## UNITED STATES ENVIRONMENTAL PROTECTION AGENCY RAW DATA MAX VALUES REPORT Nov. 25, 2014 Report Request ID: 1272142 Report Code: AMP350MX

Selection Criteria Page 1 User ID: RMV

State County City Site Parameter POC AQCR UAR CBSA CSA EPA Region 46 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration CRITERIA 88101 7 X SELECTED OPTIONS
SINGLE EVENT PROCESSING MERGE PDF FILES AGENCY ROLE Option Type Option Value INCLUDE EVENTS YES PQAO SORT ORDER
1 2 3 4 5 Order Column

STATE_CODE COUNTY_CODE SITE_ID PARAMETER_CODE POC DATE CRITERIA
2009 Start Date End Date 2009 01 01 12 31 Tribal Code

APPLICABLE STANDARDS Standard Description PM25 24-hour 2013Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 1 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-011-0002 SITE ID: 1 POC: (206) SOUTH DAKOTA AQCR: (011) Brookings COUNTY: (07580) Brookings CITY: -96.80071 LONGITUDE: 44.310283 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: BROOKINGS CITY HALL BUILDING SITE ADDRESS: COMMERCIAL LAND USE: MONITOR PURCHASED BY BROOKINGS HEALTH DEPARTMENT SITE COMMENTS: MONITOR COMMENTS: 7 PROBE HEIGHT: 501 ELEVATION-MSL: 14

4908468.06 UTM NORTHING: (0000) NOT IN AN URBAN AREA 675410.76 UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: MULTIPLE METHODS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 4.8
7.0
11.1
9.5
6.3
14.4

5.7
25.7
12.3
10.1
2.8 NO.: MAX: MEAN: 11

25.7 9.97 6.4

21.6
14.9
7.6
8.4
5.8
12.5
15.0
5.6 10.8

31.2
9.5
6.3
10.7
7.4
12.5
17.0
4.7
6.0 7.1

6.7
5.4
6.8
9.8

4.5
10.6
5.0
6.4 5.4

7.6
4.4
4.1
3.3
4.1
7.9
8.4
9.8
4.2
6.1 6.8

3.8
4.8
6.3
9.6
4.8
5.2
8.2
7.0
4.6 8.4

6.6

6.4
5.0
4.3
5.8
5.8
7.2
5.2 6.2

4.9
10.4
7.6
13.1
3.5
3.6
7.4
6.6
4.7 7.1

16.4
16.4
20.5
13.7
15.1
12.9
3.0
5.8
3.0 5.1

2.0
3.5
2.3
6.9
4.0
5.3
3.2
3.7
10.6
6.6 4.3

10.1
6.1
17.2

12.5 15.4
17.6
6.3
9.1
5.8 3.4

7.1
5.0
25.1
6.5
P 39.0
11.5

5.7
3.1
17.5
9 21.6 10.87 10

31.2 11.61 9

10.6 6.92 11

9.8 5.94 10

9.6 6.11 9

8.4 6.08 10

13.1 6.80 10

20.5 11.39 11

10.6 4.84 10

17.6 10.44 10

39.0 12.39 ANNUAL OBSERVATIONS: 120 ANNUAL MEAN: 8.59 ANNUAL MAX: 39.0 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 2 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-013-0003 SITE ID: 1 POC: (206) SOUTH DAKOTA AQCR: (013) Brown COUNTY: (00100) Aberdeen CITY: -98.486111 LONGITUDE: 45.4625 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: 111 2ND AVE SE FIRE STATION #1 ABERDEEN SITE ADDRESS: COMMERCIAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 10 PROBE HEIGHT: 406 ELEVATION-MSL: 14

5034241 UTM NORTHING: (0000) NOT IN AN URBAN AREA 540176 UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: MULTIPLE METHODS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 5.2
7.2
13.0
13.0
4.8
9.0
6.0
23.0
12.5

7.7
2.5 NO.: MAX: MEAN: 11

23.0 9.45 8.3

12.4
16.4
8.1
11.8
3.5
8.4
16.0
3.9 11.1

23.4
6.2
10.3
8.1
8.0
10.6
19.1
4.4
6.8 5.3

7.6
6.0
9.9
10.1
5.0
6.8
7.4

7.7 6.8

5.7
4.5
3.9
4.5
3.9

5.0 6.9
8.2
6.0
6.1 7.5

3.1
4.4
6.0
6.6
4.1
5.2
4.5
4.9
3.5 5.9

6.3
7.0
6.4
5.8
5.1
9.1

7.5
8.3
5.3 8.4

5.8
9.5
7.9
11.9
4.0
4.6
5.3
9.7
5.3 9.4

14.4
20.7
12.4
11.2
19.9
13.1
3.0
9.3
3.2 5.6

3.0
4.3
3.1
5.8

3.3
3.0
7.1
8.9
5.8 4.6

8.4
5.4
9.2
10.6
14.8
9.4
8.1
9.1
5.8 3.8

4.5
8.0
12.6
4.5
30.2
16.3
8.0
3.8
12.7
9 16.4 9.87 10

23.4 10.80 9

10.1 7.31 11

8.2 5.59 10

7.5 4.98 10

9.1 6.67 10

11.9 7.24 10

20.7 11.66 10

8.9 4.99 10

14.8 8.54 10

30.2 10.44 ANNUAL OBSERVATIONS: 120 ANNUAL MEAN: 8.11 ANNUAL MAX: 30.2 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 3 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-029-0002 SITE ID: 1 POC: (206) SOUTH DAKOTA AQCR: (029) Codington COUNTY: (69300) Watertown CITY: -97.128802 LONGITUDE: 44.89965 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: 801 4TH AVE SW - WATERTOWN SITE ADDRESS: COMMERCIAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 4.6 PROBE HEIGHT: 524 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: (153) Thermo Electron Model RAAS2.5-100 REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 4.7
6.6

