### Appendix 2-D(3) Comparison of SAM Outputs to Monitoring Data from Monitoring Sites in White River (East Fork) Basin, IN This appendix, the first of three spreadsheets, is provided in support of the comparison of model outputs with measured data in Section 2.4 of the SAP documentDevelopment of a Spatial Aquatic Model (SAM) for Pesticide Assessments. As a part of the model evaluation for SAM, this appendix provides a comparison of estimated daily atrazine concentrations for 2000- 2014 to monitoring data from the Atrazine Ecological Exposure Monitoring Program (AEEMP) and the Atrazine Monitoring Program (AMP) in the White River (East Fork) basin area. Monitoring data and descriptions can also be found in Appendix 2C.
The table to the right describes each tab linked to the monitoring sites found in the White River (East Fork) test basin. Figures 1 and 2 (below) shows the locations of the test sites. Each basin is identified both by the original study ID and by the NHDplus (version 2) comid for the catchment that is associated with the monitoring sampling site (pour point).
Figure 1: Location of Test Basin Areas for SAM Model Development and Evaluation.

### Figure 2: AEEMP and AMP Monitoring Sites in the White River (East Fork) (IN) Test Basin Area.Worksheet Tab Contents SummaryByYear Summary of annual (2000-2014) total mass lost, total runoff, maximum atrazine concentrations and comparisons with monitoring for each test basin site. Includes graphs comparing concentration estimates to monitoring data.
IN-10_18459870_basin Results for AEEMP site IN-10 (NHD+ comid 18459870) IN-04 river_18454511_basin Results for AMP site IN-04 river (NHD+ comid 18454511) IN-06 river_18450057_basin Results for AMP site IN-06 river (NHD+ comid 18450057) IN-07 river_18445592_basin Results for AMP site IN-07 river (NHD+ comid 18445592) IN-08 river_18445664_basin Results for AMP site IN-08 river (NHD+ comid 18445664) IN-13 river_18451035_basin Results for AMP site IN-13 river (NHD+ comid 18451035) Monitoring Monitoring data for each of the test basin sites (used for graphs) Each basin tab includes the following fields: Field Description/source Date Daily dates from scenario, 1/1/2000 - 12/31/2014 Est. Conc (ug/L) Estimated daily concentrations generated using aggregated scenarios (soils grouped by WQI criteria) Rmass (kg) Daily pesticide mass flux lost in runoff generated using aggregated scenarios (soils grouped by WQI criteria) Runoff(m) Daily runoff volume using aggregated scenarios (soils grouped by WQI criteria) RConc(ug/L) Daily runoff concentration using aggregated scenarios (soils grouped by WQI criteria) TotalFlow(m3) Total flow estimate in stream mixing cell, based on NHD+ data baseflow(m3) Base flow estimate for stream mixing cell (see Section 2.1)MassAppl Daily mass applied based on pesticide application rate, corn area, length of application window (50 days) Cumul. Mass Appl. Cumulative mass of pesticide applied in watershed (summing MassAppl) Cumul. Runoff Loss, Aggreg Scenarios Cumulative pesticide mass lost in runoff (summing daily Rmass values)

Year Year of simulation Mass(kg) Sum of daily pesticide mass loss by year for soils aggregated by WQI scenarios Runoff(m) Sum of daily runoff volumes by year for soils aggregated by WQI scenarios
Max conc Maximum annual concentration in water for soils aggregated by WQI scenarios

Max runoff conc Maximum annual concentration in runoff for soils aggregated by WQI scenarios CornArea(m2) Corn area, based on watershed recipe files for 2010-2014 CDL
CornFrac Corn as a fraction of watershed area, based on watershed recipe files for 2010-2014 CDL Applied(kg) Total kg of pesticide applied by year, based on application rate, area in corn

FracLoss Fraction of pesticide lost to runoff by year: ratio of annual mass runoff loss to amount applied