KiOR Compositional Profile for CAS# 1267611‐35‐7

GC/MS Summary for HDT Oil Study: PQ ‐ Characterization PQ ‐ Characterization

Location: DEMO DEMO

Client I.D.: Distillation Drum A Distillation Drum A

Light Naphtha  to 200 F Heavy Naptha to 257 F

Analyst / Reviewer: DAS ‐ JHJ / Strobel DAS ‐ JHJ / Strobel

Density (g/cm3

): 0.863 1.000

LIMS I.D.: o103441604‐A o103441607‐‐A

GC/MS Quant. Compounds BioOil BioOil

CAS bp ( ) C CH O mw wt. % wt. %

Formaldehyde 50‐00‐0 ‐21 1 2 1 30.026

Acetaldehyde 75‐07‐0 20.2 2 4 1 44.05 1.76 0.72

Cyclohexane 110‐82‐7 80.74 6 12 0 84.16

Methyl Vinyl Ketone 78‐94‐4 81.4 4 6 1 70.09 4.35

Butanal 123‐72‐8 74.8 4 8 1 72.11

2‐Butanone 78‐93‐3 79.64 4 8 1 72.11 5.07

2,5‐Dihydrofuran 1708‐29‐8 67.4 4 6 1 70.0898

Acetic Acid 64‐19‐7 118.1 2 4 2 60.05 0.85

Benzene 71‐43‐2 80.1 6 6 0 78.11 4.04 0.01

Methyl Cyclohexane 108‐87‐2 101 7 14 0 98.18

1‐hydroxy‐2‐propanone 116‐09‐6 145‐146 3 6 2 74.09

Propanoic Acid 79‐09‐4 141 3 6 2 74.08 0.30

Toluene 108‐88‐3 110.6 7 8 0 92.14 22.11 0.05

Ethyl Cyclohexane 1678‐91‐7 130‐132 8 16 0 112.21

2‐Cyclopenten‐1‐one 930‐30‐3 5 6 1 82.1 0.05 1.05

Furfural 98‐01‐1 96.08 5 4 2 96.08 0.02 0.02

Eth lb y enzene 100‐41‐4 136 8 10 0 106 167 106.167 6 76 . 0 23 .

(p+m) Xylene 106‐42‐3 138 8 10 0 106.16 25.23 1.56

108‐38‐3 139 8 10 0 106.16

Styrene 100‐42‐5 145 8 8 0 104.15 2.13 0.74

o‐Xylene 95‐47‐6 144 8 10 0 106.16 3.07 0.89

Isopropylbenzene (Cumene) 98‐82‐8 152 9 12 0 120.19 0.06 0.07

Propyl Cyclohexane 1678‐92‐8 155 9 18 0 126.24

n‐Propylbenzene 98‐82‐8 152 9 12 0 120.19 0.19 0.52

3‐Ethyltoluene 620‐14‐4 158‐159 9 12 0 120.19 0.27 0.70

4‐Ethyltoluene 622‐96‐8 162 9 12 0 120.19 2.15 7.22

1,3,5‐Trimethylbenzene 108‐67‐8 164.7 9 12 0 120.19 0.02 0.09

2‐Ethyltoluene 611‐14‐3 164‐165 9 12 0 120.19 0.03 0.17

Phenol 108‐95‐2 181 9 6 1 94.11 0.10 14.02

1,2,4‐Trimethylbenzene 95‐63‐6 169‐171 9 12 0 120.19 0.46 2.67

Benzofuran 271‐89‐6 173 8 6 1 118.1 0.50 4.44

Isobutyl Benzene 538‐93‐2 170 10 14 0 134.22 0.05

1,2,3‐Trimethylbenzene 526‐73‐8 175‐176 9 12 0 120.19 0.03 0.36

Indane 496‐11‐7 176 5. 9 10 0 118 176 118.176 0 23 . 2 51 .

Indene 95‐13‐6 175‐185 9 8 0 116.16 0.25 3.33

2‐Methylphenol (o‐cresol) 95‐48‐7 191.5 7 8 1 108.14 6.01

4‐Methylphenol (p‐cresol) 106‐44‐5 201.8 7 8 1 108.14 0.94

3‐Methylpheol (m‐cresol) 108‐39‐4 202.8 7 8 1 108.14 2.66

7‐Methylbenzofuran 17059‐52‐8 196.1 9 8 1 132.16 1.71

2‐Methylbenzofuran 4265‐25‐2 197‐198 9 8 1 132.16 2.43

2‐Ethylphenol 90‐00‐6 195‐197 8 10 1 122.16 0.38

2,5‐Dimethylphenol 95‐87‐4 212 8 10 1 122.16 1.67

1‐Methylindene 767‐59‐9 199 10 10 0 130.19 1.63

2‐Methylindene 2177‐47‐1 205.6 10 10 0 130.19 0.01 1.68

3‐Ethylphenol 620‐17‐7 8 10 1 122.16 0.07

4‐Ethylphenol 123‐07‐9 218 8 10 1 122.16 0.16

2,3‐Dimethylphenol 526‐75‐0 217 8 10 1 122.16 0.09

3,4‐Dimethylphenol 96‐65‐8 227 8 10 1 122.16 0.02

1,2‐Benzenediol (catechol) 120‐80‐9 245 6 6 2 110.11

5‐(Hydroxymethyl) furfural 67‐47‐0 6 6 3 126.11

1‐Indanol Indanol 697‐64‐3 9 10 1 134 18 .