9.1
9.8
18.0
5.8
23.1
10.0
8.5
2.7 NO.: MAX: MEAN: 10

23.1 9.83 6.5

15.6
7.8

7.5

5.7
6.9
14.7
3.6 9.3

32.4
8.3
6.6
9.6
7.6
10.9
6.1
6.6
9.6 6.3

4.1

7.2
9.2
13.5

8.3
8.1
7.3 8.1

8.3
5.3
5.0
5.3
3.9
9.5
8.4
7.6
4.8
7.3 7.2

3.0
6.6
7.1
9.0
5.4
5.9
6.2
5.4
5.0 7.4

6.2
8.5
8.6
5.4
5.6
6.9
9.7
7.1
6.9 8.3

5.8
10.2
7.8
15.1
3.8
3.7
6.5
8.1

5.5 8.3

15.9
18.0
18.8
13.9
12.7
13.0
2.0

5.5
2.8 5.0

2.3
3.7
2.3
6.0
3.7
4.2
2.5
4.3
14.6
6.6 7.1

12.9
13.8
16.7
13.4
13.8
14.9
6.3
9.8
5.0 3.3

5.4
4.7
13.3
5.4
P 37.8
12.8
4.5
2.2
12.8
8 15.6 8.54 10

32.4 10.70 8

13.5 8.00 11

9.5 6.68 10

9.0 6.08 10

9.7 7.23 10

15.1 7.48 10

18.8 11.09 11

14.6 5.02 10

16.7 11.37 10

37.8 10.22 ANNUAL OBSERVATIONS: 118 ANNUAL MEAN: 8.48 ANNUAL MAX: 37.8 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 4 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-033-0132 SITE ID: 1 POC: (205) BLACKHILLS-RAPID CITY AQCR: (033) Custer COUNTY: (00000) Not in a city CITY: -103.48386 LONGITUDE: 43.5576400009 LATITUDE:

RURAL LOCATION SETTING: WIND CAVE NATIONAL PARK, SOUTH DAKOTA SITE ADDRESS: FOREST LAND USE: SITE COMMENTS: MONITOR COMMENTS: 2.7 PROBE HEIGHT: 1288 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0745) National Park Service MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: (119) Andersen RAAS2.5-100 PM2.5 SAM w/W REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 1.4
1.1
1.2
1.6
1.4
2.3
1.4
1.8
3.1
1.8
1.5 NO.: MAX: MEAN: 11

3.1 1.69 2.2

2.8

2.5
5.8
8.2
2.7

2.9 3.7 2.2

6.0
1.5

2.3
4.4
3.4

4.3
3.8 3.5

2.6

2.8
4.0

2.6 2.6

2.8
2.3
2.2
2.9
5.2
4.6

5.5 8.3

4.5
4.5 2.1

3.3
3.7
3.7
4.8
5.0
4.1 3.6

3.3
4.0
4.9
4.6

4.3

5.7
5.6
7.4 5.4

6.3
3.7
5.0
5.9
3.1
2.6
5.6
5.1
6.5 6.9

P 120.5 +
17.4
9.6

7.6

7.5
1.8
4.2
2.2 2.8

3.4
3.0

.7
1.9
2.4
2.6
2.1
1.3
1.1
3.1 2.3

2.6
1.6
4.8
2.6
2.0
3.3
1.2
1.2
1.2 2.7

7.7
4.6
2.0

.7
2.6
2.4
1.3
2.1
8 8.2 3.85 8

6.0 3.49 5

4.0 3.10 11

8.3 4.13 7

5.0 3.81 9

7.4 4.82 10

6.5 4.92 9

120.5 19.74 11

3.4 2.22 10

4.8 2.28 9

7.7 2.90 ANNUAL OBSERVATIONS: 108 ANNUAL MEAN: 4.71 ANNUAL MAX: 120.5 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 5 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-033-0132 SITE ID: 3 POC: (205) BLACKHILLS-RAPID CITY AQCR: (033) Custer COUNTY: (00000) Not in a city CITY: -103.48386 LONGITUDE: 43.5576400009 LATITUDE:

RURAL LOCATION SETTING: WIND CAVE NATIONAL PARK, SOUTH DAKOTA SITE ADDRESS: FOREST LAND USE: SITE COMMENTS: MONITOR COMMENTS: 4.3 PROBE HEIGHT: 1288 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0745) National Park Service MONITOR TYPE: SPM COLLECTION AND ANALYSIS METHOD: (170) Met One BAM-1020 Mass Monitor w/VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24-HR BLK AVG Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 3.3 3.8 7.5 4.2 4.4 3.6 3.5

3.5 3.7 4.5 4.2 3.3 3.8 3.7 6.6 6.0 7.3 6.5 6.1 3.9 4.1 3.9 4.9 NO.: MAX: MEAN: 23

7.5 4.62 3.5

5.0 4.8 4.0 4.4 5.1 7.6 7.8 8.6 4.7 5.0 4.7 5.2 8.1 7.1 4.3 6.2 10.6 5.9 4.8 5.1 5.6 5.9 5.7 5.2 9.1 7.2 6.1 5.5

4.9 7.2 6.0 12.4 5.7 6.2 5.6 7.7 6.5 7.7 7.0 6.0 6.4 8.1 6.7 9.5 7.8 9.2 8.2 17.1 9.6 8.2 7.7 9.0 8.8 2.4

5.2 4.2 5.2 5.5 2.4 2.9 3.9 5.7 7.5 6.9 1.1 2.5 15.2 3.2 1.8 3.9 3.2 4.2 2.5 2.3 4.5 4.0 1.6 1.8 4.3 5.6 4.4 1.6 2.4

3.3 3.0 2.9 3.3 2.3 2.0 .9 2.8 2.3 2.9 7.3 4.4 3.2 4.3 4.9 6.1 4.5 5.6 6.8 4.8 7.4 8.9 5.1 4.6 5.9 7.6 5.9 4.5 4.3 5.2 6.7

5.7 6.0 5.3 4.8 2.9 1.6 3.0 2.7 2.7 2.7 2.8 4.7 5.0 4.7 4.5 5.0 5.0 13.3 6.2 4.7 5.9 5.6 6.5 6.3 6.1 5.7 6.0 6.7 5.9 6.4

5.5 4.8 4.9 4.3 3.7 5.8 7.4 6.6 4.8 7.5 6.7 7.3 4.7 5.7 4.8 5.4 5.2 6.1 4.9 4.3 4.3 5.9 7.6 6.0 5.5 4.7 8.0 4.7 7.8 6.5 4.7

