SAFETY DATA SHEET

SolsticeTM ZD, SolsticeTM 1233zd (E)

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION 

Product name : SolsticeTM ZD, SolsticeTM 1233zd (E) 

MSDS Number : 000000018007 

Product Use Description : Refrigerant, Power cycle fluid, Heat transfer fluid

Company : Honeywell International, Inc. 

101 Columbia Road 

Morristown, NJ 07962-1057 

For more information call : 800-522-8001 

+1-973-455-6300 

 (Monday-Friday, 9:00am-5:00pm) 

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414 

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887 

: 

 : (24 hours/day, 7 days/week) 

SECTION 2. HAZARDS IDENTIFICATION 

Emergency Overview 

Form : liquid, clear 

Color : colourless 

Odor : slight 

Classification of the substance or mixture 

Classification of the 

substance or mixture 

: Gases under pressure, Liquefied gas 

Simple Asphyxiant 

GHS Label elements, including precautionary statements 
SAFETY DATA SHEET

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Symbol(s) : 

Signal word : Warning 

Hazard statements : Contains gas under pressure; may explode if heated. 

May displace oxygen and cause rapid suffocation. 

Precautionary statements : Prevention: 

Use personal protective equipment as required. 

Storage: 

Protect from sunlight. Store in a well-ventilated place. 

Carcinogenicity 

No component of this product present at levels greater than or equal to 0.1% is identified as a known 

or anticipated carcinogen by NTP, IARC, or OSHA. 

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 

Chemical nature : Substance 

Chemical Name CAS-No. Concentration 

trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >99.00 %

SECTION 4. FIRST AID MEASURES 

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. 

If breathing is difficult, give oxygen. Use oxygen as required, 

provided a qualified operator is present. Call a physician. 

Skin contact : After contact with skin, wash immediately with plenty of water. 

If symptoms persist, call a physician. Take off all contaminated 

clothing immediately. Wash contaminated clothing before reuse. 
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Eye contact : Rinse immediately with plenty of water, also under the eyelids, 

for at least 15 minutes. Call a physician if irritation develops or 

persists. 

Ingestion : If victim is fully conscious, give a cupful of water. Do not induce 

vomiting without medical advice. Never give anything by mouth 

to an unconscious person. Call a physician immediately. 

Notes to physician 

Treatment : Treat symptomatically. 

SECTION 5. FIREFIGHTING MEASURES 

Suitable extinguishing media : The product is not flammable. 

Use extinguishing measures that are appropriate to local 

circumstances and the surrounding environment. 

Water spray 

Carbon dioxide (CO2) 

Dry chemical 

Foam 

Specific hazards during 

firefighting 

: This product is not flammable at ambient temperatures and 

atmospheric pressure. 

However, this material can ignite when mixed with air under 

pressure and exposed to strong ignition sources. 

Container may rupture on heating. 

Cool closed containers exposed to fire with water spray. 

Do not allow run-off from fire fighting to enter drains or water 

courses. 

Vapours are heavier than air and can cause suffocation by 

reducing oxygen available for breathing. 

Exposure to decomposition products may be a hazard to 

health. 

In case of fire hazardous decomposition products may be 

produced such as: 

Hydrogen fluoride 

Gaseous hydrogen chloride (HCl). 

Carbon monoxide 

Carbon dioxide (CO2) 

Carbonyl halides 
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Special protective equipment 

for firefighters 

: In the event of fire and/or explosion do not breathe fumes. 

Wear self-contained breathing apparatus and protective suit. 

No unprotected exposed skin areas. 

SECTION 6. ACCIDENTAL RELEASE MEASURES 

Personal precautions : Immediately evacuate personnel to safe areas.

Keep people away from and upwind of spill/leak.

Wear personal protective equipment. Unprotected persons 

must be kept away.

Remove all sources of ignition.

Ventilate the area.

Vapours are heavier than air and can cause suffocation by 

reducing oxygen available for breathing.

Avoid accumulation of vapours in low areas.

Unprotected personnel should not return until air has been 

tested and determined safe.

Ensure that the oxygen content is >= 19.5%.

Environmental precautions : Should not be released into the environment.

