Pag e 4 o f 4 EP A COD E NO . 8- 5 CAPACIT

Y TON S O F CARBO

N DISULFID E 26,50 0 AVERAG E PRODUCTIO

N - TON

S O F CARBO

N DISULFID E 26,50 0 EMISSION S T

O ATMOSPHER

E
Strea m Flow-Lbs./Hr . Flo w Characteristic s - Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr . Compositio nTons/To no f Carbo nDisulfid e Methan e Ethan e Propan e Sulfu r Carbony l Sulfid e Carbo nDisulfid e Thlophen e Hydroge nSulfid e Sulfu r Dioxid e Nitroge n Nitroge nDioxide s Carbo nDioxid e Wate r Oxyge n Analysi s Dat e o f Frequenc y o f Samplin g Typ e o f Analysi s Ordo r Proble m Ven t Stack s Flo w SCF M pe r Stac k Numbe r Heigh t (elev . <

? tip ) - Ft . Diamete r - Inche s Exi t Ga s Temperatur e - F ° Emissio nContro l Device s Typ e - Scrubbe r Incinerato r - Flar e Summar y

o f Pollutant s Hydrocarbon s xSulfu r Contai nCompound s bealde a SO , - Tons/To nCarbo nDisulfid e Particulate s - Tons/To nCarbo nDisulfid e NO x- Tons/To nCarbo nDisulfid e Sulfu r Storag e Ven t 1. 7 Continuou s

.0002 8

Non e Calc'd . N o N o



### N o

.0002 8 

### S0

_ Tona/To nCarbo nDisulfid e C O - Tons/To nCarbo nDisulfid e 0 0 0 Flu e Ga s

Emergenc y

Flar e 33.75 8 Intermitten t 3 0 Storag e Ven t



### Continuou s Fugitiv e Emission s
Continuou s

.0047 8 .0126 0 .0000 5 .0012 2 .0068 5 Non e Calc'd . N o Ye s 6 78 0 1 11 0 1 2 180 0 Ye s
Ye s 0 0 0 .0047 8 0 Negligibl e

Negligibl e
Non e

N o N o



### N o

Negligibl e 0 0 0 0 

### ( ) (.00007 ) 

### ( )

Non e

N o N o

N o

.0000 7 0 0 0 0

# f BP A Cod * Numbe

r y • Ton s o f

Cyclohexanone/Yr . Productio n - Ton * o f Cyclohexanone/Yr . l y Productio n Variatio n - 1 o f Max . |on s t o Atmospher e

t v - Ib./hr . \m Characteristi c • Contlnuou a o r Intermitten t i f Intermitten t - hrs./yr . flo v Impositio

n- Tons/to

nof Cyclohexanone Cyclonesane Cyclohexanon e Cycloneaano l Hathan e Ethan e Ethylene Nitrogen Oxygen Hydrogen CarbonHonoalda Carbo o Dlxold * Wate r Mlac . Hydrocarbon s •ml aTap Locatio n j t e o rFrequenc y o f S kp ao f Analyal s Mo rProblem s •tack a lo v - SCIM/Stac k am * Un g

•sigh t- r*« t Hamste r- Inche s txl tGa s Tea

m - r ° talo n Contro l Device s Bap e - Incinerato r

Flar e
• Scrubbe r Othe r 

# ( Catalo g I.D . Numbe r a l Hydrocarbo n Ealesion s a l Particulat e &

> Aeroso l a l HO , a l SO , ta l C O TABL E CO-II L NATIONAL EMISSION S INVENTOR Y CYCLOHEXANON

E PRODUCTIO

N 5- 2 207,00 0 <

5> Pag e 1 o f 6

Ton/to n o f

Cyclohexanon e l.o v Preeaur e Off-ga s (Cyclohonan a Recover y Section ) 140 9 Contlnuou

a

.0142 6 .0001 6 .0055 6 .0009 6

Ever y 2- 3 *•" • GL C fc Oraa t N o Ye a 25 0 I 6 5 6 

### a s N o

.0092 6 Hig hPreesure 0ff-ga » Cyclohexan e RecoV«T , Sectio n 44,115 " Contlnuou a

.8019 5 .0047 0 .0037 0 .0019 3 .0074 0

BI-weekly CLC a Oraat N o Y* a 10,00 0 l 8 $ 6 

### a s (7 ) 5- 3 115,00 0 (8 )

Oxldlxer "Spen t Air " & Ven t 50,00 0 Contlnuou

a

1.5681 5

.0757 7

.0297 7
Infrequen

t GLC N o Yea / w 10,00 0 1 16 0 1 0 10 4 Yea

+ C0-1 1 .0337 9

.0763 7 Purificatio n Sectio n Ven t 300 0 Contlnuou

a

.0947 4

.0011 0

.0045 7
Infrequen

t CLC H o Ye a A/60 0 1 16 0 2 4 (? ) 10 4 Yea

+ C0-1 2Plan t- EM

I Cod * Numbe r Capacit y - Ton s o f Cyclohexanone/Yr . Averag e Productio n - Ton e o f Cyclohexanone/Yr . Quarterl y Productio n Varaltlo n - 7 . o f Max . Emission s t o Atmospher e Strea m TABL E CO-II I NATIONA

L EMISSION

S INVENTOR

Y CYCLOHEXANON

E PRODUCTIO

N 5- 4 31,00 0 (5 )

Oxidize r "Spen t Air " Ven t Pag e 2 o f 6

Deaorbe d Gase s fro

m Storag e & Purificatio n Flo w - lb./hr . Flo w Characteristi c - Continuou s o r Intermitten t i f Intermitten t - hre./yr - flow Compositio n- Tons/to no f Cyclohexanon e Cyclohaxan e Cyclohexanon e Cyclohexano l Methan e Ethan * Ethylen e Nltroga Oxyge n Hydroge n Carbo nMonoxid e Carbo nDioxid e Wate r Mica . Hydrocarbon * Sampl * Ta p Locatio n Dat a o r Fremusny c o f Samplin g Typ e o f Analysi s Odo r Problem * Ven t Stack s Plo w - SCFM/Stac k Heigh t - PM t Dla_mt* r - Inche s Exi t Ca s Temp . - F ° -missio nContro l Device s Typ * - Incinerato r

Flar e Scrubbe r Othe r Catalo g I.D . Numbe r Tota l Hydrocarbo nEmission s - Ton/to no f Cyclohexanon e Tota l Particulat e (. Aeroso l - " " " Tota l N O ' Tota l SO , " " " Tota l C O 12,95 8 Continuou s

.0235 5 <"50 0 (6 ) Continuou s

1.5239 4 .0261 3 .0556 0 .0257 4 .0127 4
Stac k Infrequentl y GL C
Ye s 287 0 1 1 9 8
N o ? + +

Ye s

Ye s

• K . 0 . Drum CO-1 0 ^.0362 9

. 0257 *

C Ofrt - EP A Cod e Numbe

r cit y - Ton e o f

Cyclohexanone/Yr . kag e Productio n - Ton s o f Cyclohexanone/Yr . Irterl y Productio n Variatio n - 7 . o f Max . laaion at o Atooapher e |S trea m TABL ECO-11 1 NATIONALEMISSION S INVENTOR Y CYCLOHEXANON

E PRODUCTIO N 9- 3 51,00 0 Pag e 3 o f 6

(4 ) Oxidlre r "Spen

t Air " Ven

t

Flo v - lb./hr . Flo v Characteristi c - Contlnuou a o r Intermittent I f Intermittent - hra./yr . flo v Coapoaltlo

n- Tona/tono f Cyclohexanone Cyclohexan

e Cyclohexanon

e Cyclohexano l Methane Ethan e Ethylen e Nitrogen Oxygen Hydrogen Carbo nMonxld

a Carbo nDioxid

e Wate r Miac . Hydrocarbon s Saapl a Tap Locatio

n Dat e o r frequenc

y of Saapllng Typ e of Analysi s Odo r Problem

s pan t Stack s Plo w - SCFM/Stac k Number Height - Fee t Diamete r - Inche s Bai t Ga s Temp . - F ° •missionContro l Device s Typ e - Incinerator Flare Scrubbe r Other Catalo g I.D . Nuaber iTota l Hydrocarbo

nEalaalon

a - Ton/to

no f Cyclohexanon

e Tota l Particulat e & Aeroso l Emit s lon g - Ton/to

no f Cyclohexanon

e llota l HO , " " Tota l SO , " Tota l C o " 31,56 0 Contlnuoua

.0191 3 .0011 2 .0002 9

+
.0152 7 ?

Irregular GL C Not Specified

Ye a

CO- 5 Afc B 0

(4 ) Oxidize r "Spen t Air " Ven t 12,40 0 Continuou s

.0420 8 .0049 2 .0004 3

+
CO- 6 Ao B Diatlll./Purf . Vast e Strea m Incinerato r Flu e Ca s Croun d Flar e Flu e Ga a
No t Specifie d Continuou s 175 0 Msx . Intermitten t

. UIDO X 7

Irregala r CL C
No t Specifie d

Yea + +

Burne r

Ye a Ye a 681 4 1 3 6 7 2 180 0 Ye a 

## + Stac k +

Neve r

No t Specifie d

Ye s 9- 1 12.00 0
Cyclohexano l No t Specifie d Dehydrosanatlo n Ven t

Continuou s

.0007 1 .0008 1 c. 00001 _.0000 1 .0000 2

.0227 7

CO- 7

. 0696 8

.0308 9 CO- 8 Irregula r GL C N o Ye a 84 6 1 1 2 8 70 ° Ye a

+
CO- 9C - EP

A Code Number :lt y - Tone o f Cyclohexanone/Yr . •g e Productio

n- Ton

a of Cyclohexanone/Yr . terl y Productio

nVariatio

n- I o f Max . alon e t o Atmospher e traa a
lo v - lb./hr . lo w Characteristi c - Continuou s o r Intermittent I f Intermitten t hra./yr . flo v lomposltlo

n- Tons/to no f Cyclohexanone Cycloheaao e Cyclohexanone Cyclohexano l Methan e Ethane Ethylene Nitrogen Oxyge n Hydrogen Carbo nMonoxid e CarbonDioxid e Wate r Misc . Hydrocarbon s Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ e o f Analysi s Ode rPro* , lea - i tStack a Plo w SCFM/Stac k Numbe r Heigh t- Fea t Diamete r- Inche s Exi tCa s Temp . F ° lesio n Contro l Device s Typ e - Incinerato r Flar e Scrubbe r Othe r Catalo g I.D . Number ta l Hydrocarbo n Emission s - Ton/to n o f cyclohexanon e 1 Particulat e e. Aeroso l - .ts l HO . 

## ,ta l SO J its l C O Emission s - Ton/to no f Cyclohexanone TABL E CO-II I NATIONA L EMISSION S INVENTOR Y CYCLOHEXANON

E PRODUCTIO

N 9- 7 75,00 0 Pag e 4 o f 6

Unspec i fie

d Oxidatlio

nSectio

n Ven t No t Specifie

d Continuou s
.0011 6

Non e Never Calc'd . N o Yea 1 0 1 4 0 1. 5 85 ° Non e Oxidatio n "Air " Ven

t 76,67 5 Continuou s
.0065 2 .0025 3 Purificatio n Sectio nStea m Je t Discharg e Cyclohexano l Dehydrogenstlo

n Ven t Flu e ('a s e x Incineratio n o f

VSrlou a Vast e Stream s

1.4276 2
.0144 5 6 9 Continuou s
.0005 1

197 0 Mas s No Ye s 600 0 1 ~ 1 5 1 6 70 ° Yea



### + Spe c

C0-IA6. B & CL

C Non

a Neve r Estimat e N o Yea 5 3 5 5 1. 5 15 0 N o

.0114 1

.0145 9 70 0 Contlnuou a

.0006 7 ^.0000 1 -.0000 1 ..0000 1 .0000 2 /wlOOO (1 ) Contlnuou a

.0108 8 .0001 4

196 9 Mas s Spe c N o Ye a 63 0 ' 1 4 0 3 3 4 Ye a

Condense r CO- 2 & CL

C Non e

Neve r N o Ye a <vl5.00 0 1 3 0 7 2 175 0 Ye a + •

CO- 3Plan t- EP

A Cod e Number Capacit y - Ton ao f

Cyclohexanone/Y r Averag e Productio n - Ton ao f Cyclohexanone/Yr . Quarterl y Productio n Variatio n - 7 . o f Max. Ealaalon e t o Atmoapher e Strea m

Flo v - lb./hr . Flo v Characterlatl c - Contlnuou a o r Intermitten t I f Intermitten t hra./yr . flo v Compositio

n- Tons/tono f Cyclohexanon e Cyclohexen

e Cyclohexenone Cyclohexano l Methane Ethan e Ethylen e Nitrogen Oxygen Hydroge n Carbo nMonoxide Carbo nDioxide Wate r Misc . Hydrocarbona Sampl e Ta

p Locatio

n Dat e o r Frequenc

y o f Samplin

g Type o f Analysi s Odo r Problem

s Ven t Stsck s Flo v SCFM/Stac k Number Heigh t - Feet Diameter - Inche a Esl t Ca a Temp . F ° Emissio nContro l Device s Type - Incinerator Flare Scrubbe r Other Catalog I.D . Numbe r Tota l Hydrocarbo

nEmission s - Ton/to n o f cyclohexanon e Tota l Particulst e & Aeroso l - " " Tots l HO , Tots l SO , Tots l C O TABL E CO-II I NATIONA L EMISSION S INVENTOR Y CYCLOHEXANON

E PRODUCTIO

N 9- 4 75,00 0 Pag e 5 o f 6

Oxidatio n "Air " Ven t 38.83 7 Continuou s
.0038 3

1.8883 0 .0064 9 .1010 6 .0406 9 .0254 3

Cel c No Ye s - 375 0 

### i e 6 0 6 " 70 ° No d
. 2458 0 1<5 > 19 5

Ye a Purificatio n Sectio n Strea m Je tDischarg e No tSpecifie d

.0150 0 Non e Estimat e Non e

Non e (2 )

CO- 4 .0442 6

. 1010 6

T J

## TABL E CO-II I EXPLANATIONO F NOTE S NATIONAL EMISSION S INVENTORY CYCLOHEXANONE PRODUCTIO N Pag e 6 o f 6 (1 ) Prio r t o combustion
. (2 ) Aportio n o f thi s streamvent s through a n unli t flare
. (3 ) N o entry . (4 ) Th e quantitie s liste d belo war e believe d t o b e th e su mo f th e emission s fro mth e tw o identica l stream s tha t mak e up thi s entry . (5 ) Capacit ycalculate d b yHoudrybase d o n state d cyclohexan e feed
. Basi s - .767 3 to n cyclohexanon e pe r to n o f cyclohexan e feed ; rati o fromquestion

nair e data
. (6 ) Flo wprio r t o combustio n i n off-sit e flare
. (7 ) Operato r state s flo wi s fromscrubbe r bu t give s n o details
. (8 ) Capacit ycalculate d b yHoudry , base d o n pro-ratio n fromEP ACod e No . 5-2
.n tEP

