P.1 

OAR Box 1670 

Prepped by Charmelle Mathews 

Document Number: 

S"? ^S5 ll-D-169 

Docket Number: 

A-98-13 

Printed 9/24/2008 11:55:14 AM Sheet 38 of 56 
P.2 

PAKTANK CORPORATION 

August 17, 1998 

2000 West Loop South, Suite 2200 

Houston, Texas 77027-3597 

(713) 623-0000 

FAX: (713) 623-4480 

E-Mail: paktank@pakhoedcorp.com 

FILE COP 

wfpsUfs 

Bruce C. Jordan, Director 

Emission Standards Division (MD-13) 

Office of Air Quality Planning and Standards 

U.S. Environmental Protection Agency 

Research Triangle Park, NC 27711 

Attention: Stephen Shedd 

RE: Paktank Corporation - Deer Park Terminal 

O.L.D. Survey 

Dear Mr. Jordan: 

Please find enclosed a completed O.L.D. survey for Paktank Corporation - Deer Park 

Terminal. 

Should you have any questions regarding the survey, please call Thomas Land or me at 713-

623-0000. 

Very truly yours, 

-fa 6 *»»o , 

,^4-, Quirino Q. Wong 

Manager, Environmental Affairs 

On behalf of Paktank Corporation - Deer Park Terminal 

QQW/TDL:rmm 

/ 
P.3 

Bruce C. Jordan, Director 

Emission Standards Division (MD-13) 

Office of Air Quality Planning and Standards 

U.S. Environmental Protection Agency 

Research Triangle Park, NC 2711 

Attention: Stephen Shedd 

IT. GENERAL INFORMATION 

A. Name of legal owner of plant: Paktank Corporation DeerPark Terminal 

B. Is the company publicly or privately owned? Privately 

C. Name of legal operator of the plant, if different from legal owner: Same 

D. Address of legal owner/operator: 2759 Battleground. Deer Park Texas. 77536 

E. Size of company/plant: 

1. Approximate number of employees of the business enterprise that owns this plant, 

including where applicable, the parent company and all subsidiaries, branches and 

unrelated establishments owned by the parent company: \___ 

2. Total number of employees of the business enterprise that operates this plant: 112 

3. a) Number of employees at the entire plant site. 119 

b) Number of employees associated with the organic liquid distribution operations 

at this plant: 82 

c) Number of organic liquids distribution operations employees that are contract 

employees._5 

F. Name of plant: Paktank Corporation - Deer Park Terminal 

G. Street address of plant: 2759 Battleground Rd 

City, State, Zip code: Deer Park Texas. 77536 

H. Dun and Bradstreet number: 19-875-2784 

I. Latitude and Longitude coordinates of plant: 29 degrees. 44 minutes. 30 seconds. North 

97degrees. 5 minutes. 30 seconds. East. 

Z_ 
P.4 

J. Name of contact able to answer technical questions about the complete survey: 

Thomas Land 

Environmental Specialist 

713-623-0000 

David Carter 

Environmental Supervisor 

281-479-6051 

2> 
P.5 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Benzene 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 1.53 (a). 70 F 

b. Density (lb/gal): 7.365 

c. Reid Vapor Pressure (psia): 3.22 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 78 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): _____ 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Benzene 

CAS No. 

71-43-2 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 
P.6 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Ethyl Benzene 

II. Properties ( use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 0.15 @. 70 F 

b. Density (lb/gal): 7.259 

c. Reid Vapor Pressure (psia): (____ 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 106.17 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Ethylbenzene 

. 

' 

i 

CAS No. 

100-41-4 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

t> 
P.7 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name Co) Ethylene Glycol 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 

b. Density (lb/gal): 

c. Reid Vapor Pressure (psia): 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): 

III. HAPS Constituents (of the organic liquid listed above): 

0.008 @. 70 F 

9.257 

0.008 

62 

NA 

HAP Constituents (c) 

Ethylene glycol 

CAS No. 

107-21-1 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

& 
P.8 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Methy Ethyl Ketone 

II. Properties ( use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 1.46 (g). 70 F 

b. Density (lb/gal): 6.712 

c. Reid Vapor Pressure (psia): U_ 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 22 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA. 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Methyl ethyl ketone 

CAS No. 

