P. 1


# OAR Box 1770 Prepped by Keeia Richards



## Document

Number: 

# 34) XII-B-2 Docket Number: 

# A-79-1 5

Printed 10/28/2008 10:20:28 AM Sheet 34 of 93P. 2 

# 4 DocJcetNo.A-7 9 J 5 ItemNo.XU-B- 2 Draft Post-MACT Screening Risk

Assessment

for the Coke Oven Source Category 

# Q^m^ycayj

APPENDIX B Facilit y Emissio n Calculation s 

# D.?.j ^ rep - 4

* T-if,L s

B- 1P. 3 1



## Sources fo rCoke Oven Emissions Data : Batteries : Revise dbatter y emission s estimate s provide db y Ro y Huntle y (EPA , OAQPS)
. 9/7/2000
. Pushing/Quenching/Combustion/By-Produc tChemica l Plan t(Process Equipment) : Revise dEmission s fo

r Cok e Ove nFacilities , IC

FMemorandu

mdated8/21/2000 , Table : Summar y o f Allowable Emission s fro

mCok e Ove nFacilities
. By-Produc

tPlant(Fugitive Equipmen tLeak) : Revise dFugitiv e EmissionCalculations , ICFMemorandu mdate d8/31/2000 , Table : Fugitiv e Equipmen t Lea k Emission s fro

mBy-Produc

t Chemica l Plants
. Base

do ntelephone conversationwit h Ro y Huntle y an dTe dPalm ao n9/12/2000 , averag

e emissio nfactor s (colum n3 ) wer e use dfo r all facilitie s except

Ashland
. Monitoredemission s dat aareaavailable fo

r Ashlan d(colum n4)
. V

\P. 4



## Revise d Batter y Emission

s Estimates Provided b

y Ro y Huntley . (EPA , OAQPS) , 9/7/0 0

## BS O Emissio nRate s for Doors , Lids , Offtakes , an dChargin g Allowabl e Emission s

Facilit y A K Steel , Middletow n A K Steel , Ashlan d Eri e Coke , Eri e Gul f State s Steel , Gadsde n Ne w Boston , Portsmout h Tonawanda , Buffal o Batter y 3 3 4 A B 2 3 2 2 No , O f Oven s 

# n 7 6 7 0 2 3 3 5 4 9 6 3 7 0 6 0 Chargin g 'lim e s/ch g (1 ) 

### 11.00 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 f ercen tLeak s (&) PL D 

### 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 ^.5 0 PL L



### 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 PL O



### 3.00 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 Ma x s/ch g



### 9.3 4 50.1 0 50.1 0 20.8 3 20.8 3 7.8 4 7.8 4 18.2 7 14.42 Ma x PL D



### 5.4 1 5.3 3 5.3 3 10.8 7 11.4 3 6.0 0 4.6 9 9.4 2 9.1 7 

### Ma

x PLL 0.4 8 0.9 7 0.9 7 1.7 1 2.2 6 0.8 7 4.6 9 2.2 7 1.3 9 

### NOTE : For allowabl e emissions , emissio nlimit s fo r existin g by-product

batterie s wa s used
. ' oj (1 ) Allowable chargin g time inDecember 199 5 MACT track

limit
. (2 ) Eri e an dTonawandaare foundr

y ovens . Th e res t

ar e furnace ovens . Decembe r 199 5 MACT track

limit s were used
. Non e of thes e oven s hav e tal l doors
. 

# \y- n 

# M « 

# ^y^f •UVi c A/V 0- 

# U: W.' i l/A/ J < »\ f A/ •Aj. !-e>A7-\

f> '<&>..< !

Provide d by : Di b Paul/IC F batter~r.xl s - Battery Leaks-Allowabl e 11/8/2000-9:3 2 A M

<y XI

bi

### BS O Emissio n Rate s fo rDoors , Lids , Offtakes , an d Chargin g Allowabl e Emission s

Facilit y AK Steel , Middletow n A K Steel , Ashlan d Eri e Coke , Eri e Gul f State s Steel , Gadsde n Ne w Boston , Portsmout h Tonawanda , Buffal o Batter y 

### 3 3 4 A B 2 3 2 2 ADSOIUt e LOW i lb/h r o f BS O Visibl e Doo r 0.334 4 0.334 4 0.308 0 0.101 2 0.154 0 0.215 6 0.277 2 0.308 0 0.264 0 Lowe r

Hound t__stimate s o t

amission s lb/h r o f BS O Visibl e Doo r

NVL D Total s 0.334 4 0.430 9 0.765 3 0.334 4 0.308 0 0.101 2 0.154 0 0.215 6 0.277 2 0.308 0 0.264 0 0.430 9

0.396 9 0.130 4 0.198 5 0.277 8 0.357 2 0.396 9 0.340 2 0.765 3

0.704 9 0.231 6 0.352 5 0.493 4 0.634 4 0.704 9 0.604 2 Lowe r nes t tstimat e lb/h r o f BS O Visibl e Doo r

NVL D 0.342 8 0.574 6 0.342 8 0.315 7 0.103 7 0.157 9 0.221 0 0.284 1 0.315 7 0.270 6 0.574 6

0.529 2 0.173 9 0.264 6 0.370 4 0.476 3 0.529 2 0.453 6 

### DOORS "

0.917 3 0.917 3 0.844 9 0.277 6 0.422 5 0.591 4 0.760 4 0.844 9 0.724 2 Visibl e

0.4 1 o O 0.418 0 0.385 0 0.126 5 0.192 5 0.269 5 0.346 5 0.385 0 0.330 0


### NOTE : Fo r allowabl e emissions , emissionlimit s fo r e ; (1 ) Allowabl e chargin g time i nDecembe

r 199 : (2) Eri e an dTonawand aar

e foundr y ovens . T

l

Provide d by : Di b Paul/IC F batter~r.xl s - Battery Leaks-Allowabl e 11/8/200 0 -9:3 2 A M

## BS O Emissio nRate s fo r Doors , Lids , Offtakes , an dChargin g Allowabl e Emission s

Facilit y A K Steel , Middletow n A K Steel , Ashlan d Eri e Coke , Eri e Gul f State s Steel , Gadsde n Ne w Boston , Portsmout h Tonawanda , Buffal o Batter y 3 3 4 A B 2 3 2 2 UPl * lAKt a

Bes t Lstimat e lb/h ro f BS O 0.017 1 0.017 1 0.015 8 0.005 2 0.007 9 0.011 0 0.014 2 0.015 8 0.013 5 CHAKljrl . L r Bes tLstimat e Lowe rBoun d lb/h ro f BS O 0.000 5 0.047 1 0.000 5 0.047 1 0.000 5 0.043 4 0.000 2 0.014 3 0.000 2 0.021 7 0.000 3 0.030 4 0.000 4 0.039 1 0.000 5 0.043 4 0.000 4 0.037 2 Uppe r Boun d 0.091 2 0.091 2 0.027 6 0.042 0 0.058 8 0.075 6 0.084 0 0.072 0 Lowe rBoun d lb/h r o f BS O 0.365 7 0.365 7 0.110 7 0.168 4 0.235 8 0.303 1 0.336 8 0.288 7
NOTE : For allowabl e emissions , emission limit s fo r e ; (1 ) Allowabl e chargin g time i n Decembe

r 199 : (2 ) Eri e andTonawand aar e foundr y ovens . T

l

Provide d by : Di b Paul/IC F batter-r.xl s - Battery Leaks-Allowabl e 11/8/200 0 -9:3 2 A M 

# s^ BS O Emissio n Rate s fo rDoors , Lids , Offtakes , an d Chargin g Allowabl e Emission s

Facility A K Steel , Middletow n AK Steel , Ashland Eri e Coke , Eri e Gul f State s Steel , Gadsde n Ne w Boston , Portsmout h Tonawanda , Buffal o Batter y 

## 3 3 4 A B 2 3 2 2 nate s o tttmis s gram/se c BS O 0.295 9 0.295 9 0.089 6 0.136 3 0.190 8 0.245 3 0.272 6 0.233 6
NOTE : Fo r allowable emissions , emissio n limit s fo r e ; (1 ) Allowable chargin g time in December 199 : (2) Eri e an

dTonawand aar

e foundr y ovens . T

l

Provided by : Di b Paul/IC F batter-r.xl s - Battery Leaks-Allowabl e 11/8/200 0 - 9:3 2 A M

0 0P. 9 

### ^ & ' • /

CONSULTIN G



### Augus t 21,200 0 Mr
. TedPalm a USEPA Emissio nStandard s Divisio n Ris k & Exposur e Assessmen t

Group MD-1 3 RTP , NC Re : Revise dEmission s Estimate s for Cok e Ove nFacilitie s Dea r Mr
. Palma : IC FConsultin g (ICF ) appreciate s th e opportunit y t o suppor

t EPA' s residual ris k assessmen t projec t for th e coke ovensourc e category . Enclose dar e th e revise d calculation s o f

emissio nrate s an

dmodelin g parameters . Th e revision s reflec t throughpu t change s an

dothe r site-specifi c parameter s obtaine dfromCOETF/ACCCI
. Th e revision s als o reflect

our discussion s durin g th e Jun e 14t h

### an dAugus t 16 t h

### meetings
. The following ar e enclosed :

• Facility-wid e emission s • Summar

y o f emission s frombatterie s • Summar

y o f pushing/quenching/combustio nemission s • Summar

y o f byproduc t

chemica l plant emission s • Modelin g parameter s • Supporting documentatio n I a me-mailing yo u all dis k

files use dfo

r th e abov e calculations
. I f yo u hav e any questions , pleas e d o no t

hesitat e to call me a

t (919 ) 233-0382
. Sincerely , r v / ' o A 

# :V

_y-yy- ' DibPaul , P.E
. Projec t Manage r En d d p

9300 Le e Highwa y — —Fairfax, V

A 22031-120 7 USA

—703-934-3000— - 703-934-374 0 fa x—www.icfconsulting.co m

## EMISSION S SUMMAR Y P.1 0



### •-iaAftij-y \ 7*<QuZ22p7~2 •. 3; - &*tS.V2''^.-

j '.;' . • ;

• 3 ihjcJ O ;..,'.-

•

• ,x-.;- >::•••:> ::.^cp^::ii.- 

## j^7-<-y

'«$O 0 .,••.. - .VV0:*'>'^^0&O::'^-'^Ai! - ••• - '•' • 

# • y '^.iKSilPSvil f": :



# o ; v

• . • ' '•-••:Sv*>K£ifyZ:$l4:^^ r :..<-\--:-.y : .:,. ••••-.-•.. •: ••••(.•*•••:-,•,.•'• •.<:•• •SUMMAR YO F ALLOWABL E EMISSION S FRO M COK E OVE N FACILITIE S Al l Emission s ar e i n lb/h r

Facilit y A KSteel , Middletow n A KSteel , Ashlan d A KSteel , Ashlan d Eri e Coke , Eri e Eri e Coke , Eri e Gul fState s Steel , Gadsde n Gul fState s Steel , Gadsde n Ne wBoston , Portsmout h Tonawanda , Buffal o Indian a Harbor , E
. Chicag o Batter y 3 3 4 A B 2 3 2 2 A/B/C/ D Emission s from

Batterie s (1 ) Visibl e & Non visibl e BS O 1.713 4 1.713 4 1.578 2 0.518 5 0.789 1 1.104 7 1.420 3 1.578 2 1.352 7 N A Visibl e Onl y BS O 0.420 7 0.420 7 0.387 5 0.127 3 0.193 7 0.271 2 0.348 7 0.387 5 0.332 1 N A Emission s from Pushin g /Quenchin g

/Combustio n (2 ) Pushin g BS O 0.913 2 0.821 9 1.278 5 0.13 7 0.205 5 0.433 8 0.570 8 0.684 9 0.433 8 1.050 2 Quenchin g

BS O 0.479 5 0.433 8 0.662 1 0.068 5 0.091 3 0.251 1 0.342 5 0.433 8 0.228 3 N A Combustio n

BS O 1.2 1 0.41 1 1.48 4 0.296 8 N A 0.730 6 0.936 1 0.456 6 0.753 4 N A By-produc t Chemica l Plan t

Proces s Equipmen t (3 ) Benzen e 0.237 0 1.046 1 0.037 5 0.530 3 0.358 5 0.205 4 N A Toluen e

0.014 2 0.062 8 0.002 2 0.031 8 0.021 5 0.012 3 N A Xylene s

0.007 1 0.031 4 0.001 1 0.015 9 0.010 8 0.006 2 N A Fugitiv e Equipmen t Lea k (4 ) Benzen e 0.000 0 0.229 2 0.000 0 0.005 5 0.002 3 0.000 1 N A
NOTE : (1 ) Se e spreadshee t Battery_Emissions-Batter yLeaks-Summar

y (2 ) Se e spreadshee t P-Q- C emission s (3 ) Se e spreadshee t byproduct_emissions
. Actua l emission s = allowabl e emissions
. There i s on e by-product chemica l plan t pe rfacility
. (4 ) Se e spreadshee t fugitive_emissions
. Actua l emission s = allowabl e emissions
. Ther e i s on e by-product chemica l plan t pe rfacility
. N A= not available/no t applicabl e

Dl b Pau l IC F Consultin g Facility-Summar y 8/21A30-3:1 2 P MP.1 2



### Summary of

BS O Emission Rate s fo rDoors , Lids , OfTtakes , an d Chargin g Actual and Allowabl e Emission s Recovery Ovens 

## V

Facility

A KSteel , Middletown A KSteel , Ashland
Eri e Coke, Erie Gul f State s Steel , Gadsde n
NewBoston . Portsmout

h Tonawanda

, Buffalo Batter y



### 3 3 4 A B 2 3 

### 2 2 Tota

l Actual Emissions , lb/h r(1 ) Visibl e & Non visibl e Doo r Leaks 1.4837 1.491 3 1.373 6 0.448 8 0.673 2 0.938 1 1.224 0 1.414 6 1.1892

.. . Visibl e Doo r

Leak s Onl y 0.143 4 0.152 8 0.140 8 0.042 9 0.052 7 0.070 5 0.113 6 0.189 0 0.137 2 Total Allowabl e Emissions , lb/h r(2 )

Visibl e & Non visibl e Doo r Leak s 1.713 4 1.713 4 1.578 2 0.518 5 0.789 1 1.104 7 1.4203 1.578 2 1.352 7 Visibl e Doo r

Leak s Onl y 0.420 7 0.420 7 0.387 5 0.127 3 0.193 7 0.271 2 0.348 7 0.387 5 0.332 1
NOTE : (1 ) Tota l actua l emission s from doors , lids , offtakes , an d charging . Actua l emission s ar

e base d o n Method 303 inspectio n data. (2 ) Tota l allowable emission s fro

m doors , lids , offtakes , and charging . Allowable emission s are base d o n MAC T emissio n limits fo rexistin g by-productbatteries .

