Technical Memorandum 

TO: Brenda Shine, Environmental Engineer 

Refining and Chemicals Group, SPPD (E143-01) 

 

FROM: Eric Goehl, Environmental Protection Specialist 

Refining and Chemicals Group, SPPD (E143-01)

DATE: October 16, 2012

SUBJECT: Summary of Fluid Catalytic Cracking Unit Emission Source Test Reports

I. Purpose 

 The objective of this document is to provide a summary of the Fluid Catalytic Cracking 

Unit (FCCU) emission source test reports received by the EPA from the 2011 Information 

Collection Request (ICR) of the Petroleum Refinery industry. 

II. Background 

On April 1, 2011, the EPA sent an ICR to facilities in the U.S. petroleum refining 

industry. The ICR was comprehensive and designed to collect information on processing 

characteristics, crude slate characteristics, emissions inventories and source testing to bolster our 

current data and fill known data gaps. The ICR had four components: (1) a questionnaire on 

processes and controls to be completed by all petroleum refineries (Component 1); (2) an 

emissions inventory to be developed by all petroleum refineries using the emissions estimation 

protocol developed for this effort (Component 2); (3) distillation feed sampling and analysis to 

be conducted by all petroleum refineries (Component 3); and (4) emissions source testing to be 

completed in accordance with an EPA-approved protocol for specific sources at specific 

petroleum refineries (Component 4). 

Component 4 of the ICR required source testing for twelve different types of emission 

sources or units: fluid catalytic cracking units (FCCU), thermal catalytic cracking units, catalytic 

reforming units, sulfur recovery units, delayed coking units, fluid coking units, hydrocracking 

units, hydrogen plants, asphalt blowing units, fuel gas systems, cooling water systems, and 

wastewater treatment systems. This memorandum summarizes the results of the FCCU sources 

tests. A similar memorandum is available for the other sources required to be tested as a result of 
this ICR. Facilities often claimed specific process information as CBI, and included that 

information in the CBI version of the emission source test report stored in the EPA’s CBI office 

in Research Triangle Park, NC. However, emissions data cannot be claimed as CBI. This 

memorandum summarizes and presents only non-CBI data. 

III. Source-specific Testing Program

Below is a list of the ten facilities required to perform an emission source test on 

their FCCU. 

• Marathon Oil – Robinson, IL (IL2A0420) 

• Flint Hills – Rosemount, MN (MN2B0720) 

• Motiva – Norco, LA (LA3C0630) 

• Citgo – Lake Charles, LA (LA3C0560) 

• Hovensa – St. Croix, USVI (VI6A1530) 

• Valero – Port Arthur, TX (TX3B1250) 

• Chevron – Barbers Point, HI (HI5A0380) 

• BP – Whiting, IN (IN2A0440) 

• ExxonMobil – Torrance, CA (CA5A0190) 

• Sunoco – Philadelphia, PA (PA1A1030) 

Owners or operators of the FCCU at these facilities were required to test for: 

• Speciated volatile organic hazardous air pollutants (HAP) 

• Speciated semi-volatile organic HAP 

• Total hydrocarbons, methane, and ethane 

• Aldehydes 

• Carbon monoxide 

• Dioxins, furans, and polychlorinated biphenyls 

• Hydrogen chloride, chlorine, hydrogen fluoride, and hydrogen cyanide 

• Mercury (speciated) 

• Hexavalent chromium and multiple metals 

• Particulate matter (PM, PM2.5 filterable, and PM condensable) and ammonia 

• NOX, SO2, O2, CO2, moisture, and gas flow rate. 

2 
3 

The EPA required that the data collected from the emission source testing to be reported 

using the EPA Electronic Reporting Tool (ERT). The ERT is a Microsoft® Access database 

application. If the facility conducted testing using a method not currently supported by the ERT, 

the facility was required to report the results in the Refinery Testing Supplement, a Microsoft® 

Excel spreadsheet. After completing the Refinery Testing Supplement, the refineries were also to 

submit an electronic copy of the emission test report, preferably in PDF format. 

IV. Results 

A summary of the emission results for the FCCU are provided in attached spreadsheet. In 

order to better characterize the reported data from the emission test reports, detection level 

information was provided in the attached summary spreadsheet. The following designations were 

used to describe the detection levels of the reported emissions data. 

• DLL = Detection Level Limited = 1 or 2 runs below detection limit 

• BDL = Below Detection Limit = All three runs are below detection limit 

• No designation = All three runs are above detection limit 

While reviewing the reported FCCU test data for Motiva in Norco, LA, we found 

conflicting data between the Refinery Testing Supplement and the PDF emission test report. A 

phone call to the facility clarified that the information contained in the PDF emission test report 

reflected the correct data. 

