## SAFETY DATA SHEET

SolsticeTM ZD, SolsticeTM 1233zd (E)

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : SolsticeTM ZD, SolsticeTM 1233zd (E)

MSDS Number : 000000018007

Product Use Description : Refrigerant, Power cycle fluid, Heat transfer fluid

Company : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001

+1-973-455-6300 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887

: : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : liquid, clear

Color : colourless

Odor : slight

Classification of the substance or mixture

Classification of the

substance or mixture : Gases under pressure, Liquefied gas Simple Asphyxiant

GHS Label elements, including precautionary statements

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Symbol(s) :

Signal word : Warning

Hazard statements : Contains gas unde r pressure; may explode if heated. May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention: Use personal protective equipment as required.

Storage: Protect from sunlight. Store in a well-ventilated place.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Chemical nature : Substance

Chemical Name CAS-No. Concentration

trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >99.00 %

SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Use oxygen as required, provided a qualified operator is present. Call a physician.

Skin contact : After contact with skin, wash immediately with plenty of water. If symptoms persist, call a physician. Take off all contaminatedclothing immediately. Wash contaminated clothing before reuse.

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Eye contact : Rinse immediately with plen ty of water, also under the eyelids, for at least 15 minutes. Call a physician if irritation develops or persists.

Ingestion : If victim is fully conscious, give a cupful of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Call a physician immediately.

Notes to physician

Treatment : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : The product is not flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Carbon dioxide (CO2) Dry chemical

Foam

Specific hazards during firefighting : This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Exposure to decomposition products may be a hazard to

health. In case of fire hazardous decomposition products may be produced such as: Hydrogen fluoride Gaseous hydrogen chloride (HCl).

Carbon monoxide Carbon dioxide (CO2) Carbonyl halides

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Special protective equipment for firefighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition.

Ventilate the area. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe. Ensure that the oxygen content is >= 19.5%.

Environmental precautions : Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers).

Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Do not use in areas without adequate ventilation. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C.

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Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Advice on protection against fire and explosion : Can form a combustible mixture with air at pressures above atmospheric pressure. Keep product and empty cont ainer away from heat and sources of ignition.

Storage

Requirements for storage

areas and containers : Pressurized container: protec t from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even

after use. Keep containers tightly closed in a dry, cool and well-ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage. Store away from incompatible substances.

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Ensure that eyewash stations and safety showers are close to

the workstation location. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing.

Engineering measures : Use with local exhaust ventilation. Perform filling operations only at stations with exhaust

ventilation facilities.

Eye protection : Do not wear contact lenses. Wear as appropriate: Goggles or face shield, giving complete protection to eyes

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Hand protection : Impervious gloves Gloves must be inspected prior to use. Replace when worn.

Skin and body protection : Wear as appropriate: Solvent-resistant gloves Solvent-resistant apron and boots If splashes are likely to occur, wear:

Protective suit

Respiratory protection : In case of insu fficient ventilation wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator.For rescue and maintenance work in storage tanks use selfcontained breathing apparatus. Use NIOSH approved respiratory protection.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Ensure adequate ventilation, especially in confined areas. Remove and wash contaminated clothing before re-use. Contaminated work clothing should not be allowed out of the workplace. Keep working clothes separately. Wash hands before breaks and immediately after handling the product.

Exposure Guidelines

Components CAS-No. Value Control
parameters Upda

te Basis

trans-1-Chloro3,3,3- trifluoropropene 102687-65-0 TWA :

time weighted

average (800 ppm) 2013 Honeywell : Limit established by Honeywell

International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : liquid, clear

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Color : colourless

Odor : slight

Melting point/freezing point : < -90 °C

Method: OECD Test Guideline 102

Boiling point/boiling range : 19 °C

Flash point : Method: ISO 2719 Note: not applicable

Flammability : The product is not flammable. Method: Flammability (gases)

Lower explosion limit : Note: None

Upper explosion limit : Note: None

Vapor pressure : 1,516 hPa at 30 °C(86 °F)

Vapor density : Note: (Air = 1.0), not determined

Density : 1.27 g/cm3

Water solubility : 1.90 g/l at 20 °C

Method: OECD Test Guideline 105

Partition coefficient: noctanol/water : log Pow: 2.2 at 25 °C

Ignition temperature : 380 °C at 986.8 - 1,035.9 hPa

Method: DIN 51794

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Oxidizing properties : The substance or mi xture is not classified as oxidizing.

