# SANITIZED 1111111111111111111111111111111111111111111111111111111 

# IY}

# R

# 3~~;tfo fuBMISSION PMN2010P1 

## PMN Page 1

U.S. ENVIRONMENTAL PROTECTION AGENCY AGENCY USE ONLY PREMANUFACTURE NOTICE FOR NEW CHEMICAL SUBSTANCES



## 74126417045 OffIce of Pollution and Toxlcs Document Control OffIce 17407MI US EPA, 1200 Pennsylvania Ave NW WASHINGTON, D.C, 204eO 

## Number



## X78T84
i you donot have • Before you complete this form. you should read the "Instructions Manual for Premanutacture Notification" (the Instructions Manual is available from the Toxic Substances Control Act (TSCA) Information Service by calling 202-554-1404, or faxing 202-554-5603). • Ifa userfee has been remittedforthis notice (40 CFR 700.45), indicate in the boxes above the TS-user fee identification number you have generated. Remember. your userfee ID number

must also appearon your corresponding fee remittance For mailing address information see the Help instructions in the e"PMN tool. • You must provide all information requested in this form to the extentthat it is known to or reasonably ascertainable by you. Make

Part 1- GENERAL INFORMATION You must provide the**curren~y** correct Chemical Abstracts (CA) Name of the new chemical substance, even ifyou claim the identity as confidential. You may authorize anotherperson to submit chemical identity information foryou, but your submission will not be complete and the review will not begin until EPA receives this information. A letter in support ofyour submission should reference yourTS userfee identification number. Forall Section 5 Notice submissions (paperorelectronic) you must submit an original notice including all test data; ifyou claimed any information asconfidential, an original sanitized copy must also be submitted. Part 11- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Ifthere areseveral manufacture, processing, or use operations to be described in Part II, sections A and B ofthis notice, reproduce the sections as needed. Part 111- LIST OF ATTACHMENTS For papersubmissions, attach additional sheets ifthere is not enough space to answer a question fully. Label each continuation sheet with the corresponding section heading. I n Part III, list these attachments, any test data orotherdata and any optional information included in the notice. OPTIONAL INFORMATION You may include any information thatyou want EPAto consider in evaluating the newsubstance. On page 11 ofthis form, space has been provided foryou to describe pollution prevention and recycling information you may have regarding the new substance. "Binding" boxes are included throughout this form foryou to indicate yourwillingness to be bound to certain statements you make in this section, such as use, production volume, protective equipment

... The intention is to reduce delaysthat routinely accompanythe development ofconsent orders or Significant New Use Rules. Checking a "binding" box in a PMN does not by itself prohibit the submitterfrom later deviating from the information (except chemical identity) reported in the form; however, in the case ofexemption applications (such as TMEA, LVE, LOREX) certain information provided in such notifications is binding on the submitterwhen the Agency approves the exemption application, especially ifthe production volume "binding" box is chosen in a LVE. CONFIDENTIALITY CLAIMS You may claim any information in this notice as confidential. To assert a claim on theform, marK (X) the confidential box nextto the information thatyou claim as confidential. To assert a claim in an attachment, circle or bracketthe information you claim as confidential. Ifyou claim information in the notices as confidential you mustalso provide a sanitized version ofthe notice !including attachments). Foradditional instructions on claiming information as confidential, read the Instructions Manual. TEST DATAAND OTHER DATA 

# P-10·4521

# ·453
You are required to submit all test data in your possession or control and to provide a description ofall other data known to or reasonably ascertainable by you, ifthese data are related to the health and environmental effects on the manufacture, processing, distribution in commerce, use, ordisposal ofthe new chemical substance. Standard literabure citations may be submittedfordata in the open SCientific literature. Completetest data (written in English), notsummaries ofdata must be submitted ifthey do notappear in the open literature. You should clearly identifywhethertest data is on the substance oron an analog. Also. the chemical composition ofthetested material should becharacterized. Following are examples oftest data and otherdata. Data should be submitted according to the requirements of §720.50 ofthe Premanufacture Notification Rule (40 CFR Part 720).
Test Data (Check Below any included inthis notice) Environmental fate data Other Data 

# D D

Health effects data Risk Assessments 

# D D

Environmental effects data Structure/activity relationships 

# D D 

# o Physical/Chemical Properties (A physical and chemical propertiesworKsheet is located on the last page ofthis form.) 

# D Test data not in the possession orcontrol ofthe submitter
TYPE OF NOTICE (Check Only One) 

# o PMN (Premanufacture Notice) 

# D SNUN (Significant New Use Notice) 

# D TMEA (Test MarKeting Exemption Application) 

# D LVE (LowVolume Exemption) @ 40 CFR 723.50(c)(1) 

# D LOREX (Low Release/Low Exposure Exemption) @ 40 CFR 723.50(c)(2) LVE Modification LOREX Modification Mock Submission 

# D Mark (X) ifpending Letter ofSupport IS THIS A CONSOLIDATED PMN (Y/N)? X # of chemicals or polymers (Prenotice Communication # required, enter# on 

### 2 p.3). Mark (X) if any information in this notice is claimed as confidential. EPA FORM 7710"25 (Rev. 6-09) Replaces previous editions ofEPA Form 7710-25 Page 1 

# P10-452 

# -453

## 11I111I11I1I11 111111111111111111 SANITIZED SUBMISSION PMN2010P2 

## PMN Page 2 The public reporting and recordkeeping burden for this collection of information is estimated to average 93 hours per response. Send comments on the Agency's need for this information, the accuracy ofthe provided burden estimates, and any suggested methods for minimizing respondent burden, including through the use ofautomated collection techniques to the Director, Collection Strategies Division, U.S. Environmental Protection Agency (2822T). 1200 Pennsylvania Ave.• NW, Washington, D.C. 20460. Include the OMB control number in any correspondence. Do notsend the completed EPA Form 7710-25to this address.

. 

## CERTIFICATION
-- A printed copy ofthis signature page, with original signature, must be submitteCl with CD or paper submission. I certify that to the best ofmy knowledge and belief: 1. The company named in Part I, section A, subsection 1 a ofthis notice form intendsto

manufacture, import or process fora commercial purpose, otherthan in small quantities solely for research and development, the SUbstance identified in Part I, Section B. 2. All information provided in this notice is complete and truthful as ofthe date ofsubmission. 3. I am submitting with this notice all test data in my possession orcontrol and a description of all

other data known to or reasonably ascertainable by me as required by §720.50 ofthe Premanufacture Notification Rule. Additional Certification Statements: Ifyou are submitting a PMN, Intermediate PMN, Consolidated PMN, or SNUN, check the following userfee certification statementthat applies:
The Company named in Part I, Section A has remitted the fee of$2500 specified in 40 CFR 700.45(b), or The Company named in Part I, Section A has remitted the fee of$1000for an Intermediate PMN (defined @ 40 CFR 700.43) in 

# D accordance with 40 CFR 700.45(b). or The Company named in Part I SectionA is a small business concem under 40 CFR 700.43 and has remitted a fee of$100 in 

# D accordance with 40 CFR 700.45(b). 

### Ifyou are submitting a LowVolume Exemption (LVE) application in accordancewith 40 CFR723.50{c)(1) ora Low Release and Low Exposure Exemption (LoRex) application in accordancewith 40 CFR 723.50{c){2), check thefollowing certification statements:
The manufacturer submitting this notice intends to manufacture or importthe newchemical substance for commercial purposes. 

# D otherthan in small quantities solely for research and development, underthe terms of40 CFR 723.50. 

# D The manufacturer is familiarwith the terms ofthis section and will complywith those terms; and 

# D The newchemical substance for which the notice is submitted meets all applicable exemption conditions. 

# D Ifthis application is for an LVE in accordance with 40 CFR 723.50(c)(1), the manufacturer intends to commence manufacture of the exempted substance for commercial purposes within 1yearofthe date ofthe expiration ofthe 30 day review period. 

### The accuracy ofthe statements you make in this notice should reflect your best prediction ofthe anticipated facts regarding the chemical substance described herein. Any knowing and willful misrepresentation is subjectto criminal penalty pursuantto 18 USC 1001. Signature and title of Authorized Official (Original Signature Required) Date 

# 15 "]v\ 2010 Confidential 

# D

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 2SANITIZED SUBMISSION 11111111111111111111111111111111 11111111111 PMN2010P3 

## PMN 

## Page 3**m::l:~.!.'.I~I;:(.]:~,** 

## SeCtiorA**~IFICATION** Mark (X) theL I' box nexttoany**~"h~o** ...I;')n you claim as "VllIlVCIIlIa, 

### 1a. Person**Submittin'~** 

### Notice (in J.S.l Cv, 'VC, '''''' Name ofAuthorized Official (first) David (last) Hay Position Ronlll:>tory Compliance Director Company Huntsman CorporClllur 

# D Mailing Address (number & street) 8600 Gosling Road City The Woodlands 

## I State TX 

## I Postal Code 77381 email david hay@huntsman.com 

### b Agent (ifApplicable) Gv,",vc,"ia, Name ofAuthorized Official (first) (last) Position Company 

# D Mailing Address (number & street) City 

# I State 

# I Postal Code e-mail

# ~~~I~d'~'~~ea code) C, 

### JointSubmmer (ifann1il'"!lIhle: CU"IIU""lI'" Ifyou are submitting this notice as part ofajoint submission, mark (X) 

## I 

# [ ] Name ofAuthorized Official (first) (last) Position Company 

# D Mailing Address (number & street) City 

### I State 

### I Postal Code e-mail Telephone (include area code) 

### 2 

### Technical Contact (in U.S.) L;orlllu"ntiai Name ofAuthorized Official (first) David (last) Hay Position Regulatory Compliance Director Company Huntsman Corporation 

