# FORM A**-1**

**COMPA NY INFORMA**  **TION**
**I. Parent Company / Legal Corporate Owner Information**
1. Legal Parent Company / Legal Corporate Name Occidental Chemical Corporation 2. Mailing Address 5005 LBJ Freeway 3. City Dallas 4. State Texas 5. Zip Code 75244-6152 6. County Dallas

>1500 7. Size of Company

(approximate number of employees including all subsidiaries, branches, and related establishments owned):



# Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

## FORM A**-2**

**FA CILITY INFORMA** 

**TION**
**II. Poly vinyl Chloride and Copoly** **mers (PVC) Production Facility Information** 
1. Facility Name Oxy Vinyls, LP - Deer Park PVC Facility Address a. Street 1000 Tidal Road b. City Deer Park c. State Texas d. Zip Code 77536 e. County Harris Facility Coordinates (Decimal Degrees to the 5th decimal place) f. Latitude 29 deg, 43 min, 39 sec, N g. Longitude 95 deg, 04 min, 36 sec, W
2. Number of employees attached to the PVC production facility: 88

**III. Technical Contact**

1. Name Jadie Pryor 2. Technical Contact Title Environmental Engineer 3. Telephone (281) 476-2666 4. Facsimile 281-476-2657 5. Email Jadie_L._Pryor@oxy.com

**IV. Other**
1. Is the facility a major source of HAP? No
2. If No, did the facility take a limit of its potential HAP emissions to avoid classification as a major source? No

3. If the facility took a limit of its potential HAP emissions to avoid classification as a major source, provide the date on which the limit was taken (MM/DD/YYYY).
4. Does the facility manufacture other products in addition to PVC resin? Yes

5. If Yes, list the other products manufactured at the facility. Anhydrous Potassium Hydroxide

6. Are there any HAP emissions associated with any co-located facilities? No



## Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

## FORM B-1

**CONTROL DEVICES**

**Instructions**

2. For the purposes of this survey, cooling towers are considered process equipment. Complete Form B-4 and Form G for cooling towers and heat exchange systems. 3. For the following control devices, complete the appropriate Forms: absorbers - Form F-1; thermal or catalytic oxidizers - Form F-2, condensers - Form F-3. 4. If additional rows are needed "insert" rows before end of table to preserve formatting. 5. Refer to "Enclosure 1" for additional instructions and details.

(**DO NOT SKIP ROWS**when entering data into this table.) **1 2**  **3 4** 

**Control Device ID**  **Control Device**

**Description Control Device Ty** **pe Other Description Emission Points (EP) Exiting**  **Control Device, or Subsequent Control Device ID to which**  **Exhaust is Routed**

(C-x) (thermal oxidizer, carbon

adsorber, etc.) (If "Other (Specify)", please provide a description) (EP-x, or C-x)

C-301A Thermal Oxidizer C-302 C-301B Thermal Oxidizer C-302 C-302 Other (Specify) Spray Nozzle Scrubber (HCl) C-303 C-303 Other (Specify) Spray Nozzle Scrubber (NaOH) EP-301 C-201 Other (Specify) Wet Scrubber (PM) EP-204 C-203 Fabric Filter EP-206 C-204 Fabric Filter EP-207 C-101 Other (Specify) Wet Scrubber (PM) EP-104 C-102 Fabric Filter EP-105 C-103 Fabric Filter EP-106 C-104 Fabric Filter EP-107 C-105 Fabric Filter EP-112 C-401 Fabric Filter EP-404 N/A 1. Provide a process flow diagram and plot plan for the PVC production facility. See instructions in "Enclosure 1" for additional details.**Completion of the process flow diagram is necessary before completing this form and the rest of the survey** 

**.**



## Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM B-2 RECOVERY SYSTEMS AND CLOSED VENT SYSTEMS** 

**Instructions**
1. In Table 1, identify each recovery system. For more details regarding the definition of a recovery system and what equipment should be included on this form, refer to Enclosure 1. 2. In Table 2, provide the requested information for any emission point through which emissions from the recovery or closed vent system are discharged directly to the atmosphere. 3. In Table 3, for each recovery system identified in Table 1, provide a recovery equipment ID and short description for each piece of equipment included in the recovery system. 4. If you use a condenser as part of a recovery system, and emissions from the condenser are routed directly to the atmosphere without first passing through a control device, complete form F-3 for the condenser(s). 5. If additional rows are needed "insert" rows before end of tables to preserve formatting. 6. Refer to "Enclosure 1" for additional instructions and details.
**Table 1. Recovery System Identification Table 2. Direct Discharge Emission Points**  **Table 3. Recovery Equipment that Comprise the Recovery System** (**DO NOT SKIP ROWS**when entering data into this table.) (**DO NOT SKIP ROWS**when entering data into this table.) (**DO NOT SKIP ROWS**when entering data into this table.)

**1 2**  **3 8**  **9 10**  **1 2**  **3 4**  **1 2**  **3**

**Recovery System ID: Recovery System Description:**  **At any point in the recovery or closed vent system, can emissions**  **be discharged directly to the atmosphere? (If "Yes," complete** 

**Table 2.) Recovery**  **System ID: Emission Point ID** 

(Do not list emission points from streams that are routed through a closed vent system to a control

device) **Is the emission point designed to be a control**  **device bypass or a process**

**vent? Before a discharge occurs,** 

**are the equipment opening standards in 40 CFR Part 61,**  **subpart F been met? Recovery Equipment ID** **Recovery Equipment Description Recovery System ID:** 

(RS-x) (use consistent terminology on the

process flow diagram; be descriptive of equipment purpose) (Yes/No) (RS-x) (EP-x) (Select) (Select) (RE-x) (use consistent terminology on the process flow diagram; be descriptive of equipment purpose) (RS-x)

RS-301 VCM Recovery System No C-301A C-301B RE-301 Vacuum Pump A RS-301 RE-302 Vacuum Pump B RS-301 RE-303 Vacuum Pump C RS-301 RE-304 Vacuum Pump D RS-301 RE-305 Vacuum Compressor A RS-301 RE-306 Vacuum Compressor B RS-301 RE-307 Vacuum Compressor C RS-301 RE-308 Vacuum Compressor D RS-301 RE-309 Vacuum Compressor E RS-301 RE-310 Vacuum Pump A KO Pot RS-301 RE-311 Vacuum Pump B KO Pot RS-301 RE-312 Vacuum Pump C KO Pot RS-301 RE-313 Vacuum Pump D KO Pot RS-301 RE-314 Vacuum Compressor A KO Pot RS-301 RE-315 Vacuum Compressor B KO Pot RS-301 RE-316 Vacuum Compressor C KO Pot RS-301 RE-317 Vacuum Compressor D KO Pot RS-301 RE-318 Vacuum Compressor E KO Pot RS-301 RE-319 Vent Condenser RS-301 RE-320 Vent Condenser RS-301 RE-321 Secondary Vent Condenser RS-301 RE-322 Vent Membrane RS-301 (Select Control Device IDs Entered on

Form B-1) **List the control devices that control emissions from the closed vent** 

