FORM A-1

COMPANY INFORMATION

I. Parent Company / Legal Corporate Owner Information

1. Legal Parent Company / Legal Corporate Name Occidental Chemical Corporation

2. Mailing Address 5005 LBJ Freeway

3. City Dallas

4. State Texas 

5. Zip Code 75244-6152

6. County Dallas

>1500

7. Size of Company (approximate number of employees 

including all subsidiaries, branches, and related 

establishments owned):

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM A-2

FACILITY INFORMATION

II. Polyvinyl Chloride and Copolymers (PVC) Production Facility Information

1. Facility Name Oxy Vinyls, LP - Deer Park PVC

Facility Address

a. Street 1000 Tidal Road

b. City Deer Park

c. State Texas 

d. Zip Code 77536

e. County Harris

Facility Coordinates (Decimal Degrees to the 5th decimal place)

f. Latitude 29 deg, 43 min, 39 sec, N 

g. Longitude 95 deg, 04 min, 36 sec, W

2. Number of employees attached to the PVC 

production facility:

88

III. Technical Contact

1. Name Jadie Pryor

2. Technical Contact Title Environmental Engineer

3. Telephone (281) 476-2666

4. Facsimile 281-476-2657

5. Email Jadie_L._Pryor@oxy.com

IV. Other

1. Is the facility a major source of HAP? No

2. If No, did the facility take a limit of its 

potential HAP emissions to avoid classification 

as a major source?

No

3. If the facility took a limit of its potential HAP 

emissions to avoid classification as a major 

source, provide the date on which the limit 

was taken (MM/DD/YYYY).

4. Does the facility manufacture other products 

in addition to PVC resin?

Yes

5. If Yes, list the other products manufactured 

at the facility.

Anhydrous Potassium Hydroxide

6. Are there any HAP emissions associated 

with any co-located facilities?

No

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM B-1

CONTROL DEVICES

Instructions

2. For the purposes of this survey, cooling towers are considered process equipment. Complete Form B-4 and Form G for cooling towers and heat exchange systems.

3. For the following control devices, complete the appropriate Forms: absorbers - Form F-1; thermal or catalytic oxidizers - Form F-2, condensers - Form F-3.

4. If additional rows are needed "insert" rows before end of table to preserve formatting.

5. Refer to "Enclosure 1" for additional instructions and details.

( DO NOT SKIP ROWS when entering data into this table.)

1 2 3 4

Control 

Device ID

Control Device 

Description Control Device Type Other Description

Emission Points (EP) Exiting 

Control Device, or Subsequent 

Control Device ID to which 

Exhaust is Routed

(C-x) (thermal oxidizer, carbon 

adsorber, etc.) (If "Other (Specify)", please provide a description) (EP-x, or C-x)

C-301A Thermal Oxidizer C-302

C-301B Thermal Oxidizer C-302

C-302 Other (Specify) Spray Nozzle Scrubber (HCl) C-303

C-303 Other (Specify) Spray Nozzle Scrubber (NaOH) EP-301

C-201 Other (Specify) Wet Scrubber (PM) EP-204

C-203 Fabric Filter EP-206

C-204 Fabric Filter EP-207

C-101 Other (Specify) Wet Scrubber (PM) EP-104

C-102 Fabric Filter EP-105

C-103 Fabric Filter EP-106

C-104 Fabric Filter EP-107

C-105 Fabric Filter EP-112

C-401 Fabric Filter EP-404

N/A

1. Provide a process flow diagram and plot plan for the PVC production facility. See instructions in "Enclosure 1" for additional details. Completion of the process flow diagram is necessary

before completing this form and the rest of the survey.

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM B-2

RECOVERY SYSTEMS AND CLOSED VENT SYSTEMS

Instructions

1. In Table 1, identify each recovery system. For more details regarding the definition of a recovery system and what equipment should be included on this form, refer to Enclosure 1.

2. In Table 2, provide the requested information for any emission point through which emissions from the recovery or closed vent system are discharged directly to the atmosphere.

3. In Table 3, for each recovery system identified in Table 1, provide a recovery equipment ID and short description for each piece of equipment included in the recovery system.

4. If you use a condenser as part of a recovery system, and emissions from the condenser are routed directly to the atmosphere without first passing through a control device, complete form F-3 for the condenser(s).

5. If additional rows are needed "insert" rows before end of tables to preserve formatting.

6. Refer to "Enclosure 1" for additional instructions and details.

Table 1. Recovery System Identification Table 2. Direct Discharge Emission Points Table 3. Recovery Equipment that Comprise the Recovery System

( DO NOT SKIP ROWS when entering data into this table.) ( DO NOT SKIP ROWS when entering data into this table.) ( DO NOT SKIP ROWS when entering data into this table.)

1 2 3 8 9 10 1 2 3 4 1 2 3

Recovery System ID: Recovery System Description:

At any point in the recovery or 

closed vent system, can emissions 

be discharged directly to the 

atmosphere? (If "Yes," complete 

Table 2.)

Recovery 

System ID:

Emission Point ID

(Do not list emission points from 

streams that are routed through a 

closed vent system to a control 

device)

Is the emission point 

designed to be a control 

device bypass or a process 

vent?

Before a discharge occurs, 

are the equipment opening 

standards in 40 CFR Part 61, 

subpart F been met?

Recovery Equipment ID Recovery Equipment Description Recovery System ID:

(RS-x)

(use consistent terminology on the 

process flow diagram; be 

descriptive of equipment purpose)

(Yes/No) (RS-x) (EP-x) (Select) (Select) (RE-x)

(use consistent terminology on the 

process flow diagram; be descriptive 

of equipment purpose)

(RS-x)

RS-301 VCM Recovery System No C-301A C-301B RE-301 Vacuum Pump A RS-301

RE-302 Vacuum Pump B RS-301

RE-303 Vacuum Pump C RS-301

RE-304 Vacuum Pump D RS-301

RE-305 Vacuum Compressor A RS-301

RE-306 Vacuum Compressor B RS-301

RE-307 Vacuum Compressor C RS-301

RE-308 Vacuum Compressor D RS-301

RE-309 Vacuum Compressor E RS-301

RE-310 Vacuum Pump A KO Pot RS-301

RE-311 Vacuum Pump B KO Pot RS-301

RE-312 Vacuum Pump C KO Pot RS-301

RE-313 Vacuum Pump D KO Pot RS-301

RE-314 Vacuum Compressor A KO Pot RS-301

RE-315 Vacuum Compressor B KO Pot RS-301

RE-316 Vacuum Compressor C KO Pot RS-301

RE-317 Vacuum Compressor D KO Pot RS-301

RE-318 Vacuum Compressor E KO Pot RS-301

RE-319 Vent Condenser RS-301

RE-320 Vent Condenser RS-301

RE-321 Secondary Vent Condenser RS-301

RE-322 Vent Membrane RS-301

(Select Control Device IDs Entered on 

Form B-1)

List the control devices that control 

emissions from the closed vent 

system:

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM B-4

PROCESS EQUIPMENT

Instructions

1. Complete the table for each piece of process equipment identified on your process flow diagram. Do not include equipment or devices you have identified in Forms B-1 or B-2.