5.8 8.3 8.2 6.3 7.5 6.6 4.4 2.4 5.7 6.7 6.1 6.4 6.9 3.7 2.5 3.9 4.5 3.2 2.5 2.5 3.7 7.7 6.1 5.5 4.7 4.6 7.1 7.5 6.1 6.0 7.1

4.9 P 112.6 + P 303.6 + P 121.8 + P 37.8 + 19.3 + 12.1 7.7 6.1 4.4 3.3 6.0 6.8 7.4 10.0 7.8

1.3

4.0 5.1 3.3

3.2 2.4 2.8 .7 1.1 3.1 2.0 1.8 2.1 .9 2.9 1.0 1.8 3.0 2.3 1.6 2.0 3.1 3.5 1.2 1.8 1.9 2.0 1.9 2.1 .9 2.0 2.0 2.0 1.8 2.6

4.2 3.5 2.8 2.3 2.0 2.3 2.1 3.1 3.9 3.5 2.4 2.4 2.6 2.3 1.4 1.2 3.1 2.5 3.4 2.0 .9 1.2 2.0 1.5 .8 1.9 1.2 .5

1.7 2.8 2.0 2.4 7.9 4.6 3.4 4.2 1.6 1.8 1.3 5.0 5.8 6.1 1.5 1.9 .3 1.2 1.4 2.6 1.9 3.2 2.9 3.5 1.1 1.6 2.3 2.6 2.0 7.0 28 10.6 5.98 26

17.1 7.87 29

15.2 4.12 31

8.9 4.50 30

13.3 5.16 31

8.0 5.74 31

8.3 5.41 20

303.6 34.46 31

3.5 2.07 28

4.2 2.33 31

7.9 2.84 ANNUAL OBSERVATIONS: 339 ANNUAL MEAN: 6.32 ANNUAL MAX: 303.6 4 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 4 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 6 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-071-0001 SITE ID: 3 POC: (206) SOUTH DAKOTA AQCR: (071) Jackson COUNTY: (00000) Not in a city CITY: -101.941218 LONGITUDE: 43.74561 LATITUDE:

RURAL LOCATION SETTING: BADLANDS PO BOX 6 HEADQUARTERS SITE ADDRESS: AGRICULTURAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 3.6 PROBE HEIGHT: 742 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: (170) Met One BAM-1020 Mass Monitor w/VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24-HR BLK AVG Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 .0 5.4 5.3 1.5 .0 .7 .5 6.6 5.2 2.0 .2 4.8 2.6 4.0 2.4 1.4 .0 .9 .0 .1 .7 1.9 3.4 2.6 2.8 1.9 2.7 2.3 1.1 .1 1.2 NO.: MAX: MEAN: 31

6.6 2.07 1.0

2.3 3.6 .6 .0 .0 4.5 6.0 5.0 1.2 1.0 1.5 1.2 2.5 3.6 3.3 4.8 8.0 4.1 2.0 2.7 .3 2.2 1.5 6.7 5.9 2.7 4.1 5.9

6.8 7.4 3.4 5.5 5.2 5.5 4.5 5.8 5.4

2.4 2.7 4.2 9.0 10.4 5.9 10.2 5.0 4.5 2.8 3.4 3.3 6.1 5.8 4.4

2.3 5.2 5.0 4.5 5.7 4.1 4.0 7.2 5.3 6.1 17.0 3.0 4.0 13.9 3.7 3.0 4.7 2.9 2.2 2.2 1.5 3.1 4.7 5.0 4.3 4.1 4.5 5.7 1.9 5.1

3.9 9.3 2.3 3.7 1.0 2.8 2.7 2.2 4.0 3.7 5.1 3.3

4.8 3.4 5.7 6.6 9.5 4.1 4.8 3.3 3.8 3.8 4.3

3.4 4.0 1.8 .4 1.1 4.0 3.7 2.6 2.8 3.1 3.7 1.1 1.9 3.8 4.1 4.1 3.5 4.0 4.8 4.9 4.4 5.5 5.5 4.7 4.4 3.4 3.7

5.0 4.0 2.2 1.9 2.7 4.7 5.2 3.3 2.0 3.4 6.2 4.8 2.2 2.3 2.0 2.6 2.1 4.7 5.4 2.6 2.6 4.6 5.8 5.6 6.0 6.3 7.1 6.3 5.6 6.4 4.5

8.1 8.8 4.6 5.3 6.1 5.5 4.0 2.3 5.5 5.9 6.1 5.7 6.0 4.0 2.6 2.8 4.0 2.7 2.6 1.9 3.8 6.7 6.0 5.4 4.0 5.9 8.3 5.6 5.0 5.8 8.1

5.7 7.3 4.3 8.6 10.4 9.0 6.3 2.4 6.6 3.2 1.8 14.0 15.9 16.4 11.0 7.7 8.2 5.8 7.3 1.9 1.8 2.7 3.3 1.9 3.3 4.1 1.1 3.9 3.8 3.0

3.5 2.1 2.0 1.1 2.8 3.1 2.2 2.7 1.2 1.6 3.3 2.7 2.8 4.0 3.3 2.1 1.8 3.1 3.8 1.6 1.7 1.6 2.1 3.1 .7 1.2 1.7 2.2 2.5 1.4 1.5

3.2 4.0 3.0 2.9 2.4 .8 2.6 1.0 6.0 7.9 6.2 3.2 2.7 2.5 1.7 1.2 1.6 1.9 1.5 3.8 1.2 1.3 1.4 2.8 1.1 2.7

2.3 3.9 3.4 4.8 7.1 4.4 5.2 5.6 3.1 2.1 3.1 4.6 4.7 5.5 2.6 1.5 2.0 1.0 2.4 8.9 10.3 10.4 3.3 4.2 3.3 3.0 3.3 4.2 3.6 8.8 28 8.0 2.94 24