A Cod e No . duc t acity . Ton s o f

DM T o r(Enuivalen tDMTWYr . sslon at o Atmospher e Strea m
Flo v - Lbe./Hr . Flo v - Contlnuou

a o r Intermittent i f Intermittent - Hra./Yr . Flo v Compositio

n- Ton/TonDMT o

r 'Enuivalen

t DMT ) TP A Aceti c Aci d Wate r Carbo nMonoxid e Carbo nDioxide Oxygen Nitroge n Methyl Acetat e Xylen e Propy l Acetat e Acetaldehyd e Dimethy l Ethe r Methy l Alcoho l Sulfu rDioxid e DM T Meta l Oxlde a Bensol cAci d P-Tolui c Aci d P-Carboxy l Benaaldehyd e Hydroge n Mlac . Ligh tHydrocarbon s - a s Methan e Ven t Stack a Numbe r Heigh t- Fee t Diamete r- Inche s Exi tCa s Temp . - F ° SCFM/Stac k Typ e o f

Emissio n Contro l Devic e Employe d Contro l Devic e I . D . No . Analysi s Dat e o rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f

Analysi s Odo rProble m •r y o f Ai rPollutant s - T/ T o f DM T o rfKquivalent ) Hydrocarbon s Particulate s o rAerosol s NO , SO , C O TABL E DT-lI l NATIONA

L EMISSIO N INVENTOR Y DM T AN D TP A PRODUCTIO

N VI A VARIOUS PROCESSE S 10- 1 (A ) TP A (290,000 )
Oxidize r Ven

t 256.00 0 Continuou s

(.01886 ) (.11895 ) (.25946 ) (3.44695 ) (.00308 ) (.00077 ) (.00077 )

(.00039 )

( . 00980 )

(.00036 )
( .02017 ) Pag e 1 o f 7

Filter , Dryer . Sil o Ven

t 18,47 0 Continuou s
(.00036 ) (.00348 ) (.00227 ) (.00131 ) (.00852 ) (.02167 ) (.24011 ) (.00005 )

Ye s 1 8 3 1 t o 6 4 3 to 1 0

Non e
Monthly A t Ven t CLC N o Distillatio n Sectio nVen t

(.00028 )

(.00259 ) (.00068 ) ( . 00003 ) ( 00066 )

Ye s 4 2 1 t o 4 0 2 t o 4

Non e
Monthl y A t Ven t CL C N o

A ) Planta 10- 1 an

d 10- 6 ar e par

t o f tli o sam e overal l facility .

# - f v «

J



## • ,- *

len t EP A Cod e No . Toduc t apeclty , Ton

a o f DM

T or (Equivalent)*/Yr . mission s t o Atmospher e Strea m

Flo v - Lbs./Hr

. Flo v - Contlnuou ao rIntermitten t i f Intermitten t- Hrs./Yr

. Flo v Compositio n - Ton/To n DM T o r(Equivalen t

DMT ) TPA Aceti cAci d Wate r Carbo n Monoxid e Carbo n Dioxid e Oxyge n Nitroge n Methy l Acetat e Xylen e Propy l Acetat e Acetaldehyd e Dimethy l Ethe r Methy l Alcoho l Sulfu rDioxid e DM T Nata l Oxide s sensol cAci d Par aTolul cAci d Par aCarboxy l Benxaldehyd e Hydroge n Misc . Ligh tHydrocarbon s - a s Methan e Ven tStack s Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temp . - F ° Flo v - SCFM/Stac k Emiaslo n Contro l Devic e Typ e I . D . Numbe

r Analysi s Dat e o r Frequenc

y of Sempllng Sampl e Ta

p Locatio

n Type of Analyat a Odo r Proble

m Summar y of Ai r Pollutant s T/ T of DMT o r (Equivalen

t DMT ) Hydrocarbon s Particulate s & Aerosol s N O , 

### •° x C O Oxidize r Ven t Unknov n NATIONALEMISSION S INVENTOR Y DM T AN D TP A PRODUCTION VI A VARIOU S PROCESSE S

10- 2 TP A (84.240 ) Condensatio n Sectio n 97,03 5 Continuou s
(.00107 ) (.00024 ) (4.00158 ) (.00482 ) (00061 )

Ye s 1 6 4 2 4 21 2 Ye s Scrubbe r DT-1 2 (.02485 ) (.00021 ) (.00003 ) (.00146 ) (.01182 ) Ye s 1 12 0 7 2 31 0 73,00 0 Ye a Ba g Filte r DT-1 3 "A aRequired " ( 3 Platfor m EPA Metho dNo

. 5 & Desig n Calc'd . N o (07757 ) (.00223 ) 0 0 (.01007 ) Pag e 2 o f 7

Condensatio n Sectio n 105,59 7 Continuou s
(.00116 ) (.00026 ) (4.35466 ) ( 00525 ) (.00066 )

(.02704 ) (.00023 ) (.00003 ) (.00159 ) (.01286 ) Ye s 1 12 0 7 2 31 0 Ye s Be g Filte r DT-1 4 "A s Required " ( 3 platfor m EP A Metho dNo

. N o Incinerato r Flu e Ga s Unknov n

Ye s 1 5 0 5 2 55 0 N o

Non e 5 & Desig n Calc'd .i 

# r 3 1 

# r y 

# r" 7

TABL E DT-II I

Plsn tEP

A Cod e No . Produc t Capacity , Ton ao f

DM T o r(Equivalen tDMT)*/Yr . Emission s t o Atmospher e Stree a

Flo v - Lbs./Hr . Flo v - Contlnuoua o

r Intermittent I f Intermitten t - Hrs./Yr . Flo v Compositio

n- Ton/TonDM

T o r (Equivalent DMT ) TP A Aceti c Aci d Wate r Carbo nMonoxide Carbo nDioxide Oxyge n Nitroge n Methy l Acetet e Xylen e Propy l Acetat a Aceteldehyd e Dimethy l Ethe r Methy l Alcoho l Sulfu rDioxid e DM T Nata l Oxlde a Bensol cAci d P-Tolul cAci d P-Carboxy l Bensaldehyd e Hydroge n Misc . Light Hydrocarbon s - a s Methane Ven t Stacka Numbe r Height - Fee t Diamete r - Inche s Exi t Ca s Tamp . - F ° SCFM/Stac k Type o f EaleelonContro l Devic e Employe d Contro l Devic e I . D . No . Analysi s Dat e or Frequency

o f Samplin

g Sampl e Ta p Location Type o f Analysi s Odor Proble

m r y o f Ai r Pollutant s - T/ T o f DM T o r (Equivalent ) Hydrocarbon

a Particulate s or Aerosol s NO x SO , C O Oxidize r Ven t 229,00 0 Continuou s NATIONAL EMISSION S INVENTOR Y DM T AN D TP A PRODUCTIO

N VI A VARIOU S PROCESSE S

Incinerato r Flu e Ga s 69,85 0 Continuou s 10- 4 DM T 300,00 0 Purificatio n Sectio n Scrubbe rVen t 5,03 4 Continuou s Purificatio n Emergenc y Ven t Unknov n Intermitten t Pag e 3 o f 7

Reacto rSectio n Ejecto rDischarg e 94 2 Continuou s Purificatio n Ven t 8 Continuou s Othe r

Emission s 5,72 0 Unknov n

.0093 8 1 5 Sec./Inciden t

.0139 5 .0309 6 

## ) )3.1485 6 

## ) .2923 0 .0022 3 

## ) ).6798 5 

## ) .0002 2 .0006 8 

## ) ).0691 9 

## )
TR

.0003 1 .0025 5

Ye s 2 7 10 0 3 0 8 5 25.00 0 Absorbe r DT- 4 Weekl y Stac kBas e CL C N o Ye s

1 10 0 6 0 4 5 0 1,80 0 Incinerato r DT- 5 Weekl y @ WH B Variou s N o Ye s

1 9 0 1 2 5 0 6 0 0 Scrubbe r DT- 6 Semi-Weekl y Scrubbe rOutle t CL C & Ca s Par ti tlone r N o .0904 7 + .0025 5 .0338 9 +

+

No t Specifie

d

Non e Non e

N o .0003 1

.0000 2 

## ) ).0120 9 

## ) 0007 5

Ye s 2 ? 6 0 6 8 5 10 0 Scrubbe r DT- 7 Non e A t Scrubbe r Calc'd . N o .0000 1
).0000 6 

## ) .0000 3

.080 0

No t Specifie

d N o

Non e Non

e Non e i Non

e

Calc' d N o Calc' d

X I

### ' ' (



# I at EP A Cod e No . duc t iclty , Ton ao f

DM T o r< Eaulvelent)*/Yr. [aslon s t o Atmospher e Strea a

Flo v - Lbs./Hr . Flo v - Contlnuou a o r Intermitten t I f Intermitten t - Hra./Yr . Flo v Compositio n- Ton/To nDM T o r (Equivalen t DMT ) TP A Aceti c Aci d Wate r Carbo nMonoxid e Carbo nDioxid e Oxygo n Nitroge n Methy l Acatet e Xylen e Propy l Acetat e Aceteldahyd e Dlaathy l Ethe r Methy l Alcoho l Sulfu rDioxid e DM T Meta l Oxide s Benzoi cAci d Par e Tolul cAci d Par e Carboxy l Bensaldehyd e Hydroge n Misc . Ligh tHydrocarbon s - a aMethan e Ven tSteck a Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temp . - F ° Flo v - SCFM/Stac k Emissio n Contro l Devic e Typ e I . D . Numbe r Analysi s Dst e o rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f

Analysi s Odo rProble m Sum—tr y o f

Ai rPollutant s T/ T o f DM T o r(Equivalen tDMT ) Hydrocarbon s particulate s U

Aerosol s NO , S O , C O TABL E DT-U l NATIONA

L EMISSION S INVENTOR Y DM T AN D TP A PRODUCTIO

N VI A VARIOUS PROCESSES

10- 5 TP A (241,000 ) Oxidize r Ven t 5,72 0 Continuou s

(.00163 ) + (.01591 ) 

### ) )(2.43726 ) 

## ) (.00513 ) Surg e Ten k Ven t 1,23 8 Continuou s
(.00024 ) (.00229 ) 

### ) )(.01823 ) 

### ) (.00020 ) Psg e 4 o f 7

Storag e Sil o Ven t 11,42 8 Intermitten t 8 2 ( < .00001 )

«.0000l ) 

### ) ) ( .19346 ) 

### ) Residu e Incinereto r Flu e Ga s 74,50 8 Intermitten t 7.34 4

(1.13502 )

(.00012 )

Ye s 1 7 7 1 8 11 6 32,15 0 Ye s Hig h Pressur e Absorbe r DT- 8 Occeslona l Accessibl e CL C N o Ye s 1 6 5 1 8 12 0 3 0 0 Ye s Scrubbe r DT- 9 Occeslona l Accessibl e GLC N o Ye s 1 14 0 1 2 27 5 1,00 0 Ye s Ba g Filte r DT-1 0 Neve r Accessibl e Calc' d N o (.00855 ) (.00012 ) 0 0 (01591 ) Ye s 1 12 5 4 2 60 0 16.55 0 Ye s Precipitato r DT-l l Neve r Calc'd . N o Solven t D e hydrato r 15.65 0 Continuou s
(.00025 ) (26357 )

(.00110 )

N o

No

Once/Shif t Accessibl e Titratio n N o

# i r

Plant BP

A Code No . Produc t Capacity , Ton s o f DM T o r (Equivalent DMT)*/Yr . Emission s t o Atmospher e Stream .
Flo v - Lbs./Hr . Flo v - Continuou s o

r Intermitten t i f Intermittent - Hra./Yr . Flo y Composition- Ton/To nDM T or (Equivalent DMT ) TP A Aceti c Aci d Wate r CarbonMonoxid

e CarbonDioxid

e Oxygen Nitroge n Methy l Acetet e Xylen e Propy l Acetat e Acetaldehyd e Dlaathy l Ethe r Methy l Alcoho l Sulfu rDioxid e DM T Meta l Oxlda a Bensol c Aci d P-Tolui * Aci d P-Carboxy l Bensaldehyd e Hydroge n Misc . Ligh tHydrocarbon s - a s Methan e Ven tStack s Numbe r Heigh t- Fee t Diamete r- Inche s Exi tCa s Teap . - F ° SCFM/Stac k Typ e o f

Emissio n Contro l Devic e Employe d Contro l Devic e I . D . No . Analysi s Dat ao rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f

Analysi s Odo rProble m Summar y o f

Ai rPollutant s - T/ T o f DM T o r(Equivalent ) Hydrocarbon s Particulate s o rAerosol s NO , SO , CO (A ) Plant s 10- 1 an d 10- 6 are par

t o f tli e sam e overal l facility . (B ) Thl a strea

m neve r sampled , bu

t estimate

d to b e essentially

th e TABL EDT-11 1

NATIONALEMISSION S INVENTOR Y DM T AN D TP A PRODUCTION VI A VARIOU S PROCESSE S 10- 6 (A ) DM T 290,00 0

Reactor Ven

t 2 Continuou s

<.0000 1

<.0000 1 .0000 2 .0000 1

Ye a 1 5 0 2 70 ° Non e

On e Sessio

n A t Ven t Unknov n N o Methano l Recover y Ven t (B )

~ 2 Continuou s

.<.0000 l

^x< . 0000 1 ^/ . 0000 2 os/ . 0000 1

Ye s 1 10 0 3 70 ° Non e

Neve r Estimat e N o Pag e 5 o f 7

Metheno l Recover

y Ven t 41 5 Continuou s

.0010 7

.0005 5 .0043 3 .0003 1

Ye s I 5 0 4 70 ° Non e

On e Sessio

n A t Ven t Unknov n N o .0065 1

.0007 7 Crude Produc t

"Hold-Up " Ven

t 3 Continuou s

0000 5

Ye s 1 3 0 3 70 ° Condense r DT- 1 Neve r Estimat e N o

lam e a s th e o npreceedln

Ki t i nth e tabulatio

nfl0- 6 react o

r vent) .len tEP

A Cod e No . •redac t -peclty , Ton s o f DM T o r(Equivalen tDMT)*/Yr . Emission s t o Atmospher e Strea m . |lo v - Lbs./Hr . Flo v < • Continuou s o

r Intermitten t i f Intermitten t - Hra./Yr . Flo v Compositio

n - Ton/To n DM

T o r (Equivalen

t DMT ) TP A Aceti c Aci d Wate r Carbo n Monoxid e Carbo n Dioxid e Oxyge n Nitrogen Methy l Acetat e Xylen e Propy l Acetet e Acetaldehyd e Dimethy l Ethe r Methy l Alcoho l Sulfu rDioxid e DM T Meta l Oxlde a Benzoi cAd d P-Tolul c Aci d P-Cerboxy l Bensaldehyd e Hydroge n Mac . Ligh tHydrocarbon s - a s Methan e Ven tSteck a Numbe r