Molecular Weight : 130.5 g/mol

SECTION 10. STABILITY AND REACTIVITY

Possibility of hazardous

reactions : Polymerization can occur.

Conditions to avoid : Protect from heat/overheating. Keep away from direct sunlight. Heat, flames and sparks. Do not mix with oxygen or air above atmospheric pressure.

Incompatible materials to

avoid : Strong oxidizing agents Magnesium

Aluminium

Hazardous decomposition products : In case of fire hazardous decomposition products may be produced such as:

Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Gaseous hydrogen chloride (HCl). Gaseous hydrogen fluoride (HF).

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : LC50: 120000 ppm Exposure time: 4 h Species: rat

Skin irritation : Species: rabbit

Result: No skin irritation

Classification: Not classified as a skin irritant in animal testing.

Method: OECD Test Guideline 404 Exposure time: 4 h

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Sensitisation : Result: Does not cause skin sensitisation.

Classification: Patch test on human volunteers did not demonstrate sensitisation properties.

: Cardiac sensitization Species: dogs Note: Cardiac sensitisation threshold (dog): 25000 ppm.

Repeated dose toxicity : Species: rat Application Route: Inhalation Exposure time: 4 Weeks NOEL: 4500 ppm Note: Subacute toxicity

Genotoxicity in vitro : Test Method: Mutagenicity (Salmonella typhimurium - reverse mutation assay) Result: negative

Genotoxicity in vivo : Species: rat Cell type: Bone marrow Method: Mutagenicity (micronucleus test) Result: negative

Genotoxicity in vivo : Test Me thod: Unscheduled DNA synthesis Species: rat Result: negative

Genotoxicity in vivo : Species: mouse Cell type: Bone marrow Method: Mutagenicity (micronucleus test) Result: negative

Reproductive toxicity : Species: rabbit Note: No-observed-effect level - 15,000 ppm

: Species: rat Note: No-observed-effect level - 10,000 ppm

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Teratogenicity : Species: rabbit Note: No-observed-effect level - 15,000 ppm

: Species: rat Note: No-observed-effect level - 10,000 ppm

Further information : Note: Excessive ex posure may cause central nervous system effects including drowsiness and dizziness. Excessive exposure may also cause cardiac arrhythmia.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish : LC50: 38 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout)

Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates : Immobilization EC50: 82 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

Method: OECD Test Guideline 202

Toxicity to algae : Growth inhibition EC50: 106.7 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)

Method: OECD Test Guideline 201

: Growth rate NOEC: 115 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)

Method: OECD Test Guideline 201

Elimination information (persistence and degradability)

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Biodegradability : Result: Not readily biodegradable.

Value: 0 %

Method: OECD 301 D

Further information on ecology

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental regulations.

Note : Where possible recycling is preferred to disposal or

incineration.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. (Trans-1-Chloro-3,3, 3-trifluoropropene)

Class 2.2 Packing group

Hazard Labels 2.2

IATA UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (Trans-1-Chloro-3, 3,3-trifluoropropene)

Class : 2.2

Hazard Labels : 2.2 Packing instruction (cargo aircraft) : 200

Packing instruction (passenger aircraft) : 200

IMDG UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (TRANS-1-CHLORO-3,3,3- TRIFLUOROPROPENE)

Class : 2.2

Hazard Labels : 2.2

EmS Number : F-C, S-V

## SAFETY DATA SHEET

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Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : Not in compliance with the inventory

: trans-1-Chloro-3,3,3-

trifluoropropene 102687-65-0

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL) : All components of this product are on the Canadian DSL.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : On the inventory, or in compliance with the inventory

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : Not in compliance with the inventory

: trans-1-Chloro-3,3,3-

trifluoropropene 102687-65-0

China. Inventory of Existing

Chemical Substances : Not in compliance with the inventory

: trans-1-Chloro-3,3,3-

trifluoropropene 102687-65-0

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : Not in compliance with the inventory

## SAFETY DATA SHEET

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: trans-1-Chloro-3,3,3-

trifluoropropene 102687-65-0

National regulatory information

SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

New Jersey RTK : trans-1-Chloro-3,3,3- trifluoropropene 102687-65-

0

Pennsylvania RTK : trans-1-Chloro-3,3,3- trifluoropropene 102687-65-

0

WHMIS Classification : A : Compressed Gas This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 2 2

## SAFETY DATA SHEET

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Flammability : 0 0 Physical Hazard : 0 Instability : 0

Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publicati on. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous

versions.

Previous Issue Date : 08/12/2013 Prepared by: Honeywell Performance Materials and Technologies Product Stewardship Group