# D Mailing Address (number & street) 8600 Gosling Road City The Woodlands 

# I State TX 

# I Postal Code 77381 e-mail david hay@huntsman.com

# ~~~~~~~~~ea code) 281-719-3026 Ifyou have had a prenotice communication (PC) concerning 5608C 

### Mark (X) if

## none GU,",uc,"ial 

## 3. this notice and EPA assigned a PC Numberto the notice, 

# D D enterthe number. Ifyou previously submitted an exemption application for the 

### Mark (X) if

## none Confiu"llua, chemical substance covered by this notice, enterthe 

## 4. exemption number assigned by EPA. Ifyou previously 

# [Xl 

# D submitted a PMN for this substance enter the PMN number**~~~;nnorl** by EPA (Le. lor i Ifyou have submitted a notice of Bona fide intent to 

### Mark (X) if

## none ConfiU""lI'" 

## 5. manufacture or import for the chemical substance covered 

# [Xl 

# D by this notice, enter the notice number assigned by EPA. 

## 6. Type of Notice

.Mark (X) Manufacture Only 

# [X] Import Only 

# D D 1. 

# D 2. 

# D 3. Both Binding Option Binding Option EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 3SANITIZED SUBMISSION

(for either Item 1 or 2), mark (X) the box at the right. Identify sheet. 1. Class 1 or 2 chemical substances (for definitions ofclass 1 and class 2 substances, see the Instructions Manual)
a. Class ofsubstance - Mark Class 1 

# o Class 2 

# o o CBI 

# o b. Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar substances. For Class 1 substances a CA Index Name must be provided. For Class 2 substances either a CA Index Name or CA 

# o Preferred Name must be which ever is a . based on current CA index nomenclature rules and N''''''''·nlir,n,,\



### Method 1 (CAS Inventory Expert Service - a copy ofthe Identification report obtained from the CAS Inventory Expert EnterAttachment filename for Part I, Section B, 1. c. 

### d. 

### e.

Enter Attachment filename for Part I, Section B, 1. e.
EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 4SANITIZED SUBMISSION 11111111111111111 PMN2010P4A 

## PMN Page 4a For a class 2 substance - (1) List the immediate precursor substances with their respective CAS Registry Numbers. (2) Describe the nature ofthe reaction or process. (3) Indicatethe range ofcomposition and the typical composition (where appropriate). Confidential

e. (1) List the immediate precursor substance nameswith their respective CAS Registry Numbers. 

# D

EnterAttachment filename for Part I. Section B. 1. e. (1) 

# I 

# [ ]
e. (2) Describe the nature ofthe reaction or process. 

# D

EnterAttachment filename for Part 

### I. Section 

### 8. 1. e. (2) 

# I [ ]
e. (3) Indicatethe range of composition and the typical composition (where appropriate). 

# D

Enter Attachment filename for Part I. Section B. 

### 1. e. (3) 

# I 

# [ ]

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 5111111111111111111111111111111111111111111111111111111I SANITIZED SUBMISSION PMN2010P5 

## PMN Page 

# 5 Part I -- GENERAL INFORMATION - Continued Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 2. Polymers (For a definition ofpolymer, see the Instructions Manual.) a. Indicate the number-average weight ofthe lowest molecularweight composition ofthe polymer you intend to manufacture. Indicate maximum weight percent of low molecularweight species (not including residual monomers, reactants, or solvents) below 500 and below 1,000 absolute molecularweight ofthat composition. Confidential 

# IX]
Describe the methods of measurement or the basis for your estimates: 

### GPC 

# D I Other (Specify Below) 

# D I Specify Other:

(i) lowest number average molecular weight: (ii) maximum weight % below 500 molecular weight: (iii) maximum weight % below 1000 molecular weight: XXX XXX XXX EnterAttachment filename for Part I, Section B, 2. a. 

# I 

# D b. You must make separate confidentiality claims for monomeror other reactant identity, composition information, and residual information. Mark (X) the "Confidential" box next to any item you claim as confidential

(1)
- Provide the specific chemical name and CAS Registry Number (if a numberexists) ofeach monomer or other reactant used in the manufacture ofthe polymer. (2)
- Mark (X) this column ifentry in column (1) is confidential. (3)
- Indicate the typical weight percent ofeach monomer or other reactant in the polymer. (4)
- Choose "yes" from drop down menu ifyou want a monomer orother reactant used at two weight percent or less to be listed as part of the polymer description on the TSCA Chemical Substance Inventory. (5)
- Mark (X) this column ifentries in columns (3) and (4) are confidential. (6)
- Indicate the maximum weight percent ofeach monomer orother reactant that may be present as a residual in the polymer as manufactured for commercial purposes. (7)
- Mark (X) this column ifentry in column (6) is confidential. Monomeror other reactant specific chemical name (1) CBI (2) Typical composition (3) Include in identity

(4) CBI (5) Max residual

(6) CBI (7) Poly[oxy(methyl-1,2-ethanediyl)], .alpha.,.alpha.'_[1 ,4-cyclohexanediylbis(methylene)]bis[.omega.-hydroxyXXX 

## X XXX 

## X

CAS Registry Number (1) 1214710-36-8 Ammonia XXX 

## X XXX 

## X

CAS Registry Number (1) 17664-41-7 Raney Nickel (Catalyst) XXX 

## X XXX 

## X

CAS Registry Number (1) 17440-02-0

CAS Registry Number (1) 1

CAS Registry Number (1) 1 Mark (X) this box ifthe data continues on the next page. 

# D
EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 6111I1111 PMN2010P5A I11I111I11111 SANITIZED SUBMISSION 

## PMN Page 5a c. Please identifywhich method you used to develop orobtain the specified chemical identity information reported in this notice 

## eBI (check one). 

### Method 1 (CAS Inventory Expert Service 150681-1 IES Order 

### Method 2 a copy ofthe identification report obtained Number 

# o (other source) from CAS Inventory Expert Service must be submitted as an attachmentto this notice) EnterAttachment filename for Part I, Section B, 2. c. 1220986-58-2.pdf 

# [ ] d. The currently correct Chemical Abstracts (CA) name for the polymerthat is consistent with TSCA Inventory listings for similar polymers. 

# o Poly[oxy(methyl-1,2-ethanediyl)], .alpha.,.alpha.'-[1 ,4-cyclohexanediylbis(methylene)]bis[.omega.-(2-aminomethylethoxy)­

CAS Registry Number (ifa numberalready existsforthe substance) 1220986-58-2 e. Provide a correct representative or partial chemical structure diagram, as complete as can be known, if one can be reasonably ascertained. 

# o See Attachment 003 (Subst 1 Structure.pdf)



### 111111111111111111111111111111111111111111111111111111111111111111111111II1 5 1 100 0 0 0 4 52! S

Enter Attachment filename for Part I, Section B, 2. e. 

# I Subst 1 Structure.pdf 

# o
EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 7SANITIZED SUBMISSION 

### 1111111111111111111111111111111111111 11111111 PMN2010P6 

## PMN Page 

# 6 Part I -- GENERAL INFORMATION -- Continued Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 3. Impurities (a)
- Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial purpose. Provide the CAS Registry Number ifavailable. Ifthere are unidentified impurities, enter "unidentified." (b)
- Estimate the maximum weight % ofeach impurity. Ifthere are unidentified impurities, estimate Iheirtotal weight %. CAS Registry Maximum Confi- Impurity (a) Number Percent % dential (a) (b)

Mark (X) this box ifthe data continues on the next page. 

# D
EnterAttachment filename for Part I, Section B, 3. 

# I 

# D 4. Synonyms
- Enter any chemical synonyms for the new chemical identified in subsection 1 or 2. 

# D

EnterAttachment filename for Part I, Section B, 4. 

# I 

# D 5. Trade identification
- List trade names for the new chemical substance identified in subsection 1 or 2. XTJ-684 Jeffamine RFD-270 

# D

EnterAttachment filename for Part I, Section B, 5. 

# I 

# D 6. Generic chemical name - Ifyou claim chemical identify as confidential, you must provide a generic name for your substance that reveals the specific chemical identity ofthe new chemical substance to the maximum extent possible. Referto the TSCA Chemical Substance Inventory, 1985 Edition, Appendix B for guidance on developing generic names.

EnterAttachment filename for Part I, Section B, 6. 

# I 7. Byproducts - Describe any byproducts resulting from the manufacture, processing, use, or disposal ofthe new chemical substance. Provide the CAS Registry Number ifavailable. Byproduct (1) CAS Registry Number Confi­ (2)' dential 1,4-Cyclohexanedimethanamine 2549-93-1 3-Azabicyclo[3.2.2]nonane 283-24-9 Water 7732-18-5

Mark (X) this box ifthe data continues on the next page. 

# D

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 8SANITIZED SUBMISSION

# 111111111111I11111111111111~11111111111~111111111

Identify 

# D Class 1 or2 chemical substances (for definitions ofclass 1 and class Class 

### 1 Class 

### 2 CBI 

### 2 substances, see the Instructions Manual) 

# D 	 D D a. Class ofsubstance - Mark b. Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar substances. For Class 

### 1 substances a CA Index Name must be provided. For Class 

### 2 substances either a CA Index Name orCA 

# D Preferred Name which ever is based on current CA index nomenclature rules and



### d. 

### e.

EnterAttachment filename for Part I, Section B, 1. e.
EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions ofEPA Form 7710-25 Page 91111111111111111111111111111111111111111111111111111111 SANITIZED SUBMISSION PMN2010P4AX1 

## PMN Page4a For a class 2 substance (1) List the immediate precursor substances with their respective CAS Registry Numbers. (2) Describe the nature ofthe reaction or process. (3) Indicate the range ofcomposition and the typical composition (where appropriate). Confidential

e. (1) Listthe immediate precursor substance names with their respective CAS Registry Numbers. 

# D

EnterAttachment filename for Part I, Section B. 1. e. (1) 

# I 

# [ 

# ]
e. (2) Describethe nature ofthe reaction or process. 

# D

EnterAttachment filename for Part I, Section B, 1. e. (2) 

# I 

# D
e. (3) Indicate the range ofcomposition and the typical composition (where appropriate). 

# D

EnterAttachment filename for Part I, Section B, 1. e. (3) 

# D

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 10SANITIZED SUBMISSION

# ~11~11111111111111111111~ PMN2010P5Xl 

## PMN Page 5

Replaces previous editions of EPA Form 7710-25 I 

## Part I -- GENERAL INFORMATION - Continued

Section B .- CHEMICAL IDENTITY INFORMATION .- Continued : 2. Polymers {For a definition of polymer, seethe Instructions Manual.} a:-Tridicatethe number-average weight ofthe lowest molecularweight composition ofthe polymeryou intend to manufacture.