3‐Methyl‐1,2‐benzenediol 488‐17‐5 241 7 8 2 124.14

1,4‐Benzenediol (hydroquinone) 123‐31‐9 285 6 6 2 110.11

1,3‐Benzenediol (Resorcinol) 108‐46‐3 6 6 2 110.11

4‐Methyl‐1,2‐benzenediol 452‐86‐8 251 7 8 2 124.14

Decahydronaphthalene (trans‐) 493‐02‐7 185 10 18 0 138.25

Decahydronaphthalene (cis‐) 493‐01‐6 193 10 18 0 138.25

Tetrahydronaphthalene 119‐64‐2 207 10 12 0 132.2

Naphthalene 91‐20‐3 218 10 8 0 128.17 1.33

2‐Methylnaphthalene 91‐57‐6 241‐242 11 10 0 142.2 0.34

david.strobel Page 1 4/13/2011
KiOR Compositional Profile for CAS# 1267611‐35‐7

GC/MS Summary for HDT Oil Study: PQ ‐ Characterization PQ ‐ Characterization

Location: DEMO DEMO

Client I.D.: Distillation Drum A Distillation Drum A

Light Naphtha  to 200 F Heavy Naptha to 257 F

Analyst / Reviewer: DAS ‐ JHJ / Strobel DAS ‐ JHJ / Strobel

Density (g/cm3

): 0.863 1.000

LIMS I.D.: o103441604‐A o103441607‐‐A

GC/MS Quant. Compounds BioOil BioOil

CAS bp ( ) C CH O mw wt. % wt. %

1‐Methylnaphthalene 90‐12‐0 240‐243 11 10 0 142.2 0.02

Eugenol 97‐53‐0 254 10 12 2 164.2

2‐Ethylnaphthalene 939‐27‐5 251‐252 12 12 0 156.22

2,6‐Dimethylnaphthalene 581‐42‐0 262 12 12 0 156.22

2,7‐Dimethylnaphthalene 582‐16‐1 263 12 12 0 156.22

1‐Naphthalenol 90‐15‐3 278‐280 10 8 1 144.17

2‐Naphthalenol 135‐19‐3 285‐286 10 8 1 144.17

Acenap y hth lene 208‐96‐8 280 12 8 0 152.19

Levoglucosan 498‐07‐7 6 10 5 162.14

Acenaphthene 83‐32‐9 279 12 10 0 154.21

Fluorene 86‐73‐7 298 13 10 0 166.22

Phenanthrene 85‐01‐8 340 14 10 0 178.23

Anthracene 120‐12‐7 340 14 10 0 178.23

Fluoranthene 206‐44‐0 384 16 10 0 202.25

Pyrene 129‐00‐0 404 16 10 0 202.25

Benz[a]anthracene 56‐55‐3 437.6 18 12 0 228.29

Chrysene 218‐01‐9 448 18 12 0 228 29 .

Benzo[b]fluoranthene 205‐99‐2 20 12 0 252.31

Benzo[k]fluoranthene 207‐08‐9 480 20 12 0 252.31

Benzo[a]pyrene 50‐32‐8 495 20 12 0 252.31

Indeno[123‐cd]pyrene 193‐39‐5 497.1 22 12 0 276.33

Dibenz[a,h]anthracene 53‐70‐3 524 22 14 0 278.35

Benzo[ghi]perylene 191‐24‐2 > 500 22 12 0 276.33

GC/MS Semi‐Quant. Compounds

CAS bp (C) C H O mw wt. % wt. %

2‐Methylbenzaldehyde 529‐20‐4 199 8 8 1 120.06

2,3‐Dihydrobenzofuran 496‐16‐2 188 8 8 1 120.06

2‐Ethyl‐5‐methylphenol 1687‐61‐2 9 12 1 136.09

2,2'‐Bifuran 5905‐00‐0 8 6 2 134.04

1H‐Indenol 56631‐57‐3 9 8 1 132.06

1,3‐Dimethylindene 2177‐48‐2 11 12 0 144.09 0.69

Retene 483‐65‐8 390 18 18 0 234.34

david.strobel Page 2 4/13/2011