- Heigh t- Fee t Diamete r- Inche a Exi tCa s Temp . - F ° SCFM/Stac k Typ e o f

Emlaalo n Contro l Devic e Employe d Cootro l Devic e I . D . No . Analysi s Dat e o rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f

Analyal a Odo rProble a Summar y o f

Ai rFollutant a- T/ T o f DM T o r(Equivalent ) Hydrocarbon e partlculate ao rAeroaol s NO , SO , CO TABL E DT-II I NATIONA

L EMISSION S INVENTOR Y DM T AN D TP A PRODUCTION
' VI A VARIOUS PROCESSE S 10- 6 (A ) DM T 290,00 0
Crud e Produc t "Hold-Up " Ven

t

Continuou s

.0000 5

Ye s 1 3 0 3 70 ° 1 0 Scrubber DT- 2
Neve r Estimat e N o Sludg e Recover

y Ven t

Continuou s

.0000 5

Ye s 1 3 0 3 70 ° 1 0 Condense r DT- 3
Neve r Estimat e N o

SE E OTHE

R SHEE T Pag e 6 o f 7

Methano l Stg . & Slurr y Prep . Ven t 10.40 0 Continuou s

.0007 7 .0060 2 .0087 5

. 1408 6

N o

N o

Dall y Oraa t No Sludg e Recover y Ven t Unknov n Continuou s

Ye s 1 1 0 1 0 70 °
Ye s Scrubbe r DT-1 7 Neve r
Non e N o

(A ) Plant a 10- 1 an d 10- 6 ar e par

t of th

e sam e overal l facility .Plan tEPA Cod e No . Produc t Capacity , Ton s o f DM T o r(Equivalent)*/Yr . Emission s t o Atmospher e Strae a

Flo v - Lbs./Hr . Flo v - Continuou s o

r Intermitten t i f Intermittent - Hrs./Yr . Flo v Compositio

n- Ton/TonDM

T o r (Equivalen t DMT ) TP A Aceti c Aci d Wete r Carbo nMonoxide Carbo nDioxid

e Oxyge n Nitroge n Methy l Acetet e Xylen e Propy l Acetst e Aceteldehyd e Dimethy l B t h a r Methy l Alcoho l Sulfu rDioxid e DM T Meta l O x Id aa Benzoi cAci d Par aTolul cAci d Par s carboxy l Bensaldehyd e Hydroge n Misc . Ligh

t Hydrocarbon s - a s Methane Vent Stack

a Nuaber Heigh t - Feet Dlaaeter - Inche s Exi t Caa Teap . - F ° Flo v - SCFM/Stac k Ealaslo nContro l Devic e Typ e I . D . Nuafce r Analysi s Dat e o rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f

Analysi s Odo rProble m tr y o f Ai rPollutant s T/ T o f DM T o r(Equivalen tDMT ) Hydrocarbon s Particulate s 4 Aerosol s NO , S O , C O TABL E DT-11 1 NATIONAL EMISSION S INVENTOR Y DM T AN D TP A PRODUCTIO

N VI A VARIOUS PROCESSES

10- 7 DM T 180.00 0

Ven t 52,59 0 Continuou s

.0010 0 .0016 3 .0338 8 .1477 1 .8607 1

NO , .0002 1 Purificatio n Sectio n Ven t Unknov n

NH 3 - .0001 7 N 2 0 - .0503 3 Ye a 1 12 0 2 4 35 1 10,50 0 Yea Catalyti c Incinerato r DT-1 5 Weekl y (NO, ) Accessibl e Colorlmetrl c N o Ye s 1 8 0 8 "

Ye s Flar e DT-1 6 Never Non e N o .0022 5

.0001 7 .0002 1 Pag e 7 o f 7

Emergenc

y Ven t Unknov n Intermitten

t Unknov n Ai r Oxidizer

Ven t 88.50 0 Continuou s

Ye s 2 10 0 2 4

N o

Neve r

N o .0044 6 .0147 1 .0693 8 .0453 8 I 687 5 0022 5

Ye s 2 5 0 1 0 5 0 9.00 0 N o

Semi-Annua l Accessibl e I.R . N o

.0163 4TABL EE-.

—X1 1 NATIONA

LEMISSIONS"~INVENTOR Y ETHYLENEPRODUCTIO N Pag e 1 o f 1 3

pan y atlo n Cod e Number e on-atrea m aclt y - Ton s o f

Ethylene/Yr . irag e Productio n - Ethylene . T/Yr . ig e I n Productio n - T L o f Max . (f ) aslon s t o Atmospher e Strea m Flo v - Lb./Hr . Flo v CharacteriseI c - Continuous/Intermitten t I f Intermitten t - Hrs.'Yr . o f Flo v Coapoaltlo n- Tons/To nEthylen e Hydroge n Methan e Ethan e Ethen e Propan e Propen e C A + Hydrocarbon s Acetylen e Oxyge n Nitroge n Carbo nMonoxid e Carbo nDioxid e Nitroge nOxid e Sulfu r Oxide s Hydroge nSulfid e Wate r Sampl e Ta p Locatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Stack s Flow , SCF M

Pe r Stac k Numbe r Heigh t - Fee t Diamete r - Inche s Exi t Ca a Temperatur e - F ° Emissio nContro l Device s 1 Typ e - Flar e

Wate r Scrubbe r Refrlgerete d Condenae r 6 K . 0 . Drum Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo nEmlasion s - Ton/To no f Ethylen e (g) Tota l Partlculate/Aeroeo l Emission s - Ton/To no f Ethylen e Tote l NO , Tote l SO , Tota l C O 11- 1 600,00 0 540,00 0 5 Propan e Vaporize r Ven t <l Intermitten t 34 0

.0000 1 ^. 00001

- .0000 1 -• . 0000 1 Quenc hWate r Off-ga s 285 0 Contlnuou a

*.0000 1 -.0000 1

_ . 0000 1

.0000 1

.020 8 Emergenc y Ven t 15,00 0 Intermitten t 0.0 5

- . 0000 1 • * . 0000 1

_. . 0000 1 •t.0000 1 -.0000 1 ^.0000 1 -.0000 1 -.0000 1 Ca s Purlf . Sectio n 1,02 5 Continuou s Flar e Svee p Ga s 72 0 (a) Contlnuou a (Afte r Burning )

.0074 9 .0135 6

.0113 2

C 3 Storag e
GL C N o .00 8 1 30 ' 2 "

- 4 0 N o Ten

k No t Specified

197 1 Not Specified No 11 1 9 12 ' 8 " 19 4 N o Sourc e Sourc e GL C Ye a 7,00 0 1 100 ' 30 " 11 3 N o Strea

m

- 1 5 Mln . No t Sample

d
Aeaume d N o 14 6 1

240 * 30 " Ambient Ye a X Not Specifie d Ever y 1 5 Mln . CLC N o 28 4

E L - 2 2 <•. 0000 1

.0000 1TABLEEL-11 1 NATIONALHHISST6H B INVENTOR Y ETHYLEN

EPRODUCTION Pag e 2 o f 1 3 hpsn y ta tIo n Cod e Numbe

r fee on-atrea m aclt y - Ton ao f

Ethylene/Yr

. •rag e Productio n - Ethylene , T/Yr

. ag e I n Productio n - X o f Max . (* ) Isalon e t o Atmospher e Strea m Flo v - Lb./Hr

. Flo v Characterlati c - Continuous/Intermitten t I f Intermittent - Hre./Yr . o f Flo v Compositio

n- Tons/TonEthylene Hydroge n Methane Ethan e Ethane Propan e Propan e C + Hydrocarbon

a Acetylene Oxygen Nitrogen Carbo nMonoxid e Carbo nDioxide Nitroge nOxide Sulfu r Oxide s HydrogenSulfid e Wate r Seapl e Tap Location Dat a or Frequenc

y o f Samplin

g Type of-Analysi s Odor Proble

m Ven t Stack s Flov , SCF

M Pe r Stac k Number Height - Feet Oleaste r - inche s Exi t Ca s Temperatur e - F ° Emissio nContro l Device s Typ e - Flare Wate r Scrubbe r Refrigerated Condenae r 6 > K . 0 . Dru

m Othe r Catalog I . D . Number Tota l Hydrocarbo

nEmission s - Ton/To nof Ethylen

e Tota l Partlculate/Aeroso l Emission s - Ton/To nof Ethylen

e Tota l NO , Tota l SO , Tota l C O 11- 2 385.00 0 0 Aci d Ga s Vent 9,18 0 (a ) Continuou s (Afte r Burning ) Distillatio n Emergenc

y Ven t 800,00 0 (a ) Intermittent Not Specifie

d (Afte r Burning ) Not Specifie

d Miscellaneou s Leake 20,000/Yr . Intermittent Not Specifie

d

.0000 3

.2220 1 .0006 5 .1583 5 None Calculate

d No None

N o None N . A . None

(8 ) Not Specified I 120 ' 4 2 @ Ti p 160 0 Yea X



### E L 

### - 1 8 .0000 3

.0006 5 

# LTABL E EL-II I NATIONA L EMISSION S INVENTOR Y ETHYLEN E PRODUCTIO

N Pag e 3 of 1 3
an y tlo n Code Numbe r on-atrea

m cit y - Ton e of Ethylene/Yr . age Productio

n- Ethylen

e Tons/Yr . e I nProductio

n- % o f Max . (f ) alon e t o Atmoapher e Strea m Flo v - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermittent I f Intermittent - Hrs./Yr . Flo v Coapoaltlo

n- Tona/To

no f Ethylen

e Hydrogen Methan e Ethane Ethene Propan e Propene C, + Hydrocarbon s Acetylene Oxygen Nitrogen CarbonMonoxide Carbo nDioxid

e NitrogenOxide s Sulfur Oxlde a Hydroge nSulfide Wate r Saapl e Ta p Locatio

n Dat e o r Frequenc

y o f Samplin

g Typ e o f Analyal a Odor Proble

m n t Stack s Flov . SCFM

Pe r Stac k Nuabe r Height - Feet Diamete r - Inchea Exi t Ge e Teaperature a - F ° lia s Io nContro l Device s Typ e - Flar e Wate r Scrubbe r Refrigerated Condenser 6 . K . 0 . Dru

m Othe r Catalog l . D . Numbe r ota l Hydrocarbo

nEmission s - Ton/To nEthylen

e (g ) ota l Particulat e 6 Aeroso l Emission s Ton/To nEthylene ota l NO , ota l SO , ota l C O 11- 4 145,00 0 2 5 Emergenc

y Ven t Prod . Frsct . (a ) 36,00 0 (Max. ) Interm i tten t No t Specifie

d After Burnin

g

/ .0000 1 No t Specifie

d .0000 1

No t Specifie

d (coke ) - .0000 1 Weekly CLC N o Ye s No t Specifie

d 1 Groun d Leve l

Ye s

XSmok e Suppresso r 

## E l - 21 Emergenc y Ven t Prod . Frect . (a ) 36,00 0 (Max. ) Intermittent No t Specifie

d Afte r Burnin

g

_ , 0000 1 Not Specifie

d .0000 1

Not Specifie

d (coke ) -.0000 1 Weekl y CL C N o Ye a No t Specified 1 Groun d Leve l

Ye s

XSmok e Suppressor 

## E L '? ? .£.0000 1 .0000 2 .0000 1 11- 5 450,00 0 0 Emergenc

y Ven t Methanato r 3 4 Lb./Yr . Intermittent No t Specifie

d
*- . 0000 1 *.0000 1 -.0000 1 <- . 0000 1

-.0000 1 -.0000 1

Non e Calculate

d N o Not Specifie

d

N o

- • . 0000 1

_. . 0000 1 11- 7 325,00 0 325,00 0 1 8 11- 8 127,50 0 0 Plan t Flar e Syste m (a ) 5,74 0 (Avg. ) Continuou s Afte r Burnin

g

.0037 3 .1829 8

.1046 6
Tvic e Month GL C N o Ye s 150 0 1 22 5 3 6 40 0 Ye s X

E L - 2 0 Plsn t Flsr e Syste m No t Specifie

d

N o Ye s No t Specifie

d 1 20 0 2 4 ( 8 Ti p Ye s

E L - 2 1 No t Spec i fie

d

r

on y Io n !od e Numbe

r on-strea m :lt y - Ton ao f

Ethylene/Yr . ig e Productio n - Ethylen e Tona/Yr

. I i n Productio n - X o f Max . (f ) lion s t o Atmospher e trea a lo v • tba./Hr . lo v Characterletl c- Contlnuou ao rIntermitten t I f Intermitten t- Hra./Yr . Flo v oaposltlo n - Tone/To n o f Ethylen e Hydroge n Methan e Ethan e Ethan e Propan e Propan e C 4 + Hydrocarbon s Acetylen e Oxyge n Nitroge n Carbo n Monoxid e Carbo n Dioxid e Nitroge n Oxide s Sulfu rOxide s Hydroge n Sulfid e Wate r Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s I Odo rProble m |n tStack s Flov . SCF

M Pe rStac k Numbe r Heigh t- Fea t Diamete r- Inche a Exi tCa s Teaperature a• F ° •lesio n Contro l Device s Typ e - Fler e Wate rScrubbe r Refrigerate d Condense r & K

. O

. Dru

m Othe r Catalo g 1 . D . Numbe r ota l Hydrocsrbo n Emission s - Ton/To n Ethylen e (g ) ota l Particulat e & Aeroso l Emission s Ton/To n Ethylen e ota l NO , 'ota l SO , [ota l C O TABL EEL-lI l NATIONA LEMISSIONS INVENTOR Y ETHYLEN EPRODUCTIO

N

11- 6 100,00 0 0 Pag e 4 o f 1 3

(h ) Unspec i fle d Intermitten t Unspecifie d Fler e Ven t Unspecifie d Continuou s

On e I s provide d Non e Non e Non e Unspecifie d 1 1 2 abov e scrubbe r 6 21 2 Ye s + +

Non e

EL-3 1 Unspecifie d
Unspecifie d

Ye a +

EL-3 2 Non e Non e Non e Non e Non e

ajasgE—wn»ii| u j— > iiipiiiasiwJtsufttf'i \ r o

## = 

# r . i i i i 

### 1 j

TABL EEL-11 1 NATIONA LEMISSION S INVENTOR Y ETHYLEN

EPRODUCTION Pag e 5 o f 1 3 ompany ocatlo n P A Cod e Number at e on-atrea m apaclt y - Ton s o f

Ethylene/Yr

. verag e Productio n - Ethylen e Tons/Yr

. ang e I n Productio n - X o f Max

. (£ > alaalon s t o Atmospher e Strea m Flo v - Lba./Hr . Flov Characteristi c - Continuou s o r Intermitten t I f Intermittent - Hrs./Yr
. Flo v Compoaltlo

n- Tons/To

nof Ethylen e Hydrogen Methan e Ethane Ethane Propan e Propan e C, + Hydrocarbon s Acetylene Oxygen Nitrogen Carbo nMonoxide Carbo nDioxid

e NitrogenOxide s Sulfu r Oxide s HydrogenSulfid e Wate r Sampl e Ta p Locatio n bat e o rFrequenc y o f Samplin g Typ e o f Analyel s Odo rProble m Ven tStack s Flo v - SCF

M Pe rStac k Number Heigh t- Fee t Diamete r- Inche s Exi tGa s Teaperature a- F ° Emissio n Contro l Devlca a Typ e - Flar e Weter Scrubbe r Refrigerate

d Condense r & K . 0
. Dru m Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To n Ethylen e 18 ' Tota l Particulat e 4 Aeroso l Emission s Ton/To n Ethylen e Tota l NO , Tota l SO , Tota l C O 11- 9 600,00 0 600,00 0 

### D Plan t Flar e Syste m 9,00 0 Continuou s Afte r Burnin g

.0050 4 .0237 4

.0679 9 Non e

N o Ye s 1 36 0 6 0 1,00 0 Ye s X (b ) Hydrogenatlo n Catalys t Regeneratio n Ven t 8,15 0 Intermitten t 21 6 No t Specifie d

_EL . 