 
Summary of FCCU Test Report Data

75-07-0 Acetaldehyde 8.00E-02 8.40E-01 BDL 1.90E-01 3.62E-03 2.52E-02 4.04E-01 3.31E-03 DLL 6.27E-04 BDL 6.80E-04 BDL 1.70E-01

50-00-0 Formaldehyde 1.34E+00 2.10E-01 DLL 4.70E-02 2.05E-03 DLL 1.55E-01 BDL 5.99E-02 1.08E-02 5.91E-03 BDL 2.00E-02

74-90-8 Hydrogen cyanide 1.20E+01 4.60E-01 BDL 7.00E-01 2.07E+00 1.05E+02 4.20E+01 BDL 0.00E+00 3.22E+01 3.33E+00 5.36E+00

Propanal 3.70E-01 BDL 2.50E-01 2.83E-03 1.10E-03 DLL 4.39E-02 0.00E+00 6.73E-04 BDL 1.80E-01

7647-01-0 Hydrogen Chloride 1.01E+00 3.55E-01 2.36E-01 3.12E-02 9.90E-01 BDL 7.20E-02 DLL 7.78E-01 1.96E-01 5.75E-02

7782-50-5 Chlorine BDL 2.00E-02 5.20E-02 BDL 1.70E-03 BDL 1.00E-02 BDL 3.57E-02 BDL 0.00E+00 1.30E+00 BDL 2.90E-03

7782-41-4 Hydrogen Fluoride BDL 2.00E-02 1.40E-02 3.63E-02 BDL 2.02E-03 BDL 3.00E-02 BDL 9.85E-03 BDL 0.00E+00 BDL 2.60E-02 1.49E-02

67-64-1 Acetone 1.68E+00 3.79E+00 BDL 8.20E-04 2.86E+00 BDL 1.57E+00 8.85E+01 DLL 4.89E-01 7.00E-01 BDL 4.10E-01

750-05-8 Acetonitrile 3.70E-01 BDL 1.20E-01 BDL 1.88E-03 BDL 2.85E-01 BDL 1.93E+00 DLL 3.62E-01 BDL 6.06E-01 BDL 2.80E-01 data rejected

107-02-8 Acrolein BDL 2.30E-01 BDL 1.20E-01 BDL 6.77E-04 BDL 2.85E-01 DLL 1.60E-01 BDL 0.00E+00 BDL 2.59E-01 BDL 4.13E-01 BDL 5.40E-01

107-13-1 Acrylonitrile BDL 2.30E-01 BDL 1.19E-01 BDL 7.34E-04 BDL 2.85E-01 BDL 1.38E+00 DLL 1.92E-01 BDL 2.55E-01 BDL 2.30E-01 BDL 1.10E-02

71-43-2 Benzene BDL 2.30E-01 BDL 1.22E-01 BDL 6.60E-04 BDL 2.85E-01 BDL 4.39E-01 BDL 1.49E-01 2.40E-01 BDL 2.32E-01 BDL 4.93E-01 BDL 5.10E-01

106-99-0 1,3-Butadiene BDL 2.40E-01 BDL 1.22E-01 BDL 5.79E-04 BDL 2.85E-01 BDL 8.57E-01 BDL 7.50E-01 BDL 0.00E+00 BDL 2.66E-01 BDL 4.00E-01 BDL 6.20E-01

75-15-0 Carbon Disulfide BDL 2.30E-01 BDL 1.19E-01 BDL 4.60E-04 BDL 2.85E-01 BDL 1.49E-01 DDL 1.29E+00 DLL 1.28E-01 BDL 1.73E-01 BDL 1.40E-01

108-90-7 Chlorobenzene BDL 2.30E-01 BDL 1.22E-01 BDL 5.80E-03 BDL 2.85E-01 BDL 8.63E-01 BDL 1.49E-01 BDL 0.00E+00 BDL 7.00E-03 BDL 6.53E-02 BDL 1.10E-02

98-82-8 Cumene (Isopropylbenzene) BDL 2.30E-01 BDL 1.22E-01 BDL 4.36E-03 BDL 2.85E-01 BDL 1.84E+00 BDL 1.49E-01 BDL 0.00E+00 BDL 5.00E-03 BDL 4.73E-02 BDL 1.10E-02

106-93-4 1,2-Dibromoethane BDL 2.30E-01 DLL 1.42E-01 BDL 1.41E-03 BDL 2.85E-01 BDL 4.00E+00 BDL 1.49E-01 BDL 3.17E-01 BDL 1.27E+00 BDL 1.30E+00

100-41-4 Ethylbenzene BDL 2.30E-01 BDL 1.22E-01 BDL 4.45E-03 BDL 2.85E-01 BDL 5.43E-01 BDL 1.49E-01 BDL 0.00E+00 BDL 6.00E-03 BDL 4.83E-02 BDL 1.10E-02