**system:**

Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM B-4 PROCESS EQUIPMENT** 

**Instructions**
1. Complete the table for each piece of process equipment identified on your process flow diagram. Do not include equipment or devices you have identified in Forms B-1 or B-2. 2. For the purposes of this survey, cooling tow ers are considered process equipment. For each cooling tower reported on this Form, complete Form H for cooling towers and heat exchange systems. 3. If emissions from a condenser (not previously listed as part of a recovery system or control device) are routed directly to the atmosphere without first passing through a recovery system or control device, complete Form F-3 for the condenser(s). 4. If additional row

s are needed "insert" row s before end of tables to preserve formatting. 5. Refer to "Enclosure 1" for additional instructions and details.
(**DO NOT SKIP ROWS**when entering data into this table.) **1 2**  **3 4**  **5 6**  **7 8**  **9 10**  **11**

**Process Equipment**  **ID Process Equipment Description**  **Are emissions from the process equipment routed directly to the**  **atmosphere without first passing through a recovery system or control device?**  **Are emissions from the process equipment routed**  **to a recovery system? If you answered "Yes" in Column 7,**  **list the recovery system ID entered**

**in Form B-2.**

(U-x) (use consistent terminology on the

process flow diagram; be descriptive of

equipment purpose) (Yes/No) (Yes/No) (RS-x)

U-101 Solution Mix Tank Yes EP-110 U-102 Solution Cooler Yes EP-110 U-103 A Foam Trap No Yes RS-301 U-104 Condenser(3) No Yes RS-301 U-105 Jacketed Reactors (4) Z,A,B,C No Yes RS-301 U-106 Coating Tank Yes EP-108 U-107 Short Stop Pot No Yes RS-301 U-108 A Blow

down Tank No Yes RS-301 U-109 A Column Feed Tank No Yes RS-301 U-110 A Economizer No Yes RS-301 U-111 AA Economizer No Yes RS-301 U-112 A Stripping Column No Yes RS-301 U-113 AA Stripping Column No Yes RS-301 U-114 A Col. Condenser No Yes RS-301 U-115 AA Col. Condenser No Yes RS-301 U-116 A Knock out pot No Yes RS-301 U-117 AA Knock out pot No Yes RS-301 U-118 A Blend Tank Cooler Yes EP-101 U-119 A Blend Tank Yes EP-101 U-120 A Off Grade Blend Tank Yes EP-102 U-121 Centrifuges (2) Yes EP-103 U-122 A Dryer No No C-101 U-123 Cyclone No No C-101 U-124 Surge Hopper No No C-101 U-125 Screen No No C-101 U-126 Magnetic Separator No No C-101 U-127 Surge Hopper No No C-102 U-128 Camco Filters No No C-102 U-129 Bulk Bins (5) No No C-105 U-130 Production Bins (4) No No C-103 C-102 U-131 Fluidize Silos(2) No No C-104 U-132 Water Tank Yes EP-111 U-133 Short Stop Small Pots No Yes RS-301 U-135 Jackets(4) Yes EP-411 EP-412 U-136 Baffles No No N/A U-137 Short Stop Tote Yes EP-109 U-138 A Dryer Air Preheater No No C-101 U-201 Solution Mix Tank Yes EP-210 U-202 Solution Cooler Yes EP-210 U-203 B Foam Trap No Yes RS-301 U-204 Condenser(3) No Yes RS-301 U-205 Jacketed Reactors (4) D,E,F,G No Yes RS-301 U-208 B Blow

down Tank No Yes RS-301 U-209 B Column Feed Tank No Yes RS-301 U-210 B Economizer No Yes RS-301 U-211 B Stripping Column No Yes RS-301 U-212 B Col. Condenser No Yes RS-301 U-213 B Knock out pot No Yes RS-301 U-214 B Blend Tank Cooler Yes EP-201 U-215 B Blend Tank Yes EP-201 U-216 B Off Grade Blend Tank Yes EP-202 U-217 Centrifuges (2) Yes EP-203 U-219 B Dryer No No C-201 U-220 Cyclone No No C-201 **If you answered "Yes" in Column 3, list the emission point ID as shown on the process flow diagram.**  (Do not list streams exiting the process equipment that are routed to a recovery system or control devices)

(List EP-x) **If you answered "No" in Column 7, list the control**  **devices that control emissions from the process equipment:** 

(Select Control Device IDs Entered on Form B-1)

Page 1 of 2 PVC Combined Vent Section 114 Survey 11/17/2014**FORM B-4 PROCESS EQUIPMENT** 

**Instructions**
1. Complete the table for each piece of process equipment identified on your process flow diagram. Do not include equipment or devices you have identified in Forms B-1 or B-2. 2. For the purposes of this survey, cooling tow ers are considered process equipment. For each cooling tower reported on this Form, complete Form H for cooling towers and heat exchange systems. 3. If emissions from a condenser (not previously listed as part of a recovery system or control device) are routed directly to the atmosphere without first passing through a recovery system or control device, complete Form F-3 for the condenser(s). 4. If additional row

s are needed "insert" row s before end of tables to preserve formatting. 5. Refer to "Enclosure 1" for additional instructions and details.
(**DO NOT SKIP ROWS**when entering data into this table.) **1 2**  **3 4**  **5 6**  **7 8**  **9 10**  **11**

**Process Equipment**  **ID Process Equipment Description**  **Are emissions from the process equipment routed directly to the**  **atmosphere without first passing through a recovery system or control device?**  **Are emissions from the process equipment routed**  **to a recovery system? If you answered "Yes" in Column 7,**  **list the recovery system ID entered**

**in Form B-2.**

(U-x) (use consistent terminology on the

process flow diagram; be descriptive of

equipment purpose) (Yes/No) (Yes/No) (RS-x) **If you answered "Yes" in Column 3, list the emission point ID as shown on the process flow diagram.**  (Do not list streams exiting the process equipment that are routed to a recovery system or control devices)

(List EP-x) **If you answered "No" in Column 7, list the control**  **devices that control emissions from the process equipment:** 

(Select Control Device IDs Entered on Form B-1)

U-221 Surge Hopper No No C-201 U-222 Screen No No C-201 U-223 Magnetic Separator No No C-201 U-224 Surge Hopper No No C-102 U-225 Camco Filters No No C-102 U-227 Production Bins (4) No No C-203 C-102 U-228 Fluidize Silos(2) No No C-204 U-229 Water Tank Yes EP-211 U-230 Short Stop Small Pots No Yes RS-301 U-231 Jackets(4) Yes EP-412 EP-411 U-232 Baffles No No N/A U-233 B Dryer Air Preheater No No C-201 U-301 Low