### _L7
_ Non e No t Sample d

Ye s 300,00 0 (d ) 1 26 0 19 2 26 0 - 30 0 Ye a

X K . 0
. Dru

m 

### E L 

### - 1 2 Canno t be Determine d Aci d Ca s Ven t 180 0 - 260 0 Contlnuou s (c )

.0049 2

.0082 0 .0002 8 C j t o C 7 H C .0019 7 No t Specifie d No t Specifie d Mas s Spec . N o No t Specifie d

Ye s

X Clsu s Uni t N . A .TABL E EL-11 1 NATIONAL EMISSION S INVENTOR Y ETHYLEN

E PRODUCTIO

N Pag e 6 o f 1 3
n y tlo n Code Numbe r on-atrea m cit y - Ton s o f

Ethylene/Yr

. ag e Productio n - Ethylen e Torts/Yr

. aI n Productio n - 7

. o f Ma x alen s t o Atmospher e tree a 

### (t

'lo v - Lbs./Hr . 'lo v Characteristi c - Continuous/Intermitten t i f Intermitten t - Hrs./Yr
. Flov Coapoaltlo

n- Tons/To no f Ethylen e Hydroge n Methane Ethan e Ethen e Propan e Propan e C. + Hydrocarbona Acetylene Oxygen Nitroge n Carbo nMonoxid e Carbo nDioxide NitrogenOxlde a Sulfu r Oxide s HydrogenSulfid e Wate r Sampl e Tap Locatio n Dat e o rFrequenc y o f Samplin g Typ o o f Analysi s Odo rProble m an tStack s Flo v - SCF

M Pe rStac k Numbe r Heigh t- Fee t Diamete r- inche a Exi tCa s Teaperature a- F ° lesio n Contro l Device s Typ e - Flar e Wate rScrubbe r Refrigerate d Condense r 6 K

. 0

. Drum Othe r Catalo g I . D . Number Tota l Hydrocarbo n Emission s - Ton/To n Ethylen e (f O Tota l Particulat e 4 Aeroso l Emission s Ton/Ton e Ethylen e Tots l NO , Tota l SO , Tota l C

O Ven t Fro m Furnac e Decoking 3,17 9 Intermitten t No t Specifie d 11-1 0 33 0 00 0 0 Aci d Ga s Ven t No t Specifie d Continuou s

196 8 CL C N o Ye s 1,00 0 1 20 0 2 4 20 0 N o No t Specifie dexcep t

SO

.

.0012 1 

# T
Incinerato r Feed 2 o r 3 tlmea/1 0 Yr . CLC , Or sat , We t N o Ye s 24,00 0 1 12 0 3 6 78 0 Ye s

X Incinerato r 

### E L 

### ' 9 .0010 8

.0012 1 Demethanize r

Emergenc yVen t 50 5 Ton/Yr
. Intermitten t No t Specifie d

C t + H C Non e

No Ye s .0015 3

1 16 0 1 0 20 0 N o C „ Splitte r EmergencyVent 35 8 Ton/Yr
. Intermitten t No t Specifie d

" 2 Non eTABLE EL-11 1 NATIONAL EMISSION S INVENTOR Y ETHYLEN

E PRODUCTIO

N Pag e 7 o f 1 3

an y tlo n Cad e Numbe

r a-strea m iclt y - Ton s o f

Ethylene/Yr . reg e Productio n - Ethylen e Tona/Yr . ( e I n Productio n - X o f Max . (f ) islon s t o Ataoepher a Itrea m
Flo v - Lbs./Hr . Plo w Chsracterletl c- Contlnuou ao rIntermitten t i f Intermitten t- Hre./Yr . Flo v Compositio n • Tons/To n o f Ethylen e Hydroge n Methan e Ethan e •sbylen e Propan e Prepylao a C 4 + Hydrocarbon s Acetylen e Oxyge n Nitroge n Carbo n Monoxid e Carbar n Mdald a Nitroge n Oxide s Sulfu rOxide s Hydroge n Sulfid e Wate r Seapl aTap Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s Odo rProble m sn tStack s Flov . SCF

M ParStac k Number Heigh t- Fea t Diamete r• inche a 'Exi tCa

aTeaparature a- F ° ialsalo n Contro l Davlce e Typ e - Flar

e Wate r Scrubbe r Refrigerate

d Condense r 6

> K . 0 . Dru

m Other Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To n Ethylen e (g ) Tota l Particulat e 4 Aeroao l Eraiseion s Ton/To n Ethylen e tota l NO , Tota l SO , Tota l C O Flar e Stac k Unspecified (Variable ) Cont1nuou

a

+ + 11-1 1 197,50 0 0
Safet y Valv e Dlacharge Stack Unspecifie

d Intermittent Unspecifie

d
§0.0000 6 (j ) lo.000 5 (j ) jo.001 1 (j ) )0.0000 8 (j ) Ge s Turbine Lub e 01 1 Ven

t 22 5 Continuou s

Z 0.00000 2 ^0.00000 1 0.0001 3 Z 0.00000 2


### JO . 00 5 Compresso r Oi l Reserves * Ven

t 7 8 Contlnuou

a

£0.00000 1 ^0.00000 4

^ 0.00000 5

- 0.0000 2
lo.001 7

+ Non e
Non e Unspecifie d 1 30 0 3 6 Unspecifie d Ye a X

EL-3 3 Compresso r Sou r Dru m K . 0 . Ven

t 8 0 Contlnuou

a

0 0001 6 0.00 1 0 000 5 Trac e $0.0001 3

Not Specifie

d Not Specifie

d Not Specifie

d Non e Unspecifie

d 1 15 0 2 0 Unspecifie

d Non e

Se e Continuatio n No t Specifie

d Onc e Mas s None

4 9 1 5 0 2 8 0 Non e Spectro

m (Simple ) sete r No

t Specifie

d Onc e Mas s Non e

1 7 1 6 0 4 8 0 Non e (Staple ) Spectromete r No t Specifie

d 'Simple ) Onc e Maa a Spectrograp

h N o

1 7 1 6 0 4 8 0 Non e 

# ITABL E EL-11 1 NATIONAL EMISSION S INVENTOR Y ETHYLEN

E PRODUCTIO

N Pag e 8 o f 1 3 Compan y Locatio n EP A Cod e Numbe r Dat e on-atrea m Capacit y

- Ton a o f Ethylene/Yr . Avereg e Productio n- Ethylen e Tons/Yr . Rang e I nProductio n- 7 . o f Max . (f ) Emission s t o Atmospher e Strea m Flo v - Lbs./Hr . Flo v Characteristi c - Contlnuou a o r Intermitten t I f Intermitten t - Hrs./Yr . Flo v Compositio n- Tons/To no f Ethylen e Hydroge n Methan e Ethan e Ethylen e Propan e Propylen e C ^ + Hydrocarbon s Acetylen e Oxyge n Nitroge n Carbo nMonoxid e Carbo nDioxid e Nitroge nOxlda a Sulfu r Oxlda a Hydroge nSulfid e Wete r Sampl e Ta p Locatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Steck e Flov , SCF M

Pe r Stac k Numbe r Heigh t - Fee t Dlaaata r - Inche a Exi t Ca a Teaperature a - F ° Emissio nContro l Device s • Typ e - Flar e

Wate r Scrubbe r Refrigerate d Condenae r t . K . 0 . Dru m Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo nEmission s - Ton/To nEthylen e (g ) Tota l Particulat e 6 » Aeroso l Emission s Ton/To nEthylen e Tota l NO , Tota l SO , Tota l C O 11-1 1 197,50 0
0
Sou r Sea l Oi l Ven t 15 0 Contlnuou a

0.000 3 .0007 4 1.0014 8 

# 5 ° T 0.0005 3 0.0002 8

No t Specified (Simple ) Onc e Maaa Spectrograp

h N o

2 6 1 5 0 1 8 0 Non e Anelyeer Ven t .£0.0 1 Continuou s 

# u? 3*.ld6 

### v_id 6

No t Specifie d (Simple ) No t Specifie d Maa a Spectrograp h N o

0. 1 SCF H 1 1 0 1/ 4 8 0 Non e

Se e Continuatio n Fourt hStag e Relie f Valv e Ven t 24 5 00 0 Intermitten t 0.2 5 (i )

Il6 6
10.00015 5

No t Specifie d (Simple ) No t Specifie d Mas s Spectromete r N o
35,00 0

•e l 19 6 Non e

0 0TABLE EL-11 1

pan y atlo n Cod e Numbe r aon-strea a taclt y » Ton s o f

Ethylene/Yr . irag e Productio n - Ethylen e Tona/Yr . lg e i n Productio n - I o f Max . (f ) Lsslon s t o Atmospher e Strea m
Flo v - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t I f Intermittent - Hra./Yr . Flo v Compositio

n- Tons/To n o f Ethylen e Hydrogen Methan e Ethane Ethylene Propan e Propylen

e C A + Hydrocsrbon s Acetylene Oxygen Nitroge n Carbo nMonoxide CarbonDioxide Nitroge nOxide s Sulfu r Oxide s Hydroge nSulfide Wate r Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProble m ren tSteck e Flov , SCF

M Pe rStac k Numbe r Heigh t- Fee t Disaste r- Inche a Exi tCa s Teapersture s - F ° Emissio n Contro l Device s Typ e - Flar s

Wste rScrubbe r Refrigerate d Condense r4 K . 0 . Dru m Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s Tota l Particulat e 4 Aeroao l Tota l NO , Tota l SO , Tota l C O - Ton/To n Ethylen e (g ) Emission s Ton/To n Ethylen e NATIONAL EMISSION S INVENTOR Y ETHYLENE PRODUCTIO

N

Depropanize r Relie f Valv e Ven t (Bottom ) 214.00 0 Intermitten t 0.2 5 (i )

>0.0000 3 30.00005 3 »0.00003 5 0.00001 8 1 1 19 7 -1 1 ,50 0 0 Depropanize r Relie f Valv e Ven t (Top ) 230.00 0 Intermitten t 0. 5 (1 )

10.0000 3 I P 0001 3 Vo.0001 4 

### <.io- ° Pag e 9 o f 1 3

No tSpecifie d (Simple ) No tSpecifie d Maa aSpectromete r N o Non e 46,00 0

^ 4 0 Non e No tSpecifie d (Simple ) No tSpecifie d Maa aSpectromete r N o Non e 46,00 0

^1- 5 Non e

Se e Continuatio n Depropenlze r Overhee d Relie f

Ven t 230,00 0 Intermitten t 0.2 5 (1 )

> 0 00001 5 t O 00006 5 10.0000 7 _:io- 6

No t Specifie d (Simple ) No t Specifie d Mas a Spectromete r N o Non e 45,30 0

-.5 0 Non e Debutanlze r Overhea d Relie f Ven t 36,00 0 Intermitten t 0 2 5 (i )

- 6 

### l<u o 0 00002 3

No t Specifie d (Simple ) Tvic e Weekl y Ga s Chromatograph N o Non e 3,90 0

Non e

C O

### I I 1 1 » '

Compan y Location EP A Code Number Dat e on-atrea

m Capacity

- Ton a o f Ethylene/Yr
. Averag e Productio n - Ethylen e Tons/Yr
. Rang e InProductio n - I o f Max . (f ) Emission s to . Atmospher e Strea m
plo v Chirlcteri.tl c - Continuou s o r Intermitten t i f Intermittent - Hrs./Yr
. Flo v Compositio

n- Tons/Tono f Ethylen e Hydrogen Methane Ethane Ethylene Propan e Propylen

e C . • Hydrocarbon s Acetylene Oxygen Nitrogen Carbo nMonoxide Carbo nDioxid

e NitrogenOxide s Sulfu r Oxide s HydrogenSulfide Wate r Sampl e Ta p Locatio

n Dat e o r Frequenc

y o f Samplin

g Typ e of Analyel e Odor Proble

m Vent Stock s Flov . SCF

M Pe r Stac k Numbe r Height - Fee

t Diamete r - Inche s Exi t Ca s Temperaturea - F~ EmlsslonContro l Devlcea Typ e - Flare Wate r Scrubbe r Refrigerate

d Conden.e r 4 K . 0
. Dru m Othe r Catalog I . D . «"- be r

_Ton8 / T o n Ethylen e (g ) 

# E S Knsr

. x_r. . _r.;-- . ^ r.th,i.n

. Tots l NO , Tots l SO , Tota l C O I 1 >

TABL E El.-II I NATIONAL EMISSION S INVENTOR Y FTHYI.EN E PRODUCTIO

N

11-1 1 197,50 0 0

Remot e Operated Valv e Ven t 32 0 Continuou s

0.00 6 0.000 4 0.0001 3 0.0001 4 lo.0004 5

No t Specifie d (Simple ) Onc e Maaa Spectrograp

h N o
11 5 1 5 0 6 8 0 Non e Pag e 1 0 o f 1 3

Lub e Oi l Reservoi r Ven t 6,10 0 Continuou s

0.00 1 ^0.0000 1 ^0.0000 1 0.000 1 \013 4

No t Specifie d (Simple ) Onc e Mas s Spectrograp

h N o
1,32 0 I 5 0 6 8 0 Non e

0 0075 3 Non e Non e Non e Non e 

# m

I 

# 1

J^ B 

# n I H 

# 1

Sea l Oi l 1 Reservoi r Ven t 4 0 Continuou s

^.O.OOOO l ^0.0000 1 zs> 0000 1



### _ : 0 oooo i 

## 2^ o oo i

No t Specifie d (Simple ) Onc e Haa s Spectrograph N o

8 1 8 

## * 8 0 Non e



# a

• ..n i >——— i 

### |TABLE EL-11 1 NATIONA

L EMISSION S INVENTOR Y ETHYLEN

E PRODUCTIO

N Pag e 1 1 Of 1 3 ompan y ocatio n P A Cod e Numbe

r at e on-atrea m —pacit y - Ton s o f

Ethylene/Yr . .verag e Productio n - Ethylen e Tons/Yr . tange i n Productio n - 7 . o f Max . ( O jalaalon s t o Atmospher e Strea m Flo v - Lbs./Hr . Flo v Characteristi c - Continuou s or intermitten t i f Intermitten t - Hrs./Yr
. Flo v Compositio

n- Tona/To n o f Ethylen e Hydrogen Methane Ethan e Ethen e Propan e Propan e C4 + Hydrocarbona Acetylene Oxygen Nitrogen Carbo nMonoxid e Carbo nDioxide NitrogenOxlde e Sulfu r Oxlde a HydrogenSulfid e Wate r Seapl e Ta

p Location Dat e o r Frequenc

y of Semplin

g Typ e o f Analyal a Odo r Proble

m Ven t Stack a Flo v - SCF M per Stac k Numbe r Heigh t - Feet Diameter - lnchea Exi t Ga s Temperature s - F ° Emlaslo nContro l Device s Typ e - Flare Wate r Scrubbe r Refrigerated Condense r 6
. i:
. O . Dru m Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To n Ethylen e (S ^ Tota l Particulat e 4 Aeroso l Emission s Ton/To n Ethylen e Tota l N0