2. For the purposes of this survey, cooling towers are considered process equipment. For each cooling tower reported on this Form, complete Form H for cooling towers and heat exchange systems.

3. If emissions from a condenser (not previously listed as part of a recovery system or control device) are routed directly to the atmosphere without first passing through a recovery system or control device, complete Form F-3 for the condenser(s).

4. If additional rows are needed "insert" rows before end of tables to preserve formatting.

5. Refer to "Enclosure 1" for additional instructions and details.

( DO NOT SKIP ROWS when entering data into this table.)

1 2 3 4 5 6 7 8 9 10 11

Process 

Equipment 

ID

Process Equipment Description

Are emissions from the process 

equipment routed directly to the 

atmosphere without first passing through 

a recovery system or control device?

Are emissions from the 

process equipment routed 

to a recovery system?

If you answered "Yes" in Column 7, 

list the recovery system ID entered 

in Form B-2.

(U-x)

(use consistent terminology on the 

process flow diagram; be descriptive of 

equipment purpose)

(Yes/No) (Yes/No) (RS-x)

U-101 Solution Mix Tank Yes EP-110

U-102 Solution Cooler Yes EP-110

U-103 A Foam Trap No Yes RS-301

U-104 Condenser(3) No Yes RS-301

U-105 Jacketed Reactors (4) Z,A,B,C No Yes RS-301

U-106 Coating Tank Yes EP-108

U-107 Short Stop Pot No Yes RS-301

U-108 A Blowdown Tank No Yes RS-301

U-109 A Column Feed Tank No Yes RS-301

U-110 A Economizer No Yes RS-301

U-111 AA Economizer No Yes RS-301

U-112 A Stripping Column No Yes RS-301

U-113 AA Stripping Column No Yes RS-301

U-114 A Col. Condenser No Yes RS-301

U-115 AA Col. Condenser No Yes RS-301

U-116 A Knock out pot No Yes RS-301

U-117 AA Knock out pot No Yes RS-301

U-118 A Blend Tank Cooler Yes EP-101

U-119 A Blend Tank Yes EP-101

U-120 A Off Grade Blend Tank Yes EP-102

U-121 Centrifuges (2) Yes EP-103

U-122 A Dryer No No C-101

U-123 Cyclone No No C-101

U-124 Surge Hopper No No C-101

U-125 Screen No No C-101

U-126 Magnetic Separator No No C-101

U-127 Surge Hopper No No C-102

U-128 Camco Filters No No C-102

U-129 Bulk Bins (5) No No C-105

U-130 Production Bins (4) No No C-103 C-102

U-131 Fluidize Silos(2) No No C-104

U-132 Water Tank Yes EP-111

U-133 Short Stop Small Pots No Yes RS-301

U-135 Jackets(4) Yes EP-411 EP-412

U-136 Baffles No No N/A

U-137 Short Stop Tote Yes EP-109

U-138 A Dryer Air Preheater No No C-101

U-201 Solution Mix Tank Yes EP-210

U-202 Solution Cooler Yes EP-210

U-203 B Foam Trap No Yes RS-301

U-204 Condenser(3) No Yes RS-301

U-205 Jacketed Reactors (4) D,E,F,G No Yes RS-301

U-208 B Blowdown Tank No Yes RS-301

U-209 B Column Feed Tank No Yes RS-301

U-210 B Economizer No Yes RS-301

U-211 B Stripping Column No Yes RS-301

U-212 B Col. Condenser No Yes RS-301

U-213 B Knock out pot No Yes RS-301

U-214 B Blend Tank Cooler Yes EP-201

U-215 B Blend Tank Yes EP-201

U-216 B Off Grade Blend Tank Yes EP-202

U-217 Centrifuges (2) Yes EP-203

U-219 B Dryer No No C-201

U-220 Cyclone No No C-201

If you answered "Yes" in Column 3, list the emission point ID as shown on the 

process flow diagram.

(Do not list streams exiting the process equipment that are routed to a recovery 

system or control devices)

(List EP-x)

If you answered "No" in 

Column 7, list the control 

devices that control emissions 

from the process equipment:

(Select Control Device IDs 

Entered on Form B-1)

Page 1 of 2

PVC Combined Vent Section 114 Survey

11/17/2014
FORM B-4

PROCESS EQUIPMENT

Instructions

1. Complete the table for each piece of process equipment identified on your process flow diagram. Do not include equipment or devices you have identified in Forms B-1 or B-2.

2. For the purposes of this survey, cooling towers are considered process equipment. For each cooling tower reported on this Form, complete Form H for cooling towers and heat exchange systems.

3. If emissions from a condenser (not previously listed as part of a recovery system or control device) are routed directly to the atmosphere without first passing through a recovery system or control device, complete Form F-3 for the condenser(s).

4. If additional rows are needed "insert" rows before end of tables to preserve formatting.

5. Refer to "Enclosure 1" for additional instructions and details.

( DO NOT SKIP ROWS when entering data into this table.)

1 2 3 4 5 6 7 8 9 10 11

Process 

Equipment 

ID

Process Equipment Description

Are emissions from the process 

equipment routed directly to the 

atmosphere without first passing through 

a recovery system or control device?

Are emissions from the 

process equipment routed 

to a recovery system?

If you answered "Yes" in Column 7, 

list the recovery system ID entered 

in Form B-2.

(U-x)

(use consistent terminology on the 

process flow diagram; be descriptive of 

equipment purpose)

(Yes/No) (Yes/No) (RS-x)

If you answered "Yes" in Column 3, list the emission point ID as shown on the 

process flow diagram.