Pressure Foam Trap No Yes RS-301 U-302 High Pressure Foam Trap No Yes RS-301 U-304 Inhibitor Tank No Yes RS-301 U-308 Accumulator No Yes RS-301 U-309 Reclaim Monomer Storage No Yes RS-301 U-310 Reclaim Monomer Storage No Yes RS-301 U-311 Decanter No Yes RS-301 U-312 VCM Filters No Yes RS-301 U-313 VCM Sphere No Yes RS-301 WWE-314WWS Feed Tank No Yes RS-301 WWE-315WWS ecomomizers No Yes RS-301 WWE-316Waste Water Stripper No Yes RS-301 WWE-317 Condenser No Yes RS-301 U-401 Centrate Sump Yes EP-410 U-403 RO Pre-heater Yes EP-413 U-404 Heat Exchangers (2) Yes EP-413 U-405 Centrate Filters Yes EP-413 U-406 Recycle Water Yes EP-413 U-407 Warm RO Tank Yes N/A U-408 US Filter RO System Yes N/A U-409 Cold RO Tank Yes N/A U-410 PVC Cooling Tow er Yes EP-401 U-411 Condenser Cooling Tower Yes EP-402 U-412 Chill Water Small Tank Yes EP-411 U-413 Chillers(4) Yes EP-411 EP-412 U-414 Ammonia Chiller Yes EP-411 EP-412 U-415 Chill Water Tank Yes EP-412 WWE-416Waste Water Treatment Plant Yes EP-414 U-417 Liquid Suspending Agent Tank Yes EP-415 U-418 Boilers(2) Yes EP-403 U-419 Ammonia Refrigeration System No No N/A U-420 Diesel Air Compressor Yes EP-405 U-421 Emergency Generator Yes EP-406 U-422 #3 Diesel FW Pump Yes EP-407 U-423 #4 Diesel FW Pump Yes EP-408 U-424 Potable Water Pump Yes EP-409 WWE-425 PVC Sump Yes EP-416 U-426 Catalyst Trailer Emer Engine Yes EP-417

Page 2 of 2 PVC Combined Vent Section 114 Survey 11/17/2014

## FORM F-1

**CONTROL DEVICES - A BSORBER** 

**Instructions**
1. Complete the form for each absorber used as a control device within the PVC production facility, or for any absorber that emits directly to atmosphere. 2. Refer to "Enclosure 1" for additional instructions and details.

C-302 C-303 **1** Type of Equipment or Device Control Device Control Device **2** Equipment of Device ID C-302 C-303 **3 Ty** **pe of A bsorber**  Other (Specify) Other (Specify) **4** If other, provide a description: Spray Nozzle ScrubberSpray Nozzle Scrubber **5** Gas inlet flow rate (dscfm): 46667 46667 **6** Gas inlet temperature (°F): 500 **7** Pressure drop (in H2

## O): 6.9 6.9 **8** Liquid-to-gas ratio (gal/103

## acfm): 0.0084 0.052 **Inlet scrubbing liquor 9**  Liquor used: Softened Water Softened Water **10** pH: 9.2 **11** Percent solids: **12** Type of alkali added, if any: NaOH **13**Addition rate (lb/gal): **14**Wastewater generation rate (gal/min): 5

**15**Year Equipment Installed: 2007 2007 **16** Equipment Currently Regulated Under (cite regulations): 40 CFR 63 subpart G 40 CFR 63 subpart G



# Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

## FORM F-2 **CONTROL DEVICES - THERMA L OR CA**  **TA LYTIC OXIDIZER** 

**1** Control Device ID: C-301A C-301B **2** Number of operating hours per year (hours/year): 8760 8760 **3** Is this emergency

equipment? No No **4 Ty** **pe**(Thermal Oxidizer or Catalytic Oxidizer) Thermal Oxidizer Thermal Oxidizer **5** Oxidizer Inlet Flow Rate (dscfm): 22512 22512 **6** Average percentage of total flow originating from the production facility: 0.20% 0.20%
**7** Combustion chamber temperature (°F): (please note if temperature measurement is not in chamber) 1560 1560
**8** Excess air (%): 50 50 **9** Nominal residence time (s): 2.4 2.4 **Heat recovery 10**  Recuperative, percent heat recovery 75 75 **11** Regenerative, percent heat recovery 0% 0% **12**Design Capacity

(Heat Input) (MMBtu/hr): 70 80 **13**Fuel Basis for Design Capacity: 68627 SCFH 78431 SCFH **14**Heat Release Rate (Btu/scf): 1020 1020 **15**Is the unit subject to NSPS? No No **16** If yes, indicate the year: **Start-up Fuel/Material 17**  Start-up fuel: Natural Gas Natural Gas **18** Number of start-ups per year: 4 4 **19** Typical length of time for start-up (hours): 12 12 **20** Higher heating value (HHV): 1020 1020 **Fuels/Materials Combusted During Normal Operations (include solid, liquid, and gas waste streams) 21**  Fuel 1: Natural Gas Natural Gas **22** Hours used per year: 8760 8760 **23** Higher heating value (HHV): 1020 1020 **24** Fuel 2: Vent Gas Vent Gas **25** Hours used per year: 8760 8760 **26** Higher heating value (HHV): 51.5 51.5 **27** Fuel 3: **28** Hours used per year: **29** Higher heating value (HHV): **30** Fuel 4: **31** Hours used per year: **32** Higher heating value (HHV): **33** Fuel 5: **34** Hours used per year: **35** Higher heating value (HHV):

**36**Year Equipment Installed: 1977 1977 **37**Equipment Currently Regulated Under (cite regulations): 40 CFR 63 subpart G40 CFR 63 subpart G



## Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

## FORM F-3

**CONTROL DEVICES - CONDENSERS**

**Instructions**
1. Complete the form for each condenser used as a control device within the PVC production facility, or for any condenser that emits directly to atmosphere. 2. Refer to "Enclosure 1" for additional instructions and details.

**1** Type of Equipment or Device **2** Equipment of Device ID **3 Ty** **pe of Condenser 4**  If other, provide a description: **5** Is the condenser refrigerated?

**6** Describe the materials condensed:

**7** Describe the fate of the non-condensed gas stream:

**8** Describe the fate of the condensate outlet stream:

**9** Gas inlet flow rate (dscfm): **10**Gas inlet temperature (°F): **11**Gas outlet temperature (°F): **12**Liquid outlet for rate (gpm):

**15**Year Equipment Installed: **16**Equipment Currently Regulated Under (cite regulations):



# Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM H

**EQUIPMENT LEAKS**

**Instructions**
1. Submit a copy of the leak detection and repair procedures for the PVC production facility and provide responses to the questions below. 2. Refer to "Enclosure 1" for additional instructions and details.

**Table 1. LDAR Program**

Yes

No Yes No

No

$39,554

**Table 2. Equipment Counts**

**In Source Category**  **Subtotal of Equipment Associated**

**with Closed Vent System(s)** (Subset of count in source category)

2082 39 0

41 0

6215 124 0

12 0

82 0

5 0 0 In heavy liquid service In gas, vapor, and light liquid service Connectors

In heavy liquid service In gas, vapor, and light liquid service Agitators

In liquid service In gas and vapor service Pressure Relief Devices

Open ended valves and lines Sampling connection systems Compressors Instrumentation systems Valves

In heavy liquid service In light liquid service Pumps 40 CFR Part 61, Subpart V Other Federal LDAR Regulation Specify: State LDAR Regulation Specify: Provide the total cost to your facility for conducting the LDAR program at this process unit in 2013:

**Equipment**

In heavy liquid service In gas, vapor, and light liquid service Is there an equipment leak detection and repair (LDAR) program for all equipment at your facility included in the source category? If "No," how are equipment leaks detected and repaired?