_ 11-1 2 225,00 0 225,00 0 0 11- 3 800,00 0

Tota l Tota l 

## S°x C O Emergenc y Ven t Prod . Fract . 50,00 0 (Max. ) Intermitten t No tSpecifie d

Weekl y CL C N o Ye s No tSpecifie d 1 Ground Leve l

Ye s X
X Smok e Suppresso r E L - 2 4 No tSpecifie d Emergenc y Ven t Prod . Fract . 50,00 0 (Max. ) Intermitten t No tSpecifie d 

## 1ST" No t Specifie d

Weekl y CL C No Ye s No t Specifie d 1 Groun d Leve l

Ye s X

X Smok e Suppresso r E L - 2 4

TJ C OTABLEEL-11 1 NATIONALEMISSION S INVENTOR Y ETHYLEN

EPRODUCTION n y Io n lod e Nunbe r lon-strae a pit y - Ton s o f

Ethylene/Yr

. I n Productio n - X

o f Max

. (f ) lion s t o Atmospher e > trea m Flo v - Lbs./Hr . Flo v Characterlatl c - Continuou s o r Intermitten t I f Intermittent - Hss./Yr . Flo v Coapealtlo

n- Tona/To

no f Ethylene Hydrogen Methane Ethan e Ethene Propane Propane C. + Hydrocarbon s Acetylen e Oxygen Nitrogen Carbo nMonoxid

e CarbonDioxid

e Nitroge nOxide s Sulfur Oxide s HydrogenSulfide Wate r Seapl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s Odo rProble m n tStock s Flo v - SCF

M Pe rStsc k Number Heigh t- Fee t Diamete r- Inche s Exi tGa aTemperature s - F ° ilsslo n Contro l Device s Typ e - Flsr e Wate r Scrubbe r Refrigerate

d Condense r 4 1" . 0 . Dru m Other Catalo g I . D . Number ota l Hydrocarbo n Emission s - Ton/To n Ethylen e (g ) ota l Particulat e 6

> Aeroao l Emission s - Ton/To n Ethylen e ota l NO

x 'ota l SO , ota l C O 11-1 3 300,00 0

Ven t Fro m Furnac e Decokin

g Intermitten t

Not Specified Not Specified

.0240 0 Coke .0000 1 ( 3 Furnac e 196 9 Coulte r Counte r N o Ye s 4,29 0 1 78. 5 1 4 21 2 Ye s

E L 1 0 Acetylen e Converter Regeneratio

nVen t 46 0 Intermittent 40 8

Not Specifie

d No t Specifie

d No t Specifie

d No t Specifie

d

Not No t

N o Ye s 1 4 2 8 14 0 Ye s Specifie

d Sample d Pag e 1 2 o f 1 3

Causti c Neutrallz

. Ven t 20,67 2 Continuou s Plan t Flar e Syste m 91 0 (s ) Contlnuou s 'After . Burning )

.0669 3 .2240 6

.0001 7

Not Sample

d Engr . Est . N o Ye s 4,50 0 1 9 3 8 Ambien t Ye s

E L 1 5 XVapo r Collector s 4 Dilutio nDevic e EL - 1 1 .0348 6

.0285 2 Not Sample

d Calcuate

d N o Ye s I 13 0 3 6 180 0 - 250 0 Ye s X

E L - 3 0

c o ro

### TABL E EL-II I EXPLANATION

O F FOOTNOTE S NATIONAL EMISSION S INVENTORY ETHYLENE PRODUCTIO N Pag e 1 3 o f 1 3 (a ) Th e flow

rat e give ndescribe s th e stream prio r t o combustion . (b ) 80,00 0 lb./hr . o f a 927 . methan e strea m - mos t probabl y

th e demethanize r overhea d - i s use d t o supplemen t th e fue l t o th e pyrolysi s furnace . Thi s strea

m an d it' s resultan t atmospheri c emission s (CO 2 & H2O ) are no t detaile d elsewher e i nthi s report . (c ) Thi s strea

m i s no t emitte d t o th e atmosphere , i t i s sen t t o a Clau s plant . (d ) Boile r stac k used . (e ) Althoug hther e i s a wealt ho f Informatio ni nthi s report ; quantitativ e dat a o nemission s ar e conspicuou s b y thei r absence , (wit hexceptio no f moto r exhaus t data ) (f ) Difference betwee nmaximum an d minimum

quarterl y

productio ndivide d b y maximum

quarterl y

production . (g ) Include s H 2 

### S . Exclude s CH 4 & Hj . (h ) Thre e identica l scrubber s are provide d o nth e acetylene converter , propadiene converte r an d hydrogenatio ncatalys t regeneratio nvents . The emission s fro m eac har e essentiall y th e same . (i ) Estimate d maximum pe r year . (j ) Calculate d o nbasi s o f tota l o f maximum estimate d release s fro m eac h relie f valv e i ncircuit .EP A Cod e No . Capacit y - Ton s o f EDC Average Productio

n- Ton s o f EDC Emission s t o Atmospher e Strea m Flo v - Lbs./Hr . Flo v Character 1 atl c - Continuou s o r Intermittent I f Intermittent - Hra./Yr . Flo v Compositio

n- Tons/To

no f EDC 1, 2 Dlchloroethan

e Viny l Chlorid

e Ethyl Chlorid

e Methane Ethylen e Oxyge n Nitroge n Carbo nDioxid

e Carbo nMonoxide Wate r Ai r Hydroge nChloride Chlorin e Hydroge n Analysi s Sampl e Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analyai a Odo rProble m Ven tStack e Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGas Temperatur e - F ° Flo v - SCF

M Emissio n Contro l Device s Condense r Wate r Scrubbe r Spra y Tove r Tota l Hydrocarbo

nEmission s - Ton/TonEDC Tota l Particulat e 4 Aeroso l Emission s Tota l N O Emission s - Ton/To nEDC Tota l SO „ Emission s - Ton/TonEDC Tota l C O Emission s - Ton/TonED C Ton/To

nEDC TABL E EDC-II I NATIONA L EMISSIONS INVENTOR Y DICHLOROETHAN

E B Y DIRECT CHLORINATIO

N

Scrubbe r Ven

t 35 1 Continuou s

.00267 5

.00378 9 .00865 8 .00757 9 .00396 5 .00032 5

.00018 4 No
Estimat e On-Plan t Ye s 1 3 8 4 5 0 6 5 Ye a Ye s .00646 4 0 0 0 0 12- 1 47,50 0 47,50 0 Primar y Decante rVen t 10 0 Continuou s
.00058 8

.00043 0 .00775 4

N o
Estimat e On-Plan t Ye a 3 1 2 1.5 , 9 0 2 3 N o 2.25 , 2 

### ( D

.00058 8 0 0 0 0 Pag e 1 o f 3

Secondar y Decante rVen t 2 0 Continuous
.00011 8 Fugitiv e Emission s
Continuou s 

## ( ) ( 00009 ) 

## ( )

.00008 6 .00155 0

N o
Estimat e On-Plan t Ye s 2 2 0 1.54 , 1.5 4 < l > 8 0 4. 7 N o

.00011 8 0 0 0 0 .00009 1 0 0 0 0 (1 ) Equivalen tdiameter .

c oTABL E EDC-II I NATIONA L EMISSION

S INVENTOR

Y DICHLOROETHAN

E B Y DIREC T CHLORINATIO

N Pag e 2 o f 3 P A Cod e No . apaclt y - Ton s o f

ED C verag e Productio n - Ton s o f ED C Ealesion s t o Atmospher e Strea m 12- 2 401,30 0 401,50 0 Scrubbe rVen t Scrubbe rVen t Flo v - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t i f Intermittent - Hrs./Yr . Flo v Compositio

n- Tons/To

no f ED C 1, 2 Dlchloroethane Viny l Chloride Ethy l Chloride Methan e Ethan e Ethylen e Oxyge n Nitroge n Carbo n Dioxid e Carbo n Monoxid e Wate r HydrogenChloride Chlorine Ai r Analysi s Sampl e Locatio

n Dat e o r Frequenc

y o f Samplin

g Typ e o f Analysi s Odo r Proble

m Vent Stacka Numbe r Height - Feet Oleaste r - lache s Exi t Ca s Teaperatur e - F ° Flo v - SCFM EalBalonContro l Devic e Condense r Wate r Scrubbe r Spra y Tove r Tote l Hydrocarbo

nEmission s - Ton/To nEDC Tota l Particulat e 6 . Aeroso l Emission s - Ton/TonEDC Tota l NO , Emission s - Ton/To nEDC Tota l SO , Emission s - Ton/To nEDC Tota l C O Emission s - Ton/To nEDC 42 2 Continuou s

.00023 1 .00002 2 .00057 6 .00015 7 .00087 9

.00079 5 .00005 3

.00187 9 Ye s I nVen t Fou r time s per veek fo r si xveek e Chromatograp

h No Ye s 1 9 5 50 5 Ambient 7 5 Ye s Ye s .00186 5 0 0 0 0 70 2 Continuou s
.00077 5 .00002 3 .00040 6 .00081 2 .00012 7 .00147 6

.00150 4 .00028 2

.00231 1 Ye s InVen t Fou r time s pe

r vee k fo

r si xveek s Chromatograp

h N o Ye s 1 12 0 .50 5 Ambien t 15 0 Ye s Ye s .00280 7 0 0 0 0



## [VK\v\n W$\ «P^V\«" W 

## 4 C O e nCod e No .

specif y - Ton ao f

ED C |verag aProductio n - Ton s o f ED C lesion s t p Atmospher e Strea m Flo v - Lbs./Hr . Flo v Chsracterlstl c - Continuou s o r Intermittent I f Intermitten t - Hrs./Yr . Flo v Compositio

n- Tons/To no f ED C 1. 2 Dlchloroethane Viny l Chloride Ethy l Shlorld e Methan e Ethylen e Oaygao Nitroge n Carbo n Dioxid e Carbo n Monoxid e Wate r HydrogenChlorid e Chlorine Analysi s Sampl e Location Dat e or Frequenc

y o f Samplin

g Typ e o f Analysi s Odo r Proble

m Ven t Stack s Number Height - Fee t Diamete r - Inche s Exi t Ga s Temperatur e Flo v - SCF M •missionContro l Devic e Condense r Wate rScrubbe r Spra y Tove r Tota l Hydrocarbo n Ealaslon a- Ton/To n ED C Tota l Particulat e 6 . Aeroso l Emission s - Ton/To n ED C (4 ) Tota l NO , Ealaslon a- Ton/To n ED C Tots l SO , Emlaalon a• Ton/To n ED C Tota l C O Emission s - Ton/To n ED C TABL E EDC-II I NATIONA L EMISSIONS~TOVENTOR Y DICHLOROETHAN

E B Y DIREC T CHLORINATIO

N Page 3 of 3

31- 1 238,00 0 Not Specifie

d (V ) Scrubbe r Ven

t 64 9 Contlnuou

a (2 ) ,00015 6 .00001 8 .00001 4 .00123 2 .00026 2 .00227 4 .00398 3 .00268 9 .00019 3 .00006 2 .00002 0 Ye a InVent Onc e a vee

x Chromatograp

htitratio

nfo r Cl . Ye s Ye s (3 ) 1 14 8 3 9 0 11,00 0 Ye s Ye s Ye s .00045 0 .00008 2 0 0 0 Fugitiv e Emission s 4 2 Continuou s

.00070 6

None
Estimat e N o

.00070 6 0 0 0 0 (1 ) Approximat e capacity base d o ntota l capacit

y fo r oxychlorlnatlonan d direc t chlorlnatio nunit e an

d approximat e oxychlorlnatlo ncapeclty . (2 ) Approxlaat e compositio nbase d o npercentage of combine d oxychlorlnatlo

nan d direc t chlorlnatio nfee d strea m t o th e scrubbe r an

d assumptio

n(1) . (3 ) Uni t use

d b y oxychlorlnatlo

nproces s alao . (4 ) Classifie s HC 1 an d Cl 2 a s aeroso l becaus e bot har e vapo r a t emitte

d conditions .