Provide d by. Di b Paul/IC F BaneryEmission s - Batter y Leaks-Summar

y 8/21/00-11:5 3 AMSummar y of BS O Emissio n Rate s fo r Pushing , Quenching , an d Combustio n Stac k Allowabl e Emission s

Batter y A KSteel , Middletown , OH , Batter y3 A KSteel , Ashland , KY , Batter y3 A KSteel , Ashland
. KY , Batter y4 Eri e Coke , Erie , P ABatter yA Eri e Coke , Erie , P ABatter yB Gul fStates , Gadsden , AL , Batter y2 Gul fStates , Gadsden , AL , Batter y3 Ne wBosto n Coke , Portsmouth , OH , Batter y2 Tonawand a Coke , Tonawanda , NY , Batter y2 Indian a Harbor , Eas t Chicago , I N Allowabl e Emission s Pushin g 4 3. 6 5. 6 0. 6 0. 9 1. 9 2. 5 3 1. 0 4. 6 Quenchin g

2. 1 1. 0 2. 9 0. 3 0. 4 1. 1 1. 5 1. 9 1 N A ,tpy( D

Combustio n 5. 3 1. 8 6. 5 1. 3 Not e (3 ) 3. 2 4. 1 2 3. 3 N A Allowabl e Emissions , lb/h r(2 )

Pushin g 0.913 2 0.821 9 1.278 5 0.137 0 0.205 5 0.433 8 0.570 8 0.684 9 0.433 8 1.050 2 Quenchin g

0.479 5 0.433 8 0.662 1 0.068 5 0.091 3 0.251 1 0.342 5 0.433 8 0.228 3 N A Combustio n

1.210 0 0.411 0 1.484 0 0.296 8 Not e (3 ) 0.730 6 0.936 1 0.456 6 0.753 4 N A
NOTE : (1 ) Allowabl e emission s base d o n methylen e chlorid e extractable s data
. Thi s informatio n wa s prepare d b yMarvi n Branscom e o f RTI
. (2 ) lb/h r= tp y* 200 0 lb/to n / (876 0 hr/yr) (3 ) On e combustio n stac k serve s bot h batteries
. N A= not applicable , a s non-recover yove n i s les s likel yt o produc e gree n coke , an d HA P dat a i s no t available
.

Provided by : Marvi n Branscome/RT I Prepared by : Di b Paul/IC F P-Q-C_emisslon s Sheet l 8/18ADO-11:0 6 A M

TJSummar y o fActua l BT XEmission s Proces s Equipmen t A t By-Produc t Chemica l Plan t Compan y A KStee l A KStee l Eri e Cok e Gul fState s Stee l Ne wBosto n Cok e Tonawand a Cok e Locatio n Middletown , O H Ashland , KY 

### Erie , P A Gadsden , A L Ne wBoston , O H Tonawanda , N Y Actua l Emissions , lb/y r Benzen e (1 ) 2.07 6 9,16 3 32 8 4,64 5 3,14 1 1,79 9 Toluen e (2 )

12 5 55 0 2 0 27 9 18 8 10 8 Xylene s (3 )

6 2 27 5 1 0 13 9 9 4 5 4 Actua l Emissions , lb/h r(4 ) Benzen e 0.237 0 1.046 1 0.037 5 0.530 3 0.358 5 0.205 4 Toluen e

0.014 2 0.062 8 0.002 2 0.031 8 0.021 5 0.012 3 Xylene s

0.007 1 0.031 4 0.001 1 0.015 9 0.010 8 0.006 2 NOTE : (1 ) Revise d estimate s base d o n update d throughpu t rates
. 98 % contro l efficienc ywa s assume d fo rta rinterceptin g sump . (2 ) Toluen e emission s a t 0.0 6 time s benzen e emissio n rate
. Th e facto ri s base d o n informatio n i n ES D files
. (3 ) Xylen e emission s a t 0.0 3 time s benzen e emissio n rate
. . Th e facto ri s base d o n informatio n i n ES D files
. (4 ) lb/h r= lb/yr * 1/876 0

IC F Consultin g Dl b Pau l 1of 1 byproduct_emlsslon s 8/21/DO - 2:5 9 P M

VTabl e 5.5- 1 (Revised ) Coa l an d Cok

e Throughpu t Calculatio n
Compan y A KSlee l A KStee l A KStee l Eri e Cok e Eri e Cok e Gul fState s Stee l Gul fState s Slee l Ne wBosto n Cok e Tonawand a Cok e Inlan d Stee l Inlan d Stee l Inlan d Stee l Inlan d Stee l Locatio n Middletown , O H Ashland , K Y Ashland , K Y Erie , P A Erie , P A Gadsden , A L Gadsden , A L Ne wBoston ; O H Tonawanda , N Y Indian a Harbor , I L Indian a Harbor , I L Indian a Harbor , I L Indian a Harbor , I L Batter y 3 3 4 A B 2 3 2 2 A B C D No
. o f oven s (1 ) 7 6 7 6 7 0 2 3 3 5 4 9 6 3 7 0 6 0 6 7 6 7 6 7 6 7 Annua l cok e production , tons/y r(2 ) 423,25 2 376,34 1 588,63 6 65,08 3 99.04 0 226.67 1 291,43 3 353,09 1 219,43 9 360.00 0 360.00 0 360,00 0 360,00 0 Annua l coa l throughput , (1.00 0 tpy ) (2 ) 592.0 0 533.0 0 833.0 0 79.0 0 120.0 0 315.0 0 438.0 0 530.0 0 275.0 0 570.0 0 570.0 0 570.0 0 570.0 0 Hourl ycoa l rate , tons/h r pe rove n (3 )

0. 9 0. 8 1. 4 0. 4 0. 4 0. 7 0. 8 0. 9 0. 5 1. 0 1. 0 1. 0 1. 0 NOTE : (1 ) Fro m cokesurvey.xl s receive d fro m EPA
. (2 ) Site-specifi cdat a fro m COETF/ACCCI
. Throughpu t dat a ar e fo r1998
. Th e dat a wa s verified , an d change s were mad e wher e necessary , followin g discussion s wit h individua l site s an d Marvi n Branscom e o f RTI
. (3 ) Se e sampl e calculation
.
Sampl e Calculation : Houri ycoa l rat e pe rove n = (annua l coa l rate , "000 tpy ) * 1.000 / (no
. o f ovens ) /

8.76 0 hr/y r Fo rIndian a Harbor , th e coa l rat e wa s divide d equall yamon g th e fou rbatteries
.

IC F Consultin g Dl b Pau l 1 o f1 throughput.ad d 8/21/00 - 12:1 7 P M

T J O lCombustio n Stac k Parameter s (Revised ) Sit e A k Stee l Middletow n A KStee l Ashlan d A KStee l Ashlan d Eri e Cok e Gul fState s Stee l No
. 2 Gul fState s Stee l No. 3 Ne wBosto n Tonawand a Indian a Harbo r Batter y 3 3 4 A/ B 2 3 2 2 A/B/C/ D Di a

(m ) 4.2 7 2. 9 3. 8 2.4 4 3.3 5 3.7 9 2.7 4 2.7 4 5.4 9 Are a (m2 )

14.3 1 6.6 0 11.3 4 4.6 7 8.8 1 11.2 8 5.8 9 5.8 9 23.6 6 Are a

(ft2 ) 153.9 8 71.0 3 121.9 5 50.2 8 94.7 8 121.3 1 63.4 0 63.4 0 254.5 4 Flo w

(acfm ) 156,27 4 54,22 0 190,92 5 37,90 0 96,24 6 123,18 9 60,70 0 97,00 0 560,00 0 exi t ve l

(m/s ) 5.1 6 3.8 8 7.9 5 3.8 3 • 5.1 6 5.1 6 4.8 6 7.7 7 11.1 8 exi t ve l

(ft/s ) 16.9 1 12.7 2 26.0 9 12.5 6 16.9 2 16.9 2 15.9 5 25.4 9 36.6 6 Heigh t

(m ) 76. 2 56.0 8 6 7 57.9 1 76. 2 76. 2 64.0 1 54.8 6 91.4 4 Tem p

(oK ) 51 8 50 5 55 3 51 3 51 8 51 8 47 8 47 8 33 9 NOTE : Stack'flo wdat a wa s no t availabl e fo rGul fState s Steel
. A KStee l Middletow n dat a base d o n similarities
. Use d engineerin g judgemen t an d
Stac k flo wdat a wa s no t availabl e fo rNe wBoston
. Use d engineerin g judgemen t an d Tonawand a dat a base d o n similarities
. Indian a Harbo rdat a i s base d o n dscfm
. Sampl e Calculation : Exi t velocity , m/s = flow , acfm/(area , ft2)/6 0 * 0.304 8

IC F Consultin g E d Carr/Di b Pau l 1 o f1 con.bustion_stack_now 8/21/00-9:0 4 A M

T lP.1 7



### Summar yo fActua l Benzen e Emission s Fugitiv e Equipmen t Lea k A t By-Produc

t Chemica l Plan t
Compan y AKStee l AKStee l Eri e Cok e Gul fStates Stee l Ne wBosto n Cok

e Tonawanda Cok

e Locatio n Middletown , O H Ashland , K

Y Erie , P A Gadsden , A L Ne wBoston , O H Tonawanda , N

Y Actua l Benzen e Emissions , lb/y r 0

2,00 7 0.0 6 4 8 2 0 1 Actua l Benzen e Emissions , lb/h r

0.0000 0.2292 0.0000 0.0055 0.002 3 0.000 1 NOTE : Revised emission s estimate s based o n screenin g factor s i n "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. Fo rAshland , detaile d monitorin g repor t wa s availabl e b

ymonth , quarter , semi-annual , an d annual
. Fo rcomponent

s that leake d above 500 ppmv , i t wa s assumed lea k

occurre d fo rth e entire monitorin g period
. Fo rGul fState s Steel , revise d emission s estimate s ar e fro m th e COET F field studyreport
. Fo rothe rfacilities , emission s estimate s wer e base d o n on e cycl e ofmonitorin g only
. lb/h r= lb/yr/876 0

IC F Consultin g Di b Pau l fugitive_emission s 8/21A30-3:0 2 P MP.1 8



## MODELIN G PARAMETER S

77 l

-

UiUiftym;.

• A-: ':&>27'



# • I ;^-|J(ii|^|iSt^ffS3S ^

'''y2'c.-Ay--r;^y^pyi''-^7.Vp:l. • '••• '•••'P.1 9



### Summar yo fBuoyancyFlu xCalculation s Compan y

AKStee l AKStee l A KStee l Eri e Cok e Eri e Cok e Gul fStates Stee l Gul fStates Stee l Ne wBosto n Cok

e Tonawand a Cok

e Inlan d Stee l Inlan d Stee l Inlan d Stee l Inlan d Stee l Locatio n

Middletown , O H Ashland , K

Y Ashland , K

Y Erie , P A Erie , P A Gadsden , A L Gadsden , A L Ne wBoston , O H Tonawanda , N Y Indian a Harbor , I L Indian a Harbor , I L Indian a Harbor , I L Indian a Harbor , I L Batter y

3 3

. 4 A B 2 3 2 2 A B C D Tota l BuoyancyFlux ,

m4/s3 Previou s Estimat e (1 ) 30 5 637 97 6 46 6 2 242 340 192 135 24 6 24 6 24 6 24 6 Revised Estimat e (2 ) 304 297 432 3 8 54 17 2 252 19 1 12 8 24 5 245 245 24 5 NOTE : (1 ) Emission s estimate s submitte d b yIC F i n Ma

y2000
. (2 ) Emission s estimate s revise d b yIC F based o n throughpu t changes
. See Appendi xB fo rrevise d estimate s ofbuoyanc yflux
.

IC F Consultin g Di b Pau l 1 o f1 flux_summar y 8/90)-

_ 11:36A M

### Quenc h Towe rParameter s (Revised )

Compan y

A KSteel , Middletow n A KSteel , Ashlan d A KSteel , Ashlan d Eri e Cok e Gul fState s Stee l Ne wBosto n Tonawand a Tonawand a Indian a Harbo rA/ B Indian a Harbo rC/ D Batter y

3 3 4 A/ B 2/ 3 2 2 2 A/ B C/ D Height , ft

10 0

6 8 6 8 5 0 56. 5 5 0 4 0 6 0 6 0 6 0 Width , ft

1 4

1 4 2 1 1 8 1 5 1 4 2 0 2 1 2 1 Length , f t

5 5 7 8 3 7 37. 5 4 5 5 1 5 1 7 2 7 2 Dia , f t

1 4 Temp , o F

22 0 22 0 22 0 22 0 22 0 22 0 22 0 22 0 22 0 22 0 Duratio n o f Quench , s 8 2 7 3 11 0 10 8 9 0 7 5 8 0 8 0 7 0 7 0 Quenc h Flow , ga l 5,20 0 7,00 0 9,50 0 5.00 0 5.00 0 1,80 0 10,00 0 10,00 0 10,00 0 10,00 0 Make-up , ga l 2,25 0 3,50 0 4,75 0 2,50 0 2.50 0 90 0 2.00 0 10.00 0 5.00 0 5,00 0 Velocity , ft/s
2 0

7 5 3 5 2 4 1 4 5 5 

### Not e 1
. Sit e dat a wa s use d wher e available
. 2
. Lul a Melton' s spreadshee t wa s use d where sit e dat a was no t available
. 3
. Make-u p wate rwa s no t availabl e fo ral l quenc h towers fro m site s o rLul a Melton' s spreadsheet
. 4
. Pe rLul a Melton' s spreadsheet , ther e ar e tw o quenc h tower s a t Tonawand a an d two a

t Indian a Harbor
. Se e attache d spreadshee t "quench_flow.xls " fo rsampl e calculations
.

Di b Pau l IC F Consultin g quench_parameter s 8/21/00 - 10:3 0 A MP.2 1



### Quenc h Towe rFlo wCalculatio n AKSteel , Middletown/O H Wate rflo wpe rquenc h Tim e pe rquench Make-u p wate r % o fmake-u p wate rt o stea m Quenc h temperatur

e Diamete ro

fquenc h towe r Quenc h towe rstac k

flow Quenc h towe rvelocit

y 5,200 ga l 82 see s 2,25 0 ga l 50 % 1,12 5 ga l 22 0 deg F 1 4 f t 189,24 4 acf m 2 0 ft/ s Not

e 1 Not e 1 Not e 2 Not e 3 Not e 4 Note l Sampl e calculatio n 1 Sampl e calculatio n 2 Note 5 NOTE : 1
. Fro m site dat

a o rLul a Melton' s spreadshee t title d "cokesurvey.xls"
. 2
. Us e 50% o fquenc h flowwher

e no t available
. 3
. Engineerin g assumption
. 4
. Assume d slightl ysuperheate d vapor , based o n discussio n wit h ACCC I representatives
. T o simplif ycalculations , assume d idea l gas . 5
. Us e lengt h xwidt h wher

e quenc h towe ri s rectangular
. Sampl e calculation : 1
. 1,12 5 gal * 1/82

s • 60s/mi n * 8.3

4 lb/ga l * lbmole/1 8 l b * 359 ft3/lbmol e * (46 0 + 220)/(46 0 + 32 ) 2
. 189,24

4 acf m / (3.1 4 * 14*2 ft2/4)/(60 s/min )

IC F Consultin g Di b Pau l quench_f)o w- Middletwon-O H 8/21/00-10:2 7 A MP.2 2



## SUPPORTIN G DOCUMENTATIO N FO R BATTERYEMISSION S

T 

### $tfeifei&& ; 

### '

^1^0 : _0>0:0.:. . -:.?£$•• y r

?.* • f:«§ii-•;.'•: • r...#j. ,V ! .:i-:- : •

-
SErK_: ' i-t.'K":%«S"S- ; ''t e



## -o o iP4y7p0yPWPP

^#i|ll|i^#^ilflfS3 ; 

## r v..OOf$£-| ^

### BS O Emissio n Rate s fo rDoors , Lids , OfTtakes , an d Chargin g Allowabl e Emission s

Facilit y A K Steel
. Middletow n A K Steel , Ashlan d
Eri e Coke , Eri e Gul f State s Steel , Gadsde n
Ne w Boston , Portsmout h Tonawanda
. Buffal o Batter y 3 3 4 A B 2 3 2 2 No . O f Oven s 7 6 7 6 7 0 2 3 3 5 4 9 6 3 7 0 6 0 Chargin g Tim e s/ch g (t ) 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 12.0 0 Percen tLeak s (2 ) 1

PL D 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 5.5 0 PL L

0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 0.6 0 PL O

3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 3.0 0 DOOR S

Bes tEstimat e lb/h ro f BS O Visibl e ion-visibl e 0.342 8 0.342 8 0.315 7 0.103 7 0.157 9 0.221 0 0.284 1 0.315 7 0.270 6 1.292 8

1.292 8 1.190 7 0.391 2 0.595 4 0.833 5 1.071 6 1.190 7 1.020 6 Total s 1.635 5 1.635 5 1.506 4 0.495 0 0.753 2 1.054 5 1.355 8 1.506 4 1.291 2 

## Lro s Bes tEstimat e lb/h ro f BS O 0.013 7 0.013 7 0.012 6 0.004 1 0.006 3 0.008 8 0.011 3 0.012 6 0.010 8 OFFTAKE S Bes tEstimat e lb/h ro f BS O 0.017 1 0.017 1 0.015 8 0.005 2 0.007 9 0.011 0 0.014 2 0.015 8 0.013 5 CHARGIN G Bes tEstimat e lb/h ro f BS O 0.047 1 0.047 1 0.043 4 0.014 3 0.021 7 0.030 4 0.039 1 0.043 4 0.037 2
NOTE : Fo rallowable emissions , emission limits fo rexistin g by-produc

tbatterie s wa s used . (1 ) Allowable charging time i n Decembe

r1995 MAC

T trac klimit. (2 ) Eri e an d Tonawand

aar e foundr y ovens . The res

tar e furnac e ovens . Decembe

r199 5 MAC T trac klimit s wer e used . Non

e of thes e oven

s hav e tal l doors .