If "Yes," is the equipment subject to the requirements of: 40 CFR Part 63, Subpart UU



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-112 A Stripping Column System

10 Equipment Cleaning/Product Switch/Maintenance PM 31.2
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 6 136 49.5 0.09 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:

Equipment volume (m3): Reason(s) for Equipment Opening

Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening How is the HAP Concentration Determined? How are HAP Emissions Controlled?

**Individual HAP Present Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM **Concentration at Equipment Opening (ppmvd @ 3% O2)**  **Basis for Emissions Value**  Source Equipment Type:



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-113 AA Stripping Column System

5 Equipment Cleaning/Product Switch/Maintenance PM 21.3
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 10 330 79.4 0.05 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-211 B Stripping Column System

53 Equipment Cleaning/Product Switch/Maintenance PM 26.9
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 85 20.7 0.17 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:

Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-103 and U-203 Foam Trap 4 Equipment Cleaning/Maintenanc e PM 50
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 8 3.75 0.004 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:
Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-108 and U-208 Blowdown Tanks 3 Equipment Cleaning/Maintenanc e PM 166.7
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 4 32 13.67 0.04 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:
Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-109 and U-209 Column Feed Tanks

2 Equipment Cleaning/Maintenanc e PM 187
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 31 64 47.5 0.1 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:
Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment
Misc.Pumps and Piping

5 Maintenance 0.1
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 1.2 55 21 0.0001 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Recovery Equipment RE-305 This tab includes information for RE-305 to 309 and RE-314 to RE-318 Recovery Compressors and KO Pots

5 Maintenance 0.6
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 10 90 34.2 0.001 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Recovery Equipment RE-301 This tab includes information for RE-301 to 304 and RE-310 to RE-313 Vacuum Pump with KO Pots

7 Maintenance 0.3
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 63 23.14 0.0003 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Recovery Equipment RE-319 and RE-320 Recovery Condensers

1 Maintenance PM/Inspection 2.5
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 110 110 110 0.0016 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment
Misc. Valves and Piping

2 Maintenance 0.03
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 23 11.5 0 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment
Vapor Filters 4 Maintenance/Inspecti
on 0.3
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 55 21.25 0.0002 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-312 VCM Filters 8 Change Filters 0.7
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 345 155 0.005 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment
VCM Charge Pumps

1 Maintenance 0.17
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 122 122 122 0.0001 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Recovery Equipment RE-322 VCM Recovery Membranes

2 Maintenance 0.17
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 0 4 2 0 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment WWE-316 Wastewater Stripper

4 Maintenance/Inspecti
on 3.9
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 3 150 45 0.004 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year: Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-105 Reactors 54 Equipment Cleaning/Maintenanc
e 78.4
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 250 1923 774 18.4 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:
Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM I**

**EQUIPMENT OPENING**

**Instructions** 1. Complete this form for 2013 only. 2. Values should be reported for normal operations; not for startups, shutdowns, or malfuctions. 3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for each individual piece of process equipment, recovery equipment, and any additional equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.** Process Equipment U-205 Reactors 47 Equipment Cleaning/Maintenanc
e 78.4
Sampling Results Other method:

**Table 2.**

**Total Emissions for 2013** 

**Minimum Maximum**  **Average (pounds)** 

Vinyl chloride 93 1800 617.6 12.78 Calculated based on equipment volume and measured VOC concentration at opening (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Equipment volume (m3): Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: Number of openings during the year:
Reason(s) for Equipment Opening

How is the HAP Concentration Determined? How are HAP Emissions Controlled? Equipment is vacuum cleared through Recovery and to the Thermal Oxidizer prior to opening

**Individual HAP Present Concentration at Equipment Opening (ppmvd @ 3%**  **O2) Basis for Emissions**  **Value Notes** 

Concentration data in ppmv reported without correction to 3% O2. Handheld miniRAE meter is used to measure for VOC when opening equipment; All VOC is reported as VCM



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TA NKS, VESSELS A** **ND PORTA BLE CONTA** **INERS USED FOR FEEDSTOCK STORA GE, PRODUCT STORA** **GE, VENT GA S STORA** **GE, HOLDING A ND WA**  **STEWA TER** 

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-313 VCM Storage Sphere

1000**Restricted cell; turnovers = 1,985** 852 100

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)**

Vinyl chloride 2110 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Sphere; so fixed structure

Feedstock storage

If Other, please specify, being as descriptive as possible: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.
Select the purpose of the equipment:

If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

**Concentration (ppmvd @ 3% O2)** How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP. Are HAP Emissions Controlled? Yes

**Individual HA P Present**  Source Equipment Type:

No emissions to ATM; Emissions directed to Recovery System prior to opening Number of turnovers: Equipment volume (m3

### ):

**Notes** Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-101 Solution Mix Tank

1000**Restricted cell; turnovers = 4,691**

1.89 75

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Cumene 0.2 0 Methanol 142 0 Acetophenone 0.2 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes**
Trace HAP in some raw materials; Concentrations unknown Trace HAP in some raw materials; Concentrations unknown Trace HAP in some raw materials; Concentrations unknown Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? MSDS Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Tank used for mixing suspending agents and additives prior to charging to the reactors; Openings on tank for adding materials

Select the purpose of the equipment: Additive blending

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-201 Solution Mix Tank

1000**Restricted cell; turnovers = 4,443**

1.89 75

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Cumene 0.2 0 Methanol 142 0 Acetophenone 0.2 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes**
Trace HAP in some raw materials; Concentrations unknown Trace HAP in some raw materials; Concentrations unknown Trace HAP in some raw materials; Concentrations unknown Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? MSDS Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Tank used for mixing suspending agents and additives prior to charging to the reactors; Openings on tank for adding materials

Select the purpose of the equipment: Additive blending

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-309 Reclaim Monomer Storage

1000**Restricted cell; turnovers = 2,233** 75.66 80

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)**

Vinyl chloride 2110 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes**

No emissions to ATM; Emissions directed to Recovery System prior to opening Are HAP Emissions Controlled? Yes If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP. Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Horizontal pressure vessel

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-310 Reclaim Monomer Storage

1000**Restricted cell; turnovers = 2,233** 75.66 80

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)**
Vinyl chloride 2110 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes**

No emissions to ATM; Emissions directed to Recovery System prior to opening Are HAP Emissions Controlled? Yes If Yes, How Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP. Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Horizontal pressure vessel

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM K-1 TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER** 

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation w orksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-314 WWS Feed Tank

1000**Restricted cell; turnovers = 3,795** 37.8 100

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)**
Vinyl chloride 2110 0

Acetaldehyde 535 0

Acetophenone 0.2 0
Hydroquinone 0.00001 0

Formaldehyde 28 0

Methanol 142 0 Ethylene dichloride (1,2- Dichloroethane) 80 0 Ethylidene dichloride (1,1- Dichloroethane) 123 0