110-54-3 Hexane BDL 2.30E-01 BDL 1.19E-01 BDL 6.60E-04 BDL 2.85E-01 BDL 2.20E+00 BDL 1.49E-01 BDL 0.00E+00 BDL 2.15E-01 DLL 5.80E-01 BDL 4.40E-01

108-10-1 Methyl iso-Butyl Ketone BDL 2.30E-01 BDL 1.23E-01 BDL 2.85E-01 BDL 1.43E+00 BDL 1.44E-01 BDL 0.00E+00 BDL 5.00E-03 BDL 5.00E-02 BDL 8.90E-03

1634-04-4 Methyl t-Butyl Ether (MTBE) BDL 2.30E-01 BDL 1.19E-01 BDL 2.85E-01 BDL 1.36E+00 BDL 1.49E-01 BDL 5.00E-03 BDL 4.73E-02 BDL 7.80E-03

75-09-2 Methylene Chloride BDL 2.30E-01 BDL 1.20E-01 BDL 2.68E-03 3.64E-01 BDL 2.61E+00 1.43E+00 BDL 0.00E+00 DLL 8.97E-01 DLL 2.51E+00 BDL 1.30E+00

98-95-3 Nitrobenzene BDL 1.17E+00 BDL 6.30E-01 BDL 6.96E-03 BDL 1.42E+00 BDL 7.46E-01 7.00E-03 BDL 7.20E-02 BDL 1.30E-02

79-46-9 2-Nitropropane BDL 2.30E-01 BDL 1.22E-01 BDL 6.05E-02 BDL 2.85E-01 BDL 3.19E+00 BDL 1.49E-01 DLL 8.00E-03 BDL 4.40E-01 BDL 1.10E-02

109-66-0 Pentane BDL 2.30E-01 BDL 1.22E-01 BDL 6.63E-04 BDL 2.85E-01 BDL 1.84E+00 BDL 7.76E-01 BDL 2.14E-01 BDL 4.90E-01 BDL 7.90E-01

100-42-5 Styrene BDL 2.30E-01 BDL 1.22E-01 BDL 4.83E-03 BDL 2.85E-01 BDL 1.81E+00 BDL 1.49E-01 BDL 6.00E-03 BDL 5.23E-02 BDL 8.60E-02

127-18-4 Tetrachloroethene BDL 2.30E-01 BDL 1.22E-01 BDL 1.42E-03 BDL 2.85E-01 BDL 2.37E+00 BDL 1.49E-01 BDL 0.00E+00 BDL 2.81E-01 BDL 1.28E+00 BDL 2.30E+00

108-88-3 Toluene BDL 2.30E-01 BDL 1.23E-01 BDL 7.37E-04 BDL 2.85E-01 BDL 2.40E+00 BDL 1.50E-01 6.13E+00 DLL 2.26E-01 BDL 5.63E-01 BDL 8.60E-01

79-01-6 Trichloroethene BDL 2.30E-01 BDL 1.23E-01 BDL 1.34E-03 BDL 2.85E-01 BDL 6.71E-01 BDL 1.50E-01 BDL 3.48E-01 BDL 1.21E+00 BDL 7.60E-01

540-84-1 2,2,4-Trimethylpentane BDL 2.30E-01 BDL 1.22E-01 BDL 2.85E-01 BDL 2.04E+00 BDL 1.49E-01 BDL 4.00E-03 BDL 4.10E-02 BDL 7.00E-03

1330-20-7 Xylene BDL 1.22E-01 BDL 5.43E-01 BDL 1.49E-01 BDL 0.00E+00 BDL 1.10E-02 BDL 9.60E-02

o-Xylene BDL 2.30E-01 BDL 4.52E-03 BDL 2.85E-01 BDL 0.00E+00 BDL 1.00E-02

m&p-Xylenes BDL 2.30E-01 BDL 4.40E-03 BDL 2.85E-01 BDL 0.00E+00 BDL 1.00E-02

Total VOC as propane BDL 5.24E+01

1.93E-08

83-32-9 Acenaphthene BDL 1.92E-06 1.35E-05 BDL 1.48E-05 BDL 7.48E-06 BDL 1.18E-04 DLL 1.11E-04 BDL 1.06E-04 BDL 1.60E-05 BDL 2.10E-06

209-96-8 Acenaphthylene DLL 8.95E-06 8.03E-06 BDL 1.49E-05 9.31E-06 BDL 1.12E-04 BDL 1.42E-04 BDL 3.37E-05 BDL 1.60E-05 BDL 2.10E-06

62-53-3 Aniline BDL 3.60E-04 BDL 3.07E-04 BDL 1.03E-03 BDL 2.13E-04 4.78E-01 BDL 2.89E-07 BDL 5.09E-04 BDL 5.70E-03 BDL 5.20E-04