(Do not list streams exiting the process equipment that are routed to a recovery 

system or control devices)

(List EP-x)

If you answered "No" in 

Column 7, list the control 

devices that control emissions 

from the process equipment:

(Select Control Device IDs 

Entered on Form B-1)

U-221 Surge Hopper No No C-201

U-222 Screen No No C-201

U-223 Magnetic Separator No No C-201

U-224 Surge Hopper No No C-102

U-225 Camco Filters No No C-102

U-227 Production Bins (4) No No C-203 C-102

U-228 Fluidize Silos(2) No No C-204

U-229 Water Tank Yes EP-211

U-230 Short Stop Small Pots No Yes RS-301

U-231 Jackets(4) Yes EP-412 EP-411

U-232 Baffles No No N/A

U-233 B Dryer Air Preheater No No C-201

U-301 Low Pressure Foam Trap No Yes RS-301

U-302 High Pressure Foam Trap No Yes RS-301

U-304 Inhibitor Tank No Yes RS-301

U-308 Accumulator No Yes RS-301

U-309 Reclaim Monomer Storage No Yes RS-301

U-310 Reclaim Monomer Storage No Yes RS-301

U-311 Decanter No Yes RS-301

U-312 VCM Filters No Yes RS-301

U-313 VCM Sphere No Yes RS-301

WWE-314 WWS Feed Tank No Yes RS-301

WWE-315 WWS ecomomizers No Yes RS-301

WWE-316 Waste Water Stripper No Yes RS-301

WWE-317 Condenser No Yes RS-301

U-401 Centrate Sump Yes EP-410

U-403 RO Pre-heater Yes EP-413

U-404 Heat Exchangers (2) Yes EP-413

U-405 Centrate Filters Yes EP-413

U-406 Recycle Water Yes EP-413

U-407 Warm RO Tank Yes N/A

U-408 US Filter RO System Yes N/A

U-409 Cold RO Tank Yes N/A

U-410 PVC Cooling Tower Yes EP-401

U-411 Condenser Cooling Tower Yes EP-402

U-412 Chill Water Small Tank Yes EP-411

U-413 Chillers(4) Yes EP-411 EP-412

U-414 Ammonia Chiller Yes EP-411 EP-412

U-415 Chill Water Tank Yes EP-412

WWE-416 Waste Water Treatment Plant Yes EP-414

U-417 Liquid Suspending Agent Tank Yes EP-415

U-418 Boilers(2) Yes EP-403

U-419 Ammonia Refrigeration System No No N/A

U-420 Diesel Air Compressor Yes EP-405

U-421 Emergency Generator Yes EP-406

U-422 #3 Diesel FW Pump Yes EP-407

U-423 #4 Diesel FW Pump Yes EP-408

U-424 Potable Water Pump Yes EP-409

WWE-425 PVC Sump Yes EP-416

U-426 Catalyst Trailer Emer Engine Yes EP-417

Page 2 of 2

PVC Combined Vent Section 114 Survey

11/17/2014
FORM F-1

CONTROL DEVICES - ABSORBER

Instructions

1. Complete the form for each absorber used as a control device within the PVC production facility, or for any absorber that emits directly to atmosphere.

2. Refer to "Enclosure 1" for additional instructions and details.

C-302 C-303

1 Type of Equipment or Device Control Device Control Device

2 Equipment of Device ID C-302 C-303

3 Type of Absorber Other (Specify) Other (Specify)

4 If other, provide a description: Spray Nozzle Scrubber Spray Nozzle Scrubber

5 Gas inlet flow rate (dscfm): 46667 46667

6 Gas inlet temperature (°F): 500

7 Pressure drop (in H2O): 6.9 6.9

8 Liquid-to-gas ratio (gal/103

 acfm): 0.0084 0.052

Inlet scrubbing liquor

9 Liquor used: Softened Water Softened Water

10 pH: 9.2

11 Percent solids:

12 Type of alkali added, if any: NaOH

13 Addition rate (lb/gal):

14 Wastewater generation rate (gal/min): 5

15 Year Equipment Installed: 2007 2007

16 Equipment Currently Regulated Under (cite regulations): 40 CFR 63 subpart G 40 CFR 63 subpart G

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM F-2

CONTROL DEVICES - THERMAL OR CATALYTIC OXIDIZER

1 Control Device ID: C-301A C-301B

2 Number of operating hours per year (hours/year): 8760 8760

3 Is this emergency equipment? No No

4 Type (Thermal Oxidizer or Catalytic Oxidizer) Thermal Oxidizer Thermal Oxidizer

5 Oxidizer Inlet Flow Rate (dscfm): 22512 22512

6 Average percentage of total flow originating from the production facility: 0.20% 0.20%

7

Combustion chamber temperature (°F): (please note if temperature 

measurement is not in chamber) 1560 1560

8 Excess air (%): 50 50

9 Nominal residence time (s): 2.4 2.4

Heat recovery

10 Recuperative, percent heat recovery 75 75

11 Regenerative, percent heat recovery 0% 0%

12 Design Capacity (Heat Input) (MMBtu/hr): 70 80

13 Fuel Basis for Design Capacity: 68627 SCFH 78431 SCFH

14 Heat Release Rate (Btu/scf): 1020 1020

15 Is the unit subject to NSPS? No No

16 If yes, indicate the year:

Start-up Fuel/Material

17 Start-up fuel: Natural Gas Natural Gas

18 Number of start-ups per year: 4 4

19 Typical length of time for start-up (hours): 12 12

20 Higher heating value (HHV): 1020 1020

Fuels/Materials Combusted During Normal Operations (include solid, liquid, and gas waste streams)

21 Fuel 1: Natural Gas Natural Gas

22 Hours used per year: 8760 8760

23 Higher heating value (HHV): 1020 1020

24 Fuel 2: Vent Gas Vent Gas

25 Hours used per year: 8760 8760

26 Higher heating value (HHV): 51.5 51.5

27 Fuel 3:

28 Hours used per year:

29 Higher heating value (HHV):

30 Fuel 4:

31 Hours used per year:

32 Higher heating value (HHV):

33 Fuel 5:

34 Hours used per year:

35 Higher heating value (HHV):

36 Year Equipment Installed: 1977 1977

37 Equipment Currently Regulated Under (cite regulations): 40 CFR 63 subpart G 40 CFR 63 subpart G

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM F-3

CONTROL DEVICES - CONDENSERS

Instructions

1. Complete the form for each condenser used as a control device within the PVC production facility, or for any condenser that emits directly to atmosphere.

2. Refer to "Enclosure 1" for additional instructions and details.

1 Type of Equipment or Device

2 Equipment of Device ID

3 Type of Condenser

4 If other, provide a description:

5 Is the condenser refrigerated?

6 Describe the materials condensed:

7 Describe the fate of the non-condensed gas stream:

8 Describe the fate of the condensate outlet stream:

9 Gas inlet flow rate (dscfm):

10 Gas inlet temperature (°F):

11 Gas outlet temperature (°F):

12 Liquid outlet for rate (gpm):

15 Year Equipment Installed:

16 Equipment Currently Regulated Under (cite regulations):

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM H

EQUIPMENT LEAKS

Instructions

1. Submit a copy of the leak detection and repair procedures for the PVC production facility and provide responses to the questions below.