### I Indicate maximum weight percent oflow molecularweight species (not including residual monomers, reactants, orsolvents) below500 and below 1,000absolute molecularweight ofthat composition. Describe the methods ofmeasurement orthe basis for your estimates: 

### GPC 

# D I Other (Specify Below) 

# D 

# I : Specify Other: 

### I Confidential

I (i) lowest numberaverage molecular weight: (ii) maximum weight 

### % below500 molecular weight: (iii) maximumweight 

### % below 1000 molecular weight:

: XXX XXX 

# xxx EnterAttachment filename for Part I, Section B. 2, a, 

# I 

# [ ] b. You must make separate confidentiality claims for monomer orother reactant identity, composition information, and residual information. Mark (X) the "Confidential" box nextto any item you claim as confidential

(1)
- Provide the specific chemical name and CAS Registry Number (ifa number exists) ofeach monomerorother reactant used in the manufacture ofthe polymer. (2) Mark (X) this column ifentry in column (1) is confidential. (3) Indicate the typicalweight percent ofeach monomeror other reactant in the polymer. (4)
- Choose "yes" from drop down menu ifyouwanta monomerorother reactant used attwoweight percent or less to be listed as part of the polymerdescription on the TSCAChemical Substance Inventory. (5)
- Mark (X) this column ifentries in columns (3) and (4) are confidential. (6)
- Indicatethe maximumweight percent ofeach monomeror other reactant that may be present as a residual in the polymer as manufactured for commercial purposes. (7)
- Mark (X) this column ifentry in column (6) is confidential. Monomer or other reactant specific chemical name (1) Poly[oxy(methyl-l,2-ethanediyl)], ,alpha.,.alpha.'-(2,2-dimethyl-l,3-propanediyl)bis[.omega.-hydroxyCAS Registry Number (1) 152479-58-0 i Ammonia

CAS Registry Number (1) 17664-41-7

Raney Nickel (Catalyst)

CAS Registry Number (1) 17440-02-0

CAS Registry Number (1) 

# I

CAS Registry Number (1) 

# I Mark (X) this box ifthe data continues on the next page. EPA FORM 7710-25 (Rev. 6-09) Typical Include in CBI composition identity CBI (2) (3) (4) (5) XXX 

### X



### I 

## ! XXX 

### X

XXX 

# I X

I

I 

# I Max residual CBI

(6) (7) XXX 

### X



## xxx X

XXX 

## X



# I

L

# J

Page 11111I1111111111 PMN201OP5AX1 11111111111111 SANITIZED SUBMISSION 

## PMNPage 

## 5a I c. Please identifywhich method you used to develop or obtain the specified chemical identity information reported in this notice : (check one). 

## eBI Method 1 (CAS Inventory Expert Service - a copy ofthe identification report obtained 

# [X] from CAS Inventory Expert Service must 

### be submitted as an attachmentto this notice) IES Order Number 150681-2 

### I Method 2 

# D

I (other source) Enter Attachment filename for Part I, Section B, 2. c. 1220986-59-3.pdf 

# [ 

# ] d. The currenUy correct Chemical Abstracts (CA) name for the polymer that is consistent with TSCA Inventory listings for similar polvmers. 

# D Poly[oxy(methyl-1,2-ethanediyl)J. .alpha.,.alpha.'-(2,2-dimethyl-1 ,3-propanediyl)bis[.omega.-(2-aminomethylethoxy)­

CAS Registry Number (ifa number already exists for the substance) 11220986-59-3 1 e. Provide a correct representative or partial chemical structure diagram, as complete as can 

### be known, ifone can be reasonably ascertained. 

# D
See Attachment 004 (Subs! 2 Structure.pdf)

Enter Attachmentfilename for Part I, Section B, 2. e. 

# I Subst2 Structure.pdf 

# D
EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 12 

# P10 

# 453SANITIZED SUBMISSION 111111111111111111111111111111 PMN2010P6X1 

## PMN Page 

# 6 Part I -- GENERAL INFORMATION -- Continued Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 3. Impurities (a)
- Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial purpose. Provide the CAS Registry Number ifavailable. Ifthere are unidentified impurities, enter "unidentified." (b)
- Estimate the maximum weight % ofeach impurity. Ifthere are unidentified impurities, estimate their total weiQht %. Impurity (a) CAS Registry Number

(a) Maximum Percent % (b) Confidential

Mark (X) this box ifthe data continues on the next page. 

# D
EnterAttachment filename for Part I, Section B, 3. 

# I 

# D 4. Synonyms
- Enter any chemical synonyms for the new chemical identified in subsection 1 or 2. 

# D

Enter Attachment filename for Part I, Section B, 4. 

# I 

# D 5. Trade identification
- List trade names for the new chemical substance identified in subsection 1 or 2. XTJ-678 Jeffamine 0-198 

# D

EnterAttachment filename for Part I, Section B, 5. 

# I 

# D 6. Generic chemical name - Ifyou claim chemical identify as confidential, you must provide a generic name for your substance that reveals the specific chemical identity ofthe new chemical substance to the maximum extent possible. Refer to the TSCA Chemical Substance Inventory, 1985 Edition, Appendix B for guidance on developing generic names.

EnterAttachment filename for Part I, Section B, 6. 

# I 7. Byproducts - Describe any byproducts resulting from the manufacture, processing, use, or disposal ofthe new chemical substance. Provide the CAS Registry Number ifavailable. Byproduct (1) CAS Registry Number (2) Confidential 2-Propanamine 75-31-0 3,6,6-trimethyl homomorpholine
1,3-Propanediamine, 2,2-dimethyl­ 7328-91-8 Water 7732-18-5 Mark (X) this box if the data continues on the next page. 

# D

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 13XXX SANITIZED SUBMISSION 

# III1

# II~II~IIIIIIIIIIIIIIIIII**~III** PMN2010P7 

## PMNPage 

# 7 Part I -- GENERAL INFORMATION
-- Continued Section C
-- PRODUCTION, IMPORT, AND USE INFORMATION: The information on this page refers toconsolidated chemical number(s): 

## X] 2 

# 0 3 5 

# 06 Mark (X) the ·Confidential" box nextto any item you claim as confidential. 

### 1. Production volume - Estimate the maximum production volume during the first 12 months ofproduction. Also estimate the maximum production volume for any consecutive 12-month period during the first three years ofproduction. Estimates should be on 100% newchemical substance basis. Fora LowVolume Exemption application. ifyou choose to have your notice reviewed at a lower production volume than 10,000 kg/yr, specifythe volume and mark (x) in the binding box. Ifgranted, you are bound to this volume. Binding Option Maximum 12-month production (kg/yr) imum first 12-month production (kg/yr) Confidential Mark (X) (100% new chemical substance basis) (100% newchemical substance basis) 

# [XJ XXX 

# 0 EnterAttachment filename for Part I, Section C, 1. 

### CBI 

# 0 I 2. Use Information
- You must make separate confidentiality claims for the description ofthe category of use, the percent ofproduction volume devoted to each category, the formulation ofthe newsubstance, and other use information. Mark (X) the "Confidential" Box next to any item you claim as confidential. a. (1) --Describe each intended category of use ofthe newchemical substance by function and application. (2) --Mark (X) this column ifentry column (1) is confidential business information (CBI). (3) --Indicate yourwillingness to have the information provided in column (1) binding. (4 --Estimate the

) percent oftotal production for the first three 

### Y ears devoted to each categ0ry ofuse. (5) --Mark (X) this column if fid . I b entry In co umn (4) is can I entia 

### . f uSlness In ormation (CBI) (6) --Estimatethe percent ofthe newsubstance as formulated in mixtures, suspensions, emulsions, solutions, orgels as manufactured for commercial purposes at sites underyour control associated with each category ofuse. (7) --Mark (X) this column ifentry in column (6) is confidential business information (CBI). (8) --Indicate % ofproduct volume expected forthe listed "use" sectors. Mark more than one box ifappropriate. Mark (X) to indicate your willingness to have the use type provided in (8) binding. (9) -Mark (X) this column ifentry(ies)in column (8) is (are)confidential business information (CBI). Category of use (1) Binding Prod %in % ofsubstance expected per use CBI Option uction Form- CBI (8) CBI (by function and application i.e. a dispersive dye for finishing polyester fibers) Mark 

### (X) % ulation Site-­ Con· Com- Binding (2) {3} (4) (6) (7) limIted sume mercial Option (9) Epoxy Curing Agent 100 95 0 0 100 0

• Ifyou have identified a "consumer" use, please provide on a continuation sheet a detailed description ofthe use(s) ofthis chemical substance in consumer products. In addition include estimates ofthe concentration ofthe new chemical substance as expected in consumer products and describe the chemical reactions bywhichthis substance loses its identity in the consumer product. Mark 

### (X) this box ifthe data continues on the next page. 

# [ 

# ] b. Generic use Ifyou claim any category ofuse description in subsection 2a as confidential, enter a generic description ofthat category. deSCription Read the Instruction Manual for examples ofgeneric use descriptions.

EnterAttachment filename for Part I, Section C, 2. b. 

# I CBI 

# 0 3. Hazard Information •• Include in the notice a copy of reasonable facsimile ofany hazard warning statement, label. material safety

data sheet. orother information which will be provided to any person who is reasonably likelyto be exposed tothis substance Binding Option regarding protective equipment or practices for the safe handing. transport. use. or disposal ofthe newsubstance. List in part III Mark (X) hazard informationyou include. Mark (X) this box ifyou attach hazard information. 