78-93-3 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

^ 
P.9 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Methyl Alcohol 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 1.97 (a). 70 F 

b. Density (lb/gal): 6.63 

c. Reid Vapor Pressure (psia): 4.5 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 32.04 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA. 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Methyl Alcohol 

CAS No. 

67-56-1 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 
P.10 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) MIBE 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 4.63 @. 70 F 

b. Density (lb/gal): 6.213 

c. Reid Vapor Pressure (psia): 2___ 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): MA 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Methyl tert butyl ether 

CAS No. 

1634-04-4 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

9 
P.11 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Paraxylene 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 

b. Density (lb/gal): 

c. Reid Vapor Pressure (psia): 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): 

III. HAPS Constituents (of the organic liquid listed above): 

0.13 @ 70 F 

7.17 

0.34 

106.17 

NA 

HAP Constituents (c) 

Paraxylene 

CAS No. 

106-42-3 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

JO 
P.12 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Propylene Oxide 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 9.18 (g). 70 F 

b. Density (lb/gal): 6.9696 

c. Reid Vapor Pressure (psia): 16.66 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 58.08 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Propylene Oxide 

CAS No. 

75-56-9 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

; / 
P.13 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Styrene Monomer 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 0.1 (g). 70 F 

b. Density (lb/gal): 7.587 

c. Reid Vapor Pressure (psia): 0.27 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 145.14 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Styrene Monomer 

CAS No. 

100-42-5 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

)?-
P.14 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Toluene 

II. Properties ( use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 0.45 (g>. 70 F 

b. Density (lb/gal): lf___ 

c. Reid Vapor Pressure (psia): 1.29 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 92.14 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): HA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Toluene 

CAS No. 

108-88-3 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

13 
P.15 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Vinyl Acetate 

II. Properties ( use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 1.73 @, 70 F 

b. Density (lb/gal): 7.822 

c. Reid Vapor Pressure (psia): 3.977 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 86.04 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Vinyl Acetate 

CAS No. 

108-05-4 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

4 
P.16 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Xylene 

II. Properties ( use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 0.13 @.70F 

b. Density (lb/gal): 7.251 

c. Reid Vapor Pressure (psia): 0.2707 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 106.17 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Xylene 

CAS No. 

1330-20-7 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

lt> 
P.17 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Aromatic 200 Solvent 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 

b. Density (lb/gal): 

c. Reid Vapor Pressure (psia): 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): 

III. HAPS Constituents (of the organic liquid listed above): 

0.134(g). 70 F 

8.206 

0.2348 

70 

NA 

HAP Constituents (c) 

Naphthalene 

CAS No. 

91-20-3 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

l(J> 
P.18 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Aromatic 150 Solvent 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 

b. Density (lb/gal): 

c. Reid Vapor Pressure (psia): 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): 

III. HAPS Constituents (of the organic liquid listed above): 

0.206 @. 70 F 

7.42 

0.50 

142 

NA 

HAP Constituents (c) 

Naphthalene 

CAS No. 

91-20-3 

Average Liquid 

Weight % 

100% 

Average Vapor 

L_ Weight % 

l^h 
P.19 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Steam Cracked Naphtha 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 

b. Density (lb/gal): 

c. Reid Vapor Pressure (psia): 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): 

0.68 @. 70 F 

7.339 

2.3680 

111 

NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Benzene 

Styrene 

Xylene 

Toluene 

Naphthalene 

Ethylbenzene 

CAS No. 

71-43-2 

100-42-5 

1330-20-7 

108-88-3 

91-20-3 

100-41-4 

Average Liquid 

Weight % 

Average Vapor 

Weight % 

'8 
P.20 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Hypalon Solvent 

II. Properties ( use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 1.76 (g>. 70 F 

b. Density (lb/gal): 13.218 

c. Reid Vapor Pressure (psia): 3.9370 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 154 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Carbon Tetrachloride 

Chloroform 

CAS No. 