2. Refer to "Enclosure 1" for additional instructions and details.

Table 1. LDAR Program

Yes

No

Yes

No

No

$39,554

Table 2. Equipment Counts

In Source 

Category

Subtotal of Equipment Associated 

with Closed Vent System(s)

(Subset of count in source category)

2082 39

0

41

0

6215 124

0

12

0

82

0

5

0

0

In heavy liquid service

In gas, vapor, and light liquid service

Connectors

In heavy liquid service

In gas, vapor, and light liquid service

Agitators

In liquid service

In gas and vapor service

Pressure Relief Devices

Open ended valves and lines

Sampling connection systems

Compressors

Instrumentation systems

Valves

In heavy liquid service

In light liquid service

Pumps

40 CFR Part 61, Subpart V

Other Federal LDAR Regulation

Specify: 

State LDAR Regulation

Specify:

Provide the total cost to your facility for conducting the LDAR 

program at this process unit in 2013:

Equipment

In heavy liquid service

In gas, vapor, and light liquid service

Is there an equipment leak detection and repair (LDAR) 

program for all equipment at your facility included in the source 

category?

If "No," how are equipment leaks detected and repaired?

If "Yes," is the equipment subject to the requirements of:

40 CFR Part 63, Subpart UU

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-112

A Stripping Column System

10

Equipment 

Cleaning/Product 

Switch/Maintenance 

PM

31.2

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

6 136 49.5 0.09

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Equipment volume (m3):

Reason(s) for Equipment Opening

Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled?

Individual HAP Present Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value

Source Equipment Type:

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-113

AA Stripping Column System

5

Equipment 

Cleaning/Product 

Switch/Maintenance 

PM

21.3

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

10 330 79.4 0.05

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-211

B Stripping Column System

53

Equipment 

Cleaning/Product 

Switch/Maintenance 

PM

26.9

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 85 20.7 0.17

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-103 and U-203

Foam Trap

4

Equipment 

Cleaning/Maintenanc

e PM

50

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 8 3.75 0.004

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-108 and U-208

Blowdown Tanks

3

Equipment 

Cleaning/Maintenanc

e PM

166.7

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

4 32 13.67 0.04

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-109 and U-209

Column Feed Tanks

2

Equipment 

Cleaning/Maintenanc

e PM

187

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

31 64 47.5 0.1

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

Misc.Pumps and Piping

5

Maintenance

0.1

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

1.2 55 21 0.0001

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Recovery Equipment

RE-305 This tab includes information for RE-305 to 309 and RE-314 to RE-318

Recovery Compressors and KO Pots

5

Maintenance

0.6

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

10 90 34.2 0.001

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Recovery Equipment

RE-301 This tab includes information for RE-301 to 304 and RE-310 to RE-313

Vacuum Pump with KO Pots

7

Maintenance

0.3

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 63 23.14 0.0003

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Recovery Equipment

RE-319 and RE-320

Recovery Condensers

1

Maintenance 

PM/Inspection

2.5

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

110 110 110 0.0016

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

Misc. Valves and Piping

2

Maintenance

0.03

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 23 11.5 0

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

Vapor Filters

4

Maintenance/Inspecti

on

0.3

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 55 21.25 0.0002

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-312

VCM Filters

8

Change Filters

0.7

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 345 155 0.005

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

VCM Charge Pumps

1

Maintenance

0.17

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

122 122 122 0.0001

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Recovery Equipment

RE-322

VCM Recovery Membranes

2

Maintenance

0.17

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

0 4 2 0

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

WWE-316

Wastewater Stripper

4

Maintenance/Inspecti

on

3.9

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

3 150 45 0.004

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-105

Reactors

54

Equipment 

Cleaning/Maintenanc

e

78.4

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

250 1923 774 18.4

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM I

EQUIPMENT OPENING

Instructions

1. Complete this form for 2013 only.

2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-205

Reactors

47

Equipment 

Cleaning/Maintenanc

e

78.4

Sampling Results Other method:

Table 2.

Total Emissions for 

2013

Minimum Maximum Average (pounds)

Vinyl chloride

93 1800 617.6 12.78

Calculated based on 

equipment volume and 

measured VOC 

concentration at opening

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Equipment volume (m3):

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined?

How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3% O2) Basis for Emissions 

Value Notes

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE 

meter is used to measure for VOC when opening equipment; All VOC is reported as VCM

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-313

VCM Storage Sphere

1000 Restricted cell; turnovers = 1,985

852

100

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Sphere; so fixed structure

Feedstock storage

If Other, please specify, being as descriptive as possible:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Select the purpose of the equipment:

If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP.

Are HAP Emissions Controlled? Yes

Individual HAP Present

Source Equipment Type:

No emissions to ATM; Emissions directed to Recovery System prior to opening

Number of turnovers:

Equipment volume (m3):

Notes

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-101

Solution Mix Tank

1000 Restricted cell; turnovers = 4,691

1.89

75

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Cumene 0.2 0

Methanol 142 0

Acetophenone 0.2 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

Trace HAP in some raw materials; Concentrations unknown

Trace HAP in some raw materials; Concentrations unknown

Trace HAP in some raw materials; Concentrations unknown

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? MSDS

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Tank used for mixing suspending agents and additives prior to charging to the 

reactors; Openings on tank for adding materials

Select the purpose of the equipment: Additive blending

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-201

Solution Mix Tank

1000 Restricted cell; turnovers = 4,443

1.89

75

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Cumene 0.2 0

Methanol 142 0

Acetophenone 0.2 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

Trace HAP in some raw materials; Concentrations unknown

Trace HAP in some raw materials; Concentrations unknown

Trace HAP in some raw materials; Concentrations unknown

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? MSDS

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Tank used for mixing suspending agents and additives prior to charging to the 

reactors; Openings on tank for adding materials

Select the purpose of the equipment: Additive blending

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-309

Reclaim Monomer Storage

1000 Restricted cell; turnovers = 2,233

75.66

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

No emissions to ATM; Emissions directed to Recovery System prior to opening

Are HAP Emissions Controlled? Yes

If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP.

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Horizontal pressure vessel

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-310

Reclaim Monomer Storage

1000 Restricted cell; turnovers = 2,233

75.66

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

No emissions to ATM; Emissions directed to Recovery System prior to opening

Are HAP Emissions Controlled? Yes

If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP.

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Horizontal pressure vessel

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-314

WWS Feed Tank

1000 Restricted cell; turnovers = 3,795

37.8

100

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

Acetaldehyde 535 0

Acetophenone 0.2 0

Hydroquinone 0.00001 0

Formaldehyde 28 0

Methanol 142 0

Ethylene dichloride (1,2-

Dichloroethane) 80 0

Ethylidene dichloride (1,1-

Dichloroethane) 123 0

Ethyl chloride (Chloroethane) 540 0

Methyl chloride 

(Chloromethane) 2309 0

Cumene 0.2 0

Xylenes (isomers and mixture) 3.6 0

2,2,4-Trimethylpentane 21.8 0

Benzene (including benzene 

from gasoline) 105 0

Toluene 27 0

Phenol 0.19 0

Chloroform 160 0

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

Notes

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

No emissions to ATM; Emissions directed to Recovery System prior to 

opening

Are HAP Emissions Controlled? Yes

If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Estimated based on wastewater containing a variety of potential HAPs

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or 

floating external roof. 