### pMW Q »*«- » • n 

### M»W«"0. 4 f

o Ic o lo tTABL E FS-II I NATIONA L EMISSION S INVENTOR Y FORMALDEHYD

E VI A SILVE RCATALYS T PROCES S Pag e 1 of ' 6 P A Cod e Numbe

r at e on-atrea m apaclt y - Ton e o f

377 . HCHO/Yr

. varag e Productio n - Ton e o f 377 . HCHO/Yr

. ang e i n Productio n - 7 . o f Max . slsslon at o Atmospher e Stras a Flo v • lba./hr . Flo v Characteristi c - Continuou s o r Intermitten t I f Intermittent - hra/yr . Coaposltlo

n- Tona/To

no f 377 . HCHO Formaldehyde Methano l Methy l Format e Dl-methy l Ether Methyla l Oxyge n Nitrogen Carbo nMonoxid

e Carbo nDioxid

e Methane Wate r Hydrogen Sampl e Ta p Locatio

n Dat e o r Frequenc

y o f Samplin

g Type o f Analysi s Odo r Proble

m Iven t Stack a Flo v - SCF M pe r stac k Number Height - Fee

t (elev . @ tip ) Diamete r - Inche s Exi t Ga s Temperature - F ° lEalaalo

nContro l Device s Typ e - Wate r Scrubber

Incinerator Catalog I . D . No . Tota l Hydrocarbo

nEmission s - Ton/To nHCH O (377. ) Tota l Particulat e 4 Aeroso l Emission s - Ton/TonHCH O (377. ) Tota l NO , - Ton/To

nHCH O (377. ) Tota l SO , - Ton/To

nHCH O (37*4 ) Tota l C O - Ton/To

nHCH O (371 ) 14- 1 154,00 0 1 7 Absorbe r Ven

t Not Specified Continuou s

+
+

None Never N o Ye s 1 43. 8 4 2 Ye s X FS- 1 No t Specified Converter Emergenc y Ven t No t Specifie

d Intermittent 0.1 0
+ +

+

Non e Never

No t Specifie

d

>500 o N o 14- 3 47,50 0 47,50 0 0 Converter 262 0 Start-u

p Ven t
Intermitten

t 5

.0001 1

.0000 3

Non e Never

No t Specifie

d

N o

.0048 9 0 0 0 .0015 9 Abaorber Ven t No t Specifie

d Contlnuou

a
.0011 4 .0036 4

+ + .0015 9 + .0119 3 .0075 5

Ye a 71 8 1 6 '68 ) .6 7 82 ° N o



# 3TABL EFS-II I NATIONA LEMISSION S INVENTOR Y
EP A Cod e No

. Dat e oo-etrea m Capacit y - Ton s o f

377

. HCHO/Yr

. Averag e Productio n - Ton s o f 377

. HCHO/Yr

. Rang e I n Productio n - 7 . o f Max. Emission s t o Atmospher e Strea a Flo v - lba./hr . Flo v Characteristi c - Continuou s or Intermitten t I f Intermitten t - hrs./yr . Coapoaltlo

n- Tone/Tono f 37* 4 HCH O Formaldehyde Methano l Methy l Format e Dl-mathy l Ethe r Methyla l Oxyge n Nitroge n Carbo n Monoxid e Carbo n Dioxid e Methan e Wate r Hydroge n Seapl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ e o f Analyal a Odo rProble m Ven tStack s Flo v - SCF

M pe rstsc k Numbe r Heigh t• Fee t(elev . @ tip ) Diamete r- Inche s Exi tCa s Temperatur e - F ° Emissio n Contro l Device s Typ e - Wate rScrubbe r Incinerato r Catalo g I . D . No . Tota l Hydrocarbo n Emission s - Ton/To n HCH O (377. ) Tota l Particulat e 4 Aeroso l Emission s - Ton/To n HCH O (377. ) Tote l NO , - Ton/To n HCH O (377. ) Tota l SO , - Ton/To n HCH O ( 3 77. ) Tota l C O - Ton /To n HCH

O (377. ) FORMALDEHYD E

Absorbe t Ven t 404 0 VI

A SIL V

* 1
Continuou s
.0003 5 .0011 1

.0026 9 .2556 9 .0023 8 .0335 4 .0094 6 .0052 3 Non e Neve r Calc . No Ye a 109 0 t o 1 6 0

. 9 104 ° t o N o 

## \

115 2

140 ° rE

RCATALYS T PROCES S

Abaorber Ven t 135 0 1 4

5 2 5 2 pag

e 2 o f 6

- 4 50 0 50 0 0 # 2
Continuou s
.0001 2 .0003 7

.0009 0 .0852 3 .0008 0 .0111 5 .0031 5 .0017 4

Never Calc . N o Yea 36 3 to 38 4 1 5 0

. 6 104 ° t o N o 140 °

.0034 8 0 0 0 .0055 6 Abaorber

Ven t 404 0 # 3

Contlnuou

a
.0003 5 .0011 1

.0026 9 .2556 9 .0023 8 .0335 4 .0094 6 .0052 3 Non e Never Calc . N o Yea 109 0 t o 1 6 5 9 104 ° t o N o 115 2

140 ° 

### ;

Strippe r Overhea d Ven t 5 4 Continuou s
.0000 2 .0000 5

+
+ .0037 2
+ .0003 8

Non e Neve r Estimat e N o Ye s 5 t o 2 0 1 6 5 4 78 ° t o 110 ° N ot 

## r i

TABL E FS-II I NATIONA L EMISSIONS INVENTOR Y FORMALDEHYD

E VI A SILVE RCATALYS T PROCES S Pag e 3 o f 6 A Cod e Numbe

r t e on-stree m paclt y - Ton s o f

377 . HCH

O erag e Productio n - Ton s o f 3 77 . HCH O ng e I n Productio n - 7 . o f Max . lsslon s t o Atmospher e Strea m . Flo v - lbs./hr . Flo v Characteristi c- Continuou s o rIntermitten t I f Intermitten t- hrs./y r Compositio n - Tons/To n o f 377 . HCH

O Formaldehyd e Methano l Methy l Format e Dl-methy l Ethe

r Methyla l Oxygen Nitroge n Carbo nMonoxid

e Carbo nDioxid

e Methan e Wate r Hydroge n Seapl e Ta

p Locatio

n Dat a o r Frequenc

y o f Samplin

g Type o f Analysi s Odo r Proble

m i t Stack s Flo v - SCF M pe r atac k Number Height - Feet (elev . (? tip ) Dlaaate r - Inche s Exi t Ga s Temperatur e • F ° salo nContro l Device s Typ e - Wate r Scrubber

Incinerator Deaister Othe r Catalog I . D . No . J l Hydrocarbo

nEmission s - Ton/Tono f 37 7 HCH O s i Particulat e 4 Aeroso l Emission s - Ton/Tonof 377 . HCH O S i N O Emisalon s - Ton/To no f 37 7 HCH

O a l SO * Emission s - Ton/To no f 37 7 HCH

O • 1 CO Emission s - Ton/To no f 37 " HCH

O 14- 7 50,00 0 0 Absorbe r Ven

t 736 9 Continuou s

.0003 5 .0034 0 .0023 0

.5300 0 .0010 0 .0385 0 .0275 0 .0110 0 Non e Neve r Calc'd . No Ye s 200 0 1 9 8 8 9 5 Ye s

FS- 3 .0060 5 0 0 0 .0010 0 e

xDesig n 14- 8

75,00 0 75,00 0 0 Absorber Ven

t 11.60 0 Continuou s

,0006 7

.5612 9 .0052 9 .0592 0 .0063 4 .0126 3 Stac k 197 2 GL C + Titratio

n N o Ye a 320 0 1 10 0 1 6 5 4 Ye s

+ FS- 5 .0010 0

0 0 0 .0052 9 Jet Exhaus t

Continuou s

.0003 3

Non e . Never Celc'd . N o Yea 1 4 3 1. 5 20 0 Ye s

+ (condenser ) FS- 6 14- 9 30,91 9 30,91 9 0 Absorber Emerg . Vente Manual/Aut o Intermitten

t Absorber Ven t No t Specifie

d

Proces s Rando m Orsat + 7 N o Ye a 1/ 1 30/2 0 8/ 8 500/50 ° N o Ye s

FS- 2 Not Specifie

di > i

TABL E FS-II I NATIONA L EMISSIO

N INVENTOR

Y FORMALDEHYD

E VI A SILVE RCATALYS

T PROCES

S Pag e 4 o f 6 EP A Cod e Number Capacit y - Ton s o f

377 . HCHO/Yr

. Averag e Productio n - Ton s o f 377 . HCHO/Yr

. Rang e i n Productio n - 7 . o f Max. Emission s t o Atmospher e 

### Strea a Flo v - lbs./hr . Flo v Characteristi c - Continuou s o r Intermitten t I f Intermittent - hrs./yr . Composition- Toas/to no f 377 . HCH

O Formaldehyde Methano l Methy l Format e Dl-methy l Ethe r Methyla l Oxygen Nitrogen CarbonMonoxide Carbo nDioxide Methane Wate r Hydrogen Seapl e Ta p Locatio n Dat e o r Frequency

o f Samplin

g Type of Ana l

y el a Odo rProbea m Ven tStack s Flo v - SCF

M pe rstac k Number Heigh t- Fee t(elev . ( ° tip ) Diemete r- Inche s Exi tCa s Temperstur e - F ° Emissio n Contro l Device s Typ e - Wate rScrubbe r

Incinerato r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To n HCH O (377. ) Tota l Particulat e & Aeroso l Emission s - Ton/To n HCH O (377. ) Tota l NO , - Ton/To n HCH O (377. ) Tota l SO, , - Ton/To n HCH O (377. ) Tota l C O - Ton/To n HCH

O (377. ) 14-1 0 240.00 0

Absorbe r Ven

t Incinerato

r Flu e ga s 39,72 7 Continuou s

TR T R

.0100 5 .4794 0 .0426 9 .1849 1 T R

Never GL C N o Ye s 10,05 0 1 8 5 6 0 90 0 Ye s

FS- 7 0 0 0 0 0 14- 6 200,00 0 

# 1

No t Specifie

d

Ye s

+ Boiler FS- 6 Cannot B

e Determine

d

## i i

TABL E FS-II I NATIONA

L EMISSIONS~INVENTORY FORMALDEHYD

E V U SILVE RCATALYS T PROCES S Pag e 5 o f 6
> A Cod e No . i t e on-a trea m ipaclt y - Ton ao f 377 . HCH

O rerag e Productio n - Ton s o f 377 . HCH

O Ing e i n Productio n - X o f Max . • 1 salon s t o Atmospher e Strae a Flo v - lba./hr . Flo v Character 1 atl c - Contlnuoua o r Intermittent I f Interalttent - hra./yr . Coapoaltlo

n- Tona/Tono f 377 . HCHO Formaldehyd

e Methano l Msthy l Format e Dl-methy l Ethe r Methyle l Oxygen Nitrogen Carbo nMonoxide Carbo nDioxid

e Methan e Wete r Hydroge n Seapl e Ta

p Locatio

n Dat e o r Frequenc

y o f Semplln

g Type o f Analyst s Odor Proble

m n t Stecke Flo v - SCF M pe r atac k Number Heigh t - Feet (elev . 0 tip ) Diamete r - Inche s Exi t Gaa Temperatur e - F ° alealo nContro l Davlcea Type - Wate r Scrubbe r Incinerator Dealster Othe r Catalo g I . D . No . ota l Hydrocarbo

nEmission s - Ton/Tonof 3 77 . HCH O ota l Particulat e & Aeroso l Emission s - Ton/To nof 377 . HCH

O l l NO , Emission s - Ton/Tono f 37 7 HCH O ota l SO , Emission s - Ton/Tono f 377 . HCH O ota l C O Emission s - Ton/Tono f 377 . HCH O 14-1 2 35,00 0 35,00 0 0 Absorbe r Ven

t 5,85 5 Continuou s
.0004 1 .0008 2

.0027 6 .0019 1 .0139 0

Dall y Calc'd . Ye s .46 0 1 7 3 1 8 8 0 Ye s

+ FS- 4 .0012 3 0 0 0 .0027 6 Jet Exhaua t 100 0 Continuou s

.1851 9

Non e Never N o Ye s 1 2 2 1 20 0 N o 14-1 8

20,00 0 20,00 0 0

0 0 0 0 0029 2 Absorber Ven t 336 0 Continuou s

.0025 0 .5482 8 .0029 2 .0585 6 .0016 7 .0098 9 To p o f Tover Bl-ennua l Oraat + 7 N o Yea 89 1 1 4 4 6 5 0 N o Abaorbe r 738 6 14-2 0

50.00 0 50.00 0 0 Ven t
Continuou s
.0003 5 .0032 6 .0022 4

.5101 6 .0010 4 .0368 8 .0265 6 .0104 0

Rando m Calc'd . No Ye a 1 9 5 13 2 9 5 N o

.0082 5

0 0 0 .0010 4 Distillatio nTo m Overhea d Ven t 3 0 Continuou s
.0012 0 .0012 0

Neve r No t Specifie

d N o

1 9 5 13 2 9 5 N o



# F

T JTABLE FS-II I NATIONAL EMISSION S INVENTOR Y FORMALDEHYD

E VI A SILVE RCATALYST fMQCES S Pag e 6 o f 6 EP A Cod e No . Dat e on-atrea m Capacit y - Ton s o f 377. . HCHO/Yr . Averag e Productio n - Ton s o f 37 7 HCHO/Yr . Rang e i n Productio n - 7 . o f Max . Emlaalon at o Atmospher e Strea m

Flo v - Lbe./Hr . Flo v Characteristi c- Continuou s o rIntermitten t I f Intermitten t- Hre./Yr . Compoaltlo n - Tons/To n o f 377 . HCH

O Formaldehyd e Methano l Methy l Format e Dl-aethyl Ether Methyla l Oxyge n Nitrogen Carbo nMonoxid

e Carbo nDioxid

e Methane Wate r Hydroge n Sampl e Ta

p Locatio

n Dat e o r Frequenc

y of Samplin

g Type o f Analysi s Odor Proble

m Ven t Stack a Flo v - SCF M pe r stac k Number Heigh t - Fee t (elev . 0 tip ) Dlaaeter - inchea Exi t Ca s Temperature - F ° Emissio nContro l Device s Type - Wate r Scrubbe r

Incinerato

r Catalog 1 . D . No . Tota l Hydrocarbo

nEmission s - Ton/To nHCHO (377 ) Tota l Particulat e 4 Aeroso l Emission s - Ton/TonHCH O (377. ) Tota l N0 X- Ton/To

nHCH O ( 3 77. ) Tota l SO , - Ton/To

nHCH O ( 3 77. ) Tota l CO - Ton/To

nHCH O (377. ) 14-1 1 427,50 0 0 Absorbe r Ven

t
54,64 0 Continuou s
<•0000 1 .0007 6 .0082 9 .0012 0 .39697 5 .02101 0 .09209 6 .00012 6 .01627 1 Groun d Leve l Daily Chromatograp

h N o • Ye s 420 0 360 0 10,00 0 1 I 1 9 0 9 3 9 5 1 0 1 2 1 4 5 0 5 0 5 0 N o

.0102 5

.0210 1 14-2 0 50,00 0 50,00 0 0 Absorber Ven

t

738 6 Continuou s
.0003 5 .032 6 .0022 4

.5101 6 .0010 4 .0368 8 .0265 6 .0104 0

Rando m Calc'd . N o Ye s 1 9 5 13 2 9 5 N o

.0082 5

0 0 0 .0010 4 Dlsti11s t io n Tove r Overhea

d Ven t 3 0 Continuou s
0012 0 0012 0

Never No t Specifie

d N o
1 9 5 13 2 9 5 N o


# 1mipan y icatio n and/o rEP

A Code d Numbe r i t e on-strea m lameplate " capacit y i n shor tton s : glycero l produc tpe ryea r )proxlmst e averag e productio n rate , >n s glycero l pe ryea r asona l variatio n I n productio n rate , rcen to f

nameplat e capacit y •uplifte d flo v iscrlptlo n diagra m strea m designatio n lly l chlorid e ilorin e o-propy l alcoho l o-an d n-propy l chloride s 2 , 3 trlchloropropan e :rolel n 3 dlchloropropen e jlchlorohydrl n ceton e ite r I r yrdrocarbon , non-substitute d fo rexample , ethane , propene , butene )

' 2 3 dlchlorohydrl n TABL E G-II I NATIONA

L ATMlSPHERI C EMISSION S INVENTOR Y FO R• CI.YCF.ROl

. PIANT S USING EPICHI-OROHYDRI N AND/ORALLY

L CHLORID

E (NOT E 1 )

15- 1

47,50 0

Not e 3 Dta L Ton s pe r to no f glycero l cspaclt y 33 0 operatin g days/C y assumed ) otal , pound s pe r strea m hou r (not e 2 ) otal . SCF M

a t 60 ° F an

d 14. 7 PSIA empereture , ° F emperature , C reesurc , PSI G amplln g locatio n at e o r frequenc y

o f samplin g yp e o f Analysi s do r preaenc e

en t stack s Numbe r Height , Fee t Diameter , Inche s Temperature , Stac k exit , ° F 

### ° C Non e
B Incl' d i npropy l chloride s

0.0263 1

0.00823 8

Not e 4 0.0345 5 41 4 30 0 25 0 12 1 Atm . Not e 5

Scrubbe r Ven t On e spo t sampl e Mas s spectro . C , Chloride s

1 6 0 8 25 0 12 1 D

0.00166 5 0.00326 9

0.00153 9 0.00515 1

Not e 6 0.0116 2 14 0 2.10 0 22 0 - 24 0 10 4 - 11 6 3 - 7 Not e 7

1 10 0 8 2 3 0 11 0 Pag e 1 o f 4

Incl' d i n propy l chloride s 0.000428 3 0 00179 1 0.00168 1

0 00362 2

Not e 8 0.00752 2 9 1 5 4 15 0 6 6 Atm .