56-23-5 

67-66-3 

Average Liquid 

Weight % 

Average Vapor 

Weight % 

19 
P.21 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Reformate 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 2.85 @. 70 F 

b. Density (lb/gal): 7.506 

c. Reid Vapor Pressure (psia): 4,5 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): H I 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): NA 

III. HAPS Constituents (of the organic liquid listed above): 

HAP Constituents (c) 

Benzene 

Toluene 

Xylene 

CAS No. 

71-43-2 

108-88-3 

1330-20-7 

Average Liquid 

Weight % 

Average Vapor 

Weight % 

20 
P.22 

TABLE 1. ORGANIC LIQUIDS HANDLED AND HAPS CONTENT(a) 

(SURVEYED LIQUIDS) 

I. Organic Liquid Name (b) Naphtha Reformate 

II. Properties (use the same reference temperature for a. and b., and indicate temperature.) 

a. Average True Vapor Pressure (psia): 

b. Density (lb/gal): ' 

c. Reid Vapor Pressure (psia): 

d. Liquid Molecular Weight (lb/lb-mol @ 70 F): 

e. Vapor Molecular Weight (lb/lb-mol @ 70 F): 

III. HAPS Constituents (of the organic liquid listed above): 

2.851(g), 70 F 

6.83 

4.0 

78 

NA 

HAP Constituents (c) 

Benzene 

CAS No. 

71-42-2 

Average Liquid 

Weight % 

100% 

Average Vapor 

Weight % 

ZA 
to 

1" 1 

Tank ID 

Code 

(a) 

303 

302 

403 

404 

405 

406 

407 

408 

500 

501 

502 

504 

506 

506 

510 

511 

512 

513 

514 

315 

520 

525 

527 

531 

538 

Tank Capacity 

(gal) 

(b) 

504000 

504000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

1260000 

1260000 

1260000 

1260000 

1260000 

Name(s) of Stored 

Liquid(s) 

(c) 

Aromatic 100 

Aromatic 150 

MTBE 

MTBE 

MTBE 

MTBE 

MTBE 

MTBE 

Methyl Alcohol 

Methyl Alcohol 

Methyl Alcohol 

Benzene 

Reformate 

MTBE 

Toluene 

Paraxylen 

Benzene 

Benzene 

Benzene 

Benzene 

Methyl Ethyl Ketone 

Toluene 

Xylene 

Vinyl Acetate 

Vinyl Acetate 

TABLE 2. 

Annual 

Throughput 

(gal/yr) 

(d) 

331990 

335895 

49080527 

41820541 

36689000 

41155451 

38937780 

35285733 

19485626 

5047202 

15342259 

9737653 

2054782 

2054782 

16568860 

2813832 

50769662 

36142182 

41598231 

33124375 

8528284 

17711777 

10376796 

3411885 

10762151 

STORAGE TANK CONTROL DATA 

Roof 

Configuration 

(e) 

FXR 

FXR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

FXR 

IFR 

IFR 

Floating Roof 

Tank Only: 

Seal Type 

ffl 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

Tank Roof Fittings 

(g) 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

Add-on 

Control 

Device 

(h) 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

Applicable Air 

Regulations 

(i) 

k 

k 

k 

k 

k 

k 

k 

kb 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

k 

See end of table for footnotes. 
TABLE 2. STORAGE TANK CONTROL DATA (CONTINUED) 

01 

Tank ID 

Code 

(a) 

600 

601 

602 

603 

606 

607 

608 

612 

614 

615 

719 

719 

720 

736 

737 

776 

784 

787 

790 

791 

792 

816 

908 

910 

911 

Tank Capacity 

(gal) 

(b) 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

3360000 

1260000 

1260000 

2310000 

2310000 

2310000 

1260000 

1260000 

504000 

1260000 

1260000 

1260000 

2310000 

2310000 

1260000 

1260000 

1260000 

1260000 

Name(s) of Stored 

Liquid(s) 

(c) 

MTBE 

MTBE 

MTBE 

MTBE 

MTBE 

Steam Cracked Naphtha 

Xylene 

MTBE 

Aromatic 150 

Aromatic 200 

Reformate(Sweet Benzene) 