Fixed; closed vertical pressure vessel; Vessel contains collected wastewater prior to 

stripping to remove residual VCM; vessel is closed and not vented to ATM; any emissions 

aredirected through the Recovery System

Select the purpose of the equipment: Wastewater 

storage/equalization

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-137

Shortstop Tote

20

1.1

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Acetaldehyde 535 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

Acetaldehyde may be present as a decomposition product; trace concentration

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled? +

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Supplier tote is connected to act as a feed tank to the process; tote is vented to ATM; 

RM is not a HAP, but may contain traces of Acetaldehyde

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-106

Coating Tank

15

3.8

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Formaldehyde 28 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

Formaldehyde MAY be present in trace amounts

Are HAP Emissions Controlled? Yes

If Yes, How Are The Emissions Controlled? Closed Tank; Nitrogen Pad vent to U-104 or U-204 (condenser) and then to Recovery System; 

Conservation Vent to ATM

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Closed tank with a nitrogen pad and conservation vent; RM may contain traces of 

Formaldehyde

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-417

Liquid Suspending Agent Tank

2

36

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Methanol 142

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

Methanol may be present up to 2% of solution

Are HAP Emissions Controlled? Yes

If Yes, How Are The Emissions Controlled? Closed Tank; Conservation Vent to ATM

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? MSDS

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Closed tank with a conservation vent; RM will contain up to 2% methanol (per MSDS)

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-132

Scrubber Water Tank

unknown; continuous level control

9.5

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

Acetaldehyde 535 0

Acetophenone 0.2 0

Hydroquinone 0.00001 0

Formaldehyde 28 0

Methanol 142 0

Ethylene dichloride (1,2-

Dichloroethane) 80 0

Ethylidene dichloride (1,1-

Dichloroethane) 123 0

Ethyl chloride (Chloroethane) 540 0

Methyl chloride 

(Chloromethane) 2309 0

Cumene 0.2 0

Xylenes (isomers and mixture) 3.6 0

2,2,4-Trimethylpentane 21.8 0

Benzene (including benzene 

from gasoline) 105 0

Toluene 27 0

Phenol 0.19 0

Chloroform 160 0 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? Unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; Open to atmosphere; Holds centrate water which is used to scrub the dryer discharge to 

remove PM

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible:

Water hold tank for water fed to Wet scrubber to control dryer PM emissions

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-229

Scrubber Water Tank

unknown; continuous level control

9.5

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

Acetaldehyde 535 0

Acetophenone 0.2 0

Hydroquinone 0.00001 0

Formaldehyde 28 0

Methanol 142 0

Ethylene dichloride (1,2-

Dichloroethane) 80 0

Ethylidene dichloride (1,1-

Dichloroethane) 123 0

Ethyl chloride (Chloroethane) 540 0

Methyl chloride 

(Chloromethane) 2309 0

Cumene 0.2 0

Xylenes (isomers and mixture) 3.6 0

2,2,4-Trimethylpentane 21.8 0

Benzene (including benzene 

from gasoline) 105 0

Toluene 27 0

Phenol 0.19 0

Chloroform 160 0 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? Unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Fixed; Open to atmosphere; Holds centrate water which is used to scrub the dryer discharge 

to remove PM

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible:

Water hold tank for water fed to Wet scrubber to control dryer PM emissions

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-401

Centrate Sump

unknown

152

110

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

Acetaldehyde 535 0

Acetophenone 0.2 0

Hydroquinone 0.00001 0

Formaldehyde 28 0

Methanol 142 0

Ethylene dichloride (1,2-

Dichloroethane) 80 0

Ethylidene dichloride (1,1-

Dichloroethane) 123 0

Ethyl chloride (Chloroethane) 540 0

Methyl chloride 

(Chloromethane) 2309 0

Cumene 0.2 0

Xylenes (isomers and mixture) 3.6 0

2,2,4-Trimethylpentane 21.8 0

Benzene (including benzene 

from gasoline) 105 0

Toluene 27 0

Phenol 0.19 0

Chloroform 160 0 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown

Water collection sump which accumulates stripped centrate from the centrifuges

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Sump used to collect centrate from the centrifuges prior to storage

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

How is the HAP Concentration Determined?

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-406

Recycle Water Tank

unknown

681

110

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 0

Acetaldehyde 535 0

Acetophenone 0.2 0

Hydroquinone 0.00001 0

Formaldehyde 28 0

Methanol 142 0

Ethylene dichloride (1,2-

Dichloroethane) 80 0

Ethylidene dichloride (1,1-

Dichloroethane) 123 0

Ethyl chloride (Chloroethane) 540 0

Methyl chloride 

(Chloromethane) 2309 0

Cumene 0.2 0

Xylenes (isomers and mixture) 3.6 0

2,2,4-Trimethylpentane 21.8 0

Benzene (including benzene 

from gasoline) 105 0

Toluene 27 0

Phenol 0.19 0

Chloroform 160 0 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown

Centrate water collection tank

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Fixed; Vented to atmosphere

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

How is the HAP Concentration Determined?

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-304

Inhibitor Tank

2

0.26

80

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

No HAPS proesent in inhibitor

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? None

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, describe 

the tank, vessel, or container and indicate (if applicable) if 

the tank is a fixed, floating internal, or floating external roof. 

Fixed; tank contains inhibitor which is not a HAP

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-129

PVC Bulk Bins (6)

973 combined volume of (5) bins

85

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 20

Acetaldehyde 535

Acetophenone 0.2

Hydroquinone 0.00001

Formaldehyde 28

Methanol 142

Ethylene dichloride (1,2-

Dichloroethane) 80

Ethylidene dichloride (1,1-

Dichloroethane) 123

Ethyl chloride (Chloroethane) 540

Methyl chloride 

(Chloromethane) 2309

Cumene 0.2

Xylenes (isomers and mixture) 3.6

2,2,4-Trimethylpentane 21.8

Benzene (including benzene 

from gasoline) 105

Toluene 27

Phenol 0.19

Chloroform 160 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Emissions Inventory

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Final product storage bins holding finshed PVC product prior to loading; U-129 represents (6) 

separate storage bins and may be accessed by either production line

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-130

PVC Production Day Bins (4)

392 Combined volume of (4) bins

85

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 3

Acetaldehyde 535

Acetophenone 0.2

Hydroquinone 0.00001

Formaldehyde 28

Methanol 142

Ethylene dichloride (1,2-

Dichloroethane) 80

Ethylidene dichloride (1,1-

Dichloroethane) 123

Ethyl chloride (Chloroethane) 540

Methyl chloride 

(Chloromethane) 2309

Cumene 0.2

Xylenes (isomers and mixture) 3.6

2,2,4-Trimethylpentane 21.8

Benzene (including benzene 

from gasoline) 105

Toluene 27

Phenol 0.19

Chloroform 160 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Emissions Inventory