Provide d by : Dib Pnul/ICF Batter y Emission s - Battery Leaks-Allowabl e

8/18/00-9:4 3 A M

### BS O Emissio n Rate s fo rDoors , Lids , OfTtakes , an d Chargin g Actua l Emission s

Facilit y A KSteel , Middletow n A KSteel , Ashlan d
Eri e Coke , Eri e Gul f Slate s Steel , Gadsde n
Ne wBoston , Portsmout

h Tonawanda , Buffal o Batter y 3 3 4 A B 2 3 2 2 No . O f Oven s 7 6 7 6 7 0 2 3 3 5 4 9 6 3 7 0 6 0 Chargin g Tim e Av g s/ch g 2.9 7 3.0 7 3.0 7 3.7 8 3.7 8 1.6 0 1.60 6.3 9 2.3 2 Percen tLeak s Av g PL D 2.0 3 2.1 6 2.1 6 1.97 1.5 0 1.6 4 2.0 8 2.7 3 2.5 9 Av g PL L

0.0 8 0.1 2 0.1 2 0.0 4 0.0 6 0.0 0 0.0 2 0.1 2 0.0 4 Av g PL O

0.6 3 0.6 4 0.6 4 0.6 0 0.8 0 0.1 8 0.1 4 1.25 0.3 9 DOOR S

Bes tEstimat e lb/h ro f BS O Visibl e 0.126 2 0.134 4 0.123 8 0.037 1 0.043 2 0.065 8 0.107 4 0.156 8 0.127 5 ion-visibl e

1.340 3 1.338 5 1.232 8 0.405 9 0.620 5 0.867 6 1.110 4 1.225 6 1.052 0 Total s

1.466 5 1.472 9 1.356 6 0.443 0 0.663 7 0.933 3 1.217 8 1.382 3 1.179 5 

### LIB S Ues i Estimat e lb/h ro f BS O 0.001 9 0.002 7 0.002 5 0.000 2 0.000 6 0.000 1 0.000 3 0.002 6 0.000 7 

### OFFTAKE

S Bes tEstimat e lb/h ro f BS O 0.003 6 0.003 7 0.003 4 0.001 0 0.002 1 0.000 6 0.000 7 0.006 6 0.001 8 CHARGIN G Bes tEstimat e lb/h ro f BS O 0.011 7 0.012 0 0.011 1 0.004 5 0.006 8 0.004 0 0.005 2 0.023 1 0.007 2


### NOTE : 

### Thi s dat awa s provide db y Ro nMyer s o f EPA
.

Provided by : Ro

n Myers/EP

A Revise d by : Di b Paul/IC F Battery_Emission s - Battery Dat a 8/18/00-8:5 3 A MP.2 5



# SUPPORTING DOCUMENTATION FO R BY-PRODUC

TCHEMICA

L PLAN T PROCES S EQUIPMEN

TEMISSiiON^^^^^^f^ ^

-iKhfeJp&'O'
. '•••

: 

## $p£pA:

#£» ' 

### O 

## W&7L

LAi»A •• .P^fi'vUp-:-:
. • ' 1 -~£\L^

-\S.'--;:-^'~-.,$"i±^-..>^': -~-.-9^'~.r*-:->'•: :-r i:i&3_i_ : &£.0_^3£t^-.r * 0>' . :i»_.0^./_; :P.2 6



### Ak Steel , Middletwon/O H Process Equipment Emission s fro m By-Produc t Plan t



# 7 Sourc e

Ta rdecante r Ta rinterceptin g sum p Ta rdewaterin g tan k Ta rstorag e tan k
Flushin g liquo r circulatio n tan k Exces s ammoni a liquo r tan k Was h oi l decante r Tota l (lb/yr ) No . o f

Units' 1 '
2 2 2 1
1
4 1 Ga s

Blanketin g (Yes/No ) Ye s Ye s Ye s Ye s
Ye s
Ye s Ye s Sourc e Heigh t (ft) 12 '

Se e nex t pag e 1 1 1 0 4 0
1 0

Se e nex t pag e 1 0 ' Sourc e Di a o r Length/Widt h 

### (ft f
Se e nex t pag e 47x1 0
1 0 di a x2 2 56. 5 di a

1 0 di a x3 5

Se e nex t page
1 0 di a x3 2 Tan k

Orientatio n (Horiz/Vert )
Hori z Hori z Hori z Vert

Hori z

Ver t Hori z Calculate d

Benzen e Emission s (lb/yr)" ' 130 4 152 4 7 5 3
0
15 2 64 3,10 4 Metho d o f

Calc." '

Mas s Transfe r AP-4 2
TANK S TANK S
N o benzen e dat a
AP-4 2
AP-4 2
V

' Calculate d Benzen e Emission s (lb/yr) 14 ' A P 4 2 factor s 93 1 16 1 35 6 32 2
22 0
2 4 6 3L^OKAP-4 2

Emissio n Facto r (lb/ton) w 0.00220 0 0.00038 0 0.00084 0 0.00076 0
0.00052 0
0.00005 6 0.00015 0

NOTE : 1 ) Multipl e units ar e assume d t o b e operatin g i n parallel . 2 ) Diamete ri

fcylindrica l tank ; lenflt h an d widt h i frectangula rtank . Se e attache d shee t fo rdimension s ofmultipl e units . 3 ) Benzen e emissio n rate calculate d b y site usin g TANK S o rAP-42 . 4 ) Benzen e emissio n rat e calculate d b y IC F usin g Furnac e Plan t Draf t AP-4 2 date d Feb'99 , Tabl e 12.2-19 . Fo rta rinterceptin g sum p wit h pas blanketing , 98 % contro l efficienc y wa s use d pe rRo n Myers ' recommendation . Actua l facilit y throughpu t fo roperatin g yea r199 8 423.25 2 tons/y r Sampl e calculation : Benzen e emission s = AP-4 2 factor , lb/to n o fcok e pushe d * actua l facilit y cok e throughput , tons/y r

IC F Consultin g Prepare d by . Sit

e Update d ty . Di b Pau l 1 of 1 Middletown_Byproducl-re v 8/18/00-11- 2 A MTabl e 4.3- 1 (Revised ) A k Steel , Ashland/K Y Proces s Equipmen t Emission s fro m By-Produc t Plan t

Sourc e Ligh t oi l storag e tan k Ta rdecante r No
. o f Units' 1 ' Ga s

Blanketin g (Yes/No ) Ye s Ye s Sourc e

Heigh t («)' " 1 9 1 2 Sourc e Di a o r Length/Widt h (ft ) U ) 2 0 di a 1 2 di a x5 0 Tan k

Orientatio n (Horiz/Vert ) Ver t Hori z Calculate d

Benzen e Emission s (lb/yr) 1 " 28 2 2,97 2 Metho d o f

Calc.' " TANK S Mas s Transfe r Calculate d

Benzen e Emission s (lb/yr)' 4 ' AP 4 2 factor s

23 2 2.12 3 AP-4 2

Emissio n Facto r (lb/ton ) ,4 » 0.0002 4 0.002 2 Ta rinterceptin g sum p Ye s 1 2 1 2 di a x5 0 Hori z 3.47 4 AP-4 2 36 7 0.0003 8
Ta rdewaterin g tan k Ye s 1 0 1 0 di a x3 0 Hori z TANK S /Mas s Transfe r


## 1*7
< =jo e ) Was h oi l decante r 81 1 0.0008 4 Ta rstorag e tan k Ye s 5 0 3 3 di a Ver t 1 7 TANK S 73 3 0.0007 6 Ligh t oi l condense rven t Ye s 5 3 3 x 6 Ver t 3,43 5 AP-4 2 3.47 4 0.003 6 Ligh t oi l sum p Ye s 1 0 1 0 di a x3 0 Hori z 57 9 AP-4 2 57 9 0.000 6 Flushin g liquo rcirculatio n tan k Ye s 1 0 1 0 di a x3 0 Hori z TANK S 50 2 0.0005 2 Exces s ammoni a liquo rtan k Ye s 3 4 3 0 di a Ver t TANK S 5 4 0.00005 6 Ye s 1 0 1 0 di a x3 0 Hori z 14 7 TANK S Was h oi l circulatio n tan k 1 Ye s 1 0 1 0 di a x3 0 Hori z 5 6 TANK S 14 5 14 5 0.0001 5

0.0001 5 Tota l emissions , lb/y r 10,96 7 ^7^ 7 V3

> o NOTE : 1 ) Multipl e unit s ar e assume d t o b e operatin g i n parallel
. 2 ) Diamete ri f cylindrica l tank ; lengt h an d widt h i f rectangula rtank
. Se e attache d shee t fo rdimension s o f multipl e units
. 3 ) Benzen e emissio n rat e calculate d b ysit e usin g TANK S o rAP-4 2 (olde rtha n Feb'9 9 draft)
. 4 ) Benzen e emissio n rat e calculate d b yIC F usin g Draf t AP-4 2 date d Feb'99 , Tabl e 12.2-19 , benzen e emissio n factor s fo rFurnac e Plant
. Fo rta rinterceptin g sum p wit h ga s blanketing , 98 % contro l efficienc ywa s use d pe rRo n Myers ' recommendation
. 9^16 3

Actua l facilit ythroughpu t fo roperatin g yea r199 8 964,97 7 tons/y r Sampl e calculation : Benzen e emission s = AP-4 2 factor , lb/to n o f cok e pushe d * actua l facilit ycok e throughput , tons/y r Prepared by
. Site Updated by : Dl b Pau l Ashlan d Byproducl.rev- Proces s Equipmen t 8/18/00 - 11:2 4 A M

### Tonawand a Cok e Corporatio n Proces s Equipmen t Emission s fro m By-Produc t Plan t

Sourc e
Ligh t oi l storag e lan k Ta rdecante r Ta rstorag e tan k Ligh t oi l condense rven t Flushin g liquo rcirculatio n tan k r Exces s ammoni a liquo rtan k Was h oil decante r Was h oi l circulallo n tan k Tota l (lb/yr ) No
. o f Unlts m Ga s

Blanketin g (YesffJo )
1 N o 1 2 1 1
1 2 1

. suctio n

suctio n seale d suctio n N o seale d seale d Sourc e Heigh t (ft) m

1 0 1 0 1 0 5 0
1 0 3 0 1 0 1 0 Sourc e Di a o r

Length/Widt h

9 di a 30x1 0 1 0 di a 2 di a 1 0 di a 4 0 di a 8 di a Tan k

Orientatio n (Horlz/Vert )
Horiz
. Horiz
. Horiz
. Vert
. Horiz
. Vert
. Horiz
. Horiz
. Calculate d

Benzen e Emission s (lb/yr)' " 58 9 0 0 0 0 0. 4 0 0 58 9 Metho d o f

Calc. m
TANK S Testin g Testin g Testin g Testin g TANK S Testin g Testin g Calculate d

Benzen e Emission s (lb/yr)' " AP 4 2 factor s 1,36 1 0 0 0 0 43 9 0 0

' ' 1J79 9
. AP-4 2 Emissio n

Factor 1 " (lb/ton )
0.00620 0 N A N A N A N A 0.00200 0 N A N A

NOTE : 1 ) Multipl e unit s ar e assume d t o b e operatin g I n parallel
. 2 ) Diamete ri fcylindrica l tank ; lengt h an d widt h i frectangula rtank
. Se e attache d shee t fo rdimension s o fmultipl e units
. 3 ) Benzen e emissio n rat e calculate d b ysit e usin g TANK S o rtestin g data
. 4 ) Benzen e emissio n rat e calculate d b yIC F usin g Draf t AP-4 2 date d Feb'99
. Tabl e 12.2-19
. benzen e emissio n factor s fo rfoundr yplant
. 5 ) Emission s fro m seale d unit s o rthos e wil h suctio n ar e zer o o rnegligible
. Actua l facilit ythroughpu t fo roperatin g yea r199 8 219.439 tons/y r Sampl e calculation : Benzen e emissions , lb/y r= AP-4 2 factor , lb/to n o fcok e pushe d * actua l facilit ycoke throughput , tons/y r

Prepare d by : Sit e Update d by : Dl b Pau l 1 o f1 Tonawenrf e hvprtx..iet_rs v- Proces s Equipmen t 8/tB/OO - 11:3 3 A M

r o o o

### Eri e Coke Corporatio n Proces s Equipmen t Emission s fro m By-Produc t Plan t

Sourc e



### - Ta rdecante r

Ta rdewaterin g tan k Ta rstorag e tan k Flushin g liquo rcirculatio n tan k Exces s ammoni a liquo rtan k Tota l (lb/yr ) >: ' No . o f Units' 1 '

2 1 1 1 1 Ga s

Blanketin g (Yes/No )
suctio n suctio n suctio n suctio n N o Sourc e Heigh t (ft)' "

10. 0 12. 0 22. 0 15. 0 20. 0 Sourc e Di a o r

Length/Widt h (ft)' *
30x1 0 8. 0 30. 0 10. 0 15. 0 Tan k

Orientatio n (Horlz/Vert )
Horizonta l Horizonta l Vertica l Horizonta l Vertica l Calculate d

Benzen e Emission s (lb/yr)' " 27 0 0 0 0 0 27 0 Metho d o f

Calc.' "
Testin g & Estimat e Testin g Testin g Testin g Calculatio n Estimat e Calculate d

Benzen e Emission s (IWyr)' " AP 4 2 factor s 0 0 0 0 32 8 

### *«*H8S O AP-4 2 Emissio n

Factor' 4 ' (lb/ton )
N A N A N A N A 0.00200 0

NOTE : 1 ) Multipl e units ar e assume d to be operatin g I n parallel . 2 ) Diamete ri fcytindrica i tank ; lengt h an d widt h i frectangula rtank . Se e attache d shee t fo rdimension s o

fmultipl e units . 3 ) Benzen e emissio n rate calculate d b y site usin g tes

t dat a o rothe restimates . 4 ) Benzen e emissio n rate calculate d b y IC F usin g Draf

t AP-4 2 date d Feb'99 , Tabl e 12.2-19 , benzen e emissio n factors fo rfoundr y plant . 5 ) Emission s fro m seale d unit s o rthose wit h suctio n are aero o rnegligible . Actua l facilit

y throughpu t fo roperatin g yea r199 8 164,12 3 tons/y r Sampl e calculation : Benzen e emissions , lb/y r= AP-4 2 factor , lb/to n ofcok e pushe d * actua l facilit y cok e throughput , tons/y r