1 10 0 1 0 15 0 6 6 0.00184 0

0-0102 6

Not e 9 0.012 1 1 4 6 40 0 25 0 12 ) At m

5 vacoa m Jets / accumulato rvent * 50/3 0 4 / 2 250/20 0 121/9 3
missio n Contro l Device s Typ e Catalo g Identificatio n No. ; se e Tabl e I V ota l emission s expresse d a s tons/to n ulvcero l cspaclt y Hydrocarbo n "articulate . Aeroso l Scrubbe r 15-1-10 1

0.0345 5 Non e Non e Non e Non e Scrubbe r 15-1-10 2

0.0116 2 Non e Non e Non e Non e Scrubbe r 15-1-10 3

0.00752 2 Non e Non e Non e Non e 0 012 1 Non e Non e Non e Non e Sei - |ISI.I H i - S lhruii ( • - h lo rexplanatio n u lCompan y Locatio n and/o rEP A Code d Numbe r Dat e on-8trea m 'Nameplate " capacit y i n shor tton s o f glycero l produc tpe ryea r Approximat e averag e productio n rate . ton s glycero l pe ryea r Seasona l variatio n I n productio n rate , percen to f

nameplat e capacit y Simplifie d flo v Descriptio n diagra m strea m designatio n Ally l chlorid e chlorin e Iso-propy l alcoho l Iso-an d n-propy l chloride s 1 , 2 , 3 trlchloropropan e Acrolei n 2 , 3 dlchloropropeo e Eplchlorohydrl n Aceton e Wate r Ai r Hydrocarbon , non-substitute d (fo rexample , ethane , propene , hutene ) CO , 2 , 3 dlchlorohydri n Totel , ton s pe rto n o f glycero l capacit y (33 0 operatin g days/c y assumed ) Total , pound ape rstrea m hou r(not e 2 ) Total , SCF

N a t60 ° F an d 14. 7 PSI A Temperature , ° F Temperature , ° C Pressure , PSI G Samplin g locatio n Dat e o rfrequenc y o f samplin g Typ e o f analysi s Odo rpresenc e Ven t stack s Numbe r Height , Fee t Diameter . Inche s Temperature . Stac kexit . ° F
" C TABL E C-ll l NATIONA

L ATMOSPHERI

C EMISSION S INVENTOR Y FO R H.YCKRO L PIANT S USIN G EPICHLOROHYDRI N AND/ORALLY

L CHLORID

E (NOT E 1 )
15- 2 Pag e 2 o f 4

llypochlorina tio n ven t 0 000946 7 0.0000152 7

0.0000362 7 0.00316 5 0.0498 2

Not e 1 0 0 054 0 75 0 167. 4 8 6 - 12 2 3 0 - 5 0 0 - 3
Non e Non e Non e Chlorin e

1 7 0 8 11 3 4 5 55.00 0

Hydrollze r ven t

0.000171 7

0.0000201 5 0.00142 5 0.0228 6 C D EPI . Light s dirt'n . ven tEPI . finlshln g dlst" n ven t 0.000105 6
0.000189 4 0.0000428 4 0.00000972 0 0.0000133 2

Not e 1 1 0.0244 8 34 0 76. 4 6 9 - 10 4 2 0 - 4 0 0 - 1
No t Give n Infrequen t Flam e VP C Non e
1 4 2 4 10 4 4 0 Not e 1 2 0.0003 6 5 Amb . Amb . 0 - 1
Non e Non e Non e Non e
1 5 5 2 Amb . Amb . 0 00000288 2 0.000135 5 0.000149 9

Not e 1 3 0.00028 8 4 8 6 - 10 4 3 0 - 4 0 0 - 1
Non e Non e Non e Non e

1 5 8 2 10 4 4 0 Clycero l reacto r »e i

Trac e Trac e Majorit y

Trac e Mot e 1 4 0.00020 5 2 8 5 1 10 4 4 0 At m No t Give n Onc e VP C Non e

1 3 0 1 0 10 4 4 0

Emissio n Contro l Device s Typ e Catalo g Identificatio n No. , se e Tabl e I V Tota l emlesloi s expresse d « » tons/to n glycero l capacit y Hydrocarbo n Particulate . Aeroso l
S O le t Fum e Scrubbe r Glycero l 15-2.10 1

0 001015 , lncl . chlorin e 0.00019 5 Non e Non e Non e None Non e None Non e Se e pa , e s .-r. to r expiaua c io

no l notes . Non e 0 0003 6 Non e Non e None None 0 00013 8 Non e Non e Non e Non e None None None None None1 1 a 1 1 1 1 1



### - - - -

Compan y Locatio nand/o r EPA Code d Numbe r Dat e on-strea m "Nameplate " capacit y i nshor t ton s o f glycero l produc t pe r yea r Approximat e averag e productio nrate . ton s glycero l pe r yea r Seasona l variatio ni nproductio nrate , percen t o f nameplat e capacit y Simplifie d flo v Descriptio ndiagra m strea m

designatio n Ally l chlorid e chlorin e Iso-propy l alcoho l Tsn-an d n-propy l chloride s 1 , 2 , 3 , trlchloropropan e Acrolei n 2 , 3 dlchloropropea e Fpichlorohydrl n Aceton e Wate r Ai r Hydrocarbon , non-substitute d (fo r example , ethane , propene , butene ) CO , 2 , 3 dlchlorohydrl n Total , ton s pe r to no f glycero l capacit y (33 0 operatin g days/c y assumed ) total , pound s pe r strea m hou r (not e 2 ) Total . SCF M

a t 60° F an d 14. 7 PSI A Temperature , ° F Temperature , ° C Pressure . PSI G Samplin g Locatio n Dat e o r frequenc y o f samplin g Typ e o f analysi s Odo r presenc e
Ven t stsck s Numbe r Height. . Fee t Diameter , Inche s Temperature , Stac k exit , ° F 

### ° C Emissio nContro l Device s Typ e Catalo g Identificatio nNo. . Se e Tahli - I V 

### i • ; I. 1 . L . - 1 

### .. . i . 1 1

TABL E G-I U NATIONA L ATMOSPHERI C EMISSION S INVENTOR Y FO R GLYCERO L PIANT S USIN GEPICHLOROHYDRI N AND/O RALLY L CHLORID E (NOT E 1 )

15- 2

55,00 0

Non e F G Glycero l Evap . Ven t Glycero l Dist'n . Ven t

1007 . 1007 .

Not e 1 5 Not e 1 6
0.021 6 Unknov n 30 0 "Ver y Small " 105. 3 21 2 9 5 - 10 0 10 0 3 5 - 3 8 0 - 3 Atm . Non e Non e Non e Non e Non e Non e Non e Non e

1 N o Informatio n 4 9 1 10 4 4 0

Tota l emission s expresse d a s tuns/to nglycero l capacit y Hydrocarbo n • Particulate , aeroso l M ) , S,, x C O Se e pagr s t;- i throug h<.- H lo r i:x| > 1 iina

t i o no l no t Non e Hon e Non e Non e Non e Non e .Non e Non e Non e Non e
e S . I

_i i • m

Pag e 3 o f 4 1

I I Glycero l Ligh t Dist' nVent

1007 .

Not e 1 7
0.0360 0 50 0 175. 5 21 2 10 0 5
Non e Non e Non e Non e
supplie d

Non e

Non e Non e Non e Non e 

### - *



### -

-P.4 6



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X 

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## ^- * r t 0 3 a

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## _ ^

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TABL E HCN-lI l NATIONA

L EMISSION S INVENTOR Y HYDROGE

N CYANIDE (ANDRUSSO H PROCESS ) Pag e 1 o f 4
Plan tEP

A Cod e No . Capacit y - Ton s o f HCN/Yr . Averag e Productio n - Ton s HCN/Yr . Quarterl y Productio n Variation . 7. o f Max . Emission s t o Atmospher e Strea m

Plan tTrai n No . Flo w - Lb./Hr . Flo w Characteristic s - Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Flo w Compositio n - Tons/To n o f Hydroge n Cyanid e Methan e Ammoni a Nitroge n Oxyge n Hydroge n Hydroge n Cyanid e Carbo nDioxid e Carbo nMonoxid e Wate r Sampl e Ta p Locatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analyst s Odo r Proble m Ven t Stack s Flo w - SCFM/Stac k Numbe r Heigh t - Fee t Diamete r - Inche s Exi t Ca a Temperature , ° F Emissio nContro l Device s Typ e - Incinerato r

Flar e Scrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To n Hydroge n Cyanid e Tota l Particulate s 4 Aeroso l - Ton/To n Hvdro^e n Cyanid e Tota l Nn . I" } - Ion/To n Hydroie n Cyanid e Tota l SC V• - Ton/To n liydru i i-n Cyanid e Tota l C

O (.mission s Ion/To n ilvclro.c n Cvani.U Produc tRecover y & Purificatio n Sectio n Off-Ga s (Ai rHeate rFuel ) 1 5,35 0 Con tinuou s

.140 8

.050 5 .047 7 Non e Neve r Calc'd
. ( 1 ) 125 0 1 8 5 5 4

A i r Heate r HN- 1 0 0 .0000 2 (8 ) D I I 16- 1 83,00 0

Start-U p an d Emergenc y Fee d Ca s Ventin g I 21,60 0 Intermitten t 1 6

.539 6

.179 4 .246 8 Non e Neve r Calc'd
.
525 0 1 76. 5 2 4 ?

Ye s Start-U p & Emergenc y Reacto rEffluen t & Continuou s Proces s Tan k4 Off-Ga s Vent s 1 112,90 0 Intermitten t 4 8

(3 )

Non e Neve r Calc'd . No tApplicabl e 27,40 0 1 76. 5 2 4

HN- 2 0 0 .00 9 0 0 ( 3 ) (8 ) IIN- 3 0 0 .00 6 0 0 Proces s Tsn k ; Proces s off-C i Vent s 1 95.20 0 Continuou s

3.202 2

.419 3 .629 0
Non e Neve r Calc'd .
22,55 0 1 76. 5 2 4

'3 ) (8 ) Ye s

HN- 3 0 0 .000 1 (8 ) 0 0

J > ^ 1TABLE HCN-II I NATIONA

L EMISSION S INVENTOR Y HYDROGE

N CYANIDE (ANDRUSSO W PROCESS ) Pag e 2 o f 4
Plan t EP A

Cod e No . Capacit y

- Ton s o f HCN/Yr . Averag e Productio n- Ton s HCN/Yr . Quarterl y

Productio nVariation , 7 o f Max . Emission s t o Atmospher e S t rea m

Plan t Trai nNo . Flo w - Lb./Hr . Flo w Characteristic s - Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr . Flo w Compositio n- Tons/To no f Hydroge nCyanid e Methan e Ammoni a Nitroge n Cvyge n Hydroge n Hydroge nCyanid e Carbo nDioxid e Carbo nMonoxid e Wate r Sampl e Tap Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s OdorProble m Ven tStack s Flo w - SCFM/Stac k Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temperature , ° F Emissio n Contro l Device s Typ e - Incinerato r Flar e Scrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To n Hydroge n Cyanid e Tota l Particulate s i > Aeroso l - Ton/To n Hydroge n Cyanid e Total ' N O (8 ) - Ton/To n Hydroge n Cyanid e Tota l S0 „ - Ton/To n Hydroge n Cyanid e Tota l C O F.mlsaion s - Ton/To n llvdroge n Cyanid e Proces s Sampl e Po t Vent s 1 296,00 0 Continuou s

10.149 3 3.066 0 .000 6

Accessibl e Veekl y GL C No 65.00 0 1 15 0 6 0 Ambien t Non e

.000 6 < 4 > 0 0 0 0 16- 1 83.00 0 0 Produc tRecover y & Purlficstio n Sectio n Off-Ga s (Ai rHeate rFuel ) 2 137.00 0 Continuou s

3.604 2

1.292 7 1.221 0
Non e Neve r Calc'd .
16,00 0 (

5 ~> 2

Ai r Heate r Proces s Off-Ga s Ven t 2 1 7 80 0 Continuou s

.597 7

.000 6 Ye s

HN- 4 0 (6 ) 0 .0000 4 0 0 Proces s Tan k i > Proces s Off-Ga s Vent s 2 6 . 3 48.70 0 Continuou s

1.636 7

.078 3 .117 4
Non e Neve r Calc'd . No t Applicabl e 4.20 0 1 7 4 2 4 .214 3 .321 5
Non e Neve r Calc'd . No t Applicabl e 11,50 0 1 11 0 4 8

HN- 5 0 0 .0000 5 0 0I - »

TABL E HCn-II I NATIONA

L EMISSION S INVENTOR Y HYDROGE

N CYANID

E (ANDRUSSO

W PROCESS ) Pag e 3 o f 4

m tEP A Cod e No . laclt y - Ton s o f

HCN/Yr . irag e Productio n - Ton s HCN/Yr . irterl y Productio n Variation , 7 . o f Max . sslon s t o Atmospher e Strea m

Plan tTrai n No . Flo w - Lb./Hr . Flo w Characteristic s - Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Flo w Compositio n - Tons/To n o f Hydroge n Cyanid e Methan e Ammoni a Nitroge n Oxyge n Hydroge n Hydroge n Cyanid e Carbo n Dioxid e Carbo n Monoxid e Wate r Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProble m m tStacka . Flo w - SCFM/Stac k Numbe r Heigh t- Fee t Diamete r- Inche s Exi tCa s Temperatur e - ° F salo n Contro l Device s Typ e - Incinerato r

Flar e Scrubbe r Othe r Catalo g I . D . Numbe r ota l Hydrocarbo n Emlsalon s - Ton/To n Hydroge n Cyanid e ota l particulate s 4 Aeroso l - Ton/To n Hydroge n Cyanid e ota l N O (8 ) - TonATo n Hydroge n Cyanid e ota l S0 „ - Ton/To n Hydroge n Cyanid e ota l C O Emission s - Ton/To n Hydroge n Cyanid e Start-U p o rEmergenc y Feed-Ga s Relie f 4 Continuou s Proces s Tan k& Proces s Off-Ga s Vent s 2 66,30 0 Intermitten t 1 2