Xylene 

Refonnate (Sweet Benzene) 

Ethyl Benzene 

Ethylene Glycol 

Toluene 

Styrene Monomer 

Styrene Monomer 

Refonnate (Sweet Benzene) 

Styrene Monomer 

Styrene Monomer 

Xylene 

Methyl Alcohol 

Aromatic 150 

Ethyl Benzene 

Annual 

Throughput 

(gal/yr) 

(d) 

31064234 

31565064 

25973387 

28408282 

8224750 

11665281 

11869498 

447452 

3629287 

1168069 

3345717 

2222532 

2115226 

996250 

741106 

383459 

10082425 

5063613 

728259 

1996544 

28340054 

2271561 

877400 

3040437 

2694761 

Roof 

Configuration 

(e) 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

IFR 

FXR 

IFR 

IFR 

FXR 

FXR 

IFR 

FXR 

FXR 

FXR 

IFR 

FXR 

FXR 

Floating Roof 

Tank Only: 

Seal Type 

(0 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

VM3 

Tank Roof Fittings 

(g) 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

GPSWSGN 

Add-on 

Control 

Device 

(h) 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

N 

Applicable Air 

Regulations 

(0 

k 

k 

k 

k 

k 

k 

k 

kb 

kb 

kb 

ka 

ka 

ka 

ka 

ka 

ka 

ka 

ka 

ka 

ka 

ka 

kb 

kb 

kb 

kb 

See end of table for footnotes. 
1 

Tank ID 

Code 

(a) 

912 

913 

918 

920 

Tank Capacity 

(gal) 

(b) 

1260000 

1260000 

2310000 

2310000 

TABLE 2. STORAGE TANK CONTROL DATA (CONTINUED) 

Name(s) of Stored 

Liquid(s) 

(c) 

Ethyl Benzene 

Propylene Oxide 

Methyl Ethyl Ketone 

Methyl Alcohol 

Annual 

Throughput 

(gal/yr) 

(d) 

1613137 

46106351 

1255044 

17797940 

Roof 

Configuration 

(e) 

FXR 

IFR 

IFR 

IFR 

Floating Roof 

Tank Only: 

Seal Type 

ffl 

VM3 

VM3 

VM3 

Tank Roof Fittings 

(g) 

GPSWSGN 

GPSWSGN 

GPSWSGN 

Add-on 

Control 

Device 

(h) 

N 

N 

N 

N 

Applicable Air 

Regulations 

(0 

kb 

kb 

kb 

kb 

-

See end of table for footnotes. 
Organi

c Liquid 

Transferred 

Through Facility 

(a) 

Aromatic 150 

Aromatic ISO 

Aromatic 150 

Aromatic 150 

Aromatic 150 

Aromatic 150 

Aromatic 200 

Benzene 

Benzene 

Benzene 

Carbon Tetrachloride 

Ethyl Benzene 

Ethyl Benzene 

Ethyl Benzene 

Ethyl Benzene 

Ethylene Glycol 

Methy Ethyl Ketone 

Methy Ethyl Ketone 

Methy Ethyl Ketone 

Methy Ethyl Ketone 

Melhy Ethyl Ketone 

Methyl Alcohol 

Methyl Alcohol 

Methyl Alcohol 

Methyl Alcohol 

Methyl Alcohol 

Methyl Alcohol 

Methyl Alcohol 

MTBE 

MTBE 

MTBE 

MTBE 

Naphtha Refonnate 

Naphtha Reformate 

Naphtha Reformate 

Naphtha Refonnate 

Paraxylene 

Paraxylene 

Incoming Type 

of Transport 

Vehick or 

Container 

(b) 

RC, BG. TS, TT 

RC, BO, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC,TT 

PL, BG, TS 

PL, BG, TS 

PL, BG, TS 

RC,TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS 

RC, BG, TS 

RC, BG, TS 

RC, BG, TS 

BG.TS 

BG.TS 

BG.TS 

BG,TS 

RC, BG, TS, TT 

RC, BG, TS, TT 

Loading 

Rack ID 

Code 

<e) 