120-12-7 Anthracene 1.72E-06 1.67E-06 BDL 1.49E-05 3.73E-06 7.57E-04 DLL 2.28E-05 BDL 3.37E-05 DLL 1.60E-05 BDL 2.10E-06

92-87-5 Benzidine BDL 7.40E-03 BDL 6.31E-03 BDL 3.39E-02 BDL 4.49E-03 BDL 1.28E+00 BDL 5.94E-06 BDL 5.21E-05 BDL 1.90E-01 data rejected

56-55-3 Benzo(a)Anthracene BDL 7.79E-07 BDL 9.60E-07 BDL 6.82E-07 9.40E-04 BDL 8.78E-07 BDL 1.51E-04 DLL 1.60E-05 BDL 2.10E-06

205-99-2 Benzo(b)Fluoranthene BDL 7.79E-07 BDL 1.38E-06 BDL 1.48E-05 BDL 4.26E-06 BDL 1.12E-04 BDL 6.75E-07 BDL 2.76E-05 DLL 1.60E-05 BDL 2.10E-06

207-08-9 Benzo(k)Fluoranthene BDL 7.79E-07 BDL 1.00E-06 BDL 1.48E-05 DLL 6.98E-07 BDL 1.12E-04 BDL 6.26E-07 BDL 4.14E-05 DLL 1.60E-05 BDL 2.10E-06

191-24-2 Benzo(ghi)Perylene 1.52E-06 BDL 6.60E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 1.12E-04 DLL 3.04E-06 BDL 1.00E-04 BDL 1.60E-05 BDL 2.10E-06

50-32-8 Benzo(a)Pyrene BDL 7.79E-07 BDL 6.60E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 8.05E-06 BDL 9.35E-05 DLL 1.60E-05 BDL 2.10E-06

192-97-2 Benzo(e)Pyrene BDL 7.79E-07 BDL 2.16E-06 BDL 1.48E-05 BDL 1.62E-06 BDL 1.12E-04 DLL 1.31E-05 BDL 3.07E-05 DLL 1.60E-05 BDL 2.10E-06

92-52-4 Biphenyl 2.18E-04 1.16E-03 BDL 1.48E-05 3.00E-04 BDL 5.62E-02 BDL 9.08E-05 BDL 3.07E-05 BDL 8.20E-03 BDL 2.10E-04

1319-77-3 Cresols BDL 1.29E-03 6.49E+00 1.80E-02 DLL 1.00E-02

218-01-9 Chrysene* 1.70E-06 2.93E-06 BDL 1.48E-05 1.21E-05 8.80E-04 BDL 1.31E-06 BDL 1.07E-04 DLL 1.60E-05 BDL 2.10E-06

53-70-3 Dibenzo(a,h)Anthracene* BDL 7.79E-07 BDL 7.70E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 7.29E-07 BDL 9.12E-05 BDL 1.60E-05 BDL 2.10E-06

132-64-9 Dibenzofuran BDL 4.48E-04 BDL 3.82E-04 BDL 1.02E-03 3.69E-04 BDL 3.87E-02 BDL 3.60E-07 BDL 7.74E-05 BDL 5.60E-03 BDL 1.40E-04

192-65-4 Dibenzo(a,e)pyrene BDL 6.60E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 2.25E-04 BDL 6.26E-07 BDL 8.20E-05 BDL 2.10E-06

119-90-4 3,3'-Dimethoxybenzidine BDL 5.65E-03 BDL 4.82E-03 BDL 1.48E-03 BDL 3.43E-03 BDL 1.12E+00 BDL 4.54E-06 BDL 3.07E-05 BDL 8.20E-03 data rejected

60-11-7 Dimethylaminobenzene BDL 3.90E-04 BDL 3.32E-05 BDL 1.48E-03 BDL 2.37E-04 BDL 3.55E-02 BDL 3.13E-07 BDL 3.07E-05 BDL 8.20E-03 BDL 2.10E-04

57-97-6 7,12-Dimethybenz(a)anthracene BDL 6.60E-07 BDL 5.09E-03 BDL 4.73E-07 BDL 2.25E-04 BDL 6.26E-07 BDL 3.07E-05 BDL 3.30E-05 BDL 2.10E-06

119-93-7 3,3'-Dimethylbenzidine BDL 5.65E-03 BDL 4.82E-03 BDL 1.60E-02 BDL 3.43E-03 BDL 6.06E-01 BDL 4.54E-06 BDL 3.07E-05 BDL 8.80E-02 data rejected

122-09-8 a,a-Dimethylphenethylamine BDL 2.34E-03 BDL 1.99E-03 BDL 1.48E-03 BDL 1.42E-03 BDL 2.81E-01 BDL 1.88E-06 BDL 3.07E-05 BDL 8.20E-03 data rejected