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Final product storage bins holding finshed PVC product prior to loading; U-130 represents (4) 

separate storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-131

PVC Fluidizing Silos (2)

1000 Restricted cell; turnovers = 1,135

486 Combined volume of (2) silos

85

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 68

Acetaldehyde 535

Acetophenone 0.2

Hydroquinone 0.00001

Formaldehyde 28

Methanol 142

Ethylene dichloride (1,2-

Dichloroethane) 80

Ethylidene dichloride (1,1-

Dichloroethane) 123

Ethyl chloride (Chloroethane) 540

Methyl chloride 

(Chloromethane) 2309

Cumene 0.2

Xylenes (isomers and mixture) 3.6

2,2,4-Trimethylpentane 21.8

Benzene (including benzene 

from gasoline) 105

Toluene 27

Phenol 0.19

Chloroform 160 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Emissions Inventory

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Final product silos hold finished PVC product prior to loading; U-131 represents (2) separate 

storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-227

PVC Production Day Bins (4)

392 Combined volume of (4) bins

85

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 4

Acetaldehyde 535

Acetophenone 0.2

Hydroquinone 0.00001

Formaldehyde 28

Methanol 142

Ethylene dichloride (1,2-

Dichloroethane) 80

Ethylidene dichloride (1,1-

Dichloroethane) 123

Ethyl chloride (Chloroethane) 540

Methyl chloride 

(Chloromethane) 2309

Cumene 0.2

Xylenes (isomers and mixture) 3.6

2,2,4-Trimethylpentane 21.8

Benzene (including benzene 

from gasoline) 105

Toluene 27

Phenol 0.19

Chloroform 160 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Emissions Inventory

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Final product storage bins holding finshed PVC product prior to loading; U-227 represents (4) 

separate storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. 

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Process Equipment

U-228

PVC Fluidizing Silos (2)

1000 Restricted cell; turnovers = 1,091

486 Combined volume of (2) silos

85

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 2110 68

Acetaldehyde 535

Acetophenone 0.2

Hydroquinone 0.00001

Formaldehyde 28

Methanol 142

Ethylene dichloride (1,2-

Dichloroethane) 80

Ethylidene dichloride (1,1-

Dichloroethane) 123

Ethyl chloride (Chloroethane) 540

Methyl chloride 

(Chloromethane) 2309

Cumene 0.2

Xylenes (isomers and mixture) 3.6

2,2,4-Trimethylpentane 21.8

Benzene (including benzene 

from gasoline) 105

Toluene 27

Phenol 0.19

Chloroform 160 Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

Are HAP Emissions Controlled? No

If Yes, How Are The Emissions Controlled?

Individual HAP Present

Concentration (ppmvd @ 3% O2)

Notes

Emissions Inventory

Unknown Trace possible

Unknown Trace possible

Unknown Trace possible

How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown

Source Equipment Type:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Final product silos hold finished PVC product prior to loading; U-228 represents (2) separate 

storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible:

Number of turnovers:

Equipment volume (m3):

Storage Temperature (°F)

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM L

STARTUP, SHUTDOWN, AND MALFUNCTION

Instructions

1. Complete this form for 2013 only.

2. Submit with your response to this survey, copies of all records of emissions during periods of process startup, shutdown, and malfunctions for 2013 only.

3. Refer to "Enclosure 1" for additional instructions and details.

No

Startup Shutdown

0.5 0.5

For a malfunction:

Yes Yes

No No

The stripping column is started and set to 

operating conditions prior to introduction of 

unstripped PVC slurry (with water). Once slurry 

flow is initiated, the column is already at operating 

conditions of temperature and pressure.

Stripping conditions (steam-to-PVC ratio, 

temperature, and pressure) are maintained 

throughout the shutdown. No higher than normal 

emissions are expected as a result of the 

shutdown.

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

Total Emissions During Startup, Shutdown, 

or Malfunction Event

Were all of the emissions control devices 

operating for the entire duration of the startup, 

shutdown, or malfunction event?

Startup, Shutdown or Malfunction?

If startup or shutdown, what was the 

duration (hours):

Provide a short description of the 

malfunction and the 

circumstances:

If No, which control devices were not operating 

(Control Equipment ID), for how long, and why:

Were permitted emissions limits exceeded?

Provide a description of the 

procedures used to alert the 

owner/operator that the 

malfunction occurred. If the malfunction resulted in a 

release of emissions, describe 

any indicators used to signal 

and/or measure the release.

Is there a written startup, shutdown and/or 

malfunction plan for the process unit?

Provide a description of the systems and 

equipment in place that function to notify 

operators that a malfunction is occurring .

For year 2013, the facility is not subject to a regulation that requires a Startup, Shutdown and Malfunction plan. The PVC manufacturing process is highly 

automated, incorporating interlocks and alarms for process variables that could lead to a Health, Environmental or Process Safety event. Critical process 

variables are equipped with alarms that report through the DCS to the central control room which is staffed continuously. If appropriate action is not taken 

by operations based on alarms and the critical process variable, then automated interlocks will act to control the process and return it to a safe state. 

Implementation of the OSHA 119 PSM standard and industry standards ensures that critical process variables are alarmed and interlocked. The DCS and 

associated process instrumentation are maintained to ensure a high degree of reliability. In addition to these process control systems, the manufacturing 

site is monitored continuously with an area GC/MS system to ensure personnel protection in all VCM containing areas, as well as LEL monitors throughout 

the VCM handling areas to warn of potential explosion hazards due to unplanned VCM release. Corrective action plans are in place in the event of either 

GC/MS or LEL alarms. 

Applicable standard or regulation:

Describe what actions, if any, were taken to 

minimize emissions to the atmosphere:

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM P

PROCESS VENT EMISSIONS TESTING DATA

Instructions

1. Copy this worksheet as necessary for pollutants/compounds sampled on different dates.

2. For multiple control devices, users may copy this worksheet within this workbook.

Control Equipment ID: C-303

Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the PVC 

process and another process unit (non-PVC) ("combined"): Combined

Parameter CAS Number Run #1 Run #2 Run #3 Units Run # 1 Detection Run # 2 Detection Run # 3 Detection Analysis Method Used Note(s)

Enter the CAS number for 

each pollutant/compound. 

Do not include dashes.

Select appropriate unit from list.

Identify the status of 

measured values relative to 

the detection levels

Identify the status of 

measured values relative to 

the detection levels

Identify the status of 

measured values relative to 

the detection levels

Where applicable, select the analysis method 

used.

For all pollutants/compounds, provide any other information 

supporting information you think is necessary about this test 

report. 