SD1 

BD1 

SD2 

ST7 

ST22 

ST13 

ST7 

BD1 

SD1 

SD2 

ST20 

ST22 

BD5 

BDS 

SD3 

SD2 

SD2 

BD1 

SD1 

STI 

ST4 

SD3 

BD6 

BDI 

SD1 

ST6 

SD2 

ST22 

SD1 

BD2 

SD2 

ST9 

BDS 

BD6 

SD3 

BDI 

SD1 

BDI 

Loading 

Aran 

ID Code 

(d) 

LN25 

LN25 

LN25 

LN5 

LN26 

LN3 

LN4 

LN5 

LN4 

LN62X 

LN7 

ST22-19 

LN106 

LN106 

LN106 

LN62X 

LN62X 

LN34 

LN34 

LN8 

LN11 

LN1 

LN1 

LN1 

LN1 

LN6 

LN62X 

LN37 

LN7 

LN7 

LN7 

LN2 

LN84 

LN84 

LN84 

LN84 

t_N17 

LN17 

Outgoing 

Type of Transport 

Vehicle or 

Container TS BG TS 

TT,RC TT 

TT.RC 

TT.RC BG TS TS TT TT BG BG TS TS TS BG TS TT TC TS BG BG TS TC TS TC TS BG TS TC BG BG TS BG TS BG 

Annual Volume 

of Transferred 

Liquid 

(gal/yr) 

976849 

766704 

90246 

1761489 

3484255 

558712 

28349 

7,503,830.00 

5,437,419.00 

419,653.00 

86,970.00 

9,464.00 

404,369.00 

3,251,299.00 

1,164,175.00 

738,040.00 

429,526.00 

473,549.00 

6,450,315.00 

2,720,496.00 

431,677.00 

7,637,562.00 

18,206,646.00 

6,155,097.00 

12,104,945.00 

135,562.00 

831,399.00 

9,964,226.00 

167,494,664.00 

70,324,249.00 

100,254,604.00 

38,515,020.00 

5113634 

5476902 

2229299 

1190085 

2,725,006.00 

105,466.00 

Method of 

loading or 

Unloading 

(«) 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

Average 

Loading or 

Unloading 

Mate 

per Armi 

(gal/min) 