### + + Non e Neve r Calc'd . < 6 > No tApplicabl e 15,90 0 1 11 0 4 8

Ye s

HN- 5 0 (<> ) 0 . 0 2 0 0 (3 ) (8 ) 16- 1 83.00 0

Start-U p o rEmergenc y Fee d Ga s Relie f & Continuou s Proces s Tan k4 Proces s Off-Ga s 3 66.30 0 Intermittent 8

+ 

### + Non e Neve r Calc'd . < 6 > Not Applicabl e 15,90 0 1 11 0 4 8

HN- 5 0 (6 ) 0 .0 2 0 0 O ) (8 ) Start-U p o r Emergenc

y Reacto r Effluen

t Relie f &

, Continuou s Proces s Tsn k ( • Proces s Off-Ga s Vent 6 2 66.40 0 Intermitten

t 4 0

Non e Neve r Calc'd . (6 ) No t Applicabl e 16,40 0 1 11 0 4 8

HN- 5 0 0 .00 6 (3 ) (8 ) 0 0,_ J

TABLE HCN-II I NATIONA L EMISSION S XNVENTOR Y HYDROGE

N CYANIDE (ANDRUSSO W PROCESS ) Pag e 4 o f 4

an tEP A Cod e No . pecit y - Ton s o f

HCN/Yr . erag e Productio n - Ton s HCN/Yr . tarterl y Productio n Variation , 7 o f ilsslon s t o Atmospher e Strea m

Plan tTrai n No . Flo w - Lb./Hr . Flo w Characteristic s - Continuou s o rintermitten t I f Intermitten t- Hrs./Yr . Flo v Compositio n - Tons/To n o f Hydroge n Cyanid e Methan e Ammoni a Nitroge n Oxyge n Hydroge n Hydroge n Cyanid e Carbo n Dioxid e Carbo n Monoxid e Wate r Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProble m Ven tStack s Flo w - SCFM/Stac k Numbe r Heigh t- Fee t Diamete r- inche s Exi tGa s Temperatur e - ° F Emissio n Contro l Device s Typ e - Incinerato r

Flar e Scrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emission s - ion/To n Hydroge n Cyanid e Tota l Particulate s 4 Aeroso l - Ton/To n Hydroga i Cysnid e Tota l N0 X (8 ) - Ton/To n Hydroge n Cyanid e Tota l SO x- Ton/To n Hydroge n Cyanid e Tota l C

O Emission s - Ton/To n Hydroge n Cyanid e 16- 1 83,00 0

Start-U p o r Emergenc y Reacto rEffluen tRelie f & Continuou s Proces s Tan kt. Proces s Off-Ga s Vent s 3 66,40 0 Intermitten t 2 4

Non e Neve r Calc'd
. (6 ) No t Applicabl e 16,40 0 1 11 0 4 8

HN- 5 0

0 00 6 < 3 > < 8 > 0 0 Proces s Sampl e Po t Vent s
296,00 0 Continuou s

10.149 3 3.066 0 .000 6

Accessibl e Weekl y GL C N o 65.00 0 1 15 0 6 0 Ambien t Non e

000 6 <* ) 0 0 0 0 Proces s Ssmpl e Po t Vent s 3 18.20 0 Continuou s

624 6 .188 7 .0000 4

Non e Neve r Calc' d No 4.00 0 2 (alternating ) 12 0 1 6 Ambien t Non e

0000 4 (4 )

T J b i

## i
. - 

# . - iPlan tEP

A Cod e No . Capacit y Ton s Isocyanates/Yr . Rang e o f

Productio n - 7. o f Max . Emission s t o Atmospher e Strea m Flo w - Lb./Hr . (SCFM ) Flo w Characteristi c - Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr . Composition - Ton/Ton I so . Hydrocarbon s Nitroge n (Air ) C O CO 2 Stea m C0C1 2 -Phosgen e Chlorinated Hydrocarbon s HC 1 Anilin e Isocyanate s H 2 S , SO, , Particulate s Ven tStack s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tGa s Temperatur e - K ° SCFM/Stac k Emissio n Contro l Device s TABLE TDI-II I NATIONAL EMISSION S INVENTOR Y ISOCYANATE S

Phosgen e Decompose rVen tGa s Psg e 1 o f 5 17- 1 100,00 0 0 Residu e Ga s Scrubbe rVen t (9000 ) Continuou s

0.01621 2 0.00562 8 0.00880 0 0.00029 6 0.00243 1 N o Dat a

1 72 5 1 2 21 2 100 0 Scrubbe r 1 70 0 6 7 0 ? Scrubbe r Analysi s Dat e o rFrequenc y o f Samplin g Ta p Locatio n Typ e o f

Analysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbon s - Ton/To n I s o Aerosol s - Ton/To n Iso . N0 X - Ton/To n Iso . S0 X- Ton/To n Iso
. C O - Ton/To n Iso . Onc e pe ryea r I n Stac k GC , I R N . C . N . C . 0 00243 1 0.00029 6

0.00562 8

c nL_
.

TABL E TDI-II I NATIONA

L KHlSSION KINVENTOR Y

Plan tEP

A Cod e No . Capacit y Ton s Isocyanates/Yr . Rang e o f

Productio n - 7 . o f Max . Emission s t o Atmospher e Strea m

Flo w - Lb./Hr . (SCFM ) Flo v Characteristi c- Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Compositio n - Ton/To n Iso . Hydrocarbon s Nitroge n (Air ) C O CC 7 Stea m COCl , - Phosgen e Chlorinate d Hydrocarbon s HC 1 Anilin e Iaocyanate s HjS , S0 X Particulate s ven tStack s Numbe r Heigh t- Ft . Dlaamte r- Inche s Exi tCa s Temperatur e - F ° SCFM/Stac k Emissio n Contro l Device s Analysi s Dat e o rFrequenc y o f Samplin g Ta p Locatio n Typ e o f

Analysi s Odo rProble m sr y o f Ai rPollutant s Hydrocarbon s - Ton/To n Iso . Aerosol s - Ton/To n Iso . NO , - Ton/To n Iso . S0 „ - Ton/To n Iso . CO - Ton/To n Iso
. Phosgen e Decompose r Ven tGa s ( 8 ) Continuou s ISOCYANATE S

HC1 Absorbe r (27 ) Continuou s 17- 2 20.00 0 

## ± 8

TD I Scrub b (28 ) Continuou s

0.00020 0 0.01156 0 0.00640 0 0.02980 0

1 4 5 3 12 5 8 Scrubbe r

Occasiona l I n Stac k G C No Pap e 2 o f 5

Residu e Cat

s Scrubbe rVen t (870 ) Continuou s

0.02423 4 0.84334 3

1 5 0 4 10 0 2 7 Absorbe r

Neve r

N o 1 7 0 6 10 0 2 8 Scrubbe r
Occasiona l I n Stac k G C N o Neve r Est . N o C O Furnac e Purg e Ven t (180 ) Intermitten t

T R 0.26676 0 CO , Remova l

Regenerato r Vent (414 ) Continuou s

T R

1 1 2 8 8 0 87 0 Scrubbe r 1 9 8 8 1 0 Non e

Neve r
Est . N o 0 23657 1

T R

1 6 6 4 25 0 30 9 Non e

Occasiona l
We t N o

T R T R

c n r otEP A Cod e No . cit y Ton s Iaocyanates/Yr . e o f Productio n - 7. o f Max . slon s t o Atmospher e Strea m

Flow - Lb./Hr . (SCFM ) Flo w Characteristi c - Continuou s or Intermitten t I f Intermitten t - Hrs./Yr . Compositio n- Ton/To nIso . Hydrocarbon s Nitroge n(Air ) C O CO j Stea m COCI 2 - Phosgen e Chlorinate d Hydrocarbon s HC 1 Anilin e Isocyanate s HjS , S O particulate s Ven t Stack a Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ca s Temperatur e - F ° SCFM/Stac k Emissio nContro l Device s Analysi s Dat e o rFrequenc y o f Samplin g Ta p Locatio n Typ e o f

Analysi s Odo rProble m t r y o f Ai rPollutant s Hydrocarbon s "

—''*•"• '

Ton/To n Iso . Aerosol a- Ton/To n Iso . NO , - Ton/To n Iso . TABL E TDI-II I NATIONA

L EMISSION S INVENTOR Y ISOCYANATES 17- 3 33,50 0 0 pag e 3 o f 5

Phosgen e Decompose r Ven tGa s 115 1 Continuou s

0.00354 8 0.01175 9 0.10136 8 T R

N o Dat a

Scrubbe r

N o MD I Fum e Scrubbe rVen t 208 0 Continuou s

1.0208 8

T R

N o Dat a

Scrubbe r

N o Distillatio n

Scrubbe rVen t 22 3 Continuou s

0.01165 7

0.01084 6

0.00002 3

N o Dat a 1 1 • *
n i t 1 1 n

• 1 • * Scrubbe r

N o 0.00002 3 T R
0.01175 9 Phosgen e Decompose r

Ven t Ga s (22 ) Continuou s 17- 8 15.50 0 0

TD I Scrubbe r Ven t 24 2 Residu e Incinerato r Ven t (8300 )

0.02129 2

T R 0.00665 4

C O - Ton/To n Iso . Ton/To n lao . 1 5 5 6 15 0 7 Scrubbe r

N o 0.05865 0

1 7 6 4 12 5 7 Scrubbe r

N o 8.2867 2 0.69513 7 0.33849 5

T R

N o Dat a

Incinerato r

N o 0.00665 4

0.71642 9Plan tEP

A Cod e No . Capacit y Ton s Isocyanates/Yr . Rang e o f

Productio n - 7

. o f Max . Emission s t o Atmospher e Strea m

Flo w - Lb./H r(SCFM ) Flo w Characteristi c- Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Compositio n - Ton/To n Iso . Hydrocarbon s Nitroge n (Air ) C O CO 2 Stea m COCl , - Phosgen e Chlorinate d Hydrocarbon s HC 1 Anilin e Iaocyanate s H 2 S , S O particulate s Ven tStack s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tGa s Temperatur e - F ° SCFM/Stac k Emissio n Contro l Device s Analysi s Dat e o rFrequenc y o f Samplin g Ta p Locatio n Typ e o f Analysi s Odo rProble m
• r y o f Ai rPo l Intent s Hydrocarbon s - Ton/To n Iso . Aerosol s - Ton/To n Iso . N0 X - Ton/To n Iso . S O - Ton/To n Iso . C O - Tpn/To n Iso
. 17- 4 13,00 0 0 Mi l Recover y Uni tVen t (50 ) Intermitten t 67 5 est .
0.00487 5

0.00014 1 0.00004 4 0.00015 0
T R
I 5 0 2 Ambien t 5 0 Non e

Neve r Non e Estimat e Ye s 0.00029 1 0.00004 4 TABL E TDI-II I NATIONA

L EMISSION S INVENTOR Y ISOCYANATE

S 17- 9 85,00 0 0

Reacto r Ven t 10 0 Continuou s

0.00351 7 0.00008 5 0.00063 6
T R

I Groun d 1 0 110 °
Non e

Neve r Non e Estimat e Ye s Amin e Scrubbe r Ven t

120 0 Continuou s

0.40678 0

0.14406 8

T R

1 5 0 6 110 ° Scrubbe r

Neve r Non e Estimat e Ye s 0.00029 1 0.00004 4 Reacto rVen t (375 ) Continuou s

0.02144 2 0.04951 3 0 18596 5 Peg e 4 o f 5 17- 6

20,00 0 + 8 , - 1 6 Phosgen e Destructio n Reacto rCond . Ven tUni tOff-Ga s (39.5 ) Continuou s

T R 0.02787 5

0.00526 3 (1833 ) Continuou s
0 04132 6 1 61442 5

0 06218 3

1 17 5 1 8 2000 ° Flar e

Neve r Non e Calcul a N o te d 1

Groun d 3 ' x 5 ' 130 ° Non e

Neve r I n Lin e Calculate d Ye s 1 13 0 12 " 102 ° Scrubbe r

Neve r Non e Calculate d N o Tnc i nerato r Stac k Ca s (9000 ) Interm i tren t

T R 8.50760 2 0.11501 0 0 02495 1

TR

Groun d 8 ' x8 '

Pi t Incinerstu i

Neve r Non e Calculate d Ye s 0 04132 6 

# ITABL E TDI-II I NATIONA

L EMISSIONSTKVENTOR Y ISOCYANATES Pag e 5 o f 5 lent EP A

Cod e No . apacit y

Ton s lsocyanates/ v r . ang e o f Productio n- 'I. o f Max . aiaaion a t o Atmospher e Strea m

Flow - Lb./Hr . 'SCFM ) Flow Characteristi c - Continuou s or Intermitten t I f Intermitten t - Hrs./Yr . Compositio n- Ton/To nIso . Hydrocarbon s Nitroge n(Air ) C O
Staa m C0C1 2 - Phosgen e Chlorinate d Hydrocarbon s HC l Anilin e Isocyanate a HjS . S O particulate s Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche e Exi t Ga s Temperatur e - F ° SCFM/Stac k Emissio nContro l Device s Analysi s Dat e o rFrequenc y o f Samplin g Ta p Locatio n Typ e o f

Analysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbon s - Ton/To n Iso . Aerosol s - Ton/To n Iso . N0 X - Ton/To n iso . S O - Ton/To n Iso . C O - Ton/To n Iso . 17- 7 52,50 0 0

Plan tScrubbe rStac k (10,000 ) Continuou s

4.10312 0 0.01042 9

0.00008 3

TR Residu e Ven t Ga s (200 ) Continuou s

0.00241 9

0.04755 5

0.00008 3

2 16 0 30 " Ambien t 500 0 Scrubbe r

Continuou s I nLin e Calc' d Ye s for C0C1 2 4 6 0 4 " 200 ° 5 0 Non e

Neve r Non e Est . Ye s

0.00016 6

0.01042 9 Plan t Flar e 100 0 Continuou s (Calc'd. ) 0.12631 6 0.00321 1 0.00092 1 (Cl 2 ) 0.00131 6

1 11 0 1 1600< > Scrubbe r4 Incinereto r

Neve r Non e Calc'd . N o 17-1 0 30.00 0 0
TD I Reacto r Emergenc y

Ven t 60 0 Intermitten t 8 0.00000 2 0.00007 0

0.00000 6 0.00000 1

0.00000 1 Residu e Gs s Ven t 25 0 Cont i nuou s

0.00618 4 0.00049 3 0 02631 6 T R TR T R HC l Neu l . Off-f.s s 22.87 6 Con t i nuou s

2.6939 4 7 0.25881 6 0 06013 2

0 00121 0

1 6 0 2 " 212 ° Non e 1 8 0 2 " 120 ° Non e

Neve r Non e Calc'd . N o Neve r Non e Calc' d Ye s 0.00009 2

3 2 0 10 " 100 ° Limeston e Neu t. Neve r Non e Calc' d Ye s 0.00000 2 0 00344 8 0 00009 2