Ethyl chloride (Chloroethane) 540 0 Methyl chloride (Chloromethane) 2309 0

Cumene 0.2 0
Xylenes (isomers and mixture) 3.6 0

2,2,4-Trimethylpentane 21.8 0 Benzene (including benzene from gasoline) 105 0

Toluene 27 0

Phenol 0.19 0

Chloroform 160 0 No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening **Notes** No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening No emissions to ATM; Emissions directed to Recovery System prior to opening Are HAP Emissions Controlled? Yes If Yes, How

Are The Emissions Controlled? Pressurized tank with SSM emissions directed to Recovery System

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? Estimated based on wastew ater containing a variety of potential HAPs Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Fixed; closed vertical pressure vessel; Vessel contains collected wastew ater prior to stripping to remove residual VCM; vessel is closed and not vented to ATM; any emissions aredirected through the Recovery System

Select the purpose of the equipment: Wastew ater storage/equalization
If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3): Storage Temperature (°F)

Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-137 Shortstop Tote

20 1.1 80

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Acetaldehyde 535 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes** Acetaldehyde may be present as a decomposition product; trace concentration Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled? +

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? Unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Supplier tote is connected to act as a feed tank to the process; tote is vented to ATM; RM is not a HAP, but may contain traces of Acetaldehyde

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-106 Coating Tank

15 3.8 80

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Formaldehyde 28 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes** Formaldehyde MAY be present in trace amounts Are HAP Emissions Controlled? Yes
If Yes, How Are The Emissions Controlled? Closed Tank; Nitrogen Pad vent to U-104 or U-204 (condenser) and then to Recovery System; Conservation Vent to ATM

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? Unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Closed tank with a nitrogen pad and conservation vent; RM may contain traces of Formaldehyde

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-417 Liquid Suspending Agent Tank

2 36 80

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Methanol 142 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes** Methanol may be present up to 2% of solution Are HAP Emissions Controlled? Yes If Yes, How Are The Emissions Controlled? Closed Tank; Conservation Vent to ATM

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? MSDS Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Closed tank with a conservation vent; RM will contain up to 2% methanol (per MSDS)

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TA NKS, VESSELS A** **ND PORTA BLE CONTA** **INERS USED FOR FEEDSTOCK STORA GE, PRODUCT STORA** **GE, VENT GA S STORA** **GE, HOLDING A ND WA**  **STEWA TER** 

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-132 Scrubber Water Tank

unknown; continuous level control 9.5 80

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 0 Acetaldehyde 535 0 Acetophenone 0.2 0 Hydroquinone 0.00001 0 Formaldehyde 28 0 Methanol 142 0 Ethylene dichloride (1,2- Dichloroethane) 80 0 Ethylidene dichloride (1,1- Dichloroethane) 123 0 Ethyl chloride (Chloroethane) 540 0 Methyl chloride (Chloromethane) 2309 0
Cumene 0.2 0
Xylenes (isomers and mixture) 3.6 0 2,2,4-Trimethylpentane 21.8 0 Benzene (including benzene from gasoline) 105 0
Toluene 27 0 Phenol 0.19 0 Chloroform 160 0 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HA P Present**  **Concentration (ppmvd @ 3% O2)**  **Notes** Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? Unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; Open to atmosphere; Holds centrate water which is used to scrub the dryer discharge to remove PM

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible: Water hold tank for water fed to Wet scrubber to control dryer PM emissions

Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-229 Scrubber Water Tank

unknown; continuous level control 9.5 80

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 0 Acetaldehyde 535 0 Acetophenone 0.2 0 Hydroquinone 0.00001 0 Formaldehyde 28 0 Methanol 142 0 Ethylene dichloride (1,2- Dichloroethane) 80 0 Ethylidene dichloride (1,1- Dichloroethane) 123 0 Ethyl chloride (Chloroethane) 540 0 Methyl chloride (Chloromethane) 2309 0
Cumene 0.2 0
Xylenes (isomers and mixture) 3.6 0 2,2,4-Trimethylpentane 21.8 0 Benzene (including benzene from gasoline) 105 0
Toluene 27 0 Phenol 0.19 0 Chloroform 160 0 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? Unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Fixed; Open to atmosphere; Holds centrate water which is used to scrub the dryer discharge to remove PM

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible: Water hold tank for water fed to Wet scrubber to control dryer PM emissions

Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-401 Centrate Sump

unknown 152 110

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 0 Acetaldehyde 535 0 Acetophenone 0.2 0 Hydroquinone 0.00001 0 Formaldehyde 28 0 Methanol 142 0 Ethylene dichloride (1,2- Dichloroethane) 80 0 Ethylidene dichloride (1,1- Dichloroethane) 123 0 Ethyl chloride (Chloroethane) 540 0 Methyl chloride (Chloromethane) 2309 0
Cumene 0.2 0
Xylenes (isomers and mixture) 3.6 0 2,2,4-Trimethylpentane 21.8 0 Benzene (including benzene from gasoline) 105 0
Toluene 27 0 Phenol 0.19 0 Chloroform 160 0 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Water collection sump which accumulates stripped centrate from the centrifuges Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Sump used to collect centrate from the centrifuges prior to storage

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)

How is the HAP Concentration Determined?



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-406 Recycle Water Tank

unknown 681 110

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 0 Acetaldehyde 535 0 Acetophenone 0.2 0 Hydroquinone 0.00001 0 Formaldehyde 28 0 Methanol 142 0 Ethylene dichloride (1,2- Dichloroethane) 80 0 Ethylidene dichloride (1,1- Dichloroethane) 123 0 Ethyl chloride (Chloroethane) 540 0 Methyl chloride (Chloromethane) 2309 0
Cumene 0.2 0
Xylenes (isomers and mixture) 3.6 0 2,2,4-Trimethylpentane 21.8 0 Benzene (including benzene from gasoline) 105 0
Toluene 27 0 Phenol 0.19 0 Chloroform 160 0 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Centrate water collection tank Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Fixed; Vented to atmosphere

Select the purpose of the equipment: Other (Specify)

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)

How is the HAP Concentration Determined?



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-304 Inhibitor Tank

2 0.26 80

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)**
(select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes** No HAPS proesent in inhibitor Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  How is the HAP Concentration Determined? None Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description:
If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.Fixed; tank contains inhibitor which is not a HAP

Select the purpose of the equipment: Feedstock storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-129 PVC Bulk Bins (6)

973combined volume of (5) bins 85

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 20 Acetaldehyde 535 Acetophenone 0.2 Hydroquinone 0.00001 Formaldehyde 28 Methanol 142 Ethylene dichloride (1,2- Dichloroethane) 80 Ethylidene dichloride (1,1- Dichloroethane) 123 Ethyl chloride (Chloroethane) 540 Methyl chloride (Chloromethane) 2309 Cumene 0.2
Xylenes (isomers and mixture) 3.6 2,2,4-Trimethylpentane 21.8 Benzene (including benzene from gasoline) 105 Toluene 27 Phenol 0.19 Chloroform 160 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Emissions Inventory Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Final product storage bins holding finshed PVC product prior to loading; U-129 represents (6) separate storage bins and may be accessed by either production line

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-130 PVC Production Day Bins (4)