105-67-9 2,4-Dimethylphenol BDL 5.07E-04 BDL 4.32E-04 BDL 1.08E-03 BDL 3.08E-04 4.29E-01 BDL 4.07E-07 DLL 8.45E-04 BDL 5.90E-03 BDL 1.50E-04

206-44-0 Fluoranthene 6.72E-06 1.00E-05 3.82E-05 4.89E-05 1.58E-03 9.79E-06 BDL 3.07E-05 3.60E-05 BDL 2.10E-06

86-73-7 Fluorene DLL 4.87E-06 1.75E-05 DLL 1.78E-05 BDL 3.51E-05 BDL 1.12E-04 DLL 4.98E-05 BDL 3.99E-05 DLL 1.60E-05 3.41E-06

193-39-5 Indeno(1,2,3-cd)Pyrene BDL 7.79E-07 BDL 9.40E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 5.58E-06 BDL 9.66E-05 DLL 1.60E-05 BDL 2.10E-06

78-59-1 Isophorone BDL 4.38E-04 BDL 3.74E-04 BDL 1.11E-03 BDL 2.60E-04 BDL 4.20E-02 BDL 3.52E-07 BDL 2.22E-05 BDL 6.10E-03 BDL 1.60E-04

56-49-5 3-Methylcholanthrene BDL 6.64E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 2.25E-04 BDL 6.26E-07 BDL 3.07E-05 BDL 8.20E-05 BDL 2.10E-06

91-57-6 2-Methylnaphthalene 6.16E-05 5.89E-04 3.23E-05 2.44E-05 BDL 1.20E-04 7.41E-05 BDL 5.06E-05 3.40E-05 6.98E-06

95-48-7 2-Methylphenol BDL 4.09E-04 BDL 2.48E-04 DLL 4.26E-06 BDL 1.40E-04

106-44-5/108 4-Methylphenol & 3-Methylphenol BDL 1.10E-03 BDL 6.62E-04 BDL 1.27E-06 BDL 1.20E-04

91-20-3 Naphthalene 1.62E-04 3.22E-04 3.24E-04 7.93E-03 2.52E-04 2.80E-04 BDL 1.33E-04 5.90E-04 9.98E-05

198-55-0 Perylene BDL 7.79E-07 BDL 6.64E-07 BDL 1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 6.21E-07 BDL 3.07E-05 DLL 1.60E-05 BDL 2.10E-06

85-01-8 Phenanthrene 4.23E-05 5.11E-05 BDL 3.62E-05 3.05E-04 2.33E-03 6.31E-05 BDL 1.21E-04 2.70E-05 2.53E-06

108-95-2 Phenol BDL 1.26E-03 1.46E-03 BDL 5.79E-03 BDL 2.04E-03 6.07E+00 1.21E-06 DLL 1.31E-02 DLL 5.30E-03 1.12E-03

106-50-3 1,4-Phenylenediamine BDL 3.51E-03 BDL 2.99E-03 BDL 1.48E-03 BDL 2.13E-03 BDL 2.81E-01 BDL 2.82E-06 BDL 2.98E-05 BDL 8.20E-03 data rejected

SVOC

lb/hr DL lb/hr DL lb/hr DL lb/hr DL

VOLATILE ORGANIC HAP

CAS # Compound lb/hr DL lb/hr DL

IL2A0420 - 

Marathon 

Robinson, IL 

VI6A1530 - Hovensa 

Christiansted, USVI 

MN2B0720 - Flint 

Hills Rosemount, 

MN

HI5A0380 - Chevron 

Kapolei, HI

DL lb/hr

Detection 

Level (DL) lb/hr DL lb/hr DL lb/hr

TX3B1250 - Valero 

Port Arthur, TX 

PA1A1030 - 

Sunoco 

Philadelphia, PA 

LA3C0560 - Citgo 

Lake Charles, LA

CA5A0190 - ExxonMobil 

Torrance CA

IN2A0440 - BP 

Whiting, IN

LA3C0630 - 

Motiva Norco LA 
Summary of FCCU Test Report Data

CAS # Compound lb/hr DL lb/hr DL lb/hr DL lb/hr DL lb/hr DL lb/hr DL

IL2A0420 - 

Marathon 

Robinson, IL 

VI6A1530 - Hovensa 

Christiansted, USVI 

MN2B0720 - Flint 

Hills Rosemount, 

MN

HI5A0380 - Chevron 

Kapolei, HI

DL lb/hr

Detection 

Level (DL) lb/hr DL lb/hr DL lb/hr

TX3B1250 - Valero 

Port Arthur, TX 

PA1A1030 - 

Sunoco 

Philadelphia, PA 

LA3C0560 - Citgo 

Lake Charles, LA

CA5A0190 - ExxonMobil 

Torrance CA

IN2A0440 - BP 

Whiting, IN

LA3C0630 - 

Motiva Norco LA 

129-00-0 Pyrene 6.83E-06 1.06E-05 8.65E-05 BDL 2.49E-05 4.87E-03 DLL 2.26E-06 BDL 3.68E-05 7.30E-05 BDL 2.10E-06

95-53-4 o-Toluidine BDL 9.74E-04 BDL 8.31E-04 BDL 1.48E-03 BDL 5.91E-04 BDL 1.10E-01 BDL 7.82E-07 BDL 3.07E-05 BDL 8.20E-03 BDL 2.10E-04