Do not flush into surface water or sanitary sewer system.

Prevent further leakage or spillage if safe to do so.

Prevent spreading over a wide area (e.g. by containment or oil 

barriers).

Methods for cleaning up : Contain spillage, and then collect with non-combustible 

absorbent material, (e.g. sand, earth, diatomaceous earth, 

vermiculite) and place in container for disposal according to 

local / national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE 

Handling 

Handling : Handle with care.

Do not use in areas without adequate ventilation.

Do not breathe vapours or spray mist.

Avoid contact with skin, eyes and clothing.

Pressurized container. Protect from sunlight and do not expose 

to temperatures exceeding 50 °C.
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Follow all standard safety precautions for handling and use of 

compressed gas cylinders.

Use authorized cylinders only.

Protect cylinders from physical damage.

Do not puncture or drop cylinders, expose them to open flame 

or excessive heat.

Do not pierce or burn, even after use. Do not spray on a naked 

flame or any incandescent material.

Do not remove screw cap until immediately ready for use.

Always replace cap after use.

Advice on protection 

against fire and explosion 

: Can form a combustible mixture with air at pressures above 

atmospheric pressure.

Keep product and empty container away from heat and 

sources of ignition.

Storage 

Requirements for storage 

areas and containers 

: Pressurized container: protect from sunlight and do not expose 

to temperatures exceeding 50 °C. Do not pierce or burn, even 

after use.

Keep containers tightly closed in a dry, cool and well-ventilated 

place.

Storage rooms must be properly ventilated.

Ensure adequate ventilation, especially in confined areas.

Protect cylinders from physical damage.

Store away from incompatible substances.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Protective measures : Ensure that eyewash stations and safety showers are close to 

the workstation location.

Do not breathe vapours or spray mist.

Avoid contact with skin, eyes and clothing.

Engineering measures : Use with local exhaust ventilation.

Perform filling operations only at stations with exhaust 

ventilation facilities.

Eye protection : Do not wear contact lenses.

Wear as appropriate:

Goggles or face shield, giving complete protection to eyes
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Hand protection : Impervious gloves

Gloves must be inspected prior to use.

Replace when worn.

Skin and body protection : Wear as appropriate:

Solvent-resistant gloves

Solvent-resistant apron and boots

If splashes are likely to occur, wear:

Protective suit

Respiratory protection : In case of insufficient ventilation wear suitable respiratory 

equipment.

Wear a positive-pressure supplied-air respirator.

For rescue and maintenance work in storage tanks use selfcontained breathing apparatus.

Use NIOSH approved respiratory protection.

Hygiene measures : Handle in accordance with good industrial hygiene and safety 

practice.

Avoid contact with skin, eyes and clothing.

Do not breathe vapours or spray mist.

Ensure adequate ventilation, especially in confined areas.

Remove and wash contaminated clothing before re-use.

Contaminated work clothing should not be allowed out of the 

workplace.

Keep working clothes separately.

Wash hands before breaks and immediately after handling the 

product.

Exposure Guidelines

Components CAS-No. Value Control 

parameters 

Upda

te 

Basis 

trans-1-Chloro3,3,3-

trifluoropropene 

102687-65-0 TWA :

time 

weighted 

average 

(800 ppm) 2013 Honeywell:Limit 

established by 

Honeywell 

International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 

Physical state : liquid, clear
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Color : colourless 

Odor : slight 

Melting point/freezing point : < -90 °C 

Method: OECD Test Guideline 102 

Boiling point/boiling range : 19 °C 

Flash point : Method: ISO 2719 

Note: not applicable 

Flammability : The product is not flammable. 

Method: Flammability (gases) 

Lower explosion limit : Note: None 

Upper explosion limit : Note: None 

Vapor pressure : 1,516 hPa 

at 30 °C(86 °F) 

Vapor density : Note: (Air = 1.0), not determined 

Density : 1.27 g/cm3 

Water solubility : 1.90 g/l at 20 °C 

Method: OECD Test Guideline 105 

Partition coefficient: noctanol/water : log Pow: 2.2 at 25 °C 

Ignition temperature : 380 °C at 986.8 - 1,035.9 hPa 

Method: DIN 51794 
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Oxidizing properties : The substance or mixture is not classified as oxidizing. 

Molecular Weight : 130.5 g/mol 

SECTION 10. STABILITY AND REACTIVITY 

Possibility of hazardous 

reactions 

: Polymerization can occur. 

Conditions to avoid : Protect from heat/overheating. 

Keep away from direct sunlight. 

Heat, flames and sparks. 

Do not mix with oxygen or air above atmospheric pressure. 

Incompatible materials to 

avoid 

: Strong oxidizing agents 

Magnesium 

Aluminium 

Hazardous decomposition 

products 

: In case of fire hazardous decomposition products may be 

produced such as: 

Carbon monoxide 

Carbon dioxide (CO2) 

Carbonyl halides 

Gaseous hydrogen chloride (HCl). 

Gaseous hydrogen fluoride (HF). 

SECTION 11. TOXICOLOGICAL INFORMATION 

Acute inhalation toxicity : LC50: 120000 ppm 

Exposure time: 4 h 

Species: rat 

Skin irritation : Species: rabbit 

Result: No skin irritation 

Classification: Not classified as a skin irritant in animal testing. 

Method: OECD Test Guideline 404 

Exposure time: 4 h 
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Sensitisation : Result: Does not cause skin sensitisation. 

Classification: Patch test on human volunteers did not 

demonstrate sensitisation properties. 

 : Cardiac sensitization 

Species: dogs 

Note: Cardiac sensitisation threshold (dog): 25000 ppm. 

Repeated dose toxicity : Species: rat 

Application Route: Inhalation 

Exposure time: 4 Weeks 

NOEL: 4500 ppm 

Note: Subacute toxicity 

Genotoxicity in vitro : Test Method: Mutagenicity (Salmonella typhimurium - reverse 

mutation assay) 

Result: negative 

Genotoxicity in vivo : Species: rat 

Cell type: Bone marrow 

Method: Mutagenicity (micronucleus test) 

Result: negative 

Genotoxicity in vivo : Test Method: Unscheduled DNA synthesis 

Species: rat 

Result: negative 

Genotoxicity in vivo : Species: mouse 

Cell type: Bone marrow 

Method: Mutagenicity (micronucleus test) 

Result: negative 

Reproductive toxicity : Species: rabbit 

Note: No-observed-effect level - 15,000 ppm 

 : Species: rat 

Note: No-observed-effect level - 10,000 ppm 
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Teratogenicity : Species: rabbit 

Note: No-observed-effect level - 15,000 ppm 

 : Species: rat 

Note: No-observed-effect level - 10,000 ppm 

Further information : Note: Excessive exposure may cause central nervous system 

effects including drowsiness and dizziness. Excessive 

exposure may also cause cardiac arrhythmia.

SECTION 12. ECOLOGICAL INFORMATION 

Ecotoxicity effects 

Toxicity to fish : LC50: 38 mg/l 

Exposure time: 96 h 

Species: Oncorhynchus mykiss (rainbow trout) 

Method: OECD Test Guideline 203 

Toxicity to daphnia and other 

aquatic invertebrates

: Immobilization 

EC50: 82 mg/l 

Exposure time: 48 h 

Species: Daphnia magna (Water flea) 

Method: OECD Test Guideline 202 

Toxicity to algae : Growth inhibition 

EC50: 106.7 mg/l 

Exposure time: 72 h 

Species: Pseudokirchneriella subcapitata (green algae) 

Method: OECD Test Guideline 201 

: Growth rate 

NOEC: 115 mg/l 

Exposure time: 72 h 

Species: Pseudokirchneriella subcapitata (green algae) 

Method: OECD Test Guideline 201 

Elimination information (persistence and degradability) 
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Biodegradability : Result: Not readily biodegradable. 

Value: 0 % 

Method: OECD 301 D 

Further information on ecology 

SECTION 13. DISPOSAL CONSIDERATIONS 

Disposal methods : Observe all Federal, State, and Local Environmental 

regulations. 

Note : Where possible recycling is preferred to disposal or 

incineration.

SECTION 14. TRANSPORT INFORMATION 

DOT UN/ID No. : UN 3163

Proper shipping name : LIQUEFIED GAS, N.O.S. 

(Trans-1-Chloro-3,3,3-trifluoropropene) 

Class 2.2 

Packing group 

Hazard Labels 2.2

IATA UN/ID No. : UN 3163 

Description of the goods : LIQUEFIED GAS, N.O.S. 

 (Trans-1-Chloro-3,3,3-trifluoropropene) 

Class : 2.2 

Hazard Labels : 2.2 

Packing instruction (cargo 

aircraft) 

: 200 

Packing instruction 

(passenger aircraft) 

: 200 

IMDG UN/ID No. : UN 3163 

Description of the goods : LIQUEFIED GAS, N.O.S. 

 (TRANS-1-CHLORO-3,3,3-

TRIFLUOROPROPENE) 

Class : 2.2 

Hazard Labels : 2.2 

EmS Number : F-C, S-V 
SAFETY DATA SHEET

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Marine pollutant : no 

SECTION 15. REGULATORY INFORMATION 

Inventories 

US. Toxic Substances 

Control Act 

: On TSCA Inventory 

Australia. Industrial 

Chemical (Notification and 

Assessment) Act 

: Not in compliance with the inventory 

: trans-1-Chloro-3,3,3-

trifluoropropene 

102687-65-0 

Canada. Canadian 

Environmental Protection 

Act (CEPA). Domestic 

Substances List (DSL) 

: All components of this product are on the Canadian DSL. 

Japan. Kashin-Hou Law 

List 

: On the inventory, or in compliance with the inventory 

Korea. Toxic Chemical 

Control Law (TCCL) List 

: On the inventory, or in compliance with the inventory 

Philippines. The Toxic 

Substances and Hazardous 

and Nuclear Waste Control 

Act 

: Not in compliance with the inventory 

: trans-1-Chloro-3,3,3-

trifluoropropene 

102687-65-0 

China. Inventory of Existing 

Chemical Substances 

: Not in compliance with the inventory 

: trans-1-Chloro-3,3,3-

trifluoropropene 

102687-65-0 

New Zealand. Inventory of 

Chemicals (NZIoC), as 

published by ERMA New 

Zealand 

: Not in compliance with the inventory 
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: trans-1-Chloro-3,3,3-

trifluoropropene 

102687-65-0 

National regulatory information 

SARA 302 Components : SARA 302: No chemicals in this material are subject to the 

reporting requirements of SARA Title III, Section 302. 

SARA 313 Components : SARA 313: This material does not contain any chemical 

components with known CAS numbers that exceed the 

threshold (De Minimis) reporting levels established by SARA 

Title III, Section 313. 

SARA 311/312 Hazards : Acute Health Hazard 

Sudden Release of Pressure Hazard 

California Prop. 65 : This product does not contain any chemicals known to State of 

California to cause cancer, birth defects, or any other 

reproductive harm. 

New Jersey RTK : trans-1-Chloro-3,3,3-

trifluoropropene 

102687-65-

0 

Pennsylvania RTK : trans-1-Chloro-3,3,3-

trifluoropropene 

102687-65-

0 

WHMIS Classification : A: Compressed Gas 

This product has been classified according to the hazard criteria 

of the CPR and the MSDS contains all of the information 

required by the CPR.

SECTION 16. OTHER INFORMATION 

HMIS III NFPA

Health hazard : 2 2 
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Flammability : 0 0 

Physical Hazard : 0 

Instability : 0 

Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the 

use of individuals trained in the particular system. 

Further information 

The information provided in this Safety Data Sheet is correct to the best of our knowledge, 

information and belief at the date of its publication. The information given is designed only as a 

guidance for safe handling, use, processing, storage, transportation, disposal and release and is not 

to be considered a warranty or quality specification. The information relates only to the specific 

material designated and may not be valid for such material used in combination with any other 

materials or in any process, unless specified in the text. Final determination of suitability of any 

material is the sole responsibility of the user. This information should not constitute a guarantee for 

any specific product properties. 

Changes since the last version are highlighted in the margin. This version replaces all previous 

versions.

Previous Issue Date: 08/12/2013

Prepared by: Honeywell Performance Materials and Technologies Product Stewardship Group