392Combined volume of (4) bins 85

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 3 Acetaldehyde 535 Acetophenone 0.2 Hydroquinone 0.00001 Formaldehyde 28 Methanol 142 Ethylene dichloride (1,2- Dichloroethane) 80 Ethylidene dichloride (1,1- Dichloroethane) 123 Ethyl chloride (Chloroethane) 540 Methyl chloride (Chloromethane) 2309 Cumene 0.2
Xylenes (isomers and mixture) 3.6 2,2,4-Trimethylpentane 21.8 Benzene (including benzene from gasoline) 105 Toluene 27 Phenol 0.19 Chloroform 160 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Emissions Inventory Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Final product storage bins holding finshed PVC product prior to loading; U-130 represents (4) separate storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-131 PVC Fluidizing Silos (2)

1000**Restricted cell; turnovers = 1,135** 486Combined volume of (2) silos 85

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 68 Acetaldehyde 535 Acetophenone 0.2 Hydroquinone 0.00001 Formaldehyde 28 Methanol 142 Ethylene dichloride (1,2- Dichloroethane) 80 Ethylidene dichloride (1,1- Dichloroethane) 123 Ethyl chloride (Chloroethane) 540 Methyl chloride (Chloromethane) 2309 Cumene 0.2
Xylenes (isomers and mixture) 3.6 2,2,4-Trimethylpentane 21.8 Benzene (including benzene from gasoline) 105 Toluene 27 Phenol 0.19 Chloroform 160 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Emissions Inventory Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Final product silos hold finished PVC product prior to loading; U-131 represents (2) separate storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-227 PVC Production Day Bins (4)

392Combined volume of (4) bins 85

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 4 Acetaldehyde 535 Acetophenone 0.2 Hydroquinone 0.00001 Formaldehyde 28 Methanol 142 Ethylene dichloride (1,2- Dichloroethane) 80 Ethylidene dichloride (1,1- Dichloroethane) 123 Ethyl chloride (Chloroethane) 540 Methyl chloride (Chloromethane) 2309 Cumene 0.2
Xylenes (isomers and mixture) 3.6 2,2,4-Trimethylpentane 21.8 Benzene (including benzene from gasoline) 105 Toluene 27 Phenol 0.19 Chloroform 160 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Emissions Inventory Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Final product storage bins holding finshed PVC product prior to loading; U-227 represents (4) separate storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014

### FORM K-1

**TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING AND WASTEWATER**

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**
Process Equipment U-228 PVC Fluidizing Silos (2)

1000**Restricted cell; turnovers = 1,091** 486Combined volume of (2) silos 85

**Table 2.**
**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 2110 68 Acetaldehyde 535 Acetophenone 0.2 Hydroquinone 0.00001 Formaldehyde 28 Methanol 142 Ethylene dichloride (1,2- Dichloroethane) 80 Ethylidene dichloride (1,1- Dichloroethane) 123 Ethyl chloride (Chloroethane) 540 Methyl chloride (Chloromethane) 2309 Cumene 0.2
Xylenes (isomers and mixture) 3.6 2,2,4-Trimethylpentane 21.8 Benzene (including benzene from gasoline) 105 Toluene 27 Phenol 0.19 Chloroform 160 Unknown Trace possible Unknown Trace possible
Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible
Unknown Trace possible Unknown Trace possible Unknown Trace possible Unknown Trace possible Are HAP Emissions Controlled? No If Yes, How Are The Emissions Controlled?

**Individual HAP Present Concentration (ppmvd @ 3% O2)**  **Notes** Emissions Inventory Unknown Trace possible Unknown Trace possible Unknown Trace possible How is the HAP Concentration Determined? VCM emissions based on final product analysis; all others unknown Source Equipment Type: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof. Final product silos hold finished PVC product prior to loading; U-228 represents (2) separate storage bins

Select the purpose of the equipment: Final product storage

If Other, please specify, being as descriptive as possible: Number of turnovers: Equipment volume (m3

### ): Storage Temperature (°F)



### Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM L STA** **RTUP, SHUTDOWN, A ND MA** **LFUNCTION**

**Instructions**
1. Complete this form for 2013 only. 2. Submit with your response to this survey, copies of all records of emissions during periods of process startup, shutdown, and malfunctions for 2013 only. 3. Refer to "Enclosure 1" for additional instructions and details.

No

Startup Shutdown 0.5 0.5

For a malfunction:

Yes Yes

No No

The stripping column is started and set to operating conditions prior to introduction of unstripped PVC slurry (with water). Once slurry flow is initiated, the column is already at operating conditions of temperature and pressure. Stripping conditions (steam-to-PVC ratio, temperature, and pressure) are maintained throughout the shutdown. No higher than normal emissions are expected as a result of the shutdown.

(select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) **Total Emissions During Startup, Shutdown, or Malfunction Event**  Were all of the emissions control devices operating for the entire duration of the startup, shutdown, or malfunction event? Startup, Shutdown or Malfunction? If startup or shutdown, what was the duration (hours):

Provide a short description of the malfunction and the circumstances:

If No, which control devices were not operating (Control Equipment ID), for how long, and why:

Were permitted emissions limits ex ceeded? Provide a description of the procedures used to alert the owner/operator that the malfunction occurred. If the malfunction resulted in a release of emissions, describe any indicators used to signal and/or measure the release. Is there a written startup, shutdown and/or malfunction plan for the process unit? Provide a description of the systems and equipment in place that function to notify operators that a malfunction**is occurring**

. For year 2013, the facility is not subject to a regulation that requires a Startup, Shutdown and Malfunction plan. The PVC manufacturing process is highly automated, incorporating interlocks and alarms for process variables that could lead to a Health, Environmental or Process Safety event. Critical process variables are equipped with alarms that report through the DCS to the central control room which is staffed continuously. If appropriate action is not taken by operations based on alarms and the critical process variable, then automated interlocks will act to control the process and return it to a safe state. Implementation of the OSHA 119 PSM standard and industry standards ensures that critical process variables are alarmed and interlocked. The DCS and associated process instrumentation are maintained to ensure a high degree of reliability. In addition to these process control systems, the manufacturing site is monitored continuously with an area GC/MS systemto ensure personnel protection in all VCM containing areas, as well as LEL monitors throughout the VCM handling areas to warn of potential explosion hazards due to unplanned VCM release. Corrective action plans are in place in the event of either GC/MS or LEL alarms.

Applicable standard or regulation:

Describe what actions, if any, were taken to minimize emissions to the atmosphere:

Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM P PROCESS VENT EMISSIONS TESTING DATA** 

**Instructions**
1. Copy this worksheet as necessary for pollutants/compounds sampled on different dates. 2. For multiple control devices, users may copy this worksheet within this workbook.