# [R] 

# 0 EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 1411111111 SANITIZED SUBMISSION PMN2010P8 

## PMNPage 

# 8

# IIIIIIIIIII~IIIIIIIII Part 11-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE I Mark (X) the "Confidential" box nextto i 

### Section A - INDUSTRIAL SITES CONTROLLED BYTHE SUBMITTER any item you claim as confidential

The information on pages 8 and 8a referto consolidated chemical number(s): 

# [XJ 1 [XJ2 J3 

# l J4 

# 05 

# 06 Complete section A foreach type of manufacture, processing, or use operation involving the newchemical substance at industrial sites you control. Importers do not haveto complete this section for operations outsidethe U.S.; however, you may still have reporting



### . 

## ...... requirements Ifthere are further Industrial processing or use operations after Import. You mustdescribe these operations. See instructions manual

I 1. Operation description a. Identity -­ Enterthe identity ofthe site atwhich the operationwill occur. Name Huntsman Corporation Conroe Site Site address (number and street) 5451 Jefferson Chemical Road City Conroe County Montgomery State TX ZIP code 77306 Ifthe same operation will occur at more than one site, enterthe number ofsites. Identifythe additional sites on a continuation sheet, and if any ofthe sites have significantly different production rates or 

## 1 operations, include all the information requested in this section for those sites as attachments.**~** Mark (X) this box ifthe data continues on the next page. 

# 0 b. Type-­ Manufacturing 

# [&] Processing 

# 0 Use 

# 0 Mark (X) c. Amount and Duration Complete 1 or2 as appropriate Maximum kg/batch I (100% new chemical Hours/batch Batches/year 1. Batch substance)
Maximum kg/day Hours/day Days/year 2. Continuous (100% new chemical substance) 

### XXX XXX 

### XXX Mark (X) to indicate yourwillingness to 

# 0 d. Process description have your process description binding.**~** Confidential



# 0 0 0Confidential



# 0 [&]

(1) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specify- e.g. 5gallon pails, 55 gallon drum, rail car, tank trUCk, etc.). (2) Provide the identity, the approximate weight (by kg/day or kglbatch on a 100% new chemical substance basis), and entry point ofall starting materials and feedstocks (inCluding reactants, solvents, catalysts, etc.), and ofall products, recycle streams, and wastes. Include cleaning chemicals (note frequency ifnot used daily or per batch.). (3) Identify by numberthe pOints ofrelease, including small or intermittent releases, to the environment ofthe new chemical substance. If releasing to

### two media at the same step, assign a second release number for the second medium. 

# [&] XXX

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 1511111111111111111111111111111111111111111111111111111111111 SANITIZED SUBMISSION PMN2010P8A 

# PMNPage 

## 8 a Confidential Diagram ofthe major unit operation steps. 

# 0

See Attachment 007 (SANITIZED PMN BLOCK FLOW DIAGRAM,doc)

EnterAttachment filename for Part II, Section A. 1. d, 

# I SANITIZED PMN BLOCK FLOW DIAGRAM.doc 

# [ J

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Fonn 7710-25 Page 161111111111111111111111111111 SANITIZED SUBMISSION PMN2010P9 

# PMN Page 

# 9 Part 

## II·· HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE ..Continued Section A ..INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER .•Continued The information on pages 9 and 9a referto consolidated chemical number(s): 

## [XJ 1 [X 2 

# [J3 [J4 [ 5 [ J6 2. Occupational Exposure -- You must make separate confidentiality claims for the description ofworker activity, physical form ofthe newchemical

substance, numberofworkers exposed, and duration ofactivity. Mark (X) the ·Confidential" box nextto any item you claim as confidential.

(1)
-­ Describe the activities (Le. bag dumping, tote filling, unloading drums, sampling, cleaning, etc.) in which workers may be exposed to the substance. (2) -- Mark (X) this column ifentry in column (1) is confidential business information (CSI). (3) -- Describe any protective equipment and engineering controls used to protect workers. (4) and (6) Indicate your willingness to havethe information provided in column (3) or (5) binding. (5)
-- Indicate the physical formes) ofthe newchemical substance (e.g., solid: crystal, granule, powder, or dust) and 

### % new chemical substance (if part ofa mixture) atthe time ofexposure. (7) Mark (X) this column ifentries in columns (3) and (5) are confidential business information (CSI). (8) Estimate the maximum number ofworkers involved in each activity for all sites combined. (9) -- Mark (X) this column ifentry in column (8) is confidential business information (CSI). (10) and (11)
-- Estimate the maximum duration ofthe activity for anyworker in hours per dayand days peryear. (12)
-- Mark (X) this column ifentries in columns (10) and (11) are confidential business information (CSI). 

# I Workeractivity Protective Equipment! Binding Physical form(s) (i.e., bag dumping, filling CBI Option &%new drums) Engineering Controls Mark (X) substance

(1) (2) (3) (4) (S) Binding #of Option CBI Workers CBI Mark (X) Exposed

(6) (7) (8) (9) Maximum Duration HrslDay Days/Yr

(10) (11) 

### I CBI i (12) QC Sampling XXX 

### XXX 

## X XXX 

## X XXX XXX 

## X

Shipping QC Sampling XXX XXX 

## X XXX 

## X XXX 

### XXX 

## X

Loading tank wagons 

### XXX XXX 

## X XXX 

## X XXX XXX 

## X

Waterwaste periodically XXX XXX sentto the on-site treatment ponds 

## X XXX 

## X XXX XXX 

## X



# I



# ,
I

Mark (X) this box ifthe data continues on the next page. EnterAttachment filename for Part II, Section A on the bottom ofpage 9a. 

# I I 

# D

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 17111I SANITIZED SUBMISSION 1111111111111111111111 PMN

### 2010P9A 

# PMNPage 

# 9

# a 3. Environmental Release and Disposal-- You must make separate confidentiality claims for the release number and the amount ofthe newchemical substance released and other release and disposal information, Mark (X) the "Confidential" box next to each itemyou claim as confidential. (1)
-­ Enterthe numberofeach release point identified in the process description, part II, section A, subsection 1d(3). (2)
-­ Estimate the amount ofthe newsubstance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch), (3)
-­ Mark (X) this column ifentries in columns (1) and (2) are confidential business information (CSI), (4)
-­ Identify the media (stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration, POTW, or other (specify» towhich the new substance will be released from that release point. (5) a, Describe control technology, ifany, and control efficiencythat will be used to limit the release ofthe newsubstance to the environment. For releases disposed ofon land, characterize the disposal method and state whether it is approved for disposal ofRCRA hazardous waste. On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subjectto secondary ortertiary on-site treatment. b, Estimatethe amount released to the environment after control technology (in kg/day). (6) •• Mark (X) this column ifentries in columns (4) and (5) are confidential business information (CSI). (7)
-­ Identifythe destinalion(s) ofreleases to water, Please supply NPDES (National Pollutant Discharge Elimination System) numbers fordirect discharges or NPDES numbers ofthe POTW(Publicly Owned TreatmentWorks). Mark 

### (X) ifthe POTW name or NPDES

### # is confidential business information (CSI), Release Amount of New Medium of release Controltechnology and efficiency (you maywishto Number Substance Released CBI e.g. Stackair optionally attach efficiency data) CBI i Binding 

# I i (1) (2a) (2b) (3) (4) (58) Mark (5b) (6) (X) 1 0 0.1 kg / Other: On-site waste water tank Waste watertank 0.01 g / campaign campaign
2 0 0.1 kg / Other: On-sitewaste water tank waste water tank 0.01 g / campaign campaign I 

### 3 0 Hg/ Other: On-site waste water tank Waste watertank 0.1 g / campaign campaign
4 0 4500 kg / Other: On-site waste watertank Waste water tank, then on-site 0.1 kg / campaign treatment pondsfor microbial day digestion

I



### I Mark (X) this box ifthe data continues on the next page. 

# D (7) Mark (X) the destination(s' of releases towater. NPDES# CBI



# D POTW--provide 

# D I i 

### name(s) I 

# D Navigable waterway- i



### - provide name(s) 

# D i 

# D Other-Specify 

# D
EnterAttachment filename for Part II, Section 

### A. 

# I 

# D
EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 18PMN2010P10 11111111111111111111111111111111 SANITIZED SUBMISSION 

## PMN 

## Page 10 Part 11-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE
- Continued Section B -- INDUSTRIAL SITES CONTROLLED BY OTHERS The information on pages 10 and 10a referto consolidated chemical number(s): 

## [X] 1 [X] 2 

# D 3 

# [J4 

# [J5 

# D 6 Complete section B for typical processing or use operations involving the newchemical substance at sites you do not control. Importers do not have to complete this section for operations outside the U.S.; however, you must report any processing or use activities after import. See the Instructions Manual. Complete a separate section B foreach type of processing, oruse operation involving the newchemicalsubstance. Ifthe same operation is performed at more than one site describe the typical operation common to Ihese sites. Identify additional sites on a continuation sheet. 1(a). Operation Description -- To claim infonnalion in this section as confidential, bracket (e.g. {)) the specific information thatyou claim as confidential. (1)
-­ Diagram the major unit operation steps and chemical conversions, including interim storage and transport containers (specify
- e.g. 5 gallon pailS, 55 gallon drums, rail cars, tanktrucks, etc). On the diagram, identifyby letter and briefly describe each worker activity. (2)
-­ Either in the diagram or in the text field 1(b) below, provide the identity, the approximate weight (by kgldayor kglbatch, on an 100% new chemical substance basis), and entry point ofall feedstocks (including reactants, solvents and catalysts, etc) and all products, recycle streams, and wastes. Include cleaning chemicals (note frequency ifnot used daily or per batch). (3)
-­ Either in the diagram or in the text field 1(b) below, identify by numberthe pOints ofrelease, including small 

### or intermittent releases, to the environment ofthe new chemical substance. (4)
-­ Please enterthe # ofsites (rememberto identify the locations ofthese sites on a continuation sheet): 

### I • !

.