Test Date (mm/dd/yy)

Required Operating Parameters During Test

Total Heat Input (MMBtu/hr) MMBTU/hr

Fuel 1

Feed Rate MMBTU/hr

HHV BTU/scf

Fuel 2

Feed Rate MMBTU/hr

HHV BTU/scf

Fuel 3

Feed Rate MMBTU/hr

HHV BTU/scf

Flow Rate dscfm

Temperature deg F

Moisture %

O2 %

CO2 %

Number of PVC resin grades being produced during sampling

Number of PVC resin grades being produced (as percentage of all resin grades produced by facility) %

Testing Data

Compound CAS Number

Benzene 71432 ppmvd @ 3% O2 SW-846 Method 8260B

Chloroethane 75003 ppmvd @ 3% O2 SW-846 Method 8260B

Chloroform 67663 ppmvd @ 3% O2 SW-846 Method 8260B

Chloroprene 126998 ppmvd @ 3% O2 SW-846 Method 8260B

1,1-Dichloroethane 75343 ppmvd @ 3% O2 SW-846 Method 8260B

1,2-Dichloroethane 107062 ppmvd @ 3% O2 SW-846 Method 8260B

n-Hexane 110543 ppmvd @ 3% O2 SW-846 Method 8260B

Methylene chloride 75092 ppmvd @ 3% O2 SW-846 Method 8260B

Toluene 108883 ppmvd @ 3% O2 SW-846 Method 8260B

1,1,1-Trichloroethane 71556 ppmvd @ 3% O2 SW-846 Method 8260B

1,1,2-Trichloroethane 79005 ppmvd @ 3% O2 SW-846 Method 8260B

Vinylidene chloride 75354 ppmvd @ 3% O2 SW-846 Method 8260B

Acetophenone 98862 ppmvd @ 3% O2 SW-846 Method 8270D

Bis(2-ethylhexyl) phthalate (DEHP) 117817 ppmvd @ 3% O2 SW-846 Method 8270D

1,4-Dichlorobenzene 106467 ppmvd @ 3% O2 SW-846 Method 8270D

2,4-Dinitrophenol 51285 ppmvd @ 3% O2 SW-846 Method 8270D

Hexachlorobutadiene 87683 ppmvd @ 3% O2 SW-846 Method 8270D

Hydroquinone 123319 ppmvd @ 3% O2 SW-846 Method 8270D

Naphthalene 91203 ppmvd @ 3% O2 SW-846 Method 8270D

Phenol 108952 ppmvd @ 3% O2 SW-846 Method 8270D

1,2,4-Trichlorobenzene 120821 ppmvd @ 3% O2 SW-846 Method 8270D

Acetaldehyde 75070 ppmvd @ 3% O2

1,3-Butadiene 106990 ppmvd @ 3% O2

Chlorobenzene 108907 ppmvd @ 3% O2

Chloromethane 74873 ppmvd @ 3% O2

Cumene 98828 ppmvd @ 3% O2

Ethylbenzene 100414 ppmvd @ 3% O2

Ethylene glycol 107211 ppmvd @ 3% O2

Formaldehyde 50000 ppmvd @ 3% O2

Methanol 67561 ppmvd @ 3% O2

1,1,2,2-Tetrachloroethane 79345 ppmvd @ 3% O2

2,2,4-Trimethylpentane 540841 ppmvd @ 3% O2

Vinyl acetate 108054 ppmvd @ 3% O2

Vinyl bromide 593602 ppmvd @ 3% O2

Xylenes (isomers and mixtures) 1330207 ppmvd @ 3% O2

Vinyl chloride 75014 ppbvd @ 3% O2 US EPA Method 18

Total hydrocarbon (THC) N/A ppmvd as propane @ 3% O2 US EPA Method 25A

Methane (CH4) 74828 ppmvd @ 3% O2

Enter numerical value only.

Enter numerical value only.

OxyChem completed process vent emissions testing on November 14, 2014. 

Page 1 of 1

PVC Combined Vent Section 114 Survey

11/17/2014
FORM Q

TOTAL HYDROCARBON 30-DAY MONITORING

Note: Partial Data Set; Complete 30-Day Monitoring Data to be provided via Supplemental Submission

Instructions

1. For multiple control devices, users may copy this worksheet within this workbook.

2. Add additional rows as necessary to provide 30 days of monitoring data.

Control Equipment ID: C-301A

Combined

Date and Time THC Reading CH4 Reading O2 level in exhaust gas Moisture in exhaust 

gas

PVC Type PVC Grade Control Device 

Temperature

Control Device 

Operations Indicator

THC Monitoring 

Operations Indicator 

MM/DD/YYYY HH:MM (ppmvd as propane @ 3% O2) (ppmvd @ 3% O2) (% by volume, dry) (% by volume) (e.g., suspension, 

dispersion/emulsion, bulk, etc.) (e.g., GP, HMW, LMW, etc.) (degF)

(note periods of start-up, 

Shutdown, malfunctions, or 

normal operation) 

(note periods of abnormal 

operations) 

10/03/2014 10:25 2.31 0.34 6.04 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.05 Normal Operation Normal Operation

10/03/2014 11:25 2.22 0.32 6.03 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.03 Normal Operation Normal Operation

10/03/2014 12:25 2.03 0.32 5.98 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.01 Normal Operation Normal Operation

10/03/2014 13:25 1.88 0.10 5.99 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.09 Normal Operation Normal Operation

10/07/2014 11:35 1.24 0.26 6.03 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.96 Normal Operation Normal Operation

10/07/2014 12:35 0.89 0.22 5.97 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.23 Normal Operation Normal Operation

10/07/2014 13:35 0.89 0.21 5.92 23.49 Suspension G-3 (A Line), G-6 (B Line) 951.01 Normal Operation Normal Operation

10/07/2014 14:35 0.89 0.21 5.87 23.49 Suspension G-3 (A Line), G-6 (B Line) 948.37 Normal Operation Normal Operation

10/07/2014 15:35 0.89 0.21 5.86 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.91 Normal Operation Normal Operation

10/07/2014 16:35 0.90 0.22 6.01 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.53 Normal Operation Normal Operation

10/07/2014 17:35 0.90 0.22 6.04 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.19 Normal Operation Normal Operation

10/07/2014 18:35 0.90 0.22 6.03 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.22 Normal Operation Normal Operation

10/07/2014 19:35 0.90 0.22 6.10 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.98 Normal Operation Normal Operation

10/07/2014 20:35 0.90 0.22 6.10 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.75 Normal Operation Normal Operation

10/07/2014 21:35 0.90 0.22 5.99 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.57 Normal Operation Normal Operation

10/07/2014 22:35 0.89 0.22 5.95 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.2 Normal Operation Normal Operation