Prepare d by : Sit e Update d by : Di b Pau l Pag e 1 of1 Eri e byproduct-re v- Proces s Equipmen t 8/18/00-11:2 7 A MNe wBosto n Cok e Corp . Proces s Equipmen t Emission s fro m By-Produc t Plan t

Sourc e
Ligh t oi l storag e tan k Ta rdecante r Ta rinterceptin g sum p Ta rdewaterin g tan k Ta rstorag e tan k Ligh t oi l condense rven t !':'. Flushin g liquo rcirculatio n tan k Exces s ammoni a liquo rtan k Was h oi l decante r Was h oi l circulatio n tan k Tota l (lb/yr ) No . o f Units' "

1 1 1 1 2 2 ' 1 1 1 1 Ga s

Blanketin g (Yes/No )
Ye s Ye s Ye s Ye s Ye s Ye s Ye s Ye s Ye s Ye s Sourc e Heigh t (ft)' "

2 5 12. 5 8 2 7 3 5 6 1 8 1 5 9 1 7 Sourc e Di a o r

Length/Widt h (ft)* "
1 0 48x1 4 8 1 0 3 2 1 1 0 6 30x 8 1 0 Tan k

Orientatio n (Horlz/Vert )
Horizonta l Horizonta l Vertica l Horizonta l Vertica l Vertica l Horizonta l Horizonta l Horizonta l Horizonta l Calculate d

Benzen e Emission s (lb/yr)' 3 ' 35. 4 0. 7 0 1. 2 0. 8 1271. 2 0 0 5 3 5 3 1,41 5 Metho d o f

Calc." '

TANK S TANK S TANK S TANK S TANK S AP-4 2 TANK S TANK S AP-4 2 AP-4 2 Calculate d

Benzen e Emission s (lb/yr)' " AP 4 2 factor s 8 5 77 7 13 4 29 7 26 8 1,27 1 18 4 2 0 5 3 5 3 

## ^7007 AP-4 2 Emission ! Factor" 1 (lb/ton )
0.00024 0 0.00220 0 O.00O38 0 0.00084 0 0.00076 0 0.00360 0 0.00052 0 0.00005 6 0.00015 0 0.00015 0

NOTE : 1 ) Multipl e units ar e assume d t o be operatin g I n parallel . 2 ) Diamete rI fcylindrica l tank ; lengt h an d widt h I frectangula rtank . Se e attache d shee t fo rdimension s o

fmultipl e units . 3 ) Benzen e emissio n rate calculate d b y sH e usin g TANK S o rAP-4 2 (olde rtha n Feb'9 9 draft) . 4 ) Benzen e emissio n rate calculate d b y IC F usin g Draf

t AP-4 2 date d Feb'99 . Tabl e 12.2-19 , benzen e emissio n factors fo rfurnace plant . 5 ) Emission s fro m seale d unit s o rthos e wit h suctio n ar e zer o o rnegligible . Fo rta rInterceptin g sum p wit h ga s blanketing . 98 % contro l efficiency wa s use d pe rRo n Myers ' recommendation . Actua l facilit

y throughpu t fo roperatin g yea r199 8 353,09 1 tons/y r Sampl e calculation : Benzen e emissions , lb/y r= AP-4 2 factor , lb/to n o fcok e pushe d •actua l facilit y cok e throughput , tons/y r

Prepare d by : Sit e Update d by . Dl b Pau l 1 o f1 NewBoslon_bypr«_uct-rev. Proces s Equipmen t 8/18/00-11:3 1 A M

### Gul fState s Stee l Proces s Equipmen t Emission s fro m By-Produc t Plan t

Sourc e
O i Light oi l storag e tan k x i Reclaimed was h oi l storag e N / Ligh t oi l separato rtan k \ y Light oi l condensate tan k 0 / Flushin g liquo rcirculatio n tan k Ta rdewaterln g tan k V Ta rdecante rf... \ j Ta rstorag e \ * Excess ammoni a liquo rtan k

Tota l (lb/yr ) No . of Units' "
7 1 1 1 1 2 2 r ! 2 1 Ga s

Blanketin g (Yes/No ) Ye s Ye s Ye s Ye s Ye s Ye s Ye s Ye s Ye s Sourc e Heigh t (ft)' "

14. 0 14. 0 7. 0 11. 0 13. 5 13. 0 14. 0 32. 0 30. 0 Sourc e Di a o r

Length/Widt h («)" » 11. 0 11. 0 4. 0 8. 0 10. 5 10. 0 10.0x36. 0 40. 0 41. 0 Tan k

Orientatio n (Horlz/Vert ) Horizonta l Horizonta l Horizonta l Horizonta l Horizonta l Horizonta l Horizonta l Vertica l Vertica l Calculate d

Benzen e Emission s (lb/yr)" ' 132. 6 0. 2 23. 8 0. 0 0. 0 0. 6 0. 0 0. 8 0. 0 158. 0 Metho d o f

Calc.' "
TANKS 3 TANKS 3 TANKS 3 TANKS 3 TANKS 3 TANKS 3 TANKS 3 TANKS 3 TANKS 3 Calculate d

Benzen e Emission s (lb/yr)' 4 ' AP 4 2 factor s 12 4 7 8 31 1 1,86 5 26 9 43 5 1.14 0 39 4 2 9 ;4,64 5 AP-4 2 Emissio n

Factor' 4 ' (lb/ton ) 0.00024 0 0.00015 0 0.00060 0 0.00360 0 0.00052 0 0.00084 0 0.00220 0 0.00076 0 0.00005 6

NOTE : 1 ) Multipl e units are assume d t o be operatin g i n parallel . 2 ) Diamete ri fcylindrica l tank ; lengt h an d widt h ifrectangula rtank . Se e attache d shee t fo rdimension s o

fmultipl e units . 3 ) Benzen e emissio n rat e calculate d b y site usin g TANKS o rAP-4 2 (olde rtha n Feb'9 9 draft) . 4 ) Benzen e emissio n rat e calculate d by IC F usin g Draf t AP-4 2 date d Feb'99 . Tabl e 12.2-19 , benzen e emissio n factors fo rfurnac e plant . 5 ) Emission s fro m seale d unit s o rthos e wit h suctio n are zer o o rnegligible . Actua l facilit

y throughpu t fo roperatin g yea r199 8 518,104. 0 tons/y r Sampl e calculation : Benzen e emissions , lb/yr= AP-4 2 factor , lb/to n o fcok e pushed •actua l facilit y cok e throughput , tons/yr

Prepare d by : Sit e Update d by : Di b Pau l Pag e 1 of1 Gul fStates_byproduct-re v- Proces s Equipmen t 8/18/0011:2 8 A M

### P.3 2


## SUPPORTIN G DOCUMENTATIO N FO R

' ?T

o • '

• 

## BY-PRODUC TCHEMICA L PLANT • V . ; - 

## FUGITIV E EQUIPMEN TLEAK S

• \ • " • i

• •••»~;«t.
. • . ."•'-•• - ' • . . •
n O 

### •':' " o-A : 

### --r^H

-

•

• . . . .

• » •••"' •-• » •• - is.fV-iv

- _*•_• • • 

# m

; 

## O,O0-^i:v- ' I^^Mi^S*^' . '£&'


# r yymi

• : o,::^_ o

:

. 

## " ; 

## 'o^r :

. '



## • ypyyyr

•

.P.3 3

Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plant s TO C Emissio n Factor s (1 ) (2 ) Equipmen t Typ e

Valv e Pum p Othe r Connecto r Flang e Open-ende d Lin e Defaul t Zer o

Emissio n Rate , kg/hr/sourc e (3 )

7.80E-0 6 2.40E-0 5 4.00E-0 6 7.50E-0 6 3.10E-0 7 2.00E-0 6 Pegge d Emissio n Rates ,

kg/hr/sourc e (4 ) 10,00 0 ppm v 6.40E-0 2 7.40E-0 2 7.30E-0 2 2.80E-0 2 8.50E-0 2 3.00E-0 2 100,00 0 ppm v

1.40E-0 1 1.60E-0 1 1.10E-0 1 3.00E-0 2 8.40E-0 2 7.90E-0 2 Correlatio n Equation ,

kg/hr/sourc e (5 )

2.29E-0 6 *(SV) 0 " * 5.03E-0 5 *(SV) 0 - 61 0 1.36E-05"(SV) 0 - 68 8 1.53E-06*(SV)°- 73 S 4.61E-06*(SV) a70 3 2.20E-0 6 *(SV) U/ W
NOTE : (1 ) Emissio n factor s ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (2 ) Thes e emissio n factor s ar e fo rrefineries , marketin g terminals , an d oi l an d ga s production
. Base d o n a 198 0 study , EP Aconclude d tha t th e us e o frefinerydat a t o characteriz e cok e by-product fugitiv e emission s wa s reasonable
. (3 ) Thi s facto ri s use d whe n th e lea k detectio n monito rconsistentl yshow s 0 readings
. (4 ) Thes e factor s ar e use d whe n th e lea k detectio n monito rtrip s du e t o excessiv e hydrocarbo n concentratio n beyon d th e detectio n rang e ofth e monitor
. (5 ) SV = screenin g valu e i n ppm va s detecte d byth e lea k detectio n monito r

IC F Consultin g Di b Pau l fugibve_emission s 8/11/00-2:3 0 P MP.3 4



### A KSteel , Middletown/O H Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t

NOTE : Fugitiv e equipmen t leak

s wer e no t calculate d a

s th e plan t ha

s n o ligh t oi l recovery . Ther e ar e n o components i n ligh t oi l service
. Therefore , emission s ar

e negligibl e o rno

t quantifiable
.

DlbPau l fugitive_emission s IC F Consultin g 1 8/11/00-2:2 0 P MP.3 5

A KSteel, Ashland/KY Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t Tota l benzen e emission s

Benzen e emission s fro m non-leakin g component s = 1 4 lb/y r Benzen e emission s fro m leakin g component s = 1,99 4 lb/y r Tota l benzen e emission s = *§2~d07Mb/y r

Di b Pau l fugitive_emission s IC F Consultin g 1 8/18£0 ~ 12:0 3 P M

### A KSteel , Ashland/K

Y Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plant Emission s fro m non-leakin g component s P.3 6



### Stream(1 )

Ligh t oi l (liqui d o rvapor)

Ric h was h oi l

Lea n was h oi l Benzen e Mas s Fractio n (2 )

75 %

3 %

0.14 % 

### Type of

Equipmen t

Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d No . o fZeroReadin g Component

s (3) 4

4 6 9 3 3 0 2 1 0 11 6 2 1 3 1 0 13 1 1 9 Defaul t Zer

o Emissio n Rat e i 

### kg/hr/sourc

e (4) 2.40E-05 3.10E-07 7.80E-06 2.00E-06 2.40E-05 3.10E-07 7.80E-06 2.00E-0 6 2.40E-05 3.10E-07 7.80E-06 2.00E-06 Benzen e Emissions , lb/y r(5 )
1.3

9 0.2 1 10.5 1 0.87 0.0 3 0.0 0 0.52 0.02 0.0 0 0.0 0 0.0 3 0.0 0 Tota l Emissions , lb/y r 1 4

NOTE : (1 ) Fo rprocess stream s i n benzen e servic e (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3 ) Component count , an d no . of zer o leakin g components fro m site
. I t wa s assumed that a componen t wit h les s tha n 50 0 ppmvscreenin g valu e was not leaking
. (4 ) Defaul t zer

o emissio n factors fo rTO C ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5 ) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o f components * 876 0 hrs/y r* w

t fractio n benzen e

Di b Pau l IC F Consultin g fugitive_emission s 8/11/0 0 -2:2 2 P MP.3 7



### Eri e Coke Corporatio n Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t Stream(1 )

C O Ga s Benzen e Mas s Fractio n (2 )

1 % 

### Type of

Equipmen t

Valve s Othe r No . o

fZero- Defaul t Zero Benzen e Readin g Emissio n Emissions , Component s Rate , lb/y r(5 ) (3) kg/hr/source

(4) 42 7.80E-0 6 0.06 2 4.00E-0 6 0.00

Tota l Emissions , lb/y r0.06

NOTE : (1 ) Fo rproces

s stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3) Component count , an d no . o fzero leakin g components fro m site
. I t was assume d that a componen t wit h less tha n 500 ppmvscreenin g valu e was no t leaking
. (4 ) Defaul t zer

o emissio n factors fo rTOC ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. Tabl e C-3
. (5) Benzen e emission s = Defau H zero factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o fcomponents • 8760 hrs/y r* w

t fractio n benzen e

Di b Pau l fugitive_en.ission s IC F Consultin g 1 8/11/00-2:1 8 P MP.3 8



### Ne wBoston/O H Fugitiv e Equipmen t Leak

Emission s fro m By-Produc t Plan t Stream(1 )

Ligh t oi l (liqui d o rvapor

) Benzen e Mas s Fractio n (2 )


### 67 %

C O Ga s 10 % 

### Type o f No . o

fZero - Defaul t Zero Benzen e Equipmen t Readin g Emissio n Emissions ,

Component

s Rate , lb/y r(5 ) Pum p Flang e Valve s Ope n En d Othe r (3) kg/hr/source (4) 9 2.40E-0 5 84 8 3.10E-0 7 12 2 7.80E-0 6 7 2 2.00E-0 6 8 4.00E-0 6 

### 2.79 3.40 12.3 1 1.8 6 0.06

Tota l Emissions , lb/y r 2 0

NOTE : (1 ) Fo rprocess stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3 ) Component count , an d no . o f zero leakin g components fro m site
. I t wa s assume d tha

t a componen t wit h les s tha n 500 ppmvscreenin g valu e wa s no t leaking
. (4 ) Defaul t zer

o emissio n factor

s fo rTOC ar

e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5 ) Benzen e emission s = Defaul t zero factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o f component

s * 8760 hrs/y r* w

t fractio n benzen e

Di b Pau l IC F Consultin g fugitive_emission s 8/11/O 0 -2:1 7 P M

### Tonawanda/N Y Fugitiv e Equipment Lea k

Emission s fro m By-Produc t Plan t P.3 9



### Stream(1 )
Ligh t oi l (liqui d o rvapor)

CO Ga s Benzen e Mas s Fractio n (2 )

65 %

1 % 

### Type o

f Equipment
Pum p Flang e Valve s Ope n En d Othe r Valve s No . o

fZeroReadin g Component

s (3) 1

2 7 1 3 3 5 Defaul t Zero Emissio n Rate , kg/hr/source (4 ) 2.40E-0 5 3.10E-0 7 7.80E-0 6 2.00E-0 6 4.00E-0 6 7.80E-0 6 Benzen e

Emissions , lb/y r(5 ) 0.3 0 0.0 1 0.6 9 0.03 0.00 0.0 5

Tota l Emissions , lb/y r

NOTE : (1 ) Fo rprocess stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2) Composition s fro m site
. (3) Component count , an d no . o f zer o leakin g component

s fro m site
. I t wa

s assume d that a componen t wit h less tha n 500 ppmvscreenin g valu e was no t leaking
. (4) Defaul t zer

o emissio n factors fo rTOC ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o

f component

s * 876 0 hrs/y r* w

t fractio n benzen e

Oi b Pau l IC F Consultin g fugitive_emission s 8/11/00-15 9 P MP.4 0

CONSULTIN G 

## Augus t 31 , 200 0 Mr
. Te dPalma USEP A Emissio nStandard s Divisio

n Ris k & Exposur

e Assessmen

t Grou p MD-1 3 RTP.N C Re : Revise dFugitiv e EmissionCalculation s Dea r Mr
. Palma : IC FConsulting (ICF

) appreciate s th e opportunit

y to suppor

t EPA' s residua

l risk assessmen t project fo r th e cok e ove nsourc e category . Enclose

dar e the revised calculation s o f

emissio nrate s fromfugitive equipmen t leaks
. A s suggestedduring ou

r Augus t 2 8 meeting , I hav

e complete demissio ncalculation s fo

r the followin

g scenarios :