# I Number of Sites 

# I I Confidential 

# [Z]
See Attachment 008 (PMN BLOCK FLOW DIAGRAM 2.doc)

1(b). (Optional) This space is for a text description to clarifythe diagram above. Confidential 

# u The PMN substance is a curing agentwhich will be blended with an epoxy resin system and injected into a mold containing fiberglass. Heat is applied to complete the curing. The finished article will be a wind turbine blade for use in wind fanns that generate electricity. The PMN substance will be supplied to the customerand unloaded from 4000-gal. tank wagons (ActivityA, Release 1) into a blending vessel where other components are added under agitation. The material containing the PMN substance is then pumped (Activity B) into the closed mold along with the epoxy resin using a "vacuum bagging" process. The PMN substance is consumed in this process by reacting with the epoxy resin. The mold is opened and the finished wind blade is removed (Activity C). The fiberglass provides a substrate for the cured epoxyto adhere to thus giving the finished wind blade extra strength. The emptytank wagons ofthe PMN substance are rinsed with water (Activity D, Release 2)which is collected in a waste watertank and periodically sentto treatment ponds where it is decomposed by microbes.

EnterAttachment filename for Part 

### II, Section B on the bottom ofpage 10a. 

# I PMN BLOCK FLOW DIAGRAM 2.doc 

# D

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 19

## xxx 1111111111111111111111 11111111111111 SANITIZED SUBMISSION PMN2010P10-1 

# Continuation Sheet ID

# I P10SB1(a)(4)1 

# I Field

# IPart II, Section B, 1(a)(4). Operation Site Locations

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 20SANITIZED SUBMISSION

# IIIII~IIIIIIIIIIIIIIIIIIIIIIIII PMN2010P10A 

## PMN P

## age 10

# a 2. Worker ExposurelEnvironmental Release (1)
-­ From the diagram above. provide the letter for each worker activity. Complete 2-8 for each worker activitydescribed. (2)
-­ Estimate the number ofworkers exposed for all sites combined. (4)
-­ Estimatethe typical duration ofexposure perworker in (a) hours per dayand (b) days peryear. (6) Describe physical form ofexposure and 

### % newchemical substance (ifin mixture). and any protective equipment and engineering controls. if any, used to protectworkers. (7)
-­ Estimate the percent ofthe new substance as formulated when packaged or used as a final product. (9)
-­ From the process diagram above. enter the number ofeach release point. Complete 9-13 for each release point identified. (10)
-­ Estimate the amountofthe new substance released (a) directly to the environment or (b) into control technology tothe environment (in kg/day or kglbatch). (12)
-­ Describe media of release i.e. stack air. fugitive air (optional-see Instructions Manual). sur1ace water, on-site or off-site land or incineration. I POTW. orother (specify) and control technology. ifany. thatwill be used to limitthe release ofthe newsubstance to the environment. (14) Identify byproducts which may result from the operation. (3), (5), (8). (11), (13) and (15)
-- Mark 

### (X) this column ifany ofthe proceeding entries are confidential business information (CBI). Letter #of Duration of Protective EquipJEngineering ControlslPhysical 

### "10 new "loin

of Workers CBI CBI CBI Activity Exposed Exposure Form substance Formulation

(1) (2) (3) (4a) (4b) (5) 

### (6) (6) (7) (8) A 1 0.5 20 Hard hat. face shield, safety glasses, rubbergloves. 95 95 Nomex overalls 

### I D 1 .5 20 Hard hat, face shield. safety glasses, rubbergloves. 1 1 

### I Nomex overalls
[ I i



### I Release Amountof New Substance Released CBI Media of Release& Control Technology CBI 

# I Number

(9) (10a) 

# I (10b) (11) (12) (13) 1 0 

### I 0.01 kg / day Waste WaterTank

2 0 1 kg 

### Iday Waste watertank i

i 

## I

I I I I I Mark (X) this box ifthe data continues on the next page. 

# [] (14) Byproducts: 

# I (15) CBI 

# 0 EnterAttachment filename for Part II, Section B. 

# [ ]

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions ofEPA Form 7710-25 Page211111111111111111111111111111111111111111111111111111111111II SANITIZED SUBMISSION PMN2010P11 

## PMN Page 11 

# OPTIONALPOLLUTIONPREVENTIONINFORMATION To claim information in the following section as confidential, bracket (e.g.

## 0> the specific information that you claim as confidential. In this section you may provide information not reported elsewhere in this form regarding your efforts to reduce or minimize potential risks associated with activities surrounding manufacturing, processing, use and disposal ofthe PMN substance. Please include new information pertinentto pollution prevention, including source reduction, recycling activities and safer processes or products available due to the newchemical substance. Source reduction includes the reduction in the amount ortoxicity ofchemical wastes by technological modification, process and procedure modification, product reformulation, and/or raw materials substitution. Recycling refers tothe reclamation of useful chemical components from wastes that would otherwise betreated or released as air emiSSions orwater discharges, or land disposal. Quantitative orqualitative descriptions ofpollution prevention, source reduction and recycling should emphasize potential risk reduction in addition to compliance with existing regulatory requirements. The EPA is interested in the information to assess overall net reductions in toxicity or environmental releases and exposures, notthe shifting of risks to other media (e.g., airto water) or nonenvironmental areas (e.g., occupational or consumer exposure). To the extent known, information aboutthe technology being replaced will assist EPA in its relative risk determination. In addition, information on the relative cost or performance characteristics ofthe PMN substanceto potential alternatives may be provided. Describethe expected net benefits, such as

(1) an overall reduction in risk to human health orthe environment; (2) a reduction in the generation ofwaste materialsthrough recycling, source reduction or other means; (3) a reduction in the useofhazardous starting materials, reagents, or feedstocks; (4) a reduction in potential toxicity. human exposure and/or environmental release; or (5) the extent to which the new chemical substance may be a substitutefor an existing substance that poses a greater overall riskto human health orthe environment. 

### Information provided in thissection will be taken intoconsideration during the review ofthissubstance. See PMN Instructions Manual and Pollution Prevention Guidance manual forguidanceand examples. The PMN substance will be used to makewind bladesfor electricity generation. This will offset the need for electricity generatedfrom the buming offossil fuels thereby aVOiding all ofthe environmental problems associated with this method. This will reduce potential toxicity to human health and the environment.

EnterAttachment filename for Pollution Prevention Page 11. 

# I 

# [ ]

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page22

### SANITIZED SUBMISSION 111111111111111111111111111111



### PMN2010P12 

## PMNPage 12 Part III -- UST OF ATTACHMENTS Attach continuation sheets for sections ofthe form, testdata and other data (including physical/chemical properties and structure/activity information), and optional information afterthis page. Clearly identify the attachment and the section ofthe form to which it relates, ifappropriate. Number consecutively the pages ofany paper attachments. In the Number ofPages column below, enter the inclusive page numbers ofeach attachmentfor paper submissions or enter the total number ofpages for each attachment for electronic submissions. Electronic attachments can be identified by filename. Mark (X) 

### the "Confidential" box nextto any attachment name or filename you claim as confidential. Read the Instructions Manual for guidance on how to claim any information in an attachmentas confidential. You must include with the sanitized copy ofthe notice form a sanitized version ofany attachment in which you claim information as confidential.

# 

### Attachment Name Attachment Filename Number of Pages Associated PMN Section

Number CBI 001 CAS IES Report 1220986-58-2 1220986-58-2.pdf 1 PU, Sec.B, 2c. 002 CAS IES Report 1220986-59-3 1220986-59-3.pdf 1 PLI, Sec.B, 2c. (Chem 2) 003 Substance 1Structure Subst 1Structure.pdf 1 Pt.I, Sec.B, 2e. 004 Substance 2Structure Subst 2Structure.pdf 1 Pt.!, Sec.B, 2e. (Chem 2) 005 MSDS for Subs!. 1 Jeffamine RFD 270 Subst 1MSDS.pdf 7 006 MSDS for Subs!. 2 XTJ-678 Subst 2MSDS.pdf 7 007 Sanitized Block Flow Diagram for PMN Synthesis SANITIZED PMN BLOCK FLOW DIAGRAM.doc 1 Pt.2, Sec.A, 1d. 008 Flow Diagram ofWind Blade Formation PMN BLOCK FLOW DIAGRAM 2.doc 1 

### Pt.2, Sec.B, 1a. 009 Surrogate Toxicity Data Reference Surrogate Toxicity Data for PMN.doc 1

Mark (X) this box ifthe data continues on the next page. 

# [ ] EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 Page 231111111111111 

### SANITIZED SUBMISSION 111111111111111111111111111 

### PMN2010P13 

# PMNP

# age 13 PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET The Information on this page refers

## tochemical number(s): 

# rAJ 1 

# [AJ2 [h [ ] 4 

# [ ]5 [ ] 6 To assist EPA's review of physical and chemical properties data, please complete the following worksheetfor data you provide and include 

### it inthe notice. Identifythe property measured, the value ofthe property, the units in which the property is measured (as necessary). and whether or notthe property is claimed as confidential. Give the attachment number (found on page 12) in column (b). The physical state ofthe neat substance should be provided. These measured properties should be forthe neat (100% pure) chemical substance. Properties 

### thatare measured for mixtures or formulations should be so noted (% PMN substance in

# ->. You are not required to submit this worksheet; however, EPA strongly recommends that you do so, as it will simplify 

### the review and ensure that confidential information is proper1y protected. You should submit thisworksheet asa supplement to your submission oftest data. This worksheet is not asubstitute for 

### submission oftest data. Property

(a) Unit 

# I MarkX if Provided Attachment Number

(b) Value (e) Measured or Estimate

(M orE) 

### CBI Mark (X)

(d) 

# D Physical state ofneatsubstance (solid) 

# I (liquid) (gas) 

## X 

# D D D Vapor Pressure @ Temperature 

# xxx ·C 

# D xxx Torr 

## X Density/relative denSity 

# D XXX g/em3 

# X Solubility @ Temperature Solvent 

# ·c 

# D gil


### Solubility in Water @ Temperature 

## XXX 

# ·c 

# D XXX giL 

## X Melting Temperature 

# D ·c Boiling / Sublimation temperature @ XXX Torr 

# D XXX 

### ·C 

## X I 

### Spectra 

# D Dissociation constant 

# D Octanol/water partition coefficient 

# D Henry's Law constant 

# D Volatilization from water 

# D Volatilization from soil 

# D pH@ concentration 

# xxx 

# D xxx X Flammability 

# D Explodability 

# D Adsorption / Coefficient 

# D
Particle Size Distribution 

# D
Other
- Specify 

# D

Page 24

## ATTACHMENT HEADER SHEET

Attachment Number 001 Attachment Name CAS IES Report 1220986-58-2 

## Associated PMN Section Number Pt.l, Sec.B, 2c.
Does not contain CBI



## Report Number X78T100714067813343

# InventoryExpertService

A division oftheAmerican Chemical Society Phone: 800-631-1884, 614-447-3870 Fax: 614-447-3747 E-mail:answers@cas.org Web:www.cas.orglproducts/clientl 

# Substance 1

INVENTORY EXPERT SERVICE REPORT

rES-ORDER NUMBER: 150681-1
REGISTRY NUMBER: 1220986-58-2

CA INDEX NAME Poly[oxy(methyl-1,2-ethanediyl)l, a,a'-[l,4-cyclohexanediylbis (methylene)]bis[w-(2-aminornethylethoxy)

Please print the above CA Index Name on the appropriate page of your PMN. 