Total PAHs BDL 8.72E-03

7400-36-0 Antimony BDL 2.86E-04 3.12E-04 DLL 3.47E-03 BDL 2.21E-03 2.00E-03 BDL 3.59E-05 BDL 3.43E-04 8.44E-05

7440-38-2 Arsenic BDL 2.45E-04 BDL 2.10E-04 BDL 3.31E-04 BDL 1.94E-04 2.00E-04 BDL 1.44E-04 BDL 5.44E-04 DLL 6.80E-04

7440-41-7 Beryllium BDL 2.45E-04 BDL 5.26E-05 BDL 8.28E-05 BDL 4.46E-05 BDL 1.00E-05 BDL 3.59E-05 DLL 3.91E-06 DLL 5.00E-06

7440-43-9 Cadmium BDL 2.45E-04 1.19E-03 BDL 8.30E-05 BDL 2.68E-05 2.00E-04 8.35E-04 DLL 5.37E-05 DLL 4.40E-06

7440-47-3 Chromium 1.09E-03 2.44E-03 7.30E-04 BDL 1.29E-03 1.40E-03 4.21E-04 DLL 1.11E-03 4.07E-04

7439-92-1 Lead DLL 4.64E-04 3.11E-03 BDL 1.66E-04 1.15E-03 1.90E-03 2.16E-04 DLL 6.27E-04 1.50E-04

7439-96-5 Manganese 7.54E-04 9.46E-04 3.84E-03 2.40E-03 6.30E-03 6.71E-04 7.70E-04 9.88E-04

7440-02-0 Nickel DLL 6.08E-04 3.33E-03 1.14E-02 4.61E-03 5.30E-03 1.11E-03 2.18E-03 1.63E-02

7782-22-4 Selenium DLL 9.66E-04 BDL 5.26E-04 DLL 1.02E-03 BDL 7.29E-04 1.40E-03 BDL 3.59E-04 DLL 9.53E-04 DLL 3.80E-04

7440-48-4 Cobalt 3.39E-04 8.11E-04 BDL 2.06E-04 1.00E-03 5.82E-05 BDL 1.69E-04 1.08E-03

18540-29-9 Hexavalent Chromium BDL 1.13E-04 BDL 8.00E-03 1.64E-03 BDL 8.14E-05 DLL 9.00E-04 BDL 3.24E-04 1.74E-04 BDL 2.04E-04 DLL 4.03E-05 -

Oxidized/organic Mercury BDL 2.72E-04 6.78E-05 BDL 1.20E-05 DLL 7.24E-05 2.92E-05 1.90E-05 DLL 1.54E-06 DLL 1.50E-05

Total Mercury BDL 8.51E-04 BDL 1.98E-04 DLL 3.87E-05 BDL 1.91E-04 BDL 1.81E-04

7439-97-6 Elemental Mercury BDL 5.71E-04 BDL 1.19E-04 2.42E-05 1.04E-04 2.55E-04 BDL 1.52E-04 7.09E-04 DLL 3.86E-05 DLL 2.73E-05 DLL 3.00E-05

7664-41-7 Ammonia 5.49E+00 4.50E-01 DLL 2.70E-01 7.23E-01 9.85E+00 5.22E-01 BDL 0.00E+00 6.39E-01 5.50E+00 1.20E-01

630-08-0 Carbon Monoxide 7.86E+01 3.23E+00 3.73E+01 3.22E+00 2.36E+01 2.11E+01 1.26E+01

7782-50-5 Chlorine 5.20E-02 BDL 1.73E-03

67-56-1 Methanol BDL 5.87E-01 4.86E+01 7.67E+00 1.80E-01 5.49E-01 DLL 5.86E-01 DLL 1.33E+00 BDL 2.80E-02

74-82-8 Methane 3.45E+01 BDL 7.00E-02 BDL 1.10E-01 8.00E-01 4.10E-01 4.73E-01 2.49E+00 7.77E-01 3.50E-01 BDL 8.15E-02

74-84-0 Ethane 1.21E+01 BDL 8.00E-02 BDL 2.60E-01 BDL 1.00E-01 7.68E-01 BDL 8.05E-01 1.26E+01 1.25E+00 BDL 3.40E-01 BDL 4.70E-01

75-69-4 Trichlorofluoromethane

74-83-9 Bromomethane

10102-43-9 Nitrogen Oxides 2.52E+01 1.59E+02 2.16E+01 9.53E+00 1.26E+01 1.01E+01 1.67E+01

Sulfur Dioxide 2.84E+01 4.15E+01 2.84E+00 DLL 9.38E-01 2.70E+01 Reported a negative 0.01 6.80E+00

Condensible Inorganic (aqueous) PM 1.99E+01 2.05E+01 3.29E+01 1.59E+00

Condensible Organic Particulate Matter 9.10E-01 1.26E+00 1.32E+00 9.16E-02

Condensible Particulate Matter 9.49E+00 8.53E+00 2.28E+01 2.29E+00 2.61E+00

Filterable Particulate 1.26E+00 2.17E+01 2.27E+01 1.54E+01 6.22E+00 8.20E+01 4.45E+00

Filterable PM2.5 1.32E+01 2.42E+00

Total PM2.5 2.10E+01 2.27E+01 4.10E+00

Total PM 4.35E+01 3.12E+01 3.82E+01 8.51E+00 1.16E+02 4.23E+00

Total PCBs 3.10E-07 BDL 2.17E-08 BDL 6.51E-09

PCB TEQs 1.65E-10

2,3,3',4,4',5,5'-HpCB (PCB189) BDL 1.01E-09 2.73E-09 BDL 3.92E-10 BDL 6.92E-11 BDL 3.38E-10 BDL 3.00E-10

2,3,3',4,4',5'-HxCB (PCB157) DLL 5.42E-10 2.09E-09 DLL 2.37E-10 BDL 1.42E-10 BDL 3.54E-10 DLL 5.70E-10

2,3,3,4,4,5-HxCB (PCB156) 1.82E-09 7.50E-09 6.27E-10 BDL 1.48E-10 1.08E-08 DLL 5.70E-10

2,3,3',4,4'-PeCB (PCB105) 1.25E-08 6.14E-08 DLL 5.14E-09 DLL 6.77E-10 8.98E-08 BDL 3.57E-09

2,3',4,4',5,5'-HxCB (PCB167) DLL 8.42E-10 5.88E-09 DLL 3.26E-10 BDL 1.67E-10 2.69E-08 BDL 3.30E-10

2,3,4,4',5-PeCB (PCB114) BDL 8.62E-10 5.40E-09 BDL 4.42E-10 BDL 9.44E-11 DLL 8.30E-09 BDL 2.80E-10

2,3',4,4',5-PeCB (PCB118) 3.22E-08 1.71E-07 1.19E-08 DLL 1.78E-09 3.01E-07 1.02E-08

2',3,4,4',5-PeCB (PCB123) DLL 1.40E-09 1.68E-08 DLL 6.17E-10 BDL 1.51E-10 2.85E-07 BDL 4.70E-10

2,3,4,6,7,8-HxCDF DLL 2.19E-09 DLL 1.74E-10 BDL 6.97E-10 BDL 1.80E-10

2,3,7,8-TCDD BDL 6.79E-10 DLL 6.30E-10 BDL 3.19E-10 BDL 1.83E-10 BDL 3.82E-10 BDL 6.80E-10

2,3,7,8-TCDF 3.42E-09 BDL 4.77E-10 BDL 2.19E-10 DLL 5.44E-10 BDL 4.30E-10

3,3',4,4',5,5'-HxCB (PCB169) BDL 1.14E-09 9.42E-10 BDL 3.19E-10 BDL 2.80E-09 BDL 3.91E-10 BDL 3.40E-10

3,3',4,4',5-PeCB (PCB126) BDL 6.00E-10 3.39E-09 BDL 4.30E-10 BDL 1.67E-10 BDL 3.43E-10 BDL 3.00E-10

3,3',4,4'-TCB (PCB77) 6.71E-09 2.90E-08 DLL 5.90E-09 DLL 2.60E-10 DLL 7.39E-09 9.10E-10

3,4,4',5-TCB (PCB81) DLL 4.28E-10 3.69E-09 DLL 5.88E-10 BDL 1.06E-10 DLL 5.75E-09 BDL 3.10E-10

OCDD 4.96E-09 BDL 1.16E-09 1.45E-08 DLL 1.88E-09

OCDF BDL 1.77E-09 DLL 7.00E-09 BDL 5.58E-10 BDL 2.66E-10 DLL 2.22E-09 DLL 4.06E-09

1,2,3,6,7,8-HxCDF BDL 3.45E-10 BDL 1.44E-10 BDL 6.42E-10 DLL 2.00E-10

1,2,3,4,6,7,8-HpCDD BDL 8.65E-10 2.77E-09 BDL 3.96E-10 BDL 4.33E-10 BDL 7.12E-10 DLL 4.30E-10

2,3,4,7,8-PeCDF BDL 5.09E-10 DLL 3.39E-09 BDL 4.77E-10 DLL 3.76E-10 BDL 5.93E-10 DLL 2.20E-10

1,2,3,4,6,7,8-HpCDF DLL 5.59E-10 DLL 3.49E-09 BDL 3.24E-10 DLL 2.64E-10 1.39E-09

1,2,3,4,7,8,9-HpCDF BDL 8.58E-10 DLL 7.57E-09 BDL 3.33E-10 DLL 1.45E-10 DLL 1.14E-09 DLL 4.50E-10

1,2,3,4,7,8-HxCDD BDL 6.11E-10 DLL 4.75E-10 BDL 3.15E-10 BDL 1.71E-10 BDL 9.40E-10 BDL 3.30E-10

1,2,3,4,7,8-HxCDF 3.32E-09 BDL 2.88E-10 BDL 1.32E-10 BDL 6.93E-10 DLL 2.80E-10

1,2,3,6,7,8-HxCDD BDL 6.21E-10 DLL 8.15E-10 BDL 3.15E-10 BDL 1.69E-10 BDL 8.88E-10 DLL 4.00E-10

1,2,3,7,8,9-HxCDD BDL 6.72E-10 DLL 1.09E-09 BDL 2.88E-10 BDL 1.67E-10 BDL 9.16E-10 BDL 3.30E-10

1,2,3,7,8,9-HxCDF BDL 4.50E-10 DLL 5.37E-09 BDL 3.60E-10 BDL 1.26E-10 BDL 8.26E-10 BDL 2.10E-10

1,2,3,7,8-PeCDD BDL 7.53E-10 DLL 9.59E-10 BDL 2.88E-10 BDL 3.49E-10 BDL 6.27E-10 BDL 3.10E-10

1,2,3,7,8-PeCDF DLL 6.28E-09 BDL 2.97E-10 BDL 3.01E-10 BDL 5.80E-10 BDL 2.80E-10

Total HpCDD 4.62E-09 BDL 3.96E-10 5.17E-10 DLL 4.30E-10

METALS

PARTICULATE MATTER

TOTAL PCBs

DIOXIN AND FURANS
Summary of FCCU Test Report Data

CAS # Compound lb/hr DL lb/hr DL lb/hr DL lb/hr DL lb/hr DL lb/hr DL

IL2A0420 - 

Marathon 

Robinson, IL 

VI6A1530 - Hovensa 

Christiansted, USVI 

MN2B0720 - Flint 

Hills Rosemount, 

MN

HI5A0380 - Chevron 

Kapolei, HI

DL lb/hr

Detection 

Level (DL) lb/hr DL lb/hr DL lb/hr

TX3B1250 - Valero 

Port Arthur, TX 

PA1A1030 - 

Sunoco 

Philadelphia, PA 

LA3C0560 - Citgo 

Lake Charles, LA

CA5A0190 - ExxonMobil 

Torrance CA

IN2A0440 - BP 

Whiting, IN

LA3C0630 - 

Motiva Norco LA 

Other HpCDF DLL 4.44E-10

Total HpCDF DLL 1.41E-08 BDL 3.51E-10 DLL 3.31E-10 DLL 2.23E-09

Other HxCDD DLL 1.77E-09

Total HxCDD 5.68E-09 BDL 3.15E-10 BDL 1.71E-10 DLL 2.84E-09

Other HxCDF DLL 3.15E-10

Total HxCDF 2.50E-08 BDL 3.06E-10 DLL 3.65E-10 DLL 7.90E-10

Other PeCDD DLL 1.45E-10

Total PeCDD 7.05E-09 BDL 5.67E-10 BDL 3.49E-10 DLL 4.41E-10

Other PeCDF DLL 3.38E-10

Total PeCDF DLL 3.69E-08 BDL 5.76E-10 DLL 4.95E-10 DLL 7.90E-10

Other TCDD DLL 8.90E-12

Total TCDD 8.89E-09 BDL 2.97E-10 DLL 4.50E-10 DLL 6.90E-10

Other TCDF DLL 0.00E+00

Total TCDF 9.19E-08 BDL 8.46E-10 BDL 2.19E-10 BDL 4.30E-10

Total Dioxins and Furans DLL 2.52E-07 1.41E-08 5.80E-09

Total PCDD/F BDL 5.77E-09 2.18E-08

Total PCDD/F TEQ 3.69E-09

Total Dioxins 7.20E-09 DLL 6.29E-09

Total Furans 6.89E-09 DLL 8.29E-09

Total Hydrocarbon 1.01E+02 7.61E-01 3.19E+00