10/07/2014 23:35 0.89 0.22 5.97 23.49 Suspension G-3 (A Line), G-6 (B Line) 950 Normal Operation Normal Operation

10/08/2014 00:35 0.90 0.22 5.99 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.02 Normal Operation Normal Operation

10/08/2014 01:35 0.89 0.22 5.95 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.76 Normal Operation Normal Operation

10/08/2014 02:35 0.89 0.21 5.86 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.07 Normal Operation Normal Operation

10/08/2014 03:35 0.90 0.22 6.01 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.1 Normal Operation Normal Operation

10/08/2014 04:35 0.90 0.22 6.00 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.04 Normal Operation Normal Operation

10/08/2014 05:35 0.90 0.22 5.99 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.09 Normal Operation Normal Operation

10/08/2014 06:35 0.90 0.22 6.03 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.05 Normal Operation Normal Operation

10/08/2014 07:35 0.48 0.12 3.71 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.54 Normal Operation Normal Operation

10/08/2014 09:00 1.23 0.27 6.18 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.91 Normal Operation Normal Operation

10/08/2014 10:00 1.19 0.27 6.16 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.06 Normal Operation Normal Operation

10/08/2014 11:00 1.19 0.26 6.11 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.12 Normal Operation Normal Operation

10/08/2014 12:00 1.23 0.25 6.09 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.65 Normal Operation Normal Operation

10/08/2014 13:00 1.32 0.26 6.13 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.9 Normal Operation Normal Operation

10/08/2014 14:00 1.25 0.25 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 948.81 Normal Operation Normal Operation

10/08/2014 15:00 1.32 0.25 6.08 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.95 Normal Operation Normal Operation

10/08/2014 16:00 1.29 0.24 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.81 Normal Operation Normal Operation

10/08/2014 17:00 1.30 0.24 6.03 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.45 Normal Operation Normal Operation

10/08/2014 18:00 1.30 0.25 6.05 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.23 Normal Operation Normal Operation

10/08/2014 19:00 1.30 0.25 6.06 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.72 Normal Operation Normal Operation

10/08/2014 20:00 1.26 0.26 6.01 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.37 Normal Operation Normal Operation

10/08/2014 21:00 1.22 0.25 6.05 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.65 Normal Operation Normal Operation

10/08/2014 22:00 1.22 0.26 6.08 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.49 Normal Operation Normal Operation

10/08/2014 23:00 1.21 0.26 6.10 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.70 Normal Operation Normal Operation

10/09/2014 00:00 1.15 0.26 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.40 Normal Operation Normal Operation

10/09/2014 01:00 1.15 0.27 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.80 Normal Operation Normal Operation

10/09/2014 02:00 1.12 0.27 6.08 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.29 Normal Operation Normal Operation

Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the 

PVC process and another process unit (non-PVC) ("combined"):

Page 1 of 2

PVC Combined Vent Section 114 Survey

11/17/2014
FORM Q

TOTAL HYDROCARBON 30-DAY MONITORING

Note: Partial Data Set; Complete 30-Day Monitoring Data to be provided via Supplemental Submission

Instructions

1. For multiple control devices, users may copy this worksheet within this workbook.

2. Add additional rows as necessary to provide 30 days of monitoring data.

Control Equipment ID: C-301A

Combined

Date and Time THC Reading CH4 Reading O2 level in exhaust gas Moisture in exhaust 

gas

PVC Type PVC Grade Control Device 

Temperature

Control Device 

Operations Indicator

THC Monitoring 

Operations Indicator 

MM/DD/YYYY HH:MM (ppmvd as propane @ 3% O2) (ppmvd @ 3% O2) (% by volume, dry) (% by volume) (e.g., suspension, 

dispersion/emulsion, bulk, etc.) (e.g., GP, HMW, LMW, etc.) (degF)

(note periods of start-up, 

Shutdown, malfunctions, or 

normal operation) 

(note periods of abnormal 

operations) 

Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the 

PVC process and another process unit (non-PVC) ("combined"):

10/09/2014 03:00 1.14 0.28 6.04 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.29 Normal Operation Normal Operation

10/09/2014 04:00 1.16 0.27 5.97 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.40 Normal Operation Normal Operation

10/09/2014 05:00 1.14 0.27 6.01 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.29 Normal Operation Normal Operation

10/09/2014 06:00 1.16 0.28 6.04 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.01 Normal Operation Normal Operation

10/09/2014 07:00 1.17 0.27 5.99 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.08 Normal Operation Normal Operation

10/09/2014 09:12 1.10 0.26 5.98 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.10 Normal Operation Normal Operation

10/09/2014 10:12 1.15 0.27 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.99 Normal Operation Normal Operation

10/09/2014 11:12 1.22 0.27 6.08 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.77 Normal Operation Normal Operation

10/09/2014 12:12 1.22 0.25 6.09 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.81 Normal Operation Normal Operation

10/09/2014 13:12 1.23 0.25 6.04 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.33 Normal Operation Normal Operation

10/09/2014 14:12 1.20 0.25 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.07 Normal Operation Normal Operation

10/09/2014 15:12 1.21 0.23 6.07 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.37 Normal Operation Normal Operation

10/09/2014 16:12 1.24 0.23 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.81 Normal Operation Normal Operation

10/09/2014 17:12 1.23 0.25 6.01 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.27 Normal Operation Normal Operation

10/09/2014 18:12 1.16 0.25 6.04 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.61 Normal Operation Normal Operation

10/09/2014 19:12 1.15 0.27 6.05 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.37 Normal Operation Normal Operation

10/09/2014 20:12 1.15 0.27 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.88 Normal Operation Normal Operation

10/09/2014 21:12 1.12 0.27 6.03 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.54 Normal Operation Normal Operation

10/09/2014 22:12 1.16 0.25 6.02 23.49 Suspension G-3 (A Line), G-5 (B Line) 948.90 Normal Operation Normal Operation

10/09/2014 23:12 1.13 0.25 5.98 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.29 Normal Operation Normal Operation

10/10/2014 00:12 1.11 0.26 5.97 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.83 Normal Operation Normal Operation

10/10/2014 01:12 1.13 0.26 5.93 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.77 Normal Operation Normal Operation

10/10/2014 02:12 1.06 0.26 5.46 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.84 Normal Operation Normal Operation

10/10/2014 03:12 1.05 0.24 5.68 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.49 Normal Operation Normal Operation

10/10/2014 04:12 1.06 0.26 6.46 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.48 Normal Operation Normal Operation

10/10/2014 05:12 1.06 0.26 6.50 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.77 Normal Operation Normal Operation

10/10/2014 06:12 1.06 0.26 6.47 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.18 Normal Operation Normal Operation

10/10/2014 07:12 1.04 0.26 6.45 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.08 Normal Operation Normal Operation

Page 2 of 2

PVC Combined Vent Section 114 Survey

11/17/2014