# o If this box 

## is checked, CAS has made correction(s) marked in red to your rES order. Please make the same correction(s) to your PMN before submitting it to the EPA.

CAS 2540 Olefltangy River Road P.O. Box 3343 Columbus. Ohio 43210-0334 USA

## ATIACHMENT HEADER SHEET

Attachment Number 002 Attachment Name CAS IES Report 1220986-59-3 

## Associated PMN Section Number Pt.l, Sec.B. 2c. (Chem 2)

Does not contain CBI



## Report Number X78T100714067813343

# InventoryExpertService

A division oftheAmerican Chemical Society Phone: 

## 800-631-1884.614-447-3870 Fax:614-447-3747 E-mail: answers@cas.org Web:www.cas.orglproducts/clientf 

# Substance 2

IN'JENTORY EXPERT SERVICE REPOR'1'

IES-ORDER NUMBER: 150681-2
REGISTRY NUMBER: 1220986-59-3

CA INDEX NA!1E [oxy(rnethyl-1,2-ethanediyl)J, ula' 

## (2,2-dirnethyl-1,3­ propanediyl)bis[ro-(2-arninomethylethoxy)­

Please print the above CA Index Name on the appropriate page of your PMN.

If this box is checked, CAS has made correction(s) marked in red to your IES order. Please make the same correction(s) to your PMN before submitting it to the EPA.

CAS 2540 Olentangy River**Ro~d** P.O. Box 3343 Columbus. Ohio 43210-0334 

### USA

## ATTACHMENT HEADER SHEET

Attachment Number 003 Attachment Name Substance 1 Structure 

## Associated PMN Section Number pt.l, Sec.B, 2e.
Does not contain CBI



## Report Number X78T100714067813343

# tk 4866 p, 

# 4**,~pr,** 

# 29, 20 1

# 0 3:04PM 

# /S7)b'Jl Substance 1

XTJ-684

nAJ"lQ/0il1A TUII 10-11 r T v j 0 v un;.:. '1 ("'<I') 1 r::h A n A

## ATTACHMENT HEADER SHEET

Attachment Number 004 Attachment Name Substance 2 Structure 

## Associated PMN Section Number pt.l, 

### Sec.B, 

### 2e. (Chern 2)

Does not contain CBI



## Report Number X78T100714067813343

# No.4866 P. 

# 7 

# Substance 2

# ~NH2 

# o 

# ,'Y

XTJ"()78

04128/2010 HU 16:11 [TX/RX tlO 52631 tal007

## ATTACHMENT 

# HEADER SHEET

Attachment Number 005 Attachment Name MSDS for Subst. 1 - Jeffamine RFD 270 

## Associated 

# PMN Section Number N/A
Does not contain CBI



## Report Number X78T100714067813343

## HUNTSMAN Enriching livesthrough innovation 

# Material Safety Data Sheet 

# 11. Productand company identification Product name

# ~EFFAMINE® 

# RFD 270 MSDS # 

### Km061681 

# ,,* For Research and Development or ExportOnly

# *** Product use**~uring** 

### agents.

,.,. Huntsman International LLC P.O. Box4980 The Woodlands,TX77387

TELEPHONE NUMBERS Transportation/Emergency CHEMTREC: (800) 424·9300 Technical Information: (281) 719-7780 E-MAIL: MSDS@huntsman.com Validation date : 512812010. In case ofemergency 

## " Spills Leaks Fire or Exposure Call Chemtrec: (800) 424-9300 In Mexico: 01 8000021400 In Columbia: 01 80091 6012 

# 12. Hazards identification Physical state Odor OSHAlHCS status

GENERAL INFORMATION I!f'quid. !A"mmoniacal. rMiis material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). !'!fANGER! FFOR RESEARCH AND DEVELOPMENT OR EXPORT ONLY*** CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. r"orrosive to eyes and skin. Causes burns. May be harmful if absorbed through skin or if swallowed. Do not breathe vapor or mist. Do not ingest. Do not get in eyes or on skin or clothing. Use onlywith adequate ventilation. Keep containertightly closed and sealed until ready for use. Wash thoroughly after handling.
!Read the entire MSDS for a morethorough evaluation ofthe hazards. 

# 3. Composition/information on ingredients
Name CAS number % "'mine-terminated cycloaliphatic propoxylate 1220986-58-2 90 - 95

512812010. 

## Page: 1fl

# IfEFFAMINE®RFD 270

m 

# /4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician lIJ'et medical attention immediately, Immediatelyflush eyes with plenty ofwater, occasionally lifting the upper and lower eyelids. Checkfor and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Iret medical attention immediately. Flush contaminated skin with plenty ofwater. Remove contaminated clothing and shoes, Wash contaminated clothing thoroughly with water before removing it, or weargloves, Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoesthoroughly before reuse. Iretmedical attention immediately. Move exposed person to fresh air. If it is suspected thatfumes are still present, the rescuer should wear an appropriate mask or self­ contained breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel. It may be dangerousto the person providing aid to give mouth-to­ mouth resuscitation. Ifunconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, beltor waistband, In case of inhalation ofdecomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. rfet medical attention immediately. Wash out mouth with water, Move exposed person to fresh air. 

## 00 not inducevomiting unless directed to do so by medical personnel. Chemical burns must be treated promptlyby a physician. Nevergive anything by mouth to an unconscious person. Ifymptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least48 hours, 

# 15. Fire-fighting measures Flash point Products ofcombustion
Extinguishing media

Suitable Notsuitable Special exposure hazards
Special protective equipmentforfire-fighters**~osed** 

### cup: >149°C (>300,2°F) Ilfecomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides IT'se an extinguishing agent suitable for the surrounding fire. IifOne known. 

# Iffa fire or if heated, a pressure increase will occur and the container mayburst. promptly isolate the scene by removing all persons from the vicinity ofthe incident ifthere is a fire. No action shall be taken involving anypersonal risk orwithout suitable training. Pfre-fighters should wearappropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode, 

# /s. Accidental release measures

Personal precautions

Environmental precautions R"o action shall betaken involving any personal risk orwithout suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. 

## 00 not touch or walk through spilled material. 

## 00 not breathe vapor or mist. Provide adequate ventilation, Wearappropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8). lftVoid dispersal ofspilled material and runoff and contactwith soil, waterways, drains and sewers. Inform the relevant authorities ifthe product has caused environmental pollution (sewers, waterways, soil or air).



### 5128/2010. Page: 211

### F1E.FFAMINE®RFD270 

# 6. Accidental release measures Methods forcleaning up : imop leak ifwithout risk. Move containersfrom spill area. Approach release from upwind. Prevent entry into sewers, water courses, basementsorconfined areas. Wash spillages into an effluenttreatment plant or proceed asfollows, Contain and collect spillage with non-combustible, absorbent material e,g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations (see section 13), Dispose ofvia a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard asthe spilled product. Note: see section 

### 1for emergency contact information and section 13 forwaste disposal. 

# 17. Handling and storage Handling

Storage PUton appropriate personal protective equipment (see section 

### 8). Eating, drinking and smoking should be prohibited in areaswhere this material is handled, stored and processed, Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin orclothing, Do not breathe vapor or mist. Do not ingest. If during normal usethe material presents a respiratory hazard, use onlywith adequate ventilation orwear appropriate respirator. Keep in the original container oran approved alternative madefrom a compatible material, kepttightly closed when not in use, Empty containers retain product residue and can be hazardous. Do not reuse container. Ifore in accordance with local regulations, Store in original container protected from directsunlight in a dry, cool and well-ventilated area, awayfrom incompatible materials (see section 10) and food and drink. Keep container tightlyclosed and sealed until ready for use, Containersthat have been opened must be carefully resealed and kept upright to prevent leakage, Do notstore in unlabeled containers. Use appropriate containment to avoid environmental contamination,

# ~m Exposure controls/personal protection Consult local authorities foracceptable exposure limits. 

### PreventiveMeasures Engineering controls

Personal protection

Eyes
Skin Respiratory

Hands

## ~nditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Ifse local exhaust ventilation to maintain airborne concentrations belowthe TLV. Suitable respiratory equipmentshould be used in cases of insufficient ventilation orwhere operational procedures demand 

## tt. For guidance on engineering control measures refer to publications such as the ACGIH current edition of 'Industrial Ventilation, a manual of Recommended Practice,'

### ~fety eyewearcomplying with an approved standard should be used when a risk assessment indicatesthis is necessaryto avoid exposure to liquid splashes, mists or dusts, PYersonal protective equipmentforthe body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Ilfse a properly fitted, air-purifying orair-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards ofthe product andthe safe working limits ofthe selected respirator. rf,emical-resistant, imperviousgloves complying with an approved standard should be worn at all timeswhen handling chemical products if