• COET Ffactors • AP-42 factor s • EP Aaverag e emissio

nfactor s • EP ALeak/No-lea

k factor s • EP Adefault/pegging/correlationfactors • Al l components leakin

g a t 25 0 ppm v (half o f 50 0 ppm v lea k level)
. I a me-mailin

g yo u dis k files fo r the above calculations
. I

f yo u have an y questions , please d o no t hesitat e t o cal l m e a t (919 ) 233-0382
. Sincerely ,
DibPaul , PE
. Projec t Manage r En d d p

930 0 Le e Highwa yFairfax , V

A22031-120 7 US

A
. 703-934-300 0 —703-934-374 0 faxwww.icfconsulting.co mFugitiv e Equipmen t Lea k Emission s fro m By-Produc t Chemica l Plant s Summar y o fBenzen e Emissions , lb/y r Facility , Locatio n

A KSteel , Middletow n A KSteel , Ashlan d Eri e Cok e Gul fState s Stee l Ne wBosto n Cok e Tonawand a Cok e Base d o n COET F Factor s (1 )

14 7

7 2 5 5 3 9 5 1 0 Base d o n AP-4 2 Factor s (2 )

7 8

31.94 9 10 6 129,53 1 153.04 2 2,79 2 Base d o n Averag e Emissio n Factor s (3 ) \ ^..5 3 25,11 4 3^27 9 N 7§;95 9 ^ 37,34 0 >2;6& 8 Base d o n Leak-n o

Lea k Factor s (4 )

N , 1.41 4 ^,•0^5^23 9

1,41 3 5,55 1 7,56 7 1,73 2 Base d o n Defaul t

Zero / Pegged / Correlatio n Emissio n Rat e (5 )

0.0 5 ^At,^£®Q 7

0.0 6 4 8 2 0 1 Base d o n 25 0 I ppm vLea k

(6 ) I

1 48 4 1 1,84 7 2,95 1 3 9 NOTE : (1 ) Emissio n factor s generate d b ycok e associatio n base d o n Januar y200 0 fiel d study
. (2 ) Draf t AP-42 , Tabl e 12.2-1
. (3 ) Emissio n factor s ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. Thes e emissio n factor s ar e fo rrefineries
. Base d o n a 198 0 study , EP Aconclude d tha t th e us e o frefiner ydat a t o characteriz e coke , by-produc t fugitiv e emission s wa s reasonable
. Averag e emissio n factor s fo rrefinerie s fro m Tabl e 2- 2 o fabov e document
. (4 ) Refiner yscreenin g rang e emissio n factor s fro m Tabl e 2- 6 o fdocumen t cite d unde rnot e (3)
. Wit h th e exceptio n o fAshland , ful l monitorin g dat a wa s no t availabl e fo rth e othe rsites
. I t wa s assume d tha t emission s fro m leak s a t Ashlan d wer e representativ e o feac h facility
. Therefore , emission s fro m leakin g component s a t Ashlan d wer e adde d t o non-leakin g emission s fro m eac h site
. (5 ) Defaul t zero , pegged , an d correlatio n equation s fro m Tabl e C- 3 o fdocumen t cite d unde rnot e (3)
. (6 ) I t wa s assume d tha t a 25 0 ppm vlea k (50 0 ppm vleak/2 ) represent s leak s a t eac h site
.

IC F Consultin g Di b Pau l fugi!ive_emlssions_summar y 8/31 100-

1:4 0 P MFugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plant s Compariso n o fTO C Emissio n Factor s Equipmen t Typ e

Valv e Pum p Othe r Connecto r Flang e Open-ende d Lin e COET F Factors , kg/hr/sourc e 

### d )

8.26E-0 6 1.82E-0 4 1.46E-0 4 3.48E-0 6 3.48E-0 6 4.38E-0 6 AP-4 2

Factors , kg/hr

/ sourc e (2 )

1.08E-0 2 1.13E-0 1 1.49E-0 2 1.08E-0 2 1.08E-0 2 | 2.27E-0 3 Averag e

Emissio n Factors , kg/hr/sourc e (3 )

1.09E-0 2 1.14E-0 1 1.50E-0 2 2.50E-0 4 2.50E-0 4 2.30E-0 3 Leak-n o Lea k Factors , kg/hr/sourc e (4 )

> 10,00 0 ppm v 8.52E-0 2 4.37E-0 1 3.75E-0 2 3.75E-0 2 3.75E-0 2 1.20E-0 2 <10,00 0

ppm v 1.70E-0 3 1.20E-0 2 6.00E-0 5 6.00E-0 5 6.00E-0 5 1.50E-0 3 Defaul t Zer o

Emissio n Rate , kg/hr/sourc e (5 )

7.80E-0 6 2.40E-0 5 4.00E-0 6 7.50E-0 6 3.10E-0 7 2.00E-0 6 Pegge d Emissio n

Rates , kg/hr/sourc e (6 )

10,00 0 ppm v 6.40E-0 2 7.40E-0 2 7.30E-0 2 2.80E-0 2 8.50E-0 2 3.00E-0 2 100,00 0

ppm v 1.40E-0 1 1.60E-0 1 1.10E-0 1 3.00E-0 2 8.40E-0 2 7.90E-0 2 Correlatio n Equation ,

kg/hr/sourc e (7 )

2.29E-0 6 *(SV)°" , B 5.03E-0 5 *(SV) oa, ° 1.36E-0 5 *(SV) 058 9 1.53E-0 6 *(SV) 073 5 4.6 1 E-0 6 *(SV) 070 3 2.20E-0 6 •(SV)""' " NOTE : (1 ) Emissio n factor s submitte d b ycok e associatio n base d o h a fiel d study
. (2 ) Draf t AP-42 , Tabl e 12.2-1 , VO C emissions
. Lb/da yfactor s wer e converte d t o Kg/hr
. (3 ) Emissio n factor s ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. Thes e emissio n factor s ar e fo rrefineries
. Base d o n a 198 0 study , EP Aconclude d tha t th e us e o frefiner ydat a t o characteriz e coke , by-produc t fugitiv e emission s wa s reasonable
. Averag e emissio n factor s fo rrefinerie s fro m Tabl e 2- 2 o fabov e document
. Fo rallowabl e emissions , al l component s wer e assume d t o b e i n ligh t liqui d service
. Fo r"Other" , samplin g connectio n facto rwa s assumed
. (4 ) Refiner yscreenin g range s emissio n factor s fro m Tabl e 2- 6 o fdocumen t cite d unde rnot e (3)
. (5 ) Thi s facto ri s use d whe n th e lea k detectio n monito rconsistentl yshow s 0 readings
. Se e Tabl e C- 3 o fdocumen t cite d unde rnot e (3)
. (6 ) Thes e factor s ar e use d whe n th e lea k detectio n monito rtrip s du e t o excessiv e hydrocarbo n concentratio n beyon d th e detectio n rang e o fth e monitor
. Se e Tabl e C- 3 o fdocumen t cite d unde rnot e (3)
. (7 ) S V = screenin g valu e i n ppm va s detecte d b yth e lea k detectio n monitor
. Se e Tabl e C- 3 o fdocumen t cite d unde rnot e (3)
.

IC F Consultin g Di b Pau l fugilive_emisslon s 8/3 1 A30~12:2 5 P MP.4 3



# '7p^0M&ppp7- pyi^^^^yw^^' 

# •"••• • . :•••• • - ymmmmmmm^m ^ EMISSION

S BASE D O N AVERAG

E EMISSIO

N FACTORS ;

FUGITIV E EQUIPMENT LEAK

S r^3my^M^y7,-7m : 

## ^22PP2y7^i'7y 

## BY-PRODUC T CHEMICAL PLANTP.4 4

Summar yo fBenzen e Emission s Fugitiv e Equipmen t Lea k At By-Produc t Chemica l Plan t (Base d o n Averag e Emissio n Factors ) Compan y
A KStee l A KStee l Eri e Coke Gul fState s Stee l Ne wBosto n Cok e Locatio n
Middletown , O H Ashland , K

Y Erie , P A Gadsden , A L Ne wBoston , O H Tonawand a Cok e Tonawanda , N Y Benzen e Emissions , lb/y r 

### 5

3 25,11 4 

### 279 73,95 9 37,84 0 2,69 8 Benzen e Emissions , lb/h r
6.09E-0 3

2.87E+0 0 3.19E-0 2 8.44E+0 0 4.32E+0 0 3.08E-0 1 NOTE : Emissio n factor s ar e base d o n Tabl e 2- 2 o f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1.995
. lb/h r= lb/yr/876 0

IC F Consultin g Di b Pau l fugitive_average-facto r 8/31A0O-10:5 7 A M

### A KSteel , Middletown/O H

Fugitiv e Equipmen t Lea k

Emission s fro m By-Produc t Plan t Averag e Emissio n Factor s P.4 5



### Typ e o fEquipmen t Benzen e Mas s Fractio n No . o f Components Average Benzen e

Emissio n Emissions , Factor , lb/y r(2 ) kg/hr/sourc

e (1 )

Pum p Flang e Valve s Connecto r Othe r 0.14 % 2 8 5 7 4 3 6 1 1.14E-0 1

2.50E-04 1.09E-0 2 2.50E-04 1.50E-0 2 6.1644

0.5745 21.808 1 0.0203 24.738 9 53.306 2 NOTE : (1 ) Emissio n factors ar

e based o n Tabl e 2- 2 o f"Protoco l fo rEquipmen t Leak Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b * no . of component

s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_average-facto r 8/31/00-10:3 2 A M

_P.4 6



### A KSteel , Ashland/K Y Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t Averag e Emissio n Factor s

NOTE : (1 ) Emissio n factor s are base d o n Tabl e 2- 2 o f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e wt fractio n Strea m Ligh t oi l (liqui d o rvapor

)

Rich was h oi l

Lean was h oi l

Tota l Emissions , lb/y r Benzen e Mas s Fractio n

75 %

3 %

0.14 % Typ e o f

Equipmen t Pum p Flang e Valv e Ope n En d Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d No
. o f

Component s 5 4 6 93 30 3 1 0 11 6 2 1 3 1 0 13 1 1 9 Emissio n

Factor m , kg/hr/sourc e 1.14E-0 1 2.50E-04 1.09E-0 2 2.30E-03 1.14E-0 1 2.50E-04 1.09E-0 2 2.30E-03 1.14E-0 1 2.50E-04 1.09E-0 2 2.30E-03 Benzen e

Emissions , lb/y r m 8,256 16 7 " ^ 14,683 999 19 8 1 73 3 2 8 9 0 39 1 25,11 4

V

Di b Pau l IC F Consultin g fugitive_average-facto r 8/31/00-10:3 9 A MP.4 7

Eri e Coke Corporatio n Emission s fro m By-Produc t Plan t Averag e Emissio n Factor s Strea m Typ e o fNo . ofEmissio n Facto rBenzen e Benzen e Mass Fractio n E( * u i P men tComponent s (1) , kg/hr/sourc e Emissions , lb/yr(2 )

<1 % C o Ga s [Exhauste r2 1.60E-0 1 6 2 cio
. Ga s <1 % Valve s 4 2 2.68E-0 2 21 7

Tota l Emissions , lb/y r27 9
NOTE : (1 ) Emissio n factor s ar e base d o n Tabl e 2- 2 o f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. Factor s fo rga s wer e used
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l fugitive_averaB©-f8eto r IC F Consultin g 1 8O1/00-10:4 3 A MP.4 8

Gul fState s Stee l Emission s fro m By-Produc t Plan t Averag e Emissio n Factor s Strea m Benzen e Mas s Fractio n Typ e o f Equipmen t No . o f Component s Emissio n Facto rBenzen e

(1) , kg/hr/sourc e Emissions ,

lb/y r(2 ) 60 % Liqui d

CO . Gas 62 % 67 % 69 % 31 % 100 % 100 % 100 % Flang e

Connecto r Valv e Flang e Connecto r Flang e (Le a Valv e king) Ope n Ende d Lin e 191 181 8 3 14 6 11 2 9 11 5 1 8 2.50E-0 4

2.50E-0 4 1.09E-0 2 2.50E-0 4 2.50E-0 4 2.50E-0 4 2.68E-0 2 2.30E-0 3 55

3 54 2 11,70 6 627 16 8 4 3 59,52 0 80 0 Tota l Emissions , lb/y

r 73,95 9 NOTE : (1 ) Emissio n factor

s ar e based o n Tabl e 2- 2 o

f"Protoco l fo rEquipmen t Lea k Emission Estimates" , EPA-453/R-95-017 , Novembe r1995 . (2 ) Benzen e emissions = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component

s * 876 0 hrs/y

r* benzen e w

t fractio n

Di b Pau l IC F Consultin g fugitive_ave.age-fac.O f 8/31/00-10:4 9 AMP.4 9

Ne wBosto n Cok e Corp . Emission s fro m By-Produc t Plan t Averag e Emissio n Factor s Strea m Benzen e Mas s Fractio n Typ e o fNo . o fEmissio n Facto rBenzen e Equipmen t Component s (1) , kg/hr/sourc e Emissions , lb/yr(2)

Liqui d 67 % Valv e Ope n En d Flanges/connecto i Pump s CO
. Gas 10 % Pres
. Relie f8 1.60E-0 1 2,47 2

Tota l Emissions , lb/y r37,84 0

NOTE : (1 ) Emissio n factor s ar e base d o n Tabl e 2- 2 o f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e w t fractio n 122 72 848 9 1.09E-0 2

2.30E-0 3 2.50E-0 4 1.14E-0 1 17,20 6

2,14 3 2,74 3 13,27 6

Di b Pau l tugitive_average-lacto r IC F Consultin g 1 6/31/0 0 •10:5 3 A MTonawand a Coke Corporatio n

Emission s fro m By-Produc t Plan t Averag e Emissio n Factor s P.5 0

Strea m Benzen e Mas s Fractio n Typ e ofNo . of Equipmen t Component s Emissio n Facto rBenzen e (1) , kg/hr/sourc e Emissions ,

lb/v r(2 )

Liqui d 65 % Pum p Flang e Valv e Ope n En d 

# > 7

3
_ 1 2 7 1 1.14E-0 1

2.50E-0 4 1.09E-0 2 2.30E-0 3 1,43 1

6 95 8 2 9 CO
. Ga s <1 % Exhauste r Pres
. Relie f Valve s 2 1 3 5 1.60E-0 1

1.60E-0 1 2.68E-0 2 6 2

3 1 18 1 Tota l Emissions , lb/y r 2,69 8

NOTE : (1 ) Emissio n factor s are base d o n Tabl e 2- 2 of"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_average-facto r 8/31/00-10:5 6 A M• 

### P.5 1

..-,. . • 

## EMISSION S BASE D O NAP-4 2 FACTOR S , ? iS%'•" 7t 'r.'-, L

I 

## FUGITIV

E EQUIPMENT LEAK

S BY-PRODUC T CHEMICAL PLANT L2my;

. i. , •P.5 2



### Summar yo fBenzen e Emission s Fugitiv e Equipmen t Lea k A t By-Produc

t Chemica l Plant (Base d o n AP-42 Factors

) Compan y A KStee l A KStee l Eri e Cok e Gul fState s Stee l Ne wBosto n Cok

e Tonawand a Cok

e Locatio n

Middletown , OH Ashland , K

Y Erie , P A Gadsden , A L Ne wBoston , O H Tonawanda , N

Y Benzen e Emissions , lb/y r
7

8 31,949 10 6 129,53 1 153,04 2 2,792 Benzen e Emissions , lb/h r 8.90E-03

3.65E+00 1.21E-0 2 1.48E+0 1 1.75E+0 1 3.19E-0 1 NOTE : Emissio n factor

s ar e based o n Draf

t AP-4 2 Tabl e 12.2-21
. lb/h r= lb/yr/876 0

IC F Consultin g Di b Pau l fugitive_AP-42_emission s

_ 8/31flO-9:17A MP.5 3



### A KSteel , Middletown/O H Fugitiv e Equipmen t Lea k Emission s fro m By-Product Plant Stream(1 ) Benzen e Mas s Typ e o f Fractio n (2 ) Equipmen t No
. o f Component s (3 ) AP-4