2500 

2500 

2500 

250 

250 

250 

250 

3700 

3700 

3700 

250 

250 

1500 

1500 

10500 

1250 

14000 

10500 

14000 

250 

250 

14000 

10500 

10500 

14000 

250 

14000 

250 

14000 

6500 

14000 

250 

6500 

6500 

6500 

6500 

10500 

4500 

Vapior 

Control 

Device OD 

N 

N 

N 

N 

N 

N 

N 

VCS3 

VCS3 

VCS3 

VCS5 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

N 

N 

Control 

Device 

Efficiency 

(g) 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 
Reformate 

Refonnate 

Steam Cracked Naphtha 

Steam Cracked Naphtha 

Steam Cracked Naphtha 

Styrene Monomer 

Styrene Monomer 

Styrene Monomer 

Styrene Monomer 

Toluene 

Toluene 

Toluene 

Toluene 

Toluene 

Toluene 

Toluene 

Vinyl Acetate 

Vinyl Acetate 

Xylene 

Xylene 

Xylene 

Xylene 

Xylene 

Xylene 

Xylene 

BG,TS 

BG,TS 

BG.TS 

BG.TS 

BG,TS 

BG.TS 

BG,TS 

BG.TS 

BG.TS 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

BG.TS 

BG.TS 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

RC, BG, TS, TT 

SD2 

BDI 

BD5 

BDI 

SD#3 

SD3 

BD5 

BD6 

SD2 

BDI 

SD2 

BD5 

SD3 

BD6 

SD1 

ST8 

SD2 

SD1 

BDI 

SD1 

BD6 

SD2 

ST7 

STI 

ST4 

LN4 

LN4 

LN35 

LN35 

LN35 

LN70 

LN71 

LN72 

LN67 

LN43 

LN15 

LN110 

LN110 

LN110 

LN43 

LN1 

LN19 

LN19 

LN33 

LN33 

LN33 

LN33 

LN4 

LN1 

LN8 

TS BG TS BG TS TS BG BG TS BG TS BG TS BG TS TT TS TS BG TS BG BG 

TT,RC TT 

TT.RC 

1219026 

839350 

10180983 

494456 

1678571 

61,441,734.00 

610,049.00 

423,373.00 

1,681,688.00 

6,969,692.00 

416,514.00 

1,232,640.00 

1,274,859.00 

155,462.00 

13,947,260.00 

12,863,203.00 

9,079,660.00 

4,711,756.00 

4,036,771.00 

10,135,166.00 

939,350.00 

2,688,790.00 

4,830,052.00 

1,339,106.00 

790,705.00 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

BTM 

6500 

6500 

3500 

3500 

3500 

7500 

3200 

3200 

7500 

11000 

14000 

11000 

14000 

11000 

14000 

250 

3500 

3500 

3500 

3500 

3500 

3500 

250 

250 

250 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

N 

N 

N 

N 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

VCS3 

N 

N 

N 

N 

N 

N 

N 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 

98% 
TABLE 4. WASTEWATER FLOW RATES AND DRAIN CONTROLS 

CO 

Source of OLD 

Wastewater 

(a) 

N/A 

Total Flow 

Rate 

(gal/yr) 

HAP Name 

(b) 

HAP Concentration 

in Water (ppmw) 

(c) 

Number of Drains 

with Emission 

Suppression 

(d) 

Number of Drains 

without Emission 

Suppression 

(d) 

a). OLD = Organic Liquids Distribution. Select the codes that best describe the points of wastewater generation (insert codes as required and 

provide a full description): 

TC =tank cleanings 

LR =loading racks (identify the specific racks using the same rack codes as in footnote "a" of Table 3. 

LC = 

line cleanings 

LB =liquid blending/packaging operations 

OT =other, please provide full description (use extra sheet, if necessary). 

b). List the principal HAPs typically present in each wastewater stream. 

c). Estimated annual average concentration during periods of nominal flow in ppmw. 

d). Emission suppression controls reduce emissions from drain pipes and include, but are not limited to, water seal pots and p-traps. 
TABLE 5. WASTEWATER COLLECTION AND TREATMENT CONTROL (a) 

GP 

OLD Wastewater 

Treatment Unit 

Total Number of 

Units on Site 

(c) 

No. of Uncovered 

Units that Vent to 

the Atmosphere (d) 

No. of Covered 

Units that Vent to 

the Atmosphere (d) 

No. of Units that 

Vent Emissions to a 

Control Device 

Control Device 

(e) 

Source of Wastewater (b): Not Applicable 

Coltetfttatt tfaits 

Manholes 

Junction Boxes 

Sumps/Catch Basins 

Lift Stations 

Storage Tanks 

(0 

N/A 

N/A 

N/A 

N/A 

N/A 

Treatment Units 

Oil/Water Separators 

Air Flotation Systems 

Coagulation/Precipitation 

Units 

Sand Filtration Unit 

Equalization Units 

N/A 

N/A 

N/A 

N/A 

N/A 

See end of table for footnotes. 
TABLE 5. WASTEWATER COLLECTION AND TREATMENT CONTROL (a) (Continued) 

-0 

OLD Wastewater 

Treatment Unit 

Total 

Number of 

Units on Site 

(c) 

No. of Uncovered 

Units that Vent to 

the Atmosphere 

(d) 

No. of Covered 

Units that Vent to 

the Atmosphere 

No. of Units that 

Vent Emissions to a 

Control Device 

Control Device 

(e) 

Source of Wastewater (b): Not Applicable 

Treatment Units 

Oxidation Ponds 

Activated Sludge Units 

Trickling Filters 

Clarifiers 

Filter Presses 

Strippers 

Effluent/Recycle Pond 

Rotating Biological 

Contractors 

Ship Off Site 

(g) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

0 

See end of table for footnotes. 

lo 1° 
TABLE 6. SEMI-AQUEOUS WASTE COLLECTION AND CONTROL (a) 

« 

Type of Waste 

(b) 

Not Applicable 

Waste Generation 

Rate 

(tons/year) 

Waste Collected in 

a Closed System? 