### a risk assessment indicatesthis is necessary,



### 5/28/2010. 

### Page:

# 3n

## I1EFFAMINE®RFD270 

# 19. Physical and chemical 

# properties

_____________-----' General information

Appearance Physical state**~quid.** 

### Color**~ear** 

### Colorless to light yellow Odor Jfmmoniacal. Odorthreshold frot available. Important health, safetyand environmental information

pH iilfj.5 Boiling point**~3°C** 

### (541.4°F) Melting point I'fot available. Flash point ffosed cup: >149°C (>300.2°F) Oxidizing properties R'ot available. Vapor pressure Jlf'ot available. Relative density 

## "'96 Octanollwater partition Ilf'ot available. coefficient Viscosity Mnematic (40°C (104°F)): 0.301 cm 2

### /s (30.1 cSt) Vapordensity Frot available. VOC content 1I'f'0t available. 

# 110. Stabilityand re_a_c_ti_v_H_y

________________

# ~ Stability and reactivity lPhe product is stable. Incompatibility with various lfeactive or incompatible with the following materials: oxidizing materials, metalsand SUbstances acids. Hazardous polymerization IFnder normal conditions ofstorage and use, hazardous polymerization will notoccur. Hazardous decomposition lJ"ecomposition products may include the following materials: products carbon dioxide carbon monoxide nitrogen oxides 

# 111
. Toxicological information Toxicity data

Acutetoxicity

Product/ingredient name fS!milar material) Test LD50 Dermal LD50 Oral Species Rabbit Rat Result 1700 mglkg 500 to 1000 mglkg Exposure

Potential acute health effects

Ingestion prarmful if swallowed. Maycause burnsto mouth, throatand stomach. Inhalation M'ay give off gas, vapor or dustthat isvery irritating or corrosive to the respiratory system. Eyes !"orrosive to eyes. Causes burns. Skin !"orrosive to the skin. Causes burns. Harmful in contactwith skin. Potential chronic health effects 5/28/2010. Page:4fl

### ffEFFAMINE®RFD 270 

# 11 . Toxicological information

Target organs None known. Carcinogenicity 

# Fro known significant effects or critical hazards. Mutagenicity 

# Ilfo known significant effects or critical hazards. Teratogenicity 

# pro known significant effects or critical hazards. Fertility effects 

# R'o known significant effects or critical hazards. Developmental effects 

# Jfo known significant effects or critical hazards. 

# 12. Ecological information Environmental effects : 

# RO known signifICant effects or critical hazards. 

# 113. Disposal considerations**--------~---------,** Waste disposal P'he generation ofwaste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe way. Dispose of surplus and non-recyclable productsvia a licensed waste disposal contractor. Disposal ofthis product, solutions and anyby­ products should at all times complywith the requirements ofenvironmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal ofspilled material and runoff and contactwith soil, waterways, drains and sewers. 

# 114
. Transport information Transportation Emergency Number 1-800-424-9300 (CHEMTREC).
Propershipping Class Regulatory UN number PG* Label Additional information information name DOT Classification 1JN2922 Ibrrosive liquid, toxic, 

### r(6.1) 

# Jr 

# ". n.o.s. (Amineterminated

# ~ cycloaliphatic propoxylate)

# ~ TOG Classification fBN2922 "-orrosive liquid, toxic, 

### r(6.1) 

# If**~** n.o.s. (Amineerminated

# ~**~ycloal** 

### iphatic propoxylate) 

# ¢

IMDG Class Jirorrosive liquid, toxic, SN2922 

### W(6.1)

### IF!mergenc~ schedules 

# rr n.o.s. (Amine­ (EmS) terminated F-A, 

## SoB cycloaliphatic propoxytate) 

# ¢ 

# •

•

5/28/2010. 

## Page: 5fli 

# IrJEFFAMINE®RFD270



# 14. Transport information \IATA-DGR Class 

### IJBN2922**~orrosive** 

### liquid, toxic, 1"(6.1) 

# !IV'

# ~ l'assenaerand Carao n.o.s. (Amine- AircraftQuantity terminated limitation: 1 L cycloaliphatic Packaging instructions: propoxylate) 

# ¢ 808 Cargo AircraftOnly: Quantity limitation: 30 L Packaging instructions: 812 I

i 

# • PG* : Packing group 

# 115. Regulatory information United States

HCS Classification :**~rrosive** 

### material U.S. Federal regulations : S"nited States inventory (TSCA8b): At least one component is not listed. CERCLA: Hazardous substances.: No ingredients listed. SARA313 No ingredients listed. l'Jiis product does not contain nor is it manufactured with ozone depleting substances.

California Prop 65 mis product contains no listed substances known to the State ofCalifornia to cause cancer, birth defectsor other reproductive harm, at levels which would require a warning underthe statute. Canada

WHMIS (Canada) li!Jass 0-1 B: Material causing immediate and serioustoxic effects (Toxic). Class E: Corrosive material CEPA (OSL) 

# p:rleast one component is not listed. This product has been classified in accordancewiththe hazard criteria ofthe CPR (Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required bythe CPR. 

# 116. Other information F*FOR RESEARCH AND DEVELOPMENT OR EXPORT ONLy*** CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IFABSORBED THROUGH SKIN OR IF SWALLOWED. Hazardous Material Information System (U.S.A.)

National Fire Protection Association (U.S.A.)

## ~Iammability Health Instability


### Date ofprinting 

### 5/28/2010. 5/28/2010. Page: 6fl

### Ift;FFAMINE®RFD 270 

# 116
. Other

# informati~n Date ofissue 28 May2010 

## Date ofprevious issue : 9/1712009. 

## Noticeto reader While the information and recommendations in this publication are 

### to the best 

### of ourknowledge, information and beliefaccurate 

## at the date 

## ofpublication, NOTHING HEREIN IS TO BE CONSTRUEDASA WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY

## OF THE USER TO DETERMINE THE APPLICABILITY

## OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY

## OF ANYPRODUCTFOR ITS OWN PARTICULAR PURPOSE. THEPRODUCTMA YPRESENTHAZARDSAND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDSARE DESCRIBED IN THIS PUBLICA TION, 

### NO GUARANTEEIS MADE THAT THESEARE THE ONLYHAZARDS THA TEXIST. Hazards, toxicityandbehaviour

### ofthe products maydiffer when used with othermaterials andare dependent upon the manufacturing circumstances orotherprocesses. Such hazards, toxicity andbehaviourshould

## be determined 

### by the userandmade known 

## to handlers, processors andendusers. 

### NO PERSON OR ORGANIZATION EXCEPTA DULYAUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAYCONTAIN INFORMATION THAT IS 

### NO LONGER CURRENT OR ACCURATE. 

### NO PART

## OF THIS DATA SHEETMAYBE REPRODUCED OR TRANSMITTED IN ANYFORM, OR BYANYMEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETYAT THEABOVEADDRESS. 

## Trademarks: ". JEFFAMINE® is a registered trademark 

## of Huntsman Petrochemical Corporation in one or more countries. but not all countries. 

## "Indicates information that has changed from previously issued version.

5/28/2010. Page: 

## 7n

## ATTACHMENT HEADER SHEET

Attachment Number 006 Attachment Name MSDS for Subst. 2 - XlJ-678 

## Associated PMN Section Number N/A
Does not contain CBI



## Report Number X78l100714067813343

## HUNTSMAN 

# Material Safety Data Sheet Enriching iivesthrough innovation 

# Productand cornpany identification Product name 

# XTJ 678, EXPERIMENTAL MSDS

## # 00060811 

# *** 

# For Research and Development or Export 

# Only *** Product use Epoxy curing Huntsman Petrochemical Corporation P.O. Box4980 The Woodlands, TX 77387-4980 TELEPHONE NUMBERS Transportation Emergency Company: (800) 328·8501 CHEMTREC: (800) 424·9300 Medical Emergency: (409) 722·9673 (24 Hour)

General MSDS Assistance: (281) 719·6000 Technicallnformalion: (281) 719·7780 E·MAlL: MSDS@huntsman.com Validation dale : 6/24/2009. In case ofemergency

## Spills Leaks Fire or Exposure Call Chemtrec: (800) 424-9300 Medical Emergency Information: (800) 328-8501 In Mexico: 01 800 00 214 00 In Columbia: 01 800 91 6012 

# 12. Hazards identification Physical state Liquid. 

### Odor Amine-like. 

### OSHAlHCS status This material is considered hazardous bythe OSHA Hazard Communication Standard (29 CFR 1910.1200). DANGER! CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. Corrosive to eyes and skin. Causes burns. May be harmful if swallowed. Do not breathe vapor or mist. Do not ingest. Do not get in eyes oron skin or clothing. Use onlywith adequate ventilation. Keep containertightly closed and sealed until readyfor use. Wash thoroughly after handling.


### GENERAL INFORMATION : Read the entire MSDSfor a more thorough evaluation ofthe hazards. 

# 3. Compositionlinforrriation on ingredients
Name CAS number Neopentyl glycol, propoxylated, aminated TSCAR&D



### 6/24/2009. Page: 1/6

### IXT 

### J 

## 678, EXPERIMENTAL 

# 14. First aid measures Eye contact Immediatelyflush eyes with plentyofwater, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Skin contact Flush contaminated skin with plenty ofwater. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Inhalation Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration oroxygen bytrained personnel. Get medical attention ifsymptoms occur. Ingestion Get medical attention immediately. Wash out mouth with water. Move exposed person to fresh air. Do not induce vomiting unless directed to do so by medical personnel. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. Notesto physician SymptomatiC and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least48 hours. 

# IS. Fire-fighting measures Flash point Products ofcombustion Extinguishing media

Suitable Notsuitable Special exposure hazards
Special protective equipmentforfire-fighters Closed cup: 95.28°C (203SF) No specific data. Use an extinguishing agent suitable for the surrounding fire. None known. In a fire or if heated, a pressure increase will occur and the container mayburst. Promptly isolate the scene by removing all persons from the vicinity ofthe incident ifthere is a fire. No action shall betaken involving any personal risk orwithout suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with afull face-piece operated in positive pressure mode. 