**Control Equipment ID:** C-303 Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the PVC process and another process unit (non-PVC) ("combined"): Combined

**Parameter CAS Number**  **Run #1 Run #2**  **Run #3 Units**  **Run # 1 Detection Run # 2 Detection**  **Run # 3 Detection Analysis Method Used**  **Note(s)** Enter the CAS number for each pollutant/compound. Do not include dashes. Select appropriate unit from list. Identify the status of measured values relative to the detection levels Identify the status of measured values relative to the detection levels Identify the status of measured values relative to the detection levels Where applicable, select the analysis method used. For all pollutants/compounds, provide any other information supporting information you think is necessary about this test report. Test Date (mm/dd/yy) **Required Operating Parameters During Test** Total Heat Input (MMBtu/hr) MMBTU/hr Fuel 1 Feed Rate MMBTU/hr HHV BTU/scf Fuel 2 Feed Rate MMBTU/hr HHV BTU/scf Fuel 3 Feed Rate MMBTU/hr HHV BTU/scf Flow Rate dscfm Temperature deg F Moisture % O2 % CO2 % Number of PVC resin grades being produced during sampling Number of PVC resin grades being produced (as percentage of all resin grades produced by facility) % **Testing Data** Compound CAS Number Benzene 71432 ppmvd @ 3% O2 SW-846 Method 8260B Chloroethane 75003 ppmvd @ 3% O2 SW-846 Method 8260B Chloroform 67663 ppmvd @ 3% O2 SW-846 Method 8260B Chloroprene 126998 ppmvd @ 3% O2 SW-846 Method 8260B 1,1-Dichloroethane 75343 ppmvd @ 3% O2 SW-846 Method 8260B 1,2-Dichloroethane 107062 ppmvd @ 3% O2 SW-846 Method 8260B n-Hexane 110543 ppmvd @ 3% O2 SW-846 Method 8260B Methylene chloride 75092 ppmvd @ 3% O2 SW-846 Method 8260B Toluene 108883 ppmvd @ 3% O2 SW-846 Method 8260B 1,1,1-Trichloroethane 71556 ppmvd @ 3% O2 SW-846 Method 8260B 1,1,2-Trichloroethane 79005 ppmvd @ 3% O2 SW-846 Method 8260B Vinylidene chloride 75354 ppmvd @ 3% O2 SW-846 Method 8260B Acetophenone 98862 ppmvd @ 3% O2 SW-846 Method 8270D Bis(2-ethylhexyl) phthalate (DEHP) 117817 ppmvd @ 3% O2 SW-846 Method 8270D 1,4-Dichlorobenzene 106467 ppmvd @ 3% O2 SW-846 Method 8270D 2,4-Dinitrophenol 51285 ppmvd @ 3% O2 SW-846 Method 8270D Hexachlorobutadiene 87683 ppmvd @ 3% O2 SW-846 Method 8270D Hydroquinone 123319 ppmvd @ 3% O2 SW-846 Method 8270D Naphthalene 91203 ppmvd @ 3% O2 SW-846 Method 8270D Phenol 108952 ppmvd @ 3% O2 SW-846 Method 8270D 1,2,4-Trichlorobenzene 120821 ppmvd @ 3% O2 SW-846 Method 8270D Acetaldehyde 75070 ppmvd @ 3% O2 1,3-Butadiene 106990 ppmvd @ 3% O2 Chlorobenzene 108907 ppmvd @ 3% O2 Chloromethane 74873 ppmvd @ 3% O2 Cumene 98828 ppmvd @ 3% O2 Ethylbenzene 100414 ppmvd @ 3% O2 Ethylene glycol 107211 ppmvd @ 3% O2 Formaldehyde 50000 ppmvd @ 3% O2 Methanol 67561 ppmvd @ 3% O2 1,1,2,2-Tetrachloroethane 79345 ppmvd @ 3% O2 2,2,4-Trimethylpentane 540841 ppmvd @ 3% O2 Vinyl acetate 108054 ppmvd @ 3% O2 Vinyl bromide 593602 ppmvd @ 3% O2 Xylenes (isomers and mixtures) 1330207 ppmvd @ 3% O2 Vinyl chloride 75014 ppbvd @ 3% O2 US EPA Method 18 Total hydrocarbon (THC) N/A ppmvd as propane @ 3% O2 US EPA Method 25A Methane (CH4) 74828 ppmvd @ 3% O2 Enter numerical value only.

Enter numerical value only. OxyChem completed process vent emissions testing on November 14, 2014.

Page 1 of 1 PVC Combined Vent Section 114 Survey 11/17/2014**FORM Q**

**TOTA L HYDROCARBON 30-DAY MONITORING**  **Note: Partial Data Set; Complete 30-Day Monitoring Data to be provided via Supplemental Submission**
**Instructions**
1. For multiple control devices, users may copy this worksheet within this workbook. 2. Add additional rows as necessary to provide 30 days of monitoring data.

**Control Equipment ID:** C-301A

Combined

**Date and Time THC Reading**  **CH4 Reading O2 level in exhaust gas**  **Moisture in exhaust gas**  **PVC Type PVC Grade**  **Control Device Temperature**  **Control Device**