10.4 5.46 30

17.0 4.84 23

9.5 4.30 27

5.5 3.52 31

7.1 4.17 31

8.8 5.02 30

16.4 6.26 31

4.0 2.32 26

7.9 2.67 31

10.4 4.36 ANNUAL OBSERVATIONS: 343 ANNUAL MEAN: 3.98 ANNUAL MAX: 17.0 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 7 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-099-0006 SITE ID: 1 POC: (087) METROPOLITAN SIOUX FALLS AQCR: (099) Minnehaha COUNTY: (59020) Sioux Falls CITY: -96.726435 LONGITUDE: 43.544289 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: 500 S. PHILLIPS KELO SITE SITE ADDRESS: COMMERCIAL LAND USE: SITE ON ROOF OF KELO RADIO STATION GOOD PLACE FOR MONITOR SITE COMMENTS: MONITOR COMMENTS: 5 PROBE HEIGHT: 442 ELEVATION-MSL: 14

4823550.8 UTM NORTHING: (7760) SIOUX FALLS, SD 683678.21 UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: MULTIPLE METHODS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 3.8
5.8
13.4
9.9
5.6
11.1
5.9
18.6
9.9
10.6
3.6 NO.: MAX: MEAN: 11

18.6 8.93 6.0

19.8
15.6
4.5
7.0
6.8
9.3
15.6
6.2 10.6

30.2
9.5
6.2
12.0
8.2
11.7
17.0
6.2

7.5 6.3

6.1
7.3
8.2
9.1
9.6
4.0
11.1
6.3
9.2 5.8

8.6
3.5
5.3

5.5
3.8
7.1
10.6
11.2
6.6
5.8 8.2

5.3
10.3
11.6
14.4
8.0
8.6
7.9
7.3
4.1 9.0

6.7
10.8
7.3
6.1
3.9
7.6
8.1
8.2
6.1 6.2

5.0
10.3
9.6
13.1
4.3
4.2
7.1
6.3
5.3 7.5

17.8
16.7
19.6
14.3
15.9

2.9 5.9 7.8
3.0 5.0

2.1
3.5
2.2
6.3
5.0
8.0
4.5
4.0
9.9
6.3 4.8

8.1
7.6
18.4
15.9
21.1
17.6
8.2
9.6
4.3 3.7

10.3
6.9
22.2
6.8
P 42.7
12.8
8.4
4.3
20.2
9 19.8 10.09 10

30.2 11.91 10

11.1 7.72 11

11.2 6.71 10

14.4 8.57 10

10.8 7.38 10

13.1 7.14 10

19.6 11.14 11

9.9 5.16 10

21.1 11.56 10

42.7 13.83 ANNUAL OBSERVATIONS: 122 ANNUAL MEAN: 9.12 ANNUAL MAX: 42.7 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 8 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-099-0008 SITE ID: 1 POC: (087) METROPOLITAN SIOUX FALLS AQCR: (099) Minnehaha COUNTY: (59020) Sioux Falls CITY: -96.700769 LONGITUDE: 43.54792 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: 2001 E 8th St SITE ADDRESS: COMMERCIAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 5 PROBE HEIGHT: 451 ELEVATION-MSL: UTM NORTHING: (7760) SIOUX FALLS, SD UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: (142) BGI Models PQ200-VSCC or PQ200A-VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 4.8
6.1
14.2
10.2
5.6
12.3
6.1
18.1
10.3
9.7
4.3 NO.: MAX: MEAN: 11

18.1 9.25 6.2

21.9
15.5
5.2
7.3
9.3
9.5
15.0
5.8 11.0

28.1
9.0
7.0
11.6
6.6
12.1

7.9
8.0 6.4

6.0

7.5
7.0
9.8
10.2
4.6
11.2
6.3
8.5 6.0

8.5
3.2

5.7
4.2
6.7
8.4
11.4
11.3
7.3
6.7 7.8

3.7
6.0
5.6
13.0

4.8 5.6

5.7
8.7
5.1 9.9

6.4
10.8
6.7
5.6
4.2
6.4
7.8
8.3
5.8 6.5

4.4
10.3
11.3
13.1
5.6
4.3
7.6
5.2
5.6 7.8

18.0
16.3
20.0
14.0
14.7
12.4
2.7
6.9
3.8 4.9

2.8
3.8
2.7
6.2
3.5
6.3
4.4
5.2
10.5
6.2 4.7

8.3

7.5
18.6
16.0
17.4
21.1
7.6
10.6
4.8 4.8

9.2
8.0
21.5
7.0
P 42.0
11.5
7.9
3.1
19.8
9 21.9 10.63 9

28.1 11.26 10

11.2 7.75 11

11.4 7.22 10

13.0 6.60 10

10.8 7.19 10

13.1 7.39 10

20.0 11.66 11

10.5 5.14 10

21.1 11.66 10

42.0 13.48 ANNUAL OBSERVATIONS: 121 ANNUAL MEAN: 9.02 ANNUAL MAX: 42.0 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 9 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-099-0008 SITE ID: 3 POC: (087) METROPOLITAN SIOUX FALLS AQCR: (099) Minnehaha COUNTY: (59020) Sioux Falls CITY: -96.700769 LONGITUDE: 43.54792 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: 2001 E 8th St SITE ADDRESS: COMMERCIAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 4 PROBE HEIGHT: 451 ELEVATION-MSL: UTM NORTHING: (7760) SIOUX FALLS, SD UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SPM COLLECTION AND ANALYSIS METHOD: (170) Met One BAM-1020 Mass Monitor w/VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24-HR BLK AVG Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 3.2 7.6 13.6 4.9 2.9 5.3 12.7 6.6 13.4 9.2 10.9 7.6 4.2 7.3 9.8 10.6 5.5 5.4 5.0 4.5 11.9 14.1 10.0 8.8 9.8 6.0 8.9 8.3 7.7 9.6 2.8 NO.: MAX: MEAN: 31

14.1 8.00 1.4

3.3 4.9 8.3 15.2 19.3 10.9 10.8 14.9 5.6 8.5 5.5 8.4 7.9 6.7 10.9 21.4 7.0 6.5 17.8 10.3 5.9 6.4 15.9 16.2 7.2 6.1 6.0 9.2

9.6 12.9 24.6 27.4 6.0 7.1 9.2 6.3 7.4 6.6 8.1 9.0 11.3 16.7

16.0 24.4 16.7 2.7 4.6 7.5 4.1 7.2 7.8 7.2 7.4 6.4

5.0 5.4 5.5 3.4 4.2 7.7 9.4 6.8 8.6 12.2 11.2 9.7 9.2 12.9 10.5 15.7 6.9 5.3 4.4 5.3 12.7 12.0 7.3 6.8 3.5 5.5 8.5 10.7 5.7 5.9