# 6. Accidental release measures Personal precautions

Environmental precautions
Methods forcleaning up Noaction shall be taken involving any personal risk orwithout suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch orwalk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). Avoid dispersal ofspilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities 

### if the product has caused environmental pollution (sewers, waterways, soil orair). Stop leak ifwithout risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plantor proceed asfollows. Contain and collectspillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in containerfor disposal according to local regulations (see section 13). Dispose ofvia a licensed waste disposal contractor. Contaminated absorbent material maypose the same hazard as the spilled product. Note: see section 1for emergency contact information and section 13for waste disposal.



## 6124120()'9. Page: 216

### [XTJ

### 678, EXPERIMENTAL 

# \1. Handling and storage

Handling

Storage Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use onlywith adequate ventilation orwear appropriate respirator. Keep in the original container oran approved alternative made from a compatible material, kepttightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, awayfrom incompatible materials (see section 10) and food and drink. Keep container tightlyclosed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 

# !8. Exposure controls/personal protection Consult local authoritiesforacceptable exposure limits. 

### Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Engineering controls Use local exhaust ventilation to maintain airborne concentrations below the TLV. Suitable respiratory equipment should be used in cases ofinsufficientventilation orwhere operational procedures demand it. For guidance on engineering control measures refer to publicationssuch as the ACGIH current edition of 'Industrial Ventilation, a manual of Recommended Practice.' Personal protection

Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessaryto avoid exposure to liquid splashes, mists or dusts. Skin Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Use a properlyfitted, air-purifying orair-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known oranticipated exposure levels, the hazards ofthe productand the safe working limits ofthe selected respirator. Hands Chemical-resistant, impervious gloves complying with an approved standard should be worn at all timeswhen handling chemical products ifa risk assessment indicatesthis is necessary. 

# 19. Physical and chemical properties General information

Appearance Physical state Liquid. Color Off-white. Odor Amine-like. Odorthreshold Not available. Important health.safety and environmental information

pH 10.5 BOiling point 120to 20QoC (248 to 392°F) Melting pOint Notavailable. 

### 6/24/2009. 

## Page: 316

# r XTJ

## 678, EXPERIMENTAL



# .9. Physical and chemical properties

Flash point Oxidizing properties Vapor pressure Relative density Octanollwater partition coefficient Vapordensity VOC content Closed cup: 9S.28°C (203.S0F) Not available. Not available. 0.91 Not available. Not available. Not available.



# ,10. Stability and reactivity Stability and reactivity The product is stable. Incompatibilitywith various substances Reactive or incompatiblewith the follOwing materials: acids. Hazardous polymerization Under normal conditions ofstorage and use, hazardous polymerization will not occur. Hazardous decomposition products No specific data. 

# 111
. Toxicological information Toxicity data

Potential acute health effects

Ingestion Harmful if swallowed. May cause burns to mouth, throat and stomach. Inhalation Maygive offgas, vapor or dustthat is very irritating or corrosive to the respiratory system. Eyes Corrosive to eyes. Causes burns. Skin Corrosive to the skin. Causes burns. Potential chronic health effects

Target organs None known. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects orcritical hazards. Teratogenicity No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. 

# !12. Ecological information

Environmental effects : No known significant effects orcritical hazards. 

# \13
. Disposal considerations Waste disposal



### 6/24/2009. The generation ofwaste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed ofin a safe way. Dispose ofsurplus and non-recyclable productsvia a licensed waste disposal contractor. Disposal ofthis product, solutions and any byproducts should at all times complywith the requirements ofenvironmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal ofspilled material and runoff and contactwith soil, waterways, drains and sewers. 

## Page:416

# IXTJ

## 678, EXPERIMENTAL 

# 114
. Transport information Transportation Emergency Number 1-800-424-9300 (CHEIVITREC).

Additional information information Propershipping Class UN number !Regulatory PG* 

# ILabel name UN2735 Amines, liquid, 

## 8 

## III DOT Classification 

# - corrosive, n.o.s. (Neopentyl glycol, 

# ,+ propoxylated, aminated) 

### III TDG Classification UN2735**~mines,liquid,** 

## 8 

# - \Corrosive, n.o.s.

Neopentyl glycol, propoxylated, 

# + laminated) 

# IIMDG Class UN2735 Amines, liquid, 

## 8 III 

# - corrosive, n.o.s. (Neopentyl glycol, propoxylated, 

# + aminated) i 

### UN2735 Amines, liquid, 

## 8 III 

# - IATA-DGR Class corrosive, n.o.s. tNeOpenryl glyCOl, 

# ..s**~~** 

# ..**~** 

### propoxylated, aminated) 

# • PG* : Packing group 

# \15. Regulatory information

United States

HCS Classification Corrosive material U.S. Federal regulations United States inventory (TSCA 8b): At least one component is not fisted. ***For Research and Development or Export Only"* CERCLA: HazardoussUbstances.: No ingredients listed. SARA313 No ingredients listed. This productdoes not contain nor is it manufacturedwith ozone depleting substances.
California Prop 65 This product contains no listed substances known to the State ofCalifornia to cause cancer, birth defectsorother reproductive harm, at levels which would require a warning underthe statute. Canada

WHMIS (Canada) Class E: Corrosive material CEPA(DSL) 

### At least one component is not listed. This product has been classified in accordancewith the hazard criteria ofthe CPR (Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains allthe information required bythe CPR.

6f24f2009. 

### Page: 516

### [XTJ678, EXPERIMENTAL 

# \16
. Other information CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. 

### Hazardous Material Information System (U.S.A.) 

## 3 1 

# o
National Fire Protection

## ~Iammability Association (U.S.A.) Health

# V Instability
Date of printing 

### 6/24/2009. Date ofissue 24 

### June 2009 

### Date ofprevious issue 

## No previous validation. Noticeto reader 

### While the information and recommendations in this publication are to the best ofourknowledge, information and beliefaccurate at the date ofpublication, NOTHING HEREIN IS 

## TO BECONSTRUEDASA WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER 

## TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITYOFANYPRODUCTFOR ITS OWN PARTICULAR PURPOSE. THE PRODUCTMA

## YPRESENTHAZARDSAND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDSARE DESCRIBED IN THIS PUBLICA TlON, 

## NO GUARANTEEIS MADE THATTHESEARE THE ONL

## YHAZARDS THA

## TEXIST. Hazards, toxicityandbehaviourofthe products may differwhen used with othermaterials andare dependentupon the manufacturing circumstances orotherprocesses. Such hazards, toxicityand behaviourshouldbe determined bythe userandmade known to handlers,processors andendusers. 

## NO PERSON OR ORGANIZATION EXCEPTA DULYAUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED 

## TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAYCONTAIN INFORMA TION THA

## TIS 

## NO LONGER CURRENT ORACCURATE. 

## NO PART OF THIS DATA SHEETMAYBE REPRODUCED OR TRANSMITTED IN ANYFORM, OR BYANYMEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION 

## TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED 

## TO HUNTSMAN, MANAGER, PRODUCT SAFETYAT THEABOVEADDRESS.

,. Indicates information that has changed from previously issuedversion.



### 6/Z4/2009. Page: 6/6

## ATTACHMENT HEADER SHEET

Attachment Number007 Attachment Name Sanitized Siock Flow Diagram for PMN Synthesis 

## Associated PMN Section Number Pt.2, Sec.A, 1d.
Does not contain CSI



## Report Number X78T100714067813343

## STORAGE TANKB STORAGE TANKA ******** kg ofpolyoI 

# NH3 CAS

# #7664-41-7 CAS# 214710-36-8 

## or ****** kg for Subst.l ******** kg ofpolyoI 

## or ***** kg for Subst. 2 

# H2 CarrierGas CAS # 52479-58-0 

# H2 CarrierGas



## REACTOR Continuous BedType withFixedCatalystof RaneyNickel *********



## HYDROGEN STRIPPER 

# H2 Recycledto Reactor 

## WATER STRIPPER 

# I+-­ AMMONIA STRIPPER r-­ 

# H20 andlightamines sent 

# NH3 Recycled to Reactor to WaterWaste



## FINISHING TOWER SAMPLING & 

## QC r-­ 

## Remove anyremaining 

# ---+ (Activity A, Release#1) lightsto WaterWaste 

# 1 STORAGE TANK PACKAGING ****** kg ofXTJ-684

## or 1-----11>1 

## (Activity B, Release#2) for ****** kg ofXTJ-678 pre-packaging QC (PMN Substance) (Activity C, Release#3) for loading into tankwagons.


## WATERWASTE TANK Waterwaste including ca. **** kg ofthePMN 

## ON-SITE TREATMENT PONDS WaterWaste decomposed by microbes. (Activity D, Release#4) Substance from equipment stripping and flushes.

## ATTACHMENT HEADER SHEET

Attachment Number 008 Attachment Name Flow Diagram ofWind Blade Formation 

## Associated PMN Section Number Pt.2, Sec.B, 1a.
Does not contain CBI



## Report Number X78T100714067813343

## EPOXY RESINTANK UNLOADING 

## TANKWAGON • Epoxy Resin of PMN Substance • Catalyst (Activity A, Release #

## 1)

BLENDTANK PMN Substance is blended with other unknown components

MOLD 

## Resins injected into fiberglass-filled closedmold and heated in "Vacuum Bagging"process (Activity B, 

## Release #2)

FINISHED WIND BLADE 

## Article removed from mold (Activity C) EQUIPMENT CLEANING 

## Waterwashing ofthe tanks and otherequipmentcontainingthe PMN Substance (Activity E, Release #4) TANKWAGON CLEANING

# ~ DISPOSAL 

## Waterwashing ofthe tank Waterwaste containing PMN wagons containingthe PIVIN --'" 

## Substance is sentto treatment Substance ponds for microbial digestion. (Activity D, 

## Release #3)

## ATTACHMENT HEADER SHEET

Attachment Number 009 Attachment Name Surrogate Toxicity Data Reference 

## Associated PMN Section Number N/A
Does not contain CBI



## Report Number 

## X78T100714067813343

# Surrogate Toxicity Data for PMN TSX78T84
Huntsman Corporation suggests that the Agency use P06-0748 as a surrogate for the PMN substance. P06-0748 contains a significant amount ofdata, is used forthe same commercial purpose as the PMN substance and is of similar molecular weight.