**Operations Indicator THC Monitoring**  **Operations Indicator**

MM/DD/YYYY HH:MM (ppmvd as propane @ 3% O2) (ppmvd @ 3% O2) (% by volume, dry) (% by volume) (e.g., suspension, dispersion/emulsion, bulk, etc.) (e.g., GP, HMW, LMW, etc.) (degF) (note periods of start-up, Shutdown, malfunctions, or normal operation) (note periods of abnormal operations) 10/03/2014 10:25 2.31 0.34 6.04 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.05 Normal Operation Normal Operation 10/03/2014 11:25 2.22 0.32 6.03 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.03 Normal Operation Normal Operation 10/03/2014 12:25 2.03 0.32 5.98 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.01 Normal Operation Normal Operation 10/03/2014 13:25 1.88 0.10 5.99 17.27 Suspension G-7 (A Line), G-6 (B Line) 950.09 Normal Operation Normal Operation 10/07/2014 11:35 1.24 0.26 6.03 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.96 Normal Operation Normal Operation 10/07/2014 12:35 0.89 0.22 5.97 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.23 Normal Operation Normal Operation 10/07/2014 13:35 0.89 0.21 5.92 23.49 Suspension G-3 (A Line), G-6 (B Line) 951.01 Normal Operation Normal Operation 10/07/2014 14:35 0.89 0.21 5.87 23.49 Suspension G-3 (A Line), G-6 (B Line) 948.37 Normal Operation Normal Operation 10/07/2014 15:35 0.89 0.21 5.86 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.91 Normal Operation Normal Operation 10/07/2014 16:35 0.90 0.22 6.01 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.53 Normal Operation Normal Operation 10/07/2014 17:35 0.90 0.22 6.04 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.19 Normal Operation Normal Operation 10/07/2014 18:35 0.90 0.22 6.03 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.22 Normal Operation Normal Operation 10/07/2014 19:35 0.90 0.22 6.10 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.98 Normal Operation Normal Operation 10/07/2014 20:35 0.90 0.22 6.10 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.75 Normal Operation Normal Operation 10/07/2014 21:35 0.90 0.22 5.99 23.49 Suspension G-3 (A Line), G-6 (B Line) 949.57 Normal Operation Normal Operation 10/07/2014 22:35 0.89 0.22 5.95 23.49 Suspension G-3 (A Line), G-6 (B Line) 950.2 Normal Operation Normal Operation 10/07/2014 23:35 0.89 0.22 5.97 23.49 Suspension G-3 (A Line), G-6 (B Line) 950 Normal Operation Normal Operation 10/08/2014 00:35 0.90 0.22 5.99 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.02 Normal Operation Normal Operation 10/08/2014 01:35 0.89 0.22 5.95 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.76 Normal Operation Normal Operation 10/08/2014 02:35 0.89 0.21 5.86 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.07 Normal Operation Normal Operation 10/08/2014 03:35 0.90 0.22 6.01 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.1 Normal Operation Normal Operation 10/08/2014 04:35 0.90 0.22 6.00 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.04 Normal Operation Normal Operation 10/08/2014 05:35 0.90 0.22 5.99 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.09 Normal Operation Normal Operation 10/08/2014 06:35 0.90 0.22 6.03 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.05 Normal Operation Normal Operation 10/08/2014 07:35 0.48 0.12 3.71 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.54 Normal Operation Normal Operation 10/08/2014 09:00 1.23 0.27 6.18 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.91 Normal Operation Normal Operation 10/08/2014 10:00 1.19 0.27 6.16 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.06 Normal Operation Normal Operation 10/08/2014 11:00 1.19 0.26 6.11 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.12 Normal Operation Normal Operation 10/08/2014 12:00 1.23 0.25 6.09 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.65 Normal Operation Normal Operation 10/08/2014 13:00 1.32 0.26 6.13 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.9 Normal Operation Normal Operation 10/08/2014 14:00 1.25 0.25 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 948.81 Normal Operation Normal Operation 10/08/2014 15:00 1.32 0.25 6.08 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.95 Normal Operation Normal Operation 10/08/2014 16:00 1.29 0.24 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.81 Normal Operation Normal Operation 10/08/2014 17:00 1.30 0.24 6.03 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.45 Normal Operation Normal Operation 10/08/2014 18:00 1.30 0.25 6.05 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.23 Normal Operation Normal Operation 10/08/2014 19:00 1.30 0.25 6.06 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.72 Normal Operation Normal Operation 10/08/2014 20:00 1.26 0.26 6.01 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.37 Normal Operation Normal Operation 10/08/2014 21:00 1.22 0.25 6.05 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.65 Normal Operation Normal Operation 10/08/2014 22:00 1.22 0.26 6.08 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.49 Normal Operation Normal Operation 10/08/2014 23:00 1.21 0.26 6.10 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.70 Normal Operation Normal Operation 10/09/2014 00:00 1.15 0.26 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.40 Normal Operation Normal Operation 10/09/2014 01:00 1.15 0.27 6.07 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.80 Normal Operation Normal Operation 10/09/2014 02:00 1.12 0.27 6.08 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.29 Normal Operation Normal Operation Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the PVC process and another process unit (non-PVC) ("combined"):



### Page 1 of 2 PVC Combined Vent Section 114 Survey 11/17/2014**FORM Q**

**TOTA L HYDROCARBON 30-DAY MONITORING**  **Note: Partial Data Set; Complete 30-Day Monitoring Data to be provided via Supplemental Submission**
**Instructions**
1. For multiple control devices, users may copy this worksheet within this workbook. 2. Add additional rows as necessary to provide 30 days of monitoring data.

**Control Equipment ID:** C-301A

Combined

**Date and Time THC Reading**  **CH4 Reading O2 level in exhaust gas**  **Moisture in exhaust gas**  **PVC Type PVC Grade**  **Control Device Temperature**  **Control Device**

**Operations Indicator THC Monitoring**  **Operations Indicator**

MM/DD/YYYY HH:MM (ppmvd as propane @ 3% O2) (ppmvd @ 3% O2) (% by volume, dry) (% by volume) (e.g., suspension, dispersion/emulsion, bulk, etc.) (e.g., GP, HMW, LMW, etc.) (degF) (note periods of start-up, Shutdown, malfunctions, or normal operation) (note periods of abnormal operations) Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the PVC process and another process unit (non-PVC) ("combined"):

10/09/2014 03:00 1.14 0.28 6.04 25.31 Suspension G-3 (A Line), G-5 (B Line) 949.29 Normal Operation Normal Operation 10/09/2014 04:00 1.16 0.27 5.97 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.40 Normal Operation Normal Operation 10/09/2014 05:00 1.14 0.27 6.01 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.29 Normal Operation Normal Operation 10/09/2014 06:00 1.16 0.28 6.04 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.01 Normal Operation Normal Operation 10/09/2014 07:00 1.17 0.27 5.99 25.31 Suspension G-3 (A Line), G-5 (B Line) 950.08 Normal Operation Normal Operation 10/09/2014 09:12 1.10 0.26 5.98 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.10 Normal Operation Normal Operation 10/09/2014 10:12 1.15 0.27 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.99 Normal Operation Normal Operation 10/09/2014 11:12 1.22 0.27 6.08 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.77 Normal Operation Normal Operation 10/09/2014 12:12 1.22 0.25 6.09 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.81 Normal Operation Normal Operation 10/09/2014 13:12 1.23 0.25 6.04 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.33 Normal Operation Normal Operation 10/09/2014 14:12 1.20 0.25 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.07 Normal Operation Normal Operation 10/09/2014 15:12 1.21 0.23 6.07 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.37 Normal Operation Normal Operation 10/09/2014 16:12 1.24 0.23 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.81 Normal Operation Normal Operation 10/09/2014 17:12 1.23 0.25 6.01 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.27 Normal Operation Normal Operation 10/09/2014 18:12 1.16 0.25 6.04 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.61 Normal Operation Normal Operation 10/09/2014 19:12 1.15 0.27 6.05 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.37 Normal Operation Normal Operation 10/09/2014 20:12 1.15 0.27 6.06 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.88 Normal Operation Normal Operation 10/09/2014 21:12 1.12 0.27 6.03 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.54 Normal Operation Normal Operation 10/09/2014 22:12 1.16 0.25 6.02 23.49 Suspension G-3 (A Line), G-5 (B Line) 948.90 Normal Operation Normal Operation 10/09/2014 23:12 1.13 0.25 5.98 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.29 Normal Operation Normal Operation 10/10/2014 00:12 1.11 0.26 5.97 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.83 Normal Operation Normal Operation 10/10/2014 01:12 1.13 0.26 5.93 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.77 Normal Operation Normal Operation 10/10/2014 02:12 1.06 0.26 5.46 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.84 Normal Operation Normal Operation 10/10/2014 03:12 1.05 0.24 5.68 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.49 Normal Operation Normal Operation 10/10/2014 04:12 1.06 0.26 6.46 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.48 Normal Operation Normal Operation 10/10/2014 05:12 1.06 0.26 6.50 23.49 Suspension G-3 (A Line), G-5 (B Line) 949.77 Normal Operation Normal Operation 10/10/2014 06:12 1.06 0.26 6.47 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.18 Normal Operation Normal Operation 10/10/2014 07:12 1.04 0.26 6.45 23.49 Suspension G-3 (A Line), G-5 (B Line) 950.08 Normal Operation Normal Operation



### Page 2 of 2 PVC Combined Vent Section 114 Survey 11/17/2014