(Yes/No) 

(d) 

Method of On-Site 

Storage 

(e) 

Waste Treated or 

Disposed of OnSite? (Yes/No) 

(0 

Method of On-Site 

Treatment or 

Disposal 

(g) 

Control Device on 

Treatment or 

Disposal Unit 

(h) 

See end of table for footnotes. 

CO 
P.32 

TABLE 7. EQUIPMENT LEAK CONTROL DATA 

1. Is there a formal, periodic leak detection and repair (LDAR) program? Yes X No 

Comments: Benzene monitoring is done on a monthly bases. 

2. Please indicate which Federal/State/local rules require an LDAR program at this facility: 

al 40 CFR 61 Subpart V 

b). 

3. If a formal equipment LDAR program has been implemented at your plant, provide the 

following information: 

Definition of Leaka 

Leak Detection Methodb 

Leak Response Timec 

A 

A 

Begin 5 days, Complete 15 days 

~z>\ 
Equipment 

Component 

Valves 

Compressors 

Flanges 

Pumps 

Inspection 

Frequency 

(a) 

Q 

Q 

Q 

Q 

Total 

Equipment 

Count 

7259 

0 

14593 

157 

Equipment 

Count in 

LDAR 

Program 

7259 

0 

14593 

157 

Equipment 

Count in 

LDAR with 

HAP Service 

1835 

0 

3694 

11 

Equopmnet counts 

with Mechanical 

Control Devices 

(b) 

0 

0 

0 

0 

Equipment Counts with a 

Closed Vent System 

(c) 

44 

0 

97 

0 

Closed Vent 

System Control 

Device 

(d) 

VCS3 

VCS3 

* Carbon Tetrachloride (Hypalon Solvent) closed system control device = VCS5 

w 

y 
P.34 

12 

TABLE 8. COMPOUNDING/BLENDING/PACKAGING OPERATIONS 

PartL N/A 

Product Name 

(a) 

Not Applicable 

Chemical Composition 

(b) 

Annual Quantity 

Produced 

(gal) (c) 

Does a chemical 

reaction take place? 

Applicable 

Regulations 

a). 

b). 

c). 

d). 

e). 

Provide the product names resulting from blending, compounding, and packaging operations. 

Names must match those provided in Table 1. For families of blends, include only the family 

name listed in Table 1. 

Provide the names of the raw materials (must match Table 1) that are used to blend/compound 

the product. 

Provide the annual quantities of the products produced. 

Specify whether a chemical reaction takes place during the compounding or blending of 

organic liquids (i.e., yes-compounding, no-blending, etc.). 

Please identify any regulations (pertaining to air emissions) that apply to the 

compounding/blending operation. 

Parin, 

The questions below are facility-wide, and do not need to be answered on a product-by-product basis. 

Please answer the following questions with as much detail as possible. Insert sheets as necessary. 

1. Provide a description of the principal methods/mechanisms used for blending/compounding. 

2. Provide a detailed description of any mechanisms of vapor balancing or other vapor emission 

control utilized for these processes (e.g., submerged fill). 

35 
P.35 

TABLE 9. AIR POLLUTION CONTROL EQUIPMENT PARAMETERS 

Control Device: Flare (b) 

Identifier Code (d): Land Flare 600 

Type: 

no assist: 

steam assist: 

air assist: X 

pressure assist: 

Location: 

ground :_X 

elevated: 

Heat content of vented stream, Btu/scf: 401 avg. 

Flare gas exit velocity, ft/s: 19.4 

Flare tip diameter, in. 24.73 in2 

Flare height, ft: 50 

Supplementary fuel for: 

Pilot, scfm: 54 

Combustion purposes, scfm 228 

Steam requirements, lb/hr: N/A 

Emission Sources (c) 

1. Tank Truck Loading 

2. Railcar Loading 

34-
P.36 

TABLE 9. AIR POLLUTION CONTROL EQUIPMENT PARAMETERS 

Control Device: Flare (b) 

Identifier Code (d): Land Flare 8900 

Type: 

no assist: 

steam assist: 

air assist: X 

pressure assist: 

Location: 

ground: _X 

elevated: 

Heat content of vented stream, Btu/scf: 401 avg. 

Flare gas exit velocity, ft/s: 39.2 

Flare tip diameter, in.: 13.74 in2 

Flare height, ft: 50 

Supplementary fuel for: 

Pilot, scfm: 54 

Combustion purposes, scfm: 400 

Steam requirements, lb/hr: N/A 

Emission Sources (c) 

1. Tank Truck Loading 

2. Railcar Loading 

2 ^ 
P.37 

TABLE 9. AIR POLLUTION CONTROL EQUIPMENT PARAMETERS 

Control Device: Flare (b) 

Identifier Code (d): Marine Flare 

Type: 

no assist: 

steam assist: 

air assist: X 

pressure assist: 

Location: 

ground:X 

elevated: 

Heat content of vented stream, Btu/scf: 601 avg. 

Flare gas exit velocity, ft/s: 134 

Flare tip diameter, in. 39.41 in2 

Flare hight, ft: 60 

Supplementary fuel for: 

Pilot, scfm: 1200 

Combustion purposes, scfm 1703 

Steam requirements, lb/hr: N/A 

Emission Sources (c) 

1. Tanker Ship Loading 

2. Barge Loading 

^U> 
P.38 

TABLE 9. AIR POLLUTION CONTROL EQUIPMENT PARAMETERS 

Control Device: Flare (b) 

Identifier Code (d): Vapor Condenser 

Type of condenser: 

surface: X 

contact: 

Gas inlet temperature, F 80 

Gas outlet temperature, F 32 

Emission Sources (c) 

1. Tank Truck Loading 

2. Railcar Loading 

irrv 
P.39 

TABLE 9. AIR POLLUTION CONTROL EQUIPMENT PARAMETERS 

Control Device: Flare (b) 

Identifier Code (d): CAS 

Type of carbon bed and number: 

regenerative: non-regenerative: X_ 

fixed: X 

fluidized: 

How many pounds of carbon per bed: 3001bs 

parallel: 

Serial: X 

Number of beds on-line: 2 

Number of beds desorbing: N/A 

Pressure drop. in. H20: 2 inches 

Gas inlet temperature, F 60 avg 

Type of regeneration: N/A 

Regeneration time: N/A 

Adsorption Time: NA 

Emission Sources (c) 

1. Tank Truck Loading 

2. Railcar Loading 
P.40 

ATTACHMENT "A" 

SECTION III - PLOT PLAN 

2>^ 
P.41 

Docket No. A-98-13 

Subcategory II-D 

The enclosures for this document, which are not easily photocopied, (plot plans, 

maps, etc.) are located in the WCPG files at EPA:ESD:WCPG, RTP, NC, Mutual 

Building. 

4-0 
P.42 

ATTACHMENT "B" 

SECTION IH - PLANT OPERATIONS 

Paktank Corporation - Deer Park Terminal is a "For-Hire" bulk liquid storage terminal 

(oil/chemical storage and handling SIC 4226). The facility's operations consist of 236 storage 

tanks ranging in size from 1000 barrels to 80,000 barrels in capacity. The terminal operates a 

total of 22 tank-truck and tank-car loading stations along with three ship docks and eight barge 

docks. Product transfers are conducted from tank truck, tank car, or marine vessels into and 

out of the bulk liquid storage tanks. There are no blending or packaging operations at this 

terminal. The terminal operates twenty-four hours a day, seven days a week. The following 

categories of organic liquids were stored during the surveyed year: 

Alcohols 

Parafins 

Aromatics 

Lubricants 

Solvents 

Glycols 

Olefins 

Naphthas 

Naphthalene 

Cyclo-olefins 

Ethers 

Esters 

Ketones 

Refined petroleum 

Oxygenates 

Acetates 

The HAPs consist of 42% of the total products shipped from the terminal. The HAP 

emissions generated are estimated to be 114.7 tons per year which represents 100% of the 

HAP emissions. 

4-1