9.7 9.8 9.0 12.0 9.0 4.9 8.8 5.0 7.3 6.4 10.1 5.2 6.7 8.4 6.5 8.2 7.1 9.9

8.8 6.5 9.2 7.1 8.6

6.1 7.9 6.9 6.9 3.7 2.8 3.9 6.3 6.1 6.4 10.6 9.5 11.9 13.6 13.4 11.3 5.8 7.1 8.2 7.6 6.7 10.4 9.0 10.6 11.5 9.0 6.0 6.3 4.9 8.5

9.3 10.5 11.1 8.6 7.7 7.1 9.5 12.9 7.5 8.3 8.1 7.9 11.5 6.7 7.0 5.0 5.4 5.2 10.0 9.2 10.7 10.9 8.6 7.6 5.0 8.4 8.4 8.9 8.1 8.1 7.2

6.6 12.9 6.5 5.6 7.5 12.6 11.0 7.3 5.7 9.4 11.4 9.1 13.4 19.9 5.6 5.8 5.6 5.2 5.2 6.0 5.9 7.9 13.6 6.6 5.2 5.9 6.3 4.7 3.2 3.1 7.4

11.2 16.2 18.2 21.2 20.6 17.0 18.0 14.0 18.6 14.9 10.3 13.2 18.6 15.5 13.6 16.8 15.8 11.3 13.0 6.1 1.6 4.4 7.4 7.1 5.4 4.5 3.6 4.0 5.0 4.5

1.9 2.5 2.2 3.3 3.8 3.5 3.0 4.3 2.4 3.5 6.5 5.0 8.5 5.5 4.5 4.2 6.5 7.6 11.5 2.6 4.7 4.2 5.9 6.1 3.2 4.4 9.7 5.7 3.1 6.7 5.0

4.1 4.7 7.0 6.4 9.5 7.3 7.1 8.6 8.5 8.4 17.9 12.3 12.2 16.2 13.9 13.8 17.0 23.3 16.2 16.8 20.5 18.4 7.4 9.3 7.5 7.7 13.6 9.4 5.6 4.3

6.5 5.3 7.3 10.7 10.2 5.3 7.8 6.7 7.2 9.7 22.0 8.8 6.7 6.5 19.9 32.6 P 43.9

25.8 14.1 9.2 5.1 4.9 4.6 7.5 17.8 21.7 9.9 28 21.4 9.61 26

27.4 10.65 30

15.7 7.95 23

12.0 7.89 30

13.6 7.97 31

12.9 8.44 31

19.9 7.80 30

21.2 11.82 31

11.5 4.87 30

23.3 11.19 28

43.9 12.21 ANNUAL OBSERVATIONS: 349 ANNUAL MEAN: 9.00 ANNUAL MAX: 43.9 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 10 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-103-0020 SITE ID: 1 POC: (205) BLACKHILLS-RAPID CITY AQCR: (103) Pennington COUNTY: (52980) Rapid City CITY: -103.273777 LONGITUDE: 44.087397 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: CREDIT UNION SITE, 106 KINNEY AVE. SITE ADDRESS: COMMERCIAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 4.4 PROBE HEIGHT: 1042 ELEVATION-MSL: UTM NORTHING: (6660) RAPID CITY, SD UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: MULTIPLE METHODS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 2.3
5.2
6.2
4.7
3.9
5.8
2.2
8.4
5.0
2.1
3.4 NO.: MAX: MEAN: 11

8.4 4.47 9.6

7.1
8.1
4.8
7.1
11.1
4.7
4.5
5.4 9.4

14.3
6.2
9.3

5.5

5.5
7.0
9.0
4.2
4.0 15.2

5.8

7.7
5.2

4.0 2.3
4.8
4.8
3.4

5.5 5.3

3.7
4.1
4.3
4.1

5.5
12.1
10.5
7.4
7.6
6.7 6.5

3.9
3.9
6.5
7.1
8.8
6.2

7.9 7.7
6.5 7.6

4.5

5.7
7.8
7.6
6.2
4.8
9.4
7.8
9.5 8.1

16.1
5.6
8.8
10.1
5.6
4.6
7.2
6.5
3.1 10.3

9.0
9.5

7.7
6.8
14.0
9.0
6.1
7.1
3.7 4.4

5.0

5.5 4.4
2.5
13.9
4.8
3.9
3.1
3.3
2.9 5.3

4.3
3.0
12.4
5.3
10.4
4.6
3.0

7.1 4.8 6.5

12.3
12.7
11.2
13.2
2.1
6.6
5.4
4.1
11.9
9 11.1 6.93 10

14.3 7.44 10

15.2 5.87 11

12.1 6.48 10

8.8 6.50 10

9.5 7.09 10

16.1 7.57 10

14.0 8.32 11

13.9 4.88 10

12.4 6.02 10

13.2 8.60 ANNUAL OBSERVATIONS: 122 ANNUAL MEAN: 6.65 ANNUAL MAX: 16.1 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 11 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-103-0020 SITE ID: 3 POC: (205) BLACKHILLS-RAPID CITY AQCR: (103) Pennington COUNTY: (52980) Rapid City CITY: -103.273777 LONGITUDE: 44.087397 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: CREDIT UNION SITE, 106 KINNEY AVE. SITE ADDRESS: COMMERCIAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 4.4 PROBE HEIGHT: 1042 ELEVATION-MSL: UTM NORTHING: (6660) RAPID CITY, SD UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SPM COLLECTION AND ANALYSIS METHOD: (170) Met One BAM-1020 Mass Monitor w/VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24-HR BLK AVG Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 2.1 .6 7.6 3.0 10.7 2.8 4.7 6.1 8.0 1.8 .9 6.5 1.8 5.0 3.5 4.4 .3 -.3 1.5 4.7 7.2 9.6 7.2 2.1 2.2 5.1 13.3 .7 .1 1.8 1.8 NO.: MAX: MEAN: 31