2 Factor , VOC lb/da

y (4) Benzen e Emissions , Ib/vr(5 )

Lea n was h oi l 0.14 % Pum p Flang e Valve s Connecto r Othe r 2 8 5 7 4 3 6 1 6.00E+00

5.70E-0 1 5.70E-0 1 5.70E-0 1 7.90E-0 1 6.13E+0 0

2.48E+0 1 2.16E+0 1 8.74E-0 1 2.46E+0 1 Tota l Emissions , lb/y r 7 8 NOTE : 1 ) Al l components were assumed t o b e i n lea n was h oi l service
. 2 ) Benzen e strea m compositio n i s i n mas s basis
. 3) Componen t coun t fro m site
. 4) Draf t AP-42 , Tabl e 12.2-21 , lb/da yVOC emissio n factor

s fo rles s tha n quarterl yinspections
. Fo rflanges, th e facto rfo rvalves was used
. 5 ) Benzen e emissions , lb/y r= AP-4 2 factor , lb/da

yVOC * benzen e mas

s fractio n * no . o fcomponents * 36

5 days/y r

Oi b Pau l IC F Consultin g fugitive_AP-42_emission s ~8/31AD0-9:59A MA KSteel , Ashland/KY

Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t (Usin g AP-4 2 factor s wit h n o monitorin g data ) P.5 4

Stream(1 )

Light oi l (liqui d orvapor)

Ric h was h oi l

Lea n was h oi l Benzen e Mas s Typ e o f Fraction(2 ) Equipmen t

75 % Pum p Flang e Valve s Ope n En d 3 % Pum p Flang e Valve s Ope n En d
0.14 % Pum p Flang e Valve s Ope n En d 

### No . o

f Component s 

### (3) 5

4 6 9 3 3 0 3 1 0 11 6 2 1 3 1 0 13 1 1 9 AP-4 2 Factor , Benzen e VO C lb/da y (4 ) Emissions ,

lb/y r(5 ) 

### 6 0.5 7 0.5 7 0.1 2 6 0.5 7 0.5 7 0.1 2
6 0.5 7 0.5 7 0.1 2 8,21 3

7,17 8 14,51 1 98 6 197 6 2 72 4 2 8
9 3 3 8 1 Tota l Emissions , lb/y r 

### 31,94 9
NOTE : 1 ) Fo rproces

s stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) 2 ) Benzen e strea m compositio n i s i n mass basis . 3 ) Componen t coun

t fro m site . 4 ) Draf t AP-42 , Tabl e 12.2-21 , lb/da y VO C emissio n factor s fo rless tha n quarterl y inspections . Fo rflanges , th e facto rfo rvalve s was used . 5 ) Benzen e emissions , lb/y r= AP-4 2 factor , lb/da y VO C * benzen e mass fractio n * no . o fcomponent

s * 36 5 days/y r

Oi b Pau l IC F Consultin g fugttive_AP-42_emission s 8/31/00~10:17A MP.5 5



## Eri e Cok e Corporatio n Emission s fro m By-Produc t Plant (Usin g AP-42 factor s wit h n o monitorin g data )
Stream 11 '

CO
. Gas CO
. Gas
Tota l Emissions , lb/y r Benzen e Mass Fraction' 2 '

<1 %
<1 % Typ e o f

Equipmen t
Exhauste r
Valves No
. o f

Components' 3 '

2
4 2 AP-4

2 Facto r m , VOC , lb/day

2. 6
0.5 7 Benzen e

Emissions , Ib/v r«
1 9
8 7
106 NOTE : 1 ) Fo rprocess stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) 2 ) Benzen e strea m compositio n i s i n mass basis
. 3 ) Componen t coun t fro m site
. 4 ) Draf t AP-42 , Tabl e 12.2-21 , lb/da yVO C emissio n factor

s fo rless tha n quarterl yinspections
. Fo rflanges , th e facto rfo rvalve s wa s used
. 5 ) Benzen e emission s = AP-42 factor , lb/da yVOC * benzen e mass fractio n * no . o fcomponent

s * 36 5 days/y r

Di b Pau l IC F Consultin g fugitiv e AP-42_emission s ~8/3CK» - 4:2 8 P MP.5 6

Gul fState s Stee l Emission s fro m By-produc t Plan t (Usin g AP-4 2 Factor s wit h no-monitorin g data )
Stream 11 '
Liqui d

CO
. Ga s

Tota l Emissions , lb/y r Benzen e Mas s Fraction 11 '
60 %
62 % Type o fEquipmen t

Flang e Connecto r 67 % | Valve
89 % 31 % 100 % 100 % 100 % Flang e

Connecto r Flang e (Leaking ) Valve Ope n Ende d Lin e (leaking ) No
. o f

Components' 1 '
19 1
18 1 83
14 6 11 2 9 11 5 1 8 AP-4

2 Factor w , VOC , lb/da

y

0.5 7
0.7 9 0.57
0.57 0.79 0.57 0.1 2 Benzen e

Emissions , lb/y r (5 ) 23,84 3 32,35 9 11,57 0 27,034 10,01 2

- 23,92 6 78 8 129,53 1 NOTE : 1 ) Fo rproces

s stream s i h benzen e servic e (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) 2 ) Benzen e strea m compositio n i s i n mas s basis
. 3) Component coun t fro m site
. 4 ) Draf t AP-42 , Tabl e 12.2-21 , lb/da yVO C emissio n factors fo rles s tha n quarterl yinspections
. Fo rflanges , th e facto rfo rvalve s wa s used
. 5 ) Benzen e emission s = AP-42 factor , lb/da yVO C * benzen e mass fractio n * no . ofcomponent s * 36 5 days/y r

Dib Pau l IC F Consultin

g fugitive_AP-42_emission s ~8/30/00-4:36 P

MP.5 7



### Ne wBosto n Cok

e Corp . Emission s fro m By-Produc t Plan t (Usin g AP-42 factors wit h n o monitorin g data ) Stream(1 ) Benzen e Mas s Type o

fNo . o

fAP-4

2 Facto rBenzen e Fraction(2 ) Equipmen t Component s (3 ) (4) , VOC , Emissions , Ib/da vIb/v r(5 )
Liqui d 67 % Valve s Ope n En d Flanges/connect

t Pump s 10% Pres
. Relie f 122 7 2 848 9 8 0.57

0.1 2 0.57 6 8. 6 17,00 6

2,11 3 118,20 6 13,20 6 2,51 1 CO
. Ga s Tota l Emissions , lb/y r153,04 2
NOTE : 1 ) Fo rprocess stream s i n benzen e servic e (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) 2 ) Benzen e strea m compositio n i s i n mass basis
. 3) Componen t coun t fro m site
. 4 ) Draf t AP-42 , Tabl e 12.2-21 , lb/da yVOC emissio n factor

s fo rless tha n quarterl yinspections
. Fo rflanges , th e facto rfo rvalve s was used
. 5) Benzen e emission s = AP-42 factor , lb/da yVO C • benzen e mass fractio n * no . ofcomponents * 365 days/y r

D i b Pau l fugitive_AP-42_emission s ICFConsultin g 1 8/3OC 0 - 4:2 6 P MTonawand a Coke Corporatio n

Emission s fro m By-Produc t Plan t (Usin g AP-4 2 factor s wit h n o monitorin g data ) Stream(1 ) Benzen e Typ e of Mas s Equipmen t Fraction(2 ) No . o f Component s 

### (3) AP-4 2 Facto r

(4) . VOC , lb/day Benzen e

Emissions , lb/y r(5 )

Liqui d

CO . Gas 

### <1 % 65 % Pum p Flang e Valv e Ope n En d Exhauste r Pres . Relief Valves 

### 1 2 7 1 2 1 3 5 6

0.5 7 0.5 7 0.1 2 

### 2. 6 8. 6 0.5 7 1,42 4



### 270 94 7 

### 28 1 9 3 1 7 3 Tota l Emissions , lb/y r 

### 2,79 2

NOTE : 1 ) Fo rproces

s stream s i n benzen e service (e.g. , light oi l liquid , light oi l vapor , etc. ) 2 ) Benzen e strea m compositio n i s i n mas s basis . 3 ) Component count fro m site . 4 ) Draf t AP-42 , Tabl e 12.2-21 , lb/da y VO C emissio n factors fo rless tha n quarterl y inspections . Fo rflanges , th e facto rfo rvalve s was used . 5 ) Benzen e emission s = AP-4 2 factor , lb/da y VO C * benzen e mass fractio n * no . o fcomponent

s * 36 5 days/y r

Di b Pau l IC F Consultin g fugrtive_AP-42_emission s ~8/3CM30-4:3 8 P MP.5 9

0.. 7. '-,\j



### •••^^M^^^M^^^^^'^ 1 ~i-.?--.liH?ii$.*A"~: 

# yp^yyyy^Ky

• •f;*«**.»: , ,»i , *«-.*Uw i



## FUGITIVE EQUIPMENT LEAK S 

# ^^fpii^^^^^^'^HV ::;! 

# ^- ;

.!'-.

_£$;.'. : -;3='^--

_•<»:-;^feV^^"7^--^.^S-. :
. ^TiS:V\:-^ ? VU3'V

- _i*-.':-?^"-vi^::- ! : ; :-t 5 "i-'..-- : 

### 7L;LA:$A^£7A&7iy7y-yr:?A7---'P.6 0

Summar y o fBenzen e Emission s Fugitiv e Equipmen t Lea k At By-Produc t Chemica l Plan t (Base d o n COET F Factors ) Compan y
A KStee l A KStee l Eri e Cok e Gul fState s Stee l NewBosto n Cok e Tonawand a Cok e Locatio n
Middletown , O H Ashland , K

Y Erie , PA Gadsden , A L NewBoston , O H Tonawanda , N Y Benzen e Emissions , lb/y r 

### 14

7 

### 7 2 5 5 3 9 5 1 0 Benzen e Emissions , lb/h r
1.68E-0 2

8.18E-0 3 5.86E-0 4 6.05E-0 3 1.08E-0 2 1.14E-0 3 NOTE : Emissio n factor s ar e base d o n COET F fiel d stud yperforme d i n January2000
. lb/h r= lb/yr /

876 0

IC F Consultin g Di b Pau l fugitive_COETF_emission s

~ 8/31*30-8:5 3 A MP.6 1



### A KSteel , Middletown/O H Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plant COET F Factor

s Typ e ofEquipmen t No . o f Components COETF Facto rBenzene

fo rBenzene , Emissions , kg/hr/sourc

e (1 ) lb/y r(2)

Pum p Flang e Valve s Connecto r Othe r 

### 2 8 5 7 4 3 6 1 1.27E-0 4

2.40E-0 6 5.84E-0 6 2.40E-0 6 1.10E-0 4 4.905 3

3.939 7 8.345 9 0.139 0 129.584 7 

### 146.914 6 NOTE : (1 ) COET F factor

s ar e fro m fiel d studyconducte d i n Januar y2000
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o

f components * 8760 hrs/y r

Di b Pau l IC F Consultin g fugitive_ C O ETF_emission s " 8/30/0 0 - 2:3 0 P MP.6 2



### A KSteel, Ashland/K Y Fugitiv e Equipmen t Lea k Emission s fro m Eiy-Product Plan t (Usin g COET F Factors )

Strea m Light oi l (liqui d o rvapor )

Ric h was h oi l

Lea n was h oi l

Tota l Emissions , lb/y r Benzen e Mas s Fractio n 75 %

3 %

0.14 % Typ e o f

Equipmen t Pum p Flang e Valv e Ope n En d Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d No . o f

Component s 5 4 6 9 3 3 0 3 1 0 11 6 2 1 3 1 0 13 1 1 9 Emissio n

Facto r n , benzene , kg/h r
1.27E-0 4 2.40E-0 6 5.84E-0 6 2.39E-0 6 1.27E-0 4 2.40E-0 6 5.84E-0 6 2.39E-0 6 1.27E-0 4 2.40E-0 6 5.84E-0 6 2.39E-0 6 Benzen e

Emissions , lb/y r w
1 2 2 1 0 1 7 0 1 3 1 7 0 1 5 1 7 2

NOTE : (1 ) COET F factor s ar e fro m fiel d stud yconducte d i n Januar y2000
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r

Di b Pau l ICF Consultin

g tugitive_COETF_emission s

~ 8/31/00-8:5 0 AMEri e Cok e Corporatio n

Emission s fro m By-Produc t Plan t (Usin g COET F Factors ) Strea m Typ e o f Equipmen t No . o f

Component s Emissio n Facto rBenzen e

(1) , benzene , kg/h r Emissions ,

lb/y r(2 ) P.6 3

C O . Ga s Exhauste r2 1.02E-0 5 0.39 4 CO . Ga s Valve s 4 2 5.84E-0 6 4.73 7

Tota l Emissions , lb/y r5.13 1
NOTE : (1 ) COET F factor

s ar e fro m fiel d study conducted i n Januar y 2000 . (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f components * 876 0 hrs/yr

Di b Pau l fugitive_COETF_emission s IC F Consultin g 1 8/31/00-85 2 AMP.6 4

Gul fState s Stee l Emission s fro m By-Produc t Plan t (Usin g COET F Factors ) Strea m Typ e o f Equipmen t No . o fEmissio n Facto rBenzen e

Component s (1) , benzene , Emissions ,

kq/h rlb/y r(2 )

Liqui d

CO . Ga s Flang e Connecto r Valv e Flang e Connecto r Flang e (Leaking ) Valv e Ope n Ende d Lin e 19 1 18 1 8 3 146 11 2 9 11 5 1 8 2.40E-0 6

2.40E-0 6 5.84E-0 6 2.40E-0 6 2.40E-0 6 2.40E-0 6 5.84E-0 6 2.39E-0 6 9 8 9 7 5 0 1 3 1 Tota l Emissions , lb/y r 

### 5 3
NOTE : (1 ) COET F factor

s are fro m fiel d study conducte d i n Januar

y 2000 . (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component

s * 876 0 hrs/y r

Di b Pau l IC F Consultin g fugitive_COETF_emission s

~ 8/31/00-8:5 4 A MNe wBosto n Coke Corp .

Emission s fro m By-Produc t Plan t (Usin g COET F Factors ) P.6 5

Strea m Typ e o fNo . o fEmissio n Facto rBenzen e Equipmen t Component s (1) , benzene , Emissions , kg/h rlb/y r(2 )

Liqui d

CO . Ga s Valv e Ope n En d Flanges/connect o Pumps Pres . Relie f 

### 12 2 

### 72 848 

### 9 8 . 5.84E-0 6

2.39E-0 6 2.40E-0 6 1.27E-0 4 1.10E-0 4 

### 1 4

3 3 9 2 2 1 7

Tota l Emissions , lb/y r 

### 9 5

NOT E (1 ) COET F factor s ar e fro m fiel d stud yconducte d i n January2000
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r

Di b Pau l IC F Consultin g fugithfc^COETF^emission s

~ 8/31^0-85 5 A MP.6 6

Tonawand a Cok

e Corporatio n Emission s fro m By-Product Plan t (Usin g COET F Factors ) Strea m Typ e o f Equipmen t No . o f

Component s Emissio n Facto rBenzen e

(1) , benzene , Emissions , kg/h rlb/y r(2 )

Liqui d

CO . Ga s

Tota l Emissions , lb/y r Pum p Flang e Valve Ope n En d Exhauste r Pres . Relie

f Valve s 1 2 7 1 

### 2 1 35 1.27E-0 4

2.40E-0 6 5.84E-0 6 2.39E-0 6 1.02E-0 5 1.10E-0 4 5.84E-0 6 2 0 1 0 0 2 4 

### 1 0

NOTE : 1-K.LJ I C (1 ) COET F factor

s ar e fro m fiel d stud

y conducted i n Januar

y 2000 . (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component

s * 876 0 hrs/y r



## n

Di b Pau l IC F Consultin g fugitive_COETF_emission s " 8/31/00-8:5 9 A MP.6 7

' '• ' " • . ' ^..'V*S'#''^V/ ^ '•', 1 • , •• ^ •yP.yP : :72;'.y 

## EMISSION S BASED O N LEA KNO-LEA KF^T Q 4^^^^0^^ : ^v5n>^!at:'r. ; '. ' 7 /: P : 7 :; - $ .


## FUGITIV E EQUIPMEN T LEAK S BY-PRODUC T CHEMICA L PLAN T



# ^^t^iiS^^^i^^il l oM_$|&&$-' :'i:':;s:S.i^._'"^;i!f- . : 

### 7 : 

### : : 

### AA: : 

### A7P.6 8



### Summar yo fBenzen e Emission s Fugitiv e Equipmen t Lea k A t By-Produc t Chemica l Plan t (Base d o n leak/no-lea k

factors ) Compan y A KStee l A KStee l Eri e Cok e Gul fState s Stee l Ne wBosto n Cok

e Tonawand a Cok

e Locatio n Middletown , O H Ashland , K

Y Erie , P A Gadsden , A L Ne wBoston , O H Tonawanda , N

Y Benzen e Emissions , lb/y r 1,41 4

5,23 9 1,41 3 5,55 1 7,56 7 1,73 2 Benzen e Emissions , lb/h r 1.61E-0 1

5.98E-0 1 1.61E-0 1 6.34E-0 1 8.64E-0 1 1.98E-0 1 NOTE : Emissio n factor

s ar e based o n screenin g factor s i n "Protoco l fo rEquipment Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e 2-6
. Emission s estimate s based o n screenin g rang e emissio n factor s Fo rAshland , detaile d monitorin g repor t was availabl e b

ymonth , quarter , semi-annual , an d annual
. Fo rcomponent

s that leake d abov

e 50 0 ppmv , i t wa

s assumed lea k

occurred fo rth e entir

e monitorin g period
. Fo rGul fState s Steel , revise d emission s estimate s ar e fro m th e COETF fiel d studyreport
. Fo rothe rfacilities , emission s estimates were base d o n on e cycl e o fmonitorin g only
. ASHLAN D I S TH E ONL

YSIT E THA

TSHOWE D LEAK

S ABOV E 10,00

0 ppmv . EMISSION S FRO M LEAKIN G COMPONENT S A TASHLAN D WER E ADDE D T O TH E EMISSION S FRO M NON-LEAKIN G COMPONENTS FO R EAC H SITE
. lb/h r= lb/yr/876 0

IC F Consultin g Di b Pau l fugitiveJeak_noleak_emission s 8/31/00-12:5 5 P MP.6 9



### AKSteel , Middletown/O H Fugitiv e Equipmen t Lea k

Emission s fro m By-Produc t Plant Strea m Benzen e Mas s Typ e o fNo . o

fEmissio n Benzen e Fractio n Equipment Component s Factor , Emissions , kg/hr/source lb/y r(2 ) (1 ) Lea n was h oi l 0.14 % 

### Pum p Flang e Valve s Connecto r Othe r 2 8 5 7 4 3 6 1 1.20E-0

2 6.00E-05 1.70E-03 6.00E-05 1.50E-03 0.6489

0.1379 3.401 3 0.004 9 2.473 9 Tota l Emissions , lb/y r 6.666 8 NOTE : (1 ) Emissio n factor

s ar e based o n Tabl e 2- 6 o

f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o f component

s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_leak_noleak_emission s 8/3 1 KxP n :2 8 A MP.7 0

A KSteel , Ashland/KY Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t Tota l benzen e emission s

Benzen e emission s fro m non-leakin g component s = 3,83 1 lb/y r
Benzen e emission s fro m leakin g component s = 1,40 7 lb/y r Tota l benzen e emission s = 5,23 9 lb/y r

Di b Pau l fugitive_leak_noleak_emission s IC F Consultin g 1 ~ ~8/30£ O - 8:0 3 P MP.7 1



### A KSteel , Ashland/K

Y Fugitiv e Equipmen t Lea k Emission s from By-Product Plan t Emission s fro m non-leakin g component s Strea m
Ligh t oi l (liqui d o rvapor

) Benzene Mas

s Fractio n

75% Typ e o f

Equipmen t
Pum p Flang e Valve s No
. o f Emissio n Benzen e

Component s Factor , Emissions ,

kg/hr/source lb/y r(2 ) 

## ( D 4 1.20E-0

2 69 5 4 6 6.00E-05 4 0 9 3 1.70E-0

3 2,29 0 Ope n En d 30 1.50E-03 65 2 Ric h was h oi l 3 %

Lea n was h oi l 0.14 % 

### Pum p Flang e Valve s Ope n En d Pum p 

### Flang e Valve s Ope n En d 2 1 0 11 6 2 1 3 1 0 13 1 1 9 1.20E-0

2 6.00E-05 1.70E-03 1.50E-03 1.20E-0 2 6.00E-0 5 1.70E-03 1.50E-03 1 4

0 11 4 1 8 1 0 6 1 Tota l Emissions , lb/y r 3,83 1

NOTE : (1 ) Emissio n factor

s ar e based o n Tabl e 2- 6 o

f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o f components * 8760 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitiveJeak_noleak_emission s 8/31/00- " 11:3 0 A MP.7 2



### AKSteel , Ashland/K

Y Fugitiv e Equipmen t Lea k

Emission s fro m By-Produc t Plan t Emission s fro m leakin g component s Componen t Type

/ Screenin g Emissio n Factor , Benzen e Monitorin g Level , ppm v(1 ) kg/hr/source (2 ) Emissions , lb/y r Frequenc y (3)

Valve (difficul t t o reach-annual ) 10000 8.52E-0 2 1234.05 Othe r10000 1.20E-0 2 86.5 4 (semi-annual ) 10000 1.20E-0 2 86.5 4 Tota l benzen e emissions , lb/yr ) 1407.1 3 NOTE : (1 ) I t wa s assumed that a component wa s leakin g i fmonitorin g indicate d 500 ppmvo rgreater
. Al l leakin g component

s wer e assumed t o be i n ligh t oi l service
. (2) Fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates",EPA-453/R-95-017 , Novembe r1995
. (3 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b * benzen e mas

s fractio n * mont h o rquarte ro rsemi-annua l o rannua l i n hr s

Di b Pau l fugitive_teak_noleak_emission s IC F Consultin g 1 ~ 8/31/D0 ~ 11:5 3 A MP.7 3



### Eri e Cok e Corporatio n Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t Strea m Benzene Mas s Type o

fNo . o

fEmissio n Benzen e Fractio n Equipmen t Component s Factor , Emissions , kg/hr/sourc

e lb/y r(2 ) (1 ) C O Ga s 1 % Valve s 4 2 6.00E-04 4.87 Othe r2 1.50E-0 3 0.58

Tota l Emissions , lb/y r5.4 5

NOTE : (1 ) Emissio n factor

s ar e based o n Tabl e 2- 6 o

f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b • no . o f component

s * 8760 hrs/y r* benzen e w t fractio n

Di b Pau l * fugitive_leak_noleak_emission s IC F Consultin g 1 8/31/00-11:5 6 A MP.7 4

Gul fState s Stee l Emission s fro m By-Produc t Plan t (Usin g AP-4 2 factor s wit h n o monitorin g data ) Strea m
Liqui d Benzen e Mas s Fractio n 

### 60 % Typ e o f

Equipmen t Flang e No . o f

Component s Emissio n

Factor , kg/hr/sourc e 

### (1 ) 19 1 0.00006 Benzen e

Emissions , lb/y r(2 ) 

### 13

3

CO . Ga s 62 % 67 %
89 % 31 % Connecto r

Valv e Flang e Connecto r 100 % Flang e (Leakin j 100 % Valv e 100 % Ope n Ende d Li r Tota l Emissions , lb/y r 18 1 8 3
14 6 11 2 9 11 5 1 8 6.00E-0 5

1.70E-0 3
0.0000 6 6.00E-0 5 6.00E-0 5 0.000 6 0.001 5 13 0

1,82 6
15 1 4 0 1 0 1,33 3 52 1 4,14 4

NOTE : (1 ) Emissio n factor s ar e base d o n Tabl e 2- 6 o f"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b • no . o f component s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitiveJeak_noleak_emission s 8/31/00-12:1 5 P MP.7 5



### NewBoston/O H Fugitiv e Equipmen t Lea k Emission s from By-Produc t Pjan t Strea m
Ligh t oi l (liqui d o rvapor

) Benzen e Mas s Fractio n



### 67 % Typ e o fNo
. o fEmissio n Benzen e Equipmen t Component s Factor , Emissions , kg/hr/sourc e lb/y r(2 ) (1 ) Pum p Flang e Valve s Ope n En d 9 84 8 12 2 7 2 1.20E-0

2 6.00E-05 1.70E-03 1.50E-03 1,397

65 8 2,68 4 1,39 7 C O Ga s 10 % 

### Othe r 1.50E-03 2 3

Tota l Emissions , lb/y r 6,16 0

NOTE : (1 ) Emissio n factor

s ar e based o n Tabl e 2- 6 of"Protoco l fo rEquipmen t Leak Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o f components * 8760 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitiveJeak_noleak_en.ission s 8/31/00-12:1 7 P MP.7 6



### Tonawanda/N Y Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t (Base d o n leak/no-lea k

factors ) Strea m
Ligh t oi l (liqui d o rvapor

)

C O Ga s Benzen e Mas s Fractio n
65 %

1 % Type o f

Equipmen t
Pum p Flang e Valve s Ope n En d Othe r Valve s No . o

f Component

s
1 2 7 1 3 3 5 Emissio n Benzen e Factor , Emissions , kg/hr/source lb/y r(2) 

## d ) 1.20E-0

2 15 1 6.00E-05 2 1.70E-03 14

9 1.50E-03 1 9

. 1.50E-03 1 6.00E-04 4

Tota l Emissions , lb/y r 32 5

NOTE : (1 ) Emissio n factor

s ar e base d o n Tabl e 2-

6 of"Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995
. (2) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component

s * 8760 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitiveJeak_noleak_emission s 8/31/00"l2:18P M'.••-
. : r':_ ; :' l .:•-£<£ : j^i ^ '!-•',• • V• 

## EMISSION S BASE

D O N ZERO/PEGGED/CORRELATION .s.itb:_s.nyie_jv
. 

## FACTORS P.7 7

.:•. ; iv<A>. '.W-;..ii.d;. > -'.V i 

## FUGITIV E EQUIPMEN T LEAKS BY-PRODUCT CHEMICA L PLANT ,;<•* . v?V^/^« % ,"P.7 8



### Summar yo fBenzen e Emission s Fugitiv e Equipmen t Lea k A t By-Product Chemica l Plan t (Base d o n defaul t zero , pegge d emission , an d correlatio n equation ) Compan y A KStee l AKStee l Eri e Cok e Gul fState s Stee l Ne wBosto n Cok

e Tonawand a Cok

e Locatio n Middletown , O H Ashland , K

Y Erie , P A Gadsden , A L Ne wBoston , O H Tonawanda , N

Y Benzen e Emissions , lb/y r 0.0

5 2007.40 0.06 48.0 0 20.43 1.0 7 Benzen e Emissions , lb/h r 5.25E-06

2.29E-0 1 7.40E-0 6 5.48E-03 2.33E-0 3 1.23E-0 4 NOTE : Emission s estimates base d o n defaul t zer

o emissio n rate factor

s fo rnon-leakin g components , correlatio n equatio n fo rcomponent s leakin g a

t <10,00 0 ppm , an d pegged emissio n rate s fo r component

s leakin g a

t o r> 10,000 ppmv . Emissio n factor

s ar e based o n screenin g factors i n "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. Fo rAshland , detaile d monitorin g repor t was availabl e b

ymonth , quarter , semi-annual , an d annual
. Fo rcomponent

s tha t leaked abov

e 500 ppmv , i t was assumed lea k occurre d fo rth e entir

e monitorin g period
. Fo rGul fStates Steel , revise d emission s estimate s ar e fro m th e COET F fiel d stud yreport
. Fo rothe rfacilities , emission s estimates were based o n on e cycl e o fmonitorin g only
. lb/h r= lb/yr/876 0

IC F Consultin g Di b Pau l fugitive_emission s 8/3 1 EO~-

11:1 9 A MP.7 9

A KSteel , Middletown/O H Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t Tota l benzen e emission s

Benzen e emission s fro m non-leakin g component s = 0.024 8 lb/y r Benzen e emission s fro m leakin g component s = 0.021 2 lb/y r Tota l benzen e emission s = 0.046 0 lb/y r

Di b Pau l fug'rtive_emission s IC F Consultin g 1 8/30/0 0 - 2:0 4 P MP.8 0

A KSteel , Middletown/O H Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t Emission s from non-leakin g component s Stream(1) Benzen e Mas s Typ e o fNo
. o fZero-Defaul t Zer o Benzen e Fractio n (2) Equipmen t Readin g Emissio n Emissions , Componen t Rate , lb/y r(5 ) s (3 ) kg/hr/sourc e

(4 )

Lea n was h oi l 0.14 % Pum p Flang e Valve s Connecto r Othe r 

### 2

8 5 7 4 3 6 1 2.40E-0 5 3.10E-0 7 7.80E-0 6 7.50E-0 6 4.00E-0 6 0.001 3

0.000 7 0.015 6 0.000 6 0.006 6 Tota l Emissions , lb/y r0.024 8 NOTE : (1 ) an d (2 ) Al l component s wer e assume d t o b e i n lea n was h oi l service
. (3 ) Componen t count , an d no . o fzer o leakin g component s fro m site
. I t wa s assume d tha t a componen t wit h les s tha n 50 0 ppm vscreenin g valu e wa s no t leaking
. (4 ) Defaul t zer o emissio n factor s fo rTO C are fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5 ) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* w t fractio n benzen e

Di b Pau l fugitive_emission s IC F Consultin g 1 8I3OIO0- 2:0 1 P MP.8 1



### A KSteel , Middletown/O H Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t Emission s from leakin g component s

Componen t Type

/ Screenin g Correlatio n Benzen e Monitorin g Level , Equation , Emission s Freguenc vppmvd ) kg/hr/source (2 ) , lb/y r(3 ) Othe r(Quarterly) 1000 1.36E-0 5 "(SV) 058 9 

### 0.005 3 Tota l fo r4 components 0.021 2 NOTE : (1 ) I t wa s assume d that a componen t wa s leakin g i fmonitorin g indicate d 500 ppmvo rgreater
. Al l leakin g component

s wer e assumed t o be i n ligh t oi l service
. (2 ) Fro m "Protoco l fo rEquipmen t Leak Emissio n Estimates",EPA-453/R-95-017 , Novembe r1995
. (3 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.4536 kg/l b * benzen e mas

s fractio n * mont h o rquarte ro rsemi-annua l o rannua l i n hr s

Di b Pau l fugitive_emission s IC F Consultin g 1 B/31/00 ~ 11:4 4 A MP.8 2



### A KSteel , Ashland/K

Y Fugitive Equipmen t Lea k Emission s from By-Produc t Plan t Tota l benzen e emission s

Benzen e emission s fro m non-leakin g component s = 1 4 lb/y r Benzen e emission s fro m leakin g component s = 1,99 4 lb/y r Tota l benzen e emissions = 2,007 lb/y r

Di b Pau l fugitive_emission s IC F Consultin g 1 8/18/00-12:0 3 P M

### A KSteel , Ashland/K

Y Fugitiv e Equipmen t Leak

Emission s from By-Produc t Plan t Emission s from non-leakin g component s P.8 3



### Stream(1 )

Ligh t oi l (liqui d o rvapor

)

Ric h was h oi l

Lea n was h oi l Benzen e Mas s Fractio n (2 )

75 %

3 %

0.14 % 

### Typ

e o f Equipmen t

Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d No . o

fZeroReadin g Component

s (3) 4

4 6 9 3 30 2 1 0 11 6 2 1 3 1 0 13 1 1 9 Defaul t Zer o Emissio n Rat e • kg/hr/sourc e (4 ) 2.40E-0 5 3.10E-07 7.80E-06 2.00E-0 6 2.40E-05 3.10E-07 7.80E-0 6 2.00E-0 6 2.40E-0 5 3.10E-07 7.80E-0 6 2.00E-0 6 Benzen e

Emissions , lb/y r(5) 1.3

9 0.2 1 10.5 1 0.87 0.0 3 0.0 0 0.5 2 0.0 2 0.00 0.0 0 0.0 3 0.00 Tota l Emissions , lb/y r 1 4

NOTE : (1 ) Fo rprocess stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3 ) Componen t count , an d no . o f zer o leakin g components fro m site
. I t wa s assume d that a componen t wit h less tha n 50

0 ppmvscreenin g valu e wa s no t leaking
. (4 ) Defaul t zer

o emissio n factors fo rTOC ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f components * 8760 hrs/y r* w

t fractio n benzen e

Di b Pau l IC F Consultin g fugitive_emission s 8/11/00-2:2 2 P MP.8 4



### A KSteel , Ashland/K Y Fugitiv e Equipmen t Lea k Emission s from By-Product Plan t Emission s from leakin g component s Componen t Type /

Screenin g Correlatio n Equation , Benzen e Monitorin g Level , ppm v(1 ) kg/hr/sourc e (2 ) Emissions , lb/y r Frequenc y(3 )

Valve (Quarterly) 5000 2.29E-06 *(SV) 074 6 

### 4.7 0 500 2.29E-06 *(SV) 074 6 

### 0.8 4 Flang e (Quarterly) 700 4.6 1 E-0 6 *(SV) 070 3 

### 1.6 5 Othe r(Quarterly) 700 1.36E-0 5 *(SV)°- 5M 

### ' 2.3 0 Valv e (difficul t t o reach-annual ) 1000 0 6.40E-0

2 926.9 8 Othe r1000 0 7.30E-0

2 528.6 7 (semi-annual ) 1000 0 7.30E-0

2 528.6 7

1,99 4 NOTE : (1 ) I t wa s assume d tha

t a componen t wa

s leakin g i fmonitorin g indicate d 50 0 ppmvo rgreater
. Al l leakin g components wer e assumed t o b

e i n ligh t oi l service
. (2) Fro m "Protoco l fo rEquipmen t Leak Emissio n Estimates",EPA-453/R-95-017 , Novembe r1995
. (3 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * benzen e mass fractio n * mont h o rquarte ro rsemi-annua l o rannua l i n hr s

Di b Pau l fugrtive_emission s IC F Consultin g 1 8/3 1 AX ) - 11:4 5 A MP.8 5



### Eri e Cok e Corporatio n Fugitiv e Equipment Lea k

Emission s from By-Produc t Plant Stream(1 )

C O Ga s Benzen e Mas s Fractio n (2 )

1 % 

### Type of

Equipmen t

Valve s Othe r No . o

fZero - Defaul t Zero Benzen e Readin g Emissio n Emissions , Component

s Rate , lb/y r(5 ) (3 ) kg/hr/sourc e (4 ) 4 2 7.80E-06 0.06 2 4.00E-06 0.0 0

Tota l Emissions , lb/y r0.0 6

NOTE : (1 ) Fo rprocess stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3 ) Componen t count , an d no . of zer o leakin g components fro m site
. I t wa s assumed that a componen t wit h less tha n 500 ppmvscreenin g valu e was not leaking
. (4 ) Defaul t zer

o emissio n factors fo rTO C ar e fro m "Protoco l fo rEquipmen t Leak Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5 ) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.4536 kg/l b * no . of components * 876 0 hrs/y r* w

t fractio n benzen e

Dif c P 3 " 1 fugitive_emission s IC F Consultin g 1 8/11£0 - 2:1 8 P MP.8 6



### Ne wBoston/O H Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t Stream(1 )
Ligh t oi l (liqui d o rvapor

)

C O Ga s Benzen e Mas s

Fractio n (2 )

67 %

10 % Typ e o f

Equipmen t

Pum p Flang e Valve s Ope n En d Othe r No . ofZero Readin g Component s (3 ) 9

84 8 12 2 7 2 8 Defaul t Zer o Emissio n Rat e kg/hr/sourc e (4 . 2.40E-0 5 3.10E-0 7 7.80E-0 6 2.00E-0 6 4.00E-0 6 Benzen e

Emissions , lb/y r(5 )
2.7 9 3.4 0 12.3 1 1.86 0.0 6



### Tota l Emissions , lb/y

r 20

NOTE : (1 ) Fo rproces

s stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3) Component count , an d no . o fzer o leakin g components fro m site
. I t wa s assume d that a component wit h les s tha n 500 ppmvscreenin g valu e wa s no t leaking
. (4) Defaul t zer

o emissio n factor

s fo rTO C ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.4536 kg/l b * no . ofcomponent s * 8760 hrs/y r* w

t fractio n benzen e

Di b Pau l IC F Consultin g fugitive_emission s 8/11/00-2:1 7 P MP.8 7



### Tonawanda/N Y Fugitiv e Equipment Leak Emission s from By-Produc t Plant
Stream(1 )


### Ligh t oi l (liqui d o rvapor

)

C O Ga s Benzen e Mas s Fractio n (2

)

65 %

1 % Type o

f Equipmen t

Pum p Flang e Valve s Ope n En d Othe r Valve s ' No . o

fZero Readin g Component

s (3) 1

2 7 1 3 3 5 Defaul t Zer

o Emissio n Rat e kg/hr/source (4 i 2.40E-05 3.10E-0 7 7.80E-06 2.00E-06 4.00E-06 7.80E-06 Benzen e

Emissions , lb/y r(5 ) 0.30 0.0 1 0.69 0.0 3 0.0 0 0.05

Tota l Emissions , lb/y r

NOTE : (1 ) Fo rprocess stream s i n benzen e service (e.g. , ligh t oi l liquid , ligh t oi l vapor , etc. ) (2 ) Composition s fro m site
. (3) Componen t count , an d no . ofzer o leakin g components fro m site
. I t wa s assumed tha

t a componen t wit h les s tha n 500 ppmvscreenin g valu e was no t leaking
. (4) Defaul t zer

o emissio n factors fo rTOC ar e fro m "Protoco l fo rEquipmen t Lea k Emissio n Estimates" , EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (5) Benzen e emission s = Defaul t zer o factor , kg/hr/componen t * 1/0.4536 kg/l b * no . o fcomponents * 876 0 hrs/y r* w

t fraction.benzen e

Di b Pau l IC F Consultin g fugitive_emission s 8/11/00-1:5 9 P MP.8 8



## EMISSIONS BASE

D ON 250 ppSrf

FUGITIV E EQUIPMENT LEAK

S BY-PRODUCT CHEMICAL PLANT :'_;if»:S___!ifi ; 3;3'~^PvS : "RjO * ,.;;• « , ? rj^g:^-: ^ ^;g^-£^^-?j^rM : ;i/ ^ •s^ 4 ::vy>.'.;.;.jr . *
_P.8 9

Summary ofBenzen e Emission s Fugitiv e Equipmen t Lea k At By-Produc t Chemica l Plan t (Base d o n 25 0 ppm vleak) Compan y
A KStee l A KStee l Eri e Cok e GulfState s Stee l Ne wBosto n Cok

e Tonawand a Cok

e Locatio n

Middletown , O H Ashland , K

Y 

### Erie , P A Gadsden , A L Ne wBoston , O H Tonawanda , N Y Benzen e Emissions , lb/y r 

### 1

48 4 1 1,84 7 2,95 1 

### 3 9 Benzen e Emissions , lb/h r
1.67E-0 4

5.53E-0 2 1.46E-0 4 2.11E-0 1 3.37E-0 1 4.43E-0 3 NOTE : Al l components are assumed to lea k a t hal fth e lea k

leve l (50 0 ppmv/2 ) Emissio n Estimate s are based o n "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3 . Emission s estimate s are based o n correlatio n equation . lb/h r= lb/yr/876 0

IC F Consultin g Di b Pau l fugitive_250ppmv_emission s 8/31/00-8:4 2 A MA KSteel , Middletown/O H

Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t P.9 0

Strea m Benzen e Mas s Typ e o fNo . o f Fractio n Equipmen t Component s

Lea n was h oi l 0.14 % Pum p Flang e Valve s Connecto r Othe r 

### t s

2 8 5 7 4 3 6 1 Correlatio n

Equation , kg/hr/sourc e (1 )
5.03E-0 5 *(SV) 061 0 4.6 1 E-0 6 *(SV) 070 3 2.29E-0 6 *(SV) 074 8 1.53E-06*(SV) 073 5 1.36E-05*(SV) 058 9 Benzen e

Emissions , lb/y r(2 )
0.078 9 0.513 8 0.281 8 0.007 2 0.579 7 Tota l Emissions , lb/y r 

### 1.461 4 NOTE : (1 ) Emissio n Estimate s ar e base d on "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3 . (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f components * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_250ppmv_emission s 8/31/00-8:2 0 A MA KSteel , Ashland/KY Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t P.9 1

Strea m Benzen e Mas s Typ e o fNo . o fCorrelatio n Equation , Benzen e Fractio n Equipmen t Component s kg/hr/sourc e (1 ) Emissions , lb/y r(2 ) Ligh t oi l (liqui d o rvapor ) 

### 75 %

Ric h was h oi l 

### 3 %

Lea n was h oi l 

### 0.14 % Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d Pum p Flang e Valve s Ope n En d 

### 4 46 93 30 2 1 0 11 6 

### 2 1 3 1 0 13 1 

### 1 9 5.03E-0 5 *(SV) 0

- 61 0 4.6 1 E-0 6 •(SV) 070 3 2.29E-0 6 •(SV) 0

- 7 * 8 2.20E-0 6 *(SV) 07 M 5.03E-0 5 •(SV) 081 0 4.6 1 E-0 6 *(SV) 070 3 2.29E-0 6 *(SV) 074 8 2.20E-0 6 *(SV) 07 W 5.03E-0 5 *(SV) oe1 0 4.6 1 E-0 6 *(SV) 070 3 2.29E-0 6 *(SV)° TM 2.20E-0 6 •(SV) 070 4 84.5 8 148.9 7 189.7 0 46.6 2 1,6 9 1.3 0 9.4 6 1.3 1 0.1 2 0.0 6 0.5 0 0.0 6 Tota l Emissions , lb/y r 484.3 6

NOTE : (1 ) Emissio n Estimate s ar e base d o n "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_250ppmv_emission s 8/31*30-8:2 2 A MP.9 2

Eri e Cok e Corporatio n Fugitiv e Equipmen t Lea k Emission s from By-Produc t Plan t
Strea m 

### Benzen e

Mas s Fractio n Typ e o fNo . ofCorrelatio n Equation , Benzen e

Equipmen t Component s kg/hr/sourc e (1 ) Emissions , lb/y r(2 )
C O Ga s 1 % Valve s Othe r 4 2 2.29E-0 6 *(SV) 074 8 2 1.36E-05*(SV) 058 9 1.1 4 0.135 8

Tota l Emissions , lb/y r 1.2 8

NOTE : (1 ) Emissio n Estimate s ar e base d o n "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3
. (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_250ppmv_emission s 8/31/00-8:2 4 A MGul fState s Stee l

Emission s fro m By-Produc t Plan t P.9 3

Strea m Liqui d Benzen e Mas s Fractio n 60% Typ e o f

Equipmen t Flang e No . o f

Component s

19 1 Correlatio n Equation ,

kg/hr/sourc e (1 ) Benzen e Emissions , lb/y r(2 )

4.6 1 E-0 6 -(SV) ' ,0.70 3

CO . Ga s 62 % Connecto r 67 % Valv

e
89 % Flang e 31 % Connecto r 100 % Flang e (Leakin g 100 % Valv

e 100 % Ope n Ended Li

n 18

1 8 3
14 6 11 2 9 11 5 1 8 1.53E-0 6 •(SV) 073 5

2.29E-0 6 '(SV) 074 6
4.6 1 E-0 6 •(SV) 070 3 1.53E-06*(SV) C TM 4.6 1 E-0 6 *<SV) 070 3 2.29E-0 6 •(SV) 074 6 2.20E-0 6 •(SV) 070 4 49 5 192 15 1
56 1 5 9 39 31 3 3 7

Tota l Emissions , lb/y r 1,84 7

NOTE : (1 ) Emissio n Estimate s are base d o n "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3 . (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . of component s * 876 0 hrs/y r* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_250ppnw_emi8iion t 8/31/0 0 - 85 9 A MNewBoston/O H Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t P.94 ^

Strea m Benzen e Mas s Typ e o fNo . o fCorrelatio n Equation , Benzen e Emissions , Fractio n Equipmen t Component s kg/hr/sourc e (1 ) lb/y r(2 )
Ligh t oi l (liqui d o rvapor ) 67 %

C O Ga s 10 % Pum p

Flang e Valves Ope n En d Othe r 9 84 8 12 2 7 2 8 5.03E-0 5 *(SV) 061 0

4.6 1 E-0 6 '(SV) 070 5 2.29E-0 6 *(SV) 074 6 2.20E-0 6 •(SV) 070 4 1.36E-0 5 *(SV) 0S M 170 2,45 3 22 2 10 0

Tota l Emissions , lb/y r 2,95 1

NOTE : (1) Emissio n Estimate s ar e base d o n "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3 . (2) Benzen e emission s = emissio n factor , kg/hr/component * 1/0.453 6 kg/l b * no . o f component s * 876 0 hrs/y r* benzen e wt fractio n

Di b Pau l IC F Consultin g hjgitive_250ppmv_emiasion a 8/31/0 0 - 8:3 1 A MP.9 5 •

Tonawanda/N Y Fugitiv e Equipmen t Lea k Emission s fro m By-Produc t Plan t (Base d o n 25 0 ppm vleak ) Strea m Benzene Mas s Typ e o fNo . o f Fractio n Equipmen t Component s
Ligh t oi l (liqui d o rvapor ) 65 % Pum p 1 Correlatio n Equation , Benzen e kg/hr/sourc e (1 ) Emissions , lb/y r(2 )

5.03E-0 5 •(SV) 0 - 610 ' 18.3 3 —' irV

Flang e Valve s Ope n En d 

### 2 7 1 4.6 1 E-0 6 *(SV) 070 3 2.29E-0 6 *(SV) 074 e 2.20E-0 6 •(SV) 070 4 5.6 1 12.3 7 

### 1.3 5 C O Ga s 1 % Othe r Valve s 3 3 5 1.36E-0 5 »(SV) 05 M 2.29E-0 6 *(SV) 074 6 

### 0.203 6 0.9 5

Tota l Emissions , lb/y r 38.8 2

NOTE : (1 ) Emissio n Estimate s ar e base d o n "Protoco l fo rEquipmen t Lea k Emissio n Estimates, " EPA-453/R-95-017 , Novembe r1995 , Tabl e C-3 . (2 ) Benzen e emission s = emissio n factor , kg/hr/componen t * 1/0.453 6 kg/l b * no . of component s * 876 0 hrs/yr* benzen e w t fractio n

Di b Pau l IC F Consultin g fugitive_250ppmv_emis3ion s 8/31/00"-8:3 3 A M