13.3 4.09 1.2

3.0 8.3 6.1 8.2 7.7 8.5 4.5 6.9 3.0 2.9 3.2 2.1 3.4 4.2 6.6 8.3 9.2 6.3 1.9 4.0 2.8 8.2 2.9 5.0 6.2 2.5 8.2 5.6

5.8 9.4 4.7 4.1 3.1 2.7 4.9 4.2 4.6 7.4 11.0

12.8 13.2 17.5 15.1 10.5 9.3 12.3 10.8 9.8 11.2 10.5 10.3 12.1 16.8

22.3 13.6 11.5 11.3 16.7 15.3 11.7 6.6 3.8 4.8 5.4 3.6 3.1 14.2 2.0 4.1 5.8 4.6 4.3 5.6 3.9 5.8 6.2 1.9 4.3 3.7 3.8 5.9 2.9 4.5

3.0 3.0 3.3 2.0 3.6 2.9 4.0 4.0 2.2 4.5 9.2 3.3 3.3 5.1 3.3 4.7 5.4 11.3 7.9 4.9 9.1 10.0 8.6 7.3 10.2 6.1 6.7 5.5 4.5 5.2 8.4

7.9 4.6 5.0 6.3 2.3 2.7 3.2 2.4 3.5 2.1 4.4 4.8 4.1 8.2 5.5 6.3 10.5 8.0 6.1 7.4 6.1 7.8 10.7 8.8 10.4 9.4 6.0 9.3 7.3 10.7

11.1 9.4 18.4 6.4 4.8 11.6 7.9 7.4 8.7 8.7 11.8 12.3 8.4 9.6 9.5 10.5 7.0 7.8 13.1 5.5 6.4 9.7 16.8 10.2 11.3 11.8 9.2 7.9 10.1 11.4 7.4

11.1 14.8 7.8 9.1 9.3 13.2 9.8 6.1 11.0 11.3 10.8 9.9 14.0 8.1 3.8 6.7 7.0 5.9 4.5 3.5 5.3 8.8 12.4 5.6 7.1 7.5
6.4 6.7 9.3

11.5 8.6 9.4 8.2 9.2 10.1 8.6 3.0 9.1 5.2 3.2 5.2 9.8 10.6 12.8 6.6 6.5 6.7 6.6 1.0 2.0 5.8 4.1 4.6 5.3 3.5 .5 1.9 5.7 2.5

2.4 2.7 1.7 2.1 4.6 4.4 2.3 1.1 1.9 .3 1.8 -.1 2.8 5.7 10.5 1.9 6.0 2.0 7.6 4.5 .2 2.8 1.2 1.2 1.6 3.7 .6 1.4 2.5 1.9 3.3

3.2 4.2 2.7 5.7 3.1 2.1 3.2 .6 3.1 2.5 9.6 4.6 4.6 2.5 2.0 4.3 7.6 3.2 1.8 3.2 .3 1.4 2.1 3.1 3.7 2.8 3.3 2.4 1.9 2.2

2.7 2.2 4.4 8.1 8.9 3.8 5.8 8.9 2.8 4.2 6.9 6.3 6.1 11.2 14.7 5.3 .9 4.7 3.1 3.4 1.9 3.9 3.9 2.1 .2 3.0 6.8 15.0 8.1 7.6 28 9.2 5.19 25

17.5 8.92 30

22.3 7.52 31

11.3 5.44 30

10.7 6.32 31

18.4 9.85 29

14.8 8.44 30

12.8 6.49 31

10.5 2.77 30

9.6 3.27 31

15.0 5.45 ANNUAL OBSERVATIONS: 357 ANNUAL MEAN: 6.10 ANNUAL MAX: 22.3 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 12 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-103-1001 SITE ID: 1 POC: (205) BLACKHILLS-RAPID CITY AQCR: (103) Pennington COUNTY: (52980) Rapid City CITY: -103.22824 LONGITUDE: 44.078352 LATITUDE:

URBAN AND CENTER CITY LOCATION SETTING: CITY LIBRARY 6TH AND QUINCY SITE ADDRESS: COMMERCIAL LAND USE: SITE STARTED OPERATION 4-3-72 SITE COMMENTS: PM2.5 AMBIENT MAIN MONITOR COMMENTS: 7 PROBE HEIGHT: 988 ELEVATION-MSL: UTM NORTHING: (6660) RAPID CITY, SD UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: MULTIPLE METHODS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 2.3
5.8
6.0
5.9
4.8
9.9
1.6
6.7
4.9
4.4
3.3 NO.: MAX: MEAN: 11

9.9 5.05 1.0

8.0
7.9
4.3
7.4
9.8
5.2
5.2
4.3 11.3

5.3
6.1
9.7
6.4
6.6
2.3
3.8
4.0
5.6 19.8

5.4
6.5
5.9

3.8 2.3
4.7
5.8
4.0
5.9 4.6

3.3
2.3
3.4
3.1
3.7
7.9
6.5
3.8
6.5
5.1 6.0

3.2
3.5
3.5
5.0
6.1
5.8

7.0 6.1
5.4 5.4

3.8
7.6
7.2
6.1

6.3
8.5
7.8
10.2 8.4

7.6
4.8
8.7
10.2
5.2
4.4
7.6
6.1
9.0 8.9

10.5
9.3
7.2
7.0
11.7
8.8
2.8

5.5
2.8 3.2

5.0

3.5 2.6
3.3
4.5
4.2
4.6
2.9
2.2
3.2 4.1

5.0
3.7

4.2 3.7
6.9
4.1
2.5

3.1 4.4 6.3

10.6
13.1
9.2
14.0
2.0
6.8

5.7
3.4
8.9
9 9.8 5.90 10

11.3 6.11 10

19.8 6.41 11

7.9 4.56 10

7.0 5.16 9

10.2 6.99 10

10.2 7.20 10

11.7 7.45 11

5.0 3.56 10

6.9 4.17 10

14.0 8.00 ANNUAL OBSERVATIONS: 121 ANNUAL MEAN: 5.83 ANNUAL MAX: 19.8 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 13 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-127-0001 SITE ID: 3 POC: (086) METROPOLITAN SIOUX CITY AQCR: (127) Union COUNTY: (00000) Not in a city CITY: -96.707208 LONGITUDE: 42.751518 LATITUDE:

RURAL LOCATION SETTING: 31986 475th Ave SITE ADDRESS: AGRICULTURAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 3.8 PROBE HEIGHT: 344 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SPM COLLECTION AND ANALYSIS METHOD: (170) Met One BAM-1020 Mass Monitor w/VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24-HR BLK AVG Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 2.7 7.3 10.2 5.8 1.4 1.8 9.4 8.5 14.0 7.9 5.8 8.6 5.1 7.7 7.7 8.5 4.4 2.5 3.7 3.1 6.2 10.2 8.8 6.5 5.3 4.6 7.7 8.0 4.3 5.9 1.2 NO.: MAX: MEAN: 31

14.0 6.28 -1.0

.9 1.4 6.9 9.9 17.0 7.0 12.7 8.7 1.5 5.1 1.2 5.2 4.6 5.9 7.2 19.9 8.0 2.4 11.4 8.2 3.6 5.9 14.5 13.8 6.8 5.0 5.5 9.0

11.7 12.2 23.0 21.3 2.9 7.6 7.3 7.0 5.4 5.8 7.7 7.5 10.6 17.5

11.0 14.2

5.8 6.5 4.3 5.7 9.5 7.9 4.7 6.3

4.9 9.4 5.2 2.6 3.0 4.5 6.7 7.6 6.4 11.7 8.6 7.7 8.6 9.3 7.8 13.6 12.7 3.5 1.5 7.1 8.2 12.4 10.4 4.6 4.6 3.9 5.4 5.0

6.5 6.4 14.1 6.5 2.3 2.8 4.3 4.7 5.5 7.9 4.3 3.8 8.5 3.6 3.9 3.1 8.2 12.0 6.2 10.0 15.2 7.2 12.0 7.3 5.0 5.9 6.9 6.5 5.3 8.8

6.2 7.0 6.0 6.4 5.4 6.3 1.9 2.1 7.3 5.1 6.9 7.2 7.9 8.2 4.7 3.7 3.1 2.5 4.8 1.3 3.4 5.5 5.6 5.4 7.4 5.3 5.1 7.0 4.4 7.3

9.7 6.9 4.4 8.5 4.8 7.7 6.3 8.3 5.0 3.6 2.5 6.0 6.7 4.0 3.4 3.0 2.8 4.1 6.6 5.2 3.6 8.5 7.1 6.2 4.3 4.8 9.4 5.9 6.1 4.4 3.9

5.2 10.2 6.4 4.3 4.9 11.0 7.9 4.0 4.4 1.7 6.1 7.3 10.6 14.5 2.3 2.0 2.3 1.9 2.9 3.1 1.3 5.6 9.8 3.2 3.9 5.2 7.3 6.1 2.9 4.8 8.0

12.6 16.2 16.1 18.4 20.3 16.1 18.4 16.2 17.9 12.5 3.4 11.7 17.8 13.0 10.7 13.0 9.3 10.2 10.5 5.3 .8 5.1 6.1 3.7 4.4 6.2 5.5 3.4 4.6 4.6

1.1 2.4 1.4 2.2 2.5 2.3 3.3 3.0 2.6 2.0 5.5 5.3 7.4 3.3 3.1 3.9 6.6 7.8 16.9 4.0 3.0 3.7 4.0 4.1 2.8 4.1 6.2 2.3 1.4 5.4 3.8

4.5 4.8 5.0 5.9 9.6 4.6 8.8 10.4 7.5 9.0 18.5 10.8 9.4 8.0 9.5 13.9 17.6 24.7 8.3 17.7 18.7 14.3 6.6 4.6 5.3 5.7 10.1 8.8 3.0 3.3

4.8 5.1 6.9 8.8
8.5 9.4 6.5 9.9 19.7 16.0 6.7 8.0 20.3 30.6 P 39.3 21.4 10.9 24.2 28.5 14.1 6.2 4.2 3.8 3.4 5.2 11.2 14.2 10.9 28 19.9 7.11 24

23.0 9.42 28

13.6 7.08 30

15.2 6.70 30

8.8 5.40 31

9.7 5.71 31

14.5 5.39 30

20.3 10.58 31

16.9 4.14 30

24.7 9.65 29

39.3 12.48 ANNUAL OBSERVATIONS: 353 ANNUAL MEAN: 7.43 ANNUAL MAX: 39.3 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 14 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-127-0002 SITE ID: 1 POC: (086) METROPOLITAN SIOUX CITY AQCR: (127) Union COUNTY: (00000) Not in a city CITY: -96.747325 LONGITUDE: 42.850975 LATITUDE:

RURAL LOCATION SETTING: 31307 473rd Ave SITE ADDRESS: AGRICULTURAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 3.8 PROBE HEIGHT: 378 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SLAMS COLLECTION AND ANALYSIS METHOD: MULTIPLE METHODS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24 HOUR Micrograms/cubic meter (LC)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 3.5
4.6
11.8
9.8

7.7
11.1

5.7
14.4
7.9
9.8
3.7 NO.: MAX: MEAN: 11

14.4 8.18 4.1

20.1
11.9
3.8
9.2
7.0
8.9
16.9
6.8 12.6

24.2
9.8
8.0
14.0
7.6
11.3
15.0
6.6
9.1 6.3

6.2
6.5
7.4
8.1
8.8
7.4
8.6
8.6
8.1 5.3

10.3
3.8
5.4
3.7
3.9
7.1
9.6
10.8
4.4
2.3 6.9

6.2
3.3
7.1
11.0
5.4
5.0
6.8
6.5
3.0 10.8

9.4
11.7
7.6
6.1
4.3
6.1
9.5
9.6
5.8 5.3

9.9
6.7
13.8
4.7
4.1
6.6
5.4
6.0 7.9

16.9
17.6
19.0
14.2
12.9

2.2
6.2
3.0 3.8

2.2
2.7
2.1

5.5
3.8
8.4
3.2
3.8

7.7
4.8 4.3

8.1
6.0
17.9
9.1
16.8
18.5
7.9
8.4
4.7 3.5

10.6
6.9
21.6
7.4
P 42.1
23.3
8.4
3.1
19.3
9 20.1 9.86 10

24.2 11.82 10

8.8 7.60 11

10.8 6.05 10

11.0 6.12 10

11.7 8.09 9

13.8 6.94 9

19.0 11.10 11

8.4 4.36 10

18.5 10.17 10

42.1 14.62 ANNUAL OBSERVATIONS: 120 ANNUAL MEAN: 8.67 ANNUAL MAX: 42.1 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE:Nov. 25, 2014 RAW DATA MAX VALUES REPORT UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Page 15 of 15 (88101) PM2.5 - Local Conditions (46) South Dakota CAS NUMBER: 46-127-0002 SITE ID: 3 POC: (086) METROPOLITAN SIOUX CITY AQCR: (127) Union COUNTY: (00000) Not in a city CITY: -96.747325 LONGITUDE: 42.850975 LATITUDE:

RURAL LOCATION SETTING: 31307 473rd Ave SITE ADDRESS: AGRICULTURAL LAND USE: SITE COMMENTS: MONITOR COMMENTS: 3.8 PROBE HEIGHT: 378 ELEVATION-MSL: UTM NORTHING: (0000) NOT IN AN URBAN AREA UTM EASTING: URBANIZED AREA: UTM ZONE:

SUPPORT AGENCY: (0973) South Dakota Dept Environmental Protection Air Quality Prog MONITOR TYPE: SPM COLLECTION AND ANALYSIS METHOD: (170) Met One BAM-1020 Mass Monitor w/VS REPORT FOR: 2009 DURATION: UNITS: MIN DETECTABLE: PQAO: (0973) South Dakota Dept Environmental Protection Air Quality Prog 24-HR BLK AVG Micrograms/cubic meter (LC)

2

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 2.7 6.0 8.2 3.9 2.2 1.4 9.4 7.3 12.9 6.9 5.8 7.7 2.2 5.9 6.0 8.3 4.7 3.0 2.4 3.1 7.2 7.3 8.0 5.2 4.9 5.2 5.7 7.0 2.5 4.4 1.3 NO.: MAX: MEAN: 31

12.9 5.44 -1.1

1.0 2.7 6.7 8.1 14.4 6.4 11.9 8.2 .9 5.1 .1 4.7 4.5 5.1 6.7 17.9 6.1 2.9 9.7 6.7 3.5 4.8 13.0 13.2 6.0 4.7 4.3 8.9

8.9 11.3 20.9 20.3 2.5 6.5 5.8 5.8 4.6 4.7 6.8 6.2 9.0 14.9

9.7 15.0 21.6 14.1 2.9 5.5 6.8 4.0 7.5 9.6 8.5 5.0 6.1

4.7 9.4 6.2 4.3 4.0 6.2 8.3 8.0 7.4 12.7 9.2 9.4 8.9 10.1 8.8 13.2 14.1 8.2 4.7 6.6 11.5 15.0 8.5 7.6 6.5 5.3 7.1 6.5

6.6 9.8 12.8 9.0 3.9 5.2 7.1 7.5 8.2 11.1 7.6 8.7 13.3 8.3 8.7 9.4 11.4 14.3 8.9 10.3 15.8 14.9 12.2 7.8 5.4 6.7 7.6 7.5 7.3 10.2

9.3 7.0 7.7 5.7 7.1 3.2 4.4 9.1 6.2 8.1 8.1 8.2 9.3 5.7 5.1 4.4 3.2 4.1 2.7 4.7 7.9 7.3 6.4 9.3 7.3 6.8 7.2 5.7 10.5

14.2 13.9 8.3 10.7 10.4 12.2 11.2 16.2 10.0 5.6 6.4 8.8 11.3 6.3 5.3 4.8 5.1 6.0 9.1 7.0 7.0 11.4 11.7 9.3 9.6 11.8 10.5 8.2 6.6 4.8 6.3

8.2 11.3 11.5 10.6 9.5 17.5 8.7 4.9 3.4 6.0 9.2 9.6 13.5 19.4 3.9 4.5 5.5 4.6 5.4 6.2 7.0 11.4 14.5 4.2 5.2 6.3 6.6 5.5 3.4 5.0 7.9

12.4 16.4 16.7 19.6 21.0 15.9 17.2 14.7 18.1 11.7 4.6 12.8 18.0 15.1 12.6 12.4 11.4 10.9 12.1 6.3 1.7 5.1 7.1 5.2 5.1 5.9 4.2 4.0 5.4 3.3

1.9 3.1 2.5 2.5 4.0 3.0 4.3 4.5 3.4 3.7 6.6 5.4 8.9 4.9 4.0 2.9 6.7 9.3 13.4 4.0 3.1 5.8 4.6 3.3 3.0 5.7 7.9 4.8 2.0 7.3 4.9

4.8 4.9 5.6 7.0 9.3 6.5 8.9 6.6 7.5 8.9 17.3 11.6 9.2 8.3 10.8 13.0 15.5 22.9 11.6 16.6 19.6 15.5 8.0 7.1 6.0 8.6 10.7 9.4 6.5 5.3

7.1 5.6 8.0 10.2 12.7 7.7 8.9 9.7 7.8 10.9 20.1 14.4 7.8 8.1 19.9 28.8 P 35.9 21.5 11.6 24.3 28.7 14.4 7.8 5.1 5.7 6.3 14.0 18.4 13.7 28 17.9 6.36 27

21.6 9.16 28

15.0 8.29 30

15.8 9.13 29

10.2 6.60 31

16.2 9.17 31

19.4 8.03 30

21.0 11.05 31

13.4 4.83 30

22.9 10.10 30

35.9 13.35 ANNUAL OBSERVATIONS: 356 ANNUAL MEAN: 8.45 ANNUAL MAX: 35.9 1 Values marked with 'P' exceed the PRIMARY STANDARD of: 35.5 1 Values marked with 'S' exceed the SECONDARY STANDARD of: 35.5 Day JANUARY FEBRUARY MARCH APRIL MAY JUNE JULY AUGUST SEPTEMBER OCTOBER NOVEMBER DECEMBER MONTH

Note: A plus sign ("+") following a value indicates that the computed average includes one or more raw data values effected by a special event. STATE: